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1

{sup 99}Tc bioassay by inductively coupled plasma mass spectrometry (ICP-MS)  

SciTech Connect (OSTI)

A means of analyzing {sup 99}Tc in urine by inductively coupled plasma mass spectrometry (ICP-MS) has been developed. Historically, {sup 99}Tc analysis was based on the radiometric detection of the 293 keV E{sub Max} beta decay product by liquid scintillation or gas flow proportional counting. In a urine matrix, the analysis of{sup 99}Tc is plagued with many difficulties using conventional radiometric methods. Difficulties originate during chemical separation due to the volatile nature of Tc{sub 2}O{sub 7} or during radiation detection due to color or chemical quenching. A separation scheme for {sup 99}Tc detection by ICP-MS is given and is proven to be a sensitive and robust analytical alternative. A comparison of methods using radiometric and mass quantitation of {sup 99}Tc has been conducted in water, artificial urine, and real urine matrices at activity levels between 700 and 2,200 dpm/L. Liquid scintillation results based on an external standard quench correction and a quench curve correction method are compared to results obtained by ICP-MS. Each method produced accurate results, however the precision of the ICP-MS results is superior to that of liquid scintillation results. Limits of detection (LOD) for ICP-MS and liquid scintillation detection are 14.67 and 203.4 dpm/L, respectively, in a real urine matrix. In order to determine the basis for the increased precision of the ICP-MS results, the detection sensitivity for each method is derived and measured. The detection sensitivity for the {sup 99}Tc isotope by ICP-MS is 2.175 x 10{sup {minus}7} {+-} 8.990 x 10{sup {minus}9} and by liquid scintillation is 7.434 x 10{sup {minus}14} {+-} 7.461 x 10{sup {minus}15}. A difference by seven orders of magnitude between the two detection systems allows ICP-MS samples to be analyzed for a period of 15 s compared to 3,600 s by liquid scintillation counting with a lower LOD.

Lewis, L.A.

1998-05-01T23:59:59.000Z

2

Mass Spectrometer: Inductively Coupled Plasma (ICP-MS), Multi...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

was completed in February 2011. Although no research has been performed beyond an initial exploration of the Neptune's capabilities, potential users have been contacted in both the...

3

Mass Spectrometer: Inductively Coupled Plasma (ICP-MS), High Resolution  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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4

{sup 99}Tc bioassay: A direct comparison of liquid scintillation radiation detection and ICP-MS mass detection of the {sup 99}Tc isotope  

SciTech Connect (OSTI)

A means of analyzing {sup 99}Tc in urine by inductively coupled plasma mass spectrometry (ICP-MS) has been developed. Historically, {sup 99}Tc analysis was based on the radiometric detection of the 293 keV E{sub Max.} beta decay product by liquid scintillation or gas flow proportional counting. A separation scheme for {sup 99}Tc detection by ICP-MS is given and is proven to be a sensitive and robust analytical alternative. A comparison of methods using radiometric and mass quantitation of {sup 99}Tc has been conducted in water, artificial urine, and real urine matrices at activity levels between 700 and 2,200 dpm/L. Liquid scintillation results based on an external standard manual quench correction and an automatic quench curve correction method are compared with results obtained by ICP-MS. Each method produced accurate results; however, the precision of the ICP-MS results is superior to that of liquid scintillation results.

Lewis, L.A. [Lockheed Martin Energy Systems, Inc., Oak Ridge, TN (United States). Analytical Services Organization; Schweitzer, G.K. [Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

1998-12-31T23:59:59.000Z

5

Precise ruthenium fission product isotopic analysis using dynamic reaction cell inductively coupled plasma mass spectrometry (DRC-ICP-MS)  

SciTech Connect (OSTI)

99Tc is a subsurface contaminant of interest at numerous federal, industrial, and international facilities. However, as a mono-isotopic fission product, 99Tc lacks the ability to be used as a signature to differentiate between the different waste disposal pathways that could have contributed to subsurface contamination at these facilities. Ruthenium fission-product isotopes are attractive analogues for the characterization of 99Tc sources because of their direct similarity to technetium with regard to subsurface mobility, and their large fission yields and low natural background concentrations. We developed an inductively coupled plasma mass spectrometry (ICP-MS) method capable of measuring ruthenium isotopes in groundwater samples and extracts of vadose zone sediments. Samples were analyzed directly on a Perkin Elmer ELAN DRC II ICP-MS after a single pass through a 1-ml bed volume of Dowex AG 50W-X8 100-200 mesh cation exchange resin. Precise ruthenium isotopic ratio measurements were achieved using a low-flow Meinhard-type nebulizer and long sample acquisition times (150,000 ms). Relative standard deviations of triplicate replicates were maintained at less than 0.5% when the total ruthenium solution concentration was 0.1 ng/ml or higher. Further work was performed to minimize the impact caused by mass interferences using the dynamic reaction cell (DRC) with O2 as the reaction gas. The aqueous concentrations of 96Mo and 96Zr were reduced by more than 99.7% in the reaction cell prior to injection of the sample into the mass analyzer quadrupole. The DRC was used in combination with stable-mass correction to quantitatively analyze samples containing up to 2-orders of magnitude more zirconium and molybdenum than ruthenium. The analytical approach documented herein provides an efficient and cost-effective way to precisely measure ruthenium isotopes and quantitate total ruthenium (natural vs. fission-product) in aqueous matrixes.

Brown, Christopher F.; Dresel, P. Evan; Geiszler, Keith N.; Farmer, Orville T.

2006-05-09T23:59:59.000Z

6

Improving Alpha Spectrometry Energy Resolution by Ion Implantation with ICP-MS  

SciTech Connect (OSTI)

We report results of a novel technique using an Inductively Coupled Plasma Mass Spectrometer (ICP-MS) as a method of source preparation for alpha spectrometry. This method produced thin, contaminant free 241Am samples which yielded extraordinary energy resolution which appear to be at the lower limit of the detection technology used in this research.

Dion, Michael P.; Liezers, Martin; Farmer, Orville T.; Miller, Brian W.; Morley, Shannon M.; Barinaga, Charles J.; Eiden, Gregory C.

2015-01-01T23:59:59.000Z

7

Measurement of elemental speciation by liquid chromatography -- inductively coupled plasma mass spectrometry (LC-ICP-MS) with the direct injection nebulizer (DIN)  

SciTech Connect (OSTI)

This thesis is divided into 4 parts: elemental speciation, speciation of mercury and lead compounds by microbore column LC-ICP-MS with direct injection nebulization, spatially resolved measurements of size and velocity distributions of aerosol droplets from a direct injection nebulizer, and elemental speciation by anion exchange and size exclusion chromatography with detection by ICP-MS with direct injection nebulization. Tabs, figs, refs.

Shum, S.

1993-05-01T23:59:59.000Z

8

Mass Spectrometer: Inductively Coupled Plasma (ICP-MS), Multi-Collector  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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9

Mass Spectrometer: Inductively Coupled Plasma (ICP-MS), Ultra-High  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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10

ICP-MS (Quadrupole) | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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11

Standard practice for the determination of 237Np, 232Th, 235U and 238U in urine by inductively coupled plasma-Mass spectrometry (ICP-MS) and gamma ray spectrometry.  

E-Print Network [OSTI]

1.1 This practice covers the separation and preconcentration of neptunium-237 (237Np), thorium-232 (232Th), uranium-235 (235U) and uranium-238 (238U) from urine followed by quantitation using ICP-MS. 1.2 This practice can be used to support routine bioassay programs. The minimum detectable concentrations (MDC) for this method, taking the preconcentration factor into account, are approximately 1E-2Bq for 237Np (0.38ng), 2E-6Bq for 232Th (0.50ng), 4E-5Bq for 235U (0.50ng) and 6E-6Bq for 238U (0.48ng). 1.3 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

American Society for Testing and Materials. Philadelphia

2005-01-01T23:59:59.000Z

12

Evaluation of ultra-low background materials for uranium and thorium using ICP-MS  

SciTech Connect (OSTI)

An increasing number of physics experiments require low background materials for their construction. The presence of Uranium and Thorium and their progeny in these materials present a variety of unwanted background sources for these experiments. The sensitivity of the experiments continues to drive the necessary levels of detection ever lower as well. This requirement for greater sensitivity has rendered direct radioassay impractical in many cases requiring large quantities of material, frequently many kilograms, and prolonged counting times, often months. Other assay techniques have been employed such as Neutron Activation Analysis but this requires access to expensive facilities and instrumentation and can be further complicated and delayed by the formation of unwanted radionuclides. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) is a useful tool and recent advancements have increased the sensitivity particularly in the elemental high mass range of U and Th. Unlike direct radioassay, ICP-MS is a destructive technique since it requires the sample to be in liquid form which is aspirated into a high temperature plasma. But it benefits in that it usually requires a very small sample, typically about a gram. This paper discusses how a variety of low background materials such as copper, polymers, and fused silica are made amenable to ICP-MS assay and how the arduous task of maintaining low backgrounds of U and Th is achieved.

Hoppe, E. W.; Overman, N. R.; LaFerriere, B. D. [Pacific Northwest National Laboratory, Richland, WA 99354 (United States)] [Pacific Northwest National Laboratory, Richland, WA 99354 (United States)

2013-08-08T23:59:59.000Z

13

Evaluation of Ultra-Low Background Materials for Uranium and Thorium Using ICP-MS  

SciTech Connect (OSTI)

An increasing number of physics experiments require low background materials for their construction. The presence of Uranium and Thorium and their progeny in these materials present a variety of unwanted background sources for these experiments. The sensitivity of the experiments continues to drive the necessary levels of detection ever lower as well. This requirement for greater sensitivity has rendered direct radioassay impractical in many cases requiring large quantities of material, frequently many kilograms, and prolonged counting times, often months. Other assay techniques have been employed such as Neutron Activation Analysis but this requires access to expensive facilities and instrumentation and can be further complicated and delayed by the formation of unwanted radionuclides. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) is a useful tool and recent advancements have increased the sensitivity particularly in the elemental high mass range of U and Th. Unlike direct radioassay, ICP-MS is a destructive technique since it requires the sample to be in liquid form which is aspirated into a high temperature plasma. But it benefits in that it usually requires a very small sample, typically about a gram. Here we will discuss how a variety of low background materials such as copper, polymers, and fused silica are made amenable to ICP-MS assay and how the arduous task of maintaining low backgrounds of U and Th is achieved.

Hoppe, Eric W.; Overman, Nicole R.; LaFerriere, Brian D.

2013-08-08T23:59:59.000Z

14

Uncertainty Measurement for Trace Element Analysis of Uranium and Plutonium Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS)  

SciTech Connect (OSTI)

The measurement uncertainty estimatino associated with trace element analysis of impurities in U and Pu was evaluated using the Guide to the Expression of Uncertainty Measurement (GUM). I this evalution the uncertainty sources were identified and standard uncertainties for the components were categorized as either Type A or B. The combined standard uncertainty was calculated and a coverage factor k = 2 was applied to obtain the expanded uncertainty, U. The ICP-AES and ICP-MS methods used were deveoped for the multi-element analysis of U and Pu samples. A typical analytical run consists of standards, process blanks, samples, matrix spiked samples, post digestion spiked samples and independent calibration verification standards. The uncertainty estimation was performed on U and Pu samples that have been analyzed previously as part of the U and Pu Sample Exchange Programs. Control chart results and data from the U and Pu metal exchange programs were combined with the GUM into a concentration dependent estimate of the expanded uncertainty. Comparison of trace element uncertainties obtained using this model was compared to those obtained for trace element results as part of the Exchange programs. This process was completed for all trace elements that were determined to be above the detection limit for the U and Pu samples.

Gallimore, David L. [Los Alamos National Laboratory

2012-06-13T23:59:59.000Z

15

Validation of Electrochemically Modulated Separations Performed On-Line with MC-ICP-MS for Uranium and Plutonium Isotopic Analyses  

SciTech Connect (OSTI)

The most time consuming process in uranium or plutonium isotopic analyses is performing the requisite chromatographic separation of the actinides. Filament preparation for thermal ionization (TIMS) adds further delays, but is generally accepted due to the unmatched performance in trace isotopic analyses. Advances in Multi-Collector Inductively Coupled Plasma Mass Spectrometry (MC-ICP-MS) are beginning to rival the performance of TIMS. Methods, such as Electrochemically Modulated Separations (EMS) can efficiently pre-concentrate U or Pu quite selectively from small solution volumes in a matrix of 0.5 M nitric acid. When performed in-line with ICP-MS, the rapid analyte release from the electrode is fast, and large transient analyte signal enhancements of >100 fold can be achieved as compared to more conventional continuous nebulization of the original starting solution. This makes the approach ideal for very low level isotope ratio measurements. In this paper, some aspects of EMS performance are described. These include low level Pu isotope ratio behavior versus concentration by MC-ICP-MS and uranium rejection characteristics that are also important for reliable low level Pu isotope ratio determinations.

Liezers, Martin; Olsen, Khris B.; Mitroshkov, Alexandre V.; Duckworth, Douglas C.

2010-08-11T23:59:59.000Z

16

Ultra High Mass Range Mass Spectrometer System  

DOE Patents [OSTI]

Applicant's present invention comprises mass spectrometer systems that operate in a mass range from 1 to 10.sup.16 DA. The mass spectrometer system comprising an inlet system comprising an aerodynamic lens system, a reverse jet being a gas flux generated in an annulus moving in a reverse direction and a multipole ion guide; a digital ion trap; and a thermal vaporization/ionization detector system. Applicant's present invention further comprises a quadrupole mass spectrometer system comprising an inlet system having a quadrupole mass filter and a thermal vaporization/ionization detector system. Applicant's present invention further comprises an inlet system for use with a mass spectrometer system, a method for slowing energetic particles using an inlet system. Applicant's present invention also comprises a detector device and a method for detecting high mass charged particles.

Reilly, Peter T. A. [Knoxville, TN

2005-12-06T23:59:59.000Z

17

EMSL - Mass Spectrometer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MS) with high mass resolution (m&61636;m100,000). Solvent mixtures of acetonitrilewater and acetonitriletoluene were used to extract and ionize polar and non-polar...

18

Advanced Mass Spectrometers for Hydrogen Isotope Analyses  

SciTech Connect (OSTI)

This report is a summary of the results of a joint Savannah River Laboratory (SRL) - Savannah River Plant (SRP) ''Hydrogen Isotope Mass Spectrometer Evaluation Program''. The program was undertaken to evaluate two prototype hydrogen isotope mass spectrometers and obtain sufficient data to permit SRP personnel to specify the mass spectrometers to replace obsolete instruments.

Chastagner, P.

2001-08-01T23:59:59.000Z

19

Automated mass spectrometer grows up  

SciTech Connect (OSTI)

In 1980 we reported the development of an automated mass spectrometer for large scale batches of samples enriched in nitrogen-15 as ammonium salts. Since that time significant technical progress has been made in the instrument. Perhaps more significantly, administrative and institutional changes have permitted the entire effort to be transferred to the private sector from its original base at the Los Alamos National Laboratory. This has ensured the continuance of a needed service to the international scientific community as revealed by a development project at a national laboratory, and is an excellent example of beneficial technology transfer to private industry.

McInteer, B.B.; Montoya, J.G.; Stark, E.E.

1984-01-01T23:59:59.000Z

20

Measurement of lithium isotope ratios by quadrupole-ICP-MS: application to seawater and natural carbonates  

E-Print Network [OSTI]

Measurement of lithium isotope ratios by quadrupole-ICP-MS: application to seawater and natural method for lithium isotope ratio (7 Li/6 Li) determinations with low total lithium consumption ( lithium from all matrix elements using small volume resin (2 ml/3.4 meq AG 50W-X8) and low volume elution

Weston, Ken

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Elemental fractionation during LA-ICP-MS analysis of silicate glasses: implications for matrix-independent standardization  

E-Print Network [OSTI]

Elemental fractionation during LA-ICP-MS analysis of silicate glasses: implications for matrix-element solution and from the laser ablation of a range of silicate reference materials (SRM 61X series, MPI-independent standardization of LA- ICP-MS analysis of non-transparent silicates and ceramics, then, is an accurate and viable

Weston, Ken

22

Surface Cleaning Techniques: Ultra-Trace ICP-MS Sample Preparation and Assay of HDPE  

SciTech Connect (OSTI)

The world’s most sensitive radiation detection and assay systems depend upon ultra-low background (ULB) materials to reduce unwanted radiological backgrounds. Herein, we evaluate methods to clean HDPE, a material of interest to ULB systems and the means to provide rapid assay of surface and bulk contamination. ULB level material and ultra-trace level detection of actinide elements is difficult to attain, due to the introduction of contamination from sample preparation equipment such as pipette tips, sample vials, forceps, etc. and airborne particulate. To date, literature available on the cleaning of such polymeric materials and equipment for ULB applications and ultra-trace analyses is limited. For these reasons, a study has been performed to identify an effective way to remove surface contamination from polymers in an effort to provide improved instrumental detection limits. Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) was utilized to assess the effectiveness of a variety of leachate solutions for removal of inorganic uranium and thorium surface contamination from polymers, specifically high density polyethylene (HDPE). HDPE leaching procedures were tested to optimize contaminant removal of thorium and uranium. Calibration curves for thorium and uranium ranged from 15 ppq (fg/mL) to 1 ppt (pg/mL). Detection limits were calculated at 6 ppq for uranium and 7 ppq for thorium. Results showed the most effective leaching reagent to be clean 6 M nitric acid for 72 hour exposures. Contamination levels for uranium and thorium found in the leachate solutions were significant for ultralow level radiation detection applications.

Overman, Nicole R.; Hoppe, Eric W.; Addleman, Raymond S.

2013-06-01T23:59:59.000Z

23

Gas sampling system for a mass spectrometer  

DOE Patents [OSTI]

The present invention relates generally to a gas sampling system, and specifically to a gas sampling system for transporting a hazardous process gas to a remotely located mass spectrometer. The gas sampling system includes a capillary tube having a predetermined capillary length and capillary diameter in communication with the supply of process gas and the mass spectrometer, a flexible tube surrounding and coaxial with the capillary tube intermediate the supply of process gas and the mass spectrometer, a heat transfer tube surrounding and coaxial with the capillary tube, and a heating device in communication the heat transfer tube for substantially preventing condensation of the process gas within the capillary tube.

2003-12-30T23:59:59.000Z

24

Matrix effects in inductively coupled plasma mass spectrometry  

SciTech Connect (OSTI)

The inductively coupled plasma is an electrodeless discharge in a gas (usually Ar) at atmospheric pressure. Radio frequency energy generated by a RF power source is inductively coupled to the plasma gas through a water cooled load coil. In ICP-MS the {open_quotes}Fassel{close_quotes} TAX quartz torch commonly used in emission is mounted horizontally. The sample aerosol is introduced into the central flow, where the gas kinetic temperature is about 5000 K. The aerosol is vaporized, atomized, excited and ionized in the plasma, and the ions are subsequently extracted through two metal apertures (sampler and skimmer) into the mass spectrometer. In ICP-MS, the matrix effects, or non-spectroscopic interferences, can be defined as the type of interferences caused by dissolved concomitant salt ions in the solution. Matrix effects can be divided into two categories: (1) signal drift due to the deposition of solids on the sampling apertures; and/or (2) signal suppression or enhancement by the presence of the dissolved salts. The first category is now reasonably understood. The dissolved salts, especially refractory oxides, tend to deposit on the cool tip of the sampling cone. The clogging of the orifices reduces the ion flow into the ICP-MS, lowers the pressure in the first stage of ICP-MS, and enhances the level of metal oxide ions. Because the extent of the clogging increases with the time, the signal drifts down. Even at the very early stage of the development of ICP-MS, matrix effects had been observed. Houk et al. found out that the ICP-MS was not tolerant to solutions containing significant amounts of dissolved solids.

Chen, Xiaoshan

1995-07-07T23:59:59.000Z

25

Compact hydrogen/helium isotope mass spectrometer  

DOE Patents [OSTI]

The compact hydrogen and helium isotope mass spectrometer of the present invention combines low mass-resolution ion mass spectrometry and beam-foil interaction technology to unambiguously detect and quantify deuterium (D), tritium (T), hydrogen molecule (H.sub.2, HD, D.sub.2, HT, DT, and T.sub.2), .sup.3 He, and .sup.4 He concentrations and concentration variations. The spectrometer provides real-time, high sensitivity, and high accuracy measurements. Currently, no fieldable D or molecular speciation detectors exist. Furthermore, the present spectrometer has a significant advantage over traditional T detectors: no confusion of the measurements by other beta-emitters, and complete separation of atomic and molecular species of equivalent atomic mass (e.g., HD and .sup.3 He).

Funsten, Herbert O. (Los Alamos, NM); McComas, David J. (Los Alamos, NM); Scime, Earl E. (Morgantown, WV)

1996-01-01T23:59:59.000Z

26

Development and performance of a miniature, low cost mass spectrometer  

E-Print Network [OSTI]

A miniature, low cost mass spectrometer has been developed that is capable of unit resolution over a mass range of 10 to 50 AMU. The design of the mass spectrometer incorporates several new features that enhance the ...

Hemond, Brian D. (Brian David Thomson)

2011-01-01T23:59:59.000Z

27

Studies on the content of heavy metals in Aries River using ICP-MS  

SciTech Connect (OSTI)

Among the industrial branches, the mining industry has always been an important source of environmental pollution, both aesthetically and chemically. Through this paper results of ICP-MS characterization of Aries River Basin are reported. Mining activities from this area has resulted in contamination of environment and its surrounding biota. This is clearly evidenced in analyzed water samples, especially from Baia de Aries site where increased amount of trace elements as Cr, Zn, As, Se, Cd, Pb and U were founded. Also in this site greater amount of rare earth elements was evidenced also. Through monitoring of Aries River from other non-mining area it was observed that the quantitative content of heavy metals was below the maximum permissible levels which made us to conclude that the water table wasn't seriously affected (which possibly might be attributed to the cessation of mining activities in this area from a few years ago)

Voica, Cezara, E-mail: Cezara.Voica@itim-cj.ro; Kovacs, Melinda, E-mail: Cezara.Voica@itim-cj.ro; Feher, Ioana, E-mail: Cezara.Voica@itim-cj.ro [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)

2013-11-13T23:59:59.000Z

28

Microscale ion trap mass spectrometer  

DOE Patents [OSTI]

An ion trap for mass spectrometric chemical analysis of ions is delineated. The ion trap includes a central electrode having an aperture; a pair of insulators, each having an aperture; a pair of end cap electrodes, each having an aperture; a first electronic signal source coupled to the central electrode; a second electronic signal source coupled to the end cap electrodes. The central electrode, insulators, and end cap electrodes are united in a sandwich construction where their respective apertures are coaxially aligned and symmetric about an axis to form a partially enclosed cavity having an effective radius r.sub.0 and an effective length 2z.sub.0, wherein r.sub.0 and/or z.sub.0 are less than 1.0 mm, and a ratio z.sub.0 /r.sub.0 is greater than 0.83.

Ramsey, J. Michael (Knoxville, TN); Witten, William B. (Lancing, TN); Kornienko, Oleg (Lansdale, PA)

2002-01-01T23:59:59.000Z

29

Portable gas chromatograph-mass spectrometer  

DOE Patents [OSTI]

A gas chromatograph-mass spectrometer (GC-MS) for use as a field portable organic chemical analysis instrument. The GC-MS is designed to be contained in a standard size suitcase, weighs less than 70 pounds, and requires less than 600 watts of electrical power at peak power (all systems on). The GC-MS includes: a conduction heated, forced air cooled small bore capillary gas chromatograph, a small injector assembly, a self-contained ion/sorption pump vacuum system, a hydrogen supply, a dual computer system used to control the hardware and acquire spectrum data, and operational software used to control the pumping system and the gas chromatograph. This instrument incorporates a modified commercial quadrupole mass spectrometer to achieve the instrument sensitivity and mass resolution characteristic of laboratory bench top units.

Andresen, Brian D. (Livermore, CA); Eckels, Joel D. (Livermore, CA); Kimmons, James F. (Manteca, CA); Myers, David W. (Livermore, CA)

1996-01-01T23:59:59.000Z

30

Portable gas chromatograph-mass spectrometer  

DOE Patents [OSTI]

A gas chromatograph-mass spectrometer (GC-MS) is described for use as a field portable organic chemical analysis instrument. The GC-MS is designed to be contained in a standard size suitcase, weighs less than 70 pounds, and requires less than 600 watts of electrical power at peak power (all systems on). The GC-MS includes: a conduction heated, forced air cooled small bore capillary gas chromatograph, a small injector assembly, a self-contained ion/sorption pump vacuum system, a hydrogen supply, a dual computer system used to control the hardware and acquire spectrum data, and operational software used to control the pumping system and the gas chromatograph. This instrument incorporates a modified commercial quadrupole mass spectrometer to achieve the instrument sensitivity and mass resolution characteristic of laboratory bench top units. 4 figs.

Andresen, B.D.; Eckels, J.D.; Kimmons, J.F.; Myers, D.W.

1996-06-11T23:59:59.000Z

31

Interface for liquid chromatograph-mass spectrometer  

DOE Patents [OSTI]

A moving belt interface for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer.

Andresen, Brian D. (Pleasanton, CA); Fought, Eric R. (Livermore, CA)

1989-01-01T23:59:59.000Z

32

Interface for liquid chromatograph-mass spectrometer  

DOE Patents [OSTI]

A moving belt interface is described for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer. 8 figs.

Andresen, B.D.; Fought, E.R.

1989-09-19T23:59:59.000Z

33

Expert overseer for mass spectrometer system  

DOE Patents [OSTI]

An expert overseer for the operation and real-time management of a mass spectrometer and associated laboratory equipment. The overseer is a computer-based expert diagnostic system implemented on a computer separate from the dedicated computer used to control the mass spectrometer and produce the analysis results. An interface links the overseer to components of the mass spectrometer, components of the laboratory support system, and the dedicated control computer. Periodically, the overseer polls these devices and as well as itself. These data are fed into an expert portion of the system for real-time evaluation. A knowledge base used for the evaluation includes both heuristic rules and precise operation parameters. The overseer also compares current readings to a long-term database to detect any developing trends using a combination of statistical and heuristic rules to evaluate the results. The overseer has the capability to alert lab personnel whenever questionable readings or trends are observed and provide a background review of the problem and suggest root causes and potential solutions, or appropriate additional tests that could be performed. The overseer can change the sequence or frequency of the polling to respond to an observation in the current data.

Filby, Evan E. (Idaho Falls, ID); Rankin, Richard A. (Ammon, ID)

1991-01-01T23:59:59.000Z

34

REPORT OF THE INDUCTIVELY COUPLED PLASMA -MASS SPECTROMETRY (ICP-MS)  

E-Print Network [OSTI]

Three year Full Service Contract 1 CETAC Ultrasonic Nebulization Unit (Fig. 6) 1 Consumables Package 1

35

aerosol mass spectrometer: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2004. The concentration of a species Zhang, Qi 8 Development of a thermal desorption chemical ionization mobility mass spectrometer for the speciation of ultrafine aerosols. Open...

36

Mass spectrometer vacuum housing and pumping system  

DOE Patents [OSTI]

A vacuum housing and pumping system for a portable gas chromatograph/mass spectrometer (GC/MS). The vacuum housing section of the system has minimum weight for portability while designed and constructed to utilize metal gasket sealed stainless steel to be compatible with high vacuum operation. The vacuum pumping section of the system consists of a sorption (getter) pump to remove atmospheric leakage and outgassing contaminants as well as the gas chromatograph carrier gas (hydrogen) and an ion pump to remove the argon from atmospheric leaks. The overall GC/MS system has broad application to contaminants, hazardous materials, illegal drugs, pollution monitoring, etc., as well as for use by chemical weapon treaty verification teams, due to the light weight and portability thereof.

Coutts, Gerald W. (Livermore, CA); Bushman, John F. (Oakley, CA); Alger, Terry W. (Tracy, CA)

1996-01-01T23:59:59.000Z

37

Mass spectrometer vacuum housing and pumping system  

DOE Patents [OSTI]

A vacuum housing and pumping system is described for a portable gas chromatograph/mass spectrometer (GC/MS). The vacuum housing section of the system has minimum weight for portability while designed and constructed to utilize metal gasket sealed stainless steel to be compatible with high vacuum operation. The vacuum pumping section of the system consists of a sorption (getter) pump to remove atmospheric leakage and outgassing contaminants as well as the gas chromatograph carrier gas (hydrogen) and an ion pump to remove the argon from atmospheric leaks. The overall GC/MS system has broad application to contaminants, hazardous materials, illegal drugs, pollution monitoring, etc., as well as for use by chemical weapon treaty verification teams, due to the light weight and portability thereof. 7 figs.

Coutts, G.W.; Bushman, J.F.; Alger, T.W.

1996-07-23T23:59:59.000Z

38

Open-split interface for mass spectrometers  

DOE Patents [OSTI]

An open-split interface includes a connector body having four leg members projecting therefrom within a single plane, the first and third legs being coaxial and the second and fourth legs being coaxial. A tubular aperture extends through the first and third legs and a second tubular aperture extends through the second and fourth legs, connecting at a juncture within the center of the connector body. A fifth leg projects from the connector body and has a third tubular aperture extending therethrough to the juncture of the first and second tubular apertures. A capillary column extends from a gas chromatograph into the third leg with its end adjacent the juncture. A flow restrictor tube extends from a mass spectrometer through the first tubular aperture in the first and third legs and into the capillary columnm end, so as to project beyond the end of the third leg within the capillary column. An annular gap between the tube and column allows excess effluent to pass to the juncture. A pair of short capillary columns extend from separate detectors into the second tubular aperture in the second and fourth legs, and are oriented with their ends spaced slightly from the first capillary column end. A sweep flow tube is mounted in the fifth leg so as to supply a helium sweep flow to the juncture.

Diehl, John W. (Grand Forks, ND)

1991-01-01T23:59:59.000Z

39

Mass spectrometer having a derivatized sample presentation apparatus  

DOE Patents [OSTI]

A mass spectrometer having a derivatized sample presentation apparatus is provided. The sample presentation apparatus has a complex bound to the surface of the sample presentation apparatus. This complex includes a molecule which may chemically modify a biomolecule.

Nelson, Randall W. (Phoenix, AZ)

2000-07-25T23:59:59.000Z

40

Single-ultrafine-particle mass spectrometer development and application  

E-Print Network [OSTI]

SINGLE-ULTRAFINE-PARTICLE MASS SPECTROMETER DEVELOPMENT AND APPLICATION A Thesis by STANISLAV Y. GLAGOLENKO Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 2004 Major Subject: Mechanical Engineering SINGLE-ULTRAFINE-PARTICLE MASS SPECTROMETER DEVELOPMENT AND APPLICATION A Thesis by STANISLAV Y. GLAGOLENKO Submitted to Texas A&M University in partial...

Glagolenko, Stanislav Yurievich

2004-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Quantitative 3-D Elemental Mapping by LA-ICP-MS of a Basaltic Clast from the Hanford 300 Area, Washington, USA  

E-Print Network [OSTI]

Quantitative 3-D Elemental Mapping by LA-ICP-MS of a Basaltic Clast from the Hanford 300 Area collected from the Hanford 300 Area in south-central Washington State, United States. A calibration method and riparian quality in many locations, most notably at the Hanford, Savannah River, Oak Ridge, and Nevada Test

Hu, Qinhong "Max"

42

Sample introducing apparatus and sample modules for mass spectrometer  

DOE Patents [OSTI]

An apparatus for introducing gaseous samples from a wide range of environmental matrices into a mass spectrometer for analysis of the samples is described. Several sample preparing modules including a real-time air monitoring module, a soil/liquid purge module, and a thermal desorption module are individually and rapidly attachable to the sample introducing apparatus for supplying gaseous samples to the mass spectrometer. The sample-introducing apparatus uses a capillary column for conveying the gaseous samples into the mass spectrometer and is provided with an open/split interface in communication with the capillary and a sample archiving port through which at least about 90 percent of the gaseous sample in a mixture with an inert gas that was introduced into the sample introducing apparatus is separated from a minor portion of the mixture entering the capillary discharged from the sample introducing apparatus.

Thompson, Cyril V. (Knoxville, TN); Wise, Marcus B. (Kingston, TN)

1993-01-01T23:59:59.000Z

43

Sample introducing apparatus and sample modules for mass spectrometer  

DOE Patents [OSTI]

An apparatus for introducing gaseous samples from a wide range of environmental matrices into a mass spectrometer for analysis of the samples is described. Several sample preparing modules including a real-time air monitoring module, a soil/liquid purge module, and a thermal desorption module are individually and rapidly attachable to the sample introducing apparatus for supplying gaseous samples to the mass spectrometer. The sample-introducing apparatus uses a capillary column for conveying the gaseous samples into the mass spectrometer and is provided with an open/split interface in communication with the capillary and a sample archiving port through which at least about 90 percent of the gaseous sample in a mixture with an inert gas that was introduced into the sample introducing apparatus is separated from a minor portion of the mixture entering the capillary discharged from the sample introducing apparatus. 5 figures.

Thompson, C.V.; Wise, M.B.

1993-12-21T23:59:59.000Z

44

Compact mass spectrometer for plasma discharge ion analysis  

DOE Patents [OSTI]

A mass spectrometer and methods are disclosed for mass spectrometry which are useful in characterizing a plasma. This mass spectrometer for determining type and quantity of ions present in a plasma is simple, compact, and inexpensive. It accomplishes mass analysis in a single step, rather than the usual two-step process comprised of ion extraction followed by mass filtering. Ions are captured by a measuring element placed in a plasma and accelerated by a known applied voltage. Captured ions are bent into near-circular orbits by a magnetic field such that they strike a collector, producing an electric current. Ion orbits vary with applied voltage and proton mass ratio of the ions, so that ion species may be identified. Current flow provides an indication of quantity of ions striking the collector. 7 figs.

Tuszewski, M.G.

1997-07-22T23:59:59.000Z

45

Compact mass spectrometer for plasma discharge ion analysis  

DOE Patents [OSTI]

A mass spectrometer and methods for mass spectrometry which are useful in characterizing a plasma. This mass spectrometer for determining type and quantity of ions present in a plasma is simple, compact, and inexpensive. It accomplishes mass analysis in a single step, rather than the usual two-step process comprised of ion extraction followed by mass filtering. Ions are captured by a measuring element placed in a plasma and accelerated by a known applied voltage. Captured ions are bent into near-circular orbits by a magnetic field such that they strike a collector, producing an electric current. Ion orbits vary with applied voltage and proton mass ratio of the ions, so that ion species may be identified. Current flow provides an indication of quantity of ions striking the collector.

Tuszewski, Michel G. (Los Alamos, NM)

1997-01-01T23:59:59.000Z

46

Mass Spectrometer Facility | Photosynthetic Antenna Research Center  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMapping the Nanoscale Landscape PrintSurveyMary K. Gaillard,movesMassMass

47

Micro mass spectrometer on a chip.  

SciTech Connect (OSTI)

The design, simulation, fabrication, packaging, electrical characterization and testing analysis of a microfabricated a cylindrical ion trap ({mu}CIT) array is presented. Several versions of microfabricated cylindrical ion traps were designed and fabricated. The final design of the individual trap array element consisted of two end cap electrodes, one ring electrode, and a detector plate, fabricated in seven tungsten metal layers by molding tungsten around silicon dioxide (SiO{sub 2}) features. Each layer of tungsten is then polished back in damascene fashion. The SiO{sub 2} was removed using a standard release processes to realize a free-hung structure. Five different sized traps were fabricated with inner radii of 1, 1.5, 2, 5 and 10 {micro}m and heights ranging from 3-24 {micro}m. Simulations examined the effects of ion and neutral temperature, the pressure and nature of cooling gas, ion mass, trap voltage and frequency, space-charge, fabrication defects, and other parameters on the ability of micrometer-sized traps to store ions. The electrical characteristics of the ion trap arrays were determined. The capacitance was 2-500 pF for the various sized traps and arrays. The resistance was in the order of 1-2 {Omega}. The inductance of the arrays was calculated to be 10-1500 pH, depending on the trap and array sizes. The ion traps' field emission characteristics were assessed. It was determined that the traps could be operated up to 125 V while maintaining field emission currents below 1 x 10{sup -15} A. The testing focused on using the 5-{micro}m CITs to trap toluene (C{sub 7}H{sub 8}). Ion ejection from the traps was induced by termination of the RF voltage applied to the ring electrode and current measured on the collector electrode suggested trapping of ions in 1-10% of the traps. Improvements to the to the design of the traps were defined to minimize voltage drop to the substrate, thereby increasing trapping voltage applied to the ring electrode, and to allow for electron injection into, ion ejection from, and optical access to the trapping region.

Cruz, Dolores Y.; Blain, Matthew Glenn; Fleming, James Grant

2005-11-01T23:59:59.000Z

48

Mass Spectrometer: Time of Flight Secondary Ion (ToF SIMS) -...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

- 1997 Mass Spectrometer: Time of Flight Secondary Ion (ToF SIMS) - 1997 The Physical Electronics Instruments (PHI) Model T2100 time-of-flight secondary ion mass spectrometer...

49

Linear electric field time-of-flight ion mass spectrometer  

DOE Patents [OSTI]

A linear electric field ion mass spectrometer having an evacuated enclosure with means for generating a linear electric field located in the evacuated enclosure and means for injecting a sample material into the linear electric field. A source of pulsed ionizing radiation injects ionizing radiation into the linear electric field to ionize atoms or molecules of the sample material, and timing means determine the time elapsed between ionization of atoms or molecules and arrival of an ion out of the ionized atoms or molecules at a predetermined position.

Funsten, Herbert O. (Los Alamos, NM); Feldman, William C. (Los Alamos, NM)

2008-06-10T23:59:59.000Z

50

Continuous time-of-flight ion mass spectrometer  

DOE Patents [OSTI]

A continuous time-of-flight mass spectrometer having an evacuated enclosure with means for generating an electric field located in the evacuated enclosure and means for injecting a sample material into the electric field. A source of continuous ionizing radiation injects ionizing radiation into the electric field to ionize atoms or molecules of the sample material, and timing means determine the time elapsed between arrival of a secondary electron out of said ionized atoms or molecules at a first predetermined location and arrival of a sample ion out of said ionized atoms or molecules at a second predetermined location.

Funsten, Herbert O.; Feldman, William C.

2004-10-19T23:59:59.000Z

51

Miniature quadrupole mass spectrometer having a cold cathode ionization source  

DOE Patents [OSTI]

An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

Felter, Thomas E. (Livermore, CA)

2002-01-01T23:59:59.000Z

52

Mass measurements near the $r$-process path using the Canadian Penning Trap mass spectrometer  

E-Print Network [OSTI]

The masses of 40 neutron-rich nuclides from Z = 51 to 64 were measured at an average precision of $\\delta m/m= 10^{-7}$ using the Canadian Penning Trap mass spectrometer at Argonne National Laboratory. The measurements, of fission fragments from a $^{252}$Cf spontaneous fission source in a helium gas catcher, approach the predicted path of the astrophysical $r$ process. Where overlap exists, this data set is largely consistent with previous measurements from Penning traps, storage rings, and reaction energetics, but large systematic deviations are apparent in $\\beta$-endpoint measurements. Differences in mass excess from the 2003 Atomic Mass Evaluation of up to 400 keV are seen, as well as systematic disagreement with various mass models.

J. Van Schelt; D. Lascar; G. Savard; J. A. Clark; S. Caldwell; A. Chaudhuri; J. Fallis; J. P. Greene; A. F. Levand; G. Li; K. S. Sharma; M. G. Sternberg; T. Sun; B. J. Zabransky

2012-04-09T23:59:59.000Z

53

SIEMENS ADVANCED QUANTRA FTICR MASS SPECTROMETER FOR ULTRA HIGH RESOLUTION AT LOW MASS  

SciTech Connect (OSTI)

The Siemens Advanced Quantra Fourier Transform Ion Cyclotron Resonance (FTICR) mass spectrometer was evaluated as an alternative instrument to large double focusing mass spectrometers for gas analysis. High resolution mass spectrometers capable of resolving the common mass isomers of the hydrogen isotopes are used to provide data for accurate loading of reservoirs and to monitor separation of tritium, deuterium, and helium. Conventional double focusing magnetic sector instruments have a resolution that is limited to about 5000. The Siemens FTICR instrument achieves resolution beyond 400,000 and could possibly resolve the tritium ion from the helium-3 ion, which differ by the weight of an electron, 0.00549 amu. Working with Y-12 and LANL, SRNL requested Siemens to modify their commercial Quantra system for low mass analysis. To achieve the required performance, Siemens had to increase the available waveform operating frequency from 5 MHz to 40 MHz and completely redesign the control electronics and software. However, they were able to use the previous ion trap, magnet, passive pump, and piezo-electric pulsed inlet valve design. NNSA invested $1M in this project and acquired four systems, two for Y-12 and one each for SRNL and LANL. Siemens claimed a $10M investment in the Quantra systems. The new Siemens Advanced Quantra demonstrated phenomenal resolution in the low mass range. Resolution greater than 400,000 was achieved for mass 2. The new spectrometer had a useful working mass range to 500 Daltons. However, experiments found that a continuous single scan from low mass to high was not possible. Two useful working ranges were established covering masses 1 to 6 and masses 12 to 500 for our studies. A compromise performance condition enabled masses 1 to 45 to be surveyed. The instrument was found to have a dynamic range of about three orders of magnitude and quantitative analysis is expected to be limited to around 5 percent without using complex fitting algorithms. Analysis of low concentration ions, at the ppm level, required a separate analysis using ion ejection techniques. Chemical ionization due to the formation of the MH{sup +} ion or MD{sup +} increased the complexity of the spectra compared to magnetic sector mass spectra and formation of the protonated or deuterated complex was a dynamic function of the trap ion concentration. This made quantitative measurement more of a challenge. However, the resolution of the instrument was far superior to any other mass spectrometry technique that has been applied to the analysis of the hydrogen isotopes. The piezo-electric picoliter injection device offers a new way of submitting small quantities of atmospheric pressure sample gas for analysis. The new software had many improvements over the previous version but significant flaws in the beta codes remain that make the prototype units less than ideal. The instrument is a promising new technology that experience will likely improve. Unfortunately, Siemens has concluded that the technology will not be a commercial success and has decided to stop producing this product.

Spencer, W; Laura Tovo, L

2008-07-08T23:59:59.000Z

54

Novel endothermic and exothermic ion-molecule reactions as observed in a Fourier transform mass spectrometer  

E-Print Network [OSTI]

NOVEL ENDOTHERMIC AND EXOTHERMIC ION-MOLECULE REACTIONS AS OBSERVED IN A FOURIER TRANSFORM MASS SPECTROMETER Thesis by DONALD LEE BRICKER II Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE AUGUST 1986 Major Subject: Chemistry NOVEL ENDOTHERMIC AND EXOTHERMIC ION-MOLECULE REACTIONS AS OBSERVED IN A FOURIER TRANSFORM MASS SPECTROMETER A Thesis by Donald Lee Bricker II Approved as to style and content by...

Bricker, Donald Lee

1986-01-01T23:59:59.000Z

55

ICP-MS (Quadrupole) | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

371-6375 wietsma@pnnl.gov Publications Deposition of Platinum Nanoparticles on Carbon Nanotubes by Supercritical Fluid Method. Carbon nanotube-supported platinum nanoparticles with...

56

Fundamental and methodological investigations for the improvement of elemental analysis by inductively coupled plasma mass soectrometry  

SciTech Connect (OSTI)

This dissertation describes a variety of studies meant to improve the analytical performance of inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation (LA) ICP-MS. The emission behavior of individual droplets and LA generated particles in an ICP is studied using a high-speed, high frame rate digital camera. Phenomena are observed during the ablation of silicate glass that would cause elemental fractionation during analysis by ICP-MS. Preliminary work for ICP torch developments specifically tailored for the improvement of LA sample introduction are presented. An abnormal scarcity of metal-argon polyatomic ions (MAr{sup +}) is observed during ICP-MS analysis. Evidence shows that MAr{sup +} ions are dissociated by collisions with background gas in a shockwave near the tip of the skimmer cone. Method development towards the improvement of LA-ICP-MS for environmental monitoring is described. A method is developed to trap small particles in a collodion matrix and analyze each particle individually by LA-ICP-MS.

Ebert, Christopher Hysjulien [Ames Laboratory

2012-07-27T23:59:59.000Z

57

Laser ablation-inductively coupled plasma-mass spectrometry: Examinations of the origins of polyatomic ions and advances in the sampling of particulates  

SciTech Connect (OSTI)

This dissertation provides a general introduction to Inductively coupled plasma-mass spectrometry (ICP-MS) and laser ablation (LA) sampling, with an examination of analytical challenges in the employment of this technique. It discusses the origin of metal oxide ions (MO+) in LA-ICP-MS, as well as the effect of introducing helium and nitrogen to the aerosol gas flow on the formation of these polyatomic interferences. It extends the study of polyatomic ions in LA-ICP-MS to metal argide (MAr+) species, an additional source of possible significant interferences in the spectrum. It describes the application of fs-LA-ICP-MS to the determination of uranium isotope ratios in particulate samples.

Witte, Travis

2011-11-30T23:59:59.000Z

58

Exploring the in vitro formation of trimethylarsine sulfide from dimethylthioarsinic acid in anaerobic microflora of mouse cecum using HPLC-ICP-MS and HPLC-ESI-MS  

SciTech Connect (OSTI)

Although metabolism of arsenicals to form methylated oxoarsenical species has been extensively studied, less is known about the formation of thiolated arsenical species that have recently been detected as urinary metabolites. Indeed, their presence suggests that the metabolism of ingested arsenic is more complex than previously thought. Recent reports have shown that thiolated arsenicals can be produced by the anaerobic microflora of the mouse cecum, suggesting that metabolism prior to systemic absorption may be a significant determinant of the pattern and extent of exposure to various arsenic-containing species. Here, we examined the metabolism of {sup 34}S labeled dimethylthioarsinic acid ({sup 34}S-DMTA{sup V}) by the anaerobic microflora of the mouse cecum using HPLC-ICP-MS and HPLC-ESI-MS/MS to monitor for the presence of various oxo- and thioarsenicals. The use of isotopically enriched {sup 34}S-DMTA{sup V} made it possible to differentiate among potential metabolic pathways for production of the trimethylarsine sulfide (TMAS{sup V}). Upon in vitro incubation in an assay containing anaerobic microflora of mouse cecum, {sup 34}S-DMTA{sup V} underwent several transformations. Labile {sup 34}S was exchanged with more abundant {sup 32}S to produce {sup 32}S-DMTA{sup V}, a thiol group was added to yield DMDTA{sup V}, and a methyl group was added to yield {sup 34}S-TMAS{sup V}. Because incubation of {sup 34}S-DMTA{sup V} resulted in the formation of {sup 34}S-TMAS{sup V}, the pathway for its formation must preserve the arsenic-sulfur bond. The alternative metabolic pathway postulated for formation of TMAS{sup V} from dimethylarsinic acid (DMA{sup V}) would proceed via a dimethylarsinous acid (DMA{sup III}) intermediate and would necessitate the loss of {sup 34}S label. Structural confirmation of the metabolic product was achieved using HPLC-ESI-MS/MS. The data presented support the direct methylation of DMTA{sup V} to TMAS{sup V}. Additionally, the detection of isotopically pure {sup 34}S-TMAS{sup V} raises questions about the sulfur exchange properties of TMAS{sup V} in the cecum material. Therefore, {sup 34}S-TMAS{sup V} was incubated and the exchange was monitored with respect to time. The data suggest that the As-S bond associated with TMAS{sup V} is less labile than the As-S bond associated with DMTA{sup V}.

Kubachka, Kevin M. [US EPA, ORD, NERL, Microbiological and Chemical Exposure, Assessment Research Division, Cincinnati, OH 45268 (United States); Kohan, Michael C. [US EPA, ORD, NHEERL, Environmental Carcinogenesis Division, Research Triangle Park, NC 27711 (United States); Herbin-Davis, Karen [US EPA, ORD, NHEERL, Experimental Toxicology Division, Research Triangle Park, NC 27711 (United States); Creed, John T. [US EPA, ORD, NERL, Microbiological and Chemical Exposure, Assessment Research Division, Cincinnati, OH 45268 (United States)], E-mail: creed.jack@epa.gov; Thomas, David J. [US EPA, ORD, NHEERL, Experimental Toxicology Division, Research Triangle Park, NC 27711 (United States)

2009-09-01T23:59:59.000Z

59

Design and evaluation of a miniaturized Particle Desorption Mass Spectrometer  

E-Print Network [OSTI]

of the incident particles, the age of the detector, and the mass, polarity, and energy of the desorbed ions (25). The efficiency was estimated from a published efficiency curve which allowed for a diversity of conditions (25). From this curve the efficiency... to determine the flux of primary ions impacting the sample surface. In the configuration adopted for this experiment, the count rate of the start detector is somewhat ambiguously related to the primary ion flux since a fission fragment pair coming from...

Davis, Kelly Vaughn

1987-01-01T23:59:59.000Z

60

Chemical Reaction of Metal-Carbon Binary Cluster Anions by FT-ICR Mass Spectrometer  

E-Print Network [OSTI]

45 48 51 54 57 60 Number of Carbon Atoms Intensity(arbitrary) (a) as injected (b) SWIFTed (c) NO 1sChemical Reaction of Metal-Carbon Binary Cluster Anions by FT-ICR Mass Spectrometer S. Maruyama, M- fullerene and single walled carbon nanotubes are investigated through experimental studies of interaction

Maruyama, Shigeo

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

HD gas analysis with Gas Chromatography and Quadrupole Mass Spectrometer  

E-Print Network [OSTI]

A gas analyzer system has been developed to analyze Hydrogen-Deuteride (HD) gas for producing frozen-spin polarized HD targets, which are used for hadron photoproduction experiments at SPring-8. Small amounts of ortho-H$_{2}$ and para-D$_{2}$ gas mixtures ($\\sim$0.01%) in the purified HD gas are a key to realize a frozen-spin polarized target. In order to obtain reliable concentrations of these gas mixtures in the HD gas, we produced a new gas analyzer system combining two independent measurements with the gas chromatography and the QMS. The para-H$_{2}$, ortho-H$_{2}$, HD, and D$_{2}$ are separated using the retention time of the gas chromatography and the mass/charge. It is found that the new gas analyzer system can measure small concentrations of $\\sim$0.01% for the otho-H$_2$ and D$_2$ with good S/N ratios.

T. Ohta; S. Bouchigny; J. -P. Didelez; M. Fujiwara; K. Fukuda; H. Kohri; T. Kunimatsu; C. Morisaki; S. Ono; G. Rouille; M. Tanaka; K. Ueda; M. Uraki; M. Utsuro; S. Y. Wang; M. Yosoi

2011-01-28T23:59:59.000Z

62

High mass resolution time of flight mass spectrometer for measuring products in heterogeneous catalysis in highly sensitive microreactors  

SciTech Connect (OSTI)

We demonstrate a combined microreactor and time of flight system for testing and characterization of heterogeneous catalysts with high resolution mass spectrometry and high sensitivity. Catalyst testing is performed in silicon-based microreactors which have high sensitivity and fast thermal response. Gas analysis is performed with a time of flight mass spectrometer with a modified nude Bayard-Alpert ionization gauge as gas ionization source. The mass resolution of the time of flight mass spectrometer using the ion gauge as ionization source is estimated to m/{Delta}m > 2500. The system design is superior to conventional batch and flow reactors with accompanying product detection by quadrupole mass spectrometry or gas chromatography not only due to the high sensitivity, fast temperature response, high mass resolution, and fast acquisition time of mass spectra but it also allows wide mass range (0-5000 amu in the current configuration). As a demonstration of the system performance we present data from ammonia oxidation on a Pt thin film showing resolved spectra of OH and NH{sub 3}.

Andersen, T.; Jensen, R.; Christensen, M. K.; Chorkendorff, I. [Department of Physics, Danish National Research Foundation's Center for Individual Nanoparticle Functionality (CINF), Technical University of Denmark, Building 312, DK-2800 Kgs. Lyngby (Denmark); Pedersen, T.; Hansen, O. [Department of Micro- and Nanotechnology, Technical University of Denmark, DTU Nanotech Building 345 East, DK-2800 Kgs. Lyngby (Denmark)

2012-07-15T23:59:59.000Z

63

Elimination of ``memory`` from sample handling and inlet system of a mass spectrometer  

DOE Patents [OSTI]

This paper describes a method for preparing the sample handling and inlet system of a mass spectrometer for analysis of a subsequent sample following analysis of a previous sample comprising the flushing of the system interior with supercritical CO{sub 2} and venting the interior. The method eliminates the effect of system ``memory`` on the subsequent analysis, especially following persistent samples such as xenon and krypton.

Chastgner, P.

1991-05-08T23:59:59.000Z

64

Advanced Mass Calibration and Visualization for FT-ICR Mass Spectromet...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for FT-ICR Mass Spectrometry Imaging. Abstract: Mass spectrometry imaging by Fourier transform ion cyclotron resonance (FT-ICR) yields hundreds of unique peaks, many of which...

65

Characterization of an aerodynamic lens for transmitting particles greater than 1 micrometer in diameter into the Aerodyne aerosol mass spectrometer  

E-Print Network [OSTI]

We have designed and characterized a new inlet and aerodynamic lens for the Aerodyne aerosol mass spectrometer (AMS) that transmits particles between 80 nm and more than 3 ?m in vacuum aerodynamic diameter. The design of ...

Williams, L. R.

66

Method for studying a sample of material using a heavy ion induced mass spectrometer source  

DOE Patents [OSTI]

A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu.

Fries, David P. (St. Petersburg, FL); Browning, James F. (Palm Harbour, FL)

1999-01-01T23:59:59.000Z

67

A Novel 9.4 Tesla FT-ICR Mass Spectrometer with Improved Sensitivity, Mass Resolution, and Mass Range, for Petroleum Heavy Crude Oil Analysis  

E-Print Network [OSTI]

organic mixtures. However, analysis of petroleum crude oil as well as upcoming biofuels requires continued NHMFL 9.4 T FT- species in petroleum crude oil and its products, extending to "heavy" crudes.4 tesla widebore FT-ICR mass spectrometer. Acknowledgements : Include all grant info; e.g. G.S. Boebinger

68

Fundamental studies of the plasma extraction and ion beam formation processes in inductively coupled plasma mass spectrometry  

SciTech Connect (OSTI)

The fundamental and practical aspects are described for extracting ions from atmospheric pressure plasma sources into an analytical mass spectrometer. Methodologies and basic concepts of inductively coupled plasma mass spectrometry (ICP-MS) are emphasized in the discussion, including ion source, sampling interface, supersonic expansion, slumming process, ion optics and beam focusing, and vacuum considerations. Some new developments and innovative designs are introduced. The plasma extraction process in ICP-MS was investigated by Langmuir measurements in the region between the skimmer and first ion lens. Electron temperature (T{sub e}) is in the range 2000--11000 K and changes with probe position inside an aerosol gas flow. Electron density (n{sub e}) is in the range 10{sup 8}--10{sup 10} {sup {minus}cm }at the skimmer tip and drops abruptly to 10{sup 6}--10{sup 8} cm{sup {minus}3} near the skimmer tip and drops abruptly to 10{sup 6}--10{sup 8} cm{sup {minus}3} downstream further behind the skimmer. Electron density in the beam leaving the skimmer also depends on water loading and on the presence and mass of matrix elements. Axially resolved distributions of electron number-density and electron temperature were obtained to characterize the ion beam at a variety of plasma operating conditions. The electron density dropped by a factor of 101 along the centerline between the sampler and skimmer cones in the first stage and continued to drop by factors of 10{sup 4}--10{sup 5} downstream of skimmer to the entrance of ion lens. The electron density in the beam expansion behind sampler cone exhibited a 1/z{sup 2} intensity fall-off (z is the axial position). An second beam expansion originated from the skimmer entrance, and the beam flow underwent with another 1/z{sup 2} fall-off behind the skimmer. Skimmer interactions play an important role in plasma extraction in the ICP-MS instrument.

Niu, Hongsen

1995-02-10T23:59:59.000Z

69

A new method of alpha ray measurement using a Quadrupole Mass Spectrometer  

E-Print Network [OSTI]

We propose a new method of alpha($\\alpha$)-ray measurement that detects helium atoms with a Quadrupole Mass Spectrometer(QMS). A demonstration is undertaken with a plastic-covered $^{241}$Am $\\alpha$-emitting source to detect $\\alpha$-rays stopped in the capsule. We successfully detect helium atoms that diffuse out of the capsule by accumulating them for one to 20 hours in a closed chamber. The detected amount is found to be proportional to the accumulation time. Our method is applicable to probe $\\alpha$-emitting radioactivity in bulk material.

Y. Iwata; Y. Inoue; M. Minowa

2007-04-16T23:59:59.000Z

70

Mass spectrometer with electron source for reducing space charge effects in sample beam  

DOE Patents [OSTI]

A mass spectrometer includes an ion source which generates a beam including positive ions, a sampling interface which extracts a portion of the beam from the ion source to form a sample beam that travels along a path and has an excess of positive ions over at least part of the path, thereby causing space charge effects to occur in the sample beam due to the excess of positive ions in the sample beam, an electron source which adds electrons to the sample beam to reduce space charge repulsion between the positive ions in the sample beam, thereby reducing the space charge effects in the sample beam and producing a sample beam having reduced space charge effects, and a mass analyzer which analyzes the sample beam having reduced space charge effects.

Houk, Robert S.; Praphairaksit, Narong

2003-10-14T23:59:59.000Z

71

An Improvement on Space Focusing Resolution in Two-Field Time-of-Flight Mass Spectrometers  

SciTech Connect (OSTI)

Time-of-Flight Mass Spectrometer (TOFMS) is a sophisticated device for the mass selective analysis of a variety of samples. The main limitation on TOFMS technique is the obtainable resolution where the two main limiting factors are the initial space and energy spread of particles created in ionization region. Similar charged particles starting at different points will reach the detector at different times. So, this problem makes space focusing is very important subject. We have presented principles of two-fields TOFMS with second-order space focusing both using analytical methods and ray-tracing simulation. This work aims understanding of ion optical system clearly and gives hint of expectation for future developments.

Yildirim, M.; Aydin, R.; Akin, U.; Kilic, H. S. [Selcuk University, Dept. of Physics, Konya (Turkey); Sise, O.; Ulu, M.; Dogan, M. [Afyon Kocatepe University, Dept. of Physics, 03200 Afyonkarahisar (Turkey)

2007-04-23T23:59:59.000Z

72

Manifold and method of batch measurement of Hg-196 concentration using a mass spectrometer  

DOE Patents [OSTI]

A sample manifold and method of its use has been developed so that milligram quantities of mercury can be analyzed mass spectroscopically to determine the .sup.196 Hg concentration to less than 0.02 atomic percent. Using natural mercury as a standard, accuracy of .+-.0.002 atomic percent can be obtained. The mass spectrometer preferably used is a commercially available GC/MS manufactured by Hewlett Packard. A novel sample manifold is contained within an oven allowing flow rate control of Hg into the MS. Another part of the manifold connects to an auxiliary pumping system which facilitates rapid clean up of residual Hg in the manifold. Sample cycle time is about 1 hour.

Grossman, Mark W. (Belmont, MA); Evans, Roger (N. Hampton, NH)

1991-01-01T23:59:59.000Z

73

Manifold and method of batch measurement of Hg-196 concentration using a mass spectrometer  

DOE Patents [OSTI]

A sample manifold and method of its use has been developed so that milligram quantities of mercury can be analyzed mass spectroscopically to determine the [sup 196]Hg concentration to less than 0.02 atomic percent. Using natural mercury as a standard, accuracy of [+-]0.002 atomic percent can be obtained. The mass spectrometer preferably used is a commercially available GC/MS manufactured by Hewlett Packard. A novel sample manifold is contained within an oven allowing flow rate control of Hg into the MS. Another part of the manifold connects to an auxiliary pumping system which facilitates rapid clean up of residual Hg in the manifold. Sample cycle time is about 1 hour. 8 figures.

Grossman, M.W.; Evans, R.

1991-11-26T23:59:59.000Z

74

Measurement of low radioactivity background in a high voltage cable by high resolution inductively coupled plasma mass spectrometry  

SciTech Connect (OSTI)

The measurement of naturally occurring low level radioactivity background in a high voltage (HV) cable by high resolution inductively coupled plasma mass spectrometry (HR ICP MS) is presented in this work. The measurements were performed at the Chemistry Service of the Gran Sasso National Laboratory. The contributions to the radioactive background coming from the different components of the heterogeneous material were separated. Based on the mass fraction of the cable, the whole contamination was calculated. The HR ICP MS results were cross-checked by gamma ray spectroscopy analysis that was performed at the low background facility STELLA (Sub Terranean Low Level Assay) of the LNGS underground lab using HPGe detectors.

Vacri, M. L. di; Nisi, S.; Balata, M. [Gran Sasso National Laboratory, Chemistry Service, SS 17bis km 18.910, 67100 Assergi (Aq) (Italy)] [Gran Sasso National Laboratory, Chemistry Service, SS 17bis km 18.910, 67100 Assergi (Aq) (Italy)

2013-08-08T23:59:59.000Z

75

Invited Article: Characterization of background sources in space-based time-of-flight mass spectrometers  

SciTech Connect (OSTI)

For instruments that use time-of-flight techniques to measure space plasma, there are common sources of background signals that evidence themselves in the data. The background from these sources may increase the complexity of data analysis and reduce the signal-to-noise response of the instrument, thereby diminishing the science value or usefulness of the data. This paper reviews several sources of background commonly found in time-of-flight mass spectrometers and illustrates their effect in actual data using examples from ACE-SWICS and MESSENGER-FIPS. Sources include penetrating particles and radiation, UV photons, energy straggling and angular scattering, electron stimulated desorption of ions, ion-induced electron emission, accidental coincidence events, and noise signatures from instrument electronics. Data signatures of these sources are shown, as well as mitigation strategies and design considerations for future instruments.

Gilbert, J. A.; Gershman, D. J.; Gloeckler, G.; Lundgren, R. A.; Zurbuchen, T. H. [Department of Atmospheric, Oceanic and Space Sciences, University of Michigan, 2455 Hayward St, Ann Arbor, Michigan 48109 (United States); Orlando, T. M.; McLain, J. [Georgia Institute of Technology, 225 North Ave NW, Atlanta, Georgia 30332 (United States); Steiger, R. von [International Space Science Institute, Hallerstrasse 6, CH-3012 Bern, Switzerland and Physikalisches Institut, Universität Bern, Sidlerstrasse 5, CH-3012 Bern (Switzerland)

2014-09-15T23:59:59.000Z

76

A Design for a Compact Time-of-Flight Mass Spectrometer  

SciTech Connect (OSTI)

The design of a prototype, compact time-of-flight (TOF) mass spectrometer (MS) is described. The system primarily consists of an ion acceleration/focusing/steering assembly (AFSA), an 8 cm field-free region, a 4 cm, dual-stage reflectron and a miniature microchannel plate detector. Consequently, the resulting flight length of the system is 12 cm. The system has been designed with the capability to sample directly from atmosphere at ambient pressures. This is accomplished through the use of an electrodynamic ion funnel, housed in an intermediate-vacuum chamber that is coupled to the inlet of the TOF chamber. TOF spectra were obtained using noble gases (Ar, Kr and Xe) as test chemicals. These measured flight times were used to probe the performance of the instrument. A temporal resolution (tflight/?t) of approximately 125, acquired using 129Xe+, has been measured for the system.

Manard, M.

2012-10-01T23:59:59.000Z

77

Multi-Collector Inductively Coupled Plasma Mass Spectrometer – Operational Performance Report  

SciTech Connect (OSTI)

The INL made an assessment of the commercially available inductively coupled plasma mass spectrometers (ICPMS) for actinide analysis; emphasizing low detection limits for plutonium. INL scientists subsequently determined if plutonium was present on a swipe, at a 10 million atom decision level. This report describes the evaluation of ICPMS instruments and the operational testing of a new process for the dissolution, separation and analysis via ICPMS of swipes for plutonium and uranium. The swipe dissolution, plutonium and uranium isolation, separation and purification are wet chemistry methods following established procedures. The ICPMS is a commercially available multi-collector magnetic sector mass spectrometer that utilizes five ion counting detectors operating simultaneously. The instrument includes a sample introduction system allowing for sample volumes of < 1 mL to be reproducibly injected into the instrument with minimal waste of the sample solution, while maximizing the useable signal. The performance of the instrument was measured using SRM 996 (244Pu spike) at concentrations of 12 parts per quadrillion (ppq, fg/mL) and with SRM 4350B Columbia River Sediment samples spiked onto swipes at the 10 million atom level. The measured limit of detection (LOD, defined as 3s) for 239Pu is 310,000 atoms based upon the instrument blank data. The limit of quantification (LOQ defined as 10 s) for 239Pu is 105,000 atoms. The measured limit of detection for 239Pu from the SRM 4350B spiked onto a swipe was 2.7 million atoms with the limit of quantification being 9.0 million atoms.

Matthew Watrous; Anthony Appelhans; Robert Hague; John Olson; Tracy Houghton

2013-06-01T23:59:59.000Z

78

A convenient approach to $10^{-12}~g/g$ ICP-MS limits for Th and U in Aurubis electrolytic NA-ESN brand copper  

E-Print Network [OSTI]

Inductively coupled plasma mass spectroscopy is a powerful technique for measuring trace levels of radioactive contaminants, specifically Th and U, in materials for use in construction of low-background rare-event detectors such as double beta decay and dark matter detectors. I describe here a technique for measuring Th and U contamination in copper using direct acid digestion and dilution, without further chemical processing, achieving results comparable to previous work which utilized more complex chemical pre-concentration techniques. A convenient research-oriented analysis environment is described as well. Results are presented for measurements of three samples from the production line of electrolytically-purified, LME (London Metal Exchange) grade A, NA-ESN Aurubis copper. Purified samples showed levels consistent with zero contamination for both elements, while weak but inconclusive indications of contamination were present for the un-purified anode copper. The best limits achieved are near $1\\cdot 10^{-12}$~g/g (95% CL) for both Th and U measured for copper from the cathode of the purification process.

D. S. Leonard

2014-03-20T23:59:59.000Z

79

Atmospheric pressure flow reactor / aerosol mass spectrometer studies of tropospheric aerosol nucleat and growth kinetics. Final report, June, 2001  

SciTech Connect (OSTI)

The objective of this program was to determine the mechanisms and rates of growth and transformation and growth processes that control secondary aerosol particles in both the clear and polluted troposphere. The experimental plan coupled an aerosol mass spectrometer (AMS) with a chemical ionization mass spectrometer to provide simultaneous measurement of condensed and particle phases. The first task investigated the kinetics of tropospheric particle growth and transformation by measuring vapor accretion to particles (uptake coefficients, including mass accommodation coefficients and heterogeneous reaction rate coefficients). Other work initiated investigation of aerosol nucleation processes by monitoring the appearance of submicron particles with the AMS as a function of precursor gas concentrations. Three projects were investigated during the program: (1) Ozonolysis of oleic acid aerosols as model of chemical reactivity of secondary organic aerosol; (2) Activation of soot particles by measurement deliquescence in the presence of sulfuric acid and water vapor; (3) Controlled nucleation and growth of sulfuric acid aerosols.

Worsnop, Douglas R.

2001-06-01T23:59:59.000Z

80

Development of Soft Ionization for Particulate Organic Detection with the Aerodyne Aerosol Mass Spectrometer  

SciTech Connect (OSTI)

During this DOE SBIR Phase II project, we have successfully developed several soft ionization techniques, i.e., ionization schemes which involve less fragmentation of the ions, for use with the Aerodyne time-of-flight aerosol mass spectrometer (ToF-AMS). Vacuum ultraviolet single photon ionization was demonstrated in the laboratory and deployed in field campaigns. Vacuum ultraviolet single photon ionization allows better identification of organic species in aerosol particles as shown in laboratory experiments on single component particles, and in field measurements on complex multi-component particles. Dissociative electron attachment with lower energy electrons (less than 30 eV) was demonstrated in the measurement of particulate organics in chamber experiments in Switzerland, and is now a routine approach with AMS systems configured for bipolar, negative ion detection. This technique is particularly powerful for detection of acidic and other highly oxygenated secondary organic aerosol (SOA) chemical functionality. Low energy electron ionization (10 to 12 eV) is also a softer ionization approach routinely available to AMS users. Finally, Lithium ion attachment has been shown to be sensitive to more alkyl-like chemical functionality in SOA. Results from Mexico City are particularly exciting in observing changes in SOA molecular composition under different photochemical/meteorological conditions. More recent results detecting biomass burns at the Montana fire lab have demonstrated quantitative and selective detection of levoglucosan. These soft ionization techniques provide the ToF-AMS with better capability for identifying organic species in ambient atmospheric aerosol particles. This, in turn, will allow more detailed study of the sources, transformations and fate of organic-containing aerosol.

Trimborn, A; Williams, L R; Jayne, J T; Worsnop, D R

2008-06-19T23:59:59.000Z

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81

Atmospheric Amines and Ammonia Measured with a Chemical Ionization Mass Spectrometer (CIMS)  

SciTech Connect (OSTI)

We report ambient measurements of amines and ammonia with a fast response chemical ionization mass spectrometer (CIMS) in a Southeastern U.S. forest in Alabama and a moderately polluted Midwestern site during the summer. In the Alabama forest, mostly C3-amines (from pptv to tens of pptv) and ammonia (up to 2 ppbv) were detected on a daily basis. C3-amines and ammonia showed similar diurnal trends and temperature and wind direction dependences, and were not associated with transported CO and SO2 plumes. Consistent with temperature dependences, amine and ammonia in the gas and aerosol phases showed opposite diurnal trends, indicating gas-to-particle partitioning of amines and ammonia. Temperature dependences also imply reversible processes of amines and ammonia evaporation from soil surfaces in daytime and deposition of amines and ammonia to soil surfaces at nighttime. Various amines (C1-C6) at the pptv level were observed in the transported biomass burning plumes, showing that biomass burning can be a substantial source of amines in the Southeast U.S. At the moderately polluted Kent site, higher concentrations of amines (C1-C6, from pptv to tens of pptv) and ammonia (up to 6 ppbv) were detected. Diurnal variations of C1- to C3-amines and ammonia were correlated with the ambient temperature. C4- to C6-amines showed abrupt increases during the nighttime, suggesting that they were emitted from local sources. These abundant amines and ammonia may in part explain the frequent new particle formation events reported from Kent. Lower amine concentrations at the rural forested site highlight the importance of constraining anthropogenic sources of amines.

You, Y.; Kanawade, V. P.; de Gouw, J. A.; Guenther, Alex B.; Madronich, Sasha; Sierra-Hernandez, M. R.; Lawler, M.; Smith, James N.; Takahama, S.; Ruggeri, G.; Koss, A.; Olson, K.; Baumann, K.; Weber, R. J.; Nenes, A.; Guo, H.; Edgerton, Eric S.; Porcelli, L.; Brune, W. H.; Goldstein, Allen H.; Lee, S.-H

2014-11-19T23:59:59.000Z

82

Facilities: NHMFL 14.5 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation: A Pseudoatomic Model of the COPII Cage Obtained from Cryo-Electron Microscopy and Mass Spectrometry,  

E-Print Network [OSTI]

Facilities: NHMFL 14.5 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation ultrahigh-resolution 14.5 tesla Fourier transform ion cyclotron resonance mass spectrometry. The Mag

Weston, Ken

83

DETERMINATION OF 237NP AND PU ISOTOPES IN LARGE SOIL SAMPLES BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY  

SciTech Connect (OSTI)

A new method for the determination of {sup 237}Np and Pu isotopes in large soil samples has been developed that provides enhanced uranium removal to facilitate assay by inductively coupled plasma mass spectrometry (ICP-MS). This method allows rapid preconcentration and separation of plutonium and neptunium in large soil samples for the measurement of {sup 237}Np and Pu isotopes by ICP-MS. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via {sup 238}U peak tailing. The method provides enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then transferring Pu to DGA resin for additional purification. The decontamination factor for removal of uranium from plutonium for this method is greater than 1 x 10{sup 6}. Alpha spectrometry can also be applied so that the shorter-lived {sup 238}Pu isotope can be measured successfully. {sup 239}Pu, {sup 242}Pu and {sup 237}Np were measured by ICP-MS, while {sup 236}Pu and {sup 238}Pu were measured by alpha spectrometry.

Maxwell, S.

2010-07-26T23:59:59.000Z

84

RAPID DETERMINATION OF 237 NP AND PU ISOTOPES IN WATER BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY AND ALPHA SPECTROMETRY  

SciTech Connect (OSTI)

A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of {sup 237}Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry; a hybrid approach. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ICP-MS and alpha spectrometry so that long and short-lived Pu isotopes can be measured successfully. The method allows for simultaneous extraction of 20 samples (including QC samples) in 4 to 6 hours, and can also be used for emergency response. {sup 239}Pu, {sup 242}Pu and {sup 237}Np were measured by ICP-MS, while {sup 236}Pu, {sup 238}Pu, and {sup 239}Pu were measured by alpha spectrometry.

Maxwell, S.; Jones, V.; Culligan, B.; Nichols, S.; Noyes, G.

2010-06-23T23:59:59.000Z

85

Development of novel nano-composite membranes as introduction systems for mass spectrometers: Contrasting nano-composite membranes and conventional inlet systems.  

E-Print Network [OSTI]

??This dissertation presents the development of novel nano-composite membranes as introduction systems for mass spectrometers. These nano-composite membranes incorporate anodic aluminum oxide (AAO) membranes as… (more)

Miranda, Luis

2013-01-01T23:59:59.000Z

86

Development of A Cryogenic Drift Cell Spectrometer and Methods for Improving the Analytical Figures of Merit for Ion Mobility-Mass Spectrometry Analysis  

E-Print Network [OSTI]

A cryogenic (325-80 K) ion mobility-mass spectrometer was designed and constructed in order to improve the analytical figures-of-merit for the chemical analysis of small mass analytes using ion mobility-mass spectrometry. The instrument incorporates...

May, Jody C.

2010-10-12T23:59:59.000Z

87

E-Print Network 3.0 - accelerator mass spectrometer Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

for environmental research Mass ... Source: Pacific Northwest National Laboratory, Building Systems Program Collection: Energy Storage, Conversion and Utilization 4...

88

Combined distance-of-flight and time-of-flight mass spectrometer  

DOE Patents [OSTI]

A combined distance-of-flight mass spectrometry (DOFMS) and time-of-flight mass spectrometry (TOFMS) instrument includes an ion source configured to produce ions having varying mass-to-charge ratios, a first detector configured to determine when each of the ions travels a predetermined distance, a second detector configured to determine how far each of the ions travels in a predetermined time, and a detector extraction region operable to direct portions of the ions either to the first detector or to the second detector.

Enke, Christie G; Ray, Steven J; Graham, Alexander W; Hieftje, Gary M; Barinaga, Charles J; Koppenaal, David W

2014-02-11T23:59:59.000Z

89

Studies of the mechanism of the cluster formation in a thermally sampling atmospheric pressure ionization mass spectrometer  

SciTech Connect (OSTI)

In this study a thermally sampling atmospheric pressure ionization mass spectrometer is described and characterized. The ion transfer stage offers the capability to sample cluster ions at thermal equilibrium and during this transfer fundamental processes possibly affecting the cluster distribution are also readily identified. Additionally, the transfer stage combines optional collision-induced dissociation (CID) analysis of the cluster composition with thermal equilibrium sampling of clusters. The performance of the setup is demonstrated with regard to the proton-bound water cluster system. The benefit of the studied processes is that they can help to improve future transfer stages and to understand cluster ion reactions in ion mobility tubes and high-pressure ion sources. In addition, the instrument allows for the identification of fragmentation and protonation reactions caused by CID.

Albrecht, Sascha, E-mail: s.albrecht@fz-juelich.de; Stroh, Fred, E-mail: f.stroh@fz-juelich.de [Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Stratosphere (IEK-7), 52428 Jülich (Germany)] [Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Stratosphere (IEK-7), 52428 Jülich (Germany); Klopotowski, Sebastian, E-mail: s.klopotowski@uni-wuppertal.de; Derpmann, Valerie, E-mail: v.derpmann@uni-wuppertal.de; Klee, Sonja, E-mail: s.klee@uni-wuppertal.de; Brockmann, Klaus J., E-mail: brockma@uni-wuppertal.de; Benter, Thorsten, E-mail: tbenter@uni-wuppertal.de [Physical and Theoretical Chemistry, Institute for Pure and Applied Mass Spectrometry, University of Wuppertal, 42097 Wuppertal (Germany)] [Physical and Theoretical Chemistry, Institute for Pure and Applied Mass Spectrometry, University of Wuppertal, 42097 Wuppertal (Germany)

2014-01-15T23:59:59.000Z

90

Optically detected, single nanoparticle mass spectrometer with pre-filtered electrospray nanoparticle source  

SciTech Connect (OSTI)

An instrument designed for non-destructive mass analysis of single trapped nanoparticles is described. The heart of the instrument is a 3D quadrupole (Paul) trap constructed to give optical access to the trap center along ten directions, allowing passage of lasers for particle heating and detection, particle injection, collection of scattered or fluorescent photons for particle detection and mass analysis, and collection of particles on TEM grids for analysis, as needed. Nanoparticles are injected using an electrospray ionization (ESI) source, and conditions are described for spraying and trapping polymer particles, bare metal particles, and ligand stabilized particles with masses ranging from 200 kDa to >3 GDa. Conditions appropriate to ESI and injection of different types of particles are described. The instrument is equipped with two ion guides separating the ESI source and nanoparticle trap. The first ion guide is mostly to allow desolvation and differential pumping before the particles enter the trap section of the instrument. The second is a linear quadrupole guide, which can be operated in mass selective or mass band-pass modes to limit transmission to species with mass-to-charge ratios in the range of interest. With a little experience, the design allows injection of single particles into the trap upon demand.

Howder, Collin R.; Bell, David M.; Anderson, Scott L. [Chemistry Department, University of Utah, 315 S. 1400 E, Salt Lake City, Utah 84112 (United States)] [Chemistry Department, University of Utah, 315 S. 1400 E, Salt Lake City, Utah 84112 (United States)

2014-01-15T23:59:59.000Z

91

Standard test method for isotopic analysis of uranium hexafluoride by double standard single-collector gas mass spectrometer method  

E-Print Network [OSTI]

1.1 This is a quantitative test method applicable to determining the mass percent of uranium isotopes in uranium hexafluoride (UF6) samples with 235U concentrations between 0.1 and 5.0 mass %. 1.2 This test method may be applicable for the entire range of 235U concentrations for which adequate standards are available. 1.3 This test method is for analysis by a gas magnetic sector mass spectrometer with a single collector using interpolation to determine the isotopic concentration of an unknown sample between two characterized UF6 standards. 1.4 This test method is to replace the existing test method currently published in Test Methods C761 and is used in the nuclear fuel cycle for UF6 isotopic analyses. 1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appro...

American Society for Testing and Materials. Philadelphia

2010-01-01T23:59:59.000Z

92

Standard test method for analysis of isotopic composition of uranium in nuclear-grade fuel material by quadrupole inductively coupled plasma-mass spectrometry  

E-Print Network [OSTI]

1.1 This test method is applicable to the determination of the isotopic composition of uranium (U) in nuclear-grade fuel material. The following isotopic weight percentages are determined using a quadrupole inductively coupled plasma-mass spectrometer (Q-ICP-MS): 233U, 234U, 235U, 236U, and 238U. The analysis can be performed on various material matrices after acid dissolution and sample dilution into water or dilute nitric (HNO3) acid. These materials include: fuel product, uranium oxide, uranium oxide alloys, uranyl nitrate (UNH) crystals, and solutions. The sample preparation discussed in this test method focuses on fuel product material but may be used for uranium oxide or a uranium oxide alloy. Other preparation techniques may be used and some references are given. Purification of the uranium by anion-exchange extraction is not required for this test method, as it is required by other test methods such as radiochemistry and thermal ionization mass spectroscopy (TIMS). This test method is also described i...

American Society for Testing and Materials. Philadelphia

2000-01-01T23:59:59.000Z

93

Ion fragmentation in an electrospray ionization mass spectrometer interface with different gases  

E-Print Network [OSTI]

in the gas phase. However, particularly in multi- component samples, this may not be enough to unambigu predicts that the degree of ion fragmentation increases with increasing mass of the curtain gas. However with argon and krypton is caused by condensation of the gases within the free jet expansion between

Chen, David D.Y.

94

Automatic Identification of Proteins with a MALDI-Quadrupole Ion Trap Mass Spectrometer  

E-Print Network [OSTI]

the sample with relatively high energy- density laser pulsessthe practical result is that is often, automatic identification of proteins. A mass spectrometry-based method can satisfy this need if it (1) produces high-quality MS and MS/MS data; (2) has femtomole sensitivity; (3) is fast, i.e., collects spectra

Chait, Brian T.

95

Multiple-ion-beam time-of-flight mass spectrometer Andreas Rohrbacher and Robert E. Continettia)  

E-Print Network [OSTI]

/ionization and the molecular ions of two different proteins myoglobin and lysozyme , created by matrix assisted laser,7 and matrix assisted desorption and ionization MALDI 8­11 have become avail- able to allow the mass the samples with a robot- driven capillary,15 a scanning ion beam,16 or spatial resolu- tion was achieved

Continetti, Robert E.

96

Orbitrap Mass Spectrometer | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

acceptable approaches than presently employed is an imperative goal... Clinical Microfluidics for Neutrophil Genomics and Proteomics. Neutrophils play critical roles in...

97

Mass Spectrometer: Orbitrap | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

has been increasingly recognized for its role in cell signaling. While... Clinical Microfluidics for Neutrophil Genomics and Proteomics. Neutrophils play critical roles in...

98

Mass Spectrometer | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of strong brown carbon chromophores. Citation: Laskin J, A Laskin, S Nizkorodov, PJ Roach, PA Eckert, MK Gilles, B Wang, HJ Lee, and Q Hu.2014."Molecular Selectivity of Brown...

99

Mass Spectrometer: Orbitrap | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selected asMaratMary Louise(ElementIonOrbitrap

100

ablation laser spectrometer  

E-Print Network [OSTI]

ablation laser mass spectrometer molecular beam REMPI laser NREL has designed and developed a combined laser ablation/ pulsed sample introduction/mass spectrometry platform that integrates pyrolysis and/or laser ablation with resonance- enhanced multiphoton ionization (REMPI) time-of-flight mass

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Monolithic spectrometer  

DOE Patents [OSTI]

A monolithic spectrometer is disclosed for use in spectroscopy. The spectrometer is a single body of translucent material with positioned surfaces for the transmission, reflection and spectral analysis of light rays. 6 figs.

Rajic, S.; Egert, C.M.; Kahl, W.K.; Snyder, W.B. Jr.; Evans, B.M. III; Marlar, T.A.; Cunningham, J.P.

1998-05-19T23:59:59.000Z

102

Monolithic spectrometer  

DOE Patents [OSTI]

A monolithic spectrometer is disclosed for use in spectroscopy. The spectrometer is a single body of translucent material with positioned surfaces for the transmission, reflection and spectral analysis of light rays.

Rajic, Slobodan (Knoxville, TN); Egert, Charles M. (Oak Ridge, TN); Kahl, William K. (Knoxville, TN); Snyder, Jr., William B. (Knoxville, TN); Evans, III, Boyd M. (Oak Ridge, TN); Marlar, Troy A. (Knoxville, TN); Cunningham, Joseph P. (Oak Ridge, TN)

1998-01-01T23:59:59.000Z

103

Development and implementation of a FT-ICR mass spectrometer for the investigation of ion conformations of peptide sequence isomers containing basic amino acid residues by gas-phase hydrogen/deuterium exchange  

E-Print Network [OSTI]

The gas-phase hydrogen/deuterium (H/D) exchange of protonated di- and tripeptides containing a basic amino acid residue has been studied with a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Bimolecular reactions...

Marini, Joseph Thomas

2004-09-30T23:59:59.000Z

104

551IEEE TRANSACTIONSON GEOSCIENCE AND REMOTE SENSING, VOL. 31, NO. 3, MAY 1993 MAST: A Mass Spectrometer Telescope for  

E-Print Network [OSTI]

Spectrometer Telescope for M4 D1 D2 D3 D4 D5 D6 - I , Studies of the Isotopic Composition of Solar, Anomalous, and Galactic Cosmic Ray Nuclei W. R. Cook, A. C. Cummings, J. R. Cummings, T. L. Garrard, B. Kecman, R. AV/nuc. During large solar flares MAST will measure the iso- topic abundancesof solar energeticparticlesto

Goddard III, William A.

105

A Thomson-type mass and energy spectrometer for characterizing ion energy distributions in a coaxial plasma gun operating in a gas-puff mode  

SciTech Connect (OSTI)

Measurements of ion energy distribution are performed in the accelerated plasma of a coaxial electromagnetic plasma gun operating in a gas-puff mode at relatively low discharge energy (900 J) and discharge potential (4 kV). The measurements are made using a Thomson-type mass and energy spectrometer with a gated microchannel plate and phosphor screen as the ion sensor. The parabolic ion trajectories are captured from the sensor screen with an intensified charge-coupled detector camera. The spectrometer was designed and calibrated using the Geant4 toolkit, accounting for the effects on the ion trajectories of spatial non-uniformities in the spectrometer magnetic and electric fields. Results for hydrogen gas puffs indicate the existence of a class of accelerated protons with energies well above the coaxial discharge potential (up to 24 keV). The Thomson analyzer confirms the presence of impurities of copper and iron, also of relatively high energies, which are likely erosion or sputter products from plasma-electrode interactions.

Rieker, G. B.; Poehlmann, F. R.; Cappelli, M. A. [High Temperature Gasdynamics Laboratory, Stanford University, Stanford, California 94305 (United States)] [High Temperature Gasdynamics Laboratory, Stanford University, Stanford, California 94305 (United States)

2013-07-15T23:59:59.000Z

106

The TFTR E Parallel B Spectrometer for Mass and Energy Resolved Multi-Ion Charge Exchange Diagnostics  

SciTech Connect (OSTI)

The Charge Exchange Neutral Analyzer diagnostic for the Tokamak Fusion Test Reactor was designed to measure the energy distributions of both the thermal ions and the supra thermal populations arising from neutral-beam injection and ion cyclotron radio-frequency heating. These measurements yield the plasma ion temperature, as well as several other plasma parameters necessary to provide an understanding of the plasma condition and the performance of the auxiliary heating methods. For this application, a novel charge-exchange spectrometer using a dee-shaped region of parallel electric and magnetic fields was developed at the Princeton Plasma Physics Laboratory. The design and performance of this spectrometer is described in detail, including the effects of exposure of the microchannel plate detector to magnetic fields, neutrons, and tritium.

A.L. Roquemore; S.S. Medley

1998-01-01T23:59:59.000Z

107

Correlation spectrometer  

DOE Patents [OSTI]

A correlation spectrometer can detect a large number of gaseous compounds, or chemical species, with a species-specific mask wheel. In this mode, the spectrometer is optimized for the direct measurement of individual target compounds. Additionally, the spectrometer can measure the transmission spectrum from a given sample of gas. In this mode, infrared light is passed through a gas sample and the infrared transmission signature of the gasses present is recorded and measured using Hadamard encoding techniques. The spectrometer can detect the transmission or emission spectra in any system where multiple species are present in a generally known volume.

Sinclair, Michael B. (Albuquerque, NM); Pfeifer, Kent B. (Los Lunas, NM); Flemming, Jeb H. (Albuquerque, NM); Jones, Gary D. (Tijeras, NM); Tigges, Chris P. (Albuquerque, NM)

2010-04-13T23:59:59.000Z

108

Multidimensional spectrometer  

DOE Patents [OSTI]

A multidimensional spectrometer for the infrared, visible, and ultraviolet regions of the electromagnetic spectrum, and a method for making multidimensional spectroscopic measurements in the infrared, visible, and ultraviolet regions of the electromagnetic spectrum. The multidimensional spectrometer facilitates measurements of inter- and intra-molecular interactions.

Zanni, Martin Thomas (Madison, WI); Damrauer, Niels H. (Boulder, CO)

2010-07-20T23:59:59.000Z

109

RAPID DETERMINATION OF ACTINIDES IN URINE BY INDUCTIVELY-COUPLED PLASMA MASS SPECTROMETRY AND ALPHA SPECTROMETRY: A HYBRID APPROACH  

SciTech Connect (OSTI)

A new rapid separation method that allows separation and preconcentration of actinides in urine samples was developed for the measurement of longer lived actinides by inductively coupled plasma mass spectrometry (ICP-MS) and short-lived actinides by alpha spectrometry; a hybrid approach. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration, if required, is performed using a streamlined calcium phosphate precipitation. Similar technology has been applied to separate actinides prior to measurement by alpha spectrometry, but this new method has been developed with elution reagents now compatible with ICP-MS as well. Purified solutions are split between ICP-MS and alpha spectrometry so that long- and short-lived actinide isotopes can be measured successfully. The method allows for simultaneous extraction of 24 samples (including QC samples) in less than 3 h. Simultaneous sample preparation can offer significant time savings over sequential sample preparation. For example, sequential sample preparation of 24 samples taking just 15 min each requires 6 h to complete. The simplicity and speed of this new method makes it attractive for radiological emergency response. If preconcentration is applied, the method is applicable to larger sample aliquots for occupational exposures as well. The chemical recoveries are typically greater than 90%, in contrast to other reported methods using flow injection separation techniques for urine samples where plutonium yields were 70-80%. This method allows measurement of both long-lived and short-lived actinide isotopes. 239Pu, 242Pu, 237Np, 243Am, 234U, 235U and 238U were measured by ICP-MS, while 236Pu, 238Pu, 239Pu, 241Am, 243Am and 244Cm were measured by alpha spectrometry. The method can also be adapted so that the separation of uranium isotopes for assay is not required, if uranium assay by direct dilution of the urine sample is preferred instead. Multiple vacuum box locations may be set-up to supply several ICP-MS units with purified sample fractions such that a high sample throughput may be achieved, while still allowing for rapid measurement of short-lived actinides by alpha spectrometry.

Maxwell, S.; Jones, V.

2009-05-27T23:59:59.000Z

110

Dustbuster: a compact impact-ionization time-of-flight mass spectrometer for in situ analysis of cosmic dust  

E-Print Network [OSTI]

a large target area with a reflectron, simultaneously optimizing mass resolution, particle detection. The resulting ions, with broad energy and angular distributions, are accelerated through a modified reflectron remote sensing, collection and analysis of dust grains that have survived impact on the Earth, capture

Stewart, Sarah T.

111

Facilities: NHMFL 9.4 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation: Atmospheric Pressure Laser-Induced Acoustic Desorption Chemical Ionization Mass Spectrometry  

E-Print Network [OSTI]

. Rodgers, & Alan G. Marshall, Analytical Chemistry 84, 7131-7137 (2012). Figure 1. Schematic diagram hydrocarbons (the primary components of gasoline) are difficult to analyze by mass spectrometry, because

Weston, Ken

112

A MODULAR STEADY STATE GLOW DISCHARGE QUADRUPOLE MASS SPECTROMETER SYSTEM FOR THE AT-LINE ANALYSIS OF PLUTONIUM METAL  

SciTech Connect (OSTI)

Historically, glow discharge mass and optical spectrometric techniques have been used in industry for the characterization of processed metals, such as steels and other alloys. This technique is especially well suited for this type of product analysis because the glow discharge ionization source accommodates solid conducting samples with minimal or no sample preparation. This characteristic along with minimal matrix effect considerations makes the glow discharge source well suited for these types of applications.

R. STEINER; D. WAYNE

1998-12-01T23:59:59.000Z

113

Characterizing the Performance of a Proton-Transfer-Reaction Mass Spectrometer with a Rapid Cycling Tenax Preconcentrator  

SciTech Connect (OSTI)

Volatile organic compounds (VOCs) are species of interest for atmospheric modeling, worker chemical exposure and medical studies. Sometimes the required detection limits for these compounds is below the capability of existing real-time instrumentation. Preconcentrators have been implemented as an inexpensive way to amplify chemical signals and improve detection limits. Proton-transfer-reaction mass spectrometry (PTR-MS) has been used as a tool for studying low concentrations of VOCs, but it lacks the capability to differentiate chemical signal contributions from isobaric compounds. In this work, behavior of a newly designed Tenax TA preconcentrator when coupled with a PTRMS is characterized. This novel preconcentrator design allows rapid temperature cycling, maintaining near real-time response. The preconcentrator was exposed to a sample gas of toluene in varying concentrations and loading times between and then thermally desorbed for analysis by PTR-MS. The effects of preconcentrating multiple analytes simultaneously were also investigated as well as the chromatographic effects of the preconcentrator. A linear behavior was observed when the integrated ion count rates (ICPS) from thermal desorption peaks were regressed against both varying loading times at a constant toluene concentration and varying concentrations with constant loading times. From these trends, it is possible to determine the concentration of a VOC by knowing its ICPS from thermal desorption peaks from a known preconcentration time. Peak height ion count rates representing ultimate detectability were amplified by factors up to 257 times the original signal, extending the range of the PTR-MS from 50pptv to nearly 250 parts per quadrillion. This corresponds to an ultimate sensitivity of 200 parts per quadrillion with 20 minute time resolution. Quantitative preconcentrator behavior was demonstrated using ICPS from these ion peaks and were amplified as much as 148 times their original signal. Results from multi-analyte desorption indicate that chromatographic separation is possible with a Tenax preconcentrator and further details are discussed. The dramatic increased in sensitivity with near real-time response, combined with chromatographic resolving capability opens up new areas of research requiring the detection of ultra-trace organic species using PTR-MS.

Garland, S.P.; Alexander, M.L.

2006-01-01T23:59:59.000Z

114

The effect of ultrafast laser wavelength on ablation properties and implications on sample introduction in inductively coupled plasma mass spectrometry  

SciTech Connect (OSTI)

We investigated the role of femtosecond (fs) laser wavelength on laser ablation (LA) and its relation to laser generated aerosol counts and particle distribution, inductively coupled plasma-mass spectrometry (ICP-MS) signal intensity, detection limits, and elemental fractionation. Four different NIST standard reference materials (610, 613, 615, and 616) were ablated using 400 nm and 800 nm fs laser pulses to study the effect of wavelength on laser ablation rate, accuracy, precision, and fractionation. Our results show that the detection limits are lower for 400 nm laser excitation than 800 nm laser excitation at lower laser energies but approximately equal at higher energies. Ablation threshold was also found to be lower for 400 nm than 800 nm laser excitation. Particle size distributions are very similar for 400 nm and 800 nm wavelengths; however, they differ significantly in counts at similar laser fluence levels. This study concludes that 400 nm LA is more beneficial for sample introduction in ICP-MS, particularly when lower laser energies are to be used for ablation.

LaHaye, N. L.; Harilal, S. S.; Diwakar, P. K.; Hassanein, A. [Center for Materials under Extreme Environment, School of Nuclear Engineering Purdue University, West Lafayette, Indiana 47907 (United States); Kulkarni, P. [Centers for Disease Control and Prevention, National Institute of Occupational Safety and Health, Cincinnati, Ohio 45213 (United States)

2013-07-14T23:59:59.000Z

115

Method of multiplexed analysis using ion mobility spectrometer  

DOE Patents [OSTI]

A method for analyzing analytes from a sample introduced into a Spectrometer by generating a pseudo random sequence of a modulation bins, organizing each modulation bin as a series of submodulation bins, thereby forming an extended pseudo random sequence of submodulation bins, releasing the analytes in a series of analyte packets into a Spectrometer, thereby generating an unknown original ion signal vector, detecting the analytes at a detector, and characterizing the sample using the plurality of analyte signal subvectors. The method is advantageously applied to an Ion Mobility Spectrometer, and an Ion Mobility Spectrometer interfaced with a Time of Flight Mass Spectrometer.

Belov, Mikhail E. (Richland, WA); Smith, Richard D. (Richland, WA)

2009-06-02T23:59:59.000Z

116

Mobile Ice Nucleus Spectrometer  

SciTech Connect (OSTI)

This first year report presents results from a computational fluid dynamics (CFD) study to assess the flow and temperature profiles within the mobile ice nucleus spectrometer.

Kulkarni, Gourihar R.; Kok, G. L.

2012-05-07T23:59:59.000Z

117

Development and Application of an Electrospray Ionization Ion Mobility-mass Spectrometer Using an RF Ion Funnel and Periodic-focusing Ion Guide  

E-Print Network [OSTI]

home-built electrospray ionization (ESI) source and rf ion funnel(IF) as an ion transfer interface, modular periodic-focusing ion guide (PFIG) as a drift tube (DT) for arrival time measurement, and orthogonally accelerated linear time-of-flight mass...

Jeon, Junho

2013-10-16T23:59:59.000Z

118

Development of a MALDI-Ion Mobility-Surface-Induced Dissociation-Time-of-flight-mass spectrometer for the analysis of peptides and proteins  

E-Print Network [OSTI]

of approximately 20 and TOF mass resolution better than 200. Peptide sequences of four peptides from a tryptic digest of cytochrome c (ca. 1 pmol deposited) were obtained. The advantage of IM-SID-o-TOFMS is that a single experiment can be used to simultaneously...

Stone, Earle Gregory

2004-09-30T23:59:59.000Z

119

On-site profiling and speciation of polycyclic aromatic hydrocarbons at manufactured gas plant sites by a high temperature transfer line, membrane inlet probe coupled to a photoionization detector and gas chromatography/mass spectrometer  

SciTech Connect (OSTI)

A new high temperature transfer line, membrane inlet probe (HTTL-MIP) coupled to a photoionization detector (PID) and gas chromatograph/mass spectrometer (GC/MS) was used to rapidly profile and speciate polycyclic aromatic hydrocarbons (PAH) in the subsurface. PID signals were in agreement with GC/MS results. Correlation coefficients of 0.92 and 0.99 were obtained for discrete and composite samples collected from the same exact location. Continuous probe advancement with PID detection found coal tar, a dense nonaqueous phase liquid, in soil channels and saturated media. When samples were collected conventionally, split, solvent extracted, and analyzed in the field and confirmation laboratory, GC/MS measurement precision and accuracy were indistinguishable; despite the fact the field laboratory produced data five times faster than the laboratory using standard EPA methods. No false positive/negatives were found. Based on these findings, increased confidence in site conceptual models should be obtained, since PID response indicated total PAH presence/absence in 'real-time', while GC/MS provided information as to which PAH was present and at what concentration. Incorporation of this tool into a dynamic workplan will provide more data at less cost enabling environmental scientists, engineers, and regulators to better understand coal tar migration and its impact on human health and the environment. 24 refs., 3 figs., 4 tabs.

Thomas Considine; Albert Robbat Jr. [Tufts University, Medford, MA (United States). Chemistry Department, Center for Field Analytical Studies and Technology

2008-02-15T23:59:59.000Z

120

Glass particles produced by laser ablation for ICP-MS measurements  

E-Print Network [OSTI]

NIST) and X-ray fluorescence (XRF) monitor samples from Glenstandards), and figure 2 (XRF standards). The error barsand 160 and 180 nm for XRF monitor samples. These data show

Gonzalez, J.; Liu, C.; Wen, S.; Mao, X.; Russo, R.E.

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Determination of 235U/238U Ratio on Urine by ICP-MS  

SciTech Connect (OSTI)

LLNL Internal Dosimetry Program - The new procedure satisfies the requirement to determine {sup 235}U/{sup 238}U ratio in bioassay urine samples. MDA - The L{sub C} and MDA{sub 95} for {sup 235}U are well below the required detection limit of 0.00035 {mu}g/L. Turn around time - Analysis of 10 samples plus 2 QCs can be completed in one work day (8 hours).

Collins, L; Gobaleza, A; Langston, R; Radev, R; Than, C; Wong, C; Wood-Zika, A

2011-10-19T23:59:59.000Z

122

Trace Elemental Variation in Dosidicus Gigas Statoliths Using LA-ICP-MS  

E-Print Network [OSTI]

, southern California, and Washington State. A dissection method was recorded and published. By using laser ablation methods, discrete measurements of 10 elements were collected at 6 to 7 ablation sites covering embryonic, paralarval, juvenile and adult...

Arbuckle, Nancy 1980-

2012-08-24T23:59:59.000Z

123

E-Print Network 3.0 - alpha spectrometry icp-ms Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Multidisciplinary Databases and Resources 11 Nuclear Instruments and Methods in Physics Research A 591 (2008) 490509 Systematic study of trace radioactive...

124

Ancestral Polynesian Pottery Production and Exchange Analysis Using LA-ICP-MS  

E-Print Network [OSTI]

Samoa .......................................................... 3 2.1 Upland sites in relation to basalt quarries and volcanic provinces .................. 19 2.2 Potsherds containing various types of temper inclusions... of lithics recovered from Aganoa. Results of this study provide evidence that Aganoa did not act as a lithic workshop and that separate quarries were utilized at different stages across a temporal time span. The ceramic sequence Green?s (1974) ceramic...

Bartek, Christopher

2009-06-09T23:59:59.000Z

125

Improvements to ICP Torches for Monitoring Trace Radionuclides by ICP-MS |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinementEtching.348 270 300 219 255RetrievalsVehiclesLaboratory

126

Mass Spectrometer: Single Particle (SPLAT II) | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

nano- and micro-scales. SPLAT II's applications include but are not limited to climate, air pollution, human health, bioterrorism, and emerging nanotechnologies. Portability is a...

127

Miniaturized Mass Spectrometer - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program PreliminaryA3,0 AlabamaYear [2002] [2003]6

128

Mass Spectrometer Laboratory | Photosynthetic Antenna Research Center  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMapping the Nanoscale Landscape PrintSurveyMary K.

129

Sandia National Laboratories: multiplexed photoionization mass spectrometer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1developmentturbine bladelifetime ismobile test systeminside

130

Mass Spectrometer: Proton Transfer Reaction (PTRMS) | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selected asMaratMary

131

Mass Spectrometer: Single Particle (SPLAT II) | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selected asMaratMarySingle Particle (SPLAT II)

132

LUNAR MASS SPECTROMETER RELIABILITY LOGIC DIAGRAM  

E-Print Network [OSTI]

point (A) to (F). The block diagram also defines the reliability functions for the purpose of FMEA 1

Rathbun, Julie A.

133

Compound and Elemental Analysis At Salt Wells Area (Coolbaugh...  

Open Energy Info (EERE)

by standard Induced Coupled Plasma Mass Spectroscopy (ICP-MS), using ICP emission and atomic absorption methods for cations and ICP emission for anions. The hottest sampled...

134

ablation multi-collector inductively: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

mass spectrometry (ICP-MS). A compact computer Chen, Zhongxing 14 Measurements of Cavitation Dose, Echogenicity, and Temperature during Ultrasound Ablation Biology and Medicine...

135

Neutron range spectrometer  

DOE Patents [OSTI]

A neutron range spectrometer and method for determining the neutron energy spectrum of a neutron emitting source are disclosed. Neutrons from the source are colliminated along a collimation axis and a position sensitive neutron counter is disposed in the path of the collimated neutron beam. The counter determines positions along the collimation axis of interactions between the neutrons in the neutron beam and a neutron-absorbing material in the counter. From the interaction positions, a computer analyzes the data and determines the neutron energy spectrum of the neutron beam. The counter is preferably shielded and a suitable neutron-absorbing material is He-3. 1 fig.

Manglos, S.H.

1988-03-10T23:59:59.000Z

136

Quench anaylsis of MICE spectrometer superconducting solenoid  

SciTech Connect (OSTI)

MICE superconducting spectrometer solenoids fabrication and tests are in progress now. First tests of the Spectrometer Solenoid discovered some issues which could be related to the chosen passive quench protection system. Both solenoids do not have heaters and quench propagation relied on the 'quench back' effect, cold diodes, and shunt resistors. The solenoids have very large inductances and stored energy which is 100% dissipated in the cold mass during a quench. This makes their protection a challenging task. The paper presents the quench analysis of these solenoids based on 3D FEA solution of coupled transient electromagnetic and thermal problems. The simulations used the Vector Fields QUENCH code. It is shown that in some quench scenarios, the quench propagation is relatively slow and some areas can be overheated. They describe ways of improving the solenoids quench protection in order to reduce the risk of possible failure.

Kashikhin, Vladimir; Bross, Alan; /Fermilab; Prestemon, Soren; / /LBL, Berkeley

2011-09-01T23:59:59.000Z

137

Current developments in laser ablation-inductively coupled plasma-mass spectrometry for use in geology, forensics, and nuclear nonproliferation research  

SciTech Connect (OSTI)

This dissertation focused on new applications of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The diverse fields that were investigated show the versatility of the technique. In Chapter 2, LA-ICP-MS was used to investigate the rare earth element (REE) profiles of garnets from the Broken Hill Deposit in New South Wales, Australia. The normalized REE profiles helped to shed new light on the formation of deposits of sulfide ores. This information may be helpful in identifying the location of sulfide ore deposits in other locations. New sources of metals such as Pg, Zn, and Ag, produced from these ores, are needed to sustain our current technological society. The application of LA-ICP-MS presented in Chapter 3 is the forensics analysis of automotive putty and caulking. The elemental analysis of these materials was combined with the use of Principal Components Analysis (PCA). The PCA comparison was able to differentiate the automotive putty samples by manufacturer and lot number. The analysis of caulk was able to show a differentiation based on manufacturer, but no clear differentiation was shown by lot number. This differentiation may allow matching of evidence in the future. This will require many more analyses and the construction of a database made up of many different samples. The 4th chapter was a study of the capabilities of LA-ICP-MS for fast and precise analysis of particle ensembles for nuclear nonproliferation applications. Laser ablation has the ability to spatially resolve particle ensembles which may contain uranium or other actinides from other particles present in a sample. This is of importance in samples obtained from air on filter media. The particle ensembles of interest may be mixed in amongst dust and other particulates. A problem arises when ablating these particle ensembles directly from the filter media. Dust particles other than ones of interest may be accidentally entrained in the aerosol of the ablated particle ensemble. This would cause the analysis to be skewed. The use of a gelatin substrate allows the ablation a particle ensemble without disturbing other particles or the gelatin surface. A method to trap and ablate particles on filter paper using collodion was also investigated. The laser was used to dig through the collodion layer and into the particle ensemble. Both of these methods fix particles to allow spatial resolution of the particle ensembles. The use of vanillic acid as a possible enhancement to ablation was also studied. A vanillic acid coating of the particles fixed on top of the gelatin substrate was not found to have any positive effect on either signal intensity or precision. The mixing of vanillic acid in the collodion solution used to coat the filter paper increased ablation signal intensity by a factor of 4 to 5. There was little effect on precision, though. The collodion on filter paper method and the gelatin method of resolving particles have shown themselves to be possible tools in fighting proliferation of nuclear weapons and material. Future applications of LA-ICP-MS are only limited by the imagination of the investigator. Any material that can be ablated and aerosolized is a potential material for analysis by LA-ICP-MS. Improvements in aerosol transport, ablation chamber design, and laser focusing can make possible the ablation and analysis of very small amounts of material. This may perhaps lead to more possible uses in forensics. A similar method to the one used in Chapter 3 could perhaps be used to match drug residue to the place of origin. Perhaps a link could be made based on the elements leached from the soil by plants used to make drugs. This may have a specific pattern based on where the plant was grown. Synthetic drugs are produced in clandestine laboratories that are often times very dirty. The dust, debris, and unique materials in the lab environment could create enough variance to perhaps match drugs produced there to samples obtained off the street. Even if the match was not strong enough to be evidence, the knowledge that many sa

Messerly, Joshua D.

2008-08-26T23:59:59.000Z

138

Study of Active Shielding for {gamma} - Spectrometers  

SciTech Connect (OSTI)

The features of the ground located gamma ray spectrometer shielded passively with 12 cm of lead and actively by five 0.5m x 0.5m x 0.05m plastic veto shields are described. The detector mass related background was 0.345 C/kg s. The 511 keV annihilation line was reduced by the factor of 7 by the anticoincidence gate. It is shown that the plastic shields increase the neutron capture gamma line intensities due to neutron thermalization.

Bikit, I.; Mrdja, D.; Forkapic, S.; Todorovic, N.; Veskovic, M.; Slivka, J.; Conkic, Lj.; Krmar, M.; Varga, E. [Department of Physics, Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovica 4, 21 000 Novi Sad (Serbia and Montenegro)

2006-04-26T23:59:59.000Z

139

Neutron range spectrometer  

DOE Patents [OSTI]

A neutron range spectrometer and method for determining the neutron energy spectrum of a neutron emitting source are disclosed. Neutrons from the source are collimnated along a collimation axis and a position sensitive neutron counter is disposed in the path of the collimated neutron beam. The counter determines positions along the collimation axis of interactions between the neutrons in the neutron beam and a neutron-absorbing material in the counter. From the interaction positions, a computer analyzes the data and determines the neutron energy spectrum of the neutron beam. The counter is preferably shielded and a suitable neutron-absorbing material is He-3. The computer solves the following equation in the analysis: ##EQU1## where: N(x).DELTA.x=the number of neutron interactions measured between a position x and x+.DELTA.x, A.sub.i (E.sub.i).DELTA.E.sub.i =the number of incident neutrons with energy between E.sub.i and E.sub.i +.DELTA.E.sub.i, and C=C(E.sub.i)=N .sigma.(E.sub.i) where N=the number density of absorbing atoms in the position sensitive counter means and .sigma. (E.sub.i)=the average cross section of the absorbing interaction between E.sub.i and E.sub.i +.DELTA.E.sub.i.

Manglos, Stephen H. (East Syracuse, NY)

1989-06-06T23:59:59.000Z

140

The IPNS resonance detector spectrometer  

SciTech Connect (OSTI)

In the resonance detector method of neutron spectroscopy, a foil is placed in the scattered neutron beam and scattered neutrons having the resonance energy are detected by detecting the capture gammas resulting from the resonance absorption of the neutrons. A prototype resonance detector spectrometer called the Electron Volt Spectrometer (EVS) has been built and operated. The instrument is described, the current understanding of the background of the instrument is discussed, software developed to simulate the detector efficiency is described and compared with experimental results, and a test of the use of foil-thickness difference techniques to improve resolution is presented. (LEW)

Crawford, R.K.

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Facilities: NHMFL 9.4 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation: Characterization of Pine Pellet and Peanut Hull Pyrolysis of Bio-Oils by Negative-Ion Electrospray Ionization Fourier  

E-Print Network [OSTI]

with greater than 1% relative abundance in either phase are shown. Pyrolysis of solid biomass, in this case: Characterization of Pine Pellet and Peanut Hull Pyrolysis of Bio-Oils by Negative-Ion Electrospray Ionization of nitrogen-containing species identified in the peanut hull pyrolysis oil by FT-ICR mass spectrometry

Weston, Ken

142

MICE Spectrometer Magnet System Progress  

SciTech Connect (OSTI)

The first magnets for the muon ionization cooling experimentwill be the tracker solenoids that form the ends of the MICE coolingchannel. The primary purpose of the tracker solenoids is to provide auniform 4 T field (to better than +-0.3 percent over a volume that is 1meter long and 0.3 meters in diameter) spectrometer magnet field for thescintillating fiber detectors that are used to analyze the muons in thechannel before and after ionization cooling. A secondary purpose for thetracker magnet is the matching of the muon beam between the rest of theMICE cooling channel and the uniform field spectrometer magnet. Thetracker solenoid is powered by three 300 amp power supplies. Additionaltuning of the spectrometer is provided by a pair of 50 amp power suppliesacross the spectrometer magnet end coils. The tracker magnet will becooled using a pair of 4 K pulse tube coolers that each provide 1.5 W ofcooling at 4.2 K. Final design and construction of the tracker solenoidsbegan during the summer of 2006. This report describes the progress madeon the construction of the tracker solenoids.

Green, Michael A.; Virostek, Steve P.

2007-08-27T23:59:59.000Z

143

Educational Multiwavelength Atomic Emission Spectrometer  

E-Print Network [OSTI]

atomic absorption is the capability for simultaneous multielement analysis. It can be used colleges had acquired atomic absorption instruments by the year 1990.[2] In contrast, atomic emission with the acetylene-air flame source taken from an existing atomic absorption instrument. Two spectrometer units

Nazarenko, Alexander

144

E781 Hyperon Spectrometer Constants  

SciTech Connect (OSTI)

This is a discussion of the physical measurements, sizes, distances and magnetic fields of the Hyperon Spectrometer Magnet and its components. Some we get from construction drawings (like the target dimensions) and others from measurements in differing coordinate systems. Included also are the properties of the hyperon productions targets used in E781.

Joseph T. Lach

2004-05-04T23:59:59.000Z

145

PUBLISHED VERSION Gamma ray spectrometer for ITER  

E-Print Network [OSTI]

Ray Scintillation Spectrometer Rev. Sci. Instrum. 24, 1096 (1953); 10.1063/1.1770609 An Automatic Recording Gamma for the spectrometer is presented. Keywords: tokamak, DT plasma, alpha- particles, diagnostics, gamma- spectrometry

146

Sample rotating turntable kit for infrared spectrometers  

DOE Patents [OSTI]

An infrared spectrometer sample rotating turntable kit has a rotatable sample cup containing the sample. The infrared spectrometer has an infrared spectrometer probe for analyzing the sample and the rotatable sample cup is adapted to receive the infrared spectrometer probe. A reflectance standard is located in the rotatable sample cup. A sleeve is positioned proximate the sample cup and adapted to receive the probe. A rotator rotates the rotatable sample cup. A battery is connected to the rotator.

Eckels, Joel Del (Livermore, CA); Klunder, Gregory L. (Oakland, CA)

2008-03-04T23:59:59.000Z

147

Evaluation of pneumatic nebulization and ns-laser ablation ICP-MS for bulk elemental analysis and 2-dimensional  

E-Print Network [OSTI]

ID: JA-ART-12-2013-050387 Article Type: Paper Date Submitted by the Author: 12-Dec-2013 Complete List Brussels, Belgium.25 Electronic Supplementary Information (ESI) available Introduction The continuously

Claeys, Philippe

148

Melt Extraction and Melt Refertilization in Mantle Peridotite of the Coast Range Ophiolite: An LA-ICP-MS Study  

E-Print Network [OSTI]

Institute Songdo Techno Park 7-50 Incheon 406-840, South Korea Samuel B. Mukasa Department of Geological; Johnson et al., 1990, Johnson #12;3 and Dick, 1992; Seyler et al., 2003, 2004; Hellebrand et al., 2002, and essentially flat MREE-HREE (e.g., Johnson et al., 1990; Hellebrand et al., 2002). Niu (1997; Niu et al., 1997

Shervais, John W.

149

Inverse time-of-flight spectrometer for beam plasma research  

SciTech Connect (OSTI)

The paper describes the design and principle of operation of an inverse time-of-flight spectrometer for research in the plasma produced by an electron beam in the forevacuum pressure range (5–20 Pa). In the spectrometer, the deflecting plates as well as the drift tube and the primary ion beam measuring system are at high potential with respect to ground. This provides the possibility to measure the mass-charge constitution of the plasma created by a continuous electron beam with a current of up to 300 mA and electron energy of up to 20 keV at forevacuum pressures in the chamber placed at ground potential. Research results on the mass-charge state of the beam plasma are presented and analyzed.

Yushkov, Yu. G., E-mail: yuyushkov@gmail.com; Zolotukhin, D. B.; Tyunkov, A. V. [Tomsk State University of Control Systems and Radioelectronics, 40 Lenin Ave., Tomsk 634050 (Russian Federation); Oks, E. M. [Tomsk State University of Control Systems and Radioelectronics, 40 Lenin Ave., Tomsk 634050 (Russian Federation); Institute of High Current Electronics SB RAS, 2/3, Akademichesky Ave., Tomsk 634055 (Russian Federation); Savkin, K. P. [Institute of High Current Electronics SB RAS, 2/3, Akademichesky Ave., Tomsk 634055 (Russian Federation)

2014-08-15T23:59:59.000Z

150

Linear electric field mass spectrometry  

DOE Patents [OSTI]

A mass spectrometer and methods for mass spectrometry are described. The apparatus is compact and of low weight and has a low power requirement, making it suitable for use on a space satellite and as a portable detector for the presence of substances. High mass resolution measurements are made by timing ions moving through a gridless cylindrically symmetric linear electric field. 8 figs.

McComas, D.J.; Nordholt, J.E.

1992-12-01T23:59:59.000Z

151

Design of and data reduction from compact Thomson parabola spectrometers  

SciTech Connect (OSTI)

Thomson parabola spectrometers are used to characterize MeV ion beams produced in high intensity laser interactions. These spectrometers disperse multiple ion species according to their charge to mass ratio through the use of parallel electric and magnetic fields. Analytical solutions for ion deflection in electric and magnetic fields have been used to extract ion spectra with the assumption that fringing effects are negligible. Experimental space restrictions and dynamic range requirements necessitate designs that stress the analytical assumptions. Depending on design parameters, the error in the analytical assumption can be comparable to the energy resolution. Estimates are provided to approximate the error on the total ion deflection. A method for modeling ion trajectories including fringing effects is presented using software freely available or in common use. The magnetostatic fields are modeled in 3D, including material properties of nearby magnetic materials using RADIA. Electrostatic fields are modeled in 2D for a spectrometer implementing angled plates using the partial differential equation toolbox in MATLAB. Using these models to calculate the ion trajectory allows for analysis of a Thomson parabola spectrometer with an arbitrary field configuration.

Morrison, J. T.; Willis, C.; Freeman, R. R.; Van Woerkom, L. [Physics Department, Ohio State University, Columbus, Ohio 43210 (United States)

2011-03-15T23:59:59.000Z

152

Standard test method for determination of impurities in nuclear grade uranium compounds by inductively coupled plasma mass spectrometry  

E-Print Network [OSTI]

1.1 This test method covers the determination of 67 elements in uranium dioxide samples and nuclear grade uranium compounds and solutions without matrix separation by inductively coupled plasma mass spectrometry (ICP-MS). The elements are listed in Table 1. These elements can also be determined in uranyl nitrate hexahydrate (UNH), uranium hexafluoride (UF6), triuranium octoxide (U3O8) and uranium trioxide (UO3) if these compounds are treated and converted to the same uranium concentration solution. 1.2 The elements boron, sodium, silicon, phosphorus, potassium, calcium and iron can be determined using different techniques. The analyst's instrumentation will determine which procedure is chosen for the analysis. 1.3 The test method for technetium-99 is given in Annex A1. 1.4 The values stated in SI units are to be regarded as standard. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish ...

American Society for Testing and Materials. Philadelphia

2010-01-01T23:59:59.000Z

153

Characterization of a Sealed Americium-Beryllium (AmBe) Source by Inductively Coupled Plasma Mass Spectrometry  

SciTech Connect (OSTI)

Two Americium-Beryllium neutron sources were dismantled, sampled (sub-sampled) and analyzed via inductively coupled plasma mass spectrometry (ICP-MS). Characteristics such as “age” since purification, actinide content, trace metal content and inter and intra source composition were determined. The “age” since purification of the two sources was determined to be 25.0 and 25.4 years, respectively. The systematic errors in the “age” determination were ± 4 % 2s. The amount and isotopic composition of U and Pu varied substantially between the sub-samples of Source 2 (n=8). This may be due to the physical means of sub-sampling or the way the source was manufactured. Source 1 was much more consistent in terms of content and isotopic composition (n=3 sub-samples). The Be-Am ratio varied greatly between the two sources. Source 1 had an Am-Be ratio of 6.3 ± 52 % (1s). Source 2 had an Am-Be ratio of 9.81 ± 3.5 % (1s). In addition, the trace element content between the samples varied greatly. Significant differences were determined between Source 1 and 2 for Sc, Sr, Y, Zr, Mo, Ba and W.

James Sommers; Marcos Jimenez; Mary Adamic; Jeffrey Giglio; Kevin Carney

2009-12-01T23:59:59.000Z

154

Portable neutron spectrometer and dosimeter  

DOE Patents [OSTI]

The disclosure relates to a battery operated neutron spectrometer/dosimeter utilizing a microprocessor, a built-in tissue equivalent LET neutron detector, and a 128-channel pulse height analyzer with integral liquid crystal display. The apparatus calculates doses and dose rates from neutrons incident on the detector and displays a spectrum of rad or rem as a function of keV per micron of equivalent tissue and also calculates and displays accumulated dose in millirads and millirem as well as neutron dose rates in millirads per hour and millirem per hour.

Waechter, David A. (Los Alamos, NM); Erkkila, Bruce H. (Los Alamos, NM); Vasilik, Dennis G. (Los Alamos, NM)

1985-01-01T23:59:59.000Z

155

The Design and Construction of the MICE Spectrometer Solenoids  

SciTech Connect (OSTI)

The purpose of the MICE spectrometer solenoid is to provide a uniform field for a scintillating fiber tracker. The uniform field is produced by a long center coil and two short end coils. Together, they produce 4T field with a uniformity of better than 1% over a detector region of 1000 mm long and 300 mm in diameter. Throughout most of the detector region, the field uniformity is better than 0.3%. In addition to the uniform field coils, we have two match coils. These two coils can be independently adjusted to match uniform field region to the focusing coil field. The coil package length is 2544 mm. We present the spectrometer solenoid cold mass design, the powering and quench protection circuits, and the cryogenic cooling system based on using three cryocoolers with re-condensers.

Wang, Bert; Wahrer, Bob; Taylor, Clyde; Xu, L.; Chen, J. Y.; Wang, M.; Juang, Tiki; Zisman, Michael S.; Virostek, Steve P.; Green, Michael A.

2008-08-02T23:59:59.000Z

156

The High-Acceptance Dielectron Spectrometer HADES  

E-Print Network [OSTI]

HADES is a versatile magnetic spectrometer aimed at studying dielectron production in pion, proton and heavy-ion induced collisions. Its main features include a ring imaging gas Cherenkov detector for electron-hadron discrimination, a tracking system consisting of a set of 6 superconducting coils producing a toroidal field and drift chambers and a multiplicity and electron trigger array for additional electron-hadron discrimination and event characterization. A two-stage trigger system enhances events containing electrons. The physics program is focused on the investigation of hadron properties in nuclei and in the hot and dense hadronic matter. The detector system is characterized by an 85% azimuthal coverage over a polar angle interval from 18 to 85 degree, a single electron efficiency of 50% and a vector meson mass resolution of 2.5%. Identification of pions, kaons and protons is achieved combining time-of-flight and energy loss measurements over a large momentum range. This paper describes the main features and the performance of the detector system.

The HADES Collaboration; G. Agakishiev; A. Balanda; B. Bannier; R. Bassini; D. Belver; A. V. Belyaev; A. Blanco; M. Boehmer; J. L. Boyard; P. Braun-Munzinger; P. Cabanelas; E. Castro; S. Chernenko; T. Christ; M. Destefanis; J. Diaz; F. Dohrmann; A. Dybczak; T. Eberl; W. Enghardt; L. Fabbietti; O. V. Fateev; P. Finocchiaro; P. Fonte; J. Friese; I. Froehlich; T. Galatyuk; J. A. Garzon; R. Gernhaeuser; A. Gil; C. Gilardi; M. Golubeva; D. Gonzalez-Diaz; F. Guber; M. Heilmann; T. Heinz; T. Hennino; R. Holzmann; A. Ierusalimov; I. Iori; A. Ivashkin; M. Jurkovic; B. Kaempfer; K. Kanaki; T. Karavicheva; D. Kirschner; I. Koenig; W. Koenig; B. W. Kolb; R. Kotte; F. Krizek; R. Kruecken; W. Kuehn; A. Kugler; A. Kurepin; S. Lang; J. S. Lange; K. Lapidus; T. Liu; L. Lopes; M. Lorenz; L. Maier; A. Mangiarotti; J. Markert; V. Metag; B. Michalska; J. Michel; D. Mishra; E. Moriniere; J. Mousa; C. Muentz; L. Naumann; J. Otwinowski; Y. C. Pachmayer; M. Palka; Y. Parpottas; V. Pechenov; O. Pechenova; T. PerezCavalcanti; J. Pietraszko; W. Przygoda; B. Ramstein; A. Reshetin; M. Roy-Stephan; A. Rustamov; A. Sadovsky; B. Sailer; P. Salabura; A. Schmah; E. Schwab; Yu. G. Sobolev; S. Spataro; B. Spruck; H. Stroebele; J. Stroth; C. Sturm; M. Sudol; A. Tarantola; K. Teilab; P. Tlusty; M. Traxler; R. Trebac; H. Tsertos; V. Wagner; M. Weber; M. Wisniowski; T. Wojcik; J. Wuestenfel; S. Yurevich; Y. V. Zanevsky; P. Zhou; P. Zumbruch

2009-03-09T23:59:59.000Z

157

The High-Acceptance Dielectron Spectrometer HADES  

E-Print Network [OSTI]

HADES is a versatile magnetic spectrometer aimed at studying dielectron production in pion, proton and heavy-ion induced collisions. Its main features include a ring imaging gas Cherenkov detector for electron-hadron discrimination, a tracking system consisting of a set of 6 superconducting coils producing a toroidal field and drift chambers and a multiplicity and electron trigger array for additional electron-hadron discrimination and event characterization. A two-stage trigger system enhances events containing electrons. The physics program is focused on the investigation of hadron properties in nuclei and in the hot and dense hadronic matter. The detector system is characterized by an 85% azimuthal coverage over a polar angle interval from 18 to 85 degree, a single electron efficiency of 50% and a vector meson mass resolution of 2.5%. Identification of pions, kaons and protons is achieved combining time-of-flight and energy loss measurements over a large momentum range. This paper describes the main featur...

Agakichiev, G; Bannier, B; Bassini, R; Belver, D; Belyaev, A V; Blanco, A; Boehmer, M; Boyard, J L; Braun-Munzinger, P; Cabanelas, P; Castro, E; Chernenko, S; Christ, T; Destefanis, M; Díaz, J; Dohrmann, F; Dybczak, A; Eberl, T; Enghardt, W; Fabbietti, L; Fateev, O V; Finocchiaro, P; Fonte, Paulo J R; Friese, J; Fröhlich, I; Galatyuk, T; Garzón, J A; Gernhäuser, R; Gil1, A; Gilardi, C; Golubeva, M; Gonzalez-Diaz, D; Guber, F; Heilmann, M; Heinz, T; Hennino, T; Holzmann, R; Ierusalimov, A; Iori, I; Ivashkin, A; Jurkovic, M; Kämpfer, B; Kanaki, K; Karavicheva, T; Kirschner, D; König, I; König, W; Kolb, B W; Kotte, R; Krizek, F; Krücken, R; Kühn, W; Kugler, A; Kurepin, A; Lang, S; Lange, J S; Lapidus, K; Liu, T; Lopes, L; Lorenz, M; Maier, L; Mangiarotti, A; Markert, J; Metag, V; Michalska, B; Michel, J; Mishra, D; Moriniere, E; Mousa, J; Müntz, C; Naumann, Lutz; Otwinowski, J; Pachmayer, Y C; Palka, M; Parpottas, Y; Pechenov, V; Pechenova, O; PerezCavalcanti, T; Pietraszko, J; Przygoda, W; Ramstein, B; Reshetin, A; Roy-Stephan, M; Rustamov, A; Sadovskii, A; Sailer, B; Salabura, P; Schmah, A; Schwab, E; Sobolev, Yu G; Spataro, S; Spruck, B; Ströbele, H; Stroth, J; Sturm, C; Sudol, M; Tarantola, A; Teilab, K; Tlustý, P; Traxler, M; Trebac, R; Tsertos, H; Wagner, V; Weber, M; Wisniowski, M; Wojcik, T; Wuestenfel, J; Yurevich, S; Zanevsky, Yu V; Zhou, P; Zumbruch, P

2009-01-01T23:59:59.000Z

158

Progress on the Design and Fabircation of the MICE SpectrometerSolenoids  

SciTech Connect (OSTI)

The Muon Ionization Cooling Experiment (MICE) willdemonstrate ionization cooling in a short section of a realistic coolingchannel using a muon beam at Rutherford Appleton Laboratory (RAL) in theUK. A five-coil, superconducting spectrometer solenoid magnet at each endof the cooling channel will provide a 4 T uniform field region for thescintillating fiber tracker within the magnet bore tubes. The trackermodules are used to measure the muon beam emittance as it enters andexits the cooling channel. The cold mass for the 400 mm warm bore magnetconsists of two sections: a three-coil spectrometer magnet and a two-coilmatching section that matches the uniform field of the solenoid into theMICE cooling channel. The spectrometer solenoid detailed designandanalysis has been completed, and the fabrication of the magnets is wellunder way. The primary features of the spectrometer solenoid magnet andmechanical designs are presented along with a summary of key fabricationissues and photos of the construction.

Virostek, S.P.; Green, M.A.; Lia, D.; Sizman, M.S.

2007-06-20T23:59:59.000Z

159

Mass Spectrometer: Linear Ion Trap Quadrupole (LTQ) Orbitrap...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ion Trap Quadrupole (LTQ) Orbitrap MS - for environmental research (nanoDESI) Instrument ID: 34068 Availability: 10 hours a day, 5 days a week Quick Specs Science Contact Science...

160

Time of Flight Secondary Ion Mass Spectrometer | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the high vapor... A Segmented, Enriched N-type Germanium Detector for Neutrinoless Double Beta-Decay Experiments. We present data characterizing the performance of the rst...

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

BREAKING NEWS! EMSL's 21 T mass spectrometer at field | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation InInformationCenterResearch HighlightsToolsBES ReportsExperiment Rainarticle featured

162

Mass Spectrometer: Aerosol, time-of-flight, high resolution | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selected asMaratMary Louise SpaethAerosol,

163

Mass Spectrometer: Ion Mobility Spectrometry, Time of Flight | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selected asMaratMary Louise(ElementIon Mobility

164

Mass Spectrometer: Linear Ion Trap Quadrupole (LTQ) Orbitrap MS - for  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selected asMaratMary Louise(ElementIon

165

Accurate determination of Curium and Californium isotopic ratios by inductively coupled plasma quadrupole mass spectrometry (ICP-QMS) in 248Cm samples for transmutation studies  

SciTech Connect (OSTI)

The French Atomic Energy Commission has carried out several experiments including the mini-INCA (INcineration of Actinides) project for the study of minor-actinide transmutation processes in high intensity thermal neutron fluxes, in view of proposing solutions to reduce the radiotoxicity of long-lived nuclear wastes. In this context, a Cm sample enriched in {sup 248}Cm ({approx}97 %) was irradiated in thermal neutron flux at the High Flux Reactor (HFR) of the Laue-Langevin Institute (ILL). This work describes a quadrupole ICP-MS (ICP-QMS) analytical procedure for precise and accurate isotopic composition determination of Cm before sample irradiation and of Cm and Cf after sample irradiation. The factors that affect the accuracy and reproducibility of isotopic ratio measurements by ICP-QMS, such as peak centre correction, detector dead time, mass bias, abundance sensitivity and hydrides formation, instrumental background, and memory blank were carefully evaluated and corrected. Uncertainties of the isotopic ratios, taking into account internal precision of isotope ratio measurements, peak tailing, and hydrides formations ranged from 0.3% to 1.3%. This uncertainties range is quite acceptable for the nuclear data to be used in transmutation studies.

Gourgiotis, A.; Isnard, H.; Aubert, M.; Dupont, E.; AlMahamid, I.; Cassette, P.; Panebianco, S.; Letourneau, A.; Chartier, F.; Tian, G.; Rao, L.; Lukens, W.

2011-02-01T23:59:59.000Z

166

Soluble arsenic and selenium species in fly ash/organic waste-amended soils using ion chromatography-inductively coupled plasma mass spectrometry  

SciTech Connect (OSTI)

Mixing coal fly ash with an organic waste increases macronutrient content and may make land application of fly ash a viable disposal alternative. However, trace element chemistry of these mixed waste products warrants investigation. Speciation of As and Se in soil solutions of fly ash-, poultry litter- and sewage sludge-amended soils was determined over a 10-day period by ion chromatography coupled to inductively coupled plasma mass spectrometry (IC-ICP-MS). Detection limits were 0.031, 0.028, 0.051, 0.161, 0.497, and 0.660 {micro}g L{sup {minus}1} for dimethylarsinate (DMA), As(III), monomethylarsonate (MMA), As(V), Se(IV), and Se(VI), respectively. Arsenic was highly water-soluble from poultry litter and appeared to be predominantly As(V). Arsenic(V) was the predominant species in soil amended with two fly ashes. Application of fly ash/poultry litter mixtures increased As solubility and led to the prevalence of DMA as the major As species. DMA concentrations of these soil solutions decreased rapidly over the sampling period relative to As(V), suggesting that DMA readily underwent mineralization in the soil solution. Se(VI) was the predominant soluble Se species in all treatments indicating rapid oxidation of Se(IV) initially solubilized from the fly ashes.

Jackson, B.P.; Miller, W.P. [Univ. of Georgia, Athens, GA (United States). Dept. of Crop and Soil Sciences] [Univ. of Georgia, Athens, GA (United States). Dept. of Crop and Soil Sciences

1999-01-15T23:59:59.000Z

167

SWEPP Gamma-Ray Spectrometer System software design description  

SciTech Connect (OSTI)

To assist in the characterization of the radiological contents of contract-handled waste containers at the Stored Waste Examination Pilot Plant (SWEPP), the SWEPP Gamma-Ray Spectrometer (SGRS) System has been developed by the Radiation Measurements and Development Unit of the Idaho National Engineering Laboratory. The SGRS system software controls turntable and detector system activities. In addition to determining the concentrations of gamma-ray-emitting radionuclides, this software also calculates attenuation-corrected isotopic mass ratios of-specific interest. This document describes the software design for the data acquisition and analysis software associated with the SGRS system.

Femec, D.A.; Killian, E.W.

1994-08-01T23:59:59.000Z

168

SPEC-DOC: A USER'S GUIDE TO SPECTROMETER SOFTWARE  

E-Print Network [OSTI]

SPECTROMETER SOFTWARE S. Sinton, J.R. Garbow, J.L. Ackerman,to Spectrometer Software" S. Sinton, J. R. Garbow, J. L.

Sinton, S.

2008-01-01T23:59:59.000Z

169

Preparation and Characterization of High-Purity Metal Fluorides for Photonic Applications*  

E-Print Network [OSTI]

is quantified directly by inductively cou- pled plasma mass spectrometry (ICP-MS) and indirectly by laser,4­7 scintillators,8,9 up-con- version phosphors,10 solid-state optical refrigerators,11 and emerging crystals

Sheik-Bahae, Mansoor

170

Visible spectrometer utilizing organic thin film absorption  

E-Print Network [OSTI]

In this thesis, I modeled and developed a spectrometer for the visible wavelength spectrum, based on absorption characteristics of organic thin films. The device uses fundamental principles of linear algebra to reconstruct ...

Tiefenbruck, Laura C. (Laura Christine)

2004-01-01T23:59:59.000Z

171

A SUPERCONDUCTING-SOLENOID ISOTOPE SPECTROMETER  

E-Print Network [OSTI]

A SUPERCONDUCTING-SOLENOID ISOTOPE SPECTROMETER FOR PRODUCTION OF NEUTRON-RICH NUCLEI ( 136 Xe Superconducting Cyclotron Laboratory's weekly \\Green Sheet," 30 July 1999 #12; c Thomas W. O'Donnell 2000 All

O'Donnell, Tom

172

Optical Calibration For Jefferson Lab HKS Spectrometer  

E-Print Network [OSTI]

In order to accept very forward angle scattering particles, Jefferson Lab HKS experiment uses an on-target zero degree dipole magnet. The usual spectrometer optics calibration procedure has to be modified due to this on-target field. This paper describes a new method to calibrate HKS spectrometer system. The simulation of the calibration procedure shows the required resolution can be achieved from initially inaccurate optical description.

L. Yuan; L. Tang

2005-11-04T23:59:59.000Z

173

aerosol time-of-flight mass: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Theses and Dissertations Summary: ??The construction of a liquid nitrogen-cooled ion mobility spectrometer coupled with time-of-flight mass spectrometry was implemented to...

174

Chip-scale quadrupole mass filters for a Micro-Gas Analyzer  

E-Print Network [OSTI]

Mass spectrometers are powerful analytical instruments that serve as the gold standard for chemical analysis. This tool has numerous applications ranging from national security, industrial processing, environmental monitoring, ...

Cheung, Kerry

2009-01-01T23:59:59.000Z

175

Wide size range fast integrated mobility spectrometer  

DOE Patents [OSTI]

A mobility spectrometer to measure a nanometer particle size distribution is disclosed. The mobility spectrometer includes a conduit and a detector. The conduit is configured to receive and provide fluid communication of a fluid stream having a charged nanometer particle mixture. The conduit includes a separator section configured to generate an electrical field of two dimensions transverse to a dimension associated with the flow of the charged nanometer particle mixture through the separator section to spatially separate charged nanometer particles of the charged nanometer particle mixture in said two dimensions. The detector is disposed downstream of the conduit to detect concentration and position of the spatially-separated nanometer particles.

Wang, Jian

2013-10-29T23:59:59.000Z

176

Compact Imaging Spectrometer Utilizing Immersed Gratings  

DOE Patents [OSTI]

A compact imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The imaging spectrometer comprises an entrance slit for transmitting light, a system for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the system for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the system for receiving the light and the system for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light through an optical element to the detector array.

Chrisp, Michael P. (Danville, CA); Lerner, Scott A. (Corvallis, OR); Kuzmenko, Paul J. (Livermore, CA); Bennett, Charles L. (Livermore, CA)

2006-03-21T23:59:59.000Z

177

The response of a Bonner Sphere spectrometer to charged hadrons  

E-Print Network [OSTI]

Bonner sphere spectrometers (BSSs) are employed in neutron spectrometry and dosimetry since many years. Recent developments have seen the addition to a conventional BSS of one or more detectors (moderator plus thermal neutron counter) specifically designed to improve the overall response of the spectrometer to neutrons above 10 MeV. These additional detectors employ a shell of material with a high mass number (such as lead) within the polyethylene moderator, in order to slow down high-energy neutrons via (n, xn) reactions. A BSS can be used to measure neutron spectra both outside accelerator shielding and from an unshielded target. Measurements were recently performed at CERN of the neutron yield and spectral fluence at various angles from unshielded, semithick copper, silver and lead targets, bombarded by a mixed proton/pion beam with 40 GeV per c momentum. These experiments have provided evidence that under certain circumstances, the use of lead-enriched moderators may present a problem: these detectors wer...

Agosteo, S; Fassò, A; Silari, M; 10.1093/rpd/nch187

2004-01-01T23:59:59.000Z

178

Lens system for a photo ion spectrometer  

DOE Patents [OSTI]

A lens system in a photo ion spectrometer for manipulating a primary ion beam and ionized atomic component is disclosed. The atomic components are removed from a sample by a primary ion beam using the lens system, and the ions are extracted for analysis. The lens system further includes ionization resistant coatings for protecting the lens system. 8 figs.

Gruen, D.M.; Young, C.E.; Pellin, M.J.

1990-11-27T23:59:59.000Z

179

Study of elementary reactions with the HADES dielectron spectrometer  

E-Print Network [OSTI]

Results obtained with the HADES dielectron spectrometer at GSI are discussed, with emphasis on dilepton production in elementary reactions.

B. Ramstein

2009-12-14T23:59:59.000Z

180

Study of elementary reactions with the HADES dielectron spectrometer  

E-Print Network [OSTI]

Results obtained with the HADES dielectron spectrometer at GSI are discussed, with emphasis on dilepton production in elementary reactions.

,

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

High Precision Atomic Mass Spectrometry with Applications to Neutrino Physics, Fundamental Constants and Physical Chemistry.  

E-Print Network [OSTI]

?? The Florida State University single-ion cryogenic Penning trap mass spectrometer has been used to precisely measure the masses of the doublets 76Ge/76Se and 74Ge/74Se… (more)

Mount, Brianna Jane

2010-01-01T23:59:59.000Z

182

Structural determination of intact proteins using mass spectrometry  

DOE Patents [OSTI]

The present invention relates to novel methods of determining the sequence and structure of proteins. Specifically, the present invention allows for the analysis of intact proteins within a mass spectrometer. Therefore, preparatory separations need not be performed prior to introducing a protein sample into the mass spectrometer. Also disclosed herein are new instrumental developments for enhancing the signal from the desired modified proteins, methods for producing controlled protein fragments in the mass spectrometer, eliminating complex microseparations, and protein preparatory chemical steps necessary for cross-linking based protein structure determination.Additionally, the preferred method of the present invention involves the determination of protein structures utilizing a top-down analysis of protein structures to search for covalent modifications. In the preferred method, intact proteins are ionized and fragmented within the mass spectrometer.

Kruppa, Gary (San Francisco, CA); Schoeniger, Joseph S. (Oakland, CA); Young, Malin M. (Livermore, CA)

2008-05-06T23:59:59.000Z

183

Mass spec : the biography of a scientific instrument  

E-Print Network [OSTI]

Over the past century, the mass spectrometer has become commonplace in scientific fields ranging from chemistry to geology to environmental science. Its ability to identify compounds and determine concentrations of those ...

Calmes, Jordan

2011-01-01T23:59:59.000Z

184

Acceptance and resolution simulation studies for the dielectron spectrometer HADES at GSI  

E-Print Network [OSTI]

Design studies for a second generation Dilepton Spectrometer to be built at the SIS accelerator of GSI are presented. The basic design parameters of this system are specified and the different detector components for charged particle tracking and for lepton identification are described. The geometrical acceptance for lepton pairs is given. Results on single track momentum resolution and on lepton pair mass resolution are reported.

R. Schicker; A. Brenschede; K. Garrow; H. Schoen; A. Balanda; H. Bokemeyer; J. Friese; W. Karig; P. Kienle; W. Koenig; W. Kuehn; F. Lefevre; V. Metag; G. Roche; P. Salabura; A. Schroeter; J. Stroth; H. Tsertos

1996-05-21T23:59:59.000Z

185

Imaging spectrometer wide field catadioptric design  

DOE Patents [OSTI]

A wide field catadioptric imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The catadioptric design has zero Petzval field curvature. The imaging spectrometer comprises an entrance slit for transmitting light, a system with a catadioptric lens and a dioptric lens for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the system for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the system for receiving the light and the system for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light through the system for receiving the light to the detector array.

Chrisp; Michael P. (Danville, CA)

2008-08-19T23:59:59.000Z

186

Neutron spectrometer for improved SNM search.  

SciTech Connect (OSTI)

With the exception of large laboratory devices with very low sensitivities, a neutron spectrometer have not been built for fission neutrons such as those emitted by special nuclear materials (SNM). The goal of this work was to use a technique known as Capture Gated Neutron Spectrometry to develop a solid-state device with this functionality. This required modifications to trans-stilbene, a known solid-state scintillator. To provide a neutron capture signal we added lithium to this material. This unique triggering signal allowed identification of neutrons that lose all of their energy in the detector, eliminating uncertainties that arise due to partial energy depositions. We successfully implemented a capture gated neutron spectrometer and were able to distinguish an SNM like fission spectrum from a spectrum stemming from a benign neutron source.

Vance, Andrew L.; Aigeldinger, Georg

2007-03-01T23:59:59.000Z

187

Compact imaging spectrometer utilizing immersed gratings  

DOE Patents [OSTI]

A compact imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The imaging spectrometer comprises an entrance slit for transmitting light, means for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the means for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the means for receiving the light and the means for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light to the means for receiving the light, and the means for receiving the light directs the light to the detector array.

Chrisp, Michael P. (Danville, CA); Lerner, Scott A. (Corvallis, OR); Kuzmenko, Paul J. (Livermore, CA); Bennett, Charles L. (Livermore, CA)

2007-07-03T23:59:59.000Z

188

Associated Particle Tagging (APT) in Magnetic Spectrometers  

SciTech Connect (OSTI)

Summary In Brief The Associated Particle Tagging (APT) project, a collaboration of Pacific Northwest National Laboratory (PNNL), Idaho National Laboratory (INL) and the Idaho State University (ISU)/Idaho Accelerator Center (IAC), has completed an exploratory study to assess the role of magnetic spectrometers as the linchpin technology in next-generation tagged-neutron and tagged-photon active interrogation (AI). The computational study considered two principle concepts: (1) the application of a solenoidal alpha-particle spectrometer to a next-generation, large-emittance neutron generator for use in the associated particle imaging technique, and (2) the application of tagged photon beams to the detection of fissile material via active interrogation. In both cases, a magnetic spectrometer momentum-analyzes charged particles (in the neutron case, alpha particles accompanying neutron generation in the D-T reaction; in the tagged photon case, post-bremsstrahlung electrons) to define kinematic properties of the relevant neutral interrogation probe particle (i.e. neutron or photon). The main conclusions of the study can be briefly summarized as follows: Neutron generator: • For the solenoidal spectrometer concept, magnetic field strengths of order 1 Tesla or greater are required to keep the transverse size of the spectrometer smaller than 1 meter. The notional magnetic spectrometer design evaluated in this feasibility study uses a 5-T magnetic field and a borehole radius of 18 cm. • The design shows a potential for 4.5 Sr tagged neutron solid angle, a factor of 4.5 larger than achievable with current API neutron-generator designs. • The potential angular resolution for such a tagged neutron beam can be less than 0.5o for modest Si-detector position resolution (3 mm). Further improvement in angular resolution can be made by using Si-detectors with better position resolution. • The report documents several features of a notional generator design incorporating the alpha-particle spectrometer concept, and outlines challenges involved in the magnetic field design. Tagged photon interrogation: • We investigated a method for discriminating fissile from benign cargo-material response to an energy-tagged photon beam. The method relies upon coincident detection of the tagged photon and a photoneutron or photofission neutron produced in the target material. The method exploits differences in the shape of the neutron production cross section as a function of incident photon energy in order to discriminate photofission yield from photoneutrons emitted by non-fissile materials. Computational tests of the interrogation method as applied to material composition assay of a simple, multi-layer target suggest that the tagged-photon information facilitates precise (order 1% thickness uncertainty) reconstruction of the constituent thicknesses of fissile (uranium) and high-Z (Pb) constituents of the test targets in a few minutes of photon-beam exposure. We assumed an 18-MeV endpoint tagged photon beam for these simulations. • The report addresses several candidate design and data analysis issues for beamline infrastructure required to produce a tagged photon beam in a notional AI-dedicated facility, including the accelerator and tagging spectrometer.

Jordan, David V.; Baciak, James E.; Stave, Sean C.; Chichester, David; Dale, Daniel; Kim, Yujong; Harmon, Frank

2012-10-16T23:59:59.000Z

189

Progress on the Fabrication and Testing of the MICE Spectrometer Solenoids  

SciTech Connect (OSTI)

The Muon Ionization Cooling Experiment (MICE) is an international collaboration that will demonstrate ionization cooling in a section of a realistic cooling channel using a muon beam at Rutherford Appleton Laboratory (RAL) in the UK. At each end of the cooling channel a spectrometer solenoid magnet consisting of five superconducting coils will provide a 4 tesla uniform field region. The scintillating fiber tracker within the magnet bore will measure the muon beam emittance as it enters and exits the cooling channel. The 400 mm diameter warm bore, 3 meter long magnets incorporate a cold mass consisting of two coil sections wound on a single aluminum mandrel: a three-coil spectrometer magnet and a two-coil section that matches the solenoid uniform field into the MICE cooling channel. The fabrication of the first of two spectrometer solenoids has been completed, and preliminary testing of the magnet is nearly complete. The key design features of the spectrometer solenoid magnets are presented along with a summary of the progress on the training and testing of the first magnet.

Virostek, Steve; Green, M.A.; Li, Derun; Zisman, Michael

2009-05-19T23:59:59.000Z

190

A laser-ablation ICP-MS study of Apollo 15 low-titanium olivine-normative and quartz-normative mare basalts  

E-Print Network [OSTI]

differences in the mantle source to explain the $25% difference in whole-rock TiO2, and corresponding-normative basalt types, based on their different SiO2, FeO, and TiO2 whole-rock compositions. Previous studies have as originating from different lunar mantle source regions. To provide new information on the compositions

Perfect, Ed

191

Heterogeneous Chemistry of Individual Mineral Dust Particles with Nitric Acid. A Combined CCSEM/EDX, ESEM AND ICP-MS Study  

SciTech Connect (OSTI)

The heterogeneous chemistry of individual dust particles from four authentic dust samples with gas-phase nitric acid was investigated in this study. Morphology and compositional changes of individual particles as they react with nitric acid were observed using conventional scanning electron microscopy with energy dispersive analysis of X-rays (SEM/EDX) and computer controlled SEM/EDX. Environmental Scanning Electron Microscopy (ESEM) was utilized to investigate the hygroscopic behavior of mineral dust particles reacted with nitric acid. Differences in the reactivity of mineral dust particles from these four different dust source regions with nitric acid were observed. Mineral dust from source regions containing high levels of calcium, namely China loess dust and Saudi coastal dust, were found to react to the greatest extent.

Laskin, Alexander; Wietsma, Thomas W.; Krueger, Brenda J.; Grassian, Vicki H.

2005-05-26T23:59:59.000Z

192

Dual waveband compact catadioptric imaging spectrometer  

DOE Patents [OSTI]

A catadioptric dual waveband imaging spectrometer that covers the visible through short-wave infrared, and the midwave infrared spectral regions, dispersing the visible through shortwave infrared with a zinc selenide grating and midwave infrared with a sapphire prism. The grating and prism are at the cold stop position, enabling the pupil to be split between them. The spectra for both wavebands are focused onto the relevant sections of a single dual waveband detector. Spatial keystone distortion is controlled to less than one tenth of a pixel over the full wavelength range, facilitating the matching of the spectra in the midwave infrared with the shorter wavelength region.

Chrisp, Michael P.

2012-12-25T23:59:59.000Z

193

Lead Slowing Down Spectrometer Status Report  

SciTech Connect (OSTI)

This report documents the progress that has been completed in the first half of FY2012 in the MPACT-funded Lead Slowing Down Spectrometer project. Significant progress has been made on the algorithm development. We have an improve understanding of the experimental responses in LSDS for fuel-related material. The calibration of the ultra-depleted uranium foils was completed, but the results are inconsistent from measurement to measurement. Future work includes developing a conceptual model of an LSDS system to assay plutonium in used fuel, improving agreement between simulations and measurement, design of a thorium fission chamber, and evaluation of additional detector techniques.

Warren, Glen A.; Anderson, Kevin K.; Bonebrake, Eric; Casella, Andrew M.; Danon, Yaron; Devlin, M.; Gavron, Victor A.; Haight, R. C.; Imel, G. R.; Kulisek, Jonathan A.; O'Donnell, J. M.; Weltz, Adam

2012-06-07T23:59:59.000Z

194

Ion mobility spectrometer with virtual aperture grid  

DOE Patents [OSTI]

An ion mobility spectrometer does not require a physical aperture grid to prevent premature ion detector response. The last electrodes adjacent to the ion collector (typically the last four or five) have an electrode pitch that is less than the width of the ion swarm and each of the adjacent electrodes is connected to a source of free charge, thereby providing a virtual aperture grid at the end of the drift region that shields the ion collector from the mirror current of the approaching ion swarm. The virtual aperture grid is less complex in assembly and function and is less sensitive to vibrations than the physical aperture grid.

Pfeifer, Kent B. (Los Lunas, NM); Rumpf, Arthur N. (Albuquerque, NM)

2010-11-23T23:59:59.000Z

195

Micro-optical-mechanical system photoacoustic spectrometer  

DOE Patents [OSTI]

All-optical photoacoustic spectrometer sensing systems (PASS system) and methods include all the hardware needed to analyze the presence of a large variety of materials (solid, liquid and gas). Some of the all-optical PASS systems require only two optical-fibers to communicate with the opto-electronic power and readout systems that exist outside of the material environment. Methods for improving the signal-to-noise are provided and enable mirco-scale systems and methods for operating such systems.

Kotovsky, Jack; Benett, William J.; Tooker, Angela C.; Alameda, Jennifer B.

2013-01-01T23:59:59.000Z

196

Wide swath imaging spectrometer utilizing a multi-modular design  

DOE Patents [OSTI]

A wide swath imaging spectrometer utilizing an array of individual spectrometer modules in the telescope focal plane to provide an extended field of view. The spectrometer modules with their individual detectors are arranged so that their slits overlap with motion on the scene providing contiguous spatial coverage. The number of modules can be varied to take full advantage of the field of view available from the telescope.

Chrisp, Michael P. (Danville, CA)

2010-10-05T23:59:59.000Z

197

antiparticle spectrometer gaps: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Next Page Last Page Topic Index 1 The General Antiparticle Spectrometer (GAPS) - Hunt for dark matter using low-energy antideuterons CERN Preprints Summary: The GAPS experiment is...

198

Ultra-high-mass mass spectrometry with charge discrimination using cryogenic detectors  

DOE Patents [OSTI]

An ultra-high-mass time-of-flight mass spectrometer using a cryogenic particle detector as an ion detector with charge discriminating capabilities. Cryogenic detectors have the potential for significantly improving the performance and sensitivity of time-of-flight mass spectrometers, and compared to ion multipliers they exhibit superior sensitivity for high-mass, slow-moving macromolecular ions and can be used as "stop" detectors in time-of-flight applications. In addition, their energy resolving capability can be used to measure the charge state of the ions. Charge discrimination is very valuable in all time-of-flight mass spectrometers. Using a cryogenically-cooled Nb-Al.sub.2 O.sub.3 -Nb superconductor-insulator-superconductor (SIS) tunnel junction (STJ) detector operating at 1.3 K as an ion detector in a time-of-flight mass spectrometer for large biomolecules it was found that the STJ detector has charge discrimination capabilities. Since the cryogenic STJ detector responds to ion energy and does not rely on secondary electron production, as in the conventionally used microchannel plate (MCP) detectors, the cryogenic detector therefore detects large molecular ions with a velocity-independent efficiency approaching 100%.

Frank, Matthias (Berkeley, CA); Mears, Carl A. (Oakland, CA); Labov, Simon E. (Berkeley, CA); Benner, W. Henry (Danville, CA)

1999-01-01T23:59:59.000Z

199

Lead iodide X-ray and gamma-ray spectrometers for room and high temperature operation  

SciTech Connect (OSTI)

In this study the authors report on the results of the investigation of lead iodide material properties. The effectiveness of a zone refining purification method on the material purity is determined by ICP-MS and ICP-OES and correlated to the electrical and physical material properties. They show that this zone refining method is very efficient in removing impurities from lead iodide, and they also determine the segregation coefficient for some of these impurities. Triple axis X-ray diffraction (TAD) analysis has been used to determine the crystalline perfection of the lead iodide after applying various cutting, etching and fabrication methods. The soft lead iodide crystal was found to be damaged when cleaved by a razor blade, but by using a diamond wheel saw, followed by etching, the crystallinity of the material was much improved, as observed by TAD. Low temperature photoluminescence also indicates an improvement in the material properties of the purified lead iodide. Electrical properties of lead iodide such as carrier mobility, were calculated based on carrier-phonon scattering. The results for the electrical properties were in good agreement with the experimental data.

Hermon, H.; James, R.B.; Lund, J. [Sandia National Labs., Livermore, CA (United States)] [and others

1998-12-31T23:59:59.000Z

200

Lead iodide X-ray and gamma-ray spectrometers for room and high temperature operation  

SciTech Connect (OSTI)

In this study, we report on the results of the investigation of lead iodide material properties. The effectiveness of zone refining purification methods on the material purity is determined by ICP-MS and ICP-OES and correlated to the electrical and physical material properties. We show that this zone refining method is very efficient in removing impurities from lead iodide and we also determine the segregation coefficient for some of these impurities. Triple axis x- ray diffraction (TAD) analysis has been used to determine the crystalline perfection of the lead iodide after applying various cutting, etching, and fabrication methods. The soft lead iodide crystal was found to be damaged when cleaved by a razor blade, but by using a diamond wheel saw, followed by etching, the crystallinity of the material was improved, as observed by TAD. Low temperature photoluminescence also indicates an improvement in the material properties of the purified lead iodide. Electrical properties of lead iodide such as carrier mobility, were calculated based on carrier- phonon scattering. The results for the electrical properties were in good agreement with the experimental data.

Hermon, H.; James, R.B.; Cross, E. [and others

1997-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Ion mobility spectrometer, spectrometer analyte detection and identification verification system, and method  

DOE Patents [OSTI]

Methods and apparatus for ion mobility spectrometry and analyte detection and identification verification system are disclosed. The apparatus is configured to be used in an ion mobility spectrometer and includes a plurality of reactant reservoirs configured to contain a plurality of reactants which can be reacted with the sample to form adducts having varying ion mobilities. A carrier fluid, such as air or nitrogen, is used to carry the sample into the spectrometer. The plurality of reactants are configured to be selectively added to the carrier stream by use inlet and outlet manifolds in communication with the reagent reservoirs, the reservoirs being selectively isolatable by valves. The invention further includes a spectrometer having the reagent system described. In the method, a first reactant is used with the sample. Following a positive result, a second reactant is used to determine whether a predicted response occurs. The occurrence of the second predicted response tends to verify the existence of a component of interest within the sample. A third reactant can also be used to provide further verification of the existence of a component of interest. A library can be established of known responses of compounds of interest with various reactants and the results of a specific multi-reactant survey of a sample can be compared against the library to determine whether a component detected in the sample is likely to be a specific component of interest.

Atkinson, David A. (Idaho Falls, ID)

2002-01-01T23:59:59.000Z

202

Detection Efficiency of a ToF Spectrometer from Heavy-Ion Elastic Recoil Detection  

SciTech Connect (OSTI)

The detection efficiency of a time-of-flight system based on two micro-channel plates (MCP) time zero detectors plus a conventional silicon surface barrier detector was obtained from heavy ion elastic recoil measurements (this ToF spectrometer is mainly devoted to measurements of total fusion cross section of weakly bound projectiles on different mass-targets systems). In this work we have used beams of {sup 7}Li, {sup 16}O, {sup 32}S and {sup 35}Cl to study the mass region of interest for its application to measurements fusion cross sections in the {sup 6,7}Li+{sup 27}Al systems at energies around and above the Coulomb barrier (0.8V{sub B{<=}}E{<=}2.0V{sub B}). As the efficiency of a ToF spectrometer is strongly dependent on the energy and mass of the detected particles, we have covered a wide range of the scattered particle energies with a high degree of accuracy at the lowest energies. The different experimental efficiency curves obtained in that way were compared with theoretical electronic stopping power curves on carbon foils and were applied.

Barbara, E. de; Marti, G. V.; Capurro, O. A.; Fimiani, L.; Mingolla, M. G. [Laboratorio ANDAR, Comision Nacional de Energia Atomica, Av. Gral. Paz 1499, B1650KNA Partido de San Martin, Provincia de Buenos Aires (Argentina); Negri, A. E.; Arazi, A.; Figueira, J. M.; Pacheco, A. J.; Martinez Heimann, D.; Carnelli, P. F. F. [Laboratorio ANDAR, Comision Nacional de Energia Atomica, Av. Gral. Paz 1499, B1650KNA Partido de San Martin, Provincia de Buenos Aires (Argentina); CONICET, Av. Rivadavia 1917, C1033AAJ Ciudad Autonoma de Buenos Aires (Argentina); Fernandez Niello, J. O. [Laboratorio ANDAR, Comision Nacional de Energia Atomica, Av. Gral. Paz 1499, B1650KNA Partido de San Martin, Provincia de Buenos Aires (Argentina); CONICET, Av. Rivadavia 1917, C1033AAJ Ciudad Autonoma de Buenos Aires (Argentina); Universidad Nacional de General San Martin, Ayacucho 2197, B1650BWA Partido de San Martin, Provincia de Buenos Aires (Argentina)

2010-08-04T23:59:59.000Z

203

The EUV Imaging Spectrometer for Hinode  

SciTech Connect (OSTI)

The EUV Imaging Spectrometer (EIS) on Hinode will observe solar corona and upper transition region emission lines in the wavelength ranges 170?-?210 Angstroms and 250?-?290 Angstroms . The line centroid positions and profile widths will allow plasma velocities and turbulent or non-thermal line broadenings to be measured. We will derive local plasma temperatures and densities from the line intensities. The spectra will allow accurate determination of differential emission measure and element abundances within a variety of corona and transition region structures. These powerful spectroscopic diagnostics will allow identification and characterization of magnetic reconnection and wave propagation processes in the upper solar atmosphere. We will also directly study the detailed evolution and heating of coronal loops. The EIS instrument incorporates a unique two element, normal incidence design. The optics are coated with optimized multilayer coatings. We have selected highly efficient, backside-illuminated, thinned CCDs. These design features result in an instrument that has significantly greater effective area than previous orbiting EUV spectrographs with typical active region 2?-?5 s exposure times in the brightest lines. EIS can scan a field of 6x8.5 arc?min with spatial and velocity scales of 1 arc?sec and 25 km?s-1 per pixel. The instrument design, its absolute calibration, and performance are described in detail in this paper. EIS will be used along with the Solar Optical Telescope (SOT) and the X-ray Telescope (XRT) for a wide range of studies of the solar atmosphere.

Culhane,J.; Harra, L.; James, A.; Al-Janabi, K.; Bradley, L.; Chaudry, R.; Rees, K.; Tandy, J.; Thomas, P.; et al

2007-01-01T23:59:59.000Z

204

Improving the resolution of chopper spectrometers at pulsed neutron sources  

SciTech Connect (OSTI)

We examine the relationships between intensity and resolution in pulsed-source chopper spectrometers, including the effects of Soller collimation, narrower rotor slits and higher rotor speeds. The basis is a simplified description of a spectrometer, approximately optimizing the rotor pulse and lighthouse effects. the analysis includes a new treatment of the angular distribution transmitted through a system consisting of a coarse collimator and a Soller collimator. The results encourage the prospect for a reasonably easily accomplished, higher resolution, optional configuration of the pulsed source chopper spectrometers at IPNS. 6 refs., 5 figs.

Carpenter, J.M. (Argonne National Lab., IL (USA)); Mildner, D.F.R. (National Bureau of Standards, Washington, DC (USA). Center for Analytical Chemistry)

1990-01-01T23:59:59.000Z

205

Organic aerosol components observed in Northern Hemispheric datasets from Aerosol Mass Spectrometry  

E-Print Network [OSTI]

In this study we compile and present results from the factor analysis of 43 Aerosol Mass Spectrometer (AMS) datasets (27 of the datasets are reanalyzed in this work). The components from all sites, when taken together, ...

Kroll, Jesse

206

A study of the tropospheric oxidation of volatile organic compounds using chemical ionization mass spectrometry  

E-Print Network [OSTI]

The mechanisms and kinetics of reactions important to the troposphere have been investigated using a high pressure, turbulent, discharge-flow technique coupled to a chemical ionization mass spectrometer. The ability to ...

Broekhuizen, Keith Edward, 1974-

2002-01-01T23:59:59.000Z

207

Determination of particulate lead using aerosol mass spectrometry: MILAGRO/MCMA-2006 observations  

E-Print Network [OSTI]

We report the first measurements of particulate lead (Pb) from Aerodyne Aerosol Mass Spectrometers, which were deployed in and around Mexico City during the Megacity Initiative: Local and Global Research Observations ...

Salcedo, D.

208

An Analysis of Nuclear Fuel Burnup in the AGR 1 TRISO Fuel Experiment Using Gamma Spectrometry, Mass Spectrometry, and Computational Simulation Techniques  

SciTech Connect (OSTI)

AGR 1 was the first in a series of experiments designed to test US TRISO fuel under high temperature gas-cooled reactor irradiation conditions. This experiment was irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) and is currently undergoing post irradiation examination (PIE) at INL and Oak Ridge National Laboratory. One component of the AGR 1 PIE is the experimental evaluation of the burnup of the fuel by two separate techniques. Gamma spectrometry was used to non destructively evaluate the burnup of all 72 of the TRISO fuel compacts that comprised the AGR 1 experiment. Two methods for evaluating burnup by gamma spectrometry were developed, one based on the Cs 137 activity and the other based on the ratio of Cs 134 and Cs 137 activities. Burnup values determined from both methods compared well with the values predicted from simulations. The highest measured burnup was 20.1 %FIMA for the direct method and 20.0 %FIMA for the ratio method (compared to 19.56% FIMA from simulations). An advantage of the ratio method is that the burnup of the cylindrical fuel compacts can determined in small (2.5 mm) axial increments and an axial burnup profile can be produced. Destructive chemical analysis by inductively coupled mass spectrometry (ICP MS) was then performed on selected compacts that were representative of the expected range of fuel burnups in the experiment to compare with the burnup values determined by gamma spectrometry. The compacts analyzed by mass spectrometry had a burnup range of 19.3 % FIMA to 10.7 % FIMA. The mass spectrometry evaluation of burnup for the four compacts agreed well with the gamma spectrometry burnup evaluations and the expected burnup from simulation. For all four compacts analyzed by mass spectrometry, the maximum range in the three experimentally determined values and the predicted value was 6% or less. The results confirm the accuracy of the nondestructive burnup evaluation from gamma spectrometry for TRISO fuel compacts across a burnup range of approximately 10 to 20 % FIMA and also validate the approach used in the physics simulation of the AGR 1 experiment.

Jason M. Harp; Paul A. Demkowicz; Phillip L. Winston; James W. Sterbentz

2014-10-01T23:59:59.000Z

209

Temperature response of the ultra-high throughput mutational spectrometer  

E-Print Network [OSTI]

The Ultra-High Throughput Mutational Spectrometer is an instrument designed to separate mutant from wild type DNA through capillary electrophoresis. Since this technique uses the melting point of the molecule to distinguish ...

Suen, Timothy W. (Timothy Wu)

2005-01-01T23:59:59.000Z

210

The FIRE infrared spectrometer at Magellan: construction and commissioning  

E-Print Network [OSTI]

We describe the construction and commissioning of FIRE, a new 0.8-2.5?m echelle spectrometer for the Magellan/ Baade 6.5 meter telescope. FIRE delivers continuous spectra over its full bandpass with nominal spectral ...

Simcoe, Robert A.

211

airborne imaging spectrometer: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ADC dynamic range, because the low-energy pulse signal has a larger gain than the high-energy pulse signal. The spectrometer can clearly distinguish the photopeaks at 239, 352,...

212

Diamond neutral particle spectrometer for fusion reactor ITER  

SciTech Connect (OSTI)

A compact diamond neutral particle spectrometer with digital signal processing has been developed for fast charge-exchange atoms and neutrons measurements at ITER fusion reactor conditions. This spectrometer will play supplementary role for Neutral Particle Analyzer providing 10 ms time and 30 keV energy resolutions for fast particle spectra in non-tritium ITER phase. These data will also be implemented for independent studies of fast ions distribution function evolution in various plasma scenarios with the formation of a single fraction of high-energy ions. In tritium ITER phase the DNPS will measure 14 MeV neutrons spectra. The spectrometer with digital signal processing can operate at peak counting rates reaching a value of 10{sup 6} cps. Diamond neutral particle spectrometer is applicable to future fusion reactors due to its high radiation hardness, fast response and high energy resolution.

Krasilnikov, V.; Amosov, V.; Kaschuck, Yu.; Skopintsev, D. [Institution PROJECT CENTER ITER, 1, Akademik Kurchatov Sq., Moscow (Russian Federation)

2014-08-21T23:59:59.000Z

213

The X-ray Microcalorimeter Spectrometer onboard of IXO  

E-Print Network [OSTI]

One of the instruments on the International X-ray Observatory (IXO), under study with NASA, ESA and JAXA, is the X-ray Microcalorimeter Spectrometer (XMS). This instrument, which will provide high spectral resolution images, ...

Figueroa-Feliciano, Enectali

214

C-III flow measurements with a coherence imaging spectrometer  

SciTech Connect (OSTI)

This work describes a coherence imaging spectrometer capable of making spatially resolved CIII flow measurements in the DIII-D lower divertor. The spectrometer exploits a periscope view of the plasma to produce line-of-sight averaged velocity measurements of CIII. From these chord averaged flow measurements, a 2D poloidal cross section of the CIII flow is tomographically reconstructed. Details of the diagnostic setup, acquired data, and data analysis will be presented, along with prospects for future applications.

Weber, T. R.; Allen, S. L. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Howard, J. [Australian National University, Canberra, ACT 0200 (Australia)

2012-10-15T23:59:59.000Z

215

The ALICE muon spectrometer: trigger detectors and quarkonia detection in p-p collisions  

E-Print Network [OSTI]

This work was carried out in the context of the optimisation of the performances of the muon spectrometer of the forthcoming ALICE experiment at the Large Hadron Collider (LHC, CERN). The aim of ALICE is the study of nuclear matter at the highest energy densities ever accessed experimentally. More in detail, the focus is on the expected phase transition to a deconfined phase of matter where the degrees of freedom are those of quarks and gluons: the Quark-Gluon Plasma. The conditions for QGP formation are expected to be achieved in highly relativistic heavy ion collisions. The energy in the centre of mass of Pb-Pb collisions at the LHC will be 5.5 TeV per nucleon pair. The ALICE physics program also includes data-taking in p-p collisions at the centre-of-mass-energy of 14 TeV. The ALICE muon spectrometer has been designed for the detection of heavy quarkonia through their muon decay: both theoretical predictions and experimental data obtained at SPS and RHIC indicate that the production of these resonances sho...

Gagliardi, Martino

216

Apparatus and methods for continuous beam fourier transform mass spectrometry  

DOE Patents [OSTI]

A continuous beam Fourier transform mass spectrometer in which a sample of ions to be analyzed is trapped in a trapping field, and the ions in the range of the mass-to-charge ratios to be analyzed are excited at their characteristic frequencies of motion by a continuous excitation signal. The excited ions in resonant motions generate real or image currents continuously which can be detected and processed to provide a mass spectrum.

McLuckey, Scott A. (Oak Ridge, TN); Goeringer, Douglas E. (Oak Ridge, TN)

2002-01-01T23:59:59.000Z

217

Lead Slowing Down Spectrometer Research Plans  

SciTech Connect (OSTI)

The MPACT-funded Lead Slowing Down Spectrometry (LSDS) project has been evaluating the feasibility of using LSDS techniques to assay fissile isotopes in used nuclear fuel assemblies. The approach has the potential to provide considerable improvement in the assay of fissile isotopic masses in fuel assemblies compared to other non-destructive techniques in a direct and independent manner. The LSDS collaborations suggests that the next step to in empirically testing the feasibility is to conduct measurements on fresh fuel assemblies to understand investigate self-attenuation and fresh mixed-oxide (MOX) fuel rodlets so we may betterto understand extraction of masses for 235U and 239Pu. While progressing toward these goals, the collaboration also strongly suggests the continued development of enabling technology such as detector development and algorithm development, thatwhich could provide significant performance benefits.

Warren, Glen A.; Kulisek, Jonathan A.; Gavron, Victor; Danon, Yaron; Weltz, Adam; Harris, Jason; Stewart, T.

2013-03-22T23:59:59.000Z

218

Extending Penning trap mass measurements with SHIPTRAP to the heaviest elements  

SciTech Connect (OSTI)

Penning-trap mass spectrometry of radionuclides provides accurate mass values and absolute binding energies. Such mass measurements are sensitive indicators of the nuclear structure evolution far away from stability. Recently, direct mass measurements have been extended to the heavy elements nobelium (Z=102) and lawrencium (Z=103) with the Penning-trap mass spectrometer SHIPTRAP. The results probe nuclear shell effects at N=152. New developments will pave the way to access even heavier nuclides.

Block, M.; Ackermann, D.; Herfurth, F.; Hofmann, S. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Blaum, K. [Max-Planck-Institut fuer Kernphysik, 69117 Heidelberg, Germany and Ruprecht-Karls-Universitaet, 69120 Heidelberg (Germany); Droese, C.; Marx, G.; Schweikhard, L. [Ernst-Moritz-Arndt-Universitaet, 17487 Greifswald (Germany); Duellmann, Ch. E. [Johannes Gutenberg-Universitaet, 55099 Mainz, Germany and GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Helmholtz-Institut Mainz, 55099 Mainz (Germany); Eibach, M. [Ruprecht-Karls-Universitaet, 69120 Heidelberg, Germany and Johannes Gutenberg-Universitaet, 55099 Mainz (Germany); Eliseev, S. [Max-Planck-Institut fuer Kernphysik, 69117 Heidelberg (Germany); Haettner, E.; Plass, W. R.; Scheidenberger, C. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Justus-Liebig-Universitaet, 35392 Giessen (Germany); Hessberger, F. P. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Helmholtz-Institut Mainz, 55099 Mainz (Germany); Ramirez, E. Minaya [Helmholtz-Institut Mainz, 55099 Mainz, Germany and GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Nesterenko, D. [Petersburg Nuclear Physics Institute, Gatchina, 188300 St. Petersburg (Russian Federation); and others

2013-03-19T23:59:59.000Z

219

Ultracold-neutron infrastructure for the gravitational spectrometer GRANIT  

E-Print Network [OSTI]

The gravitational spectrometer GRANIT will be set up at the Institut Laue Langevin. It will profit from the high ultracold neutron density produced by a dedicated source. A monochromator made of crystals from graphite intercalated with potassium will provide a neutron beam with 0.89 nm incident on the source. The source employs superthermal conversion of cold neutrons in superfluid helium, in a vessel made from BeO ceramics with Be windows. A special extraction technique has been tested which feeds the spectrometer only with neutrons with a vertical velocity component v < 20 cm/s, thus keeping the density in the source high. This new source is expected to provide a density of up to 800 1/cm3 for the spectrometer.

P. Schmidt-Wellenburg; K. H. Andersen; P. Courtois; M. Kreuz; S. Mironov; V. V. Nesvizhevsky; G. Pignol; K. V. Protasov; T. Soldner; F. Vezzu; O. Zimmer

2009-01-29T23:59:59.000Z

220

Ultracold-neutron infrastructure for the gravitational spectrometer GRANIT  

E-Print Network [OSTI]

The gravitational spectrometer GRANIT will be set up at the Institut Laue Langevin. It will profit from the high ultracold neutron density produced by a dedicated source. A monochromator made of crystals from graphite intercalated with potassium will provide a neutron beam with 8.9 Angstrom incident on the source. The source employs superthermal conversion of cold neutrons in superfluid helium, in a vessel made from BeO ceramics with Be windows. A special extraction technique has been tested which feeds the spectrometer only with neutrons with a vertical velocity component v = 20 cm/s, thus keeping the density in the source high. This new source is expected to provide a density of up to R = 800 cm-3 for the spectrometer.

Schmidt-Wellenburg, P; Courtois, P; Kreuz, M; Mironov, S; Nesvizhevsky, V V; Pignol, G; Protasov, K V; Soldner, T; Vezzu, F; Zimmer, O

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

SPEC-DOC: a user's guide to spectrometer software  

SciTech Connect (OSTI)

SPEC is the name of the operating system designed to control NMR spectrometers. SPEC is actually one large program which handles many functions necessary to control each spectrometer. The SPEC operating system is documented. The general operation of SPEC is discussed, including how to get into the program and how to issue commands. The commands are discussed in detail, as well as the operation of the microprocessor based pulse programmer, spectrometer peripherals, supporting programs, and how to create and load a TEMP program. Appended are details on bootstrapping procedures, hardware specifics, a technical description of SPEC and how to change or recreate it, a description of microcode loading and the procedure for formatting floppies, disks, and recreating RDOS. (LEW)

Sinton, S.; Garbow, J.R.; Ackerman, J.L.; Drobny, G.; Ruben, D.J.; Pines, A.

1983-05-01T23:59:59.000Z

222

The MARTE VNIR Imaging Spectrometer Experiment: Design and Analysis  

E-Print Network [OSTI]

We report on the design, operation, and data analysis methods employed on the VNIR imaging spectrometer instrument that was part of the Mars Astrobiology Research and Technology Experiment (MARTE). The imaging spectrometer is a hyperspectral scanning pushbroom device sensitive to VNIR wavelengths from 400-1000 nm. During the MARTE project, the spectrometer was deployed to the Rio Tinto region of Spain. We analyzed subsets of 3 cores from Rio Tinto using a new band modeling technique. We found most of the MARTE drill cores to contain predominantly goethite, though spatially coherent areas of hematite were identified in Core 23. We also distinguished non Fe-bearing minerals that were subsequently analyzed by X-ray diffraction (XRD) and found to be primarily muscovite. We present drill core maps that include spectra of goethite, hematite, and non Fe-bearing minerals.

Brown, Adrian J; Dunagan, Stephen

2014-01-01T23:59:59.000Z

223

Radiochemical method development  

SciTech Connect (OSTI)

The authors have developed methods for chemical characterization of the environment under a multitask project that focuses on improvement of radioanalytical methods with an emphasis on faster and cheaper routine methods. The authors have developed improved methods for separation of environmental levels of technetium-99, radium, and actinides from soil and water; separation of actinides from soil and water matrix interferences; and isolation of strontium. They are also developing methods for simultaneous detection of multiple isotopes (including nonradionuclides) by using a new instrumental technique, inductively coupled plasma-mass spectrometry (ICP-MS). The new ICP-MS methods have greater sensitivity and efficiency and could replace many radiometric techniques. They are using flow injection analysis to integrate and automate the separation methods with the ICP-MS methodology. The final product of all activities will be methods that are available (published in the U.S. Department of Energy`s analytical methods compendium) and acceptable for use in regulatory situations.

Erickson, M.D.; Aldstadt, J.H.; Alvarado, J.S.; Crain, J.S.; Orlandini, K.A.; Smith, L.L.

1994-09-01T23:59:59.000Z

224

Extended Evaluations of the Commercial Spectrometer Systems for Safeguards Applications  

SciTech Connect (OSTI)

Safeguards applications require the best of the spectrometer system with excellent resolution, stability, and throughput. Instruments must perform well in all situations and environments. Data communication to the computer should be convenient, fast, and reliable. The software should have all the necessary tools and be easy to use. Portable systems should be small in size, lightweight, and have a long battery life. Nine commercially available spectrometer systems are tested with five different germanium detectors. Considering the performance of the Digital Signal Processors (DSP), digital-based spectroscope y may become the way of future gamma-ray spectroscopy.

Duc T. Vo

1999-08-01T23:59:59.000Z

225

Waveguide-integrated photonic crystal spectrometer with camera readout  

SciTech Connect (OSTI)

We demonstrate an infrared spectrometer based on waveguide-coupled nanocavity filters in a planar photonic crystal structure. The input light is coupled into the waveguide, from which spectral components are dropped into the cavities and radiated off-chip for detection on a commercial InGaAs camera. The spectrometer has a footprint of only 60??m by 8??m. The spectral resolution is about 1?nm in the operation bandwidth of 1522–1545?nm. By substituting the membrane material and structure parameters, this design can be easily extended into the visible regime and developed for a variety of highly efficient, miniature photonic applications.

Meng, Fan; Shiue, Ren-Jye; Li, Luozhou; Nie, Jing; Harris, Nicholas C.; Chen, Edward H.; Schröder, Tim; Englund, Dirk, E-mail: englund@mit.edu [Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology (MIT), Cambridge, Massachusetts 02139 (United States); Wan, Noel [Department of Physics, Columbia University, New York, New York 10027 (United States); Pervez, Nadia [Chromation Partners LLC, 18 Bridge Street Suite 2J, Brooklyn, New York 11201 (United States); Kymissis, Ioannis [Chromation Partners LLC, 18 Bridge Street Suite 2J, Brooklyn, New York 11201 (United States); Department of Electrical Engineering, Columbia University, New York, New York 10027 (United States)

2014-08-04T23:59:59.000Z

226

The NIF x-ray spectrometer calibration campaign at Omega  

SciTech Connect (OSTI)

The calibration campaign of the National Ignition Facility X-ray Spectrometer (NXS) was carried out at the OMEGA laser facility. Spherically symmetric, laser-driven, millimeter-scale x-ray sources of K-shell and L-shell emission from various mid-Z elements were designed for the 2–18 keV energy range of the NXS. The absolute spectral brightness was measured by two calibrated spectrometers. We compare the measured performance of the target design to radiation hydrodynamics simulations.

Pérez, F.; Kemp, G. E.; Barrios, M. A.; Pino, J.; Scott, H.; Ayers, S.; Chen, H.; Emig, J.; Colvin, J. D.; Fournier, K. B., E-mail: fournier2@llnl.gov [Lawrence Livermore National Laboratory, P. O. Box 808, Livermore, California 94551 (United States); Regan, S. P.; Bedzyk, M.; Shoup, M. J.; Agliata, A.; Yaakobi, B.; Marshall, F. J.; Hamilton, R. A. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States); Jaquez, J.; Farrell, M.; Nikroo, A. [General Atomics, P.O. Box 85608, San Diego, California 92186 (United States)

2014-11-15T23:59:59.000Z

227

The Results of Recent MICE Superconducting Spectrometer Solenoid Test  

SciTech Connect (OSTI)

The MICE spectrometer solenoid magnets will be the first magnets to be installed within the MICE cooling channel. The MICE spectrometer solenoids may be the largest magnets that have been cooled using small two stage coolers. During the previous test of this magnet, the cooler first stage temperatures were too high. The causes of some of the extra first stage heat load has been identified and corrected. The rebuilt magnet had a single stage GM cooler in addition to the three pulse tube coolers. The added cooler reduces the temperature of the top of the HTS leads, the shield and of the first stage of the pulse tube coolers.

Green, Michael A; Virostek, Steve P.; Zisman, Michael S.

2010-10-15T23:59:59.000Z

228

Bragg x-ray survey spectrometer for ITER  

SciTech Connect (OSTI)

Several potential impurity ions in the ITER plasmas will lead to loss of confined energy through line and continuum emission. For real time monitoring of impurities, a seven channel Bragg x-ray spectrometer (XRCS survey) is considered. This paper presents design and analysis of the spectrometer, including x-ray tracing by the Shadow-XOP code, sensitivity calculations for reference H-mode plasma and neutronics assessment. The XRCS survey performance analysis shows that the ITER measurement requirements of impurity monitoring in 10 ms integration time at the minimum levels for low-Z to high-Z impurity ions can largely be met.

Varshney, S. K.; Jakhar, S. [ITER-India, Institute for Plasma Research, Bhat, Gandhinagar, Gujarat 382428 (India); Barnsley, R. [ITER Organization, Route de Vinon sur Verdon, 13115 Saint Paul Lez Durance (France); O'Mullane, M. G. [Department of Physics, University of Strathclyde, Glasgow G4 0NG (United Kingdom)

2012-10-15T23:59:59.000Z

229

Development of multichannel low-energy neutron spectrometer  

SciTech Connect (OSTI)

A multichannel low-energy neutron spectrometer for down-scattered neutron (DSN) measurements in inertial confinement fusion (ICF) experiments has been developed. Our compact-size 256-channel lithium-glass-scintillator-based spectrometer has been implemented and tested in ICF experiments with the GEKKO XII laser. We have performed time calibration of the 256-channel analog-to-digital convertor system used for DSN measurements via X-ray pulse signals. We have clearly observed the DD-primary fusion neutron signal and have successfully studied the detector's impulse response. Our detector is soon to be implemented in future ICF experiments.

Arikawa, Y., E-mail: arikawa-y@ile.osaka-u.ac.jp; Nagai, T.; Abe, Y.; Kojima, S.; Sakata, S.; Inoue, H.; Utsugi, M.; Iwasa, Y.; Sarukura, N.; Nakai, M.; Shiraga, H.; Fujioka, S.; Azechi, H. [Institute of Laser Engineering, Osaka University, 2-6 Yamada-oka, Suita, Osaka (Japan); Murata, T. [Kumamoto University, 2-40-1 Kurokami, Kumamoto 860-8555 (Japan)

2014-11-15T23:59:59.000Z

230

A method for direct, semi-quantitative analysis of gas phase samples using gas chromatography-inductively coupled plasma-mass spectrometry  

SciTech Connect (OSTI)

A new and complete GC–ICP-MS method is described for direct analysis of trace metals in a gas phase process stream. The proposed method is derived from standard analytical procedures developed for ICP-MS, which are regularly exercised in standard ICP-MS laboratories. In order to implement the method, a series of empirical factors were generated to calibrate detector response with respect to a known concentration of an internal standard analyte. Calibrated responses are ultimately used to determine the concentration of metal analytes in a gas stream using a semi-quantitative algorithm. The method was verified using a traditional gas injection from a GC sampling valve and a standard gas mixture containing either a 1 ppm Xe + Kr mix with helium balance or 100 ppm Xe with helium balance. Data collected for Xe and Kr gas analytes revealed that agreement of 6–20% with the actual concentration can be expected for various experimental conditions. To demonstrate the method using a relevant “unknown” gas mixture, experiments were performed for continuous 4 and 7 hour periods using a Hg-containing sample gas that was co-introduced into the GC sample loop with the xenon gas standard. System performance and detector response to the dilute concentration of the internal standard were pre-determined, which allowed semi-quantitative evaluation of the analyte. The calculated analyte concentrations varied during the course of the 4 hour experiment, particularly during the first hour of the analysis where the actual Hg concentration was under predicted by up to 72%. Calculated concentration improved to within 30–60% for data collected after the first hour of the experiment. Similar results were seen during the 7 hour test with the deviation from the actual concentration being 11–81% during the first hour and then decreasing for the remaining period. The method detection limit (MDL) was determined for the mercury by injecting the sample gas into the system following a period of equilibration. The MDL for Hg was calculated as 6.8 ?g · m{sup ? 3}. This work describes the first complete GC–ICP-MS method to directly analyze gas phase samples, and detailed sample calculations and comparisons to conventional ICP-MS methods are provided.

Carter, Kimberly E.; Gerdes, Kirk

2013-07-01T23:59:59.000Z

231

Explanatory Optimization of Protein Mass Spectrometry via Genetic Search  

E-Print Network [OSTI]

of the mass spectrometer settings that accounts for much of this success. Specifically, the conditions of Wales, Aberystwyth, Ceredigion SY23 3DD, U.K. Optimizing experimental conditions for the effective analy that little or no a priori knowledge of the optimal conditions is available. There is much current interest

Fernandez, Thomas

232

Optical system for high resolution spectrometer/monochromator  

DOE Patents [OSTI]

An optical system for use in a spectrometer or monochromator employing a mirror which reflects electromagnetic radiation from a source to converge with same in a plane is disclosed. A straight grooved, varied-spaced diffraction grating receives the converging electromagnetic radiation from the mirror and produces a spectral image for capture by a detector, target or like receiver. 11 figs.

Hettrick, M.C.; Underwood, J.H.

1988-10-11T23:59:59.000Z

233

Compact Catadioptric Imaging Spectrometer Designs Utilizing Immersed Gratings  

DOE Patents [OSTI]

An imaging spectrometer comprising an entrance slit for directing light, a lens that receives said light and reflects said light, a grating that defracts said light back onto said lens which focuses said light, and a detector array that receives said focused light. In one embodiment the grating has rulings immersed into a germanium surface.

Lerner, Scott A. (Livermore, CA)

2006-02-28T23:59:59.000Z

234

Analysis of a time-of-flight neutron spectrometer  

SciTech Connect (OSTI)

A neutron spectrometer is analyzed. The spectrum is resolved using a time-of-flight method in which the angular position of a rapidly spinning wheel is used to measure time. The measurement method is summarized, the data-analysis problem is formulated, units are discussed, the calibration technique is described, and a spectral transformation is developed.

Biggs, F.

1983-12-01T23:59:59.000Z

235

Modulated optical solid-state spectrometer applications in plasma diagnostics  

E-Print Network [OSTI]

Modulated optical solid-state spectrometer applications in plasma diagnostics John Howard Plasma A new electro-optically modulated optical solid-state MOSS interferometer has been constructed for the measurement of the low order spectral moments of line emission from optically thin radiant media

Howard, John

236

A fourier spectrometer for studying the radiation from Josephson Junctions  

SciTech Connect (OSTI)

The paper describes a Fourier spectrometer designed to study the radiation generated by a Josephson junction in the millimeter and FIR bands with a resolution of {approx}2 GHz in the two-pass mode and {approx}1 GHz in the multipass mode. A feature is that one Josephson junctions operates as both generator and detector at the same time.

Verevkin, A.A.; Il`in, V.A.; Lipatov, A.P. [V.I. Lenin Moscow Pedagogical State Univ., Moscow (Russian Federation)

1995-06-01T23:59:59.000Z

237

FINGERPRINTING INORGANIC ARSENIC AND ORGANOARSENIC COMPOUNDS IN IN SITU OIL SHALE RETORT AND PROCESS VOTERS USING A LIQUID CHROMATOGRAPH COUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTOR  

E-Print Network [OSTI]

COUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTORCoupled with an Atomic Absorption Spectrometer as a DetectorcOUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTOR

Fish, Richard H.

2013-01-01T23:59:59.000Z

238

A co-axially configured submillimeter spectrometer and investigations of hydrogen bound molecular complexes  

E-Print Network [OSTI]

The development of a co-axially configured submillimeter spectrometer is reported. The spectrometer has been constructed to observe molecular complexes that exhibit non-covalent interactions with energies much less than that of a traditional...

McElmurry, Blake Anthony

2009-05-15T23:59:59.000Z

239

Upgrade of the neon soft X-ray spectrometer for Alcator C-Mod  

E-Print Network [OSTI]

In order to study plasma rotation, temperature, and impurity density, a Neon Soft X-ray Spectrometer (NeSoXs) was installed on the Alcator C-Mod tokamak. This spectrometer used a spherically bent mica crystal as the ...

Podpaly, Yuri Anatoly

2007-01-01T23:59:59.000Z

240

E-Print Network 3.0 - anti-compton gamma-ray spectrometer Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

compton gamma-ray spectrometer Search Powered by Explorit Topic List Advanced Search Sample search results for: anti-compton gamma-ray spectrometer Page: << < 1 2 3 4 5 > >> 1...

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

The development of an Omegratron plasma ion mass spectrometer for Alcator C-Mod  

SciTech Connect (OSTI)

A new diagnostic device, the Omegatron Probe, has been developed to investigate relative impurity levels and impurity charge state distribution in the Alcator C-Mod Tokamak edge plasma. The Omegatron probe consists of two principal components, a ``front-end`` of independently biased grids, arranged in a gridded energy analyzer fashion and a large collection cavity. Particles enter the probe in a thin ``ribbon`` through a knife-edge slit. The grids provide a means to measure and control the parallel energy distribution of the ions. In the collection cavity, an oscillating electric field is applied perpendicularly to the ambient magnetic field. Ions whose cyclotron frequencies are resonant with this electric field oscillation will gain perpendicular energy and be collected. In this way, the probe can be operated in two modes: first, by fixing the potentials on the grids and sweeping frequencies to obtain a `` Z/m spectrum`` of ion species and second, by fixing the frequency and sweeping the grid potentials to obtain the distribution function of an individual impurity species. The Omegatron probe performed successfully in tests on a Hollow Cathode Discharge (HCD) linear plasma column. It obtained measurements of T{sub e} {approx} 5 eV, T{sub i} (H{sup +}) {approx} 2.0 {plus_minus} 0.2 eV, n{sub 0} {approx} 9 {times} 10{sup 15} m{sup {minus}3}, RMS potential fluctuation levels of {approximately} 0.5 {plus_minus} 0.05 {plus_minus} T{sub e}, and obtained ``Z/m`` spectra for the plasma ions (H{sup +}, H{sub 2}{sup +}, He{sup +}). Additional experiments confirmed the theoretical scalings of the f/{delta}f resolution with the applied electric field and magnetic field strengths. The instrument yielded an absolute level of resolution, f/{delta}f, of approximately 2.5 to 3 times the theoretical values. Finally, the results from the HCD are used to project operation on Alcator C-Mod.

Thomas, E.E. Jr.

1993-05-01T23:59:59.000Z

242

An industrial hygiene survey of acetonitrile using a miniature quadrupole mass spectrometer  

E-Print Network [OSTI]

to Life or Health Concentrations. Cincinnati, OH: NIOSH, 1995. 6. National Institute of Occupational Safety and Health (NIOSH): Acetonitrile (Analytical Method 1606). In NlOSH Manual of Analytical Methods, 4th ed. , P. M. Eller (ed. ). Cincinnati, OH... of Occupational Safety and Health (NIOSH): Development aud Evaluation of Methods. Iu ?1OSH Manual of Analytical Methods, 4' ed. , PM. Eller (cd. ). Cincinnati, OH: NIOSH, 1994. pp. 36-44 13. Einfeld, W. , S. F. Bender, M. R. Keenan, S. M. Thornberg, and M. M...

Bruss, Stacy M

1999-01-01T23:59:59.000Z

243

Investigation of gamma induced degradation of Amberlite 200 cation resin by mass spectrometer and liquid chromatograph  

E-Print Network [OSTI]

, provisions were made for collecting samples of any gas produced. The irradiated resin was exposed to total 7 8 8 accumulations of 1. 0129X10 , 1. 0215XIO , and 5. 0168X10 Rads in three separate runs. It should be noted that the same amount of demineral.... (December 1977) Albert Antonio Freitag, B. S. , Texas A&M University Chairman of Advisory Committee: Dr. James 8. Smathers Amberlite 200 cation exchange resin was irradiated by gamma 7 8 radiation to doses of 10 to 5X10 Rads. Results of the analysis...

Freitag, Albert Antonio

1977-01-01T23:59:59.000Z

244

Performance of the Recoil Mass Spectrometer and its Detector Systems at the Holi eld  

E-Print Network [OSTI]

Ridge Institute for Science and Education, Oak Ridge, Tennessee 37831 USA bPhysics Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 USA cDepartment of Physics and Astronomy, Vanderbilt L69 3BX, UK eJoint Institute for Heavy Ion Research, Oak Ridge, Tennessee 37831 USA f

245

Performance of the Recoil Mass Spectrometer and its Detector Systems at the Holifield  

E-Print Network [OSTI]

.­H. Yu b , and E. F. Zganjar k a Oak Ridge Institute for Science and Education, Oak Ridge, Tennessee 37831 USA b Physics Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 USA c Department of Liverpool, P. O. Box 147, Liverpool L69 3BX, UK e Joint Institute for Heavy Ion Research, Oak Ridge

246

Design and development of an ultrafine particle reflection-time-of-flight mass spectrometer  

E-Print Network [OSTI]

particle sizes proposed by the International Commission on Radiological Protection (ICRP 1994) shov s that ultratine particles ol' around 20nm in diameter have 50"z; deposition efficiency in thc alveolar region. Thc harmful effects ol P'I Fh on rats have...

Das, Rishiraj

2002-01-01T23:59:59.000Z

247

Evaluation of Technologies to Complement/Replace Mass Spectrometers in the Tritium Facilities  

SciTech Connect (OSTI)

The primary goal of this work is to determine the suitability of the Infraran sensor for use in the Palladium Membrane Reactor. This application presents a challenge for the sensor, since the process temperature exceeds its designed operating range. We have demonstrated that large baseline offsets, comparable to the sensor response to the analyte, are obtained if cool air is blown across the sensor. We have also shown that there is a strong environmental component to the noise. However, the current arrangement does not utilize a reference detector. The strong correlation between the CO and H{sub 2}O sensor responses to environmental changes indicate that a reference detector can greatly reduce the environmental sensitivity. In fact, incorporation of a reference detector is essential for the sensor to work in this application. We have also shown that the two sensor responses are adequately independent. Still, there are several small corrections which must to be made to the sensor response to accommodate chemical and physical effects. Interactions between the two analytes will alter the relationship between number density and pressure. Temperature and pressure broadening will alter the relationship between absorbance and number density. The individual effects are small--on the order of a few percent or less--but cumulatively significant. Still, corrections may be made if temperature and total pressure are independently measured and incorporated into a post-analysis routine. Such corrections are easily programmed and automated and do not represent a significant burden for installation. The measurements and simulations described above indicate that with appropriate corrections, the Infraran sensor can approach the 1-1.5% measurement accuracy required for effective PMR process control. It is also worth noting that the Infraran may be suitable for other gas sensing applications, especially those that do not need to be made in a high-temperature environment. Any gas with an infrared absorption (methane, ammonia, etc.) may be detected so long as an appropriate bandpass filter can be manufactured. Note that homonuclear diatomic molecules (hydrogen and its isotopes, nitrogen, oxygen) do not have infrared absorptions. We have shown that the sensor response may be adequately predicted using commercially available software. Measurement of trace concentrations is limited by the broad spectral bandpass, since the total signal includes non-absorbed frequencies. However, cells with longer pathlengths can be designed to address this problem.

Tovo, L. L.; Lascola, R. J.; Spencer, W. A.; McWhorter, C. S.; Zeigler, K. E.

2005-08-30T23:59:59.000Z

248

Mass spectrometer calibration of Cosmic Dust Analyzer Thomas J. Ahrens, Satish C. Gupta,1  

E-Print Network [OSTI]

. Using aluminum alloy as a test sample, each pulse produces a charge of $4.6 pC (mostly Al+1 ), whereas of the instrument. Particles impact a Rh target plate at velocities of 1-100 km/s and produce some 10Ã?8 to 10Ã?5 in the CDA geometry. Employing a multichannel plate detector in this MS yields for Al-Mg-Cu alloy

Stewart, Sarah T.

249

Mass Spectrometer: FT-ICR, 6T (Ion Surface Collisions) | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selected asMaratMary Louise

250

Mass Spectrometer: Time of Flight Secondary Ion (ToF SIMS) - 1997 | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund LasDubey selected asMaratMarySingle Particle (SPLAT

251

Conversion electrons used to monitor the energy scale of electron spectrometer near tritium endpoint - a simulation study  

E-Print Network [OSTI]

Measurements of the endpoint region of the tritium beta-decay spectrum provides good possibility to determine neutrino mass. This, however, needs a perfect monitoring of the spectrometer energy scale. A parallel measurement of electron line of known energy - in particular the 83mKr conversion K-line - may serve well to this purpose. The 83Rb decaying to 83mKr seems to be a very suitable radioactive source due to its halflife of 86.2 day. In this work, we determine the amount of 83Rb which is necessary for a successful monitoring.

M. Rysavy

2006-01-15T23:59:59.000Z

252

High-precision CO2 isotopologue spectrometer with a difference-frequency-generation laser source  

E-Print Network [OSTI]

High-precision CO2 isotopologue spectrometer with a difference-frequency-generation laser source A precision laser spectrometer for the detection of CO2 isotopes is reported. The spectrometer measures the fundamental absorption signatures of 13 C and 12 C isotopes in CO2 at 4.32 m using a tunable mid-IR laser

253

Commissioning of the ATLAS Muon Spectrometer with Cosmic Rays  

E-Print Network [OSTI]

The ATLAS detector at the Large Hadron Collider has collected several hundred million cosmic ray events during 2008 and 2009. These data were used to commission the Muon Spectrometer and to study the performance of the trigger and tracking chambers, their alignment, the detector control system, the data acquisition and the analysis programs. We present the performance in the relevant parameters that determine the quality of the muon measurement. We discuss the single element efficiency, resolution and noise rates, the calibration method of the detector response and of the alignment system, the track reconstruction efficiency and the momentum measurement. The results show that the detector is close to the design performance and that the Muon Spectrometer is ready to detect muons produced in high energy proton-proton collisions.

The ATLAS Collaboration

2010-08-02T23:59:59.000Z

254

Compact Refractive Imaging Spectrometer Designs Utilizing Immersed Gratings  

DOE Patents [OSTI]

A compact imaging spectrometer comprising an entrance slit for directing light, a first means for receiving the light and focusing the light, an immersed diffraction grating that receives the light from the first means and defracts the light, a second means for receiving the light from the immersed diffraction grating and focusing the light, and an image plane that receives the light from the second means

Lerner, Scott A. (Livermore, CA); Bennett, Charles L. (Livermore, CA); Bixler, Jay V. (Oakland, CA); Kuzmenko, Paul J. (Livermore, CA); Lewis, Isabella T. (San Jose, CA)

2005-07-26T23:59:59.000Z

255

Imaging Spectrometer Designs Utilizing Immersed Gratings With Accessible Entrance Slit  

DOE Patents [OSTI]

A compact imaging spectrometer comprises an entrance slit, a catadioptric lens with a mirrored surface, a grating, and a detector array. The entrance slit directs light to the mirrored surface of the catadioptric lens; the mirrored surface reflects the light back through the lens to the grating. The grating receives the light from the catadioptric lens and diffracts the light to the lens away from the mirrored surface. The lens transmits the light and focuses it onto the detector array.

Chrisp, Michael P. (Danville, CA); Lerner, Scott A. (Corvallis, OR)

2006-03-21T23:59:59.000Z

256

Polarization Measurements in Photoproduction with CEBAF Large Acceptance Spectrometer  

SciTech Connect (OSTI)

A significant part of the experimental program in Hall-B of the Jefferson Lab is dedicated to the studies of the structure of baryons. CEBAF Large Acceptance Spectrometer (CLAS), availability of circularly and linearly polarized photon beams and recent addition of polarized targets provides remarkable opportunity for single, double and in some cases triple polarization measurements in photoproduction. An overview of the experiments will be presented.

E. Pasyuk

2010-05-01T23:59:59.000Z

257

Polarimeters and Energy Spectrometers for the ILC Beam Delivery System  

SciTech Connect (OSTI)

This article gives an overview of current plans and issues for polarimeters and energy spectrometers in the Beam Delivery System of the ILC. It is meant to serve as a useful reference for the Detector Letter of Intent documents currently being prepared. Concepts for high precision polarization and energy measurements exist. These concepts have resulted in detailed system layouts that are included in the RDR description for the Beam Delivery System. The RDR includes both upstream and downstream polarimeters and energy spectrometers for both beams. This provides needed complementarity and redundancy for achieving the precision required, with adequate control and demonstration of systematic errors. The BDS polarimeters and energy spectrometers need to be a joint effort of the ILC BDS team and the Detector collaborations, with collaboration members responsible for the performance and accuracy of the measurements. Details for this collaboration and assigning of responsibilities remain to be worked out. There is also a demonstrated need for Detector physicists to play an active role in the design and evaluation of accelerator components that impact beam polarization and beam energy capabilities, including the polarized source and spin rotator systems. A workshop was held in 2008 on ILC Polarization and Energy measurements, which resulted in a set of recommendations for the ILC design and operation. Additional input and action is needed on these from the Detector collaborations, the Research Director and the GDE. Work is continuing during the ILC engineering design phase to further optimize the polarimeter and energy spectrometer concepts and fully implement them in the ILC. This includes consideration for alternative methods, detailed design and cost estimates, and prototype and test beam activities.

Boogert, S.; /Royal Holloway, U. of London; Hildreth, M.; /Notre Dame U.; Kafer, D.; List, J.; Monig, K.; /DESY; Moffeit, K.C.; /SLAC; Moortgat-Pick, G.; /Durham U., IPPP; Riemann, S.; Schreiber, H.J.; Schuler, P.; /DESY; Torrence, E.; /Oregon U.; Woods, M.; /SLAC

2009-02-24T23:59:59.000Z

258

analytica chimica acta 6 2 1 ( 2 0 0 8 ) 140147 available at www.sciencedirect.com  

E-Print Network [OSTI]

homepage: www.elsevier.com/locate/aca Rare earth elements determined in Antarctic ice by inductively Rare earth elements Antarctic ice a b s t r a c t Inductively coupled plasma mass spectrometry (ICP-MS) is a suitable tool for multi-element analysis at low concentration levels. Rare earth element (REE

Howat, Ian M.

259

Overprinting Deformations in Mantle Rocks, Dun Mountain, New Zealand  

E-Print Network [OSTI]

sliding DMOB Dun Mountain Ophiolite Belt EBSD Electron backscatter diffraction HREE Heavy rare earth element ICP-MS Inductively coupled plasma-mass spectrometry LPO Lattice preferred orientation LREE Light rare earth element P Pressure PBS Phase... boundary sliding REE Rare earth element SEM Scanning electron microscopy SPO Shape preferred orientation T Temperature vi TABLE OF CONTENTS Page ABSTRACT...

Donnelly, Sara

2014-04-25T23:59:59.000Z

260

Mexico City Aerosol Analysis During Milagro Using High Resolution Aerosol Mass Spectrometry at the Urban Supersite (T0) - Part 1: Fine Particle Composition and Organic Source Apportionment.  

E-Print Network [OSTI]

Submicron aerosol was analyzed during the MILAGRO field campaign in March 2006 at the T0 urban supersite in Mexico City with a High-Resolution Aerosol Mass Spectrometer (AMS) and complementary instrumentation. Positive ...

Aiken, A. C.

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Interface for the rapid analysis of liquid samples by accelerator mass spectrometry  

DOE Patents [OSTI]

An interface for the analysis of liquid sample having carbon content by an accelerator mass spectrometer including a wire, defects on the wire, a system for moving the wire, a droplet maker for producing droplets of the liquid sample and placing the droplets of the liquid sample on the wire in the defects, a system that converts the carbon content of the droplets of the liquid sample to carbon dioxide gas in a helium stream, and a gas-accepting ion source connected to the accelerator mass spectrometer that receives the carbon dioxide gas of the sample in a helium stream and introduces the carbon dioxide gas of the sample into the accelerator mass spectrometer.

Turteltaub, Kenneth; Ognibene, Ted; Thomas, Avi; Daley, Paul F; Salazar Quintero, Gary A; Bench, Graham

2014-02-04T23:59:59.000Z

262

Direct mass measurements beyond the proton drip-line  

E-Print Network [OSTI]

First on-line mass measurements were performed at the SHIPTRAP Penning trap mass spectrometer. The masses of 18 neutron-deficient isotopes in the terbium-to-thulium region produced in fusion-evaporation reactions were determined with relative uncertainties of about $7\\cdot 10^{-8}$, nine of them for the first time. Four nuclides ($^{144, 145}$Ho and $^{147, 148}$Tm) were found to be proton-unbound. The implication of the results on the location of the proton drip-line is discussed by analyzing the one-proton separation energies.

C. Rauth; D. Ackermann; K. Blaum; M. Block; A. Chaudhuri; S. Eliseev; R. Ferrer; D. Habs; F. Herfurth; F. P. Hessberger; S. Hofmann; H. -J. Kluge; G. Maero; A. Martin; G. Marx; M. Mukherjee; J. B. Neumayr; W. R. Plass; W. Quint; S. Rahaman; D. Rodriguez; C. Scheidenberger; L. Schweikhard; P. G. Thirolf; G. Vorobjev; C. Weber; Z. Di

2007-01-22T23:59:59.000Z

263

Small system for tritium accelerator mass spectrometry  

DOE Patents [OSTI]

Apparatus for ionizing and accelerating a sample containing isotopes of hydrogen and detecting the ratios of hydrogen isotopes contained in the sample is disclosed. An ion source generates a substantially linear ion beam including ions of tritium from the sample. A radio-frequency quadrupole accelerator is directly coupled to and axially aligned with the source at an angle of substantially zero degrees. The accelerator accelerates species of the sample having different mass to different energy levels along the same axis as the ion beam. A spectrometer is used to detect the concentration of tritium ions in the sample. In one form of the invention, an energy loss spectrometer is used which includes a foil to block the passage of hydrogen, deuterium and .sup.3 He ions, and a surface barrier or scintillation detector to detect the concentration of tritium ions. In another form of the invention, a combined momentum/energy loss spectrometer is used which includes a magnet to separate the ion beams, with Faraday cups to measure the hydrogen and deuterium and a surface barrier or scintillation detector for the tritium ions.

Roberts, Mark L. (Livermore, CA); Davis, Jay C. (Livermore, CA)

1993-01-01T23:59:59.000Z

264

Small system for tritium accelerator mass spectrometry  

DOE Patents [OSTI]

Apparatus for ionizing and accelerating a sample containing isotopes of hydrogen and detecting the ratios of hydrogen isotopes contained in the sample is disclosed. An ion source generates a substantially linear ion beam including ions of tritium from the sample. A radio-frequency quadrupole accelerator is directly coupled to and axially aligned with the source at an angle of substantially zero degrees. The accelerator accelerates species of the sample having different mass to different energy levels along the same axis as the ion beam. A spectrometer is used to detect the concentration of tritium ions in the sample. In one form of the invention, an energy loss spectrometer is used which includes a foil to block the passage of hydrogen, deuterium and [sup 3]He ions, and a surface barrier or scintillation detector to detect the concentration of tritium ions. In another form of the invention, a combined momentum/energy loss spectrometer is used which includes a magnet to separate the ion beams, with Faraday cups to measure the hydrogen and deuterium and a surface barrier or scintillation detector for the tritium ions.

Roberts, M.L.; Davis, J.C.

1993-02-23T23:59:59.000Z

265

Focused analyte spray emission apparatus and process for mass spectrometric analysis  

DOE Patents [OSTI]

An apparatus and process are disclosed that deliver an analyte deposited on a substrate to a mass spectrometer that provides for trace analysis of complex organic analytes. Analytes are probed using a small droplet of solvent that is formed at the junction between two capillaries. A supply capillary maintains the droplet of solvent on the substrate; a collection capillary collects analyte desorbed from the surface and emits analyte ions as a focused spray to the inlet of a mass spectrometer for analysis. The invention enables efficient separation of desorption and ionization events, providing enhanced control over transport and ionization of the analyte.

Roach, Patrick J. (Kennewick, WA); Laskin, Julia (Richland, WA); Laskin, Alexander (Richland, WA)

2012-01-17T23:59:59.000Z

266

A 4. pi. tracking TPC magnetic spectrometer for RHIC  

SciTech Connect (OSTI)

The primary physics objective of the 4{pi} TPC magnetic spectrometer proposal is to search for the Quark-Gluon Plasma. In previous workshops we have discussed what the possible hadronic signatures of such a state of matter would be. Succinctly, the QGP is a direct prediction of non-perturbative QCD. Therefore the question of the existence of this new state of matter bears directly on the validity of non-perturbative QCD. However, since non-perturbative QCD has never been established, it is apparent that what may await us is a host of new phenomena that will go beyond the standard model.

Danby, G.; Eiseman, S.E.; Etkin, A.; Foley, K.J.; Hackenburg, R.W.; Longacre, R.S.; Love, W.A.; Morris, T.W.; Platner, E.D.; Saulys, A.C.; Van Dijk, J.H. (Brookhaven National Lab., Upton, NY (USA)); Lindenbaum, S.J. (Brookhaven National Lab., Upton, NY (USA) City Coll., New York, NY (USA)); Chan, C.S.; Kramer, M.A.; Zhao, K. (City Coll., New York, NY (USA)); Biswas, N.; Kenney, P.; Piekarz, J. (Notre Dame Univ

1990-01-01T23:59:59.000Z

267

Report on First Activations with the Lead Slowing Down Spectrometer  

SciTech Connect (OSTI)

On Feb. 17 and 18 2011, six items were irradiated with neutrons using the Lead Slowing Down Spectrometer. After irradiation, dose measurements and gamma-spectrometry measurements were completed on all of the samples. No contamination was found on the samples, and all but one provided no dose. Gamma-spectroscopy measurements qualitatively agreed with expectations based on the materials, with the exception of silver. We observed activation in the room in general, mostly due to 56Mn and 24Na. Most of the activation was short lived, with half-lives on the scale of hours, except for 198Au which has a half-life of 2.7 d.

Warren, Glen A.; Mace, Emily K.; Pratt, Sharon L.; Stave, Sean; Woodring, Mitchell L.

2011-03-03T23:59:59.000Z

268

A 100-kc modulation system for an EPR microwave spectrometer  

E-Print Network [OSTI]

A 100-kc FIELD MODULATION SYSTEM FOR AN EPR MICROWAVE SPECTROMETER A Thesis By Frank Edwin Stewart Approved as to style and content by: /I i r Chairman of Committee C ead of Dep rtment Member ember August 1964 ACM ONLEDGi PENT... LIST OF FIGURES FIGURE PAGE II-1 Molecular Structure of DPPH 22 II-2 11-3 III-1 IV-1 Hyperfine Splitting in the DPPH EPR Spectrum . 25 Hyperfine Splitting in the Mn EpR Spectrum , . 27 100-kc Field Modulation and Detection System . 4I Typical...

Stewart, Frank Edwin

2012-06-07T23:59:59.000Z

269

Light Baryon Spectroscopy using the CLAS Spectrometer at Jefferson Laboratory  

SciTech Connect (OSTI)

Baryons are complex systems of confined quarks and gluons and exhibit the characteristic spectra of excited states. The systematics of the baryon excitation spectrum is important to our understanding of the effective degrees of freedom underlying nucleon matter. High-energy electrons and photons are a remarkably clean probe of hadronic matter, providing a microscope for examining the nucleon and the strong nuclear force. Current experimental efforts with the CLAS spectrometer at Jefferson Laboratory utilize highly-polarized frozen-spin targets in combination with polarized photon beams. The status of the recent double-polarization experiments and some preliminary results are discussed in this contribution.

Volker Crede

2011-12-01T23:59:59.000Z

270

Positron lifetime spectrometer using a DC positron beam  

DOE Patents [OSTI]

An entrance grid is positioned in the incident beam path of a DC beam positron lifetime spectrometer. The electrical potential difference between the sample and the entrance grid provides simultaneous acceleration of both the primary positrons and the secondary electrons. The result is a reduction in the time spread induced by the energy distribution of the secondary electrons. In addition, the sample, sample holder, entrance grid, and entrance face of the multichannel plate electron detector assembly are made parallel to each other, and are arranged at a tilt angle to the axis of the positron beam to effectively separate the path of the secondary electrons from the path of the incident positrons.

Xu, Jun; Moxom, Jeremy

2003-10-21T23:59:59.000Z

271

Test of an LED Monitoring System for the PHOS Spectrometer  

E-Print Network [OSTI]

Preprint submitted to Elsevier Print on 26th January 2000A prototype monitoring system for the Photon Spectrometer (PHOS) of the ALICE experiment at LHC is described in detail. The prototype consists of Control and Master modules. The first one is 8x8 matrix of Light Emitting Diodes coupled with stable generators of current pulses. The system provides an individual control for each of the 64 channels of PHOS prototype based on lead-tungstate crystals. A long term stability of order of 10-3 has been achieved in integral beam tests of the monitoring system and PHOS prototypes.

Blick, A M; Erin, S V; Kharlov, Yu V; Lobanov, M O; Mikhailov, Yu V; Minaev, N G; Petrov, V A; Sadovsky, S A; Samoylenko, V D; Suzdalev, V I; Senko, V A; Tikhonov, V V

1999-01-01T23:59:59.000Z

272

New results from the LASS (Large Aperture Superconducting Solenoid) spectrometer  

SciTech Connect (OSTI)

New results are presented from analyses of several mesonic and baryonic states containing one or more strange quarks. The data are taken from a high statistics (4 events/nb) study of K p interactions at 11 GeV/c carried out in the LASS Spectrometer at SLAC. New information is reported on the underlying K* states and also evidence for selective coupling of K eta to the K*'s; on the strangeonium members of the axial vector nonets in the K anti K channel; and on evidence for an * state.

Aston, D.; Awaji, N.; Bienz, T.; Bird, F.; D'Amore, J.; Dunwoodie, W.; Endorf, R.; Fujii, K.; Hayashii, H.; Iwata, S.

1987-06-22T23:59:59.000Z

273

ARM - Evaluation Product - Airborne Visible/Infrared Imaging Spectrometer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcal Documentation(AVIRIS) ProductsAirborne Visible/Infrared Imaging Spectrometer (AVIRIS) ARM Data Discovery

274

Method for predicting peptide detection in mass spectrometry  

DOE Patents [OSTI]

A method of predicting whether a peptide present in a biological sample will be detected by analysis with a mass spectrometer. The method uses at least one mass spectrometer to perform repeated analysis of a sample containing peptides from proteins with known amino acids. The method then generates a data set of peptides identified as contained within the sample by the repeated analysis. The method then calculates the probability that a specific peptide in the data set was detected in the repeated analysis. The method then creates a plurality of vectors, where each vector has a plurality of dimensions, and each dimension represents a property of one or more of the amino acids present in each peptide and adjacent peptides in the data set. Using these vectors, the method then generates an algorithm from the plurality of vectors and the calculated probabilities that specific peptides in the data set were detected in the repeated analysis. The algorithm is thus capable of calculating the probability that a hypothetical peptide represented as a vector will be detected by a mass spectrometry based proteomic platform, given that the peptide is present in a sample introduced into a mass spectrometer.

Kangas, Lars [West Richland, WA; Smith, Richard D [Richland, WA; Petritis, Konstantinos [Richland, WA

2010-07-13T23:59:59.000Z

275

E-Print Network 3.0 - atomic emission spectrometry Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to Basics Review Quadrupole ICP-MS: Introduction to Instrumentation, Summary: , such as atomic absorption or atomic emission spectrometry (Willard et al. 1988). Quadrupole ICP-MS...

276

PRISMA Spectrometer EVR Spectra And Collection Efficiencies In Gas-Filled Mode  

SciTech Connect (OSTI)

In order to study nuclear fusion reaction, the heavy-ion magnetic spectrometer PRISMA installed at INFN Legnaro is planned to be modified to work in Gas-Filled Mode. For that purpose, the possible response of the spectrometer will be examined in Rutherford scattering experiments which simulate the fusion reaction products. predictions for the evaporation residue (EVR) position spectra and collection efficiencies, as well as the respective spectrometer set ups, as determined using the algorithm of ANAMARI code, are presented.

Dragosavac, D. R.; Ujic, P. N.; Subotic, K. M. [Institute of Nuclear Sciences VINCA, PO Box 522, 11001 Belgrade (Serbia and Montenegro); Scarlassara, F. [Universita di Padova, Padova (Italy); INFN Sezione di Padova, Padova (Italy)

2007-04-23T23:59:59.000Z

277

High gain, Fast Scan, Broad Spectrum Parallel Beam Wavelength Dispersive X-ray Spectrometer for SEM  

SciTech Connect (OSTI)

During contract # DE-FG02-ER83545, Parallax Research, Inc. developed a High gain, Fast Scan Broad Spectrum Parallel beam Wavelength Dispersive X-ray Spectrometer for use on Scanning Electron Microscopes (SEM). This new spectrometer allows very fast high resolution elemental analysis of samples in an electron microscope. By comparison to previous WDS spectrometers, it can change from one energy position to another very quickly and has an extended range compared to some similar products.

OHara, David

2009-05-08T23:59:59.000Z

278

A solenoidal electron spectrometer for a precision measurement of the neutron $?$-asymmetry with ultracold neutrons  

E-Print Network [OSTI]

We describe an electron spectrometer designed for a precision measurement of the neutron $\\beta$-asymmetry with spin-polarized ultracold neutrons. The spectrometer consists of a 1.0-Tesla solenoidal field with two identical multiwire proportional chamber and plastic scintillator electron detector packages situated within 0.6-Tesla field-expansion regions. Select results from performance studies of the spectrometer with calibration sources are reported.

B. Plaster; R. Carr; B. W. Filippone; D. Harrison; J. Hsiao; T. M. Ito; J. Liu; J. W. Martin; B. Tipton; J. Yuan

2008-06-12T23:59:59.000Z

279

Optical apparatus for forming correlation spectrometers and optical processors  

DOE Patents [OSTI]

Optical apparatus is disclosed for forming correlation spectrometers and optical processors. The optical apparatus comprises one or more diffractive optical elements formed on a substrate for receiving light from a source and processing the incident light. The optical apparatus includes an addressing element for alternately addressing each diffractive optical element thereof to produce for one unit of time a first correlation with the incident light, and to produce for a different unit of time a second correlation with the incident light that is different from the first correlation. In preferred embodiments of the invention, the optical apparatus is in the form of a correlation spectrometer; and in other embodiments, the apparatus is in the form of an optical processor. In some embodiments, the optical apparatus comprises a plurality of diffractive optical elements on a common substrate for forming first and second gratings that alternately intercept the incident light for different units of time. In other embodiments, the optical apparatus includes an electrically-programmable diffraction grating that may be alternately switched between a plurality of grating states thereof for processing the incident light. The optical apparatus may be formed, at least in part, by a micromachining process. 24 figs.

Butler, M.A.; Ricco, A.J.; Sinclair, M.B.; Senturia, S.D.

1999-05-18T23:59:59.000Z

280

Light ion transfer reactions with the HELIOS spectrometer  

SciTech Connect (OSTI)

Light-ion induced transfer and inelastic scattering reactions on stable or long-lived targets have been used extensively to study the structure of nuclei near the line of {beta}-stability, and much of the detailed information on the single-particle structure of nuclei has been derived from such studies. Recently, however, a substantial expansion of the range of isotopes, for which this nuclear structure information can be obtained, has presented itself by using radioactive beams in inverse kinematics reactions. Such beams are now available at a number of facilities around the world, including the in-flight production method and CARIBU facility at ATLAS. The HELIOS spectrometer, which has been used since August 2008 at ATLAS, circumvents many of the problems associated with inverse kinematics. In this talk I will discuss the principle of the spectrometer as well as some of main physics results that have been obtained to date in nuclei ranging from {sup 13}B to {sup 137}Xe using both stable and radioactive beams.

Back, B. B. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Collaboration: HELIOS Collaboration

2012-10-20T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

SPEC-DOC: A USER'S GUIDE TO SPECTROMETER SOFTWARE  

SciTech Connect (OSTI)

SPEC is the name of the operating system designed to control the NMR spectrometers in lab. SPEC is actually one large program which handles many functions necessary to control each spectrometer. The program handles all I/O with peripheral devices such as the console ('terminal' or 'CRT'). The program carries out its operations by accepting commands which each invoke specific subroutines to perform their function. There are a total of 60 commands in SPEC, each carrying out a different function. Because so many commands make SPEC a very large program, not all of the program is core resident. Rather, each command calls in an overlay handler which loads into memory the appropriate overlay from the disk and begins execution of the command. Thus SPEC is an independent disk based operating system. The commands in SPEC are capable of operating the microprocessor based pulse programmer, starting and acquiring data from the spectrometer data acquisition system, storing data on disk and manipulating it mathematically, displaying and plotting data. All arithmetic operations within SPEC are performed on integers. Since the DATA GENERAL computers are 16 bit machines operating in two's complement mode, the integer range is +32767. Many of the mathematical operations of SPEC are done in double precision integer mode with the final result always scaled to the above range. For many of the commands, integer overflow is detected and reported as an error message. Overflowed points are set to +32767. SPEC accepts command input from the console or reads a string of commands previously entered on the disk. The later command structure is called a macro. Macros may be nested and may have constants passed to them at execution time, thus allowing for a powerful supercommand structure. Both forms of commands are discussed in the next section. SPEC is designed to run on a DATA GENERAL computer with 32K words of memory and a 10Mbyte hard disk system. There are minor differences between the various computers in lab which are discussed in one of the appendices. The disk systems consist of two. 5Mbyte platters, one fixed and one in a removable pack. While running SPEC, all disk I/O is with the fixed disk. All pulse programs, data records, phase box records, etc. reside on the fixed disk. Thus each disk drive is specific to one spectrometer. When running under RDOS (the DG operating system) these disk files may also be accessed. All the source listings of SPEC subroutines, the SPEC program library, and all supporting programs reside on one of the removable packs (labeled 'SPEC'). This pack will normally be in the drive but it is not required to run SPEC. It is required to run any of the supporting programs discussed in another chapter. This manual attempts to document the SPEC operating system and related topics. The following section discusses the general operation of SPEC including how to get into the program and how to issue commands. The following chapters discuss the commands in detail, operation of the microprocessor based pulse programmer, spectrometer peripherals, supporting programs, and how to create and load a 'TEMP' program. The appendices contain details on bootstrapping procedures, hardware specifics, a technical description of SPEC and how to change or recreate it, a description of microcode loading and the procedure for formatting floppy, disks and recreating RDGS.

Sinton, S.

1983-05-01T23:59:59.000Z

282

E-Print Network 3.0 - atomic emission spectrometer Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

spectrometer (MOSS) that is sensitive to the temporal ... Source: Howard, John - Plasma Research Laboratory, Research School of Physical Sciences and Engineering, Australian...

283

E-Print Network 3.0 - absorption gamma-ray spectrometer Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Explorit Topic List Advanced Search Sample search results for: absorption gamma-ray spectrometer Page: << < 1 2 3 4 5 > >> 1 The detection of nitrogen using nuclear...

284

Characterisation of deuterium spectra from laser driven multi-species sources by employing differentially filtered image plate detectors in Thomson spectrometers  

SciTech Connect (OSTI)

A novel method for characterising the full spectrum of deuteron ions emitted by laser driven multi-species ion sources is discussed. The procedure is based on using differential filtering over the detector of a Thompson parabola ion spectrometer, which enables discrimination of deuterium ions from heavier ion species with the same charge-to-mass ratio (such as C{sup 6+}, O{sup 8+}, etc.). Commonly used Fuji Image plates were used as detectors in the spectrometer, whose absolute response to deuterium ions over a wide range of energies was calibrated by using slotted CR-39 nuclear track detectors. A typical deuterium ion spectrum diagnosed in a recent experimental campaign is presented, which was produced from a thin deuterated plastic foil target irradiated by a high power laser.

Alejo, A.; Kar, S., E-mail: s.kar@qub.ac.uk; Ahmed, H.; Doria, D.; Green, A.; Jung, D.; Lewis, C. L. S.; Nersisyan, G. [Centre for Plasma Physics, School of Mathematics and Physics, Queen's University Belfast, Belfast BT7 1NN (United Kingdom); Krygier, A. G.; Freeman, R. R. [Department of Physics, The Ohio State University, Columbus, Ohio 43210 (United States); Clarke, R.; Green, J. S.; Notley, M. [Central Laser Facility, Rutherford Appleton Laboratory, Didcot, Oxfordshire OX11 0QX (United Kingdom); Fernandez, J. [Central Laser Facility, Rutherford Appleton Laboratory, Didcot, Oxfordshire OX11 0QX (United Kingdom); Instituto de Fusión Nuclear, Universidad Politécnica de Madrid, 28006 Madrid (Spain); Fuchs, J. [LULI, École Polytechnique, CNRS, CEA, UPMC, 91128 Palaiseau (France); Kleinschmidt, A.; Roth, M. [Institut für Kernphysik, Technische Universität Darmstadt, Schloßgartenstrasse 9, D-64289 Darmstadt (Germany); Morrison, J. T. [Propulsion Systems Directorate, Air Force Research Lab, Wright Patterson Air Force Base, Ohio 45433 (United States); Najmudin, Z.; Nakamura, H. [Blackett Laboratory, Department of Physics, Imperial College, London SW7 2AZ (United Kingdom); and others

2014-09-15T23:59:59.000Z

285

The use of strontium isotope ratio measurements by MC-ICP-MS for fundamental studies on diagenesis and for the reconstruction of animal migration at the Celtic excavation site Roseldorf.  

E-Print Network [OSTI]

??Die Anwendung von Strontiumisotopenmessungen im Bereich der anthropologischen und archäologischen Forschung bietet die Möglichkeit, Aufschlüsse über historische Fragestellungen zu erlangen, die Migrationsbewegungen von Menschen und… (more)

Theiner, Sarah

2011-01-01T23:59:59.000Z

286

Ion source for high-precision mass spectrometry  

DOE Patents [OSTI]

The invention is directed to a method for increasing the precision of positive-ion relative abundance measurements conducted in a sector mass spectrometer having an ion source for directing a beam of positive ions onto a collimating slit. The method comprises incorporating in the source an electrostatic lens assembly for providing a positive-ion beam of circular cross section for collimation by the slit. 2 figures, 3 tables.

Todd, P.J.; McKown, H.S.; Smith, D.H.

1982-04-26T23:59:59.000Z

287

Polarisation studies of the prompt gamma-ray emission from GRB 041219a using the Spectrometer aboard INTEGRAL  

E-Print Network [OSTI]

The spectrometer aboard INTEGRAL, SPI, has the capability to detect the signature of polarised emission from a bright gamma-ray source. GRB 041219a is the most intense burst localised by INTEGRAL and is an ideal candidate for such a study. Polarisation can be measured using multiple events scattered into adjacent detectors because the Compton scatter angle depends on the polarisation of the incoming photon. A search for linear polarisation in the most intense pulse of duration 66 seconds and in the brightest 12 seconds of GRB 041219a was performed in the 100-350keV, 100-500keV and 100keV-1MeV energy ranges. The multiple event data from the spectrometer was analysed and compared with the predicted instrument response obtained from Monte-Carlo simulations using the GEANT 4 INTEGRAL mass model. The chi^2 distribution between the real and simulated data as a function of the percentage polarisation and polarisation angle was calculated for all three energy ranges. The degree of linear polarisation in the brightest...

McGlynn, S; Dean, A J; Hanlon, L; McBreen, S; Willis, D R; McBreen, B; Bird, A J; Foley, S

2007-01-01T23:59:59.000Z

288

Two wide-angle imaging neutral-atom spectrometers  

SciTech Connect (OSTI)

The Two Wide-angle Imaging Neutral-atom Spectrometers (TWINS) mission provides a new capability for stereoscopically imaging the magnetosphere. By imaging the charge exchange neutral atoms over a broad energy range (1 < E , {approximately} 100 keV) using two identical instruments on two widely-spaced high-altitude, high-inclination spacecraft, TWINS will enable the 3-dimensional visualization and the resolution of large scale structures and dynamics within the magnetosphere for the first time. These observations will provide a leap ahead in the understanding of the global aspects of the terrestrial magnetosphere and directly address a number of critical issues in the ``Sun-Earth Connections`` science theme of the NASA Office of Space Science.

McComas, D.J.

1997-12-31T23:59:59.000Z

289

Report on Second Activations with the Lead Slowing Down Spectrometer  

SciTech Connect (OSTI)

Summary On August 18 and 19 2011, five items were irradiated with neutrons using the Lead Slowing Down Spectrometer (LSDS). After irradiation, dose measurements and gamma-spectrometry measurements were completed on all of the samples. No contamination was found on the samples, and all but one provided no dose. Gamma-spectroscopy measurements qualitatively agreed with expectations based on the materials. As during the first activation run, we observed activation in the room in general, mostly due to 56Mn and 24Na. Most of the activation of the samples was short lived, with half-lives on the scale of hours to days, except for 60Co which has a half-life of 5.3 y.

Stave, Sean C.; Mace, Emily K.; Pratt, Sharon L.; Warren, Glen A.

2012-04-27T23:59:59.000Z

290

Imaging X-ray Thomson Scattering Spectrometer Design and Demonstration  

SciTech Connect (OSTI)

In many laboratory astrophysics experiments, intense laser irradiation creates novel material conditions with large, one-dimensional gradients in the temperature, density, and ionization state. X-ray Thomson scattering is a powerful technique for measuring these plasma parameters. However, the scattered signal has previously been measured with little or no spatial resolution, which limits the ability to diagnose inhomogeneous plasmas. We report on the development of a new imaging x-ray Thomson spectrometer (IXTS) for the Omega laser facility. The diffraction of x-rays from a toroidally-curved crystal creates high-resolution images that are spatially resolved along a one-dimensional profile while spectrally dispersing the radiation. This focusing geometry allows for high brightness while localizing noise sources and improving the linearity of the dispersion. Preliminary results are presented from a scattering experiment that used the IXTS to measure the temperature profile of a shocked carbon foam.

Gamboa, E.J. [University of Michigan; Huntington, C.M. [University of Michigan; Trantham, M.R. [University of Michigan; Keiter, P.A [University of Michigan; Drake, R.P. [University of Michigan; Montgomery, David [Los Alamos National Laboratory; Benage, John F. [Los Alamos National Laboratory; Letzring, Samuel A. [Los Alamos National Laboratory

2012-05-04T23:59:59.000Z

291

Dynamic multiplexed analysis method using ion mobility spectrometer  

DOE Patents [OSTI]

A method for multiplexed analysis using ion mobility spectrometer in which the effectiveness and efficiency of the multiplexed method is optimized by automatically adjusting rates of passage of analyte materials through an IMS drift tube during operation of the system. This automatic adjustment is performed by the IMS instrument itself after determining the appropriate levels of adjustment according to the method of the present invention. In one example, the adjustment of the rates of passage for these materials is determined by quantifying the total number of analyte molecules delivered to the ion trap in a preselected period of time, comparing this number to the charge capacity of the ion trap, selecting a gate opening sequence; and implementing the selected gate opening sequence to obtain a preselected rate of analytes within said IMS drift tube.

Belov, Mikhail E [Richland, WA

2010-05-18T23:59:59.000Z

292

Aerosol beam-focus laser-induced plasma spectrometer device  

DOE Patents [OSTI]

An apparatus for detecting elements in an aerosol includes an aerosol beam focuser for concentrating aerosol into an aerosol beam; a laser for directing a laser beam into the aerosol beam to form a plasma; a detection device that detects a wavelength of a light emission caused by the formation of the plasma. The detection device can be a spectrometer having at least one grating and a gated intensified charge-coupled device. The apparatus may also include a processor that correlates the wavelength of the light emission caused by the formation of the plasma with an identity of an element that corresponds to the wavelength. Furthermore, the apparatus can also include an aerosol generator for forming an aerosol beam from bulk materials. A method for detecting elements in an aerosol is also disclosed.

Cheng, Meng-Dawn (Oak Ridge, TN)

2002-01-01T23:59:59.000Z

293

Two wide-angle imaging neutral-atom spectrometers (TWINS)  

SciTech Connect (OSTI)

Two Wide-angle Imaging Neutral-atom Spectrometers (TWINS) is a revolutionary new mission designed to stereoscopically image the magnetosphere in charge exchange neutral atoms for the first time. The authors propose to fly two identical TWINS instruments as a mission of opportunity on two widely-spaced high-altitude, high-inclination US Government spacecraft. Because the spacecraft are funded independently, TWINS can provide a vast quantity of high priority science observations (as identified in an ongoing new missions concept study and the Sun-Earth Connections Roadmap) at a small fraction of the cost of a dedicated mission. Because stereo observations of the near-Earth space environs will provide a particularly graphic means for visualizing the magnetosphere in action, and because of the dedication and commitment of the investigator team to the principles of carrying space science to the broader audience, TWINS will also be an outstanding tool for public education and outreach.

McComas, D.J. [Los Alamos National Lab., NM (United States)] [Los Alamos National Lab., NM (United States); Blake, B. [Aerospace Corp., CA (United States)] [Aerospace Corp., CA (United States); Burch, J. [Southwest Research Inst., San Antonio, TX (United States)] [and others] [Southwest Research Inst., San Antonio, TX (United States); and others

1998-11-01T23:59:59.000Z

294

Isotopic response with small scintillator based gamma-ray spectrometers  

DOE Patents [OSTI]

The intrinsic background of a gamma ray spectrometer is significantly reduced by surrounding the scintillator with a second scintillator. This second (external) scintillator surrounds the first scintillator and has an opening of approximately the same diameter as the smaller central scintillator in the forward direction. The second scintillator is selected to have a higher atomic number, and thus has a larger probability for a Compton scattering interaction than within the inner region. Scattering events that are essentially simultaneous in coincidence to the first and second scintillators, from an electronics perspective, are precluded electronically from the data stream. Thus, only gamma-rays that are wholly contained in the smaller central scintillator are used for analytic purposes.

Madden, Norman W. (Sparks, NV); Goulding, Frederick S. (Lafayette, CA); Asztalos, Stephen J. (Oakland, CA)

2012-01-24T23:59:59.000Z

295

The data processing pipeline for the Herschel/SPIRE Imaging Fourier Transform Spectrometer  

E-Print Network [OSTI]

The data processing pipeline for the Herschel/SPIRE Imaging Fourier Transform Spectrometer Trevor R the data processing pipeline to generate calibrated data products from the Spectral and Photometric Imaging Receiver (SPIRE) imaging Fourier Transform Spectrometer. The pipeline processes telemetry from SPIRE point

Naylor, David A.

296

Simulation-guided optimization of small-angle analyzer geometry in the neutron backscattering spectrometer SPHERES  

SciTech Connect (OSTI)

The resolution of neutron backscattering spectrometers deteriorates at small scattering angles where analyzers deviate from exact backscattering. By reducing the azimuth angle range of the analyzers, the resolution can be improved with little loss of peak intensity. Measurements at the spectrometer SPHERES are in excellent agreement with simulations, which proves the dominance of geometric effects.

Wuttke, Joachim; Zamponi, Michaela [Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science at MLZ, Lichtenbergstraße 1, 85747 Garching (Germany)] [Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science at MLZ, Lichtenbergstraße 1, 85747 Garching (Germany)

2013-11-15T23:59:59.000Z

297

Direct determination of Neutrino Mass from Tritium Beta Spectrum  

E-Print Network [OSTI]

The investigation of the endpoint region of the tritium beta decay spectrum is still the most sensitive direct method to determine the neutrino mass scale. In the nineties and the beginning of this century the tritium beta decay experiments at Mainz and Troitsk have reached a sensitivity on the neutrino mass of 2 eV/c^2 . They were using a new type of high-resolution spectrometer with large sensitivity, the MAC-E-Filter, and were studying the systematics in detail. Currently, the KATRIN experiment is being set up at Forschungszentrum Karlsruhe, Germany. KATRIN will improve the neutrino mass sensitivity by one order of magnitude down to 0.2 eV/c^2, sufficient to cover the degenerate neutrino mass scenarios and the cosmologically relevant neutrino mass range.

C. Weinheimer

2009-12-08T23:59:59.000Z

298

Echelle grating multi-order imaging spectrometer utilizing a catadioptric lens  

DOE Patents [OSTI]

A cryogenically cooled imaging spectrometer that includes a spectrometer housing having a first side and a second side opposite the first side. An entrance slit is on the first side of the spectrometer housing and directs light to a cross-disperser grating. An echelle immersions grating and a catadioptric lens are positioned in the housing to receive the light. A cryogenically cooled detector is located in the housing on the second side of the spectrometer housing. Light from the entrance slit is directed to the cross-disperser grating. The light is directed from the cross-disperser grating to the echelle immersions grating. The light is directed from the echelle immersions grating to the cryogenically cooled detector on the second side of the spectrometer housing.

Chrisp, Michael P; Bowers, Joel M

2014-05-27T23:59:59.000Z

299

Method for analyzing the mass of a sample using a cold cathode ionization source mass filter  

DOE Patents [OSTI]

An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

Felter, Thomas E.

2003-10-14T23:59:59.000Z

300

J. Environ. Radioactivity 5 (1987)425--444 The Mass Spectrometric Determination of Fallout  

E-Print Network [OSTI]

and Justin E. Halverson Savannah River Laboratory,,Aiken, SouthCarolina29808,USA (Received 17November 1986 in this study is operated by E. I. DuPont de Nemours & Co. at the Savannah River Laboratory (S.R.L.) in South Carolina. The instrument was designed and built similar to other mass spectrometers within the national

Buesseler, Ken

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Laser vaporization/ionization interface for coupling microscale separation techniques with mass spectrometry  

DOE Patents [OSTI]

The present invention provides a laser-induced vaporization and ionization interface for directly coupling microscale separation processes to a mass spectrometer. Vaporization and ionization of the separated analytes are facilitated by the addition of a light-absorbing component to the separation buffer or solvent. 8 figs.

Yeung, E.S.; Chang, Y.C.

1999-06-29T23:59:59.000Z

302

²?²Cf-plasma desorption mass spectrometry of RNA nucleosides  

E-Print Network [OSTI]

~ CH5 + CH3 CH3 + CH4 ~ C2H5 + H2 Proton or hydride transfer reactions of these secondary ions with the sample molecule produce the major portion of the CI mass spectra. Because the molecular ions are formed by these chemical reactions... low, and co'1'lisional deactivation between sample fons and air molecules results in a loss of intensity and resolution for the sample ions detected. -7 The vacuum in the mass spectrometer is maintained in the 10 16 torr region by a Sargent...

Piper, Duane Gilbert

1976-01-01T23:59:59.000Z

303

Potential incorporation of transuranics into uranium phases  

SciTech Connect (OSTI)

The UO{sub 2} in spent nuclear fuel is unstable under moist oxidizing conditions and will be altered to uranyl oxide hydrate phases. The transuranics released during the corrosion of spent fuel may also be incorporated into the structures of secondary U{sup 6+} phases. The incorporation of radionuclides into alteration products will affect their mobility. A series of precipitation tests were conducted at either 150 or 90 C for seven days to determine the potential incorporation of Ce{sup 4+} and Nd{sup 3+} (surrogates for Pu{sup 4+} and Am{sup 3+}, respectively) into uranium phases. Ianthinite ([U{sub 2}{sup 4+}(UO{sub 2}){sub 4}O{sub 6}(OH){sub 4}(H{sub 2}O){sub 4}](H{sub 2}O){sub 5}) was produced by dissolving uranium oxyacetate in a solution containing copper acetate monohydrate as a reductant. The leachant used in these tests were doped with either 2.1 ppm cerium or 399 ppm neodymium. Inductively coupled plasma-mass spectrometer (ICP-MS) analysis of the solid phase reaction products which were dissolved in a HNO{sub 3} solution indicates that about 306 ppm Ce (K{sub d} = 146) was incorporated into ianthinite, while neodymium contents were much higher, being approximately 24,800 ppm (K{sub d} = 62). Solid phase examinations using an analytical transmission electron microscope/electron energy-loss spectrometer (AEM/EELS) indicate a uniform distribution of Nd, while Ce contents were below detection. Becquerelite (Ca[(UO{sub 2}){sub 6}O{sub 4}(OH){sub 6}]{center_dot}8H{sub 2}O) was produced by dissolving uranium oxyacetate in a solution containing calcium acetate. The leachant in these tests was doped with either 2.1 ppm cerium or 277 ppm neodymium. ICP-MS results indicate that about 33 ppm Ce (K{sub d}=16) was incorporated into becquerelite, while neodymium contents were higher, being approximately 1,300 ppm (K{sub d}=5). Homogeneous distribution of Nd in the solid phase was noted during AEM/EELS examination, and Ce contents were also below detection.

Kim, C. W.; Wronkiewicz, D. J.; Buck, E. C.

1999-12-07T23:59:59.000Z

304

ONE-DIMENSIONAL MODELING FOR TEMPERATURE-DEPENDENT UPFLOW IN THE DIMMING REGION OBSERVED BY HINODE/EUV IMAGING SPECTROMETER  

SciTech Connect (OSTI)

We previously found a temperature-dependent upflow in the dimming region following a coronal mass ejection observed by the Hinode EUV Imaging Spectrometer (EIS). In this paper, we reanalyzed the observations along with previous work on this event and provided boundary conditions for modeling. We found that the intensity in the dimming region dramatically drops within 30 minutes from the flare onset, and the dimming region reaches the equilibrium stage after {approx}1 hr. The temperature-dependent upflows were observed during the equilibrium stage by EIS. The cross-sectional area of the flux tube in the dimming region does not appear to expand significantly. From the observational constraints, we reconstructed the temperature-dependent upflow by using a new method that considers the mass and momentum conservation law and demonstrated the height variation of plasma conditions in the dimming region. We found that a super-radial expansion of the cross-sectional area is required to satisfy the mass conservation and momentum equations. There is a steep temperature and velocity gradient of around 7 Mm from the solar surface. This result may suggest that the strong heating occurred above 7 Mm from the solar surface in the dimming region. We also showed that the ionization equilibrium assumption in the dimming region is violated, especially in the higher temperature range.

Imada, S.; Shimizu, T. [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, Chuo-ku, Sagamihara-shi, Kanagawa 252-5210 (Japan); Hara, H.; Watanabe, T. [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka-shi, Tokyo 181-8588 (Japan); Murakami, I. [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki, Gifu 509-5292 (Japan); Harra, L. K. [UCL-Mullard Space Science Laboratory, Holmbury St Mary, Dorking, Surrey, RH5 6NT (United Kingdom); Zweibel, E. G. [Department of Astronomy, University of Wisconsin-Madison, 475 N Charter Street, Madison, WI 53706 (United States)

2011-12-10T23:59:59.000Z

305

Neutron flux estimations based on niobium impurities in reactor pressure vessel steel  

SciTech Connect (OSTI)

The use of (ppm level) niobium impurities in reactor pressure vessel (RPV) steel for neutron flux estimations based on the reaction {sup 93}Nb (n,n{prime}) {sup 93m}Nb has been reported previously. The method has now been further investigated and refined. Small niobium fractions in RPV steel ({approx} ppm) and plating ({approx} 1%) materials have been separated by ion exchange chromatography in one to three steps. The measured Nb fractions in samples from some four pressure vessel (RPV) base materials were 1 to 3 ppm. The purification of tens of milligrams of RPV material provides sufficient amounts of niobium for mass determination with a highly sensitive (10{sup {minus}5} ppm) Inductively Coupled Plasma Mass Spectrometer (ICP-MS). The {sup 93m}Nb and small remaining {sup 54}Mn activities were measured with a Calibrated Liquid Scintillation Counter (LSC) based on dual label technique and almost 100% efficiency to {sup 93m}Nb. One purification is needed for plating materials ({approx}1% Nb) and two purifications of about one gram of steel with Nb impurities in order to resolve the needed activities ({approx}10 Bq {sup 93m}Nb/{mu}g Nb). The achieved accuracy of the measured specific {sup 93m}Nb activities was about {+-} 3% (1{sigma}) in irradiated RPV plating materials and about {+-} 4% for Nb ppm impurities.

Baers, L.B.; Hasanen, E.K. [Technical Research Centre of Finland, Espoo (Finland). Reactor Lab.

1994-12-31T23:59:59.000Z

306

Analytical Chemistry Division annual progress report for period ending December 31, 1991  

SciTech Connect (OSTI)

The following sentences highlight some of the technical activities carried out during 1991. They illustrate the diversity of programs and technical work performed within the Analytical Chemistry Division. Our neutron activation analysis laboratory at HFIR was placed into operation during 1991. We have combined inductively coupled plasma mass spectrometry (ICP/MS) with a preparation procedure developed at the Argonne National Laboratory to measure ultra-trace levels of U, Pu, Np, and Am in body fluids, primarily urine. Much progress has been made over the last year in the interfacing of an rf-powered glow discharge source to a double-focusing mass spectrometer. Preliminary experiments using electrospray ionization combined with ion trap mass spectrometry show much promise for the analysis of metals in solution. A secondary ion microprobe has been constructed that permits determination of the distribution of organic compounds less than a monolayer thick on samples as large as 1 cm diameter. Fourier transform mass spectrometry has been demonstrated to be a highly effective tool for the detailed characterization of biopolymers, especially normal and modified oligonucleotides. Much has been accomplished in understanding the fundamentals of quadrupole ion trap mass spectrometry. Work with ITMS instrumentation has led to the development of rapid methods for the detection of trace organics in environmental and physiological samples. A new type of time-of-flight mass spectrometer was designed for use with our positron ionization experiments. Fundamental research on chromatography at high concentrations and on gas-solid adsorption has continued. The preparation of a monograph on the chemistry of environmental tobacco smoke was completed this year.

NONE

1992-01-01T23:59:59.000Z

307

Multichannel CdZnTe Gamma Ray Spectrometer  

SciTech Connect (OSTI)

A 3 cm{sup 3} multichannel gamma spectrometer for DOE applications is under development by Digirad Corporation. The device is based on a position sensitive detector packaged in a compact multi-chip module (MCM) with integrated readout circuitry. The modular, multichannel design will enable identification and quantitative analysis of radionuclides in extended sources, or sources containing low levels of activity. The MCM approach has the advantages that the modules are designed for imaging applications, and the sensitivity can be arbitrarily increased by increasing the number of pixels, i.e. adding modules to the instrument. For a high sensitivity probe, the outputs for each pixel can be corrected for gain and offset variations, and summed digitally. Single pixel results obtained with discrete low noise readout indicate energy resolution of 3 keV can be approached with currently available CdZnTe. The energy resolution demonstrated to date with MCMs for 511 keV gamma rays is 10 keV.

F. P. Doty; C. L. Lingren; B. A. Apotovsky; J. Brunsch; J. F. Butler; T. Collins; R. L. Conwell; S. Friesenhahn; J. Gormley; B. Pi; S. Zhao (Digirad Corp., San Diego, CA); F. L. Augustine, Augustine Engineering, Encinitas, CA; B. A. Bennet; E. Cross; R. B. James (Sandia Nat'l. Labs.)

1998-07-22T23:59:59.000Z

308

In-situ droplet monitoring for self-tuning spectrometers  

DOE Patents [OSTI]

A laser scattering based imaging technique is utilized in order to visualize the aerosol droplets in an inductively coupled plasma (ICP) torch from an aerosol source to the site of analytical measurements. The resulting snapshots provide key information about the spatial distribution of the aerosol introduced by direct and indirect injection devices: 1) a direct injection high efficiency nebulizer (DIHEN); 2) a large-bore DIHEN (LB-DIHEN); and 3) a PFA microflow nebulizer with a PFA Scott-type spray chamber. Moreover, particle image velocimetry (PIV) is used to study the in-situ behavior of the aerosol before interaction with, for example, plasma, while the individual surviving droplets are explored by particle tracking velocimetry (PTV). Further, the velocity distribution of the surviving droplets demonstrates the importance of the initial droplet velocities in complete desolvation of the aerosol for optimum analytical performance in ICP spectrometries. These new observations are important in the design of the next-generation direct injection devices for lower sample consumption, higher sensitivity, lower noise levels, suppressed matrix effects, and for developing smart spectrometers. For example, a controller can be provided to control the output of the aerosol source by controlling the configuration of the source or the gas flow rate via feedback information concerning the aerosol.

Montaser, Akbar (Potomac, MD); Jorabchi, Kaveh (Arlington, VA); Kahen, Kaveh (Kleinburg, CA)

2010-09-28T23:59:59.000Z

309

THE COSMIC INFRARED BACKGROUND EXPERIMENT (CIBER): THE LOW RESOLUTION SPECTROMETER  

SciTech Connect (OSTI)

Absolute spectrophotometric measurements of diffuse radiation at 1 {mu}m to 2 {mu}m are crucial to our understanding of the radiative content of the universe from nucleosynthesis since the epoch of reionization, the composition and structure of the zodiacal dust cloud in our solar system, and the diffuse galactic light arising from starlight scattered by interstellar dust. The Low Resolution Spectrometer (LRS) on the rocket-borne Cosmic Infrared Background Experiment is a {lambda}/{Delta}{lambda} {approx} 15-30 absolute spectrophotometer designed to make precision measurements of the absolute near-infrared sky brightness between 0.75 {mu}m <{lambda} < 2.1 {mu}m. This paper presents the optical, mechanical, and electronic design of the LRS, as well as the ground testing, characterization, and calibration measurements undertaken before flight to verify its performance. The LRS is shown to work to specifications, achieving the necessary optical and sensitivity performance. We describe our understanding and control of sources of systematic error for absolute photometry of the near-infrared extragalactic background light.

Tsumura, K.; Arai, T.; Matsumoto, T.; Matsuura, S.; Murata, K. [Department of Space Astronomy and Astrophysics, Institute of Space and Astronoutical Science (ISAS), Japan Aerospace Exploration Agency (JAXA), Sagamihara, Kanagawa 252-5210 (Japan); Battle, J.; Bock, J. [Jet Propulsion Laboratory (JPL), National Aeronautics and Space Administration (NASA), Pasadena, CA 91109 (United States); Brown, S.; Lykke, K.; Smith, A. [Optical Technology Division, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States); Cooray, A. [Center for Cosmology, University of California, Irvine, Irvine, CA 92697 (United States); Hristov, V.; Levenson, L. R.; Mason, P. [Department of Astronomy, California Institute of Technology, Pasadena, CA 91125 (United States); Keating, B.; Renbarger, T. [Department of Physics, University of California, San Diego, San Diego, CA 92093 (United States); Kim, M. G. [Department of Physics and Astronomy, Seoul National University, Seoul 151-742 (Korea, Republic of); Lee, D. H.; Nam, U. W. [Korea Astronomy and Space Science Institute (KASI), Daejeon 305-348 (Korea, Republic of); Sullivan, I., E-mail: tsumura@ir.isas.jaxa.jp [Department of Physics, The University of Washington, Seattle, WA 98195 (United States); and others

2013-08-15T23:59:59.000Z

310

X-ray crystal spectrometer upgrade for ITER-like wall experiments at JET  

SciTech Connect (OSTI)

The high resolution X-Ray crystal spectrometer at the JET tokamak has been upgraded with the main goal of measuring the tungsten impurity concentration. This is important for understanding impurity accumulation in the plasma after installation of the JET ITER-like wall (main chamber: Be, divertor: W). This contribution provides details of the upgraded spectrometer with a focus on the aspects important for spectral analysis and plasma parameter calculation. In particular, we describe the determination of the spectrometer sensitivity: important for impurity concentration determination.

Shumack, A. E., E-mail: amy.shumack@ccfe.ac.uk [JET-EFDA, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); FOM Institute DIFFER, P.O. Box 1207, NL-3430 BE Nieuwegein (Netherlands); Rzadkiewicz, J. [National Centre for Nuclear Research, Andrzeja So?tana 7, 05-400 Otwock (Poland); Chernyshova, M.; Czarski, T.; Karpinski, L. [Institute of Plasma Physics and Laser Microfusion, Hery 23, 01-497 Warsaw (Poland); Jakubowska, K. [Institute of Plasma Physics and Laser Microfusion, Hery 23, 01-497 Warsaw (Poland); Université Bordeaux, CNRS, CEA, CELIA, UMR 5107, F-33405 Talence (France); Scholz, M. [Institute of Nuclear Physics PAN, ul. Radzikowskiego 152, 31-342 Kraków (Poland); Byszuk, A.; Cieszewski, R.; Kasprowicz, G.; Pozniak, K.; Wojenski, A.; Zabolotny, W. [Institute of Electronic Systems, Warsaw University of Technology, 00-665 Warsaw (Poland); Dominik, W. [Faculty of Physics, Institute of Experimental Physics, Warsaw University, 00-681 Warsaw (Poland); Conway, N. J.; Dalley, S.; Tyrrell, S.; Zastrow, K.-D. [JET-EFDA, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Figueiredo, J. [EFDA-CSU, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Associação EURATOM/IST, Instituto de Plasmas e Fusão Nuclear, Instituto Superior Técnico, Av Rovisco Pais, 1049-001 Lisbon (Portugal); and others

2014-11-15T23:59:59.000Z

311

High-Sensitivity Delayed-Coincidence Spectrometer to Search for Short-Lived Nuclear States  

E-Print Network [OSTI]

A high-sensitivity four-dimensional triple-coincidence spectrometer with two detectors is developed on the basis of an autocorrelation single-crystal scintillation time 4{\\pi} spectrometer and a semiconductor HPGe detector. The delayed-coincidence spectrometer is designed for searching for isomeric nano- and microsecond states in short-lived nuclei and for their related gamma-rays. Half-lives of short-lived states are measured in the range from 4 ns to 4 {\\mu}s. The sufficient activity of the monoisotopic source for the investigations does not exceed 0.01 {\\mu}Ci.

Morozov, V A; Norseev, Yu V; Sereeter, Z; Zlokazov, V B

2002-01-01T23:59:59.000Z

312

A high-resolution imaging x-ray crystal spectrometer for high energy density plasmas  

SciTech Connect (OSTI)

Adapting a concept developed for magnetic confinement fusion experiments, an imaging crystal spectrometer has been designed and tested for HED plasmas. The instrument uses a spherically bent quartz [211] crystal with radius of curvature of 490.8 mm. The instrument was tested at the Titan laser at Lawrence Livermore National Laboratory by irradiating titanium slabs with laser intensities of 10{sup 19}–10{sup 20} W/cm{sup 2}. He-like and Li-like Ti lines were recorded, from which the spectrometer performance was evaluated. This spectrometer provides very high spectral resolving power (E/dE > 7000) while acquiring a one-dimensional image of the source.

Chen, Hui, E-mail: chen33@llnl.gov, E-mail: bitter@pppl.gov; Magee, E.; Nagel, S. R.; Park, J.; Schneider, M. B.; Stone, G.; Williams, G. J.; Beiersdorfer, P. [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550-9234 (United States); Bitter, M., E-mail: chen33@llnl.gov, E-mail: bitter@pppl.gov; Hill, K. W. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Kerr, S. [Department of Applied Science, University of Alberta, Edmonton, Alberta T6G 2R3 (Canada)

2014-11-15T23:59:59.000Z

313

A source of ultra-cold neutrons for the gravitational spectrometer GRANIT  

E-Print Network [OSTI]

We present the status of the development of a dedicated high density ultra-cold neutron (UCN) source dedicated to the gravitational spectrometer GRANIT. The source employs superthermal conversion of cold neutrons to UCN in superfluid helium. Tests have shown that UCN produced inside the liquid can be extracted into vacuum. Furthermore a dedicated neutron selection channel was tested to maintain high initial density and extract only neutrons with a vertical velocity component 20 cm/s for the spectrometer. This new source would have a phase-space density of 0.18 cm-3(m/s)-3 for the spectrometer.

Schmidt-Wellenburg, P; Nesvizhevsky, V V; Plonka, C; Soldner, T; Vezzu, F; Zimmer, O

2007-01-01T23:59:59.000Z

314

A source of ultra-cold neutrons for the gravitational spectrometer GRANIT  

E-Print Network [OSTI]

We present the status of the development of a dedicated high density ultra-cold neutron (UCN) source dedicated to the gravitational spectrometer GRANIT. The source employs superthermal conversion of cold neutrons to UCN in superfluid helium. Tests have shown that UCN produced inside the liquid can be extracted into vacuum. Furthermore a dedicated neutron selection channel was tested to maintain high initial density and extract only neutrons with a vertical velocity component 20 cm/s for the spectrometer. This new source would have a phase-space density of 0.18 cm-3(m/s)-3 for the spectrometer.

P. Schmidt-Wellenburg; P. Geltenbort; V. V. Nesvizhevsky; C. Plonka; T. Soldner; F. Vezzu; O. Zimmer

2007-08-21T23:59:59.000Z

315

DC superconducting quantum interference device usable in nuclear quadrupole resonance and zero field nuclear magnetic spectrometers  

DOE Patents [OSTI]

A spectrometer for measuring the nuclear quadrupole resonance spectra or the zero-field nuclear magnetic resonance spectra generated by a sample is disclosed. The spectrometer uses an amplifier having a dc SQUID operating in a flux-locked loop for generating an amplified output as a function of the intensity of the signal generated by the sample. The flux-locked loop circuit includes an integrator. The amplifier also includes means for preventing the integrator from being driven into saturation. As a result, the time for the flux-locked loop to recover from the excitation pulses generated by the spectrometer is reduced. 7 figures.

Fan, N.Q.; Clarke, J.

1993-10-19T23:59:59.000Z

316

DC superconducting quantum interference device usable in nuclear quadrupole resonance and zero field nuclear magnetic spectrometers  

DOE Patents [OSTI]

A spectrometer for measuring the nuclear quadrupole resonance spectra or the zero-field nuclear magnetic resonance spectra generated by a sample is disclosed. The spectrometer uses an amplifier having a dc SQUID operating in a flux-locked loop for generating an amplified output as a function of the intensity of the signal generated by the sample. The flux-locked loop circuit includes an integrator. The amplifier also includes means for preventing the integrator from being driven into saturation. As a result, the time for the flux-locked loop to recover from the excitation pulses generated by the spectrometer is reduced.

Fan, Non Q. (San Diego, CA); Clarke, John (Berkeley, CA)

1993-01-01T23:59:59.000Z

317

FIELD TEST OF THE WATER-WHEEL IR (WIR) SPECTROMETER ON EVAPORATIVE SALT DEPOSITS AT TIBETAN PLATEAU. P. Sobron, J. J. Freeman, Alian Wang, Dept Earth and Planetary Sciences  

E-Print Network [OSTI]

"contact survey", i.e., to install a WIR unit inside of a well set into the middle wheel of a pla- netary of WIR has a size of 10x7.5x6.5cm, mass of 450 grams, power consump- tion of 4W, and output data through transformed into a rugged, field portable NIR reflectance spectrometer that is able to operate in tough field

318

Flat Quartz-Crystal X-ray Spectrometer for Nuclear Forensics Applications  

E-Print Network [OSTI]

structure. The higher energy background radiation was blocked from reaching the detector using a customized collimator and shielding system. A flat quartz-crystal x-ray spectrometer system was designed specifically to fit the constraints and requirements...

Goodsell, Alison

2012-10-19T23:59:59.000Z

319

E-Print Network 3.0 - atomic absorption spectrometer Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometer Page: << < 1 2 3 4 5 > >> 1 In the post-genome era, the...

320

Superconducting gamma and fast-neutron spectrometers with high energy resolution  

DOE Patents [OSTI]

Superconducting Gamma-ray and fast-neutron spectrometers with very high energy resolution operated at very low temperatures are provided. The sensor consists of a bulk absorber and a superconducting thermometer weakly coupled to a cold reservoir, and determines the energy of the incident particle from the rise in temperature upon absorption. A superconducting film operated at the transition between its superconducting and its normal state is used as the thermometer, and sensor operation at reservoir temperatures around 0.1 K reduces thermal fluctuations and thus enables very high energy resolution. Depending on the choice of absorber material, the spectrometer can be configured either as a Gamma-spectrometer or as a fast-neutron spectrometer.

Friedrich, Stephan (San Jose, CA); , Niedermayr, Thomas R. (Oakland, CA); Labov, Simon E. (Berkeley, CA)

2008-11-04T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Progress on the Modeling and Modification of the MICE Superconducting Spectrometer Solenoids  

E-Print Network [OSTI]

updated calculations confirmed the measured heat load of ~6of these calculations was the direct heat load into the coldcalculations was carried out in order to characterize the spectrometer solenoid heat loads

Virostek, S.P.

2013-01-01T23:59:59.000Z

322

Addition and recombination reactions of unsaturated radicals using a novel laser kinetics spectrometer  

E-Print Network [OSTI]

This thesis describes the construction of a novel, low-noise laser kinetics spectrometer. A quasi-CW (picosecond pulse), tunable Ti:Sapphire laser is used to detect various transient species in laser flash photolysis ...

Ismail, Huzeifa

2008-01-01T23:59:59.000Z

323

E-Print Network 3.0 - axis neutron spectrometer Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

results for: axis neutron spectrometer Page: << < 1 2 3 4 5 > >> 1 For more information: Neutron Scattering Science User Office, neutronusers@ornl.gov or (865) 574-4600. Summary:...

324

Characterization of AP-MALDI and ESI for a differential mobility spectrometer  

E-Print Network [OSTI]

The following thesis entails the construction, testing, modification, and analysis of two systems that couple sample ion introduction methods with a Differential Mobility Spectrometer (DMS). The sample ionization methods ...

Agrawal, Priya

2005-01-01T23:59:59.000Z

325

Calibration of a gated flat field spectrometer as a function of x-ray intensity  

SciTech Connect (OSTI)

We present an experimental determination of the response of a gated flat-field spectrometer at the Shenguang-II laser facility. X-rays were emitted from a target that was heated by laser beams and then were divided into different intensities with a step aluminum filter and collected by a spectrometer. The transmission of the filter was calibrated using the Beijing Synchrotron Radiation Facility. The response characteristics of the spectrometer were determined by comparing the counts recorded by the spectrometer with the relative intensities of the x-rays transmitted through the step aluminum filter. The response characteristics were used to correct the transmission from two shots of an opacity experiment using the same samples. The transmissions from the two shots are consistent with corrections, but discrepant without corrections.

Xiong, Gang; Yang, Guohong; Li, Hang; Zhang, Jiyan, E-mail: zhangjiyanzjy@sina.com; Zhao, Yang; Hu, Zhimin; Wei, Minxi; Qing, Bo; Yang, Jiamin; Liu, Shenye; Jiang, Shaoen [Research Center of Laser Fusion, China Academy of Engineering Physics, P. O. Box 919-986, Mianyang 621900 (China)] [Research Center of Laser Fusion, China Academy of Engineering Physics, P. O. Box 919-986, Mianyang 621900 (China)

2014-04-15T23:59:59.000Z

326

A simple scanning spectrometer based on a stretchable elastomeric reflective grating  

SciTech Connect (OSTI)

We report a scanning optical spectrometer based on the use of a stretchable elastomeric reflective grating. The grating is obtained by supersonic cluster beam implantation of silver nanoparticles on polydimethylsiloxane previously grooved by molding to create a replica of a commercial digital versatile disk grating. The use of a stretchable grating allows the spectrometer spanning the whole optical wavelength range by solely extending the diffraction element by more than 100% of its original dimensions. The stretchable reflective optical grating shows excellent performances and stability upon thousands of stretching cycles. The use of this elastomeric element makes the optical layout and the mechanics of the spectrometer extremely simple and advantageous for those applications where spectral resolution is not a major requirement. As a proof of principle, we present the absorption spectrum of Rhodamine B in solution obtained by our spectrometer and compared to commercial instruments.

Ghisleri, C.; Milani, P., E-mail: paolo.milani@mi.infn.it [CIMAINA and Dipartimento di Fisica, Università di Milano, via Celoria 16, 20133 Milano (Italy); WISE srl, Piazza Duse 2, 20122 Milano (Italy); Potenza, M. A. C.; Bellacicca, A. [CIMAINA and Dipartimento di Fisica, Università di Milano, via Celoria 16, 20133 Milano (Italy); Ravagnan, L. [WISE srl, Piazza Duse 2, 20122 Milano (Italy)

2014-02-10T23:59:59.000Z

327

E-Print Network 3.0 - airborne gamma-ray spectrometer Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Powered by Explorit Topic List Advanced Search Sample search results for: airborne gamma-ray spectrometer Page: << < 1 2 3 4 5 > >> 1 GAMMA RAYS FROM MAJOR ELEMENTS BY THERMAL...

328

Upgrade of the PNNL TEPC and Multisphere Spectrometer  

SciTech Connect (OSTI)

The Pacific Northwest National Laboratory (PNNL) has used two types of instruments, the tissue equivalent proportional counter (TEPC) and the multisphere spectrometer for characterizing neutron radiation fields in support of neutron dosimetry at the Hanford site. The US Department of Energy recently issued new requirements for radiation protection standards in 10 CFR 835 which affect the way that neutron dose equivalent rates are evaluated. In response to the new requirements, PNNL has upgraded the analyses used in conjunction with the TEPC and multisphere. The analysis software for the TEPC was modified for this effort, and a new analysis code was selected for the multisphere. These new analysis techniques were implemented and tested with measurement data that had been collected in previous measurements. In order to test the effectiveness of the changes, measurements were taken in PNNL’s Low Scatter Room using 252Cf sources in both unmoderated and D2O-moderated configurations that generate well-characterized neutron fields. The instruments were also used at Los Alamos National Laboratory (LANL), in their Neutron Free-in-Air calibration room, also using neutron sources that generate well-characterized neutron fields. The results of the software modifications and the measurements are documented in this report. The TEPC measurements performed at PNNL agreed well with accepted dose equivalent rates using the traditional analysis, agreeing with the accepted value to within 13% for both unmoderated and moderated 252Cf sources. When the new analysis was applied to the TEPC measurement data, the results were high compared to the new accepted value. A similar pattern was seen for TEPC measurements at LANL. Using the traditional analysis method, results for all neutron sources showed good agreement with accepted values, nearly always less than 10%. For the new method of analysis, however, the TEPC responded with higher dose equivalent rates than accepted, by as much as 25%. The reason for the overresponse is that there is very little attenuation of the neutrons by tissue, so it cannot match the effect of attenuation by 1 cm of tissue called for in the new standards. This could be corrected with a modified instrument with a thicker wall, or by analytical means that would need to be developed. The multisphere spectrometer performed reasonably well both at PNNL and at LANL. It could produce a neutron spectrum that was similar to the accepted spectrum, and total flux values were usually within 15% of the accepted values. Dose equivalent rates were usually within 18% of the accepted values. The average energies, however, were usually lower than the accepted values. The performance of this instrument could be much better than seen in this study. If PNNL were to add some moderating spheres to its measurement set and calculate a new set of instrument response functions, performance could be improved. The multisphere could then be a more useful instrument for assessing the dose equivalent rate in the workplace.

Scherpelz, Robert I.; Conrady, Matthew M.

2008-09-10T23:59:59.000Z

329

Developing improved nuclear magnetic resonance marginal oscillator spectrometers for advanced teaching laboratories  

E-Print Network [OSTI]

DEVELOPING IMPROVED NUCLEAR MAGNETIC RESONANCE MARGINAL OSCILLATOR SPECTROMETERS FOR ADVANCED TEACHING LABORATORIES A Thesis by FRANK PHILLIP WILLINGHAM Submitted to the Office of Graduate Studies of Texas ASM University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE D e cemb er 1988 Major Subject: Physics DEVELOPING IMPROVED NUCLEAR MAGNETIC RESONANCE MARGINAL OSCILLATOR SPECTROMETERS FOR ADVANCED TEACHING LABORATORIES A Thesis by FRANK PHILLIP...

Willingham, Frank Phillip

1988-01-01T23:59:59.000Z

330

The new very small angle neutron scattering spectrometer at Laboratoire Leon Brillouin  

E-Print Network [OSTI]

The design and characteristics of the new very small angle neutron scattering spectrometer under construction at the Laboratoire Leon Brillouin is described. Its goal is to extend the range of scattering vectors magnitudes towards 2x10{-4} /A. The unique feature of this new spectrometer is a high resolution two dimensional image plate detector sensitive to neutrons. The wavelength selection is achieved by a double reflection supermirror monochromator and the collimator uses a novel multibeam design.

Sylvain Desert; Vincent Thevenot; Julian Oberdisse; Annie Brulet

2007-06-12T23:59:59.000Z

331

Characterization and calibration of compact array spectrometers in the ultraviolet spectral region  

SciTech Connect (OSTI)

Array-based spectrometers, with their compact size, low weight, low cost, and fast measurement time, are now frequently used in place of both conventional single-channel scanning monochromators, and broadband meters. Their rapid measurement capability makes them an attractive option for routine solar UV spectral measurements, where shortterm variability in signal is a challenge. However, compactness, portability, low cost and high speed are achieved at the expense of the spectrometer's optical and electronic performance. Thus such spectrometers are more prone to measurement error from environmental changes, and more prone to other intrinsic sources of error such as stray light and detector non-linearity, which significantly affect solar UV measurements, than a scanning monochromator. The effects of stray light and non-linearity can be reduced either by improved optical and detector design or by a detailed spectrometer characterization. We present in this paper our investigation of the performance of three different commercial array spectrometers: two mini-spectrometers, and a more elaborate array spectrometer with an on-board image amplifier device. These were tested for a subset of performance parameters: their wavelength accuracy and stability, electronic linearity, responsivity linearity, stray light sensitivity, and mechanical stability and repeatability. With all three spectrometers we found that these parameters, particularly but not limited to stray light, had a significant impact on the measurement of the incoming optical radiation. This meant that, without characterization, the instruments would be unable to accurately measure the UV component of any source with significant visible radiation. We discuss various simple and low-cost solutions for improving the performance of these instruments, and providing a rigorous calibration using a straightforward set-up including optical filters and the quasi-monochromatic light from a double monochromator.

Shindo, Francois [Measurement Standards Laboratory of New Zealand, Industrial Research, Lower Hutt (New Zealand); Woolliams, Emma; Scott, Barry; Harris, Subrena [National Physical Laboratory, Teddington (United Kingdom)

2013-05-10T23:59:59.000Z

332

Electron Positron Proton Spectrometer for use at Laboratory for Laser Energetics  

SciTech Connect (OSTI)

The Electron Positron Proton Spectrometer (EPPS) is mounted in a TIM (Ten-Inch Manipulator) system on the Omega-60 or Omega-EP laser facilities at the University of Rochester, Laboratory for Laser Energetics (LLE), when in use, see Fig. 1. The Spectrometer assembly, shown in Fig. 2, is constructed of a steel box containing magnets, surrounded by Lead 6% Antimony shielding with SS threaded insert, sitting on an Aluminum 6061-T6 plate.

Ayers, S L

2010-04-07T23:59:59.000Z

333

Atomic data for the ITER Core Imaging X-ray Spectrometer  

SciTech Connect (OSTI)

The parameters of the ITER core plasmas will be measured using the Core Imaging X-ray Spectrometer (CIXS), a high-resolution crystal spectrometer focusing on the L-shell spectra of highly ionized tungsten atoms. In order to correctly infer the plasma properties accurate atomic data are required. Here, some aspects of the underlying physics are discussed using experimental data and theoretical predictions from modeling.

Clementson, J; Beiersdorfer, P; Biedermann, C; Bitter, M; Delgado-Aparicio, L F; Graf, A; Gu, M F; Hill, K W; Barnsley, R

2012-06-15T23:59:59.000Z

334

Environmental Levels Of 129I Present In Bovine Thyroid And Fresh Water In Argentina  

SciTech Connect (OSTI)

Concentrations of {sup 129}I in bovine thyroid and fresh water samples coming from all over Argentina were analyzed by Accelerator Mass Spectrometry (AMS) and total iodine present in samples by Gas Chromatography (GC) and Inductive Coupled Plasma Mass Spectrometry (ICP-MS), respectively. Once we complete this study, it will be the first set of data of this kind from an extended region of the south American subcontinent.

Negri, A. E.; Arazi, A.; Carnellia, P. F. F.; Barbara, E. de; Figueira, J. M.; Fimiani, L.; Heimanna, D. M.; Zalazara, L. [Laboratorio TANDAR, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Fernandez Niello, J. [Laboratorio TANDAR, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Universidad Nacional de San Martin, Campus Miguelete, B1650BWA, Buenos Aires (Argentina); La Gamma, A. M. [Gerencia Quimica, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Wallner, A. [VERA-Laboratory, Faculty of Physics, University of Vienna, Waehringer Str. 17, A-1090 Wien (Austria)

2010-08-04T23:59:59.000Z

335

Analysis on the Go: Quantitation of Drugs of Abuse in Dried Urine with Digital Microfluidics and Miniature Mass Spectrometry  

E-Print Network [OSTI]

Analysis on the Go: Quantitation of Drugs of Abuse in Dried Urine with Digital Microfluidics the development of a method coupling microfluidics and a miniature mass spectrometer, applied to quantitation of drugs of abuse in urine. A custom digital microfluidic system was designed to deliver droplets

Zandstra, Peter W.

336

Apparatus for preparing a sample for mass spectrometry  

DOE Patents [OSTI]

An apparatus is described for preparing a sample for analysis by a mass spectrometer system. The apparatus has an entry chamber and an ionization chamber separated by a skimmer. A capacitor having two space-apart electrodes followed by one or more ion-imaging lenses is disposed in the ionization chamber. The chamber is evacuated and the capacitor is charged. A valve injects a sample gas in the form of sample pulses into the entry chamber. The pulse is collimated by the skimmer and enters the ionization chamber. When the sample pulse passes through the gap between the electrodes, it discharges the capacitor and is thereby ionized. The ions are focused by the imaging lenses and enter the mass analyzer, where their mass and charge are analyzed. 1 figures.

Villa-Aleman, E.

1994-05-10T23:59:59.000Z

337

Mass spectrometric immunoassay  

DOE Patents [OSTI]

Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

Nelson, Randall W; Williams, Peter; Krone, Jennifer Reeve

2013-07-16T23:59:59.000Z

338

Mass spectrometric immunoassay  

DOE Patents [OSTI]

Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

Nelson, Randall W (Phoenix, AZ); Williams, Peter (Phoenix, AZ); Krone, Jennifer Reeve (Granbury, TX)

2007-12-04T23:59:59.000Z

339

Development of a variable-temperature ion mobility/ time-of-flight mass spectrometer for separation of electronic isomers  

E-Print Network [OSTI]

potentials to produce the periodic field.50 In 1964, Szilagyi of the Research Institute for Technical Physics of the Hungarian Academy of Sciences developed the mathematical treatment for a periodic electrostatic lens using a series of concentric...

Verbeck, Guido Fridolin

2005-08-29T23:59:59.000Z

340

ANALYSIS OF PASSIVATED SURFACES FOR MASS SPECTROMETER INLET SYSTEMS BY AUGER ELECTRON AND X-RAY PHOTOELECTRON SPECTROSCOPY  

SciTech Connect (OSTI)

Stainless steel coupons approximately 0.5' in diameter and 0.125' thick were passivated with five different surface treatments and an untreated coupon was left as a control. These surface treatments are being explored for use in tritium storage containers. These coupons were made to allow surface analysis of the surface treatments using well-know surface analysis techniques. Depth profiles using Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) were performed on these coupons to characterize the surface and near surface regions. Scanning electron microscope (SEM) images were collected as well. All of the surface treatments studied here appear to change the surface morphology dramatically, as evidenced by lack of tool marks on the treated samples. In terms of the passivation treatment, Vendors A-D appeared to have oxide layers that were very similar in thickness to each other (0.7-0.9 nm thick) as well as the untreated samples (the untreated sample oxide layers appeared to be somewhat larger). Vendor E's silicon coating appears to be on the order of 200 nm thick.

Ajo, H.; Clark, E.

2010-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Standard Test Method for Isotopic Analysis of Uranium Hexafluoride by Single-Standard Gas Source Multiple Collector Mass Spectrometer Method  

E-Print Network [OSTI]

1.1 This test method is applicable to the isotopic analysis of uranium hexafluoride (UF6) with 235U concentrations less than or equal to 5 % and 234U, 236U concentrations of 0.0002 to 0.1 %. 1.2 This test method may be applicable to the analysis of the entire range of 235U isotopic compositions providing that adequate Certified Reference Materials (CRMs or traceable standards) are available. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety health practices and determine the applicability of regulatory limitations prior to use.

American Society for Testing and Materials. Philadelphia

2011-01-01T23:59:59.000Z

342

PPPL3278, Preprint: January 1998, UC426 The TFTR E||B Spectrometer for Mass and Energy Resolved  

E-Print Network [OSTI]

and the supra thermal populations arising from neutral beam injection and ion cyclotron radio frequency heating for Tokamak Fusion Test Reactor was designed to measure the energy distributions of both the thermal ions devices, the extensive use of neutral beam injection and radio frequency auxiliary heating generates

343

PPPL-3278, Preprint: January 1998, UC-426 The TFTR E||B Spectrometer for Mass and Energy Resolved  

E-Print Network [OSTI]

and the supra thermal populations arising from neutral beam injection and ion cyclotron radio frequency heating for Tokamak Fusion Test Reactor was designed to measure the energy distributions of both the thermal ions, the extensive use of neutral beam injection and radio frequency auxiliary heating generates multispecies plasmas

344

Hydrophobic Proteome Analysis of Triple Negative and Hormone-Receptor-Positive-Her2-Negative Breast Cancer by Mass Spectrometer  

E-Print Network [OSTI]

solvents: 1. Water/acetonitrile/isopropanol/TFA by vol. )2. Water/acetonitrile/isopropanol/TFA by vol. )3. Water/acetonitrile/isopropanol/TFA by vol. ) 4. Water/

2010-01-01T23:59:59.000Z

345

A simplified spectrometer based on a fast digital oscilloscope for the measurement of high energy $?$-rays  

E-Print Network [OSTI]

A simplified digital spectrometer for the study of $\\gamma$-rays with energies up to $\\sim100$ MeV is presented and tested. The spectrometer is only consisted of a fast digital oscilloscope and three scintillation detectors which can work in single or in coincidence modes: two BGO-detectors comprising $\\varnothing\\,7.62\\times7.62$ cm BGO-crystalls and one plastic detector which includes an organic polystyrene-based scintillator. The basic properties of the spectrometer (energy resolution, time resolution, $\\gamma$-rays detection efficiency) were studied exhaustively also using a Geant4-based Monte-Carlo simulation. Several numerical algorithms for processing of waveforms in offline mode were proposed and tested to perform digital timing, pulse area measurement and processing of pile-up events without rejection. As a result, the spectrometer demonstrated $\\sim10\\%$ better energy resolution than was obtained by a common 10-bit CAMAC ADC with the same detectors. And the developed algorithm based on the pulse shape analysis for processing of pile-up events showed high efficiency under severe conditions (the portion of pile-ups contained $\\sim30\\%$). The measured maximum counting rate of the spectrometer was $1.8\\times10^5$ waveforms/sec.

S. S. Markochev; N. V. Eremin

2014-05-28T23:59:59.000Z

346

A solenoidal electron spectrometer for a precision measurement of the neutron $\\beta$-asymmetry with ultracold neutrons  

E-Print Network [OSTI]

We describe an electron spectrometer designed for a precision measurement of the neutron $\\beta$-asymmetry with spin-polarized ultracold neutrons. The spectrometer consists of a 1.0-Tesla solenoidal field with two identical multiwire proportional chamber and plastic scintillator electron detector packages situated within 0.6-Tesla field-expansion regions. Select results from performance studies of the spectrometer with calibration sources are reported.

Plaster, B; Filippone, B W; Harrison, D; Hsiao, J; Ito, T M; Liu, J; Martin, J W; Tipton, B; Yuan, J

2008-01-01T23:59:59.000Z

347

Plume collimation for laser ablation electrospray ionization mass spectrometry  

DOE Patents [OSTI]

In various embodiments, a device may generally comprise a capillary having a first end and a second end; a laser to emit energy at a sample in the capillary to ablate the sample and generate an ablation plume in the capillary; an electrospray apparatus to generate an electrospray plume to intercept the ablation plume to produce ions; and a mass spectrometer having an ion transfer inlet to capture the ions. The ablation plume may comprise a collimated ablation plume. The device may comprise a flow cytometer. Methods of making and using the same are also described.

Vertes, Akos; Stolee, Jessica A.

2014-09-09T23:59:59.000Z

348

A compact neutron spectrometer for characterizing inertial confinement fusion implosions at OMEGA and the NIF  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

A compact spectrometer for measurements of the primary deuterium-tritium neutron spectrum has been designed and implemented on the OMEGA laser facility [T. Boehly et al. , Opt. Commun.133, 495 (1997)]. This instrument uses the recoil spectrometry technique, where neutrons produced in an implosion elastically scatter protons in a plastic foil, which are subsequently detected by a proton spectrometer. This diagnostic is currently capable of measuring the yield to ?±10% accuracy, and mean neutron energy to ?±50 keV precision. As these compact spectrometers can be readily placed at several locations around an implosion, effects of residual fuel bulk flows during burn can be measured. Future improvements to reduce the neutron energy uncertainty to ±15?20 keV are discussed, which will enable measurements of fuel velocities to an accuracy of ?±25?40 km/s.

Zylstra, A. B.; Gatu Johnson, M.; Frenje, J. A.; Seguin, F. H.; Rinderknecht, H. G.; Rosenberg, M. J.; Sio, H. W.; Li, C. K.; Petrasso, R. D.; McCluskey, M.; Mastrosimone, D.; Glebov, V. Yu.; Forrest, C.; Stoeckl, C.; Sangster, T. C.

2014-06-01T23:59:59.000Z

349

Quantum states of neutrons in the gravitational and centrifugal potentials in a new GRANIT spectrometer  

ScienceCinema (OSTI)

We will discuss the scientific program to be studied in a new gravitational spectrometer GRANIT in a broad context of quantum states (quantum behaviour) of ultracold neutrons (UCN) in gravitational [1] and centrifugal [2] potentials, as well as applications of these phenomena/spectrometer to various domains of physics, ranging from studies of fundamental short-range interactions and symmetries to neutron quantum optics and reflectometry using UCN. All these topics, as well as related instrumental and methodical developments have been discussed during dedicated GRANIT-2010 Workshop [3]. The GRANIT spectrometer has been recently installed at the Institut Laue-Langevin, Grenoble, France [4] and could become operational in near future. 1. V.V. Nesvizhevsky et al (2002), Nature 415, 297. 2. V.V. Nesvizhevsky et al (2010), Nature Physics 6, 114. 3. GRANIT-2010, Les Houches, 14-19 february 2010. 4. M. Kreuz et al (2009), NIM 611, 326.

None

2011-10-06T23:59:59.000Z

350

Temperature and nonlinearity corrections for a photodiode array spectrometer used in the field  

SciTech Connect (OSTI)

Temperature and nonlinearity effects are two important factors that limit the use of photodiode array spectrometers. Usually the spectrometer is calibrated at a known temperature against a reference source of a particular spectral radiance, and then it is used at different temperatures to measure sources of different spectral radiances. These factors are expected to be problematic for nontemperature-stabilized instruments used for in-the-field experiments, where the radiant power of the site changes continuously with the sun tilt. This paper describes the effect of ambient temperature on a nontemperature-stabilized linear photodiode array spectrometer over the temperature range from 5 deg. C to 40 deg. C. The nonlinearity effects on both signal amplification and different levels of radiant power have also been studied and are presented in this paper.

Salim, Saber G. R.; Fox, Nigel P.; Theocharous, Evangelos; Sun, Tong; Grattan, Kenneth T. V.

2011-02-20T23:59:59.000Z

351

A firmware-defined digital direct-sampling NMR spectrometer for condensed matter physics  

SciTech Connect (OSTI)

We report on the design and implementation of a new digital, broad-band nuclear magnetic resonance (NMR) spectrometer suitable for probing condensed matter. The spectrometer uses direct sampling in both transmission and reception. It relies on a single, commercially-available signal processing device with a user-accessible field-programmable gate array (FPGA). Its functions are defined exclusively by the FPGA firmware and the application software. Besides allowing for fast replication, flexibility, and extensibility, our software-based solution preserves the option to reuse the components for other projects. The device operates up to 400?MHz without, and up to 800?MHz with undersampling, respectively. Digital down-conversion with ±10?MHz passband is provided on the receiver side. The system supports high repetition rates and has virtually no intrinsic dead time. We describe briefly how the spectrometer integrates into the experimental setup and present test data which demonstrates that its performance is competitive with that of conventional designs.

Pikulski, M., E-mail: marekp@ethz.ch; Shiroka, T.; Ott, H.-R.; Mesot, J. [Laboratorium für Festkörperphysik, ETH Hönggerberg, CH-8093 Zürich, Switzerland and Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland)

2014-09-15T23:59:59.000Z

352

Laser sampling system for an inductively-coupled atomic emission spectrometer. Final report  

SciTech Connect (OSTI)

A laser sampling system was attached to a Perkin Elmer Optima 3000 inductively-coupled plasma, atomic emission spectrometer that was already installed and operating in the Chemistry and Geochemistry Department at the Colorado School of Mines. The use of the spectrometer has been highly successful. Graduate students and faculty from at least four different departments across the CSM campus have used the instrument. The final report to NSF is appended to this final report. Appendices are included which summarize several projects utilizing this instrument: acquisition of an inductively-coupled plasma atomic emission spectrometer for the geochemistry program; hydrogen damage susceptibility assessment for high strength steel weldments through advanced hydrogen content analysis, 1996 and 1997 annual reports; and methods for determination of hydrogen distribution in high strength steel welds.

NONE

1998-02-15T23:59:59.000Z

353

A compact stilbene crystal neutron spectrometer for EAST D-D plasma neutron diagnostics  

SciTech Connect (OSTI)

A new compact stilbene crystal neutron spectrometer has been investigated and applied in the neutron emission spectroscopy on the EAST tokamak. A new components analysis method is presented to study the anisotropic light output in the stilbene crystal detector. A Geant4 code was developed to simulate the neutron responses in the spectrometer. Based on both the optimal light output function and the fitted pulse height resolution function, a reliable neutron response matrix was obtained by Geant4 simulations and validated by 2.5 MeV and 14 MeV neutron measurements at a 4.5 MV Van de Graaff accelerator. The spectrometer was used to diagnose the ion temperature in plasma discharges with lower hybrid wave injection and ion cyclotron resonance heating on the EAST tokamak.

Zhang Xing; Yuan Xi; Xie Xufei; Chen Zhongjing; Peng Xingyu; Chen Jinxiang; Zhang Guohui; Li Xiangqing; Fan Tieshuan [School of Physics and State Key Laboratory of Nuclear Physics and Technology, Peking University, Chengfu Road 201, 100871 Beijing (China); Zhong Guoqiang; Hu Liqun; Wan Baonian [Institute of Plasma Physics, Chinese Academy of Sciences, PO Box 1126, 230031 Hefei, Anhui (China)

2013-03-15T23:59:59.000Z

354

A compact neutron spectrometer for characterizing inertial confinement fusion implosions at OMEGA and the NIF  

SciTech Connect (OSTI)

A compact spectrometer for measurements of the primary deuterium-tritium neutron spectrum has been designed and implemented on the OMEGA laser facility [T. Boehly et al., Opt. Commun. 133, 495 (1997)]. This instrument uses the recoil spectrometry technique, where neutrons produced in an implosion elastically scatter protons in a plastic foil, which are subsequently detected by a proton spectrometer. This diagnostic is currently capable of measuring the yield to ?±10% accuracy, and mean neutron energy to ?±50 keV precision. As these compact spectrometers can be readily placed at several locations around an implosion, effects of residual fuel bulk flows during burn can be measured. Future improvements to reduce the neutron energy uncertainty to ±15?20 keV are discussed, which will enable measurements of fuel velocities to an accuracy of ?±25?40 km/s.

Zylstra, A. B., E-mail: zylstra@mit.edu; Gatu Johnson, M.; Frenje, J. A.; Séguin, F. H.; Rinderknecht, H. G.; Rosenberg, M. J.; Sio, H. W.; Li, C. K.; Petrasso, R. D. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); McCluskey, M.; Mastrosimone, D.; Glebov, V. Yu.; Forrest, C.; Stoeckl, C.; Sangster, T. C. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States)

2014-06-15T23:59:59.000Z

355

Foil cycling technique for the VESUVIO spectrometer operating in the resonance detector configuration  

SciTech Connect (OSTI)

This article reports a novel experimental technique, namely, the foil cycling technique, developed on the VESUVIO spectrometer (ISIS spallation source) operating in the resonance detector configuration. It is shown that with a proper use of two foils of the same neutron absorbing material it is possible, in a double energy analysis process, to narrow the width of the instrumental resolution of a spectrometer operating in the resonance detector configuration and to achieve an effective subtraction of the neutron and gamma backgrounds. Preliminary experimental results, obtained from deep inelastic neutron scattering measurements on lead, zirconium hydride, and deuterium chloride samples, are presented.

Schooneveld, E. M.; Mayers, J.; Rhodes, N. J.; Pietropaolo, A.; Andreani, C.; Senesi, R.; Gorini, G.; Perelli-Cippo, E.; Tardocchi, M. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Consiglio Nazionale delle Ricerche-Istituto Nazionale per la Fisica della Materia, Universita degli Studi di Roma Tor Vergata, Via della Ricerca Scientifica 1, 00133 Rome (Italy); Dipartimento di Fisica, Universita degli Studi di Roma 'Tor Vergata', Via della Ricerca Scientifica 1, 00133 Rome (Italy); Dipartimento di Fisica 'G. Occhialini', Universita degli Studi di Milano Bicocca, Piazza della Scienza 2, I-20126 Milan (Italy) and CNR-INFM, Universita degli Studi di Milano Bicocca, Piazza della Scienza 2, I-20126 Milan (Italy)

2006-09-15T23:59:59.000Z

356

Electron pair emission detected by time-of-flight spectrometers: Recent progress  

SciTech Connect (OSTI)

We present results for electron coincidence spectroscopy using two time-of-flight (ToF) spectrometers. Excited by electron impact, the energy and momentum distribution of electron pairs emitted from the Cu(111) surface are resolved and a spectral feature related to the Shockley surface state is identified. By combining the two ToF spectrometers with a high-order harmonic generation light source, we demonstrate double photoemission spectroscopy in the laboratory that required synchrotron radiation in the past. Utilizing this setup, we report results for (?,2e) on NiO(001) on Ag(001) excited with light at 30?eV photon energy.

Huth, Michael; Schumann, Frank O. [Max Planck Institute of Microstructure Physics, Weinberg 2, D-06120 Halle (Germany); Chiang, Cheng-Tien; Trützschler, Andreas; Kirschner, Jürgen [Max Planck Institute of Microstructure Physics, Weinberg 2, D-06120 Halle (Germany); Institute of Physics, Martin-Luther-Universität Halle-Wittenberg, Von-Danckelmann-Platz 3, D-06120 Halle (Saale) (Germany); Widdra, Wolf [Institute of Physics, Martin-Luther-Universität Halle-Wittenberg, Von-Danckelmann-Platz 3, D-06120 Halle (Saale) (Germany); Max Planck Institute of Microstructure Physics, Weinberg 2, D-06120 Halle (Germany)

2014-02-10T23:59:59.000Z

357

Next-Generation Germanium Spectrometer Background Reduction Techniques at 2 MeV  

SciTech Connect (OSTI)

The Majorana project, a next-generation 76Ge neutrinoless double-beta decay experiment being undertaken by a large international collaboration, has the goal of measuring the neutrinoless double-beta decay rate by observing monochromatic events at 2039 keV in 500 kg of isotopically enriched 76Ge gamma-ray spectrometers. In order to achieve the desired sensitivity limit, the background in the 2037-2041 keV region must be reduced to <1 event per year in the entire germanium array. The effects of various background reduction techniques, and the combination thereof, to produce a huge 76Ge spectrometer array with virtually zero background are discussed.

Brodzinski, Ronald L.

2005-04-01T23:59:59.000Z

358

Investigations of 2? decay measured by low background HPGe spectrometer OBELIX  

SciTech Connect (OSTI)

A low background high sensitive HPGe spectrometer OBELIX was installed at the Modane Underground Laboratory (LSM, France, 4800 m w.e.). The detector was designed to measure a contamination of enriched isotopes and radio-impurities in construction materials, to investigate rare nuclear processes such as resonance neutrinoless double electron capture and two-neutrino double beta decay to excited states of daughter nuclei. Spectrometer sensitivity, contamination of NEMO-3 sources and results of 2?2?{sup ?} decay of {sup 100}Mo to the 0{sup +} (1130 keV) and 2{sup +} (540 keV) excited states as well as future plans for OBELIX detector are given.

Rukhadze, Ekaterina [Institute of Experimental and Applied Physics, CTU in Prague, Horska 3a/22, 128 00 Prague 2 (Czech Republic); Collaboration: OBELIX Collaboration; SuperNEMO Collaboration

2013-12-30T23:59:59.000Z

359

Calibration of a Thomson parabola ion spectrometer and Fujifilm imaging plate detectors for protons, deuterons, and alpha particles  

SciTech Connect (OSTI)

A Thomson parabola ion spectrometer has been designed for use at the Multiterawatt (MTW) laser facility at the Laboratory for Laser Energetics (LLE) at University of Rochester. This device uses parallel electric and magnetic fields to deflect particles of a given mass-to-charge ratio onto parabolic curves on the detector plane. Once calibrated, the position of the ions on the detector plane can be used to determine the particle energy. The position dispersion of both the electric and magnetic fields of the Thomson parabola was measured using monoenergetic proton and alpha particle beams from the SUNY Geneseo 1.7 MV tandem Pelletron accelerator. The sensitivity of Fujifilm BAS-TR imaging plates, used as a detector in the Thomson parabola, was also measured as a function of the incident particle energy over the range from 0.6 MeV to 3.4 MeV for protons and deuterons and from 0.9 MeV to 5.4 MeV for alpha particles. The device was used to measure the energy spectrum of laser-produced protons at MTW.

Freeman, C. G.; Canfield, M. J.; Graeper, G. B.; Lombardo, A. T.; Stillman, C. R.; Padalino, S. J. [Physics Department, SUNY Geneseo, Geneseo, New York 14454 (United States); Fiksel, G.; Stoeckl, C.; Mileham, C.; Sangster, T. C. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States); Sinenian, N.; Frenje, J. A. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

2011-07-15T23:59:59.000Z

360

Elbow mass flow meter  

DOE Patents [OSTI]

Elbow mass flow meter. The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity.

McFarland, Andrew R. (College Station, TX); Rodgers, John C. (Santa Fe, NM); Ortiz, Carlos A. (Bryan, TX); Nelson, David C. (Santa Fe, NM)

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Introduction to direct neutrino mass measurements and KATRIN  

E-Print Network [OSTI]

The properties of neutrinos and especially their rest mass play an important role at the intersections of cosmology, particle physics and astroparticle physics. At present there are two complementary approaches to address this topic in laboratory experiments. The search for neutrinoless double beta decay probes whether neutrinos are Majorana particles and determines an effective neutrino mass value. On the other hand experiments such as MARE, KATRIN and the recently proposed Project 8 will investigate the spectral shape of beta-decay electrons close to their kinematic endpoint in order to determine the neutrino rest mass with a model-independent method. Here, because of neutrino flavour mixing, the neutrino mass appears as an average of all neutrino mass eigenstates contributing to the electron neutrino. The KArlsruhe TRItium Neutrino experiment (KATRIN) is currently the experiment in the most advanced status of commissioning. It combines an ultra-luminous molecular windowless gaseous tritium source with an integrating high-resolution spectrometer of MAC-E filter type. It will investigate the neutrino rest mass with 0.2 eV/c (90% C.L.) sensitivity and allow beta spectroscopy close to the tritium endpoint at 18.6 keV with unprecedented precision.

Thomas Thümmler; for the KATRIN Collaboration

2010-12-10T23:59:59.000Z

362

A method to measure the resonance transitions between the gravitationally bound quantum states of neutrons in the GRANIT spectrometer  

E-Print Network [OSTI]

of neutrons in the GRANIT spectrometer M. Kreuz a , V.V. Nesvizhevsky a,Ã?, P. Schmidt-Wellenburg a , T bound quantum states of neutrons in the GRANIT spectrometer. The purpose of GRANIT is to improve quantum states, the transition probability will sharply increase. The GRANIT experiment is motivated

Meyerovich, Alex

363

X-Band EPR Spectrometer with Customizable Arbitrary Waveform Generator based on a 1 GHz DAC Board  

E-Print Network [OSTI]

X-Band EPR Spectrometer with Customizable Arbitrary Waveform Generator based on a 1 GHz DAC Board-4120 , Email: songi@chem.ucsb.edu Abstract We present an EPR spectrometer featuring an arbitrary waveform of pulsed electron paramagnetic resonance (EPR) and enable new experiments. It generates shaped X

Martinis, John M.

364

Results for the response function determination of the Compact Neutron Spectrometer  

E-Print Network [OSTI]

The Compact Neutron Spectrometer (CNS) is a Joint European Torus (JET) Enhancement Project, designed for fusion diagnostics in different plasma scenarios. The CNS is based on a liquid scintillator (BC501A) which allows good discrimination between neutron and gamma radiation. Neutron spectrometry with a BC501A spectrometer requires the use of a reliable, fully characterized detector. The determination of the response matrix was carried out at the Ion Accelerator Facility (PIAF) of the Physikalisch-Technische Bundesanstalt (PTB). This facility provides several monoenergetic beams (2.5, 8, 10, 12 and 14 MeV) and a 'white field'(Emax ~17 MeV), which allows for a full characterization of the spectrometer in the region of interest (from ~1.5 MeV to ~17 MeV. The energy of the incoming neutrons was determined by the time of flight method (TOF), with time resolution in the order of 1 ns. To check the response matrix, the measured pulse height spectra were unfolded with the code MAXED and the resulting energy distributions were compared with those obtained from TOF. The CNS project required modification of the PTB BC501A spectrometer design, to replace an analog data acquisition system (NIM modules) with a digital system developed by the 'Ente per le Nuove tecnologie, l'Energia e l'Ambiente' (ENEA). Results for the new digital system were evaluated using new software developed specifically for this project.

F. Gagnon-Moisan; M. Reginatto; A. Zimbal

2012-01-30T23:59:59.000Z

365

Measurements with the high flux lead slowing-down spectrometer at LANL  

E-Print Network [OSTI]

slow down by scattering interactions with the lead and thus enable measurements of neutron.40.Sc Keywords: Lead-slowing-down spectrometer; Lithium; Alpha; Cross section; Neutron reactions 1.elsevier.com/locate/nimb Nuclear Instruments and Methods in Physics Research B 261 (2007) 953­955 NIM BBeam Interactions

Danon, Yaron

366

A light-weight optics-free EUV spectrometer with substantially improved efficiency and spectral resolution  

E-Print Network [OSTI]

ionization chamber for detecting UV radiation with sufficient photon energy for rare gas ionization was first "clones". All of these space based EUV spectrometers develop some time dependent degradation measurement uncertainties increase the total error in degradation estimates, and thus, decrease the accuracy

Didkovsky, Leonid

367

High-Sensitivity Raman Spectrometer To Study Pristine and Irradiated Interstellar Ice Analogs  

E-Print Network [OSTI]

to ionizing radiation which produces small quantities of new chemical species within the bulk of the icesHigh-Sensitivity Raman Spectrometer To Study Pristine and Irradiated Interstellar Ice Analogs Chris with low temperature ices relevant to the solar system and interstellar medium. The design is based

Kaiser, Ralf I.

368

TOWARDS BENCHMARK MEASUREMENTS FOR USED NUCLEAR FUEL ASSAY USING A LEAD SLOWING-DOWN SPECTROMETER  

E-Print Network [OSTI]

for spent fuel testing. The characterization of spent fuel is particularly important for nuclear safeguardsTOWARDS BENCHMARK MEASUREMENTS FOR USED NUCLEAR FUEL ASSAY USING A LEAD SLOWING-DOWN SPECTROMETER B) is considered as a possible option for non- destructive assay of fissile material in used nuclear fuel

Danon, Yaron

369

Near-infrared thermal lens spectrometer based on an erbium-doped fiber amplifier and  

E-Print Network [OSTI]

Near-infrared thermal lens spectrometer based on an erbium-doped fiber amplifier and an acousto, guanosine, and thymidine is described. © 1997 Optical Society of America Key words: Near infrared, thermal measurements of absorption in the near-IR region has been developed. In this instrument the near-IR excitation

Reid, Scott A.

370

Port Compensation Using the Herschel/SPIRE Imaging Fourier Transform Spectrometer  

E-Print Network [OSTI]

Port Compensation Using the Herschel/SPIRE Imaging Fourier Transform Spectrometer Locke D. Spencer the position of zero optical path difference (ZPD). The process of port compensation involves a broadband spectral source placed at the second, complementary input port of an FTS, reducing the dynamic range

Naylor, David A.

371

Analysis of perchlorate in groundwater by electrospray ionization mass spectrometry/mass spectrometry  

SciTech Connect (OSTI)

An electrospray ionization mass spectrometry/mass spectrometry (ESI/MS/MS) method was developed to measure part-per-billion ({micro}g/L) concentrations of perchlorate in groundwater. Selective and sensitive perchlorate detection was achieved by operating the mass spectrometer in the negative ionization mode and by using MS/MS to monitor the CIO{sub 4}{sup {minus}} to ClO{sub 3}{sup {minus}} transition. The method of standard additions was used to address the considerable signal suppression caused by anions that are typically present in groundwater, such as bicarbonate and sulfate. ESI-MS/MS analysis was rapid, accurate, reproducible, and provided a detection limit of 0.5 {micro}g/L perchlorate in groundwater. Accuracy and precision of the ESI/MS/MS method were assessed by analyzing performance evaluation samples in a groundwater matrix and by comparing ion chromatography (IC) and ESI/MS/MS results for local groundwater samples. Results for the performance evaluation samples differed from the certified values by 4--13%, and precision ranged from 3 to 10% (relative standard deviation). The IC and ESI/MS/MS results were statistically indistinguishable for perchlorate concentrations above the detection limits of both methods.

Koester, C.J.; Beller, H.R.; Halden, R.U.

2000-05-01T23:59:59.000Z

372

FULL-SCALE TESTING OF A CAUSTIC SIDE SOLVENT EXTRACTION SYSTEM TO REMOVE CESIUM FROM SAVANNAH RIVER SITE RADIOACTIVE WASTE  

SciTech Connect (OSTI)

Savannah River Site (SRS) personnel have completed construction and assembly of the Modular Caustic Side Solvent Extraction Unit (MCU) facility. Following assembly, they conducted testing to evaluate the ability of the process to remove non-radioactive cesium and to separate the aqueous and organic phases. They conducted tests at salt solution flow rates of 3.5, 6.0, and 8.5 gpm. During testing, the MCU Facility collected samples and submitted them to Savannah River National Laboratory (SRNL) personnel for analysis of cesium, Isopar{reg_sign} L, and Modifier [1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol]. SRNL personnel analyzed the aqueous samples for cesium by Inductively-Coupled Plasma Mass Spectroscopy (ICP-MS) and the solvent samples for cesium using a Parr Bomb Digestion followed by ICP-MS. They analyzed aqueous samples for Isopar{reg_sign} L and Modifier by gas chromatography (GC).

Poirier, M; Thomas Peters, T; Earl Brass, E; Stanley Brown, S; Mark Geeting, M; Lcurtis Johnson, L; Charles02 Coleman, C; S Crump, S; Mark Barnes, M; Samuel Fink, S

2007-10-15T23:59:59.000Z

373

Lead Slowing Down Spectrometer FY2013 Annual Report  

SciTech Connect (OSTI)

Executive Summary The Lead Slowing Down Spectrometry (LSDS) project, funded by the Materials Protection And Control Technology campaign, has been evaluating the feasibility of using LSDS techniques to assay fissile isotopes in used nuclear fuel assemblies. The approach has the potential to provide considerable improvement in the assay of fissile isotopic masses in fuel assemblies compared to other non-destructive techniques in a direct and independent manner. This report is a high level summary of the progress completed in FY2013. This progress included: • Fabrication of a 4He scintillator detector to detect fast neutrons in the LSDS operating environment. Testing of the detector will be conducted in FY2014. • Design of a large area 232Th fission chamber. • Analysis using the Los Alamos National Laboratory perturbation model estimated the required number of neutrons for an LSDS measurement to be 10 to the 16th source neutrons. • Application of the algorithms developed at Pacific Northwest National Laboratory to LSDS measurement data of various fissile samples conducted in 2012. The results concluded that the 235U could be measured to 2.7% and the 239Pu could be measured to 6.3%. Significant effort is yet needed to demonstrate the applicability of these algorithms for used-fuel assemblies, but the results reported here are encouraging in demonstrating that we are making progress toward that goal. • Development and cost-analysis of a research plan for the next critical demonstration measurements. The plan suggests measurements on fresh fuel sub assemblies as a means to experimentally test self-attenuation and the use of fresh mixed-oxide fuel as a means to test simultaneous measurement of 235U and 239Pu.

Warren, Glen A.; Kulisek, Jonathan A.; Gavron, Victor A.; Danon, Yaron; Weltz, Adam; Harris, Jason; Stewart, T.

2013-10-29T23:59:59.000Z

374

First Results from the CARIBU Facility: Mass Measurements on the r-Process Path  

E-Print Network [OSTI]

The Canadian Penning Trap mass spectrometer has made mass measurements of 33 neutron-rich nuclides provided by the new Californium Rare Isotope Breeder Upgrade (CARIBU) facility at Argonne National Laboratory. The studied region includes the 132Sn double shell closure and ranges in Z from In to Cs, with Sn isotopes measured out to A = 135, and the typical measurement precision is at the 100 ppb level or better. The region encompasses a possible major waiting point of the astrophysical r process, and the impact of the masses on the r process is shown through a series of simulations. These first-ever simulations with direct mass information on this waiting point show significant increases in waiting time at Sn and Sb in comparison with commonly used mass models, demonstrating the inadequacy of existing models for accurate r-process calculations.

J. Van Schelt; D. Lascar; G. Savard; J. A. Clark; P. F. Bertone; S. Caldwell; A. Chaudhuri; 1 A. F. Levand; G. Li; G. E. Morgan; R. Orford; R. E. Segel; K. S. Sharma; M. G. Sternberg

2013-07-01T23:59:59.000Z

375

Study of thermal neutron capture gamma rays using a lithium-drifted germanium spectrometer / [by] Victor John Orphan [and] Norman C. Rasmussen  

E-Print Network [OSTI]

A gamma-ray spectrometer, using a 30 cc coaxial Ge(Li) detector, which can be operated as a pair spectrometer at high energies and in the Compton suppression mode at low energies provides an effective means of obtaining ...

Orphan, V. J.

1967-01-01T23:59:59.000Z

376

New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico brine pool via in situ mass spectrometry  

E-Print Network [OSTI]

New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico Keywords: Methane flux Mass spectrometer Brine pool Methane oxidation Gulf of Mexico a b s t r a c t Deep heterogeneity. In particular, biogeochemical fluxes of volatiles such as methane remain largely unconstrained

Girguis, Peter R.

377

Aerosol Mass Spectrometry via Laser-Induced Incandescence Particle Vaporization Final Report  

SciTech Connect (OSTI)

We have successfully developed and commercialized a soot particle aerosol mass spectrometer (SP-AMS) instrument to measure mass, size, and chemical information of soot particles in ambient environments. The SP-AMS instrument has been calibrated and extensively tested in the laboratory and during initial field studies. The first instrument paper describing the SP-AMS has been submitted for publication in a peer reviewed journal and there are several related papers covering initial field studies and laboratory studies that are in preparation. We have currently sold 5 SP-AMS instruments (either as complete systems or as SP modules to existing AMS instrument operators).

Timothy B. Onasch

2011-10-20T23:59:59.000Z

378

Top quark mass measurements  

SciTech Connect (OSTI)

The top quark, with its extraordinarily large mass (nearly that of a gold atom), plays a significant role in the phenomenology of EWSB in the Standard Model. In particular, the top quark mass when combined with the W mass constrains the mass of the as yet unobserved Higgs boson. Thus, a precise determination of the mass of the top quark is a principal goal of the CDF and D0 experiments. With the data collected thus far in Runs 1 and 2 of the Tevatron, CDF and D0 have measured the top quark mass in both the lepton+jets and dilepton decay channels using a variety of complementary experimental techniques. The author presents an overview of the most recent of the measurements.

Hill, Christopher S.; /UC, Santa Barbara

2004-12-01T23:59:59.000Z

379

Multinozzle Emitter Arrays for Nanoelectrospray Mass Spectrometry  

SciTech Connect (OSTI)

Mass spectrometry (MS) is the enabling technology for proteomics and metabolomics. However, dramatic improvements in both sensitivity and throughput are still required to achieve routine MS-based single cell proteomics and metabolomics. Here, we report the silicon-based monolithic multinozzle emitter array (MEA), and demonstrate its proof-of-principle applications in high-sensitivity and high-throughput nanoelectrospray mass spectrometry. Our MEA consists of 96 identical 10-nozzle emitters in a circular array on a 3-inch silicon chip. The geometry and configuration of the emitters, the dimension and number of the nozzles, and the micropillar arrays embedded in the main channel, can be systematically and precisely controlled during the microfabrication process. Combining electrostatic simulation and experimental testing, we demonstrated that sharpened-end geometry at the stem of the individual multinozzle emitter significantly enhanced the electric fields at its protruding nozzle tips, enabling sequential nanoelectrospray for the high-density emitter array. We showed that electrospray current of the multinozzle emitter at a given total flow rate was approximately proportional to the square root of the number of its spraying-nozzles, suggesting the capability of high MS sensitivity for multinozzle emitters. Using a conventional Z-spray mass spectrometer, we demonstrated reproducible MS detection of peptides and proteins for serial MEA emitters, achieving sensitivity and stability comparable to the commercial capillary emitters. Our robust silicon-based MEA chip opens up the possibility of a fully-integrated microfluidic system for ultrahigh-sensitivity and ultrahigh-throughput proteomics and metabolomics.

Mao, Pan; Wang, Hung-Ta; Yang, Peidong; Wang, Daojing

2011-06-16T23:59:59.000Z

380

Nuclear Masses in Astrophysics  

E-Print Network [OSTI]

Among all nuclear ground-state properties, atomic masses are highly specific for each particular combination of N and Z and the data obtained apply to a variety of physics topics. One of the most crucial questions to be addressed in mass spectrometry of unstable radionuclides is the one of understanding the processes of element formation in the Universe. To this end, accurate atomic mass values of a large number of exotic nuclei participating in nucleosynthesis are among the key input data in large-scale reaction network calculations. In this paper, a review on the latest achievements in mass spectrometry for nuclear astrophysics is given.

Christine Weber; Klaus Blaum; Hendrik Schatz

2008-12-09T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

HYSPEC : A CRYSTAL TIME OF FLIGHT HYBRID SPECTROMETER FOR THE SPALLATION NEUTRON SOURCE.  

SciTech Connect (OSTI)

This document lays out a proposal by the Instrument Development Team (IDT) composed of scientists from leading Universities and National Laboratories to design and build a conceptually new high-flux inelastic neutron spectrometer at the pulsed Spallation Neutron Source (SNS) at Oak Ridge. This instrument is intended to supply users of the SNS and scientific community, of which the IDT is an integral part, with a platform for ground-breaking investigations of the low-energy atomic-scale dynamical properties of crystalline solids. It is also planned that the proposed instrument will be equipped with a polarization analysis capability, therefore becoming the first polarized beam inelastic spectrometer in the SNS instrument suite, and the first successful polarized beam inelastic instrument at a pulsed spallation source worldwide. The proposed instrument is designed primarily for inelastic and elastic neutron spectroscopy of single crystals. In fact, the most informative neutron scattering studies of the dynamical properties of solids nearly always require single crystal samples, and they are almost invariably flux-limited. In addition, in measurements with polarization analysis the available flux is reduced through selection of the particular neutron polarization, which puts even more stringent limits on the feasibility of a particular experiment. To date, these investigations have mostly been carried out on crystal spectrometers at high-flux reactors, which usually employ focusing Bragg optics to concentrate the neutron beam on a typically small sample. Construction at Oak Ridge of the high-luminosity spallation neutron source, which will provide intense pulsed neutron beams with time-averaged fluxes equal to those at medium-flux reactors, opens entirely new opportunities for single crystal neutron spectroscopy. Drawing upon experience acquired during decades of studies with both crystal and time-of-flight (TOF) spectrometers, the IDT has developed a conceptual design for a focused-beam, hybrid time-of-flight instrument with a crystal monochromator for the SNS called HYSPEC (an acronym for hybrid spectrometer). The proposed instrument has a potential to collect data more than an order of magnitude faster than existing steady-source spectrometers over a wide range of energy transfer ({h_bar}{omega}) and momentum transfer (Q) space, and will transform the way that data in elastic and inelastic single-crystal spectroscopy are collected. HYSPEC is optimized to provide the highest neutron flux on sample in the thermal and epithermal neutron energy ranges at a good-to-moderate energy resolution. By providing a flux on sample several times higher than other inelastic instruments currently planned for the SNS, the proposed instrument will indeed allow unique ground-breaking measurements, and will ultimately make polarized beam studies at a pulsed spallation source a realistic possibility.

SHAPIRO,S.M.; ZALIZNYAK,I.A.

2002-12-30T23:59:59.000Z

382

Neutron Time-Of-Flight Spectrometer Based on HIRFL for Studies of Spallation Reactions Related to ADS Project  

E-Print Network [OSTI]

A Neutron Time-Of-Flight (NTOF) spectrometer based on Heavy Ion Research Facility in Lanzhou (HIRFL) is developed for studies of neutron production of proton induced spallation reactions related to the ADS project. After the presentation of comparisons between calculated spallation neutron production double-differential cross sections and the available experimental one, a detailed description of NTOF spectrometer is given. Test beam results show that the spectrometer works well and data analysis procedures are established. The comparisons of the test beam neutron spectra with those of GEANT4 simulations are presented.

Suyalatu Zhang; Zhiqiang Chen; Rui Han; Roy Wada; Xingquan Liu; Weiping Lin; Jianli Liu; Fudong Shi; Peipei Ren; Guoyu Tian; Fei Luo

2014-11-20T23:59:59.000Z

383

mass communication advertising &  

E-Print Network [OSTI]

mass communication advertising & public relations introduction. Graduate programs in the Department of Mass Communication, Advertising, and Public Relations provide an entry to a wide spectrum of careers in the communication industry. Classes, internships, site visits, and presentations by top professionals offer students

Finzi, Adrien

384

Elbow mass flow meter  

DOE Patents [OSTI]

The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity. 3 figs.

McFarland, A.R.; Rodgers, J.C.; Ortiz, C.A.; Nelson, D.C.

1994-08-16T23:59:59.000Z

385

The Origins of Mass  

SciTech Connect (OSTI)

The Higgs boson was discovered in July of 2012 and is generally understood to be the origin of mass. While those statements are true, they are incomplete. It turns out that the Higgs boson is responsible for only about 2% of the mass of ordinary matter. In this dramatic new video, Dr. Don Lincoln of Fermilab tells us the rest of the story.

Lincoln, Don

2014-07-30T23:59:59.000Z

386

Gas Chromatography -Mass Spectrometry  

E-Print Network [OSTI]

GCMS - 1 Gas Chromatography - Mass Spectrometry GC-MS ANALYSIS OF ETHANOL AND BENZENE IN GASOLINE Last updated: June 17, 2014 #12;GCMS - 2 Gas Chromatography - Mass Spectrometry GC-MS ANALYSIS). The goal of this experiment is to separate the components in a sample of gasoline using Gas Chromatography

Nizkorodov, Sergey

387

The Origins of Mass  

ScienceCinema (OSTI)

The Higgs boson was discovered in July of 2012 and is generally understood to be the origin of mass. While those statements are true, they are incomplete. It turns out that the Higgs boson is responsible for only about 2% of the mass of ordinary matter. In this dramatic new video, Dr. Don Lincoln of Fermilab tells us the rest of the story.

Lincoln, Don

2014-08-07T23:59:59.000Z

388

The new cold neutron chopper spectrometer at the Spallation Neutron Source: Design and performance  

SciTech Connect (OSTI)

The design and performance of the new cold neutron chopper spectrometer (CNCS) at the Spallation Neutron Source in Oak Ridge are described. CNCS is a direct-geometry inelastic time-of-flight spectrometer, designed essentially to cover the same energy and momentum transfer ranges as IN5 at ILL, LET at ISIS, DCS at NIST, TOFTOF at FRM-II, AMATERAS at J-PARC, PHAROS at LANSCE, and NEAT at HZB, at similar energy resolution. Measured values of key figures such as neutron flux at sample position and energy resolution are compared between measurements and ray tracing Monte Carlo simulations, and good agreement (better than 20% of absolute numbers) has been achieved. The instrument performs very well in the cold and thermal neutron energy ranges, and promises to become a workhorse for the neutron scattering community for quasielastic and inelastic scattering experiments.

Ehlers, G.; Podlesnyak, A. A.; Niedziela, J. L.; Iverson, E. B. [Neutron Scattering Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Sokol, P. E. [Department of Physics, Indiana University, Bloomington, Indiana 47405 (United States)

2011-08-15T23:59:59.000Z

389

The new Cold Neutron Chopper Spectrometer at the Spallation Neutron Source -- Design and Performance  

SciTech Connect (OSTI)

The design and performance of the new cold neutron chopper spectrometer (CNCS) at the Spallation Neutron Source in Oak Ridge are described. CNCS is a direct-geometry inelastic time-of-flight spectrometer, designed essentially to cover the same energy and momentum transfer ranges as IN5 at ILL, LET at ISIS, DCS at NIST, TOFTOF at FRM-II, AMATERAS at J-PARC, PHAROS at LANSCE, and NEAT at HZB, at similar energy resolution. Measured values of key figures such as neutron flux at sample position and energy resolution are compared between measurements and ray tracing Monte Carlo simulations, and good agreement (better than 20% of absolute numbers) has been achieved. The instrument performs very well in the cold and thermal neutron energy ranges, and promises to become a workhorse for the neutron scattering community for quasielastic and inelastic scattering experiments.

Ehlers, Georg [ORNL; Podlesnyak, Andrey A [ORNL; Niedziela, Jennifer L [ORNL; Iverson, Erik B [ORNL; Sokol, Paul E [ORNL

2011-01-01T23:59:59.000Z

390

Optimising a Muon Spectrometer for Measurements at the ISIS Pulsed Muon Source  

E-Print Network [OSTI]

This work describes the development of a state-of-the-art muon spectrometer for the ISIS pulsed muon source. Conceived as a major upgrade of the highly successful EMU instrument, emphasis has been placed on making effective use of the enhanced flux now available at the ISIS source. This has been achieved both through the development of a highly segmented detector array and enhanced data acquisition electronics. The pulsed nature of the ISIS beam is particularly suited to the development of novel experiments involving external stimuli, and therefore the ability to sequence external equipment has been added to the acquisition system. Finally, the opportunity has also been taken to improve both the magnetic field and temperature range provided by the spectrometer, to better equip the instrument for running the future ISIS user programme.

Giblin, S R; King, P J C; Tomlinson, S; Jago, S J S; Randall, L J; Roberts, M J; Norris, J; Howarth, S; Mutamba, Q B; Rhodes, N J; Akeroyd, F

2014-01-01T23:59:59.000Z

391

Spectrometer for Sky-Scanning Sun-Tracking Atmospheric Research (4STAR): Instrument Technology  

SciTech Connect (OSTI)

The Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) combines airborne sun tracking and sky scanning with diffraction spectroscopy, to improve knowledge of atmospheric constituents and their links to air-pollution/climate. Direct beam hyper-spectral measurement of optical depth improves retrievals of gas constituents and determination of aerosol properties. Sky scanning enhances retrievals of aerosol type and size distribution. 4STAR measurements will tighten the closure between satellite and ground-based measurements. 4STAR incorporates a modular sun-tracking/ sky-scanning optical head with fiber optic signal transmission to rack mounted spectrometers, permitting miniaturization of the external optical head, and future detector evolution. Technical challenges include compact optical collector design, radiometric dynamic range and stability, and broad spectral coverage. Test results establishing the performance of the instrument against the full range of operational requirements are presented, along with calibration, engineering flight test, and scientific field campaign data and results.

Dunagan, Stephen; Johnson, Roy; Zavaleta, Jhony; Russell, P. B.; Schmid, Beat; Flynn, Connor J.; Redemann, Jens; Shinozuka, Yohei; Livingston, J.; Segal Rozenhaimer, Michal

2013-08-06T23:59:59.000Z

392

Development of a Time-resolved Soft X-ray Spectrometer for Laser Produced Plasma Experiments  

SciTech Connect (OSTI)

A 2400 line/mm variable spaced grating spectrometer (VSG) has been used to measure soft x-ray emission (8-22 {angstrom}) from laser-produced plasma experiments at Lawrence Livermore National Laboratory's Compact Multipulse Terrawatt (COMET) Laser Facility. The spectrometer was coupled to a Kentech x-ray streak camera to study the temporal evolution of soft x-rays emitted from the back of mylar and copper foils irradiated at 10{sup 15} W/cm{sup 2}. The instrument demonstrated a resolving power of {approx} 120 at 19 {angstrom} with a time resolution of 31 ps. The time-resolved copper emission spectrum was consistent with a photodiode monitoring the laser temporal pulse shape and indicated that the soft x-ray emission follows the laser heating of the target. The time and spectral resolution of this diagnostic make it useful for studies of high temperature plasmas.

Cone, K V; Dunn, J; Schneider, M B; Baldis, H A; Brown, G V; Emig, J; James, D L; May, M J; Park, J; Shepherd, R; Widmann, K

2010-05-12T23:59:59.000Z

393

Development of a time-resolved soft x-ray spectrometer for laser produced plasma experiments  

SciTech Connect (OSTI)

A 2400 lines/mm variable-spaced grating spectrometer has been used to measure soft x-ray emission (8-22 A) from laser-produced plasma experiments at Lawrence Livermore National Laboratory's Compact Multipulse Terrawatt (COMET) Laser Facility. The spectrometer was coupled to a Kentech x-ray streak camera to study the temporal evolution of soft x rays emitted from the back of the Mylar and the copper foils irradiated at 10{sup 15} W/cm{sup 2}. The instrument demonstrated a resolving power of {approx}120 at 19 A with a time resolution of 31 ps. The time-resolved copper emission spectrum was consistent with a photodiode monitoring the laser temporal pulse shape and indicated that the soft x-ray emission follows the laser heating of the target. The time and spectral resolutions of this diagnostic make it useful for studies of high temperature plasmas.

Cone, K. V.; Park, J. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); University of California at Davis, Davis, California 95616 (United States); Dunn, J.; Schneider, M. B.; Brown, G. V.; Emig, J.; James, D. L.; May, M. J.; Shepherd, R.; Widmann, K. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Baldis, H. A. [University of California at Davis, Davis, California 95616 (United States)

2010-10-15T23:59:59.000Z

394

Development of a ten inch manipulators-based, flexible, broadband two-crystal spectrometer  

SciTech Connect (OSTI)

We have developed and implemented a broadband X-ray spectrometer with a variable energy range for use at the Atomic Weapons Establishment's Orion Laser. The spectrometer covers an energy bandwidth of ?1–2 keV using two independently mounted, movable Bragg diffraction crystals. Using combinations of cesium hydrogen pthlate, ammonium dihydrogen phosphate, and pentaerythritol crystals, spectra covering the 1.4–2.5, 1.85–3.15, or 3.55–5.1 keV energy bands have been measured. Image plate is used for detection owing to its high dynamic range. Background signals caused by high energy X-rays and particles commonly produced in high energy laser experiments are reduced by a series of tantalum baffles and filters installed between the source and crystal and also between the crystals and detector.

Steel, A. B., E-mail: steel1@llnl.gov; Dunn, J.; Emig, J.; Beiersdorfer, P.; Brown, G. V.; Shepherd, R.; Marley, E. V. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Hoarty, D. J. [Atomic Weapons Establishment, Aldermaston (United Kingdom)

2014-11-15T23:59:59.000Z

395

Monte Carlo study of the performance of a time-of-flight multichopper spectrometer  

SciTech Connect (OSTI)

The Monte Carlo method is a powerful technique for neutron transport studies. While it has been applied for many years to the study of nuclear systems, there are few codes available for neutron transport in the optical regime. The recent surge of interest in so-called next generation spallation neutron sources and the desire to design new and optimized instruments for these facilities has led us to develop a Monte Carlo code geared toward the simulation of neutron scattering instruments. The time-of-flight multichopper spectrometer, of which IN5 at the ILL is the prototypical example, is the first spectrometer studied with the code. Some of the results of a comparison between the IN5 performance at a reactor and at a Long Pulse Spallation Source (LPSS) are summarized here.

Daemen, L.L.; Eckert, J.; Pynn, R. [and others

1995-12-01T23:59:59.000Z

396

The gamma-ray spectrometer HORUS and its applications for nuclear astrophysics  

E-Print Network [OSTI]

A dedicated setup for the in-beam measurement of absolute cross sections of astrophysically relevant charged-particle induced reactions is presented. These, usually very low, cross sections at energies of astrophysical interest are important to improve the modeling of the nucleosynthesis processes of heavy nuclei. Particular emphasis is put on the production of the $p$ nuclei during the astrophysical $\\gamma$ process. The recently developed setup utilizes the high-efficiency $\\gamma$-ray spectrometer HORUS, which is located at the 10 MV FN tandem ion accelerator of the Institute for Nuclear Physics in Cologne. The design of this setup will be presented and results of the recently measured $^{89}$Y(p,$\\gamma$)$^{90}$Zr reaction will be discussed. The excellent agreement with existing data shows, that the HORUS spectrometer is a powerful tool to determine total and partial cross sections using the in-beam method with high-purity germanium detectors.

L. Netterdon; V. Derya; J. Endres; C. Fransen; A. Hennig; J. Mayer; C. Müller-Gatermann; A. Sauerwein; P. Scholz; M. Spieker; A. Zilges

2014-05-12T23:59:59.000Z

397

A Compact, Backscattering Deplolarization Cloud Spectrometer for Ice and Water Discrimination  

SciTech Connect (OSTI)

This project was to develop a compact optical particle spectrometer, small enough for operation on UAVS, that measures the optical diameter of cloud hydrometeors and differentiates their water phase (liquid or solid). To reach this goal, a work plan was laid out that would complete three objectives: 1) Evaluation of designs for an optical particle spectrometer that measures the component of light backscattered at two polarization angles. 2) Testing of selected designs on an optical bench. 3) Construction and preliminary testing of a prototype instrument based on the selected, optimum design. A protoype instrument was developed and tested in an icing wind tunnel where the results showed good measurement of cloud droplets and ice particles.

Thomson, David

2014-05-15T23:59:59.000Z

398

THE COSMIC INFRARED BACKGROUND EXPERIMENT (CIBER): THE NARROW-BAND SPECTROMETER  

SciTech Connect (OSTI)

We have developed a near-infrared spectrometer designed to measure the absolute intensity of the solar 854.2 nm Ca II Fraunhofer line, scattered by interplanetary dust, in the zodiacal light (ZL) spectrum. Based on the known equivalent line width in the solar spectrum, this measurement can derive the zodiacal brightness, testing models of the ZL based on morphology that are used to determine the extragalactic background light in absolute photometry measurements. The spectrometer is based on a simple high-resolution tipped filter placed in front of a compact camera with wide-field refractive optics to provide the large optical throughput and high sensitivity required for rocket-borne observations. We discuss the instrument requirements for an accurate measurement of the absolute ZL brightness, the measured laboratory characterization, and the instrument performance in flight.

Korngut, P. M.; Bock, J. [Jet Propulsion Laboratory (JPL), National Aeronautics and Space Administration (NASA), Pasadena, CA 91109 (United States); Renbarger, T.; Keating, B. [Department of Physics, University of California, San Diego, San Diego, CA 92093 (United States); Arai, T.; Matsumoto, T.; Matsuura, S. [Department of Space Astronomy and Astrophysics, Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA), Sagamihara, Kanagawa 252-5210 (Japan); Battle, J.; Hristov, V.; Lanz, A.; Levenson, L. R.; Mason, P. [Department of Physics, California Institute of Technology, Pasadena, CA 91125 (United States); Brown, S. W.; Lykke, K. R.; Smith, A. W. [Sensor Science Division, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States); Cooray, A. [Center for Cosmology, University of California, Irvine, Irvine, CA 92697 (United States); Kim, M. G. [Department of Physics and Astronomy, Seoul National University, Seoul 151-742 (Korea, Republic of); Lee, D. H.; Nam, U. W. [Korea Astronomy and Space Science Institute (KASI), Daejeon 305-348 (Korea, Republic of); Shultz, B., E-mail: pkorngut@caltech.edu [Materion Barr Precision Optics and Thin Film Coatings, Westford, MA 01886 (United States); and others

2013-08-15T23:59:59.000Z

399

Spectrometer for X-ray emission experiments at FERMI free-electron-laser  

SciTech Connect (OSTI)

A portable and compact photon spectrometer to be used for photon in-photon out experiments, in particular x-ray emission spectroscopy, is presented. The instrument operates in the 25–800 eV energy range to cover the full emissions of the FEL1 and FEL2 stages of FERMI. The optical design consists of two interchangeable spherical varied-lined-spaced gratings and a CCD detector. Different input sections can be accommodated, with/without an entrance slit and with/without an additional relay mirror, that allow to mount the spectrometer in different end-stations and at variable distances from the target area both at synchrotron and at free-electron-laser beamlines. The characterization on the Gas Phase beamline at ELETTRA Synchrotron (Italy) is presented.

Poletto, L., E-mail: poletto@dei.unipd.it; Frassetto, F.; Miotti, P. [CNR - Institute of Photonics and Nanotechnologies (CNR-IFN), via Trasea 7, I-35131 Padova (Italy); Di Cicco, A.; Iesari, F. [Physics Division, School of Science and Technology, Università di Camerino, I-62032 Camerino (Italy); Finetti, P. [ELETTRA - Sincrotrone Trieste, Basovizza Area Science Park, S. S. 14 - km 163,5, I-34149, Basovizza (TS) (Italy); Grazioli, C. [Department of Chemical and Pharmaceutical Sciences, University of Trieste, Via L. Giorgieri 1, I-34127 Trieste (Italy); CNR-Istituto Officina dei Materiali (CNR-IOM), Laboratorio TASC, I-34149 Trieste (Italy); Kivimäki, A. [CNR-Istituto Officina dei Materiali (CNR-IOM), Laboratorio TASC, I-34149 Trieste (Italy); Stagira, S. [Politecnico di Milano – Department of Physics, I-20133 Milano (Italy); Coreno, M. [ELETTRA - Sincrotrone Trieste, Basovizza Area Science Park, S. S. 14 - km 163,5, I-34149, Basovizza (TS) (Italy); CNR – Istituto di Struttura della Materia (CNR-ISM), UOS Basovizza, I-34149 Trieste (Italy)

2014-10-15T23:59:59.000Z

400

A magnetic spectrometer measurement of the charge ratio of energetic cosmic ray muons  

E-Print Network [OSTI]

" of 35 Bev. Th, . " periment has been carried out with a magnetic momentum spectrometer-telescope consisting of two separate solid- izon magnets in conjun tinn iwith detectors of penetrating ionizing particles. The incident particles recorded were... directions of the particles as they entered the top magnet and the exit directions from the lower magnet. The magnitudes and directions of the deflections in the known magnetic field have then been used to determine the moments and charges...

Bateman, Benjamin Jefferson

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

High Gain, Fast Scan, Broad Spectrum, Parallel Beam Wavelength Dispersive X-ray Spectrometer for SEM  

SciTech Connect (OSTI)

Parallax Research, Inc. proposes to produce a new type of x-ray spectrometer for use with Scanning Electron Microscopy (SEM) that would have the energy resolution of WDS and the ease of use of EDS with sufficient gain for lower energies that it can be used at low beam currents as is EDS. Parallax proposes to do this by development of new multiple reflection x-ray collimation optics, new diffractor technology, new detector technology and new scan algorithms.

David OHara; Dr. Eric Lochmer

2003-09-12T23:59:59.000Z

402

Compact Reflective Imaging Spectrometer Design Utilizing An Immersed Grating And Anamorphic Mirror  

DOE Patents [OSTI]

A compact imaging spectrometer comprising an entrance slit, an anamorphic mirror, a grating, and a detector array. The entrance slit directs light to the anamorphic mirror. The anamorphic mirror receives the light and directs the light to the grating. The grating receives the light from the anamorphic mirror and defracts the light back onto the anamorphic mirror. The anamorphic mirror focuses the light onto a detector array.

Lerner, Scott A. (Corvalis, OR)

2006-01-10T23:59:59.000Z

403

Extending the response of the sum coincidence spectrometer to multiple gamma radiation cascades  

E-Print Network [OSTI]

). crystal of sodium iodide with the sample placed inside of it is used. For larger crystals there is less probability of part of the gamma-ray energy escaping. This method gives a high detection efficiency; however, the resolution of large crystals can... be limited by light collection problems. For precision gamma-ray spectroscopy, high resolution out-weighs the disadvantage of low detection efficiency. The three-crystal scintillation spectrometer, developed by Maieschein' and Bair5, gives higher counting...

Helton, Victor Dean

1964-01-01T23:59:59.000Z

404

Results for the response function determination of the Compact Neutron Spectrometer  

E-Print Network [OSTI]

The Compact Neutron Spectrometer (CNS) is a Joint European Torus (JET) Enhancement Project, designed for fusion diagnostics in different plasma scenarios. The CNS is based on a liquid scintillator (BC501A) which allows good discrimination between neutron and gamma radiation. Neutron spectrometry with a BC501A spectrometer requires the use of a reliable, fully characterized detector. The determination of the response matrix was carried out at the Ion Accelerator Facility (PIAF) of the Physikalisch-Technische Bundesanstalt (PTB). This facility provides several monoenergetic beams (2.5, 8, 10, 12 and 14 MeV) and a 'white field'(Emax ~17 MeV), which allows for a full characterization of the spectrometer in the region of interest (from ~1.5 MeV to ~17 MeV. The energy of the incoming neutrons was determined by the time of flight method (TOF), with time resolution in the order of 1 ns. To check the response matrix, the measured pulse height spectra were unfolded with the code MAXED and the resulting energy distribut...

Gagnon-Moisan, F; Zimbal, A

2012-01-01T23:59:59.000Z

405

Status of SuperSpec: A Broadband, On-Chip Millimeter-Wave Spectrometer  

E-Print Network [OSTI]

SuperSpec is a novel on-chip spectrometer we are developing for multi-object, moderate resolution (R = 100 - 500), large bandwidth (~1.65:1) submillimeter and millimeter survey spectroscopy of high-redshift galaxies. The spectrometer employs a filter bank architecture, and consists of a series of half-wave resonators formed by lithographically-patterned superconducting transmission lines. The signal power admitted by each resonator is detected by a lumped element titanium nitride (TiN) kinetic inductance detector (KID) operating at 100-200 MHz. We have tested a new prototype device that is more sensitive than previous devices, and easier to fabricate. We present a characterization of a representative R=282 channel at f = 236 GHz, including measurements of the spectrometer detection efficiency, the detector responsivity over a large range of optical loading, and the full system optical efficiency. We outline future improvements to the current system that we expect will enable construction of a photon-noise-lim...

Hailey-Dunsheath, S; Barry, P S; Bradford, C M; Chattopadhyay, G; Day, P; Doyle, S; Hollister, M; Kovacs, A; LeDuc, H G; Mauskopf, P; McKenney, C M; Monroe, R; O'Brient, R; Padin, S; Reck, T; Swenson, L; Tucker, C E; Zmuidzinas, J

2015-01-01T23:59:59.000Z

406

A design study of VOR: a versatile optimal resolution chopper spectrometer for the ESS  

E-Print Network [OSTI]

VOR, the versatile optimal resolution chopper spectrometer, is designed to probe dynamic phenomena that are currently inaccessible for inelastic neutron scattering due to flux limitations. VOR is a short instrument by the standards of the European Spallation Source (ESS), 30.2 m moderator to sample, and provides instantaneous access to a broad dynamic range, 1 - 120 meV within each ESS period. The short instrument length combined with the long ESS pulse width enables a quadratic flux increase, even at longer wavelengths, by relaxing energy resolution from $\\Delta$E/E = 1% up to $\\Delta$E/E = 7%. This is impossible both on a long chopper spectrometer at the ESS and with instruments at short pulsed sources. In comparison to current day chopper spectrometers, VOR can offer an order of magnitude improvement in flux for equivalent energy resolutions, $\\Delta$E/E = 1-3%. Further relaxing the energy resolution enables VOR to gain an extra order of magnitude in flux. In addition, VOR has been optimised for repetition...

Deen, P P; Andersen, K H; Hall-Wilton, R

2014-01-01T23:59:59.000Z

407

Superresolution of a compact neutron spectrometer at energies relevant for fusion diagnostics  

SciTech Connect (OSTI)

The ability to achieve resolution that is better than the instrument resolution (i.e., superresolution) is well known in optics, where it has been extensively studied. Unfortunately, there are only a handful of theoretical studies concerning superresolution of particle spectrometers, even though experimentalists are familiar with the enhancement of resolution that is achievable when appropriate methods of data analysis are used, such as maximum entropy and Bayesian methods. Knowledge of the superresolution factor is in many cases important. For example, in applications of neutron spectrometry to fusion diagnostics, the temperature of a burning plasma is an important physical parameter which may be inferred from the width of the peak of the neutron energy spectrum, and the ability to determine this width depends on the superresolution factor. Kosarev has derived an absolute limit for resolution enhancement using arguments based on a well known theorem of Shannon. Most calculations of superresolution factors in the literature, however, are based on the assumption of Gaussian, translationally invariant response functions and therefore not directly applicable to neutron spectrometers which typically have response functions not satisfying these requirements. In this work, we develop a procedure that allows us to overcome these difficulties and we derive estimates of superresolution for liquid scintillator spectrometers of a type commonly used for neutron measurements. Theoretical superresolution factors are compared to experimental results.

Reginatto, M.; Zimbal, A. [Physikalisch-Technische Bundesanstalt (PTB), Braunschweig (Germany)

2011-03-14T23:59:59.000Z

408

Application of non-radiometric methods to the determination of plutonium. Literature review conducted for the Buried Waste Integrated Program  

SciTech Connect (OSTI)

This literature review was motivated by discussions that took place during a review of contamination control technologies proposed for INEL (buried waste). It should be a useful tool in identifying non-radiation measurement techniques for Pu and Am such as ICP-MS, which should fulfill the following criteria: apparatus must be field deployable; up to 100 samples per day; and lower levels of detection and required time must be listed. The sensitivity of ICP and RIMS is compared against that needed for contamination monitoring at INEL. Only Pu-241, with a required detection limit of 400 ppt, would challenge the sensitivity of ICP-MS; Pu-238 would be easily determined. The need to determine Pu-238 and Am-241 in the presence of U-238 and Pu-241 seems to preclude the possibility of using laser ablation ICP-MS for Pu monitoring. ICP-AES and -LEAFS methods may not have enough sensitivity to determine Pu-238 at 2 ppb level with confidence, but RIMS (resonance ionization mass spectroscopy) should be adequate. 47 refs, figs.

Edelson, M.C.

1992-03-05T23:59:59.000Z

409

Design of a Real-Time Scanning Electrical Mobility Spectrometer and its Application in Study of Nanoparticle Aerosol Generation  

E-Print Network [OSTI]

A real-time, mobile Scanning Electrical Mobility Spectrometer (SEMS) was designed using a Condensation Particle Counter (CPC) and Differential Mobility Analyzer (DMA) to measure the size distribution of nanoparticles. The SEMS was calibrated using...

Singh, Gagan

2012-07-16T23:59:59.000Z

410

Absolute neutrino mass measurements  

SciTech Connect (OSTI)

The neutrino mass plays an important role in particle physics, astrophysics and cosmology. In recent years the detection of neutrino flavour oscillations proved that neutrinos carry mass. However, oscillation experiments are only sensitive to the mass-squared difference of the mass eigenvalues. In contrast to cosmological observations and neutrino-less double beta decay (0v2{beta}) searches, single {beta}-decay experiments provide a direct, model-independent way to determine the absolute neutrino mass by measuring the energy spectrum of decay electrons at the endpoint region with high accuracy.Currently the best kinematic upper limits on the neutrino mass of 2.2eV have been set by two experiments in Mainz and Troitsk, using tritium as beta emitter. The next generation tritium {beta}-experiment KATRIN is currently under construction in Karlsruhe/Germany by an international collaboration. KATRIN intends to improve the sensitivity by one order of magnitude to 0.2eV. The investigation of a second isotope ({sup 137}Rh) is being pursued by the international MARE collaboration using micro-calorimeters to measure the beta spectrum. The technology needed to reach 0.2eV sensitivity is still in the R and D phase. This paper reviews the present status of neutrino-mass measurements with cosmological data, 0v2{beta} decay and single {beta}-decay.

Wolf, Joachim [Karlsruhe Institute of Technology (KIT), IEKP, Postfach 3640, 76021 Karlsruhe (Germany)

2011-10-06T23:59:59.000Z

411

Determination of iodine to compliment mass spectrometric measurements  

SciTech Connect (OSTI)

The dose of iodine-129 to facility personnel and the general public as a result of past, present, and future activities at DOE sites is of continuing interest, WINCO received about 160 samples annually in a variety of natural matrices, including snow, milk, thyroid tissue, and sagebrush, in which iodine-129 is determined in order to evaluate this dose, Currently, total iodine and the isotopic ratio of iodine-127 to iodine-129 are determined by mass spectrometry. These two measurements determine the concentration of iodine-129 in each sample, These measurements require at least 16 h of mass spectrometer operator time for each sample. A variety of methods are available which concentrate and determine small quantities of iodine. Although useful, these approaches would increase both time and cost. The objective of this effort was to determine total iodine by an alternative method in order to decrease the load on mass spectrometry by 25 to 50%. The preparation of each sample for mass spectrometric analysis involves a common step--collection of iodide on an ion exchange bed. This was the focal point of the effort since the results would be applicable to all samples.

Hohorst, F.A.

1994-11-01T23:59:59.000Z

412

MASS POLITICAL MOBILIZATION  

E-Print Network [OSTI]

................................................................................................................................................... MASS POLITICAL MOBILIZATION ................................................................................................................................................... Boix & Stokes: The Oxford Handbook of Comparative Politics Boixandstokes-chap21 Revise Proof page 497 20.4.2007 12:41pm #12;Boix & Stokes: The Oxford Handbook of Comparative Politics Boixandstokes-chap21

413

Masses of Fundamental Particles  

E-Print Network [OSTI]

In the original paper entitled, "Masses of Fundamental Particles"(arXiv:1109.3705v5, 10 Feb 2012), not only the masses of fundamental particles including the weak bosons, Higgs boson, quarks, and leptons, but also the mixing angles of quarks and those of neutrinos are all explained and/or predicted in the unified composite models of quarks and leptons successfully. In this addendum entitled, "Higgs Boson Mass in the Minimal Unified Subquark Model", it is emphasized that the Higgs boson mass is predicted to be about 130Gev in the minimal unified subquark model, which agrees well with the experimental values of 125-126GeV recently found by the ATLAS and CMS Collaborations at the LHC.

Hidezumi Terazawa

2014-06-11T23:59:59.000Z

414

Heavy Hybrid mesons Masses  

E-Print Network [OSTI]

We estimate the ground state masses of the heavy hybrid mesons using a phenomenological QCD-type potential. 0^{- -},1^{- -},0^{- +},1^{- +} and 0^{+ -} J^{PC} states are considered.

F. Iddir; L. Semlala

2006-11-13T23:59:59.000Z

415

HIGEE Mass Transfer  

E-Print Network [OSTI]

HIGEE MASS TRANSFER R.J. Mohr and R. Fowler GLITSCH, INC. Dallas, Texas ABSTRACT Distillation, absorption, and gas stripping have traditionally been performed in tall columns utilizing trays or packing. Columns perform satisfactorily... transfer system which utilizes a rotating bed of packing to achieve high efficiency separations, and consequent reduction in size and weight. INTRODUCTION HIGEE is probably one of the most interesting developments in mass transfer equipment made...

Mohr, R. J.; Fowler, R.

416

spectrometer | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

iron nanoparticles was quantified by monitoring the kinetics as well as products of carbon tetrachloride reduction, and significant differences in reactivity and chloroform...

417

Exploration of the neutron-rich mass surface from sup 11 Li to sup 66 Fe  

SciTech Connect (OSTI)

A small revolution in our ability to perform mass measurements of light-mass, neutron-rich nuclei has occurred during the last five years with the extension of the direct, total mass measurement method to fast recoiling nuclei. To date the work of two groups, one using the SPEG spectrometer at GANIL and the other using the TOFI spectrometer at LAMPF, has yielded over 85 mass measurements of which 62 had not been reported previously. Extending from the neutron-halo nucleus {sup 11}Li up to {sup 66}Fe, a region relevant to the astrophysical r-process, these measurements have provided a valuable first glimpse into the interesting nuclear structure present in many of these exotic nuclei. Herein we highlight the nuclear structure insight which as been gained from these measurements, especially that learned from a comparison to recent shell model calculations. Attention is given to: (1) the binding of loosely-bound neutron halo nuclei; (2) the N=14--16 region in the neutron-rich isotopes of O, F, and Ne where the strong two-body interaction plays an important role; (3) the deformed intruder state region around {sup 31}Na of long standing interest; (4) the neutron-rich isotopes of sulfur and chlorine; and (5) the question of the isospin dependence (or independence) of neutron and proton pairing energies in the fp shell. Only the briefest account of this work can be given here; emphasis is placed on the most recent results. 24 refs., 3 figs.

Vieira, D.J.; Wouters, J.M.; Butler, G.W. (Los Alamos National Lab., NM (United States)); Seifert, H.L. (Los Alamos National Lab., NM (United States) Giessen Univ. (Germany). 2. Physikalisches Inst.); Zhou, Z.Y. (Los Alamos National Lab., NM (United States) Nanjing Univ., JS (China). Dept. of Physics and Astronomy); Zhou, X.G.; Tu, X.L.; Lind, V.G. (Utah State Univ., Logan, UT (United States). Dept.

1991-01-01T23:59:59.000Z

418

Exploration of the neutron-rich mass surface from {sup 11}Li to {sup 66}Fe  

SciTech Connect (OSTI)

A small revolution in our ability to perform mass measurements of light-mass, neutron-rich nuclei has occurred during the last five years with the extension of the direct, total mass measurement method to fast recoiling nuclei. To date the work of two groups, one using the SPEG spectrometer at GANIL and the other using the TOFI spectrometer at LAMPF, has yielded over 85 mass measurements of which 62 had not been reported previously. Extending from the neutron-halo nucleus {sup 11}Li up to {sup 66}Fe, a region relevant to the astrophysical r-process, these measurements have provided a valuable first glimpse into the interesting nuclear structure present in many of these exotic nuclei. Herein we highlight the nuclear structure insight which as been gained from these measurements, especially that learned from a comparison to recent shell model calculations. Attention is given to: (1) the binding of loosely-bound neutron halo nuclei; (2) the N=14--16 region in the neutron-rich isotopes of O, F, and Ne where the strong two-body interaction plays an important role; (3) the deformed intruder state region around {sup 31}Na of long standing interest; (4) the neutron-rich isotopes of sulfur and chlorine; and (5) the question of the isospin dependence (or independence) of neutron and proton pairing energies in the fp shell. Only the briefest account of this work can be given here; emphasis is placed on the most recent results. 24 refs., 3 figs.

Vieira, D.J.; Wouters, J.M.; Butler, G.W. [Los Alamos National Lab., NM (United States); Seifert, H.L. [Los Alamos National Lab., NM (United States)]|[Giessen Univ. (Germany). 2. Physikalisches Inst.; Zhou, Z.Y. [Los Alamos National Lab., NM (United States)]|[Nanjing Univ., JS (China). Dept. of Physics and Astronomy; Zhou, X.G.; Tu, X.L.; Lind, V.G. [Utah State Univ., Logan, UT (United States). Dept. of Physics; Loebner, K.E.G. [Muenchen Univ. (Germany). Sektion Physik

1991-12-01T23:59:59.000Z

419

MAINTAINING HIGH RESOLUTION MASS SPECTROMETRY CAPABILITIES FOR NATIONAL NUCLEAR SECURITY ADMINISTRATION APPLICATIONS  

SciTech Connect (OSTI)

The Department of Energy (DOE) National Nuclear Security Administration (NNSA) has a specialized need for analyzing low mass gas species at very high resolutions. The currently preferred analytical method is electromagnetic sector mass spectrometry. This method allows the NNSA Nuclear Security Enterprise (NSE) to resolve species of similar masses down to acceptable minimum detection limits (MDLs). Some examples of these similar masses are helium-4/deuterium and carbon monoxide/nitrogen. Through the 1980s and 1990s, there were two vendors who supplied and supported these instruments. However, with declining procurements and down turns in the economy, the supply of instruments, service and spare parts from these vendors has become less available, and in some cases, nonexistent. The largest NSE user of this capability is the Savannah River Site (SRS), located near Aiken, South Carolina. The Research and Development Engineering (R&DE) Group in the Savannah River National Laboratory (SRNL) investigated the areas of instrument support that were needed to extend the life cycle of these aging instruments. Their conclusions, as to the focus areas of electromagnetic sector mass spectrometers to address, in order of priority, were electronics, software and hardware. Over the past 3-5 years, the R&DE Group has designed state of the art electronics and software that will allow high resolution legacy mass spectrometers, critical to the NNSA mission, to be operated for the foreseeable future. The funding support for this effort has been from several sources, including the SRS Defense Programs, NNSA Readiness Campaign, Pantex Plant and Sandia National Laboratory. To date, electronics systems have been upgraded on one development system at SRNL, two production systems at Pantex and one production system at Sandia National Laboratory. An NSE working group meets periodically to review strategies going forward. The R&DE Group has also applied their work to the electronics for a Thermal Ionization Mass Spectrometer (TIMS) instrument, which applies a similar mass spectrometric technology for resolving high mass isotopes, such as plutonium and uranium. Due to non-compete clauses for DOE, all work has been performed and applied to instruments which are obsolete and are no longer supported by the original vendor.

Wyrick, S.; Cordaro, J.; Reeves, G.; Mcintosh, J.; Mauldin, C.; Tietze, K.; Varble, D.

2011-06-06T23:59:59.000Z

420

Atomic mass compilation 2012  

SciTech Connect (OSTI)

Atomic mass reflects the total binding energy of all nucleons in an atomic nucleus. Compilations and evaluations of atomic masses and derived quantities, such as neutron or proton separation energies, are indispensable tools for research and applications. In the last decade, the field has evolved rapidly after the advent of new production and measuring techniques for stable and unstable nuclei resulting in substantial ameliorations concerning the body of data and their precision. Here, we present a compilation of atomic masses comprising the data from the evaluation of 2003 as well as the results of new measurements performed. The relevant literature in refereed journals and reports as far as available, was scanned for the period beginning 2003 up to and including April 2012. Overall, 5750 new data points have been collected. Recommended values for the relative atomic masses have been derived and a comparison with the 2003 Atomic Mass Evaluation has been performed. This work has been carried out in collaboration with and as a contribution to the European Nuclear Structure and Decay Data Network of Evaluations.

Pfeiffer, B., E-mail: bpfeiffe@uni-mainz.de [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany); GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany); Venkataramaniah, K. [Sri Sathya Sai Institute of Higher Learning, Prasanthinilayam (India)] [Sri Sathya Sai Institute of Higher Learning, Prasanthinilayam (India); Czok, U. [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany)] [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany); Scheidenberger, C. [GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany) [GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany); II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany)

2014-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

High-resolution x-ray spectroscopy with the EBIT Calorimeter Spectrometer  

SciTech Connect (OSTI)

The EBIT Calorimeter Spectrometer (ECS) is a production-class 36 pixel x-ray calorimeter spectrometer that has been continuously operating at the Electron Beam Ion Trap (EBIT) facility at Lawrence Livermore National Laboratory for almost 2 years. The ECS was designed to be a long-lifetime, turn-key spectrometer that couples high performance with ease of operation and minimal operator intervention. To this end, a variant of the Suzaku/XRS spaceflight detector system has been coupled to a low-maintenance cryogenic system consisting of a long-lifetime liquid He cryostat, and a closed cycle, {sup 3}He pre-cooled adiabatic demagnetization refrigerator. The ECS operates for almost 3 weeks between cryogenic servicing and the ADR operates at 0.05 K for more than 60 hours between automatic recycles under software control. Half of the ECS semiconductor detector array is populated with mid-band pixels that have a resolution of 4.5 eV FWHM, a bandpass from 0.05-12 keV, and a quantum efficiency of 95% at 6 keV. The other half of the array has thick HgTe absorbers that have a bandpass from 0.3 to over 100 keV, an energy resolution of 33 eV FWHM, and a quantum efficiency of 32% at 60 keV. In addition, the ECS uses a real-time, autonomous, data collection and analysis system developed for the Suzaku/XRS instrument and implemented in off-the-shelf hardware for the ECS. Here we will discuss the performance of the ECS instrument and its implementation as a turnkey cryogenic detector system.

Porter, F S; Adams, J S; Beiersdorfer, P; Brown, G V; Clementson, J; Frankel, M; Kahn, S M; Kelley, R L; Kilbourne, C A

2009-10-01T23:59:59.000Z

422

Sampling probe for microarray read out using electrospray mass spectrometry  

DOE Patents [OSTI]

An automated electrospray based sampling system and method for analysis obtains samples from surface array spots having analytes. The system includes at least one probe, the probe including an inlet for flowing at least one eluting solvent to respective ones of a plurality of spots and an outlet for directing the analyte away from the spots. An automatic positioning system is provided for translating the probe relative to the spots to permit sampling of any spot. An electrospray ion source having an input fluidicly connected to the probe receives the analyte and generates ions from the analyte. The ion source provides the generated ions to a structure for analysis to identify the analyte, preferably being a mass spectrometer. The probe can be a surface contact probe, where the probe forms an enclosing seal along the periphery of the array spot surface.

Van Berkel, Gary J.

2004-10-12T23:59:59.000Z

423

On the kinematics and resolution of spectrometers for neutron Brillouin scattering  

SciTech Connect (OSTI)

Neutron Brillouin scattering involves measurement of excitations at smaller Q values than in currently customary. We outline the kinematic constraints on scattering angle and incident energy for excitations with both linear dispersion (sound waves) and parabolic dispersion (ferromagnetic spin waves), and discuss the resolution characteristics of the chopper spectrometer proposed for LANSCE which should be suitable for such studies. In particular, we demonstrate that longitudinal resolution focusing can be exploited both in neutron energy gain and in neutron energy loss. 13 refs., 8 figs., 1 tab.

Robinson, R.A.

1988-01-01T23:59:59.000Z

424

A multi-object, multi-field spectrometer and imager for a European ELT  

E-Print Network [OSTI]

One of the highlights of the European ELT Science Case book is the study of resolved stellar populations, potentially out to the Virgo Cluster of galaxies. A European ELT would enable such studies in a wide range of unexplored distant environments, in terms of both galaxy morphology and metallicity. As part of a small study, a revised science case has been used to shape the conceptual design of a multi-object, multi-field spectrometer and imager (MOMSI). Here we present an overview of some key science drivers, and how to achieve these with elements such as multiplex, AO-correction, pick-off technology and spectral resolution.

Chris Evans; Colin Cunningham; Eli Atad-Ettedgui; Jeremy Allington-Smith; Francois Assemat; Gavin Dalton; Peter Hastings; Timothy Hawarden; Isobel Hook; Rob Ivison; Simon Morris; Suzanne Ramsay Howat; Mel Strachan; Stephen Todd

2006-05-19T23:59:59.000Z

425

A radial collimator for a time-of-flight neutron spectrometer  

SciTech Connect (OSTI)

We have engineered and installed a radial collimator for use in the scattered beam of a neutron time-of-flight spectrometer at a spallation neutron source. The radial collimator may be used with both thermal and epithermal neutrons, reducing the detected scattering intensity due to material outside of the sample region substantially. The collimator is located inside of the sample chamber of the instrument, which routinely cycles between atmospheric conditions and cryogenic vacuum. The oscillation and support mechanism of the collimator allow it to be removed from use without breaking vacuum. We describe here the design and characterization of this radial collimator.

Stone, M. B.; Abernathy, D. L. [Quantum Condensed Matter Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Niedziela, J. L.; Loguillo, M. J.; Overbay, M. A. [Instrument and Source Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2014-08-15T23:59:59.000Z

426

Progress in development of neutron energy spectrometer for deuterium plasma operation in KSTAR  

SciTech Connect (OSTI)

Two types of DD neutron energy spectrometer (NES) are under development for deuterium plasma operation in KSTAR to understand behavior of beam ions in the plasma. One is based on the state-of-the-art nuclear emulsion technique. The other is based on a coincidence detection of a recoiled proton and a scattered neutron caused by an elastic scattering of an incident DD neutron, which is called an associated particle coincidence counting-NES. The prototype NES systems were installed at J-port in KSTAR in 2012. During the 2012 and 2013 experimental campaigns, multiple shots-integrated neutron spectra were preliminarily obtained by the nuclear emulsion-based NES system.

Tomita, H., E-mail: tomita@nagoya-u.jp; Yamashita, F.; Nakayama, Y.; Morishima, K.; Yamamoto, Y.; Sakai, Y.; Hayashi, S.; Kawarabayashi, J.; Iguchi, T. [Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Cheon, M. S. [Diagnostics Technology Team, ITER Korea, National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of); Isobe, M. [The Graduate University for Advanced Studies, 322-6 Oroshi-cho, Toki 509-5292 (Japan); National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan); Ogawa, K. [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan)

2014-11-15T23:59:59.000Z

427

Galaxy Cosmological Mass Function  

E-Print Network [OSTI]

We study the galaxy cosmological mass function (GCMF) in a semi-empirical relativistic approach using observational data provided by galaxy redshift surveys. Starting from the theory of Ribeiro & Stoeger (2003, arXiv:astro-ph/0304094) between the mass-to-light ratio, the selection function obtained from the luminosity function (LF) data and the luminosity density, the average luminosity $L$ and the average galactic mass $\\mathcal{M}_g$ are computed in terms of the redshift. $\\mathcal{M}_g$ is also alternatively estimated by a method that uses the galaxy stellar mass function (GSMF). Comparison of these two forms of deriving the average galactic mass allows us to infer a possible bias introduced by the selection criteria of the survey. We used the FORS Deep Field galaxy survey sample of 5558 galaxies in the redshift range $0.5 light ratio and its GSMF data. Assuming ${\\mathcal{M}_{g_0}} \\approx 10^{11} \\mathcal{M}_\\odot$ as the local value of the average galactic mass, the LF approach results in $L_{B} \\propto (1+z)^{(2.40 \\pm 0.03)}$ and $\\mathcal{M}_g \\propto (1+z)^{(1.1\\pm0.2)}$. However, using the GSMF results produces $\\mathcal{M}_g \\propto (1+z)^{(-0.58 \\pm 0.22)}$. We chose the latter result as it is less biased. We then obtained the theoretical quantities of interest, such as the differential number counts, to calculate the GCMF, which can be fitted by a Schechter function. The derived GCMF follows theoretical predictions in which the less massive objects form first, being followed later by more massive ones. In the range $0.5 < z < 2.0$ the GCMF has a strong variation that can be interpreted as a higher rate of galaxy mergers or as a strong evolution in the star formation history of these galaxies.

Amanda R. Lopes; Alvaro Iribarrem; Marcelo B. Ribeiro; William R. Stoeger

2014-12-03T23:59:59.000Z

428

Mass of Ne-16  

E-Print Network [OSTI]

1983 The American Physical Society 28 C. J. WOODWARD, R. E. TRIBBLE, AND D. M. TANNER 27 tron rf. A 0.3 mm Kapton absorber foil was insert- ed after the proportional counter in order to ensure that the He particles stopped in the Si detector...PHYSICAL REVIEWER C VOLUME 27, NUMBER 1 Mass of ' Ne JANUARY 1983 C. J. Woodward, * R. E. Tribble, and D. M. Tanner Cyclotron Institute, Texas A&M University, College Station, Texas 77843 (Received 23 August 1982) The mass of ' Ne has been...

Woodward, C. J.; Tribble, Robert E.; Tanner, D. M.

1983-01-01T23:59:59.000Z

429

Evaluation of the LLNL Spectrometer for Possible use with the NSTec Optical Streak Camera as a Light Gas Gun Diagnostic  

SciTech Connect (OSTI)

In fiscal year 2012, it was desired to combine a visible spectrometer with a streak camera to form a diagnostic system for recording time-resolved spectra generated in light gas gun experiments. Acquiring a new spectrometer was an option, but it was possible to borrow an existing unit for a period of months, which would be sufficient to evaluate both “off-line” and in-gas gun shots. If it proved adequate for this application, it could be duplicated (with possible modifications); if not, such testing would help determine needed specifications for another model. This report describes the evaluation of the spectrometer (separately and combined with the NSTec LO streak camera) for this purpose. Spectral and temporal resolutions were of primary interest. The first was measured with a monochromatic laser input. The second was ascertained by the combination of the spectrometer’s spatial resolution in the time-dispersive direction and the streak camera’s intrinsic temporal resolution. System responsivity was also important, and this was investigated by measuring the response of the spectrometer/camera system to black body input—the gas gun experiments are expected to be similar to a 3000K black body—as well as measuring the throughput of the spectrometer separately over a range of visible light provided by a monochromator. The flat field (in wavelength) was also measured and the final part of the evaluation was actual fielding on two gas gun shots. No firm specifications for spectral or temporal resolution were defined precisely, but these were desired to be in the 1–2 nm and 1–2 ns ranges, respectively, if possible. As seen below, these values were met or nearly met, depending on wavelength. Other performance parameters were also not given (threshold requirements) but the evaluations performed with laser, black body, and successful gas gun shots taken in aggregate indicate that the spectrometer is adequate for this purpose. Even still, some (relatively minor) opportunities for improvement were noticed and these were documented for incorporation into any near-duplicate spectrometer that might be fabricated in the future.

O'Connor, J., Cradick, J.

2012-09-27T23:59:59.000Z

430

Mass Extinctions Geology 331  

E-Print Network [OSTI]

into shallow water and released to atmosphere. · Oxidation of coal and hydrocarbons by extensive erosion of sedimentary rocks, and/or massive volcanic eruptions in Siberia? CH2O + O2 CO2 +H2O · Release of methane by rapid influx of C12 caused by methane release and mass dying at the end of the Permian. Organisms

Kammer, Thomas

431

Residential Thermal Mass Construction  

E-Print Network [OSTI]

The southwest has long known the value of building homes with high mass materials. The ancient Pueblo Indians found that by using "adobe" they could capture the energy necessary to survive the harsh desert climate. Our ancestors knew that a heavy...

Thieken, J. S.

1988-01-01T23:59:59.000Z

432

2{pi} spectrometer: A new apparatus for the investigation of ion surface interaction  

SciTech Connect (OSTI)

A new spectrometer for studying ion surface interaction is described. This apparatus is built around a secondary electron and ion detector with a very large acceptance angle and made of 16 individual microchannel plate detectors located on a half sphere. A simultaneous detection of the scattered projectiles with an additional position sensitive detector allows measurements of the correlation between all these particles using a multicoincidence technique. With this spectrometer, a large variety of measurements are possible such as the energy spectra of the secondary electrons as well as the statistics of the number of ejected electrons, the scattering pattern of the reflected projectiles and their charge-state distribution, the analysis of the sputtered ions. Some examples are given concerning the impact of multiply charged ions on a LiF single crystal. The dependence of the secondary electron multiplicity as a function of the charge state, of the surface channeling condition, and of the scattering angle of the reflected ion, is given as a type of information provided by the analysis of the correlation. {copyright} {ital 1996 American Institute of Physics.}

Morosov, V.A.; Kalinin, A.; Szilagyi, Z.; Barat, M.; Roncin, P. [Laboratoire des Collisions Atomiques et Moleculaires, Bat 351, Universite Paris Sud, Orsay Cedex F 91405 (France)] [Laboratoire des Collisions Atomiques et Moleculaires, Bat 351, Universite Paris Sud, Orsay Cedex F 91405 (France)

1996-06-01T23:59:59.000Z

433

The magnetic shielding for the neutron decay spectrometer aSPECT  

E-Print Network [OSTI]

Many experiments in nuclear and neutron physics are confronted with the problem that they use a superconducting magnetic spectrometer which potentially affects other experiments by their stray magnetic field. The retardation spectrometer aSPECT consists, inter alia, of a superconducting magnet system that produces a strong longitudinal magnetic field of up to 6.2T. In order not to disturb other experiments in the vicinity of aSPECT, we had to develop a magnetic field return yoke for the magnet system. While the return yoke must reduce the stray magnetic field, the internal magnetic field and its homogeneity should not be affected. As in many cases, the magnetic shielding for aSPECT must manage with limited space. In addition, we must ensure that the additional magnetic forces on the magnet coils are not destructive. In order to determine the most suitable geometry for the magnetic shielding for aSPECT, we simulated a variety of possible geometries and combinations of shielding materials of non-linear permeability. The results of our simulations were checked through magnetic field measurements both with Hall and nuclear magnetic resonance probes. The experimental data are in good agreement with the simulated values: The mean deviation from the simulated exterior magnetic field is (-1.7+/-4.8)%. However, in the two critical regions, the internal magnetic field deviates by 0.2% respectively <1E-4 from the simulated values.

Gertrud Konrad; Fidel Ayala Guardia; Stefan Baeßler; Michael Borg; Ferenc Glück; Werner Heil; Stefan Hiebel; Raquel Munoz Horta; Yury Sobolev

2014-05-05T23:59:59.000Z

434

A split imaging spectrometer for temporally and spatially resolved titanium absorption spectroscopy  

SciTech Connect (OSTI)

We present a temporally and a spatially resolved spectrometer for titanium x-ray absorption spectroscopy along 2 axial symmetric lines-of-sight. Each line-of-sight of the instrument uses an elliptical crystal to acquire both the 2p and 3p Ti absorption lines on a single, time gated channel of the instrument. The 2 axial symmetric lines-of-sight allow the 2p and 3p absorption features to be measured through the same point in space using both channels of the instrument. The spatially dependent material temperature can be inferred by observing the 2p and the 3p Ti absorption features. The data are recorded on a two strip framing camera with each strip collecting data from a single line-of-sight. The design is compatible for use at both the OMEGA laser and the National Ignition Facility. The spectrometer is intended to measure the material temperature behind a Marshak wave in a radiatively driven SiO{sub 2} foam with a Ti foam tracer. In this configuration, a broad band CsI backlighter will be used for a source and the Ti absorption spectrum measured.

Hager, J. D., E-mail: hager@lanl.gov; Lanier, N. E.; Kline, J. L.; Flippo, K. A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Bruns, H. C.; Schneider, M.; Saculla, M.; McCarville, T. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

2014-11-15T23:59:59.000Z

435

In Silico Identification Software (ISIS): A Machine Learning Approach to Tandem Mass Spectral Identification of Lipids  

SciTech Connect (OSTI)

Liquid chromatography-mass spectrometry-based metabolomics has gained importance in the life sciences, yet it is not supported by software tools for high throughput identification of metabolites based on their fragmentation spectra. An algorithm (ISIS: in silico identification software) and its implementation are presented and show great promise in generating in silico spectra of lipids for the purpose of structural identification. Instead of using chemical reaction rate equations or rules-based fragmentation libraries, the algorithm uses machine learning to find accurate bond cleavage rates in a mass spectrometer employing collision-induced dissocia-tion tandem mass spectrometry. A preliminary test of the algorithm with 45 lipids from a subset of lipid classes shows both high sensitivity and specificity.

Kangas, Lars J.; Metz, Thomas O.; Isaac, Georgis; Schrom, Brian T.; Ginovska-Pangovska, Bojana; Wang, Luning; Tan, Li; Lewis, Robert R.; Miller, John H.

2012-05-15T23:59:59.000Z

436

Nanoelectrospray ion generation for high-throughput mass spectrometry using a micromachined ultrasonic ejector array  

SciTech Connect (OSTI)

Ultrasonic electrospray ionization (ESI) for high-throughput mass spectrometry is demonstrated using a silicon micromachined microarray. The device uses a micromachined ultrasonic atomizer operating in the 900 kHz-2.5 MHz range for droplet generation and a metal electrode in the fluid cavity for ionization. Since the atomization and ionization processes are separated, the ultrasonic ESI source shows the potential for operation at low voltages with a wide range of solvents in contrast with conventional capillary ESI technology. This is demonstrated using the ultrasonic ESI microarray to obtain the mass spectrum of a 10 {mu}M reserpine sample on a time of flight mass spectrometer with 197:1 signal-to-noise ratio at an ionization potential of 200 V.

Aderogba, S.; Meacham, J.M.; Degertekin, F.L.; Fedorov, A.G.; Fernandez, F.M. [G.W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States)

2005-05-16T23:59:59.000Z

437

Top-Down Mass Spectrometry Imaging of Intact Proteins by LAESI FT-ICR MS  

E-Print Network [OSTI]

Laser Ablation Electrospray Ionization is a recent development in mass spectrometry imaging. It has been shown that lipids and small metabolites can be imaged in various samples such as plant material, tissue sections or bacterial colonies without anysample pre-treatment. Further, laser ablation electrospray ionization has been shown to produce multiply charged protein ions from liquids or solid surfaces. This presents a means to address one of the biggest challenges in mass spectrometry imaging; the identification of proteins directly from biological tissue surfaces. Such identification is hindered by the lack of multiply charged proteins in common MALDI ion sources and the difficulty of performing tandem MS on such large, singly charged ions. We present here top-down identification of intact proteins from tissue with a LAESI ion source combined with a hybrid ion-trap FT-ICR mass spectrometer. The performance of the system was first tested with a standard protein with ECD and IRMPD fragmentation to prove the...

Kiss, András; Reschke, Brent R; Powell, Matthew J; Heeren, Ron M A

2013-01-01T23:59:59.000Z

438

The In-medium Mass and Widths of Light Vector Mesons  

SciTech Connect (OSTI)

Partial restoration of chiral symmetry in ordinary nuclear matter suggests the modification of properties of vector mesons, such as a shift in mass and/or a change of width. Photoproduction of vector mesons off nuclei were performed at Jefferson Lab using the CEBAF Large Acceptance Spectrometer (CLAS). The properties of the {rho}, {omega} and {phi} mesons were investigated via their rare leptonic decay to e+e-. This decay channel has an advantage over hadronic modes as it eliminates final state interactions in the nuclear matter. After subtracting the combinatorial background, the meson mass distributions were extracted for each of the nuclear targets. No significant mass shift is observed, however substantial increase in the widths of the mesons is reported.

Djalali, C.; Paolone, M. [University of South Carolina, Department of Physics and Astronomy, Columbia, SC 29208 (United States); Weygand, D. [Thomas Jefferson National Accelerator Facility, Newport News, VA 23606 (United States); Wood, M. H. [Canisius College, Department of Physics, Buffalo, NY 14208 (United States); Nasseripour, R. [George Washington University, Department of Physics, Washington, DC 20052 (United States)

2011-05-23T23:59:59.000Z

439

Elemental and isotopic analysis of inorganic salts by laser desorption ionization mass spectrometry  

SciTech Connect (OSTI)

Laser desorption ionization mass spectrometry is applied for the analysis of elements as well as their isotopic composition in different inorganic salts. At very low laser energies the inorganic ions are desorbed and ionized from the thin layer of the sample surface. The naturally occurring isotopes of alkali and silver ions are resolved using time of flight mass spectrometer. Further increase in laser energy shows the appearance of Al, Cr, and Fe ions in the mass spectra. This indicates the penetration laser beam beyond the sample surface leading to the ablation of sample target at higher energies. The simultaneous appearance of atomic ions from the sample target at relatively higher laser energies hampers the unambiguous identification of amino acid residues from the biomolecular ions in MALDI-MS.

Jayasekharan, T.; Sahoo, N. K. [Applied Spectroscopy Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India)

2013-02-05T23:59:59.000Z

440

Riddle of the Neutrino Mass  

E-Print Network [OSTI]

We discuss some known approaches and results as well as few new ideas concerning origins and nature of neutrino mass. The key issues include (i) connections of neutrino and charged fermions masses, relation between masses and mixing, energy scale of new physics behind neutrino mass where possibilities spread from the Planck and GUT masses down to a sub-eV scale. The data hint two different new physics involved in generation of neutrino mass. Determination of the CP phase as well as mass hierarchy can play important role in identification of new physics. It may happen that sterile neutrinos provide the key to resolve the riddle.

Smirnov, A Yu

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

High-resolution, high-transmission soft x-ray spectrometer for the study of biological samples  

SciTech Connect (OSTI)

We present a variable line-space grating spectrometer for soft s-rays that coverst the photon energy range between 130 and 650 eV. The optical design is based on the Hettrick-Underwood principle and tailored to synchrotron-based studies of radiation-sensitive biological samples. The spectrometer is able to record the entire spectral range in one shot, i.e., without any mechanical motion, at a resolving power of 1200 or better. Despite is slitless design, such a resolving power can be achieved for a source spot as large as (30 x 3000) micrometers squared, which is important for keeping beam damage effects in radiation-sensitive samples low. The high spectrometer efficiency allows recording of comprehensive two-dimensional resonant inelastic soft x-ray scatters (RIXS) maps with good statistics within several minutes. This is exemplarily demonstrated for a RIXS map of highly oriented pyrolytic graphite, which was taken with 10 min.

Fuchs, Oliver; Weinhardt, L.; Blum, M.; Welgand, M.; Umbach, E.; Bar, M.; Heske, C.; Denlinger, J.; Chuang, Y.-D.; McKinney, W.; Hussain, Z.; Gullikson, E.; Jones, M.; Batson, P.; Nelles, B.; Follath, R.

2009-06-11T23:59:59.000Z

442

High-resolution, high-transmission soft x-ray spectrometer for the study of biological samples  

SciTech Connect (OSTI)

We present a variable line-space grating spectrometer for soft x-rays that covers the photon energy range between 130 and 650 eV. The optical design is based on the Hettrick-Underwood principle and tailored to synchrotron-based studies of radiation-sensitive biological samples. The spectrometer is able to record the entire spectral range in one shot, i.e., without any mechanical motion, at a resolving power of 1200 or better. Despite its slitless design, such a resolving power can be achieved for a source spot as large as 30x3000 mu m2, which is important for keeping beam damage effects in radiation-sensitive samples low. The high spectrometer efficiency allows recording of comprehensive two-dimensional resonant inelastic soft x-ray scattering (RIXS) maps with good statistics within several minutes. This is exemplarily demonstrated for a RIXS map of highly oriented pyrolytic graphite, which was taken within 10 min.

Fuchs, Oliver; Weinhardt, L.; Blum, M.; Weigand, M.; Umbach, E.; Bar, M.; Heske, Clemens; Denlinger, Jonathan; Chuang, Y.-D.; McKinney, Wayne; Hussain, Zahid; Gullikson, Eric; Jones, M.; Batson, Phil; Nelles, B.; Follath, R.

2009-03-09T23:59:59.000Z

443

Qualification of a high-efficiency, gated spectrometer for x-ray Thomson scattering on the National Ignition Facility  

SciTech Connect (OSTI)

We have designed, built, and successfully fielded a highly efficient and gated Bragg crystal spectrometer for x-ray Thomson scattering measurements on the National Ignition Facility (NIF). It utilizes a cylindrically curved Highly Oriented Pyrolytic Graphite crystal. Its spectral range of 7.4–10?keV is optimized for scattering experiments using a Zn He-? x-ray probe at 9.0 keV or Mo K-shell line emission around 18 keV in second diffraction order. The spectrometer has been designed as a diagnostic instrument manipulator-based instrument for the NIF target chamber at the Lawrence Livermore National Laboratory, USA. Here, we report on details of the spectrometer snout, its novel debris shield configuration and an in situ spectral calibration experiment with a Brass foil target, which demonstrated a spectral resolution of E/?E = 220 at 9.8 keV.

Döppner, T.; Kritcher, A. L.; Bachmann, B.; Burns, S.; Hawreliak, J.; House, A.; Landen, O. L.; LePape, S.; Ma, T.; Pak, A.; Swift, D. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Neumayer, P. [Gesellschaft für Schwerionenphysik, 64291 Darmstadt (Germany); Kraus, D. [University of California, Berkeley, California 94720 (United States); Falcone, R. W. [University of California, Berkeley, California 94720 (United States); Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Glenzer, S. H. [SLAC National Accelerator Laboratory, Menlo Park, California 94309 (United States)

2014-11-15T23:59:59.000Z

444

CAMEA ESS - The Continuous Angle Multi-Energy Analysis Indirect Geometry Spectrometer for the European Spallation Source  

E-Print Network [OSTI]

The CAMEA ESS neutron spectrometer is designed to achieve a high detection efficiency in the horizontal scattering plane, and to maximize the use of the long pulse European Spallation Source. It is an indirect geometry time-of-flight spectrometer that uses crystal analysers to determine the final energy of neutrons scattered from the sample. Unlike other indirect gemeotry spectrometers CAMEA will use ten concentric arcs of analysers to analyse scattered neutrons at ten different final energies, which can be increased to 30 final energies by use of prismatic analysis. In this report we will outline the CAMEA instrument concept, the large performance gain, and the potential scientific advancements that can be made with this instrument.

Freeman, P G; Markó, M; Bertelsen, M; Larsen, J; Christensen, N B; Lefmann, K; Jacobsen, J; Niedermayer, Ch; Juranyi, F; Ronnow, H M

2014-01-01T23:59:59.000Z

445

Isoscalar giant resonances in Si-28 and the mass dependence of nuclear compressibility  

E-Print Network [OSTI]

the mass dependence of the GMR energy quite well and this led to the conclusion that a Gogny interaction with Knm523165 MeV was consistent with the data. 0556-2813/2002/65~3!/034302~7!/$20.00 65 034302- s dependence of nuclear compressibility . Lui... of the spectrometer was 4? and ray tracing was used ?2002 The American Physical Society1 an a ~fm D. H. YOUNGBLOOD, Y.-W. LUI, AND H. L. CLARK PHYSICAL REVIEW C 65 034302 shape at low excitation @Eq. ~1!# to model particle threshold effects: Y ~continuum!5A1B...

Youngblood, David H.; Lui, YW; Clark, HL.

2002-01-01T23:59:59.000Z

446

Nanoscale mass conveyors  

DOE Patents [OSTI]

A mass transport method and device for individually delivering chargeable atoms or molecules from source particles is disclosed. It comprises a channel; at least one source particle of chargeable material fixed to the surface of the channel at a position along its length; a means of heating the channel; and a means for applying an controllable electric field along the channel, whereby the device transports the atoms or molecules along the channel in response to applied electric field. In a preferred embodiment, the mass transport device will comprise a multiwalled carbon nanotube (MWNT), although other one dimensional structures may also be used. The MWNT or other structure acts as a channel for individual or small collections of atoms due to the atomic smoothness of the material. Also preferred is a source particle of a metal such as indium. The particles move by dissociation into small units, in some cases, individual atoms. The particles are preferably less than 100 nm in size.

Regan, Brian C. (Oakland, CA); Aloni, Shaul (Albany, CA); Zettl, Alexander K. (Kensington, CA)

2008-03-11T23:59:59.000Z

447

Design and commissioning of a high magnetic field muon spin relaxation spectrometer at the ISIS pulsed neutron and muon source  

SciTech Connect (OSTI)

The high magnetic field (HiFi) muon instrument at the ISIS pulsed neutron and muon source is a state-of-the-art spectrometer designed to provide applied magnetic fields up to 5 T for muon studies of condensed matter and molecular systems. The spectrometer is optimised for time-differential muon spin relaxation studies at a pulsed muon source. We describe the challenges involved in its design and construction, detailing, in particular, the magnet and detector performance. Commissioning experiments have been conducted and the results are presented to demonstrate the scientific capabilities of the new instrument.

Lord, J. S.; McKenzie, I.; Baker, P. J.; Cottrell, S. P.; Giblin, S. R.; Hillier, A. D.; Holsman, B. H.; King, P. J. C.; Nightingale, J. B.; Pratt, F. L.; Rhodes, N. J. [ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Oxon OX11 0QX (United Kingdom); Blundell, S. J.; Lancaster, T. [Clarendon Laboratory, Department of Physics, Oxford University, Parks Road, Oxford OX1 3PU (United Kingdom); Good, J.; Mitchell, R.; Owczarkowski, M.; Poli, S. [Cryogenic Limited, 30 Acton Park Industrial Estate, The Vale, Acton, London W3 7QE (United Kingdom); Scheuermann, R. [Laboratory for Muon Spin Spectroscopy, Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland); Salman, Z. [ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Oxon OX11 0QX (United Kingdom); Clarendon Laboratory, Department of Physics, Oxford University, Parks Road, Oxford OX1 3PU (United Kingdom)

2011-07-15T23:59:59.000Z

448

A user's guide to SWIFT: A Monte Carlo technique for inference of differential energy spectra from multisphere spectrometer measurements  

SciTech Connect (OSTI)

SWIFT is a FORTRAN-77 program written for the VAX-11/750 computer. Its purpose is to unfold neutron spectra from multisphere spectrometer measurements using the Monte Carlo technique. This guide describes the code in sufficient detail to enable a user, with a background in FORTRAN programming, to alter the code for use with other spectrometers and/or to install it on computers other than the VAX-11/750. The code and the required input and resulting output are described. As an aid to its implementation, input and output for a sample problem are also presented. 19 refs., 1 fig., 6 tabs.

Sanna, R.S.; O'Brien, K.

1987-12-01T23:59:59.000Z

449

Breakdown of the Isobaric Multiplet Mass Equation for the A = 20 and 21 Multiplets  

E-Print Network [OSTI]

Using the Penning trap mass spectrometer TITAN, we performed the first direct mass measurements of 20,21Mg, isotopes that are the most proton-rich members of the A = 20 and A = 21 isospin multiplets. These measurements were possible through the use of a unique ion-guide laser ion source, a development that suppressed isobaric contamination by six orders of magnitude. Compared to the latest atomic mass evaluation, we find that the mass of 21Mg is in good agreement but that the mass of 20Mg deviates by 3{\\sigma}. These measurements reduce the uncertainties in the masses of 20,21Mg by 15 and 22 times, respectively, resulting in a significant departure from the expected behavior of the isobaric multiplet mass equation in both the A = 20 and A = 21 multiplets. This presents a challenge to shell model calculations using either the isospin non-conserving USDA/B Hamiltonians or isospin non-conserving interactions based on chiral two- and three-nucleon forces.

A. T. Gallant; M. Brodeur; C. Andreoiu; A. Bader; A. Chaudhuri; U. Chowdhury; A. Grossheim; R. Klawitter; A. A. Kwiatkowski; K. G. Leach; A. Lennarz; T. D. Macdonald; B. E. Schultz; J. Lassen; H. Heggen; S. Raeder; A. Teigelhöfer; B. A. Brown; A. Magilligan; J. D. Holt; J. Menéndez; J. Simonis; A. Schwenk; J. Dilling

2014-09-04T23:59:59.000Z

450

Electrospray Ionization Mass Spectrometry  

SciTech Connect (OSTI)

Electrospray Ionization (ESI) is a process whereby gas phase ions are created from molecules in solution. As a solution exits a narrow tube in the presence of a strong electric field, an aerosol of charged droplets are is formed that produces gas phase ions as they it desolvates. ESI-MS comprises the creation of ions by ESI and the determination of their mass to charge ratio (m/z) by MS.

Kelly, Ryan T.; Marginean, Ioan; Tang, Keqi

2014-06-13T23:59:59.000Z

451

Arsenic speciation and transport associated with the release of spent geothermal fluids in Mutnovsky field (Kamchatka, Russia)  

SciTech Connect (OSTI)

The use of geothermal fluids for the production of electricity poses a risk of contaminating surface waters when spent fluids are discharged into (near) surface environments. Arsenic (As) in particular is a common component in geothermal fluids and leads to a degradation of water quality when present in mobile and bioavailable forms. We have examined changes in arsenic speciation caused by quick transition from high temperature reducing conditions to surface conditions, retention mechanisms, and the extent of transport associated with the release of spent geothermal fluids at the Dachny geothermal fields (Mutnovsky geothermal region), Kamchatka, Russia -- a high temperature field used for electricity production. In the spent fluids, the arsenic concentration reaches 9 ppm, while in natural hot springs expressed in the vicinity of the field, the As concentration is typically below 10 ppb. The aqueous phase arsenic speciation was determined using Liquid Chromatography (LC) coupled to an Inductively Coupled Plasma Mass Spectrometer (ICP-MS). The arsenic speciation in the bottom sediments (< 65 {mu}m fraction) of the local surface waters was analyzed using X-ray Absorption Spectroscopy (XAS). Arsenic in the geothermal source fluids is predominantly found as As(III), while a mixture of As(III)/As(V) is found in the water and sediment of the Falshivaia River downstream from the power plant. The extent of elevated arsenic concentrations in water is limited by adsorption to the bottom sediment and dilution, as determined using Cl{sup -} from the deep well fluids as a tracer. Analysis of the Extended X-ray Absorption Fine Structure (EXAFS) spectra shows that sediment phase arsenic is associated with both Al- and Fe-rich phases with a bi-dentate corner sharing local geometry. The geothermal waste fluids released in the surface water create a localized area of arsenic contamination. The extent of transport of dissolved As is limited to {approx}7 km downstream from the source, while As associated with bottom sediment travels {approx}3 km farther.

Ilgen, Anastasia G.; Rychagov, Sergey N.; Trainor, Thomas P. (Alaska Fairbanks); (Russ. Acad. Sci.)

2011-09-20T23:59:59.000Z

452

Mass spectrometry of proteins of known mass Andrew D. Miranker*  

E-Print Network [OSTI]

deter- mination has two significant advantages. First, the mass accuracy under these conditions to the orifice of the mass analyzer. As a result, there is a local separation of charges at the tip

Miranker, Andrew

453

Velocity-space sensitivity of the time-of-flight neutron spectrometer at JET  

SciTech Connect (OSTI)

The velocity-space sensitivities of fast-ion diagnostics are often described by so-called weight functions. Recently, we formulated weight functions showing the velocity-space sensitivity of the often dominant beam-target part of neutron energy spectra. These weight functions for neutron emission spectrometry (NES) are independent of the particular NES diagnostic. Here we apply these NES weight functions to the time-of-flight spectrometer TOFOR at JET. By taking the instrumental response function of TOFOR into account, we calculate time-of-flight NES weight functions that enable us to directly determine the velocity-space sensitivity of a given part of a measured time-of-flight spectrum from TOFOR.

Jacobsen, A. S., E-mail: Ajsen@fysik.dtu.dk; Salewski, M.; Korsholm, S. B.; Leipold, F.; Nielsen, S. K.; Rasmussen, J.; Stejner, M. [Association Euratom - DTU, Technical University of Denmark, Department of Physics, Kgs. Lyngby (Denmark); Eriksson, J.; Ericsson, G.; Hjalmarsson, A. [Association Euratom - VR, Uppsala University, Department of Physics and Astronomy, Uppsala (Sweden)

2014-11-15T23:59:59.000Z

454

Development and operation of a high-throughput accurate-wavelength lens-based spectrometer  

SciTech Connect (OSTI)

A high-throughput spectrometer for the 400–820 nm wavelength range has been developed for charge exchange recombination spectroscopy or general spectroscopy. A large 2160 mm{sup ?1} grating is matched with fast f/1.8 200 mm lenses, which provide stigmatic imaging. A precision optical encoder measures the grating angle with an accuracy ?0.075 arc sec. A high quantum efficiency low-etaloning CCD detector allows operation at longer wavelengths. A patch panel allows input fibers to interface with interchangeable fiber holders that attach to a kinematic mount at the entrance slit. Computer-controlled hardware allows automated control of wavelength, timing, f-number, automated data collection, and wavelength calibration.

Bell, Ronald E., E-mail: rbell@pppl.gov [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States)

2014-11-15T23:59:59.000Z

455

The magnetic recoil spectrometer for measurements of the absolute neutron spectrum at OMEGA and the NIF  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

The neutron spectrum produced by deuterium-tritium (DT) inertial confinement fusion implosions contains a wealth of information about implosion performance including the DT yield, iontemperature, and areal-density. The Magnetic Recoil Spectrometer (MRS) has been used at both the OMEGA laser facility and the National Ignition Facility (NIF) to measure the absolute neutron spectrum from 3 to 30 MeV at OMEGA and 3 to 36 MeV at the NIF. These measurements have been used to diagnose the performance of cryogenic target implosions to unprecedented accuracy. Interpretation of MRS data requires a detailed understanding of the MRS response and background. This paper describes ab initio characterization of the system involving Monte Carlo simulations of the MRS response in addition to the commission experiments for in situ calibration of the systems on OMEGA and the NIF.

Casey, D. T. [MIT, Cambridge, MA (United States). Plasma Science and Fusion Center; Frenje, J. A. [MIT, Cambridge, MA (United States). Plasma Science and Fusion Center; Gatu Johnson, M. [MIT, Cambridge, MA (United States). Plasma Science and Fusion Center; Seguin, F. H. [MIT, Cambridge, MA (United States). Plasma Science and Fusion Center; Li, C. K. [MIT, Cambridge, MA (United States). Plasma Science and Fusion Center; Petrasso, R. D. [MIT, Cambridge, MA (United States). Plasma Science and Fusion Center; Glebov, V. Yu. [Univ. of Rochester, NY (United States). Lab. for Laser Energitics; Katz, J. [Univ. of Rochester, NY (United States). Lab. for Laser Energitics; Magoon, J. [Univ. of Rochester, NY (United States). Lab. for Laser Energitics; Meyerhofer, D. D. [Univ. of Rochester, NY (United States). Lab. for Laser Energitics; Sangster, T. C. [Univ. of Rochester, NY (United States). Lab. for Laser Energitics; Shoup, M. [Univ. of Rochester, NY (United States). Lab. for Laser Energitics; Ulreich, J. [Univ. of Rochester, NY (United States). Lab. for Laser Energitics; Ashabranner, R. C. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Bionta, R. M. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Carpenter, A. C. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Felker, B. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Khater, H. Y. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); LePape, S. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); MacKinnon, A. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); McKernan, M. A. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Moran, M. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Rygg, J. R. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Yeoman, M. F. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Zacharias, R. [Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States); Leeper, R. J. [Sandia National Laboratories, Albuquerque, NM (United States); Fletcher, K. [State Univ. of New York at Geneseo, NY (United States); Farrell, M. [General Atomics, San Diego, CA (United States); Jasion, D. [General Atomics, San Diego, CA (United States); Kilkenny, J. [General Atomics, San Diego, CA (United States); Paguio, R. [General Atomics, San Diego, CA (United States)

2013-01-01T23:59:59.000Z

456

The High Momentum Spectrometer Drift Chambers in Hall C at CEBAF  

SciTech Connect (OSTI)

The mutiwire drift chambers to be used in the High Momentum Spectrometer (HMS) at the Continuous Electron Beam Accelerator Facility (CEBAF) have been designed and constructed, and recently employed in initial data-taking runs.These chambers are used to reconstruct scattered charged particle momenta in the HMS using 12C and BeO2 targets for incident electron energies up to 2.2 GeV.Offline analysis of the data indicate that these drift chambers have spatial resolution (per plane) of about 115 mu-m (sigma) in rates approaching a KHz/wire/mm.It is expected that this performance will improve at higher momenta where multiple scattering contributions are smaller.

Vulcan, William; Kross, Brian; Beaufait, Joseph; Baker, O.; Carlini, Roger; Majewski, Stanislaw; Johnson, A.; McCauley, A.; Niculescu, Gabriel; Niculescu, Maria-Ioana; Cha, Jinseok; Shin, Taeksu; Naing, Win; Danagoulian, Samuel

1995-12-01T23:59:59.000Z

457

X-ray imaging crystal spectrometer for extended X-ray sources  

DOE Patents [OSTI]

Spherically or toroidally curved, double focusing crystals are used in a spectrometer for X-ray diagnostics of an extended X-ray source such as a hot plasma produced in a tokomak fusion experiment to provide spatially and temporally resolved data on plasma parameters using the imaging properties for Bragg angles near 45. For a Bragg angle of 45.degree., the spherical crystal focuses a bundle of near parallel X-rays (the cross section of which is determined by the cross section of the crystal) from the plasma to a point on a detector, with parallel rays inclined to the main plain of diffraction focused to different points on the detector. Thus, it is possible to radially image the plasma X-ray emission in different wavelengths simultaneously with a single crystal.

Bitter, Manfred L. (Princeton, NJ); Fraenkel, Ben (Jerusalem, IL); Gorman, James L. (Bordentown, NJ); Hill, Kenneth W. (Lawrenceville, NJ); Roquemore, A. Lane (Cranbury, NJ); Stodiek, Wolfgang (Princeton, NJ); von Goeler, Schweickhard E. (Princeton, NJ)

2001-01-01T23:59:59.000Z

458

The magnetic recoil spectrometer for measurements of the absolute neutron spectrum at OMEGA and the NIF  

SciTech Connect (OSTI)

The neutron spectrum produced by deuterium-tritium (DT) inertial confinement fusion implosions contains a wealth of information about implosion performance including the DT yield, ion-temperature, and areal-density. The Magnetic Recoil Spectrometer (MRS) has been used at both the OMEGA laser facility and the National Ignition Facility (NIF) to measure the absolute neutron spectrum from 3 to 30 MeV at OMEGA and 3 to 36 MeV at the NIF. These measurements have been used to diagnose the performance of cryogenic target implosions to unprecedented accuracy. Interpretation of MRS data requires a detailed understanding of the MRS response and background. This paper describes ab initio characterization of the system involving Monte Carlo simulations of the MRS response in addition to the commission experiments for in situ calibration of the systems on OMEGA and the NIF.

Casey, D. T.; Frenje, J. A.; Gatu Johnson, M.; Seguin, F. H.; Li, C. K.; Petrasso, R. D. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Glebov, V. Yu.; Katz, J.; Magoon, J.; Meyerhofer, D. D.; Sangster, T. C.; Shoup, M.; Ulreich, J. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States); Ashabranner, R. C.; Bionta, R. M.; Carpenter, A. C.; Felker, B.; Khater, H. Y.; LePape, S.; MacKinnon, A. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); and others

2013-04-15T23:59:59.000Z

459

Operation of a high purity germanium crystal in liquid argon as a Compton suppressed radiation spectrometer  

E-Print Network [OSTI]

A high purity germanium crystal was operated in liquid argon as a Compton suppressed radiation spectrometer. Spectroscopic quality resolution of less than 1% of the full-width half maximum of full energy deposition peaks was demonstrated. The construction of the small apparatus used to obtain these results is reported. The design concept is to use the liquid argon bath to both cool the germanium crystal to operating temperatures and act as a scintillating veto. The scintillation light from the liquid argon can veto cosmic-rays, external primordial radiation, and gamma radiation that does not fully deposit within the germanium crystal. This technique was investigated for its potential impact on ultra-low background gamma-ray spectroscopy. This work is based on a concept initially developed for future germanium-based neutrinoless double-beta decay experiments.

John L. Orrell; Craig E. Aalseth; John F. Amsbaugh; Peter J. Doe; Todd W. Hossbach

2006-10-11T23:59:59.000Z

460

A comparison of four direct geometry time-of-flight spectrometers at the Spallation Neutron Source  

SciTech Connect (OSTI)

The Spallation Neutron Source at Oak Ridge National Laboratory now hosts four direct geometry time-of-flight chopper spectrometers. These instruments cover a range of wave-vector and energy transfer space with varying degrees of neutron flux and resolution. The regions of reciprocal and energy space available to measure at these instruments are not exclusive and overlap significantly. We present a direct comparison of the capabilities of this instrumentation, conducted by data mining the instrument usage histories, and specific scanning regimes. In addition, one of the common science missions for these instruments is the study of magnetic excitations in condensed matter systems. We have measured the powder averaged spin wave spectra in one particular sample using each of these instruments, and use these data in our comparisons.

Stone, M. B.; Abernathy, D. L.; Ehlers, G.; Garlea, O.; Podlesnyak, A.; Winn, B. [Quantum Condensed Matter Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)] [Quantum Condensed Matter Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Niedziela, J. L.; DeBeer-Schmitt, L.; Graves-Brook, M. [Instrument and Source Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)] [Instrument and Source Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Granroth, G. E. [Neutron Data Analysis and Visualization Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)] [Neutron Data Analysis and Visualization Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Kolesnikov, A. I. [Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)] [Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2014-04-15T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


461

Data acquisition system with pulse height capability for the TOFED time-of-flight neutron spectrometer  

SciTech Connect (OSTI)

A new time-of-flight neutron spectrometer TOFED has been constructed for installation at Experimental Advanced Superconducting Tokamak. A data acquisition system combining measurements of flight time and energy from the interaction of neutrons with the TOFED scintillators has been developed. The data acquisition system can provide a digitizing resolution better than 1.5% (to be compared with the >10% resolution of the recoil particle energy in the plastic scintillators) and a time resolution <1 ns. At the same time, it is compatible with high count rate event recording, which is an essential feature to investigate phenomena occurring on time scales faster than the slowing down time (?100 ms) of the beam ions in the plasma. Implications of these results on the TOFED capability to resolve fast ion signatures in the neutron spectrum from EAST plasmas are discussed.

Chen, Z. J.; Peng, X. Y.; Zhang, X.; Du, T. F.; Hu, Z. M.; Cui, Z. Q.; Ge, L. J.; Xie, X. F.; Yuan, X.; Li, X. Q.; Zhang, G. H.; Chen, J. X.; Fan, T. S., E-mail: tsfan@pku.edu.cn [School of Physics and State Key Laboratory of Nuclear Physics and Technology, Peking University, Beijing 100871 (China); Gorini, G.; Nocente, M.; Tardocchi, M. [Dipartimento di Fisica, Università di Milano-Bicocca, Milano, Piazza della Scienza 3, 20126 Milano (Italy); Istituto di Fisica del Plasma “P. Caldirola”, EURATOM-ENEA-CNR Association, Via Cozzi 53, 20125 Milano (Italy); Hu, L. Q.; Zhong, G. Q.; Lin, S. Y.; Wan, B. N. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031, Anhui (China)

2014-11-15T23:59:59.000Z

462

A soft x-ray transmission grating imaging-spectrometer for the National Ignition Facility  

SciTech Connect (OSTI)

A soft x-ray transmission grating spectrometer has been designed for use on high energy-density physics experiments at the National Ignition Facility (NIF); coupled to one of the NIF gated x-ray detectors it records 16 time-gated spectra between 250 and 1000 eV with 100 ps temporal resolution. The trade-off between spectral and spatial resolution leads to an optimized design for measurement of emission around the peak of a 100-300 eV blackbody spectrum. Performance qualification results from the NIF, the Trident Laser Facility and vacuum ultraviolet beamline at the National Synchrotron Light Source, evidence a <100 {mu}m spatial resolution in combination with a source-size limited spectral resolution that is <10 eV at photon energies of 300 eV.

Moore, A. S.; Guymer, T. M.; Morton, J.; Bentley, C.; Stevenson, M. [Directorate Science and Technology, AWE Aldermaston, Reading, RG7 4PR (United Kingdom); Kline, J. L.; Taccetti, M.; Lanier, N. E.; Workman, J.; Peterson, B.; Mussack, K.; Cowan, J. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Prasad, R.; Richardson, M.; Burns, S.; Kalantar, D. H.; Benedetti, L. R.; Bell, P.; Bradley, D.; Hsing, W. [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551-0808 (United States)

2012-10-15T23:59:59.000Z

463

Measuring the absolute DT neutron yield using the Magnetic Recoil Spectrometer at OMEGA and the NIF  

SciTech Connect (OSTI)

A Magnetic Recoil Spectrometer (MRS) has been installed and extensively used on OMEGA and the National Ignition Facility (NIF) for measurements of the absolute neutron spectrum from inertial confinement fusion (ICF) implosions. From the neutron spectrum measured with the MRS, many critical implosion parameters are determined including the primary DT neutron yield, the ion temperature, and the down-scattered neutron yield. As the MRS detection efficiency is determined from first principles, the absolute DT neutron yield is obtained without cross-calibration to other techniques. The MRS primary DT neutron measurements at OMEGA and the NIF are shown to be in excellent agreement with previously established yield diagnostics on OMEGA, and with the newly commissioned nuclear activation diagnostics on the NIF.

Mackinnon, A; Casey, D; Frenje, J A; Johnson, M G; Seguin, F H; Li, C K; Petrasso, R D; Glebov, V Y; Katz, J; Knauer, J; Meyerhofer, D; Sangster, T; Bionta, R; Bleuel, D; Hachett, S P; Hartouni, E; Lepape, S; Mckernan, M; Moran, M; Yeamans, C

2012-05-03T23:59:59.000Z

464

A soft x-ray transmission grating imaging-spectrometer for the National Ignition Facility  

SciTech Connect (OSTI)

A soft x-ray transmission grating spectrometer has been designed for use on high energy-density physics experiments at the National Ignition Facility (NIF); coupled to one of the NIF gated x-ray detectors (GXD) it records sixteen time-gated spectra between 250 and 1000eV with 100ps temporal resolution. The trade-off between spectral and spatial resolution leads to an optimized design for measurement of emission around the peak of a 100-300eV blackbody spectrum. Performance qualification results from the NIF, the Trident Laser Facility and VUV beamline at the National Synchrotron Light Source (NSLS), evidence a <100{micro}m spatial resolution in combination with a source-size limited spectral resolution that is <10eV at photon energies of 300eV.

Moore, A S; Guymer, T M; Kline, J L; Morton, J; Taccetti, M; Lanier, N E; Bentley, C; Workman, J; Peterson, B; Mussack, K; Cowan, J; Prasad, R; Richardson, M; Burns, S; Kalantar, D H; Benedetti, L R; Bell, P; Bradley, D; Hsing, W; Stevenson, M

2012-05-01T23:59:59.000Z

465

Development and Operation of High-throughput Accurate-wavelength Lens-based Spectrometer  

SciTech Connect (OSTI)

A high-throughput spectrometer for the 400-820 nm wavelength range has been developed for charge exchange recombination spectroscopy or general spectroscopy. A large 2160 mm-1 grating is matched with fast f /1.8 200 mm lenses, which provide stigmatic imaging. A precision optical encoder measures the grating angle with an accuracy < 0.075 arc seconds. A high quantum efficiency low-etaloning CCD detector allows operation at longer wavelengths. A patch panel allows input fibers to interface with interchangeable fiber holders that attach to a kinematic mount behind the entrance slit. Computer-controlled hardware allows automated control of wavelength, timing, f-number, automated data collection, and wavelength calibration.

Bell, Ronald E

2014-07-01T23:59:59.000Z

466

Total Ozone Mapping Spectrometer (TOMS) Derived Data, Global Earth Coverage (GEC) from NASA's Earth Probe Satellite  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

This is data from an external datastream processed through the ARM External Data Center (XDC) at Brookhaven National Laboratory. The XDC identifies sources and acquires data, called "external data", to augment the data being generated within the ARM program. The external data acquired are usually converted from native format to either netCDF or HDF formats. The GEC collection contains global data derived from the Total Ozone Mapping Spectrometer (TOMS) instrument on the Earth Probe satellite, consisting of daily values of aerosol index, ozone and reflectivity remapped into a regular 1x1.25 deg grid. Data are available from July 25, 1996 - December 31, 2005, but have been updated or replaced as of September 2007. See the explanation on the ARM web site at http://www.arm.gov/xds/static/toms.stm and the information at the NASA/TOMS web site: http://toms.gsfc.nasa.gov/ (Registration required)

467

Tunable vacuum ultraviolet laser based spectrometer for angle resolved photoemission spectroscopy  

SciTech Connect (OSTI)

We have developed an angle-resolved photoemission spectrometer with tunable vacuum ultraviolet laser as a photon source. The photon source is based on the fourth harmonic generation of a near IR beam from a Ti:sapphire laser pumped by a CW green laser and tunable between 5.3 eV and 7 eV. The most important part of the set-up is a compact, vacuum enclosed fourth harmonic generator based on potassium beryllium fluoroborate crystals, grown hydrothermally in the US. This source can deliver a photon flux of over 10{sup 14} photon/s. We demonstrate that this energy range is sufficient to measure the k{sub z} dispersion in an iron arsenic high temperature superconductor, which was previously only possible at synchrotron facilities.

Jiang, Rui; Mou, Daixiang; Wu, Yun; Huang, Lunan; Kaminski, Adam [Division of Materials Science and Engineering, Ames Laboratory, Ames, Iowa 50011 (United States) [Division of Materials Science and Engineering, Ames Laboratory, Ames, Iowa 50011 (United States); Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); McMillen, Colin D.; Kolis, Joseph [Department of Chemistry, Clemson University, Clemson, South Carolina 29634 (United States)] [Department of Chemistry, Clemson University, Clemson, South Carolina 29634 (United States); Giesber, Henry G.; Egan, John J. [Advanced Photonic Crystals LLC, Fort Mill, South Carolina 29708 (United States)] [Advanced Photonic Crystals LLC, Fort Mill, South Carolina 29708 (United States)

2014-03-15T23:59:59.000Z

468

Dual mode ion mobility spectrometer and method for ion mobility spectrometry  

DOE Patents [OSTI]

Ion mobility spectrometer apparatus may include an ion interface that is operable to hold positive and negative ions and to simultaneously release positive and negative ions through respective positive and negative ion ports. A first drift chamber is operatively associated with the positive ion port of the ion interface and encloses an electric field therein. A first ion detector operatively associated with the first drift chamber detects positive ions from the first drift chamber. A second drift chamber is operatively associated with the negative ion port of the ion interface and encloses an electric field therein. A second ion detector operatively associated with the second drift chamber detects negative ions from said second drift chamber.

Scott, Jill R [Idaho Falls, ID; Dahl, David A [Idaho Falls, ID; Miller, Carla J [Idaho Falls, ID; Tremblay, Paul L [Idaho Falls, ID; McJunkin, Timothy R [Idaho Falls, ID

2007-08-21T23:59:59.000Z

469

Deuterium density profile determination at JET using a neutron camera and a neutron spectrometer  

SciTech Connect (OSTI)

In this work we estimate the fuel ion density profile in deuterium plasmas at JET, using the JET neutron camera, the neutron time-of-flight spectrometer TOFOR, and fusion reactivities modeled by the transport code TRANSP. The framework has been tested using synthetic data, which showed that the density profile could be reconstructed with an average accuracy of the order of 10 %. The method has also been applied to neutron measurements from a neutral beam heated JET discharge, which gave n{sub d}/n{sub e} ? 0.6 ± 0.3 in the plasma core and n{sub d}/n{sub e} ? 0.4 ± 0.3 towards the edge. Correction factors for detector efficiencies, neutron attenuation, and back-scattering are not yet included in the analysis; future work will aim at refining the estimated density.

Eriksson, J., E-mail: jacob.eriksson@physics.uu.se; Castegnetti, G.; Conroy, S.; Ericsson, G.; Hellesen, C. [EURATOM-VR, Department of Physics and Astronomy, Uppsala University (Sweden); Giacomelli, L. [Department of Physics, Università degli Studi di Milano-Bicocca, Milano (Italy); EURATOM-CCFE Fusion Association, Culham Science Centre, Abingdon (United Kingdom)

2014-11-15T23:59:59.000Z

470

IBIS: An inverse geometry Brillouin inelastic neutron spectrometer for the SNS  

SciTech Connect (OSTI)

The high power target station at the Spallation Neutron Source (SNS) currently has about 20 completed neutron scattering instruments. With a broad coverage of the momentum transfer (Q)-energy (E) space, these instruments serve an extensive user community. In an effort to further expand the scientific capabilities of the SNS instrument suites, we propose a low background, inverse geometry Brillouin inelastic spectrometer for the SNS which will expand the Q-E coverage of the current instrument suite and facilitate the study of inelastic and quasi-elastic scatterings at low Q values. The possible location for the proposed instrument is either beamline 8 which views the decoupled water moderator, or beamline 14A, which views a cold, coupled super critical hydrogen moderator. The instrument parameters, optimizations, and performances at these two beamline locations are discussed.

Zhao, J. K.; Robertson, Lee; Herwig, Kenneth W. [Instrument and Source Development Division, Spallation Neutron Source, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Wildgruber, Christoph U. [Chemical and Engineering Division, Spallation Neutron Source, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2013-02-15T23:59:59.000Z

471

Wavelength Determination for Solar Features Observed by the EUV Imaging Spectrometer on Hinode  

SciTech Connect (OSTI)

A wavelength calibration of solar lines observed by the high resolution EUV Imaging Spectrometer (EIS) on the Hinode satellite is reported. Spectral features of the quiet sun and of two mildly active areas were measured and calibrated. A listing of the stronger observed lines with identification of the leading contributor ions is presented. 41 lines are reported, with 90% identified. Wavelength precisions (2{sigma}) of {+-}0.0031 Angstroms for the EIS short band and {+-}0.0029 Angstroms for the EIS long band are obtained. These lines, typical of 1-2x10{sup 6} K plasmas, are recommended as standards for the establishment of EIS wavelength scales. The temperature of EIS varies by about 1.5 C around the orbit and also with spacecraft pointing. The correlation of these temperature changes with wavelength versus pixel number scale changes is reported.

Brown,C.; Hara, H.; Kamio, S.; Feldman, U.; Seely, J.; Doschek, G.; Mariska, J.; Korendyke, C.; Lang, J.; Dere, K.

2007-01-01T23:59:59.000Z

472

Developing a narrow-line laser spectrometer based on a tunable continuous-wave dye laser  

SciTech Connect (OSTI)

We present the development of a dye-laser-based spectrometer operating at 550–600 nm. The spectrometer will be used to detect an ultra-narrow clock transition ({sup 1}S{sub 0}-{sup 3}P{sub 0}) in an Ytterbium optical lattice clock and perform high-resolution spectroscopy of iodine molecules trapped in the sub-nanometer channels of zeolite crystal (AlPO{sub 4}-11). Two-stage Pound-Drever-Hall frequency stabilization is implemented on the tunable continuous-wave dye laser to obtain a reliable operation and provide stable laser radiations with two different spectral linewidths. In the first-stage frequency locking, a compact home-built intracavity electro-optic modulator is adopted for suppressing fast frequency noise. With an acquisition time of 0.1 s the 670-kHz linewidth of the free-running dye laser is reduced to 2 kHz when locked to a pre-stabilization optical cavity with a finesse of 1170. When the pre-stabilized laser is locked to a high-finesse optical cavity, a linewidth of 1.4 Hz (2 s) is observed and the frequency stability is 3.7 × 10{sup ?15} (3 s). We also measure and analyze the individual noise contributions such as those from residual amplitude modulation and electronic noise. The ongoing upgrades include improving long-term frequency stability at time scales from 10 to 100 s and implementing continuous frequency scan across 10 GHz with radio-frequency precision.

Wang, Chun; Lv, Shasha; Bi, Jin [Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Liu, Fang [College of Engineering and Applied Sciences, Nanjing University, Nanjing 210093 (China); Li, Liufeng; Chen, Lisheng [Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (China); State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan 430071, China and Laboratory of Atomic Frequency Standards, Chinese Academy of Sciences, Wuhan 430071 (China)

2014-08-15T23:59:59.000Z

473

Streaked x-ray spectrometer having a discrete selection of Bragg geometries for Omega  

SciTech Connect (OSTI)

The streaked x-ray spectrometer (SXS) is used with streak cameras [D. H. Kalantar, P. M. Bell, R. L. Costa, B. A. Hammel, O. L. Landen, T. J. Orzechowski, J. D. Hares, and A. K. L. Dymoke-Bradshaw, in 22nd International Congress on High-Speed Photography and Photonics, edited by D. L. Paisley and A. M. Frank (SPIE, Bellingham, WA, 1997), Vol. 2869, p. 680] positioned with a ten-inch manipulator on OMEGA [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)] and OMEGA EP [L. J. Waxer et al., Presented at CLEO/QELS 2008, San Jose, CA, 4-9 May 2008 (Paper JThB1)] for time-resolved, x-ray spectroscopy of laser-produced plasmas in the 1.4- to 20-keV photon-energy range. These experiments require measuring a portion of this photon-energy range to monitor a particular emission or absorption feature of interest. The SXS relies on a pinned mechanical reference system to create a discrete set of Bragg reflection geometries for a variety of crystals. A wide selection of spectral windows is achieved accurately and efficiently using this technique. It replaces the previous spectrometer designs that had a continuous Bragg angle adjustment and required a tedious alignment calibration procedure. The number of spectral windows needed for the SXS was determined by studying the spectral ranges selected by OMEGA users over the last decade. These selections are easily configured in the SXS using one of the 25 discrete Bragg reflection geometries and one of the six types of Bragg crystals, including two curved crystals.

Millecchia, M.; Regan, S. P.; Bahr, R. E.; Romanofsky, M.; Sorce, C. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623-1299 (United States)

2012-10-15T23:59:59.000Z

474

Total Absorption Gamma-ray Spectrometer (TAGS) Intensity Distributions from INL's Gamma-Ray Spectrometry Center  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

A 252Cf fission-product source and the INL on-line isotope separator were used to supply isotope-separated fission-product nuclides to a total absorption -ray spectrometer. This spectrometer consisted of a large (25.4-cm diameter x 30.5-cm long) NaI(Tl) detector with a 20.3-cm deep axial well in which is placed a 300-mm2 x 1.0-mm Si detector. The spectra from the NaI(Tl) detector are collected both in the singles mode and in coincidence with the B-events detected in the Si detector. Ideally, this detector would sum all the energy of the B- rays in each cascade following the population of daughter level by B- decay, so that the event could be directly associated with a particular daughter level. However, there are losses of energy from attenuation of the rays before they reach the detector, transmission of rays through the detector, escape of secondary photons from Compton scattering, escape of rays through the detector well, internal con