National Library of Energy BETA

Sample records for mass electron based

  1. ELECTRONICS UPGRADE OF HIGH RESOLUTION MASS SPECTROMETERS

    SciTech Connect (OSTI)

    Mcintosh, J; Joe Cordaro, J

    2008-03-10

    High resolution mass spectrometers are specialized systems that allow researchers to determine the exact mass of samples to four significant digits by using magnetic and electronic sector mass analyzers. Many of the systems in use today at research laboratories and universities were designed and built more than two decades ago. The manufacturers of these systems have abandoned the support for some of the mass spectrometers and parts to power and control them have become scarce or obsolete. The Savannah River National Laboratory has been involved in the upgrade of the electronics and software for these legacy machines. The Electronics Upgrade of High Resolution Mass Spectrometers consists of assembling high-end commercial instrumentation from reputable manufacturers with a minimal amount of customization to replace the electronics for the older systems. By taking advantage of advances in instrumentation, precise magnet control can be achieved using high resolution current sources and continuous feedback from a high resolution hall-effect probe. The custom equipment include a precision voltage divider/summing amplifier chassis, high voltage power supply chassis and a chassis for controlling the voltage emission for the mass spectrometer source tube. The upgrade package is versatile enough to interface with valve control, vacuum and other instrumentation. Instrument communication is via a combination of Ethernet and traditional IEEE-488 GPIB protocols. The system software upgrades include precision control, feedback and spectral waveform analysis tools.

  2. Electron Ionization Mass Spectrum of Tellurium Hexafluoride

    SciTech Connect (OSTI)

    Clark, Richard A.; McNamara, Bruce K.; Barinaga, Charles J.; Peterson, James M.; Govind, Niranjan; Andersen, Amity; Abrecht, David G.; Schwantes, Jon M.; Ballou, Nathan E.

    2015-05-18

    The first electron ionization mass spectrum of tellurium hexafluoride (TeF6) is reported. The starting material was produced by direct fluorination of Te metal or TeO2 with nitrogen trifluoride. Formation of TeF6 was confirmed through cryogenic capture of the tellurium fluorination product and analysis through Raman spectroscopy. The eight natural abundance isotopes were observed for each of the set of fragment ions: TeF5+, TeF4+ TeF3+, TeF2+, TeF1+, and Te+, Te2+. A trend in increasing abundance was observed for the even fluoride bearing ions: TeF1+ < TeF3+ < TeF5+, and a decreasing abundance was observed for the even fragment series: Te(0)+ > TeF2+ > TeF4+ > TeF6+, with the molecular ion TeF6+ not observed at all. Density functional theory based electronic structure calculations were used to calculate optimized ground state geometries of these gas phase species and their relative stabilities explain the trends in the data and the lack of observed signal for TeF6+.

  3. Electron source for a mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, Daniel D.; Keville, Robert F.

    1995-01-01

    An ion trap which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10.sup.9 and commercial mass spectrometers requiring 10.sup.4 ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products.

  4. Electron source for a mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, D.D.; Keville, R.F.

    1995-12-19

    An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

  5. Stretchable polymer-based electronic device (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    Stretchable polymer-based electronic device Title: Stretchable polymer-based electronic device A stretchable electronic circuit or electronic device and a polymer-based process to ...

  6. Digitally synthesized high purity, high-voltage radio frequency drive electronics for mass spectrometry

    SciTech Connect (OSTI)

    Schaefer, R. T.; Mojarradi, M.; MacAskill, J. A.; Chutjian, A.; Darrach, M. R.; Madzunkov, S. M.; Shortt, B. J.

    2008-09-15

    Reported herein is development of a quadrupole mass spectrometer controller (MSC) with integrated radio frequency (rf) power supply and mass spectrometer drive electronics. Advances have been made in terms of the physical size and power consumption of the MSC, while simultaneously making improvements in frequency stability, total harmonic distortion, and spectral purity. The rf power supply portion of the MSC is based on a series-resonant LC tank, where the capacitive load is the mass spectrometer itself, and the inductor is a solenoid or toroid, with various core materials. The MSC drive electronics is based on a field programmable gate array (FPGA), with serial peripheral interface for analog-to-digital and digital-to-analog converter support, and RS232/RS422 communications interfaces. The MSC offers spectral quality comparable to, or exceeding, that of conventional rf power supplies used in commercially available mass spectrometers; and as well an inherent flexibility, via the FPGA implementation, for a variety of tasks that includes proportional-integral derivative closed-loop feedback and control of rf, rf amplitude, and mass spectrometer sensitivity. Also provided are dc offsets and resonant dipole excitation for mass selective accumulation in applications involving quadrupole ion traps; rf phase locking and phase shifting for external loading of a quadrupole ion trap; and multichannel scaling of acquired mass spectra. The functionality of the MSC is task specific, and is easily modified by simply loading FPGA registers or reprogramming FPGA firmware.

  7. Linear electronic field time-of-flight ion mass spectrometers

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM)

    2010-08-24

    Time-of-flight mass spectrometer comprising a first drift region and a second drift region enclosed within an evacuation chamber; a means of introducing an analyte of interest into the first drift region; a pulsed ionization source which produces molecular ions from said analyte of interest; a first foil positioned between the first drift region and the second drift region, which dissociates said molecular ions into constituent atomic ions and emits secondary electrons; an electrode which produces secondary electrons upon contact with a constituent atomic ion in second drift region; a stop detector comprising a first ion detection region and a second ion detection region; and a timing means connected to the pulsed ionization source, to the first ion detection region, and to the second ion detection region.

  8. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Electron Correlation in Iron-Based Superconductors Print Wednesday, 24 February 2010 00:00 In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of

  9. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One clue lies in whether the electrons in...

  10. Study of node and mass sensitivity of resonant mode based cantilevers with concentrated mass loading

    SciTech Connect (OSTI)

    Zhang, Kewei Chai, Yuesheng; Fu, Jiahui

    2015-12-15

    Resonant-mode based cantilevers are an important type of acoustic wave based mass-sensing devices. In this work, the governing vibration equation of a bi-layer resonant-mode based cantilever attached with concentrated mass is established by using a modal analysis method. The effects of resonance modes and mass loading conditions on nodes and mass sensitivity of the cantilever were theoretically studied. The results suggested that the node did not shift when concentrated mass was loaded on a specific position. Mass sensitivity of the cantilever was linearly proportional to the square of the point displacement at the mass loading position for all the resonance modes. For the first resonance mode, when mass loading position x{sub c} satisfied 0 < x{sub c} < ∼ 0.3l (l is the cantilever beam length and 0 represents the rigid end), mass sensitivity decreased as the mass increasing while the opposite trend was obtained when mass loading satisfied ∼0.3l ≤ x{sub c} ≤ l. Mass sensitivity did not change when concentrated mass was loaded at the rigid end. This work can provide scientific guidance to optimize the mass sensitivity of a resonant-mode based cantilever.

  11. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  12. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  13. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  14. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  15. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  16. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  17. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Correlation in Iron-Based Superconductors Print In 2008, the discovery of iron-based superconductors stimulated a worldwide burst of activity, leading to about two preprints per day ever since. With a maximum superconducting transition temperature (so far) of 55 K, it is natural to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature superconductors." One

  18. Stretchable polymer-based electronic device

    DOE Patents [OSTI]

    Maghribi, Mariam N.; Krulevitch, Peter A.; Davidson, James Courtney; Wilson, Thomas S.; Hamilton, Julie K.; Benett, William J.; Tovar, Armando R.

    2008-02-26

    A stretchable electronic circuit or electronic device and a polymer-based process to produce a circuit or electronic device containing a stretchable conducting circuit. The stretchable electronic apparatus has a central longitudinal axis and the apparatus is stretchable in a longitudinal direction generally aligned with the central longitudinal axis. The apparatus comprises a stretchable polymer body and at least one circuit line operatively connected to the stretchable polymer body. The circuit line extends in the longitudinal direction and has a longitudinal component that extends in the longitudinal direction and has an offset component that is at an angle to the longitudinal direction. The longitudinal component and the offset component allow the apparatus to stretch in the longitudinal direction while maintaining the integrity of the circuit line.

  19. ERL BASED ELECTRON-ION COLLIDER ERHIC.

    SciTech Connect (OSTI)

    LITVINENKO,V.N.; BEN-ZVI,I.; ANDERSON,D.; ET AL.

    2005-05-16

    In this paper we describe eRHIC design based on the RHIC hadron rings and 10-to-20 GeV energy recovery electron linac. RHIC requires a very large tunability range for c.m. energies while maintaining very high luminosity up to 10{sup 34} cm{sup -2} s{sup -1} per nucleon. The designs of this future polarized electron-hadron collider, eRHIC, based on a high current super-conducting energy-recovery linac (ERL) with energy of electrons up to 20 GeV, have a number of specific requirements on the ERL optics. Two of the most attractive features of this scheme are full spin transparency of the ERL at all operational energies and the capability to support up to four interaction points. We present two main layouts of the eRHIC, the expected beam and luminosity parameter, and discuss the potential limitation of its performance. Two of the most attractive features of this scheme are full spin transparency of the ERL at all operational energies and the capability to support up to four interaction points. We present two main layouts of the eRHIC, the expected beam and luminosity parameter, and discuss the potential limitation of its performance.

  20. Negative-mass mitigation of Coulomb repulsion for terahertz undulator radiation of electron bunches

    SciTech Connect (OSTI)

    Balal, N.; Magory, E.; Bandurkin, I. V.; Bratman, V. L.; Savilov, A. V.

    2015-10-19

    It is proposed to utilize the effect of negative mass for stabilization of the effective axial size of very dense and short electron bunches produced by photo-injector guns by using combined undulator and strong uniform magnetic fields. It has been shown that in the “abnormal” regime, an increase in the electron energy leads to a decrease in the axial velocity of the electron; due to the negative-mass effect, the Coulomb repulsion of electrons leads to their attraction and formation of a fairly stable and compact bunch “nucleus.” An undulator with a strong uniform magnetic field providing the negative-mass effect is designed for an experimental source of terahertz radiation. The use of the negative-mass regime in this experiment should result in a long-pulse coherent spontaneous undulator emission from a short dense moderately relativistic (5.5 MeV) photo-injector electron bunch with a high (up to 20%) efficiency and a narrow frequency spectrum.

  1. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    between different theoretical models and experimental data indicated that, instead of localized states due to strong electron interactions, electrons in iron pnictides prefer...

  2. Spin orbit torque based electronic neuron

    SciTech Connect (OSTI)

    Sengupta, Abhronil Choday, Sri Harsha; Kim, Yusung; Roy, Kaushik

    2015-04-06

    A device based on current-induced spin-orbit torque (SOT) that functions as an electronic neuron is proposed in this work. The SOT device implements an artificial neuron's thresholding (transfer) function. In the first step of a two-step switching scheme, a charge current places the magnetization of a nano-magnet along the hard-axis, i.e., an unstable point for the magnet. In the second step, the SOT device (neuron) receives a current (from the synapses) which moves the magnetization from the unstable point to one of the two stable states. The polarity of the synaptic current encodes the excitatory and inhibitory nature of the neuron input and determines the final orientation of the magnetization. A resistive crossbar array, functioning as synapses, generates a bipolar current that is a weighted sum of the inputs. The simulation of a two layer feed-forward artificial neural network based on the SOT electronic neuron shows that it consumes ?3 lower power than a 45?nm digital CMOS implementation, while reaching ?80% accuracy in the classification of 100 images of handwritten digits from the MNIST dataset.

  3. Measurement of the electron antineutrino mass from the beta spectrum of gaseous tritium

    SciTech Connect (OSTI)

    Knapp, D.A.

    1986-12-01

    A measurement has been made of the mass of the electron antineutrino using the beta spectrum from a source of gaseous molecular tritium, and an upper limit of 36 eV/c/sup 2/ has been set on this mass. This measurement is the first upper limit on neutrino mass that does not rely on assumptions about the atomic configuration after the beta decay, and it has significantly smaller systematic errors associated with it than do previous measurements. 130 refs., 83 figs., 8 tabs.

  4. Electron Flood Charge Compensation Device for Ion Trap Secondary Ion Mass Spectrometry

    SciTech Connect (OSTI)

    Appelhans, Anthony David; Ward, Michael Blair; Olson, John Eric

    2002-11-01

    During secondary ion mass spectrometry (SIMS) analyses of organophosphorous compounds adsorbed onto soils, the measured anion signals were lower than expected and it was hypothesized that the low signals could be due to sample charging. An electron flood gun was designed, constructed and used to investigate sample charging of these and other sample types. The flood gun was integrated into one end cap of an ion trap secondary ion mass spectrometer and the design maintained the geometry of the self-stabilizing extraction optics used in this instrument. The SIMION ion optics program was used to design the flood gun, and experimental results agreed with the predicted performance. Results showed the low anion signals from the soils were not due to sample charging. Other insulating and conducting samples were tested using both a ReO4- and a Cs+ primary ion beam. The proximity of the sample and electron source to the ion trap aperture resulted in generation of background ions in the ion trap via electron impact (EI) ionization during the period the electron gun was flooding the sample region. When using the electron gun with the ReO4- primary beam, the required electron current was low enough that the EI background was negligible; however, the high electron flood current required with the Cs+ beam produced background EI ions that degraded the quality of the mass spectra. The consequences of the EI produced cations will have to be evaluated on a sample-by-sample basis when using electron flood. It was shown that the electron flood gun could be intentionally operated to produce EI spectra in this instrument. This offers the opportunity to measure, nearly simultaneously, species evaporating from a sample, via EI, and species bound to the surface, via SIMS.

  5. CALIBRATING C-IV-BASED BLACK HOLE MASS ESTIMATORS

    SciTech Connect (OSTI)

    Park, Daeseong; Woo, Jong-Hak; Shin, Jaejin [Astronomy Program, Department of Physics and Astronomy, Seoul National University, Seoul 151-742 (Korea, Republic of); Denney, Kelly D., E-mail: pds2001@astro.snu.ac.kr, E-mail: woo@astro.snu.ac.kr, E-mail: jjshin@astro.snu.ac.kr, E-mail: kelly@dark-cosmology.dk [Dark Cosmology Centre, Niels Bohr Institute, Juliane Maries Vej 30, DK-2100 Copenhagen O (Denmark)

    2013-06-20

    We present the single-epoch black hole mass estimators based on the C IV {lambda}1549 broad emission line, using the updated sample of the reverberation-mapped active galactic nuclei and high-quality UV spectra. By performing multi-component spectral fitting analysis, we measure the C IV line widths (FWHM{sub C{sub IV}} and line dispersion, {sigma}{sub C{sub IV}}) and the continuum luminosity at 1350 A (L{sub 1350}) to calibrate the C-IV-based mass estimators. By comparing with the H{beta} reverberation-based masses, we provide new mass estimators with the best-fit relationships, i.e., M{sub BH}{proportional_to}L{sub 1350}{sup 0.50{+-}0.07}{sigma}{sub C{sub IV}{sup 2}} and M{sub BH}{proportional_to}L{sub 1350}{sup 0.52{+-}0.09} FWHM{sub C{sub IV}{sup 0.56{+-}0.48}}. The new C-IV-based mass estimators show significant mass-dependent systematic difference compared to the estimators commonly used in the literature. Using the published Sloan Digital Sky Survey QSO catalog, we show that the black hole mass of high-redshift QSOs decreases on average by {approx}0.25 dex if our recipe is adopted.

  6. Enzyme Nanoparticles-Based Electronic Biosensor

    SciTech Connect (OSTI)

    Liu, Guodong; Lin, Yuehe; Ostatna, V.; Wang, Joseph

    2005-06-28

    A novel method for fabricating electronic biosensors based on coupling enzyme nanoparticles and self assembly technology is illustrated. Redox horseradish peroxidase nanoparticles were prepared by desolvation with ethanol and subsequent crosslinking with glutaraldehyde. The cross-linked enzyme nanoparticles were functionalized by cysteine to introduce thiol groups on the nanoparticle surface. Immobilized enzyme nanoparticle on the gold electrode by self-assembly kept redox and electrocatalytic activities, and was used to develop reagentless biosensors for H2O2 detection without promoters and mediators. The new approach is simple, low cost and circumvents complications associated with solution systems. It is a universal immobilization method for biosensor, biomedical devices, biofuel cells and enzymatic bioreactors fabrication and expected to open new opportunities for biosensor, clinical diagnostics, and for bioanalysis, in general.

  7. Kinetic electron and ion instability of the lunar wake simulated at physical mass ratio

    SciTech Connect (OSTI)

    Haakonsen, Christian Bernt Hutchinson, Ian H. Zhou, Chuteng

    2015-03-15

    The solar wind wake behind the moon is studied with 1D electrostatic particle-in-cell (PIC) simulations using a physical ion to electron mass ratio (unlike prior investigations); the simulations also apply more generally to supersonic flow of dense magnetized plasma past non-magnetic objects. A hybrid electrostatic Boltzmann electron treatment is first used to investigate the ion stability in the absence of kinetic electron effects, showing that the ions are two-stream unstable for downstream wake distances (in lunar radii) greater than about three times the solar wind Mach number. Simulations with PIC electrons are then used to show that kinetic electron effects can lead to disruption of the ion beams at least three times closer to the moon than in the hybrid simulations. This disruption occurs as the result of a novel wake phenomenon: the non-linear growth of electron holes spawned from a narrow dimple in the electron velocity distribution. Most of the holes arising from the dimple are small and quickly leave the wake, approximately following the unperturbed electron phase-space trajectories, but some holes originating near the center of the wake remain and grow large enough to trigger disruption of the ion beams. Non-linear kinetic-electron effects are therefore essential to a comprehensive understanding of the 1D electrostatic stability of such wakes, and possible observational signatures in ARTEMIS data from the lunar wake are discussed.

  8. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    which prevents two electrons from occupying the same site, resulting in a so-called Mott insulator. The lack of information on the strength of electron correlation in the iron...

  9. Mass spectrometer with electron source for reducing space charge effects in sample beam

    DOE Patents [OSTI]

    Houk, Robert S.; Praphairaksit, Narong

    2003-10-14

    A mass spectrometer includes an ion source which generates a beam including positive ions, a sampling interface which extracts a portion of the beam from the ion source to form a sample beam that travels along a path and has an excess of positive ions over at least part of the path, thereby causing space charge effects to occur in the sample beam due to the excess of positive ions in the sample beam, an electron source which adds electrons to the sample beam to reduce space charge repulsion between the positive ions in the sample beam, thereby reducing the space charge effects in the sample beam and producing a sample beam having reduced space charge effects, and a mass analyzer which analyzes the sample beam having reduced space charge effects.

  10. Electron impact and chemical ionization mass spectral analysis of a volatile uranyl derivative

    SciTech Connect (OSTI)

    Reutter, D.J.; Hardy, D.R.

    1981-01-01

    Quadrupole mass spectral analysis of the volatile uranium ligand complex bis (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato) dioxouranium-di-n-butyl sulfoxide is described utilizing electron impact (EI) and methane chemical ionization (CI) ion sources. All major ions are tentatively identified and the potential usefulness of this complex for determining uranium isotope /sup 235/U//sup 238/U abundance is demonstrated.

  11. OBSERVATION OF HEATING BY FLARE-ACCELERATED ELECTRONS IN A SOLAR CORONAL MASS EJECTION

    SciTech Connect (OSTI)

    Glesener, Lindsay; Bain, Hazel M.; Krucker, Sm; Lin, Robert P.

    2013-12-20

    We report a Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) observation of flare-accelerated electrons in the core of a coronal mass ejection (CME) and examine their role in heating the CME. Previous CME observations have revealed remarkably high thermal energies that can far surpass the CME's kinetic energy. A joint observation by RHESSI and the Atmospheric Imaging Assembly of a partly occulted flare on 2010 November 3 allows us to test the hypothesis that this excess energy is collisionally deposited by flare-accelerated electrons. Extreme ultraviolet (EUV) images show an ejection forming the CME core and sheath, with isothermal multifilter analysis revealing temperatures of ?11MK in the core. RHESSI images reveal a large (?100 50 arcsec{sup 2}) hard X-ray (HXR) source matching the location, shape, and evolution of the EUV plasma, indicating that the emerging CME is filled with flare-accelerated electrons. The time derivative of the EUV emission matches the HXR light curve (similar to the Neupert effect observed in soft and HXR time profiles), directly linking the CME temperature increase with the nonthermal electron energy loss, while HXR spectroscopy demonstrates that the nonthermal electrons contain enough energy to heat the CME. This is the most direct observation to date of flare-accelerated electrons heating a CME, emphasizing the close relationship of the two in solar eruptive events.

  12. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mechanism of superconductivity in the copper-based "high-temperature superconductors." ... for the famous copper-based "high-temperature superconductors," also known as cuprates. ...

  13. Tests of time independence of the electron and nuclear masses with ultracold molecules

    SciTech Connect (OSTI)

    Schiller, S.; Korobov, V.

    2005-03-01

    We propose to use laser spectroscopy of ultracold molecules to establish improved limits on the time independence of electron-to-nuclear and nuclear-nuclear mass ratios by comparing, via an optical frequency comb, the frequencies of suitable sets of transitions in the ground electronic state. Hydrogen molecular ions trapped in a radiofrequency trap, sympathetically cooled by atomic ions, are identified as an accessible system. We show that the dipole-allowed rovibrational transition frequencies of HD{sup +} are suitable probes for a time dependence of m{sub e}/m{sub p} or m{sub p}/m{sub d}. Separate bounds on the time independence of these constants can be obtained from a comparison of HD{sup +} and H{sub 2}{sup +} transitions frequencies. Spectroscopy of single molecular ions via a quantum jump method is proposed as an approach toward ultrahigh precision.

  14. Electron impact action spectroscopy of mass/charge selected macromolecular ions: Inner-shell excitation of ubiquitin protein

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rankovic, Milos Lj.; Giuliani, Alexandre; Milosavljevic, Aleksandar R.

    2016-02-11

    In this study, we have performed inner-shell electron impact action spectroscopy of mass and charge selected macromolecular ions. For this purpose, we have coupled a focusing electron gun with a linear quadrupole ion trap mass spectrometer. This experiment represents a proof of principle that an energy-tunable electron beam can be used in combination with radio frequency traps as an activation method in tandem mass spectrometry (MS2) and allows performing action spectroscopy. Electron impact MS2 spectra of multiply protonated ubiquitin protein ion have been recorded at incident electron energies around the carbon 1s excitation. Both MS2 and single ionization energy dependencemore » spectra are compared with literature data obtained using the soft X-ray activation conditions.« less

  15. Initial experimental test of a helicon plasma based mass filter

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gueroult, R.; Evans, E. S.; Zweben, S. J.; Fisch, N. J.; Levinton, F.

    2016-05-12

    High throughput plasma mass separation requires rotation control in a high density multi-species plasmas. A preliminary mass separation device based on a helicon plasma operating in gas mixtures and featuring concentric biasable ring electrodes is introduced. Plasma profile shows strong response to electrode biasing. In light of floating potential measurements, the density response is interpreted as the consequence of a reshaping of the radial electric field in the plasma. This field can be made confining or de-confining depending on the imposed potential at the electrodes, in a way which is consistent with single particle orbit radial stability. In conclusion, concurrentmore » spatially resolved spectroscopic measurements suggest ion separation, with heavy to light ion emission line ratio increasing with radius when a specific potential gradient is applied to the electrodes.« less

  16. Electronic Structure Based Discovery of Hybrid Photovoltaic Materials on

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next-Generation HPC Platforms | Argonne Leadership Computing Facility Electronic Structure Based Discovery of Hybrid Photovoltaic Materials on Next-Generation HPC Platforms PI Name: Volker Blum PI Email: volker.blum@duke.edu Institution: Duke University Allocation Program: ESP Year: 2015 Research Domain: Materials Science Tier 2 Code Development Project Numerical Methods/Algorithms The FHI-aims all-electron electronic structure code is a well-established, accurate framework for large-scale

  17. Electron Correlation in Iron-Based Superconductors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to wonder if studying the new materials will help uncover one of the deepest mysteries in modern physics-the mechanism of superconductivity in the copper-based "high-temperature...

  18. Direct determination of the electron effective mass of GaAsN by terahertz cyclotron resonance spectroscopy

    SciTech Connect (OSTI)

    Eßer, F.; Helm, M.; Drachenko, O.; Winnerl, S.; Schneider, H.; Patanè, A.; Ozerov, M.

    2015-08-10

    We use cyclotron resonance THz-spectroscopy in pulsed magnetic fields up to 63 T to measure the electron effective mass in Si-doped GaAsN semiconductor alloys with nitrogen content up to 0.2%. This technique directly probes the transport properties of the N-modified conduction band, particularly the electron effective mass, which has been discussed controversially in the experimental and theoretical literature. We report a slight increase of the electron effective mass and nonparabolicity with N-content for different photon energies in agreement with the two-level band anticrossing model calculations. Furthermore, we show a pronounced electron mobility drop with increasing N-content.

  19. Controlled cooling of an electronic system based on projected conditions

    DOE Patents [OSTI]

    David, Milnes P.; Iyengar, Madhusudan K.; Schmidt, Roger R.

    2015-08-18

    Energy efficient control of a cooling system cooling an electronic system is provided based, in part, on projected conditions. The control includes automatically determining an adjusted control setting(s) for an adjustable cooling component(s) of the cooling system. The automatically determining is based, at least in part, on projected power consumed by the electronic system at a future time and projected temperature at the future time of a heat sink to which heat extracted is rejected. The automatically determining operates to reduce power consumption of the cooling system and/or the electronic system while ensuring that at least one targeted temperature associated with the cooling system or the electronic system is within a desired range. The automatically determining may be based, at least in part, on an experimentally obtained model(s) relating the targeted temperature and power consumption of the adjustable cooling component(s) of the cooling system.

  20. Controlled cooling of an electronic system based on projected conditions

    DOE Patents [OSTI]

    David, Milnes P.; Iyengar, Madhusudan K.; Schmidt, Roger R.

    2016-05-17

    Energy efficient control of a cooling system cooling an electronic system is provided based, in part, on projected conditions. The control includes automatically determining an adjusted control setting(s) for an adjustable cooling component(s) of the cooling system. The automatically determining is based, at least in part, on projected power consumed by the electronic system at a future time and projected temperature at the future time of a heat sink to which heat extracted is rejected. The automatically determining operates to reduce power consumption of the cooling system and/or the electronic system while ensuring that at least one targeted temperature associated with the cooling system or the electronic system is within a desired range. The automatically determining may be based, at least in part, on an experimentally obtained model(s) relating the targeted temperature and power consumption of the adjustable cooling component(s) of the cooling system.

  1. Conversion of experimental half-life to effective electron neutrino mass in 0nubetabeta decay

    SciTech Connect (OSTI)

    Smolnikov, Anatoly; Grabmayr, Peter [Joint Institute for Nuclear Research, Dubna, Russia, and Institute for Nuclear Research of the Russian Academy of Sciences, Moscow (Russian Federation); Kepler Center for Astro and Particle Physics, Eberhard Karls Universitaet Tuebingen (Germany)

    2010-02-15

    The Germanium Detector Array (GERDA) collaboration will be searching for neutrinoless double beta decay of {sup 76}Ge. As a result it will measure the half-life T{sub 1/2} of this rare process; or at least a new value for the lower limit for T{sub 1/2} will be derived. The sensitivity of the GERDA experiment on the effective electron neutrino mass depends on the theoretical value for the nuclear matrix element M and the kinematical phase space factor G.In this Brief Report we focus on existing difficulties in applying the dimensionless values of M calculated by various theoretical groups, which use different methods and parametrizations. The implicit radius dependencies in M and G are discussed. Resulting values of the neutrino mass are tabulated for various representative half-lives T{sub 1/2} representing the sensitivity of the various phases of the GERDA experiment.

  2. Semiconductor-based, large-area, flexible, electronic devices

    DOE Patents [OSTI]

    Goyal, Amit

    2011-03-15

    Novel articles and methods to fabricate the same resulting in flexible, large-area, triaxially textured, single-crystal or single-crystal-like, semiconductor-based, electronic devices are disclosed. Potential applications of resulting articles are in areas of photovoltaic devices, flat-panel displays, thermophotovoltaic devices, ferroelectric devices, light emitting diode devices, computer hard disc drive devices, magnetoresistance based devices, photoluminescence based devices, non-volatile memory devices, dielectric devices, thermoelectric devices and quantum dot laser devices.

  3. Vibration isolation based on mass coupling by gear system

    SciTech Connect (OSTI)

    Akbar, S.; Esat, I.I.

    1996-12-31

    This paper investigates the idea of vibration control through mass coupling and demonstrates this with a simple three mass system coupled together by a gear roller system. The coupling between masses introduces off diagonal terms in the mass matrix. These additional terms are variables and may be utilized in such a way as to eliminate relevant elements of the frequency matrix to obtain zero displacement at the operating frequency. This new found ability for control of non-diagonal elements through the use of a mass coupling therefore forms the back bone of this procedure. The procedure is used to isolate the system at typical operating frequencies by the using the parameters of the gear mechanism. The results showed that such a method can be successful for isolation and the introduction of damping on the system increased the range over which isolation occurred.

  4. Multifunctional bulk plasma source based on discharge with electron injection

    SciTech Connect (OSTI)

    Klimov, A. S.; Medovnik, A. V.; Tyunkov, A. V.; Savkin, K. P.; Shandrikov, M. V.; Vizir, A. V.

    2013-01-15

    A bulk plasma source, based on a high-current dc glow discharge with electron injection, is described. Electron injection and some special design features of the plasma arc emitter provide a plasma source with very long periods between maintenance down-times and a long overall lifetime. The source uses a sectioned sputter-electrode array with six individual sputter targets, each of which can be independently biased. This discharge assembly configuration provides multifunctional operation, including plasma generation from different gases (argon, nitrogen, oxygen, acetylene) and deposition of composite metal nitride and oxide coatings.

  5. An Optimized Informatics Pipeline for Mass Spectrometry-Based Peptidomics

    SciTech Connect (OSTI)

    Wu, Chaochao; Monroe, Matthew E.; Xu, Zhe; Slysz, Gordon W.; Payne, Samuel H.; Rodland, Karin D.; Liu, Tao; Smith, Richard D.

    2015-12-26

    Comprehensive MS analysis of peptidome, the intracellular and intercellular products of protein degradation, has the potential to provide novel insights on endogenous proteolytic processing and their utility in disease diagnosis and prognosis. Along with the advances in MS instrumentation, a plethora of proteomics data analysis tools have been applied for direct use in peptidomics; however an evaluation of the currently available informatics pipelines for peptidomics data analysis has yet to be reported. In this study, we set off by evaluating the results of several popular MS/MS database search engines including MS-GF+, SEQUEST and MS-Align+ for peptidomics data analysis, followed by identification and label-free quantification using the well-established accurate mass and time (AMT) tag and newly developed informed quantification (IQ) approaches, both based on direct LC-MS analysis. Our result demonstrated that MS-GF+ outperformed both SEQUEST and MS-Align+ in identifying peptidome peptides. Using a database established from the MS-GF+ peptide identifications, both the AMT tag and IQ approaches provided significantly deeper peptidome coverage and less missing value for each individual data set than the MS/MS methods, while achieving robust label-free quantification. Besides having an excellent correlation with the AMT tag quantification results, IQ also provided slightly higher peptidome coverage than AMT. Taken together, we propose an optimal informatics pipeline combining MS-GF+ for initial database searching with IQ (or AMT) for identification and label-free quantification for high-throughput, comprehensive and quantitative peptidomics analysis.

  6. Electron-doping of graphene-based devices by hydrazine

    SciTech Connect (OSTI)

    Feng, Tingting; Xie, Dan; Wang, Dongxia; Wen, Lang; Wu, Mengqiang

    2014-12-14

    A facile and effective technique to tune the electronic properties of graphene is essential to facilitate the flexibility of graphene-based device performances. Here, the use of hydrazine as a solution-processable and effective n-type dopant for graphene is described. By dropping hydrazine solutions at different concentrations on a graphene surface, the Dirac point of graphene can be remarkably tuned. The transport behavior of graphene can be changed from p-type to n-type accordingly, demonstrating the controllable and adjustable doping effect of the hydrazine solutions. Accompanying the Dirac point shift is an enhanced hysteretic behavior of the graphene conductance, indicating an increasing trap state density induced by the hydrazine adsorbates. The electron-doping of graphene by the hydrazine solutions can be additionally confirmed with graphene/p-type silicon heterojunctions. The decrease of the junction current after the hydrazine treatment demonstrates an increase of the junction barrier between graphene and silicon, which is essentially due to the electron-doping of graphene and the resultant upshift of the Fermi level. Finally, partially doped graphene is realized and its electrical property is studied to demonstrate the potential of the hydrazine solutions to selectively electron-doping graphene for future electronic applications.

  7. Accelerator physics in ERL based polarized electron ion collider

    SciTech Connect (OSTI)

    Hao, Yue

    2015-05-03

    This talk will present the current accelerator physics challenges and solutions in designing ERL-based polarized electron-hadron colliders, and illustrate them with examples from eRHIC and LHeC designs. These challenges include multi-pass ERL design, highly HOM-damped SRF linacs, cost effective FFAG arcs, suppression of kink instability due to beam-beam effect, and control of ion accumulation and fast ion instabilities.

  8. The VME-based D0 muon trigger electronics

    SciTech Connect (OSTI)

    Fortner, M; Green, J; Hedin, D; Morphis, R; Repond, S; Willis, S; Zazula, R; Johns, K; Bazizi, K; Fahland, T; Hall, R E; Jerger, S; Lietzke, C; Smith, D; Butler, J M; Diehl, H T; Eartly, D; Fitzpatrick, T; Green, D; Haggerty, H; Hansen, S; Hawkins, J; Igarashi, S; Joestlein, H

    1990-11-01

    The trigger electronics for the muon system of the Fermilab D0 detector is described. The hardware trigger consists of VME-based cards designed to find probable tracks in individual chambers and then match these track segments. The fast trigger is highly parallel and able to discern probable tracks from about 15,000 trigger cells in under 200 ns from receipt of all bits in the counting house. There is a parallel confirmation trigger with a response time of 1--5 microseconds that provides a crude calculation of the momentum and charge of the muon. 6 refs., 7 figs.

  9. High-temperature superconducting thin-film-based electronic devices

    SciTech Connect (OSTI)

    Wu, X.D; Finokoglu, A.; Hawley, M.; Jia, Q.; Mitchell, T.; Mueller, F.; Reagor, D.; Tesmer, J.

    1996-09-01

    This the final report of a one-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The project involved optimization of processing of Y123 and Tl-2212 thin films deposited on novel substrates for advanced electronic devices. The Y123 films are the basis for development of Josephson Junctions to be utilized in magnetic sensors. Microwave cavities based on the Tl-2212 films are the basis for subsequent applications as communication antennas and transmitters in satellites.

  10. High-efficiency cross-beam magnetic electron-impact source for improved miniature Mattauch-Herzog mass spectrometer performance

    SciTech Connect (OSTI)

    Hadjar, O.; Fowler, W. K.

    2012-06-15

    We describe a newly designed cross-beam magnetic electron-impact ion source (CBM-EI). We demonstrate its superiority in comparison with a conventional source (CB-EI) when used with a commercial miniature sector-field-type, non-scanning mass spectrometer featuring Mattauch-Herzog geometry (MH-MS) and a permanent sector-field magnet. This paper clearly shows the value of the CBM-EI for enhancing MH-MS sensitivity. Unlike secondary electron-multiplier type detectors, the pixelated detector (IonCCD Trade-Mark-Sign ) used in the commercial MH-MS has no gain. The MH-MS/IonCCD system is therefore challenged to compete with time-of-flight and quadrupole MS systems due to their higher ion transmissions and detector gains. Using the new CBM-EI, we demonstrate an instrument sensitivity increase of 20-fold to 100-fold relative to the CB-EI-equipped instrument. This remarkable signal increase by the simple addition of the magnet assembly arises from the magnet-induced gyromotion of the thermionic electrons, which vastly increases the effective path length of the electrons through the ionization region, and the collimated nature of the electron flux, which optimizes the ion transmission through the 100-{mu}m object slit of the MH-MS. Some or all of the realized sensitivity increase may be exchanged for an increase in resolution and/or mass range through the use of a narrower object slit, or for a reduction in ion-source pressure to limit quenching. The CBM-EI should facilitate development of a differentially pumped ion source to extend the lifetime of the filament, especially in otherwise intractable applications associated with oxidizing and corrosive samples.

  11. A reliability and mass perspective of SP-100 Stirling cycle lunar-base powerplant designs

    SciTech Connect (OSTI)

    Bloomfield, H.S.

    1991-06-01

    The purpose was to obtain reliability and mass perspectives on selection of space power system conceptual designs based on SP-100 reactor and Stirling cycle power-generation subsystems. The approach taken was to: (1) develop a criterion for an acceptable overall reliability risk as a function of the expected range of emerging technology subsystem unit reliabilities; (2) conduct reliability and mass analyses for a diverse matrix of 800-kWe lunar-base design configurations employing single and multiple powerplants with both full and partial subsystem redundancy combinations; and (3) derive reliability and mass perspectives on selection of conceptual design configurations that meet an acceptable reliability criterion with the minimum system mass increase relative to reference powerplant design. The developed perspectives provided valuable insight into the considerations required to identify and characterize high-reliability and low-mass lunar-base powerplant conceptual design.

  12. Multilevel learning-based segmentation of ill-defined and spiculated masses in mammograms

    SciTech Connect (OSTI)

    Tao, Yimo; Lo, Shih-Chung B.; Freedman, Matthew T.; Makariou, Erini; Xuan, Jianhua

    2010-11-15

    Purpose: A learning-based approach integrating the use of pixel-level statistical modeling and spiculation detection is presented for the segmentation of mammographic masses with ill-defined margins and spiculations. Methods: The algorithm involves a multiphase pixel-level classification, using a comprehensive group of features computed from regional intensity, shape, and textures, to generate a mass-conditional probability map (PM). Then, the mass candidate, along with the background clutters consisting of breast fibroglandular and other nonmass tissues, is extracted from the PM by integrating the prior knowledge of shape and location of masses. A multiscale steerable ridge detection algorithm is employed to detect spiculations. Finally, all the object-level findings, including mass candidate, detected spiculations, and clutters, along with the PM, are integrated by graph cuts to generate the final segmentation mask. Results: The method was tested on 54 masses (51 malignant and 3 benign), all with ill-defined margins and irregular shape or spiculations. The ground truth delineations were provided by five experienced radiologists. Area overlapping ratio of 0.689 ({+-}0.160) and 0.540 ({+-}0.164) were obtained for segmenting entire mass and margin portion only, respectively. Williams index of area and contour based measurements indicated that the segmentation results of the algorithm agreed well with the radiologists' delineation. Conclusions: The proposed approach could closely delineate the mass body. Most importantly, it is capable of including mass margin and its spicule extensions which are considered as key features for breast lesion analyses.

  13. An electronic laboratory notebook based on HTML forms

    SciTech Connect (OSTI)

    Marstaller, J.E.; Zorn, M.D.

    1995-10-01

    The electronic notebook records information that has traditionally been kept in handwritten laboratory notebooks. It keeps detailed information about the progress of the research , such as the optimization of primers, the screening of the primers and, finally, the mapping of the probes. The notebook provides two areas of services: Data entry, and reviewing of data in all stages. The World wide Web browsers, with HTML based forms provide a fast and easy mechanism to create forms-based user interfaces. The computer scientist can sit down with the biologist and rapidly make changes in response to the user`s comments. Furthermore the HTML forms work equally well on a number of different hardware platforms; thus the biologists may continue using their Macintosh computers and find a familiar interface if they have to work on a Unix workstation. The web browser can be run from any machine connected to the Internet: thus the users are free to enter or view information even away from their labs at home or while on travel. Access can be restricted by password and other means to secure the confidentiality of the data. A bonus that is hard to implement otherwise is the facile connection to outside resources. Linking local information to data in public databases is only a hypertext link away with little or no additional programming efforts.

  14. Analysis of passivated A-286 stainless steel surfaces for mass spectrometer inlet systems by Auger electron and X-ray photoelectron spectroscopy and scanning electron microscopy

    SciTech Connect (OSTI)

    Ajo, Henry; Blankenship, Donnie; Clark, Elliot

    2014-07-25

    In this study, various commercially available surface treatments are being explored for use on stainless steel components in mass spectrometer inlet systems. Type A-286 stainless steel coupons, approximately 12.5 mm in diameter and 3 mm thick, were passivated with one of five different surface treatments; an untreated coupon served as a control. The surface and near-surface microstructure and chemistry of the coupons were investigated using sputter depth profiling using Auger electron spectroscopy, x-ray photoelectron spectroscopy, and scanning electron microscopy (SEM). All the surface treatments studied appeared to change the surface morphology dramatically, as evidenced by lack of tool marks on the treated samples in SEM images. In terms of the passivation treatment, Vendors A-D appeared to have oxide layers that were very similar in thickness to each other (0.7–0.9 nm thick), as well as to the untreated samples (the untreated sample oxide layers appeared to be somewhat larger). Vendor E’s silicon coating appears to be on the order of 200 nm thick.

  15. Analysis of passivated A-286 stainless steel surfaces for mass spectrometer inlet systems by Auger electron and X-ray photoelectron spectroscopy and scanning electron microscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ajo, Henry; Blankenship, Donnie; Clark, Elliot

    2014-07-25

    In this study, various commercially available surface treatments are being explored for use on stainless steel components in mass spectrometer inlet systems. Type A-286 stainless steel coupons, approximately 12.5 mm in diameter and 3 mm thick, were passivated with one of five different surface treatments; an untreated coupon served as a control. The surface and near-surface microstructure and chemistry of the coupons were investigated using sputter depth profiling using Auger electron spectroscopy, x-ray photoelectron spectroscopy, and scanning electron microscopy (SEM). All the surface treatments studied appeared to change the surface morphology dramatically, as evidenced by lack of tool marks onmore » the treated samples in SEM images. In terms of the passivation treatment, Vendors A-D appeared to have oxide layers that were very similar in thickness to each other (0.7–0.9 nm thick), as well as to the untreated samples (the untreated sample oxide layers appeared to be somewhat larger). Vendor E’s silicon coating appears to be on the order of 200 nm thick.« less

  16. IDENTIFICATION OF STAPHYLOCOCCAL SPECIES BASED ON VARIATIONS IN PROTEIN SEQUENCES (MASS SPECTROMETRY) AND DNA SEQUENCE (sodA MICROARRAY)

    SciTech Connect (OSTI)

    Kooken, Jennifer M.; Fox, Karen F.; Fox, Alvin; Altomare, Diego; Creek, Kim E.; Wunschel, David S.; Pajares-Merino, Sara; Martinez-Ballesteros, Ilargi; Garaizar, Javier; Oyarzabal, Omar A.; Samadpour, Mansour

    2014-02-03

    IDENTIFICATION OF STAPHYLOCOCCAL SPECIES BASED ON VARIATIONS IN PROTEIN SEQUENCES (MASS SPECTROMETRY) AND DNA SEQUENCE (sodA MICROARRAY)

  17. Invited Article: Characterization of background sources in space-based time-of-flight mass spectrometers

    SciTech Connect (OSTI)

    Gilbert, J. A.; Gershman, D. J.; Gloeckler, G.; Lundgren, R. A.; Zurbuchen, T. H.; Orlando, T. M.; McLain, J.; Steiger, R. von

    2014-09-15

    For instruments that use time-of-flight techniques to measure space plasma, there are common sources of background signals that evidence themselves in the data. The background from these sources may increase the complexity of data analysis and reduce the signal-to-noise response of the instrument, thereby diminishing the science value or usefulness of the data. This paper reviews several sources of background commonly found in time-of-flight mass spectrometers and illustrates their effect in actual data using examples from ACE-SWICS and MESSENGER-FIPS. Sources include penetrating particles and radiation, UV photons, energy straggling and angular scattering, electron stimulated desorption of ions, ion-induced electron emission, accidental coincidence events, and noise signatures from instrument electronics. Data signatures of these sources are shown, as well as mitigation strategies and design considerations for future instruments.

  18. Electronic desalting for controlling the ionic environment in droplet-based biosensing platforms

    SciTech Connect (OSTI)

    Swaminathan, Vikhram Vilasur; Dak, Piyush; Alam, Muhammad A. E-mail: alam@purdue.edu; Reddy, Bobby; Duarte-Guevara, Carlos; Zhong, Yu; Salm, Eric; Fischer, Andrew; Bashir, Rashid E-mail: alam@purdue.edu

    2015-02-02

    The ability to control the ionic environment in saline waters and aqueous electrolytes is useful for desalination as well as electronic biosensing. We demonstrate a method of electronic desalting at micro-scale through on-chip micro electrodes. We show that, while desalting is limited in bulk solutions with unlimited availability of salts, significant desalting of ≥1 mM solutions can be achieved in sub-nanoliter volume droplets with diameters of ∼250 μm. Within these droplets, by using platinum-black microelectrodes and electrochemical surface treatments, we can enhance the electrode surface area to achieve >99% and 41% salt removal in 1 mM and 10 mM salt concentrations, respectively. Through self-consistent simulations and experimental measurements, we demonstrate that conventional double-layer theory over-predicts the desalting capacity and, hence, cannot be used to model systems that are mass limited or undergoing significant salt removal from the bulk. Our results will provide a better understanding of capacitive desalination, as well as a method for salt manipulation in high-throughput droplet-based microfluidic sensing platforms.

  19. Electron Charged Graphite-based Hydrogen Storage Material

    SciTech Connect (OSTI)

    Dr. Chinbay Q. Fan R&D Manager Office of Technology and Innovations Phone: 847 768 0812

    2012-03-14

    The electron-charge effects have been demonstrated to enhance hydrogen storage capacity using materials which have inherent hydrogen storage capacities. A charge control agent (CCA) or a charge transfer agent (CTA) was applied to the hydrogen storage material to reduce internal discharge between particles in a Sievert volumetric test device. GTI has tested the device under (1) electrostatic charge mode; (2) ultra-capacitor mode; and (3) metal-hydride mode. GTI has also analyzed the charge distribution on storage materials. The charge control agent and charge transfer agent are needed to prevent internal charge leaks so that the hydrogen atoms can stay on the storage material. GTI has analyzed the hydrogen fueling tank structure, which contains an air or liquid heat exchange framework. The cooling structure is needed for hydrogen fueling/releasing. We found that the cooling structure could be used as electron-charged electrodes, which will exhibit a very uniform charge distribution (because the cooling system needs to remove heat uniformly). Therefore, the electron-charge concept does not have any burden of cost and weight for the hydrogen storage tank system. The energy consumption for the electron-charge enhancement method is quite low or omitted for electrostatic mode and ultra-capacitor mode in comparison of other hydrogen storage methods; however, it could be high for the battery mode.

  20. Sensitivity of transitions in internal rotor molecules to a possible variation of the proton-to-electron mass ratio

    SciTech Connect (OSTI)

    Jansen, Paul; Ubachs, Wim; Bethlem, Hendrick L.; Kleiner, Isabelle; Xu, Li-Hong

    2011-12-15

    Recently, methanol was identified as a sensitive target system to probe variations of the proton-to-electron mass ratio {mu}[Jansen et al., Phys. Rev. Lett. 106, 100801 (2011)]. The high sensitivity of methanol originates from the interplay between overall rotation and hindered internal rotation of the molecule; that is, transitions that convert internal rotation energy into overall rotation energy, or vice versa, have an enhanced sensitivity coefficient, K{sub {mu}}. As internal rotation is a common phenomenon in polyatomic molecules, it is likely that other molecules display similar or even larger effects. In this paper we generalize the concepts that form the foundation of the high sensitivity in methanol and use this to construct an approximate model which makes it possible to estimate the sensitivities of transitions in internal rotor molecules with C{sub 3v} symmetry, without performing a full calculation of energy levels. We find that a reliable estimate of transition sensitivities can be obtained from the three rotational constants (A, B, and C) and three torsional constants (F, V{sub 3}, and {rho}). This model is verified by comparing obtained sensitivities for methanol, acetaldehyde, acetamide, methyl formate, and acetic acid with a full analysis of the molecular Hamiltonian. Of the molecules considered, methanol is by far the most suitable candidate for laboratory and cosmological tests searching for a possible variation of {mu}.

  1. FIRST COSMOLOGICAL CONSTRAINTS ON THE PROTON-TO-ELECTRON MASS RATIO FROM OBSERVATIONS OF ROTATIONAL TRANSITIONS OF METHANOL

    SciTech Connect (OSTI)

    Ellingsen, S. P.; Lovell, J. E. J.; Voronkov, M. A.; Breen, S. L.

    2012-03-15

    We have used the Australia Telescope Compact Array to measure the absorption from the 2{sub 0} {yields} 3{sub -1} E 12.2 GHz transition of methanol toward the z = 0.89 lensing galaxy in the PKS B1830-211 gravitational lens system. Comparison of the velocity of the main absorption feature with the published absorption spectrum from the 1{sub 0} {yields} 2{sub -1} E transition of methanol shows that they differ by -0.6 {+-} 1.6 km s{sup -1}. We can use these observations to constrain the changes in the proton-to-electron mass ratio {mu} from z = 0.89 to the present to 0.8 {+-} 2.1 Multiplication-Sign 10{sup -7}. This result is consistent, and of similar precision to recent observations at z = 0.68 achieved through comparison of a variety of rotational and inversion transitions, and approximately a factor of two better than previous constraints obtained in this source. Future more sensitive observations that incorporate additional rotational methanol transitions offer the prospect of improving current results by a factor of 5-10.

  2. Electron effective mass in Al{sub 0.72}Ga{sub 0.28}N alloys determined by mid-infrared optical Hall effect

    SciTech Connect (OSTI)

    Schöche, S. Kühne, P.; Hofmann, T.; Schubert, M.; Nilsson, D.; Kakanakova-Georgieva, A.; Janzén, E.; Darakchieva, V.

    2013-11-18

    The effective electron mass parameter in Si-doped Al{sub 0.72}Ga{sub 0.28}N is determined to be m{sup ∗}=(0.336±0.020) m{sub 0} from mid-infrared optical Hall effect measurements. No significant anisotropy of the effective electron mass parameter is found supporting theoretical predictions. Assuming a linear change of the effective electron mass with the Al content in AlGaN alloys and m{sup ∗}=0.232 m{sub 0} for GaN, an average effective electron mass of m{sup ∗}=0.376 m{sub 0} can be extrapolated for AlN. The analysis of mid-infrared spectroscopic ellipsometry measurements further confirms the two phonon mode behavior of the E{sub 1}(TO) and one phonon mode behavior of the A{sub 1}(LO) phonon mode in high-Al-content AlGaN alloys as seen in previous Raman scattering studies.

  3. Electron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    density measurement by differential interferometry W. X. Ding, D. L. Brower, B. H. Deng, and T. Yates Electrical Engineering Department, University of California-Los Angeles, Los Angeles, California 90095 ͑Received 5 May 2006; presented on 10 May 2006; accepted 16 June 2006; published online 26 September 2006͒ A novel differential interferometer is being developed to measure the electron density gradient and its fluctuations. Two separate laser beams with slight spatial offset and frequency

  4. Final Technical Report- Back-gate Field Emission-based Cathode RF Electron Gun

    SciTech Connect (OSTI)

    McGuire, Gary; Martin, Allen; Noonan, John

    2010-10-30

    The objective was to complete the design of an electron gun which utilizes a radio frequency (RF) power source to apply a voltage to a field emission (FE) cathode, a so called cold cathode, in order to produce an electron beam. The concept of the RF electron gun was originally conceived at Argonne National Laboratory but never reduced to practice. The research allowed the completion of the design based upon the integration of the FE electron source. Compared to other electron guns, the RF gun is very compact, less than one third the size of other comparable guns, and produces a high energy (to several MeV), high quality, high power electron beam with a long focal length with high repetition rates. The resultant electron gun may be used in welding, materials processing, analytical equipment and waste treatment.

  5. Electron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron thermal transport within magnetic islands in the reversed-field pinch a... H. D. Stephens, 1,b͒ D. J. Den Hartog, 1,3 C. C. Hegna, 1,2 and J. A. Reusch 1 1 Department of Physics, University of Wisconsin-Madison, 1150 University Ave., Madison, Wisconsin 53706, USA 2 Department of Engineering Physics, University of Wisconsin-Madison, 1500 Engineering Drive, Madison, Wisconsin 53706, USA 3 Center for Magnetic Self-Organization in Laboratory and Astrophysical Plasmas, University of

  6. Moving beyond mass-based parameters for conductivity analysis of sulfonated polymers

    SciTech Connect (OSTI)

    Kim, Yu Seung; Pivovar, Bryan

    2009-01-01

    Proton conductivity of polymer electrolytes is critical for fuel cells and has therefore been studied in significant detail. The conductivity of sulfonated polymers has been linked to material characteristics in order to elucidate trends. Mass based measurements based on water uptake and ion exchange capacity are two of the most common material characteristics used to make comparisons between polymer electrolytes, but have significant limitations when correlated to proton conductivity. These limitations arise in part because different polymers can have significantly different densities and conduction happens over length scales more appropriately represented by volume measurements rather than mass. Herein, we establish and review volume related parameters that can be used to compare proton conductivity of different polymer electrolytes. Morphological effects on proton conductivity are also considered. Finally, the impact of these phenomena on designing next generation sulfonated polymers for polymer electrolyte membrane fuel cells is discussed.

  7. Betatron radiation based measurement of the electron-beam size in a wakefield accelerator

    SciTech Connect (OSTI)

    Schnell, Michael; Saevert, Alexander; Reuter, Maria; and others

    2012-07-09

    We present a spatial and spectral characterization of a laser-plasma based betatron source which allows us to determine the betatron oscillation amplitude of the electrons which decreases with increasing electron energies. Due to the observed oscillation amplitude and the independently measured x-ray source size of (1.8{+-}0.3){mu}m we are able to estimate the electron bunch diameter to be (1.6{+-}0.3){mu}m.

  8. Cherenkov Light-based Beam Profiling for Ultrarelativistic Electron...

    Office of Scientific and Technical Information (OSTI)

    We describe a beam profile monitor design based on Cherenkov light emitted from a charged particle beam in an air gap. The main components of the profile monitor are silicon wafers ...

  9. A micro seismometer based on molecular electronic transducer technology for planetary exploration

    SciTech Connect (OSTI)

    Huang, Hai; Tang, Rui; Carande, Bryce; Oiler, Jonathan; Zaitsev, Dmitri; Agafonov, Vadim; Yu, Hongyu; School of Earth and Space Exploration, Arizona State University, Tempe, Arizona 85287

    2013-05-13

    This letter describes an implementation of micromachined seismometer based on molecular electronic transducer (MET) technology. As opposed to a solid inertial mass, MET seismometer senses the movement of liquid electrolyte relative to fixed electrodes. The employment of micro-electro-mechanical systems techniques reduces the internal size of the sensing cell to 1{mu}m and improves the reproducibility of the device. For operating bias of 600 mV, a sensitivity of 809 V/(m/s{sup 2}) was measured under acceleration of 400{mu}g(g{identical_to}9.81m/s{sup 2}) at 0.32 Hz. A -115 dB (relative to (m/s{sup 2})/{radical}(Hz)) noise level at 1 Hz was achieved. This work develops an alternative paradigm of seismic sensing device with small size, high sensitivity, low noise floor, high shock tolerance, and independence of installation angle, which is promising for next generation seismometers for planetary exploration.

  10. Note: Design and development of improved indirectly heated cathode based strip electron gun

    SciTech Connect (OSTI)

    Maiti, Namita; Patil, D. S.; Dasgupta, K.; Bade, Abhijeet; Tembhare, G. U.

    2015-02-15

    An improved design of indirectly heated solid cathode based electron gun (200 kW, 45 kV, 270° bent strip type electron gun) has been presented. The solid cathode is made of thoriated tungsten, which acts as an improved source of electron at lower temperature. So, high power operation is possible without affecting structural integrity of the electron gun. The design issues are addressed based on the uniformity of temperature on the solid cathode and the single long filament based design. The design approach consists of simulation followed by extensive experimentation. In the design, the effort has been put to tailor the non-uniformity of the heat flux from the filament to the solid cathode to obtain better uniformity of temperature on the solid cathode. Trial beam experiments have been carried out and it is seen that the modified design achieves one to one correspondence of the solid cathode length and the electron beam length.

  11. A Hybrid Approach to Protein Differential Expression in Mass Spectrometry-Based Proteomics

    SciTech Connect (OSTI)

    Wang, Xuan; Anderson, Gordon A.; Smith, Richard D.; Dabney, Alan R.

    2012-04-19

    Motivation: Quantitative mass spectrometry-based proteomics involves statistical inference on protein abundance, based on the intensities of each protein's associated spectral peaks. However, typical MS-based proteomics data sets have substantial proportions of missing observations, due at least in part to censoring of low intensities. This complicates intensity-based differential expression analysis. Results: We outline a statistical method for protein differential expression, based on a simple Binomial likelihood. By modeling peak intensities as binary, in terms of 'presence/ absence,' we enable the selection of proteins not typically amendable to quantitative analysis; e.g., 'one-state' proteins that are present in one condition but absent in another. In addition, we present an analysis protocol that combines quantitative and presence/ absence analysis of a given data set in a principled way, resulting in a single list of selected proteins with a single associated FDR.

  12. Mixed ionic-electronic conductor-based radiation detectors and methods of fabrication

    DOE Patents [OSTI]

    Conway, Adam; Beck, Patrick R; Graff, Robert T; Nelson, Art; Nikolic, Rebecca J; Payne, Stephen A; Voss, Lars; Kim, Hadong

    2015-04-07

    A method of fabricating a mixed ionic-electronic conductor (e.g. TlBr)-based radiation detector having halide-treated surfaces and associated methods of fabrication, which controls polarization of the mixed ionic-electronic MIEC material to improve stability and operational lifetime.

  13. Electron beam melting of charge based on titanium sponge

    SciTech Connect (OSTI)

    Tikhonovsky, A.L.; Tikhonovsky, K.A.

    1995-12-31

    An experience of 0.8 MW consumable box melting furnace operation and theoretical simulation have led to the further development of the FIKO plant under construction on the base of melting of two consumable box-like bullets which move opposite each other and form narrow heated space between melted butt ends. It allows to reduce vaporization, spatter and radiation losses by several times and to reach two times increase in melting rate and 99%(97%) yield for c.p. titanium (alloys) without furnace power add. Future furnace design will provide the optimum protection of vacuum pumps against chlorides, the safety when melting titanium sponge and will permit hot ingots to move to the special furnace for EB surface conditioning. The maximum productivity is to be 18,000 t/year. The furnace can be used for the manufacture of aluminum-, copper-, iron-, nickel-, tungsten-based alloys and others of any charge including salvage.

  14. Cherenkov Light-based Beam Profiling for Ultrarelativistic Electron Beams

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Adli, E.; Gessner, S. J.; Corde, S.; Hogan, M. J.; Bjerke, H. H.

    2015-02-09

    We describe a beam profile monitor design based on Cherenkov light emitted from a charged particle beam in an air gap. The main components of the profile monitor are silicon wafers used to reflect Cherenkov light onto a camera lens system. The design allows for measuring large beam sizes, with large photon yield per beam charge and excellent signal linearity with beam charge. Furthermore, the profile monitor signal is independent of the particle energy for ultrarelativistic particles. Different design and parameter considerations are discussed. A Cherenkov light-based profile monitor has been installed at the FACET User Facility at SLAC. Finally,more » we report on the measured performance of this profile monitor.« less

  15. An ANFIS-based on B2C electronic commerce transaction

    SciTech Connect (OSTI)

    Lin, Juan; Liu, Chenlian; Guo, Yongning

    2014-10-06

    The purpose of this study is to use an adaptive-network-based fuzzy inference system to model a fuzzy logic-based system (FIS) for supporting decision-making process in B2C electronic commerce transaction. Firstly we introduce FIS in B2C electronic commerce transaction and ANFIS. Then we use ANFIS to model FIS with different membership functions(MF). Lastly we give a conclusion.

  16. Optically induced transport through semiconductor-based molecular electronics

    SciTech Connect (OSTI)

    Li, Guangqi; Seideman, Tamar; Fainberg, Boris D.

    2015-04-21

    A tight binding model is used to investigate photoinduced tunneling current through a molecular bridge coupled to two semiconductor electrodes. A quantum master equation is developed within a non-Markovian theory based on second-order perturbation theory with respect to the molecule-semiconductor electrode coupling. The spectral functions are generated using a one dimensional alternating bond model, and the coupling between the molecule and the electrodes is expressed through a corresponding correlation function. Since the molecular bridge orbitals are inside the bandgap between the conduction and valence bands, charge carrier tunneling is inhibited in the dark. Subject to the dipole interaction with the laser field, virtual molecular states are generated via the absorption and emission of photons, and new tunneling channels open. Interesting phenomena arising from memory are noted. Such a phenomenon could serve as a switch.

  17. SEM technique for imaging and measuring electronic transport in nanocomposites based on electric field induced contrast

    DOE Patents [OSTI]

    Jesse, Stephen [Knoxville, TN; Geohegan, David B. [Knoxville, TN; Guillorn, Michael [Brooktondale, NY

    2009-02-17

    Methods and apparatus are described for SEM imaging and measuring electronic transport in nanocomposites based on electric field induced contrast. A method includes mounting a sample onto a sample holder, the sample including a sample material; wire bonding leads from the sample holder onto the sample; placing the sample holder in a vacuum chamber of a scanning electron microscope; connecting leads from the sample holder to a power source located outside the vacuum chamber; controlling secondary electron emission from the sample by applying a predetermined voltage to the sample through the leads; and generating an image of the secondary electron emission from the sample. An apparatus includes a sample holder for a scanning electron microscope having an electrical interconnect and leads on top of the sample holder electrically connected to the electrical interconnect; a power source and a controller connected to the electrical interconnect for applying voltage to the sample holder to control the secondary electron emission from a sample mounted on the sample holder; and a computer coupled to a secondary electron detector to generate images of the secondary electron emission from the sample.

  18. Electronically conductive perovskite-based oxide nanoparticles and films for optical sensing applications

    DOE Patents [OSTI]

    Ohodnicki, Jr., Paul R; Schultz, Andrew M

    2015-04-28

    The disclosure relates to a method of detecting a change in a chemical composition by contacting a electronically conducting perovskite-based metal oxide material with a monitored stream, illuminating the electronically conducting perovskite-based metal oxide with incident light, collecting exiting light, monitoring an optical signal based on a comparison of the incident light and the exiting light, and detecting a shift in the optical signal. The electronically conducting perovskite-based metal oxide has a perovskite-based crystal structure and an electronic conductivity of at least 10.sup.-1 S/cm, where parameters are specified at the gas stream temperature. The electronically conducting perovskite-based metal oxide has an empirical formula A.sub.xB.sub.yO.sub.3-.delta., where A is at least a first element at the A-site, B is at least a second element at the B-site, and where 0.8electronically conducting perovskite-based oxides include but are not limited to La.sub.1-xSr.sub.xCoO.sub.3, La.sub.1-xSr.sub.xMnO.sub.3, LaCrO.sub.3, LaNiO.sub.3, La.sub.1-xSr.sub.xMn.sub.1-yCr.sub.yO.sub.3, SrFeO.sub.3, SrVO.sub.3, La-doped SrTiO.sub.3, Nb-doped SrTiO.sub.3, and SrTiO.sub.3-.delta..

  19. Semiconductor-based, large-area, flexible, electronic devices on {110}<100> oriented substrates

    SciTech Connect (OSTI)

    Goyal, Amit

    2014-08-05

    Novel articles and methods to fabricate the same resulting in flexible, oriented, semiconductor-based, electronic devices on {110}<100> textured substrates are disclosed. Potential applications of resulting articles are in areas of photovoltaic devices, flat-panel displays, thermophotovoltaic devices, ferroelectric devices, light emitting diode devices, computer hard disc drive devices, magnetoresistance based devices, photoluminescence based devices, non-volatile memory devices, dielectric devices, thermoelectric devices and quantum dot laser devices.

  20. [100] or [110] aligned, semiconductor-based, large-area, flexible, electronic devices

    SciTech Connect (OSTI)

    Goyal, Amit

    2015-03-24

    Novel articles and methods to fabricate the same resulting in flexible, large-area, [100] or [110] textured, semiconductor-based, electronic devices are disclosed. Potential applications of resulting articles are in areas of photovoltaic devices, flat-panel displays, thermophotovoltaic devices, ferroelectric devices, light emitting diode devices, computer hard disc drive devices, magnetoresistance based devices, photoluminescence based devices, non-volatile memory devices, dielectric devices, thermoelectric devices and quantum dot laser devices.

  1. Search for new physics in high mass electron-positron events in p anti-p collisions at s**(1/2) = 1.96-TeV

    SciTech Connect (OSTI)

    Aaltonen, T.; Abulencia, A.; Adelman, J.; Affolder, Anthony Allen; Akimoto, T.; Albrow, Michael G.; Amerio, S.; Amidei, Dante E.; Anastassov, A.; Anikeev, K.; Annovi, A. /Taiwan, Inst. Phys. /Argonne /Barcelona, IFAE /Baylor U. /INFN, Bologna /Bologna U. /Brandeis U. /UC, Davis /UCLA /UC, San Diego /UC, Santa Barbara

    2007-07-01

    We report the results of a search for a narrow resonance in electron-positron events in the invariant mass range of 150-950 GeV/c{sup 2} using 1.3 fb{sup -1} of p{bar p} collision data at {radical}s=1.96 TeV collected by the CDF II detector at Fermilab. No significant evidence of such a resonance is observed and we interpret the results to exclude the standard model-like Z{prime} with a mass below 923 GeV/c{sup 2} and the Randall-Sundrum graviton with a mass below 807 GeV/c{sup 2} for k/{bar M}{sub pl} = 0.1, both at the 95% confidence level. Combining with di-photon data excludes the Randall-Sundrum graviton for masses below 889 GeV/c{sup 2} for k/{bar M}{sub pl} = 0.1

  2. Membrane-Based Emitter for Coupling Microfluidics with Ultrasensitive Nanoelectrospray Ionization-Mass Spectrometry

    SciTech Connect (OSTI)

    Sun, Xuefei; Kelly, Ryan T.; Tang, Keqi; Smith, Richard D.

    2011-06-09

    An integrated poly(dimethylsiloxane) (PDMS) membrane-based microfluidic emitter for high performance nanoelectrospray ionization-mass spectrometry (nanoESI-MS) has been fabricated and evaluated. The ~100-?m-thick emitter was created by cutting a PDMS membrane that protrudes beyond the bulk substrate. The reduced surface area at the emitter enhances the electric field and reduces wetting of the surface by the electrospray solvent. As such, the emitter provides highly stable electrospray at flow rates as low as 10 nL/min, and is compatible with electrospray solvents containing a large organic component (e.g., 90% methanol). This approach enables facile emitter construction, and provides excellent stability, reproducibility and sensitivity, as well as compatibility with multilayer soft lithography.

  3. Design of a proton-electron beam overlap monitor for the new RHIC electron lens, based on detecting energetic backscattered electrons

    SciTech Connect (OSTI)

    Thieberger T.; Beebe, E.; Fischer, W.; Gassner, D.; Gu, X.; Hamdi, K.; Hock, J.; Minty, M.; Miller, T.; Montag, C.; Pikin, A.

    2012-04-15

    The optimal performance of the two electron lenses that are being implemented for high intensity polarized proton operation of RHIC requires excellent collinearity of the {approx}0.3 mm RMS wide electron beams with the proton bunch trajectories over the {approx}2m interaction lengths. The main beam overlap diagnostic tool will make use of electrons backscattered in close encounters with the relativistic protons. These electrons will spiral along the electron guiding magnetic field and will be detected in a plastic scintillator located close to the electron gun. A fraction of these electrons will have energies high enough to emerge from the vacuum chamber through a thin window thus simplifying the design and operation of the detector. The intensity of the detected electrons provides a measure of the overlap between the e- and the opposing proton beams. Joint electron arrival time and energy discrimination may be used additionally to gain some longitudinal position information with a single detector per lens.

  4. Structural Analysis of a Highly Glycosylated and Unliganded gp120-Based Antigen Using Mass Spectrometry

    SciTech Connect (OSTI)

    L Wang; Y Qin; S Ilchenko; J Bohon; W Shi; M Cho; K Takamoto; M Chance

    2011-12-31

    Structural characterization of the HIV-1 envelope protein gp120 is very important for providing an understanding of the protein's immunogenicity and its binding to cell receptors. So far, the crystallographic structure of gp120 with an intact V3 loop (in the absence of a CD4 coreceptor or antibody) has not been determined. The third variable region (V3) of the gp120 is immunodominant and contains glycosylation signatures that are essential for coreceptor binding and entry of the virus into T-cells. In this study, we characterized the structure of the outer domain of gp120 with an intact V3 loop (gp120-OD8) purified from Drosophila S2 cells utilizing mass spectrometry-based approaches. We mapped the glycosylation sites and calculated the glycosylation occupancy of gp120-OD8; 11 sites from 15 glycosylation motifs were determined as having high-mannose or hybrid glycosylation structures. The specific glycan moieties of nine glycosylation sites from eight unique glycopeptides were determined by a combination of ECD and CID MS approaches. Hydroxyl radical-mediated protein footprinting coupled with mass spectrometry analysis was employed to provide detailed information about protein structure of gp120-OD8 by directly identifying accessible and hydroxyl radical-reactive side chain residues. Comparison of gp120-OD8 experimental footprinting data with a homology model derived from the ligated CD4-gp120-OD8 crystal structure revealed a flexible V3 loop structure in which the V3 tip may provide contacts with the rest of the protein while residues in the V3 base remain solvent accessible. In addition, the data illustrate interactions between specific sugar moieties and amino acid side chains potentially important to the gp120-OD8 structure.

  5. Electrons in the D0 central calorimeter: A study of the systematic biases in the measurement of the W mass

    SciTech Connect (OSTI)

    Heuring, T.C.

    1993-08-01

    The D0 detector at Fermilab is a general purpose collider detector designed for the study of proton-antiproton collisions at a center of mass energy of 1.8 TeV. The detector consists of an inner tracking volume, a hermetic uranium/liquid argon calorimeter, and an outer muon detection system. Since the detector lacks a central magnetic field, it relies on energy measurements from the calorimeter as opposed to momentum measurements using the tracking chambers. To provide the necessary understanding of the calorimeter, a testbeam was conducted at Fermilab during the second half of 1991 featuring detector modules from the central calorimeter. Detailed simulations of the detector apparatus were also written. This thesis will present the results of this testbeam and simulation effort and relate them to the measurement of the W{sup {plus_minus}} intermediate vector boson mass in the full D0 detector. In the testbeam, an energy resolution that scaled as 14% divided by the square root of the beam energy was found. The uniformity of response of the detector as a function of angle of incidence was investigated. We found that the response increased by 4% over the range investigated. The results were compared to a simulation written using the CERN package GEANT. Although GEANT was able to reproduce the energy resolution, it was not able to reproduce the uniformity of response function. A second simulation utilizing the EGS4 package from SLAC was successful in reproducing the behavior of the detector as a function of angle. The biases induced by the discrepancies between the detector and GEANT response functions in the W{sup {plus_minus}} mass measurement are studied. We find that using GEANT as a detector simulation will cause a bias of between 460 and 680 MeV in the W{sup {plus_minus}} mass determination.

  6. Tetrakis(1-imidazolyl) borate (BIM4) based zwitterionic and related molecules used as electron injection layers

    DOE Patents [OSTI]

    Li, Huaping; Xu, Yunhua; Bazan, Guillermo C

    2013-02-05

    Tetrakis(1-imidazolyl)borate (BIm4) based zwitterionic and/or related molecules for the fabrication of PLEDs is provided. Device performances with these materials approaches that of devices with Ba/Al cathodes for which the cathode contact is ohmic. Methods of producing such materials, and electron injection layers and devices containing these materials are also provided.

  7. Estimation of the electron density and radiative energy losses in a calcium plasma source based on an electron cyclotron resonance discharge

    SciTech Connect (OSTI)

    Potanin, E. P. Ustinov, A. L.

    2013-06-15

    The parameters of a calcium plasma source based on an electron cyclotron resonance (ECR) discharge were calculated. The analysis was performed as applied to an ion cyclotron resonance system designed for separation of calcium isotopes. The plasma electrons in the source were heated by gyrotron microwave radiation in the zone of the inhomogeneous magnetic field. It was assumed that, in such a combined trap, the energy of the extraordinary microwave propagating from the high-field side was initially transferred to a small group of resonance electrons. As a result, two electron components with different transverse temperatures-the hot resonance component and the cold nonresonance component-were created in the plasma. The longitudinal temperatures of both components were assumed to be equal. The entire discharge space was divided into a narrow ECR zone, where resonance electrons acquired transverse energy, and the region of the discharge itself, where the gas was ionized. The transverse energy of resonance electrons was calculated by solving the equations for electron motion in an inhomogeneous magnetic field. Using the law of energy conservation and the balance condition for the number of hot electrons entering the discharge zone and cooled due to ionization and elastic collisions, the density of hot electrons was estimated and the dependence of the longitudinal temperature T{sub e Parallel-To} of the main (cold) electron component on the energy fraction {beta} lost for radiation was obtained.

  8. Constraint-Based Modeling of Carbon Fixation and the Energetics of Electron Transfer in Geobacter metallireducens

    SciTech Connect (OSTI)

    Feist, AM; Nagarajan, H; Rotaru, AE; Tremblay, PL; Zhang, T; Nevin, KP; Lovley, DR; Zengler, K

    2014-04-24

    Geobacter species are of great interest for environmental and biotechnology applications as they can carry out direct electron transfer to insoluble metals or other microorganisms and have the ability to assimilate inorganic carbon. Here, we report on the capability and key enabling metabolic machinery of Geobacter metallireducens GS-15 to carry out CO2 fixation and direct electron transfer to iron. An updated metabolic reconstruction was generated, growth screens on targeted conditions of interest were performed, and constraint-based analysis was utilized to characterize and evaluate critical pathways and reactions in G. metallireducens. The novel capability of G. metallireducens to grow autotrophically with formate and Fe(III) was predicted and subsequently validated in vivo. Additionally, the energetic cost of transferring electrons to an external electron acceptor was determined through analysis of growth experiments carried out using three different electron acceptors (Fe(III), nitrate, and fumarate) by systematically isolating and examining different parts of the electron transport chain. The updated reconstruction will serve as a knowledgebase for understanding and engineering Geobacter and similar species. Author Summary The ability of microorganisms to exchange electrons directly with their environment has large implications for our knowledge of industrial and environmental processes. For decades, it has been known that microbes can use electrodes as electron acceptors in microbial fuel cell settings. Geobacter metallireducens has been one of the model organisms for characterizing microbe-electrode interactions as well as environmental processes such as bioremediation. Here, we significantly expand the knowledge of metabolism and energetics of this model organism by employing constraint-based metabolic modeling. Through this analysis, we build the metabolic pathways necessary for carbon fixation, a desirable property for industrial chemical production. We

  9. Electron beam-based sources of ultrashort x-ray pulses.

    SciTech Connect (OSTI)

    Zholents, A.; Accelerator Systems Division

    2010-09-30

    A review of various methods for generation of ultrashort x-ray pulses using relativistic electron beam from conventional accelerators is presented. Both spontaneous and coherent emission of electrons is considered. The importance of the time-resolved studies of matter at picosecond (ps), femtosecond (fs), and atttosecond (as) time scales using x-rays has been widely recognized including by award of a Nobel Prize in 1999 [Zewa]. Extensive reviews of scientific drivers can be found in [BES1, BES2, BES3, Lawr, Whit]. Several laser-based techniques have been used to generate ultrashort x-ray pulses including laser-driven plasmas [Murn, Alte, Risc, Rose, Zamp], high-order harmonic generation [Schn, Rund, Wang, Arpi], and laser-driven anode sources [Ande]. In addition, ultrafast streak-camera detectors have been applied at synchrotron sources to achieve temporal resolution on the picosecond time scale [Wulf, Lind1]. In this paper, we focus on a different group of techniques that are based on the use of the relativistic electron beam produced in conventional accelerators. In the first part we review several techniques that utilize spontaneous emission of electrons and show how solitary sub-ps x-ray pulses can be obtained at existing storage ring based synchrotron light sources and linacs. In the second part we consider coherent emission of electrons in the free-electron lasers (FELs) and review several techniques for a generation of solitary sub-fs x-ray pulses. Remarkably, the x-ray pulses that can be obtained with the FELs are not only significantly shorter than the ones considered in Part 1, but also carry more photons per pulse by many orders of magnitude.

  10. UV-Vis, infrared, and mass spectroscopy of electron irradiated frozen oxygen and carbon dioxide mixtures with water

    SciTech Connect (OSTI)

    Jones, Brant M.; Kaiser, Ralf I.; Strazzulla, Giovanni

    2014-02-01

    Ozone has been detected on the surface of Ganymede via observation of the Hartley band through the use of ultraviolet spectroscopy and is largely agreed upon to be formed by radiolytic processing via interaction of magnetospheric energetic ions and/or electrons with oxygen-bearing ices on Ganymede's surface. Interestingly, a clearly distinct band near 300 nm within the shoulder of the UV-Vis spectrum of Ganymede was also observed, but currently lacks an acceptable physical or chemical explanation. Consequently, the primary motivation behind this work was the collection of UV-Vis absorption spectroscopy of ozone formation by energetic electron bombardment of a variety of oxygen-bearing ices (oxygen, carbon dioxide, water) relevant to this moon as well as other solar system. Ozone was indeed synthesized in pure ices of molecular oxygen, carbon dioxide and a mixture of water and oxygen, in agreement with previous studies. The Hartley band of the ozone synthesized in these ice mixtures was observed in the UV-Vis spectra and compared with the spectrum of Ganymede. In addition, a solid state ozone absorption cross section of 6.0 0.6 10{sup 17} cm{sup 2} molecule{sup 1} was obtained from the UV-Vis spectral data. Ozone was not produced in the irradiated carbon dioxide-water mixtures; however, a spectrally 'red' UV continuum is observed and appears to reproduce well what is observed in a large number of icy moons such as Europa.

  11. ANALYSIS OF PASSIVATED SURFACES FOR MASS SPECTROMETER INLET SYSTEMS BY AUGER ELECTRON AND X-RAY PHOTOELECTRON SPECTROSCOPY

    SciTech Connect (OSTI)

    Ajo, H.; Clark, E.

    2010-09-01

    Stainless steel coupons approximately 0.5' in diameter and 0.125' thick were passivated with five different surface treatments and an untreated coupon was left as a control. These surface treatments are being explored for use in tritium storage containers. These coupons were made to allow surface analysis of the surface treatments using well-know surface analysis techniques. Depth profiles using Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS) were performed on these coupons to characterize the surface and near surface regions. Scanning electron microscope (SEM) images were collected as well. All of the surface treatments studied here appear to change the surface morphology dramatically, as evidenced by lack of tool marks on the treated samples. In terms of the passivation treatment, Vendors A-D appeared to have oxide layers that were very similar in thickness to each other (0.7-0.9 nm thick) as well as the untreated samples (the untreated sample oxide layers appeared to be somewhat larger). Vendor E's silicon coating appears to be on the order of 200 nm thick.

  12. A double-layer based model of ion confinement in electron cyclotron resonance ion source

    SciTech Connect (OSTI)

    Mascali, D. Neri, L.; Celona, L.; Castro, G.; Gammino, S.; Ciavola, G.; Torrisi, G.; Universit Mediterranea di Reggio Calabria, Dipartimento di Ingegneria dellInformazione, delle Infrastrutture e dellEnergia Sostenibile, Via Graziella, I-89100 Reggio Calabria ; Sorbello, G.; Universit degli Studi di Catania, Dipartimento di Ingegneria Elettrica Elettronica ed Informatica, Viale Andrea Doria 6, 95125 Catania

    2014-02-15

    The paper proposes a new model of ion confinement in ECRIS, which can be easily generalized to any magnetic configuration characterized by closed magnetic surfaces. Traditionally, ion confinement in B-min configurations is ascribed to a negative potential dip due to superhot electrons, adiabatically confined by the magneto-static field. However, kinetic simulations including RF heating affected by cavity modes structures indicate that high energy electrons populate just a thin slab overlapping the ECR layer, while their density drops down of more than one order of magnitude outside. Ions, instead, diffuse across the electron layer due to their high collisionality. This is the proper physical condition to establish a double-layer (DL) configuration which self-consistently originates a potential barrier; this barrier confines the ions inside the plasma core surrounded by the ECR surface. The paper will describe a simplified ion confinement model based on plasma density non-homogeneity and DL formation.

  13. Modeling of induction-linac based free-electron laser amplifiers

    SciTech Connect (OSTI)

    Jong, R.A.; Fawley, W.M.; Scharlemann, E.T.

    1988-12-01

    We describe the modeling of an induction-linac based free-electron laser (IFEL) amplifier for producing multimegawatt levels of microwave power. We have used the Lawrence Livermore National Laboratory (LLNL) free-electron laser simulation code, FRED, and the simulation code for sideband calculations, GINGER for this study. For IFEL amplifiers in the frequency range of interest (200 to 600 GHz), we have devised a wiggler design strategy which incorporates a tapering algorithm that is suitable for free-electron laser (FEL) systems with moderate space-charge effects and that minimizes spontaneous noise growth at frequencies below the fundamental, while enhancing the growth of the signal at the fundamental. In addition, engineering design considerations of the waveguide wall loading and electron beam fill factor in the waveguide set limits on the waveguide dimensions, the wiggler magnet gap spacing, the wiggler period, and the minimum magnetic field strength in the tapered region of the wiggler. As an example, we shall describe an FEL amplifier designed to produce an average power of about 10 MW at a frequency of 280 GHz to be used for electron cyclotron resonance heating of tokamak fusion devices. 17 refs., 4 figs.

  14. OpenMSI: A High-Performance Web-Based Platform for Mass Spectrometry Imaging

    SciTech Connect (OSTI)

    Rubel, Oliver; Greiner, Annette; Cholia, Shreyas; Louie, Katherine; Bethel, E. Wes; Northen, Trent R.; Bowen, Benjamin P.

    2013-10-02

    Mass spectrometry imaging (MSI) enables researchers to directly probe endogenous molecules directly within the architecture of the biological matrix. Unfortunately, efficient access, management, and analysis of the data generated by MSI approaches remain major challenges to this rapidly developing field. Despite the availability of numerous dedicated file formats and software packages, it is a widely held viewpoint that the biggest challenge is simply opening, sharing, and analyzing a file without loss of information. Here we present OpenMSI, a software framework and platform that addresses these challenges via an advanced, high-performance, extensible file format and Web API for remote data access (http://openmsi.nersc.gov). The OpenMSI file format supports storage of raw MSI data, metadata, and derived analyses in a single, self-describing format based on HDF5 and is supported by a large range of analysis software (e.g., Matlab and R) and programming languages (e.g., C++, Fortran, and Python). Careful optimization of the storage layout of MSI data sets using chunking, compression, and data replication accelerates common, selective data access operations while minimizing data storage requirements and are critical enablers of rapid data I/O. The OpenMSI file format has shown to provide >2000-fold improvement for image access operations, enabling spectrum and image retrieval in less than 0.3 s across the Internet even for 50 GB MSI data sets. To make remote high-performance compute resources accessible for analysis and to facilitate data sharing and collaboration, we describe an easy-to-use yet powerful Web API, enabling fast and convenient access to MSI data, metadata, and derived analysis results stored remotely to facilitate high-performance data analysis and enable implementation of Web based data sharing, visualization, and analysis.

  15. Electron - polar acoustical phonon interactions in nitride based diluted magnetic semiconductor quantum well via hot electron magnetotransport

    SciTech Connect (OSTI)

    Pandya, Ankur; Shinde, Satyam; Jha, Prafulla K.

    2015-05-15

    In this paper the hot electron transport properties like carrier energy and momentum scattering rates and electron energy loss rates are calculated via interactions of electrons with polar acoustical phonons for Mn doped BN quantum well in BN nanosheets via piezoelectric scattering and deformation potential mechanisms at low temperatures with high electric field. Electron energy loss rate increases with the electric field. It is observed that at low temperatures and for low electric field the phonon absorption is taking place whereas, for sufficient large electric field, phonon emission takes place. Under the piezoelectric (polar acoustical phonon) scattering mechanism, the carrier scattering rate decreases with the reduction of electric field at low temperatures wherein, the scattering rate variation with electric field is limited by a specific temperature beyond which there is no any impact of electric field on such scattering.

  16. Neutral beamline with ion energy recovery based on magnetic blocking of electrons

    DOE Patents [OSTI]

    Stirling, William L.

    1982-01-01

    A neutral beamline generator with energy recovery of the full-energy ion ponent of the beam based on magnetic blocking of electrons is provided. Ions from a positive ion source are accelerated to the desired beam energy from a slightly positive potential level with respect to ground through a neutralizer cell by means of a negative acceleration voltage. The unneutralized full-energy ion component of the beam exiting the neutralizer are retarded and slightly deflected and the electrons in the neutralizer are blocked by a magnetic field generated transverse to the beamline. An electron collector in the form of a coaxial cylinder surrounding and protruding axial a few centimeters beyond the neutralizer exit terminates the electrons which exit the neutralizer in an E x B drift to the collector when the collector is biased a few hundred volts positive with respect to the neutralizer voltage. The neutralizer is operated at the negative acceleration voltage, and the deflected full energy ions are decelerated and the charge collected at ground potential thereby expending none of their energy received from the acceleration power supply.

  17. Electron phonon coupling in Ni-based binary alloys with application to displacement cascade modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samolyuk, German D.; Stocks, George Malcolm; Stoller, Roger E.

    2016-04-01

    Energy transfer between lattice atoms and electrons is an important channel of energy dissipation during displacement cascade evolution in irradiated materials. On the assumption of small atomic displacements, the intensity of this transfer is controlled by the strength of electron–phonon (el–ph) coupling. The el–ph coupling in concentrated Ni-based alloys was calculated using electronic structure results obtained within the coherent potential approximation. It was found that Ni0.5Fe0.5, Ni0.5Co0.5 and Ni0.5Pd0.5 are ordered ferromagnetically, whereas Ni0.5Cr0.5 is nonmagnetic. Since the magnetism in these alloys has a Stoner-type origin, the magnetic ordering is accompanied by a decrease of electronic density of states atmore » the Fermi level, which in turn reduces the el–ph coupling. Thus, the el–ph coupling values for all alloys are approximately 50% smaller in the magnetic state than for the same alloy in a nonmagnetic state. As the temperature increases, the calculated coupling initially increases. After passing the Curie temperature, the coupling decreases. The rate of decrease is controlled by the shape of the density of states above the Fermi level. Introducing a two-temperature model based on these parameters in 10 keV molecular dynamics cascade simulation increases defect production by 10–20% in the alloys under consideration.« less

  18. In situ electrical characterization of palladium-based single electron transistors made by electromigration technique

    SciTech Connect (OSTI)

    Arzubiaga, L.; Llopis, R.; Golmar, F.; Casanova, F.; Hueso, L. E.

    2014-11-15

    We report the fabrication of single electron transistors (SETs) by feedback-controlled electromigration of palladium and palladium-nickel alloy nanowires. We have optimized a gradual electromigration process for obtaining devices consisting of three terminals (source, drain and gate electrodes), which are capacitively coupled to a metallic cluster of nanometric dimensions. This metal nanocluster forms into the inter-electrode channel during the electromigration process and constitutes the active element of each device, acting as a quantum dot that rules the electron flow between source and drain electrodes. The charge transport of the as-fabricated devices shows Coulomb blockade characteristics and the source to drain conductance can be modulated by electrostatic gating. We have thus achieved the fabrication and in situ measurement of palladium-based SETs inside a liquid helium cryostat chamber.

  19. Reconnaissance Estimates of Recharge Based on an Elevation-dependent Chloride Mass-balance Approach

    SciTech Connect (OSTI)

    Charles E. Russell; Tim Minor

    2002-08-31

    Significant uncertainty is associated with efforts to quantity recharge in arid regions such as southern Nevada. However, accurate estimates of groundwater recharge are necessary to understanding the long-term sustainability of groundwater resources and predictions of groundwater flow rates and directions. Currently, the most widely accepted method for estimating recharge in southern Nevada is the Maxey and Eakin method. This method has been applied to most basins within Nevada and has been independently verified as a reconnaissance-level estimate of recharge through several studies. Recharge estimates derived from the Maxey and Eakin and other recharge methodologies ultimately based upon measures or estimates of groundwater discharge (outflow methods) should be augmented by a tracer-based aquifer-response method. The objective of this study was to improve an existing aquifer-response method that was based on the chloride mass-balance approach. Improvements were designed to incorporate spatial variability within recharge areas (rather than recharge as a lumped parameter), develop a more defendable lower limit of recharge, and differentiate local recharge from recharge emanating as interbasin flux. Seventeen springs, located in the Sheep Range, Spring Mountains, and on the Nevada Test Site were sampled during the course of this study and their discharge was measured. The chloride and bromide concentrations of the springs were determined. Discharge and chloride concentrations from these springs were compared to estimates provided by previously published reports. A literature search yielded previously published estimates of chloride flux to the land surface. {sup 36}Cl/Cl ratios and discharge rates of the three largest springs in the Amargosa Springs discharge area were compiled from various sources. This information was utilized to determine an effective chloride concentration for recharging precipitation and its associated uncertainty via Monte Carlo simulations

  20. The effect of maximum-allowable payload temperature on the mass of a multimegawatt space-based platform

    SciTech Connect (OSTI)

    Dobranich, D.

    1987-08-01

    Calculations were performed to determine the mass of a space-based platform as a function of the maximum-allowed operating temperature of the electrical equipment within the platform payload. Two computer programs were used in conjunction to perform these calculations. The first program was used to determine the mass of the platform reactor, shield, and power conversion system. The second program was used to determine the mass of the main and secondary radiators of the platform. The main radiator removes the waste heat associated with the power conversion system and the secondary radiator removes the waste heat associated with the platform payload. These calculations were performed for both Brayton and Rankine cycle platforms with two different types of payload cooling systems: a pumped-loop system (a heat exchanger with a liquid coolant) and a refrigerator system. The results indicate that increases in the maximum-allowed payload temperature offer significant platform mass savings for both the Brayton and Rankine cycle platforms with either the pumped-loop or refrigerator payload cooling systems. Therefore, with respect to platform mass, the development of high temperature electrical equipment would be advantageous. 3 refs., 24 figs., 7 tabs.

  1. A Test Facility for MEIC ERL Circulator Ring Based Electron Cooler Design

    SciTech Connect (OSTI)

    Zhang, Yuhong; Derbenev, Yaroslav S.; Douglas, David R.; Hutton, Andrew M.; Krafft, Geoffrey A.; Nissen, Edward W.

    2013-05-01

    An electron cooling facility which is capable to deliver a beam with energy up to 55 MeV and average current up to 1.5 A at a high bunch repetition rate up to 750 MHz is required for MEIC. The present cooler design concept is based on a magnetized photo-cathode SRF gun, an SRF ERL and a compact circulator ring. In this paper, we present a proposal of a test facility utilizing the JLab FEL ERL for a technology demonstration of this cooler design concept. Beam studies will be performed and supporting technologies will also be developed in this test facility.

  2. Induction-linac based free-electron laser amplifiers for plasma heating

    SciTech Connect (OSTI)

    Jong, R.A.

    1988-08-22

    We describe an induction-linac based free-electron laser amplifier that is presently under construction at the Lawrence Livermore National Laboratory. It is designed to produce up to 2 MW of average power at a frequency of 250 GHz for plasma heating experiments in the Microwave Tokamak Experiment. In addition, we shall describe a FEL amplifier design for plasma heating of advanced tokamak fusion devices. This system is designed to produce average power levels of about 10 MW at frequencies ranging form 280 to 560 GHz. 7 refs., 1 tab.

  3. Neutral beamline with ion energy recovery based on magnetic blocking of electrons

    DOE Patents [OSTI]

    Stirling, W.L.

    1980-07-01

    A neutral beamline generator with energy recovery of the full-energy ion component of the beam based on magnetic blocking of electrons is provided. Ions from a positive ion source are accelerated to the desired beam energy from a slightly positive potential level with respect to ground through a neutralizer cell by means of a negative acceleration voltage. The unneutralized full-energy ion component of the beam exiting the neutralizer are retarded and slightly deflected and the elecrons in the neutralizer are blocked by a magnetic field generated transverse to the beamline. An electron collector in the form of a coaxial cylinder surrounding and protruding axial a few centimeters beyond the neutralizer exit terminates the electrons which exit the neutralizer in an E x B drift to the collector when the collector is biased a few hundred volts positive with respect to the neutralizer voltage. The neutralizer is operated at the negative acceleration voltage. The neutralizer is operated at the negative acceleration voltage, and the deflected full energy ions are decelerated and the charge collected at ground potential thereby expending none of their energy received from the acceleration power supply.

  4. Method to fabricate portable electron source based on nitrogen incorporated ultrananocrystalline diamond (N-UNCD)

    DOE Patents [OSTI]

    Sumant, Anirudha V.; Divan, Ralu; Posada, Chrystian M.; Castano, Carlos H.; Grant, Edwin J.; Lee, Hyoung K.

    2016-03-29

    A source cold cathode field emission array (FEA) source based on ultra-nanocrystalline diamond (UNCD) field emitters. This system was constructed as an alternative for detection of obscured objects and material. Depending on the geometry of the given situation a flat-panel source can be used in tomography, radiography, or tomosynthesis. Furthermore, the unit can be used as a portable electron or X-ray scanner or an integral part of an existing detection system. UNCD field emitters show great field emission output and can be deposited over large areas as the case with carbon nanotube "forest" (CNT) cathodes. Furthermore, UNCDs have better mechanical and thermal properties as compared to CNT tips which further extend the lifetime of UNCD based FEA.

  5. Web-based Electronic Sharing and RE-allocation of Assets

    Energy Science and Technology Software Center (OSTI)

    2002-09-09

    The Electronic Asses Sharing Program is a web-based application that provides the capability for complex-wide sharing and reallocation of assets that are excess, under utilized, or un-utilized. through a web-based fron-end and supporting has database with a search engine, users can search for assets that they need, search for assets needed by others, enter assets they need, and enter assets they have available for reallocation. In addition, entire listings of available assets and needed assetsmore » can be viewed. The application is written in Java, the hash database and search engine are in Object-oriented Java Database Management (OJDBM). The application will be hosted on an SRS-managed server outside the Firewall and access will be controlled via a protected realm. An example of the application can be viewed at the followinig (temporary) URL: http://idgdev.srs.gov/servlet/srs.weshare.WeShare« less

  6. Mass spectrometry-based methods for detection and differentiation of botulinum neurotoxins

    DOE Patents [OSTI]

    Schmidt, Jurgen G.; Boyer, Anne E.; Kalb, Suzanne R.; Moura, Hercules; Barr, John R.; Woolfitt, Adrian R.

    2009-11-03

    The present invention is directed to a method for detecting the presence of clostridial neurotoxins in a sample by mixing a sample with a peptide that can serve as a substrate for proteolytic activity of a clostridial neurotoxin; and measuring for proteolytic activity of a clostridial neurotoxin by a mass spectroscopy technique. In one embodiment, the peptide can have an affinity tag attached at two or more sites.

  7. Floating Refrigerant Loop Based on R-134a Refrigerant Cooling of High-Heat Flux Electronics

    SciTech Connect (OSTI)

    Lowe, K.T.

    2005-10-07

    The Oak Ridge National Laboratory (ORNL) Power Electronics and Electric Machinery Research Center (PEEMRC) have been developing technologies to address the thermal issues associated with hybrid vehicles. Removal of the heat generated from electrical losses in traction motors and their associated power electronics is essential for the reliable operation of motors and power electronics. As part of a larger thermal control project, which includes shrinking inverter size and direct cooling of electronics, ORNL has developed U.S. Patent No. 6,772,603 B2, ''Methods and Apparatus for Thermal Management of Vehicle Systems and Components'' [1], and patent pending, ''Floating Loop System for Cooling Integrated Motors and Inverters Using Hot Liquid Refrigerant'' [2]. The floating-loop system provides a large coefficient of performance (COP) for hybrid-drive component cooling. This loop (based on R-134a) is integrated with a vehicle's existing air-conditioning (AC) condenser, which dissipates waste heat to the ambient air. Because the temperature requirements for cooling of power electronics and electric machines are not as low as that required for passenger compartment air, this adjoining loop can operate on the high-pressure side of the existing AC system. This arrangement also allows the floating loop to run without the need for the compressor and only needs a small pump to move the liquid refrigerant. For the design to be viable, the loop must not adversely affect the existing system. The loop should also provide a high COP, a flat-temperature profile, and low-pressure drop. To date, the floating-loop test prototype has successfully removed 2 kW of heat load in a 9 kW automobile passenger AC system with and without the automotive AC system running. The COP for the tested floating-loop system ranges from 40-45, as compared to a typical AC system COP of about 2-4. The estimated required waste-heat load for future hybrid applications is 5.5 kW and the existing system could be

  8. A nanostructure-initiator mass spectrometry-based enzyme activity assay

    SciTech Connect (OSTI)

    Siuzdak, Gary; Northen, Trent R.; Lee, Jinq-Chyi; Hoang, Linh; Raymond, Jason; Hwang, Der-Ren; Yannone, Steven M.; Wong, Chi-Huey; Siuzdak, Gary

    2008-03-10

    We describe a Nanostructure-Initiator Mass Spectrometry (NIMS) enzymatic (Nimzyme) assay in which enzyme substrates are immobilized on the mass spectrometry surface by using fluorous-phase interactions. This 'soft' immobilization allows efficient desorption/ionization while also enabling the use of surface-washing steps to reduce signal suppression from complex biological samples, which results from the preferential retention of the tagged products and reactants. The Nimzyme assay is sensitive to subpicogram levels of enzyme, detects both addition and cleavage reactions (sialyltransferase and galactosidase), is applicable over a wide range of pHs and temperatures, and can measure activity directly from crude cell lysates. The ability of the Nimzyme assay to analyze complex mixtures is illustrated by identifying and directly characterizing {beta}-1,4-galactosidase activity from a thermophilic microbial community lysate. The optimal enzyme temperature and pH were found to be 65 C and 5.5, respectively, and the activity was inhibited by both phenylethyl-{beta}-d-thiogalactopyranoside and deoxygalactonojirimycin. Metagenomic analysis of the community suggests that the activity is from an uncultured, unsequenced {gamma}-proteobacterium. In general, this assay provides an efficient method for detection and characterization of enzymatic activities in complex biological mixtures prior to sequencing or cloning efforts. More generally, this approach may have important applications for screening both enzymatic and inhibitor libraries, constructing and screening glycan microarrays, and complementing fluorous-phase organic synthesis. The interest in leveraging mass spectrometry for studying enzyme activities in complex biological samples derives from its high sensitivity and specificity; however, signal suppression and significant sample preparation requirements limit its overall utility (1). Here we describe a Nanostructure-Initiator Mass Spectrometry (NIMS) enzymatic (Nimzyme

  9. GPAW - massively parallel electronic structure calculations with Python-based software.

    SciTech Connect (OSTI)

    Enkovaara, J.; Romero, N.; Shende, S.; Mortensen, J.

    2011-01-01

    Electronic structure calculations are a widely used tool in materials science and large consumer of supercomputing resources. Traditionally, the software packages for these kind of simulations have been implemented in compiled languages, where Fortran in its different versions has been the most popular choice. While dynamic, interpreted languages, such as Python, can increase the effciency of programmer, they cannot compete directly with the raw performance of compiled languages. However, by using an interpreted language together with a compiled language, it is possible to have most of the productivity enhancing features together with a good numerical performance. We have used this approach in implementing an electronic structure simulation software GPAW using the combination of Python and C programming languages. While the chosen approach works well in standard workstations and Unix environments, massively parallel supercomputing systems can present some challenges in porting, debugging and profiling the software. In this paper we describe some details of the implementation and discuss the advantages and challenges of the combined Python/C approach. We show that despite the challenges it is possible to obtain good numerical performance and good parallel scalability with Python based software.

  10. Room temperature, hybrid sodium-based flow batteries with multi-electron transfer redox reactions

    SciTech Connect (OSTI)

    Shamie, Jack S.; Liu, Caihong; Shaw, Leon L.; Sprenkle, Vincent L.

    2015-06-11

    We introduce a new concept of hybrid Na-based flow batteries (HNFBs) with a molten Na alloy anode in conjunction with a flowing catholyte separated by a solid Na-ion exchange membrane for grid-scale energy storage. Such HNFBs can operate at ambient temperature, allow catholytes to have multiple electron transfer redox reactions per active ion, offer wide selection of catholyte chemistries with multiple active ions to couple with the highly negative Na alloy anode, and enable the use of both aqueous and non-aqueous catholytes. Further, the molten Na alloy anode permits the decoupled design of power and energy since a large volume of the molten Na alloy can be used with a limited ion-exchange membrane size. In this proof-of-concept study, the feasibility of multielectron transfer redox reactions per active ion and multiple active ions for catholytes has been demonstrated. Furthermore, the critical barriers to mature this new HNFBs have also been explored.

  11. Room Temperature, Hybrid Sodium-Based Flow Batteries with Multi-Electron Transfer Redox Reactions

    SciTech Connect (OSTI)

    Shamie, Jack S.; Liu, Caihong; Shaw, Leon L.; Sprenkle, Vincent L.

    2015-06-11

    We introduce a new concept of hybrid Na-based flow batteries (HNFBs) with a molten Na alloy anode in conjunction with a flowing catholyte separated by a solid Na-ion exchange membrane for grid-scale energy storage. Such HNFBs can operate at ambient temperature, allow catholytes to have multiple electron transfer redox reactions per active ion, offer wide selection of catholyte chemistries with multiple active ions to couple with the highly negative Na alloy anode, and enable the use of both aqueous and non-aqueous catholytes. Further, the molten Na alloy anode permits the decoupled design of power and energy since a large volume of the molten Na alloy can be used with a limited ion-exchange membrane size. In this proof-of-concept study, the feasibility of multielectron transfer redox reactions per active ion and multiple active ions for catholytes has been demonstrated. The critical barriers to mature this new HNFBs have also been explored.

  12. Urethane-based stabilizers for radiation-crosslinked polyethylene. [Electron beams

    SciTech Connect (OSTI)

    Shkolnik, S.; Rajbenbach, L.A.

    1982-11-01

    Unsaturated urethane-based stabilizers for use in radiation-crosslinked polyethylene were synthesized. Aromatic amine moieties were attached to allylic and acrylic monomers by means of aromatic or aliphatic diisocyanates. The synthesized stabilizers were incorporated in high-density polyethylene films which were subjected to electron beam irradiation. The oxidative stability of the films prior to and after extraction was determined by DTA in the temperature range 185-210/sup 0/C and compared with samples treated with commercial amine-bearing antioxidants. Tensile strength and gel content were also determined. Best results were obtained with a stabilizer prepared from equimolecular amounts of allyl alcohol, tolylene-2,4-diisocyanate and N-phenyl-1,4-phenylenediamine. Estimated lifetimes at 70/sup 0/C of stabilized irradiated polyethylene samples were calculated.

  13. Star-cluster mass and age distributions of two fields in M83 based on HST/WFC3 observations

    SciTech Connect (OSTI)

    Chandar, Rupali; Whitmore, Bradley C.; Calzetti, Daniela; O'Connell, Robert

    2014-05-20

    We study star clusters in two fields in the nearby spiral galaxy M83 using broadband and narrowband optical imaging taken with the Wide Field Camera 3 onboard the Hubble Space Telescope. We present results on the basis of several different catalogs of star clusters in inner and outer fields, and we conclude that different methods of selection do not strongly affect the results, particularly for clusters older than ?10 Myr. The age distributions can be described by a power law, dN/d???{sup ?}, with ? ? 0.84 0.12 in the inner field, and ? ? 0.48 0.12 in the outer field for ? ? 10 Myr. We bracket the difference, ??, between the two fields to be in the 0.18 to 0.36 range, based on estimates of the relative star-formation histories. The mass functions can also be described by a power law, dN/dM?M {sup ?}, with ? ? 1.98 0.14 and ? ? 2.34 0.26 in the inner and outer fields, respectively. We conclude that the shapes of the mass and age distributions of the clusters in the two fields are similar, as predicted by the quasi-universal model. Any differences between the two fields are at the ?2?-3? (?1?-2?) level for the age (mass) distributions. Therefore, any dependence of these distributions on the local environment is probably weak. We compare the shapes of the distributions with those predicted by two popular cluster disruption models. We find that both show evidence that the clusters are disrupted at a rate that is approximately independent of their mass. We compare the shapes of the distributions with those predicted by two popular cluster disruption models, and find that both show evidence that the clusters are disrupted at a rate that is approximately independent of their mass, and that observational results do not support the earlier disruption of lower-mass clusters relative to their higher-mass counterparts.

  14. Thermodynamic Prediction of Compositional Phases Confirmed by Transmission Electron Microscopy on Tantalum-Based Alloy Weldments

    SciTech Connect (OSTI)

    Moddeman, William E.; Birkbeck, Janine C.; Barklay, Chadwick D.; Kramer, Daniel P.; Miller, Roger G.; Allard, Lawrence F.

    2007-01-30

    Tantalum alloys have been used by the U.S. Department of Energy as structural alloys for radioisotope based thermal to electrical power systems since the 1960s. Tantalum alloys are attractive for high temperature structural applications due to their high melting point, excellent formability, good thermal conductivity, good ductility (even at low temperatures), corrosion resistance, and weldability. Tantalum alloys have demonstrated sufficient high-temperature toughness to survive prolonged exposure to the radioisotope power-system working environment. Typically, the fabrication of power systems requires the welding of various components including the structural members made of tantalum alloys. Issues such as thermodynamics, lattice structure, weld pool dynamics, material purity and contamination, and welding atmosphere purity all potentially confound the understanding of the differences between the weldment properties of the different tantalum-based alloys. The objective of this paper is to outline the thermodynamically favorable material phases in tantalum alloys, with and without small amounts of hafnium, during and following solidification, based on the results derived from the FactSage(c) Integrated Thermodynamic Databank. In addition, Transition Electron Microscopy (TEM) data will show for the first time, the changes occurring in the HfC before and after welding, and the data will elucidate the role HfC plays in pinning grain boundaries.

  15. Recommendations for the generation, quantification, storage and handling of peptides used for mass spectrometry-based assays

    SciTech Connect (OSTI)

    Hoofnagle, Andrew N.; Whiteaker, Jeffrey R.; Carr, Steven A.; Kuhn, Eric; Liu, Tao; Massoni, Sam A.; Thomas, Stefani N.; Townsend, Reid; Zimmerman, Lisa J.; Boja, Emily; Chen, Jing; Crimmins, Daniel L.; Davies, Sherri; Gao, Yuqian; Hiltke, Tara R.; Ketchum, Karen; Kinsinger, Christopher; Mesri, Mehdi; Meyer, Matthew R.; Qian, Weijun; Schoenherr, Regine M.; Scott, Mitchell; Shi, Tujin; Whiteley, Gordon; Wrobel, John; Wu, Chaochao; Ackermann, Bradley L.; Aebersold, Ruedi; Barnidge, David R.; Bunk, David M.; Clarke, Nigel; Fishman, Jordan B.; Grant, Russ P.; Kusebauch, Ulrike; Kushnir, Mark M.; Lowenthal, Mark S.; Moritz, Robert; Neubert, Hendrik; Patterson, Scott D.; Rockwood, Alan L.; Rogers, John; Singh, Ravinder J.; Van Eyk, Jennifer; Wong, Steven H.; Zhang, Shucha; Chan, Daniel W.; Chen, Xian; Ellis, Matthew J.; Liebler, Daniel; Rodland, Karin D.; Rodriguez, Henry; Smith, Richard D.; Zhang, Zhen; Zhang, Hui; Paulovich, Amanda G.

    2015-12-30

    The Clinical Proteomic Tumor Analysis Consortium (1) (CPTAC) of the National Cancer Institute (NCI) is a comprehensive and coordinated effort to accelerate the understanding of the molecular basis of cancer through the application of robust technologies and workflows for the quantitative measurements of proteins. The Assay Development Working Group of the CPTAC Program aims to foster broad uptake of targeted mass spectrometry-based assays employing isotopically labeled peptides for confident assignment and quantification, including multiple reaction monitoring (MRM; also referred to as Selected Reaction Monitoring), parallel reaction monitoring (PRM), and other targeted methods.

  16. Goniometer-based femtosecond crystallography with X-ray free electron lasers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cohen, Aina E.; Soltis, S. Michael; González, Ana; Aguila, Laura; Alonso-Mori, Roberto; Barnes, Christopher O.; Baxter, Elizabeth L.; Brehmer, Winnie; Brewster, Aaron S.; Brunger, Axel T.; et al

    2014-10-31

    The emerging method of femtosecond crystallography (FX) may extend the diffraction resolution accessible from small radiation-sensitive crystals and provides a means to determine catalytically accurate structures of acutely radiation-sensitive metalloenzymes. Automated goniometer-based instrumentation developed for use at the Linac Coherent Light Source enabled efficient and flexible FX experiments to be performed on a variety of sample types. In the case of rod-shaped Cpl hydrogenase crystals, only five crystals and about 30 min of beam time were used to obtain the 125 still diffraction patterns used to produce a 1.6-Å resolution electron density map. With smaller crystals, high-density grids were usedmore » to increase sample throughput; 930 myoglobin crystals mounted at random orientation inside 32 grids were exposed, demonstrating the utility of this approach. Screening results from cryocooled crystals of β2-adrenoreceptor and an RNA polymerase II complex indicate the potential to extend the diffraction resolution obtainable from very radiation-sensitive samples beyond that possible with undulator-based synchrotron sources.« less

  17. Goniometer-based femtosecond crystallography with X-ray free electron lasers

    SciTech Connect (OSTI)

    Cohen, Aina E.; Soltis, S. Michael; Gonzlez, Ana; Aguila, Laura; Alonso-Mori, Roberto; Barnes, Christopher O.; Baxter, Elizabeth L.; Brehmer, Winnie; Brewster, Aaron S.; Brunger, Axel T.; Calero, Guillermo; Chang, Joseph F.; Chollet, Matthieu; Ehrensberger, Paul; Eriksson, Thomas L.; Feng, Yiping; Hattne, Johan; Hedman, Britt; Hollenbeck, Michael; Holton, James M.; Keable, Stephen; Kobilka, Brian K.; Kovaleva, Elena G.; Kruse, Andrew C.; Lemke, Henrik T.; Lin, Guowu; Lyubimov, Artem Y.; Manglik, Aashish; Mathews, Irimpan I.; McPhillips, Scott E.; Nelson, Silke; Peters, John W.; Sauter, Nicholas K.; Smith, Clyde A.; Song, Jinhu; Stevenson, Hilary P.; Tsai, Yingssu; Uervirojnangkoorn, Monarin; Vinetsky, Vladimir; Wakatsuki, Soichi; Weis, William I.; Zadvornyy, Oleg A.; Zeldin, Oliver B.; Zhu, Diling; Hodgson, Keith O.

    2014-10-31

    The emerging method of femtosecond crystallography (FX) may extend the diffraction resolution accessible from small radiation-sensitive crystals and provides a means to determine catalytically accurate structures of acutely radiation-sensitive metalloenzymes. Automated goniometer-based instrumentation developed for use at the Linac Coherent Light Source enabled efficient and flexible FX experiments to be performed on a variety of sample types. In the case of rod-shaped Cpl hydrogenase crystals, only five crystals and about 30 min of beam time were used to obtain the 125 still diffraction patterns used to produce a 1.6- resolution electron density map. With smaller crystals, high-density grids were used to increase sample throughput; 930 myoglobin crystals mounted at random orientation inside 32 grids were exposed, demonstrating the utility of this approach. Screening results from cryocooled crystals of ?2-adrenoreceptor and an RNA polymerase II complex indicate the potential to extend the diffraction resolution obtainable from very radiation-sensitive samples beyond that possible with undulator-based synchrotron sources.

  18. Non parametric denoising methods based on wavelets: Application to electron microscopy images in low exposure time

    SciTech Connect (OSTI)

    Soumia, Sid Ahmed; Messali, Zoubeida; Ouahabi, Abdeldjalil; Trepout, Sylvain E-mail: cedric.messaoudi@curie.fr Messaoudi, Cedric E-mail: cedric.messaoudi@curie.fr Marco, Sergio E-mail: cedric.messaoudi@curie.fr

    2015-01-13

    The 3D reconstruction of the Cryo-Transmission Electron Microscopy (Cryo-TEM) and Energy Filtering TEM images (EFTEM) hampered by the noisy nature of these images, so that their alignment becomes so difficult. This noise refers to the collision between the frozen hydrated biological samples and the electrons beam, where the specimen is exposed to the radiation with a high exposure time. This sensitivity to the electrons beam led specialists to obtain the specimen projection images at very low exposure time, which resulting the emergence of a new problem, an extremely low signal-to-noise ratio (SNR). This paper investigates the problem of TEM images denoising when they are acquired at very low exposure time. So, our main objective is to enhance the quality of TEM images to improve the alignment process which will in turn improve the three dimensional tomography reconstructions. We have done multiple tests on special TEM images acquired at different exposure time 0.5s, 0.2s, 0.1s and 1s (i.e. with different values of SNR)) and equipped by Golding beads for helping us in the assessment step. We herein, propose a structure to combine multiple noisy copies of the TEM images. The structure is based on four different denoising methods, to combine the multiple noisy TEM images copies. Namely, the four different methods are Soft, the Hard as Wavelet-Thresholding methods, Bilateral Filter as a non-linear technique able to maintain the edges neatly, and the Bayesian approach in the wavelet domain, in which context modeling is used to estimate the parameter for each coefficient. To ensure getting a high signal-to-noise ratio, we have guaranteed that we are using the appropriate wavelet family at the appropriate level. So we have chosen âĂIJsym8âĂİ wavelet at level 3 as the most appropriate parameter. Whereas, for the bilateral filtering many tests are done in order to determine the proper filter parameters represented by the size of the filter, the range parameter and the

  19. Femtosecond laser ablation-based mass spectrometry. An ideal tool for stoichiometric analysis of thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    LaHaye, Nicole L.; Kurian, Jose; Diwakar, Prasoon K.; Alff, Lambert; Harilal, Sivanandan S.

    2015-08-19

    An accurate and routinely available method for stoichiometric analysis of thin films is a desideratum of modern materials science where a material’s properties depend sensitively on elemental composition. We thoroughly investigated femtosecond laser ablation-inductively coupled plasma-mass spectrometry (fs-LA-ICP-MS) as an analytical technique for determination of the stoichiometry of thin films down to the nanometer scale. The use of femtosecond laser ablation allows for precise removal of material with high spatial and depth resolution that can be coupled to an ICP-MS to obtain elemental and isotopic information. We used molecular beam epitaxy-grown thin films of LaPd(x)Sb2 and T´-La2CuO4 to demonstrate themore » capacity of fs-LA-ICP-MS for stoichiometric analysis and the spatial and depth resolution of the technique. Here we demonstrate that the stoichiometric information of thin films with a thickness of ~10 nm or lower can be determined. Furthermore, our results indicate that fs-LA-ICP-MS provides precise information on the thin film-substrate interface and is able to detect the interdiffusion of cations.« less

  20. Femtosecond laser ablation-based mass spectrometry. An ideal tool for stoichiometric analysis of thin films

    SciTech Connect (OSTI)

    LaHaye, Nicole L.; Kurian, Jose; Diwakar, Prasoon K.; Alff, Lambert; Harilal, Sivanandan S.

    2015-08-19

    An accurate and routinely available method for stoichiometric analysis of thin films is a desideratum of modern materials science where a material’s properties depend sensitively on elemental composition. We thoroughly investigated femtosecond laser ablation-inductively coupled plasma-mass spectrometry (fs-LA-ICP-MS) as an analytical technique for determination of the stoichiometry of thin films down to the nanometer scale. The use of femtosecond laser ablation allows for precise removal of material with high spatial and depth resolution that can be coupled to an ICP-MS to obtain elemental and isotopic information. We used molecular beam epitaxy-grown thin films of LaPd(x)Sb2 and T´-La2CuO4 to demonstrate the capacity of fs-LA-ICP-MS for stoichiometric analysis and the spatial and depth resolution of the technique. Here we demonstrate that the stoichiometric information of thin films with a thickness of ~10 nm or lower can be determined. Furthermore, our results indicate that fs-LA-ICP-MS provides precise information on the thin film-substrate interface and is able to detect the interdiffusion of cations.

  1. Training the Masses ? Web-based Laser Safety Training at LLNL

    SciTech Connect (OSTI)

    Sprague, D D

    2004-12-17

    The LLNL work smart standard requires us to provide ongoing laser safety training for a large number of persons on a three-year cycle. In order to meet the standard, it was necessary to find a cost and performance effective method to perform this training. This paper discusses the scope of the training problem, specific LLNL training needs, various training methods used at LLNL, the advantages and disadvantages of these methods and the rationale for selecting web-based laser safety training. The tools and costs involved in developing web-based training courses are also discussed, in addition to conclusions drawn from our training operating experience. The ILSC lecture presentation contains a short demonstration of the LLNL web-based laser safety-training course.

  2. {100}<100> or 45.degree.-rotated {100}<100>, semiconductor-based, large-area, flexible, electronic devices

    DOE Patents [OSTI]

    Goyal, Amit

    2012-05-15

    Novel articles and methods to fabricate the same resulting in flexible, {100}<100> or 45.degree.-rotated {100}<100> oriented, semiconductor-based, electronic devices are disclosed. Potential applications of resulting articles are in areas of photovoltaic devices, flat-panel displays, thermophotovoltaic devices, ferroelectric devices, light emitting diode devices, computer hard disc drive devices, magnetoresistance based devices, photoluminescence based devices, non-volatile memory devices, dielectric devices, thermoelectric devices and quantum dot laser devices.

  3. Visible-light-induced instability in amorphous metal-oxide based TFTs for transparent electronics

    SciTech Connect (OSTI)

    Ha, Tae-Jun

    2014-10-15

    We investigate the origin of visible-light-induced instability in amorphous metal-oxide based thin film transistors (oxide-TFTs) for transparent electronics by exploring the shift in threshold voltage (V{sub th}). A large hysteresis window in amorphous indium-gallium-zinc-oxide (a-IGZO) TFTs possessing large optical band-gap (≈3 eV) was observed in a visible-light illuminated condition whereas no hysteresis window was shown in a dark measuring condition. We also report the instability caused by photo irradiation and prolonged gate bias stress in oxide-TFTs. Larger V{sub th} shift was observed after photo-induced stress combined with a negative gate bias than the sum of that after only illumination stress and only negative gate bias stress. Such results can be explained by trapped charges at the interface of semiconductor/dielectric and/or in the gate dielectric which play a role in a screen effect on the electric field applied by gate voltage, for which we propose that the localized-states-assisted transitions by visible-light absorption can be responsible.

  4. Accelerating Atomic Orbital-based Electronic Structure Calculation via Pole Expansion plus Selected Inversion

    SciTech Connect (OSTI)

    Lin, Lin; Chen, Mohan; Yang, Chao; He, Lixin

    2012-02-10

    We describe how to apply the recently developed pole expansion plus selected inversion (PEpSI) technique to Kohn-Sham density function theory (DFT) electronic structure calculations that are based on atomic orbital discretization. We give analytic expressions for evaluating charge density, total energy, Helmholtz free energy and atomic forces without using the eigenvalues and eigenvectors of the Kohn-Sham Hamiltonian. We also show how to update the chemical potential without using Kohn-Sham eigenvalues. The advantage of using PEpSI is that it has a much lower computational complexity than that associated with the matrix diagonalization procedure. We demonstrate the performance gain by comparing the timing of PEpSI with that of diagonalization on insulating and metallic nanotubes. For these quasi-1D systems, the complexity of PEpSI is linear with respect to the number of atoms. This linear scaling can be observed in our computational experiments when the number of atoms in a nanotube is larger than a few hundreds. Both the wall clock time and the memory requirement of PEpSI is modest. This makes it even possible to perform Kohn-Sham DFT calculations for 10,000-atom nanotubes on a single processor. We also show that the use of PEpSI does not lead to loss of accuracy required in a practical DFT calculation.

  5. Room temperature, hybrid sodium-based flow batteries with multi-electron transfer redox reactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shamie, Jack S.; Liu, Caihong; Shaw, Leon L.; Sprenkle, Vincent L.

    2015-06-11

    We introduce a new concept of hybrid Na-based flow batteries (HNFBs) with a molten Na alloy anode in conjunction with a flowing catholyte separated by a solid Na-ion exchange membrane for grid-scale energy storage. Such HNFBs can operate at ambient temperature, allow catholytes to have multiple electron transfer redox reactions per active ion, offer wide selection of catholyte chemistries with multiple active ions to couple with the highly negative Na alloy anode, and enable the use of both aqueous and non-aqueous catholytes. Further, the molten Na alloy anode permits the decoupled design of power and energy since a large volumemore » of the molten Na alloy can be used with a limited ion-exchange membrane size. In this proof-of-concept study, the feasibility of multielectron transfer redox reactions per active ion and multiple active ions for catholytes has been demonstrated. Furthermore, the critical barriers to mature this new HNFBs have also been explored.« less

  6. Room Temperature, Hybrid Sodium-Based Flow Batteries with Multi-Electron Transfer Redox Reactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shamie, Jack S.; Liu, Caihong; Shaw, Leon L.; Sprenkle, Vincent L.

    2015-06-11

    We introduce a new concept of hybrid Na-based flow batteries (HNFBs) with a molten Na alloy anode in conjunction with a flowing catholyte separated by a solid Na-ion exchange membrane for grid-scale energy storage. Such HNFBs can operate at ambient temperature, allow catholytes to have multiple electron transfer redox reactions per active ion, offer wide selection of catholyte chemistries with multiple active ions to couple with the highly negative Na alloy anode, and enable the use of both aqueous and non-aqueous catholytes. Further, the molten Na alloy anode permits the decoupled design of power and energy since a large volumemoreof the molten Na alloy can be used with a limited ion-exchange membrane size. In this proof-of-concept study, the feasibility of multielectron transfer redox reactions per active ion and multiple active ions for catholytes has been demonstrated. The critical barriers to mature this new HNFBs have also been explored.less

  7. Accelerator-based neutron source using a cold deuterium target with degenerate electrons

    SciTech Connect (OSTI)

    Phillips, R. E.; Ordonez, C. A. [Department of Physics, University of North Texas, Denton, Texas 76203 (United States)] [Department of Physics, University of North Texas, Denton, Texas 76203 (United States)

    2013-07-15

    A neutron generator is considered in which a beam of tritons is incident on a hypothetical cold deuterium target with degenerate electrons. The energy efficiency of neutron generation is found to increase substantially with electron density. Recent reports of potential targets are discussed.

  8. Modeling of free electronic state density in hydrogenic plasmas based on nearest neighbor approximation

    SciTech Connect (OSTI)

    Nishikawa, Takeshi

    2014-07-15

    Most conventional atomic models in a plasma do not treat the effect of the plasma on the free-electron state density. Using a nearest neighbor approximation, the state densities in hydrogenic plasmas for both bound and free electrons were evaluated and the effect of the plasma on the atomic model (especially for the state density of the free electron) was studied. The model evaluates the electron-state densities using the potential distribution formed by the superposition of the Coulomb potentials of two ions. The potential from one ion perturbs the electronic state density on the other. Using this new model, one can evaluate the free-state density without making any ad-hoc assumptions. The resulting contours of the average ionization degree, given as a function of the plasma temperature and density, are shifted slightly to lower temperatures because of the effect of the increasing free-state density.

  9. An algorithm for nonrelativistic quantum-mechanical finite-nuclear-mass variational calculations of nitrogen atom in L = 0, M = 0 states using all-electrons explicitly correlated Gaussian basis functions

    SciTech Connect (OSTI)

    Sharkey, Keeper L.; Adamowicz, Ludwik; Department of Physics, University of Arizona, Tucson, Arizona 85721

    2014-05-07

    An algorithm for quantum-mechanical nonrelativistic variational calculations of L = 0 and M = 0 states of atoms with an arbitrary number of s electrons and with three p electrons have been implemented and tested in the calculations of the ground {sup 4}S state of the nitrogen atom. The spatial part of the wave function is expanded in terms of all-electrons explicitly correlated Gaussian functions with the appropriate pre-exponential Cartesian angular factors for states with the L = 0 and M = 0 symmetry. The algorithm includes formulas for calculating the Hamiltonian and overlap matrix elements, as well as formulas for calculating the analytic energy gradient determined with respect to the Gaussian exponential parameters. The gradient is used in the variational optimization of these parameters. The Hamiltonian used in the approach is obtained by rigorously separating the center-of-mass motion from the laboratory-frame all-particle Hamiltonian, and thus it explicitly depends on the finite mass of the nucleus. With that, the mass effect on the total ground-state energy is determined.

  10. An alpha–gamma coincidence spectrometer based on the Photon–Electron Rejecting Alpha Liquid Scintillation (PERALS®) system

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cadieux, J. R.; Fugate, G. A.; King, III, G. S.

    2015-02-07

    Here, an alpha–gamma coincidence spectrometer has been developed for the measurement of selected actinide isotopes in the presence of high beta/gamma fields. The system is based on a PERALS® liquid scintillation counter for beta/alpha discrimination and was successfully tested with both high purity germanium and bismuth germanate, gamma-ray detectors using conventional analog electronics.

  11. Capillary liquid chromatography using laser-based and mass spectrometric detection. [Capillary zone electrophoresis (CZE); micellar electrokinetic capillary kchromatography (MECC)

    SciTech Connect (OSTI)

    Sepaniak, M.J.; Cook, K.D.

    1992-01-01

    In the years following the 1986 seminal paper (J. Chromatogr. Sci., 24, 347-352) describing modern capillary zone electrophoresis (CZE), the prominence of capillary electrokinetic separation techniques has grown. A related electrochromatographic technique is micellar electrokinetic capillary chromatography (MECC). This report presents a brief synopsis of research efforts during the current 3-year period. In addition to a description of analytical separations-based research, results of efforts to develop and expand spectrometric detection for the techniques is reviewed. Laser fluorometric detection schemes have been successfully advanced. Mass spectrometric research was less fruitful, largely owing to personnel limitations. A regenerable fiber optic sensor was developed that can be used to remotely monitor chemical carcinogens, etc. (DLC)

  12. Group-III nitride based high electron mobility transistor (HEMT) with barrier/spacer layer

    DOE Patents [OSTI]

    Chavarkar, Prashant; Smorchkova, Ioulia P.; Keller, Stacia; Mishra, Umesh; Walukiewicz, Wladyslaw; Wu, Yifeng

    2005-02-01

    A Group III nitride based high electron mobility transistors (HEMT) is disclosed that provides improved high frequency performance. One embodiment of the HEMT comprises a GaN buffer layer, with an Al.sub.y Ga.sub.1-y N (y=1 or y 1) layer on the GaN buffer layer. An Al.sub.x Ga.sub.1-x N (0.ltoreq.x.ltoreq.0.5) barrier layer on to the Al.sub.y Ga.sub.1-y N layer, opposite the GaN buffer layer, Al.sub.y Ga.sub.1-y N layer having a higher Al concentration than that of the Al.sub.x Ga.sub.1-x N barrier layer. A preferred Al.sub.y Ga.sub.1-y N layer has y=1 or y.about.1 and a preferred Al.sub.x Ga.sub.1-x N barrier layer has 0.ltoreq.x.ltoreq.0.5. A 2DEG forms at the interface between the GaN buffer layer and the Al.sub.y Ga.sub.1-y N layer. Respective source, drain and gate contacts are formed on the Al.sub.x Ga.sub.1-x N barrier layer. The HEMT can also comprising a substrate adjacent to the buffer layer, opposite the Al.sub.y Ga.sub.1-y N layer and a nucleation layer between the Al.sub.x Ga.sub.1-x N buffer layer and the substrate.

  13. Oxide-based method of making compound semiconductor films and making related electronic devices

    DOE Patents [OSTI]

    Kapur, Vijay K.; Basol, Bulent M.; Leidholm, Craig R.; Roe, Robert A.

    2000-01-01

    A method for forming a compound film includes the steps of preparing a source material, depositing the source material on a base and forming a preparatory film from the source material, heating the preparatory film in a suitable atmosphere to form a precursor film, and providing suitable material to said precursor film to form the compound film. The source material includes oxide-containing particles including Group IB and IIIA elements. The precursor film includes non-oxide Group IB and IIIA elements. The compound film includes a Group IB-IIIA-VIA compound. The oxides may constitute greater than about 95 molar percent of the Group IB elements and greater than about 95 molar percent of the Group IIIA elements in the source material. Similarly, non-oxides may constitute greater than about 95 molar percent of the Group IB elements and greater than about 95 molar percent of the Group IIIA elements in the precursor film. The molar ratio of Group IB to Group IIIA elements in the source material may be greater than about 0.6 and less than about 1.0, or substantially greater that 1.0, in which case this ratio in the compound film may be reduced to greater than about 0.6 and less than about 1.0. The source material may be prepared as an ink from particles in powder form. The oxide-containing particles may include a dopant, as may the compound film. Compound films including a Group IIB-IVA-VA compound may be substituted using appropriate substitutions in the method. The method, also, is applicable to fabrication of solar cells and other electronic devices.

  14. A brief comparison between grid based real space algorithms andspectrum algorithms for electronic structure calculations

    SciTech Connect (OSTI)

    Wang, Lin-Wang

    2006-12-01

    Quantum mechanical ab initio calculation constitutes the biggest portion of the computer time in material science and chemical science simulations. As a computer center like NERSC, to better serve these communities, it will be very useful to have a prediction for the future trends of ab initio calculations in these areas. Such prediction can help us to decide what future computer architecture can be most useful for these communities, and what should be emphasized on in future supercomputer procurement. As the size of the computer and the size of the simulated physical systems increase, there is a renewed interest in using the real space grid method in electronic structure calculations. This is fueled by two factors. First, it is generally assumed that the real space grid method is more suitable for parallel computation for its limited communication requirement, compared with spectrum method where a global FFT is required. Second, as the size N of the calculated system increases together with the computer power, O(N) scaling approaches become more favorable than the traditional direct O(N{sup 3}) scaling methods. These O(N) methods are usually based on localized orbital in real space, which can be described more naturally by the real space basis. In this report, the author compares the real space methods versus the traditional plane wave (PW) spectrum methods, for their technical pros and cons, and the possible of future trends. For the real space method, the author focuses on the regular grid finite different (FD) method and the finite element (FE) method. These are the methods used mostly in material science simulation. As for chemical science, the predominant methods are still Gaussian basis method, and sometime the atomic orbital basis method. These two basis sets are localized in real space, and there is no indication that their roles in quantum chemical simulation will change anytime soon. The author focuses on the density functional theory (DFT), which is the

  15. Functionalized Thiophene-Based [7]Helicene: Chirooptical Properties versus Electron Delocalization

    SciTech Connect (OSTI)

    Rajca, Andrzej; Pink, Maren; Xiao, Shuzhang; Miyasaka, Makoto; Rajca, Suchada; Das, Kausik; Plessel, Kristin

    2009-11-04

    The functionalized, enantiomerically pure [7]helicene 1 derived from bis(benzodithiophene) functionalized with four heptyl groups is prepared from 1,8-dibromo-4,5-diheptylbenzo[1,2-b:4,3-b']dithiophene building block 2. Such [7]helicene structure, functionalized with bromines at the terminal positions of the helicene inner rim and multiple solubilizing alkyl groups, is an attractive building block for long [n]helicenes and oligo[7]helicenes. Chirooptical properties and the degree of electron delocalization are determined and compared to those of analogous carbon-sulfur [7]helicene and [7]helicenes derived from benzodithiophene to provide a correlation between chirooptical properties and the degree of electron delocalization. [7]Helicene 1 possesses a moderately increased electron delocalization, but its chirooptical properties are similar to those for analogous [7]helicenes with relatively lower electron delocalization, indicating that chirooptical properties are not significantly affected by electron delocalization for this series of [7]helicenes. Molecular structures of racemic [7]helicene 1 and its benzodithiophene building block 2 are confirmed by single-crystal X-ray analysis. Crystals of 2 are chiral and adopt the shape of long, flexible, flat needles that can be readily bent.

  16. Thermoelectric-enhanced, liquid-based cooling of a multi-component electronic system

    SciTech Connect (OSTI)

    Chainer, Timothy J; Graybill, David P; Iyengar, Madhusudan K; Kamath, Vinod; Kochuparambil, Bejoy J; Schmidt, Roger R; Steinke, Mark E

    2015-05-12

    Apparatus and method are provided for facilitating cooling of an electronic component. The apparatus includes a liquid-cooled structure, a thermal conduction path coupling the electronic component and the liquid-cooled structure, a coolant loop in fluid communication with a coolant-carrying channel of the liquid-cooled structure, and an outdoor-air-cooled heat exchange unit coupled to facilitate heat transfer from the liquid-cooled structure via, at least in part, the coolant loop. The thermoelectric array facilitates transfer of heat from the electronic component to the liquid-cooled structure, and the heat exchange unit cools coolant passing through the coolant loop by dissipating heat from the coolant to outdoor ambient air. In one implementation, temperature of coolant entering the liquid-cooled structure is greater than temperature of the outdoor ambient air to which heat is dissipated.

  17. Thermoelectric-enhanced, liquid-based cooling of a multi-component electronic system

    SciTech Connect (OSTI)

    Chainer, Timothy J; Graybill, David P; Iyengar, Madhusudan K; Kamath, Vinod; Kochuparambil, Bejoy J; Schmidt, Roger R; Steinke, Mark E

    2015-11-10

    Methods are provided for facilitating cooling of an electronic component. The methods include providing: a liquid-cooled structure, a thermal conduction path coupling the electronic component and the liquid-cooled structure, a coolant loop in fluid communication with a coolant-carrying channel of the liquid-cooled structure, and an outdoor-air-cooled heat exchange unit coupled to facilitate heat transfer from the liquid-cooled structure via, at least in part, the coolant loop. The thermoelectric array facilitates transfer of heat from the electronic component to the liquid-cooled structure, and the heat exchange unit cools coolant passing through the coolant loop by dissipating heat from the coolant to outdoor ambient air. In one implementation, temperature of coolant entering the liquid-cooled structure is greater than temperature of the outdoor ambient air to which heat is dissipated.

  18. Likelihood-based modification of experimental crystal structure electron density maps

    DOE Patents [OSTI]

    Terwilliger, Thomas C.

    2005-04-16

    A maximum-likelihood method for improves an electron density map of an experimental crystal structure. A likelihood of a set of structure factors {F.sub.h } is formed for the experimental crystal structure as (1) the likelihood of having obtained an observed set of structure factors {F.sub.h.sup.OBS } if structure factor set {F.sub.h } was correct, and (2) the likelihood that an electron density map resulting from {F.sub.h } is consistent with selected prior knowledge about the experimental crystal structure. The set of structure factors {F.sub.h } is then adjusted to maximize the likelihood of {F.sub.h } for the experimental crystal structure. An improved electron density map is constructed with the maximized structure factors.

  19. Monte Carlo based beam model using a photon MLC for modulated electron radiotherapy

    SciTech Connect (OSTI)

    Henzen, D. Manser, P.; Frei, D.; Volken, W.; Born, E. J.; Vetterli, D.; Chatelain, C.; Fix, M. K.; Neuenschwander, H.; Stampanoni, M. F. M.

    2014-02-15

    Purpose: Modulated electron radiotherapy (MERT) promises sparing of organs at risk for certain tumor sites. Any implementation of MERT treatment planning requires an accurate beam model. The aim of this work is the development of a beam model which reconstructs electron fields shaped using the Millennium photon multileaf collimator (MLC) (Varian Medical Systems, Inc., Palo Alto, CA) for a Varian linear accelerator (linac). Methods: This beam model is divided into an analytical part (two photon and two electron sources) and a Monte Carlo (MC) transport through the MLC. For dose calculation purposes the beam model has been coupled with a macro MC dose calculation algorithm. The commissioning process requires a set of measurements and precalculated MC input. The beam model has been commissioned at a source to surface distance of 70 cm for a Clinac 23EX (Varian Medical Systems, Inc., Palo Alto, CA) and a TrueBeam linac (Varian Medical Systems, Inc., Palo Alto, CA). For validation purposes, measured and calculated depth dose curves and dose profiles are compared for four different MLC shaped electron fields and all available energies. Furthermore, a measured two-dimensional dose distribution for patched segments consisting of three 18 MeV segments, three 12 MeV segments, and a 9 MeV segment is compared with corresponding dose calculations. Finally, measured and calculated two-dimensional dose distributions are compared for a circular segment encompassed with a C-shaped segment. Results: For 15 34, 5 5, and 2 2 cm{sup 2} fields differences between water phantom measurements and calculations using the beam model coupled with the macro MC dose calculation algorithm are generally within 2% of the maximal dose value or 2 mm distance to agreement (DTA) for all electron beam energies. For a more complex MLC pattern, differences between measurements and calculations are generally within 3% of the maximal dose value or 3 mm DTA for all electron beam energies. For the two

  20. Temporal profile measurements of relativistic electron bunch based on wakefield generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bettoni, S.; Craievich, P.; Lutman, A. A.; Pedrozzi, M.

    2016-02-25

    A complete characterization of the time-resolved longitudinal beam phase space is important to optimize the final performances of an accelerator, and in particular this is crucial for Free Electron Laser (FEL) facilities. In this study we propose a novel method to characterize the profile of a relativistic electron bunch by passively streaking the beam using its self-interaction with the transverse wakefield excited by the bunch itself passing off-axis through a dielectric-lined or a corrugated waveguide. Results of a proof-of-principle experiment at the SwissFEL Injector Test Facility are discussed.

  1. Clock asynchrony and mass variation

    SciTech Connect (OSTI)

    Gruber, R.P.; Brahm, D.E.

    1993-04-01

    Many theories have been proposed in which particle masses vary with time. In a world with varying particle masses, clocks become asynchronous and metersticks inconsistent. By combining two or more clocks with different known dependences on mass, one can construct a nearly invariant clock, and measure the rate of mass variation. If the proton and electron masses vary differently, then certain equations must be applied to predict a clock's dependence on each. 8 refs.

  2. A study of planar anchor groups for graphene-based single-molecule electronics

    SciTech Connect (OSTI)

    Bailey, Steven; Visontai, David; Lambert, Colin J.; Bryce, Martin R.; Frampton, Harry; Chappell, David

    2014-02-07

    To identify families of stable planar anchor groups for use in single molecule electronics, we report detailed results for the binding energies of two families of anthracene and pyrene derivatives adsorbed onto graphene. We find that all the selected derivatives functionalized with either electron donating or electron accepting substituents bind more strongly to graphene than the parent non-functionalized anthracene or pyrene. The binding energy is sensitive to the detailed atomic alignment of substituent groups over the graphene substrate leading to larger than expected binding energies for –OH and –CN derivatives. Furthermore, the ordering of the binding energies within the anthracene and pyrene series does not simply follow the electron affinities of the substituents. Energy barriers to rotation or displacement on the graphene surface are much lower than binding energies for adsorption and therefore at room temperature, although the molecules are bound to the graphene, they are almost free to move along the graphene surface. Binding energies can be increased by incorporating electrically inert side chains and are sensitive to the conformation of such chains.

  3. X-ray FEL based on harmonics generation and electron beam outcoupling

    SciTech Connect (OSTI)

    Litvinenko, V.N.; Burnham, B.

    1995-12-31

    Electron beam outcoupling was suggested by N. A. Vinokurov as a method of optics independent outcoupling for high power FELs. The bunching of the electron beam is provided in a master oscillator. The prebunched electron beam then radiates coherently into an additional wiggler called the radiator. The electron beam is turned by an achromatic bend into this wiggler and its radiation propagates with a small angle with respect to the OK-4 optical axis. Thus, the radiation will pass around the mirror of the master oscillator optical cavity and can then be utilized. This scheme is perfectly suited for harmonic generation if the radiator wiggler is tuned on one of the master oscillator wavelength harmonics. This system is reminiscent of a klystron operating on a harmonic of the reference frequency. In this paper we present the theory of this device, its spectral and spatial characteristics of radiation, the optimization of the master oscillator, the achromatic bend and bunching for harmonic generation, and influence of beam parameters (energy spread, emittance, etc.) on generated power. Examples of possible storage ring and linac driven systems are discussed.

  4. Proof-of-principle experiment for FEL-based coherent electron cooling

    SciTech Connect (OSTI)

    Litvinenko, V.N.; Belomestnykh, S.; Ben-Zvi, I.; Brutus, J.C.; Fedotov, A.; Hao, Y.; Kayran, D.; Mahler, G.; Marusic, A.; Meng, W.; McIntyre, G.; Minty, M.; Ptitsyn, V.; Pinayev, I.; Rao, T.; Roser, T.; Sheehy, B.; Tepikian, S.; Than, Y.; Trbojevic, D.; Tuozzolo, J.; Wang, G.; Yakimenko, V.; Poelker, M.; Hutton, A.; Kraft, G.; Rimmer, R.; Bruhwiler, D.L.; Abell, D.T.; Nieter, C.; Ranjbar, V.; Schwartz, B.T.; Vobly, P.; Kholopov, M.; Shevchenko, O.; Mcintosh, P.; Wheelhouse, A.

    2011-08-21

    Coherent electron cooling (CEC) has a potential to significantly boost luminosity of high-energy, high-intensity hadron-hadron and electron-hadron colliders. In a CEC system, a hadron beam interacts with a cooling electron beam. A perturbation of the electron density caused by ions is amplified and fed back to the ions to reduce the energy spread and the emittance of the ion beam. To demonstrate the feasibility of CEC we propose a proof-of-principle experiment at RHIC using SRF linac. In this paper, we describe the setup for CeC installed into one of RHIC's interaction regions. We present results of analytical estimates and results of initial simulations of cooling a gold-ion beam at 40 GeV/u energy via CeC. We plan to complete the program in five years. During first two years we will build coherent electron cooler in IP2 of RHIC. In parallel we will develop complete package of computer simulation tools for the start-to-end simulation predicting exact performance of a CeC. The later activity will be the core of Tech X involvement into the project. We will use these tools to predict the performance of our CeC device. The experimental demonstration of the CeC will be undertaken in years three to five of the project. The goal of this experiment is to demonstrate the cooling of ion beam and to compare its measured performance with predictions made by us prior to the experiments.

  5. CORONAL MASS EJECTION PROPAGATION AND EXPANSION IN THREE-DIMENSIONAL SPACE IN THE HELIOSPHERE BASED ON STEREO/SECCHI OBSERVATIONS

    SciTech Connect (OSTI)

    Poomvises, Watanachak; Zhang Jie; Olmedo, Oscar

    2010-07-10

    We report on several new findings regarding the kinematic and morphological evolution of coronal mass ejections (CMEs) in the inner heliosphere using the unprecedented STEREO/SECCHI observations. The CME tracking is based on the three-dimensional Raytrace model, which is free of the projection effect, resulting in true CME velocities. We also measure the cross section size of the CME and hence its expansion velocity. For the four major CME events investigated, we find that their leading edge (LE) velocity converges from an initial range between 400 km s{sup -1} and 1500 km s{sup -1} at 5-10 R{sub sun} to a narrow range between 500 km s{sup -1} and 750 km s{sup -1} at 50 R{sub sun}. The expansion velocity is also found to converge into a narrow range between 75 km s{sup -1} and 175 km s{sup -1}. Both LE and expansion velocities are nearly constant after 50 R{sub sun}. We further find that the acceleration of CMEs in the inner heliosphere from {approx}10 to 90 R{sub sun} can be described by an exponential function, with an initial value as large as {approx}-80 m s{sup -2} but exponentially decreasing to almost zero (more precisely, less than {+-}5 m s{sup -2} considering the uncertainty of measurements). These results provide important observational constraints on understanding CME dynamics in interplanetary space.

  6. HELIOSPHERIC PROPAGATION OF CORONAL MASS EJECTIONS: COMPARISON OF NUMERICAL WSA-ENLIL+CONE MODEL AND ANALYTICAL DRAG-BASED MODEL

    SciTech Connect (OSTI)

    Vrnak, B.; ic, T.; Dumbovi?, M.; Temmer, M.; Mstl, C.; Veronig, A. M.; Taktakishvili, A.; Mays, M. L.; Odstr?il, D. E-mail: tzic@geof.hr E-mail: manuela.temmer@uni-graz.at E-mail: astrid.veronig@uni-graz.at E-mail: m.leila.mays@nasa.gov

    2014-08-01

    Real-time forecasting of the arrival of coronal mass ejections (CMEs) at Earth, based on remote solar observations, is one of the central issues of space-weather research. In this paper, we compare arrival-time predictions calculated applying the numerical ''WSA-ENLIL+Cone model'' and the analytical ''drag-based model'' (DBM). Both models use coronagraphic observations of CMEs as input data, thus providing an early space-weather forecast two to four days before the arrival of the disturbance at the Earth, depending on the CME speed. It is shown that both methods give very similar results if the drag parameter ? = 0.1 is used in DBM in combination with a background solar-wind speed of w = 400 km s{sup 1}. For this combination, the mean value of the difference between arrival times calculated by ENLIL and DBM is ?-bar =0.099.0 hr with an average of the absolute-value differences of |?|-bar =7.1 hr. Comparing the observed arrivals (O) with the calculated ones (C) for ENLIL gives O C = 0.3 16.9 hr and, analogously, O C = +1.1 19.1 hr for DBM. Applying ? = 0.2 with w = 450 km s{sup 1} in DBM, one finds O C = 1.7 18.3 hr, with an average of the absolute-value differences of 14.8 hr, which is similar to that for ENLIL, 14.1 hr. Finally, we demonstrate that the prediction accuracy significantly degrades with increasing solar activity.

  7. Attosecond Thomson-scattering x-ray source driven by laser-based electron acceleration

    SciTech Connect (OSTI)

    Luo, W.; Zhuo, H. B.; Yu, T. P.; Ma, Y. Y.; Song, Y. M.; Zhu, Z. C.; Yu, M. Y.

    2013-10-21

    The possibility of producing attosecond x-rays through Thomson scattering of laser light off laser-driven relativistic electron beams is investigated. For a ≤200-as, tens-MeV electron bunch produced with laser ponderomotive-force acceleration in a plasma wire, exceeding 10{sup 6} photons/s in the form of ∼160 as pulses in the range of 3–300 keV are predicted, with a peak brightness of ≥5 × 10{sup 20} photons/(s mm{sup 2} mrad{sup 2} 0.1% bandwidth). Our study suggests that the physical scheme discussed in this work can be used for an ultrafast (attosecond) x-ray source, which is the most beneficial for time-resolved atomic physics, dubbed “attosecond physics.”.

  8. Metal complex-based electron-transfer mediators in dye-sensitized solar cells

    DOE Patents [OSTI]

    Elliott, C. Michael; Sapp, Shawn A.; Bignozzi, Carlo Alberto; Contado, Cristiano; Caramori, Stefano

    2006-03-28

    This present invention provides a metal-ligand complex and methods for using and preparing the same. In particular, the metal-ligand complex of the present invention is of the formula: L.sub.a-M-X.sub.b where L, M, X, a, and b are those define herein. The metal-ligand complexes of the present invention are useful in a variety of applications including as electron-transfer mediators in dye-sensitized solar cells and related photoelectrochromic devices.

  9. A new interferometry-based electron density fluctuation diagnostic on Alcator C-Mod

    SciTech Connect (OSTI)

    Kasten, C. P.; Irby, J. H.; Murray, R.; White, A. E.; Pace, D. C.

    2012-10-15

    The two-color interferometry diagnostic on the Alcator C-Mod tokamak has been upgraded to measure fluctuations in the electron density and density gradient for turbulence and transport studies. Diagnostic features and capabilities are described. In differential mode, fast phase demodulation electronics detect the relative phase change between ten adjacent, radially-separated ({Delta}R= 1.2 cm, adjustable), vertical-viewing chords, which allows for measurement of the line-integrated electron density gradient. The system can be configured to detect the absolute phase shift of each chord by comparison to a local oscillator, measuring the line-integrated density. Each chord is sensitive to density fluctuations with k{sub R} < 20.3 cm{sup -1} and is digitized at up to 10 MS/s, resolving aspects of ion temperature gradient-driven modes and other long-wavelength turbulence. Data from C-Mod discharges is presented, including observations of the quasi-coherent mode in enhanced D-alpha H-mode plasmas and the weakly coherent mode in I-mode.

  10. Trapping in GaN-based metal-insulator-semiconductor transistors: Role of high drain bias and hot electrons

    SciTech Connect (OSTI)

    Meneghini, M. Bisi, D.; Meneghesso, G.; Zanoni, E.

    2014-04-07

    This paper describes an extensive analysis of the role of off-state and semi-on state bias in inducing the trapping in GaN-based power High Electron Mobility Transistors. The study is based on combined pulsed characterization and on-resistance transient measurements. We demonstrate thatby changing the quiescent bias point from the off-state to the semi-on stateit is possible to separately analyze two relevant trapping mechanisms: (i) the trapping of electrons in the gate-drain access region, activated by the exposure to high drain bias in the off-state; (ii) the trapping of hot-electrons within the AlGaN barrier or the gate insulator, which occurs when the devices are operated in the semi-on state. The dependence of these two mechanisms on the bias conditions and on temperature, and the properties (activation energy and cross section) of the related traps are described in the text.

  11. Silicon Based Solid Oxide Fuel Cell Chip for Portable Consumer Electronics -- Final Technical Report

    SciTech Connect (OSTI)

    Alan Ludwiszewski

    2009-06-29

    LSIs fuel cell uses efficient Solid Oxide Fuel Cell (SOFC) technology, is manufactured using Micro Electrical Mechanical System (MEMS) fabrication methods, and runs on high energy fuels, such as butane and ethanol. The companys Fuel Cell on a Chip technology enables a form-factor battery replacement for portable electronic devices that has the potential to provide an order-of-magnitude run-time improvement over current batteries. Further, the technology is clean and environmentally-friendly. This Department of Energy funded project focused on accelerating the commercialization and market introduction of this technology through improvements in fuel cell chip power output, lifetime, and manufacturability.

  12. Development of Tandem, Double-Focusing, Electron Impact, Gas Source Mass Spectrometer for Measurement of Rare Double-Substituted Isotoplogues in Geochemistry

    SciTech Connect (OSTI)

    Young, Edward D.

    2015-07-30

    This project culminated in construction and delivery of the world’s first large-radius gas-source isotope ratio mass spectrometer that permits unparalleled analyses of the stable isotopic composition of methane gas. The instrument, referred to as the “Panorama” and installed at UCLA in March 2015, can now be used to determine the relative abundances of rare isotopic species of methane that serve as tracers of temperature of formation and/or subsequent processing of gas. With this technology we can begin to delineate different sources and sinks of methane isotopically in ways not possible until now.

  13. Advanced solvent based methods for molecular characterization of soil organic matter by high-resolution mass spectrometry

    SciTech Connect (OSTI)

    Tfaily, Malak M.; Chu, Rosalie K.; Tolic, Nikola; Roscioli, Kristyn M.; Anderton, Christopher R.; Pasa-Tolic, Ljiljana; Robinson, Errol W.; Hess, Nancy J.

    2015-05-19

    Soil organic matter (SOM) a complex, heterogeneous mixture of above and belowground plant litter and animal and microbial residues at various degrees of decomposition, is a key reservoir for carbon (C) and nutrient biogeochemical cycling in soil based ecosystems. A limited understanding of the molecular composition of SOM limits the ability to routinely decipher chemical processes within soil and predict accurately how terrestrial carbon fluxes will response to changing climatic conditions and land use. To elucidate the molecular-level structure of SOM, we selectively extracted a broad range of intact SOM compounds by a combination of different organic solvents from soils with a wide range of C content. Our use of Electrospray ionization (ESI) coupled with Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS) and a suite of solvents with varying polarity significantly expands the inventory of the types of organic molecules present in soils. Specifically, we found that hexane is selective for lipid-like compounds with very low O:C ratios; water was selective for carbohydrates with high O:C ratios; acetonitrile preferentially extracts lignin, condensed structures, and tannin poly phenolic compounds with O:C > 0.5; methanol has higher selectivity towards compounds characterized with low O:C < 0.5; and hexane, MeOH, ACN and water solvents increase the number and types of organic molecules extracted from soil for a broader range of chemically diverse soil types. Our study of SOM molecules by ESI-FTICR MS revealed new insight into the molecular-level complexity of organics contained in soils.

  14. Ultrahigh-spatial-resolution chemical and magnetic imaging by laser-based photoemission electron microscopy

    SciTech Connect (OSTI)

    Taniuchi, Toshiyuki Kotani, Yoshinori; Shin, Shik

    2015-02-15

    We report the first experiments carried out on a new chemical and magnetic imaging system, which combines the high spatial resolution of a photoemission electron microscope (PEEM) with a continuous-wave deep-ultraviolet laser. Threshold photoemission is sensitive to the chemical and magnetic structures of the surface of materials. The spatial resolution of PEEM is limited by space charging when using pulsed photon sources as well as aberrations in the electron optics. We show that the use of a continuous-wave laser enabled us to overcome such a limit by suppressing the space-charge effect, allowing us to obtain a resolution of approximately 2.6 nm. With this system, we demonstrated the imaging of surface reconstruction domains on Si(001) by linear dichroism with normal incidence of the laser beam. We also succeeded in magnetic imaging of thin films with the use of magnetic circular dichroism near the Fermi level. The unique features of the ultraviolet laser will give us fast switching of the incident angles and polarizations of the photon source, which will be useful for the characterization of antiferromagnetic materials as well as ferromagnetic materials.

  15. Synchrotron radiation-based Mössbauer spectra of {sup 174}Yb measured with internal conversion electrons

    SciTech Connect (OSTI)

    Masuda, Ryo Kobayashi, Yasuhiro; Kitao, Shinji; Kurokuzu, Masayuki; Saito, Makina; Mitsui, Takaya; Iga, Fumitoshi; Seto, Makoto

    2014-02-24

    A detection system for synchrotron-radiation (SR)-based Mössbauer spectroscopy was developed to enhance the nuclear resonant scattering counting rate and thus increase the available nuclides. In the system, a windowless avalanche photodiode (APD) detector was combined with a vacuum cryostat to detect the internal conversion (IC) electrons and fluorescent X-rays accompanied by nuclear de-excitation. As a feasibility study, the SR-based Mössbauer spectrum using the 76.5 keV level of {sup 174}Yb was observed without {sup 174}Yb enrichment of the samples. The counting rate was five times higher than that of our previous system, and the spectrum was obtained within 10 h. This result shows that nuclear resonance events can be more efficiently detected by counting IC electrons for nuclides with high IC coefficients. Furthermore, the windowless detection system enables us to place the sample closer to the APD elements and is advantageous for nuclear resonant inelastic scattering measurements. Therefore, this detection system can not only increase the number of nuclides accessible in SR-based Mössbauer spectroscopy but also allows the nuclear resonant inelastic scattering measurements of small single crystals or enzymes with dilute probe nuclides that are difficult to measure with the previous detection system.

  16. Investigation of Electron Transfer-Based Photonic and Electro-Optic Materials and Devices

    SciTech Connect (OSTI)

    Bromenshenk, Jerry J; Abbott, Edwin H; Dickensheets, David; Donovan, Richard P; Hobbs, J D; Spangler, Lee; McGuirl, Michele A; Spangler, Charles; Rebane, Aleksander; Rosenburg, Edward; Schmidt, V H; Singel, David J

    2008-03-28

    Montana's state program began its sixth year in 2006. The project's research cluster focused on physical, chemical, and biological materials that exhibit unique electron-transfer properties. Our investigators have filed several patents and have also have established five spin-off businesses (3 MSU, 2 UM) and a research center (MT Tech). In addition, this project involved faculty and students at three campuses (MSU, UM, MT Tech) and has a number of under-represented students, including 10 women and 5 Native Americans. In 2006, there was an added emphasis on exporting seminars and speakers via the Internet from UM to Chief Dull Knife Community College, as well as work with the MT Department of Commerce to better educate our faculty regarding establishing small businesses, licensing and patent issues, and SBIR program opportunities.

  17. A Test Facility for MEIC ERL Circulator Ring Based Electron Cooler...

    Office of Scientific and Technical Information (OSTI)

    repetition rate up to 750 MHz is required for MEIC. The present cooler design concept is based on a magnetized photo-cathode SRF gun, an SRF ERL and a compact circulator ring. ...

  18. An accurate online calibration system based on combined clamp-shape coil for high voltage electronic current transformers

    SciTech Connect (OSTI)

    Li, Zhen-hua; Li, Hong-bin; Zhang, Zhi; State Key Laboratory of Advanced Electromagnetic Engineering and Technology, Wuhan 430074

    2013-07-15

    Electronic transformers are widely used in power systems because of their wide bandwidth and good transient performance. However, as an emerging technology, the failure rate of electronic transformers is higher than that of traditional transformers. As a result, the calibration period needs to be shortened. Traditional calibration methods require the power of transmission line be cut off, which results in complicated operation and power off loss. This paper proposes an online calibration system which can calibrate electronic current transformers without power off. In this work, the high accuracy standard current transformer and online operation method are the key techniques. Based on the clamp-shape iron-core coil and clamp-shape air-core coil, a combined clamp-shape coil is designed as the standard current transformer. By analyzing the output characteristics of the two coils, the combined clamp-shape coil can achieve verification of the accuracy. So the accuracy of the online calibration system can be guaranteed. Moreover, by employing the earth potential working method and using two insulating rods to connect the combined clamp-shape coil to the high voltage bus, the operation becomes simple and safe. Tests in China National Center for High Voltage Measurement and field experiments show that the proposed system has a high accuracy of up to 0.05 class.

  19. Plasmonic terahertz detectors based on a high-electron mobility GaAs/AlGaAs heterostructure

    SciTech Connect (OSTI)

    Bia?ek, M. Witowski, A. M.; Grynberg, M.; ?usakowski, J.; Orlita, M.; Potemski, M.; Czapkiewicz, M.; Umansky, V.

    2014-06-07

    In order to characterize magnetic field (B) tunable THz plasmonic detectors, spectroscopy experiments were carried out at liquid helium temperatures and high magnetic fields on devices fabricated on a high electron mobility GaAs/AlGaAs heterostructure. The samples were either gated (the gate of a meander shape) or ungated. Spectra of a photovoltage generated by THz radiation were obtained as a function of B at a fixed THz excitation from a THz laser or as a function of THz photon frequency at a fixed B with a Fourier spectrometer. In the first type of measurements, the wave vector of magnetoplasmons excited was defined by geometrical features of samples. It was also found that the magnetoplasmon spectrum depended on the gate geometry which gives an additional parameter to control plasma excitations in THz detectors. Fourier spectra showed a strong dependence of the magnetoplasmon resonance amplitude on the conduction-band electron filling factor which was explained within a model of the electron gas heating with THz radiation. The study allows to define both the advantages and limitations of plasmonic devices based on high-mobility GaAs/AlGaAs heterostructures for THz detection at low temperatures and high magnetic fields.

  20. Carrier density independent scattering rate in SrTiO₃-based electron liquids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mikheev, Evgeny; Raghavan, Santosh; Zhang, Jack Y.; Marshall, Patrick B.; Kajdos, Adam P.; Balents, Leon; Stemmer, Susanne

    2016-02-10

    We examine the carrier density dependence of the scattering rate in two- and three-dimensional electron liquids in SrTiO3 in the regime where it scales with Tn (T is the temperature and n ≤ 2) in the cases when it is varied by electrostatic control and chemical doping, respectively. It is shown that the scattering rate is independent of the carrier density. This is contrary to the expectations from Landau Fermi liquid theory, where the scattering rate scales inversely with the Fermi energy (EF). We discuss that the behavior is very similar to systems traditionally identified as non-Fermi liquids (n

  1. Carrier density independent scattering rate in SrTiO3-based electron liquids

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mikheev, Evgeny; Raghavan, Santosh; Zhang, Jack Y.; Marshall, Patrick B.; Kajdos, Adam P.; Balents, Leon; Stemmer, Susanne

    2016-02-10

    We examine the carrier density dependence of the scattering rate in two- and three-dimensional electron liquids in SrTiO3 in the regime where it scales with Tn (T is the temperature and n ≤ 2) in the cases when it is varied by electrostatic control and chemical doping, respectively. It is shown that the scattering rate is independent of the carrier density. This is contrary to the expectations from Landau Fermi liquid theory, where the scattering rate scales inversely with the Fermi energy (EF). We discuss that the behavior is very similar to systems traditionally identified as non-Fermi liquids (n

  2. Novel Iron-based ternary amorphous oxide semiconductor with very high transparency, electronic conductivity, and mobility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malasi, A.; Taz, H.; Farah, A.; Patel, M.; Lawrie, Benjamin; Pooser, R.; Baddorf, A.; Duscher, G.; Kalyanaraman, R.

    2015-12-16

    We report that ternary metal oxides of type (Me)2O3 with the primary metal (Me) constituent being Fe (66 atomic (at.) %) along with the two Lanthanide elements Tb (10 at.%) and Dy (24 at.%) can show excellent semiconducting transport properties. Thin films prepared by pulsed laser deposition at room temperature followed by ambient oxidation showed very high electronic conductivity (>5 × 104 S/m) and Hall mobility (>30 cm2/V-s). These films had an amorphous microstructure which was stable to at least 500 °C and large optical transparency with a direct band gap of 2.85 ± 0.14 eV. This material shows emergentmore » semiconducting behavior with significantly higher conductivity and mobility than the constituent insulating oxides. In conclusion, since these results demonstrate a new way to modify the behaviors of transition metal oxides made from unfilled d- and/or f-subshells, a new class of functional transparent conducting oxide materials could be envisioned.« less

  3. Novel Iron-based ternary amorphous oxide semiconductor with very high transparency, electronic conductivity, and mobility

    SciTech Connect (OSTI)

    Malasi, A.; Taz, H.; Farah, A.; Patel, M.; Lawrie, Benjamin; Pooser, R.; Baddorf, A.; Duscher, G.; Kalyanaraman, R.

    2015-12-16

    We report that ternary metal oxides of type (Me)2O3 with the primary metal (Me) constituent being Fe (66 atomic (at.) %) along with the two Lanthanide elements Tb (10 at.%) and Dy (24 at.%) can show excellent semiconducting transport properties. Thin films prepared by pulsed laser deposition at room temperature followed by ambient oxidation showed very high electronic conductivity (>5 × 104 S/m) and Hall mobility (>30 cm2/V-s). These films had an amorphous microstructure which was stable to at least 500 °C and large optical transparency with a direct band gap of 2.85 ± 0.14 eV. This material shows emergent semiconducting behavior with significantly higher conductivity and mobility than the constituent insulating oxides. In conclusion, since these results demonstrate a new way to modify the behaviors of transition metal oxides made from unfilled d- and/or f-subshells, a new class of functional transparent conducting oxide materials could be envisioned.

  4. Ultrafast harmonic rf kicker design and beam dynamics analysis for an energy recovery linac based electron circulator cooler ring

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Yulu; Wang, Haipeng; Rimmer, Robert A.; Wang, Shaoheng; Guo, Jiquan

    2016-08-01

    An ultrafast kicker system is being developed for the energy recovery linac (ERL) based electron circulator cooler ring (CCR) in the proposed Jefferson Lab Electron Ion Collider (JLEIC, previously named MEIC). In the CCR, the injected electron bunches can be recirculated while performing ion cooling for 10–30 turns before the extraction, thus reducing the recirculation beam current in the ERL to 1/10–1/30 (150mA–50 mA) of the cooling beam current (up to 1.5 A). Assuming a bunch repetition rate of 476.3 MHz and a recirculating factor of 10 in the CCR, the kicker is required to operate at a pulse repetitionmore » rate of 47.63 MHz with pulse width of around 2 ns, so that only every 10th bunch in the CCR will experience a transverse kick while the rest of the bunches will not be disturbed. Such a kicker pulse can be synthesized by ten harmonic modes of the 47.63 MHz kicker pulse repetition frequency, using up to four quarter wavelength resonator (QWR) based deflecting cavities. In this paper, several methods to synthesize such a kicker waveform will be discussed and a comparison of their beam dynamics performance is made using ELEGANT. Four QWR cavities are envisaged with high transverse shunt impedance requiring less than 100 W of total rf power for a Flat-Top kick pulse. Multipole fields due to the asymmetry of this type of cavity are analyzed. The transverse emittance growth due to the sextupole component is simulated in ELEGANT. In conclusion, off-axis injection and extraction issues and beam optics using a multicavity kick-drift scheme will also be discussed.« less

  5. Direct electrical observation of plasma wave-related effects in GaN-based two-dimensional electron gases

    SciTech Connect (OSTI)

    Zhao, Y.; Chen, W.; Li, W.; Zhu, M.; Yue, Y.; Song, B.; Encomendero, J.; Xing, H.; Fay, P.; Sensale-Rodriguez, B.

    2014-10-27

    In this work, signatures of plasma waves in GaN-based high electron mobility transistors were observed by direct electrical measurement at room temperature. Periodic grating-gate device structures were fabricated and characterized by on-wafer G-band (140220?GHz) s-parameter measurements as a function of gate bias voltage and device geometry. A physics-based equivalent circuit model was used to assist in interpreting the measured s-parameters. The kinetic inductance extracted from the measurement data matches well with theoretical predictions, consistent with direct observation of plasma wave-related effects in GaN-channel devices at room temperature. This observation of electrically significant room-temperature plasma-wave effects in GaN-channel devices may have implications for future millimeter-wave and THz device concepts and designs.

  6. Colossal Magnetoresistive Manganite Based Fast Bolometric X-ray Sensors for Total Energy Measurements of Free Electron Lasers

    SciTech Connect (OSTI)

    Yong, G J; Kolagani, R M; Adhikari, S; Mundle, R M; Cox, D W; Davidson III, A L; Liang, Y; Drury, O B; Hau-Riege, S P; Gardner, C; Ables, E; Bionta, R M; Friedrich, S

    2008-12-17

    Bolometric detectors based on epitaxial thin films of rare earth perovskite manganites have been proposed as total energy monitors for X-ray pulses at the Linac Coherent Light Source free electron laser. We demonstrate such a detector scheme based on epitaxial thin films of the perovskite manganese oxide material Nd{sub 0.67}Sr{sub x0.33}MnO{sub 3}, grown by pulsed laser deposition on buffered silicon substrates. The substrate and sensor materials are chosen to meet the conflicting requirements of radiation hardness, sensitivity, speed and linearity over a dynamic range of three orders of magnitude. The key challenge in the material development is the integration of the sensor material with Si. Si is required to withstand the free electron laser pulse impact and to achieve a readout speed three orders of magnitude faster than conventional cryoradiometers for compatibility with the Linac Coherent Light Source pulse rate. We discuss sensor material development and the photoresponse of prototype devices. This Linac Coherent Light Source total energy monitor represents the first practical application of manganite materials as bolometric sensors.

  7. Characterisation of amorphous silica in air-oxidised Ti3SiC2 at 500-1000 °C using secondary-ion mass spectrometry, nuclear magnetic resonance and transmission electron microscopy

    SciTech Connect (OSTI)

    Pang, W K; Low, I M; Hanna, J V

    2010-05-18

    In this paper we have described the use of secondary-ion mass spectrometry (SIMS), solid state {sup 29}Si magic-angle-spinning (MAS) nuclear magnetic resonance (NMR) and transmission electron microscopy (TEM) to detect the existence of amorphous silica in Ti{sub 3}SiC{sub 2} oxidised at 500-1000 C. The formation of amorphous SiO{sub 2} and growth of crystalline TiO{sub 2} with temperature was monitored using dynamic SIMS and synchrotron radiation diffraction. A duplex structure with an outer TiO{sub 2}-rich layer and an inner mixed layer of SiO{sub 2} and TiO{sub 2} was observed. Results of NMR and TEM verified for the first time the direct evidence of amorphous silica formation during the oxidation of Ti{sub 3}SiC{sub 2} at the temperature range 500-1000 C.

  8. Polymer electronic devices and materials.

    SciTech Connect (OSTI)

    Schubert, William Kent; Baca, Paul Martin; Dirk, Shawn M.; Anderson, G. Ronald; Wheeler, David Roger

    2006-01-01

    Polymer electronic devices and materials have vast potential for future microsystems and could have many advantages over conventional inorganic semiconductor based systems, including ease of manufacturing, cost, weight, flexibility, and the ability to integrate a wide variety of functions on a single platform. Starting materials and substrates are relatively inexpensive and amenable to mass manufacturing methods. This project attempted to plant the seeds for a new core competency in polymer electronics at Sandia National Laboratories. As part of this effort a wide variety of polymer components and devices, ranging from simple resistors to infrared sensitive devices, were fabricated and characterized. Ink jet printing capabilities were established. In addition to promising results on prototype devices the project highlighted the directions where future investments must be made to establish a viable polymer electronics competency.

  9. Low temperature synthesis of diamond-based nano-carbon composite materials with high electron field emission properties

    SciTech Connect (OSTI)

    Saravanan, A.; Huang, B. R.; Yeh, C. J.; Leou, K. C.; Lin, I. N.

    2015-06-08

    A diamond-based nano-carbon composite (d/NCC) material, which contains needle-like diamond grains encased with the nano-graphite layers, was synthesized at low substrate temperature via a bias enhanced growth process using CH{sub 4}/N{sub 2} plasma. Such a unique granular structure renders the d/NCC material very conductive (??=?714.8?S/cm), along with superior electron field emission (EFE) properties (E{sub 0}?=?4.06?V/?m and J{sub e}?=?3.18?mA/cm{sup 2}) and long lifetime (??=?842?min at 2.41?mA/cm{sup 2}). Moreover, the electrical conductivity and EFE behavior of d/NCC material can be tuned in a wide range that is especially useful for different kind of applications.

  10. Simulation Studies of Beam-Beam Effects of a Ring-Ring Electron-Ion Collider Based on CEBAF

    SciTech Connect (OSTI)

    Yuhong Zhang,Ji Qiang

    2009-05-01

    The collective beam-beam effect can potentially cause a rapid growth of beam sizes and reduce the luminosity of a collider to an unacceptably low level. The ELIC, a proposed ultra high luminosity electron-ion collider based on CEBAF, employs high repetition rate crab crossing colliding beams with very small bunch transverse sizes and very short bunch lengths, and collides them at up to 4 interaction points with strong final focusing. All of these features can make the beam-beam effect challenging. In this paper, we present simulation studies of the beam-beam effect in ELIC using a self-consistent strong-strong beam-beam simulation code developed at Lawrence Berkeley National Laboratory. This simulation study is used for validating the ELIC design and for searching for an optimal parameter set.

  11. Electronic and optical device applications of hollow cathode plasma assisted atomic layer deposition based GaN thin films

    SciTech Connect (OSTI)

    Bolat, Sami Tekcan, Burak; Ozgit-Akgun, Cagla; Biyikli, Necmi; Okyay, Ali Kemal

    2015-01-15

    Electronic and optoelectronic devices, namely, thin film transistors (TFTs) and metalsemiconductormetal (MSM) photodetectors, based on GaN films grown by hollow cathode plasma-assisted atomic layer deposition (PA-ALD) are demonstrated. Resistivity of GaN thin films and metal-GaN contact resistance are investigated as a function of annealing temperature. Effect of the plasma gas and postmetallization annealing on the performances of the TFTs as well as the effect of the annealing on the performance of MSM photodetectors are studied. Dark current to voltage and responsivity behavior of MSM devices are investigated as well. TFTs with the N{sub 2}/H{sub 2} PA-ALD based GaN channels are observed to have improved stability and transfer characteristics with respect to NH{sub 3} PA-ALD based transistors. Dark current of the MSM photodetectors is suppressed strongly after high-temperature annealing in N{sub 2}:H{sub 2} ambient.

  12. Final LDRD report : development of sample preparation methods for ChIPMA-based imaging mass spectrometry of tissue samples.

    SciTech Connect (OSTI)

    Maharrey, Sean P.; Highley, Aaron M.; Behrens, Richard, Jr.; Wiese-Smith, Deneille

    2007-12-01

    The objective of this short-term LDRD project was to acquire the tools needed to use our chemical imaging precision mass analyzer (ChIPMA) instrument to analyze tissue samples. This effort was an outgrowth of discussions with oncologists on the need to find the cellular origin of signals in mass spectra of serum samples, which provide biomarkers for ovarian cancer. The ultimate goal would be to collect chemical images of biopsy samples allowing the chemical images of diseased and nondiseased sections of a sample to be compared. The equipment needed to prepare tissue samples have been acquired and built. This equipment includes an cyro-ultramicrotome for preparing thin sections of samples and a coating unit. The coating unit uses an electrospray system to deposit small droplets of a UV-photo absorbing compound on the surface of the tissue samples. Both units are operational. The tissue sample must be coated with the organic compound to enable matrix assisted laser desorption/ionization (MALDI) and matrix enhanced secondary ion mass spectrometry (ME-SIMS) measurements with the ChIPMA instrument Initial plans to test the sample preparation using human tissue samples required development of administrative procedures beyond the scope of this LDRD. Hence, it was decided to make two types of measurements: (1) Testing the spatial resolution of ME-SIMS by preparing a substrate coated with a mixture of an organic matrix and a bio standard and etching a defined pattern in the coating using a liquid metal ion beam, and (2) preparing and imaging C. elegans worms. Difficulties arose in sectioning the C. elegans for analysis and funds and time to overcome these difficulties were not available in this project. The facilities are now available for preparing biological samples for analysis with the ChIPMA instrument. Some further investment of time and resources in sample preparation should make this a useful tool for chemical imaging applications.

  13. Mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, Daniel D.; Keville, Robert F.

    1995-01-01

    An ion trap which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10.sup.9 and commercial mass spectrometers requiring 10.sup.4 ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products.

  14. Mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, D.D.; Keville, R.F.

    1995-09-19

    An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

  15. MASS SPECTROMETER

    DOE Patents [OSTI]

    White, F.A.

    1960-08-23

    A mass spectrometer is designed with a first adjustable magnetic field for resolving an ion beam into beams of selected masses, a second adjustable magnetic field for further resolving the ion beam from the first field into beams of selected masses, a thin foil disposed in the path of the beam between the first and second magnets to dissociate molecular ions incident thereon, an electrostatic field for further resolving the ion beam from the second field into beams of selected masses, and a detector disposed adjacent to the electrostatic field to receive the ion beam.

  16. Development of a Silicon Based Electron Beam Transmission Window for Use in a KrF Excimer Laser System

    SciTech Connect (OSTI)

    C.A. Gentile; H.M. Fan; J.W. Hartfield; R.J. Hawryluk; F. Hegeler; P.J. Heitzenroeder; C.H. Jun; L.P. Ku; P.H. LaMarche; M.C. Myers; J.J. Parker; R.F. Parsells; M. Payen; S. Raftopoulos; J.D. Sethian

    2002-11-21

    The Princeton Plasma Physics Laboratory (PPPL), in collaboration with the Naval Research Laboratory (NRL), is currently investigating various novel materials (single crystal silicon, <100>, <110> and <111>) for use as electron-beam transmission windows in a KrF excimer laser system. The primary function of the window is to isolate the active medium (excimer gas) from the excitation mechanism (field-emission diodes). Chosen window geometry must accommodate electron energy transfer greater than 80% (750 keV), while maintaining structural integrity during mechanical load (1.3 to 2.0 atm base pressure differential, approximate 0.5 atm cyclic pressure amplitude, 5 Hz repetition rate) and thermal load across the entire hibachi area (approximate 0.9 W {center_dot} cm superscript ''-2''). In addition, the window must be chemically resistant to attack by fluorine free-radicals (hydrofluoric acid, secondary). In accordance with these structural, functional, and operational parameters, a 22.4 mm square silicon prototype window, coated with 500 nm thin-film silicon nitride (Si{sub 3}N{sub 4}), has been fabricated. The window consists of 81 square panes with a thickness of 0.019 mm {+-} 0.001 mm. Stiffened (orthogonal) sections are 0.065 mm in width and 0.500 mm thick (approximate). Appended drawing (Figure 1) depicts the window configuration. Assessment of silicon (and silicon nitride) material properties and CAD modeling and analysis of the window design suggest that silicon may be a viable solution to inherent parameters and constraints.

  17. Electronic and optical properties of TaO{sub 1-x}N{sub 1+x}-based alloys

    SciTech Connect (OSTI)

    Al-Aqtash, Nabil; Apostol, Florin; Mei, Wai-Ning; Sabirianov, Renat F.; Nebraska Center for Materials and Nanoscience, University of Nebraska, Lincoln, NE 68588

    2013-02-15

    TaON is considered as a potential candidate as a visible-light responsive photocatalyst. We report the results of ab initio studies of electronic structure of TaON-based alloys. Specifically, we show that the position of conduction and valence band can be modified by varying the oxygen and nitrogen concentrations in TaO{sub 1-x}N{sub 1+x}. We find that the band gap decreases monotonically with the increase of N/O ratio. The band gap energy is decreased in monoclinic TaON from near 2.3 eV to just over 1.7 eV (i.e., by 35%) when N/O ratio is increased from 3/5 to 5/3. Our calculations show that the band gap reduces in a series of experimentally fabricated alloys ZrTa{sub 3}O{sub 5}N{sub 3}{yields}TaON{yields}YTa{sub 7}O{sub 7}N{sub 8}. The band gap reduction is mostly associated with the change in the position of the valence band due to the hybridization of N 2p states, while the conduction band consisting mostly of Ta 5d-states is not sensitive to N content. The calculated optical absorption spectra show reduction in the optical band gap with increasing N/O ratio. - Graphical abstract: Band gap energy of TaO{sub 1-x}N{sub 1+x} as a function of N/O ratio. Highlights: Black-Right-Pointing-Pointer The electronic and optical properties of TaON-based alloys are studied using DFT. Black-Right-Pointing-Pointer The position of conduction and valence bands can be modified by varying N/O ratio. Black-Right-Pointing-Pointer The band gap decreases monotonically with the increase of N/O ratio in TaO{sub 1-x}N{sub 1+x}. Black-Right-Pointing-Pointer The band gap reduces in a series of fabricated alloys ZrTa{sub 3}O{sub 5}N{sub 3}{yields}TaON{yields}YTa{sub 7}O{sub 7}N{sub 8}. Black-Right-Pointing-Pointer The optical band gap decreases with the increase of N/O ratio.

  18. Electron Ionization Mass Spectrum of Tellurium Hexafluoride ...

    Office of Scientific and Technical Information (OSTI)

    Formation of TeF6 was confirmed through cryogenic capture of the tellurium fluorination product and analysis through Raman spectroscopy. The eight natural abundance isotopes were ...

  19. Utilizing the Inherent Electrolysis in a Chip-Based Nanoelectrospray Emitter System to Facilitate Selective Ionization and Mass Spectrometric Analysis of Metallo Alkylporphyrins

    SciTech Connect (OSTI)

    Van Berkel, Gary J; Kertesz, Vilmos

    2012-01-01

    A commercially available chip-based infusion nanoelectrospray ionization system was used to ionize metallo alkylporphyrins for mass spectrometric detection and structure elucidation by mass spectrometry. Different ionic forms of model compounds (nickel (II), vanadyl (II), copper (II) and cobalt (II) octaethylporphyrin) were created by using two different types of conductive pipette tips supplied with the device. These pipette tips provide the conductive contact to solution at which the electrolysis process inherent to electrospray takes places in the device. The original unmodified, bare carbon-impregnated plastic pipette tips, were exploited to intentionally electrochemically oxidize (ionize) the porphyrins to form molecular radical cations for detection. Use of modified pipette tips, with a surface coating devised to inhibit analyte mass transport to the surface, was shown to limit the ionic species observed in the mass spectra of these porphyrins largely, but not exclusively, to the protonated molecule. Under the conditions of these experiments, the effective upper potential limit for oxidation with the uncoated pipette tip was 1.1 V or less and the coated pipette tips effectively prevented the oxidation of analytes with redox potentials greater than about 0.25 V. Product ion spectra of either molecular ionic species could be used to determine the alkyl chain length on the porphyrin macrocycle. The utility of this electrochemical ionization approach for the analysis of naturally occurring samples was demonstrated using nickel geoporphyrin fractions isolated from Gilsonite bitumen. Acquiring neutral loss spectra as a means to improve the specificity of detection in these complex natural samples was also illustrated.

  20. An improved empirical model of electron and ion fluxes at geosynchronous orbit based on upstream solar wind conditions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Denton, M. H.; Henderson, M. G.; Jordanova, V. K.; Thomsen, M. F.; Borovsky, J. E.; Woodroffe, J.; Hartley, D. P.; Pitchford, D.

    2016-07-27

    In this study, a new empirical model of the electron fluxes and ion fluxes at geosynchronous orbit (GEO) is introduced, based on observations by Los Alamos National Laboratory (LANL) satellites. The model provides flux predictions in the energy range ~1 eV to ~40 keV, as a function of local time, energy, and the strength of the solar wind electric field (the negative product of the solar wind speed and the z component of the magnetic field). Given appropriate upstream solar wind measurements, the model provides a forecast of the fluxes at GEO with a ~1 h lead time. Model predictionsmore » are tested against in-sample observations from LANL satellites and also against out-of-sample observations from the Compact Environmental Anomaly Sensor II detector on the AMC-12 satellite. The model does not reproduce all structure seen in the observations. However, for the intervals studied here (quiet and storm times) the normalized root-mean-square deviation < ~0.3. It is intended that the model will improve forecasting of the spacecraft environment at GEO and also provide improved boundary/input conditions for physical models of the magnetosphere.« less

  1. Energy Storage & Power Electronics 2008 Peer Review - Power Electronic...

    Office of Environmental Management (EM)

    Power Electronics (PE) Systems Presentations Energy Storage & Power Electronics 2008 Peer ... Compact SiC-Based Power Converter System - Timothy Lin, Aegis.pdf (370.13 KB) ...

  2. The double well mass filter

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gueroult, Renaud; Rax, Jean -Marcel; Fisch, Nathaniel J.

    2014-02-03

    Various mass filter concepts based on rotating plasmas have been suggested with the specific purpose of nuclear waste remediation. We report on a new rotating mass filter combining radial separation with axial extraction. Lastly, the radial separation of the masses is the result of a “double-well” in effective radial potential in rotating plasma with a sheared rotation profile.

  3. Manasa Electronics | Open Energy Information

    Open Energy Info (EERE)

    Manasa Electronics Jump to: navigation, search Name: Manasa Electronics Place: Ghaziabad, Uttar Pradesh, India Zip: 201 005 Sector: Solar Product: Ghaziabad-based manufacturer of...

  4. MASS SPECTROMETRY

    DOE Patents [OSTI]

    Nier, A.O.C.

    1959-08-25

    A voltage switching apparatus is described for use with a mass spectrometer in the concentratron analysis of several components of a gas mixture. The system automatically varies the voltage on the accelerating electrode of the mass spectrometer through a program of voltages which corresponds to the particular gas components under analysis. Automatic operation may be discontinued at any time to permit the operator to manually select any desired predetermined accelerating voltage. Further, the system may be manually adjusted to vary the accelerating voltage over a wide range.

  5. Silicon drift detector based X-ray spectroscopy diagnostic system for the study of non-thermal electrons at Aditya tokamak

    SciTech Connect (OSTI)

    Purohit, S., E-mail: pshishir@ipr.res.in; Joisa, Y. S.; Raval, J. V.; Ghosh, J.; Tanna, R.; Shukla, B. K.; Bhatt, S. B. [Institute for Plasma Research, Bhat, Gandhinagar 382 428 (India)

    2014-11-15

    Silicon drift detector based X-ray spectrometer diagnostic was developed to study the non-thermal electron for Aditya tokamak plasma. The diagnostic was mounted on a radial mid plane port at the Aditya. The objective of diagnostic includes the estimation of the non-thermal electron temperature for the ohmically heated plasma. Bi-Maxwellian plasma model was adopted for the temperature estimation. Along with that the study of high Z impurity line radiation from the ECR pre-ionization experiments was also aimed. The performance and first experimental results from the new X-ray spectrometer system are presented.

  6. Quark Masses

    SciTech Connect (OSTI)

    Gasser, Juerg

    2005-10-26

    In my talk, I reviewed some basic aspects of quark masses: what do they mean, how can they be determined, what is our present knowledge on them. The talk was addressed to non specialists in the field, and so is this write up.

  7. Handbook of mass spectra of environmental contaminants

    SciTech Connect (OSTI)

    Hites, R.A.

    1985-01-01

    This handbook is a collection of the electron impact mass spectra of 394 commonly encountered environmental pollutants. Each page is devoted to the examination of a single pollutant, which is presented as a bar graph always starting at M/z = 40. Each spectra is determined by analyses of data in EPA data bases. The major fragment ions are correlated with their respective structure. The mass and intensity of the four most intense ions in the spectrum are given. Each spectrum is marked to indicate the origin of the selected fragment ions. For each spectra, also given are the approved name of the chemical Abstract Service, the common name of the compound, the article number (if any) given to the Merck Index, the CAS Registry Number, the molecular formula, and the nominal molecular weight of the compound. Each spectra is indexed by common chemical name, CAS Registry Number, exact molecular weight, and intense peaks.

  8. Capillary liquid chromatography using laser-based and mass spectrometric detection. Final technical progress report, September 1, 1989--January 31, 1993

    SciTech Connect (OSTI)

    Sepaniak, M.J.; Cook, K.D.

    1992-09-01

    In the years following the 1986 seminal paper (J. Chromatogr. Sci., 24, 347-352) describing modern capillary zone electrophoresis (CZE), the prominence of capillary electrokinetic separation techniques has grown. A related electrochromatographic technique is micellar electrokinetic capillary chromatography (MECC). This report presents a brief synopsis of research efforts during the current 3-year period. In addition to a description of analytical separations-based research, results of efforts to develop and expand spectrometric detection for the techniques is reviewed. Laser fluorometric detection schemes have been successfully advanced. Mass spectrometric research was less fruitful, largely owing to personnel limitations. A regenerable fiber optic sensor was developed that can be used to remotely monitor chemical carcinogens, etc. (DLC)

  9. An efficient electron-beam-pumped semiconductor laser for the green spectral range based on II-VI multilayer nanostructures

    SciTech Connect (OSTI)

    Zverev, M. M.; Gamov, N. A.; Peregoudov, D. V.; Studionov, V. B.; Zdanova, E. V.; Sedova, I. V. Gronin, S. V.; Sorokin, S. V.; Ivanov, S. V.; Kop'ev, P. S.

    2008-12-15

    Emission characteristics of an electron-beam-pumped Cd(Zn)Se/ZnMgSSe semiconductor laser are studied. The laser's active region consists of a set of ten equidistant ZnSe quantum wells containing fractional-monolayer CdSe quantum-dot inserts and a waveguide formed by a short-period superlattice with the net thickness of {approx}0.65 {mu}m. Lasing occurs at room temperature at a wavelength of 542 nm. Pulsed power as high as 12 W per cavity face and an unprecedentedly high efficiency of {approx}8.5% are attained for the electron-beam energy of 23 keV.

  10. Electron radiography

    DOE Patents [OSTI]

    Merrill, Frank E.; Morris, Christopher

    2005-05-17

    A system capable of performing radiography using a beam of electrons. Diffuser means receive a beam of electrons and diffuse the electrons before they enter first matching quadrupoles where the diffused electrons are focused prior to the diffused electrons entering an object. First imaging quadrupoles receive the focused diffused electrons after the focused diffused electrons have been scattered by the object for focusing the scattered electrons. Collimator means receive the scattered electrons and remove scattered electrons that have scattered to large angles. Second imaging quadrupoles receive the collimated scattered electrons and refocus the collimated scattered electrons and map the focused collimated scattered electrons to transverse locations on an image plane representative of the electrons' positions in the object.

  11. High electron mobility thin-film transistors based on Ga{sub 2}O{sub 3} grown by atmospheric ultrasonic spray pyrolysis at low temperatures

    SciTech Connect (OSTI)

    Thomas, Stuart R. E-mail: thomas.anthopoulos@imperial.ac.uk; Lin, Yen-Hung; Faber, Hendrik; Anthopoulos, Thomas D. E-mail: thomas.anthopoulos@imperial.ac.uk; Adamopoulos, George; Sygellou, Labrini; Stratakis, Emmanuel; Pliatsikas, Nikos; Patsalas, Panos A.

    2014-09-01

    We report on thin-film transistors based on Ga{sub 2}O{sub 3} films grown by ultrasonic spray pyrolysis in ambient atmosphere at 400450?C. The elemental, electronic, optical, morphological, structural, and electrical properties of the films and devices were investigated using a range of complementary characterisation techniques, whilst the effects of post deposition annealing at higher temperature (700?C) were also investigated. Both as-grown and post-deposition annealed Ga{sub 2}O{sub 3} films are found to be slightly oxygen deficient, exceptionally smooth and exhibit a wide energy bandgap of ?4.9?eV. Transistors based on as-deposited Ga{sub 2}O{sub 3} films show n-type conductivity with the maximum electron mobility of ?2?cm{sup 2}/V s.

  12. MEMC Electronic Materials Inc | Open Energy Information

    Open Energy Info (EERE)

    MEMC Electronic Materials Inc Jump to: navigation, search Name: MEMC Electronic Materials Inc Place: St. Peters, Missouri Zip: 63376 Product: US-based manufacturer of silicon-based...

  13. High-Compression-Ratio; Atkinson-Cycle Engine Using Low-Pressure Direct Injection and Pneumatic-Electronic Valve Actuation Enabled by Ionization Current and Foward-Backward Mass Air Flow Sensor Feedback

    SciTech Connect (OSTI)

    Harold Schock; Farhad Jaberi; Ahmed Naguib; Guoming Zhu; David Hung

    2007-12-31

    This report describes the work completed over a two and one half year effort sponsored by the US Department of Energy. The goal was to demonstrate the technology needed to produce a highly efficient engine enabled by several technologies which were to be developed in the course of the work. The technologies included: (1) A low-pressure direct injection system; (2) A mass air flow sensor which would measure the net airflow into the engine on a per cycle basis; (3) A feedback control system enabled by measuring ionization current signals from the spark plug gap; and (4) An infinitely variable cam actuation system based on a pneumatic-hydraulic valve actuation These developments were supplemented by the use of advanced large eddy simulations as well as evaluations of fuel air mixing using the KIVA and WAVE models. The simulations were accompanied by experimental verification when possible. In this effort a solid base has been established for continued development of the advanced engine concepts originally proposed. Due to problems with the valve actuation system a complete demonstration of the engine concept originally proposed was not possible. Some of the highlights that were accomplished during this effort are: (1) A forward-backward mass air flow sensor has been developed and a patent application for the device has been submitted. We are optimistic that this technology will have a particular application in variable valve timing direct injection systems for IC engines. (2) The biggest effort on this project has involved the development of the pneumatic-hydraulic valve actuation system. This system was originally purchased from Cargine, a Swedish supplier and is in the development stage. To date we have not been able to use the actuators to control the exhaust valves, although the actuators have been successfully employed to control the intake valves. The reason for this is the additional complication associated with variable back pressure on the exhaust valves when

  14. Large scale electromechanical transistor with application in mass sensing

    SciTech Connect (OSTI)

    Jin, Leisheng; Li, Lijie

    2014-12-07

    Nanomechanical transistor (NMT) has evolved from the single electron transistor, a device that operates by shuttling electrons with a self-excited central conductor. The unfavoured aspects of the NMT are the complexity of the fabrication process and its signal processing unit, which could potentially be overcome by designing much larger devices. This paper reports a new design of large scale electromechanical transistor (LSEMT), still taking advantage of the principle of shuttling electrons. However, because of the large size, nonlinear electrostatic forces induced by the transistor itself are not sufficient to drive the mechanical member into vibrationan external force has to be used. In this paper, a LSEMT device is modelled, and its new application in mass sensing is postulated using two coupled mechanical cantilevers, with one of them being embedded in the transistor. The sensor is capable of detecting added mass using the eigenstate shifts method by reading the change of electrical current from the transistor, which has much higher sensitivity than conventional eigenfrequency shift approach used in classical cantilever based mass sensors. Numerical simulations are conducted to investigate the performance of the mass sensor.

  15. MASS SPECTROMETRY

    DOE Patents [OSTI]

    Friedman, L.

    1962-01-01

    method is described for operating a mass spectrometer to improve its resolution qualities and to extend its period of use substantially between cleanings. In this method, a small amount of a beta emitting gas such as hydrogen titride or carbon-14 methane is added to the sample being supplied to the spectrometer for investigation. The additive establishes leakage paths on the surface of the non-conducting film accumulating within the vacuum chamber of the spectrometer, thereby reducing the effect of an accumulated static charge on the electrostatic and magnetic fields established within the instrument. (AEC)

  16. Electron-Heated Target Temperature Measurements in Petawatt Laser Experiments Based on Extreme Ultraviolet Imaging and Spectroscopy

    SciTech Connect (OSTI)

    Ma, T; Beg, F; Macphee, A; Chung, H; Key, M; Mackinnon, A; Patel, P; Hatchett, S; Akli, K; Stephens, R; Chen, C; Freeman, R; Link, A; Offermann, D; Ovchinnikov, V; VanWoerkom, L; Zhang, B

    2008-05-02

    Three independent methods (XUV spectroscopy, imaging at 68 eV and 256 eV) have been used to measure planar target rear surface plasma temperature due to heating by hot electrons. The hot electrons are produced by ultra-intense laser plasma interactions using the 150 J, 0.5 ps Titan laser. Soft x-ray spectroscopy in the 50-400 eV region and imaging at the 68 eV and 256 eV photon energies were used to determine the rear surface temperature of planar CD targets. Temperatures were found to be in the 60-150 eV range, with good agreement between the three diagnostics.

  17. Rational engineering of Geobacter sulfurreducens electron transfer components: A foundation for building improved Geobacter-based bioelectrochemical technologies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dantas, Joana M.; Morgado, Leonor; Aklujkar, Muktak; Bruix, Marta; Londer, Yuri Y.; Schiffer, Marianne; Pokkuluri, P. Raj; Salgueiro, Carlos A.

    2015-07-30

    Multiheme cytochromes have been implicated in Geobacter sulfurreducens extracellular electron transfer (EET). These proteins are potential targets to improve EET and enhance bioremediation and electrical current production by G. sulfurreducens. However, the functional characterization of multiheme cytochromes is particularly complex due to the co-existence of several microstates in solution, connecting the fully reduced and fully oxidized states. Throughout the last decade, new strategies have been developed to characterize multiheme redox proteins functionally and structurally. These strategies were used to reveal the functional mechanism of G. sulfurreducens multiheme cytochromes and also to identify key residues in these proteins for EET. Inmore » previous studies, we set the foundations for enhancement of the EET abilities of G. sulfurreducens by characterizing a family of five triheme cytochromes (PpcA-E). These periplasmic cytochromes are implicated in electron transfer between the oxidative reactions of metabolism in the cytoplasm and the reduction of extracellular terminal electron acceptors at the cell's outer surface. The results obtained suggested that PpcA can couple e-/H+ transfer, a property that might contribute to the proton electrochemical gradient across the cytoplasmic membrane for metabolic energy production. The structural and functional properties of PpcA were characterized in detail and used for rational design of a family of 23 single site PpcA mutants. In this review, we summarize the functional characterization of the native and mutant proteins. Mutants that retain the mechanistic features of PpcA and adopt preferential e-/H+ transfer pathways at lower reduction potential values compared to the wild-type protein were selected for in vivo studies as the best candidates to increase the electron transfer rate of G. sulfurreducens. For the first time G. sulfurreducens strains have been manipulated by the introduction of mutant forms of

  18. Effect of electron withdrawing unit for dye-sensitized solar cell based on D-A-π-A organic dyes

    SciTech Connect (OSTI)

    Kwon, Dong Yuel; Chang, Dong Min; Kim, Young Sik

    2014-10-15

    Highlights: • To gain the red-shifted absorption spectra, withdrawing unit was substituted in dye. • By the introduction of additional withdrawing unit, LUMOs level of dye are decreased. • Decreasing LUMOs level of dye caused the red-shifted absorption spectra of dye. • Novel acceptor, DCRD, showed better photovoltaic properties than cyanoacetic acid. - Abstract: In this work, two novel D-A-π-A dye sensitizers with triarylamine as an electron donor, isoindigo and cyano group as electron withdrawing units and cyanoacetic acid and 2-(1,1-dicyanomethylene) rhodanine as an electron acceptor for an anchoring group (TICC, TICR) were designed and investigated with the ID6 dye as the reference. The difference in HOMO and LUMO levels were compared according to the presence or absence of isoindigo in ID6 (TC and ID6). To gain insight into the factors responsible for photovoltaic performance, we used density functional theory (DFT) and time-dependent density functional theory (TDDFT) calculations. Owing to different LUMO levels for each acceptor, the absorption band and molar extinction coefficient of each dye was different. Among the dyes, TICR showed more red-shifted and broader absorption spectra than other dyes and had a higher molar extinction coefficient than the reference. It is expected that TICR would show better photovoltaic properties than the other dyes, including the reference dye.

  19. Hybrid DFT Functional-Based Static and Molecular Dynamics Studies of Excess Electron in Liquid Ethylene Carbonate

    SciTech Connect (OSTI)

    Yu, J. M.; Balbuena, P. B.; Budzien, J. L.; Leung, Kevin

    2011-02-22

    We applied static and dynamic hybrid functional density functional theory (DFT) calculations to study the interactions of one and two excess electrons with ethylene carbonate (EC) liquid and clusters. Optimal structures of (EC)n and (EC)n- clusters devoid of Li+ ions, n = 16, were obtained. The excess electron was found to be localized on a single EC in all cases, and the EC dimeric radical anion exhibits a reduced barrier associated with the breaking of the ethylene carbonoxygen covalent bond compared to EC-. In ab initio molecular dynamics (AIMD) simulations of EC- solvated in liquid EC, large fluctuations in the carbonyl carbonoxygen bond lengths were observed. AIMD simulations of a two-electron attack on EC in EC liquid and on Li metal surfaces yielded products similar to those predicted using nonhybrid DFT functionals, except that CO release did not occur for all attempted initial configurations in the liquid state.

  20. Note: A disposable x-ray camera based on mass produced complementary metal-oxide-semiconductor sensors and single-board computers

    SciTech Connect (OSTI)

    Hoidn, Oliver R.; Seidler, Gerald T.

    2015-08-15

    We have integrated mass-produced commercial complementary metal-oxide-semiconductor (CMOS) image sensors and off-the-shelf single-board computers into an x-ray camera platform optimized for acquisition of x-ray spectra and radiographs at energies of 2–6 keV. The CMOS sensor and single-board computer are complemented by custom mounting and interface hardware that can be easily acquired from rapid prototyping services. For single-pixel detection events, i.e., events where the deposited energy from one photon is substantially localized in a single pixel, we establish ∼20% quantum efficiency at 2.6 keV with ∼190 eV resolution and a 100 kHz maximum detection rate. The detector platform’s useful intrinsic energy resolution, 5-μm pixel size, ease of use, and obvious potential for parallelization make it a promising candidate for many applications at synchrotron facilities, in laser-heating plasma physics studies, and in laboratory-based x-ray spectrometry.

  1. Review, evaluation, and discussion of the challenges of missing value imputation for mass spectrometry-based label-free global proteomics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Webb-Robertson, Bobbie-Jo M.; Wiberg, Holli K.; Matzke, Melissa M.; Brown, Joseph N.; Wang, Jing; McDermott, Jason E.; Smith, Richard D.; Rodland, Karin D.; Metz, Thomas O.; Pounds, Joel G.; et al

    2015-04-09

    In this review, we apply selected imputation strategies to label-free liquid chromatography–mass spectrometry (LC–MS) proteomics datasets to evaluate the accuracy with respect to metrics of variance and classification. We evaluate several commonly used imputation approaches for individual merits and discuss the caveats of each approach with respect to the example LC–MS proteomics data. In general, local similarity-based approaches, such as the regularized expectation maximization and least-squares adaptive algorithms, yield the best overall performances with respect to metrics of accuracy and robustness. However, no single algorithm consistently outperforms the remaining approaches, and in some cases, performing classification without imputation sometimes yieldedmore » the most accurate classification. Thus, because of the complex mechanisms of missing data in proteomics, which also vary from peptide to protein, no individual method is a single solution for imputation. In summary, on the basis of the observations in this review, the goal for imputation in the field of computational proteomics should be to develop new approaches that work generically for this data type and new strategies to guide users in the selection of the best imputation for their dataset and analysis objectives.« less

  2. e/a classification of Hume–Rothery Rhombic Triacontahedron-type approximants based on all-electron density functional theory calculations

    SciTech Connect (OSTI)

    Mizutani, U; Inukai, M; Sato, H; Zijlstra, E S; Lin, Q

    2014-05-16

    There are three key electronic parameters in elucidating the physics behind the Hume–Rothery electron concentration rule: the square of the Fermi diameter (2kF)2, the square of the critical reciprocal lattice vector and the electron concentration parameter or the number of itinerant electrons per atom e/a. We have reliably determined these three parameters for 10 Rhombic Triacontahedron-type 2/1–2/1–2/1 (N = 680) and 1/1–1/1–1/1 (N = 160–162) approximants by making full use of the full-potential linearized augmented plane wave-Fourier band calculations based on all-electron density-functional theory. We revealed that the 2/1–2/1–2/1 approximants Al13Mg27Zn45 and Na27Au27Ga31 belong to two different sub-groups classified in terms of equal to 126 and 109 and could explain why they take different e/a values of 2.13 and 1.76, respectively. Among eight 1/1–1/1–1/1 approximants Al3Mg4Zn3, Al9Mg8Ag3, Al21Li13Cu6, Ga21Li13Cu6, Na26Au24Ga30, Na26Au37Ge18, Na26Au37Sn18 and Na26Cd40Pb6, the first two, the second two and the last four compounds were classified into three sub-groups with = 50, 46 and 42; and were claimed to obey the e/a = 2.30, 2.10–2.15 and 1.70–1.80 rules, respectively.

  3. Laser based analysis using a passively Q-switched laser employing analysis electronics and a means for detecting atomic optical emission of the laser media

    DOE Patents [OSTI]

    Woodruff, Steven D.; Mcintyre, Dustin L.

    2016-03-29

    A device for Laser based Analysis using a Passively Q-Switched Laser comprising an optical pumping source optically connected to a laser media. The laser media and a Q-switch are positioned between and optically connected to a high reflectivity mirror (HR) and an output coupler (OC) along an optical axis. The output coupler (OC) is optically connected to the output lens along the optical axis. A means for detecting atomic optical emission comprises a filter and a light detector. The optical filter is optically connected to the laser media and the optical detector. A control system is connected to the optical detector and the analysis electronics. The analysis electronics are optically connected to the output lens. The detection of the large scale laser output production triggers the control system to initiate the precise timing and data collection from the detector and analysis.

  4. Studies of Basic Electronic Properties of CdTe-Based Solar Cells and Their Evolution During Processing and Stress: Final Technical Report, 16 October 2001 - 31 August 2005

    SciTech Connect (OSTI)

    Kaydanov, V. I.; Ohno, T. R.

    2007-02-01

    This report describes basic issues behind CdTe/CdS cell performance and stability, such as the nature and electronic properties of impurities and defects that control the majority carrier concentration, mechanisms of dopant compensation, recombination processes, their nature and properties, migration and transformation of defects under various processing, stress, and operating conditions. We believe that a better basic understanding of the specific influence of grain boundaries, especially for fine-grain materials such as those making up CdTe-based cells, is now one of the most important issues we must address. We need to clarify the role of grain boundaries in forming the film electronic properties, as well as those of the p-n junction.

  5. MASS SEPARATORS

    DOE Patents [OSTI]

    Oppenheimer, F.; Bell, J.W.

    1959-02-17

    An improvement in the mounting arrangement for the ion source within the vacuum tank of a calutron is presented. The entire source is supported by the vacuum envelope through the medium of a bracket secured to a removable face plate. The bracket forms a supporting platform that is generally transverse to the magnetic field. The ion generator is mounted on a pedestal-type insulator supported on the bracket, and the hot leads are brought into the vacuum envelope through a tubular elbow connected to the vacuum envelope, having the axis of its outer opening aligned with the magnetic field at which point a bushing-type insulator is employed. With this arrangement thc ion source is maintained at a positive potential with respect to the vacuum tank and the problem of electron bombardment of the insulator is considerably reduced.

  6. The electron geodesic acoustic mode

    SciTech Connect (OSTI)

    Chakrabarti, N. [Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Calcutta 700 064 (India); Guzdar, P. N. [Institute for Research in Electronics and Applied Physics, University of Maryland, College Park, Maryland 20742 (United States); Kaw, P. K. [Institute for Plasma Research Bhat, Gandhinagar 382428 (India)

    2012-09-15

    In this report, a novel new mode, named the electron geodesic acoustic mode, is presented. This mode can occur in toroidal plasmas like the conventional geodesic acoustic mode (GAM). The frequency of this new mode is much larger than that of the conventional GAM by a factor equal to the square root of the ion to electron mass ratio.

  7. Geochemical Speciation Mass Transfer

    Energy Science and Technology Software Center (OSTI)

    1985-12-01

    PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineralmore » phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.« less

  8. Hot-stage transmission electron microscopy study of (Na, K)NbO{sub 3} based lead-free piezoceramics

    SciTech Connect (OSTI)

    Lu, Shengbo; Xu, Zhengkui; Kwok, K. W.; Chan, Helen L. W.

    2014-07-28

    Hierarchical nanodomains assembled into micron-sized stripe domains, which is believed to be associated with outstanding piezoelectric properties, were observed at room temperature in a typical lead free piezoceramics, (Na{sub 0.52}K{sub 0.48−x})(Nb{sub 0.95−x}Ta{sub 0.05})-xLiSbO{sub 3}, with finely tuned polymorphic phase boundaries (x = 0.0465) by transmission electron microscopy. The evolution of domain morphology and crystal structure under heating and cooling cycles in the ceramic was investigated by in-situ hot stage study. It is found that the nanodomains are irreversibly transformed into micron-sized rectangular domains during heating and cooling cycles, which lead to the thermal instability of piezoelectric properties of the materials.

  9. Opto-electronic device for frequency standard generation and terahertz-range optical demodulation based on quantum interference

    DOE Patents [OSTI]

    Georgiades, N.P.; Polzik, E.S.; Kimble, H.J.

    1999-02-02

    An opto-electronic system and technique for comparing laser frequencies with large frequency separations, establishing new frequency standards, and achieving phase-sensitive detection at ultra high frequencies are disclosed. Light responsive materials with multiple energy levels suitable for multi-photon excitation are preferably used for nonlinear mixing via quantum interference of different excitation paths affecting a common energy level. Demodulation of a carrier with a demodulation frequency up to 100`s THZ can be achieved for frequency comparison and phase-sensitive detection. A large number of materials can be used to cover a wide spectral range including the ultra violet, visible and near infrared regions. In particular, absolute frequency measurement in a spectrum from 1.25 {micro}m to 1.66 {micro}m for fiber optics can be accomplished with a nearly continuous frequency coverage. 7 figs.

  10. Opto-electronic device for frequency standard generation and terahertz-range optical demodulation based on quantum interference

    DOE Patents [OSTI]

    Georgiades, Nikos P.; Polzik, Eugene S.; Kimble, H. Jeff

    1999-02-02

    An opto-electronic system and technique for comparing laser frequencies with large frequency separations, establishing new frequency standards, and achieving phase-sensitive detection at ultra high frequencies. Light responsive materials with multiple energy levels suitable for multi-photon excitation are preferably used for nonlinear mixing via quantum interference of different excitation paths affecting a common energy level. Demodulation of a carrier with a demodulation frequency up to 100's THZ can be achieved for frequency comparison and phase-sensitive detection. A large number of materials can be used to cover a wide spectral range including the ultra violet, visible and near infrared regions. In particular, absolute frequency measurement in a spectrum from 1.25 .mu.m to 1.66 .mu.m for fiber optics can be accomplished with a nearly continuous frequency coverage.

  11. Method based on atomic photoionization for spot-size measurement on focused soft x-ray free-electron laser beams

    SciTech Connect (OSTI)

    Sorokin, A. A.; Gottwald, A.; Hoehl, A.; Kroth, U.; Schoeppe, H.; Ulm, G.; Richter, M.; Bobashev, S. V.; Domracheva, I. V.; Smirnov, D. N.; Tiedtke, K.; Duesterer, S.; Feldhaus, J.; Hahn, U.; Jastrow, U.; Kuhlmann, M.; Nunez, T.; Ploenjes, E.; Treusch, R.

    2006-11-27

    A method has been developed and applied to measure the beam waist and spot size of a focused soft x-ray beam at the free-electron laser FLASH of the Deutsches Elektronen-Synchrotron in Hamburg. The method is based on a saturation effect upon atomic photoionization and represents an indestructible tool for the characterization of powerful beams of ionizing electromagnetic radiation. At the microfocus beamline BL2 at FLASH, a full width at half maximum focus diameter of (15{+-}2) {mu}m was determined.

  12. Fabrication of large area plasmonic nanoparticle grating structure on silver halide based transmission electron microscope film and its application as a surface enhanced Raman spectroscopy substrate

    SciTech Connect (OSTI)

    Sudheer, Tiwari, P.; Singh, M. N.; Sinha, A. K.; Rai, V. N.; Srivastava, A. K.; Bhartiya, S.; Mukherjee, C.

    2015-08-14

    The plasmonic responses of silver nanoparticle grating structures of different periods made on silver halide based electron microscope film are investigated. Raster scan of the conventional scanning electron microscope (SEM) is used to carry out electron beam lithography for fabricating the plasmonic nanoparticle grating (PNG) structures. Morphological characterization of the PNG structures, carried out by the SEM and the atomic force microscope, indicates that the depth of the groove decreases with a decrease in the grating period. Elemental characterization performed by the energy dispersive spectroscopy and the x-ray diffraction shows the presence of nanoparticles of silver in the PNG grating. The optical characterization of the gratings shows that the localized surface plasmon resonance peak shifts from 366 to 378 nm and broadens with a decrease in grating period from 10 to 2.5 μm. The surface enhanced Raman spectroscopy of the Rhodamine-6G dye coated PNG structure shows the maximum enhancement by two orders of magnitude in comparison to the randomly distributed silver nanoparticles having similar size and shape as the PNG structure.

  13. A compact time-of-flight mass spectrometer for ion source characterization

    SciTech Connect (OSTI)

    Chen, L. Wan, X.; Jin, D. Z.; Tan, X. H.; Huang, Z. X.; Tan, G. B.

    2015-03-15

    A compact time-of-flight mass spectrometer with overall dimension of about 413 × 250 × 414 mm based on orthogonal injection and angle reflection has been developed for ion source characterization. Configuration and principle of the time-of-flight mass spectrometer are introduced in this paper. The mass resolution is optimized to be about 1690 (FWHM), and the ion energy detection range is tested to be between about 3 and 163 eV with the help of electron impact ion source. High mass resolution and compact configuration make this spectrometer useful to provide a valuable diagnostic for ion spectra fundamental research and study the mass to charge composition of plasma with wide range of parameters.

  14. WE-E-BRE-01: An Image-Based Skeletal Dosimetry Model for the ICRP Reference Adult Female - Internal Electron Sources

    SciTech Connect (OSTI)

    O'Reilly, S; Maynard, M; Marshall, E; Bolch, W; Sinclair, L; Rajon, D; Wayson, M

    2014-06-15

    Purpose: Limitations seen in previous skeletal dosimetry models, which are still employed in commonly used software today, include the lack of consideration of electron escape and cross-fire from cortical bone, the modeling of infinite spongiosa, the disregard of the effect of varying cellularity on active marrow self-irradiation, and the lack of use of the more recent ICRP definition of a 50 micron surrogate tissue region for the osteoprogenitor cells - shallow marrow. These limitations were addressed in the present dosimetry model. Methods: Electron transport was completed to determine specific absorbed fractions to active marrow and shallow marrow of the skeletal regions of the adult female. The bone macrostructure was obtained from the whole-body hybrid computational phantom of the UF series of reference phantoms, while the bone microstructure was derived from microCT images of skeletal region samples taken from a 45 year-old female cadaver. The target tissue regions were active marrow and shallow marrow. The source tissues were active marrow, inactive marrow, trabecular bone volume, trabecular bone surfaces, cortical bone volume and cortical bone surfaces. The marrow cellularity was varied from 10 to 100 percent for active marrow self-irradiation. A total of 33 discrete electron energies, ranging from 1 keV to 10 MeV, were either simulated or modeled analytically. Results: The method of combining macro- and microstructure absorbed fractions calculated using MCNPX electron transport was found to yield results similar to those determined with the PIRT model for the UF adult male in the Hough et al. study. Conclusion: The calculated skeletal averaged absorbed fractions for each source-target combination were found to follow similar trends of more recent dosimetry models (image-based models) and did not follow current models used in nuclear medicine dosimetry at high energies (due to that models use of an infinite expanse of trabecular spongiosa)

  15. A high-resolution field-emission-gun, scanning electron microscope investigation of anisotropic hydrogen decrepitation in Nd-Fe-B-based sintered magnets

    SciTech Connect (OSTI)

    Soderznik, Marko; McGuiness, Paul; Zuzek-Rozman, Kristina; Kobe, Spomenka; Skulj, Irena; Yan Gaolin

    2010-05-15

    In this investigation commercial magnets based on (Nd,Dy){sub 14}(Fe,Co){sub 79}B{sub 7} were prepared by a conventional powder-metallurgy route with a degree of alignment equal to {approx}90% and then exposed to hydrogen at a pressure of 1 bar. The magnets, in the form of cylinders, were observed to decrepitate exclusively from the ends. High-resolution electron microscopy was able to identify the presence of crack formation within the Nd{sub 2}Fe{sub 14}B grains, with the cracks running parallel to the c axis of these grains. Based on the concentration profile for hydrogen in a rare-earth transition-metal material, it is clear that the presence of hydrogen-induced cracks running perpendicular to the ends of the magnet provides for a much more rapidly progressing hydrogen front in this direction than from the sides of the magnet. This results in the magnet exhibiting a macroscopic tendency to decrepitate from the poles of the magnet toward the center. This combination of microstructural modification via particle alignment as part of the sintering process and direct observation via high-resolution electron microscopy has led to a satisfying explanation for the anisotropic hydrogen-decrepitation effect.

  16. Atom Probe Tomography of Nanoscale Electronic Materials

    SciTech Connect (OSTI)

    Larson, David J.; Prosa, Ty J.; Perea, Daniel E.; Inoue, Hidekazu; Mangelinck, D.

    2016-01-01

    Atom probe tomography (APT) is a mass spectrometry based on time-of-flight measurements which also concurrently produces 3D spatial information. The reader is referred to any of the other papers in this volume or to the following references for further information 4–8. The current capabilities of APT, such as detecting a low number of dopant atoms in nanoscale devices or segregation at a nanoparticle interface, make this technique an important component in the nanoscale metrology toolbox. In this manuscript, we review some of the applications of APT to nanoscale electronic materials, including transistors and finFETs, silicide contact microstructures, nanowires, and nanoparticles.

  17. Electron Transfer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 Pierre Kennepohl1,2 and Edward Solomon1* 1Department of Chemistry, Stanford University, Stanford, CA 94305 Electron transfer, or the act of moving an electron from one place to another, is amongst the simplest of chemical processes, yet certainly one of the most critical. The process of efficiently and controllably moving electrons around is one of the primary regulation mechanisms in biology. Without stringent control of electrons in living organisms, life could simply not exist. For example,

  18. Diamondoid monolayers as electron emitters

    DOE Patents [OSTI]

    Yang, Wanli; Fabbri, Jason D.; Melosh, Nicholas A.; Hussain, Zahid; Shen, Zhi-Xun

    2012-04-10

    Provided are electron emitters based upon diamondoid monolayers, preferably self-assembled higher diamondoid monolayers. High intensity electron emission has been demonstrated employing such diamondoid monolayers, particularly when the monolayers are comprised of higher diamondoids. The application of such diamondoid monolayers can alter the band structure of substrates, as well as emit monochromatic electrons, and the high intensity electron emissions can also greatly improve the efficiency of field-effect electron emitters as applied to industrial and commercial applications.

  19. Diamondoid monolayers as electron emitters

    DOE Patents [OSTI]

    Yang, Wanli; Fabbri, Jason D.; Melosh, Nicholas A.; Hussain, Zahid; Shen, Zhi-Xun

    2013-10-29

    Provided are electron emitters based upon diamondoid monolayers, preferably self-assembled higher diamondoid monolayers. High intensity electron emission has been demonstrated employing such diamondoid monolayers, particularly when the monolayers are comprised of higher diamondoids. The application of such diamondoid monolayers can alter the band structure of substrates, as well as emit monochromatic electrons, and the high intensity electron emissions can also greatly improve the efficiency of field-effect electron emitters as applied to industrial and commercial applications.

  20. Incorporating Amino Acid Esters into Catalysts for Hydrogen Oxidation: Steric and Electronic Effects and the Role of Water as a Base

    SciTech Connect (OSTI)

    Lense, Sheri; Ho, Ming-Hsun; Chen, Shentan; Jain, Avijita; Raugei, Simone; Linehan, John C.; Roberts, John A.; Appel, Aaron M.; Shaw, Wendy J.

    2012-10-08

    Four derivatives of a hydrogen oxidation catalyst, [Ni(PCy2NBn-R2)]2+ (Cy=cyclohexyl, Bn=benzyl, R= OMe, COOMe, CO-Alanine-methyl ester or CO-Phenylalanine-methyl ester), have been prepared to investigate steric and electronic effects on catalysis. Each complex was characterized spectroscopically and electrochemically, and thermodynamic data were determined. Crystal structures are also reported for the -OMe and -COOMe derivatives. All four catalysts were found to be active for H2 oxidation. The methyl ester (R = COOMe) and amino acid ester containing complexes (R = CO-Alanine-methyl ester or CO-Phenylalanine-methyl ester) had slower rates (4 s-1) than that of the parent complex (10 s-1), in which R = H, consistent with the lower amine pKa’s and less favorable GH2’s found for these electron-withdrawing substituents. Dynamic processes for the amino acid ester containing complexes were also investigated and found not to hinder catalysis. The electron-donating methoxy ether derivative (R = OMe) was prepared to compare electronic effects and has a similar catalytic rate as the parent complex. In the course of these studies, it was found that water could act as a weak base for H2 oxidation, although catalytic turnover requires a significantly higher potential and utilizes a different sequence of catalytic steps than when using a base with a higher pKa. Importantly, these catalysts provide a foundation upon which larger peptides can be attached to [Ni(PCy2NBn2)2]2+ hydrogen oxidation catalysts in order to more fully investigate and implement the effects of the outer-coordination sphere. This work was funded by the DOE Office of Science Early Career Research Program through the Office of Basic Energy Sciences (SL and WJS), by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences (JR), and by the US DOE Basic Energy Sciences, Chemical Sciences, Geoscience

  1. Development of an ion-to-electron converter

    SciTech Connect (OSTI)

    Rachev, Mikhail; Srama, Ralf; Fettig, Rainer; Koehler, Uwe; Maas, Dieter; Gruen, Eberhard

    2005-06-15

    This article describes the design aspects of an ion-to-electron converter with a large area detector (approximately 450 cm{sup 2}). This converter was designed for a large area mass analyzer for the detection of cosmic dust particles. The design is based on the MM1 electron multiplier and the simulations were carried out using the software package SIMION 3D for the calculations of the electric field. Several dynode profiles were investigated in order to compare the time resolution and particle transmission. It is shown that the converter properties strongly depend on the dynode profile. Potential manufacturing processes are discussed briefly.

  2. Electron g-2 in Light-front Quantization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Xingbo; Honkanen, Heli; Maris, Pieter; Vary, James P.; Brodsky, Stanley J.

    2014-10-01

    Basis Light-front Quantization has been proposed as a nonperturbative framework for solving quantum field theory. We apply this approach to Quantum Electrodynamics and explicitly solve for the light-front wave function of a physical electron. Based on the resulting light-front wave function, we evaluate the electron anomalous magnetic moment. Nonperturbative mass renormalization is performed. Upon extrapolation to the infinite basis limit our numerical results agree with the Schwinger result obtained in perturbation theory to an accuracy of 0.06%.

  3. Green Electronics Council | Open Energy Information

    Open Energy Info (EERE)

    Electronics Council Jump to: navigation, search Name: Green Electronics Council Place: Portland, Oregon Product: Oregon-based program that supports the design, manufacture, use and...

  4. Vickers Electronics Ltd | Open Energy Information

    Open Energy Info (EERE)

    Vickers Electronics Ltd Jump to: navigation, search Name: Vickers Electronics Ltd Place: United Kingdom Product: Manchester-based company which installs an Energy Management System...

  5. MGI Electronics LLC | Open Energy Information

    Open Energy Info (EERE)

    MGI Electronics LLC Jump to: navigation, search Name: MGI Electronics LLC Place: Temple, Arizona Zip: 85282 Product: US-based manufacturer of wafer transfer and PV cell handling...

  6. Compel Electronics GmbH | Open Energy Information

    Open Energy Info (EERE)

    Electronics GmbH Jump to: navigation, search Name: Compel Electronics GmbH Place: Germany Product: Germany-based manufacturer of electronic cables and interconnections. The...

  7. Search for High-Mass States with One Lepton Plus Missing Transverse Momentum in Proton-Proton Collisions at $\\sqrt{s} with the ATLAS Detector

    SciTech Connect (OSTI)

    Aad, Georges; Abbott, Brad; Abdallah, Jalal; Abdelalim, Ahmed Ali; Abdesselam, Abdelouahab; Abdinov, Ovsat; Abi, Babak; Abolins, Maris; Abramowicz, Halina; Abreu, Henso; Acerbi, Emilio; Acharya, Bobby Samir; Adams, David; Addy, Tetteh; Adelman, Jahred; Aderholz, Michael; Adomeit, Stefanie; Adragna, Paolo; Adye, Tim; Aefsky, Scott; Aguilar-Saavedra, Juan Antonio; /Freiburg U. /Oklahoma U. /Barcelona, IFAE /Geneva U. /Oxford U. /Baku, Inst. Phys. /Oklahoma State U. /Michigan State U. /Tel Aviv U. /Orsay, LAL /INFN, Milan /Milan U. /INFN, Udine /ICTP, Trieste /Brookhaven /Hampton U. /Yale U. /Heidelberg, Max Planck Inst. /Munich U. /Queen Mary, U. of London /Rutherford

    2012-06-20

    The ATLAS detector is used to search for high-mass states, such as heavy charged gauge bosons (W{prime},W*), decaying to a charged lepton (electron or muon) and a neutrino. Results are presented based on the analysis of ppcollisions at a center-of-mass energy of 7 TeV corresponding to an integrated luminosity of 36 pb{sup -1}. No excess beyond standard model expectations is observed. A W{prime} with sequential standard model couplings is excluded at 95% confidence level for masses below 1.49 TeV, and a W* (charged chiral boson) for masses below 1.35 TeV.

  8. Electrophoresis-mass spectrometry probe

    DOE Patents [OSTI]

    Andresen, Brian D.; Fought, Eric R.

    1987-01-01

    The invention involves a new technique for the separation of complex mixtures of chemicals, which utilizes a unique interface probe for conventional mass spectrometers which allows the electrophoretically separated compounds to be analyzed in real-time by a mass spectrometer. This new chemical analysis interface, which couples electrophoresis with mass spectrometry, allows complex mixtures to be analyzed very rapidly, with much greater specificity, and with greater sensitivity. The interface or probe provides a means whereby large and/or polar molecules in complex mixtures to be completely characterized. The preferred embodiment of the probe utilizes a double capillary tip which allows the probe tip to be continually wetted by the buffer, which provides for increased heat dissipation, and results in a continually operating interface which is more durable and electronically stable than the illustrated single capillary tip probe interface.

  9. Electrophoresis-mass spectrometry probe

    DOE Patents [OSTI]

    Andresen, B.D.; Fought, E.R.

    1987-11-10

    The invention involves a new technique for the separation of complex mixtures of chemicals, which utilizes a unique interface probe for conventional mass spectrometers which allows the electrophoretically separated compounds to be analyzed in real-time by a mass spectrometer. This new chemical analysis interface, which couples electrophoresis with mass spectrometry, allows complex mixtures to be analyzed very rapidly, with much greater specificity, and with greater sensitivity. The interface or probe provides a means whereby large and/or polar molecules in complex mixtures to be completely characterized. The preferred embodiment of the probe utilizes a double capillary tip which allows the probe tip to be continually wetted by the buffer, which provides for increased heat dissipation, and results in a continually operating interface which is more durable and electronically stable than the illustrated single capillary tip probe interface. 8 figs.

  10. Spectral restoration in high resolution electron energy loss spectroscopy based on iterative semi-blind Lucy-Richardson algorithm applied to rutile surfaces

    SciTech Connect (OSTI)

    Lazzari, Rmi Li, Jingfeng Jupille, Jacques

    2015-01-15

    A new spectral restoration algorithm of reflection electron energy loss spectra is proposed. It is based on the maximum likelihood principle as implemented in the iterative Lucy-Richardson approach. Resolution is enhanced and point spread function recovered in a semi-blind way by forcing cyclically the zero loss to converge towards a Dirac peak. Synthetic phonon spectra of TiO{sub 2} are used as a test bed to discuss resolution enhancement, convergence benefit, stability towards noise, and apparatus function recovery. Attention is focused on the interplay between spectral restoration and quasi-elastic broadening due to free carriers. A resolution enhancement by a factor up to 6 on the elastic peak width can be obtained on experimental spectra of TiO{sub 2}(110) and helps revealing mixed phonon/plasmon excitations.

  11. ELECTRON EMISSION REGULATING MEANS

    DOE Patents [OSTI]

    Brenholdt, I.R.

    1957-11-19

    >An electronic regulating system is described for controlling the electron emission of a cathode, for example, the cathode in a mass spectrometer. The system incorporates a transformer having a first secondary winding for the above-mentioned cathode and a second secondary winding for the above-mentioned cathode and a second secondary winding load by grid controlled vacuum tubes. A portion of the electron current emitted by the cathode is passed through a network which develops a feedback signal. The system arrangement is completed by using the feedback signal to control the vacuum tubes in the second secondary winding through a regulator tube. When a change in cathode emission occurs, the feedback signal acts to correct this change by adjusting the load on the transformer.

  12. Consumer Electronics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    & Events Expand News & Events Skip navigation links Residential Residential Lighting Energy Star Appliances Consumer Electronics Heat Pump Water Heaters Electric Storage Water...

  13. Noise reduction in negative-ion quadrupole mass spectrometry

    DOE Patents [OSTI]

    Chastagner, Philippe

    1993-01-01

    A quadrupole mass spectrometer (QMS) system having an ion source, quadrupole mass filter, and ion collector/recorder system. A weak, transverse magnetic field and an electron collector are disposed between the quadrupole and ion collector. When operated in negative ion mode, the ion source produces a beam of primarily negatively-charged particles from a sample, including electrons as well as ions. The beam passes through the quadrupole and enters the magnetic field, where the electrons are deflected away from the beam path to the electron collector. The negative ions pass undeflected to the ion collector where they are detected and recorded as a mass spectrum.

  14. Noise reduction in negative-ion quadrupole mass spectrometry

    DOE Patents [OSTI]

    Chastagner, P.

    1993-04-20

    A quadrupole mass spectrometer (QMS) system is described having an ion source, quadrupole mass filter, and ion collector/recorder system. A weak, transverse magnetic field and an electron collector are disposed between the quadrupole and ion collector. When operated in negative ion mode, the ion source produces a beam of primarily negatively-charged particles from a sample, including electrons as well as ions. The beam passes through the quadrupole and enters the magnetic field, where the electrons are deflected away from the beam path to the electron collector. The negative ions pass undeflected to the ion collector where they are detected and recorded as a mass spectrum.

  15. Ultra High Mass Range Mass Spectrometer System

    DOE Patents [OSTI]

    Reilly, Peter T. A. [Knoxville, TN

    2005-12-06

    Applicant's present invention comprises mass spectrometer systems that operate in a mass range from 1 to 10.sup.16 DA. The mass spectrometer system comprising an inlet system comprising an aerodynamic lens system, a reverse jet being a gas flux generated in an annulus moving in a reverse direction and a multipole ion guide; a digital ion trap; and a thermal vaporization/ionization detector system. Applicant's present invention further comprises a quadrupole mass spectrometer system comprising an inlet system having a quadrupole mass filter and a thermal vaporization/ionization detector system. Applicant's present invention further comprises an inlet system for use with a mass spectrometer system, a method for slowing energetic particles using an inlet system. Applicant's present invention also comprises a detector device and a method for detecting high mass charged particles.

  16. Tyco Electronics | Open Energy Information

    Open Energy Info (EERE)

    Product: Pennsylvania-based passive component manufacturer. The firm produces power storage devices. References: Tyco Electronics1 This article is a stub. You can help OpenEI...

  17. Cookson Electronics | Open Energy Information

    Open Energy Info (EERE)

    Place: Providence, Rhode Island Zip: 2903 Product: Rhode Island-based materials science company. The division produces PV junction boxes. References: Cookson Electronics1...

  18. Compact electron beam focusing column

    SciTech Connect (OSTI)

    Persaud, Arun; Leung, Ka-Ngo; Reijonen, Jani

    2001-07-13

    A novel design for an electron beam focusing column has been developed at LBNL. The design is based on a low-energy spread multicusp plasma source which is used as a cathode for electron beam production. The focusing column is 10 mm in length. The electron beam is focused by means of electrostatic fields. The column is designed for a maximum voltage of 50 kV. Simulations of the electron trajectories have been performed by using the 2-D simulation code IGUN and EGUN. The electron temperature has also been incorporated into the simulations. The electron beam simulations, column design and fabrication will be discussed in this presentation.

  19. Advancing the surgical implantation of electronic tags in fish: a gap analysis and research agenda based on a review of trends in intracoelomic tagging effects studies

    SciTech Connect (OSTI)

    Cooke, Steven J.; Woodley, Christa M.; Eppard, M. B.; Brown, Richard S.; Nielsen, Jennifer L.

    2011-03-08

    Early approaches to surgical implantation of electronic tags in fish were often through trial and error, however, in recent years there has been an interest in using scientific research to identify techniques and procedures that improve the outcome of surgical procedures and determine the effects of tagging on individuals. Here we summarize the trends in 108 peer-reviewed electronic tagging effect studies focused on intracoleomic implantation to determine opportunities for future research. To date, almost all of the studies have been conducted in freshwater, typically in laboratory environments, and have focused on biotelemetry devices. The majority of studies have focused on salmonids, cyprinids, ictalurids and centrarchids, with a regional bias towards North America, Europe and Australia. Most studies have focused on determining whether there is a negative effect of tagging relative to control fish, with proportionally fewer that have contrasted different aspects of the surgical procedure (e.g., methods of sterilization, incision location, wound closure material) that could advance the discipline. Many of these studies included routine endpoints such as mortality, growth, healing and tag retention, with fewer addressing sublethal measures such as swimming ability, predator avoidance, physiological costs, or fitness. Continued research is needed to further elevate the practice of electronic tag implantation in fish in order to ensure that the data generated are relevant to untagged conspecifics (i.e., no long-term behavioural or physiological consequences) and the surgical procedure does not impair the health and welfare status of the tagged fish. To that end, we advocate for i) rigorous controlled manipulations based on statistical designs that have adequate power, account for inter-individual variation, and include controls and shams, ii) studies that transcend the laboratory and the field with more studies in marine waters, iii) incorporation of knowledge and

  20. Enhanced electron collection in TiO{sub 2} nanoparticle-based dye-sensitized solar cells by an array of metal micropillars on a planar fluorinated tin oxide anode.

    SciTech Connect (OSTI)

    Yang, Z.; Xu, T.; Gao, S.; Welp, U.; Kwok, W.-K.; Materials Science Division; Northern Illinois Univ.

    2010-01-01

    Charge collection efficiency exhibits a strong influence on the overall efficiency of nanocrystalline dye-sensitized solar cells. It highly depends on the quality of the TiO{sub 2} nanoparticulate layer in the photoanode, and hence most efforts have been directed on the improvement and deliberate optimization of the quality the TiO{sub 2} nanocrystalline layer. In this work, we aim to reduce the electron collection distance between the place of origin in the TiO{sub 2} layer to the electron-collecting TCO anode as an alternative way to enhance the charge collection efficiency. We use an array of metal micropillars on fluorine-doped tin oxide (FTO) as the collecting anode. Under the same conditions, the Ni micropillar-on-FTO-based dye-sensitized solar cells (DSSCs) exhibit a remarkably enhanced current density, which is approximately 1.8 times greater compared with the bare FTO-based DSSCs. Electron transport was investigated using the electrochemical impedance spectroscopy technique. Our results reveal that the electron collection time in Ni micropillar-on-FTO-based DSSCs is much shorter than that of bare FTO-based DSSCs, indicating faster electron collection due to the Ni micropillars buried in TiO{sub 2} nanoparticulate layer that serve as electron transport shortcuts. As a result, the charge collection efficiency was enhanced by 15?20% with respect to that of the bare FTO-based DSSCs. Consequently, the overall energy conversion efficiency was found to increase from 2.6% in bare FTO-based DSSCs to 4.8% in Ni micropillar-on-FTO-based DSSCs for a 6 {micro}m-thick TiO{sub 2} NP film.

  1. Low thermal budget photonic processing of highly conductive Cu interconnects based on CuO nanoinks. Potential for flexible printed electronics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rager, Matthew S.; Aytug, Tolga; Veith, Gabriel M.; Joshi, Pooran C.

    2015-12-31

    The developing field of printed electronics nanoparticle based inks such as CuO show great promise as a low-cost alternative to other metal-based counterparts (e.g., silver). In particular, CuO inks significantly eliminate the issue of particle oxidation, before and during the sintering process, that is prevalent in Cu-based formulations. We report here the scalable and low-thermal budget photonic fabrication of Cu interconnects employing a roll-to-roll compatible pulse-thermal-processing (PTP) technique that enables phase reduction and subsequent sintering of inkjet-printed CuO patterns onto flexible polymer templates. Detailed investigations of curing and sintering conditions were performed to understand the impact of PTP system conditionsmore » on the electrical performance of the Cu patterns. Specifically, the impact of energy and power of photonic pulses on print conductivity was systematically studied by varying the following key processing parameters: pulse intensity, duration and sequence. Through optimization of such parameters, highly conductive prints in < 1 s with resistivity values as low as 100 n m has been achieved. We also observed that the introduction of an initial ink-drying step in ambient atmosphere, after the printing and before sintering, leads to significant improvements in mechanical integrity and electrical performance of the printed Cu patterns. Moreover, the viability of CuO reactive inks, coupled with the PTP technology and pre ink-drying protocols, has also been demonstrated for the additive integration of a low-cost Cu temperature sensor onto a flexible polymer substrate.« less

  2. Low thermal budget photonic processing of highly conductive Cu interconnects based on CuO nanoinks. Potential for flexible printed electronics

    SciTech Connect (OSTI)

    Rager, Matthew S.; Aytug, Tolga; Veith, Gabriel M.; Joshi, Pooran C.

    2015-12-31

    The developing field of printed electronics nanoparticle based inks such as CuO show great promise as a low-cost alternative to other metal-based counterparts (e.g., silver). In particular, CuO inks significantly eliminate the issue of particle oxidation, before and during the sintering process, that is prevalent in Cu-based formulations. We report here the scalable and low-thermal budget photonic fabrication of Cu interconnects employing a roll-to-roll compatible pulse-thermal-processing (PTP) technique that enables phase reduction and subsequent sintering of inkjet-printed CuO patterns onto flexible polymer templates. Detailed investigations of curing and sintering conditions were performed to understand the impact of PTP system conditions on the electrical performance of the Cu patterns. Specifically, the impact of energy and power of photonic pulses on print conductivity was systematically studied by varying the following key processing parameters: pulse intensity, duration and sequence. Through optimization of such parameters, highly conductive prints in < 1 s with resistivity values as low as 100 n m has been achieved. We also observed that the introduction of an initial ink-drying step in ambient atmosphere, after the printing and before sintering, leads to significant improvements in mechanical integrity and electrical performance of the printed Cu patterns. Moreover, the viability of CuO reactive inks, coupled with the PTP technology and pre ink-drying protocols, has also been demonstrated for the additive integration of a low-cost Cu temperature sensor onto a flexible polymer substrate.

  3. Mass-sensitive chemical preconcentrator

    DOE Patents [OSTI]

    Manginell, Ronald P.; Adkins, Douglas R.; Lewis, Patrick R.

    2007-01-30

    A microfabricated mass-sensitive chemical preconcentrator actively measures the mass of a sample on an acoustic microbalance during the collection process. The microbalance comprises a chemically sensitive interface for collecting the sample thereon and an acoustic-based physical transducer that provides an electrical output that is proportional to the mass of the collected sample. The acoustic microbalance preferably comprises a pivot plate resonator. A resistive heating element can be disposed on the chemically sensitive interface to rapidly heat and release the collected sample for further analysis. Therefore, the mass-sensitive chemical preconcentrator can optimize the sample collection time prior to release to enable the rapid and accurate analysis of analytes by a microanalytical system.

  4. Mass spectrometric immunoassay

    DOE Patents [OSTI]

    Nelson, Randall W.; Williams, Peter; Krone, Jennifer Reeve

    2005-12-13

    Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

  5. Mass spectrometric immunoassay

    DOE Patents [OSTI]

    Nelson, Randall W; Williams, Peter; Krone, Jennifer Reeve

    2013-07-16

    Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

  6. Mass spectrometric immunoassay

    DOE Patents [OSTI]

    Nelson, Randall W; Williams, Peter; Krone, Jennifer Reeve

    2007-12-04

    Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

  7. Imaging mass spectrometer with mass tags

    DOE Patents [OSTI]

    Felton, James S.; Wu, Kuang Jen; Knize, Mark G.; Kulp, Kristen S.; Gray, Joe W.

    2010-06-01

    A method of analyzing biological material by exposing the biological material to a recognition element, that is coupled to a mass tag element, directing an ion beam of a mass spectrometer to the biological material, interrogating at least one region of interest area from the biological material and producing data, and distributing the data in plots.

  8. Imaging mass spectrometer with mass tags

    DOE Patents [OSTI]

    Felton, James S.; Wu, Kuang Jen J.; Knize, Mark G.; Kulp, Kristen S.; Gray, Joe W.

    2013-01-29

    A method of analyzing biological material by exposing the biological material to a recognition element, that is coupled to a mass tag element, directing an ion beam of a mass spectrometer to the biological material, interrogating at least one region of interest area from the biological material and producing data, and distributing the data in plots.

  9. Thermal and mechanical properties of palm oil-based polyurethane acrylate/clay nanocomposites prepared by in-situ intercalative method and electron beam radiation

    SciTech Connect (OSTI)

    Salih, A. M.; Ahmad, Mansor Bin; Ibrahim, Nor Azowa; Dahlan, Khairul Zaman Hj Mohd; Tajau, Rida; Mahmood, Mohd Hilmi; Yunus, Wan Md. Zin Wan

    2014-02-12

    Palm oil based-polyurethane acrylate (POBUA)/clay nanocomposites were prepared via in-situ intercalative polymerization using epoxidized palm oil acrylate (EPOLA) and 4,4' methylene diphenyl diisocyante (MDI). Organically modified Montmorillonite (ODA-MMT) was incorporated in EPOLA (1, 3 and 5%wt), and then subjected to polycondensation reaction with MDI. Nanocomposites solid films were obtained successfully by electron beam radiation induced free radical polymerization (curing). FTIR results reveal that the prepolymer was obtained successfully, with nanoclay dispersed in the matrix. The intercalation of the clay in the polymer matrix was investigated by XRD and the interlayer spacing of clay was found to be increased up to 37 , while the structure morphology of the nanocomposites was investigated by TEM and SEM. The nanocomposites were found to be a mixture of exfoliated and intercalated morphologies. The thermal stability of the nanocomposites was significantly increased by incorporation of nanoclay into the polymer matrix. DSC results reveal that the Tg was shifted to higher values, gradually with increasing the amount of filler in the nanocomposites. Tensile strength and Young's modulus of the nanocomposites showed remarkable improvement compared to the neat POBUA.

  10. Coherent electron cooling

    SciTech Connect (OSTI)

    Litvinenko,V.

    2009-05-04

    Cooling intense high-energy hadron beams remains a major challenge in modern accelerator physics. Synchrotron radiation is still too feeble, while the efficiency of two other cooling methods, stochastic and electron, falls rapidly either at high bunch intensities (i.e. stochastic of protons) or at high energies (e-cooling). In this talk a specific scheme of a unique cooling technique, Coherent Electron Cooling, will be discussed. The idea of coherent electron cooling using electron beam instabilities was suggested by Derbenev in the early 1980s, but the scheme presented in this talk, with cooling times under an hour for 7 TeV protons in the LHC, would be possible only with present-day accelerator technology. This talk will discuss the principles and the main limitations of the Coherent Electron Cooling process. The talk will describe the main system components, based on a high-gain free electron laser driven by an energy recovery linac, and will present some numerical examples for ions and protons in RHIC and the LHC and for electron-hadron options for these colliders. BNL plans a demonstration of the idea in the near future.