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Sample records for malta pf paracel

  1. Demetrio Aguilera Malta (1909-1981)

    E-Print Network [OSTI]

    Carbó n Gorell, Lynn

    1982-04-01

    , dramaturgo, dibu jante, diplomático, periodista, y director de cine. Fue editor de libros y revis tas, entre ellas Trópico, Hoy y Mundo, en Quito, Panamá y México, respecti vamente. Dio cursos y conferencias en diversas universidades e institutos... Comendador. Su primer éxito como novelista ocurre con la publicación de Don Goyo en 1933 en que trata de la fascinación por la mitología india y la fuerza de la na turaleza, temas que toman importancia al desarrollarse la obra de Aguilera Malta y que...

  2. Malta: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas:Montezuma,Information MHKMHK5Transport Projects |NIESMalheurMallard LakeMalta:

  3. 21PF overpack problems

    SciTech Connect (OSTI)

    Kovac, F.M.

    1995-12-31

    The 21PF overpack has had severe metal corrosion and stress corrosion cracking (SCC) for many years. The US Department of Transportation (DOT) and the US Nuclear Regulatory Commission (NRC) have disallowed the use of overpacks containing high chloride foam. Corrosion and SCC of 21PF overpacks have been documented and papers have been presented at conferences about these issues. Regulatory agencies have restricted 21PF overpack use and have requested data to determine if phenolic foam overpacks not meeting original design specifications will be authorized for continued use. This paper details some of the problems experienced by users and relates actions of the DOT and NRC concerning these packages. Industry is working to correct deficiencies, but if they are not successful, the entire uranium enrichment industry will be severely impacted.

  4. PF-4 actinide disposition strategy

    SciTech Connect (OSTI)

    Margevicius, Robert W [Los Alamos National Laboratory

    2010-05-28

    The dwindling amount of Security Category I processing and storage space across the DOE Complex has driven the need for more effective storage of nuclear materials at LANL's Plutonium Facility's (PF-4's) vault. An effort was begun in 2009 to create a strategy, a roadmap, to identify all accountable nuclear material and determine their disposition paths, the PF-4 Actinide Disposition Strategy (PADS). Approximately seventy bins of nuclear materials with similar characteristics - in terms of isotope, chemical form, impurities, disposition location, etc. - were established in a database. The ultimate disposition paths include the material to remain at LANL, disposition to other DOE sites, and disposition to waste. If all the actions described in the document were taken, over half of the containers currently in the PF-4 vault would been eliminated. The actual amount of projected vault space will depend on budget and competing mission requirements, however, clearly a significant portion of the current LANL inventory can be either dispositioned or consolidated.

  5. Los Alamos National Laboratory Plutonium Facility (PF-4) Seismic...

    Office of Environmental Management (EM)

    Laboratory Plutonium Facility (PF-4) Seismic Safety Los Alamos National Laboratory Plutonium Facility (PF-4) Seismic Safety Los Alamos National Laboratory Plutonium Facility (PF-4)...

  6. May 23, 2001 Review of FIRE TF, PF, Structures

    E-Print Network [OSTI]

    May 23, 2001 Review of FIRE TF, PF, Structures VV, PFC's, Fueling and Pumping June 5-7, 2001, June 5--TF/PF/Structures Organization of Review and Charge to Reviewers Schmidt & Chairman of Reviewers & Allowables Zatz (20+10) 1345-1415 Structural Analyses Titus (60+15) 1415-1530 break 1530-1545 Discussion

  7. TPX: Contractor preliminary design review. Volume 2, PF systems engineering

    SciTech Connect (OSTI)

    Calvin, H.A.

    1995-07-28

    This system development specification covers the Poloidal Field (PF) Magnet System, WBS 14 in the Princeton Plasma Physics Laboratory TPX Program to build a tokamak fusion reactor. This specification establishes the performance, design, development and test requirements of the PF Magnet System.

  8. TRAC-PF1 choked-flow model

    SciTech Connect (OSTI)

    Sahota, M.S.; Lime, J.F.

    1983-01-01

    The two-phase, two-component choked-flow model implemented in the latest version of the Transient Reactor analysis Code (TRAC-PF1) was developed from first principles using the characteristic analysis approach. The subcooled choked-flow model in TRAC-PF1 is a modified form of the Burnell model. This paper discusses these choked-flow models and their implementation in TRAC-PF1. comparisons using the TRAC-PF1 choked-flow models are made with the Burnell model for subcooled flow and with the homogeneous-equilibrium model (HEM) for two-phae flow. These comparisons agree well under homogeneous conditions. Generally good agreements have been obtained between the TRAC-PF1 results from models using the choking criteria and those using a fine mesh (natural choking). Code-data comparisons between the separate-effects tests of the Marviken facility and the Edwards' blowdown experiment also are favorable. 10 figures.

  9. Hurricane Emergency Shutdown Actions June 24, 2014 Chancellor directs P&F to commence emergency preparations 1

    E-Print Network [OSTI]

    &F) 8 Commence Boiler Shutdown (P&F) 9 Remove perishable items from kitchenette refrigerators (P&F). 10-44 School of Dentistry - Shutdown Boiler (P&F) 27 School of Dentistry - Move waste to Rm 8412, Clinic Bldg - Shutdown Chiller/Cooling Tower (P&F) 48 Residence Hall - Shutdown Domestic Hot Water Boiler (P&F) 49 Legend

  10. TRAC-PF1/MOD2 status and plans

    SciTech Connect (OSTI)

    Spore, J.W.; Nelson, R.A.; Steinke, R.; Cappiello, M.; Jenks, R.

    1988-01-01

    The development of the TRAC-PF1/MOD1 code was completed in July 1988 with the release of Version 14.4. A TRAC-PF1/MOD2 code development plan addresses code deficiencies identified in the MOD1 code in order to provide an accurate and defensible tool that can be used to simulate large-break loss-of-coolant accidents (LOCAs), small-break LOCAs, and operational transients. The MOD2 code development plan is an international cooperative effort that includes contributions from Los Alamos National Laboratory, Idaho National Engineering Laboratory (INEL), Japanese Atomic Energy Research Institute (JAERI), Cray Research, Central Electricity Generating Board (CEGB), and United Kingdom Atomic Energy Authority (UKAEA). 8 refs., 7 figs.

  11. Neutron scattering investigation of (TMTTF)2PF6

    E-Print Network [OSTI]

    Paris-Sud 11, Université de

    of excitations gapped (Uhrig et Schulz PRB 54, R9624 (1996)) at 2 S=0 S=1 #12;Magnetic excitations in the SP: l(q)= +E(q) and s(q)= 2{sup[E(q/2),E[(q-qSP)/2]} (Uhrig & Schulz PRB 54, R9624 (1996)) qSP=/a #12-Leylekian et al PRB 7 R180405 (2004)) #12;TSP=13K Thermal dependence of the (TMTTF)2PF6 (D12) (1

  12. TRAC-PF1/MOD1 assessment at Los Alamos

    SciTech Connect (OSTI)

    Knight, T.D.

    1984-01-01

    The Los Alamos National Laboratory is developing the Transient Reactor Analysis Code (TRAC) to provide an advanced best-estimate predictive capability for the analysis of postulated accidents in pressurized water reactors (PWRs). Over the past several years, four distinct versions of the code have been released; each new version introduced improvements to the existing models and numerics and added new models to extend the applications of the code. The first goal of the code was to analyze large-break loss-of-coolant accidents (LOCAs), and the TRAC-P1A and TRAC-PD2 codes primarily addressed the large-break LOCA. (The TRAC-PD2/MOD1 code is essentially the same as the TRAC-PD2 code but it also includes a released set of error corrections.) The TRAC-PF1 code contained major changes to the models and trips and to the numerical methods. These modifications enhanced the computational speed of the code and improved the application to small-break LOCAs. The TRAC-PF1/MOD1 code, the latest released version, added improved steam-generator modeling, a turbine component, and a control system together with modified constitutive relations to model the balance of plant on the secondary side and to extend the applications to non-LOCA transients. The TRAC-PF1/MOD1 code also contains reasonably general reactor-kinetics modeling to facilitate the simulation of transients with delayed scram or without scram. 13 references, 24 figures.

  13. TRAC-PF1/MOD1 computer code. [PWR

    SciTech Connect (OSTI)

    Liles, D.R.; Mahaffy, J.H.

    1983-01-01

    TRAC-PF1 was designed to improve the ability of TRAC-PD2 to handle small-break LOCAs and other transients. TRAC-PF1 has all of the major improvements of TRAC-PD2 but, in addition, uses a full two-fluid model with two-step numerics in the one-dimensional components. The two-fluid model, in conjunction with a stratified-flow regime, handles countercurrent flow better than the drift-flux model previously used. The two-step numerics allow large time steps to be taken for slow transients. TRAC-PF1/MOD1 was designed to provide full balance-of-plant modeling capabilities. This required addition of a general capability for modeling plant control systems. The steam generator model was replaced to allow a wider variety of feedwater connections and better modeling of steam tube ruptures. A special turbine component also has been added, but new components were not required for adequate modeling of condensors, heaters, and pumps in the secondary system.

  14. TRAC-PF1/MOD1 computer code

    SciTech Connect (OSTI)

    Liles, D.R.; Mahaffy, J.H.

    1984-01-01

    The TRAC-P1 program was designed primarily for the analysis of large-break loss-of-coolant accidents (LOCAs) in pressurized water reactors (PWRs). Because of its versatility, however, it can be applied directly to many analyses ranging from blowdowns in simple pipes to integral LOCA tests in multiloop facilities. A refined version, called TRAC-P1A, was released to the National Energy Software Center (NESC) in March 1979. Although it still treats the same class of problems, TRAC-P1A is more efficient than TRAC-P1 and incorporates improved hydrodynamic and heat-transfer models. It also is easier to implement on various computers. TRAC-PD2 contains improved reflood and heat-transfer models and improvements in the numerical solution methods. Although a large LOCA code, it has been applied successfully to small-break problems and to the Three Mile Island incident. Distinguishing characteristics of the TRAC-PF1/MOD1 are summarized.

  15. The mechanism of HF formation in LiPF6-based organic carbonate electrolytes

    E-Print Network [OSTI]

    Lux, Simon

    2014-01-01

    The mechanism of HF formation in LiPF6-based organicliterature data, a simplified mechanism for the formation of3 . In this proposed mechanism, the blue lines represent the

  16. Physical and Mechanical Properties of Sugarcane Rind and Mixed Hardwood Oriented Strandboard Bonded with PF Resin

    E-Print Network [OSTI]

    comrind and hardwoods oriented strandboard (OSB) was manufactured using phenol formaldehyde (PF) resin, accounting for more than 40% of the total U.S. production (Rowell 1995). Large quantities of outer rinds (i

  17. 111-f:l.~A PfC, qs: Hoo control of boost converters

    E-Print Network [OSTI]

    ,I-.; ... 111- f:l.~A PfC, qs: f'EEEin !f Hoo control of boost converters Rami NAIM, George WEISS at low frequencies). In a case study, for a typical low power boost converter, we obtain significantly\\vitching frequency. Boost and buck-boost converters (in continuous conduction mode) have a zero in the right half

  18. Structural basis of HIV-1 capsid recognition by PF74 and CPSF6

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bhattacharya, Akash; Alam, Steven L.; Fricke, Thomas; Zadrozny, Kaneil; Sedzicki, Jaroslaw; Taylor, Alexander B.; Demeler, Borries; Pornillos, Owen; Ganser-Pornillos, Barbie K.; Diaz-Griffero, Felipe; et al

    2014-12-17

    Upon infection of susceptible cells by HIV-1, the conical capsid formed by ~250 hexamers and 12 pentamers of the CA protein is delivered to the cytoplasm. In this study, the capsid shields the RNA genome and proteins required for reverse transcription. In addition, the surface of the capsid mediates numerous host–virus interactions, which either promote infection or enable viral restriction by innate immune responses. In the intact capsid, there is an intermolecular interface between the N-terminal domain (NTD) of one subunit and the C-terminal domain (CTD) of the adjacent subunit within the same hexameric ring. The NTD–CTD interface is criticalmore »for capsid assembly, both as an architectural element of the CA hexamer and pentamer and as a mechanistic element for generating lattice curvature. Here we report biochemical experiments showing that PF-3450074 (PF74), a drug that inhibits HIV-1 infection, as well as host proteins cleavage and polyadenylation specific factor 6 (CPSF6) and nucleoporin 153 kDa (NUP153), bind to the CA hexamer with at least 10-fold higher affinities compared with nonassembled CA or isolated CA domains. The crystal structure of PF74 in complex with the CA hexamer reveals that PF74 binds in a preformed pocket encompassing the NTD–CTD interface, suggesting that the principal inhibitory target of PF74 is the assembled capsid. Likewise, CPSF6 binds in the same pocket. Given that the NTD–CTD interface is a specific molecular signature of assembled hexamers in the capsid, binding of NUP153 at this site suggests that key features of capsid architecture remain intact upon delivery of the preintegration complex to the nucleus.« less

  19. Structural basis of HIV-1 capsid recognition by PF74 and CPSF6

    SciTech Connect (OSTI)

    Bhattacharya, Akash; Alam, Steven L.; Fricke, Thomas; Zadrozny, Kaneil; Sedzicki, Jaroslaw; Taylor, Alexander B.; Demeler, Borries; Pornillos, Owen; Ganser-Pornillos, Barbie K.; Diaz-Griffero, Felipe; Ivanov, Dmitri N.; Yeager, Mark

    2014-12-17

    Upon infection of susceptible cells by HIV-1, the conical capsid formed by ~250 hexamers and 12 pentamers of the CA protein is delivered to the cytoplasm. In this study, the capsid shields the RNA genome and proteins required for reverse transcription. In addition, the surface of the capsid mediates numerous host–virus interactions, which either promote infection or enable viral restriction by innate immune responses. In the intact capsid, there is an intermolecular interface between the N-terminal domain (NTD) of one subunit and the C-terminal domain (CTD) of the adjacent subunit within the same hexameric ring. The NTD–CTD interface is critical for capsid assembly, both as an architectural element of the CA hexamer and pentamer and as a mechanistic element for generating lattice curvature. Here we report biochemical experiments showing that PF-3450074 (PF74), a drug that inhibits HIV-1 infection, as well as host proteins cleavage and polyadenylation specific factor 6 (CPSF6) and nucleoporin 153 kDa (NUP153), bind to the CA hexamer with at least 10-fold higher affinities compared with nonassembled CA or isolated CA domains. The crystal structure of PF74 in complex with the CA hexamer reveals that PF74 binds in a preformed pocket encompassing the NTD–CTD interface, suggesting that the principal inhibitory target of PF74 is the assembled capsid. Likewise, CPSF6 binds in the same pocket. Given that the NTD–CTD interface is a specific molecular signature of assembled hexamers in the capsid, binding of NUP153 at this site suggests that key features of capsid architecture remain intact upon delivery of the preintegration complex to the nucleus.

  20. TRAC-PF1/MOD1 post-test calculations of the OECD LOFT Experiment LP-SB-3

    SciTech Connect (OSTI)

    Allen, E J; Neill, A P [UKAEA Atomic Energy Establishment, Winfrith (UK)

    1990-04-01

    Analysis of the small, cold leg break, OECD LOFT Experiment LP-SB-3 using the best-estimate computer code TRAC-PF1/MOD1 is presented. Descriptions of the LOFT facility and the LP-SB-3 experiment are given and development of the TRAC-PF1/MOD1 input model is detailed. The calculations performed in achieving the steady state conditions, from which the experiment was initiated, and the specification of experimental boundary conditions are outlined. Results of the TRAC-PF1/MOD1 calculation are found to be generally consistent with those reported, by members of the OECD LOFT Program Review Group, in the LP-SB-3 Comparison Report.'' Overall trends with respect to pressure histories, minimum primary system mass inventory and accumulator behaviour are reasonably well reproduced by TRAC-PF1/MOD1. 17 refs., 26 figs., 3 tabs.

  1. TRAC-PF1/MOD1 pretest predictions of MIST experiments

    SciTech Connect (OSTI)

    Boyack, B.E.; Steiner, J.L.; Siebe, D.A.

    1986-01-01

    Los Alamos National Laboratory is a participant in the Integral System Test (IST) program initiated in June 1983 to provide integral system test data on specific issues and phenomena relevant to post small-break loss-of-coolant accidents (SBLOCAs) in Babcock and Wilcox plant designs. The Multi-Loop Integral System Test (MIST) facility is the largest single component in the IST program. During Fiscal Year 1986, Los Alamos performed five MIST pretest analyses. The five experiments were chosen on the basis of their potential either to approach the facility limits or to challenge the predictive capability of the TRAC-PF1/MOD1 code. Three SBLOCA tests were examined which included nominal test conditions, throttled auxiliary feedwater and asymmetric steam-generator cooldown, and reduced high-pressure-injection (HPI) capacity, respectively. Also analyzed were two ''feed-and-bleed'' cooling tests with reduced HPI and delayed HPI initiation. Results of the tests showed that the MIST facility limits would not be approached in the five tests considered. Early comparisons with preliminary test data indicate that the TRAC-PF1/MOD1 code is correctly calculating the dominant phenomena occurring in the MIST facility during the tests. Posttest analyses are planned to provide a quantitative assessment of the code's ability to predict MIST transients.

  2. Down-regulation of four putative arabinoxylan feruloyl transferase genes from family PF02458 reduces ester-linked ferulate content in rice cell walls

    E-Print Network [OSTI]

    Piston, Fernando; Uauy, Cristobal; Fu, Lianhai; Langston, James; Labavitch, John; Dubcovsky, Jorge

    2010-01-01

    of four putative arabinoxylan feruloyl transferase genescan cross- link different arabinoxylan molecules in the cellPF02458 may act as arabinoxylan feruloyl transferases. We

  3. TRAC-PF1 MOD1 post test calculations of the OECD LOFT Experiment LP-SB-1

    SciTech Connect (OSTI)

    Allen, E J [UKAEA Atomic Energy Establishment, Winfrith (UK)

    1990-04-01

    Analysis of the small, hot leg break, OECD LOFT Experiment LP-SB-1. using the best-estimate'' computer code TRAC-PF1/MOD1 is presented. Descriptions of the LOFT facility and the LP-SB-1 experiment are given and development of the TRAC-PF1/MOD1 input model is detailed. The calculations performed in achieving the steady state conditions, from which the experiment was initiated, and the specification of experimental boundary conditions are outlined. 24 refs., 66 figs., 12 tabs.

  4. Nuclear spin relaxation of sodium cations in bacteriophage Pf1 solutions D. N. Sobieski, N. R. Krueger, S. Vyas,a

    E-Print Network [OSTI]

    Augustine, Mathew P.

    Nuclear spin relaxation of sodium cations in bacteriophage Pf1 solutions D. N. Sobieski, N. R The nuclear magnetic resonance NMR spectra for the I=3/2 23 Na cation dissolved into filamentous bacteriophage the 23 Na nuclear quadrupole moment and the electric field gradient produced by the negatively charged Pf

  5. Thermal stability of LiPF6EC:EMC electrolyte for lithium ion batteries Gerardine G. Bottea

    E-Print Network [OSTI]

    Thermal stability of LiPF6±EC:EMC electrolyte for lithium ion batteries Gerardine G. Bottea , Ralph scanning calorimeter; Lithium ion batteries; Electrolyte; Thermal stability; Decomposition 1. Introduction Despite the improvement and developments in safety of the lithium ion batteries (PTC, CID, shutdown

  6. Direct measurement of the chemical reactivity of silicon electrodes with LiPF6-based battery electrolytes

    SciTech Connect (OSTI)

    Veith, Gabriel M; Baggetto, Loic; Sacci, Robert L; Unocic, Raymond R; Tenhaeff, Wyatt E; Browning, Jim

    2014-01-01

    We report the first direct measurement of the chemistry and extent of reactivity between a lithium ion battery electrode surface (Si) and a liquid electrolyte (1.2M LiPF6-3:7 wt% ethylene carbonate:dimethyl carbonate). This layer is estimated to be 3.6 nm thick and partially originates from the consumption of the silicon surface.

  7. Ultrafast gigantic photo-response in (EDO-TTF)2PF6 initiated by 10-fs laser pulses

    SciTech Connect (OSTI)

    Schoenlein, Robert William; Itatani, Jiro; Rini, Matteo; Cavalleri, Andrea; Onda, Ken; Ishikawa, Tadahiko; Koshihara, Shin-ya; Shao, Xiangfeng; Yamochi, Hideki; Saito, Gunzi; Schoenlein, Robert W.

    2006-08-07

    We photo-exited a charge-ordered organic salt (EDO-TTF)2PF6 with sub-10-fs optical pulses. The photo-induced metallic phase appeared within 80-fs after pumping, characterized by large changes in reflectivity (DELTA R/R~0.8) followed by strong coherent phonon modulation

  8. Thickness-dependent changes in the optical properties of PPV-and PF-based polymer light emitting diodes

    E-Print Network [OSTI]

    Carter, Sue

    the thickness-dependent optical properties of single layer polymer light emitting diodes for two materials, poly the electronic and optical properties of these materials in light emitting diode LED structures.2 OurThickness-dependent changes in the optical properties of PPV- and PF-based polymer light emitting

  9. A model for an under floor air distribution system Y.J.P. Lina,*, P.F. Lindenb

    E-Print Network [OSTI]

    Linden, Paul F.

    ; improved thermal comfort; improved ventilation efficiency and indoor air quality; reduced energy useA model for an under floor air distribution system Y.J.P. Lina,*, P.F. Lindenb a Energy gains that occur above the occupied zone are isolated from the calculation of the required space supply

  10. Posttest analysis of MIST Test 330302 using TRAC-PF1/MOD1

    SciTech Connect (OSTI)

    Boyack, B E [Los Alamos National Lab., NM (United States)

    1992-09-01

    This report discusses a posttest analysis of Multi-Loop Integral System Test (MIST) 330302 which has been performed using TRAC-PF1/MOD1. This test was one of group performed in the MIST facility to investigate high-pressure injection (HPI)-power-operated relief valve (PORV) cooling, also known as feed-and-bleed cooling. In Test 330302, HPI cooling was delayed 20 min after opening and locking the PORV open to induce extensive system voiding. We have concluded that the TRAC-calculated results are in reasonable overall agreement with the data for Test 330302. All major trends and phenomena were correctly predicted. Differences observed between the measured and calculated results have been traced and related, in part, to deficiencies in our knowledge of the facility configuration and operation. We have identified two models forwhich additional review is appropriate. However, in general, the TRAC closure models and correlations appear to be adequate for the prediction of the phenomena expected to occur during feed-and-bleed transientsin the MIST facility. We believe that the correct conclusions about trends and phenomena will be reached if the code is used in similar applications. Conclusions reached regarding use of the code to calculate similar phenomena in full-size plants (scaling implications) and regulatory implications of this work are also presented.

  11. PF131010 Ciechanow fireball - the body possible related to Near Earth Asteroids 2010 TB54 and 2010 SX11

    E-Print Network [OSTI]

    Olech, A; Wisniewski, M; Rudawska, R; Laskowski, J; Polakowski, K; Maciejewski, M; Krzyzanowski, T; Fajfer, T; Tyminski, Z

    2015-01-01

    On 2010 October 13, the Apollo type 20-meter asteroid 2010 TB54 passed within 6.1 lunar distances from the Earth. On the same date, but 11.4 hours earlier, exactly at 02:52:32 UT, the sky over central Poland was illuminated by -8.6 magnitude PF131010 Ciechanow fireball. The trajectory and orbit of the fireball was computed using multi-station data of Polish Fireball Network (PFN). The results indicate that the orbit of the meteoroid which caused the PF131010 fireball is similar to the orbit of 2010 TB54 asteroid and both bodies may be related. Moreover, two days before appearance of Ciechanow fireball another small asteroid denoted as 2010 SX11 passed close to the Earth-Moon system. Its orbit is even more similar to the orbit of Ciechanow fireball parent body than in case of 2010 TB54. The PF131010 Ciechanow entered Earth's atmosphere with the velocity of 12.9 +\\- 0.2 km/s and started to shine at height of 82.5 +\\- 0.3 km. Clear deceleration started after first three seconds of flight, and the terminal veloci...

  12. TRAC-PF1/MOD1 US/Japanese PWR conservative LOCA prediction

    SciTech Connect (OSTI)

    Gruen, G E; Fisher, J E

    1987-11-01

    This report documents the results of a 200%, double-ended, cold-leg-break, loss-of-coolant-accident (LOCA) calculation using the TRAC-PF1/MOD1 computer code. The reactor system represented a typical United States/Japanese pressurized water reactor with a 15 x 15 fuel bundle arrangement 12-ft long, four loops, and cold-leg Emergency Core Cooling (ECC) Systems. Conservation boundary and initial conditions were used. Reactor power was 102% of the 3250 MWt rated power, decay heat was set to 120% of American Nuclear Society Standard 5.1, highest core lifetime values for power peaking and fuel stored energy were used, and the LOCA occurred simultaneously with a loss of offsite power. Best estimate assumptions were used for the break flow model, fuel rod heat transfer and metal-water reaction correlations, and steady-state fuel temperature profiles. A flow blockage model, having the capability to account for the effects of cladding ballooning or rupturing, was not used. Except for these best estimate assumptions, the boundary and initial conditions were consistent with those used in licensing calculations. Maximum fuel rod temperatures were 1380 K (2020/sup 0/F) and 1040 K (1410/sup 0/F) on the hottest evaluation model rod and hottest best estimate rod, respectively. The high reported values or fuel cladding temperature were a direct consequence of the conservative boundary and initial conditions used for the calculation, primarily the 2% overpower condition, the core decay heat assumption, and the degraded ECCS. The calculation demonstrated successful core reflooding before 1478 K (2200/sup 0/F) cladding temperature was exceeded on any fuel rod. 7 refs., 47 figs., 5 tabs.

  13. Computational Studies of [Bmim][PF6]/n-Alcohol Interfaces with Many-Body Potentials

    SciTech Connect (OSTI)

    Chang, Tsun-Mei; Dang, Liem X.

    2014-09-04

    In this paper, we present the results from molecular-dynamics simulations of the equilibrium properties of liquid/liquid interfaces of room temperature ionic liquid [bmim][PF6] and simple alcohols (i.e., methanol, 1-butanol, and 1-hexanol) at room temperature. Polarizable potential models are employed to describe the interactions among species. Results from our simulations show stable interfaces between the ionic liquid and n-alcohols, and we found that the interfacial widths decrease from methanol to 1-butanol systems, and then increase for 1-hexanol interfaces. Angular distribution analysis reveals that the interface induces a strong orientational order of [bmim] and n-alcohol molecules near the interface, with [bmim] extending its butyl group into the alcohol phase while the alcohol has the OH group pointing into the ion liquid region, which is consistent with the recent sum-frequency-generation experiments. We found the interface to have a significant influence on the dynamics of ionic liquids and n-alcohols. The orientational autocorrelation functions illustrate that [bmim] rotate more freely near the interface than in the bulk, while the rotation of n-alcohol is hindered at the interface. Additionally, the time scale associated with the diffusion along the interfacial direction is found to be faster for [bmim] but slowed down for n-alcohols approaching the interface. We also calculate the dipole moment of n-alcohols as a function of the distance normal to the interface. We found that, even though methanol and 1-butanol have different dipole moments in bulk phase, they reach a similar value at the interface. This work was supported by the U.S. Department of Energy, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for the Department of Energy by Battelle. The calculations were carried out using computer resources provided by the Office of Basic Energy Sciences.

  14. A review of "A True Account of the Great Tryals and Cruel Sufferings Undergone by those Two Faithful Servants of God, Katherine Evans and Sarah Cheevers: La vicenda di due quacchere prigioniere dell’inquisizione di Malta." by Stefano Villani ed. 

    E-Print Network [OSTI]

    Julie D. Campbell

    2005-01-01

    between women?s active agency?often dismissed or diminished?and property law. Stefano Villani, ed. A True Account of the Great Tryals and Cruel Sufferings Undergone by those Two Faithful Servants of God, Katherine Evans and Sarah Cheevers: La vicenda... of the Isle of Malta (1662); To all People upon the face of the Earth: A sweet Salutation and a clear Manifestation of the True Light, which lighteth every one who cometh into the World (1662) by Sarah Cheevers; and A brief discovery of God?s Eternal...

  15. AP600 large-break loss-of-collant-accident developmental assessment plan for TRAC-PF1/MOD2

    SciTech Connect (OSTI)

    Knight, T.D.

    1996-07-01

    The Westinghouse AP600 reactor is an advanced pressurized water reactor with passive safety systems to protect the plant against possible accidents and transients. The design has been submitted to the U.S. NRC for design certification. The NRC has selected the Transient Reactor Analysis Code (TRAC)-PF1/MOD2 for performing large break loss-of coolant-accident (LBLOCA) analysis to support the certification effort. This document defines the tests to be used in the current phase of developmental assessment related to AP600 LBLOCA.

  16. TRAC-PF1/MOD1 thermal-hydraulic predictions of JAERI Slab Core Test Facility gravity-feed tests

    SciTech Connect (OSTI)

    Gilbert, J.S.; Lin, J.C.

    1985-12-01

    The Transient Reactor Analysis Code, TRAC-PF1/MOD1, was used to analyze the Slab Core Test Facility gravity-feed tests (Runs 604, 605, 611, and 613) performed by the Japan Atomic Energy Research Institute. The objectives of the TRAC analysis are to compare the TRAC predictions with the test results and to assess the TRAC capability for simulating the core thermal-hydraulic behavior during the reflood phase of a large loss-of-coolant accident. In general, the TRAC-calculated results agree well with the data.

  17. TRAC-PF1 analysis of LOFT steam-generator feedwater transient test L9-1. [PWR

    SciTech Connect (OSTI)

    Meier, J.K.

    1983-01-01

    The Transient Reactor Analysis Code (TRAC-PF1) calculations were compared to test data from Loss-of-Fluid Test (LOFT) L9-1, which was a loss-of-feedwater transient. This paper includes descriptions of the test and the TRAC input and compares the TRAC-calculated results with the test data. We conclude that the code predicted the experiment well, given the uncertainties in the boundary conditions. The analysis indicates the need to model all the flow paths and heat structures, and to improve the TRAC wall condensation heat-transfer model.

  18. TRAC-PF1/MOD-1 analysis of Loss-Of-Flow Test L9-4

    SciTech Connect (OSTI)

    Meier, J.

    1985-01-01

    Los Alamos National Laboratory is developing the Transient Reactor Analysis Code (TRAC) to provide advanced best-estimate predictions of postulated accidents in pressurized water reactors (PWRs) and for many thermal-hydraulic experimental facilities. As part of our independent assessment of code version TRAC-PF1/MOD1, we analyzed Loss-of-Fluid Test (LOFT) L9-4 and compared the test data to the calculated results. This was an anticipated-transient-without-scram test in which the pumps were tripped, the steam generator main feedwater discontinued, and the main steam-outlet valve closed. This data comparison is the first extensive test of TRAC's reactor-kinetics models. The comparisons show that TRAC can calculate the power generation within a nuclear reactor if the program is supplied with adequate reactor-kinetics input specifications. The data comparisons also indicate that TRAC calculated the thermal-hydraulic parameters within LOFT well with only minor discrepancies. A number of models within TRAC-PF1/MOD1 were verified for the first time. They include the reactor-kinetics models, the trip-activated time-step controls, and the LOFT pump-coastdown calculations. In general, the final input description is adequate to analyze the experiment. The calculations indicate the importance and difficulty of obtaining accurate and applicable reactor-kinetics input data. They also indicate the need to include the effects of xenon-poisoning buildup in the analysis.

  19. TRAC-PF1 analysis of loss-of-fluid test L6-7/L9-2

    SciTech Connect (OSTI)

    Meier, J.K.

    1984-01-01

    The Los Alamos National Laboratory is developing the Transient Reactor Analysis Code (TRAC-PF1) to provide the capability for advanced best-estimate predictions of postulated accidents in pressurized-water reactors (PWRs) and for many thermal-hydraulic experimental facilities. As part of an independent assessment of TRAC-PF1, Loss-of-Fluid Test (LOFT) L6-7/L9-2 is analyzed and compared to the calculated results. Test L6-7 simulated a cooldown transient similar to the Arkansas Nuclear One Unit-2 turbine-trip transient. During the L9-2 phase of the test, the primary-coolant pumps were tripped and natural circulation cooled the core while the plant cooldown continued. The TRAC results matched the test data well during the L6-7 portion of the transient (0.0-324 s). However, during the L9-2 portion the calculated natural-circulation flow rate in the intact loop was much higher than the measured rate.

  20. Uncertainties in modelling and scaling of critical flows and pump model in TRAC-PF1/MOD1

    SciTech Connect (OSTI)

    Rohatgi, U.S.; Yu, Wen-Shi

    1987-01-01

    The USNRC has established a Code Scalability, Applicability and Uncertainty (CSAU) evaluation methodology to quantify the uncertainty in the prediction of safety parameters by the best estimate codes. These codes can then be applied to evaluate the Emergency Core Cooling System (ECCS). The TRAC-PF1/MOD1 version was selected as the first code to undergo the CSAU analysis for LBLOCA applications. It was established through this methodology that break flow and pump models are among the top ranked models in the code affecting the peak clad temperature (PCT) prediction for LBLOCA. The break flow model bias or discrepancy and the uncertainty were determined by modelling the test section near the break for 12 Marviken tests. It was observed that the TRAC-PF1/MOD1 code consistently underpredicts the break flow rate and that the prediction improved with increasing pipe length (larger L/D). This is true for both subcooled and two-phase critical flows. A pump model was developed from Westinghouse (1/3 scale) data. The data represent the largest available test pump relevant to Westinghouse PWRs. It was then shown through the analysis of CE and CREARE pump data that larger pumps degrade less and also that pumps degrade less at higher pressures. Since the model developed here is based on the 1/3 scale pump and on low pressure data, it is conservative and will overpredict the degradation when applied to PWRs.

  1. TRAC PF1/MOD1 calculations and data comparisons for mist feed and bleed and steam generator tube rupture experiments

    SciTech Connect (OSTI)

    Siebe, D.A.; Boyack, B.E.; Steiner, J.L.

    1988-01-01

    Los Alamos National Laboratory is a participant in the Integral System Test (IST) program initiated in June 1983 for the purpose of providing integral system test data on specific issues/phenomena relevant to post-small-break loss-of-coolant accidents, loss of feedwater and other transients in Babcock and Wilcox (BandW) plant designs. The Multi-Loop Integral System Test (MIST) facility is the largest single component in the IST program. MIST is a 2 /times/ 4 (two hot legs and steam generators (SGs), four cold legs and reactor coolant pumps) representation of lowered-loop reactor system of the BandW design. It is a full-height, full-pressure facility with 1/817 power and volume scaling. Two other integral experimental facilities are included in the IST program: test loops at the University of Maryland, College Park, and at SRI International (SRI-2). The objective of the IST tests is to generate high-quality experimental data to be used for assessing thermal-hydraulic safety computer codes. Efforts are under way at Los Alamos to assess TRAC-PF1/MOD1 against data from each of the IST facilities. Calculations and data comparisons for TRAC-PF1/MOD1 assessment are presented for two transients run in the MIST facility. These are MIST Test 330302, a feed and bleed test with delayed high-pressure injection; and Test 3404AA, an SG tube-rupture test with the affected SG isolated. Only MIST assessment results are presented in this paper. The TRAC-PF1/MOD1 calculations completed to date for MIST tests are in reasonable agreement with the data from these tests. Reasonable agreement is defined as meaning that major trends are predicted correctly, although TRAC values are frequently outside the range of data uncertainty. We believe that correct conclusions will be reached if the code is used in similar applications despite minor code/model deficiencies. 7 refs., 5 figs., 2 tabs.

  2. Assessment of TRAC-PF1/MOD1 against a loss-of-grid transient in Ringhals 4 power plant

    SciTech Connect (OSTI)

    Sjoberg, A; Almberger, J; Sandervag, O

    1989-07-01

    A loss of grid transient in a three loop Westinghouse PWR has been simulated with the frozen version of TRAC-PF1/MOD1 computer code. The results reveal the capability of the code to qualitatively predict the different pertinent phenomena and the data comparison was quite encouraging. Accurate predictions of the system response required careful determination of the boundary conditions simulating the turbine governor valves and steam dump valves behaviour. An explicit modeling of the steam generator internals was also found to be important for the results. It was also revealed that the pressurizer system including spray and heaters and their operation should be modeled in some detail for proper response. 4 refs., 18 figs.

  3. Refurbishment and modification of existing protective shipping packages (for 30-inch UF{sub 6} cylinders) per USDOT specification No. USA-DOT-21PF-1A

    SciTech Connect (OSTI)

    Housholder, W.R. [Nuclear Containers, Incorporated, Elizabethton, TN (United States)

    1991-12-31

    This paper addresses the refurbishment procedures for existing shipping containers for 30-inch diameter UF{sub 6} cylinders in accordance with DOT Specification 21PF-1 and the criteria used to determine rejection when such packages are unsuitable for refurbishment.

  4. TRAC-PF1/MOD1 independent assessment: Semiscale Mod-2A intermediate break test S-IB-3

    SciTech Connect (OSTI)

    Kmetyk, L N

    1986-02-01

    The TRAC-PF1/MOD1 independent assessment project at Sandia National Laboratories is part of an overall effort funded by the NRC to determine the ability of various system codes to predict the detailed thermal/hydraulic response of light water reactors during accident and off-normal conditions. The TRAC code is being assessed at SNLA against test data from various integral and separate effects test facilities. As part of this assessment matrix, an intermediate break test (S-IB-3), performed at the Semiscale Mod-2A facility, has been analyzed. Using an input model with a 3-D VESSEL component, the vessel and downcomer inventories during 3-IB-3 were generally well predicted, but the core heatup was underpredicted compared to data. An equivalent calculation with an all 1-D input model ran about twice as fast as our basecase analysis using a 3-D VESSEL in the input model, but the results of the two calculations diverged significantly for many parameters of interest, with the 3-D VESSEL model results in better agreement with data. 22 refs., 100 figs.

  5. Comparison of TRAC-PF1/MOD1 to a no-failure UPI test in the Cylindrical Core Test Facility

    SciTech Connect (OSTI)

    Cappiello, M.; Spore, J.

    1986-01-01

    TRAC-PF1/MOD1 is compared to a no-failure upper plenum injection reflood test in the Cylindrical Core Test Facility. The results show that TRAC can accurately predict the asymmetric channeling of fluid from upper plenum into the core and that a multidimensional modeling capability is required to do so. The rod temperature behavior is accurately predicted for both the peak cladding temperature and the quench time in the high- and low-power zones. Excessive downflow of liquid at the tie plate is predicted as a result of the interfacial drag model used in TRAC. 10 figs.

  6. An evaluation of TRAC-PF1/MOD1 computer code performance during posttest simulations of Semiscale MOD-2C feedwater line break transients

    SciTech Connect (OSTI)

    Hall, D.G.: Watkins, J.C.

    1987-01-01

    This report documents an evaluation of the TRAC-PF1/MOD1 reactor safety analysis computer code during computer simulations of feedwater line break transients. The experimental data base for the evaluation included the results of three bottom feedwater line break tests performed in the Semiscale Mod-2C test facility. The tests modeled 14.3% (S-FS-7), 50% (S-FS-11), and 100% (S-FS-6B) breaks. The test facility and the TRAC-PF1/MOD1 model used in the calculations are described. Evaluations of the accuracy of the calculations are presented in the form of comparisons of measured and calculated histories of selected parameters associated with the primary and secondary systems. In addition to evaluating the accuracy of the code calculations, the computational performance of the code during the simulations was assessed. A conclusion was reached that the code is capable of making feedwater line break transient calculations efficiently, but there is room for significant improvements in the simulations that were performed. Recommendations are made for follow-on investigations to determine how to improve future feedwater line break calculations and for code improvements to make the code easier to use.

  7. Simulation of LOFT anticipated-transient experiments L6-1, L6-2, and L6-3 using TRAC-PF1/MOD1

    SciTech Connect (OSTI)

    Sahota, M.S.

    1984-01-01

    Anticipated-transient experiments L6-1, L6-2, and L6-3, performed at the Loss-of-fluid Test (LOFT) facility, are analyzed using the latest released version of the Transient Reactor Analysis Code (TRAC-PF1/MOD1). The results are used to assess TRAC-PF1/MOD1 trip and control capabilities, and predictions of thermal-hydraulic phenomena during slow transients. Test L6-1 simulated a loss-of-stream load in a large pressurized-water reactor (PWR), and was initiated by closing the main steam-flow control valve (MSFCV) at its maximum rate, which reduced the heat removal from the secondary-coolant system and increased the primary-coolant system pressure that initiated a reactor scram. Test L6-2 simulated a loss-of-primary coolant flow in a large PWR, and was initiated by tripping the power to the primary-coolant pumps (PCPs) allowing the pumps to coast down. The reduced primary-coolant flow caused a reactor scram. Test L6-3 simulated an excessive-load increase incident in a large PWR, and was initiated by opening the MSFCV at its maximum rate, which increased the heat removal from the secondary-coolant system and decreased the primary-coolant system pressure that initiated a reactor scram. The TRAC calculations accurately predict most test events. The test data and the calculated results for most parameters of interest also agree well.

  8. TRAC-PF1/MOD1 analysis of a 200% cold-leg break in a US/Japanese PWR with four loops and 15 x 15 fuel

    SciTech Connect (OSTI)

    Spore, J.W.; Cappiello, M.W.

    1986-01-01

    This report presents the results of a TRAC-PF1/MOD1 calculation that simulated a 200% double-ended cold-leg-break loss-of-coolant accident in a generic US/Japanese pressurized water reactor. This is a best-estimate analysis using conservative boundary conditions and minimum safeguards. The calculation shows that the peak cladding temperature (PCT) occurs during blowdown and that the core reheat is minimal during reflood. The results also show that for an evaluation-model peak rod linear power of 15.85 kW/ft, a PCT of 1084 K is reached at 3.5 s into the blowdown transient, which is approx.394 K below the design basis limit of 1478 K. 10 figs.

  9. 8/25/08 8:13 AMLung provides breathing room underwater -The Boston Globe Page 1 of 1http://www.boston.com/news/science/articles/2008/08/25/lung_provides_breathing_room_underwater?mode=PF

    E-Print Network [OSTI]

    Flynn, Morris R.

    ://www.boston.com/news/science/articles/2008/08/25/lung_provides_breathing_room_underwater?mode=PF THIS STORY HAS BEEN FORMATTED FOR EASY PRINTING Lung provides breathing room underwater By Michelle Sipics, Globe Correspondent | August 25, 2008 bucket. "I accidentally caught a backswimmer while I was lunging for a water strider," recalled

  10. Structure/function studies of resorcinol-formaldehyde (R-F) and phenol-formaldehyde (P-F) copolymer ion-exchange resins

    SciTech Connect (OSTI)

    Hubler, T.L.; Franz, J.A.; Shaw, W.J.; Hogan, M.O.; Hallen, R.T.; Brown, G.N.; Linehan, J.C.

    1996-09-01

    he U.S. Department of Energy`s (DOE) Hanford Site was established to produce plutonium for the U.S. defense mission. Over the course of decades, hazardous, toxic, and radioactive chemical wastes were generated and disposed of in a variety of ways including storage in underground tanks. An estimated 180 million tons of high-level radioactive wastes are stored in 177 underground storage tanks. During production of fissile plutonium, large quantities of 90Sr and 137CS were produced. The high abundance and intermediate length half- lives of these fission products are the reason that effort is directed toward selective removal of these radionuclides from the bulk waste stream before final tank waste disposal is effected. Economically, it is desirable to remove the highly radioactive fraction of the tank waste for vitrification. Ion-exchange technology is being evaluated for removing cesium from Hanford Site waste tanks. This report summarizes data and analysis performed by Pacific Northwest National Laboratory (PNNL)for both resorcinol-formaldehyde (R-F) and phenol-formaldehyde (P-F) resins and relates their observed differences in performance and chemical stability to their structure. The experimental approach used to characterize the resins was conducted using primarily two types of data: batch distribution coefficients (Kds) and solid-state 13C NMR. Comparison of these data for a particular resin allowed correlation of resin performance to resin structure. Additional characterization techniques included solid-state 19F NMR, and elemental analyses.

  11. TRAC-PF1/MOD1: an advanced best-estimate computer program for pressurized water reactor thermal-hydraulic analysis

    SciTech Connect (OSTI)

    Liles, D.R.; Mahaffy, J.H.

    1986-07-01

    The Los Alamos National Laboratory is developing the Transient Reactor Analysis Code (TRAC) to provide advanced best-estimate predictions of postulated accidents in light-water reactors. The TRAC-PF1/MOD1 program provides this capability for pressurized water reactors and for many thermal-hydraulic test facilities. The code features either a one- or a three-dimensional treatment of the pressure vessel and its associated internals, a two-fluid nonequilibrium hydrodynamics model with a noncondensable gas field and solute tracking, flow-regime-dependent constitutive equation treatment, optional reflood tracking capability for bottom-flood and falling-film quench fronts, and consistent treatment of entire accident sequences including the generation of consistent initial conditions. The stability-enhancing two-step (SETS) numerical algorithm is used in the one-dimensional hydrodynamics and permits this portion of the fluid dynamics to violate the material Courant condition. This technique permits large time steps and, hence, reduced running time for slow transients.

  12. Malta, New York: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource HistoryScenarios TowardsInformation Reducing the GHG Impacts ofMalibu

  13. TRAC-PF1/MOD2 best-estimate analysis of a large-break LOCA in a 15 times 15 generic four-loop Westinghouse nuclear power plant

    SciTech Connect (OSTI)

    Spore, J.W.; Lin, J.C.; Schnurr, N.M.; White, J.R.; Cappiello, M.C.

    1992-01-01

    Calculations of a large-break loss-of-coolant accident (LOCA) in a 15 {times} 15 generic four-loop Westinghouse nuclear power plant with both the TRAC-PF1/MOD1 and TRAC-PF1/MOD2 computer codes will be presented. The Transient Reactor Analysis Code (TRAC) has been developed by Los Alamos National Laboratory to provide advanced best-estimate simulations of real postulated transients in pressurized light-water reactors (LWRs) and for many related thermal-hydraulic facilities. The latest released version of TRAC is TRAC-PF1/MOD2. Significant improvements and enhancements over the MOD1 version were implemented in the MOD2 heat-transfer and constitutive models. One of the most significant improvements in the MOD2 code has been the implementation of the two-step numerics method in the three-dimensional components, which can significantly reduce run times for long, slow transients. A very important area of improvement has been in the reflood heat-transfer models. Developmental assessment results (i.e., code comparisons with experimental data) will be discussed for several separate-effects and integral test, including analysis of the Upper Plenum Test Facility (UPTF), the Cylindrical Core Test Facility (CCTF), and the Loss-of-Fluid Test Facility (LOFT). The assessment results provide information on the anticipated accuracy for the best-estimate models in the MOD2 computer code. The MOD1 to MOD2 comparison will provide an estimate for the effect of improved heat-transfer models on predicted peak cladding temperatures.

  14. TRAC-PF1/MOD2 best-estimate analysis of a large-break LOCA in a 15 {times} 15 generic four-loop Westinghouse nuclear power plant

    SciTech Connect (OSTI)

    Spore, J.W.; Lin, J.C.; Schnurr, N.M.; White, J.R.; Cappiello, M.C.

    1992-03-01

    Calculations of a large-break loss-of-coolant accident (LOCA) in a 15 {times} 15 generic four-loop Westinghouse nuclear power plant with both the TRAC-PF1/MOD1 and TRAC-PF1/MOD2 computer codes will be presented. The Transient Reactor Analysis Code (TRAC) has been developed by Los Alamos National Laboratory to provide advanced best-estimate simulations of real postulated transients in pressurized light-water reactors (LWRs) and for many related thermal-hydraulic facilities. The latest released version of TRAC is TRAC-PF1/MOD2. Significant improvements and enhancements over the MOD1 version were implemented in the MOD2 heat-transfer and constitutive models. One of the most significant improvements in the MOD2 code has been the implementation of the two-step numerics method in the three-dimensional components, which can significantly reduce run times for long, slow transients. A very important area of improvement has been in the reflood heat-transfer models. Developmental assessment results (i.e., code comparisons with experimental data) will be discussed for several separate-effects and integral test, including analysis of the Upper Plenum Test Facility (UPTF), the Cylindrical Core Test Facility (CCTF), and the Loss-of-Fluid Test Facility (LOFT). The assessment results provide information on the anticipated accuracy for the best-estimate models in the MOD2 computer code. The MOD1 to MOD2 comparison will provide an estimate for the effect of improved heat-transfer models on predicted peak cladding temperatures.

  15. Lithium Ethylene Dicarbonate Identified as the Primary Product ofChemical and Electrochemical Reduction of EC in EC:EMC/1.2M LiPF6Electrolyte

    SciTech Connect (OSTI)

    Zhuang, Guorong V.; Xu, Kang; Yang, Hui; Jow, T. Richard; RossJr., Philip N.

    2005-05-11

    Lithium ethylene dicarbonate (CH2OCO2Li)2 was chemically synthesized and its Fourier Transform Infrared (FTIR) spectrum was obtained and compared with that of surface films formed on Ni after cyclic voltammetry (CV) in 1.2M lithium hexafluorophosphate(LiPF6)/ethylene carbonate (EC): ethyl methyl carbonate (EMC) (3:7, w/w) electrolyte and on metallic lithium cleaved in-situ in the same electrolyte. By comparison of IR experimental spectra with that of the synthesized compound, we established that the title compound is the predominant surface species in both instances. Detailed analysis of the IR spectrum utilizing quantum chemical (Hartree-Fock) calculations indicates that intermolecular association through O...Li...O interactions is very important in this compound. It is likely that the title compound in passivation layer has a highly associated structure, but the exact intermolecular conformation could not be established based on analysis of the IR spectrum.

  16. TRAC-PF1/MOD1 calculations and data comparisons for MIST (Multi-Loop Integral System Test) small-break loss-of-coolant accidents with scaled 10 cm/sup 2/ and 50 cm/sup 2/ breaks

    SciTech Connect (OSTI)

    Steiner, J.L.; Siebe, D.A.; Boyack, B.E.

    1987-01-01

    Los Alamos National Laboratory is a participant in the Integral System Test (IST) program initiated in June 1983 for the purpose of providing integral system test data on specific issues/phenomena relevant to post-small-break loss-of-coolant accidents (SBLOCAs), loss of feedwater and other transients in Babcock and Wilcox (B and W) plant designs. The Multi-Loop Integral System Test (MIST) facility is the largest single component in the IST program. MIST is a 2 x 4 (2 hot legs and steam generators, 4 cold legs and reactor-coolant pumps) representation of lowered-loop reactor systems of the B and W design. It is a full-height, full-pressure facility with 1/817 power and volume scaling. Two other experimental facilities are included in the IST program: test loops at the University of Maryland, College Park, and at Stanford Research Institute. The objective of the IST tests is to generate high-quality experimental data to be used for assessing thermal-hydraulic safety computer codes. Efforts are underway at Los Alamos to assess TRAC-PF1/MOD1 against data from each of the IST facilities. Calculations and data comparisons for TRAC-PF1/MOD1 assessment have been completed for two transients run in the MIST facility. These are the MIST nominal test. Test 3109AA, a scaled 10 cm/sup 2/ SBLOCA and Test 320201, a scaled 50 cm/sup 2/ SBLOCA. Only MIST assessment results are presented in this paper.

  17. arXiv:1006.2066v2[hep-ph]16Nov2010 Alberta Thy 04-10, TUM-EFT 8/10, UB-ECM-PF 10/15, ICCUB-10-029 Precision determination of r0MS from the QCD static energy

    E-Print Network [OSTI]

    Weise, Wolfram

    arXiv:1006.2066v2[hep-ph]16Nov2010 Alberta Thy 04-10, TUM-EFT 8/10, UB-ECM-PF 10/15, ICCUB-10, Germany 2 Department of Physics, University of Alberta, Edmonton, Alberta, Canada T6G 2G7 3 Departament d

  18. Empowering Women: The Role of Economic Development, Political Culture and Institutional Design in the World’s Societies

    E-Print Network [OSTI]

    Alexander, Amy C.

    2007-01-01

    Lesotho, Liberia, Lithuania, Macedonia, Malawi, Mali, Malta,Japan, Latvia, Lithuania, Macedonia, Malta, Mexico, Moldova,

  19. Pf/Zeolite Catalyst for Tritium Stripping

    SciTech Connect (OSTI)

    Hsu, R.H.

    2001-03-26

    This report described promising hydrogen (protium and tritium) stripping results obtained with a Pd/zeolite catalyst at ambient temperature. Preliminary results show 90-99+ percent tritium stripping efficiency may be obtained, with even better performance expected as bed configuration and operating conditions are optimized. These results suggest that portable units with single beds of the Pd/zeolite catalyst may be utilized as ''catalytic absorbers'' to clean up both tritium gas and tritiated water. A cart-mounted prototype stripper utilizing this catalyst has been constructed for testing. This portable stripper has potential applications in maintenance-type jobs such as tritium line breaks. This catalyst can also potentially be utilized in an emergency stripper for the Replacement Tritium Facility.

  20. Microsoft Word - S04617_PF.doc

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-SessionsSouth DakotaRobbinsMonumentThird Five-Year ReviewOfficeGroundwaterFinal

  1. Pageflex Server [document: PF1888317_00001]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access| Department ofStephen PSeptember 30,Page of 1 pages 4b. vsp.com or

  2. Pageflex Server [document: PF4577458_00001]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access| Department ofStephen PSeptember 30,Page of 1 pages 4b. vsp.com or

  3. Microsoft Word - PF Training Final 0624051.doc

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nAand DOE SafetyofDepartment. " 21 ran Wilson Blvd.Opinion ofPART

  4. Constitutional Environment and Entrepreneurship: An Empirical Study

    E-Print Network [OSTI]

    Zhang, Wei

    2012-01-01

    Japan Kuwait Latvia Macedonia Malaysia Malta MauritiusItaly Japan Kuwait Latvia Macedonia Malaysia Malta MauritiusItaly Japan Kuwait Latvia Macedonia Malaysia Malta Mauritius

  5. Trade, piracy, and naval warfare in the central Mediterranean: the maritime history and archaeology of Malta 

    E-Print Network [OSTI]

    Atauz, Ayse Devrim

    2004-09-30

    Located approximately in the middle of the central Mediterranean channel, the Maltese Archipelago was touched by the historical events that effected the political, economic and cultural environment of Europe, North Africa, ...

  6. P.F. Peterson Department of Nuclear Engineering

    E-Print Network [OSTI]

    velocity coolant ­ Sustain thermal stresses from neutron/gamma volumetric heating ­ Sustain a range neutron/gamma volumetric heating ­ Sustain a range of neutron fluences/spectra (depends on liquid ­ Challenges: » control of liquid geometry » pumping power Simplifiedchambermaterialsrequirements

  7. Property and Facilities Division VEHICLE PURCHASING & DISPOSAL REQUISITION PF330

    E-Print Network [OSTI]

    Blows, Mark

    Type: 2WD, 4WD No. of Doors: Transmission: Auto, Manual Fuel Type: Unleaded, Diesel, LPG No Driver's Airbag Dual Airbag Headlight Protectors Cargo Blind (Wagon) Leather Trim Metallic Paint Mud Account Project ID Free Form Tag Place operational account i.e. fuel , servicing, registration costs below

  8. PF SECRETARIAT January 2010 BBRRIIEEFF RREEPPOORRTT OONN TTHHEE 77

    E-Print Network [OSTI]

    being one of them has a wealth of natural resources if managed sustainably can support people in OECD led to dramatic increase in demand for nat. Resources Policy Forum on this month's Debate in Tanzania. The presentations debate was done by Dr. Cosmas Sokoni Department of Geography ­University of Dar

  9. Thermal Stability of LiPF 6 Salt and Li-ion Battery Electrolytes Containing LiPF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S.Week DayDr. JeffreyThermal Multi-layer Coating

  10. . 16 (9. ).

    E-Print Network [OSTI]

    , Lesotho, Liberia, Malawi, Malta, Mauritius, Namibia, Nauru, New Zealand, Nigeria, Pakistan, Palau, Papua

  11. -TOEFL ITP -(S-TOPIK, TOEFL, IELTS, TEPS)

    E-Print Network [OSTI]

    , Lesotho, Liberia, Malawi, Malta, Ma uritius, Namibia, Nauru, New Zealand, Nigeria, Pakistan, Palau, Papua

  12. Die neuen Learning Agreements Dr. Sabine Habermalz | 22.05.2014

    E-Print Network [OSTI]

    Pfeifer, Holger

    , Irland, Italien, Kroatien, Lettland, Litauen, Luxemburg, Malta, Niederlande, Österreich, Polen, Portugal

  13. Racial geopolitics : interrogating Caribbean cultural discourse in the era pf globalization

    E-Print Network [OSTI]

    Reyes-Santos, Irmary

    2007-01-01

    good intentions to the Spanish government. He cannot concedepolicies of the Spanish colonial government in the previousunder the Spanish colonial government in Cuba, then Betances

  14. QL/G A Query Language for Geometric Data Edward P.F. Chan & Rupert Zhu

    E-Print Network [OSTI]

    Chan, Edward P.F.

    be expressed with the language. To facilitate the evolution of applications and to tailor to individual need A geometric database management system (DBMS) is a data base system with capabilities for the representation

  15. High-Volume Manufacturing of LiPF6, A Critical Lithium-ion Battery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting arravt014esoleary2012...

  16. High-Volume Manufacturing of LiPF6, A Critical Lithium-ion Battery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation arravt014esoleary2011...

  17. PF coil voltage optimization for start-up scenarios in air core tokamaks

    SciTech Connect (OSTI)

    Albanese, R.; Martone, R.; Ambrosino, G.; Pironti, A.

    1994-09-01

    The basic features of a procedure for the optimization of the plasma scenario in an air core tokamak are presented. The method takes into account the eddy currents in the passive conducting structures. The problem is reduced to the synthesis of time-varying magnetic field. The solution of this inverse electromagnetic problem is carried out by means of an optimization procedure based on the receding horizon approach. The paper includes an example of application to the ITER tokamak.

  18. Quantitative detection of PfHRP2 in saliva of malaria patients in the Philippines

    E-Print Network [OSTI]

    2012-01-01

    Roxas, Palawan, Philippines. 5 Biomedical Engineering IDP,of malaria patients in the Philippines. Malaria Journal 2012of malaria patients in the Philippines Andrew O Fung 1,7* ,

  19. Materials Data on NaPF6 (SG:225) by Materials Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Kristin Persson

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  20. Magnetization measurements of uranium dioxide single crystals (P08358-E002-PF)

    SciTech Connect (OSTI)

    Gofryk, K. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Zapf, V. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States). National High Magnetic Field Lab. (MagLab); Jaime, M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States). National High Magnetic Field Lab. (MagLab)

    2014-12-01

    Our preliminary magnetic susceptibility measurements of UO2 point to complex nature of the magnetic ordering in this material, consistent with the proposed non-collinear 3-k magnetic structure. Further extensive magnetic studies are planned to address the puzzling behavior of UO2 in both antiferromagnetic and paramagnetic states.

  1. High Field Magnetization measurements of uranium dioxide single crystals (P08358- E003-PF)

    SciTech Connect (OSTI)

    Gofryk, K. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Harrison, N. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States). National High Magnetic Field Lab. (MagLab); Jaime, M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States). National High Magnetic Field Lab. (MagLab)

    2014-12-01

    Our preliminary high field magnetic measurements of UO2 are consistent with a complex nature of the magnetic ordering in this material, compatible with the previously proposed non-collinear 3-k magnetic structure. Further extensive magnetic studies on well-oriented (<100 > and <111>) UO2 crystals are planned to address the puzzling behavior of UO2 in both antiferromagnetic and paramagnetic states at high fields.

  2. The mechanism of HF formation in LiPF6-based organic carbonate electrolytes

    E-Print Network [OSTI]

    Lux, Simon

    2014-01-01

    6 at 50°C in a lithium ion battery electrolyte containingcarbonate-based lithium ion battery electrolytes upon

  3. JB RISOE 20-05-2003 Advanced 700C PF Power Plant

    E-Print Network [OSTI]

    prices of imported coal · Security of supply is threatened without coal · Clean Coal Technology in efficiency of Elsam's coal-fired power plants 1950 19701960 19901980 20202000 2010 30 32 34 36 38 40 42 44 46 of Coal Based Power Generation · Abundant reserves · Many independent producers of coal · Low and stable

  4. Structural determination of triclosan derivatives as inhibitors of Plasmodium falciparum enoyl reductase (PfENR) 

    E-Print Network [OSTI]

    Lucumi Moreno, Edinson

    2007-04-25

    -malaria drugs is necessary in modern days. Recent studies have shown that the parasite synthesizes fatty acids using a fatty acid synthase type II (FAS-II) instead of a type-I fatty acid synthase (FAS-I) that is present in other eukaryotes. Plasmodium falciparum...

  5. arXiv:cs.PF/0412027 Correlated dynamics in human printing behavior

    E-Print Network [OSTI]

    Imperial College, London

    et al. [2], who stud- ied network traÆc and found that packet traces show scaling behavior. Observations of scaling behavior raise a number of questions about how to model these sys- tems, optimize

  6. arXiv:cs.PF/0412027v17Dec2004 Correlated dynamics in human printing behavior

    E-Print Network [OSTI]

    Imperial College, London

    al. [2], who stud- ied network traffic and found that packet traces show scaling behavior. Observations of scaling behavior raise a number of questions about how to model these sys- tems, optimize

  7. WTJ(S^rf7?\\ Ris-R-761p* ANNUAL PROGRESS

    E-Print Network [OSTI]

    WTJ(S^rf7?\\ Risø-R-761£p*Thermonuclear Fusion September 1994 #12;ANNUAL PROGRESS _****ig*r REPORT 1993 Work in Controlled Thermonuclear Fusion Research Research Performed in The Fusion Research Unit underthe Contract ofAssociationbetween Euratom and Risø

  8. UNIT= STATES DEPARTMWT PF COMMERCE National Ooaanic and Atmoepherlo Adrnlnl-ion

    E-Print Network [OSTI]

    Valley springrunChinook salmon, Lower ColumbiaRiver Chinook salmon, Upper ColumbiaRiver spring-run Chinook salmon, Puget Sound Chinook salmon, SacramentoRiver winter-nmChinook salmon, Snake #12;River fall-run Chinook salmon, Snake River spring/summer-run Chinook salmon, Upper Willamette River Chinook salmon, Columbia

  9. High-Volume Manufacturing of LiPF6, A Critical Lithium-ion Battery Material

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancingR Walls - Building America Topa High BindingVoltage|

  10. High-Volume Manufacturing of LiPF6, A Critical Lithium-ion Battery Material

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancingR Walls - Building America Topa High BindingVoltage||

  11. Microsoft Word - S09IS004 _LLNL_PF_Authority_08262009a FINAL.doc

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties - WAPAEnergy May2.docTechnicalBARACK ofAcquisitionLegacy U.S.

  12. 03/10/2006 09:02 AMFusion power gets slammed Page 1 of 2http://www.nature.com/news/2006/060306/pf/060306-13_pf.html

    E-Print Network [OSTI]

    worked on the Manhattan Project to build the first nuclear bomb. And it makes bleak reading for scientists involved with the ITER project. ITER, meaning 'the way' in Latin, is an experimental fusion reactor that will be built in southern France (see 'France wins fusion project'). Its proponents hope

  13. Going Beyond 10,000 Years at Yucca Mountain P.F. Peterson, W.E. Kastenberg

    E-Print Network [OSTI]

    comes from the 1999 Final Environmental Impact Statement (FEIS). Figure 1 shows FEIS predictions, brought by the State of Nevada, argued that the U.S. Environmental Protection Agency (EPA) had deviated for the Waste Isolation Pilot Plant repository in New Mexico. The NAS report concluded that there is "no

  14. Identity of Passive Film Formed on Aluminum in Li-ion Battery Electrolytes with LiPF6

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, T.M.

    2008-01-01

    Influence Formation of AlF 3 Passive Film on Aluminum in Li-Identity of Passive Film Formed on Aluminum in Li-ionEngineering Abstract The passive film that forms on aluminum

  15. 4/23/08 2:28 PMhttp://news.nationalgeographic.com/news/pf/19339168.html Page 1 of 2

    E-Print Network [OSTI]

    Provancher, William

    as the world leader in installed capacity to spin the wind into electricity. Globally, wind-power capacity rose, researchers believe wind could account for 20 percent of U.S. electricity by 2030. Global Growth Wind power World in Wind-Power Growth John Roach for National Geographic News April 21, 2008 As Earth Day

  16. Spin-lattice coupling in uranium dioxide probed by magnetostriction measurements at high magnetic fields (P08358-E001-PF)

    SciTech Connect (OSTI)

    Gofryk, K. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Jaime, M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States). National High Magnetic Field Lab. (MagLab)

    2014-12-01

    Our preliminary magnetostriction measurements have already shown a strong interplay of lattice dynamic and magnetism in both antiferromagnetic and paramagnetic states, and give unambiguous evidence of strong spin- phonon coupling in uranium dioxide. Further studies are planned to address the puzzling behavior of UO2 in magnetic and paramagnetic states and details of the spin-phonon coupling.

  17. Martinez, Nebel, Makris: Graph-based PF for Human Tracking with Stylistic Variations 1 2011. The copyright of this document resides with its authors.

    E-Print Network [OSTI]

    Nebel, Jean-Christophe

    with Stylistic Variations Jesús Martínez del Rincón http://cism.kingston.ac.uk/people/researcher/1214 Jean-Christophe Nebel http://cism.kingston.ac.uk/people/academic/423 Dimitrios Makris http://cism

  18. Down-regulation of four putative arabinoxylan feruloyl transferase genes from family PF02458 reduces ester-linked ferulate content in rice cell walls

    E-Print Network [OSTI]

    Piston, Fernando; Uauy, Cristobal; Fu, Lianhai; Langston, James; Labavitch, John; Dubcovsky, Jorge

    2010-01-01

    materials for ef?cient bioethanol production. In: Olsson L,BE (2004) Global potential bioethanol production from wasted

  19. Thermodynamic stability of complexes of BF{sub 3}, PF{sub 5} and AsF{sub 5} with chlorine fluorides, oxyfluorides, and related compounds

    SciTech Connect (OSTI)

    Trowbridge, L.D.

    1996-07-01

    The recent discovery of solid, water sensitive, arsenic-containing deposits in auxiliary process piping in the PGDP led to a search for explanations that could account for such accumulated material. A plausible explanation for the deposits is the formation of complexes of AsF{sub 5} with one or more gases that may have been present as a result of cascade equipment cleanup activities. A literature search was performed. The target of the search was literature that would provide information on the dissociation pressure of complexes of AsF{sub 5} or its hydrolysis products with any gases that may be (at least intermittently) present in the cascade location where the deposits were found. While the precise information sought (namely reliable, accurate dissociation pressures of such complexes at cascade temperatures) was not found in the detail desired. other information on these or similar complexes was obtained which permits prediction of the conditions under which the complexes might form, dissociate, or migrate, and how they might behave in the presence of atmospheric moisture. Information was gathered on potential AsF{sub 5} complexes with ClF, ClF{sub 3}, ClF{sub 5}, ClF{sub 3}O, ClO{sub 2}F, and ClO{sub 3}F. Information was also collected on many other related complexes as it was encountered, particularly for series of complexes which could assist in predicting chemical trends. Thermodynamic analysis and property estimation methods have been used to generate provisional estimates of the dissociation pressures of the two complexes ClF{sub 3}*AsF{sub 5} and ClO{sub 2}F*AsF{sub 5}. In addition, several hydrolysis species have been identified, and stability properties of the most relevant such complex (H{sub 3}O*AsF{sub 6}) have similarly been estimated. While the predicted dissociation pressures are somewhat uncertain. they do lead to a tentative picture of the formation and behavior of such complexes in a cascade cleanup environment.

  20. TRAC-PF1 post-test predictions for the Semiscale Natural-Circulation Tests S-NC-2 and S-NC-6. [PWR

    SciTech Connect (OSTI)

    Booker, C.P.

    1983-01-01

    The TRAC prediction are compared to the data for the Semiscale natural-circular Tests S-NC-2B and S-NC-6. S-NC-2B is a baseline test covering single- and two-phase natural circulation as well as reflux; here TRAC compares quite well with the experiment results for mass flow. For Test S-NC-6, which is a reflux test with various amounts of nitrogen injected into the system, the TRAC prediction of the reflux rate is close to the experiment value with no nitrogen in the system. Ultimately, the maximum reflux rate predicted by TRAC is about 20% higher than the data.

  1. Commissioning of a Soft X-ray Beamline PF-BL-16A with a Variable-Included-Angle Varied-Line-Spacing Grating Monochromator

    SciTech Connect (OSTI)

    Amemiya, Kenta; Toyoshima, Akio; Kikuchi, Takashi; Kosuge, Takashi; Nigorikawa, Kazuyuki; Sumii, Ryohei; Ito, Kenji

    2010-06-23

    The design and commissioning of a new soft X-ray beamline, BL-16A, at the Photon Factory is presented. The beamline consists of a pre-focusing mirror, an entrance slit, a variable-included-angle varied-line-spacing plane grating monochromator, and a post-focusing system as usual, and provides circularly and linearly polarized soft X rays in the energy range 200-1500 eV with an APPLE-II type undulator. The commissioning procedure for the beamline optics is described in detail, especially the check of the focal position for the zero-th order and diffracted X rays.

  2. Analysis of a 4-inch small-break loss-of-coolant accident in a Westinghouse Pressurized Water Reactor using TRAC-PF1/MOD1 

    E-Print Network [OSTI]

    Knippel, Kimberley I.R.

    1988-01-01

    4-inch SBLOCAs 65 XI. Comparison of RESAR-3S, TRAC and RELAP SBLOCAs . . 70 LIST OF ACRONYMS Acronym Name CCFL CVCS ECCS EPRI FSAR HPI INEL LB LOCA LOCA LPI MSIV NRC PCT PORV PWR RCP RCS RESAR RHR SI SBLOCA Argonne National... and RELAP57 a) it was decided to model the 4- loop RCS with a 2-loop input model. The three coolant loops that did not have the pressurizer or the pipe break were lumped together to form one equivalent intact loop. The coolant loop that contained...

  3. A Plan for Nuclear Waste http://www.washingtonpost.com/wp-dyn/content/article/2006/01/29/AR2006012900719_pf.html

    E-Print Network [OSTI]

    Deutch, John

    proliferation risks. Iran, which is suspected of using nuclear power development to disguise a weapons program in civilian nuclear power programs across the globe. This decision committed the United States to direct of radioactive waste and heighten rather than reduce public concerns about expanded nuclear power. We agree

  4. Down-regulation of four putative arabinoxylan feruloyl transferase genes from family PF02458 reduces ester-linked ferulate content in rice cell walls

    E-Print Network [OSTI]

    Piston, Fernando; Uauy, Cristobal; Fu, Lianhai; Langston, James; Labavitch, John; Dubcovsky, Jorge

    2010-01-01

    materials for ef?cient bioethanol production. In: Olsson L,Global potential bioethanol production from wasted crops and

  5. Analysis of small-break LOCA transients combined with complete loss-of-feedwater accidents for the South Texas Project plant using TRAC-PF1/MOD1 

    E-Print Network [OSTI]

    Guyot, Carole Chantal

    1987-01-01

    with two-step numerics in the one-dimensional components. The two-fluid model, in conjunction with a stratified flow regime handles countercurrent flow better than the drift-flux model previously used. The two-step numerics allow large time... the combined transients. 33. Void fraction of the fluid flowing through the break during the one-inch small-break LOCA combined with LOFW 69 71 34. Void fraction in the vessel upper head during the one-inch small-break IDCA combined with IDFW. . . . 72...

  6. * M.P. Brady, P.F. Tortorelli, K.L. More, E.A. Payzant, B.L. Armstrong, H.-T. Lin, M.J. Lance

    E-Print Network [OSTI]

    Pennycook, Steve

    to electrochemical devices such as fuel cells to catalysts. Phenomen- ological examples are presented for coatings is that the substrate alloy can be optimized for properties other than corrosion resistance (i.e. ductility, formability

  7. Cellular Tracking in Time-lapse Phase Contrast Images K. Thirusittampalam, M.J. Hossain, O. Ghita, and P.F. Whelan

    E-Print Network [OSTI]

    Whelan, Paul F.

    Cellular Tracking in Time-lapse Phase Contrast Images K. Thirusittampalam, M.J. Hossain, O. Ghita {kethesan, julius, ghitao, whelanp}@eeng.dcu.ie Abstract The quantitative analysis of live cellular structures in time-lapse image sequences is a key issue in evaluating biological processes such as cellular

  8. 13-040505-CLN-01 TO: DISTRIBUTION

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    to a useful level. Specifically, the studs on the PF4 coil support clamps, and the bolts on the PF5 turnbuckle of the ability of the support structure to withstand same. Since PF4 and PF5 are situated very close to one to the hardware associated with the support structure will be necessary in order that PF4 can be energized

  9. LANL team wins best paper award at Sustainable Development Conference

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The event drew more that 1,000 participants and speakers, including the presidents of Liberia, Malta and Rwanda; the First Lady of Panama; and U.N. Sustainable Development...

  10. Sustainable Development Conference

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The event drew more that 1,000 participants and speakers, including the presidents of Liberia, Malta and Rwanda; the First Lady of Panama; and U.N. Sustainable Development...

  11. CX-011208: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Danger Tree Management on Malta-Mount Elbert 230-Kilovolt Transmission Line CX(s) Applied: B1.3 Date: 09/09/2013 Location(s): Colorado Offices(s): Western Area Power Administration-Rocky Mountain Region

  12. Supporting Information Tandem Catalytic Conversion of Glucose to 5-Hydroxymethylfurfural with

    E-Print Network [OSTI]

    Zhao, Huimin

    conducted in Kinesis microwave vials (Malta, NY). One unit (U) represents the conversion of 1.0 µmole1 Supporting Information Tandem Catalytic Conversion of Glucose to 5-Hydroxymethylfurfural

  13. EuroGOV: Engineering a Multilingual Web Borkur Sigurbjornsson1

    E-Print Network [OSTI]

    de Rijke, Maarten

    retrieval task. EuroGOV is a collection of web pages crawled from the European Union portal, European Union Russia .mt Malta .se Sweden .pl Poland .uk United Kingdom .si Slovenia .sk Slovakia January 2005 [5

  14. EuroGOV: Engineering a Multilingual Web Corpus

    E-Print Network [OSTI]

    Kamps, Jaap

    of web pages crawled from the European Union portal, European Union member state governmental web sites The Netherlands .lu Luxemburg .pt Portugal .lv Latvia .ru Russia .mt Malta .se Sweden .pl Poland .uk United

  15. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    to Maldives of Crude Oil and Petroleum Products (Thousand Barrels)","U.S. Exports to Mali of Crude Oil and Petroleum Products (Thousand Barrels)","U.S. Exports to Malta of Crude...

  16. INL Researchers Advance Detection of Brucellosis

    ScienceCinema (OSTI)

    Roberto, Frank; Newby, Deborah

    2010-01-08

    What do cattle ranchers in the greater Yellowstone region have in common with British soldiers garrisoned on the island of Malta in the late 1800s? Hint: it's a pathogen that starts with the letter B. It's Brucella Abortus.

  17. Problem Set 3 MAS 622J/1.126J: Pattern Recognition and Analysis

    E-Print Network [OSTI]

    samples from class 1 x1 = dd(:,1); % test samples from class 2 x2 = dd(:,2); Pd_save = []; Pf_save(x > x_c | x in w=1) Pf = nFP / num_samples; Pd_save = [Pd_save; Pd]; Pf_save = [Pf_save; Pf]; end mean1 - mean2)/sig % d' figure hold on plot(Pf_save, Pd_save, 'r') 2 #12;sprintf('dataset2:') dd = load

  18. Hurricane Emergency Startup Actions June 24, 2014 Check on conditions in Animal Care and check/fill dewars (if required) (SOM) 1

    E-Print Network [OSTI]

    &F) 14 4 CSRB - Animal Care starts operations (full operations appx six hours after MEB boiler started Boiler (P&F) 26 LEC - Unlock all exits and gates (P&F) 27 LEC - Remove Door Dams (P&F) 28 6 LEC - Start RESIDENCE HALL - Start domestic hot water boiler (P&F) 43 STANISLAUS HALL - Unlock all exits and gates (P

  19. DPF heater attachment mechanisms

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-04-26

    An exhaust filter system includes a particulate filter (PF) that is disposed downstream from an engine. The PF filters particulates within an exhaust from the engine. A heating element heats particulate matter in the PF. A fastener limits expansion movement of the heating element relative to the PF.

  20. 05/24/2006 11:52 AMNations Agree to Build Fusion Reactor Page 1 of 2http://www.washingtonpost.com/wp-dyn/content/article/2006/05/24/AR2006052401048_pf.html

    E-Print Network [OSTI]

    percent to 20 percent of the world's energy could come from fusion by the end of the century fusion project they hope will lead to a cheaper, safer, cleaner and endless source of energy. The seven-party consortium, which also includes India and South Korea, agreed last year to build the International

  1. Transgenic Papaya Genome Sequenced http://www.genomeweb.com/issues/news/146481-1.html?type=pf 1 of 2 4/27/2008 7:12 PM

    E-Print Network [OSTI]

    Alam, Maqsudul

    in the mid-1990s and fruit from these plants is currently marketed in the mainland US and Canada of the woody polymer lignin. Because SunUp is a transgenic papaya variety, the authors noted, sequencing its

  2. Keywords. Protein interaction; putative integral membrane protein; ribosomal phosphoprotein P0; surface expression; yeast two-Abbreviations used: GST, glutathione-S transferase; IP, immunoprecipitation; ORF, open reading frame; PfP0, Plasmodium falci-

    E-Print Network [OSTI]

    Sharma, Shobhona

    , Homi Bhabha Road, Mumbai 400 005, India Corresponding author (Fax, 91-22-2280-4610; Email, sharma. One of the strongest interactors (clone 67B) mapped to the gene YFL034W which codes for a hypothetical interacted with clone 67B, was mapped to 60­148 amino acids. It is envisaged that the surface localization

  3. Perfusion-based High-Resolution Functional Imaging in the Human Brain at 7 Tesla J. Pfeuffer, G. Adriany, A. Shmuel, E. Yacoub, P.-F. van de Moortele, X. Hu, K. Ugurbil

    E-Print Network [OSTI]

    Perfusion-based High-Resolution Functional Imaging in the Human Brain at 7 Tesla J. Pfeuffer, G was made possible by signal-to-noise gains at the high magnetic field of 7 Tesla and by using a novel RF

  4. Estimation of the Dynamic States of Synchronous Machines Using an Extended Particle Filter

    SciTech Connect (OSTI)

    Zhou, Ning; Meng, Da; Lu, Shuai

    2013-11-11

    In this paper, an extended particle filter (PF) is proposed to estimate the dynamic states of a synchronous machine using phasor measurement unit (PMU) data. A PF propagates the mean and covariance of states via Monte Carlo simulation, is easy to implement, and can be directly applied to a non-linear system with non-Gaussian noise. The extended PF modifies a basic PF to improve robustness. Using Monte Carlo simulations with practical noise and model uncertainty considerations, the extended PF’s performance is evaluated and compared with the basic PF and an extended Kalman filter (EKF). The extended PF results showed high accuracy and robustness against measurement and model noise.

  5. The Role of Platelet Factor 4 in Radiation-Induced Thrombocytopenia

    SciTech Connect (OSTI)

    Lambert, Michele P.; Xiao Liqing; Nguyen, Yvonne; Kowalska, M. Anna; Poncz, Mortimer

    2011-08-01

    Purpose: Factors affecting the severity of radiation-induced thrombocytopenia (RIT) are not well described. We address whether platelet factor 4 (PF4; a negative paracrine for megakaryopoiesis) affects platelet recovery postradiation. Methods and Materials: Using conditioned media from irradiated bone marrow (BM) cells from transgenic mice overexpressing human (h) PF4 (hPF4+), megakaryocyte colony formation was assessed in the presence of this conditioned media and PF4 blocking agents. In a model of radiation-induced thrombocytopenia, irradiated mice with varying PF4 expression levels were treated with anti-hPF4 and/or thrombopoietin (TPO), and platelet count recovery and survival were examined. Results: Conditioned media from irradiated BM from hPF4+ mice inhibited megakaryocyte colony formation, suggesting that PF4 is a negative paracrine released in RIT. Blocking with an anti-hPF4 antibody restored colony formation of BM grown in the presence of hPF4+ irradiated media, as did antibodies that block the megakaryocyte receptor for PF4, low-density lipoprotein receptor-related protein 1 (LRP1). Irradiated PF4 knockout mice had higher nadir platelet counts than irradiated hPF4+/knockout litter mates (651 vs. 328 x 106/mcL, p = 0.02) and recovered earlier (15 days vs. 22 days, respectively, p <0.02). When irradiated hPF4+ mice were treated with anti-hPF4 antibody and/or TPO, they showed less severe thrombocytopenia than untreated mice, with improved survival and time to platelet recovery, but no additive effect was seen. Conclusions: Our studies show that in RIT, damaged megakaryocytes release PF4 locally, inhibiting platelet recovery. Blocking PF4 enhances recovery while released PF4 from megakaryocytes limits TPO efficacy, potentially because of increased release of PF4 stimulated by TPO. The clinical value of blocking this negative paracrine pathway post-RIT remains to be determined.

  6. Electrically heated particulate filter using catalyst striping

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J; Ament, Frank

    2013-07-16

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating is applied to the PF that increases a temperature of the combustion of the particulates within the PF.

  7. Reducing Power Factor Cost

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Before PF 100142 0.70 or 70% After PF 100105 0.95 or 95% PB References: B.C. Hydro. Power Factor. The GEM Series. October 1989. Commonwealth Sprague Capacitor, Inc....

  8. NMR-Based Computational Studies of Membrane Proteins in Explicit Membranes

    E-Print Network [OSTI]

    Cheng, Xi

    2015-05-31

    , Pf1 coat protein was preassembled in a protein/micelle model and simulated in explicit environment. Compared to previous simulations of Pf1 coat protein in bilayers, different protein conformations were observed in these simulations due...

  9. Advanced Functional Materials for Energy Related Applications

    E-Print Network [OSTI]

    Sasan, Koroush

    2015-01-01

    b) Model structure of zirconium-porphyrin MOF (ZrPF). Color2 ) 8 (H 2 O) 8 . (c) zirconium-prophyrin MOF (ZrPF). Color6 ] into the highly robust zirconium-porphyrin based metal-

  10. SolenoidSolenoid--free Startfree Start--up and Rampup and Ramp--upup Progress and Plans for 2009Progress and Plans for 2009--1313

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    in solenoid-free plasma startup research · NSTX has so far explored CHI and Outer PF startup for plasma

  11. Diesel particulate filter regeneration via resistive surface heating

    DOE Patents [OSTI]

    Gonze, Eugene V; Ament, Frank

    2013-10-08

    An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine; and a grid of electrically resistive material that is applied to an exterior upstream surface of the PF and that selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF.

  12. NSTX Upgrade FDR Calculation Executive Summaries

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    in format, but it should give an indication of the scope of the analysis work performed to support the NSTX-CALC-12-04-00 PF2 / PF3 Bolting, Bracket, and weld Stress P. Titus 1.1.2 NSTXU-CALC-12-05-00 PF4 and PF5 Support Analysis P. Titus 1.1.2 NSTXU-CALC-12-06-00 Aluminum Block (To Be Revised by Pete T.) P. Titus 1

  13. NSTX Upgrade FDR Calculation Executive Summaries

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    performed to support the NSTX Upgrade design effort. Some, but not most, have been reviewed and signed.1.2 NSTXU-CALC-12-04-00 PF2 / PF3 Bolting, Bracket, and weld Stress P. Titus I.Zatz 1.1.2 NSTXU-CALC-12-05-00 PF4 and PF5 Support Analysis P. Titus I.Zatz 1.1.2 NSTXU-CALC-12-06-00 Aluminum Block (To Be Revised

  14. Zone heated diesel particulate filter electrical connection

    DOE Patents [OSTI]

    Gonze, Eugene V. (Pinckney, MI); Paratore, Jr., Michael J. (Howell, MI)

    2010-03-30

    An electrical connection system for a particulate filter is provided. The system includes: a particulate filter (PF) disposed within an outer shell wherein the PF is segmented into a plurality of heating zones; an outer mat disposed between the particulate filter and the outer shell; an electrical connector coupled to the outer shell of the PF; and a plurality of printed circuit connections that extend along the outer surface of the PF from the electrical connector to the plurality of heating zones.

  15. A selective sweep on a deleterious mutation in the CPT1A gene in Arctic populations

    E-Print Network [OSTI]

    Clemente, Florian J.; Cardona, Alexia; Inchley, Charlotte E.; Peter, Benjamin M.; Jacobs, Guy; Pagani, Luca; Lawson, Daniel J.; Antão, Tiago; Vicente, Mário; Mitt, Mario; DeGiorgio, Michael; Faltyskova, Zuzana; Xue, Yali; Ayub, Qasim; Szpak, Michal; Mägi, Reedik; Eriksson, Anders; Manica, Andrea; Raghavan, Maanasa; Rasmussen, Morten; Rasmussen, Simon; Willerslev, Eske; Vidal?Puig, Antonio; Tyler?Smith, Chris; Villems, Richard; Nielsen, Rasmus; Metspalu, Mait; Malyarchuk, Boris; Derenko, Miroslava; Kivisild, Toomas

    2014-10-23

    Project 7,8; NUN – Nunavut Inuit 3; M’TA –Mal’ta 16; ANZ – Clovis 17; ALE – Aleutian Islander, DOR – Early- Middle- and Late Dorset (Table S10) 19; SQQ – Saqqaq 18; and GIN – Greenland Inuit 2. (B) The Haplotype Median Joining Network was constructed...

  16. 140 Computer T H E P R O F E S S I O N

    E-Print Network [OSTI]

    Santini, Simone

    140 Computer T H E P R O F E S S I O N L ike death and taxes, standards are apparently-hand side of the road--or left-hand side if you drive in England, Malta, Japan, or a handful of other

  17. PostQuantum Signatures Johannes Buchmann Carlos Coronado Martin D oring

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Abstract Digital signatures have become a key technology for making the Internet and other signatures have become a key technology for making the Internet and other IT infrastructures secure. Digital, Italy, Japan, Luxembourg, Malaysia, Malta, Mexico, Netherlands, New Zealand, Nicaragua, Norway, Panama

  18. Post-Quantum Signatures Johannes Buchmann Carlos Coronado Martin Doring

    E-Print Network [OSTI]

    International Association for Cryptologic Research (IACR)

    Abstract Digital signatures have become a key technology for making the Internet and other signatures have become a key technology for making the Internet and other IT infrastructures secure. Digital, Malaysia, Malta, Mexico, Netherlands, New Zealand, Nicaragua, Norway, Panama, Peru, Philippines, Poland

  19. SPRING 2010 International Edition

    E-Print Network [OSTI]

    Mateo, Jill M.

    E-mail: hermans@acadbookprom.nl Germany, Austria, Switzerland, and Italy Uwe Lüdemann Schleiermacherstrasse 8 D 10961Berlin Germany Tel: 030 69 50 81 89 Fax: 030 69 50 81 90 E-mail: mail Algeria, Cyprus, Jordan, Malta, Morocco, Tunisia, Turkey, and West Bank Claire de Gruchy Avicenna

  20. Assessing Design Patterns for Concurrency Fikre Leguesse Adrian Francalanza

    E-Print Network [OSTI]

    Francalanza, Adrian

    -oriented machinery in mind such as classes and inheritance. We test the paradigm independence of these designAssessing Design Patterns for Concurrency Fikre Leguesse Adrian Francalanza Department of Computer Science, ICT University of Malta {fleg0001,afra1}@um.edu.mt Abstract Design patterns are language

  1. Comparison of 3D phase field and Peierls-Nabarro modeling of dislocation

    E-Print Network [OSTI]

    Chen, Long-Qing

    ), phase field (PF) · PF & PN formulations · energy densities · stacking fault energy (SFE) · interface energy scaling · results · comparison of dissociation in PF & PN · dislocation loops under loading-Nabarro (Frenkel; red) · phase field (double well; green) · Volterra (blue) order parameter density stress across

  2. PAO Form 5/2001 1 REQUEST FOR DAVIS-BACON DETERMINATION

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    flags, hubs, and flexible connectors - Ohmic Heating (OH) coil - Poloidal Field (PF) coils PF1A Upper (IBD) - Pedestal which supports Center Stack Assembly from floor b. Various components which interface, and PF1BL leads - Cables and connectors associated with CSA sensors - Supply piping for heating

  3. Electrically heated particulate filter regeneration using hydrocarbon adsorbents

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI

    2011-02-01

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material selectively heats exhaust passing through the upstream end to initiate combustion of particulates within the PF. A hydrocarbon adsorbent coating applied to the PF releases hydrocarbons into the exhaust to increase a temperature of the combustion of the particulates within the PF.

  4. Reasoning Exercises in Assisted Living: a cluster randomized trial to improve reasoning and everyday problem solving

    E-Print Network [OSTI]

    Williams, Kristine; Herman, Ruth; Bontempo, Daniel

    2014-06-25

    in Assisted living activity Ultraviolet index number Exposure level Time to burn, minutes Actions to take 0, 1, 2 Minimal 60 Apply sPF 15 sunscreen 3, 4 low 45 Apply sPF 15 sunscreen; wear a hat 5, 6 Moderate 30 Apply sPF 15 sunscreen; wear a hat 7, 8, 9... high 15–25 Apply sPF 15–30 sunscreen; wear a hat and sunglasses 10 or higher Very high 10 Apply sPF 30 sunscreen; wear a hat, sunglasses, and protective clothing The Us national Weather service issues daily forecasts of ultraviolet levels...

  5. Electrically heated particulate filter enhanced ignition strategy

    DOE Patents [OSTI]

    Gonze, Eugene V; Paratore, Jr., Michael J

    2012-10-23

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine. A grid of electrically resistive material is applied to an exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF. A catalyst coating applied to at least one of the PF and the grid. A control module estimates a temperature of the grid and controls the engine to produce a desired exhaust product to increase the temperature of the grid.

  6. Reports & News Briefs

    E-Print Network [OSTI]

    1969-10-01

    of Demetrio Aguilera Malta's "Dientes Blancos." HOLZAPFEL, TÁMARA (University of New Mexico) Article: Griselda Gámbaro's Theatre of the Absurd. JASSO, ARTURO F. (Western Carolina University) Article: Orígenes de la crítica teatral mexicana. JOHNSON, DAVID... for the Humani ties, Fall, 1969. YALE UNIVERSITY Visiting Lecturer Alberto Castilla (Spain), Department of Romance Lan guages, 1969-70. U.S. STATE DEPARTMENT José Joaquin Ramírez Barrero (Colombia), Director of La Mama and Theatre Professor at Universidad...

  7. Shielded regeneration heating element for a particulate filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2011-01-04

    An exhaust system includes a particulate filter (PF) that is disposed downstream from an engine. The PF filters particulates within an exhaust from the engine. A heating element heats particulate matter in the PF. A catalyst substrate or a flow converter is disposed upstream from said heating element. The catalyst substrate oxidizes the exhaust prior to reception by the heating element. The flow converter converts turbulent exhaust flow to laminar exhaust flow prior to reception by the heating element.

  8. cPIES sites Q: Downstream of SFZ

    E-Print Network [OSTI]

    Rhode Island, University of

    from PF core [km] North (downstream) South (upstream) 5958.55857.557 0 50 100 150 Latitude of max() N cPIES sites Q: Downstream of SFZ Neutraldensity[kg/m 3 ] Distance from PF core [km] -100-50050100 27.2 27.4 27.6 27.8 28 28.2 Q: Upstream of SFZ Distance from PF core [km] -100

  9. A pathogenetic study of the thrombocytopenia caused by Ehrlichia canis in beagles 

    E-Print Network [OSTI]

    Marrs, Glen Edward

    1974-01-01

    techniques: (a) the total thrombocyte concentration, (b) the mega thrombocyte concentration, (c) the platelet factor 3 tes t. and (d) determination of 31Cr-labelled thrombocyte survival. All infected dogs developed clinical signs of canine ehrlich- iasis... of the platelet factor 3 (PF-3) tests revealed that the release of PF ? 3 from normal canine thrombocytes was inhibited after incubation in globulin fractions from the infected dogs. The inhibition of PF ? 3 was at- tributed to the development of a mechanical...

  10. Physical activity, physical fitness and leukocyte telomere length.

    E-Print Network [OSTI]

    Soares-Miranda, Luisa; Imamura, Fumiaki; Siscovick, David; Jenny, Nancy Swords; Fitzpatrick, Annette L.; Mozaffarian, Dariush

    2015-01-01

    types, frequency, and duration of each 107 activity were used to calculate weekly energy expenditure (kcal/week) from leisure-108 time activity. Usual exercise intensity was also assessed, with responses including no 109 exercise or low, medium... ) and also better represent long-term effects of 175 habitual PA and PF, we took advantage of repeated measures of PA to PF to perform 176 cumulative updating (averaging of serial values) (Supplementary Figure 1, SDC, 177 Timeline). When PA or PF were...

  11. October 2014 Natural Phenomena Hazards (NPH) Meeting - Wednesday...

    Office of Environmental Management (EM)

    Flooding Hazard Assessment Los Alamos National Laboratory Plutonium Facility (PF-4) Seismic Safety Implementation of DOE NPH Requirements at the Thomas Jefferson National...

  12. Analysis Procedures to Estimate Seismic Demands of Structures...

    Office of Environmental Management (EM)

    Laboratory Plutonium Facility (PF-4) Seismic Safety May 2015 Seismic Lessons-Learned Panel Meeting Agenda Risk-Informed Design of Seismic Isolation Systems for Nuclear Facilities...

  13. Problems and Solutions: Training Disaster Organizations of the...

    Energy Savers [EERE]

    Soft Costs Author Florida Solar Energy Center j-fsec-pf-371-03.pdf More Documents & Publications Florida's Emergency Shelters Go Solar Disasters: Photovoltaics for Special Needs...

  14. Permafrost and organic layer interactions over a climate gradient...

    Office of Scientific and Technical Information (OSTI)

    in permafrost occurrence (PF) and organic layer thickness (OLT) in more than 3000 soil pedons across a mean annual temperature (MAT) gradient. Cause and effect relationships...

  15. EUROPEAN ORGANISATION FOR PARTICLE PHYSICS CERNPPE/93183

    E-Print Network [OSTI]

    , M. Hansroul 8 , C.K. Hargrove 7 , P.F. Harrison 13 , J. Hart 8 , P.A. Hart 9 , P.M. Hattersley 1 , M

  16. EUROPEAN ORGANISATION FOR PARTICLE PHYSICS CERNPPE/9442

    E-Print Network [OSTI]

    , P.F. Harrison 13 , J. Hart 8 , P.A. Hart 9 , P.M. Hattersley 1 , M. Hauschild 8 , C.M.Hawkes 8 , E

  17. EUROPEAN ORGANISATION FOR PARTICLE PHYSICS CERNPPE/9449

    E-Print Network [OSTI]

    , M. Hansroul 8 , C.K. Hargrove 7 , P.F. Harrison 13 , J. Hart 8 , P.A. Hart 9 , P.M. Hattersley 1 , M

  18. DOI: 10.1126/science.1172867 , 1682 (2009);325Science

    E-Print Network [OSTI]

    Morgan, David

    2009-01-01

    to that of quinine and verapamil. Measurements of [3 H]YPWF-NH2 uptake in oocytes express- ing different Pf

  19. Attachment 1: Overview of the Proposed Avista Deemer Settlement

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    generally as a "deemer account." Interest accrued on the outstanding deemer account balance. If the ASC of a utility with a deemer balance subsequently exceeded the PF Exchange...

  20. Electrically heated particulate filter embedded heater design

    DOE Patents [OSTI]

    Gonze, Eugene V.; Chapman, Mark R.

    2014-07-01

    An exhaust system that processes exhaust generated by an engine is provided. The system generally includes a particulate filter (PF) that filters particulates from the exhaust wherein an upstream end of the PF receives exhaust from the engine and wherein an upstream surface of the particulate filter includes machined grooves. A grid of electrically resistive material is inserted into the machined grooves of the exterior upstream surface of the PF and selectively heats exhaust passing through the grid to initiate combustion of particulates within the PF.

  1. 11-980223-CLN-01 TO: DISTRIBUTION

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    NSTX 11-980223-CLN-01 TO: DISTRIBUTION FROM: C NEUMEYER SUBJECT: FORCES ON INTERNAL HARDWARE upper and lower coils (three wire feed). 5) PF1b either [0] or [+], corresponding CHI X-point formation for radial position control with Ip [+]. Although PF3 is actually bipolar, this mode will be used only

  2. THE SMALL SIGNAL AMPLIFICATION OF THE GATED DIODE OPERATED IN BREAKDOWN REGIME

    E-Print Network [OSTI]

    capacitance of approximately 4pF. Figure 1 - Cross section of the gated diode. The device was fabricated impedance given by the pn junction avalanche regime. The cross section of the utilized device is presented and the area of the gate gives a capacitance of approximately 4pF. 2. DC Measurements In order to set the bias

  3. CaMn1-x NbxO3 (x e 0.08) Perovskite-Type Phases As Promising New High-Temperature n-Type Thermoelectric Materials

    E-Print Network [OSTI]

    for the SC-derived phases ( power factors combined the direct conversion of heat into electric power.1 This energy conversion has the advan- tage of being in a high power factor, PF (e.g., for x ) 0.05, S1000K ) -180 µV K -1 , F1000K ) 16.8 m cm, and PF > 1

  4. Calculations of pH-Dependent Binding of Proteins to Biological Membranes Maja Mihajlovic and Themis Lazaridis*

    E-Print Network [OSTI]

    Lazaridis, Themis

    Lazaridis* Department of Chemistry, City College of the City UniVersity of New York, New York, New York energies. The standard free energy of binding, G, is defined as -RT ln(Pb/Pf), where Pb and Pf free energy are (a) the free energy cost of ionization state changes (Gion), (b) the effective energy

  5. 13-970204-CLN-01 TO: DISTRIBUTION

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    NSTX 13-970204-CLN-01 TO: DISTRIBUTION FROM: C NEUMEYER SUBJECT: PRELIMINARY FMEA OF CENTER STACK Analysis (FMEA) which considers failures within the center stack as well as failures in other elements, the OH coil, the PF1a coil, the PF1b coil, and the Center Stack Casing. A FMEA matrix is presented

  6. The use of personality profiles in personnel selection: an exploration of issues encountered in practical applications 

    E-Print Network [OSTI]

    Shelton, Matthew Larrence

    2004-11-15

    Factors (APO)? 55 5 Descriptive Analysis: Five Broad Factors (APO) 57 6 Logistic Regression Analysis of Success as a Function of the Five Broad Factors From the 16PF (Press Operator)????????????????????????? 58 7... Descriptive Analysis: 16 Narrow Factors (Company-Wide)???????????????????????????????? 60 8 Logistic Regression Analysis of Success as a Function of the Sixteen Narrow Factors from the 16PF (Company-Wide)??????????????????????? 62...

  7. 1 Plasmodium falciparum SSB Tetramer Wraps 2 Single-Stranded DNA with Similar Topology but

    E-Print Network [OSTI]

    Lohman, Timothy M.

    1 Plasmodium falciparum SSB Tetramer Wraps 2 Single-Stranded DNA with Similar Topology but 3 methods, we show that Pf-SSB forms a stable homo-tetramer 32 alone and when bound to single-stranded DNA (ssDNA). We also present a 33 crystal structure at 2.1 Å resolution of the Pf-SSB tetramer bound

  8. April 7, 1998 Studies of Coolant Compatibility with Beryllium

    E-Print Network [OSTI]

    Cinabro, David

    CBX 98­8 April 7, 1998 D.Cinabro S.McGee Studies of Coolant Compatibility with Beryllium Abstract A study of the petroleum­based coolant, PF200, has found it to be chemically compat­ ible with beryllium. These features make PF200 a suitable substitute for water in the coolant system of CLEO's beryllium beam pipe. 1

  9. NSTX Weekly Report (June 18, 2010) FY 2010 NSTX plasma operations

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    as well as dual probe lithium evaporation. Commissioning of new coil protection circuitry and the integrated system testing required for combined PF4 and PF5 coil operation were successfully completed on the vessel next week for a period of extended lithium evaporation in preparation for an upcoming Liquid

  10. Hydrostatic pressure dependence of the luminescence and Raman frequencies in polyfluorene C. M. Martin,1

    E-Print Network [OSTI]

    Chandrasekhar, Meera

    , absorption, and Raman scattering spectra from poly 2,7-,,9,9 -bis(2-ethylhexyl)...fluorene under hydrostatic fabricated from the PF family of materials are known to degrade under operation. The desired blue elec,14 In this work we probe the optical properties of poly 2,7-,,9,9 -bis(2-ethylhexyl)...fluorene PF2/6 via PL

  11. Failure modes and effects analysis of fusion magnet systems

    SciTech Connect (OSTI)

    Zimmermann, M; Kazimi, M S; Siu, N O; Thome, R J

    1988-12-01

    A failure modes and consequence analysis of fusion magnet system is an important contributor towards enhancing the design by improving the reliability and reducing the risk associated with the operation of magnet systems. In the first part of this study, a failure mode analysis of a superconducting magnet system is performed. Building on the functional breakdown and the fault tree analysis of the Toroidal Field (TF) coils of the Next European Torus (NET), several subsystem levels are added and an overview of potential sources of failures in a magnet system is provided. The failure analysis is extended to the Poloidal Field (PF) magnet system. Furthermore, an extensive analysis of interactions within the fusion device caused by the operation of the PF magnets is presented in the form of an Interaction Matrix. A number of these interactions may have significant consequences for the TF magnet system particularly interactions triggered by electrical failures in the PF magnet system. In the second part of this study, two basic categories of electrical failures in the PF magnet system are examined: short circuits between the terminals of external PF coils, and faults with a constant voltage applied at external PF coil terminals. An electromagnetic model of the Compact Ignition Tokamak (CIT) is used to examine the mechanical load conditions for the PF and the TF coils resulting from these fault scenarios. It is found that shorts do not pose large threats to the PF coils. Also, the type of plasma disruption has little impact on the net forces on the PF and the TF coils. 39 refs., 30 figs., 12 tabs.

  12. Farmington Metropolitan Planning Organization 2010-2035 Transportation Plan 

    E-Print Network [OSTI]

    Farmington Metropoliatan Planning Organization

    2010-04-15

    ?bike?lanesfrom?Murray?to?Miler? Ruth?Lane?Blomfield? New?bike?lanesfrom?US?64?to?West?Blanco?Blvd?NM?516?&?US?50? Aztec? Wide?shoulders?marked?as?bike?routeswithin?the?City?Limits?Ash?St.? Aztec? New?bike?lanesfrom?Llano?to?NM?516? Chaco?St.? Aztec? New?bike?lanesfrom?NM?516?to...?Ash?St.?Rio?Grande?Ave? Aztec? New?bike?lanesfrom?Blanco?to?US?550?US?64? Farmington? New?sidewalksfrom?Malta?to?Hilside?(north?side?only)? San?Juan?Blvd? Farmington? New?sidewalksfrom?Butler?to?Main?St.?West?Blanco?Blvd? Blomfield? New?sidewalksfrom?US?50?to...

  13. World frontiers beckon oil finders

    SciTech Connect (OSTI)

    Not Available

    1991-09-01

    This paper discusses the international aspects of the petroleum industry. Most who work in the industry agree that the possibilities for huge are found largely in international regions. Something that is helping fuel that possibility is the way countries are increasingly opening their doors to US oil industry involvement. Listed in this paper is a partial list of the reported projects now underway around the world involving US companies. It is not intended to be comprehensive, but rather an indication of how work continues despite a general lull atmosphere for the oil industry. These include Albania, Bulgaria, Congo, Czechoslovakia, Dominican Republic, Ethiopia, Ireland, Malta, Madagascar, Mongolia, Mozambique, Nigeria, Panama, Paraquay, and Senegal.

  14. Sandia National Laboratories: News: Publications: Lab News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    played a key role in the early years of the affirmative action and equal employment movements as one of the first organizations to sign on to the Plans for Progress (PfP), a...

  15. Available online at www.sciencedirect.com Observation-based learning for brainmachine interfaces

    E-Print Network [OSTI]

    Hatsopoulos, Nicholas

    -like activity in animals and humans [9­12,13 ]. Here, we review a number of recent reports of mirror) and in the rostral inferior parietal cortex (parietal mirror neurons; located in PF/PFG com- plex of the IPL

  16. "Title","Creator/Author","Publication Date","OSTI Identifier...

    Office of Scientific and Technical Information (OSTI)

    Fermi Gamma-Ray Space Telescope: High-Energy Results From the First Year","Michelson, P.F.; KIPAC, Menlo Park; Atwood, W.B.; Ritz, S.; UC, Santa Cruz UC, Santa Cruz, Phys....

  17. Fermi Gamma-Ray Space Telescope: High-Energy Results From the...

    Office of Scientific and Technical Information (OSTI)

    Gamma-Ray Space Telescope: High-Energy Results From the First Year Michelson, P.F.; KIPAC, Menlo Park; Atwood, W.B.; Ritz, S.; UC, Santa Cruz UC, Santa Cruz, Phys. Dept....

  18. TRAC independent assessment for PWR analysis

    SciTech Connect (OSTI)

    Knight, T.D.

    1983-01-01

    LANL is developing the Transient Reactor Analysis Code (TRAC) for application to PWRs. Goal was to analyze large-break loss-of-coolant accidents (LOCAs), and the TRAC-P1A and TRAC-PD2 codes primarily addressed the large-break LOCA. The TRAC-PF1 code contained modifications which enhanced the computational speed of the code and improved its application to small-break LOCAs. The TRAC-PF1/MOD1 code added improved steam-generator modeling, a turbine component, and a control system together with modified constitutive relations to model the balance of plant on the secondary side and to extend the applications to non-LOCA transients. During the past year we assessed TRAC-PD2, TRAC-PF1, and TRAC-PF1/MOD1, using LOFT and Semiscale experiments.

  19. Dendrite-Free Li Deposition Using Trace-Amounts of Water as an...

    Office of Scientific and Technical Information (OSTI)

    (Li) batteries. This is because water is highly reactive with the commonly used LiPF6 salt and leads to the formation of HF that corrodes battery materials. In this work, we...

  20. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    (Li) batteries. This is because water is highly reactive with the commonly used LiPF6 salt and leads to the formation of HF that corrodes battery materials. In this work, we...

  1. Solvate Structures and Computational/Spectroscopic Characterization...

    Office of Scientific and Technical Information (OSTI)

    be obtained from a Raman spectroscopic evaluation of electrolytes containing the LiPF6 salt and aprotic solvents. Of particular note is the overlap of the Raman bands for both...

  2. Protective Force Program Manual

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2000-06-30

    Provides detailed requirements to supplement DOE O 473.2, Protective Force Program, which establishes the requirements and responsibilities for management and operation of the Department of Energy (DOE) Protective Force (PF) Program. Does not cancel other directives.

  3. Structure and dynamical balance of the Antarctic Circumpolar Current in Drake Passage

    E-Print Network [OSTI]

    Firing, Yvonne L.

    2012-01-01

    coordinates, with cross-stream energy greater than along-range. In the PF cross-stream energy at these wavelengthsand potential energy in the deep regions up- stream (W) and

  4. ANALYSIS OF THE PERFORMANCE AND COST EFFECTIVENESS OF NINE SMALL WIND ENERGY CONVERSION SYSTEMS FUNDED BY THE DOE SMALL GRANTS PROGRAM

    E-Print Network [OSTI]

    Kay, J.

    2009-01-01

    C.G. , and Hargreaves, W.R. (May 1977), Wind Energy tics forLarge Arrays Statis- of Wind Turbines (Great Lakes andNo. PF-98655 N under DOE Federal Wind Contract No. DE-AC04-

  5. Pool boiling on nano-finned surfaces 

    E-Print Network [OSTI]

    Sriraman, Sharan Ram

    2008-10-10

    The effect of nano-structured surfaces on pool boiling heat transfer is explored in this study. Experiments are conducted in a cubical test chamber containing fluoroinert coolant (PF5060, Manufacturer: 3M Co.) as the working fluid. Pool boiling...

  6. Var gene transcription and clinical disease manifestation in African P. falciparum malaria field isolates 

    E-Print Network [OSTI]

    Kyriacou, Helen M

    2008-01-01

    The Plasmodium falciparum erythrocyte membrane protein 1 (PfEMP1) variant surface antigens, encoded by the var gene family, play a crucial role in malaria pathogenesis through mediating immunomodulation and host cell ...

  7. Methods for hydrographic data collection and use applied to infer biogeochemistry in the Southern Ocean

    E-Print Network [OSTI]

    Carter, Brendan Rae

    2011-01-01

    Circulation, 143-173. Speer, K. , S. R. Rintoul, and B.the Polar Front (PF) [Speer et al. , 2000]. This upwellingby a strong eddy return flux [Speer et al. , 2000; Böning et

  8. Communicating Design Research Effectively

    E-Print Network [OSTI]

    Roschuni, Celeste Nicole

    2012-01-01

    design research through documentary film”. In: Symposium onthe research were a documentary film and send it out to thePF uses classic documentary film techniques as a “volume

  9. Metabolomic and transcriptomic analysis of the rice response to the bacterial blight pathogen Xanthomonas oryzae pv. oryzae.

    E-Print Network [OSTI]

    2010-01-01

    system in Xanthomonas oryzae pv. oryzae required for AvrXa212002). The Xanthomonas oryzae pv. lozengeoryzae raxP andPf1 against Xanthomo- nas oryzae pv. oryzae in rice leaves.

  10. Metabolomic and transcriptomic analysis of the rice response to the bacterial blight pathogen Xanthomonas oryzae pv. oryzae

    E-Print Network [OSTI]

    2010-01-01

    system in Xanthomonas oryzae pv. oryzae required for AvrXa212002). The Xanthomonas oryzae pv. lozengeoryzae raxP andPf1 against Xanthomo- nas oryzae pv. oryzae in rice leaves.

  11. Slide 1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tier 2 rate pool. Once executed, it creates a binding commitment by the customer to purchase PF power at a Tier 2 Vintage Rate, if such a rate is established. As noted above,...

  12. Plasma focus ion beam fluence and flux—For various gases

    SciTech Connect (OSTI)

    Lee, S. [Centre for Plasma Research, INTI International University, 71800 Nilai (Malaysia) [Centre for Plasma Research, INTI International University, 71800 Nilai (Malaysia); Institute for Plasma Focus Studies, 32 Oakpark Drive, Chadstone 3148 (Australia); Physics Department, University of Malaya (Malaysia); Saw, S. H. [Centre for Plasma Research, INTI International University, 71800 Nilai (Malaysia) [Centre for Plasma Research, INTI International University, 71800 Nilai (Malaysia); Institute for Plasma Focus Studies, 32 Oakpark Drive, Chadstone 3148 (Australia)

    2013-06-15

    A recent paper derived benchmarks for deuteron beam fluence and flux in a plasma focus (PF) [S. Lee and S. H. Saw, Phys. Plasmas 19, 112703 (2012)]. In the present work we start from first principles, derive the flux equation of the ion beam of any gas; link to the Lee Model code and hence compute the ion beam properties of the PF. The results show that, for a given PF, the fluence, flux, ion number and ion current decrease from the lightest to the heaviest gas except for trend-breaking higher values for Ar fluence and flux. The energy fluence, energy flux, power flow, and damage factors are relatively constant from H{sub 2} to N{sub 2} but increase for Ne, Ar, Kr and Xe due to radiative cooling and collapse effects. This paper provides much needed benchmark reference values and scaling trends for ion beams of a PF operated in any gas.

  13. 2011NatureAmerica,Inc.Allrightsreserved.2011NatureAmerica,Inc.Allrightsreserved. N E W S A N D V I E W S

    E-Print Network [OSTI]

    Raychaudhuri, Soumya

    . Acad. Sci. USA 100, 1072­1077 (2003). 9. Colosimo, P.F. et al. Science 307, 1928­1933 (2005). 10. Woods variation in the densities of microbes after experimental infections in stud- ies of host

  14. A study of small drilled shaft piles 

    E-Print Network [OSTI]

    Riewe, Tillman Arthur

    1954-01-01

    2 ~. . . 41 211 Pile 08(44+ Bsseg ol Boll Pf0$%'ties ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ e ~ ~ ~ ~ e ~ ~ 43 22 e Me IIAIF 1 Al Beisg Nt80telk e ~ ~ ~ ~ ~ ~ o ~ r ~ ~ ~ ~ ~ ~ ~ ~ o? ~ ~ ~ ~ ~ 45 23 those Basthm Xllastrsttag %aors ef Plastic Rqpailfhrias...

  15. Pool boiling on nano-finned surfaces 

    E-Print Network [OSTI]

    Sriraman, Sharan Ram

    2009-05-15

    The effect of nano-structured surfaces on pool boiling heat transfer is explored in this study. Experiments are conducted in a cubical test chamber containing fluoroinert coolant (PF5060, Manufacturer: 3M Co.) as the working ...

  16. 450 IEEE TRANSACTIONS ON SMART GRID, VOL. 6, NO. 1, JANUARY 2015 Dynamic State Estimation of a Synchronous

    E-Print Network [OSTI]

    Pollefeys, Marc

    of a Synchronous Machine Using PMU Data: A Comparative Study Ning Zhou, Senior Member, IEEE, Da Meng, Member, IEEEKF), extended Kalman filter (EKF), particle filter (PF), phasor measurement unit (PMU), power system dynamics

  17. Protective Force

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2005-08-26

    Establishes requirements for management and operation of the DOE Protective Force (PF), establishes requirements for firearms operations and defines the firearms courses of fire. Cancels: DOE M 473.2-1A DOE M 473.2-2

  18. Nonlinear Estimation for Model Based Fault Diagnosis of Nonlinear Chemical Systems 

    E-Print Network [OSTI]

    Qu, Chunyan

    2011-02-22

    Kalman filter (EKF), unscented Kalman filter (UKF), particle filtering (PF) and moving horizon estimation (MHE) etc. However, many issues related to the available techniques are to be solved. This dissertation discusses three important techniques...

  19. Notice

    Broader source: Energy.gov (indexed) [DOE]

    Louisiana LNG Energy, LLC Docket No. PF14-17-000 SUPPLEMENTAL NOTICE OF INTENT TO PREPARE AN ENVIRONMENTAL IMPACT STATEMENT FOR THE PLANNED MISSISSIPPI RIVER LNG PROJECT, AND...

  20. Design of PHEVs and Electrolyte Properties | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modeling with Emphasis on Low Temperature Performance High-Volume Manufacturing of LiPF6, A Critical Lithium-ion Battery Material High Voltage Electrolyte for Lithium Batteries...

  1. Search for: All records | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    for a way to improve these results? Fermi Gamma-Ray Space Telescope: High-Energy Results From the First Year Michelson, P.F. ; KIPAC, Menlo Park ; Atwood, W.B. ;...

  2. Throughput Performance of Quantized Proportional Fair Scheduling with Adaptive Modulation and

    E-Print Network [OSTI]

    Ishizaki, Fumio

    Throughput Performance of Quantized Proportional Fair Scheduling with Adaptive Modulation where QPF (Quantized Proportional Fair) scheduling and AMC (adaptive modulation and coding) scheme condition [11]. To solve this unfair problem, the proportional fair (PF) scheduling was proposed where

  3. X-ray photoelectron spectroscopy of negative electrodes from high-power lithium-ion cells showing various levels of power fade

    E-Print Network [OSTI]

    Herstedt, Marie; Abraham, Daniel P.; Kerr, John B.

    2004-01-01

    on samples from low power fade cells, whereas LiPF 6 -basedon samples from high power fade cells. The effect of samplecriteria based on power fade Cell disassembly was conducted

  4. Cotton Response to 1-Methylcyclopropene Under Different Light Regimes and Growth Stages: Lint Yield and Yield Components 

    E-Print Network [OSTI]

    Carden, Charles Warren

    2010-10-12

    imposed at four developmental stages of growth: pinhead square (PHS), first flower (FF), peak flower (PF), and boll development (BD). Data pooled over both years indicated that there were no significant differences in yield for 1-MCP treatments; however...

  5. The influence of anion-pi interactions between multi-atomic anions and pi-acidic ring systems on the self-assembly of coordination compounds 

    E-Print Network [OSTI]

    Schottel, Brandi Lee

    2009-05-15

    ]- and [PF6]- interacting with simple heteroaromatic rings of varying degrees of ?-acidity. Based on the final optimized complex geometries and Atoms in Molecules (AIM) critical point analyses, it was determined that anion-? interactions involving multiatomic...

  6. Static and dynamic light scattering of healthy and malaria-parasite blood cells

    E-Print Network [OSTI]

    Suresh, Subra

    We present the light scattering of individual Plasmodium falciparum-parasitized human red blood cells (Pf-RBCs), and demonstrate progressive alterations to the scattering signal arising from the development of malaria-inducing ...

  7. TRAC Code Modifications Made for APT Blanket Safety Analyses

    SciTech Connect (OSTI)

    Hamm, L.L.

    1998-10-07

    This report provides documentation of the necessary source code modifications made to the TRAC-PF1/MOD2 code version 5.4.28a developed at Los Alamos National Laboratory.

  8. ESPC Project Developer's Resource Guide

    Energy Savers [EERE]

    Federal Project Executive (FPE) 0 2115 X X 2 FPE initiates renewable screening with NREL 0 212015 X X 3 Golden Field Office (GFO) assigns PF identified by FPE; FPE assigns...

  9. 1

    Office of Environmental Management (EM)

    the pad running from the northwest side to the southeast side to minimize run-on of precipitation. Waste containments storage building TA-55-PF-190 is located on the south-eastern...

  10. Zone heated inlet ignited diesel particulate filter regeneration

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Ament, Frank [Troy, MI

    2012-06-26

    An exhaust system that processes exhaust generated by an engine is provided. The system includes: a particulate filter (PF) that is disposed downstream of the engine and that filters particulates from the exhaust; and a grid that includes electrically resistive material that is segmented by non-conductive material into a plurality of zones and wherein the grid is applied to an exterior upstream surface of the PF.

  11. TPX: Contractor preliminary design review. Volume 3, Design and analysis

    SciTech Connect (OSTI)

    NONE

    1995-06-30

    Several models have been formed for investigating the maximum electromagnetic loading and magnetic field levels associated with the Tokamak Physics eXperiment (TPX) superconducting Poloidal Field (PF) coils. The analyses have been performed to support the design of the individual fourteen hoop coils forming the PF system. The coils have been sub-divided into three coil systems consisting of the central solenoid (CS), PF5 coils, and the larger radius PF6 and PF7 coils. Various electromagnetic analyses have been performed to determine the electromagnetic loadings that the coils will experience during normal operating conditions, plasma disruptions, and fault conditions. The loadings are presented as net body forces acting individual coils, spatial variations throughout the coil cross section, and force variations along the path of the conductor due to interactions with the TF coils. Three refined electromagnetic models of the PF coil system that include a turn-by-turn description of the fields and forces during a worst case event are presented in this report. A global model including both the TF and PF system was formed to obtain the force variations along the path of the PF conductors resulting from interactions with the TF currents. In addition to spatial variations, the loadings are further subdivided into time-varying and steady components so that structural fatigue issues can be addressed by designers and analysts. Other electromagnetic design issues such as the impact of the detailed coil designs on field errors are addressed in this report. Coil features that are analyzed include radial transitions via short jogs vs. spiral type windings and the effects of layer-to-layer rotations (i.e clocking) on the field errors.

  12. Morphology-Based Language Modeling for Arabic Speech Recognition Dimitra Vergyri1

    E-Print Network [OSTI]

    Kirchhoff, Katrin

    features (or fac- tors), i.e. w f1:K. Factors represent morphological, syntac- tic, or semantic word are then constructed over (sub)sets of factors. Using a trigram approximation, this can be expressed as: p(f1:K 1 f1:K 2 ::: f1:K T ) TY t=3 p(f1:K t jf1:K t;1 f1:K t;2 ) (1) Each word is dependent not only on a single

  13. Proceedings of the ACL Workshop on Building and Using Parallel Texts, pages 125128, Ann Arbor, June 2005. c Association for Computational Linguistics, 2005

    E-Print Network [OSTI]

    #12;word w can be decomposed into k features, i.e. w f1:K, a trigram model can be defined as p(f1:K 1 , f1:K 2 , ..., f1:K T ) T t=3 p(f1:K t |f1:K t-1 , f1:K t-2 ) (3) Each word is dependent not only Machine Translation Katrin Kirchhoff and Mei Yang Department of Electrical Engineering University

  14. MEASURING PROTOPLANETARY DISK ACCRETION WITH H I PFUND {beta}

    SciTech Connect (OSTI)

    Salyk, Colette [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); Herczeg, Gregory J. [Kavli Institute for Astronomy and Astrophysics at Peking University, Yi He Yuan Lu 5, Hai Dian Qu, Beijing 100871 (China); Brown, Joanna M. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Blake, Geoffrey A. [Division of Geological and Planetary Sciences, Mail Code 150-21, California Institute of Technology, Pasadena, CA 91125 (United States); Pontoppidan, Klaus M. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Van Dishoeck, Ewine F., E-mail: csalyk@noao.edu [Leiden Observatory, Leiden University, P.O. Box 9513, 2300 RA Leiden (Netherlands)

    2013-05-20

    In this work, we introduce the use of H I Pfund {beta} (Pf{beta}; 4.6538 {mu}m) as a tracer of mass accretion from protoplanetary disks onto young stars. Pf{beta} was serendipitously observed in NIRSPEC and CRIRES surveys of CO fundamental emission, amounting to a sample size of 120 young stars with detected Pf{beta} emission. Using a subsample of disks with previously measured accretion luminosities, we show that Pf{beta} line luminosity is well correlated with accretion luminosity over a range of at least three orders of magnitude. We use this correlation to derive accretion luminosities for all 120 targets, 65 of which are previously unreported in the literature. The conversion from accretion luminosity to accretion rate is limited by the availability of stellar mass and radius measurements; nevertheless, we also report accretion rates for 67 targets, 16 previously unmeasured. Our large sample size and our ability to probe high extinction values allow for relatively unbiased comparisons between different types of disks. We find that the transitional disks in our sample have lower than average Pf{beta} line luminosities, and thus accretion luminosities, at a marginally significant level. We also show that high Pf{beta} equivalent width is a signature of transitional disks with high inner disk gas/dust ratios. In contrast, we find that disks with signatures of slow disk winds have Pf{beta} luminosities comparable to those of other disks in our sample. Finally, we investigate accretion rates for stage I disks, including significantly embedded targets. We find that stage I and stage II disks have statistically indistinguishable Pf{beta} line luminosities, implying similar accretion rates, and that the accretion rates of stage I disks are too low to be consistent with quiescent accretion. Our results are instead consistent with both observational and theoretical evidence that stage I objects experience episodic, rather than quiescent, accretion.

  15. A Monte-Carlo Method without Grid to Compute the Exchange Coefficient in the Double Porosity Model

    E-Print Network [OSTI]

    Boyer, Edmond

    Classification: 76S05 (65C05 76M35) Published in Monte Carlo Methods Appl.. 8:2, 129­147, 2002 Archives, links Methods and Applications 8, 2 (2002) 129-147" #12;F. Campillo and A. Lejay / A Monte Carlo Method witouth consists in transforming (1) into a system: m Pm t = a-Pm - (Pm - Pf), m = Meas(m) Meas() f Pf t = a

  16. Electron oxidation of graphite by fluorospecies

    SciTech Connect (OSTI)

    Rosenthal, G.L.

    1984-09-01

    The fluoride-ion affinity (A/sub F/sup -//) of phosphorus pentafluoride was determined to be 100 kcal/mole from the heats of reaction of the Lewis bases SF/sub 4/ and ClO/sub 2/F with PF/sub 5/ near room temperature. The fluoride-ion affinity of boron trifluoride was determined to be 92 kcal/mole from the heat of reaction of ClO/sub 2/F with BF/sub 3/. The crystal structure of ClO/sub 2/BF/sub 4/ was determined and a precise lattice energy was calculated from this structure and used to determined A/sub F/sup -//. Both PF/sub 5/ and BF/sub 3/ were found to react with graphite in the presence of fluorine gas to yield a variety of non-stoichiometric compounds. The fluoride-ion affinity of silicon tetrafluoride is not known, but it does not react with graphite and F/sub 2/ except at high pressures. These and previous results suggested a threshold in oxidizing power of intercalating species below which the oxidative intercalation reaction would not occur. The reduction of C/sub x/PF/sub 6/ by PF/sub 3/ proved that the reaction is thermodynamically controlled to some extent. The displacement of PF/sub 5/ in C/sub x/PF/sub 6/ by BF/sub 3/ (with a smaller A/sub F/sup -//) suggested that two BF/sub 3/ molecules may have a larger fluoride-ion affinity than one PF/sub 5/ and that B/sub 2/F/sub 7//sup -/ may be a stable anion in graphite. Conductivity studies of PF/sub x/ and BF/sub y/ salts showed that a large drop in conductivity when the reaction reaches first stage is due in the most part to direct fluorination of carbon in graphite.

  17. 13-040507-CLN-01 TO: DISTRIBUTION

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    , with zero through the supports cantilevered off of the VV, the safety factor on the shear on the clevis bolt to maintain a safety factor of 1.5 on the mechanical loading of the PF4 support pad studs, assuming that the existing support structure is retained and not improved. ! FzPF 4 = " 1789IPF 4 + 628IPF 4IPF 5 + 52IPF 4 2

  18. Investigation of criticality safety control infraction data at a nuclear facility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cournoyer, Michael E.; Merhege, James F.; Costa, David A.; Art, Blair M.; Gubernatis, David C.

    2014-10-27

    Chemical and metallurgical operations involving plutonium and other nuclear materials account for most activities performed at the LANL's Plutonium Facility (PF-4). The presence of large quantities of fissile materials in numerous forms at PF-4 makes it necessary to maintain an active criticality safety program. The LANL Nuclear Criticality Safety (NCS) Program provides guidance to enable efficient operations while ensuring prevention of criticality accidents in the handling, storing, processing and transportation of fissionable material at PF-4. In order to achieve and sustain lower criticality safety control infraction (CSCI) rates, PF-4 operations are continuously improved, through the use of Lean Manufacturing andmore »Six Sigma (LSS) business practices. Employing LSS, statistically significant variations (trends) can be identified in PF-4 CSCI reports. In this study, trends have been identified in the NCS Program using the NCS Database. An output metric has been developed that measures ADPSM Management progress toward meeting its NCS objectives and goals. Using a Pareto Chart, the primary CSCI attributes have been determined in order of those requiring the most management support. Data generated from analysis of CSCI data help identify and reduce number of corresponding attributes. In-field monitoring of CSCI's contribute to an organization's scientific and technological excellence by providing information that can be used to improve criticality safety operation safety. This increases technical knowledge and augments operational safety.« less

  19. Investigation of criticality safety control infraction data at a nuclear facility

    SciTech Connect (OSTI)

    Cournoyer, Michael E.; Merhege, James F.; Costa, David A.; Art, Blair M.; Gubernatis, David C.

    2014-10-27

    Chemical and metallurgical operations involving plutonium and other nuclear materials account for most activities performed at the LANL's Plutonium Facility (PF-4). The presence of large quantities of fissile materials in numerous forms at PF-4 makes it necessary to maintain an active criticality safety program. The LANL Nuclear Criticality Safety (NCS) Program provides guidance to enable efficient operations while ensuring prevention of criticality accidents in the handling, storing, processing and transportation of fissionable material at PF-4. In order to achieve and sustain lower criticality safety control infraction (CSCI) rates, PF-4 operations are continuously improved, through the use of Lean Manufacturing and Six Sigma (LSS) business practices. Employing LSS, statistically significant variations (trends) can be identified in PF-4 CSCI reports. In this study, trends have been identified in the NCS Program using the NCS Database. An output metric has been developed that measures ADPSM Management progress toward meeting its NCS objectives and goals. Using a Pareto Chart, the primary CSCI attributes have been determined in order of those requiring the most management support. Data generated from analysis of CSCI data help identify and reduce number of corresponding attributes. In-field monitoring of CSCI's contribute to an organization's scientific and technological excellence by providing information that can be used to improve criticality safety operation safety. This increases technical knowledge and augments operational safety.

  20. Temperature-dependent structural property and power factor of n type thermoelectric Bi{sub 0.90}Sb{sub 0.10} and Bi{sub 0.86}Sb{sub 0.14} alloys

    SciTech Connect (OSTI)

    Malik, K.; Das, Diptasikha; Bandyopadhyay, S.; Banerjee, Aritra; Center for Research in Nanoscience and Nanotechnology, University of Calcutta, JD-2, Sector-III, Saltlake City, Kolkata 700 098 ; Mandal, P.; Srihari, Velaga

    2013-12-09

    Thermal variation of structural property, linear thermal expansion coefficient (?), resistivity (?), thermopower (S), and power factor (PF) of polycrystalline Bi{sub 1-x}Sb{sub x} (x?=?0.10 and 0.14) samples are reported. Temperature-dependent powder diffraction experiments indicate that samples do not undergo any structural phase transition. Rietveld refinement technique has been used to perform detailed structural analysis. Temperature dependence of ? is found to be stronger for Bi{sub 0.90}Sb{sub 0.10}. Also, PF for direct band gap Bi{sub 0.90}Sb{sub 0.10} is higher as compared to that for indirect band gap Bi{sub 0.86}Sb{sub 0.14}. Role of electron-electron and electron-phonon scattering on ?, S, and PF has been discussed.

  1. Topography and Mechanical Property Mapping of International Simple Glass Surfaces with Atomic Force Microscopy

    SciTech Connect (OSTI)

    Hopf, Juliane [ORNL; Pierce, Eric M [ORNL

    2014-01-01

    Quantitative Nanomechanical Peak Force (PF-QNM) TappingModeTM atomic force microscopy measurements are presented for the first time on polished glass surfaces. The PF-QNM technique allows for topography and mechanical property information to be measured simultaneously at each pixel. Results for the international simple glass which represents a simplified version of SON68 glass suggests an average Young s modulus of 78.8 15.1 GPa is within the experimental error of the modulus measured for SON68 glass (83.6 2 GPa) with conventional approaches. Application of the PF-QNM technique will be extended to in situ glass corrosion experiments with the goal of gaining atomic-scale insights into altered layer development by exploiting the mechanical property differences that exist between silica gel (e.g., altered layer) and pristine glass surface.

  2. Tokamak Physics Experiment (TPX) power supply design and development

    SciTech Connect (OSTI)

    Neumeyer, C.; Bronner, G.; Lu, E.; Ramakrishnan, S.

    1995-04-01

    The Tokamak Physics Experiment (TPX) is an advanced tokamak project aimed at the production of quasi-steady state plasmas with advanced shape, heating, and particle control. TPX is to be built at the Princeton Plasma Physics Laboratory (PPPL) using many of the facilities from the Tokamak Fusion Test Reactor (TFTR). TPX will be the first tokamak to utilize superconducting (SC) magnets in both the toroidal field (TF) and poloidal field (PF) systems. This new feature requires a departure from the traditional tokamak power supply schemes. This paper describes the plan for the adaptation of the PPPL/FTR power system facilities to supply TPX. Five major areas are addressed, namely the AC power system, the TF, PF and Fast Plasma Position Control (FPPC) power supplies, and quench protection for the TF and PF systems. Special emphasis is placed on the development of new power supply and protection schemes.

  3. Diallylsulfide attenuates excessive collagen production and apoptosis in a rat model of bleomycin induced pulmonary fibrosis through the involvement of protease activated receptor-2

    SciTech Connect (OSTI)

    Kalayarasan, Srinivasan, E-mail: kalaivasanbio@gmail.com; Sriram, Narayanan; Soumyakrishnan, Syamala; Sudhandiran, Ganapasam, E-mail: sudhandiran@yahoo.com

    2013-09-01

    Pulmonary fibrosis (PF) can be a devastating lung disease. It is primarily caused by inflammation leading to severe damage of the alveolar epithelial cells. The pathophysiology of PF is not yet been clearly defined, but studying lung parenchymal injury by involving reactive oxygen species (ROS) through the activation of protease activated receptor-2 (PAR-2) may provide promising results. PAR-2 is a G-protein coupled receptor is known to play an important role in the development of PF. In this study, we investigated the inhibitory role of diallylsulfide (DAS) against ROS mediated activation of PAR-2 and collagen production accompanied by epithelial cell apoptosis. Bleomycin induced ROS levels may prompt to induce the expression of PAR-2 as well as extracellular matrix proteins (ECM), such as MMP 2 and 9, collagen specific proteins HSP-47, ?-SMA, and cytokines IL-6, and IL-8RA. Importantly DAS treatment effectively decreased the expression of all these proteins. The inhibitory effect of DAS on profibrotic molecules is mediated by blocking the ROS level. To identify apoptotic signaling as a mediator of PF induction, we performed apoptotic protein expression, DNA fragmentation analysis and ultrastructural details of the lung tissue were performed. DAS treatment restored all these changes to near normalcy. In conclusion, treatment of PF bearing rats with DAS results in amelioration of the ROS production, PAR-2 activation, ECM production, collagen synthesis and alveolar epithelial cell apoptosis during bleomycin induction. We attained the first evidence that treatment of DAS decreases the ROS levels and may provide a potential therapeutic effect attenuating bleomycin induced PF. - Highlights: • DAS inhibits PAR-2 activity; bleomycin stimulates PAR-2 activity. • Increase in PAR-2 activity is correlated with pulmonary fibrosis • DAS reduces pro-inflammatory activity linked to facilitating pulmonary fibrosis. • DAS inhibits apoptosis of alveolar epithelial cells.

  4. Removal and recovery of metal ions from process and waste streams using polymer filtration

    SciTech Connect (OSTI)

    Jarvinen, G.D.; Smith, B.F.; Robison, T.W.; Kraus, K.M.; Thompson, J.A.

    1999-06-13

    Polymer Filtration (PF) is an innovative, selective metal removal technology. Chelating, water-soluble polymers are used to selectively bind the desired metal ions and ultrafiltration is used to concentrate the polymer-metal complex producing a permeate with low levels of the targeted metal ion. When applied to the treatment of industrial metal-bearing aqueous process streams, the permeate water can often be reused within the process and the metal ions reclaimed. This technology is applicable to many types of industrial aqueous streams with widely varying chemistries. Application of PF to aqueous streams from nuclear materials processing and electroplating operations will be described.

  5. A radiation-hardened, low-noise, high-speed, integrated charge preamplifier for the Superconducting Supercollider 

    E-Print Network [OSTI]

    Ling, Kuok Young

    1989-01-01

    of the tester enclosed in an Aluminium box, 28 HP6062A Pulse 6enerator 50 0 coax +7 V Ferrite Bead 10 pF Chip 1 pF 1 ns 47 0 61FE Pream Ibias N4416 475 0 1 mH g Ferrite 6ead -7 V 50 0 coax HP541110 Wavet. Rec. Fig. 13. Complete test set... and all the circuit components are soldered onto the PCB. A 24-pin. text tool socket is also soldered onto the PCB to make repetition of measurements easy to manage. The PCB is then mounted onto the Aluminium box by using four plastic snap-on's. A test...

  6. TRAC code development status and plans

    SciTech Connect (OSTI)

    Spore, J.W.; Liles, D.R.; Nelson, R.A.; Dotson, P.J.; Steinke, R.G.; Knight, T.D.; Henninger, R.J.; Martinez, V.; Jenks, R.P.; Cappiello, M.W.

    1986-01-01

    This report summarizes the characteristics and current status of the TRAC-PF1/MOD1 computer code. Recent error corrections and user-convenience features are described, and several user enhancements are identified. Current plans for the release of the TRAC-PF1/MOD2 computer code and some preliminary MOD2 results are presented. This new version of the TRAC code implements stability-enhancing two-step numerics into the 3-D vessel, using partial vectorization to obtain a code that has run 400% faster than the MOD1 code.

  7. Environmentally Safe Control of Zebra Mussel Fouling

    SciTech Connect (OSTI)

    Daniel Molloy

    2008-02-29

    The two primary objectives of this USDOE-NETL contract were successfully achieved during the project: (1) to accelerate research on the development of the bacterium Pseudomonas fluorescens strain CL145A (Pf-CL145A) as a biocontrol agent for zebra mussels (Dreissena polymorpha) and quagga mussels (Dreissena rostriformis bugensis)--two invasive freshwater bivalve species that are infesting water pipes in power plants; and (2) to identify a private-sector company that would move forward to commercialize Pf-CL145A as a substitute for the current polluting use of biocide chemicals for control of these dreissenid mussels in power plant pipes.

  8. Structure and sequence analyses of Bacteroides proteins BVU_4064 and BF1687 reveal presence of two novel predominantly-beta domains, predicted to be involved in lipid and cell surface interactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Natarajan, Padmaja; Punta, Marco; Kumar, Abhinav; Yeh, Andrew P; Godzik, Adam; Aravind, L.

    2015-01-16

    N-terminal domains of BVU_4064 and BF1687 proteins from Bacteroides vulgatus and Bacteroides fragilis respectively are members of the Pfam family PF12985 (DUF3869). Proteins containing a domain from this family can be found in most Bacteroides species and, in large numbers, in all human gut microbiome samples. Both BVU_4064 and BF1687 proteins have a consensus lipobox motif implying they are anchored to the membrane, but their functions are otherwise unknown. The C-terminal half of BVU_4064 is assigned to protein family PF12986 (DUF3870); the equivalent part of BF1687 was unclassified.

  9. ELLESMERE ROAD ELLESMERE ROAD

    E-Print Network [OSTI]

    Toronto, University of

    Up Area Emergency Phones Parking Lots Accessible ParkingPARKING Building Index AA - Arts PA - Vistor Parking Lot A D4 PB - Permit Lot B D5 PC - Permit/Accessible Parking Lot C C5 PD - Permit Parking Lot D B5 PE - Dept. Visitor Parking Lot E B3 PF - Vistor Parking Lot F C2 PG - Permit Parking Lot

  10. Technical and Cost Assessment of the PCAST Machine

    E-Print Network [OSTI]

    . The electrical energy dissipated during a pulse causes the temperature in the PF and TF coils to rise. The coils and engineering prototype aspects. Descoping the mission in this way allows a number of cost-saving design changesCode to calculate the plasma volume and to the elongation used to calculate the energy confinement time (K, here

  11. ITER Project Status Positioning the US

    E-Print Network [OSTI]

    of the funds #12;ITER value is about 50% in "high-tech systems" TF Coils and Structure 10% PF/CS/CC 4% Nb3Sn 3% Cooling Water System 5% Building and Site Facilities 14% High-TechLower-Tech #12;Guidelines water 23% Tentative US in-kind contributions by Value High-TechLower-Tech #12;Overview of tentative US

  12. arXiv:hepex/0109015 CLNS 01/1754

    E-Print Network [OSTI]

    -end sig- nal processing chips, with a combined power output of #24;360 W. The drift chamber's heat sources coolant-control platforms provides independent and regulated heat removal from four recently upgraded: the suitability of using the aliphatic-hydrocarbon solvent PF TM -200IG as a heat-transfer uid, the sensor

  13. 22 September 2000 Z .Chemical Physics Letters 328 2000 197202

    E-Print Network [OSTI]

    Ashworth, Stephen H.

    22 September 2000 Z .Chemical Physics Letters 328 2000 197­202 www.elsevier.nlrlocatercplett Sub BS8 1TS, UK Received 4 July 2000; in final form 2 August 2000 Abstract A preliminary version with a discussion of the bonding in PF as revealed by the hyperfine constants. q 2000 Elsevier Science B.V. All

  14. SCATTERING CONFIGURATION SPACES RICHARD MELROSE AND MICHAEL SINGER

    E-Print Network [OSTI]

    Melrose, Richard

    with orners T PF foundry low up V QF sntersetionEorders II RF foundry ongurtion spes IT SF wultiEdigonls IW TF hEolletions PP UF foundry digonls PS VF ttering ongurtion spes PU WF eordering lowEups PU IHF

  15. Atmos. Chem. Phys., 9, 83178330, 2009 www.atmos-chem-phys.net/9/8317/2009/

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    and Physics Carbon monoxide distributions from the IASI/METOP mission: evaluation with other space-borne remote sensors M. George1, C. Clerbaux1, D. Hurtmans2, S. Turquety1,*, P.-F. Coheur2, M. Pommier1, J Abstract. The Infrared Atmospheric Sounding Interferom- eter (IASI) onboard the MetOp satellite measures

  16. Molecular Cell, Vol. 6, 861871, October, 2000, Copyright 2000 by Cell Press Mutations in the P. falciparum Digestive

    E-Print Network [OSTI]

    Symington, Lorraine S.

    . falciparum Digestive Vacuole Transmembrane Protein PfCRT and Evidence for Their Role in Chloroquine molecules released by digestion of hemoglobin (Goldberg et al., 1990). Two characteristics that distinguish in the DV upon hemoglobinThe Bronx, New York 10461 Department of Chemistry digestion), and (4) increased

  17. AN INTEGRATED APPROACH TOWARDS THE SIMULATION ANALYSIS OF NETWORK PROTOCOLS

    E-Print Network [OSTI]

    Massari, Luisa

    represents an important aspect at every stage in the life cycle of computer systems. Design, recon guration of the processing mech- anisms of the system itself. The architectures of computer systems, and the ap- plications Research Council (C.N.R.) under Grant 92.01571.PF69 and by the Italian MURST under the 40% and 60% Projects

  18. or executed, and not to others, while the remainder responded to

    E-Print Network [OSTI]

    Behrmann, Marlene

    characteristics in anterior intraparietal area PF/IPL. One of the studies [2] reported that a small number,3] reproduced the original finding in area F5, while the third [4] reported neurons with the same functional that a small number of mirror neurons in areas F5 and IPL responded selectively to a particular movement goal

  19. Thermally Stable Gel Polymer Electrolytes Min-Kyu Song,a

    E-Print Network [OSTI]

    Popov, Branko N.

    Thermally Stable Gel Polymer Electrolytes Min-Kyu Song,a Young-Taek Kim,a Yong Tae Kim,b Byung Won/polyvinylidene fluoride PEGDA/PVdF blend gel polymer electrolytes, low molecular weight (M 742) liquid PEGDA oligomer was mixed with PVdF-HFP dissolved in ethylene carbonate/dimethyl carbonate/LiPF6 liquid electrolytes

  20. TDDB AT LOW VOLTAGES: AN ELECTROCHEMICAL PERSPECTIVE

    E-Print Network [OSTI]

    Bazant, Martin Z.

    tail of the lifetime distribution2 ). Typical electron injection mechansms include Schottky emission and Fowler- Nordheim (FN) tunneling and transport in conduction band (CB) of dielectric is Poole-Frenkel (PF) in presence of traps. Carrier heating in CB and thermalization can lead to formation of additional traps

  1. ACCEPTED -IEEE INTERNATIONAL SYMPOSIUM ON INTELLIGENT CONTROL -2003 1 Internet-like Protocols for the Control and

    E-Print Network [OSTI]

    Mexico Albuquerque, NM 87131-0001 {rsandova,chaouki,hokayem}@eece.unm.edu Abstract In this paper we show, priced, and corrupted". However, and for control purposes, it is also "timed". To make the general idea, Mexico. The research of C.T. Abdallah and P.F. Hokayem is supported by NSF-0233205. #12;ACCEPTED - IEEE

  2. An Off-Chip Capacitor Free Low Dropout Regulator with PSR Enhancement at Higher Frequencies 

    E-Print Network [OSTI]

    Gopalraju, Seenu

    2012-02-14

    closer to open loop?s unity-gain frequency. The stability and PSR are totally valid even for load capacitor varying from 0 to 100 pF. The proposed capacitor-less LDO is fabricated in On-Semi 0.5 ?m fully CMOS process. Experimental results confirm a PSR...

  3. IFE Chamber Development -To ETF and Beyond

    E-Print Network [OSTI]

    . Logan, J. D Lindl, P.F. Peterson, "An Engineering Test Facility of Heavy Ion Fusion ­ Options (~1000 MWe) Engineering Test Facility (100-300 MWe) Power Technologies for Demo Funded by NNSA · NIF phenomena testing (e.g., molten salt flow loops, x-ray exposure testing, etc.) #12;FESAC Dev Plan 5 IFE ETF

  4. HighHigh--Performance Computing Research atPerformance Computing Research at Oak Ridge National LaboratoryOak Ridge National Laboratory

    E-Print Network [OSTI]

    Engelmann, Christian

    Computing 1/47 · Nation's largest energy laboratory · Nation's largest science facility: · The $1.4 billion Science Laboratory within the U.S. Department of Energywithin the U.S. Department of Energy · Privately of Energy Bland_Jaguar_SC08 Peak performance 1.645 PF System memory 362 TB Disk space 10.7 PB Disk bandwidth

  5. ELECTRICAL ENGINEERING TECHNOLOGY PROGRAM EET 105: ELECTRICAL SYSTEMS

    E-Print Network [OSTI]

    Lozano-Nieto, Albert

    Storage -Energy can be stored in a capacitor to be released when desired Example: Defibrillator used1 ELECTRICAL ENGINEERING TECHNOLOGY PROGRAM EET 105: ELECTRICAL SYSTEMS Instructor: Albert Lozano. electrolytic - Non-electrolytic: smaller values: nF, pF - Electrolytic: Chemical process to increase

  6. Departmental Narrative for Math 108 Math 108 is an introductory calculus course designed primarily for prospective School of Business

    E-Print Network [OSTI]

    Yu, Gexin

    must give the College today if my goal is to provide the mathematics department with an income stream, if a firm's costs rise by $C per unit produced, then in order to maximize profit, the firm's optimal if demand elasticity E = |pf f | income stream of length Y

  7. Protective Force Program Manual

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2001-12-20

    Provides detailed requirements to supplement DOE O 473.2, PROTECTIVE FORCE PROGRAM, which establishes the requirements and responsibilities for management and operation of the Department of Energy (DOE) Protective Force (PF) Program. Change 1 revised pages in Chapters IV and VI on 12/20/2001.

  8. BIOLOGY OF REPRODUCTION 74, 473480 (2006) Published online before print 9 November 2005.

    E-Print Network [OSTI]

    Burnstock, Geoffrey

    2006-01-01

    Neuroscience Centre,3 Departments of Urology4 and Clinical Biochemistry,5 Royal Free Hospital, London NW3 2PF measurement of semen analysis [4]. Semen analysis is the end product of sperm production, transport, and ejaculation through the genitourinary system. A reduction in sperm numbers may reflect reduced transportation

  9. FY2009 Run Campaign Highlights Roger Raman

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    Capabilities for 2009: · Routine Li usage ( 65% of shots) · CHI absorber PF coils · HHFW antenna grounding to Retention Milestone Important for Understanding Li pumping, ITER T Retention PMI probe measurements show Li increases global retention from 87% to 93% in NBI-heated plasmas With Li Without Li 4 #12;NSTXNSTX

  10. Helium isotope study of geothermal features in Chile with field and laboratory data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dobson, Patrick

    Dobson, P.F., Kennedy, B.M., Reich, M., Sanchez, P., and Morata, D. (2013) Effects of volcanism, crustal thickness, and large scale faulting on the He isotope signatures of geothermal systems in Chile. Proceedings, 38th Workshop on Geothermal Reservoir Engineering, Stanford University, Feb. 11-13, 2013

  11. Laser Direct Writing Organic Small Molecule Luminophores

    E-Print Network [OSTI]

    Petta, Jason

    efficiency, high cost Low efficiency, low cost http://www.aist.go.jp/aist_e/aist_today http electroluminescent Iridium complex developed by Bernhard, Slinker groups Ir(ppy)2(dtb-bpy)]+(PF6 -) #12;How PV's Work from valence band into conduction band #12;Junctions · Efficiency of PV cell depends partly on whether

  12. Capture of particles of dust by convective flow Dmitry V. Lyubimov

    E-Print Network [OSTI]

    Straube, Arthur V.

    , University of Potsdam, Am Neuen Palais 10, PF 601553, D-14415 Potsdam, Germany and CFD Laboratory, Institute of Theoretical Physics, Perm State University, Bukirev 15, 614990 Perm, Russia and CFD Laboratory, Institute is essential in lowering fuel consumption during combustion of liquid fuels. In biology, recent developments

  13. Stabilization of Layered Metal Oxides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    stabilizing cations and anions (NH 4 ) 3 AlF 6 ; NH 4 PF 6 ; NH 4 BF 4 in water, methanol, etc molarity of solutions 2.5 x 10 -3 M pH 6.0 - 6.5 Composition used:...

  14. Helium isotope study of geothermal features in Chile with field and laboratory data

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Dobson, Patrick

    2013-02-11

    Dobson, P.F., Kennedy, B.M., Reich, M., Sanchez, P., and Morata, D. (2013) Effects of volcanism, crustal thickness, and large scale faulting on the He isotope signatures of geothermal systems in Chile. Proceedings, 38th Workshop on Geothermal Reservoir Engineering, Stanford University, Feb. 11-13, 2013

  15. Cerebellar LTD and Pattern Recognition by Purkinje Cells

    E-Print Network [OSTI]

    Steuber, Volker

    ., 1998; Ohyama et al., 2003). The hypothesis that PF LTD implements motor learning dates back to Marr and Albus's theoretical work (Albus, 1971; Marr, 1969), published long before Ito and collabo- rators found experimental evidence for the existence of LTD (Ito et al., 1982). This hypothesis has become known as the Marr

  16. SOUTHERN OCEAN EDDY MIXING AND THE FORMATION OF MODE WATERS J.B. Salle, R. Morrow

    E-Print Network [OSTI]

    fronts (PF, SAF and SAF- N). Sallee, J.B. N. Wienders, K. Speer and R.A. Morrow, 2006. Formation.B; Morrow, R. ; Speer, K., 2008. Eddy heat diffusion and Subantarctic Mode Water formation, Geophys. Res. Lett, 35, L05607, doi:10.1029/2007GL032827 Sallée, J.B. Morrow, R.; Speer, K. and Lumpkin, R

  17. Publications by Bruno Leibundgut Leibundgut, B.: Light Curves of Supernovae Type I, Ph.D. Thesis, Basel: University of Basel

    E-Print Network [OSTI]

    Leibundgut, Bruno

    .: Supernovae a Few Years Past Maximum, in SN 1987A and other Supernovae, eds. I.J. Danziger and K. Kj., Phillips, M.M., Smith, R.C., Win- kler, P.F., Winge, C., Roth, K.C., Blades, J.C., Branch, D., Chevalier, R

  18. The average zero time lag cross-correlation of LASA earth noise signals 

    E-Print Network [OSTI]

    Calmes, Grady Alden

    1972-01-01

    between 100 to 200 mHz is absent. All the long-period vertical data obtained from LASA indicated a PF peak between 50 to 100 mHz and in all cases the LPSFI RO (10) SP SEIS 0755:56 GYT NGV. 20 1969 CI CI I CI S C I IX CI p 25 I III D CI CL...

  19. NOVEL INDUCTORLESS NEURISTOR LINE Indexing terms: Delays, Neural nets

    E-Print Network [OSTI]

    Wilamowski, Bogdan Maciej

    of a pair of p-n-p-n-p-n transistors and an RC circuit with small capacitor values. This allows integration = 30kfi, C, = C2 = 50 pF b Type-T junction realisation c Type-R junction realisation ELECTRONICS

  20. Protective Force Program

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2000-06-30

    Establishes policy, requirements, responsibilities, and authorities, for the management and operation of the Department of Energy (DOE) Protective Force (PF) Program. Extended until 7-7-06 by DOE N 251.64, dated 7-7-05 Cancels: DOE 5632.7A

  1. Perception & Psychophysics 2001, 63 (8), 1421-1455

    E-Print Network [OSTI]

    Klein, Stanley

    Perception & Psychophysics 2001, 63 (8), 1421-1455 Psychophysics, as its metaphysical sounding name (Strasburger, 2001a) on a new defin- ition of slope as applied to a wide variety of PF shapes, I will comment the method of choice.Kaern- bach (2001b) introducesan "unforced choice"methodthat offers

  2. JOURNAL DE PHYSIQUE Colloque C3,suppl6ment au n06, Tome 44,juin 1983 page C3-551

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    stayed to delay the commercialization of high energy density batteries. The "doping" of (CHJxand related was previously only known for graphite, but the extreme reactivity of its intercalation compounds have precluded-oxidizable, non-nucleophilic, like C10 -, PF6-, AsF6-. Such systems can be used for secondary batteries only i4

  3. Current collectors for rechargeable Li-Air batteries

    SciTech Connect (OSTI)

    Veith, Gabriel M [ORNL; Dudney, Nancy J [ORNL

    2011-01-01

    Here we report the negative influence of porous nickel foam for use as current collectors in rechargeable Li-air batteries. Uncoated nickel foam promotes the decomposition of LiPF6-organic carbonate electrolytes under normal charging conditions reported for rechargeable Li-air cells. We have identified Ni free porous carbon supports as more appropriate cathode current collectors.

  4. A Framework for Assessing Impacts of Marine Protected Areas in Moorea (French Polynesia)1

    E-Print Network [OSTI]

    Osenberg, Craig W.

    .lison@mail .pf ). (AutoPDF V7 22/1/08 14:13) UHP (7Â10") Janson J-1906 Pacific Science, 62:3 PMU: D(C) 07/01/2008 PMU: WSL(A) 18/01/2008 pp. 427­438 1906_62-3_15 (p. 427) #12;Attempts to restore marine systems

  5. Operator-splitting finite element algorithms for computations of high-dimensional parabolic problems

    E-Print Network [OSTI]

    Ganesan, Sashikumaar

    problems Sashikumaar Ganesan a, , Lutz Tobiska b a Numerical Mathematics and Scientific Computing of Analysis and Numerical Mathematics, Otto-von-Guericke University, PF 4120, D-39016 Magdeburg, Germany a r. The numerical results obtained with the full 3D computations and the operator-split 2D + 1D computations

  6. Efficient blind symbol rate estimation and data symbol detection algorithms for linearly modulated signals 

    E-Print Network [OSTI]

    Park, Sang Woo

    2009-05-15

    the EM algorithm. In the EM algorithm, it is difficult to obtain the closed form of the log-likelihood function and the density function. Therefore, both functions are approximated by using the Particle Filter (PF) technique. In addition, the symbol rate...

  7. Family Health and Medical Record. 

    E-Print Network [OSTI]

    Shirer, Mary Ann

    1982-01-01

    A 1 ;.:::=====-====== gr cultural Ext ---0 -0 enalon Service --~?The~Te~xaa~AA~~ . M University S yatem, Daniel C Pf 0 annallel, Director, College Stall _____on, Texas B-1377 Contents Introduction..., Extension health education specialist, The Texas A&M University System. 1 Family name! __________________________________________________________________ __ Add res&-__________________________________________________________________ __ Telephone...

  8. Multiprobe Spectroscopic Evidence for "Hyperpolarity" within 1-Butyl-3-methylimidazolium Hexafluorophosphate Mixtures with Tetraethylene Glycol

    SciTech Connect (OSTI)

    Sarkar, Abhra [Indian Institute of Technology, Delhi; Trivedi, Shruti [Indian Institute of Technology, Delhi; Baker, Gary A [ORNL; Pandey, Siddharth [Indian Institute of Technology, Delhi

    2008-01-01

    A hybrid, potentially green solvent system composed of tetraethylene glycol (TEG) and the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim][PF6]) was investigated across all mole fractions with regard to the solvent properties of the mixture. For this purpose, a suite of absorbance- and fluorescence-based solvatochromic probes were utilized to explore solute-solvent and solvent-solvent interactions existing within the [bmim][PF6] + TEG system. These studies revealed an interesting and unusual synergistic solvent effect. In particular, a remarkable hyperpolarity was observed in which the ET value, comprising dipolarity/polarizability and hydrogen bond donor (HBD) acidity contributions, at intermediate mole fractions of the binary mixture well exceeded that of the most polar pure component (i.e., [bmim][PF6]). Independently determined dipolarity/polarizability ( *) and HBD acidity (R) Kamlet-Taft values for the [bmim][PF6] + TEG mixtures were also observed to be anomalously high at intermediate mole fractions, whereas hydrogen bond acceptor (HBA) basicities ( values) were much more in line with the ideal arithmetic values predicted on a mole fraction basis.

  9. HHFW and ECW/EBWHHFW and ECW/EBW Progress and Plans for 2009-13Progress and Plans for 2009-13

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    ) Control & Bulk Heating& Bulk Heating (12) 28 GHz ECH generates plasma for HHFW heating & CD (2) IP q(0) control & bulk heating IP Target [kA] Time (2) HHFW (3) HHFW + NBI (1) CHI, PF, Guns, 28 GHz Efficient &Provides Efficient & Controllable HeatingControllable Heating & Core CD in& Core CD in H

  10. Actin Filament Tracking Based on Particle Filters and Stretching Open Active Contour

    E-Print Network [OSTI]

    Huang, Xiaolei

    Actin Filament Tracking Based on Particle Filters and Stretching Open Active Contour Models a novel algorithm for actin filament tracking and elongation measurement. Particle Filters (PF-dimensional state space while naturally integrating filament body constraints to tip estimation. Our algorithm

  11. Compatibility of Lithium Salts with Solvent of the Non-Aqueous Electrolyte in Li–O2 Batteries

    SciTech Connect (OSTI)

    Du, Peng; Lu, Jun; Lau, Kah Chun; Luo, Xiangyi; Bareno, Javier; Zhang, Xiaoyi; Ren, Yang; Zhang, Zhengcheng; Curtiss, Larry A.; Sun, Yang-Kook; Amine, Khalil

    2013-02-20

    The stability of lithium salts, especially in the presence of reduced oxygen species, O2 and H2O (even in a small amount), plays an important role in the cyclability and capacity of Li–O2 cells. This combined experimental and computational study provides evidence that the stability of the electrolyte used in Li–O2 cells strongly depends on the compatibility of lithium salts with solvent. In the case of the LiPF6–1NM3 electrolyte, the decomposition of LiPF6 occurs in the cell as evidenced by in situ XRD, FT-IR and XPS analysis, which triggers the decomposition of 1NM3 solvent due to formation of HF from the decomposition of LiPF6. These reactions lead to degradation of the electrolyte and cause poor cyclability of the cell. The same reactions are not observed when LiTFSI and LiCF3SO3 are used as the lithium salts in 1NM3 solvent, or LiPF6 is used in TEGDME solvent.

  12. Proportionally Fair Selective Cooperation for Cellular Networks

    E-Print Network [OSTI]

    Leung, Kin K.

    Proportionally Fair Selective Cooperation for Cellular Networks: Algorithm, Simulation and Analysis, a node and a cooperative relay are selected in a proportionally fair (PF) manner to transmit to the base cooperative transmissions, and is called proportionally fair selective cooperation (PFSC). This tech- nique

  13. Collinear Laser-Beam Ion-Beam Measurement of the Mean Lifetime of the Ar Ii 4p'2f-Degrees-7/2 Level 

    E-Print Network [OSTI]

    Jin, J.; Church, David A.

    1993-01-01

    The mean lifetime tau of the 4p'F-2(7/2)-degrees level of Ar II has been measured using a variant of the collinear laser-beam-fast-ion-beam spectroscopy technique. Our variant requires no mechanical motion or laser frequency tuning. The result...

  14. 1 Plasmodium falciparum SSB Tetramer Binds 2 Single-Stranded DNA Only in a Fully Wrapped Mode

    E-Print Network [OSTI]

    Lohman, Timothy M.

    1 Plasmodium falciparum SSB Tetramer Binds 2 Single-Stranded DNA Only in a Fully Wrapped Mode 3 with numerous DNA repair and replication proteins. Ec- 24 SSB tetramers can bind ssDNA in multiple DNA binding in fully wrapped complexes with site sizes of 30 52­65 nt/tetramer. Pf-SSB does not transition to the more

  15. Physical and mechanical properties of mixed comrind and hardwood

    E-Print Network [OSTI]

    with phenol-formaldehyde resin Guangping Han Qinglin Wu Xinfang Duan Abstract Three-layer mixed comrind (CRD) and hardwood oriented strandboard (OSB) were manufactured using phenol- formaldehyde (PF) resin with comrind. With continuing production growth and decreasing quality wood supply, the cost of wood fibers used to manufacture

  16. Tensile and dimensional properties of wood strands made from

    E-Print Network [OSTI]

    the developmentofnewstrand-basedcom- posite lumber as substitutes. The most common composite lumber products on the market, com- posite lumber has gained tremendous market share with projected production volume at 2 million m3- cally phenol-formaldehyde (PF) or emul- sified polymeric isocyanate resins. Strands applied with resin

  17. F1-CN-64/AP2-17 DEUTERIUM-TRITIUM TFTR PLASMAS WITH HIGH

    E-Print Network [OSTI]

    Budny, Robert

    . The fusion power output, Pf, in high temperature tokamak plasmas heated by neutral beam injection scales by increasing the product of li Ip . Technical aspects of generating the high li plasma in previous experimentsF1-CN-64/AP2-17 DEUTERIUM-TRITIUM TFTR PLASMAS WITH HIGH INTERNAL INDUCTANCE* S. A. SABBAGH1 , E. D

  18. Final environmental assessment: TRU waste drum staging building, Technical Area 55, Los Alamos National Laboratory

    SciTech Connect (OSTI)

    1996-02-09

    Much of the US Department of Energy`s (DOE`s) research on plutonium metallurgy and plutonium processing is performed at Los Alamos National Laboratory (LANL), in Los Alamos, New Mexico. LANL`s main facility for plutonium research is the Plutonium Facility, also referred to as Technical Area 55 (TA-55). The main laboratory building for plutonium work within the Plutonium Facility (TA-55) is the Plutonium Facility Building 4, or PF-4. This Environmental Assessment (EA) analyzes the potential environmental effects that would be expected to occur if DOE were to stage sealed containers of transuranic (TRU) and TRU mixed waste in a support building at the Plutonium Facility (TA-55) that is adjacent to PF-4. At present, the waste containers are staged in the basement of PF-4. The proposed project is to convert an existing support structure (Building 185), a prefabricated metal building on a concrete foundation, and operate it as a temporary staging facility for sealed containers of solid TRU and TRU mixed waste. The TRU and TRU mixed wastes would be contained in sealed 55-gallon drums and standard waste boxes as they await approval to be transported to TA-54. The containers would then be transported to a longer term TRU waste storage area at TA-54. The TRU wastes are generated from plutonium operations carried out in PF-4. The drum staging building would also be used to store and prepare for use new, empty TRU waste containers.

  19. 5X-960304-CLN-01 TO: DISTRIBUTION

    E-Print Network [OSTI]

    Princeton Plasma Physics Laboratory

    and perhaps some reduction in the plasma ramp rate it will be possible to match the requirements to their maximum values (per 5) above) in 200mS, the voltage and power requirement exceeds that of the ESAT PF point. However, more exact scenario information is required. This assumption is very conservative; more

  20. J. Phys. I ffance 4 (1994) 351-355 MARCH 1994, PAGE 351 Classification

    E-Print Network [OSTI]

    Boyer, Edmond

    1994-01-01

    .ork of a refined theoretical model we show that the sharp magne- toresistance dips instead of peaks must exist, PF6, Re04, etc., demonstrate unique properties both in field-induced spin-density-wave (FISDW) state and a metallic state in a magnetic field [1-9]. One of the most interesting features of their magnetic properties

  1. A dynamic grouping strategy for implementation of the particle filter on a massively parallel computer

    E-Print Network [OSTI]

    Nakano, Shin'ya

    computer Shin'ya Nakano The Institute of Statistical Mathematics Tachikawa, Tokyo, Japan. shiny@ism.ac.jp Abstract ­ A practical way to implement the parti- cle filter (PF) on a massively parallel computer is dis to be computation- ally expensive in applying to high-dimensional problems because a enormous number of particles

  2. High performance CMOS integrated circuits for optical receivers 

    E-Print Network [OSTI]

    SamadiBoroujeni, MohammadReza

    2009-05-15

    .7GHz for a 0.6pF photodiode capacitance. The power dissipations for the highest and the lowest gains are 8.2mW and 24.9mW respectively. A new technique for designing uniform multistage amplifiers (MA) for high frequency applications is introduced...

  3. Methods for Rapid Estimation of Motor Input Power in HVAC Assessments 

    E-Print Network [OSTI]

    Christman, Kevin D.

    2011-08-08

    -based input power estimation approach.....................................................................................................45 Table 5: Coefficients for Equation 97 determined by regression of the Baldor... and Reliance motor performance data................................................................................70 Table 6: Comparison of Current Method, V?I?PF??3, and Slip Method at predicting input power for the Baldor/Reliance motors...

  4. Contributions of Burning Plasma Physics Experiment to Fusion Energy Goals

    E-Print Network [OSTI]

    life-cycle cost of electricity: · Low recirculating power; · High power density; · High thermal any current-drive system. There is more flexibility in choosing plasma parameters. (Incorrect) Pulsed operation has a current-drive system, the PF system. This "current- drive" system is quite expensive (large

  5. Journal of Power Sources 165 (2007) 427435 Short communication

    E-Print Network [OSTI]

    2007-01-01

    of the electrode (cm2 cm-3) Brug Bruggeman coefficient ce Li+ concentration in the electrolyte (mol cm-3) cs solid. The electrolyte (Ferro, Independence, OH) was 1.0 M LiPF6 in a solvent mixture of EC/PC/EMC/DEC. The half cell

  6. Highly efficient electrochemiluminescence from Ru,,II... complex with PEO-PHP-PEO as a buffer layer

    E-Print Network [OSTI]

    Wan, Xin-hua

    CF3SO3 was introduced into light-emitting electrochemical cells. The response rate and efficiency of indium tin oxide/PEO-PHP-PEO LiCF3SO3 / Ru bpy 3 PF6 2/Au, showed a turn-on voltage as low as 2.85 V

  7. THE INFLUENCE OF FINES CONTENT AND PANEL DENSITY ON PROPERTIES OF MIXED HARDWOOD ORIENTED STRANDBOARD1

    E-Print Network [OSTI]

    Research Associate School of Renewable Natural Resources Louisiana State University Agricultural Center-formaldehyde (PF) resin as binder. The effects of fines level and density on the panel properties were studied, including effective modulus (EM), linear expansion (LE), and swelling stresses using single-layer data

  8. Contribution of seasonal sub-Antarctic surface water variability to millennial-scale changes in atmospheric CO2over the last deglaciation and Marine Isotope Stage 3

    E-Print Network [OSTI]

    Gottschalk, Julia; Skinner, Luke C.; Waelbroeck, Claire

    2014-12-17

    production of biogenic opal in e Southern Ocean south of the PF (Anderson et al., 2009). While the ?13C of G. bulloides decreases during millennial-scale ses in CO2,atm, that of N. pachyderma (s.) increases (Fig. 5). We ggest that the rise in ?13C of N...

  9. Fast Curing of Composite Wood Products

    SciTech Connect (OSTI)

    Dr. Arthur J. Ragauskas

    2006-04-26

    The overall objective of this program is to develop low temperature curing technologies for UF and PF resins. This will be accomplished by: • Identifying the rate limiting UF and PF curing reactions for current market resins; • Developing new catalysts to accelerate curing reactions at reduced press temperatures and times. In summary, these new curing technologies will improve the strength properties of the composite wood products and minimize the detrimental effects of wood extractives on the final product while significantly reducing energy costs for wood composites. This study is related to the accelerated curing of resins for wood composites such as medium density fiberboard (MDF), particle board (PB) and oriented strandboard (OSB). The latter is frequently manufactured with a phenol-formaldehyde resin whereas ureaformaldehyde (UF) resins are usually used in for the former two grades of composite wood products. One of the reasons that hinder wider use of these resins in the manufacturing of wood composites is the slow curing speed as well as inferior bondability of UF resin. The fast curing of UP and PF resins has been identified as an attractive process development that would allow wood to be bonded at higher moisture contents and at lower press temperatures that currently employed. Several differing additives have been developed to enhance cure rates of PF resins including the use of organic esters, lactones and organic carbonates. A model compound study by Conner, Lorenz and Hirth (2002) employed 2- and 4-hydroxymethylphenol with organic esters to examine the chemical basis for the reported enhanced reactivity. Their studies suggested that the enhance curing in the presence of esters could be due to enhanced quinone methide formation or enhanced intermolecular SN2 reactions. In either case the esters do not function as true catalysts as they are consumed in the reaction and were not found to be incorporated in the polymerized resin product. An alternative approach to accelerated PF curing can be accomplished with the addition amines or amides. The later functionality undergoes base catalyzed hydrolysis yielding the corresponding carboxyl ate and free amine which rapidly reacts with the phenolic methylol groups facilitating polymerization and curing of the PF resin (Pizzi, 1997).

  10. Adaptive and Efficient Computing for Subsurface Simulation within ParFlow

    SciTech Connect (OSTI)

    Tiedeman, H; Woodward, C S

    2010-11-16

    This project is concerned with the PF.WRF model as a means to enable more accurate predictions of wind fluctuations and subsurface storage. As developed at LLNL, PF.WRF couples a groundwater (subsurface) and surface water flow model (ParFlow) to a mesoscale atmospheric model (WRF, Weather Research and Forecasting Model). It was developed as a unique tool to address coupled water balance and wind energy questions that occur across traditionally separated research regimes of the atmosphere, land surface, and subsurface. PF.WRF is capable of simulating fluid, mass, and energy transport processes in groundwater, vadose zone, root zone, and land surface systems, including overland flow, and allows for the WRF model to both directly drive and respond to surface and subsurface hydrologic processes and conditions. The current PF.WRF model is constrained to have uniform spatial gridding below the land surface and matching areal grids with the WRF model at the land surface. There are often cases where it is advantageous for land surface, overland flow and subsurface models to have finer gridding than their atmospheric counterparts. Finer vertical discretization is also advantageous near the land surface (to properly capture feedbacks) yet many applications have a large vertical extent. However, the surface flow is strongly dependent on topography leading to a need for greater lateral resolution in some regions and the subsurface flow is tightly coupled to the atmospheric model near the surface leading to a need for finer vertical resolution. In addition, the interactions (e.g. rain) will be highly variable in space and time across the problem domain so an adaptive scheme is preferred to a static strategy to efficiently use computing and memory resources. As a result, this project focussed on algorithmic research required for development of an adaptive simulation capability in the PF.WRF system and its subsequent use in an application problem in the Central Valley of California. This report documents schemes of use for a future implementation of an adaptive grid capability within the ParFlow subsurface flow simulator in PF.WRF. The methods describe specific handling of the coarse/fine boundaries within a cell-centered discretization of the nonlinear parabolic Richards equation model for variable saturated flow. In addition, we describe development of a spline fit and table lookup method implemented within ParFlow to enhance computational efficiency of variably saturated flow calculations.

  11. TRAC analysis of the Crystal River Unit-3 Plant transient of February 26, 1980

    SciTech Connect (OSTI)

    Coddington, P.; Willcutt, G.J.E. Jr.

    1983-01-01

    This paper describes the application of the TRAC-PD2 and TRAC-PF1 codes to analyze the Crystal River transient. The PD2 and PF1 analyses used the three-dimensional and one-dimensional vessel models, respectively. Both calculations predicted the plant depressurization caused by the open PORV and the subsequent repressurization caused by closing the PORV and continuing high-pressure injection flow. Also, natural circulation was calculated in loop B following reestablishment of feedwater to the loop-B steam generator. After system repressurization, the codes calculated that pressure was relieved through the safety valves, and an intermittent flow occurred in loop A because of high-pressure-injection-driven density variations.

  12. Lithium Salts for Advanced Lithium Batteries: Li-metal, Li-O2, and Li-S

    SciTech Connect (OSTI)

    Younesi, Reza; Veith, Gabriel M; Johansson, Patrik; Edstrom, Kristina; Vegge, Tejs

    2015-01-01

    Presently lithium hexafluorophosphate (LiPF6) is the dominant Li-salt used in commercial rechargeable lithium-ion batteries (LIBs) based on a graphite anode and a 3-4 V cathode material. While LiPF6 is not the ideal Li-salt for every important electrolyte property, it has a uniquely suitable combination of properties (temperature range, passivation, conductivity, etc.) rendering it the overall best Li-salt for LIBs. However, this may not necessarily be true for other types of Li-based batteries. Indeed, next generation batteries, for example lithium-metal (Li-metal), lithium-oxygen (Li-O2), and lithium sulphur (Li-S), require a re-evaluation of Li-salts due to the different electrochemical and chemical reactions and conditions within such cells. This review explores the critical role Li-salts play in ensuring in these batteries viability.

  13. Spatially resolved high-resolution x-ray spectroscopy of high-current plasma-focus discharges

    SciTech Connect (OSTI)

    ZajaPc, S.; Rzadkiewicz, J.; Scholz, M.; Paduch, M.; Zielinska, E.; Rosmej, O.; Yongtao, Zhao; Gojska, A.

    2010-10-15

    Soft x-ray emission from a Mather-type plasma-focus device (PF-1000) operated at {approx}400 kJ was measured. The high density and temperature plasma were generated by the discharge in the deuterium-argon gas mixture in the modified (high-current) plasma-focus configuration. A spherically bent mica crystal spectrograph viewing the axial output of the pinch region was used to measure the x-ray spectra. Spatially resolved spectra including the characteristic x-ray lines of highly ionized Ar and continua were recorded by means of an x-ray film. The x-ray emission of PF-1000 device was studied at different areas of the pinch.

  14. Solvation of the Fluorine Containing Anions and Their Lithium Salts in Propylene Carbonate and Dimethoxyethane

    E-Print Network [OSTI]

    Chaban, Vitaly

    2015-01-01

    Electrolyte solutions based on the propylene carbonate (PC)-dimethoxyethane (DME) mixtures are of significant importance and urgency due to emergence of lithium-ion batteries. Solvation and coordination of the lithium cation in these systems have been recently attended in detail. However, analogous information concerning anions (tetrafluoroborate, hexafluorophosphate) is still missed. This work reports PM7-MD simulations (electronic-structure level of description) to include finite-temperature effects on the anion solvation regularities in the PC-DME mixture. The reported result evidences that the anions appear weakly solvated. This observation is linked to the absence of suitable coordination sites in the solvent molecules. In the concentrated electrolyte solutions, both BF4 and PF6 prefer to exist as neutral ion pairs (LiBF4, LiPF6).

  15. Bis(fluoromalonato)borate (BFMB) Anion Based Ionic Liquid As an Additive for Lithium-Ion Battery Electrolytes

    SciTech Connect (OSTI)

    Sun, Xiao-Guang [ORNL] [ORNL; Liao, Chen [ORNL] [ORNL; Baggetto, Loic [ORNL] [ORNL; Guo, Bingkun [ORNL] [ORNL; Unocic, Raymond R [ORNL] [ORNL; Veith, Gabriel M [ORNL] [ORNL; Dai, Sheng [ORNL] [ORNL

    2014-01-01

    Propylene carbonate (PC) is a good solvent for lithium ion battery applications due to its low melting point and high dielectric constant. However, PC is easily intercalated into graphite causing it to exfoliate, killing its electrochemical performance. Here we report on the synthesis of a new ionic liquid electrolyte based on partially fluorinated borate anion, 1-butyl-1,2-dimethylimidazolium bis(fluoromalonato)borate (BDMIm.BFMB), which can be used as an additive in 1 M LiPF6/PC electrolyte to suppress graphite exfoliation and improve cycling performance. In addition, both PC and BDMIm.BFMB can be used synergistically as additive to 1.0M LiPF6/methyl isopropyl sulfone (MIPS) to dramatically improve its cycling performance. It is also found that the chemistry nature of the ionic liquids has dramatic effect on their role as additive in PC based electrolyte.

  16. The role of triplet states in the emission mechanism of polymer light-emitting diodes

    E-Print Network [OSTI]

    M. Arif; S. Mukhopadhyay; S. Ramasesha; S. Guha

    2009-03-01

    The blue emission of polyfluorene (PF) based light-emitting diodes (LEDs) is known to degrade due to a low energy green emission, which hitherto has been attributed to oxidative defects. By studying the electroluminescence from ethyl-hexyl substituted PF LEDs in the presence of oxygen and in an inert atmosphere, and by using trace quantities of paramagnetic impurities (PM) in the polymer, we show that the triplet states play a major role in the low energy emission mechanism. Our time-dependent many-body studies show that there is a large cross-section for the triplet formation in the electron-hole recombination process in presence of PM, and intersystem crossing from excited singlet to triplet states.

  17. Usher Road NW University Court NW

    E-Print Network [OSTI]

    Calgary, University of

    AB KNB OO DC TFDL PF MFH RC RT IH MLT KA CA RU CHG MC NO BR CHC A CHF CHE CHD MLB GL SW20 EDC OL Lot 2 Lot3 Lot 1 Arts Parkade Lot 3A Lot 5 Lot 33 Lot 8 Lot 7 MSC Parkade Lot 13 Lot 16 DC IH Lot 8 Lot 5 Dining Centre Detail Dining Centre Parking Locations ¯UCMAPS Feb 7, 2010 University of Calgary

  18. Estimating and controlling Gulf Coast ticks, Amblyomma maculatum Koch, on the coastal prairie of Texas 

    E-Print Network [OSTI]

    Bengaly, Sekouba

    1987-01-01

    cattle 26 e C ~ Caner el 5 Pirmechri n-Chl or myri fc s ~ Lace Seasan Fenvalerace m 0 Early Seasan Fenvalerace c 4 X 07/17 08/0 I 08/15 08/29 09/13 09/27 10/ IQ gefe kkG. 3. C P ' o f Pf' t' k, Otokf' Duges, burden on Hereford cattle treated...

  19. A small angle neutron scattering (SANS) experiment using very cold neutrons (VCN).

    SciTech Connect (OSTI)

    Bleuel, M.; Carpenter, J. M.; Micklich, B. J.; Geltenbort, P.; Mishima, K.; Shimizu, H. M.; Iwashita, Y.; Hirota, K.; Hino, M.; Kennedy, S. J.; Lal, J.; Inst. Laue Langevin; Neutron Science Lab.; Kyoto Univ.; Riken; Bragg Inst.

    2009-01-01

    This paper describes the results of SANS measurements of small samples using the very cold neutron (VCN) beam of the PF2 instrument at the Institut Laue Langevin (ILL), France. In addition to a classical SANS pinhole collimation, the experiment used a polarizing supermirror as a monochromator and a magnetic sextupole lens to focus the neutron beam in order to gain intensity and avoid any material in the neutron beam besides the sample.

  20. ---Home Yahoo! Help My Yahoo! http://asia.news.yahoo.com/041215/kyodo/d870cn2o0.html

    E-Print Network [OSTI]

    - - -Home Yahoo! Help My Yahoo! http://asia.news.yahoo.com/041215/kyodo/d870cn2o0.html Thursday to release energy. But in a fusion reactor, energy is harnessed by forcing the nuclei of light atoms together.news.yahoo.com/search/news_asia_pf?p=ukey%3A3043438 #12;Rokkasho is already home to nuclear fuel cycle facilities run by Japan Nuclear Fuel

  1. Clerodendrum x speciosum (C. splendens x C. thomsoniae) (Cultivated) 2 

    E-Print Network [OSTI]

    James R. Manhart

    2011-08-10

    mixed-valent FeIFeII complexes. An X-ray crystal structure of one of these complexes, (?-SCH2C(CH3)2CH2S-)[Fe(CO)2PMe3]2PF6 shows both a semi-bridging carbonyl and an open site similar to the 2-Fe subsite in the Hox state of the enzyme active site...

  2. The Divisor Classes of the Hypersurface zpm = G(I1,...,In) in charcteristic p>0

    E-Print Network [OSTI]

    Lang, Jeffrey

    1983-08-01

    /3x,, 3G/3x;) = 1. Then the order o/Cl(F) ispf, where n-\\ fm, has order pf where f< ngig -l)/2. Q.E.D. Theorem 3.9. For each m, Cl(Fm) is a finite p-group of type ip'\\...,p'r) where each ij < m. The order of Cl(Fm) « pm("_ ')«<«-fc)/2, where g = deg G. Proof (by...

  3. Polymer filtration systems for dilute metal ion recovery

    SciTech Connect (OSTI)

    Smith, B.F.; Robison, T.W.; Jarvinen, G.D.

    1998-12-01

    Scientists at Los Alamos National Laboratory have developed a metal recovery system that meets the global treatment demands for all kinds of industrial and metal-processing streams. The Polymer Filtration (PF) System--a process that is easily operated and robust--offers metal-finishing businesses a convenient and inexpensive way to recover and recycle metal ions in-house, thus reducing materials costs, waste removal costs, and industrial liability. As a valuable economic and environmental asset, the PF System has been named a winner of a 1995 R and D 100 Award. These awards are presented annually by R and D Magazine to the one hundred most significant technical innovations of the year. The PF System is based on the use of water-soluble metal-binding polymers and on advanced ultrafiltration membranes. Customers for this technology will receive new soluble polymers, especially formulated for their waste stream, and the complete PF processing unit: a reaction reservoir, pumps, plumbing, controls, and the advanced ultrafiltration membranes, all in a skid mounted frame. Metal-bearing waste water is treated in the reaction reservoir, where the polymer binds with the metal ions under balanced acid/base conditions. The reservoir fluid is then pumped through the ultrafiltration system--a cartridge packed with ultrafiltration membranes shaped in hollow fibers. As the fluid travels inside the fiber, water and other small molecules--simple salts such as calcium and sodium, for example--pass through the porous membrane walls of the fibers and are discharged through the outlet as permeate. The polymer-bound metal, which is too large to pass through the pores, is both purified and concentrated inside the hollow fibers and is returned to the fluid reservoir for further waste water treatment.

  4. NUMERICAL ANALYSIS OF FLOW FIELDS GENERATED BY ACCELERATING FLAMES

    E-Print Network [OSTI]

    Kurylo, J.

    2011-01-01

    TR=D60*1 pf'o/nf>o/I GF-I '+UfO*.2/0f C. *2/2. ' C-----A(CTC SC=INITIAL STEP ~IZE C A"UFO=SPtC VOL "ATIC FCI' CCNST PRE=CFI". ~1 $ UPCCl,I,::UFO',O) EPC(I,I'=EP(M,O' $ PPC(I, II=

  5. Possibility of Pairing-Induced Even-Denominator Fractional Quantum

    E-Print Network [OSTI]

    Scarola, Vito

    fermions (CFs) B* = B ­2p0 Effective Field = 0 / B * = 0 / |B*| } = */(2p * 1)+- Effective Filling at = 5/2 ( Willett et. al. '87, Pan et. al `99) Novel p-wave paired state of CFs at = 5/2 : Electrons transform into CFs and pair up to yield a gap and hence FQHE MR = (zj -zk) 2 Pf[ (zj - zk) -1] (Moore, Read

  6. 496 IEEE COMMUNICATIONS LETTERS, VOL. 9, NO. 6, JUNE 2005 A Family of ISI-Free Polynomial Pulses

    E-Print Network [OSTI]

    Chaturvedi, A K

    transmission [5] for a data rate of 2W, for any arbitrary function H(f). P(f) = 1 2W , |f| f1 H(|f|), f1 f1) 0, elsewhere (1) where f1 = W(1 - ), 0 1 and hence f1 W. We wish to find the constraints on H(f) such that the ADR of p(t) is t-k . For this

  7. An artificial intelligence approach to model-based gas lift troubleshooting 

    E-Print Network [OSTI]

    Ortiz-Volcan, Jose Luis

    1990-01-01

    . 6 Prudhoe Bay Gas Factor Correlation. . . . . . . . . . . . . . , . C. 7 Program Listing Written Under Microsoft QuickBasicr& . D GEOTHERMAL GRADIENT CORRELATIONS. . . . . . . . . . . Page 124 124 130 132 132 133 134 135 137 141 144... of liquid slug, Mft/min. XIX Subscript Gas component. Greek pf pt OR Liquid gradient (without dissolved gas), Psi/ft Liquid gradient (with dissolved gas), Psig/ft Upstream temperature, oR 1 ~DUCTION This introductory section has three goals: (1...

  8. FYI: January 6, 1983 - June 30, 1983

    E-Print Network [OSTI]

    1983-01-01

    ~en h.:1mpcred th is year by the f;l e t til.:l t seve r al 11: 1."T·bcrs of the corr:mittee nre ;}l s(l bp.ing co nsid ered for p romotion and/nr tenure .,nd .1re n, ... t pf'rillitted t o be presen t during discussion of theLr fil('~ . t\\ rt er ~:(1...

  9. INTRODUCTION '.,J; ";:'.~, I;; ~' 'i'(: i./.; ,. , . . , , ' ; : ! " , . ' : -O

    E-Print Network [OSTI]

    ~,'~~ualidi~tripu:' :o~of.temperl1turef()r that:seasoA. On anotherYoyage(fr~mH~lifll:+ Pf?:Ne,~vXR.!lf~ Ul'lng the last~ ;Mal,uY's,(181i2) t\\lp.~1jl.alcbart by i'qoW'lng ab(lutne~ parts or tho Gult or Mahiea's54:6°to 59°and

  10. AC System Equipment Specification, Installation and Operational Options for Improved Indoor Humidity Control 

    E-Print Network [OSTI]

    Shirey, D. B.

    2008-01-01

    Specification, Installation and Operational Options for Improved Indoor Humidity Control Don B. Shirey, III Program Manager Florida Solar Energy Center Cocoa, Florida ABSTRACT High-efficiency home designs have significantly reduced sensible...: Florida Solar Energy Center. James, P., J.E. Cummings, J. Sonne, R. Vieira, J. Klongerbo. 1997. The Effect of Residential Equipment Capacity on Energy Use, Demand, and Run-Time, FSEC-PF-328-97. Cocoa, FL: Florida Solar Energy Center. Lennox...

  11. EA-1963: Elba Liquefaction Project, Savannah, Georgia

    Broader source: Energy.gov [DOE]

    The Federal Energy Regulatory Commission (FERC) is preparing, with DOE as a cooperating agency, an EA to analyze the potential environmental impacts of a proposal to add natural gas liquefaction and export capabilities at the existing Elba Liquefied Natural Gas Terminal near Savannah, Georgia. Additional information is available at FERC’s eLibrary website, elibrary.ferc.gov/idmws/docket_search.asp; search for docket number PF13-3.

  12. PrincetonUniversityLibrary FirestoneLibraryInformation

    E-Print Network [OSTI]

    Petta, Jason

    Room Reference Collection (DSS) 1-6E Data and Statistical Services (SSRCDC) 2-10E Data and Statistical are designated by a "q" placed after the call number: AP20.R2425q. These books are usually shelved after all" B-15L Fine Arts P ­ PC C-7H Language and Literature PD ­ PF B-8L Language and Literature PG ­ PG3097

  13. The TPX Cryostat Conceptual Design

    SciTech Connect (OSTI)

    Ravenscroft, D.; Posey, A.; Heitzenroeder, P.; Brown, T.

    1993-10-06

    The TPX (Tokamak Physics Experiment) will be the first tokamak to employ both superconducting TF (toroidal field) and PF (poloidal field) magnets. Consequently, the entire device is located within an evacuated cryostat to provide the necessary thermal barrier between the ambient temperature test cell and the magnets that are cooled by supercritical liquid helium at 5{degrees}K. This paper describes the cryostat design requirements, design concepts, and the cryostat fabrication and installation.

  14. Internal Technical Report, Safety Analysis Report 5 MW(e) Raft River Research and Development Plant

    SciTech Connect (OSTI)

    Brown, E.S.; Homer, G.B.; Shaber, C.R.; Thurow, T.L.

    1981-11-17

    The Raft River Geothermal Site is located in Southern Idaho's Raft River Valley, southwest of Malta, Idaho, in Cassia County. EG and G idaho, Inc., is the DOE's prime contractor for development of the Raft River geothermal field. Contract work has been progressing for several years towards creating a fully integrated utilization of geothermal water. Developmental progress has resulted in the drilling of seven major DOE wells. Four are producing geothermal water from reservoir temperatures measured to approximately 149 C (approximately 300 F). Closed-in well head pressures range from 69 to 102 kPa (100 to 175 psi). Two wells are scheduled for geothermal cold 60 C (140 F) water reinjection. The prime development effort is for a power plant designed to generate electricity using the heat from the geothermal hot water. The plant is designated as the ''5 MW(e) Raft River Research and Development Plant'' project. General site management assigned to EG and G has resulted in planning and development of many parts of the 5 MW program. Support and development activities have included: (1) engineering design, procurement, and construction support; (2) fluid supply and injection facilities, their study, and control; (3) development and installation of transfer piping systems for geothermal water collection and disposal by injection; and (4) heat exchanger fouling tests.

  15. Internal Technical Report, Safety Analysis Report 5 MW(e) Raft River Pilot Plant

    SciTech Connect (OSTI)

    Brown, E.S.; Homer, G.B.; Spencer, S.G.; Shaber, C.R.

    1980-05-30

    The Raft River Geothermal Site is located in Southern Idaho's Raft River Valley, southwest of Malta, Idaho, in Cassia County. EG and G idaho, Inc., is the DOE's prime contractor for development of the Raft River geothermal field. Contract work has been progressing for several years towards creating a fully integrated utilization of geothermal water. Developmental progress has resulted in the drilling of seven major DOE wells. Four are producing geothermal water from reservoir temperatures measured to approximately 149 C (approximately 300 F). Closed-in well head pressures range from 69 to 102 kPa (100 to 175 psi). Two wells are scheduled for geothermal cold 60 C (140 F) water reinjection. The prime development effort is for a power plant designed to generate electricity using the heat from the geothermal hot water. The plant is designated as the ''5 MW(e) Raft River Research and Development Plant'' project. General site management assigned to EG and G has resulted in planning and development of many parts of the 5 MW program. Support and development activities have included: (1) engineering design, procurement, and construction support; (2) fluid supply and injection facilities, their study, and control; (3) development and installation of transfer piping systems for geothermal water collection and disposal by injection; and (4) heat exchanger fouling tests.

  16. 2007 Wholesale Power Rate Schedules : 2007 General Rate Schedule Provisions.

    SciTech Connect (OSTI)

    United States. Bonneville Power Administration.

    2006-11-01

    This schedule is available for the contract purchase of Firm Power to be used within the Pacific Northwest (PNW). Priority Firm (PF) Power may be purchased by public bodies, cooperatives, and Federal agencies for resale to ultimate consumers, for direct consumption, and for Construction, Test and Start-Up, and Station Service. Rates in this schedule are in effect beginning October 1, 2006, and apply to purchases under requirements Firm Power sales contracts for a three-year period. The Slice Product is only available for public bodies and cooperatives who have signed Slice contracts for the FY 2002-2011 period. Utilities participating in the Residential Exchange Program (REP) under Section 5(c) of the Northwest Power Act may purchase Priority Firm Power pursuant to the Residential Exchange Program. Rates under contracts that contain charges that escalate based on BPA's Priority Firm Power rates shall be based on the three-year rates listed in this rate schedule in addition to applicable transmission charges. This rate schedule supersedes the PF-02 rate schedule, which went into effect October 1, 2001. Sales under the PF-07 rate schedule are subject to BPA's 2007 General Rate Schedule Provisions (2007 GRSPs). Products available under this rate schedule are defined in the 2007 GRSPs. For sales under this rate schedule, bills shall be rendered and payments due pursuant to BPA's 2007 GRSPs and billing process.

  17. Growth and shortening of microtubules: a two-state model approach

    E-Print Network [OSTI]

    Yunxin Zhang

    2011-08-03

    In this study, a two-state mechanochemical model is presented to describe the dynamic instability of microtubules (MTs) in cells. The MTs switches between two states, assembly state and disassembly state. In assembly state, the growth of MTs includes two processes: free GTP-tubulin binding to the tip of protofilament (PF) and conformation change of PF, during which the first tubulin unit which curls outwards is rearranged into MT surface using the energy released from the hydrolysis of GTP in the penultimate tubulin unit. In disassembly state, the shortening of MTs includes also two processes, the release of GDP-tibulin from the tip of PF and one new tubulin unit curls out of the MT surface. Switches between these two states, which are usually called rescue and catastrophe, happen stochastically with external force dependent rates. Using this two-state model with parameters obtained by fitting the recent experimental data, detailed properties of MT growth are obtained, we find that MT is mainly in assembly state, its mean growth velocity increases with external force and GTP-tubulin concentration, MT will shorten in average without external force. To know more about the external force and GTP-tubulin concentration dependent properties of MT growth, and for the sake of the future experimental verification of this two-state model, eleven {\\it critical forces} are defined and numerically discussed.

  18. Interactions of Ionic Liquids with Uranium and its Bioreduction

    SciTech Connect (OSTI)

    Zhang, C.; Francis, A.

    2012-09-18

    We investigated the influence of ionic liquids (ILs) 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM]{sup +}[PF{sub 6}]{sup -}, N-ethylpyridinium trifluoroacetate [EtPy]{sup +}[CF{sub 3}COO]{sup -} and N-ethylpyridinium tetrafluoroborate [Et-Py]{sup +}[BF{sub 4}]{sup -} on uranium reduction by Clostridium sp. under anaerobic conditions. Potentiometric titration, UV-vis spectrophotometry, LC-MS and EXAFS analyses showed monodentate complexation between uranyl and BF{sub 4}{sup -} PF{sub 6}{sup -}; and bidentate complexation with CF{sub 3}COO{sup -}. Ionic liquids affected the growth of Clostridium sp. as evidenced by decrease in optical density, changes in pH, gas production, and the extent of U(VI) reduction and precipitation of U(IV) from solution. Reduction of U(VI) to U(IV) was observed in the presence of [EtPy][BF{sub 4}] and [BMIM][PF{sub 6}] but not with [EtPy][CF{sub 3}COO].

  19. Survival and Quality of Life After Stereotactic or 3D-Conformal Radiotherapy for Inoperable Early-Stage Lung Cancer

    SciTech Connect (OSTI)

    Widder, Joachim; Postmus, Douwe; Ubbels, Jan F.; Wiegman, Erwin M.; Langendijk, Johannes A.

    2011-11-15

    Purpose: To investigate survival and local recurrence after stereotactic ablative radiotherapy (SABR) or three-dimensional conformal radiotherapy (3D-CRT) administered for early-stage primary lung cancer and to investigate longitudinal changes of health-related quality of life (HRQOL) parameters after either treatment. Methods and Materials: Two prospective cohorts of inoperable patients with T1-2N0M0 primary lung tumors were analyzed. Patients received 70 Gy in 35 fractions with 3D-CRT or 60 Gy in three to eight fractions with SABR. Global quality of life (GQOL), physical functioning (PF), and patient-rated dyspnea were assessed using the respective dimensions of European Organization for Research and Treatment of Cancer Core Questionnaire-C30 and LC13. HRQOL was analyzed using multivariate linear mixed-effects modeling, survival and local control (LC) using the Kaplan-Meier method, Cox proportional hazards analysis, and Fine and Gray multivariate competing risk analysis as appropriate. Results: Overall survival (OS) was better after SABR compared with 3D-CRT with a HR of 2.6 (95% confidence interval [CI]: 1.5-4.8; p < 0.01). 3D-CRT conferred a subhazard ratio for LC of 5.0 (95% CI: 1.7-14.7; p < 0.01) compared with SABR. GQOL and PF were stable after SABR (p = 0.21 and p = 0.62, respectively). Dyspnea increased after SABR by 3.2 out of 100 points (95% CI: 1.0-5.3; p < 0.01), which is clinically insignificant. At 1 year, PF decreased by an excess of 8.7 out of 100 points (95% CI: 2.8-14.7; p < 0.01) after 3D-CRT compared with SABR. Conclusion: In this nonrandomized comparison of two prospective cohorts of medically inoperable patients with Stage I lung cancer, OS and LC were better after SABR. GQOL, PF, and patient-rated dyspnea were stable after SABR, whereas PF decreased after 3D-CRT approaching clinical significance already at 1 year.

  20. Does Plasmodium falciparum have an Achilles' heel?

    E-Print Network [OSTI]

    Liao Y Chen

    2013-05-21

    Plasmodium falciparum is the parasite that causes the most severe form of malaria. Currently, science has been established about its cellular structures, its metabolic processes, and even the molecular structures of its intrinsic membrane proteins responsible for transporting water, nutrient, and waste molecules across the parasite plasma membrane (PPM). I hypothesize that Plasmodium falciparum has an Achilles' heel that can be attacked with erythritol, the well-known sweetener that is classified as generally safe. Most organisms have in their cell membrane two types of water-channel proteins: aquaporins to maintain hydro-homeostasis across the membrane and aquaglyceroporins to uptake glycerols etc. In contrast, P. falciparum has only one type of such proteins---the multi-functional aquaglyceroporin (PfAQP) expressed in the PPM---to do both jobs. Moreover, the parasite also uses PfAQP to excrete its metabolic wastes (ammonia included) produced at a very high rate in the blood stage. This extremely high efficiency of the bug using one protein for multiple essential tasks makes the parasite fatally vulnerable. Erythritol in the blood stream can kill the parasite by clogging up its PfAQP channel that needs to be open for maintaining hydro-homeostasis and for excreting toxic wastes across the bug's PPM. In vitro tests are to measure the growth/death rate of P. falciparum in blood with various erythritol concentrations. In vivo experiments are to administer groups of infected mice with various doses of erythritol and monitor the parasite growth levels from blood samples drawn from each group. Clinic trials can be performed to observe the added effects of administering to patients erythritol along with the known drugs because erythritol was classified as a safe food ingredient.

  1. Use of the Charlson Combined Comorbidity Index To Predict Postradiotherapy Quality of Life for Prostate Cancer Patients

    SciTech Connect (OSTI)

    Wahlgren, Thomas; Levitt, Seymour; Kowalski, Jan; Nilsson, Sten; Brandberg, Yvonne

    2011-11-15

    Purpose: To determine the impact of pretreatment comorbidity on late health-related quality of life (HRQoL) scores after patients have undergone combined radiotherapy for prostate cancer, including high-dose rate brachytherapy boost and hormonal deprivation therapy. Methods and Materials: Results from the European Organization for Research and Treatment of Cancer QLQ-C30 questionnaire survey of 158 patients 5 years or more after completion of therapy were used from consecutively accrued subjects treated with curative radiotherapy at our institution, with no signs of disease at the time of questionnaire completion. HRQoL scores were compared with the Charlson combined comorbidity index (CCI), using analysis of covariance and multivariate regression models together with pretreatment factors including tumor stage, tumor grade, pretreatment prostate-specific antigen level, neoadjuvant hormonal treatment, diabetes status, cardiovascular status, and age and Charlson score as separate variables or the composite CCI. Results: An inverse correlation between the two HRQoL domains, long-term global health (QL) and physical function (PF) scores, and the CCI score was observed, indicating an impact of comorbidity in these function areas. Selected pretreatment factors poorly explained the variation in functional HRQoL in the multivariate models; however, a statistically significant impact was found for the CCI (with QL and PF scores) and the presence of diabetes (with QL and emotional function). Cognitive function and social function were not statistically significantly predicted by any of the pretreatment factors. Conclusions: The CCI proved to be valid in this context, but it seems useful mainly in predicting long-term QL and PF scores. Of the other variables investigated, diabetes had more impact than cardiovascular morbidity on HRQoL outcomes in prostate cancer.

  2. The importance of ion size and electrode curvature on electrical double layers in ionic liquids

    SciTech Connect (OSTI)

    Feng, G.; Qiao, R.; Huang, J; Dai, S.; Sumpter, B. G.; Meunier, V.

    2011-01-01

    Room-temperature ionic liquids (ILs) are an emerging class of electrolytes for supercapacitors. We investigate the effects of ion size and electrode curvature on the electrical double layers (EDLs) in two ILs 1-butyl-3-methylimidazolium chloride [BMIM][Cl] and 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF{sub 6}], using a combination of molecular dynamics (MD) and quantum density functional theory (DFT) simulations. The sizes of the counter-ion and co-ion affect the ion distribution and orientational structure of EDLs. The EDL capacitances near both planar and cylindrical electrodes were found to follow the order: [BMIM][Cl] (near the positive electrode) > [BMIM][PF{sub 6}] (near the positive electrode) ? [BMIM][Cl] (near the negative electrode) ? [BMIM][PF{sub 6}] (near the negative electrode). The EDL capacitance was also found to increase as the electrode curvature increases. These capacitance data can be fit to the Helmholtz model and the recently proposed exohedral electrical double-cylinder capacitor (xEDCC) model when the EDL thickness is properly parameterized, even though key features of the EDLs in ILs are not accounted for in these models. To remedy the shortcomings of existing models, we propose a “Multiple Ion Layers with Overscreening” (MILO) model for the EDLs in ILs that takes into account two critical features of such EDLs, i.e., alternating layering of counter-ions and co-ions and charge overscreening. The capacitance computed from the MILO model agrees well with the MD prediction. Although some input parameters of the MILO model must be obtained from MD simulations, the MILO model may provide a new framework for understanding many important aspects of EDLs in ILs (e.g., the variation of EDL capacitance with the electrode potential) that are difficult to interpret using classical EDL models and experiments.

  3. The Importance of Ion Size and Electrode Curvature on Electrical Double Layers in Ionic Liquids

    SciTech Connect (OSTI)

    Feng, Guang; Qiao, Rui; Huang, Jingsong; Dai, Sheng; Sumpter, Bobby G; Meunier, Vincent

    2010-01-01

    Room-temperature ionic liquids (ILs) are an emerging class of electrolytes for supercapacitors. We investigate the effects of ion size and electrode curvature on the electrical double layers (EDLs) in two ILs 1-butyl-3-methylimidazolium chloride [BMIM][Cl] and 1-butyl-3-methylimidazolium hexafluorophosphate [BMIM][PF(6)], using a combination of molecular dynamics (MD) and quantum density functional theory (DFT) simulations. The sizes of the counter-ion and co-ion affect the ion distribution and orientational structure of EDLs. The EDL capacitances near both planar and cylindrical electrodes were found to follow the order: [BMIM][Cl] (near the positive electrode) > [BMIM][PF(6)] (near the positive electrode) {approx} [BMIM][Cl] (near the negative electrode) {approx} [BMIM][PF(6)] (near the negative electrode). The EDL capacitance was also found to increase as the electrode curvature increases. These capacitance data can be fit to the Helmholtz model and the recently proposed exohedral electrical double-cylinder capacitor (xEDCC) model when the EDL thickness is properly parameterized, even though key features of the EDLs in ILs are not accounted for in these models. To remedy the shortcomings of existing models, we propose a 'Multiple Ion Layers with Overscreening' (MILO) model for the EDLs in ILs that takes into account two critical features of such EDLs, i.e., alternating layering of counter-ions and co-ions and charge overscreening. The capacitance computed from the MILO model agrees well with the MD prediction. Although some input parameters of the MILO model must be obtained from MD simulations, the MILO model may provide a new framework for understanding many important aspects of EDLs in ILs (e.g., the variation of EDL capacitance with the electrode potential) that are difficult to interpret using classical EDL models and experiments.

  4. Modelling of the internal dynamics and density in a tens of joules plasma focus device

    SciTech Connect (OSTI)

    Marquez, Ariel; Gonzalez, Jose; Tarifeno-Saldivia, Ariel; Pavez, Cristian; Soto, Leopoldo; Clausse, Alejandro

    2012-01-15

    Using MHD theory, coupled differential equations were generated using a lumped parameter model to describe the internal behaviour of the pinch compression phase in plasma focus discharges. In order to provide these equations with appropriate initial conditions, the modelling of previous phases was included by describing the plasma sheath as planar shockwaves. The equations were solved numerically, and the results were contrasted against experimental measurements performed on the device PF-50J. The model is able to predict satisfactorily the timing and the radial electron density profile at the maximum compression.

  5. The project design flood and spillway for the Arroyo Seco Reservoir near San Antonio, Texas 

    E-Print Network [OSTI]

    Gilbreth, Joe Clyde

    1961-01-01

    THE PROJECT DESIGN FLOOD AND SPILLWAY FOR THE ARROYO SECO RESERVOIR SAN ANTONIO, TEXAS A Thesis By Joe Clyde Gilbreth Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in Partial fulfillment... of the requirements for the degree of CIVIL ENGINEER ~ll 1961 Major Sub)ect: @r~drolo Pf THE PROJECT DESIGN FLOOD AND SPILLWAY FOR THE ARROYO SECO RESERVOIR NEI! R SAN ANTONIO& TEXAS A Thesis By Joe Clyde Gilbreth Approved as to style and content by...

  6. The Power of Space: The Acropolis, the Theatre of Dionysos, and Tragedy in the 5th Century BCE

    E-Print Network [OSTI]

    Bondari, Katrina

    2011-05-19

    ssssc?s?wct??c? HE POWRFWSAC:FLIW,D::N:IWAC:WSNDEYEGRLWLARGGWLRALWP5EU:WAC:WNRAOIWRALWDBRFLW PDARLARNPGGOWGRAWPAWFRoCAWAEWpBGGOW RLYGPOWRALWyOLA:DOWPF WyPoFRpRN:FN:WriGPA:WTghWSFOEF:W tPG2RFoWACDEBoCWAC:WSNDEYEGRLWNEyYG:0W BDRFoWAC:W POWNPFWp...::GWAC:WLAD:FoACWPF W YEt:DWEpWAC:WPFNR:FAWLENR:AOWACPAWNEFLADBNA: WLBNCWoGEDREBLWyEFBy:FALhW1EE2RFo FEDACWpDEyWAC:WYD:NRYRN:WEpWAC:WSNDEYEGRLWEF:WCPLWPWUR:tWEpWAC:WPFNR:FAWKEyPFWpEDByW PF W,D::2Wpolip IWPLWt:GGWPLWAC:WAEBDRLAOWD:LAPBDPFALIWNPp:LIWPF WLEBU...

  7. Electronic computer utilization by small business 

    E-Print Network [OSTI]

    Calvert, Gerald Stephen

    1962-01-01

    to 1956, . 71 Bnyioyment by Sire of PXnn: Pirst Quarter, lg45 to E 956 ~ ~ ~ ~ ~ ~ ~ t ~ a w ~ e ~ ~ ~ ~ ~ ~ ~ ~ Taxable Wages by S&e of Pf, xn; Pkrst Quarter, i/45 1956 ~ ~ i ~ a ~ ~ ~ ~ ~ r ~ e e ~ a ~ Industrial. and Qommerc1al Failures, @saber 5...'ade Journals. Tt will hereafter be so desiIpaated in this study. Mature oz ~he Study. Xn the eaux*as of the research involved in this thesis, a study was made to determine if small business in general was op is in 8 zet1 eat ~ This research is des igllgd...

  8. Mechanical Properties and Radiation Tolerance of Metallic Multilayers 

    E-Print Network [OSTI]

    Li, Nan

    2011-08-08

    across the interface between lattice A and lattice B beginning at point S. Vector p f is an arbitrary interface vector from the origin O terminating at S. (b) The Burgers circuit in (a) constructed in a coherent reference lattice. If lattice A... is obtained from the reference lattice through a homogeneous deformation FA and lattice B is similarly constructed using FB, then the Burgers circuit has the closure failure 1 1( A B )B F F? ?= ?f pf , dashed arrow [15, 18]. ...................... 12 xii...

  9. Evaluation of the SEI using a multilayer spectroscopic ellipsometry model

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dufek, Eric J.

    2014-08-28

    A multilayer spectroscopic ellipsometry (SE) model has been developed to characterize SEI formation. The model, which consists of two Cauchy layers, is constructed with an inner layer meant to model primarily inorganic compounds adjacent to an electrode and an outer layer which mirrors polymeric, organic constituents on the exterior of the SEI. Comparison of 1:1 EC:EMC and 1:4 EC:EMC with 1.0 M LiPF? shows distinct differences in the two modeled layers. The data suggest that the thickness of both layers change over a wide potential range. These changes have been linked with other reports on the growth of the SEI.

  10. Spectroscopy of {sup 52,53}Sc

    SciTech Connect (OSTI)

    Bhattacharyya, S.; Rejmund, M.; Navin, A.; Gelin, M.; Mittig, W.; Mukherjee, G.; Rejmund, F.; Roussel-Chomaz, P.; Poves, A.; Theisen, Ch.

    2009-01-15

    Excited states of neutron-rich odd-A and odd-odd Sc isotopes, populated in deep inelastic multinucleon transfer reactions, induced by a {sup 238}U beam on a thin {sup 48}Ca target, have been identified. A strong feeding of both yrast and nonyrast states in such a reaction is illustrated using a combination of a large efficiency spectrometer and a {gamma} detector array. The structure of the populated states is interpreted in terms of the role of the valence proton and neutrons and compared to shell model calculations in the full pf shell.

  11. PFT: a Protocol For evaluating video Trackers The mean () and standard deviation () of AUC scores obtained for the trackers on

    E-Print Network [OSTI]

    Cavallaro, Andrea

    .483 (0.0794) 0.555 (0.0272) 0.686 (0.1061) 0.500 (0.0723) #12;Trial 2 (Size perturbation) Tracker Reference H1 µ() H2 µ() H3 µ() H4 µ() PF pdf 0.463 (0.0532) 0.698 (0.1311) 0.593 (0.0555) 0.814 (0.0716) MS.0781) 0.820 (0.0430) 0.770 (0.1232) 0.555 (0.0818) Hybrid pdf 0.506 (0.0759) 0.586 (0.0530) 0.741 (0

  12. Factored Language Models and Generalized Parallel Backoff Jeff A. Bilmes Katrin Kirchhoff

    E-Print Network [OSTI]

    Washington at Seattle, University of

    model, a word is viewed as a vec- tor of k factors, so that wt {f1 t , f2 t , . . . , fK t }. Fac- tors. An FLM is a model over factors, i.e., p(f1:K t |f1:K t-1:t-n), that can be factored as a product of probabilities of the form p(f|f1, f2, . . . , fN ). Our task is twofold: 1) find an appropriate set of factors

  13. Role of nucleonic Fermi surface depletion in neutron star cooling

    E-Print Network [OSTI]

    Dong, J M; Zhang, H F; Zuo, W

    2015-01-01

    The Fermi surface depletion of beta-stable nuclear matter is calculated to study its effects on several physical properties which determine the neutron star thermal evolution. The neutron and proton Z factors measuring the corresponding Fermi surface depletions, are calculated within the Brueckner-Hartree-Fock approach employing the AV18 two-body force supplemented by a microscopic three body force. Neutrino emissivity, heat capacity and, in particular, neutron 3PF2 superfluidity turn out to be reduced, especially at high baryonic density, to such an extent that the cooling rates of young neutron stars are significantly slowed

  14. Role of nucleonic Fermi surface depletion in neutron star cooling

    E-Print Network [OSTI]

    J. M. Dong; U. Lombardo; H. F. Zhang; W. Zuo

    2015-12-09

    The Fermi surface depletion of beta-stable nuclear matter is calculated to study its effects on several physical properties which determine the neutron star thermal evolution. The neutron and proton Z factors measuring the corresponding Fermi surface depletions, are calculated within the Brueckner-Hartree-Fock approach employing the AV18 two-body force supplemented by a microscopic three body force. Neutrino emissivity, heat capacity and, in particular, neutron 3PF2 superfluidity turn out to be reduced, especially at high baryonic density, to such an extent that the cooling rates of young neutron stars are significantly slowed

  15. FYI: July 7, 1983 - December 29, 1983

    E-Print Network [OSTI]

    1983-01-01

    \\itinr: pOSition, a n:! }re might be in a bett er position li we were to look for s oneone with experience in affirm2.tive action anri other personnel procedltr8s . There }HlS a lJriPf dicctws i on l:.bout the pr oblems of ap'lointinG fr om within... The position of Photographic Archivist (Research Assistant Appointment) with the Kansas Collection was advertised in the 6/23/83 FYI as a 10-month appointment with possible 2-month extension (funding anticipated September 1, 1983). The vacancy notice has...

  16. Energy Efficient Computing with the Low Power, Energy Aware Processing (LEAP) Architecture

    E-Print Network [OSTI]

    McIntire, Dustin Hale

    2012-01-01

    TMS TRST TDI A1 A16 F6 F11 G7 G8 G9 G10 H7 H8 H9 H10 J7 J822pF R52 100K A1 A16 F6 F11 G7 G8 G9 G10 H7 H8 H9 H10 J7 J8A11 A12 SDRAM_BA0 JP2 MA_23 G8 G9 F7 F3 G1 G2 G3 H1 H2 J3 G7

  17. Subjects: Trematoda and Trematode Diseases, Part 7: Supergenera and Genera R-S 

    E-Print Network [OSTI]

    Farr, Marion M.; Breen, Virginia L.; Doss, Mildred A.; Roach, Katharine F.

    1968-01-01

    . 21, 1907).? Dollfus,R. P.F. ,[1937c], 399,400,418.- Froissant, A. , 1930a, 11, 37.? Fuhrmann, ?. , 1928b, 19, 29.-Guberlet, J.E., 1933a, 324,325, 326-327(Polystomatidae, Oncho- cotylinae); 1937a, 466. ?Lameere, A. A. L. G. , 1933a, 245.... --Monticelli,F.S., 1903c, 336 (Onchocotylidae, Onchocotylinae). -- Palombi, ?., 1949b, 317-3 18(syn. :Oncho- cotyle Diesing, 1850 p. p. ). --Poche, F. , 1926b, 110 (Polystomatidae). - -Price, E. W., 1942a, 51(Hexabothriiidae, Rajoncho- cotylinae...

  18. The Compelling Case for Indentation as a Functional Exploratory and Characterization Tool

    E-Print Network [OSTI]

    Marshall, David B.; Cook, Robert F.; Padture, Nitin P.; Oyen, Michelle L.; Pajares, Antonia; Bradby, Jodie E.; Reimanis, Ivar E.; Tandon, Rajan; Page, Trevor F.; Pharr, George M.; Lawn, Brian R.

    2015-06-18

    Matrix-Fiber Frictional Stresses in Ceramic Composites," J. Amer. Ceram. Soc., 67[12] C259-60 (1984). 24 56. P.F. Becher, E.Y. Sun, C.H. Hseuh, K.B. Alexander, S.L. Waters and C.G. Westmoreland, "Debonding of Interfaces Between Beta-Silicon Nitride... in Cyclic Microindentations," J. Mater. Res., 18[4] 758-61 (2003). 31. P.E.D. Morgan and D.B. Marshall, "Ceramic Composites of Monazite and Alumina," J. Amer. Ceram. Soc., 78[11] 1553-63 (1995). 32. I.E. Reimanis, C. Seick, K. Fitspatrick, E.R. Fuller and S...

  19. 6. Fluid mechanics: fluid statics; fluid dynamics

    E-Print Network [OSTI]

    Zevenhoven, Ron

    to the atmosphere at patm For the Figure, with gravity g and densities g and l for gas and liquid: pC = g·h1·g + pB pD = l·h2·g + pC = l·h2·g + g·h1·g + pB and also, from the other side pD = l·(h3+h2)·g + pF = l·(h3°C after Torricelli: 1 torr = 1 mm Hg pressure 1 atm = 760 torr at 0°C A device for measuring

  20. Cost-Effective Energy Efficiency Measures for Above Code (ASHRAE 90.1-2001 and 2007) Small Office Buildings in the City of Arlington 

    E-Print Network [OSTI]

    2011-01-01

    Efficiency FEDERAL MINIMUM EFFICIENCY STANDARDS Heating System Efficiency (%) ASHRAE 90.1-2001 Table 6.2.1E and ASHRAE 90.1-2007 Table 6.8.1E Gas-fired furnace Capacity Capacity (Btu/hr) Heating Capacity (Btu/hr) Economizer ASHRAE... 40 kW Photovoltaic Array 0.5 PF Window Shading (None to 2.5 ft. Overhang for S/E/W) Tankless Gas Water Heater Decreased Glazing U-Value (ASHRAE 90.1-2001: from 1.22 to 0.35; and ASHRAE 90.1-2007: from 0.65 to 0.35) High Albedo Roof for ASHRAE 90...

  1. Evaluation of the SEI using a multilayer spectroscopic ellipsometry model

    SciTech Connect (OSTI)

    Eric J. Dufek

    2014-08-01

    A multilayer spectroscopic ellipsometry (SE) model has been developed to characterize SEI formation. The model, which consists of two Cauchy layers, is constructed with an inner layer meant to model primarily inorganic compounds adjacent to an electrode and an outer layer which mirrors polymeric, organic constituents on the exterior of the SEI. Comparison of 1:1 EC:EMC and 1:4 EC:EMC with 1.0 M LiPF6 shows distinct differences in the two modeled layers. The data suggest that the thickness of both layers change over a wide potential range. These changes have been linked with other reports on the growth of the SEI.

  2. Thermophysical property predictions of propane, propylene and their mixtures by Benedict-Webb-Rubin type equations of state 

    E-Print Network [OSTI]

    Bengani, Pramod Kumar

    1990-01-01

    equation (1989): ln[ j = ? (Ar+ Br ' + Cr ? 'Dr ) [P (Pf'agner)i 1 i 5 3 J r, where T, : ? T/T& and r: ? 1 ? T, . The values of the constants obtained are, A = -6. 61637520 B = 1. 16175821 C = -1. /4473360 D = ? 1. 95674512 Values of the critical... by PRAMOD KI)MAR BENGANI Approved as to style and content by: P. T. Eubank (Chair of Comrnjttee) J. C. Holste (Member) Alan Let on (Member) R. W. Flu erfelt (Head of Department) December 1990 nl ABSTRACT Thermophysical Property Predictions...

  3. The CCR5 chemokine receptor mediates vasoconstriction and stimulates intimal hyperplasia in human vessels in vitro

    E-Print Network [OSTI]

    Maguire, Janet J.; Jones, Katie L.; Kuc, Rhoda E.; Clarke, Murray C. H.; Bennett, Martin R.; Davenport, Anthony P.

    2013-12-09

    CCR5 antagonist PF-232796.25 For dilator studies, the vein was pre-constricted with 10 nmol/L of ET-1 and CCL4 (10 pmol/L–100 nmol/L) was added cumulatively. Data were analysed using a four parameter logistic equation (GraphPad Prism 5) to give values... to determine chemokine concentrations in vein culture supernatant. 2.5 Reverse transcription polymerase chain reaction assays RNA was extracted and reverse transcribed from human tissues. PCR was carried out using primers specific for Gsa, CCR5,29 CCL3, CCL4...

  4. Distributively generated near rings on the dihedral group of order eight 

    E-Print Network [OSTI]

    Willhite, Mary Lynn

    1970-01-01

    (~ ~@mbezeb Decemh. -. 1970 ABSTRACT Distributively Gene' ated Near Rings on the Dihedral Group of Order Eight. (December 1)70) Mary lynn Willhite, B. A. , Texas Christian University; Directed by: Dr. J. J. Malone, Jr. In this thesis, observations... OF TABLES TABLE 1 . THE DIHEDRAL GROUP D 2. THE ENDONORPHTSNS OF D Page 9 10 POSSIBLE KJLTIPLICATIONS FOR P=~ O, bi. . . 1$ 4-. POSSIBLE IIULTIPLICATIONS FOR P={ 0, 2a] . . . 18 5. AS OCIATIUE KH TIPLICATIONS FOR P=f0, 2a, b, 2a+b...

  5. old.new.factsheets.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26thI D- 6 0 4 2 r m m m m port m fm f m T mRLUOBCMRLos5 PF-4

  6. Investigation of injury/illness data at a nuclear facility: Part II

    SciTech Connect (OSTI)

    Cournoyer, Michael E.; Garcia, Vincent E.; Sandoval, Arnold N.; George, Gerald L.; Gubernatis, David C.; Schreiber, Stephen B.

    2014-11-21

    At Los Alamos National Laboratory (LANL), there are several nuclear facilities, accelerator facilities, radiological facilities, explosives sites, moderate- and high-hazard non-nuclear facilities, biosciences laboratory, etc. The Plutonium Science and Manufacturing Directorate (ADPSM) provides special nuclear material research, process development, technology demonstration, and manufacturing capabilities. ADPSM manages the LANL Plutonium Facility. Within the Radiological Control Area at TA-55 (PF-4), chemical and metallurgical operations with plutonium and other hazardous materials are performed. LANL Health and Safety Programs investigate injury and illness data. In this study, statistically significant trends have been identified and compared for LANL, ADPSM, and PF-4 injury/illness cases. A previously described output metric is used to measures LANL management progress towards meeting its operational safety objectives and goals. Timelines are used to determine trends in Injury/Illness types. Pareto Charts are used to prioritize causal factors. The data generated from analysis of Injury/Illness data have helped identify and reduce the number of corresponding causal factors.

  7. Use of bark-derived pyrolysis oils ass a phenol substitute in structural panel adhesives

    SciTech Connect (OSTI)

    Louisiana Pacific Corp

    2004-03-01

    The main objective of this program was to pilot the world's first commercial-scale production of an acceptable phenol formaldehyde (PF) resin containing natural resin (NR) ingredients, for use as an adhesive in Oriented-Strand Board (OSB) and plywood panel products. Natural Resin products, specifically MNRP are not lignin ''fillers''. They are chemically active, natural phenolics that effectively displace significant amounts of phenol in PF resins, and which are extracted from bark-derived and wood-derived bio-oils. Other objectives included the enhancement of the economics of NR (MNRP) production by optimizing the production of certain Rapid Thermal Processing (RTP{trademark}) byproducts, particularly char and activated carbon. The options were to activate the char for use in waste-water and/or stack gas purification. The preliminary results indicate that RTP{trademark} carbon may ultimately serve as a feedstock for activated carbon synthesis, as a fuel to be used within the wood product mill, or a fuel for an electrical power generating facility. Incorporation of the char as an industrial heat source for use in mill operations was L-P's initial intention for the carbon, and was also of interest to Weyerhaeuser as they stepped into in the project.

  8. Transmission resonance spectroscopy in the third minimum of 232Pa

    E-Print Network [OSTI]

    L. Csige; M. Csatlos; T. Faestermann; J. Gulyas; D. Habs; R. Hertenberger; M. Hunyadi; A. Krasznahorkay; H. J. Maier; P. G. Thirolf; H. -F. Wirth

    2012-04-04

    The fission probability of 232Pa was measured as a function of the excitation energy in order to search for hyperdeformed (HD) transmission resonances using the (d,pf) transfer reaction on a radioactive 231Pa target. The experiment was performed at the Tandem accelerator of the Maier-Leibnitz Laboratory (MLL) at Garching using the 231Pa(d,pf) reaction at a bombarding energy of E=12 MeV and with an energy resolution of dE=5.5 keV. Two groups of transmission resonances have been observed at excitation energies of E=5.7 and 5.9 MeV. The fine structure of the resonance group at E=5.7 MeV could be interpreted as overlapping rotational bands with a rotational parameter characteristic to a HD nuclear shape. The fission barrier parameters of 232Pa have been determined by fitting TALYS 1.2 nuclear reaction code calculations to the overall structure of the fission probability. From the average level spacing of the J=4 states, the excitation energy of the ground state of the 3rd minimum has been deduced to be E(III)=5.05 MeV.

  9. Transport of triplet excitons along continuous 100 nm polyfluorene chains

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xi, Liang; Bird, Matthew; Mauro, Gina; Asaoka, Sadayuki; Cook, Andrew R.; Chen, Hung -Cheng; Miller, John R.

    2014-12-03

    Triplet excitons created in poly-2,7-(9,9-dihexyl)fluorene (pF) chains with end trap groups in solution are efficiently transported to and captured by the end groups. The triplets explore the entire lengths of the chains, even for ~100 nm long chains enabling determination of the completeness of end capping. The results show that the chains continuous: they may contain transient barriers or traps, such as those from fluctuations of dihedral angles, but are free of major defects that stop motion of the triplets. Quantitative determinations are aided by the addition of a strong electron donor, TMPD, which removes absorption bands of the end-trappedmore »triplets. For chains having at least one end trap, triplet capture is quantitative on the 1 µs timescale imposed by the use of the donor. Fractions of chains having no end traps were 0.15 for pF samples with anthraquinone (AQ) end traps and 0.063 with naphthylimide (NI) end traps. These determinations agreed with measurements by NMR for short (« less

  10. gamma-ray spectroscopy of neutron-rich {sup 40}S

    SciTech Connect (OSTI)

    Wang, Z. M.; Chapman, R.; Liang, X.; Burns, M.; Hodsdon, A.; Keyes, K.; Kumar, V.; Papenberg, A.; Smith, J. F.; Spohr, K. M.; Haas, F.; Caurier, E.; Curien, D.; Nowacki, F.; Azaiez, F.; Ibrahim, F.; Verney, D.; Behera, B. R.; Corradi, L.; Fioretto, E.

    2010-05-15

    Yrast states up to (6{sup +}) in the neutron-rich {sup 40}S nucleus have been studied using binary grazing reactions produced by the interaction of a 215 MeV beam of {sup 36}S ions with a thin {sup 208}Pb target. The novel experimental setup that combines the large acceptance magnetic spectrometer, PRISMA, and the high-efficiency gamma-ray detection array, CLARA, was used. A new gamma-ray transition at an energy of 1572 keV was observed and tentatively assigned to the (6{sup +})->(4{sup +}) transition. A comparison of experimental observations and the results of large-scale 0(Planck constant/2pi)omega sd-pf shell-model calculations indicates that one- and two-proton excitations from the 2s{sub 1/2} to the 1d{sub 3/2} orbitals play an important role in reproducing the {sup 40}S yrast level structure and the published B(E2;0{sub g.s.}{sup +}->2{sub 1}{sup +}) value. The structure of the yrast states of the even-A isotopes of sulfur is interpreted in terms of the configurations of valence protons and neutrons within the context of large-scale 0(Planck constant/2pi)omega sd-pf shell-model calculations.

  11. Development of high energy density fuels from mild gasification of coal

    SciTech Connect (OSTI)

    Greene, Marvin

    1991-12-01

    METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily skimmed'' from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

  12. Development of high energy density fuels from mild gasification of coal. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-12-01

    METC has concluded that MCG technology has the potential to simultaneously satisfy the transportation and power generation fuel needs in the most cost-effective manner. MCG is based on low temperature pyrolysis, a technique known to the coal community for over a century. Most past pyrolysis developments were aimed at maximizing the liquids yield which results in a low quality tarry product requiring significant and capital intensive upgrading. By properly tailoring the pyrolysis severity to control the liquid yield-liquid quality relationship, it has been found that a higher quality distillate-boiling liquid can be readily ``skimmed`` from the coal. The resultant liquids have a much higher H/C ratio than conventional pyrolytic tars and therefore can be hydroprocessed at lower cost. These liquids are also extremely enriched in l-, 2-, and 3-ring aromatics. The co-product char material can be used in place of coal as a pulverized fuel (pf) for power generation in a coal combustor. In this situation where the original coal has a high sulfur content, the MCG process can be practiced with a coal-lime mixture and the calcium values retained on the char can tie up the unconverted coal sulfur upon pf combustion of the char. Lime has also been shown to improve the yield and quality of the MCG liquids.

  13. Electrochemical and impedance investigation of the effect of lithium malonate on the performance of natural graphite electrodes in lithium-ion batteries

    SciTech Connect (OSTI)

    Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL

    2010-01-01

    Lithium malonate (LM) was coated on the surface of a natural graphite (NG) electrode, which was then tested as the negative electrode in the electrolytes of 0.9 M LiPF6/EC-PC-DMC (1/1/3, by weight) and 1.0 M LiBF4/EC-PC-DMC (1/1/3, by weight) under a current density of 0.075 mA cm-2. LM was also used as an additive to the electrolyte of 1.0 M LiPF6/EC-DMC-DEC (1/1/1, by volume) and tested on a bare graphite electrode. It was found that both the surface coating and the additive approach were effective in improving first charge discharge capacity and coulomb efficiency. Electrochemical impedance spectra showed that the decreased interfacial impedance was coupled with improved coulomb efficiency of the cells using coated graphite electrodes. Cyclic voltammograms (CVs) on fresh bare and coated natural graphite electrodes confirmed that all the improvement in the half-cell performance was due to the suppression of the solvent decomposition through the surface modification with LM. The CV data also showed that the carbonate electrolyte with LM as the additive was not stable against oxidation, which resulted in lower capacity of the full cell with commercial graphite and LiCoO2 electrodes.

  14. Current sheath formation dynamics and structure for different insulator lengths of plasma focus device

    SciTech Connect (OSTI)

    Seng, Y. S.; Lee, P.; Rawat, R. S.

    2014-11-15

    The breakdown phase of the UNU-ICTP plasma focus (PF) device was successfully simulated using the electromagnetic particle in cell method. A clear uplift of the current sheath (CS) layer was observed near the insulator surface, accompanied with an exponential increase in the plasma density. Both phenomena were found to coincide with the surge in the electric current, which is indicative of voltage breakdown. Simulations performed on the device with different insulator lengths showed an increase in the fast ionization wave velocity with length. The voltage breakdown time was found to scale linearly with the insulator length. Different spatial profiles of the CS electron density, and the associated degree of uniformity, were found to vary with different insulator lengths. The ordering, according to the degree of uniformity, among insulator lengths of 19, 22, and 26?mm agreed with that in terms of soft X-ray radiation yield observed from experiments. This suggests a direct correlation between CS density homogeneity near breakdown and the radiation yield performance. These studies were performed with a linearly increasing voltage time profile as input to the PF device.

  15. Significant enhancement in thermoelectric properties of polycrystalline Pr-doped SrTiO{sub 3??} ceramics originating from nonuniform distribution of Pr dopants

    SciTech Connect (OSTI)

    Dehkordi, Arash Mehdizadeh; Bhattacharya, Sriparna; He, Jian; Alshareef, Husam N.; Tritt, Terry M.

    2014-05-12

    Recently, we have reported a significant enhancement (>70% at 500?°C) in the thermoelectric power factor (PF) of bulk polycrystalline Pr-doped SrTiO{sub 3} ceramics employing a novel synthesis strategy which led to the highest ever reported values of PF among doped polycrystalline SrTiO{sub 3}. It was found that the formation of Pr-rich grain boundary regions gives rise to an enhancement in carrier mobility. In this Letter, we investigate the electronic and thermal transport in Sr{sub 1?x}Pr{sub x}TiO{sub 3} ceramics in order to determine the optimum doping concentration and to evaluate the overall thermoelectric performance. Simultaneous enhancement in the thermoelectric power factor and reduction in thermal conductivity in these samples resulted in more than 30% improvement in the dimensionless thermoelectric figure of merit (ZT) for the whole temperature range over all previously reported maximum values. Maximum ZT value of 0.35 was obtained at 500?°C.

  16. Investigation of injury/illness data at a nuclear facility. Part II

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cournoyer, Michael E.; Garcia, Vincent E.; Sandoval, Arnold N.; George, Gerald L.; Gubernatis, David C.; Schreiber, Stephen B.

    2015-07-01

    At Los Alamos National Laboratory (LANL), there are several nuclear facilities, accelerator facilities, radiological facilities, explosives sites, moderate- and high-hazard non-nuclear facilities, biosciences laboratory, etc. The Plutonium Science and Manufacturing Directorate (ADPSM) provides special nuclear material research, process development, technology demonstration, and manufacturing capabilities. ADPSM manages the LANL Plutonium Facility. Within the Radiological Control Area at TA-55 (PF-4), chemical and metallurgical operations with plutonium and other hazardous materials are performed. LANL Health and Safety Programs investigate injury and illness data. In this study, statistically significant trends have been identified and compared for LANL, ADPSM, and PF-4 injury/illness cases. A previouslymore »described output metric is used to measures LANL management progress towards meeting its operational safety objectives and goals. Timelines are used to determine trends in Injury/Illness types. Pareto Charts are used to prioritize causal factors. The data generated from analysis of Injury/Illness data have helped identify and reduce the number of corresponding causal factors.« less

  17. Transport of Triplet Excitons along Continuous 100 nm Polyfluorene Chains

    SciTech Connect (OSTI)

    Xi, L.; Bird, M.; Mauro, G.; Asaoka, S.; Cook, A. R.; Chen, H. -C.; Miller, J. R

    2014-10-03

    Triplet excitons created in poly-2,7-(9,9-dihexyl)fluorene (pF) chains with end trap groups in solution are efficiently transported to and captured by the end groups. The triplets explore the entire lengths of the chains, even for ~100 nm long chains enabling determination of the completeness of end capping. The results show that the chains continuous: they may contain transient barriers or traps, such as those from fluctuations of dihedral angles, but are free of major defects that stop motion of the triplets. Quantitative determinations are aided by the addition of a strong electron donor, TMPD, which removes absorption bands of the end-trapped triplets. For chains having at least one end trap, triplet capture is quantitative on the 1 µs timescale imposed by the use of the donor. Fractions of chains having no end traps were 0.15 for pF samples with anthraquinone (AQ) end traps and 0.063 with naphthylimide (NI) end traps. These determinations agreed with measurements by NMR for short (<40 polymer repeat units (PRU)) chains, where NMR determinations are accurate. The results find no evidence for traps or barriers to transport of triplets, and places limits on the possible presence of defects as impenetrable barriers to less than one per 300 PRU. The present results present a paradigm different from the current consensus, derived from observations of singlet excitons, that conjugated chains are divided into “segments,” perhaps by some kind of defects. For the present pF chains, the segmentation either does not apply to triplet excitons or is transient so that the defects are healed or surmounted in times much shorter than 1 µs. Triplets on chains without end trap groups transfer to chains with end traps on a slower time scale. Rate constants for these bimolecular triplet transfer reactions were found to increase with the length of the accepting chain, as did rate constants for triplet transfer to the chains from small molecules like biphenyl. A second set of polyfluorenes with 2-butyloctyl side chains was found to have a much lower completeness of end capping

  18. Electrochemical performance and kinetics of Li{sub 1+x}(Co{sub 1/3}Ni{sub 1/3}Mn{sub 1/3}){sub 1-x}O{sub 2} cathodes and graphite anodes in low temperature electrolytes.

    SciTech Connect (OSTI)

    Smart, M. C.; Whitacre, J. F.; Ratnakumar, B. V.; Amine, K.; Chemical Engineering; Jet Propulsion Lab.

    2007-06-01

    Lithium-ion batteries have started replacing the conventional aqueous nickel-based battery systems in space applications, such as planetary landers, rovers, orbiters and satellites. The reasons for such widespread use of these batteries are the savings in mass and volume of the power subsystems, resulting from their high gravimetric and volumetric energy densities, and their ability to operate at extreme temperatures. In our pursuit to further enhance the specific energy as well as low-temperature performance of Li-ion batteries, we have been investigating various layered lithiated metal oxides, e.g., LiCoO{sub 2}, LiNi{sub 0.8}Co{sub 0.2} and LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2}, as well as different low-temperature electrolytes, including ternary and quaternary carbonate mixtures with various co-solvents. In this paper, we report our recent studies on Li{sub 1+x}(Co{sub 1/3}Ni{sub 1/3}Mn{sub 1/3}){sub 1-x}O{sub 2} cathodes, combined with three different low-temperature electrolytes, i.e.: (1) 1.0 M LiPF{sub 6} in EC:EMC (20:80), (2) 1.2 M LiPF{sub 6} in EC:EMC (20:80) and (3) 1.2 M LiPF{sub 6} in EC:EMC (30:70). Electrical performance characteristics were determined in laboratory glass cells at different discharge rates and different temperatures. Further, individual electrode kinetics of both Li{sub 1+x}(Co{sub 1/3}Ni{sub 1/3}Mn{sub 1/3}){sub 1-x}O{sub 2} cathodes and MCMB graphite anodes were determined at different temperatures, using dc micropolarization, Tafel polarization and electrochemical impedance spectroscopy (EIS). Analysis of these data has led to interesting trends relative to the effects of solvent composition and salt concentration, on the electrical performance and on the kinetics of cathode and anode.

  19. Characterization of a ballistic supermirror neutron guide

    E-Print Network [OSTI]

    H. Abele; D. Dubbers; H. Haese; M. Klein; A. Knoepfler; M. Kreuz; T. Lauer; B. Maerkisch; D. Mund; V. Nesvizhevsky; A. Petoukhov; C. Schmidt; M. Schumann; T. Soldner

    2005-10-26

    We describe the beam characteristics of the first ballistic supermirror neutron guide H113 that feeds the neutron user facility for particle physics PF1B of the Institute Laue-Langevin, Grenoble (ILL). At present, the neutron capture flux density of H113 at its 20x6cm2 exit window is 1.35x10^10/cm^2/s, and will soon be raised to above 2x10^10/cm^2/s. Beam divergence is no larger than beam divergence from a conventional Ni coated guide. A model is developed that permits rapid calculation of beam profiles and absolute event rates from such a beam. We propose a procedure that permits inter-comparability of the main features of beams emitted from ballistic or conventional neutron guides.

  20. An evaluation of the crossed box contribution to pion-nucleon scattering, using perturbation theory 

    E-Print Network [OSTI]

    Hale, Gerald Mallory

    1967-01-01

    ) '(W + TVi) 4l2 = (W ? TP)') (l1 ? Tt() 02 = WI AW2/(2 ~ -'iS) WRITE(6p3CO) S 300 FCRt&AT ( lH1//59X p3('S = F12 7) WRITE(6p350) 350 FQR(PAT(IHO//52Xp26HA(L)p B(L L = 1 3 A = O. OCOQQQQO 8 = 0 OCCCOOOQ RZ(20)pGZ(20) (25p5)pF 1(5)iF2... acceptable HI from the free fields of the interacting particles, (c) calculate the matrix elements of S using the model HI, and (d) compare with experiment. Writing a solution of (7) as 10 restricts U(t, t ) to satisfying (1) U(t~to ) ?1? and. (2) i ? U...

  1. The effect of tangential blowing on boundary-layer profiles 

    E-Print Network [OSTI]

    Olson, Milford Eugene

    1967-01-01

    . 2065 Blowing Rate Sys&ho 1 " hw (in. H20) Pf (p ~ s i) (Slot width-0. 033 inches) Cl C C 3. 1 7. 5 9. 7 14. 980 15. 5l 0 15. 820 534 534 534 . 2935 . 4670 . 5370 (Slot wi. dth-0. 0415 inches) Dl D2 D 5. 0 11. 5 15. 9 15. 040...; Blowing Rate Symbols B) B2 B 3 Cl C 2 C 3 D V (fps) J 163 246 2 75 163 246 275 163 Bjowing Rale (ft /sec) . 3 0. 0418 0. 0630 0. 0705 0. 1061 0. 1600 0. 1790 0. 1333 D D 3 246 275 0. 2013 0. 2250 A theory which expressed a...

  2. The computation of the orbit of an asteroid considering perturbations using a modified Gaussian technique 

    E-Print Network [OSTI]

    McKinney, John Carlton

    1967-01-01

    !, &? LQ['0, !~DURSL, Xf[INL, S, CL XLQNG=!IQ(JRSL?1. 6 +XNI !L/4 ~ +SEC! /240, X L 0 N G = X L l f f'I G P I / 1 [) 0 ~ RELUNG=RELQNG/240. Ki:LONG=RFLQNG?l'[/ IHO. AO= 4&2. 66/10. ??6 DQ 21 1=1, 3 READ (5, 1) 40!JRSG X!IING SECG Gl ST [ I ) =H... are the geocentric coordinates of the asteroid. For each of tho three observation times a space triangle exists P?(F3, n3, 43) 'P3 3 'I QSJ~J r (x2 2 '2) 2 2 2 R p2 2 2(XZ, 2, Z ) '3 '2 4' "I (~ g~z ) el yi(KI a I Figure 3. Three Observation Positions...

  3. Polymer filtration: A new technology for selective metals recovery

    SciTech Connect (OSTI)

    Smith, B.F.; Robison, T.W.; Cournoyer, M.E.; Wilson, K.V.; Sauer, N.N.; Mullen, K.I.; Lu, M.T.; Jarvinen, J.J.

    1995-04-01

    Polymer Filtration (PF) was evaluated for the recovery of electroplating metal ions (zinc and nickel) from rinse waters. Polymer Filtration combines the use of water-soluble metal-binding polymers and ultrafiltration to concentrate metal ions from dilute rinse water solutions. The metal ions are retained by the polymers; the smaller, unbound species freely pass through the ultrafiltration membrane. By using this process the ultrafiltered permeate more than meets EPA discharge limits. The metal ions are recovered from the concentrated polymer solution by pH adjustment using diafiltration and can be recycled to the original electroplating baths with no deleterious effects on the test panels. Metal-ion recovery is accomplished without producing sludge.

  4. Thin Flexible Lithium Ion Battery Featuring Graphite Paper Based Current Collectors with Enhanced Conductivity

    E-Print Network [OSTI]

    Qu, Hang; Tang, Yufeng; Semenikihin, Oleg; Skorobogatiy, Maksim

    2015-01-01

    A flexible, light weight and high conductivity current collector is the key element that enables fabrication of high performance flexible lithium ion battery. Here we report a thin, light weight and flexible lithium ion battery that uses graphite paper enhanced with a nano-sized metallic layers as the current collector, LiFePO4 and Li4Ti5O12 as the cathode and anode materials, and PE membrane soaked in LiPF6 as a separator. Using thin and flexible graphite paper as a substrate for the current collector instead of a rigid and heavy metal foil enables us to demonstrate a very thin Lithium-Ion Battery into ultra-thin (total thickness including encapsulation layers of less than 250 {\\mu}m) that is also light weight and highly flexible.

  5. Interfacing systems loss-of-coolant accident in Oconee-1 pressurized water reactor

    SciTech Connect (OSTI)

    Nassersharif, B.

    1984-01-01

    The primary system of a pressurized water reactor (PWR) operates at a relatively high pressure (15.5 MPa, 2250 psia) and consists of piping and components designed to withstand these pressures. The low-pressure-injection system (LPIS) connects to the primary system but possesses low-pressure piping passing outside the containment. Therefore, a potential exists for a loss-of-coolant accident (LOCA) outside the containment and concurrent damage to systems needed to cope with this problem. The emergency core-cooling system (ECCS) is assumed to be available for this event. A set of calculations were performed using the TRAC-PF1 code and a model of the Oconee-1 PWR to investigate the consequences of, and possible operator actions for, such an accident scenario.

  6. Current algorithms used in reactor safety codes and the impact of future computer development on these algorithms

    SciTech Connect (OSTI)

    Mahaffy, J.H.; Liles, D.R.; Woodruff, S.B.

    1985-01-01

    Computational methods and solution procedures used in the US Nuclear Regulatory Commission's reactor safety systems codes, Transient Reactor Analysis Code (TRAC) and Reactor Leak and Power Safety Excursion Code (RELAP), are reviewed. Methods used in TRAC-PF1/MOD1, including the stability-enhancing two-step (SETS) technique, which permits fast computations by allowing time steps larger than the material Courant stability limit, are described in detail, and the differences from RELAP5/MOD2 are noted. Developments in computing, including parallel and vector processing, and their applicability to nuclear reactor safety codes are described. These developments, coupled with appropriate numerical methods, make detailed faster-than-real-time reactor safety analysis a realistic near-term possibility.

  7. A linear dynamic analysis of stiffened shells of revolution by the matrix displacement method 

    E-Print Network [OSTI]

    Hoover, Charlie Doll

    1971-01-01

    , and dA is the time interval. For a rectangular-pulse load DLF is given as follows t DLF=1 ? cosmt=l ? cos 2r- T (1. 3) 12 for t & t DLF ~ cos m ( t t cos 2r (? T ) ? cos m t. d t t /T) ? cos 2s- d T (I 4) fo t td where T is the natural period... [&=E (ol+ot2s+a3 s +a4 s ) cos i 8 i=0 (2. 22) u = E 0 i=0 pi of (0 +'0 s) cos i 8 (2. 23) 0 v i=0 01 oi (n +0 s) sini8 (2. 24) also fd19 = J'pdv (2. 25) so that T = q pf(u + v + w ) dV o2 02 02 (2. 26) where p is the density...

  8. The ROSAT HRI Point Spread Function

    E-Print Network [OSTI]

    Peter Predehl; Almudena Prieto

    2001-09-28

    A sample of the brightest point-like sources observed with the ROSAT-HRI were analysed to asses on the intrinsic shape of the ROSAT-HRI Point Spread Function (PSF). Almost all of the HRI observations collected during the ROSAT lifetime are found to be artificially broadened by factors up two ~2 due to residual errors in the ROSAT aspect solution. After correction by departing pointing positions, the width of the core of the PSF is found to be less than 5 arcsec (half energy width, HEW). On the basis of these results, an improved analytical representation of the ROSAT-HRI PSF is provided. However, for most of the new observations the source countrate is too weak to allow reliable recovering pf the ROSAT-HRI resolution. Therefore, a series of examples (data, correction, and theoretical PSF) are given in order to help the ROSAT user in determining whether "his/her source" is extended or not.

  9. Re-appraisal and extension of the Gratton-Vargas two-dimensional analytical snowplow model of plasma focus evolution in the context of contemporary research

    SciTech Connect (OSTI)

    Auluck, S. K. H.

    2013-11-15

    Recent resurgence of interest in applications of dense plasma focus and doubts about the conventional view of dense plasma focus as a purely irrotational compressive flow have re-opened questions concerning device optimization. In this context, this paper re-appraises and extends the analytical snowplow model of plasma focus sheath evolution developed by F. Gratton and J. M. Vargas [Energy Storage, Compression and Switching, edited by V. Nardi, H. Sahlin, and W. H. Bostick (Plenum, New York, 1983), Vol. 2, p. 353)] and shows its relevance to contemporary research. The Gratton-Vargas (GV) model enables construction of a special orthogonal coordinate system in which the plasma flow problem can be simplified and a model of sheath structure can be formulated. The Lawrenceville Plasma Physics (LPP) plasma focus facility, which reports neutron yield better than global scaling law, is shown to be operating closer to an optimum operating point of the GV model as compared with PF-1000.

  10. Structural Interactions within Lithium Salt Solvates: Acyclic Carbonates and Esters

    SciTech Connect (OSTI)

    Afroz, Taliman; Seo, D. M.; Han, Sang D.; Boyle, Paul D.; Henderson, Wesley A.

    2015-03-06

    Solvate crystal structures serve as useful models for the molecular-level interactions within the diverse solvates present in liquid electrolytes. Although acyclic carbonate solvents are widely used for Li-ion battery electrolytes, only three solvate crystal structures with lithium salts are known for these and related solvents. The present work, therefore, reports six lithium salt solvate structures with dimethyl and diethyl carbonate: (DMC)2:LiPF6, (DMC)1:LiCF3SO3, (DMC)1/4:LiBF4, (DEC)2:LiClO4, (DEC)1:LiClO4 and (DEC)1:LiCF3SO3 and four with the structurally related methyl and ethyl acetate: (MA)2:LiClO4, (MA)1:LiBF4, (EA)1:LiClO4 and (EA)1:LiBF4.

  11. UF{sub 6} tiedowns for truck transport - right way/wrong way

    SciTech Connect (OSTI)

    Stout, F.W. Jr. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States)

    1991-12-31

    Tiedown systems for truck transport of UF{sub 6} must be defined and controlled to assure the least risk for hauling the material over the highways. This paper and an associated poster display will present the current status of regulatory criteria for tiedowns, analyze the structural stresses involved in tiedowns for two major UF{sub 6} packaging systems, the 21PF series of overpacks and the 48 in. diameter shipping cylinders, and will present photographs showing some {open_quote}right ways{close_quotes} and some {open_quotes}wrong (or risky) ways{close_quotes} currently used for tiedown systems. Risky tiedown methods must be replaced with safer less risky methods to insure the safe transport of UF{sub 6}.

  12. Influence of a Weak Field of Pulsed DC Electricity on the Behavior and Incidence of Injury in Adult Steelhead and Pacific Lamprey, Final Report.

    SciTech Connect (OSTI)

    Mesa, Matthew

    2009-02-13

    Predation by pinnipeds, such as California sea lions Zalophus californianus, Pacific harbor seals Phoca vitulina, and Stellar sea lions Eumetopias jubatus on adult Pacific salmon Oncorhynchus spp in the lower Columbia River has become a serious concern for fishery managers trying to conserve and restore runs of threatened and endangered fish. As a result, Smith-Root, Incorporated (SRI; Vancouver, Washington), manufacturers of electrofishing and closely-related equipment, proposed a project to evaluate the potential of an electrical barrier to deter marine mammals and reduce the amount of predation on adult salmonids (SRI 2007). The objectives of their work were to develop, deploy, and evaluate a passive, integrated sonar and electric barrier that would selectively inhibit the upstream movements of marine mammals and reduce predation, but would not injure pinnipeds or impact anadromous fish migrations. However, before such a device could be deployed in the field, concerns by regional fishery managers about the potential effects of such a device on the migratory behavior of Pacific salmon, steelhead O. mykiss, Pacific lampreys Entoshpenus tridentata, and white sturgeon Acipenser transmontanus, needed to be addressed. In this report, we describe the results of laboratory research designed to evaluate the effects of prototype electric barriers on adult steelhead and Pacific lampreys. The effects of electricity on fish have been widely studied and include injury or death (e.g., Sharber and Carothers 1988; Dwyer et al. 2001; Snyder 2003), physiological dysfunction (e.g., Schreck et al. 1976; Mesa and Schreck 1989), and altered behavior (Mesa and Schreck 1989). Much of this work was done to investigate the effects of electrofishing on fish in the wild. Because electrofishing operations would always use more severe electrical settings than those proposed for the pinniped barrier, results from these studies are probably not relevant to the work proposed by SRI. Field electrofishing operations typically use high voltage and amperage settings and a variety of waveforms, pulse widths (PW), and pulse frequencies (PF), depending on conditions and target species. For example, when backpack electrofishing for trout in a small stream, one might use settings such as 500 V pulsed DC, a PW of 1 ms, and a PF of 60 Hz. In contrast, the electrical barrier proposed by SRI will produce electrical conditions significantly lower than those used in electrofishing, particularly for PW and PF (e.g., PW ranging from 300-1,000 {micro}s and PF from 2-3 Hz). Further, voltage gradients (in V/cm) are predicted to be lower in the electric barrier than those produced during typical electrofishing. Although the relatively weak, pulsed DC electric fields to be produced by the barrier may be effective at deterring pinnipeds, little, if anything, is known about the effects of such low intensity electrical fields on fish behavior. For this research, we evaluated the effects of weak, pulsed DC electric currents on the behavior of adult steelhead and Pacific lamprey and the incidence of injury in steelhead only. In a series of laboratory experiments, we: (1) documented the rate of passage of fish over miniature, prototype electric barriers when they were on and off; (2) determined some electric thresholds beyond which fish would not pass over the barrier; and (3) assessed the incidence and severity of injury in steelhead exposed to relatively severe electrical conditions. The results of this study should be useful for making decisions about whether to install electrical barriers in the lower Columbia River, or elsewhere, to reduce predation on upstream migrating salmonids and other fishes by marine pinnipeds.

  13. Advanced Photovoltaic Inverter Functionality using 500 kW Power Hardware-in-Loop Complete System Laboratory Testing: Preprint

    SciTech Connect (OSTI)

    Mather, B. A.; Kromer, M. A.; Casey, L.

    2013-01-01

    With the increasing penetration of distribution connected photovoltaic (PV) systems, more and more PV developers and utilities are interested in easing future PV interconnection concerns by mitigating some of the impacts of PV integration using advanced PV inverter controls and functions. This paper describes the testing of a 500 kW PV inverter using Power Hardware-in-Loop (PHIL) testing techniques. The test setup is described and the results from testing the inverter in advanced functionality modes, not commonly used in currently interconnected PV systems, are presented. PV inverter operation under PHIL evaluation that emulated both the DC PV array connection and the AC distribution level grid connection are shown for constant power factor (PF) and constant reactive power (VAr) control modes. The evaluation of these modes was completed under varying degrees of modeled PV variability.

  14. Verification Of The Defense Waste Processing Facility's (DWPF) Process Digestion Methods For The Sludge Batch 8 Qualification Sample

    SciTech Connect (OSTI)

    Click, D. R.; Edwards, T. B.; Wiedenman, B. J.; Brown, L. W.

    2013-03-18

    This report contains the results and comparison of data generated from inductively coupled plasma – atomic emission spectroscopy (ICP-AES) analysis of Aqua Regia (AR), Sodium Peroxide/Sodium Hydroxide Fusion Dissolution (PF) and Cold Chem (CC) method digestions and Cold Vapor Atomic Absorption analysis of Hg digestions from the DWPF Hg digestion method of Sludge Batch 8 (SB8) Sludge Receipt and Adjustment Tank (SRAT) Receipt and SB8 SRAT Product samples. The SB8 SRAT Receipt and SB8 SRAT Product samples were prepared in the SRNL Shielded Cells, and the SRAT Receipt material is representative of the sludge that constitutes the SB8 Batch or qualification composition. This is the sludge in Tank 51 that is to be transferred into Tank 40, which will contain the heel of Sludge Batch 7b (SB7b), to form the SB8 Blend composition.

  15. Predicting the Voltage Dependence of Interfacial Electrochemical Processes at Lithium-Intercalated Graphite Edge Planes

    E-Print Network [OSTI]

    Leung, Kevin

    2015-01-01

    The applied potential governs lithium-intercalation and electrode passivation reactions in lithium ion batteries, but are challenging to calibrate in condensed phase DFT calculations. In this work, the "anode potential" of charge-neutral lithium-intercalated graphite (LiC(6)) with oxidized edge planes is computed as a function of Li-content n(Li)) at edge planes, using ab initio molecular dynamics (AIMD), a previously introduced Li+ transfer free energy method, and the experimental Li+/Li(s) value as reference. The voltage assignments are corroborated using explicit electron transfer from fluoroethylene carbonate radical anion markers. PF6- is shown to decompose electrochemically (i.e., not just thermally) at low potentials imposed by our voltage calibration technique. We demonstrate that excess electrons reside in localized states-in-the-gap in the organic carbonate liquid region, which is not semiconductor-like (band-state-like) as widely assumed in the literature.

  16. NMR studies of chiral P,S-chelate platinum, rhodium, and iridium complexes and the X-ray structure of a palladium(II) allyl derivative

    SciTech Connect (OSTI)

    Albinati, A. [Univ. of Milan (Italy)] [Univ. of Milan (Italy); Eckert, J. [Los Alamos National Lab., NM (United States)] [Los Alamos National Lab., NM (United States); Pregosin, P.; Ruegger, H.; Salzmann, R.; Stoessel, C. [ETH-Zentrum, Zuerich (Switzerland)] [ETH-Zentrum, Zuerich (Switzerland)

    1997-02-18

    Several Rh(I), Ir(III), and Pt(II) complexes of the chiral P,S-bidentate ligand 2 have been prepared and characterized. Detailed two-dimensional NMR studies show that (i) the boat-type chelate ring and the stereogenic sulfur center can invert rapidly at ambient temperature and (ii) the sulfur donor may dissociate, essentially destroying the chiral pocket. The solid-state structure of [Pt({eta}{sup 3}-C{sub 3}H{sub 5})(2)]PF{sub 6} (3) has been determined and the sulfur substituent shown to have an axial orientation. The six-membered chelate ring takes up a boat-like conformation. As shown by an X-ray diffraction study for 3, and via incoherent inelastic neutron scattering (IINS) measurements for the Pd analog, 4, the OH group is remote from the metal atom. 42 refs., 11 figs., 6 tabs.

  17. Advanced density matrix renormalization group method for nuclear structure calculations

    E-Print Network [OSTI]

    Legeza, Ö; Poves, A; Dukelsky, J

    2015-01-01

    We present an efficient implementation of the Density Matrix Renormalization Group (DMRG) algorithm that includes an optimal ordering of the proton and neutron orbitals and an efficient expansion of the active space utilizing various concepts of quantum information theory. We first show how this new DMRG methodology could solve a previous $400$ KeV discrepancy in the ground state energy of $^{56}$Ni. We then report the first DMRG results in the $pf+g9/2$ shell model space for the ground $0^+$ and first $2^+$ states of $^{64}$Ge which are benchmarked with reference data obtained from Monte Carlo shell model. The corresponding correlation structure among the proton and neutron orbitals is determined in terms of the two-orbital mutual information. Based on such correlation graphs we propose several further algorithmic improvement possibilities that can be utilized in a new generation of tensor network based algorithms.

  18. On the explanation and calculation of anomalous reflood hydrodynamics in large PWR cores

    SciTech Connect (OSTI)

    Rodriguez, S.E.

    1985-01-01

    Reflood hydrodynamics from large-scale (1:20) test facilities in Japan have yielded apparently anomalous behavior relative to FLECHT tests. Namely, even at reflooding rates below one inch per second, very large liquid volume fractions (10-15%) exist above the quench fronts shortly after flood begins; thus cladding temperature excursions are terminated early in the reflood phase. This paper discusses an explanation for this behavior: liquid films on the core's unheated rods. The experimental findings are shown to be correctly simulated with a new four-field (vapor, films, droplets) version of the best-estimate TRAC-PF1 computer code, TRAC-FF. These experimental and analytical findings have important implications for PWR large-break LOCA licensing.

  19. Tagging the boll weevil (Anthonomus gradis Boh.) with P³² 

    E-Print Network [OSTI]

    Mayer, Marion Sidney

    1961-01-01

    of qptahs of PIL feil at ~ xate of 1D ac/al af a R5 Psx asst bags~ter so3utian by media?reaxed boll weeviis AMN6 ~l8 bacxe prior ta treatment ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 28 Bats af nptabs cf P3 f46 at a gate of 25 Qc/ml cl' a 25 per- cent bagmCjt~ter sot...N, at ~ sate af $. g re/a1 at d1atjllel. war ly yqasee-~ ba11 vaeriie starnkl 48 hood prior ta txeataeet. 1 4, 08a 2 6, 49' 6, 8~ 3 7, 639 8, 488 4, 8' 8, 048 8, 47k 11 041 12, 368 . 8 'able 4. Rate of uptake of P3 fe&l at a cate cf l. pf uc/ml cf a 10...

  20. Lithium ion battery with improved safety

    DOE Patents [OSTI]

    Chen, Chun-hua; Hyung, Yoo Eup; Vissers, Donald R.; Amine, Khalil

    2006-04-11

    A lithium battery with improved safety that utilizes one or more additives in the battery electrolyte solution wherein a lithium salt is dissolved in an organic solvent, which may contain propylene, carbonate. For example, a blend of 2 wt % triphenyl phosphate (TPP), 1 wt % diphenyl monobutyl phosphate (DMP) and 2 wt % vinyl ethylene carbonate additives has been found to significantly enhance the safety and performance of Li-ion batteries using a LiPF6 salt in EC/DEC electrolyte solvent. The invention relates to both the use of individual additives and to blends of additives such as that shown in the above example at concentrations of 1 to 4-wt % in the lithium battery electrolyte. This invention relates to additives that suppress gas evolution in the cell, passivate graphite electrode and protect it from exfoliating in the presence of propylene carbonate solvents in the electrolyte, and retard flames in the lithium batteries.

  1. Tunable wavelength soft photoionization of ionic liquid vapors

    SciTech Connect (OSTI)

    Strasser, Daniel; Goulay, Fabien; Belau, Leonid; Kostko, Oleg; Koh, Christine; Chambreau, Steven D.; Vaghjiani, Ghanshyam L.; Ahmed, Musahid; Leone, Stephen R.

    2009-11-11

    Combined data of photoelectron spectra and photoionization efficiency curves in the near threshold ionization region of isolated ion-pairs from [emim][Tf2N], [emim][Pf2N]and [dmpim][Tf2N]ionic liquid vapors reveal small shifts in the ionization energies of ion-pair systems due to cation and anion substitutions. Shifts towards higher binding energy following anion substitution are attributed to increased electronegativity of the anion itself, while shifts towards lower binding energies following cation substitution are attributed to an increase in the cation-anion distance that causes a lower Coulombic binding potential. The predominant ionization mechanism in the near threshold photon energy region is identified as dissociative ionization, involving dissociation of the ion-pair and the production of intact cations as the positively charged products.

  2. Neutron density distributions from antiprotonic 208Pb and 209Bi atoms

    E-Print Network [OSTI]

    B. Klos; A. Trzcinska; J. Jastrzebski; T. Czosnyka; M. Kisielinski; P. Lubinski; P. Napiorkowski; L. Pienkowski; F. J. Hartmann; B. Ketzer; P. Ring; R. Schmidt; T. von Egidy; R. Smolanczuk; S. Wycech; K. Gulda; W. Kurcewicz; E. Widmann; B. A. Brown

    2007-02-26

    The X-ray cascade from antiprotonic atoms was studied for 208Pb and 209Bi. Widths and shifts of the levels due to the strong interaction were determined. Using modern antiproton-nucleus optical potentials the neutron densities in the nuclear periphery were deduced. Assuming two parameter Fermi distributions (2pF) describing the proton and neutron densities the neutron rms radii were deduced for both nuclei. The difference of neutron and proton rms radii /\\r_np equal to 0.16 +-(0.02)_{stat} +- (0.04)_{syst} fm for 208Pb and 0.14 +- (0.04)_{stat} +- (0.04)_{syst} fm for 209Bi were determined and the assigned systematic errors are discussed. The /\\r_np values and the deduced shapes of the neutron distributions are compared with mean field model calculations.

  3. Shell model description of Gamow-Teller strengths for $^{42}$Ti, $^{46}$Cr, $^{50}$Fe and $^{54}$Ni

    E-Print Network [OSTI]

    Kumar, Vikas; Hirsch, Jorge G

    2015-01-01

    A systematic shell model description of the experimental Gamow-Teller transition strength distributions in $^{42}$Ti, $^{46}$Cr, $^{50}$Fe and $^{54}$Ni is presented. These transitions have been recently measured via $\\beta$ decay of these $T_z$=-1 nuclei, produced in fragmentation reactions at GSI and also with ($^3${He},$t$) charge-exchange (CE) reactions corresponding to $T_z = + 1$ to $T_z = 0$ carried out at RCNP-Osaka. The calculations are performed in the $pf$ model space, using the GXPF1a and KB3G effective interactions. Qualitative agreement is obtained for the individual transitions, while the calculated summed transition strengths closely reproduce the observed ones.

  4. Structural Interactions within Lithium Salt Solvates: Cyclic Carbonates and Esters

    SciTech Connect (OSTI)

    Seo, D. M.; Afroz, Taliman; Allen, Joshua L.; Boyle, Paul D.; Trulove, Paul C.; De Long, Hugh C.; Henderson, Wesley A.

    2014-11-13

    Only limited information is available regarding the manner in which cyclic carbonate and ester solvents coordinate Li+ cations in electrolyte solutions for lithium batteries. One approach to gleaning significant insight into these interactions is to examine crystalline solvate structures. To this end, eight new solvate structures are reported with ethylene carbonate, ?-butyrolactone and ?-valerolactone: (EC)3:LiClO4, (EC)2:LiClO4, (EC)2:LiBF4, (GBL)4:LiPF6, (GBL)1:LiClO4, (GVL)1:LiClO4, (GBL)1:LiBF4 and (GBL)1:LiCF3SO3. The crystal structure of (EC)1:LiCF3SO3 is also re-reported for comparison. These structures enable the factors which govern the manner in which the ions are coordinated and the ion/solvent packing—in the solid-state—to be scrutinized in detail.

  5. Remanent Creep Life Prediction in Low-Alloy Ferritic Steel Power Plant Components

    E-Print Network [OSTI]

    Wilson, Peter

    1991-03-19

    sources (coal, oil, the nuclear pile etc.) being used to heat the steam. The basic furnace and 4 boiler arrangement of steam turbine generating plant is the same regardless of the fuel source used. Water is supplied to the steam drum by feed pumps, usually... )Orr ,jf-'r----Rp-f, rbtsh heatPf ~.; W. Ir,' IlSP-:'1 ;lr",.1'Jl,ll"."",ICfY Replace PIpe. and hangers ttention lor p'ant 'ilee I-I-- Mt.ta" c1uslfiers and nroes ~ {1!f'rJ 'i fr' m Revl<'W demgn Rppl'K'e• so All preheaters If_!!] 1r:lprr,v@~nQ R··~~ ell :n...

  6. Mass Measurements Demonstrate a Strong N =28 Shell Gap in Argon

    E-Print Network [OSTI]

    Z. Meisel; S. George; S. Ahn; J. Browne; D. Bazin; B. A. Brown; J. F. Carpino; H. Chung; R. H. Cyburt; A. Estradé; M. Famiano; A. Gade; C. Langer; M. Matoš; W. Mittig; F. Montes; D. J. Morrissey; J. Pereira; H. Schatz; J. Schatz; M. Scott; D. Shapira; K. Smith; J. Stevens; W. Tan; O. Tarasov; S. Towers; K. Wimmer; J. R. Winkelbauer; J. Yurkon; R. G. T. Zegers

    2015-10-06

    We present results from recent time-of-flight nuclear mass measurements at the National Superconducting Cyclotron Laboratory at Michigan State University. We report the first mass measurements of 48Ar and 49Ar and find atomic mass excesses of -22.28(31) MeV and -17.8(1.1) MeV, respectively. These masses provide strong evidence for the closed shell nature of neutron number N=28 in argon, which is therefore the lowest even-Z element exhibiting the N=28 closed shell. The resulting trend in binding-energy differences, which probes the strength of the N=28 shell, compares favorably with shellmodel calculations in the sd-pf shell using SDPF-U and SDPF-MU Hamiltonians.

  7. Mixing of partial waves near B*B?* threshold in e?e? annihilation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Xin; Voloshin, M. B.

    2013-05-31

    We consider the production of B*B?* meson pairs in e?e? annihilation near the threshold. The rescattering due to pion exchange between the mesons results in a mixing between three partial wave amplitudes: two P-wave amplitudes with the total spin of the meson pair S=0 and S=2 and an F-wave amplitude. The mixing due to pion exchange with a low momentum transfer is calculable up to c.m. energy E?15–20 MeV above the threshold. We find that the P–F mixing is numerically quite small in this energy range, while the mixing of the two P-wave amplitudes is rapidly changing with energy andmore »can reach of order one at such low energies.« less

  8. Magnetic field distribution in the plasma flow generated by a plasma focus discharge

    SciTech Connect (OSTI)

    Mitrofanov, K. N.; Krauz, V. I. Myalton, V. V.; Velikhov, E. P.; Vinogradov, V. P.; Vinogradova, Yu. V.

    2014-11-15

    The magnetic field in the plasma jet propagating from the plasma pinch region along the axis of the chamber in a megajoule PF-3 plasma focus facility is studied. The dynamics of plasma with a trapped magnetic flow is analyzed. The spatial sizes of the plasma jet region in which the magnetic field concentrates are determined in the radial and axial directions. The magnetic field configuration in the plasma jet is investigated: the radial distribution of the azimuthal component of the magnetic field inside the jet is determined. It is shown that the magnetic induction vector at a given point in space can change its direction during the plasma flight. Conclusions regarding the symmetry of the plasma flow propagation relative to the chamber axis are drawn.

  9. Lithium difluoro(oxalato)borate as additive to Improve the thermal stability of llithiated graphite.

    SciTech Connect (OSTI)

    Chen, Z.; Qin, Y.; Liu, J.; Amine, K.; Chemical Sciences and Engineering Division

    2009-01-21

    The reaction of lithiated graphite with a nonaqueous electrolyte of 1.2 M LiPF{sub 6} in ethylene carbonate/ethyl methyl carbonate (3:7 by weight) was investigated using differential scanning calorimetry. The decomposition of the solid electrolyte interphase (SEI) took place at about 100 C and was followed by a continuous formation/decomposition of the SEI up to 250 C. Another two peaks were observed at temperatures above 250 C. These peaks were attributed to the major reaction of lithiated graphite with the nonaqueous electrolyte. With the addition of lithium difluoro(oxalato)borate as an electrolyte additive, the onset temperatures of the three peaks were pushed higher, as confirmed by the activation energies obtained.

  10. First order switched-capacitor building blocks for analog circuits 

    E-Print Network [OSTI]

    Nguyen, Liem Thanh

    1983-01-01

    switches. (a. ) Circuit schematic and, (b. ) the resulting two-phase clock signals. 29 13 Magnitude response of the stray sensitive configuration with V3 connected to V and V2 grounded. Cl 4. 591nF, 0 C3=255. 4pF, and C4 14. 7nF, 31 14 Phase response... of the stray sensitive configuration with V3 connected to V and V2 grounded . C 1 =4 . 5 91 nF 0 C3=255. 4pP, and C4=14. 7nF. 32 15 Magnitude response of the stray sensitive configuration with V3 connected to VO and Vl grounded. Cp4. 591nF, C3=255. 4p...

  11. R.W. Moore 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    /D-ft- F Pf 110. 0 lb/ft C - 0. 24 BTU/lb-oF f Fluid Properties: pr - 500 cp p 55. 0 lb/ft3 io 1'8 BTU/D-ft-oF 0 -6 . -1 co - 5. 0 x 10 4 psil c 4, 0 x 10 oF to Other Reservoir Properties: pe 75. 0 psia p - 14. 7 psia T 900 F rw ' 5 t re - 640..., q 2. Based on present day economics and the predictive equation, a screening method was developed. The screening method will aid in the identification of economically infeasible applications of ERH. 3. The effect of tool placement and reservoir...

  12. The effect of population on the performance of sweet corn hybrids 

    E-Print Network [OSTI]

    Appadurai, Reginald Rajakulasingham

    1956-01-01

    Ixlfllhaent of the ~eights fax' the CogseL Of NAILED 0|I' SC1E JIB August 1/$6 llagor Sub+ots Agroucey THE ~' QP FOPOQlTIQJ Om THE PERFORMANCE PF @WEST CORE HK3RXDS Ap~+4 +s to eQXe anal oontaat lg s 11SL RI1 spit%' oP tu ~ v goy Aug@. st I95$ TAIsLR OP CGi...&TEMTS' ACKRCKDQFZ1?-S e e e s s ~ ~ ~ e e s ~, ~ ~ 4 e s s s ~ DTBWfJCiXOM e e e e e s 'I +Vga', 0 O$' LTTII . ~T'lBR ~ e ~ e ~ ~ e 4 0, s s' e e ~ ~ s e e e e R&P%%. P'PAY& ~BOCCIE e ~ e ~ ~ ~ ~ ~ ~ ~ e e ~ ~ ~ e e EX(I(RIi'Wi'. ~iQi RKSIffJPS e e e e ~ g...

  13. Production of Fast Neutron With Plasma Focus Device

    E-Print Network [OSTI]

    Moshe Gai

    2006-05-05

    Before its demise DIANA Hi-TECH, LLC, demonstrated the use of two 50 kJoule Plasma Focus devices for the copius production of fast neutrons, x-rays and radio-isotopes. Such a device is suitable for fast neutron non invasive interogation of contra-band materials including hidden nuclear materials. It could be particularly useful for a fast and fail safe interogation of large cargo containers, or in merchant marine port of entries. The performance and fast neutron production (2.5 or 14 MeV at 10^11 or 10^13 neutrons per pulse, respectively) of the two PF50 Plasma Focus devices produced by DIANA HiTECH, LLC, are discussed.

  14. Heliotropium indicum (Native) 8 

    E-Print Network [OSTI]

    Hugh D. Wilson

    2011-08-10

    54 ~8S 6f ih48;: '& JPCK . 4$';4& 48SX~. &g CA~lG -~Cia , -, en@ esXktx'@Cia in:- "m~5 . a~St: ?::le f~r lehi~aCp~ . $4?'%if~ of-: cQ-pf tJssigili4p' $650~, ". l9J+8 ~' ~658 x" 3 0'l~i3', 5, 'J j 1 I Q. G 5'Q-+ A~ e, ~em~es et~4l. ~r 4o Chat ef...'. Burnett:hei %e~v:. -. : ' e;" . . - eom~teiet, . 4& vn;1. "~e~tm) fat Xabe~~t~m:&~-. . ~~ * I s't. - . t9. ~hi if. 'e. . +/mes:" JP. Xty iaees~. r~ "~~0, "- -. , gmemm ~la' 8 . ', ~at' s. :eye~ le'b&ntorg, AiueeitelC'~a. eai ye fsr~eh -' witt; e...

  15. Current parallel I/O limitations to scalable data analysis.

    SciTech Connect (OSTI)

    Mascarenhas, Ajith Arthur; Pebay, Philippe Pierre

    2011-07-01

    This report describes the limitations to parallel scalability which we have encountered when applying our otherwise optimally scalable parallel statistical analysis tool kit to large data sets distributed across the parallel file system of the current premier DOE computational facility. This report describes our study to evaluate the effect of parallel I/O on the overall scalability of a parallel data analysis pipeline using our scalable parallel statistics tool kit [PTBM11]. In this goal, we tested it using the Jaguar-pf DOE/ORNL peta-scale platform on a large combustion simulation data under a variety of process counts and domain decompositions scenarios. In this report we have recalled the foundations of the parallel statistical analysis tool kit which we have designed and implemented, with the specific double intent of reproducing typical data analysis workflows, and achieving optimal design for scalable parallel implementations. We have briefly reviewed those earlier results and publications which allow us to conclude that we have achieved both goals. However, in this report we have further established that, when used in conjuction with a state-of-the-art parallel I/O system, as can be found on the premier DOE peta-scale platform, the scaling properties of the overall analysis pipeline comprising parallel data access routines degrade rapidly. This finding is problematic and must be addressed if peta-scale data analysis is to be made scalable, or even possible. In order to attempt to address these parallel I/O limitations, we will investigate the use the Adaptable IO System (ADIOS) [LZL+10] to improve I/O performance, while maintaining flexibility for a variety of IO options, such MPI IO, POSIX IO. This system is developed at ORNL and other collaborating institutions, and is being tested extensively on Jaguar-pf. Simulation code being developed on these systems will also use ADIOS to output the data thereby making it easier for other systems, such as ours, to process that data.

  16. Timing analysis of PWR fuel pin failures

    SciTech Connect (OSTI)

    Jones, K.R.; Wade, N.L.; Katsma, K.R.; Siefken, L.J. (EG and G Idaho, Inc., Idaho Falls, ID (United States)); Straka, M. (Halliburton NUS, Idaho Falls, ID (United States))

    1992-09-01

    This report discusses research conducted to develop and demonstrate a methodology for calculation of the time interval between receipt of the containment isolation signals and the first fuel pin failure for loss-of-coolant accidents (LOCAs). Demonstration calculations were performed for a Babcock and Wilcox (B W) design (Oconee) and a Westinghouse (W) four-loop design (Seabrook). Sensitivity studies were performed to assess the impacts of fuel pin burnup, axial peaking factor, break size, emergency core cooling system availability, and main coolant pump trip on these times. The analysis was performed using the following codes: FRAPCON-2, for the calculation of steady-state fuel behavior; SCDAP/RELAP5/MOD3 and TRACPF1/MOD1, for the calculation of the transient thermal-hydraulic conditions in the reactor system; and FRAP-T6, for the calculation of transient fuel behavior. In addition to the calculation of fuel pin failure timing, this analysis provides a comparison of the predicted results of SCDAP/RELAP5/MOD3 and TRAC-PF1/MOD1 for large-break LOCA analysis. Using SCDAP/RELAP5/MOD3 thermal-hydraulic data, the shortest time intervals calculated between initiation of containment isolation and fuel pin failure are 10.4 seconds and 19.1 seconds for the B W and W plants, respectively. Using data generated by TRAC-PF1/MOD1, the shortest intervals are 10.3 seconds and 29.1 seconds for the B W and W plants, respectively. These intervals are for a double-ended, offset-shear, cold leg break, using the technical specification maximum peaking factor and applied to fuel with maximum design burnup. Using peaking factors commensurate with actual burnups would result in longer intervals for both reactor designs. This document provides appendices K and L of this report which provide plots for the timing analysis of PWR fuel pin failures for Oconee and Seabrook respectively.

  17. Qualification of the ITER CS Quench Detection System using Numerical Modeling

    SciTech Connect (OSTI)

    Martovetsky, Nicolai N [ORNL; Radovinsky, Alexey L [ORNL

    2013-01-01

    Abstract The ITER Central Solenoid (CS) magnet needs to be protected against overheating of the conductor in the event of the occurrence of a normal zone (NZ). Due to a large amount of stored energy and slow NZ propagation, the NZ needs to be detected and the switchyard needs to open the breakers within 2 s after detection of the NZ. The CS will be discharged on a dump resistor with a time constant of 7.5 s. During operation of the CS and its interaction with the poloidal field (PF) coils and plasma current, the CS experiences large inductive voltages from multiple sources, including nonlinear signals from eddy currents in the vacuum vessel and plasma current variation, that make the task of detecting the resistive signal even more difficult. This inductive voltage needs to be cancelled by quench detection (QD) hardware (e.g., bridges, converters, filters, processors) and appropriate processing of the QD signals to reliably detect NZ initiation and propagation. Two redundant schemes are proposed as the baseline for the CS QD System: 1) A scheme with Regular Voltage Taps (RVT) from triads of Double Pancakes (DP) supplemented by Central Difference Averaging (CDA) and by digital suppression of the inductive voltage from all active coils (the CS and PF coils). Voltage taps are taken from helium outlets at the CS outer diameter. 2)A scheme with Cowound Voltage Taps (CVT) taken from cowound wires routed from the helium inlet at the CS inner diameter. Summary of results of the numerical modeling of the performance of both baseline CS QD systems is presented in this paper. Index Terms Quench detection, Central Solenoid, ITER

  18. MAR flow mapping of Analytical Chemistry Operations (Preliminary Report)

    SciTech Connect (OSTI)

    Barr, Mary E. [Los Alamos National Laboratory; Farish, Thomas J. [Los Alamos National Laboratory

    2012-06-13

    The recently released Supplemental Directive, NA-1 SD 1027, updates the radionuclide threshold values in DOE-STD-1027-92 CN1 to reflect the use of modern parameters for dose conversion factors and breathing rates. The directive also corrects several arithmetic errors within the original standard. The result is a roughly four-fold increase in the amount of weapons-grade nuclear material allowed within a designated radiological facility. Radiological laboratory space within the recently constructed Radiological Laboratory Office and Utility Building (RLUOB) is slated to house selected analytical chemistry support activities in addition to small-scale actinide R&D activities. RLUOB is within the same facility operations envelope as TA-55. Consolidation of analytical chemistry activities to RLUOB and PF-4 offers operational efficiency improvements relative to the current pre-CMRR plans of dividing these activities between RLUOB, PF-4, and CMR. RLUOB is considered a Radiological Facility under STD-1027 - 'Facilities that do not meet or exceed Category 3 threshold criteria but still possess some amount of radioactive material may be considered Radiological Facilities.' The supplemental directive essentially increases the allowable material-at-risk (MAR) within radiological facilities from 8.4 g to 38.6 g for {sup 239}Pu. This increase in allowable MAR provides a unique opportunity to establish additional analytical chemistry support functions in RLUOB without negatively impacting either R&D activities or facility operations. Individual radiological facilities are tasked to determine MAR limits (up to the Category 3 thresholds) appropriate to their operational conditions. This study presents parameters that impact establishing MAR limits for RLUOB and an assessment of how various analytical chemistry support functions could operate within the established MAR limits.

  19. Plutonium (III) and uranium (III) nitrile complexes

    SciTech Connect (OSTI)

    Enriquez, A. E.; Matonic, J. H.; Scott, B. L.; Neu, M. P.

    2002-01-01

    Iodine oxidation of uranium and plutonium metals in tetrahydrofuran and pyridine form AnI{sub 3}(THF){sub 4} and AnI{sub 3}(py){sub 4} (An = Pu, U). These compounds represent convenient entries Into solution An(III) chemistry in organic solvents. Extensions of the actinide metal oxidation methodology in nitrile solvents by I{sub 2}, AgPF{sub 6}, and TIPF{sub 6} are presented here. Treatment of Pu{sup 0} in acetonitrile with iodine yields a putative PuI{sub 3}(NCMe){sub x} intermediate which can be trapped with the tripodal nitrogen donor ligand tpza (tpza = (tris[(2-pyrazinyl)methyl]amine)) and forms the eight-coordinate complex (tpza)PuI{sub 3}(NCMe). Treatment of excess U{sup 0} metal by iodine in acetonitrile afforded a brown crystalline mixed valence complex, [U(NCMe){sub 9}][UI{sub 6}][I], instead of UI{sub 3}(NCMe){sub 4}. The analogous reaction in bezonitrile forms red crystalline UI{sub 4}(NCPh){sub 4}. In contrast, treatment of UI{sub 3}(THF){sub 4} with excess acetonitrile cleanly generates [U(NCMe){sub 9}][I]{sub 3}. Oxidation of Pu{sup 0} by either TI(I) or Ag(I) hexafluorophosphate salts generates a nine-coordinate homoleptic acetonitrile adduct [Pu(NCMe){sub 9}][PF{sub 6}]{sub 3}. Attempts to oxidize U{sub 0} with these salts were unsuccessful.

  20. Mixed-Symmetry Shell-Model Calculations in Nuclear Physics

    E-Print Network [OSTI]

    V. G. Gueorguiev

    2010-02-17

    We consider a novel approach to the nuclear shell model. The one-dimensional harmonic oscillator in a box is used to introduce the concept of an oblique-basis shell-model theory. By implementing the Lanczos method for diagonalization of large matrices, and the Cholesky algorithm for solving generalized eigenvalue problems, the method is applied to nuclei. The mixed-symmetry basis combines traditional spherical shell-model states with SU(3) collective configurations. We test the validity of this mixed-symmetry scheme on 24Mg and 44Ti. Results for 24Mg, obtained using the Wilthental USD intersection in a space that spans less than 10% of the full-space, reproduce the binding energy within 2% as well as an accurate reproduction of the low-energy spectrum and the structure of the states - 90% overlap with the exact eigenstates. In contrast, for an m-scheme calculation, one needs about 60% of the full space to obtain compatible results. Calculations for 44Ti support the mixed-mode scheme although the pure SU(3) calculations with few irreps are not as good as the standard m-scheme calculations. The strong breaking of the SU(3) symmetry results in relatively small enhancements within the combined basis. However, an oblique-basis calculation in 50% of the full pf-shell space is as good as a usual m-scheme calculation in 80% of the space. Results for the lower pf-shell nuclei 44-48Ti and 48Cr, using the Kuo-Brown-3 interaction, show that SU(3) symmetry breaking in this region is driven by the single-particle spin-orbit splitting. In our study we observe some interesting coherent structures, such as coherent mixing of basis states, quasi-perturbative behavior in the toy model, and enhanced B(E2) strengths close to the SU(3) limit even though SU(3) appears to be rather badly broken.

  1. Tuning redox potentials of bis(imino)pyridine cobalt complexes: an experimental and theoretical study involving solvent and ligand effects

    SciTech Connect (OSTI)

    Moyses Araujo, C.; Doherty, Mark D.; Konezny, Steven J.; Luca, Oana R.; Usyatinsky, Alex; Grade, Hans; Lobkovsky, Emil; Soloveichik, Grigorii L.; Crabtree, Robert H.; Batista, Victor S.

    2012-01-01

    The structure and electrochemical properties of a series of bis(imino)pyridine CoII complexes (NNN)CoX? and [(NNN)?Co][PF?]? (NNN = 2,6-bis[1-(4-R-phenylimino)ethyl]pyridine, with R = CN, CF?, H, CH?, OCH?, N(CH?)?; NNN = 2,6-bis[1-(2,6-(iPr)?-phenylimino)ethyl]pyridine and X = Cl, Br) were studied using a combination of electrochemical and theoretical methods. Cyclic voltammetry measurements and DFT/B3LYP calculations suggest that in solution (NNN)CoCl? complexes exist in equilibrium with disproportionation products [(NNN)?Co]²? [CoCl?]²? with the position of the equilibrium heavily influenced by both the solvent polarity and the steric and electronic properties of the bis(imino)pyridine ligands. In strong polar solvents (e.g., CH?CN or H?O) or with electron donating substituents (R = OCH? or N(CH?)?) the equilibrium is shifted and only oxidation of the charged products [(NNN)?Co]²? and [CoCl?]²? is observed. Conversely, in nonpolar organic solvents such as CH?Cl? or with electron withdrawing substituents (R = CN or CF?), disproportionation is suppressed and oxidation of the (NNN)CoCl? complexes leads to 18e? CoIII complexes stabilized by coordination of a solvent moiety. In addition, the [(NNN)?Co][PF?]? complexes exhibit reversible CoII/III oxidation potentials that are strongly dependent on the electron withdrawing/donating nature of the N-aryl substituents, spanning nearly 750 mV in acetonitrile. The resulting insight on the regulation of redox properties of a series of bis(imino)pyridine cobalt(II) complexes should be particularly valuable to tune suitable conditions for reactivity.

  2. Determining the exchange parameters of spin-1 metal-organic molecular magnets in pulsed magnetic fields

    SciTech Connect (OSTI)

    Mcdonald, Ross D; Singleton, John; Lancaster, Tom; Goddard, Paul; Manson, Jamie

    2011-01-14

    We nave measured the high-field magnetization of a number of Ni-based metal-organic molecular magnets. These materials are self-assembly coordination polymers formed from transition metal ions and organic ligands. The chemistry of the compounds is versatile allowing many structures with different magnetic properties to be formed. These studies follow on from previous measurements of the Cu-based analogues in which we showed it was possible to extract the exchange parameters of low-dimensional magnets using pulsed magnetic fields. In our recent experiments we have investigated the compound (Ni(HF{sub 2})(pyz){sub 2})PF{sub 6}, where pyz = pyrazine, and the Ni-ions are linked in a quasi-two-dimensional (Q2D) square lattice via the pyrazine molecules, with the layers held together by HF{sub 2} ligands. We also investigated Ni(NCS){sub 2}(pyzdo){sub 2}, where pyzdo = pyrazine dioxide. The samples are grown at Eastern Washington University using techniques described elsewhere. Measurements are performed at the pulsed magnetic field laboratory in Los Alamos. The magnetization of powdered samples is determined using a compensated coil magnetometer in a 65 T short pulse magnet. Temperatures as low as 500 mK are achievable using a {sup 3}He cryostat. The main figure shows the magnetization of the spin-1 [Ni(HF{sub 2})(pyz){sub 2}]PF{sub 6} compound at 1.43 K. The magnetization rises slowly at first, achieving a rounded saturation whose midpoint is around 19 T. A small anomaly is also seen in the susceptibility at low fields ({approx}3 T), which might be attributed to a spin-flop transition. In contrast, the spin-1/2 [Cu(HF{sub 2})(pyz){sub 2}]PF{sub 6} measured previously has a saturation magnetization of 35.5 T and a strongly concave form of M(B) below this field. This latter compound was shown to be a good example of a Q2D Heisenberg antiferromagnet with the strong exchange coupling (J{sub 2D} = 12.4 K, J{sub {perpendicular}}/J{sub 2D} {approx} 10{sup -2}) directed along the Cu-pyz-Cu directions. The structure of the two compounds is similar, but in the case of the Cu-compound the Cu-Cu pathways are linear, whereas in the Ni-compound they are kinked. The pulsed-field data combined with information from temperature-dependent susceptibility, muon-spin rotation, electron-spin resonance and ligand-field calculations suggest that, far from being magnetically Q2D, the Ni-compound is fairly one-dimensional with the dominant exchange (J{sub 1D} = 3.1 K and J{sub {perpendicular}}/J{sub 1D} = 0.63) directed along the Ni-FHF-Ni direction. Ni(NCS){sub 2}(pyzdo){sub 2} was also investigated. Previous ultra-high field measurements using the 100 T magnet have shown that this compound has a saturation field close to 80 T. The purpose of the present studies is to map out the phase diagram of this material at mid-range fields. The data are shown in the inset to the figure. This continuing project probes the ability of organic ligands to mediate magnetic exchange, the link between structure, dimensionality and bulk magnetic properties, as well as the role of spin number in quantum magnets. Ultimately the investigations aim to determine to what extent it is possible to produce self-assembly molecular materials with tailor-made magnetic characteristics.

  3. The detection of reconstituted milk in natural milk 

    E-Print Network [OSTI]

    Mulay, Charudatta Anant

    1959-01-01

    l i b r a r y A A M COLLEGE O F TEXAS lib rblbalymO mnk 'bamOnlylSlbr Pyy. yY OslS'so Pyo. s rNppFR^J^Nh? a?JRHEJ^^J s?J?^ PH4JC nHe?N^^FE ^h ^?F *RJEHJ^F n??hh4 h? ^?F s?RN?H4^HRJ4 J?E PF??J?N?J4 ah44F?F h? lF?Jp N? ?JR^NJ4 ?H4?N44?F?^ h...? ^?F 'F?HNRF?F?^ ?hR ^?F rF?RFF h? rh?^hR h? ??N4hph??C PJC ???? PJ?hR nHe?F?^? rJNRC PJ?H?J?^HRN?? lib rblbalymO m? 'bamOnlylSlbr Pyo. yO OslS'so Pyo. s rNppFR^J^Nh? ??C a?JRH?J^^J s?J?^ PH4JC s??Rh?FE Jp ^h p^C4F J?E ?h?^F?^ ?eC? 0 ? y 4 a...

  4. Crystallization and preliminary crystallographic analysis of orotidine 5?-monophosphate decarboxylase from the human malaria parasite Plasmodium falciparum

    SciTech Connect (OSTI)

    Krungkrai, Sudaratana R.; Tokuoka, Keiji; Kusakari, Yukiko; Inoue, Tsuyoshi; Adachi, Hiroaki; Matsumura, Hiroyoshi; Takano, Kazufumi; Murakami, Satoshi; Mori, Yusuke; Kai, Yasushi; Krungkrai, Jerapan; Horii, Toshihiro

    2006-06-01

    Orotidine 5?-monophosphate decarboxylase of human malaria parasite P. falciparum was crystallized by the seeding method in a hanging drop using PEG 3000 as a precipitant. A complete set of diffraction data from a native crystal was collected to 2.7 Å resolution at 100 K using synchrotron radiation. Orotidine 5?-monophosphate (OMP) decarboxylase (OMPDC; EC 4.1.1.23) catalyzes the final step in the de novo synthesis of uridine 5?-monophosphate (UMP) and defects in the enzyme are lethal in the malaria parasite Plasmodium falciparum. Active recombinant P. falciparum OMPDC (PfOMPDC) was crystallized by the seeding method in a hanging drop using PEG 3000 as a precipitant. A complete set of diffraction data from a native crystal was collected to 2.7 Å resolution at 100 K using synchrotron radiation at the Swiss Light Source. The crystal exhibits trigonal symmetry (space group R3), with hexagonal unit-cell parameters a = b = 201.81, c = 44.03 Å. With a dimer in the asymmetric unit, the solvent content is 46% (V{sub M} = 2.3 Å{sup 3} Da{sup ?1})

  5. Stability of the solid electrolyte Li{sub 3}OBr to common battery solvents

    SciTech Connect (OSTI)

    Schroeder, D.J.; Hubaud, A.A.; Vaughey, J.T.

    2014-01-01

    Graphical abstract: The stability of the anti-perovskite phase Li{sub 3}OBr has been assessed in a variety of battery solvents. - Highlights: • Lithium stable solid electrolyte Li{sub 3}OBr unstable to polar organic solvents. • Solvation with no dissolution destroys long-range structure. • Ion exchange with protons observed. - Abstract: Recently a new class of solid lithium ion conductors was reported based on the anti-perovskite structure, notably Li{sub 3}OCl and Li{sub 3}OBr. For many beyond lithium-ion battery uses, the solid electrolyte is envisioned to be in direct contact with liquid electrolytes and lithium metal. In this study we evaluated the stability of the Li{sub 3}OBr phase against common battery solvents electrolytes, including diethylcarbonate (DEC) and dimethylcarbonate (DMC), as well as a LiPF{sub 6} containing commercial electrolyte. In contact with battery-grade organic solvents, Li{sub 3}OBr was typically found to be insoluble but lost its crystallinity and reacted with available protons and in some cases with the solvent. A low temperature heat treatment was able to restore crystallinity of the samples; however evidence of proton ion exchange was conserved.

  6. Fluorinated Phosphazene Co-solvents for Improved Thermal and Safety Performance in Lithium-Ion Battery Electrolytes

    SciTech Connect (OSTI)

    Harry W. Rollins; Mason K. Harrup; Eric J. Dufek; David K. Jamison; Sergiy V. Sazhin; Kevin L. Gering; Dayna L. Daubaras

    2014-10-01

    The safety of lithium-ion batteries is coming under increased scrutiny as they are being adopted for large format applications especially in the vehicle transportation industry and for grid-scale energy storage. The primary short-comings of lithium-ion batteries are the flammability of the liquid electrolyte and sensitivity to high voltage and elevated temperatures. We have synthesized a series of non-flammable fluorinated phosphazene liquids and blended them with conventional carbonate solvents. While the use of these phosphazenes as standalone electrolytes is highly desirable, they simply do not satisfy all of the many requirements that must be met such as high LiPF6 solubility and low viscosity, thus we have used them as additives and co-solvents in blends with typical carbonates. The physical and electrochemical properties of the electrolyte blends were characterized, and then the blends were used to build 2032-type coin cells which were evaluated at constant current cycling rates from C/10 to C/1. We have evaluated the performance of the electrolytes by determining the conductivity, viscosity, flash point, vapor pressure, thermal stability, electrochemical window, cell cycling data, and the ability to form solid electrolyte interphase (SEI) films. This paper presents our results on a series of chemically similar fluorinated cyclic phosphazene trimers, the FM series, which has exhibited numerous beneficial effects on battery performance, lifetimes, and safety aspects.

  7. Polymer quantum effects on compact stars models

    E-Print Network [OSTI]

    Guillermo Chacon-Acosta; Hector Hernandez-Hernandez

    2014-08-05

    In this work we study a completely degenerated fermion gas at zero temperature within a semiclassical approximation for the Hamiltonian arising in polymer quantum mechanics. Polymer quantum systems are quantum mechanical models quantized in a similar way as in loop quantum gravity that allow the study of the discreteness of space and other features of the loop quantization in a simplified way. We obtain the polymer modified thermodynamical properties noticing that the corresponding Fermi energy is exactly the same as if one directly polymerizes the momentum $p_F$. We also obtain the corresponding expansion of thermodynamical variables for small values of the polymer length scale $\\lambda$. With this results we study a simple model of a compact object where the gravitational collapse is supported by electron degeneracy pressure. We find polymer corrections to the mass of the star. When compared with typical measurements of the mass of white dwarfs we obtain a bound on the polymer length of $\\lambda^2\\lesssim 10^{-26}m^2$.

  8. Self-assembly molecular squares with metal complexes as bridging ligands

    SciTech Connect (OSTI)

    Sun, S.S.; Silva, A.S.; Brinn, I.M.; Lees, A.J.

    2000-04-03

    Polynuclear transition metal complexes containing multichromophoric units, such as metal polypyridyl complexes, are of considerable current interest. Much attention has been paid to the synthesis of multicomponent systems that exhibit photoinduced intercomponent electron and/or energy-transfer processes and to their potential applications for photonic and electronic devices. Systems incorporating Re(I)- Ru(II)-, and Os(II)-based polypyridyl chromophores are the most commonly studied because of their favorable redox and spectroscopic characteristics. In this communication, the authors combine the concepts of self-assembly and complexes as ligands and report the preparation of a series of molecular squares with the general molecular formula [fac-Br(CO){sub 3}Re({mu}-(pyterpy){sub 2}M)]{sub 4}(PF{sub 6}){sub 8}, where pyterpy is 4{prime}-(4{prime}{double_prime}-pyridyl)-2,2{prime}:6{prime}2{double_prime}-terpyridine and M = Fe, Ru, or Os. The spectroscopic properties and a preliminary anion binding study of these novel octanuclear molecular squares are also presented.

  9. Sputter deposition of thin film MIM capacitors on LTCC substrates for RF bypass and filtering applications

    SciTech Connect (OSTI)

    Murray, Jack [Missouri University of Science and Technology; O'Keefe, Matthew J. [Missouri University of Science and Technology; Wilder, Kristina [Missouri University of Science and Technology; Eatinger, Ryan [Kansas State University; Kuhn, William [Kansas State University; Krueger, Daniel S. [Honeywell Federal Manufacturing & Technologies; Wolf, J. Ambrose [Honeywell Federal Manufacturing & Technologies

    2011-08-31

    Thin film capacitors for RF bypass and filtering applications were sputter deposited onto low temperature co-fired ceramic (LTCC) substrates. The capacitors were configured in a metal-insulator-metal (MIM) design featuring 200 nm thick Al electrodes and a 300 nm thick Al{sub 2}O{sub 3} dielectric layer, with dimensions varied between ~150x150 ?m and ~750x750 ?m. DC current-voltage measurements (E ? 5 MV/cm) coupled with impedance analysis (?15 MHz) was used to characterize the resulting devices. More than 90% of the devices functioned as capacitors with high DC resistance (>20 M?) and low loss (tan ? <0.1). A second set of capacitors were made under the same experimental conditions with device geometries optimized for high frequency (?200 MHz) applications. These capacitors featured temperature coefficient of capacitance (TCC) values between 500 and 1000 ppm/°C as well as low loss and high self-resonant frequency performance (ESR <0.6 Ohms at self-resonance of 5.7 GHz for 82 pF). Capacitance and loss values were comparable between the capacitor structures of similar areas at the different frequency regimes.

  10. TRAC code assessment using data from SCTF Core-III, a large-scale 2D/3D facility

    SciTech Connect (OSTI)

    Boyack, B.E.; Shire, P.R.; Harmony, S.C.; Rhee, G.

    1988-01-01

    Nine tests from the SCTF Core-III configuration have been analyzed using TRAC-PF1/MOD1. The objectives of these assessment activities were to obtain a better understanding of the phenomena occurring during the refill and reflood phases of a large-break loss-of-coolant accident, to determine the accuracy to which key parameters are calculated, and to identify deficiencies in key code correlations and models that provide closure for the differential equations defining thermal-hydraulic phenomena in pressurized water reactors. Overall, the agreement between calculated and measured values of peak cladding temperature is reasonable. In addition, TRAC adequately predicts many of the trends observed in both the integral effect and separate effect tests conducted in SCTF Core-III. The importance of assessment activities that consider potential contributors to discrepancies between the measured and calculated results arising from three sources are described as those related to (1) knowledge about the facility configuration and operation, (2) facility modeling for code input, and (3) deficiencies in code correlations and models. An example is provided. 8 refs., 7 figs., 2 tabs.

  11. Use of 2D/3D data for peak cladding temperature uncertainty studies

    SciTech Connect (OSTI)

    Boyack, B.E.

    1988-01-01

    In August 1988, the Nuclear Regulatory Commission (NRC) approved the final version of a revised rule on the acceptance of emergency core cooling systems. The revised rule allows emergency core cooling system analysis based on best-estimate methods, provided uncertainties in the prediction of prescribed acceptance limits are quantified and reported. To support the revised rule, the NRC developed the Code Scaling, Applicability, and Uncertainty (CSAU) evaluation methodology. Data from the 2D/3D program have been used in a demonstration of the CSAU methodology in two ways. First, the data were used to identify and quantify biases that are related to the implementation of selected correlations and models in the thermal-hydraulic systems code TRAC-PF1/MOD1 as it is used to calculate the demonstration transient, a large-break loss-of-coolant accident. Second, the data were used in a supportive role to provide insight into the accuracy of code calculations and to confirm conclusions that are drawn regarding specific CSAU studies. Examples are provided illustrating each of these two uses of 2D/3D data. 9 refs., 7 figs.

  12. Quantifying reactor safety margins: Part 1: An overview of the code scaling, applicability, and uncertainty evaluation methodology

    SciTech Connect (OSTI)

    Boyack, B.E.; Duffey, R.B.; Griffith, P.; Katsma, K.R.; Lellouche, G.S.; Levy, S.; Rohatgi, U.S.; Wilson, G.E.; Wulff, W.; Zuber, N.

    1988-01-01

    In August 1988, the Nuclear Regulatory Commission (NRC) approved the final version of a revised rule on the acceptance of emergency core cooling systems (ECCS) entitled ''Emergency Core Cooling System; Revisions to Acceptance Criteria.'' The revised rule states an alternate ECCS performance analysis, based on best-estimate methods, may be used to provide more realistic estimates of plant safety margins, provided the licensee quantifies the uncertainty of the estimates and included that uncertainty when comparing the calculated results with prescribed acceptance limits. To support the revised ECCS rule, the NRC and its contractors and consultants have developed and demonstrated a method called the Code Scaling, Applicability, and Uncertainty (CSAU) evaluation methodology. It is an auditable, traceable, and practical method for combining quantitative analyses and expert opinions to arrive at computed values of uncertainty. This paper provides an overview of the CSAU evaluation methodology and its application to a postulated cold-leg, large-break loss-of-coolant accident in a Westinghouse four-loop pressurized water reactor with 17 /times/ 17 fuel. The code selected for this demonstration of the CSAU methodology was TRAC-PF1/MOD1, Version 14.3. 23 refs., 5 figs., 1 tab.

  13. Reflood completion report: Volume 1. A phenomenological thermal-hydraulic model of hot rod bundles experiencing simultaneous bottom and top quenching and an optimization methodology for closure development

    SciTech Connect (OSTI)

    Nelson, R.A. Jr.; Pimentel, D.A.; Jolly-Woodruff, S.; Spore, J.

    1998-04-01

    In this report, a phenomenological model of simultaneous bottom-up and top-down quenching is developed and discussed. The model was implemented in the TRAC-PF1/MOD2 computer code. Two sets of closure relationships were compared within the study, the Absolute set and the Conditional set. The Absolute set of correlations is frequently viewed as the pure set because the correlations is frequently viewed as the pure set because the correlations utilize their original coefficients as suggested by the developer. The Conditional set is a modified set of correlations with changes to the correlation coefficient only. Results for these two sets indicate quite similar results. This report also summarizes initial results of an effort to investigate nonlinear optimization techniques applied to the closure model development. Results suggest that such techniques can provide advantages for future model development work, but that extensive expertise is required to utilize such techniques (i.e., the model developer must fully understand both the physics of the process being represented and the computational techniques being employed). The computer may then be used to improve the correlation of computational results with experiments.

  14. Axial magnetic field and toroidally streaming fast ions in the dense plasma focus are natural consequences of conservation laws in the curved axisymmetric geometry of the current sheath

    SciTech Connect (OSTI)

    Auluck, S. K. H.

    2014-10-15

    Direct measurement of axial magnetic field in the PF-1000 dense plasma focus (DPF), and its reported correlation with neutron emission, call for a fresh look at previous reports of existence of axial magnetic field component in the DPF from other laboratories, and associated data suggesting toroidal directionality of fast ions participating in fusion reactions, with a view to understand the underlying physics. In this context, recent work dealing with application of the hyperbolic conservation law formalism to the DPF is extended in this paper to a curvilinear coordinate system, which reflects the shape of the DPF current sheath. Locally unidirectional shock propagation in this coordinate system enables construction of a system of 7 one-dimensional hyperbolic conservation law equations with geometric source terms, taking into account all the components of magnetic field and flow velocity. Rankine-Hugoniot jump conditions for this system lead to expressions for the axial magnetic field and three components of fluid velocity having high ion kinetic energy.

  15. Studies on the double-{beta} decay nucleus {sup 64}Zn using the (d,{sup 2}He) reaction

    SciTech Connect (OSTI)

    Grewe, E.-W.; Baeumer, C.; Dohmann, H.; Frekers, D.; Hollstein, S.; Rakers, S.; Thies, J. H. [Institut fuer Kernphysik, Westfaelische Wilhelms-Universitaet Muenster (Germany); Harakeh, M. N.; Berg, A. M. van den; Woertche, H. J. [Kernfysisch Versneller Instituut, University of Groningen, NL-9747 AA Groningen (Netherlands); Johansson, H.; Martinez-Pinedo, G.; Petermann, I.; Sieja, K.; Simon, H. [Gesellschaft fuer Schwerionenforschung, D-64291 Darmstadt (Germany); Langanke, K. [Gesellschaft fuer Schwerionenforschung, D-64291 Darmstadt (Germany); Institut fuer Kernphysik, Technische Universitaet Darmstadt, D-64289 Darmstadt (Germany); Nowacki, F. [Institut de Recherches Subatomiques, Universite Louis Pasteur, F-67037 Strasbourg (France); Popescu, L. [Vakgroep Subatomaire en Stralingsfysica, Universiteit Gent, B-9000 Gent (Belgium); Savran, D. [Kernfysisch Versneller Instituut, University of Groningen, NL-9747 AA Groningen (Netherlands); Institut fuer Kernphysik, Technische Universitaet Darmstadt, D-64289 Darmstadt (Germany); Zilges, A. [Institut fuer Kernphysik, Technische Universitaet Darmstadt, D-64289 Darmstadt (Germany)

    2008-06-15

    The (d,{sup 2}He) charge-exchange reaction on the double-{beta} decay ({beta}{beta}) nucleus {sup 64}Zn has been studied at an incident energy of 183 MeV. The two protons in the {sup 1}S{sub 0} state (indicated as {sup 2}He) were both momentum analyzed and detected simultaneously by the BBS magnetic spectrometer and its position-sensitive detector. {sup 2}He spectra with a resolution of about 115 keV (FWHM) have been obtained allowing identification of many levels in the residual nucleus {sup 64}Cu with high precision. {sup 64}Zn is one of the rare cases undergoing a {beta}{beta} decay in {beta}{sup +} direction. In the experiment presented here, Gamow-Teller (GT{sup +}) transition strengths have been extracted. Together with the GT{sup -} transition strengths from {sup 64}Ni({sup 3}He,t) data to the same intermediate nucleus {sup 64}Cu, the nuclear matrix elements of the {beta}{beta} decay of {sup 64}Zn have been evaluated. Finally, the GT{sup {+-}} distributions are compared with shell-model calculations and a critical assessment is given of the various residual interactions presently employed for the pf shell.

  16. NSTX Disruption Simulations of Detailed Divertor and Passive Plate Models by Vector Potential Transfer from OPERA Global Analysis Results

    SciTech Connect (OSTI)

    P. H. Titus, S. Avasaralla, A.Brooks, R. Hatcher

    2010-09-22

    The National Spherical Torus Experiment (NSTX) project is planning upgrades to the toroidal field, plasma current and pulse length. This involves the replacement of the center-stack, including the inner legs of the TF, OH, and inner PF coils. A second neutral beam will also be added. The increased performance of the upgrade requires qualification of the remaining components including the vessel, passive plates, and divertor for higher disruption loads. The hardware needing qualification is more complex than is typically accessible by large scale electromagnetic (EM) simulations of the plasma disruptions. The usual method is to include simplified representations of components in the large EM models and attempt to extract forces to apply to more detailed models. This paper describes a more efficient approach of combining comprehensive modeling of the plasma and tokamak conducting structures, using the 2D OPERA code, with much more detailed treatment of individual components using ANSYS electromagnetic (EM) and mechanical analysis. This capture local eddy currents and resulting loads in complex details, and allows efficient non-linear, and dynamic structural analyses.

  17. Analysis of the cryogenic system behavior for pulsed heat load in EAST

    SciTech Connect (OSTI)

    Hu, L. B.; Zhuang, M.; Zhou, Z. W.; Xia, G. H. [Cryogenic Engineering Division, Institute of Plasma Physics, Chinese Academy of Sciences, P.O. Box 1126, Shushanhu Road 350, Hefei, Anhui 230031 (China)

    2014-01-29

    EAST is the first full superconducting fusion device. The plasma is confined by the magnetic fields generated from a large set of superconducting magnets which are made of cable in-conduit conductor (CICC). In operation, these magnets suffer heat loads from thermal and nuclear radiation from the surrounding components and plasma as well as the eddy currents and the AC losses generated within the magnets, together with the heat conduction through supports and the resistive heat generated at the current lead transiting to room temperature. The cryogenic system of our EAST consists of a 2kW/4K helium refrigerator and a distribution system for the cooling of poloidal field (PF) and toroidal field (TF) coils, structures, thermal shields, buslines and current leads. Pulsed heat load is the main difference between the cryogenic system of a full superconducting Tokamak system and other large scale cryogenic systems. The cryogenic system operates in a pulsed heat loads mode requiring the helium refrigerator to remove periodically large heat loads in time. At the same time, the cryogenic system parameters such as helium cooling superconducting magnets, helium refrigerator and helium distribution system are changing. In this paper, the variation range of the parameters of superconducting magnets and refrigerator has been analyzed in the typical plasma discharge mode. The control scheme for the pulsed loads characteristics of the cryogenic system has been proposed, the implementation of which helps to smooth the pulse loads and to improve the stability of the operation of the cryogenic system.

  18. Fluoroalkyl containing salts combined with fluorinated solvents for electrolytes

    SciTech Connect (OSTI)

    Tikhonov, Konstantin; Yip, Ka Ki; Lin, Tzu-Yuan; Erickson, Michael Jason

    2015-04-21

    Provided are electrochemical cells and electrolytes used to build such cells. An electrolyte may include a fluoroalkyl-substituted LiPF.sub.6 salt or a fluoroalkyl-substituted LiBF.sub.4 salt. In some embodiments, at least one fluorinated alkyl of the salt has a chain length of from 1 to 8 or, more specifically, between about 2 and 8. These fluorinated alkyl groups, in particular, relatively large fluorinated alkyl groups improve solubility of these salts in fluorinated solvents that are less flammable than, for example, conventional carbonate solvents. At the same time, the size of fluoroalkyl-substituted salts should be limited to ensure adequate concentration of the salt in an electrolyte and low viscosity of the electrolyte. In some embodiments, the concentration of a fluoroalkyl-substituted salt is at least about 0.5M. Examples of fluorinated solvents include various fluorinated esters, fluorinated ethers, and fluorinated carbonates, such a 1-methoxyheptafluoropropane, methyl nonafluorobutyl ether, ethyl nonafluorobutyl ether, 1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane, 3-ethoxy-1,1,1,2,3,4,4,5,5,6,6,6-dodecafluoro-2-trifluoromethyl-hexane, and 1,1,1,2,3,3-hexafluoro-4-(1,1,2,3,3,3-hexafluoropropoxy)-pentane.

  19. Design and Construction of the NSTX Bakeout, Cooling and Vacuum Systems

    SciTech Connect (OSTI)

    L.E. Dudek; M. Kalish; R. Gernhardt; R.F. Parsells; W. Blanchard

    1999-11-01

    This paper will describe the design, construction and initial operation of the NSTX bakeout, water cooling and vacuum systems. The bakeout system is designed for two modes of operation. The first mode allows heating of the first wall components to 350 degrees C while the external vessel is cooled to 150 degrees C. The second mode cools the first wall to 150 degrees C and the external vessel to 50 degrees C. The system uses a low viscosity heat transfer oil which is capable of high temperature low pressure operation. The NSTX Torus Vacuum Pumping System (TVPS) is designed to achieve a base pressure of approximately 1x10 (superscript -8) Torr and to evacuate the plasma fuel gas loads in less than 5 minutes between discharges. The vacuum pumping system is capable of a pumping speed of approximately 3400 l/s for deuterium. The hardware consists of two turbo molecular pumps (TMPs) and a mechanical pump set consisting of a mechanical and a Roots blower pump. A PLC is used as the control system to provide remote monitoring, control and software interlock capability. The NSTX cooling water provides chilled, de ionized water for heat removal in the TF, OH and PF, power supplies, bus bar systems, and various diagnostics. The system provides flow monitoring via a PLC to prevent damage due to loss of flow.

  20. Structure, Function and Inhibition of the Phosphoethanolamine Methyltransferases of the Human Malaria Parasites Plasmodium vivax and Plasmodium knowlesi

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Garg, Aprajita; Lukk, Tiit; Kumar, Vidya; Choi, Jae-Yeon; Augagneur, Yoann; Voelker, Dennis R.; Nair, Satish; Mamoun, Choukri Ben

    2015-03-12

    Phosphoethanolamine methyltransferases (PMTs) catalyze the three-step methylation of phosphoethanolamine to form phosphocholine, a critical step in the synthesis of phosphatidylcholine in a select number of eukaryotes including human malaria parasites, nematodes and plants. Genetic studies in the malaria parasite Plasmodium falciparum have shown that the methyltransferase PfPMT plays a critical function in parasite development and differentiation. The presence of PMT orthologs in other malaria parasites that infect humans and their absence in mammals make them ideal targets for the development of selective antimalarials with broad specificity against different Plasmodium species. Here we describe the X-ray structures and biochemical properties ofmore »PMT orthologs from Plasmodium vivax and Plasmodium knowlesi and show that both enzymes are inhibited by amodiaquine and NSC158011, two drugs with potent antimalarial activity. Metabolic studies in a yeast mutant that relies on PkPMT or PvPMT for survival demonstrated that these compounds inhibit phosphatidylcholine biosynthesis from ethanolamine. Our structural and functional data provide insights into the mechanism of catalysis and inhibition of PMT enzymes and set the stage for a better design of more specific and selective antimalarial drugs.« less

  1. Coordinating Tectons: Bipyridyl Terminated Allenylidene Complexes

    SciTech Connect (OSTI)

    Cifuentes, Marie P.; Humphrey, Mark G.; Koutsantonis, George A.; Lengkeek, Nigel A.; Petrie, Simon; Sanford, Vanessa; Schauer, Phil A.; Skelton, Brian W.; Stranger, Robert; White, Allan H.

    2009-01-15

    A series of complexes with {pi}-conjugated carbon chains terminated by bipyridyl moieties has been prepared. These allenylidene complexes were derived from 9-hydroxy-9-ethynyl-4,5-diazafluorene, the preparation of which is reported; the new allenylidene complexes are highly colored with the cumulated carbon chain terminating in a bipyridyl unit providing a site for further coordination. The synthesis, characterization, and X-ray structure determination of trans-[MCl(P{intersection}P){sub 2}{sub {double_bond}}C{sub {double_bond}}C{sub {double_bond}}(4,5-diazafluoren-9-yl)]PF{sub 6} (M = Ru, P{intersection}P = bis(diphenylphosphino)methane (dppm), 1,2-bis(diphenylphosphino)ethane (dppe), 1,2-bis(dimethylphosphino)ethane (dmpe); M = Os, P{intersection}P = dppm) are described. The effect of the variation in metal and ligand on electronic and electrochemical characteristics of these complexes has been investigated by using UV-vis, solution electrochemistry, and a combination of these techniques in spectroelectrochemical experiments. DFT calculations have been performed on trans-[RuCl(P{intersection}P){sub 2}{sub {double_bond}}C{sub {double_bond}}C{sub {double_bond}}(4,5-diazafluoren-9-yl)]{sup q} (P{intersection}P = dppm, bis(dimethylphosphino)methane (dmpm); q = -1, 0, +1, +2) and subsequently solvent-corrected calculations with use of COSMO were also undertaken to examine the nature of electronic transitions in various oxidation states.

  2. Crystallization and doping of amorphous silicon on low temperature plastic

    DOE Patents [OSTI]

    Kaschmitter, J.L.; Truher, J.B.; Weiner, K.H.; Sigmon, T.W.

    1994-09-13

    A method or process of crystallizing and doping amorphous silicon (a-Si) on a low-temperature plastic substrate using a short pulsed high energy source in a selected environment, without heat propagation and build-up in the substrate is disclosed. The pulsed energy processing of the a-Si in a selected environment, such as BF3 and PF5, will form a doped micro-crystalline or poly-crystalline silicon (pc-Si) region or junction point with improved mobilities, lifetimes and drift and diffusion lengths and with reduced resistivity. The advantage of this method or process is that it provides for high energy materials processing on low cost, low temperature, transparent plastic substrates. Using pulsed laser processing a high (>900 C), localized processing temperature can be achieved in thin films, with little accompanying temperature rise in the substrate, since substrate temperatures do not exceed 180 C for more than a few microseconds. This method enables use of plastics incapable of withstanding sustained processing temperatures (higher than 180 C) but which are much lower cost, have high tolerance to ultraviolet light, have high strength and good transparency, compared to higher temperature plastics such as polyimide. 5 figs.

  3. Crystallization and doping of amorphous silicon on low temperature plastic

    DOE Patents [OSTI]

    Kaschmitter, James L. (Pleasanton, CA); Truher, Joel B. (Palo Alto, CA); Weiner, Kurt H. (Campbell, CA); Sigmon, Thomas W. (Beaverton, OR)

    1994-01-01

    A method or process of crystallizing and doping amorphous silicon (a-Si) on a low-temperature plastic substrate using a short pulsed high energy source in a selected environment, without heat propagation and build-up in the substrate. The pulsed energy processing of the a-Si in a selected environment, such as BF3 and PF5, will form a doped micro-crystalline or poly-crystalline silicon (pc-Si) region or junction point with improved mobilities, lifetimes and drift and diffusion lengths and with reduced resistivity. The advantage of this method or process is that it provides for high energy materials processing on low cost, low temperature, transparent plastic substrates. Using pulsed laser processing a high (>900.degree. C.), localized processing temperature can be achieved in thin films, with little accompanying temperature rise in the substrate, since substrate temperatures do not exceed 180.degree. C. for more than a few microseconds. This method enables use of plastics incapable of withstanding sustained processing temperatures (higher than 180.degree. C.) but which are much lower cost, have high tolerance to ultraviolet light, have high strength and good transparency, compared to higher temperature plastics such as polyimide.

  4. VERIFICATION OF THE DEFENSE WASTE PROCESSING FACILITY'S (DWPF) PROCESS DIGESTION METHOD FOR THE SLUDGE BATCH 7A QUALIFICATION SAMPLE

    SciTech Connect (OSTI)

    Click, D.; Edwards, T.; Jones, M.; Wiedenman, B.

    2011-03-14

    For each sludge batch that is processed in the Defense Waste Processing Facility (DWPF), the Savannah River National Laboratory (SRNL) performs confirmation of the applicability of the digestion method to be used by the DWPF lab for elemental analysis of Sludge Receipt and Adjustment Tank (SRAT) receipt samples and SRAT product process control samples. DWPF SRAT samples are typically dissolved using a room temperature HF-HNO{sub 3} acid dissolution (i.e., DWPF Cold Chem Method, see DWPF Procedure SW4-15.201) and then analyzed by inductively coupled plasma - atomic emission spectroscopy (ICP-AES). This report contains the results and comparison of data generated from performing the Aqua Regia (AR), Sodium peroxide/Hydroxide Fusion (PF) and DWPF Cold Chem (CC) method digestions of Sludge Batch 7a (SB7a) SRAT Receipt and SB7a SRAT Product samples. The SB7a SRAT Receipt and SB7a SRAT Product samples were prepared in the SRNL Shielded Cells, and the SRAT Receipt material is representative of the sludge that constituates the SB7a Batch or qualification composition. This is the sludge in Tank 51 that is to be transferred into Tank 40, which will contain the heel of Sludge Batch 6 (SB6), to form the Sb7a Blend composition.

  5. Intruder negative-parity states of neutron-rich {sup 33}Si

    SciTech Connect (OSTI)

    Wang, Z. M.; Chapman, R.; Liang, X.; Burns, M.; Hodsdon, A.; Keyes, K.; Kumar, V.; Papenberg, A.; Smith, J. F.; Spohr, K. M.; Haas, F.; Bouhelal, M.; Caurier, E.; Curien, D.; Nowacki, F.; Azaiez, F.; Ibrahim, F.; Verney, D.; Behera, B. R.; Corradi, L.

    2010-06-15

    Yrast states in the neutron-rich {sub 14}{sup 33}Si{sub 19} nucleus have been studied using binary grazing reactions produced by the interaction of a 215-MeV beam of {sup 36}S ions with a thin {sup 208}Pb target. An experimental setup that combines the large-acceptance magnetic spectrometer PRISMA and the high-efficiency gamma-ray detection array CLARA was used in the experiment. Four new gamma-ray photopeaks at energies of 971, 1724, 1772, and 2655 keV were observed and assigned to the {sup 33}Si level scheme. The experimental level scheme is compared with the results of 1(Planck constant/2pi)omega p-sd-pf large-scale shell-model calculations using the recently developed PSDPFB effective interaction; good agreement is obtained. The structure of the populated states of {sup 33}Si is discussed within the context of an odd neutron coupled to states of the {sup 32}Si core.

  6. Lifetime measurements in {sup 63}Co and {sup 65}Co

    SciTech Connect (OSTI)

    Dijon, A.; Clement, E.; France, G. de; Van Isacker, P.; Rejmund, M.; Schmitt, C.; Goergen, A.; Obertelli, A.; Korten, W.; Dewald, A.; Hackstein, M.; Pissulla, Th.; Rother, W.; Zell, K. O.; Gadea, A.; Gaudefroy, L.; Mengoni, D.; Recchia, F.; Sahin, E.

    2011-06-15

    Lifetimes of the 9/2{sub 1}{sup -} and 3/2{sub 1}{sup -} states in {sup 63}Co and the 9/2{sub 1}{sup -} state in {sup 65}Co were measured using the recoil distance Doppler shift and the differential decay curve methods. The nuclei were populated by multinucleon transfer reactions in inverse kinematics. {gamma} rays were measured with the EXOGAM Ge array and the recoiling fragments were fully identified using the large-acceptance VAMOS spectrometer. The E2 transition probabilities from the 3/2{sub 1}{sup -} and 9/2{sub 1}{sup -} states to the 7/2{sup -} ground state could be extracted in {sup 63}Co as well as an upper limit for the 9/2{sub 1}{sup -}{yields}7/2{sub 1}{sup -} B(E2) value in {sup 65}Co. The experimental results were compared to large-scale shell-model calculations in the pf and pfg{sub 9/2} model spaces, allowing us to draw conclusions on the single-particle or collective nature of the various states.

  7. Phenomenology of the minimal inflation scenario: inflationary trajectories and particle production

    E-Print Network [OSTI]

    Luis Alvarez-Gaume; Cesar Gomez; Raul Jimenez

    2012-03-06

    We discuss the phenomenology of the minimal inflation scenario. We concentrate on two aspects: inflationary trajectories and particle production. Our findings can be summarized in two main results: first, that inflationary trayectories that are very flat and provide enough number of e-foldings are natural in the scenario without fine tunning. We present a general formalism to identify attractors in multi-field inflation regardless of trajectories fulfilling the slow-roll conditions. We then explore particle production in the model and show how the inflaton naturally transmutes into a dark matter particle. One interesting feature of our model is that it provides a novel mechanism to generate particles and entropy in the universe: the filling of the Fermi sphere up to a given momentum p_F due to the sea of goldstinos that are an important part of the matter generated after inflation. With this mechanism in hand we predict that the gravitino should have a mass of > 100-1000 TeV. Another interesting feature of our model is that the predicted level of gravity waves is r=0.1 - 0.001, which is in the range of detectability from Planck and upcoming CMB polarization experiments.

  8. Investigating the low-temperature impedance increase of lithium-ion cells.

    SciTech Connect (OSTI)

    Abraham, D. P.; Heaton, J. R.; Kang, S.-H.; Dees, D. W.; Jansen, A. N.; Chemical Engineering

    2008-01-01

    Low-temperature performance loss is a significant barrier to commercialization of lithium-ion cells in hybrid electric vehicles. Increased impedance, especially at temperatures below 0 C, reduces the cell pulse power performance required for cold engine starts, quick acceleration, or regenerative braking. Here we detail electrochemical impedance spectroscopy data on binder- and carbon-free layered-oxide and spinel-oxide electrodes, obtained over the +30 to ?30 C temperature range, in coin cells containing a lithium-preloaded Li{sub 4/3}Ti{sub 5/3}O{sub 4} composite (LTOc) counter electrode and a LiPF{sub 6}-bearing ethylene carbonate/ethyl methyl carbonate electrolyte. For all electrodes studied, the impedance increased with decreasing cell temperature; the increases observed in the midfrequency arc dwarfed the increases in ohmic resistance and diffusional impedance. Our data suggest that the movement of lithium ions across the electrochemical interface on the active material may have been increasingly hindered at lower temperatures, especially below 0 C. Low-temperature performance may be improved by modifying the electrolyte-active material interface (for example, through electrolyte composition changes). Increasing surface area of active particles (for example, through nanoparticle use) can lower the initial electrode impedance and lead to lower cell impedances at -30 C.

  9. Polarizability effects on the structure and dynamics of ionic liquids

    SciTech Connect (OSTI)

    Cavalcante, Ary de Oliveira; Ribeiro, Mauro C. C.; Skaf, Munir S.

    2014-04-14

    Polarization effects on the structure and dynamics of ionic liquids are investigated using molecular dynamics simulations. Four different ionic liquids were simulated, formed by the anions Cl{sup ?} and PF{sub 6}{sup ?}, treated as single fixed charge sites, and the 1-n-alkyl-3-methylimidazolium cations (1-ethyl and 1-butyl-), which are polarizable. The partial charge fluctuation of the cations is provided by the electronegativity equalization model (EEM) and a complete parameter set for the cations electronegativity (?) and hardness (J) is presented. Results obtained from a non-polarizable model for the cations are also reported for comparison. Relative to the fixed charged model, the equilibrium structure of the first solvation shell around the imidazolium cations shows that inclusion of EEM polarization forces brings cations closer to each other and that anions are preferentially distributed above and below the plane of the imidazolium ring. The polarizable model yields faster translational and reorientational dynamics than the fixed charges model in the rotational-diffusion regime. In this sense, the polarizable model dynamics is in better agreement with the experimental data.

  10. Detecting Crowdsourced Spam Reviews in Social Media 

    E-Print Network [OSTI]

    Fayazi, Amir A

    2013-11-25

    C1 1079 14.5 C2 285 31.1 C3 1273 13.0 Everything Else 5217 2.3 31 T ab le 5. 4: Id en ti fie d gr ou ps of co lla b or at in g re vi ew er s C lu st er C ha ra ct er is ti cs R ea l N am e % M or e H el pf ul on Fa - vo ra bl e R ev ie w s M or e V... er ifi ed P ur - ch as es on Fa vo ra bl e R ev ie w s M ed ia n L og -R ev ie w L en gt h % C 1 P os te d de ce pt iv e re vi ew s fo r th e sa m e se t of m os tl y he al th an d b ea ut y pr od uc ts 14 % 14 % 31 % 5. 5 C 2 P os te d de ce pt iv e...

  11. Certain aspects of shear stresses in tapered cantilever beams as revealed through photoelasticity 

    E-Print Network [OSTI]

    Perry, John Vivian

    1954-01-01

    ~p~ + Yg JpJg)6 +P) + Ah o ~~gg~r~o ~ooy Cm) 8 Smaze FZFwrZnr7 dpcvpnp or ~ ~wSF/C' ~ooy cohFgws peur s g 8A'/sr g QT pp' oA' g+~ p' &g/s o+ &h4 I gP I 6'+o4 DEFdk'AWE' THF pdw7$ ISSPhtd AS/TAWS Jf 7 0/ A Q AAfo c' +Fsp~7/k wc y~ o ' APE/wc& r...-?-~~~) P' s p/vg ~ ( Op -~Pp) r ore mum's ZnW~rz srWArM i 4d& &WC+ g~ %jag p a( ( ) 8$ rNb w 7+F cpn/pg Fr gA' r1 y Eg 4rgTlp A/ = ~ L~ ? e(c ~ -?~~) ~ ?, (g mc?)7 rr 8 w~ ~I 9p 8p L~g 2 p~& p Hl/w~j ~& 3 ('~ ~~)~ 8 (' ~~) / ) 8g + dr PF4Fn...

  12. Assessment of the Electrohol process to manufacture acetaldehyde from ethanol electrogeneratively. Final report

    SciTech Connect (OSTI)

    Trevino, A.A.

    1985-04-10

    Preliminary process economics data for the electrogenerative process to manufacture acetaldehyde from ethanol were generated based on patent information. The technology was assessed in four alternative processing options. The Electrohol process is viable in the US only if integrated to the production of 190 pf ethanol from corn in a large scale unit. To be competitive, the Electrohol process must show yields in excess of 93%. Its attractiveness depends on corn prices remaining under $2.90/bu and DDG selling for more than $132/T. A corn price of $2.00/bu is needed to make a farm-size corn-based processing alternative competitive. A plant based on the fermentation of molasses proved too expensive under the US economic assumptions. The Electrohol technology based on purchased ethanol cannot compete with the existing ethylene-based process under current conditions. To become attractive, the Electrohol process must have access to cheap ethanol ($1.43/gal). The zero electricity generation mode is the most attractive mode of operation for the Electrohol technology in the US. The penalty for low levels of generation (0.130 kwh/kg AcH) is, however, negligible. The optimum operating mode in W. Europe is the generation of 0.312 kwh/kg AcH. In Japan, the low generation level is perferred (0.130 kwh/kg AcH). In general, higher energy prices improve the competitiveness of the Electrohol processing alternatives.

  13. Importance-Truncated Large-Scale Shell Model

    E-Print Network [OSTI]

    Stumpf, Christina; Roth, Robert

    2015-01-01

    We propose an importance-truncation scheme for the large-scale nuclear shell model that extends its range of applicability to larger valence spaces and mid-shell nuclei. It is based on a perturbative measure for the importance of individual basis states that acts as an additional truncation for the many-body model space in which the eigenvalue problem of the Hamiltonian is solved numerically. Through a posteriori extrapolations of all observables to vanishing importance threshold, the full shell-model results can be recovered. In addition to simple threshold extrapolations, we explore extrapolations based on the energy variance. We apply the importance-truncated shell model for the study of 56-Ni in the pf valence space and of 60-Zn and 64-Ge in the pfg9/2 space. We demonstrate the efficiency and accuracy of the approach, which pave the way for future shell-model calculations in larger valence spaces with valence-space interactions derived in ab initio approaches.

  14. Neutron production from puffing deuterium in plasma focus device

    SciTech Connect (OSTI)

    Kubes, P.; Cikhardt, J.; Kortanek, J.; Batobolotova, B.; Rezac, K.; Klir, D.; Kravarik, J. [Czech Technical University, Prague (Czech Republic); Paduch, M.; Zielinska, E. [Institute of Plasma Physics and Laser Microfusion, Warsaw (Poland); Surala, W.; Sadowski, M. J. [National Centre for Nuclear Research, Otwock, ?wierk (Poland); Scholz, M. [Institute of Nuclear Physics, Krakow (Poland); Karpinski, L. [Rzeszow University of Technology, Rzeszow (Poland)

    2014-08-15

    The current research has continued on the PF-1000 plasma focus device at the current of 2 MA by comparison of the shots with and without injected deuterium. The increase of the total neutron yield at the level of 10{sup 10}–10{sup 11} per shot was achieved after the compression of about 10??g/cm of the deuterium from the gas-valve by about 46??g/cm of the neon or deuterium plasma sheath. It increases five times at the decrease of the puffing deuterium mass to one-half. In shots with neon in the chamber and with puffing deuterium, a considerable decrease was confirmed of the soft X-ray emission in comparison with shots without deuterium injection. This decrease can be explained by the absence of the neon in the region of the compressed and hot plasma. The deuterium plasma from the gas-puff should then be confined in the internal structures both in the phase of implosion as well as during their formation and transformation. In shots with puffing deuterium, the evolution of instabilities in the plasma column was suppressed. The deuterium plasma has a higher conductance and better ability to form expressive and dense plasmoids and to transport the internal current in comparison with neon plasma. Neutrons were produced both at the initial phase of stagnation, as well as at a later time at the evolution of the constrictions and dense plasmoids.

  15. Review of Wind Energy Forecasting Methods for Modeling Ramping Events

    SciTech Connect (OSTI)

    Wharton, S; Lundquist, J K; Marjanovic, N; Williams, J L; Rhodes, M; Chow, T K; Maxwell, R

    2011-03-28

    Tall onshore wind turbines, with hub heights between 80 m and 100 m, can extract large amounts of energy from the atmosphere since they generally encounter higher wind speeds, but they face challenges given the complexity of boundary layer flows. This complexity of the lowest layers of the atmosphere, where wind turbines reside, has made conventional modeling efforts less than ideal. To meet the nation's goal of increasing wind power into the U.S. electrical grid, the accuracy of wind power forecasts must be improved. In this report, the Lawrence Livermore National Laboratory, in collaboration with the University of Colorado at Boulder, University of California at Berkeley, and Colorado School of Mines, evaluates innovative approaches to forecasting sudden changes in wind speed or 'ramping events' at an onshore, multimegawatt wind farm. The forecast simulations are compared to observations of wind speed and direction from tall meteorological towers and a remote-sensing Sound Detection and Ranging (SODAR) instrument. Ramping events, i.e., sudden increases or decreases in wind speed and hence, power generated by a turbine, are especially problematic for wind farm operators. Sudden changes in wind speed or direction can lead to large power generation differences across a wind farm and are very difficult to predict with current forecasting tools. Here, we quantify the ability of three models, mesoscale WRF, WRF-LES, and PF.WRF, which vary in sophistication and required user expertise, to predict three ramping events at a North American wind farm.

  16. Static characterization of a soft elastomeric capacitor for non destructive evaluation applications

    SciTech Connect (OSTI)

    Saleem, Hussam; Laflamme, Simon; Zhang, Huanhuan; Geiger, Randall; Kessler, Michael; Rajan, Krishna

    2014-02-18

    A large and flexible strain transducer consisting of a soft elastomeric capacitor (SEC) has been proposed by the authors. Arranged in a network setup, the sensing strategy offers tremendous potential at conducting non-destructive evaluation of large-scale surfaces. In prior work, the authors have demonstrated the performance of the sensor at tracking strain history, localizing cracks, and detecting vibration signatures. In this paper, we characterize the static performance of the proposed SEC. The characterization includes sensitivity of the signal, and temperature and humidity dependences. Tests are conducted on a simply supported aluminum beam subjected to bending as well as on a free standing sensor. The performance of the SEC is compared against off-the-shelf resistance-based strain gauges with resolution of 1 ??. A sensitivity of 1190 pF/? is obtained experimentally, in agreement with theory. Results also show the sensor linearity over the given level of strain, showing the promise of the SEC at monitoring of surface strain.

  17. Highly Quantitative Electrochemical Characterization of Non-Aqueous Electrolytes & Solid Electrolyte Interphases

    SciTech Connect (OSTI)

    Sergiy V. Sazhin; Kevin L. Gering; Mason K. Harrup; Harry W. Rollins

    2012-10-01

    The methods to measure solid electrolyte interphase (SEI) electrochemical properties and SEI formation capability of non-aqueous electrolyte solutions are not adequately addressed in the literature. And yet, there is a strong demand in new electrolyte generations that promote stabilized SEIs and have an influence to resolve safety, calendar life and other limitations of Li-ion batteries. To fill this gap, in situ electrochemical approach with new descriptive criteria for highly quantitative characterization of SEI and electrolytes is proposed. These criteria are: SEI formation capacity, SEI corrosion rate, SEI maintenance rate, and SEI kinetic stability. These criteria are associated with battery parameters like irreversible capacity, self-discharge, shelf-life, power, etc. Therefore, they are especially useful for electrolyte development and standard fast screening, allowing a skillful approach to narrow down the search for the best electrolyte. The characterization protocol also allows retrieving information on interfacial resistance for SEI layers and the electrochemical window of electrolytes, the other important metrics of characterization. The method validation was done on electrolyte blends containing phosphazenes, developed at Idaho National Laboratory, as 1.2M LiPF6 [80 % EC-MEC (2:8) (v/v) + 20% Phosphazene variety] (v/v), which were targeted for safer electrolyte variations.

  18. Los Alamos PWR feed-and-bleed studies summary results and conclusions

    SciTech Connect (OSTI)

    Boyack, B.E.; Henninger, R.J.; Lime, J.F.

    1985-01-01

    The adequacy of shutdown decay heat removal in pressurized water reactors (PWRs) is currently under investigation by the Nuclear Regulatory Commission. One part of this effort is review of feed-and-bleed procedures that could be used if the normal cooling mode through the steam generators was unavailable. Feed-and-bleed cooling is effected by manually activating the high-pressure injection (HPI) system and opening the power-operated relief valves (PORVs) to release the core decay energy. The feasibility of the feed-and-bleed concept as a diverse mode of heat removal has been evaluated at the Los Alamos National Laboratory. The TRAC-PF1 code has been used to predict the expected performances of the Oconee-1 and Calvert Cliffs-1 reactors of Babcock and Wilcox and Combustion Engineering, respectively, and the Zion-1 and H.B. Robinson-2 plants of Westinghouse. Feed and bleed was successfully applied in each of the four plants studied, provided it was initiated no later than the time of loss-of-secondary heat sink.

  19. Self-consistent simulation of plasma scenarios for ITER using a combination of 1.5D transport codes and free-boundary equilibrium codes

    E-Print Network [OSTI]

    Parail, V; Ambrosino, R; Artaud, J-F; Besseghir, K; Cavinato, M; Corrigan, G; Garcia, J; Garzotti, L; Gribov, Y; Imbeaux, F; Koechl, F; Labate, C V; Lister, J; Litaudon, X; Loarte, A; Maget, P; Mattei, M; McDonald, D; Nardon, E; Saibene, G; Sartori, R; Urban, J

    2013-01-01

    Self-consistent transport simulation of ITER scenarios is a very important tool for the exploration of the operational space and for scenario optimisation. It also provides an assessment of the compatibility of developed scenarios (which include fast transient events) with machine constraints, in particular with the poloidal field (PF) coil system, heating and current drive (H&CD), fuelling and particle and energy exhaust systems. This paper discusses results of predictive modelling of all reference ITER scenarios and variants using two suite of linked transport and equilibrium codes. The first suite consisting of the 1.5D core/2D SOL code JINTRAC [1] and the free boundary equilibrium evolution code CREATE-NL [2,3], was mainly used to simulate the inductive D-T reference Scenario-2 with fusion gain Q=10 and its variants in H, D and He (including ITER scenarios with reduced current and toroidal field). The second suite of codes was used mainly for the modelling of hybrid and steady state ITER scenarios. It...

  20. Nonaqueous electrolyte for electrical storage devices

    DOE Patents [OSTI]

    McEwen, Alan B. (Melrose, MA); Yair, Ein-Eli (Waltham, MA)

    1999-01-01

    Improved nonaqueous electrolytes for application in electrical storage devices such as electrochemical capacitors or batteries are disclosed. The electrolytes of the invention contain salts consisting of alkyl substituted, cyclic delocalized aromatic cations, and their perfluoro derivatives, and certain polyatomic anions having a van der Waals volume less than or equal to 100 .ANG..sup.3, preferably inorganic perfluoride anions and most preferably PF.sub.6.sup.-, the salts being dissolved in organic liquids, and preferably alkyl carbonate solvents, or liquid sulfur dioxide or combinations thereof, at a concentration of greater than 0.5M and preferably greater than 1.0M. Exemplary electrolytes comprise 1-ethyl-3-methylimidazolium hexafluorophosphate dissolved in a cyclic or acylic alkyl carbonate, or methyl formate, or a combination therof. These improved electrolytes have useful characteristics such as higher conductivity, higher concentration, higher energy storage capabilities, and higher power characteristics compared to prior art electrolytes. Stacked capacitor cells using electrolytes of the invention permit high energy, high voltage storage.

  1. Ultracold neutron production and up-scattering in superfluid helium between 1.1 K and 2.4 K

    E-Print Network [OSTI]

    K. K. H. Leung; S. Ivanov; F. M. Piegsa; M. Simson; O. Zimmer

    2015-07-27

    Ultracold neutrons (UCNs) were produced in a 4 liter volume of superfluid helium using the PF1B cold neutron beam facility at the Institut Laue-Langevin and then extracted to a detector at room temperature. With a converter temperature of 1.08 K the number of accumulated UCNs was counted to be $91,\\!700 \\pm 300$. From this, we derive a volumetric UCN production rate of $(6.9 \\pm 1.7)\\,\\mathrm{cm^{-3}\\,s^{-1}}$, which includes a correction for losses in the converter during UCN extraction caused by a short storage time, but not accounting for UCN transport and detection efficiencies. The up-scattering rate of UCNs due to excitations in the superfluid was studied by scanning the temperature between 1.2-2.4 K. Using the temperature-dependent UCN production rate calculated from inelastic neutron scattering data in the analysis, the only UCN up-scattering process found to be present was from two-phonon scattering. Our analysis rules out contributions from the other scattering processes to $\\lesssim 10\\%$ of their predicted levels.

  2. Ultracold neutron production and up-scattering in superfluid helium between 1.1 K and 2.4 K

    E-Print Network [OSTI]

    Leung, K K H; Piegsa, F M; Simson, M; Zimmer, O

    2015-01-01

    Ultracold neutrons (UCNs) were produced in a 4 liter volume of superfluid helium using the PF1B cold neutron beam facility at the Institut Laue-Langevin and then extracted to a detector at room temperature. With a converter temperature of 1.08 K the number of accumulated UCNs was counted to be $91,\\!700 \\pm 300$. From this, we derive a volumetric UCN production rate of $(6.9 \\pm 1.7)\\,\\mathrm{cm^{-3}\\,s^{-1}}$, which includes a correction for losses in the converter during UCN extraction caused by a short storage time, but not accounting for UCN transport and detection efficiencies. The up-scattering rate of UCNs due to excitations in the superfluid was studied by scanning the temperature between 1.2-2.4 K. Using the temperature-dependent UCN production rate calculated from inelastic neutron scattering data in the analysis, the only UCN up-scattering process found to be present was from two-phonon scattering. Our analysis rules out contributions from the other scattering processes to $\\lesssim 10\\%$ of their ...

  3. Minor antigen graft-versus-host reactions revealed in irradiated spleen and popliteal lymph node assays

    SciTech Connect (OSTI)

    Claman, H.N.; Jaffee, B.D.

    1984-10-01

    The graft-versus-hot (GVH) reaction across minor (non-H-2) histocompatibility barriers was studied in mice, in vivo. To increase GVH potential and to mimic clinical bone marrow transplantation protocols, we modified the popliteal lymph node (PLN) and the splenomegaly assays by irradiating the recipients before they received allogeneic lymphoid cell suspensions. In several combinations across major (H-2), minor (non-H-2) and multiple minor (non-H-2 plus minor lymphocyte stimulation) barriers, increased recipient organ weight (a measure of GVH activity) was seen with irradiated F1 recipients of parental cells. The irradiated splenomegaly (x-splenomegaly) assay was more sensitive than the (x-PLN) assay, but both correlated with in vivo GVH experiments of the P----F1 variety. The x-splenomegaly test indicated histoincompatibility in a system (B10.D2----BALB/c) in which the primary in vitro mixed leukocyte reactions is nonreactive, but in which systemic GVH can be induced. The x-splenomegaly test should be useful in analyzing complex reactions involving minor histocompatibility antigens in vivo.

  4. Generalized drift-flux correlation

    SciTech Connect (OSTI)

    Takeuchi, K.; Young, M.Y.; Hochreiter, L.E. (Westinghouse Electric Corp., Pittsburgh, PA (United States))

    1991-01-01

    A one-dimensional drift-flux model with five conservation equations is frequently employed in major computer codes, such as TRAC-PD2, and in simulator codes. In this method, the relative velocity between liquid and vapor phases, or slip ratio, is given by correlations, rather than by direct solution of the phasic momentum equations, as in the case of the two-fluid model used in TRAC-PF1. The correlations for churn-turbulent bubbly flow and slug flow regimes were given in terms of drift velocities by Zuber and Findlay. For the annular flow regime, the drift velocity correlations were developed by Ishii et al., using interphasic force balances. Another approach is to define the drift velocity so that flooding and liquid hold-up conditions are properly simulated, as reported here. The generalized correlation is used to reanalyze the MB-2 test data for two-phase flow in a large-diameter pipe. The results are applied to the generalized drift flux velocity, whose relationship to the other correlations is discussed. Finally, the generalized drift flux correlation is implemented in TRAC-PD2. Flow reversal from countercurrent to cocurrent flow is computed in small-diameter U-shaped tubes and is compared with the flooding curve.

  5. Studies of ionic liquids in lithium-ion battery test systems

    SciTech Connect (OSTI)

    Salminen, Justin; Prausnitz, John M.; Newman, John

    2006-06-01

    In this work, thermal and electrochemical properties of neat and mixed ionic liquid - lithium salt systems have been studied. The presence of a lithium salt causes both thermal and phase-behavior changes. Differential scanning calorimeter DSC and thermal gravimetric analysis TGA were used for thermal analysis for several imidazolium bis(trifluoromethylsulfonyl)imide, trifluoromethansulfonate, BF{sub 4}, and PF{sub 6} systems. Conductivities and diffusion coefficient have been measured for some selected systems. Chemical reactions in electrode - ionic liquid electrolyte interfaces were studied by interfacial impedance measurements. Lithium-lithium and lithium-carbon cells were studied at open circuit and a charged system. The ionic liquids studied include various imidazolium systems that are already known to be electrochemically unstable in the presence of lithium metal. In this work the development of interfacial resistance is shown in a Li|BMIMBF{sub 4} + LiBF{sub 4}|Li cell as well as results from some cycling experiments. As the ionic liquid reacts with the lithium electrode the interfacial resistance increases. The results show the magnitude of reactivity due to reduction of the ionic liquid electrolyte that eventually has a detrimental effect on battery performance.

  6. Electrospun nanocomposite fibrous polymer electrolyte for secondary lithium battery applications

    SciTech Connect (OSTI)

    Padmaraj, O.; Rao, B. Nageswara; Jena, Paramananda; Satyanarayana, N., E-mail: nallanis2011@gmail.com [Department of Physics, Pondicherry University, Pondicherry-605014 (India); Venkateswarlu, M. [R and D, Amaraja batteries, Thirupathi-517501 (India)

    2014-04-24

    Hybrid nanocomposite [poly(vinylidene fluoride -co- hexafluoropropylene) (PVdF-co-HFP)/magnesium aluminate (MgAl{sub 2}O{sub 4})] fibrous polymer membranes were prepared by electrospinning method. The prepared pure and nanocomposite fibrous polymer electrolyte membranes were soaked into the liquid electrolyte 1M LiPF{sub 6} in EC: DEC (1:1,v/v). XRD and SEM are used to study the structural and morphological studies of nanocomposite electrospun fibrous polymer membranes. The nanocomposite fibrous polymer electrolyte membrane with 5 wt.% of MgAl{sub 2}O{sub 4} exhibits high ionic conductivity of 2.80 × 10{sup ?3} S/cm at room temperature. The charge-discharge capacity of Li/LiCoO{sub 2} coin cells composed of the newly prepared nanocomposite [(16 wt.%) PVdF-co-HFP+(5 wt.%) MgAl{sub 2}O{sub 4}] fibrous polymer electrolyte membrane was also studied and compared with commercial Celgard separator.

  7. UCN production by multiphonon processes in superfluid Helium under pressure

    E-Print Network [OSTI]

    P. Schmidt-Wellenburg; K. H. Andersen; O. Zimmer

    2009-01-29

    Cold neutrons are converted to ultra-cold neutrons (UCN) by the excitation of a single phonon or multiphonons in superfluid helium. The dynamic scattering function S(q, omega) of the superfluid helium strongly depends on pressure, leading to a pressure- dependent differential UCN production rate. A phenomenological expression for the multiphonon part of the scattering function s(lambda) describing UCN production has been derived from inelastic neutron scattering data. When combined with the production rate from single phonon processes this allows us to calculate the UCN production for any incident neutron flux. For calculations of the UCN production from single phonon processes we propose to use the values for S*(SVP) = 0.118(8) and S*(20 bar) = 0.066(6). As an example we will calculate the expected UCN production rate at the cold neutron beam for fundamental physics PF1b at the Institut Laue Langevin. We conclude that UCN production in superfluid helium under pressure is not attractive.

  8. Progression of soot cake layer properties during the systematic regeneration of diesel particulate filters measured with neutron tomography

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Toops, Todd J.; Pihl, Josh A.; Finney, Charles E. A.; Gregor, Jens; Bilheux, Hassina

    2015-01-16

    Although particulate filters (PFs) have been a key component of the emission control system for modern diesel engines, there remain significant questions about the basic regeneration behavior of the filters and how it changes with accumulation of increasing soot layers. This effort describes a systematic deposition and regeneration of particulate matter in 25-mm diameter × 76-mm long wall-flow PFs composed of silicon carbide (SiC) material. The initial soot distributions were analyzed for soot cake thickness using a nondestructive neutron imaging technique. With the PFs intact, it was then possible to sequentially regenerate the samples and reanalyze them, which was performedmore »after nominal 20, 50, and 70 % regenerations. The loaded samples show a relatively uniform distribution of particulate with an increasing soot cake thickness and nearly identical initial density of 70 mg/cm3. Throughout regeneration, the soot cake thickness initially decreases significantly while the density increases to 80–90 mg/cm3. After ~50 % regeneration, the soot cake thickness stays relatively constant, but instead, the density decreases as pores open up in the layer (~35 mg/cm3 at 70 % regeneration). Complete regeneration initially occurs at the rear of the PF channels. With this information, a conceptual model of the regeneration is proposed.« less

  9. Rhodium mediated bond activation: from synthesis to catalysis

    SciTech Connect (OSTI)

    Ho, Hung-An

    2012-03-06

    Recently, our lab has developed monoanionic tridentate ligand, To{sup R}, showing the corresponding coordination chemistry and catalyst reactivity of magnesium, zirconium, zinc and iridium complexes. This thesis details synthetic chemistry, structural study and catalytic reactivity of the To{sup R}-supported rhodium compounds. Tl[To{sup R}] has been proved to be a superior ligand transfer agent for synthesizing rhodium complexes. The salt metathesis route of Tl[To{sup M}] with [Rh({mu}-Cl)(CO)]{sub 2} and [Rh({mu}- Cl)(COE)]{sub 2} gives To{sup M}Rh(CO){sub 2} (2.2) and To{sup M}RhH({eta}{sup 3}-C{sub 8}H{sub 13}) (3.1) respectively while Tl[To{sup P}] with [Rh({mu}-Cl)(CO)]{sub 2} affords To{sup P}Rh(CO){sub 2} (2.3). 2.2 reacts with both strong and weak electrophiles, resulting in the oxazoline N-attacked and the metal center-attacked compounds correspondingly. Using one of the metal center-attacked electrophiles, 2.3 was demonstrated to give high diastereoselectivity. Parallel to COE allylic C-H activation complex 3.1, the propene and allylbenzene allylic C-H activation products have also been synthesized. The subsequent functionalization attempts have been examined by treating with Brønsted acids, Lewis acids, electrophiles, nucleophiles, 1,3-dipolar reagents and reagents containing multiple bonds able to be inserted. Various related complexes have been obtained under these conditions, in which one of the azide insertion compounds reductively eliminates to give an allylic functionalization product stoichiometrically. 3.1 reacts with various primary alcohols to give the decarbonylation dihydride complex To{sup M}Rh(H){sub 2}CO (4.1). 4.1 shows catalytic reactivity for primary alcohol decarbonylation under a photolytic condition. Meanwhile, 2.2 has been found to be more reactive than 4.1 for catalytic alcohol decarbonylation under the same condition. Various complexes and primary alcohols have been investigated as well. The proposed mechanism is based on the stochiometric reactions of the possible metal and organic intermediates. Primary amines, hypothesized to undergo a similar reaction pathway, have been verified to give dehydrogenative coupling product, imines. In the end, the well-developed neutral tridentate Tpm coordinates to the rhodium bis(ethylene) dimer in the presence of TlPF{sub 6} to give the cationic complex, [TpmRh(C{sub 2}H{sub 4}){sub 2}][PF{sub 6}] (5.1). 5.1 serves as the first example of explicit determination of the solid state hapticity, evidenced by X-ray structure, among all the cationic Tpm{sup R}M(C{sub 2}H{sub 4}){sub 2}{sup +} (Tpm{sup R} = Tpm, Tpm*, M = Rh, Ir) derivatives. The substitution chemistry of this compound has been studied by treating with soft and hard donors. The trimethylphosphine-sbustituted complex activates molecular hydrogen to give the dihydride compound.

  10. Excitation energy dependence of fission in the mercury region

    E-Print Network [OSTI]

    J. D. McDonnell; W. Nazarewicz; J. A. Sheikh; A. Staszczak; M. Warda

    2014-06-26

    Background: Recent experiments on beta-delayed fission reported an asymmetric mass yield in the neutron-deficient nucleus 180Hg. Earlier experiments in the mass region A=190-200 close to the beta-stability line, using the (p,f) and (\\alpha,f) reactions, observed a more symmetric distribution of fission fragments. While the beta-delayed fission of 180Hg can be associated with relatively low excitation energy, this is not the case for light-ion reactions, which result in warm compound nuclei. Purpose: To elucidate the roles of proton and neutron numbers and excitation energy in determining symmetric and asymmetric fission yields, we compute and analyze the isentropic potential energy surfaces of 174,180,198Hg and 196,210Po. Methods: We use the finite-temperature superfluid nuclear density functional theory, for excitation energies up to E*=30MeV and zero angular momentum. For our theoretical framework, we consider the Skyrme energy density functional SkM* and a density-dependent pairing interaction. Results: For 174,180Hg, we predict fission pathways consistent with asymmetric fission at low excitation energies, with the symmetric fission pathway opening very gradually as excitation energy is increased. For 198Hg and 196Po, we expect the nearly-symmetric fission channel to dominate. 210Po shows a preference for a slightly asymmetric pathway at low energies, and a preference for a symmetric pathway at high energies. Conclusions: Our self-consistent theory suggests that excitation energy weakly affects the fission pattern of the nuclei considered. The transition from the asymmetric fission in the proton-rich nuclei to a more symmetric fission in the heavier isotopes is governed by the shell structure of pre-scission configurations.

  11. Screening of low cost sorbents for arsenic and mercury capture in gasification systems

    SciTech Connect (OSTI)

    Cedric Charpenteau; Revata Seneviratne; Anthe George; Marcos Millan; Denis R. Dugwell; Rafael Kandiyoti

    2007-09-15

    A novel laboratory-scale fixed-bed reactor has been developed to investigate trace metal capture on selected sorbents for cleaning the hot raw gas in Integrated Gasification Combined Cycle (IGCC) power plants. The new reactor design is presented, together with initial results for mercury and arsenic capture on five sorbents. It was expected that the capture efficiency of sorbents would decrease with increasing temperature. However, a commercial activated carbon, Norit Darco 'Hg', and a pyrolysis char prepared from scrap tire rubber exhibit similar efficiencies for arsenic at 200 and at 400{sup o}C (70% and 50%, respectively). Meta-kaolinite and fly ash both exhibit an efficiency of around 50% at 200{sup o}C, which then dropped as the test temperature was increased to 400{sup o}C. Activated scrap tire char performed better at 200{sup o}C than the pyrolysis char showing an arsenic capture capacity similar to that of commercial Norit Darco 'Hg'; however, efficiency dropped to below 40% at 400{sup o}C. These results suggest that the capture mechanism of arsenic (As4) is more complex than purely physical adsorption onto the sorbents. Certain elements within the sorbents may have significant importance for chemical adsorption, in addition to the effect of surface area, as determined by the BET method. This was indeed the case for the mercury capture efficiency for all four sorbents tested. Three of the sorbents tested retained 90% of the mercury when operated at 100{sup o}C. As the temperature increased, the efficiency of activated carbon and pyrolysis char reduced significantly. Curiously, despite having the smallest Brunauer-Emmet-Teller (BET) surface area, a pf-combustion ash was the most effective in capturing mercury over the temperature range studied. These observations suggest that the observed mercury capture was not purely physical adsorption but a combination of physical and chemical processes. 27 refs., 4 figs., 4 tabs.

  12. Report on 238Pu(n,x) surrogate cross section measurement

    SciTech Connect (OSTI)

    Burke, J T; Ressler, J J; Henderson, R A; Scielzo, N D; Escher, J E; Thompson, I J; Gostic, J; Bleuel, D; Weideking, M; Bernstein, L A

    2010-03-31

    The goal of this year's effort is to measure the {sup 238}Pu(n,f) and {sup 238}Pu(n,2n) cross section from 100 keV to 20 MeV. We designed a surrogate experiment that used the reaction {sup 239}Pu(a,a{prime}x) as a surrogate for {sup 238}Pu(n,x). The experiment was conducted using the STARS/LIBERACE experimental facility located at the 88 Inch Cyclotron at Lawrence Berkeley National Laboratory in January 2010. A description of the experiment and status of the data analysis is given. In order to obtain a reliable {sup 238}Pu(n,x) cross section we designed the experiment using the surrogate ratio technique. This technique allows one to measure a desired, unknown, cross section relative to a known cross section. In the present example, the {sup 238}Pu(n,x) cross section of interest is determined relative to the known {sup 235}U(n,x) cross section. To increase confidence in the results, and to reduce overall uncertainties, we are also determining the {sup 238}Pu(n,x) cross section relative to the known {sup 234}U(n,x) cross section. The compound nuclei of interest for this experiment were produced using inelastic alpha scattering. For example, {sup 236}U(a,a{prime}x) served as a surrogate for {sup 235}U(n,x); analogous reactions were considered for the other cross sections. Surrogate experiments determine the probabilities for the decay of the compound nuclei into the various channels of interest (fission, gamma decay) by measuring particle-fission (p-f) or particle?gamma (p?g) reaction spectra. By comparing the decay probabilities associated with the unknown cross section to that of a known cross section it is possible to obtain the ratio of these cross sections and thus determine the unknown, desired cross section.

  13. Nuclear quantum effects on the structure and the dynamics of [H{sub 2}O]{sub 8} at low temperatures

    SciTech Connect (OSTI)

    Videla, Pablo E.; Rossky, Peter J.; Laria, D.

    2013-11-07

    We use ring-polymer-molecular-dynamics (RPMD) techniques and the semi-empirical q-TIP4P/F water model to investigate the relationship between hydrogen bond connectivity and the characteristics of nuclear position fluctuations, including explicit incorporation of quantum effects, for the energetically low lying isomers of the prototype cluster [H{sub 2}O]{sub 8} at T = 50 K and at 150 K. Our results reveal that tunneling and zero-point energy effects lead to sensible increments in the magnitudes of the fluctuations of intra and intermolecular distances. The degree of proton spatial delocalization is found to map logically with the hydrogen-bond connectivity pattern of the cluster. Dangling hydrogen bonds exhibit the largest extent of spatial delocalization and participate in shorter intramolecular O-H bonds. Combined effects from quantum and polarization fluctuations on the resulting individual dipole moments are also examined. From the dynamical side, we analyze the characteristics of the infrared absorption spectrum. The incorporation of nuclear quantum fluctuations promotes red shifts and sensible broadening relative to the classical profile, bringing the simulation results in much more satisfactory agreement with direct experimental information in the mid and high frequency range of the stretching band. While RPMD predictions overestimate the peak position of the low frequency shoulder, the overall agreement with that reported using an accurate, parameterized, many-body potential is reasonable, and far superior to that one obtains by implementing a partially adiabatic centroid molecular dynamics approach. Quantum effects on the collective dynamics, as reported by instantaneous normal modes, are also discussed.

  14. The performance of magnetic lens for focusing VCN-SANS.

    SciTech Connect (OSTI)

    Yamada, M.; Iwashita, Y.; Kanaya, T.; Ichikawa, M.; Tongu, H.; Kennedy, S. J.; Shimizu, H. M.; Mishima, K.; Yamada, N. L.; Hirota, K.; Carpenter, J..; Lal, J.; Anderson, K.; Geltenbort, P.; Guerard, B.; Manzin, G.; Hino, M.; Kitaguchi, M.; Bleuel, M.; NOP Collaboration (Biosciences Division); ( AES); ( MSD); (Kyoto Univ.); (Bragg Inst.); (KEK, 1-1); (RIKEN, 2-1, Hirosawa, Wako); (ILL); (KURRI); (Reactor Inst.)

    2011-01-01

    We have developed a prototype rotating-permanent magnet sextupole lens (named rot-PMSx) for more efficient experiments with neutron beams in time of flight (ToF) mode. This lens can modulate the focusing strength over range 1.5 x 10{sup 4} T/m{sup 2} {le} g' {le} 5.9 x 10{sup 4} T/m{sup 2}. Synchronization between the modulation and the beam pulse produces a focused beam without significant chromatic aberration. We anticipate that this lens could be utilized in focusing small angle neutron scattering (SANS) instruments for novel approach to high resolution SANS. We carried out experiments testing the principle of this lens at the very cold neutron (VCN) beamline (PF2) at Institut Laue-Langevin (ILL), France. The focused beam image size at the detector was kept constant at the same beam size as the source ({approx} 3 mm) over a wavelength range of 30 {angstrom} {le} {lambda} {le} 48 {angstrom} in focal length of {approx} 1.14 m. The flux gain was about 12 relative to a beam without focusing, and the depth of focus was quite large. These results show the good performance of this lens and the system. Thereupon we have demonstrated the performance of this test bed for high resolution focusing of VCN-SANS for a well-studied softmatter sample; a deuterium oxide solution of Pluronic F127, an (PEO){sub 100}(PPO){sub 65}(PEO){sub 100} tri-block copolymer in deuterium oxide. The results of the focusing experiment and the focusing VCN-SANS are presented.

  15. Develop and Manufacture an airlock sliding tray

    SciTech Connect (OSTI)

    Lawton, Cindy M.

    2014-02-26

    Objective: The goal of this project is to continue to develop an airlock sliding tray and then partner with an industrial manufacturing company for production. The sliding tray will be easily installed into and removed from most glovebox airlocks in a few minutes. Technical Approach: A prototype of a sliding tray has been developed and tested in the LANL cold lab and 35 trays are presently being built for the plutonium facility (PF-4). The current, recently approved design works for a 14-inch diameter round airlock and has a tray length of approximately 20 inches. The grant will take the already tested and approved round technology and design for the square airlock. These two designs will be suitable for the majority of the existing airlocks in the multitude of DOE facilities. Partnering with an external manufacturer will allow for production of the airlock trays at a much lower cost and increase the availability of the product for all DOE sites. Project duration is estimated to be 12-13 months. Benefits: The purpose of the airlock sliding trays is fourfold: 1) Mitigate risk of rotator cuff injuries, 2) Improve ALARA, 3) Reduce risk of glovebox glove breaches and glove punctures, and 4) Improve worker comfort. I have had the opportunity to visit many other DOE facilities including Savannah, Y-12, ORNL, Sandia, and Livermore for assistance with ergonomic problems and/or injuries. All of these sites would benefit from the airlock sliding tray and I can assume all other DOE facilities with gloveboxes built prior to 1985 could also use the sliding trays.

  16. Competing quantum effects in the dynamics of a flexible water model

    E-Print Network [OSTI]

    Scott Habershon; Thomas E. Markland; David E. Manolopoulos

    2010-11-04

    Numerous studies have identified large quantum mechanical effects in the dynamics of liquid water. In this paper, we suggest that these effects may have been overestimated due to the use of rigid water models and flexible models in which the intramolecular interactions were described using simple harmonic functions. To demonstrate this, we introduce a new simple point charge model for liquid water, q-TIP4P/F, in which the O--H stretches are described by Morse-type functions. We have parameterized this model to give the correct liquid structure, diffusion coefficient, and infra-red absorption frequencies in quantum (path integral-based) simulations. By comparing classical and quantum simulations of the liquid, we find that quantum mechanical fluctuations increase the rates of translational diffusion and orientational relaxation in our model by a factor of around 1.15. This effect is much smaller than that observed in all previous simulations of simple empirical water models, which have found a quantum effect of at least 1.4 regardless of the quantum simulation method or the water model employed. The small quantum effect in our model is a result of two competing phenomena. Intermolecular zero point energy and tunneling effects destabilize the hydrogen bonding network, leading to a less viscous liquid with a larger diffusion coefficient. However this is offset by intramolecular zero point motion, which changes the average water monomer geometry resulting in a larger dipole moment, stronger intermolecular interactions, and slower diffusion. We end by suggesting, on the basis of simulations of other potential energy models, that the small quantum effect we find in the diffusion coefficient is associated with the ability of our model to produce a single broad O-H stretching band in the infra-red absorption spectrum.

  17. Determining the Radiation Damage Effect on Glovebox Glove Material.

    SciTech Connect (OSTI)

    Cournoyer, M. E.; Balkey, J. J.; Andrade, R.M.

    2005-01-01

    The Nuclear Material Technology (NMT) Division has the largest inventory of glove box gloves at Los Alamos National Laboratory. The minimization of unplanned breaches in the glovebox, e.g., glove failures, is a primary concern in the daily operations in NMT Division facilities, including the Plutonium Facility (PF-4) at TA-55 and Chemical and Metallurgy Research (CMR) Facility. Glovebox gloves in these facilities are exposed to elevated temperatures and exceptionally aggressive radiation environments (particulate {sup 239}Pu and {sup 238}Pu). Predictive models are needed to estimate glovebox glove service lifetimes, i.e. change-out intervals. Towards this aim aging studies have been initiated that correlate changes in mechanical (physical) properties with degradation chemistry. This present work derives glovebox glove change intervals based on previously reported mechanical data of thermally aged hypalon glove samples. Specifications for 30 mil tri-layered hypalon/lead glovebox gloves (TLH) and 15 mil hypalon gloves (HYP) have already been established. The relevant mechanical properties are shown on Table 1. Tensile strength is defined as the maximum load applied in breaking a tensile test piece divided by the original cross-sectional area of the test piece (Also termed maximum stress and ultimate tensile stress). Ultimate elongation is the elongation at time of rupture (Also termed maximum strain). The specification for the tensile test and ultimate elongation are the minimum acceptable values. In addition, the ultimate elongation must not vary 20% from the original value. In order to establish a service lifetimes for glovebox gloves in a thermal environment, the mechanical properties of glovebox glove materials were studied.

  18. Preconversion catalytic deoxygenation of phenolic functional groups. Quarterly technical progress report, April 1, 1992--June 30, 1992

    SciTech Connect (OSTI)

    Kubiak, C.P.

    1992-11-01

    Aryl carbon-oxygen bond cleavage is a chemical transformation of importance in coal liquefaction and the upgrading of coal liquids as well as in the synthesis of natural products. There have been numerous attempts to discover general methods for the cleavage of aryl carbon-oxygen bonds. All the stoichiometric organic methods for phenol deoxygenation have limited applications and involve expensive reagents. Catalytic method, for the hydrodeoxygenation (HDO) of phenols involve supported transition metal oxides, such as Mo/{gamma}-Al{sub 2}O{sub 3}, Ni-MO/{gamma}-Al{sub 2}O{sub 3}, Co-Mo/{gamma}-Al{sub 2}O{sub 3}, and Fe{sub 2}O{sub 3}/SiO{sub 2}. Typical phenol hydrodeoxygenation conditions involve hydrogen pressures in excess of 100 atm and temperatures in excess of 200{degrees}C. Under these conditions arene ring hydrogenation is generally found to compete with phenol deoxygenation; and the coproduct water is found to impair the activity of the catalysts. This proposed research offers the possibility of effecting the selective catalytic deoxygenation of phenolic functional groups using CO. The deoxygenation of phenols by carbon monoxide mediated by Ir(triphos)OAr has provided us with a catalytic Phenol deoxygenation pathway, through the elimination of CO{sub 2} and formation of a benzyne intermediate. Although the [Pt(triphos)(O-Ph-Me)]PF{sub 6} system is not expected to be as efficient a catalyst as some of the other transition metals systems we are currently exploring, it will provide more information about the deoxygenation mechanism in these triphos complexes. This is due to the presence of the structurally sensitive {sup 3l}P--{sup 195}Pt coupling constant and comparisons to the extensively studied Pt(dppe)(O-Ph){sub 2} systems.

  19. Once-through steam-generator sensitivity calculations

    SciTech Connect (OSTI)

    Steiner, J.L.; Siebe, D.A.

    1988-01-01

    A series of TRAC-PF1/MOD2 thermal-hydraulic calculations has been performed to determine the effect of uncertainties in modeling once through steam-generator (OTSG) secondary-side phenomena on the calculated behavior of Babcock and Wilcox power plants. The calculations were performed by varying parameters in correlations for the secondary-side phenomena. The parameters and transients were chosen to show the maximum expected sensitivity of the calculated results to the parameter variations. The parameters were then varied over a range representing the estimated uncertainty in the correlation. In this manner, the sensitivity if the calculated plant behavior to the modeling uncertainties was determined with a reasonable number of calculations. The sensitivity of calculated plant behavior to variations in interfacial heat-transfer in the OTSG secondaries was determined in a series of steam-generator overfill transient calculations. Calculations were performed for a main steam line break (MSLB) transient to quantify the sensitivity to variations in interfacial drag in the secondaries; the interfacial drag was varied in these calculations to indicate the effects of entrainment and de-entrainment processes, for which no specific models exist in the code. In addition to the transient calculations, a series of steady-state calculations was performed to determine the sensitivity of the OTSG primary-to-secondary heat transfer to the assumed fraction of tubes wetted by the auxiliary feedwater (AFW) injection. The plant model used for the sensitivity calculations was qualified by performing a benchmark calculation for a natural circulation test in the TMI-1 plant.

  20. Timing analysis of PWR fuel pin failures

    SciTech Connect (OSTI)

    Jones, K.R.; Wade, N.L.; Katsma, K.R.; Siefken, L.J. (EG and G Idaho, Inc., Idaho Falls, ID (United States)); Straka, M. (Halliburton NUS, Idaho Falls, ID (United States))

    1992-09-01

    Research has been conducted to develop and demonstrate a methodology for calculation of the time interval between receipt of the containment isolation signals and the first fuel pin failure for loss-of-coolant accidents (LOCAs). Demonstration calculations were performed for a Babcock and Wilcox (B W) design (Oconee) and a Westinghouse (W) four-loop design (Seabrook). Sensitivity studies were performed to assess the impacts of fuel pin bumup, axial peaking factor, break size, emergency core cooling system availability, and main coolant pump trip on these times. The analysis was performed using the following codes: FRAPCON-2, for the calculation of steady-state fuel behavior; SCDAP/RELAP5/MOD3 and TRACPF1/MOD1, for the calculation of the transient thermal-hydraulic conditions in the reactor system; and FRAP-T6, for the calculation of transient fuel behavior. In addition to the calculation of fuel pin failure timing, this analysis provides a comparison of the predicted results of SCDAP/RELAP5/MOD3 and TRAC-PFL/MOD1 for large-break LOCA analysis. Using SCDAP/RELAP5/MOD3 thermal-hydraulic data, the shortest time intervals calculated between initiation of containment isolation and fuel pin failure are 10.4 seconds and 19.1 seconds for the B W and W plants, respectively. Using data generated by TRAC-PF1/MOD1, the shortest intervals are 10.3 seconds and 29.1 seconds for the B W and W plants, respectively. These intervals are for a double-ended, offset-shear, cold leg break, using the technical specification maximum peaking factor and applied to fuel with maximum design bumup. Using peaking factors commensurate widi actual bumups would result in longer intervals for both reactor designs. This document also contains appendices A through J of this report.

  1. A survey for nanodiamond features in the 3 micron spectra of Herbig Ae/Be stars

    E-Print Network [OSTI]

    B. Acke; M. E. van den Ancker

    2006-06-27

    We have carried out a survey of 60 Herbig Ae/Be stars in the 3 micron wavelength region in search for the rare spectral features at 3.43 and 3.53 micron. These features have been attributed to the presence of large, hot, hydrogen-terminated nanodiamonds. Only two Herbig Ae/Be stars, HD 97048 and Elias 3-1 are known to display both these features. We have obtained medium-resolution spectra (R ~2500) with the ESO near-IR instrument ISAAC in the 3.15-3.65 micron range. In our sample, no new examples of sources with prominent nanodiamond features in their 3 micron spectra were discovered (detection rate less than 4%). We report tentative 3.53 micron detections in V921 Sco (=CD-42.11721), HD 163296 and T CrA. The sources which display the nanodiamond features are not exceptional in the group of Herbig stars with respect to disk properties, stellar characteristics, or disk and stellar activity. Moreover, the nanodiamond sources are very different from each other in terms of these parameters. We do not find evidence for a recent supernova in the vicinity of any of the nanodiamond sources. We have analyzed the PAH 3.3 micron feature and the Pfund delta hydrogen emission line, two other spectral features which occur in the 3 micron wavelength range. We reinforce the conclusion of previous authors that flared-disk systems display significantly more PAH emission than self-shadowed-disk sources. The Pf delta line detection rate is higher in self-shadowed-disk sources than in the flared-disk systems. We discuss the possible origin and paucity of the (nano)diamond features in Herbig stars. Different creation mechanisms have been proposed in the literature, amongst others in-situ and supernova-induced formation. Our data set is inconclusive in proving or disproving either formation mechanism.

  2. Changes in the peripheral blood transcriptome associated with occupational benzene exposure identified by cross-comparison on two microarray platforms

    SciTech Connect (OSTI)

    McHale, Cliona M.; Zhang, Luoping; Lan, Qing; Li, Guilan; Hubbard, Alan E.; Forrest, Matthew S.; Vermeulen, Roel; Chen, Jinsong; Shen, Min; Rappaport, Stephen M.; Yin, Songnian; Smith, Martyn T.; Rothman, Nathaniel

    2009-03-01

    Benzene is an established cause of leukemia and a possible cause of lymphoma in humans but the molecular pathways underlying this remain largely undetermined. This study sought to determine if the use of two different microarray platforms could identify robust global gene expression and pathway changes associated with occupational benzene exposure in the peripheral blood mononuclear cell (PBMC) gene expression of a population of shoe-factory workers with well-characterized occupational exposures to benzene. Microarray data was analyzed by a robust t-test using a Quantile Transformation (QT) approach. Differential expression of 2692 genes using the Affymetrix platform and 1828 genes using the Illumina platform was found. While the overall concordance in genes identified as significantly associated with benzene exposure between the two platforms was 26% (475 genes), the most significant genes identified by either array were more likely to be ranked as significant by the other platform (Illumina = 64%, Affymetrix = 58%). Expression ratios were similar among the concordant genes (mean difference in expression ratio = 0.04, standard deviation = 0.17). Four genes (CXCL16, ZNF331, JUN and PF4), which we previously identified by microarray and confirmed by real-time PCR, were identified by both platforms in the current study and were among the top 100 genes. Gene Ontology analysis showed over representation of genes involved in apoptosis among the concordant genes while Ingenuity{reg_sign} Pathway Analysis (IPA) identified pathways related to lipid metabolism. Using a two-platform approach allows for robust changes in the PBMC transcriptome of benzene-exposed individuals to be identified.

  3. Large Bore Powder Gun Qualification (U)

    SciTech Connect (OSTI)

    Rabern, Donald A.; Valdiviez, Robert

    2012-04-02

    A Large Bore Powder Gun (LBPG) is being designed to enable experimentalists to characterize material behavior outside the capabilities of the NNSS JASPER and LANL TA-55 PF-4 guns. The combination of these three guns will create a capability to conduct impact experiments over a wide range of pressures and shock profiles. The Large Bore Powder Gun will be fielded at the Nevada National Security Site (NNSS) U1a Complex. The Complex is nearly 1000 ft below ground with dedicated drifts for testing, instrumentation, and post-shot entombment. To ensure the reliability, safety, and performance of the LBPG, a qualification plan has been established and documented here. Requirements for the LBPG have been established and documented in WE-14-TR-0065 U A, Large Bore Powder Gun Customer Requirements. The document includes the requirements for the physics experiments, the gun and confinement systems, and operations at NNSS. A detailed description of the requirements is established in that document and is referred to and quoted throughout this document. Two Gun and Confinement Systems will be fielded. The Prototype Gun will be used primarily to characterize the gun and confinement performance and be the primary platform for qualification actions. This gun will also be used to investigate and qualify target and diagnostic modifications through the life of the program (U1a.104 Drift). An identical gun, the Physics Gun, will be fielded for confirmatory and Pu experiments (U1a.102D Drift). Both guns will be qualified for operation. The Gun and Confinement System design will be qualified through analysis, inspection, and testing using the Prototype Gun for the majority of process. The Physics Gun will be qualified through inspection and a limited number of qualification tests to ensure performance and behavior equivalent to the Prototype gun. Figure 1.1 shows the partial configuration of U1a and the locations of the Prototype and Physics Gun/Confinement Systems.

  4. Effects of Village Power Quality on Fuel Consumption and Operating Expenses

    SciTech Connect (OSTI)

    Richard Wies; Ron Johnson

    2008-12-31

    Alaska's rural village electric utilities are isolated from the Alaska railbelt electrical grid intertie and from each other. Different strategies have been developed for providing power to meet demand in each of these rural communities. Many of these communities rely on diesel electric generators (DEGs) for power. Some villages have also installed renewable power sources and automated generation systems for controlling the DEGs and other sources of power. For example, Lime Village has installed a diesel battery photovoltaic hybrid system, Kotzebue and Wales have wind-diesel hybrid systems, and McGrath has installed a highly automated system for controlling diesel generators. Poor power quality and diesel engine efficiency in village power systems increases the cost of meeting the load. Power quality problems may consist of poor power factor (PF) or waveform disturbances, while diesel engine efficiency depends primarily on loading, the fuel type, the engine temperature, and the use of waste heat for nearby buildings. These costs take the form of increased fuel use, increased generator maintenance, and decreased reliability. With the cost of bulk fuel in some villages approaching $1.32/liter ($5.00/gallon) a modest 5% decrease in fuel use can result in substantial savings with short payback periods depending on the village's load profile and the cost of corrective measures. This project over its five year history has investigated approaches to improving power quality and implementing fuel savings measures through the use of performance assessment software tools developed in MATLAB{reg_sign} Simulink{reg_sign} and the implementation of remote monitoring, automated generation control, and the addition of renewable energy sources in select villages. The results have shown how many of these communities would benefit from the use of automated generation control by implementing a simple economic dispatch scheme and the integration of renewable energy sources such as wind generation.

  5. Postsunset rise of F layer height in the equatorial region and its relation to the F layer dynamo polarization fields

    SciTech Connect (OSTI)

    Goel, M.K.; Singh, S.S.; Rao, B.C.N. (National Physical Lab., New Delhi (India))

    1990-05-01

    The ionosonde data are studied for equatorial station, Thumba, to delineate various features of the evening height rise of F layer. Sharp increase of h'F and h{sub p}F2 is observed in the postsunset period for high solar activity. Seasonal variation is observed in this increase of h'F and it is maximum for equinox months. For summer months, there is a delay of about an hour in the time of occurrence of h'F (peak) as compared to winter and equinox months. This delay is shown to be associated with the delay in sunset times in the conjugate E regions. As for magnetic activity dependence, it is found that this height increase is less pronounced for disturbed days for winter and equinox whereas for summer it is marginally higher over the quiet day values. Further, it is observed that the value of h'F (peak) during disturbed periods is almost at the same value of 350 km for all the three seasons. Thus the seasonal variation of magnetic activity effects appears to be mainly governed by the average seasonal variation for quiet times. The increase in F layer height is due to zonal eastward electric fields developed after sunset which is believed to be due to F region dynamo fields. While the main driving force for these fields is the zonal neutral winds, the development of these fields depend on the ratio of the F region to E region conductivity and the longitudinal gradient in the E region conductivity. Experimental observations of both the neutral winds and ionospheric conductivities are examined for their variation with solar activity, season and magnetic activity as both these factors will contribute for the various observed features of the height rise.

  6. Discovery of $^{34g,m}$Cl$(p,?)^{35}$Ar resonances activated at classical nova temperatures

    E-Print Network [OSTI]

    C. Fry; C. Wrede; S. Bishop; B. A. Brown; A. A. Chen; T. Faestermann; R. Hertenberger; A. Parikh; D. Pérez-Loureiro; H. -F. Wirth; A. García; R. Ortez

    2015-10-14

    Background: The thermonuclear $^{34g,m}$Cl($p,\\gamma$)$^{35}$Ar reaction rates are unknown due to a lack of experimental nuclear physics data. Uncertainties in these rates translate to uncertainties in $^{34}$S production in models of classical novae on oxygen-neon white dwarfs. $^{34}$S abundances have the potential to aid in the classification of presolar grains. Purpose: Determine resonance energies for the $^{34g,m}$Cl($p,\\gamma$)$^{35}$Ar reactions within the region of astrophyical interest for classical novae to a precision of a few keV as an essential first step toward constraining their thermonuclear reaction rates. Method: $^{35}$Ar excited states were populated by the $^{36}$Ar($d,t$)$^{35}$Ar reaction at $E$(d)=22~MeV and reaction products were momentum analyzed by a high resolution quadrupole-dipole-dipole-dipole (Q3D) magnetic spectrograph. Results: Seventeen new $^{35}$Ar levels have been detected at a statistically significant level in the region $E_x\\approx$~5.9-6.7~MeV ($E_r$ \\textless~800~ keV) and their excitation energies have been determined to typical uncertainties of 3~keV. The uncertainties for five previously known levels have also been reduced substantially. The measured level density was compared to those calculated using the WBMB Hamiltonian within the $sd-pf$ model space. Conclusions: Most of the resonances in the region of astrophyical interest have likely been discovered and their energies have been determined, but the resonance strengths are still unknown, and experimentally constraining the $^{34g,m}$Cl($p,\\gamma$)$^{35}$Ar reaction rates will require further experiments.

  7. Cadmium Chemical Form in Mine Waste Materials by X-ray Absorption Spectroscopy

    SciTech Connect (OSTI)

    Diacomanolis, V.; Ng, J. C. [University of Queensland, National Research Centre for Environmental Toxicology, Coopers Plains, QLD, 4008 (Australia); Sadler, R. [School of Public Health, Griffith University, Brisbane, QLD (Australia); Harris, H. H. [School of Chemistry and Physics, University of Adelaide, Adelaide, SA (Australia); Nomura, M. [Photon Factory, Institute of Material Structure Science, Tsukuba (Japan); Noller, B. N. [University of Queensland, Centre For Mined Land Rehabilitation, St Lucia 4072 QLD (Australia)

    2010-06-23

    This study examines the molecular form of cadmium (Cd) present in mine wastes by X-ray Absorption Spectroscopy (XAS; Cd>20 mg/kg) using the K-edge of Cd at the Photon Factory Advanced Ring (PF-AR), NW10A beam line at KEK-Tsukuba-Japan. Mine waste materials and zinc concentrate were analyzed for Cd by ICPMS prior to undertaking XAS (range 21-452 mg/kg). Model compounds (CdO, Cd(OH){sub 2}, CdCO{sub 3}, Cdacetate, CdS, Cdstearate, CdDEDTC) and samples were examined in solid form at 20 K. The XANES spectra showed similar E max values for both model compounds and samples. The EXAFS showed that Cd-S in CdS, gives a flatter spectrum in the extended region compared to Cd-O found with CdCO{sub 3}, CdO and Cd Stearate. Linear combination fitting with model Cd compounds did not give clear assignments of composition, indicating that more detailed EXAFS spectra is required as mineral forms containing Cd were present rather than simple Cd compounds such as CdCO{sub 3}. The Cd bond for a single shell model in mine waste sample matrices appears to be either Cd-O or Cd-S, or a combination of both. Comparison of molecular data from the XAS studies with bioaccessibility data giving a prediction of bioavailability for mine waste materials provides useful information about the significance of the cadmium form as a contaminant for health risk assessment purposes.

  8. Direct examination of cadmium bonding in rat tissues dosed with mine wastes and cadmium-containing solutions

    SciTech Connect (OSTI)

    Diacomanolis, V.; Ng, J. C. [University of Queensland, National Research Centre for Environmental Toxicology, Coopers Plains, QLD, 4008 (Australia); Sadler, R. [School of Public Health, Griffith University, Brisbane, QLD (Australia); Harris, H. H. [School of Chemistry and Physics, University of Adelaide, Adelaide, SA (Australia); Nomura, M. [Photon Factory, Institute of Material Structure Science, Tsukuba (Japan); Noller, B. N. [University of Queensland, Centre For Mined Land Rehabilitation, St Lucia 4072 QLD (Australia)

    2010-06-23

    Direct examination by XANES and EXAFS of metal bonding in tissue can be demonstrated by examining cadmium uptake and bonding in animal tissue maintained at cryogenic temperatures. XANES at the K-edge of cadmium were collected at the Photon Factory Advanced Ring (PF-AR), NW10A beam line at KEK-Tsukuba-Japan. Rats fed with 1g mine waste containing 8-400 mg/kg cadmium per 200g body weight (b.w.) or dosed by oral gavage with either cadmium chloride solution alone (at 6 mg/kg b.w.) or in combination with other salts (As, Cu or Zn), 5 days/week for 6 weeks, had 0.1-7.5 and 8-86 mg/kg cadmium in the liver or kidney, respectively. Rats given intraperitoneally (ip) or intravenously (iv) 1-4 times with 1 mg/kg b.w. cadmium solution had 30-120 mg/kg cadmium in the liver or kidney. Tissues from rats were kept and transferred at cryogenic temperature and XANES were recorded at 20 K. The spectra for rat liver samples suggested conjugation of cadmium with glutathione or association with the sulfide bond (Cd-S) of proteins and peptides. EXAFS of rat liver fed by Cd and Zn solutions showed that Cd was clearly bound to S ligands with an inter-atomic distance of 2.54 A ring for Cd-S that was similar to cadmium sulfide with an inter-atomic distance of 2.52 A ring for Cd-S. Liver or kidney of rats fed with mine wastes did not give an edge in the XANES spectra indicating little uptake of cadmium by the animals. Longer and higher dosing regimen may be required in order to observe the same Cd-S bond in the rat tissue from mine wastes, including confirmation by EXAFS.

  9. Air Conditioner Compressor Performance Model

    SciTech Connect (OSTI)

    Lu, Ning; Xie, YuLong; Huang, Zhenyu

    2008-09-05

    During the past three years, the Western Electricity Coordinating Council (WECC) Load Modeling Task Force (LMTF) has led the effort to develop the new modeling approach. As part of this effort, the Bonneville Power Administration (BPA), Southern California Edison (SCE), and Electric Power Research Institute (EPRI) Solutions tested 27 residential air-conditioning units to assess their response to delayed voltage recovery transients. After completing these tests, different modeling approaches were proposed, among them a performance modeling approach that proved to be one of the three favored for its simplicity and ability to recreate different SVR events satisfactorily. Funded by the California Energy Commission (CEC) under its load modeling project, researchers at Pacific Northwest National Laboratory (PNNL) led the follow-on task to analyze the motor testing data to derive the parameters needed to develop a performance models for the single-phase air-conditioning (SPAC) unit. To derive the performance model, PNNL researchers first used the motor voltage and frequency ramping test data to obtain the real (P) and reactive (Q) power versus voltage (V) and frequency (f) curves. Then, curve fitting was used to develop the P-V, Q-V, P-f, and Q-f relationships for motor running and stalling states. The resulting performance model ignores the dynamic response of the air-conditioning motor. Because the inertia of the air-conditioning motor is very small (H<0.05), the motor reaches from one steady state to another in a few cycles. So, the performance model is a fair representation of the motor behaviors in both running and stalling states.

  10. Development and application of LEESA (Low Energy Electrostatic Sensitivity Apparatus)

    SciTech Connect (OSTI)

    Carlson, R.S. ); Wood, R.L. )

    1990-01-01

    A precision Low Energy Electrostatic Sensitivity Apparatus (LEESA) was developed in the voltage range 0--3000 volts dc and was employed over a capacitance range of 25--50,000 pF on sensitive, very sensitive, and extremely sensitive pyrotechnic fuels and compositions. Zirconium powder, Zr/KClO{sub 4} pyrotechnic, titanium powder, Ti/KClO{sub 4} and TiH{sub x}/KClO{sub 4} pyrotechnics (x = 0.65, 1.65) and several other sensitive materials were evaluated. LEESA simulates casual human contact with potentially hazardous materials. In operation, a hand-held probe is applied to the sample to discharge the capacitance. As the probe approaches the sample, a spark jumps from the probe tip to the sample when the gap closes to the appropriate distance. This is analagous to a finger or a tool touching a sensitive material during which maneuver a spark jumps to the material. LEESA defines the probability of ignition over a voltage or energy range and is capable of thousands of trials on a test material in the span of a few hours. In addition to evaluating static sensitivity, the effect of electrode polarity, individual differences between operators, test method, humidity, sample size, particle size, capacitance, time constant RC, and voltage versus energy have been determined. The equipment is inexpensive and easy to build and use and is a low risk method because of the small quantities of sensitive material being tested at any one time. The accuracy and precision of the results surpasses that of methods currently in use. 7 refs., 11 figs., 1 tab.

  11. Accident Conditions versus Regulatory Test for NRC-Approved UF6 Packages

    SciTech Connect (OSTI)

    MILLS, G. SCOTT; AMMERMAN, DOUGLAS J.; LOPEZ, CARLOS

    2003-01-01

    The Nuclear Regulatory Commission (NRC) approves new package designs for shipping fissile quantities of UF{sub 6}. Currently there are three packages approved by the NRC for domestic shipments of fissile quantities of UF{sub 6}: NCI-21PF-1; UX-30; and ESP30X. For approval by the NRC, packages must be subjected to a sequence of physical tests to simulate transportation accident conditions as described in 10 CFR Part 71. The primary objective of this project was to relate the conditions experienced by these packages in the tests described in 10 CFR Part 71 to conditions potentially encountered in actual accidents and to estimate the probabilities of such accidents. Comparison of the effects of actual accident conditions to 10 CFR Part 71 tests was achieved by means of computer modeling of structural effects on the packages due to impacts with actual surfaces, and thermal effects resulting from test and other fire scenarios. In addition, the likelihood of encountering bodies of water or sufficient rainfall to cause complete or partial immersion during transport over representative truck routes was assessed. Modeled effects, and their associated probabilities, were combined with existing event-tree data, plus accident rates and other characteristics gathered from representative routes, to derive generalized probabilities of encountering accident conditions comparable to the 10 CFR Part 71 conditions. This analysis suggests that the regulatory conditions are unlikely to be exceeded in real accidents, i.e. the likelihood of UF{sub 6} being dispersed as a result of accident impact or fire is small. Moreover, given that an accident has occurred, exposure to water by fire-fighting, heavy rain or submersion in a body of water is even less probable by factors ranging from 0.5 to 8E-6.

  12. Neutron counter based on beryllium activation

    SciTech Connect (OSTI)

    Bienkowska, B.; Prokopowicz, R.; Kaczmarczyk, J.; Paducha, M. [Institute of Plasma Physics and Laser Microfusion (IPPLM), Hery 23, 01-497 Warsaw (Poland); Scholz, M.; Igielski, A. [Institute of Nuclear Physics PAS (IFJPAN), Radzikowskiego 152, 31-342 Krakow (Poland); Karpinski, L. [Faculty of Electrical Engineering, Rzeszow University of Technology, Pola 2, 35-959 Rzeszow (Poland); Pytel, K. [National Centre for Nuclear Research (NCBJ), Soltana 7, 05-400 Otwock - Swierk (Poland)

    2014-08-21

    The fusion reaction occurring in DD plasma is followed by emission of 2.45 MeV neutrons, which carry out information about fusion reaction rate and plasma parameters and properties as well. Neutron activation of beryllium has been chosen for detection of DD fusion neutrons. The cross-section for reaction {sup 9}Be(n, ?){sup 6}He has a useful threshold near 1 MeV, which means that undesirable multiple-scattered neutrons do not undergo that reaction and therefore are not recorded. The product of the reaction, {sup 6}He, decays with half-life T{sub 1/2} = 0.807 s emitting ?{sup ?} particles which are easy to detect. Large area gas sealed proportional detector has been chosen as a counter of ?–particles leaving activated beryllium plate. The plate with optimized dimensions adjoins the proportional counter entrance window. Such set-up is also equipped with appropriate electronic components and forms beryllium neutron activation counter. The neutron flux density on beryllium plate can be determined from the number of counts. The proper calibration procedure needs to be performed, therefore, to establish such relation. The measurements with the use of known ?–source have been done. In order to determine the detector response function such experiment have been modeled by means of MCNP5–the Monte Carlo transport code. It allowed proper application of the results of transport calculations of ?{sup ?} particles emitted from radioactive {sup 6}He and reaching proportional detector active volume. In order to test the counter system and measuring procedure a number of experiments have been performed on PF devices. The experimental conditions have been simulated by means of MCNP5. The correctness of simulation outcome have been proved by measurements with known radioactive neutron source. The results of the DD fusion neutron measurements have been compared with other neutron diagnostics.

  13. Improved oil recovery in Mississippian carbonate reservoirs of Kansas near term Class 2. Annual report, September 18, 1994--March 15, 1997

    SciTech Connect (OSTI)

    Carr, T.R.; Green, D.W.; Willhite, G.P.

    1998-04-01

    This annual report describes progress during the second year of the project entitled {open_quotes}Improved Oil Recovery in Mississippian Carbonate Reservoirs in Kansas{close_quotes}. This project funded under the Department of Energy`s Class 2 program targets improving the reservoir performance of mature oil fields located in shallow shelf carbonate reservoirs. The focus of this project is development and demonstration of cost-effective reservoir description and management technologies to extend the economic life of mature reservoirs in Kansas and the mid-continent. As part of the project, several tools and techniques for reservoir description and management were developed, modified and demonstrated. These include: (1) a new approach to subsurface visualization using electric logs ({open_quotes}Pseudoseismic{open_quotes}); (2) a low-cost easy-to-use spreadsheet log analysis software (PfEFFER); and (3) an extension of the BOAST-3 computer program for full field reservoir simulation. The world-wide-web was used to provide rapid and flexible dissemination of the project results through the Internet. Included in this report is a summary of significant project results at the demonstration site (Schaben Field, Ness County, Kansas). These results include an outline of the reservoir description based on available and newly acquired data and reservoir simulation results. Detailed information is available on-line through the Internet. Based on the reservoir simulation, three infill wells will be drilled to validate the reservoir description and demonstrate the effectiveness of the proposed reservoir management strategies. The demonstration phase of the project has just begun and will be presented in the next annual report.

  14. IMPROVED OIL RECOVERY IN MISSISSIPPIAN CARBONATE RESERVOIRS OF KANSAS - NEAR TERM - CLASS 2

    SciTech Connect (OSTI)

    Timothy R. Carr; Don W. Green; G. Paul Willhite

    2000-04-30

    This annual report describes progress during the final year of the project entitled ''Improved Oil Recovery in Mississippian Carbonate Reservoirs in Kansas''. This project funded under the Department of Energy's Class 2 program targets improving the reservoir performance of mature oil fields located in shallow shelf carbonate reservoirs. The focus of the project was development and demonstration of cost-effective reservoir description and management technologies to extend the economic life of mature reservoirs in Kansas and the mid-continent. As part of the project, tools and techniques for reservoir description and management were developed, modified and demonstrated, including PfEFFER spreadsheet log analysis software. The world-wide-web was used to provide rapid and flexible dissemination of the project results through the Internet. A summary of demonstration phase at the Schaben and Ness City North sites demonstrates the effectiveness of the proposed reservoir management strategies and technologies. At the Schaben Field, a total of 22 additional locations were evaluated based on the reservoir characterization and simulation studies and resulted in a significant incremental production increase. At Ness City North Field, a horizontal infill well (Mull Ummel No.4H) was planned and drilled based on the results of reservoir characterization and simulation studies to optimize the location and length. The well produced excellent and predicted oil rates for the first two months. Unexpected presence of vertical shale intervals in the lateral resulted in loss of the hole. While the horizontal well was not economically successful, the technology was demonstrated to have potential to recover significant additional reserves in Kansas and the Midcontinent. Several low-cost approaches were developed to evaluate candidate reservoirs for potential horizontal well applications at the field scale, lease level, and well level, and enable the small independent producer to identify efficiently candidate reservoirs and also to predict the performance of horizontal well applications.

  15. The dynamic behavior of thin-film ionic transition metal complex-based light-emitting electrochemical cells

    SciTech Connect (OSTI)

    Meier, Sebastian B., E-mail: sebastian.meier@belectric.com, E-mail: wiebke.sarfert@siemens.com [Department of Materials Science VI: Materials for Electronics and Energy Technology, Friedrich-Alexander-University of Erlangen-Nuremberg, 91058 Erlangen (Germany); Siemens AG, Corporate Technology, CT RTC MAT IEC-DE, 91058 Erlangen (Germany); Hartmann, David; Sarfert, Wiebke, E-mail: sebastian.meier@belectric.com, E-mail: wiebke.sarfert@siemens.com [Siemens AG, Corporate Technology, CT RTC MAT IEC-DE, 91058 Erlangen (Germany); Winnacker, Albrecht [Department of Materials Science VI: Materials for Electronics and Energy Technology, Friedrich-Alexander-University of Erlangen-Nuremberg, 91058 Erlangen (Germany)

    2014-09-14

    Light-emitting electrochemical cells (LECs) have received increasing attention during recent years due to their simple architecture, based on solely air-stabile materials, and ease of manufacture in ambient atmosphere, using solution-based technologies. The LEC's active layer offers semiconducting, luminescent as well as ionic functionality resulting in device physical processes fundamentally different as compared with organic light-emitting diodes. During operation, electrical double layers (EDLs) form at the electrode interfaces as a consequence of ion accumulation and electrochemical doping sets in leading to the in situ development of a light-emitting p-i-n junction. In this paper, we comment on the use of impedance spectroscopy in combination with complex nonlinear squares fitting to derive key information about the latter events in thin-film ionic transition metal complex-based light-emitting electrochemical cells based on the model compound bis-2-phenylpyridine 6-phenyl-2,2´-bipyridine iridium(III) hexafluoridophosphate ([Ir(ppy)?(pbpy)][PF?]). At operating voltages below the bandgap potential of the ionic complex used, we obtain the dielectric constant of the active layer, the conductivity of mobile ions, the transference numbers of electrons and ions, and the thickness of the EDLs, whereas the transient thickness of the p-i-n junction is determined at voltages above the bandgap potential. Most importantly, we find that charge transport is dominated by the ions when carrier injection from the electrodes is prohibited, that ion movement is limited by the presence of transverse internal interfaces and that the width of the intrinsic region constitutes almost 60% of the total active layer thickness in steady state at a low operating voltage.

  16. Effects of electrolyte salts on the performance of Li-O2 batteries

    SciTech Connect (OSTI)

    Nasybulin, Eduard N.; Xu, Wu; Engelhard, Mark H.; Nie, Zimin; Burton, Sarah D.; Cosimbescu, Lelia; Gross, Mark E.; Zhang, Jiguang

    2013-02-05

    It is well known that the stability of nonaqueous electrolyte is critical for the rechargeable Li-O2 batteries. Although stability of many solvents used in the electrolytes has been investigated, considerably less attention has been paid to the stability of electrolyte salt which is the second major component. Herein, we report the systematic investigation of the stability of seven common lithium salts in tetraglyme used as electrolytes for Li-O2 batteries. The discharge products of Li-O2 reaction were analyzed by X-ray diffraction, X-ray photoelectron spectroscopy and nuclear magnetic resonance spectroscopy. The performance of Li-O2 batteries was strongly affected by the salt used in the electrolyte. Lithium tetrafluoroborate (LiBF4) and lithium bis(oxalato)borate (LiBOB) decompose and form LiF and lithium borates, respectively during the discharge of Li-O2 batteries. Several other salts, including lithium bis(trifluoromethane)sulfonamide (LiTFSI), lithium trifluoromethanesulfonate (LiTf), lithium hexafluorophosphate (LiPF6), lithium perchlorate (LiClO4) , and lithium bromide (LiBr) led to the discharge products which mainly consisted of Li2O2 and only minor signs of decomposition of LiTFSI, LiTf, LPF6 and LiClO4 were detected. LiBr showed the best stability during the discharge process. As for the cycling performance, LiTf and LiTFSI were the best among the studied salts. In addition to the instability of lithium salts, decomposition of tetraglyme solvent was a more significant factor contributing to the limited cycling stability. Thus a more stable nonaqueous electrolyte including organic solvent and lithium salt still need to be further developed to reach a fully reversible Li-O2 battery.

  17. Physics and Engineering Assessments ?of the K-DEMO Magnet Configuration

    SciTech Connect (OSTI)

    Neilson, George H.; Brown, Thomas

    2014-09-01

    Increased attention is being given now to studies of next-step fusion facilities with nuclear missions. Among these, South Korea's K DEMO is unique in its focus on a high toroidal magnetic field, large major radius, steady-state tokamak design for the core of a facility to test fusion nuclear components in Phase I and, after upgrades, produce 500 MW of electricity in a Phase II. Innovative features of the K DEMO magnet set include the use of two toroidal field (TF) coil winding packs with conductor grading and a machine configuration designed for vertical maintenance. The magnet arrangement features large TF coils and widelyspaced poloidal field (PF) coils to accommodate removal of in-vessel components as large modules. Physics and engineering assessments of the pre-conceptual K-DEMO magnet configuration are reported, including: 1) design point and operating space assessment, 2) conductor assessment, and 3) structural assessment. It is found that a reference design point at 6.8 m major radius and 7.4 T toroidal field provides sufficient operating margins for the 500 MWe Phase II mission. Analyses of candidate cable-in-conduit conductors provide predictions of critical current degradation, both in the initial load cycle and an additionally with cyclic loading. A first-pass global analysis of the magnet system found minimal out-of-plane deformations of the TF coil, but an overstress condition in the inner leg of the TF coil. However an analysis taking into account elastic-plastic behavior, frictional sliding, and displacement shows that the structure can safely carry the load. Although the design evolution is still at an early stage, these assessments support the design point choices to date and the expectation that a feasible solution for the high-field K DEMO magnet system can be found.

  18. On the control of filamentation of intense laser beams propagating in underdense plasma

    SciTech Connect (OSTI)

    Williams, E.A. [Lawrence Livermore National Laboratory, University of California, Livermore, California 94550 (United States)

    2006-05-15

    In indirect drive inertial confinement fusion ignition designs, the laser energy is delivered into the hohlraum through the laser entrance holes (LEHs), which are sized as small as practicable to minimize x-ray radiation losses. On the other hand, deleterious laser plasma processes, such as filamentation and stimulated backscatter, typically increase with laser intensity. Ideally, therefore, the laser spot shape should be a close fit to the LEH, with uniform (envelope) intensity in the spot and minimal energy at larger radii spilling onto the LEH material. This keeps the laser intensity as low as possible, consistent with the area of the LEH aperture and the power requirements of the design. This can be achieved (at least for apertures significantly larger than the laser's aberrated focal spot) by the use of custom-designed phase plates. However, outfitting the 192-beam National Ignition Facility [J. A. Paisner, E. M. Campbell, and W. J. Hogan, Fusion Tech. 26, 755 1994)] laser with multiple sets of phase plates optimized for a variety of different LEH aperture sizes is an expensive proposition. It is thus important to assess the impact on laser-plasma interaction processes of using phase plates with a smaller than optimum focal spot (or even no phase plates at all{exclamation_point}) and then defocusing the beam to expand it to fill the LEH and lower its intensity. Significant effects are found from changes in the characteristic sizes of the laser speckle, from the lack of uniformity of the laser envelope out of the focal plane and on the efficacy of additional polarization smoothing and/or smoothing by spectral dispersion (SSD). These effects are quantified with analytic estimates and simulations using PF3D, our laser-plasma interaction code.

  19. Conformational Variability of Organophosphorus Hydrolase upon Soman and Paraoxon Binding

    SciTech Connect (OSTI)

    Gomes, Diego Eb; Lins, Roberto D.; Pascutti, Pedro G.; Lei, Chenghong; Soares, Thereza A.

    2011-12-31

    The bacterial enzyme organophosphorus hydrolase (OPH) exhibits both catalytic and substrate promiscuity. It hydrolyzes bonds in a variety of phosphotriester (P-O), phosphonothioate (P-S), phosphofluoridate (P-F) and phosphonocyanate (F-CN) compounds. However, its catalytic efficiency varies markedly for different substrates, limiting the broad-range application of OPH as catalyst in the bioremediation of pesticides and chemical war agents. In the present study, pK{sub a} calculations and multiple explicit-solvent molecular dynamics (MD) simulations were performed to characterize and contrast the structural dynamics of OPH bound to two substrates hydrolyzed with very distinct catalytic efficiencies: the nerve agent soman (O-pinacolyl-methyl-phosphonofluoridate) and the pesticide paraoxon (diethyl p-nitrophenyl phosphate). pK{sub a} calculations for the substrate-bound and unbound enzyme showed a significant pK{sub a} shift from standard values ({Delta}pK{sub a} = {+-} 3 units) for residues 254His and 275Arg. MD simulations of the doubly protonated 254His revealed a dynamic hydrogen bond network connecting the catalytic residue 301Asp via 254His to 232Asp, 233Asp, 275Arg and 235Asp, and is consistent with a previously postulated proton relay mechanism to ferry protons away from the active site with substrates that do not require activation of the leaving group. Hydrogen bonds between 301Asp and 254His were persistent in the OPH-paraoxon complex but not in the OPH-soman one, suggesting a potential role for such interaction in the more efficient hydrolysis of paraoxon over soman by OPH. These results are in line with previous mutational studies of residue 254His, which led to an increase of the catalytic efficiency of OPH over soman yet decreased its efficiency for paraoxon. In addition, comparative analysis of the molecular trajectories for OPH bound to soman and paraoxon suggests that binding of the latter facilitates the conformational transition of OPH from the open to the closed substate promoting a tighter binding of paraoxon.

  20. Syntheses, structures and properties of silver(I) complexes with flexible 1,3,5-tris(pyridylmethoxyl)benzene ligands

    SciTech Connect (OSTI)

    Wu Gang [Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China); Department of Chemistry and Life Science, Chuzhou University, Chuzhou 239012 (China); Wang Xiaofeng [Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China); Okamura, Taka-aki [Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan); Chen Min [Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China); Sun Weiyin, E-mail: sunwy@nju.edu.c [Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093 (China); Ueyama, Norikazu [Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043 (Japan)

    2010-09-15

    Five new silver(I) complexes [Ag{sub 2}(L{sub 2}){sub 2}](BF{sub 4}){sub 2}.CH{sub 3}CN.CH{sub 3}OH (1), [Ag(L{sub 2})(CF{sub 3}SO{sub 3})] (2), [Ag(L{sub 3})]ClO{sub 4}.CH{sub 3}OH (3), [Ag{sub 2}(L{sub 3}){sub 2}](CF{sub 3}SO{sub 3}){sub 2}.CH{sub 3}CN.CH{sub 3}OH.H{sub 2}O (4) and [Ag(L{sub 3})]PF{sub 6}.2CH{sub 3}CN (5) [L{sub 2}=1,3,5-tris(2-pyridylmethoxyl)benzene, L{sub 3}=1,3,5-tris(3-pyridylmethoxyl)benzene] were synthesized and characterized by single crystal X-ray diffraction analyses. In complexes 1-5, ligands L{sub 2} and L{sub 3} show different conformations and act as three-connectors, while the Ag(I) atom serves as three-connecting node to result in the formation of 2D and 3D frameworks. Complexes 1 and 2 with different counteranions have similar 2D network structure with the same (4,8{sup 2}) topology. Complex 3 has a 3D structure with (10,3)-a topology while complexes 4 and 5 have the same 2D (6,3) topological structure. The results showed that the structure of organic ligands and counteranions play subtle but important role in determining the structure of the complexes. In addition, the photoluminescence and anion-exchange properties of the complexes were investigated in the solid state at room temperature. - Graphical abstract: Five new silver(I) coordination frameworks with different topology were obtained and their structures were determined by single crystal X-ray diffraction studies. The influence of counteranion and ligand on the structure of complexes was discussed, the photoluminescence and anion-exchange properties were reported.

  1. InP quantum dots: Electronic structure, surface effects, and the redshifted emission

    SciTech Connect (OSTI)

    Fu, H.; Zunger, A.

    1997-07-01

    We present pseudopotential plane-wave electronic-structure calculations on InP quantum dots in an effort to understand quantum confinement and surface effects and to identify the origin of the long-lived and redshifted luminescence. We find that (i) unlike the case in small GaAs dots, the lowest unoccupied state of InP dots is the {Gamma}{sub 1c}-derived direct state rather than the X{sub 1c}-derived indirect state and (ii) unlike the prediction of {bold k}{center_dot}{bold p} models, the highest occupied state in InP dots has a 1sd-type envelope function rather than a (dipole-forbidden) 1pf envelope function. Thus explanations (i) and (ii) to the long-lived redshifted emission in terms of an orbitally forbidden character can be excluded. Furthermore, (iii) fully passivated InP dots have no surface states in the gap. However, (iv) removal of the anion-site passivation leads to a P dangling bond (DB) state just above the valence band, which will act as a trap for photogenerated holes. Similarly, (v) removal of the cation-site passivation leads to an In dangling-bond state below the conduction band. While the energy of the In DB state depends only weakly on quantum size, its radiative lifetime increases with quantum size. The calculated {approximately}300-meV redshift and the {approximately}18 times longer radiative lifetime relative to the dot-interior transition for the 26-{Angstrom} dot with an In DB are in good agreement with the observations of full-luminescence experiments for unetched InP dots. Yet, (vi) this type of redshift due to surface defect is inconsistent with that measured in {ital selective} excitation for HF-etched InP dots. (vii) The latter type of ({open_quotes}resonant{close_quotes}) redshift is compatible with the calculated {ital screened} singlet-triplet splitting in InP dots, suggesting that the slow emitting state seen in selective excitation could be a triplet state. {copyright} {ital 1997} {ital The American Physical Society}

  2. Large-amplitude, circularly polarized, compressive, obliquely propagating electromagnetic proton cyclotron waves throughout the Earth's magnetosheath: low plasma ? conditions

    SciTech Connect (OSTI)

    Remya, B.; Reddy, R. V.; Lakhina, G. S. [Indian Institute of Geomagnetism, Kalamboli Highway, New Panvel, Navi Mumbai, Maharashtra (India); Tsurutani, B. T.; Falkowski, B. J. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Echer, E. [Instituto Nacional de Pesquisas Espaciais (INPE), Avenida Astronautas, 1758, P.O. Box 515, Sao Jose dos Campos, SP (Brazil); Glassmeier, K.-H., E-mail: remyaphysics@gmail.com [Institute for Geophysics and Extraterrestrial Physics (IGEP), Mendelssohnstr.3, D-38106, Braunschweig (Germany)

    2014-09-20

    During 1999 August 18, both Cassini and WIND were in the Earth's magnetosheath and detected transverse electromagnetic waves instead of the more typical mirror-mode emissions. The Cassini wave amplitudes were as large as ?14 nT (peak to peak) in a ?55 nT ambient magnetic field B {sub 0}. A new method of analysis is applied to study these waves. The general wave characteristics found were as follows. They were left-hand polarized and had frequencies in the spacecraft frame (f {sub scf}) below the proton cyclotron frequency (f{sub p} ). Waves that were either right-hand polarized or had f {sub scf} > f{sub p} are shown to be consistent with Doppler-shifted left-hand waves with frequencies in the plasma frame f{sub pf} < f{sub p} . Thus, almost all waves studied are consistent with their being electromagnetic proton cyclotron waves. Most of the waves (?55%) were found to be propagating along B {sub 0} (?{sub kB{sub 0}}<30{sup ?}), as expected from theory. However, a significant fraction of the waves were found to be propagating oblique to B {sub 0}. These waves were also circularly polarized. This feature and the compressive ([B {sub max} – B {sub min}]/B {sub max}, where B {sub max} and B {sub min} are the maximum and minimum field magnitudes) nature (ranging from 0.27 to 1.0) of the waves are noted but not well understood at this time. The proton cyclotron waves were shown to be quasi-coherent, theoretically allowing for rapid pitch-angle transport of resonant protons. Because Cassini traversed the entire subsolar magnetosheath and WIND was in the dusk-side flank of the magnetosheath, it is surmised that the entire region was filled with these waves. In agreement with past theory, it was the exceptionally low plasma ? (0.35) that led to the dominance of the proton cyclotron wave generation during this interval. A high-speed solar wind stream ((V{sub sw} ) = 598 km s{sup –1}) was the source of this low-? plasma.

  3. Micro mass spectrometer on a chip.

    SciTech Connect (OSTI)

    Cruz, Dolores Y.; Blain, Matthew Glenn; Fleming, James Grant

    2005-11-01

    The design, simulation, fabrication, packaging, electrical characterization and testing analysis of a microfabricated a cylindrical ion trap ({mu}CIT) array is presented. Several versions of microfabricated cylindrical ion traps were designed and fabricated. The final design of the individual trap array element consisted of two end cap electrodes, one ring electrode, and a detector plate, fabricated in seven tungsten metal layers by molding tungsten around silicon dioxide (SiO{sub 2}) features. Each layer of tungsten is then polished back in damascene fashion. The SiO{sub 2} was removed using a standard release processes to realize a free-hung structure. Five different sized traps were fabricated with inner radii of 1, 1.5, 2, 5 and 10 {micro}m and heights ranging from 3-24 {micro}m. Simulations examined the effects of ion and neutral temperature, the pressure and nature of cooling gas, ion mass, trap voltage and frequency, space-charge, fabrication defects, and other parameters on the ability of micrometer-sized traps to store ions. The electrical characteristics of the ion trap arrays were determined. The capacitance was 2-500 pF for the various sized traps and arrays. The resistance was in the order of 1-2 {Omega}. The inductance of the arrays was calculated to be 10-1500 pH, depending on the trap and array sizes. The ion traps' field emission characteristics were assessed. It was determined that the traps could be operated up to 125 V while maintaining field emission currents below 1 x 10{sup -15} A. The testing focused on using the 5-{micro}m CITs to trap toluene (C{sub 7}H{sub 8}). Ion ejection from the traps was induced by termination of the RF voltage applied to the ring electrode and current measured on the collector electrode suggested trapping of ions in 1-10% of the traps. Improvements to the to the design of the traps were defined to minimize voltage drop to the substrate, thereby increasing trapping voltage applied to the ring electrode, and to allow for electron injection into, ion ejection from, and optical access to the trapping region.

  4. The activation of carbon dioxide by niobocene complexes

    SciTech Connect (OSTI)

    Fu, P.F.

    1993-01-01

    The reduction of Cp[prime][sub 2]Nb(Cl)R (Cp[prime] = [eta][sup 5]-C[sub 5]H[sub 4]CH[sub 3]) by Na/Hg under one atmosphere of CO[sub 2] produces Cp[prime][sub 2]Nb([eta][sup 2]-CO[sub 2])R (R = CH[sub 2]SiMe[sub 3], CH[sub 2]CMe[sub 3], CH[sub 2]Ph, CH[sub 3]). Thermolysis of Cp [sub 2]Nb([eta][sup 2]-CO[sub 2])R (R = CH[sub 2]SiMe[sub 3], CH[sub 2]CMe[sub 3], CH[sub 2]Ph) in THF at 60[degrees]C (at low concentration for R = CH[sub 2]Ph) resulted in decarbonylation of the complex with first order kinetics to generate the corresponding metal-oxo complexes Cp[prime][sub 2]Nb(O)R. The same process is greatly accelerated photochemically with a quantum yield of 0.17 for R = CH[sub 2]SiMe[sub 3]. At higher concentration, carbonyl complex Cp[prime][sub 2]Nb(CO)Ch[sub 2]Ph is also generated in the thermolysis of Cp[prime][sub 2]Nb([eta][sup 2]-CO[sub 2])CH[sub 2]Ph. In continuing effort to promote migratory insertion of Cp[prime][sub 2]Nb([eta][sup 2]-CO[sub 2])CH[sub 2]SiMe[sub 3], its reactions with of a variety of Lewis acids (LiPF[sub 6], BF[sub 3][center dot]Et[sub 2]O, ZnCl[sub 2], HgCl[sub 2], CdCl[sub 2], and ClSiMe[sub 3]) have been investigated. The interaction of Cp[prime][sub 2]Nb([eta][sup 2]-CO[sub 2])CH[sub 2]SiMe[sub 3] with several Lewis acids resulted in its facile decarbonylation. The carbonyl complexes Cp[prime][sub 2]Nb(CO)R (R = CH[sub 2]SiMe[sub 3], CH[sub 2]CMe[sub 3], CH[sub 2]Ph, CH[sub 3]) reacted cleanly and quantitatively with molecular oxygen under ambient conditions to produce the corresponding CO[sub 2] complexes, Cp[prime][sub 2]Nb([eta][sup 2]-CO[sub 2])R, in high yield. The interaction of Cp[prime][sub 2]Nb(CO)H with O[sub 2] generates a novel formato complex. The reaction of Cp[prime][sub 2]Nb(CO)CH[sub 2]SiMe[sub 3] with elemental sulfur (S[sub 8]) gives a carbonyl sulfide complex Cp[prime][sub 2]Nb([eta][sup 2]-CSO) CH[sub 2]SiMe[sub 3], whose structure has been established crystallographically.

  5. TRITIUM AGING EFFECTS ON THE FRACTURE TOUGHNESS PROPERTIES OF STAINLESS STEEL BASE METAL AND WELDS

    SciTech Connect (OSTI)

    Morgan, M.

    2009-07-30

    Tritium reservoirs are constructed from welded stainless steel forgings. While these steels are highly resistant to the embrittling effects of hydrogen isotopes and helium from tritium decay; they are not immune. Tritium embrittlement is an enhanced form of hydrogen embrittlement because of the presence of helium-3 from tritium decay which nucleates as nanometer-sized bubbles on dislocations, grain boundaries, and other microstructural defects. Steels with decay helium bubble microstructures are hardened and less able to deform plastically and become more susceptible to embrittlement by hydrogen and its isotopes. Ductility, elongation-to-failure, and fracture toughness are reduced by exposures to tritium and the reductions increase with time as helium-3 builds into the material from tritium permeation and radioactive decay. Material and forging specifications have been developed for optimal material compatibility with tritium. These specifications cover composition, mechanical properties, and select microstructural characteristics like grain size, flow-line orientation, inclusion content, and ferrite distribution. For many years, the forming process of choice for reservoir manufacturing was high-energy-rate forging (HERF), principally because the DOE forging facility owned only HERF hammers. Today, some reservoir forgings are being made that use a conventional, more common process known as press forging (PF or CF). One of the chief differences between the two forging processes is strain rate: Conventional hydraulic or mechanical forging presses deform the metal at 4-8 ft/s, about ten-fold slower than the HERF process. The material specifications continue to provide successful stockpile performance by ensuring that the two forging processes produce similar reservoir microstructures. While long-term life storage tests have demonstrated the general tritium compatibility of tritium reservoirs, fracture-toughness properties of both conventionally forged and high-energy-rate forged are needed for designing and establishing longer tritium-reservoir lifetimes, ranking materials, and, potentially, for qualifying new forging vendors or processes. Measurements on the effects of tritium and decay helium on the fracture toughness properties of CF stainless steels having similar composition, grain size, and mechanical properties to previously studied HERF steels are needed and have not been conducted until now. The compatibility of stainless steel welds with tritium represents another concern for long-term reservoir performance. Weldments have not been well-characterized with respect to tritium embrittlement, although a recent study was completed on the effect of tritium and decay helium on the fracture toughness properties of Type 304L weldments. This study expands the characterization of weldments through measurements of tritium and decay helium effects on the fracture toughness properties of Type 21-6-9 stainless steel. The purpose of this study was to measure and compare the fracture toughness properties of Type 21-6-9 stainless steel for conventional forgings and weldments in the non-charged, hydrogen-charged and tritium-charged-and-aged conditions.

  6. A BRIEF DESCRIPTION OF THE SMALL-SCALE SAFETY TESTING SYSTEMS AT LAWRENCE LIVERMORE NATIONAL LABORATORY

    SciTech Connect (OSTI)

    HSU, P C

    2008-07-31

    Small-scale sensitivity testing is important for determining material response to various stimuli including impact, friction, and static spark. These tests, briefly described below, provide parameters for safety in handling. ERL Type 12 drop hammer equipment at LLNL, shown in Figure 1, was used to determine the impact sensitivity. The equipment includes a 2.5-kg drop weight, a striker (upper anvil, 2.5 kg for solid samples and 1.0 kg for liquid samples), a bottom anvil, a microphone sensor, and a peakmeter. For each drop, sample (35 mg for solid or 45 microliter for liquid) is placed on the bottom anvil surface and impacted by the drop weight from different heights. Signs of reactions upon impact are observed and recorded. These signs include noises, flashes or sparks, smoke, pressure, gas emissions, temperature rise due to exothermic reaction, color change of the sample, and changes to the anvil surface (noted by inspection). For solid samples, a 'GO' was defined as a microphone sensor (for noise detection) response of {ge} 1.3 V as measured by a peakmeter. The higher the DH{sub 50} values, the lower the impact sensitivity. The method used to calculate DH{sub 50} values is the 'up and down' or Bruceton method. PETN and RDX have impact sensitivities of 15 and 35 cm, respectively. TATB has impact sensitivity more than 177 cm. For liquid samples, a 'GO' was determined by the noise levels as measured by the peakmeter, appearance of flashes, temperature rise of the anvil, and visual inspection of the anvil surface. Two liquid samples TMETN and FEFO have impact sensitivities of 14 and 32 cm, respectively. Figure 2 shows a 'GO' event observed during the impact sensitivity test; flashes appeared as the drop weight impacted the sample. A BAM friction sensitivity test machine, as shown in Figure 3, was used to determine the frictional sensitivity. The system uses a fixed porcelain pin and a movable porcelain plate that executes a reciprocating motion. Weight affixed to a torsion arm allows for a variation in applied force between 0.5 kg to 36.0 kg. The relative measure of the frictional sensitivity of a material is based upon the smallest load (kg) at which reaction occurs for a 1-in-10 series of attempts. The lower the load values, the higher the frictional sensitivity. PETN has a frictional sensitivity of 6.4 kg. The static spark machine at LLNL is used to evaluate the electrostatic discharge hazards (human ESD) associated with the handling of explosives. The machine was custom-built almost 30 years ago and consists of a capacitor bank (up to 20,000 pF), a voltage meter, and a discharge circuit, as shown in Figure 4. An adjustable resistor up to 510 ohms (chosen to simulate human body) is wired to the discharge circuit. A 5-mg sample is placed in a Teflon washer sealed to a steel disc and covered with a Mylar tape. High static voltage (up to 10 kv) is applied and discharged to the sample. Evidence of reaction is judged from the condition of Mylar tape, smokes, and color change of the sample. Voltage, capacitance, and resistance can be adjusted to achieve the desired static energy. The results obtained are expressed as a zero in 10 or one-in-ten at a specific voltage and joules. One reaction in ten trials at {le} 0.25 joules is considered spark-sensitive. Primary explosives show reaction at 0.1 joule.

  7. HPC-Colony: Services and Interfaces to Aupport Systems With Very Large Numbers of Processors

    SciTech Connect (OSTI)

    Jones, T; Kale, L; Moreira, J; Mendes, C; Chakravorty, S; Tauferner, A; Inglett, T

    2007-01-31

    The HPC-Colony Project, a collaboration with Lawrence Livermore National Laboratory, the University of Illinois at Urbana-Champaign and IBM, is focused on services and interfaces for very large numbers of processors. Advances in parallel systems in the last decade have delivered phenomenal progress in the overall capability available to a single parallel application. Several systems with peak capability of over 100TF are already available and systems are expected to exceed 1PF within a few years. Despite these impressive advances in peak performance capability, the sustained performance of these systems continues to fall as a percentage of the peak capability. Initial analysis suggests that key architectural bottlenecks (in hardware and software) are responsible for the lower sustained performance and some architectural change of direction may be necessary to address the declining sustained performance. In this proposal we focus on addressing software architectural bottlenecks, in the areas of operating system and runtime systems. While the trend towards larger processor counts benefits application developers through more processing power, it also challenges application developers to harness ever-increasing numbers of processors for productive work. Much of the burden falls to operating systems and runtime systems that were originally designed for much smaller processor counts. Under the Colony project, we are researching and developing system software to enable general purpose operating and runtime systems for tens of thousands of processors. Difficulties in achieving a balanced partitioning and dynamically scheduling workloads can limit scaling for complex problems on large machines. Scientific simulations that span components of large machines require common operating system services, such as process scheduling, event notification, and job management to scale to large machines. Today, application programmers must explicitly manage these resources. We address scaling issues and porting issues by delegating resource management tasks to a sophisticated parallel OS. Our definition of ''managing resources'' includes balancing CPU time, network utilization, and memory usage across the entire machine. We believe a consistent environment that provides newly necessary technology (such as fault tolerance) will also provide important efficiencies in system administration. The primary objective of the Colony Project is to develop technologies that enable application scientists to easily scale applications to computing platforms comprised of tens of thousands to hundreds of thousands of compute cores. This will be accomplished by addressing several problem areas that are known to be key factors when scaling applications to tens of thousands of processors. First, by providing a smart runtime system to quickly and dynamically make cpu and memory and interconnect resource management adjustments, we remove the burden of achieving applications that are highly tuned and load-balanced for a particular execution instance (i.e. a particular input datasets and machine platform combination). Second, by providing a full complement of system services including the entire Linux system call set, we ease the challenge of developing portable applications since lightweight kernels frequently incorporate only a small subset of the POSIX calls prevalent in typical large scientific applications. Third, by providing fundamental changes to the Linux kernel that reduce variability in context switch times and provide for parallel-aware scheduling across the entire machine, we remove the negative impact of synchronizing collectives on bulk-synchronous applications. Fourth, by providing fault tolerance mechanisms that utilize our unique migration abilities in conjunction with in-memory techniques for minimal overhead, we eliminate the necessity for costly frequent application-driven check-points. Our research utilizes full implementations of these technologies on systems consisting of tens of thousands of processors.

  8. 2012 SARA Students Technical Report

    SciTech Connect (OSTI)

    Briccetti, Angelo [Los Alamos National Laboratory; Lorei, Nathan [Los Alamos National Laboratory; Yonkings, David [Los Alamos National Laboratory; Lorio, David [Los Alamos National Laboratory; Goorley, John T. [Los Alamos National Laboratory; Sood, Avneet [Los Alamos National Laboratory

    2012-07-30

    The Service Academy Research Associates (SARA) program provides an opportunity for Midshipmen and Cadets from US Service Academies to participate in research at Los Alamos National Laboratory (LANL), Lawrence Livermore National Laboratory (LLNL), and Sandia National Laboratory for several weeks during the summer as part of their summer training assignments. During the summer of 2012, three Midshipmen were assigned to work with the XCP Division at LANL for approximately 5-6 weeks. As one of the nation's top national security science laboratories, LANL stretches across 36 square miles, has over 2,100 facilities, and employs over 9,000 individuals including a significant number of students and postdocs. LANL's mission is to 'apply science and technology to: ensure the safety, security, and reliability of the US nuclear deterrent, reduce global threats, and solve other emerging national security challenges.' While LANL officially operates under the US Department of Energy (DoE), fulfilling this mission requires mutual cooperation with the US Department of Defense (DoD) as well. LANL's high concentration of knowledge and experience provides interns a chance to perform research in many disciplines, and its connection with the DoD in both operation and personnel gives SARA students insight to career possibilities both during and after military service. SARA students have plenty of opportunity to enjoy hiking, camping, the Los Alamos YMCA, and many other outdoor activities in New Mexico while staying at the Buffalo Thunder Resort, located 20 miles east of the lab. XCP Division is the Computational Physics division of LANL's Weapons Department. Working with XCP Division requires individuals to be Q cleared by the DoE. This means it is significantly more convenient for SARA students to be assigned to XCP Division than their civilian counterparts as the DoD CNWDI clearance held by SARA students is easily transferred to the lab prior to the students arriving at the start of the summer. SARA students working with XCP Division were given a comprehensive introduction into nuclear engineering and physics, nuclear weapons, and radiation transport and detection via texts and lectures at various classification levels. Students also attended tours of several prominent facilities at LANL including TA-41 Ice House, TA-55 PF-4 plutonium facility, the Nicholas C. Metropolis Center for Modeling and Simulation, also known as the Secure Computing Center (SCC), and the Dual-Axis Radiological Hydro Test (DARHT) facility; in addition, SARA students accompanied by LANL staff traveled to Minot AFB in North Dakota for tours of the 5th Bomb Wing and 91st Missile Wing facilities. Students participated in a week long class on the Monte Carlo N Particle (MCNP) code to supplement their understanding of radiation transport simulations. SARA students were then tasked with using this knowledge to model radiation detectors and use MCNP to compare their models to experimental data and previously accepted models.

  9. PLUTONIUM METALLOGRAPHY AT LOS ALAMOS

    SciTech Connect (OSTI)

    PEREYRA, RAMIRO A.; LOVATO, DARRYL

    2007-01-08

    From early days of the Manhattan program to today, scientists and engineers have continued to investigate the metallurgical properties of plutonium (Pu). Although issues like aging was not a concern to the early pioneers, today the reliability of our aging stockpile is of major focus. And as the country moves toward a new generation of weapons similar problems that the early pioneers faced such as compatibility, homogeneity and malleability have come to the forefront. And metallography will continue to be a principle tool for the resolution of old and new issues. Standard metallographic techniques are used for the preparation of plutonium samples. The samples are first cut with a slow speed idamond saw. After mounting in Epon 815 epoxy resin, the samples are ground through 600 grit silicon carbide paper. PF 5070 (a Freon substitute) is used as a coolant, lubricant, and solvent for most operations. Rough mechanical polished is done with 9-{mu} diamond using a nap less cloth, for example nylon or cotton. Final polish is done with 1-{mu} diamond on a nappy cloth such as sylvet. Ethyl alcohol is then used ultrasonically to clean the samples before electro polishing. The sample is then electro-polished and etched in an electrolyte containing 10% nitric acid, and 90% dimethyleneformalmide. Ethyl alcohol is used as a final cleaning agent. Although standard metallographic preparation techniques are used, there are several reasons why metallography of Pu is difficult and challenging. Firstly, because of the health hazards associated with its radioactive properties, sample preparation is conducted in glove boxes. Figure 1 shows the metallography line, in an R and D facility. Since they are designed to be negative in pressure to the laboratory, cross-contamination of abrasives is a major problem. In addition, because of safety concerns and waste issues, there is a limit to the amount of solvent that can be used. Secondly, Pu will readily hydride or oxidize when in contact with metallographic polishing lubricants, solvents, or chemicals. And water being one of the most reactive solutions, is not used in the preparation. Figure 2 shows an example of a plutonium sample in which an oxide film has formed on the surface due to overexposure to solutions. it has been noted that nucleation of the hydride/oxide begins around inclusions and samples with a higher concentration of impurities seem to be more susceptible to this reaction. Figure 3 shows examples of small oxide rings, forming around inclusions. Lastly, during the cutting, grinding, or polishing process there is enough stress induced in the sample that the surface can transform from the soft face-centered-cubic delta phase (30 HV) to the strain-induced monoclinic alpha{prime} phase (300 HV). Figure 4 and 5 shows cross-sectional views of samples in which one was cut using a diamond saw and the other was processed through 600 grit. The white layers on the edges is the strain induced alpha{prime} phase. The 'V' shape indentation in Figure 5 was caused by a coarser abrasive which resulted in transformations to a depth of approximately 20 {micro}m. Another example of the transformation sensitivity of plutonium can be seen in Figure 6, in which the delta phase has partly transformed to alpha{prime} during micro hardness indentation.

  10. High Temperature Integrated Thermoelectric Ststem and Materials

    SciTech Connect (OSTI)

    Mike S. H. Chu

    2011-06-06

    The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits. Two composition systems, specifically 1.0 SrO - 0.8 x 1.03 TiO2 - 0.2 x 1.03 NbO2.5 and 0.97 TiO2 - 0.03 NbO2.5, have been identified as good base line compositions for n-type thermoelectric compositions in future module design. Tests of these materials at an outside company were promising using that company's processing and material expertise. There was no unique p-type thermoelectric compositions identified in phase I work other than several current cobaltite materials. Ca3Co4O9 will be the primary p-type material for the future module design until alternative materials are developed. BaTiO3 and rare earth titanate based dielectric compositions show both p-type and n-type behavior even though their electrical conductivities were very low. Further research and development of these materials for thermoelectric applications is planned in the future. A preliminary modeling and optimization of a thermoelectric generator (TEG) that uses the n-type 1.0 SrO - 1.03 x 0.8 TiO2 - 1.03 x 0.2 NbO2.5 was performed. Future work will combine development of ceramic powders and manufacturing expertise at TAM, development of SPS at TAM or a partner organization, and thermoelectric material/module testing, modeling, optimization, production at several partner organizations.