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Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Determination of Boron in Coal Using Closed-Vessel Microwave Digestion and Inductively Coupled Plasma Mass Spectrometry (ICP-MS)  

Science Journals Connector (OSTI)

Previous studies indicate that boron in coal has been mostly determined by atomic emission spectroscopy (AES) or inductively coupled plasma–atomic emission spectrometry (ICP-AES). ... The results (Figure 1) indicated that a 2% ammonia solution can effectively eliminate the boron memory effect and reduce boron signals to blank levels (within 120 s), similar to analytical results obtained by Al-Ammar et al.(54) and Huang et al.(55) The boron memory effect is not attributed to the skimmer, sampler, or other mass spectrometer components, but originates from the tendency of boron to volatilize as boric acid from the sample solution that covers the inside surface of the ICP-MS spray chamber. ... Using different online additions of internal standard solutions, the observed boron concentrations based on the 10B and 11B spectral lines are close to each other, indicating that the observed boron concentrations based on the two isotope spectral lines are both suitable for determination of boron in coal. ...

Shifeng Dai; Weijiao Song; Lei Zhao; Xiao Li; James C. Hower; Colin R. Ward; Peipei Wang; Tian Li; Xin Zheng; Vladimir V. Seredin; Panpan Xie; Qingqian Li

2014-06-23T23:59:59.000Z

2

Mass Spectrometer: Inductively Coupled Plasma (ICP-MS), Multi...  

NLE Websites -- All DOE Office Websites (Extended Search)

was completed in February 2011. Although no research has been performed beyond an initial exploration of the Neptune's capabilities, potential users have been contacted in both the...

3

Precise ruthenium fission product isotopic analysis using dynamic reaction cell inductively coupled plasma mass spectrometry (DRC-ICP-MS)  

SciTech Connect

99Tc is a subsurface contaminant of interest at numerous federal, industrial, and international facilities. However, as a mono-isotopic fission product, 99Tc lacks the ability to be used as a signature to differentiate between the different waste disposal pathways that could have contributed to subsurface contamination at these facilities. Ruthenium fission-product isotopes are attractive analogues for the characterization of 99Tc sources because of their direct similarity to technetium with regard to subsurface mobility, and their large fission yields and low natural background concentrations. We developed an inductively coupled plasma mass spectrometry (ICP-MS) method capable of measuring ruthenium isotopes in groundwater samples and extracts of vadose zone sediments. Samples were analyzed directly on a Perkin Elmer ELAN DRC II ICP-MS after a single pass through a 1-ml bed volume of Dowex AG 50W-X8 100-200 mesh cation exchange resin. Precise ruthenium isotopic ratio measurements were achieved using a low-flow Meinhard-type nebulizer and long sample acquisition times (150,000 ms). Relative standard deviations of triplicate replicates were maintained at less than 0.5% when the total ruthenium solution concentration was 0.1 ng/ml or higher. Further work was performed to minimize the impact caused by mass interferences using the dynamic reaction cell (DRC) with O2 as the reaction gas. The aqueous concentrations of 96Mo and 96Zr were reduced by more than 99.7% in the reaction cell prior to injection of the sample into the mass analyzer quadrupole. The DRC was used in combination with stable-mass correction to quantitatively analyze samples containing up to 2-orders of magnitude more zirconium and molybdenum than ruthenium. The analytical approach documented herein provides an efficient and cost-effective way to precisely measure ruthenium isotopes and quantitate total ruthenium (natural vs. fission-product) in aqueous matrixes.

Brown, Christopher F.; Dresel, P. Evan; Geiszler, Keith N.; Farmer, Orville T.

2006-05-09T23:59:59.000Z

4

Improving Alpha Spectrometry Energy Resolution by Ion Implantation with ICP-MS  

SciTech Connect

We report results of a novel technique using an Inductively Coupled Plasma Mass Spectrometer (ICP-MS) as a method of source preparation for alpha spectrometry. This method produced thin, contaminant free 241Am samples which yielded extraordinary energy resolution which appear to be at the lower limit of the detection technology used in this research.

Dion, Michael P.; Liezers, Martin; Farmer, Orville T.; Miller, Brian W.; Morley, Shannon M.; Barinaga, Charles J.; Eiden, Gregory C.

2015-01-01T23:59:59.000Z

5

Development of an on-line isotope dilution laser ablation inductively coupled plasma mass spectrometry (LA–ICP-MS) method for determination of boron in silicon wafers  

Science Journals Connector (OSTI)

A method has been developed based on an on-line isotope dilution technique couple with laser ablation/inductively coupled plasma mass spectrometry (LA–ICP-MS), for the determination of boron in p-type silicon wafers. The laser-ablated sample aerosol was mixed on-line with an enriched boron aerosol supplied continuously using a conventional nebulization system. Upon mixing the two aerosol streams, the isotope ratio of boron changed rapidly and was then recorded by the ICP-MS system for subsequent quantification based on the isotope dilution principle. As an on-line solid analysis method, this system accurately quantifies boron concentrations in silicon wafers without the need for an internal or external solid reference standard material. Using this on-line isotope dilution technique, the limit of detection for boron in silicon wafers is 2.8 × 1015 atoms cm?3. The analytical results obtained using this on-line methodology agree well with those obtained using wet chemical digestion methods for the analysis of p-type silicon wafers containing boron concentrations ranging from 1.0 × 1016 to 9.6 × 1018 atoms cm?3.

Chao-Kai Yang; Po-Hsiang Chi; Yong-Chine Lin; Yuh-Chang Sun; Mo-Hsiung Yang

2010-01-01T23:59:59.000Z

6

Measurement of elemental speciation by liquid chromatography -- inductively coupled plasma mass spectrometry (LC-ICP-MS) with the direct injection nebulizer (DIN)  

SciTech Connect

This thesis is divided into 4 parts: elemental speciation, speciation of mercury and lead compounds by microbore column LC-ICP-MS with direct injection nebulization, spatially resolved measurements of size and velocity distributions of aerosol droplets from a direct injection nebulizer, and elemental speciation by anion exchange and size exclusion chromatography with detection by ICP-MS with direct injection nebulization. Tabs, figs, refs.

Shum, S.

1993-05-01T23:59:59.000Z

7

Reduction of polyatomic interferences in ICP-MS by collision/reaction cell (CRC-ICP-MS) techniques  

SciTech Connect

Polyatomic and other spectral interferences in plasma source mass spectrometry (PSMS) can be dramatically reduced using collision and reaction cells (CRC). These devices have been used for decades in fundamental studies of ion-molecule chemistry, but have only recently been applied to PSMS. Benefits of this approach as applied in inductively coupled plasma MS (ICP-MS) include interference reduction, isobar separation, and thermalization/focusing of ions. Novel ion-molecule chemistry schemes are now routinely designed and empirically evaluated with relative ease. These “chemical resolution” techniques can avert interferences requiring mass spectral resolutions of >600,000 (m/?m). Purely physical ion beam processes, including collisional dampening and collisional dissociation, are also employed to provide improved sensitivity, resolution, and spectral simplicity. CRC techniques are now firmly entrenched in current-day ICP-MS technology, enabling unprecedented flexibility and freedom from many spectral interferences. A significant body of applications has now been reported in the literature. CRC techniques are found to be most useful for specialized or difficult analytical needs and situations, and are employed in both single- and multi-element determination modes.

Eiden, Greg C.; Barinaga, Charles J.; Koppenaal, David W.

2012-05-01T23:59:59.000Z

8

EMSL - Mass Spectrometer  

NLE Websites -- All DOE Office Websites (Extended Search)

mass-spectrometer en Physical Properties of Ambient and Laboratory-Generated Secondary Organic Aerosol. http:www.emsl.pnl.govemslwebpublicationsphysical-properties-ambient-and...

9

Evaluation of Ultra-Low Background Materials for Uranium and Thorium Using ICP-MS  

SciTech Connect

An increasing number of physics experiments require low background materials for their construction. The presence of Uranium and Thorium and their progeny in these materials present a variety of unwanted background sources for these experiments. The sensitivity of the experiments continues to drive the necessary levels of detection ever lower as well. This requirement for greater sensitivity has rendered direct radioassay impractical in many cases requiring large quantities of material, frequently many kilograms, and prolonged counting times, often months. Other assay techniques have been employed such as Neutron Activation Analysis but this requires access to expensive facilities and instrumentation and can be further complicated and delayed by the formation of unwanted radionuclides. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) is a useful tool and recent advancements have increased the sensitivity particularly in the elemental high mass range of U and Th. Unlike direct radioassay, ICP-MS is a destructive technique since it requires the sample to be in liquid form which is aspirated into a high temperature plasma. But it benefits in that it usually requires a very small sample, typically about a gram. Here we will discuss how a variety of low background materials such as copper, polymers, and fused silica are made amenable to ICP-MS assay and how the arduous task of maintaining low backgrounds of U and Th is achieved.

Hoppe, Eric W.; Overman, Nicole R.; LaFerriere, Brian D.

2013-08-08T23:59:59.000Z

10

Uncertainty Measurement for Trace Element Analysis of Uranium and Plutonium Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS)  

SciTech Connect

The measurement uncertainty estimatino associated with trace element analysis of impurities in U and Pu was evaluated using the Guide to the Expression of Uncertainty Measurement (GUM). I this evalution the uncertainty sources were identified and standard uncertainties for the components were categorized as either Type A or B. The combined standard uncertainty was calculated and a coverage factor k = 2 was applied to obtain the expanded uncertainty, U. The ICP-AES and ICP-MS methods used were deveoped for the multi-element analysis of U and Pu samples. A typical analytical run consists of standards, process blanks, samples, matrix spiked samples, post digestion spiked samples and independent calibration verification standards. The uncertainty estimation was performed on U and Pu samples that have been analyzed previously as part of the U and Pu Sample Exchange Programs. Control chart results and data from the U and Pu metal exchange programs were combined with the GUM into a concentration dependent estimate of the expanded uncertainty. Comparison of trace element uncertainties obtained using this model was compared to those obtained for trace element results as part of the Exchange programs. This process was completed for all trace elements that were determined to be above the detection limit for the U and Pu samples.

Gallimore, David L. [Los Alamos National Laboratory

2012-06-13T23:59:59.000Z

11

ARSENIC INCORPORATION IN COLEMANITE FROM BORATE DEPOSITS: DATA FROM ICP–MS, ?-SXRF, XAFS AND EPR ANALYSES  

Science Journals Connector (OSTI)

...calculated A(75As)/h constant of ~2240 MHz along the b axis (Fig. 9) is significantly...scorodite from sulfate solutions under atmosphericpressure conditions. Metall. Mater. Trans...on sulfarsenides. Inductively coupled plasma-mass spectrometry (ICP-MS) analysis...

Jinru Lin; Yuanming Pan; Ning Chen; Mao Mao; Rong Li; Renfei Feng

12

Rapid scanning mass spectrometer  

SciTech Connect

Mass spectrometers and residual gas analyzers (RGA) are used in a variety of applications for analysis of volatile and semi-volatile materials. Analysis is performed by detecting fragments of gas molecules, based on their mass to charge ratio, which are generated in the mass spectrometer. When used as a detector for a gas chromatograph, they function as a means to quantitatively identify isolated volatile species which have been separated from other species via the gas chromatograph. Vacuum Technology, Inc., (VTI) produces a magnetic sector mass spectrometer/RGA which is used in many industrial and laboratory environments. In order to increase the utility of this instrument, it is desirable to increase the mass scanning speed, thereby increasing the number of applications for which it is suited. This project performed the following three upgrades on the computer interface. (1) A new electrometer was designed and built to process the signal from the detector. This new electrometer is more sensitive, over 10 times faster, and over 100 times more stable than the electrometer it will replace. (2) The controller EPROM was reprogrammed with new firmware. This firmware acts as an operating system for the interface and is used to shuttle communications between the PC and the AEROVAC mass spectrometer. (3) The voltage regulator which causes the ion selector voltage to ramp to allow ions of selected mass to be sequentially detected was redesigned and prototyped. The redesigned voltage regulator can be ramped up or down more than 100 times faster than the existing regulator. These changes were incorporated into a prototype unit and preliminary performance testing conducted. Results indicated that scanning speed was significantly increased over the unmodified version.

Leckey, J.H. [Lockheed Martin Energy Systems, Inc., Oak Ridge, TN (United States); Boeckmann, M.D. [Vacuum Technology, Inc., Oak Ridge, TN (United States)

1996-11-25T23:59:59.000Z

13

Boston University User Fee Structure for ICP-ES, ICP-MS and Laser Labs  

E-Print Network (OSTI)

Boston University User Fee Structure for ICP-ES, ICP-MS and Laser Labs The Department of Earth for digestions protocols include flux fusions, microwave digestions, and open vial digestions. Standardization come to BU and digest their samples in our labs with sufficient training. Laser-ICP-MS cost per sample

Hutyra, Lucy R.

14

Validation of Electrochemically Modulated Separations Performed On-Line with MC-ICP-MS for Uranium and Plutonium Isotopic Analyses  

SciTech Connect

The most time consuming process in uranium or plutonium isotopic analyses is performing the requisite chromatographic separation of the actinides. Filament preparation for thermal ionization (TIMS) adds further delays, but is generally accepted due to the unmatched performance in trace isotopic analyses. Advances in Multi-Collector Inductively Coupled Plasma Mass Spectrometry (MC-ICP-MS) are beginning to rival the performance of TIMS. Methods, such as Electrochemically Modulated Separations (EMS) can efficiently pre-concentrate U or Pu quite selectively from small solution volumes in a matrix of 0.5 M nitric acid. When performed in-line with ICP-MS, the rapid analyte release from the electrode is fast, and large transient analyte signal enhancements of >100 fold can be achieved as compared to more conventional continuous nebulization of the original starting solution. This makes the approach ideal for very low level isotope ratio measurements. In this paper, some aspects of EMS performance are described. These include low level Pu isotope ratio behavior versus concentration by MC-ICP-MS and uranium rejection characteristics that are also important for reliable low level Pu isotope ratio determinations.

Liezers, Martin; Olsen, Khris B.; Mitroshkov, Alexandre V.; Duckworth, Douglas C.

2010-08-11T23:59:59.000Z

15

Mini ion trap mass spectrometer  

DOE Patents (OSTI)

An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

Dietrich, D.D.; Keville, R.F.

1995-09-19T23:59:59.000Z

16

Mini ion trap mass spectrometer  

DOE Patents (OSTI)

An ion trap which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10.sup.9 and commercial mass spectrometers requiring 10.sup.4 ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products.

Dietrich, Daniel D. (Livermore, CA); Keville, Robert F. (Valley Springs, CA)

1995-01-01T23:59:59.000Z

17

Mass Spectrometer: Orbitrap | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Software (ISIS): A Machine Learning Approach to Tandem Mass Spectral Identification of Lipids. Liquid chromatography-mass spectrometry-based metabolomics has gained importance...

18

Glass particles produced by laser ablation for ICP-MS measurements  

E-Print Network (OSTI)

Glass particles produced by laser ablation for ICP-MS266nm) was used to generate glass particles from two sets ofWhen the current data on glass were compared with the metal

Gonzalez, J.; Liu, C.; Wen, S.; Mao, X.; Russo, R.E.

2008-01-01T23:59:59.000Z

19

Advanced Mass Spectrometers for Hydrogen Isotope Analyses  

SciTech Connect

This report is a summary of the results of a joint Savannah River Laboratory (SRL) - Savannah River Plant (SRP) ''Hydrogen Isotope Mass Spectrometer Evaluation Program''. The program was undertaken to evaluate two prototype hydrogen isotope mass spectrometers and obtain sufficient data to permit SRP personnel to specify the mass spectrometers to replace obsolete instruments.

Chastagner, P.

2001-08-01T23:59:59.000Z

20

Measurement of lithium isotope ratios by quadrupole-ICP-MS: application to seawater and natural carbonates  

E-Print Network (OSTI)

Measurement of lithium isotope ratios by quadrupole-ICP-MS: application to seawater and natural method for lithium isotope ratio (7 Li/6 Li) determinations with low total lithium consumption ( lithium from all matrix elements using small volume resin (2 ml/3.4 meq AG 50W-X8) and low volume elution

Weston, Ken

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Compact time-of-flight mass spectrometer  

SciTech Connect

This paper describes a time-of-flight mass spectrometer developed for measuring the parameters of a pulsed hydrogen beam. The duration of an electron-beam current pulse in the ionizer of the mass spectrometer can be varied within 2-20 usec, the pulse electron current is 0.6 mA, and the electron energy is 250 eV. The time resolution of the mass spectrometer is determined by the repetition period of the electron-beam current pulses and is 40 usec. The mass spectrometer has 100% transmission in the direction of motion of molecular-beam particles. The dimension of the mass spectrometer is 7 cm in this direction. The mass resolution is sufficient for determination of the composition of the hydrogen beam.

Belov, A.S.; Kubalov, S.A.; Kuzik, V.F.; Yakushev, V.P.

1986-02-01T23:59:59.000Z

22

Time of Flight Secondary Ion (TOF SIMS) Mass Spectrometer | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

(TOF SIMS) Mass Spectrometer Time of Flight Secondary Ion (TOF SIMS) Mass Spectrometer The Physical Electronics Instruments (PHI) Model T2100 time-of-flight secondary ion mass...

23

Analysis of IAEA environmental samples for plutonium and uranium by ICP/MS in support of international safeguards  

Science Journals Connector (OSTI)

A method for the separation and determination of total and isotopic uranium and plutonium by ICP/MS was developed for IAEA samples on cellulose-based media. Preparation of the IAEA samples involved a series of...

O. T. Farmer III; K. B. Olsen; M. L. Thomas…

2008-05-01T23:59:59.000Z

24

Multidetector calibration for mass spectrometers  

SciTech Connect

The International Atomic Energy Agency`s Safeguards Analytical Laboratory has performed calibration experiments to measure the different efficiencies among multi-Faraday detectors for a Finnigan-MAT 261 mass spectrometer. Two types of calibration experiments were performed: (1) peak-shift experiments and (2) peak-jump experiments. For peak-shift experiments, the ion intensities were measured for all isotopes of an element in different Faraday detectors. Repeated measurements were made by shifting the isotopes to various Faraday detectors. Two different peak-shifting schemes were used to measure plutonium (UK Pu5/92138) samples. For peak-jump experiments, ion intensities were measured in a reference Faraday detector for a single isotope and compared with those measured in the other Faraday detectors. Repeated measurements were made by switching back-and-forth between the reference Faraday detector and a selected Faraday detector. This switching procedure is repeated for all Faraday detectors. Peak-jump experiments were performed with replicate measurements of {sup 239}Pu, {sup 187}Re, and {sup 238}U. Detector efficiency factors were estimated for both peak-jump and peak-shift experiments using a flexible calibration model to statistically analyze both types of multidetector calibration experiments. Calculated detector efficiency factors were shown to depend on both the material analyzed and the experimental conditions. A single detector efficiency factor is not recommended for each detector that would be used to correct routine sample analyses. An alternative three-run peak-shift sample analysis should be considered. A statistical analysis of the data from this peak-shift experiment can adjust the isotopic ratio estimates for detector differences due to each sample analysis.

Bayne, C.K. [Oak Ridge National Lab., TN (United States); Donohue, D.L.; Fiedler, R. [IAEA, Seibersdorf (Austria). Safeguards Analytical Lab.

1994-06-01T23:59:59.000Z

25

Development and performance of a miniature, low cost mass spectrometer  

E-Print Network (OSTI)

A miniature, low cost mass spectrometer has been developed that is capable of unit resolution over a mass range of 10 to 50 AMU. The design of the mass spectrometer incorporates several new features that enhance the ...

Hemond, Brian D. (Brian David Thomson)

2011-01-01T23:59:59.000Z

26

Interface for liquid chromatograph-mass spectrometer  

DOE Patents (OSTI)

A moving belt interface for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer.

Andresen, Brian D. (Pleasanton, CA); Fought, Eric R. (Livermore, CA)

1989-01-01T23:59:59.000Z

27

Interface for liquid chromatograph-mass spectrometer  

DOE Patents (OSTI)

A moving belt interface is described for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer. 8 figs.

Andresen, B.D.; Fought, E.R.

1989-09-19T23:59:59.000Z

28

Portable gas chromatograph-mass spectrometer  

SciTech Connect

A gas chromatograph-mass spectrometer (GC-MS) for use as a field portable organic chemical analysis instrument. The GC-MS is designed to be contained in a standard size suitcase, weighs less than 70 pounds, and requires less than 600 watts of electrical power at peak power (all systems on). The GC-MS includes: a conduction heated, forced air cooled small bore capillary gas chromatograph, a small injector assembly, a self-contained ion/sorption pump vacuum system, a hydrogen supply, a dual computer system used to control the hardware and acquire spectrum data, and operational software used to control the pumping system and the gas chromatograph. This instrument incorporates a modified commercial quadrupole mass spectrometer to achieve the instrument sensitivity and mass resolution characteristic of laboratory bench top units.

Andresen, B.D.; Eckels, J.D.; Kimmins, J.F.; Myers, D.W.

1994-12-31T23:59:59.000Z

29

Portable gas chromatograph-mass spectrometer  

DOE Patents (OSTI)

A gas chromatograph-mass spectrometer (GC-MS) for use as a field portable organic chemical analysis instrument. The GC-MS is designed to be contained in a standard size suitcase, weighs less than 70 pounds, and requires less than 600 watts of electrical power at peak power (all systems on). The GC-MS includes: a conduction heated, forced air cooled small bore capillary gas chromatograph, a small injector assembly, a self-contained ion/sorption pump vacuum system, a hydrogen supply, a dual computer system used to control the hardware and acquire spectrum data, and operational software used to control the pumping system and the gas chromatograph. This instrument incorporates a modified commercial quadrupole mass spectrometer to achieve the instrument sensitivity and mass resolution characteristic of laboratory bench top units.

Andresen, Brian D. (Livermore, CA); Eckels, Joel D. (Livermore, CA); Kimmons, James F. (Manteca, CA); Myers, David W. (Livermore, CA)

1996-01-01T23:59:59.000Z

30

Portable gas chromatograph-mass spectrometer  

DOE Patents (OSTI)

A gas chromatograph-mass spectrometer (GC-MS) is described for use as a field portable organic chemical analysis instrument. The GC-MS is designed to be contained in a standard size suitcase, weighs less than 70 pounds, and requires less than 600 watts of electrical power at peak power (all systems on). The GC-MS includes: a conduction heated, forced air cooled small bore capillary gas chromatograph, a small injector assembly, a self-contained ion/sorption pump vacuum system, a hydrogen supply, a dual computer system used to control the hardware and acquire spectrum data, and operational software used to control the pumping system and the gas chromatograph. This instrument incorporates a modified commercial quadrupole mass spectrometer to achieve the instrument sensitivity and mass resolution characteristic of laboratory bench top units. 4 figs.

Andresen, B.D.; Eckels, J.D.; Kimmons, J.F.; Myers, D.W.

1996-06-11T23:59:59.000Z

31

An automated hydride generation-cryogenic trapping-ICP-MS system for measuring inorganic and methylated Ge, Sb and As species  

E-Print Network (OSTI)

An automated hydride generation-cryogenic trapping-ICP-MS system for measuring inorganic of both flow injection and batch hydride generation and couples it to an automated cryogenic trapping unit with detection by ICP-MS. The Teflon cryogenic trap was packed with 10 cm of SE-30 5% Chromosorb W-HP 80­100 mesh

Canberra, University of

32

Continuum flow sampling mass spectrometer for elemental analysis with an inductively coupled plasma ion source  

SciTech Connect

The sampling of ions from an atmospheric pressure inductively coupled plasma for mass spectrometry (ICP-MS) with a supersonic nozzle and skimmer is shown to follow similar behavior found for neutral beam studies and for ion extraction from other plasmas and flames. In particular, highest ion beam intensity is found if the skimmer tip is close to the Mach disk and at a calculated skimming Knudsen number close to the recommended value of 1. Our ICP-MS instrument with an off-axis detector and conventional cylindrical electrostatic ion focusing in the transition flow regime gives intense count rates of 1 to 5 MHz per mg L/sup -1/ of analyte superimposed on a background of 1 to 10 kHz. The dependence of count rates for metal oxide and doubly charged ions on ICP operating parameters, and sampling interface configuration are discussed for this instrument. A simple method is described for the approximate measurement of the ion energy distribution in ICP-MS. The average ion kinetic energy, kinetic energy spread, and maximum kinetic energy are evaluated from a plot of ion signal as a function of retarding voltage applied to the quadrupole mass analyzer. The effects of plasma operating parameters on ion signals and energies are described. In particular, kinetic energy is a sensitive function of aerosol gas flow rate. This behavior is attributed to a non-thermal, possibly electrical, interaction between the plasma and the sampling interface, which is induced by the presence of the axial channel in the ICP. The interference on the ionization of cobalt by five salts, NaCl, MgCl/sub 2/, NH/sub 4/I, NH/sub 4/Br and NH/sub 4/Cl, in an ICP is first considered theoretically and subsequently the theoretical trends are established experimentally by ICP-MS. The interference trends are found to be in the order of the most easily ionized element in the matrix salt, i.e., Na > Mg > I > Br > Cl.

Olivares, J.A.

1985-06-01T23:59:59.000Z

33

Linear Electric Field Time-Of-Flight Ion Mass Spectrometers  

NLE Websites -- All DOE Office Websites (Extended Search)

Linear Electric Field Time-Of-Flight Ion Mass Spectrometers Linear Electric Field Time-Of-Flight Ion Mass Spectrometers Linear Electric Field Time-Of-Flight Ion Mass Spectrometers Time-of-flight mass spectrometer comprising a first drift region and a second drift region enclosed within an evacuation chamber. Available for thumbnail of Feynman Center (505) 665-9090 Email Linear Electric Field Time-Of-Flight Ion Mass Spectrometers Time-of-flight mass spectrometer comprising a first drift region and a second drift region enclosed within an evacuation chamber; a means of introducing an analyte of interest into the first drift region; a pulsed ionization source which produces molecular ions from said analyte of interest; a first foil positioned between the first drift region and the second drift region, which dissociates said molecular ions into constituent

34

REPORT OF THE INDUCTIVELY COUPLED PLASMA -MASS SPECTROMETRY (ICP-MS)  

E-Print Network (OSTI)

) to be conducted. All fumes are neutralized via a water-based scrubber before being vented to the atmosphere Hydride Generator (Fig. 7) 1 IBM Computer with 17" Monitor 1 Eletrothermal Vaporization Unit (Mark IIIa at a cost of $27,225. Ultrapure water is supplied by a Barnstead-Thermolyne Nanopure water system which

35

Mass spectrometer vacuum housing and pumping system  

DOE Patents (OSTI)

A vacuum housing and pumping system for a portable gas chromatograph/mass spectrometer (GC/MS). The vacuum housing section of the system has minimum weight for portability while designed and constructed to utilize metal gasket sealed stainless steel to be compatible with high vacuum operation. The vacuum pumping section of the system consists of a sorption (getter) pump to remove atmospheric leakage and outgassing contaminants as well as the gas chromatograph carrier gas (hydrogen) and an ion pump to remove the argon from atmospheric leaks. The overall GC/MS system has broad application to contaminants, hazardous materials, illegal drugs, pollution monitoring, etc., as well as for use by chemical weapon treaty verification teams, due to the light weight and portability thereof.

Coutts, Gerald W. (Livermore, CA); Bushman, John F. (Oakley, CA); Alger, Terry W. (Tracy, CA)

1996-01-01T23:59:59.000Z

36

Mass spectrometer vacuum housing and pumping system  

DOE Patents (OSTI)

A vacuum housing and pumping system is described for a portable gas chromatograph/mass spectrometer (GC/MS). The vacuum housing section of the system has minimum weight for portability while designed and constructed to utilize metal gasket sealed stainless steel to be compatible with high vacuum operation. The vacuum pumping section of the system consists of a sorption (getter) pump to remove atmospheric leakage and outgassing contaminants as well as the gas chromatograph carrier gas (hydrogen) and an ion pump to remove the argon from atmospheric leaks. The overall GC/MS system has broad application to contaminants, hazardous materials, illegal drugs, pollution monitoring, etc., as well as for use by chemical weapon treaty verification teams, due to the light weight and portability thereof. 7 figs.

Coutts, G.W.; Bushman, J.F.; Alger, T.W.

1996-07-23T23:59:59.000Z

37

In situ LA–MC–ICP–MS boron isotope and zircon U–Pb age determinations of Paleoproterozoic borate deposits in Liaoning Province, northeastern China  

Science Journals Connector (OSTI)

Abstract A large number of Paleoproterozoic borate deposits are hosted by the lower units of a volcanic-sedimentary sequence in Liaoning Province, northeastern China, and are a major source of boron in China. The ore-bearing wall rocks in the deposits are serpentinized ultrabasic rocks and carbonates, with layered leptynites, leptites, amphibolites, and migmatites adjacent to the ore. Both the borate ores and country rocks contain tourmaline, although the country rocks have much lower abundances of the mineral. Based on in situ boron isotope measurements using laser ablation–multi-collector–inductively coupled plasma–mass spectrometry (LA–MC–ICP–MS), boron isotope data show that: (1) ?11B values of borate ores range from + 6.8‰ to + 13.9‰ (mean + 10.8‰); (2) tourmalines from the borate ores have ?11B values from + 9.5‰ to + 12.7‰; and (3) the wall rocks within the borate ores yield slightly lower ?11B values ranging from + 5.7‰ to + 7.6‰, and those outside the deposits from ? 9.9‰ to ? 5.9‰. Positive ?11B values in borates as well as in tourmalines inside the mining area indicate that boron in these Paleoproterozoic borate deposits was derived from marine evaporites. ?34SV-CDT (where V-CDT is Vienna Canyon Diablo Troilite) values of borate ores, serpentinized marbles, and anhydrites range from + 16.1‰ to + 24.7‰, whereas ?13CV-PDB (where V-PDB is Vienna Pee Dee Belemnite) values of marbles range from + 3.2‰ to + 5.9‰. These isotopic characteristics are interpreted to reflect formation in a marine evaporative environment. LA–MC–ICP–MS zircon weighted207Pb/206Pb ages of leptite and serpentinized olivine basalt from the hanging wall of the borate deposits are 2139 ± 13 Ma and 2130 ± 19 Ma, respectively. Therefore, the (~ 2.2 Ga) borate deposits may have originated from marine evaporative boron-bearing sediments, which were interbedded within bimodal volcanic rocks during the early stages of development of the Liaoji rift.

Guyue Hu; Yanhe Li; Changfu Fan; Kejun Hou; Yue Zhao; Lingsen Zeng

2014-01-01T23:59:59.000Z

38

Mass spectrometer having a derivatized sample presentation apparatus  

DOE Patents (OSTI)

A mass spectrometer having a derivatized sample presentation apparatus is provided. The sample presentation apparatus has a complex bound to the surface of the sample presentation apparatus. This complex includes a molecule which may chemically modify a biomolecule.

Nelson, Randall W. (Phoenix, AZ)

2000-07-25T23:59:59.000Z

39

Single-ultrafine-particle mass spectrometer development and application  

E-Print Network (OSTI)

SINGLE-ULTRAFINE-PARTICLE MASS SPECTROMETER DEVELOPMENT AND APPLICATION A Thesis by STANISLAV Y. GLAGOLENKO Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 2004 Major Subject: Mechanical Engineering SINGLE-ULTRAFINE-PARTICLE MASS SPECTROMETER DEVELOPMENT AND APPLICATION A Thesis by STANISLAV Y. GLAGOLENKO Submitted to Texas A&M University in partial...

Glagolenko, Stanislav Yurievich

2004-11-15T23:59:59.000Z

40

Electron source for a mini ion trap mass spectrometer  

DOE Patents (OSTI)

An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

Dietrich, D.D.; Keville, R.F.

1995-12-19T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Electron source for a mini ion trap mass spectrometer  

DOE Patents (OSTI)

An ion trap which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10.sup.9 and commercial mass spectrometers requiring 10.sup.4 ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products.

Dietrich, Daniel D. (Livermore, CA); Keville, Robert F. (Valley Springs, CA)

1995-01-01T23:59:59.000Z

42

Quantitative 3-D Elemental Mapping by LA-ICP-MS of a Basaltic Clast from the Hanford 300 Area, Washington, USA  

E-Print Network (OSTI)

Quantitative 3-D Elemental Mapping by LA-ICP-MS of a Basaltic Clast from the Hanford 300 Area collected from the Hanford 300 Area in south-central Washington State, United States. A calibration method and riparian quality in many locations, most notably at the Hanford, Savannah River, Oak Ridge, and Nevada Test

Hu, Qinhong "Max"

43

Compact mass spectrometer for plasma discharge ion analysis  

DOE Patents (OSTI)

A mass spectrometer and methods for mass spectrometry which are useful in characterizing a plasma. This mass spectrometer for determining type and quantity of ions present in a plasma is simple, compact, and inexpensive. It accomplishes mass analysis in a single step, rather than the usual two-step process comprised of ion extraction followed by mass filtering. Ions are captured by a measuring element placed in a plasma and accelerated by a known applied voltage. Captured ions are bent into near-circular orbits by a magnetic field such that they strike a collector, producing an electric current. Ion orbits vary with applied voltage and proton mass ratio of the ions, so that ion species may be identified. Current flow provides an indication of quantity of ions striking the collector.

Tuszewski, Michel G. (Los Alamos, NM)

1997-01-01T23:59:59.000Z

44

Compact mass spectrometer for plasma discharge ion analysis  

DOE Patents (OSTI)

A mass spectrometer and methods are disclosed for mass spectrometry which are useful in characterizing a plasma. This mass spectrometer for determining type and quantity of ions present in a plasma is simple, compact, and inexpensive. It accomplishes mass analysis in a single step, rather than the usual two-step process comprised of ion extraction followed by mass filtering. Ions are captured by a measuring element placed in a plasma and accelerated by a known applied voltage. Captured ions are bent into near-circular orbits by a magnetic field such that they strike a collector, producing an electric current. Ion orbits vary with applied voltage and proton mass ratio of the ions, so that ion species may be identified. Current flow provides an indication of quantity of ions striking the collector. 7 figs.

Tuszewski, M.G.

1997-07-22T23:59:59.000Z

45

Micro mass spectrometer on a chip.  

SciTech Connect

The design, simulation, fabrication, packaging, electrical characterization and testing analysis of a microfabricated a cylindrical ion trap ({mu}CIT) array is presented. Several versions of microfabricated cylindrical ion traps were designed and fabricated. The final design of the individual trap array element consisted of two end cap electrodes, one ring electrode, and a detector plate, fabricated in seven tungsten metal layers by molding tungsten around silicon dioxide (SiO{sub 2}) features. Each layer of tungsten is then polished back in damascene fashion. The SiO{sub 2} was removed using a standard release processes to realize a free-hung structure. Five different sized traps were fabricated with inner radii of 1, 1.5, 2, 5 and 10 {micro}m and heights ranging from 3-24 {micro}m. Simulations examined the effects of ion and neutral temperature, the pressure and nature of cooling gas, ion mass, trap voltage and frequency, space-charge, fabrication defects, and other parameters on the ability of micrometer-sized traps to store ions. The electrical characteristics of the ion trap arrays were determined. The capacitance was 2-500 pF for the various sized traps and arrays. The resistance was in the order of 1-2 {Omega}. The inductance of the arrays was calculated to be 10-1500 pH, depending on the trap and array sizes. The ion traps' field emission characteristics were assessed. It was determined that the traps could be operated up to 125 V while maintaining field emission currents below 1 x 10{sup -15} A. The testing focused on using the 5-{micro}m CITs to trap toluene (C{sub 7}H{sub 8}). Ion ejection from the traps was induced by termination of the RF voltage applied to the ring electrode and current measured on the collector electrode suggested trapping of ions in 1-10% of the traps. Improvements to the to the design of the traps were defined to minimize voltage drop to the substrate, thereby increasing trapping voltage applied to the ring electrode, and to allow for electron injection into, ion ejection from, and optical access to the trapping region.

Cruz, Dolores Y.; Blain, Matthew Glenn; Fleming, James Grant

2005-11-01T23:59:59.000Z

46

Determination of boron isotope compositions of geological materials by laser ablation MC-ICP-MS using newly designed high sensitivity skimmer and sample cones  

Science Journals Connector (OSTI)

Abstract The effects of addition of nitrogen gas with use of three different combinations of sample and skimmer cones on the performance of LA-MC-ICP-MS for in situ B isotope ratio measurements were investigated in detail. Compared to the standard arrangement (H skimmer cone + standard sample cone), sensitivities of B isotopes were improved by a factor of 2.4 and 3.8 with use of X skimmer cone + standard sampler cone and the X skimmer cone + Jet sample cone, respectively. The best within-run precision (2 s) of 11B/10B was approximately 50 ppm for B4 reference material (B content = 31,400 ?g/g) with use of X skimmer cone + Jet sample cone. It was found that different cone combinations had significant effects on the instrument mass bias, but had little effect on the precisions of B isotope ratios. Addition of nitrogen (2–4 ml/min) in the central channel gas did not improve the sensitivity of B. However, significant wider ion axial distribution profile and more stable mass-bias for B isotope ratios were evident. Under selected optimum conditions, good agreements between the measured ?11B values and the reference values were obtained for the international reference minerals (B4, Dravite, Elbaite, IMMRB1 and Schorl), the NIST SRM 610–612 synthetic soda-lime glasses and the MPI-DING glasses (GOR-128-G, GOR-132-G, and StHs6/80). It was found that for low-B containing (11 ppm and 31 ppm) materials, the precisions (2 s) of 11B/10B can be improved by a factor of 2–10 by using the newly designed X-skimmer cone and Jet sample cone, compared to that of using the standard cones. The international reference mineral Danburite (?11B of ? 14.92 ± 6.77 2SD, n = 32) showed a significant non-uniformity of B isotope ratio distribution. Our first boron isotopic results from standards GSD-1G (?11B: 11.92 ± 1.03, n = 30), GSE-1G (?11B: 1.63 ± 0.32, n = 30), GP-4 (?11B: ? 5.85 ± 1.01, n = 40) and DD-1 (?11B: ? 13.21 ± 0.56, n = 35) showed these materials were fairly homogeneous in boron isotope ratios, making them as good candidates as reference materials. The proposed LA-MC-ICPMS method is suitable for the direct determination of B isotope ratio in a variety of geological materials.

Lin Lin; Zhaochu Hu; Lu Yang; Wen Zhang; Yongsheng Liu; Shan Gao; Shenghong Hu

2014-01-01T23:59:59.000Z

47

Mass Spectrometer: FT-ICR, 6T (Ion Surface Collisions) | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

Mass Spectrometer: FT-ICR, 6T (Ion Surface Collisions) The 6-Tesla High-Field Fourier Transform Ion Cyclotron Resonance Mass Spectrometer (FT-ICR MS), is a unique instrument...

48

Miniature quadrupole mass spectrometer having a cold cathode ionization source  

DOE Patents (OSTI)

An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

Felter, Thomas E. (Livermore, CA)

2002-01-01T23:59:59.000Z

49

Laser Ablation Inductively Coupled Plasma Mass Spectrometry Measurement of Isotope Ratios in Depleted Uranium Contaminated Soils  

Science Journals Connector (OSTI)

Laser ablation of pressed soil pellets was examined as a means of direct sample introduction to enable inductively coupled plasma mass spectrometry (ICP-MS) screening of soils for...

Seltzer, Michael D

2003-01-01T23:59:59.000Z

50

Determination of Depleted Uranium in Urine via Isotope Ratio Measurements Using Large-Bore Direct Injection High Efficiency Nebulizer–Inductively Coupled Plasma Mass Spectrometry  

Science Journals Connector (OSTI)

Inductively coupled plasma mass spectrometry (ICP-MS), coupled with a large-bore direct injection high efficiency nebulizer (LB-DIHEN), was utilized to determine the concentration and...

Westphal, Craig S; McLean, John A; Hakspiel, Shelly J; Jackson, William E; McClain, David E; Montaser, Akbar

2004-01-01T23:59:59.000Z

51

Novel endothermic and exothermic ion-molecule reactions as observed in a Fourier transform mass spectrometer  

E-Print Network (OSTI)

NOVEL ENDOTHERMIC AND EXOTHERMIC ION-MOLECULE REACTIONS AS OBSERVED IN A FOURIER TRANSFORM MASS SPECTROMETER Thesis by DONALD LEE BRICKER II Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE AUGUST 1986 Major Subject: Chemistry NOVEL ENDOTHERMIC AND EXOTHERMIC ION-MOLECULE REACTIONS AS OBSERVED IN A FOURIER TRANSFORM MASS SPECTROMETER A Thesis by Donald Lee Bricker II Approved as to style and content by...

Bricker, Donald Lee

1986-01-01T23:59:59.000Z

52

ICP-MS (Quadrupole) | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

371-6375 wietsma@pnnl.gov Publications Deposition of Platinum Nanoparticles on Carbon Nanotubes by Supercritical Fluid Method. Carbon nanotube-supported platinum nanoparticles with...

53

Fundamental and methodological investigations for the improvement of elemental analysis by inductively coupled plasma mass soectrometry  

SciTech Connect

This dissertation describes a variety of studies meant to improve the analytical performance of inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation (LA) ICP-MS. The emission behavior of individual droplets and LA generated particles in an ICP is studied using a high-speed, high frame rate digital camera. Phenomena are observed during the ablation of silicate glass that would cause elemental fractionation during analysis by ICP-MS. Preliminary work for ICP torch developments specifically tailored for the improvement of LA sample introduction are presented. An abnormal scarcity of metal-argon polyatomic ions (MAr{sup +}) is observed during ICP-MS analysis. Evidence shows that MAr{sup +} ions are dissociated by collisions with background gas in a shockwave near the tip of the skimmer cone. Method development towards the improvement of LA-ICP-MS for environmental monitoring is described. A method is developed to trap small particles in a collodion matrix and analyze each particle individually by LA-ICP-MS.

Ebert, Christopher Hysjulien [Ames Laboratory

2012-07-27T23:59:59.000Z

54

Design and evaluation of a miniaturized Particle Desorption Mass Spectrometer  

E-Print Network (OSTI)

resolution was dependent upon both mass and sample bias. For a mass of 133 amu and sample bias of 1KV, the mass resolution (m/Am) was 130. Desorbed ions were focused by means of an electrostatic particle guide (EPG). The overall instrument transmission... amu. Since the fission process provides a primary, bombarding particle discretely in time, the temporal relationship between the desorbed, secondary ion and the primary ion can be readily ascertained, resulting in an efficient, simultaneous...

Davis, Kelly Vaughn

2012-06-07T23:59:59.000Z

55

Low mass dimuon production with the ALICE muon spectrometer.  

E-Print Network (OSTI)

??Low mass vector meson (?, ?,? ) production provides key information on the hot and dense state of strongly interacting matter produced in high-energy heavy… (more)

Casula, Ester Anna Rita

2014-01-01T23:59:59.000Z

56

Precise and accurate determination of boron isotope ratios by multiple collector ICP-MS: origin of boron in the Ngawha geothermal system, New Zealand  

Science Journals Connector (OSTI)

A new technique has been developed for the measurement of boron isotope ratios in fluids using a double focusing multiple collector inductively coupled plasma (ICP) mass spectrometer. Sample introduction using a direct injection nebuliser was found to eliminate memory problems that are common where spray chambers are involved. The 4–9% mass bias can be corrected for by bracketing sample measurements with standards. As matrices were found to affect the mass bias all samples must be purified and that sample and standard solutions must be similar. A new purification technique was developed that yields adequately purified samples. Using this technique, it is possible to make rapid measurements (4 min) from samples containing 250 ng B to a precision of ±0.2‰. This analytical technique has been applied to the Ngawha geothermal system in New Zealand in an attempt to determine the source of B in geothermal fluids where the B concentrations can exceed 100 mmol/l. The ?11B values range between ?3.1‰ and ?3.9‰ indicating that no seawater sources are involved and that the elevated B concentrations can only be accounted for by low water/rock ratios with the B being derived from basement greywacke/argillite. The similarity of B isotope ratios for hydrothermal fluids that have been diluted and cooled with groundwaters indicates that isotope fractionation due to adsorption is unlikely to occur in cool geothermal fluids (<40 °C).

J.K. Aggarwal; D. Sheppard; K. Mezger; E. Pernicka

2003-01-01T23:59:59.000Z

57

Exploring the in vitro formation of trimethylarsine sulfide from dimethylthioarsinic acid in anaerobic microflora of mouse cecum using HPLC-ICP-MS and HPLC-ESI-MS  

SciTech Connect

Although metabolism of arsenicals to form methylated oxoarsenical species has been extensively studied, less is known about the formation of thiolated arsenical species that have recently been detected as urinary metabolites. Indeed, their presence suggests that the metabolism of ingested arsenic is more complex than previously thought. Recent reports have shown that thiolated arsenicals can be produced by the anaerobic microflora of the mouse cecum, suggesting that metabolism prior to systemic absorption may be a significant determinant of the pattern and extent of exposure to various arsenic-containing species. Here, we examined the metabolism of {sup 34}S labeled dimethylthioarsinic acid ({sup 34}S-DMTA{sup V}) by the anaerobic microflora of the mouse cecum using HPLC-ICP-MS and HPLC-ESI-MS/MS to monitor for the presence of various oxo- and thioarsenicals. The use of isotopically enriched {sup 34}S-DMTA{sup V} made it possible to differentiate among potential metabolic pathways for production of the trimethylarsine sulfide (TMAS{sup V}). Upon in vitro incubation in an assay containing anaerobic microflora of mouse cecum, {sup 34}S-DMTA{sup V} underwent several transformations. Labile {sup 34}S was exchanged with more abundant {sup 32}S to produce {sup 32}S-DMTA{sup V}, a thiol group was added to yield DMDTA{sup V}, and a methyl group was added to yield {sup 34}S-TMAS{sup V}. Because incubation of {sup 34}S-DMTA{sup V} resulted in the formation of {sup 34}S-TMAS{sup V}, the pathway for its formation must preserve the arsenic-sulfur bond. The alternative metabolic pathway postulated for formation of TMAS{sup V} from dimethylarsinic acid (DMA{sup V}) would proceed via a dimethylarsinous acid (DMA{sup III}) intermediate and would necessitate the loss of {sup 34}S label. Structural confirmation of the metabolic product was achieved using HPLC-ESI-MS/MS. The data presented support the direct methylation of DMTA{sup V} to TMAS{sup V}. Additionally, the detection of isotopically pure {sup 34}S-TMAS{sup V} raises questions about the sulfur exchange properties of TMAS{sup V} in the cecum material. Therefore, {sup 34}S-TMAS{sup V} was incubated and the exchange was monitored with respect to time. The data suggest that the As-S bond associated with TMAS{sup V} is less labile than the As-S bond associated with DMTA{sup V}.

Kubachka, Kevin M. [US EPA, ORD, NERL, Microbiological and Chemical Exposure, Assessment Research Division, Cincinnati, OH 45268 (United States); Kohan, Michael C. [US EPA, ORD, NHEERL, Environmental Carcinogenesis Division, Research Triangle Park, NC 27711 (United States); Herbin-Davis, Karen [US EPA, ORD, NHEERL, Experimental Toxicology Division, Research Triangle Park, NC 27711 (United States); Creed, John T. [US EPA, ORD, NERL, Microbiological and Chemical Exposure, Assessment Research Division, Cincinnati, OH 45268 (United States)], E-mail: creed.jack@epa.gov; Thomas, David J. [US EPA, ORD, NHEERL, Experimental Toxicology Division, Research Triangle Park, NC 27711 (United States)

2009-09-01T23:59:59.000Z

58

Chemical Reaction of Metal-Carbon Binary Cluster Anions by FT-ICR Mass Spectrometer  

E-Print Network (OSTI)

45 48 51 54 57 60 Number of Carbon Atoms Intensity(arbitrary) (a) as injected (b) SWIFTed (c) NO 1sChemical Reaction of Metal-Carbon Binary Cluster Anions by FT-ICR Mass Spectrometer S. Maruyama, M- fullerene and single walled carbon nanotubes are investigated through experimental studies of interaction

Maruyama, Shigeo

59

Marketability and Feasibility of Chair-Side Gas Chromatography Mass Spectrometer for Dental Application  

E-Print Network (OSTI)

, the likelihood of dentists using the product aforementioned, cost structures of production and marketing, and keyMarketability and Feasibility of Chair-Side Gas Chromatography Mass Spectrometer for Dental metabolite signals when compared to caries-free sites. These signal profiles were determined using Gas

Zhou, Yaoqi

60

HD gas analysis with Gas Chromatography and Quadrupole Mass Spectrometer  

E-Print Network (OSTI)

A gas analyzer system has been developed to analyze Hydrogen-Deuteride (HD) gas for producing frozen-spin polarized HD targets, which are used for hadron photoproduction experiments at SPring-8. Small amounts of ortho-H$_{2}$ and para-D$_{2}$ gas mixtures ($\\sim$0.01%) in the purified HD gas are a key to realize a frozen-spin polarized target. In order to obtain reliable concentrations of these gas mixtures in the HD gas, we produced a new gas analyzer system combining two independent measurements with the gas chromatography and the QMS. The para-H$_{2}$, ortho-H$_{2}$, HD, and D$_{2}$ are separated using the retention time of the gas chromatography and the mass/charge. It is found that the new gas analyzer system can measure small concentrations of $\\sim$0.01% for the otho-H$_2$ and D$_2$ with good S/N ratios.

T. Ohta; S. Bouchigny; J. -P. Didelez; M. Fujiwara; K. Fukuda; H. Kohri; T. Kunimatsu; C. Morisaki; S. Ono; G. Rouille; M. Tanaka; K. Ueda; M. Uraki; M. Utsuro; S. Y. Wang; M. Yosoi

2011-01-28T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Development of a cold cathode ion source for a mass spectrometer type vacuum leak detector  

E-Print Network (OSTI)

DEVELOPMENT OF A COLD CATHODE ION SOURCE FOR A MASS SPECTROL'ETER TYPE VACUUM LEAK DETECTOR A Dissertation By Harold A. Thomas June 1947 Approval as to style and content recommended* Head Deparanent of Electrical Engineering DEVELOPMENT OF A... Investigation of Ion Source ? .......... 6 III. Investigation of Ion Energies ...................... 21 IV. Development of Lrass Spectrometer Tube Utilizing the Cold Cathode Ion S o u r c e ........ 41 V* Conclusions...

Thomas, Harold Albert

2013-10-04T23:59:59.000Z

62

Elimination of ``memory`` from sample handling and inlet system of a mass spectrometer  

DOE Patents (OSTI)

This paper describes a method for preparing the sample handling and inlet system of a mass spectrometer for analysis of a subsequent sample following analysis of a previous sample comprising the flushing of the system interior with supercritical CO{sub 2} and venting the interior. The method eliminates the effect of system ``memory`` on the subsequent analysis, especially following persistent samples such as xenon and krypton.

Chastgner, P.

1991-05-08T23:59:59.000Z

63

Advanced Mass Calibration and Visualization for FT-ICR Mass Spectromet...  

NLE Websites -- All DOE Office Websites (Extended Search)

for FT-ICR Mass Spectrometry Imaging. Abstract: Mass spectrometry imaging by Fourier transform ion cyclotron resonance (FT-ICR) yields hundreds of unique peaks, many of which...

64

Characterization of an aerodynamic lens for transmitting particles greater than 1 micrometer in diameter into the Aerodyne aerosol mass spectrometer  

E-Print Network (OSTI)

We have designed and characterized a new inlet and aerodynamic lens for the Aerodyne aerosol mass spectrometer (AMS) that transmits particles between 80 nm and more than 3 ?m in vacuum aerodynamic diameter. The design of ...

Williams, L. R.

65

Method for studying a sample of material using a heavy ion induced mass spectrometer source  

DOE Patents (OSTI)

A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu.

Fries, David P. (St. Petersburg, FL); Browning, James F. (Palm Harbour, FL)

1999-01-01T23:59:59.000Z

66

System for studying a sample of material using a heavy ion induced mass spectrometer source  

DOE Patents (OSTI)

A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu.

Fries, David P. (St. Petersburg, FL); Browning, James F. (Palm Harbour, FL)

1998-01-01T23:59:59.000Z

67

A laser and molecular beam mass spectrometer study of low-pressure dimethyl ether flames  

SciTech Connect

The oxidation of dimethyl ether (DME) is studied in low-pressure flames using new molecular beam mass spectrometer and laser diagnostics. Two 30.0-Torr, premixed DME/oxygen/argon flames are investigated with stoichiometries of 0.98 and 1.20. The height above burner profiles of nine stable species and two radicals are measured. These results are compared to the detailed chemical reaction mechanism of Curran and coworkers. Generally good agreement is found between the model and data. The largest discrepancies are found for the methyl radical profiles where the model predicts qualitatively different trends in the methyl concentration with stoichiometry than observed in the experiment.

Andrew McIlroy; Toby D. Hain; Hope A. Michelsen; Terrill A. Cool

2000-12-15T23:59:59.000Z

68

Inductively Coupled Plasma: Fundamental Particle Investigations with Laser Ablation and Applications in Magnetic Sector Mass Spectrometry  

SciTech Connect

Particle size effects and elemental fractionation in laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) are investigated with nanosecond and femtosecond laser ablation, differential mobility analysis, and magnetic sector ICP-MS. Laser pulse width was found to have a significant influence on the LA particle size distribution and the elemental composition of the aerosol and thus fractionation. Emission from individual particles from solution nebulization, glass, and a pressed powder pellet are observed with high speed digital photography. The presence of intact particles in an ICP is shown to be a likely source of fractionation. A technique for the online detection of stimulated elemental release from neural tissue using magnetic sector ICP-MS is described. Detection limits of 1 {micro}g L{sup -1} or better were found for P, Mn, Fe, Cu, and Zn in a 60 {micro}L injection in a physiological saline matrix.

Nathan Joe Saetveit

2008-08-18T23:59:59.000Z

69

Measurement of low radioactivity background in a high voltage cable by high resolution inductively coupled plasma mass spectrometry  

SciTech Connect

The measurement of naturally occurring low level radioactivity background in a high voltage (HV) cable by high resolution inductively coupled plasma mass spectrometry (HR ICP MS) is presented in this work. The measurements were performed at the Chemistry Service of the Gran Sasso National Laboratory. The contributions to the radioactive background coming from the different components of the heterogeneous material were separated. Based on the mass fraction of the cable, the whole contamination was calculated. The HR ICP MS results were cross-checked by gamma ray spectroscopy analysis that was performed at the low background facility STELLA (Sub Terranean Low Level Assay) of the LNGS underground lab using HPGe detectors.

Vacri, M. L. di; Nisi, S.; Balata, M. [Gran Sasso National Laboratory, Chemistry Service, SS 17bis km 18.910, 67100 Assergi (Aq) (Italy)] [Gran Sasso National Laboratory, Chemistry Service, SS 17bis km 18.910, 67100 Assergi (Aq) (Italy)

2013-08-08T23:59:59.000Z

70

Comparison of Time-of-flight and Multicollector ICP Mass Spectrometers for Measuring Actinides in Small Samples using single shot Laser Ablations  

SciTech Connect

The objective of these experiments is to evaluate the performance of two types of ICP-MS device for measurement of actinide isotopes by laser ablation (LA) ICP-MS. The key advantage of ICP-MS compared to monitoring of radioactive decay is that the element need not decay during the measurement time. Hence ICP-MS is much faster for long-lived radionuclides. The LA process yields a transient signal. When spatially resolved analysis is required for small samples, the laser ablation sample pulse lasts only {approx}10 seconds. It is difficult to measure signals at several isotopes with analyzers that are scanned for such a short sample transient. In this work, a time-of-flight (TOF) ICP-MS device, the GBC Optimass 8000 (Figure 1) is one instrument used. Strictly speaking, ions at different m/z values are not measured simultaneously in TOF. However, they are measured in very rapid sequence with little or no compromise between the number of m/z values monitored and the performance. Ions can be measured throughout the m/z range in single sample transients by TOF. The other ICP-MS instrument used is a magnetic sector multicollector MS, the NU Plasma 1700 (Figure 2). Up to 8 adjacent m/z values can be monitored at one setting of the magnetic field and accelerating voltage. Three of these m/z values can be measured with an electron multiplier. This device is usually used for high precision isotope ratio measurements with the Faraday cup detectors. The electron multipliers have much higher sensitivity. In our experience with the scanning magnetic sector instrument in Ames, these devices have the highest sensitivity and lowest background of any ICP-MS device. The ability to monitor several ions simultaneously, or nearly so, should make these devices valuable for the intended application: measurement of actinide isotopes at low concentrations in very small samples for nonproliferation purposes. The primary sample analyzed was an urban dust pellet reference material, NIST 1648. The ability to provide good detection limits for single laser shots is critical.

R.S. Houk; D.B. Aeschliman; S.J. Bajic; D. Baldwin

2005-11-01T23:59:59.000Z

71

Hybrid quadrupole mass filter/quadrupole ion trap/time-of-flight-mass spectrometer for infrared multiple photon dissociation spectroscopy of mass-selected ions  

SciTech Connect

We present a laboratory-constructed mass spectrometer optimized for recording infrared multiple photon dissociation (IRMPD) spectra of mass-selected ions using a benchtop tunable infrared optical parametric oscillator/amplifier (OPO/A). The instrument is equipped with two ionization sources, an electrospray ionization source, as well as an electron ionization source for troubleshooting. This hybrid mass spectrometer is composed of a quadrupole mass filter for mass selection, a reduced pressure ({approx}10{sup -5} Torr) quadrupole ion trap (QIT) for OPO irradiation, and a reflectron time-of-flight drift tube for detecting the remaining precursor and photofragment ions. A helium gas pulse is introduced into the QIT to temporarily increase the pressure and hence enhance the trapping efficiency of axially injected ions. After a brief pump-down delay, the compact ion cloud is subjected to the focused output from the continuous wave OPO. In a recent study, we implemented this setup in the study of protonated tryptophan, TrpH{sup +}, as well as collision-induced dissociation products of this protonated amino acid [W. K. Mino, Jr., K. Gulyuz, D. Wang, C. N. Stedwell, and N. C. Polfer, J. Phys. Chem. Lett. 2, 299 (2011)]. Here, we give a more detailed account on the figures of merit of such IRMPD experiments. The appreciable photodissociation yields in these measurements demonstrate that IRMPD spectroscopy of covalently bound ions can be routinely carried out using benchtop OPO setups.

Gulyuz, Kerim; Stedwell, Corey N.; Wang Da; Polfer, Nick C. [Department of Chemistry, University of Florida, P.O. Box 117200, Gainesville, Florida 32611 (United States)

2011-05-15T23:59:59.000Z

72

Hybrid quadrupole mass filter/quadrupole ion trap/time-of-flight-mass spectrometer for infrared multiple photon dissociation spectroscopy of mass-selected ions  

Science Journals Connector (OSTI)

We present a laboratory-constructed mass spectrometer optimized for recording infrared multiple photondissociation (IRMPD) spectra of mass-selected ions using a benchtop tunable infrared optical parametric oscillator/amplifier (OPO/A). The instrument is equipped with two ionization sources an electrospray ionization source as well as an electron ionization source for troubleshooting. This hybrid mass spectrometer is composed of a quadrupole mass filter for mass selection a reduced pressure (?10?5 Torr) quadrupoleion trap (QIT) for OPOirradiation and a reflectron time-of-flight drift tube for detecting the remaining precursor and photofragment ions. A helium gas pulse is introduced into the QIT to temporarily increase the pressure and hence enhance the trapping efficiency of axially injected ions. After a brief pump-down delay the compact ion cloud is subjected to the focused output from the continuous wave OPO. In a recent study we implemented this setup in the study of protonated tryptophan TrpH+ as well as collision-induced dissociation products of this protonated amino acid[W. K. Mino Jr. K. Gulyuz D. Wang C. N. Stedwell and N. C. Polfer J. Phys. Chem. Lett.2 299 (2011)]. Here we give a more detailed account on the figures of merit of such IRMPD experiments. The appreciable photodissociation yields in these measurements demonstrate that IRMPD spectroscopy of covalently bound ions can be routinely carried out using benchtop OPO setups.

Kerim Gulyuz; Corey N. Stedwell; Da Wang; Nick C. Polfer

2011-01-01T23:59:59.000Z

73

A Design for a Compact Time-of-Flight Mass Spectrometer  

SciTech Connect

The design of a prototype, compact time-of-flight (TOF) mass spectrometer (MS) is described. The system primarily consists of an ion acceleration/focusing/steering assembly (AFSA), an 8 cm field-free region, a 4 cm, dual-stage reflectron and a miniature microchannel plate detector. Consequently, the resulting flight length of the system is 12 cm. The system has been designed with the capability to sample directly from atmosphere at ambient pressures. This is accomplished through the use of an electrodynamic ion funnel, housed in an intermediate-vacuum chamber that is coupled to the inlet of the TOF chamber. TOF spectra were obtained using noble gases (Ar, Kr and Xe) as test chemicals. These measured flight times were used to probe the performance of the instrument. A temporal resolution (tflight/?t) of approximately 125, acquired using 129Xe+, has been measured for the system.

Manard, M.

2012-10-01T23:59:59.000Z

74

Ultrasensitive leak detection during ultrahigh vacuum evacuation by quadrupole mass spectrometer  

SciTech Connect

One must do ultrasensitive leak detection during ultrahigh-vacuum (UHV) evacuation, especially just before the device is sealed off from the vacuum system, to guarantee the longevity of the sealed high-vacuum or even UHV devices with small volume. A quadrupole mass spectrometer (QMS) with an UHV evacuation system can be used under accumulation mode to do the testing. Possible accumulate modes, as well as their advantages and shortcomings, are studied experimentally and discussed in this paper. We found that the opening action of the metal valve during accumulation mode always severely affects the height of the peak indicated by QMS and causes considerable errors. If we determine the leak rate by the peak area instead of the peak height, the situation is much improved. This method has proven quite useful in ensuring the tightness quality for complex sealed UHV devices with small volumes. Ultrasensitive leak detection has been carried out for such real evacuating devices, and a leak rate of 2x10{sup -14} Pa{center_dot}m{sup 3}/s was detected, which is far lower than its dynamic mode and the detection limit of the current advanced commercial leak detectors.

Chen Xu; Huang Tianbin; Wang Ligong; Jin Qiji; Cha Liangzhen [Department of Electronic Engineering, Tsinghua University, Beijing, 100084 (China)

2006-01-15T23:59:59.000Z

75

Precise and accurate determination of boron concentration in silicate rocks by direct isotope dilution ICP-MS: Insights into the B budget of the mantle and B behavior in magmatic systems  

Science Journals Connector (OSTI)

Abstract We determine the bulk boron concentration of silicate rocks using a new method that does not require sample evaporation. After spiking (10B enriched NIST SRM 952) and HF attack, the rock solution is directly aspirated into the ICP-MS, and B concentration is determined by isotopic dilution. This technique is applied to samples with B contents in the range of 0.1–30 ppm. The very low blank (boron during mantle melting and enrichment processes (i.e. metasomatism), and to estimate the primitive mantle B content (0.26 ± 0.04 ppm), while the lava data allows us to quantify B loss due to magmatic degassing (between 10 and 30%), using the composition of a primitive melt inclusion as the reference for an initial magma composition. Our knowledge of the degassing history of the samples allows us to quantify loss during lava emplacement and cooling (4–10%), continuous open-system degassing (10%) and shallow closed-system degassing (5–8%). Our results indicate that 1) B abundances of ocean island basalts are ca. 60–75% less than estimates based on elements with similar incompatibility (e.g., Nb and Ta), 2) this deficiency could reflect source depletion and/or magmatic degassing, and 3) magma degassing accounts for less than half of the inferred boron anomaly seen on primitive mantle-normalized patterns, implying that the mantle sources of ocean island basalts must be depleted in boron. The robust technique presented in this study could provide useful constraints on boron distribution within the Earth's mantle as well as on its behavior in magmatic systems.

G. Menard; I. Vlastélic; D.A. Ionov; E.F. Rose-Koga; J.-L. Piro; C. Pin

2013-01-01T23:59:59.000Z

76

Atmospheric Amines and Ammonia Measured with a Chemical Ionization Mass Spectrometer (CIMS)  

SciTech Connect

We report ambient measurements of amines and ammonia with a fast response chemical ionization mass spectrometer (CIMS) in a Southeastern U.S. forest in Alabama and a moderately polluted Midwestern site during the summer. In the Alabama forest, mostly C3-amines (from pptv to tens of pptv) and ammonia (up to 2 ppbv) were detected on a daily basis. C3-amines and ammonia showed similar diurnal trends and temperature and wind direction dependences, and were not associated with transported CO and SO2 plumes. Consistent with temperature dependences, amine and ammonia in the gas and aerosol phases showed opposite diurnal trends, indicating gas-to-particle partitioning of amines and ammonia. Temperature dependences also imply reversible processes of amines and ammonia evaporation from soil surfaces in daytime and deposition of amines and ammonia to soil surfaces at nighttime. Various amines (C1-C6) at the pptv level were observed in the transported biomass burning plumes, showing that biomass burning can be a substantial source of amines in the Southeast U.S. At the moderately polluted Kent site, higher concentrations of amines (C1-C6, from pptv to tens of pptv) and ammonia (up to 6 ppbv) were detected. Diurnal variations of C1- to C3-amines and ammonia were correlated with the ambient temperature. C4- to C6-amines showed abrupt increases during the nighttime, suggesting that they were emitted from local sources. These abundant amines and ammonia may in part explain the frequent new particle formation events reported from Kent. Lower amine concentrations at the rural forested site highlight the importance of constraining anthropogenic sources of amines.

You, Y.; Kanawade, V. P.; de Gouw, J. A.; Guenther, Alex B.; Madronich, Sasha; Sierra-Hernandez, M. R.; Lawler, M.; Smith, James N.; Takahama, S.; Ruggeri, G.; Koss, A.; Olson, K.; Baumann, K.; Weber, R. J.; Nenes, A.; Guo, H.; Edgerton, Eric S.; Porcelli, L.; Brune, W. H.; Goldstein, Allen H.; Lee, S.-H

2014-11-19T23:59:59.000Z

77

DETERMINATION OF 237NP AND PU ISOTOPES IN LARGE SOIL SAMPLES BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY  

SciTech Connect

A new method for the determination of {sup 237}Np and Pu isotopes in large soil samples has been developed that provides enhanced uranium removal to facilitate assay by inductively coupled plasma mass spectrometry (ICP-MS). This method allows rapid preconcentration and separation of plutonium and neptunium in large soil samples for the measurement of {sup 237}Np and Pu isotopes by ICP-MS. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via {sup 238}U peak tailing. The method provides enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then transferring Pu to DGA resin for additional purification. The decontamination factor for removal of uranium from plutonium for this method is greater than 1 x 10{sup 6}. Alpha spectrometry can also be applied so that the shorter-lived {sup 238}Pu isotope can be measured successfully. {sup 239}Pu, {sup 242}Pu and {sup 237}Np were measured by ICP-MS, while {sup 236}Pu and {sup 238}Pu were measured by alpha spectrometry.

Maxwell, S.

2010-07-26T23:59:59.000Z

78

RAPID DETERMINATION OF 237 NP AND PU ISOTOPES IN WATER BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY AND ALPHA SPECTROMETRY  

SciTech Connect

A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of {sup 237}Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry; a hybrid approach. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ICP-MS and alpha spectrometry so that long and short-lived Pu isotopes can be measured successfully. The method allows for simultaneous extraction of 20 samples (including QC samples) in 4 to 6 hours, and can also be used for emergency response. {sup 239}Pu, {sup 242}Pu and {sup 237}Np were measured by ICP-MS, while {sup 236}Pu, {sup 238}Pu, and {sup 239}Pu were measured by alpha spectrometry.

Maxwell, S.; Jones, V.; Culligan, B.; Nichols, S.; Noyes, G.

2010-06-23T23:59:59.000Z

79

Combined use of a mass-spectrometer and a UV analyzer in the dynamic study of NH3-SCR for diesel exhaust aftertreatment  

Science Journals Connector (OSTI)

A mass spectrometer (MS) and a novel UV analyzer were coupled in the experimental study of the transient Selective Catalytic Reduction (SCR) reactivity, aimed at the development of a dynamic numerical model of...

Cristian Ciardelli; Isabella Nova; Enrico Tronconi…

2007-05-01T23:59:59.000Z

80

Development of novel nano-composite membranes as introduction systems for mass spectrometers: Contrasting nano-composite membranes and conventional inlet systems.  

E-Print Network (OSTI)

??This dissertation presents the development of novel nano-composite membranes as introduction systems for mass spectrometers. These nano-composite membranes incorporate anodic aluminum oxide (AAO) membranes as… (more)

Miranda, Luis

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Development of A Cryogenic Drift Cell Spectrometer and Methods for Improving the Analytical Figures of Merit for Ion Mobility-Mass Spectrometry Analysis  

E-Print Network (OSTI)

A cryogenic (325-80 K) ion mobility-mass spectrometer was designed and constructed in order to improve the analytical figures-of-merit for the chemical analysis of small mass analytes using ion mobility-mass spectrometry. The instrument incorporates...

May, Jody C.

2010-10-12T23:59:59.000Z

82

Upgrade of the Resonance Ionization Mass Spectrometer for Precise Identification of Failed Fuel in a Fast Reactor  

SciTech Connect

Isotopic analysis of krypton (Kr) and xenon (Xe) by resonance ionization mass spectrometry (RIMS) is an effective tool for identification of failed fuel in fast reactors to achieve their safety operation and high plant availability. Reliability of the failed fuel detection and location (FFDL) system depends on the precise determination of {sup 78}Kr/{sup 80}Kr, {sup 82}Kr/{sup 80}Kr and {sup 126}Xe/{sup 129}Xe isotopic ratios, which is mainly hampered by statistical errors for detection of the corresponding isotopes except {sup 82}Kr generated in large amounts during operation of fast reactors. In this paper, we report on improvements of the laser optical system of our spectrometer to increase the resonance ionization efficiency of Kr and Xe atoms, focusing on (i) utilization of the uniform YAG laser beam to improve the wavelength conversion efficiency of sum frequency generation and (ii) reflection of the ultraviolet light by a concave mirror to increase the photon density. The results indicate that our upgraded resonance ionization mass spectrometer has enough performance for isotopic analysis of Kr and Xe required in the Monju FFDL system.

Iwata, Yoshihiro; Ito, Chikara [Experimental Fast Reactor Department, Oarai Research and Development Center, Japan Atomic Energy Agency, 4002 Narita, Oarai, Ibaraki 311-1393 (Japan); Harano, Hideki [National Institute of Advanced Industrial Science and Technology, Central 2, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568 (Japan); Aoyama, Takafumi [Experimental Fast Reactor Department, Oarai Research and Development Center, Japan Atomic Energy Agency, 4002 Narita, Oarai, Ibaraki 311-1393 (Japan); Research Institute of Nuclear Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui 910-8507 (Japan)

2011-12-13T23:59:59.000Z

83

E-Print Network 3.0 - accelerator mass spectrometer Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

for environmental research Mass ... Source: Pacific Northwest National Laboratory, Building Systems Program Collection: Energy Storage, Conversion and Utilization 4...

84

An industrial hygiene survey of acetonitrile using a miniature quadrupole mass spectrometer  

E-Print Network (OSTI)

LIST OF TABLES Page Table I. Characteristics of the Three Common MS Instruments . . . Table II. Compounds with Ions of Mass 39 to 41 AMU. . . 15 Table III. Micropole System Components. . . 18 Table IV. Charcoal Tube Results for Samples Taken... and multi-charged ions, the mass-charge ratio will be simply referred to as mass, or atomic mass unit (AMU), in this thesis, Between pairs of opposite and electrically connected rods, a DC voltage and superimposed RF potential are applied (see Pigure 4...

Bruss, Stacy M

2012-06-07T23:59:59.000Z

85

Capillary electrophoresis–electrospray mass spectrometry and HR–ICP–MS for the detection and quantification of 10B-boronophenylalanine (10B–BPA) used in boron neutron capture therapy  

Science Journals Connector (OSTI)

Boron neutron capture therapy (BNCT) is a bimodal radiotherapeutic treatment based on the irradiation of neoplastic tissues with neutrons after the tissues have selectively accumulated molecules loaded with nu...

Aurélien Pitois; Laura Aldave de las Heras…

2006-02-01T23:59:59.000Z

86

Optically detected, single nanoparticle mass spectrometer with pre-filtered electrospray nanoparticle source  

SciTech Connect

An instrument designed for non-destructive mass analysis of single trapped nanoparticles is described. The heart of the instrument is a 3D quadrupole (Paul) trap constructed to give optical access to the trap center along ten directions, allowing passage of lasers for particle heating and detection, particle injection, collection of scattered or fluorescent photons for particle detection and mass analysis, and collection of particles on TEM grids for analysis, as needed. Nanoparticles are injected using an electrospray ionization (ESI) source, and conditions are described for spraying and trapping polymer particles, bare metal particles, and ligand stabilized particles with masses ranging from 200 kDa to >3 GDa. Conditions appropriate to ESI and injection of different types of particles are described. The instrument is equipped with two ion guides separating the ESI source and nanoparticle trap. The first ion guide is mostly to allow desolvation and differential pumping before the particles enter the trap section of the instrument. The second is a linear quadrupole guide, which can be operated in mass selective or mass band-pass modes to limit transmission to species with mass-to-charge ratios in the range of interest. With a little experience, the design allows injection of single particles into the trap upon demand.

Howder, Collin R.; Bell, David M.; Anderson, Scott L. [Chemistry Department, University of Utah, 315 S. 1400 E, Salt Lake City, Utah 84112 (United States)] [Chemistry Department, University of Utah, 315 S. 1400 E, Salt Lake City, Utah 84112 (United States)

2014-01-15T23:59:59.000Z

87

Standard test method for isotopic analysis of uranium hexafluoride by double standard single-collector gas mass spectrometer method  

E-Print Network (OSTI)

1.1 This is a quantitative test method applicable to determining the mass percent of uranium isotopes in uranium hexafluoride (UF6) samples with 235U concentrations between 0.1 and 5.0 mass %. 1.2 This test method may be applicable for the entire range of 235U concentrations for which adequate standards are available. 1.3 This test method is for analysis by a gas magnetic sector mass spectrometer with a single collector using interpolation to determine the isotopic concentration of an unknown sample between two characterized UF6 standards. 1.4 This test method is to replace the existing test method currently published in Test Methods C761 and is used in the nuclear fuel cycle for UF6 isotopic analyses. 1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appro...

American Society for Testing and Materials. Philadelphia

2010-01-01T23:59:59.000Z

88

Standard test method for analysis of isotopic composition of uranium in nuclear-grade fuel material by quadrupole inductively coupled plasma-mass spectrometry  

E-Print Network (OSTI)

1.1 This test method is applicable to the determination of the isotopic composition of uranium (U) in nuclear-grade fuel material. The following isotopic weight percentages are determined using a quadrupole inductively coupled plasma-mass spectrometer (Q-ICP-MS): 233U, 234U, 235U, 236U, and 238U. The analysis can be performed on various material matrices after acid dissolution and sample dilution into water or dilute nitric (HNO3) acid. These materials include: fuel product, uranium oxide, uranium oxide alloys, uranyl nitrate (UNH) crystals, and solutions. The sample preparation discussed in this test method focuses on fuel product material but may be used for uranium oxide or a uranium oxide alloy. Other preparation techniques may be used and some references are given. Purification of the uranium by anion-exchange extraction is not required for this test method, as it is required by other test methods such as radiochemistry and thermal ionization mass spectroscopy (TIMS). This test method is also described i...

American Society for Testing and Materials. Philadelphia

2000-01-01T23:59:59.000Z

89

Ion fragmentation in an electrospray ionization mass spectrometer interface with different gases  

E-Print Network (OSTI)

in the gas phase. However, particularly in multi- component samples, this may not be enough to unambigu predicts that the degree of ion fragmentation increases with increasing mass of the curtain gas. However with argon and krypton is caused by condensation of the gases within the free jet expansion between

Chen, David D.Y.

90

The Proton Transfer Reaction-Mass Spectrometer for Atmospheric Chemistry Tracers of Diesel Exhaust Emissions and Measurements of Trace gas and Aerosol properties.  

E-Print Network (OSTI)

The Proton Transfer Reaction-Mass Spectrometer for Atmospheric Chemistry Tracers of Diesel Exhaust exhaust experiment It has previously been difficult to identify the emissions of diesel exhaust until reactive with organic compounds such as alkanes which are present in diesel exhaust emissions. The reaction

Collins, Gary S.

91

Determination of Zofenopril and Its Active Metabolite in Human Plasma Using High-Performance Liquid Chromatography Combined With a Triple-Quadruple Tandem Mass Spectrometer  

Science Journals Connector (OSTI)

......Chromatography Combined With a Triple-Quadruple Tandem Mass Spectrometer Yuan Tian 1 Jing Cao 1 Lifang Luo 1 Zunjian Zhang 1 2 * Pengcheng Ma 3 * Author to whom correspondence should be addressed. Email: zunjianzhangcpu@hotmail.com 1 Key Laboratory of Drug......

Yuan Tian; Jing Cao; Lifang Luo; Zunjian Zhang; Pengcheng Ma

2014-06-01T23:59:59.000Z

92

Real-time quadrupole mass spectrometer analysis of gas in boreholefluid samples acquired using the U-Tube sampling methodology  

SciTech Connect

Sampling of fluids in deep boreholes is challenging becauseof the necessity to minimize external contamination and maintain sampleintegrity during recovery. The U-tube sampling methodology was developedto collect large volume, multiphase samples at in situ pressures. As apermanent or semi-permanent installation, the U-tube can be used forrapidly acquiring multiple samples or it may be installed for long-termmonitoring applications. The U-tube was first deployed in Liberty County,TX to monitor crosswell CO2 injection as part of the Frio CO2sequestration experiment. Analysis of gases (dissolved or separate phase)was performed in the field using a quadrupole mass spectrometer, whichserved as the basis for determining the arrival of the CO2 plume. Thepresence of oxygen and argon in elevated concentrations, along withreduced methane concentration, indicate sample alteration caused by theintroduction of surface fluids during borehole completion. Despiteproducing the well to eliminate non-native fluids, measurementsdemonstrate that contamination persists until the immiscible CO2injection swept formation fluid into the observationwellbore.

Freifeld, Barry M.; Trautz, Robert C.

2006-01-11T23:59:59.000Z

93

High-efficiency cross-beam magnetic electron-impact source for improved miniature Mattauch-Herzog mass spectrometer performance  

SciTech Connect

We describe a newly designed cross-beam magnetic electron-impact ion source (CBM-EI). We demonstrate its superiority in comparison with a conventional source (CB-EI) when used with a commercial miniature sector-field-type, non-scanning mass spectrometer featuring Mattauch-Herzog geometry (MH-MS) and a permanent sector-field magnet. This paper clearly shows the value of the CBM-EI for enhancing MH-MS sensitivity. Unlike secondary electron-multiplier type detectors, the pixelated detector (IonCCD Trade-Mark-Sign ) used in the commercial MH-MS has no gain. The MH-MS/IonCCD system is therefore challenged to compete with time-of-flight and quadrupole MS systems due to their higher ion transmissions and detector gains. Using the new CBM-EI, we demonstrate an instrument sensitivity increase of 20-fold to 100-fold relative to the CB-EI-equipped instrument. This remarkable signal increase by the simple addition of the magnet assembly arises from the magnet-induced gyromotion of the thermionic electrons, which vastly increases the effective path length of the electrons through the ionization region, and the collimated nature of the electron flux, which optimizes the ion transmission through the 100-{mu}m object slit of the MH-MS. Some or all of the realized sensitivity increase may be exchanged for an increase in resolution and/or mass range through the use of a narrower object slit, or for a reduction in ion-source pressure to limit quenching. The CBM-EI should facilitate development of a differentially pumped ion source to extend the lifetime of the filament, especially in otherwise intractable applications associated with oxidizing and corrosive samples.

Hadjar, O.; Fowler, W. K. [OI Analytical/CMS Field Products, 2148 Pelham Parkway, Bldg. 400, Pelham, Alabama 35124 (United States)

2012-06-15T23:59:59.000Z

94

Mass Spectrometer | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

on the substrate. Because they flatten less upon impaction, particles with higher viscosity and surface tension can be identified by a steeper slope on a plot of TCA vs. size....

95

Aerosol Mass Spectrometer | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

AMS data is shown below in figure 2. This data was acquired by sampling the output of a diesel engine in a laboratory setting allowing for precise control of engine parameters....

96

Mass Spectrometer: Orbitrap | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

productivity over vast regions of the oceans. We... Separation and Classification of Lipids Using Differential Ion Mobility Spectrometry. Correlations between the dimensions...

97

Determination of long-lived actinides in soil leachates by inductively coupled plasma: Mass spectrometry  

SciTech Connect

Inductively coupled plasma -- mass spectrometry (ICP-MS) was used to concurrently determine multiple long-lived (t{sub 1/2} > 10{sup 4} y) actinide isotopes in soil samples. Ultrasonic nebulization was found to maximize instrument sensitivity. Instrument detection limits for actinides in solution ranged from 50 mBq L{sup {minus}1} ({sup 239}Pu) to 2 {mu}Bq L{sup {minus}1} ({sup 235}U) Hydride adducts of {sup 232}Th and {sup 238}U interfered with the determinations of {sup 233}U and {sup 239} Pu; thus, extraction chromatography was, used to eliminate the sample matrix, concentrate the analytes, and separate uranium from the other actinides. Alpha spectrometric determinations of {sup 230}Th, {sup 239}Pu, and the {sup 234}U/{sup 238}U activity ratio in soil leachates compared well with ICP-MS determinations; however, there were some small systematic differences (ca. 10%) between ICP-MS and a-spectrometric determinations of {sup 234}U and {sup 238}U activities.

Crain, J.S.; Smith, L.L.; Yaeger, J.S.; Alvarado, J.A.

1994-06-01T23:59:59.000Z

98

ablation laser spectrometer  

E-Print Network (OSTI)

ablation laser mass spectrometer molecular beam REMPI laser NREL has designed and developed a combined laser ablation/ pulsed sample introduction/mass spectrometry platform that integrates pyrolysis and/or laser ablation with resonance- enhanced multiphoton ionization (REMPI) time-of-flight mass

99

Calibration of laser ablation inductively coupled plasma mass spectrometry using dried solution aerosols for the quantitative analysis of solid samples  

SciTech Connect

Inductively coupled plasma mass spectrometry (ICP-MS) has become the method of choice for elemental and isotopic analysis. Several factors contribute to its success. Modern instruments are capable of routine analysis at part per trillion levels with relative detection limits in part per quadrillion levels. Sensitivities in these instruments can be as high as 200 million counts per second per part per million with linear dynamic ranges up to eight orders of magnitude. With standards for only a few elements, rapid semiquantitative analysis of over 70 elements in an individual sample can be performed. Less than 20 years after its inception ICP-MS has shown to be applicable to several areas of science. These include geochemistry, the nuclear industry, environmental chemistry, clinical chemistry, the semiconductor industry, and forensic chemistry. In this introduction, the general attributes of ICP-MS will be discussed in terms of instrumentation and sample introduction. The advantages and disadvantages of current systems are presented. A detailed description of one method of sample introduction, laser ablation, is given. The paper also gives conclusions and suggestions for future work. Chapter 2, Quantitative analysis of solids by laser ablation inductively coupled plasma mass spectrometry using dried solution aerosols for calibration, has been removed for separate processing.

Leach, J.

1999-02-12T23:59:59.000Z

100

Monolithic spectrometer  

DOE Patents (OSTI)

A monolithic spectrometer is disclosed for use in spectroscopy. The spectrometer is a single body of translucent material with positioned surfaces for the transmission, reflection and spectral analysis of light rays. 6 figs.

Rajic, S.; Egert, C.M.; Kahl, W.K.; Snyder, W.B. Jr.; Evans, B.M. III; Marlar, T.A.; Cunningham, J.P.

1998-05-19T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Monolithic spectrometer  

DOE Patents (OSTI)

A monolithic spectrometer is disclosed for use in spectroscopy. The spectrometer is a single body of translucent material with positioned surfaces for the transmission, reflection and spectral analysis of light rays.

Rajic, Slobodan (Knoxville, TN); Egert, Charles M. (Oak Ridge, TN); Kahl, William K. (Knoxville, TN); Snyder, Jr., William B. (Knoxville, TN); Evans, III, Boyd M. (Oak Ridge, TN); Marlar, Troy A. (Knoxville, TN); Cunningham, Joseph P. (Oak Ridge, TN)

1998-01-01T23:59:59.000Z

102

Development and implementation of a FT-ICR mass spectrometer for the investigation of ion conformations of peptide sequence isomers containing basic amino acid residues by gas-phase hydrogen/deuterium exchange  

E-Print Network (OSTI)

The gas-phase hydrogen/deuterium (H/D) exchange of protonated di- and tripeptides containing a basic amino acid residue has been studied with a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Bimolecular reactions...

Marini, Joseph Thomas

2004-09-30T23:59:59.000Z

103

Measurements of the mass and isotopic yields of the {sup 233}U(n{sub th},f) reaction at the Lohengrin spectrometer  

SciTech Connect

Over the last 10 years, a vast campaign of measurements has been initiated to improve the precision of neutron data for the involved key nuclei ({sup 232}Th, {sup 233}Pa and {sup 233}U) of the innovative Th -{sup 233}U cycle. This latter might indeed provide cleaner nuclear energy than the present U-Pu one. New measurements of charge and mass distributions of the fission products have been achieved at the Lohengrin spectrometer of the Inst. Laue-Langevin (ILL) during fall 2010 to complete the experimental data of {sup 233}U(n,f) that exist mainly for light fission fragments. That is why we performed measurements of mass and isotopic yields with a special focus on the heavy fission fragment part. Mass yields were measured by ion counting with an ionization chamber after separation by the Lohengrin spectrometer. Isotopic yields were derived from gamma spectrometry of mass-separated beams using HPGe clover detectors. This paper will present the results of these fission yield measurements along with details on the experimental set-up and the chosen analysis method. (authors)

Martin, F.; Sage, C.; Kessedjian, G. [LPSC, UJF Grenoble 1, CNRS/IN2P3, Grenoble (France); Bacri, C. O. [IPN, CNRS/IN2P3, Univ. Paris-Sud (France); Bidaud, A.; Billebaud, A.; Capellan, N.; Chabod, S. [LPSC, UJF Grenoble 1, CNRS/IN2P3, Grenoble (France); Cywinski, R. [Dept. Chemical and Biological Sciences, Univ. Ruddersfield (United Kingdom); Doligez, X. [IPN, CNRS/IN2P3, Univ. Paris-Sud (France); Faust, H.; Koester, U. [Institut Laue-Langevin, Grenoble (France); Letourneau, A.; Materna, T. [DSM/IRFU/SPhN, CEA Saclay (France); Mathieu, L. [CENBG, Universite de Bordeaux 1 (France); Meplan, O. [LPSC, UJF Grenoble 1, CNRS/IN2P3, Grenoble (France); Panebianco, S. [DSM/IRFU/SPhN, CEA Saclay (France); Serot, O. [DEN/DER/SPRC/LEPh, CEA Cadarache (France)

2011-07-01T23:59:59.000Z

104

Use of the ECL-CAMAC trigger processor system for recoil missing mass triggers at the Tagged Photon Spectrometer at Fermilab  

SciTech Connect

A trigger processor in operation since May 1980 at the Tagged Photon Spectrometer at Fermilab will be described. The processor, based on the Fermilab ECL-CAMAC system, allows fast selection of high mass diffractive events from the total hadronic cross section. Data from a recoil detector, consisting of 3 wire chambers and 4 layers of scintillator concentric about a 1.5 m liquid hydrogen target, is digitized and presented to the processor within 3 sec. From the chamber data are found the vertices and angles of all recoiling tracks.

Martin, J.; Bracker, S.; Hartner, G.; Appel, J.; Nash, T.

1981-05-01T23:59:59.000Z

105

National High Magnetic Field Laboratory Audio Dictionary: Spectrometer  

NLE Websites -- All DOE Office Websites (Extended Search)

Spectrometer? Now Playing: What's a Spectrometer? Enable Javascript and Flash to stream the Magnet Minute Munir Humayun Associated Links Mass Spectrometry: How to Weigh an Atom...

106

Correlation spectrometer  

DOE Patents (OSTI)

A correlation spectrometer can detect a large number of gaseous compounds, or chemical species, with a species-specific mask wheel. In this mode, the spectrometer is optimized for the direct measurement of individual target compounds. Additionally, the spectrometer can measure the transmission spectrum from a given sample of gas. In this mode, infrared light is passed through a gas sample and the infrared transmission signature of the gasses present is recorded and measured using Hadamard encoding techniques. The spectrometer can detect the transmission or emission spectra in any system where multiple species are present in a generally known volume.

Sinclair, Michael B. (Albuquerque, NM); Pfeifer, Kent B. (Los Lunas, NM); Flemming, Jeb H. (Albuquerque, NM); Jones, Gary D. (Tijeras, NM); Tigges, Chris P. (Albuquerque, NM)

2010-04-13T23:59:59.000Z

107

Bio-oil Analysis Using Negative Electrospray Ionization: Comparative Study of High-Resolution Mass Spectrometers and Phenolic versus Sugaric Components  

SciTech Connect

We have previously demonstrated that a petroleomic analysis could be performed for bio-oils and revealed the complex nature of bio-oils for the nonvolatile phenolic compounds (Smith, E.; Lee, Y. J. Energy Fuels 2010, 24, 5190?5198). As a subsequent study, we have adapted electrospray ionization in negative-ion mode to characterize a wide variety of bio-oil compounds. A comparative study of three common high-resolution mass spectrometers was performed to validate the methodology and to investigate the differences in mass discrimination and resolution. The mass spectrum is dominated by low mass compounds with m/z of 100–250, with some compounds being analyzable by gas chromatography–mass spectrometry (GC–MS). We could characterize over 800 chemical compositions, with only about 40 of them being previously known in GC–MS. This unveiled a much more complex nature of bio-oils than typically shown by GC–MS. The pyrolysis products of cellulose and hemicellulose, particularly polyhydroxy cyclic hydrocarbons (or what we call “sugaric” compounds), such as levoglucosan, could be effectively characterized with this approach. Phenolic compounds from lignin pyrolysis could be clearly distinguished in a contour map of double bond equivalent (DBE) versus the number of carbons from these sugaric compounds.

Smith, Erica A.; Park, Soojin; Klein, Adam T.; Lee, Young Jin

2012-05-16T23:59:59.000Z

108

RAPID DETERMINATION OF ACTINIDES IN URINE BY INDUCTIVELY-COUPLED PLASMA MASS SPECTROMETRY AND ALPHA SPECTROMETRY: A HYBRID APPROACH  

SciTech Connect

A new rapid separation method that allows separation and preconcentration of actinides in urine samples was developed for the measurement of longer lived actinides by inductively coupled plasma mass spectrometry (ICP-MS) and short-lived actinides by alpha spectrometry; a hybrid approach. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration, if required, is performed using a streamlined calcium phosphate precipitation. Similar technology has been applied to separate actinides prior to measurement by alpha spectrometry, but this new method has been developed with elution reagents now compatible with ICP-MS as well. Purified solutions are split between ICP-MS and alpha spectrometry so that long- and short-lived actinide isotopes can be measured successfully. The method allows for simultaneous extraction of 24 samples (including QC samples) in less than 3 h. Simultaneous sample preparation can offer significant time savings over sequential sample preparation. For example, sequential sample preparation of 24 samples taking just 15 min each requires 6 h to complete. The simplicity and speed of this new method makes it attractive for radiological emergency response. If preconcentration is applied, the method is applicable to larger sample aliquots for occupational exposures as well. The chemical recoveries are typically greater than 90%, in contrast to other reported methods using flow injection separation techniques for urine samples where plutonium yields were 70-80%. This method allows measurement of both long-lived and short-lived actinide isotopes. 239Pu, 242Pu, 237Np, 243Am, 234U, 235U and 238U were measured by ICP-MS, while 236Pu, 238Pu, 239Pu, 241Am, 243Am and 244Cm were measured by alpha spectrometry. The method can also be adapted so that the separation of uranium isotopes for assay is not required, if uranium assay by direct dilution of the urine sample is preferred instead. Multiple vacuum box locations may be set-up to supply several ICP-MS units with purified sample fractions such that a high sample throughput may be achieved, while still allowing for rapid measurement of short-lived actinides by alpha spectrometry.

Maxwell, S.; Jones, V.

2009-05-27T23:59:59.000Z

109

Dustbuster: a compact impact-ionization time-of-flight mass spectrometer for in situ analysis of cosmic dust  

E-Print Network (OSTI)

a large target area with a reflectron, simultaneously optimizing mass resolution, particle detection. The resulting ions, with broad energy and angular distributions, are accelerated through a modified reflectron remote sensing, collection and analysis of dust grains that have survived impact on the Earth, capture

Stewart, Sarah T.

110

On-line Analysis of Organic Compounds in Diesel Exhaust Using a Proton Transfer Reaction Mass Spectrometer (PTR-MS)  

SciTech Connect

Chemical ionization mass spectrometry using H3O+ proton transfer in an ion drift tube (PTR-MS) was used to measure volatile organic compound (VOC) concentrations on-line in diesel engine exhaust as a function on engine load. The purpose of the study was to evaluate the PTR-MS instrument as an analytical tool for diesel engine emissions abatement research. Measured sensitivities determined from gas standards were found to be between 30% and 100% greater than calculated sensitivities. A slight humidity dependent sensitivity was observed for non-polar species, implying that reactions with H+(H2O)2 were important for some organics. The mass spectra of diesel exhaust were complex but displayed a pattern of strong ion signals at 14n+1 (n=3..8) masses, with a relative ion abundance similar to that obtained from electron impact ionization of alkanes. Laboratory experiments verified that C8-C16 n-alkanes and C8-C13 1-alkenes react with H3O+ in dissociative proton transfer reaction resulting in alkyl cation ion products, primarily m/z 41, 43, 57, 71 and 85. Monitoring the sum of these ions signals may be useful for estimating alkane emissions from unburnt diesel fuel. Alkane fragmentation likely simplified the diesel exhaust mass spectrum and reduced potential mass interferences with isobaric aromatic compounds. It is shown that the relative abundances of VOCs changed as a function of engine load. Concentrations of aldehydes and ketones dominated those of aromatic species with formaldehyde and acetaldehyde estimated to be the most abundant VOCs in the PTR-MS mass spectrum at all engine loads. The relative abundances of benzene and toluene increased with engine load indicating their pyrogenic origin. The relative abundance of alkanes, aromatics, aldehydes, and alcohols was broadly consistent with literature publications of diesel exhaust analysis by gas chromatography. About 75% of the organic ion signal could be assigned. On line analysis of diesel exhaust using this technology may be valuable tool for diesel engine emission research.

Jobson, B Tom T.; Alexander, M. Lizabeth; Maupin, Gary D.; Muntean, George G.

2005-08-01T23:59:59.000Z

111

A MODULAR STEADY STATE GLOW DISCHARGE QUADRUPOLE MASS SPECTROMETER SYSTEM FOR THE AT-LINE ANALYSIS OF PLUTONIUM METAL  

SciTech Connect

Historically, glow discharge mass and optical spectrometric techniques have been used in industry for the characterization of processed metals, such as steels and other alloys. This technique is especially well suited for this type of product analysis because the glow discharge ionization source accommodates solid conducting samples with minimal or no sample preparation. This characteristic along with minimal matrix effect considerations makes the glow discharge source well suited for these types of applications.

R. STEINER; D. WAYNE

1998-12-01T23:59:59.000Z

112

Spectrometer gun  

DOE Patents (OSTI)

A hand-holdable, battery-operated, microprocessor-based spectrometer gun is described that includes a low-power matrix display and sufficient memory to permit both real-time observation and extended analysis of detected radiation pulses. Universality of the incorporated signal processing circuitry permits operation with various detectors having differing pulse detection and sensitivity parameters.

Waechter, D.A.; Wolf, M.A.; Umbarger, C.J.

1981-11-03T23:59:59.000Z

113

Spectrometer gun  

DOE Patents (OSTI)

A hand-holdable, battery-operated, microprocessor-based spectrometer gun includes a low-power matrix display and sufficient memory to permit both real-time observation and extended analysis of detected radiation pulses. Universality of the incorporated signal processing circuitry permits operation with various detectors having differing pulse detection and sensitivity parameters.

Waechter, David A. (Los Alamos, NM); Wolf, Michael A. (Los Alamos, NM); Umbarger, C. John (Los Alamos, NM)

1985-01-01T23:59:59.000Z

114

Chemical Analysis of Diesel Engine Nanoparticles Using a Nano-DMA/Thermal Desorption Particle Beam Mass Spectrometer  

Science Journals Connector (OSTI)

Modern combustion engines burn cleaner and produce less particulate mass than older models, but it has also been observed that some engines, for example, diesels, emit high number concentrations of a subset of fine particles called nanoparticles (diameter cycle, turbocharged diesel engine that produced a peak torque of 350 N-m at an intermediate engine speed of 1400 rpm, which is generally used for short-duration work periods of heavy lifting or material handling. ... However, general trends from past studies can be applied to the analysis of this work. ...

Herbert J. Tobias; Derek E. Beving; Paul J. Ziemann; Hiromu Sakurai; Miriam Zuk; Peter H. McMurry; Darrick Zarling; Robert Waytulonis; David B. Kittelson

2001-04-25T23:59:59.000Z

115

The Canadian Penning Trap Spectrometer at Argonne  

Science Journals Connector (OSTI)

The Canadian Penning Trap (CPT) mass spectrometer is a device used for high-precision mass measurements on short-lived isotopes. It is located at the ATLAS superconducting heavy-ion linac facility where a nove...

G. Savard; R. C. Barber; C. Boudreau…

2001-01-01T23:59:59.000Z

116

The Canadian Penning Trap Spectrometer at Argonne  

Science Journals Connector (OSTI)

The Canadian Penning Trap (CPT) mass spectrometer is a device used for high-precision mass measurements on short-lived isotopes. It is located at the ATLAS superconducting heavy-ion linac facility where a nove...

G. Savard; R. C. Barber; C. Boudreau; F. Buchinger; J. Caggiano…

117

Mobile Ice Nucleus Spectrometer  

SciTech Connect

This first year report presents results from a computational fluid dynamics (CFD) study to assess the flow and temperature profiles within the mobile ice nucleus spectrometer.

Kulkarni, Gourihar R.; Kok, G. L.

2012-05-07T23:59:59.000Z

118

EMSL - fluorescence spectrometer  

NLE Websites -- All DOE Office Websites (Extended Search)

fluorescence-spectrometer en Structures and Stabilities of (MgO)n Nanoclusters. http:www.emsl.pnl.govemslwebpublicationsstructures-and-stabilities-mgon-nanoclusters

119

New perspectives in laser analytics: Resonance-enhanced multiphoton ionization in a Paul ion trap combined with a time-of-flight mass spectrometer  

SciTech Connect

A new laser analytical device has been developed that is based on resonance-enhanced multiphoton ionization in the very center of a radio-frequency quadrupole ion trap. Applications in speciation anlaysis of biological and enviromental samples and in materials science will all benefit from laser-optical selectivity in the resonance excitation process, combined with mass-spectropic sensivity which is further enhanced by the ion accumulation and storage capability.

Bisling, Peter; Heger, Hans Joerg; Michaelis, Walfried; Weitkamp, Claus; Zobel, Harald [GKSS-Forschungszentrum Geesthacht GmbH, Postfach 11 60, D-21494 Geesthacht (Germany)

1995-04-01T23:59:59.000Z

120

CX-004805: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

05: Categorical Exclusion Determination 05: Categorical Exclusion Determination CX-004805: Categorical Exclusion Determination 773-A C-150 and B-142/146 Inductively Coupled Plasma Mass Spectrometer (ICP-MS) Installation CX(s) Applied: B3.6 Date: 11/12/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office Lab utilities are being modified, Central Hood Exhaust (CHEX) canopy hood, to support installation modifications of an ICP-MS (Inductively Coupled Plasma Mass Spectrometer) in C-150 for clean testing and procedure development. Then, lab utilities will be modified to support permanent installation of the equipment in a Process Hood Exhaust (PHEX) Hood located in B-142/146. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-004805.pdf More Documents & Publications CX-002883: Categorical Exclusion Determination

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

EMSL - Mass Spectrometry  

NLE Websites -- All DOE Office Websites (Extended Search)

mass-spectrometry Proteomics Capabilities High resolution and mass accuracy Fourier-transform ion cyclotron resonance (FT-ICR) spectrometers, from 6 Tesla (T) to 15T and 21T in...

122

In situ boron isotope measurements of natural geological materials by LA-MC-ICP-MS  

Science Journals Connector (OSTI)

There are two main methods to determine boron isotopic composition. One is the solution method, in which boron is purified after the samples are dissolved in solution and the boron isotope ratios are determined b...

KeJun Hou; YanHe Li; YingKai Xiao; Feng Liu; YouRong Tian

2010-10-01T23:59:59.000Z

123

Lead Speciation by HPLC—ICP—AES and HPLC—ICP—MS  

Science Journals Connector (OSTI)

......detection. | Department of Chemistry, University of Cincinnati...Caruso Department of Chemistry, University of Cincinnati...Smelting operations and the combustion of coal have also con tributed...National Forensic Chemistry Center, U.S. Food......

Amel Al-Rashdan; Douglas Heitkemper; Joseph A. Caruso

1991-03-01T23:59:59.000Z

124

Ancestral Polynesian Pottery Production and Exchange Analysis Using LA-ICP-MS  

E-Print Network (OSTI)

(Clark 1989). Within the last 400 years, Tula underwent shoreline progradation by approximately 0.4 kilometers, while shoreline progradation has occurred in Maloata as well, leaving behind 1500 year old cultural deposits (Ayres and Eisler 1987...). Studies in site formation processes at To?aga, Ofu resulted in a morphodynamic model for the development of the coastal plain at To?aga (Kirch 1993). This model demonstrates Holocene sea levels rose at range of 1 to 2 meters from 4000 to 2000 years B...

Bartek, Christopher

2009-06-09T23:59:59.000Z

125

Lead Speciation by HPLC—ICP—AES and HPLC—ICP—MS  

Science Journals Connector (OSTI)

......graphite furnace atomic absorption spectrometry (GFAAS) (5...electrothermal atom- ization atomic absorption spectrometry (EAAAS) (6...gas chromatog raphy atomic absorption spectrometry (GC-AAS...9 C with a refrigerated chiller (Neslab Instruments). The......

Amel Al-Rashdan; Douglas Heitkemper; Joseph A. Caruso

1991-03-01T23:59:59.000Z

126

On-Line Boron-10 Determination from Blood Samples by ICP-MS  

Science Journals Connector (OSTI)

Accurate and fast boron analysis is essential in BNC-treatment of glioma patients. Standard boron analytical assay from biological samples are direct current plasma atomic emission spectrometry,1 inductively coup...

M. Kulvik; J. Laakso; J. Vähätalo; R. Zilliacus

2001-01-01T23:59:59.000Z

127

Trace Elemental Variation in Dosidicus Gigas Statoliths Using LA-ICP-MS  

E-Print Network (OSTI)

classified as distinct group for the first time using these methods. Elemental fingerprint signatures were found to be significantly different at multiple ontogenic growth regions of the statolith. Seattle and California paralarvae exhibited similar...

Arbuckle, Nancy 1980-

2012-08-24T23:59:59.000Z

128

E-Print Network 3.0 - alpha spectrometry icp-ms Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Collection: Multidisciplinary Databases and Resources 11 Nuclear Instruments and Methods in Physics Research A 591 (2008) 490509 Systematic study of trace radioactive...

129

Determination of 235U/238U Ratio on Urine by ICP-MS  

SciTech Connect

LLNL Internal Dosimetry Program - The new procedure satisfies the requirement to determine {sup 235}U/{sup 238}U ratio in bioassay urine samples. MDA - The L{sub C} and MDA{sub 95} for {sup 235}U are well below the required detection limit of 0.00035 {mu}g/L. Turn around time - Analysis of 10 samples plus 2 QCs can be completed in one work day (8 hours).

Collins, L; Gobaleza, A; Langston, R; Radev, R; Than, C; Wong, C; Wood-Zika, A

2011-10-19T23:59:59.000Z

130

Lead Speciation by HPLC—ICP—AES and HPLC—ICP—MS  

Science Journals Connector (OSTI)

......ronment is cause for great concern. Health authorities around the world are...even trace levels pose long term health risks (1). Young children are...in the home are a particularly dangerous health * This work w a s presented in......

Amel Al-Rashdan; Douglas Heitkemper; Joseph A. Caruso

1991-03-01T23:59:59.000Z

131

Lead Speciation by HPLC—ICP—AES and HPLC—ICP—MS  

Science Journals Connector (OSTI)

......Industries) that allowed real-time display as well as data storage on magnetic disc. The concentric nebulizer was used with a...stripping voltametric determination of trimethyl- lead in seawater by polarography and mercury-199 and lead-207 nuclear magnetic......

Amel Al-Rashdan; Douglas Heitkemper; Joseph A. Caruso

1991-03-01T23:59:59.000Z

132

Mass Spectrometer: Single Particle (SPLAT II) | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

and micro-scales. SPLAT II's applications include but are not limited to climate, air pollution, human health, bioterrorism, and emerging nanotechnologies. Portability is a...

133

LUNAR MASS SPECTROMETER RELIABILITY LOGIC DIAGRAM  

E-Print Network (OSTI)

point (A) to (F). The block diagram also defines the reliability functions for the purpose of FMEA 1

Rathbun, Julie A.

134

Slurry Nebulization-Inductively Coupled Plasma Mass Spectrometry with Solution Calibration for Determination of Ultratrace Boron in High Pure Nuclear Graphite Powder  

Science Journals Connector (OSTI)

Slurry nebulization-inductively coupled plasma mass spectrometry (ICP-MS) was developed for the direct determination of trace boron (B) in high-purity graphite powders. After the graphite powders were ground and sifted, the particle size of graphite was collected less than 5 ?m. Polyvinylpyrrolidone (PVP) was used as the dispersant in slurry preparation. The optimal mass ratio of PVP to the graphite was found to be 0.5. Well-proportioned and stable slurry solution was obtained by magnetic stirrer. 0.1 M NH4OH as the aqueous medium could provide the optimal pH of 10 for the stable slurry and eliminate the memory effect of B. ICP-MS was operated in a higher resolution mode (0.6 amu) to eliminate the interference with the matrix 12C by peak tailing. Oxygen was added into the plasma at a flow rate of 60 mL min?1 to resolve carbon deposition on the sampler and skimmer cones and accelerate particle dissociation in the plasma. External calibration with aqueous solution standards was established for quantification. Beryllium was chosen as the internal standard to evaluate the efficiency of matrix effect correction. A correlation coefficient of 0.9995 was obtained for B concentration ranging 2–200 ?g L?1. The detection limit (3S) of B was 0.095 ?g g?1. As a practical application, the proposed method was used for the determination of trace B in four nuclear graphite samples (claimed 99.999% purity), with the satisfactory recoveries for the spike tests in the range of 97.2%–103.1%.

Xin-Li LIU; Tai-Cheng DUAN; Yi HAN; Xiao-Yu JIA; Wei-Na ZHANG; Hang-Ting CHEN

2010-01-01T23:59:59.000Z

135

E-Print Network 3.0 - analytical chromatography methods Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

inductively coupled plasma-mass spectrometry (IC-ICP-MS), liquid ... Source: Missouri-Rolla, University of - Laboratory for Information Technology Evaluation Collection:...

136

Compound and Elemental Analysis At Salt Wells Area (Coolbaugh...  

Open Energy Info (EERE)

by standard Induced Coupled Plasma Mass Spectroscopy (ICP-MS), using ICP emission and atomic absorption methods for cations and ICP emission for anions. The hottest sampled...

137

MagLab - Acronyms  

NLE Websites -- All DOE Office Websites (Extended Search)

High BT Program HPLC high-performance liquid chromatography ICR Instruments & Tools HTS high temperature superconductor Grain Boundaries I ICP-MS Inductively Coupled Plasma Mass...

138

DOE/RL-96-68  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Transport Association ICP-MS Inductively Coupled Plasma Mass Spectrometry ISMS Integrated Safety Management System PCB Polychlorinated Biphenyls QA Quality Assurance QC...

139

Download Full-text PDF  

Science Journals Connector (OSTI)

coupled to high-resolution inductively coupled plasma mass spectrometry, in samples from ..... 2000 Focus, Postnova) was coupled online to an ICP-MS.

2009-10-26T23:59:59.000Z

140

46  

Science Journals Connector (OSTI)

(Princeton University), and NSF grant OCE-9720692 (to R.M.S.). ... sector field inductively coupled plasma mass spectrometry. [HR-ICP-MS] and 59Fe uptake).

2001-08-08T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Download Full-text PDF  

Science Journals Connector (OSTI)

Department of Geosciences, Princeton University, Princeton, New Jersey 08544. Susana .... plasma mass spectrometry (ICP-MS; ThermoFinigan,. Element 2) ...

2006-06-12T23:59:59.000Z

142

Download  

Science Journals Connector (OSTI)

Chemistry at Princeton and the Center for Microbial Oceanog- raphy Research and .... inductively coupled plasma mass spectrometry (ICP-MS) according to a ...

2007-12-18T23:59:59.000Z

143

Kustka, Adam B., Sergio A. Sañudo-Wilhelmy, Edward J. Carpenter ...  

Science Journals Connector (OSTI)

1 Present address: Department of Geosciences, Princeton Univer- sity, Princeton ..... coupled plasma mass spectrometry (MR-ICP-MS, Element. II, Finnigan) by ...

2003-08-25T23:59:59.000Z

144

Neutron range spectrometer  

DOE Patents (OSTI)

A neutron range spectrometer and method for determining the neutron energy spectrum of a neutron emitting source are disclosed. Neutrons from the source are colliminated along a collimation axis and a position sensitive neutron counter is disposed in the path of the collimated neutron beam. The counter determines positions along the collimation axis of interactions between the neutrons in the neutron beam and a neutron-absorbing material in the counter. From the interaction positions, a computer analyzes the data and determines the neutron energy spectrum of the neutron beam. The counter is preferably shielded and a suitable neutron-absorbing material is He-3. 1 fig.

Manglos, S.H.

1988-03-10T23:59:59.000Z

145

Quench anaylsis of MICE spectrometer superconducting solenoid  

SciTech Connect

MICE superconducting spectrometer solenoids fabrication and tests are in progress now. First tests of the Spectrometer Solenoid discovered some issues which could be related to the chosen passive quench protection system. Both solenoids do not have heaters and quench propagation relied on the 'quench back' effect, cold diodes, and shunt resistors. The solenoids have very large inductances and stored energy which is 100% dissipated in the cold mass during a quench. This makes their protection a challenging task. The paper presents the quench analysis of these solenoids based on 3D FEA solution of coupled transient electromagnetic and thermal problems. The simulations used the Vector Fields QUENCH code. It is shown that in some quench scenarios, the quench propagation is relatively slow and some areas can be overheated. They describe ways of improving the solenoids quench protection in order to reduce the risk of possible failure.

Kashikhin, Vladimir; Bross, Alan; /Fermilab; Prestemon, Soren; / /LBL, Berkeley

2011-09-01T23:59:59.000Z

146

Photo ion spectrometer  

DOE Patents (OSTI)

A charged particle spectrometer for performing ultrasensitive quantitative analysis of selected atomic components removed from a sample. Significant improvements in performing energy and angular refocusing spectroscopy are accomplished by means of a two dimensional structure for generating predetermined electromagnetic field boundary conditions. Both resonance and non-resonance ionization of selected neutral atomic components allow accumulation of increased chemical information. A multiplexed operation between a SIMS mode and a neutral atomic component ionization mode with EARTOF analysis enables comparison of chemical information from secondary ions and neutral atomic components removed from the sample. An electronic system is described for switching high level signals, such as SIMS signals, directly to a transient recorder and through a charge amplifier to the transient recorder for a low level signal pulse counting mode, such as for a neutral atomic component ionization mode.

Gruen, Dieter M. (Downers Grove, IL); Young, Charles E. (Westmont, IL); Pellin, Michael J. (Naperville, IL)

1989-01-01T23:59:59.000Z

147

Photo ion spectrometer  

DOE Patents (OSTI)

A charged particle spectrometer is described for performing ultrasensitive quantitative analysis of selected atomic components removed from a sample. Significant improvements in performing energy and angular refocusing spectroscopy are accomplished by means of a two dimensional structure for generating predetermined electromagnetic field boundary conditions. Both resonance and non-resonance ionization of selected neutral atomic components allow accumulation of increased chemical information. A multiplexed operation between a SIMS mode and a neutral atomic component ionization mode with EARTOF analysis enables comparison of chemical information from secondary ions and neutral atomic components removed from the sample. An electronic system is described for switching high level signals, such as SIMS signals, directly to a transient recorder and through a charge amplifier to the transient recorder for a low level signal pulse counting mode, such as for a neutral atomic component ionization mode. 12 figs.

Gruen, D.M.; Young, C.E.; Pellin, M.J.

1989-12-26T23:59:59.000Z

148

Current developments in laser ablation-inductively coupled plasma-mass spectrometry for use in geology, forensics, and nuclear nonproliferation research  

SciTech Connect

This dissertation focused on new applications of laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The diverse fields that were investigated show the versatility of the technique. In Chapter 2, LA-ICP-MS was used to investigate the rare earth element (REE) profiles of garnets from the Broken Hill Deposit in New South Wales, Australia. The normalized REE profiles helped to shed new light on the formation of deposits of sulfide ores. This information may be helpful in identifying the location of sulfide ore deposits in other locations. New sources of metals such as Pg, Zn, and Ag, produced from these ores, are needed to sustain our current technological society. The application of LA-ICP-MS presented in Chapter 3 is the forensics analysis of automotive putty and caulking. The elemental analysis of these materials was combined with the use of Principal Components Analysis (PCA). The PCA comparison was able to differentiate the automotive putty samples by manufacturer and lot number. The analysis of caulk was able to show a differentiation based on manufacturer, but no clear differentiation was shown by lot number. This differentiation may allow matching of evidence in the future. This will require many more analyses and the construction of a database made up of many different samples. The 4th chapter was a study of the capabilities of LA-ICP-MS for fast and precise analysis of particle ensembles for nuclear nonproliferation applications. Laser ablation has the ability to spatially resolve particle ensembles which may contain uranium or other actinides from other particles present in a sample. This is of importance in samples obtained from air on filter media. The particle ensembles of interest may be mixed in amongst dust and other particulates. A problem arises when ablating these particle ensembles directly from the filter media. Dust particles other than ones of interest may be accidentally entrained in the aerosol of the ablated particle ensemble. This would cause the analysis to be skewed. The use of a gelatin substrate allows the ablation a particle ensemble without disturbing other particles or the gelatin surface. A method to trap and ablate particles on filter paper using collodion was also investigated. The laser was used to dig through the collodion layer and into the particle ensemble. Both of these methods fix particles to allow spatial resolution of the particle ensembles. The use of vanillic acid as a possible enhancement to ablation was also studied. A vanillic acid coating of the particles fixed on top of the gelatin substrate was not found to have any positive effect on either signal intensity or precision. The mixing of vanillic acid in the collodion solution used to coat the filter paper increased ablation signal intensity by a factor of 4 to 5. There was little effect on precision, though. The collodion on filter paper method and the gelatin method of resolving particles have shown themselves to be possible tools in fighting proliferation of nuclear weapons and material. Future applications of LA-ICP-MS are only limited by the imagination of the investigator. Any material that can be ablated and aerosolized is a potential material for analysis by LA-ICP-MS. Improvements in aerosol transport, ablation chamber design, and laser focusing can make possible the ablation and analysis of very small amounts of material. This may perhaps lead to more possible uses in forensics. A similar method to the one used in Chapter 3 could perhaps be used to match drug residue to the place of origin. Perhaps a link could be made based on the elements leached from the soil by plants used to make drugs. This may have a specific pattern based on where the plant was grown. Synthetic drugs are produced in clandestine laboratories that are often times very dirty. The dust, debris, and unique materials in the lab environment could create enough variance to perhaps match drugs produced there to samples obtained off the street. Even if the match was not strong enough to be evidence, the knowledge that many sa

Messerly, Joshua D.

2008-08-26T23:59:59.000Z

149

Neutron range spectrometer  

DOE Patents (OSTI)

A neutron range spectrometer and method for determining the neutron energy spectrum of a neutron emitting source are disclosed. Neutrons from the source are collimnated along a collimation axis and a position sensitive neutron counter is disposed in the path of the collimated neutron beam. The counter determines positions along the collimation axis of interactions between the neutrons in the neutron beam and a neutron-absorbing material in the counter. From the interaction positions, a computer analyzes the data and determines the neutron energy spectrum of the neutron beam. The counter is preferably shielded and a suitable neutron-absorbing material is He-3. The computer solves the following equation in the analysis: ##EQU1## where: N(x).DELTA.x=the number of neutron interactions measured between a position x and x+.DELTA.x, A.sub.i (E.sub.i).DELTA.E.sub.i =the number of incident neutrons with energy between E.sub.i and E.sub.i +.DELTA.E.sub.i, and C=C(E.sub.i)=N .sigma.(E.sub.i) where N=the number density of absorbing atoms in the position sensitive counter means and .sigma. (E.sub.i)=the average cross section of the absorbing interaction between E.sub.i and E.sub.i +.DELTA.E.sub.i.

Manglos, Stephen H. (East Syracuse, NY)

1989-06-06T23:59:59.000Z

150

Photo ion spectrometer  

DOE Patents (OSTI)

A method and apparatus for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected autoionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy.

Gruen, Dieter M. (Downers Grove, IL); Young, Charles E. (Westmont, IL); Pellin, Michael J. (Naperville, IL)

1989-01-01T23:59:59.000Z

151

Photo ion spectrometer  

DOE Patents (OSTI)

A method and apparatus are described for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected auto-ionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy. 8 figs.

Gruen, D.M.; Young, C.E.; Pellin, M.J.

1989-08-08T23:59:59.000Z

152

Facilities: NHMFL 9.4 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation: Characterization of Pine Pellet and Peanut Hull Pyrolysis of Bio-Oils by Negative-Ion Electrospray Ionization Fourier  

E-Print Network (OSTI)

with greater than 1% relative abundance in either phase are shown. Pyrolysis of solid biomass, in this case: Characterization of Pine Pellet and Peanut Hull Pyrolysis of Bio-Oils by Negative-Ion Electrospray Ionization of nitrogen-containing species identified in the peanut hull pyrolysis oil by FT-ICR mass spectrometry

Weston, Ken

153

Pickup for pulse NMR spectrometer  

SciTech Connect

This paper describes a single-coil pickup for a pulse NMR spectrometer. The pickup is alternately connected by rf diode switches to the transmitter (in transmit mode) and to the receiver (in receive mode). The dead time of a receiver with this pickup is less than or equal to 10 usec.

Zaitsev, V.N.; Podsekin, A.K.

1985-01-01T23:59:59.000Z

154

MICE Spectrometer Magnet System Progress  

SciTech Connect

The first magnets for the muon ionization cooling experimentwill be the tracker solenoids that form the ends of the MICE coolingchannel. The primary purpose of the tracker solenoids is to provide auniform 4 T field (to better than +-0.3 percent over a volume that is 1meter long and 0.3 meters in diameter) spectrometer magnet field for thescintillating fiber detectors that are used to analyze the muons in thechannel before and after ionization cooling. A secondary purpose for thetracker magnet is the matching of the muon beam between the rest of theMICE cooling channel and the uniform field spectrometer magnet. Thetracker solenoid is powered by three 300 amp power supplies. Additionaltuning of the spectrometer is provided by a pair of 50 amp power suppliesacross the spectrometer magnet end coils. The tracker magnet will becooled using a pair of 4 K pulse tube coolers that each provide 1.5 W ofcooling at 4.2 K. Final design and construction of the tracker solenoidsbegan during the summer of 2006. This report describes the progress madeon the construction of the tracker solenoids.

Green, Michael A.; Virostek, Steve P.

2007-08-27T23:59:59.000Z

155

Educational Multiwavelength Atomic Emission Spectrometer  

E-Print Network (OSTI)

atomic absorption is the capability for simultaneous multielement analysis. It can be used colleges had acquired atomic absorption instruments by the year 1990.[2] In contrast, atomic emission with the acetylene-air flame source taken from an existing atomic absorption instrument. Two spectrometer units

Nazarenko, Alexander

156

Evaluation of pneumatic nebulization and ns-laser ablation ICP-MS for bulk elemental analysis and 2-dimensional  

E-Print Network (OSTI)

ID: JA-ART-12-2013-050387 Article Type: Paper Date Submitted by the Author: 12-Dec-2013 Complete List Brussels, Belgium.25 Electronic Supplementary Information (ESI) available Introduction The continuously

Claeys, Philippe

157

Elemental fractionation during LA-ICP-MS analysis of silicate glasses: implications for matrix-independent standardization  

E-Print Network (OSTI)

-independent standardization Mabry Gaboardi and Munir Humayun* Received 16th January 2009, Accepted 11th June 2009 First-independent standardization of refractory elements is possible if the internal normalizing element is approximately the same uniform ESRs in transparent samples and matrix-independent standardization of volatiles in transparent

Weston, Ken

158

Uranium isotopic ratio determination in urine using flow-injection ICP-MS: a tool for emergency monitoring  

Science Journals Connector (OSTI)

......Biological monitoring of uranium exposure in south central...determination of low uranium isotopes ratios in small...Carpenter D. O. Depleted uranium contamination by inhalation...implication for human health assessment. Sci. Total......

Maria Luiza D. P. Godoy; Ligia M. Q. C. Julião; José Marcus Godoy

2009-02-01T23:59:59.000Z

159

Inverse time-of-flight spectrometer for beam plasma research  

Science Journals Connector (OSTI)

The paper describes the design and principle of operation of an inverse time-of-flight spectrometer for research in the plasma produced by an electron beam in the forevacuum pressure range (5–20 Pa). In the spectrometer the deflecting plates as well as the drift tube and the primary ion beam measuring system are at high potential with respect to ground. This provides the possibility to measure the mass-charge constitution of the plasma created by a continuous electron beam with a current of up to 300 mA and electron energy of up to 20 keV at forevacuum pressures in the chamber placed at ground potential. Research results on the mass-charge state of the beam plasma are presented and analyzed.

A. V. Tyunkov; K. P. Savkin

2014-01-01T23:59:59.000Z

160

Design of and data reduction from compact Thomson parabola spectrometers  

SciTech Connect

Thomson parabola spectrometers are used to characterize MeV ion beams produced in high intensity laser interactions. These spectrometers disperse multiple ion species according to their charge to mass ratio through the use of parallel electric and magnetic fields. Analytical solutions for ion deflection in electric and magnetic fields have been used to extract ion spectra with the assumption that fringing effects are negligible. Experimental space restrictions and dynamic range requirements necessitate designs that stress the analytical assumptions. Depending on design parameters, the error in the analytical assumption can be comparable to the energy resolution. Estimates are provided to approximate the error on the total ion deflection. A method for modeling ion trajectories including fringing effects is presented using software freely available or in common use. The magnetostatic fields are modeled in 3D, including material properties of nearby magnetic materials using RADIA. Electrostatic fields are modeled in 2D for a spectrometer implementing angled plates using the partial differential equation toolbox in MATLAB. Using these models to calculate the ion trajectory allows for analysis of a Thomson parabola spectrometer with an arbitrary field configuration.

Morrison, J. T.; Willis, C.; Freeman, R. R.; Van Woerkom, L. [Physics Department, Ohio State University, Columbus, Ohio 43210 (United States)

2011-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Standard test method for determination of impurities in nuclear grade uranium compounds by inductively coupled plasma mass spectrometry  

E-Print Network (OSTI)

1.1 This test method covers the determination of 67 elements in uranium dioxide samples and nuclear grade uranium compounds and solutions without matrix separation by inductively coupled plasma mass spectrometry (ICP-MS). The elements are listed in Table 1. These elements can also be determined in uranyl nitrate hexahydrate (UNH), uranium hexafluoride (UF6), triuranium octoxide (U3O8) and uranium trioxide (UO3) if these compounds are treated and converted to the same uranium concentration solution. 1.2 The elements boron, sodium, silicon, phosphorus, potassium, calcium and iron can be determined using different techniques. The analyst's instrumentation will determine which procedure is chosen for the analysis. 1.3 The test method for technetium-99 is given in Annex A1. 1.4 The values stated in SI units are to be regarded as standard. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish ...

American Society for Testing and Materials. Philadelphia

2010-01-01T23:59:59.000Z

162

Characterization of a Sealed Americium-Beryllium (AmBe) Source by Inductively Coupled Plasma Mass Spectrometry  

SciTech Connect

Two Americium-Beryllium neutron sources were dismantled, sampled (sub-sampled) and analyzed via inductively coupled plasma mass spectrometry (ICP-MS). Characteristics such as “age” since purification, actinide content, trace metal content and inter and intra source composition were determined. The “age” since purification of the two sources was determined to be 25.0 and 25.4 years, respectively. The systematic errors in the “age” determination were ± 4 % 2s. The amount and isotopic composition of U and Pu varied substantially between the sub-samples of Source 2 (n=8). This may be due to the physical means of sub-sampling or the way the source was manufactured. Source 1 was much more consistent in terms of content and isotopic composition (n=3 sub-samples). The Be-Am ratio varied greatly between the two sources. Source 1 had an Am-Be ratio of 6.3 ± 52 % (1s). Source 2 had an Am-Be ratio of 9.81 ± 3.5 % (1s). In addition, the trace element content between the samples varied greatly. Significant differences were determined between Source 1 and 2 for Sc, Sr, Y, Zr, Mo, Ba and W.

James Sommers; Marcos Jimenez; Mary Adamic; Jeffrey Giglio; Kevin Carney

2009-12-01T23:59:59.000Z

163

Portable neutron spectrometer and dosimeter  

DOE Patents (OSTI)

The disclosure relates to a battery operated neutron spectrometer/dosimeter utilizing a microprocessor, a built-in tissue equivalent LET neutron detector, and a 128-channel pulse height analyzer with integral liquid crystal display. The apparatus calculates doses and dose rates from neutrons incident on the detector and displays a spectrum of rad or rem as a function of keV per micron of equivalent tissue and also calculates and displays accumulated dose in millirads and millirem as well as neutron dose rates in millirads per hour and millirem per hour.

Waechter, David A. (Los Alamos, NM); Erkkila, Bruce H. (Los Alamos, NM); Vasilik, Dennis G. (Los Alamos, NM)

1985-01-01T23:59:59.000Z

164

Compact reflective imaging spectrometer utilizing immersed gratings  

DOE Patents (OSTI)

A compact imaging spectrometer comprising an entrance slit for directing light, a first mirror that receives said light and reflects said light, an immersive diffraction grating that diffracts said light, a second mirror that focuses said light, and a detector array that receives said focused light. The compact imaging spectrometer can be utilized for remote sensing imaging spectrometers where size and weight are of primary importance.

Chrisp, Michael P. (Danville, CA)

2006-05-09T23:59:59.000Z

165

The Design and Construction of the MICE Spectrometer Solenoids  

SciTech Connect

The purpose of the MICE spectrometer solenoid is to provide a uniform field for a scintillating fiber tracker. The uniform field is produced by a long center coil and two short end coils. Together, they produce 4T field with a uniformity of better than 1% over a detector region of 1000 mm long and 300 mm in diameter. Throughout most of the detector region, the field uniformity is better than 0.3%. In addition to the uniform field coils, we have two match coils. These two coils can be independently adjusted to match uniform field region to the focusing coil field. The coil package length is 2544 mm. We present the spectrometer solenoid cold mass design, the powering and quench protection circuits, and the cryogenic cooling system based on using three cryocoolers with re-condensers.

Wang, Bert; Wahrer, Bob; Taylor, Clyde; Xu, L.; Chen, J. Y.; Wang, M.; Juang, Tiki; Zisman, Michael S.; Virostek, Steve P.; Green, Michael A.

2008-08-02T23:59:59.000Z

166

Progress on the Design and Fabircation of the MICE SpectrometerSolenoids  

SciTech Connect

The Muon Ionization Cooling Experiment (MICE) willdemonstrate ionization cooling in a short section of a realistic coolingchannel using a muon beam at Rutherford Appleton Laboratory (RAL) in theUK. A five-coil, superconducting spectrometer solenoid magnet at each endof the cooling channel will provide a 4 T uniform field region for thescintillating fiber tracker within the magnet bore tubes. The trackermodules are used to measure the muon beam emittance as it enters andexits the cooling channel. The cold mass for the 400 mm warm bore magnetconsists of two sections: a three-coil spectrometer magnet and a two-coilmatching section that matches the uniform field of the solenoid into theMICE cooling channel. The spectrometer solenoid detailed designandanalysis has been completed, and the fabrication of the magnets is wellunder way. The primary features of the spectrometer solenoid magnet andmechanical designs are presented along with a summary of key fabricationissues and photos of the construction.

Virostek, S.P.; Green, M.A.; Lia, D.; Sizman, M.S.

2007-06-20T23:59:59.000Z

167

The High-Acceptance Dielectron Spectrometer HADES  

E-Print Network (OSTI)

HADES is a versatile magnetic spectrometer aimed at studying dielectron production in pion, proton and heavy-ion induced collisions. Its main features include a ring imaging gas Cherenkov detector for electron-hadron discrimination, a tracking system consisting of a set of 6 superconducting coils producing a toroidal field and drift chambers and a multiplicity and electron trigger array for additional electron-hadron discrimination and event characterization. A two-stage trigger system enhances events containing electrons. The physics program is focused on the investigation of hadron properties in nuclei and in the hot and dense hadronic matter. The detector system is characterized by an 85% azimuthal coverage over a polar angle interval from 18 to 85 degree, a single electron efficiency of 50% and a vector meson mass resolution of 2.5%. Identification of pions, kaons and protons is achieved combining time-of-flight and energy loss measurements over a large momentum range. This paper describes the main features and the performance of the detector system.

The HADES Collaboration; G. Agakishiev; A. Balanda; B. Bannier; R. Bassini; D. Belver; A. V. Belyaev; A. Blanco; M. Boehmer; J. L. Boyard; P. Braun-Munzinger; P. Cabanelas; E. Castro; S. Chernenko; T. Christ; M. Destefanis; J. Diaz; F. Dohrmann; A. Dybczak; T. Eberl; W. Enghardt; L. Fabbietti; O. V. Fateev; P. Finocchiaro; P. Fonte; J. Friese; I. Froehlich; T. Galatyuk; J. A. Garzon; R. Gernhaeuser; A. Gil; C. Gilardi; M. Golubeva; D. Gonzalez-Diaz; F. Guber; M. Heilmann; T. Heinz; T. Hennino; R. Holzmann; A. Ierusalimov; I. Iori; A. Ivashkin; M. Jurkovic; B. Kaempfer; K. Kanaki; T. Karavicheva; D. Kirschner; I. Koenig; W. Koenig; B. W. Kolb; R. Kotte; F. Krizek; R. Kruecken; W. Kuehn; A. Kugler; A. Kurepin; S. Lang; J. S. Lange; K. Lapidus; T. Liu; L. Lopes; M. Lorenz; L. Maier; A. Mangiarotti; J. Markert; V. Metag; B. Michalska; J. Michel; D. Mishra; E. Moriniere; J. Mousa; C. Muentz; L. Naumann; J. Otwinowski; Y. C. Pachmayer; M. Palka; Y. Parpottas; V. Pechenov; O. Pechenova; T. PerezCavalcanti; J. Pietraszko; W. Przygoda; B. Ramstein; A. Reshetin; M. Roy-Stephan; A. Rustamov; A. Sadovsky; B. Sailer; P. Salabura; A. Schmah; E. Schwab; Yu. G. Sobolev; S. Spataro; B. Spruck; H. Stroebele; J. Stroth; C. Sturm; M. Sudol; A. Tarantola; K. Teilab; P. Tlusty; M. Traxler; R. Trebac; H. Tsertos; V. Wagner; M. Weber; M. Wisniowski; T. Wojcik; J. Wuestenfel; S. Yurevich; Y. V. Zanevsky; P. Zhou; P. Zumbruch

2009-03-09T23:59:59.000Z

168

The High-Acceptance Dielectron Spectrometer HADES  

E-Print Network (OSTI)

HADES is a versatile magnetic spectrometer aimed at studying dielectron production in pion, proton and heavy-ion induced collisions. Its main features include a ring imaging gas Cherenkov detector for electron-hadron discrimination, a tracking system consisting of a set of 6 superconducting coils producing a toroidal field and drift chambers and a multiplicity and electron trigger array for additional electron-hadron discrimination and event characterization. A two-stage trigger system enhances events containing electrons. The physics program is focused on the investigation of hadron properties in nuclei and in the hot and dense hadronic matter. The detector system is characterized by an 85% azimuthal coverage over a polar angle interval from 18 to 85 degree, a single electron efficiency of 50% and a vector meson mass resolution of 2.5%. Identification of pions, kaons and protons is achieved combining time-of-flight and energy loss measurements over a large momentum range. This paper describes the main featur...

Agakichiev, G; Bannier, B; Bassini, R; Belver, D; Belyaev, A V; Blanco, A; Boehmer, M; Boyard, J L; Braun-Munzinger, P; Cabanelas, P; Castro, E; Chernenko, S; Christ, T; Destefanis, M; Díaz, J; Dohrmann, F; Dybczak, A; Eberl, T; Enghardt, W; Fabbietti, L; Fateev, O V; Finocchiaro, P; Fonte, Paulo J R; Friese, J; Fröhlich, I; Galatyuk, T; Garzón, J A; Gernhäuser, R; Gil1, A; Gilardi, C; Golubeva, M; Gonzalez-Diaz, D; Guber, F; Heilmann, M; Heinz, T; Hennino, T; Holzmann, R; Ierusalimov, A; Iori, I; Ivashkin, A; Jurkovic, M; Kämpfer, B; Kanaki, K; Karavicheva, T; Kirschner, D; König, I; König, W; Kolb, B W; Kotte, R; Krizek, F; Krücken, R; Kühn, W; Kugler, A; Kurepin, A; Lang, S; Lange, J S; Lapidus, K; Liu, T; Lopes, L; Lorenz, M; Maier, L; Mangiarotti, A; Markert, J; Metag, V; Michalska, B; Michel, J; Mishra, D; Moriniere, E; Mousa, J; Müntz, C; Naumann, Lutz; Otwinowski, J; Pachmayer, Y C; Palka, M; Parpottas, Y; Pechenov, V; Pechenova, O; PerezCavalcanti, T; Pietraszko, J; Przygoda, W; Ramstein, B; Reshetin, A; Roy-Stephan, M; Rustamov, A; Sadovskii, A; Sailer, B; Salabura, P; Schmah, A; Schwab, E; Sobolev, Yu G; Spataro, S; Spruck, B; Ströbele, H; Stroth, J; Sturm, C; Sudol, M; Tarantola, A; Teilab, K; Tlustý, P; Traxler, M; Trebac, R; Tsertos, H; Wagner, V; Weber, M; Wisniowski, M; Wojcik, T; Wuestenfel, J; Yurevich, S; Zanevsky, Yu V; Zhou, P; Zumbruch, P

2009-01-01T23:59:59.000Z

169

The Mass Spectrometer as a Detector for Gas Chromatography  

Science Journals Connector (OSTI)

......derivatives of amines were detected in oil-shale process water by use of EIPC plots...bottom trace) from an anlysis of oil shale process water. The value of this...total ion current in the analysis of oil-shale process water for compound-specific......

Michael A. Grayson

1986-12-01T23:59:59.000Z

170

Mass Spectrometer: Linear Ion Trap Quadrupole (LTQ) Orbitrap...  

NLE Websites -- All DOE Office Websites (Extended Search)

Ion Trap Quadrupole (LTQ) Orbitrap MS - for environmental research (nanoDESI) Instrument ID: 34068 Availability: 10 hours a day, 5 days a week Quick Specs Science Contact Science...

171

Fossil packrat middens and the tandem accelerator mass spectrometer  

Science Journals Connector (OSTI)

... glacial standard date (15.7 kyr, A-1581)14. The presence of this low desert shrub in a pinyon-juniper-oak woodland, an anomalous association by current standards, remains ... bigelovii) woodland/chaparral community which presently occurs much higher in elevation than the present Sonoran desert- ...

Thomas R. Van Devender; Paul S. Martin; Robert S. Thompson; Kenneth L. Cole; A. J. Timothy Jull; Austin Long; Laurence J. Toolin; Douglas J. Donahue

1985-10-17T23:59:59.000Z

172

Accurate determination of Curium and Californium isotopic ratios by inductively coupled plasma quadrupole mass spectrometry (ICP-QMS) in 248Cm samples for transmutation studies  

SciTech Connect

The French Atomic Energy Commission has carried out several experiments including the mini-INCA (INcineration of Actinides) project for the study of minor-actinide transmutation processes in high intensity thermal neutron fluxes, in view of proposing solutions to reduce the radiotoxicity of long-lived nuclear wastes. In this context, a Cm sample enriched in {sup 248}Cm ({approx}97 %) was irradiated in thermal neutron flux at the High Flux Reactor (HFR) of the Laue-Langevin Institute (ILL). This work describes a quadrupole ICP-MS (ICP-QMS) analytical procedure for precise and accurate isotopic composition determination of Cm before sample irradiation and of Cm and Cf after sample irradiation. The factors that affect the accuracy and reproducibility of isotopic ratio measurements by ICP-QMS, such as peak centre correction, detector dead time, mass bias, abundance sensitivity and hydrides formation, instrumental background, and memory blank were carefully evaluated and corrected. Uncertainties of the isotopic ratios, taking into account internal precision of isotope ratio measurements, peak tailing, and hydrides formations ranged from 0.3% to 1.3%. This uncertainties range is quite acceptable for the nuclear data to be used in transmutation studies.

Gourgiotis, A.; Isnard, H.; Aubert, M.; Dupont, E.; AlMahamid, I.; Cassette, P.; Panebianco, S.; Letourneau, A.; Chartier, F.; Tian, G.; Rao, L.; Lukens, W.

2011-02-01T23:59:59.000Z

173

Soluble arsenic and selenium species in fly ash/organic waste-amended soils using ion chromatography-inductively coupled plasma mass spectrometry  

SciTech Connect

Mixing coal fly ash with an organic waste increases macronutrient content and may make land application of fly ash a viable disposal alternative. However, trace element chemistry of these mixed waste products warrants investigation. Speciation of As and Se in soil solutions of fly ash-, poultry litter- and sewage sludge-amended soils was determined over a 10-day period by ion chromatography coupled to inductively coupled plasma mass spectrometry (IC-ICP-MS). Detection limits were 0.031, 0.028, 0.051, 0.161, 0.497, and 0.660 {micro}g L{sup {minus}1} for dimethylarsinate (DMA), As(III), monomethylarsonate (MMA), As(V), Se(IV), and Se(VI), respectively. Arsenic was highly water-soluble from poultry litter and appeared to be predominantly As(V). Arsenic(V) was the predominant species in soil amended with two fly ashes. Application of fly ash/poultry litter mixtures increased As solubility and led to the prevalence of DMA as the major As species. DMA concentrations of these soil solutions decreased rapidly over the sampling period relative to As(V), suggesting that DMA readily underwent mineralization in the soil solution. Se(VI) was the predominant soluble Se species in all treatments indicating rapid oxidation of Se(IV) initially solubilized from the fly ashes.

Jackson, B.P.; Miller, W.P. [Univ. of Georgia, Athens, GA (United States). Dept. of Crop and Soil Sciences] [Univ. of Georgia, Athens, GA (United States). Dept. of Crop and Soil Sciences

1999-01-15T23:59:59.000Z

174

SPEC-DOC: A USER'S GUIDE TO SPECTROMETER SOFTWARE  

E-Print Network (OSTI)

SPECTROMETER SOFTWARE S. Sinton, J.R. Garbow, J.L. Ackerman,to Spectrometer Software" S. Sinton, J. R. Garbow, J. L.

Sinton, S.

2008-01-01T23:59:59.000Z

175

Mass spectrometry: analytical capabilities and potentials  

Science Journals Connector (OSTI)

...INSULIN AND OTHER LARGE PEPTIDES, JOURNAL...MASS-SPECTROMETRY OF LARGE, FRAGILE, AND INVOLATILE...APPLICATIONS IN THE AREA OF MOLECULAR MODIFICATIONS...I-127-LABELED PLASMA DESORPTION MASS-SPECTROMETRY...PIONEER VENUS LARGE PROBE NEUTRAL MASS-SPECTROMETER...HORNING, E.C., ATMOSPHERIC-PRESSURE IONIZATION...

RG Cooks; KL Busch; GL Glish

1983-10-21T23:59:59.000Z

176

Visible spectrometer utilizing organic thin film absorption  

E-Print Network (OSTI)

In this thesis, I modeled and developed a spectrometer for the visible wavelength spectrum, based on absorption characteristics of organic thin films. The device uses fundamental principles of linear algebra to reconstruct ...

Tiefenbruck, Laura C. (Laura Christine)

2004-01-01T23:59:59.000Z

177

Optical Calibration For Jefferson Lab HKS Spectrometer  

E-Print Network (OSTI)

In order to accept very forward angle scattering particles, Jefferson Lab HKS experiment uses an on-target zero degree dipole magnet. The usual spectrometer optics calibration procedure has to be modified due to this on-target field. This paper describes a new method to calibrate HKS spectrometer system. The simulation of the calibration procedure shows the required resolution can be achieved from initially inaccurate optical description.

L. Yuan; L. Tang

2005-11-04T23:59:59.000Z

178

Chip-scale quadrupole mass filters for a Micro-Gas Analyzer  

E-Print Network (OSTI)

Mass spectrometers are powerful analytical instruments that serve as the gold standard for chemical analysis. This tool has numerous applications ranging from national security, industrial processing, environmental monitoring, ...

Cheung, Kerry

2009-01-01T23:59:59.000Z

179

Compact Imaging Spectrometer Utilizing Immersed Gratings  

DOE Patents (OSTI)

A compact imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The imaging spectrometer comprises an entrance slit for transmitting light, a system for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the system for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the system for receiving the light and the system for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light through an optical element to the detector array.

Chrisp, Michael P. (Danville, CA); Lerner, Scott A. (Corvallis, OR); Kuzmenko, Paul J. (Livermore, CA); Bennett, Charles L. (Livermore, CA)

2006-03-21T23:59:59.000Z

180

EMSL: Capabilities: Mass Spectrometry: Next-Generation Mass Spectrometry  

NLE Websites -- All DOE Office Websites (Extended Search)

Next-Generation Mass Spectrometry Next-Generation Mass Spectrometry Additional Information Meet the Mass Spectrometry Experts Related EMSL User Projects Mass Spectrometry Tools are Applied to all Science Themes Next-Generation Mass Spectrometry Proteomics Research Resource for Integrative Biology Biological and Environmental Research - PNNL Proteomics PNNL's Biological MS Data and Software Distribution Center Mass Spectrometry brochure EMSL is committed to offering state-of-the-art instruments to its users. At a workshop in January of 2008, EMSL mass spectrometry experts joined experts from many universities, private companies, and government institutions and laboratories at a conference held at the National High Magnetic Field Laboratory in Tallahassee Florida. Workshop participants reviewed the state of the art of high-performance mass spectrometers,

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Lens system for a photo ion spectrometer  

DOE Patents (OSTI)

A lens system in a photo ion spectrometer for manipulating a primary ion beam and ionized atomic component is disclosed. The atomic components are removed from a sample by a primary ion beam using the lens system, and the ions are extracted for analysis. The lens system further includes ionization resistant coatings for protecting the lens system. 8 figs.

Gruen, D.M.; Young, C.E.; Pellin, M.J.

1990-11-27T23:59:59.000Z

182

Lens system for a photo ion spectrometer  

DOE Patents (OSTI)

A lens system in a photo ion spectrometer for manipulating a primary ion beam and ionized atomic component. The atomic components are removed from a sample by a primary ion beam using the lens system, and the ions are extracted for analysis. The lens system further includes ionization resistant coatings for protecting the lens system.

Gruen, Dieter M. (Downers Grove, IL); Young, Charles E. (Westmont, IL); Pellin, Michael J. (Napersville, IL)

1990-01-01T23:59:59.000Z

183

 

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Project installs a new Ortec Detector and LYNX Digital Signal Analyzer and restores the pneumatic Rabbit Sample Delivery system in B-003; Replaces Project installs a new Ortec Detector and LYNX Digital Signal Analyzer and restores the pneumatic Rabbit Sample Delivery system in B-003; Replaces Surface Area Analyzer in C-123 with newer model; Upgrades Carbon/Sulfur (C/S) and Nitrogen/Oxygen (N/O) Analyzers in B-137 to newer models; Installs new Inductively Coupled Plasma- Mass Spectrometer (ICP-MS) in C-150 which requires modification to Chemical Hood Exhaust (CHEX) hoods. Replaces Scanning Electron Microscope (SEM) in C-108. No new gas service routing is required, all gases needed currently exist in the labs. The only new emission source is 0.5 - 0.7 Liter/min of Argon for the new ICP-MS to be installed in C-150. The upgraded C/S and N/O Analyzers in B-137, the Surface Area Analyzer in C-123, and the SEM in C-108 all use the same gases and rates as the old models being replaced.

184

 

NLE Websites -- All DOE Office Websites (Extended Search)

Project installs a new Ortec Detector and LYNX Digital Signal Analyzer and restores the pneumatic Rabbit Sample Delivery system in B-003; Replaces Surface Area Analyzer in C-123 with newer model; Upgrades Carbon/Sulfur (C/S) and Nitrogen/Oxygen (N/O) Analyzers in B-137 to newer models; Installs new Inductively Coupled Plasma- Mass Spectrometer (ICP-MS) in C-150 which requires modification to Chemical Hood Exhaust (CHEX) hoods. Replaces Scanning Electron Microscope (SEM) in C-108. No new gas service routing is required, all gases needed currently exist in the labs. The only new emission source is 0.5 - 0.7 Liter/min of Argon for the new ICP-MS to be installed in C-150. The upgraded C/S and N/O Analyzers in B-137, the Surface Area Analyzer in C-123, and the SEM in C-108 all use the same gases and rates as the old models being replaced.

185

MICROMACHINED FOURIER TRANSFORM SPECTROMETER ON SILICON OPTICAL BENCH PLATFORM  

E-Print Network (OSTI)

MICROMACHINED FOURIER TRANSFORM SPECTROMETER ON SILICON OPTICAL BENCH PLATFORM Kyoungsik Yu1 a miniaturized Fourier transform spectrometer implemented on a silicon optical bench platform. The optical is becoming increasingly important in a number of applications such as environmental monitoring, chemical

Park, Namkyoo

186

High Precision Atomic Mass Spectrometry with Applications to Neutrino Physics, Fundamental Constants and Physical Chemistry.  

E-Print Network (OSTI)

?? The Florida State University single-ion cryogenic Penning trap mass spectrometer has been used to precisely measure the masses of the doublets 76Ge/76Se and 74Ge/74Se… (more)

Mount, Brianna Jane

2010-01-01T23:59:59.000Z

187

Unambiguous mass determination of major stratospheric positive ions  

Science Journals Connector (OSTI)

... with a balloon-borne mass spectrometer, flown on 16 June 1980 with a 100,000m3 stratospheric balloon at mid-latitude (CNES launching base at Gap-Tallard, France, 4433'N). ...

E. Arijs; D. Nevejans; J. Ingels

1980-12-18T23:59:59.000Z

188

Study of elementary reactions with the HADES dielectron spectrometer  

E-Print Network (OSTI)

Results obtained with the HADES dielectron spectrometer at GSI are discussed, with emphasis on dilepton production in elementary reactions.

B. Ramstein

2009-12-14T23:59:59.000Z

189

Study of elementary reactions with the HADES dielectron spectrometer  

E-Print Network (OSTI)

Results obtained with the HADES dielectron spectrometer at GSI are discussed, with emphasis on dilepton production in elementary reactions.

,

2009-01-01T23:59:59.000Z

190

Acceptance and resolution simulation studies for the dielectron spectrometer HADES at GSI  

E-Print Network (OSTI)

Design studies for a second generation Dilepton Spectrometer to be built at the SIS accelerator of GSI are presented. The basic design parameters of this system are specified and the different detector components for charged particle tracking and for lepton identification are described. The geometrical acceptance for lepton pairs is given. Results on single track momentum resolution and on lepton pair mass resolution are reported.

R. Schicker; A. Brenschede; K. Garrow; H. Schoen; A. Balanda; H. Bokemeyer; J. Friese; W. Karig; P. Kienle; W. Koenig; W. Kuehn; F. Lefevre; V. Metag; G. Roche; P. Salabura; A. Schroeter; J. Stroth; H. Tsertos

1996-05-21T23:59:59.000Z

191

Compact imaging spectrometer utilizing immersed gratings  

DOE Patents (OSTI)

A compact imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The imaging spectrometer comprises an entrance slit for transmitting light, means for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the means for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the means for receiving the light and the means for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light to the means for receiving the light, and the means for receiving the light directs the light to the detector array.

Chrisp, Michael P. (Danville, CA); Lerner, Scott A. (Corvallis, OR); Kuzmenko, Paul J. (Livermore, CA); Bennett, Charles L. (Livermore, CA)

2007-07-03T23:59:59.000Z

192

Imaging spectrometer wide field catadioptric design  

DOE Patents (OSTI)

A wide field catadioptric imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The catadioptric design has zero Petzval field curvature. The imaging spectrometer comprises an entrance slit for transmitting light, a system with a catadioptric lens and a dioptric lens for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the system for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the system for receiving the light and the system for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light through the system for receiving the light to the detector array.

Chrisp; Michael P. (Danville, CA)

2008-08-19T23:59:59.000Z

193

Compact, self-contained optical spectrometer  

SciTech Connect

We describe the construction and performance of a self-contained, battery-operated, hand-held optical spectrometer. This unit contains an on-board optical excitation source, miniaturized monochromator, CCD detector, Peltier cooler, LCD display module, and microprocessor control. We demonstrate capabilities for qualitative fluorescence determinations and semiquantitative fluorescence and absorption measurements. Resolution is {lambda}/{delta}{lambda}{approx_equal}1200 at 434 nm. {copyright} {ital 1995 Society for Applied Spectroscopy.}

Baird, W.; Nogar, N.S. [Chemical Sciences and Technology, CST-1 MSJ565, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

1995-11-01T23:59:59.000Z

194

High Mass Accuracy and High Mass Resolving Power FT-ICR Secondary Ion Mass Spectrometry for Biological Tissue Imaging  

SciTech Connect

Biological tissue imaging by secondary ion mass spectrometry has seen rapid development with the commercial availability of polyatomic primary ion sources. Endogenous lipids and other small bio-molecules can now be routinely mapped on the micrometer scale. Such experiments are typically performed on time-of-flight mass spectrometers for high sensitivity and high repetition rate imaging. However, such mass analyzers lack the mass resolving power to ensure separation of isobaric ions and the mass accuracy for exact mass elemental formula assignment. We have recently reported a secondary ion mass spectrometer with the combination of a C60 primary ion gun with a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS) for high mass resolving power, high mass measurement accuracy and tandem mass spectrometry capabilities. In this work, high specificity and high sensitivity secondary ion FT-ICR MS was applied to chemical imaging of biological tissue. An entire rat brain tissue was measured with 150 ?m spatial resolution (75 ?m primary ion spot size) with mass resolving power (m/?m50%) of 67,500 (at m/z 750) and root-mean-square measurement accuracy less than two parts-per-million for intact phospholipids, small molecules and fragments. For the first time, ultra-high mass resolving power SIMS has been demonstrated, with m/?m50% > 3,000,000. Higher spatial resolution capabilities of the platform were tested at a spatial resolution of 20 ?m. The results represent order of magnitude improvements in mass resolving power and mass measurement accuracy for SIMS imaging and the promise of the platform for ultra-high mass resolving power and high spatial resolution imaging.

Smith, Donald F.; Kiss, Andras; Leach, Franklin E.; Robinson, Errol W.; Pasa-Tolic, Ljiljana; Heeren, Ronald M.

2013-07-01T23:59:59.000Z

195

Fast Determination of Arsenic Species and Total Arsenic in Urine by HPLC-ICP-MS: Concentration Ranges for Unexposed German Inhabitants and Clinical Case Studies  

Science Journals Connector (OSTI)

......also recommended low temperatures for storage of the urine samples prior to analysis...wolffish (Anarhichas lupus), which is a seawater fish living in the Northern Atlantic...Microstomus kitt), which is a bottom-living seawater fish from the North Sea and Atlantic......

Peter Heitland; Helmut D. Köster

2008-05-01T23:59:59.000Z

196

Ion mobility spectrometer with virtual aperture grid  

DOE Patents (OSTI)

An ion mobility spectrometer does not require a physical aperture grid to prevent premature ion detector response. The last electrodes adjacent to the ion collector (typically the last four or five) have an electrode pitch that is less than the width of the ion swarm and each of the adjacent electrodes is connected to a source of free charge, thereby providing a virtual aperture grid at the end of the drift region that shields the ion collector from the mirror current of the approaching ion swarm. The virtual aperture grid is less complex in assembly and function and is less sensitive to vibrations than the physical aperture grid.

Pfeifer, Kent B. (Los Lunas, NM); Rumpf, Arthur N. (Albuquerque, NM)

2010-11-23T23:59:59.000Z

197

Compact proton spectrometers for measurements of shock  

SciTech Connect

The compact Wedge Range Filter (WRF) proton spectrometer was developed for OMEGA and transferred to the National Ignition Facility (NIF) as a National Ignition Campaign (NIC) diagnostic. The WRF measures the spectrum of protons from D-{sup 3}He reactions in tuning-campaign implosions containing D and {sup 3}He gas; in this work we report on the first proton spectroscopy measurement on the NIF using WRFs. The energy downshift of the 14.7-MeV proton is directly related to the total {rho}R through the plasma stopping power. Additionally, the shock proton yield is measured, which is a metric of the final merged shock strength.

Mackinnon, A; Zylstra, A; Frenje, J A; Seguin, F H; Rosenberg, M J; Rinderknecht, H G; Johnson, M G; Casey, D T; Sinenian, N; Manuel, M; Waugh, C J; Sio, H W; Li, C K; Petrasso, R D; Friedrich, S; Knittel, K; Bionta, R; McKernan, M; Callahan, D; Collins, G; Dewald, E; Doeppner, T; Edwards, M J; Glenzer, S H; Hicks, D; Landen, O L; London, R; Meezan, N B

2012-05-02T23:59:59.000Z

198

Ultra-high-mass mass spectrometry with charge discrimination using cryogenic detectors  

DOE Patents (OSTI)

An ultra-high-mass time-of-flight mass spectrometer using a cryogenic particle detector as an ion detector with charge discriminating capabilities. Cryogenic detectors have the potential for significantly improving the performance and sensitivity of time-of-flight mass spectrometers, and compared to ion multipliers they exhibit superior sensitivity for high-mass, slow-moving macromolecular ions and can be used as "stop" detectors in time-of-flight applications. In addition, their energy resolving capability can be used to measure the charge state of the ions. Charge discrimination is very valuable in all time-of-flight mass spectrometers. Using a cryogenically-cooled Nb-Al.sub.2 O.sub.3 -Nb superconductor-insulator-superconductor (SIS) tunnel junction (STJ) detector operating at 1.3 K as an ion detector in a time-of-flight mass spectrometer for large biomolecules it was found that the STJ detector has charge discrimination capabilities. Since the cryogenic STJ detector responds to ion energy and does not rely on secondary electron production, as in the conventionally used microchannel plate (MCP) detectors, the cryogenic detector therefore detects large molecular ions with a velocity-independent efficiency approaching 100%.

Frank, Matthias (Berkeley, CA); Mears, Carl A. (Oakland, CA); Labov, Simon E. (Berkeley, CA); Benner, W. Henry (Danville, CA)

1999-01-01T23:59:59.000Z

199

Wide swath imaging spectrometer utilizing a multi-modular design  

DOE Patents (OSTI)

A wide swath imaging spectrometer utilizing an array of individual spectrometer modules in the telescope focal plane to provide an extended field of view. The spectrometer modules with their individual detectors are arranged so that their slits overlap with motion on the scene providing contiguous spatial coverage. The number of modules can be varied to take full advantage of the field of view available from the telescope.

Chrisp, Michael P. (Danville, CA)

2010-10-05T23:59:59.000Z

200

Software Polarization Spectrometer "PolariS"  

E-Print Network (OSTI)

We have developed a software-based polarization spectrometer, PolariS, to acquire full-Stokes spectra with a very high spectral resolution of 61 Hz. The primary aim of PolariS is to measure the magnetic fields in dense star-forming cores by detecting the Zeeman splitting of molecular emission lines. The spectrometer consists of a commercially available digital sampler and a Linux computer. The computer is equipped with a graphics processing unit (GPU) to process FFT and cross-correlation using the CUDA (Compute Unified Device Architecture) library developed by NVIDIA. Thanks to a high degree of precision in quantization of the analog-to-digital converter and arithmetic in the GPU, PolariS offers excellent performances in linearity, dynamic range, sensitivity, bandpass flatness and stability. The software has been released under the MIT License and is available to the public. In this paper, we report the design of PolariS and its performance verified through engineering tests and commissioning observations.

Mizuno, Izumi; Kano, Amane; Kuroo, Makoto; Nakamura, Fumitaka; Kawaguchi, Noriyuki; Shibata, Katsunori M; Kuji, Seisuke; Kuno, Nario

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Electro-optic Phase Grating Streak Spectrometer  

SciTech Connect

The electro-optic phase grating streak spectrometer (EOPGSS) generates a time-resolved spectra equivalent to that obtained with a conventional spectrometer/streak camera combination, but without using a streak camera (by far the more expensive and problematic component of the conventional system). The EOPGSS is based on a phase, rather than an amplitude grating. Further, this grating is fabricated of electro-optic material such as, for example, KD*P, by either etching grooves into an E-O slab, or by depositing lines of the E-O material onto an optical flat. An electric field normal to the grating alters the material’s index of refraction and thus affects a shift (in angle) of the output spectrum. Ramping the voltage streaks the spectrum correspondingly. The streak and dispersion directions are the same, so a second (static, conventional) grating disperses the spectrum in the orthogonal direction to prevent different wavelengths from “overwriting” each other. Because the streaking is done by the grating, the streaked output spectrum is recorded with a time-integrating device, such as a CCD. System model, typical design, and performance expectations will be presented.

Goldin, F. J.

2012-08-02T23:59:59.000Z

202

CX-002883: Categorical Exclusion Determination | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

883: Categorical Exclusion Determination 883: Categorical Exclusion Determination CX-002883: Categorical Exclusion Determination Procure and Install Analytical Chemistry Instrumentation, 773-A (B&C Wings) CX(s) Applied: B3.1 Date: 06/02/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office Project installs a new Ortec Detector and LYNX Digital Signal Analyzer and restores the pneumatic Rabbit Sample Delivery system in B-003; Replaces Surface Area Analyzer in C-123 with newer model; Upgrades Carbon/Sulfur (C/S) and Nitrogen/Oxygen (N/O) Analyzers in B-137 to newer models; Installs new Inductively Coupled Plasma- Mass Spectrometer (ICP-MS) in C-150 which requires modification to Chemical Hood Exhaust (CHEX) hoods. Replaces Scanning Electron Microscope (SEM) in C-108.

203

ORISS Isomer and Isobar Spectrometer and Separator for Study of Exotic Decays  

NLE Websites -- All DOE Office Websites (Extended Search)

ORISS Isomer ORISS Isomer and Isobar Spectrometer and Separator for Study of Exotic Decays A. Piechaczek for the 2 EMIS 2007 UNIRIB Consortium * The purpose is to provide a nuclear research facility at ORNL for consortium members * Consortium members: 3 EMIS 2007 * Our Deliverable is Science - Nuclear Physics * We do research * We give scientific reports at meetings * We train students * UNIRIB, with ORISE and ORAU, provides a university atmosphere in a national laboratory 4 Motivation to build ORISS - Oak Ridge Isomer/Isobar Spectrometer and Separator: * Decay studies often possible from yield considerations, but limited by background from isobaric/isomeric contamination * Need high resolution separator for background suppression ORISS predicted performance: * High mass resolving power, M/∆M

204

2014 TUNL REU PROJECTS 1. Commissioning the Enge Spectrometer...  

NLE Websites -- All DOE Office Websites (Extended Search)

TUNL REU PROJECTS 1. Commissioning the Enge Spectrometer's Focal Plane Detector Advisor: Richard Longland REU Student: Robert Leonard (Georgia Tech) The Enge Split-Pole...

205

A Low Cost Spectrographic Attachment for an Echelle Spectrometer  

Science Journals Connector (OSTI)

The report describes a simple, low cost photographic attachment for an echelle spectrometer. The crossed dispersion prism/echelle grating system provides a high resolution spectrum...

Brackett, John M; Mitchell, Joel C; Vickers, Thomas J

1983-01-01T23:59:59.000Z

206

Making Mobile Measurement Using an EEPS Spectrometer | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Engine Emissions Reduction (DEER) Conference Presentation: TSI Incorporated 2004deerjohnson.pdf More Documents & Publications An Engine Exhaust Particle SizerTM Spectrometer for...

207

High intensity line source for x-ray spectrometer calibration  

SciTech Connect

A high intensity electron-impact x-ray source using a one-dimensional Pierce lens has been built for the purpose of calibrating a bent crystal x-ray spectrometer. This source focuses up to 100 mA of 20-keV electrons to a line on a liquid-cooled anode. The line (which can serve as a virtual slit for the spectrometer) measures approximately 800 ..mu.. x 2 cm. The source is portable and therefore adaptable to numerous types of spectrometer applications. One particular application, the calibration of a high resolution (r = 10/sup 4/) time-resolved cyrstal spectrometer, will be discussed in detail.

Thoe, R.S.

1986-06-01T23:59:59.000Z

208

LANL/Green Star spectrometer tests  

SciTech Connect

The US and Russia have agreed to the joint development of a nondestructive assay system for use to support the dismantlement of nuclear weapons in Russia. This nondestructive assay system will be used to measure plutonium produced by the conversion of Russian nuclear weapons. The NDA system for Russia will be patterned after the ARIES NDA system being constructed at Los Alamos. One goal of the program is to produce an NDA system for use in Russia that maximizes the use of Russian resources to facilitate maintenance and future upgrades. The Green Star SBS50 Single Board Spectrometer system (Green Star Ltd., Moscow, Russia) has been suggested for use as the data acquisition component for gamma ray instruments in the system. Possible uses are for plutonium isotopic analysis and also segmented gamma scanning. Green Star has also developed analysis software for the SBS50. This software, both plutonium isotopic analysis and uranium enrichment analysis, was developed specifically for customs/border inspection applications (low counting rate applications and identification as opposed to quantification) and was not intended for MC and A applications. Because of the relative immaturity of the Green Star plutonium isotopic analysis software (it has been under development for only one year and is patterned after US development circa 1980), it was tentatively agreed, before the tests, that the Russian NDA system would use the Los Alamos PC/FRAM software for plutonium isotopic analysis. However, it was also decided to include the Green Star plutonium isotopic software in the testing, both to quantify its performance for MC and A applications and also to provide additional data to Green Star for further development of their software. The main purpose of the testing was to evaluate the SBS-50 spectrometer as a data acquisition device for use with LANL software.

Sampson, T.E.; Cremers, T.L.; Vo, D.T. [Los Alamos National Lab., NM (United States); Seldiakov, Y.P.; Dorin, A.B.; Kondrashov, M.V. [Green Star, Moscow (Russian Federation); Timoshin, V.I. [VNIINM, Moscow (Russian Federation)

1997-12-01T23:59:59.000Z

209

Compact imaging Bragg spectrometer for fusion devices  

SciTech Connect

A compact imaging x-ray spectrometer has been designed for tokamaks and stellarators to measure the plasma parameters at different spatial chords. It has been optimized for high spectral resolution and high sensitivity. High spectral resolution is obtained by using solid state detectors and minimizing the imaging errors of the spherical crystals. It is shown, that using spherical crystals the solid angle and hence the throughput can be increased significantly, without compromising the spectral resolution. The design is useful for the measurement of the spectra of He- and H-like ions from Si to Kr. The spectral resolution is sufficient for the measurement of plasma parameters. The temporal resolution is high enough for transport studies by gas puff and laser ablation experiments. The design is based on a modified Johann spectrometer mount, utilizing a spherically bent crystal instead of the cylindrically bent crystal in the traditional Johann mount. The astigmatism of the wavelength selective reflection on the spherical crystal is applied to obtain imaging of an extended plasma source on a two-dimensional detector. For each element, a separate crystal is required, only in few cases, a crystal can be used for the spectra of two elements. For the spectra of most of the He-like ions from Si up to Kr, suitable crystal cuts have been found on quartz, silicon and germanium crystals with Bragg angles in a small interval around the design value of 53.5 deg. All of the crystals have the same radius. They are fixed on a rotational table. The distance to the detector is adjusted by an x-y table to fit to the Rowland circle.

Bertschinger, G.; Biel, W.; Jaegers, H.; Marchuk, O. [Institute of Plasma Physics, Forschungszentrum Juelich GmbH, EURATOM Association, Trilateral Euregio Cluster, D-52425 Juelich (Germany)

2004-10-01T23:59:59.000Z

210

An all-cryogenic THz transmission spectrometer P. J. Burkea)  

E-Print Network (OSTI)

An all-cryogenic THz transmission spectrometer P. J. Burkea) and J. P. Eisenstein Condensed Matter contained in a cryogenic environment. Cyclotron emission from a two-dimensional electron gas 2DEG heated microwave to optical frequencies.2 In this article an all-cryogenic spectrometer is presented that bypasses

Eisenstein, Jim

211

Stochastic Heating by ECR as a Novel Means of Background Reduction in the KATRIN Spectrometers  

E-Print Network (OSTI)

The primary objective of the KATRIN experiment is to probe the absolute neutrino mass scale with a sensitivity of 200 meV (90% C.L.) by precision spectroscopy of tritium beta-decay. To achieve this, a low background of the order of 10 mHz in the region of the tritium beta-decay endpoint is required. Measurements with an electrostatic retarding spectrometer have revealed that electrons, arising from nuclear decays in the volume of the spectrometer, are stored over long time periods and thereby act as a major source of background exceeding this limit. In this paper we present a novel active background reduction method based on stochastic heating of stored electrons by the well-known process of electron cyclotron resonance (ECR). A successful proof-of-principle of the ECR technique was demonstrated in test measurements at the KATRIN pre-spectrometer, yielding a large reduction of the background rate. In addition, we have carried out extensive Monte Carlo simulations to reveal the potential of the ECR technique t...

Mertens, S; Bornschein, L; Drexlin, G; Fränkle, F M; Furse, D; Glück, F; Görhardt, S; Krömer, O; Leiber, B; Schlösser, K; Thümmler, T; Wandkowsky, N; Wüstling, S

2012-01-01T23:59:59.000Z

212

Detection Efficiency of a ToF Spectrometer from Heavy-Ion Elastic Recoil Detection  

SciTech Connect

The detection efficiency of a time-of-flight system based on two micro-channel plates (MCP) time zero detectors plus a conventional silicon surface barrier detector was obtained from heavy ion elastic recoil measurements (this ToF spectrometer is mainly devoted to measurements of total fusion cross section of weakly bound projectiles on different mass-targets systems). In this work we have used beams of {sup 7}Li, {sup 16}O, {sup 32}S and {sup 35}Cl to study the mass region of interest for its application to measurements fusion cross sections in the {sup 6,7}Li+{sup 27}Al systems at energies around and above the Coulomb barrier (0.8V{sub B{<=}}E{<=}2.0V{sub B}). As the efficiency of a ToF spectrometer is strongly dependent on the energy and mass of the detected particles, we have covered a wide range of the scattered particle energies with a high degree of accuracy at the lowest energies. The different experimental efficiency curves obtained in that way were compared with theoretical electronic stopping power curves on carbon foils and were applied.

Barbara, E. de; Marti, G. V.; Capurro, O. A.; Fimiani, L.; Mingolla, M. G. [Laboratorio ANDAR, Comision Nacional de Energia Atomica, Av. Gral. Paz 1499, B1650KNA Partido de San Martin, Provincia de Buenos Aires (Argentina); Negri, A. E.; Arazi, A.; Figueira, J. M.; Pacheco, A. J.; Martinez Heimann, D.; Carnelli, P. F. F. [Laboratorio ANDAR, Comision Nacional de Energia Atomica, Av. Gral. Paz 1499, B1650KNA Partido de San Martin, Provincia de Buenos Aires (Argentina); CONICET, Av. Rivadavia 1917, C1033AAJ Ciudad Autonoma de Buenos Aires (Argentina); Fernandez Niello, J. O. [Laboratorio ANDAR, Comision Nacional de Energia Atomica, Av. Gral. Paz 1499, B1650KNA Partido de San Martin, Provincia de Buenos Aires (Argentina); CONICET, Av. Rivadavia 1917, C1033AAJ Ciudad Autonoma de Buenos Aires (Argentina); Universidad Nacional de General San Martin, Ayacucho 2197, B1650BWA Partido de San Martin, Provincia de Buenos Aires (Argentina)

2010-08-04T23:59:59.000Z

213

Development of position-sensitive time-of-flight spectrometer for fission fragment research  

E-Print Network (OSTI)

A position-sensitive, high-resolution time-of-flight detector for fission fragments has been developed. The SPectrometer for Ion DEterminiation in fission Research (SPIDER) is a $2E-2v$ spectrometer designed to measure the mass of light fission fragments to a single mass unit. The time pick-off detector pairs to be used in SPIDER have been tested with $\\alpha$-particles from $^{229}$Th and its decay chain and $\\alpha$-particles and spontaneous fission fragments from $^{252}$Cf. Each detector module is comprised of a thin electron conversion foil, electrostatic mirror, microchannel plates, and delay-line anodes. Particle trajectories on the order of 700 mm are determined accurately to within 0.7 mm. Flight times on the order of 70 ns were measured with 200 ps resolution FWHM. Computed particle velocities are accurate to within 0.06 mm/ns corresponding to precision of 0.5%. An ionization chamber capable of 400 keV energy resolution coupled with the velocity measurements described here will pave the way for modestly efficient measurements of light fission fragments with unit mass resolution.

C. W. Arnold; F. Tovesson; K. Meierbachtol; T. Bredeweg; M. Jandel; H. J. Jorgenson; A. Laptev; G. Rusev; D. W. Shields; M. White; R. E. Blakeley; D. M. Mader; A. A. Hecht

2014-03-06T23:59:59.000Z

214

Determination of particulate lead using aerosol mass spectrometry: MILAGRO/MCMA-2006 observations  

E-Print Network (OSTI)

We report the first measurements of particulate lead (Pb) from Aerodyne Aerosol Mass Spectrometers, which were deployed in and around Mexico City during the Megacity Initiative: Local and Global Research Observations ...

Salcedo, D.

215

BASIS: Backscattering Spectrometer at SNS | ORNL Neutron Sciences  

NLE Websites -- All DOE Office Websites (Extended Search)

Backscattering Spectrometer Backscattering Spectrometer View inside the BAIS tank View inside the BASIS tank. BASIS is a near-backscattering, crystal-analyzer spectrometer that provides very fine energy resolution, as low as 3.0 to 3.5 µeV at the elastic peak (depending on sample size). This requires a long initial guide section of 84 m from moderator to sample in order to achieve the timing resolution necessary for obtaining the desired energy resolution. BASIS provides an excellent dynamic range near the elastic peak of about plus and minus 100 µeV in the standard high-intensity operation regime, which, if needed, could be extended to plus and minus 200 µeV and beyond. The spectrometer is optimized for quasielastic scattering but provides about 0.1% resolution in energy transfers up to ~40 meV; the inelastic excitations need to be

216

Gas Analysis with IR-Diode Laser Spectrometers  

Science Journals Connector (OSTI)

An IR laser diode spectrometer of modular design with micro-processor control is presented. ... It consists of laser source (vibration decoupled refrigerator with temperature control unit and laser power...

Gerhard Schmidtke; Wolfgang Julius Riedel…

1984-01-01T23:59:59.000Z

217

Gas analysis with IR-diode laser spectrometers  

Science Journals Connector (OSTI)

An IR laser diode spectrometer of modular design with micro-processor control is presented. ... It consists of laser source (vibration decoupled refrigerator with temperature control unit and laser power...

Gerhard Schmidtke; Wolfgang Julius Riedel…

1984-01-01T23:59:59.000Z

218

High-resolution spectrometer design using spherically curved crystals  

SciTech Connect

A Bragg crystal spectrometer that has a quartz crystal elastically bent into a segment of a sphere has been successfully constructed and calibrated. The principal advantage of the spherical surface over a cylindrical surface is an increase of almost 3 orders of magnitude in spectral intensity, with no corresponding loss in resolving power. This optical system also possesses good imaging properties. The precision components used in constructing the spectrometer are inexpensive and readily available.

Thoe, R.

1986-09-01T23:59:59.000Z

219

Apparatus and methods for continuous beam fourier transform mass spectrometry  

DOE Patents (OSTI)

A continuous beam Fourier transform mass spectrometer in which a sample of ions to be analyzed is trapped in a trapping field, and the ions in the range of the mass-to-charge ratios to be analyzed are excited at their characteristic frequencies of motion by a continuous excitation signal. The excited ions in resonant motions generate real or image currents continuously which can be detected and processed to provide a mass spectrum.

McLuckey, Scott A. (Oak Ridge, TN); Goeringer, Douglas E. (Oak Ridge, TN)

2002-01-01T23:59:59.000Z

220

The ALICE muon spectrometer: trigger detectors and quarkonia detection in p-p collisions  

E-Print Network (OSTI)

This work was carried out in the context of the optimisation of the performances of the muon spectrometer of the forthcoming ALICE experiment at the Large Hadron Collider (LHC, CERN). The aim of ALICE is the study of nuclear matter at the highest energy densities ever accessed experimentally. More in detail, the focus is on the expected phase transition to a deconfined phase of matter where the degrees of freedom are those of quarks and gluons: the Quark-Gluon Plasma. The conditions for QGP formation are expected to be achieved in highly relativistic heavy ion collisions. The energy in the centre of mass of Pb-Pb collisions at the LHC will be 5.5 TeV per nucleon pair. The ALICE physics program also includes data-taking in p-p collisions at the centre-of-mass-energy of 14 TeV. The ALICE muon spectrometer has been designed for the detection of heavy quarkonia through their muon decay: both theoretical predictions and experimental data obtained at SPS and RHIC indicate that the production of these resonances sho...

Gagliardi, Martino

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Development of position-sensitive time-of-flight spectrometer for fission fragment research  

E-Print Network (OSTI)

A position-sensitive, high-resolution time-of-flight detector for fission fragments has been developed. The SPectrometer for Ion DEterminiation in fission Research (SPIDER) is a $2E-2v$ spectrometer designed to measure the mass of light fission fragments to a single mass unit. The time pick-off detector pairs to be used in SPIDER have been tested with $\\alpha$-particles from $^{229}$Th and its decay chain and $\\alpha$-particles and spontaneous fission fragments from $^{252}$Cf. Each detector module is comprised of a thin electron conversion foil, electrostatic mirror, microchannel plates, and delay-line anodes. Particle trajectories on the order of 700 mm are determined accurately to within 0.7 mm. Flight times on the order of 70 ns were measured with 200 ps resolution FWHM. Computed particle velocities are accurate to within 0.06 mm/ns corresponding to precision of 0.5%. An ionization chamber capable of 400 keV energy resolution coupled with the velocity measurements described here will pave the way for mode...

Arnold, C W; Meierbachtol, K; Bredeweg, T; Jandel, M; Jorgenson, H J; Laptev, A; Rusev, G; Shields, D W; White, M; Blakeley, R E; Mader, D M; Hecht, A A

2014-01-01T23:59:59.000Z

222

Lead Slowing Down Spectrometer Research Plans  

SciTech Connect

The MPACT-funded Lead Slowing Down Spectrometry (LSDS) project has been evaluating the feasibility of using LSDS techniques to assay fissile isotopes in used nuclear fuel assemblies. The approach has the potential to provide considerable improvement in the assay of fissile isotopic masses in fuel assemblies compared to other non-destructive techniques in a direct and independent manner. The LSDS collaborations suggests that the next step to in empirically testing the feasibility is to conduct measurements on fresh fuel assemblies to understand investigate self-attenuation and fresh mixed-oxide (MOX) fuel rodlets so we may betterto understand extraction of masses for 235U and 239Pu. While progressing toward these goals, the collaboration also strongly suggests the continued development of enabling technology such as detector development and algorithm development, thatwhich could provide significant performance benefits.

Warren, Glen A.; Kulisek, Jonathan A.; Gavron, Victor; Danon, Yaron; Weltz, Adam; Harris, Jason; Stewart, T.

2013-03-22T23:59:59.000Z

223

Extending Penning trap mass measurements with SHIPTRAP to the heaviest elements  

SciTech Connect

Penning-trap mass spectrometry of radionuclides provides accurate mass values and absolute binding energies. Such mass measurements are sensitive indicators of the nuclear structure evolution far away from stability. Recently, direct mass measurements have been extended to the heavy elements nobelium (Z=102) and lawrencium (Z=103) with the Penning-trap mass spectrometer SHIPTRAP. The results probe nuclear shell effects at N=152. New developments will pave the way to access even heavier nuclides.

Block, M.; Ackermann, D.; Herfurth, F.; Hofmann, S. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Blaum, K. [Max-Planck-Institut fuer Kernphysik, 69117 Heidelberg, Germany and Ruprecht-Karls-Universitaet, 69120 Heidelberg (Germany); Droese, C.; Marx, G.; Schweikhard, L. [Ernst-Moritz-Arndt-Universitaet, 17487 Greifswald (Germany); Duellmann, Ch. E. [Johannes Gutenberg-Universitaet, 55099 Mainz, Germany and GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Helmholtz-Institut Mainz, 55099 Mainz (Germany); Eibach, M. [Ruprecht-Karls-Universitaet, 69120 Heidelberg, Germany and Johannes Gutenberg-Universitaet, 55099 Mainz (Germany); Eliseev, S. [Max-Planck-Institut fuer Kernphysik, 69117 Heidelberg (Germany); Haettner, E.; Plass, W. R.; Scheidenberger, C. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Justus-Liebig-Universitaet, 35392 Giessen (Germany); Hessberger, F. P. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Helmholtz-Institut Mainz, 55099 Mainz (Germany); Ramirez, E. Minaya [Helmholtz-Institut Mainz, 55099 Mainz, Germany and GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Nesterenko, D. [Petersburg Nuclear Physics Institute, Gatchina, 188300 St. Petersburg (Russian Federation); and others

2013-03-19T23:59:59.000Z

224

ARM - Field Campaign - ASSIST: Atmospheric Sounder Spectrometer for  

NLE Websites -- All DOE Office Websites (Extended Search)

govCampaignsASSIST: Atmospheric Sounder Spectrometer for Infrared govCampaignsASSIST: Atmospheric Sounder Spectrometer for Infrared Spectral Technology Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Campaign : ASSIST: Atmospheric Sounder Spectrometer for Infrared Spectral Technology 2008.07.08 - 2008.07.18 Lead Scientist : Michael Howard For data sets, see below. Description Goals of assist were to intercompare radiance spectra and profile retrievals from a new AERI-like instrument, called "ASSIST" with the SGP site AERI(s) and calculations from Radiosondes measurements. * To bring the ASSIST instrument to the SGP ACRF and perform simultaneous measurements of the sky radiation with those from the AERI. * On relatively cloud-free days, release a special radiosonde at the

225

SPEC-DOC: a user's guide to spectrometer software  

SciTech Connect

SPEC is the name of the operating system designed to control NMR spectrometers. SPEC is actually one large program which handles many functions necessary to control each spectrometer. The SPEC operating system is documented. The general operation of SPEC is discussed, including how to get into the program and how to issue commands. The commands are discussed in detail, as well as the operation of the microprocessor based pulse programmer, spectrometer peripherals, supporting programs, and how to create and load a TEMP program. Appended are details on bootstrapping procedures, hardware specifics, a technical description of SPEC and how to change or recreate it, a description of microcode loading and the procedure for formatting floppies, disks, and recreating RDOS. (LEW)

Sinton, S.; Garbow, J.R.; Ackerman, J.L.; Drobny, G.; Ruben, D.J.; Pines, A.

1983-05-01T23:59:59.000Z

226

Photo-Spectrometer Realized In A Standard Cmos Ic Process  

DOE Patents (OSTI)

A spectrometer, comprises: a semiconductor having a silicon substrate, the substrate having integrally formed thereon a plurality of layers forming photo diodes, each of the photo diodes having an independent spectral response to an input spectra within a spectral range of the semiconductor and each of the photo diodes formed only from at least one of the plurality of layers of the semiconductor above the substrate; and, a signal processing circuit for modifying signals from the photo diodes with respective weights, the weighted signals being representative of a specific spectral response. The photo diodes have different junction depths and different polycrystalline silicon and oxide coverings. The signal processing circuit applies the respective weights and sums the weighted signals. In a corresponding method, a spectrometer is manufactured by manipulating only the standard masks, materials and fabrication steps of standard semiconductor processing, and integrating the spectrometer with a signal processing circuit.

Simpson, Michael L. (Knoxville, TN); Ericson, M. Nance (Knoxville, TN); Dress, William B. (Knoxville, TN); Jellison, Gerald E. (Oak Ridge, TN); Sitter, Jr., David N. (Tucson, AZ); Wintenberg, Alan L. (Knoxville, TN)

1999-10-12T23:59:59.000Z

227

CORELLI: the Elastic Diffuse Scattering Spectrometer at SNS | ORNL Neutron  

NLE Websites -- All DOE Office Websites (Extended Search)

The Elastic Diffuse Scattering Spectrometer The Elastic Diffuse Scattering Spectrometer CORELLI The CORELLI instrument. CORELLI is a statistical chopper spectrometer with energy discrimination. It's designed and optimized to probe complex disorder in crystalline materials through diffuse scattering of single-crystal samples. The momentum transfer ranges from 0.5 to 12 Ã…-1, and the energy of incident neutrons ranges from 10 to 200 meV. This instrument combines the high efficiency of white-beam Laue diffraction with energy discrimination by modulating the beam with a statistical chopper. A cross-correlation method is used to reconstruct the elastic signal from the modulated data. Accurate modeling of the short-range order associated with the diffuse scattering requires measurements over large volumes of three-dimensional reciprocal space, with sufficient momentum

228

Penning trap mass measurements on nobelium isotopes  

SciTech Connect

The Penning trap mass spectrometer SHIPTRAP at GSI Darmstadt allows accurate mass measurements of radionuclides, produced in fusion-evaporation reactions and separated by the velocity filter SHIP from the primary beam. Recently, the masses of the three nobelium isotopes {sup 252-254}No were determined. These are the first direct mass measurements of transuranium elements, which provide new anchor points in this region. The heavy nuclides were produced in cold-fusion reactions by irradiating a PbS target with a {sup 48}Ca beam, resulting in production rates of the nuclei of interest of about one atom per second. In combination with data from decay spectroscopy our results are used to perform a new atomic-mass evaluation in this region.

Dworschak, M.; Block, M.; Ackermann, D.; Herfurth, F.; Hessberger, F. P.; Hofmann, S.; Vorobyev, G. K. [GSI Helmholtzzentrum fuer Schwerionenforschung, D-64291 Darmstadt (Germany); Audi, G. [CSNSM-IN2P3-CNRS, F-91405 Orsay-Campus (France); Blaum, K. [Max-Planck-Institut fuer Kernphysik, D-69117 Heidelberg (Germany); Ruprecht-Karls-Universitaet, D-69120 Heidelberg (Germany); Droese, C.; Marx, G.; Schweikhard, L. [Ernst-Moritz-Arndt-Universitaet, Institut fuer Physik, D-17487 Greifswald (Germany); Eliseev, S.; Ketter, J. [Max-Planck-Institut fuer Kernphysik, D-69117 Heidelberg (Germany); Fleckenstein, T. [Justus-Liebig-Universitaet Giessen, D-35390 Giessen (Germany); Haettner, E.; Plass, W. R.; Scheidenberger, C. [GSI Helmholtzzentrum fuer Schwerionenforschung, D-64291 Darmstadt (Germany); Justus-Liebig-Universitaet Giessen, D-35390 Giessen (Germany); Ketelaer, J. [Johannes Gutenberg-Universitaet, Institut fuer Physik, D-55099 Mainz (Germany); Kluge, H.-J. [GSI Helmholtzzentrum fuer Schwerionenforschung, D-64291 Darmstadt (Germany); Ruprecht-Karls-Universitaet, D-69120 Heidelberg (Germany)

2010-06-15T23:59:59.000Z

229

A sensitive neutron spectrometer for the National Ignition Facility  

SciTech Connect

We are developing a sensitive neutron spectrometer for the National Ignition Facility laser at Livermore. The spectrometer will consist of a 1020 channel single-neutron-interaction time-of-flight detector array fielded 23 m from the neutron-producing target. It will use an existing detector array together with upgraded electronics for improved time resolution. Measurements of neutron yield, ion and electron temperatures, and density-radius product are all possible under certain conditions using one-, two-, or three-step reaction processes. The locations of the most important potential sources of scattered neutron backgrounds are determined as the first step in designing collimation to reduce these backgrounds.

Watt, R. G.; Chrien, R. E.; Klare, K. A.; Murphy, T. J.; Wilson, D. C.; Haan, S.

2001-01-01T23:59:59.000Z

230

Development of multichannel low-energy neutron spectrometer  

SciTech Connect

A multichannel low-energy neutron spectrometer for down-scattered neutron (DSN) measurements in inertial confinement fusion (ICF) experiments has been developed. Our compact-size 256-channel lithium-glass-scintillator-based spectrometer has been implemented and tested in ICF experiments with the GEKKO XII laser. We have performed time calibration of the 256-channel analog-to-digital convertor system used for DSN measurements via X-ray pulse signals. We have clearly observed the DD-primary fusion neutron signal and have successfully studied the detector's impulse response. Our detector is soon to be implemented in future ICF experiments.

Arikawa, Y., E-mail: arikawa-y@ile.osaka-u.ac.jp; Nagai, T.; Abe, Y.; Kojima, S.; Sakata, S.; Inoue, H.; Utsugi, M.; Iwasa, Y.; Sarukura, N.; Nakai, M.; Shiraga, H.; Fujioka, S.; Azechi, H. [Institute of Laser Engineering, Osaka University, 2-6 Yamada-oka, Suita, Osaka (Japan); Murata, T. [Kumamoto University, 2-40-1 Kurokami, Kumamoto 860-8555 (Japan)

2014-11-15T23:59:59.000Z

231

Extraction and Determination of Boron Isotopic Composition in Tourmalines  

Science Journals Connector (OSTI)

Tourmaline is an abundant boron-rich alumosilicate mineral with complex chemistry and rich in Fe, Mg, Al, Si elements. In this study, tourmaline samples were decomposed by alkali fusion method, and then the boron was separated and purified using three different procedures. It was found that both Fe3+ and Al3+ ions, rich in tourmaline samples seriously, which affected the accurate determination of boron concentration by Azomethine-H spectrophotometric method and also caused a loss of boron by specific adsorption when large amount of amorphous hydroxide precipitate formed in ion-exchange columns. The addition of small amount of EDTA can eliminate the influence, but brings serious isobaric interference on boron isotopic analysis by TIMS. Finally, a three-column ion-exchange procedure was established including the first mixed resin column, the peristaltic pump coupled boron specific resin column, and the second mixed resin column, which ensures the full recovery of boron (> 99%) from tourmaline samples with complex matrices. The PTIMS-Cs2BO2+-static double-collection method was established by selecting H3-H4 Faraday cups and optimizing parameters in Zoom Optics (Focus Quad: 15; Dispersion Quad: ?85) in a Triton TI mass spectrometer. The determined average 11B/10B value of NIST SRM 951 standard boron solution was 4.05044±0.00012 (2?, n = 8, 1 ?g B), which was superior to the dynamic collection method in internal/external precision. A ?11B value of ?0.3% for NIST SRM 951 through the same pretreatment procedure was obtained, indicating that there was no isotopic fractionation occurred during the extraction procedure. The comparison of boron isotopic compositions in natural samples by TIMS and MC-ICP-MS after the chemistry procedure indicated that ?11B values determined by the static PTIMS-Cs2BO2+ method were in good agreement with that by MC-ICP-MS.

Xiong YAN; Shao-Yong JIANG; Hai-Zhen WEI; Yan YAN; He-Pin WU; Wei PU

2012-01-01T23:59:59.000Z

232

Explanatory Optimization of Protein Mass Spectrometry via Genetic Search  

E-Print Network (OSTI)

of the mass spectrometer settings that accounts for much of this success. Specifically, the conditions of Wales, Aberystwyth, Ceredigion SY23 3DD, U.K. Optimizing experimental conditions for the effective analy that little or no a priori knowledge of the optimal conditions is available. There is much current interest

Fernandez, Thomas

233

A method for direct, semi-quantitative analysis of gas phase samples using gas chromatography-inductively coupled plasma-mass spectrometry  

SciTech Connect

A new and complete GC–ICP-MS method is described for direct analysis of trace metals in a gas phase process stream. The proposed method is derived from standard analytical procedures developed for ICP-MS, which are regularly exercised in standard ICP-MS laboratories. In order to implement the method, a series of empirical factors were generated to calibrate detector response with respect to a known concentration of an internal standard analyte. Calibrated responses are ultimately used to determine the concentration of metal analytes in a gas stream using a semi-quantitative algorithm. The method was verified using a traditional gas injection from a GC sampling valve and a standard gas mixture containing either a 1 ppm Xe + Kr mix with helium balance or 100 ppm Xe with helium balance. Data collected for Xe and Kr gas analytes revealed that agreement of 6–20% with the actual concentration can be expected for various experimental conditions. To demonstrate the method using a relevant “unknown” gas mixture, experiments were performed for continuous 4 and 7 hour periods using a Hg-containing sample gas that was co-introduced into the GC sample loop with the xenon gas standard. System performance and detector response to the dilute concentration of the internal standard were pre-determined, which allowed semi-quantitative evaluation of the analyte. The calculated analyte concentrations varied during the course of the 4 hour experiment, particularly during the first hour of the analysis where the actual Hg concentration was under predicted by up to 72%. Calculated concentration improved to within 30–60% for data collected after the first hour of the experiment. Similar results were seen during the 7 hour test with the deviation from the actual concentration being 11–81% during the first hour and then decreasing for the remaining period. The method detection limit (MDL) was determined for the mercury by injecting the sample gas into the system following a period of equilibration. The MDL for Hg was calculated as 6.8 ?g · m{sup ? 3}. This work describes the first complete GC–ICP-MS method to directly analyze gas phase samples, and detailed sample calculations and comparisons to conventional ICP-MS methods are provided.

Carter, Kimberly E.; Gerdes, Kirk

2013-07-01T23:59:59.000Z

234

A fourier spectrometer for studying the radiation from Josephson Junctions  

SciTech Connect

The paper describes a Fourier spectrometer designed to study the radiation generated by a Josephson junction in the millimeter and FIR bands with a resolution of {approx}2 GHz in the two-pass mode and {approx}1 GHz in the multipass mode. A feature is that one Josephson junctions operates as both generator and detector at the same time.

Verevkin, A.A.; Il`in, V.A.; Lipatov, A.P. [V.I. Lenin Moscow Pedagogical State Univ., Moscow (Russian Federation)

1995-06-01T23:59:59.000Z

235

Optical system for high resolution spectrometer/monochromator  

DOE Patents (OSTI)

An optical system for use in a spectrometer or monochromator employing a mirror which reflects electromagnetic radiation from a source to converge with same in a plane is disclosed. A straight grooved, varied-spaced diffraction grating receives the converging electromagnetic radiation from the mirror and produces a spectral image for capture by a detector, target or like receiver. 11 figs.

Hettrick, M.C.; Underwood, J.H.

1988-10-11T23:59:59.000Z

236

Compact Catadioptric Imaging Spectrometer Designs Utilizing Immersed Gratings  

DOE Patents (OSTI)

An imaging spectrometer comprising an entrance slit for directing light, a lens that receives said light and reflects said light, a grating that defracts said light back onto said lens which focuses said light, and a detector array that receives said focused light. In one embodiment the grating has rulings immersed into a germanium surface.

Lerner, Scott A. (Livermore, CA)

2006-02-28T23:59:59.000Z

237

Modulated optical solid-state spectrometer applications in plasma diagnostics  

E-Print Network (OSTI)

Modulated optical solid-state spectrometer applications in plasma diagnostics John Howard Plasma A new electro-optically modulated optical solid-state MOSS interferometer has been constructed for the measurement of the low order spectral moments of line emission from optically thin radiant media

Howard, John

238

FINGERPRINTING INORGANIC ARSENIC AND ORGANOARSENIC COMPOUNDS IN IN SITU OIL SHALE RETORT AND PROCESS VOTERS USING A LIQUID CHROMATOGRAPH COUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTOR  

E-Print Network (OSTI)

COUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTORCoupled with an Atomic Absorption Spectrometer as a DetectorcOUPLED WITH AN ATOMIC ABSORPTION SPECTROMETER AS A DETECTOR

Fish, Richard H.

2013-01-01T23:59:59.000Z

239

Results from the NSTX X-ray Crystal Spectrometer  

SciTech Connect

A high-resolution X-ray crystal spectrometer has recently been installed at the National Spherical Torus Experiment to record the satellite spectra of helium-like argon, ArXVII, in the wavelength range from 3.94 to 4.00 {angstrom} for measurements of ion and electron temperatures, and measurements of the ionization equilibrium of argon, which is of interest for studies of ion transport. The instrument presently consists of a spherically bent quartz crystal and a conventional one-dimensional position-sensitive multi-wire proportional counter, but it will soon be upgraded to a new type of X-ray imaging crystal spectrometer by the installation of a large size (10 cm x 30 cm) two-dimensional position-sensitive detector that will allow us to obtain temporally and spatially resolved spectra from an 80 cm high cross-section of the plasma. In its present configuration, the spectrometer has been optimized for high throughput so that it is possible to record spectra with small statistical errors with a time resolution of 10 ms by adding only small, nonperturbing amounts of argon to the plasma. The spectrometer is most valuable for measurements of the ion temperature in the absence of a neutral beam in ohmically heated and radio-frequency heated discharges, when charge exchange recombination spectroscopy does not function. Electron temperature measurements from the satellite-to-resonance line ratios have been important for a quantitative comparison with (and verification of) the Thomson scattering data. The paper will describe the instrumental details of the present and future spectrometer configurations, and present recent experimental results.

M. Bitter; K. Hill; L. Roquemore; P. Beiersdorfer; D. Thorn; Ming Feng Gu

2003-01-14T23:59:59.000Z

240

E-Print Network 3.0 - anti-compton gamma-ray spectrometer Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

compton gamma-ray spectrometer Search Powered by Explorit Topic List Advanced Search Sample search results for: anti-compton gamma-ray spectrometer Page: << < 1 2 3 4 5 > >> 1...

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Cryogenic Fourier spectrometer for measuring trace species in the lower stratosphere  

Science Journals Connector (OSTI)

A cryogenic Fourier transform spectrometer has been built to measure thermal emission of the earth’s limb from a balloon-borne platform. Liquid nitrogen cooling of the spectrometer and...

Brasunas, John C; Kunde, Virgil G; Herath, L W

1988-01-01T23:59:59.000Z

242

Upgrade of the neon soft X-ray spectrometer for Alcator C-Mod  

E-Print Network (OSTI)

In order to study plasma rotation, temperature, and impurity density, a Neon Soft X-ray Spectrometer (NeSoXs) was installed on the Alcator C-Mod tokamak. This spectrometer used a spherically bent mica crystal as the ...

Podpaly, Yuri Anatoly

2007-01-01T23:59:59.000Z

243

E-Print Network 3.0 - alice muon spectrometer Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Search Sample search results for: alice muon spectrometer Page: << < 1 2 3 4 5 > >> 1 (LHC) , 2750 . ALICE, Summary: ., "Stations 4 and 5 of the ALICE muon spectrometer: modular...

244

E-Print Network 3.0 - alice dimuon spectrometer Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Search Sample search results for: alice dimuon spectrometer Page: << < 1 2 3 4 5 > >> 1 (LHC) , 2750 . ALICE, Summary: ., "Stations 4 and 5 of the ALICE muon spectrometer: modular...

245

Mass spectrometer calibration of Cosmic Dust Analyzer Thomas J. Ahrens, Satish C. Gupta,1  

E-Print Network (OSTI)

. Using aluminum alloy as a test sample, each pulse produces a charge of $4.6 pC (mostly Al+1 ), whereas of the instrument. Particles impact a Rh target plate at velocities of 1-100 km/s and produce some 10Ã?8 to 10Ã?5 in the CDA geometry. Employing a multichannel plate detector in this MS yields for Al-Mg-Cu alloy

Stewart, Sarah T.

246

Elastic and Inelastic Polarization Effects Observed with the Argonne Effective Mass Spectrometer  

Science Journals Connector (OSTI)

The Argonne polarized proton beam has been used together...?p??++n we find a left-right production asymmetry of about 40% for ?t ? 0.5 GeV2, independent of energy. Absorbed one-pion-exchange together with quark-m...

D. S. Ayres; D. Cohen; R. Diebold; S. L. Kramer…

1977-01-01T23:59:59.000Z

247

Performance of the Recoil Mass Spectrometer and its Detector Systems at the Holi eld  

E-Print Network (OSTI)

Ridge Institute for Science and Education, Oak Ridge, Tennessee 37831 USA bPhysics Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 USA cDepartment of Physics and Astronomy, Vanderbilt L69 3BX, UK eJoint Institute for Heavy Ion Research, Oak Ridge, Tennessee 37831 USA f

248

Performance of the Recoil Mass Spectrometer and its Detector Systems at the Holifield  

E-Print Network (OSTI)

.­H. Yu b , and E. F. Zganjar k a Oak Ridge Institute for Science and Education, Oak Ridge, Tennessee 37831 USA b Physics Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 USA c Department of Liverpool, P. O. Box 147, Liverpool L69 3BX, UK e Joint Institute for Heavy Ion Research, Oak Ridge

249

Investigation of gamma induced degradation of Amberlite 200 cation resin by mass spectrometer and liquid chromatograph  

E-Print Network (OSTI)

, provisions were made for collecting samples of any gas produced. The irradiated resin was exposed to total 7 8 8 accumulations of 1. 0129X10 , 1. 0215XIO , and 5. 0168X10 Rads in three separate runs. It should be noted that the same amount of demineral.... (December 1977) Albert Antonio Freitag, B. S. , Texas A&M University Chairman of Advisory Committee: Dr. James 8. Smathers Amberlite 200 cation exchange resin was irradiated by gamma 7 8 radiation to doses of 10 to 5X10 Rads. Results of the analysis...

Freitag, Albert Antonio

1977-01-01T23:59:59.000Z

250

The development of an Omegratron plasma ion mass spectrometer for Alcator C-Mod  

SciTech Connect

A new diagnostic device, the Omegatron Probe, has been developed to investigate relative impurity levels and impurity charge state distribution in the Alcator C-Mod Tokamak edge plasma. The Omegatron probe consists of two principal components, a ``front-end`` of independently biased grids, arranged in a gridded energy analyzer fashion and a large collection cavity. Particles enter the probe in a thin ``ribbon`` through a knife-edge slit. The grids provide a means to measure and control the parallel energy distribution of the ions. In the collection cavity, an oscillating electric field is applied perpendicularly to the ambient magnetic field. Ions whose cyclotron frequencies are resonant with this electric field oscillation will gain perpendicular energy and be collected. In this way, the probe can be operated in two modes: first, by fixing the potentials on the grids and sweeping frequencies to obtain a `` Z/m spectrum`` of ion species and second, by fixing the frequency and sweeping the grid potentials to obtain the distribution function of an individual impurity species. The Omegatron probe performed successfully in tests on a Hollow Cathode Discharge (HCD) linear plasma column. It obtained measurements of T{sub e} {approx} 5 eV, T{sub i} (H{sup +}) {approx} 2.0 {plus_minus} 0.2 eV, n{sub 0} {approx} 9 {times} 10{sup 15} m{sup {minus}3}, RMS potential fluctuation levels of {approximately} 0.5 {plus_minus} 0.05 {plus_minus} T{sub e}, and obtained ``Z/m`` spectra for the plasma ions (H{sup +}, H{sub 2}{sup +}, He{sup +}). Additional experiments confirmed the theoretical scalings of the f/{delta}f resolution with the applied electric field and magnetic field strengths. The instrument yielded an absolute level of resolution, f/{delta}f, of approximately 2.5 to 3 times the theoretical values. Finally, the results from the HCD are used to project operation on Alcator C-Mod.

Thomas, E.E. Jr.

1993-05-01T23:59:59.000Z

251

The mass  

Science Journals Connector (OSTI)

The mass of the charged Higgs boson at the 1-loop level is investigated, assuming the CP symmetry to be violated explicitly in the Higgs sector of the minimal supersymmetric standard model (MSSM). It is found that there is a parameter region of the MSSM where the presence of explicit CP violation in the Higgs sector yields negative radiative corrections to the charged Higgs boson mass. Thus, the charged Higgs boson in the MSSM may have as low a mass as 60 GeV at the 1-loop level, if the CP symmetry is violated. This lower bound may be improved by the Higgs search at LEP2, which imposes experimental constraints on the charged Higgs mass, as well as on the masses of the neutral Higgs bosons. Hence, LEP2 can constrain experimentally the charged Higgs mass to be not smaller than 109 GeV under our assumption. In addition, it sets 75 GeV as the lower bound on the mass of the lightest neutral Higgs boson, and 84 GeV for that of the next-to-lightest neutral Higgs boson.

Seung Woo Ham; Sun Kun Oh; Eun Jong Yoo; Hyun Kyu Lee

2001-01-01T23:59:59.000Z

252

Mass Spectroscopic Determination of Photoionization Products  

Science Journals Connector (OSTI)

A radio?frequency mass spectrometer of the Bennett type has been utilized to measure the mass of ions formed by photoionization of several gases by the ultraviolet radiation of a hydrogen discharge. Investigations were performed up to 11.4 electron volts the LiF cutoff. The mass spectra were found to be very simple and usually consisted of only one peak representing the mass of the whole molecule. This has been found to be true for acetone butadiene butene carbon disulfide methyl?ethyl ketone nitric oxide propylene and toluene. Only in the case of butane ethyl acetate and isopropyl alcohol fragment ions have been found. Some of them are even more intense than the parent ions. Undesirable ``secondary spectra '' reported by Lossing and Tanaka can be avoided by grounding of the lithium fluoride window.

Richard F. Herzog; Frederick F. Marmo

1957-01-01T23:59:59.000Z

253

High-accuracy mass measurements of neutron-rich Kr isotopes  

Science Journals Connector (OSTI)

The atomic masses of the neutron-rich krypton isotopes Kr84,86-95 have been determined with the tandem Penning trap mass spectrometer ISOLTRAP with uncertainties ranging from 20 to 220 ppb. The masses of the short-lived isotopes Kr94 and Kr95 were measured for the first time. The masses of the radioactive nuclides Kr89 and Kr91 disagree by 4 and 6 standard deviations, respectively, from the present Atomic-Mass Evaluation database. The resulting modification of the mass surface with respect to the two-neutron separation energies as well as implications for mass models and stellar nucleosynthesis are discussed.

P. Delahaye; G. Audi; K. Blaum; F. Carrel; S. George; F. Herfurth; A. Herlert; A. Kellerbauer; H.-J. Kluge; D. Lunney; L. Schweikhard; C. Yazidjian

2006-09-28T23:59:59.000Z

254

Conversion electrons used to monitor the energy scale of electron spectrometer near tritium endpoint - a simulation study  

E-Print Network (OSTI)

Measurements of the endpoint region of the tritium beta-decay spectrum provides good possibility to determine neutrino mass. This, however, needs a perfect monitoring of the spectrometer energy scale. A parallel measurement of electron line of known energy - in particular the 83mKr conversion K-line - may serve well to this purpose. The 83Rb decaying to 83mKr seems to be a very suitable radioactive source due to its halflife of 86.2 day. In this work, we determine the amount of 83Rb which is necessary for a successful monitoring.

M. Rysavy

2006-01-15T23:59:59.000Z

255

High-precision CO2 isotopologue spectrometer with a difference-frequency-generation laser source  

E-Print Network (OSTI)

High-precision CO2 isotopologue spectrometer with a difference-frequency-generation laser source A precision laser spectrometer for the detection of CO2 isotopes is reported. The spectrometer measures the fundamental absorption signatures of 13 C and 12 C isotopes in CO2 at 4.32 m using a tunable mid-IR laser

256

ARM - Evaluation Product - Airborne Visible/Infrared Imaging Spectrometer  

NLE Websites -- All DOE Office Websites (Extended Search)

ProductsAirborne Visible/Infrared Imaging ProductsAirborne Visible/Infrared Imaging Spectrometer (AVIRIS) Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Evaluation Product : Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) 1997.08.01 - 1997.08.01 Site(s) SGP General Description AVIRIS is an optical sensor that delivers calibrated images of the upwelling spectral radiance in 224 contiguous spectral channels (bands) with wavelengths from 400 to 2500 nanometers. AVIRIS has been flown on two aircraft platforms: a NASA ER-2 jet and the Twin Otter turboprop. The main objective of the AVIRIS project is to identify, measure, and monitor constituents of the Earth's surface and atmosphere based on molecular absorption and particle scattering signatures. Research with

257

Analysis and System Design Framework for Infrared Spatial Heterodyne Spectrometers  

SciTech Connect

The authors present a preliminary analysis and design framework developed for the evaluation and optimization of infrared, Imaging Spatial Heterodyne Spectrometer (SHS) electro-optic systems. Commensurate with conventional interferometric spectrometers, SHS modeling requires an integrated analysis environment for rigorous evaluation of system error propagation due to detection process, detection noise, system motion, retrieval algorithm and calibration algorithm. The analysis tools provide for optimization of critical system parameters and components including : (1) optical aperture, f-number, and spectral transmission, (2) SHS interferometer grating and Littrow parameters, and (3) image plane requirements as well as cold shield, optical filtering, and focal-plane dimensions, pixel dimensions and quantum efficiency, (4) SHS spatial and temporal sampling parameters, and (5) retrieval and calibration algorithm issues.

Cooke, B.J.; Smith, B.W.; Laubscher, B.E.; Villeneuve, P.V.; Briles, S.D.

1999-04-05T23:59:59.000Z

258

Compact Refractive Imaging Spectrometer Designs Utilizing Immersed Gratings  

DOE Patents (OSTI)

A compact imaging spectrometer comprising an entrance slit for directing light, a first means for receiving the light and focusing the light, an immersed diffraction grating that receives the light from the first means and defracts the light, a second means for receiving the light from the immersed diffraction grating and focusing the light, and an image plane that receives the light from the second means

Lerner, Scott A. (Livermore, CA); Bennett, Charles L. (Livermore, CA); Bixler, Jay V. (Oakland, CA); Kuzmenko, Paul J. (Livermore, CA); Lewis, Isabella T. (San Jose, CA)

2005-07-26T23:59:59.000Z

259

Imaging Spectrometer Designs Utilizing Immersed Gratings With Accessible Entrance Slit  

DOE Patents (OSTI)

A compact imaging spectrometer comprises an entrance slit, a catadioptric lens with a mirrored surface, a grating, and a detector array. The entrance slit directs light to the mirrored surface of the catadioptric lens; the mirrored surface reflects the light back through the lens to the grating. The grating receives the light from the catadioptric lens and diffracts the light to the lens away from the mirrored surface. The lens transmits the light and focuses it onto the detector array.

Chrisp, Michael P. (Danville, CA); Lerner, Scott A. (Corvallis, OR)

2006-03-21T23:59:59.000Z

260

An approximately 4. pi. tracking magnetic spectrometer for RHIC  

SciTech Connect

A tracking magnetic spectrometer based on large Time Projection Chambers (TPC) is proposed to measure the momentum of charged particles emerging from the RHIC beam pipe at angles larger than four degrees and to identify the particle type for those beyond fifteen degrees with momenta up to 700 MeV/c, which is a large fraction of the final charged particles emitted by a low rapidity quark-gluon plasma.

Not Available

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Applying Stable Isotope Fractionation Theory to New Systems  

Science Journals Connector (OSTI)

...desktop computer with a 400 MHz G4 processor, and yields...Thiemens M (2000) Atmospheric influence of Earths earliest...collector inductively coupled plasma mass spectrometry (MC-ICP-MS...desktop computer with a 400 MHz G4 processor, and yields...Thiemens M (2000) Atmospheric influence of Earth's...

Edwin A. Schauble

262

Z .Chemical Geology 157 1999 219234 z /Quantifying the platinum group elements PGEs and gold in  

E-Print Network (OSTI)

-mass z /spectrometry USN-ICP-MS James C. Ely ) , Clive R. Neal, James A. O'Neill Jr., Jinesh C. Jain thereof e.g., Alvarez et al., 1980; Kyte et al., 1980, 1985; O'Neill, 1991; Evans et al., .1993, 1995

263

analytica chimica acta 6 2 1 ( 2 0 0 8 ) 140147 available at www.sciencedirect.com  

E-Print Network (OSTI)

homepage: www.elsevier.com/locate/aca Rare earth elements determined in Antarctic ice by inductively Rare earth elements Antarctic ice a b s t r a c t Inductively coupled plasma mass spectrometry (ICP-MS) is a suitable tool for multi-element analysis at low concentration levels. Rare earth element (REE

Howat, Ian M.

264

Overprinting Deformations in Mantle Rocks, Dun Mountain, New Zealand  

E-Print Network (OSTI)

sliding DMOB Dun Mountain Ophiolite Belt EBSD Electron backscatter diffraction HREE Heavy rare earth element ICP-MS Inductively coupled plasma-mass spectrometry LPO Lattice preferred orientation LREE Light rare earth element P Pressure PBS Phase... boundary sliding REE Rare earth element SEM Scanning electron microscopy SPO Shape preferred orientation T Temperature vi TABLE OF CONTENTS Page ABSTRACT...

Donnelly, Sara

2014-04-25T23:59:59.000Z

265

Interface for the rapid analysis of liquid samples by accelerator mass spectrometry  

DOE Patents (OSTI)

An interface for the analysis of liquid sample having carbon content by an accelerator mass spectrometer including a wire, defects on the wire, a system for moving the wire, a droplet maker for producing droplets of the liquid sample and placing the droplets of the liquid sample on the wire in the defects, a system that converts the carbon content of the droplets of the liquid sample to carbon dioxide gas in a helium stream, and a gas-accepting ion source connected to the accelerator mass spectrometer that receives the carbon dioxide gas of the sample in a helium stream and introduces the carbon dioxide gas of the sample into the accelerator mass spectrometer.

Turteltaub, Kenneth; Ognibene, Ted; Thomas, Avi; Daley, Paul F; Salazar Quintero, Gary A; Bench, Graham

2014-02-04T23:59:59.000Z

266

Instrument Series: Mass Spectrometry SPLAT II  

NLE Websites -- All DOE Office Websites (Extended Search)

Mass Spectrometry Mass Spectrometry SPLAT II SPLAT II is a one-of-a-kind single particle mass spectrometer that was designed, constructed, and deployed at EMSL to allow users to precisely characterize the physical and chemical properties of nanoparticles. SPLAT II yields quantitative information on particle physical and chemical properties in the laboratory or in the field-even aboard an aircraft. In the context of EMSL's integrated problem-solving environment, the unique capabilities of SPLAT II enable vital research across a range of scientific fields. Research Applications Fundamental science - characterizing the properties and behavior of matter on the nanoscale Atmospheric chemistry - understanding the processes that control atmospheric aerosol life cycle Climate change - uncovering and helping

267

Noise reduction in negative-ion quadrupole mass spectrometry  

DOE Patents (OSTI)

A quadrupole mass spectrometer (QMS) system having an ion source, quadrupole mass filter, and ion collector/recorder system. A weak, transverse magnetic field and an electron collector are disposed between the quadrupole and ion collector. When operated in negative ion mode, the ion source produces a beam of primarily negatively-charged particles from a sample, including electrons as well as ions. The beam passes through the quadrupole and enters the magnetic field, where the electrons are deflected away from the beam path to the electron collector. The negative ions pass undeflected to the ion collector where they are detected and recorded as a mass spectrum.

Chastagner, Philippe (3134 Natalie Cir., Augusta, GA 30909-2748)

1993-01-01T23:59:59.000Z

268

Focused analyte spray emission apparatus and process for mass spectrometric analysis  

DOE Patents (OSTI)

An apparatus and process are disclosed that deliver an analyte deposited on a substrate to a mass spectrometer that provides for trace analysis of complex organic analytes. Analytes are probed using a small droplet of solvent that is formed at the junction between two capillaries. A supply capillary maintains the droplet of solvent on the substrate; a collection capillary collects analyte desorbed from the surface and emits analyte ions as a focused spray to the inlet of a mass spectrometer for analysis. The invention enables efficient separation of desorption and ionization events, providing enhanced control over transport and ionization of the analyte.

Roach, Patrick J. (Kennewick, WA); Laskin, Julia (Richland, WA); Laskin, Alexander (Richland, WA)

2012-01-17T23:59:59.000Z

269

IR Spectrometer Using 90-degree Off-axis Parabolic Mirrors  

SciTech Connect

A gated spectrometer has been designed for real-time, pulsed infrared (IR) studies at the National Synchrotron Light ource at the Brookhaven National Laboratory. A pair of 90-degree, off-axis parabolic mirrors are used to relay the light from an entrance slit to an output IR recording camera. With an initial wavelength range of 1500–4500 nm required, gratings could not be used in the spectrometer because grating orders would overlap. A magnesium oxide prism, placed between these parabolic mirrors, serves as the dispersion element. The spectrometer is doubly telecentric. With proper choice of the air spacing between the prism and the second parabolic mirror, any spectral region of interest within the InSb camera array’s sensitivity region can be recorded. The wavelengths leaving the second parabolic mirror are collimated, thereby relaxing the camera positioning tolerance. To set up the instrument, two different wavelength (visible) lasers are introduced at the entrance slit and made collinear with the optical axis via flip mirrors. After dispersion by the prism, these two laser beams are directed to tick marks located on the outside housing of the gated IR camera. This provides first-order wavelength calibration for the instrument. Light that is reflected off the front prism face is coupled into a high-speed detector to verify steady radiance during the gated spectral imaging. Alignment features include tick marks on the prism and parabolic mirrors. This instrument was designed to complement singlepoint pyrometry, which provides continuous time histories of a small collection of spots from shock-heated targets.

Robert M. Malone, Richard, G. Hacking, Ian J. McKenna, and Daniel H. Dolan

2008-09-02T23:59:59.000Z

270

HELIOS: A high intensity chopper spectrometer at LANSCE  

SciTech Connect

A proposal to construct a high intensity chopper spectrometer at LANSCE as part of the SPSS upgrade project is discussed. HELIOS will be optimized for science requiring high sensitivity neutron spectroscopy. This includes studies of phonon density of states in small polycrystalline samples, magnetic excitations in quantum magnets and highly correlated electron systems, as well as parametric studies (as a function of pressure, temperature, or magnetic field) of S(Q,{omega}). By employing a compact design together with the use of supermirror guide in the incident flight path the neutron flux at HELIOS will be significantly higher than any other comparable instrument now operating.

Mason, T.E. [Oak Ridge National Lab., TN (United States); Broholm, C. [Johns Hopkins Univ., Baltimore, MD (United States). Dept. of Physics and Astronomy; Fultz, B. [California Inst. of Tech., Pasadena, CA (United States). Dept. of Materials Science] [and others

1998-12-31T23:59:59.000Z

271

A 100-kc modulation system for an EPR microwave spectrometer  

E-Print Network (OSTI)

A 100-kc FIELD MODULATION SYSTEM FOR AN EPR MICROWAVE SPECTROMETER A Thesis By Frank Edwin Stewart Approved as to style and content by: /I i r Chairman of Committee C ead of Dep rtment Member ember August 1964 ACM ONLEDGi PENT... LIST OF FIGURES FIGURE PAGE II-1 Molecular Structure of DPPH 22 II-2 11-3 III-1 IV-1 Hyperfine Splitting in the DPPH EPR Spectrum . 25 Hyperfine Splitting in the Mn EpR Spectrum , . 27 100-kc Field Modulation and Detection System . 4I Typical...

Stewart, Frank Edwin

2012-06-07T23:59:59.000Z

272

A 4. pi. tracking TPC magnetic spectrometer for RHIC  

SciTech Connect

The primary physics objective of the 4{pi} TPC magnetic spectrometer proposal is to search for the Quark-Gluon Plasma. In previous workshops we have discussed what the possible hadronic signatures of such a state of matter would be. Succinctly, the QGP is a direct prediction of non-perturbative QCD. Therefore the question of the existence of this new state of matter bears directly on the validity of non-perturbative QCD. However, since non-perturbative QCD has never been established, it is apparent that what may await us is a host of new phenomena that will go beyond the standard model.

Danby, G.; Eiseman, S.E.; Etkin, A.; Foley, K.J.; Hackenburg, R.W.; Longacre, R.S.; Love, W.A.; Morris, T.W.; Platner, E.D.; Saulys, A.C.; Van Dijk, J.H. (Brookhaven National Lab., Upton, NY (USA)); Lindenbaum, S.J. (Brookhaven National Lab., Upton, NY (USA) City Coll., New York, NY (USA)); Chan, C.S.; Kramer, M.A.; Zhao, K. (City Coll., New York, NY (USA)); Biswas, N.; Kenney, P.; Piekarz, J. (Notre Dame Univ

1990-01-01T23:59:59.000Z

273

PHYSICAL REVIEW C 81, 014607 (2010) Fission fragment mass and energy distributions as a function of incident neutron energy measured  

E-Print Network (OSTI)

of incident neutron energy measured in a lead slowing-down spectrometer C. Romano,1 Y. Danon,1,* R. Block,1 J; published 19 January 2010) A new method of measuring fission fragment mass and energy distributions to measure the neutron-induced fission cross section and fragment mass and energy distributions of 25.3 ± 0

Danon, Yaron

274

Mass-resolved retarding field energy analyzer and its measurement of ion energy distribution in helicon plasma  

E-Print Network (OSTI)

Mass-resolved retarding field energy analyzer and its measurement of ion energy distribution analyzer and a quadrupole mass spectrometer (QMS), has been developed to simultaneously measure the energy) are measured at rf power of 1000 W. The results show that the fairly broad energy distributions of different

Zexian, Cao

275

E-Print Network 3.0 - atomic emission spectrometry Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

to Basics Review Quadrupole ICP-MS: Introduction to Instrumentation, Summary: , such as atomic absorption or atomic emission spectrometry (Willard et al. 1988). Quadrupole ICP-MS...

276

Predicted performance of neutron spectrometers using scintillating fibers  

SciTech Connect

A variety of needs exists for knowing the energy spectral content of a neutron flux. Among these needs are arms-control and national-security applications, which arise because different neutron sources produce different neutron energy spectra. This work is primarily directed at these applications. The concept described herein is a spectrometer in the same sense as a Bonner sphere. The instrument response reflects a statistical average of the energy spectrum. The Bonner sphere is an early rendition of this class. In this, a neutron detector is placed at the center of a moderating (and absorbing) sphere (of varying thickness and composition). Spectral unfolding is required, and the resolution and efficiency are, typically, poor, although the potential bandwidth is very large. A recent variation on the Bonner-sphere approach uses {sup 3}He gas proportional counters with resistive wires to locate the position of the event (Toyokawa et al 1996). The spectrometer concept investigated here has the potential for better resolution and much improved neutron efficiency compared to Bonner spheres and similar devices. These improvements are possible because of the development of neutron-sensitive, scintillating-glass fibers. These fibers can be precisely located in space, which allows a corresponding precision in energy resolution. Also, they can be fabricated into arrays that intercept a large fraction of incident thermal neutrons, providing the improvement in neutron economy.

RA Craig; M Bliss

2000-02-14T23:59:59.000Z

277

Femtosecond photoelectron and photoion spectrometer with vacuum ultraviolet probe pulses  

E-Print Network (OSTI)

We describe a setup to study ultrafast dynamics in gas-phase molecules using time-resolved photoelectron and photoion spectroscopy. The vacuum ultraviolet (VUV) probe pulses are generated via strong field high-order harmonic generation from infrared femtosecond laser pulses. The band pass characteristic in transmission of thin indium (In) metal foil is exploited to isolate the $9^{\\text{th}}$ harmonic of the 800 nm fundamental (H9, 14 eV, 89 nm) from all other high harmonics. The $9^{\\text{th}}$ harmonic is obtained with high conversion efficiencies and has sufficient photon energy to access the complete set of valence electron levels in most molecules. The setup also allows for direct comparison of VUV single-photon probe with 800 nm multi-photon probe without influencing the delay of excitation and probe pulse or the beam geometry. We use a magnetic bottle spectrometer with high collection efficiency for electrons, serving at the same time as a time of flight spectrometer for ions. Characterization measurem...

Koch, Markus; Grilj, Jakob; Sistrunk, Emily; Gühr, Markus

2014-01-01T23:59:59.000Z

278

Measurement of the Surface and Underground Neutron Spectra with the UMD/NIST Fast Neutron Spectrometers.  

E-Print Network (OSTI)

?? The typical fast neutron detector falls into one of two categories, Bonner sphere spectrometers and liquid scintillator proton recoil detectors. These two detector types… (more)

Langford, Thomas J.

2014-01-01T23:59:59.000Z

279

E-Print Network 3.0 - absorption gamma-ray spectrometer Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

by Explorit Topic List Advanced Search Sample search results for: absorption gamma-ray spectrometer Page: << < 1 2 3 4 5 > >> 1 The detection of nitrogen using nuclear...

280

E-Print Network 3.0 - alice photon spectrometer Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Physics Summary: identification for photons, electrons and high momentum hadrons. A di-muon spectrometer system will be installed... of ALICE; direct photon detection, enabling...

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Modified Schwarzschild imaging spectrometer with a low F-number and a long slit  

Science Journals Connector (OSTI)

A modified Schwarzschild imaging spectrometer utilizing three nonconcentric aspheric mirrors and a plane grating is designed that can handle low F-number, long slit, and broad spectral...

Xue, Qingsheng

2013-01-01T23:59:59.000Z

282

An Airborne Spectrometer and Retrieval Development Project for Air Quality Measurements  

Science Journals Connector (OSTI)

The NASA-funded GeoTASO Instrument Incubator project will develop an airborne spectrometer, participate in field campaigns, and test trace gas and aerosol retrieval performance in...

Leitch, James; Valle, Tim; Hardesty, Chuck; Delker, Tom; Baker, Brian; Eskin, Joshua; Chance, Kelly; Liu, Xiong; Janz, Scott; Pickering, Ken; Wang, Jun

283

The Instrumental Function of the X-ray Imaging Crystal Spectrometer...  

NLE Websites -- All DOE Office Websites (Extended Search)

toroidal plasma rotation velocity. The spectrometer consists of two spherically bent crystals and high count rate 'PILATUS II' semi-conductor diode arrays; and it records...

284

SPEC-DOC: A USER'S GUIDE TO SPECTROMETER SOFTWARE  

SciTech Connect

SPEC is the name of the operating system designed to control the NMR spectrometers in lab. SPEC is actually one large program which handles many functions necessary to control each spectrometer. The program handles all I/O with peripheral devices such as the console ('terminal' or 'CRT'). The program carries out its operations by accepting commands which each invoke specific subroutines to perform their function. There are a total of 60 commands in SPEC, each carrying out a different function. Because so many commands make SPEC a very large program, not all of the program is core resident. Rather, each command calls in an overlay handler which loads into memory the appropriate overlay from the disk and begins execution of the command. Thus SPEC is an independent disk based operating system. The commands in SPEC are capable of operating the microprocessor based pulse programmer, starting and acquiring data from the spectrometer data acquisition system, storing data on disk and manipulating it mathematically, displaying and plotting data. All arithmetic operations within SPEC are performed on integers. Since the DATA GENERAL computers are 16 bit machines operating in two's complement mode, the integer range is +32767. Many of the mathematical operations of SPEC are done in double precision integer mode with the final result always scaled to the above range. For many of the commands, integer overflow is detected and reported as an error message. Overflowed points are set to +32767. SPEC accepts command input from the console or reads a string of commands previously entered on the disk. The later command structure is called a macro. Macros may be nested and may have constants passed to them at execution time, thus allowing for a powerful supercommand structure. Both forms of commands are discussed in the next section. SPEC is designed to run on a DATA GENERAL computer with 32K words of memory and a 10Mbyte hard disk system. There are minor differences between the various computers in lab which are discussed in one of the appendices. The disk systems consist of two. 5Mbyte platters, one fixed and one in a removable pack. While running SPEC, all disk I/O is with the fixed disk. All pulse programs, data records, phase box records, etc. reside on the fixed disk. Thus each disk drive is specific to one spectrometer. When running under RDOS (the DG operating system) these disk files may also be accessed. All the source listings of SPEC subroutines, the SPEC program library, and all supporting programs reside on one of the removable packs (labeled 'SPEC'). This pack will normally be in the drive but it is not required to run SPEC. It is required to run any of the supporting programs discussed in another chapter. This manual attempts to document the SPEC operating system and related topics. The following section discusses the general operation of SPEC including how to get into the program and how to issue commands. The following chapters discuss the commands in detail, operation of the microprocessor based pulse programmer, spectrometer peripherals, supporting programs, and how to create and load a 'TEMP' program. The appendices contain details on bootstrapping procedures, hardware specifics, a technical description of SPEC and how to change or recreate it, a description of microcode loading and the procedure for formatting floppy, disks and recreating RDGS.

Sinton, S.

1983-05-01T23:59:59.000Z

285

THE COMPOSITION AND ORIGIN OF HYDROTHERMAL FLUIDS IN A NYF-TYPE GRANITIC PEGMATITE, SOUTH PLATTE DISTRICT, COLORADO: EVIDENCE FROM LA–ICP–MS ANALYSIS OF FLUORITE-AND QUARTZ-HOSTED FLUID INCLUSIONS  

Science Journals Connector (OSTI)

...a F3) et dans la fluorite hydrothermale violette, blanche et incolore (fluides F2 et F4...Windsor Canada 1331 1355 PACROFI VIII Kontak Daniel J. editor Anderson A. J. editor Marshall Daniel D. editor University of Windsor Canada CAMIA6...

Joel E. Gagnon; Iain M. Samson; Brian J. Fryer; Anthony E. Williams-Jones

286

The use of strontium isotope ratio measurements by MC-ICP-MS for fundamental studies on diagenesis and for the reconstruction of animal migration at the Celtic excavation site Roseldorf.  

E-Print Network (OSTI)

??Die Anwendung von Strontiumisotopenmessungen im Bereich der anthropologischen und archäologischen Forschung bietet die Möglichkeit, Aufschlüsse über historische Fragestellungen zu erlangen, die Migrationsbewegungen von Menschen und… (more)

Theiner, Sarah

2011-01-01T23:59:59.000Z

287

A Novel 9.4 Tesla FT-ICR Mass Spectrometer with Improved Sensitivity, Mass Resolution, and Mass Range, for Petroleum Heavy Crude Oil Analysis  

E-Print Network (OSTI)

Range, for Petroleum Heavy Crude Oil Analysis Nathan K. Kaiser, John P. Quinn, Greg T. Blakney NHMFL 9.4 T FT- species in petroleum crude oil and its products, extending to "heavy" crudes for unequivocal identification of sulfur-containing components in petroloeum heavy crude oils. Facilities: NHMFL 9

288

Determining plasma-fueling sources with an end-loss ion spectrometer  

SciTech Connect

To help identify the major sources of fueling gas in Tandem Mirror Experiment-Upgrade (TMX-U), we mounted a mass-sensitive, E parallel to B, end-loss ion spectrometer (ELIS) near the machine's centerline. We set the electric field in the ELIS to simultaneously measure the axial loss currents of both hydrogen and deuterium. We then initiated plasma discharges, where we injected either hydrogen or deuterium gas into the central cell. We also selected and deselected the central-cell neutral beams that were fueled with hydrogen gas. The end-cell neutral beams were always selected and fueled with deuterium. By taking the ratio of the hydrogen end-loss current to the deuterium end-loss current (with a known deuterium-gas feed rate), we were able to infer the effective fueling rates that were due to wall reflux, central-cell beams, and end-cell beams. The results were the following: wall reflux, 6 Torr.l/s; central-cell beams, 15 Torr.l/s; and end-cell beams 1 Torr.l/s. 3 refs., 3 figs., 1 tab.

Grubb, D.P.; Foote, J.H.

1986-03-04T23:59:59.000Z

289

Determining plasma-fueling sources with an end-loss ion spectrometer. Revision 1  

SciTech Connect

To help identify the major sources of fueling gas in Tandem Mirror Experiment-Upgrade (TMX-U), we mounted a mass-sensitive, E parallel B, end-loss ion spectrometer (ELIS) near the machine's centerline. We set the electric field in the ELIS to simultaneously measure the axial loss currents of both hydrogen and deuterium. We then initiated plasma discharges, where we injected either hydrogen or deuterium gas into the central cell. We also selected and deselected the central-cell neutral beams that were fueled with hydrogen gas. The end-cell neutral beams were always selected and fueled with deuterium. By taking the ratio of the hydrogen end-loss current to the deuterium end-loss current (with a known deuterium-gas feed rate), we were able to infer the effective fueling rates that were due to wall reflux, central-cell beams, and end-cell beams. The results were the following: wall reflux, 6 Torr x 1/s; central-cell beams, 15 Torr x 1/s; and end-cell beams 1 Torr x 1/s.

Grubb, D.P.; Foote, J.H.

1986-03-04T23:59:59.000Z

290

Passive Millimeter-Wave Spectrometer for Remote Chemical Detection  

NLE Websites -- All DOE Office Websites (Extended Search)

Closed Captioning Transcript Closed Captioning Transcript Welcome to a demonstration of the Passive Millimeter-Wave Spectrometer for Remote Chemical Detection. The ultimate goal of the project was to detect a hot target gas in front of a cooler background. This setup was eventually tested at the Nevada Test Site. Prior to field test we tested the concept in a laboratory. We simulated the field conditions by simultaneously reducing the two relative temperatures. In this demonstration we will show a room temperature gas (CH3CN) with a cold background (liquid nitrogen). To understand the experiment we will be showing, the first subplot here represents all data channels plotted on a single plot, the second plot represents a two-dimensional representation of the same data, the X axis represents time, the Y axis represents frequency. As the plot is animated later the first and second subplots will have a cross section marker sweep across them.

291

Two wide-angle imaging neutral-atom spectrometers (TWINS)  

SciTech Connect

Two Wide-angle Imaging Neutral-atom Spectrometers (TWINS) is a revolutionary new mission designed to stereoscopically image the magnetosphere in charge exchange neutral atoms for the first time. The authors propose to fly two identical TWINS instruments as a mission of opportunity on two widely-spaced high-altitude, high-inclination US Government spacecraft. Because the spacecraft are funded independently, TWINS can provide a vast quantity of high priority science observations (as identified in an ongoing new missions concept study and the Sun-Earth Connections Roadmap) at a small fraction of the cost of a dedicated mission. Because stereo observations of the near-Earth space environs will provide a particularly graphic means for visualizing the magnetosphere in action, and because of the dedication and commitment of the investigator team to the principles of carrying space science to the broader audience, TWINS will also be an outstanding tool for public education and outreach.

McComas, D.J. [Los Alamos National Lab., NM (United States)] [Los Alamos National Lab., NM (United States); Blake, B. [Aerospace Corp., CA (United States)] [Aerospace Corp., CA (United States); Burch, J. [Southwest Research Inst., San Antonio, TX (United States)] [and others] [Southwest Research Inst., San Antonio, TX (United States); and others

1998-11-01T23:59:59.000Z

292

Isotopic response with small scintillator based gamma-ray spectrometers  

DOE Patents (OSTI)

The intrinsic background of a gamma ray spectrometer is significantly reduced by surrounding the scintillator with a second scintillator. This second (external) scintillator surrounds the first scintillator and has an opening of approximately the same diameter as the smaller central scintillator in the forward direction. The second scintillator is selected to have a higher atomic number, and thus has a larger probability for a Compton scattering interaction than within the inner region. Scattering events that are essentially simultaneous in coincidence to the first and second scintillators, from an electronics perspective, are precluded electronically from the data stream. Thus, only gamma-rays that are wholly contained in the smaller central scintillator are used for analytic purposes.

Madden, Norman W. (Sparks, NV); Goulding, Frederick S. (Lafayette, CA); Asztalos, Stephen J. (Oakland, CA)

2012-01-24T23:59:59.000Z

293

Neutron beam imaging at neutron spectrometers at Dhruva  

SciTech Connect

A low efficiency, 2-Dimensional Position Sensitive Neutron Detector based on delay line position encoding is developed. It is designed to handle beam flux of 10{sup 6}-10{sup 7} n/cm{sup 2}/s and for monitoring intensity profiles of neutron beams. The present detector can be mounted in transmission mode, as the hardware allows maximum neutron transmission in sensitive region. Position resolution of 1.2 mm in X and Y directions, is obtained. Online monitoring of beam images and intensity profile of various neutron scattering spectrometers at Dhruva are presented. It shows better dynamic range of intensity over commercial neutron camera and is also time effective over the traditionally used photographic method.

Desai, Shraddha S.; Rao, Mala N. [Solid State Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400 085 (India)

2012-06-05T23:59:59.000Z

294

Self-contained, hand-held optical spectrometer  

SciTech Connect

The authors describe the design(s) and performance of a self-contained, portable (hand-held) optical spectrometer. The current instrument is based on a miniaturized monochromator, diode array detector, Peltier cooler and microprocessor control. It can be used either in absorption mode, or in a fluorescence-excitation mode (using an on-board UV penlamp). The unit contains an on-board computer, control pad and LCD display, and can write data to a demountable data key. On-board batteries allow operation for up to three hours in data acquisition mode, or up to twenty-four hours in stand-by mode. The instrument may couple to the sample either fiber-optically, or directly with a light-tight coupling unit. The authors also describe second generation instruments incorporating monolithic optical devices and/or interference filters. In general, these instruments can be made more compact, but at some cost in versatility and information content.

Baird, W.; Nogar, N.S. [Los Alamos National Laboratory, NM (United States)

1994-12-31T23:59:59.000Z

295

Search for Antimatter in Space with the Alpha Magnetic Spectrometer  

E-Print Network (OSTI)

The Alpha Magnetic Spectrometer (AMS) is a state of the art particle physics experiment for the extraterrestrial study of antimatter, matter and missing matter. AMS successfully completed the precursor STS91 Discovery flight (June 2nd-12th, 1998), completing 152 orbits at 52 degrees of latitude and about 400 km of height, collecting more than 100 million CR events. In this paper we report on the first flight experience and we present preliminary results on the search for nuclear antimatter. No antimatter nuclei with Z>=2 were detected. We obtain a model dependent upper limit on the anti-He /He flux 2, improving the results of previous published searches performed with stratospheric balloons.

Roberto Battiston

1999-07-12T23:59:59.000Z

296

Two wide-angle imaging neutral-atom spectrometers  

SciTech Connect

The Two Wide-angle Imaging Neutral-atom Spectrometers (TWINS) mission provides a new capability for stereoscopically imaging the magnetosphere. By imaging the charge exchange neutral atoms over a broad energy range (1 < E , {approximately} 100 keV) using two identical instruments on two widely-spaced high-altitude, high-inclination spacecraft, TWINS will enable the 3-dimensional visualization and the resolution of large scale structures and dynamics within the magnetosphere for the first time. These observations will provide a leap ahead in the understanding of the global aspects of the terrestrial magnetosphere and directly address a number of critical issues in the ``Sun-Earth Connections`` science theme of the NASA Office of Space Science.

McComas, D.J.

1997-12-31T23:59:59.000Z

297

Simulation-guided optimization of small-angle analyzer geometry in the neutron backscattering spectrometer SPHERES  

SciTech Connect

The resolution of neutron backscattering spectrometers deteriorates at small scattering angles where analyzers deviate from exact backscattering. By reducing the azimuth angle range of the analyzers, the resolution can be improved with little loss of peak intensity. Measurements at the spectrometer SPHERES are in excellent agreement with simulations, which proves the dominance of geometric effects.

Wuttke, Joachim; Zamponi, Michaela [Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science at MLZ, Lichtenbergstraße 1, 85747 Garching (Germany)] [Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science at MLZ, Lichtenbergstraße 1, 85747 Garching (Germany)

2013-11-15T23:59:59.000Z

298

The data processing pipeline for the Herschel/SPIRE Imaging Fourier Transform Spectrometer  

E-Print Network (OSTI)

The data processing pipeline for the Herschel/SPIRE Imaging Fourier Transform Spectrometer Trevor R the data processing pipeline to generate calibrated data products from the Spectral and Photometric Imaging Receiver (SPIRE) imaging Fourier Transform Spectrometer. The pipeline processes telemetry from SPIRE point

Naylor, David A.

299

Passive Spectroscopy Bolometers, Grating- And X-Ray Imaging Crystal Spectrometers  

SciTech Connect

This tutorial gives a brief introduction into passive spectroscopy and describes the working principles of bolometers, a high-resolution grating spectrometer, and a novel X-ray imaging crystal spectrometer, which is of particular interest for profile measurements of the ion temperature and plasma rotation velocity on ITER and future burning plasma experiments.

Bitter, M; Hill, K W; Scott, S; Paul, S; Ince-Cushmann, A; Reinke, M; Rice, J; Beiersdorfer, P; Gu, M F; Lee, S G; Broennimann, C; Eikenberry, E F

2007-11-07T23:59:59.000Z

300

Laser vaporization/ionization interface for coupling microscale separation techniques with mass spectrometry  

DOE Patents (OSTI)

The present invention provides a laser-induced vaporization and ionization interface for directly coupling microscale separation processes to a mass spectrometer. Vaporization and ionization of the separated analytes are facilitated by the addition of a light-absorbing component to the separation buffer or solvent. 8 figs.

Yeung, E.S.; Chang, Y.C.

1999-06-29T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

CTAX: the US/Japan Cold Neutron Triple-Axis Spectromete at HFIR | ORNL  

NLE Websites -- All DOE Office Websites (Extended Search)

CTAX-US/Japan Cold Neutron Triple-Axis Spectrometer CTAX-US/Japan Cold Neutron Triple-Axis Spectrometer CTAX US/Japan Cold Neutron Triple-Axis Spectrometer (CG-4C). (larger image) The U.S.-Japan Cold Neutron Triple-Axis Spectrometer (CTAX) is a conventional triple-axis spectrometer with variable incident energy and variable monochromator-sample and sample-analyzer distances. The cold guide 4 bender and guide hall shielding reduce background levels at CG-4C, and the 15-cm-tall guide profile is well exploited by CG-4C's vertically focusing monochromator (PG 002). To enhance accommodation of strong magnetic fields at the sample position and to simplify future polarization analysis, the amount of ferromagnetic material has been minimized in the construction of this instrument. CG-4C is a collaboration of Oak Ridge National Laboratory, the Neutron

302

Echelle grating multi-order imaging spectrometer utilizing a catadioptric lens  

DOE Patents (OSTI)

A cryogenically cooled imaging spectrometer that includes a spectrometer housing having a first side and a second side opposite the first side. An entrance slit is on the first side of the spectrometer housing and directs light to a cross-disperser grating. An echelle immersions grating and a catadioptric lens are positioned in the housing to receive the light. A cryogenically cooled detector is located in the housing on the second side of the spectrometer housing. Light from the entrance slit is directed to the cross-disperser grating. The light is directed from the cross-disperser grating to the echelle immersions grating. The light is directed from the echelle immersions grating to the cryogenically cooled detector on the second side of the spectrometer housing.

Chrisp, Michael P; Bowers, Joel M

2014-05-27T23:59:59.000Z

303

²?²Cf-plasma desorption mass spectrometry of RNA nucleosides  

E-Print Network (OSTI)

~ CH5 + CH3 CH3 + CH4 ~ C2H5 + H2 Proton or hydride transfer reactions of these secondary ions with the sample molecule produce the major portion of the CI mass spectra. Because the molecular ions are formed by these chemical reactions... low, and co'1'lisional deactivation between sample fons and air molecules results in a loss of intensity and resolution for the sample ions detected. -7 The vacuum in the mass spectrometer is maintained in the 10 16 torr region by a Sargent...

Piper, Duane Gilbert

1976-01-01T23:59:59.000Z

304

ONE-DIMENSIONAL MODELING FOR TEMPERATURE-DEPENDENT UPFLOW IN THE DIMMING REGION OBSERVED BY HINODE/EUV IMAGING SPECTROMETER  

SciTech Connect

We previously found a temperature-dependent upflow in the dimming region following a coronal mass ejection observed by the Hinode EUV Imaging Spectrometer (EIS). In this paper, we reanalyzed the observations along with previous work on this event and provided boundary conditions for modeling. We found that the intensity in the dimming region dramatically drops within 30 minutes from the flare onset, and the dimming region reaches the equilibrium stage after {approx}1 hr. The temperature-dependent upflows were observed during the equilibrium stage by EIS. The cross-sectional area of the flux tube in the dimming region does not appear to expand significantly. From the observational constraints, we reconstructed the temperature-dependent upflow by using a new method that considers the mass and momentum conservation law and demonstrated the height variation of plasma conditions in the dimming region. We found that a super-radial expansion of the cross-sectional area is required to satisfy the mass conservation and momentum equations. There is a steep temperature and velocity gradient of around 7 Mm from the solar surface. This result may suggest that the strong heating occurred above 7 Mm from the solar surface in the dimming region. We also showed that the ionization equilibrium assumption in the dimming region is violated, especially in the higher temperature range.

Imada, S.; Shimizu, T. [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, Chuo-ku, Sagamihara-shi, Kanagawa 252-5210 (Japan); Hara, H.; Watanabe, T. [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka-shi, Tokyo 181-8588 (Japan); Murakami, I. [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki, Gifu 509-5292 (Japan); Harra, L. K. [UCL-Mullard Space Science Laboratory, Holmbury St Mary, Dorking, Surrey, RH5 6NT (United Kingdom); Zweibel, E. G. [Department of Astronomy, University of Wisconsin-Madison, 475 N Charter Street, Madison, WI 53706 (United States)

2011-12-10T23:59:59.000Z

305

Developing in-spectrometer photochemistry and integration of...  

NLE Websites -- All DOE Office Websites (Extended Search)

as an excitation source on a time-of-flight secondary ion mass spectrometry system (ToF-SIMS) for understanding molecular distribution on the surface. Using these capabilities, N3,...

306

Analytical Chemistry Division annual progress report for period ending December 31, 1991  

SciTech Connect

The following sentences highlight some of the technical activities carried out during 1991. They illustrate the diversity of programs and technical work performed within the Analytical Chemistry Division. Our neutron activation analysis laboratory at HFIR was placed into operation during 1991. We have combined inductively coupled plasma mass spectrometry (ICP/MS) with a preparation procedure developed at the Argonne National Laboratory to measure ultra-trace levels of U, Pu, Np, and Am in body fluids, primarily urine. Much progress has been made over the last year in the interfacing of an rf-powered glow discharge source to a double-focusing mass spectrometer. Preliminary experiments using electrospray ionization combined with ion trap mass spectrometry show much promise for the analysis of metals in solution. A secondary ion microprobe has been constructed that permits determination of the distribution of organic compounds less than a monolayer thick on samples as large as 1 cm diameter. Fourier transform mass spectrometry has been demonstrated to be a highly effective tool for the detailed characterization of biopolymers, especially normal and modified oligonucleotides. Much has been accomplished in understanding the fundamentals of quadrupole ion trap mass spectrometry. Work with ITMS instrumentation has led to the development of rapid methods for the detection of trace organics in environmental and physiological samples. A new type of time-of-flight mass spectrometer was designed for use with our positron ionization experiments. Fundamental research on chromatography at high concentrations and on gas-solid adsorption has continued. The preparation of a monograph on the chemistry of environmental tobacco smoke was completed this year.

NONE

1992-01-01T23:59:59.000Z

307

Development of two-grating spectrometer for the charge exchange spectroscopy system on KSTAR  

SciTech Connect

The charge exchange spectroscopy (CES) system on Korea Superconducting Tokamak Advanced Research (KSTAR) was installed last year and had been applied to measure the C VI ion temperature and rotation velocity profiles. The ion temperature and rotation velocity profiles had been estimated from the C VI 5290.5 A (n = 8-7) charge-exchange spectrum signal measured by a Czerny-Turner type spectrometer and a thinned back-illuminated charge coupled device (CCD) camera. However, the Czerny-Turner type spectrometer used for the KSTAR CES system showed so low signal to noise ratio for KSTAR plasmas in the 2010 experimental campaign that the time resolution of the CES system had been limited to 100 ms due to the increased exposure time of the attached CCD camera. Then, new two-grating spectrometer had been developed in order to improve the time resolution of the CES system. The spectrometer consists of two gratings (1200 g/mm and 1800 g/mm each) with additive configuration, concave mirrors (f = 50 cm), and a cylindrical lens (f = 50 cm). The time resolution of the CES system increases by a factor of 2-4 with the two-grating spectrometer. The C VI ion temperature and rotation velocity profiles obtained by the two-grating spectrometer are compared to those by Czerny-Turner type spectrometer in this paper.

Lee, Hyungho [Department of Nuclear Fusion and Plasma Science, University of Science and Technology (UST), Gajungro 217, Daejeon 305-350 (Korea, Republic of); National Fusion Research Institute (NFRI), Gwahangno113, Daejeon 305-333 (Korea, Republic of); Song, Eun-ji; Oh, Soo-ghee [Division of Energy Systems Research, Ajou University, Suwon 443-749 (Korea, Republic of); Park, Young-dong [Department of Chemistry, Ajou University, Suwon 443-749 (Korea, Republic of); Ko, Won-Ha [National Fusion Research Institute (NFRI), Gwahangno113, Daejeon 305-333 (Korea, Republic of)

2011-06-15T23:59:59.000Z

308

Upgrades of the high resolution imaging x-ray crystal spectrometers on experimental advanced superconducting tokamak  

SciTech Connect

Two imaging x-ray crystal spectrometers, the so-called 'poloidal' and 'tangential' spectrometers, were recently implemented on experimental advanced superconducting tokamak (EAST) to provide spatially and temporally resolved impurity ion temperature (T{sub i}), electron temperature (T{sub e}) and rotation velocity profiles. They are derived from Doppler width of W line for Ti, the intensity ratio of Li-like satellites to W line for Te, and Doppler shift of W line for rotation. Each spectrometer originally consisted of a spherically curved crystal and a two-dimensional multi-wire proportional counter (MWPC) detector. Both spectrometers have now been upgraded. The layout of the tangential spectrometer was modified, since it had to be moved to a different port, and the spectrometer was equipped with two high count rate Pilatus detectors (Model 100 K) to overcome the count rate limitation of the MWPC and to improve its time resolution. The poloidal spectrometer was equipped with two spherically bent crystals to record the spectra of He-like and H-like argon simultaneously and side by side on the original MWPC. These upgrades are described, and new results from the latest EAST experimental campaign are presented.

Lu, B.; Wang, F.; Fu, J.; Li, Y.; Wan, B. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, Anhui (China); Shi, Y. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, Anhui (China); National Fusion Research Institute, 52 Eoeun-Dong, Yusung-Gu, Daejeon (Korea, Republic of); Bitter, M.; Hill, K. W. [Princeton Plasma Physics Laboratory, MS37-B332, Princeton, New Jersey 08543-0451 (United States); Lee, S. G. [National Fusion Research Institute, 52 Eoeun-Dong, Yusung-Gu, Daejeon (Korea, Republic of)

2012-10-15T23:59:59.000Z

309

THE COSMIC INFRARED BACKGROUND EXPERIMENT (CIBER): THE LOW RESOLUTION SPECTROMETER  

SciTech Connect

Absolute spectrophotometric measurements of diffuse radiation at 1 {mu}m to 2 {mu}m are crucial to our understanding of the radiative content of the universe from nucleosynthesis since the epoch of reionization, the composition and structure of the zodiacal dust cloud in our solar system, and the diffuse galactic light arising from starlight scattered by interstellar dust. The Low Resolution Spectrometer (LRS) on the rocket-borne Cosmic Infrared Background Experiment is a {lambda}/{Delta}{lambda} {approx} 15-30 absolute spectrophotometer designed to make precision measurements of the absolute near-infrared sky brightness between 0.75 {mu}m <{lambda} < 2.1 {mu}m. This paper presents the optical, mechanical, and electronic design of the LRS, as well as the ground testing, characterization, and calibration measurements undertaken before flight to verify its performance. The LRS is shown to work to specifications, achieving the necessary optical and sensitivity performance. We describe our understanding and control of sources of systematic error for absolute photometry of the near-infrared extragalactic background light.

Tsumura, K.; Arai, T.; Matsumoto, T.; Matsuura, S.; Murata, K. [Department of Space Astronomy and Astrophysics, Institute of Space and Astronoutical Science (ISAS), Japan Aerospace Exploration Agency (JAXA), Sagamihara, Kanagawa 252-5210 (Japan); Battle, J.; Bock, J. [Jet Propulsion Laboratory (JPL), National Aeronautics and Space Administration (NASA), Pasadena, CA 91109 (United States); Brown, S.; Lykke, K.; Smith, A. [Optical Technology Division, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States); Cooray, A. [Center for Cosmology, University of California, Irvine, Irvine, CA 92697 (United States); Hristov, V.; Levenson, L. R.; Mason, P. [Department of Astronomy, California Institute of Technology, Pasadena, CA 91125 (United States); Keating, B.; Renbarger, T. [Department of Physics, University of California, San Diego, San Diego, CA 92093 (United States); Kim, M. G. [Department of Physics and Astronomy, Seoul National University, Seoul 151-742 (Korea, Republic of); Lee, D. H.; Nam, U. W. [Korea Astronomy and Space Science Institute (KASI), Daejeon 305-348 (Korea, Republic of); Sullivan, I., E-mail: tsumura@ir.isas.jaxa.jp [Department of Physics, The University of Washington, Seattle, WA 98195 (United States); and others

2013-08-15T23:59:59.000Z

310

E-Print Network 3.0 - airborne gamma-ray spectrometer Sample...  

NLE Websites -- All DOE Office Websites (Extended Search)

Powered by Explorit Topic List Advanced Search Sample search results for: airborne gamma-ray spectrometer Page: << < 1 2 3 4 5 > >> 1 GAMMA RAYS FROM MAJOR ELEMENTS BY THERMAL...

311

E-Print Network 3.0 - axis neutron spectrometer Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

results for: axis neutron spectrometer Page: << < 1 2 3 4 5 > >> 1 For more information: Neutron Scattering Science User Office, neutronusers@ornl.gov or (865) 574-4600. Summary:...

312

Testing and Performance of Two-Dimensional Optical Array Spectrometers with Greyscale  

Science Journals Connector (OSTI)

Two laboratory optical array spectrometers with greyscale were evaluated for their sizing, depth of field and timing performance; these three factors are necessary to calculate concentrations and liquid water contents. The probes were of 10 and ...

Paul Joe; Roland List

1987-03-01T23:59:59.000Z

313

Bradbury-Nielsen vs. Field switching shutters for high resolution drift tube ion mobility spectrometers  

Science Journals Connector (OSTI)

A key component in the design of every drift tube ion mobility spectrometer (IMS) is the ion shutter which controls the injection of ions into the drift tube. Especially, compact drift tube IMS require very short...

Ansgar T. Kirk; Stefan Zimmermann

2014-12-01T23:59:59.000Z

314

E-Print Network 3.0 - atomic absorption spectrometer Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic absorption spectrometer Page: << < 1 2 3 4 5 > >> 1 In the post-genome era, the...

315

Development of a compact quantum cascade laser spectrometer for field measurements of CO2 isotopes  

Science Journals Connector (OSTI)

We report the development of a field-deployable, pulsed quantum cascade laser spectrometer. The instrument is designed to measure...13C/12C isotopic ratio in the CO2 released from volcanic vents. Specific 12CO2 a...

D. Weidmann; G. Wysocki; C. Oppenheimer; F.K. Tittel

2005-02-01T23:59:59.000Z

316

E-Print Network 3.0 - atlas muon spectrometer Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: atlas muon spectrometer Page: << < 1 2 3 4 5 > >> 1 Vol. 38 (2007) ACTA PHYSICA POLONICA B...

317

A Soft X-ray Spectrometer using a Highly Dispersive Multilayer Grating  

SciTech Connect

There is a need for higher resolution spectrometers as a tool for inelastic x-ray scattering. Currently, resolving power around R = 10,000 is advertised. Measured RIXS spectra are often limited by this instrumental resolution and higher resolution spectrometers using conventional gratings would be prohibitively large. We are engaged in a development program to build blazed multilayer grating structures for diffracting soft x-rays in high order. This leads to spectrometers with dispersion much higher than is possible using metal coated-gratings. The higher dispersion then provides higher resolution and the multilayer gratings are capable of operating away from grazing incidence as required. A spectrometer design is presented with a total length 3.8 m and capable of 10{sup 5} resolving power.

Warwick, Tony; Padmore, Howard; Voronov, Dmitriy; Yashchuk, Valeriy [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, CA94720 (United States)

2010-06-23T23:59:59.000Z

318

Superconducting gamma and fast-neutron spectrometers with high energy resolution  

DOE Patents (OSTI)

Superconducting Gamma-ray and fast-neutron spectrometers with very high energy resolution operated at very low temperatures are provided. The sensor consists of a bulk absorber and a superconducting thermometer weakly coupled to a cold reservoir, and determines the energy of the incident particle from the rise in temperature upon absorption. A superconducting film operated at the transition between its superconducting and its normal state is used as the thermometer, and sensor operation at reservoir temperatures around 0.1 K reduces thermal fluctuations and thus enables very high energy resolution. Depending on the choice of absorber material, the spectrometer can be configured either as a Gamma-spectrometer or as a fast-neutron spectrometer.

Friedrich, Stephan (San Jose, CA); , Niedermayr, Thomas R. (Oakland, CA); Labov, Simon E. (Berkeley, CA)

2008-11-04T23:59:59.000Z

319

Calibration of a gated flat field spectrometer as a function of x-ray intensity  

SciTech Connect

We present an experimental determination of the response of a gated flat-field spectrometer at the Shenguang-II laser facility. X-rays were emitted from a target that was heated by laser beams and then were divided into different intensities with a step aluminum filter and collected by a spectrometer. The transmission of the filter was calibrated using the Beijing Synchrotron Radiation Facility. The response characteristics of the spectrometer were determined by comparing the counts recorded by the spectrometer with the relative intensities of the x-rays transmitted through the step aluminum filter. The response characteristics were used to correct the transmission from two shots of an opacity experiment using the same samples. The transmissions from the two shots are consistent with corrections, but discrepant without corrections.

Xiong, Gang; Yang, Guohong; Li, Hang; Zhang, Jiyan, E-mail: zhangjiyanzjy@sina.com; Zhao, Yang; Hu, Zhimin; Wei, Minxi; Qing, Bo; Yang, Jiamin; Liu, Shenye; Jiang, Shaoen [Research Center of Laser Fusion, China Academy of Engineering Physics, P. O. Box 919-986, Mianyang 621900 (China)] [Research Center of Laser Fusion, China Academy of Engineering Physics, P. O. Box 919-986, Mianyang 621900 (China)

2014-04-15T23:59:59.000Z

320

A simple scanning spectrometer based on a stretchable elastomeric reflective grating  

SciTech Connect

We report a scanning optical spectrometer based on the use of a stretchable elastomeric reflective grating. The grating is obtained by supersonic cluster beam implantation of silver nanoparticles on polydimethylsiloxane previously grooved by molding to create a replica of a commercial digital versatile disk grating. The use of a stretchable grating allows the spectrometer spanning the whole optical wavelength range by solely extending the diffraction element by more than 100% of its original dimensions. The stretchable reflective optical grating shows excellent performances and stability upon thousands of stretching cycles. The use of this elastomeric element makes the optical layout and the mechanics of the spectrometer extremely simple and advantageous for those applications where spectral resolution is not a major requirement. As a proof of principle, we present the absorption spectrum of Rhodamine B in solution obtained by our spectrometer and compared to commercial instruments.

Ghisleri, C.; Milani, P., E-mail: paolo.milani@mi.infn.it [CIMAINA and Dipartimento di Fisica, Università di Milano, via Celoria 16, 20133 Milano (Italy); WISE srl, Piazza Duse 2, 20122 Milano (Italy); Potenza, M. A. C.; Bellacicca, A. [CIMAINA and Dipartimento di Fisica, Università di Milano, via Celoria 16, 20133 Milano (Italy); Ravagnan, L. [WISE srl, Piazza Duse 2, 20122 Milano (Italy)

2014-02-10T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Developing improved nuclear magnetic resonance marginal oscillator spectrometers for advanced teaching laboratories  

E-Print Network (OSTI)

DEVELOPING IMPROVED NUCLEAR MAGNETIC RESONANCE MARGINAL OSCILLATOR SPECTROMETERS FOR ADVANCED TEACHING LABORATORIES A Thesis by FRANK PHILLIP WILLINGHAM Submitted to the Office of Graduate Studies of Texas ASM University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE D e cemb er 1988 Major Subject: Physics DEVELOPING IMPROVED NUCLEAR MAGNETIC RESONANCE MARGINAL OSCILLATOR SPECTROMETERS FOR ADVANCED TEACHING LABORATORIES A Thesis by FRANK PHILLIP...

Willingham, Frank Phillip

1988-01-01T23:59:59.000Z

322

A balloon-borne aerosol spectrometer for high altitude low aerosol concentration measurements  

SciTech Connect

Funded by Air Force Wright Aeronautical Laboratory, a new balloon-borne high altitude aerosol spectrometer, for the measurement of cirrus cloud ice crystals, has been developed and successfully flown by Sandia National Laboratories and Radiance Research. This report (1) details the aerosol spectrometer design and construction, (2) discusses data transmission and decoding, (3) presents data collected on three Florida flights in tables and plots. 2 refs., 11 figs., 3 tabs.

Brown, G.S. (Sandia National Labs., Albuquerque, NM (USA)); Weiss, R.E. (Radiance Research, Seattle, WA (USA))

1990-08-01T23:59:59.000Z

323

The new very small angle neutron scattering spectrometer at Laboratoire Leon Brillouin  

E-Print Network (OSTI)

The design and characteristics of the new very small angle neutron scattering spectrometer under construction at the Laboratoire Leon Brillouin is described. Its goal is to extend the range of scattering vectors magnitudes towards 2x10{-4} /A. The unique feature of this new spectrometer is a high resolution two dimensional image plate detector sensitive to neutrons. The wavelength selection is achieved by a double reflection supermirror monochromator and the collimator uses a novel multibeam design.

Sylvain Desert; Vincent Thevenot; Julian Oberdisse; Annie Brulet

2007-06-12T23:59:59.000Z

324

DUVAS (derivative uv-absorption spectrometer): instrument description and operating manual  

SciTech Connect

DUVAS is a real-time, field-portable spectrometer capable of monitoring a variety of aromatic organic vapors and inorganic gases at sub-ppM concentrations. The instrument is a prototype, microcomputer-controlled, derivative ultraviolet (UV) absorption spectrometer (DUVAS) developed primarily for area monitoring at coal conversion facilities, although other important occupational and environmental monitoring applications for compounds such as SO/sub 2/, NO/sub x/, NH/sub 3/, and HCHO are also being pursued.

Hawthorne, A.R.; Dougherty, J.M.; Metcalfe, C.E.

1980-11-01T23:59:59.000Z

325

Electron Positron Proton Spectrometer for use at Laboratory for Laser Energetics  

SciTech Connect

The Electron Positron Proton Spectrometer (EPPS) is mounted in a TIM (Ten-Inch Manipulator) system on the Omega-60 or Omega-EP laser facilities at the University of Rochester, Laboratory for Laser Energetics (LLE), when in use, see Fig. 1. The Spectrometer assembly, shown in Fig. 2, is constructed of a steel box containing magnets, surrounded by Lead 6% Antimony shielding with SS threaded insert, sitting on an Aluminum 6061-T6 plate.

Ayers, S L

2010-04-07T23:59:59.000Z

326

A Differential Time-of-flight Spectrometer of Very Slow Neutrons  

E-Print Network (OSTI)

A time-of-flight spectrometer of neutrons in the energy range (0.05 -- 2.5)$\\mu$eV is described. This spectrometer has been tested my measuring the total and differential neutron cross sections for a number of materials: Al, Cu, $^{6}$LiF, Si, Zr, teflon, polyethylene and liquid fluoropolymers, that are essential for experiments in the physics of ultracold neutrons.

Yu. N. Pokotilovski; M. I. Novopoltsev; P. Geltenbort; Th. Brenner

2011-02-14T23:59:59.000Z

327

Characterization and calibration of compact array spectrometers in the ultraviolet spectral region  

SciTech Connect

Array-based spectrometers, with their compact size, low weight, low cost, and fast measurement time, are now frequently used in place of both conventional single-channel scanning monochromators, and broadband meters. Their rapid measurement capability makes them an attractive option for routine solar UV spectral measurements, where shortterm variability in signal is a challenge. However, compactness, portability, low cost and high speed are achieved at the expense of the spectrometer's optical and electronic performance. Thus such spectrometers are more prone to measurement error from environmental changes, and more prone to other intrinsic sources of error such as stray light and detector non-linearity, which significantly affect solar UV measurements, than a scanning monochromator. The effects of stray light and non-linearity can be reduced either by improved optical and detector design or by a detailed spectrometer characterization. We present in this paper our investigation of the performance of three different commercial array spectrometers: two mini-spectrometers, and a more elaborate array spectrometer with an on-board image amplifier device. These were tested for a subset of performance parameters: their wavelength accuracy and stability, electronic linearity, responsivity linearity, stray light sensitivity, and mechanical stability and repeatability. With all three spectrometers we found that these parameters, particularly but not limited to stray light, had a significant impact on the measurement of the incoming optical radiation. This meant that, without characterization, the instruments would be unable to accurately measure the UV component of any source with significant visible radiation. We discuss various simple and low-cost solutions for improving the performance of these instruments, and providing a rigorous calibration using a straightforward set-up including optical filters and the quasi-monochromatic light from a double monochromator.

Shindo, Francois [Measurement Standards Laboratory of New Zealand, Industrial Research, Lower Hutt (New Zealand); Woolliams, Emma; Scott, Barry; Harris, Subrena [National Physical Laboratory, Teddington (United Kingdom)

2013-05-10T23:59:59.000Z

328

Environmental Levels Of 129I Present In Bovine Thyroid And Fresh Water In Argentina  

SciTech Connect

Concentrations of {sup 129}I in bovine thyroid and fresh water samples coming from all over Argentina were analyzed by Accelerator Mass Spectrometry (AMS) and total iodine present in samples by Gas Chromatography (GC) and Inductive Coupled Plasma Mass Spectrometry (ICP-MS), respectively. Once we complete this study, it will be the first set of data of this kind from an extended region of the south American subcontinent.

Negri, A. E.; Arazi, A.; Carnellia, P. F. F.; Barbara, E. de; Figueira, J. M.; Fimiani, L.; Heimanna, D. M.; Zalazara, L. [Laboratorio TANDAR, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Fernandez Niello, J. [Laboratorio TANDAR, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Universidad Nacional de San Martin, Campus Miguelete, B1650BWA, Buenos Aires (Argentina); La Gamma, A. M. [Gerencia Quimica, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Wallner, A. [VERA-Laboratory, Faculty of Physics, University of Vienna, Waehringer Str. 17, A-1090 Wien (Austria)

2010-08-04T23:59:59.000Z

329

Mass Spectrometry | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

and Microfabrication Mass Spectrometry Microscopy Molecular Science Computing NMR and EPR Spectroscopy and Diffraction Subsurface Flow and Transport Mass Spectrometry Systems...

330

Analysis on the Go: Quantitation of Drugs of Abuse in Dried Urine with Digital Microfluidics and Miniature Mass Spectrometry  

E-Print Network (OSTI)

Analysis on the Go: Quantitation of Drugs of Abuse in Dried Urine with Digital Microfluidics the development of a method coupling microfluidics and a miniature mass spectrometer, applied to quantitation of drugs of abuse in urine. A custom digital microfluidic system was designed to deliver droplets

Zandstra, Peter W.

331

Apparatus for preparing a sample for mass spectrometry  

DOE Patents (OSTI)

An apparatus is described for preparing a sample for analysis by a mass spectrometer system. The apparatus has an entry chamber and an ionization chamber separated by a skimmer. A capacitor having two space-apart electrodes followed by one or more ion-imaging lenses is disposed in the ionization chamber. The chamber is evacuated and the capacitor is charged. A valve injects a sample gas in the form of sample pulses into the entry chamber. The pulse is collimated by the skimmer and enters the ionization chamber. When the sample pulse passes through the gap between the electrodes, it discharges the capacitor and is thereby ionized. The ions are focused by the imaging lenses and enter the mass analyzer, where their mass and charge are analyzed. 1 figures.

Villa-Aleman, E.

1994-05-10T23:59:59.000Z

332

The isobaric multiplet mass equation for A?71 revisited  

SciTech Connect

Accurate mass determination of short-lived nuclides by Penning-trap spectrometers and progress in the spectroscopy of proton-rich nuclei have triggered renewed interest in the isobaric multiplet mass equation (IMME). The energy levels of the members of T=1/2,1,3/2, and 2 multiplets and the coefficients of the IMME are tabulated for A?71. The new compilation is based on the most recent mass evaluation (AME2011) and it includes the experimental results on energies of the states evaluated up to end of 2011. Taking into account the error bars, a significant deviation from the quadratic form of the IMME for the A=9,35 quartets and the A=32 quintet is observed.

Lam, Yi Hua, E-mail: lamyihua@gmail.com [CENBG (UMR 5797 — Université Bordeaux 1 — CNRS/IN2P3), Chemin du Solarium, Le Haut Vigneau, BP 120, 33175 Gradignan Cedex (France); Blank, Bertram, E-mail: blank@cenbg.in2p3.fr [CENBG (UMR 5797 — Université Bordeaux 1 — CNRS/IN2P3), Chemin du Solarium, Le Haut Vigneau, BP 120, 33175 Gradignan Cedex (France)] [CENBG (UMR 5797 — Université Bordeaux 1 — CNRS/IN2P3), Chemin du Solarium, Le Haut Vigneau, BP 120, 33175 Gradignan Cedex (France); Smirnova, Nadezda A. [CENBG (UMR 5797 — Université Bordeaux 1 — CNRS/IN2P3), Chemin du Solarium, Le Haut Vigneau, BP 120, 33175 Gradignan Cedex (France)] [CENBG (UMR 5797 — Université Bordeaux 1 — CNRS/IN2P3), Chemin du Solarium, Le Haut Vigneau, BP 120, 33175 Gradignan Cedex (France); Bueb, Jean Bernard; Antony, Maria Susai [IPHC, Université de Strasbourg, CNRS/UMR7178, 23 Rue du Loess, 67037 Strasbourg Cedex (France)] [IPHC, Université de Strasbourg, CNRS/UMR7178, 23 Rue du Loess, 67037 Strasbourg Cedex (France)

2013-11-15T23:59:59.000Z

333

Mass spectrometric immunoassay  

DOE Patents (OSTI)

Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

Nelson, Randall W; Williams, Peter; Krone, Jennifer Reeve

2013-07-16T23:59:59.000Z

334

Mass spectrometric immunoassay  

DOE Patents (OSTI)

Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

Nelson, Randall W (Phoenix, AZ); Williams, Peter (Phoenix, AZ); Krone, Jennifer Reeve (Granbury, TX)

2007-12-04T23:59:59.000Z

335

PPPL3278, Preprint: January 1998, UC426 The TFTR E||B Spectrometer for Mass and Energy Resolved  

E-Print Network (OSTI)

and the supra thermal populations arising from neutral beam injection and ion cyclotron radio frequency heating for Tokamak Fusion Test Reactor was designed to measure the energy distributions of both the thermal ions devices, the extensive use of neutral beam injection and radio frequency auxiliary heating generates

336

PPPL-3278, Preprint: January 1998, UC-426 The TFTR E||B Spectrometer for Mass and Energy Resolved  

E-Print Network (OSTI)

and the supra thermal populations arising from neutral beam injection and ion cyclotron radio frequency heating for Tokamak Fusion Test Reactor was designed to measure the energy distributions of both the thermal ions, the extensive use of neutral beam injection and radio frequency auxiliary heating generates multispecies plasmas

337

Development of a variable-temperature ion mobility/ time-of-flight mass spectrometer for separation of electronic isomers  

E-Print Network (OSTI)

-sphere? cross-section of the ion, the cross-section for atomic and small molecular ions must include all related interaction potentials.19 3 For large molecules (>500 amu) a trajectory cross-section (approximated by simple hard-sphere) accurately...-sphere? cross-section of the ion, the cross-section for atomic and small molecular ions must include all related interaction potentials.19 3 For large molecules (>500 amu) a trajectory cross-section (approximated by simple hard-sphere) accurately...

Verbeck, Guido Fridolin

2005-08-29T23:59:59.000Z

338

Standard Test Method for Isotopic Analysis of Uranium Hexafluoride by Single-Standard Gas Source Multiple Collector Mass Spectrometer Method  

E-Print Network (OSTI)

1.1 This test method is applicable to the isotopic analysis of uranium hexafluoride (UF6) with 235U concentrations less than or equal to 5 % and 234U, 236U concentrations of 0.0002 to 0.1 %. 1.2 This test method may be applicable to the analysis of the entire range of 235U isotopic compositions providing that adequate Certified Reference Materials (CRMs or traceable standards) are available. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety health practices and determine the applicability of regulatory limitations prior to use.

American Society for Testing and Materials. Philadelphia

2011-01-01T23:59:59.000Z

339

Plume collimation for laser ablation electrospray ionization mass spectrometry  

DOE Patents (OSTI)

In various embodiments, a device may generally comprise a capillary having a first end and a second end; a laser to emit energy at a sample in the capillary to ablate the sample and generate an ablation plume in the capillary; an electrospray apparatus to generate an electrospray plume to intercept the ablation plume to produce ions; and a mass spectrometer having an ion transfer inlet to capture the ions. The ablation plume may comprise a collimated ablation plume. The device may comprise a flow cytometer. Methods of making and using the same are also described.

Vertes, Akos; Stolee, Jessica A.

2014-09-09T23:59:59.000Z

340

X-ray spectrometers with cylindrical, spherical and toroidal dispersive elements  

SciTech Connect

This paper describes a series of crystal spectrometers for soft x-ray diagnostics of pulsed plasmas. Most use high quality quartz crystals with different orientations of their crystal planes, attached by optical contact to spherical and toroidal substrates. The authors developed special procedures to attach spherical Johansson quartz crystals with optical contact, and to mount Cauchois type (transmission) crystals. Some mica crystals can be connected to the substrate with glue. The spectrometers cover an extended energy range, from the low end (0.7 keV) in reflection with a Johann or Johannson configuration to the high end (200 keV) with the Cauchois crystal. They use film as x-ray detector. They pay special attention to spectral and spatial resolutions. These characteristics are modeled analytically and compared with experimental calibration. Some crystals have spectral resolution better than 9 x 10{sup {minus}5}, and spatial resolution of a few microns. One of these is a uniquely large (100 mm by 40 mm) quartz crystal bent to a 3,770 mm radius. The spectrometer was used on a 500 kA plasma focus, with enough resolution to estimate temperature and density of the argon plasma from the line shapes, and the fraction of current in an electron beam from the line's polarization. Compared to a conventional spectrometer with a cylindrically bent crystal, the spectrometer with a chemically polished spherical crystal has much better resolution of the fine structure.

Baronova, E.O.; Lider, V.V.; Stepanenko, M.M.; Vikhrev, V.V.; Pereira, N.R.

1999-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Self-Heterodyne Spectrometer Using Uni-Traveling-Carrier Photodiodes for Terahertz-Wave Generators and Optoelectronic Mixers  

Science Journals Connector (OSTI)

We demonstrate a self-heterodyne terahertz (THz) frequency-domain spectrometer in which commercially available uni-traveling-carrier photodiodes (UTC-PDs) are used as...

Hisatake, Shintaro; Kim, Jae-Young; Ajito, Katsuhiro; Nagatsuma, Tadao

2014-01-01T23:59:59.000Z

342

The Wide Angular-Range Chopper Spectrometer at SNS | ORNL Neutron Sciences  

NLE Websites -- All DOE Office Websites (Extended Search)

The Wide Angular-Range Chopper Spectrometer at SNS The Wide Angular-Range Chopper Spectrometer at SNS and Doug Abernathy at ARCS Materials researcher Judy Pang and instrument scientist Doug Abernathy at ARCS. ARCS is optimized to provide a high neutron flux at the sample and a large solid angle of detector coverage. This spectrometer is capable of selecting incident energies over the full energy spectrum of neutrons, making it useful for studies of excitations from a few to several hundred milli-electron volts. An elliptically shaped supermirror guide in the incident flight path boosts the performance at the lower end of this range. The sample and detector vacuum chambers provide a window-free final flight path and incorporate a large gate valve to allow rapid sample changeout. A T0 neutron chopper not only blocks the prompt radiation from the source

343

NSE: the Neutron Spin Echo Spectrometer at SNS | ORNL Neutron Sciences  

NLE Websites -- All DOE Office Websites (Extended Search)

Spin Echo Spectrometer at SNS Spin Echo Spectrometer at SNS NSE NSE is funded and operated by the Jülich Centre for Neutron Science. The SNS NSE instrument provides ultrahigh resolution spectroscopy with a Fourier time range that covers τ = 1 ps to a nominal 350 ns with a high effective neutron flux, aiming to be the best of its class in both resolution and dynamic range (please refer to the instrument fact sheet for a detailed current status). Researchers use this instrument to investigate soft condensed matter and complex fluids applications in a variety of fields. The planned optional ferromagnetic and intensity-modulated modes will allow for detailed investigation of magnetic samples and phenomena. The design of the NSE spectrometer takes full advantage of recent progress in neutron optics and polarizing supermirror microbenders,1,2 resulting in

344

CNCS: the Cold Neutron Chopper Spectrometer at SNS | ORNL Neutron Sciences  

NLE Websites -- All DOE Office Websites (Extended Search)

Cold Neutron Chopper Spectrometer at SNS Cold Neutron Chopper Spectrometer at SNS CNCS detector array Interior of the CNCS detector array. CNCS is a high-resolution, direct-geometry, multi-chopper inelastic spectrometer designed to provide flexibility in the choice of energy resolution and to perform best at low incident energies (2 to 50 meV). Although the detector coverage around the sample is 1.7 sr, a later upgrade to 3 sr is possible. Experiments at CNCS typically use energy resolutions between 10 and 500 µeV. A broad variety of scientific problems, ranging from complex and quantum fluids to magnetism and chemical spectroscopy, are being addressed through experiments at CNCS. Applications Schematic of CNCS (larger image). Complex fluids: dilute protein solutions, biological gels, selective

345

Temperature and nonlinearity corrections for a photodiode array spectrometer used in the field  

SciTech Connect

Temperature and nonlinearity effects are two important factors that limit the use of photodiode array spectrometers. Usually the spectrometer is calibrated at a known temperature against a reference source of a particular spectral radiance, and then it is used at different temperatures to measure sources of different spectral radiances. These factors are expected to be problematic for nontemperature-stabilized instruments used for in-the-field experiments, where the radiant power of the site changes continuously with the sun tilt. This paper describes the effect of ambient temperature on a nontemperature-stabilized linear photodiode array spectrometer over the temperature range from 5 deg. C to 40 deg. C. The nonlinearity effects on both signal amplification and different levels of radiant power have also been studied and are presented in this paper.

Salim, Saber G. R.; Fox, Nigel P.; Theocharous, Evangelos; Sun, Tong; Grattan, Kenneth T. V.

2011-02-20T23:59:59.000Z

346

A compact stilbene crystal neutron spectrometer for EAST D-D plasma neutron diagnostics  

SciTech Connect

A new compact stilbene crystal neutron spectrometer has been investigated and applied in the neutron emission spectroscopy on the EAST tokamak. A new components analysis method is presented to study the anisotropic light output in the stilbene crystal detector. A Geant4 code was developed to simulate the neutron responses in the spectrometer. Based on both the optimal light output function and the fitted pulse height resolution function, a reliable neutron response matrix was obtained by Geant4 simulations and validated by 2.5 MeV and 14 MeV neutron measurements at a 4.5 MV Van de Graaff accelerator. The spectrometer was used to diagnose the ion temperature in plasma discharges with lower hybrid wave injection and ion cyclotron resonance heating on the EAST tokamak.

Zhang Xing; Yuan Xi; Xie Xufei; Chen Zhongjing; Peng Xingyu; Chen Jinxiang; Zhang Guohui; Li Xiangqing; Fan Tieshuan [School of Physics and State Key Laboratory of Nuclear Physics and Technology, Peking University, Chengfu Road 201, 100871 Beijing (China); Zhong Guoqiang; Hu Liqun; Wan Baonian [Institute of Plasma Physics, Chinese Academy of Sciences, PO Box 1126, 230031 Hefei, Anhui (China)

2013-03-15T23:59:59.000Z

347

Laser sampling system for an inductively-coupled atomic emission spectrometer. Final report  

SciTech Connect

A laser sampling system was attached to a Perkin Elmer Optima 3000 inductively-coupled plasma, atomic emission spectrometer that was already installed and operating in the Chemistry and Geochemistry Department at the Colorado School of Mines. The use of the spectrometer has been highly successful. Graduate students and faculty from at least four different departments across the CSM campus have used the instrument. The final report to NSF is appended to this final report. Appendices are included which summarize several projects utilizing this instrument: acquisition of an inductively-coupled plasma atomic emission spectrometer for the geochemistry program; hydrogen damage susceptibility assessment for high strength steel weldments through advanced hydrogen content analysis, 1996 and 1997 annual reports; and methods for determination of hydrogen distribution in high strength steel welds.

NONE

1998-02-15T23:59:59.000Z

348

Quantum states of neutrons in the gravitational and centrifugal potentials in a new GRANIT spectrometer  

SciTech Connect

We will discuss the scientific program to be studied in a new gravitational spectrometer GRANIT in a broad context of quantum states (quantum behaviour) of ultracold neutrons (UCN) in gravitational [1] and centrifugal [2] potentials, as well as applications of these phenomena/spectrometer to various domains of physics, ranging from studies of fundamental short-range interactions and symmetries to neutron quantum optics and reflectometry using UCN. All these topics, as well as related instrumental and methodical developments have been discussed during dedicated GRANIT-2010 Workshop [3]. The GRANIT spectrometer has been recently installed at the Institut Laue-Langevin, Grenoble, France [4] and could become operational in near future. 1. V.V. Nesvizhevsky et al (2002), Nature 415, 297. 2. V.V. Nesvizhevsky et al (2010), Nature Physics 6, 114. 3. GRANIT-2010, Les Houches, 14-19 february 2010. 4. M. Kreuz et al (2009), NIM 611, 326.

None

2010-03-18T23:59:59.000Z

349

mass communication advertising &  

E-Print Network (OSTI)

mass communication advertising & public relations introduction. Graduate programs in the Department of Mass Communication, Advertising, and Public Relations provide an entry to a wide spectrum of careers the opportunity to create content, campaigns, strategy, and research in public relations, advertising

Finzi, Adrien

350

Multi-manoeuvrable UHV crystal holder (for X-ray spectrometer)  

Science Journals Connector (OSTI)

The design of a multi-manoeuvrable ultrahigh vacuum (UHV) crystal holder for a new soft X-ray spectrometer is described. The holder is capable of adjusting the position of the crystal by 80 mm in the z direction which is normal to the Rowland circumference of the spectrometer and 8 mm in the orthogonal x and y directions. Angular adjustment is allowed within a maximum range of 10 degrees . All adjustments are accurately reproducible and are made from outside the UHV system. The holder also makes provision for cooling of the crystal by a liquid or gas coolant.

S Ottosson

1976-01-01T23:59:59.000Z

351

Electron pair emission detected by time-of-flight spectrometers: Recent progress  

SciTech Connect

We present results for electron coincidence spectroscopy using two time-of-flight (ToF) spectrometers. Excited by electron impact, the energy and momentum distribution of electron pairs emitted from the Cu(111) surface are resolved and a spectral feature related to the Shockley surface state is identified. By combining the two ToF spectrometers with a high-order harmonic generation light source, we demonstrate double photoemission spectroscopy in the laboratory that required synchrotron radiation in the past. Utilizing this setup, we report results for (?,2e) on NiO(001) on Ag(001) excited with light at 30?eV photon energy.

Huth, Michael; Schumann, Frank O. [Max Planck Institute of Microstructure Physics, Weinberg 2, D-06120 Halle (Germany); Chiang, Cheng-Tien; Trützschler, Andreas; Kirschner, Jürgen [Max Planck Institute of Microstructure Physics, Weinberg 2, D-06120 Halle (Germany); Institute of Physics, Martin-Luther-Universität Halle-Wittenberg, Von-Danckelmann-Platz 3, D-06120 Halle (Saale) (Germany); Widdra, Wolf [Institute of Physics, Martin-Luther-Universität Halle-Wittenberg, Von-Danckelmann-Platz 3, D-06120 Halle (Saale) (Germany); Max Planck Institute of Microstructure Physics, Weinberg 2, D-06120 Halle (Germany)

2014-02-10T23:59:59.000Z

352

Investigations of 2? decay measured by low background HPGe spectrometer OBELIX  

SciTech Connect

A low background high sensitive HPGe spectrometer OBELIX was installed at the Modane Underground Laboratory (LSM, France, 4800 m w.e.). The detector was designed to measure a contamination of enriched isotopes and radio-impurities in construction materials, to investigate rare nuclear processes such as resonance neutrinoless double electron capture and two-neutrino double beta decay to excited states of daughter nuclei. Spectrometer sensitivity, contamination of NEMO-3 sources and results of 2?2?{sup ?} decay of {sup 100}Mo to the 0{sup +} (1130 keV) and 2{sup +} (540 keV) excited states as well as future plans for OBELIX detector are given.

Rukhadze, Ekaterina [Institute of Experimental and Applied Physics, CTU in Prague, Horska 3a/22, 128 00 Prague 2 (Czech Republic); Collaboration: OBELIX Collaboration; SuperNEMO Collaboration

2013-12-30T23:59:59.000Z

353

Reduction of plyatomic ion interferences in indictively coupled plasma mass spectrometry with cryogenic desolvation  

SciTech Connect

A desolvation scheme for introducing aqueous and organic samples into an argon inductively coupled plasma is described; the aerosol generated by nebulizer is heated (+140 C) and cooled ({minus}80 C) repeatedly, and the dried aerosol is then injected into the mass spectrometer. Polyatomic ions are greatly suppressed. This scheme was validated with analysis of seawater and urine reference samples. Finally, the removal of organic solvents by cryogenic desolvation was studied.

Alves, L.C.

1993-09-01T23:59:59.000Z

354

Precision Spectroscopy of Pionic Atoms: From Pion Mass Evaluation to Tests of Chiral Perturbation Theory  

E-Print Network (OSTI)

Preliminary results of the strong interaction shift and width in pionic hydrogen ($\\pi H$) using an X-ray spectrometer with spherically bent crystals and CCDs as X-ray detector are presented. In the experiment at the Paul Scherrer Institute three different $(np\\to 1s)$ transitions in $\\pi H$ were measured. Moreover the pion mass measurement using the $(5 \\to 4)$ transitions in pionic nitrogen and muonic oxygen is presented

Trassinelli, M

2004-01-01T23:59:59.000Z

355

Elbow mass flow meter  

DOE Patents (OSTI)

Elbow mass flow meter. The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity.

McFarland, Andrew R. (College Station, TX); Rodgers, John C. (Santa Fe, NM); Ortiz, Carlos A. (Bryan, TX); Nelson, David C. (Santa Fe, NM)

1994-01-01T23:59:59.000Z

356

Analysis of perchlorate in groundwater by electrospray ionization mass spectrometry/mass spectrometry  

SciTech Connect

An electrospray ionization mass spectrometry/mass spectrometry (ESI/MS/MS) method was developed to measure part-per-billion ({micro}g/L) concentrations of perchlorate in groundwater. Selective and sensitive perchlorate detection was achieved by operating the mass spectrometer in the negative ionization mode and by using MS/MS to monitor the CIO{sub 4}{sup {minus}} to ClO{sub 3}{sup {minus}} transition. The method of standard additions was used to address the considerable signal suppression caused by anions that are typically present in groundwater, such as bicarbonate and sulfate. ESI-MS/MS analysis was rapid, accurate, reproducible, and provided a detection limit of 0.5 {micro}g/L perchlorate in groundwater. Accuracy and precision of the ESI/MS/MS method were assessed by analyzing performance evaluation samples in a groundwater matrix and by comparing ion chromatography (IC) and ESI/MS/MS results for local groundwater samples. Results for the performance evaluation samples differed from the certified values by 4--13%, and precision ranged from 3 to 10% (relative standard deviation). The IC and ESI/MS/MS results were statistically indistinguishable for perchlorate concentrations above the detection limits of both methods.

Koester, C.J.; Beller, H.R.; Halden, R.U.

2000-05-01T23:59:59.000Z

357

Trace element fingerprinting of ancient Chinese gold with femtosecond laser  

NLE Websites -- All DOE Office Websites (Extended Search)

Trace element fingerprinting of ancient Chinese gold with femtosecond laser Trace element fingerprinting of ancient Chinese gold with femtosecond laser ablation-inductivity coupled mass spectrometry Title Trace element fingerprinting of ancient Chinese gold with femtosecond laser ablation-inductivity coupled mass spectrometry Publication Type Journal Article Year of Publication 2009 Authors Brostoff, Lynn B., Jhanis J. Gonzalez, Paul Jett, and Richard E. Russo Journal Journal of Archeological Science Volume 36 Start Page 461 Issue 2 Pagination 461-466 Date Published 02/2009 Keywords Ancient gold, femtosecond, la-icp-ms, Trace element Abstract In this collaborative investigation, femtosecond laser ablation-inductively coupled mass spectrometry (LA-ICP-MS) was applied to the study of a remarkable group of ancient Chinese gold objects in the Smithsonian's Freer Gallery of Art and Arthur M. Sackler Gallery. Taking advantage of the superior ablation characteristics and high precision of a femtosecond 266 nm Ti:sapphire laser at Lawrence Berkeley National Laboratory, major, minor and trace element concentrations in the gold fragments were quantified. Results validate use of femtosecond LA-ICP-MS for revealing ''fingerprints'' in minute gold samples. These fingerprints allow us to establish patterns based on the association of silver, palladium and platinum that support historical, technical and stylistic relationships, and shed new light on these ancient objects.

358

Transmission Grating Spectrometer for Constellation-X White paper response to NASA solicitation 210S-GBG-06-001  

E-Print Network (OSTI)

1 Transmission Grating Spectrometer for Constellation-X White paper response to NASA solicitation proposes a transmission grating spectrometer to provide high spectral resolution at low energies, extending down below 0.2 keV. The transmission grating is blazed, concentrating the energy among a single set

Heilmann, Ralf

359

X-Band EPR Spectrometer with Customizable Arbitrary Waveform Generator based on a 1 GHz DAC Board  

E-Print Network (OSTI)

X-Band EPR Spectrometer with Customizable Arbitrary Waveform Generator based on a 1 GHz DAC Board-4120 , Email: songi@chem.ucsb.edu Abstract We present an EPR spectrometer featuring an arbitrary waveform of pulsed electron paramagnetic resonance (EPR) and enable new experiments. It generates shaped X

Martinis, John M.

360

Port Compensation Using the Herschel/SPIRE Imaging Fourier Transform Spectrometer  

E-Print Network (OSTI)

Port Compensation Using the Herschel/SPIRE Imaging Fourier Transform Spectrometer Locke D. Spencer the position of zero optical path difference (ZPD). The process of port compensation involves a broadband spectral source placed at the second, complementary input port of an FTS, reducing the dynamic range

Naylor, David A.

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Neutron Experiment descriptions: N1: Triple-Axis Spectrometers, HFIR HB1A & HB3  

E-Print Network (OSTI)

Neutron Experiment descriptions: N1: Triple-Axis Spectrometers, HFIR HB1A & HB3 Spin wave2A Magnetic structure of NiO Neutron diffraction measurements will be performed to investigate 600K to 288K, using the Neutron Powder Diffractometer at the HFIR. Rietveld analysis of the crystal

Pennycook, Steve

362

Optimizing and characterizing grating efficiency for a soft X-ray emission spectrometer  

Science Journals Connector (OSTI)

The efficiency of soft X-ray diffraction gratings is examined using theoretical calculations with new open-source software, and insights to design a high-performance emission spectrometer are applied. The calculated and measured efficiencies of real-world gratings are compared, and discrepancies are explained by incorporating real-world effects into the calculations.

Boots, M.

2013-02-06T23:59:59.000Z

363

A compact neutron spectrometer for characterizing inertial confinement fusion implosions at OMEGA and the NIF  

E-Print Network (OSTI)

A compact neutron spectrometer for characterizing inertial confinement fusion implosions at OMEGA-resolution spectroscopy used to measure inertial confinement fusion neutron spectra on Omega (invited)a) Rev. Sci. Instrum. 83, 10D919 (2012); 10.1063/1.4742926 Neutron spectrometry--An essential tool for diagnosing

364

High-Sensitivity Raman Spectrometer To Study Pristine and Irradiated Interstellar Ice Analogs  

E-Print Network (OSTI)

to ionizing radiation which produces small quantities of new chemical species within the bulk of the icesHigh-Sensitivity Raman Spectrometer To Study Pristine and Irradiated Interstellar Ice Analogs Chris with low temperature ices relevant to the solar system and interstellar medium. The design is based

Kaiser, Ralf I.

365

TOWARDS BENCHMARK MEASUREMENTS FOR USED NUCLEAR FUEL ASSAY USING A LEAD SLOWING-DOWN SPECTROMETER  

E-Print Network (OSTI)

for spent fuel testing. The characterization of spent fuel is particularly important for nuclear safeguardsTOWARDS BENCHMARK MEASUREMENTS FOR USED NUCLEAR FUEL ASSAY USING A LEAD SLOWING-DOWN SPECTROMETER B) is considered as a possible option for non- destructive assay of fissile material in used nuclear fuel

Danon, Yaron

366

High-resolution Bent-crystal Spectrometer for the Ultra-soft X-ray Region  

DOE R&D Accomplishments (OSTI)

A multichannel vacuum Brag-crystal spectrometer has been developed for high-resolution measurements of the line emission from tokamak plasmas in the wavelength region between 4 and 25 angstrom. The spectrometer employs a bent crystal in Johann geometry and a microchannel-plate intensified photodiode array. The instrument is capable of measuring high-resolution spectra (lambda/..delta..lambda approx. 3000) with fast time resolution (4 msec per spectrum) and good spatial resolution (3 cm). The spectral bandwidth is ..delta..lambda/lambda{sub 0} = 8 angstrom. A simple tilt mechanism allows access to different wavelength intervals. In order to illustrate the utility of the new spectrometer, time- and space-resolved measurements of the n = 3 to n = 2 spectrum of selenium from the Princeton Large Torus tokamak plasmas are presented. The data are used to determine the plasma transport parameters and to infer the radial distribution of fluorinelike, neonlike, and sodiumlike ions of selenium in the plasma. The new ultra-soft x-ray spectrometer has thus enabled us to demonstrate the utility of high-resolution L-shell spectroscopy of neonlike ions as a fusion diagnostic.

Beiersdorfer, P.; von Goeler, S.; Bitter, M.; Hill, K. W.; Hulse, R. A.; Walling, R. S.

1988-10-00T23:59:59.000Z

367

Near-infrared thermal lens spectrometer based on an erbium-doped fiber amplifier and  

E-Print Network (OSTI)

Near-infrared thermal lens spectrometer based on an erbium-doped fiber amplifier and an acousto, guanosine, and thymidine is described. © 1997 Optical Society of America Key words: Near infrared, thermal measurements of absorption in the near-IR region has been developed. In this instrument the near-IR excitation

Reid, Scott A.

368

A high-resolution soft x-ray spectrometer on the MAST tokamak  

SciTech Connect

A curved crystal spectrometer in Johann configuration has been implemented on MAST to obtain values for electron temperature, ion temperature and toroidal velocity. The spectrometer is used to examine medium Z impurities in the soft x-ray region by utilising a Silicon (111) crystal, bent using a 4 pin bending jig, and a CCD detector ({delta}t=8 ms). Helium-like Argon emissions from 3.94 to 4.00 A have been examined using a crystal radius of 859.77 mm. The Bragg angle and crystal radius can be adjusted with relative ease. The spectrometer can be scanned toroidally and poloidally to include a radial view which facilitates absolute velocity measurements by assuming radial velocity =0. Doppler shifts of 2.3x10{sup -5} A (1.8 kms{sup -1}) can be measured. The line of sight is shared with a neutral particle analyzer, which enables in situ ion temperature comparisons. Ray tracing has been used for the development of new imaging spectrometers, using spherical/toroidal crystals, planned to be implemented on MAST.

Nelson, M.J.; Barnsley, R.; Keenan, F.; Meyer, H.; Bunting, C.A.; Carolan, P.G.; Conway, N.J.; Cunningham, G.; Lehane, I.; Tournianski, M.R. [Queens University, Belfast, N. Ireland BT7 1NN (United Kingdom); EURATOM/UKAEA Fusion Association, Culham Science Centre, Abingdon OX14 3DB (United Kingdom)

2004-10-01T23:59:59.000Z

369

Combined inclusive diffractive cross sections measured with forward proton spectrometers at HERA  

SciTech Connect

A combination is presented of the inclusive diffractive cross section measurements made by the H1 and ZEUS Collaborations at HERA. The analysis uses samples of diffractive deep inelastic scattering data where leading protons are detected by dedicated spectrometers. Correlations of systematic uncertainties are taken into account by the combination method, resulting in improved precision.

Ruspa, Marta [Univ. Piemonte Orientale, via Solaroli 17, 28100 Novara (Italy); Collaboration: H1 Collaboration; ZEUS Collaboration

2013-04-15T23:59:59.000Z

370

Lead Slowing Down Spectrometer FY2013 Annual Report  

SciTech Connect

Executive Summary The Lead Slowing Down Spectrometry (LSDS) project, funded by the Materials Protection And Control Technology campaign, has been evaluating the feasibility of using LSDS techniques to assay fissile isotopes in used nuclear fuel assemblies. The approach has the potential to provide considerable improvement in the assay of fissile isotopic masses in fuel assemblies compared to other non-destructive techniques in a direct and independent manner. This report is a high level summary of the progress completed in FY2013. This progress included: • Fabrication of a 4He scintillator detector to detect fast neutrons in the LSDS operating environment. Testing of the detector will be conducted in FY2014. • Design of a large area 232Th fission chamber. • Analysis using the Los Alamos National Laboratory perturbation model estimated the required number of neutrons for an LSDS measurement to be 10 to the 16th source neutrons. • Application of the algorithms developed at Pacific Northwest National Laboratory to LSDS measurement data of various fissile samples conducted in 2012. The results concluded that the 235U could be measured to 2.7% and the 239Pu could be measured to 6.3%. Significant effort is yet needed to demonstrate the applicability of these algorithms for used-fuel assemblies, but the results reported here are encouraging in demonstrating that we are making progress toward that goal. • Development and cost-analysis of a research plan for the next critical demonstration measurements. The plan suggests measurements on fresh fuel sub assemblies as a means to experimentally test self-attenuation and the use of fresh mixed-oxide fuel as a means to test simultaneous measurement of 235U and 239Pu.

Warren, Glen A.; Kulisek, Jonathan A.; Gavron, Victor A.; Danon, Yaron; Weltz, Adam; Harris, Jason; Stewart, T.

2013-10-29T23:59:59.000Z

371

Studies on Neurosteroids XX. Liquid Chromatography—Tandem Mass Spectrometric Method for Simultaneous Determination of Testosterone and 5?-Dihydrotestosterone in Rat Brain and Serum  

Science Journals Connector (OSTI)

......LC) coupled with atmospheric pressure ionization...ionization (ESI) and atmospheric pressure chemical ionization...developed API technique, atmospheric pressure photoionization...methanol (2 mL), and water (2 mL) prior to use...between the nitrogen generator and the mass spectrometer......

Tatsuya Higashi; Yasuaki Ninomiya; Kazutake Shimada

2008-08-01T23:59:59.000Z

372

Study of thermal neutron capture gamma rays using a lithium-drifted germanium spectrometer / [by] Victor John Orphan [and] Norman C. Rasmussen  

E-Print Network (OSTI)

A gamma-ray spectrometer, using a 30 cc coaxial Ge(Li) detector, which can be operated as a pair spectrometer at high energies and in the Compton suppression mode at low energies provides an effective means of obtaining ...

Orphan, V. J.

1967-01-01T23:59:59.000Z

373

Aerosol Mass Spectrometry via Laser-Induced Incandescence Particle Vaporization Final Report  

SciTech Connect

We have successfully developed and commercialized a soot particle aerosol mass spectrometer (SP-AMS) instrument to measure mass, size, and chemical information of soot particles in ambient environments. The SP-AMS instrument has been calibrated and extensively tested in the laboratory and during initial field studies. The first instrument paper describing the SP-AMS has been submitted for publication in a peer reviewed journal and there are several related papers covering initial field studies and laboratory studies that are in preparation. We have currently sold 5 SP-AMS instruments (either as complete systems or as SP modules to existing AMS instrument operators).

Timothy B. Onasch

2011-10-20T23:59:59.000Z

374

Nuclear Masses in Astrophysics  

E-Print Network (OSTI)

Among all nuclear ground-state properties, atomic masses are highly specific for each particular combination of N and Z and the data obtained apply to a variety of physics topics. One of the most crucial questions to be addressed in mass spectrometry of unstable radionuclides is the one of understanding the processes of element formation in the Universe. To this end, accurate atomic mass values of a large number of exotic nuclei participating in nucleosynthesis are among the key input data in large-scale reaction network calculations. In this paper, a review on the latest achievements in mass spectrometry for nuclear astrophysics is given.

Christine Weber; Klaus Blaum; Hendrik Schatz

2008-12-09T23:59:59.000Z

375

HYSPEC : A CRYSTAL TIME OF FLIGHT HYBRID SPECTROMETER FOR THE SPALLATION NEUTRON SOURCE.  

SciTech Connect

This document lays out a proposal by the Instrument Development Team (IDT) composed of scientists from leading Universities and National Laboratories to design and build a conceptually new high-flux inelastic neutron spectrometer at the pulsed Spallation Neutron Source (SNS) at Oak Ridge. This instrument is intended to supply users of the SNS and scientific community, of which the IDT is an integral part, with a platform for ground-breaking investigations of the low-energy atomic-scale dynamical properties of crystalline solids. It is also planned that the proposed instrument will be equipped with a polarization analysis capability, therefore becoming the first polarized beam inelastic spectrometer in the SNS instrument suite, and the first successful polarized beam inelastic instrument at a pulsed spallation source worldwide. The proposed instrument is designed primarily for inelastic and elastic neutron spectroscopy of single crystals. In fact, the most informative neutron scattering studies of the dynamical properties of solids nearly always require single crystal samples, and they are almost invariably flux-limited. In addition, in measurements with polarization analysis the available flux is reduced through selection of the particular neutron polarization, which puts even more stringent limits on the feasibility of a particular experiment. To date, these investigations have mostly been carried out on crystal spectrometers at high-flux reactors, which usually employ focusing Bragg optics to concentrate the neutron beam on a typically small sample. Construction at Oak Ridge of the high-luminosity spallation neutron source, which will provide intense pulsed neutron beams with time-averaged fluxes equal to those at medium-flux reactors, opens entirely new opportunities for single crystal neutron spectroscopy. Drawing upon experience acquired during decades of studies with both crystal and time-of-flight (TOF) spectrometers, the IDT has developed a conceptual design for a focused-beam, hybrid time-of-flight instrument with a crystal monochromator for the SNS called HYSPEC (an acronym for hybrid spectrometer). The proposed instrument has a potential to collect data more than an order of magnitude faster than existing steady-source spectrometers over a wide range of energy transfer ({h_bar}{omega}) and momentum transfer (Q) space, and will transform the way that data in elastic and inelastic single-crystal spectroscopy are collected. HYSPEC is optimized to provide the highest neutron flux on sample in the thermal and epithermal neutron energy ranges at a good-to-moderate energy resolution. By providing a flux on sample several times higher than other inelastic instruments currently planned for the SNS, the proposed instrument will indeed allow unique ground-breaking measurements, and will ultimately make polarized beam studies at a pulsed spallation source a realistic possibility.

SHAPIRO,S.M.; ZALIZNYAK,I.A.

2002-12-30T23:59:59.000Z

376

Elbow mass flow meter  

DOE Patents (OSTI)

The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity. 3 figs.

McFarland, A.R.; Rodgers, J.C.; Ortiz, C.A.; Nelson, D.C.

1994-08-16T23:59:59.000Z

377

The Origins of Mass  

SciTech Connect

The Higgs boson was discovered in July of 2012 and is generally understood to be the origin of mass. While those statements are true, they are incomplete. It turns out that the Higgs boson is responsible for only about 2% of the mass of ordinary matter. In this dramatic new video, Dr. Don Lincoln of Fermilab tells us the rest of the story.

Lincoln, Don

2014-07-30T23:59:59.000Z

378

Gas Chromatography -Mass Spectrometry  

E-Print Network (OSTI)

GCMS - 1 Gas Chromatography - Mass Spectrometry GC-MS ANALYSIS OF ETHANOL AND BENZENE IN GASOLINE Last updated: June 17, 2014 #12;GCMS - 2 Gas Chromatography - Mass Spectrometry GC-MS ANALYSIS). The goal of this experiment is to separate the components in a sample of gasoline using Gas Chromatography

Nizkorodov, Sergey

379

W Transverse Mass  

NLE Websites -- All DOE Office Websites (Extended Search)

Some Data Analysis Some Data Analysis The Tevatron produces millions of collisions each second in CDF and DZero. The detectors have hardware triggers to decide if a collision is "interesting," that is it contains a candidate event for any one of a number studies. Our dataset contains 48,844 candidate events for a W mass study. There are other datasets to study Z mass, top and b quarks, QCD, etc. Why don't all the W decays give exactly the same mass? Are all these candidates really Ws? What if we chose only some of these data. How would our choice effect the value of the transverse mass? Work with your classmates. Test the data to see what you can learn. Help with data analysis. Record the best estimate of the W transverse mass from your data analysis. Explain which data you used and why. Check with your classmates and explain any differences between your estimate and theirs.

380

Neutron Time-Of-Flight Spectrometer Based on HIRFL for Studies of Spallation Reactions Related to ADS Project  

E-Print Network (OSTI)

A Neutron Time-Of-Flight (NTOF) spectrometer based on Heavy Ion Research Facility in Lanzhou (HIRFL) is developed for studies of neutron production of proton induced spallation reactions related to the ADS project. After the presentation of comparisons between calculated spallation neutron production double-differential cross sections and the available experimental one, a detailed description of NTOF spectrometer is given. Test beam results show that the spectrometer works well and data analysis procedures are established. The comparisons of the test beam neutron spectra with those of GEANT4 simulations are presented.

Zhang, Suyalatu; Han, Rui; Wada, Roy; Liu, Xingquan; Lin, Weiping; Liu, Jianli; Shi, Fudong; Ren, Peipei; Tian, Guoyu; Luo, Fei

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Neutron Time-Of-Flight Spectrometer Based on HIRFL for Studies of Spallation Reactions Related to ADS Project  

E-Print Network (OSTI)

A Neutron Time-Of-Flight (NTOF) spectrometer based on Heavy Ion Research Facility in Lanzhou (HIRFL) is developed for studies of neutron production of proton induced spallation reactions related to the ADS project. After the presentation of comparisons between calculated spallation neutron production double-differential cross sections and the available experimental one, a detailed description of NTOF spectrometer is given. Test beam results show that the spectrometer works well and data analysis procedures are established. The comparisons of the test beam neutron spectra with those of GEANT4 simulations are presented.

Suyalatu Zhang; Zhiqiang Chen; Rui Han; Roy Wada; Xingquan Liu; Weiping Lin; Jianli Liu; Fudong Shi; Peipei Ren; Guoyu Tian; Fei Luo

2014-11-20T23:59:59.000Z

382

Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR)  

NLE Websites -- All DOE Office Websites (Extended Search)

Ames: Phil Russell, Jens Redemann, NASA Ames: Phil Russell, Jens Redemann, Ames: Phil Russell, Jens Redemann, NASA Ames: Phil Russell, Jens Redemann, Steve Dunagan, Roy Johnson: Steve Dunagan, Roy Johnson: Battelle PND: Connor Flynn, Beat Schmid, Battelle PND: Connor Flynn, Beat Schmid, Evgueni Kassianov Evgueni Kassianov NASA GSFC: Alexander Sinyuk, Brent NASA GSFC: Alexander Sinyuk, Brent Holben Holben , , & AERONET Team & AERONET Team Collaboration involving: Collaboration involving: NASA Ames, Battelle PND, NASA GSFC NASA Ames, Battelle PND, NASA GSFC 4S 4S TAR TAR : : S S pectrometer for pectrometer for S S ky ky - - S S canning, canning, S S un un - - T T racking racking A A tmospheric tmospheric R R esearch esearch 4STAR: 4STAR: Spectrometer Spectrometer for for Sky Sky - - Scanning Scanning , , Sun Sun - - Tracking Tracking Atmospheric Research Atmospheric Research

383

Ultrahigh resolution soft x-ray emission spectrometer at BL07LSU in SPring-8  

SciTech Connect

An extremely high resolution flat field type slit less soft x-ray emission spectrometer has been designed and constructed for the long undulator beamline BL07LSU in SPring-8. By optimizing the ruling parameters of two cylindrical gratings, a high energy resolution {Delta}E < 100 meV and/or an E/{Delta}E{approx} 10 000 are expected for the energy range of 350 eV - 750 eV taking into account the broadening by the spatial resolution (25 {mu}m) of a CCD detector. A coma-free operation mode proposed by Strocov et al., is also applied to eliminate both defocus and coma aberrations. The spectrometer demonstrated experimentally that E/{Delta}E= 10 050 and 8046 for N 1s (402.1 eV) and Mn 2p (641.8 eV) edges, respectively.

Harada, Yoshihisa [Department of Applied Chemistry, Graduate School of Engineering, University of Tokyo, Hongo, Bunkyo, Tokyo 113-8656 (Japan); Synchrotron Radiation Research Organization, University of Tokyo, Koto, Shingu-cho, Tatsuno, Hyogo 679-5165 (Japan); RIKEN/SPring-8, Sayo-cho, Sayo, Hyogo 679-5148 (Japan); CREST, Japan Science and Technology (JST), Kawaguchi, Saitama 332-0012 (Japan); Kobayashi, Masaki [Department of Applied Chemistry, Graduate School of Engineering, University of Tokyo, Hongo, Bunkyo, Tokyo 113-8656 (Japan); Synchrotron Radiation Research Organization, University of Tokyo, Koto, Shingu-cho, Tatsuno, Hyogo 679-5165 (Japan); RIKEN/SPring-8, Sayo-cho, Sayo, Hyogo 679-5148 (Japan); Niwa, Hideharu [Department of Applied Chemistry, Graduate School of Engineering, University of Tokyo, Hongo, Bunkyo, Tokyo 113-8656 (Japan); Synchrotron Radiation Research Organization, University of Tokyo, Koto, Shingu-cho, Tatsuno, Hyogo 679-5165 (Japan); Senba, Yasunori; Ohashi, Haruhiko [Japan Synchrotron Radiation Research Institute (JASRI), Koto, Sayo-cho, Sayo, Hyogo 679-5198 (Japan); Tokushima, Takashi; Horikawa, Yuka [RIKEN/SPring-8, Sayo-cho, Sayo, Hyogo 679-5148 (Japan); Shin, Shik [RIKEN/SPring-8, Sayo-cho, Sayo, Hyogo 679-5148 (Japan); CREST, Japan Science and Technology (JST), Kawaguchi, Saitama 332-0012 (Japan); Institute for Solid State Physics, University of Tokyo, Kashiwa, Chiba 277-8581 (Japan); Oshima, Masaharu [Department of Applied Chemistry, Graduate School of Engineering, University of Tokyo, Hongo, Bunkyo, Tokyo 113-8656 (Japan); Synchrotron Radiation Research Organization, University of Tokyo, Koto, Shingu-cho, Tatsuno, Hyogo 679-5165 (Japan); CREST, Japan Science and Technology (JST), Kawaguchi, Saitama 332-0012 (Japan)

2012-01-15T23:59:59.000Z

384

Monte Carlo study of the performance of a time-of-flight multichopper spectrometer  

SciTech Connect

The Monte Carlo method is a powerful technique for neutron transport studies. While it has been applied for many years to the study of nuclear systems, there are few codes available for neutron transport in the optical regime. The recent surge of interest in so-called next generation spallation neutron sources and the desire to design new and optimized instruments for these facilities has led us to develop a Monte Carlo code geared toward the simulation of neutron scattering instruments. The time-of-flight multichopper spectrometer, of which IN5 at the ILL is the prototypical example, is the first spectrometer studied with the code. Some of the results of a comparison between the IN5 performance at a reactor and at a Long Pulse Spallation Source (LPSS) are summarized here.

Daemen, L.L.; Eckert, J.; Pynn, R. [and others

1995-12-01T23:59:59.000Z

385

The super separator spectrometer (S{sup 3}) for SPIRAL2 stable beams.  

SciTech Connect

S{sup 3} (Super Separator Spectrometer) is a device designed for experiments with the very high intensity stable beams of LINAG, the superconducting linear accelerator of GANIL, which will be built in the framework of SPIRAL2. These beams can reach intensities exceeding 100p{mu}A for lighter ions. These unprecedented intensities open new opportunities in several physics domains, e.g. super-heavy and very-heavy element properties, spectroscopy at and beyond the dripline, isomer and ground state properties, and the products of multi-nucleon transfer and deep-inelastic reactions. An international collaboration has been formed for proposing physics experiments and developing technical solutions for this new instrument. We present here the optical layout of the spectrometer and the studies of its multipole magnets.

Drouart, A.; Amthor, A. M.; Boutin, D.; Delferriere, O.; Duval, M.; Manikonda, S.; Nolen, J. A.; Payet, J.; Savajols, H.; Stodel, M.-H.; Uriot, D.; Physics; CEA-DSM /Irfu/SPhN; GANIL; CEA-DSM /Irfu/SACM

2010-01-01T23:59:59.000Z

386

The new cold neutron chopper spectrometer at the Spallation Neutron Source: Design and performance  

SciTech Connect

The design and performance of the new cold neutron chopper spectrometer (CNCS) at the Spallation Neutron Source in Oak Ridge are described. CNCS is a direct-geometry inelastic time-of-flight spectrometer, designed essentially to cover the same energy and momentum transfer ranges as IN5 at ILL, LET at ISIS, DCS at NIST, TOFTOF at FRM-II, AMATERAS at J-PARC, PHAROS at LANSCE, and NEAT at HZB, at similar energy resolution. Measured values of key figures such as neutron flux at sample position and energy resolution are compared between measurements and ray tracing Monte Carlo simulations, and good agreement (better than 20% of absolute numbers) has been achieved. The instrument performs very well in the cold and thermal neutron energy ranges, and promises to become a workhorse for the neutron scattering community for quasielastic and inelastic scattering experiments.

Ehlers, G.; Podlesnyak, A. A.; Niedziela, J. L.; Iverson, E. B. [Neutron Scattering Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Sokol, P. E. [Department of Physics, Indiana University, Bloomington, Indiana 47405 (United States)

2011-08-15T23:59:59.000Z

387

Development of a Time-resolved Soft X-ray Spectrometer for Laser Produced Plasma Experiments  

SciTech Connect

A 2400 line/mm variable spaced grating spectrometer (VSG) has been used to measure soft x-ray emission (8-22 {angstrom}) from laser-produced plasma experiments at Lawrence Livermore National Laboratory's Compact Multipulse Terrawatt (COMET) Laser Facility. The spectrometer was coupled to a Kentech x-ray streak camera to study the temporal evolution of soft x-rays emitted from the back of mylar and copper foils irradiated at 10{sup 15} W/cm{sup 2}. The instrument demonstrated a resolving power of {approx} 120 at 19 {angstrom} with a time resolution of 31 ps. The time-resolved copper emission spectrum was consistent with a photodiode monitoring the laser temporal pulse shape and indicated that the soft x-ray emission follows the laser heating of the target. The time and spectral resolution of this diagnostic make it useful for studies of high temperature plasmas.

Cone, K V; Dunn, J; Schneider, M B; Baldis, H A; Brown, G V; Emig, J; James, D L; May, M J; Park, J; Shepherd, R; Widmann, K

2010-05-12T23:59:59.000Z

388

Development of a time-resolved soft x-ray spectrometer for laser produced plasma experiments  

SciTech Connect

A 2400 lines/mm variable-spaced grating spectrometer has been used to measure soft x-ray emission (8-22 A) from laser-produced plasma experiments at Lawrence Livermore National Laboratory's Compact Multipulse Terrawatt (COMET) Laser Facility. The spectrometer was coupled to a Kentech x-ray streak camera to study the temporal evolution of soft x rays emitted from the back of the Mylar and the copper foils irradiated at 10{sup 15} W/cm{sup 2}. The instrument demonstrated a resolving power of {approx}120 at 19 A with a time resolution of 31 ps. The time-resolved copper emission spectrum was consistent with a photodiode monitoring the laser temporal pulse shape and indicated that the soft x-ray emission follows the laser heating of the target. The time and spectral resolutions of this diagnostic make it useful for studies of high temperature plasmas.

Cone, K. V.; Park, J. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); University of California at Davis, Davis, California 95616 (United States); Dunn, J.; Schneider, M. B.; Brown, G. V.; Emig, J.; James, D. L.; May, M. J.; Shepherd, R.; Widmann, K. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Baldis, H. A. [University of California at Davis, Davis, California 95616 (United States)

2010-10-15T23:59:59.000Z

389

A Compact, Backscattering Deplolarization Cloud Spectrometer for Ice and Water Discrimination  

SciTech Connect

This project was to develop a compact optical particle spectrometer, small enough for operation on UAVS, that measures the optical diameter of cloud hydrometeors and differentiates their water phase (liquid or solid). To reach this goal, a work plan was laid out that would complete three objectives: 1) Evaluation of designs for an optical particle spectrometer that measures the component of light backscattered at two polarization angles. 2) Testing of selected designs on an optical bench. 3) Construction and preliminary testing of a prototype instrument based on the selected, optimum design. A protoype instrument was developed and tested in an icing wind tunnel where the results showed good measurement of cloud droplets and ice particles.

Thomson, David

2014-05-15T23:59:59.000Z

390

In-situ, nondestructive identification of chemical elements by means of portable EDXRF spectrometer  

SciTech Connect

The performances of a new portable EDXRF (Energy Dispersive X-ray Fluorescence) Spectrometer designed for in-situ, non-destructive identification of chemical elements in materials are here described. The instrument, based on a Silicon Drift Detector cooled by a Peltier element, does not require a liquid nitrogen cooling system. The energy resolution of the spectrometer is typically 155 eV FWHM at 6 keV at a temperature of about {minus}8 C and the peak to valley ratio is better than 10,000. The paper reports on the most significant results recently obtained, by using a new version of the Silicon Drift Detector, in measurements carried out on-the-field on samples of different materials. The results of the first quantitative analyses of metal alloys carried out with this instrument are also presented.

Fiorini, C.; Longoni, A.

1999-12-01T23:59:59.000Z

391

Spectrometer for X-ray emission experiments at FERMI free-electron-laser  

SciTech Connect

A portable and compact photon spectrometer to be used for photon in-photon out experiments, in particular x-ray emission spectroscopy, is presented. The instrument operates in the 25–800 eV energy range to cover the full emissions of the FEL1 and FEL2 stages of FERMI. The optical design consists of two interchangeable spherical varied-lined-spaced gratings and a CCD detector. Different input sections can be accommodated, with/without an entrance slit and with/without an additional relay mirror, that allow to mount the spectrometer in different end-stations and at variable distances from the target area both at synchrotron and at free-electron-laser beamlines. The characterization on the Gas Phase beamline at ELETTRA Synchrotron (Italy) is presented.

Poletto, L., E-mail: poletto@dei.unipd.it; Frassetto, F.; Miotti, P. [CNR - Institute of Photonics and Nanotechnologies (CNR-IFN), via Trasea 7, I-35131 Padova (Italy); Di Cicco, A.; Iesari, F. [Physics Division, School of Science and Technology, Università di Camerino, I-62032 Camerino (Italy); Finetti, P. [ELETTRA - Sincrotrone Trieste, Basovizza Area Science Park, S. S. 14 - km 163,5, I-34149, Basovizza (TS) (Italy); Grazioli, C. [Department of Chemical and Pharmaceutical Sciences, University of Trieste, Via L. Giorgieri 1, I-34127 Trieste (Italy); CNR-Istituto Officina dei Materiali (CNR-IOM), Laboratorio TASC, I-34149 Trieste (Italy); Kivimäki, A. [CNR-Istituto Officina dei Materiali (CNR-IOM), Laboratorio TASC, I-34149 Trieste (Italy); Stagira, S. [Politecnico di Milano – Department of Physics, I-20133 Milano (Italy); Coreno, M. [ELETTRA - Sincrotrone Trieste, Basovizza Area Science Park, S. S. 14 - km 163,5, I-34149, Basovizza (TS) (Italy); CNR – Istituto di Struttura della Materia (CNR-ISM), UOS Basovizza, I-34149 Trieste (Italy)

2014-10-15T23:59:59.000Z

392

Calculation of the Johann error for spherically bent x-ray imaging crystal spectrometers  

SciTech Connect

New x-ray imaging crystal spectrometers, currently operating on Alcator C-Mod, NSTX, EAST, and KSTAR, record spectral lines of highly charged ions, such as Ar{sup 16+}, from multiple sightlines to obtain profiles of ion temperature and of toroidal plasma rotation velocity from Doppler measurements. In the present work, we describe a new data analysis routine, which accounts for the specific geometry of the sightlines of a curved-crystal spectrometer and includes corrections for the Johann error to facilitate the tomographic inversion. Such corrections are important to distinguish velocity induced Doppler shifts from instrumental line shifts caused by the Johann error. The importance of this correction is demonstrated using data from Alcator C-Mod.

Wang, E.; Beiersdorfer, P.; Gu, M. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Bitter, M.; Delgado-Aparicio, L.; Hill, K. W. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Reinke, M.; Rice, J. E.; Podpaly, Y. [Plasma Fusion Center, MIT, Cambridge, Massachusetts 02139-4307 (United States)

2010-10-15T23:59:59.000Z

393

THE COSMIC INFRARED BACKGROUND EXPERIMENT (CIBER): THE NARROW-BAND SPECTROMETER  

SciTech Connect

We have developed a near-infrared spectrometer designed to measure the absolute intensity of the solar 854.2 nm Ca II Fraunhofer line, scattered by interplanetary dust, in the zodiacal light (ZL) spectrum. Based on the known equivalent line width in the solar spectrum, this measurement can derive the zodiacal brightness, testing models of the ZL based on morphology that are used to determine the extragalactic background light in absolute photometry measurements. The spectrometer is based on a simple high-resolution tipped filter placed in front of a compact camera with wide-field refractive optics to provide the large optical throughput and high sensitivity required for rocket-borne observations. We discuss the instrument requirements for an accurate measurement of the absolute ZL brightness, the measured laboratory characterization, and the instrument performance in flight.

Korngut, P. M.; Bock, J. [Jet Propulsion Laboratory (JPL), National Aeronautics and Space Administration (NASA), Pasadena, CA 91109 (United States); Renbarger, T.; Keating, B. [Department of Physics, University of California, San Diego, San Diego, CA 92093 (United States); Arai, T.; Matsumoto, T.; Matsuura, S. [Department of Space Astronomy and Astrophysics, Institute of Space and Astronautical Science (ISAS), Japan Aerospace Exploration Agency (JAXA), Sagamihara, Kanagawa 252-5210 (Japan); Battle, J.; Hristov, V.; Lanz, A.; Levenson, L. R.; Mason, P. [Department of Physics, California Institute of Technology, Pasadena, CA 91125 (United States); Brown, S. W.; Lykke, K. R.; Smith, A. W. [Sensor Science Division, National Institute of Standards and Technology (NIST), Gaithersburg, MD 20899 (United States); Cooray, A. [Center for Cosmology, University of California, Irvine, Irvine, CA 92697 (United States); Kim, M. G. [Department of Physics and Astronomy, Seoul National University, Seoul 151-742 (Korea, Republic of); Lee, D. H.; Nam, U. W. [Korea Astronomy and Space Science Institute (KASI), Daejeon 305-348 (Korea, Republic of); Shultz, B., E-mail: pkorngut@caltech.edu [Materion Barr Precision Optics and Thin Film Coatings, Westford, MA 01886 (United States); and others

2013-08-15T23:59:59.000Z

394

X-Ray Imaging Crystal Spectrometer for Extended X-Ray Sources  

SciTech Connect

Spherically or toroidally curved, double focusing crystals are used in a spectrometer for X-ray diagnostics of an extended X-ray source such as a hot plasma produced in a tokamak fusion experiment to provide spatially and temporally resolved data on plasma parameters such as ion temperature, toroidal and poloidal rotation, electron temperature, impurity ion charge-state distributions, and impurity transport. The imaging properties of these spherically or toroidally curved crystals provide both spectrally and spatially resolved X-ray data from the plasma using only one small spherically or toroidally curved crystal, thus eliminating the requirement for a large array of crystal spectrometers and the need to cross-calibrate the various crystals.

Bitter, Manfred L.; Fraekel, Benjamin; Gorman, James L.; Hill, Kenneth W.; Roquemore, Lane A.; Stodiek, Wolfgang; Goeler, Schweickhard von

1999-05-01T23:59:59.000Z

395

Spectrometer for Sky-Scanning Sun-Tracking Atmospheric Research (4STAR): Instrument Technology  

SciTech Connect

The Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) combines airborne sun tracking and sky scanning with diffraction spectroscopy, to improve knowledge of atmospheric constituents and their links to air-pollution/climate. Direct beam hyper-spectral measurement of optical depth improves retrievals of gas constituents and determination of aerosol properties. Sky scanning enhances retrievals of aerosol type and size distribution. 4STAR measurements will tighten the closure between satellite and ground-based measurements. 4STAR incorporates a modular sun-tracking/ sky-scanning optical head with fiber optic signal transmission to rack mounted spectrometers, permitting miniaturization of the external optical head, and future detector evolution. Technical challenges include compact optical collector design, radiometric dynamic range and stability, and broad spectral coverage. Test results establishing the performance of the instrument against the full range of operational requirements are presented, along with calibration, engineering flight test, and scientific field campaign data and results.

Dunagan, Stephen; Johnson, Roy; Zavaleta, Jhony; Russell, P. B.; Schmid, Beat; Flynn, Connor J.; Redemann, Jens; Shinozuka, Yohei; Livingston, J.; Segal Rozenhaimer, Michal

2013-08-06T23:59:59.000Z

396

Compact Reflective Imaging Spectrometer Design Utilizing An Immersed Grating And Anamorphic Mirror  

DOE Patents (OSTI)

A compact imaging spectrometer comprising an entrance slit, an anamorphic mirror, a grating, and a detector array. The entrance slit directs light to the anamorphic mirror. The anamorphic mirror receives the light and directs the light to the grating. The grating receives the light from the anamorphic mirror and defracts the light back onto the anamorphic mirror. The anamorphic mirror focuses the light onto a detector array.

Lerner, Scott A. (Corvalis, OR)

2006-01-10T23:59:59.000Z

397

A magnetic spectrometer measurement of the charge ratio of energetic cosmic ray muons  

E-Print Network (OSTI)

" of 35 Bev. Th, . " periment has been carried out with a magnetic momentum spectrometer-telescope consisting of two separate solid- izon magnets in conjun tinn iwith detectors of penetrating ionizing particles. The incident particles recorded were... directions of the particles as they entered the top magnet and the exit directions from the lower magnet. The magnitudes and directions of the deflections in the known magnetic field have then been used to determine the moments and charges...

Bateman, Benjamin Jefferson

2012-06-07T23:59:59.000Z

398

Extending the response of the sum coincidence spectrometer to multiple gamma radiation cascades  

E-Print Network (OSTI)

). crystal of sodium iodide with the sample placed inside of it is used. For larger crystals there is less probability of part of the gamma-ray energy escaping. This method gives a high detection efficiency; however, the resolution of large crystals can... be limited by light collection problems. For precision gamma-ray spectroscopy, high resolution out-weighs the disadvantage of low detection efficiency. The three-crystal scintillation spectrometer, developed by Maieschein' and Bair5, gives higher counting...

Helton, Victor Dean

1964-01-01T23:59:59.000Z

399

On the characterisation of a Bragg spectrometer with X-rays from an ECR source  

E-Print Network (OSTI)

Narrow X-ray lines from helium-like argon emitted from a dedicated ECR source have been used to determine the response function of a Bragg crystal spectrometer equipped with large area spherically bent silicon (111) or quartz (10$\\bar{1}$) crystals. The measured spectra are compared with simulated ones created by a ray-tracing code based on the expected theoretical crystal's rocking curve and the geometry of the experimental set-up.

Anagnostopoulos, D F; Gotta, D; Gruber, A; Indelicato, P J; Leoni, B; Fuhrmann, H; Simons, L M; Stingelin, L; Wasser, A; Zmeskal, J; Indelicato, Paul

2004-01-01T23:59:59.000Z

400

A design study of VOR: a versatile optimal resolution chopper spectrometer for the ESS  

E-Print Network (OSTI)

VOR, the versatile optimal resolution chopper spectrometer, is designed to probe dynamic phenomena that are currently inaccessible for inelastic neutron scattering due to flux limitations. VOR is a short instrument by the standards of the European Spallation Source (ESS), 30.2 m moderator to sample, and provides instantaneous access to a broad dynamic range, 1 - 120 meV within each ESS period. The short instrument length combined with the long ESS pulse width enables a quadratic flux increase, even at longer wavelengths, by relaxing energy resolution from $\\Delta$E/E = 1% up to $\\Delta$E/E = 7%. This is impossible both on a long chopper spectrometer at the ESS and with instruments at short pulsed sources. In comparison to current day chopper spectrometers, VOR can offer an order of magnitude improvement in flux for equivalent energy resolutions, $\\Delta$E/E = 1-3%. Further relaxing the energy resolution enables VOR to gain an extra order of magnitude in flux. In addition, VOR has been optimised for repetition...

Deen, P P; Andersen, K H; Hall-Wilton, R

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Status of SuperSpec: A Broadband, On-Chip Millimeter-Wave Spectrometer  

E-Print Network (OSTI)

SuperSpec is a novel on-chip spectrometer we are developing for multi-object, moderate resolution (R = 100 - 500), large bandwidth (~1.65:1) submillimeter and millimeter survey spectroscopy of high-redshift galaxies. The spectrometer employs a filter bank architecture, and consists of a series of half-wave resonators formed by lithographically-patterned superconducting transmission lines. The signal power admitted by each resonator is detected by a lumped element titanium nitride (TiN) kinetic inductance detector (KID) operating at 100-200 MHz. We have tested a new prototype device that is more sensitive than previous devices, and easier to fabricate. We present a characterization of a representative R=282 channel at f = 236 GHz, including measurements of the spectrometer detection efficiency, the detector responsivity over a large range of optical loading, and the full system optical efficiency. We outline future improvements to the current system that we expect will enable construction of a photon-noise-lim...

Hailey-Dunsheath, S; Barry, P S; Bradford, C M; Chattopadhyay, G; Day, P; Doyle, S; Hollister, M; Kovacs, A; LeDuc, H G; Mauskopf, P; McKenney, C M; Monroe, R; O'Brient, R; Padin, S; Reck, T; Swenson, L; Tucker, C E; Zmuidzinas, J

2015-01-01T23:59:59.000Z

402

The lead-glass electromagnetic calorimeters for the magnetic spectrometers in Hall C at Jefferson Lab  

E-Print Network (OSTI)

The electromagnetic calorimeters of the various magnetic spectrometers in Hall C at Jefferson Lab are presented. For the existing HMS and SOS spectrometers design considerations, relevant construction information, and comparisons of simulated and experimental results are included. The energy resolution of the HMS and SOS calorimeters is better than $\\sigma/E \\sim 6%/\\sqrt E $, and pion/electron ($\\pi/e$) separation of about 100:1 has been achieved in energy range 1 -- 5 GeV. Good agreement has been observed between the experimental and simulated energy resolutions, but simulations systematically exceed experimentally determined $\\pi^-$ suppression factors by close to a factor of two. For the SHMS spectrometer presently under construction details on the design and accompanying GEANT4 simulation efforts are given. The anticipated performance of the new calorimeter is predicted over the full momentum range of the SHMS. Good electron/hadron separation is anticipated by combining the energy deposited in an initial (preshower) calorimeter layer with the total energy deposited in the calorimeter.

H. Mkrtchyan; R. Carlini; V. Tadevosyan; J. Arrington; A. Asaturyan; M. E. Christy; D. Dutta; R. Ent; H. C. Fenker; D. Gaskell; T. Horn; M. K. Jones; C. E. Keppel; D. J. Mack; S. P. Malace; A. Mkrtchyan; M. I. Niculescu; J. Seely; V. Tvaskis; S. A. Wood; S. Zhamkochyan

2012-04-28T23:59:59.000Z

403

Mass of Ca-36  

E-Print Network (OSTI)

PH YS ICA 1. RE VIK W C VO I. UMK 15, 5 UMBER 6 Mass of ~Cat R. E. Tribble, ~ J. D. Cossairt, and R. A. Kenefick Cyclotron Institute and Physics Department, Texas AChM University, College Station, Texas 77843 (Received 14 October 1976) The ' Ca...('He, He)' Ca reaction has been used to provide the first observation of the nuclide ' Ca. The Q value and mass excess were found to be ?57.58~0.04 and ?6.44+0.04 MeV, respectively. The new mass completes four members of the A = 36 isobaric quintet...

Tribble, Robert E.; Cossairt, J. D.; Kenefick, R. A.

1977-01-01T23:59:59.000Z

404

Chromatographic speciation of anionic and neutral selenium compounds in Se-accumulating Brassica juncea (Indian mustard) and in selenized yeast  

Science Journals Connector (OSTI)

Selenium-accumulating plants such as Brassica juncea (Indian mustard) concentrate the element in plant shoots and roots. Such behavior may provide a cost-effective technology to clean up contaminated soils and waters that pose major environmental and human health problems (phytoremediation). Such ability to transform selenium into bioactive compounds has important implications for human nutrition and health. Element selective characterization of B. juncea grown in the presence of inorganic selenium under hydroponic conditions provides valuable information to better understand selenium metabolism in plants. The present work determines both previously observed organoselenium species such as selenomethionine and Se-methylselenocysteine and for the first time detects the newly characterized S-(methylseleno)cysteine in plant shoots and roots when grown in the presence of selenate or selenite as the only selenium source. A key feature of this study is the complementary role of selenium and sulfur specific chromatographic detection by HPLC with interfaced inductively coupled plasma mass spectrometry (ICP-MS) detection and by derivatization GC with interfaced atomic spectral emission. HPLC–ICP-MS limits of detection for such species were in the range 5–50 ng Se mL?1 in the injected extracts. Speciation profiles are compared with those of selenium-enriched yeast by both HPLC–ICP-MS and GC–AED.

Chethaka Kahakachchi; Harriet Totoe Boakye; Peter C. Uden; Julian F. Tyson

2004-01-01T23:59:59.000Z

405

Raman spectroscopy on Mars: identification of geological and bio-geological signatures in Martian analogues using miniaturized Raman spectrometers  

Science Journals Connector (OSTI)

...Department of Physics and Astronomy, Space Research Centre, University...with building spectrometers for space applications, including limited...Report. National Aeronautics and Space Administration. 77 Sharma...induced breakdown spectroscopy library for the Martian environment...

2014-01-01T23:59:59.000Z

406

Fast-neutron radiation effects in a silica-core optical fiber studied by a CCD-camera spectrometer  

Science Journals Connector (OSTI)

A simple CCD-camera spectrometer was deployed at the Los Alamos Spallation Radiation Effects Facility to characterize fast-neutron irradiation effects in several silica-based optical...

Griscom, D L; Gingerich, M E; Friebele, E J; Putnam, M; Unruh, W

1994-01-01T23:59:59.000Z

407

Bradbury-Nielsen gate electrode potential switching modes optimizing the ion packet time width in an ion mobility spectrometer  

Science Journals Connector (OSTI)

The methods minimizing duration of the output pulse of the ion mobility spectrometer at its maximum intensity were proposed in order to increase the instrument resolution. The optimal duration of the enabling pul...

Igor V. Kurnin; Nikolai V. Krasnov…

2014-06-01T23:59:59.000Z

408

A question of mass  

Science Journals Connector (OSTI)

We present a pedagogical discussion of spontaneous symmetry breaking the Goldstone theorem and the Higgs mechanism. If the Higgs boson is found it might provide an explanation of the origin of mass.

Jeremy Bernstein

2011-01-01T23:59:59.000Z

409

Heavy Hybrid mesons Masses  

E-Print Network (OSTI)

We estimate the ground state masses of the heavy hybrid mesons using a phenomenological QCD-type potential. 0^{- -},1^{- -},0^{- +},1^{- +} and 0^{+ -} J^{PC} states are considered.

F. Iddir; L. Semlala

2006-11-13T23:59:59.000Z

410

MASS POLITICAL MOBILIZATION  

E-Print Network (OSTI)

................................................................................................................................................... MASS POLITICAL MOBILIZATION ................................................................................................................................................... Boix & Stokes: The Oxford Handbook of Comparative Politics Boixandstokes-chap21 Revise Proof page 497 20.4.2007 12:41pm #12;Boix & Stokes: The Oxford Handbook of Comparative Politics Boixandstokes-chap21

411

Masses of Fundamental Particles  

E-Print Network (OSTI)

In the original paper entitled, "Masses of Fundamental Particles"(arXiv:1109.3705v5, 10 Feb 2012), not only the masses of fundamental particles including the weak bosons, Higgs boson, quarks, and leptons, but also the mixing angles of quarks and those of neutrinos are all explained and/or predicted in the unified composite models of quarks and leptons successfully. In this addendum entitled, "Higgs Boson Mass in the Minimal Unified Subquark Model", it is emphasized that the Higgs boson mass is predicted to be about 130Gev in the minimal unified subquark model, which agrees well with the experimental values of 125-126GeV recently found by the ATLAS and CMS Collaborations at the LHC.

Hidezumi Terazawa

2014-06-11T23:59:59.000Z

412

Mass of Cd104  

Science Journals Connector (OSTI)

A quadrupole-dipole-dipole-dipole spectrograph has been used with a 34.6 MeV proton beam to observe the Cd106(p, t)Cd104 reaction. The Q value is measured and a mass excess of -83 963(14) keV is inferred for Cd104.NUCLEAR REACTIONS Cd106(p, t)Cd104, E=34.6 MeV; Q value measured; mass excess inferred.

R. A. Dewberry; R. T. Kouzes; R. A. Naumann

1983-02-01T23:59:59.000Z

413

W Transverse Mass  

NLE Websites -- All DOE Office Websites (Extended Search)

Transverse Mass Histogram Transverse Mass Histogram Data for 49,844 candidate W events are in an Excel spreadsheet with the following data as shown in the table below: A B C D 1 Run No Event No W TMass GeV/c2 Bins 2 55237 19588 68.71732 3 55237 30799 72.19464 Get the data. Sort the data by ascending mass. Be sure to sort all the data in the first three columns! Make a histogram of the data. Rather than graphing the data as individual points, physicists group the data by mass. They consider the full range of the data and divide it into "bins" of equal range size. A histogram is a graph of the number of events in each bin vs. the bin range. They are looking for a peak in the data where most of the masses fall. This will be the value of the mass as detemined by that dataset, and the width of the distribution is a reflection of the errors in the measurements.

414

MAINTAINING HIGH RESOLUTION MASS SPECTROMETRY CAPABILITIES FOR NATIONAL NUCLEAR SECURITY ADMINISTRATION APPLICATIONS  

SciTech Connect

The Department of Energy (DOE) National Nuclear Security Administration (NNSA) has a specialized need for analyzing low mass gas species at very high resolutions. The currently preferred analytical method is electromagnetic sector mass spectrometry. This method allows the NNSA Nuclear Security Enterprise (NSE) to resolve species of similar masses down to acceptable minimum detection limits (MDLs). Some examples of these similar masses are helium-4/deuterium and carbon monoxide/nitrogen. Through the 1980s and 1990s, there were two vendors who supplied and supported these instruments. However, with declining procurements and down turns in the economy, the supply of instruments, service and spare parts from these vendors has become less available, and in some cases, nonexistent. The largest NSE user of this capability is the Savannah River Site (SRS), located near Aiken, South Carolina. The Research and Development Engineering (R&DE) Group in the Savannah River National Laboratory (SRNL) investigated the areas of instrument support that were needed to extend the life cycle of these aging instruments. Their conclusions, as to the focus areas of electromagnetic sector mass spectrometers to address, in order of priority, were electronics, software and hardware. Over the past 3-5 years, the R&DE Group has designed state of the art electronics and software that will allow high resolution legacy mass spectrometers, critical to the NNSA mission, to be operated for the foreseeable future. The funding support for this effort has been from several sources, including the SRS Defense Programs, NNSA Readiness Campaign, Pantex Plant and Sandia National Laboratory. To date, electronics systems have been upgraded on one development system at SRNL, two production systems at Pantex and one production system at Sandia National Laboratory. An NSE working group meets periodically to review strategies going forward. The R&DE Group has also applied their work to the electronics for a Thermal Ionization Mass Spectrometer (TIMS) instrument, which applies a similar mass spectrometric technology for resolving high mass isotopes, such as plutonium and uranium. Due to non-compete clauses for DOE, all work has been performed and applied to instruments which are obsolete and are no longer supported by the original vendor.

Wyrick, S.; Cordaro, J.; Reeves, G.; Mcintosh, J.; Mauldin, C.; Tietze, K.; Varble, D.

2011-06-06T23:59:59.000Z

415

Measurement of the light absorbing properties of diesel exhaust particles using a three-wavelength photoacoustic spectrometer  

Science Journals Connector (OSTI)

Abstract Diesel-exhaust particles (DEP) are one of the main anthropogenic sources of black carbon (BC) and organic matter (OM). Understanding the optical properties of DEP, including the enhancement of light absorption by BC due to coating and light absorption by OM, is important for evaluating the climate impact of DEP. In this study, a three-wavelength photoacoustic soot spectrometer (405, 532, and 781 nm) was used to investigate the wavelength-dependent optical properties of DEP emitted from a diesel engine vehicle running on a chassis dynamometer in transient driving mode (JE-05) and at a constant speed (either idling or driving at 70 km/h). Optical properties were measured after passing the diluted exhaust through a heater, set at 20, 47, or 300 °C (transient driving mode) or between 20 and 400 °C (constant driving mode). The OM accounted for, on average, ?40 and ?35% of the total mass concentration of DEP during the transient and constant driving modes, respectively. In transient driving mode, enhancements of scattering coefficients at 20 and 47 °C, and of the mass concentration of organics, were observed during the high-speed driving period (?80 km/h) corresponding to driving on a highway. No difference was observed in the absorption coefficients between heated and unheated particles at 781 nm for either the transient (including the high-speed driving period) or constant driving modes. These results indicate a lack of enhancement due to the lensing effect, possibly because the BC was mainly mixed externally with the OM or because it was located at the edges of particles under these experimental conditions. Contributions to total light absorption at 405 nm by the OM were estimated by comparing the wavelength dependence of the absorption coefficients with and without heating. A significant contribution by light-absorbing OM (20 ± 7%) to total light absorption at 405 nm was observed during the high-speed driving period of the JE-05 mode, while the contributions were small during other periods in the JE-05 mode (0 ± 8%) and the constant driving mode (idling: 4 ± 12%; driving at 70 km/h: 0 ± 16%).

Xuesong Guo; Tomoki Nakayama; Hiroyuki Yamada; Satoshi Inomata; Kenichi Tonokura; Yutaka Matsumi

2014-01-01T23:59:59.000Z

416

spectrometer | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

iron nanoparticles was quantified by monitoring the kinetics as well as products of carbon tetrachloride reduction, and significant differences in reactivity and chloroform...

417

Atomic mass compilation 2012  

SciTech Connect

Atomic mass reflects the total binding energy of all nucleons in an atomic nucleus. Compilations and evaluations of atomic masses and derived quantities, such as neutron or proton separation energies, are indispensable tools for research and applications. In the last decade, the field has evolved rapidly after the advent of new production and measuring techniques for stable and unstable nuclei resulting in substantial ameliorations concerning the body of data and their precision. Here, we present a compilation of atomic masses comprising the data from the evaluation of 2003 as well as the results of new measurements performed. The relevant literature in refereed journals and reports as far as available, was scanned for the period beginning 2003 up to and including April 2012. Overall, 5750 new data points have been collected. Recommended values for the relative atomic masses have been derived and a comparison with the 2003 Atomic Mass Evaluation has been performed. This work has been carried out in collaboration with and as a contribution to the European Nuclear Structure and Decay Data Network of Evaluations.

Pfeiffer, B., E-mail: bpfeiffe@uni-mainz.de [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany); GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany); Venkataramaniah, K. [Sri Sathya Sai Institute of Higher Learning, Prasanthinilayam (India)] [Sri Sathya Sai Institute of Higher Learning, Prasanthinilayam (India); Czok, U. [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany)] [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany); Scheidenberger, C. [GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany) [GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany); II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany)

2014-03-15T23:59:59.000Z

418

High-resolution x-ray spectroscopy with the EBIT Calorimeter Spectrometer  

SciTech Connect

The EBIT Calorimeter Spectrometer (ECS) is a production-class 36 pixel x-ray calorimeter spectrometer that has been continuously operating at the Electron Beam Ion Trap (EBIT) facility at Lawrence Livermore National Laboratory for almost 2 years. The ECS was designed to be a long-lifetime, turn-key spectrometer that couples high performance with ease of operation and minimal operator intervention. To this end, a variant of the Suzaku/XRS spaceflight detector system has been coupled to a low-maintenance cryogenic system consisting of a long-lifetime liquid He cryostat, and a closed cycle, {sup 3}He pre-cooled adiabatic demagnetization refrigerator. The ECS operates for almost 3 weeks between cryogenic servicing and the ADR operates at 0.05 K for more than 60 hours between automatic recycles under software control. Half of the ECS semiconductor detector array is populated with mid-band pixels that have a resolution of 4.5 eV FWHM, a bandpass from 0.05-12 keV, and a quantum efficiency of 95% at 6 keV. The other half of the array has thick HgTe absorbers that have a bandpass from 0.3 to over 100 keV, an energy resolution of 33 eV FWHM, and a quantum efficiency of 32% at 60 keV. In addition, the ECS uses a real-time, autonomous, data collection and analysis system developed for the Suzaku/XRS instrument and implemented in off-the-shelf hardware for the ECS. Here we will discuss the performance of the ECS instrument and its implementation as a turnkey cryogenic detector system.

Porter, F. Scott; Adams, Joseph S.; Kelley, Richard L.; Kilbourne, Caroline A. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Beiersdorfer, Peter; Brown, Gregory V.; Clementson, Joel; Frankel, Miriam [Lawrence Livermore National Laboratory, Livermore, CA 94550 (United States); Kahn, Steven M. [Stanford University, Stanford, CA 94305 (United States)

2009-12-16T23:59:59.000Z

419

High-resolution x-ray spectroscopy with the EBIT Calorimeter Spectrometer  

SciTech Connect

The EBIT Calorimeter Spectrometer (ECS) is a production-class 36 pixel x-ray calorimeter spectrometer that has been continuously operating at the Electron Beam Ion Trap (EBIT) facility at Lawrence Livermore National Laboratory for almost 2 years. The ECS was designed to be a long-lifetime, turn-key spectrometer that couples high performance with ease of operation and minimal operator intervention. To this end, a variant of the Suzaku/XRS spaceflight detector system has been coupled to a low-maintenance cryogenic system consisting of a long-lifetime liquid He cryostat, and a closed cycle, {sup 3}He pre-cooled adiabatic demagnetization refrigerator. The ECS operates for almost 3 weeks between cryogenic servicing and the ADR operates at 0.05 K for more than 60 hours between automatic recycles under software control. Half of the ECS semiconductor detector array is populated with mid-band pixels that have a resolution of 4.5 eV FWHM, a bandpass from 0.05-12 keV, and a quantum efficiency of 95% at 6 keV. The other half of the array has thick HgTe absorbers that have a bandpass from 0.3 to over 100 keV, an energy resolution of 33 eV FWHM, and a quantum efficiency of 32% at 60 keV. In addition, the ECS uses a real-time, autonomous, data collection and analysis system developed for the Suzaku/XRS instrument and implemented in off-the-shelf hardware for the ECS. Here we will discuss the performance of the ECS instrument and its implementation as a turnkey cryogenic detector system.

Porter, F S; Adams, J S; Beiersdorfer, P; Brown, G V; Clementson, J; Frankel, M; Kahn, S M; Kelley, R L; Kilbourne, C A

2009-10-01T23:59:59.000Z

420

Low-temperature vacuum resonator for IRES-1001 and IRES-1003 EPR spectrometer-relaxometers  

SciTech Connect

A vacuum resonator for studying electron paramagnetic resonance at temperatures of 4.2-300 degrees K is described. The resonator allows recording of EPR spectra when the scanning time of the polarizing magnetic field greater than or equal to50 usec and its amplitude less than or equal to20 mT. Use of this resonator in the IRES-1001 EPR spectrometer relaxometer considerably increased the accuracy of studies of the temperature dependence of the spectra and the electron SLR times of the paramagnetic centers.

Troitskii, V.V.; Cheredintsev, V.G.; Dudkov, V.N.; Nuromtsev, V.I.

1985-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

The Los Alamos Fourier-transform spectrometer: Applications to molecular spectroscopy  

SciTech Connect

We outline design considerations and operating characteristics of the Los Alamos Fourier-transform spectrometer, a state-of-the-art instrument operating from 200 nm to 20 ..mu..m with a resolution of 0.0026 cm/sup /minus/1/ and very high wave number and intensity accuracy. Recent work in molecular spectroscopy carried out with this instrument will be discussed, including N/sub 2//sup +/ spectra obtained in inductively-coupled plasmas; high-temperature spectra of diatomic molecules of astrophysical interest; high-resolution rovibrational fine structure; and Fourier-transform Raman spectroscopy of species in expansion-cooled gases. 8 refs., 5 figs., 4 tabs.

Palmer, B.A.; McDowell, R.S.

1989-01-01T23:59:59.000Z

422

On the kinematics and resolution of spectrometers for neutron Brillouin scattering  

SciTech Connect

Neutron Brillouin scattering involves measurement of excitations at smaller Q values than in currently customary. We outline the kinematic constraints on scattering angle and incident energy for excitations with both linear dispersion (sound waves) and parabolic dispersion (ferromagnetic spin waves), and discuss the resolution characteristics of the chopper spectrometer proposed for LANSCE which should be suitable for such studies. In particular, we demonstrate that longitudinal resolution focusing can be exploited both in neutron energy gain and in neutron energy loss. 13 refs., 8 figs., 1 tab.

Robinson, R.A.

1988-01-01T23:59:59.000Z

423

A radial collimator for a time-of-flight neutron spectrometer  

SciTech Connect

We have engineered and installed a radial collimator for use in the scattered beam of a neutron time-of-flight spectrometer at a spallation neutron source. The radial collimator may be used with both thermal and epithermal neutrons, reducing the detected scattering intensity due to material outside of the sample region substantially. The collimator is located inside of the sample chamber of the instrument, which routinely cycles between atmospheric conditions and cryogenic vacuum. The oscillation and support mechanism of the collimator allow it to be removed from use without breaking vacuum. We describe here the design and characterization of this radial collimator.

Stone, Matthew B [ORNL; Niedziela, Jennifer L [ORNL; Loguillo, Mark [ORNL; Overbay, Mark A [ORNL; Abernathy, Douglas L [ORNL

2013-01-01T23:59:59.000Z

424

Determination of the Multipolarity of Nuclear Electromagnetic Transitions Using a Magnetic Pair Spectrometer  

Science Journals Connector (OSTI)

An intermediate-image magnetic pair spectrometer has been modified so as to respond to positron-electron internal pairs emitted at large relative angles (50°???90°) thereby making the pair-line transmission depend sensitively on the multipolarity of electromagnetic transitions above 2 MeV. The modification consists of a specially designed spiral baffle system which selects pairs emitted within 105° azimuthal sectors on opposite sides of the axis. Measurements are made of the net yield of an internal-pair-conversion coincidence line, both in the normal spectrometer operation (pairs with relative angles 0°???90°) and with the spiral baffle installed, giving a reduction ratio R?=Ywith baffle Ywithout baffle . Experimental ratios were determined for 14 known transitions including E0, E1, M1, E2, M2, and E3 multipoles between 3 and 7 MeV. Theoretical calculations were carried out on the spectrometer transmission, when using the baffle, for E0, E1 through E4, and M1 through M4 transitions from nonaligned nuclei over a wide energy range. These transmissions were combined with previous calculations of the transmission without the baffle in order to derive curves of R?(l) versus transition energy for the various multipoles. A best fit to the experimental ratios for the known multipoles was made in the calculations by adjusting slightly the values of the mean spectrometer-entrace angle and the sector angle ? of the baffle. The various ratio curves thus obtained are spaced widely enough apart to allow clear multipole assignments to be made in most cases. For mixed transitions from aligned nuclei, calculations were made of correction factors to be applied to the experimentally determined ratios. It is shown how the correction factors can be derived from separate measurements of the angular distributions of the corresponding gamma rays. The method has been applied to a number of previously unassigned transitions in Be10, B10, C14, and N14 leading to new spin and parity information on certain levels in these nuclei. In particular, it is found that the Be10 6.18-MeV level and the C14 6.58-MeV level are both 0+ and the N14 5.10-MeV level has odd parity.

E. K. Warburton; D. E. Alburger; A. Gallmann; P. Wagner; L. F. Chase; Jr.

1964-01-13T23:59:59.000Z

425

Full Hemisphere Fermi Surface Mapping Using A Novel Toroidal Electron Spectrometer  

SciTech Connect

An overview is provided of a next-generation toroidal angle-resolving photoemission spectrometer, currently in operation at BESSY II. The instrument features exceptional multi-detection in energy and angle, facilitating rapid full-hemisphere photoemission measurements. The instrument is ideal for band structure and Fermi Surface (FS) mapping using Angle Resolved Photoemission Spectroscopy (ARPES). Recent full-hemisphere FS measurements of a prototypical material, copper, reveal previously unseen fine structure due to lifetime broadening, demonstrating the high angular resolution and dense {kappa}-space sampling capabilities of the instrument.

Tadich, A. [Australian Synchrotron, Clayton, VIC 3168 (Australia); Department of Physics, La Trobe University, Bundoora, VIC 3086 (Australia); Riley, J.; Huwald, E.; Leckey, R. [Department of Physics, La Trobe University, Bundoora, VIC 3086 (Australia); Seyller, T.; Ley, L. [Institut fuer Technische Physik II, Universitaet Erlangen Nurnberg, 91058 Erlangen (Germany)

2010-06-23T23:59:59.000Z

426

Progress in development of neutron energy spectrometer for deuterium plasma operation in KSTAR  

SciTech Connect

Two types of DD neutron energy spectrometer (NES) are under development for deuterium plasma operation in KSTAR to understand behavior of beam ions in the plasma. One is based on the state-of-the-art nuclear emulsion technique. The other is based on a coincidence detection of a recoiled proton and a scattered neutron caused by an elastic scattering of an incident DD neutron, which is called an associated particle coincidence counting-NES. The prototype NES systems were installed at J-port in KSTAR in 2012. During the 2012 and 2013 experimental campaigns, multiple shots-integrated neutron spectra were preliminarily obtained by the nuclear emulsion-based NES system.

Tomita, H., E-mail: tomita@nagoya-u.jp; Yamashita, F.; Nakayama, Y.; Morishima, K.; Yamamoto, Y.; Sakai, Y.; Hayashi, S.; Kawarabayashi, J.; Iguchi, T. [Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Cheon, M. S. [Diagnostics Technology Team, ITER Korea, National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of); Isobe, M. [The Graduate University for Advanced Studies, 322-6 Oroshi-cho, Toki 509-5292 (Japan); National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan); Ogawa, K. [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan)

2014-11-15T23:59:59.000Z

427

A multi-object, multi-field spectrometer and imager for a European ELT  

E-Print Network (OSTI)

One of the highlights of the European ELT Science Case book is the study of resolved stellar populations, potentially out to the Virgo Cluster of galaxies. A European ELT would enable such studies in a wide range of unexplored distant environments, in terms of both galaxy morphology and metallicity. As part of a small study, a revised science case has been used to shape the conceptual design of a multi-object, multi-field spectrometer and imager (MOMSI). Here we present an overview of some key science drivers, and how to achieve these with elements such as multiplex, AO-correction, pick-off technology and spectral resolution.

Chris Evans; Colin Cunningham; Eli Atad-Ettedgui; Jeremy Allington-Smith; Francois Assemat; Gavin Dalton; Peter Hastings; Timothy Hawarden; Isobel Hook; Rob Ivison; Simon Morris; Suzanne Ramsay Howat; Mel Strachan; Stephen Todd

2006-05-19T23:59:59.000Z

428

The Mass Spectroscope  

Science Journals Connector (OSTI)

... THE handbook, prepared by M. G. Inghram of JL the University of Chicago, and R ... Committee on Nuclear Science of the National Research Council*, presents in some detail the fundamental design and operational techniques pertinent to the efficient utilization of the mass spectroscope. Attention ...

S. WEINTROUB

1955-03-12T23:59:59.000Z

429

Mass Media Science Fellows  

Science Journals Connector (OSTI)

...alternative energy sources, including solar, bio-mass, and geothermal. The changing...assistant secretary for con-servation and solar applications, U.S. Department of Energy...representative of the United Re-public of Tanzania to the United Na-tions, the resolution...

1979-12-07T23:59:59.000Z

430

Residential Thermal Mass Construction  

E-Print Network (OSTI)

The southwest has long known the value of building homes with high mass materials. The ancient Pueblo Indians found that by using "adobe" they could capture the energy necessary to survive the harsh desert climate. Our ancestors knew that a heavy...

Thieken, J. S.

1988-01-01T23:59:59.000Z

431

Top Quark Mass Measurements  

Science Journals Connector (OSTI)

First observed in 1995 the top quark is one of a pair of third?generation quarks in the Standard Model of particle physics. It has charge +2/3e and a mass of 171.4 GeV about 40 times heavier than its partner the bottom quark. The CDF and DØ collaborations have identified several hundred events containing the decays of top?antitop pairs in the large dataset collected at the Tevatron proton?antiproton collider over the last four years. They have used these events to measure the top quark’s mass to nearly 1% precision and to study other top quark properties. The mass of the top quark is a fundamental parameter of the Standard Model and knowledge of its value with small uncertainty allows us to predict properties of the as?yet?unobserved Higgs boson. This paper presents the status of the measurements of the top quark mass. It is based on a talk I gave at the Conference on the Intersections of Particle and Nuclear Physics in Puerto Rico May 2006 which also included discussion of measurements of other top quark properties.

A. P. Heinson; CDF Collaboration; DØ Collaboration

2006-01-01T23:59:59.000Z

432

Mass Extinctions Geology 331  

E-Print Network (OSTI)

into shallow water and released to atmosphere. · Oxidation of coal and hydrocarbons by extensive erosion of sedimentary rocks, and/or massive volcanic eruptions in Siberia? CH2O + O2 CO2 +H2O · Release of methane by rapid influx of C12 caused by methane release and mass dying at the end of the Permian. Organisms

Kammer, Thomas

433

Gauge Invariance and Mass  

Science Journals Connector (OSTI)

It is argued that the gauge invariance of a vector field does not necessarily imply zero mass for an associated particle if the current vector coupling is sufficiently strong. This situation may permit a deeper understanding of nucleonic charge conservation as a manifestation of a gauge invariance, without the obvious conflict with experience that a massless particle entails.

Julian Schwinger

1962-01-01T23:59:59.000Z

434

Nanoelectrospray ion generation for high-throughput mass spectrometry using a micromachined ultrasonic ejector array  

SciTech Connect

Ultrasonic electrospray ionization (ESI) for high-throughput mass spectrometry is demonstrated using a silicon micromachined microarray. The device uses a micromachined ultrasonic atomizer operating in the 900 kHz-2.5 MHz range for droplet generation and a metal electrode in the fluid cavity for ionization. Since the atomization and ionization processes are separated, the ultrasonic ESI source shows the potential for operation at low voltages with a wide range of solvents in contrast with conventional capillary ESI technology. This is demonstrated using the ultrasonic ESI microarray to obtain the mass spectrum of a 10 {mu}M reserpine sample on a time of flight mass spectrometer with 197:1 signal-to-noise ratio at an ionization potential of 200 V.

Aderogba, S.; Meacham, J.M.; Degertekin, F.L.; Fedorov, A.G.; Fernandez, F.M. [G.W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States); School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332 (United States)

2005-05-16T23:59:59.000Z

435

Elemental and isotopic analysis of inorganic salts by laser desorption ionization mass spectrometry  

SciTech Connect

Laser desorption ionization mass spectrometry is applied for the analysis of elements as well as their isotopic composition in different inorganic salts. At very low laser energies the inorganic ions are desorbed and ionized from the thin layer of the sample surface. The naturally occurring isotopes of alkali and silver ions are resolved using time of flight mass spectrometer. Further increase in laser energy shows the appearance of Al, Cr, and Fe ions in the mass spectra. This indicates the penetration laser beam beyond the sample surface leading to the ablation of sample target at higher energies. The simultaneous appearance of atomic ions from the sample target at relatively higher laser energies hampers the unambiguous identification of amino acid residues from the biomolecular ions in MALDI-MS.

Jayasekharan, T.; Sahoo, N. K. [Applied Spectroscopy Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India)

2013-02-05T23:59:59.000Z

436

Evaluation of the LLNL Spectrometer for Possible use with the NSTec Optical Streak Camera as a Light Gas Gun Diagnostic  

SciTech Connect

In fiscal year 2012, it was desired to combine a visible spectrometer with a streak camera to form a diagnostic system for recording time-resolved spectra generated in light gas gun experiments. Acquiring a new spectrometer was an option, but it was possible to borrow an existing unit for a period of months, which would be sufficient to evaluate both “off-line” and in-gas gun shots. If it proved adequate for this application, it could be duplicated (with possible modifications); if not, such testing would help determine needed specifications for another model. This report describes the evaluation of the spectrometer (separately and combined with the NSTec LO streak camera) for this purpose. Spectral and temporal resolutions were of primary interest. The first was measured with a monochromatic laser input. The second was ascertained by the combination of the spectrometer’s spatial resolution in the time-dispersive direction and the streak camera’s intrinsic temporal resolution. System responsivity was also important, and this was investigated by measuring the response of the spectrometer/camera system to black body input—the gas gun experiments are expected to be similar to a 3000K black body—as well as measuring the throughput of the spectrometer separately over a range of visible light provided by a monochromator. The flat field (in wavelength) was also measured and the final part of the evaluation was actual fielding on two gas gun shots. No firm specifications for spectral or temporal resolution were defined precisely, but these were desired to be in the 1–2 nm and 1–2 ns ranges, respectively, if possible. As seen below, these values were met or nearly met, depending on wavelength. Other performance parameters were also not given (threshold requirements) but the evaluations performed with laser, black body, and successful gas gun shots taken in aggregate indicate that the spectrometer is adequate for this purpose. Even still, some (relatively minor) opportunities for improvement were noticed and these were documented for incorporation into any near-duplicate spectrometer that might be fabricated in the future.

O'Connor, J., Cradick, J.

2012-09-27T23:59:59.000Z

437

Raman spectroscopic and mass spectrometric investigations of the hydrogen isotopes and isotopically labelled methane  

SciTech Connect

Suitable analytical methods must be tested and developed for monitoring the individual process steps within the fuel cycle of a fusion reactor and for tritium accountability. The utility of laser-Raman spectroscopy accompanied by mass spectrometry with an Omegatron was investigated using the analysis of all hydrogen isotopes and isotopically labeled methanes as an example. The Omegatron is useful for analyzing all hydrogen isotopes mixed with the stable helium isotopes. The application of this mass spectrometer were demonstrated by analyzing mixtures of deuterated methanes. In addition, it was employed to study the radiochemical Witzbach exchange reaction between tritium and methanes. A laser-Raman spectrometer was designed for analysis of tritium-containing gases and was built from individual components. A tritium-compatible, metal-sealed Raman cuvette having windows with good optical properties and additional means for measuring the stray light was first used successfully in this work. The Raman spectra of the hydrogen isotopes were acquired in the pure rotation mode and in the rotation-vibration mode and were used for on. The deuterated methanes were measured by Raman spectroscopy, the wavenumbers determined were assigned to the corresponding vibrations, and the wavenumbers for the rotational fine-structure were summarized in tables. The fundamental Vibrations of the deuterated methanes produced Witzbach reactions were detected and assigned. The fundamental vibrations of the molecules were obtained with Raman spectroscopy for the first time in this work. The @-Raman spectrometer assembled is well suited for the analysis of tritium- containing gases and is practical in combination with mass spectrometry using an Omegatron, for studying gases used in fusion.

Jewett, J.R., Fluor Daniel Hanford

1997-02-24T23:59:59.000Z

438

A Superconducting Tunnel Junction X-ray Spectrometer without Liquid Cryogens  

SciTech Connect

Superconducting tunnel junctions (STJs) are being developed as X-ray detectors because they combine the high energy resolution of cryogenic detector technologies with the high count rate capabilities of athermal devices. We have built STJ spectrometers for chemical analysis of dilute samples by high-resolution soft X-ray spectroscopy at the synchrotron. The instruments use 36 pixels of 200 {micro}m x 200 {micro}m Nb-Al-AlOx-Al-Nb STJs with 165 nm thick Nb absorber films. They have achieved an energy resolution of {approx}10-20 eV FWHM for X-ray energies below 1 keV, and can be operated at a total count rate of {approx}10{sup 6} counts/s. For increased user-friendliness, we have built a liquid-cryogen-free refrigerator based on a two-stage pulse tube cryocooler in combination with a two-stage adiabatic demagnetization stage. It holds the STJ detector at the end of a 40-cm-long cold finger, and attains the required operating temperature of {approx}0.3 K at the push of a button. We describe the instrument performance and present speciation measurements on Eu dopant activators in the novel scintillator material SrI{sub 2} to illustrate the potential for STJ spectrometers at the synchrotron.

Friedrich, S; Hertrich, T; Drury, O B; Cherepy, N J; Hohne, J

2008-06-15T23:59:59.000Z

439

Micromegas Detectors for the Muon Spectrometer Upgrade of the ATLAS Experiment  

E-Print Network (OSTI)

The Micromegas (MICRO MEsh GAseous Structure) have been proven along the years to be reliable detectors with excellent space resolution and high rate capability. Large area Micromegas will be employed for the first time in high-energy physics for the Muon Spectrometer upgrade of the ATLAS experiment at CERN LHC. A total surface of about 150 m$^2$ of the forward regions of the Muon Spectrometer will be equipped with 8 layers of Micromegas modules. Each module covers a surface from 2 to 3 m$^2$ for a total active area of 1200 m$^2$. Together with the small-strips Thin Gap Chambers, they will compose the two New Small Wheels, which will replace the innermost stations of the ATLAS Endcap Muon tracking system in the 2018/19 shutdown. The breakthroughs and developments of this type of Micro Pattern Gas Detector will be reviewed, along with the path towards the construction of the modules, which will take place in several production sites starting in 2015. An overview of the detector performances obtained in the rec...

Iodice, Mauro; The ATLAS collaboration

2014-01-01T23:59:59.000Z

440

Micromegas Detectors for the Muon Spectrometer Upgrade of the ATLAS Experiment  

E-Print Network (OSTI)

The Micromegas (MICRO MEsh GAseous Structure) chambers have been proven along the years to be reliable detectors with excellent space resolution and high rate capability. Large area Micromegas will be employed for the first time in high-energy physics for the Muon Spectrometer upgrade of the ATLAS experiment at CERN LHC. A total surface of about 150 m2 of the forward regions of the Muon Spectrometer will be equipped with 8 layers of Micromegas modules. Each module covers a surface from 2 to 3 m2 for a total active area of 1200 m2. Together with the small-strips Thin Gap Chambers, they will compose the two New Small Wheels, which will replace the innermost stations of the ATLAS Endcap Muon tracking system in the 2018/19 shutdown. The principles of operation and recent developments of this type of Micro Pattern Gas Detector will be reviewed, along with our plans towards the construction of the modules, which will take place in several production sites. An overview of the detector performances obtained in the re...

Iodice, M; The ATLAS collaboration

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "mass spectrometer icp-ms" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Imaging x-ray crystal spectrometers for the National Spherical Torus Experiment  

SciTech Connect

A new type of high-resolution x-ray imaging crystal spectrometers is described for implementation on the National Spherical Torus Experiment (NSTX) to provide spatially and temporally resolved data on the ion temperature, toroidal and poloidal plasma rotation, electron temperature, impurity ion-charge state distributions, and impurity transport. These data are derived from observations of the satellite spectra of heliumlike argon, ArthinspXVII, which is the dominant charge state for electron temperatures in the range from 0.4 to 3.0 keV and which is accessible to NSTX. Experiments at the Torus Experiment for Technology Oriented Research (TEXTOR) demonstrate that a throughput of 2{times}10{sup 5}thinspphotons/s (corresponding to the count-rate limit of the present detectors) can easily be obtained with small, nonperturbing argon gas puffs of less than 1{times}10{sup {minus}3}thinspTorrthinspscr(l)/s, so that it is possible to record spectra with a small statistical error and a good time resolution (typically 50 and 1 ms in some cases). Employing a novel design, which is based on the imaging properties of spherically bent crystals, the spectrometers will provide spectrally and spatially resolved images of the plasma for all experimental conditions, which include ohmically heated discharges as well as plasmas with rf and neutral-beam heating. The conceptual design, experimental results on the focusing properties, and relevant spectral data from TEXTOR are presented. {copyright} {ital 1999 American Institute of Physics.}

Bitter, M.; Hill, K.W.; Roquemore, A.L. [Princeton Plasma Physics Laboratory, Princeton University, Princeton, New Jersey 08543 (United States)] [Princeton Plasma Physics Laboratory, Princeton University, Princeton, New Jersey 08543 (United States); Beiersdorfer, P. [Department of Physics, Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)] [Department of Physics, Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Kahn, S.M. [Department of Physics, Columbia University, New York, New York 10027 (United States)] [Department of Physics, Columbia University, New York, New York 10027 (United States); Elliott, S.R. [Department of Physics, University of Washington, Seattle, Washington 98195 (United States)] [Department of Physics, University of Washington, Seattle, Washington 98195 (United States); Fraenkel, B. [Racah Institute of Physics, Hebrew University, Jerusalem (Israel)] [Racah Institute of Physics, Hebrew University, Jerusalem (Israel)

1999-01-01T23:59:59.000Z

442

HPLC AND Mass Spectroscopic Characterization of Mango (Mangifera Indica L.) Gallotannins Following Enzymatic Hydrolysis  

E-Print Network (OSTI)

Finnigan LCQ Deca XP Max MSn ion trap mass spectrometer equipped with an ESI ion source (ThermoFisher, San Jose, CA). Separation of compounds was completed with a Dionex (Sunnydale, CA) Acclaim? 120 A, (4.6 X 250 mm; 5?M). Mobile phases used included 0... was observed from incubation with both 13,000 U/mL and 20,000 U/mL ?-glucosidase. If all gallotannins were hydrolyzed into their respective moieties, the amount of increase observed after hydrolysis would be expected to be higher than an 8-fold increase...

Krenek, Kimberly A.

2009-06-09T23:59:59.000Z

443

Mass Market Demand Response  

NLE Websites -- All DOE Office Websites (Extended Search)

Mass Market Demand Response Mass Market Demand Response Speaker(s): Karen Herter Date: July 24, 2002 - 12:00pm Location: Bldg. 90 Demand response programs are often quickly and poorly crafted in reaction to an energy crisis and disappear once the crisis subsides, ensuring that the electricity system will be unprepared when the next crisis hits. In this paper, we propose to eliminate the event-driven nature of demand response programs by considering demand responsiveness a component of the utility obligation to serve. As such, demand response can be required as a condition of service, and the offering of demand response rates becomes a requirement of utilities as an element of customer service. Using this foundation, we explore the costs and benefits of a smart thermostat-based demand response system capable of two types of programs: (1) a mandatory,

444

Nanoscale mass conveyors  

DOE Patents (OSTI)

A mass transport method and device for individually delivering chargeable atoms or molecules from source particles is disclosed. It comprises a channel; at least one source particle of chargeable material fixed to the surface of the channel at a position along its length; a means of heating the channel; and a means for applying an controllable electric field along the channel, whereby the device transports the atoms or molecules along the channel in response to applied electric field. In a preferred embodiment, the mass transport device will comprise a multiwalled carbon nanotube (MWNT), although other one dimensional structures may also be used. The MWNT or other structure acts as a channel for individual or small collections of atoms due to the atomic smoothness of the material. Also preferred is a source particle of a metal such as indium. The particles move by dissociation into small units, in some cases, individual atoms. The particles are preferably less than 100 nm in size.

Regan, Brian C. (Oakland, CA); Aloni, Shaul (Albany, CA); Zettl, Alexander K. (Kensington, CA)

2008-03-11T23:59:59.000Z

445

CAMEA ESS - The Continuous Angle Multi-Energy Analysis Indirect Geometry Spectrometer for the European Spallation Source  

E-Print Network (OSTI)

The CAMEA ESS neutron spectrometer is designed to achieve a high detection efficiency in the horizontal scattering plane, and to maximize the use of the long pulse European Spallation Source. It is an indirect geometry time-of-flight spectrometer that uses crystal analysers to determine the final energy of neutrons scattered from the sample. Unlike other indirect gemeotry spectrometers CAMEA will use ten concentric arcs of analysers to analyse scattered neutrons at ten different final energies, which can be increased to 30 final energies by use of prismatic analysis. In this report we will outline the CAMEA instrument concept, the large performance gain, and the potential scientific advancements that can be made with this instrument.

Freeman, P G; Markó, M; Bertelsen, M; Larsen, J; Christensen, N B; Lefmann, K; Jacobsen, J; Niedermayer, Ch; Juranyi, F; Ronnow, H M

2014-01-01T23:59:59.000Z

446

High-resolution, high-transmission soft x-ray spectrometer for the study of biological samples  

SciTech Connect

We present a variable line-space grating spectrometer for soft s-rays that coverst the photon energy range between 130 and 650 eV. The optical design is based on the Hettrick-Underwood principle and tailored to synchrotron-based studies of radiation-sensitive biological samples. The spectrometer is able to record the entire spectral range in one shot, i.e., without any mechanical motion, at a resolving power of 1200 or better. Despite is slitless design, such a resolving power can be achieved for a source spot as large as (30 x 3000) micrometers squared, which is important for keeping beam damage effects in radiation-sensitive samples low. The high spectrometer efficiency allows recording of comprehensive two-dimensional resonant inelastic soft x-ray scatters (RIXS) maps with good statistics within several minutes. This is exemplarily demonstrated for a RIXS map of highly oriented pyrolytic graphite, which was taken with 10 min.

Fuchs, Oliver; Weinhardt, L.; Blum, M.; Welgand, M.; Umbach, E.; Bar, M.; Heske, C.; Denlinger, J.; Chuang, Y.-D.; McKinney, W.; Hussain, Z.; Gullikson, E.; Jones, M.; Batson, P.; Nelles, B.; Follath, R.

2009-06-11T23:59:59.000Z

447

High-resolution, high-transmission soft x-ray spectrometer for the study of biological samples  

SciTech Connect

We present a variable line-space grating spectrometer for soft x-rays that covers the photon energy range between 130 and 650 eV. The optical design is based on the Hettrick-Underwood principle and tailored to synchrotron-based studies of radiation-sensitive biological samples. The spectrometer is able to record the entire spectral range in one shot, i.e., without any mechanical motion, at a resolving power of 1200 or better. Despite its slitless design, such a resolving power can be achieved for a source spot as large as 30x3000 mu m2, which is important for keeping beam damage effects in radiation-sensitive samples low. The high spectrometer efficiency allows recording of comprehensive two-dimensional resonant inelastic soft x-ray scattering (RIXS) maps with good statistics within several minutes. This is exemplarily demonstrated for a RIXS map of highly oriented pyrolytic graphite, which was taken within 10 min.

Fuchs, Oliver; Weinhardt, L.; Blum, M.; Weigand, M.; Umbach, E.; Bar, M.; Heske, Clemens; Denlinger, Jonathan; Chuang, Y.-D.; McKinney, Wayne; Hussain, Zahid; Gullikson, Eric; Jones, M.; Batson, Phil; Nelles, B.; Follath, R.

2009-03-09T23:59:59.000Z

448

Electrospray Ionization Mass Spectrometry  

SciTech Connect

Electrospray Ionization (ESI) is a process whereby gas phase ions are created from molecules in solution. As a solution exits a narrow tube in the presence of a strong electric field, an aerosol of charged droplets are is formed that produces gas phase ions as they it desolvates. ESI-MS comprises the creation of ions by ESI and the determination of their mass to charge ratio (m/z) by MS.

Kelly, Ryan T.; Marginean, Ioan; Tang, Keqi

2014-06-13T23:59:59.000Z

449

Top Mass and Properties  

E-Print Network (OSTI)

The top quark was discovered in 1995. The top quark mass is now well measured at the Tevatron, with uncertainty getting below 1% of the top mass. The world average from last year was 170.9 $\\pm$ 1.8 GeV/$c^2$. The new CDF measurement is 172 $\\pm$ 1.2 (stat) $\\pm$ 1.5 (sys) GeV/$c^2$, and D0 will soon present a new measurement. The top quark mass is an important parameter in the Standard Model, and should be measured as precisely as possible. To learn more about the top quark observed and study possible new physics, other properties also should be measured. At the Tevatron, the charge of the top quark can be measured directly. Examples of other properties studied and reported in this presentation are W helicity, top decay branching ratio to b ($R_b$), searches for $t \\to H b$ and for flavor changing neutral current (FCNC). The results are all consistent with the Standard Model within current statistics. With significantly more data being collected at the Tevatron, precision measurements of the top properties are just starting.

Yen-Chu Chen

2008-05-15T23:59:59.000Z

450

Mass spectrometry of proteins of known mass Andrew D. Miranker*  

E-Print Network (OSTI)

deter- mination has two significant advantages. First, the mass accuracy under these conditions to the orifice of the mass analyzer. As a result, there is a local separation of charges at the tip

Miranker, Andrew

451

"Gravitational mass" of information?  

E-Print Network (OSTI)

We hypothesize possible new types of forces that would be the result of new types of interactions, static and a slow transient, between objects with related information contents (pattern). Such mechanism could make material composition dependence claimed by Fishbach, et al in Eotvos type experiments plausible. We carried out experiments by using a high-resolution scale with the following memories: USB-2 flash drives (1-16GB), DVD and CD disks to determine if such an interaction exist/detectable with a scale resolution of 10 microgram with these test objects. We applied zero information, white noise and 1/f noise type data. Writing or deleting the information in any of these devices causes peculiar negative weight transients, up to milligrams (mass fraction around 10^-5), which is followed by various types of relaxation processes. These relaxations have significantly different dynamics compared to transients observed during cooling after stationary external heating. Interestingly, a USB-1 MP3 player has also developed comparable transient mass loss during playing music. A classical interpretation of the negative weight transients could be absorbed water in hygroscopic components however comparison of relaxation time constants with air humidity data does not support an obvious explanation. Another classical interpretation with certain contribution is the lifting Bernoulli force caused by the circulation due to convection of the warm air. However, in this case all observed time constants with a device should have been the same unless some hidden parameter causes the observed variations. Further studies are warranted to clarify if there is indeed a new force, which is showing up as negative mass at weight measurement when high-density structural information is changed or read out (measured).

Laszlo B. Kish

2007-11-08T23:59:59.000Z

452

Mass of Si-24  

E-Print Network (OSTI)

PHYSICAL REVIEW C VOLUME 22, NUMBER 1 JULY 1980 Mass of Si R. E. Tribble, D. M. Tanner, and A. F. Zeller* Cyclotron Institute and Physics Department, Texas A&M University, College Station, Texas 77843 (Received 11 January 1980) The Si( He, 'He... quintet. The theoretical predictions are from Ref. 14. Nuclides +Si- 4AI Al Mg +Mg 24Na +Na- 4Ne Experimental 4&, 5661(24) 5179(9) 4735(2) 42840. 0) Predicted &&, 5646 5184 4722 4260 15 -5 12 24 +37 +12 -12 -37 ay g@eXQ ~~ thearC C...

Tribble, Robert E.; Tanner, D. M.; Zeller, A. F.

1980-01-01T23:59:59.000Z

453

OPTIMIZATION OF A TWO-STAGE ADR FOR THE SOFT X-RAY SPECTROMETER (SXS) INSTRUMENT ON THE ASTRO-H MISSION  

SciTech Connect

NASA/Goddard Space Flight Center has begun developing the Soft X-ray Spectrometer (SXS) instrument that will be flown on the Japanese Astro-H mission. The SXS's 36-pixel detector array will be cooled to 50 mK using a two-stage adiabatic demagnetization refrigerator (ADR). A complicating factor for its design is that the ADR will be integrated into a superfluid helium dewar at 1.3 K that will be coupled to a 1.8 K Joule-Thomson (JT) stage through a heat switch. When liquid helium is present, the coupling will be weak, and the JT stage will act primarily as a shield to reduce parasitic heat loads. When the liquid is depleted, the heat switch will couple more strongly so that the ADR can continue to operate using the JT stage as its heat sink. A two-stage ADR is the most mass efficient option and it has the operational flexibility to work well with a stored cryogen and a cryocooler. The stages are operated independently, and this opens up a very large parameter space for optimizing the design. This paper discusses the optimization process and most relevant trades considered in the design of the SXS ADR, and its expected performance.

Shirron, P. J.; Kimball, M. O.; Wegel, D. C. [NASA/Goddard Space Flight Center, Greenbelt, MD, 20771 (United States); Miller, F. K. [University of Wisconsin, Dept. of Mech. Eng., Madison, WI, 53715 (United States)

2010-04-09T23:59:59.000Z

454

Hypervelocity Impact Effect of Molecules from Enceladus’ Plume and Titan’s Upper Atmosphere on NASA’s Cassini Spectrometer from Reactive Dynamics Simulation  

Science Journals Connector (OSTI)

The NASA/ESA Cassini probe of Saturn analyzed the molecular composition of plumes emanating from one of its moons, Enceladus, and the upper atmosphere of another, Titan. However, interpretation of this data is complicated by the hypervelocity (HV) flybys of up to ?18??km/sec that cause substantial molecular fragmentation. To interpret this data we use quantum mechanical based reactive force fields to simulate the HV impact of various molecular species and ice clathrates on oxidized titanium surfaces mimicking those in Cassini’s neutral and ion mass spectrometer (INMS). The predicted velocity dependent fragmentation patterns and composition mixing ratios agree with INMS data providing the means for identifying the molecules in the plume. We used our simulations to predict the surface damage from the HV impacts on the INMS interior walls, which we suggest acts as a titanium sublimation pump that could alter the instrument’s readings. These results show how the theory can identify chemical events from hypervelocity impacts in space plumes and atmospheres, providing in turn clues to the internal structure of the corresponding sources (e.g., Enceladus). This may be valuable in steering modifications in future missions.

Andres Jaramillo-Botero, Qi An, Mu-Jeng Cheng, William A. Goddard, III, Luther W. Beegle, and Robert Hodyss

2012-11-21T23:59:59.000Z

455

The Road to Ultrahigh-Resolution X-ray Spectrometers | Advanced Photon  

NLE Websites -- All DOE Office Websites (Extended Search)

How Atoms Behave: Characteristics of Microstructural Avalanches How Atoms Behave: Characteristics of Microstructural Avalanches Iodate Refuses to Intimidate Creating the Heart of a Planet in the Heart of a Gem How a Powerful Antibody Neutralizes HIV Taking a Page from Nature to Build Better Nanomaterials Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed The Road to Ultrahigh-Resolution X-ray Spectrometers NOVEMBER 22, 2011 Bookmark and Share Basic phenomena underlying the AD&AT x-ray optics. In x-ray Bragg diffraction from atomic planes composing nonzero angle η to the crystal entrance face, the crystal acts (a) like an optical prism dispersing the photons into a divergent x-ray fan with photons of different energies E

456

USING HINODE/EXTREME-ULTRAVIOLET IMAGING SPECTROMETER TO CONFIRM A SEISMOLOGICALLY INFERRED CORONAL TEMPERATURE  

SciTech Connect

The Extreme-Ultraviolet Imaging Spectrometer on board the HINODE satellite is used to examine the loop system described in Marsh et al. by applying spectroscopic diagnostic methods. A simple isothermal mapping algorithm is applied to determine where the assumption of isothermal plasma may be valid, and the emission measure locii technique is used to determine the temperature profile along the base of the loop system. It is found that, along the base, the loop has a uniform temperature profile with a mean temperature of 0.89 +- 0.09 MK which is in agreement with the temperature determined seismologically in Marsh et al., using observations interpreted as the slow magnetoacoustic mode. The results further strengthen the slow mode interpretation, propagation at a uniform sound speed, and the analysis method applied in Marsh et al. It is found that it is not possible to discriminate between the slow mode phase speed and the sound speed within the precision of the present observations.

Marsh, M. S.; Walsh, R. W., E-mail: mike.s.marsh@gmail.co [Jeremiah Horrocks Institute for Astrophysics and Supercomputing, University of Central Lancashire, Preston, PR1 2HE (United Kingdom)

2009-11-20T23:59:59.000Z

457

DETERMINATION OF THE AGR-1 CAPSULE TO FPMS SPECTROMETER TRANSPORT VOLUMES FROM LEADOUT FLOW TEST DATA  

SciTech Connect

The AGR-1 experiment is a fueled multiple-capsule irradiation experiment being conducted in the Advanced Test Reactor (ATR) in support of the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. A flow experiment conducted during the AGR-1 irradiation provided data that included the effect of flow rate changes on the decay of a short-lived radionuclide (23Ne). This data has been analyzed to determine the capsule-specific downstream transport volume through which the capsule effluents must pass before arrival at the fission product monitoring system spectrometers. These resultant transport volumes when coupled with capsule outlet flow rates determine the transport times from capsule-to-detector. In this work an analysis protocol is developed and applied in order to determine capsule-specific transport volumes to precisions of better than +/- 7%.

J. K. Hartwell; J. B. Walter; D. M. Scates; M. W. Drigert

2007-05-01T23:59:59.000Z

458

A comparison of four direct geometry time-of-flight spectrometers at the Spallation Neutron Source  

SciTech Connect

The Spallation Neutron Source at Oak Ridge National Laboratory now hosts four direct geometry time-of-flight chopper spectrometers. These instruments cover a range of wave-vector and energy transfer space with varying degrees of neutron flux and resolution. The regions of reciprocal and energy space available to measure at these instruments are not exclusive and overlap significantly. We present a direct comparison of the capabilities of this instrumentation, conducted by data mining the instrument usage histories, and specific scanning regimes. In addition, one of the common science missions for these instruments is the study of magnetic excitations in condensed matter systems. We have measured the powder averaged spin wave spectra in one particular sample using each of these instruments, and use these data in our comparisons.

Stone, M. B.; Abernathy, D. L.; Ehlers, G.; Garlea, O.; Podlesnyak, A.; Winn, B. [Quantum Condensed Matter Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)] [Quantum Condensed Matter Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Niedziela, J. L.; DeBeer-Schmitt, L.; Graves-Brook, M. [Instrument and Source Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)] [Instrument and Source Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Granroth, G. E. [Neutron Data Analysis and Visualization Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)] [Neutron Data Analysis and Visualization Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Kolesnikov, A. I. [Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)] [Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2014-04-15T23:59:59.000Z

459

A comparison of four direct geometry time-of-flight spectrometers at the Spallation Neutron Source  

SciTech Connect

The Spallation Neutron Source at Oak Ridge National Laboratory now hosts four direct geometry time-of-flight chopper spectrometers. These instruments cover a range of wave vector and energy transfer space with varying degrees of neutron flux and resolution. The regions of reciprocal and energy space available to measure at these instruments is not exclusive and overlaps significantly. We present a direct comparison of the capabilities of this instrumentation, conducted by data mining the instrument usage histories, and specific scanning regimes. In addition, one of the common science missions for these instruments is the study of magnetic excitations in condensed matter systems. We have measured the powder averaged spin wave spectra in one particular sample using each of these instruments, and use these data in our comparisons.

Stone, Matthew B [ORNL] [ORNL; Niedziela, Jennifer L [ORNL] [ORNL; Abernathy, Douglas L [ORNL] [ORNL; Debeer-Schmitt, Lisa M [ORNL] [ORNL; Garlea, Vasile O [ORNL] [ORNL; Granroth, Garrett E [ORNL] [ORNL; Graves-Brook, Melissa K [ORNL] [ORNL; Ehlers, Georg [ORNL] [ORNL; Kolesnikov, Alexander I [ORNL] [ORNL; Podlesnyak, Andrey A [ORNL] [ORNL; Winn, Barry L [ORNL] [ORNL

2014-01-01T23:59:59.000Z

460

The magnetic recoil spectrometer for measurements of the absolute neutron spectrum at OMEGA and the NIF  

SciTech Connect

The neutron spectrum produced by deuterium-tritium (DT) inertial confinement fusion implosions contains a wealth of information about implosion performance including the DT yield, ion-temperature, and areal-density. The Magnetic Recoil Spectrometer (MRS) has been used at both the OMEGA laser facility and the National Ignition Facility (NIF) to measure the absolute neutron spectrum from 3 to 30 MeV at OMEGA and 3 to 36 MeV at the NIF. These measurements have been used to diagnose the performance of cryogenic target implosions to unprecedented accuracy. Interpretation of MRS data requires a detailed understanding of the MRS response and background. This paper describes ab initio characterization of the system involving Monte Carlo simulations of the MRS response in addition to the commission experiments for in situ calibration of the systems on OMEGA and the NIF.

Casey, D. T.; Frenje, J. A.; Gatu Johnson, M.; Seguin, F. H.; Li, C. K.; Petrasso, R. D. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Glebov, V. Yu.; Katz, J.; Magoon, J.; Meyerhofer, D. D.; Sangster, T. C.; Shoup, M.; Ulreich, J. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States); Ashabranner, R. C.; Bionta, R. M.; Carpenter, A. C.; Felker, B.; Khater, H. Y.; LePape, S.; MacKinnon, A. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); and others

2013-04-15T23:59:59.000Z

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461

IBIS: An inverse geometry Brillouin inelastic neutron spectrometer for the SNS  

SciTech Connect

The high power target station at the Spallation Neutron Source (SNS) currently has about 20 completed neutron scattering instruments. With a broad coverage of the momentum transfer (Q)-energy (E) space, these instruments serve an extensive user community. In an effort to further expand the scientific capabilities of the SNS instrument suites, we propose a low background, inverse geometry Brillouin inelastic spectrometer for the SNS which will expand the Q-E coverage of the current instrument suite and facilitate the study of inelastic and quasi-elastic scatterings at low Q values. The possible location for the proposed instrument is either beamline 8 which views the decoupled water moderator, or beamline 14A, which views a cold, coupled super critical hydrogen moderator. The instrument parameters, optimizations, and performances at these two beamline locations are discussed.

Zhao, J. K.; Robertson, Lee; Herwig, Kenneth W. [Instrument and Source Development Division, Spallation Neutron Source, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Wildgruber, Christoph U. [Chemical and Engineering Division, Spallation Neutron Source, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2013-02-15T23:59:59.000Z

462

Tunable VUV laser based spectrometer for Angle Resolved Photoemission Spectroscopy (ARPES)  

E-Print Network (OSTI)

We have developed an angle-resolved photoemission spectrometer with tunable VUV laser as a photon source. The photon source is based on the fourth harmonic generation of a near IR beam from a Ti:sapphire laser pumped by a CW green laser and tunable between 5.3eV and 7eV. The most important part of the set-up is a compact, vacuum enclosed fourth harmonic generator based on KBBF crystals, grown hydrothermally in the US. This source can deliver a photon flux of over 10^14 photons/s. We demonstrate that this energy range is sufficient to measure the kz dispersion in an iron arsenic high temperature superconductor, which was previously only possible at synchrotron facilities.

Jiang, Rui; Wu, Yun; Huang, Lunan; McMillen, Colin D; Kolis, Joseph; Giesber, Henry G; Egan, John J; Kaminski, Adam

2014-01-01T23:59:59.000Z

463

A soft x-ray transmission grating imaging-spectrometer for the National Ignition Facility  

SciTech Connect

A soft x-ray transmission grating spectrometer has been designed for use on high energy-density physics experiments at the National Ignition Facility (NIF); coupled to one of the NIF gated x-ray detectors (GXD) it records sixteen time-gated spectra between 250 and 1000eV with 100ps temporal resolution. The trade-off between spectral and spatial resolution leads to an optimized design for measurement of emission around the peak of a 100-300eV blackbody spectrum. Performance qualification results from the NIF, the Trident Laser Facility and VUV beamline at the National Synchrotron Light Source (NSLS), evidence a <100{micro}m spatial resolution in combination with a source-size limited spectral resolution that is <10eV at photon energies of 300eV.

Moore, A S; Guymer, T M; Kline, J L; Morton, J; Taccetti, M; Lanier, N E; Bentley, C; Workman, J; Peterson, B; Mussack, K; Cowan, J; Prasad, R; Richardson, M; Burns, S; Kalantar, D H; Benedetti, L R; Bell, P; Bradley, D; Hsing, W; Stevenson, M

2012-05-01T23:59:59.000Z

464

Advances in compact proton spectrometers for inertial-confinement fusion and plasma nuclear science  

SciTech Connect

Compact wedge-range-filter proton spectrometers cover proton energies {approx}3-20 MeV. They have been used at the OMEGA laser facility for more than a decade for measuring spectra of primary D{sup 3}He protons in D{sup 3}He implosions, secondary D{sup 3}He protons in DD implosions, and ablator protons in DT implosions; they are now being used also at the National Ignition Facility. The spectra are used to determine proton yields, shell areal density at shock-bang time and compression-bang time, fuel areal density, and implosion symmetry. There have been changes in fabrication and in analysis algorithms, resulting in a wider energy range, better accuracy and precision, and better robustness for survivability with indirect-drive inertial-confinement-fusion experiments.

Seguin, F. H.; Sinenian, N.; Rosenberg, M.; Zylstra, A.; Manuel, M. J.-E.; Sio, H.; Waugh, C.; Rinderknecht, H. G.; Johnson, M. Gatu; Frenje, J.; Li, C. K.; Petrasso, R. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Sangster, T. C.; Roberts, S. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States)

2012-10-15T23:59:59.000Z

465

A soft x-ray transmission grating imaging-spectrometer for the National Ignition Facility  

SciTech Connect

A soft x-ray transmission grating spectrometer has been designed for use on high energy-density physics experiments at the National Ignition Facility (NIF); coupled to one of the NIF gated x-ray detectors it records 16 time-gated spectra between 250 and 1000 eV with 100 ps temporal resolution. The trade-off between spectral and spatial resolution leads to an optimized design for measurement of emission around the peak of a 100-300 eV blackbody spectrum. Performance qualification results from the NIF, the Trident Laser Facility and vacuum ultraviolet beamline at the National Synchrotron Light Source, evidence a <100 {mu}m spatial resolution in combination with a source-size limited spectral resolution that is <10 eV at photon energies of 300 eV.

Moore, A. S.; Guymer, T. M.; Morton, J.; Bentley, C.; Stevenson, M. [Directorate Science and Technology, AWE Aldermaston, Reading, RG7 4PR (United Kingdom); Kline, J. L.; Taccetti, M.; Lanier, N. E.; Workman, J.; Peterson, B.; Mussack, K.; Cowan, J. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Prasad, R.; Richardson, M.; Burns, S.; Kalantar, D. H.; Benedetti, L. R.; Bell, P.; Bradley, D.; Hsing, W. [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551-0808 (United States)

2012-10-15T23:59:59.000Z

466

Total Ozone Mapping Spectrometer (TOMS) Derived Data, Global Earth Coverage (GEC) from NASA's Earth Probe Satellite  

DOE Data Explorer (OSTI)

This is data from an external datastream processed through the ARM External Data Center (XDC) at Brookhaven National Laboratory. The XDC identifies sources and acquires data, called "external data", to augment the data being generated within the ARM program. The external data acquired are usually converted from native format to either netCDF or HDF formats. The GEC collection contains global data derived from the Total Ozone Mapping Spectrometer (TOMS) instrument on the Earth Probe satellite, consisting of daily values of aerosol index, ozone and reflectivity remapped into a regular 1x1.25 deg grid. Data are available from July 25, 1996 - December 31, 2005, but have been updated or replaced as of September 2007. See the explanation on the ARM web site at http://www.arm.gov/xds/static/toms.stm and the information at the NASA/TOMS web site: http://toms.gsfc.nasa.gov/ (Registration required)

467

Operation of a high purity germanium crystal in liquid argon as a Compton suppressed radiation spectrometer  

E-Print Network (OSTI)

A high purity germanium crystal was operated in liquid argon as a Compton suppressed radiation spectrometer. Spectroscopic quality resolution of less than 1% of the full-width half maximum of full energy deposition peaks was demonstrated. The construction of the small apparatus used to obtain these results is reported. The design concept is to use the liquid argon bath to both cool the germanium crystal to operating temperatures and act as a scintillating veto. The scintillation light from the liquid argon can veto cosmic-rays, external primordial radiation, and gamma radiation that does not fully deposit within the germanium crystal. This technique was investigated for its potential impact on ultra-low background gamma-ray spectroscopy. This work is based on a concept initially developed for future germanium-based neutrinoless double-beta decay experiments.

John L. Orrell; Craig E. Aalseth; John F. Amsbaugh; Peter J. Doe; Todd W. Hossbach

2006-10-11T23:59:59.000Z

468

A Dual Channel X-ray Spectrometer for Fast Ignition Research  

SciTech Connect

A new Dual Channel Highly Ordered Pyrolytic Graphite (DC-HOPG) x-ray spectrometer was developed to study laser-generated electron beam transport. The instrument uses a pair of graphite crystals and has the advantage of simultaneously detecting self emission from low-Z materials in first diffraction order and high-Z materials in second order. The emissions from the target are detected using a pair of parallel imaging plates positioned in a such way that the noise from background is minimized and the mosaic focusing is achieved. Initial tests of the diagnostic on Titan laser (I {approx} 10{sup 20} W/cm{sup 2}, {tau} = 0.7 ps) show excellent signal-to-noise ratio (SNR) > 1000 for the low energy channel and SNR > 400 for the high energy channel.

Akli, K U; Patel, P K; Van Maren, R; Stephens, R B; Key, M H; Higginson, D P; Westover, B; Chen, C D; Mackinnon, A J; Bartal, T; Beg, F N; Chawla, S; Fedosejevs, R; Freeman, R R; Hey, D S; Kemp, G E; LePape, S; Link, A; Ma, T; MacPhee, A G; McLean, H S; Ping, Y; Tsui, Y Y; Van Woerkom, L D; Wei, M S; Yabuuchi, T

2010-04-19T23:59:59.000Z

469

A versatile medium-resolution x-ray emission spectrometer for diamond anvil cell applications  

SciTech Connect

We present design and performance details for a polycapillary-coupled x-ray spectrometer that provides very high collection efficiency at a moderate energy resolution suitable for many studies of nonresonant x-ray emission spectroscopy, especially for samples of heavy elements under high pressures. Using a single Bragg analyzer operating close to backscattering geometry so as to minimize the effect of the weak divergence of the quasicollimated exit beam from the polycapillary optic, this instrument can maintain a typical energy resolution of 5 eV over photon energies from 5 keV to 10 keV. We find dramatically improved count rates as compared to a traditional higher-resolution instrument based on a single spherically bent crystal analyzer.

Mortensen, D. R.; Seidler, G. T. [Physics Department, University of Washington, Seattle, Washington 98195-1560 (United States)] [Physics Department, University of Washington, Seattle, Washington 98195-1560 (United States); Bradley, J. A.; Lipp, M. J.; Evans, W. J. [Condensed Matter and Materials Division, Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)] [Condensed Matter and Materials Division, Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Chow, P.; Xiao, Y.-M.; Boman, G. [HPCAT, Carnegie Institution of Washington, Argonne, Illinois 60439 (United States)] [HPCAT, Carnegie Institution of Washington, Argonne, Illinois 60439 (United States); Bowden, M. E. [Pacific Northwest National Laboratory, Richland, Washington 99354 (United States)] [Pacific Northwest National Laboratory, Richland, Washington 99354 (United States)

2013-08-15T23:59:59.000Z

470

X-ray imaging crystal spectrometer for extended X-ray sources  

DOE Patents (OSTI)

Spherically or toroidally curved, double focusing crystals are used in a spectrometer for X-ray diagnostics of an extended X-ray source such as a hot plasma produced in a tokomak fusion experiment to provide spatially and temporally resolved data on plasma parameters using the imaging properties for Bragg angles near 45. For a Bragg angle of 45.degree., the spherical crystal focuses a bundle of near parallel X-rays (the cross section of which is determined by the cross section of the crystal) from the plasma to a point on a detector, with parallel rays inclined to the main plain of diffraction focused to different points on the detector. Thus, it is possible to radially image the plasma X-ray emission in different wavelengths simultaneously with a single crystal.

Bitter, Manfred L. (Princeton, NJ); Fraenkel, Ben (Jerusalem, IL); Gorman, James L. (Bordentown, NJ); Hill, Kenneth W. (Lawrenceville, NJ); Roquemore, A. Lane (Cranbury, NJ); Stodiek, Wolfgang (Princeton, NJ); von Goeler, Schweickhard E. (Princeton, NJ)

2001-01-01T23:59:59.000Z

471

The X-Ray Microcalorimeter Spectrometer for the International X-Ray Observatory  

SciTech Connect

The International X-Ray Observatory (IXO) is under formulation by NASA, ESA and JAXA for deployment in 2022. IXO emerged over the last 18 months as the NASA Constellation-X and ESA/JAXA X-Ray Evolving Universe Spectrometer (XEUS) missions were combined. The driving performance requirements for the X-Ray Microcalorimeter Spectrometer (XMS) are a spectral resolution of 2.5 eV over the central 2'x2' in the 0.3-7.0 keV band, and 10 eV to the edge of the 5'x5' field of view (FOV). The XMS is now based on a microcalorimeter array of Transition-Edge Sensor (TES) thermometers with Au/Bi absorbers and a SQUID MUX readout. One of the concepts studied as part of the mission formulation has a core 40x40 array corresponding to a 2'x2' FOV with 3'' pixels surrounded by an outer, annular 52x52 array of 6'' pixels that extends the field of view to 5.4'x5.4' with better than 10 eV resolution. There are several options for implementing the readout and cooling system of the XMS under study in the US, Europe and Japan. The ADR system will have from two to five stages depending on the performance of the cryocooler. Mechanical coolers with sufficient cooling power at 4K are available now, and {approx}2K coolers are under development. In this paper we give an overview of the XMS instrument, and some of the tradeoffs to be addressed for this observatory instrument.

Kelley, R. L.; Bandler, S. R.; Kilbourne, C. A.; Porter, F. S.; Shirron, P.; Smith, S. J.; Whitehouse, P. [NASA/Goddard Space Flight Center, Greenbelt, MD (United States); Doriese, W. B.; Irwin, K. [National Institute of Standards and Technology, Boulder, CO (United States); Ezoe, Y.; Ishisaki, Y.; Ohashi, T. [Tokyo Metropolitan University, Hachioji, Tokyo (Japan); Fujimoto, R.; Sato, K. [Faculty of Mathematics and Physics, Kanazawa University, Kanazawa (Japan); Gottardi, L.; Hartog, R. den; Herder, J.-W. den; Hoevers, H.; Korte, P. de; Kuur, J. van der [SRON Netherlands Institute for Space Research, Utrecht (Netherlands)] (and others)

2009-12-16T23:59:59.000Z

472

Total Absorption Gamma-ray Spectrometer (TAGS) Intensity Distributions from INL's Gamma-Ray Spectrometry Center  

DOE Data Explorer (OSTI)

A 252Cf fission-product source and the INL on-line isotope separator were used to supply isotope-separated fission-product nuclides to a total absorption -ray spectrometer. This spectrometer consisted of a large (25.4-cm diameter x 30.5-cm long) NaI(Tl) detector with a 20.3-cm deep axial well in which is placed a 300-mm2 x 1.0-mm Si detector. The spectra from the NaI(Tl) detector are collected both in the singles mode and in coincidence with the B-events detected in the Si detector. Ideally, this detector would sum all the energy of the B- rays in each cascade following the population of daughter level by B- decay, so that the event could be directly associated with a particular daughter level. However, there are losses of energy from attenuation of the rays before they reach the detector, transmission of rays through the detector, escape of secondary photons from Compton scattering, escape of rays through the detector well, internal conversion, etc., and the measured spectra are thus more complicated than the ideal case and the analysis is more complex. Analysis methods have been developed to simulate all of these processes and thus provide a direct measure of the B- intensity distribution as a function of the excitation energy in the daughter nucleus. These data yield more accurate information on the B- distribution than conventional decay-scheme studies for complex decay schemes with large decay energies, because in the latter there are generally many unobserved and observed but unplaced rays. The TAGS data have been analyzed and published [R. E. Greenwood et al., Nucl Instr. and metho. A390(1997)] for 40 fission product-nuclides to determine the B- intensity distributions. [Copied from the TAGS page at http://www.inl.gov/gammaray/spectrometry/tags.shtml]. Those values are listed on this page for quick reference.

Greenwood, R.E.

473

The Neutron-Hydrogen Mass Difference and the Neutron Mass  

Science Journals Connector (OSTI)

Data in the literature leading to the neutron-hydrogen mass difference and the neutron mass are summarized. The disintegration energy of the deuteron together with the HH-D mass spectroscopic doublet separation apparently yields the best value of n-H=0.755±0.016 Mev and a neutron mass of 1.008,941±0.000,02 mass units. Other transmutation-radioactivity cycles check this value. Several inconsistencies in these data and their possible explanation are pointed out. Experiments of interest for improvement in accuracy and reliability of these values are noted.

W. E. Stephens

1947-01-01T23:59:59.000Z

474

Primordial black hole minimum mass  

SciTech Connect

In this paper we revisit thermodynamic constraints on primordial black hole (PBH) formation in the early universe. Under the assumption that PBH mass is equal to the cosmological horizon mass, one can use the 2nd Law of Thermodynamics to put a lower limit on the PBH mass. In models of PBH formation, however, PBHs are created at some fraction of the horizon mass. We show that this thermodynamic constraint still holds for subhorizon PBH formation.

Chisholm, James R. [Institute for Fundamental Theory, University of Florida, Gainesville, Florida 32611-8440 (United States)

2006-08-15T23:59:59.000Z

475

Lunar X-ray fluorescence observations by the Chandrayaan-1 X-ray Spectrometer (C1XS): Results from the nearside southern highlands  

E-Print Network (OSTI)

Lunar X-ray fluorescence observations by the Chandrayaan-1 X-ray Spectrometer (C1XS): Results from Spectroscopy a b s t r a c t The Chandrayaan-1 X-ray Spectrometer (C1XS) flown on-board the first Indian lunar mission Chan- drayaan-1, measured X-ray fluorescence spectra during several episodes of solar flares

Wieczorek, Mark

476

Mass Transport within Soils  

SciTech Connect

Contaminants in soil can impact human health and the environment through a complex web of interactions. Soils exist where the atmosphere, hydrosphere, geosphere, and biosphere converge. Soil is the thin outer zone of the earth's crust that supports rooted plants and is the product of climate and living organisms acting on rock. A true soil is a mixture of air, water, mineral, and organic components. The relative proportions of these components determine the value of the soil for agricultural and for other human uses. These proportions also determine, to a large extent, how a substance added to soil is transported and/or transformed within the soil (Spositio, 2004). In mass-balance models, soil compartments play a major role, functioning both as reservoirs and as the principal media for transport among air, vegetation, surface water, deeper soil, and ground water (Mackay, 2001). Quantifying the mass transport of chemicals within soil and between soil and atmosphere is important for understanding the role soil plays in controlling fate, transport, and exposure to multimedia pollutants. Soils are characteristically heterogeneous. A trench dug into soil typically reveals several horizontal layers having different colors and textures. As illustrated in Figure 1, these multiple layers are often divided into three major horizons: (1) the A horizon, which encompasses the root zone and contains a high concentration of organic matter; (2) the B horizon, which is unsaturated, lies below the roots of most plants, and contains a much lower organic carbon content; and (3) the C horizon, which is the unsaturated zone of weathered parent rock consisting of bedrock, alluvial material, glacial material, and/or soil of an earlier geological period. Below these three horizons lies the saturated zone - a zone that encompasses the area below ground surface in which all interconnected openings within the geologic media are completely filled with water. Similarly to the unsaturated zone with three major horizons, the saturated zone can be further divided into other zones based on hydraulic and geologic conditions. Wetland soils are a special and important class in which near-saturation conditions exist most of the time. When a contaminant is added to or formed in a soil column, there are several mechanisms by which it can be dispersed, transported out of the soil column to other parts of the environment, destroyed, or transformed into some other species. Thus, to evaluate or manage any contaminant introduced to the soil column, one must determine whether and how that substance will (1) remain or accumulate within the soil column, (2) be transported by dispersion or advection within the soil column, (3) be physically, chemically, or biologically transformed within the soil (i.e., by hydrolysis, oxidation, etc.), or (4) be transported out of the soil column to another part of the environment through a cross-media transfer (i.e., volatilization, runoff, ground water infiltration, etc.). These competing processes impact the fate of physical, chemical, or biological contaminants found in soils. In order to capture these mechanisms in mass transfer models, we must develop mass-transfer coefficients (MTCs) specific to soil layers. That is the goal of this chapter. The reader is referred to other chapters in this Handbook that address related transport processes, namely Chapter 13 on bioturbation, Chapter 15 on transport in near-surface geological formations, and Chapter 17 on soil resuspention. This chapter addresses the following issues: the nature of soil pollution, composition of soil, transport processes and transport parameters in soil, transformation processes in soil, mass-balance models, and MTCs in soils. We show that to address vertical heterogeneity in soils in is necessary to define a characteristic scaling depth and use this to establish process-based expressions for soil MTCs. The scaling depth in soil and the corresponding MTCs depend strongly on (1) the composition of the soil and physical state of the soil, (2) the chemical and physic

McKone, Thomas E.

2009-03-01T23:59:59.000Z

477

Mid-Infrared Spectrometer Using Opto-Nanofluidic Slot-Waveguide for Label-Free On-Chip Chemical Sensing  

E-Print Network (OSTI)

, provides a unique platform for chemical detection. KEYWORDS: Midinfrared, opto-nanofluidics, onMid-Infrared Spectrometer Using Opto-Nanofluidic Slot-Waveguide for Label-Free On-Chip Chemical Avenue, Cambridge, Massachusetts 02139, United States Department of Chemistry and Chemical Biology

Heller, Eric

478

Mid-Infrared Continuous Wave Cavity Ringdown Spectrometer for Acquisition of the High-Resolution Spectrum of C60  

E-Print Network (OSTI)

cascade laser (QCL) provided by collaborators at Princeton [1] Kroto et al. Nature 318, 162 (1985). [2 have been fit to an effective Hamiltonian using Pgopher[6] Simulations indicate cold gas (~7 K) from supersonic jet as well as warm background gas Spectrometer has a sensitivity of ~5Ã?10-8 cm-1 Hz-1

McCall, Benjamin J.

479

High energy resolution five-crystal spectrometer for high quality fluorescence and absorption measurements on an X-ray Absorption  

E-Print Network (OSTI)

-ray photons from a large solid angle with five spherically bent crystals. It will cover a large energy rangeHigh energy resolution five-crystal spectrometer for high quality fluorescence and absorption however presents some limitations related to the limited energy resolution and saturation. Crystal

Paris-Sud XI, Université de

480

High explosives vapor detection by atmospheric sampling glow discharge ionization/tandem mass spectrometry  

SciTech Connect

The combination of atmospheric sampling glow discharge ionization with tandem mass spectrometry for the detection of traces of high explosives is described. Particular emphasis is placed on use of the quadrupole ion trap as the type of tandem mass spectrometer. Atmospheric sampling glow discharge provides a simple, rugged, and efficient means for anion formation while the quadrupole ion trap provides for efficient tandem mass spectrometry. Mass selective ion accumulation and non-specific ion activation methods can be used to overcome deleterious effects arising from ion/ion interactions. Such interactions constitute the major potential technical barrier to the use of the ion trap for real-time monitoring of targeted compounds in uncontrolled and highly variable matrices. Tailored waveforms can be used to effect both mass selective ion accumulation and ion activation. Concatenated tailored waveforms allow for both functions in a single experiment thereby providing the capability for monitoring several targeted species simultaneously. The combination of atmospheric sampling glow discharge ionization with a state-of-the-art analytical quadrupole ion trap is a highly sensitive and specific detector for traces of high explosives. The combination is also small and inexpensive relative to virtually any other form of tandem mass spectrometry. The science and technology underlying the glow discharge/ion trap combination is sufficiently mature to form the basis for an engineering effort to make the detector portable. 85 refs.

McLuckey, S.A.; Goeringer, D.E.; Asano, K.G. [Oak Ridge National Lab., TN (United States). Chemical and Analytical Sciences Div.

1996-02-01T23:59:59.000Z

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481

Mass of Cu-57  

E-Print Network (OSTI)

the extension of these systematics to higher Z. If the 3 =57 nuclei have true single particle low-lying states, the Cu beta decay rates determine the 2p3/2 +2p3/2 and 2p 3/2 ~2p ~ &2 Gamow-Teller matrix elements, providing a measure of Gamow... with A ~ 56 (Ref. 3) and possibly for the time evolu- tion of cosmic x-ray bursts. Cu has been observed in the Cu~ Ni+e++v, and Ni( Li, He} Cu reactions. The former study found the Cu mass excess to be ?47.34(13) MeV and deter- mined its beta decay...

Gagliardi, Carl A.; Semon, D. R.; Tribble, Robert E.; Vanausdeln, L. A.

1986-01-01T23:59:59.000Z