Sample records for manganese superoxide dismutase

  1. Localization and Role of Manganese Superoxide Dismutase in a Marine Diatom1[OA

    E-Print Network [OSTI]

    the product in Escherichia coli, and purified the mature protein (TpMnSOD). This recombinant enzyme was usedLocalization and Role of Manganese Superoxide Dismutase in a Marine Diatom1[OA] Felisa Wolfe-Simon2 and Molecular Ecology Program, Institute of Marine and Coastal Sciences (F.W.-S., O.S., P.G.F.), and Department

  2. Investigation of the Highly Active Manganese Superoxide Dismutase from Saccharomyces cerevisiae

    SciTech Connect (OSTI)

    Cabelli, D.E.; Barnese, K.; Sheng, Y.; Stich, T.A.; Gralla, E.B.; Britt, R.D.; Valentine, J.S.

    2010-09-15T23:59:59.000Z

    Manganese superoxide dismutase (MnSOD) from different species differs in its efficiency in removing high concentrations of superoxide (O{sub 2}{sup -}), due to different levels of product inhibition. Human MnSOD exhibits a substantially higher level of product inhibition than the MnSODs from bacteria. In order to investigate the mechanism of product inhibition and whether it is a feature common to eukaryotic MnSODs, we purified MnSOD from Saccharomyces cerevisiae (ScMnSOD). It was a tetramer with 0.6 equiv of Mn per monomer. The catalytic activity of ScMnSOD was investigated by pulse radiolysis and compared with human and two bacterial (Escherichia coli and Deinococcus radiodurans) MnSODs. To our surprise, ScMnSOD most efficiently facilitates removal of high concentrations of O{sub 2}{sup -} among these MnSODs. The gating value k{sub 2}/k{sub 3} that characterizes the level of product inhibition scales as ScMnSOD > D. radiodurans MnSOD > E. coli MnSOD > human MnSOD. While most MnSODs rest as the oxidized form, ScMnSOD was isolated in the Mn{sup 2+} oxidation state as revealed by its optical and electron paramagnetic resonance spectra. This finding poses the possibility of elucidating the origin of product inhibition by comparing human MnSOD with ScMnSOD.

  3. Original Contribution SUPEROXIDE DISMUTASE MIMETICS ELEVATE SUPEROXIDE DISMUTASE

    E-Print Network [OSTI]

    Gems, David

    damage from reactive oxygen species (ROS), particularly superoxide and its derivatives. This predicts. Where life span was reduced by the superoxide generators paraquat and plumbagin, EUK-8 treatment increased life span in a dose-dependent fashion. Yet in the absence of a superoxide generator, treatment

  4. Overexpression of copper zinc superoxide dismutase impairs human trophoblast cell fusion and differentiation

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    investigated the role of the key antioxidant enzyme copper/zinc superoxide dismutase (SOD-1), encoded and the synthesis of steroid and peptide hormones required for fetal growth and development (5, 6). Some

  5. Effects of protein deficiency on superoxide dismutase and immunological competence in peritoneal macrophages of the guinea pig

    E-Print Network [OSTI]

    Burch, Troie Ann Pruett

    1979-01-01T23:59:59.000Z

    EFFECTS OF PROTEIN DEFICIENCY ON SUPEROXZDE DIcMUTASE AND LMMUNOLOGZCAL COMPETENCE IN PERITONEAL MACROPHAOES OF THE GUINEA PZG A Thesis By TROZE ANN PRUETT BURCH Submitted to the Graduate College of Texas ASM University in Partial... By TROIE ANN PRUETT BURCH Approved as to style and content by: (Chairman of t e Committee) (Head of the Department) (Mam (Member) (Member ) August 1979 ABSTRACT Effects of Protein Deficiency on Superoxide Dismutase and Tmmunologica' Competence...

  6. Nickel superoxide dismutase: structural and functional roles of His1 and its H-bonding network

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maroney, Michael J. [Univ. of Massachusetts, Amherst, MA (United States); Cabelli, Diane E. [Brookhaven National Lab. (BNL), Upton, NY (United States); Ryan, Kelly C. [Univ. of Massachusetts, Amherst, MA (United States); Guce, Abigail I. [Univ. of Massachusetts, Amherst, MA (United States); Johnson, Olivia E. [Univ. of Wisconsin, Madison, WI (United States); Brunold, Thomas C. [Univ. of Wisconsin, Madison, WI (United States); Garman, Scott C. [Univ. of Massachusetts, Amherst, MA (United States)

    2015-02-03T23:59:59.000Z

    Crystal structures of nickel-dependent superoxide dismutases (NiSODs) reveal the presence of a H-bonding network formed between the NH group of the apical imidazole ligand from His1 and the Glu17 carboxylate from a neighboring subunit in the hexameric enzyme. This interaction is supported by another intrasubunit H-bond between Glu17 and Arg47. In this study, four mutant NiSOD proteins were produced to experimentally evaluate the roles of this H-bonding network and compare the results with prior predictions from density functional theory calculations. The X-ray crystal structure of H1A-NiSOD, which lacks the apical ligand entirely, reveals that in the absence of the Glu17-His1 H-bond, the active site is disordered. Characterization of this variant using X-ray absorption spectroscopy (XAS) shows that Ni(II) is bound in the expected N?S? planar coordination site. Despite these structural perturbations, the H1A-NiSOD variant retains 4% of wild-type (WT) NiSOD activity. Three other mutations were designed to preserve the apical imidazole ligand but perturb the H-bonding network: R47A-NiSOD, which lacks the intramolecular H-bonding interaction; E17R/R47A-NiSOD, which retains the intramolecular H-bond but lacks the intermolecular Glu17-His1 H-bond; and E17A/R47ANiSOD, which lacks both H-bonding interactions. These variants were characterized by a combination of techniques, including XAS to probe the nickel site structure, kinetic studies employing pulse-radiolytic production of superoxide, and electron paramagnetic resonance to assess the Ni redox activity. The results indicate that in addition to the roles in redox tuning suggested on the basis of previous computational studies, the Glu17-His1 H-bond plays an important structural role in the proper folding of the “Ni-hook” motif that is a critical feature of the active site.

  7. Nickel superoxide dismutase: structural and functional roles of His1 and its H-bonding network

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Maroney, Michael J.; Cabelli, Diane E.; Ryan, Kelly C.; Guce, Abigail I.; Johnson, Olivia E.; Brunold, Thomas C.; Garman, Scott C.

    2015-02-03T23:59:59.000Z

    Crystal structures of nickel-dependent superoxide dismutases (NiSODs) reveal the presence of a H-bonding network formed between the NH group of the apical imidazole ligand from His1 and the Glu17 carboxylate from a neighboring subunit in the hexameric enzyme. This interaction is supported by another intrasubunit H-bond between Glu17 and Arg47. In this study, four mutant NiSOD proteins were produced to experimentally evaluate the roles of this H-bonding network and compare the results with prior predictions from density functional theory calculations. The X-ray crystal structure of H1A-NiSOD, which lacks the apical ligand entirely, reveals that in the absence of the Glu17-His1more »H-bond, the active site is disordered. Characterization of this variant using X-ray absorption spectroscopy (XAS) shows that Ni(II) is bound in the expected N?S? planar coordination site. Despite these structural perturbations, the H1A-NiSOD variant retains 4% of wild-type (WT) NiSOD activity. Three other mutations were designed to preserve the apical imidazole ligand but perturb the H-bonding network: R47A-NiSOD, which lacks the intramolecular H-bonding interaction; E17R/R47A-NiSOD, which retains the intramolecular H-bond but lacks the intermolecular Glu17-His1 H-bond; and E17A/R47ANiSOD, which lacks both H-bonding interactions. These variants were characterized by a combination of techniques, including XAS to probe the nickel site structure, kinetic studies employing pulse-radiolytic production of superoxide, and electron paramagnetic resonance to assess the Ni redox activity. The results indicate that in addition to the roles in redox tuning suggested on the basis of previous computational studies, the Glu17-His1 H-bond plays an important structural role in the proper folding of the “Ni-hook” motif that is a critical feature of the active site.« less

  8. Role of copper in the regulation of CU, ZN-superoxide dismutase in human K562 erythroleukemia cells and human fibroblasts

    E-Print Network [OSTI]

    Yu, Dan

    1994-01-01T23:59:59.000Z

    Activation of the enzyme CU2Zn2-SUperoxide dismutase (CuZnSOD) by its copper cofactor was studied in K562 erythroleukemia cells and skin fibroblasts. K562 cells were incubated in medium supplemented with 0-50 IIM CUC12 or ZnCI2 for 24 h and extracts...

  9. A Multinuclear Copper(I) Cluster Forms the Dimerization Interface in Copper-Loaded Human Copper Chaperone for Superoxide Dismutase

    SciTech Connect (OSTI)

    Stasser, J.P.; Siluvai, G.S.; Barry, A.N.; Blackburn, N.J.

    2009-06-04T23:59:59.000Z

    Copper binding and X-ray aborption spectroscopy studies are reported on untagged human CCS (hCCS; CCS = copper chaperone for superoxide dismutase) isolated using an intein self-cleaving vector and on single and double Cys to Ala mutants of the hCCS MTCQSC and CSC motifs of domains 1 (D1) and 3 (D3), respectively. The results on the wild-type protein confirmed earlier findings on the CCS-MBP (maltose binding protein) constructs, namely, that Cu(I) coordinates to the CXC motif, forming a cluster at the interface of two D3 polypeptides. In contrast to the single Cys to Ser mutations of the CCS-MBP protein (Stasser, J. P., Eisses, J. F., Barry, A. N., Kaplan, J. H., and Blackburn, N. J. (2005) Biochemistry 44, 3143-3152), single Cys to Ala mutations in D3 were sufficient to eliminate cluster formation and significantly reduce CCS activity. Analysis of the intensity of the Cu-Cu cluster interaction in C244A, C246A, and C244/246A variants suggested that the nuclearity of the cluster was greater than 2 and was most consistent with a Cu4S6 adamantane-type species. The relationship among cluster formation, oligomerization, and metal loading was evaluated. The results support a model in which Cu(I) binding converts the apo dimer with a D2-D2 interface to a new dimer connected by cluster formation at two D3 CSC motifs. The predominance of dimer over tetramer in the cluster-containing species strongly suggests that the D2 dimer interface remains open and available for sequestering an SOD1 monomer. This work implicates the copper cluster in the reactive form and adds detail to the cluster nuclearity and how copper loading affects the oligomerization states and reactivity of CCS for its partner SOD1.

  10. The Cu-Zn superoxide dismutase (SOD1) inhibits ERK phosphorylation by muscarinic receptor modulation in rat pituitary GH3 cells

    SciTech Connect (OSTI)

    Secondo, Agnese [Department of Neuroscience, Section of Pharmacology, University of Naples 'Federico II', Via S. Pansini, 5, 80131 Naples (Italy); De Mizio, Mariarosaria; Zirpoli, Laura; Santillo, Mariarosaria [Department of Neuroscience, Section of Physiology, University of Naples 'Federico II', Via S. Pansini, 5, 80131 Naples (Italy); Mondola, Paolo [Department of Neuroscience, Section of Physiology, University of Naples 'Federico II', Via S. Pansini, 5, 80131 Naples (Italy)], E-mail: mondola@unina.it

    2008-11-07T23:59:59.000Z

    The Cu-Zn superoxide dismutase (SOD1) belongs to a family of isoenzymes that are able to dismutate the oxygen superoxide in hydrogen peroxide and molecular oxygen. This enzyme is secreted by many cellular lines and it is also released trough a calcium-dependent depolarization mechanism involving SNARE protein SNAP 25. Using rat pituitary GH3 cells that express muscarinic receptors we found that SOD1 inhibits P-ERK1/2 pathway trough an interaction with muscarinic M1 receptor. This effect is strengthened by oxotremorine, a muscarinic M agonist and partially reverted by pyrenzepine, an antagonist of M1 receptor; moreover this effect is independent from increased intracellular calcium concentration induced by SOD1. Finally, P-ERK1/2 inhibition was accompanied by the reduction of GH3 cell proliferation. These data indicate that SOD1 beside the well studied antioxidant properties can be considered as a neuromodulator able to affect mitogen-activated protein kinase in rat pituitary cells trough a M1 muscarinic receptor.

  11. Sequence and Structural Determinants of Cu, Zn Superoxide Dismutase Aggregation

    E-Print Network [OSTI]

    Dokholyan, Nikolay V.

    , 2 microglobu- lin, and tau protein, have been shown to form amyloid fibrils in vitro (Thirumalai et dynamics simula- tion; protein misfolding; domain- swapping INTRODUCTION The formation of protein of native proteins to amyloids.4,5 Peptides corresponding to sequence fragments of amyloid-forming

  12. High resistance to oxidative damage in the Antarctic midge Belgica antarctica, and developmentally linked expression of genes encoding superoxide

    E-Print Network [OSTI]

    Lee Jr., Richard E.

    antioxidant enzymes, superoxide dismutase (SOD) and catalase (Cat), and showed that SOD mRNA was expressed upregulated in response to sunlight. Total antioxidant capacity of the adults was higher than and fragmentation of the peptide chain to total enzyme inactivation by superoxide anions (Stadtman, 1986). ROS can

  13. Characterization of superoxide production by isolated pea thylakoids

    SciTech Connect (OSTI)

    Grace, S.; Osmond, B. (Duke Univ., Durham, NC (United States))

    1991-05-01T23:59:59.000Z

    During photosynthesis chloroplasts univalently reduce molecular oxygen to superoxide through autoxidations in the electron transport chain. Cytochrome c reduction was used to assay superoxide production in illuminate pea thylakoids under a variety of conditions. Superoxide dismutase was found to inhibit the reaction by 80%, indicating that cytochrome c reduction is primarily mediated by superoxide. This was further supported by the observation that the highest rates of cytochrome c reduction occurred in the presence of methyl viologen, an autoxidizable redox carrier that accepts electrons from photosystem I. The reaction was fully suppressed by DCMU, demonstrating a requirement for electron transport. In the presence of the plastoquinone antagonist DBMIB the rate of cytochrome c reduction increased substantially. This indicates that under conditions where electron transport to photosystem I is blocked, autoxidation reactions can occur on the reducing side of photosystem II to maintain Q{sub A} in the oxidized state. Superoxide production at sites other than the reducing side of photosystem I may thus represent an important pathway for dissipating excess excitation energy.

  14. Oxidative Modifications and Aggregation of Cu,Zn-Superoxide Dismutase Associated with Alzheimer and Parkinson Diseases*

    E-Print Network [OSTI]

    Li, Lian

    to cysteic acid in AD and PD brains. Quantitative Western blot analyses demonstrate that the total level(s) that could potentially be tar- geted by similar therapeutic strategies. Alzheimer disease (AD),1 Parkinson

  15. Reactive Gliosis Reactive Oxygen Species: Superoxide

    E-Print Network [OSTI]

    . By sensing the electric signals generated by other 3368 Reactive Gliosis #12;individuals, mormyrids are alsoReactive Gliosis Glial Scar Reactive Oxygen Species: Superoxide Anions Neuroinflammation motor output. Reafferent Control in Electric Communication Reafferent Control in Electric Communication

  16. Effects of a superoxide dismutase mimetic on biomarkers of lung angiogenesis and alveolarization during hyperoxia with intermittent hypoxia

    E-Print Network [OSTI]

    Chang, Michael; Bany-Mohammed, Fayez; Kenney, M Cristina; Beharry, Kay D

    2013-01-01T23:59:59.000Z

    Dif- ferential responses in the lungs of newborn mouse pupsdismutase protein in the lungs of patients with respiratoryventilation exposes the lungs of ELGANs to oxidative stress

  17. CHARACTERIZATION OF THE STRUCTURE AND REACTIVITY OF A NICKEL(II)-TRIPEPTIDE MIMIC OF NICKEL SUPEROXIDE DISMUTASE

    E-Print Network [OSTI]

    Glass, Amanda M.

    2012-08-31T23:59:59.000Z

    The tripeptide asparagine-cysteine-cysteine (NCC) was found by the J. Laurence lab to bind nickel very tightly. In fact, NCC was serendipitously discovered as a metal-abstraction peptide tag (MAP-tag) because it was stripping nickel from a standard...

  18. Action of manganese on puberty

    E-Print Network [OSTI]

    Lee, Bo Yeon

    2007-09-17T23:59:59.000Z

    Manganese (Mn) is considered important for normal growth and reproduction. Because Mn can cross the blood brain barrier and accumulate in the hypothalamus, and because it has been suggested that infants and children are potentially more sensitive...

  19. Heteroepitaxial Nucleation and Oriented Growth of Manganese

    E-Print Network [OSTI]

    Heteroepitaxial Nucleation and Oriented Growth of Manganese Oxide Islands on Carbonate Minerals-limit. Our results provide an improved basis both for the development of predictive models of contaminant Manganese oxide minerals in surface and groundwaters dissolve as Mn2+ (aq) and precipitate as manganese

  20. Superoxide reduction by a superoxide reductase lacking the highly conserved lysine residue

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Teixeira, Miguel [Univ. Nova de Lisboa, Oeiras (Portugal); Cabelli, Diane [Brookhaven National Lab. (BNL), Upton, NY (United States); Pinto, Ana F. [Univ. Nova de Lisboa, Oeiras (Portugal); Karolinska Inst., Stockholm (Sweden); Romao, Celia V. [Univ. Nova de Lisboa, Oeiras (Portugal); Pinto, Liliana C. [Univ. Nova de Lisboa, Oeiras (Portugal); Huber, Harald [Univ. Regensburg, Regensburg (Germany); Saraiva, Ligia M. [Univ. Nova de Lisboa, Oeiras (Portugal); Todorovic, Smilja [Univ. Nova de Lisboa, Oeiras (Portugal)

    2015-01-01T23:59:59.000Z

    Superoxide reductases (SORs) are the most recently identified superoxide detoxification systems, being found in microorganisms from the three domains of life. These enzymes are characterized by a catalytic mononuclear iron site, with one cysteine and four histidine ligands of the ferrous active form. A lysine residue in the –EKHVP– motif, located close to the active site, has been considered to be essential for the enzyme function, by contributing to the positive surface patch that attracts the superoxide anion and by controlling the chemistry of the catalytic mechanism through a hydrogen bond network. However, we show here that this residue is substituted by non-equivalent amino acids in several putative SORs from Archaea and unicellular Eukarya. In this work, we focus on mechanistic and spectroscopic studies of one of these less common enzymes, the SOR from the hyperthermophilic crenarchaeon Ignicoccus hospitalis. We employ pulse radiolysis fast kinetics and spectroscopic approaches to study the wild-type enzyme (?E??T??HVP?), and two mutants, T24K and E23A, the later mimicking enzymes lacking both the lysine and glutamate (a ferric ion ligand) of the motif. The efficiency of the wild type protein and mutants in reducing superoxide is comparable to other SORs, revealing the robustness of these enzymes to single mutations.

  1. Superoxide reduction by a superoxide reductase lacking the highly conserved lysine residue

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Teixeira, Miguel; Cabelli, Diane; Pinto, Ana F.; Romao, Celia V.; Pinto, Liliana C.; Huber, Harald; Saraiva, Ligia M.; Todorovic, Smilja

    2015-01-01T23:59:59.000Z

    Superoxide reductases (SORs) are the most recently identified superoxide detoxification systems, being found in microorganisms from the three domains of life. These enzymes are characterized by a catalytic mononuclear iron site, with one cysteine and four histidine ligands of the ferrous active form. A lysine residue in the –EKHVP– motif, located close to the active site, has been considered to be essential for the enzyme function, by contributing to the positive surface patch that attracts the superoxide anion and by controlling the chemistry of the catalytic mechanism through a hydrogen bond network. However, we show here that this residue ismore »substituted by non-equivalent amino acids in several putative SORs from Archaea and unicellular Eukarya. In this work, we focus on mechanistic and spectroscopic studies of one of these less common enzymes, the SOR from the hyperthermophilic crenarchaeon Ignicoccus hospitalis. We employ pulse radiolysis fast kinetics and spectroscopic approaches to study the wild-type enzyme (?E??T??HVP?), and two mutants, T24K and E23A, the later mimicking enzymes lacking both the lysine and glutamate (a ferric ion ligand) of the motif. The efficiency of the wild type protein and mutants in reducing superoxide is comparable to other SORs, revealing the robustness of these enzymes to single mutations.« less

  2. Superoxide reduction by a superoxide reductase lacking the highly conserved lysine residue

    SciTech Connect (OSTI)

    Teixeira, Miguel [Univ. Nova de Lisboa, Oeiras (Portugal); Cabelli, Diane [Brookhaven National Lab. (BNL), Upton, NY (United States); Pinto, Ana F. [Univ. Nova de Lisboa, Oeiras (Portugal); Karolinska Inst., Stockholm (Sweden); Romao, Celia V. [Univ. Nova de Lisboa, Oeiras (Portugal); Pinto, Liliana C. [Univ. Nova de Lisboa, Oeiras (Portugal); Huber, Harald [Univ. Regensburg, Regensburg (Germany); Saraiva, Ligia M. [Univ. Nova de Lisboa, Oeiras (Portugal); Todorovic, Smilja [Univ. Nova de Lisboa, Oeiras (Portugal)

    2015-01-01T23:59:59.000Z

    Superoxide reductases (SORs) are the most recently identified superoxide detoxification systems, being found in microorganisms from the three domains of life. These enzymes are characterized by a catalytic mononuclear iron site, with one cysteine and four histidine ligands of the ferrous active form. A lysine residue in the –EKHVP– motif, located close to the active site, has been considered to be essential for the enzyme function, by contributing to the positive surface patch that attracts the superoxide anion and by controlling the chemistry of the catalytic mechanism through a hydrogen bond network. However, we show here that this residue is substituted by non-equivalent amino acids in several putative SORs from Archaea and unicellular Eukarya. In this work, we focus on mechanistic and spectroscopic studies of one of these less common enzymes, the SOR from the hyperthermophilic crenarchaeon Ignicoccus hospitalis. We employ pulse radiolysis fast kinetics and spectroscopic approaches to study the wild-type enzyme (?E??T??HVP?), and two mutants, T24K and E23A, the later mimicking enzymes lacking both the lysine and glutamate (a ferric ion ligand) of the motif. The efficiency of the wild type protein and mutants in reducing superoxide is comparable to other SORs, revealing the robustness of these enzymes to single mutations.

  3. Superoxide Mediates Acute Liver Injury in Irradiated Mice Lacking Sirtuin 3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Coleman, Mitchell C.; Olivier, Alicia K.; Jacobus, James A.; Mapuskar, Kranti A.; Mao, Gaowei; Martin, Sean M.; Riley, Dennis P.; Gius, David; Spitz, Douglas R.

    2014-01-01T23:59:59.000Z

    Aims: This study determined whether acute radiation-induced liver injury seen in Sirtuin3 - / - mice after exposure to Cs-137 c-rays was mediated by superoxide anion (O2#2; - ). Results: Male wild-type (WT) and SIRT3 - / - mice were given 2 · 2Gy whole-body radiation doses separated by 24 h and livers were harvested 20 h after the second dose. Ex vivo measurements in fresh frozen liver sections demonstrated 50% increases in dihydroethidium oxidation from SIRT3 - / - animals, relative to WT animals, before irradiation, but this increase was not detected 20 h after radiation exposure. In addition, irradiated livers from SIRT3 - / - animals showed significant hydropic degeneration, loss of MitoTracker Green FM staining, increased immunohistochemical staining for 3-nitrotyrosine, loss of Ki67 staining, and increased mitochondrial localization of p53. These parameters of radiation-induced injury were significantly attenuated by an intraperitoneal injection of 2mg/kg of the highly specific superoxide dismutase mimic, GC4401, 30min before each fraction. Innovation: Sirtuin 3 (SIRT3) is believed to regulate mitochondrial oxidative metabolism and antioxidant defenses in response to acute radiation-induced liver injury. This work provides strong evidence for the causal role of O2 #2; - in the liver injury process initiated by whole-body irradiation in SIRT3 - / - mice. Conclusion: These results support the hypothesis that O2#2; - mediates acute liver injury in SIRT3 - / - animals exposed to whole-body c-radiation and suggest that GC4401 could be used as a radio-protective compound in vivo.

  4. New manganese catalyst for light alkane oxidation

    DOE Patents [OSTI]

    Durante, Vincent A. (West Chester, PA); Lyons, James E. (Wallingford, PA); Walker, Darrell W. (Visalia, CA); Marcus, Bonita K. (Radnor, PA)

    1994-01-01T23:59:59.000Z

    Aluminophosphates containing manganese in the structural framework are employed for the oxidation of alkanes, for example the vapor phase oxidation of methane to methanol.

  5. Manganese Oxide Composite Electrodes for Lithium Batteries |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Oxide Composite Electrodes for Lithium Batteries Technology available for licensing: Improved spinel-containing "layered-layered" lithium metal oxide electrodes Materials...

  6. Thermodynamic Investigations of Lithium- and Manganese-Rich Transition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermodynamic Investigations of Lithium- and Manganese-Rich Transition Metal Oxides Thermodynamic Investigations of Lithium- and Manganese-Rich Transition Metal Oxides 2013 DOE...

  7. Examining Hysteresis in Lithium- and Manganese-Rich Composite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hysteresis in Lithium- and Manganese-Rich Composite Cathode Materials Examining Hysteresis in Lithium- and Manganese-Rich Composite Cathode Materials 2013 DOE Hydrogen and Fuel...

  8. Addressing the Voltage Fade Issue with Lithium-Manganese-Rich...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode Materials Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode Materials 2013 DOE...

  9. Addressing the Voltage Fade Issue with Lithium-Manganese-Rich...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode Materials Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode Materials 2012 DOE Hydrogen and...

  10. Hair As A Biomarker Of Environmental Manganese Exposure

    E-Print Network [OSTI]

    Eastman, Rachel

    2012-01-01T23:59:59.000Z

    Neuropsychological correlates of hair arsenic, manganese,and physiology of hair. , Forensic Science International 63,D. (2010) High levels of hair manganese in children living

  11. Similar Transition States Mediate the Q-cycle and Superoxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the uninhibited Q-cycle and superoxide production in the presence of Antimycin A in wild type. This behavior was also preserved in a series of mutants with altered driving...

  12. MANGANESE--2003 48.1 By Lisa A. Corathers

    E-Print Network [OSTI]

    Torgersen, Christian

    , including its ironmaking component, has accounted for most of the domestic manganese demand, presently

  13. Relationship of the superoxide dismutase genes, sodA and sodB, to the iron uptake (/ital fur/) regulon in /ital Escherichia coli/ K-12

    SciTech Connect (OSTI)

    Niederhoffer, E.C.; Naranjo, C.M.; Fee, J.A.

    1988-01-01T23:59:59.000Z

    Expression of sodA, as indicated by MnSod activity is normal in /ital fur/ mutants. This suggests that sodA is not a member of the /ital fur/ regulon and that the putative Fe-binding, regulatory protein of sodA, suggested by Moody and Hassan is not the Fur protein. by contrast, expression of sodB, as indicated by FeSod activity, is completely blocked in /ital fur/ mutants and the effect is restored by transformation with a plasmid having a normal /ital fur/ locus. The observations suggest that Fur, either directly or indirectly, controls SodB biosynthesis. Additional observations are described which indicate that SodB and Fur act together in a complicated fashion to control the biosynthesis of enterobactin. 26 refs., 3 tabs.

  14. Effect of Catalase/Superoxide Dismutase Mimetic EUK-134 on Damage, Inflammation, and Force Generation of the Diaphragm Muscle in mdx Mice

    E-Print Network [OSTI]

    Kim, Jong Hee

    2010-10-12T23:59:59.000Z

    Duchenne muscular dystrophy (DMD) is the most devastating form of muscular dystrophy caused by a mutation in the dystrophin gene. Defects in the dystrophin gene in DMD, are homologous to that found in mdx mice, and result in profound muscle damage...

  15. MANGANESE--1998 49.1 By Thomas S. Jones

    E-Print Network [OSTI]

    Torgersen, Christian

    -carbon ferromanganese. In manganese-containing dry cell batteries, the feasibility of recycling such batteries aluminum alloys and is used in oxide form in dry cell batteries. The overall level and nature of manganese year 1998 was 18,144 metric tons (t) for natural battery-grade ore, 2,732 t for synthetic manganese

  16. Silver manganese oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Vaughey, John T.; Dees, Dennis W.

    2006-05-09T23:59:59.000Z

    This invention relates to electrodes for non-aqueous lithium cells and batteries with silver manganese oxide positive electrodes, denoted AgxMnOy, in which x and y are such that the manganese ions in the charged or partially charged electrodes cells have an average oxidation state greater than 3.5. The silver manganese oxide electrodes optionally contain silver powder and/or silver foil to assist in current collection at the electrodes and to improve the power capability of the cells or batteries. The invention relates also to a method for preparing AgxMnOy electrodes by decomposition of a permanganate salt, such as AgMnO4, or by the decomposition of KMnO4 or LiMnO4 in the presence of a silver salt.

  17. Drinking Water Problems: Iron and Manganese

    E-Print Network [OSTI]

    Dozier, Monty; McFarland, Mark L.

    2004-02-20T23:59:59.000Z

    . The chemical must be in the water for at least 20 minutes for oxi- dation to take place, longer if the water contains colloidal iron/manganese. After solid particles have formed they are filtered, often with a sand filter. Adding aluminum sulfate (alum...

  18. Promises and Challenges of Lithium- and Manganese-Rich Transition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrochemical Modeling of LMR-NMC Materials and Electrodes Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode Materials PHEV Battery Cost Assessment...

  19. address arsenic manganese: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mobilization in the critical zone: Oxidation by manganese oxide minerals Environmental Management and Restoration Websites Summary: . Lafferty2, Donald L. Sparks1. (1)...

  20. Manganese-Based Magnets: Manganese-Based Permanent Magnet with 40 MGOe at 200°C

    SciTech Connect (OSTI)

    None

    2012-01-01T23:59:59.000Z

    REACT Project: PNNL is working to reduce the cost of wind turbines and EVs by developing a manganese-based nano-composite magnet that could serve as an inexpensive alternative to rare-earth-based magnets. The manganese composite, made from low-cost and abundant materials, could exceed the performance of today’s most powerful commercial magnets at temperature higher than 200°C. Members of PNNL’s research team will leverage comprehensive computer high-performance supercomputer modeling and materials testing to meet this objective. Manganese-based magnets could withstand higher temperatures than their rare earth predecessors and potentially reduce the need for any expensive, bulky engine cooling systems for the motor and generator. This would further contribute to cost savings for both EVs and wind turbines.

  1. Reaction of Plutonium(VI) with the Manganese-Substituted Iron Oxide Mineral Goethite

    E-Print Network [OSTI]

    Hu, Yung-Jin Hu

    2011-01-01T23:59:59.000Z

    4.2 Goethite . . . . . . . . . . . . . . . .on Manganese-Substituted Goethite . . . . . . . . . 7.4.14.3 Manganese-Substituted Goethite . . 4.3.1

  2. Mn(II) Oxidation by an Ascomycete Fungus is Linked to Superoxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Asexual Reproduction. Abstract: Manganese (Mn) oxides are among the most reactive minerals within the environment, where they control the bioavailability of carbon, nutrients,...

  3. MANGANESE--2001 49.1 By Lisa A. Corathers

    E-Print Network [OSTI]

    Torgersen, Christian

    MANGANESE--2001 49.1 MANGANESE By Lisa A. Corathers Domestic survey data and tables were prepared by 11%, while the number of units imported declined by 19%. While 2001 prices of ore continued the rising trend of 2000, prices of ferroalloys fell in 2001. The amount of increase for metallurgical

  4. Effect of quantity and route of administration of manganese monoxide on feed intake and serum manganese in ruminants

    SciTech Connect (OSTI)

    Black, J.R.; Ammerman, C.B.; Henry, P.R.

    1985-02-01T23:59:59.000Z

    The experiment investigated effects of high quantities of manganese and route of administration (diet versus capsule-dosed) on feed intake and blood characteristics in sheep. Twenty-four Florida native or Florida native by St. Croix crossbred wethers, 47 kg initially, were assigned randomly to eight treatments including basal diet supplemented with 0, 3000, 6000, or 9000 ppm manganese as a reagent grade manganese monoxide or basal diet plus gelatin capsules containing the equivalent of 0, 3000, 6000, or 9000 ppm manganese based on intake of the previous day. Three sheep per treatment were provided feed and tap water for ad libitum intake. Sheep were fed basal diet for 7 days followed by a 21-day experimental period, then placed back on the basal diet for 7 days. Average daily feed intake was reduced by increasing supplemental manganese, regardless of route. Animals dosed by capsule consumed less feed than those administered manganese in the diet. Serum manganese increased as manganese supplementation increased, but route of administration had no effect.

  5. Superoxide Electrochemistry in an Ionic Liquid Inas M. AlNashef, Matthew L. Leonard, Michael A. Matthews,* and

    E-Print Network [OSTI]

    Weidner, John W.

    -temperature molten salt systems.21 Os- teryoung et al.22 showed that superoxide ion could be generated

  6. Manganese in Texas Soils and its Relation to Crops.

    E-Print Network [OSTI]

    Carlyle, E. C. (Elmer Cardinal)

    1931-01-01T23:59:59.000Z

    manganese salts in pot ex1 rnents to a productive Hagerstown loam from the plots of the PC sylvania Experiment Station. The soil was slightly acid, and they tained no beneficial results with wheat. Skinner and Reid ~eported in 1916 (17) a six-year test... wit11 wh rye, corn, and soy beans, on an acicl silty clay loam soil at the Esp ment Station farm at Arlington, Virginia.. When no manganese fate was used, one acre yielded 4192 pounds of wheat straw and grz , with manganese the yielcl was 3258...

  7. (Data in thousand metric tons gross weight unless otherwise specified) Domestic Production and Use: Manganese ore containing 35% or more manganese was not produced domestically

    E-Print Network [OSTI]

    Torgersen, Christian

    as production of dry cell batteries, plant fertilizers and animal feed, and as a brick colorant. Manganese Recycling: Manganese was recycled incidentally as a minor constituent of ferrous and nonferrous scrap inventory inventory for disposal FY 2006 FY 2006 Manganese ore: Battery grade -- 18 -- 27 -- Chemical grade

  8. (Data in thousand metric tons gross weight unless otherwise specified) Domestic Production and Use: Manganese ore containing 35% or more manganese was not produced domestically

    E-Print Network [OSTI]

    Torgersen, Christian

    as production of dry cell batteries, in plant fertilizers and animal feed, and as a brick colorant. Manganese of apparent consumption 100 100 100 100 100 Recycling: Manganese was recycled incidentally as a minor inventory inventory for disposal FY 2007 FY 2007 Manganese ore: Battery grade 16 2 16 27 2 Chemical grade 0

  9. (Data in thousand metric tons gross weight unless otherwise specified) Domestic Production and Use: Manganese ore containing 35% or more manganese was not produced

    E-Print Network [OSTI]

    Torgersen, Christian

    as production of dry cell batteries, plant fertilizers and animal feed, and as a brick colorant. Manganese Recycling: Manganese was recycled incidentally as a minor constituent of ferrous and nonferrous scrap inventory inventory for disposal FY 2005 FY 2005 Manganese ore: Battery grade -- 18 -- 27 23 Chemical grade

  10. (Data in thousand metric tons gross weight unless otherwise specified) Domestic Production and Use: Manganese ore containing 35% or more manganese was not produced domestically

    E-Print Network [OSTI]

    Torgersen, Christian

    as production of dry cell batteries, in plant fertilizers and animal feed, and as a brick colorant. Manganese 100 100 100 100 Recycling: Manganese was recycled incidentally as a minor constituent of ferrous FY 2008 FY 2008 Manganese ore: Battery grade -- -- 18 16 Chemical grade -- -- -- -- Metallurgical

  11. Molecular Interactions of Plutonium(VI) with SyntheticManganese...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on the surface of well-characterized synthetic manganese-substituted goethite minerals (Fe1-xMnxOOH) was studied using X-ray absorption spectroscopy. We chose to study the...

  12. Electrochromic reactions in manganese oxides I. Raman analysis

    SciTech Connect (OSTI)

    Bernard, M.C.; Hugot-Le Goff, A.; Thi, B.V. (Univ. Pierre et Marie Curie, Paris (France). UPR 15 du CNRS Physique des Liquides et Electrochimie); Cordoba de Torresi, S. (Univ. Estadual de Campinas (Brazil). Dept. de Fisica Aplicada)

    1993-11-01T23:59:59.000Z

    Like nickel oxide, manganese oxide is a widely studied material in the primary batteries field. The reactions taking place during voltametric cycling of manganese oxides can be determined using in situ Raman spectroscopy. The main difficulty for the oxide identification is to obtain relevant Raman reference spectra because of the many possible compounds and, for some of these compounds, of their instability in the laser beam. As a consequence, several modifications of different tetra-, tri- and divalent manganese oxides and oxyhydroxides were carefully studied. The electrochromic behavior of three types of manganese oxides, two prepared by thermal oxidations and the other by electrochemical deposition, were then compared. The presence of nonstoichiometry in the pristine material was necessary to obtain a reversible electrochromic effect. The reaction during electrochromic cycling is more complicated than a simple passage from MnO[sub 2] to MnOOH.

  13. Manganese Based Oxidative Technologies For Water/Wastewater Treatment 

    E-Print Network [OSTI]

    Desai, Ishan

    2013-08-27T23:59:59.000Z

    Manganese is a commonly occurring mineral found in soil and sediments that takes part in chemical reactions in groundwater and soil systems. It plays a significant role in controlling the environmental fate and transport ...

  14. SOFC Ohmic Resistance Reduction by HCl-Induced Removal of Manganese...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SOFC Ohmic Resistance Reduction by HCl-Induced Removal of Manganese at the AnodeElectrolyte Interface. SOFC Ohmic Resistance Reduction by HCl-Induced Removal of Manganese at the...

  15. Electrical behavior of natural manganese dioxide (NMD)

    SciTech Connect (OSTI)

    Gorgulho, H.F. [Fundacao de Ensino Superior de Sao Joao del Rei, Minas Gerais (Brazil); Fernandes, R.Z.D.; Pernaut, J.M. [Univ. Federal de Minas Gerais, Belo Horizonte, Minas Gerais (Brazil)

    1996-12-31T23:59:59.000Z

    NMD samples from Brazil have been submitted to magnetic and particle size separations and characterized by X-ray diffraction and fluorescence and thermogravimetric analyses. Results showed that simple physical treatments can lead to more than 60% enriched MnO{sub 2} materials which could satisfy some electrochemical applications. The electrical properties of the samples conditioned as pressed pellets have been investigated by four-points direct current probe and impedance spectroscopy, varying the conditions of preparation and measurement. It is proposed that the higher frequency impedance is equivalent to the intrinsic electronic resistance of the MnO{sub 2} phases while at lower frequencies occurs an interphase charge separation coupled with a possible ionic transport. The corresponding contact resistance depends on the particle size distribution of the material, the compactation pressure of pellets and the iron content of the materials. The interphase dielectric relaxation does not behave ideally; the depression of the impedance semicircles as shown in the Nyquist plane is assumed to be related to the roughness of the bulk interfaces. Recent developments have shown the possibility of using manganese oxides as reversible electrodes for battery or supercapacitor applications for electrical vehicle. In these perspectives it is important to study the electrical and electrochemical properties of NMD in order to estimate its suitability for this kind of applications.

  16. Manganese sulfide formation via concomitant microbial manganese oxide and thiosulfate reduction

    SciTech Connect (OSTI)

    Lee, Ji-Hoon; Kennedy, David W.; Dohnalkova, Alice; Moore, Dean A.; Nachimuthu, Ponnusamy; Reed, Samantha B.; Fredrickson, Jim K.

    2011-12-13T23:59:59.000Z

    The dissimilatory metal-reducing bacterium, Shewanella oneidensis MR-1 produced {gamma}-MnS (rambergite) nanoparticles during the concurrent reduction of MnO{sub 2} and thiosulfate coupled to H{sub 2} oxidation. To investigate effect of direct microbial reduction of MnO{sub 2} on MnS formation, two MR-1 mutants defective in outer membrane c-type cytochromes ({Delta}mtrC/{Delta}omcA and {Delta}mtrC/{Delta}omcA/{Delta}mtrF) were also used and it was determined that direct reduction of MnO{sub 2} was dominant relative to chemical reduction by biogenic sulfide generated from thiosulfate reduction. Although bicarbonate was excluded from the medium, incubations of strain MR-1 with lactate as the electron donor produced MnCO{sub 3} (rhodochrosite) as well as MnS in nearly equivalent amounts as estimated by micro X-ray diffraction (micro-XRD) analysis. It was concluded that carbonate released from lactate metabolism promoted MnCO{sub 3} formation and that Mn(II) mineralogy was strongly affected by carbonate ions even in the presence of abundant sulfide and weakly alkaline conditions expected to favor the precipitation of MnS. Formation of MnS, as determined by a combination of micro-XRD, transmission electron microscopy, energy dispersive X-ray spectroscopy, and selected area electron diffraction analyses was consistent with equilibrium speciation modeling predictions. Biogenic manganese sulfide may be a manganese sink in the Mn biogeochemical cycle in select environments such as deep anoxic marine basins within the Baltic Sea.

  17. Manganese Oxidation In A Natural Marine Environment- San Antonio Bay

    E-Print Network [OSTI]

    Neyin, Rosemary Ogheneochuko

    2013-04-12T23:59:59.000Z

    ................................................................................................................. 24 REFERENCES .................................................................................................................. 25 vii LIST OF FIGURES Page Figure 1 Study Area in ANWR, San Antonio Bay, Texas... by microorganisms, colloidal matter, mineral surfaces, or all three; and (3) is superoxide a significant proximal oxidant? 4 STUDY AREA The area chosen for this study was located in the Aransas National Wildlife Refuge (ANWR) in San Antonio...

  18. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li-air batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang; Yang, Xiao -Qing; Zheng, Doug; McKinnon, Meaghan E.; Qu, Deyang

    2015-01-01T23:59:59.000Z

    Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. The reactions are found to be first order and the rate constants are 0.033 s-1 M-1,more »0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.« less

  19. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li-air batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Qiang [Univ. of Massachusetts at Boston, Boston, MA (United States); Yang, Xiao -Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States); Zheng, Doug [Univ. of Massachusetts at Boston, Boston, MA (United States); McKinnon, Meaghan E. [Univ. of Massachusetts at Boston, Boston, MA (United States); Qu, Deyang [Univ. of Massachusetts at Boston, Boston, MA (United States)

    2015-01-01T23:59:59.000Z

    Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. The reactions are found to be first order and the rate constants are 0.033 s-1 M-1, 0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.

  20. Manganese-oxidizing photosynthesis before the rise of cyanobacteria

    E-Print Network [OSTI]

    Fischer, Woodward

    Manganese-oxidizing photosynthesis before the rise of cyanobacteria Jena E. Johnsona,1 , Samuel M) The emergence of oxygen-producing (oxygenic) photosynthesis fundamentally transformed our planet; however biological innovation-- the evolution of oxygenic photosynthesis (3, 4). Several bio- chemical attributes

  1. MANGANESE--1997 49.1 By Thomas S. Jones

    E-Print Network [OSTI]

    Torgersen, Christian

    production by virtue of its sulfur-fixing, deoxidizing, and alloying properties. Steelmaking dioxide by synthetic dioxide, principally electrolytic manganese dioxide (EMD). For U.S. foreign trade%. The decrease in year-average price was about 4% for silicomanganese and 18% for medium-carbon ferromanganese

  2. Hot coal gas desulfurization with manganese-based sorbents

    SciTech Connect (OSTI)

    Hepworth, M.T.; Ben-Slimane, R.

    1995-11-01T23:59:59.000Z

    The primary major deposit of manganese in the US which can be readily mined by an in situ process is located in the Emily district of Minnesota. The US Bureau of Mines Research Centers at both the Twin Cities and Salt Lake City have developed a process for extracting and refining manganese in the form of a high-purity carbonate product. This product has been formulated into pellets by a multi-step process of drying, calcination, and induration to produce relatively high-strength formulations which are capable of being used for hot fuel gas desulfurization. These pellets, which have been developed at the University of Minnesota under joint sponsorship of the US Department of Energy and the US Bureau of Mines, appear superior to other, more expensive, formulations of zinc titanate and zinc ferrite which have previously been studied for multi-cycle loading (desulfurization) and regeneration (evolution of high-strength SO{sub 2} and restoration of pellet reactivity). Although these other formulations have been under development for the past twelve years, their prices still exceed $7 per pound. If manganese pellets perform as predicted in fixed bed testing, and if a significant number of utilities which burn high-sulfur coals incorporate combined-cycle gasification with hot coal gas desulfurization as a viable means of increasing conversion efficiencies, then the potential market for manganese pellets may be as high as 200,000 tons per year at a price not less than $3 per pound. This paper discusses the role of manganese pellets in the desulfurization process with respect to the integrated gasification combined-cycle (IGCC) for power generation.

  3. (Data in thousand metric tons gross weight unless otherwise specified) Domestic Production and Use: Manganese ore containing 35% or more manganese has not been produced

    E-Print Network [OSTI]

    Torgersen, Christian

    purposes as production of dry cell batteries, in plant fertilizers and animal feed, and as a brick colorant of apparent consumption 100 100 100 100 100 Recycling: Manganese was recycled incidentally as a minor inventory for disposal FY 2009 FY 2009 Manganese ore: Battery grade -- -- 18 -- Chemical grade -- -- 23

  4. Superoxide reductase from Desulfoarculus baarsii: reaction mechanism and role of glutamate 47 and lysine 48 in catalysis

    E-Print Network [OSTI]

    Lombard, M; Touati, D; Fontecave, M; Nivière, V

    2015-01-01T23:59:59.000Z

    Superoxide reductase (SOR) is a small metalloenzyme that catalyzes reduction of O(2)(*)(-) to H(2)O(2) and thus provides an antioxidant mechanism against superoxide radicals. Its active site contains an unusual mononuclear ferrous center, which is very efficient during electron transfer to O(2)(*)(-) [Lombard, M., Fontecave, M., Touati, D., and Nivi{\\`e}re, V. (2000) J. Biol. Chem. 275, 115-121]. The reaction of the enzyme from Desulfoarculus baarsii with superoxide was studied by pulse radiolysis methods. The first step is an extremely fast bimolecular reaction of superoxide reductase with superoxide, with a rate constant of (1.1 +/- 0.3) x 10(9) M(-1) s(-1). A first intermediate is formed which is converted to a second one at a much slower rate constant of 500 +/- 50 s(-1). Decay of the second intermediate occurs with a rate constant of 25 +/- 5 s(-1). These intermediates are suggested to be iron-superoxide and iron-peroxide species. Furthermore, the role of glutamate 47 and lysine 48, which are the closest...

  5. New nanocrystalline manganese oxides as cathode materials for lithium batteries : electron microscopy, electrochemical and X-ray absorption studies

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 New nanocrystalline manganese oxides as cathode materials for lithium batteries : electron: manganese oxide, lithium batteries, nanomaterials Corresponding author: Pierre Strobel, tel. 33 476 887 940 with lithium iodide in aqueous medium at room temperature. Transmission electron microscopy (TEM) showed

  6. Periadolescent oral manganese exposure affects conditioned place preference by cocaine and conditioned place aversion by lithium chloride in rats

    E-Print Network [OSTI]

    Lee, Samuel Ming Hin

    2013-02-22T23:59:59.000Z

    Manganese neurotoxicity compromises basal ganglia functions that could affect the limbic system and drug sensitivity. Male rats were orally exposed to manganese chloride (0, 100, 200 mg/kg/day Mn) for 15 days starting at postnatal day (PND) 28...

  7. MediumAlloy ManganeseRich TransformationInduced Plasticity Steels

    E-Print Network [OSTI]

    Cambridge, University of

    for strong and ductile alloys containing some 6 wt% of manganese, but with aluminium additions in orderMedium­Alloy Manganese­Rich Transformation­Induced Plasticity Steels D. W. Suha , J. H. Ryua , M. S to permit heat treatments which are amenable to rapid production. However, large concentrations of aluminium

  8. GEOC Andrew Stack Thursday, March 20, 2014 152 Kinetics of arsenic oxidation by manganese oxide minerals: The influence of origin and structure on reactivity

    E-Print Network [OSTI]

    Sparks, Donald L.

    minerals: The influence of origin and structure on reactivity Jason S. Fischel1, fischelj@udel.edu, Matthew. Their highly reactive surfaces allow manganese minerals to oxidize trace metals such as arsenic from the mobile of manganese minerals found in natural systems. Five Manganese oxide minerals manganese oxide (HMO), hexagonal

  9. Anti-inflammatory and anti-oxidative effects of corilagin in a rat model of acute cholestasis

    E-Print Network [OSTI]

    2013-01-01T23:59:59.000Z

    MPO), malondialdehyde (MDA), superoxide dismutase (SOD) andintervention, levels of MPO, MDA and translocation of NF-?BMPO), malondialdehyde (MDA), super- oxide dismutase (SOD),

  10. Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li-air batteries

    SciTech Connect (OSTI)

    Wang, Qiang [Univ. of Massachusetts at Boston, Boston, MA (United States); Yang, Xiao -Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States); Zheng, Doug [Univ. of Massachusetts at Boston, Boston, MA (United States); McKinnon, Meaghan E. [Univ. of Massachusetts at Boston, Boston, MA (United States); Qu, Deyang [Univ. of Massachusetts at Boston, Boston, MA (United States)

    2015-01-01T23:59:59.000Z

    Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2-) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2-produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. The reactions are found to be first order and the rate constants are 0.033 s-1 M-1, 0.020 s-1 M-1and 0.67 s-1M-1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.

  11. A study of the chemical forms of manganese in sea water

    E-Print Network [OSTI]

    Buglio, Benjamin

    1961-01-01T23:59:59.000Z

    Sampling Equipment Methods Cleaning Procedure Total Manganese Determination. . . . . . . . . Calculations Separation of Mn+2 from other Forms of Manganese. . Removal of MnOs from Solution 7 7 7 7 7 0 e 9 9 9 9 9 9 13 15 17 CHAPTER II... Results and Discussion Study of Mn+2 in sea water. Study of MnOs in sea water Exchange between Mn+2 and Laboratory Prepared MnOs Exchange between Mn and the MnOs of sea water Study of Organically Bound Manganese in Sea Water . ~ ~ ~ Exchange of Mn...

  12. Manganese Porphyrins Catalyze Selective C-H Bond Halogenations

    SciTech Connect (OSTI)

    Liu, Wei; Groves, John T

    2010-01-01T23:59:59.000Z

    We report a manganese porphyrin mediated aliphatic C?H bond chlorination using sodium hypochlorite as the chlorine source. In the presence of catalytic amounts of phase transfer catalyst and manganese porphyrin Mn(TPP)Cl 1, reaction of sodium hypochlorite with different unactivated alkanes afforded alkyl chlorides as the major products with only trace amounts of oxygenation products. Substrates with strong C?H bonds, such as neopentane (BDE =?100 kcal/mol) can be also chlorinated with moderate yield. Chlorination of a diagnostic substrate, norcarane, afforded rearranged products indicating a long-lived carbon radical intermediate. Moreover, regioselective chlorination was achieved by using a hindered catalyst, Mn(TMP)Cl, 2. Chlorination of trans-decalin with 2 provided 95% selectivity for methylene-chlorinated products as well as a preference for the C2 position. This novel chlorination system was also applied to complex substrates. With 5?-cholestane as the substrate, we observed chlorination only at the C2 and C3 positions in a net 55% yield, corresponding to the least sterically hindered methylene positions in the A-ring. Similarly, chlorination of sclareolide afforded the equatorial C2 chloride in a 42% isolated yield. Regarding the mechanism, reaction of sodium hypochlorite with the Mn{sup III} porphyrin is expected to afford a reactive Mn{sup V}?O complex that abstracts a hydrogen atom from the substrate, resulting in a free alkyl radical and a Mn{sup IV}—OH complex. We suggest that this carbon radical then reacts with a Mn{sup IV}—OCl species, providing the alkyl chloride and regenerating the reactive Mn{sup V}?O complex. The regioselectivity and the preference for CH{sub 2} groups can be attributed to nonbonded interactions between the alkyl groups on the substrates and the aryl groups of the manganese porphyrin. The results are indicative of a bent [Mn{sup v}?O---H---C] geometry due to the C—H approach to the Mn{sup v}?O (d??p?)* frontier orbital.

  13. New Environmentally Friendly Dispersants for High Temperature Invert-Emulsion Drilling Fluids Weighted by Manganese Tetraoxide

    E-Print Network [OSTI]

    Rehman, Abdul

    2012-02-14T23:59:59.000Z

    This thesis provides a detailed evaluation of different environmentally friendly dispersants in invert-emulsion drilling fluids that can be used to drill wells under difficult conditions such as HPHT. The drilling fluid is weighted by manganese...

  14. Process for the electrodeposition of low stress nickel-manganese alloys

    DOE Patents [OSTI]

    Kelly, James John; Goods, Steven Howard; Yang, Nancy Yuan-Chi; Cadden, Charles Henry

    2005-06-07T23:59:59.000Z

    A process for electrodepositing a low stress nickel-manganese multilayer alloy on an electrically conductive substrate is provided. The process includes the steps of immersing the substrate in an electrodeposition solution containing a nickel salt and a manganese salt and repeatedly passing an electric current through an immersed surface of the substrate. The electric current is alternately pulsed for predetermined durations between a first electrical current that is effective to electrodeposit nickel and a second electrical current that is effective to electrodeposit nickel and manganese. A multilayered alloy having adjacent layers of nickel and a nickel-manganese alloy on the immersed surface of the substrate is thereby produced. The resulting multilayered alloy exhibits low internal stress, high strength and ductility, and high strength retention upon exposure to heat.

  15. Influences on the oceanic biogeochemical cycling of the hybrid-type metals, cobalt, iron, and manganese

    E-Print Network [OSTI]

    Noble, Abigail Emery

    2012-01-01T23:59:59.000Z

    Trace metal cycling is one of many processes that influence ocean ecosystem dynamics. Cobalt, iron, and manganese are redox active trace metal micro-nutrients with oceanic distributions that are influenced by both biological ...

  16. Ab initio molecular dynamics study of manganese porphine hydration and interaction with nitric oxide

    E-Print Network [OSTI]

    Kevin Leung; Craig J. Medforth

    2007-01-23T23:59:59.000Z

    The authors use ab initio molecular dynamics and the density functional theory+U (DFT+U) method to compute the hydration environment of the manganese ion in manganese (II) and manganese (III) porphines (MnP) dispersed in liquid water. These are intended as simple models for more complex water soluble porphyrins, which have important physiological and electrochemical applications. The manganese ion in Mn(II)P exhibits significant out-of-porphine plane displacement and binds strongly to a single H2O molecule in liquid water. The Mn in Mn(III)P is on average coplanar with the porphine plane and forms a stable complex with two H2O molecules. The residence times of these water molecules exceed 15 ps. The DFT+U method correctly predicts that water displaces NO from Mn(III)P-NO, but yields an ambiguous spin state for the MnP(II)-NO complex.

  17. Commercialization of cryptomelane-type manganese oxide (OMS-2) nanowire paper oil sorbent

    E-Print Network [OSTI]

    Soo, Haw Yun

    2007-01-01T23:59:59.000Z

    Cryptomelane-type Manganese oxide (OMS-2, a group of Octahedral Molecular Sieves) nanowire paper exhibits interesting properties: reversible wettability, oleophilic while being hydrophobic, and high thermal stability. These ...

  18. Molecular Interactions of Plutonium(VI) with Synthetic Manganese-Substituted Goethite

    E-Print Network [OSTI]

    Hu, Yung-Jin

    2011-01-01T23:59:59.000Z

    Mn-Substituted Goethite Synthesis Manganese substituted (Mn-The laboratory synthesis of Mn-substituted goethite requiresgoethite existed as Mn(III), even though Mn was added during mineral synthesis

  19. MANGANESE ABUNDANCES IN THE GLOBULAR CLUSTER {omega} CENTAURI

    SciTech Connect (OSTI)

    Cunha, Katia; Smith, Verne V. [National Optical Astronomy Observatory, 950 N. Cherry Avenue, Tucson, AZ, 85719 (United States); Bergemann, Maria [Max-Planck Institute for Astrophysics, Karl-Schwarzschild Str. 1, 85741 Garching (Germany); Suntzeff, Nicholas B. [Department of Physics and Astronomy and Mitchell Institute for Fundamental Physics and Astronomy, Texas A and M University, College Station, TX 77843-4242 (United States); Lambert, David L. [University of Texas, 1 University Station, C1400, Austin, TX 78712 (United States)

    2010-07-01T23:59:59.000Z

    We present manganese abundances in 10 red giant members of the globular cluster {omega} Centauri; eight stars are from the most metal-poor population (RGB MP and RGB MInt1) while two targets are members of the more metal-rich groups (RGB MInt2 and MInt3). This is the first time Mn abundances have been studied in this peculiar stellar system. The LTE values of [Mn/Fe] in {omega} Cen overlap those of Milky Way stars in the metal-poor {omega} Cen populations ([Fe/H] {approx}-1.5 to -1.8), however unlike what is observed in Milky Way halo and disk stars, [Mn/Fe] declines in the two more metal-rich RGB MInt2 and MInt3 targets. Non-LTE calculations were carried out in order to derive corrections to the LTE Mn abundances. The non-LTE results for {omega} Cen in comparison with the non-LTE [Mn/Fe] versus [Fe/H] trend obtained for the Milky Way confirm and strengthen the conclusion that the manganese behavior in {omega} Cen is distinct. These results suggest that low-metallicity supernovae (with metallicities {<=} -2) of either Type II or Type Ia dominated the enrichment of the more metal-rich stars in {omega} Cen. The dominance of low-metallicity stars in the chemical evolution of {omega} Cen has been noted previously in the s-process elements where enrichment from metal-poor asymptotic giant branch stars is indicated. In addition, copper, which also has metallicity-dependent yields, exhibits lower values of [Cu/Fe] in the RGB MInt2 and MInt3 {omega} Cen populations.

  20. (Data in thousand metric tons, gross weight, unless otherwise specified) Domestic Production and Use: Manganese ore containing 35% or more manganese was not produced domestically

    E-Print Network [OSTI]

    Torgersen, Christian

    of ore were used for such nonmetallurgical purposes as production of dry cell batteries, as an ingredient Recycling: Scrap recovery specifically for manganese was negligible, but a significant amount was recycled inventory inventory for disposal FY 2001 FY 2001 Battery: Natural ore 103 0.2 103 27 1 Synthetic dioxide 3

  1. (Data in thousand metric tons, gross weight, unless noted) Domestic Production and Use: Manganese ore containing 35% or more manganese was not produced domestically

    E-Print Network [OSTI]

    Torgersen, Christian

    purposes as producing dry cell batteries, as an ingredient in plant fertilizers and animal feed Recycling: Scrap recovery specifically for manganese was negligible, but a significant amount was recycled of nonstockpile- grade materials, as follows: 16,400 tons of natural battery ore, 81 tons of chemical ore, and 392

  2. (Data in thousand metric tons, gross weight, unless otherwise specified) Domestic Production and Use: Manganese ore containing 35% or more manganese was not produced domestically

    E-Print Network [OSTI]

    Torgersen, Christian

    for such nonmetallurgical purposes as producing dry cell batteries, as an ingredient in plant fertilizers and animal feed Recycling: Scrap recovery specifically for manganese was negligible, but a significant amount was recycled inventories of nonstockpile-grade materials, as follows, in tons: natural battery ore, 16,800; chemical ore

  3. (Data in thousand metric tons, gross weight, unless otherwise specified) Domestic Production and Use: Manganese ore containing 35% or more manganese was not produced domestically

    E-Print Network [OSTI]

    Torgersen, Christian

    of ore were used for such nonmetallurgical purposes as production of dry cell batteries, as an ingredient Recycling: Scrap recovery specifically for manganese was negligible, but a significant amount was recycled, as follows, in tons: natural battery, 16,800, and metallurgical, 331,000. Prepared by Thomas S. Jones [(703

  4. (Data in thousand metric tons, gross weight, unless otherwise specified) Domestic Production and Use: Manganese ore containing 35% or more manganese was not produced domestically

    E-Print Network [OSTI]

    Torgersen, Christian

    for such nonmetallurgical purposes as producing dry cell batteries, as an ingredient in plant fertilizers and animal feed Recycling: Scrap recovery specifically for manganese was negligible, but a significant amount was recycled of nonstockpile-grade materials, as follows: 16,400 tons of natural battery ore, 81 tons of chemical ore, and 392

  5. By Thomas S. Jones Manganese (Mn) is essential to iron and silicomanganese increased about 7%. consisted of, in tons, natural battery-grade ore,

    E-Print Network [OSTI]

    Torgersen, Christian

    . years of apparent consumption. 25. At yearend, the estimated manganese Ironmaking and steelmaking have to reported data, the rates of consumption of manganese as ore in ironmaking and as ferroalloys and metal

  6. Iron and manganese are two similar ele-ments that can be a nuisance in a drinking

    E-Print Network [OSTI]

    with miner- al deposits. This raises energy and water costs. Water contaminated with iron and manganese often contains iron or manganese bacteria. These bacteria feed on the minerals in the water. They do not cause elements in the earth's crust. As water percolates through soil and rock it can dissolve these minerals

  7. Abstract Dormant spores of the marine Bacillus sp. strain SG-1 catalyze the oxidation of manganese(II),

    E-Print Network [OSTI]

    Tebo, Brad

    , MnxG was overexpressed in Escherichia coli and used to generate polyclonal antibodies. Western blotAbstract Dormant spores of the marine Bacillus sp. strain SG-1 catalyze the oxidation of manganese Introduction Mature spores of the marine Bacillus sp. strain SG-1 oxi- dize soluble manganese [Mn(II)], thereby

  8. Element-and site-specific oxidation state and cation distribution in manganese ferrite films by diffraction anomalous fine structure

    E-Print Network [OSTI]

    Haskel, Daniel

    Element- and site-specific oxidation state and cation distribution in manganese ferrite films Received 2 April 2008; accepted 9 July 2008; published online 8 August 2008 Epitaxial manganese ferrite.1063/1.2969406 Spinel ferrites represent an important class of materials that provide high permeability, moderate

  9. Passive removal of manganese from acid mine drainage

    SciTech Connect (OSTI)

    Brant, D.L.; Ziemkiewicz, P.F. [West Virginia Univ., Morgantown, WV (United States)

    1997-12-31T23:59:59.000Z

    Removal of manganese (Mn) from mine drainage is difficult due to the abnormal chemistry of the element. The removal requires the oxidation of Mn(II) (the form found in mine drainage) to the more oxidized forms (Mn(III) or Mn(IV)). The more oxidized forms exist only as solids and will not return to Mn(II) spontaneously. Chemical treatment of Mn often requires a pH near 10 to initiate the oxidation quickly. A stabilized pH of 10 normally causes more harm to aquatic organisms than the Mn and is not desirable, making additional steps in the treatment necessary. Biological removal of Mn can be achieved at near neutral pH levels. The Shade Mining site in Somerset County, PA has been treating Mn to discharge limits since the early 1990`s (reducing Mn concentrations from 12 - 25 mg/L in the influent to <2 mg/L in the effluent). The treatment system consists of an anoxic limestone drain discharging into a wetland to remove iron, aluminum, and acidity, while increasing pH and alkalinity. The wetland effluent flows into two limestone beds (Mn removal). The limestone beds developed a black slime coating as the Mn removal increased. This system continues to remove Mn in all weather conditions and has not required chemical treatment since the black coating appeared on the limestone. A laboratory study was conducted using limestone collected from the Shade site to use the same naturally occurring Mn oxidizing microbes. The lab study compared W removal rates of microbial oxidation, MnO{sub 2} catalyzed limestone, and fresh uncoated limestone. The microbial removal performed the best (25 mg/L Mn reduced to <2 mg/L in 72 hours).

  10. Hyperthermia HeLa cell treatment with silica coated manganese oxide nanoparticles

    E-Print Network [OSTI]

    Villanueva, A; Alonso, JM; Rueda, T; Martínez, A; Crespo, P; Morales, MP; Fernandez, MA Gonzalez; Valdes, J; Rivero, G

    2009-01-01T23:59:59.000Z

    HeLa tumour cells incubated with ferromagnetic nanoparticles of manganese oxide perovskite La0.56(SrCa)0.22MnO3 were treated with a high frequency alternating magnetic field. The particles were previously coated with silica to improve their biocompatibility. The control assays made with HeLa tumour cells showed that cell survival and growth rate were not affected by the particle internalization in cells, or by the electromagnetic field on cells without nanoparticles. The application of an alternating electromagnetic field to cells incubated with this silica coated manganese oxide induced a significant cellular damage that finally lead to cell death by an apoptotic mechanism.

  11. The connection between the damping capacity and the crystal structure of some copper-manganese alloys

    E-Print Network [OSTI]

    McCrary, Leon Eldon

    1960-01-01T23:59:59.000Z

    THE CONNECTION BETHEEN THE DANPIING CAPACIITY AND THE CRYSTAL STRUCTURE OF SOME COPPER-MANGANESE ALLOYS A Thesis By Leon Eldon McCrary Submitted to the Graduate School of the Agricultural and Mechanlcai College of Texas ln partial fulfil... lment of the requirements for the degree of MASTER OF SCIIENCE August 'l960 Major Sub)ect: Physics THE CONNECTION BETWEEN THE DAMPING CAPACITY AND THE CRYSTAL STRUCTURE OF SOME COPPER-MANGANESE ALLOYS A Thesis By Leon E I don McC ra ry Approved...

  12. LOW TEMPERATURE VOC COMBUSTION OVER MANGANESE, COBALT AND ZINC ALPO4 MOLECULAR SIEVES

    SciTech Connect (OSTI)

    Rosemarie Szostak

    2003-03-06T23:59:59.000Z

    The objective of this project was to prepare microporous aluminophosphates containing magnesium, manganese, cobalt and zinc (MeAPOs) and to evaluate their performance as oxidation catalysts for the removal of low levels of volatile organic compounds (VOCs) from gas streams. The tasks to be accomplished were as follows: (1) To develop reliable synthesis methods for metal aluminophosphates containing manganese, cobalt and zinc in their framework; (2) To characterize these materials for crystallinity, phase purity, the location and nature of the incorporated metal in the framework; and (3) To evaluate the materials for their catalytic activities in the oxidation of volatile organic environmental pollutants.

  13. Synthesis gas conversion in a mixed slurry reactor with iron-manganese catalysts

    SciTech Connect (OSTI)

    Pennline, H.W.; Schehl, R.R.; Tischer, R.E.; Zarochak, M.F.

    1984-08-01T23:59:59.000Z

    Synthesis gas was reacted over different compositions of iron-manganese Fischer-Tropsch catalysts in a slurry reactor. The reactor operates in a back-mixed mode with a continuous flow of feed gas through the catalyst suspended in the liquid medium. Four catalysts with iron-manganese ratios of 57/43, 44/56, 22/78, and 10/90 were investigated at identical process conditions after a standard activation procedure. With time on stream for each catalyst system, hydrogenation of olefins occurred, along with olefin isomerization reactions. Activity, selectivity, and stability are discussed in general. Analyses of used catalyst samples are also reported.

  14. Hot Coal Gas Desulfurization With Manganese-Based Sorbents

    SciTech Connect (OSTI)

    Berns, J.J.; Hepworth, M.T. [Dept. of Civil Engineering, Univ. of Minnesota, Minneapolis, MN (United States)

    1996-12-31T23:59:59.000Z

    The objective of this project is to develop a pellet formulation which is capable of achieving low sulfur partial pressures and a high capacity for sulfur, loaded from a hot fuel gas and which is readily regenerable. Furthermore the pellet must be strong for potential use in a fluidized and regenerable over many cycles of loading and regeneration. Regeneration should be in air or oxygen-depleted air to produce a high-concentration sulfur dioxide. Fixed-bed tests were conducted with several formulations of manganese sesquioxide and titania, and alumina. They were subject to a simplified fuel gas of the oxygen-blown Shell type spiked with a 30,000 ppmv concentration of H{sub 2}S. Pellet crush strengths for 4 and 2 mm diameter pellets was typically 12 lbs per pellet and 4 lbs per pellet, respectively. For the most favorable of the formulations tested and under the criteria of break-through at less than 100 ppmv H{sub 2}S and loading temperatures of 5000 {degrees}C and an empty-bed space velocity of 4, 000 per hour, breakthrough occurred an effective loading of sulfur of 27 to 29% over 5 loading and regeneration cycles. At 90% of this saturation condition, the observed level of H{sub 2}S was below 10 ppmv. For regeneration, a temperature of 9000 {degrees}C is required to dissociate the sulfide into sulfur dioxide using air at atmospheric pressure. The mean sulfur dioxide concentration which is achieved during regeneration is 8% with empty-bed space velocities of 700/hr. TGA tests on individual pellets indicate that bentonite is not desirable as a bonding material and that Mn/Ti ratios higher than 7:1 produce relatively non-porous pellets. Whereas the reactivity is rapid below 12% conversion, the kinetics of conversion decreased significantly above this level. This observation may be the result of plugging of the pellet pores with sulfided product creating inaccessible pore volumes or alternately an increase in diffusional resistance by formation of MnS.

  15. MANGANESE DEFICIENCIES IN INDIANA SOILS Sylvie M. Brouder, Purdue Soil Fertility Specialist

    E-Print Network [OSTI]

    Brouder, Sylvie

    MANGANESE DEFICIENCIES IN INDIANA SOILS Sylvie M. Brouder, Purdue Soil Fertility Specialist Andrea S. Bongen and barley. #12;4 AY-276-W Table 2. M anganese fertilizers and suggestions for their use in banded/row starter application (B nd) and foliar application (Fol). B roadcast applications are not recom m ended

  16. The effect of paramagnetic manganese cations on 1 H MR spectroscopy of the brain

    E-Print Network [OSTI]

    The effect of paramagnetic manganese cations on 1 H MR spectroscopy of the brain K. S. Madsen1 has investigated the effect of Mn on 1 H MR spectroscopy using an in vivo Mn-enhanced optic tract into a stereotactic device. Images and 1 H MR spectra were acquired using a Varian 4.7T animal scanner together

  17. Effect of intranasal manganese administration on neurotransmission and spatial learning in rats

    SciTech Connect (OSTI)

    Blecharz-Klin, Kamilla; Piechal, Agnieszka; Joniec-Maciejak, Ilona; Pyrzanowska, Justyna; Widy-Tyszkiewicz, Ewa, E-mail: etyszkiewicz@wum.edu.pl

    2012-11-15T23:59:59.000Z

    The effect of intranasal manganese chloride (MnCl{sub 2}·4H{sub 2}O) exposure on spatial learning, memory and motor activity was estimated in Morris water maze task in adult rats. Three-month-old male Wistar rats received for 2 weeks MnCl{sub 2}·4H{sub 2}O at two doses the following: 0.2 mg/kg b.w. (Mn0.2) or 0.8 mg/kg b.w. (Mn0.8) per day. Control (Con) and manganese-exposed groups were observed for behavioral performance and learning in water maze. ANOVA for repeated measurements did not show any significant differences in acquisition in the water maze between the groups. However, the results of the probe trial on day 5, exhibited spatial memory deficits following manganese treatment. After completion of the behavioral experiment, the regional brain concentrations of neurotransmitters and their metabolites were determined via HPLC in selected brain regions, i.e. prefrontal cortex, hippocampus and striatum. ANOVA demonstrated significant differences in the content of monoamines and metabolites between the treatment groups compared to the controls. Negative correlations between platform crossings on the previous platform position in Southeast (SE) quadrant during the probe trial and neurotransmitter turnover suggest that impairment of spatial memory and cognitive performance after manganese (Mn) treatment is associated with modulation of the serotonergic, noradrenergic and dopaminergic neurotransmission in the brain. These findings show that intranasally applied Mn can impair spatial memory with significant changes in the tissue level and metabolism of monoamines in several brain regions. -- Highlights: ? Intranasal exposure to manganese in rats impairs spatial memory in the water maze. ? Regional changes in levels of neurotransmitters in the brain have been identified. ? Cognitive disorder correlates with modulation of 5-HT, NA and DA neurotransmission.

  18. Transcriptome Analysis of Manganese-deficient Chlamydomonas reinhardtii Provides Insight on the Chlorophyll Biosynthesis Pathway

    SciTech Connect (OSTI)

    Lockhart, Ainsley; Zvenigorodsky, Natasha; Pedraza, Mary Ann; Lindquist, Erika

    2011-08-11T23:59:59.000Z

    The biosynthesis of chlorophyll and other tetrapyrroles is a vital but poorly understood process. Recent genomic advances with the unicellular green algae Chlamydomonas reinhardtii have created opportunity to more closely examine the mechanisms of the chlorophyll biosynthesis pathway via transcriptome analysis. Manganese is a nutrient of interest for complex reactions because of its multiple stable oxidation states and role in molecular oxygen coordination. C. reinhardtii was cultured in Manganese-deplete Tris-acetate-phosphate (TAP) media for 24 hours and used to create cDNA libraries for sequencing using Illumina TruSeq technology. Transcriptome analysis provided intriguing insight on possible regulatory mechanisms in the pathway. Evidence supports similarities of GTR (Glutamyl-tRNA synthase) to its Chlorella vulgaris homolog in terms of Mn requirements. Data was also suggestive of Mn-related compensatory up-regulation for pathway proteins CHLH1 (Manganese Chelatase), GUN4 (Magnesium chelatase activating protein), and POR1 (Light-dependent protochlorophyllide reductase). Intriguingly, data suggests possible reciprocal expression of oxygen dependent CPX1 (coproporphyrinogen III oxidase) and oxygen independent CPX2. Further analysis using RT-PCR could provide compelling evidence for several novel regulatory mechanisms in the chlorophyll biosynthesis pathway.

  19. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, M.M.; Peng, M.Y.; Ma, Y.; Visco, S.J.; DeJonghe, L.C.

    1996-09-24T23:59:59.000Z

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M{sub x}Z{sub y}Mn{sub (1{minus}y)}O{sub 2}, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell. 11 figs.

  20. Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

    DOE Patents [OSTI]

    Doeff, Marca M. (Hayward, CA); Peng, Marcus Y. (Cupertino, CA); Ma, Yanping (Albany, CA); Visco, Steven J. (Berkeley, CA); DeJonghe, Lutgard C. (Lafayette, CA)

    1996-01-01T23:59:59.000Z

    An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M.sub.x Z.sub.y Mn.sub.(1-y) O.sub.2, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell.

  1. Hot coal gas desulfurization with manganese-based sorbents. Final report, September 1992--December 1994

    SciTech Connect (OSTI)

    Hepworth, M.T.; Slimane, R.B.

    1994-11-01T23:59:59.000Z

    The focus of much current work being performed by the Morgantown Energy Technology Center (METC) of the Department of Energy on hot coal-derived fuel gas desulfurization is in the use of zinc-based sorbents. METC has shown interest in formulating and testing manganese-based pellets as alternative effective sulfur sorbents in the 700 to 1200{degree}C temperature range. To substantiate the potential superiority of Mn-based pellets, a systematic approach toward the evaluation of the desulfurizing power of single-metal sorbents is developed based on thermodynamic considerations. This novel procedure considered several metal-based sorbents and singled out manganese oxide as a prime candidate sorbent capable of being utilized under a wide temperature range, irrespective of the reducing power (determined by CO{sub 2}/CO ratio) of the fuel gas. Then, the thermodynamic feasibility of using Mn-based pellets for the removal of H{sub 2}S from hot-coal derived fuel gases, and the subsequent oxidative regeneration of loaded (sulfided) pellets was established. It was concluded that MnO is the stable form of manganese for virtually all commercially available coal-derived fuel gases. In addition, the objective of reducing the H{sub 2}S concentration below 150 ppMv to satisfy the integrated gasification combined cycle system requirement was shown to be thermodynamically feasible. A novel process is developed for the manufacture of Mn-based spherical pellets which have the desired physical and chemical characteristics required.

  2. Formation of manganese -doped atomic layer in wurtzite GaN Meng Shi, Abhijit Chinchore, Kangkang Wang, Andrada-Oana Mandru, Yinghao Liu et al.

    E-Print Network [OSTI]

    Formation of manganese -doped atomic layer in wurtzite GaN Meng Shi, Abhijit Chinchore, Kangkang in wurtzite GaN Meng Shi, Abhijit Chinchore, Kangkang Wang, Andrada-Oana Mandru, Yinghao Liu, and Arthur R 2012) We describe the formation of a d-doped manganese layer embedded within c-plane wurtzite gallium

  3. Magnetism in bcc and fcc Fe with carbon and manganese This article has been downloaded from IOPscience. Please scroll down to see the full text article.

    E-Print Network [OSTI]

    Medvedeva, Julia E.

    Magnetism in bcc and fcc Fe with carbon and manganese This article has been downloaded from.1088/0953-8984/22/31/316002 Magnetism in bcc and fcc Fe with carbon and manganese N I Medvedeva1,2 , D Van Aken2 and J E Medvedeva3 1 functional theory calculations were performed to study the structure and magnetic properties of bcc

  4. Thermal treatment for recovery of manganese and zinc from zinc-carbon and alkaline spent batteries

    SciTech Connect (OSTI)

    Belardi, G. [Institute for Environmental Engineering and Geosciences (CNR) Area della Ricerca CNR, via Salaria km 29,300, Monterotondo, 00016 Rome (Italy); Lavecchia, R.; Medici, F. [Department of Chemical Engineering, Materials and Environment, Sapienza University of Rome, via Eudossiana 84, 00184 Rome (Italy); Piga, L., E-mail: luigi.piga@uniroma1.it [Department of Chemical Engineering, Materials and Environment, Sapienza University of Rome, via Eudossiana 84, 00184 Rome (Italy)

    2012-10-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer We separated Zn from Mn in zinc-carbon and alkaline batteries after removal of Hg. Black-Right-Pointing-Pointer Almost total removal of Hg is achieved at low temperature in air. Black-Right-Pointing-Pointer Nitrogen atmosphere is needed to reduce zinc and to permit its volatilization. Black-Right-Pointing-Pointer A high grade Zn concentrate was obtained with a high recovery at 1000-1200 Degree-Sign C. Black-Right-Pointing-Pointer The grade of Mn in the residue was enhanced with complete recovery. - Abstract: The aim of this paper is the recovery of manganese and zinc from a mixture of zinc-carbon and alkaline spent batteries, containing 40.9% of Mn and 30.1% of Zn, after preliminary physical treatment followed by removal of mercury. Separation of the metals has been carried out on the basis of their different boiling points, being 357 Degree-Sign C and 906 Degree-Sign C the boiling point of mercury and zinc and 1564 Degree-Sign C the melting point of Mn{sub 2}O{sub 3}. Characterization by chemical analysis, TGA/DTA and X-ray powder diffraction of the mixture has been carried out after comminution sieving and shaking table treatment to remove the anodic collectors and most of chlorides contained in the mixture. The mixture has been roasted at various temperatures and resident times in a flow of air to set the best conditions to remove mercury that were 400 Degree-Sign C and 10 min. After that, the flow of air has been turned into a nitrogen one (inert atmosphere) and the temperatures raised, thus permitting the zinc oxide to be reduced to metallic zinc by the carbon present in the original mixture and recovered after volatilization as a high grade concentrate, while manganese was left in the residue. The recovery and the grade of the two metals, at 1000 Degree-Sign C and 30 min residence time, were 84% and 100% for zinc and 85% and 63% for manganese, respectively. The recovery of zinc increased to 99% with a grade of 97% at 1200 Degree-Sign C and 30 min residence time, while the recovery and grade of manganese were 86% and 87%, respectively, at that temperature. Moreover, the chlorinated compounds that could form by the combustion of the plastics contained in the spent batteries, are destroyed at the temperature required by the process.

  5. Synthesis and Characterization of Rare-earth-free Magnetic Manganese Bismuth Nanocrystals

    SciTech Connect (OSTI)

    Shen, Jian Q.; Cui, Huizhong; Huang, Xiaopeng; Gong, Maogang; Qin, Wei; Kirkeminde, Alec; Cui, Jun; Ren, Shenqiang

    2015-01-01T23:59:59.000Z

    Earth abundant manganese bismuth (MnBi) has long been of interest due to its large magnetocrystalline anisotropy and high energy density for advanced permanent magnet applications. However, solution synthesis of MnBi phase is challenging due to the reduction potential mismatch between Mn and Bi elements. In this study, we show a versatile MnBi synthesis method involving the metal co-reduction followed by thermal annealing. The magnetically hard MnBi crystalline phase is then exchange coupled with magnetically soft cobalt coating. Our processing approach offers a promising strategy for manufacturing rare-earth-free magnetic nanocrystals.

  6. Influence of film thickness and air exposure on the transport gap of manganese phthalocyanine

    SciTech Connect (OSTI)

    Haidu, F.; Fechner, A.; Salvan, G.; Gordan, O. D.; Fronk, M.; Zahn, D. R. T. [Semiconductor Physics, Chemnitz University of Technology, D-09107 Chemnitz (Germany); Lehmann, D. [Semiconductor Physics, Chemnitz University of Technology, D-09107 Chemnitz (Germany); INNOVENT Technology Development, D-07745 Jena (Germany); Mahns, B.; Knupfer, M. [Electronic and Optical Properties Department, IFW Dresden, D-01171 Dresden (Germany)

    2013-06-15T23:59:59.000Z

    The interface formation between manganese phthalocyanine (MnPc) and cobalt was investigated combining ultraviolet photoelectron spectroscopy and inverse photoelectron spectroscopy. The transport band gap of the MnPc increases with the film thickness up to a value of (1.2 {+-} 0.3) eV while the optical band gap as determined from spectroscopic ellipsometry amounts to 0.5 eV. The gap values are smaller compared to other phthalocyanines due to metallic Mn 3d states close to the Fermi level. The transport band gap was found to open upon air exposure as a result of the disappearance of the occupied 3d electronic states.

  7. Manganese-Aluminum-Based Magnets: Nanocrystalline t-MnAI Permanent Magnets

    SciTech Connect (OSTI)

    None

    2012-01-01T23:59:59.000Z

    REACT Project: Dartmouth is developing specialized alloys with magnetic properties superior to the rare earths used in today’s best magnets. EVs and renewable power generators typically use rare earths to turn the axles in their electric motors due to the magnetic strength of these minerals. However, rare earths are difficult and expensive to refine. Dartmouth will swap rare earths for a manganese-aluminum alloy that could demonstrate better performance and cost significantly less. The ultimate goal of this project is to develop an easily scalable process that enables the widespread use of low-cost and abundant materials for the magnets used in EVs and renewable power generators.

  8. Effects of solar radiation on manganese oxide reactions with selected organic compounds

    SciTech Connect (OSTI)

    Bertino, D.J.; Zepp, R.G. (Environmental Protection Agency, Athens, GA (United States))

    1991-07-01T23:59:59.000Z

    The effects of sunlight on aqueous redox reactions between manganese oxides (MnO{sub x}) and selected organic substances are reported. No sunlight-induced rate enhancement was observed for the MnO{sub x} oxidation of substituted phenols, anisole, o-dichlorobenzene, or p-chloroaniline. On the other hand, solar radiation did accelerate the reduction of manganese oxides by dissolved organic matter (DOM) from aquatic environments. The photoreduction of MnO{sub x} by DOM was little affected by molecular oxygen in air-saturated water (250 {mu}M), but was inhibited by 2,6-dichloroindophenol (0.5-6 {mu}M), and excellent electron acceptor. MnO{sub x} reduction also was photosensitized by anthraquinone-2-sulfonate. These results indicate that the photoreduction probably involves electron transfer from excited states of sorbed DOM to the oxide surface. Wavelength studies indicated that ultraviolet-B radiation (280-320 nm) plays an important role in this photoreduction.

  9. Forms and pedogenic distribution of extractable manganese in some soils of south-western Nigeria

    SciTech Connect (OSTI)

    Ayanlaja, S.A.

    1984-01-01T23:59:59.000Z

    The contents of various forms of manganese in 10 profiles from S.W. Nigeria was determined by selective extraction methods: dithionite (total), oxalate (amorphous), hydroquinone (easily reducible) and pyrophosphate (organic). All forms were generally highest in the surface horizon and decreased down the profile. Amorphous Mn is the dominant form, being between 80-100% of the total Mn. This indicates that a high proportion of the total soil Mn is potentially available to plant. The active Mn ratio remains fairly constant through most of the profiles suggesting that a dynamic equilibrium exists between the crystalline and the amorphous forms. X-ray diffraction analysis of the manganese concretions picked out from the soils revealed birnessite as the prevalent crystalline form, and the formula derived for birnessite by chemical and thermogravimetric analyses is: (Mn/sub 6.37/, Co/sub 0.16/, Na/sub 1.52/, Ni/sub 0.03/, Ca/sub 0.02/, K/sub 0.06/, Cu/sub 0.01/, Mg/ sub 0.07/) O/sub 14/.4H/sub 2/O.

  10. Mesoporous titanium-manganese dioxide for sulphur mustard and soman decontamination

    SciTech Connect (OSTI)

    Stengl, Vaclav, E-mail: stengl@iic.cas.cz [Department of Solid State Chemistry, Institute of Inorganic Chemistry AS CR v.v.i., 250 68 Rez (Czech Republic)] [Department of Solid State Chemistry, Institute of Inorganic Chemistry AS CR v.v.i., 250 68 Rez (Czech Republic); Bludska, Jana [Department of Solid State Chemistry, Institute of Inorganic Chemistry AS CR v.v.i., 250 68 Rez (Czech Republic)] [Department of Solid State Chemistry, Institute of Inorganic Chemistry AS CR v.v.i., 250 68 Rez (Czech Republic); Oplustil, Frantisek; Nemec, Tomas [Military Technical Institute of Protection Brno, Veslarska 230, 628 00 Brno (Czech Republic)] [Military Technical Institute of Protection Brno, Veslarska 230, 628 00 Brno (Czech Republic)

    2011-11-15T23:59:59.000Z

    Highlights: {yields} New nano-dispersive materials for warfare agents decontamination. {yields} 95% decontamination activities for sulphur mustard. {yields} New materials base on titanium and manganese oxides. -- Abstract: Titanium(IV)-manganese(IV) nano-dispersed oxides were prepared by a homogeneous hydrolysis of potassium permanganate and titanium(IV) oxo-sulphate with 2-chloroacetamide. Synthesised samples were characterised using Brunauer-Emmett-Teller (BET) surface area and Barrett-Joiner-Halenda porosity (BJH), X-ray diffraction (XRD), infrared spectroscopy (IR), and scanning electron microscopy (SEM). These oxides were taken for an experimental evaluation of their reactivity with sulphur mustard (HD or bis(2-chloroethyl)sulphide) and soman (GD or (3,3'-dimethylbutan-2-yl)-methylphosphonofluoridate). Mn{sup 4+} content affects the decontamination activity; with increasing Mn{sup 4+} content the activity increases for sulphur mustard and decreases for soman. The best decontamination activities for sulphur mustard and soman were observed for samples TiMn{sub 3}7 with 18.6 wt.% Mn and TiMn{sub 5} with 2.1 wt.% Mn, respectively.

  11. Composition and Flow Behavior of F-Canyon Tank 804 Sludge following Manganese Addition and pH Adjustment

    SciTech Connect (OSTI)

    Poirier, M. R.; Stallings, M. E.; Burket, P.R.; Fink, S. D.

    2005-11-30T23:59:59.000Z

    The Site Deactivation and Decommissioning (SDD) Organization is evaluating options to disposition the 800 underground tanks (including removal of the sludge heels from these tanks). To support this effort, SDD requested assistance from Savannah River National Laboratory (SRNL) personnel to examine the composition and flow characteristics of the Tank 804 sludge slurry after diluting it 10:1 with water, adding manganese nitrate to produce a slurry containing 5.5 wt % manganese (40:1 ratio of Mn:Pu), and adding sufficient 8 M caustic to raise the pH to 7, 10, and 14. Researchers prepared slurries containing one part Tank 804 sludge and 10 parts water. The water contained 5.5 wt % manganese (which SDD will add to poison the plutonium in Tank 804) and was pH adjusted to 3, 7, 10, or 14. They hand mixed (i.e., shook) these slurries and allowed them to sit overnight. With the pH 3, 7, and 10 slurries, much of the sludge remained stuck to the container wall. With the pH 14 slurry, most of the sludge appeared to be suspended in the slurry. They collected samples from the top and bottom of each container, which were analyzed for plutonium, manganese, and organic constituents. Following sampling, they placed the remaining material into a viscometer and measured the relationship between applied shear stress and shear rate. The pH 14 slurry was placed in a spiral ''race track'' apparatus and allowed to gravity drain.

  12. ENVR Dionysios Dionysiou Wednesday, August 22, 2012 261 -Arsenic mobilization in the critical zone: Oxidation by manganese oxide minerals

    E-Print Network [OSTI]

    Sparks, Donald L.

    : Oxidation by manganese oxide minerals Jason S. Fischel1, fischelj@udel.edu, Matthew H. Fischel1, Brandon J, biogenic and abiotic. Five Mn oxide minerals were reacted under identical conditions with equal reactivity, due to passivation. Understanding the reactivity of naturally occurring Mn oxide minerals

  13. Defining manganese(II) removal processes in passive coal mine drainage treatment systems through laboratory incubation experiments

    E-Print Network [OSTI]

    Burgos, William

    - trations. At operating coal mines, the most commonly used ``active treatment'' method to remove MnDefining manganese(II) removal processes in passive coal mine drainage treatment systems through for the passive removal of Mn(II) from coal mine drainage (CMD). Aqueous Mn(II) is removed via oxidative

  14. Electronic transport in Lithium Nickel Manganese Oxide, a high-voltage cathode material for Lithium-Ion batteries

    E-Print Network [OSTI]

    Ransil, Alan Patrick Adams

    2013-01-01T23:59:59.000Z

    Potential routes by which the energy densities of lithium-ion batteries may be improved abound. However, the introduction of Lithium Nickel Manganese Oxide (LixNi1i/2Mn3/2O4, or LNMO) as a positive electrode material appears ...

  15. Selective adsorption of manganese onto cobalt for optimized Mn/Co/TiO2 FischerTropsch catalysts

    E-Print Network [OSTI]

    Regalbuto, John R.

    Selective adsorption of manganese onto cobalt for optimized Mn/Co/TiO2 Fischer­Tropsch catalysts promotion Fischer­Tropsch Strong Electrostatic Adsorption a b s t r a c t The Strong Electrostatic Adsorption (SEA) method was applied to the rational design of a promoted Co catalyst for Fischer­Tropsch (FT

  16. Integrative Study of Physiological Changes Associated with Bacterial Infection in Pacific Oyster Larvae

    E-Print Network [OSTI]

    Boyer, Edmond

    of antioxidant defenses (catalase, superoxide dismutase, peroxiredoxin) and cytoprotective processes (heat shock and antimicrobial peptides). Conclusion: Overall, our results allowed us to propose an integrative view of changes

  17. Structure analysis of aluminium silicon manganese nitride precipitates formed in grain-oriented electrical steels

    SciTech Connect (OSTI)

    Bernier, Nicolas, E-mail: n.bernier@yahoo.fr [OCAS N.V., ArcelorMittal Global R and D Gent, Pres. J.F. Kennedylaan 3, 9060 Zelzate (Belgium); Xhoffer, Chris [OCAS N.V., ArcelorMittal Global R and D Gent, Pres. J.F. Kennedylaan 3, 9060 Zelzate (Belgium); Van De Putte, Tom, E-mail: tom.vandeputte@arcelormittal.com [OCAS N.V., ArcelorMittal Global R and D Gent, Pres. J.F. Kennedylaan 3, 9060 Zelzate (Belgium); Galceran, Montserrat [Université Libre de Bruxelles, 4MAT (Materials Engineering, Characterization, Synthesis and Recycling), Avenue F.D. Roosevelt 50, 1050 Brussels (Belgium); CIC Energigune, Albert Einstein 48, 01510 Miñano (Álava) (Spain); Godet, Stéphane [Université Libre de Bruxelles, 4MAT (Materials Engineering, Characterization, Synthesis and Recycling), Avenue F.D. Roosevelt 50, 1050 Brussels (Belgium)

    2013-12-15T23:59:59.000Z

    We report a detailed structural and chemical characterisation of aluminium silicon manganese nitrides that act as grain growth inhibitors in industrially processed grain-oriented (GO) electrical steels. The compounds are characterised using energy dispersive X-ray spectrometry (EDX) and energy filtered transmission electron microscopy (EFTEM), while their crystal structures are analysed using X-ray diffraction (XRD) and TEM in electron diffraction (ED), dark-field, high-resolution and automated crystallographic orientation mapping (ACOM) modes. The chemical bonding character is determined using electron energy loss spectroscopy (EELS). Despite the wide variation in composition, all the precipitates exhibit a hexagonal close-packed (h.c.p.) crystal structure and lattice parameters of aluminium nitride. The EDX measurement of ? 900 stoichiometrically different precipitates indicates intermediate structures between pure aluminium nitride and pure silicon manganese nitride, with a constant Si/Mn atomic ratio of ? 4. It is demonstrated that aluminium and silicon are interchangeably precipitated with the same local arrangement, while both Mn{sup 2+} and Mn{sup 3+} are incorporated in the h.c.p. silicon nitride interstitial sites. The oxidation of the silicon manganese nitrides most likely originates from the incorporation of oxygen during the decarburisation annealing process, thus creating extended planar defects such as stacking faults and inversion domain boundaries. The chemical composition of the inhibitors may be written as (AlN){sub x}(SiMn{sub 0.25}N{sub y}O{sub z}){sub 1?x} with x ranging from 0 to 1. - Highlights: • We study the structure of (Al,Si,Mn)N inhibitors in grain oriented electrical steels. • Inhibitors have the hexagonal close-packed symmetry with lattice parameters of AlN. • Inhibitors are intermediate structures between pure AlN and (Si,Mn)N with Si/Mn ? 4. • Al and Si share the same local arrangement; Mn is incorporated in both Mn{sup 2+} and Mn{sup 3+}. • Oxygen incorporation is invoked to account for the thermal stability of (Al,Si,Mn)N.

  18. Nano-sized Lithium Manganese Oxide Dispersed on Carbon Nanotubes for Energy Storage Applications

    SciTech Connect (OSTI)

    Bak, S.B.

    2009-08-01T23:59:59.000Z

    Nano-sized lithium manganese oxide (LMO) dispersed on carbon nanotubes (CNT) has been synthesized successfully via a microwave-assisted hydrothermal reaction at 200 C for 30 min using MnO{sub 2}-coated CNT and an aqueous LiOH solution. The initial specific capacity is 99.4 mAh/g at a 1.6 C-rate, and is maintained at 99.1 mAh/g even at a 16 C-rate. The initial specific capacity is also maintained up to the 50th cycle to give 97% capacity retention. The LMO/CNT nanocomposite shows excellent power performance and good structural reversibility as an electrode material in energy storage systems, such as lithium-ion batteries and electrochemical capacitors. This synthetic strategy opens a new avenue for the effective and facile synthesis of lithium transition metal oxide/CNT nanocomposite.

  19. Investigation of the release of Si from SiO{sub 2} during the formation of manganese/ruthenium barrier layers

    SciTech Connect (OSTI)

    McCoy, A. P.; Casey, P.; Bogan, J.; Byrne, C.; Hughes, G. [School of Physical Sciences, Dublin City University, Dublin 9 (Ireland)] [School of Physical Sciences, Dublin City University, Dublin 9 (Ireland)

    2013-05-20T23:59:59.000Z

    The thermodynamic and structural stability of ruthenium-manganese diffusion barriers on SiO{sub 2} is assessed. A {approx}2 nm film composed of partially oxidized manganese (MnO{sub x} where x < 1) was deposited on a 3 nm thick Ru film and the Mn-MnO{sub x}/Ru/SiO{sub 2} structure was subsequently thermally annealed. X-ray photoelectron spectroscopy and secondary ion mass spectroscopy studies suggest the release and upward diffusion of Si from the dielectric substrate as a result of manganese-silicate formation at the Ru/SiO{sub 2} interface. The migration of Si up through the Ru film results in further manganese-silicate formation upon its interaction with the Mn-MnO{sub x} deposited layer.

  20. By Thomas S. Jones Manganese (Mn) is essential to iron and steel production by have been among the larger producers. World production of

    E-Print Network [OSTI]

    Torgersen, Christian

    . Steelmaking, including its ironmaking Survey to three significant digits. Table footnotes will indicate. According to reported data, the rates of consumption of manganese as ore in ironmaking and as ferroalloys

  1. Synthesis gas conversion in a mixed slurry reactor with iron-manganese catalysts. [Four catalysts with iron-manganese ratios of 57/43, 44/56, 22/78, and 10/90

    SciTech Connect (OSTI)

    Pennline, H.W.; Zarochak, M.F.; Tischer, R.E.; Schehl, R.R.

    1984-01-01T23:59:59.000Z

    Synthesis gas was reacted over different compositions of iron-manganese Fischer-Tropsch catalysts in a slurry reactor. The reactor operates in a back-mixed mode with a continuous flow of feed gas through the catalyst suspended in the liquid medium. Four catalysts with iron-manganese ratios of 57/43, 44/56, 22/78, and 10/90 were investigated at identical process conditions after a standard activation procedure. With time on stream for each catalyst system, hydrogenation of olefins occurred, along with olefin isomerization reactions. Activity, selectivity, and stability are discussed in general. Analyses of used catalyst samples are also reported. 20 refs., 2 figs., 4 tabs.

  2. Aerobic oxidation of anthracene in the presence of manganese porphyrinates and NaBH/sub 4/ reducing agent

    SciTech Connect (OSTI)

    Lukashova, E.A.; Solov'ev, A.B.; Chugreev, A.L.; Enikolopyan, N.S.

    1987-12-01T23:59:59.000Z

    The authors investigate the kinetics of anthracene oxidation by molecular oxygen in the presence of manganese, iron, and cobalt porphyrinate catalysts and a sodium borohydride reducing agent at room temperature in solutions of ethanol or ethanol with chloroform and benzene. Effective rate constants for the reactions are determined based on the amount of anthraquinone formed in the reaction. In all cases with the exception of cobalt tetraphenylporphyrinate the only oxidation product was anthraquinone. Its structure was verified by NMR and IR spectroscopy.

  3. Activation and promotion studies in a mixed slurry reactor with an iron-manganese Fischer-Tropsch catalyst

    SciTech Connect (OSTI)

    Pennline, H.W.; Zarochak, M.F.; Stencel, J.M.; Diehl, J.R.

    1987-03-01T23:59:59.000Z

    Synthesis gas was reacted over a coprecipitated iron-manganese Fischer-Tropsch catalyst in a slurry reactor. The effect of various activation parameters - temperature, pressure, and gas composition - on subsequent catalyst activity and product selectivity was investigated. The gas composition had the most dramatic effect on the catalyst activation and the ensuing synthesis gas conversion. The effect of potassium promotion on catalyst activity and product selectivity was also studied in slurry reactor tests.

  4. Synthesis, structures and properties of a series of manganese coordination complexes constructed from dicarboxylic fluorene derivatives

    SciTech Connect (OSTI)

    Li Xing, E-mail: lixing@nbu.edu.cn [State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211 (China); Zhao Xiuhua; Bing Yue; Zha Meiqin; Xie Hongzhen; Guo Zhiyong [State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211 (China)

    2013-01-15T23:59:59.000Z

    Assembly reactions of 9,9-diethylfluorene-2,7-dicarboxylic acid (H{sub 2}DFDC) and Mn(CH{sub 3}COO){sub 2}{center_dot}4H{sub 2}O or MnCl{sub 2}{center_dot}4H{sub 2}O by tuning of various secondary ligands such as 2,2 Prime -bipyridine (2,2 Prime -bpy), 4,4 Prime -bipyridine (4,4 Prime -bpy) or 1,3-bis(4-pyridyl)propane) (bpp), gave rise to four complexes {l_brace} [Mn{sub 2}(DFDC){sub 2}(DMF){sub 2}]{center_dot}H{sub 2}O{r_brace} {sub n} (1), [Mn(DFDC)(2,2 Prime -bpy)]{sub n} (2), {l_brace} [Mn{sub 2}(DFDC){sub 2}(4,4 Prime -bpy){sub 2}]{center_dot}2CH{sub 3}OH{r_brace} {sub n} (3), and {l_brace} [Mn{sub 4}(DFDC){sub 4}(bpp){sub 2}(CH{sub 3}OH){sub 3} (H{sub 2}O){sub 3}]{center_dot}3(CH{sub 3}OH){center_dot}3(H{sub 2}O){r_brace} {sub n} (4). Single crystal X-ray diffraction analysis reveal that complex 1 is three dimensional structure with rhombic channels filled by guest water molecules; 2 presents a close-packed structure with high thermal stability; 3 exhibits a three dimensional framework with micro-porous channels filled by guest methanol molecules and 4 is a two-dimensional structure. The photoluminescent properties of 1-4 have been studied, respectively, showing that the Mn(II) ions, accessorial organic ligands or crystal structures exert important influences on the photoluminescence emissions of H{sub 2}DFDC ligands. Thermogravimetric analysis show that the complexes have remarkably high thermal stability. Magnetic susceptibility measurements have been finished and discussed for the complexes. - Graphical abstract: Assembly of 9,9-diethylfluorene-2,7-dicarboxylic acid and Mn(II) salts by tuning of various accessorial ligands resulted in four manganese complexes with different topological frameworks. Highlights: Black-Right-Pointing-Pointer Four manganese complexes based on 9,9-diethylfluorene-2,7-dicarboxylic acid were obtained. Black-Right-Pointing-Pointer The complexes were structurally characterized by single-crystal X-ray diffraction. Black-Right-Pointing-Pointer The complexes 1-4 display different topological structures. Black-Right-Pointing-Pointer Thermogravimetric analysis show the complexes have remarkably high thermal stability.

  5. Enhanced power factor of higher manganese silicide via melt spin synthesis method

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shi, Xiaoya [Brookhaven National Lab. (BNL), Upton, NY (United States); Shi, Xun [Chinese Academy of Sciences, Shanghai (China); Li, Yulong [Chinese Academy of Sciences, Shanghai (China); He, Ying [Chinese Academy of Sciences, Shanghai (China); Chen, Lidong [Chinese Academy of Sciences, Shanghai (China); Li, Qiang [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2014-12-28T23:59:59.000Z

    We report on the thermoelectric properties of the Higher Manganese Silicide MnSi?.?? (HMS) synthesized by means of a one-step non-equilibrium method. The ultrahigh cooling rate generated from the melt-spin technique is found to be effective in reducing second phases, which are inevitable during the traditional solid state diffusion processes. Aside from being detrimental to thermoelectric properties, second phases skew the revealing of the intrinsic properties of this class of materials, for example the optimal level of carrier concentration. With this melt-spin sample, we are able to formulate a simple model based on a single parabolic band that can well describe the carrier concentration dependence of the Seebeck coefficient and power factor of the data reported in the literature. An optimal carrier concentration around 5x10²? cm?³ at 300 K is predicted according to this model. The phase-pure melt-spin sample shows the largest power factor at high temperature, resulting in the highest zT value among the three samples in this paper. And the maximum value is superior to those reported in the literatures.

  6. Influence of nitrogen sufficiency and manganese deficiency on PAH degradation by Bjerkandera sp.

    SciTech Connect (OSTI)

    Kotterman, M.J.J.; Wasseveld, R.; Field, J.A. [Wageningen Agricultural Univ. (Netherlands). Div. of Industrial Microbiology

    1995-12-31T23:59:59.000Z

    The effect of Mn and N nutrients on the biodegradation of the model polycyclic aromatic hydrocarbon (PAH) compound, anthracene, by the N-deregulated ligninolytic fungus Bjerkandera sp. BOS55 was studied. Organic N supplements in the form of an amino acid mixture or peptone resulted in 10- to 14-fold increases in the extracellular peroxidase titers compared to those obtained in the basal N-limited medium. Although these enzymes are involved in the initial attack on PAH, the peptone supplement only increased the rate of anthracene elimination by 2.5 fold. The absence of Mn, which decreased the manganese peroxidase (MnP) titer and increased the lignin peroxidase (LiP) titer, was associated with a large improvement in the anthracene degradation. Mn deficiency also increased the yield of anthraquinone, a known product from peroxidase-mediated conversions of anthracene. Under the best conditions, with peptone N supplementing Mn-free medium, the anthracene degradation rate was 31 mg L{sup {minus}1} day{sup {minus}1}.

  7. Synthesis and crystal structure of the coordination compound of pyridoxine with manganese sulfate

    SciTech Connect (OSTI)

    Furmanova, N. G., E-mail: furm@ns.crys.ras.ru; Verin, I. A. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Shyityeva, N.; Sulaimankulov, K. S.; Berdalieva, Zh.; Resnyanskii, V. F. [National Academy of Sciences of Kyrgyzstan, Institute of Chemistry and Chemical Technology (Kyrgyzstan); Duishenbaeva, A. T. [Kyrgyz National University (Kyrgyzstan)

    2011-11-15T23:59:59.000Z

    The reaction of pyridoxine with manganese sulfate in an aqueous solution gave the coordination compound MnSO{sub 4} {center_dot} 2C{sub 8}H{sub 11}O{sub 3}N {center_dot} 2H{sub 2}O (I). The structure of I was determined from single-crystal X-ray diffraction data. In the centrosymmetric complex (sp. gr. P1-bar, Z = 1), the Mn atom is coordinated by two pyridoxine molecules and two water molecules, thus adopting an octahedral coordination. The sulfate anion is also at a center of symmetry and, consequently, is disordered. The pyridoxine molecules are coordinated to the metal atom through the oxygen atoms of the deprotonated hydroxyl group and the CH{sub 2}OH group that retains the hydrogen atom. The nitrogen atom is protonated in such a way that the heterocycle assumes a pyridinium character. The crystal structure also contains six water molecules of crystallization. A thermogravimetric study showed that the decomposition of I occurs in several successive steps, such as dehydration, the combustion of organic ligands, and the formation of an inorganic residue.

  8. Magnesium and Manganese Silicides For Efficient And Low Cost Thermo-Electric Power Generation

    SciTech Connect (OSTI)

    Trivedi, Sudhir B. [Brimrose Technology Corporation; Kutcher, Susan W. [Brimrose Technology Corporation; Rosemeier, Cory A. [Brimrose Technology Corporation; Mayers, David [Brimrose Technology Corporation; Singh, Jogender [Pennsylvania State University

    2013-12-02T23:59:59.000Z

    Thermoelectric Power Generation (TEPG) is the most efficient and commercially deployable power generation technology for harvesting wasted heat from such things as automobile exhausts, industrial furnaces, and incinerators, and converting it into usable electrical power. We investigated the materials magnesium silicide (Mg2Si) and manganese silicide (MnSi) for TEG. MgSi2 and MnSi are environmentally friendly, have constituent elements that are abundant in the earth's crust, non-toxic, lighter and cheaper. In Phase I, we successfully produced Mg2Si and MnSi material with good TE properties. We developed a novel technique to synthesize Mg2Si with good crystalline quality, which is normally very difficult due to high Mg vapor pressure and its corrosive nature. We produced n-type Mg2Si and p-type MnSi nanocomposite pellets using FAST. Measurements of resistivity and voltage under a temperature gradient indicated a Seebeck coefficient of roughly 120 V/K on average per leg, which is quite respectable. Results indicated however, that issues related to bonding resulted in high resistivity contacts. Determining a bonding process and bonding material that can provide ohmic contact from room temperature to the operating temperature is an essential part of successful device fabrication. Work continues in the development of a process for reproducibly obtaining low resistance electrical contacts.

  9. Approaching the Minimum Thermal Conductivity in Rhenium-Substituted Higher Manganese Silicides

    SciTech Connect (OSTI)

    Chen, Xi [University of Texas at Austin] [University of Texas at Austin; Girard, S. N. [University of Wisconsin, Madison] [University of Wisconsin, Madison; Meng, F. [University of Wisconsin, Madison] [University of Wisconsin, Madison; Lara-Curzio, Edgar [ORNL] [ORNL; Jin, S [University of Wisconsin, Madison] [University of Wisconsin, Madison; Goodenough, J. B. [University of Texas at Austin] [University of Texas at Austin; Zhou, J. S. [University of Texas at Austin] [University of Texas at Austin; Shi, L [University of Texas at Austin] [University of Texas at Austin

    2014-01-01T23:59:59.000Z

    Higher manganese silicides (HMS) made of earth-abundant and non-toxic elements are regarded as promising p-type thermoelectric materials because their complex crystal structure results in low lattice thermal conductivity. It is shown here that the already low thermal conductivity of HMS can be reduced further to approach the minimum thermal conductivity via partial substitu- tion of Mn with heavier rhenium (Re) to increase point defect scattering. The solubility limit of Re in the obtained RexMn1 xSi1.8 is determined to be about x = 0.18. Elemental inhomogeneity and the formation of ReSi1.75 inclusions with 50 200 nm size are found within the HMS matrix. It is found that the power factor does not change markedly at low Re content of x 0.04 before it drops considerably at higher Re contents. Compared to pure HMS, the reduced lattice thermal conductivity in RexMn1 xSi1.8 results in a 25% increase of the peak figure of merit ZT to reach 0.57 0.08 at 800 K for x = 0.04. The suppressed thermal conductivity in the pure RexMn1 xSi1.8 can enable further investigations of the ZT limit of this system by exploring different impurity doping strategies to optimize the carrier concentration and power factor.

  10. Enhanced power factor of higher manganese silicide via melt spin synthesis method

    SciTech Connect (OSTI)

    Shi, Xiaoya [Brookhaven National Lab. (BNL), Upton, NY (United States); Shi, Xun [Chinese Academy of Sciences, Shanghai (China); Li, Yulong [Chinese Academy of Sciences, Shanghai (China); He, Ying [Chinese Academy of Sciences, Shanghai (China); Chen, Lidong [Chinese Academy of Sciences, Shanghai (China); Li, Qiang [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2014-12-28T23:59:59.000Z

    We report on the thermoelectric properties of the Higher Manganese Silicide MnSi?.?? (HMS) synthesized by means of a one-step non-equilibrium method. The ultrahigh cooling rate generated from the melt-spin technique is found to be effective in reducing second phases, which are inevitable during the traditional solid state diffusion processes. Aside from being detrimental to thermoelectric properties, second phases skew the revealing of the intrinsic properties of this class of materials, for example the optimal level of carrier concentration. With this melt-spin sample, we are able to formulate a simple model based on a single parabolic band that can well describe the carrier concentration dependence of the Seebeck coefficient and power factor of the data reported in the literature. An optimal carrier concentration around 5x10²? cm?³ at 300 K is predicted according to this model. The phase-pure melt-spin sample shows the largest power factor at high temperature, resulting in the highest zT value among the three samples in this paper. And the maximum value is superior to those reported in the literatures.

  11. Solar-thermal Water Splitting Using the Sodium Manganese Oxide Process & Preliminary H2A Analysis

    SciTech Connect (OSTI)

    Todd M. Francis, Paul R. Lichty, Christopher Perkins, Melinda Tucker, Peter B. Kreider, Hans H. Funke, Allan Lewandowski, and Alan W. Weimer

    2012-10-24T23:59:59.000Z

    There are three primary reactions in the sodium manganese oxide high temperature water splitting cycle. In the first reaction, Mn2O3 is decomposed to MnO at 1,500°C and 50 psig. This reaction occurs in a high temperature solar reactor and has a heat of reaction of 173,212 J/mol. Hydrogen is produced in the next step of this cycle. This step occurs at 700°C and 1 atm in the presence of sodium hydroxide. Finally, water is added in the hydrolysis step, which removes NaOH and regenerates the original reactant, Mn2O3. The high temperature solar�driven step for decomposing Mn2O3 to MnO can be carried out to high conversion without major complication in an inert environment. The second step to produce H2 in the presence of sodium hydroxide is also straightforward and can be completed. The third step, the low temperature step to recover the sodium hydroxide is the most difficult. The amount of energy required to essentially distill water to recover sodium hydroxide is prohibitive and too costly. Methods must be found for lower cost recovery. This report provides information on the use of ZnO as an additive to improve the recovery of sodium hydroxide.

  12. Enhanced power factor of higher manganese silicide via melt spin synthesis method

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shi, Xiaoya; Shi, Xun; Li, Yulong; He, Ying; Chen, Lidong; Li, Qiang

    2014-12-28T23:59:59.000Z

    We report on the thermoelectric properties of the Higher Manganese Silicide MnSi?.?? (HMS) synthesized by means of a one-step non-equilibrium method. The ultrahigh cooling rate generated from the melt-spin technique is found to be effective in reducing second phases, which are inevitable during the traditional solid state diffusion processes. Aside from being detrimental to thermoelectric properties, second phases skew the revealing of the intrinsic properties of this class of materials, for example the optimal level of carrier concentration. With this melt-spin sample, we are able to formulate a simple model based on a single parabolic band that can well describemore »the carrier concentration dependence of the Seebeck coefficient and power factor of the data reported in the literature. An optimal carrier concentration around 5x10²? cm?³ at 300 K is predicted according to this model. The phase-pure melt-spin sample shows the largest power factor at high temperature, resulting in the highest zT value among the three samples in this paper. And the maximum value is superior to those reported in the literatures.« less

  13. american soil geochemical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    METAL DEFICIENCY IN CATTLE? By: Emily, they are also vital to the health of cattle. The metals investigated in this report were copper, iron, manganese and superoxide radicals....

  14. Search for new manganese-cobalt oxides as positive electrode materials for lithium batteries P. Strobel, J. Tillier, A. Diaz, A. Ibarra-Palos, F. Thiry and J.B. Soupart *

    E-Print Network [OSTI]

    Boyer, Edmond

    positive electrode material for lithium batteries ; last but not least, copper or cobalt substitutionSearch for new manganese-cobalt oxides as positive electrode materials for lithium batteries P new mixed manganese-cobalt oxides for lithium battery positive electrode materials were obtained using

  15. Site-specific local structure of Mn in artificial manganese ferrite films E. Kravtsov,1,2 D. Haskel,1 A. Cady,1 A. Yang,3 C. Vittoria,3 X. Zuo,4 and V. G. Harris3

    E-Print Network [OSTI]

    Haskel, Daniel

    Site-specific local structure of Mn in artificial manganese ferrite films E. Kravtsov,1,2 D. Haskel in manganese ferrite films grown under nonequilibrium conditions. The DAFS spectra were measured at a number. INTRODUCTION There has been considerable long-term interest in spinel ferrite materials due

  16. Synthesis, characterization and magnetic properties of a manganese (II) silicate containing frustrated S=5/2 zig–zag ladders

    SciTech Connect (OSTI)

    Brandão, P., E-mail: pbrandao@ua.pt [Departamento de Qímica/CICECO, Universidade de Aveiro, 3810-193 Aveiro (Portugal); Santos, A.M. dos [Quantum Condensed Matter Division, Neutron Sciences Directorate, Oak Ridge National Laboratory, Oak Ridge, TN 37831-6475 (United States); Paixão, L.S.; Reis, M.S. [Instituto de Física, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza s/n, 24210-346 Niterói, RJ (Brazil)

    2014-03-15T23:59:59.000Z

    The hydrothermal synthesis, structural characterization and magnetic properties of a manganese silicate with ideal formula of NaMn{sub 2}Si{sub 3}O{sub 8}(OH) is reported. This compound is a synthetic analog to the naturally occurring mineral Serandite. The crystal structure comprises MnO{sub 6} octahedra and SiO{sub 4} tetrahedra. The MnO{sub 6} share four edges with neighboring octahedra forming double chains. These chains are connected by silicate chains Si{sub 3}O{sub 8}(OH) resulting in an open framework structure with six-member ring channels where sodium ions are located. From the magnetic point of view, the intra-chain exchange between neighboring S=5/2 manganese ions is weak, partly due to the distortion observed in the octahedra, but also due to the frustrated topology of the chain. A successful fitting of the magnetic susceptibility was obtained by considering a double chain numerical model with Monte Carlo derived empirical parameters. -- Graphical abstract: A manganese silicate prepared hydrothermally with formula NaMn{sub 2}Si{sub 3}O{sub 8}(OH) possessing the structure of the mineral Serandite contains doubled chains of edge-sharing MnO{sub 6} octahedra. The magnetic susceptibility was measured and shows an antiferromagnetic behavior. Highlights: • Characterization of a synthetic analog to the mineral Serandite: NaMn{sub 2}Si{sub 3}O{sub 8}(OH). • Fitting of the magnetic susceptibility considering a classical regular chain. • Weak metal–oxygen–metal super-exchange interactions; antiferromagnetic in nature. • Elevated degree of frustration along the chain, without sign of interchain ordering.

  17. Spatially resolved characterization of biogenic manganese oxideproduction within a bacterial biofilm

    SciTech Connect (OSTI)

    Toner, Brandy; Fakra, Sirine; Villalobos, Mario; Warwick, Tony; Sposito, Garrison

    2004-10-01T23:59:59.000Z

    Pseudomonas putida strain MnB1, a biofilm forming bacteria, was used as a model for the study of bacterial Mn oxidation in freshwater and soil environments. The oxidation of Mn{sub (aq)}{sup +2} by P. putida was characterized by spatially and temporally resolving the oxidation state of Mn in the presence of a bacterial biofilm using scanning transmission x-ray microscopy (STXM) combined with near edge x-ray absorption fine structure (NEXAFS) spectroscopy at the Mn-L{sub 2,3} absorption edges. Subsamples were collected from growth flasks containing 0.1 mM and 1 mM total Mn at 16, 24, 36 and 48 hours after inoculation. Immediately after collection, the unprocessed hydrated subsamples were imaged at 40 nm resolution. Manganese NEXAFS spectra were extracted from x-ray energy sequences of STXM images (stacks) and fit with linear combinations of well characterized reference spectra to obtain quantitative relative abundances of Mn(II), Mn(III) and Mn(IV). Careful consideration was given to uncertainty in the normalization of the reference spectra, choice of reference compounds, and chemical changes due to radiation damage. The STXM results confirm that Mn{sub (aq)}{sup +2} was removed from solution by P. putida and was concentrated as Mn(III) and Mn(IV) immediately adjacent to the bacterial cells. The Mn precipitates were completely enveloped by bacterial biofilm material. The distribution of Mn oxidation states was spatially heterogeneous within and between the clusters of bacterial cells. Scanning transmission x-ray microscopy is a promising tool to advance the study of hydrated interfaces between minerals and bacteria, particularly in cases where the structure of bacterial biofilms needs to be maintained.

  18. Structural implications of the C-terminal tail in the catalytic and stability properties of manganese peroxidases from ligninolytic fungi

    SciTech Connect (OSTI)

    Fernández-Fueyo, Elena [CSIC, Ramiro de Maeztu 9, 28040 Madrid (Spain); Acebes, Sandra [Barcelona Supercomputing Center, Jordi Girona 29, 08034 Barcelona (Spain); Ruiz-Dueñas, Francisco J.; Martínez, María Jesús; Romero, Antonio; Medrano, Francisco Javier, E-mail: fjmedrano@cib.csic.es [CSIC, Ramiro de Maeztu 9, 28040 Madrid (Spain); Guallar, Victor, E-mail: fjmedrano@cib.csic.es [Barcelona Supercomputing Center, Jordi Girona 29, 08034 Barcelona (Spain); ICREA, Passeig Lluís Companys 23, 08010 Barcelona (Spain); Martínez, Angel T., E-mail: fjmedrano@cib.csic.es [CSIC, Ramiro de Maeztu 9, 28040 Madrid (Spain)

    2014-12-01T23:59:59.000Z

    The variable C-terminal tail of manganese peroxidases, a group of enzymes involved in lignin degradation, is implicated in their catalytic and stability properties, as shown by new crystal structures, molecular-simulation and directed-mutagenesis data. Based on this structural–functional evaluation, short and long/extralong manganese peroxidase subfamilies have been accepted; the latter are characterized by exceptional stability, while it is shown for the first time that the former are able to oxidize other substrates at the same site where manganese(II) is oxidized. The genome of Ceriporiopsis subvermispora includes 13 manganese peroxidase (MnP) genes representative of the three subfamilies described in ligninolytic fungi, which share an Mn{sup 2+}-oxidation site and have varying lengths of the C-terminal tail. Short, long and extralong MnPs were heterologously expressed and biochemically characterized, and the first structure of an extralong MnP was solved. Its C-terminal tail surrounds the haem-propionate access channel, contributing to Mn{sup 2+} oxidation by the internal propionate, but prevents the oxidation of 2, 2?-azino-bis(3-ethylbenzothiazoline-6-sulfonate) (ABTS), which is only oxidized by short MnPs and by shortened-tail variants from site-directed mutagenesis. The tail, which is anchored by numerous contacts, not only affects the catalytic properties of long/extralong MnPs but is also associated with their high acidic stability. Cd{sup 2+} binds at the Mn{sup 2+}-oxidation site and competitively inhibits oxidation of both Mn{sup 2+} and ABTS. Moreover, mutations blocking the haem-propionate channel prevent substrate oxidation. This agrees with molecular simulations that position ABTS at an electron-transfer distance from the haem propionates of an in silico shortened-tail form, while it cannot reach this position in the extralong MnP crystal structure. Only small differences exist between the long and the extralong MnPs, which do not justify their classification as two different subfamilies, but they significantly differ from the short MnPs, with the presence/absence of the C-terminal tail extension being implicated in these differences.

  19. Preparation of anionic clay-birnessite manganese oxide composites by interlayer oxidation of oxalate ions by permanganate

    SciTech Connect (OSTI)

    Arulraj, James [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India)] [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India); Rajamathi, Michael, E-mail: mikerajamathi@rediffmail.com [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India)] [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India)

    2013-02-15T23:59:59.000Z

    Oxalate intercalated anionic clay-like nickel zinc hydroxysalt was obtained starting from nickel zinc hydroxyacetate, Ni{sub 3}Zn{sub 2}(OH){sub 8}(OAc){sub 2}{center_dot}2H{sub 2}O, by anion exchange. The intercalated oxalate species was reacted with potassium permanganate in such a way that the layered manganese oxide formed was within the interlayer region of the anionic clay resulting in a layered composite in which the negative charges on the birnessite type manganese oxide layers compensate the positive charges on the anionic clay layers. Birnessite to anionic clay ratio could be varied by varying the reaction time or the amount of potassium permanganate used. - Graphical abstract: Nickel zinc hydroxyoxalate was reacted with potassium permanganate to get nickel zinc hydroxide birnessite composites in which the positive charges on the hydroxide layers are neutralized by the negative charges on birnessite layers. Highlights: Black-Right-Pointing-Pointer Anionic and cationic layered solid composites prepared. Black-Right-Pointing-Pointer Ni-Zn hydroxyoxalate reacted with KMnO{sub 4} to deposit MnO{sub 2} in the interlayer. Black-Right-Pointing-Pointer Birnessite layers coexist with anionic clay layers in the composites. Black-Right-Pointing-Pointer Birnessite/anionic clay ratio controlled by amount of KMnO{sub 4} used and reaction time.

  20. Manganese reduction/oxidation reaction on graphene composites as a reversible process for storing enormous energy at a fast rate

    E-Print Network [OSTI]

    Chen, Yanyi; Shi, Shan; Li, Jia; Kang, Feiyu; Wei, Chunguang

    2014-01-01T23:59:59.000Z

    Oxygen reduction/evolution reaction (ORR/OER) is a basic process for fuel cells or metal air batteries. However, ORR/OER generally requires noble metal catalysts and suffers from low solubility (10-3 molar per liter) of O2, low kinetics rate (10-6 cm2/s) and low reversibility. We report a manganese reduction/oxidation reaction (MRR/MOR) on graphene/MnO2 composites, delivering a high capacity (4200 mAh/g), fast kinetics (0.0024 cm2/s, three orders higher than ORR/OER), high solubility (three orders than O2), and high reversibility (100%). We further use MRR/MOR to invent a rechargeable manganese ion battery (MIB), which delivers an energy density of 1200 Wh/Kg (several times of lithium ion battery), a fast charge ability (3 minutes), and a long cycle life (10,000 cycles). MRR/MOR renders a new class of energy conversion or storage systems with a very high energy density enabling electric vehicles run much more miles at one charge.

  1. Electrodeposited Manganese Oxides on Three-Dimensional Carbon Nanotube Substrate: Supercapacitive Behaviour in Aqueous and Organic Electrolytes

    SciTech Connect (OSTI)

    Nam,K.W.; Yang,X.

    2009-03-01T23:59:59.000Z

    Thin amorphous manganese oxide layers with a thickness of 3-5nm are electrodeposited on a carbon nanotube (CNT) film substrate that has a three-dimensional nanoporous structure (denoted asMnO2/CNT electrode). For the purpose of comparison, manganese oxide films are also electrodeposited on a flat Pt-coated Si wafer substrate (denoted as MnO2 film electrode). The pseudocapacitive properties of the MnO2 film and MnO2/CNT electrodes are examined in both aqueous electrolyte (1.0M KCl) and nonaqueousorganic electrolyte (1.0M LiClO4 in propylene carbonate). While both types of electrode showpseudocapacitive behaviour in the aqueous electrolyte, only the MnO2/CNT electrode does so in the organic electrolyte, due to its high oxide/electrolyte interfacial area and improved electron conduction through the CNT substrate. Compared with the MnO2 film electrode, the MnO2/CNT electrode shows a much higher specific capacitance and better high-rate capability, regardless of the electrolyte used.Use of the organic electrolyte results in a ?6 times higher specific energy compared with that obtained with the aqueous electrolyte, while maintaining a similar specific power. The construction of a threedimensional nanoporous network structure consisting of a thin oxide layer on a CNT film substrate at the nm scale and the use of an organic electrolyte are promising approaches to improving the specific energyof supercapacitors.

  2. Oxygen detoxification in micro-metazoans of the sulfide-system

    E-Print Network [OSTI]

    Morrill, Audrey Carr

    1986-01-01T23:59:59.000Z

    )& neither need or possess the enzymes catalase and superoxide dismutase (SOD), which are neccessary to detoxify hydrogen peroxide& H 0 , and superoxide radicals, 0 , respectively. Second& if meioi'auna do contain catalase and superoxide dismutase, could.... It is possible that superoxi. de radioals and The style and format of this thesis follows that of &) ~~ hydrogen peroxide are formed in the process of sulfur detoxificationi since these are unwanted byproducts of any reaction involving molecular oxygen...

  3. Effects of (Al,Ge) double doping on the thermoelectric properties of higher manganese silicides

    SciTech Connect (OSTI)

    Chen, Xi; Salta, Daniel; Zhang, Libin [Materials Science and Engineering Program, Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712 (United States); Weathers, Annie [Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States); Zhou, Jianshi; Goodenough, John B.; Shi, Li [Materials Science and Engineering Program, Texas Materials Institute, The University of Texas at Austin, Austin, Texas 78712 (United States); Department of Mechanical Engineering, The University of Texas at Austin, Austin, Texas 78712 (United States)

    2013-11-07T23:59:59.000Z

    Experiments and analysis have been carried out to investigate the effects of Al and (Al,Ge) doping on the microstructure and thermoelectric properties of polycrystalline higher manganese silicide (HMS) samples, which were prepared by solid-state reaction, ball milling, and followed by spark plasma sintering. It has been found that Al doping effectively increases the hole concentration, which leads to an increase in the electrical conductivity and power factor. By introducing the second dopant Ge into Al-doped HMS, the electrical conductivity is increased, and the Seebeck coefficient is decreased as a result of further increased hole concentration. The peak power factor is found to occur at a hole concentration between 1.8?×?10{sup 21} and 2.2?×?10{sup 21}?cm{sup ?3} measured at room temperature. The (Al,Ge)-doped HMS samples show lower power factors owing to their higher hole concentrations. The mobility of Mn(Al{sub 0.0035}Ge{sub y}Si{sub 0.9965-y}){sub 1.8} with y?=?0.035 varies approximately as T{sup ?3/2} above 200?K, suggesting acoustic phonon scattering is the dominant scattering mechanism. The thermal conductivity of HMS does not change appreciably by Al or (Al,Ge) doping. The maximum ZT of (Al,Ge)-doped HMS is 0.57 at 823?K, which is similar to the highest value found in the Al-doped HMS samples. The ZT values were reduced in the Mn(Al{sub 0.0035}Ge{sub y}Si{sub 0.9965-y}){sub 1.8} samples with high Ge concentration of y?=?0.025 and 0.035, because of reduced power factor. In addition, a two-band model was employed to show that the hole contribution to the thermal conductivity dominates the bipolar and electron contributions for all samples from 300 to 823?K and accounts for about 12% of the total thermal conductivity at about 800?K.

  4. Correlation between structural, magnetic, and dielectric properties of manganese substituted cobalt ferrite

    SciTech Connect (OSTI)

    Ramana, C. V., E-mail: rvchintalapalle@utep.edu; Kolekar, Y. D.; Kamala Bharathi, K. [Department of Mechanical Engineering, University of Texas at El Paso, El Paso, Texas 79968 (United States); Sinha, B. [Functional Nanopowder Material Division, Korea Institute of Material Science, Changwon 642-831, Gyeongnam (Korea, Republic of); Ghosh, K. [Department of Physics, Astronomy and Materials Science, Missouri State University, Springfield, Missouri 65897 (United States)

    2013-11-14T23:59:59.000Z

    Manganese (Mn) substituted cobalt ferrites (CoFe{sub 2?x}Mn{sub x}O{sub 4}, referred to CFMO) were synthesized and their structural, magnetic, and dielectric properties were evaluated. X-ray diffraction measurements coupled with Rietveld refinement indicate that the CFMO materials crystallize in the inverse cubic spinel phase. Temperature (T?=?300?K and 10?K) dependent magnetization (M(H)) measurements indicate the long range ferromagnetic ordering in CoFe{sub 2?x}Mn{sub x}O{sub 4} (x?=?0.00–0.15) ferrites. The cubic anisotropy constant (K{sub 1}(T)) and saturation magnetization (M{sub s}(T)) were derived by using the “law of approach” to saturation that describes the field dependence of M(H) for magnetic fields much higher than the coercive field (H{sub c}). Saturation magnetization (M{sub s}), obtained from the model, decreases with increasing temperature. For CoFe{sub 2}O{sub 4}, M{sub s} decreases from 3.63??{sub B} per formula unit (f.u.) to 3.47??{sub B}/f.u. with increasing temperature from 10 to 300?K. CFMO (0.00–0.15) exhibit the similar trend while the magnitude of M{sub s} is dependent on Mn-concentration. M{sub s}-T functional relationship obeys the Bloch's law. The lattice parameter and magnetic moment calculated for CFMO reveals that Mn ions occupying the Fe and Co position at the octahedral site in the inverse cubic spinel phase. The structure and magnetism in CFMO are further corroborated by bond length and bond angle calculations. The dielectric constant dispersion of CFMO in the frequency range of 20?Hz–1?MHz fits to the modified Debye's function with more than one ion contributing to the relaxation. The relaxation time and spread factor derived from modeling the experimental data are ?10{sup ?4}?s and ?0.35(±0.05), respectively.

  5. Thermal chemistry of Mn{sub 2}(CO){sub 10} during deposition of thin manganese films on silicon oxide and on copper surfaces

    SciTech Connect (OSTI)

    Qin Xiangdong; Sun Huaxing; Zaera, Francisco [Department of Chemistry, University of California, Riverside, California 92521 (United States)

    2012-01-15T23:59:59.000Z

    The surface chemistry of dimanganese decacarbonyl on the native oxide of Si(100) wafers was characterized with the aid of x-ray photoelectron spectroscopy. Initial experiments in a small stainless-steel reactor identified a narrow range of temperatures, between approximately 445 and 465 K, in which the deposition of manganese could be achieved in a self-limiting fashion, as is desirable for atomic layer deposition. Deposition at higher temperatures leads to multilayer growth, but the extent of this Mn deposition reverses at even higher temperatures (about 625 K), and also ifhydrogen is added to the reaction mixture. Extensive decarbonylation takes place below room temperature, but limited C-O bond dissociation and carbon deposition are still seen after high exposures at 625 K. The films deposited at low ({approx}450 K) temperatures are mostly in the form of MnO, but at 625 K that converts to a manganese silicate, and upon higher doses a manganese silicide forms at the SiO{sub 2}/Si(100) interface as well. No metallic manganese could be deposited with this precursor on either silicon dioxide or copper surfaces.

  6. Atomic layer structure of manganese atoms on wurtzite gallium nitride Abhijit Chinchore, Kangkang Wang, Wenzhi Lin, Jeongihm Pak, and Arthur R. Smitha

    E-Print Network [OSTI]

    Atomic layer structure of manganese atoms on wurtzite gallium nitride ,,0001¯... Abhijit Chinchore on wurtzite GaN 0001¯ . The surface is monitored using reflection high energy electron diffraction, which to grow with an abrupt interface and well- defined epitaxial orientation on top of wurtzite w -GaN. Re

  7. A Large Manganese-doped Polyoxotitanate Nanocluster: Ti14MnO14(OH)2(OEt)28 Yang Chen,a

    E-Print Network [OSTI]

    Coppens, Philip

    containing titanium were stored and handled in a glove-box under a nitrogen atmosphere. Synthesis of Ti14Mn; Polyoxotitanate; Nanocluster; Crystal structure; Band gap. INTRODUCTION During the past decades, titanium dioxide as received: Titanium(IV) ethoxide (99+ %) was purchased from Alfa Aesar; manganese(III) acetate dihydrate (97

  8. Linking local structure and properties in perovskites containing equal concentrations of manganese and ruthenium

    SciTech Connect (OSTI)

    King, Graham; Ricciardo, Rebecca A.; Soliz, Jennifer R.; Woodward, Patrick M.; Llobet, Anna (OSU); (LANL)

    2011-08-16T23:59:59.000Z

    The local structures of six perovskite compounds containing equal amounts of manganese and ruthenium on the B-site have been investigated by neutron and x-ray pair distribution function analysis. The compounds SrMn{sub 0.5}Ru{sub 0.5}O{sub 3}, Sr{sub 0.5}Ca{sub 0.5}Mn{sub 0.5}Ru{sub 0.5}O{sub 3}, and CaMn{sub 0.5}Ru{sub 0.5}O{sub 3} were studied to investigate the effects of pure chemical pressure on the local structure and valency ratio between Mn{sup 3+}/Ru{sup 5+} and Mn{sup 4+}/Ru{sup 4+}. Reverse Monte Carlo simulations confirm that there is a shift in the B-site cation charge distribution from nearly equal amounts of Mn{sup 3+}, Ru{sup 5+}, Mn{sup 4+}, and Ru{sup 4+} for SrMn{sub 0.5}Ru{sub 0.5}O{sub 3} to primarily Mn{sup 4+} and Ru{sup 4+} for CaMn{sub 0.5}Ru{sub 0.5}O{sub 3}. The compounds Ba{sub 0.5}La{sub 0.5}Mn{sub 0.5}Ru{sub 0.5}O{sub 3}, Ca{sub 0.5}La{sub 0.5}Mn{sub 0.5}Ru{sub 0.5}O{sub 3}, and Sr{sub 0.5}Ca{sub 0.25}La{sub 0.25}Mn{sub 0.5}Ru{sub 0.5}O{sub 3} were also investigated to study the effects of changing the charge of the A-site cation. Although substitution of La{sup 3+} for a divalent alkaline earth ion increases the Mn{sup 3+} content, this series of compounds also shows a relative increase in the concentration of Mn{sup 4+} as the average size of the A-site cation is decreased. In all compounds the octahedra containing Mn{sup 3+} are found to be Jahn-Teller distorted regardless of whether or not long-range orbital ordering is observed, while the Ru-centered octahedra are symmetric. No evidence for short-range cation ordering at either the A- or B-sites was found for any of the compositions. This study also reports that locally the A-site cations lie closer to the Mn ions than to the Ru ions and this asymmetry appears to be correlated to the degree of octahedral tilting.

  9. Structural Study of Biotic and Abiotic Poorly-crystalline Manganese Oxides Using Atomic Pair Distribution Function Analysis

    SciTech Connect (OSTI)

    Billinge S. J.; Zhu, M.; Farrow, C.L.; Post, J.E.; Livi, K.J.T.; Ginder-Vogel, M.; Sparks, D.L.

    2012-03-15T23:59:59.000Z

    Manganese (Mn) oxides are among the most reactive natural minerals and play an important role in elemental cycling in oceanic and terrestrial environments. A large portion of naturally-occurring Mn oxides tend to be poorly-crystalline and/or nanocrystalline, with not fully resolved crystal structures. In this study, the crystal structures of their synthetic analogs including acid birnessite (AcidBir), {delta}-MnO{sub 2}, polymeric MnO{sub 2} (PolyMnO{sub 2}) and a bacteriogenic Mn oxide (BioMnO{sub x}), have been revealed using atomic pair distribution function (PDF) analysis. Results unambiguously verify that these Mn oxides are layered materials. The best models that accurately allow simulation of pair distribution functions (PDFs) belong to the monoclinic C12/m1 space group with a disk-like shape. The single MnO{sub 6} layers in the average structures deviate significantly from hexagonal symmetry, in contrast to the results of previous studies based on X-ray diffraction analysis in reciprocal space. Manganese occupancies in MnO{sub 6} layers are estimated to be 0.936, 0.847, 0.930 and 0.935, for AcidBir, BioMnO{sub x}, {delta}-MnO{sub 2} and PolyMnO{sub 2}, respectively; however, occupancies of interlayer cations and water molecules cannot be accurately determined using the models in this study. The coherent scattering domains (CSDs) of PolyMnO{sub 2}, {delta}-MnO{sub 2} and BioMnO{sub x} are at the nanometer scale, comprising one to three MnO{sub 6} layers stacked with a high disorder in the crystallographic c-axis direction. Overall, the results of this study advance our understanding of the mineralogy of Mn oxide minerals in the environment.

  10. Structural study of biotic and abiotic poorly-crystalline manganese oxides using atomic pair distribution function analysis

    SciTech Connect (OSTI)

    Zhu, Mengqiang; Farrow, Christopher L.; Post, Jeffrey E.; Livi, Kenneth J.T.; Billinge, Simon J.L.; Ginder-Vogel, Matthew; Sparks, Donald L. (Delaware); (Columbia); (JHU); (Smithsonian)

    2012-03-15T23:59:59.000Z

    Manganese (Mn) oxides are among the most reactive natural minerals and play an important role in elemental cycling in oceanic and terrestrial environments. A large portion of naturally-occurring Mn oxides tend to be poorly-crystalline and/or nanocrystalline, with not fully resolved crystal structures. In this study, the crystal structures of their synthetic analogs including acid birnessite (AcidBir), {delta}-MnO{sub 2}, polymeric MnO{sub 2} (PolyMnO{sub 2}) and a bacteriogenic Mn oxide (BioMnO{sub x}), have been revealed using atomic pair distribution function (PDF) analysis. Results unambiguously verify that these Mn oxides are layered materials. The best models that accurately allow simulation of pair distribution functions (PDFs) belong to the monoclinic C12/m1 space group with a disk-like shape. The single MnO{sub 6} layers in the average structures deviate significantly from hexagonal symmetry, in contrast to the results of previous studies based on X-ray diffraction analysis in reciprocal space. Manganese occupancies in MnO{sub 6} layers are estimated to be 0.936, 0.847, 0.930 and 0.935, for AcidBir, BioMnOx, {delta}-MnO{sub 2} and PolyMnO{sub 2}, respectively; however, occupancies of interlayer cations and water molecules cannot be accurately determined using the models in this study. The coherent scattering domains (CSDs) of PolyMnO{sub 2}, {delta}-MnO{sub 2} and BioMnO{sub x} are at the nanometer scale, comprising one to three MnO{sub 6} layers stacked with a high disorder in the crystallographic c-axis direction. Overall, the results of this study advance our understanding of the mineralogy of Mn oxide minerals in the environment.

  11. Acute ethanol intake induces superoxide anion generation and mitogen-activated protein kinase phosphorylation in rat aorta: A role for angiotensin type 1 receptor

    SciTech Connect (OSTI)

    Yogi, Alvaro; Callera, Glaucia E. [Kidney Research Centre, Ottawa Hospital Research Institute, University of Ottawa, Ontario (Canada)] [Kidney Research Centre, Ottawa Hospital Research Institute, University of Ottawa, Ontario (Canada); Mecawi, André S. [Department of Physiology, Faculty of Medicine of Ribeirão Preto, University of São Paulo (USP), Ribeirão Preto, SP (Brazil)] [Department of Physiology, Faculty of Medicine of Ribeirão Preto, University of São Paulo (USP), Ribeirão Preto, SP (Brazil); Batalhão, Marcelo E.; Carnio, Evelin C. [Department of General and Specialized Nursing, College of Nursing of Ribeirão Preto, USP, São Paulo (Brazil)] [Department of General and Specialized Nursing, College of Nursing of Ribeirão Preto, USP, São Paulo (Brazil); Antunes-Rodrigues, José [Department of Physiology, Faculty of Medicine of Ribeirão Preto, University of São Paulo (USP), Ribeirão Preto, SP (Brazil)] [Department of Physiology, Faculty of Medicine of Ribeirão Preto, University of São Paulo (USP), Ribeirão Preto, SP (Brazil); Queiroz, Regina H. [Department of Clinical, Toxicological and Food Science Analysis, Faculty of Pharmaceutical Sciences, USP, São Paulo (Brazil)] [Department of Clinical, Toxicological and Food Science Analysis, Faculty of Pharmaceutical Sciences, USP, São Paulo (Brazil); Touyz, Rhian M. [Kidney Research Centre, Ottawa Hospital Research Institute, University of Ottawa, Ontario (Canada)] [Kidney Research Centre, Ottawa Hospital Research Institute, University of Ottawa, Ontario (Canada); Tirapelli, Carlos R., E-mail: crtirapelli@eerp.usp.br [Department of Psychiatric Nursing and Human Sciences, Laboratory of Pharmacology, College of Nursing of Ribeirão Preto, USP, Ribeirão Preto, SP (Brazil)

    2012-11-01T23:59:59.000Z

    Ethanol intake is associated with increase in blood pressure, through unknown mechanisms. We hypothesized that acute ethanol intake enhances vascular oxidative stress and induces vascular dysfunction through renin–angiotensin system (RAS) activation. Ethanol (1 g/kg; p.o. gavage) effects were assessed within 30 min in male Wistar rats. The transient decrease in blood pressure induced by ethanol was not affected by the previous administration of losartan (10 mg/kg; p.o. gavage), a selective AT{sub 1} receptor antagonist. Acute ethanol intake increased plasma renin activity (PRA), angiotensin converting enzyme (ACE) activity, plasma angiotensin I (ANG I) and angiotensin II (ANG II) levels. Ethanol induced systemic and vascular oxidative stress, evidenced by increased plasma thiobarbituric acid-reacting substances (TBARS) levels, NAD(P)H oxidase?mediated vascular generation of superoxide anion and p47phox translocation (cytosol to membrane). These effects were prevented by losartan. Isolated aortas from ethanol-treated rats displayed increased p38MAPK and SAPK/JNK phosphorylation. Losartan inhibited ethanol-induced increase in the phosphorylation of these kinases. Ethanol intake decreased acetylcholine-induced relaxation and increased phenylephrine-induced contraction in endothelium-intact aortas. Ethanol significantly decreased plasma and aortic nitrate levels. These changes in vascular reactivity and in the end product of endogenous nitric oxide metabolism were not affected by losartan. Our study provides novel evidence that acute ethanol intake stimulates RAS activity and induces vascular oxidative stress and redox-signaling activation through AT{sub 1}-dependent mechanisms. These findings highlight the importance of RAS in acute ethanol-induced oxidative damage. -- Highlights: ? Acute ethanol intake stimulates RAS activity and vascular oxidative stress. ? RAS plays a role in acute ethanol-induced oxidative damage via AT{sub 1} receptor activation. ? Translocation of p47phox and MAPKs phosphorylation are downstream effectors. ? Acute ethanol consumption increases the risk for acute vascular injury.

  12. JOURNAL DE PHYSIQUE Collogue CI, supplement au n 4, Tome 38, Avril 1977, page Cl-27 PERMEABILITY MECHANISMS IN MANGANESE ZINC FERRITES

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    MECHANISMS IN MANGANESE ZINC FERRITES J. E. KNOWLES Mullard Research Laboratories Redhill, Surrey RH1 5HA des parois et des rotations à la perméabilité. Dans un ferrite à perméabilité élevée /iT et iï" sont ferrite à petits grains et faibles pertes fiT est alors maximal mais /iw et v sont minima. Ceci est

  13. Flow-Assisted Alkaline Battery: Low-Cost Grid-Scale Electrical Storage using a Flow-Assisted Rechargeable Zinc-Manganese Dioxide Battery

    SciTech Connect (OSTI)

    None

    2010-09-15T23:59:59.000Z

    GRIDS Project: Traditional consumer-grade disposable batteries are made of Zinc and Manganese, 2 inexpensive, abundant, and non-toxic metals. But these disposable batteries can only be used once. If they are recharged, the Zinc in the battery develops filaments called dendrites that grow haphazardly and disrupt battery performance, while the Manganese quickly loses its ability to store energy. CUNY Energy Institute is working to tame dendrite formation and to enhance the lifetime of Manganese in order to create a long-lasting, fully rechargeable battery for grid-scale energy storage. CUNY Energy Institute is also working to reduce dendrite formation by pumping fluid through the battery, enabling researchers to fix the dendrites as they’re forming. The team has already tested its Zinc battery through 3,000 recharge cycles (and counting). CUNY Energy Institute aims to demonstrate a better cycle life than lithium-ion batteries, which can be up to 20 times more expensive than Zinc-based batteries.

  14. Protective effects of ebselen (Ebs) and para-aminosalicylic acid (PAS) against manganese (Mn)-induced neurotoxicity

    SciTech Connect (OSTI)

    Marreilha dos Santos, A.P., E-mail: apsantos@ff.ul.pt [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal); Lucas, Rui L.; Andrade, Vanda; Mateus, M. Luísa [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)] [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal); Milatovic, Dejan; Aschner, Michael [Department of Pediatrics, Vanderbilt University Medical Center, Nashville, TN 37232 (United States)] [Department of Pediatrics, Vanderbilt University Medical Center, Nashville, TN 37232 (United States); Batoreu, M. Camila [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)] [I-Med.UL, Department of Toxicology and Food Sciences, Faculty of Pharmacy, University of Lisbon, Lisbon (Portugal)

    2012-02-01T23:59:59.000Z

    Chronic, excessive exposure to manganese (Mn) may induce neurotoxicity and cause an irreversible brain disease, referred to as manganism. Efficacious therapies for the treatment of Mn are lacking, mandating the development of new interventions. The purpose of the present study was to investigate the efficacy of ebselen (Ebs) and para-aminosalicylic acid (PAS) in attenuating the neurotoxic effects of Mn in an in vivo rat model. Exposure biomarkers, inflammatory and oxidative stress biomarkers, as well as behavioral parameters were evaluated. Co-treatment with Mn plus Ebs or Mn plus PAS caused a significant decrease in blood and brain Mn concentrations (compared to rats treated with Mn alone), concomitant with reduced brain E{sub 2} prostaglandin (PGE{sub 2}) and enhanced brain glutathione (GSH) levels, decreased serum prolactin (PRL) levels, and increased ambulation and rearing activities. Taken together, these results establish that both PAS and Ebs are efficacious in reducing Mn body burden, neuroinflammation, oxidative stress and locomotor activity impairments in a rat model of Mn-induced toxicity. -- Highlights: ? The manuscript is unique in its approach to the neurotoxicity of Mn. ? The manuscript incorporates molecular, cellular and functional (behavioral) analyses. ? Both PAS and Ebs are effective in restoring Mn behavioral function. ? Both PAS and Ebs are effective in reducing Mn-induced oxidative stress. ? Both PAS and Ebs led to a decrease in Mn-induced neuro-inflammation.

  15. Electron spin resonance investigation of Mn^{2+} ions and their dynamics in manganese doped SrTiO_3

    E-Print Network [OSTI]

    V. V. Laguta; I. V. Kondakova; I. P. Bykov; M. D. Glinchuk; P. M. Vilarinho; A. Tkach; L. Jastrabik

    2007-02-28T23:59:59.000Z

    Using electron spin resonance, lattice position and dynamic properties of Mn2+ ions were studied in 0.5 and 2 % manganese doped SrTiO3 ceramics prepared by conventional mixed oxide method. The measurements showed that Mn2+ ions substitute preferably up to 97 % for Sr if the ceramics is prepared with a deficit of Sr ions. Motional narrowing of the Mn2+ ESR spectrum was observed when temperature increases from 120 K to 240-250 K that was explained as a manifestation of off-center position of this ion at the Sr site. From the analysis of the ESR spectra the activation energy Ea = 86 mV and frequency factor 1/?0 ? (2-10)x10^(-14) 1/s for jumping of the impurity between symmetrical off-center positions were determined. Both values are in agreement with those derived previously from dielectric relaxation. This proves the origin of dielectric anomalies in SrTiO3:Mn as those produced by the reorientation dynamics of Mn2+ dipoles.

  16. The bipyridyl herbicide paraquat-induced toxicity in human neuroblastoma SH-SY5Y cells: relevance to dopaminergic pathogenesis

    E-Print Network [OSTI]

    Yang, Wonsuk

    2006-10-30T23:59:59.000Z

    depends on the enzymes superoxide dismutase (SOD), glutathione peroxidase (GPX), and glutathione reductase (GR) together with glutathione and a sufficiently reduced redox state of NAD(P)H to drive the reduction of glutathione and consequently...

  17. Hydrothermal Synthesis of Pure r-Phase Manganese(II) Sulfide without the Use of Organic Reagents

    SciTech Connect (OSTI)

    Michel, F.M.; Schoonen, M.A.A.; Zhang, X.V.; Martin, S.T.; Parise, J.B. (SBU); (Harvard)

    2008-06-18T23:59:59.000Z

    Recent studies exploring the role of metal sulfides as (photo)catalysts in prebiotic synthesis reactions provide the impetus for finding carbon-free synthesis methods for metal sulfides. The decomposition of organosulfur and organometallic precursor compounds is often the protocol for synthesizing bulk metal chalcogenides, such as manganese sulfide (MnS). Here we report a hydrothermal synthesis method for the formation of MnS in which a MnCl{sub 2} solution is injected into a preheated sulfide solution. By varying the temperature of injection and subsequent aging time, we can control the specific crystal phase of the product. Three MnS polymorphs are known, and two of these, {alpha}-MnS and {gamma}-MnS, form as pure phases in aqueous systems. The initial precipitate formed upon mixing of aqueous solutions of Mn{sup 2+} and S{sup 2-} at ambient temperature is nanocrystalline and is composed of a mixture of {gamma}-MnS (wurtzite structure) and {beta}-MnS (zinc blende structure). {beta}-MnS has not previously been identified as forming under aqueous conditions. The initial binary-phase precipitate can be transformed to pure, highly crystalline {gamma}-MnS by aging at temperatures as low as 150 C within 3 days. Aging to yield pure {alpha}-MnS requires temperatures in excess of 200 C for 3 days. Characterization of the products was performed using powder X-ray diffraction, total scattering and pair distribution function analysis, dynamic light scattering, and transmission and scanning electron microscopy. Chemical analyses were performed using colorimetric techniques.

  18. Effects of iron and manganese in culture solution on their concentrations in roots and shoots of rice plants (Oryza sativa L.) grown under anaerobic conditions 

    E-Print Network [OSTI]

    Bacha, Richard E

    1976-01-01T23:59:59.000Z

    of higher oxides of Nn, and the residual Nn, is a minor constituent of soil minerals (Gotoh and Patrick, 1974). Soil Solution Iron and Manganese Ponnamperuma (1964) reported that the influence of pH on the solubility of Fe is particularly important... vary according to factors such as weathering of minerals, mineralization of organic matter, pH, and redox potential. Mann and 0uastel (1946) showed that Mn is biologically reduced in soils. Mann and 0uastei (1946), and 0uastel et al. , (1948...

  19. Homogeneity testing and quantitative analysis of manganese (Mn) in vitrified Mn-doped glasses by laser-induced breakdown spectroscopy (LIBS)

    SciTech Connect (OSTI)

    Unnikrishnan, V. K.; Nayak, Rajesh; Kartha, V. B.; Santhosh, C., E-mail: santhosh.cls@manipal.edu, E-mail: unnikrishnan.vk@manipal.edu [Department of Atomic and Molecular Physics, Manipal University, Manipal (India); Sonavane, M. S. [Nuclear Recycle Board, Bhabha Atomic Research Centre, Mumbai (India); Yeotikar, R. G. [Process Development Division, Bhabha Atomic Research Centre, Mumbai (India); Shah, M. L.; Gupta, G. P.; Suri, B. M. [Laser and Plasma Technology Division, Bhabha Atomic Research Centre, Mumbai (India)

    2014-09-15T23:59:59.000Z

    Laser-induced breakdown spectroscopy (LIBS), an atomic emission spectroscopy method, has rapidly grown as one of the best elemental analysis techniques over the past two decades. Homogeneity testing and quantitative analysis of manganese (Mn) in manganese-doped glasses have been carried out using an optimized LIBS system employing a nanosecond ultraviolet Nd:YAG laser as the source of excitation. The glass samples have been prepared using conventional vitrification methods. The laser pulse irradiance on the surface of the glass samples placed in air at atmospheric pressure was about 1.7×10{sup 9} W/cm{sup 2}. The spatially integrated plasma emission was collected and imaged on to the spectrograph slit using an optical-fiber-based collection system. Homogeneity was checked by recording LIBS spectra from different sites on the sample surface and analyzing the elemental emission intensities for concentration determination. Validation of the observed LIBS results was done by comparison with scanning electron microscope- energy dispersive X-ray spectroscopy (SEM-EDX) surface elemental mapping. The analytical performance of the LIBS system has been evaluated through the correlation of the LIBS determined concentrations of Mn with its certified values. The results are found to be in very good agreement with the certified concentrations.

  20. Manganese and Ceria Sorbents for High Temperature Sulfur Removal from Biomass-Derived Syngas -- The Impact of Steam on Capacity and Sorption Mode

    SciTech Connect (OSTI)

    Cheah, S.; Parent, Y. O.; Jablonski, W. S.; Vinzant, T.; Olstad, J. L.

    2012-07-01T23:59:59.000Z

    Syngas derived from biomass and coal gasification for fuel synthesis or electricity generation contains sulfur species that are detrimental to downstream catalysts or turbine operation. Sulfur removal in high temperature, high steam conditions has been known to be challenging, but experimental reports on methods to tackle the problem are not often reported. We have developed sorbents that can remove hydrogen sulfide from syngas at high temperature (700 C), both in dry and high steam conditions. The syngas composition chosen for our experiments is derived from statistical analysis of the gasification products of wood under a large variety of conditions. The two sorbents, Cu-ceria and manganese-based, were tested in a variety of conditions. In syngas containing steam, the capacity of the sorbents is much lower, and the impact of the sorbent in lowering H{sub 2}S levels is only evident in low space velocities. Spectroscopic characterization and thermodynamic consideration of the experimental results suggest that in syngas containing 45% steam, the removal of H{sub 2}S is primarily via surface chemisorptions. For the Cu-ceria sorbent, analysis of the amount of H{sub 2}S retained by the sorbent in dry syngas suggests both copper and ceria play a role in H{sub 2}S removal. For the manganese-based sorbent, in dry conditions, there is a solid state transformation of the sorbent, primarily into the sulfide form.

  1. Chemistry and Biology of Deoxynyboquinone, a Potent Inducer of Cancer Cell Death

    E-Print Network [OSTI]

    Hergenrother, Paul J.

    of hydrogen peroxide in activating pro-growth pathways3-6 is consistent with evidence that suggests increased we describe a facile synthetic route to this anthraquinone, and we use this material to determine of the endogenous antioxidant system, superoxide dismutase converts superoxide radicals into less reactive hydrogen

  2. Advanced Recombinant Manganese Peroxidase for Biosynthesis of Lignin Bioproducts, Phase I Final Report, STTR Grant #: DE-SC0007503.

    SciTech Connect (OSTI)

    Beatty, Christopher; Kitner, Joshua; Lajoie, Curtis; McClain, Sean; Potochnik, Steve

    2012-12-13T23:59:59.000Z

    The core purpose of this Phase I STTR was to evaluate the feasibility of a new method of producing a recombinant version of manganese peroxidase (MnP) enzyme. MnP is a potentially valuable enzyme for producing high value lignin products and also for industrial de-coloring operations such as biobleaching of pulp and color removal from textile dye effluents. This lignin-modifying enzyme is produced in small amounts by the native host, a white rot fungus. Previous work by Oregon State University developed a secreted recombinant version of the enzyme in the yeast Pichia pastoris. Unfortunately, the expression is barely moderate and the enzyme is heavily glycosylated, which inhibits purification. In this work, the gene for the enzyme is given a tag which targets production of the enzyme to the peroxisome. This is a promising approach since this location is also where heme and hydrogen peroxide are sequestered, which are both necessary cofactors for MnP. More than ten recombinant strains were constructed, verified, and expressed in the Pichia system. Constitutive (GAP) and methanol-induced promoters (AOX) were tried for peroxisomal targeted, cytosolic, and secreted versions of MnP. Only the secreted strains showed activity. The amount of expression was not significantly changed. The degree of glycosylation was lessened using the AOX (methanol) promotoer, but the resulting enzyme was still not able to be purified using immobilized metal affinity chromatography. Additional work beyond the scope of the defined Phase I project was undertaken to construct, verify, and express Pichia strains that mutated the MnP glycosylation sites to inhibit this process. These strains did not show significant activity. The cause is not known, but it is possible that these sites are important to the structure of the enzyme. Also beyond the scope proposed for our Phase I STTR, the team collaborated with AbSci, a startup with a new E. coli based expression system focused on the production of antibodies and enzymes containing disulfide bonds and requiring folding/post-translational modification. With only limited time remaining in the Phase I schedule, a single construct was made to produce MnP with this system. The enzyme was produced in the soluble fraction of the cell lysate, but no activity was measured. MnP from the existing recombinant source was used to act on lignin. The lignin was from a Kraft process and had a molecular weight of about 10,000 Da. Using 1000 Da dialysis membranes and UV-visible spectroscopy, no modification of either lignin was evident in the dialysate or the retentate. Assays using 2,6 dimethoxy phenol (DMP) as a substrate showed consistent activity throughout the project. In summary, these results fell far short of our expectations. A Phase II proposal was not submitted. Possible reasons for the failure of peroxisomal targeting include destruction by native hydrogen peroxide, native proteases, or unforeseen causes. The AbSci system was only lighted tested and further work may yield a strain with active enzyme. The lack of evidence for lignin modification may be due to the techniques employed. NMR or GC-MS studies may reveal evidence of modification.

  3. Manganese peroxidase mRNA and enzyme activity levels during bioremediation of polycyclic aromatic hydrocarbon-contaminated soil with Phanerochaete chrysosporium

    SciTech Connect (OSTI)

    Bogan, B.W. [Univ. of Wisconsin, Madison, WI (United States); Schoenike, B.; Lamar, R.T.; Cullen, D. [Forest Service Forest Products Lab., Madison, WI (United States)

    1996-07-01T23:59:59.000Z

    mRNA extraction from soil and quantitation by competitive reverse transcription-PCR were combined to study the expression of three manganese peroxidase (MnP) genes during removal of polycyclic aromatic hydrocarbons from cultures of Phanerochaete chrysosporium grown in presterilized soil. Periods of high mnp transcript levels and extractable MnP enzyme activity were temporally correlated, although separated by a short (1- to 2-day) lag period. This time frame also coincided with maximal rates of fluorene oxidation and chrysene disappearance in soil cultures, supporting the hypothesis that high ionization potential polycyclic aromatic hydrocarbons are oxidized in soil via MnP-dependent mechanisms. The patterns of transcript abundance over time in soil-grown P. chrysosporium were similar for all three of the mnp mRNAs studied, indicating that transcription of this gene family may be coordinately regulated under these growth conditions. 47 refs., 6 figs., 1 tab.

  4. A Highly Reactive Mononuclear Non-Heme Manganese(IV)?Oxo Complex That Can Activate the Strong C?H Bonds of Alkanes

    SciTech Connect (OSTI)

    Wu, Xiujuan; Seo, Mi Sook; Davis, Katherine M.; Lee, Yong-Min; Chen, Junying; Cho, Kyung-Bin; Pushkar, Yulia N.; Nam, Wonwoo (Ewha); (Purdue)

    2012-03-15T23:59:59.000Z

    A mononuclear non-heme manganese(IV)-oxo complex has been synthesized and characterized using various spectroscopic methods. The Mn(IV)-oxo complex shows high reactivity in oxidation reactions, such as C-H bond activation, oxidations of olefins, alcohols, sulfides, and aromatic compounds, and N-dealkylation. In C-H bond activation, the Mn(IV)-oxo complex can activate C-H bonds as strong as those in cyclohexane. It is proposed that C-H bond activation by the non-heme Mn(IV)-oxo complex does not occur via an oxygen-rebound mechanism. The electrophilic character of the non-heme Mn(IV)-oxo complex is demonstrated by a large negative {rho} value of {approx}4.4 in the oxidation of para-substituted thioanisoles.

  5. Development of Surface Complexation Models of Cr(VI) Adsorption on Soils, Sediments and Model Mixtures of Kaolinite, Montmorillonite, ?-Alumina, Hydrous Manganese and Ferric Oxides and Goethite

    SciTech Connect (OSTI)

    Koretsky, Carla [Western Michigan University] [Western Michigan University

    2013-11-29T23:59:59.000Z

    Hexavalent chromium is a highly toxic contaminant that has been introduced into aquifers and shallow sediments and soils via many anthropogenic activities. Hexavalent chromium contamination is a problem or potential problem in the shallow subsurface at several DOE sites, including Hanford, Idaho National Laboratory, Los Alamos National Laboratory and the Oak Ridge Reservation (DOE, 2008). To accurately quantify the fate and transport of hexavalent chromium at DOE and other contaminated sites, robust geochemical models, capable of correctly predicting changes in chromium chemical form resulting from chemical reactions occurring in subsurface environments are needed. One important chemical reaction that may greatly impact the bioavailability and mobility of hexavalent chromium in the subsurface is chemical binding to the surfaces of particulates, termed adsorption or surface complexation. Quantitative thermodynamic surface complexation models have been derived that can correctly calculate hexavalent chromium adsorption on well-characterized materials over ranges in subsurface conditions, such pH and salinity. However, models have not yet been developed for hexavalent chromium adsorption on many important constituents of natural soils and sediments, such as clay minerals. Furthermore, most of the existing thermodynamic models have been developed for relatively simple, single solid systems and have rarely been tested for the complex mixtures of solids present in real sediments and soils. In this study, the adsorption of hexavalent chromium was measured as a function of pH (3-10), salinity (0.001 to 0.1 M NaNO3), and partial pressure of carbon dioxide(0-5%) on a suite of naturally-occurring solids including goethite (FeOOH), hydrous manganese oxide (MnOOH), hydrous ferric oxide (Fe(OH)3), ?-alumina (Al2O3), kaolinite (Al2Si2O5(OH)4), and montmorillonite (Na3(Al, Mg)2Si4O10(OH)2?nH2O). The results show that all of these materials can bind substantial quantities of hexavalent chromium, especially at low pH. Unexpectedly, experiments with the clay minerals kaolinite and montmorillonite suggest that hexavalent chromium may interact with these solids over much longer periods of time than expected. Furthermore, hexavalent chromium may irreversibly bind to these solids, perhaps because of oxidation-reduction reactions occurring on the surfaces of the clay minerals. More work should be done to investigate and quantify these chemical reactions. Experiments conducted with mixtures of goethite, hydrous manganese oxide, hydrous ferric oxide, ?-alumina, montmorillonite and kaolinite demonstrate that it is possible to correctly predict hexavalent chromium binding in the presence of multiple minerals using thermodynamic models derived for the simpler systems. Further, these models suggest that of the six solid considered in this study, goethite is typically the solid to which most of the hexavalent chromium will bind. Experiments completed with organic-rich and organic-poor natural sediments demonstrate that in organic-rich substrates, organic matter is likely to control uptake of the hexavalent chromium. The models derived and tested in this study for hexavalent chromium binding to ?-alumina, hydrous manganese oxide, goethite, hydrous ferric oxide and clay minerals can be used to better predict changes in hexavalent chromium bioavailability and mobility in contaminated sediments and soils.

  6. Structural And Physical Characterization of Tetranuclear [Mn**II(3)Mn**IV] And [Mn**II(2)Mn**III(2)] Valence-Isomer Manganese Complexes

    SciTech Connect (OSTI)

    Zaleski, C.M.; Weng, T.-C.; Dendrinou-Samara, C.; Alexiou, M.; Kanakaraki, P.; Hsieh, W.-Y.; Kampf, J.; Penner-Hahn, J.E.; Pecoraro, V.L.; Kessissoglou, D.P.

    2009-05-28T23:59:59.000Z

    Two tetranuclear Mn complexes with an average Mn oxidation state of +2.5 have been prepared. These valence isomers have been characterized by a combination of X-ray crystallography, X-ray absorption spectroscopy, and magnetic susceptibility. The Mn{sup II}{sub 3}Mn{sup IV} tetramer has the Mn ions arranged in a distorted tetrahedron, with an S = 6 ground spin state, dominated by ferromagnetic exchange among the manganese ions. The Mn{sup II}{sub 2}Mn{sup III}{sub 2} tetramer also has a distorted tetrahedral arrangement of Mn ions but shows magnetic behavior, suggesting that it is a single-molecule magnet. The X-ray absorption near-edge structure (XANES) spectra for the two complexes are similar, suggesting that, while Mn XANES has sufficient sensitivity to distinguish between trinuclear valence isomers (Alexiou et al. Inorg. Chem. 2003, 42, 2185), similar distinctions are difficult for tetranuclear complexes such as that found in the photosynthetic oxygen-evolving complex.

  7. Manganese 2 -Complexes as Auxiliaries

    E-Print Network [OSTI]

    Lepore, Salvatore D.

    , 15, 4394. (c) Miesch, L.; Rietsch, V.; Welsch, T.; Miesch, M. Tetrahedron Lett. 2008, 49, 5053. (5) (a) Miesch, L.; Welsch, T.; Rietsch, V.; Miesch, M. Chem.sEur. J. 2009, 15, 4394. (b) Miesch, L

  8. Oxime based manganese molecular magnets 

    E-Print Network [OSTI]

    Inglis, Ross

    2010-01-01T23:59:59.000Z

    The synthesis and characterisation of a large family of hexametallic [MnIII 6] Single-Molecule Magnets with general formula [MnIII 6O2(R-sao)6(X)2(L)4-6] (where sao2- = dianion of salicylaldoxime; R = H, Me, Et, Ph; X ...

  9. Measurement of chlorite dismutase activities in perchlorate respiring bacteria

    E-Print Network [OSTI]

    concentration (0.6 mM) to four other perchlorate respiring bacteria (PRB), and to one non-PRB (Pseudomonas aeruginosa). Chlorate-grown cultures of the five PRB strains had CD activities ranging from 25 to 50 U/mg of cell dry weight (DW), while aerobically grown cultures of the PRB had much lower CD activities (0.5­4 U

  10. Oxidative stress in K562 cells differentiation 1 OXIDATIVE STRESS INVOLVEMENT IN CHEMICALLY-INDUCED

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ) and doxorubicin (DOX). When used at subtoxic concentration, these drugs induce the overexpression of erythroid with BA, ACLA and DOX lead to a decrease in reduced glutathione and antioxidant enzymes (glutathione peroxidase, glutathione reductase, CuZn superoxide dismutase (SOD) and catalase). In addition, DOX increased

  11. Development and Characterization of an In-Vitro Tissue Culture Model for Equine Laminitis

    E-Print Network [OSTI]

    Johnson, Margarete

    2014-07-25T23:59:59.000Z

    ) ligand 14 DEFB4 Beta-defensin 2 IFN-? Interferon gamma IL-1? Interleukin-1? IL-6 Interleukin-6 IL-8 Interleukin-8 LBP Lipopolysaccharide binding protein LPS Lipopolysaccharide MMP matrix metalloproteinase SOD2 Superoxide dismutase 2, mitochondrial S100A8...

  12. Abstract An important principle of the func-tional organization of plant cells is the targeting

    E-Print Network [OSTI]

    Zaiane, Osmar R.

    -dimensional gel electrophoresis, tandem mass spectrometry (LC-MS/MS) and de novo sequencing. Another high, plastocyanin-like domains, copper­zinc superoxide dismutases, gamma-thi- oinins, thaumatins, ubiquitins napus Æ Extracellular proteins Æ Proteomics Abbreviations MS mass spectrometry DTT dithiothreitol IPG

  13. Short communication Hydrogen peroxide induce modifications of human extracellular

    E-Print Network [OSTI]

    Schierup, Mikkel Heide

    -specific bond cleavage. Analyses by peptide mapping and mass spectrometry shows that oxidation of Pro112 supports the cleavage of the Pro112­ His113 peptide bond. Substitution of Ala for Pro112 did not inhibit dismutase (EC-SOD) is an extracellu- lar antioxidant that catalyzes the dismutation of superoxide (O2 d

  14. Structural stability and depolarization of manganese-doped (Bi{sub 0.5}Na{sub 0.5}){sub 1?x}Ba{sub x}TiO{sub 3} relaxor ferroelectrics

    SciTech Connect (OSTI)

    Wang, Sheng-Fen [Department of Physics, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China); Tu, Chi-Shun, E-mail: 039611@mail.fju.edu.tw [Department of Physics, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China); Graduate Institute of Applied Science and Engineering, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China); Chang, Ting-Lun; Chen, Pin-Yi [Department of Mechanical Engineering, Ming-Chi University of Technology, New Taipei City 24301, Taiwan (China); Chen, Cheng-Sao [Department of Mechanical Engineering, Hwa-Hsia University of Technology, New Taipei City 23567, Taiwan (China); Hugo Schmidt, V. [Department of Physics, Montana State University, Bozeman, Montana 59717 (United States); Anthoniappen, J. [Graduate Institute of Applied Science and Engineering, Fu Jen Catholic University, New Taipei City 24205, Taiwan (China)

    2014-10-21T23:59:59.000Z

    This work reveals that 0.5?mol. % manganese (Mn) doping in (Bi{sub 0.5}Na{sub 0.5}){sub 1?x}Ba{sub x}TiO{sub 3} (x?=?0 and 0.075) solid solutions can increase structural thermal stability, depolarization temperature (T{sub d}), piezoelectric coefficient (d{sub 33}), and electromechanical coupling factor (k{sub t}). High-resolution X-ray diffraction and transmission electron microscopy reveal coexistence of rhombohedral (R) R3c and tetragonal (T) P4bm phases in (Bi{sub 0.5}Na{sub 0.5}){sub 0.925}Ba{sub 0.075}TiO{sub 3} (BN7.5BT) and 0.5?mol. % Mn-doped BN7.5BT (BN7.5BT-0.5Mn). (Bi{sub 0.5}Na{sub 0.5})TiO{sub 3} (BNT) and BN7.5BT show an R???R?+?T phase transition, which does not occur in 0.5?mol. % Mn-doped BNT (BNT-0.5Mn) and BN7.5BT-0.5Mn. Dielectric permittivity (??) follows the Curie-Weiss equation, ???=?C/(T???T{sub o}), above the Burns temperature (T{sub B}), below which polar nanoregions begin to develop. The direct piezoelectric coefficient (d{sub 33}) and electromechanical coupling factor (k{sub t}) of BN7.5BT-0.5Mn reach 190 pC/N and 47%.

  15. Electrochemical Generation of Superoxide in Room-Temperature Ionic Liquids

    E-Print Network [OSTI]

    Weidner, John W.

    with an inorganic salt.7 They are directly related to more familiar high-temperature molten salts that are used by the reduction of dioxygen in imidizalium chloride-aluminum chloride molten salt. However, the resulting su and chlorides.2,3,6 Room-temperature ionic liquids RTILs are stable mixtures of an organic cation/anion salt

  16. Drinking Water Problems: Iron and Manganese (Spanish) 

    E-Print Network [OSTI]

    Dozier, Monty; McFarland, Mark L.

    2004-02-20T23:59:59.000Z

    tapa- dos y para calentar agua si los rodos de los calenta- dores est?n cubiertos con dep?sitos minerales. Esto aumenta los costos de la energ?a y el agua. El agua contaminada con hierro y manganeso usual- mente contiene bacterias de hierro o manganeso...

  17. Iron and Manganese in Potable Water

    E-Print Network [OSTI]

    Young, Clifford Caudy

    1911-06-01T23:59:59.000Z

    none 22. Hays 469.0 1.0 none 23. Hays .55 24. Peabody 830.0 .5 trace 25. Caldwell 458.0 2.0 trace 26. Lyons 456.0 .1 trace 27. Osborne 377.0 .3 none 28. Herington 608,0 .1 trace 29. Sterling - - _ .1 .036 30. Waverly 546,0 .2 none 31. Clifton 350.... The occurence of a black peaty layer overlying white sand containing iron, the white sand in turn overlying red sand containing 10. oxidize^ iron, is a familiar sight to all engineers who have made excavations. Here the carbon dioxide produced...

  18. Color stable manganese-doped phosphors

    DOE Patents [OSTI]

    Lyons, Robert Joseph; Setlur, Anant Achyut; Deshpande, Anirundha Rajendra; Grigorov, Ljudmil Slavchev

    2014-04-29T23:59:59.000Z

    A lighting apparatus capable of emitting white light includes a semiconductor light source; and a phosphor material radiationally coupled to the light source. The phosphor material includes a color-stable Mn.sup.+4 doped phosphor prepared by a process including providing a phosphor of formula I; A.sub.x[MF.sub.y]:Mn.sup.+4 I and contacting the phosphor in particulate form with a saturated solution of a composition of formula II in aqueous hydrofluoric acid; A.sub.x[MF.sub.y]; II wherein A is Li, Na, K, Rb, Cs, NR.sub.4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [MF.sub.y] ion; and y is 5, 6 or 7. In particular embodiments, M is Si, Ge, Sn, Ti, Zr, or a combination thereof.

  19. Color stable manganese-doped phosphors

    DOE Patents [OSTI]

    Lyons, Robert Joseph (Burnt Hills, NY); Setlur, Anant Achyut (Niskayuna, NY); Deshpande, Anirudha Rajendra (Twinsburg, OH); Grigorov, Ljudmil Slavchev (Sofia, BG)

    2012-08-28T23:59:59.000Z

    A process for preparing color stable Mn.sup.+4 doped phosphors includes providing a phosphor of formula I; A.sub.x[MF.sub.y]:Mn.sup.+4 I and contacting the phosphor in particulate form with a saturated solution of a composition of formula II in aqueous hydrofluoric acid; A.sub.x[MF.sub.y]; II wherein A is Li, Na, K, Rb, Cs, NR.sub.4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [MF.sub.y] ion; and y is 5, 6 or 7. In particular embodiments, M is Si, Ge, Sn, Ti, Zr, or a combination thereof. A lighting apparatus capable of emitting white light includes a semiconductor light source; and a phosphor composition radiationally coupled to the light source, and which includes a color stable Mn.sup.+4 doped phosphor.

  20. Manganese oxide composite electrodes for lithium batteries

    DOE Patents [OSTI]

    Johnson, Christopher S. (Naperville, IL); Kang, Sun-Ho (Naperville, IL); Thackeray, Michael M. (Naperville, IL)

    2009-12-22T23:59:59.000Z

    An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor thereof a lithium metal oxide with the formula xLi.sub.2MnO.sub.3.(1-x)LiMn.sub.2-yM.sub.yO.sub.4 for 0.5

  1. Manganese oxide composite electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Li, Naichao (Croton on Hudson, NY)

    2007-12-04T23:59:59.000Z

    An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor of a lithium metal oxide with the formula xLi.sub.2MnO.sub.3.(1-x)LiMn.sub.2-yM.sub.yO.sub.4 for 0

  2. Drinking Water Problems: Iron and Manganese (Spanish)

    E-Print Network [OSTI]

    Dozier, Monty; McFarland, Mark L.

    2004-02-20T23:59:59.000Z

    . Estas bacterias se alimentan de los minerales que hay en el agua. No causan problemas de salud, pero s? forman una baba rojiza-caf? (hierro) o caf?- negra (manganeso) en los tanques de los inodoros y pueden tapar los sistemas de agua. ?C?mo entran el.... Las part?culas se forman debido a que el ox?geno en el sistema de plomer?a est? oxidando y precipitando el hierro y el manganeso. Si el agua est? clara cuando sale del grifo, pero las part?culas se forman y se acumulan despu?s de que el agua ha estado...

  3. Manganese containing layer for magnetic recording media

    DOE Patents [OSTI]

    Lambeth, David N. (Pittsburgh, PA); Lee, Li-Lien (Santa Clara, CA); Laughlin, David E. (Pittsburgh, PA)

    1999-01-01T23:59:59.000Z

    The present invention provides for a magnetic recording media incorporating Mn-containing layers between a substrate and a magnetic layer to provide media having increased coercivity and lower noise. The Mn-containing layer can be incorporated in a rotating, translating or stationary recording media to operate in conjunction with magnetic transducing heads for recording and reading of magnetic data, as well as other applications. The magnetic recording medium of the invention preferably includes a Co or Co alloy film magnetic layer, and Mn-containing layer, preferably comprised of VMn, TiMn, MnZn, CrMnMo, CrMnW, CrMnV, and CrMnTi, and most preferably a CrMn alloy, disposed between the substrate and the magnetic layer to promote an epitaxial crystalline structure in the magnetic layer. The medium can further include seed layers, preferably polycrystalline MgO for longitudinal media, underlayers, and intermediate layers. Underlayers and intermediate layers are comprised of materials having either an A2 structure or a B2-ordered crystalline structure disposed between the seed layer and the magnetic layer. Materials having an A2 structure are preferably Cr or Cr alloys, such as CrV, CrMo, CrW and CrTi. Materials having a B2-ordered structure having a lattice constant that is substantially comparable to that of Cr, such as those preferably selected from the group consisting of NiAl, AILCo, FeAl, FeTi, CoFe, CoTi, CoHf, CoZr, NiTi, CuBe, CuZn, A-LMn, AlRe, AgMg, and Al.sub.2 FeMn.sub.2, and is most preferably FeAl or NiAl.

  4. Structural Determination of Marine Bacteriogenic Manganese Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our Instagram Secretary900SteepStrengthening northernDetermination of Marine

  5. Developing a DNA vaccine to protect against brucellosis

    E-Print Network [OSTI]

    Owen, David Matthew

    2013-02-22T23:59:59.000Z

    Predicted size Function Upre ulation GenBank ID AapJ 37. 1 kDa Amino acid heat shock AE009560 binding gi17983192 acid pH Asp24 20. 4 kDa Calcium AF014823 binding gi2353000 CuZn SOD 18. 2 kDa Superoxide oxidative stress AE009694 dismutase gil7984757... DnaK 68. 7 kDa Chaperone heat shock, acid AE009633 pFI gi17984056 Mn SOD 22. 5 kDa Superoxide heat shock AE009560 dismutase gi17983362 AapJ, CuZn SOD, and DnaK have been shown to be immunogenic in sheep '. After making the decision to test...

  6. Manganese sulfide formation via concomitant microbial manganese oxide and thiosulfate reduction.

    SciTech Connect (OSTI)

    Lee, Ji-Hoon; Kennedy, David W.; Dohnalkova, Alice; Moore, Dean A.; Nachimuthu, Ponnusamy; Reed, Samantha B.; Fredrickson, Jim K.

    2011-12-27T23:59:59.000Z

    The dissimilatory metal-reducing bacterium, Shewanella oneidensis MR-1 produced ?-MnS (rambergite) nanoparticles under the concurrent reduction of synthetic MnO2 and thiosulfate coupled to H2 oxidation. Using two MR-1 mutants defective in outer membrane c-type cytochromes (?mtrC/?omcA and ?mtrC/?omcA/?mtrF) to eliminate the direct reduction pathway for solid electron acceptors, it was determined that respiratory reduction of MnO2 was dominant relative to chemical reduction by biogenic sulfide generated from bacterial thiosulfate reduction. Although bicarbonate was excluded from the medium, incubations of MR-1 using lactate as the sole electron donor produced MnCO3 (rhodochrosite) as well as MnS in nearly equivalent amounts as estimated by micro X-ray diffraction (micro-XRD) analysis. It was concluded that carbonate released from lactate metabolism promoted MnCO3 formation and that Mn(II) mineralogy was strongly affected by carbonate ions even in the presence of abundant sulfide and weakly alkaline conditions that favor the precipitation of MnS. Formation of the biogenic MnS, as determined by a combination of micro-XRD, transmission electron microscopy, energy dispersive X-ray spectroscopy, and selected area electron diffraction analyses was consistent with equilibrium speciation modeling predictions. Although biogenic MnS likely only forms and is stable over a relatively narrow range of conditions, it may be a significant sink for Mn in anoxic marine basins and terrestrial subsurface sediments where Mn and sulfur compounds are undergoing concurrent reduction.

  7. Analysis of genes regulated by the peroxide response regulator PerR in Borrelia burgdorferi using real-time RT-PCR

    E-Print Network [OSTI]

    Swingle, Kristen Lynn

    2002-01-01T23:59:59.000Z

    upstream of sodA in B. burgdorjeri. However, sodA is co- transcribed with secA in B. burgdarferi (25), and upstream of secA there is a putative PerR binding domain with homology at 10 of the 19 bases (Fig. I). For this reason, we want to determine... of the secA gene, which is co-transcribed with sodA (25). We have observed an increase in superoxide dismutase activity in JS167 compared to the Lab parental strain (Fig. 8), implying that PerR regulates the expression of sodA or regulates the expression...

  8. Assessing Exposures to Particulate Matter and Manganese in Welding Fumes

    E-Print Network [OSTI]

    LIU, SA

    2010-01-01T23:59:59.000Z

    Ventilation                 Natural                 Mechanical                 Local on Cancer LEV: local-exhaust ventilation LOD: limit of42% lower with local exhaust ventilation, was higher among

  9. Growth of Manganese Oxide Nanostructures Alters the Layout of

    E-Print Network [OSTI]

    under natural conditions can modify the layout of adhesion on mineral surfaces. Using force influences contaminant immobilization and bacterial attachment. 1. Introduction The immobilization of metal ions, colloidal particles, and bacterial cells by lacustrine, riparian, and hypogeal minerals can

  10. Transformation kinetics and pathways of tetracycline antibiotics with manganese oxide

    E-Print Network [OSTI]

    Huang, Ching-Hua

    Oxidation Emerging contaminants Pharmaceuticals a b s t r a c t Tetracycline antibiotics including(IV) oxide/hydroxide colloidal particles or coatings on other minerals in soils and sediments, plays

  11. Assessing Exposures to Particulate Matter and Manganese in Welding Fumes

    E-Print Network [OSTI]

    LIU, SA

    2010-01-01T23:59:59.000Z

    465.   Sapp ME.  A History of Welding: from Hepheastus to whistoryfolder/welding/index.html.   Saric M, Markicevic, be retrieved from American Welding Society publications. The

  12. 1. Lithographically Patterned Gold/Manganese Dioxide Core/Shell...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    follow from these factors. 3. HIERARCHICAL ARCHITECTURES FOR ENERGY STORAGE DEVICES USING VIRAL NANOTEMPLATES Konstantinos Gerasopoulos*, Markus Gnerlich*, Sangwook...

  13. Assessing Exposures to Particulate Matter and Manganese in Welding Fumes

    E-Print Network [OSTI]

    LIU, SA

    2010-01-01T23:59:59.000Z

    less hazardous compared to MIG welding, these areas as wellareas where high concentrations occurred; 3) although resistance welding is considered less hazardoushazardous welding operations such as resistance welding should also be effectively controlled. Those who work in areas

  14. Assessing Exposures to Particulate Matter and Manganese in Welding Fumes

    E-Print Network [OSTI]

    LIU, SA

    2010-01-01T23:59:59.000Z

    titanium and zinc; non-metal constituents such as fluorides and silica; and gases such as carbon monoxide and carbon dioxide, nitrogen

  15. A ROLE FOR MANGANESE IN OXYGEN EVOLUTION IN PHOTOSYNTHESIS

    E-Print Network [OSTI]

    Sauer, Kenneth

    2012-01-01T23:59:59.000Z

    synthesis, Topics jn Photosynthesis, vol. 2, J. Barber,and J. R. Benemann, in Photosynthesis in Relation to ModelProcesses of Photosynthesis, Topics in Photosynthesis, vol.

  16. Iron, zinc, and manganese distribution in mature soybean seeds

    E-Print Network [OSTI]

    Cvitanich, Cristina; Przyby?owicz, Wojciech J.; Mesjasz-Przyby?owicz, Jolanta; Blair, Matthew W.; Jensen, Erik Ø.; Stougaard, Jens

    2009-01-01T23:59:59.000Z

    Augustyniak M, et al. (2005) Micro-PIXE in ecophysiology. Xsensitive, non-destructive micro-PIXE (Particle Induced X-ICP-AES) in axial mode. Micro-PIXE analysis. Both dry and

  17. A ROLE FOR MANGANESE IN OXYGEN EVOLUTION IN PHOTOSYNTHESIS

    E-Print Network [OSTI]

    Sauer, Kenneth

    2012-01-01T23:59:59.000Z

    and s. B. Marks, in Bioenergetics of Membranes, L. Packer,Current Topics in Bioenergetics, vol. 1, D. R. Sanadi, Ed. ,

  18. Assessing Exposures to Particulate Matter and Manganese in Welding Fumes

    E-Print Network [OSTI]

    LIU, SA

    2010-01-01T23:59:59.000Z

    helmets.   American Industrial Hygiene Association Journal welding.   American Industrial Hygiene Association Journal electrodes.  American  Industrial Hygiene Association 

  19. Manganese-stabilized austenitic stainless steels for fusion applications

    DOE Patents [OSTI]

    Klueh, Ronald L. (Knoxville, TN); Maziasz, Philip J. (Oak Ridge, TN)

    1990-01-01T23:59:59.000Z

    An austenitic stainless steel that is comprised of Fe, Cr, Mn, C but no Ni or Nb and minimum N. To enhance strength and fabricability minor alloying additions of Ti, W, V, B and P are made. The resulting alloy is one that can be used in fusion reactor environments because the half-lives of the elements are sufficiently short to allow for handling and disposal.

  20. Studies on Lithium Manganese Rich MNC Composite Cathodes

    Broader source: Energy.gov (indexed) [DOE]

    America Inc. 3 Presentation name Project Objectives - Relevance Undertake advanced materials research in the area of high energy (capacity) electrode materials for lithium-ion...

  1. MANGANESE--1999 49.1 By Thomas S. Jones

    E-Print Network [OSTI]

    Torgersen, Christian

    by virtue of its sulfur-fixing, deoxidizing, and alloying properties. Steelmaking, including its ironmaking

  2. MANGANESE--2000 50.1 By Thomas S. Jones

    E-Print Network [OSTI]

    Torgersen, Christian

    by virtue of its sulfur-fixing, deoxidizing, and alloying properties. Steelmaking, including its ironmaking

  3. Complex deoxidation equilibria of molten steels by titanium and manganese

    SciTech Connect (OSTI)

    Morita, K.; Morioka, Y.; Tsukihashi, F.; Sano, N. [Univ. of Tokyo (Japan). Dept. of Metallurgy

    1996-12-31T23:59:59.000Z

    The relationship between the equilibrium composition of Fe-Ti-Mn melts and that of coexisting oxides has been investigated by employing a cold crucible melting at 1,873 K. Using metal compositions and the Gibbs energies of formation of component oxides, iso-activity contours of FeO and MnO for the FeO-TiO{sub 1.5}-MnO melts at 1,873 K were evaluated. The optimal conditions for practical deoxidation processes with Ti-Mn alloys are discussed.

  4. Manganese-oxidizing photosynthesis before the rise of cyanobacteria

    E-Print Network [OSTI]

    Thomas, Katherine

    The emergence of oxygen-producing (oxygenic) photosynthesis fundamentally transformed our planet; however, the processes that led to the evolution of biological water splitting have remained largely unknown. To illuminate ...

  5. Manganese Based Oxidative Technologies For Water/Wastewater Treatment

    E-Print Network [OSTI]

    Desai, Ishan

    2013-08-27T23:59:59.000Z

    radical production within catalytic ozonation systems. Thus their catalyst effectiveness was determined by measuring R_(ct), ozone exposure, hydroxyl radical production, and ozone decomposition. The effect of catalyst type, catalyst dosage, pre...

  6. Synthesis of manganese spinel nanoparticles at room temperature by coprecipitation

    SciTech Connect (OSTI)

    Giovannelli, F., E-mail: fabien.giovannelli@univ-tours.fr [GREMAN, UMR 7347 CNRS-CEA, Universite Francois Rabelais, 15 rue de la chocolaterie, 41000 BLOIS (France); Autret-Lambert, C.; Mathieu, C.; Chartier, T.; Delorme, F. [GREMAN, UMR 7347 CNRS-CEA, Universite Francois Rabelais, 15 rue de la chocolaterie, 41000 BLOIS (France); Seron, A [BRGM, 3 Avenue Claude Guillemin, BP 36009, 45060 ORLEANS Cedex 2 (France)

    2012-08-15T23:59:59.000Z

    This paper is focused on a new route to synthesize Mn{sub 3}O{sub 4} nanoparticles by alkalisation by sodium hydroxide on a manganeous solution at room temperature. The precipitates obtained at different pH values have been characterized by XRD and TEM. Since the first addition of sodium hydroxide, a white Mn(OH){sub 2} precipitate appears. At pH=7, {gamma}-MnOOH phase is predominant with needle like shaped particles. At pH=10, hausmanite nanoparticles, which exhibits well defined cubic shape in the range 50-120 nm are obtained. This new precipitation route is a fast and easy environmentally friendly process to obtain well crystallized hausmanite nanoparticles. - Graphical abstract: TEM image showing Mn{sub 3}O{sub 4} particles after a precipitation at pH=10. Highlights: Black-Right-Pointing-Pointer A new route to synthesize Mn{sub 3}O{sub 4} nanoparticles has been demonstrated. Black-Right-Pointing-Pointer Synthesis has been performed by precipitation at room temperature. Black-Right-Pointing-Pointer The size of the Mn{sub 3}O{sub 4} nanoparticles is between 50 and 120 nm.

  7. Examining Hysteresis in Lithium- and Manganese-Rich Composite...

    Broader source: Energy.gov (indexed) [DOE]

    with Li 2 CO 3 Cell configurations - Lithium half cells - 1.2 M LiPF 6 in ECEMC (3:7 wt), no additives in 2032 coin cell - All cycling data at least in duplicate at...

  8. REGULAR ARTICLE Interaction of nickel and manganese in accumulation

    E-Print Network [OSTI]

    Sparks, Donald L.

    of Maryland, College Park, USA E. F. Erbe Electron Microscopy Unit, Soybean Genomics and Improvement

  9. arsenic manganese uranium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Mn) is enriched in surface soils at the (more) Herndon, Elizabeth 2012-01-01 56 Depleted Uranium Technical Brief Environmental Sciences and Ecology Websites Summary: and...

  10. Addressing the Voltage Fade Issue with Lithium-Manganese-Rich...

    Broader source: Energy.gov (indexed) [DOE]

    electrode structures at the Advanced Photon Source (APS) by X-ray diffraction, X-ray absorption and pair-distribution-function (pdf) analyses. Measure entropy changes...

  11. Structural Sequestration of Uranium in Bacteriogenic Manganese Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our Instagram Secretary900SteepStrengtheningFunctions | Stanford

  12. Comparing Well-Defined Manganese, Iron, Cobalt, and Nickel Ketone

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms AboutRESEARCHHydrosilylation Catalysts Comparing Well-Defined

  13. A highly active manganese precatalyst for the hydrosilylation of ketones

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >InternshipDepartmentNeutrino-Induced Charged-CurrentN NA goldenand

  14. Thermodynamic Investigations of Lithium- and Manganese-Rich Transition

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreakingMayDepartmentTest for PumpingThe FactsSynthesis of Lignocellulosic2013Metal

  15. Examining Hysteresis in Lithium- and Manganese-Rich Composite Cathode

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:RevisedAdvisoryStandardGeneration |10Examination

  16. Studies on Lithium Manganese Rich MNC Composite Cathodes | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideoStrategic Safety Goals Strategic Safety|Research with EM LaboratoryEnergy

  17. Age-related comparison of superoxide production by canine neutrophilic polymorphonuclear leukocytes

    E-Print Network [OSTI]

    Hanson, Thomas Dale

    1983-01-01T23:59:59.000Z

    LIST OF FIGURES F1gure No. T1tle Page Figure 1. Figure 2. F1gure 3. Figure 4. Temporal traces of 02 dependent cytochrome C 18 reduction by CE-Con )( st1mulated canine neutro- phils from a selected group of 12 young (0. 5 to 6 years) and 26 aged... (2, 15, 64). Phagocytically stimulated neutro- phils synthes1ze abundant quantities of 02 . In vitro and in viva observations suggest that e1ther 02- and/or H202, or a product of their interaction, is 1nvolved in the microbic1dal event (2, 64...

  18. angiotensin ii-stimulated superoxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the rat brain in response to dietary sodium manipulation and angiotensin (Ang)II infusion. Male Wistar Kyoto rats (n ? 6) were fed normal, high, or low sodium diets for 12 d...

  19. angiotensin ii-mediated superoxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the rat brain in response to dietary sodium manipulation and angiotensin (Ang)II infusion. Male Wistar Kyoto rats (n ? 6) were fed normal, high, or low sodium diets for 12 d...

  20. Mitochondrial Targeted Coenzyme Q, Superoxide, and Fuel Selectivity in Endothelial Cells

    E-Print Network [OSTI]

    Fink, Brian D.; O'Malley, Yunxia; Dake, Brian L.; Ross, Nicholette C.; Prisinzano, Thomas E.; Sivitz, William I.

    2009-01-22T23:59:59.000Z

    on mitochondrial respiration, measured respiration and mitochondrial membrane potential in intact cells, and tested the intriguing hypothesis that mitoquinone might impart fuel selectivity in intact BAE cells. In mitochondria respiring on differing concentrations...

  1. Functional and morphological alterations in compound transgenic mice overexpreszing Cu/Zn superoxide

    E-Print Network [OSTI]

    Segal, Menahem

    -term potentiation (LTP), which could be rescued by antioxidants (Gahtan et al., 1998). In humans, cortical neurons- ronal death, which could be prevented by antioxidants (Busciglio & Yankner, 1995). The second chromosome with familial AD, and the protein is involved in the amyloid-b (Ab) peptides deposits within senile plaques

  2. Endonuclease IV of Escherichia coli is induced by paraquat

    SciTech Connect (OSTI)

    Chan, E.; Weiss, B.

    1987-05-01T23:59:59.000Z

    The addition of paraquat (methyl viologen) to a growing culture of Escherichia coli K-12 led within 1 hr to a 10- to 20-fold increase in the level of endonuclease IV, a DNase for apurinic/apyrimidinic sites. The induction was blocked by chloramphenicol. Increases of 3-fold or more were also seen with plumbagin, menadione, and phenazine methosulfate. H/sub 2/O/sub 2/ produced no more than a 2-fold increase in endonuclease IV activity. The following agents had no significant effect: streptonigrin, nitrofurantoin, tert-butyl hydroperoxide, ..gamma.. rays, 260-nm UV radiation, methyl methanesulfonate, mitomycin C, and ascorbate. Paraquat, plumbagin, menadione, and phenazine methosulfate are known to generate superoxide radical anions via redox cycling in vivo. A mutant lacking superoxide dismutase was unusually sensitive to induction by paraquat. In addition, endonuclease IV could be induced by merely growing the mutant in pure O/sub 2/. The levels of endonuclease IV in uninduced or paraquat-treated cells were unaffected by mutations of oxyR, a H/sub 2/O/sub 2/-inducible gene that governs an oxidative-stress regulon. The results indicate that endonuclease IV is an inducible DNA-repair enzyme and that its induction can be mediated via the production of superoxide radicals.

  3. Mitochondrial fragmentation and superoxide anion production in coronary endothelial cells from a mouse model of type 1 diabetes

    E-Print Network [OSTI]

    Makino, A.; Scott, B. T.; Dillmann, W. H.

    2010-01-01T23:59:59.000Z

    muscle: effects of type 2 diabetes, obesity, weight loss,alpha and interleukin-6. Diabetes 54:2685–2693 28. Bach D,endothelial dysfunction in diabetes mellitus. Circ Res 88:

  4. Evidence That the [beta] Subunit of Chlamydia trachomatis Ribonucleotide Reductase Is Active with the Manganese Ion of Its Manganese(IV)/Iron(III) Cofactor in Site 1

    SciTech Connect (OSTI)

    Dassama, Laura M.K.; Boal, Amie K.; Krebs, Carsten; Rosenzweig, Amy C.; Bollinger, Jr., J. Martin (NWU); (Penn)

    2014-10-02T23:59:59.000Z

    The reaction of a class I ribonucleotide reductase (RNR) begins when a cofactor in the {beta} subunit oxidizes a cysteine residue {approx}35 {angstrom} away in the {alpha} subunit, generating a thiyl radical. In the class Ic enzyme from Chlamydia trachomatis (Ct), the cysteine oxidant is the Mn{sup IV} ion of a Mn{sup IV}/Fe{sup III} cluster, which assembles in a reaction between O{sub 2} and the Mn{sup II}/Fe{sup II} complex of {beta}. The heterodinuclear nature of the cofactor raises the question of which site, 1 or 2, contains the Mn{sup IV} ion. Because site 1 is closer to the conserved location of the cysteine-oxidizing tyrosyl radical of class Ia and Ib RNRs, we suggested that the Mn{sup IV} ion most likely resides in this site (i.e., {sup 1}Mn{sup IV}/{sup 2}Fe{sup III}), but a subsequent computational study favored its occupation of site 2 ({sup 1}Fe{sup III}/{sup 2}Mn{sup IV}). In this work, we have sought to resolve the location of the Mn{sup IV} ion in Ct RNR-{beta} by correlating X-ray crystallographic anomalous scattering intensities with catalytic activity for samples of the protein reconstituted in vitro by two different procedures. In samples containing primarily Mn{sup IV}/Fe{sup III} clusters, Mn preferentially occupies site 1, but some anomalous scattering from site 2 is observed, implying that both {sup 1}Mn{sup II}/{sup 2}Fe{sup II} and {sup 1}Fe{sup II}/{sup 2}Mn{sup II} complexes are competent to react with O{sub 2} to produce the corresponding oxidized states. However, with diminished Mn{sup II} loading in the reconstitution, there is no evidence for Mn occupancy of site 2, and the greater activity of these 'low-Mn' samples on a per-Mn basis implies that the {sup 1}Mn{sup IV}/{sup 2}Fe{sup III}-{beta} is at least the more active of the two oxidized forms and may be the only active form.

  5. Soil tests for copper, iron, manganese, and zinc in histosols. 2. The distributions of soil iron and manganese in sequentially extractable forms

    SciTech Connect (OSTI)

    Mathur, S.P.; Levesque, M.

    1988-02-01T23:59:59.000Z

    The authors identified and quantified the immediately available and the reserve forms of Fe and Mn in 55 cultivated organic solid to assist selection of a reliable soil test for Fe and Mn in such soils. Soil Fe and Mn were sequentially partitioned into (1) H/sub 2/O-soluble, (2) Ca-exchangeable, (3) free-oxide-associated, (4) weakly complexed, (5) strongly complexed, (6) carbonate-associated, and (7) sulfide-associated extractable forms by dissolution in (1) H/sub 2/O, and aqueous solutions of (2) CaCl/sub 2/, (3) CaCl/sub 2/ + hydroquinone, (4) CH/sub 3/COOH; (5) DTPA-TEA, (6) HCl, and (7) KCN, respectively. On an average, 66% of the total Fe was unextractable, 26% strongly complexed, 4% sulfide-associated, 3% in carbonates, 0.5% weakly complexed, 0.4% in association with free oxides, 0.2% H/sub 2/O-soluble, and 0.1% Ca-exchangeable. Of the average total Mn, 57% was unextractable, 18% associated with free oxides, 10% weakly complexed, 6.5% each strongly complexed and Ca-exchangeable, 0.9% in carbonates, 0.4% in sulfide, and 0.5% in H/sub 2/O-soluble forms. Of the average total Zn, 8.7% was in free oxides, 4.5% Ca-exchangeable, and 1.9% in H/sub 2/O-soluble forms. The immediately available forms of Fe in H/sub 2/O-soluble and Ca-exchangeable factions were indicated to be replenishable mainly by the strongly complexed form. The capacity factor for Mn was suggested to be more than one form of soil Mn.

  6. Effects of Macromolecular Crowding on the Structure of a Protein Complex

    SciTech Connect (OSTI)

    Rajapaksha Mudalige, Ajith Rathnaweera [ORNL; Stanley, Christopher B [ORNL; Todd, Brian [ORNL

    2015-01-01T23:59:59.000Z

    Macromolecular crowding can alter the structure and function of biological macromolecules. We used small angle scattering (SAS) to measure the change in size of a protein complex, superoxide dismutase (SOD), induced by macromolecular crowding. Crowding was induced using 400 MW polyethylene glycol (PEG), triethylene glycol (TEG), methyl- -glucoside ( -MG) and trimethylamine N-oxide (TMAO). Parallel small angle neutron scattering (SANS) and small angle x-ray scattering (SAXS) allowed us to unambiguously attribute apparent changes in radius of gyration to changes in the structure of SOD. For a 40% PEG solution, we find that the volume of SOD was reduced by 9%. Considering the osmotic pressure due to PEG, this deformation corresponds to a highly compressible structure. SAXS done in the presence of TEG suggests that for further deformation beyond a 9% decrease in volume the resistance to deformation may increase dramatically.

  7. Nucleation of the isothermal martensitic transformation in iron-nickel-manganese alloys

    E-Print Network [OSTI]

    Pati, Satya Ranjan

    1967-01-01T23:59:59.000Z

    By means of quantitative metallography and electrical resistance measurements, the incubation period (time to form a detectable amount of martensite) and the initial nucleation rate have been determined as a function of ...

  8. Synthesis and Characterization of 14-1-11 Ytterbium Manganese Antimonide Derivatives for Thermoelectric Applications

    E-Print Network [OSTI]

    Star, Kurt

    2013-01-01T23:59:59.000Z

    have made radioisotope thermoelectric generators (RTGs),Mission Radioisotope Thermoelectric Generator (MMRTG) used

  9. Anthracene-Induced Turnover Enhancement in the Manganese Porphyrin-Catalyzed Epoxidation of Olefins

    E-Print Network [OSTI]

    effect, and (c) anthracene is ultimately converted to anthraquinone. The origin of the observed of the catalyst. This reaction, which produces anthraquinone, regenerates the catalytically active monomeric form

  10. Evolution of Nickel-Manganese-Silicon Dominated Phases in Highly Irradiated Reactor Pressure Vessel Steels

    SciTech Connect (OSTI)

    Peter B Wells; Yuan Wu; Tim Milot; G. Robert Odette; Takuya Yamamoto; Brandon Miller; James Cole

    2014-11-01T23:59:59.000Z

    Formation of a high density of Ni-Mn-Si nm-scale precipitates in irradiated reactor pressure vessel steels, both with and without Cu, could lead to severe embrittlement. Models long ago predicted that these precipitates, which are not treated in current embrittlement regulations, would emerge only at high fluence. However, the mechanisms and variables that control Ni-Mn- Si precipitate formation, and their detailed characteristics, have not been well understood. High flux irradiations of six steels with systematic variations in Cu and Ni were carried out at ˜ 295±5°C to high and very high neutron fluences of ˜ 1.3x1020 and 1.1x1021 n/cm2. Atom probe tomography (APT) shows that significant mole fractions of these precipitates form in the Cu bearing steels at ˜ 1.3x1020 n/cm2, while they are only beginning to develop in Cu-free steels. However, large mole fractions, far in excess of those found in previous studies, are observed at 1.1x1021 n/cm2 at all Cu levels. The precipitates diffract, and in one case are compositionally and structurally consistent with the Mn6Ni16Si7 G-phase. At the highest fluence, the large precipitate mole fractions primarily depend on the steel Ni content, rather than Cu, and lead to enormous strength increases up to about 700 MPa. The implications of these results to light water reactor life extension are discussed briefly.

  11. Received 29 Apr 2014 | Accepted 22 Aug 2014 | Published 14 Oct 2014 Manganese hexacyanomanganate open framework

    E-Print Network [OSTI]

    Cui, Yi

    Publishers Limited. All rights reserved. #12;L ithium-ion batteries (LIBs) dominate the energy storage market with that of Li results in lower cell voltages and consequently lower energy densities4. Moreover, the larger size applications of sodium-ion batteries in grid-scale energy storage, portable electronics and electric vehicles

  12. The Effects of Ozone Deposition and Dissolved Organic Matter on Manganese Speciation in the Surface Ocean 

    E-Print Network [OSTI]

    Smyth, Alison Michelle

    2014-07-31T23:59:59.000Z

    Despite the known reactivity of ozone (O_(3)) in water and ozone’s environmental importance in the atmosphere, there are relatively few studies published examining the chemistry of O_(3) in seawater. This study focused on developing a flow injection...

  13. AN X-RAY ABSORPTION SPECTROSCOPY STUDY OF MANGANESE CONTAINING COMPOUNDS AND PHOTOSYNTHETIC SPINACH CHLOROPLASTS

    E-Print Network [OSTI]

    Kirby, Jon Allan

    2012-01-01T23:59:59.000Z

    dictate the usage of ion chambers for the measurement of rmonitoring front r 0 ion chamber is necessary to correct thebe substituted for the rear ion chamber. How- ever, under

  14. Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts

    E-Print Network [OSTI]

    Smieja, Jonathan Mark

    2012-01-01T23:59:59.000Z

    Si surface was exposed to Re(CO) 5 Cl in toluene at elevatedexposed to solution. Those vials were placed in a flask that also contained toluene and

  15. SUPPORTING INFORMATION Growth of Manganese Oxide Nanostructures Alters the Layout of

    E-Print Network [OSTI]

    0 0 0.8 1.5 2.6 log fadh(MnOx) (pN) 2.22 2.15 2.41 2.84 2.67 2.46 2.44 Source Degrees of Freedom Sum and McCabe, W. H. Freeman and Company, New York, 1998. R2 = 3052/3184 = 0.96 and adjusted R2 = 0. Freeman and Company, New York, 1998 * Large probabilities indicate that there is no linear relation

  16. Delta-phase manganese gallium on gallium nitride: a magnetically tunable spintronic system

    E-Print Network [OSTI]

    with Mn:Ga ratio between 1:1 to 1.5:1 is grown on wurtzite gallium nitride and scandium nitride substrates. Results suggest that for growth on wurtzite GaN, Ga-polar surface promotes quicker interface formation epitaxially on top of wide band-gap Ga-polar wurtzite GaN(0001), with controllable magnetism by adjusting

  17. Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts

    E-Print Network [OSTI]

    Smieja, Jonathan Mark

    2012-01-01T23:59:59.000Z

    are on the decline of the peak oil production curve, and thedue to the impending peak in oil production and the threatoil production curves for those countries that have passed peak

  18. Molecular Interactions of Plutonium(VI) with Synthetic Manganese-Substituted Goethite

    E-Print Network [OSTI]

    Hu, Yung-Jin

    2011-01-01T23:59:59.000Z

    WA 99352 Savannah River National Laboratory, Aiken, SCWork at the Savannah River National Laboratory (SRNL) was

  19. Synthesis and Characterization of 14-1-11 Ytterbium Manganese Antimonide Derivatives for Thermoelectric Applications

    E-Print Network [OSTI]

    Star, Kurt

    2013-01-01T23:59:59.000Z

    for remote impoverished communities. [1] For heat rejection,heat generated by a decaying radioisotope to electrical power, well suited for deep space exploration as well as use in remote

  20. Quantitative room-temperature mineralization of airborne formaldehyde using manganese oxide catalysts

    E-Print Network [OSTI]

    Sidheswaran, Meera A.

    2012-01-01T23:59:59.000Z

    in VOC abatement. Applied Catalysis B-Environmental. 61:calcination temperature. Applied Catalysis B- Environmental.ambient temperature. Applied Catalysis B-Environmental. 81:

  1. The relationship of nutritional manganese to the development of postmenopausal osteopenia in rats

    E-Print Network [OSTI]

    Miyasato, Jan Leiko

    1995-01-01T23:59:59.000Z

    . 'Cortical Thickness Index (CTI) calculated as: (outer diameter at midshaft (mm) ? inner diameter at midshaft (mm)/outer diameter at midshaft (mm). TABLE 6 Bone tissue area' GROUP (n) PERCENT PERCENT CORTICAL TRABE- AREA CULAR BONE AREA PERCENT... TRABECULAR BONE PERCENT TRAB - EC UL BONE/ TRABE- CULAR BONE AREA NON (9) 20. 19 + 1. 20 0. 49 + 1. 45 35. 79 + 2. 89 44. 62 + 3. 33 NON (8) NOL (9) LON (8) LOL (9) 21. 04 + I 03 78. 98 + 1. 04 18. 36 + 1. 02 82. 89 + 1. 76 20. 84 + 2 32 79 75...

  2. Removal of Filter Cake Generated by Manganese Tetraoxide Water-based Drilling Fluids

    E-Print Network [OSTI]

    Al Mojil, Abdullah Mohammed A.

    2011-10-21T23:59:59.000Z

    Three effective solutions to dissolve the filter cake created by water-based drilling fluids weighted with Mn3O4 particles were developed. Hydrochloric acid at concentration lower than 5 wt% can dissolve most of Mn3O4-based filter cake. Dissolving...

  3. X-ray Fluorescence Measurements of Manganese in Petroglyphs and Graffiti in the Bluff, Utah Area

    E-Print Network [OSTI]

    ABSTRACT Desert varnish accumulates with time through a microbial process that binds clay minerals to be extracted from the desert varnish which, though usually small, damages the artifact. Despite

  4. Hard and tough electrodeposited aluminum-manganese alloys with tailored nanostructures

    E-Print Network [OSTI]

    Ruan, Shiyun

    2010-01-01T23:59:59.000Z

    Tailoring the nanostructure of electrodeposited Al-Mn films to achieve high hardness and toughness is the overarching goal of this thesis. Binary Al-Mn alloys are electrodeposited using a conventional current waveform in ...

  5. Chemically bonded phosphate ceramics of trivalent oxides of iron and manganese

    DOE Patents [OSTI]

    Wagh, Arun S. (Orland Park, IL); Jeong, Seung-Young (Westmont, IL)

    2002-01-01T23:59:59.000Z

    A new method for combining elemental iron and other metals to form an inexpensive ceramic to stabilize arsenic, alkaline red mud wastes, swarfs, and other iron or metal-based additives, to create products and waste forms which can be poured or dye cast.

  6. Layered manganese oxide intergrowth electrodes for rechargeable lithium batteries: Part 1-substitution with Co or Ni

    E-Print Network [OSTI]

    Dolle, Mickael; Patoux, Sebastien; Doeff, Marca M.

    2004-01-01T23:59:59.000Z

    Cathode Materials for Lithium Batteries, 2003, Massachusettsfor Rechargeable Lithium Batteries: Part 1-Substitution withelectrode materials for lithium batteries because of their

  7. Synthesis and Characterization of 14-1-11 Ytterbium Manganese Antimonide Derivatives for Thermoelectric Applications

    E-Print Network [OSTI]

    Star, Kurt

    2013-01-01T23:59:59.000Z

    oxide basis) and other rare earth metals were cut by handof phosphorus, transition metals and rare earths go outsideor Alkaline metals (or in this case rare earths) are treated

  8. AN X-RAY ABSORPTION SPECTROSCOPY STUDY OF MANGANESE CONTAINING COMPOUNDS AND PHOTOSYNTHETIC SPINACH CHLOROPLASTS

    E-Print Network [OSTI]

    Kirby, Jon Allan

    2012-01-01T23:59:59.000Z

    SPINACH CHLOROPLASTS Jon Allan Kirby (Ph.D. thesis) May 1981SPINACH CHLOROPLASTS Jon Allan Kirby Ph.D. Thesis May 1981Spinach Chloroplasts Jon Allan Kirby B.S. (Ottawa

  9. Lithium manganese oxide films fabricated by electron beam directed vapor deposition

    E-Print Network [OSTI]

    Wadley, Haydn

    material for high energy den- sity battery applications.7,8 Lithium­transition metal oxide films can.2. After annealing in air at 700 °C, thin films grown with a low jet speed had a cubic spinel structure Li/Li-ion batteries. © 2008 American Vacuum Society. DOI: 10.1116/1.2823488 I. INTRODUCTION Thin film

  10. OXIDATION AND SORPTION KINETICS OF ARSENIC ON A POORLY CRYSTALLINE MANGANESE OXIDE

    E-Print Network [OSTI]

    Sparks, Donald L.

    : __________________________________________________________ James T. Sims, Ph.D. Member of dissertation committee #12;iv ACKNOWLEDGMENTS I thank my advisor, Dr remember our road trip to Pittsburgh and our many group picnics. Special acknowledgement is due to Jerry

  11. aluminium-manganese alloy vliyanie: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aluminum, alloy 706 provides good hardenability and resistance against oxidation and corrosion. It displays excellent mechanical strength in combination with good fabricability,...

  12. Settling Rates for Flocculation of Iron and Manganese Ore-Containing Suspensions by Cationic Glycogen

    E-Print Network [OSTI]

    North Texas, University of

    --and a valuable one in all nations--reusage of industrial water and municipal sludges can have a power- ful impact the world the application of synthetic flocculants is accepted for solid­liq- uid separation the polymer flocculant [4­6]. Synthetic polyacrylamides are effective flocculants and easily tailored

  13. Carbon spheres-assisted strategy to prepare mesoporous manganese dioxide for supercapacitor applications

    SciTech Connect (OSTI)

    Li Siheng [State Key Laboratory of Electroanalytical Chemistry, and Jilin Provincial Key Laboratory of Advanced Low-carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin St., Changchun 130022 (China); Graduate University of Chinese Academy of Sciences, Beijing 100039 (China); Qi Li, E-mail: qil@ciac.jl.cn [State Key Laboratory of Electroanalytical Chemistry, and Jilin Provincial Key Laboratory of Advanced Low-carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin St., Changchun 130022 (China); Lu Lehui; Wang Hongyu [State Key Laboratory of Electroanalytical Chemistry, and Jilin Provincial Key Laboratory of Advanced Low-carbon Chemical Power, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin St., Changchun 130022 (China)

    2013-01-15T23:59:59.000Z

    Mesoporous MnO{sub 2} microstructures with large specific surface area have been successfully synthesized by an in-situ redox precipitation method in the presence of colloidal carbon spheres. The samples of them had much higher specific surface area, pore size and pore volume than those obtained via routes without carbon spheres. The morphology, chemical compositions and porous nature of products were fully characterized. Electrochemical measurements showed that these mesoporous MnO{sub 2} could function well when used as positive electrode materials for supercapacitor. Ideal electrochemical capacitive performances and cyclic stability after 2000 galvanostatic charge-discharge cycles could be observed in 1 M neutral Na{sub 2}SO{sub 4} aqueous electrolyte with a working voltage of 1.7 V. - Graphical Abstract: Mesoporous MnO{sub 2} microstructures with large S{sub BET} were successfully synthesized by in-situ redox precipitation method in the presence of colloidal carbon spheres. Electrochemical measurements showed that these mesoporous MnO{sub 2} could be well used as electrode materials for supercapacitor. Highlights: Black-Right-Pointing-Pointer Mesoporous MnO{sub 2} was prepared by in-situ redox method assisted by carbon spheres. Black-Right-Pointing-Pointer S{sub BET}, pore size and volume were higher than MnO{sub 2} obtained without carbon spheres. Black-Right-Pointing-Pointer They could function well when used as electrode materials for supercapacitor. Black-Right-Pointing-Pointer Ideal capacitive behaviors and long cycling life showed after 2000 charge-discharge.

  14. Reaction of Plutonium(VI) with the Manganese-Substituted Iron Oxide Mineral Goethite

    E-Print Network [OSTI]

    Hu, Yung-Jin Hu

    2011-01-01T23:59:59.000Z

    level. Goethite Synthesis Goethite (table 4.1) wasThe laboratory synthesis of goethite requires relativelyindicating that the goethite synthesis was successful. SEM

  15. Molecular Interactions of Plutonium(VI) with Synthetic Manganese-Substituted Goethite

    E-Print Network [OSTI]

    Hu, Yung-Jin

    2011-01-01T23:59:59.000Z

    VI) with the Iron Oxide Goethite, University of California,Values for Synthetic Goethite and Pyrolusite" submitted tothe two Mn-substituted goethite minerals used in this study.

  16. Electrocatalytic reduction of carbon dioxide to carbon monoxide by rhenium and manganese polypyridyl catalysts

    E-Print Network [OSTI]

    Smieja, Jonathan Mark

    2012-01-01T23:59:59.000Z

    carbon electrode in acetonitrile. The two reductions arepseudo-reference electrode, acetonitrile with 0.1 M TBAH asyield of 94%. 1 H NMR (acetonitrile-d 3 ): ? 2.33 (s, 6H, CH

  17. The Effects of Ozone Deposition and Dissolved Organic Matter on Manganese Speciation in the Surface Ocean

    E-Print Network [OSTI]

    Smyth, Alison Michelle

    2014-07-31T23:59:59.000Z

    analysis (FIA) chemiluminescence system to measure Mn(II) in order to investigate the effect of O_(3) deposition to the sea surface on Mn speciation. Modifications to earlier FIA systems had to be made in order to accommodate the relatively high...

  18. Sorption of Ferric Iron from Siderophore Complexes by Layer Type Manganese

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our Instagram Secretary Moniz9MorganYouofSolving the Unsovlable:

  19. High-Quality Manganese-Doped Zinc Sulfide Quantum Rods with Tunable

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) EnvironmentalGyroSolé(tm) Harmonicbet WhenHiggsmiddlewareHigh-Pressure

  20. 1. Lithographically Patterned Gold/Manganese Dioxide Core/Shell Nanowires for High

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch >Internship ProgramBiomassUniversityNuclearIBM8)4-08) SECTION

  1. Promises and Challenges of Lithium- and Manganese-Rich Transition-Metal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of ContaminationHubs+ ReportEnergy National SolarPublications »with

  2. Thermodynamic Investigations of Lithium- and Manganese-Rich Transition Metal Oxides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideoStrategic|Industrial Sector,Department of Energythe Use of Lowand Their

  3. Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platform is alwaysISO 50001 Energy26.1U.S.-BrazilAdditiveComments byMaterials |

  4. Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The Future of1 AAccelerated aging of1.1Energy DPFFOA ||CommonCommentsMaterials

  5. Addressing the Voltage Fade Issue with Lithium-Manganese-Rich Oxide Cathode Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The Future of1 AAccelerated aging of1.1Energy DPFFOA

  6. NaCl transport across the opercular epithelium of Fundulus heteroclitus is inhibited by an endothelin to NO, superoxide, and prostanoid signaling axis

    E-Print Network [OSTI]

    Evans, David H.

    . Sarafotoxin S6c was equipotent to ET-1, suggesting that ETB receptors are involved. Incubation with NG -nitro (e.g., 28). The cardiovascular effects of ETs are mediated by two receptors, termed ETA and ETB (e sarafotoxin S6c (SRXS6c) shows very high specificity for ETB receptors (e.g., 36). ET produces potent

  7. Diminished Superoxide Generation Is Associated With Respiratory Chain Dysfunction and Changes in the Mitochondrial Proteome of Sensory Neurons From Diabetic Rats

    E-Print Network [OSTI]

    Akude, Eli; Zherebitskaya, Elena; Chowdhury, Subir K. Roy; Smith, Darrell R.; Dobrowsky, Rick T.; Fernyhough, Paul

    2011-09-28T23:59:59.000Z

    .42 MnSOD BA C Control NADH dehydrogenase Fe-S protein 3 744 745 746 747 748 749 m/z 0 2000 4000 6000 8000 10000 12000 14000 16000 18000 In te ns ity 743.90 744.41 744.91 748.90 749.41 VVAEPVELAQEFR 16 13VVAEPVELAQEF N C R 4 6 R0/R10=5.26 GDVTTQVALQPALK... dehydrogenase Fe-S protein 3 744 745 746 747 748 749 m/z 0 1000 2000 3000 4000 5000 6000 7000 8000 9000 10000 11000 In te ns ity 743.90 744.40 748.90 749.41 744.91 MnSOD VVAEPVELAQEFR 16 13VVAEPVELAQEF N C R 4 6 GDVTTQVALQPALK 13GDVTTQVALQPAL C K 6 R0/R10 = 2...

  8. Thermal stability in the blended lithium manganese oxide – Lithium nickel cobalt manganese oxide cathode materials: An in situ time-resolved X-Ray diffraction and mass spectroscopy study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Enyuan; Bak, Seong Min; Senanayake, Sanjaya D.; Yang, Xiao-Qing; Nam, Kyung-Wan; Zhang, Lulu; Shao, Minhua

    2015-03-01T23:59:59.000Z

    Thermal stabilities of a series of blended LiMn2O4(LMO)-LiNi1/3Co1/3Mn1/3O2 (NCM) cathode materials with different weight ratios were studied by in situ time-resolved X-ray diffraction (XRD) combined with mass spectroscopy in the temperature range of 25°C-580°C under helium atmosphere. Upon heating, the electrochemically delithiated LMO changed into Mn3O4 phase at around 250°C. Formation of MnO with rocksalt structure started at 520°C. This observation is in contrast to the previous report for chemically delithiate LMO in air, in which a process of ?-MnO2 transforming to ?-MnO2 was observed. Oxygen peak was not observed in all cases, presumably as a result of either consumptionmore »by the carbon or detection limit. CO2 profile correlates well with the phase transition and indirectly suggests the oxygen release of the cathode. Introducing NCM into LMO has two effects: first, it makes the high temperature rock-salt phase formation more complicated with more peaks in CO2 profile due to different MO (M = Ni, Mn, Co) phases; secondly, the onset temperature of CO2 release is lowered, implying lowered oxygen release temperature. Upon heating, XRD patterns indicate the NCM part reacts first, followed by the LMO part. This confirms the better thermal stability of LMO over NCM.« less

  9. Thermal stability in the blended lithium manganese oxide – Lithium nickel cobalt manganese oxide cathode materials: An in situ time-resolved X-Ray diffraction and mass spectroscopy study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Enyuan [Brookhaven National Lab. (BNL), Upton, NY (United States); Bak, Seong Min [Brookhaven National Lab. (BNL), Upton, NY (United States); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States); Yang, Xiao-Qing [Dongguk Univ., Seoul (Korea, Republic of). Dept. of Energy and Materials Engineering; Nam, Kyung-Wan [Dongguk Univ., Seoul (Korea, Republic of). Dept. of Energy and Materials Engineering] (ORCID:0000000162786369); Zhang, Lulu [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong); Shao, Minhua

    2015-03-01T23:59:59.000Z

    Thermal stabilities of a series of blended LiMn2O4(LMO)-LiNi1/3Co1/3Mn1/3O2 (NCM) cathode materials with different weight ratios were studied by in situ time-resolved X-ray diffraction (XRD) combined with mass spectroscopy in the temperature range of 25°C-580°C under helium atmosphere. Upon heating, the electrochemically delithiated LMO changed into Mn3O4 phase at around 250°C. Formation of MnO with rocksalt structure started at 520°C. This observation is in contrast to the previous report for chemically delithiate LMO in air, in which a process of ?-MnO2 transforming to ?-MnO2 was observed. Oxygen peak was not observed in all cases, presumably as a result of either consumption by the carbon or detection limit. CO2 profile correlates well with the phase transition and indirectly suggests the oxygen release of the cathode. Introducing NCM into LMO has two effects: first, it makes the high temperature rock-salt phase formation more complicated with more peaks in CO2 profile due to different MO (M = Ni, Mn, Co) phases; secondly, the onset temperature of CO2 release is lowered, implying lowered oxygen release temperature. Upon heating, XRD patterns indicate the NCM part reacts first, followed by the LMO part. This confirms the better thermal stability of LMO over NCM.

  10. Molecular dissection of the roles of the SOD genes in mammalian response to low dose irradiation

    SciTech Connect (OSTI)

    Eric Y. Chuang

    2006-08-31T23:59:59.000Z

    It has been long recognized that a significant fraction of the radiation-induced genetic damage to cells are caused by secondary oxidative species. Internal cellular defense systems against oxidative stress play significant roles in countering genetic damage induced by ionizing radiation. The role of the detoxifying enzymes may be even more prominent in the case of low-dose, low-LET irradiation, as the majority of genetic damage may be caused by secondary oxidative species. In this study we have attempted to decipher the roles of the superoxide dismutase (SOD) genes, which are responsible for detoxifying the superoxide anions. We used adenovirus vectors to deliver RNA interference (RNAi or siRNA) technology to down-regulate the expression levels of the SOD genes. We have also over-expressed the SOD genes by use of recombinant adenovirus vectors. Cells infected with the vectors were then subjected to low dose ?-irradiation. Total RNA were extracted from the exposed cells and the expression of 9000 genes were profiled by use of cDNA microarrays. The result showed that low dose radiation had clear effects on gene expression in HCT116 cells. Both over-expression and down-regulation of the SOD1 gene can change the expression profiles of sub-groups of genes. Close to 200 of the 9000 genes examined showed over two-fold difference in expression under various conditions. Genes with changed expression pattern belong to many categories that include: early growth response, DNA-repair, ion transport, apoptosis, and cytokine response.

  11. ROLE OF MANGANESE REDUCTION/OXIDATION (REDOX) ON FOAMING AND MELT RATE IN HIGH LEVEL WASTE (HLW) MELTERS (U)

    SciTech Connect (OSTI)

    Jantzen, C; Michael Stone, M

    2007-03-30T23:59:59.000Z

    High-level nuclear waste is being immobilized at the Savannah River Site (SRS) by vitrification into borosilicate glass at the Defense Waste Processing Facility (DWPF). Control of the Reduction/Oxidation (REDOX) equilibrium in the DWPF melter is critical for processing high level liquid wastes. Foaming, cold cap roll-overs, and off-gas surges all have an impact on pouring and melt rate during processing of high-level waste (HLW) glass. All of these phenomena can impact waste throughput and attainment in Joule heated melters such as the DWPF. These phenomena are caused by gas-glass disequilibrium when components in the melter feeds convert to glass and liberate gases such as H{sub 2}O vapor (steam), CO{sub 2}, O{sub 2}, H{sub 2}, NO{sub x}, and/or N{sub 2}. During the feed-to-glass conversion in the DWPF melter, multiple types of reactions occur in the cold cap and in the melt pool that release gaseous products. The various gaseous products can cause foaming at the melt pool surface. Foaming should be avoided as much as possible because an insulative layer of foam on the melt surface retards heat transfer to the cold cap and results in low melt rates. Uncontrolled foaming can also result in a blockage of critical melter or melter off-gas components. Foaming can also increase the potential for melter pressure surges, which would then make it difficult to maintain a constant pressure differential between the DWPF melter and the pour spout. Pressure surges can cause erratic pour streams and possible pluggage of the bellows as well. For these reasons, the DWPF uses a REDOX strategy and controls the melt REDOX between 0.09 {le} Fe{sup 2+}/{summation}Fe {le} 0.33. Controlling the DWPF melter at an equilibrium of Fe{sup +2}/{summation}Fe {le} 0.33 prevents metallic and sulfide rich species from forming nodules that can accumulate on the floor of the melter. Control of foaming, due to deoxygenation of manganic species, is achieved by converting oxidized MnO{sub 2} or Mn{sub 2}O{sub 3} species to MnO during melter preprocessing. At the lower redox limit of Fe{sup +2}/{summation}Fe {approx} 0.09 about 99% of the Mn{sup +4}/Mn{sup +3} is converted to Mn{sup +2}. Therefore, the lower REDOX limits eliminates melter foaming from deoxygenation.

  12. Final Report: Manganese Redox Mediation of UO2 Stability and Uranium Fate in the Subsurface: Molecular and Meter Scale Dynamics

    SciTech Connect (OSTI)

    Tebo, Bradley M. [OSHU; Tebo, Bradley M.

    2014-09-02T23:59:59.000Z

    One strategy to remediate U contamination in the subsurface is the immobilization of U via injection of an electron donor, e.g., acetate, which leads to stimulation of the bioreduction of U(VI), the more mobile form of U, to U(IV), the less mobile form. This process is inevitably accompanied by the sequential reductive dissolution of Mn and Fe oxides and often continuing into sulfate-reducing conditions. When these reducing zones, which accumulate U(IV), experience oxidizing conditions, reduced Fe and Mn can be reoxidized forming Fe and Mn oxides that, along with O2, can impact the stability of U(IV). The focus of our project has been to investigate (i) the effects of Mn(II) on the dissolution of UO2 under both reducing and oxidizing conditions, (ii) the oxidative dissolution of UO2 by soluble Mn(III), (iii) the fate of U once it is oxidized by MnO2 in both laboratory and field settings, and (iv) the effects of groundwater constituents on the coupled Mn(II)/U(IV) oxidation process. Additionally, studies of the interaction of Se, found at the DOE site at Rifle, CO, and Mn cycling were initiated to understand if observed seasonal fluctuations of Se and Mn are directly linked and whether any such linkages can affect the stability of U(IV).

  13. Role of the Berry Phase in the Formation of Stripes in Manganese Oxides 3 Takashi Hotta y and Yasutami Takada

    E-Print Network [OSTI]

    Takada, Yasutami

    106­8666, Japan Hiroyasu Koizumi Faculty of Science, Himeji Institute of Technology, Kanaji, Kamigori, Ako­gun, Hyogo 678­1297, Japan (25 November 1998) In order to gain an insight into the formation elec­ tron correlation, and (iv) strong electron­phonon cou­ pling leading to the Jahn­Teller (JT

  14. Microbial Manganese(II) oxidation : biogeochemistry of a deep-sea hydrothermal plume, enzymatic mechanism, and genomic perspectives

    E-Print Network [OSTI]

    Dick, Gregory J.

    2006-01-01T23:59:59.000Z

    plume. Multicopper oxidase (MCO) enzymes are involved in Mn(elucidated multicopper oxidase (MCO) genes that are requiredO (Solomon et al. , 1996). MCO substrates include a variety

  15. Real-time x-ray absorption spectroscopy of uranium, iron, and manganese in contaminated sediments during bioreduction

    E-Print Network [OSTI]

    Tokunaga, T.K.

    2008-01-01T23:59:59.000Z

    National Laboratory, Berkeley, California 94720 University of Chicago, Chicago, Illinois 60637 Savannah River

  16. Fabrication and characterization of lithium manganese nickel oxide sputtered thin film cathodes for lithium-ion batteries

    SciTech Connect (OSTI)

    Baggetto, Loic [ORNL] [ORNL; Unocic, Raymond R [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; Veith, Gabriel M [ORNL] [ORNL

    2012-01-01T23:59:59.000Z

    Li-rich and stoichiometric Li1Mn1.5Ni0.5O4 (LMNO) cathode films have been prepared by magnetron sputtering. Sputtering from a Li stoichiometric target yields Li-rich films composed of spinel, layered and monoclinic phases. Films obtained from a Li deficient target are mostly made of a spinel phase and little layered material. The resulting cathode thin films have good capacity retention and very high rate capability. The reaction mechanism has been investigated by XRD and HRTEM and evidences the reversible formation of a spinel phase, as is also found for the powder samples. The film geometry enables to understand the effect of coatings (ZnO or LiPON). Coating high voltage cathodes reduces the coulombic losses but at the price of rate performance. Nonetheless, these coated sputtered electrode thin films offer a higher rate capability than other LMNO thin films obtained by other physical vapor deposition techniques.

  17. Electrochromic properties of manganese oxide (MnO{sub x}) thin films made by electron beam deposition

    SciTech Connect (OSTI)

    Erlandsson, O.; Lindvall, J.; Nguyen Ngoc Toan; Nguyen Van Hung; Vu Thi Bich; Nguyen Nang Dinh [National Inst. of Physics of Vietnam, Hanoi (Viet Nam)

    1993-12-31T23:59:59.000Z

    In recent years, considerable attention has been given to both the theoretical and the experimental investigation of the physical and physico-chemical properties of the chromogenics materials due their favorable and promising applications such as electrochromic devices, energy-efficient smart windows, automobile mirrors and building glazings. Electrochromic MnO{sub x} thin films were prepared by using an electron beam technique followed by annealing post-treatment. Electrochromic properties of the films were studied in three different solutions: 1M LiClO{sub 4} in propylene carbonate, KOH (pH = 10.5) and natrium borate (pH = 9.2). The transmittance spectra of the colored films combined with their cyclic voltammograms have showed that the enhancement of the electrochromic behavior of these films can be attributed to the insertion (or extraction) of the OH{sup {minus}} anions into (or from) the MnO{sub x} films. The best electrochromic efficiency of the films was obtained in the borate electrolyte.

  18. Microbial Manganese(II) oxidation : biogeochemistry of a deep-sea hydrothermal plume, enzymatic mechanism, and genomic perspectives

    E-Print Network [OSTI]

    Dick, Gregory J.

    2006-01-01T23:59:59.000Z

    2738. Cowen J. P. and Bruland K. W. (1985) Metal depositsLanding W. M. and Bruland K. W. (1987) The contrastingopen ocean (Landing and Bruland, 1987) or some hydrothermal

  19. Optical spin orientation of a single manganese atom in a semiconductor quantum dot using quasi-resonant excitation

    E-Print Network [OSTI]

    Boyer, Edmond

    of these mem- ories. Dilute magnetic semiconductors (DMS) systems combining semiconductor heterostructures

  20. Hydrothermal Synthesis of Pure r-Phase Manganese(II) Sulfide without the Use of Organic Reagents

    E-Print Network [OSTI]

    Reagents F. M. Michel,*,, M. A. A. Schoonen,, X. V. Zhang,§ S. T. Martin,§ and J. B. Parise, Center for En

  1. Detection of Sequence-Specific Tyrosine Nitration of Manganese SOD and SERCA in Cardiovascular Disease and Aging

    SciTech Connect (OSTI)

    Xu, Shanqin; Ying, Jia; Jiang, Bingbing; Guo, Wei; Adachi, Takeshi; Sharov, Victor; Lazar, Harold; Menzoian, James; Knyushko, Tanya V.; Bigelow, Diana J.; Schoneich, Christian; Cohen, Richard

    2006-06-01T23:59:59.000Z

    Nitration of protein tyrosine residues (nY) is a marker of oxidative stress and may alter the biological activity of the modified proteins. The aim of this study was to develop antibodies towards site-specific nY-modified proteins and to use histochemical and immunoblotting to demonstrate protein nitration in tissues. Affinity-purified polyclonal antibodies towards peptides with known nY sites in MnSOD nY-34 and of two adjacent nY in the sarcoplasmic endoplasmic reticulum calcium ATPase (SERCA2 di-nY-294,295) were developed. Kidneys from rats infused with angiotensin II with known MnSOD nY and aorta from atherosclerotic rabbits and aging rat skeletal and cardiac sarcoplasmic reticulum with known SERCA di-nY were used for positive controls. Staining for MnSOD nY-34 was most intense in distal renal tubules and collecting ducts. Staining of atherosclerotic aorta for SERCA2 di-nY was most intense in atherosclerotic plaques. Aging rat skeletal muscle and atherosclerotic aorta and cardiac atrium from human diabetic patients also stained positively. Staining was decreased by sodium dithionite that chemically reduces nitrotyrosine to aminotyrosine, and the antigenic nY-peptide blocked staining for each respective nY site, but not for the other. As previously demonstrated, immunoblotting failed to detect these modified proteins in whole tissue lysates, but did when the proteins were concentrated. Immunohistochemical staining for specific nY-modified tyrosine residues offers the ability to assess the effects of oxidant stress associated with pathological conditions on individual proteins whose function may be affected in specific tissue sites.

  2. Real-time x-ray absorption spectroscopy of uranium, iron, and manganese in contaminated sediments during bioreduction

    E-Print Network [OSTI]

    Tokunaga, T.K.

    2008-01-01T23:59:59.000Z

    to Mn(II) in sediments infused with OC ? 3 mM. However, Fecontaminated sediments were infused with a steady supply ofspectra obtained on sediments infused with 30 and 100 mM OC

  3. Real-time x-ray absorption spectroscopy of uranium, iron, and manganese in contaminated sediments during bioreduction

    SciTech Connect (OSTI)

    Tokunaga, Tetsu; Tokunaga, T.K.; Wan, J.; Kim, Y.; Sutton, S.R.; Newville, M.; Lanzirotti, A.; Rao, W.

    2008-01-15T23:59:59.000Z

    The oxidation status of uranium in sediments is important because the solubility of this toxic and radioactive element is much greater for U(VI) than for U(IV) species. Thus, redox manipulation to promote precipitation of UO{sub 2} is receiving interest as a method to remediate U-contaminated sediments. Presence of Fe and Mn oxides in sediments at much higher concentrations than U requires understanding of their redox status as well. This study was conducted to determine changes in oxidation states of U, Fe, and Mn in U-contaminated sediments from Oak Ridge National Laboratory. Oxidation states of these elements were measured in real-time and nondestructively using X-ray absorption spectroscopy, on sediment columns supplied with synthetic groundwater containing organic carbon (OC, 0, 3, 10, 30 and 100 mM OC as lactate) for over 400 days. In sediments supplied with OC {ge} 30 mM, 80% of the U was reduced to U(IV), with transient reoxidation at about 150 days. Mn(III,IV) oxides were completely reduced to Mn(II) in sediments infused with OC {ge} 3 mM. However, Fe remained largely unreduced in all sediment columns, showing that Fe(III) can persist as an electron acceptor in reducing sediments over long times. This result in combination with the complete reduction of all other potential electron acceptors supports the hypothesis that the reactive Fe(III) fraction was responsible for reoxidizing U(IV).

  4. Z .The Science of the Total Environment 265 2001 169 179 Manganese and land-use in upland catchments in

    E-Print Network [OSTI]

    Heal, Kate

    from conifer foliage and litter, and mature conifers enhance acid deposition and loss of Mn from is a transition metal which is widespread in the environment, occurring in all Z .rocks and soils Krauskopf for Mn Scottish Office, 1997 , the ma- jority of failures occurred in upland water sources. Mn

  5. Microbial Manganese(II) oxidation : biogeochemistry of a deep-sea hydrothermal plume, enzymatic mechanism, and genomic perspectives

    E-Print Network [OSTI]

    Dick, Gregory J.

    2006-01-01T23:59:59.000Z

    Mn(II) oxidation. Near the Mox-1 region there is a predictedCu-binding regions. In the Mox-2 region there is a permeasethat are duplicated in both Mox regions include several

  6. Fabrication and characterization of high energy density lithium-rich nickel manganese cobalt oxide cathode thin films

    SciTech Connect (OSTI)

    Baggetto, Loic [ORNL] [ORNL; Mohanty, Debasish [ORNL] [ORNL; Meisner, Roberta Ann [ORNL] [ORNL; Daniel, Claus [ORNL] [ORNL; Wood III, David L [ORNL] [ORNL; Dudney, Nancy J [ORNL] [ORNL; Veith, Gabriel M [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    This paper reports a method to prepare Li-rich NMC (Li1.2Mn0.55Ni0.15Co0.1O2) thin film cathodes for Li-ion batteries using magnetron sputtering and post-annealing in O2. The use of thin films with no binder and conductive additives enables to study in detail the surface reaction chemistry upon cycling as well as the microstructural changes in the bulk. We show that it is essential to control the deposition pressure to obtain the expected layered(R-3m)-layered(C2/m) structure, thus providing large reversible capacities up to 270 mAh g-1 and voltage profiles close to those expected. This is substantiated by TEM/SAED results showing that the films consist of a layered structure with trigonal symmetry in which Li/TM ordering is achieved. The study of various XPS core levels determines that the surface is comprised of Mn4+, Co3+ and Ni2+ cations inside an O2- framework. The losses mechanisms are studied during long cycling. After 184 cycles, the microstructure does not reveal the presence of Li/TM ordering, which supports that Li2MnO3 conversion is irreversible. In addition, we characterize that the surface chemistry evolves significantly upon cycling. The surface of cycled discharged electrodes is mostly made of inorganic species (LiF, Lix POy Fz , LixPFy), along with small amounts of organic species with C-O and O-C=O groups such as PEO, LiOR and LiCO2R. Moreover, the results support that Ni and Co migrate into the bulk whereas Mn is enriched at the surface. In the case of Mn, the reduction of Mn4+ into Mn3+ is clearly evidenced, as expected from the activation of Li2MnO3 domains.

  7. Heterolytic Cleavage of H2 by Bifunctional Manganese(I) Complexes: Impact of Ligand Dynamics, Electrophilicity, and Base Positioning

    SciTech Connect (OSTI)

    Hulley, Elliott B.; Helm, Monte L.; Bullock, R. Morris

    2014-12-01T23:59:59.000Z

    We report the synthesis, characterization, and reactivity with H2 of a series of MnI complexes of the type [(P-P)Mn(L2)CO]+ (L2 = dppm, bppm, or (CO)2; P-P = PPhNMePPh or PPh2 NBn2 ) that bear pendant amine ligands designed to function as proton relays. The pendant amine was found to function as a hemilabile ligand; its binding strength is strongly affected by the ancillary ligand environment around Mn. Tuning the electrophilicity of the Mn center leads to systems capable of reversible heterolytic cleavage of the H-H bond. The strength of pendant amine binding can be balanced to protect the Mn center while still leading to facile reactivity with H2. Neutral amine-bearing MnIH species were found to react with one-electron oxidants and, after proton and electron transfer reactions, regenerate MnI cationic species. The reactivity presented herein indicate that the Mn complexes we have developed are a promising platform for Mn-based H2 oxidation electrocatalyst development. The research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for DOE.

  8. Real-time x-ray absorption spectroscopy of uranium, iron, and manganese in contaminated sediments during bioreduction

    E-Print Network [OSTI]

    Tokunaga, T.K.

    2008-01-01T23:59:59.000Z

    precipitation of uranyl on goethite. Environmental Science23 used were hematite and goethite for Fe(III), and fayaliteenergies for hematite and goethite standards were 7,114.9 ±

  9. Chlorobenzene induces oxidative stress in human lung epithelial cells in vitro

    SciTech Connect (OSTI)

    Feltens, Ralph, E-mail: ralph.feltens@ufz.d [UFZ- Helmholtz Centre for Environmental Research, Department of Environmental Immunology, Permoserstrasse 15, D-04318 Leipzig (Germany); UFZ- Helmholtz Centre for Environmental Research, Department of Proteomics, Permoserstrasse 15, D-04318 Leipzig (Germany); Moegel, Iljana, E-mail: iljana.moegel@ufz.d [UFZ- Helmholtz Centre for Environmental Research, Department of Environmental Immunology, Permoserstrasse 15, D-04318 Leipzig (Germany); Roeder-Stolinski, Carmen, E-mail: carmen.roeder-stolinski@ufz.d [UFZ- Helmholtz Centre for Environmental Research, Department of Environmental Immunology, Permoserstrasse 15, D-04318 Leipzig (Germany); Simon, Jan-Christoph, E-mail: Jan-Christoph.Simon@medizin.uni-leipzig.d [Leipzig University Medical Center, Clinic of Dermatology, Venerology and Allergology, Philipp-Rosenthal-Str. 23-25, D-4103 Leipzig (Germany); Herberth, Gunda, E-mail: gunda.herberth@ufz.d [UFZ- Helmholtz Centre for Environmental Research, Department of Environmental Immunology, Permoserstrasse 15, D-04318 Leipzig (Germany); Lehmann, Irina, E-mail: irina.lehmann@ufz.d [UFZ- Helmholtz Centre for Environmental Research, Department of Environmental Immunology, Permoserstrasse 15, D-04318 Leipzig (Germany)

    2010-01-01T23:59:59.000Z

    Chlorobenzene is a volatile organic compound (VOC) that is widely used as a solvent, degreasing agent and chemical intermediate in many industrial settings. Occupational studies have shown that acute and chronic exposure to chlorobenzene can cause irritation of the mucosa of the upper respiratory tract and eyes. Using in vitro assays, we have shown in a previous study that human bronchial epithelial cells release inflammatory mediators such as the cytokine monocyte chemoattractant protein-1 (MCP-1) in response to chlorobenzene. This response is mediated through the NF-kappaB signaling pathway. Here, we investigated the effects of monochlorobenzene on human lung cells, with emphasis on potential alterations of the redox equilibrium to clarify whether the chlorobenzene-induced inflammatory response in lung epithelial cells is caused via an oxidative stress-dependent mechanism. We found that expression of cellular markers for oxidative stress, such as heme oxygenase 1 (HO-1), glutathione S-transferase pi1 (GSTP1), superoxide dismutase 1 (SOD1), prostaglandin-endoperoxide synthase 2 (PTGS2) and dual specificity phosphatase 1 (DUSP1), were elevated in the presence of monochlorobenzene. Likewise, intracellular reactive oxygen species (ROS) were increased in response to exposure. However, in the presence of the antioxidants N-(2-mercaptopropionyl)-glycine (MPG) or bucillamine, chlorobenzene-induced upregulation of marker proteins and release of the inflammatory mediator MCP-1 are suppressed. These results complement our previous findings and point to an oxidative stress-mediated inflammatory response following chlorobenzene exposure.

  10. In utero and in vitro effects of benzene and its metabolites on erythroid differentiation and the role of reactive oxygen species

    SciTech Connect (OSTI)

    Badham, Helen J. [Department of Pharmacology and Toxicology. Queen's University, Kingston, Ontario, K7L 3N6 (Canada); Winn, Louise M., E-mail: winnl@queensu.c [Department of Pharmacology and Toxicology. Queen's University, Kingston, Ontario, K7L 3N6 (Canada); School of Environmental Studies, Queen's University, Kingston, Ontario, K7L 3N6 (Canada)

    2010-05-01T23:59:59.000Z

    Benzene is a ubiquitous occupational and environmental toxicant. Exposures to benzene both prenatally and during adulthood are associated with the development of disorders such as aplastic anemia and leukemia. Mechanisms of benzene toxicity are unknown; however, generation of reactive oxygen species (ROS) by benzene metabolites may play a role. Little is known regarding the effects of benzene metabolites on erythropoiesis. Therefore, to determine the effects of in utero exposure to benzene on the growth and differentiation of fetal erythroid progenitor cells (CFU-E), pregnant CD-1 mice were exposed to benzene and CFU-E numbers were assessed in fetal liver (hematopoietic) tissue. In addition, to determine the effect of benzene metabolite-induced ROS generation on erythropoiesis, HD3 chicken erythroblast cells were exposed to benzene, phenol, or hydroquinone followed by stimulation of erythrocyte differentiation. Our results show that in utero exposure to benzene caused significant alterations in female offspring CFU-E numbers. In addition, exposure to hydroquinone, but not benzene or phenol, significantly reduced the percentage of differentiated HD3 cells, which was associated with an increase in ROS. Pretreatment of HD3 cells with polyethylene glycol-conjugated superoxide dismutase (PEG-SOD) prevented hydroquinone-induced inhibition of erythropoiesis, supporting the hypothesis that ROS generation is involved in the development of benzene erythrotoxicity. In conclusion, this study provided evidence that ROS generated as a result of benzene metabolism may significantly alter erythroid differentiation, potentially leading to the development of Blood Disorders.

  11. Investigation of layered intergrowth LixMyMn1-yO2+z (M=Ni,Co,Al) compounds as positive electrodes for Li-ion batteries

    E-Print Network [OSTI]

    Dolle, M.; Hollingsworth, J.; Richardson, T.J.; Doeff, M.M.

    2003-01-01T23:59:59.000Z

    as Positive Electrodes for Li-ion Batteries M. Dollé,* J.layered manganese oxide electrodes for lithium batteries.Keywords: Lithium batteries, layered manganese oxides,

  12. Li and Mn uptake data from initial set of imprinted polymers

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Susanna Ventura

    Batch tests of crosslinked lithium and manganese imprinted polymers of variable composition to assess their ability to extract lithium and manganese from synthetic brines at T=45C .

  13. The Synthesis and Characterization of Substituted Phosphates...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phosphates and Layered Manganese Oxides The Synthesis and Characterization of Substituted Phosphates and Layered Manganese Oxides 2011 DOE Hydrogen and Fuel Cells Program, and...

  14. Batteries for Plug-in Hybrid Electric Vehicles (PHEVs): Goals and the State of Technology circa 2008

    E-Print Network [OSTI]

    Axsen, Jonn; Burke, Andy; Kurani, Kenneth S

    2008-01-01T23:59:59.000Z

    in power and energy density. LTO – Lithiated Titanium: A Li-power, energy, and affordability. MNS - Manganese Titanium:energy and safety at moderate costs. MS – Manganese Titanium:

  15. Marine Conservation Science and Policy Service learning Program

    E-Print Network [OSTI]

    Miami, University of

    for minerals, including salt, sand, gravel, manganese, copper, nickel, and iron, and drilled for crude oil

  16. 2010 Minerals Yearbook U.S. Department of the Interior

    E-Print Network [OSTI]

    Torgersen, Christian

    . Steelmaking, including its ironmaking component, accounted for most of the reported domestic manganese

  17. 2011 Minerals Yearbook U.S. Department of the Interior

    E-Print Network [OSTI]

    Torgersen, Christian

    . steelmaking, including its ironmaking component, accounted for most of the reported domestic manganese

  18. 2008 Minerals Yearbook U.S. Department of the Interior

    E-Print Network [OSTI]

    Torgersen, Christian

    , including its ironmaking component, accounted for most of the reported domestic manganese consumption

  19. Theoretical Studies of Structures and Mechanisms in Organometallic and Bioinorganic Chemistry: Heck Reaction with Palladium Phosphines, Active Sites of Superoxide Reductase and Cytochrome P450 Monooxygenase, and Tetrairon Hexathiolate Hydrogenase Model

    E-Print Network [OSTI]

    Surawatanawong, Panida

    2010-07-14T23:59:59.000Z

    and formation of (FeIV=O)(SCH3)(L) H2O, and ii) the protonation on proximal oxygen for SOR, which leads to (FeIII-HOOH)(SCH3)(L) formation before the Fe-O bond cleavage and H2O2 production. The hydrogen bonding from explicit waters also stabilizes Fe...

  20. Electronic structure of the dioxygen to transition metal bond: generalized molecular orbital calculations on models of manganese, iron, and cobalt porphyrins

    E-Print Network [OSTI]

    Newton, James Edward

    1982-01-01T23:59:59.000Z

    are reported for FeP where P = porphinato(2-) ~ (NH2)4 , (NHCH2)4 , (N4C2H10) , (N4CBH6) and for Fe(02)PL where P = porphi nato(2-), (NH2)4 , (N4C2H6) and L = imidazole, NH3. The MO calculations indicate that (N4C2H6) is a better model for the porphyri n... ring in metal-dioxygen porphyrin complexes than the model (NH ) . This model was employed in generalized molecular orbital-confi guration interaction calculations of Fe(02)P(NH3), Co(02)P(NH3), and Mn(02)P where P = (N4C2H6) The ozone...

  1. Iron, Manganese and Ruthenium Metal Carbonyls as Photoactive Carbon Monoxide Releasing Molecules (photoCORMS): Ligand Design Strategies, Syntheses and Structure Characterizations

    E-Print Network [OSTI]

    Gonzales, Margarita Andal

    2013-01-01T23:59:59.000Z

    15 , components of dye-sensitized solar cells 16 and ion-components in dye-sensitized solar cells. 2-4 When carbon

  2. Iron, Manganese and Ruthenium Metal Carbonyls as Photoactive Carbon Monoxide Releasing Molecules (photoCORMS): Ligand Design Strategies, Syntheses and Structure Characterizations

    E-Print Network [OSTI]

    Gonzales, Margarita Andal

    2013-01-01T23:59:59.000Z

    L = SBPy 3 , Tpmen [(L)Fe(CO)] n+ [(L)Fe(Solv)] n+ + CO (Eq.1b) Solvent (Solv) MeCN, DMF, H 2 O The stronger tendency ofCl,Cl)- [Ru(Cl) 2 (CO)(solv)(bpy)] adduct. With prolonged

  3. THE INFLUENCE OF LIGAND PARAMETERS ON THE PHOTOLABILITY OF NITRIC OXIDE FROM DESIGNED IRON, MANGANESE, AND RUTHENIUM NITROSYLS UNDER VISIBLE LIGHT

    E-Print Network [OSTI]

    Fry, Nicole L.

    2012-01-01T23:59:59.000Z

    typically exhibits a low-energy (L)Ru-NO + h? + solv ? (L)Ru(III)-solv + NO • absorption band in its electronicin The [(L)Ru(III)(FlEt)(solv)] (L = Me 2 bpb or (OMe) 2

  4. Astrocyte-derived nitric oxide in manganese neurotoxicity: from cellular and molecular mechanisms underlying selective neuronal vulnerability in the basal ganglia to potential therapeutic modalities

    E-Print Network [OSTI]

    Liu, Xuhong

    2007-04-25T23:59:59.000Z

    T: Terminal deoxynucleotidyl Transferase Tf: transferrin TH: tyrosine hydroxylase TIF-2: transcriptional intermediate factor-2 TPN: total parenteral nutrition TUNEL: terminal deoxynucleotidyl transferase-mediated dUTP-biotin nick- end labeling ? m..., and this causes many concerns (Lonnerdal, 1994; Krachler and Rossipal, 2000). Individuals receiving total parenteral nutrition (TPN) are at higher risk for Mn toxicity, because the normal mechanisms of Mn metabolism are bypassed (i.e., the gut), and 100...

  5. Influence of Ga{sup 3+} ions on spectroscopic and dielectric features of multi component lithium lead boro bismuth silicate glasses doped with manganese ions

    SciTech Connect (OSTI)

    Ramesh Babu, P.; Vijay, R. [Department of Physics, Acharya Nagarjuna University, Nagarjunanagar 522510, A.P. (India); Nageswara Rao, P. [Department of Physics, University College of Engg. and Technology, Acharya Nagarjuna University, Nagarjunanagar 522510, A.P. (India); Veeraiah, N. [Department of Physics, Acharya Nagarjuna University, Nagarjunanagar 522510, A.P. (India); Krishna Rao, D., E-mail: krdhanekula@yahoo.co.in [Department of Physics, Acharya Nagarjuna University, Nagarjunanagar 522510, A.P. (India)

    2013-11-15T23:59:59.000Z

    Graphical abstract: The plots between ??(?)? vs. ??(?) and ??(?)/? vs. ??(?) yield straight lines with slope 1/? and ?, respectively. Considerable deviation from the straight line is observed in the high frequency region. Such deviation suggests spreading of relaxation times and this is attributed to the presence of multiple type of dipoles in the glass matrix. Variation of the parameters ???(?) and ??(?)/? with ??(?) of glass Li{sub 2}O–PbO–B{sub 2}O{sub 3}–SiO{sub 2}–Bi{sub 2}O{sub 3}–MnO multi-component glasses mixed with 2.0 mol% of Ga{sub 2}O{sub 3} measured at 373 K. - Highlights: • A series of Li{sub 2}O–PbO–B{sub 2}O{sub 3}–SiO{sub 2}–Bi{sub 2}O{sub 3}–MnO:Ga{sub 2}O{sub 3} glasses have been synthesized. • A variety of spectroscopic and dielectric properties have been investigated. • Analysis of the results indicated that glasses with below 3.0 mol% Ga{sub 2}O{sub 3} are good conducting materials. - Abstract: Multi-component glasses of the chemical composition 19.5Li{sub 2}O–20PbO–20B{sub 2}O{sub 3}–30SiO–(10 ? x)Bi{sub 2}O{sub 3}–0.5MnO:xGa{sub 2}O{sub 3} with 0 ? x ? 5.0 have been synthesized. Spectroscopic (optical absorption, IR, Raman and ESR) and dielectric properties were investigated. Optical absorption and ESR spectral studies have indicated that managanese ions do exist in Mn{sup 3+} state in addition to Mn{sup 2+} state in the samples containing low concentration of Ga{sub 2}O{sub 3}. The IR and Raman studies indicated increasing degree of disorder in the glass network with the concentration of Ga{sub 2}O{sub 3} up to 3.0 mol%. The dielectric constant, loss and ac conductivity are observed to increase with the concentration of Ga{sub 2}O{sub 3} up to 3.0 mol%. The quantitative analysis of the results of dielectric properties has indicated an increase in the insulating strength of the glasses as the concentration of Ga{sub 2}O{sub 3} is raised beyond 3.0 mol%. This has been attributed to adaption of gallium ions from octahedral to tetrahedral coordination.

  6. Long-term stability of organic carbon-stimulated chromate reduction in contaminated soils, and its relation to manganese redox status

    E-Print Network [OSTI]

    Tokunaga, Tetsu K.; Wan, Jiamin; Lanzirotti, Antonio; Sutton, Steve R.; Newville, Matthew; Rao, William

    2007-01-01T23:59:59.000Z

    National Laboratory, Berkeley, California 94720 e 'university of Chicago, Chicago, Illinois 60637 Savannah River

  7. Relationships between chemical forms of soil iron and manganese and their absorption by rice from 34 flooded Gulf Coast soils of Texas

    E-Print Network [OSTI]

    Phillips, Douglas Patton

    1971-01-01T23:59:59.000Z

    measure of the level of reduction of a system. It is given by the electrical potential where an inert electrode, such as platinum or gold, comes in contact with the system (15, 47) . The reduction potential of a system of the type, Oxidant + ne... climatic conditions. All soils were slightly acid to acid with the exception of soil 20. It has been shown that the pH of acid soils increases to approximately neutrality upon constant submergence (41). Soil texture ranged from sandy loam to clay. Most...

  8. Chemical and structural investigation of the role of both Mn and Mn oxide in the formation of manganese silicate barrier layers on SiO{sub 2}

    SciTech Connect (OSTI)

    Casey, P.; Bogan, J.; Hughes, G. [School of Physical Sciences, Dublin City University, Glasnevin, Dublin 9 (Ireland); Lozano, J. G.; Nellist, P. D. [Department of Materials, University of Oxford, Parks Road, Oxford OX1 3PH (United Kingdom)

    2011-09-01T23:59:59.000Z

    In this study, Mn silicate (MnSiO{sub 3}) barrier layers were formed on thermally grown SiO{sub 2} using both metallic Mn and oxidized Mn films, in order to investigate the role of oxygen in determining the extent of the interaction between the deposited Mn and the SiO{sub 2} substrate. Using x-ray photoelectron spectroscopy, it has been shown that a metallic Mn film with an approximate thickness of 1 nm cannot be fully converted to Mn silicate following vacuum annealing to 500 deg. C. Transmission electron microscopy (TEM) analysis suggests the maximum MnSiO{sub 3} layer thickness obtainable using metallic Mn is {approx}1.7 nm. In contrast, a {approx}1 nm partially oxidized Mn film can be fully converted to Mn silicate following thermal annealing to 400 deg. C, forming a MnSiO{sub 3} layer with a measured thickness of 2.6 nm. TEM analysis also clearly shows that MnSiO{sub 3} growth results in a corresponding reduction in the SiO{sub 2} layer thickness. It has also been shown that a fully oxidized Mn oxide thin film can be converted to Mn silicate, in the absence of metallic Mn. Based on these results it is suggested that the presence of Mn oxide species at the Mn/SiO{sub 2} interface facilitates the conversion of SiO{sub 2} to MnSiO{sub 3}, in agreement with previously published studies.

  9. Microstructural analysis of a single pass 2.25% Cr-1.0% Mo steel weld metal with different manganese contents

    SciTech Connect (OSTI)

    Guimares de Souza, Luis Felipe [Centro Federal de Educacao Tecnologica Celso Suckow da Fonseca (CEFET-RJ), Av. Maracana, 229, Rio de Janeiro, RJ, 20271-110 (Brazil); Souza Bott, Ivani de [Pontificia Universidade Catolica (PUC-RIO), R. Marques de SaoVicente, 225, Rio de Janeiro, RJ, 22453-900 (Brazil); Ferreira Jorge, Jorge Carlos [Centro Federal de Educacao Tecnologica Celso Suckow da Fonseca (CEFET-RJ), Av. Maracana, 229, Rio de Janeiro, RJ, 20271-110 (Brazil); Sauer Guimaraes, Ari [Universidade Federal do Rio de Janeiro (COPPE/UFRJ), Caixa Postal 68.505, Cidade Universitaria, Ilha do Fundao, RJ, 21945-970 (Brazil); Pinheiro Rocha Paranhos, Ronaldo [Universidade Estadual do Norte Fluminense (UENF), Av. Alberto Lamego, 2000, Campos, RJ, 28013-602 (Brazil)]. E-mail: paranhos@uenf.br

    2005-07-15T23:59:59.000Z

    Weld metals of the 2.25% Cr-1.0% Mo type with 0.84%, 1.21% and 2.3% Mn produced by submerged-arc welding were analyzed in the as-welded (AW), post weld heat treatment (PWHT) and PWHT followed by step-cooling (SC) heat treatment conditions. Fracture surface analysis revealed an evolution in the mode of fracture due to Mn content variations and heat treatment conditions, the occurrence of intergranular fracture being observed in welds with 2.30% Mn that were step-cooled. Transmission electron microscopy revealed that the microstructure was predominantly composed of bainite, although martensite was also observed for high Mn contents. A marked carbide precipitation was observed, preferentially at grain boundaries. This could be attributed to the SC heat treatment and associated with the embrittlement. However, the application of a de-embrittlement heat treatment to this step cooled weld metal has proved efficient, because the impact energy levels after this heat treatment surpassed those obtained in the stress relieved condition. This indicates that segregation of impurities to grain boundaries was responsible for the low impact energy levels observed after SC of weld metal containing > 0.84% Mn.

  10. Electronic structure of the dioxygen to transition metal bond: generalized molecular orbital calculations on models of manganese, iron, and cobalt porphyrins 

    E-Print Network [OSTI]

    Newton, James Edward

    1982-01-01T23:59:59.000Z

    calculat1on y1elded a I ground. state conf1gurat1on in which the bonding orbital has an occu- pation number of 1. 97 and the antibond1ng orbital has an occupat1on number of 0. 03 electrons. Both Pauling and Griffith geometr1es of Nn(0 )(H C H ) y1... Geometries. Basis sets. . Results Fenske-Hall molecular orbi tal calculations. Restricted Hartree-Fock-Roothaan-Configuration Interaction calculations. 56 58 59 ~ ~ 59 ~ ~ 61 62 62 65 Generalized Molecular Orbi tal-Conf i gurati on Interaction...

  11. Supporting information for Kinetics of Chromium(III) Oxidation by Manganese(IV) Oxides Using Quick Scanning X-Ray Absorption Fine Structure Spectroscopy (Q-XAFS)

    E-Print Network [OSTI]

    Sparks, Donald L.

    H 2.5, 3, and 3.5 Page S-5 to S-7: Figure S5 ­ S5-S1) Effect of Cr concentration S5-S2) Effect of Mn SH 2.5, 3, and 3.5 #12;S-5 Figure S5-S1 #12;S-6 Figure S5-S2 #12;S-7 Figure S5-S3 Figure S5 ­ S5-S1) Effect of Cr concentration ­ pH 2.5; 20 g/L HMO; [Cr(III)]= 100 mM, 80 mM, and 60 mM S5-S2) Effect of Mn

  12. atom. The indium lies almost at the center of gravity of the ring spanned by the five manganese atoms (distance 8.5 pm;

    E-Print Network [OSTI]

    Silverman, Scott K.

    ) in the absence ofmoisture and air. All glass apparatus was evacuated Several times on an oil v'xuiim line and flushed with argon before use. The solvents were dried under argon and freshly distilled. 1: Prepared-63 F,eluent THFjmethanol l0jl). Ayellow and a blue fraction that have not yet been able

  13. Suppression of manganese-dependent production of nitric oxide in astrocytes: implications for therapeutic modulation of glial-derived inflammatory mediators

    E-Print Network [OSTI]

    Wright, Tyler T.

    2009-05-15T23:59:59.000Z

    induction of the nos2 gene, they had no effect on induction of guanosine tri-phosphate cyclohydrolase (GTPCH) the rate limiting enzyme for the production of tetrahydrobiopterin (BH4), a cofactor essential to the conversion of arginine to NO, Thus...

  14. A study of nerve agent model organophosphonate binding with manganese-A2B-corrole and -A2B2-porphyrin systems

    E-Print Network [OSTI]

    Kwak, Juhyoun

    the synthesis and binding studies of novel trans-A2B-corrole and trans-A2B2-porphyrin derivatives are presented: they possess one di- rect pyrrole­pyrrole bond in place of one methine (C­H) linkage, and they are trivalent

  15. Advances in Synthesis of Co- and Ter- Polycarbonates and Polyesters from Non-Petroleum Feedstocks and Kinetic Studies of Ligand Substitution from Manganese Half-Sandwich Complexes

    E-Print Network [OSTI]

    Poland, Ross Rivers

    2012-07-16T23:59:59.000Z

    polycarbonate properties is to produce an epoxide A/epoxide B/CO2 terpolymer, thus allowing more fine "tuning" of properties to what one may desire while simultaneously influencing relative epoxide reactivity to potentially increase catalytic turnovers...

  16. Repeated surveillance of exposure to cadmium, manganese, and arsenic in school-age children living in rural, urban, and nonferrous smelter areas in Belgium

    SciTech Connect (OSTI)

    Buchet, J.P. (Univ. of Louvain, Brussels, Belgium); Roels, H.; Lauwerys, R.; Bruaux, P.; Claeys-Thoreau, F.; Lafontaine, A.; Verduyn, G.

    1980-06-01T23:59:59.000Z

    The intensity of exposure to Cd, As, Mn in groups of school-age children living around a lead smelter was assessed. By comparison, groups of children living in an urban and a rural area were also examined. The metal content of blood, urine, hand-rinsing, air, dust, and dirt collected in the school-playground was compared. The urinary excretion of cadmium in children living around the lead smelter is greater than in those living in the urban and in the rural area. In the latter there seems to exist a time-dependent trend in the renal accumulation of cadmium. This suggests that the overall pollution of the environment by cadmium in Belgium is progressively increasing. In the smelter area, both the oral and pulmonary routes play a role in the children's exposure to cadmium. Their relative contribution to the amount of cadmium absorbed appears similar. The concentration of arsenic in urine of children living around the smelter is significantly higher than that of rural children. Speciation of the chemical forms of arsenic in urine indicates that the difference is not due to different dietary habits of the children examined but to different intensity of exposure to inorganic arsenic. The amount of arsenic on the hand of children living at less than 1 km from the smelter (anti X = 17.6 ..mu..g As/hand) was more than 10 times that found in children living at 2.5 km from the plant (anti X = 1.5 ..mu..g As/hand) whereas that found in children living in urban and rural areas was below 0.2 ..mu..g As/hand. The arsenic concentration of dust and dirt collected in the school-playground in the different areas follows the same trend.

  17. The distribution of copper, manganese, zinc, and iron in antarctic waters and the relation of the concentrations of these metals to biological primary productivity

    E-Print Network [OSTI]

    Arhelger, Martin Edward

    1967-01-01T23:59:59.000Z

    - ? 7 centration of this species is only about 5 x 10 pg/1 (Cooper 193 7b) . The distribution of particulate iron in sea water appears to be rather inhomogeneous, especially near the coast (Cooper 1948a, b; Shaefer and Bishop 1958), but may be more... to the ferrous ion, have been described by Diehl and Smith (1960). None of the ions present in sea water at their normal concentrations interfere with these 12 reagents. Dipyridyl and tripyridyl were used by Cooper (1937a, b) in the English Channel...

  18. Effects of iron and manganese in culture solution on their concentrations in roots and shoots of rice plants (Oryza sativa L.) grown under anaerobic conditions

    E-Print Network [OSTI]

    Bacha, Richard E

    1976-01-01T23:59:59.000Z

    into pots containing sand with varying Fe and Mn concentrations which were established by the addition of soluble Fe and Mn salts. Solution concentrations of Fe and Mn were monitored through a 30-day growth period of the plants. Solution concentrations... of Fe varied from 0. 5 to 50. 5 ppm; whereas Mn concen- trations ranged from 0. 1 to 12. 5 ppm. Variations in solution concen- trations of Fe and Mn over time were obtained. Initial high concentrations (50. 5 ppm Fe and 12. 5 ppm Mn) in solution...

  19. Iron, Manganese and Ruthenium Metal Carbonyls as Photoactive Carbon Monoxide Releasing Molecules (photoCORMS): Ligand Design Strategies, Syntheses and Structure Characterizations

    E-Print Network [OSTI]

    Gonzales, Margarita Andal

    2013-01-01T23:59:59.000Z

    is due to the bound acetonitrile ligands. Figure 3.II.21. IR2 (qmtpm)(PPh 3 )]ClO 4 in acetonitrile xi Figure 3.II.7.CO) 2 (qmtpm)]ClO 4 in acetonitrile Figure 3.II.8. Changes

  20. Reactive oxygen species mediate arsenic induced cell transformation and tumorigenesis through Wnt/{beta}-catenin pathway in human colorectal adenocarcinoma DLD1 cells

    SciTech Connect (OSTI)

    Zhang Zhuo [Department of Preventive Medicine and Environmental Health, University of Kentucky, 121 Washington Avenue, Lexington, KY 40536 (United States); Wang Xin; Cheng Senping; Sun Lijuan; Son, Young-Ok [Graduate Center for Toxicology, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Yao Hua [Department of Stomatology, The First Affiliated Hospital, College of Medicine, Zhejiang University, Hangzhou, Zhejiang 310003 (China); Li Wenqi [Department of Preventive Medicine and Environmental Health, University of Kentucky, 121 Washington Avenue, Lexington, KY 40536 (United States); Budhraja, Amit [Graduate Center for Toxicology, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Li Li [Department of Family Medicine, Case Western Reserve University, Cleveland, OH 44106 (United States); Shelton, Brent J.; Tucker, Thomas [Markey Cancer Control Program, University of Kentucky, 2365 Harrodsburg Rd, Lexington, KY 40504 (United States); Arnold, Susanne M. [Markey Cancer Center, University of Kentucky, 800 Rose street, Lexington, KY 40536 (United States); Shi Xianglin, E-mail: Xianglin.sh@uky.edu [Graduate Center for Toxicology, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States)

    2011-10-15T23:59:59.000Z

    Long term exposure to arsenic can increase incidence of human cancers, such as skin, lung, and colon rectum. The mechanism of arsenic induced carcinogenesis is still unclear. It is generally believed that reactive oxygen species (ROS) may play an important role in this process. In the present study, we investigate the possible linkage between ROS, {beta}-catenin and arsenic induced transformation and tumorigenesis in human colorectal adenocarcinoma cell line, DLD1 cells. Our results show that arsenic was able to activate p47{sup phox} and p67{sup phox}, two key proteins for activation of NADPH oxidase. Arsenic was also able to generate ROS in DLD1 cells. Arsenic increased {beta}-catenin expression level and its promoter activity. ROS played a major role in arsenic-induced {beta}-catenin activation. Treatment of DLD1 cells by arsenic enhanced both transformation and tumorigenesis of these cells. The tumor volumes of arsenic treated group were much larger than those without arsenic treatment. Addition of either superoxide dismutase (SOD) or catalase reduced arsenic induced cell transformation and tumor formation. The results indicate that ROS are involved in arsenic induced cell transformation and tumor formation possible through Wnt/{beta}-catenin pathway in human colorectal adenocarcinoma cell line DLD1 cells. - Highlights: > Arsenic activates NADPH oxidase and increases reactive oxygen species generation in DLD1 cells. > Arsenic increases {beta}-catenin expression. > Inhibition of ROS induced by arsenic reduce {beta}-catenin expression. > Arsenic increases cell transformation in DLD1 cells and tumorigenesis in nude mice. > Blockage of ROS decrease cell transformation and tumorigenesis induced by arsenic.

  1. The effect of copper deficiency on fetal growth and liver anti-oxidant capacity in the Cohen diabetic rat model

    SciTech Connect (OSTI)

    Ergaz, Zivanit, E-mail: zivanit@hadassah.org.il [Hebrew University Hadassah Medical School, Jerusalem (Israel)] [Hebrew University Hadassah Medical School, Jerusalem (Israel); Shoshani-Dror, Dana [Hebrew University Hadassah Medical School, Jerusalem (Israel)] [Hebrew University Hadassah Medical School, Jerusalem (Israel); Guillemin, Claire [Department of Pharmacology and Therapeutics, McGill University, Montreal (Canada)] [Department of Pharmacology and Therapeutics, McGill University, Montreal (Canada); Neeman-azulay, Meytal; Fudim, Liza [Hebrew University Hadassah Medical School, Jerusalem (Israel)] [Hebrew University Hadassah Medical School, Jerusalem (Israel); Weksler-Zangen, Sarah [Diabetes Research Unit, Hebrew University Hadassah Medical School and Hospital, Jerusalem (Israel)] [Diabetes Research Unit, Hebrew University Hadassah Medical School and Hospital, Jerusalem (Israel); Stodgell, Christopher J.; Miller, Richard K. [Department of Obstetrics and Gynecology, University of Rochester, Rochester, MN (United States)] [Department of Obstetrics and Gynecology, University of Rochester, Rochester, MN (United States); Ornoy, Asher [Hebrew University Hadassah Medical School, Jerusalem (Israel)] [Hebrew University Hadassah Medical School, Jerusalem (Israel)

    2012-12-01T23:59:59.000Z

    High sucrose low copper diet induces fetal growth restriction in the three strains of the Cohen diabetic rats: an inbred copper deficient resistant (CDr), an inbred copper deficient sensitive (CDs that become diabetic on high sucrose low copper diet -HSD) and an outbred Wistar derived Sabra rats. Although those growth restricted fetuses also exhibit increased oxidative stress, antioxidants do not restore normal growth. In the present study, we evaluated the role of copper deficiency in the HSD induced fetal growth restriction by adding to the drinking water of the rats 1 ppm or 2 ppm of copper throughout their pregnancy. Fetal and placental growth in correlation with fetal liver copper content and anti-oxidant capacity was evaluated on day 21 of pregnancy. HSD compared to regular chow induced fetal growth restriction, which was most significant in the Cohen diabetic sensitive animals. The addition of 1 ppm and 2 ppm copper to the drinking water normalized fetal growth in a dose dependent manner and reduced the degree of hyperglycemia in the diabetes sensitive rats. The CDs fetuses responded to the HSD with lower catalase like activity, and less reduced superoxide dismutase levels compared to the Sabra strain, and had high malondialdehyde levels even when fed regular chow. Immunostaining was higher for nitrotyrosine among the CDr and higher for hypoxia factor 1 ? among the CDs. We conclude that in our model of dietary-induced fetal growth restriction, copper deficiency plays a major etiologic role in the decrease of fetal growth and anti-oxidant capacity. -- Highlights: ? High sucrose low copper diet restricted fetal growth in the Cohen diabetic rat model ? Maternal copper blood levels directly correlated with fetal liver copper content ? Copper supplementation decreased embryonic resorption in the inbred strains ? Copper supplementation reduced hyperglycemia in the sucrose sensitive inbred strain ? Copper supplementation alleviated growth restriction and oxidative stress of liver.

  2. Omega-3 polyunsaturated fatty acid has an anti-oxidant effect via the Nrf-2/HO-1 pathway in 3T3-L1 adipocytes

    SciTech Connect (OSTI)

    Kusunoki, Chisato, E-mail: yosizaki@belle.shiga-med.ac.jp [Department of Medicine, Shiga University of Medical Science, Seta Tsukinowa-Cho, Otsu, Shiga 520-2192 (Japan)] [Department of Medicine, Shiga University of Medical Science, Seta Tsukinowa-Cho, Otsu, Shiga 520-2192 (Japan); Yang, Liu; Yoshizaki, Takeshi; Nakagawa, Fumiyuki; Ishikado, Atsushi; Kondo, Motoyuki; Morino, Katsutaro; Sekine, Osamu; Ugi, Satoshi [Department of Medicine, Shiga University of Medical Science, Seta Tsukinowa-Cho, Otsu, Shiga 520-2192 (Japan)] [Department of Medicine, Shiga University of Medical Science, Seta Tsukinowa-Cho, Otsu, Shiga 520-2192 (Japan); Nishio, Yoshihiko [Division of Diabetes, Metabolism and Endocrinology, Department of Graduate School of Medical and Dental Sciences, Kagoshima University, 8-35-1 Sakuragaoka, Kagoshima 890-8544 (Japan)] [Division of Diabetes, Metabolism and Endocrinology, Department of Graduate School of Medical and Dental Sciences, Kagoshima University, 8-35-1 Sakuragaoka, Kagoshima 890-8544 (Japan); Kashiwagi, Atsunori; Maegawa, Hiroshi [Department of Medicine, Shiga University of Medical Science, Seta Tsukinowa-Cho, Otsu, Shiga 520-2192 (Japan)] [Department of Medicine, Shiga University of Medical Science, Seta Tsukinowa-Cho, Otsu, Shiga 520-2192 (Japan)

    2013-01-04T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Omega-3 PUFA has a direct anti-oxidant effect in adipocytes. Black-Right-Pointing-Pointer EPA and DHA induce HO-1 expression in 3T3-L1 adipocytes. Black-Right-Pointing-Pointer Omega-3 PUFA and its end-product, 4-HHE, activates the Nrf-2/HO-1 pathway. Black-Right-Pointing-Pointer Omega-3 PUFA protects against oxidative stress-induced cytotoxicity. -- Abstract: Oxidative stress is produced in adipose tissue of obese subjects and has been associated with obesity-related disorders. Recent studies have shown that omega-3 polyunsaturated fatty acid ({omega}3-PUFA) has beneficial effects in preventing atherosclerotic diseases and insulin resistance in adipose tissue. However, the role of {omega}3-PUFA on adipocytes has not been elucidated. In this study, 3T3-L1 adipocytes were treated with {omega}3-PUFA and its metabolites, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), or 4-hydroxy hexenal (4-HHE). {omega}3-PUFA and its metabolites dose-dependently increased mRNA and protein levels of the anti-oxidative enzyme, heme oxygenase-1 (HO-1); whereas no changes in the well-known anti-oxidant molecules, superoxide dismutase, catalase, and glutathione peroxidase, were observed. Knockdown of nuclear factor erythroid 2-related factor 2 (Nrf-2) significantly reduced EPA, DHA or 4-HHE-induced HO-1 mRNA and protein expression. Also, pretreatment with {omega}3-PUFA prevented H{sub 2}O{sub 2}-induced cytotoxicity in a HO-1 dependent manner. In conclusion, treatment with EPA and DHA induced HO-1 through the activation of Nrf-2 and prevented oxidative stress in 3T3-L1 adipocytes. This anti-oxidant defense may be of high therapeutic value for clinical conditions associated with systemic oxidative stress.

  3. Hyperoside attenuates hydrogen peroxide-induced L02 cell damage via MAPK-dependent Keap{sub 1}-Nrf{sub 2}-ARE signaling pathway

    SciTech Connect (OSTI)

    Xing, Hai-Yan; Liu, Yao; Chen, Jian-Hong; Sun, Feng-Jun; Shi, Hui-Qing [Department of Pharmacy, Southwest Hospital, Third Military Medical University, Chongqing 400038 (China)] [Department of Pharmacy, Southwest Hospital, Third Military Medical University, Chongqing 400038 (China); Xia, Pei-Yuan, E-mail: py_xia@yahoo.com.cn [Department of Pharmacy, Southwest Hospital, Third Military Medical University, Chongqing 400038 (China)] [Department of Pharmacy, Southwest Hospital, Third Military Medical University, Chongqing 400038 (China)

    2011-07-15T23:59:59.000Z

    Highlights: {yields} Hyperoside attenuated H{sub 2}O{sub 2}-induced L02 cell damage. {yields} Hyperoside up-regulated HO-1 expression at both mRNA and protein levels. {yields} Hyperoside activated both Nrf{sub 2} nuclear translocation and gene expression. {yields} Hyperoside may inhibit Keap{sub 1} mRNA translation or protein degradation. {yields} Phosphorylation of ERK and p38 is involved in hyperoside-mediated Nrf{sub 2} activation. -- Abstract: The flavonoid hyperoside has been reported to elicit cytoprotection against oxidative stress partly by increasing the activity of antioxidant enzymes, such as glutathione peroxidase, superoxide dismutase and catalase. However, the cellular and molecular mechanisms underlying this effect remain unclear. Here, hepatic L02 cells exposed to H{sub 2}O{sub 2} (100 {mu}M) were used to demonstrate that hyperoside protected cells by significantly inhibiting overproduction of intracellular ROS, depletion of the mitochondrial membrane potential and leakage of lactate dehydrogenase. Hyperoside further enhanced the cellular antioxidant defense system through increasing the activity of heme oxygenase-1 (HO-1), and by up-regulating HO-1 expression. Meanwhile, real time PCR, western blot and immunofluorescence studies revealed that hyperoside stimulated nuclear translocation of the Nrf{sub 2} transcription factor in a dose-dependent manner, and this effect was significantly suppressed by pharmacological inhibition of the mitogen-activated protein kinases (MAPK) p38 and ERK. Collectively, our data provide the first description of the mechanism underlying hyperoside's ability to attenuate H{sub 2}O{sub 2}-induced cell damage, namely this compound interacts with the MAPK-dependent Keap{sub 1}-Nrf{sub 2}-ARE signaling pathway to up-regulate HO-1 expression and enhance intracellular antioxidant activity.

  4. Metal, mutagenicity, and biochemical studies on bivalve molluscs from Spanish coasts

    SciTech Connect (OSTI)

    Rodriguez-Ariza, A.; Abril, N.; Navas, J.I.; Dorado, G.; Lopez-Barea, J.; Pueyo, C. (Departmento de Genetica, Facultad de Ciencias, Universidad de Cordoba, (Spain))

    1992-01-01T23:59:59.000Z

    Three species of marine bivalve molluscs (Chamelea gallina, Ruditapes decussatus, and Crassostrea gigas) have been studied in order to evaluate the levels of pollution on the South Atlantic Spanish littoral. Several transition metals (Cu, As, Cd, Sn, Hg, Pb) were determined as a general index of total contamination. Animals from putative contaminated areas exhibited higher metal contents than those from cleaner waters. C. gigas showed 5-20-fold higher total metal content than the other two species. The mutagenicity of ethanolic extracts was assayed by using both the His reversion and the Ara forward mutation tests. Mollusc tissues from the three species did not contain genotoxins active on TA98 (frameshift mutations) or TA100 (mainly G:C base-pair substitutions), but did contain direct-acting genotoxins of a polar nature and oxidative type. This was based on the following observations: (1) mammalian metabolic activation was not required for mutagenicity, (2) mutagens were eluted with the polar fraction from XAD-2 columns, and (3) mutagenic responses were observed with Salmonella typhimurium TA102 (base-pair substitutions; sensitive to oxidative damages) and Escherichia coli catalase-deficient (AraR forward mutations) strains. No relevant differences were found in the mutagenicity of mollusc extracts from areas with different pollution levels. Otherwise, our data suggest that, in general, animals living in contaminated environments had fewer genotoxins of oxidative type than those from less polluted areas. Such a result might be explained by the observation of increased levels of a number of detoxifying and antioxidant enzymes, such as glutathione-S-transferase, glutathione-peroxidase, catalase, and superoxide dismutase.

  5. Silver nanoparticles induced heat shock protein 70, oxidative stress and apoptosis in Drosophila melanogaster

    SciTech Connect (OSTI)

    Ahamed, Maqusood; Posgai, Ryan; Gorey, Timothy J.; Nielsen, Mark [Department of Biology, Center for Tissue Regeneration and Engineering, University of Dayton, Dayton, OH 45469 (United States); Hussain, Saber M. [Applied Biotechnology Branch, Human Effectiveness Directorate, Air Force Research Laboratory, Wright-Patterson Air Force Base, Dayton, OH 45433 (United States); Rowe, John J., E-mail: John.Rowe@notes.udayton.ed [Department of Biology, Center for Tissue Regeneration and Engineering, University of Dayton, Dayton, OH 45469 (United States)

    2010-02-01T23:59:59.000Z

    Due to the intensive commercial application of silver nanoparticles (Ag NPs), risk assessment of this nanoparticle is of great importance. Our previous in vitro study demonstrated that Ag NPs caused DNA damage and apoptosis in mouse embryonic stem cells and fibroblasts. However, toxicity of Ag NPs in vivo is largely lacking. This study was undertaken to examine the toxic effects of well-characterized polysaccharide coated 10 nm Ag NPs on heat shock stress, oxidative stress, DNA damage and apoptosis in Drosophila melanogaster. Third instar larvae of D. melanogaster were fed a diet of standard cornmeal media mixed with Ag NPs at the concentrations of 50 and 100 mug/ml for 24 and 48 h. Ag NPs up-regulated the expression of heat shock protein 70 and induced oxidative stress in D. melanogaster. Malondialdehyde level, an end product of lipid peroxidation was significantly higher while antioxidant glutathione content was significantly lower in Ag NPs exposed organisms. Activities of antioxidant enzyme superoxide dismutase and catalase were also significantly higher in the organisms exposed to Ag NPs. Furthermore, Ag NPs up-regulated the cell cycle checkpoint p53 and cell signaling protein p38 that are involved in the DNA damage repair pathway. Moreover, activities of caspase-3 and caspase-9, markers of apoptosis were significantly higher in Ag NPs exposed organisms. The results indicate that Ag NPs in D. melanogaster induce heat shock stress, oxidative stress, DNA damage and apoptosis. This study suggests that the organism is stressed and thus warrants more careful assessment of Ag NPs using in vivo models to determine if chronic exposure presents developmental and reproductive toxicity.

  6. The Architecture of the Qo Site of Cytochrome bc1 Complex Probed...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Architecture of the Qo Site of Cytochrome bc1 Complex Probed by Superoxide Production. The Architecture of the Qo Site of Cytochrome bc1 Complex Probed by Superoxide Production....

  7. Activation of sulfonate ester based matrix metalloproteinase proinhibitors by hydrogen peroxide

    E-Print Network [OSTI]

    Daniel, Kevin B.; Major Jourden, Jody L.; Negoescu, Kimberly E.; Cohen, Seth M.

    2011-01-01T23:59:59.000Z

    proinhibitors by hydrogen peroxide Kevin B. Daniel • Jody L.for detecting several ROS (hydrogen peroxide, superoxide

  8. Effect of Titanium Substitution on the Compatiblity of Electrodes with Pyrrolidinium-Based Ionic Liquid Electrolytes

    E-Print Network [OSTI]

    Saint, Juliette A.; Shin, Joon-Ho; Best, Adam; Hollenkamp, Anthony; Kerr, John; Doeff, Marca M.

    2008-01-01T23:59:59.000Z

    part of the manganese for titanium [Figure References: [1]Effect of Titanium Substitution on the Compatibility of

  9. Ductile aluminide alloys for high temperature applications

    DOE Patents [OSTI]

    Liu, Chain T. (Oak Ridge, TN); Koch, Carl C. (Oak Ridge, TN)

    1987-01-01T23:59:59.000Z

    Alloys are described which contain nickel, aluminum, boron, iron and in some instances manganese, niobium and titanium.

  10. am501650q 1..8

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a symmetric suspension electrode based on activated carbon. KEYWORDS: asymmetric supercapacitor, electrochemical flow capacitor, flowable electrode, manganese oxide, percolating...

  11. DISCRETE SYNCHRONIZATION UNDER THE HIERARCHICAL VIEW POINT CAMILLE POIGNARD

    E-Print Network [OSTI]

    .Shechtman discovered the existence of a solid (an aluminium-manganese alloy) presenting a 5-fold symmetry in its

  12. Cast B2-phase iron-aluminum alloys with improved fluidity

    DOE Patents [OSTI]

    Maziasz, Philip J. (122 Clark La., Oak Ridge, TN 37830); Paris, Alan M. (P.O. Box 64, Tarrs, PA 15688); Vought, Joseph D. (124 Cove Point Rd., Rockwood, TN 37854)

    2002-01-01T23:59:59.000Z

    Systems and methods are described for iron aluminum alloys. A composition includes iron, aluminum and manganese. A method includes providing an alloy including iron, aluminum and manganese; and processing the alloy. The systems and methods provide advantages because additions of manganese to iron aluminum alloys dramatically increase the fluidity of the alloys prior to solidification during casting.

  13. Arkansas Water Resources Center

    E-Print Network [OSTI]

    Soerens, Thomas

    Arkan- sas in order to determine the effect of local manganese, phosphate, pyrite, lead-zinc and uranium manganese district. Hydrogeochemical exploration for these types of manganese deposits appears possible .,.:;, Water Quality. 18 Comparison of Water Chemistry. 27 Geochemical Exploration. 30 Four Minera 1i zed Areas

  14. Making Lemonade: Using Graffiti to Date Petroglyphs James A. McNeil

    E-Print Network [OSTI]

    abundance and geological events. Using x-ray fluorescence (XRF), they also measured manganese levels petroglyphs in the using non-destructive field-based XRF measurements. In this work we also use XRF to measure-ray fluorescence (XRF) measurements of manganese accumulation in petroglyphs. The hope is that if the manganese

  15. Comparative developmental toxicity of environmentally relevant oxygenated PAHs

    SciTech Connect (OSTI)

    Knecht, Andrea L., E-mail: andrea.knecht@tanguaylab.com [Department of Environmental and Molecular Toxicology, the Environmental Health Sciences Center, Oregon State University, Corvallis, OR (United States); Goodale, Britton C., E-mail: goodaleb@onid.orst.edu [Department of Environmental and Molecular Toxicology, the Environmental Health Sciences Center, Oregon State University, Corvallis, OR (United States); Truong, Lisa, E-mail: lisa.truong.888@gmail.com [Department of Environmental and Molecular Toxicology, the Environmental Health Sciences Center, Oregon State University, Corvallis, OR (United States); Simonich, Michael T., E-mail: mtsimonich@oregonstate.edu [Department of Environmental and Molecular Toxicology, the Environmental Health Sciences Center, Oregon State University, Corvallis, OR (United States); Swanson, Annika J., E-mail: swansoan@onid.orst.edu [Department of Environmental and Molecular Toxicology, the Environmental Health Sciences Center, Oregon State University, Corvallis, OR (United States); Matzke, Melissa M., E-mail: melissa.matzke@pnl.gov [Computational Biology and Bioinformatics, Pacific Northwest National Laboratory, Richland, WA (United States); Anderson, Kim A., E-mail: kim.anderson@oregonstate.edu [Department of Environmental and Molecular Toxicology, the Environmental Health Sciences Center, Oregon State University, Corvallis, OR (United States); Waters, Katrina M., E-mail: katrina.waters@pnl.gov [Computational Biology and Bioinformatics, Pacific Northwest National Laboratory, Richland, WA (United States); Tanguay, Robert L., E-mail: robert.tanguay@oregonstate.edu [Department of Environmental and Molecular Toxicology, the Environmental Health Sciences Center, Oregon State University, Corvallis, OR (United States)

    2013-09-01T23:59:59.000Z

    Oxygenated polycyclic aromatic hydrocarbons (OPAHs) are byproducts of combustion and photo-oxidation of parent PAHs. OPAHs are widely present in the environment and pose an unknown hazard to human health. The developing zebrafish was used to evaluate a structurally diverse set of 38 OPAHs for malformation induction, gene expression changes and mitochondrial function. Zebrafish embryos were exposed from 6 to 120 h post fertilization (hpf) to a dilution series of 38 different OPAHs and evaluated for 22 developmental endpoints. AHR activation was determined via CYP1A immunohistochemistry. Phenanthrenequinone (9,10-PHEQ), 1,9-benz-10-anthrone (BEZO), xanthone (XAN), benz(a)anthracene-7,12-dione (7,12-B[a]AQ), and 9,10-anthraquinone (9,10-ANTQ) were evaluated for transcriptional responses at 48 hpf, prior to the onset of malformations. qRT-PCR was conducted for a number of oxidative stress genes, including the glutathione transferase(gst), glutathione peroxidase(gpx), and superoxide dismutase(sod) families. Bioenergetics was assayed to measure in vivo oxidative stress and mitochondrial function in 26 hpf embryos exposed to OPAHs. Hierarchical clustering of the structure-activity outcomes indicated that the most toxic of the OPAHs contained adjacent diones on 6-carbon moieties or terminal, para-diones on multi-ring structures. 5-carbon moieties with adjacent diones were among the least toxic OPAHs while the toxicity of multi-ring structures with more centralized para-diones varied considerably. 9,10-PHEQ, BEZO, 7,12-B[a]AQ, and XAN exposures increased expression of several oxidative stress related genes and decreased oxygen consumption rate (OCR), a measurement of mitochondrial respiration. Comprehensive in vivo characterization of 38 structurally diverse OPAHs indicated differential AHR dependency and a prominent role for oxidative stress in the toxicity mechanisms. - Highlights: • OPAHs are byproducts of combustion present in the environment. • OPAHs pose a largely unknown hazard to human health. • We assayed the developmental toxicology of 39 different OPAHs in zebrafish. • The most toxic OPAHs contained adjacent diones or terminal, para-diones. • AHR dependency varied among OPAHs, and oxidative stress influenced their toxicology.

  16. Quercetin 3-O-methyl ether protects FL83B cells from copper induced oxidative stress through the PI3K/Akt and MAPK/Erk pathway

    SciTech Connect (OSTI)

    Tseng, Hsiao-Ling, E-mail: lily1001224@gmail.com [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China)] [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China); Li, Chia-Jung, E-mail: 97751101@stmail.tcu.edu.tw [Institute of Medical Sciences, Tzu Chi University, Hualien, Taiwan (China)] [Institute of Medical Sciences, Tzu Chi University, Hualien, Taiwan (China); Huang, Lin-Huang, E-mail: yg1236@yahoo.com.tw [School of Medicine, Institute of Traditional Medicine, National Yang-Ming University, Taipei, Taiwan (China)] [School of Medicine, Institute of Traditional Medicine, National Yang-Ming University, Taipei, Taiwan (China); Chen, Chun-Yao, E-mail: cychen@mail.tcu.edu.tw [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China)] [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China); Tsai, Chun-Hao, E-mail: 100726105@stmail.tcu.edu.tw [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China)] [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China); Lin, Chun-Nan, E-mail: lincna@cc.kmu.edu.tw [Faculty of Pharmacy, College of Pharmacy, Kaohsiung Medical University, Kaohsiung, Taiwan (China) [Faculty of Pharmacy, College of Pharmacy, Kaohsiung Medical University, Kaohsiung, Taiwan (China); Department of Biological Science and Technology, School of Medicine, China Medical University, Taichung, Taiwan (China); Hsu, Hsue-Yin, E-mail: hsueyin@mail.tcu.edu.tw [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China)] [Department of Life Sciences, Tzu Chi University, Hualien, Taiwan (China)

    2012-10-01T23:59:59.000Z

    Quercetin is a bioflavonoid that exhibits several biological functions in vitro and in vivo. Quercetin 3-O-methyl ether (Q3) is a natural product reported to have pharmaceutical activities, including antioxidative and anticancer activities. However, little is known about the mechanism by which it protects cells from oxidative stress. This study was designed to investigate the mechanisms by which Q3 protects against Cu{sup 2+}-induced cytotoxicity. Exposure to Cu{sup 2+} resulted in the death of mouse liver FL83B cells, characterized by apparent apoptotic features, including DNA fragmentation and increased nuclear condensation. Q3 markedly suppressed Cu{sup 2+}-induced apoptosis and mitochondrial dysfunction, characterized by reduced mitochondrial membrane potential, caspase-3 activation, and PARP cleavage, in Cu{sup 2+}-exposed cells. The involvement of PI3K, Akt, Erk, FOXO3A, and Mn-superoxide dismutase (MnSOD) was shown to be critical to the survival of Q3-treated FL83B cells. The liver of both larval and adult zebrafish showed severe damage after exposure to Cu{sup 2+} at a concentration of 5 ?M. Hepatic damage induced by Cu{sup 2+} was reduced by cotreatment with Q3. Survival of Cu{sup 2+}-exposed larval zebrafish was significantly increased by cotreatment with 15 ?M Q3. Our results indicated that Cu{sup 2+}-induced apoptosis in FL83B cells occurred via the generation of ROS, upregulation and phosphorylation of Erk, overexpression of 14-3-3, inactivation of Akt, and the downregulation of FOXO3A and MnSOD. Hence, these results also demonstrated that Q3 plays a protective role against oxidative damage in zebrafish liver and remarked the potential of Q3 to be used as an antioxidant for hepatocytes. Highlights: ? Protective effects of Q3 on Cu{sup 2+}-induced oxidative stress in vitro and in vivo. ? Cu{sup 2+} induced apoptosis in FL83B cells via ROS and the activation of Erk. ? Q3 abolishes Cu{sup 2+}-induced apoptosis through the PI3K/Akt and MAPK/Erk pathway.

  17. Systemic inflammatory changes and increased oxidative stress in rural Indian women cooking with biomass fuels

    SciTech Connect (OSTI)

    Dutta, Anindita, E-mail: anidu14@gmail.com [College of Environmental Sciences and Engineering, Peking University, Beijing (China) [College of Environmental Sciences and Engineering, Peking University, Beijing (China); Department of Experimental Hematology, Chittaranjan National Cancer Institute, 37, S.P. Mukherjee Road, Kolkata-700 026 (India); Ray, Manas Ranjan; Banerjee, Anirban [Department of Experimental Hematology, Chittaranjan National Cancer Institute, 37, S.P. Mukherjee Road, Kolkata-700 026 (India)] [Department of Experimental Hematology, Chittaranjan National Cancer Institute, 37, S.P. Mukherjee Road, Kolkata-700 026 (India)

    2012-06-15T23:59:59.000Z

    The study was undertaken to investigate whether regular cooking with biomass aggravates systemic inflammation and oxidative stress that might result in increase in the risk of developing cardiovascular disease (CVD) in rural Indian women compared to cooking with a cleaner fuel like liquefied petroleum gas (LPG). A total of 635 women (median age 36 years) who cooked with biomass and 452 age-matched control women who cooked with LPG were enrolled. Serum interleukin-6 (IL-6), C-reactive protein (CRP), tumor necrosis factor-alpha (TNF-?) and interleukin-8 (IL-8) were measured by ELISA. Generation of reactive oxygen species (ROS) by leukocytes was measured by flow cytometry, and erythrocytic superoxide dismutase (SOD) was measured by spectrophotometry. Hypertension was diagnosed following the Seventh Report of the Joint Committee. Tachycardia was determined as pulse rate > 100 beats per minute. Particulate matter of diameter less than 10 and 2.5 ?m (PM{sub 10} and PM{sub 2.5}, respectively) in cooking areas was measured using real-time aerosol monitor. Compared with control, biomass users had more particulate pollution in indoor air, their serum contained significantly elevated levels of IL-6, IL-8, TNF-? and CRP, and ROS generation was increased by 37% while SOD was depleted by 41.5%, greater prevalence of hypertension and tachycardia compared to their LPG-using neighbors. PM{sub 10} and PM{sub 2.5} levels were positively associated with markers of inflammation, oxidative stress and hypertension. Inflammatory markers correlated with raised blood pressure. Cooking with biomass exacerbates systemic inflammation, oxidative stress, hypertension and tachycardia in poor women cooking with biomass fuel and hence, predisposes them to increased risk of CVD development compared to the controls. Systemic inflammation and oxidative stress may be the mechanistic factors involved in the development of CVD. -- Highlights: ? Effect of chronic biomass smoke exposure on cardiovascular health was investigated. ? Serum markers of systemic inflammation and oxidative stress were studied. ? Biomass using women had increased systemic inflammation and oxidative stress. ? Indoor air pollution and observed changes were positively associated.

  18. Activation of protein kinase B (PKB/Akt) and risk of lung cancer among rural women in India who cook with biomass fuel

    SciTech Connect (OSTI)

    Roychoudhury, Sanghita; Mondal, Nandan Kumar; Mukherjee, Sayali; Dutta, Anindita; Siddique, Shabana; Ray, Manas Ranjan, E-mail: manasrray@rediffmail.com

    2012-02-15T23:59:59.000Z

    The impact of indoor air pollution (IAP) from biomass fuel burning on the risk of carcinogenesis in the airways has been investigated in 187 pre-menopausal women (median age 34 years) from eastern India who cooked exclusively with biomass and 155 age-matched control women from same locality who cooked with cleaner fuel liquefied petroleum gas. Compared with control, Papanicolau-stained sputum samples showed 3-times higher prevalence of metaplasia and 7-times higher prevalence of dysplasia in airway epithelial cell (AEC) of biomass users. Immunocytochemistry showed up-regulation of phosphorylated Akt (p-Akt{sup ser473} and p-Akt{sup thr308}) proteins in AEC of biomass users, especially in metaplastic and dysplastic cells. Compared with LPG users, biomass-using women showed marked rise in reactive oxygen species (ROS) generation and depletion of antioxidant enzyme, superoxide dismutase (SOD) indicating oxidative stress. There were 2–5 times more particulate pollutants (PM{sub 10} and PM{sub 2.5}), 72% more nitrogen dioxide and 4-times more particulate-laden benzo(a)pyrene, but no change in sulfur dioxide in indoor air of biomass-using households, and high performance liquid chromatography estimated 6-fold rise in the concentration of benzene metabolite trans,trans-muconic acid (t,t-MA) in urine of biomass users. Metaplasia and dysplasia, p-Akt expression and ROS generation were positively associated with PM and t,t-MA levels. It appears that cumulative exposure to biomass smoke increases the risk of lung carcinogenesis via oxidative stress-mediated activation of Akt signal transduction pathway. -- Highlights: ? Carcinogenesis in airway cells was examined in biomass and LPG using women. ? Metaplasia and dysplasia of epithelial cells were more prevalent in biomass users. ? Change in airway cytology was associated with oxidative stress and Akt activation. ? Biomass users had greater exposure to respirable PM, B(a)P and benzene. ? Cooking with biomass increases cancer risk in the airways via Akt activation.

  19. Ferruginous layers in sediments from the Gulf of Mexico

    E-Print Network [OSTI]

    Watson, Jerry Allan

    1968-01-01T23:59:59.000Z

    of iron, manganese, cobalt, and nickel is 66, 33, 5l, and Zg percent, re- spectively. The yellow, iron-rich sediments commonly occur in the Pleistocene-Holocene transition zone and in the upper Pleistocene sediments. The iron-rich zones are interpreted... OF FIGURES LIST OF TABLES CHAPTER I INTRODUCTION Location CHAPTER II LITERATURE REVIEW Red or Yellow Sediments Iron, Manganese, Cobalt and Nickel Iron Manganese Cobalt and Nickel CHAPTER III EXPERIMENTAL PROCEDURE Preparation of Samples Solution...

  20. antagonizes cardiac hypertrophy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hypertrophy, ie, angiotensin II and isoproterenol infusions in mice. Angiotensin II infusion for 14 days215505) prevented the increase in cardiac superoxide generation and...

  1. angiotensin ii-induced cardiac: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hypertrophy, ie, angiotensin II and isoproterenol infusions in mice. Angiotensin II infusion for 14 days215505) prevented the increase in cardiac superoxide generation and...

  2. attenuates cardiac hypertrophy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hypertrophy, ie, angiotensin II and isoproterenol infusions in mice. Angiotensin II infusion for 14 days215505) prevented the increase in cardiac superoxide generation and...

  3. angiotensin ii-infused mice: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    hypertrophy, ie, angiotensin II and isoproterenol infusions in mice. Angiotensin II infusion for 14 days215505) prevented the increase in cardiac superoxide generation and...

  4. Hydrogen-peroxide-induced oxidative stress responses in Desulfovibrio vulgaris Hildenborough

    E-Print Network [OSTI]

    Zhou, A.

    2010-01-01T23:59:59.000Z

    Escherichia coli response to hydrogen peroxide. J Bacteriolagainst superoxide and hydrogen peroxide. Annu Rev BiochemHydrogen peroxide-induced oxidative stress responses in

  5. Serotonin 5-HT2B Receptor Blockade Prevents Reactive Oxygen SpeciesInduced Cardiac Hypertrophy in Mice

    E-Print Network [OSTI]

    Boyer, Edmond

    hypertrophy, ie, angiotensin II and isoproterenol infusions in mice. Angiotensin II infusion for 14 days215505) prevented the increase in cardiac superoxide generation and hypertrophy. Similarly, infusion

  6. Method for digesting a nitro-bearing explosive compound

    DOE Patents [OSTI]

    Shah, Manish M. (Richland, WA)

    2000-01-01T23:59:59.000Z

    The present invention is a process wherein superoxide radicals from superoxide salt are used to break down the explosive compounds. The process has an excellent reaction rate for degrading explosives, and operates at ambient temperature and atmospheric pressure in aqueous or non-aqueous conditions. Because the superoxide molecules are small, much smaller than an enzyme molecule for example, they can penetrate the microstructure of plastic explosives faster. The superoxide salt generates reactive hydroxyl radicals, which can destroy other organic contaminants, if necessary, along with digesting the explosive nitro-bearing compound.

  7. Double perovskite catalysts for oxidative coupling

    DOE Patents [OSTI]

    Campbell, K.D.

    1991-01-01T23:59:59.000Z

    Alkali metal doped double perovskites containing manganese and at least one of cobalt, iron and nickel are useful in the oxidative coupling of alkane to higher hydrocarbons.

  8. CEES Frontiers in Energy Research Articles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Read some of their contributions: "X-Ray Detection of Manganese Contamination in Lithium-Ion Batteries" by Laila Jaber-Ansari http:www.energyfrontier.usnewsletter201407...

  9. Ductile aluminide alloys for high temperature applications

    DOE Patents [OSTI]

    Liu, C.T.; Kock, C.C.

    1983-08-03T23:59:59.000Z

    Heat- and corrosion-resistant alloys are described which contain nickel, aluminum, boron, iron and in some instances manganese, niobium and titanium.

  10. --No Title--

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for growing functional materials, such as manganese oxides for electronic and solid-oxide fuel cell applications. Confining Liquids in Hollow Nanospheres Can Yield Superior...

  11. Iron and Steel Phosphate Rock

    E-Print Network [OSTI]

    Torgersen, Christian

    Lime Lithium Magnesium Manganese Mercury Mica Molybdenum Nickel Nitrogen Peat Perlite Phosphate Rock . . . . . . . . . . . . . . . . . . . . . . . . 194 Appendix C--Resource/Reserve Definitions . . . . . . 195 Commodities: Abrasives (Manufactured

  12. U.S. Department of the Interior U.S. Geological Survey

    E-Print Network [OSTI]

    Torgersen, Christian

    Lithium Magnesium Manganese Mercury Mica Molybdenum Nickel Nitrogen Peat Perlite Phosphate Rock Platinum..............................................................192 Appendix C--A Resource/Reserve Classification for Minerals

  13. Nanoscale Morphological and Chemical Changes of High Voltage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale Morphological and Chemical Changes of High Voltage Lithium-Manganese Rich NMC Composite Cathodes with Cycling Friday, August 29, 2014 Renewable energy is critical for the...

  14. CEES Conference Proceedings, Abstracts, Presentations, and Poster...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Seattle, WA, May. M. M. Thackeray, "Recent Advances in Manganese- and Iron-Based Electrodes for Lithium Batteries," Joint International Battery Association-Pacific Power...

  15. Investigations of segregation phenomena in highly strained Mn-doped Ge wetting layers and Ge quantum dots embedded in silicon

    SciTech Connect (OSTI)

    Prestat, E., E-mail: eric.prestat@gmail.com; Porret, C.; Favre-Nicolin, V.; Tainoff, D.; Boukhari, M.; Bayle-Guillemaud, P.; Jamet, M.; Barski, A., E-mail: andre.barski@cea.com [INAC, SP2M, CEA and Université Joseph Fourier, 17 rue des Martyrs, 38054 Grenoble (France)

    2014-03-10T23:59:59.000Z

    In this Letter, we investigate manganese diffusion and the formation of Mn precipitates in highly strained, few monolayer thick, Mn-doped Ge wetting layers and nanometric size Ge quantum dot heterostructures embedded in silicon. We show that in this Ge(Mn)/Si system manganese always precipitates and that the size and the position of Mn clusters (precipitates) depend on the growth temperature. At high growth temperature, manganese strongly diffuses from germanium to silicon, whereas decreasing the growth temperature reduces the manganese diffusion. In the germanium quantum dots layers, Mn precipitates are detected, not only in partially relaxed quantum dots but also in fully strained germanium wetting layers between the dots.

  16. ascending tract neurons: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of these neurons has been established in electrophysiological (more) Shakya Shrestha, Sony 2012-01-01 3 Improved Neuronal Tract Tracing using Manganese Enhanced Magnetic...

  17. aligned carbon nanofiber: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with a variety of cell types 12 Manganese Oxide-Doped Carbon Nanofiber as Electrode Materials for Electric Double Layer Capacitors. Open Access Theses and Dissertations Summary:...

  18. Development of High Energy Lithium Batteries for Electric Vehicles...

    Broader source: Energy.gov (indexed) [DOE]

    Kasei * Focused on High Capacity Manganese Rich (HCMR TM ) cathodes & Silicon-Carbon composite anodes for Lithium ion batteries * Envia's high energy Li-ion battery materials...

  19. aligned carbon nanofibers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with a variety of cell types 12 Manganese Oxide-Doped Carbon Nanofiber as Electrode Materials for Electric Double Layer Capacitors. Open Access Theses and Dissertations Summary:...

  20. The Synthesis and Characterization of Substituted Olivines and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D.C. es22whittingham.pdf More Documents & Publications The Synthesis and Characterization of Substituted Olivines and Layered Manganese Oxides The Synthesis and...

  1. The Synthesis and Characterization of Substituted Olivines and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D.C. es050whittingham2010p.pdf More Documents & Publications The Synthesis and Characterization of Substituted Phosphates and Layered Manganese Oxides The Synthesis and...

  2. Status of Baseline Sampling for Elements in Soil and Vegetation...

    Open Energy Info (EERE)

    facility indicate that there are not significant differences in soil residue levels of lithium and manganese between the 50 sites. However, there are significant difference between...

  3. High-Performance Thermoelectric Devices Based on Abundant Silicide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reports of methods to synthesize single-crystal and poly or nano- crystalline p- and n-type higher manganese silicides to reduce lattice thermal conductivity...

  4. E-Print Network 3.0 - active electrode cooling Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    >> 21 Multisegmented Au-MnO2Carbon Nanotube Hybrid Coaxial Arrays for High-Power Supercapacitor Applications Summary: conductivity of the manganese oxide electrodes, in addition...

  5. Structural Characterization of and Plutonium Sorption on Mesoporous and Nanoparticulate Ferrihydrite

    E-Print Network [OSTI]

    Brogan, Luna Kestrel Schwaiger

    2012-01-01T23:59:59.000Z

    4 Manganese-Substituted Goethite 4.1Mn-Substituted Goethite . . . . . . . . . .5 FerrihydriteX-ray diffractograms of goethite and Mn-substituted goethite

  6. Trace Elements Greg Mullins, Extension Nutrient Management Specialist, Virginia Tech

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    the plants. Manganese (Mn) Manganese deficiency has been found on soybeans and peanuts grown in VirginiaTrace Elements Greg Mullins, Extension Nutrient Management Specialist, Virginia Tech Steve Heckendorn, Soil Test Laboratory Manager, Virginia Tech Soil Test Note #4 Introduction Your Soil Test Report

  7. Dual battery sets including zinc MnO{sub 2} rechargeable cells on constant power tests

    SciTech Connect (OSTI)

    Schumm, B. Jr.

    1998-07-01T23:59:59.000Z

    Electric vehicle power requirements typically are much greater than what would be recommended for rechargeable zinc manganese dioxide alkaline batteries. In order to use the zinc manganese dioxide system as an economical power source for heavy load or pulse systems it is necessary to augment the pulse load carrying capability. Eagle-Cliffs is testing commercially available rechargeable zinc manganese dioxide cells in sets. These sets consist one configuration of the zinc manganese dioxide cells accompanied by a much lower capacity device ( which may be another configuration of zinc manganese dioxide cells) supporting any heavy pulse current requirements. Thus the zinc manganese dioxide cells provide at least a low cost, environmentally desirable main power battery and perhaps the pulse power yet the system still meets the intermittent high power needs of many uses. In this test program, small zinc manganese dioxide rechargeable cells are supported by a nickel cadmium battery or a different set of zinc manganese dioxide cells simulating any of a number of devices such as power batteries, large capacitors, flywheels, etc. Discharge performance demonstrating forty-five to fifty watt-hours per kilogram and 80 watts per kilogram is achieved by the system.

  8. The design of new ligands and transition metal compounds for the oxidation of organic compounds

    E-Print Network [OSTI]

    Grill, Joseph Michael

    2009-06-02T23:59:59.000Z

    ........................................................................................... 108 APPENDIX B............................................................................................ 215 APPENDIX C............................................................................................ 225 VITA..., oxidation of manganese (III) to manganese (V) occurs, followed by addition of an olefin to form a C-O bond and a carbon radical. Collapse of the radical species t 12 then gives the epoxide (Scheme 1.8). 38 This mechanism allows for the possibility...

  9. Red, Green and Blue Silicate Phosphor Thin Films by Pulsed Laser X. W. Sun and H. S. Kwok

    E-Print Network [OSTI]

    Red, Green and Blue Silicate Phosphor Thin Films by Pulsed Laser Deposition X. W. Sun and H. S University of Science and Technology Clear Water Bay, Kowloon, Hong Kong Abstract Three kinds of silicate deposition: manganese and lead doped calcium silicate (CaSiO3:MnPb) for red color, manganese doped zinc

  10. Quantitative evaluation of hydrogen sulfide at 0.3 M and 1.0 M-hydrogen-ion concentration

    E-Print Network [OSTI]

    Machel, Albert R.

    1958-01-01T23:59:59.000Z

    Concentration................. 14 1. Precipitation of Arsenic (III) sulfide....................... 15 2. Precipitation of Nickel (II) sulfide....................... 16 3* Precipitation of Manganese (II) sulfide....................... 17 4. Arsenic... (III) - Manganese (II) Separation................... 18 5- Arsenic (III) - Nickel (II) Separation................... 19 6. Precipitation of Bismuth. (Ill) sulfide....................... 20 7. Precipitation of Cobalt (II) sulfide...

  11. Open Archive TOULOUSE Archive Ouverte (OATAO) OATAO is an open access repository that collects the work of Toulouse researchers and

    E-Print Network [OSTI]

    Mailhes, Corinne

    vehicles' CO2 emissions are particularly interested in polymer-coated steels. For example, Smoosteel, manganese phosphate, and vinylphenol was applied on the HDG steel to obtain high corrosion resistance and high adherence of a polyester and melamine primer. The influence of the manganese phosphate

  12. Molten salt extraction process for the recovery of valued transition metals from land-based and deep-sea minerals

    DOE Patents [OSTI]

    Maroni, Victor A. (Naperville, IL); von Winbush, Samuel (Huntington, NY)

    1988-01-01T23:59:59.000Z

    A process for extracting transition metals and particularly cobalt and manganese together with iron, copper and nickel from low grade ores (including ocean-floor nodules) by converting the metal oxides or other compositions to chlorides in a molten salt, and subsequently using a combination of selective distillation at temperatures below about 500.degree. C., electrolysis at a voltage not more negative than about -1.5 volt versus Ag/AgCl, and precipitation to separate the desired manganese and cobalt salts from other metals and provide cobalt and manganese in metallic forms or compositions from which these metals may be more easily recovered.

  13. Molten salt extraction process for the recovery of valued transition metals from land-based and deep-sea minerals

    DOE Patents [OSTI]

    Maroni, V.A.; von Winbush, S.

    1987-05-01T23:59:59.000Z

    A process for extracting transition metals and particularly cobalt and manganese together with iron, copper and nickel from low grade ores (including ocean-floor nodules) by converting the metal oxides or other compositions to chlorides in a molten salt, and subsequently using a combination of selective distillation at temperatures below about 500/degree/C, electrolysis at a voltage not more negative that about /minus/1.5 volt versus Ag/AgCl, and precipitation to separate the desired manganese and cobalt salts from other metals and provide cobalt and manganese in metallic forms or compositions from which these metals may be more easily recovered.

  14. Genomic consequences of DNA oxidation by peroxynitrite

    E-Print Network [OSTI]

    Neeley, William Louis

    2006-01-01T23:59:59.000Z

    The radicals nitric oxide and superoxide are produced endogenously by activated macrophages and neutrophils and combine in a diffusion-limited reaction to form peroxynitrite, a powerful oxidizing and nitrating agent capable ...

  15. ROLE OF AN ABC TRANSPORTER COMPLEX IN VIOLOGEN TOLERANCE IN STREPTOCOCCUS MUTANS

    E-Print Network [OSTI]

    Biswas, Saswati

    2011-05-31T23:59:59.000Z

    the mechanisms by which S. mutans withstand exposure to various quaternary ammonium compounds (QAC) such as methyl viologen (MV) that also generates superoxide radicals in the cell. To elucidate the genes that are essential for MV tolerance, sensitive mutants...

  16. Activation of microglial NADPH oxidase is synergistic with glial iNOS expression in inducing neuronal death: a dual-key mechanism of inflammatory neurodegeneration

    E-Print Network [OSTI]

    Mander, Palwinder K; Brown, Guy C

    2005-09-12T23:59:59.000Z

    inflammatory neurodegeneration in response to cytokines, bacteria, ATP, arachidonate and pathological prions, in which case neurons may be protected by iNOS or NOX inhibitors, or scavengers of NO, superoxide or peroxynitrite....

  17. Synthesis and investigation of hexacarboxamide cryptands as anionic binucleating ligands by Glen E. Alliger.

    E-Print Network [OSTI]

    Alliger, Glen E. (Glen Edward)

    2010-01-01T23:59:59.000Z

    We have investigated the use of hexacarboxamide cryptands as sextuply anionic binucleating ligands. Two homobimetallic complexes of a t-butyl-substituted cryptand, featuring manganese(II) ion and cobalt(II) ions, have been ...

  18. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

    1994-01-01T23:59:59.000Z

    As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  19. Maternal Blood Lead Levels and the Risk of Pregnancy Induced Hypertension. The "EDEN" Cohort Study.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Maternal Blood Lead Levels and the Risk of Pregnancy Induced Hypertension. The "EDEN" Cohort title: Lead and Gestational Hypertension Key words: cadmium; environmental health; epidemiology; gestation; hypertension; lead; manganese. Acknowledgments: We are indebted to the participating families

  20. The Influence of Spray Water Quality on Herbicide www.btny.purdue.edu/weedscience

    E-Print Network [OSTI]

    calcium, magnesium, iron, aluminum, zinc, manganese, sodium, potassium, cesium, and lithium can influence be difficult. When the spray tank is not cleaned properly, leftover traces of the herbicide can contaminate

  1. New Insights into the Mechanism of Bacterial Metal Respiration

    SciTech Connect (OSTI)

    DiChristina, Thomas J.

    2004-04-17T23:59:59.000Z

    This project goal is to identify genes and gene products required for microbial metal reduction: reductive dissolution of iron; reductive dissolution of manganese; reductive precipitation of selenium; reductive precipitation of uranium; and reductive precipitation of technetium.

  2. Birnessite formation and its transformation in acid media Xiong Han Feng, fxh73@mail.hzau.edu.cn, Matthew Ginder-Vogel, mattgv@udel.edu, Mengqiang Zhu, mzhu@UDel.Edu, and Donald

    E-Print Network [OSTI]

    Sparks, Donald L.

    Birnessite formation and its transformation in acid media GEOC 47 Xiong Han Feng, fxh73@mail hexagonal structure to biogenic manganese oxide. The formation of acid birnessite and its transformation

  3. Chemistry & Physics at Interfaces | Advanced Materials | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for growing functional materials, such as manganese oxides for electronic and solid-oxide fuel cell applications. Phase coexistence enables switching in strained BiFeO3 July 17,...

  4. U.S. Department of the Interior U.S. Geological Survey

    E-Print Network [OSTI]

    Torgersen, Christian

    Lithium Magnesium Manganese Mercury Mica Molybdenum Nickel Nitrogen Peat Perlite Phosphate Rock Platinum Molybdenum Nickel Nitrogen Peat Perlite Phosphate Rock Platinum Potash Pumice Quartz Crystal Rare Earths..............................................................194 Appendix C--A Resource/Reserve Classification for Minerals

  5. U.S. Department of the Interior U.S. Geological Survey

    E-Print Network [OSTI]

    Torgersen, Christian

    Lithium Magnesium Manganese Mercury Mica Molybdenum Nickel Nitrogen Peat Perlite Phosphate Rock Platinum Molybdenum Nickel Nitrogen Peat Perlite Phosphate Rock Platinum Potash Pumice Quartz Crystal Rare Earths..............................................................192 Appendix C--A Resource/Reserve Classification for Minerals

  6. STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES

    E-Print Network [OSTI]

    Wilcox, James D.

    2010-01-01T23:59:59.000Z

    Linden, D. , Handbook of Batteries. 2nd ed. 1995, New York:rechargeable lithium batteries. Nature, 2001. 414(6861): p.of rechargeable lithium batteries, I. Lithium manganese

  7. Heat transfer characteristics of a two-pass trapezoidal channel and a novel heat pipe

    E-Print Network [OSTI]

    Lee, Sang Won

    2009-06-02T23:59:59.000Z

    , monocrystalline silicon, beryllium oxide, strontium dichromate, boron oxide, aluminum dichromate, and manganese dichromate, as shown in Fig. 3. The focus of this study is to determine/quantify the thermal characteristics of the QTHP and identify the possible...

  8. Ken Nealson is the Wrigley Professor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    account for the major portion of organic carbon oxidation in many sediments. On more modest spatial scales, iron and manganese reduction can be linked to the oxidation of a wide...

  9. Alternative Energy Technologies Solar Power

    E-Print Network [OSTI]

    Scott, Christopher

    #12;Alternative Energy Technologies Solar Power Photovoltaics Concentrating Solar Power (CSP) Power;Concentrating Solar Power (CSP) Reflector material is Aluminum or Silver Tube material ..... Several possible ............... Mexico, Canada, Peru Alumina ............Guinea, Brazil, Australia, Jamaica Manganese ....... S. Africa

  10. Ultrafine-scale magnetostratigraphy of marine ferromanganese crust

    E-Print Network [OSTI]

    Oda, Hirokuni

    Hydrogenetic ferromanganese crusts are iron-manganese oxide chemical precipitates on the seafloor that grow over periods of tens of millions of years. Their secular records of chemical, mineralogical, and textural variations ...

  11. Design of novel lithium storage materials with a polyanionic framework

    E-Print Network [OSTI]

    Kim, Jae Chul, Ph. D. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Lithium ion batteries for large-scale applications demand a strict safety standard from a cathode material during operating cycles. Lithium manganese borate (LiMnBO?) that crystallizes into a hexagonal or monoclinic framework ...

  12. ORNL 2010-G01207/chj UT-B ID 200701976

    E-Print Network [OSTI]

    steel is a valuable structural alloy for power generation systems, nuclear fusion research temperature or cyrogenic temperatures, but not at the high temperatures required in power generation systems structure changes and offers better, tougher mechanical properties. High manganese austenitic stainless

  13. www.sciencemag.org SCIENCE VOL 334 18 NOVEMBER 2011 927 SPECIALSECTION

    E-Print Network [OSTI]

    Bashir, Rashid

    lithium, manganese, and oxygen. And earlier this year, Dismukes's team reported in the Journal of the's low natural gas prices, companies can use a mature technology called steam reform- ing to convert

  14. Process for removing technetium from iron and other metals

    DOE Patents [OSTI]

    Leitnaker, James M. (Kingston, TN); Trowbridge, Lee D. (Oak Ridge, TN)

    1999-01-01T23:59:59.000Z

    A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag.

  15. anatase titanium dioxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mixed anatase and rutile phases. Under simulated AM 1.5 G illumination, the peak solar energy conversion Heller, Eric 6 Room-temperature ferromagnetism in manganese doped reduced...

  16. EPR determination of the rate constants of detachment of hydrogen from triethylsilane by metal carbonyl radicals

    SciTech Connect (OSTI)

    Gasanov, R.G.; Dotdaev, S.Kh.

    1987-03-10T23:59:59.000Z

    The rate constants of detachment of hydrogen triethylsilane by radicals of rhenium and manganese pentacarbonyls, tungsten cyclopentadienyltricarbonyl, and iron cyclopentadienyldicarbonyl were determined, and the order of the reactivity of the metal carbonyls was hypothesized.

  17. Model for the Fabrication of Tailored Materials for Lithium-Ion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A process technology that yields high-capacity batteries. Unique method creates nickel-rich particles on the inside for a high-capacity battery, and a manganese-rich...

  18. XEDS STEM Tomography For 3D Chemical CharacterizationOf Nanoscale...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    view of the TEM sample. We employed this technique to investigate 3D distribution of Nickel (Ni), Manganese (Mn) and Oxygen (O) in Li(NiMn)O2 battery cathode material. For this...

  19. Catalytic properties, densification and mechanical properties of nanocrystalline yttria-zirconia-based materials

    E-Print Network [OSTI]

    Cui, Jianyi

    2007-01-01T23:59:59.000Z

    Alumina, titania, ceria and manganese oxide were either coated onto or doped in cubic 7 mol% Y203-ZrO2 (7YZ) nanocrystals to form nanocomposites for methane combustion. These novel catalysts were very active and thermally ...

  20. Isolation of a High-Affinity Functional Protein Complex between...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    such as manganese Mn(III, IV) and iron Fe(III) oxides and oxyhydroxides, as terminal electron acceptors during anaerobic respiration. The ability of S. oneidensis MR-1 to...

  1. Electronic and magnetic properties of Fe and Mn doped two dimensional hexagonal germanium sheets

    SciTech Connect (OSTI)

    Soni, Himadri R., E-mail: himadri.soni@gmail.com; Jha, Prafulla K., E-mail: himadri.soni@gmail.com [Department of Physics, Maharaja Krishnakumarsinhji Bhavnagar University, Bhavnagar-364001 (India)

    2014-04-24T23:59:59.000Z

    Using first principles density functional theory calculations, the present paper reports systematic total energy calculations of the electronic properties such as density of states and magnetic moment of pristine and iron and manganese doped two dimensional hexagonal germanium sheets.

  2. Role of stress-assisted martensite in the design of strong ultrafine-grained duplex steels

    E-Print Network [OSTI]

    Yen, Hung-Wei; Ooi, Steve Woei; Eizadjou, Mehdi; Breen, Andrew; Huang, Ching-Yuan; Bhadeshia, H. K. D. H.; Ringer, Simon P.

    2014-10-03T23:59:59.000Z

    intrusion applications or hole-expanded components in the automotive industry [1]. Moreover, some of the medium manganese steels require prolonged heat treatments so as to ensure solute partitioning in order to stabilise the austenite [16, 17], making...

  3. Non-Equilibrium Pathways during Electrochemical Phase Transformations...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    level, where incomplete reactions and failure are prone to occur. Micrometric-sized lithium-manganese spinel cathode material - Li1+xMn2-xO4 - is one of the state-of-the-art...

  4. Effect of high-pressure on molecular magnetism 

    E-Print Network [OSTI]

    Prescimone, Alessandro

    2010-01-01T23:59:59.000Z

    The effect of pressure on a number of magnetically interesting compounds such as single-molecule magnets and dimeric copper and manganese molecules has been investigated to probe the validity of ambient magneto-structural ...

  5. Batteries: Overview of Battery Cathodes

    E-Print Network [OSTI]

    Doeff, Marca M

    2011-01-01T23:59:59.000Z

    used graphite anode. After charging, the batteries are readylithium ion batteries (i.e. , to lithiate graphite anodes soGraphite Electrodes Due to the Deposition of Manganese Ions on Them in Li-Ion Batteries.

  6. Process for removing technetium from iron and other metals

    DOE Patents [OSTI]

    Leitnaker, J.M.; Trowbridge, L.D.

    1999-03-23T23:59:59.000Z

    A process for removing technetium from iron and other metals comprises the steps of converting the molten, alloyed technetium to a sulfide dissolved in manganese sulfide, and removing the sulfide from the molten metal as a slag. 4 figs.

  7. The combined immunoenhancing effects of vitamins E & A, E & Beta-carotene and E & canthaxanthin

    E-Print Network [OSTI]

    Cahill, Maureen Grace

    1994-01-01T23:59:59.000Z

    by phagocytic neutrophils during the oxidative burst, include the hydroxyl radical (OH ), 10 superoxide anion radical (0, ), hydroperoxyl radical (HO, ) hyperchlorous acid (HOCL), and hydrogen peroxide (H, O, ). These molecules are also generated...) Species Name 02 Dioxygen 02 Superoxide 1O 2 Singlet Oxygen H202 Hydrogen Peroxide 0, Ozone OH Hydroxyl Radical RO, H Organic Peroxide Noz Nitrogen Dioxide electron transport system cytochromes Psso ond b 5 xonthine oxidase hemoglobin...

  8. JOURNAL DE PHYSIQUE C o l l o q u e C8, suppl6ment a u n012, Tome 48; dhcembre 1987

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    FRICTION IN MANGANESE-COPPER AND MANGANESE-COPPER-ALUMINIUM ALLOYS A T.S. KE, L.T. WANG and H.C. YI a s t i c modulus of Mn-Cu alloys containing 60 and 70 w t % Mn and of Mn-Cu-A1 alloys containing about 40-martensite interfaces. It has also been found that the addition of aluminium enhances the strength but reduces

  9. Synthesis, reactivity, and coordination chemistry relevant to the copolymerization of CO2 and epoxides by first row transition metal schiff base complexes 

    E-Print Network [OSTI]

    Frantz, Eric Benjamin

    2009-05-15T23:59:59.000Z

    -3. The bands at 2042 cm -1 and 2040 cm -1 represent (salen)MnN 3 epoxide adducts, while 2096 cm -1 is organic azide........................................................................................... 109 xiv LIST OF TABLES... are asymmetric epoxidation catalysts for bulky di- and tri- substituted olefins. 15 The mechanism involves the oxidation of manganese(III) to manganese(V) with an oxidant, such as NaOCl, followed Inoue Mang and Holmes 9 by the non...

  10. Potential for selenium migration at a lignite power plant solid waste disposal facility

    E-Print Network [OSTI]

    Hall, Steven Douglas

    1986-01-01T23:59:59.000Z

    . All groundwater that recharges on the disposal site is slightly saline and flows east, probably discharging into the Gibbons Creek Reservoir. Selenium, arsenic, boron, iron, manganese, and sulfate in the lignite waste effluent exceed either EPA... ( 1975) drinking water standards or EPA (1973) recommended livestock water standards. Since the natural groundwater contains higher concentrations of selenium, iron, manganese, and sulfate than the waste effluent, only arsenic and boron should...

  11. Reduced-activation austenitic stainless steels: The Fe--Mn--Cr--C system

    SciTech Connect (OSTI)

    Klueh, R.L.; Maziasz, P.J.

    1988-01-01T23:59:59.000Z

    Nickel-free manganese-stabilized steels are being developed for fusion-reactor applications. As the first part of this effort, the austenite-stable region in the Fe--Mn--Cr--C system was determined. Results indicated that the Schaeffler diagram developed for Fe--Ni--Cr--C alloys cannot be used to predict the constituents expected for high-manganese steels. This is true because manganese is not as strong an austenite stabilizer relative to delta-ferrite formation as predicted by the diagram, but it is a stronger austenite stabilizer relative to martensite than predicted. Therefore, the austenite-stable region for Ne--Mn--Cr--C alloys occurs at lower chromium and hugher combinations of manganese and carbon than predicted by the Schaeffler diagram. Development of a manganese-stabilized stainless steel should be possible in the composition range of 20 to 25% Mn, 10 to 15% Cr, and 0.01 to 0.25%C. Tensile behavior of an Fe--20%Mn--12%Cr--0.25%C alloy was determined. The strength and ductility of this possible base composition was comparable to type 316 stainless steel in both the solution-annealed and cold-worked condition.

  12. Theoretical susceptibilities of linear antiferromagnets

    E-Print Network [OSTI]

    McSwain, Sulane

    1968-01-01T23:59:59.000Z

    . TABLE OF CONTENTS CHAPTER I. INTRODUCTION II. THEORY AND APPLICATIONS A. Manganese(II) Chloride B. Iron(II) Chloride C. Cobalt(II) Chloride D. Nickel(II) Chloride E. Copper(II) Chloride F. Manganese(II) Squarate Dihydrate G. Iron(II) Squarate... Dihydrate H. Cobalt(II) Squarate Dihydrate I. Nickel(II) Squarate Dihydrate III. DISCUSSION IV. EXPERIMENTAL Page 12 15 18 20 26 29 52 54 57 APPENDIX A. Synthesis of Transition Metal Squarates. . . . . . . . . . . . . . 45 B. Electron Spin...

  13. Autogenous electrolyte, non-pyrolytically produced solid capacitor structure

    DOE Patents [OSTI]

    Sharp, D.J.; Armstrong, P.S.; Panitz, J.K.G.

    1998-03-17T23:59:59.000Z

    A solid electrolytic capacitor is described having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects. 2 figs.

  14. Autogenous electrolyte, non-pyrolytically produced solid capacitor structure

    DOE Patents [OSTI]

    Sharp, Donald J. (Albuquerque, NM); Armstrong, Pamela S. (Abingdon, MD); Panitz, Janda Kirk G. (Edgewood, NM)

    1998-01-01T23:59:59.000Z

    A solid electrolytic capacitor having a solid electrolyte comprising manganese dioxide dispersed in an aromatic polyamide capable of further cure to form polyimide linkages, the solid electrolyte being disposed between a first electrode made of valve metal covered by an anodic oxide film and a second electrode opposite the first electrode. The electrolyte autogenously produces water, oxygen, and hydroxyl groups which act as healing substances and is not itself produced pyrolytically. Reduction of the manganese dioxide and the water molecules released by formation of imide linkages result in substantially improved self-healing of anodic dielectric layer defects.

  15. Theoretical susceptibilities of linear antiferromagnets 

    E-Print Network [OSTI]

    McSwain, Sulane

    1968-01-01T23:59:59.000Z

    . TABLE OF CONTENTS CHAPTER I. INTRODUCTION II. THEORY AND APPLICATIONS A. Manganese(II) Chloride B. Iron(II) Chloride C. Cobalt(II) Chloride D. Nickel(II) Chloride E. Copper(II) Chloride F. Manganese(II) Squarate Dihydrate G. Iron(II) Squarate... Dihydrate H. Cobalt(II) Squarate Dihydrate I. Nickel(II) Squarate Dihydrate III. DISCUSSION IV. EXPERIMENTAL Page 12 15 18 20 26 29 52 54 57 APPENDIX A. Synthesis of Transition Metal Squarates. . . . . . . . . . . . . . 45 B. Electron Spin...

  16. In-situ photocatalytic remediation of organic contaminants in groundwater

    E-Print Network [OSTI]

    Lim, Leonard Lik Pueh

    2010-07-06T23:59:59.000Z

    on the catalyst, i.e. titanium dioxide (TiO2). In the presence of oxygen, highly reactive oxidising agents are generated such as superoxide (O2-), hydroxyl (OH·-) radicals, and holes (hvb+) on the catalyst surface which can oxidise a wide range of organic...

  17. Electronic Structures and Spin Topologies of -Picoliniumyl Radicals. A Study of the Homolysis of N-Methyl--picolinium and of Benzo-, Dibenzo-, and Naphthoannulated

    E-Print Network [OSTI]

    Glaser, Rainer

    topologies in metalloenzymes. Introduction The redox reactions of quaternized nitrogen heterocycles interesting. For example, the herbicide methyl viologen (paraquat) and the promising antitumor agent equivalent of superoxide O2 ·-.1­4 The repeated enzymatic reduction and back-oxidation by O2, i.e., the redox

  18. Biocbonicd Pharmacology. Vol. 3.5. No. 18. pp. 3095-3101. 1986 Printed in Great Britain.

    E-Print Network [OSTI]

    California at Berkeley, University of

    -2952/86 53.00 + 0.W Pergamon Journals Ltd. ROLE OF REDOX CYCLING AND LIPID PEROXIDATION IN BIPYRIDYL that these compounds are potent generators of active oxygen speciesby redox cyclingand that they stimulate lipid herbicides, diquat (DQ), paraquat (PQ) and benzyl viologen (BV), to generate superoxide anion radical (07

  19. Hybrid Energy Cell for Degradation of Methyl Orange by Self-Powered Electrocatalytic Oxidation

    E-Print Network [OSTI]

    Wang, Zhong L.

    Hybrid Energy Cell for Degradation of Methyl Orange by Self- Powered Electrocatalytic Oxidation Ya of superoxidative hydroxyl radical on the anode. Here, we report a hybrid energy cell that is used for a self-powered electrocatalytic process for the degradation of MO without using an external power source. The hybrid energy cell

  20. Open Access Available online http://arthritis-research.com/content/7/1/R93

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    O2 ·- production by PMA-stimulated monocytes. Treatment of healthy monocytes with nifedipine with DTCCA and second after 2 weeks of treatment with nifedipine (60 mg/day). O2 ·- production by monocytes the effects in vivo and in vitro of nifedipine on superoxide anion (O2 ·-) production by peripheral blood

  1. Molecular Cell Hydroxyurea Induces Hydroxyl

    E-Print Network [OSTI]

    Collins, James J.

    and physiological responses of E. coli to HU treatment. Our results suggest a model by which HU treatment rapidly proteins and stimulation of enve- lope stress responses. These effects alter the proper- ties of one of the cell's terminal cytochrome oxidases, causing an increase in superoxide production. The increased

  2. Cyclophilin and the Regulation of Symbiosis in Aiptasia pallida

    E-Print Network [OSTI]

    microscopy using superoxide and nitric oxide-sensitive fluorescent dyes on live specimens of A. pallida the CsA-sensitive isomerase activity is important for main- taining the activity of the antioxidant as cnidarian bleaching, results through mechanisms dependent on host cell death pathways triggered in part

  3. APPLIED AND ENVIRONMENTAL MICROBIOLOGY, Sept. 2006, p. 60706078 Vol. 72, No. 9 0099-2240/06/$08.00 0 doi:10.1128/AEM.00483-06

    E-Print Network [OSTI]

    Daub, Margaret

    of a strain that rapidly degrades cercosporin (XCZ-3) were generated by ethyl methanesulfonate mutagenesis and uses light energy to produce the activated oxygen species superoxide and singlet oxygen (11, 47). Although cer- cosporin has been shown to produce both activated oxygen species, singlet oxygen appears

  4. Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under Physiologically Relevant

    E-Print Network [OSTI]

    Gates, Kent. S.

    Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under found that micromolar concentrations of H2S generated single-strand DNA cleavage. Mechanistic studies indicate that this process involved autoxidation of H2S to generate superoxide, hydrogen peroxide, and

  5. Molecular analysis of the cercosporin biosynthetic gene cluster in Cercospora nicotianae

    E-Print Network [OSTI]

    Daub, Margaret

    molecules to generate reactive oxygen species, including singlet oxygen (1 O2) and superoxide radicals (O2; Daub et al., 2005). Cercosporin is a perylenequinone that absorbs light and reacts with oxygen ­ ) (Daub and Hangarter, 1983). The reactive oxygen species cause peroxidation of cell membranes

  6. The CRG1 gene required for resistance to the singlet oxygen-generating cercosporin toxin in Cercospora nicotianae encodes a putative

    E-Print Network [OSTI]

    Daub, Margaret

    The CRG1 gene required for resistance to the singlet oxygen-generating cercosporin toxin electron or energy transfer to generate reactive oxygen species such as superoxide (OÅÀ 2 ) and singlet gene is involved in cellular resistance to the perylenequinone toxin, cercosporin, that generates

  7. The accompanying Soil Test Report (and supplemental Soil Test Notes, when provided) will help you assess

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    and Abbreviations P = phosphorus K = potassium Ca = calcium Mg = magnesium Zn = zinc Mn = manganese Cu = copper Fe Specialist, Virginia Tech Steve Heckendorn, Soil Test Laboratory Manager, Virginia Tech Soil Test Note #1 www.ext.vt.edu Produced by Communications and Marketing, College of Agriculture and Life Sciences, Virginia Polytechnic

  8. 2014 Virginia Polytechnic Institute and State University PPWS-40NP Peanut (Arachis hypogaea, L.) Nutrition

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    2014 Virginia Polytechnic Institute and State University PPWS-40NP Peanut (Arachis hypogaea, L. For peanut, the recommended pH range is 5.8 ­ 6.2. If soil pH is higher than 6.2, manganese (Mn) or boron (B-8 inches. Analyzing the soil samples at the Virginia Tech's Soil Testing Laboratory, 145 Smith Hall (0465

  9. J. PHYS. IV FRANCE 7 (1997) Colloque C1, Suppldmentau Journal de Physique I11 de mars 1997

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1997-01-01T23:59:59.000Z

    .J. Churchill, K.D.T.Ngo* and R.J. Thibodeaux*" American Research Corporationof Virginia,1509 Fourth Street, Radford, Virginia24143-3406, U.S.A. *Department of Electrical Engineering, Universityof Florida-permeability,ultra-low-loss, substituted nickel (Ni) and manganese (Mn)ferrites that serve as cores for magnetic components, while the non

  10. PHYSICAL REVIEW B 85, 235438 (2012) Prediction of solid-aqueous equilibria: Scheme to combine first-principles calculations of solids

    E-Print Network [OSTI]

    Ceder, Gerbrand

    2012-01-01T23:59:59.000Z

    5 for aqueous stability, (2) the stability of small nanoparticle Pt in acid water, and (3) the prediction of particle morphology and facet stabilization of olivine LiFePO4 as a function of aqueous modeled proton-mediated dissolution of manganese and cobalt oxides in acid. In their calculation

  11. This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research

    E-Print Network [OSTI]

    Burgos, William

    ,* a Department of Civil and Environmental Engineering, The Pennsylvania State University, 212 Sackett Building on their influent Mn(II) concentrations (20­150 mg/L), system construction (±inoculation with patented Mn(II)-oxidizing bacteria), and bed materials (limestone vs. sandstone). Manganese(II) removal occurred at pH values as low

  12. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation

    DOE Patents [OSTI]

    Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

    1993-01-01T23:59:59.000Z

    New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or .beta.-pyrrolic positions.

  13. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation

    DOE Patents [OSTI]

    Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

    1995-01-01T23:59:59.000Z

    New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or .beta.-pyrrolic positions.

  14. Nitrated metalloporphyrins as catalysts for alkane oxidation

    DOE Patents [OSTI]

    Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

    1994-01-01T23:59:59.000Z

    Compositions of matter comprising nitro-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has nitro groups attached thereto in meso and/or .beta.-pyrrolic positions.

  15. CX-100010: Categorical Exclusion Determination

    Office of Energy Efficiency and Renewable Energy (EERE)

    Geothermal Thermoelectric Generation (G-TEG) with integrated Temperature Driven Membrane Distillation and Novel Manganese Oxide for Lithium Extraction Award Number: DE-EE0006746 CX(s) Applied: A9, B3.6 Date: 08/27/2014 Location(s): Georgia Offices(s): Golden Field Office Technology Office: Geothermal Technologies

  16. GEOLOGY, March 2011 227 INTRODUCTION

    E-Print Network [OSTI]

    Weiss, Benjamin P.

    remanent magnetization (NRM) in fer- romanganese nodules and found evidence of geomagnetic reversals formulae on the Co flux into the ferro- manganese crusts (e.g., Puteanus and Halbach, 1988). However, these empirical formulae have not been well documented theoretically, and Frank et al. (1999) found disagreement

  17. Digestive efficiency and dry-matter digestibility in Steller sea lions fed herring, pollock, squid, and

    E-Print Network [OSTI]

    Digestive efficiency and dry-matter digestibility in Steller sea lions fed herring, pollock, squid, and salmon D.A.S. Rosen and A.W. Trites Abstract: Dry-matter digestibility and energy digestive efficiency-matter digestibility (DMD) and digestive efficiency (DE) were measured using the energy and manganese concentration

  18. Aluminum battery alloys

    DOE Patents [OSTI]

    Thompson, David S. (Richmond, VA); Scott, Darwin H. (Mechanicsville, VA)

    1985-01-01T23:59:59.000Z

    Aluminum alloys suitable for use as anode structures in electrochemical cs are disclosed. These alloys include iron levels higher than previously felt possible, due to the presence of controlled amounts of manganese, with possible additions of magnesium and controlled amounts of gallium.

  19. Aluminum battery alloys

    DOE Patents [OSTI]

    Thompson, D.S.; Scott, D.H.

    1984-09-28T23:59:59.000Z

    Aluminum alloys suitable for use as anode structures in electrochemical cells are disclosed. These alloys include iron levels higher than previously felt possible, due to the presence of controlled amounts of manganese, with possible additions of magnesium and controlled amounts of gallium.

  20. JOURNAL DE PHYSIQUE IV Colloque C7, suppldmentau Journal de Physique 111,Volume 3, novembre 1993

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    deformation behaviour of AA 6063 and AA 6005 aluminium alloys has been related to chemical composition with the reduction in spacing between grain boundaryprecipitates. 1. INTRODUCTION Aluminium alloys containing Mg Microstructure control and extrudability of aluminium-Mg-Sialloys microalloyedwith manganese S. ZAJAC, B

  1. Characterization of contaminant phases in foraminifera carbonates by electron microprobe mapping

    E-Print Network [OSTI]

    Characterization of contaminant phases in foraminifera carbonates by electron microprobe mapping L characterized by the presence of manganese-rich minerals in the sediments. The combined application the foraminiferal shells. Results illustrate the presence of at least two different Mn-rich contaminant phases

  2. EFFECT OF QUALITY OF FORAGE ON AVAILABILITY OF TRACE ELEMENTS AND SOME MAJOR ELEMENTS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    there was an increase in some minerals especially for manganese. Contamination by the soil was possible, but certainly forages have been shown to produce mineral deficiencies in ruminants. Several factors are involved but an insolved question is the role played by the low level of minerals in the diet and the influence of poor

  3. 48 28th ANNUAL eMS CHROMIUM(llI) INDUCED SOLID PHASE TRANSFORMATION OF o-Mn02

    E-Print Network [OSTI]

    Sparks, Donald L.

    48 28th ANNUAL eMS CHROMIUM(llI) INDUCED SOLID PHASE TRANSFORMATION OF o-Mn02 Fendorf S pathways which will allow for transformations between oxidation states (redox reactions). Manganese oxides implications for environmental quality. The highly redox reactive a-Mn02 is transformed into a redox stable

  4. CX-004134: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Electrodeposited Manganese-Cobalt Alloy Coating for Solid Oxide Fuel Cell InterconnectsCX(s) Applied: B3.6, B5.1Date: 09/17/2010Location(s): Clayton, OhioOffice(s): Energy Efficiency and Renewable Energy

  5. Physics Today Livermore ends LIFE

    E-Print Network [OSTI]

    flow batteries include one being developed by Harvard Univer- sity (shown in the photo on page 25). Duracell technology Not all the technologies backed by ARPA­E are flow batteries. The City University of New York, working with a $3.5 million grant, is advancing a rechargeable zinc­manganese oxide cell

  6. t e n t i p s f o r your private

    E-Print Network [OSTI]

    Liskiewicz, Maciej

    residue Hardness Water tastes salty Chloride, sodium, TDS* Odor of gas / fuel VOCs** Pin hole leaks / blue operations Nitrate, coliform bacteria, pesticides Coal mining pH, iron, manganese Gas drilling Sodium, chloride, barium Dump, landfill, factory Metals, VOCs** Heavily salted roadways Sodium, chloride, TDS* TDS

  7. www.ccsenet.org/ijb International Journal of Biology Vol. 4, No. 1; January 2012 ISSN 1916-9671 E-ISSN 1916-968X172

    E-Print Network [OSTI]

    Qin, Wensheng

    ("Survey of Energy Resources 2007" by World Energy Council 2007). Peat is of industrial value as a fuel Fermentation of Peat Containing Medium Yuanyuan Hong Biorefining Research Initiative and Department of Biology gallica Fr.) were studied using statically submerged media containing peat. The laccase, manganese

  8. Iron and Steel Phosphate Rock

    E-Print Network [OSTI]

    Torgersen, Christian

    Kyanite Lead Lime Lithium Magnesium Manganese Mercury Mica Molybdenum Nickel Nitrogen Peat Perlite Graphite Peat Sulfur Beryllium Gypsum Perlite Talc Bismuth Hafnium Phosphate Rock Tantalum Boron Helium information on the USGS--the Federal source for science about the Earth, its natural and living resources

  9. Iron and Steel Phosphate Rock

    E-Print Network [OSTI]

    Torgersen, Christian

    Kyanite Lead Lime Lithium Magnesium Manganese Mercury Mica Molybdenum Nickel Nitrogen Peat Perlite Niobium Stone Barite Gold Nitrogen Strontium Bauxite Graphite Peat Sulfur Beryllium Gypsum Perlite Talc, its natural and living resources, natural hazards, and the environment: World Wide Web: http

  10. U.S. Department of the Interior U.S. Geological Survey

    E-Print Network [OSTI]

    Torgersen, Christian

    Lithium Magnesium Manganese Mercury Mica Molybdenum Nickel Nitrogen Peat Perlite Phosphate Rock Platinum Nickel Stone Barite Germanium Nitrogen Strontium Bauxite Gold Peat Sulfur Beryllium Graphite Perlite Talc, its natural and living resources, natural hazards, and the environment: World Wide Web: http

  11. DOI: 10.1002/ejic.200501155 Hydrothermal Syntheses, Architectures and Magnetic Properties of Six Novel

    E-Print Network [OSTI]

    Gao, Song

    ; interpenetration of these 2D layers results in the formation of a 3D supramolecular network. Magnetic Properties of Six Novel MnII Coordination Polymers with Mixed Ligands Chang-Yan Sun,[a] Song Gao,*[b] and Lin-Pei Jin*[a] Keywords: Coordination polymers / Magnetic properties / Manganese / Microporous materials

  12. Characterization of a Tunable Optical Parametric Oscillator Laser System for Multielement Flame

    E-Print Network [OSTI]

    Michel, Robert G.

    spectrum to allow for the determination of as many elements as possible, together with high peak energy to enable the atomic energy levels to be optically saturated by the laser, and high average power to allow Laser Excited Atomic Fluorescence Spectrometry of Cobalt, Copper, Lead, Manganese, and Thallium

  13. This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research

    E-Print Network [OSTI]

    Li, Yat

    - line (PANI) and manganese oxide (MnO2) nanoparticles. To enhance the interaction of MnO2 and PANI. The results demonstrated that PANI-ND-MnO2 nanocomposites are promising materials for supercapacitor electrode such as starting automotives and regenerating of brake energy. To date, carbon [2­5], transition metal oxides [6

  14. Cathode for the electrolytic production of hydrogen

    SciTech Connect (OSTI)

    Nicolas, E.

    1983-07-19T23:59:59.000Z

    The invention relates to a cathode for the electrolytic production of hydrogen. The cathode comprises an active surface consisting of a metal oxide obtained by the thermal decomposition of a thermally decomposable compound of a metal chosen from amongst cobalt, iron, manganese or nickel. The cathode is particularly suitable for the electrolysis of aqueous sodium chloride solutions in cells with a permeable diaphragm.

  15. JOURNAL DE PHYSIQUE Collogue CI, supplement au n 4, Tome 38, Avril 1977, page Cl-47 SIMULTANEOUS SUBSTITUTION OF COBALT AND TITANIUM

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    SUBSTITUTION OF COBALT AND TITANIUM IN LINEAR MANGANESE ZINC FERRITES A. D. GILES (*) and F. F. WESTENDORP. Abstract. -- It is shown that addition of titanium to cobalt containing Mn-Zn ferrite greatly improves were of high purity. Firing was carried out in a control- led oxygen-nitrogen mixture, the oxygen level

  16. APPLIED AND ENVIRONMENTAL MICROBIOLOGY, May 2006, p. 31843190 Vol. 72, No. 5 0099-2240/06/$08.00 0 doi:10.1128/AEM.72.5.31843190.2006

    E-Print Network [OSTI]

    Tebo, Brad

    APPLIED AND ENVIRONMENTAL MICROBIOLOGY, May 2006, p. 3184­3190 Vol. 72, No. 5 0099-2240/06/$08.00 0 Reserved. Manganese(II)-Oxidizing Bacillus Spores in Guaymas Basin Hydrothermal Sediments and Plumes Biotechnology and Biomedicine, Scripps Institution of Oceanography, University of California, San Diego, La

  17. A GEOCHEMICAL MODULE FOR "AMDTreat" TO COMPUTE CAUSTIC QUANTITY, EFFLUENT QUALITY, AND SLUDGE VOLUME1

    E-Print Network [OSTI]

    of sludge produced by the treatment, a titration simulation is being developed using the geochemical program The AMDTreat computer program ( . Treatment with caustic chemicals typically is used to increase pH (6 to 8), whereas active manganese removal requires treatment to alkaline pH (~10). The treatment

  18. 9 Ultra Low Temperature ADI 2 9.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2

    E-Print Network [OSTI]

    Cambridge, University of

    Contents 9 Ultra Low Temperature ADI 2 9.1 Introduction;Chapter 9 Ultra Low Temperature ADI 9.1 Introduction It has been indicated that a family of austempered]. These steels contain high carbon silicon and manganese, and they are isothermally heat treated at very low

  19. Dipartimento di Scienze di Base e Applicate per l'Ingegneria -Universit degli Studi di Roma "La Sapienza" Cod. Fiscale 80209930587 -P.IVA 02133771002

    E-Print Network [OSTI]

    Guidoni, Leonardo

    o arilico di ferro (II), fosfonato alchilico o arilico di manganese (II) e carbonato di litio per potenziale, misure d'impedenza e ciclazioni galvanostatiche tutte fatte su celle con anodo di litio metallico materiali elettrodici per batterie litio-ioni, in soluzioni organiche o in liquidi ionici DURATA E LUOGO: La

  20. Dipartimento di Scienze di Base e Applicate per l'Ingegneria -Universit degli Studi di Roma "La Sapienza" Cod. Fiscale 80209930587 -P.IVA 02133771002

    E-Print Network [OSTI]

    Guidoni, Leonardo

    ferro (II), fosfonato alchilico o arilico di manganese (II) e carbonato di litio per ottenere LiMnxFe1-x, misure d'impedenza e ciclazioni galvanostatiche tutte fatte su celle con anodo di litio metallico. Al elettrodici per batterie litio-ioni, in soluzioni organiche o in liquidi ionici In data 23/03/2012 alle ore 11

  1. Ecology of microbe/basaltic glass interactions : mechanisms and diversity

    E-Print Network [OSTI]

    Sudek, Lisa A.

    2011-01-01T23:59:59.000Z

    510-547. Landing W. M. and Bruland K. W. 1980. Manganese in67:223-229. Rue E. L. and Bruland K. W. 1997. The role of23:47-57. Rue E. L. and Bruland K. W. 1995. Complexation of

  2. Sparing and Salvaging Metals in Chloroplasts Crysten E. Blaby-Haas and Sabeeha S. Merchant

    E-Print Network [OSTI]

    Koehler, Carla

    INTRODUCTION Of the essential inorganic minerals, the micronutri- ents (manganese, iron, copper, and zinc) have observations of metal nutrition. It was not until the early to mid-1800s with the popularization of the mineral on the donor side of each photosystem II (PSII) monomer unit in the dimer catalyzes the extraction of electrons

  3. Gas Well Drilling and Water Resources Regulated by the Pennsylvania Oil and

    E-Print Network [OSTI]

    Boyer, Elizabeth W.

    used in drilling and fracking · Recent increase in permit fee to fund new DEP enforcement · Permit fluids ­ return fluids from fracking ­ mixture of water, sand and chemicals Production fluids ­ fluids, manganese, barium, arsenic, etc.) Surfactants/detergents Total suspended solids Oil/Grease Fracking

  4. IEEE TRANSACTIONS ON POWER ELECTRONICS, VOL. 17, NO. 4, JULY 2002 453 A Static Hysteresis Model for Power Ferrites

    E-Print Network [OSTI]

    Vu-Quoc, Loc

    for Power Ferrites Paiboon Nakmahachalasint, Student Member, IEEE, Khai D. T. Ngo, Senior Member, IEEE manganese­zinc (MnZn) ferrites. The procedures to extract the model parameters from voltage and current and minor hysteresis loops of three commercial power ferrites. Index Terms--Domain-wall, hysteresis modeling

  5. JOURNAL DE PHYSIQUE Colloque C8, Suppl6ment au no 12, Tome 49, decembre 1988

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    studied as a result of the technological importance of their soft magnetic properties. The Fe, including chromium [l-31, manganese [2-41, cobalt [2, 5, 61, nickel [2, 71 and copper [2, 31. One and Technology, Hefei, Anhui, China. Article published online by EDP Sciences and available at http

  6. Br-rich tips of calcified crab claws are less hard but more fracture resistant: A comparison of mineralized and heavy-element biological materials

    E-Print Network [OSTI]

    Scott, Robert A.

    of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China d Department of Chemistry the viscoelasticity of the material. We suggest that fracture resistance is of greater importance in smaller organisms cuticle. Bromine is one of a variety of heavy elements including zinc, iron, copper and manganese

  7. 1Y.V. Li and J.H. Zhang (eds.), Metal Ion in Stroke, Springer Series in Translational Stroke Research, DOI 10.1007/978-1-4419-9663-3_1,

    E-Print Network [OSTI]

    Li, Yang V.

    . They function as cofactors in cellular and genetic signaling and, therefore, have important roles), sodium (Na), magnesium (Mg), copper (Cu), manganese (Mn), or selenium (Se) in neurotoxicity as well 2004). For example, countries like India and China have experienced a rapid economic development

  8. 2012 Annual Merit Review Results Report - Energy Storage Technologies

    Broader source: Energy.gov (indexed) [DOE]

    3.33 3.33 3.33 2.67 3.25 Examining Hysteresis in Lithium- and Manganese-Rich Composite Cathode Materials Kevin Gallagher (Argonne National Laboratory) 2-195 3.25 3.00 3.00...

  9. Method for inhibiting alkali metal corrosion of nickel-containing alloys

    DOE Patents [OSTI]

    DeVan, Jackson H. (Oak Ridge, TN); Selle, James E. (Westminster, CO)

    1983-01-01T23:59:59.000Z

    Structural components of nickel-containing alloys within molten alkali metal systems are protected against corrosion during the course of service by dissolving therein sufficient aluminum, silicon, or manganese to cause the formation and maintenance of a corrosion-resistant intermetallic reaction layer created by the interaction of the molten metal, selected metal, and alloy.

  10. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA)

    2006-12-26T23:59:59.000Z

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  11. 612 NATURE PHYSICS | VOL 9 | OCTOBER 2013 | www.nature.com/naturephysics news & views

    E-Print Network [OSTI]

    Loss, Daniel

    (manganese), high- temperature superconductivity (copper), lithium-ion battery electrochemistry (cobalt phase): it's as though the electronic conductivity, one of the most fundamental physical properties interactions between them and the degeneracy of their energy levels2,3 -- play a significant role. And

  12. Chapter Eight Rock Varnish

    E-Print Network [OSTI]

    Dorn, Ron

    ) Coating Description Carbonate skin Coating composed primarily of carbonate, usually calcium carbonate; the agent may be manganese, sulphate, carbonate, silica, iron, oxalate, organisms, or anthropogenic Dust, cyanobacteria, algae Nitrate crust Potassium and calcium nitrate coatings on rocks, often in caves and rock

  13. EML Procedures Manual, HASL-300

    SciTech Connect (OSTI)

    Not Available

    1981-09-28T23:59:59.000Z

    Additions and corrections for the EML Procedures Manual, HASL-300, are presented for the following areas: wet/dry collector; ion chamber; field gamma spectrometry; TLD; reactive gas monitoring; cesium; cadmium and lead; carbon dioxide; polynuclear aromatic hydrocarbons; manganese precipitation samples; iron precipitation samples; aluminium precipitation samples; and lead precipitation samples.

  14. PREDICTION OF DEFORMATION AND HOT TEAR FORMATION USING A VISCOPLASTIC MODEL WITH DAMAGE

    E-Print Network [OSTI]

    Beckermann, Christoph

    of the hot tears. Introduction The automotive industry is showing greater interest in magnesium alloys as they have a high strength to weight ratio when compared to steel or aluminum alloys. Because of their low was 8.61% aluminum, 0.6% zinc, 0.23% manganese, 0.017% silicon, 0.003% copper, 0.0038% iron, 0

  15. Evaluation of Novel Ceria-Supported Metal Oxides As Oxygen Carriers for Chemical-Looping Combustion

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    for copper-based materials, and at 950 °C for iron- and manganese-based materials. Methane or syngas (50% COEvaluation of Novel Ceria-Supported Metal Oxides As Oxygen Carriers for Chemical-Looping Combustion of Chemical and Biological Engineering, Chalmers University of Technology, SE-412 96 Goteborg, Sweden

  16. MAY 2011 EXAMINATION DIET SCHOOL OF MATHEMATICS & STATISTICS

    E-Print Network [OSTI]

    St Andrews, University of

    : Knowledge Discovery and Data Mining EXAM DURATION: 2 hours EXAM INSTRUCTIONS Attempt ALL questions THIS EXAM PAPER UNTIL YOU ARE INSTRUCTED TO DO SO. Page 1 of 6 #12;1. (a) Write down the linear regression Index (RI) and the 8 oxides sodium (Na), manganese (Mg), aluminium (Al), silicon (Si), potassium (K

  17. Process for decomposing lignin in biomass

    DOE Patents [OSTI]

    Rector, Kirk Davin; Lucas, Marcel; Wagner, Gregory Lawrence; Kimball, David Bryan; Hanson, Susan Kloek

    2014-10-28T23:59:59.000Z

    A mild inexpensive process for treating lignocellulosic biomass involves oxidative delignification of wood using an aqueous solution prepared by dissolving a catalytic amount of manganese (III) acetate into water and adding hydrogen peroxide. Within 4 days and without agitation, the solution was used to convert poplar wood sections into a fine powder-like delignified, cellulose rich materials that included individual wood cells.

  18. N e w E n g l a n d W a t e r T r e a t m e n t Technology Assistance Center

    E-Print Network [OSTI]

    filtration, iron and manganese control and arsenic removal. The CD was designed to educate state and federal and location of full-scale facilities Multimedia, graphic, and design elements were an important feature program incorporating text, graphics, photos, video, and other multimedia · Obtaining external peer

  19. OPEN OCEAN OPERATIONAL EXPERIENCE WITH THE AUTOSUB-1 AUTONOMOUS UNDERWATER VEHICLE

    E-Print Network [OSTI]

    Griffiths, Gwyn

    secondary (lead-acid) and primary (manganese alkaline) batteries have been used to power the vehicle. Using sealed lead-acid batteries the maximum mission endurance is 10 hours, whereas with the primary battery.8 m long and 0.9 m in diameter with a battery payload capacity of 300 kg and a sensor capacity of 1000

  20. Reactive transport of trace elements and isotopes in the Eutaw coastal plain aquifer, Alabama

    E-Print Network [OSTI]

    Wang, Yang

    geochemistry, mineralogy, and numerical modeling techniques to study the reactive transport of heavy metals ground- water geochemistry. Because the possible biogeochemical reactions in regional aquifers are quite suggest that that elevated metal concentrations may be derived from bacterial iron and manganese reduction

  1. UNIVERSIT DEGLI STUDI DI PADOVA Ufficio Stampa

    E-Print Network [OSTI]

    Cesare, Bernardo

    , in grado di generare ossigeno dall'acqua, in presenza di luce solare. Quattro atomi di Manganese'enzima foto sintetico II (PS2), grazie al quale le foglie verdi riescono ad immagazzinare l'energia della luce solare per rigenerare quotidianamente ossigeno e riconvertire l'anidride carbonica liberata nell

  2. Sampling and analytical testing of groundwater and surface water at the Colorado School of Mines Research Institute (CSMRI) has been conducted on a quarterly basis since early

    E-Print Network [OSTI]

    is being consumed, changing the water chemistry, and leading to lower uranium concentrations with flow, Th-230, Th-232, and uranium), and metals (arsenic, barium calcium, cadmium, chromium, lead, manganese and analytical testing for radium, calcium, magnesium, potassium, sodium, uranium, and zinc will continue

  3. Process for producing dimethyl ether from synthesis gas

    DOE Patents [OSTI]

    Pierantozzi, R.

    1985-06-04T23:59:59.000Z

    This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.

  4. Process for producing dimethyl ether form synthesis gas

    DOE Patents [OSTI]

    Pierantozzi, Ronald (Macungie, PA)

    1985-01-01T23:59:59.000Z

    This invention pertains to a Fischer Tropsch process for converting synthesis gas to an oxygenated hydrocarbon with particular emphasis on dimethyl ether. Synthesis gas comprising carbon monoxide and hydrogen are converted to dimethyl ether by carrying out the reaction in the presence of an alkali metal-manganese-iron carbonyl cluster incorporated onto a zirconia-alumina support.

  5. Chronic exposure of sheep to a zinc smelter in Peru

    SciTech Connect (OSTI)

    Reif, J.S.; Ameghino, E.; Aaronson, M.J.

    1989-06-01T23:59:59.000Z

    Liver levels of arsenic, cadmium, copper, lead, manganese, and zinc were assessed in adult female sheep living in the vicinity of a zinc smelter in Peru. The study was conducted on a large sheep-raising cooperative divided into seven management units, operated under a standardized husbandry system. Soil samples were analyzed for the same metals at varying distances from the smelter. A gradient of concentration of heavy metals in soil was found between 1 and 56 km from the smelter. Soil concentrations for all metals except manganese decreased significantly with increasing distance from the smelter. The strongest correlations were found for copper, lead, and zinc (P less than 0.001). Topographic features and prevailing wind direction appeared to play a role in the dispersion of pollutants. Liver samples were obtained from 153 sheep on five units of the cooperative. The centers of the units sampled were between 13 and 56 km from the smelter. Hepatic concentrations of arsenic, lead, manganese, and zinc decreased significantly with increasing distance from the smelter. Liver arsenic and liver zinc were significantly related to soil concentrations. Liver levels of arsenic, cadmium, lead, and manganese in sheep from the cooperative were significantly higher than those detected in control sheep from southern Peru. Sheep populations may serve as biological monitors for heavy metal accumulation and environmental carcinogenesis.

  6. Metal articles having ultrafine particles dispersed therein

    SciTech Connect (OSTI)

    Alexander, G.B.; Nadkarni, R.A.

    1992-07-28T23:59:59.000Z

    This patent describes a metal article of manufacture. It comprises: a metal selected from the group consisting of copper, silver, gold, lead, tin, nickel, zinc, cobalt, antimony, bismuth, iron, cadmium, chromium, germanium, gallium, selenium, tellurium, mercury, tungsten arsenic, manganese, iridium, indium, ruthenium, rhenium, rhodium, molybdenum, palladium, osmium and platinum; and a plurality of ultrafine particles.

  7. New Neutron Cross-Section Measurements from ORELA and New Resonance Parameter Evaluations

    SciTech Connect (OSTI)

    Guber, Klaus H [ORNL; Koehler, Paul [ORNL; Wiarda, Dorothea [ORNL; Harvey, John A [ORNL; Valentine, Timothy E [ORNL; Sayer, Royce O [ORNL; Leal, Luiz C [ORNL; Larson, Nancy M [ORNL; Bigelow, Tim S [ORNL

    2008-01-01T23:59:59.000Z

    A series of new measurements has been undertaken in response to deficiencies identified in nuclear data libraries of crucial importance to the Nuclear Criticality Safety Program. New data and evaluations, including covariances, are required for several materials found in mixtures with uranium. For this purpose we performed neutron capture and total cross-section measurements on natural potassium, {sup 41}K, and manganese.

  8. Comparative study on corrosion behaviour of pure Mg and WE43 alloy in static, stirring and

    E-Print Network [OSTI]

    Zheng, Yufeng

    of magnesium based alloys are those that contain 2­10 wt-% aluminium with trace additions of zinc and manganeseComparative study on corrosion behaviour of pure Mg and WE43 alloy in static, stirring and flowing Hank's solution N. Li1 , C. Guo1 , Y. H. Wu1 , Y. F. Zheng*1 and L. Q. Ruan2 WE43 magnesium alloy has

  9. Mineral resources of Cactus Plain and East Cactus Plain Wilderness Study Areas, La Paz County, Arizona

    SciTech Connect (OSTI)

    Tosdal, R.M.; Eppinger, R.G.; Erdman, J.A.; Hanna, W.F.; Pitkin, J.A.; Blank, H.R. Jr.; O'Leary, R.M.; Watterson, J.R. (US Geological Survey (US)); Kreidler, T.J. (US Bureau of Mines (US))

    1990-01-01T23:59:59.000Z

    This paper reports on geologic, geochemical, and geophysical studies in the Cactus Plain and East Cactus Plain Wilderness Study Areas outlined in areas with moderate to high potential for gold, silver, copper, lead, zinc, barite, fluorite, manganese, and sand suitable for foundry, fracturing, and abrasive uses and low resource potential for beryllium, uranium and bentonitic clays.

  10. Department of Slavic Languages and Literature University of Wisconsin-Madison

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    ? · Russian is a strategic world language: Russia spans 9 time zones and covers about 1/8th of the world, including petroleum, diamonds, gold, copper, manganese, uranium, silver, graphite, platinum, and timber's largest natural gas reserves, and holds the second-largest coal reserves in the world. It is a top

  11. Distinctly Ambitious www.hw.ac.uk

    E-Print Network [OSTI]

    Painter, Kevin

    allowed the company to realise the crucial areas where change is required to allow significant improvement crossing (CMX) products that are produced from austenitic manganese steel (AMS). The company, initially to the desired lead time of 12 weeks. The company's competitive position has improved mainly through industrial

  12. Atomic-resolution study of Mn tetramer clusters using scanning tunneling Rong Yang, Haiqiang Yang, and Arthur R. Smitha

    E-Print Network [OSTI]

    Atomic-resolution study of Mn tetramer clusters using scanning tunneling microscopy Rong Yang clusters is investigated. The clusters are composed of a quadrant array of Mn atoms forming a tetramer of manganese nitride, on which are stabilized peri- odic, self-organized array of MnN-bonded Mn tetramer clus

  13. Nitrated metalloporphyrins as catalysts for alkane oxidation

    DOE Patents [OSTI]

    Ellis, P.E. Jr.; Lyons, J.E.

    1994-01-18T23:59:59.000Z

    Compositions of matter comprising nitro-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has nitro groups attached thereto in meso and/or [beta]-pyrrolic positions.

  14. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation

    DOE Patents [OSTI]

    Ellis, P.E. Jr.; Lyons, J.E.

    1995-01-17T23:59:59.000Z

    New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or [beta]-pyrrolic positions.

  15. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation

    DOE Patents [OSTI]

    Ellis, P.E. Jr.; Lyons, J.E.

    1993-05-18T23:59:59.000Z

    New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso- and/or [beta]-pyrrolic positions.

  16. One-electron oxidation in the degradation of creosote polycyclic aromatic hydrocarbons by Phanerochaete chrysoporium

    SciTech Connect (OSTI)

    Bogan, B.W. [Univ. of Wisconsin, Madison, WI (United States)]|[USDA Forest Service Forest Products Lab., Madison, WI (United States); Lamar, R.T. [USDA Forest Service Forest Products Lab., Madison, WI (United States)

    1995-07-01T23:59:59.000Z

    The abilities of whole cultures of Phanerochaete chrysosporium and P. chrysosporium manganese peroxidase-mediated lipid peroxidation reactions to degrade the polycyclic aromatic hydrocarbons (PAHs) found in creosote were studied. The disappearance of 12 three- to six-ring PAHs occurred in both systems. Both in vivo and in vitro, the disappearance of all PAHs was found to be very strongly correlated with ionization potential. This was true even for compounds beyond the ionization potential thresholds of lignin peroxidase and Mn{sup 3+}. Deviations from this correlation were seen in the cases of PAHs which are susceptible to radical addition reactions. These results thus begin to clarify the mechanisms of non-lignin peroxidase-labile PAH degradation in the manganese peroxidase-lipid peroxidation system and provide further evidence for the ability of this system to explain the in vivo oxidation of these compounds. 35 refs., 5 figs., 2 tabs.

  17. Mn-Fe base and Mn-Cr-Fe base austenitic alloys

    DOE Patents [OSTI]

    Brager, Howard R. (Richland, WA); Garner, Francis A. (Richland, WA)

    1987-01-01T23:59:59.000Z

    Manganese-iron base and manganese-chromium-iron base austenitic alloys designed to have resistance to neutron irradiation induced swelling and low activation have the following compositions (in weight percent): 20 to 40 Mn; up to about 15 Cr; about 0.4 to about 3.0 Si; an austenite stabilizing element selected from C and N, alone or in combination with each other, and in an amount effective to substantially stabilize the austenite phase, but less than about 0.7 C, and less than about 0.3 N; up to about 2.5 V; up to about 0.1 P; up to about 0.01 B; up to about 3.0 Al; up to about 0.5 Ni; up to about 2.0 W; up to about 1.0 Ti; up to about 1.0 Ta; and with the remainder of the alloy being essentially iron.

  18. Water quality effects of tire chip fills placed above the groundwater table

    SciTech Connect (OSTI)

    Humphrey, D.N.; Katz, L.E. [Univ. of Maine, Orono, ME (United States). Dept. of Civil and Environmental Engineering; Blumenthal, M. [Scrap Tire Management Council, Washington, DC (United States)

    1997-12-31T23:59:59.000Z

    Two field trials were constructed to investigate the effect on water quality of tire chip fills placed above the groundwater table. Control wells were used to distinguish the substances naturally present in groundwater from those that leached from tire chips. There was no evidence that tire chips increased the level of substances that have a primary drinking water standard. In addition, there was no evidence that tire chips increased the levels of aluminum, zinc, chloride or sulfate which have secondary (aesthetic) drinking water standards. Under some conditions iron levels may exceed their secondary standard. It is likely that manganese levels will exceed their secondary standard, however, manganese is naturally present in groundwater in many areas. Two sets of samples were tested for organics. Results were below the method detection limit for all compounds.

  19. Embrittlement of RPV steels; An atom probe tomography perspective

    SciTech Connect (OSTI)

    Miller, Michael K [ORNL; Russell, Kaye F [ORNL

    2007-01-01T23:59:59.000Z

    Atom probe tomography has played a key role in the understanding of the embrittlement of neutron irradiated reactor pressure vessel steels through the atomic level characterization of the microstructure. Atom probe tomography has been used to demonstrate the importance of the post weld stress relief treatment in reducing the matrix copper content in high copper alloys, the formation of {approx}-nm-diameter copper-, nickel-, manganese- and silicon-enriched precipitates during neutron irradiation in copper containing RPV steels, and the coarsening of these precipitates during post irradiation heat treatments. Atom probe tomography has been used to detect {approx}2-nm-diameter nickel-, silicon- and manganese-enriched clusters in neutron irradiated low copper and copper free alloys. Atom probe tomography has also been used to quantify solute segregation to, and precipitation on, dislocations and grain boundaries.

  20. Three very young HgMn stars in the Orion OB1 Association

    E-Print Network [OSTI]

    Vincent M. Woolf; David L. Lambert

    1999-05-18T23:59:59.000Z

    We report the detection of three mercury-manganese stars in the Orion OB1 association. HD 37886 and BD-0 984 are in the approximately 1.7 million year old Orion OB1b. HD 37492 is in the approximately 4.6 million year old Orion OB1c. Orion OB1b is now the youngest cluster with known HgMn star members. This places an observational upper limit on the time scale needed to produce the chemical peculiarities seen in mercury-manganese stars, which should help in the search for the cause or causes of the peculiar abundances in HgMn and other chemically peculiar upper main sequence stars.