Sample records for mass spectrometer icp-ms

  1. {sup 99}Tc bioassay by inductively coupled plasma mass spectrometry (ICP-MS)

    SciTech Connect (OSTI)

    Lewis, L.A.

    1998-05-01T23:59:59.000Z

    A means of analyzing {sup 99}Tc in urine by inductively coupled plasma mass spectrometry (ICP-MS) has been developed. Historically, {sup 99}Tc analysis was based on the radiometric detection of the 293 keV E{sub Max} beta decay product by liquid scintillation or gas flow proportional counting. In a urine matrix, the analysis of{sup 99}Tc is plagued with many difficulties using conventional radiometric methods. Difficulties originate during chemical separation due to the volatile nature of Tc{sub 2}O{sub 7} or during radiation detection due to color or chemical quenching. A separation scheme for {sup 99}Tc detection by ICP-MS is given and is proven to be a sensitive and robust analytical alternative. A comparison of methods using radiometric and mass quantitation of {sup 99}Tc has been conducted in water, artificial urine, and real urine matrices at activity levels between 700 and 2,200 dpm/L. Liquid scintillation results based on an external standard quench correction and a quench curve correction method are compared to results obtained by ICP-MS. Each method produced accurate results, however the precision of the ICP-MS results is superior to that of liquid scintillation results. Limits of detection (LOD) for ICP-MS and liquid scintillation detection are 14.67 and 203.4 dpm/L, respectively, in a real urine matrix. In order to determine the basis for the increased precision of the ICP-MS results, the detection sensitivity for each method is derived and measured. The detection sensitivity for the {sup 99}Tc isotope by ICP-MS is 2.175 x 10{sup {minus}7} {+-} 8.990 x 10{sup {minus}9} and by liquid scintillation is 7.434 x 10{sup {minus}14} {+-} 7.461 x 10{sup {minus}15}. A difference by seven orders of magnitude between the two detection systems allows ICP-MS samples to be analyzed for a period of 15 s compared to 3,600 s by liquid scintillation counting with a lower LOD.

  2. THE NOTRE DAME INDUCTIVELY COUPLED PLASMA -MASS SPECTROMETRY (ICP-MS)

    E-Print Network [OSTI]

    the PQII STE ICP-MS, Electrothermal Vaporization, and Laser Ablation units The report supercedes STE, LaserProbe (tuned to 266 nm, but with 532 nm and 1046 nm capabilities), CETAC Ultrasonic

  3. Mass Spectrometer: Inductively Coupled Plasma (ICP-MS), High...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    will be deployed in conjunction with the Neptune and can be used with the supplementary laser ablation unit to provide elemental concentrations at extremely small ablation spot...

  4. Mass Spectrometer: Inductively Coupled Plasma (ICP-MS), Multi...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    scientific communities. In addition, EMSL has initiated the process to purchase a custom laser ablation unit with an image size of 1 micron that in combination with the Neptune...

  5. {sup 99}Tc bioassay: A direct comparison of liquid scintillation radiation detection and ICP-MS mass detection of the {sup 99}Tc isotope

    SciTech Connect (OSTI)

    Lewis, L.A. [Lockheed Martin Energy Systems, Inc., Oak Ridge, TN (United States). Analytical Services Organization; Schweitzer, G.K. [Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

    1998-12-31T23:59:59.000Z

    A means of analyzing {sup 99}Tc in urine by inductively coupled plasma mass spectrometry (ICP-MS) has been developed. Historically, {sup 99}Tc analysis was based on the radiometric detection of the 293 keV E{sub Max.} beta decay product by liquid scintillation or gas flow proportional counting. A separation scheme for {sup 99}Tc detection by ICP-MS is given and is proven to be a sensitive and robust analytical alternative. A comparison of methods using radiometric and mass quantitation of {sup 99}Tc has been conducted in water, artificial urine, and real urine matrices at activity levels between 700 and 2,200 dpm/L. Liquid scintillation results based on an external standard manual quench correction and an automatic quench curve correction method are compared with results obtained by ICP-MS. Each method produced accurate results; however, the precision of the ICP-MS results is superior to that of liquid scintillation results.

  6. ICP-MS Workshop

    SciTech Connect (OSTI)

    Carman, April J.; Eiden, Gregory C.

    2014-11-01T23:59:59.000Z

    This is a short document that explains the materials that will be transmitted to LLNL and DNN HQ regarding the ICP-MS Workshop held at PNNL June 17-19th. The goal of the information is to pass on to LLNL information regarding the planning and preparations for the Workshop at PNNL in preparation of the SIMS workshop at LLNL.

  7. Improving Alpha Spectrometry Energy Resolution by Ion Implantation with ICP-MS

    SciTech Connect (OSTI)

    Dion, Michael P.; Liezers, Martin; Farmer, Orville T.; Miller, Brian W.; Morley, Shannon M.; Barinaga, Charles J.; Eiden, Gregory C.

    2015-01-01T23:59:59.000Z

    We report results of a novel technique using an Inductively Coupled Plasma Mass Spectrometer (ICP-MS) as a method of source preparation for alpha spectrometry. This method produced thin, contaminant free 241Am samples which yielded extraordinary energy resolution which appear to be at the lower limit of the detection technology used in this research.

  8. Standard test method for the determination of impurities in plutonium metal: acid digestion and inductively coupled plasma-mass spectroscopy (ICP-MS) analysis

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2006-01-01T23:59:59.000Z

    1.1 This Test Method covers the determination of 58 trace elements in plutonium (Pu) metal. The Pu sample is dissolved in acid, and the concentration of the trace impurities are determined by Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS). 1.2 This Test Method is specific for the determination of trace impurities in Pu metal. It may be applied to other types of Pu materials, such as Pu oxides, if the samples are dissolved and oxidized to the Pu(IV) state. However, it is the responsibility of the user to evaluate the performance of other matrices. 1.3 This standard does not purport to address all of the safety concerns associated with its use. It is the responsibility of the user of this method to establish appropriate safety and health practices and to determine the applicability of regulatory limitations prior to use of this standard.

  9. Measurement of elemental speciation by liquid chromatography -- inductively coupled plasma mass spectrometry (LC-ICP-MS) with the direct injection nebulizer (DIN)

    SciTech Connect (OSTI)

    Shum, S.

    1993-05-01T23:59:59.000Z

    This thesis is divided into 4 parts: elemental speciation, speciation of mercury and lead compounds by microbore column LC-ICP-MS with direct injection nebulization, spatially resolved measurements of size and velocity distributions of aerosol droplets from a direct injection nebulizer, and elemental speciation by anion exchange and size exclusion chromatography with detection by ICP-MS with direct injection nebulization. Tabs, figs, refs.

  10. Use of Electrodeposition for Sample Preparation and Rejection Rate Prediction for Assay of Electroformed Ultra High Purity Copper for 232Th and 238U Prior to Inductively Coupled Plasma Mass Spectrometry (ICP/MS)

    SciTech Connect (OSTI)

    Hoppe, Eric W.; Aalseth, Craig E.; Brodzinski, Ronald L.; Day, Anthony R.; Farmer, Orville T.; Hossbach, Todd W.; McIntyre, Justin I.; Miley, Harry S.; Mintzer, Esther E.; Seifert, Allen; Smart, John E.; Warren, Glen A.

    2008-07-01T23:59:59.000Z

    The search for neutrinoless double beta decay in 76Ge has driven the need for ultra-low background Ge detectors shielded by electroformed copper of ultra-high radiopurity (<0.1µBq/kg). Although electrodeposition processes are almost sophisticated enough to produce copper of this purity, to date there are no methods sensitive enough to assay it. Inductively-coupled plasma mass spectrometry (ICP/MS) can detect thorium and uranium at femtogram levels, but in the past, this assay has been hindered by high copper concentrations in the sample. Electrodeposition of copper samples removes copper from the solution while selectively concentrating thorium and uranium contaminants to be assayed by ICP/MS. Spiking 232Th and 238U into the plating bath simulates low purity copper and allows for the calculation of the electrochemical rejection rate of thorium and uranium in the electroplating system. This rejection value will help to model plating bath chemistry.

  11. Laser Ablation-ICP-MS Analysis of Dissected Tissue: A

    E-Print Network [OSTI]

    Hopkins, William A.

    Laser Ablation-ICP-MS Analysis of Dissected Tissue: A Conservation-Minded Approach to Assessing the animal. In this paper, we report on the application of laser ablation-ICP-MS (LA- ICP-MS) for sampling

  12. Evaluation of pneumatic nebulization and ns-laser ablation ICP-MS for bulk elemental analysis and 2-dimensional

    E-Print Network [OSTI]

    Claeys, Philippe

    Evaluation of pneumatic nebulization and ns-laser ablation ICP-MS for bulk elemental analysis and 2 nebulization and ns-laser ablation ICP-MS for bulk elemental analysis and 2-dimensional element mapping of iron 20XX DOI: 10.1039/b000000x The capabilities and limitations of nanosecond laser ablation ICP ­ mass

  13. Sediment profiles of less commonly determined elements measured by Laser Ablation ICP-MS

    E-Print Network [OSTI]

    Mcdonough, William F.

    Sediment profiles of less commonly determined elements measured by Laser Ablation ICP on a short list of high-abundance trace elements. Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry of this investigation is to harness the analytical power of Laser Ablation ICP-MS to explore the behavior of a large

  14. MICROANALYSIS OF SIDEROPHILE ELEMENTS IN FREMDLINGE USING LASER ABLATION ICP-MS. A. J. Campbell

    E-Print Network [OSTI]

    Grossman, Lawrence

    MICROANALYSIS OF SIDEROPHILE ELEMENTS IN FREMDLINGE USING LASER ABLATION ICP-MS. A. J. Campbell 1@midway.uchicago.edu). Introduction: Laser ablation ICP mass spectrome- try has been used to measure distributions of the highly vein in Allende (CV3-oxidized). Experimental: The laser ablation system utilized a CETAC LSX-200 laser

  15. Standard practice for the determination of 237Np, 232Th, 235U and 238U in urine by inductively coupled plasma-Mass spectrometry (ICP-MS) and gamma ray spectrometry.

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2005-01-01T23:59:59.000Z

    1.1 This practice covers the separation and preconcentration of neptunium-237 (237Np), thorium-232 (232Th), uranium-235 (235U) and uranium-238 (238U) from urine followed by quantitation using ICP-MS. 1.2 This practice can be used to support routine bioassay programs. The minimum detectable concentrations (MDC) for this method, taking the preconcentration factor into account, are approximately 1E-2Bq for 237Np (0.38ng), 2E-6Bq for 232Th (0.50ng), 4E-5Bq for 235U (0.50ng) and 6E-6Bq for 238U (0.48ng). 1.3 This standard does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

  16. Quantitative 3-D Elemental Mapping by LA-ICP-MS of a Basaltic Clast from the Hanford 300 Area, Washington, USA

    E-Print Network [OSTI]

    Hu, Qinhong "Max"

    : Laser ablation with inductively coupled plasma- mass spectrometry (LA-ICP-MS) was used to measure (XAS2,8 ), and by cryogenic laser-induced fluorescence spectroscopy (CLIFS7 ). Both XAS and CLIFS

  17. Evaluation of ultra-low background materials for uranium and thorium using ICP-MS

    SciTech Connect (OSTI)

    Hoppe, E. W.; Overman, N. R.; LaFerriere, B. D. [Pacific Northwest National Laboratory, Richland, WA 99354 (United States)] [Pacific Northwest National Laboratory, Richland, WA 99354 (United States)

    2013-08-08T23:59:59.000Z

    An increasing number of physics experiments require low background materials for their construction. The presence of Uranium and Thorium and their progeny in these materials present a variety of unwanted background sources for these experiments. The sensitivity of the experiments continues to drive the necessary levels of detection ever lower as well. This requirement for greater sensitivity has rendered direct radioassay impractical in many cases requiring large quantities of material, frequently many kilograms, and prolonged counting times, often months. Other assay techniques have been employed such as Neutron Activation Analysis but this requires access to expensive facilities and instrumentation and can be further complicated and delayed by the formation of unwanted radionuclides. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) is a useful tool and recent advancements have increased the sensitivity particularly in the elemental high mass range of U and Th. Unlike direct radioassay, ICP-MS is a destructive technique since it requires the sample to be in liquid form which is aspirated into a high temperature plasma. But it benefits in that it usually requires a very small sample, typically about a gram. This paper discusses how a variety of low background materials such as copper, polymers, and fused silica are made amenable to ICP-MS assay and how the arduous task of maintaining low backgrounds of U and Th is achieved.

  18. Evaluation of Ultra-Low Background Materials for Uranium and Thorium Using ICP-MS

    SciTech Connect (OSTI)

    Hoppe, Eric W.; Overman, Nicole R.; LaFerriere, Brian D.

    2013-08-08T23:59:59.000Z

    An increasing number of physics experiments require low background materials for their construction. The presence of Uranium and Thorium and their progeny in these materials present a variety of unwanted background sources for these experiments. The sensitivity of the experiments continues to drive the necessary levels of detection ever lower as well. This requirement for greater sensitivity has rendered direct radioassay impractical in many cases requiring large quantities of material, frequently many kilograms, and prolonged counting times, often months. Other assay techniques have been employed such as Neutron Activation Analysis but this requires access to expensive facilities and instrumentation and can be further complicated and delayed by the formation of unwanted radionuclides. Inductively Coupled Plasma Mass Spectrometry (ICP-MS) is a useful tool and recent advancements have increased the sensitivity particularly in the elemental high mass range of U and Th. Unlike direct radioassay, ICP-MS is a destructive technique since it requires the sample to be in liquid form which is aspirated into a high temperature plasma. But it benefits in that it usually requires a very small sample, typically about a gram. Here we will discuss how a variety of low background materials such as copper, polymers, and fused silica are made amenable to ICP-MS assay and how the arduous task of maintaining low backgrounds of U and Th is achieved.

  19. Radionuclide content of simulated and fully radioactive SRLLL waste gl;asses: comparison of results from ICP-MS, gamma spectrometry and alpha spectrometry

    SciTech Connect (OSTI)

    Wolf, S.F.; Bates, J.K.

    1995-12-31T23:59:59.000Z

    We have measured the transuranic content of two transuranic=doped, simulated waste glasses, using inductively coupled plasma-mass spectrometry (ICP-MS), {gamma}-spectrometry, and {alpha}-spectrometry. Average concentrations measured by each technique were within {+-} 10% of the as-doped concentrations. We also report the transuranic content of three fully radioactive SRL waste glasses that were determined using {gamma}- and {alpha}-spectrometry measurements to deconvolute isobaric interferences present in the ICP-MS analyses.

  20. Uncertainty Measurement for Trace Element Analysis of Uranium and Plutonium Samples by Inductively Coupled Plasma-Atomic Emission Spectrometry (ICP-AES) and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS)

    SciTech Connect (OSTI)

    Gallimore, David L. [Los Alamos National Laboratory

    2012-06-13T23:59:59.000Z

    The measurement uncertainty estimatino associated with trace element analysis of impurities in U and Pu was evaluated using the Guide to the Expression of Uncertainty Measurement (GUM). I this evalution the uncertainty sources were identified and standard uncertainties for the components were categorized as either Type A or B. The combined standard uncertainty was calculated and a coverage factor k = 2 was applied to obtain the expanded uncertainty, U. The ICP-AES and ICP-MS methods used were deveoped for the multi-element analysis of U and Pu samples. A typical analytical run consists of standards, process blanks, samples, matrix spiked samples, post digestion spiked samples and independent calibration verification standards. The uncertainty estimation was performed on U and Pu samples that have been analyzed previously as part of the U and Pu Sample Exchange Programs. Control chart results and data from the U and Pu metal exchange programs were combined with the GUM into a concentration dependent estimate of the expanded uncertainty. Comparison of trace element uncertainties obtained using this model was compared to those obtained for trace element results as part of the Exchange programs. This process was completed for all trace elements that were determined to be above the detection limit for the U and Pu samples.

  1. Ultrafast laser ablation ICP-MS: role of spot size, laser fluence, and repetition rate in signal intensity

    E-Print Network [OSTI]

    Harilal, S. S.

    Ultrafast laser ablation ICP-MS: role of spot size, laser fluence, and repetition rate in signal,a Richard E. Russob and Ahmed Hassaneina Ultrafast laser ablation inductively coupled plasma mass system. Though ultrafast laser ablation sample introduction provides better accuracy and precision

  2. Boston University User Fee Structure for ICP-ES, ICP-MS and Laser Labs

    E-Print Network [OSTI]

    Hutyra, Lucy R.

    Cost per sample by laser ablation includes three spots on a sample plus an additional three spotsBoston University User Fee Structure for ICP-ES, ICP-MS and Laser Labs The Department of Earth come to BU and digest their samples in our labs with sufficient training. Laser-ICP-MS cost per sample

  3. Ultra High Mass Range Mass Spectrometer System

    DOE Patents [OSTI]

    Reilly, Peter T. A. [Knoxville, TN

    2005-12-06T23:59:59.000Z

    Applicant's present invention comprises mass spectrometer systems that operate in a mass range from 1 to 10.sup.16 DA. The mass spectrometer system comprising an inlet system comprising an aerodynamic lens system, a reverse jet being a gas flux generated in an annulus moving in a reverse direction and a multipole ion guide; a digital ion trap; and a thermal vaporization/ionization detector system. Applicant's present invention further comprises a quadrupole mass spectrometer system comprising an inlet system having a quadrupole mass filter and a thermal vaporization/ionization detector system. Applicant's present invention further comprises an inlet system for use with a mass spectrometer system, a method for slowing energetic particles using an inlet system. Applicant's present invention also comprises a detector device and a method for detecting high mass charged particles.

  4. Mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, Daniel D. (Livermore, CA); Keville, Robert F. (Valley Springs, CA)

    1995-01-01T23:59:59.000Z

    An ion trap which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10.sup.9 and commercial mass spectrometers requiring 10.sup.4 ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products.

  5. Mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, D.D.; Keville, R.F.

    1995-09-19T23:59:59.000Z

    An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

  6. EMSL - Mass Spectrometer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MS) with high mass resolution (m&61636;m100,000). Solvent mixtures of acetonitrilewater and acetonitriletoluene were used to extract and ionize polar and non-polar...

  7. Glass particles produced by laser ablation for ICP-MS measurements

    E-Print Network [OSTI]

    Gonzalez, J.; Liu, C.; Wen, S.; Mao, X.; Russo, R.E.

    2008-01-01T23:59:59.000Z

    Glass particles produced by laser ablation for ICP-MS266nm) was used to generate glass particles from two sets ofWhen the current data on glass were compared with the metal

  8. Imaging mass spectrometer with mass tags

    DOE Patents [OSTI]

    Felton, James S.; Wu, Kuang Jen; Knize, Mark G.; Kulp, Kristen S.; Gray, Joe W.

    2010-06-01T23:59:59.000Z

    A method of analyzing biological material by exposing the biological material to a recognition element, that is coupled to a mass tag element, directing an ion beam of a mass spectrometer to the biological material, interrogating at least one region of interest area from the biological material and producing data, and distributing the data in plots.

  9. Imaging mass spectrometer with mass tags

    DOE Patents [OSTI]

    Felton, James S.; Wu, Kuang Jen J.; Knize, Mark G.; Kulp, Kristen S.; Gray, Joe W.

    2013-01-29T23:59:59.000Z

    A method of analyzing biological material by exposing the biological material to a recognition element, that is coupled to a mass tag element, directing an ion beam of a mass spectrometer to the biological material, interrogating at least one region of interest area from the biological material and producing data, and distributing the data in plots.

  10. Time of flight mass spectrometer

    DOE Patents [OSTI]

    Ulbricht, Jr., William H. (Arvada, CO)

    1984-01-01T23:59:59.000Z

    A time-of-flight mass spectrometer is described in which ions are desorbed from a sample by nuclear fission fragments, such that desorption occurs at the surface of the sample impinged upon by the fission fragments. This configuration allows for the sample to be of any thickness, and eliminates the need for complicated sample preparation.

  11. Advanced Mass Spectrometers for Hydrogen Isotope Analyses

    SciTech Connect (OSTI)

    Chastagner, P.

    2001-08-01T23:59:59.000Z

    This report is a summary of the results of a joint Savannah River Laboratory (SRL) - Savannah River Plant (SRP) ''Hydrogen Isotope Mass Spectrometer Evaluation Program''. The program was undertaken to evaluate two prototype hydrogen isotope mass spectrometers and obtain sufficient data to permit SRP personnel to specify the mass spectrometers to replace obsolete instruments.

  12. Automated mass spectrometer grows up

    SciTech Connect (OSTI)

    McInteer, B.B.; Montoya, J.G.; Stark, E.E.

    1984-01-01T23:59:59.000Z

    In 1980 we reported the development of an automated mass spectrometer for large scale batches of samples enriched in nitrogen-15 as ammonium salts. Since that time significant technical progress has been made in the instrument. Perhaps more significantly, administrative and institutional changes have permitted the entire effort to be transferred to the private sector from its original base at the Los Alamos National Laboratory. This has ensured the continuance of a needed service to the international scientific community as revealed by a development project at a national laboratory, and is an excellent example of beneficial technology transfer to private industry.

  13. Elemental fractionation during LA-ICP-MS analysis of silicate glasses: implications for matrix-independent standardization

    E-Print Network [OSTI]

    Weston, Ken

    Elemental fractionation during LA-ICP-MS analysis of silicate glasses: implications for matrix-element solution and from the laser ablation of a range of silicate reference materials (SRM 61X series, MPI-independent standardization of LA- ICP-MS analysis of non-transparent silicates and ceramics, then, is an accurate and viable

  14. Lee, C-T A Laser Ablation Data Reduction 2006 LASER ABLATION ICP-MS: DATA

    E-Print Network [OSTI]

    Lee, Cin-Ty Aeolus

    Lee, C-T A Laser Ablation Data Reduction 2006 1 LASER ABLATION ICP-MS: DATA REDUCTION Cin-Ty A. Lee 24 September 2006 Analysis and calculation of concentrations Laser ablation analyses are done in time by turning on the laser and ablating the sample, generating a time-dependent signal (Fig. 1). Measurements

  15. Surface Cleaning Techniques: Ultra-Trace ICP-MS Sample Preparation and Assay of HDPE

    SciTech Connect (OSTI)

    Overman, Nicole R.; Hoppe, Eric W.; Addleman, Raymond S.

    2013-06-01T23:59:59.000Z

    The world’s most sensitive radiation detection and assay systems depend upon ultra-low background (ULB) materials to reduce unwanted radiological backgrounds. Herein, we evaluate methods to clean HDPE, a material of interest to ULB systems and the means to provide rapid assay of surface and bulk contamination. ULB level material and ultra-trace level detection of actinide elements is difficult to attain, due to the introduction of contamination from sample preparation equipment such as pipette tips, sample vials, forceps, etc. and airborne particulate. To date, literature available on the cleaning of such polymeric materials and equipment for ULB applications and ultra-trace analyses is limited. For these reasons, a study has been performed to identify an effective way to remove surface contamination from polymers in an effort to provide improved instrumental detection limits. Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) was utilized to assess the effectiveness of a variety of leachate solutions for removal of inorganic uranium and thorium surface contamination from polymers, specifically high density polyethylene (HDPE). HDPE leaching procedures were tested to optimize contaminant removal of thorium and uranium. Calibration curves for thorium and uranium ranged from 15 ppq (fg/mL) to 1 ppt (pg/mL). Detection limits were calculated at 6 ppq for uranium and 7 ppq for thorium. Results showed the most effective leaching reagent to be clean 6 M nitric acid for 72 hour exposures. Contamination levels for uranium and thorium found in the leachate solutions were significant for ultralow level radiation detection applications.

  16. Solid-phase chelation for the determination of trace elements by ICP-MS

    SciTech Connect (OSTI)

    Taylor, D.B.; Kingston, H.M.; Nogay, D. [Duquesne Univ., Pittsburgh, PA (United States)

    1995-12-31T23:59:59.000Z

    A low pressure method for the concentration of analytes and elimination of matrix elements prior to determination by ICP-MS is described. The method reduces the interferences caused by high concentrations of matrix elements in samples and biases caused by differences between samples and standards by delivering the analytes to the ICP-MS in a consistent nitric acid matrix. The method uses a commercially available low pressure sample manipulation system (PrepLab, Fisons) to perform Solid Phase Chelation (SPC) on an iminodiacetate column. The effectiveness of the method is demonstrated for the determination of Cd, Co, Cu, Mn, Ni, Pb, U, and Zn in the certified reference materials CASS-2, near shore seawater, NASS-4, open ocean seawater, and 1643b, trace elements in water. The detection limits for 10 mL samples ranged from 0.4 ng L{sup -1} for Co to 5.6 ng L{sup -1} for Ni and Zn.

  17. Gas sampling system for a mass spectrometer

    DOE Patents [OSTI]

    2003-12-30T23:59:59.000Z

    The present invention relates generally to a gas sampling system, and specifically to a gas sampling system for transporting a hazardous process gas to a remotely located mass spectrometer. The gas sampling system includes a capillary tube having a predetermined capillary length and capillary diameter in communication with the supply of process gas and the mass spectrometer, a flexible tube surrounding and coaxial with the capillary tube intermediate the supply of process gas and the mass spectrometer, a heat transfer tube surrounding and coaxial with the capillary tube, and a heating device in communication the heat transfer tube for substantially preventing condensation of the process gas within the capillary tube.

  18. Matrix effects in inductively coupled plasma mass spectrometry

    SciTech Connect (OSTI)

    Chen, Xiaoshan

    1995-07-07T23:59:59.000Z

    The inductively coupled plasma is an electrodeless discharge in a gas (usually Ar) at atmospheric pressure. Radio frequency energy generated by a RF power source is inductively coupled to the plasma gas through a water cooled load coil. In ICP-MS the {open_quotes}Fassel{close_quotes} TAX quartz torch commonly used in emission is mounted horizontally. The sample aerosol is introduced into the central flow, where the gas kinetic temperature is about 5000 K. The aerosol is vaporized, atomized, excited and ionized in the plasma, and the ions are subsequently extracted through two metal apertures (sampler and skimmer) into the mass spectrometer. In ICP-MS, the matrix effects, or non-spectroscopic interferences, can be defined as the type of interferences caused by dissolved concomitant salt ions in the solution. Matrix effects can be divided into two categories: (1) signal drift due to the deposition of solids on the sampling apertures; and/or (2) signal suppression or enhancement by the presence of the dissolved salts. The first category is now reasonably understood. The dissolved salts, especially refractory oxides, tend to deposit on the cool tip of the sampling cone. The clogging of the orifices reduces the ion flow into the ICP-MS, lowers the pressure in the first stage of ICP-MS, and enhances the level of metal oxide ions. Because the extent of the clogging increases with the time, the signal drifts down. Even at the very early stage of the development of ICP-MS, matrix effects had been observed. Houk et al. found out that the ICP-MS was not tolerant to solutions containing significant amounts of dissolved solids.

  19. Compact hydrogen/helium isotope mass spectrometer

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM); McComas, David J. (Los Alamos, NM); Scime, Earl E. (Morgantown, WV)

    1996-01-01T23:59:59.000Z

    The compact hydrogen and helium isotope mass spectrometer of the present invention combines low mass-resolution ion mass spectrometry and beam-foil interaction technology to unambiguously detect and quantify deuterium (D), tritium (T), hydrogen molecule (H.sub.2, HD, D.sub.2, HT, DT, and T.sub.2), .sup.3 He, and .sup.4 He concentrations and concentration variations. The spectrometer provides real-time, high sensitivity, and high accuracy measurements. Currently, no fieldable D or molecular speciation detectors exist. Furthermore, the present spectrometer has a significant advantage over traditional T detectors: no confusion of the measurements by other beta-emitters, and complete separation of atomic and molecular species of equivalent atomic mass (e.g., HD and .sup.3 He).

  20. Development and performance of a miniature, low cost mass spectrometer

    E-Print Network [OSTI]

    Hemond, Brian D. (Brian David Thomson)

    2011-01-01T23:59:59.000Z

    A miniature, low cost mass spectrometer has been developed that is capable of unit resolution over a mass range of 10 to 50 AMU. The design of the mass spectrometer incorporates several new features that enhance the ...

  1. The production of ultra-high purity single isotopes or tailored isotope mixtures by ICP-MS

    SciTech Connect (OSTI)

    Liezers, Martin; Farmer, Orville T.; Dion, Michael P.; Thomas, Linda MP; Eiden, Gregory C.

    2015-01-01T23:59:59.000Z

    We report the development and testing of a simple collector arrangement for a commercial quadrupole ICP-MS that for the first time has been used to produce small quantities of highly enriched (>99.99%) single isotopes, with deposition rates >10 ng/hour. The collector assembly replaces the standard instrument detector allowing for implantation with simultaneous monitoring of the incident ion current. Even under zero bias implant conditions, low energy (<10 eV), ion collection efficiency was observed to be very high ~99%. 151Eu ion currents of 0.1-0.5 nA were collected on a simple, planar foil without resorting to any type of cup configuration. Recovery of the enriched isotope from such foils is much simpler than from a more complex cup configuration. High rejection of adjacent mass isotopes was demonstrated by selectively implanting 167Er without any discernible co-implantation of 166Er and 168Er. The important analytical possibilities of the new approach to isotope ratio measurement, tracer purification and radiation measurements are discussed.

  2. Microscale ion trap mass spectrometer

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Witten, William B. (Lancing, TN); Kornienko, Oleg (Lansdale, PA)

    2002-01-01T23:59:59.000Z

    An ion trap for mass spectrometric chemical analysis of ions is delineated. The ion trap includes a central electrode having an aperture; a pair of insulators, each having an aperture; a pair of end cap electrodes, each having an aperture; a first electronic signal source coupled to the central electrode; a second electronic signal source coupled to the end cap electrodes. The central electrode, insulators, and end cap electrodes are united in a sandwich construction where their respective apertures are coaxially aligned and symmetric about an axis to form a partially enclosed cavity having an effective radius r.sub.0 and an effective length 2z.sub.0, wherein r.sub.0 and/or z.sub.0 are less than 1.0 mm, and a ratio z.sub.0 /r.sub.0 is greater than 0.83.

  3. Portable gas chromatograph-mass spectrometer

    DOE Patents [OSTI]

    Andresen, B.D.; Eckels, J.D.; Kimmons, J.F.; Myers, D.W.

    1996-06-11T23:59:59.000Z

    A gas chromatograph-mass spectrometer (GC-MS) is described for use as a field portable organic chemical analysis instrument. The GC-MS is designed to be contained in a standard size suitcase, weighs less than 70 pounds, and requires less than 600 watts of electrical power at peak power (all systems on). The GC-MS includes: a conduction heated, forced air cooled small bore capillary gas chromatograph, a small injector assembly, a self-contained ion/sorption pump vacuum system, a hydrogen supply, a dual computer system used to control the hardware and acquire spectrum data, and operational software used to control the pumping system and the gas chromatograph. This instrument incorporates a modified commercial quadrupole mass spectrometer to achieve the instrument sensitivity and mass resolution characteristic of laboratory bench top units. 4 figs.

  4. Portable gas chromatograph-mass spectrometer

    DOE Patents [OSTI]

    Andresen, Brian D. (Livermore, CA); Eckels, Joel D. (Livermore, CA); Kimmons, James F. (Manteca, CA); Myers, David W. (Livermore, CA)

    1996-01-01T23:59:59.000Z

    A gas chromatograph-mass spectrometer (GC-MS) for use as a field portable organic chemical analysis instrument. The GC-MS is designed to be contained in a standard size suitcase, weighs less than 70 pounds, and requires less than 600 watts of electrical power at peak power (all systems on). The GC-MS includes: a conduction heated, forced air cooled small bore capillary gas chromatograph, a small injector assembly, a self-contained ion/sorption pump vacuum system, a hydrogen supply, a dual computer system used to control the hardware and acquire spectrum data, and operational software used to control the pumping system and the gas chromatograph. This instrument incorporates a modified commercial quadrupole mass spectrometer to achieve the instrument sensitivity and mass resolution characteristic of laboratory bench top units.

  5. Studies on the content of heavy metals in Aries River using ICP-MS

    SciTech Connect (OSTI)

    Voica, Cezara, E-mail: Cezara.Voica@itim-cj.ro; Kovacs, Melinda, E-mail: Cezara.Voica@itim-cj.ro; Feher, Ioana, E-mail: Cezara.Voica@itim-cj.ro [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)

    2013-11-13T23:59:59.000Z

    Among the industrial branches, the mining industry has always been an important source of environmental pollution, both aesthetically and chemically. Through this paper results of ICP-MS characterization of Aries River Basin are reported. Mining activities from this area has resulted in contamination of environment and its surrounding biota. This is clearly evidenced in analyzed water samples, especially from Baia de Aries site where increased amount of trace elements as Cr, Zn, As, Se, Cd, Pb and U were founded. Also in this site greater amount of rare earth elements was evidenced also. Through monitoring of Aries River from other non-mining area it was observed that the quantitative content of heavy metals was below the maximum permissible levels which made us to conclude that the water table wasn't seriously affected (which possibly might be attributed to the cessation of mining activities in this area from a few years ago)

  6. BREAKING NEWS! EMSL's 21 T mass spectrometer at field | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a Q&A is available on the 21T FTICR mass spectrometer web page. EMSL's new 21 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer is now at its full magnetic field...

  7. Capillary zone electrophoresis-mass spectrometer interface

    DOE Patents [OSTI]

    D'Silva, Arthur (Ames, IA)

    1996-08-06T23:59:59.000Z

    A device for providing equal electrical potential between two loci unconnected by solid or liquid electrical conducts is provided. The device comprises a first electrical conducting terminal, a second electrical conducting terminal connected to the first terminal by a rigid dielectric structure, and an electrically conducting gas contacting the first and second terminals. This device is particularly suitable for application in the electrospray ionization interface between a capillary zone electrophoresis apparatus and a mass spectrometer.

  8. Capillary zone electrophoresis-mass spectrometer interface

    DOE Patents [OSTI]

    D`Silva, A.

    1996-08-06T23:59:59.000Z

    A device for providing equal electrical potential between two loci unconnected by solid or liquid electrical conductors is provided. The device comprises a first electrical conducting terminal, a second electrical conducting terminal connected to the first terminal by a rigid dielectric structure, and an electrically conducting gas contacting the first and second terminals. This device is particularly suitable for application in the electrospray ionization interface between a capillary zone electrophoresis apparatus and a mass spectrometer. 1 fig.

  9. Expert overseer for mass spectrometer system

    DOE Patents [OSTI]

    Filby, Evan E. (Idaho Falls, ID); Rankin, Richard A. (Ammon, ID)

    1991-01-01T23:59:59.000Z

    An expert overseer for the operation and real-time management of a mass spectrometer and associated laboratory equipment. The overseer is a computer-based expert diagnostic system implemented on a computer separate from the dedicated computer used to control the mass spectrometer and produce the analysis results. An interface links the overseer to components of the mass spectrometer, components of the laboratory support system, and the dedicated control computer. Periodically, the overseer polls these devices and as well as itself. These data are fed into an expert portion of the system for real-time evaluation. A knowledge base used for the evaluation includes both heuristic rules and precise operation parameters. The overseer also compares current readings to a long-term database to detect any developing trends using a combination of statistical and heuristic rules to evaluate the results. The overseer has the capability to alert lab personnel whenever questionable readings or trends are observed and provide a background review of the problem and suggest root causes and potential solutions, or appropriate additional tests that could be performed. The overseer can change the sequence or frequency of the polling to respond to an observation in the current data.

  10. aerosol mass spectrometer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2004. The concentration of a species Zhang, Qi 8 Development of a thermal desorption chemical ionization mobility mass spectrometer for the speciation of ultrafine aerosols. Open...

  11. Mass spectrometer vacuum housing and pumping system

    DOE Patents [OSTI]

    Coutts, Gerald W. (Livermore, CA); Bushman, John F. (Oakley, CA); Alger, Terry W. (Tracy, CA)

    1996-01-01T23:59:59.000Z

    A vacuum housing and pumping system for a portable gas chromatograph/mass spectrometer (GC/MS). The vacuum housing section of the system has minimum weight for portability while designed and constructed to utilize metal gasket sealed stainless steel to be compatible with high vacuum operation. The vacuum pumping section of the system consists of a sorption (getter) pump to remove atmospheric leakage and outgassing contaminants as well as the gas chromatograph carrier gas (hydrogen) and an ion pump to remove the argon from atmospheric leaks. The overall GC/MS system has broad application to contaminants, hazardous materials, illegal drugs, pollution monitoring, etc., as well as for use by chemical weapon treaty verification teams, due to the light weight and portability thereof.

  12. Mass spectrometer vacuum housing and pumping system

    SciTech Connect (OSTI)

    Coutts, G.W.; Bushman, J.F.; Alger, T.W.

    1996-07-23T23:59:59.000Z

    A vacuum housing and pumping system is described for a portable gas chromatograph/mass spectrometer (GC/MS). The vacuum housing section of the system has minimum weight for portability while designed and constructed to utilize metal gasket sealed stainless steel to be compatible with high vacuum operation. The vacuum pumping section of the system consists of a sorption (getter) pump to remove atmospheric leakage and outgassing contaminants as well as the gas chromatograph carrier gas (hydrogen) and an ion pump to remove the argon from atmospheric leaks. The overall GC/MS system has broad application to contaminants, hazardous materials, illegal drugs, pollution monitoring, etc., as well as for use by chemical weapon treaty verification teams, due to the light weight and portability thereof. 7 figs.

  13. REPORT OF THE INDUCTIVELY COUPLED PLASMA -MASS SPECTROMETRY (ICP-MS)

    E-Print Network [OSTI]

    Three year Full Service Contract 1 CETAC Ultrasonic Nebulization Unit (Fig. 6) 1 Consumables Package 1

  14. Open-split interface for mass spectrometers

    DOE Patents [OSTI]

    Diehl, John W. (Grand Forks, ND)

    1991-01-01T23:59:59.000Z

    An open-split interface includes a connector body having four leg members projecting therefrom within a single plane, the first and third legs being coaxial and the second and fourth legs being coaxial. A tubular aperture extends through the first and third legs and a second tubular aperture extends through the second and fourth legs, connecting at a juncture within the center of the connector body. A fifth leg projects from the connector body and has a third tubular aperture extending therethrough to the juncture of the first and second tubular apertures. A capillary column extends from a gas chromatograph into the third leg with its end adjacent the juncture. A flow restrictor tube extends from a mass spectrometer through the first tubular aperture in the first and third legs and into the capillary columnm end, so as to project beyond the end of the third leg within the capillary column. An annular gap between the tube and column allows excess effluent to pass to the juncture. A pair of short capillary columns extend from separate detectors into the second tubular aperture in the second and fourth legs, and are oriented with their ends spaced slightly from the first capillary column end. A sweep flow tube is mounted in the fifth leg so as to supply a helium sweep flow to the juncture.

  15. Method for increasing the dynamic range of mass spectrometers

    DOE Patents [OSTI]

    Belov, Mikhail; Smith, Richard D.; Udseth, Harold R.

    2004-09-07T23:59:59.000Z

    A method for enhancing the dynamic range of a mass spectrometer by first passing a sample of ions through the mass spectrometer having a quadrupole ion filter, whereupon the intensities of the mass spectrum of the sample are measured. From the mass spectrum, ions within this sample are then identified for subsequent ejection. As further sampling introduces more ions into the mass spectrometer, the appropriate rf voltages are applied to a quadrupole ion filter, thereby selectively ejecting the undesired ions previously identified. In this manner, the desired ions may be collected for longer periods of time in an ion trap, thus allowing better collection and subsequent analysis of the desired ions. The ion trap used for accumulation may be the same ion trap used for mass analysis, in which case the mass analysis is performed directly, or it may be an intermediate trap. In the case where collection is an intermediate trap, the desired ions are accumulated in the intermediate trap, and then transferred to a separate mass analyzer. The present invention finds particular utility where the mass analysis is performed in an ion trap mass spectrometer or a Fourier transform ion cyclotron resonance mass spectrometer.

  16. Single-ultrafine-particle mass spectrometer development and application

    E-Print Network [OSTI]

    Glagolenko, Stanislav Yurievich

    2004-11-15T23:59:59.000Z

    A single-ultrafine-particle mass spectrometer was constructed and deployed for size-resolved ultrafine aerosol composition measurements during the winter of 2002-2003 in College Station, Texas. Three separate experiments were held between December...

  17. Electron source for a mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, D.D.; Keville, R.F.

    1995-12-19T23:59:59.000Z

    An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

  18. Electron source for a mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, Daniel D. (Livermore, CA); Keville, Robert F. (Valley Springs, CA)

    1995-01-01T23:59:59.000Z

    An ion trap which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10.sup.9 and commercial mass spectrometers requiring 10.sup.4 ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products.

  19. EXTENDING THE USEFUL LIFE OF OLDER MASS SPECTROMETERS

    SciTech Connect (OSTI)

    Johnson, S.; Cordaro, J.; Holland, M.; Jones, V.

    2010-06-17T23:59:59.000Z

    Thermal ionization and gas mass spectrometers are widely used across the Department of Energy (DOE) Complex and contractor laboratories. These instruments support critical missions, where high reliability and low measurement uncertainty are essential. A growing number of these mass spectrometers are significantly older than their original design life. The reality is that manufacturers have declared many of the instrument models obsolete, with direct replacement parts and service no longer available. Some of these obsolete models do not have a next generation, commercially available replacement. Today's budget conscious economy demands for the use of creative funds management. Therefore, the ability to refurbish (or upgrade) these valuable analytical tools and extending their useful life is a cost effective option. The Savannah River Site (SRS) has the proven expertise to breathe new life into older mass spectrometers, at a significant cost savings compared to the purchase and installation of new instruments. A twenty-seven year old Finnigan MAT-261{trademark} Thermal Ionization Mass Spectrometer (TIMS), located at the SRS F/H Area Production Support Laboratory, has been successfully refurbished. Engineers from the Savannah River National Laboratory (SRNL) fabricated and installed the new electronics. These engineers also provide continued instrument maintenance services. With electronic component drawings being DOE Property, other DOE Complex laboratories have the option to extend the life of their aged Mass Spectrometers.

  20. Compact mass spectrometer for plasma discharge ion analysis

    DOE Patents [OSTI]

    Tuszewski, Michel G. (Los Alamos, NM)

    1997-01-01T23:59:59.000Z

    A mass spectrometer and methods for mass spectrometry which are useful in characterizing a plasma. This mass spectrometer for determining type and quantity of ions present in a plasma is simple, compact, and inexpensive. It accomplishes mass analysis in a single step, rather than the usual two-step process comprised of ion extraction followed by mass filtering. Ions are captured by a measuring element placed in a plasma and accelerated by a known applied voltage. Captured ions are bent into near-circular orbits by a magnetic field such that they strike a collector, producing an electric current. Ion orbits vary with applied voltage and proton mass ratio of the ions, so that ion species may be identified. Current flow provides an indication of quantity of ions striking the collector.

  1. Design and construction of an experimental mass spectrometer

    E-Print Network [OSTI]

    Wall, Robert F.

    1950-01-01T23:59:59.000Z

    Experiment Station, the Texas A and M Research Foundation, and the Westinghouse Electric Corporation. The Westinghouse Electric Corporation donated a mass spectrometer and recorder of their manufacture to the col? lege and established a fellowship... in mass spectrometry. This instrument is of the 90? magnetic sector type, and em? ploys automatic magnetic mass scanning and recording. The experience gained with this instrument and the assistance of the Westinghouse fellows has been invaluable...

  2. Mass Spectrometer Laboratory | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighand Retrievals from a New 183-GHzMAR Os ZD15netMary K.MasatoshiMass

  3. Micro mass spectrometer on a chip.

    SciTech Connect (OSTI)

    Cruz, Dolores Y.; Blain, Matthew Glenn; Fleming, James Grant

    2005-11-01T23:59:59.000Z

    The design, simulation, fabrication, packaging, electrical characterization and testing analysis of a microfabricated a cylindrical ion trap ({mu}CIT) array is presented. Several versions of microfabricated cylindrical ion traps were designed and fabricated. The final design of the individual trap array element consisted of two end cap electrodes, one ring electrode, and a detector plate, fabricated in seven tungsten metal layers by molding tungsten around silicon dioxide (SiO{sub 2}) features. Each layer of tungsten is then polished back in damascene fashion. The SiO{sub 2} was removed using a standard release processes to realize a free-hung structure. Five different sized traps were fabricated with inner radii of 1, 1.5, 2, 5 and 10 {micro}m and heights ranging from 3-24 {micro}m. Simulations examined the effects of ion and neutral temperature, the pressure and nature of cooling gas, ion mass, trap voltage and frequency, space-charge, fabrication defects, and other parameters on the ability of micrometer-sized traps to store ions. The electrical characteristics of the ion trap arrays were determined. The capacitance was 2-500 pF for the various sized traps and arrays. The resistance was in the order of 1-2 {Omega}. The inductance of the arrays was calculated to be 10-1500 pH, depending on the trap and array sizes. The ion traps' field emission characteristics were assessed. It was determined that the traps could be operated up to 125 V while maintaining field emission currents below 1 x 10{sup -15} A. The testing focused on using the 5-{micro}m CITs to trap toluene (C{sub 7}H{sub 8}). Ion ejection from the traps was induced by termination of the RF voltage applied to the ring electrode and current measured on the collector electrode suggested trapping of ions in 1-10% of the traps. Improvements to the to the design of the traps were defined to minimize voltage drop to the substrate, thereby increasing trapping voltage applied to the ring electrode, and to allow for electron injection into, ion ejection from, and optical access to the trapping region.

  4. Mass Spectrometer: Time of Flight Secondary Ion (ToF SIMS) -...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - 1997 Mass Spectrometer: Time of Flight Secondary Ion (ToF SIMS) - 1997 The Physical Electronics Instruments (PHI) Model T2100 time-of-flight secondary ion mass spectrometer...

  5. Mass Spectrometer: FT-ICR, 6T (Ion Surface Collisions) | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mass Spectrometer: FT-ICR, 6T (Ion Surface Collisions) The 6-Tesla High-Field Fourier Transform Ion Cyclotron Resonance Mass Spectrometer (FT-ICR MS), is a unique...

  6. Estimation of the formation rates of polyatomic species of heavy metals in plutonium analyses using a multicollector ICP-MS with a desolvating nebulizer

    SciTech Connect (OSTI)

    Mitroshkov, Alexandre V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Olsen, Khris B. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Thomas, Linda M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-01-01T23:59:59.000Z

    The analyses of IAEA and environmental samples for Plutonium isotopic content are conducted normally at very low concentrations of Pu–usually in the range of part per trillion level and even more often at the parts per quadrillion level. To analyze such low concentrations, the interferences in the analytical solution must be reduced as much as possible. Polyatomic interferences (PIs), formed by the heavy metals (HMs) from Hf to Bi are known to create the problems for Pu isotopic analyses, because even the relatively high resolution of a modern multicollector ICP-MS is not enough to separate Pu isotopes from this PIs in most of the cases. Desolvating nebulizers (DSN) (e.g. APEX and AridusII) reduce significantly the formation of PIs compare to the use of wet plasma. The purpose of this work was to investigate the rate of formation of PIs, produced by HMs, when high resolution MC ICP-MS with desolvating nebulizer was used for Pu isotopic analyses and to estimate the influence of the metals present in the sample on the results of analyses. The NU Plasma HR Multicollector and AridusII desolvating nebulizer were used in this investigation. This investigation was done for all Pu isotopes normally analyzed by ICP-MS, including ²??Pu, with the exception of ²³?Pu, which most of the time can’t be analyzed by ICP-MS, because of the overwhelming presence of ²³?U in the solutions. The PI formation rates were determined and reported for all 12 HMs from Hf to Bi. Selected IAEA samples were scanned for the presence of HMs and the influence of HMs on the results of Pu isotopic analyses was evaluated. It was found that the implemented separation procedure provides sufficient separation of HM from Pu, although the effect of PIs on the measurement of low level isotopes like ²?¹Pu and ²?²Pu in some cases can still be observed.

  7. Continuous time-of-flight ion mass spectrometer

    DOE Patents [OSTI]

    Funsten, Herbert O.; Feldman, William C.

    2004-10-19T23:59:59.000Z

    A continuous time-of-flight mass spectrometer having an evacuated enclosure with means for generating an electric field located in the evacuated enclosure and means for injecting a sample material into the electric field. A source of continuous ionizing radiation injects ionizing radiation into the electric field to ionize atoms or molecules of the sample material, and timing means determine the time elapsed between arrival of a secondary electron out of said ionized atoms or molecules at a first predetermined location and arrival of a sample ion out of said ionized atoms or molecules at a second predetermined location.

  8. Miniature quadrupole mass spectrometer having a cold cathode ionization source

    DOE Patents [OSTI]

    Felter, Thomas E. (Livermore, CA)

    2002-01-01T23:59:59.000Z

    An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

  9. Linear electric field time-of-flight ion mass spectrometer

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM); Feldman, William C. (Los Alamos, NM)

    2008-06-10T23:59:59.000Z

    A linear electric field ion mass spectrometer having an evacuated enclosure with means for generating a linear electric field located in the evacuated enclosure and means for injecting a sample material into the linear electric field. A source of pulsed ionizing radiation injects ionizing radiation into the linear electric field to ionize atoms or molecules of the sample material, and timing means determine the time elapsed between ionization of atoms or molecules and arrival of an ion out of the ionized atoms or molecules at a predetermined position.

  10. UV and IR laser ablation for inductively coupled plasma mass spectrometry

    SciTech Connect (OSTI)

    Smith, M.R.; Koppenaal, D.W.; Farmer, O.T.

    1993-06-01T23:59:59.000Z

    Laser ablation particle plume compositions are characterized using inductively coupled plasma mass spectrometry (ICP/MS). This study evaluates the mass response characteristics peculiar to ICP/MS detection as a function of laser fluence and frequency. Evaluation of the ICP/MS mass response allows deductions to be made concerning how representative the laser ablation produced particle plume composition is relative to the targeted sample. Using a black glass standard, elemental fractionation was observed, primarily for alkalis and other volatile elements. The extent of elemental fractionation between the target sample and the sampled plume varied significantly as a function of laser fluences and IR and UV laser frequency.

  11. Linear electronic field time-of-flight ion mass spectrometers

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM)

    2010-08-24T23:59:59.000Z

    Time-of-flight mass spectrometer comprising a first drift region and a second drift region enclosed within an evacuation chamber; a means of introducing an analyte of interest into the first drift region; a pulsed ionization source which produces molecular ions from said analyte of interest; a first foil positioned between the first drift region and the second drift region, which dissociates said molecular ions into constituent atomic ions and emits secondary electrons; an electrode which produces secondary electrons upon contact with a constituent atomic ion in second drift region; a stop detector comprising a first ion detection region and a second ion detection region; and a timing means connected to the pulsed ionization source, to the first ion detection region, and to the second ion detection region.

  12. Mass measurements near the $r$-process path using the Canadian Penning Trap mass spectrometer

    E-Print Network [OSTI]

    J. Van Schelt; D. Lascar; G. Savard; J. A. Clark; S. Caldwell; A. Chaudhuri; J. Fallis; J. P. Greene; A. F. Levand; G. Li; K. S. Sharma; M. G. Sternberg; T. Sun; B. J. Zabransky

    2012-04-09T23:59:59.000Z

    The masses of 40 neutron-rich nuclides from Z = 51 to 64 were measured at an average precision of $\\delta m/m= 10^{-7}$ using the Canadian Penning Trap mass spectrometer at Argonne National Laboratory. The measurements, of fission fragments from a $^{252}$Cf spontaneous fission source in a helium gas catcher, approach the predicted path of the astrophysical $r$ process. Where overlap exists, this data set is largely consistent with previous measurements from Penning traps, storage rings, and reaction energetics, but large systematic deviations are apparent in $\\beta$-endpoint measurements. Differences in mass excess from the 2003 Atomic Mass Evaluation of up to 400 keV are seen, as well as systematic disagreement with various mass models.

  13. SIEMENS ADVANCED QUANTRA FTICR MASS SPECTROMETER FOR ULTRA HIGH RESOLUTION AT LOW MASS

    SciTech Connect (OSTI)

    Spencer, W; Laura Tovo, L

    2008-07-08T23:59:59.000Z

    The Siemens Advanced Quantra Fourier Transform Ion Cyclotron Resonance (FTICR) mass spectrometer was evaluated as an alternative instrument to large double focusing mass spectrometers for gas analysis. High resolution mass spectrometers capable of resolving the common mass isomers of the hydrogen isotopes are used to provide data for accurate loading of reservoirs and to monitor separation of tritium, deuterium, and helium. Conventional double focusing magnetic sector instruments have a resolution that is limited to about 5000. The Siemens FTICR instrument achieves resolution beyond 400,000 and could possibly resolve the tritium ion from the helium-3 ion, which differ by the weight of an electron, 0.00549 amu. Working with Y-12 and LANL, SRNL requested Siemens to modify their commercial Quantra system for low mass analysis. To achieve the required performance, Siemens had to increase the available waveform operating frequency from 5 MHz to 40 MHz and completely redesign the control electronics and software. However, they were able to use the previous ion trap, magnet, passive pump, and piezo-electric pulsed inlet valve design. NNSA invested $1M in this project and acquired four systems, two for Y-12 and one each for SRNL and LANL. Siemens claimed a $10M investment in the Quantra systems. The new Siemens Advanced Quantra demonstrated phenomenal resolution in the low mass range. Resolution greater than 400,000 was achieved for mass 2. The new spectrometer had a useful working mass range to 500 Daltons. However, experiments found that a continuous single scan from low mass to high was not possible. Two useful working ranges were established covering masses 1 to 6 and masses 12 to 500 for our studies. A compromise performance condition enabled masses 1 to 45 to be surveyed. The instrument was found to have a dynamic range of about three orders of magnitude and quantitative analysis is expected to be limited to around 5 percent without using complex fitting algorithms. Analysis of low concentration ions, at the ppm level, required a separate analysis using ion ejection techniques. Chemical ionization due to the formation of the MH{sup +} ion or MD{sup +} increased the complexity of the spectra compared to magnetic sector mass spectra and formation of the protonated or deuterated complex was a dynamic function of the trap ion concentration. This made quantitative measurement more of a challenge. However, the resolution of the instrument was far superior to any other mass spectrometry technique that has been applied to the analysis of the hydrogen isotopes. The piezo-electric picoliter injection device offers a new way of submitting small quantities of atmospheric pressure sample gas for analysis. The new software had many improvements over the previous version but significant flaws in the beta codes remain that make the prototype units less than ideal. The instrument is a promising new technology that experience will likely improve. Unfortunately, Siemens has concluded that the technology will not be a commercial success and has decided to stop producing this product.

  14. High Resolution Studies of the Origins of Polyatomic Ions in Inductively Coupled Plasma-Mass Spectrometry

    SciTech Connect (OSTI)

    Jill Wisnewski Ferguson

    2006-08-09T23:59:59.000Z

    The inductively coupled plasma (ICP) is an atmospheric pressure ionization source. Traditionally, the plasma is sampled via a sampler cone. A supersonic jet develops behind the sampler, and this region is pumped down to a pressure of approximately one Torr. A skimmer cone is located inside this zone of silence to transmit ions into the mass spectrometer. The position of the sampler and skimmer cones relative to the initial radiation and normal analytical zones of the plasma is key to optimizing the useful analytical signal [1]. The ICP both atomizes and ionizes the sample. Polyatomic ions form through ion-molecule interactions either in the ICP or during ion extraction [l]. Common polyatomic ions that inhibit analysis include metal oxides (MO{sup +}), adducts with argon, the gas most commonly used to make up the plasma, and hydride species. While high resolution devices can separate many analytes from common interferences, this is done at great cost in ion transmission efficiency--a loss of 99% when using high versus low resolution on the same instrument [2]. Simple quadrupole devices, which make up the bulk of ICP-MS instruments in existence, do not present this option. Therefore, if the source of polyatomic interferences can be determined and then manipulated, this could potentially improve the figures of merit on all ICP-MS devices, not just the high resolution devices often utilized to study polyatomic interferences.

  15. Fundamental and methodological investigations for the improvement of elemental analysis by inductively coupled plasma mass soectrometry

    SciTech Connect (OSTI)

    Ebert, Christopher Hysjulien [Ames Laboratory

    2012-07-27T23:59:59.000Z

    This dissertation describes a variety of studies meant to improve the analytical performance of inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation (LA) ICP-MS. The emission behavior of individual droplets and LA generated particles in an ICP is studied using a high-speed, high frame rate digital camera. Phenomena are observed during the ablation of silicate glass that would cause elemental fractionation during analysis by ICP-MS. Preliminary work for ICP torch developments specifically tailored for the improvement of LA sample introduction are presented. An abnormal scarcity of metal-argon polyatomic ions (MAr{sup +}) is observed during ICP-MS analysis. Evidence shows that MAr{sup +} ions are dissociated by collisions with background gas in a shockwave near the tip of the skimmer cone. Method development towards the improvement of LA-ICP-MS for environmental monitoring is described. A method is developed to trap small particles in a collodion matrix and analyze each particle individually by LA-ICP-MS.

  16. Laser ablation-inductively coupled plasma-mass spectrometry: Examinations of the origins of polyatomic ions and advances in the sampling of particulates

    SciTech Connect (OSTI)

    Witte, Travis

    2011-11-30T23:59:59.000Z

    This dissertation provides a general introduction to Inductively coupled plasma-mass spectrometry (ICP-MS) and laser ablation (LA) sampling, with an examination of analytical challenges in the employment of this technique. It discusses the origin of metal oxide ions (MO+) in LA-ICP-MS, as well as the effect of introducing helium and nitrogen to the aerosol gas flow on the formation of these polyatomic interferences. It extends the study of polyatomic ions in LA-ICP-MS to metal argide (MAr+) species, an additional source of possible significant interferences in the spectrum. It describes the application of fs-LA-ICP-MS to the determination of uranium isotope ratios in particulate samples.

  17. accelerator mass spectrometer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sensitive detector Osborne, David L. 2009-01-01 9 RAPID COMMUNICATIONS IN MASS SPECTROMETRY, VOL. 9, 1141-1147 (1995) New Matrices and Accelerating Voltage Effects Chemistry...

  18. Dipole Excitation With A Paul Ion Trap Mass Spectrometer

    SciTech Connect (OSTI)

    MacAskill, J. A.; Madzunkov, S. M.; Chutjian, A. [Atomic and Molecular Physics Group, Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109 (United States)

    2011-06-01T23:59:59.000Z

    Preliminary results are presented for the use of an auxiliary radiofrequency (rf) excitation voltage in combination with a high purity, high voltage rf generator to perform dipole excitation within a high precision Paul ion trap. These results show the effects of the excitation frequency over a continuous frequency range on the resultant mass spectra from the Paul trap with particular emphasis on ion ejection times, ion signal intensity, and peak shapes. Ion ejection times are found to decrease continuously with variations in dipole frequency about several resonant values and show remarkable symmetries. Signal intensities vary in a complex fashion with numerous resonant features and are driven to zero at specific frequency values. Observed intensity variations depict dipole excitations that target ions of all masses as well as individual masses. Substantial increases in mass resolution are obtained with resolving powers for nitrogen increasing from 114 to 325.

  19. ICP-MS (Quadrupole) | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanocomposite Synthesized in Supercritical Fluid as Electrocatalysts for Low-Temperature Fuel Cells. Carbon nanotube (CNT)-supported Pt nanoparticles catalysts have been...

  20. Field-Deployable, High-Resolution, Time-of-Flight Aerosol Mass Spectrometer

    E-Print Network [OSTI]

    Jimenez, Jose-Luis

    as a powerful tool to characterize aerosols. A number of laser ablation instruments have been developed and trigger a laser ablation time-of-flight mass spectrometer, which determines the composition of the sized surface rather than by ablation lasers.8-10 At present, the most commonly used instrument of this type

  1. Gas chromatograph-mass spectrometer (GC/MS) system for quantitative analysis of reactive chemical compounds

    DOE Patents [OSTI]

    Grindstaff, Quirinus G. (Oak Ridge, TN)

    1992-01-01T23:59:59.000Z

    Described is a new gas chromatograph-mass spectrometer (GC/MS) system and method for quantitative analysis of reactive chemical compounds. All components of such a GC/MS system external to the oven of the gas chromatograph are programmably temperature controlled to operate at a volatilization temperature specific to the compound(s) sought to be separated and measured.

  2. Design and evaluation of a miniaturized Particle Desorption Mass Spectrometer

    E-Print Network [OSTI]

    Davis, Kelly Vaughn

    1987-01-01T23:59:59.000Z

    of the incident particles, the age of the detector, and the mass, polarity, and energy of the desorbed ions (25). The efficiency was estimated from a published efficiency curve which allowed for a diversity of conditions (25). From this curve the efficiency... to determine the flux of primary ions impacting the sample surface. In the configuration adopted for this experiment, the count rate of the start detector is somewhat ambiguously related to the primary ion flux since a fission fragment pair coming from...

  3. HD gas analysis with Gas Chromatography and Quadrupole Mass Spectrometer

    E-Print Network [OSTI]

    Ohta, T; Didelez, J -P; Fujiwara, M; Fukuda, K; Kohri, H; Kunimatsu, T; Morisaki, C; Ono, S; Rouille, G; Tanaka, M; Ueda, K; Uraki, M; Utsuro, M; Wang, S Y; Yosoi, M

    2011-01-01T23:59:59.000Z

    A gas analyzer system has been developed to analyze Hydrogen-Deuteride (HD) gas for producing frozen-spin polarized HD targets, which are used for hadron photoproduction experiments at SPring-8. Small amounts of ortho-H$_{2}$ and para-D$_{2}$ gas mixtures ($\\sim$0.01%) in the purified HD gas are a key to realize a frozen-spin polarized target. In order to obtain reliable concentrations of these gas mixtures in the HD gas, we produced a new gas analyzer system combining two independent measurements with the gas chromatography and the QMS. The para-H$_{2}$, ortho-H$_{2}$, HD, and D$_{2}$ are separated using the retention time of the gas chromatography and the mass/charge. It is found that the new gas analyzer system can measure small concentrations of $\\sim$0.01% for the otho-H$_2$ and D$_2$ with good S/N ratios.

  4. HD gas analysis with Gas Chromatography and Quadrupole Mass Spectrometer

    E-Print Network [OSTI]

    T. Ohta; S. Bouchigny; J. -P. Didelez; M. Fujiwara; K. Fukuda; H. Kohri; T. Kunimatsu; C. Morisaki; S. Ono; G. Rouille; M. Tanaka; K. Ueda; M. Uraki; M. Utsuro; S. Y. Wang; M. Yosoi

    2011-01-28T23:59:59.000Z

    A gas analyzer system has been developed to analyze Hydrogen-Deuteride (HD) gas for producing frozen-spin polarized HD targets, which are used for hadron photoproduction experiments at SPring-8. Small amounts of ortho-H$_{2}$ and para-D$_{2}$ gas mixtures ($\\sim$0.01%) in the purified HD gas are a key to realize a frozen-spin polarized target. In order to obtain reliable concentrations of these gas mixtures in the HD gas, we produced a new gas analyzer system combining two independent measurements with the gas chromatography and the QMS. The para-H$_{2}$, ortho-H$_{2}$, HD, and D$_{2}$ are separated using the retention time of the gas chromatography and the mass/charge. It is found that the new gas analyzer system can measure small concentrations of $\\sim$0.01% for the otho-H$_2$ and D$_2$ with good S/N ratios.

  5. High mass resolution time of flight mass spectrometer for measuring products in heterogeneous catalysis in highly sensitive microreactors

    SciTech Connect (OSTI)

    Andersen, T.; Jensen, R.; Christensen, M. K.; Chorkendorff, I. [Department of Physics, Danish National Research Foundation's Center for Individual Nanoparticle Functionality (CINF), Technical University of Denmark, Building 312, DK-2800 Kgs. Lyngby (Denmark); Pedersen, T.; Hansen, O. [Department of Micro- and Nanotechnology, Technical University of Denmark, DTU Nanotech Building 345 East, DK-2800 Kgs. Lyngby (Denmark)

    2012-07-15T23:59:59.000Z

    We demonstrate a combined microreactor and time of flight system for testing and characterization of heterogeneous catalysts with high resolution mass spectrometry and high sensitivity. Catalyst testing is performed in silicon-based microreactors which have high sensitivity and fast thermal response. Gas analysis is performed with a time of flight mass spectrometer with a modified nude Bayard-Alpert ionization gauge as gas ionization source. The mass resolution of the time of flight mass spectrometer using the ion gauge as ionization source is estimated to m/{Delta}m > 2500. The system design is superior to conventional batch and flow reactors with accompanying product detection by quadrupole mass spectrometry or gas chromatography not only due to the high sensitivity, fast temperature response, high mass resolution, and fast acquisition time of mass spectra but it also allows wide mass range (0-5000 amu in the current configuration). As a demonstration of the system performance we present data from ammonia oxidation on a Pt thin film showing resolved spectra of OH and NH{sub 3}.

  6. Elimination of ``memory`` from sample handling and inlet system of a mass spectrometer

    DOE Patents [OSTI]

    Chastgner, P.

    1991-05-08T23:59:59.000Z

    This paper describes a method for preparing the sample handling and inlet system of a mass spectrometer for analysis of a subsequent sample following analysis of a previous sample comprising the flushing of the system interior with supercritical CO{sub 2} and venting the interior. The method eliminates the effect of system ``memory`` on the subsequent analysis, especially following persistent samples such as xenon and krypton.

  7. Investigation of gamma induced degradation of Amberlite 200 cation resin by mass spectrometer and liquid chromatograph

    E-Print Network [OSTI]

    Freitag, Albert Antonio

    1977-01-01T23:59:59.000Z

    of the requirement for the degree of MASTER OF SCIENCE December 1977 Major Subject: Nuclear Engineering INVESTIGATION OI' GAMMA INDUCED DEGRADATION OF AMBERLITE 200 CATION RESIN BY MASS SPECTROMETER AND LIQUID CHROMATOGRAPH A Thesis by ALBERT ANTONIO FREITAG... and to Dr. Robert G. Cochran, Head of the Nuclear Engineering Department, for providing the financial support necessary for completion of this work. DEDICATION I dedicate this work to my wife, Diann, for her tolerance and support. Vi TADLE OF CONTL...

  8. Portable gas chromatograph mass spectrometer for on-site chemical analyses

    DOE Patents [OSTI]

    Haas, Jeffrey S. (San Ramon, CA); Bushman, John F. (Oakley, CA); Howard, Douglas E. (Livermore, CA); Wong, James L. (Livermore, CA); Eckels, Joel D. (Livermore, CA)

    2002-01-01T23:59:59.000Z

    A portable, lightweight (approximately 25 kg) gas chromatograph mass spectrometer, including the entire vacuum system, can perform qualitative and quantitative analyses of all sample types in the field. The GC/MS has a conveniently configured layout of components for ease of serviceability and maintenance. The GC/MS system can be transported under operating or near-operating conditions (i.e., under vacuum and at elevated temperature) to reduce the downtime before samples can be analyzed on-site.

  9. Fundamental studies of the plasma extraction and ion beam formation processes in inductively coupled plasma mass spectrometry

    SciTech Connect (OSTI)

    Niu, Hongsen

    1995-02-10T23:59:59.000Z

    The fundamental and practical aspects are described for extracting ions from atmospheric pressure plasma sources into an analytical mass spectrometer. Methodologies and basic concepts of inductively coupled plasma mass spectrometry (ICP-MS) are emphasized in the discussion, including ion source, sampling interface, supersonic expansion, slumming process, ion optics and beam focusing, and vacuum considerations. Some new developments and innovative designs are introduced. The plasma extraction process in ICP-MS was investigated by Langmuir measurements in the region between the skimmer and first ion lens. Electron temperature (T{sub e}) is in the range 2000--11000 K and changes with probe position inside an aerosol gas flow. Electron density (n{sub e}) is in the range 10{sup 8}--10{sup 10} {sup {minus}cm }at the skimmer tip and drops abruptly to 10{sup 6}--10{sup 8} cm{sup {minus}3} near the skimmer tip and drops abruptly to 10{sup 6}--10{sup 8} cm{sup {minus}3} downstream further behind the skimmer. Electron density in the beam leaving the skimmer also depends on water loading and on the presence and mass of matrix elements. Axially resolved distributions of electron number-density and electron temperature were obtained to characterize the ion beam at a variety of plasma operating conditions. The electron density dropped by a factor of 101 along the centerline between the sampler and skimmer cones in the first stage and continued to drop by factors of 10{sup 4}--10{sup 5} downstream of skimmer to the entrance of ion lens. The electron density in the beam expansion behind sampler cone exhibited a 1/z{sup 2} intensity fall-off (z is the axial position). An second beam expansion originated from the skimmer entrance, and the beam flow underwent with another 1/z{sup 2} fall-off behind the skimmer. Skimmer interactions play an important role in plasma extraction in the ICP-MS instrument.

  10. Method for studying a sample of material using a heavy ion induced mass spectrometer source

    DOE Patents [OSTI]

    Fries, David P. (St. Petersburg, FL); Browning, James F. (Palm Harbour, FL)

    1999-01-01T23:59:59.000Z

    A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu.

  11. Advanced Mass Calibration and Visualization for FT-ICR Mass Spectromet...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for FT-ICR Mass Spectrometry Imaging. Abstract: Mass spectrometry imaging by Fourier transform ion cyclotron resonance (FT-ICR) yields hundreds of unique peaks, many of...

  12. Improved ion optics for introduction of ions into a 9.4-T Fourier transform ion cyclotron resonance mass spectrometer

    SciTech Connect (OSTI)

    Chen, Yu; Leach, Franklin E.; Kaiser, Nathan K.; Dang, Xibei; Ibrahim, Yehia M.; Norheim, Randolph V.; Anderson, Gordon A.; Smith, Richard D.; Marshall, Alan G.

    2015-01-01T23:59:59.000Z

    Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry provides unparalleled mass accuracy and resolving power.[1],[2] With electrospray ionization (ESI), ions are typically transferred into the mass spectrometer through a skimmer, which serves as a conductance-limiting orifice. However, the skimmer allows only a small fraction of incoming ions to enter the mass spectrometer. An ion funnel, originally developed by Smith and coworkers at Pacific Northwest National Laboratory (PNNL)[3-5] provides much more efficient ion focusing and transfer. The large entrance aperture of the ion funnel allows almost all ions emanating from a heated capillary to be efficiently captured and transferred, resulting in nearly lossless transmission.

  13. A new method of alpha ray measurement using a Quadrupole Mass Spectrometer

    E-Print Network [OSTI]

    Y. Iwata; Y. Inoue; M. Minowa

    2007-04-16T23:59:59.000Z

    We propose a new method of alpha($\\alpha$)-ray measurement that detects helium atoms with a Quadrupole Mass Spectrometer(QMS). A demonstration is undertaken with a plastic-covered $^{241}$Am $\\alpha$-emitting source to detect $\\alpha$-rays stopped in the capsule. We successfully detect helium atoms that diffuse out of the capsule by accumulating them for one to 20 hours in a closed chamber. The detected amount is found to be proportional to the accumulation time. Our method is applicable to probe $\\alpha$-emitting radioactivity in bulk material.

  14. Development of a cold cathode ion source for a mass spectrometer type vacuum leak detector

    E-Print Network [OSTI]

    Thomas, Harold Albert

    1947-01-01T23:59:59.000Z

    of about 7 cm., discharge voltage of about 2000 volts, discharge current of 10 ma., and a magnetic field strength of approximately 2200 Oersteds. As a leak detector it had a differential sensitivity of one part of helium in 10,000 parts of air ? about... for this ion souree as for the first type tested# Be? cause of the simpler construction and fewer components reauired, it appears that this type of source would have some valuable possibili? ties as a mass spectrometer ion source for the leak detector...

  15. Inductively Coupled Plasma: Fundamental Particle Investigations with Laser Ablation and Applications in Magnetic Sector Mass Spectrometry

    SciTech Connect (OSTI)

    Nathan Joe Saetveit

    2008-08-18T23:59:59.000Z

    Particle size effects and elemental fractionation in laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) are investigated with nanosecond and femtosecond laser ablation, differential mobility analysis, and magnetic sector ICP-MS. Laser pulse width was found to have a significant influence on the LA particle size distribution and the elemental composition of the aerosol and thus fractionation. Emission from individual particles from solution nebulization, glass, and a pressed powder pellet are observed with high speed digital photography. The presence of intact particles in an ICP is shown to be a likely source of fractionation. A technique for the online detection of stimulated elemental release from neural tissue using magnetic sector ICP-MS is described. Detection limits of 1 {micro}g L{sup -1} or better were found for P, Mn, Fe, Cu, and Zn in a 60 {micro}L injection in a physiological saline matrix.

  16. Measurement of low radioactivity background in a high voltage cable by high resolution inductively coupled plasma mass spectrometry

    SciTech Connect (OSTI)

    Vacri, M. L. di; Nisi, S.; Balata, M. [Gran Sasso National Laboratory, Chemistry Service, SS 17bis km 18.910, 67100 Assergi (Aq) (Italy)] [Gran Sasso National Laboratory, Chemistry Service, SS 17bis km 18.910, 67100 Assergi (Aq) (Italy)

    2013-08-08T23:59:59.000Z

    The measurement of naturally occurring low level radioactivity background in a high voltage (HV) cable by high resolution inductively coupled plasma mass spectrometry (HR ICP MS) is presented in this work. The measurements were performed at the Chemistry Service of the Gran Sasso National Laboratory. The contributions to the radioactive background coming from the different components of the heterogeneous material were separated. Based on the mass fraction of the cable, the whole contamination was calculated. The HR ICP MS results were cross-checked by gamma ray spectroscopy analysis that was performed at the low background facility STELLA (Sub Terranean Low Level Assay) of the LNGS underground lab using HPGe detectors.

  17. Mass spectrometer with electron source for reducing space charge effects in sample beam

    DOE Patents [OSTI]

    Houk, Robert S.; Praphairaksit, Narong

    2003-10-14T23:59:59.000Z

    A mass spectrometer includes an ion source which generates a beam including positive ions, a sampling interface which extracts a portion of the beam from the ion source to form a sample beam that travels along a path and has an excess of positive ions over at least part of the path, thereby causing space charge effects to occur in the sample beam due to the excess of positive ions in the sample beam, an electron source which adds electrons to the sample beam to reduce space charge repulsion between the positive ions in the sample beam, thereby reducing the space charge effects in the sample beam and producing a sample beam having reduced space charge effects, and a mass analyzer which analyzes the sample beam having reduced space charge effects.

  18. Manifold and method of batch measurement of Hg-196 concentration using a mass spectrometer

    DOE Patents [OSTI]

    Grossman, M.W.; Evans, R.

    1991-11-26T23:59:59.000Z

    A sample manifold and method of its use has been developed so that milligram quantities of mercury can be analyzed mass spectroscopically to determine the [sup 196]Hg concentration to less than 0.02 atomic percent. Using natural mercury as a standard, accuracy of [+-]0.002 atomic percent can be obtained. The mass spectrometer preferably used is a commercially available GC/MS manufactured by Hewlett Packard. A novel sample manifold is contained within an oven allowing flow rate control of Hg into the MS. Another part of the manifold connects to an auxiliary pumping system which facilitates rapid clean up of residual Hg in the manifold. Sample cycle time is about 1 hour. 8 figures.

  19. Manifold and method of batch measurement of Hg-196 concentration using a mass spectrometer

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); Evans, Roger (N. Hampton, NH)

    1991-01-01T23:59:59.000Z

    A sample manifold and method of its use has been developed so that milligram quantities of mercury can be analyzed mass spectroscopically to determine the .sup.196 Hg concentration to less than 0.02 atomic percent. Using natural mercury as a standard, accuracy of .+-.0.002 atomic percent can be obtained. The mass spectrometer preferably used is a commercially available GC/MS manufactured by Hewlett Packard. A novel sample manifold is contained within an oven allowing flow rate control of Hg into the MS. Another part of the manifold connects to an auxiliary pumping system which facilitates rapid clean up of residual Hg in the manifold. Sample cycle time is about 1 hour.

  20. Soil and Water Science Department University of Florida Background concentrations of trace metals in Florida surface soils

    E-Print Network [OSTI]

    Ma, Lena

    using Teflon pressure bombs in a microwave digestion oven and analyzed using a graphite furnace atomic absorption spectrometer (GFAAS), an inductively coupled plasma-mass spectrometer (ICP/MS) and an inductively

  1. Development of A Cryogenic Drift Cell Spectrometer and Methods for Improving the Analytical Figures of Merit for Ion Mobility-Mass Spectrometry Analysis 

    E-Print Network [OSTI]

    May, Jody C.

    2010-10-12T23:59:59.000Z

    A cryogenic (325-80 K) ion mobility-mass spectrometer was designed and constructed in order to improve the analytical figures-of-merit for the chemical analysis of small mass analytes using ion mobility-mass spectrometry. ...

  2. Method for calibrating a Fourier transform ion cyclotron resonance mass spectrometer

    DOE Patents [OSTI]

    Smith, Richard D.; Masselon, Christophe D.; Tolmachev, Aleksey

    2003-08-19T23:59:59.000Z

    A method for improving the calibration of a Fourier transform ion cyclotron resonance mass spectrometer wherein the frequency spectrum of a sample has been measured and the frequency (f) and intensity (I) of at least three species having known mass to charge (m/z) ratios and one specie having an unknown (m/z) ratio have been identified. The method uses the known (m/z) ratios, frequencies, and intensities at least three species to calculate coefficients A, B, and C, wherein the mass to charge ratio of a least one of the three species (m/z).sub.i is equal to ##EQU1## wherein f.sub.i is the detected frequency of the specie, G(I.sub.i) is a predetermined function of the intensity of the species, and Q is a predetermined exponent. Using the calculated values for A, B, and C, the mass to charge ratio of the unknown specie (m/z).sub.ii is calculated as the sum of ##EQU2## wherein f.sub.ii is the measured frequency of the unknown specie, and (I.sub.ii) is the measured intensity of the unknown specie.

  3. A Design for a Compact Time-of-Flight Mass Spectrometer

    SciTech Connect (OSTI)

    Manard, M.

    2012-10-01T23:59:59.000Z

    The design of a prototype, compact time-of-flight (TOF) mass spectrometer (MS) is described. The system primarily consists of an ion acceleration/focusing/steering assembly (AFSA), an 8 cm field-free region, a 4 cm, dual-stage reflectron and a miniature microchannel plate detector. Consequently, the resulting flight length of the system is 12 cm. The system has been designed with the capability to sample directly from atmosphere at ambient pressures. This is accomplished through the use of an electrodynamic ion funnel, housed in an intermediate-vacuum chamber that is coupled to the inlet of the TOF chamber. TOF spectra were obtained using noble gases (Ar, Kr and Xe) as test chemicals. These measured flight times were used to probe the performance of the instrument. A temporal resolution (tflight/?t) of approximately 125, acquired using 129Xe+, has been measured for the system.

  4. Invited Article: Characterization of background sources in space-based time-of-flight mass spectrometers

    SciTech Connect (OSTI)

    Gilbert, J. A.; Gershman, D. J.; Gloeckler, G.; Lundgren, R. A.; Zurbuchen, T. H. [Department of Atmospheric, Oceanic and Space Sciences, University of Michigan, 2455 Hayward St, Ann Arbor, Michigan 48109 (United States); Orlando, T. M.; McLain, J. [Georgia Institute of Technology, 225 North Ave NW, Atlanta, Georgia 30332 (United States); Steiger, R. von [International Space Science Institute, Hallerstrasse 6, CH-3012 Bern, Switzerland and Physikalisches Institut, Universität Bern, Sidlerstrasse 5, CH-3012 Bern (Switzerland)

    2014-09-15T23:59:59.000Z

    For instruments that use time-of-flight techniques to measure space plasma, there are common sources of background signals that evidence themselves in the data. The background from these sources may increase the complexity of data analysis and reduce the signal-to-noise response of the instrument, thereby diminishing the science value or usefulness of the data. This paper reviews several sources of background commonly found in time-of-flight mass spectrometers and illustrates their effect in actual data using examples from ACE-SWICS and MESSENGER-FIPS. Sources include penetrating particles and radiation, UV photons, energy straggling and angular scattering, electron stimulated desorption of ions, ion-induced electron emission, accidental coincidence events, and noise signatures from instrument electronics. Data signatures of these sources are shown, as well as mitigation strategies and design considerations for future instruments.

  5. Multi-Collector Inductively Coupled Plasma Mass Spectrometer – Operational Performance Report

    SciTech Connect (OSTI)

    Matthew Watrous; Anthony Appelhans; Robert Hague; John Olson; Tracy Houghton

    2013-06-01T23:59:59.000Z

    The INL made an assessment of the commercially available inductively coupled plasma mass spectrometers (ICPMS) for actinide analysis; emphasizing low detection limits for plutonium. INL scientists subsequently determined if plutonium was present on a swipe, at a 10 million atom decision level. This report describes the evaluation of ICPMS instruments and the operational testing of a new process for the dissolution, separation and analysis via ICPMS of swipes for plutonium and uranium. The swipe dissolution, plutonium and uranium isolation, separation and purification are wet chemistry methods following established procedures. The ICPMS is a commercially available multi-collector magnetic sector mass spectrometer that utilizes five ion counting detectors operating simultaneously. The instrument includes a sample introduction system allowing for sample volumes of < 1 mL to be reproducibly injected into the instrument with minimal waste of the sample solution, while maximizing the useable signal. The performance of the instrument was measured using SRM 996 (244Pu spike) at concentrations of 12 parts per quadrillion (ppq, fg/mL) and with SRM 4350B Columbia River Sediment samples spiked onto swipes at the 10 million atom level. The measured limit of detection (LOD, defined as 3s) for 239Pu is 310,000 atoms based upon the instrument blank data. The limit of quantification (LOQ defined as 10 s) for 239Pu is 105,000 atoms. The measured limit of detection for 239Pu from the SRM 4350B spiked onto a swipe was 2.7 million atoms with the limit of quantification being 9.0 million atoms.

  6. Atmospheric pressure flow reactor / aerosol mass spectrometer studies of tropospheric aerosol nucleat and growth kinetics. Final report, June, 2001

    SciTech Connect (OSTI)

    Worsnop, Douglas R.

    2001-06-01T23:59:59.000Z

    The objective of this program was to determine the mechanisms and rates of growth and transformation and growth processes that control secondary aerosol particles in both the clear and polluted troposphere. The experimental plan coupled an aerosol mass spectrometer (AMS) with a chemical ionization mass spectrometer to provide simultaneous measurement of condensed and particle phases. The first task investigated the kinetics of tropospheric particle growth and transformation by measuring vapor accretion to particles (uptake coefficients, including mass accommodation coefficients and heterogeneous reaction rate coefficients). Other work initiated investigation of aerosol nucleation processes by monitoring the appearance of submicron particles with the AMS as a function of precursor gas concentrations. Three projects were investigated during the program: (1) Ozonolysis of oleic acid aerosols as model of chemical reactivity of secondary organic aerosol; (2) Activation of soot particles by measurement deliquescence in the presence of sulfuric acid and water vapor; (3) Controlled nucleation and growth of sulfuric acid aerosols.

  7. Application of laser ablation-ICP-mass spectrometry for 2-dimensional mapping of element distributions in a

    E-Print Network [OSTI]

    Claeys, Philippe

    Application of laser ablation-ICP-mass spectrometry for 2-dimensional mapping of element McDonald,d Scott W. Hassler,ce Philippe Claeysb and Frank Vanhaecke*a Laser ablation spherules, were acquired by LA-ICP-MS using two different ablation ­ standard (circular) and teardrop

  8. Toward a Fieldable Atomic Mass Spectrometer for Safeguards Applications: Sample Preparation and Ionization

    SciTech Connect (OSTI)

    Barinaga, Charles J.; Hager, George J.; Hart, Garret L.; Koppenaal, David W.; Marcus, R. Kenneth; Jones, Sarah MH; Manard, Benjamin T.

    2014-10-31T23:59:59.000Z

    The International Atomic Energy Agency’s (IAEA’s) long-term research and development plan calls for the development of new methods to detect misuse at nuclear fuel cycle facilities such as reprocessing and enrichment plants. At enrichment plants, for example, the IAEA’s contemporary safeguards approaches are based on a combination of routine and random inspections that include collection of UF6 samples from in-process material and selected cylinders for subsequent analyses. These analyses include destructive analysis (DA) in a laboratory (typically by mass spectrometry [MS]) for isotopic characterization, and environmental sampling (ES) for subsequent laboratory elemental and isotopic analysis (also both typically by MS). One area of new method development includes moving this kind of isotope ratio analytical capability for DA and ES activities into the field. Some of the reasons for these developments include timeliness of results, avoidance of hazardous material shipments, and guidance for additional sample collecting. However, this capability does not already exist for several reasons, such as that most lab-based chemical and instrumental methods rely on laboratory infrastructure (highly trained staff, power, space, hazardous material handling, etc.) and require significant amounts of consumables (power, compressed gases, etc.). In addition, there are no currently available, fieldable instruments for atomic or isotope ratio analysis. To address these issues, Pacific Northwest National Laboratory (PNNL) and collaborator, Clemson University, are studying key areas that limit the fieldability of isotope ratio mass spectrometry for atomic ions: sample preparation and ionization, and reducing the physical size of a fieldable mass spectrometer. PNNL is seeking simple and robust techniques that could be effectively used by inspectors who may have no expertise in analytical MS. In this report, we present and describe the preliminary findings for three candidate techniques: matrix-assisted laser desorption/ionization (MALDI) MS, liquid sampling-atmospheric pressure glow discharge (LS-APGD), and laser ablation/ionization (LAI) MS at atmospheric pressure. Potential performance metrics for these techniques will be presented, including detectability, response, isotope ratio accuracy and precision, and ease of use.

  9. Atmospheric Amines and Ammonia Measured with a Chemical Ionization Mass Spectrometer (CIMS)

    SciTech Connect (OSTI)

    You, Y.; Kanawade, V. P.; de Gouw, J. A.; Guenther, Alex B.; Madronich, Sasha; Sierra-Hernandez, M. R.; Lawler, M.; Smith, James N.; Takahama, S.; Ruggeri, G.; Koss, A.; Olson, K.; Baumann, K.; Weber, R. J.; Nenes, A.; Guo, H.; Edgerton, Eric S.; Porcelli, L.; Brune, W. H.; Goldstein, Allen H.; Lee, S.-H

    2014-11-19T23:59:59.000Z

    We report ambient measurements of amines and ammonia with a fast response chemical ionization mass spectrometer (CIMS) in a Southeastern U.S. forest in Alabama and a moderately polluted Midwestern site during the summer. In the Alabama forest, mostly C3-amines (from pptv to tens of pptv) and ammonia (up to 2 ppbv) were detected on a daily basis. C3-amines and ammonia showed similar diurnal trends and temperature and wind direction dependences, and were not associated with transported CO and SO2 plumes. Consistent with temperature dependences, amine and ammonia in the gas and aerosol phases showed opposite diurnal trends, indicating gas-to-particle partitioning of amines and ammonia. Temperature dependences also imply reversible processes of amines and ammonia evaporation from soil surfaces in daytime and deposition of amines and ammonia to soil surfaces at nighttime. Various amines (C1-C6) at the pptv level were observed in the transported biomass burning plumes, showing that biomass burning can be a substantial source of amines in the Southeast U.S. At the moderately polluted Kent site, higher concentrations of amines (C1-C6, from pptv to tens of pptv) and ammonia (up to 6 ppbv) were detected. Diurnal variations of C1- to C3-amines and ammonia were correlated with the ambient temperature. C4- to C6-amines showed abrupt increases during the nighttime, suggesting that they were emitted from local sources. These abundant amines and ammonia may in part explain the frequent new particle formation events reported from Kent. Lower amine concentrations at the rural forested site highlight the importance of constraining anthropogenic sources of amines.

  10. Development of Soft Ionization for Particulate Organic Detection with the Aerodyne Aerosol Mass Spectrometer

    SciTech Connect (OSTI)

    Trimborn, A; Williams, L R; Jayne, J T; Worsnop, D R

    2008-06-19T23:59:59.000Z

    During this DOE SBIR Phase II project, we have successfully developed several soft ionization techniques, i.e., ionization schemes which involve less fragmentation of the ions, for use with the Aerodyne time-of-flight aerosol mass spectrometer (ToF-AMS). Vacuum ultraviolet single photon ionization was demonstrated in the laboratory and deployed in field campaigns. Vacuum ultraviolet single photon ionization allows better identification of organic species in aerosol particles as shown in laboratory experiments on single component particles, and in field measurements on complex multi-component particles. Dissociative electron attachment with lower energy electrons (less than 30 eV) was demonstrated in the measurement of particulate organics in chamber experiments in Switzerland, and is now a routine approach with AMS systems configured for bipolar, negative ion detection. This technique is particularly powerful for detection of acidic and other highly oxygenated secondary organic aerosol (SOA) chemical functionality. Low energy electron ionization (10 to 12 eV) is also a softer ionization approach routinely available to AMS users. Finally, Lithium ion attachment has been shown to be sensitive to more alkyl-like chemical functionality in SOA. Results from Mexico City are particularly exciting in observing changes in SOA molecular composition under different photochemical/meteorological conditions. More recent results detecting biomass burns at the Montana fire lab have demonstrated quantitative and selective detection of levoglucosan. These soft ionization techniques provide the ToF-AMS with better capability for identifying organic species in ambient atmospheric aerosol particles. This, in turn, will allow more detailed study of the sources, transformations and fate of organic-containing aerosol.

  11. Facilities: NHMFL 14.5 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation: A Pseudoatomic Model of the COPII Cage Obtained from Cryo-Electron Microscopy and Mass Spectrometry,

    E-Print Network [OSTI]

    Weston, Ken

    Facilities: NHMFL 14.5 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation ultrahigh-resolution 14.5 tesla Fourier transform ion cyclotron resonance mass spectrometry. The Mag

  12. RAPID DETERMINATION OF 237 NP AND PU ISOTOPES IN WATER BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY AND ALPHA SPECTROMETRY

    SciTech Connect (OSTI)

    Maxwell, S.; Jones, V.; Culligan, B.; Nichols, S.; Noyes, G.

    2010-06-23T23:59:59.000Z

    A new method that allows rapid preconcentration and separation of plutonium and neptunium in water samples was developed for the measurement of {sup 237}Np and Pu isotopes by inductively-coupled plasma mass spectrometry (ICP-MS) and alpha spectrometry; a hybrid approach. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via peak tailing. The method provide enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then moving Pu to DGA resin for additional removal of uranium. The decontamination factor for uranium from Pu is almost 100,000 and the decontamination factor for U from Np is greater than 10,000. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration is performed using a streamlined calcium phosphate precipitation method. Purified solutions are split between ICP-MS and alpha spectrometry so that long and short-lived Pu isotopes can be measured successfully. The method allows for simultaneous extraction of 20 samples (including QC samples) in 4 to 6 hours, and can also be used for emergency response. {sup 239}Pu, {sup 242}Pu and {sup 237}Np were measured by ICP-MS, while {sup 236}Pu, {sup 238}Pu, and {sup 239}Pu were measured by alpha spectrometry.

  13. DETERMINATION OF 237NP AND PU ISOTOPES IN LARGE SOIL SAMPLES BY INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY

    SciTech Connect (OSTI)

    Maxwell, S.

    2010-07-26T23:59:59.000Z

    A new method for the determination of {sup 237}Np and Pu isotopes in large soil samples has been developed that provides enhanced uranium removal to facilitate assay by inductively coupled plasma mass spectrometry (ICP-MS). This method allows rapid preconcentration and separation of plutonium and neptunium in large soil samples for the measurement of {sup 237}Np and Pu isotopes by ICP-MS. {sup 238}U can interfere with {sup 239}Pu measurement by ICP-MS as {sup 238}UH{sup +} mass overlap and {sup 237}Np via {sup 238}U peak tailing. The method provides enhanced removal of uranium by separating Pu and Np initially on TEVA Resin, then transferring Pu to DGA resin for additional purification. The decontamination factor for removal of uranium from plutonium for this method is greater than 1 x 10{sup 6}. Alpha spectrometry can also be applied so that the shorter-lived {sup 238}Pu isotope can be measured successfully. {sup 239}Pu, {sup 242}Pu and {sup 237}Np were measured by ICP-MS, while {sup 236}Pu and {sup 238}Pu were measured by alpha spectrometry.

  14. The geochemical analysis of minerals and geologi-cal glasses relies on well characterised reference

    E-Print Network [OSTI]

    Zack, Thomas

    -mass spectrometry (MC-ICP-MS), laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) and secondary de masse à plasma inductif et ablation laser (LA-ICP-MS) et spectrométrie de masse à ionisation

  15. Inductively coupled plasma mass spectrometry for stable isotope metabolic tracer studies of living systems

    SciTech Connect (OSTI)

    Luong, E.

    1999-05-10T23:59:59.000Z

    This dissertation focuses on the development of methods for stable isotope metabolic tracer studies in living systems using inductively coupled plasma single and dual quadrupole mass spectrometers. Sub-nanogram per gram levels of molybdenum (Mo) from human blood plasma are isolated by the use of anion exchange alumina microcolumns. Million-fold more concentrated spectral and matrix interferences such as sodium, chloride, sulfate, phosphate, etc. in the blood constituents are removed from the analyte. The recovery of Mo from the alumina column is 82 {+-} 5% (n = 5). Isotope dilution inductively coupled plasma mass spectrometry (ID-ICP-MS) is utilized for the quantitative ultra-trace concentration determination of Mo in bovine and human blood samples. The average Mo concentration in reference bovine serum determined by this method is 10.2 {+-} 0.4 ng/g, while the certified value is 11.5 {+-} 1.1 ng/g (95% confidence interval). The Mo concentration of one pool of human blood plasma from two healthy male donors is 0.5 {+-} 0.1 ng/g. The inductively coupled plasma twin quadrupole mass spectrometer (ICP-TQMS) is used to measure the carbon isotope ratio from non-volatile organic compounds and bio-organic molecules to assess the ability as an alternative analytical method to gas chromatography combustion isotope ratio mass spectrometry (GC-combustion-IRMS). Trytophan, myoglobin, and {beta}-cyclodextrin are chosen for the study, initial observation of spectral interference of {sup 13}C{sup +} with {sup 12}C{sup 1}H{sup +} comes from the incomplete dissociation of myoglobin and/or {beta}-cyclodextrin.

  16. Studies of the mechanism of the cluster formation in a thermally sampling atmospheric pressure ionization mass spectrometer

    SciTech Connect (OSTI)

    Albrecht, Sascha, E-mail: s.albrecht@fz-juelich.de; Stroh, Fred, E-mail: f.stroh@fz-juelich.de [Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Stratosphere (IEK-7), 52428 Jülich (Germany)] [Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Stratosphere (IEK-7), 52428 Jülich (Germany); Klopotowski, Sebastian, E-mail: s.klopotowski@uni-wuppertal.de; Derpmann, Valerie, E-mail: v.derpmann@uni-wuppertal.de; Klee, Sonja, E-mail: s.klee@uni-wuppertal.de; Brockmann, Klaus J., E-mail: brockma@uni-wuppertal.de; Benter, Thorsten, E-mail: tbenter@uni-wuppertal.de [Physical and Theoretical Chemistry, Institute for Pure and Applied Mass Spectrometry, University of Wuppertal, 42097 Wuppertal (Germany)] [Physical and Theoretical Chemistry, Institute for Pure and Applied Mass Spectrometry, University of Wuppertal, 42097 Wuppertal (Germany)

    2014-01-15T23:59:59.000Z

    In this study a thermally sampling atmospheric pressure ionization mass spectrometer is described and characterized. The ion transfer stage offers the capability to sample cluster ions at thermal equilibrium and during this transfer fundamental processes possibly affecting the cluster distribution are also readily identified. Additionally, the transfer stage combines optional collision-induced dissociation (CID) analysis of the cluster composition with thermal equilibrium sampling of clusters. The performance of the setup is demonstrated with regard to the proton-bound water cluster system. The benefit of the studied processes is that they can help to improve future transfer stages and to understand cluster ion reactions in ion mobility tubes and high-pressure ion sources. In addition, the instrument allows for the identification of fragmentation and protonation reactions caused by CID.

  17. Combined distance-of-flight and time-of-flight mass spectrometer

    DOE Patents [OSTI]

    Enke, Christie G; Ray, Steven J; Graham, Alexander W; Hieftje, Gary M; Barinaga, Charles J; Koppenaal, David W

    2014-02-11T23:59:59.000Z

    A combined distance-of-flight mass spectrometry (DOFMS) and time-of-flight mass spectrometry (TOFMS) instrument includes an ion source configured to produce ions having varying mass-to-charge ratios, a first detector configured to determine when each of the ions travels a predetermined distance, a second detector configured to determine how far each of the ions travels in a predetermined time, and a detector extraction region operable to direct portions of the ions either to the first detector or to the second detector.

  18. Standard test method for isotopic analysis of uranium hexafluoride by double standard single-collector gas mass spectrometer method

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2010-01-01T23:59:59.000Z

    1.1 This is a quantitative test method applicable to determining the mass percent of uranium isotopes in uranium hexafluoride (UF6) samples with 235U concentrations between 0.1 and 5.0 mass %. 1.2 This test method may be applicable for the entire range of 235U concentrations for which adequate standards are available. 1.3 This test method is for analysis by a gas magnetic sector mass spectrometer with a single collector using interpolation to determine the isotopic concentration of an unknown sample between two characterized UF6 standards. 1.4 This test method is to replace the existing test method currently published in Test Methods C761 and is used in the nuclear fuel cycle for UF6 isotopic analyses. 1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appro...

  19. Investigations into the origins of polyatomic ions in inductively coupled plasma-mass spectrometry

    SciTech Connect (OSTI)

    McIntyre, Sally M.

    2010-05-16T23:59:59.000Z

    An inductively coupled plasma-mass spectrometer (ICP-MS) is an elemental analytical instrument capable of determining nearly all elements in the periodic table at limits of detection in the parts per quadrillion and with a linear analytical range over 8-10 orders of magnitude. Three concentric quartz tubes make up the plasma torch. Argon gas is spiraled through the outer tube and generates the plasma powered by a looped load coil operating at 27.1 or 40.6 MHz. The argon flow of the middle channel is used to keep the plasma above the innermost tube through which solid or aqueous sample is carried in a third argon stream. A sample is progressively desolvated, atomized and ionized. The torch is operated at atmospheric pressure. To reach the reduced pressures of mass spectrometers, ions are extracted through a series of two, approximately one millimeter wide, circular apertures set in water cooled metal cones. The space between the cones is evacuated to approximately one torr. The space behind the second cone is pumped down to, or near to, the pressure needed for the mass spectrometer (MS). The first cone, called the sampler, is placed directly in the plasma plume and its position is adjusted to the point where atomic ions are most abundant. The hot plasma gas expands through the sampler orifice and in this expansion is placed the second cone, called the skimmer. After the skimmer traditional MS designs are employed, i.e. quadrupoles, magnetic sectors, time-of-flight. ICP-MS is the leading trace element analysis technique. One of its weaknesses are polyatomic ions. This dissertation has added to the fundamental understanding of some of these polyatomic ions, their origins and behavior. Although mainly continuing the work of others, certain novel approaches have been introduced here. Chapter 2 includes the first reported efforts to include high temperature corrections to the partition functions of the polyatomic ions in ICP-MS. This and other objections to preceeding papers in this area were addressed. Errors in the measured T{sub gas} values were found for given errors in the experimental and spectroscopic values. The ionization energy of the neutral polyatomic ion was included in calculations to prove the validity of ignoring more complicated equilibria. Work was begun on the question of agreement between kinetics of the plasma and interface and the increase and depletion seen in certain polyatomic ions. This dissertation was also the first to report day to day ranges for T{sub gas} values and to use a statistical test to compare different operating conditions. This will help guide comparisons of previous and future work. Chapter 4 was the first attempt to include the excited electronic state 2 in the partition function of ArO{sup +} as well as the first to address the different dissociation products of the ground and first electronic levels of ArO{sup +}. Chapter 5 reports an interesting source of memory in ICP-MS that could affect mathematical corrections for polyatomic ions. For future work on these topics I suggest the following experiments and investigations. Clearly not an extensive list, they are instead the first topics curiosity brings to mind. (1) Measurement of T{sub gas} values when using the flow injection technique of Appendix B. It was believed that there was a fundamental difference in the plasma when the auto-sampler was used versus a continuous injection. Is this reflected in T{sub gas} values? (2) The work of Chapter 3 can be expanded and supplemented with more trials, new cone materials (i.e. copper, stainless steel) and more cone geometries. Some of this equipment is already present in the laboratory, others could be purchased or made. (3) T{sub gas} values from Chapter 3 could be correlated with instrument pressures during the experiment. Pressures after the skimmer cone were recorded for many days but have yet to be collated with the measured T{sub gas} values. (4) The work in Chapter 5 could be expanded to include more metals. Does the curious correlation between measured T{sub gas} and element boili

  20. Multiple-ion-beam time-of-flight mass spectrometer Andreas Rohrbacher and Robert E. Continettia)

    E-Print Network [OSTI]

    Continetti, Robert E.

    /ionization and the molecular ions of two different proteins myoglobin and lysozyme , created by matrix assisted laser,7 and matrix assisted desorption and ionization MALDI 8­11 have become avail- able to allow the mass the samples with a robot- driven capillary,15 a scanning ion beam,16 or spatial resolu- tion was achieved

  1. Automatic Identification of Proteins with a MALDI-Quadrupole Ion Trap Mass Spectrometer

    E-Print Network [OSTI]

    Chait, Brian T.

    the sample with relatively high energy- density laser pulsessthe practical result is that is often, automatic identification of proteins. A mass spectrometry-based method can satisfy this need if it (1) produces high-quality MS and MS/MS data; (2) has femtomole sensitivity; (3) is fast, i.e., collects spectra

  2. Novel endothermic and exothermic ion-molecule reactions as observed in a Fourier transform mass spectrometer

    E-Print Network [OSTI]

    Bricker, Donald Lee

    1986-01-01T23:59:59.000Z

    is the electric field strength in. v/m and t ~ 2rB/E (6) B is the magnetic field strength in tesla. 6 The standard FTICR trap cell developed by McIver is a one 7 region cell consisting of six flat plates arranged in a rectangular geometry. A positive... q is the charge on the KE = q r B /2m (7) 2 2 2 ion, r is the radius of the trap cell in meters, B is the magnetic field strength in tesla and m is the mass of the ion in kilograms. therefore an ion of m/z 100 in a 1. 9 tesla magnetic field...

  3. Arsenic speciation in soil using high performance liquid chromatography/inductively coupled plasma/mass spectrometry

    SciTech Connect (OSTI)

    Bass, D.A.; Yaeger, J.S.; Parish, K.J.; Crain, J.S.; Kiely, J.T.; Gowdy, M.J. [Argonne National Lab., IL (United States); Mohrman, G.B.; Besmer, M.G. [Rocky Mountain Arsenal, Commerce City, CO (United States)

    1996-08-01T23:59:59.000Z

    A method has been developed to identify and quantify As(III), As(V), and organoarsenic compounds in soil samples from the Rocky Mountain Arsenal (RMA) by high performance liquid chromatography/inductively coupled plasma/mass spectrometry (HPLC/ICP/MS). The soils were extracted using tetrabutylammonium hydroxide (TBAH) and sonication. The percentages of As(III), As(V), and organoarsenic species extracted from soil samples were 30, 50, and 100 respectively. The arsenic species were not altered during the extraction process. They were separated by reversed-phase, ion-pairing, HPLC using a microbore Inertsil-ODS{trademark} column. The HPLC column effluent was introduced into an ICP/MS system using a direct injection nebulizer (DIN). Detection limits of less than 1 pg were readily obtained for each arsenic species. Internal standards are recommended to increase accuracy and precision. Soil samples spiked with arsenic oxide, sodium arsenate, dimethylarsinic acid (DMAA), and chlorovinyl arsenious acid (CVAA) were extracted, identified and quantified with the HPLC/ICP/MS system. The soil samples were analyzed in support of the analytical needs of a thermal desorption treatability study being conducted at the RMA.

  4. Mass Spectrometer | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of strong brown carbon chromophores. Citation: Laskin J, A Laskin, S Nizkorodov, PJ Roach, PA Eckert, MK Gilles, B Wang, HJ Lee, and Q Hu.2014."Molecular Selectivity of Brown...

  5. Mass Spectrometer: Orbitrap | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    time dependent changes in the degree of nitration and oxidation of... Clinical Microfluidics for Neutrophil Genomics and Proteomics. Neutrophils play critical roles in...

  6. Monolithic spectrometer

    DOE Patents [OSTI]

    Rajic, S.; Egert, C.M.; Kahl, W.K.; Snyder, W.B. Jr.; Evans, B.M. III; Marlar, T.A.; Cunningham, J.P.

    1998-05-19T23:59:59.000Z

    A monolithic spectrometer is disclosed for use in spectroscopy. The spectrometer is a single body of translucent material with positioned surfaces for the transmission, reflection and spectral analysis of light rays. 6 figs.

  7. Monolithic spectrometer

    DOE Patents [OSTI]

    Rajic, Slobodan (Knoxville, TN); Egert, Charles M. (Oak Ridge, TN); Kahl, William K. (Knoxville, TN); Snyder, Jr., William B. (Knoxville, TN); Evans, III, Boyd M. (Oak Ridge, TN); Marlar, Troy A. (Knoxville, TN); Cunningham, Joseph P. (Oak Ridge, TN)

    1998-01-01T23:59:59.000Z

    A monolithic spectrometer is disclosed for use in spectroscopy. The spectrometer is a single body of translucent material with positioned surfaces for the transmission, reflection and spectral analysis of light rays.

  8. Development and implementation of a FT-ICR mass spectrometer for the investigation of ion conformations of peptide sequence isomers containing basic amino acid residues by gas-phase hydrogen/deuterium exchange 

    E-Print Network [OSTI]

    Marini, Joseph Thomas

    2004-09-30T23:59:59.000Z

    The gas-phase hydrogen/deuterium (H/D) exchange of protonated di- and tripeptides containing a basic amino acid residue has been studied with a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Bimolecular reactions...

  9. Development and implementation of a FT-ICR mass spectrometer for the investigation of ion conformations of peptide sequence isomers containing basic amino acid residues by gas-phase hydrogen/deuterium exchange

    E-Print Network [OSTI]

    Marini, Joseph Thomas

    2004-09-30T23:59:59.000Z

    The gas-phase hydrogen/deuterium (H/D) exchange of protonated di- and tripeptides containing a basic amino acid residue has been studied with a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Bimolecular reactions...

  10. 551IEEE TRANSACTIONSON GEOSCIENCE AND REMOTE SENSING, VOL. 31, NO. 3, MAY 1993 MAST: A Mass Spectrometer Telescope for

    E-Print Network [OSTI]

    Goddard III, William A.

    Spectrometer Telescope for M4 D1 D2 D3 D4 D5 D6 - I , Studies of the Isotopic Composition of Solar, Anomalous, and Galactic Cosmic Ray Nuclei W. R. Cook, A. C. Cummings, J. R. Cummings, T. L. Garrard, B. Kecman, R. AV/nuc. During large solar flares MAST will measure the iso- topic abundancesof solar energeticparticlesto

  11. Correlation spectrometer

    DOE Patents [OSTI]

    Sinclair, Michael B. (Albuquerque, NM); Pfeifer, Kent B. (Los Lunas, NM); Flemming, Jeb H. (Albuquerque, NM); Jones, Gary D. (Tijeras, NM); Tigges, Chris P. (Albuquerque, NM)

    2010-04-13T23:59:59.000Z

    A correlation spectrometer can detect a large number of gaseous compounds, or chemical species, with a species-specific mask wheel. In this mode, the spectrometer is optimized for the direct measurement of individual target compounds. Additionally, the spectrometer can measure the transmission spectrum from a given sample of gas. In this mode, infrared light is passed through a gas sample and the infrared transmission signature of the gasses present is recorded and measured using Hadamard encoding techniques. The spectrometer can detect the transmission or emission spectra in any system where multiple species are present in a generally known volume.

  12. Multidimensional spectrometer

    DOE Patents [OSTI]

    Zanni, Martin Thomas (Madison, WI); Damrauer, Niels H. (Boulder, CO)

    2010-07-20T23:59:59.000Z

    A multidimensional spectrometer for the infrared, visible, and ultraviolet regions of the electromagnetic spectrum, and a method for making multidimensional spectroscopic measurements in the infrared, visible, and ultraviolet regions of the electromagnetic spectrum. The multidimensional spectrometer facilitates measurements of inter- and intra-molecular interactions.

  13. Facilities: NHMFL 9.4 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation: Characterization of Pine Pellet and Peanut Hull Pyrolysis of Bio-Oils by Negative-Ion Electrospray Ionization Fourier

    E-Print Network [OSTI]

    Weston, Ken

    Facilities: NHMFL 9.4 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation Fourier Transform Ion Cyclotron Resonance Mass Spectrometry, Jacqueline M. Jarvis, Amy M. McKenna, Roger N and aqueous phases. Here, each phase is characterized by negative-ion electrospray ionization Fourier

  14. RAPID DETERMINATION OF ACTINIDES IN URINE BY INDUCTIVELY-COUPLED PLASMA MASS SPECTROMETRY AND ALPHA SPECTROMETRY: A HYBRID APPROACH

    SciTech Connect (OSTI)

    Maxwell, S.; Jones, V.

    2009-05-27T23:59:59.000Z

    A new rapid separation method that allows separation and preconcentration of actinides in urine samples was developed for the measurement of longer lived actinides by inductively coupled plasma mass spectrometry (ICP-MS) and short-lived actinides by alpha spectrometry; a hybrid approach. This method uses stacked extraction chromatography cartridges and vacuum box technology to facilitate rapid separations. Preconcentration, if required, is performed using a streamlined calcium phosphate precipitation. Similar technology has been applied to separate actinides prior to measurement by alpha spectrometry, but this new method has been developed with elution reagents now compatible with ICP-MS as well. Purified solutions are split between ICP-MS and alpha spectrometry so that long- and short-lived actinide isotopes can be measured successfully. The method allows for simultaneous extraction of 24 samples (including QC samples) in less than 3 h. Simultaneous sample preparation can offer significant time savings over sequential sample preparation. For example, sequential sample preparation of 24 samples taking just 15 min each requires 6 h to complete. The simplicity and speed of this new method makes it attractive for radiological emergency response. If preconcentration is applied, the method is applicable to larger sample aliquots for occupational exposures as well. The chemical recoveries are typically greater than 90%, in contrast to other reported methods using flow injection separation techniques for urine samples where plutonium yields were 70-80%. This method allows measurement of both long-lived and short-lived actinide isotopes. 239Pu, 242Pu, 237Np, 243Am, 234U, 235U and 238U were measured by ICP-MS, while 236Pu, 238Pu, 239Pu, 241Am, 243Am and 244Cm were measured by alpha spectrometry. The method can also be adapted so that the separation of uranium isotopes for assay is not required, if uranium assay by direct dilution of the urine sample is preferred instead. Multiple vacuum box locations may be set-up to supply several ICP-MS units with purified sample fractions such that a high sample throughput may be achieved, while still allowing for rapid measurement of short-lived actinides by alpha spectrometry.

  15. Standard test method for determination of uranium or plutonium isotopic composition or concentration by the total evaporation method using a thermal ionization mass spectrometer

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2007-01-01T23:59:59.000Z

    1.1 This method describes the determination of the isotopic composition and/or the concentration of uranium and plutonium as nitrate solutions by the thermal ionization mass spectrometric (TIMS) total evaporation method. Purified uranium or plutonium nitrate solutions are loaded onto a degassed metal filament and placed in the mass spectrometer. Under computer control, ion currents are generated by heating of the filament(s). The ion beams are continually measured until the sample is exhausted. The measured ion currents are integrated over the course of the run, and normalized to a reference isotope ion current to yield isotopic ratios. 1.2 In principle, the total evaporation method should yield isotopic ratios that do not require mass bias correction. In practice, some samples may require this bias correction. When compared to the conventional TIMS method, the total evaporation method is approximately two times faster, improves precision from two to four fold, and utilizes smaller sample sizes. 1.3 The tot...

  16. "No Ions" Troubleshooting Strategy ELEMENT ICP-MS

    E-Print Network [OSTI]

    Lee, Cin-Ty Aeolus

    -trace users often forget that there is an Analog Detector Mode and they fail to test for ion transmission.g. loss of contact or GE relay failure) will cause a significant loss of ion transmission since the energy DIAGNOSTICS/Statusbit INLET to switch "Valve 12" on and off. If GE relay works correctly then this should gr

  17. Spectrometer gun

    DOE Patents [OSTI]

    Waechter, D.A.; Wolf, M.A.; Umbarger, C.J.

    1981-11-03T23:59:59.000Z

    A hand-holdable, battery-operated, microprocessor-based spectrometer gun is described that includes a low-power matrix display and sufficient memory to permit both real-time observation and extended analysis of detected radiation pulses. Universality of the incorporated signal processing circuitry permits operation with various detectors having differing pulse detection and sensitivity parameters.

  18. Spectrometer gun

    DOE Patents [OSTI]

    Waechter, David A. (Los Alamos, NM); Wolf, Michael A. (Los Alamos, NM); Umbarger, C. John (Los Alamos, NM)

    1985-01-01T23:59:59.000Z

    A hand-holdable, battery-operated, microprocessor-based spectrometer gun includes a low-power matrix display and sufficient memory to permit both real-time observation and extended analysis of detected radiation pulses. Universality of the incorporated signal processing circuitry permits operation with various detectors having differing pulse detection and sensitivity parameters.

  19. A MODULAR STEADY STATE GLOW DISCHARGE QUADRUPOLE MASS SPECTROMETER SYSTEM FOR THE AT-LINE ANALYSIS OF PLUTONIUM METAL

    SciTech Connect (OSTI)

    R. STEINER; D. WAYNE

    1998-12-01T23:59:59.000Z

    Historically, glow discharge mass and optical spectrometric techniques have been used in industry for the characterization of processed metals, such as steels and other alloys. This technique is especially well suited for this type of product analysis because the glow discharge ionization source accommodates solid conducting samples with minimal or no sample preparation. This characteristic along with minimal matrix effect considerations makes the glow discharge source well suited for these types of applications.

  20. Facilities: NHMFL 9.4 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer Citation: Atmospheric Pressure Laser-Induced Acoustic Desorption Chemical Ionization Mass Spectrometry

    E-Print Network [OSTI]

    Weston, Ken

    . Rodgers, & Alan G. Marshall, Analytical Chemistry 84, 7131-7137 (2012). Figure 1. Schematic diagram hydrocarbons (the primary components of gasoline) are difficult to analyze by mass spectrometry, because

  1. Characterizing the Performance of a Proton-Transfer-Reaction Mass Spectrometer with a Rapid Cycling Tenax Preconcentrator

    SciTech Connect (OSTI)

    Garland, S.P.; Alexander, M.L.

    2006-01-01T23:59:59.000Z

    Volatile organic compounds (VOCs) are species of interest for atmospheric modeling, worker chemical exposure and medical studies. Sometimes the required detection limits for these compounds is below the capability of existing real-time instrumentation. Preconcentrators have been implemented as an inexpensive way to amplify chemical signals and improve detection limits. Proton-transfer-reaction mass spectrometry (PTR-MS) has been used as a tool for studying low concentrations of VOCs, but it lacks the capability to differentiate chemical signal contributions from isobaric compounds. In this work, behavior of a newly designed Tenax TA preconcentrator when coupled with a PTRMS is characterized. This novel preconcentrator design allows rapid temperature cycling, maintaining near real-time response. The preconcentrator was exposed to a sample gas of toluene in varying concentrations and loading times between and then thermally desorbed for analysis by PTR-MS. The effects of preconcentrating multiple analytes simultaneously were also investigated as well as the chromatographic effects of the preconcentrator. A linear behavior was observed when the integrated ion count rates (ICPS) from thermal desorption peaks were regressed against both varying loading times at a constant toluene concentration and varying concentrations with constant loading times. From these trends, it is possible to determine the concentration of a VOC by knowing its ICPS from thermal desorption peaks from a known preconcentration time. Peak height ion count rates representing ultimate detectability were amplified by factors up to 257 times the original signal, extending the range of the PTR-MS from 50pptv to nearly 250 parts per quadrillion. This corresponds to an ultimate sensitivity of 200 parts per quadrillion with 20 minute time resolution. Quantitative preconcentrator behavior was demonstrated using ICPS from these ion peaks and were amplified as much as 148 times their original signal. Results from multi-analyte desorption indicate that chromatographic separation is possible with a Tenax preconcentrator and further details are discussed. The dramatic increased in sensitivity with near real-time response, combined with chromatographic resolving capability opens up new areas of research requiring the detection of ultra-trace organic species using PTR-MS.

  2. Chemical Evolution of Metal in Refractory Inclusions in CV3 ANDREW J. CAMPBELL*,1

    E-Print Network [OSTI]

    Campbell, Andrew

    . Clayton #12;2 Abstract­Laser ablation inductively coupled plasma mass spectrometry (LA-ICP- MS) was used

  3. Origin of kamacite, schreibersite, and perryite in metal-sulfide nodules of the enstatite chondrite Sahara 97072 (EH3)

    E-Print Network [OSTI]

    Mcdonough, William F.

    with laser ablation, inductively coupled plasma mass spectrometry (ICP- MS). We also measured their Fe, Ni, P

  4. FISHERIES DISASTER RELIEF PROGRAM (FDRP) ANNUAL REPORT FOR FY 2007

    E-Print Network [OSTI]

    Hawai'i at Manoa, University of

    , for instrument time on the laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) instrument. During this first LA-ICP-MS analysis run, laser sampling parameters were worked out and duplicate

  5. The "stock" concept is a central tenet of modern fisheries science because it

    E-Print Network [OSTI]

    electron probe microanalysis (EPMA) and laser ablation inductively coupled plasma mass spectrometry (ICP-MS). Ele- ments measured at the nucleus of otoliths by EPMA and laser abla- tion ICP-MS differed

  6. The effect of ultrafast laser wavelength on ablation properties and implications on sample introduction in inductively coupled plasma mass spectrometry

    SciTech Connect (OSTI)

    LaHaye, N. L.; Harilal, S. S.; Diwakar, P. K.; Hassanein, A. [Center for Materials under Extreme Environment, School of Nuclear Engineering Purdue University, West Lafayette, Indiana 47907 (United States); Kulkarni, P. [Centers for Disease Control and Prevention, National Institute of Occupational Safety and Health, Cincinnati, Ohio 45213 (United States)

    2013-07-14T23:59:59.000Z

    We investigated the role of femtosecond (fs) laser wavelength on laser ablation (LA) and its relation to laser generated aerosol counts and particle distribution, inductively coupled plasma-mass spectrometry (ICP-MS) signal intensity, detection limits, and elemental fractionation. Four different NIST standard reference materials (610, 613, 615, and 616) were ablated using 400 nm and 800 nm fs laser pulses to study the effect of wavelength on laser ablation rate, accuracy, precision, and fractionation. Our results show that the detection limits are lower for 400 nm laser excitation than 800 nm laser excitation at lower laser energies but approximately equal at higher energies. Ablation threshold was also found to be lower for 400 nm than 800 nm laser excitation. Particle size distributions are very similar for 400 nm and 800 nm wavelengths; however, they differ significantly in counts at similar laser fluence levels. This study concludes that 400 nm LA is more beneficial for sample introduction in ICP-MS, particularly when lower laser energies are to be used for ablation.

  7. Method of multiplexed analysis using ion mobility spectrometer

    DOE Patents [OSTI]

    Belov, Mikhail E. (Richland, WA); Smith, Richard D. (Richland, WA)

    2009-06-02T23:59:59.000Z

    A method for analyzing analytes from a sample introduced into a Spectrometer by generating a pseudo random sequence of a modulation bins, organizing each modulation bin as a series of submodulation bins, thereby forming an extended pseudo random sequence of submodulation bins, releasing the analytes in a series of analyte packets into a Spectrometer, thereby generating an unknown original ion signal vector, detecting the analytes at a detector, and characterizing the sample using the plurality of analyte signal subvectors. The method is advantageously applied to an Ion Mobility Spectrometer, and an Ion Mobility Spectrometer interfaced with a Time of Flight Mass Spectrometer.

  8. Mobile Ice Nucleus Spectrometer

    SciTech Connect (OSTI)

    Kulkarni, Gourihar R.; Kok, G. L.

    2012-05-07T23:59:59.000Z

    This first year report presents results from a computational fluid dynamics (CFD) study to assess the flow and temperature profiles within the mobile ice nucleus spectrometer.

  9. The Filter Difference Spectrometer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Difference Spectrometer (FDS) is used for molecular vibrational spectroscopy by inelastic neutron scattering. The instrument is designed for high count rates by use of large...

  10. Development and Application of an Electrospray Ionization Ion Mobility-mass Spectrometer Using an RF Ion Funnel and Periodic-focusing Ion Guide

    E-Print Network [OSTI]

    Jeon, Junho

    2013-10-16T23:59:59.000Z

    ion mobility-mass spectrometry (IM-MS). Through experimental measurements and ion trajectory calculations from well known model peptides and proteins having multiple charge states, a correlation factor ? which links the results from the two different...

  11. Development of a MALDI-Ion Mobility-Surface-Induced Dissociation-Time-of-flight-mass spectrometer for the analysis of peptides and proteins

    E-Print Network [OSTI]

    Stone, Earle Gregory

    2004-09-30T23:59:59.000Z

    of approximately 20 and TOF mass resolution better than 200. Peptide sequences of four peptides from a tryptic digest of cytochrome c (ca. 1 pmol deposited) were obtained. The advantage of IM-SID-o-TOFMS is that a single experiment can be used to simultaneously...

  12. Isolation and Puification of Uranium Isotopes for Measurement by Mass-Spectrometry (233, 234, 235, 236, 238U) and Alpha Spectrometry (232U)

    SciTech Connect (OSTI)

    Marinelli, R; Hamilton, T; Brown, T; Marchetti, A; Williams, R; Tumey, S

    2006-05-30T23:59:59.000Z

    This report describes a standardized methodology used by researchers from the Center for Accelerator Mass Spectrometry (CAMS) (Energy and Environment Directorate) and the Environmental Radiochemistry Group (Chemistry and Materials Science Directorate) at the Lawrence Livermore National Laboratory (LLNL) for the full isotopic analysis of uranium from solution. The methodology has largely been developed for use in characterizing the uranium composition of selected nuclear materials but may also be applicable to environmental studies and assessments of public, military or occupational exposures to uranium using in-vitro bioassay monitoring techniques. Uranium isotope concentrations and isotopic ratios are measured using a combination of Multi Collector Inductively Coupled Plasma Mass Spectrometry (MC ICP-MS), Accelerator Mass Spectrometry (AMS) and Alpha Spectrometry.

  13. The Results of Tests of the MICE Spectrometer Solenoids

    SciTech Connect (OSTI)

    Green, Michael A.; Virostek, Steve P.

    2009-10-19T23:59:59.000Z

    The Muon Ionization Cooling Experiment (MICE) spectrometer solenoid magnets will be the first magnets to be installed within the MICE cooling channel. The spectrometer magnets are the largest magnets in both mass and surface area within the MICE ooling channel. Like all of the other magnets in MICE, the spectrometer solenoids are kept cold using 1.5 W (at 4.2 K) pulse tube coolers. The MICE spectrometer solenoid is quite possibly the largest magnet that has been cooled using small coolers. Two pectrometer magnets have been built and tested. This report discusses the results of current and cooler tests of both magnets.

  14. Final Technical Report [Toward Simultaneous Single-Particle Chemical and Optical Characterization: Development of a Multi-Angle Optical Scattering Module for the Aerosol Time-of-Flight Mass Spectrometer

    SciTech Connect (OSTI)

    Buckley, Steven [Photon Machines, Inc.] [Photon Machines, Inc.

    2013-10-22T23:59:59.000Z

    This project was an initial effort to investigate the feasibility of an instrument combining real-time atmospheric particle composition measurements using an ATOFMS (Atmospheric Time-Of-Flight Mass Spectrometer) such as those performed by Prather’s group at the University of California, San Diego (UCSD) with multi-wavelength scattering measurements of the type investigated by Sorensen et al., of Kansas State University (KSU). In this Phase I effort we proposed to investigate near-angle scattering and the possibility of integration of a multi-wavelength scattering instrument into the UCSD ATOFMS. After an initial optical design and calculations, we discovered issues with the theory of measurement and with mechanical integration. Evidence emerged that the method of multi-wavelength scattering is only efficacious for spherical particles, while most atmospheric particles are non-spherical fractal aggregates. We also determined that the integration of the detector into existing ATOFMS instruments would be severely limited by volume constraints, and additional volume would require prohibitive additional pumping compared with the existing ATOFMS systems. Based on this evidence, we decided not to pursue a Phase II effort.

  15. On-site profiling and speciation of polycyclic aromatic hydrocarbons at manufactured gas plant sites by a high temperature transfer line, membrane inlet probe coupled to a photoionization detector and gas chromatography/mass spectrometer

    SciTech Connect (OSTI)

    Thomas Considine; Albert Robbat Jr. [Tufts University, Medford, MA (United States). Chemistry Department, Center for Field Analytical Studies and Technology

    2008-02-15T23:59:59.000Z

    A new high temperature transfer line, membrane inlet probe (HTTL-MIP) coupled to a photoionization detector (PID) and gas chromatograph/mass spectrometer (GC/MS) was used to rapidly profile and speciate polycyclic aromatic hydrocarbons (PAH) in the subsurface. PID signals were in agreement with GC/MS results. Correlation coefficients of 0.92 and 0.99 were obtained for discrete and composite samples collected from the same exact location. Continuous probe advancement with PID detection found coal tar, a dense nonaqueous phase liquid, in soil channels and saturated media. When samples were collected conventionally, split, solvent extracted, and analyzed in the field and confirmation laboratory, GC/MS measurement precision and accuracy were indistinguishable; despite the fact the field laboratory produced data five times faster than the laboratory using standard EPA methods. No false positive/negatives were found. Based on these findings, increased confidence in site conceptual models should be obtained, since PID response indicated total PAH presence/absence in 'real-time', while GC/MS provided information as to which PAH was present and at what concentration. Incorporation of this tool into a dynamic workplan will provide more data at less cost enabling environmental scientists, engineers, and regulators to better understand coal tar migration and its impact on human health and the environment. 24 refs., 3 figs., 4 tabs.

  16. Broad band waveguide spectrometer

    SciTech Connect (OSTI)

    Goldman, D.S.

    1995-08-29T23:59:59.000Z

    A spectrometer is disclosed for analyzing a sample of material utilizing a broad band source of electromagnetic radiation and a detector. The spectrometer employs a waveguide possessing an entry and an exit for the electromagnetic radiation emanating from the source. The waveguide further includes a surface between the entry and exit portions which permits interaction between the electromagnetic radiation passing through the waveguide and a sample material. A tapered portion forms a part of the entry of the waveguide and couples the electromagnetic radiation emanating from the source to the waveguide. The electromagnetic radiation passing from the exit of the waveguide is captured and directed to a detector for analysis. 16 figs.

  17. Broad band waveguide spectrometer

    DOE Patents [OSTI]

    Goldman, Don S. (Folsom, CA)

    1995-01-01T23:59:59.000Z

    A spectrometer for analyzing a sample of material utilizing a broad band source of electromagnetic radiation and a detector. The spectrometer employs a waveguide possessing an entry and an exit for the electromagnetic radiation emanating from the source. The waveguide further includes a surface between the entry and exit portions which permits interaction between the electromagnetic radiation passing through the wave guide and a sample material. A tapered portion forms a part of the entry of the wave guide and couples the electromagnetic radiation emanating from the source to the waveguide. The electromagnetic radiation passing from the exit of the waveguide is captured and directed to a detector for analysis.

  18. EMSL - Mass Spectrometry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mass-spectrometry Proteomics Capabilities High resolution and mass accuracy Fourier-transform ion cyclotron resonance (FT-ICR) spectrometers, from 6 Tesla (T) to 15T and 21T in...

  19. Mass Spectrometer: Proton Transfer Reaction (PTRMS) | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and has been successfully flown on a research aircraft to collect measurements of urban air pollution. The figure below illustrates its measurement capability. These data were...

  20. Mass Spectrometer: Single Particle (SPLAT II) | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nano- and micro-scales. SPLAT II's applications include but are not limited to climate, air pollution, human health, bioterrorism, and emerging nanotechnologies. Portability is a...

  1. LUNAR MASS SPECTROMETER RELIABILITY LOGIC DIAGRAM

    E-Print Network [OSTI]

    Rathbun, Julie A.

    point (A) to (F). The block diagram also defines the reliability functions for the purpose of FMEA 1

  2. Miniaturized Mass Spectrometer - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighandSWPA / SPRA / USACE625DataNeutrino mode fit in 200

  3. Mass Spectrometer Facility | Photosynthetic Antenna Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighand Retrievals from a New 183-GHzMAR Os ZD15netMary K.Masatoshi

  4. ablation multi-collector inductively: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mass spectrometry (ICP-MS). A compact computer Chen, Zhongxing 14 Measurements of Cavitation Dose, Echogenicity, and Temperature during Ultrasound Ablation Biology and Medicine...

  5. Compound and Elemental Analysis At Salt Wells Area (Coolbaugh...

    Open Energy Info (EERE)

    Induced Coupled Plasma Mass Spectroscopy (ICP-MS), using ICP emission and atomic absorption methods for cations and ICP emission for anions. The hottest sampled spring appears...

  6. The Application of LC-ICP-MS to Study Metal Ion Homeostasis in Biological Systems 

    E-Print Network [OSTI]

    McCormick, Sean P.

    2014-12-10T23:59:59.000Z

    reported mismetallation of MnSOD2 was examined in the mutant strain ?mtm1. A combination of SEC and AEX chromatography revealed that the degree of mismetallation of the SOD2 protein, in which Fe replace Mn in the active site, was no greater in ?mtm1 cells...

  7. alpha spectrometry icp-ms: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the source. Simulations and measurements highlight the importance of coincidences in high-resolution alpha spectrometry. To show the validity of the simulated results,...

  8. Trace Elemental Variation in Dosidicus Gigas Statoliths Using LA-ICP-MS

    E-Print Network [OSTI]

    Arbuckle, Nancy 1980-

    2012-08-24T23:59:59.000Z

    concentrations at depth with variability in low oxygen environments (Johnson et al., 1996, Donat and Bruland, 1994, Bruland, 1983). Some authors suggest that relative to levels found in statoliths, manganese concentration is nearly uniform in the ocean... (Zumholz et al., 2007c). Copper exhibits a nutrient like profile with reduced concentrations in surface waters (Bruland, 1983, Donat and Bruland, 1994). It has not been measured in many statolith studies but was successfully used to distinguish between...

  9. Glass particles produced by laser ablation for ICP-MS measurements

    E-Print Network [OSTI]

    Gonzalez, J.; Liu, C.; Wen, S.; Mao, X.; Russo, R.E.

    2008-01-01T23:59:59.000Z

    NIST) and X-ray fluorescence (XRF) monitor samples from Glenstandards), and figure 2 (XRF standards). The error barsand 160 and 180 nm for XRF monitor samples. These data show

  10. Determination of 235U/238U Ratio on Urine by ICP-MS

    SciTech Connect (OSTI)

    Collins, L; Gobaleza, A; Langston, R; Radev, R; Than, C; Wong, C; Wood-Zika, A

    2011-10-19T23:59:59.000Z

    LLNL Internal Dosimetry Program - The new procedure satisfies the requirement to determine {sup 235}U/{sup 238}U ratio in bioassay urine samples. MDA - The L{sub C} and MDA{sub 95} for {sup 235}U are well below the required detection limit of 0.00035 {mu}g/L. Turn around time - Analysis of 10 samples plus 2 QCs can be completed in one work day (8 hours).

  11. The Application of LC-ICP-MS to Study Metal Ion Homeostasis in Biological Systems

    E-Print Network [OSTI]

    McCormick, Sean P.

    2014-12-10T23:59:59.000Z

    reported mismetallation of MnSOD2 was examined in the mutant strain ?mtm1. A combination of SEC and AEX chromatography revealed that the degree of mismetallation of the SOD2 protein, in which Fe replace Mn in the active site, was no greater in ?mtm1 cells...

  12. Improvements to ICP Torches for Monitoring Trace Radionuclides by ICP-MS |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogenITLaboratory in Inductively Coupled

  13. Neutron range spectrometer

    DOE Patents [OSTI]

    Manglos, S.H.

    1988-03-10T23:59:59.000Z

    A neutron range spectrometer and method for determining the neutron energy spectrum of a neutron emitting source are disclosed. Neutrons from the source are colliminated along a collimation axis and a position sensitive neutron counter is disposed in the path of the collimated neutron beam. The counter determines positions along the collimation axis of interactions between the neutrons in the neutron beam and a neutron-absorbing material in the counter. From the interaction positions, a computer analyzes the data and determines the neutron energy spectrum of the neutron beam. The counter is preferably shielded and a suitable neutron-absorbing material is He-3. 1 fig.

  14. Lessons Learned for the MICE Coupling Solenoid from the MICE Spectrometer Solenoids

    SciTech Connect (OSTI)

    Green, Michael A.; Wang, Li; Pan, Heng; Wu, Hong; Guo, Xinglong; Li, S. Y.; Zheng, S. X.; Virostek, Steve P.; DeMello, Allen J.; Li, Derun; Trillaud, Frederick; Zisman, Michael S.

    2010-05-30T23:59:59.000Z

    Tests of the spectrometer solenoids have taught us some important lessons. The spectrometer magnet lessons learned fall into two broad categories that involve the two stages of the coolers that are used to cool the magnets. On the first spectrometer magnet, the problems were centered on the connection of the cooler 2nd-stage to the magnet cold mass. On the first test of the second spectrometer magnet, the problems were centered on the cooler 1st-stage temperature and its effect on the operation of the HTS leads. The second time the second spectrometer magnet was tested; the cooling to the cold mass was still not adequate. The cryogenic designs of the MICE and MuCOOL coupling magnets are quite different, but the lessons learned from the tests of the spectrometer magnets have affected the design of the coupling magnets.

  15. Photo ion spectrometer

    DOE Patents [OSTI]

    Gruen, Dieter M. (Downers Grove, IL); Young, Charles E. (Westmont, IL); Pellin, Michael J. (Naperville, IL)

    1989-01-01T23:59:59.000Z

    A charged particle spectrometer for performing ultrasensitive quantitative analysis of selected atomic components removed from a sample. Significant improvements in performing energy and angular refocusing spectroscopy are accomplished by means of a two dimensional structure for generating predetermined electromagnetic field boundary conditions. Both resonance and non-resonance ionization of selected neutral atomic components allow accumulation of increased chemical information. A multiplexed operation between a SIMS mode and a neutral atomic component ionization mode with EARTOF analysis enables comparison of chemical information from secondary ions and neutral atomic components removed from the sample. An electronic system is described for switching high level signals, such as SIMS signals, directly to a transient recorder and through a charge amplifier to the transient recorder for a low level signal pulse counting mode, such as for a neutral atomic component ionization mode.

  16. Photo ion spectrometer

    DOE Patents [OSTI]

    Gruen, D.M.; Young, C.E.; Pellin, M.J.

    1989-12-26T23:59:59.000Z

    A charged particle spectrometer is described for performing ultrasensitive quantitative analysis of selected atomic components removed from a sample. Significant improvements in performing energy and angular refocusing spectroscopy are accomplished by means of a two dimensional structure for generating predetermined electromagnetic field boundary conditions. Both resonance and non-resonance ionization of selected neutral atomic components allow accumulation of increased chemical information. A multiplexed operation between a SIMS mode and a neutral atomic component ionization mode with EARTOF analysis enables comparison of chemical information from secondary ions and neutral atomic components removed from the sample. An electronic system is described for switching high level signals, such as SIMS signals, directly to a transient recorder and through a charge amplifier to the transient recorder for a low level signal pulse counting mode, such as for a neutral atomic component ionization mode. 12 figs.

  17. What Happened with Spectrometer Magnet 2B

    SciTech Connect (OSTI)

    Green, Michael A

    2010-05-27T23:59:59.000Z

    The spectrometer solenoid is supposed to be the first magnets installed in MICE [1]-[4]. This report described what happened during the test of the MICE spectrometer solenoid 2B. First, the report describes the temperatures in the magnet, the cooler top plate and the shield during the run where the magnet quenched at 258 A. During this quench, a lead between the bottom of the HTS leads and the diode bank burned out causing the magnet to quench. Second, three methods for measuring the net heat flow into the cold mass are described. Third, there is a discussion of possible resistive heating in the HTS leads between liquid helium temperature and the copper plate, which is at about 50 K. Fourth, there is a discussion of the measured first stage heat loads in the magnet, when there is no current in the magnet. The first stage heat load calculations are based on knowing the first stage temperatures of the three two-stage pulse tube coolers and the single stage GM cooler. Fifth, the estimated heat load to the first stage when the magnet has current in it is discussed. Sixth, there is a comparison of the stage 1 heat loads in magnet 1A [5], magnet 2A [6], and magnet 2B [7]. Finally there is a discussion of recommended changes for improving the spectrometer solenoids so that the coolers can keep them cold.

  18. Study of Active Shielding for {gamma} - Spectrometers

    SciTech Connect (OSTI)

    Bikit, I.; Mrdja, D.; Forkapic, S.; Todorovic, N.; Veskovic, M.; Slivka, J.; Conkic, Lj.; Krmar, M.; Varga, E. [Department of Physics, Faculty of Sciences, University of Novi Sad, Trg Dositeja Obradovica 4, 21 000 Novi Sad (Serbia and Montenegro)

    2006-04-26T23:59:59.000Z

    The features of the ground located gamma ray spectrometer shielded passively with 12 cm of lead and actively by five 0.5m x 0.5m x 0.05m plastic veto shields are described. The detector mass related background was 0.345 C/kg s. The 511 keV annihilation line was reduced by the factor of 7 by the anticoincidence gate. It is shown that the plastic shields increase the neutron capture gamma line intensities due to neutron thermalization.

  19. Aerosol mobility size spectrometer

    DOE Patents [OSTI]

    Wang, Jian (Port Jefferson, NY); Kulkarni, Pramod (Port Jefferson Station, NY)

    2007-11-20T23:59:59.000Z

    A device for measuring aerosol size distribution within a sample containing aerosol particles. The device generally includes a spectrometer housing defining an interior chamber and a camera for recording aerosol size streams exiting the chamber. The housing includes an inlet for introducing a flow medium into the chamber in a flow direction, an aerosol injection port adjacent the inlet for introducing a charged aerosol sample into the chamber, a separation section for applying an electric field to the aerosol sample across the flow direction and an outlet opposite the inlet. In the separation section, the aerosol sample becomes entrained in the flow medium and the aerosol particles within the aerosol sample are separated by size into a plurality of aerosol flow streams under the influence of the electric field. The camera is disposed adjacent the housing outlet for optically detecting a relative position of at least one aerosol flow stream exiting the outlet and for optically detecting the number of aerosol particles within the at least one aerosol flow stream.

  20. Photo ion spectrometer

    DOE Patents [OSTI]

    Gruen, Dieter M. (Downers Grove, IL); Young, Charles E. (Westmont, IL); Pellin, Michael J. (Naperville, IL)

    1989-01-01T23:59:59.000Z

    A method and apparatus for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected autoionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy.

  1. Photo ion spectrometer

    DOE Patents [OSTI]

    Gruen, D.M.; Young, C.E.; Pellin, M.J.

    1989-08-08T23:59:59.000Z

    A method and apparatus are described for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected auto-ionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy. 8 figs.

  2. Z .Chemical Geology 167 2000 405425 www.elsevier.comrlocaterchemgeo

    E-Print Network [OSTI]

    Rudnick, Roberta L.

    and isotope ratio determination by simultaneous solution nebulization and laser ablation-ICP-MS: application measurements by simultaneous solution nebulization and laser ablation inductively coupled plasma mass 2000 Elsevier Science B.V. All rights reserved. Keywords: Isotope ratio; Laser ablation-ICP-MS; U

  3. A mobile Magnetic Sensor Unit for the KATRIN Main Spectrometer

    E-Print Network [OSTI]

    Osipowicz, A; Letnev, J; Marte, P; Müller, A; Spengler, A; Unru, A; 10.1088/1748-0221/7/06/T06002

    2012-01-01T23:59:59.000Z

    The KArlsruhe TRItium Neutrino experiment (KATRIN) aims to measure the electron neutrino mass with an unprecedented sensitivity of 0.2 eV/c2, using b decay electrons from tritium decay. For the control of magnetic field in the main spectrometer area of the KATRIN experiment a mobile magnetic sensor unit is constructed and tested at the KATRIN main spectrometer site. The unit moves on inner rails of the support structures of the low field shaping coils which are arranged along the the main spectrometer. The unit propagates on a caterpillar drive and contains an electro motor, battery pack, board electronics, 2 triaxial flux gate sensors and 2 inclination senors. During operation all relevant data are stored on board and transmitted to the master station after the docking station is reached.

  4. The IPNS resonance detector spectrometer

    SciTech Connect (OSTI)

    Crawford, R.K.

    1986-01-01T23:59:59.000Z

    In the resonance detector method of neutron spectroscopy, a foil is placed in the scattered neutron beam and scattered neutrons having the resonance energy are detected by detecting the capture gammas resulting from the resonance absorption of the neutrons. A prototype resonance detector spectrometer called the Electron Volt Spectrometer (EVS) has been built and operated. The instrument is described, the current understanding of the background of the instrument is discussed, software developed to simulate the detector efficiency is described and compared with experimental results, and a test of the use of foil-thickness difference techniques to improve resolution is presented. (LEW)

  5. MICE Spectrometer Magnet System Progress

    SciTech Connect (OSTI)

    Green, Michael A.; Virostek, Steve P.

    2007-08-27T23:59:59.000Z

    The first magnets for the muon ionization cooling experimentwill be the tracker solenoids that form the ends of the MICE coolingchannel. The primary purpose of the tracker solenoids is to provide auniform 4 T field (to better than +-0.3 percent over a volume that is 1meter long and 0.3 meters in diameter) spectrometer magnet field for thescintillating fiber detectors that are used to analyze the muons in thechannel before and after ionization cooling. A secondary purpose for thetracker magnet is the matching of the muon beam between the rest of theMICE cooling channel and the uniform field spectrometer magnet. Thetracker solenoid is powered by three 300 amp power supplies. Additionaltuning of the spectrometer is provided by a pair of 50 amp power suppliesacross the spectrometer magnet end coils. The tracker magnet will becooled using a pair of 4 K pulse tube coolers that each provide 1.5 W ofcooling at 4.2 K. Final design and construction of the tracker solenoidsbegan during the summer of 2006. This report describes the progress madeon the construction of the tracker solenoids.

  6. An improved scintillation beta spectrometer

    E-Print Network [OSTI]

    McClary, Jimmy Fred

    1964-01-01T23:59:59.000Z

    ~i'TILLATIGR 3ZTA SPECTROMETER ~ ~ ? ~ ~ ~ ~ ~ ~ o ~ o ~ ~ SPECTRAL eSPC. .TSZ: OP DIP. Z. -W. T 3110TOIXLTI" LIL"-i O'TiiODZS ZiISSIOH SPECTRA OP iaI(T1) AiiD AHTRRACZHZ. . . . . ?. . . . . . ~ . ~ ~ ~ ~ 7 TIIL' SCATTZRI'iG 1'ROBLZ. Iii 3ETA SPECTROSCOPY...

  7. E781 Hyperon Spectrometer Constants

    SciTech Connect (OSTI)

    Joseph T. Lach

    2004-05-04T23:59:59.000Z

    This is a discussion of the physical measurements, sizes, distances and magnetic fields of the Hyperon Spectrometer Magnet and its components. Some we get from construction drawings (like the target dimensions) and others from measurements in differing coordinate systems. Included also are the properties of the hyperon productions targets used in E781.

  8. Contaminant Mass Balance for Sinclair and Dyes Inlets, Puget Sound, WA

    SciTech Connect (OSTI)

    Crecelius, Eric A.; Johnston, Robert K.; Leather, Jim; Guerrero, Joel; Miller, Martin C.; Brandenberger, Jill M.

    2003-04-03T23:59:59.000Z

    Sinclair Inlet and Dyes Inlets have historically received contaminates from military installations, industrial activities, municipal outfalls, and other nonpoint sources. For the purpose of determining a ?total maximum daily load? (TMDL) of contaminants for the Inlets, a contaminant mass balance for the sediments is being developed. Sediment cores and traps were collected from depositional areas of the Inlets and surface sediment grabs were collected from fluvial deposits associated with major drainage areas into the Inlets. All sediment samples were screened using X-Ray fluorescence (XRF) for metals, UV fluorescence for organics (PAHs), and immunoassay for PCBs. A subset of split-samples was analyzed using ICP/MS for metals and GC/MS for phthalates, PAHs, and PCBs. Sediment cores were age-dated using radionuclides to determine the sedimentation rate and the history of sediment contamination. Streams and storm water outfalls were sampled in both the wet and dry seasons to assess loading from the watershed. Seawater samples collected from the marine waters of the Inlets and boundary passages to central Puget Sound were used to estimate the exchange of contaminates with central Puget Sound. The historical trends from the cores indicate that contamination was at a maximum in the middle of the 1900s and decreased significantly by the late 1900s. The thickness of the contaminated sediment is in the range of 30 to 50 cm.

  9. PUBLISHED VERSION Gamma ray spectrometer for ITER

    E-Print Network [OSTI]

    Ray Scintillation Spectrometer Rev. Sci. Instrum. 24, 1096 (1953); 10.1063/1.1770609 An Automatic Recording Gamma for the spectrometer is presented. Keywords: tokamak, DT plasma, alpha- particles, diagnostics, gamma- spectrometry

  10. Sample rotating turntable kit for infrared spectrometers

    DOE Patents [OSTI]

    Eckels, Joel Del (Livermore, CA); Klunder, Gregory L. (Oakland, CA)

    2008-03-04T23:59:59.000Z

    An infrared spectrometer sample rotating turntable kit has a rotatable sample cup containing the sample. The infrared spectrometer has an infrared spectrometer probe for analyzing the sample and the rotatable sample cup is adapted to receive the infrared spectrometer probe. A reflectance standard is located in the rotatable sample cup. A sleeve is positioned proximate the sample cup and adapted to receive the probe. A rotator rotates the rotatable sample cup. A battery is connected to the rotator.

  11. Inverse time-of-flight spectrometer for beam plasma research

    SciTech Connect (OSTI)

    Yushkov, Yu. G., E-mail: yuyushkov@gmail.com; Zolotukhin, D. B.; Tyunkov, A. V. [Tomsk State University of Control Systems and Radioelectronics, 40 Lenin Ave., Tomsk 634050 (Russian Federation); Oks, E. M. [Tomsk State University of Control Systems and Radioelectronics, 40 Lenin Ave., Tomsk 634050 (Russian Federation); Institute of High Current Electronics SB RAS, 2/3, Akademichesky Ave., Tomsk 634055 (Russian Federation); Savkin, K. P. [Institute of High Current Electronics SB RAS, 2/3, Akademichesky Ave., Tomsk 634055 (Russian Federation)

    2014-08-15T23:59:59.000Z

    The paper describes the design and principle of operation of an inverse time-of-flight spectrometer for research in the plasma produced by an electron beam in the forevacuum pressure range (5–20 Pa). In the spectrometer, the deflecting plates as well as the drift tube and the primary ion beam measuring system are at high potential with respect to ground. This provides the possibility to measure the mass-charge constitution of the plasma created by a continuous electron beam with a current of up to 300 mA and electron energy of up to 20 keV at forevacuum pressures in the chamber placed at ground potential. Research results on the mass-charge state of the beam plasma are presented and analyzed.

  12. Linear electric field mass spectrometry

    DOE Patents [OSTI]

    McComas, D.J.; Nordholt, J.E.

    1992-12-01T23:59:59.000Z

    A mass spectrometer and methods for mass spectrometry are described. The apparatus is compact and of low weight and has a low power requirement, making it suitable for use on a space satellite and as a portable detector for the presence of substances. High mass resolution measurements are made by timing ions moving through a gridless cylindrically symmetric linear electric field. 8 figs.

  13. 21 Tesla mass spectrometry magnet arrives at EMSL | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and biological materials are one step closer to using EMSL's new 21 Tesla Fourier Transform Ion Cyclotron Resonance Mass Spectrometer. The magnet, a critical piece of...

  14. Targeted Tandem Mass Spectrometry for High-Throughput Comparative...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    states. Herein, we report on a targeted LC-MSMS capability realized with a 7 Tesla Fourier transform ion cyclotron resonance (FTICR) mass spectrometer equipped with a...

  15. Standard test method for determination of impurities in nuclear grade uranium compounds by inductively coupled plasma mass spectrometry

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2010-01-01T23:59:59.000Z

    1.1 This test method covers the determination of 67 elements in uranium dioxide samples and nuclear grade uranium compounds and solutions without matrix separation by inductively coupled plasma mass spectrometry (ICP-MS). The elements are listed in Table 1. These elements can also be determined in uranyl nitrate hexahydrate (UNH), uranium hexafluoride (UF6), triuranium octoxide (U3O8) and uranium trioxide (UO3) if these compounds are treated and converted to the same uranium concentration solution. 1.2 The elements boron, sodium, silicon, phosphorus, potassium, calcium and iron can be determined using different techniques. The analyst's instrumentation will determine which procedure is chosen for the analysis. 1.3 The test method for technetium-99 is given in Annex A1. 1.4 The values stated in SI units are to be regarded as standard. 1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish ...

  16. Melt Extraction and Melt Refertilization in Mantle Peridotite of the Coast Range Ophiolite: An LA-ICP-MS Study

    E-Print Network [OSTI]

    Shervais, John W.

    Institute Songdo Techno Park 7-50 Incheon 406-840, South Korea Samuel B. Mukasa Department of Geological; Johnson et al., 1990, Johnson #12;3 and Dick, 1992; Seyler et al., 2003, 2004; Hellebrand et al., 2002, and essentially flat MREE-HREE (e.g., Johnson et al., 1990; Hellebrand et al., 2002). Niu (1997; Niu et al., 1997

  17. Portable neutron spectrometer and dosimeter

    DOE Patents [OSTI]

    Waechter, David A. (Los Alamos, NM); Erkkila, Bruce H. (Los Alamos, NM); Vasilik, Dennis G. (Los Alamos, NM)

    1985-01-01T23:59:59.000Z

    The disclosure relates to a battery operated neutron spectrometer/dosimeter utilizing a microprocessor, a built-in tissue equivalent LET neutron detector, and a 128-channel pulse height analyzer with integral liquid crystal display. The apparatus calculates doses and dose rates from neutrons incident on the detector and displays a spectrum of rad or rem as a function of keV per micron of equivalent tissue and also calculates and displays accumulated dose in millirads and millirem as well as neutron dose rates in millirads per hour and millirem per hour.

  18. Compact reflective imaging spectrometer utilizing immersed gratings

    DOE Patents [OSTI]

    Chrisp, Michael P. (Danville, CA)

    2006-05-09T23:59:59.000Z

    A compact imaging spectrometer comprising an entrance slit for directing light, a first mirror that receives said light and reflects said light, an immersive diffraction grating that diffracts said light, a second mirror that focuses said light, and a detector array that receives said focused light. The compact imaging spectrometer can be utilized for remote sensing imaging spectrometers where size and weight are of primary importance.

  19. Electron Spectrometer: Scanning Multiprobe Surface Analysis System...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scanning Multiprobe Surface Analysis System - Versaprobe Electron Spectrometer: Scanning Multiprobe Surface Analysis System - Versaprobe The SMSAS is a multi-technique surface...

  20. Electron Spectrometer: XPS with Laser Interface | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with Laser Interface Electron Spectrometer: XPS with Laser Interface This ultrahigh vacuum machine can be applied as a routine means for analyzing the structure and chemical...

  1. Evaluation of Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and Moderate Resolution Imaging Spectrometer

    E-Print Network [OSTI]

    Evaluation of Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and Moderate Resolution the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and the Moderate Resolution Imaging Spectrometer (MODIS). Key goals were to assess the nature of these relationships as they varied between sensors

  2. The High-Acceptance Dielectron Spectrometer HADES

    E-Print Network [OSTI]

    The HADES Collaboration; G. Agakishiev; A. Balanda; B. Bannier; R. Bassini; D. Belver; A. V. Belyaev; A. Blanco; M. Boehmer; J. L. Boyard; P. Braun-Munzinger; P. Cabanelas; E. Castro; S. Chernenko; T. Christ; M. Destefanis; J. Diaz; F. Dohrmann; A. Dybczak; T. Eberl; W. Enghardt; L. Fabbietti; O. V. Fateev; P. Finocchiaro; P. Fonte; J. Friese; I. Froehlich; T. Galatyuk; J. A. Garzon; R. Gernhaeuser; A. Gil; C. Gilardi; M. Golubeva; D. Gonzalez-Diaz; F. Guber; M. Heilmann; T. Heinz; T. Hennino; R. Holzmann; A. Ierusalimov; I. Iori; A. Ivashkin; M. Jurkovic; B. Kaempfer; K. Kanaki; T. Karavicheva; D. Kirschner; I. Koenig; W. Koenig; B. W. Kolb; R. Kotte; F. Krizek; R. Kruecken; W. Kuehn; A. Kugler; A. Kurepin; S. Lang; J. S. Lange; K. Lapidus; T. Liu; L. Lopes; M. Lorenz; L. Maier; A. Mangiarotti; J. Markert; V. Metag; B. Michalska; J. Michel; D. Mishra; E. Moriniere; J. Mousa; C. Muentz; L. Naumann; J. Otwinowski; Y. C. Pachmayer; M. Palka; Y. Parpottas; V. Pechenov; O. Pechenova; T. PerezCavalcanti; J. Pietraszko; W. Przygoda; B. Ramstein; A. Reshetin; M. Roy-Stephan; A. Rustamov; A. Sadovsky; B. Sailer; P. Salabura; A. Schmah; E. Schwab; Yu. G. Sobolev; S. Spataro; B. Spruck; H. Stroebele; J. Stroth; C. Sturm; M. Sudol; A. Tarantola; K. Teilab; P. Tlusty; M. Traxler; R. Trebac; H. Tsertos; V. Wagner; M. Weber; M. Wisniowski; T. Wojcik; J. Wuestenfel; S. Yurevich; Y. V. Zanevsky; P. Zhou; P. Zumbruch

    2009-03-09T23:59:59.000Z

    HADES is a versatile magnetic spectrometer aimed at studying dielectron production in pion, proton and heavy-ion induced collisions. Its main features include a ring imaging gas Cherenkov detector for electron-hadron discrimination, a tracking system consisting of a set of 6 superconducting coils producing a toroidal field and drift chambers and a multiplicity and electron trigger array for additional electron-hadron discrimination and event characterization. A two-stage trigger system enhances events containing electrons. The physics program is focused on the investigation of hadron properties in nuclei and in the hot and dense hadronic matter. The detector system is characterized by an 85% azimuthal coverage over a polar angle interval from 18 to 85 degree, a single electron efficiency of 50% and a vector meson mass resolution of 2.5%. Identification of pions, kaons and protons is achieved combining time-of-flight and energy loss measurements over a large momentum range. This paper describes the main features and the performance of the detector system.

  3. Birefringent Fourier-transform imaging spectrometer

    E-Print Network [OSTI]

    Harvey, Andy

    Birefringent Fourier-transform imaging spectrometer Andrew Robert Harvey and David William Fletcher.r.Harvey@hw.ac.uk http://www.ece.eps.hw.ac.uk/~arharvey Abstract: Fourier-transform imaging spectrometers offer important, for application in harsh environments, deployment of Fourier-transform instruments based on traditional moving

  4. Accurate determination of Curium and Californium isotopic ratios by inductively coupled plasma quadrupole mass spectrometry (ICP-QMS) in 248Cm samples for transmutation studies

    SciTech Connect (OSTI)

    Gourgiotis, A.; Isnard, H.; Aubert, M.; Dupont, E.; AlMahamid, I.; Cassette, P.; Panebianco, S.; Letourneau, A.; Chartier, F.; Tian, G.; Rao, L.; Lukens, W.

    2011-02-01T23:59:59.000Z

    The French Atomic Energy Commission has carried out several experiments including the mini-INCA (INcineration of Actinides) project for the study of minor-actinide transmutation processes in high intensity thermal neutron fluxes, in view of proposing solutions to reduce the radiotoxicity of long-lived nuclear wastes. In this context, a Cm sample enriched in {sup 248}Cm ({approx}97 %) was irradiated in thermal neutron flux at the High Flux Reactor (HFR) of the Laue-Langevin Institute (ILL). This work describes a quadrupole ICP-MS (ICP-QMS) analytical procedure for precise and accurate isotopic composition determination of Cm before sample irradiation and of Cm and Cf after sample irradiation. The factors that affect the accuracy and reproducibility of isotopic ratio measurements by ICP-QMS, such as peak centre correction, detector dead time, mass bias, abundance sensitivity and hydrides formation, instrumental background, and memory blank were carefully evaluated and corrected. Uncertainties of the isotopic ratios, taking into account internal precision of isotope ratio measurements, peak tailing, and hydrides formations ranged from 0.3% to 1.3%. This uncertainties range is quite acceptable for the nuclear data to be used in transmutation studies.

  5. A comparison of continuous pneumatic nebulization and flow injection-direct injection nebulization for sample introduction in inductively coupled plasma-mass spectrometry

    SciTech Connect (OSTI)

    Crain, J.S.; Kiely, J.T.

    1995-08-01T23:59:59.000Z

    Dilute nitric acid blanks and solutions containing Ni, Cd, Pb, and U (including two laboratory waste samples) were analyzed eighteen times over a two-month period using inductively coupled plasma-mass spectrometry (ICP-MS). Two different sample introduction techniques were employed: flow injection-direct injection nebulization (FI-DIN) and continuous pneumatic nebulization (CPN). Using comparable instrumental measurement procedures, FI-DIN analyses were 33% faster and generated 52% less waste than CPN analyses. Instrumental limits of detection obtained with FI-DIN and CPN were comparable but not equivalent (except in the case of Pb) because of nebulizer-related differences in sensitivity (i.e., signal per unit analyte concentration) and background. Substantial and statistically significant differences were found between FI-DIN and CPN Ni determinations, and in the case of the laboratory waste samples, there were also small but statistically significant differences between Cd determinations. These small (2 to 3%) differences were not related to polyatomic ion interference (e.g., {sup 95}Mo{sup 16}O{sup +}), but in light of the time savings and waste reduction to be realized, they should not preclude the use of FI-DIN in place of CPN for determination of Cd, Pb, U and chemically.

  6. SWEPP Gamma-Ray Spectrometer System software design description

    SciTech Connect (OSTI)

    Femec, D.A.; Killian, E.W.

    1994-08-01T23:59:59.000Z

    To assist in the characterization of the radiological contents of contract-handled waste containers at the Stored Waste Examination Pilot Plant (SWEPP), the SWEPP Gamma-Ray Spectrometer (SGRS) System has been developed by the Radiation Measurements and Development Unit of the Idaho National Engineering Laboratory. The SGRS system software controls turntable and detector system activities. In addition to determining the concentrations of gamma-ray-emitting radionuclides, this software also calculates attenuation-corrected isotopic mass ratios of-specific interest. This document describes the software design for the data acquisition and analysis software associated with the SGRS system.

  7. THE GAS CHROMATOGRAPH MASS SPECTROMETER FOR THE HUYGENS PROBE

    E-Print Network [OSTI]

    Atreya, Sushil

    sampling and ACP gas sampling re- spectively. The instrument is also equipped with a chemical scrubber cell

  8. Mass Spectrometer: Aerosol, time-of-flight, high resolution ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from diesel exhaust and aircraft studies of particle size and composition from power plants. Studies are currently underway to use the AMS for the characterization of...

  9. Mass Spectrometer: Ion Mobility Spectrometry, Time of Flight...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    isolated human pancreatic islets using LC-MSMS-based proteomics. The prevalence of diabetes mellitus is increasing dramatically throughout the world, and the disease has become...

  10. An Engine Exhaust Particle SizerTM Spectrometer for Transient...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An Engine Exhaust Particle SizerTM Spectrometer for Transient Emission Particle Measurements An Engine Exhaust Particle SizerTM Spectrometer for Transient Emission Particle...

  11. actinide standard ii-iii: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Spectrometry (ICP-MS). This alternate calibration is mass bias adjusted using thorium-232 (232Th) and uranium-238 (238U) standards. One of the benefits of this standard...

  12. Preparation and Characterization of High-Purity Metal Fluorides for Photonic Applications*

    E-Print Network [OSTI]

    Sheik-Bahae, Mansoor

    is quantified directly by inductively cou- pled plasma mass spectrometry (ICP-MS) and indirectly by laser,4­7 scintillators,8,9 up-con- version phosphors,10 solid-state optical refrigerators,11 and emerging crystals

  13. LCLS Injector Straight-Ahead Spectrometer

    SciTech Connect (OSTI)

    Limborg-Deprey , C.

    2010-12-10T23:59:59.000Z

    The spectrometer design was modified to allow the measurement of uncorrelated energy spread for the nominal lattice. One bunch from every 120 each second would be sent to the straight ahead spectrometer while the transverse cavity is on. The implementation of this 'stealing mode' will not be available for the LCLS commissioning and the early stage of operation. However, the spectrometer was redesigned to retain that option. The energy feedback relies independently on the beam position of the beam in the dispersive section of dogleg 1 (DL1). The main modification of the spectrometer design is the Pole face rotation of 7.5 degrees on both entrance and exit faces. The location and range of operation of the 3 quadrupoles remains unchanged relative to those of the earlier design.

  14. Visible spectrometer utilizing organic thin film absorption

    E-Print Network [OSTI]

    Tiefenbruck, Laura C. (Laura Christine)

    2004-01-01T23:59:59.000Z

    In this thesis, I modeled and developed a spectrometer for the visible wavelength spectrum, based on absorption characteristics of organic thin films. The device uses fundamental principles of linear algebra to reconstruct ...

  15. A SUPERCONDUCTING-SOLENOID ISOTOPE SPECTROMETER

    E-Print Network [OSTI]

    O'Donnell, Tom

    A SUPERCONDUCTING-SOLENOID ISOTOPE SPECTROMETER FOR PRODUCTION OF NEUTRON-RICH NUCLEI ( 136 Xe Superconducting Cyclotron Laboratory's weekly \\Green Sheet," 30 July 1999 #12; c Thomas W. O'Donnell 2000 All

  16. Optical Calibration For Jefferson Lab HKS Spectrometer

    E-Print Network [OSTI]

    L. Yuan; L. Tang

    2005-11-04T23:59:59.000Z

    In order to accept very forward angle scattering particles, Jefferson Lab HKS experiment uses an on-target zero degree dipole magnet. The usual spectrometer optics calibration procedure has to be modified due to this on-target field. This paper describes a new method to calibrate HKS spectrometer system. The simulation of the calibration procedure shows the required resolution can be achieved from initially inaccurate optical description.

  17. aerosol time-of-flight mass: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theses and Dissertations Summary: ??The construction of a liquid nitrogen-cooled ion mobility spectrometer coupled with time-of-flight mass spectrometry was implemented to...

  18. Chip-scale quadrupole mass filters for a Micro-Gas Analyzer

    E-Print Network [OSTI]

    Cheung, Kerry

    2009-01-01T23:59:59.000Z

    Mass spectrometers are powerful analytical instruments that serve as the gold standard for chemical analysis. This tool has numerous applications ranging from national security, industrial processing, environmental monitoring, ...

  19. Development and characterization of a multiple-coincidence ion-momentum imaging spectrometer

    SciTech Connect (OSTI)

    Laksman, J.; Céolin, D.; Månsson, E. P.; Sorensen, S. L.; Gisselbrecht, M. [Department of Synchrotron Radiation Research, Lund University, Box 118, S-221 00 Lund (Sweden)] [Department of Synchrotron Radiation Research, Lund University, Box 118, S-221 00 Lund (Sweden)

    2013-12-15T23:59:59.000Z

    The design and performance of a high-resolution momentum-imaging spectrometer for ions which is optimized for experiments using synchrotron radiation is presented. High collection efficiency is achieved by a focusing electrostatic lens; a long drift tube improves mass resolution and a position-sensitive detector enables measurement of the transverse momentum of ions. The optimisation of the lens for particle momentum measurement at the highest resolution is described. We discuss the overall performance of the spectrometer and present examples demonstrating the momentum resolution for both kinetics and for angular measurements in molecular fragmentation for carbon monoxide and fullerenes. Examples are presented that confirm that complete space-time focussing is possible for a two-field three-dimensional imaging spectrometer.

  20. Evaluation of Biomimetic and Alloy-based Materials for Orthopedic Applications 

    E-Print Network [OSTI]

    Guiza-Arguello, Viviana R.

    2013-07-17T23:59:59.000Z

    ICP-MS measures. ............................................................... 17 3. Cytotoxicity of uncoated NiMnSn alloys relative to NiMnSn alloys with uncrosslinked and crosslinked PAH/PAA coatings alloys as evaluated by DNA assessments... similarly harvested at day 14 for cell viability assessments. 2.3.3.3. Ion release Levels of Ni, Sn, and Mn ions released from the cultured alloy samples were monitored using Inductively Coupled Plasma Emission-Mass Spectroscopy (ICP-MS). At the time...

  1. Wide size range fast integrated mobility spectrometer

    DOE Patents [OSTI]

    Wang, Jian

    2013-10-29T23:59:59.000Z

    A mobility spectrometer to measure a nanometer particle size distribution is disclosed. The mobility spectrometer includes a conduit and a detector. The conduit is configured to receive and provide fluid communication of a fluid stream having a charged nanometer particle mixture. The conduit includes a separator section configured to generate an electrical field of two dimensions transverse to a dimension associated with the flow of the charged nanometer particle mixture through the separator section to spatially separate charged nanometer particles of the charged nanometer particle mixture in said two dimensions. The detector is disposed downstream of the conduit to detect concentration and position of the spatially-separated nanometer particles.

  2. Compact Imaging Spectrometer Utilizing Immersed Gratings

    DOE Patents [OSTI]

    Chrisp, Michael P. (Danville, CA); Lerner, Scott A. (Corvallis, OR); Kuzmenko, Paul J. (Livermore, CA); Bennett, Charles L. (Livermore, CA)

    2006-03-21T23:59:59.000Z

    A compact imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The imaging spectrometer comprises an entrance slit for transmitting light, a system for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the system for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the system for receiving the light and the system for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light through an optical element to the detector array.

  3. Performance of a Moderating Neutron Spectrometer That Uses Scintillating Fibers

    SciTech Connect (OSTI)

    Bliss, Mary; Craig, Richard A.; Barnett, Debra S.; Anderson, Dale N.; Smart, John E.; Knopf, Michael A.; Hartley, Stacey A.

    2001-08-03T23:59:59.000Z

    The Bonner sphere is the canonical example of instruments that provide a measure of neutron spectra by using moderating and absorbing materials together with thermal-neutron detectors. For such spectrometers, the instrument response reflects a statistical average of the energy spectrum. Pacific Northwest National Laboratory has developed neutron-sensitive cerium-activated scintillating fibers composed of lithium-silicate glass. These fibers present an enabling technology for efficient neutron spectroscopy. A moderating spectrometer was built as a testbed for materials identification. Based on the results of Monte Carlo experiments, six fiber layers are separated by polyethylene layers whose thickness has been chosen to maximize neutron spectral information. The completed, self-contained instrument, including electronics and data logging computer has a mass less than 35 kg, slightly more than half of which is polyethylene. Measurements have been performed by this instrument with various sources representing hard and soft neutron spectra. Because this instrument is a technology testbed, the data are recorded as pulse-height spectra. Results and future directions are presented.

  4. The response of a Bonner Sphere spectrometer to charged hadrons

    E-Print Network [OSTI]

    Agosteo, S; Fassò, A; Silari, M; 10.1093/rpd/nch187

    2004-01-01T23:59:59.000Z

    Bonner sphere spectrometers (BSSs) are employed in neutron spectrometry and dosimetry since many years. Recent developments have seen the addition to a conventional BSS of one or more detectors (moderator plus thermal neutron counter) specifically designed to improve the overall response of the spectrometer to neutrons above 10 MeV. These additional detectors employ a shell of material with a high mass number (such as lead) within the polyethylene moderator, in order to slow down high-energy neutrons via (n, xn) reactions. A BSS can be used to measure neutron spectra both outside accelerator shielding and from an unshielded target. Measurements were recently performed at CERN of the neutron yield and spectral fluence at various angles from unshielded, semithick copper, silver and lead targets, bombarded by a mixed proton/pion beam with 40 GeV per c momentum. These experiments have provided evidence that under certain circumstances, the use of lead-enriched moderators may present a problem: these detectors wer...

  5. Broadband Infrared Heterodyne Spectrometer: Final Report

    SciTech Connect (OSTI)

    Stevens, C G; Cunningham, C T; Tringe, J W

    2010-12-16T23:59:59.000Z

    This report summarizes the most important results of our effort to develop a new class of infrared spectrometers based on a novel broadband heterodyne design. Our results indicate that this approach could lead to a near-room temperature operation with performance limited only by quantum noise carried by the incoming signal. Using a model quantum-well infrared photodetector (QWIP), we demonstrated key performance features of our approach. For example, we directly measured the beat frequency signal generated by superimposing local oscillator (LO) light of one frequency and signal light of another through a spectrograph, by injecting the LO light at a laterally displaced input location. In parallel with the development of this novel spectrometer, we modeled a new approach to reducing detector volume though plasmonic resonance effects. Since dark current scales directly with detector volume, this ''photon compression'' can directly lead to lower currents. Our calculations indicate that dark current can be reduced by up to two orders of magnitude in an optimized ''superlens'' structure. Taken together, our spectrometer and dark current reduction strategies provide a promising path toward room temperature operation of a mid-wave and possibly long-wave infrared spectrometer.

  6. Neutron spectrometer for fast nuclear reactors

    E-Print Network [OSTI]

    Osipenko, M; Ricco, G; Caiffi, B; Pompili, F; Pillon, M; Angelone, M; Verona-Rinati, G; Cardarelli, R; Mila, G; Argiro, S

    2015-01-01T23:59:59.000Z

    In this paper we describe the development and first tests of a neutron spectrometer designed for high flux environments, such as the ones found in fast nuclear reactors. The spectrometer is based on the conversion of neutrons impinging on $^6$Li into $\\alpha$ and $t$ whose total energy comprises the initial neutron energy and the reaction $Q$-value. The $^6$LiF layer is sandwiched between two CVD diamond detectors, which measure the two reaction products in coincidence. The spectrometer was calibrated at two neutron energies in well known thermal and 3 MeV neutron fluxes. The measured neutron detection efficiency varies from 4.2$\\times 10^{-4}$ to 3.5$\\times 10^{-8}$ for thermal and 3 MeV neutrons, respectively. These values are in agreement with Geant4 simulations and close to simple estimates based on the knowledge of the $^6$Li(n,$\\alpha$)$t$ cross section. The energy resolution of the spectrometer was found to be better than 100 keV when using 5 m cables between the detector and the preamplifiers.

  7. Neutron spectrometer for fast nuclear reactors

    E-Print Network [OSTI]

    M. Osipenko; M. Ripani; G. Ricco; B. Caiffi; F. Pompili; M. Pillon; M. Angelone; G. Verona-Rinati; R. Cardarelli; G. Mila; S. Argiro

    2015-05-25T23:59:59.000Z

    In this paper we describe the development and first tests of a neutron spectrometer designed for high flux environments, such as the ones found in fast nuclear reactors. The spectrometer is based on the conversion of neutrons impinging on $^6$Li into $\\alpha$ and $t$ whose total energy comprises the initial neutron energy and the reaction $Q$-value. The $^6$LiF layer is sandwiched between two CVD diamond detectors, which measure the two reaction products in coincidence. The spectrometer was calibrated at two neutron energies in well known thermal and 3 MeV neutron fluxes. The measured neutron detection efficiency varies from 4.2$\\times 10^{-4}$ to 3.5$\\times 10^{-8}$ for thermal and 3 MeV neutrons, respectively. These values are in agreement with Geant4 simulations and close to simple estimates based on the knowledge of the $^6$Li(n,$\\alpha$)$t$ cross section. The energy resolution of the spectrometer was found to be better than 100 keV when using 5 m cables between the detector and the preamplifiers.

  8. Study of elementary reactions with the HADES dielectron spectrometer

    E-Print Network [OSTI]

    B. Ramstein

    2009-12-14T23:59:59.000Z

    Results obtained with the HADES dielectron spectrometer at GSI are discussed, with emphasis on dilepton production in elementary reactions.

  9. Calibrations of a multichannel soft x-ray spectrometer

    SciTech Connect (OSTI)

    Blake, R.L.; Hockaday, R.G.; Grosso, J.S.

    1986-01-01T23:59:59.000Z

    A time resolved, 14 channel spectrometer with an absolutely calibrated response, was developed to cove an x-ray photon energy spectrum from 70 to 650 eV. The spectrometer utilized a combination of thin film prefilters, layered synthetic microstructure (LSM) diffractors, metal coated plastic scintillators, and photomultiplier detector tubes. Calibration of the spectrometer was done piecemeal for each component with standard techniques and the component calibrations were convolved to get a complete spectrometer response function. The two calibration procedures were compared.

  10. Development of Mossbauer spectrometer and it's application to characterization of

    E-Print Network [OSTI]

    FeCO3 Development of M¨ossbauer spectrometer and it's application to characterization of FeCO3 film #12; #12; FeCO3 Development of M¨ossbauer spectrometer and it. #12;#12;#12; Development of M¨ossbauer spectrometer and it's application to characterization of FeCO3

  11. Structural determination of intact proteins using mass spectrometry

    DOE Patents [OSTI]

    Kruppa, Gary (San Francisco, CA); Schoeniger, Joseph S. (Oakland, CA); Young, Malin M. (Livermore, CA)

    2008-05-06T23:59:59.000Z

    The present invention relates to novel methods of determining the sequence and structure of proteins. Specifically, the present invention allows for the analysis of intact proteins within a mass spectrometer. Therefore, preparatory separations need not be performed prior to introducing a protein sample into the mass spectrometer. Also disclosed herein are new instrumental developments for enhancing the signal from the desired modified proteins, methods for producing controlled protein fragments in the mass spectrometer, eliminating complex microseparations, and protein preparatory chemical steps necessary for cross-linking based protein structure determination.Additionally, the preferred method of the present invention involves the determination of protein structures utilizing a top-down analysis of protein structures to search for covalent modifications. In the preferred method, intact proteins are ionized and fragmented within the mass spectrometer.

  12. Mass spec : the biography of a scientific instrument

    E-Print Network [OSTI]

    Calmes, Jordan

    2011-01-01T23:59:59.000Z

    Over the past century, the mass spectrometer has become commonplace in scientific fields ranging from chemistry to geology to environmental science. Its ability to identify compounds and determine concentrations of those ...

  13. Acceptance and resolution simulation studies for the dielectron spectrometer HADES at GSI

    E-Print Network [OSTI]

    R. Schicker; A. Brenschede; K. Garrow; H. Schoen; A. Balanda; H. Bokemeyer; J. Friese; W. Karig; P. Kienle; W. Koenig; W. Kuehn; F. Lefevre; V. Metag; G. Roche; P. Salabura; A. Schroeter; J. Stroth; H. Tsertos

    1996-05-21T23:59:59.000Z

    Design studies for a second generation Dilepton Spectrometer to be built at the SIS accelerator of GSI are presented. The basic design parameters of this system are specified and the different detector components for charged particle tracking and for lepton identification are described. The geometrical acceptance for lepton pairs is given. Results on single track momentum resolution and on lepton pair mass resolution are reported.

  14. Associated Particle Tagging (APT) in Magnetic Spectrometers

    SciTech Connect (OSTI)

    Jordan, David V.; Baciak, James E.; Stave, Sean C.; Chichester, David; Dale, Daniel; Kim, Yujong; Harmon, Frank

    2012-10-16T23:59:59.000Z

    Summary In Brief The Associated Particle Tagging (APT) project, a collaboration of Pacific Northwest National Laboratory (PNNL), Idaho National Laboratory (INL) and the Idaho State University (ISU)/Idaho Accelerator Center (IAC), has completed an exploratory study to assess the role of magnetic spectrometers as the linchpin technology in next-generation tagged-neutron and tagged-photon active interrogation (AI). The computational study considered two principle concepts: (1) the application of a solenoidal alpha-particle spectrometer to a next-generation, large-emittance neutron generator for use in the associated particle imaging technique, and (2) the application of tagged photon beams to the detection of fissile material via active interrogation. In both cases, a magnetic spectrometer momentum-analyzes charged particles (in the neutron case, alpha particles accompanying neutron generation in the D-T reaction; in the tagged photon case, post-bremsstrahlung electrons) to define kinematic properties of the relevant neutral interrogation probe particle (i.e. neutron or photon). The main conclusions of the study can be briefly summarized as follows: Neutron generator: • For the solenoidal spectrometer concept, magnetic field strengths of order 1 Tesla or greater are required to keep the transverse size of the spectrometer smaller than 1 meter. The notional magnetic spectrometer design evaluated in this feasibility study uses a 5-T magnetic field and a borehole radius of 18 cm. • The design shows a potential for 4.5 Sr tagged neutron solid angle, a factor of 4.5 larger than achievable with current API neutron-generator designs. • The potential angular resolution for such a tagged neutron beam can be less than 0.5o for modest Si-detector position resolution (3 mm). Further improvement in angular resolution can be made by using Si-detectors with better position resolution. • The report documents several features of a notional generator design incorporating the alpha-particle spectrometer concept, and outlines challenges involved in the magnetic field design. Tagged photon interrogation: • We investigated a method for discriminating fissile from benign cargo-material response to an energy-tagged photon beam. The method relies upon coincident detection of the tagged photon and a photoneutron or photofission neutron produced in the target material. The method exploits differences in the shape of the neutron production cross section as a function of incident photon energy in order to discriminate photofission yield from photoneutrons emitted by non-fissile materials. Computational tests of the interrogation method as applied to material composition assay of a simple, multi-layer target suggest that the tagged-photon information facilitates precise (order 1% thickness uncertainty) reconstruction of the constituent thicknesses of fissile (uranium) and high-Z (Pb) constituents of the test targets in a few minutes of photon-beam exposure. We assumed an 18-MeV endpoint tagged photon beam for these simulations. • The report addresses several candidate design and data analysis issues for beamline infrastructure required to produce a tagged photon beam in a notional AI-dedicated facility, including the accelerator and tagging spectrometer.

  15. Neutron spectrometer for improved SNM search.

    SciTech Connect (OSTI)

    Vance, Andrew L.; Aigeldinger, Georg

    2007-03-01T23:59:59.000Z

    With the exception of large laboratory devices with very low sensitivities, a neutron spectrometer have not been built for fission neutrons such as those emitted by special nuclear materials (SNM). The goal of this work was to use a technique known as Capture Gated Neutron Spectrometry to develop a solid-state device with this functionality. This required modifications to trans-stilbene, a known solid-state scintillator. To provide a neutron capture signal we added lithium to this material. This unique triggering signal allowed identification of neutrons that lose all of their energy in the detector, eliminating uncertainties that arise due to partial energy depositions. We successfully implemented a capture gated neutron spectrometer and were able to distinguish an SNM like fission spectrum from a spectrum stemming from a benign neutron source.

  16. Imaging spectrometer wide field catadioptric design

    DOE Patents [OSTI]

    Chrisp; Michael P. (Danville, CA)

    2008-08-19T23:59:59.000Z

    A wide field catadioptric imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The catadioptric design has zero Petzval field curvature. The imaging spectrometer comprises an entrance slit for transmitting light, a system with a catadioptric lens and a dioptric lens for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the system for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the system for receiving the light and the system for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light through the system for receiving the light to the detector array.

  17. Compact imaging spectrometer utilizing immersed gratings

    DOE Patents [OSTI]

    Chrisp, Michael P. (Danville, CA); Lerner, Scott A. (Corvallis, OR); Kuzmenko, Paul J. (Livermore, CA); Bennett, Charles L. (Livermore, CA)

    2007-07-03T23:59:59.000Z

    A compact imaging spectrometer with an immersive diffraction grating that compensates optical distortions. The imaging spectrometer comprises an entrance slit for transmitting light, means for receiving the light and directing the light, an immersion grating, and a detector array. The entrance slit, the means for receiving the light, the immersion grating, and the detector array are positioned wherein the entrance slit transmits light to the means for receiving the light and the means for receiving the light directs the light to the immersion grating and the immersion grating receives the light and directs the light to the means for receiving the light, and the means for receiving the light directs the light to the detector array.

  18. Progress on the Fabrication and Testing of the MICE Spectrometer Solenoids

    SciTech Connect (OSTI)

    Virostek, Steve; Green, M.A.; Li, Derun; Zisman, Michael

    2009-05-19T23:59:59.000Z

    The Muon Ionization Cooling Experiment (MICE) is an international collaboration that will demonstrate ionization cooling in a section of a realistic cooling channel using a muon beam at Rutherford Appleton Laboratory (RAL) in the UK. At each end of the cooling channel a spectrometer solenoid magnet consisting of five superconducting coils will provide a 4 tesla uniform field region. The scintillating fiber tracker within the magnet bore will measure the muon beam emittance as it enters and exits the cooling channel. The 400 mm diameter warm bore, 3 meter long magnets incorporate a cold mass consisting of two coil sections wound on a single aluminum mandrel: a three-coil spectrometer magnet and a two-coil section that matches the solenoid uniform field into the MICE cooling channel. The fabrication of the first of two spectrometer solenoids has been completed, and preliminary testing of the magnet is nearly complete. The key design features of the spectrometer solenoid magnets are presented along with a summary of the progress on the training and testing of the first magnet.

  19. Lead Slowing Down Spectrometer Status Report

    SciTech Connect (OSTI)

    Warren, Glen A.; Anderson, Kevin K.; Bonebrake, Eric; Casella, Andrew M.; Danon, Yaron; Devlin, M.; Gavron, Victor A.; Haight, R. C.; Imel, G. R.; Kulisek, Jonathan A.; O'Donnell, J. M.; Weltz, Adam

    2012-06-07T23:59:59.000Z

    This report documents the progress that has been completed in the first half of FY2012 in the MPACT-funded Lead Slowing Down Spectrometer project. Significant progress has been made on the algorithm development. We have an improve understanding of the experimental responses in LSDS for fuel-related material. The calibration of the ultra-depleted uranium foils was completed, but the results are inconsistent from measurement to measurement. Future work includes developing a conceptual model of an LSDS system to assay plutonium in used fuel, improving agreement between simulations and measurement, design of a thorium fission chamber, and evaluation of additional detector techniques.

  20. Dual waveband compact catadioptric imaging spectrometer

    DOE Patents [OSTI]

    Chrisp, Michael P.

    2012-12-25T23:59:59.000Z

    A catadioptric dual waveband imaging spectrometer that covers the visible through short-wave infrared, and the midwave infrared spectral regions, dispersing the visible through shortwave infrared with a zinc selenide grating and midwave infrared with a sapphire prism. The grating and prism are at the cold stop position, enabling the pupil to be split between them. The spectra for both wavebands are focused onto the relevant sections of a single dual waveband detector. Spatial keystone distortion is controlled to less than one tenth of a pixel over the full wavelength range, facilitating the matching of the spectra in the midwave infrared with the shorter wavelength region.

  1. 140 GHz pulsed Fourier transform microwave spectrometer

    DOE Patents [OSTI]

    Kolbe, W.F.; Leskovar, B.

    1985-07-29T23:59:59.000Z

    A high frequency energy pulsing system suitable for use in a pulsed microwave spectrometer, including means for generating a high frequency carrier signal, and means for generating a low frequency modulating signal. The carrier signal is continuously fed to a modulator and the modulating signal is fed through a pulse switch to the modulator. When the pulse switch is on, the modulator will produce sideband signals above and below the carrier signal frequency. A frequency-responsive device is tuned to one of the sideband signals and sway from the carrier frequency so that the high frequency energization of the frequency-responsive device is controlled by the pulse switch.

  2. Micro-optical-mechanical system photoacoustic spectrometer

    DOE Patents [OSTI]

    Kotovsky, Jack; Benett, William J.; Tooker, Angela C.; Alameda, Jennifer B.

    2013-01-01T23:59:59.000Z

    All-optical photoacoustic spectrometer sensing systems (PASS system) and methods include all the hardware needed to analyze the presence of a large variety of materials (solid, liquid and gas). Some of the all-optical PASS systems require only two optical-fibers to communicate with the opto-electronic power and readout systems that exist outside of the material environment. Methods for improving the signal-to-noise are provided and enable mirco-scale systems and methods for operating such systems.

  3. Ion mobility spectrometer with virtual aperture grid

    DOE Patents [OSTI]

    Pfeifer, Kent B. (Los Lunas, NM); Rumpf, Arthur N. (Albuquerque, NM)

    2010-11-23T23:59:59.000Z

    An ion mobility spectrometer does not require a physical aperture grid to prevent premature ion detector response. The last electrodes adjacent to the ion collector (typically the last four or five) have an electrode pitch that is less than the width of the ion swarm and each of the adjacent electrodes is connected to a source of free charge, thereby providing a virtual aperture grid at the end of the drift region that shields the ion collector from the mirror current of the approaching ion swarm. The virtual aperture grid is less complex in assembly and function and is less sensitive to vibrations than the physical aperture grid.

  4. What Caused the Lead burn-out in Spectrometer Magnet 2B

    SciTech Connect (OSTI)

    Green, Michael A

    2010-11-29T23:59:59.000Z

    The spectrometer solenoids are supposed to be the first magnets installed in the MICE Cooling Channel. The results of the test of Spectrometer Magnet 2B are reported in a previous MICE Note. Magnet 2B was tested with all five coils connected in series. The magnet failed because a lead to coil M2 failed before it could be trained to its full design current of 275 A. First, this report describes the condition of the magnet when the lead failure occurred. The lead that failed was between the cold mass feed-through and the heavy lead that connected to coil M2 and the quench protection diodes. It is believed that the lead failed because the minimum propagation zone (MPZ) length was too short. The quench was probably triggered by lead motion in the field external to the magnet center coil. The effect of heat transfer on quench propagation and MPZ length is discussed. The MPZ length is compared for a number of cases that apply to the spectrometer solenoid 2B as built and as it has been repaired. The required heat transfer coefficient for cryogenic stability and the quench propagation velocity along the leads are compared for various parts of the Magnet leads inside the cold mass cryostat. The effect of the insulation on leads on heat transfer is and stability is discussed.

  5. alpha spectrometers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flight CERN Preprints Summary: The Alpha Magnetic Spectrometer (AMS) is a particle detector designed to detect antimatter. During the 10-day test flight on the space shuttle in...

  6. atomic emission spectrometer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: Characterization of Tropospheric Emission Spectrometer (TES) CO2 for carbon cycle science Susan footprint ave ** Crevoisier et al., 2009 0.22K error at 700...

  7. antiparticle spectrometer gaps: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next Page Last Page Topic Index 1 The General Antiparticle Spectrometer (GAPS) - Hunt for dark matter using low-energy antideuterons CERN Preprints Summary: The GAPS experiment is...

  8. alpha magnetic spectrometer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    23 24 25 Next Page Last Page Topic Index 1 Testing and Final Construction of the Superconducting Magnet for the Alpha Magnetic Spectrometer MIT - DSpace Summary: The Alpha...

  9. Ultra-high-mass mass spectrometry with charge discrimination using cryogenic detectors

    DOE Patents [OSTI]

    Frank, Matthias (Berkeley, CA); Mears, Carl A. (Oakland, CA); Labov, Simon E. (Berkeley, CA); Benner, W. Henry (Danville, CA)

    1999-01-01T23:59:59.000Z

    An ultra-high-mass time-of-flight mass spectrometer using a cryogenic particle detector as an ion detector with charge discriminating capabilities. Cryogenic detectors have the potential for significantly improving the performance and sensitivity of time-of-flight mass spectrometers, and compared to ion multipliers they exhibit superior sensitivity for high-mass, slow-moving macromolecular ions and can be used as "stop" detectors in time-of-flight applications. In addition, their energy resolving capability can be used to measure the charge state of the ions. Charge discrimination is very valuable in all time-of-flight mass spectrometers. Using a cryogenically-cooled Nb-Al.sub.2 O.sub.3 -Nb superconductor-insulator-superconductor (SIS) tunnel junction (STJ) detector operating at 1.3 K as an ion detector in a time-of-flight mass spectrometer for large biomolecules it was found that the STJ detector has charge discrimination capabilities. Since the cryogenic STJ detector responds to ion energy and does not rely on secondary electron production, as in the conventionally used microchannel plate (MCP) detectors, the cryogenic detector therefore detects large molecular ions with a velocity-independent efficiency approaching 100%.

  10. Partition coefficients of chalcophile elements between sulfide and silicate melts and the early crystallization history of sulfide liquid: LA-ICP-MS

    E-Print Network [OSTI]

    the crystallization history of the sulfide liquid is ignored in most studies. Here we present laser ablation

  11. Measurement of water-soluble arsenic species in freeze-dried marine animal tissues by microwave-assisted extraction and HPLC-ICP-MS

    E-Print Network [OSTI]

    Canberra, University of

    Article on the web 8th July 2002 A microwave-assisted procedure is outlined for the extraction of water extractions with 50% (v/v) methanol­ water at 70 to 75 uC for 5 min. Quantitative extraction of arsenic samples are prepared in a similar manner, the efficiency to extract arsenic in the methanol­water soluble

  12. Heterogeneous Chemistry of Individual Mineral Dust Particles with Nitric Acid. A Combined CCSEM/EDX, ESEM AND ICP-MS Study

    SciTech Connect (OSTI)

    Laskin, Alexander; Wietsma, Thomas W.; Krueger, Brenda J.; Grassian, Vicki H.

    2005-05-26T23:59:59.000Z

    The heterogeneous chemistry of individual dust particles from four authentic dust samples with gas-phase nitric acid was investigated in this study. Morphology and compositional changes of individual particles as they react with nitric acid were observed using conventional scanning electron microscopy with energy dispersive analysis of X-rays (SEM/EDX) and computer controlled SEM/EDX. Environmental Scanning Electron Microscopy (ESEM) was utilized to investigate the hygroscopic behavior of mineral dust particles reacted with nitric acid. Differences in the reactivity of mineral dust particles from these four different dust source regions with nitric acid were observed. Mineral dust from source regions containing high levels of calcium, namely China loess dust and Saudi coastal dust, were found to react to the greatest extent.

  13. A laser-ablation ICP-MS study of Apollo 15 low-titanium olivine-normative and quartz-normative mare basalts

    E-Print Network [OSTI]

    Perfect, Ed

    differences in the mantle source to explain the $25% difference in whole-rock TiO2, and corresponding-normative basalt types, based on their different SiO2, FeO, and TiO2 whole-rock compositions. Previous studies have as originating from different lunar mantle source regions. To provide new information on the compositions

  14. Spectrometer for new gravitational experiment with UCN

    E-Print Network [OSTI]

    Kulin, G V; Goryunov, S V; Kustov, D V; Geltenbort, P; Jentschel, M; Strepetov, A N; Bushuev, V A

    2015-01-01T23:59:59.000Z

    We describe an experimental installation for a new test of the weak equivalence principle for neutron. The device is a sensitive gravitational spectrometer for ultra-cold neutrons allowing to precisely compare the gain in kinetic energy of free falling neutrons to quanta of energy ${\\hbar}{\\Omega}$ transferred to the neutron via a non stationary device, i.e. a quantum modulator. The results of first test experiments indicate a collection rate allowing measurements of the factor of equivalence $ { \\gamma}$ with a statistical uncertainty in the order of $5{\\times}10^{-3}$ per day. A number of systematic effects were found, which partially can be easily corrected. For the elimination of others more detailed investigations and analysis are needed. Some possibilities to improve the device are also discussed.

  15. 140 GHz pulsed Fourier transform microwave spectrometer

    DOE Patents [OSTI]

    Kolbe, W.F.; Leskovar, B.

    1987-10-27T23:59:59.000Z

    A high frequency energy pulsing system suitable for use in a pulsed microwave spectrometer, including means for generating a high frequency carrier signal, and means for generating a low frequency modulating signal is disclosed. The carrier signal is continuously fed to a modulator and the modulating signal is fed through a pulse switch to the modulator. When the pulse switch is on, the modulator will produce sideband signals above and below the carrier signal frequency. A frequency-responsive device is tuned to one of the sideband signals and away from the carrier frequency so that the high frequency energization of the frequency-responsive device is controlled by the pulse switch. 5 figs.

  16. 140 GHz pulsed fourier transform microwave spectrometer

    DOE Patents [OSTI]

    Kolbe, William F. (Oakland, CA); Leskovar, Branko (Moraga, CA)

    1987-01-01T23:59:59.000Z

    A high frequency energy pulsing system suitable for use in a pulsed microwave spectrometer (10), including means (11, 19) for generating a high frequency carrier signal, and means (12) for generating a low frequency modulating signal. The carrier signal is continuously fed to a modulator (20) and the modulating signal is fed through a pulse switch (23) to the modulator. When the pulse switch (23) is on, the modulator (20) will produce sideband signals above and below the carrier signal frequency. A frequency-responsive device (31) is tuned to one of the sideband signals and away from the carrier frequency so that the high frequency energization of the frequency-responsive device (31) is controlled by the pulse switch (23).

  17. An improved selective excitation double Mossbauer spectrometer J. van Lieropa)

    E-Print Network [OSTI]

    Ryan, Dominic

    An improved selective excitation double Mo¨ssbauer spectrometer J. van Lieropa) and D. H. Ryan, operation and performance of a selective excitation double Mo¨ssbauer SEDM spectrometer are described circuitry together with Wissel Mo¨ssbauer velocity transducers and electronics supplies energy

  18. MICROMACHINED FOURIER TRANSFORM SPECTROMETER ON SILICON OPTICAL BENCH PLATFORM

    E-Print Network [OSTI]

    Park, Namkyoo

    MICROMACHINED FOURIER TRANSFORM SPECTROMETER ON SILICON OPTICAL BENCH PLATFORM Kyoungsik Yu1 a miniaturized Fourier transform spectrometer implemented on a silicon optical bench platform. The optical-etching. A spectral resolution of 45 nm near 1550 nm wavelength is demonstrated. Keywords: Fourier transform

  19. In situ calibration of inductively coupled plasma-atomic emission and mass spectroscopy

    DOE Patents [OSTI]

    Braymen, Steven D. (Ames, IA)

    1996-06-11T23:59:59.000Z

    A method and apparatus for in situ addition calibration of an inductively coupled plasma atomic emission spectrometer or mass spectrometer using a precision gas metering valve to introduce a volatile calibration gas of an element of interest directly into an aerosol particle stream. The present situ calibration technique is suitable for various remote, on-site sampling systems such as laser ablation or nebulization.

  20. LANL/Green Star spectrometer tests

    SciTech Connect (OSTI)

    Sampson, T.E.; Cremers, T.L.; Vo, D.T. [Los Alamos National Lab., NM (United States); Seldiakov, Y.P.; Dorin, A.B.; Kondrashov, M.V. [Green Star, Moscow (Russian Federation); Timoshin, V.I. [VNIINM, Moscow (Russian Federation)

    1997-12-01T23:59:59.000Z

    The US and Russia have agreed to the joint development of a nondestructive assay system for use to support the dismantlement of nuclear weapons in Russia. This nondestructive assay system will be used to measure plutonium produced by the conversion of Russian nuclear weapons. The NDA system for Russia will be patterned after the ARIES NDA system being constructed at Los Alamos. One goal of the program is to produce an NDA system for use in Russia that maximizes the use of Russian resources to facilitate maintenance and future upgrades. The Green Star SBS50 Single Board Spectrometer system (Green Star Ltd., Moscow, Russia) has been suggested for use as the data acquisition component for gamma ray instruments in the system. Possible uses are for plutonium isotopic analysis and also segmented gamma scanning. Green Star has also developed analysis software for the SBS50. This software, both plutonium isotopic analysis and uranium enrichment analysis, was developed specifically for customs/border inspection applications (low counting rate applications and identification as opposed to quantification) and was not intended for MC and A applications. Because of the relative immaturity of the Green Star plutonium isotopic analysis software (it has been under development for only one year and is patterned after US development circa 1980), it was tentatively agreed, before the tests, that the Russian NDA system would use the Los Alamos PC/FRAM software for plutonium isotopic analysis. However, it was also decided to include the Green Star plutonium isotopic software in the testing, both to quantify its performance for MC and A applications and also to provide additional data to Green Star for further development of their software. The main purpose of the testing was to evaluate the SBS-50 spectrometer as a data acquisition device for use with LANL software.

  1. Ion mobility spectrometer, spectrometer analyte detection and identification verification system, and method

    DOE Patents [OSTI]

    Atkinson, David A. (Idaho Falls, ID)

    2002-01-01T23:59:59.000Z

    Methods and apparatus for ion mobility spectrometry and analyte detection and identification verification system are disclosed. The apparatus is configured to be used in an ion mobility spectrometer and includes a plurality of reactant reservoirs configured to contain a plurality of reactants which can be reacted with the sample to form adducts having varying ion mobilities. A carrier fluid, such as air or nitrogen, is used to carry the sample into the spectrometer. The plurality of reactants are configured to be selectively added to the carrier stream by use inlet and outlet manifolds in communication with the reagent reservoirs, the reservoirs being selectively isolatable by valves. The invention further includes a spectrometer having the reagent system described. In the method, a first reactant is used with the sample. Following a positive result, a second reactant is used to determine whether a predicted response occurs. The occurrence of the second predicted response tends to verify the existence of a component of interest within the sample. A third reactant can also be used to provide further verification of the existence of a component of interest. A library can be established of known responses of compounds of interest with various reactants and the results of a specific multi-reactant survey of a sample can be compared against the library to determine whether a component detected in the sample is likely to be a specific component of interest.

  2. A study of the mass discrimination properties of the palletron

    E-Print Network [OSTI]

    Hallmark, Glen D.

    1953-01-01T23:59:59.000Z

    A STUDY OF THE MASS DISCRIMINATION PROPERTIES OF THE PALLETRON A Dissertation By Glen D. Hallmark June 1953 Approved as to style and content by Head of Departme A STUDY OF THE MASS DISCRIMINATION PROPERTIES OF THE PALLETRON A Dissertation... Cylindrical Electrode System . . 58 16. Photograph of Arrangement of Equipment . . . . . . . 60 A STUDY OF THE IviASS DISCRIMINATION PROPERTIES OF THE PALLETRON INTRODUCTION A mass spectrometer is an instrument that may be used to measure the masses...

  3. SWEPP gamma-ray spectrometer system software test plan and report

    SciTech Connect (OSTI)

    Femec, D.A.

    1994-09-01T23:59:59.000Z

    The SWEPP Gamma-Ray Spectrometer (SGRS) System has been developed by the Radiation Measurements and Development Unit of the Idaho National Engineering Laboratory to assist in the characterization of the radiological contents of contact-handled waste containers at the Stored Waste Examination Pilot Plant (SWEPP). In addition to determining the concentrations of gamma-ray-emitting radionuclides, the software also calculates attenuation-corrected isotopic mass ratios of specific interest, and provides controls for SGRS hardware as required. This document presents the test plan and report for the data acquisition and analysis software associated with the SGRS system.

  4. Improving the resolution of chopper spectrometers at pulsed neutron sources

    SciTech Connect (OSTI)

    Carpenter, J.M. (Argonne National Lab., IL (USA)); Mildner, D.F.R. (National Bureau of Standards, Washington, DC (USA). Center for Analytical Chemistry)

    1990-01-01T23:59:59.000Z

    We examine the relationships between intensity and resolution in pulsed-source chopper spectrometers, including the effects of Soller collimation, narrower rotor slits and higher rotor speeds. The basis is a simplified description of a spectrometer, approximately optimizing the rotor pulse and lighthouse effects. the analysis includes a new treatment of the angular distribution transmitted through a system consisting of a coarse collimator and a Soller collimator. The results encourage the prospect for a reasonably easily accomplished, higher resolution, optional configuration of the pulsed source chopper spectrometers at IPNS. 6 refs., 5 figs.

  5. The EUV Imaging Spectrometer for Hinode

    SciTech Connect (OSTI)

    Culhane,J.; Harra, L.; James, A.; Al-Janabi, K.; Bradley, L.; Chaudry, R.; Rees, K.; Tandy, J.; Thomas, P.; et al

    2007-01-01T23:59:59.000Z

    The EUV Imaging Spectrometer (EIS) on Hinode will observe solar corona and upper transition region emission lines in the wavelength ranges 170?-?210 Angstroms and 250?-?290 Angstroms . The line centroid positions and profile widths will allow plasma velocities and turbulent or non-thermal line broadenings to be measured. We will derive local plasma temperatures and densities from the line intensities. The spectra will allow accurate determination of differential emission measure and element abundances within a variety of corona and transition region structures. These powerful spectroscopic diagnostics will allow identification and characterization of magnetic reconnection and wave propagation processes in the upper solar atmosphere. We will also directly study the detailed evolution and heating of coronal loops. The EIS instrument incorporates a unique two element, normal incidence design. The optics are coated with optimized multilayer coatings. We have selected highly efficient, backside-illuminated, thinned CCDs. These design features result in an instrument that has significantly greater effective area than previous orbiting EUV spectrographs with typical active region 2?-?5 s exposure times in the brightest lines. EIS can scan a field of 6x8.5 arc?min with spatial and velocity scales of 1 arc?sec and 25 km?s-1 per pixel. The instrument design, its absolute calibration, and performance are described in detail in this paper. EIS will be used along with the Solar Optical Telescope (SOT) and the X-ray Telescope (XRT) for a wide range of studies of the solar atmosphere.

  6. A study of the tropospheric oxidation of volatile organic compounds using chemical ionization mass spectrometry

    E-Print Network [OSTI]

    Broekhuizen, Keith Edward, 1974-

    2002-01-01T23:59:59.000Z

    The mechanisms and kinetics of reactions important to the troposphere have been investigated using a high pressure, turbulent, discharge-flow technique coupled to a chemical ionization mass spectrometer. The ability to ...

  7. Elemental ratio measurements of organic compounds using aerosol mass spectrometry: characterization, improved calibration, and implications

    E-Print Network [OSTI]

    Canagaratna, M. R.

    Elemental compositions of organic aerosol (OA) particles provide useful constraints on OA sources, chemical evolution, and effects. The Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS) is ...

  8. Organic aerosol components observed in Northern Hemispheric datasets from Aerosol Mass Spectrometry

    E-Print Network [OSTI]

    Kroll, Jesse

    In this study we compile and present results from the factor analysis of 43 Aerosol Mass Spectrometer (AMS) datasets (27 of the datasets are reanalyzed in this work). The components from all sites, when taken together, ...

  9. Determination of particulate lead using aerosol mass spectrometry: MILAGRO/MCMA-2006 observations

    E-Print Network [OSTI]

    Salcedo, D.

    We report the first measurements of particulate lead (Pb) from Aerodyne Aerosol Mass Spectrometers, which were deployed in and around Mexico City during the Megacity Initiative: Local and Global Research Observations ...

  10. Ion spectrometer composed of time-of-flight and Thomson parabola spectrometers for simultaneous characterization of laser-driven ions

    SciTech Connect (OSTI)

    Choi, I. W.; Kim, C. M.; Sung, J. H.; Yu, T. J.; Lee, S. K.; Kim, I. J.; Jin, Y.-Y.; Jeong, T. M.; Hafz, N.; Pae, K. H.; Noh, Y.-C.; Ko, D.-K.; Lee, J. [Advanced Photonics Research Institute and Center for Femto-Atto Science and Technology, GIST, Gwangju 500-712 (Korea, Republic of); Yogo, A.; Pirozhkov, A. S.; Ogura, K.; Orimo, S.; Sagisaka, A.; Nishiuchi, M.; Daito, I. [Advanced Photon Research Center and Photo Medical Research Center, Japan Atomic Energy Agency, Kizugawa, Kyoto 619-0215 (Japan); and others

    2009-05-15T23:59:59.000Z

    An ion spectrometer, composed of a time-of-flight spectrometer (TOFS) and a Thomson parabola spectrometer (TPS), has been developed to measure energy spectra and to analyze species of laser-driven ions. Two spectrometers can be operated simultaneously, thereby facilitate to compare the independently measured data and to combine advantages of each spectrometer. Real-time and shot-to-shot characterizations have been possible with the TOFS, and species of ions can be analyzed with the TPS. The two spectrometers show very good agreement of maximum proton energy even for a single laser shot. The composite ion spectrometer can provide two complementary spectra measured by TOFS with a large solid angle and TPS with a small one for the same ion source, which are useful to estimate precise total ion number and to investigate fine structure of energy spectrum at high energy depending on the detection position and solid angle. Advantage and comparison to other online measurement system, such as the TPS equipped with microchannel plate, are discussed in terms of overlay of ion species, high-repetition rate operation, detection solid angle, and detector characteristics of imaging plate.

  11. Tritium--helium-3 mass difference using the Penning trap mass spectroscopy

    SciTech Connect (OSTI)

    Van Dyck, R.S. Jr.; Farnham, D.L.; Schwinberg, P.B. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1993-05-10T23:59:59.000Z

    The atomic masses of both [sup 3]H and [sup 3]He have been measured with a Penning trap mass spectrometer that utilizes a frequency-shift detector to observe ion cyclotron resonances. Present resolution exceeds 1 part in 10[sup 9] and is limited only by the stability of the magnetic field. The leading systematic shift (at [approx lt]1 part in 10[sup 10]) is due to the residual quadratic [bold B] field dependence. The atomic masses have been combined to yield [Delta][ital Mc][sup 2]([sup 3]H[minus][sup 3]He)=18 590.1(1.7) eV. The excellent agreement with recent results from [beta] spectrometers lends strong support for new limits on the neutrino's rest mass.

  12. An Analysis of Nuclear Fuel Burnup in the AGR 1 TRISO Fuel Experiment Using Gamma Spectrometry, Mass Spectrometry, and Computational Simulation Techniques

    SciTech Connect (OSTI)

    Jason M. Harp; Paul A. Demkowicz; Phillip L. Winston; James W. Sterbentz

    2014-10-01T23:59:59.000Z

    AGR 1 was the first in a series of experiments designed to test US TRISO fuel under high temperature gas-cooled reactor irradiation conditions. This experiment was irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) and is currently undergoing post irradiation examination (PIE) at INL and Oak Ridge National Laboratory. One component of the AGR 1 PIE is the experimental evaluation of the burnup of the fuel by two separate techniques. Gamma spectrometry was used to non destructively evaluate the burnup of all 72 of the TRISO fuel compacts that comprised the AGR 1 experiment. Two methods for evaluating burnup by gamma spectrometry were developed, one based on the Cs 137 activity and the other based on the ratio of Cs 134 and Cs 137 activities. Burnup values determined from both methods compared well with the values predicted from simulations. The highest measured burnup was 20.1 %FIMA for the direct method and 20.0 %FIMA for the ratio method (compared to 19.56% FIMA from simulations). An advantage of the ratio method is that the burnup of the cylindrical fuel compacts can determined in small (2.5 mm) axial increments and an axial burnup profile can be produced. Destructive chemical analysis by inductively coupled mass spectrometry (ICP MS) was then performed on selected compacts that were representative of the expected range of fuel burnups in the experiment to compare with the burnup values determined by gamma spectrometry. The compacts analyzed by mass spectrometry had a burnup range of 19.3 % FIMA to 10.7 % FIMA. The mass spectrometry evaluation of burnup for the four compacts agreed well with the gamma spectrometry burnup evaluations and the expected burnup from simulation. For all four compacts analyzed by mass spectrometry, the maximum range in the three experimentally determined values and the predicted value was 6% or less. The results confirm the accuracy of the nondestructive burnup evaluation from gamma spectrometry for TRISO fuel compacts across a burnup range of approximately 10 to 20 % FIMA and also validate the approach used in the physics simulation of the AGR 1 experiment.

  13. Tunable light source for use in photoacoustic spectrometers

    DOE Patents [OSTI]

    Bisson, Scott E.; Kulp, Thomas J.; Armstrong, Karla M.

    2005-12-13T23:59:59.000Z

    The present invention provides a photoacoustic spectrometer that is field portable and capable of speciating complex organic molecules in the gas phase. The spectrometer has a tunable light source that has the ability to resolve the fine structure of these molecules over a large wavelength range. The inventive light source includes an optical parametric oscillator (OPO) having combined fine and coarse tuning. By pumping the OPO with the output from a doped-fiber optical amplifier pumped by a diode seed laser, the inventive spectrometer is able to speciate mixtures having parts per billion of organic compounds, with a light source that has a high efficiency and small size, allowing for portability. In an alternative embodiment, the spectrometer is scanned by controlling the laser wavelength, thus resulting in an even more compact and efficient design.

  14. Design and Simulation of a Boron-loaded Neutron Spectrometer

    E-Print Network [OSTI]

    Martin, Thomas

    2012-10-19T23:59:59.000Z

    spectrometer, consisting of plastic scintillating fibers in a hexagonal array, was simulated via Monte Carlo. Fiber size and boron content were varied to optimize response characteristics. The results were compared to industry standard multi...

  15. airborne imaging spectrometer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ADC dynamic range, because the low-energy pulse signal has a larger gain than the high-energy pulse signal. The spectrometer can clearly distinguish the photopeaks at 239, 352,...

  16. TRACES Centre Thermo GFS35 Graphite Furnace Spectrometer

    E-Print Network [OSTI]

    Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

    TRACES Centre Thermo GFS35 Graphite Furnace Spectrometer Standard Operating Procedure 1. Turn. Click on the lamp icon a. ID the lamp of choice and click the `Off' button to `On' b. Non-Thermo lamps

  17. TRACES Centre Thermo iCE 3500 Flame AA Spectrometer

    E-Print Network [OSTI]

    Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

    TRACES Centre Thermo iCE 3500 Flame AA Spectrometer Standard Operating Procedure 1. Turn on the lamp icon a. ID the lamp of choice and click the `Off' button to `On' b. Non-Thermo lamps MUST

  18. The FIRE infrared spectrometer at Magellan: construction and commissioning

    E-Print Network [OSTI]

    Simcoe, Robert A.

    We describe the construction and commissioning of FIRE, a new 0.8-2.5?m echelle spectrometer for the Magellan/ Baade 6.5 meter telescope. FIRE delivers continuous spectra over its full bandpass with nominal spectral ...

  19. Diamond neutral particle spectrometer for fusion reactor ITER

    SciTech Connect (OSTI)

    Krasilnikov, V.; Amosov, V.; Kaschuck, Yu.; Skopintsev, D. [Institution PROJECT CENTER ITER, 1, Akademik Kurchatov Sq., Moscow (Russian Federation)

    2014-08-21T23:59:59.000Z

    A compact diamond neutral particle spectrometer with digital signal processing has been developed for fast charge-exchange atoms and neutrons measurements at ITER fusion reactor conditions. This spectrometer will play supplementary role for Neutral Particle Analyzer providing 10 ms time and 30 keV energy resolutions for fast particle spectra in non-tritium ITER phase. These data will also be implemented for independent studies of fast ions distribution function evolution in various plasma scenarios with the formation of a single fraction of high-energy ions. In tritium ITER phase the DNPS will measure 14 MeV neutrons spectra. The spectrometer with digital signal processing can operate at peak counting rates reaching a value of 10{sup 6} cps. Diamond neutral particle spectrometer is applicable to future fusion reactors due to its high radiation hardness, fast response and high energy resolution.

  20. atomic absorption spectrometer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption spectrometer First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Educational Multiwavelength...

  1. C-III flow measurements with a coherence imaging spectrometer

    SciTech Connect (OSTI)

    Weber, T. R.; Allen, S. L. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Howard, J. [Australian National University, Canberra, ACT 0200 (Australia)

    2012-10-15T23:59:59.000Z

    This work describes a coherence imaging spectrometer capable of making spatially resolved CIII flow measurements in the DIII-D lower divertor. The spectrometer exploits a periscope view of the plasma to produce line-of-sight averaged velocity measurements of CIII. From these chord averaged flow measurements, a 2D poloidal cross section of the CIII flow is tomographically reconstructed. Details of the diagnostic setup, acquired data, and data analysis will be presented, along with prospects for future applications.

  2. Apparatus and methods for continuous beam fourier transform mass spectrometry

    DOE Patents [OSTI]

    McLuckey, Scott A. (Oak Ridge, TN); Goeringer, Douglas E. (Oak Ridge, TN)

    2002-01-01T23:59:59.000Z

    A continuous beam Fourier transform mass spectrometer in which a sample of ions to be analyzed is trapped in a trapping field, and the ions in the range of the mass-to-charge ratios to be analyzed are excited at their characteristic frequencies of motion by a continuous excitation signal. The excited ions in resonant motions generate real or image currents continuously which can be detected and processed to provide a mass spectrum.

  3. Lead Slowing Down Spectrometer Research Plans

    SciTech Connect (OSTI)

    Warren, Glen A.; Kulisek, Jonathan A.; Gavron, Victor; Danon, Yaron; Weltz, Adam; Harris, Jason; Stewart, T.

    2013-03-22T23:59:59.000Z

    The MPACT-funded Lead Slowing Down Spectrometry (LSDS) project has been evaluating the feasibility of using LSDS techniques to assay fissile isotopes in used nuclear fuel assemblies. The approach has the potential to provide considerable improvement in the assay of fissile isotopic masses in fuel assemblies compared to other non-destructive techniques in a direct and independent manner. The LSDS collaborations suggests that the next step to in empirically testing the feasibility is to conduct measurements on fresh fuel assemblies to understand investigate self-attenuation and fresh mixed-oxide (MOX) fuel rodlets so we may betterto understand extraction of masses for 235U and 239Pu. While progressing toward these goals, the collaboration also strongly suggests the continued development of enabling technology such as detector development and algorithm development, thatwhich could provide significant performance benefits.

  4. Preliminary results from the lunar prospector alpha particle spectrometer

    SciTech Connect (OSTI)

    Lawson, S. L. (Stefanie L.)

    2001-01-01T23:59:59.000Z

    The Lunar Prospector Alpha Particle Spectrometer (LP APS) builds on Apollo heritage and maps the distribution of outgassing sites on the Moon. The APS searches for lunar surface gas release events and maps their distribution by detecting alpha particles produced by the decay of gaseous radon-222 (5.5 MeV, 3.8 day half-life) and solid polonium-210 (5.3 MeV, 138 day half-life, but remains on the surface with a 21 year half-life as lead-210), which are radioactive daughters from the decay of uranium-238. Radon is in such small quantities that it is not released directly from the lunar interior, rather it is entrained in a stream of gases and serves as a tracer for such gases. Once released, the radon spreads out by 'bouncing' across the surface on ballistic trajectories in a random-walk process. The 3.8 day half-life of radon-222 allows the gas to spread out by several 100 km before it decays and allows the APS to detect gas release events up to a few days after they occur. The long residence time (10s of years) of the lead-210 precursor to the polonium-210 allows the mapping of gas vents which have been active over the last approximately 50 years. Because radon and polonium are daughter products of the decay of uranium, the background level of alpha particle activity is a function of the lunar crustal uranium distribution. Using radioactive radon and polonium as tracers, the Apollo 15 and 16 Command Module orbital alpha particle experiments obtained evidence for the release of gases at several sites beneath the orbit tracks, especially over the Aristarchus Plateau and Mare Fecunditatis [1]. Aristarchus crater had previously been identified by ground-based observers as the site of transient optical events [2]. The Apollo 17 surface mass spectrometer showed that argon-40 is released from the lunar interior every few months, apparently in concert with some of the shallow moonquakes that are believed to be of tectonic origin [3]. The latter tectonic events could be associated with very young scarps identified in the lunar highlands [4] and are believed to indicate continued global contraction. Such quakes could open fissures leading to the release of gases that are trapped below the surface. The detection of radon-222 outgassing events at the margins of Fecunditatis basin was surprising because the observed surface distribution of uranium and thorium do not extend sufficiently eastward to cover Fecunditatis. If the Apollo detections prove sound, then those alpha particle emissions indicate substantial subsurface concentrations of uranium-238 within Fecunditatis. A primary goal of the APS was to map gas-release events, thus allowing both an appraisal of the current level of tectonic activity on the Moon and providing a probe of subsurface uranium concentrations.

  5. Extending Penning trap mass measurements with SHIPTRAP to the heaviest elements

    SciTech Connect (OSTI)

    Block, M.; Ackermann, D.; Herfurth, F.; Hofmann, S. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Blaum, K. [Max-Planck-Institut fuer Kernphysik, 69117 Heidelberg, Germany and Ruprecht-Karls-Universitaet, 69120 Heidelberg (Germany); Droese, C.; Marx, G.; Schweikhard, L. [Ernst-Moritz-Arndt-Universitaet, 17487 Greifswald (Germany); Duellmann, Ch. E. [Johannes Gutenberg-Universitaet, 55099 Mainz, Germany and GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Helmholtz-Institut Mainz, 55099 Mainz (Germany); Eibach, M. [Ruprecht-Karls-Universitaet, 69120 Heidelberg, Germany and Johannes Gutenberg-Universitaet, 55099 Mainz (Germany); Eliseev, S. [Max-Planck-Institut fuer Kernphysik, 69117 Heidelberg (Germany); Haettner, E.; Plass, W. R.; Scheidenberger, C. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Justus-Liebig-Universitaet, 35392 Giessen (Germany); Hessberger, F. P. [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt, Germany and Helmholtz-Institut Mainz, 55099 Mainz (Germany); Ramirez, E. Minaya [Helmholtz-Institut Mainz, 55099 Mainz, Germany and GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany); Nesterenko, D. [Petersburg Nuclear Physics Institute, Gatchina, 188300 St. Petersburg (Russian Federation); and others

    2013-03-19T23:59:59.000Z

    Penning-trap mass spectrometry of radionuclides provides accurate mass values and absolute binding energies. Such mass measurements are sensitive indicators of the nuclear structure evolution far away from stability. Recently, direct mass measurements have been extended to the heavy elements nobelium (Z=102) and lawrencium (Z=103) with the Penning-trap mass spectrometer SHIPTRAP. The results probe nuclear shell effects at N=152. New developments will pave the way to access even heavier nuclides.

  6. Radiochemical method development

    SciTech Connect (OSTI)

    Erickson, M.D.; Aldstadt, J.H.; Alvarado, J.S.; Crain, J.S.; Orlandini, K.A.; Smith, L.L.

    1994-09-01T23:59:59.000Z

    The authors have developed methods for chemical characterization of the environment under a multitask project that focuses on improvement of radioanalytical methods with an emphasis on faster and cheaper routine methods. The authors have developed improved methods for separation of environmental levels of technetium-99, radium, and actinides from soil and water; separation of actinides from soil and water matrix interferences; and isolation of strontium. They are also developing methods for simultaneous detection of multiple isotopes (including nonradionuclides) by using a new instrumental technique, inductively coupled plasma-mass spectrometry (ICP-MS). The new ICP-MS methods have greater sensitivity and efficiency and could replace many radiometric techniques. They are using flow injection analysis to integrate and automate the separation methods with the ICP-MS methodology. The final product of all activities will be methods that are available (published in the U.S. Department of Energy`s analytical methods compendium) and acceptable for use in regulatory situations.

  7. Ultracold-neutron infrastructure for the gravitational spectrometer GRANIT

    E-Print Network [OSTI]

    P. Schmidt-Wellenburg; K. H. Andersen; P. Courtois; M. Kreuz; S. Mironov; V. V. Nesvizhevsky; G. Pignol; K. V. Protasov; T. Soldner; F. Vezzu; O. Zimmer

    2009-01-29T23:59:59.000Z

    The gravitational spectrometer GRANIT will be set up at the Institut Laue Langevin. It will profit from the high ultracold neutron density produced by a dedicated source. A monochromator made of crystals from graphite intercalated with potassium will provide a neutron beam with 0.89 nm incident on the source. The source employs superthermal conversion of cold neutrons in superfluid helium, in a vessel made from BeO ceramics with Be windows. A special extraction technique has been tested which feeds the spectrometer only with neutrons with a vertical velocity component v < 20 cm/s, thus keeping the density in the source high. This new source is expected to provide a density of up to 800 1/cm3 for the spectrometer.

  8. Ultracold-neutron infrastructure for the gravitational spectrometer GRANIT

    E-Print Network [OSTI]

    Schmidt-Wellenburg, P; Courtois, P; Kreuz, M; Mironov, S; Nesvizhevsky, V V; Pignol, G; Protasov, K V; Soldner, T; Vezzu, F; Zimmer, O

    2008-01-01T23:59:59.000Z

    The gravitational spectrometer GRANIT will be set up at the Institut Laue Langevin. It will profit from the high ultracold neutron density produced by a dedicated source. A monochromator made of crystals from graphite intercalated with potassium will provide a neutron beam with 8.9 Angstrom incident on the source. The source employs superthermal conversion of cold neutrons in superfluid helium, in a vessel made from BeO ceramics with Be windows. A special extraction technique has been tested which feeds the spectrometer only with neutrons with a vertical velocity component v = 20 cm/s, thus keeping the density in the source high. This new source is expected to provide a density of up to R = 800 cm-3 for the spectrometer.

  9. Wavelength calibration of the JWST-MIRI medium resolution spectrometer

    E-Print Network [OSTI]

    Martinez-Galarza, J R; Hernan-Caballero, A; Azzollini, R; Glasse, A; Kendrew, S; Brandl, B; Lahuis, F

    2010-01-01T23:59:59.000Z

    We present the wavelength and spectral resolution characterisation of the Integral Field Unit (IFU) Medium Resolution Spectrometer for the Mid-InfraRed Instrument (MIRI), to fly onboard the James Webb Space Telescope in 2014. We use data collected using the Verification Model of the instrument and develop an empirical method to calibrate properties such as wavelength range and resolving power in a portion of the spectrometer's full spectral range (5-28 microns). We test our results against optical models to verify the system requirements and combine them with a study of the fringing pattern in the instrument's detector to provide a more accurate calibration. We show that MIRI's IFU spectrometer will be able to produce spectra with a resolving power above R=2800 in the wavelength range 6.46-7.70 microns, and that the unresolved spectral lines are well fitted by a Gaussian profile.

  10. The MARTE VNIR Imaging Spectrometer Experiment: Design and Analysis

    E-Print Network [OSTI]

    Brown, Adrian J; Dunagan, Stephen

    2014-01-01T23:59:59.000Z

    We report on the design, operation, and data analysis methods employed on the VNIR imaging spectrometer instrument that was part of the Mars Astrobiology Research and Technology Experiment (MARTE). The imaging spectrometer is a hyperspectral scanning pushbroom device sensitive to VNIR wavelengths from 400-1000 nm. During the MARTE project, the spectrometer was deployed to the Rio Tinto region of Spain. We analyzed subsets of 3 cores from Rio Tinto using a new band modeling technique. We found most of the MARTE drill cores to contain predominantly goethite, though spatially coherent areas of hematite were identified in Core 23. We also distinguished non Fe-bearing minerals that were subsequently analyzed by X-ray diffraction (XRD) and found to be primarily muscovite. We present drill core maps that include spectra of goethite, hematite, and non Fe-bearing minerals.

  11. Analysis of CZT crystals and detectors grown in Russia and the Ukraine by high-pressure Bridgman methods

    SciTech Connect (OSTI)

    H. Hermon; M. Schieber; R. B. James; E. Y. Lee; N. Yang; A. J. Antolak; D. H. Morse; C. Hackett; E. Tarver; N. N. P. Kolesnikov; Yu N. Ivanov; V. Komar; M. S. Goorsky; H. Yoon

    2000-01-10T23:59:59.000Z

    Sandia National Laboratories (SNL) is leading an effort to evaluate vertical high pressure Bridgman (VHPB) Cd{sub 1-x}Zn{sub x}Te (CZT) crystals grown in the former Soviet Union (FSU) (Ukraine and Russia), in order to study the parameters limiting the crystal quality and the radiation detector performance. The stoichiometry of the CZT crystals, with 0.04 < x < 0.25, has been determined by methods such as proton-induced X-ray emission (PIXE), X-ray diffraction (XRD), microprobe analysis and laser ablation ICP mass spectroscopy (LA-ICP/MS). Other methods such as triaxial double crystal x-ray diffraction (TADXRD), infrared transmission spectroscopy (IR), atomic force microscopy (AFM), thermoelectric emission spectroscopy (TEES) and laser induced transient charge technique (TCT) were also used to evaluate the material properties. The authors have measured the zinc distribution in a CZT ingot along the axial direction and also its homogeneity. The (Cd+Zn)/Te average ratio measured on the Ukraine crystals was 1.2, compared to the ratio of 0.9-1.06 on the Russian ingots. The IR transmission showed highly decorated grain boundaries with precipitates and hollow bubbles. Microprobe elemental analysis and LA-ICP/MS showed carbon precipitates in the CZT bulk and carbon deposits along grain boundaries. The higher concentration of impurities and the imperfect crystallinity lead to shorter electron and hole lifetimes in the range of 0.5--2 {micro}s and 0.1 {micro}s respectively, compared to 3--20 {micro}s and 1--7 {micro}s measured on US spectrometer grade CZT detectors. These results are consistent with the lower resistivity and worse crystalline perfection of these crystals, compared to US grown CZT. However, recently grown CZT from FSU exhibited better detector performance and good response to alpha particles.

  12. Analysis of CZT crystals and detectors grown in Russia and the Ukraine by high-pressure Bridgman methods

    SciTech Connect (OSTI)

    Hermon, H.; Schieber, M. [Sandia National Labs., Livermore, CA (United States)]|[Hebrew Univ., Jerusalem (Israel); James, R.B. [Sandia National Labs., Livermore, CA (United States)] [and others

    1999-06-01T23:59:59.000Z

    Sandia National Laboratories (SNL) is leading an effort to evaluate vertical high pressure Bridgman (VHPB) Cd{sub 1{minus}x}Zn{sub x}Te (CZT) crystals grown in the former Soviet Union (FSU) (Ukraine and Russia), in order to study the parameters limiting the crystal quality and the radiation detector performance. The stoichiometry of the CZT crystals, with 0.04 < x < 0.25, has been determined by methods such as proton-induced x-ray emission (PIXE), x-ray diffraction (XRD), microprobe analysis and laser ablation ICP mass spectroscopy (LA-ICP/MS). Other methods such as triaxial double crystal x-ray diffraction (TADXRD), infrared transmission spectroscopy (IR), atomic force microscopy (AFM), thermoelectric emission spectroscopy (TEES) and laser induced transient charge technique (TCT) were also used to evaluate the material properties. The authors have measured the zinc distribution in a CZT ingot along the axial direction and also its homogeneity. The (Cd+Zn)/Te average ratio measured on the Ukraine crystals was 1.2, compared to the ratio of 0.9--1.06 on the Russian ingots. The IR transmission showed highly decorated grain boundaries with precipitates and hollow bubbles. Microprobe elemental analysis and LA-ICP/MS showed carbon precipitates in the CZT bulk and carbon deposits along grain boundaries. The higher concentration of impurities and the imperfect crystallinity lead to shorter electron and hole lifetimes in the range of 0.5--2 and 0.1 {micro}s, respectively, compared to 3--20 and 1--7 {micro}s measured on US spectrometer grade CZT detectors. These results are consistent with the lower resistivity and worse crystalline perfection of these crystals, compared to US-grown CZT. However, recently grown CZT from FSU exhibited better detector performance and good response to alpha particles.

  13. Bragg x-ray survey spectrometer for ITER

    SciTech Connect (OSTI)

    Varshney, S. K.; Jakhar, S. [ITER-India, Institute for Plasma Research, Bhat, Gandhinagar, Gujarat 382428 (India); Barnsley, R. [ITER Organization, Route de Vinon sur Verdon, 13115 Saint Paul Lez Durance (France); O'Mullane, M. G. [Department of Physics, University of Strathclyde, Glasgow G4 0NG (United Kingdom)

    2012-10-15T23:59:59.000Z

    Several potential impurity ions in the ITER plasmas will lead to loss of confined energy through line and continuum emission. For real time monitoring of impurities, a seven channel Bragg x-ray spectrometer (XRCS survey) is considered. This paper presents design and analysis of the spectrometer, including x-ray tracing by the Shadow-XOP code, sensitivity calculations for reference H-mode plasma and neutronics assessment. The XRCS survey performance analysis shows that the ITER measurement requirements of impurity monitoring in 10 ms integration time at the minimum levels for low-Z to high-Z impurity ions can largely be met.

  14. The NIF x-ray spectrometer calibration campaign at Omega

    SciTech Connect (OSTI)

    Pérez, F.; Kemp, G. E.; Barrios, M. A.; Pino, J.; Scott, H.; Ayers, S.; Chen, H.; Emig, J.; Colvin, J. D.; Fournier, K. B., E-mail: fournier2@llnl.gov [Lawrence Livermore National Laboratory, P. O. Box 808, Livermore, California 94551 (United States); Regan, S. P.; Bedzyk, M.; Shoup, M. J.; Agliata, A.; Yaakobi, B.; Marshall, F. J.; Hamilton, R. A. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States); Jaquez, J.; Farrell, M.; Nikroo, A. [General Atomics, P.O. Box 85608, San Diego, California 92186 (United States)

    2014-11-15T23:59:59.000Z

    The calibration campaign of the National Ignition Facility X-ray Spectrometer (NXS) was carried out at the OMEGA laser facility. Spherically symmetric, laser-driven, millimeter-scale x-ray sources of K-shell and L-shell emission from various mid-Z elements were designed for the 2–18 keV energy range of the NXS. The absolute spectral brightness was measured by two calibrated spectrometers. We compare the measured performance of the target design to radiation hydrodynamics simulations.

  15. Extended Evaluations of the Commercial Spectrometer Systems for Safeguards Applications

    SciTech Connect (OSTI)

    Duc T. Vo

    1999-08-01T23:59:59.000Z

    Safeguards applications require the best of the spectrometer system with excellent resolution, stability, and throughput. Instruments must perform well in all situations and environments. Data communication to the computer should be convenient, fast, and reliable. The software should have all the necessary tools and be easy to use. Portable systems should be small in size, lightweight, and have a long battery life. Nine commercially available spectrometer systems are tested with five different germanium detectors. Considering the performance of the Digital Signal Processors (DSP), digital-based spectroscope y may become the way of future gamma-ray spectroscopy.

  16. Waveguide-integrated photonic crystal spectrometer with camera readout

    SciTech Connect (OSTI)

    Meng, Fan; Shiue, Ren-Jye; Li, Luozhou; Nie, Jing; Harris, Nicholas C.; Chen, Edward H.; Schröder, Tim; Englund, Dirk, E-mail: englund@mit.edu [Department of Electrical Engineering and Computer Science, Massachusetts Institute of Technology (MIT), Cambridge, Massachusetts 02139 (United States); Wan, Noel [Department of Physics, Columbia University, New York, New York 10027 (United States); Pervez, Nadia [Chromation Partners LLC, 18 Bridge Street Suite 2J, Brooklyn, New York 11201 (United States); Kymissis, Ioannis [Chromation Partners LLC, 18 Bridge Street Suite 2J, Brooklyn, New York 11201 (United States); Department of Electrical Engineering, Columbia University, New York, New York 10027 (United States)

    2014-08-04T23:59:59.000Z

    We demonstrate an infrared spectrometer based on waveguide-coupled nanocavity filters in a planar photonic crystal structure. The input light is coupled into the waveguide, from which spectral components are dropped into the cavities and radiated off-chip for detection on a commercial InGaAs camera. The spectrometer has a footprint of only 60??m by 8??m. The spectral resolution is about 1?nm in the operation bandwidth of 1522–1545?nm. By substituting the membrane material and structure parameters, this design can be easily extended into the visible regime and developed for a variety of highly efficient, miniature photonic applications.

  17. Development of multichannel low-energy neutron spectrometer

    SciTech Connect (OSTI)

    Arikawa, Y., E-mail: arikawa-y@ile.osaka-u.ac.jp; Nagai, T.; Abe, Y.; Kojima, S.; Sakata, S.; Inoue, H.; Utsugi, M.; Iwasa, Y.; Sarukura, N.; Nakai, M.; Shiraga, H.; Fujioka, S.; Azechi, H. [Institute of Laser Engineering, Osaka University, 2-6 Yamada-oka, Suita, Osaka (Japan); Murata, T. [Kumamoto University, 2-40-1 Kurokami, Kumamoto 860-8555 (Japan)

    2014-11-15T23:59:59.000Z

    A multichannel low-energy neutron spectrometer for down-scattered neutron (DSN) measurements in inertial confinement fusion (ICF) experiments has been developed. Our compact-size 256-channel lithium-glass-scintillator-based spectrometer has been implemented and tested in ICF experiments with the GEKKO XII laser. We have performed time calibration of the 256-channel analog-to-digital convertor system used for DSN measurements via X-ray pulse signals. We have clearly observed the DD-primary fusion neutron signal and have successfully studied the detector's impulse response. Our detector is soon to be implemented in future ICF experiments.

  18. The Results of Recent MICE Superconducting Spectrometer Solenoid Test

    SciTech Connect (OSTI)

    Green, Michael A; Virostek, Steve P.; Zisman, Michael S.

    2010-10-15T23:59:59.000Z

    The MICE spectrometer solenoid magnets will be the first magnets to be installed within the MICE cooling channel. The MICE spectrometer solenoids may be the largest magnets that have been cooled using small two stage coolers. During the previous test of this magnet, the cooler first stage temperatures were too high. The causes of some of the extra first stage heat load has been identified and corrected. The rebuilt magnet had a single stage GM cooler in addition to the three pulse tube coolers. The added cooler reduces the temperature of the top of the HTS leads, the shield and of the first stage of the pulse tube coolers.

  19. A 100-kc modulation system for an EPR microwave spectrometer

    E-Print Network [OSTI]

    Stewart, Frank Edwin

    1964-01-01T23:59:59.000Z

    LIST OF FIGURES FIGURE PAGE II-1 Molecular Structure of DPPH 22 II-2 11-3 III-1 IV-1 Hyperfine Splitting in the DPPH EPR Spectrum . 25 Hyperfine Splitting in the Mn EpR Spectrum , . 27 100-kc Field Modulation and Detection System . 4I Typical... spectrometer. Most EPR spectrometers induce transitions at microwave frequencies and split the Zeeman levels with a polarizing field of 3400 gauss' The inherent advantage of operating in this region is that high sensitivities can be realized from small...

  20. Determination of petroleum pipe scale solubility in simulated lung fluid

    E-Print Network [OSTI]

    Cezeaux, Jason Roderick

    2005-08-29T23:59:59.000Z

    are ionized in the plasma. Figure 7. Schematic diagram of the RF coil used to produce an inductively coupled plasma. (Taylor 2001) After being focused by the ion lens, a charged metallic cylinder, the ions are separated by their mass... of ICP-MS for detection and quantification of 234U, 238U, 99Tc, 237Np, actinides, and fission products (Morrow 1998). In addition to these papers, numerous others indicate the viability of ICP-MS use in the determination of radionuclides, in which...

  1. Plasma desorption mass spectrometry of organics at low temperatures

    E-Print Network [OSTI]

    Shirey, Eldon Lynn

    1993-01-01T23:59:59.000Z

    , cyclohexane, cyclohexene, 1,3-cyclohexadiene, benzene, toluene, ortho- xylene, meta-xylene, and para-xylene. PDMS is best carried out on solids; accordingly, the samples were frozen. The experiments were run using a time-of-flight mass spectrometer with a 252...

  2. Modulated optical solid-state spectrometer applications in plasma diagnostics

    E-Print Network [OSTI]

    Howard, John

    Modulated optical solid-state spectrometer applications in plasma diagnostics John Howard Plasma A new electro-optically modulated optical solid-state MOSS interferometer has been constructed for the measurement of the low order spectral moments of line emission from optically thin radiant media

  3. Integration and commissioning of the ATLAS Muon spectrometer

    E-Print Network [OSTI]

    Alberto Belloni; for the ATLAS collaboration

    2008-10-16T23:59:59.000Z

    The ATLAS experiment at the Large Hadron Collider (LHC) at CERN is currently waiting to record the first collision data in spring 2009. Its muon spectrometer is designed to achieve a momentum resolution of 10% pT(mu) = 1 TeV/c. The spectrometer consists of a system of three superconducting air-core toroid magnets and is instrumented with three layers of Monitored Drift Tube chambers (Cathode Strip Chambers in the extreme forward region) as precision detectors. Resistive Plate Chambers in the barrel and Thin Gap Chambers in the endcap regions provide a fast trigger system. The spectrometer passed important milestones in the last year. The most notable milestone was the installation of the inner layer of endcap muon chambers, which constituted the last big piece of the ATLAS detector to be lowered in the ATLAS cavern. In addition, during the last two years most of the muon detectors were commissioned with cosmic rays while being assembled in the underground experimental cavern. We will report on our experience with the precision and trigger chambers, the optical spectrometer alignment system, the level-1 trigger, and the ATLAS data acquisition system. Results of the global performance of the muon system from data with magnetic field will also be presented.

  4. Photonic Crystal Slot Waveguide Spectrometer for Detection of Methane

    E-Print Network [OSTI]

    Texas at Austin, University of

    Photonic Crystal Slot Waveguide Spectrometer for Detection of Methane 1 Funded by Environmental. of Electrical and Computer Engineering, University of Texas, Austin #12;Motivation No other chip based optical Similar to: Doping of Semiconductor 3 #12;4 Photonic Crystal Bio-Chemical Sensors Loncar et al, Appl. Phys

  5. Analysis of a time-of-flight neutron spectrometer

    SciTech Connect (OSTI)

    Biggs, F.

    1983-12-01T23:59:59.000Z

    A neutron spectrometer is analyzed. The spectrum is resolved using a time-of-flight method in which the angular position of a rapidly spinning wheel is used to measure time. The measurement method is summarized, the data-analysis problem is formulated, units are discussed, the calibration technique is described, and a spectral transformation is developed.

  6. Correction to ``Scanning Imaging Absorption Spectrometer for Atmospheric Chartography carbon monoxide total columns

    E-Print Network [OSTI]

    Laat, Jos de

    Correction to ``Scanning Imaging Absorption Spectrometer for Atmospheric Chartography carbon to ``Scanning Imaging Absorption Spectrometer for Atmospheric Chartography carbon monoxide total columns, doi:10.1029/2007JD009378. [1] In the paper ``Scanning Imaging Absorption Spec- trometer

  7. Oil Spill Detection and Mapping Along the Gulf of Mexico Coastline Based on Imaging Spectrometer Data

    E-Print Network [OSTI]

    Arslan, Meryem Damla

    2013-11-27T23:59:59.000Z

    based on hyperspectral images acquired along the coastline of the Gulf of Mexico. A number of AVIRIS (Airborne Visible/Infrared Imaging Spectrometer) imaging spectrometer images were investigated in this research collected over Bay Jimmy and Wilkinson...

  8. Upgrade of the neon soft X-ray spectrometer for Alcator C-Mod

    E-Print Network [OSTI]

    Podpaly, Yuri Anatoly

    2007-01-01T23:59:59.000Z

    In order to study plasma rotation, temperature, and impurity density, a Neon Soft X-ray Spectrometer (NeSoXs) was installed on the Alcator C-Mod tokamak. This spectrometer used a spherically bent mica crystal as the ...

  9. In situ calibration of inductively coupled plasma-atomic emission and mass spectroscopy

    DOE Patents [OSTI]

    Braymen, S.D.

    1996-06-11T23:59:59.000Z

    A method and apparatus are disclosed for in situ addition calibration of an inductively coupled plasma atomic emission spectrometer or mass spectrometer using a precision gas metering valve to introduce a volatile calibration gas of an element of interest directly into an aerosol particle stream. The present in situ calibration technique is suitable for various remote, on-site sampling systems such as laser ablation or nebulization. 5 figs.

  10. Real-time monitoring of volatile organic compounds using chemical ionization mass spectrometry

    DOE Patents [OSTI]

    Mowry, Curtis Dale (Albuquerque, NM); Thornberg, Steven Michael (Peralta, NM)

    1999-01-01T23:59:59.000Z

    A system for on-line quantitative monitoring of volatile organic compounds (VOCs) includes pressure reduction means for carrying a gaseous sample from a first location to a measuring input location maintained at a low pressure, the system utilizing active feedback to keep both the vapor flow and pressure to a chemical ionization mode mass spectrometer constant. A multiple input manifold for VOC and gas distribution permits a combination of calibration gases or samples to be applied to the spectrometer.

  11. High-precision CO2 isotopologue spectrometer with a difference-frequency-generation laser source

    E-Print Network [OSTI]

    High-precision CO2 isotopologue spectrometer with a difference-frequency-generation laser source A precision laser spectrometer for the detection of CO2 isotopes is reported. The spectrometer measures the fundamental absorption signatures of 13 C and 12 C isotopes in CO2 at 4.32 m using a tunable mid-IR laser

  12. Conversion electrons used to monitor the energy scale of electron spectrometer near tritium endpoint - a simulation study

    E-Print Network [OSTI]

    M. Rysavy

    2006-01-15T23:59:59.000Z

    Measurements of the endpoint region of the tritium beta-decay spectrum provides good possibility to determine neutrino mass. This, however, needs a perfect monitoring of the spectrometer energy scale. A parallel measurement of electron line of known energy - in particular the 83mKr conversion K-line - may serve well to this purpose. The 83Rb decaying to 83mKr seems to be a very suitable radioactive source due to its halflife of 86.2 day. In this work, we determine the amount of 83Rb which is necessary for a successful monitoring.

  13. O isotopic composition of CaCO3 measured by continuous ow isotope ratio mass spectrometry

    E-Print Network [OSTI]

    d13 C and d18 O isotopic composition of CaCO3 measured by continuous ¯ow isotope ratio mass. This new method streamlines the classical phosphoric acid/calcium carbonate (H3PO4/CaCO3) reaction method XL continuous flow isotope ratio mass spectrometer. Conditions for which the H3PO4/CaCO3 reaction

  14. Design and development of an ultrafine particle reflection-time-of-flight mass spectrometer

    E-Print Network [OSTI]

    Das, Rishiraj

    2002-01-01T23:59:59.000Z

    particle sizes proposed by the International Commission on Radiological Protection (ICRP 1994) shov s that ultratine particles ol' around 20nm in diameter have 50"z; deposition efficiency in thc alveolar region. Thc harmful effects ol P'I Fh on rats have...

  15. Evaluation of Technologies to Complement/Replace Mass Spectrometers in the Tritium Facilities

    SciTech Connect (OSTI)

    Tovo, L. L.; Lascola, R. J.; Spencer, W. A.; McWhorter, C. S.; Zeigler, K. E.

    2005-08-30T23:59:59.000Z

    The primary goal of this work is to determine the suitability of the Infraran sensor for use in the Palladium Membrane Reactor. This application presents a challenge for the sensor, since the process temperature exceeds its designed operating range. We have demonstrated that large baseline offsets, comparable to the sensor response to the analyte, are obtained if cool air is blown across the sensor. We have also shown that there is a strong environmental component to the noise. However, the current arrangement does not utilize a reference detector. The strong correlation between the CO and H{sub 2}O sensor responses to environmental changes indicate that a reference detector can greatly reduce the environmental sensitivity. In fact, incorporation of a reference detector is essential for the sensor to work in this application. We have also shown that the two sensor responses are adequately independent. Still, there are several small corrections which must to be made to the sensor response to accommodate chemical and physical effects. Interactions between the two analytes will alter the relationship between number density and pressure. Temperature and pressure broadening will alter the relationship between absorbance and number density. The individual effects are small--on the order of a few percent or less--but cumulatively significant. Still, corrections may be made if temperature and total pressure are independently measured and incorporated into a post-analysis routine. Such corrections are easily programmed and automated and do not represent a significant burden for installation. The measurements and simulations described above indicate that with appropriate corrections, the Infraran sensor can approach the 1-1.5% measurement accuracy required for effective PMR process control. It is also worth noting that the Infraran may be suitable for other gas sensing applications, especially those that do not need to be made in a high-temperature environment. Any gas with an infrared absorption (methane, ammonia, etc.) may be detected so long as an appropriate bandpass filter can be manufactured. Note that homonuclear diatomic molecules (hydrogen and its isotopes, nitrogen, oxygen) do not have infrared absorptions. We have shown that the sensor response may be adequately predicted using commercially available software. Measurement of trace concentrations is limited by the broad spectral bandpass, since the total signal includes non-absorbed frequencies. However, cells with longer pathlengths can be designed to address this problem.

  16. Mass Spectrometer Studies of Ion Sources for One Shot Accelerator Tube

    E-Print Network [OSTI]

    Brumbaugh, R.; Pon, W.; Seaman, W.; Wiegand, C.

    1951-01-01T23:59:59.000Z

    by a crystal of a lithium deuteride mounted on the end of aI T . F i g . Si Llthiura deuteride orystal and deuterised T

  17. An industrial hygiene survey of acetonitrile using a miniature quadrupole mass spectrometer

    E-Print Network [OSTI]

    Bruss, Stacy M

    1999-01-01T23:59:59.000Z

    Charcoal tubes are an industry standard for the collection and concentration of airborne chemicals in the field for later analysis in a laboratory. There are a few drawbacks in using charcoal tubes, including the time delay before results...

  18. Neutrino Masses

    E-Print Network [OSTI]

    Christian Weinheimer; Kai Zuber

    2013-09-04T23:59:59.000Z

    The various experiments on neutrino oscillation evidenced that neutrinos have indeed non-zero masses but cannot tell us the absolute neutrino mass scale. This scale of neutrino masses is very important for understanding the evolution and the structure formation of the universe as well as for nuclear and particle physics beyond the present Standard Model. Complementary to deducing constraints on the sum of all neutrino masses from cosmological observations two different methods to determine the neutrino mass scale in the laboratory are pursued: the search for neutrinoless double $\\beta$-decay and the direct neutrino mass search by investigating single $\\beta$-decays or electron captures. The former method is not only sensitive to neutrino masses but also probes the Majorana character of neutrinos and thus lepton number violation with high sensitivity. Currently quite a few experiments with different techniques are being constructed, commissioned or are even running, which aim for a sensitivity on the neutrino mass of {\\cal O}(100) meV. The principle methods and these experiments will be discussed in this short review.

  19. Commissioning of the ATLAS Muon Spectrometer with Cosmic Rays

    E-Print Network [OSTI]

    The ATLAS Collaboration

    2010-08-02T23:59:59.000Z

    The ATLAS detector at the Large Hadron Collider has collected several hundred million cosmic ray events during 2008 and 2009. These data were used to commission the Muon Spectrometer and to study the performance of the trigger and tracking chambers, their alignment, the detector control system, the data acquisition and the analysis programs. We present the performance in the relevant parameters that determine the quality of the muon measurement. We discuss the single element efficiency, resolution and noise rates, the calibration method of the detector response and of the alignment system, the track reconstruction efficiency and the momentum measurement. The results show that the detector is close to the design performance and that the Muon Spectrometer is ready to detect muons produced in high energy proton-proton collisions.

  20. Triboelectric Nanosensors DOI: 10.1002/anie.201300437

    E-Print Network [OSTI]

    Wang, Zhong L.

    /emission spectrometry[3] and inductively coupled plasma mass spectrometry (ICP-MS),[4] have been applied to detect for environmental protec- tion/detection in the near future because no battery is needed to power the device with different triboelectric polarity yields surface charge transfer. The periodic contact and separation

  1. Research papers Distribution of platinum-group and chalcophile elements in the Aguablanca NiCu

    E-Print Network [OSTI]

    -group elements Aguablanca Laser ablation Base-metal sulfides Pyrite The concentrations of platinum-group elements (PGE) and chalcophile elements Ni, Co, Au, Ag, Se, Re, Cd, Bi, Te and As have been determined by laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP- MS) in base metal sulfide minerals (BMS

  2. PII S0016-7037(02)01048-7 Sr investigation of igneous apatites and carbonates using laser-ablation

    E-Print Network [OSTI]

    Long, Bernard

    using laser-ablation MC-ICP-MS MARTIN BIZZARRO,1* ANTONIO SIMONETTI,1 R. K. STEVENSON,1 and STEPHAN, Greenland, have been determined by laser-ablation multicollector inductively coupled plasma mass 50% carbonate by volume, are ideally suited for laser-ablation (LA) studies be- cause

  3. 0361-0128/12/4012/275-20 275 Introduction

    E-Print Network [OSTI]

    -rich melts at temperatures lower than 1,000°C. Hence, arsenides and sulfarsenides may play a role, mineralogy, in situ mineral chemistry (by LA-ICP- MS[laser ablation-inductively coupled plasma-mass spec) in selected samples represen

  4. Polarization Measurements in Photoproduction with CEBAF Large Acceptance Spectrometer

    SciTech Connect (OSTI)

    E. Pasyuk

    2010-05-01T23:59:59.000Z

    A significant part of the experimental program in Hall-B of the Jefferson Lab is dedicated to the studies of the structure of baryons. CEBAF Large Acceptance Spectrometer (CLAS), availability of circularly and linearly polarized photon beams and recent addition of polarized targets provides remarkable opportunity for single, double and in some cases triple polarization measurements in photoproduction. An overview of the experiments will be presented.

  5. Extracting source parameters from beam monitors on a chopper spectrometer

    SciTech Connect (OSTI)

    Abernathy, Douglas L [ORNL; Niedziela, Jennifer L [ORNL; Stone, Matthew B [ORNL

    2015-01-01T23:59:59.000Z

    The intensity distributions of beam monitors in direct-geometry time-of-flight neutron spectrometers provide important information about the instrument resolution. For short-pulse spallation neutron sources in particular, the asymmetry of the source pulse may be extracted and compared to Monte Carlo source simulations. An explicit formula using a Gaussian-convolved Ikeda-Carpenter distribution is given and compared to data from the ARCS instrument at the Spallation Neutron Source.

  6. Compact Refractive Imaging Spectrometer Designs Utilizing Immersed Gratings

    DOE Patents [OSTI]

    Lerner, Scott A. (Livermore, CA); Bennett, Charles L. (Livermore, CA); Bixler, Jay V. (Oakland, CA); Kuzmenko, Paul J. (Livermore, CA); Lewis, Isabella T. (San Jose, CA)

    2005-07-26T23:59:59.000Z

    A compact imaging spectrometer comprising an entrance slit for directing light, a first means for receiving the light and focusing the light, an immersed diffraction grating that receives the light from the first means and defracts the light, a second means for receiving the light from the immersed diffraction grating and focusing the light, and an image plane that receives the light from the second means

  7. Low background HPGe spectrometer in investigations of 2? decay

    SciTech Connect (OSTI)

    Rukhadze, Ekaterina [Institute of Experimental and Applied Physics, CTU in Prague, Horska 3a/22, 128 00 Prague 2 (Czech Republic)] [Institute of Experimental and Applied Physics, CTU in Prague, Horska 3a/22, 128 00 Prague 2 (Czech Republic); Collaboration: OBELIX Collaboration; TGV Collaboration; SuperNEMO Collaboration; and others

    2013-08-08T23:59:59.000Z

    The low background high sensitive HPGe spectrometer called OBELIX is briefly described. The calibration measurements using {sup 152}Eu, {sup 133}Ba and La{sub 2}O{sub 3} sources in different geometries, the obtained efficiency curves for OBELIX HPGe detector, the results of measurements of radioactivity of the NEMO-3 sources ({sup 100}Mo, {sup 150}Nd) as well as future plans for OBELIX detector (e.g. 0?EC/EC decay of {sup 106}Cd) are presented.

  8. A short working distance multiple crystal x-ray spectrometer

    SciTech Connect (OSTI)

    Dickinson, B.; Seidler, G. T.; Webb, Z. W.; Bradley, J. A.; Nagle, K. P. [Department of Physics, University of Washington, Seattle, Washington 98195 (United States); Heald, S. M. [Advanced Photon Source, Argonne National Laboratories, Argonne, Illinois 60439 (United States); Gordon, R. A. [Department of Physics, Simon Fraser University, Burnaby, British Columbia V5A 1S6 (Canada); Chou, I. M. [U.S. Geological Survey, Reston, Virginia 20192 (United States)

    2008-12-15T23:59:59.000Z

    For x-ray spot sizes of a few tens of microns or smaller, a millimeter-sized flat analyzer crystal placed {approx}1 cm from the sample will exhibit high energy resolution while subtending a collection solid angle comparable to that of a typical spherically bent crystal analyzer (SBCA) at much larger working distances. Based on this observation and a nonfocusing geometry for the analyzer optic, we have constructed and tested a short working distance (SWD) multicrystal x-ray spectrometer. This prototype instrument has a maximum effective collection solid angle of 0.14 sr, comparable to that of 17 SBCA at 1 m working distance. We find good agreement with prior work for measurements of the Mn K{beta} x-ray emission and resonant inelastic x-ray scattering for MnO, and also for measurements of the x-ray absorption near-edge structure for Dy metal using L{alpha}{sub 2} partial-fluorescence yield detection. We discuss future applications at third- and fourth-generation light sources. For concentrated samples, the extremely large collection angle of SWD spectrometers will permit collection of high-resolution x-ray emission spectra with a single pulse of the Linac Coherent Light Source. The range of applications of SWD spectrometers and traditional multi-SBCA instruments has some overlap, but also is significantly complementary.

  9. A multi-crystal wavelength dispersive x-ray spectrometer

    SciTech Connect (OSTI)

    Alonso-Mori, Roberto; Montanez, Paul; Delor, James; Bergmann, Uwe [LCLS, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Kern, Jan [LCLS, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Physical Biosciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720-8099 (United States); Sokaras, Dimosthenis; Weng, Tsu-Chien; Nordlund, Dennis [SSRL, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Tran, Rosalie; Yachandra, Vittal K.; Yano, Junko [Physical Biosciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720-8099 (United States)

    2012-07-15T23:59:59.000Z

    A multi-crystal wavelength dispersive hard x-ray spectrometer with high-energy resolution and large solid angle collection is described. The instrument is specifically designed for time-resolved applications of x-ray emission spectroscopy (XES) and x-ray Raman scattering (XRS) at X-ray Free Electron Lasers (XFEL) and synchrotron radiation facilities. It also simplifies resonant inelastic x-ray scattering (RIXS) studies of the whole 2d RIXS plane. The spectrometer is based on the Von Hamos geometry. This dispersive setup enables an XES or XRS spectrum to be measured in a single-shot mode, overcoming the scanning needs of the Rowland circle spectrometers. In conjunction with the XFEL temporal profile and high-flux, it is a powerful tool for studying the dynamics of time-dependent systems. Photo-induced processes and fast catalytic reaction kinetics, ranging from femtoseconds to milliseconds, will be resolvable in a wide array of systems circumventing radiation damage.

  10. Mexico City Aerosol Analysis During Milagro Using High Resolution Aerosol Mass Spectrometry at the Urban Supersite (T0) - Part 1: Fine Particle Composition and Organic Source Apportionment.

    E-Print Network [OSTI]

    Aiken, A. C.

    Submicron aerosol was analyzed during the MILAGRO field campaign in March 2006 at the T0 urban supersite in Mexico City with a High-Resolution Aerosol Mass Spectrometer (AMS) and complementary instrumentation. Positive ...

  11. Interface for the rapid analysis of liquid samples by accelerator mass spectrometry

    DOE Patents [OSTI]

    Turteltaub, Kenneth; Ognibene, Ted; Thomas, Avi; Daley, Paul F; Salazar Quintero, Gary A; Bench, Graham

    2014-02-04T23:59:59.000Z

    An interface for the analysis of liquid sample having carbon content by an accelerator mass spectrometer including a wire, defects on the wire, a system for moving the wire, a droplet maker for producing droplets of the liquid sample and placing the droplets of the liquid sample on the wire in the defects, a system that converts the carbon content of the droplets of the liquid sample to carbon dioxide gas in a helium stream, and a gas-accepting ion source connected to the accelerator mass spectrometer that receives the carbon dioxide gas of the sample in a helium stream and introduces the carbon dioxide gas of the sample into the accelerator mass spectrometer.

  12. Atmospheric sampling glow discharge ionizataion and triple quadrupole tandem mass spectrometry for explosives vapor detection

    SciTech Connect (OSTI)

    McLuckey, S.A.; Goeringer, D.E.; Asano, K.G.; Hart, K.J.; Glish, G.L.; Grant, B.C.; Chambers, D.M.

    1993-08-01T23:59:59.000Z

    The detection and identification of trace vapors of hidden high explosives is an excellent example of a targeted analysis problem. It is desirable to push to ever lower levels the quantity or concentration of explosives material that provides an analytical signal, while at the same time discriminating against all other uninteresting material. The detection system must therefore combine high sensitivity with high specificity. This report describes the philosophy behind the use of atmospheric sampling glow discharge ionization, which is a sensitive, rugged, and convenient means for forming anions from explosives molecules, with tandem mass spectrometry, which provides unparalleled specificity in the identification of explosives-related ions. Forms of tandem mass spectrometry are compared and contrasted to provide a summary of the characteristics to be expected from an explosives detector employing mass spectrometry/mass spectrometry. The instrument developed for the FAA, an atmospheric sampling glow discharge/triple quadrupole mass spectrometer, is described in detail with particular emphasis on the ion source/spectrometer interface and on the capabilities of the spectrometer. Performance characteristics of the system are also described as they pertain to explosives of interest including a description of an automated procedure for the detection and identification of specific explosives. A comparison of various tandem mass spectrometers mated with atmospheric sampling glow discharge is then described and preliminary studies with a vapor preconcentration system provided by the FAA will be described.

  13. Direct mass measurements beyond the proton drip-line

    E-Print Network [OSTI]

    C. Rauth; D. Ackermann; K. Blaum; M. Block; A. Chaudhuri; S. Eliseev; R. Ferrer; D. Habs; F. Herfurth; F. P. Hessberger; S. Hofmann; H. -J. Kluge; G. Maero; A. Martin; G. Marx; M. Mukherjee; J. B. Neumayr; W. R. Plass; W. Quint; S. Rahaman; D. Rodriguez; C. Scheidenberger; L. Schweikhard; P. G. Thirolf; G. Vorobjev; C. Weber; Z. Di

    2007-01-22T23:59:59.000Z

    First on-line mass measurements were performed at the SHIPTRAP Penning trap mass spectrometer. The masses of 18 neutron-deficient isotopes in the terbium-to-thulium region produced in fusion-evaporation reactions were determined with relative uncertainties of about $7\\cdot 10^{-8}$, nine of them for the first time. Four nuclides ($^{144, 145}$Ho and $^{147, 148}$Tm) were found to be proton-unbound. The implication of the results on the location of the proton drip-line is discussed by analyzing the one-proton separation energies.

  14. Focused analyte spray emission apparatus and process for mass spectrometric analysis

    DOE Patents [OSTI]

    Roach, Patrick J. (Kennewick, WA); Laskin, Julia (Richland, WA); Laskin, Alexander (Richland, WA)

    2012-01-17T23:59:59.000Z

    An apparatus and process are disclosed that deliver an analyte deposited on a substrate to a mass spectrometer that provides for trace analysis of complex organic analytes. Analytes are probed using a small droplet of solvent that is formed at the junction between two capillaries. A supply capillary maintains the droplet of solvent on the substrate; a collection capillary collects analyte desorbed from the surface and emits analyte ions as a focused spray to the inlet of a mass spectrometer for analysis. The invention enables efficient separation of desorption and ionization events, providing enhanced control over transport and ionization of the analyte.

  15. Test of an LED Monitoring System for the PHOS Spectrometer

    E-Print Network [OSTI]

    Blick, A M; Erin, S V; Kharlov, Yu V; Lobanov, M O; Mikhailov, Yu V; Minaev, N G; Petrov, V A; Sadovsky, S A; Samoylenko, V D; Suzdalev, V I; Senko, V A; Tikhonov, V V

    1999-01-01T23:59:59.000Z

    Preprint submitted to Elsevier Print on 26th January 2000A prototype monitoring system for the Photon Spectrometer (PHOS) of the ALICE experiment at LHC is described in detail. The prototype consists of Control and Master modules. The first one is 8x8 matrix of Light Emitting Diodes coupled with stable generators of current pulses. The system provides an individual control for each of the 64 channels of PHOS prototype based on lead-tungstate crystals. A long term stability of order of 10-3 has been achieved in integral beam tests of the monitoring system and PHOS prototypes.

  16. New results from the LASS (Large Aperture Superconducting Solenoid) spectrometer

    SciTech Connect (OSTI)

    Aston, D.; Awaji, N.; Bienz, T.; Bird, F.; D'Amore, J.; Dunwoodie, W.; Endorf, R.; Fujii, K.; Hayashii, H.; Iwata, S.

    1987-06-22T23:59:59.000Z

    New results are presented from analyses of several mesonic and baryonic states containing one or more strange quarks. The data are taken from a high statistics (4 events/nb) study of K p interactions at 11 GeV/c carried out in the LASS Spectrometer at SLAC. New information is reported on the underlying K* states and also evidence for selective coupling of K eta to the K*'s; on the strangeonium members of the axial vector nonets in the K anti K channel; and on evidence for an * state.

  17. Light Baryon Spectroscopy using the CLAS Spectrometer at Jefferson Laboratory

    SciTech Connect (OSTI)

    Volker Crede

    2011-12-01T23:59:59.000Z

    Baryons are complex systems of confined quarks and gluons and exhibit the characteristic spectra of excited states. The systematics of the baryon excitation spectrum is important to our understanding of the effective degrees of freedom underlying nucleon matter. High-energy electrons and photons are a remarkably clean probe of hadronic matter, providing a microscope for examining the nucleon and the strong nuclear force. Current experimental efforts with the CLAS spectrometer at Jefferson Laboratory utilize highly-polarized frozen-spin targets in combination with polarized photon beams. The status of the recent double-polarization experiments and some preliminary results are discussed in this contribution.

  18. Cryostat for Ultra-low-energy Threshold Germanium Spectrometers

    SciTech Connect (OSTI)

    Aalseth, Craig E.; Bonicalzi, Ricco; Fast, James E.; Hossbach, Todd W.; Orrell, John L.; Overman, Cory T.; VanDevender, Brent A.

    2013-04-01T23:59:59.000Z

    Abstract: This paper presents progress on the development of a cryostat intended to improve upon the low-energy threshold (below 0.5 keV) of p-type point contact germanium gamma-ray spectrometers. Ultra-low energy thresholds are important in the detection of low-energy nuclear recoils, an event class relevant to both dark matter direct detection and measurement of coherent neutrino-nucleus scattering. The cryostat design, including a thermal and electrical-field model, is presented. A prototype cryostat has been assembled and data acquired to evaluate its vacuum and thermal performance.

  19. Cryostat for Ultra-low-energy Threshold Germanium Spectrometers

    E-Print Network [OSTI]

    Craig E. Aalseth; Ricco M. Bonicalzi; James E. Fast; Todd W. Hossbach; John L. Orrell; Cory T. Overman; Brent A. Vandevender

    2012-10-08T23:59:59.000Z

    This paper presents progress on the development of a cryostat intended to improve upon the low-energy threshold (below 0.5 keV) of p-type point contact germanium gamma-ray spectrometers. Ultra-low energy thresholds are important in the detection of low-energy nuclear recoils, an event class relevant to both dark matter direct detection and measurement of coherent neutrino-nucleus scattering. The cryostat design, including a thermal and electrical-field model, is given. A prototype cryostat has been assembled and data acquired to evaluate its vacuum and thermal performance.

  20. Report on First Activations with the Lead Slowing Down Spectrometer

    SciTech Connect (OSTI)

    Warren, Glen A.; Mace, Emily K.; Pratt, Sharon L.; Stave, Sean; Woodring, Mitchell L.

    2011-03-03T23:59:59.000Z

    On Feb. 17 and 18 2011, six items were irradiated with neutrons using the Lead Slowing Down Spectrometer. After irradiation, dose measurements and gamma-spectrometry measurements were completed on all of the samples. No contamination was found on the samples, and all but one provided no dose. Gamma-spectroscopy measurements qualitatively agreed with expectations based on the materials, with the exception of silver. We observed activation in the room in general, mostly due to 56Mn and 24Na. Most of the activation was short lived, with half-lives on the scale of hours, except for 198Au which has a half-life of 2.7 d.

  1. Material characterization using a hyperspectral infrared imaging spectrometer

    SciTech Connect (OSTI)

    Aimonetti, W D; Bixler, J V; Roberts, R S

    1998-10-30T23:59:59.000Z

    Fourier transform spectroscopy has found application in many areas including chemometrics, biomedical and biochemical studies, and atmospheric chemistry. This paper describes an investigation into the application of the LLNL Hyperspectral Infrared Imaging Spectrometer (HIRIS) to the non-destructive evaluation of man-made and natural materials. We begin by describing the HIRIS system and the objects studied in the investigation. Next, we describe the technique used to collect the hyperspec- tral imagery, and discuss the processing required to transform the data into usable form. We then describe a technique to analyze the data, and provide some preliminary results.

  2. FTIR spectrometer with solid-state drive system

    DOE Patents [OSTI]

    Rajic, Slobodan (Knoxville, TN); Seals, Roland D. (Oak Ridge, TN); Egert, Charles M. (Oak Ridge, TN)

    1999-01-01T23:59:59.000Z

    An FTIR spectrometer (10) and method using a solid-state drive system with thermally responsive members (27) that are subject to expansion upon heating and to contraction upon cooling. Such members (27) are assembled in the device (10) so as to move an angled, reflective surface (22) a small distance. The sample light beam (13) is received at a detector (24) along with a reference light beam (13) and there it is combined into a resulting signal. This allows the "interference" between the two beams to occur for spectral analysis by a processor (29).

  3. Positron lifetime spectrometer using a DC positron beam

    DOE Patents [OSTI]

    Xu, Jun; Moxom, Jeremy

    2003-10-21T23:59:59.000Z

    An entrance grid is positioned in the incident beam path of a DC beam positron lifetime spectrometer. The electrical potential difference between the sample and the entrance grid provides simultaneous acceleration of both the primary positrons and the secondary electrons. The result is a reduction in the time spread induced by the energy distribution of the secondary electrons. In addition, the sample, sample holder, entrance grid, and entrance face of the multichannel plate electron detector assembly are made parallel to each other, and are arranged at a tilt angle to the axis of the positron beam to effectively separate the path of the secondary electrons from the path of the incident positrons.

  4. Small system for tritium accelerator mass spectrometry

    DOE Patents [OSTI]

    Roberts, M.L.; Davis, J.C.

    1993-02-23T23:59:59.000Z

    Apparatus for ionizing and accelerating a sample containing isotopes of hydrogen and detecting the ratios of hydrogen isotopes contained in the sample is disclosed. An ion source generates a substantially linear ion beam including ions of tritium from the sample. A radio-frequency quadrupole accelerator is directly coupled to and axially aligned with the source at an angle of substantially zero degrees. The accelerator accelerates species of the sample having different mass to different energy levels along the same axis as the ion beam. A spectrometer is used to detect the concentration of tritium ions in the sample. In one form of the invention, an energy loss spectrometer is used which includes a foil to block the passage of hydrogen, deuterium and [sup 3]He ions, and a surface barrier or scintillation detector to detect the concentration of tritium ions. In another form of the invention, a combined momentum/energy loss spectrometer is used which includes a magnet to separate the ion beams, with Faraday cups to measure the hydrogen and deuterium and a surface barrier or scintillation detector for the tritium ions.

  5. Small system for tritium accelerator mass spectrometry

    DOE Patents [OSTI]

    Roberts, Mark L. (Livermore, CA); Davis, Jay C. (Livermore, CA)

    1993-01-01T23:59:59.000Z

    Apparatus for ionizing and accelerating a sample containing isotopes of hydrogen and detecting the ratios of hydrogen isotopes contained in the sample is disclosed. An ion source generates a substantially linear ion beam including ions of tritium from the sample. A radio-frequency quadrupole accelerator is directly coupled to and axially aligned with the source at an angle of substantially zero degrees. The accelerator accelerates species of the sample having different mass to different energy levels along the same axis as the ion beam. A spectrometer is used to detect the concentration of tritium ions in the sample. In one form of the invention, an energy loss spectrometer is used which includes a foil to block the passage of hydrogen, deuterium and .sup.3 He ions, and a surface barrier or scintillation detector to detect the concentration of tritium ions. In another form of the invention, a combined momentum/energy loss spectrometer is used which includes a magnet to separate the ion beams, with Faraday cups to measure the hydrogen and deuterium and a surface barrier or scintillation detector for the tritium ions.

  6. Method for predicting peptide detection in mass spectrometry

    DOE Patents [OSTI]

    Kangas, Lars [West Richland, WA; Smith, Richard D [Richland, WA; Petritis, Konstantinos [Richland, WA

    2010-07-13T23:59:59.000Z

    A method of predicting whether a peptide present in a biological sample will be detected by analysis with a mass spectrometer. The method uses at least one mass spectrometer to perform repeated analysis of a sample containing peptides from proteins with known amino acids. The method then generates a data set of peptides identified as contained within the sample by the repeated analysis. The method then calculates the probability that a specific peptide in the data set was detected in the repeated analysis. The method then creates a plurality of vectors, where each vector has a plurality of dimensions, and each dimension represents a property of one or more of the amino acids present in each peptide and adjacent peptides in the data set. Using these vectors, the method then generates an algorithm from the plurality of vectors and the calculated probabilities that specific peptides in the data set were detected in the repeated analysis. The algorithm is thus capable of calculating the probability that a hypothetical peptide represented as a vector will be detected by a mass spectrometry based proteomic platform, given that the peptide is present in a sample introduced into a mass spectrometer.

  7. A solenoidal electron spectrometer for a precision measurement of the neutron $?$-asymmetry with ultracold neutrons

    E-Print Network [OSTI]

    B. Plaster; R. Carr; B. W. Filippone; D. Harrison; J. Hsiao; T. M. Ito; J. Liu; J. W. Martin; B. Tipton; J. Yuan

    2008-06-12T23:59:59.000Z

    We describe an electron spectrometer designed for a precision measurement of the neutron $\\beta$-asymmetry with spin-polarized ultracold neutrons. The spectrometer consists of a 1.0-Tesla solenoidal field with two identical multiwire proportional chamber and plastic scintillator electron detector packages situated within 0.6-Tesla field-expansion regions. Select results from performance studies of the spectrometer with calibration sources are reported.

  8. PRISMA Spectrometer EVR Spectra And Collection Efficiencies In Gas-Filled Mode

    SciTech Connect (OSTI)

    Dragosavac, D. R.; Ujic, P. N.; Subotic, K. M. [Institute of Nuclear Sciences VINCA, PO Box 522, 11001 Belgrade (Serbia and Montenegro); Scarlassara, F. [Universita di Padova, Padova (Italy); INFN Sezione di Padova, Padova (Italy)

    2007-04-23T23:59:59.000Z

    In order to study nuclear fusion reaction, the heavy-ion magnetic spectrometer PRISMA installed at INFN Legnaro is planned to be modified to work in Gas-Filled Mode. For that purpose, the possible response of the spectrometer will be examined in Rutherford scattering experiments which simulate the fusion reaction products. predictions for the evaporation residue (EVR) position spectra and collection efficiencies, as well as the respective spectrometer set ups, as determined using the algorithm of ANAMARI code, are presented.

  9. High gain, Fast Scan, Broad Spectrum Parallel Beam Wavelength Dispersive X-ray Spectrometer for SEM

    SciTech Connect (OSTI)

    OHara, David

    2009-05-08T23:59:59.000Z

    During contract # DE-FG02-ER83545, Parallax Research, Inc. developed a High gain, Fast Scan Broad Spectrum Parallel beam Wavelength Dispersive X-ray Spectrometer for use on Scanning Electron Microscopes (SEM). This new spectrometer allows very fast high resolution elemental analysis of samples in an electron microscope. By comparison to previous WDS spectrometers, it can change from one energy position to another very quickly and has an extended range compared to some similar products.

  10. O Isotopic Composition of CaCO3 Measured by Continuous Flow Isotope Ratio Mass Spectrometry: Statistical Evaluation and

    E-Print Network [OSTI]

    d13 C and d18 O Isotopic Composition of CaCO3 Measured by Continuous Flow Isotope Ratio Mass method streamlines the classical phosphoric acid ­ calcium carbonate (H3 PO4 ­ CaCO3 ) reaction method XL continuous flow isotope ratio mass spectrometer. Conditions for which the H3 PO4 ­ CaCO3 reaction

  11. Characterisation of deuterium spectra from laser driven multi-species sources by employing differentially filtered image plate detectors in Thomson spectrometers

    SciTech Connect (OSTI)

    Alejo, A.; Kar, S., E-mail: s.kar@qub.ac.uk; Ahmed, H.; Doria, D.; Green, A.; Jung, D.; Lewis, C. L. S.; Nersisyan, G. [Centre for Plasma Physics, School of Mathematics and Physics, Queen's University Belfast, Belfast BT7 1NN (United Kingdom); Krygier, A. G.; Freeman, R. R. [Department of Physics, The Ohio State University, Columbus, Ohio 43210 (United States); Clarke, R.; Green, J. S.; Notley, M. [Central Laser Facility, Rutherford Appleton Laboratory, Didcot, Oxfordshire OX11 0QX (United Kingdom); Fernandez, J. [Central Laser Facility, Rutherford Appleton Laboratory, Didcot, Oxfordshire OX11 0QX (United Kingdom); Instituto de Fusión Nuclear, Universidad Politécnica de Madrid, 28006 Madrid (Spain); Fuchs, J. [LULI, École Polytechnique, CNRS, CEA, UPMC, 91128 Palaiseau (France); Kleinschmidt, A.; Roth, M. [Institut für Kernphysik, Technische Universität Darmstadt, Schloßgartenstrasse 9, D-64289 Darmstadt (Germany); Morrison, J. T. [Propulsion Systems Directorate, Air Force Research Lab, Wright Patterson Air Force Base, Ohio 45433 (United States); Najmudin, Z.; Nakamura, H. [Blackett Laboratory, Department of Physics, Imperial College, London SW7 2AZ (United Kingdom); and others

    2014-09-15T23:59:59.000Z

    A novel method for characterising the full spectrum of deuteron ions emitted by laser driven multi-species ion sources is discussed. The procedure is based on using differential filtering over the detector of a Thompson parabola ion spectrometer, which enables discrimination of deuterium ions from heavier ion species with the same charge-to-mass ratio (such as C{sup 6+}, O{sup 8+}, etc.). Commonly used Fuji Image plates were used as detectors in the spectrometer, whose absolute response to deuterium ions over a wide range of energies was calibrated by using slotted CR-39 nuclear track detectors. A typical deuterium ion spectrum diagnosed in a recent experimental campaign is presented, which was produced from a thin deuterated plastic foil target irradiated by a high power laser.

  12. Light ion transfer reactions with the HELIOS spectrometer

    SciTech Connect (OSTI)

    Back, B. B. [Physics Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Collaboration: HELIOS Collaboration

    2012-10-20T23:59:59.000Z

    Light-ion induced transfer and inelastic scattering reactions on stable or long-lived targets have been used extensively to study the structure of nuclei near the line of {beta}-stability, and much of the detailed information on the single-particle structure of nuclei has been derived from such studies. Recently, however, a substantial expansion of the range of isotopes, for which this nuclear structure information can be obtained, has presented itself by using radioactive beams in inverse kinematics reactions. Such beams are now available at a number of facilities around the world, including the in-flight production method and CARIBU facility at ATLAS. The HELIOS spectrometer, which has been used since August 2008 at ATLAS, circumvents many of the problems associated with inverse kinematics. In this talk I will discuss the principle of the spectrometer as well as some of main physics results that have been obtained to date in nuclei ranging from {sup 13}B to {sup 137}Xe using both stable and radioactive beams.

  13. High resolution, high rate X-ray spectrometer

    DOE Patents [OSTI]

    Goulding, Frederick S. (Lafayette, CA); Landis, Donald A. (Pinole, CA)

    1987-01-01T23:59:59.000Z

    A pulse processing system (10) for use in an X-ray spectrometer in which a ain channel pulse shaper (12) and a fast channel pulse shaper (13) each produce a substantially symmetrical triangular pulse (f, p) for each event detected by the spectrometer, with the pulse width of the pulses being substantially independent of the magnitude of the detected event and with the pulse width of the fast pulses (p) being substantially shorter than the pulse width of the main channel pulses (f). A pile-up rejector circuit (19) allows output pulses to be generated, with amplitudes linearly related to the magnitude of the detected events, whenever the peak of a main channel pulse (f) is not affected by a preceding or succeeding main channel pulse, while inhibiting output pulses wherein peak magnitudes of main channel pulses are affected by adjacent pulses. The substantially symmetrical triangular main channel pulses (f) are generated by the weighted addition (27-31) of successive RC integrations (24, 25, 26) of an RC differentiated step wave (23). The substantially symmetrical triangular fast channel pulses (p) are generated by the RC integration ( 43) of a bipolar pulse (o) in which the amplitude of the second half is 1/e that of the first half, with the RC time constant of integration being equal to one-half the width of the bipolar pulse.

  14. Ion source for high-precision mass spectrometry

    DOE Patents [OSTI]

    Todd, P.J.; McKown, H.S.; Smith, D.H.

    1982-04-26T23:59:59.000Z

    The invention is directed to a method for increasing the precision of positive-ion relative abundance measurements conducted in a sector mass spectrometer having an ion source for directing a beam of positive ions onto a collimating slit. The method comprises incorporating in the source an electrostatic lens assembly for providing a positive-ion beam of circular cross section for collimation by the slit. 2 figures, 3 tables.

  15. Polarisation studies of the prompt gamma-ray emission from GRB 041219a using the Spectrometer aboard INTEGRAL

    E-Print Network [OSTI]

    McGlynn, S; Dean, A J; Hanlon, L; McBreen, S; Willis, D R; McBreen, B; Bird, A J; Foley, S

    2007-01-01T23:59:59.000Z

    The spectrometer aboard INTEGRAL, SPI, has the capability to detect the signature of polarised emission from a bright gamma-ray source. GRB 041219a is the most intense burst localised by INTEGRAL and is an ideal candidate for such a study. Polarisation can be measured using multiple events scattered into adjacent detectors because the Compton scatter angle depends on the polarisation of the incoming photon. A search for linear polarisation in the most intense pulse of duration 66 seconds and in the brightest 12 seconds of GRB 041219a was performed in the 100-350keV, 100-500keV and 100keV-1MeV energy ranges. The multiple event data from the spectrometer was analysed and compared with the predicted instrument response obtained from Monte-Carlo simulations using the GEANT 4 INTEGRAL mass model. The chi^2 distribution between the real and simulated data as a function of the percentage polarisation and polarisation angle was calculated for all three energy ranges. The degree of linear polarisation in the brightest...

  16. A Novel 9.4 Tesla FT-ICR Mass Spectrometer with Improved Sensitivity, Mass Resolution, and Mass Range, for Petroleum Heavy Crude Oil Analysis

    E-Print Network [OSTI]

    Range, for Petroleum Heavy Crude Oil Analysis Nathan K. Kaiser, John P. Quinn, Greg T. Blakney NHMFL 9.4 T FT- species in petroleum crude oil and its products, extending to "heavy" crudes for unequivocal identification of sulfur-containing components in petroloeum heavy crude oils. Facilities: NHMFL 9

  17. Dynamic multiplexed analysis method using ion mobility spectrometer

    DOE Patents [OSTI]

    Belov, Mikhail E [Richland, WA

    2010-05-18T23:59:59.000Z

    A method for multiplexed analysis using ion mobility spectrometer in which the effectiveness and efficiency of the multiplexed method is optimized by automatically adjusting rates of passage of analyte materials through an IMS drift tube during operation of the system. This automatic adjustment is performed by the IMS instrument itself after determining the appropriate levels of adjustment according to the method of the present invention. In one example, the adjustment of the rates of passage for these materials is determined by quantifying the total number of analyte molecules delivered to the ion trap in a preselected period of time, comparing this number to the charge capacity of the ion trap, selecting a gate opening sequence; and implementing the selected gate opening sequence to obtain a preselected rate of analytes within said IMS drift tube.

  18. Aerosol beam-focus laser-induced plasma spectrometer device

    DOE Patents [OSTI]

    Cheng, Meng-Dawn (Oak Ridge, TN)

    2002-01-01T23:59:59.000Z

    An apparatus for detecting elements in an aerosol includes an aerosol beam focuser for concentrating aerosol into an aerosol beam; a laser for directing a laser beam into the aerosol beam to form a plasma; a detection device that detects a wavelength of a light emission caused by the formation of the plasma. The detection device can be a spectrometer having at least one grating and a gated intensified charge-coupled device. The apparatus may also include a processor that correlates the wavelength of the light emission caused by the formation of the plasma with an identity of an element that corresponds to the wavelength. Furthermore, the apparatus can also include an aerosol generator for forming an aerosol beam from bulk materials. A method for detecting elements in an aerosol is also disclosed.

  19. Isotopic response with small scintillator based gamma-ray spectrometers

    DOE Patents [OSTI]

    Madden, Norman W. (Sparks, NV); Goulding, Frederick S. (Lafayette, CA); Asztalos, Stephen J. (Oakland, CA)

    2012-01-24T23:59:59.000Z

    The intrinsic background of a gamma ray spectrometer is significantly reduced by surrounding the scintillator with a second scintillator. This second (external) scintillator surrounds the first scintillator and has an opening of approximately the same diameter as the smaller central scintillator in the forward direction. The second scintillator is selected to have a higher atomic number, and thus has a larger probability for a Compton scattering interaction than within the inner region. Scattering events that are essentially simultaneous in coincidence to the first and second scintillators, from an electronics perspective, are precluded electronically from the data stream. Thus, only gamma-rays that are wholly contained in the smaller central scintillator are used for analytic purposes.

  20. THE ABSOLUTE CALIBRATION OF THE EUV IMAGING SPECTROMETER ON HINODE

    SciTech Connect (OSTI)

    Warren, Harry P. [Space Science Division, Naval Research Laboratory, Washington, DC 20375 (United States); Ugarte-Urra, Ignacio [College of Science, George Mason University, 4400 University Drive, Fairfax, VA 22030 (United States); Landi, Enrico [Department of Atmospheric, Oceanic and Space Sciences, University of Michigan, Ann Arbor, MI 48109 (United States)

    2014-07-01T23:59:59.000Z

    We investigate the absolute calibration of the EUV Imaging Spectrometer (EIS) on Hinode by comparing EIS full-disk mosaics with irradiance observations from the EUV Variability Experiment on the Solar Dynamics Observatory. We also use extended observations of the quiet corona above the limb combined with a simple differential emission measure model to establish new effective area curves that incorporate information from the most recent atomic physics calculations. We find that changes to the EIS instrument sensitivity are a complex function of both time and wavelength. We find that the sensitivity is decaying exponentially with time and that the decay constants vary with wavelength. The EIS short wavelength channel shows significantly longer decay times than the long wavelength channel.

  1. Two wide-angle imaging neutral-atom spectrometers

    SciTech Connect (OSTI)

    McComas, D.J.

    1997-12-31T23:59:59.000Z

    The Two Wide-angle Imaging Neutral-atom Spectrometers (TWINS) mission provides a new capability for stereoscopically imaging the magnetosphere. By imaging the charge exchange neutral atoms over a broad energy range (1 < E , {approximately} 100 keV) using two identical instruments on two widely-spaced high-altitude, high-inclination spacecraft, TWINS will enable the 3-dimensional visualization and the resolution of large scale structures and dynamics within the magnetosphere for the first time. These observations will provide a leap ahead in the understanding of the global aspects of the terrestrial magnetosphere and directly address a number of critical issues in the ``Sun-Earth Connections`` science theme of the NASA Office of Space Science.

  2. Imaging X-ray Thomson Scattering Spectrometer Design and Demonstration

    SciTech Connect (OSTI)

    Gamboa, E.J. [University of Michigan; Huntington, C.M. [University of Michigan; Trantham, M.R. [University of Michigan; Keiter, P.A [University of Michigan; Drake, R.P. [University of Michigan; Montgomery, David [Los Alamos National Laboratory; Benage, John F. [Los Alamos National Laboratory; Letzring, Samuel A. [Los Alamos National Laboratory

    2012-05-04T23:59:59.000Z

    In many laboratory astrophysics experiments, intense laser irradiation creates novel material conditions with large, one-dimensional gradients in the temperature, density, and ionization state. X-ray Thomson scattering is a powerful technique for measuring these plasma parameters. However, the scattered signal has previously been measured with little or no spatial resolution, which limits the ability to diagnose inhomogeneous plasmas. We report on the development of a new imaging x-ray Thomson spectrometer (IXTS) for the Omega laser facility. The diffraction of x-rays from a toroidally-curved crystal creates high-resolution images that are spatially resolved along a one-dimensional profile while spectrally dispersing the radiation. This focusing geometry allows for high brightness while localizing noise sources and improving the linearity of the dispersion. Preliminary results are presented from a scattering experiment that used the IXTS to measure the temperature profile of a shocked carbon foam.

  3. Report on Second Activations with the Lead Slowing Down Spectrometer

    SciTech Connect (OSTI)

    Stave, Sean C.; Mace, Emily K.; Pratt, Sharon L.; Warren, Glen A.

    2012-04-27T23:59:59.000Z

    Summary On August 18 and 19 2011, five items were irradiated with neutrons using the Lead Slowing Down Spectrometer (LSDS). After irradiation, dose measurements and gamma-spectrometry measurements were completed on all of the samples. No contamination was found on the samples, and all but one provided no dose. Gamma-spectroscopy measurements qualitatively agreed with expectations based on the materials. As during the first activation run, we observed activation in the room in general, mostly due to 56Mn and 24Na. Most of the activation of the samples was short lived, with half-lives on the scale of hours to days, except for 60Co which has a half-life of 5.3 y.

  4. Simulation-guided optimization of small-angle analyzer geometry in the neutron backscattering spectrometer SPHERES

    SciTech Connect (OSTI)

    Wuttke, Joachim; Zamponi, Michaela [Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science at MLZ, Lichtenbergstraße 1, 85747 Garching (Germany)] [Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science at MLZ, Lichtenbergstraße 1, 85747 Garching (Germany)

    2013-11-15T23:59:59.000Z

    The resolution of neutron backscattering spectrometers deteriorates at small scattering angles where analyzers deviate from exact backscattering. By reducing the azimuth angle range of the analyzers, the resolution can be improved with little loss of peak intensity. Measurements at the spectrometer SPHERES are in excellent agreement with simulations, which proves the dominance of geometric effects.

  5. Echelle grating multi-order imaging spectrometer utilizing a catadioptric lens

    DOE Patents [OSTI]

    Chrisp, Michael P; Bowers, Joel M

    2014-05-27T23:59:59.000Z

    A cryogenically cooled imaging spectrometer that includes a spectrometer housing having a first side and a second side opposite the first side. An entrance slit is on the first side of the spectrometer housing and directs light to a cross-disperser grating. An echelle immersions grating and a catadioptric lens are positioned in the housing to receive the light. A cryogenically cooled detector is located in the housing on the second side of the spectrometer housing. Light from the entrance slit is directed to the cross-disperser grating. The light is directed from the cross-disperser grating to the echelle immersions grating. The light is directed from the echelle immersions grating to the cryogenically cooled detector on the second side of the spectrometer housing.

  6. Direct determination of Neutrino Mass from Tritium Beta Spectrum

    E-Print Network [OSTI]

    C. Weinheimer

    2009-12-08T23:59:59.000Z

    The investigation of the endpoint region of the tritium beta decay spectrum is still the most sensitive direct method to determine the neutrino mass scale. In the nineties and the beginning of this century the tritium beta decay experiments at Mainz and Troitsk have reached a sensitivity on the neutrino mass of 2 eV/c^2 . They were using a new type of high-resolution spectrometer with large sensitivity, the MAC-E-Filter, and were studying the systematics in detail. Currently, the KATRIN experiment is being set up at Forschungszentrum Karlsruhe, Germany. KATRIN will improve the neutrino mass sensitivity by one order of magnitude down to 0.2 eV/c^2, sufficient to cover the degenerate neutrino mass scenarios and the cosmologically relevant neutrino mass range.

  7. Potential incorporation of transuranics into uranium phases

    SciTech Connect (OSTI)

    Kim, C. W.; Wronkiewicz, D. J.; Buck, E. C.

    1999-12-07T23:59:59.000Z

    The UO{sub 2} in spent nuclear fuel is unstable under moist oxidizing conditions and will be altered to uranyl oxide hydrate phases. The transuranics released during the corrosion of spent fuel may also be incorporated into the structures of secondary U{sup 6+} phases. The incorporation of radionuclides into alteration products will affect their mobility. A series of precipitation tests were conducted at either 150 or 90 C for seven days to determine the potential incorporation of Ce{sup 4+} and Nd{sup 3+} (surrogates for Pu{sup 4+} and Am{sup 3+}, respectively) into uranium phases. Ianthinite ([U{sub 2}{sup 4+}(UO{sub 2}){sub 4}O{sub 6}(OH){sub 4}(H{sub 2}O){sub 4}](H{sub 2}O){sub 5}) was produced by dissolving uranium oxyacetate in a solution containing copper acetate monohydrate as a reductant. The leachant used in these tests were doped with either 2.1 ppm cerium or 399 ppm neodymium. Inductively coupled plasma-mass spectrometer (ICP-MS) analysis of the solid phase reaction products which were dissolved in a HNO{sub 3} solution indicates that about 306 ppm Ce (K{sub d} = 146) was incorporated into ianthinite, while neodymium contents were much higher, being approximately 24,800 ppm (K{sub d} = 62). Solid phase examinations using an analytical transmission electron microscope/electron energy-loss spectrometer (AEM/EELS) indicate a uniform distribution of Nd, while Ce contents were below detection. Becquerelite (Ca[(UO{sub 2}){sub 6}O{sub 4}(OH){sub 6}]{center_dot}8H{sub 2}O) was produced by dissolving uranium oxyacetate in a solution containing calcium acetate. The leachant in these tests was doped with either 2.1 ppm cerium or 277 ppm neodymium. ICP-MS results indicate that about 33 ppm Ce (K{sub d}=16) was incorporated into becquerelite, while neodymium contents were higher, being approximately 1,300 ppm (K{sub d}=5). Homogeneous distribution of Nd in the solid phase was noted during AEM/EELS examination, and Ce contents were also below detection.

  8. J. Environ. Radioactivity 5 (1987)425--444 The Mass Spectrometric Determination of Fallout

    E-Print Network [OSTI]

    Buesseler, Ken

    1987-01-01T23:59:59.000Z

    and Justin E. Halverson Savannah River Laboratory,,Aiken, SouthCarolina29808,USA (Received 17November 1986 in this study is operated by E. I. DuPont de Nemours & Co. at the Savannah River Laboratory (S.R.L.) in South Carolina. The instrument was designed and built similar to other mass spectrometers within the national

  9. Laser vaporization/ionization interface for coupling microscale separation techniques with mass spectrometry

    DOE Patents [OSTI]

    Yeung, E.S.; Chang, Y.C.

    1999-06-29T23:59:59.000Z

    The present invention provides a laser-induced vaporization and ionization interface for directly coupling microscale separation processes to a mass spectrometer. Vaporization and ionization of the separated analytes are facilitated by the addition of a light-absorbing component to the separation buffer or solvent. 8 figs.

  10. Mass spectrometry analysis of Arabidopsis histone H3 reveals distinct combinations of post-translational

    E-Print Network [OSTI]

    Jacobsen, Steve

    , Donald F. Hunt3 and Steven E. Jacobsen1, * Life Science Core Curriculum and 1 Molecular, Cell to electrospray ionization on a hybrid linear ion trap- Fourier transform mass spectrometer (LTQ/FTMS). We find and the histone octamer can be altered, influencing the sliding or movement of nucleosomes and thereby affecting

  11. Method for analyzing the mass of a sample using a cold cathode ionization source mass filter

    DOE Patents [OSTI]

    Felter, Thomas E.

    2003-10-14T23:59:59.000Z

    An improved quadrupole mass spectrometer is described. The improvement lies in the substitution of the conventional hot filament electron source with a cold cathode field emitter array which in turn allows operating a small QMS at much high internal pressures then are currently achievable. By eliminating of the hot filament such problems as thermally "cracking" delicate analyte molecules, outgassing a "hot" filament, high power requirements, filament contamination by outgas species, and spurious em fields are avoid all together. In addition, the ability of produce FEAs using well-known and well developed photolithographic techniques, permits building a QMS having multiple redundancies of the ionization source at very low additional cost.

  12. Proposal for the award of thin-walled precision aluminium alloy tubes for the Atlas Muon Spectrometer

    E-Print Network [OSTI]

    1999-01-01T23:59:59.000Z

    Proposal for the award of thin-walled precision aluminium alloy tubes for the Atlas Muon Spectrometer

  13. KATRIN: an experiment to measure the neutrino mass

    E-Print Network [OSTI]

    R. G. H. Robertson; for the KATRIN Collaboration

    2007-12-23T23:59:59.000Z

    KATRIN is a very large scale tritium-beta-decay experiment to determine the mass of the neutrino. It is presently under construction at the Forschungszentrum Karlsruhe, and makes use of the Tritium Laboratory built there for the ITER project. The combination of a very large retarding-potential electrostatic-magnetic spectrometer and an intense gaseous molecular tritium source makes possible a sensitivity to neutrino mass of 0.2 eV, about an order of magnitude below present laboratory limits. The measurement is kinematic and independent of whether the neutrino is Dirac or Majorana. The status of the project is summarized briefly in this report.

  14. Neutron flux estimations based on niobium impurities in reactor pressure vessel steel

    SciTech Connect (OSTI)

    Baers, L.B.; Hasanen, E.K. [Technical Research Centre of Finland, Espoo (Finland). Reactor Lab.

    1994-12-31T23:59:59.000Z

    The use of (ppm level) niobium impurities in reactor pressure vessel (RPV) steel for neutron flux estimations based on the reaction {sup 93}Nb (n,n{prime}) {sup 93m}Nb has been reported previously. The method has now been further investigated and refined. Small niobium fractions in RPV steel ({approx} ppm) and plating ({approx} 1%) materials have been separated by ion exchange chromatography in one to three steps. The measured Nb fractions in samples from some four pressure vessel (RPV) base materials were 1 to 3 ppm. The purification of tens of milligrams of RPV material provides sufficient amounts of niobium for mass determination with a highly sensitive (10{sup {minus}5} ppm) Inductively Coupled Plasma Mass Spectrometer (ICP-MS). The {sup 93m}Nb and small remaining {sup 54}Mn activities were measured with a Calibrated Liquid Scintillation Counter (LSC) based on dual label technique and almost 100% efficiency to {sup 93m}Nb. One purification is needed for plating materials ({approx}1% Nb) and two purifications of about one gram of steel with Nb impurities in order to resolve the needed activities ({approx}10 Bq {sup 93m}Nb/{mu}g Nb). The achieved accuracy of the measured specific {sup 93m}Nb activities was about {+-} 3% (1{sigma}) in irradiated RPV plating materials and about {+-} 4% for Nb ppm impurities.

  15. Analytical Chemistry Division annual progress report for period ending December 31, 1991

    SciTech Connect (OSTI)

    NONE

    1992-01-01T23:59:59.000Z

    The following sentences highlight some of the technical activities carried out during 1991. They illustrate the diversity of programs and technical work performed within the Analytical Chemistry Division. Our neutron activation analysis laboratory at HFIR was placed into operation during 1991. We have combined inductively coupled plasma mass spectrometry (ICP/MS) with a preparation procedure developed at the Argonne National Laboratory to measure ultra-trace levels of U, Pu, Np, and Am in body fluids, primarily urine. Much progress has been made over the last year in the interfacing of an rf-powered glow discharge source to a double-focusing mass spectrometer. Preliminary experiments using electrospray ionization combined with ion trap mass spectrometry show much promise for the analysis of metals in solution. A secondary ion microprobe has been constructed that permits determination of the distribution of organic compounds less than a monolayer thick on samples as large as 1 cm diameter. Fourier transform mass spectrometry has been demonstrated to be a highly effective tool for the detailed characterization of biopolymers, especially normal and modified oligonucleotides. Much has been accomplished in understanding the fundamentals of quadrupole ion trap mass spectrometry. Work with ITMS instrumentation has led to the development of rapid methods for the detection of trace organics in environmental and physiological samples. A new type of time-of-flight mass spectrometer was designed for use with our positron ionization experiments. Fundamental research on chromatography at high concentrations and on gas-solid adsorption has continued. The preparation of a monograph on the chemistry of environmental tobacco smoke was completed this year.

  16. ONE-DIMENSIONAL MODELING FOR TEMPERATURE-DEPENDENT UPFLOW IN THE DIMMING REGION OBSERVED BY HINODE/EUV IMAGING SPECTROMETER

    SciTech Connect (OSTI)

    Imada, S.; Shimizu, T. [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, Chuo-ku, Sagamihara-shi, Kanagawa 252-5210 (Japan); Hara, H.; Watanabe, T. [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka-shi, Tokyo 181-8588 (Japan); Murakami, I. [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki, Gifu 509-5292 (Japan); Harra, L. K. [UCL-Mullard Space Science Laboratory, Holmbury St Mary, Dorking, Surrey, RH5 6NT (United Kingdom); Zweibel, E. G. [Department of Astronomy, University of Wisconsin-Madison, 475 N Charter Street, Madison, WI 53706 (United States)

    2011-12-10T23:59:59.000Z

    We previously found a temperature-dependent upflow in the dimming region following a coronal mass ejection observed by the Hinode EUV Imaging Spectrometer (EIS). In this paper, we reanalyzed the observations along with previous work on this event and provided boundary conditions for modeling. We found that the intensity in the dimming region dramatically drops within 30 minutes from the flare onset, and the dimming region reaches the equilibrium stage after {approx}1 hr. The temperature-dependent upflows were observed during the equilibrium stage by EIS. The cross-sectional area of the flux tube in the dimming region does not appear to expand significantly. From the observational constraints, we reconstructed the temperature-dependent upflow by using a new method that considers the mass and momentum conservation law and demonstrated the height variation of plasma conditions in the dimming region. We found that a super-radial expansion of the cross-sectional area is required to satisfy the mass conservation and momentum equations. There is a steep temperature and velocity gradient of around 7 Mm from the solar surface. This result may suggest that the strong heating occurred above 7 Mm from the solar surface in the dimming region. We also showed that the ionization equilibrium assumption in the dimming region is violated, especially in the higher temperature range.

  17. Upgrades of the high resolution imaging x-ray crystal spectrometers on experimental advanced superconducting tokamak

    SciTech Connect (OSTI)

    Lu, B.; Wang, F.; Fu, J.; Li, Y.; Wan, B. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, Anhui (China); Shi, Y. [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, Anhui (China); National Fusion Research Institute, 52 Eoeun-Dong, Yusung-Gu, Daejeon (Korea, Republic of); Bitter, M.; Hill, K. W. [Princeton Plasma Physics Laboratory, MS37-B332, Princeton, New Jersey 08543-0451 (United States); Lee, S. G. [National Fusion Research Institute, 52 Eoeun-Dong, Yusung-Gu, Daejeon (Korea, Republic of)

    2012-10-15T23:59:59.000Z

    Two imaging x-ray crystal spectrometers, the so-called 'poloidal' and 'tangential' spectrometers, were recently implemented on experimental advanced superconducting tokamak (EAST) to provide spatially and temporally resolved impurity ion temperature (T{sub i}), electron temperature (T{sub e}) and rotation velocity profiles. They are derived from Doppler width of W line for Ti, the intensity ratio of Li-like satellites to W line for Te, and Doppler shift of W line for rotation. Each spectrometer originally consisted of a spherically curved crystal and a two-dimensional multi-wire proportional counter (MWPC) detector. Both spectrometers have now been upgraded. The layout of the tangential spectrometer was modified, since it had to be moved to a different port, and the spectrometer was equipped with two high count rate Pilatus detectors (Model 100 K) to overcome the count rate limitation of the MWPC and to improve its time resolution. The poloidal spectrometer was equipped with two spherically bent crystals to record the spectra of He-like and H-like argon simultaneously and side by side on the original MWPC. These upgrades are described, and new results from the latest EAST experimental campaign are presented.

  18. DC superconducting quantum interference device usable in nuclear quadrupole resonance and zero field nuclear magnetic spectrometers

    DOE Patents [OSTI]

    Fan, N.Q.; Clarke, J.

    1993-10-19T23:59:59.000Z

    A spectrometer for measuring the nuclear quadrupole resonance spectra or the zero-field nuclear magnetic resonance spectra generated by a sample is disclosed. The spectrometer uses an amplifier having a dc SQUID operating in a flux-locked loop for generating an amplified output as a function of the intensity of the signal generated by the sample. The flux-locked loop circuit includes an integrator. The amplifier also includes means for preventing the integrator from being driven into saturation. As a result, the time for the flux-locked loop to recover from the excitation pulses generated by the spectrometer is reduced. 7 figures.

  19. DC superconducting quantum interference device usable in nuclear quadrupole resonance and zero field nuclear magnetic spectrometers

    DOE Patents [OSTI]

    Fan, Non Q. (San Diego, CA); Clarke, John (Berkeley, CA)

    1993-01-01T23:59:59.000Z

    A spectrometer for measuring the nuclear quadrupole resonance spectra or the zero-field nuclear magnetic resonance spectra generated by a sample is disclosed. The spectrometer uses an amplifier having a dc SQUID operating in a flux-locked loop for generating an amplified output as a function of the intensity of the signal generated by the sample. The flux-locked loop circuit includes an integrator. The amplifier also includes means for preventing the integrator from being driven into saturation. As a result, the time for the flux-locked loop to recover from the excitation pulses generated by the spectrometer is reduced.

  20. A field-deployable gamma-ray spectrometer utilizing xenon at high pressure

    SciTech Connect (OSTI)

    Smith, G.C.; Mahler, G.J.; Yu, B.; Salwen, C.; Kane, W.R.; Lemley, J.R.

    1996-10-01T23:59:59.000Z

    Prototype gamma-ray spectrometers utilizing xenon gas at high pressure, suitable for applications in the nuclear safeguards, arms control, and nonproliferation communities, have been developed at Brookhaven National Laboratory (BNL). These spectrometers function as ambient-temperature ionization chambers detecting gamma rays with good efficiency in the energy range 50 keV - 2 MeV, with an energy resolution intermediate between semiconductor (Ge) and scintillation (NaI) spectrometers. They are capable of prolonged, low-power operation without a requirement for cryogenic fluids or other cooling mechanisms, and with the addition of small quantities of {sup 3}He gas, can function simultaneously as efficient thermal neutron detectors.

  1. A high-resolution imaging x-ray crystal spectrometer for high energy density plasmas

    SciTech Connect (OSTI)

    Chen, Hui, E-mail: chen33@llnl.gov, E-mail: bitter@pppl.gov; Magee, E.; Nagel, S. R.; Park, J.; Schneider, M. B.; Stone, G.; Williams, G. J.; Beiersdorfer, P. [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550-9234 (United States); Bitter, M., E-mail: chen33@llnl.gov, E-mail: bitter@pppl.gov; Hill, K. W. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Kerr, S. [Department of Applied Science, University of Alberta, Edmonton, Alberta T6G 2R3 (Canada)

    2014-11-15T23:59:59.000Z

    Adapting a concept developed for magnetic confinement fusion experiments, an imaging crystal spectrometer has been designed and tested for HED plasmas. The instrument uses a spherically bent quartz [211] crystal with radius of curvature of 490.8 mm. The instrument was tested at the Titan laser at Lawrence Livermore National Laboratory by irradiating titanium slabs with laser intensities of 10{sup 19}–10{sup 20} W/cm{sup 2}. He-like and Li-like Ti lines were recorded, from which the spectrometer performance was evaluated. This spectrometer provides very high spectral resolving power (E/dE > 7000) while acquiring a one-dimensional image of the source.

  2. A source of ultra-cold neutrons for the gravitational spectrometer GRANIT

    E-Print Network [OSTI]

    Schmidt-Wellenburg, P; Nesvizhevsky, V V; Plonka, C; Soldner, T; Vezzu, F; Zimmer, O

    2007-01-01T23:59:59.000Z

    We present the status of the development of a dedicated high density ultra-cold neutron (UCN) source dedicated to the gravitational spectrometer GRANIT. The source employs superthermal conversion of cold neutrons to UCN in superfluid helium. Tests have shown that UCN produced inside the liquid can be extracted into vacuum. Furthermore a dedicated neutron selection channel was tested to maintain high initial density and extract only neutrons with a vertical velocity component 20 cm/s for the spectrometer. This new source would have a phase-space density of 0.18 cm-3(m/s)-3 for the spectrometer.

  3. A source of ultra-cold neutrons for the gravitational spectrometer GRANIT

    E-Print Network [OSTI]

    P. Schmidt-Wellenburg; P. Geltenbort; V. V. Nesvizhevsky; C. Plonka; T. Soldner; F. Vezzu; O. Zimmer

    2007-08-21T23:59:59.000Z

    We present the status of the development of a dedicated high density ultra-cold neutron (UCN) source dedicated to the gravitational spectrometer GRANIT. The source employs superthermal conversion of cold neutrons to UCN in superfluid helium. Tests have shown that UCN produced inside the liquid can be extracted into vacuum. Furthermore a dedicated neutron selection channel was tested to maintain high initial density and extract only neutrons with a vertical velocity component 20 cm/s for the spectrometer. This new source would have a phase-space density of 0.18 cm-3(m/s)-3 for the spectrometer.

  4. X-ray crystal spectrometer upgrade for ITER-like wall experiments at JET

    SciTech Connect (OSTI)

    Shumack, A. E., E-mail: amy.shumack@ccfe.ac.uk [JET-EFDA, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); FOM Institute DIFFER, P.O. Box 1207, NL-3430 BE Nieuwegein (Netherlands); Rzadkiewicz, J. [National Centre for Nuclear Research, Andrzeja So?tana 7, 05-400 Otwock (Poland); Chernyshova, M.; Czarski, T.; Karpinski, L. [Institute of Plasma Physics and Laser Microfusion, Hery 23, 01-497 Warsaw (Poland); Jakubowska, K. [Institute of Plasma Physics and Laser Microfusion, Hery 23, 01-497 Warsaw (Poland); Université Bordeaux, CNRS, CEA, CELIA, UMR 5107, F-33405 Talence (France); Scholz, M. [Institute of Nuclear Physics PAN, ul. Radzikowskiego 152, 31-342 Kraków (Poland); Byszuk, A.; Cieszewski, R.; Kasprowicz, G.; Pozniak, K.; Wojenski, A.; Zabolotny, W. [Institute of Electronic Systems, Warsaw University of Technology, 00-665 Warsaw (Poland); Dominik, W. [Faculty of Physics, Institute of Experimental Physics, Warsaw University, 00-681 Warsaw (Poland); Conway, N. J.; Dalley, S.; Tyrrell, S.; Zastrow, K.-D. [JET-EFDA, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Figueiredo, J. [EFDA-CSU, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Associação EURATOM/IST, Instituto de Plasmas e Fusão Nuclear, Instituto Superior Técnico, Av Rovisco Pais, 1049-001 Lisbon (Portugal); and others

    2014-11-15T23:59:59.000Z

    The high resolution X-Ray crystal spectrometer at the JET tokamak has been upgraded with the main goal of measuring the tungsten impurity concentration. This is important for understanding impurity accumulation in the plasma after installation of the JET ITER-like wall (main chamber: Be, divertor: W). This contribution provides details of the upgraded spectrometer with a focus on the aspects important for spectral analysis and plasma parameter calculation. In particular, we describe the determination of the spectrometer sensitivity: important for impurity concentration determination.

  5. High-Sensitivity Delayed-Coincidence Spectrometer to Search for Short-Lived Nuclear States

    E-Print Network [OSTI]

    Morozov, V A; Norseev, Yu V; Sereeter, Z; Zlokazov, V B

    2002-01-01T23:59:59.000Z

    A high-sensitivity four-dimensional triple-coincidence spectrometer with two detectors is developed on the basis of an autocorrelation single-crystal scintillation time 4{\\pi} spectrometer and a semiconductor HPGe detector. The delayed-coincidence spectrometer is designed for searching for isomeric nano- and microsecond states in short-lived nuclei and for their related gamma-rays. Half-lives of short-lived states are measured in the range from 4 ns to 4 {\\mu}s. The sufficient activity of the monoisotopic source for the investigations does not exceed 0.01 {\\mu}Ci.

  6. FIELD TEST OF THE WATER-WHEEL IR (WIR) SPECTROMETER ON EVAPORATIVE SALT DEPOSITS AT TIBETAN PLATEAU. P. Sobron, J. J. Freeman, Alian Wang, Dept Earth and Planetary Sciences

    E-Print Network [OSTI]

    "contact survey", i.e., to install a WIR unit inside of a well set into the middle wheel of a pla- netary of WIR has a size of 10x7.5x6.5cm, mass of 450 grams, power consump- tion of 4W, and output data through transformed into a rugged, field portable NIR reflectance spectrometer that is able to operate in tough field

  7. ASIC for SDD-Based X-Ray Spectrometers

    SciTech Connect (OSTI)

    G De Geronimo; P Rehak; K Ackley; G Carini; W Chen; J Fried; J Keister; S Li; Z Li; et al.

    2011-12-31T23:59:59.000Z

    We present an application-specific integrated circuit (ASIC) for high-resolution x-ray spectrometers (XRS). The ASIC reads out signals from pixelated silicon drift detectors (SDDs). The pixel does not have an integrated field effect transistor (FET); rather, readout is accomplished by wire-bonding the anodes to the inputs of the ASIC. The ASIC dissipates 32 mW, and offers 16 channels of low-noise charge amplification, high-order shaping with baseline stabilization, discrimination, a novel pile-up rejector, and peak detection with an analog memory. The readout is sparse and based on custom low-power tristatable low-voltage differential signaling (LPT-LVDS). A unit of 64 SDD pixels, read out by four ASICs, covers an area of 12.8 cm{sup 2} and dissipates with the sensor biased about 15 mW/cm{sup 2}. As a tile-based system, the 64-pixel units cover a large detection area. Our preliminary measurements at -44 C show a FWHM of 145 eV at the 5.9 keV peak of a {sup 55}Fe source, and less than 80 eV on a test-pulse line at 200 eV.

  8. In-situ droplet monitoring for self-tuning spectrometers

    DOE Patents [OSTI]

    Montaser, Akbar (Potomac, MD); Jorabchi, Kaveh (Arlington, VA); Kahen, Kaveh (Kleinburg, CA)

    2010-09-28T23:59:59.000Z

    A laser scattering based imaging technique is utilized in order to visualize the aerosol droplets in an inductively coupled plasma (ICP) torch from an aerosol source to the site of analytical measurements. The resulting snapshots provide key information about the spatial distribution of the aerosol introduced by direct and indirect injection devices: 1) a direct injection high efficiency nebulizer (DIHEN); 2) a large-bore DIHEN (LB-DIHEN); and 3) a PFA microflow nebulizer with a PFA Scott-type spray chamber. Moreover, particle image velocimetry (PIV) is used to study the in-situ behavior of the aerosol before interaction with, for example, plasma, while the individual surviving droplets are explored by particle tracking velocimetry (PTV). Further, the velocity distribution of the surviving droplets demonstrates the importance of the initial droplet velocities in complete desolvation of the aerosol for optimum analytical performance in ICP spectrometries. These new observations are important in the design of the next-generation direct injection devices for lower sample consumption, higher sensitivity, lower noise levels, suppressed matrix effects, and for developing smart spectrometers. For example, a controller can be provided to control the output of the aerosol source by controlling the configuration of the source or the gas flow rate via feedback information concerning the aerosol.

  9. Multichannel CdZnTe Gamma Ray Spectrometer

    SciTech Connect (OSTI)

    F. P. Doty; C. L. Lingren; B. A. Apotovsky; J. Brunsch; J. F. Butler; T. Collins; R. L. Conwell; S. Friesenhahn; J. Gormley; B. Pi; S. Zhao (Digirad Corp., San Diego, CA); F. L. Augustine, Augustine Engineering, Encinitas, CA; B. A. Bennet; E. Cross; R. B. James (Sandia Nat'l. Labs.)

    1998-07-22T23:59:59.000Z

    A 3 cm{sup 3} multichannel gamma spectrometer for DOE applications is under development by Digirad Corporation. The device is based on a position sensitive detector packaged in a compact multi-chip module (MCM) with integrated readout circuitry. The modular, multichannel design will enable identification and quantitative analysis of radionuclides in extended sources, or sources containing low levels of activity. The MCM approach has the advantages that the modules are designed for imaging applications, and the sensitivity can be arbitrarily increased by increasing the number of pixels, i.e. adding modules to the instrument. For a high sensitivity probe, the outputs for each pixel can be corrected for gain and offset variations, and summed digitally. Single pixel results obtained with discrete low noise readout indicate energy resolution of 3 keV can be approached with currently available CdZnTe. The energy resolution demonstrated to date with MCMs for 511 keV gamma rays is 10 keV.

  10. Addition and recombination reactions of unsaturated radicals using a novel laser kinetics spectrometer

    E-Print Network [OSTI]

    Ismail, Huzeifa

    2008-01-01T23:59:59.000Z

    This thesis describes the construction of a novel, low-noise laser kinetics spectrometer. A quasi-CW (picosecond pulse), tunable Ti:Sapphire laser is used to detect various transient species in laser flash photolysis ...

  11. What Caused the Lead burn-out in Spectrometer Magnet 2B

    E-Print Network [OSTI]

    Green, Michael A

    2011-01-01T23:59:59.000Z

    MICE Note 324 What Caused the Lead burn-out in SpectrometerThe magnet failed because a lead to coil M2 failed before itof the magnet when the lead failure occurred. The lead that

  12. Flat Quartz-Crystal X-ray Spectrometer for Nuclear Forensics Applications

    E-Print Network [OSTI]

    Goodsell, Alison

    2012-10-19T23:59:59.000Z

    structure. The higher energy background radiation was blocked from reaching the detector using a customized collimator and shielding system. A flat quartz-crystal x-ray spectrometer system was designed specifically to fit the constraints and requirements...

  13. Calibration of a gated flat field spectrometer as a function of x-ray intensity

    SciTech Connect (OSTI)

    Xiong, Gang; Yang, Guohong; Li, Hang; Zhang, Jiyan, E-mail: zhangjiyanzjy@sina.com; Zhao, Yang; Hu, Zhimin; Wei, Minxi; Qing, Bo; Yang, Jiamin; Liu, Shenye; Jiang, Shaoen [Research Center of Laser Fusion, China Academy of Engineering Physics, P. O. Box 919-986, Mianyang 621900 (China)] [Research Center of Laser Fusion, China Academy of Engineering Physics, P. O. Box 919-986, Mianyang 621900 (China)

    2014-04-15T23:59:59.000Z

    We present an experimental determination of the response of a gated flat-field spectrometer at the Shenguang-II laser facility. X-rays were emitted from a target that was heated by laser beams and then were divided into different intensities with a step aluminum filter and collected by a spectrometer. The transmission of the filter was calibrated using the Beijing Synchrotron Radiation Facility. The response characteristics of the spectrometer were determined by comparing the counts recorded by the spectrometer with the relative intensities of the x-rays transmitted through the step aluminum filter. The response characteristics were used to correct the transmission from two shots of an opacity experiment using the same samples. The transmissions from the two shots are consistent with corrections, but discrepant without corrections.

  14. Superconducting gamma and fast-neutron spectrometers with high energy resolution

    DOE Patents [OSTI]

    Friedrich, Stephan (San Jose, CA); , Niedermayr, Thomas R. (Oakland, CA); Labov, Simon E. (Berkeley, CA)

    2008-11-04T23:59:59.000Z

    Superconducting Gamma-ray and fast-neutron spectrometers with very high energy resolution operated at very low temperatures are provided. The sensor consists of a bulk absorber and a superconducting thermometer weakly coupled to a cold reservoir, and determines the energy of the incident particle from the rise in temperature upon absorption. A superconducting film operated at the transition between its superconducting and its normal state is used as the thermometer, and sensor operation at reservoir temperatures around 0.1 K reduces thermal fluctuations and thus enables very high energy resolution. Depending on the choice of absorber material, the spectrometer can be configured either as a Gamma-spectrometer or as a fast-neutron spectrometer.

  15. Progress on the Modeling and Modification of the MICE Superconducting Spectrometer Solenoids

    E-Print Network [OSTI]

    Virostek, S.P.

    2013-01-01T23:59:59.000Z

    updated calculations confirmed the measured heat load of ~6of these calculations was the direct heat load into the coldcalculations was carried out in order to characterize the spectrometer solenoid heat loads

  16. Characterization of AP-MALDI and ESI for a differential mobility spectrometer

    E-Print Network [OSTI]

    Agrawal, Priya

    2005-01-01T23:59:59.000Z

    The following thesis entails the construction, testing, modification, and analysis of two systems that couple sample ion introduction methods with a Differential Mobility Spectrometer (DMS). The sample ionization methods ...

  17. Estimation Pression-Temprature de la transition Chrysotile-Lizardite/Antigorite et volutions gochimiques associes: exemple des serpentinites HP des Alpes Occidentales

    E-Print Network [OSTI]

    Nicollet, Christian

    ablation laser (LA-HR-ICP-MS) des différents polymorphes de serpentines indique des enrichissements en

  18. The new very small angle neutron scattering spectrometer at Laboratoire Leon Brillouin

    E-Print Network [OSTI]

    Sylvain Desert; Vincent Thevenot; Julian Oberdisse; Annie Brulet

    2007-06-12T23:59:59.000Z

    The design and characteristics of the new very small angle neutron scattering spectrometer under construction at the Laboratoire Leon Brillouin is described. Its goal is to extend the range of scattering vectors magnitudes towards 2x10{-4} /A. The unique feature of this new spectrometer is a high resolution two dimensional image plate detector sensitive to neutrons. The wavelength selection is achieved by a double reflection supermirror monochromator and the collimator uses a novel multibeam design.

  19. Atomic data for the ITER Core Imaging X-ray Spectrometer

    SciTech Connect (OSTI)

    Clementson, J; Beiersdorfer, P; Biedermann, C; Bitter, M; Delgado-Aparicio, L F; Graf, A; Gu, M F; Hill, K W; Barnsley, R

    2012-06-15T23:59:59.000Z

    The parameters of the ITER core plasmas will be measured using the Core Imaging X-ray Spectrometer (CIXS), a high-resolution crystal spectrometer focusing on the L-shell spectra of highly ionized tungsten atoms. In order to correctly infer the plasma properties accurate atomic data are required. Here, some aspects of the underlying physics are discussed using experimental data and theoretical predictions from modeling.

  20. Upgrade of the PNNL TEPC and Multisphere Spectrometer

    SciTech Connect (OSTI)

    Scherpelz, Robert I.; Conrady, Matthew M.

    2008-09-10T23:59:59.000Z

    The Pacific Northwest National Laboratory (PNNL) has used two types of instruments, the tissue equivalent proportional counter (TEPC) and the multisphere spectrometer for characterizing neutron radiation fields in support of neutron dosimetry at the Hanford site. The US Department of Energy recently issued new requirements for radiation protection standards in 10 CFR 835 which affect the way that neutron dose equivalent rates are evaluated. In response to the new requirements, PNNL has upgraded the analyses used in conjunction with the TEPC and multisphere. The analysis software for the TEPC was modified for this effort, and a new analysis code was selected for the multisphere. These new analysis techniques were implemented and tested with measurement data that had been collected in previous measurements. In order to test the effectiveness of the changes, measurements were taken in PNNL’s Low Scatter Room using 252Cf sources in both unmoderated and D2O-moderated configurations that generate well-characterized neutron fields. The instruments were also used at Los Alamos National Laboratory (LANL), in their Neutron Free-in-Air calibration room, also using neutron sources that generate well-characterized neutron fields. The results of the software modifications and the measurements are documented in this report. The TEPC measurements performed at PNNL agreed well with accepted dose equivalent rates using the traditional analysis, agreeing with the accepted value to within 13% for both unmoderated and moderated 252Cf sources. When the new analysis was applied to the TEPC measurement data, the results were high compared to the new accepted value. A similar pattern was seen for TEPC measurements at LANL. Using the traditional analysis method, results for all neutron sources showed good agreement with accepted values, nearly always less than 10%. For the new method of analysis, however, the TEPC responded with higher dose equivalent rates than accepted, by as much as 25%. The reason for the overresponse is that there is very little attenuation of the neutrons by tissue, so it cannot match the effect of attenuation by 1 cm of tissue called for in the new standards. This could be corrected with a modified instrument with a thicker wall, or by analytical means that would need to be developed. The multisphere spectrometer performed reasonably well both at PNNL and at LANL. It could produce a neutron spectrum that was similar to the accepted spectrum, and total flux values were usually within 15% of the accepted values. Dose equivalent rates were usually within 18% of the accepted values. The average energies, however, were usually lower than the accepted values. The performance of this instrument could be much better than seen in this study. If PNNL were to add some moderating spheres to its measurement set and calculate a new set of instrument response functions, performance could be improved. The multisphere could then be a more useful instrument for assessing the dose equivalent rate in the workplace.

  1. Data for Users of Handheld Ion Mobility Spectrometers

    SciTech Connect (OSTI)

    Keith A. Daum; Sandra L. Fox

    2008-05-01T23:59:59.000Z

    Chemical detection technology end-user surveys conducted by Idaho National Laboratory (INL) in 2005 and 2007 indicated that first responders believed manufacturers’ claims for instruments sometimes were not supported in field applications, and instruments sometimes did not meet their actual needs. Based on these findings, the Department of Homeland Security (DHS) asked INL to conduct a similar survey for handheld ion mobility spectrometers (IMS), which are used by a broad community of first responders as well as for other applications. To better access this broad community, the INL used the Center for Technology Commercialization, Inc. (CTC), Public Safety Technology Center (PSTC) to set up an online framework to gather information from users of handheld IMS units. This framework (Survey Monkey) was then used to perform an online Internet survey, augmented by e-mail prompts, to get information from first responders and personnel from various agencies about their direct experience with handheld IMS units. Overall, 478 individuals responded to the survey. Of these, 174 respondents actually owned a handheld IMS. Performance and satisfaction data from these 174 respondents are captured in this report. The survey identified the following observations: • The most common IMS unit used by respondents was the Advanced Portable Detector (APD 2000), followed by ChemRae, Sabre 4000, Sabre 2000, Draeger Multi IMS, Chemical Agent Monitor-2, Chemical Agent Monitor, Vapor Tracer, and Vapor Tracer 2. • The primary owners were HazMat teams (20%), fire services (14%), local police (12%), and sheriffs’ departments (9%). • IMS units are seldom used as part of an integrated system for detecting and identifying chemicals but instead are used independently. • Respondents are generally confused about the capabilities of their IMS unit. This is probably a result of lack of training. • Respondents who had no training or fewer than 8 hours were not satisfied with the overall operation of the handheld IMS unit. • IMS units were used for detecting a range of analytes. The most common use was for detection of hazardous chemicals, followed by detection of explosives, illicit drugs, chemical warfare, nerve agents, and radiation. One IMS unit had dual capability as a radiation detector. • Respondents who did not own an IMS listed prohibitive cost of equipment as the main factor for not having one. • Respondents who were highly satisfied with the overall operation of the handheld IMS obtained the IMS through a direct purchase. In comparison, the respondents who were not satisfied had obtained the handheld IMS through a DHS grant.

  2. Analysis on the Go: Quantitation of Drugs of Abuse in Dried Urine with Digital Microfluidics and Miniature Mass Spectrometry

    E-Print Network [OSTI]

    Zandstra, Peter W.

    Analysis on the Go: Quantitation of Drugs of Abuse in Dried Urine with Digital Microfluidics the development of a method coupling microfluidics and a miniature mass spectrometer, applied to quantitation of drugs of abuse in urine. A custom digital microfluidic system was designed to deliver droplets

  3. Neutrino mass matrix

    SciTech Connect (OSTI)

    Strobel, E.L.

    1985-01-01T23:59:59.000Z

    Given the many conflicting experimental results, examination is made of the neutrino mass matrix in order to determine possible masses and mixings. It is assumed that the Dirac mass matrix for the electron, muon, and tau neutrinos is similar in form to those of the quarks and charged leptons, and that the smallness of the observed neutrino masses results from the Gell-Mann-Ramond-Slansky mechanism. Analysis of masses and mixings for the neutrinos is performed using general structures for the Majorana mass matrix. It is shown that if certain tentative experimental results concerning the neutrino masses and mixing angles are confirmed, significant limitations may be placed on the Majorana mass matrix. The most satisfactory simple assumption concerning the Majorana mass matrix is that it is approximately proportional to the Dirac mass matrix. A very recent experimental neutrino mass result and its implications are discussed. Some general properties of matrices with structure similar to the Dirac mass matrices are discussed.

  4. Effective Mass and Energy-Mass Relationship

    E-Print Network [OSTI]

    Viktor Ariel

    2012-05-14T23:59:59.000Z

    The particle effective mass is often a challenging concept in solid state physics due to the many different definitions of the effective mass that are routinely used. Also, the most commonly used theoretical definition of the effective mass was derived from the assumption of a parabolic energy-momentum relationship, E(p), and therefore should not be applied to non-parabolic materials. In this paper, we use wave-particle duality to derive a definition of the effective mass and the energy-mass approximation suitable for non-parabolic materials. The new energy-mass relationship can be considered a generalization of Einstein's E=mc^2 suitable for arbitrary E(p) and therefore applicable to solid state materials and devices. We show that the resulting definition of the effective mass seems suitable for non-paraboic solid state materials such as HgCdTe, GaAs, and graphene.

  5. A solenoidal electron spectrometer for a precision measurement of the neutron $\\beta$-asymmetry with ultracold neutrons

    E-Print Network [OSTI]

    Plaster, B; Filippone, B W; Harrison, D; Hsiao, J; Ito, T M; Liu, J; Martin, J W; Tipton, B; Yuan, J

    2008-01-01T23:59:59.000Z

    We describe an electron spectrometer designed for a precision measurement of the neutron $\\beta$-asymmetry with spin-polarized ultracold neutrons. The spectrometer consists of a 1.0-Tesla solenoidal field with two identical multiwire proportional chamber and plastic scintillator electron detector packages situated within 0.6-Tesla field-expansion regions. Select results from performance studies of the spectrometer with calibration sources are reported.

  6. A simplified spectrometer based on a fast digital oscilloscope for the measurement of high energy $?$-rays

    E-Print Network [OSTI]

    S. S. Markochev; N. V. Eremin

    2014-05-28T23:59:59.000Z

    A simplified digital spectrometer for the study of $\\gamma$-rays with energies up to $\\sim100$ MeV is presented and tested. The spectrometer is only consisted of a fast digital oscilloscope and three scintillation detectors which can work in single or in coincidence modes: two BGO-detectors comprising $\\varnothing\\,7.62\\times7.62$ cm BGO-crystalls and one plastic detector which includes an organic polystyrene-based scintillator. The basic properties of the spectrometer (energy resolution, time resolution, $\\gamma$-rays detection efficiency) were studied exhaustively also using a Geant4-based Monte-Carlo simulation. Several numerical algorithms for processing of waveforms in offline mode were proposed and tested to perform digital timing, pulse area measurement and processing of pile-up events without rejection. As a result, the spectrometer demonstrated $\\sim10\\%$ better energy resolution than was obtained by a common 10-bit CAMAC ADC with the same detectors. And the developed algorithm based on the pulse shape analysis for processing of pile-up events showed high efficiency under severe conditions (the portion of pile-ups contained $\\sim30\\%$). The measured maximum counting rate of the spectrometer was $1.8\\times10^5$ waveforms/sec.

  7. Apparatus for preparing a sample for mass spectrometry

    DOE Patents [OSTI]

    Villa-Aleman, Eliel (Aiken, SC)

    1994-01-01T23:59:59.000Z

    An apparatus for preparing a sample for analysis by a mass spectrometer system. The apparatus has an entry chamber and an ionization chamber separated by a skimmer. A capacitor having two space-apart electrodes followed by one or more ion-imaging lenses is disposed in the ionization chamber. The chamber is evacuated and the capacitor is charged. A valve injects a sample gas in the form of sample pulses into the entry chamber. The pulse is collimated by the skimmer and enters the ionization chamber. When the sample pulse passes through the gap between the electrodes, it discharges the capacitor and is thereby ionized. The ions are focused by the imaging lenses and enter the mass analyzer, where their mass and charge are analyzed.

  8. Apparatus for preparing a sample for mass spectrometry

    DOE Patents [OSTI]

    Villa-Aleman, E.

    1994-05-10T23:59:59.000Z

    An apparatus is described for preparing a sample for analysis by a mass spectrometer system. The apparatus has an entry chamber and an ionization chamber separated by a skimmer. A capacitor having two space-apart electrodes followed by one or more ion-imaging lenses is disposed in the ionization chamber. The chamber is evacuated and the capacitor is charged. A valve injects a sample gas in the form of sample pulses into the entry chamber. The pulse is collimated by the skimmer and enters the ionization chamber. When the sample pulse passes through the gap between the electrodes, it discharges the capacitor and is thereby ionized. The ions are focused by the imaging lenses and enter the mass analyzer, where their mass and charge are analyzed. 1 figures.

  9. Application of the BINS superheated drop detector spectrometer to the {sup 9}Be(p,xn) neutron energy spectrum determination

    SciTech Connect (OSTI)

    Di Fulvio, A.; Ciolini, R.; Mirzajani, N.; Romei, C.; D'Errico, F. [Dipartimento di Ingegneria Meccanica, Nucleare e della Produzione, Universita di Pisa, Pisa (Italy); Bedogni, R. [INFN, Laboratori Nazionali di Frascati, Frascati (Roma) (Italy); Esposito, J.; Zafiropoulos, D.; Colautti, P. [INFN, Laboratori Nazionali di Legnaro, Legnaro (Padova) (Italy)

    2013-07-18T23:59:59.000Z

    In the framework of TRASCO-BNCT project, a Bubble Interactive Neutron Spectrometer (BINS) device was applied to the characterization of the angle-and energy-differential neutron spectra generated by the {sup 9}Be(p,xn)reaction. The BINS spectrometer uses two superheated emulsion detectors, sequentially operated at different temperatures and thus provides a series of six sharp threshold responses, covering the 0.1-10 MeV neutron energy range. Spectrum unfolding of the data was performed by means of MAXED code. The obtained angle, energy-differential spectra were compared with those measured with a Bonner sphere spectrometer, a silicon telescope spectrometer and literature data.

  10. Comparison of improved Aura Tropospheric Emission Spectrometer (TES) CO2 with HIPPO and SGP aircraft profile measurements

    E-Print Network [OSTI]

    Kulawik, S.S.

    2013-01-01T23:59:59.000Z

    Spectrometer stare ozone profiles with ARC-IONS sondespriori of trace gas profile estimates from the TroposphericHIPPO and SGP aircraft profile measurements S. S. Kulawik ,

  11. Chemical Ionization Mass Spectrometer (CIMS) Shanhu Lee, Kent State University (http://www.personal.kent.edu/~slee19/)

    E-Print Network [OSTI]

    Lee, Shan-Hu

    . For example, SF6 - ion reagent is used to detect H2SO4: SF6 - + H2SO4 H2SO4F- + SF5 Because H2SO4F-518, 2003. Huey, G. L., D. R. Hanson, and C. J. Howard, Reactions of SF6 - and I- with atmospheric trace

  12. Standard Test Method for Isotopic Analysis of Uranium Hexafluoride by Single-Standard Gas Source Multiple Collector Mass Spectrometer Method

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2011-01-01T23:59:59.000Z

    1.1 This test method is applicable to the isotopic analysis of uranium hexafluoride (UF6) with 235U concentrations less than or equal to 5 % and 234U, 236U concentrations of 0.0002 to 0.1 %. 1.2 This test method may be applicable to the analysis of the entire range of 235U isotopic compositions providing that adequate Certified Reference Materials (CRMs or traceable standards) are available. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety health practices and determine the applicability of regulatory limitations prior to use.

  13. Development of a variable-temperature ion mobility/ time-of-flight mass spectrometer for separation of electronic isomers

    E-Print Network [OSTI]

    Verbeck, Guido Fridolin

    2005-08-29T23:59:59.000Z

    potentials to produce the periodic field.50 In 1964, Szilagyi of the Research Institute for Technical Physics of the Hungarian Academy of Sciences developed the mathematical treatment for a periodic electrostatic lens using a series of concentric...

  14. Hydrophobic Proteome Analysis of Triple Negative and Hormone-Receptor-Positive-Her2-Negative Breast Cancer by Mass Spectrometer

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    solvents: 1. Water/acetonitrile/isopropanol/TFA by vol. )2. Water/acetonitrile/isopropanol/TFA by vol. )3. Water/acetonitrile/isopropanol/TFA by vol. ) 4. Water/

  15. Plume collimation for laser ablation electrospray ionization mass spectrometry

    DOE Patents [OSTI]

    Vertes, Akos; Stolee, Jessica A.

    2014-09-09T23:59:59.000Z

    In various embodiments, a device may generally comprise a capillary having a first end and a second end; a laser to emit energy at a sample in the capillary to ablate the sample and generate an ablation plume in the capillary; an electrospray apparatus to generate an electrospray plume to intercept the ablation plume to produce ions; and a mass spectrometer having an ion transfer inlet to capture the ions. The ablation plume may comprise a collimated ablation plume. The device may comprise a flow cytometer. Methods of making and using the same are also described.

  16. Quantum states of neutrons in the gravitational and centrifugal potentials in a new GRANIT spectrometer

    ScienceCinema (OSTI)

    None

    2011-10-06T23:59:59.000Z

    We will discuss the scientific program to be studied in a new gravitational spectrometer GRANIT in a broad context of quantum states (quantum behaviour) of ultracold neutrons (UCN) in gravitational [1] and centrifugal [2] potentials, as well as applications of these phenomena/spectrometer to various domains of physics, ranging from studies of fundamental short-range interactions and symmetries to neutron quantum optics and reflectometry using UCN. All these topics, as well as related instrumental and methodical developments have been discussed during dedicated GRANIT-2010 Workshop [3]. The GRANIT spectrometer has been recently installed at the Institut Laue-Langevin, Grenoble, France [4] and could become operational in near future. 1. V.V. Nesvizhevsky et al (2002), Nature 415, 297. 2. V.V. Nesvizhevsky et al (2010), Nature Physics 6, 114. 3. GRANIT-2010, Les Houches, 14-19 february 2010. 4. M. Kreuz et al (2009), NIM 611, 326.

  17. A compact neutron spectrometer for characterizing inertial confinement fusion implosions at OMEGA and the NIF

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zylstra, A. B.; Gatu Johnson, M.; Frenje, J. A.; Seguin, F. H.; Rinderknecht, H. G.; Rosenberg, M. J.; Sio, H. W.; Li, C. K.; Petrasso, R. D.; McCluskey, M.; et al

    2014-06-01T23:59:59.000Z

    A compact spectrometer for measurements of the primary deuterium-tritium neutron spectrum has been designed and implemented on the OMEGA laser facility [T. Boehly et al. , Opt. Commun.133, 495 (1997)]. This instrument uses the recoil spectrometry technique, where neutrons produced in an implosion elastically scatter protons in a plastic foil, which are subsequently detected by a proton spectrometer. This diagnostic is currently capable of measuring the yield to ~±10% accuracy, and mean neutron energy to ~±50 keV precision. As these compact spectrometers can be readily placed at several locations around an implosion, effects of residual fuel bulk flows during burnmore »can be measured. Future improvements to reduce the neutron energy uncertainty to ±15-20 keV are discussed, which will enable measurements of fuel velocities to an accuracy of ~±25-40 km/s.« less

  18. A compact neutron spectrometer for characterizing inertial confinement fusion implosions at OMEGA and the NIF

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zylstra, A. B.; Gatu Johnson, M.; Frenje, J. A.; Seguin, F. H.; Rinderknecht, H. G.; Rosenberg, M. J.; Sio, H. W.; Li, C. K.; Petrasso, R. D.; McCluskey, M.; Mastrosimone, D.; Glebov, V. Yu.; Forrest, C.; Stoeckl, C.; Sangster, T. C.

    2014-06-01T23:59:59.000Z

    A compact spectrometer for measurements of the primary deuterium-tritium neutron spectrum has been designed and implemented on the OMEGA laser facility [T. Boehly et al. , Opt. Commun.133, 495 (1997)]. This instrument uses the recoil spectrometry technique, where neutrons produced in an implosion elastically scatter protons in a plastic foil, which are subsequently detected by a proton spectrometer. This diagnostic is currently capable of measuring the yield to ?±10% accuracy, and mean neutron energy to ?±50 keV precision. As these compact spectrometers can be readily placed at several locations around an implosion, effects of residual fuel bulk flows during burn can be measured. Future improvements to reduce the neutron energy uncertainty to ±15?20 keV are discussed, which will enable measurements of fuel velocities to an accuracy of ?±25?40 km/s.

  19. Characterization of a new modular decay total absorption gamma-ray spectrometer (DTAS) for FAIR

    SciTech Connect (OSTI)

    Montaner Piza, A.; Tain, J. L.; Agramunt, J.; Algora, A.; Guadilla, V.; Marin, E.; Rice, S.; Rubio, B. [Instituto de Fisica Corpuscular, CSIC-Univ. de Valencia, Apdo. Correos 22085, E-46071 Valencia (Spain)

    2013-06-10T23:59:59.000Z

    Beta-decay studies are one of the main goals of the DEcay SPECtroscopy experiment (DESPEC) to be installed at the future Facility for Antiproton and Ion Research (FAIR). DESPEC aims at the study of nuclear structure of exotic nuclei. A new modular Decay Total Absorption gamma-ray Spectrometer (DTAS) is being built at IFIC and is specially adapted to studies at fragmentation facilities such as the Super Fragment Separator (Super-FRS) at FAIR. The designed spectrometer is composed of 16 identical NaI(Tl) scintillation crystals. This work focuses on the characterization of these independent modules, as an initial step for the characterization of the full spectrometer. Monte Carlo simulations have been performed in order to understand the detector response.

  20. A compact neutron spectrometer for characterizing inertial confinement fusion implosions at OMEGA and the NIF

    SciTech Connect (OSTI)

    Zylstra, A. B., E-mail: zylstra@mit.edu; Gatu Johnson, M.; Frenje, J. A.; Séguin, F. H.; Rinderknecht, H. G.; Rosenberg, M. J.; Sio, H. W.; Li, C. K.; Petrasso, R. D. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); McCluskey, M.; Mastrosimone, D.; Glebov, V. Yu.; Forrest, C.; Stoeckl, C.; Sangster, T. C. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States)

    2014-06-15T23:59:59.000Z

    A compact spectrometer for measurements of the primary deuterium-tritium neutron spectrum has been designed and implemented on the OMEGA laser facility [T. Boehly et al., Opt. Commun. 133, 495 (1997)]. This instrument uses the recoil spectrometry technique, where neutrons produced in an implosion elastically scatter protons in a plastic foil, which are subsequently detected by a proton spectrometer. This diagnostic is currently capable of measuring the yield to ?±10% accuracy, and mean neutron energy to ?±50 keV precision. As these compact spectrometers can be readily placed at several locations around an implosion, effects of residual fuel bulk flows during burn can be measured. Future improvements to reduce the neutron energy uncertainty to ±15?20 keV are discussed, which will enable measurements of fuel velocities to an accuracy of ?±25?40 km/s.

  1. A firmware-defined digital direct-sampling NMR spectrometer for condensed matter physics

    SciTech Connect (OSTI)

    Pikulski, M., E-mail: marekp@ethz.ch; Shiroka, T.; Ott, H.-R.; Mesot, J. [Laboratorium für Festkörperphysik, ETH Hönggerberg, CH-8093 Zürich, Switzerland and Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland)

    2014-09-15T23:59:59.000Z

    We report on the design and implementation of a new digital, broad-band nuclear magnetic resonance (NMR) spectrometer suitable for probing condensed matter. The spectrometer uses direct sampling in both transmission and reception. It relies on a single, commercially-available signal processing device with a user-accessible field-programmable gate array (FPGA). Its functions are defined exclusively by the FPGA firmware and the application software. Besides allowing for fast replication, flexibility, and extensibility, our software-based solution preserves the option to reuse the components for other projects. The device operates up to 400?MHz without, and up to 800?MHz with undersampling, respectively. Digital down-conversion with ±10?MHz passband is provided on the receiver side. The system supports high repetition rates and has virtually no intrinsic dead time. We describe briefly how the spectrometer integrates into the experimental setup and present test data which demonstrates that its performance is competitive with that of conventional designs.

  2. Laser sampling system for an inductively-coupled atomic emission spectrometer. Final report

    SciTech Connect (OSTI)

    NONE

    1998-02-15T23:59:59.000Z

    A laser sampling system was attached to a Perkin Elmer Optima 3000 inductively-coupled plasma, atomic emission spectrometer that was already installed and operating in the Chemistry and Geochemistry Department at the Colorado School of Mines. The use of the spectrometer has been highly successful. Graduate students and faculty from at least four different departments across the CSM campus have used the instrument. The final report to NSF is appended to this final report. Appendices are included which summarize several projects utilizing this instrument: acquisition of an inductively-coupled plasma atomic emission spectrometer for the geochemistry program; hydrogen damage susceptibility assessment for high strength steel weldments through advanced hydrogen content analysis, 1996 and 1997 annual reports; and methods for determination of hydrogen distribution in high strength steel welds.

  3. A compact neutron spectrometer for characterizing inertial confinement fusion implosions at OMEGA and the NIF

    SciTech Connect (OSTI)

    Zylstra, A. B.; Gatu Johnson, M.; Frenje, J. A.; Seguin, F. H.; Rinderknecht, H. G.; Rosenberg, M. J.; Sio, H. W.; Li, C. K.; Petrasso, R. D.; McCluskey, M.; Mastrosimone, D.; Glebov, V. Yu.; Forrest, C.; Stoeckl, C.; Sangster, T. C.

    2014-06-01T23:59:59.000Z

    A compact spectrometer for measurements of the primary deuterium-tritium neutron spectrum has been designed and implemented on the OMEGA laser facility [T. Boehly et al. , Opt. Commun.133, 495 (1997)]. This instrument uses the recoil spectrometry technique, where neutrons produced in an implosion elastically scatter protons in a plastic foil, which are subsequently detected by a proton spectrometer. This diagnostic is currently capable of measuring the yield to ~±10% accuracy, and mean neutron energy to ~±50 keV precision. As these compact spectrometers can be readily placed at several locations around an implosion, effects of residual fuel bulk flows during burn can be measured. Future improvements to reduce the neutron energy uncertainty to ±15-20 keV are discussed, which will enable measurements of fuel velocities to an accuracy of ~±25-40 km/s.

  4. Mass spectrometric immunoassay

    DOE Patents [OSTI]

    Nelson, Randall W; Williams, Peter; Krone, Jennifer Reeve

    2013-07-16T23:59:59.000Z

    Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

  5. Mass spectrometric immunoassay

    DOE Patents [OSTI]

    Nelson, Randall W (Phoenix, AZ); Williams, Peter (Phoenix, AZ); Krone, Jennifer Reeve (Granbury, TX)

    2007-12-04T23:59:59.000Z

    Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

  6. Electron pair emission detected by time-of-flight spectrometers: Recent progress

    SciTech Connect (OSTI)

    Huth, Michael; Schumann, Frank O. [Max Planck Institute of Microstructure Physics, Weinberg 2, D-06120 Halle (Germany); Chiang, Cheng-Tien; Trützschler, Andreas; Kirschner, Jürgen [Max Planck Institute of Microstructure Physics, Weinberg 2, D-06120 Halle (Germany); Institute of Physics, Martin-Luther-Universität Halle-Wittenberg, Von-Danckelmann-Platz 3, D-06120 Halle (Saale) (Germany); Widdra, Wolf [Institute of Physics, Martin-Luther-Universität Halle-Wittenberg, Von-Danckelmann-Platz 3, D-06120 Halle (Saale) (Germany); Max Planck Institute of Microstructure Physics, Weinberg 2, D-06120 Halle (Germany)

    2014-02-10T23:59:59.000Z

    We present results for electron coincidence spectroscopy using two time-of-flight (ToF) spectrometers. Excited by electron impact, the energy and momentum distribution of electron pairs emitted from the Cu(111) surface are resolved and a spectral feature related to the Shockley surface state is identified. By combining the two ToF spectrometers with a high-order harmonic generation light source, we demonstrate double photoemission spectroscopy in the laboratory that required synchrotron radiation in the past. Utilizing this setup, we report results for (?,2e) on NiO(001) on Ag(001) excited with light at 30?eV photon energy.

  7. Foil cycling technique for the VESUVIO spectrometer operating in the resonance detector configuration

    SciTech Connect (OSTI)

    Schooneveld, E. M.; Mayers, J.; Rhodes, N. J.; Pietropaolo, A.; Andreani, C.; Senesi, R.; Gorini, G.; Perelli-Cippo, E.; Tardocchi, M. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Consiglio Nazionale delle Ricerche-Istituto Nazionale per la Fisica della Materia, Universita degli Studi di Roma Tor Vergata, Via della Ricerca Scientifica 1, 00133 Rome (Italy); Dipartimento di Fisica, Universita degli Studi di Roma 'Tor Vergata', Via della Ricerca Scientifica 1, 00133 Rome (Italy); Dipartimento di Fisica 'G. Occhialini', Universita degli Studi di Milano Bicocca, Piazza della Scienza 2, I-20126 Milan (Italy) and CNR-INFM, Universita degli Studi di Milano Bicocca, Piazza della Scienza 2, I-20126 Milan (Italy)

    2006-09-15T23:59:59.000Z

    This article reports a novel experimental technique, namely, the foil cycling technique, developed on the VESUVIO spectrometer (ISIS spallation source) operating in the resonance detector configuration. It is shown that with a proper use of two foils of the same neutron absorbing material it is possible, in a double energy analysis process, to narrow the width of the instrumental resolution of a spectrometer operating in the resonance detector configuration and to achieve an effective subtraction of the neutron and gamma backgrounds. Preliminary experimental results, obtained from deep inelastic neutron scattering measurements on lead, zirconium hydride, and deuterium chloride samples, are presented.

  8. Next-Generation Germanium Spectrometer Background Reduction Techniques at 2 MeV

    SciTech Connect (OSTI)

    Brodzinski, Ronald L.

    2005-04-01T23:59:59.000Z

    The Majorana project, a next-generation 76Ge neutrinoless double-beta decay experiment being undertaken by a large international collaboration, has the goal of measuring the neutrinoless double-beta decay rate by observing monochromatic events at 2039 keV in 500 kg of isotopically enriched 76Ge gamma-ray spectrometers. In order to achieve the desired sensitivity limit, the background in the 2037-2041 keV region must be reduced to <1 event per year in the entire germanium array. The effects of various background reduction techniques, and the combination thereof, to produce a huge 76Ge spectrometer array with virtually zero background are discussed.

  9. Calibration of a Thomson parabola ion spectrometer and Fujifilm imaging plate detectors for protons, deuterons, and alpha particles

    SciTech Connect (OSTI)

    Freeman, C. G.; Canfield, M. J.; Graeper, G. B.; Lombardo, A. T.; Stillman, C. R.; Padalino, S. J. [Physics Department, SUNY Geneseo, Geneseo, New York 14454 (United States); Fiksel, G.; Stoeckl, C.; Mileham, C.; Sangster, T. C. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States); Sinenian, N.; Frenje, J. A. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

    2011-07-15T23:59:59.000Z

    A Thomson parabola ion spectrometer has been designed for use at the Multiterawatt (MTW) laser facility at the Laboratory for Laser Energetics (LLE) at University of Rochester. This device uses parallel electric and magnetic fields to deflect particles of a given mass-to-charge ratio onto parabolic curves on the detector plane. Once calibrated, the position of the ions on the detector plane can be used to determine the particle energy. The position dispersion of both the electric and magnetic fields of the Thomson parabola was measured using monoenergetic proton and alpha particle beams from the SUNY Geneseo 1.7 MV tandem Pelletron accelerator. The sensitivity of Fujifilm BAS-TR imaging plates, used as a detector in the Thomson parabola, was also measured as a function of the incident particle energy over the range from 0.6 MeV to 3.4 MeV for protons and deuterons and from 0.9 MeV to 5.4 MeV for alpha particles. The device was used to measure the energy spectrum of laser-produced protons at MTW.

  10. A method to measure the resonance transitions between the gravitationally bound quantum states of neutrons in the GRANIT spectrometer

    E-Print Network [OSTI]

    Meyerovich, Alex

    of neutrons in the GRANIT spectrometer M. Kreuz a , V.V. Nesvizhevsky a,Ã?, P. Schmidt-Wellenburg a , T bound quantum states of neutrons in the GRANIT spectrometer. The purpose of GRANIT is to improve quantum states, the transition probability will sharply increase. The GRANIT experiment is motivated

  11. Neutrino mass matrix

    SciTech Connect (OSTI)

    Capps, R.H.; Strobel, E.L.

    1985-07-01T23:59:59.000Z

    It is assumed that the Dirac mass matrix for the neutrinos (..nu../sub e/,..nu../sub ..mu../,..nu../sub tau/) is similar in form to those for the quarks and charged leptons, and that the smallness of the observed ..nu.. masses results from the Gell-Mann--Ramond--Slansky mechanism. It is shown that if certain tentative experimental results concerning the ..nu.. masses and mixing angles are confirmed, significant limitations may be placed on the Majorana mass matrix. The most satisfactory simple assumption concerning the Majorana mass matrix is that it is approximately proportional to the Dirac mass matrix. Some general properties of the Dirac matrices are discussed.

  12. An In-Situ Ion Mobility Spectrometer Sensor System for Detecting Gaseous VOCs in Unsaturated Soils

    E-Print Network [OSTI]

    Baker, R. Jacob

    An In-Situ Ion Mobility Spectrometer Sensor System for Detecting Gaseous VOCs in Unsaturated Soils and will be ultimately equipped with water content, temperature, and pressure sensors. The proposed system is designed knowledge, an in-situ IMS for detection of subsurface gaseous VOCs has not been previously developed. VOCs

  13. A personal computer-based nuclear magnetic resonance spectrometer Constantin Job

    E-Print Network [OSTI]

    Brown, Michael F.

    A personal computer-based nuclear magnetic resonance spectrometer Constantin Job Arizona Research of Arizona,, lkson, Arizona 85721 (Received 24 May 1994; accepted for publication 27 July 1994) Nuclear engineering, agriculture, geology, archaeology, and others have the possibility of utilizing magnetic

  14. Chemometric calibration of infrared spectrometers: selection and validation of variables by non-linear models

    E-Print Network [OSTI]

    Verleysen, Michel

    regression (PCR) and partial least squares regression (PLSR). Then, we will propose to incorporate non-linearChemometric calibration of infrared spectrometers: selection and validation of variables by non-linear (step by step) for the selection of spectral variables, using linear regression or neural networks

  15. Measurements with the high flux lead slowing-down spectrometer at LANL

    E-Print Network [OSTI]

    Danon, Yaron

    slow down by scattering interactions with the lead and thus enable measurements of neutron.40.Sc Keywords: Lead-slowing-down spectrometer; Lithium; Alpha; Cross section; Neutron reactions 1.elsevier.com/locate/nimb Nuclear Instruments and Methods in Physics Research B 261 (2007) 953­955 NIM BBeam Interactions

  16. The Pluto Energetic Particle Spectrometer Science Investigation (PEPSSI) on the New

    E-Print Network [OSTI]

    Stern, S. Alan

    The Pluto Energetic Particle Spectrometer Science Investigation (PEPSSI) on the New Horizons and ~2.5 W. Keywords: New Horizons, PEPSSI, Pluto, Energetic particle instrument #12;Abbreviations 1PPS of Colorado, Boulder, CO 80309, USA 6 443-778-5435, 443-778-0386, Ralph.mcnutt@jhuapl.edu The Pluto Energetic

  17. airborne gamma-ray spectrometer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gamma-ray spectrometer First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Digital Logarithmic Airborne...

  18. anti-compton gamma-ray spectrometer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    anti-compton gamma-ray spectrometer First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Monte Carlo...

  19. Results for the response function determination of the Compact Neutron Spectrometer

    E-Print Network [OSTI]

    F. Gagnon-Moisan; M. Reginatto; A. Zimbal

    2012-01-30T23:59:59.000Z

    The Compact Neutron Spectrometer (CNS) is a Joint European Torus (JET) Enhancement Project, designed for fusion diagnostics in different plasma scenarios. The CNS is based on a liquid scintillator (BC501A) which allows good discrimination between neutron and gamma radiation. Neutron spectrometry with a BC501A spectrometer requires the use of a reliable, fully characterized detector. The determination of the response matrix was carried out at the Ion Accelerator Facility (PIAF) of the Physikalisch-Technische Bundesanstalt (PTB). This facility provides several monoenergetic beams (2.5, 8, 10, 12 and 14 MeV) and a 'white field'(Emax ~17 MeV), which allows for a full characterization of the spectrometer in the region of interest (from ~1.5 MeV to ~17 MeV. The energy of the incoming neutrons was determined by the time of flight method (TOF), with time resolution in the order of 1 ns. To check the response matrix, the measured pulse height spectra were unfolded with the code MAXED and the resulting energy distributions were compared with those obtained from TOF. The CNS project required modification of the PTB BC501A spectrometer design, to replace an analog data acquisition system (NIM modules) with a digital system developed by the 'Ente per le Nuove tecnologie, l'Energia e l'Ambiente' (ENEA). Results for the new digital system were evaluated using new software developed specifically for this project.

  20. A high-resolution soft x-ray spectrometer on the MAST tokamak

    SciTech Connect (OSTI)

    Nelson, M.J.; Barnsley, R.; Keenan, F.; Meyer, H.; Bunting, C.A.; Carolan, P.G.; Conway, N.J.; Cunningham, G.; Lehane, I.; Tournianski, M.R. [Queens University, Belfast, N. Ireland BT7 1NN (United Kingdom); EURATOM/UKAEA Fusion Association, Culham Science Centre, Abingdon OX14 3DB (United Kingdom)

    2004-10-01T23:59:59.000Z

    A curved crystal spectrometer in Johann configuration has been implemented on MAST to obtain values for electron temperature, ion temperature and toroidal velocity. The spectrometer is used to examine medium Z impurities in the soft x-ray region by utilising a Silicon (111) crystal, bent using a 4 pin bending jig, and a CCD detector ({delta}t=8 ms). Helium-like Argon emissions from 3.94 to 4.00 A have been examined using a crystal radius of 859.77 mm. The Bragg angle and crystal radius can be adjusted with relative ease. The spectrometer can be scanned toroidally and poloidally to include a radial view which facilitates absolute velocity measurements by assuming radial velocity =0. Doppler shifts of 2.3x10{sup -5} A (1.8 kms{sup -1}) can be measured. The line of sight is shared with a neutral particle analyzer, which enables in situ ion temperature comparisons. Ray tracing has been used for the development of new imaging spectrometers, using spherical/toroidal crystals, planned to be implemented on MAST.

  1. absorption gamma-ray spectrometer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    absorption gamma-ray spectrometer First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Digital Logarithmic...

  2. FULL-SCALE TESTING OF A CAUSTIC SIDE SOLVENT EXTRACTION SYSTEM TO REMOVE CESIUM FROM SAVANNAH RIVER SITE RADIOACTIVE WASTE

    SciTech Connect (OSTI)

    Poirier, M; Thomas Peters, T; Earl Brass, E; Stanley Brown, S; Mark Geeting, M; Lcurtis Johnson, L; Charles02 Coleman, C; S Crump, S; Mark Barnes, M; Samuel Fink, S

    2007-10-15T23:59:59.000Z

    Savannah River Site (SRS) personnel have completed construction and assembly of the Modular Caustic Side Solvent Extraction Unit (MCU) facility. Following assembly, they conducted testing to evaluate the ability of the process to remove non-radioactive cesium and to separate the aqueous and organic phases. They conducted tests at salt solution flow rates of 3.5, 6.0, and 8.5 gpm. During testing, the MCU Facility collected samples and submitted them to Savannah River National Laboratory (SRNL) personnel for analysis of cesium, Isopar{reg_sign} L, and Modifier [1-(2,2,3,3-tetrafluoropropoxy)-3-(4-sec-butylphenoxy)-2-propanol]. SRNL personnel analyzed the aqueous samples for cesium by Inductively-Coupled Plasma Mass Spectroscopy (ICP-MS) and the solvent samples for cesium using a Parr Bomb Digestion followed by ICP-MS. They analyzed aqueous samples for Isopar{reg_sign} L and Modifier by gas chromatography (GC).

  3. Introduction to direct neutrino mass measurements and KATRIN

    E-Print Network [OSTI]

    Thomas Thümmler; for the KATRIN Collaboration

    2010-12-10T23:59:59.000Z

    The properties of neutrinos and especially their rest mass play an important role at the intersections of cosmology, particle physics and astroparticle physics. At present there are two complementary approaches to address this topic in laboratory experiments. The search for neutrinoless double beta decay probes whether neutrinos are Majorana particles and determines an effective neutrino mass value. On the other hand experiments such as MARE, KATRIN and the recently proposed Project 8 will investigate the spectral shape of beta-decay electrons close to their kinematic endpoint in order to determine the neutrino rest mass with a model-independent method. Here, because of neutrino flavour mixing, the neutrino mass appears as an average of all neutrino mass eigenstates contributing to the electron neutrino. The KArlsruhe TRItium Neutrino experiment (KATRIN) is currently the experiment in the most advanced status of commissioning. It combines an ultra-luminous molecular windowless gaseous tritium source with an integrating high-resolution spectrometer of MAC-E filter type. It will investigate the neutrino rest mass with 0.2 eV/c (90% C.L.) sensitivity and allow beta spectroscopy close to the tritium endpoint at 18.6 keV with unprecedented precision.

  4. Study of thermal neutron capture gamma rays using a lithium-drifted germanium spectrometer / [by] Victor John Orphan [and] Norman C. Rasmussen

    E-Print Network [OSTI]

    Orphan, V. J.

    1967-01-01T23:59:59.000Z

    A gamma-ray spectrometer, using a 30 cc coaxial Ge(Li) detector, which can be operated as a pair spectrometer at high energies and in the Compton suppression mode at low energies provides an effective means of obtaining ...

  5. Lead Slowing Down Spectrometer FY2013 Annual Report

    SciTech Connect (OSTI)

    Warren, Glen A.; Kulisek, Jonathan A.; Gavron, Victor A.; Danon, Yaron; Weltz, Adam; Harris, Jason; Stewart, T.

    2013-10-29T23:59:59.000Z

    Executive Summary The Lead Slowing Down Spectrometry (LSDS) project, funded by the Materials Protection And Control Technology campaign, has been evaluating the feasibility of using LSDS techniques to assay fissile isotopes in used nuclear fuel assemblies. The approach has the potential to provide considerable improvement in the assay of fissile isotopic masses in fuel assemblies compared to other non-destructive techniques in a direct and independent manner. This report is a high level summary of the progress completed in FY2013. This progress included: • Fabrication of a 4He scintillator detector to detect fast neutrons in the LSDS operating environment. Testing of the detector will be conducted in FY2014. • Design of a large area 232Th fission chamber. • Analysis using the Los Alamos National Laboratory perturbation model estimated the required number of neutrons for an LSDS measurement to be 10 to the 16th source neutrons. • Application of the algorithms developed at Pacific Northwest National Laboratory to LSDS measurement data of various fissile samples conducted in 2012. The results concluded that the 235U could be measured to 2.7% and the 239Pu could be measured to 6.3%. Significant effort is yet needed to demonstrate the applicability of these algorithms for used-fuel assemblies, but the results reported here are encouraging in demonstrating that we are making progress toward that goal. • Development and cost-analysis of a research plan for the next critical demonstration measurements. The plan suggests measurements on fresh fuel sub assemblies as a means to experimentally test self-attenuation and the use of fresh mixed-oxide fuel as a means to test simultaneous measurement of 235U and 239Pu.

  6. Elbow mass flow meter

    DOE Patents [OSTI]

    McFarland, Andrew R. (College Station, TX); Rodgers, John C. (Santa Fe, NM); Ortiz, Carlos A. (Bryan, TX); Nelson, David C. (Santa Fe, NM)

    1994-01-01T23:59:59.000Z

    Elbow mass flow meter. The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity.

  7. First Results from the CARIBU Facility: Mass Measurements on the r-Process Path

    E-Print Network [OSTI]

    J. Van Schelt; D. Lascar; G. Savard; J. A. Clark; P. F. Bertone; S. Caldwell; A. Chaudhuri; 1 A. F. Levand; G. Li; G. E. Morgan; R. Orford; R. E. Segel; K. S. Sharma; M. G. Sternberg

    2013-07-01T23:59:59.000Z

    The Canadian Penning Trap mass spectrometer has made mass measurements of 33 neutron-rich nuclides provided by the new Californium Rare Isotope Breeder Upgrade (CARIBU) facility at Argonne National Laboratory. The studied region includes the 132Sn double shell closure and ranges in Z from In to Cs, with Sn isotopes measured out to A = 135, and the typical measurement precision is at the 100 ppb level or better. The region encompasses a possible major waiting point of the astrophysical r process, and the impact of the masses on the r process is shown through a series of simulations. These first-ever simulations with direct mass information on this waiting point show significant increases in waiting time at Sn and Sb in comparison with commonly used mass models, demonstrating the inadequacy of existing models for accurate r-process calculations.

  8. New constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico brine pool via in situ mass spectrometry

    E-Print Network [OSTI]

    Girguis, Peter R.

    , likely exceeding reserves of conventional oil and gas (Collett and Kuuskraa, 1998). In deep-ocean regionsNew constraints on methane fluxes and rates of anaerobic methane oxidation in a Gulf of Mexico Keywords: Methane flux Mass spectrometer Brine pool Methane oxidation Gulf of Mexico a b s t r a c t Deep

  9. Aerosol Mass Spectrometry via Laser-Induced Incandescence Particle Vaporization Final Report

    SciTech Connect (OSTI)

    Timothy B. Onasch

    2011-10-20T23:59:59.000Z

    We have successfully developed and commercialized a soot particle aerosol mass spectrometer (SP-AMS) instrument to measure mass, size, and chemical information of soot particles in ambient environments. The SP-AMS instrument has been calibrated and extensively tested in the laboratory and during initial field studies. The first instrument paper describing the SP-AMS has been submitted for publication in a peer reviewed journal and there are several related papers covering initial field studies and laboratory studies that are in preparation. We have currently sold 5 SP-AMS instruments (either as complete systems or as SP modules to existing AMS instrument operators).

  10. HYSPEC : A CRYSTAL TIME OF FLIGHT HYBRID SPECTROMETER FOR THE SPALLATION NEUTRON SOURCE.

    SciTech Connect (OSTI)

    SHAPIRO,S.M.; ZALIZNYAK,I.A.

    2002-12-30T23:59:59.000Z

    This document lays out a proposal by the Instrument Development Team (IDT) composed of scientists from leading Universities and National Laboratories to design and build a conceptually new high-flux inelastic neutron spectrometer at the pulsed Spallation Neutron Source (SNS) at Oak Ridge. This instrument is intended to supply users of the SNS and scientific community, of which the IDT is an integral part, with a platform for ground-breaking investigations of the low-energy atomic-scale dynamical properties of crystalline solids. It is also planned that the proposed instrument will be equipped with a polarization analysis capability, therefore becoming the first polarized beam inelastic spectrometer in the SNS instrument suite, and the first successful polarized beam inelastic instrument at a pulsed spallation source worldwide. The proposed instrument is designed primarily for inelastic and elastic neutron spectroscopy of single crystals. In fact, the most informative neutron scattering studies of the dynamical properties of solids nearly always require single crystal samples, and they are almost invariably flux-limited. In addition, in measurements with polarization analysis the available flux is reduced through selection of the particular neutron polarization, which puts even more stringent limits on the feasibility of a particular experiment. To date, these investigations have mostly been carried out on crystal spectrometers at high-flux reactors, which usually employ focusing Bragg optics to concentrate the neutron beam on a typically small sample. Construction at Oak Ridge of the high-luminosity spallation neutron source, which will provide intense pulsed neutron beams with time-averaged fluxes equal to those at medium-flux reactors, opens entirely new opportunities for single crystal neutron spectroscopy. Drawing upon experience acquired during decades of studies with both crystal and time-of-flight (TOF) spectrometers, the IDT has developed a conceptual design for a focused-beam, hybrid time-of-flight instrument with a crystal monochromator for the SNS called HYSPEC (an acronym for hybrid spectrometer). The proposed instrument has a potential to collect data more than an order of magnitude faster than existing steady-source spectrometers over a wide range of energy transfer ({h_bar}{omega}) and momentum transfer (Q) space, and will transform the way that data in elastic and inelastic single-crystal spectroscopy are collected. HYSPEC is optimized to provide the highest neutron flux on sample in the thermal and epithermal neutron energy ranges at a good-to-moderate energy resolution. By providing a flux on sample several times higher than other inelastic instruments currently planned for the SNS, the proposed instrument will indeed allow unique ground-breaking measurements, and will ultimately make polarized beam studies at a pulsed spallation source a realistic possibility.

  11. Multinozzle Emitter Arrays for Nanoelectrospray Mass Spectrometry

    SciTech Connect (OSTI)

    Mao, Pan; Wang, Hung-Ta; Yang, Peidong; Wang, Daojing

    2011-06-16T23:59:59.000Z

    Mass spectrometry (MS) is the enabling technology for proteomics and metabolomics. However, dramatic improvements in both sensitivity and throughput are still required to achieve routine MS-based single cell proteomics and metabolomics. Here, we report the silicon-based monolithic multinozzle emitter array (MEA), and demonstrate its proof-of-principle applications in high-sensitivity and high-throughput nanoelectrospray mass spectrometry. Our MEA consists of 96 identical 10-nozzle emitters in a circular array on a 3-inch silicon chip. The geometry and configuration of the emitters, the dimension and number of the nozzles, and the micropillar arrays embedded in the main channel, can be systematically and precisely controlled during the microfabrication process. Combining electrostatic simulation and experimental testing, we demonstrated that sharpened-end geometry at the stem of the individual multinozzle emitter significantly enhanced the electric fields at its protruding nozzle tips, enabling sequential nanoelectrospray for the high-density emitter array. We showed that electrospray current of the multinozzle emitter at a given total flow rate was approximately proportional to the square root of the number of its spraying-nozzles, suggesting the capability of high MS sensitivity for multinozzle emitters. Using a conventional Z-spray mass spectrometer, we demonstrated reproducible MS detection of peptides and proteins for serial MEA emitters, achieving sensitivity and stability comparable to the commercial capillary emitters. Our robust silicon-based MEA chip opens up the possibility of a fully-integrated microfluidic system for ultrahigh-sensitivity and ultrahigh-throughput proteomics and metabolomics.

  12. A Compact, Backscattering Deplolarization Cloud Spectrometer for Ice and Water Discrimination

    SciTech Connect (OSTI)

    Thomson, David

    2014-05-15T23:59:59.000Z

    This project was to develop a compact optical particle spectrometer, small enough for operation on UAVS, that measures the optical diameter of cloud hydrometeors and differentiates their water phase (liquid or solid). To reach this goal, a work plan was laid out that would complete three objectives: 1) Evaluation of designs for an optical particle spectrometer that measures the component of light backscattered at two polarization angles. 2) Testing of selected designs on an optical bench. 3) Construction and preliminary testing of a prototype instrument based on the selected, optimum design. A protoype instrument was developed and tested in an icing wind tunnel where the results showed good measurement of cloud droplets and ice particles.

  13. A method for Removing Surface Contamination on Ultra-pure Copper Spectrometer Components

    SciTech Connect (OSTI)

    Hoppe, Eric W.; Seifert, Allen; Aalseth, Craig E.; Day, Anthony R.; Farmer, Orville T.; Hossbach, Todd W.; McIntyre, Justin I.; Miley, Harry S.; Smart, John E.; Warren, Glen A.

    2008-06-15T23:59:59.000Z

    Spectrometers for the lowest-level radiometric measurements require materials of extreme radiopurity. Measurements of rare nuclear decays, e.g. neutrinoless double-beta decay, can require construction and shielding materials with bulk radiopurity reaching one micro-Becquerel per kilogram or less. When such extreme material purity is achieved, surface contamination, particularly solid daughters in the natural radon decay chains, can become the limiting background. High-purity copper is an important material for ultra-low-background spectrometers and thus is the focus of this work. A method for removing surface contamination at very low levels without attacking the bulk material is described. An assay method using a low-background proportional counter made of the material under examination is employed, and the resulting preliminary result of achievable surface contamination levels is presented.

  14. The gamma-ray spectrometer HORUS and its applications for nuclear astrophysics

    E-Print Network [OSTI]

    L. Netterdon; V. Derya; J. Endres; C. Fransen; A. Hennig; J. Mayer; C. Müller-Gatermann; A. Sauerwein; P. Scholz; M. Spieker; A. Zilges

    2014-05-12T23:59:59.000Z

    A dedicated setup for the in-beam measurement of absolute cross sections of astrophysically relevant charged-particle induced reactions is presented. These, usually very low, cross sections at energies of astrophysical interest are important to improve the modeling of the nucleosynthesis processes of heavy nuclei. Particular emphasis is put on the production of the $p$ nuclei during the astrophysical $\\gamma$ process. The recently developed setup utilizes the high-efficiency $\\gamma$-ray spectrometer HORUS, which is located at the 10 MV FN tandem ion accelerator of the Institute for Nuclear Physics in Cologne. The design of this setup will be presented and results of the recently measured $^{89}$Y(p,$\\gamma$)$^{90}$Zr reaction will be discussed. The excellent agreement with existing data shows, that the HORUS spectrometer is a powerful tool to determine total and partial cross sections using the in-beam method with high-purity germanium detectors.

  15. The new cold neutron chopper spectrometer at the Spallation Neutron Source: Design and performance

    SciTech Connect (OSTI)

    Ehlers, G.; Podlesnyak, A. A.; Niedziela, J. L.; Iverson, E. B. [Neutron Scattering Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Sokol, P. E. [Department of Physics, Indiana University, Bloomington, Indiana 47405 (United States)

    2011-08-15T23:59:59.000Z

    The design and performance of the new cold neutron chopper spectrometer (CNCS) at the Spallation Neutron Source in Oak Ridge are described. CNCS is a direct-geometry inelastic time-of-flight spectrometer, designed essentially to cover the same energy and momentum transfer ranges as IN5 at ILL, LET at ISIS, DCS at NIST, TOFTOF at FRM-II, AMATERAS at J-PARC, PHAROS at LANSCE, and NEAT at HZB, at similar energy resolution. Measured values of key figures such as neutron flux at sample position and energy resolution are compared between measurements and ray tracing Monte Carlo simulations, and good agreement (better than 20% of absolute numbers) has been achieved. The instrument performs very well in the cold and thermal neutron energy ranges, and promises to become a workhorse for the neutron scattering community for quasielastic and inelastic scattering experiments.

  16. The new Cold Neutron Chopper Spectrometer at the Spallation Neutron Source -- Design and Performance

    SciTech Connect (OSTI)

    Ehlers, Georg [ORNL; Podlesnyak, Andrey A [ORNL; Niedziela, Jennifer L [ORNL; Iverson, Erik B [ORNL; Sokol, Paul E [ORNL

    2011-01-01T23:59:59.000Z

    The design and performance of the new cold neutron chopper spectrometer (CNCS) at the Spallation Neutron Source in Oak Ridge are described. CNCS is a direct-geometry inelastic time-of-flight spectrometer, designed essentially to cover the same energy and momentum transfer ranges as IN5 at ILL, LET at ISIS, DCS at NIST, TOFTOF at FRM-II, AMATERAS at J-PARC, PHAROS at LANSCE, and NEAT at HZB, at similar energy resolution. Measured values of key figures such as neutron flux at sample position and energy resolution are compared between measurements and ray tracing Monte Carlo simulations, and good agreement (better than 20% of absolute numbers) has been achieved. The instrument performs very well in the cold and thermal neutron energy ranges, and promises to become a workhorse for the neutron scattering community for quasielastic and inelastic scattering experiments.

  17. Optimising a Muon Spectrometer for Measurements at the ISIS Pulsed Muon Source

    E-Print Network [OSTI]

    Giblin, S R; King, P J C; Tomlinson, S; Jago, S J S; Randall, L J; Roberts, M J; Norris, J; Howarth, S; Mutamba, Q B; Rhodes, N J; Akeroyd, F

    2014-01-01T23:59:59.000Z

    This work describes the development of a state-of-the-art muon spectrometer for the ISIS pulsed muon source. Conceived as a major upgrade of the highly successful EMU instrument, emphasis has been placed on making effective use of the enhanced flux now available at the ISIS source. This has been achieved both through the development of a highly segmented detector array and enhanced data acquisition electronics. The pulsed nature of the ISIS beam is particularly suited to the development of novel experiments involving external stimuli, and therefore the ability to sequence external equipment has been added to the acquisition system. Finally, the opportunity has also been taken to improve both the magnetic field and temperature range provided by the spectrometer, to better equip the instrument for running the future ISIS user programme.

  18. Spectrometer for Sky-Scanning Sun-Tracking Atmospheric Research (4STAR): Instrument Technology

    SciTech Connect (OSTI)

    Dunagan, Stephen; Johnson, Roy; Zavaleta, Jhony; Russell, P. B.; Schmid, Beat; Flynn, Connor J.; Redemann, Jens; Shinozuka, Yohei; Livingston, J.; Segal Rozenhaimer, Michal

    2013-08-06T23:59:59.000Z

    The Spectrometer for Sky-Scanning, Sun-Tracking Atmospheric Research (4STAR) combines airborne sun tracking and sky scanning with diffraction spectroscopy, to improve knowledge of atmospheric constituents and their links to air-pollution/climate. Direct beam hyper-spectral measurement of optical depth improves retrievals of gas constituents and determination of aerosol properties. Sky scanning enhances retrievals of aerosol type and size distribution. 4STAR measurements will tighten the closure between satellite and ground-based measurements. 4STAR incorporates a modular sun-tracking/ sky-scanning optical head with fiber optic signal transmission to rack mounted spectrometers, permitting miniaturization of the external optical head, and future detector evolution. Technical challenges include compact optical collector design, radiometric dynamic range and stability, and broad spectral coverage. Test results establishing the performance of the instrument against the full range of operational requirements are presented, along with calibration, engineering flight test, and scientific field campaign data and results.

  19. Spectrometer for X-ray emission experiments at FERMI free-electron-laser

    SciTech Connect (OSTI)

    Poletto, L., E-mail: poletto@dei.unipd.it; Frassetto, F.; Miotti, P. [CNR - Institute of Photonics and Nanotechnologies (CNR-IFN), via Trasea 7, I-35131 Padova (Italy); Di Cicco, A.; Iesari, F. [Physics Division, School of Science and Technology, Università di Camerino, I-62032 Camerino (Italy); Finetti, P. [ELETTRA - Sincrotrone Trieste, Basovizza Area Science Park, S. S. 14 - km 163,5, I-34149, Basovizza (TS) (Italy); Grazioli, C. [Department of Chemical and Pharmaceutical Sciences, University of Trieste, Via L. Giorgieri 1, I-34127 Trieste (Italy); CNR-Istituto Officina dei Materiali (CNR-IOM), Laboratorio TASC, I-34149 Trieste (Italy); Kivimäki, A. [CNR-Istituto Officina dei Materiali (CNR-IOM), Laboratorio TASC, I-34149 Trieste (Italy); Stagira, S. [Politecnico di Milano – Department of Physics, I-20133 Milano (Italy); Coreno, M. [ELETTRA - Sincrotrone Trieste, Basovizza Area Science Park, S. S. 14 - km 163,5, I-34149, Basovizza (TS) (Italy); CNR – Istituto di Struttura della Materia (CNR-ISM), UOS Basovizza, I-34149 Trieste (Italy)

    2014-10-15T23:59:59.000Z

    A portable and compact photon spectrometer to be used for photon in-photon out experiments, in particular x-ray emission spectroscopy, is presented. The instrument operates in the 25–800 eV energy range to cover the full emissions of the FEL1 and FEL2 stages of FERMI. The optical design consists of two interchangeable spherical varied-lined-spaced gratings and a CCD detector. Different input sections can be accommodated, with/without an entrance slit and with/without an additional relay mirror, that allow to mount the spectrometer in different end-stations and at variable distances from the target area both at synchrotron and at free-electron-laser beamlines. The characterization on the Gas Phase beamline at ELETTRA Synchrotron (Italy) is presented.

  20. Development of a ten inch manipulators-based, flexible, broadband two-crystal spectrometer

    SciTech Connect (OSTI)

    Steel, A. B., E-mail: steel1@llnl.gov; Dunn, J.; Emig, J.; Beiersdorfer, P.; Brown, G. V.; Shepherd, R.; Marley, E. V. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Hoarty, D. J. [Atomic Weapons Establishment, Aldermaston (United Kingdom)

    2014-11-15T23:59:59.000Z

    We have developed and implemented a broadband X-ray spectrometer with a variable energy range for use at the Atomic Weapons Establishment's Orion Laser. The spectrometer covers an energy bandwidth of ?1–2 keV using two independently mounted, movable Bragg diffraction crystals. Using combinations of cesium hydrogen pthlate, ammonium dihydrogen phosphate, and pentaerythritol crystals, spectra covering the 1.4–2.5, 1.85–3.15, or 3.55–5.1 keV energy bands have been measured. Image plate is used for detection owing to its high dynamic range. Background signals caused by high energy X-rays and particles commonly produced in high energy laser experiments are reduced by a series of tantalum baffles and filters installed between the source and crystal and also between the crystals and detector.

  1. Top quark mass measurements

    SciTech Connect (OSTI)

    Hill, Christopher S.; /UC, Santa Barbara

    2004-12-01T23:59:59.000Z

    The top quark, with its extraordinarily large mass (nearly that of a gold atom), plays a significant role in the phenomenology of EWSB in the Standard Model. In particular, the top quark mass when combined with the W mass constrains the mass of the as yet unobserved Higgs boson. Thus, a precise determination of the mass of the top quark is a principal goal of the CDF and D0 experiments. With the data collected thus far in Runs 1 and 2 of the Tevatron, CDF and D0 have measured the top quark mass in both the lepton+jets and dilepton decay channels using a variety of complementary experimental techniques. The author presents an overview of the most recent of the measurements.

  2. A magnetic spectrometer measurement of the charge ratio of energetic cosmic ray muons

    E-Print Network [OSTI]

    Bateman, Benjamin Jefferson

    1967-01-01T23:59:59.000Z

    A MAGNETIC SPECTROIIETER MEASUREPIENT OF THE CHARGE PATIO OF ENEIFGFTIC COSMIC RAY MUONS A Thesis BENJAMIN JEF1'EIHSON BATFIKN, JR. Submdtted to the Graduate College of the Texas AAM University in Daltial full'Ills, 'ent of the requirellents... magnet ~ 2 Schematic representation of the magnets, counters and spark chambers to form a spectrometer-telescope. A typical muon trajectory is shown. . . . . . . . ~ 3 End view of the eighteen-lamina magnet. 4 The winding process 5 The complete...

  3. High Gain, Fast Scan, Broad Spectrum, Parallel Beam Wavelength Dispersive X-ray Spectrometer for SEM

    SciTech Connect (OSTI)

    David OHara; Dr. Eric Lochmer

    2003-09-12T23:59:59.000Z

    Parallax Research, Inc. proposes to produce a new type of x-ray spectrometer for use with Scanning Electron Microscopy (SEM) that would have the energy resolution of WDS and the ease of use of EDS with sufficient gain for lower energies that it can be used at low beam currents as is EDS. Parallax proposes to do this by development of new multiple reflection x-ray collimation optics, new diffractor technology, new detector technology and new scan algorithms.

  4. MassMass transfer andtransfer and MassMass transfer andtransfer and

    E-Print Network [OSTI]

    Zevenhoven, Ron

    Heat conductivity T'1 Heat flux h" (W/m2), local and overall heat transfer coeffients h1 Heat transfer coefficientcoefficient /1/1 Mass flow species A:interface a p A = A mol/s M f1 (L) 2 (G) Mass transfer rate per area: A = A/a = "A mol/(m2·s) 1 (L) 2 (G) xi C1.i M t f ffi i t k x C y 1.i AA !!! Mass transfer coefficients

  5. Mass and Heat Recovery

    E-Print Network [OSTI]

    Hindawai, S. M.

    2010-01-01T23:59:59.000Z

    - 1 - MASS AND HEAT RECOVERY SYSTEM SALAH MAHMOUD HINDAWI DIRECTOR HINDAWI FOR ENGINEERING SERVICES & CONTRACTING NEW DAMIETTA , EGYPT ABSTRACT : In the last few years heat recovery was under spot . and in air conditioning fields... ) as a heat recovery . and I use the water as a mass recovery . The source of mass and heat recovery is the condensate water which we were dispose and connect it to the drain lines . THE BENEFIT OF THIS SYSTEM ARE : 1) Using the heat energy from...

  6. Status of SuperSpec: A Broadband, On-Chip Millimeter-Wave Spectrometer

    E-Print Network [OSTI]

    Hailey-Dunsheath, S; Barry, P S; Bradford, C M; Chattopadhyay, G; Day, P; Doyle, S; Hollister, M; Kovacs, A; LeDuc, H G; Mauskopf, P; McKenney, C M; Monroe, R; O'Brient, R; Padin, S; Reck, T; Swenson, L; Tucker, C E; Zmuidzinas, J

    2015-01-01T23:59:59.000Z

    SuperSpec is a novel on-chip spectrometer we are developing for multi-object, moderate resolution (R = 100 - 500), large bandwidth (~1.65:1) submillimeter and millimeter survey spectroscopy of high-redshift galaxies. The spectrometer employs a filter bank architecture, and consists of a series of half-wave resonators formed by lithographically-patterned superconducting transmission lines. The signal power admitted by each resonator is detected by a lumped element titanium nitride (TiN) kinetic inductance detector (KID) operating at 100-200 MHz. We have tested a new prototype device that is more sensitive than previous devices, and easier to fabricate. We present a characterization of a representative R=282 channel at f = 236 GHz, including measurements of the spectrometer detection efficiency, the detector responsivity over a large range of optical loading, and the full system optical efficiency. We outline future improvements to the current system that we expect will enable construction of a photon-noise-lim...

  7. The lead-glass electromagnetic calorimeters for the magnetic spectrometers in Hall C at Jefferson Lab

    E-Print Network [OSTI]

    H. Mkrtchyan; R. Carlini; V. Tadevosyan; J. Arrington; A. Asaturyan; M. E. Christy; D. Dutta; R. Ent; H. C. Fenker; D. Gaskell; T. Horn; M. K. Jones; C. E. Keppel; D. J. Mack; S. P. Malace; A. Mkrtchyan; M. I. Niculescu; J. Seely; V. Tvaskis; S. A. Wood; S. Zhamkochyan

    2012-04-28T23:59:59.000Z

    The electromagnetic calorimeters of the various magnetic spectrometers in Hall C at Jefferson Lab are presented. For the existing HMS and SOS spectrometers design considerations, relevant construction information, and comparisons of simulated and experimental results are included. The energy resolution of the HMS and SOS calorimeters is better than $\\sigma/E \\sim 6%/\\sqrt E $, and pion/electron ($\\pi/e$) separation of about 100:1 has been achieved in energy range 1 -- 5 GeV. Good agreement has been observed between the experimental and simulated energy resolutions, but simulations systematically exceed experimentally determined $\\pi^-$ suppression factors by close to a factor of two. For the SHMS spectrometer presently under construction details on the design and accompanying GEANT4 simulation efforts are given. The anticipated performance of the new calorimeter is predicted over the full momentum range of the SHMS. Good electron/hadron separation is anticipated by combining the energy deposited in an initial (preshower) calorimeter layer with the total energy deposited in the calorimeter.

  8. GeMini: The Next Generation Mechanically-Cooled Germanium Spectrometer

    SciTech Connect (OSTI)

    Burks, M

    2008-06-13T23:59:59.000Z

    The next-generation mechanically-cooled germanium spectrometer has been developed. GeMini (GErmanium MINIature spectrometer) has been designed to bring high-resolution gamma-ray spectroscopy to a range of demanding field environments. Intended applications include short-notice and surprise inspections where positive nuclide identification of radioactive materials is required. GeMini weighs 2.75 kg (6 lbs) total including the detector, cryostat, cryocooler, batteries, electronics and readout. It is very low power allowing it to operate for 10 hours on a single set of rechargeable batteries. This instrument employs technology adapted from the gamma-ray spectrometer currently flying on NASA's Mercury MESSENGER spacecraft. Specifically, infrared shielding techniques allow for a vast reduction of thermal load. This in turn allows for a smaller, lighter-weight design, well-suited for a hand-held instrument. Two working prototypes have been built and tested in the lab. The target energy resolution is 3 keV fwhm or better for 1332 keV gamma-rays. The detectors currently achieve around 4.5 keV resolution, which is slightly higher than our goal due to microphonic noise. Our present work focuses on improving the resolution through mechanical and electronic means of reducing the microphonic noise. This paper will focus on the performance of the instrument and its applicability for inspectors in the field.

  9. A design study of VOR: a versatile optimal resolution chopper spectrometer for the ESS

    E-Print Network [OSTI]

    Deen, P P; Andersen, K H; Hall-Wilton, R

    2014-01-01T23:59:59.000Z

    VOR, the versatile optimal resolution chopper spectrometer, is designed to probe dynamic phenomena that are currently inaccessible for inelastic neutron scattering due to flux limitations. VOR is a short instrument by the standards of the European Spallation Source (ESS), 30.2 m moderator to sample, and provides instantaneous access to a broad dynamic range, 1 - 120 meV within each ESS period. The short instrument length combined with the long ESS pulse width enables a quadratic flux increase, even at longer wavelengths, by relaxing energy resolution from $\\Delta$E/E = 1% up to $\\Delta$E/E = 7%. This is impossible both on a long chopper spectrometer at the ESS and with instruments at short pulsed sources. In comparison to current day chopper spectrometers, VOR can offer an order of magnitude improvement in flux for equivalent energy resolutions, $\\Delta$E/E = 1-3%. Further relaxing the energy resolution enables VOR to gain an extra order of magnitude in flux. In addition, VOR has been optimised for repetition...

  10. Results for the response function determination of the Compact Neutron Spectrometer

    E-Print Network [OSTI]

    Gagnon-Moisan, F; Zimbal, A

    2012-01-01T23:59:59.000Z

    The Compact Neutron Spectrometer (CNS) is a Joint European Torus (JET) Enhancement Project, designed for fusion diagnostics in different plasma scenarios. The CNS is based on a liquid scintillator (BC501A) which allows good discrimination between neutron and gamma radiation. Neutron spectrometry with a BC501A spectrometer requires the use of a reliable, fully characterized detector. The determination of the response matrix was carried out at the Ion Accelerator Facility (PIAF) of the Physikalisch-Technische Bundesanstalt (PTB). This facility provides several monoenergetic beams (2.5, 8, 10, 12 and 14 MeV) and a 'white field'(Emax ~17 MeV), which allows for a full characterization of the spectrometer in the region of interest (from ~1.5 MeV to ~17 MeV. The energy of the incoming neutrons was determined by the time of flight method (TOF), with time resolution in the order of 1 ns. To check the response matrix, the measured pulse height spectra were unfolded with the code MAXED and the resulting energy distribut...

  11. An Ion Doppler Spectrometer Instrument for Ion Temperature and Flow Measurements on SSPX

    SciTech Connect (OSTI)

    King, J D; McLean, H S; Wood, R D; Romero-Talamas, C A; Moller, J M; Morse, E C

    2008-05-19T23:59:59.000Z

    A high-resolution ion Doppler spectrometer has been installed on the Sustained Spheromak Plasma Experiment to measure ion temperatures and plasma flow. The system is composed of a 1 meter focal length Czerny-Turner spectrometer with diffraction grating line density of 2400 lines/mm, which allows for first order spectra between 300 and 600 nm. A 16-channel photomultiplier tube detection assembly combined with output coupling optics provides a spectral resolution of 0.0126 nm per channel. We calculate in some detail the mapping of curved slit images onto the linear detector array elements. This is important in determining wavelength resolution and setting the optimum vertical extent of the slit. Also, because of the small wavelength window of the IDS, a miniature fiber optic survey spectrometer sensitive to a wavelength range 200 to 1100 nm and having resolution 0.2 nm, is used to obtain a time-integrated spectrum for each shot to verify specific impurity line radiation. Several measurements validate the systems operation. Doppler broadening of C III 464.72 nm line in the plasma shows time-resolved ion temperatures up to 250 eV for hydrogen discharges, which is consistent with neutral particle energy analyzer measurements. Flow measurements show a sub-Alfvenic plasma flow ranging from 5 to 45 km/s for helium discharges.

  12. Superresolution of a compact neutron spectrometer at energies relevant for fusion diagnostics

    SciTech Connect (OSTI)

    Reginatto, M.; Zimbal, A. [Physikalisch-Technische Bundesanstalt (PTB), Braunschweig (Germany)

    2011-03-14T23:59:59.000Z

    The ability to achieve resolution that is better than the instrument resolution (i.e., superresolution) is well known in optics, where it has been extensively studied. Unfortunately, there are only a handful of theoretical studies concerning superresolution of particle spectrometers, even though experimentalists are familiar with the enhancement of resolution that is achievable when appropriate methods of data analysis are used, such as maximum entropy and Bayesian methods. Knowledge of the superresolution factor is in many cases important. For example, in applications of neutron spectrometry to fusion diagnostics, the temperature of a burning plasma is an important physical parameter which may be inferred from the width of the peak of the neutron energy spectrum, and the ability to determine this width depends on the superresolution factor. Kosarev has derived an absolute limit for resolution enhancement using arguments based on a well known theorem of Shannon. Most calculations of superresolution factors in the literature, however, are based on the assumption of Gaussian, translationally invariant response functions and therefore not directly applicable to neutron spectrometers which typically have response functions not satisfying these requirements. In this work, we develop a procedure that allows us to overcome these difficulties and we derive estimates of superresolution for liquid scintillator spectrometers of a type commonly used for neutron measurements. Theoretical superresolution factors are compared to experimental results.

  13. Nuclear Masses in Astrophysics

    E-Print Network [OSTI]

    Christine Weber; Klaus Blaum; Hendrik Schatz

    2008-12-09T23:59:59.000Z

    Among all nuclear ground-state properties, atomic masses are highly specific for each particular combination of N and Z and the data obtained apply to a variety of physics topics. One of the most crucial questions to be addressed in mass spectrometry of unstable radionuclides is the one of understanding the processes of element formation in the Universe. To this end, accurate atomic mass values of a large number of exotic nuclei participating in nucleosynthesis are among the key input data in large-scale reaction network calculations. In this paper, a review on the latest achievements in mass spectrometry for nuclear astrophysics is given.

  14. Multiple mass solvers

    E-Print Network [OSTI]

    B. Jegerlehner

    1997-08-29T23:59:59.000Z

    We present a general method to construct multiple mass solvers from standard algorithms. As an example, the BiCGstab-M algorithm is derived.

  15. Design of a Real-Time Scanning Electrical Mobility Spectrometer and its Application in Study of Nanoparticle Aerosol Generation

    E-Print Network [OSTI]

    Singh, Gagan

    2012-07-16T23:59:59.000Z

    A real-time, mobile Scanning Electrical Mobility Spectrometer (SEMS) was designed using a Condensation Particle Counter (CPC) and Differential Mobility Analyzer (DMA) to measure the size distribution of nanoparticles. The SEMS was calibrated using...

  16. Direct and quantitative broadband absorptance spectroscopy on small objects using Fourier transform infrared spectrometer and bilayer cantilever probes

    E-Print Network [OSTI]

    Hsu, Wei-Chun

    A measurement platform is introduced that combines a bilayer cantilever probe with a Fourier transform infrared spectrometer to measure absolute spectral absorptance between wavelengths of 3??m and 18??m directly and ...

  17. mass communication advertising &

    E-Print Network [OSTI]

    Finzi, Adrien

    mass communication advertising & public relations introduction. Graduate programs in the Department of Mass Communication, Advertising, and Public Relations provide an entry to a wide spectrum of careers in the communication industry. Classes, internships, site visits, and presentations by top professionals offer students

  18. The Origins of Mass

    ScienceCinema (OSTI)

    Lincoln, Don

    2014-08-07T23:59:59.000Z

    The Higgs boson was discovered in July of 2012 and is generally understood to be the origin of mass. While those statements are true, they are incomplete. It turns out that the Higgs boson is responsible for only about 2% of the mass of ordinary matter. In this dramatic new video, Dr. Don Lincoln of Fermilab tells us the rest of the story.

  19. The Origins of Mass

    SciTech Connect (OSTI)

    Lincoln, Don

    2014-07-30T23:59:59.000Z

    The Higgs boson was discovered in July of 2012 and is generally understood to be the origin of mass. While those statements are true, they are incomplete. It turns out that the Higgs boson is responsible for only about 2% of the mass of ordinary matter. In this dramatic new video, Dr. Don Lincoln of Fermilab tells us the rest of the story.

  20. Determination of iodine to compliment mass spectrometric measurements

    SciTech Connect (OSTI)

    Hohorst, F.A.

    1994-11-01T23:59:59.000Z

    The dose of iodine-129 to facility personnel and the general public as a result of past, present, and future activities at DOE sites is of continuing interest, WINCO received about 160 samples annually in a variety of natural matrices, including snow, milk, thyroid tissue, and sagebrush, in which iodine-129 is determined in order to evaluate this dose, Currently, total iodine and the isotopic ratio of iodine-127 to iodine-129 are determined by mass spectrometry. These two measurements determine the concentration of iodine-129 in each sample, These measurements require at least 16 h of mass spectrometer operator time for each sample. A variety of methods are available which concentrate and determine small quantities of iodine. Although useful, these approaches would increase both time and cost. The objective of this effort was to determine total iodine by an alternative method in order to decrease the load on mass spectrometry by 25 to 50%. The preparation of each sample for mass spectrometric analysis involves a common step--collection of iodide on an ion exchange bed. This was the focal point of the effort since the results would be applicable to all samples.

  1. spectrometer | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computational and Magnetic Resonance Spectroscopy: A Case Study on Abstract: Redox flow battery (RFB) is a promising candidate for energy storage component in designing resilient...

  2. Absolute neutrino mass measurements

    SciTech Connect (OSTI)

    Wolf, Joachim [Karlsruhe Institute of Technology (KIT), IEKP, Postfach 3640, 76021 Karlsruhe (Germany)

    2011-10-06T23:59:59.000Z

    The neutrino mass plays an important role in particle physics, astrophysics and cosmology. In recent years the detection of neutrino flavour oscillations proved that neutrinos carry mass. However, oscillation experiments are only sensitive to the mass-squared difference of the mass eigenvalues. In contrast to cosmological observations and neutrino-less double beta decay (0v2{beta}) searches, single {beta}-decay experiments provide a direct, model-independent way to determine the absolute neutrino mass by measuring the energy spectrum of decay electrons at the endpoint region with high accuracy.Currently the best kinematic upper limits on the neutrino mass of 2.2eV have been set by two experiments in Mainz and Troitsk, using tritium as beta emitter. The next generation tritium {beta}-experiment KATRIN is currently under construction in Karlsruhe/Germany by an international collaboration. KATRIN intends to improve the sensitivity by one order of magnitude to 0.2eV. The investigation of a second isotope ({sup 137}Rh) is being pursued by the international MARE collaboration using micro-calorimeters to measure the beta spectrum. The technology needed to reach 0.2eV sensitivity is still in the R and D phase. This paper reviews the present status of neutrino-mass measurements with cosmological data, 0v2{beta} decay and single {beta}-decay.

  3. Exploration of the neutron-rich mass surface from sup 11 Li to sup 66 Fe

    SciTech Connect (OSTI)

    Vieira, D.J.; Wouters, J.M.; Butler, G.W. (Los Alamos National Lab., NM (United States)); Seifert, H.L. (Los Alamos National Lab., NM (United States) Giessen Univ. (Germany). 2. Physikalisches Inst.); Zhou, Z.Y. (Los Alamos National Lab., NM (United States) Nanjing Univ., JS (China). Dept. of Physics and Astronomy); Zhou, X.G.; Tu, X.L.; Lind, V.G. (Utah State Univ., Logan, UT (United States). Dept.

    1991-01-01T23:59:59.000Z

    A small revolution in our ability to perform mass measurements of light-mass, neutron-rich nuclei has occurred during the last five years with the extension of the direct, total mass measurement method to fast recoiling nuclei. To date the work of two groups, one using the SPEG spectrometer at GANIL and the other using the TOFI spectrometer at LAMPF, has yielded over 85 mass measurements of which 62 had not been reported previously. Extending from the neutron-halo nucleus {sup 11}Li up to {sup 66}Fe, a region relevant to the astrophysical r-process, these measurements have provided a valuable first glimpse into the interesting nuclear structure present in many of these exotic nuclei. Herein we highlight the nuclear structure insight which as been gained from these measurements, especially that learned from a comparison to recent shell model calculations. Attention is given to: (1) the binding of loosely-bound neutron halo nuclei; (2) the N=14--16 region in the neutron-rich isotopes of O, F, and Ne where the strong two-body interaction plays an important role; (3) the deformed intruder state region around {sup 31}Na of long standing interest; (4) the neutron-rich isotopes of sulfur and chlorine; and (5) the question of the isospin dependence (or independence) of neutron and proton pairing energies in the fp shell. Only the briefest account of this work can be given here; emphasis is placed on the most recent results. 24 refs., 3 figs.

  4. Exploration of the neutron-rich mass surface from {sup 11}Li to {sup 66}Fe

    SciTech Connect (OSTI)

    Vieira, D.J.; Wouters, J.M.; Butler, G.W. [Los Alamos National Lab., NM (United States); Seifert, H.L. [Los Alamos National Lab., NM (United States)]|[Giessen Univ. (Germany). 2. Physikalisches Inst.; Zhou, Z.Y. [Los Alamos National Lab., NM (United States)]|[Nanjing Univ., JS (China). Dept. of Physics and Astronomy; Zhou, X.G.; Tu, X.L.; Lind, V.G. [Utah State Univ., Logan, UT (United States). Dept. of Physics; Loebner, K.E.G. [Muenchen Univ. (Germany). Sektion Physik

    1991-12-01T23:59:59.000Z

    A small revolution in our ability to perform mass measurements of light-mass, neutron-rich nuclei has occurred during the last five years with the extension of the direct, total mass measurement method to fast recoiling nuclei. To date the work of two groups, one using the SPEG spectrometer at GANIL and the other using the TOFI spectrometer at LAMPF, has yielded over 85 mass measurements of which 62 had not been reported previously. Extending from the neutron-halo nucleus {sup 11}Li up to {sup 66}Fe, a region relevant to the astrophysical r-process, these measurements have provided a valuable first glimpse into the interesting nuclear structure present in many of these exotic nuclei. Herein we highlight the nuclear structure insight which as been gained from these measurements, especially that learned from a comparison to recent shell model calculations. Attention is given to: (1) the binding of loosely-bound neutron halo nuclei; (2) the N=14--16 region in the neutron-rich isotopes of O, F, and Ne where the strong two-body interaction plays an important role; (3) the deformed intruder state region around {sup 31}Na of long standing interest; (4) the neutron-rich isotopes of sulfur and chlorine; and (5) the question of the isospin dependence (or independence) of neutron and proton pairing energies in the fp shell. Only the briefest account of this work can be given here; emphasis is placed on the most recent results. 24 refs., 3 figs.

  5. MAINTAINING HIGH RESOLUTION MASS SPECTROMETRY CAPABILITIES FOR NATIONAL NUCLEAR SECURITY ADMINISTRATION APPLICATIONS

    SciTech Connect (OSTI)

    Wyrick, S.; Cordaro, J.; Reeves, G.; Mcintosh, J.; Mauldin, C.; Tietze, K.; Varble, D.

    2011-06-06T23:59:59.000Z

    The Department of Energy (DOE) National Nuclear Security Administration (NNSA) has a specialized need for analyzing low mass gas species at very high resolutions. The currently preferred analytical method is electromagnetic sector mass spectrometry. This method allows the NNSA Nuclear Security Enterprise (NSE) to resolve species of similar masses down to acceptable minimum detection limits (MDLs). Some examples of these similar masses are helium-4/deuterium and carbon monoxide/nitrogen. Through the 1980s and 1990s, there were two vendors who supplied and supported these instruments. However, with declining procurements and down turns in the economy, the supply of instruments, service and spare parts from these vendors has become less available, and in some cases, nonexistent. The largest NSE user of this capability is the Savannah River Site (SRS), located near Aiken, South Carolina. The Research and Development Engineering (R&DE) Group in the Savannah River National Laboratory (SRNL) investigated the areas of instrument support that were needed to extend the life cycle of these aging instruments. Their conclusions, as to the focus areas of electromagnetic sector mass spectrometers to address, in order of priority, were electronics, software and hardware. Over the past 3-5 years, the R&DE Group has designed state of the art electronics and software that will allow high resolution legacy mass spectrometers, critical to the NNSA mission, to be operated for the foreseeable future. The funding support for this effort has been from several sources, including the SRS Defense Programs, NNSA Readiness Campaign, Pantex Plant and Sandia National Laboratory. To date, electronics systems have been upgraded on one development system at SRNL, two production systems at Pantex and one production system at Sandia National Laboratory. An NSE working group meets periodically to review strategies going forward. The R&DE Group has also applied their work to the electronics for a Thermal Ionization Mass Spectrometer (TIMS) instrument, which applies a similar mass spectrometric technology for resolving high mass isotopes, such as plutonium and uranium. Due to non-compete clauses for DOE, all work has been performed and applied to instruments which are obsolete and are no longer supported by the original vendor.

  6. Masses of Fundamental Particles

    E-Print Network [OSTI]

    Hidezumi Terazawa

    2014-06-11T23:59:59.000Z

    In the original paper entitled, "Masses of Fundamental Particles"(arXiv:1109.3705v5, 10 Feb 2012), not only the masses of fundamental particles including the weak bosons, Higgs boson, quarks, and leptons, but also the mixing angles of quarks and those of neutrinos are all explained and/or predicted in the unified composite models of quarks and leptons successfully. In this addendum entitled, "Higgs Boson Mass in the Minimal Unified Subquark Model", it is emphasized that the Higgs boson mass is predicted to be about 130Gev in the minimal unified subquark model, which agrees well with the experimental values of 125-126GeV recently found by the ATLAS and CMS Collaborations at the LHC.

  7. Microlens Mass Functions

    E-Print Network [OSTI]

    William D. Heacox

    2005-10-10T23:59:59.000Z

    A non-parametric statistical model is constructed to directly relate The distribution of observed microlens timescales to that of the mass Function of the population from which the lenses are drawn, corrected For observational selection based on timescales and event amplifications. Explicit distributions are derived for microlensing impact parameters and maximum amplifications; both are shown to be statistically independent of all other parameters in the problem, including lens mass. The model is used to demonstrate that the narrow range of microlens timescales observed toward the Large Magellanic Cloud (LMC) is probably not consistent with lensing by a widely distributed spheroidal population of large velocity dispersion, as expected of a dark halo; but is consistent with lensing within a rotating thick disk. Poor numerical conditioning on the statistical connection between lens masses and event timescales, and small number statistics, severely limit the mass function information obtainable from current microlensing surveys toward the LMC.

  8. HIGEE Mass Transfer

    E-Print Network [OSTI]

    Mohr, R. J.; Fowler, R.

    HIGEE MASS TRANSFER R.J. Mohr and R. Fowler GLITSCH, INC. Dallas, Texas ABSTRACT Distillation, absorption, and gas stripping have traditionally been performed in tall columns utilizing trays or packing. Columns perform satisfactorily... transfer system which utilizes a rotating bed of packing to achieve high efficiency separations, and consequent reduction in size and weight. INTRODUCTION HIGEE is probably one of the most interesting developments in mass transfer equipment made...

  9. Mass of Cu-57

    E-Print Network [OSTI]

    Gagliardi, Carl A.; Semon, D. R.; Tribble, Robert E.; Vanausdeln, L. A.

    1986-01-01T23:59:59.000Z

    the experimental and theoretical Coulomb displacement energies for similar cases in A =17 and 41 has been attributed~ to ground state correlations in the nuclear wave functions. It is in- teresting to examine the mass 57 mirror nuclei to investi- gate... indicated. Reference 9. 'Reference 7. Reference 6. 'This work. 34 MASS OF Cu 1665 the 3=57 Coulomb displacement energy, using radial wave functions obtained in a spherical Hartree-Fock cal- culation, assuming a closed Ni core, and including...

  10. Wavelength calibration of x-ray imaging crystal spectrometer on Joint Texas Experimental Tokamak

    SciTech Connect (OSTI)

    Yan, W.; Chen, Z. Y., E-mail: zychen@hust.edu.cn; Jin, W.; Huang, D. W.; Ding, Y. H.; Li, J. C.; Zhang, X. Q.; Zhuang, G. [School of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan (China); Lee, S. G.; Shi, Y. J. [National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of)

    2014-11-15T23:59:59.000Z

    The wavelength calibration of x-ray imaging crystal spectrometer is a key issue for the measurements of plasma rotation. For the lack of available standard radiation source near 3.95 Å and there is no other diagnostics to measure the core rotation for inter-calibration, an indirect method by using tokamak plasma itself has been applied on joint Texas experimental tokamak. It is found that the core toroidal rotation velocity is not zero during locked mode phase. This is consistent with the observation of small oscillations on soft x-ray signals and electron cyclotron emission during locked-mode phase.

  11. Spatially resolvable optical emission spectrometer for analyzing density uniformity of semiconductor process plasma

    SciTech Connect (OSTI)

    Oh, Changhoon; Ryoo, Hoonchul; Lee, Hyungwoo; Hahn, Jae W. [Nano Photonics Laboratory, School of Mechanical Engineering, Yonsei University, 134 Sinchon-dong, Seodaemun-gu, Seoul 120-749 (Korea, Republic of); Kim, Se-Yeon; Yi, Hun-Jung [Manufacturing Technology Team, Memory Division, Semiconductor Business, Samsung Electronics, Hwasung-City, Gyeonggi-do 445-701 (Korea, Republic of)

    2010-10-15T23:59:59.000Z

    We proposed a spatially resolved optical emission spectrometer (SROES) for analyzing the uniformity of plasma density for semiconductor processes. To enhance the spatial resolution of the SROES, we constructed a SROES system using a series of lenses, apertures, and pinholes. We calculated the spatial resolution of the SROES for the variation of pinhole size, and our calculated results were in good agreement with the measured spatial variation of the constructed SROES. The performance of the SROES was also verified by detecting the correlation between the distribution of a fluorine radical in inductively coupled plasma etch process and the etch rate of a SiO{sub 2} film on a silicon wafer.

  12. Progress in development of neutron energy spectrometer for deuterium plasma operation in KSTAR

    SciTech Connect (OSTI)

    Tomita, H., E-mail: tomita@nagoya-u.jp; Yamashita, F.; Nakayama, Y.; Morishima, K.; Yamamoto, Y.; Sakai, Y.; Hayashi, S.; Kawarabayashi, J.; Iguchi, T. [Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603 (Japan); Cheon, M. S. [Diagnostics Technology Team, ITER Korea, National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of); Isobe, M. [The Graduate University for Advanced Studies, 322-6 Oroshi-cho, Toki 509-5292 (Japan); National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan); Ogawa, K. [National Institute for Fusion Science, 322-6 Oroshi-cho, Toki 509-5292 (Japan)

    2014-11-15T23:59:59.000Z

    Two types of DD neutron energy spectrometer (NES) are under development for deuterium plasma operation in KSTAR to understand behavior of beam ions in the plasma. One is based on the state-of-the-art nuclear emulsion technique. The other is based on a coincidence detection of a recoiled proton and a scattered neutron caused by an elastic scattering of an incident DD neutron, which is called an associated particle coincidence counting-NES. The prototype NES systems were installed at J-port in KSTAR in 2012. During the 2012 and 2013 experimental campaigns, multiple shots-integrated neutron spectra were preliminarily obtained by the nuclear emulsion-based NES system.

  13. A radial collimator for a time-of-flight neutron spectrometer

    SciTech Connect (OSTI)

    Stone, M. B.; Abernathy, D. L. [Quantum Condensed Matter Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Niedziela, J. L.; Loguillo, M. J.; Overbay, M. A. [Instrument and Source Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

    2014-08-15T23:59:59.000Z

    We have engineered and installed a radial collimator for use in the scattered beam of a neutron time-of-flight spectrometer at a spallation neutron source. The radial collimator may be used with both thermal and epithermal neutrons, reducing the detected scattering intensity due to material outside of the sample region substantially. The collimator is located inside of the sample chamber of the instrument, which routinely cycles between atmospheric conditions and cryogenic vacuum. The oscillation and support mechanism of the collimator allow it to be removed from use without breaking vacuum. We describe here the design and characterization of this radial collimator.

  14. A photoelectron velocity map imaging spectrometer for experiments combining synchrotron and laser radiations

    SciTech Connect (OSTI)

    O'Keeffe, P.; Bolognesi, P.; Coreno, M.; Avaldi, L. [CNR-IMIP, Area della Ricerca di Roma 1, Monterotondo Scalo (Italy); Moise, A.; Richter, R.; Cautero, G.; Stebel, L.; Sergo, R. [Sincrotrone Trieste SCpA, Area Science Park, I-34149 Basovizza (Trieste) (Italy); Pravica, L. [The University of Western Australia, 35 Stirling Hwy, Crawley, Western Australia (Australia); Ovcharenko, Y. [Institute of Electron Physics, 88017 Uzhgorod (Ukraine)

    2011-03-15T23:59:59.000Z

    A velocity map imaging/ion time-of-flight spectrometer designed specifically for pump-probe experiments combining synchrotron and laser radiations is described. The in-house built delay line detector can be used in two modes: the high spatial resolution mode and the coincidence mode. In the high spatial resolution mode a kinetic energy resolution of 6% has been achieved. The coincidence mode can be used to improve signal-to-noise ratio for the pump-probe experiments either by using a gate to count electrons only when the laser is present or by recording coincidences with the ion formed in the ionization process.

  15. Sampling probe for microarray read out using electrospray mass spectrometry

    DOE Patents [OSTI]

    Van Berkel, Gary J.

    2004-10-12T23:59:59.000Z

    An automated electrospray based sampling system and method for analysis obtains samples from surface array spots having analytes. The system includes at least one probe, the probe including an inlet for flowing at least one eluting solvent to respective ones of a plurality of spots and an outlet for directing the analyte away from the spots. An automatic positioning system is provided for translating the probe relative to the spots to permit sampling of any spot. An electrospray ion source having an input fluidicly connected to the probe receives the analyte and generates ions from the analyte. The ion source provides the generated ions to a structure for analysis to identify the analyte, preferably being a mass spectrometer. The probe can be a surface contact probe, where the probe forms an enclosing seal along the periphery of the array spot surface.

  16. 2{pi} spectrometer: A new apparatus for the investigation of ion surface interaction

    SciTech Connect (OSTI)

    Morosov, V.A.; Kalinin, A.; Szilagyi, Z.; Barat, M.; Roncin, P. [Laboratoire des Collisions Atomiques et Moleculaires, Bat 351, Universite Paris Sud, Orsay Cedex F 91405 (France)] [Laboratoire des Collisions Atomiques et Moleculaires, Bat 351, Universite Paris Sud, Orsay Cedex F 91405 (France)

    1996-06-01T23:59:59.000Z

    A new spectrometer for studying ion surface interaction is described. This apparatus is built around a secondary electron and ion detector with a very large acceptance angle and made of 16 individual microchannel plate detectors located on a half sphere. A simultaneous detection of the scattered projectiles with an additional position sensitive detector allows measurements of the correlation between all these particles using a multicoincidence technique. With this spectrometer, a large variety of measurements are possible such as the energy spectra of the secondary electrons as well as the statistics of the number of ejected electrons, the scattering pattern of the reflected projectiles and their charge-state distribution, the analysis of the sputtered ions. Some examples are given concerning the impact of multiply charged ions on a LiF single crystal. The dependence of the secondary electron multiplicity as a function of the charge state, of the surface channeling condition, and of the scattering angle of the reflected ion, is given as a type of information provided by the analysis of the correlation. {copyright} {ital 1996 American Institute of Physics.}

  17. A split imaging spectrometer for temporally and spatially resolved titanium absorption spectroscopy

    SciTech Connect (OSTI)

    Hager, J. D., E-mail: hager@lanl.gov; Lanier, N. E.; Kline, J. L.; Flippo, K. A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Bruns, H. C.; Schneider, M.; Saculla, M.; McCarville, T. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States)

    2014-11-15T23:59:59.000Z

    We present a temporally and a spatially resolved spectrometer for titanium x-ray absorption spectroscopy along 2 axial symmetric lines-of-sight. Each line-of-sight of the instrument uses an elliptical crystal to acquire both the 2p and 3p Ti absorption lines on a single, time gated channel of the instrument. The 2 axial symmetric lines-of-sight allow the 2p and 3p absorption features to be measured through the same point in space using both channels of the instrument. The spatially dependent material temperature can be inferred by observing the 2p and the 3p Ti absorption features. The data are recorded on a two strip framing camera with each strip collecting data from a single line-of-sight. The design is compatible for use at both the OMEGA laser and the National Ignition Facility. The spectrometer is intended to measure the material temperature behind a Marshak wave in a radiatively driven SiO{sub 2} foam with a Ti foam tracer. In this configuration, a broad band CsI backlighter will be used for a source and the Ti absorption spectrum measured.

  18. The magnetic shielding for the neutron decay spectrometer aSPECT

    E-Print Network [OSTI]

    Gertrud Konrad; Fidel Ayala Guardia; Stefan Baeßler; Michael Borg; Ferenc Glück; Werner Heil; Stefan Hiebel; Raquel Munoz Horta; Yury Sobolev

    2014-05-05T23:59:59.000Z

    Many experiments in nuclear and neutron physics are confronted with the problem that they use a superconducting magnetic spectrometer which potentially affects other experiments by their stray magnetic field. The retardation spectrometer aSPECT consists, inter alia, of a superconducting magnet system that produces a strong longitudinal magnetic field of up to 6.2T. In order not to disturb other experiments in the vicinity of aSPECT, we had to develop a magnetic field return yoke for the magnet system. While the return yoke must reduce the stray magnetic field, the internal magnetic field and its homogeneity should not be affected. As in many cases, the magnetic shielding for aSPECT must manage with limited space. In addition, we must ensure that the additional magnetic forces on the magnet coils are not destructive. In order to determine the most suitable geometry for the magnetic shielding for aSPECT, we simulated a variety of possible geometries and combinations of shielding materials of non-linear permeability. The results of our simulations were checked through magnetic field measurements both with Hall and nuclear magnetic resonance probes. The experimental data are in good agreement with the simulated values: The mean deviation from the simulated exterior magnetic field is (-1.7+/-4.8)%. However, in the two critical regions, the internal magnetic field deviates by 0.2% respectively <1E-4 from the simulated values.

  19. Atomic mass compilation 2012

    SciTech Connect (OSTI)

    Pfeiffer, B., E-mail: bpfeiffe@uni-mainz.de [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany); GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany); Venkataramaniah, K. [Sri Sathya Sai Institute of Higher Learning, Prasanthinilayam (India)] [Sri Sathya Sai Institute of Higher Learning, Prasanthinilayam (India); Czok, U. [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany)] [II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany); Scheidenberger, C. [GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany) [GSI Helmholtzzentrum für Schwerionenforschung, Darmstadt (Germany); II. Physikalisches Institut, Justus-Liebig-Universität Gießen, Gießen (Germany)

    2014-03-15T23:59:59.000Z

    Atomic mass reflects the total binding energy of all nucleons in an atomic nucleus. Compilations and evaluations of atomic masses and derived quantities, such as neutron or proton separation energies, are indispensable tools for research and applications. In the last decade, the field has evolved rapidly after the advent of new production and measuring techniques for stable and unstable nuclei resulting in substantial ameliorations concerning the body of data and their precision. Here, we present a compilation of atomic masses comprising the data from the evaluation of 2003 as well as the results of new measurements performed. The relevant literature in refereed journals and reports as far as available, was scanned for the period beginning 2003 up to and including April 2012. Overall, 5750 new data points have been collected. Recommended values for the relative atomic masses have been derived and a comparison with the 2003 Atomic Mass Evaluation has been performed. This work has been carried out in collaboration with and as a contribution to the European Nuclear Structure and Decay Data Network of Evaluations.

  20. SEASONAL PERIODICITY OF GROWTH AND COMPOSITION IN VALVES OF DIPLODON CHILENSIS PATAGONICUS

    E-Print Network [OSTI]

    Schöne, Bernd R.

    elements (Mn, Mg, Sr, Ba, Na, S) in situ by Laser Ablation ICP-MS and Electron Probe Microanalyser analyses