Sample records for making basic oxygen

  1. Ways of arrangement : the basic operations of form-making

    E-Print Network [OSTI]

    Wang, Minghong

    1987-01-01T23:59:59.000Z

    Making forms is essentially a matter of arranging things, and arranging things is essentially to establish spatial relations among selected elements. The thesis provides a minimal set of basic operations believed to be ...

  2. Method for making oxygen-reducing catalyst layers

    DOE Patents [OSTI]

    O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; O'Neill, David G.

    2010-06-22T23:59:59.000Z

    Methods are provided for making oxygen-reducing catalyst layers, which include simultaneous or sequential stops of physical vapor depositing an oxygen-reducing catalytic material onto a substrate, the catalytic material comprising a transition metal that is substantially free of platinum; and thermally treating the catalytic material. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  3. Improving the System Life of Basic Oxygen and Electric Arc Furnace Hoods, Roofs, and Side Vents

    Broader source: Energy.gov [DOE]

    This factsheet describes the benefits of a high-performance aluminum bronze alloy to basic oxygen furnace and electric arc furnace components such as hoods, roofs, and side vents.

  4. Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BES PrincipalBasicBasics Basics

  5. Method for making photovoltaic devices using oxygenated semiconductor thin film layers

    DOE Patents [OSTI]

    Johnson, James Neil; Albin, David Scott; Feldman-Peabody, Scott; Pavol, Mark Jeffrey; Gossman, Robert Dwayne

    2014-12-16T23:59:59.000Z

    A method for making a photovoltaic device is presented. The method includes steps of disposing a window layer on a substrate and disposing an absorber layer on the window layer. Disposing the window layer, the absorber layer, or both layers includes introducing a source material into a deposition zone, wherein the source material comprises oxygen and a constituent of the window layer, of the absorber layer or of both layers. The method further includes step of depositing a film that comprises the constituent and oxygen.

  6. Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BES PrincipalBasic EnergyBasics

  7. Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BES PrincipalBasic Energy

  8. Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BES PrincipalBasic

  9. Oxygen-resistant hydrogenases and methods for designing and making same

    DOE Patents [OSTI]

    King, Paul (Golden, CO); Ghirardi, Maria L (Lakewood, CO); Seibert, Michael (Lakewood, CO)

    2009-03-10T23:59:59.000Z

    The invention provides oxygen- resistant iron-hydrogenases ([Fe]-hydrogenases) for use in the production of H2. Methods used in the design and engineering of the oxygen-resistant [Fe]-hydrogenases are disclosed, as are the methods of transforming and culturing appropriate host cells with the oxygen-resistant [Fe]-hydrogenases. Finally, the invention provides methods for utilizing the transformed, oxygen insensitive, host cells in the bulk production of H.sub.2 in a light catalyzed reaction having water as the reactant.

  10. Oxygen-resistant hydrogenases and methods for designing and making same

    DOE Patents [OSTI]

    King, Paul; Ghirardi, Maria Lucia; Seibert, Michael

    2014-03-04T23:59:59.000Z

    The invention provides oxygen-resistant iron-hydrogenases ([Fe]-hydrogenases) for use in the production of H.sub.2. Methods used in the design and engineering of the oxygen-resistant [Fe]-hydrogenases are disclosed, as are the methods of transforming and culturing appropriate host cells with the oxygen-resistant [Fe]-hydrogenases. Finally, the invention provides methods for utilizing the transformed, oxygen insensitive, host cells in the bulk production of H.sub.2 in a light catalyzed reaction having water as the reactant.

  11. Bringing Order to Defects - Making Way for Oxygen to Move | U...

    Office of Science (SC) Website

    Energy Sciences Advisory Committee (BESAC) News & Resources Contact Information Basic Energy Sciences U.S. Department of Energy SC-22Germantown Building 1000 Independence...

  12. Aluminum Bronze Alloys to Improve the System Life of Basic Oxygen and Electric Arc Furnace Hoods, Roofs and Side Vents.

    SciTech Connect (OSTI)

    Lawrence C. Boyd Jr.; Dr. Vinod K. Sikka

    2006-12-29T23:59:59.000Z

    Energy Industries of Ohio was the lead organization for a consortium that examined the current situation involving the service life of electric arc and basic oxygen furnace hoods, roofs and side vents. Republic Engineered Products (REP), one of the project partners, installed a full-scale Al-Bronze “skirt” in their BOF at their Lorain OH facility, believed to be the first such installation of this alloy in this service. In 24 months of operation, the Al-Bronze skirt has processed a total of 4,563 heats, requiring only 2 shutdowns for maintenance, both related to physical damage to the skirt from operational mishaps. Yearly energy savings related to the REP facility are projected to be ~ 10 billion Btu's with significant additional environmental and productivity benefits. In recognition of the excellent results, this project was selected as the winner of the Ohio’s 2006 Governor’s Award for Excellence in Energy, the state’s award for outstanding achievements in energy efficiency.

  13. Tutorial 5: R programming basics While R is perhaps best known as a statistical tool for analyzing data or for making

    E-Print Network [OSTI]

    Miller, Thomas E.

    1 Tutorial 5: R programming basics Tom Miller While R is perhaps best known as a statistical tool for analyzing data or for making graphs, it is also really useful as a simple programming language and compiler. Using R for programming is not "machine efficient" and the programs can be a tad clunky and slow

  14. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, William H. (Danville, CA)

    1986-01-01T23:59:59.000Z

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  15. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, W.H.

    1984-05-08T23:59:59.000Z

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  16. AISI/DOE Advanced Process Control Program Vol. 1 of 6: Optical Sensors and Controls for Improved Basic Oxygen Furnace Operations

    SciTech Connect (OSTI)

    Sarah Allendorf; David Ottesen; Donald Hardesty

    2002-01-31T23:59:59.000Z

    The development of an optical sensor for basic oxygen furnace (BOF) off-gas composition and temperature in this Advanced Process Control project has been a laboratory spectroscopic method evolve into a pre-commercialization prototype sensor system. The sensor simultaneously detects an infrared tunable diode laser ITDL beam transmitted through the process off-gas directly above the furnace mouth, and the infrared greybody emission from the particulate-laden off-gas stream. Following developmental laboratory and field-testing, the sensor prototype was successfully tested in four long-term field trials at Bethlehem Steel's Sparrows Point plant in Baltimore, MD> The resulting optical data were analyzed and reveal correlations with four important process variables: (1) bath turndown temperature; (2) carbon monoxide post-combustion control; (2) bath carbon concentration; and (4) furnace slopping behavior. The optical sensor measurement of the off-gas temperature is modestly correlated with bath turndown temperature. A detailed regression analysis of over 200 heats suggests that a dynamic control level of +25 Degree F can be attained with a stand-alone laser-based optical sensor. The ability to track off-gas temperatures to control post-combustion lance practice is also demonstrated, and may be of great use in optimizing post-combustion efficiency in electric furnace steelmaking operations. In addition to the laser-based absorption spectroscopy data collected by this sensor, a concurrent signal generated by greybody emission from the particle-laden off-gas was collected and analyzed. A detailed regression analysis shows an excellent correlation of a single variable with final bath turndown carbon concentration. Extended field trials in 1998 and early 1999 show a response range from below 0.03% to a least 0.15% carbon concentration with a precision of +0.0007%. Finally, a strong correlation between prolonged drops in the off-gas emission signal and furnace slopping events was observed. A simple computer algorithm was written that successfully predicts furnace slopping for 90% of the heats observed; over 80% are predicted with at least a 30-second warning prior to the initial slopping events,

  17. Science as Knowledge, Practice, and Map Making: The Challenge of Defining Metrics for Evaluating and Improving DOE-Funded Basic Experimental Science

    SciTech Connect (OSTI)

    Bodnarczuk, M.

    1993-03-01T23:59:59.000Z

    Industrial R&D laboratories have been surprisingly successful in developing performance objectives and metrics that convincingly show that planning, management, and improvement techniques can be value-added to the actual output of R&D organizations. In this paper, I will discuss the more difficult case of developing analogous constructs for DOE-funded non-nuclear, non-weapons basic research, or as I will refer to it - basic experimental science. Unlike most industrial R&D or the bulk of applied science performed at the National Renewable Energy Laboratory (NREL), the purpose of basic experimental science is producing new knowledge (usually published in professional journals) that has no immediate application to the first link (the R) of a planned R&D chain. Consequently, performance objectives and metrics are far more difficult to define. My claim is that if one can successfully define metrics for evaluating and improving DOE-funded basic experimental science (which is the most difficult case), then defining such constructs for DOE-funded applied science should be much less problematic. With the publication of the DOE Standard - Implementation Guide for Quality Assurance Programs for Basic and Applied Research (DOE-ER-STD-6001-92) and the development of a conceptual framework for integrating all the DOE orders, we need to move aggressively toward the threefold next phase: (1) focusing the management elements found in DOE-ER-STD-6001-92 on the main output of national laboratories - the experimental science itself; (2) developing clearer definitions of basic experimental science as practice not just knowledge; and (3) understanding the relationship between the metrics that scientists use for evaluating the performance of DOE-funded basic experimental science, the management elements of DOE-ER-STD-6001-92, and the notion of continuous improvement.

  18. Recycling and Reuse of Basic Oxygen Furnace (BOF)/Basic Oxygen Process (BOP) Steelmaking Slags

    Broader source: Energy.gov [DOE]

    This factsheet describes a project to develop technologies and methodologies to allow value-added utilization of steelmaking slag, thus reducing waste and saving energy.

  19. Oxygen-reducing catalyst layer

    DOE Patents [OSTI]

    O'Brien, Dennis P. (Maplewood, MN); Schmoeckel, Alison K. (Stillwater, MN); Vernstrom, George D. (Cottage Grove, MN); Atanasoski, Radoslav (Edina, MN); Wood, Thomas E. (Stillwater, MN); Yang, Ruizhi (Halifax, CA); Easton, E. Bradley (Halifax, CA); Dahn, Jeffrey R. (Hubley, CA); O'Neill, David G. (Lake Elmo, MN)

    2011-03-22T23:59:59.000Z

    An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  20. Geothermal: Basic Search

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Basic Search Geothermal Technologies Legacy Collection HelpFAQ | Site Map | Contact Us HomeBasic Search About Publications Advanced Search New Hot Docs News Related Links Search...

  1. Craypat basics Craypat Automatic Performance Analysis

    E-Print Network [OSTI]

    approach Detecting load imbalance Apprentice2 basics XT5 Introduction Workshop - CSCS July 2-3, 2009 Slide CrayPat & Cray Apprentice2 module files module load xt-craypat apprentice2 Build application make clean

  2. PARKING AND BACKING BASICS

    E-Print Network [OSTI]

    Kirschner, Denise

    PARKING AND BACKING BASICS BACK TO BASICS: YOUR KEYS TO SAFE DRIVING DRIVE SAFELY WORK WEEK in parking lots. Safe parking and backing is an important basic for all driver groups to master. GET BASICS GOT KIDS OR GRANDKIDS? ·It is estimated that backing over pedestrians causes 45% of non- traffic

  3. Introduction Basic dynamics

    E-Print Network [OSTI]

    LaCasce, Joseph H.

    Introduction Basic dynamics The Gulf Stream The thermohaline circulation Ocean currents: some misconceptions and some dynamics Joe LaCasce Dept. Geosciences October 30, 2012 Joe LaCasce Dept. Geosciences Ocean currents: some misconceptions and some dynamics #12;Introduction Basic dynamics The Gulf Stream

  4. Basic Microfluidic Lithographic

    E-Print Network [OSTI]

    Prentiss, Mara

    CHAPTER 2 Basic Microfluidic and Soft Lithographic Techniques Sindy K.Y. Tang and George M in these devices are based on those developed for microfluidics used in biochemical anal- ysis. This chapter describes the basic ideas of microfluidics. We first summarize the materials most commonly used

  5. Basic principle of superconductivity

    E-Print Network [OSTI]

    Tian De Cao

    2009-11-10T23:59:59.000Z

    The basic principle of superconductivity is suggested in this paper. There have been two vital wrong suggestions on the basic principle, one is the relation between superconductivity and the Bose-Einstein condensation (BEC), and another is the relation between superconductivity and pseudogap.

  6. BASIC INSTRUCTIONS How to make normal coffee drinks

    E-Print Network [OSTI]

    Liblit, Ben

    · Lower the coffee spouts to avoid spilling · Rotate the dial for desired amount of water: 1oz to 8 oz the tip of the frother in to the milk and turn the Steam/Water selector to the Steam symbol. · Place a cup underneath the frother and turn the stream/water selector to the water symbol. · Let water

  7. Artificial oxygen transport protein

    DOE Patents [OSTI]

    Dutton, P. Leslie

    2014-09-30T23:59:59.000Z

    This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

  8. Basic Instructor Training

    Broader source: Energy.gov [DOE]

    The Emergency Operations Training Academy, NA 40.2, Readiness and Training, Albuquerque, NM is pleased to announce site certification by the National Training Center for conduct of the Basic Instructor Training class

  9. Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy and Electronic Structure Theory . Covalency in Metal-Oxygen Multiple Bonds Evaluated Using Oxygen K-edge Spectroscopy...

  10. oxygen-plasma | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxygen-plasma oxygen-plasma Leads No leads are available at this time. Conversion of 1,2-Propylene Glycol on Rutile TiO2(110). Abstract: We have studied the reactions of...

  11. Notes on basic algebraic geometry

    E-Print Network [OSTI]

    2008-06-16T23:59:59.000Z

    Jun 16, 2008 ... Notes on basic algebraic geometry ...... Having discovered the basic equation ..... back to a rational function on X. Thus we get a nonzero ...

  12. Intellectual Patent Basics

    E-Print Network [OSTI]

    Heller, Barbara

    Intellectual Property Patent Basics Roland W. Norris Pauley Petersen Kinne & Erickson 2800 W;Introduction Intellectual property: Patents Trademarks Copyrights Trade Secrets #12;What is a Patent? A right For the term of the patent 20 years from date of filing of earliest related patent or application #12;A

  13. Ethanol Basics (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2015-01-01T23:59:59.000Z

    Ethanol is a widely-used, domestically-produced renewable fuel made from corn and other plant materials. More than 96% of gasoline sold in the United States contains ethanol. Learn more about this alternative fuel in the Ethanol Basics Fact Sheet, produced by the U.S. Department of Energy's Clean Cities program.

  14. Lung, Artificial: Basic Principles and Current Applications William J. Federspiel

    E-Print Network [OSTI]

    Federspiel, William J.

    Lung, Artificial: Basic Principles and Current Applications William J. Federspiel Kristie A. Henchir University of Pittsburgh, Pittsburgh, Pennsylvania, U.S.A. INTRODUCTION Artificial lungs currently of the lung, which is to oxygenate the blood and remove carbon dioxide. Current artificial lungs are also

  15. Proton-coupled electron transfer : from basic principles to small molecule activation

    E-Print Network [OSTI]

    Rosenthal, Joel, 1979-

    2007-01-01T23:59:59.000Z

    Proton-coupled electron transfer (PCET) is the basic mechanism for bioenergetic conversion. Hallmark examples of such reactivities include water oxidation which is coupled to photosynthesis and oxygen reduction which is ...

  16. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, D.W.

    1994-09-06T23:59:59.000Z

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

  17. Energy and Development: Is Energy a Basic Human Right?

    E-Print Network [OSTI]

    Energy and Development: Is Energy a Basic Human Right? Skype/Video presentation for senior pupils national Laboratory/DTU Denmark #12;Is energy a basic human right? · What is energy? ­ the ability to make something happen · Different kinds of energy ­ or energy carriers - fuels · What do we use energy for

  18. Health Care Basics: Choosing the

    E-Print Network [OSTI]

    Hutcheon, James M.

    ;Health Care Basics 3 · Sickle Cell Anemia · HIV/AIDS(chroniccondition) · Low Back problems (chronic

  19. Underground coal gasification using oxygen and steam

    SciTech Connect (OSTI)

    Yang, L.H.; Zhang, X.; Liu, S. [China University of Mining & Technology, Xuzhou (China)

    2009-07-01T23:59:59.000Z

    In this paper, through model experiment of the underground coal gasification, the effects of pure oxygen gasification, oxygen-steam gasification, and moving-point gasification methods on the underground gasification process and gas quality were studied. Experiments showed that H{sub 2} and CO volume fraction in product gas during the pure oxygen gasification was 23.63-30.24% and 35.22-46.32%, respectively, with the gas heating value exceeding 11.00 MJ/m{sup 3}; under the oxygen-steam gasification, when the steam/oxygen ratio stood at 2: 1, gas compositions remained virtually stable and CO + H{sub 2} was basically between 61.66 and 71.29%. Moving-point gasification could effectively improve the changes in the cavity in the coal seams or the effects of roof inbreak on gas quality; the ratio of gas flowing quantity to oxygen supplying quantity was between 3.1:1 and 3.5:1 and took on the linear changes; on the basis of the test data, the reasons for gas quality changes under different gasification conditions were analyzed.

  20. Integrated turbomachine oxygen plant

    SciTech Connect (OSTI)

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17T23:59:59.000Z

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  1. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  2. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  3. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  4. NREL: Learning - Hydrogen Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated CodesTransparency Visit |Infrastructure TheSolar EnergyHydrogen Basics

  5. Basic Energy Sciences Jobs

    Office of Science (SC) Website

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron4 Self-Scrubbing:,,of Science (SC) BESAC Home Basic Energy

  6. Basic Energy Sciences Reports

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWPAlumniComplex historian ...BES PrincipalBasic Energy Sciences

  7. Methods for separating oxygen from oxygen-containing gases

    DOE Patents [OSTI]

    Mackay, Richard (Lafayette, CO); Schwartz, Michael (Boulder, CO); Sammells, Anthony F. (Boulder, CO)

    2000-01-01T23:59:59.000Z

    This invention provides mixed conducting metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes. The materials of this invention have the general formula: A.sub.x A'.sub.x A".sub.2-(x+x') B.sub.y B'.sub.y B".sub.2-(y+y') O.sub.5+z ; where x and x' are greater than 0; y and y' are greater than 0; x+x' is less than or equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the f block lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides or Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof; and B' and B" are different elements and are independently selected from the group of elements Mg or the d-block transition elements. The invention also provides methods for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula. Examples of the materials used for the preparation of the membrane include A.sub.x Sr.sub.x' B.sub.y Fe.sub.y' Co.sub.2-(y+y') O.sub.5+z, where x is about 0.3 to about 0.5, x' is about 1.5 to about 1.7, y is 0.6, y' is between about 1.0 and 1.4 and B is Ga or Al.

  8. Phosphorescent semiconductor nanocrystals and proteins for biological oxygen sensing

    E-Print Network [OSTI]

    McLaurin, Emily J. (Emily Jane)

    2011-01-01T23:59:59.000Z

    Oxygen is required for cellular respiration by all complex life making it a key metabolic profiling factor in biological systems. Tumors are defined by hypoxia (low pO2), which has been shown to influence response to ...

  9. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15T23:59:59.000Z

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  10. EMSL - oxygen-plasma

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxygen-plasma en Conversion of 1,2-Propylene Glycol on Rutile TiO2(110). http:www.emsl.pnl.govemslwebpublicationsconversion-12-propylene-glycol-rutile-tio2110

  11. Composite material and method of making

    DOE Patents [OSTI]

    Fryxell, Glen E.; Samuels, William D.; Simmons, Kevin L.

    2004-04-20T23:59:59.000Z

    The composite material and methods of making the present invention rely upon a fully dense monolayer of molecules attached to an oxygenated surface at one end, and an organic terminal group at the other end, which is in turn bonded to a polymer. Thus, the composite material is a second material chemically bonded to a polymer with fully dense monolayer there between.

  12. Optimization of Oxygen Purity for Coal Conversion Energy Reduction 

    E-Print Network [OSTI]

    Baker, C. R.; Pike, R. A.

    1982-01-01T23:59:59.000Z

    %. Oxygen is a major tonnage chemical which is also highly energy intensive. The current United States capacity of about 80 thousand tons per day places it in the top five of basic chemicals, and its energy requirement of 350 to 450 kilowatt hours per ton...

  13. A calcium oxygen secondary battery

    SciTech Connect (OSTI)

    Pujare, N.U.; Semkow, K.W.; Sammells, A.F.

    1988-01-01T23:59:59.000Z

    The authors report preliminary work performed in their laboratory on a high-temperature electrochemically reversible calcium-oxygen cell. Following an analogous strategy to that recently discussed for the lithium-oxygen secondary system, this calcium-oxygen cell utilizes stabilized zirconia oxygen vacancy conducting solid electrolytes to achieve effective separation between half-cell reactions.

  14. Oxygenates du`jour...MTBE? Ethanol? ETBE?

    SciTech Connect (OSTI)

    Wolfe, R.

    1995-12-31T23:59:59.000Z

    There are many different liquids that contain oxygen which could be blended into gasoline. The ones that have been tried and make the most sense are in the alcohol (R-OH) and ether (R-O-R) chemical family. The alcohols considered are: methanol (MeOH), ethanol (EtOH), tertiary butyl alcohol (TBA). The ethers are: methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), tertiary amyl ethyl ether (TAEE), di-isopropyl ether (DIPE). Of the eight oxygenates listed above, the author describes the five that are still waiting for widespread marketing acceptance (methanol, TBA, TAME, TAEE, and DIPE). He then discusses the two most widely used oxygenates in the US, MTBE and ethanol, along with the up-and-coming ethanol ether, ETBE. Selected physical properties for all of these oxygenates can be found in Table 2 at the end of this paper. A figure shows a simplified alcohol/ether production flow chart for the oxygenates listed above and how they are interrelated.

  15. Electrolysis of Molten Iron Oxide with an Iridium Anode: The Role of Electrolyte Basicity

    E-Print Network [OSTI]

    Kim, Hojong

    Molten oxide electrolysis (MOE) is a carbon-free, electrochemical technique to decompose a metal oxide directly into liquid metal and oxygen gas. From an environmental perspective what makes MOE attractive is its ability ...

  16. The Basicity of Texas Soils.

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach); Carlyle, E. C. (Elmer Cardinal)

    1929-01-01T23:59:59.000Z

    basicity is here used to mean the bases which neutralize dilute nitric acid, sulphuric acid or similar acids, as measured by titra- tion of the acid after contact with the soil. It is recognized that this does not correctly represent the real basicity... of the soil and other circumstances. The use of nitrate of soda on acid soils tends to reduce the acidity. A mixture of nitrate of soda and sulphate of ammonia in proper proportions will not affect the acidity of the soil. THE BASICITY OF TEXAS SOILS 7...

  17. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2003-01-01T23:59:59.000Z

    In the present quarter, the possibility of using a more complex interfacial engineering approach to the development of reliable and stable oxygen transport perovskite ceramic membranes/metal seals is discussed. Experiments are presented and ceramic/metal interactions are characterized. Crack growth and fracture toughness of the membrane in the reducing conditions are also discussed. Future work regarding this approach is proposed are evaluated for strength and fracture in oxygen gradient conditions. Oxygen gradients are created in tubular membranes by insulating the inner surface from the reducing environment by platinum foils. Fracture in these test conditions is observed to have a gradient in trans and inter-granular fracture as opposed to pure trans-granular fracture observed in homogeneous conditions. Fracture gradients are reasoned to be due to oxygen gradient set up in the membrane, variation in stoichiometry across the thickness and due to varying decomposition of the parent perovskite. The studies are useful in predicting fracture criterion in actual reactor conditions and in understanding the initial evolution of fracture processes.

  18. Direct Observation of the Oxygenated Species during Oxygen Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray...

  19. Biopower Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergyDepartmentWindConversionResults inBiopower Basics Biopower Basics

  20. 3) What makes a species invasive? i) Disturbance and land use hypothesis

    E-Print Network [OSTI]

    Nowak, Robert S.

    changes in the extent and frequency of disturbance to an ecosystem #12;3) What makes a species invasive? i3) What makes a species invasive? i) Disturbance and land use hypothesis Basic concepts: · Many;3) What makes a species invasive? i) Disturbance and land use hypothesis Basic concepts: · Invasive

  1. Oxygen Concentration Microgradients for Cell Culture

    E-Print Network [OSTI]

    Park, Jaehyun

    2010-01-01T23:59:59.000Z

    The Chemotactic Effect of Oxygen on Bacteria,” J. Pathol.Measurement and Control of Oxygen Levels in MicrofluidicA Microfabricated Electrochemical Oxygen Generator for High-

  2. Oxygen abundances in the most oxygen-rich spiral galaxies

    E-Print Network [OSTI]

    L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

    2006-01-06T23:59:59.000Z

    Oxygen abundances in the spiral galaxies expected to be richest in oxygen are estimated. The new abundance determinations are based on the recently discovered ff-relation between auroral and nebular oxygen line fluxes in HII regions. We find that the maximum gas-phase oxygen abundance in the central regions of spiral galaxies is 12+log(O/H)~8.75. This value is significantly lower than the previously accepted value. The central oxygen abundance in the Milky Way is similar to that in other large spirals.

  3. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, Donald E. (Kensington, CA)

    1992-01-01T23:59:59.000Z

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  4. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, D.E.

    1992-07-14T23:59:59.000Z

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  5. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-08-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the previous research, the reference point of oxygen occupancy was determined and verified. In the current research, the oxygen occupancy was investigated at 1200 C as a function of oxygen activity and compared with that at 1000 C. The cause of bumps at about 200 C was also investigated by using different heating and cooling rates during TGA. The fracture toughness of LSFT and dual phase membranes at room temperature is an important mechanical property. Vicker's indentation method was used to evaluate this toughness. Through this technique, a K{sub Ic} (Mode-I Fracture Toughness) value is attained by means of semi-empirical correlations between the indentation load and the length of the cracks emanating from the corresponding Vickers indentation impression. In the present investigation, crack propagation behavior was extensively analyzed in order to understand the strengthening mechanisms involved in the non-transforming La based ceramic composites. Cracks were generated using Vicker's indenter and used to identify and evaluate the toughening mechanisms involved. Preliminary results of an electron microscopy study of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Modeling of the isotopic transients on operating membranes (LSCrF-2828 at 900 C) and a ''frozen'' isotope profile have been analyzed in conjunction with a 1-D model to reveal the gradient in oxygen diffusivity through the membrane under conditions of high chemical gradients.

  6. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. The in situ electrical conductivity and Seebeck coefficient measurements were made on LSFT at 1000 and 1200 C over the oxygen activity range from air to 10{sup -15} atm. The electrical conductivity measurements exhibited a p to n type transition at an oxygen activity of 1 x 10{sup -10} at 1000 C and 1 x 10{sup -6} at 1200 C. Thermogravimetric studies were also carried out over the same oxygen activities and temperatures. Based on the results of these measurements, the chemical and mechanical stability range of LSFT were determined and defect structure was established. The studies on the fracture toughness of the LSFT and dual phase membranes exposed to air and N{sub 2} at 1000 C was done and the XRD and SEM analysis of the specimens were carried out to understand the structural and microstructural changes. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affect the mechanical properties. A complete transformation of fracture behavior was observed in the N{sub 2} treated LSFT samples. Further results to investigate the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appear to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. Recent results on transient kinetic data are presented. The 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model is used to study ''frozen'' profiles in patterned or composite membranes.

  7. Basics of advanced software Lecture 5 monoprocessor scheduling & basics of

    E-Print Network [OSTI]

    Navet, Nicolas

    /s ? · Q2: is it possible to trigger the opening of an airbag· Q2: is it possible to trigger the opening of an airbag through a 125kbit/s CAN bus ? 30/03/2012N. Navet - Basics of Advanced Software Systems - Univers

  8. Oxygen Transport Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay

    2008-08-30T23:59:59.000Z

    The focus of this research was to develop new membrane materials by synthesizing different compounds and determining their defect structures, crystallographic structures and electrical properties. In addition to measuring electrical conductivity, oxygen vacancy concentration was also evaluated using thermogravimetry, Neutron diffraction and Moessbauer Spectroscopy. The reducing conditions (CO{sub 2}/CO/H{sub 2} gas mixtures with steam) as encountered in a reactor environment can be expected to have significant influence on the mechanical properties of the oxides membranes. Various La based materials with and without Ti were selected as candidate membrane materials for OTM. The maximum electrical conductivity of LSF in air as a function of temperature was achieved at < 600 C and depends on the concentration of Sr (acceptor dopant). Oxygen occupancy in LSF was estimated using Neutron diffractometry and Moessbauer Spectroscopy by measuring magnetic moment changes depending on the Fe{sup 3+} and Fe{sup 4+} ratio. After extensive studies of candidate materials, lanthanum ferrites (LSF and LSFT) were selected as the favored materials for the oxygen transport membrane (OTM). LSF is a very good material for an OTM because of its high electronic and oxygen ionic conductivity if long term stability and mechanical strength are improved. LSFT not only exhibits p-type behavior in the high oxygen activity regime, but also has n-type conduction in reducing atmospheres. Higher concentrations of oxygen vacancies in the low oxygen activity regime may improve the performance of LSFT as an OTM. The hole concentration is related to the difference in the acceptor and donor concentration by the relation p = [Sr'{sub La}]-[Ti{sm_bullet}{sub Fe}]. The chemical formulation predicts that the hole concentration is, p = 0.8-0.45 or 0.35. Experimental measurements indicated that p is about {approx} 0.35. The activation energy of conduction is 0.2 eV which implies that LSCF conducts via the small polaron conduction mechanism. Scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS) were used to develop strategies to detect and characterize vacancy creation, dopant segregations and defect association in the oxygen conducting membrane material. The pO{sub 2} and temperature dependence of the conductivity, non-stoichiometry and thermal-expansion behavior of compositions with increasing complexity of substitution on the perovskite A and B sites were studied. Studies with the perovskite structure show anomalous behavior at low oxygen partial pressures (<10{sup -5} atm). The anomalies are due to non-equilibrium effects and can be avoided by using very strict criteria for the attainment of equilibrium. The slowness of the oxygen equilibration kinetics arises from two different mechanisms. In the first, a two phase region occurs between an oxygen vacancy ordered phase such as brownmillerite SrFeO{sub 2.5} and perovskite SrFeO{sub 3-x}. The slow kinetics is associated with crossing the two phase region. The width of the miscibility gap decreases with increasing temperature and consequently the effect is less pronounced at higher temperature. The preferred kinetic pathway to reduction of perovskite ferrites when the vacancy concentration corresponds to the formation of significant concentrations of Fe{sup 2+} is via the formation of a Ruddlesden-Popper (RP) phases as clearly observed in the case of La{sub 0.5}Sr{sub 0.5}FeO{sub 3-x} where LaSrFeO{sub 4} is found together with Fe. In more complex compositions, such as LSFTO, iron or iron rich phases are observed locally with no evidence for the presence of discrete RP phase. Fracture strength of tubular perovskite membranes was determined in air and in reducing atmospheric conditions. The strength of the membrane decreased with temperature and severity of reducing conditions although the strength distribution (Weibull parameter, m) was relatively unaltered. Surface and volume dominated the fracture origins and the overall fracture was purely transgranular. The dual phas

  9. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-02-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. Thermogravimetric analysis (TGA) was carried out on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} to investigate oxygen deficiency ({delta}) of the sample. The TGA was performed in a controlled atmosphere using oxygen, argon, carbon monoxide and carbon dioxide with adjustable gas flow rates. In this experiment, the weight loss and gain of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} was directly measured by TGA. The weight change of the sample was evaluated at between 600 and 1250 C in air or 1000 C as a function of oxygen partial pressure. The oxygen deficiencies calculated from TGA data as a function of oxygen activity and temperature will be estimated and compared with that from neutron diffraction measurement in air. The LSFT and LSFT/CGO membranes were fabricated from the powder obtained from Praxair Specialty Ceramics. The sintered membranes were subjected to microstructure analysis and hardness analysis. The LSFT membrane is composed of fine grains with two kinds of grain morphology. The grain size distribution was characterized using image analysis. In LSFT/CGO membrane a lot of grain pullout was observed from the less dense, porous phase. The hardness of the LSFT and dual phase membranes were studied at various loads. The hardness values obtained from the cross section of the membranes were also compared to that of the values obtained from the surface. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. Measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} as a function of temperature an oxygen partial pressure are reported. Further analysis of the dilatometry data obtained previously is presented. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  10. Cosmic Particle Acceleration: Basic Issues

    E-Print Network [OSTI]

    T. W. Jones

    2000-12-22T23:59:59.000Z

    Cosmic-rays are ubiquitous, but their origins are surprisingly difficult to understand. A review is presented of some of the basic issues common to cosmic particle accelerators and arguments leading to the likely importance of diffusive shock acceleration as a general explanation. The basic theory of diffusive shock acceleration is outlined, followed by a discussion of some of the key issues that still prevent us from a full understanding of its outcomes. Some recent insights are mentioned at the end that may help direct ultimate resolution of our uncertainties.

  11. Net-Baryon Physics: Basic Mechanisms

    E-Print Network [OSTI]

    J. Alvarez-Muniz; R. Conceicao; J. Dias de Deus; M. C. Espirito Santo; J. G. Milhano; M. Pimenta

    2007-11-12T23:59:59.000Z

    It is well known that, in nuclear collisions, a sizable fraction of the available energy is carried away by baryons. As the baryon number is conserved, the net-baryon $B-\\bar{B}$ retains information on the energy-momentum carried by the incoming nuclei. A simple but consistent model for net-baryon production in high energy hadron-hadron, hadron-nucleus and nucleus-nucleus collisions is presented. The basic ingredients of the model are valence string formation based on standard PDFs with QCD evolution and string fragmentation via the Schwinger mechanism. The results of the model are presented and compared with both data and existing models. These results show that a good description of the main features of net-baryon data is possible on the framework of a simplistic model, with the advantage of making the fundamental production mechanisms manifest.

  12. Basic Research Needs: Catalysis for Energy

    SciTech Connect (OSTI)

    Bell, Alexis T.; Gates, Bruce C.; Ray, Douglas; Thompson, Michael R.

    2008-03-11T23:59:59.000Z

    The report presents results of a workshop held August 6-8, 2007, by DOE SC Basic Energy Sciences to determine the basic research needs for catalysis research.

  13. Cooling System Basics | Department of Energy

    Energy Savers [EERE]

    Homes & Buildings Space Heating & Cooling Cooling System Basics Cooling System Basics August 16, 2013 - 1:08pm Addthis Cooling technologies used in homes and buildings...

  14. Hydrogen Delivery - Basics | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Delivery Hydrogen Delivery - Basics Hydrogen Delivery - Basics Photo of light-duty vehicle at hydrogen refueling station. Infrastructure is required to move hydrogen from the...

  15. Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on High-Stability-Low-Cost Supports Contiguous Platinum Monolayer Oxygen Reduction Electrocatalysts on...

  16. Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Platinum Nanoparticle Electrocatalysts for Oxygen Reduction Using Poly(diallyldimethylammonium chloride). Stabilization of Platinum Nanoparticle Electrocatalysts for Oxygen...

  17. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham

    2006-12-31T23:59:59.000Z

    Ti doping on La{sub 1-x}Sr{sub x}FeO{sub 3-{delta}} (LSF) tends to increase the oxygen equilibration kinetics of LSF in lower oxygen activity environment because of the high valence state of Ti. However, the addition of Ti decreases the total conductivity because the acceptor ([Sr{prime}{sub La}]) is compensated by the donor ([Ti{sub Fe}{sup {sm_bullet}}]) which decreases the carrier concentration. The properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 1-x}Ti{sub x}O{sub 3-{delta}} (LSFT, x = 0.45) have been experimentally and theoretically investigated to elucidate (1) the dependence of oxygen occupancy and electrochemical properties on temperature and oxygen activity by thermogravimetric analysis (TGA) and (2) the electrical conductivity and carrier concentration by Seebeck coefficient and electrical measurements. In the present study, dual phase (La{sub 0.2}Sr{sub 0.8}Fe{sub 0.6}Ti{sub 0.4}O{sub 3-{delta}}/Ce{sub 0.9}Gd{sub 0.1}O{sub 2-{delta}}) membranes have been evaluated for structural properties such as hardness, fracture toughness and flexural strength. The effect of high temperature and slightly reducing atmosphere on the structural properties of the membranes was studied. The flexural strength of the membrane decreases upon exposure to slightly reducing conditions at 1000 C. The as-received and post-fractured membranes were characterized using XRD, SEM and TG-DTA to understand the fracture mechanisms. Changes in structural properties of the composite were sought to be correlated with the physiochemical features of the two-phases. We have reviewed the electrical conductivity data and stoichiometry data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} some of which was reported previously. Electrical conductivity data for La{sub 0.2}Sr{sub 0.8}Cr{sub 0.2}Fe{sub 0.8}O{sub 3-{delta}} (LSCrF) were obtained in the temperature range, 752 {approx} 1055 C and in the pO{sub 2} range, 10{sup -18} {approx} 0.5 atm. The slope of the plot of log {sigma} vs. log pO{sub 2} is {approx} 1/5 in the p-type region, pO{sub 2} = 10{sup -5} {approx} 10{sup -1} atm. The pO{sub 2} at which the p-n transition is observed increases with increasing temperature. The activation energy for ionic conduction was estimated to be 0.86 eV from an Arrhenius plot of the minimum conductivity vs. reciprocal temperature. At temperatures below 940 C, a plateau in the conductivity isotherm suggests the presence of a two-phase region. Most likely, phase separation occurs to form a mixture of a perovskite phase and an oxygen vacancy ordered phase related to brownmillerite. Additional data for the oxygen non stoichiometry are presented.

  18. Keep Communication Professional BASIC TIPS

    E-Print Network [OSTI]

    Gering, Jon C.

    Keep Communication Professional BASIC TIPS: Staying professional in your career is vital. You the way through your career until you retire. It's important to not become too casual when communicating with employers or other professionals while seeking an internship/co-op. Don't use slang when communicating

  19. Composite oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2014-08-05T23:59:59.000Z

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  20. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Arthur J. Ragauskas

    2005-09-30T23:59:59.000Z

    The overall objective of this program was to develop improved extended oxygen delignification (EOD) technologies for current U.S. pulp mill operations. This was accomplished by: (1) Identifying pulping conditions that optimize O and OO performance; (2) Identifying structural features of lignin that enhance reactivity towards EOD of high kappa pulps; (3) Identifying factors minimizing carbohydrate degradation and improve pulp strength of EOD high kappa pulps; (4) Developing a simple, reproducible method of quantifying yield gains from EOD; and (5) Developing process conditions that significantly reduce the capital requirements of EOD while optimizing the yield benefits. Key research outcomes included, demonstrating the use of a mini-O sequence such as (E+O)Dkf:0.05(E+O) or Dkf:0.05(E+O)(E+O) without interstage washing could capture approximately 60% of the delignification efficiency of a conventional O-stage without the major capital requirements associated with an O-stage for conventional SW kraft pulps. The rate of formation and loss of fiber charge during an O-stage stage can be employed to maximize net fiber charge. Optimal fiber charge development and delignification are two independent parameters and do not parallel each other. It is possible to utilize an O-stage to enhance overall cellulosic fiber charge of low and high kappa SW kraft pulps which is beneficial for physical strength properties. The application of NIR and multi-variant analysis was developed into a rapid and simple method of determining the yield of pulp from an oxygen delignification stage that has real-world mill applications. A focus point of this program was the demonstration that Kraft pulping conditions and oxygen delignification of high and low-kappa SW and HW pulps are intimately related. Improved physical pulp properties and yield can be delivered by controlling the H-factor and active alkali charge. Low AA softwood kraft pulp with a kappa number 30 has an average improvement of 2% in yield and 4 cP in viscosity in comparison to high AA pulp for the oxygen delignification. This difference is also seen for high-kappa SW kraft pulps with an average improvement of {approx}3% in yield and 3 cP in viscosity for low AA high kappa number 50 pulp. Low AA hardwood kappa number 20 pulp had an average improvement of {approx}4% in yield and 6-12 cP in viscosity as compared to high AA pulp. Lower kraft cooking temperature (160 vs. 170 C) in combination with the medium AA provides a practical approach for integrating high kappa pulping of hardwoods (i.e., low rejects) with an advanced extended oxygen delignification stage. ECF pulp bleaching of low and high kappa kraft SW and HW pulps exhibit comparable optical and physical strength properties when bleached D(EPO)D.

  1. Biopower Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergyDepartmentWindConversionResults inBiopower Basics Biopower

  2. Bioproducts Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergyDepartmentWindConversionResults inBiopower Basics

  3. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C. It was found that space group of R3c yielded a better refinement than a cubic structure of Pm3m. Oxygen occupancy was nearly 3 in the region from room temperature to 700 C, above which the occupancy decreased due to oxygen loss. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. The X-Ray data and fracture mechanisms points to non-equilibrium decomposition of the LSFCO OTM membrane. The non-equilibrium conditions could probably be due to the nature of the applied stress field (stressing rates) and leads to transition in crystal structures and increased kinetics of decomposition. The formations of a Brownmillerite or Sr2Fe2O5 type structures, which are orthorhombic are attributed to the ordering of oxygen vacancies. The cubic to orthorhombic transitions leads to 2.6% increase in strains and thus residual stresses generated could influence the fracture behavior of the OTM membrane. Continued investigations on the thermodynamic properties (stability and phase-separation behavior) and total conductivity of prototype membrane materials were carried out. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previously characterization, stoichiometry and conductivity measurements for samples of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were reported. In this report, measurements of the chemical and thermal expansion as a function of temperature and p{sub O2} are described.

  4. Electrochemical studies of quinone oxygen

    SciTech Connect (OSTI)

    Deanhardt, M.L. (Lander College, Greenwood, SC (US)); Mushrush, G.W.; Stalick, W.M. (Chemistry Dept., George mason Univ., Fairfax, VA (US)); Watkins, J.M. Jr. (Naval Research Lab., Fuels Section, Code 6180, Washington, DC (US))

    1990-02-01T23:59:59.000Z

    Asphaltenes are a chemically complex mixture of aromatic and heteroaromatic compounds. This material contains oxygen in various functional groups. The distribution includes esters, carboxylic acids, phenolic and most probably quinone type oxygen functionalities. The present work details the complete electrochemical behaviour of quinone type oxygen. The method is quinone specific. A condensed aromatic quinone, 9,10-anthraquinone, was selected as representative of complex quinones. By this method quinones can be determined in the presence of other oxygen functional groups, alcohols, carboxylic acids, ethers, and other carbonyls.

  5. The NIEHS Superfund basic research and training program

    SciTech Connect (OSTI)

    Anderson, B. [National Inst. of Environmental Health Sciences, Research Triangle Park, NC (United States). Superfund Basic Research and Training Program; Blackard, B. [Technology Planning and Management Corp., Durham, NC (United States)

    1994-12-31T23:59:59.000Z

    The National Institute of Environmental Health Sciences (NIEHS) Superfund Basic Research and Training Program (SBRP) was established in 1986 by the Superfund Amendments and Reauthorization Act (SARA). This is a unique program of basic research and training grants directed towards understanding, assessing and attenuating the adverse effects on human health resulting from exposure to hazardous substances. The research findings from this program are being used by state, local, and federal agencies, private organizations and industry in making decisions related to the management of hazardous substances. Many innovative technologies for detecting, assessing and reducing toxic materials in the environment have been developed as a result of funding by the SBRP. To assist grantees, the SBRP has developed a technology transfer strategy designed to handle the unique problems associated with transferring multidisciplinary technology from basic research to applied research.

  6. Ion implantation method for preparing polymers having oxygen erosion resistant surfaces

    DOE Patents [OSTI]

    Lee, Eal H. (Oak Ridge, TN); Mansur, Louis K. (Clinton, TN); Heatherly, Jr., Lee (Jacksboro, TN)

    1995-01-01T23:59:59.000Z

    Hard surfaced polymers and the method for making them are generally described. Polymers are subjected to simultaneous multiple ion beam bombardment, that results in a hardening of the surface, improved wear resistance, and improved oxygen erosion resistance.

  7. 3) What makes a species invasive? d) Variable resource availability hypothesis

    E-Print Network [OSTI]

    Nowak, Robert S.

    3) What makes a species invasive? d) Variable resource availability hypothesis Davis et al. (2000) Basic concepts: · In most plant communities at most times, most of the resources that are available makes a species invasive? d) Variable resource availability hypothesis Davis et al. (2000) Basic

  8. Organizational and Individual Decision Making Organizational and Individual Decision Making

    E-Print Network [OSTI]

    Sadeh, Norman M.

    Organizational and Individual Decision Making Organizational and Individual Decision Making Citation: Kathleen M. Carley & Dean Behrens, 1999, "Organizational and Individual Decision Making." Ch. 18, Inc. #12;Organizational and Individual Decision Making Organizational and Individual Decision Making

  9. Basic visual observation skills training course: Appendix B. Final report

    SciTech Connect (OSTI)

    Toquam, J.L.; Morris, F.A.; Griggs, J.R.

    1995-06-01T23:59:59.000Z

    The purpose of the basic visual observation skills course is to help safeguards inspectors evaluate and improve their skills in making observations during inspections and in evaluating and interpreting this information. The first 12 hours of the course provide training in five skill areas: perception and recognition; attention to detail; memory; mental imaging, mapping, and modeling skills; and judgment and decision making. Following this training is an integrating exercise involving a simulated safeguards inspection. This report contains the in-class exercises in the five skill areas; pre- and post-course exercises in closure, hidden figures, map memory, and mental rotations; the final examination; a training evaluation form; and the integrating exercise.

  10. Energy Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube|6721 Federal Register /of Energy 3 BTOWebinar EnergyJuly 2012Basics Energy

  11. Sandia Energy - Basic Energy Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearch > TheNuclear Press ReleasesInApplied & Computational Math HomeBasic

  12. Biomass Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergyDepartmentWindConversionResults in First AlgaeDepartment ofBasics

  13. Hydropower Basics | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogen and FuelInnovation Portal BiomassBasics

  14. BASIC Solar | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:EzfeedflagBiomass Conversions Inc Jump to:AurigaPlantillas Jump to:­nculosAzurRB9BASIC Solar

  15. Oxygen detection using evanescent fields

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Cao, Weenqing (Los Alamos, NM)

    2007-08-28T23:59:59.000Z

    An apparatus and method for the detection of oxygen using optical fiber based evanescent light absorption. Methylene blue was immobilized using a sol-gel process on a portion of the exterior surface of an optical fiber for which the cladding has been removed, thereby forming an optical oxygen sensor. When light is directed through the optical fiber, transmitted light intensity varies as a result of changes in the absorption of evanescent light by the methylene blue in response to the oxygen concentration to which the sensor is exposed. The sensor was found to have a linear response to oxygen concentration on a semi-logarithmic scale within the oxygen concentration range between 0.6% and 20.9%, a response time and a recovery time of about 3 s, ant to exhibit good reversibility and repeatability. An increase in temperature from 21.degree. C. to 35.degree. C. does not affect the net absorption of the sensor.

  16. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-10-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, Moessbauer spectroscopy was used to study the local environmentals of LSFT with various level of oxygen deficiency. Ionic valence state, magnetic interaction and influence of Ti on superexchange are discussed Stable crack growth studies on Dense OTM bars provided by Praxair were done at elevated temperature, pressure and elevated conditions. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. An electrochemical cell has been designed and built for measurements of the Seebeck coefficient as a function of temperature and pressure. The initial measurements on La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} are reported. Neutron diffraction measurements of the same composition are in agreement with both the stoichiometry and the kinetic behavior observed in coulometric titration measurements. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The COCO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  17. Low Oxygen Environments in Chesapeake Bay

    E-Print Network [OSTI]

    Boynton, Walter R.

    Low Oxygen Environments in Chesapeake Bay Jeremy Testa Chesapeake Biological Laboratory University of Maryland Center for Environmental Science Why we care about low oxygen? What causes low oxygen? Where and When does Chesapeake Bay lose oxygen? #12;#12;Hypoxia and Chesapeake Animals Low dissolved oxygen

  18. Mixed oxygen ion/electron-conducting ceramics for oxygen separation

    SciTech Connect (OSTI)

    Stevenson, J.W.; Armstrong, B.L.; Armstrong, T.R.; Bates, J.L.; Pederson, L.R.; Weber, W.J.

    1995-05-01T23:59:59.000Z

    Solid mixed-conducting electrolytes in the series La{sub l-x}A{sub x}Co{sub l-y}Fe{sub y}O{sub 3-{delta}} (A = Sr,Ca,Ba) are potentially useful as passive membranes to separate high purity oxygen from air and as cathodes in fuel cells. All of the compositions studied exhibited very high electrical conductivities. At lower temperatures, conductivities increased with increasing temperature, characterized by activation energies of 0.05 to 0.16 eV that are consistent with a small polaron (localized electronic carrier) conduction mechanism. At higher temperatures, electronic conductivities tended to decrease with increasing temperature, which is attributed to decreased electronic carrier populations associated with lattice oxygen loss. Oxygen ion conductivities were higher than that of yttria stabilized zirconia and increased with the cobalt content and also increased with the extent of divalent A-site substitution. Thermogravimetric studies were conducted to establish the extent of oxygen vacancy formation as a function of temperature, oxygen partial pressure, and composition. These vacancy populations strongly depend on the extent of A-site substitution. Passive oxygen permeation rates were established for each of the compositions as a function of temperature and oxygen partial pressure gradient. For 2.5 mm thick membranes in an oxygen vs nitrogen partial pressure gradient, oxygen fluxes at 900 C ranged from approximately 0.3 sccm/cm{sup 2} for compositions high in iron and with low amounts of strontium A-site substitution to approximately 0.8 sccm/cm{sup 2} for compositions high in cobalt and strontium. A-site substitution with calcium instead of strontium resulted in substantially lower fluxes.

  19. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; W.B. Yelon; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-02-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and initial studies on newer composition of Ti doped LSF. Dense OTM bars provided by Praxair were loaded to fracture at varying stress rates. Studies were done at room temperature in air and at 1000 C in a specified environment to evaluate slow crack growth behavior. In addition, studies were also begun to obtain reliable estimates of fracture toughness and stable crack growth in specific environments. Newer composition of Ti doped LSF membranes were characterized by neutron diffraction analysis. Quench studies indicated an apparent correlation between the unit cell volume and oxygen occupancy. The studies however, indicated an anomaly of increasing Fe/Ti ratio with change in heat treatment. Ti doped LSF was also characterized for stoichiometry as a function of temp and pO{sub 2}. The non stoichiometry parameter {delta} was observed to increase almost linearly on lowering pO{sub 2} until a ideal stoichiometric composition of {delta} = 0.175 was approached.

  20. Basic Research Needs for the Hydrogen Economy

    Fuel Cell Technologies Publication and Product Library (EERE)

    The Basic Energy Sciences (BES) Workshop on Hydrogen Production, Storage and Use was held May 13-15, 2003 to assess the basic research needs to assure a secure energy future. This report is based on t

  1. BACK TO BASICS: YOUR KEYS TO SAFE

    E-Print Network [OSTI]

    Kirschner, Denise

    BACK TO BASICS: YOUR KEYS TO SAFE DRIVING FINE-TUNE THE FUNDAMENTALS DRIVE SAFELY WORK WEEK: FRIDAY an occasional refresher. In fact, most company fleet safety programs emphasize basic skills and defensive

  2. Back to basics: Measuring rainfall at sea

    E-Print Network [OSTI]

    Quartly, Graham

    Back to basics: Measuring rainfall at sea: Part 1 - In situ sensors G. D. Quartly, T. H. Guymer-320 #12;#12;Back to basics: Measuring rainfall at sea: Part 1 ± In situ sensors G. D. Quartly, T. H

  3. Fuel Cells - Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cells Fuel Cells - Basics Fuel Cells - Basics Photo of a fuel cell stack A fuel cell uses the chemical energy of hydrogen to cleanly and efficiently produce electricity with...

  4. On the relationship between auroral and nebular oxygen line intensities in spectra of HII regions

    E-Print Network [OSTI]

    L. S. Pilyugin

    2005-04-18T23:59:59.000Z

    We investigate relationships between observed auroral and nebular oxygen line fluxes in spectra of HII regions. We find a relation that is metallicity-dependent at low metallicities, but becomes independent of metallicity (within the uncertainties of the available data) above 12+logO/H ~ 8.25, i.e. there is one-to-one correspondance (the ff - relation) between auroral and nebular oxygen line fluxes in spectra of high-metallicity HII regions. The ff - relation allows one to estimate the flux in the auroral line from strong oxygen line measurements. This solves the problem of the electron temperature (and, consequently, abundance) determination in high-metallicity HII regions. The ff - relation confirms the basic idea of the empirical method, proposed by Pagel et al. (1979) a qurter of a century ago, that the oxygen abundance in HII region can be estimated from the strong oxygen lines measurements only.

  5. OXYGEN DIFFUSION IN UO2-x

    E-Print Network [OSTI]

    Kim, K.C.

    2013-01-01T23:59:59.000Z

    ~ K.C. K:i.m, "Oxygen Diffusion in Hypostoichiometricsystem for enriching uo 2 in oxygen-18 or for stoichiometry+nal of Nuclear Materials OXYGEN DIFFUSION IN U0 2 _:x K.C.

  6. Oxygen transfer in the implant environment

    E-Print Network [OSTI]

    Goor, Jared Braden

    2007-01-01T23:59:59.000Z

    Temperature dependence of oxygen diffusion and consumptionRN. Influence of temperature on oxygen diffusion in hamster341-347, 1988. Cox ME. Oxygen Diffusion in Poly(dimethyl

  7. PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux

    E-Print Network [OSTI]

    Mallin, Michael

    PRIMARY RESEARCH PAPER Water column oxygen demand and sediment oxygen flux: patterns of oxygen dissolved oxygen (DO) levels often occur during summer in tidal creeks along the southeastern coast of the USA. We analyzed rates of oxygen loss as water-column biochemical oxygen demand (BOD5) and sediment

  8. Your UNIX Account Basic Unix Tools

    E-Print Network [OSTI]

    Qiu, Weigang

    Your UNIX Account 2 Basic Unix Tools 3 Unix Power Tools Weigang Qiu Introduction & UNIX Tutorial #12 & UNIX Tutorial #12;Your UNIX Account Basic Unix Tools Unix Power Tools UNIX Directory Structure FileYour UNIX Account Basic Unix Tools Unix Power Tools Introduction & UNIX Tutorial Weigang Qiu

  9. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana

    2003-08-07T23:59:59.000Z

    In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

  10. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; T. Nithyanantham; X.-D Zhou; Y-W. Sin; H.U. Anderson; Alan Jacobson; C.A. Mims

    2005-11-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In the current research, the electrical conductivity and Seebeck coefficient were measured as a function of temperature in air. Based on these measurements, the charge carrier concentration, net acceptor dopant concentration, activation energy of conduction and mobility were estimated. The studies on the fracture toughness of the LSFT and dual phase membranes at room temperature have been completed and reported previously. The membranes that are exposed to high temperatures at an inert and a reactive atmosphere undergo many structural and chemical changes which affects the mechanical properties. To study the effect of temperature on the membranes when exposed to an inert environment, the membranes (LAFT and Dual phase) were heat treated at 1000 C in air and N{sub 2} atmosphere and hardness and fracture toughness of the membranes were studied after the treatment. The indentation method was used to find the fracture toughness and the effect of the heat treatment on the mechanical properties of the membranes. Further results on the investigation of the origin of the slow kinetics on reduction of ferrites have been obtained. The slow kinetics appears to be related to a non-equilibrium reduction pathway that initially results in the formation of iron particles. At long times, equilibrium can be reestablished with recovery of the perovskite phase. 2-D modeling of oxygen movement has been undertaken in order to fit isotope data. The model will serve to study ''frozen'' profiles in patterned or composite membranes.

  11. Dilute Oxygen Combustion Phase IV Final Report

    SciTech Connect (OSTI)

    Riley, M.F.

    2003-04-30T23:59:59.000Z

    Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations are critical. DOC technology will continue to have a highly competitive role in retrofit applications requiring increases in furnace productivity.

  12. Process for making structure for a MCFC

    DOE Patents [OSTI]

    Pasco, Wayne D. (Scotia, NY); Arendt, Ronald H. (Schenectady, NY)

    1986-01-01T23:59:59.000Z

    A process of making a porous carbonate-containing structure for use in a molten carbonate fuel cell, wherein a suitable porous structure is prepared having disposed therein a metal salt selected from the alkali metals and the alkaline earth metals or mixtures thereof with at least a portion of the salt being a monobasic organic acid salt. The monobasic acid salt is converted to the carbonate in situ by heating in the presence of oxygen. Both electrode and electrolyte structures can be prepared. Formic acid is preferred.

  13. Extracorporeal membrane oxygenation promotes long chain fatty...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    membrane oxygenation promotes long chain fatty acid oxidation in the immature swine heart in vivo. Extracorporeal membrane oxygenation promotes long chain fatty acid oxidation...

  14. Electrocatalytic Reactivity for Oxygen Reduction of Palladium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactivity for Oxygen Reduction of Palladium-Modified Carbon Nanotubes Synthesized in Supercritical Fluid. Electrocatalytic Reactivity for Oxygen Reduction of Palladium-Modified...

  15. OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC URANIUM DIOXIDE

    E-Print Network [OSTI]

    Kim, Kee Chul

    2010-01-01T23:59:59.000Z

    Research Division OXYGEN DIFFUSION IN HYPOSTOICHIOMETRIC11905 -DISCLAIMER - OXYGEN DIFFUSION IN HYPOSTOICHIOMETRICc o n e e n i g woroxygen self-diffusion coefficient

  16. Formation, characterization and reactivity of adsorbed oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Formation, characterization and reactivity of adsorbed oxygen on BaOPt(111). Abstract: The formation...

  17. Angling chromium to let oxygen through | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Angling chromium to let oxygen through Angling chromium to let oxygen through Released: September 10, 2014 New semiconducting material works at lower temperatures Scanning...

  18. Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies

    E-Print Network [OSTI]

    VanVeller, Brett

    The cyclization and planarization of polycyclic aromatic hydrocarbons with concomitant oxygen substitution was achieved through acid catalyzed transetherification and oxygen-radical reactions. The triptycene scaffold ...

  19. NOVA Making Stuff Season 2

    SciTech Connect (OSTI)

    Leombruni, Lisa; Paulsen, Christine Andrews

    2014-12-12T23:59:59.000Z

    Over the course of four weeks in fall 2013, 11.7 million Americans tuned in to PBS to follow host David Pogue as he led them in search of engineering and scientific breakthroughs poised to change our world. Levitating trains, quantum computers, robotic bees, and bomb-detecting plants—these were just a few of the cutting-edge innovations brought into the living rooms of families across the country in NOVA’s four-part series, Making Stuff: Faster, Wilder, Colder, and Safer. Each of the four one-hour programs gave viewers a behind-the-scenes look at novel technologies poised to change our world—showing them how basic research and scientific discovery can hold the keys to transforming how we live. Making Stuff Season 2 (MS2) combined true entertainment with educational value, creating a popular and engaging series that brought accessible science into the homes of millions. NOVA’s goal to engage the public with such technological innovation and basic research extended beyond the broadcast series, including a variety of online, educational, and promotional activities: original online science reporting, web-only short-form videos, a new online quiz-game, social media engagement and promotion, an educational outreach “toolkit” for science educators to create their own “makerspaces,” an online community of practice, a series of nationwide Innovation Cafés, educator professional development, a suite of teacher resources, an “Idealab,” participation in national conferences, and specialized station relation and marketing. A summative evaluation of the MS2 project indicates that overall, these activities helped make a significant impact on the viewers, users, and participants that NOVA reached. The final evaluation conducted by Concord Evaluation Group (CEG) confidently concluded that the broadcast, website, and outreach activities were successful at achieving the project’s intended impacts. CEG reported that the MS2 series and website content were successful in raising awareness and sparking interest in innovation, and increased public awareness that basic research leads to technological innovation; this interest was also sustained over a six month period. Efforts to create an online community of practice were also successful: the quality of collaboration increased, and community members felt supported while using Maker pedagogy. These findings provide clear evidence that large-scale science media projects like MS2 are an effective means of “moving the needle” on attitudes about and excitement for science. NOVA’s broadcast audience and ratings have always indicated that a large portion of the population is interested in and engages with educational science media on a weekly basis. Yet these evaluation results provide the empirical evidence that beyond being capable of attracting, maintaining, and growing a dedicated group of citizens interested in science, these shows—with their diverse content provided on a variety of media channels—are capable of sparking new interest in science, raising public awareness of the importance of science, and maintaining and growing that interest over time. In a country where approximately a quarter of the population doesn’t know the earth rotates around the sun,1 roughly half still don’t accept evolution,2 and about 20% don’t think climate change is happening,3 the importance of these findings cannot be overstated. The success of MS2 suggests that large-scale media projects dedicated to and linked by coverage of scientific “big ideas” are an effective means of shifting public opinion on—and improving understanding of—science. REFERENCES 1, 2 National Science Foundation, Science and Engineering Indicators (2014). Chapter 7: Science and Technology: Public Attitudes and Understanding. 3 Leiserowitz, A., Maibach, E., Roser-Renouf, C., Feinberg, G., & Rosenthal, S. (2014) Climate change in the American mind: April, 2014. Yale University and George Mason University. New Haven, CT: Yale Project on Climate Change Communication.

  20. A lithium oxygen secondary battery

    SciTech Connect (OSTI)

    Semkow, K.W.; Sammells, A.F.

    1987-08-01T23:59:59.000Z

    In principle the lithium-oxygen couple should provide one of the highest energy densities yet investigated for advanced battery systems. The problem to this time has been one of identifying strategies for achieving high electrochemical reversibilities at each electrode under conditions where one might anticipate to also achieve long materials lifetimes. This has been addressed in recent work by us via the application of stabilized zirconia oxygen vacancy conducting solid electrolytes, for the effective separation of respective half-cell reactions.

  1. Essays in decision making

    E-Print Network [OSTI]

    Chang, Tom Y., 1976-

    2009-01-01T23:59:59.000Z

    This thesis explores the impact of individual decision making on the functioning of firms and markets. The first chapter examines how deviations from strict rationality by individuals impact the market for consumer goods. ...

  2. Industrial Decision Making 

    E-Print Network [OSTI]

    Elliott, R. N.; McKinney, V.; Shipley, A.

    2008-01-01T23:59:59.000Z

    and industrial investment decision-making. The paper will also address several important questions: • Why has industrial investment declined? • What is the outlook for industrial investment? • How can programs engage industry for future opportunities?...

  3. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; Thomas W. Eagar; Harold R. Larson; Raymundo Arroyave; X.-D Zhou; Y.-W. Shin; H.U. Anderson; Nigel Browning; Alan Jacobson; C.A. Mims

    2003-11-01T23:59:59.000Z

    The present quarterly report describes some of the initial studies on newer compositions and also includes newer approaches to address various materials issues such as in metal-ceramic sealing. The current quarter's research has also focused on developing a comprehensive reliability model for predicting the structural behavior of the membranes in realistic conditions. In parallel to industry provided compositions, models membranes have been evaluated in varying environment. Of importance is the behavior of flaws and generation of new flaws aiding in fracture. Fracture mechanics parameters such as crack tip stresses are generated to characterize the influence of environment. Room temperature slow crack growth studies have also been initiated in industry provided compositions. The electrical conductivity and defect chemistry of an A site deficient compound (La{sub 0.55}Sr{sub 0.35}FeO{sub 3}) was studied. A higher conductivity was observed for La{sub 0.55}Sr{sub 0.35}FeO{sub 3} than that of La{sub 0.60}Sr{sub 0.40}FeO{sub 3} and La{sub 0.80}Sr{sub 0.20}FeO{sub 3}. Defect chemistry analysis showed that it was primarily contributed by a higher carrier concentration in La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. Moreover, the ability for oxygen vacancy generation is much higher in La{sub 0.55}Sr{sub 0.35}FeO{sub 3} as well, which indicates a lower bonding strength between Fe-O and a possible higher catalytic activity for La{sub 0.55}Sr{sub 0.35}FeO{sub 3}. The program continued to investigate the thermodynamic properties (stability and phase separation behavior) and total conductivity of prototype membrane materials. The data are needed together with the kinetic information to develop a complete model for the membrane transport. Previous report listed initial measurements on a sample of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-x} prepared in-house by Praxair. Subsequently, a second sample of powder from a larger batch of sample were characterized and compared with the results from the previous batch.

  4. Phys780: Basic Plasma Physics 1 PHYS 780. Basic Plasma Physics

    E-Print Network [OSTI]

    Phys780: Basic Plasma Physics 1 PHYS 780. Basic Plasma Physics Course objective The course objective is to introduce students to basic concepts of plasma physics and magneto-hydrodynamics with applications to solar-terrestrial physics. The course topics include: plasma classification, basic plasma prop

  5. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana; X.-D Zhou; Q. Cai; J. Yang; W.B. Yelon; W.J. James; H.U. Anderson; Alan Jacobson; C.A. Mims

    2004-05-01T23:59:59.000Z

    The present quarterly report describes some of the investigations on the structural properties of dense OTM bars provided by Praxair and studies on newer composition of Ti doped LSF. In this report, in situ neutron diffraction was used to characterize the chemical and structural properties of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} (here after as L2SF55T) specimen, which was subject to measurements of neutron diffraction from room temperature to 900 C in N{sub 2}. Space group of R3c was found to result in a better refinement and is used in this study. The difference for crystal structure, lattice parameters and local crystal chemistry for LSFT nearly unchanged when gas environment switched from air to N{sub 2}. Stable crack growth studies on Dense OTM bars provided by Praxair were done at room temperature in air. A bridge-compression fixture was fabricated to achieve stable pre-cracks from Vickers indents. Post fracture evaluation indicated stable crack growth from the indent and a regime of fast fracture. Post-fracture X-ray data of the OTM fractured at 1000 C in environment were refined by FullProf code and results indicate a distortion of the parent cubic perovskite to orthorhombic structure with reduced symmetry. TGA-DTA studies on the post-fracture samples also indicated residual effect arising from the thermal and stress history of the samples. The thermal and chemical expansion of La{sub 0.2}Sr{sub 0.8}Fe{sub 0.55}Ti{sub 0.45}O{sub 3-{delta}} were studied at 800 {le} T {le} 1000 C and at {approx} 1 x 10{sup -15} {le} pO{sub 2} {le} 0.21 atm. The thermal expansion coefficient of the sample was calculated from the dilatometric analysis in the temperature range between room temperature and 1200 C in air. A series of isotope transients under air separation mode (small gradient) were completed on the membrane of LSCrF-2828 at 900 C. Low pO{sub 2} atmospheres based on with CO-CO{sub 2} mixtures have also been admitted to the delivery side of the LSCrF-2828 membrane to produce the gradients which exist under syngas generation conditions. The CO-CO{sub 2} mixtures have normal isotopic {sup 18}O abundances. The evolution of {sup 18}O on the delivery side in these experiments after an {sup 18}O pulse on the air side reveals a wealth of information about the oxygen transport processes.

  6. A REVISED METHOD FOR ESTIMATING OXIDE BASICITY PER THE SMITH SCALE WITH EXAMPLE APPLICATION TO GLASS DURABILITY

    SciTech Connect (OSTI)

    REYNOLDS JG

    2011-07-27T23:59:59.000Z

    Previous researchers have developed correlations between oxide electronegativity and oxide basicity. The present paper revises those correlations using a newer method of calculating electronegativity of the oxygen anion. Basicity is expressed using the Smith {alpha} parameter scale. A linear relation was found between the oxide electronegativity and the Smith {alpha} parameter, with an R{sup 2} of 0.92. An example application of this new correlation to the durability of high-level nuclear waste glass is demonstrated. The durability of waste glass was found to be directly proportional to the quantity and basicity of the oxides of tetrahedrally coordinated network forming ions.

  7. OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES

    E-Print Network [OSTI]

    Truong, Thanh N.

    OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil, Fanor-rich site of the carbon basal plane of graphite and then, it dissociates into oxygen atoms.1,2 Oxygen atoms at the edge of the carbon surface can form covalent bonds with oxygen. These sites can chemisorb

  8. Electric-Drive Vehicle Basics (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2011-04-01T23:59:59.000Z

    Describes the basics of electric-drive vehicles, including hybrid electric vehicles, plug-in hybrid electric vehicles, all-electric vehicles, and the various charging options.

  9. NATIONAL ENERGY TECHNOLOGY LABORATORY Technology Transfer Basic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is an important step in mitigating environmental risks associated with conventional energy production. The Basic Immobilized Amine Sorbent (BIAS) Process is an award-winning...

  10. Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Oxygen isotopic exchange: A useful tool for characterizing oxygen conducting oxides Bassat J we obtain in both cases data concerning the oxygen diffusion in the bulk and the oxygen exchange with regards to the oxygen reduction reaction. Detailed experimental and analytical processes are given

  11. Making Li-air batteries rechargeable: material challenges

    SciTech Connect (OSTI)

    Shao, Yuyan; Ding, Fei; Xiao, Jie; Zhang, Jian; Xu, Wu; Park, Seh Kyu; Zhang, Jiguang; Wang, Yong; Liu, Jun

    2013-02-25T23:59:59.000Z

    A Li-air battery could potentially provide three to five times higher energy density/specific energy than conventional batteries, thus enable the driving range of an electric vehicle comparable to a gasoline vehicle. However, making Li-air batteries rechargeable presents significant challenges, mostly related with materials. Herein, we discuss the key factors that influence the rechargeability of Li-air batteries with a focus on nonaqueous system. The status and materials challenges for nonaqueous rechargeable Li-air batteries are reviewed. These include electrolytes, cathode (electocatalysts), lithium metal anodes, and oxygen-selective membranes (oxygen supply from air). The perspective of rechargeable Li-air batteries is provided.

  12. Electrochemical oxygen pumps. Final CRADA report.

    SciTech Connect (OSTI)

    Carter, J. D.

    2009-10-01T23:59:59.000Z

    All tasks of the Work Plan of ISTC Project 2277p have been completed, thus: (1) techniques of chemical synthesis were developed for more than ten recipes of electrolyte based on cerium oxide doped with 20 mole% of gadolinium (CeGd)O{sub 2}, doped by more than 10 oxide systems including 6 recipes in addition to the Work Plan; (2) electric conductivity and mechanical strength of CeGd specimens with additions of oxide systems were performed, two candidate materials for the electrolyte of electrochemical oxygen pump (pure CeGd and CeGd doped by 0.2 wt% of a transition metal) were chosen; (3) extended studies of mechanical strength of candidate material specimens were performed at room temperature and at 400, 600, 800 C; (4) fixtures for determination of mechanical strength of tubes by external pressure above 40 atmospheres at temperature up to 700 C were developed and fabricated; and (5) technology of slip casting of tubes from pure (Ce,Gd)O{sub 2} and of (Ce,Gd)O{sub 2} doped by 0.2 wt% of a transition metal, withstanding external pressure of minimum 40 atmospheres at temperature up to 700 C was developed, a batch of tubes was sent for testing to Argonne National Laboratory; (6) technology of making nanopowder from pure (Ce,Gd)O{sub 2} was developed based on chemical synthesis and laser ablation techniques, a batch of nanopowder with the weight 1 kg was sent for testing to Argonne National Laboratory; (7) a business plan for establishing a company for making powders of materials for electrochemical oxygen pump was developed; and (8) major results obtained within the Project were reported at international conferences and published in the Russian journal Electrochemistry. In accordance with the Work Plan a business trip of the following project participants was scheduled for April 22-29, 2006, to Tonawanda, NY, USA: Manager Victor Borisov; Leader of technology development Gennady Studenikin; Leader of business planning Elena Zadorozhnaya; Leader of production Vasily Lepalovsky; and Translator Vladimir Litvinov. During this trip project participants were to discuss with the project Technical Monitor J.D. Carter and representative of Praxair Inc. J. Chen the results of project activities (prospects of transition metal-doped material application in oxygen pumps), as well as the prospects of cooperation with Praxair at the meeting with the company management in the following fields: (1) Deposition of thin films of oxide materials of complex composition on support by magnetron and ion sputtering, research of coatings properties; (2) Development of block-type structure technology (made of porous and dense ceramics) for oxygen pump. The block-type structure is promising because when the size of electrolyte block is 2 x 2 inches and assembly height is 10 inches (5 blocks connected together) the area of active surface is ca. 290 square inches (in case of 8 slots), that roughly corresponds to one tube with diameter 1 inch and height 100 inches. So performance of the system made of such blocks may be by a factor of two or three higher than that of tube-based system. However one month before the visit, J. Chen notified us of internal changes at Praxair and the cancellation of the visit to Tonawanda, NY. During consultations with the project Technical Monitor J.D. Carter and Senior Project Manager A. Taylor a decision was made to extend the project term by 2 quarters to prepare proposals for follow-on activities during this extension (development of block-type structures made of dense and porous oxide ceramics for electrochemical oxygen pumps) using the funds that were not used for the trip to the US.

  13. Frequency Regulation Basics and Trends

    SciTech Connect (OSTI)

    Kirby, BJ

    2005-05-06T23:59:59.000Z

    The electric power system must address two unique requirements: the need to maintain a near real-time balance between generation and load, and the need to adjust generation (or load) to manage power flows through individual transmission facilities. These requirements are not new: vertically integrated utilities have been meeting them for a century as a normal part of conducting business. With restructuring, however, the services needed to meet these requirements, now called ''ancillary services'', are being more clearly defined. Ancillary services are those functions performed by the equipment and people that generate, control, and transmit electricity in support of the basic services of generating capacity, energy supply, and power delivery. The Federal Energy Regulatory Commission (FERC) has defined such services as those ''necessary to support the transmission of electric power from seller to purchaser given the obligations of control areas and transmitting utilities within those control areas to maintain reliable operations of the interconnected transmission system''. This statement recognizes the importance of ancillary services for both bulk-power reliability and support of commercial transactions. Balancing generation and load instantaneously and continuously is difficult because loads and generators are constantly fluctuating. Minute-to-minute load variability results from the random turning on and off of millions of individual loads. Longer-term variability results from predictable factors such as the daily and seasonal load patterns as well as more random events like shifting weather patterns. Generators also introduce unexpected fluctuations because they do not follow their generation schedules exactly and they trip unexpectedly due to a range of equipment failures. The output from wind generators varies with the wind. Storage technologies should be ideal suppliers of several ancillary services, including regulation, contingency reserves (spinning reserve, supplemental reserve, replacement reserve), and voltage support. These services are not free; in regions with energy markets, generators are paid to supply these services. In vertically integrated utilities (without energy markets) the utility incurs significant costs to supply these services. Supplying these services may be a significant business opportunity for emerging storage technologies. This report briefly explores the various ancillary services that may be of interest to storage. It then focuses on regulation, the most expensive ancillary service. It also examines the impact that increasing amounts of wind generation may have on regulation requirements, decreasing conventional regulation supplies, and the implications for energy storage.

  14. Future steelmaking technologies and the role of basic research

    SciTech Connect (OSTI)

    Fruehan, R.J. [Carnegie Mellon Univ., Pittsburgh, PA (United States). Dept. of Materials Science and Engineering

    1996-12-31T23:59:59.000Z

    The steel industry is going through a technological revolution which will not only change how steel is produced but, also, the entire structure of the industry. The drivers for the new or improved technologies, including reduction in capital requirements, possible shortages in raw materials such as coke and low residual scrap, environmental concerns and customer demands are briefly examined. The current status of research and development in the US and selected international producers was examined. As expected, it was found that the industry`s research capabilities have been greatly reduced. Furthermore, less than half of the companies which identified a given technology as critical have significant R and D programs addressing the technology. Examples of how basic research aided in process improvements in the past are given. The examples include demonstrating how fundamentals of reaction kinetics, improved nitrogen control, thermodynamics of systems helped reduce nozzle clogging and fluid flow studies reduced defects in casting. However, in general, basic research did not play a major role in processes previously developed, but helped understanding and aided optimization. To have a major impact, basic research must be focused and be an integral part of any new process development. An example where this has been done successfully is the AISI Direct Ironmaking and Waste Oxide Recycle Projects in which fundamental studies on reduction, slag foaming, and post combustion reactions have led to process understanding, control and optimization. Industry leaders recognize the value and need for basic research but insist it be truly relevant and done with industry input. From these examples the lessons learned on how to make basic research more effective are discussed.

  15. Oxygen uptake of benthic systems

    E-Print Network [OSTI]

    Priebe, William Franklin

    1972-01-01T23:59:59.000Z

    mg/hr/sq m between standard and maximum mixing. Hanes and Irvine (23) made a determination of the effects of temperature on quiescent oxygen uptake rates by covering sludge with aerated water and allowing the supernatant to be totally de- pleted.... ECTROLTSIS STSTDI FOA MEMURIRC BOO. FIGURE 2. SWITCH ELECTROQE IN CONTACT WITH ELECTROIYTE. OXYGEN GENERATOR OFF. FIGURE 3. SWIICH ELECI'RODE NOT IN CONTACT' WITH -' ECTROLYTE. 0 0 0 a 0 0 0 ~ O0 0 o 0 0 o o 0 0 0 0 PIERRE A. HIGH SPEED NIXINC...

  16. Oxygen uptake of benthic systems 

    E-Print Network [OSTI]

    Priebe, William Franklin

    1972-01-01T23:59:59.000Z

    mg/hr/sq m between standard and maximum mixing. Hanes and Irvine (23) made a determination of the effects of temperature on quiescent oxygen uptake rates by covering sludge with aerated water and allowing the supernatant to be totally de- pleted.... ECTROLTSIS STSTDI FOA MEMURIRC BOO. FIGURE 2. SWITCH ELECTROQE IN CONTACT WITH ELECTROIYTE. OXYGEN GENERATOR OFF. FIGURE 3. SWIICH ELECI'RODE NOT IN CONTACT' WITH -' ECTROLYTE. 0 0 0 a 0 0 0 ~ O0 0 o 0 0 o o 0 0 0 0 PIERRE A. HIGH SPEED NIXINC...

  17. Fuel cell electrolyte membrane with basic polymer

    DOE Patents [OSTI]

    Larson, James M.; Pham, Phat T.; Frey, Matthew H.; Hamrock, Steven J.; Haugen, Gregory M.; Lamanna, William M.

    2012-12-04T23:59:59.000Z

    The present invention is an electrolyte membrane comprising an acid and a basic polymer, where the acid is a low-volatile acid that is fluorinated and is either oligomeric or non-polymeric, and where the basic polymer is protonated by the acid and is stable to hydrolysis.

  18. Patent Information Basics Andrea Twiss-Brooks

    E-Print Network [OSTI]

    Ober, Carole

    Patent Information Basics Andrea Twiss-Brooks Bibliographer for Chemistry, Physics, Geophysical Patent Information Basics What are patents? Where do patents come from? Where will I see patent references? How do I find the full text of a patent? Where to go for more information? #12;11/30/2006Page 3

  19. Fuel cell electrolyte membrane with basic polymer

    DOE Patents [OSTI]

    Larson, James M. (Saint Paul, MN); Pham, Phat T. (Little Canada, MN); Frey, Matthew H. (Cottage Grove, MN); Hamrock, Steven J. (Stillwater, MN); Haugen, Gregory M. (Edina, MN); Lamanna, William M. (Stillwater, MN)

    2010-11-23T23:59:59.000Z

    The present invention is an electrolyte membrane comprising an acid and a basic polymer, where the acid is a low-volatile acid that is fluorinated and is either oligomeric or non-polymeric, and where the basic polymer is protonated by the acid and is stable to hydrolysis.

  20. Back to basics: Measuring rainfall at sea

    E-Print Network [OSTI]

    Quartly, Graham

    Back to basics: Measuring rainfall at sea: Part 2 - Space-borne sensors G. D. Quartly, T. H. Guymer-366 & ii #12;#12;Back to basics: Measuring rainfall at sea: Part 2 ­ Space-borne sensors G. D. Quartly, T are present the measure- ment will correspond to the cloud-top tem- peratures (see Fig. 1, back cover

  1. Method for making nanomaterials

    DOE Patents [OSTI]

    Fan, Hongyou; Wu, Huimeng

    2013-06-04T23:59:59.000Z

    A method of making a nanostructure by preparing a face centered cubic-ordered metal nanoparticle film from metal nanoparticles, such as gold and silver nanoparticles, exerting a hydrostatic pressure upon the film at pressures of several gigapascals, followed by applying a non-hydrostatic stress perpendicularly at a pressure greater than approximately 10 GPA to form an array of nanowires with individual nanowires having a relatively uniform length, average diameter and density.

  2. CSC418 / CSCD18 / CSC2504 Basic Lighting and Reflection 8 Basic Lighting and Reflection

    E-Print Network [OSTI]

    Toronto, University of

    CSC418 / CSCD18 / CSC2504 Basic Lighting and Reflection 8 Basic Lighting and Reflection Up things, on the lighting that illuminates the scene, and on the interaction of light with the objects in the scene. Some of the basic qualitative properties of lighting and object reflectance that we need

  3. ACT Basic Training 05/08/2009ACT Basic Training 05/08/2009ACT Basic Training 05/08/2009ACT Basic Training 05/08/2009 OFFICIAL ANNOUNCEMENT & REGISTRATION INFORMATION

    E-Print Network [OSTI]

    Zhou, Yaoqi

    ACT Basic Training 05/08/2009ACT Basic Training 05/08/2009ACT Basic Training 05/08/2009ACT Basic Training 05/08/2009 OFFICIAL ANNOUNCEMENT & REGISTRATION INFORMATION ACT Basic Training ­ May 8, 2009 PURPOSE: The ACT Basic Training is designed to help staff who are new to Assertive Community Treatment

  4. Analysis of two basic variables of timeout 

    E-Print Network [OSTI]

    Zella, William Francis

    1974-01-01T23:59:59.000Z

    ANALYSIS OF TWO BASIC VARIABLES OF TIMEOUT A Thesis WILLIAM FRANCIS ZELLA Submitted to the Graduate College of Texas AaM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August l974 Major Subjects... Psychology ANALYSI QF TWQ BASIC VARIABLES CF TINEQU '. A Thesis V/ILLIAM FRANCIS ZELLA Approved as to s+yle and content bye Chairman of Commi, ee Head of De artment) (Membe Member) Member ABSTRACT Analysis of Two Basic Variables of Timeout. (August...

  5. The Role of Oxygen in Coal Gasification 

    E-Print Network [OSTI]

    Klosek, J.; Smith, A. R.; Solomon, J.

    1986-01-01T23:59:59.000Z

    Air Products supplies oxygen to a number of coal gasification and partial oxidation facilities worldwide. At the high operating pressures of these processes, economics favor the use of 90% and higher oxygen purities. The effect of inerts...

  6. Oxygen reduction on platinum : an EIS study

    E-Print Network [OSTI]

    Golfinopoulos, Theodore

    2009-01-01T23:59:59.000Z

    The oxygen reduction reaction (ORR) on platinum over yttria-stabilized zirconia (YSZ) is examined via electrochemical impedance spectroscopy (EIS) for oxygen partial pressures between 10-4 and 1 atm and at temperatures ...

  7. Microbial oceanography of anoxic oxygen minimum zones

    E-Print Network [OSTI]

    Ulloa, Osvaldo

    Vast expanses of oxygen-deficient and nitrite-rich water define the major oxygen minimum zones (OMZs) of the global ocean. They support diverse microbial communities that influence the nitrogen economy of the oceans, ...

  8. Microchemical systems for singlet oxygen generation

    E-Print Network [OSTI]

    Hill, Tyrone F. (Tyrone Frank), 1980-

    2008-01-01T23:59:59.000Z

    Chemical Oxygen-Iodine Lasers (COIL) are a technology of interest for industrial and military audiences. COILs are flowing gas lasers where the gain medium of iodine atoms is collisionally pumped by singlet delta oxygen ...

  9. Mitochondrial reactive oxygen species and cancer

    E-Print Network [OSTI]

    Chandel, Navdeep S

    Mitochondria produce reactive oxygen species (mROS) as a natural by-product of electron transport chain activity. While initial studies focused on the damaging effects of reactive oxygen species, a recent paradigm shift ...

  10. Imaging Oxygen Molecules Up Close | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Imaging Oxygen Molecules Up Close Imaging Oxygen Molecules Up Close Released: March 20, 2011 ARRA-enabled upgrades enhance research capabilities STM images of the same TiO2(110)...

  11. Materials and methods for the separation of oxygen from air

    DOE Patents [OSTI]

    MacKay, Richard; Schwartz, Michael; Sammells, Anthony F.

    2003-07-15T23:59:59.000Z

    Metal oxides particularly useful for the manufacture of catalytic membranes for gas-phase oxygen separation processes having the formula: O.sub.5+z where: x and x' are greater than 0; y and y' are greater than 0; x+x' is equal to 2; y+y' is less than or equal to 2; z is a number that makes the metal oxide charge neutral; A is an element selected from the lanthanide elements; A' is an element selected from Be, Mg, Ca, Sr, Ba and Ra; A" is an element selected from the f block lanthanides, Be, Mg, Ca, Sr, Ba and Ra; B is an element selected from the group consisting of Al, Ga, In or mixtures thereof and B" is Co or Mg, with the exception that when B" is Mg, A' and A" are not Mg. The metal oxides are useful for preparation of dense membranes which may be formed from dense thin films of the mixed metal oxide on a porous metal oxide element. The invention also provides methods and catalytic reactors for oxygen separation and oxygen enrichment of oxygen deficient gases which employ mixed conducting metal oxides of the above formula.

  12. The Mechanisms of Oxygen Reduction and Evolution Reactions in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous...

  13. Composite oxygen ion transport element

    DOE Patents [OSTI]

    Chen, Jack C. (Getzville, NY); Besecker, Charles J. (Batavia, IL); Chen, Hancun (Williamsville, NY); Robinson, Earil T. (Mentor, OH)

    2007-06-12T23:59:59.000Z

    A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

  14. Catalyst containing oxygen transport membrane

    DOE Patents [OSTI]

    Christie, Gervase Maxwell; Wilson, Jamie Robyn; van Hassel, Bart Antonie

    2012-12-04T23:59:59.000Z

    A composite oxygen transport membrane having a dense layer, a porous support layer and an intermediate porous layer located between the dense layer and the porous support layer. Both the dense layer and the intermediate porous layer are formed from an ionic conductive material to conduct oxygen ions and an electrically conductive material to conduct electrons. The porous support layer has a high permeability, high porosity, and a high average pore diameter and the intermediate porous layer has a lower permeability and lower pore diameter than the porous support layer. Catalyst particles selected to promote oxidation of a combustible substance are located in the intermediate porous layer and in the porous support adjacent to the intermediate porous layer. The catalyst particles can be formed by wicking a solution of catalyst precursors through the porous support toward the intermediate porous layer.

  15. Effects of oxygen on fracturing fluids

    SciTech Connect (OSTI)

    Walker, M.L.; Shuchart, C.E.; Yaritz, J.G.; Norman, L.R.

    1995-11-01T23:59:59.000Z

    The stability of polysaccharide gels at high temperature is limited by such factors as pH, mechanical degradation, and oxidants. Oxygen is unavoidably placed in fracturing fluids through dissolution of air. To prevent premature degradation of the fracturing fluid by this oxidant, oxygen scavengers are commonly used. In this paper, the effects of oxygen and various oxygen scavengers on gel stability will be presented. Mechanical removal of oxygen resulted in surprisingly stable fracturing gels at 275 F. However, chemical removal of oxygen gave mixed results. Test data from sodium thiosulfate, sodium sulfite, and sodium erythorbate used as oxygen scavengers/gel stabilizers showed that the efficiency of oxygen removal from gels did not directly coincide with the viscosity retention of the gel, and large excesses of additives were necessary to provide optimum gel stabilization. The inability of some oxygen scavengers to stabilize the gel was the result of products created from the interaction of oxygen with the oxygen scavenger, which in turn, produced species that degraded the gel. The ideal oxygen scavenger should provide superior gel stabilization without creating detrimental side reaction products. Of the materials tested, sodium thiosulfate appeared to be the most beneficial.

  16. Oxygen Detection via Nanoscale Optical Indicators

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    Oxygen Detection via Nanoscale Optical Indicators Ruby N. Ghosh Dept. of Physics Michigan State University East Lansing, MI, USA weekschr@msu.edu Abstract--Oxygen plays a ubiquitous role in terrestrial developed an optical technique for monitoring oxygen in both gas and liquid phases utilizing nanoscale metal

  17. 8, 22252248, 2008 Detection of oxygen

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ACPD 8, 2225­2248, 2008 Detection of oxygen emission related to spring bloom H. Yamagishi et al Chemistry and Physics Discussions Detection of regional scale sea-to-air oxygen emission related to spring bloom near Japan by using in-situ measurements of atmospheric oxygen/nitrogen ratio H. Yamagishi 1 , Y

  18. Basic Research Needs for Countering Terrorism

    SciTech Connect (OSTI)

    Stevens, W.; Michalske, T.; Trewhella, J.; Makowski, L.; Swanson, B.; Colson, S.; Hazen, T.; Roberto, F.; Franz, D.; Resnick, G.; Jacobson, S.; Valdez, J.; Gourley, P.; Tadros, M.; Sigman, M.; Sailor, M.; Ramsey, M.; Smith, B.; Shea, K.; Hrbek, J.; Rodacy, P.; Tevault, D.; Edelstein, N.; Beitz, J.; Burns, C.; Choppin, G.; Clark, S.; Dietz, M.; Rogers, R.; Traina, S.; Baldwin, D.; Thurnauer, M.; Hall, G.; Newman, L.; Miller, D.; Kung, H.; Parkin, D.; Shuh, D.; Shaw, H.; Terminello, L.; Meisel, D.; Blake, D.; Buchanan, M.; Roberto, J.; Colson, S.; Carling, R.; Samara, G.; Sasaki, D.; Pianetta, P.; Faison, B.; Thomassen, D.; Fryberger, T.; Kiernan, G.; Kreisler, M.; Morgan, L.; Hicks, J.; Dehmer, J.; Kerr, L.; Smith, B.; Mays, J.; Clark, S.

    2002-03-01T23:59:59.000Z

    To identify connections between technology needs for countering terrorism and underlying science issues and to recommend investment strategies to increase the impact of basic research on efforts to counter terrorism.

  19. Building the Basic PVC Wind Turbine

    Broader source: Energy.gov (indexed) [DOE]

    Building the Basic PVC Wind Turbine Grades: 5-8, 9-12 Topic: Wind Energy Owner: Kidwind Project This educational material is brought to you by the U.S. Department of Energy's...

  20. Method of making L-dopa from L-tyrosine

    DOE Patents [OSTI]

    Xun, L.; Lee, J.Y.

    1998-11-17T23:59:59.000Z

    The invention is a method of making a L-dopa from L-tyrosine in the presence of an enzyme catalyst and oxygen. By starting with L-tyrosine, no variant of the L-dopa is produced and the L-dopa is stable in the presence of the enzyme catalyst. In other words, the reaction favors the L-dopa and is not reversible. 3 figs.

  1. Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Oxygen permeation in bismuth-based materials part I: Sintering and oxygen permeation fluxes E;2 Abstract Oxygen permeation measurements were performed on two layered bismuth based oxide ceramics. Oxygen permeability for these systems was compared to permeability of the cubic fluorite type structure

  2. Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as

    E-Print Network [OSTI]

    Wells, Mathew G. - Department of Physical and Environmental Sciences, University of Toronto

    Singlet Oxygen Singlet oxygen generation and detection are growing fields with applications in such areas as cancer treatment, photosensitized oxidations, and biomolecular degradation. Ground state oxygen state of an oxygen molecule is a singlet state, which can readily react with other singlet molecules

  3. Lycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic

    E-Print Network [OSTI]

    Wurtzel, Eleanore

    , quenching singlet oxygen generated during the water-splitting process of photo- synthesis (10, 11). VariousLycopene cyclase paralog CruP protects against reactive oxygen species in oxygenic photosynthetic cyclase. Instead, we show that CruP aids in preventing accumulation of reactive oxygen species (ROS

  4. Experimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine Laser

    E-Print Network [OSTI]

    Carroll, David L.

    state I. Conventionally, a two-phase (gas-liquid) chemistry singlet oxygen generator (SOG) producesExperimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine of the electric discharge iodine laser continues, the role of oxygen atoms downstream of the discharge region

  5. Making silicon stronger.

    SciTech Connect (OSTI)

    Boyce, Brad Lee

    2010-11-01T23:59:59.000Z

    Silicon microfabrication has seen many decades of development, yet the structural reliability of microelectromechanical systems (MEMS) is far from optimized. The fracture strength of Si MEMS is limited by a combination of poor toughness and nanoscale etch-induced defects. A MEMS-based microtensile technique has been used to characterize the fracture strength distributions of both standard and custom microfabrication processes. Recent improvements permit 1000's of test replicates, revealing subtle but important deviations from the commonly assumed 2-parameter Weibull statistical model. Subsequent failure analysis through a combination of microscopy and numerical simulation reveals salient aspects of nanoscale flaw control. Grain boundaries, for example, suffer from preferential attack during etch-release thereby forming failure-critical grain-boundary grooves. We will discuss ongoing efforts to quantify the various factors that affect the strength of polycrystalline silicon, and how weakest-link theory can be used to make worst-case estimates for design.

  6. 1 JUNE 2006 Bact to basics

    E-Print Network [OSTI]

    Lovley, Derek

    , forming an electric current. Courtesy Geobacter Project That's only slightly below the level industrial fermenters get while using bacteria to make ethanol for car fuel. But B subtilis has some advantages to make electricity? The ability of bacteria to make an electric current has been known since 1910

  7. Highly-basic large-pore zeolite catalysts for NOx reduction at low temperatures

    DOE Patents [OSTI]

    Penetrante, Bernardino M.; Brusasco, Raymond M.; Merritt, Bernard T.; Vogtlin, George E.

    2004-02-03T23:59:59.000Z

    A high-surface-area (greater than 600 m2/g), large-pore (pore size diameter greater than 6.5 angstroms), basic zeolite having a structure such as an alkali metal cation-exchanged Y-zeolite is employed to convert NO.sub.x contained in an oxygen-rich engine exhaust to N.sub.2 and O.sub.2. Preferably, the invention relates to a two-stage method and apparatus for NO.sub.x reduction in an oxygen-rich engine exhaust such as diesel engine exhaust that includes a plasma oxidative stage and a selective reduction stage. The first stage employs a non-thermal plasma treatment of NO.sub.x gases in an oxygen-rich exhaust and is intended to convert NO to NO.sub.2 in the presence of O.sub.2 and added hydrocarbons. The second stage employs a lean-NO.sub.x catalyst including the basic zeolite at relatively low temperatures to convert such NO.sub.2 to environmentally benign gases that include N.sub.2, CO.sub.2, and H.sub.2 O.

  8. OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES

    E-Print Network [OSTI]

    Byrn, Marianne; Calvin, Melvin

    1965-01-01T23:59:59.000Z

    OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES TWO-eng-48 OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES

  9. DOE Office of Basic Sciences: An Overview of Basic Research Activities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    & Publications Basic Energy Sciences Overview Progress from DOE EF RC: Solid-State Solar-Thermal Energy Conversion Center (S3TEC ) Grid Storage and the Energy Frontier...

  10. Developments in ITM oxygen technology for IGCC

    SciTech Connect (OSTI)

    Stein, V.E.E.; Richards, R.E.

    1999-07-01T23:59:59.000Z

    In partnership with the U.S. Department of Energy (DOE), an Air Products-led team (with Ceramatec, Eltron Research, McDermott Technology, NREC, Texaco, the Pennsylvania State University, and the University of Pennsylvania) is developing a new technology for air separation - Ion Transport Membrane Oxygen - based on the use of mixed-conducting ceramic membranes that have both electronic and oxygen ionic conductivity when operated at high temperature, typically 800 to 900 C. Under the influence of an oxygen partial-pressure driving force, the ITM Oxygen process achieves a high-purity, high-flux separation of oxygen from a compressed-air stream. By integrating the energy-rich, oxygen-depleted, non-permeate stream with a gas turbine system, the ITM Oxygen process becomes a co-producer of high-purity oxygen, power, and steam. Under a recent CRADA entitled ``Ion Transport Membranes (ITM) for Oxygen-Blown IGCC Systems and Indirect Coal Liquefaction,'' Air Products and DOE completed an initial quantification of the benefits of an ITM Oxygen-integrated IGCC facility. Compared to the cryogenic oxygen base case, the ITM Oxygen technology can potentially: reduce total installed costs by 7%; improve thermal efficiency for the integrated IGCC system by about 3%, leading to further decreases in carbon dioxide and sulfur emissions; and reduce the cost of generated electric power by more than 6%. The ITM Oxygen development project will proceed in three phases. Phase 1, which commenced under a DOE Cooperative Agreement in October 1998, is a 3-year effort focusing on construction of a technology development unit (TDU) for process concept validation tests at a capacity of 0.1 ton-per-day (TPD) oxygen. To accomplish this objective, the Air Products team will address relevant technical challenges in ITM Oxygen materials, engineering, membrane module development, and performance testing. During Phase 1 the team will also verify the economic prospects for integrating ITM Oxygen technology with IGCC and other advanced power generation systems. After at least one intermediate scaleup, Phase 2 and 3 activities will culminate with scaleup to a 25- to 50-TPD pre-commercial demonstration unit, fully integrated with a gas turbine. Meeting these challenges of developing cost-effective fabrication techniques for ITM Oxygen devices, and successfully integrating them with commercially available gas turbine engines, is key to bringing ITM Oxygen technology to the marketplace.

  11. Geothermal Heat Pump Basics | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist.NewofGeothermal Heat Pump Basics Geothermal Heat Pump Basics

  12. FEMA: Family Basic Disaster Supplies There are six basics you should stock in your home

    E-Print Network [OSTI]

    Su, Xiao

    the containers with dishwashing soap and water, and rinse completely so there is no residual soap. Follow the bottles with dishwashing soap and water, and rinse completely so #12;there is no residual soapFEMA: Family Basic Disaster Supplies There are six basics you should stock in your home: Water

  13. Merging parton showers and matrix elements -- back to basics

    E-Print Network [OSTI]

    Lavesson, Nils

    2008-01-01T23:59:59.000Z

    We make a thorough comparison between different schemes of merging fixed-order tree-level matrix element generators with parton-shower models. We use the most basic benchmark of the O(alpha_S) correction to e+e- -> jets, where the simple kinematics allows us to study in detail the transition between the matrix-element and parton-shower regions. We find that the CKKW-based schemes give a reasonably smooth transition between these regions, although problems may occur if the parton shower used is not ordered in transverse momentum. However, the so-called Pseudo-Shower and MLM schemes turn out to have potentially serious problems due to different scale definitions in different regions of phase space, and due to sensitivity to the details in the initial conditions of the parton shower programs used.

  14. Merging parton showers and matrix elements -- back to basics

    E-Print Network [OSTI]

    Nils Lavesson; Leif Lonnblad

    2008-04-23T23:59:59.000Z

    We make a thorough comparison between different schemes of merging fixed-order tree-level matrix element generators with parton-shower models. We use the most basic benchmark of the O(alpha_S) correction to e+e- -> jets, where the simple kinematics allows us to study in detail the transition between the matrix-element and parton-shower regions. We find that the CKKW-based schemes give a reasonably smooth transition between these regions, although problems may occur if the parton shower used is not ordered in transverse momentum. However, the so-called Pseudo-Shower and MLM schemes turn out to have potentially serious problems due to different scale definitions in different regions of phase space, and due to sensitivity to the details in the initial conditions of the parton shower programs used.

  15. Clean Energy Finance Guide (Chapter 5: Basic Concepts for Clean...

    Broader source: Energy.gov (indexed) [DOE]

    Provides basic concepts for Clean Energy Unsecured Lending and Loan Loss Reserve Funds. Author: U. S. Department of Energy Chapter 5: Basic Concepts for Clean Energy Unsecured...

  16. DOE Selects Seven Contractors for Waste Treatment Basic Ordering...

    Office of Environmental Management (EM)

    Selects Seven Contractors for Waste Treatment Basic Ordering Agreements DOE Selects Seven Contractors for Waste Treatment Basic Ordering Agreements June 4, 2015 - 12:00pm Addthis...

  17. Energy Saving Performance Contracting (ESPC) Basics (Text Version...

    Broader source: Energy.gov (indexed) [DOE]

    Saving Performance Contracting (ESPC) Basics (Text Version) Energy Saving Performance Contracting (ESPC) Basics (Text Version) Chani Vines: Hello. We'll be starting in five...

  18. Pamphlet, A Basic Overview of Occupational Radiation Exposure...

    Energy Savers [EERE]

    Pamphlet, A Basic Overview of Occupational Radiation Exposure Monitoring, Analysis & Reporting Pamphlet, A Basic Overview of Occupational Radiation Exposure Monitoring, Analysis &...

  19. Electricity Grid Basics Webinar Presentation Slides and Text...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity Grid Basics Webinar Presentation Slides and Text Version Electricity Grid Basics Webinar Presentation Slides and Text Version Download presentation slides and a text...

  20. applying basic science: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    basic and applied domains (physics and meteorology). We Zhao, Yuxiao 2 189188 Master of Science in Informatics, Major in Applied Informatics 189 Basic Courses (30 ECTS)...

  1. 'Grand Challenge' for Basic and Applied Research in Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    'Grand Challenge' for Basic and Applied Research in Hydrogen Storage Solicitation 'Grand Challenge' for Basic and Applied Research in Hydrogen Storage Solicitation DOE is issuing a...

  2. A Basic Overview of the Energy Employees Occupational Illness...

    Energy Savers [EERE]

    Policy, Guidance & Reports Worker Health & Safety A Basic Overview of the Energy Employees Occupational Illness Compensation Program A Basic Overview of the Energy Employees...

  3. Evaluation of GaN substrates grown in supercritical basic ammonia

    SciTech Connect (OSTI)

    Saito, Makoto; Yamada, Hisashi; Iso, Kenji; Sato, Hitoshi; Hirasawa, Hirohiko; Kamber, Derrick S.; Hashimoto, Tadao; Baars, Steven P. den; Speck, James S.; Nakamura, Shuji [Materials Department, University of California, Santa Barbara, California 93106 (United States)

    2009-02-02T23:59:59.000Z

    GaN crystals grown by the basic ammonothermal method were investigated for their use as substrates for device regrowth. X-ray diffraction analysis indicated that the substrates contained multiple grains while secondary ion mass spectroscopy (SIMS) revealed a high concentration of hydrogen, oxygen, and sodium. Despite these drawbacks, the emission from the light emitting diode structures grown by metal organic chemical vapor deposition on both the c-plane and m-plane epitaxial wafers was demonstrated. The SIMS depth profiles showed that the diffusion of the alkali metal from the substrate into the epitaxial film was small, especially in the m-direction.

  4. Opportunities for discovery: Theory and computation in Basic Energy Sciences

    SciTech Connect (OSTI)

    Harmon, Bruce; Kirby, Kate; McCurdy, C. William

    2005-01-11T23:59:59.000Z

    New scientific frontiers, recent advances in theory, and rapid increases in computational capabilities have created compelling opportunities for theory and computation to advance the scientific mission of the Office of Basic Energy Sciences (BES). The prospects for success in the experimental programs of BES will be enhanced by pursuing these opportunities. This report makes the case for an expanded research program in theory and computation in BES. The Subcommittee on Theory and Computation of the Basic Energy Sciences Advisory Committee was charged with identifying current and emerging challenges and opportunities for theoretical research within the scientific mission of BES, paying particular attention to how computing will be employed to enable that research. A primary purpose of the Subcommittee was to identify those investments that are necessary to ensure that theoretical research will have maximum impact in the areas of importance to BES, and to assure that BES researchers will be able to exploit the entire spectrum of computational tools, including leadership class computing facilities. The Subcommittee s Findings and Recommendations are presented in Section VII of this report.

  5. Bringing Order to Defects - Making Way for Oxygen to Move | U...

    Office of Science (SC) Website

    & Resources Contact Information Biological and Environmental Research U.S. Department of Energy SC-23Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301)...

  6. GOALS FOR BASIC RESEARCH IN CONSTRUCTION

    E-Print Network [OSTI]

    Tommelein, Iris D.

    1 GOALS FOR BASIC RESEARCH IN CONSTRUCTION A Report on a Workshop Sponsored by THE STANFORD CONSTRUCTION INSTITUTE and Funded by THE NATIONAL SCIENCE FQUNDATION Grant ENG 74-23lll Boyd C, Paulson, Jr, construction will be challenged by increasingly difficult and complex problems in both engineering

  7. Online Course Syllabus STATS 7: Basic Statistics

    E-Print Network [OSTI]

    Loudon, Catherine

    Online Course Syllabus Page 1 STATS 7: Basic Statistics Summer Session I 2011 Class Meeting at UC Irvine where she has been teaching statistics for many years. She is also involved in the development of educational material for statistics, from helping to conceive a TV program for distance

  8. of Basic Energy S Present, Shaping

    E-Print Network [OSTI]

    Kemner, Ken

    , Office of Basic Energy Sciences In July of 1996, the camera recording APS construction captured; the Argonne central campus and the APS central laboratory office building are beneath the lightning strike for Nanoscale Materials (CNM) Nanoprobe beamline at sector 26. Our p

  9. Molecular Biology Basics Planning Restriction Enzyme Digests

    E-Print Network [OSTI]

    Aris, John P.

    Molecular Biology Basics Planning Restriction Enzyme Digests A. Checklist: Buffer type Addition of BSA Optimum temperature Number of units of enzyme B. Plan to digest DNA with an "excess" of enzyme activity. Plan for the "excess" to be divided between time of digestion and number of units of enzyme

  10. BACK TO BASICS: YOUR KEYS TO SAFE

    E-Print Network [OSTI]

    Kirschner, Denise

    BACK TO BASICS: YOUR KEYS TO SAFE DRIVING BUCKLE UP! Seat belts should never have time off DRIVE the back seat to the front seat.4 ·The back is the best place for pets. According to AAA, similar. Never place the shoulder portion under your arm or behind your back! ·Drivers should sit with at least

  11. Sam Madden Basically Everyone Except My Bank

    E-Print Network [OSTI]

    O'Brien, James F.

    Sam Madden Physicists Biologists Basically Everyone Except My Bank #12;· Benefit(DBMS) DBMS? · DBMS setup & boundary crossings painful ­ Especially if you have to do it multiple times! MATLAB a fleet of 40 cabs on Boston streets · Pipeline ­ Raw data in DBMS ­ Trajectories with Matlab ­ Queries

  12. Event simulation for colliders - A basic overview

    E-Print Network [OSTI]

    Christian Reuschle

    2014-11-26T23:59:59.000Z

    In this article we will discuss the basic calculational concepts to simulate particle physics events at high energy colliders. We will mainly focus on the physics in hadron colliders and particularly on the simulation of the perturbative parts, where we will in turn focus on the next-to-leading order QCD corrections.

  13. (Basic properties of coals and other solids)

    SciTech Connect (OSTI)

    Not Available

    1991-11-25T23:59:59.000Z

    This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number sign}8, Illinois {number sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

  14. NPTEL Syllabus Basic Electrical Circuits -Video course

    E-Print Network [OSTI]

    Krishnapura, Nagendra

    with an introduction to basic linear elements used in electrical circuits. Mesh and node analysis for systematic analysis of large circuits will be studied. Fundamental circuit theorems and their use in analysis steady state analysis for simple analysis of such circuits will be studied. The concepts of power

  15. Climate Change Basics: Science, Adaptation, & Mitigation

    E-Print Network [OSTI]

    Fox-Kemper, Baylor

    Science Global atmospheric concentrations of carbon dioxide, methane and nitrous oxide have increased from ice cores spanning many thousands of years. The global increases in carbon dioxide concentrationClimate Change Basics: Science, Adaptation, & Mitigation with a Family Forest Perspective Baylor

  16. Myocardial Reloading after Extracorporeal Membrane Oxygenation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protein Synthesis. Abstract: Extracorporeal membrane oxygenation (ECMO) unloads the heart providing a bridge to recovery in children after myocardial stunning. Mortality after...

  17. The Role of Oxygen in Coal Gasification

    E-Print Network [OSTI]

    Klosek, J.; Smith, A. R.; Solomon, J.

    in downst eam absorbs oxygen from air at low pressure by units. Selection of the optimum oxygen urHy contact with a circulating molten salt. High must be performed by optimizing the capit land purity (>99.5%) oxygen is regenerated from the operating... are evaluated, the use of oxygen is often preferred over air regardless of the pressure requirement. GOX GAN WASTE AIR FROM MOL SIEVE MAIN EXCHANGERS EXPANDER Figure 4 - Low Pressure Cryogenic Cycle Below about 95% purity, the specific power (k...

  18. Making Hard Choices: Using Data to Make Collections Decisions

    E-Print Network [OSTI]

    Edwards, Susan E.

    2014-01-01T23:59:59.000Z

    analysis methodologies for collection management. College &2012). Relevance of library collections for graduate studentUsing Data to Make Collections Decisions Susan Elizabeth

  19. Evolution of Photosynthesis and Biospheric Oxygenation Contingent Upon Nitrogen Fixation?

    E-Print Network [OSTI]

    John W. Grula

    2006-05-12T23:59:59.000Z

    How photosynthesis by Precambrian cyanobacteria oxygenated Earth's biosphere remains incompletely understood. Here it is argued that the oxic transition, which took place between approximately 2.3 and 0.5 Gyr ago, required a great proliferation of cyanobacteria, and this in turn depended on their ability to fix nitrogen via the nitrogenase enzyme system. However, the ability to fix nitrogen was not a panacea, and the rate of biospheric oxygenation may still have been affected by nitrogen constraints on cyanobacterial expansion. Evidence is presented for why cyanobacteria probably have a great need for fixed nitrogen than other prokaryotes, underscoring the importance of their ability to fix nitrogen. The connection between nitrogen fixation and the evolution of photosynthesis is demonstrated by the similarities between nitrogenase and enzymes critical for the biosynthesis of (bacterio)chlorophyll. It is hypothesized that biospheric oxygenation would not have occurred if the emergence of cyanobacteria had not been preceded by the evolution of nitrogen fixation, and if these organisms had not also acquired the ability to fix nitrogen at the beginning of or very early in their history. The evolution of nitrogen fixation also appears to have been a precondition for the evolution of (bacterio)chlorophyll-based photosynthesis. Given that some form of chlorophyll is obligatory for true photosynthesis, and its light absorption and chemical properties make it a "universal pigment," it may be predicted that the evolution of nitrogen fixation and photosynthesis are also closely linked on other Earth- like planets.

  20. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y. Simon (Lakewood, CO)

    1991-01-01T23:59:59.000Z

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

  1. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y.S.

    1991-08-20T23:59:59.000Z

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used. 5 figures.

  2. Transient oxygen consumption rate measurements with the BDT?M? oxygen biosensor system

    E-Print Network [OSTI]

    Low, Clarke Alan

    2008-01-01T23:59:59.000Z

    Oxygen consumption rate (OCR) is a reliable indicator of tissue health. Recently, the OCR of isolated human islets has been shown to predict transplant outcome in diabetic mice. The Oxygen Biosensor System (OBS) is a ...

  3. High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen

    E-Print Network [OSTI]

    Sibener, Steven

    High density adsorbed oxygen on Rh,,111... and enhanced routes to metallic oxidation using atomic oxygen K. D. Gibson, Mark Viste, Errol C. Sanchez, and S. J. Sibener The James Franck Institute; accepted 30 November 1998 Exposure of Rh 111 to atomic oxygen leads to the facile formation of a full

  4. Department of Basic Sciences Philadelphia University Module Syllabus

    E-Print Network [OSTI]

    Department of Basic Sciences ­ Philadelphia University Module Syllabus: Course Title: Computational

  5. Oxygen and Nitrogen Contamination During Arc Welding

    E-Print Network [OSTI]

    Eagar, Thomas W.

    ) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, shielded metal arc, self-shielded metal arc, and submerged arc welding are reviewed. Calcu- lations upon heating is also discussed. Introduction Oxygen and nitrogen ~ontamination of weld metal

  6. New Oxygen-Production Technology Proving Successful

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy's National Energy Technology Laboratory has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies.

  7. National Energy Information System basic concepts

    SciTech Connect (OSTI)

    Not Available

    1980-07-01T23:59:59.000Z

    The basic concepts on which the National Energy Information System (NEIS) rests are described and clarified. Identified are the current state of, as well as future information gathering activities of the system. The NEIS was originally created under Congressional mandate to collect, process, and disseminate data useful for analysis of energy supply and consumption issues. An overview of NEIS, data descriptions, metadata (directories, documentation), and procedures of the NEIS system are discussed in a question-and-answer format.

  8. 1. BASICS 1 1 Lattices 1

    E-Print Network [OSTI]

    Micciancio, Daniele

    Contents Preface ix 1. BASICS 1 1 Lattices 1 1.1 Determinant 6 1.2 Successive minima 7 1.3 Minkowski's theorems 11 2 Computational problems 14 2.1 Complexity Theory 15 2.2 Some lattice problems 17 2.3 Hardness of approximation 19 3 Notes 21 2. APPROXIMATION ALGORITHMS 23 1 Solving SVP in dimension 2 24 1.1

  9. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2001-04-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the fourth quarter January-March 2001 in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes and Task 4 - Program Management. This report will also recap the results of the past year. The program is proceeding in accordance with the objectives for the first year. OTM material characterization was completed. 100% of commercial target flux was demonstrated with OTM disks. The design and assembly of Praxair's single tube high-pressure test facility was completed. The production of oxygen with a purity of better than 99.5% was demonstrated. Coal combustion testing was conducted at the University of Arizona. Modest oxygen enhancement resulted in NOx emissions reduction. The injector for oxygen enhanced coal based reburning was conducted at Praxair. Combustion modeling with Keystone boiler was completed. Pilot-scale combustion test furnace simulations continued this quarter.

  10. Method of making monodisperse nanoparticles

    DOE Patents [OSTI]

    Fan, Hongyon; Sun, Zaicheng

    2012-10-16T23:59:59.000Z

    A method of making particles of either spherical or cylindrical geometry with a characteristic diameter less than 50 nanometers by mixing at least one structure directing agent dissolved in a solvent with at least one amphiphilic block copolymer dissolved in a solvent to make a solution containing particles, where the particles can be subsequently separated and dispersed in a solvent of choice.

  11. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01T23:59:59.000Z

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

  12. Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen minimum zone (7001100 m)

    E-Print Network [OSTI]

    Levin, Lisa

    Oxygen and organic matter thresholds for benthic faunal activity on the Pakistan margin oxygen increased animal activity associated with increasing bottom-water oxygen concentration. We examined faunal community responses to oxygen and organic matter gradients across the lower oxygen minimum zone (OMZ

  13. Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen-Iodine Laser System

    E-Print Network [OSTI]

    Carroll, David L.

    Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen a low-pressure oxygen/helium/nitric oxide discharge. In the electric discharge oxygen-iodine laser (ElectricOIL) the discharge production of atomic oxygen, ozone, and other excited species adds levels

  14. Long-term oxygen sensor implantation in the porcine subcutaneous environment

    E-Print Network [OSTI]

    Kumosa, Lucas Stefan

    2011-01-01T23:59:59.000Z

    Membrane-­?Covered  Oxygen  Electrode.   Analytical  Microvascular  and  tissue  oxygen   distribution.  vitro  stability  of  an  oxygen  sensor.   Anal  Chem,  

  15. Oxygen Tension Modulates Neurite Outgrowth in PC12 Cells Through A Mechanism Involving HIF and VEGF

    E-Print Network [OSTI]

    Genetos, Damian C.; Cheung, Whitney K.; Decaris, Martin L.; Leach, J. Kent

    2010-01-01T23:59:59.000Z

    neural repair. Keywords Oxygen tension . Neurite extension .respective physiological oxygen microenvironments (Chen etet al. 2008). For example, oxygen tension differentially

  16. On the oxygen abundance in our Galaxy

    E-Print Network [OSTI]

    L. S. Pilyugin; F. Ferrini; R. V. Shkvarun

    2003-02-03T23:59:59.000Z

    The compilation of published spectra of Galactic HII regions with available diagnostic [OIII]4363 line has been carried out. Our list contains 71 individual measurements of 13 HII regions in the range of galactocentric distances from 6.6 to 14.8 kpc. The oxygen abundances in all the HII regions were recomputed in the same way, using the classic Te - method. The oxygen abundance at the solar galactocentric distance traced by those HII regions is in agreement with the oxygen abundance in the interstellar medium in the solar vicinity derived with high precision from the interstellar absorption lines towards stars. The derived radial oxygen abundance distribution was compared with that for HII regions from the Shaver et al. (1983) sample which is the basis of many models for the chemical evolution of our Galaxy. It was found that the original Shaver et al.'s oxygen abundances are overestimated by 0.2-0.3 dex. Oxygen abundances in HII regions from the Shaver et al. sample have been redetermined with the recently suggested P - method. The radial distribution of oxygen abundances from the Shaver et al. sample redetermined with the P - method is in agreement with our radial distribution of (O/H)_Te abundances.

  17. Hydroxyalkyl phosphine gold complexes for use as diagnostic and therapeutic pharmaceuticals and method of making same

    DOE Patents [OSTI]

    Katti, Kattesh V. (Columbia, MO); Berning, Douglas E. (Columbia, MO); Volkert, Wynn A. (Columbia, MO); Ketring, Alan R. (Columbia, MO)

    1998-01-01T23:59:59.000Z

    A complex and method for making same for use as a diagnostic or therapeutic pharmaceutical includes a ligand comprising at least one hydroxyalkyl phosphine donor group bound to a gold atom to form a gold-ligand complex that is stable in aqueous solutions containing oxygen, serum and other body fluids.

  18. Hydroxyalkyl phosphine gold complexes for use as diagnostic and therapeutic pharmaceuticals and method of making same

    DOE Patents [OSTI]

    Katti, K.V.; Berning, D.E.; Volkert, W.A.; Ketring, A.R.

    1998-12-01T23:59:59.000Z

    A complex and method for making a diagnostic or therapeutic pharmaceutical includes a ligand comprising at least one hydroxyalkyl phosphine donor group bound to a gold atom to form a gold-ligand complex that is stable in aqueous solutions containing oxygen, serum and other body fluids. 20 figs.

  19. Characterization of an oxygen suspension used for intravenous infusion

    E-Print Network [OSTI]

    Peña, Kristen Helen

    2012-01-01T23:59:59.000Z

    Oxygenated fluid mixture can be used to treat critically ill patients suffering from asphyxia, lung injury, and cardiac arrest. This oxygenated fluid delivered intravenously re-oxygenates the bloodstream, allowing for more ...

  20. Blood oxygen transport and depletion : the key of consummate divers

    E-Print Network [OSTI]

    Meir, Jessica Ulrika

    2009-01-01T23:59:59.000Z

    and Dill, D. B. (1935). Oxygen dissociation curves of birdE. (1964). A venous blood oxygen reservoir in the divingand Torrance, J. D. (1977). Oxygen-Affinity of Avian Blood.

  1. Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Imaging Intrinsic Diffusion of Bridge-Bonded Oxygen Vacancies on TiO2(110). Abstract: Since oxygen atom...

  2. Oxygen Coverage Dependence of NO Oxidation on Pt(111). | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen Coverage Dependence of NO Oxidation on Pt(111). Oxygen Coverage Dependence of NO Oxidation on Pt(111). Abstract: The interaction of NO with adsorbed atomic oxygen on Pt(111)...

  3. Reactive oxygen species: a breath of life or death?

    E-Print Network [OSTI]

    Fruehauf, John P; Meyskens, Frank L Jr

    2007-01-01T23:59:59.000Z

    AP1, activator protein-1; ODD, oxygen-dependent degradationSignaling response when oxygen levels decrease (Fig. 1C;3. Halliwell B. Reactive oxygen species in living sys- tems:

  4. Conceptual design report, CEBAF basic experimental equipment

    SciTech Connect (OSTI)

    NONE

    1990-04-13T23:59:59.000Z

    The Continuous Electron Beam Accelerator Facility (CEBAF) will be dedicated to basic research in Nuclear Physics using electrons and photons as projectiles. The accelerator configuration allows three nearly continuous beams to be delivered simultaneously in three experimental halls, which will be equipped with complementary sets of instruments: Hall A--two high resolution magnetic spectrometers; Hall B--a large acceptance magnetic spectrometer; Hall C--a high-momentum, moderate resolution, magnetic spectrometer and a variety of more dedicated instruments. This report contains a short description of the initial complement of experimental equipment to be installed in each of the three halls.

  5. Annual report, Basic Sciences Branch, FY 1991

    SciTech Connect (OSTI)

    Not Available

    1993-04-01T23:59:59.000Z

    This report summarizes the progress of the Basic Sciences Branch of the National Renewable Energy Laboratory (NREL) from October 1, 1990, through September 30, 1991. Seven technical sections of the report cover these main areas of NREL's in-house research: Semiconductor Crystal Growth, Amorphous Silicon Research, Polycrystalline Thin Films, III-V High-Efficiency Photovoltaic Cells, Solid-State Theory, Solid-State Spectroscopy, and Superconductivity. Each section explains the purpose and major accomplishments of the work in the context of the US Department of Energy's National Photovoltaic Research Program plans.

  6. Photovoltaic Cell Structure Basics | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2:Introduction toManagementOPAM5Parabolic TroughPhotoCell Structure Basics Photovoltaic Cell

  7. Photovoltaic Silicon Cell Basics | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2:Introduction toManagementOPAM5Parabolic TroughPhotoCell Structure Basics

  8. Photovoltaic System Performance Basics | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2:Introduction toManagementOPAM5Parabolic TroughPhotoCell Structure BasicsEnergySystem

  9. Photovoltaic System Basics | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO Overview OCHCO Overview OCHCO OCHCOControlGuide to aEnergy LivingSystem Basics

  10. The Basics of Underground Natural Gas Storage

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122 40 Buildingto17 34 44Year Jan Feb Mar Apr May Jun Jul2011Dry ProductionThe Basics

  11. Ventilation System Basics | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed off Energy.gov. Are you sureReportsofDepartmentSeries |Attacks | DepartmentVentilation System Basics

  12. NREL: Concentrating Solar Power Research - Technology Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Saleshttp://www.fnal.gov/directorate/nalcal/nalcal02_07_05_files/nalcal.gifNREL NRELChemical andWhatTechnology Basics Concentrating

  13. Basic Instructor Training | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureComments fromof EnergyBILIWG:Background:BagdadBaseballs andBasic

  14. Basic Plasma Science | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMForms About BecomeTechnologiesVehicleAuthorAwardsarticleOfficeBasic

  15. NREL: Learning - Fuel Cell Vehicle Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for Renewable Energy: Grid Integration NREL isDataWorking withFuel Cell Vehicle Basics

  16. Alternative Fuels Data Center: Hydrogen Basics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisiting the TWP TWP RelatedCellulase C.Tier 2NorthAvailabilityBasics to someone by

  17. Radiant Heating Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of ContaminationHubs+18, 2012 Qualified11 Connecticut Ave NW,Radiant Heating Basics

  18. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies. Tetraoxygen on Reduced Ti02(110): Oxygen Adsorption and Reactions with Oxygen Vacancies....

  19. On the maximum value of the cosmic abundance of oxygen and the oxygen yield

    E-Print Network [OSTI]

    L. S. Pilyugin; T. X. Thuan; J. M. Vilchez

    2007-01-11T23:59:59.000Z

    We search for the maximum oxygen abundance in spiral galaxies. Because this maximum value is expected to occur in the centers of the most luminous galaxies, we have constructed the luminosity - central metallicity diagram for spiral galaxies, based on a large compilation of existing data on oxygen abundances of HII regions in spiral galaxies. We found that this diagram shows a plateau at high luminosities (-22.3 oxygen abundance 12+log(O/H) ~ 8.87. This provides strong evidence that the oxygen abundance in the centers of the most luminous metal-rich galaxies reaches the maximum attainable value of oxygen abundance. Since some fraction of the oxygen (about 0.08 dex) is expected to be locked into dust grains, the maximum value of the true gas+dust oxygen abundance in spiral galaxies is 12+log(O/H) ~ 8.95. This value is a factor of ~ 2 higher than the recently estimated solar value. Based on the derived maximum oxygen abundance in galaxies, we found the oxygen yield to be about 0.0035, depending on the fraction of oxygen incorporated into dust grains.

  20. Three essays in decision making

    E-Print Network [OSTI]

    Weaver, Ray, Ph. D. Massachusetts Institute of Technology

    2008-01-01T23:59:59.000Z

    This dissertation is composed of three essays about consumer judgment and decision making. In Essay 1, I develop a novel explanation for the well-known endowment effect - the tendency for owners to value goods more than ...

  1. Temporal Work in Strategy Making

    E-Print Network [OSTI]

    Kaplan, Sarah

    This paper reports on a field study of strategy making in one organization facing an industry crisis. In a comparison of five strategy projects, we observed that organizational participants struggled with competing ...

  2. Making Decisions with Enterprise Budgets

    E-Print Network [OSTI]

    Smith, Jackie; McCorkle, Dean; Outlaw, Joe

    2000-11-08T23:59:59.000Z

    Enterprise budgets can help farmers and ranchers make better decisions about what products to produce and how to produce them economically. This publication tells how to create and use enterprise budgets and includes an example....

  3. Method of making alkyl esters

    DOE Patents [OSTI]

    Elliott, Brian (Wheat Ridge, CO)

    2010-09-14T23:59:59.000Z

    Methods of making alkyl esters are described herein. The methods are capable of using raw, unprocessed, low-cost feedstocks and waste grease. Generally, the method involves converting a glyceride source to a fatty acid composition and esterifying the fatty acid composition to make alkyl esters. In an embodiment, a method of making alkyl esters comprises providing a glyceride source. The method further comprises converting the glyceride source to a fatty acid composition comprising free fatty acids and less than about 1% glyceride by mass. Moreover, the method comprises esterifying the fatty acid composition in the presence of a solid acid catalyst at a temperature ranging firm about 70.degree. C. to about 120.degree. C. to produce alkyl esters, such that at least 85% of the free fatty acids are converted to alkyl esters. The method also incorporates the use of packed bed reactors for glyceride conversion and/or fatty acid esterification to make alkyl esters.

  4. CALS Student Making Strides In

    E-Print Network [OSTI]

    Florida, University of

    CALS Student Making Strides In Jaguar Conservation Building Better Peppers Aquaponics Working Conservation 7 Celebrating AgFacts Day 8 Aquaponics Working to Sustain the World 9 Students Get Their Feet Wet

  5. Oxygen-Enriched Combustion for Military Diesel Engine Generators...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygen-Enriched Combustion for Military Diesel Engine Generators Oxygen-Enriched Combustion for Military Diesel Engine Generators Substantial increases in brake power and...

  6. Advantages of Oxygenates Fuels over Gasoline in Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines...

  7. avec oxygenation modelisation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experimental calibration of oxygen isotope fractionation between quartz and zircon Dustin Trail a the results of an experimental calibration of oxygen isotope fractionation...

  8. Electron-Stimulated Production of Molecular Oxygen in Amorphous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water. Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water. Abstract: The low-energy, electron-stimulated production of molecular oxygen from pure amorphous...

  9. Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium Oxygen Diffusion (OD) Dramatically Improves Wear-Resistance of Titanium 2007 Diesel Engine-Efficiency &...

  10. Isolation, Characterization of an Intermediate in an Oxygen Atom...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Characterization of an Intermediate in an Oxygen Atom-Transfer Reaction, and the Determination of the Bond Isolation, Characterization of an Intermediate in an Oxygen Atom-Transfer...

  11. Theoretical Study of the Structure, Stability and Oxygen Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Study of the Structure, Stability and Oxygen Reduction Activity ofUltrathin Platinum Nanowires. Theoretical Study of the Structure, Stability and Oxygen Reduction Activity...

  12. Density Functional Study of the Structure, Stability and Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Study of the Structure, Stability and Oxygen Reduction Activity of Ultrathin Platinum Nanowires. Density Functional Study of the Structure, Stability and Oxygen Reduction Activity...

  13. Testing Oxygen Reduction Reaction Activity with the Rotating...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique...

  14. Fractionation of Oxygen Isotopes in Phosphate during its Interactions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides. Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides....

  15. Effects of Oxygen-Containing Functional Groups on Supercapacitor...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effects of Oxygen-Containing Functional Groups on Supercapacitor Performance. Effects of Oxygen-Containing Functional Groups on Supercapacitor Performance. Abstract: Molecular...

  16. Oxygen detected in atmosphere of Saturn's moon Dione

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen detected in atmosphere of Saturn's moon Dione Oxygen detected in atmosphere of Saturn's moon Dione Scientists and an international research team have announced discovery of...

  17. Virtual Oxygen Sensor for Innovative NOx and PM Emission Control...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies Virtual Oxygen Sensor for Innovative NOx and PM Emission Control Technologies A virtual O2 sensor for...

  18. Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Bimetallic and Ternary Alloys for Improved Oxygen Reduction Catalysis . Abstract: The research described in...

  19. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measurement of Oxygen Incorporation into Thin Film Oxides at Room Temperature Upon Ultraviolet Phton Irradiation. Direct Measurement of Oxygen Incorporation into Thin Film Oxides...

  20. Oxygen Transport Studies in Nanocrystalline Ceria Films. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transport Studies in Nanocrystalline Ceria Films. Oxygen Transport Studies in Nanocrystalline Ceria Films. Abstract: Oxygen uptake and conductivity were measured by nuclear...

  1. Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From...

    Open Energy Info (EERE)

    Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Oxygen...

  2. Density Functional Theory Study of Oxygen Reduction Activity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Density Functional Theory Study of Oxygen Reduction Activity on Ultrathin Platinum Nanotubes. Density Functional Theory Study of Oxygen Reduction Activity on Ultrathin Platinum...

  3. Design optimization of oxygenated fluid pump

    E-Print Network [OSTI]

    Piazzarolo, Bruno Aiala

    2012-01-01T23:59:59.000Z

    In medical emergencies, an oxygen-starved brain quickly suffers irreparable damage. In many cases, patients who stop breathing can be resuscitated but suffer from brain damage. Dr. John Kheir from Boston Children's Hospital ...

  4. Reactive Gliosis Reactive Oxygen Species: Superoxide

    E-Print Network [OSTI]

    . By sensing the electric signals generated by other 3368 Reactive Gliosis #12;individuals, mormyrids are alsoReactive Gliosis Glial Scar Reactive Oxygen Species: Superoxide Anions Neuroinflammation motor output. Reafferent Control in Electric Communication Reafferent Control in Electric Communication

  5. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-08-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the thirteenth quarter, April-June 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with project objectives. REI's model was modified to evaluate mixing issues in the upper furnace of a staged unit. Analysis of the results, and their potential application to this unit is ongoing. Economic evaluation continues to confirm the advantage of oxygen-enhanced combustion. A contract for a commercial demonstration has been signed with the Northeast Generation Services Company to supply oxygen and license the oxygen enhanced low NOx combustor technology for use at the 147-megawatt coal fired Mt. Tom Station in Holyoke, MA. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  6. Electron-impact excitation of neutral oxygen

    E-Print Network [OSTI]

    P. S. Barklem

    2006-09-25T23:59:59.000Z

    Aims: To calculate transition rates from ground and excited states in neutral oxygen atoms due to electron collisions for non-LTE modelling of oxygen in late-type stellar atmospheres, thus enabling reliable interpretation of oxygen lines in stellar spectra. Methods: A 38-state R-matrix calculation in LS-coupling has been performed. Basis orbitals from the literature (Thomas et al.) are adopted, and a large set of configurations are included to obtain good representations of the target wavefunctions. Rate coefficients are calculated by averaging over a Maxwellian velocity distribution. Results: Estimates for the cross sections and rate coefficients are presented for transitions between the seven lowest LS states of neutral oxygen. The cross sections for excitation from the ground state compare well with existing experimental and recent theoretical results.

  7. Dynamic Nuclear Polarization of Oxygen-17

    E-Print Network [OSTI]

    Michaelis, Vladimir K.

    Oxygen-17-detected DNP NMR of a water/glycerol glass enabled an 80-fold enhancement of signal intensity at 82 K, using the biradical TOTAPOL. The >6000-fold savings in acquisition time enable [superscript 17]O–[superscript ...

  8. Magnetism in Lithium–Oxygen Discharge Product

    SciTech Connect (OSTI)

    Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

    2013-05-13T23:59:59.000Z

    Nonaqueous lithium–oxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithium–oxygen batteries. We demonstrate that the major discharge product formed in the lithium–oxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium– oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

  9. Atomic Oxygen in the Comae of Comets

    E-Print Network [OSTI]

    Anita L. Cochran

    2008-07-03T23:59:59.000Z

    We report on the detection of atomic oxygen lines in the spectra of 8 comets. These forbidden lines are a result of the photodissociation of the parent oxygen-bearing species directly into an excited state. We used high resolution spectra obtained at the McDonald Observatory 2.7m telescope to resolve the cometary oxygen lines from the telluric oxygen lines and from other cometary emissions. We find that the relative intensities of the two red lines (6300.304 and 6363.776A) are consistent with theory. The green line (5577.339A) has an intensity which is about 10% of the sum of the intensities of the two red lines. We show that collisional quenching may be important in the inner coma. If we assume the relative excitation rates of potential parents which have appeared in the literature, then H2O would be the parent of the cometary green oxygen line. However, those rates have been questioned. We measured the width of the three oxygen lines and find that the green line is wider than either of the two red lines. The finding of a wider line could imply a different parent for the green and red lines. However, the constancy of the green to red line flux ratio suggests the parent is the same for these lines but that the exciting photons have different energies.

  10. Process for selection of Oxygen-tolerant algal mutants that produce H.sub.2

    DOE Patents [OSTI]

    Ghirardi, Maria L. (Lakewood, CO); Seibert, Michael (Lakewood, CO)

    1999-01-01T23:59:59.000Z

    A process for selection of oxygen-tolerant, H.sub.2 -producing algal mutant cells comprising: (a) growing algal cells photoautotrophically under fluorescent light to mid log phase; (b) inducing algal cells grown photoautrophically under fluorescent light to mid log phase in step (a) anaerobically by (1) resuspending the cells in a buffer solution and making said suspension anaerobic with an inert gas; (2) incubating the suspension in the absence of light at ambient temperature; (c) treating the cells from step (b) with metronidazole, sodium azide, and added oxygen to controlled concentrations in the presence of white light. (d) washing off metronidazole and sodium azide to obtain final cell suspension; (e) plating said final cell suspension on a minimal medium and incubating in light at a temperature sufficient to enable colonies to appear; (f) counting the number of colonies to determine the percent of mutant survivors; and (g) testing survivors to identify oxygen-tolerant H.sub.2 -producing mutants.

  11. Advanced Technology and Alternative Fuel Vehicle Basics | Department...

    Energy Savers [EERE]

    Advanced Technology and Alternative Fuel Vehicle Basics Advanced Technology and Alternative Fuel Vehicle Basics August 20, 2013 - 9:00am Addthis Photo of a large blue truck with...

  12. Space Heating and Cooling Basics | Department of Energy

    Office of Environmental Management (EM)

    Homes & Buildings Space Heating and Cooling Basics Space Heating and Cooling Basics August 16, 2013 - 1:04pm Addthis A wide variety of technologies are available for heating and...

  13. adult basic education: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ranging from the design of sorting. In this survey we review basic facts regarding expander graphs that are most relevant to the theory Goldreich, Oded 312 PHD BASIC SEMINAR...

  14. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-07-01T23:59:59.000Z

    Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

  15. Radiation Safety Training Basic Radiation Safety Training for

    E-Print Network [OSTI]

    Dai, Pengcheng

    Radiation Safety Training Basic Radiation Safety Training for X-ray Users for Physics 461 & 462 Protocol Title: Basic Radiation Safety Training for X-ray Users Drafted By: Chris Millsaps, RSS Reviewers: ZB, TU, GS Purpose: To provide basic radiation safety training to the users of x-ray producing

  16. Basic Ground-Water Hydrology By RALPH C. HEATH

    E-Print Network [OSTI]

    Sohoni, Milind

    #12;Basic Ground-Water Hydrology By RALPH C. HEATH Prepared in cooperation with the North Carolina., 1983, Basic ground-water hydrology: U .S. Geological Survey Water-Supply Paper 2220, 86 p. Library of Congress Cataloging-in-Publications Data Heath, Ralph C . Basic ground-water hydrology (Geological Survey

  17. Illustration: Sean Kelly Back to basics for the

    E-Print Network [OSTI]

    Wilson, W. Stephen

    Illustration: Sean Kelly Back to basics for the "division clueless" DECEMBER 6, 2010 | BY LISA research in algebraic topology to question basic math education. At two well- regarded private schools to only 31 percent of the 2006 students. As another experiment, Wilson gave a short test of basic math

  18. Oxygen generator for medical applications (USIC)

    SciTech Connect (OSTI)

    Staiger, C. L.

    2012-03-01T23:59:59.000Z

    The overall Project objective is to develop a portable, non-cryogenic oxygen generator capable of supplying medical grade oxygen at sufficient flow rates to allow the field application of the Topical Hyperbaric Oxygen Therapy (THOT{reg_sign}) developed by Numotech, Inc. This project was sponsored by the U.S. Department of Energy Global Initiatives for Proliferation Prevention (GIPP) and is managed by collaboration between Sandia National Laboratories (SNL), Numotech, Inc, and LLC SPE 'Spektr-Conversion.' The project had two phases, with the objective of Phase I being to develop, build and test a laboratory prototype of the membrane-pressure swing adsorber (PSA) system producing at 15 L/min of oxygen with a minimum of 98% oxygen purity. Phase II objectives were to further refine and identify the pre-requisites needed for a commercial product and to determine the feasibility of producing 15 L/min of oxygen with a minimum oxygen purity of 99%. In Phase I, Spektr built up the necessary infrastructure to perform experimental work and proceeded to build and demonstrate a membrane-PSA laboratory prototype capable of producing 98% purity oxygen at a flow rate of 5 L/min. Spektr offered a plausible path to scale up the process for 15 L/min. Based on the success and experimental results obtained in Phase I, Spektr performed work in three areas for Phase II: construction of a 15 L/min PSA; investigation of compressor requirements for the front end of the membrane/PSA system; and performing modeling and simulation of assess the feasibility of producing oxygen with a purity greater than 99%. Spektr successfully completed all of the tasks under Phase II. A prototype 15 L/min PSA was constructed and operated. Spektr determined that no 'off the shelf' air compressors met all of the specifications required for the membrane-PSA, so a custom compressor will likely need to be built. Modeling and simulation concluded that production of oxygen with purities greater than 99% was possible using a Membrane-PSA system.

  19. Actual energy implementations and basic investigations

    SciTech Connect (OSTI)

    Nockemann, C.; Wuestenberg, H. [BAM, Berlin (Germany). Federal Inst. of Materials Research and Testing

    1995-12-31T23:59:59.000Z

    The actual implementations in guaranteeing the reliability of NDE systems applied in service inspections in nuclear power plants will be presented. The difference between the American PDI (Performance Demonstration Initiative) which is based on blind trials and the European ENIQ (European Network for Inspection Qualification) approach which is based on a mixed procedure of physical modeling, experience data and test experiments will be discussed. The ROC (Receiver Operating Characteristic) has been adapted from the signal detection theory to NDE problems at BAM to be used for basic investigations and for the validation of new exceptional NDE systems where modeling and reference to standards is not yet possible. Examples of application will be shown and critical discussed especially concerning the influence of the grading unit raster.

  20. Mirror Symmetry in Physics: The Basics

    E-Print Network [OSTI]

    Callum Quigley

    2014-12-28T23:59:59.000Z

    These notes are aimed at mathematicians working on topics related to mirror symmetry, but are unfamiliar with the physical origins of this subject. We explain the physical concepts that enable this surprising duality to exist, using the torus as an illustrative example. Then, we develop the basic foundations of conformal field theory so that we can explain how mirror symmetry was first discovered in that context. Along the way we will uncover a deep connection between conformal field theories with (2,2) supersymmetry and Calabi-Yau manifolds. (Based on lectures given during the "Thematic Program on Calabi-Yau Varieties: Arithmetic, Geometry and Physics" at the Fields Institute in Toronto, October 10-11, 2013.)

  1. Basic mechanisms for the new millennium

    SciTech Connect (OSTI)

    Dressendorfer, P.V.

    1998-09-01T23:59:59.000Z

    This part of the Short Course will review the basic mechanisms for radiation effects in semiconductor devices. All three areas of radiation damage will be considered -- total dose, displacement effects, and single event effects. Each of these areas will be discussed in turn. First an overview and background will be provided on the historical understanding of the damage mechanism. Then there will be a discussion of recent enhancements to the understanding of those mechanisms and an up-to-date picture provided of the current state of knowledge. Next the potential impact of each of these damage mechanisms on devices in emerging technologies and how the mechanisms may be used to understand device performance will be described, with an emphasis on those likely to be of importance in the new millennium. Finally some additional thoughts will be presented on how device scaling expected into the next century may impact radiation hardness.

  2. ACAA fly ash basics: quick reference card

    SciTech Connect (OSTI)

    NONE

    2006-07-01T23:59:59.000Z

    Fly ash is a fine powdery material created when coal is burned to generate electricity. Before escaping into the environment via the utility stacks, the ash is collected and may be stored for beneficial uses or disposed of, if necessary. The use of fly ash provides environmental benefits, such as the conservation of natural resources, the reduction of greenhouse gas emissions and eliminating the needed for ash disposal in landfills. It is also a valuable mineral resource that is used in construction and manufacturing. Fly ash is used in the production of Portland cement, concrete, mortars and stuccos, manufactured aggregates along with various agricultural applications. As mineral filler, fly ash can be used for paints, shingles, carpet backing, plastics, metal castings and other purposes. This quick reference card is intended to provide the reader basic source, identification and composition, information specifically related to fly ash.

  3. Nanostructured Basic Catalysts: Opportunities for Renewable Fuels

    SciTech Connect (OSTI)

    Conner, William C; Huber, George; Auerbach, Scott

    2009-06-30T23:59:59.000Z

    This research studied and developed novel basic catalysts for production of renewable chemicals and fuels from biomass. We focused on the development of unique porous structural-base catalysts zeolites. These catalysts were compared to conventional solid base materials for aldol condensation, that were being commercialized for production of fuels from biomass and would be pivotal in future biomass conversion to fuels and chemicals. Specifically, we had studied the aldolpyrolysis over zeolites and the trans-esterification of vegetable oil with methanol over mixed oxide catalysts. Our research has indicated that the base strength of framework nitrogen in nitrogen substituted zeolites (NH-zeolites) is nearly twice as strong as in standard zeolites. Nitrogen substituted catalysts have been synthesized from several zeolites (including FAU, MFI, BEA, and LTL) using NH3 treatment.

  4. Basics of Low-temperature Refrigeration

    E-Print Network [OSTI]

    Alekseev, A

    2014-01-01T23:59:59.000Z

    This chapter gives an overview of the principles of low temperature refrigeration and the thermodynamics behind it. Basic cryogenic processes - Joule-Thomoson process, Brayton process as well as Claude process - are described and compared. A typical helium laboratory refrigerator based on Claude process is used as a typical example of a low-temperature refrigeration system. A description of the hardware components for helium liquefaction is an important part of this paper, because the design of the main hardware components (compressors, turbines, heat exchangers, pumps, adsorbers, etc.) provides the input for cost calculation, as well as enables to estimate the reliability of the plant and the maintenance expenses. All these numbers are necessary to calculate the economics of a low temperature application.

  5. Criticality Safety Basics for INL Emergency Responders

    SciTech Connect (OSTI)

    Valerie L. Putman

    2012-08-01T23:59:59.000Z

    This document is a modular self-study guide about criticality safety principles for Idaho National Laboratory emergency responders. This guide provides basic criticality safety information for people who, in response to an emergency, might enter an area that contains much fissionable (or fissile) material. The information should help responders understand unique factors that might be important in responding to a criticality accident or in preventing a criticality accident while responding to a different emergency.

    This study guide specifically supplements web-based training for firefighters (0INL1226) and includes information for other Idaho National Laboratory first responders. However, the guide audience also includes other first responders such as radiological control personnel.

    For interested readers, this guide includes clearly marked additional information that will not be included on tests. The additional information includes historical examples (Been there. Done that.), as well as facts and more in-depth information (Did you know …).

    INL criticality safety personnel revise this guide as needed to reflect program changes, user requests, and better information. Revision 0, issued May 2007, established the basic text. Revision 1 incorporates operation, program, and training changes implemented since 2007. Revision 1 increases focus on first responders because later responders are more likely to have more assistance and guidance from facility personnel and subject matter experts. Revision 1 also completely reorganized the training to better emphasize physical concepts behind the criticality controls that help keep emergency responders safe. The changes are based on and consistent with changes made to course 0INL1226.

  6. Participation in crisis decision making

    E-Print Network [OSTI]

    Marsico, Dale Joseph

    1973-01-01T23:59:59.000Z

    PARTICIPATION IN CRISIS DECISION MAKiNG A Thesis by DALE JOSEPH MARSICO Submitted to the Graduate Col. legs of Te-. :as A&M University in partial fulfillment of the requirement~ for the degree MASTFR OF ARTS December 1973 Na)or Sub...]ect: Political Science PARTICIPATION IN CRISIS DECISION MAI'1NG A Thesis by DARE JOSEPH YARSICO Approved as to style and content by: (Chairman of Corm'. ttee M mber) PQBIQ ()~~ December 1973 487889 ABSTRACT Participation in Crisis Decision Making. (De...

  7. Software development guidelines for Visual Basic and SQL Server

    SciTech Connect (OSTI)

    IBSEN, T.G.

    2000-07-26T23:59:59.000Z

    Development Guidelines are programming directions that focus not on the logic of the program but on its physical structure and appearance. These directions make the code easier to read, understand, and maintain. These guidelines are put in place to create a consistent set of conventions to follow that will standardize the development process. With these guidelines in place the readability and understanding others have when reviewing the code is greatly enhanced. Use these guidelines as a general rule when writing any set of logical statements. Development Guidelines are put into place in an effort to standardize the structure and style of the development process. They are not intended to limit or channel the developer's own creativity and flexibility. These guidelines will cover general development syntax, organization and documentation. The general information covers the high level areas of development, no matter what the environment. This guide will detail specific Visual Basic guidelines, following the same standard naming conventions set by Microsoft, with some minor additions. The guideline will finish with conventions specific to a Database or Microsoft's SQL Server specific environment.

  8. High energy density lithium-oxygen secondary battery

    SciTech Connect (OSTI)

    Sammells, A.F.

    1989-02-07T23:59:59.000Z

    A high energy density lithium-oxygen secondary cell is described comprising a lithium-containing negative electrode; a lithium ion conducting molten salt electrolyte contacting the negative electrode; an oxygen ion conducting solid electrolyte contacting and containing the molten salt electrolyte; and an oxygen redox positive electrode contacting the oxygen ion conducting solid electrolyte.

  9. Energetic neutral atoms at Mars 4. Imaging of planetary oxygen

    E-Print Network [OSTI]

    Lukyanov, Alex

    Energetic neutral atoms at Mars 4. Imaging of planetary oxygen S. Barabash and M. Holmstro of the Martian oxygen exosphere/corona results in the production of planetary oxygen ions. The newborn ions start. The oxygen ions can then charge exchange with the neutral gases (H, H2, and O) of the Martian exosphere

  10. Oxygen Toxicity Calculations by Erik C. Baker, P.E.

    E-Print Network [OSTI]

    Read, Charles

    1 Oxygen Toxicity Calculations by Erik C. Baker, P.E. Management of exposure to oxygen toxicity myself using the good ole' FORTRAN programming language, I found that incorporating oxygen toxicity for others. Background Two oxygen toxicity parameters are typically "tracked" in technical diving

  11. Systems Biology Group Decision Making

    E-Print Network [OSTI]

    entities (e.g., molecular, cellular, organism, ecological) #12;OHIO STATE T . H . E UNIVERSITY Systems/analysis of perception, attention, choice, learning, optimality,... #12;OHIO STATE T . H . E UNIVERSITY Group decision making, evolution and ecology Current work: Modeling/analysis of coordinated motion, foraging, choice

  12. Copper-substituted perovskite compositions for solid oxide fuel cell cathodes and oxygen reduction electrodes in other electrochemical devices

    DOE Patents [OSTI]

    Rieke, Peter C. (Pasco, WA); Coffey, Gregory W. (Richland, WA); Pederson, Larry R. (Kennewick, WA); Marina, Olga A. (Richland, WA); Hardy, John S. (Richland, WA); Singh, Prabhaker (Richland, WA); Thomsen, Edwin C. (Richland, WA)

    2010-07-20T23:59:59.000Z

    The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells. Also provided are electrochemical devices that include active oxygen reduction electrodes, such as solid oxide fuel cells, sensors, pumps and the like. The compositions comprises a copper-substituted ferrite perovskite material. The invention also provides novel methods for making and using the electrode compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having cathodes comprising the compositions.

  13. The oxygen that gives us the breath of life is renewed by sunlight falling on plants, algae

    E-Print Network [OSTI]

    Allen, John F.

    and NADPH drive the `dark reactions' that transfer the electrons to CO2 so as to provide the energy to make and geochemistry. So when and how did cells first learn to split water to make oxygen gas? ­1.4 ­1.2 ­0.8 ­0.4 0 in photosynthesis. Photosystems I and II absorb light energy, convert it into electrochemical potential

  14. Oxygen-Reducing Biocathodes Operating with Passive Oxygen Transfer in Microbial Fuel Cells

    E-Print Network [OSTI]

    Oxygen-Reducing Biocathodes Operating with Passive Oxygen Transfer in Microbial Fuel Cells Xue Xia, Justin C. Tokash, Fang Zhang, Peng Liang, Xia Huang,*, and Bruce E. Logan*,, State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, P

  15. On the solar nickel and oxygen abundances

    E-Print Network [OSTI]

    Pat Scott; Martin Asplund; Nicolas Grevesse; A. Jacques Sauval

    2009-01-27T23:59:59.000Z

    Determinations of the solar oxygen content relying on the neutral forbidden transition at 630 nm depend upon the nickel abundance, due to a Ni I blend. Here we rederive the solar nickel abundance, using the same ab initio 3D hydrodynamic model of the solar photosphere employed in the recent revision of the abundances of C, N, O and other elements. Using 17 weak, unblended lines of Ni I together with the most accurate atomic and observational data available we find log epsilon_Ni = 6.17 +/- 0.02 (statistical) +/- 0.05 (systematic), a downwards shift of 0.06 to 0.08 dex relative to previous 1D-based abundances. We investigate the implications of the new nickel abundance for studies of the solar oxygen abundance based on the [O I] 630 nm line in the quiet Sun. Furthermore, we demonstrate that the oxygen abundance implied by the recent sunspot spectropolarimetric study of Centeno & Socas-Navarro needs to be revised downwards from log epsilon_O = 8.86 +/- 0.07 to 8.71 +/- 0.10. This revision is based on the new nickel abundance, application of the best available gf-value for the 630 nm forbidden oxygen line, and a more transparent treatment of CO formation. Determinations of the solar oxygen content relying on forbidden lines now appear to converge around log epsilon_O = 8.7.

  16. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-04-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the twelfth quarter, January-March 2003, in the following task areas: Task 1--Oxygen Enhanced Combustion, Task 2--Oxygen Transport Membranes, Task 3--Economic Evaluation and Task 4--Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah explored both the effectiveness of oxygen addition and the best way to add oxygen with a scaled version of Riley Power's newest low NOx burner design. CFD modeling was done to compare the REI's modeling results for James River Unit 3 with the NOx and LOI results obtained during the demonstration program at that facility. Investigation of an alternative method of fabrication of PSO1d elements was conducted. OTM process development work has concluded with the completion of a long-term test of a PSO1d element Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. Commercial proposals have been submitted. Economic analysis of a beta site test performance was conducted.

  17. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2003-02-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the eleventh quarter, October-December 2002, in the following task areas: Task 1 - Oxygen Enhanced Combustion, Task 2 - Oxygen Transport Membranes, Task 3 - Economic Evaluation and Task 4 - Program Management. The program is proceeding in accordance with the objectives for the third year. Pilot scale experiments conducted at the University of Utah were aimed at confirming the importance of oxygen injection strategy for different types of burners. CFD modeling at REI was used to better understand the potential for increased corrosion under oxygen enhanced combustion conditions. Data from a full-scale demonstration test in Springfield, MO were analyzed. OTM element development continued with preliminary investigation of an alternative method of fabrication of PSO1d elements. OTM process development continued with long-term testing of a PSO1d element. Economic evaluation has confirmed the advantage of oxygen-enhanced combustion. Proposals have been submitted for two additional beta test sites. A first commercial proposal has been submitted. Economic analysis of a beta site test performance was conducted.

  18. Oxygen abundance of open cluster dwarfs

    E-Print Network [OSTI]

    Z. -X. Shen; X. -W. Liu; H. -W. Zhang; B. Jones; D. N. C. Lin

    2007-03-30T23:59:59.000Z

    We present oxygen abundances of dwarfs in the young open cluster IC 4665 deduced from the OI $\\lambda$7774 triplet lines and of dwarfs in the open cluster Pleiades derived from the [OI] $\\lambda$6300 forbidden line. Stellar parameters and oxygen abundances were derived using the spectroscopic synthesis tool SME (Spectroscopy Made Easy). We find a dramatic increase in the upper boundary of the OI triplet abundances with decreasing temperature in the dwarfs of IC 4665, consistent with the trend found by Schuler et al. in the open clusters Pleiades and M 34, and to a less extent in the cool dwarfs of Hyades (Schuler et al. 2006a) and UMa (King & Schuler 2005). By contrast, oxygen abundances derived from the [OI] $\\lambda$6300 forbidden line for stars in Pleiades and Hyades (Schuler et al. 2006b) are constant within the errors. Possible mechanisms that may lead a varying oxygen triplet line abundance are examined, including systematic errors in the stellar parameter determinations, the NLTE effects, surface activities and granulation. The age-related effects stellar surface activities (especially the chromospheric activities) are suggested by our analysis to blame for the large spreads of oxygen triplet line abundances.

  19. Oxygen: From Environment to Genes. The periodic occurrence of oxygen minima can powerfully influence organisms living in near

    E-Print Network [OSTI]

    Oxygen: From Environment to Genes. The periodic occurrence of oxygen minima can powerfully to the winter of 2014. Their scholarly work is presented in this collection. #12;1 Oxygen: From Environment", 2013, 2014 Table of contents Page 2. Laura Lilly - Low-oxygen formation along the California current. 6

  20. The oxygen abundance deficiency in irregular galaxies

    E-Print Network [OSTI]

    L. S. Pilyugin; F. Ferrini

    2000-01-05T23:59:59.000Z

    The observed oxygen abundances in a number of irregular galaxies have been compared with predictions of the closed-box model of chemical and photometric evolution of galaxies. Oxygen is found to be deficient with respect to the predicted abundances. This is an indicator in favor of loss of heavy elements via galactic winds or/and of infall of low--abundance gas onto the galaxy. The oxygen abundance deficiency observed within the optical edge of a galaxy cannot be explained by mixing with the gas envelope observed outside the optical limit. We confirm the widespread idea that a significant part of the heavy elements is ejected by irregular galaxies in the intergalactic medium.

  1. Photochemical Escape of Oxygen from Early Mars

    E-Print Network [OSTI]

    Zhao, Jinjin

    2015-01-01T23:59:59.000Z

    Photochemical escape is an important process for oxygen escape from present Mars. In this work, a 1-D Monte-Carlo Model is developed to calculate escape rates of energetic oxygen atoms produced from O2+ dissociative recombination reactions (DR) under 1, 3, 10, and 20 times present solar XUV fluxes. We found that although the overall DR rates increase with solar XUV flux almost linearly, oxygen escape rate increases from 1 to 10 times present solar XUV conditions but decreases when increasing solar XUV flux further. Analysis shows that atomic species in the upper thermosphere of early Mars increases more rapidly than O2+ when increasing XUV fluxes. While the latter is the source of energetic O atoms, the former increases the collision probability and thus decreases the escape probability of energetic O. Our results suggest that photochemical escape be a less important escape mechanism than previously thought for the loss of water and/or CO2 from early Mars.

  2. Contributions to risk-informed decision making

    E-Print Network [OSTI]

    Elliott, Michael A. (Michael Alfred)

    2010-01-01T23:59:59.000Z

    Risk-informed decision-making (RIDM) is a formal process that assists stakeholders make decisions in the face of uncertainty. At MIT, a tool known as the Analytic Deliberative Decision Making Process (ADP) has been under ...

  3. MS makes the clinical grade | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PRISM using mass spectrometers, shown here, to identify biomarkers associated with cancer and other diseases. PRISM could speed drug discovery and basic biology research....

  4. Oxygen isotope exchange between water and semiquinones

    SciTech Connect (OSTI)

    Stevenson, G.R.; Wang, Z.Y.; Reiter, R.C.; Peters, S.J.

    1988-09-14T23:59:59.000Z

    A reaction is described that can be utilized to produce /sup 17/O-labeled anion radicals that yield strong well resolved ESR signals exhibiting splitting from the /sup 17/O nucleus. The oxygen anthraquinone has been studied, and the results are reported herein. 7 references, 1 figure.

  5. Oxygen Enriched Combustion System Performance Study 

    E-Print Network [OSTI]

    Chen, S. L.; Kwan, Y.; Abele, A. R.; Silver, L. S.; Kobayashi, H.

    1987-01-01T23:59:59.000Z

    , and then to verify the performance of selected systems in research furnaces. Tests of several commercial burner designs have been conducted at scales of 1 x 10^6 Btu/hr and 10 x 10^6 Btu/hr. The burners represent both conventional air fired designs and oxygen...

  6. Oxygen addition to sulfur of metal thiolates

    E-Print Network [OSTI]

    Soma, Takako

    1996-01-01T23:59:59.000Z

    , and characterized. Molecular oxygen or hydrogen peroxide reacted with (N,N'-bis(mercaptoethyl)-1,5-diazacyclooctane-nickel(II), (BME-DACO)2Ni3 +2, to produce a trimetallic, (N,N'-bismercaptoethyl-1,5-diazacyclooctane-nickel(II))-nickelate, (BME-DACO)2Ni3 2...

  7. Basic Research Needs for Electrical Energy Storage: Report of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    their extraordinarily high discharge rate properties and cyclability, we need an infusion of basic science to provide the vital background for the materials and mechanisms...

  8. EES and Batteries: The Basics | University of Texas Energy Frontier...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EES AND BATTERIES: THE BASICS Virtually all portable electronic devices, including cell phones, PDAs and laptop computers, rely on chemical energy stored in batteries. Batteries...

  9. Grand Challenge for Basic and Applied Research in Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage Grand Challenge for Basic and Applied Research in Hydrogen Storage Presentation from the Hydrogen Storage Pre-Solicitation Meeting held June 19, 2003 in Washington, DC....

  10. Grand Challenge for Basic and Applied Research in Hydrogen Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storage: Statement of Objectives Grand Challenge for Basic and Applied Research in Hydrogen Storage: Statement of Objectives Statement of objectives for the Grand Challenge for...

  11. Chapter 5. Basic Concepts for Clean Energy Unsecured Lending...

    Broader source: Energy.gov (indexed) [DOE]

    DRAFT U.S. DOE CLEAN ENERGY FINANCE GUIDE, THIRD EDITION DECEMBER 9, 2010 Chapter 5. Basic Concepts for Clean Energy Unsecured...

  12. A Basic Overview of Occupational Radiation Exposure Monitoring...

    Office of Environmental Management (EM)

    Analysis & Reporting A Basic Overview of Occupational Radiation Exposure Monitoring, Analysis & Reporting September 2012 This pamphlet is intended to provide a short summary...

  13. atmospheric aerosols basic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of atmospheric aerosol. Aplin, KL 2012-01-01 13 1. Introduction The atmospheric greenhouse effect is the basic mechanism Environmental Sciences and Ecology Websites Summary: 1....

  14. Oxygen-producing inert anodes for SOM process

    DOE Patents [OSTI]

    Pal, Uday B

    2014-02-25T23:59:59.000Z

    An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

  15. Simulation of human decision making

    DOE Patents [OSTI]

    Forsythe, J. Chris (Sandia Park, NM); Speed, Ann E. (Albuquerque, NM); Jordan, Sabina E. (Albuquerque, NM); Xavier, Patrick G. (Albuquerque, NM)

    2008-05-06T23:59:59.000Z

    A method for computer emulation of human decision making defines a plurality of concepts related to a domain and a plurality of situations related to the domain, where each situation is a combination of at least two of the concepts. Each concept and situation is represented in the computer as an oscillator output, and each situation and concept oscillator output is distinguishable from all other oscillator outputs. Information is input to the computer representative of detected concepts, and the computer compares the detected concepts with the stored situations to determine if a situation has occurred.

  16. Method of making permanent magnets

    DOE Patents [OSTI]

    McCallum, R.W.; Dennis, K.W.; Lograsso, B.K.; Anderson, I.E.

    1993-09-07T23:59:59.000Z

    A method for making an isotropic permanent magnet comprises atomizing a melt of a rare earth-transition metal alloy (e.g., an Nd--Fe--B alloy enriched in Nd and B) under conditions to produce protectively coated, rapidly solidified, generally spherical alloy particles. Wherein a majority of the particles are produced/size classified within a given size fraction (e.g., 5 to 40 microns diameter) exhibiting optimum as-atomized magnetic properties and subjecting the particles to concurrent elevated temperature and elevated isotropic pressure for a time effective to yield a densified, magnetically isotropic magnet compact having enhanced magnetic properties and mechanical properties. 13 figures.

  17. Method of making diode structures

    DOE Patents [OSTI]

    Compaan, Alvin D.; Gupta, Akhlesh

    2006-11-28T23:59:59.000Z

    A method of making a diode structure includes the step of depositing a transparent electrode layer of any one or more of the group ZnO, ZnS and CdO onto a substrate layer, and depositing an active semiconductor junction having an n-type layer and a p-type layer onto the transparent electrode layer under process conditions that avoid substantial degradation of the electrode layer. A back electrode coating layer is applied to form a diode structure.

  18. Making predictions in the multiverse

    E-Print Network [OSTI]

    Ben Freivogel

    2011-09-18T23:59:59.000Z

    I describe reasons to think we are living in an eternally inflating multiverse where the observable "constants" of nature vary from place to place. The major obstacle to making predictions in this context is that we must regulate the infinities of eternal inflation. I review a number of proposed regulators, or measures. Recent work has ruled out a number of measures by showing that they conflict with observation, and focused attention on a few proposals. Further, several different measures have been shown to be equivalent. I describe some of the many nontrivial tests these measures will face as we learn more from theory, experiment, and observation.

  19. Introduction to 'Make' NERSC Tutorial

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes | National NuclearInterlibraryDocumentationTechnical'Make'

  20. ARM - Lesson Plans: Making Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDC documentationBarrow, Alaska OutreachMaking Clouds Outreach Home

  1. Making, Measuring, and Modeling Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |IsLove Your Home and It'll LoveMail andAbout Us /ofMaking,

  2. Self-assembled monolayer and method of making

    DOE Patents [OSTI]

    Fryxell, Glen E [Kennewick, WA; Zemanian, Thomas S [Richland, WA; Liu, Jun [West Richland, WA; Shin, Yongsoon [Richland, WA

    2003-03-11T23:59:59.000Z

    According to the present invention, the previously known functional material having a self-assembled monolayer on a substrate has a plurality of assembly molecules each with an assembly atom with a plurality of bonding sites (four sites when silicon is the assembly molecule) wherein a bonding fraction (or fraction) of fully bonded assembly atoms (the plurality of bonding sites bonded to an oxygen atom) has a maximum when made by liquid solution deposition, for example a maximum of 40% when silicon is the assembly molecule, and maximum surface density of assembly molecules was 5 silanes per square nanometer. Note that bonding fraction and surface population are independent parameters. The method of the present invention is an improvement to the known method for making a siloxane layer on a substrate, wherein instead of a liquid phase solution chemistry, the improvement is a supercritical phase chemistry. The present invention has the advantages of greater fraction of oxygen bonds, greater surface density of assembly molecules and reduced time for reaction of about 5 minutes to about 24 hours.

  3. Self-Assembled Monolayer And Method Of Making

    DOE Patents [OSTI]

    Fryxell, Glen E. (Kennewick, WA); Zemanian, Thomas S. (Richland, WA); Liu, Jun (West Richland, WA); Shin, Yongsoon (Richland, WA)

    2005-01-25T23:59:59.000Z

    According to the present invention, the previously known functional material having a self-assembled monolayer on a substrate has a plurality of assembly molecules each with an assembly atom with a plurality of bonding sites (four sites when silicon is the assembly molecule) wherein a bonding fraction (or fraction) of fully bonded assembly atoms (the plurality of bonding sites bonded to an oxygen atom) has a maximum when made by liquid solution deposition, for example a maximum of 40% when silicon is the assembly molecule, and maximum surface density of assembly molecules was 5 silanes per square nanometer. Note that bonding fraction and surface population are independent parameters. The method of the present invention is an improvement to the known method for making a siloxane layer on a substrate, wherein instead of a liquid phase solution chemistry, the improvement is a supercritical phase chemistry. The present invention has the advantages of greater fraction of oxygen bonds, greater surface density of assembly molecules and reduced time for reaction of about 5 minutes to about 24 hours.

  4. Self-Assembled Monolayer And Method Of Making

    DOE Patents [OSTI]

    Fryxell, Glen E. (Kennewick, WA); Zemanian, Thomas S. (Richland, WA); Liu, Jun (West Richland, WA); Shin, Yongsoon (Richland, WA)

    2004-06-22T23:59:59.000Z

    According to the present invention, the previously known functional material having a self-assembled monolayer on a substrate has a plurality of assembly molecules each with an assembly atom with a plurality of bonding sites (four sites when silicon is the assembly molecule) wherein a bonding fraction (or fraction) of fully bonded assembly atoms (the plurality of bonding sites bonded to an oxygen atom) has a maximum when made by liquid solution deposition, for example a maximum of 40% when silicon is the assembly molecule, and maximum surface density of assembly molecules was 5 silanes per square nanometer. Note that bonding fraction and surface population are independent parameters. The method of the present invention is an improvement to the known method for making a siloxane layer on a substrate, wherein instead of a liquid phase solution chemistry, the improvement is a supercritical phase chemistry. The present invention has the advantages of greater fraction of oxygen bonds, greater surface density of assembly molecules and reduced time for reaction of about 5 minutes to about 24 hours.

  5. Self-assembled monolayer and method of making

    DOE Patents [OSTI]

    Fryxell, Glen E.; Zemanian, Thomas S.; Liu, Jun; Shin, Yongsoon

    2004-05-11T23:59:59.000Z

    According to the present invention, the previously known functional material having a self-assembled monolayer on a substrate has a plurality of assembly molecules each with an assembly atom with a plurality of bonding sites (four sites when silicon is the assembly molecule) wherein a bonding fraction (or fraction) of fully bonded assembly atoms (the plurality of bonding sites bonded to an oxygen atom) has a maximum when made by liquid solution deposition, for example a maximum of 40% when silicon is the assembly molecule, and maximum surface density of assembly molecules was 5 silanes per square nanometer. Note that bonding fraction and surface population are independent parameters. The method of the present invention is an improvement to the known method for making a siloxane layer on a substrate, wherein instead of a liquid phase solution chemistry, the improvement is a supercritical phase chemistry. The present invention has the advantages of greater fraction of oxygen bonds, greater surface density of assembly molecules and reduced time for reaction of about 5 minutes to about 24 hours.

  6. Glass-ceramic material and method of making

    DOE Patents [OSTI]

    Meinhardt, Kerry D [Richland, WA; Vienna, John D [West Richland, WA; Armstrong, Timothy R [Pasco, WA; Pederson, Larry R [Kennewick, WA

    2002-08-13T23:59:59.000Z

    The present invention is a glass-ceramic material and method of making useful for joining at least two solid ceramic parts. The seal is a blend of M.sub.A O--M.sub.B O.sub.y --SiO.sub.2 that substantially matches a coefficient of thermal expansion of the solid electrolyte. According to the present invention, a series of glass ceramics in the M.sub.A O--M.sub.B O.sub.y --SiO.sub.2 system can be used to join or seal both tubular and planar ceramic solid oxide fuel cells, oxygen electrolyzers, and membrane reactors for the production of syngas, commodity chemicals and other products.

  7. The Economics of Oxygen Enriched Air Production Via Membranes

    E-Print Network [OSTI]

    Gollan, A.; Kleper, M. H.

    1984-01-01T23:59:59.000Z

    Oxygen enriched air combustion is a recognized approach to energy conservation. Conventional methods of producing oxygen enriched air: Pressure Swing Adsorption and Cryogenics, are energy-intensive and expensive. In this paper the economics of using...

  8. Methane Adsorption and Dissociation and Oxygen Adsorption and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methane Adsorption and Dissociation and Oxygen Adsorption and Reaction with CO on Pd Nanoparticles on MgO(100) and on Pd(111). Methane Adsorption and Dissociation and Oxygen...

  9. On the reduction of oxygen from dispersed media

    E-Print Network [OSTI]

    Roushdy, Omar H., 1977-

    2007-01-01T23:59:59.000Z

    The reduction of oxygen from an organic phase dispersed in a concentrated electrolyte is investigated. Dispersed organic phases are used to enhance oxygen transport in fermenters and artificial blood substitutes. This work ...

  10. atomic oxygen reactions: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is caused Zare, Richard N. 179 Interactions of Oxygen and Hydrogen on Pd(111) surface Plasma Physics and Fusion Websites Summary: for the oxygen (2?2) structure. The...

  11. Design, measurement, and analysis of oxygenated fluid pump system

    E-Print Network [OSTI]

    Mason, Alexander M., IV (Alexander Martin)

    2012-01-01T23:59:59.000Z

    The author sought out the opportunity to design and implement a system for pumping oxygenated fluid and mixing it with saline, for the purpose of providing sufficient levels of oxygen for patients undergoing forms of ...

  12. Label-free oxygen-metabolic photoacoustic microscopy in vivo

    E-Print Network [OSTI]

    Wang, Lihong

    tomography (PET) using radioactively labeled oxy- gen. Many other pathological and physiological functions of oxygen consumption instead of the static oxygen concentration.11 If the region of interest has well

  13. In vivo blood oxygenation level measurements using photoacoustic microscopy

    E-Print Network [OSTI]

    Sivaramakrishnan, Mathangi

    2007-09-17T23:59:59.000Z

    in absorption spectra of oxygenated (HbO 2 ) and deoxygenated hemoglobin (Hb) is exploited to yield oxygenation level information. This method consists of using Light Emitting Diodes (LEDs) as light sources to deliver light of known intensity and wavelength...

  14. Inhibitive Influence of Oxygen Vacancies for Photoactivity on...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Inhibitive Influence of Oxygen Vacancies for Photoactivity on TiO2(110). Abstract: Scanning tunneling...

  15. Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale Sn0.99Co0.01O. Dopant Distribution, Oxygen Stoichiometry and Magnetism of Nanoscale Sn0.99Co0.01O. Abstract: In...

  16. OXYGEN TRANSFER IN TRICKLING FILTERS By BruceE. Logan~

    E-Print Network [OSTI]

    OXYGEN TRANSFER IN TRICKLING FILTERS By BruceE. Logan~ ABSTRACT: Insufficientoxygen transfer can result in anaerobic biofilmsand odor generation during biochemicaloxygen demand (BOD) removal plastic media trickling filters occurs by diffusion of oxygen through thin fluid films, previous models

  17. Reaction Pathways for Oxygen Evolution Promoted by Cobalt Giuseppe Mattioli,*,

    E-Print Network [OSTI]

    Guidoni, Leonardo

    ABSTRACT: The in-depth understanding of the molecular mechanisms regulating the water oxidation catalysis heterogeneous and homogeneous TM-based oxygen evolving catalysts,5 containing different metal-oxygen cores (Mn,6

  18. Optimization of Oxygen Purity for Coal Conversion Energy Reduction

    E-Print Network [OSTI]

    Baker, C. R.; Pike, R. A.

    1982-01-01T23:59:59.000Z

    The conversion of coal into gaseous and liquid fuels and chemical feedstock will require large quantities of oxygen. This oxygen will be produced in large multi-train air separation plants which will consume about 350 kilowatt hours of energy...

  19. Radiation Safety Training Basic Radiation Safety Training for

    E-Print Network [OSTI]

    Dai, Pengcheng

    Radiation Safety Training Basic Radiation Safety Training for Sealed Source Users for Physics 461 Protocol Title: Training for Sealed Source Users Drafted By: Chris Millsaps, RSS Reviewers: ZB, TU, GS Purpose: To provide basic radiation safety training to the users of sealed sources located

  20. PROCESSING TIP . . . BACK TO BASICS: REVISITING BLOOD COLLECTION

    E-Print Network [OSTI]

    Navara, Kristen

    MAY 2009 PROCESSING TIP . . . BACK TO BASICS: REVISITING BLOOD COLLECTION Technological advances it is often a good idea to periodically step back from the small details and revisit the basics. One that approximately 50% of the blood in the carcass will drain out. This represents about 3-4% of total body weight

  1. REVIEW OF THE LITERATURE ON BASIC EDUCATION IN NIGERIA

    E-Print Network [OSTI]

    Sussex, University of

    June 2014 REVIEW OF THE LITERATURE ON BASIC EDUCATION IN NIGERIA Issues of access, quality, equity and impact Sara Humphreys with Lee Crawfurd #12;Review of the literature on basic education in Nigeria EDOREN ­ Education Data, Research and Evaluation in Nigeria i Acknowledgements Thanks are due to many individuals who

  2. Ecology-basics and applications Planned activities 2013

    E-Print Network [OSTI]

    Ecology- basics and applications Planned activities 2013 Last update 2013-04-23 Anna-Sara Liman Activities Approximate dates Contact persons Advances in Basic Ecology Nov ­February 2013 Pär Forslund of Ecological Ideas January 2013 Jan.Bengtsson@slu.se Statistical programming in R 22-26th April 2013 Matt

  3. Accident/Injury Reporting, Investigation, & Basic First Aid Plan

    E-Print Network [OSTI]

    Long, Nicholas

    Accident/Injury Reporting, Investigation, & Basic First Aid Plan Environmental Health, Safety of accidents/injuries at Stephen F. Austin State University (SFASU) and provides basic first aid practices. It is designed to help reduce injuries by reducing unsafe or hazardous conditions and discouraging accident

  4. Process to make structured particles

    DOE Patents [OSTI]

    Knapp, Angela Michelle; Richard, Monique N; Luhrs, Claudia; Blada, Timothy; Phillips, Jonathan

    2014-02-04T23:59:59.000Z

    Disclosed is a process for making a composite material that contains structured particles. The process includes providing a first precursor in the form of a dry precursor powder, a precursor liquid, a precursor vapor of a liquid and/or a precursor gas. The process also includes providing a plasma that has a high field zone and passing the first precursor through the high field zone of the plasma. As the first precursor passes through the high field zone of the plasma, at least part of the first precursor is decomposed. An aerosol having a second precursor is provided downstream of the high field zone of the plasma and the decomposed first material is allowed to condense onto the second precursor to from structured particles.

  5. Oxygen isotope fractionation in the vacuum ultraviolet photodissociation of carbon monoxide: Wavelength, pressure and temperature dependency.

    E-Print Network [OSTI]

    Chakraborty, Subrata

    2013-01-01T23:59:59.000Z

    Oxygen isotope fractionation in the vacuum ultravioletmeasurement of the associated oxygen isotopic composition ofwavelength dependency of the oxygen isotopic composition in

  6. OXYGEN REDUCTION WITH CARBON SUPPORTED METALLIC CLUSTER CATALYSTS IN ALKALINE ELECTROLYTE

    E-Print Network [OSTI]

    Ross Jr., Philip N.

    2013-01-01T23:59:59.000Z

    be published in the Proceedings OXYGEN REDUCTION WITH CARBONof California. LBL-11891 Oxygen Reduction with Carbonof Pt interacts with both oxygen and water more strongly

  7. Oxygen-driven relaxation processes in pre-irradiated Ar cryocrystals

    E-Print Network [OSTI]

    Savchenko, E. V; Belov, A. G; Gumenchuk, G. B; Ponomaryov, A. N; Bondybey, V. E

    2006-01-01T23:59:59.000Z

    Excitations of Solid Oxygen ?in Russian?, B. I. Verkin andNUMBER 11 NOVEMBER 2006 Oxygen-driven relaxation processes? Relaxation processes in oxygen-containing Ar cryocrystals

  8. Green fluorescent protein based indicators of dynamic redox changes and reactive oxygen species

    E-Print Network [OSTI]

    Dooley, Colette

    2006-01-01T23:59:59.000Z

    attached a singlet oxygen generator to the C-terminal ofencoded singlet oxygen generators, which is currentlyassays. A. Singlet oxygen generator and sensor are tethered;

  9. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, Roland R. (Lansdale, PA); Bond, James A. (Exton, PA)

    1994-01-01T23:59:59.000Z

    A high-voltage electrical insulator (21) for electrically insulating a thermoelectric module (17) in a spacecraft from a niobium-1% zirconium alloy wall (11) of a heat exchanger (13) filled with liquid lithium (16) while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator (21) has a single crystal alumina layer (SxAl.sub.2 O.sub.3, sapphire) with a niobium foil layer (32) bonded thereto on the surface of the alumina crystal (26) facing the heat exchanger wall (11), and a molybdenum layer (31) bonded to the niobium layer (32) to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface.

  10. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-10-01T23:59:59.000Z

    This quarterly technical progress report will summarize work accomplished for the Program through the second quarter July--September 2000 in the following task areas: Task 1-Oxygen Enhanced Combustion, Task 2-Oxygen Transport Membranes and Task 4-Program Management. The program is proceeding in accordance with the objectives for the first year. OTM tube characterization is well underway, the design and assembly of the high pressure permeation test facility is complete and the facility will be in full operation during the next quarter. Combustion testing has been initiated at both the University of Arizona and Praxair. Testing at the University of Arizona has experienced some delays; steps have been take to get the test work back on schedule. Completion of the first phase of the testing is expected in next quarter. Combustion modeling has been started at both REI and Praxair, preliminary results are expected in the next quarter.

  11. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, R.R.; Bond, J.A.

    1994-03-29T23:59:59.000Z

    A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

  12. IMPROVEMENTS IN MODELLING DISSOLVED OXYGEN IN ACTIVATED SLUDGE SYSTEMS

    E-Print Network [OSTI]

    Wells, Scott A.

    1 IMPROVEMENTS IN MODELLING DISSOLVED OXYGEN IN ACTIVATED SLUDGE SYSTEMS Jacek Makinia*, Scott A in a full-scale activated sludge reactor. The Activated Sludge Model No. 1 was used to describe for dissolved oxygen. KEYWORDS Activated sludge; dispersion; dissolved oxygen dynamics; mass transfer

  13. Instructions for use Removal of Oxygen and Nitrogen from Niobium

    E-Print Network [OSTI]

    Tachizawa, Kazuya

    Instructions for use #12;------ Removal of Oxygen and Nitrogen from Niobium by External Gettering External Gettering, Purification of Niobium, Thermodynamics of Impurities, Oxygen Diffusion, Purity niobium even below 1500K. The oxygen concentration in the deposit and the Nb bulk is evaluated

  14. Oceanic oxygen changes as a bellwether of climate change

    E-Print Network [OSTI]

    Fischlin, Andreas

    Oceanic oxygen changes as a bellwether of climate change Term paper in Biogeochemistry@ethz.ch] Tutor: Prof. Dr. Nicholas Gruber [nicholas.gruber@env.ethz.ch] Abstract The response of oceanic oxygen of climate change. Recent publications indicate that the oceanic oxygen outgassing is substaintially larger

  15. THE OXYGEN REQUIREMENTS OF SHELLFISH By Philip H. Mitchell

    E-Print Network [OSTI]

    THE OXYGEN REQUIREMENTS OF SHELLFISH ~ By Philip H. Mitchell 2°7 #12;Blank page retained for pagination #12;THE OXYGEN REQUIREMENTS OF SHELLFISH. By PHILIP H. MITCHELL. J1, The respiratory exchanges to temperature changes, a smaller utili- zation of oxygen in proportion to the body weight with increase in size

  16. Oxygen Reduction DOI: 10.1002/anie.201403264

    E-Print Network [OSTI]

    Goddard III, William A.

    Oxygen Reduction DOI: 10.1002/anie.201403264 Dramatic Increase in the Oxygen Reduction Reaction solvation) is used to predict how the energies and barriers for the mechanistic steps of the oxygen. In these electro- chemical devices, H2 (generated e.g. from solar energy conversion) reacts with O2 to produce

  17. Oxygen stabilized zirconium vanadium intermetallic compound

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

    1982-01-01T23:59:59.000Z

    An oxygen stabilized intermetallic compound having the formula Zr.sub.x OV.sub.y where x=0.7 to 2.0 and y=0.18 to 0.33. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 450.degree. C. at pressures down to 10.sup.-6 Torr. The compound is also capable of selectively sorbing hydrogen from gaseous mixtures in the presence of CO and CO.sub.2.

  18. The oxygen abundance distribution in M101

    E-Print Network [OSTI]

    L. S. Pilyugin

    2001-05-07T23:59:59.000Z

    The well-observed spiral galaxy M101 was considered. The radial distributions of oxygen abundances determined in three different ways (with the classic Te - method, with the R23 - method, and with the P -- method) were compared. It was found that the parameters (the central oxygen abundance and the gradient) of the radial O/H(P) abundance distribution are close to those of the O/H(Te) abundance distribution. The parameters of the O/H(R23) abundance distribution differ significantly from those of the O/H(Te) abundance distribution: the central O/H(R23) oxygen abundance is higher by around 0.4dex and the gradient is steeper by a factor of around 1.5 as compared to those values in the O/H(Te) abundance distribution. The dispersion in O/H(P) abundance at fixed radius is rather small, around 0.08 dex, and is equal to that in O/H(Te) abundance. The dispersion in O/H(R23) abundance at fixed radius is appreciably larger, around 0.16 dex, compared to that in O/H(Te) abundance. It has been shown that the extra dispersion in O/H(R23) abundances is an artifact and reflects scatter in excitation parameter P at fixed radius.

  19. DME-to-oxygenates process studies

    SciTech Connect (OSTI)

    Tartamella, T.L.; Sardesai, A.; Lee, S. [Univ. of Akron, OH (United States); Kulik, C.J. [Electric Power Research Inst., Palo Alto, CA (United States)

    1994-12-31T23:59:59.000Z

    The feasibility of the production of hydrocarbons from dimethyl ether (DNM) has been illustrated in a fixed bed micro-reactor as well as a bench scale fluidized bed reactor by the University of Akron/EPRI DME-to-Hydrocarbon (DTG) Process. The DTG process has distinct advantages over its methanol based counterpart. Specifically, the DTG process excels in the area of higher productivity, higher per-pass conversion, and lower heat duties than the MTG process. Also of special importance is the production of oxygenates -- including MTBE, ETBE, and TAME. DME may be reacted with isobutylene to produce a mixture of MTBE and ETBE. The properties of ETBE excel over MTBE in the areas of lower RVP and higher RON. According to industrial reports, MTBE is the fastest growing chemical (1992 US capacity 135,350 BPD, with expected growth of 34%/year to 1997). Also, recent renewed interest as an octane-enhancer and as a source of oxygen has spurred a growing interest in nonrefinery synthesis routes to ETBE. TAME, with its lower RVP and higher RON has proven useful as a gasoline blending agent and octane enhancer and may also be produced directly from DME. DME, therefore, serves as a valuable feedstock in the conversion of may oxygenates with wide-scale industrial importance. It should be also noted that the interest in the utilization of DME as process feedstock is based on the favorable process economics of EPRI/UA`s liquid phase DME process.

  20. Magnetic interaction in oxygenated alpha Fe-phthalocyanines

    SciTech Connect (OSTI)

    Kuzmann, Ern?, E-mail: kuzmann@caesar.elte.hu; Homonnay, Zoltán; Horváth, Attila [Institute of Chemistry, Eötvös Loránd University, P.O. Box 32, 1512 Budapest (Hungary); Pechousek, Jiri; Cuda, Jan; Machala, Libor; Zoppellaro, Giorgio; Zboril, Radek [Regional Centre of Advanced Technologies and Materials, Departments of Experimental Physics and Physical Chemistry, Faculty of Science Palacky University, 17. Listopadu 1192/12, 771 46 Olomouc (Czech Republic); Yin, Houping; Wei, Yen [Department of Chemistry, Drexel University, Philadelphia, PA 19104 (United States); Klencsár, Zoltán [Research Centre for Natural Sciences, Hungarian Academy of Sciences, Budapest, 1117 (Hungary); Kubuki, Shiro [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Metropolitan University, 1-1 Minami-Osawa, Hachi-Oji, Tokyo 192-0397 (Japan); Nath, Amar [Department of Chemistry, University of North Carolina, Asheville, NC 28804 (United States)

    2014-10-27T23:59:59.000Z

    Alpha iron phthalocyanines (?-FePc) oxygenated at low temperatures were investigated with the help of {sup 57}Fe Mössbauer spectroscopy, magnetization measurements (SQUID) and X-ray diffractometry (XRD). Mössbauer spectroscopy revealed that upon oxygenation of ?-FePc, new species were formed which could be associated with Fe{sup III}Pc oxygen adducts. Unexpectedly, magnetically split spectrum of oxygenated ?-FePc was observed below 20 K. In-field Mössbauer spectra in a 5 T external magnetic field at 5K and magnetization measurements indicate antiferromagnetic coupling in oxygenated ?-FePc.

  1. Making almost commuting matrices commute

    SciTech Connect (OSTI)

    Hastings, Matthew B [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    Suppose two Hermitian matrices A, B almost commute ({parallel}[A,B]{parallel} {<=} {delta}). Are they close to a commuting pair of Hermitian matrices, A', B', with {parallel}A-A'{parallel},{parallel}B-B'{parallel} {<=} {epsilon}? A theorem of H. Lin shows that this is uniformly true, in that for every {epsilon} > 0 there exists a {delta} > 0, independent of the size N of the matrices, for which almost commuting implies being close to a commuting pair. However, this theorem does not specifiy how {delta} depends on {epsilon}. We give uniform bounds relating {delta} and {epsilon}. The proof is constructive, giving an explicit algorithm to construct A' and B'. We provide tighter bounds in the case of block tridiagonal and tridiagnonal matrices. Within the context of quantum measurement, this implies an algorithm to construct a basis in which we can make a projective measurement that approximately measures two approximately commuting operators simultaneously. Finally, we comment briefly on the case of approximately measuring three or more approximately commuting operators using POVMs (positive operator-valued measures) instead of projective measurements.

  2. Apparatus for making photovoltaic devices

    DOE Patents [OSTI]

    Foote, James B. (Toledo, OH); Kaake, Steven A. F. (Perrysburg, OH); Meyers, Peter V. (Bowling Green, OH); Nolan, James F. (Sylvania, OH)

    1994-12-13T23:59:59.000Z

    A process and apparatus (70) for making a large area photovoltaic device (22) that is capable of generating low cost electrical power. The apparatus (70) for performing the process includes an enclosure (126) providing a controlled environment in which an oven (156) is located. At least one and preferably a plurality of deposition stations (74,76,78) provide heated vapors of semiconductor material within the oven (156) for continuous elevated temperature deposition of semiconductor material on a sheet substrate (24) including a glass sheet (26) conveyed within the oven. The sheet substrate (24) is conveyed on a roller conveyor (184) within the oven (156) and the semiconductor material whose main layer (82) is cadmium telluride is deposited on an upwardly facing surface (28) of the substrate by each deposition station from a location within the oven above the roller conveyor. A cooling station (86) rapidly cools the substrate (24) after deposition of the semiconductor material thereon to strengthen the glass sheet of the substrate.

  3. Method for melting glass by measurement of non-bridging oxygen

    DOE Patents [OSTI]

    Jantzen, Carol M. (3922 Wood Valley Dr., Aiken, SC 29801)

    1992-01-01T23:59:59.000Z

    A method for making better quality molten glass in a glass melter, the glass having the desired viscosity and, preferably, also the desired resistivity so that the glass melt can be established effectively and the product of the glass melter will have the desired level of quality. The method includes the adjustment of the composition of the glass constituents that are fed into the melter in accordance with certain correlations that reliably predict the viscosity and resistivity from the melter temperature and the melt composition, then heating the ingredients to the melter's operating temperature until they melt and homogenize. The equations include the calculation of a "non-bridging oxygen" term from the numbers of moles of the various ingredients, and then the determination of the viscosity and resistivity from the operating temperature of the melter and the non-bridging oxygen term.

  4. Method for melting glass by measurement of non-bridging oxygen

    DOE Patents [OSTI]

    Jantzen, C.M.

    1992-04-07T23:59:59.000Z

    A method is described for making better quality molten glass in a glass melter, the glass having the desired viscosity and, preferably, also the desired resistivity so that the glass melt can be established effectively and the product of the glass melter will have the desired level of quality. The method includes the adjustment of the composition of the glass constituents that are fed into the melter in accordance with certain correlations that reliably predict the viscosity and resistivity from the melter temperature and the melt composition, then heating the ingredients to the melter's operating temperature until they melt and homogenize. The equations include the calculation of a non-bridging oxygen' term from the numbers of moles of the various ingredients, and then the determination of the viscosity and resistivity from the operating temperature of the melter and the non-bridging oxygen term. 4 figs.

  5. Dissolved Oxygen in Allen CreekDissolved Oxygen in Allen Creek Dissolved oxygen (DO) enters the water by diffusion from air, as a by-product of photosynthesis and

    E-Print Network [OSTI]

    Tyler, Christy

    Dissolved Oxygen in Allen CreekDissolved Oxygen in Allen Creek Dissolved oxygen (DO) enters and rapids. There is an inverse relationship between temperature and DO, i.e. colder water holds more oxygen it supplies oxygen to aquatic organisms. Higher DO levels also give the water a better taste. Figure 2. During

  6. Increased Efficiency in SI Engine with Air Replaced by Oxygen in Argon Mixture

    SciTech Connect (OSTI)

    Killingsworth, N J; Rapp, V H; Flowers, D L; Aceves, S M; Chen, J; Dibble, R

    2010-01-13T23:59:59.000Z

    Basic engine thermodynamics predicts that spark ignited engine efficiency is a function of both the compression ratio of the engine and the specific heat ratio of the working fluid. In practice the compression ratio of the engine is often limited due to knock. Both higher specific heat ratio and higher compression ratio lead to higher end gas temperatures and increase the likelihood of knock. In actual engine cycles, heat transfer losses increase at higher compression ratios and limit efficiency even when the knock limit is not reached. In this paper we investigate the role of both the compression ratio and the specific heat ratio on engine efficiency by conducting experiments comparing operation of a single-cylinder variable-compression-ratio engine with both hydrogen-air and hydrogen-oxygen-argon mixtures. For low load operation it is found that the hydrogen-oxygen-argon mixtures result in higher indicated thermal efficiencies. Peak efficiency for the hydrogen-oxygen-argon mixtures is found at compression ratio 5.5 whereas for the hydrogen-air mixture with an equivalence ratio of 0.24 the peak efficiency is found at compression ratio 13. We apply a three-zone model to help explain the effects of specific heat ratio and compression ratio on efficiency. Operation with hydrogen-oxygen-argon mixtures at low loads is more efficient because the lower compression ratio results in a substantially larger portion of the gas to reside in the adiabatic core rather than in the boundary layer and in the crevices, leading to less heat transfer and more complete combustion.

  7. FORMATION OF MOLECULAR OXYGEN AND OZONE ON AMORPHOUS SILICATES

    SciTech Connect (OSTI)

    Jing Dapeng; He Jiao; Vidali, Gianfranco [Physics Department, Syracuse University, Syracuse, NY 13244 (United States); Brucato, John Robert; Tozzetti, Lorenzo [Osservatorio Astrofisico di Arcetri, INAF, I-50125 Florence (Italy); De Sio, Antonio [Department of Physics and Astronomy, University of Florence, I-50125 Florence (Italy)

    2012-09-01T23:59:59.000Z

    Oxygen in the interstellar medium is seen in the gas phase, in ices (incorporated in H{sub 2}O, CO, and CO{sub 2}), and in grains such as (Mg{sub x} Fe{sub 1-x} )SiO{sub 3} or (Mg{sub x} Fe{sub 1-x} ){sub 2}SiO{sub 4}, 0 < x < 1. In this investigation, we study the diffusion of oxygen atoms and the formation of oxygen molecules and ozone on the surface of an amorphous silicate film. We find that ozone is formed at low temperature (<30 K), and molecular oxygen forms when the diffusion of oxygen atoms becomes significant, at around 60 K. This experiment, besides being the first determination of the diffusion energy barrier (1785 {+-} 35 K) for oxygen atoms on a silicate surface, suggests bare silicates as a possible storage place for oxygen atoms in low-A{sub v} environments.

  8. Making Education and Training Impact on Industry

    E-Print Network [OSTI]

    Cohen, K. C.

    1980-01-01T23:59:59.000Z

    Making education and training impact on anyone these days seems to be an increasing difficult problem. Perhaps one of the reasons we see this growing problem and our relative failure in attempts to make education and training more effective...

  9. Information, decision-making and health

    E-Print Network [OSTI]

    Abaluck, Jason T

    2011-01-01T23:59:59.000Z

    This thesis consists of three essays on information, decision-making and health. All three concern the relationship between the choices consumers would make if they were "fully informed" in an appropriate sense and the ...

  10. Investigating online decision-making styles

    E-Print Network [OSTI]

    Park, Young A

    2009-05-15T23:59:59.000Z

    As one of the factors influencing consumers purchase behavior, decision-making styles are crucial for understanding consumer shopping behavior and for developing successful marketing strategies. Decision-making styles have been mainly viewed as a...

  11. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong; Zhang, Xuran; Qu, Deyu; Yang, Xiao-Qing; Lee, Hung-Sui; Qu, Deyang

    2015-08-01T23:59:59.000Z

    Oxygen reduction and oxygen evolution reactions were studied on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently andmore »a new strategy of developing the catalyst for oxygen evolution reaction.« less

  12. Investigation of the electrocatalytic oxygen reduction and evolution reactions in lithium–oxygen batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Dong [Univ. of Wisconsin, Milwaukee, WI (United States). Collece of Engineering and Applied Science; Zhang, Xuran [Wuhan Univ. of Technology, Wuhan (China). School of Science; Qu, Deyu [Wuhan Univ. of Technology, Wuhan (China). School of Science; Yang, Xiao-Qing [Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Lee, Hung-Sui [Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Qu, Deyang [Univ. of Wisconsin, Milwaukee, WI (United States). Collece of Engineering and Applied Science

    2015-08-01T23:59:59.000Z

    Oxygen reduction and oxygen evolution reactions were studied on graphite electrodes with different crystal orientations. The kinetics for the redox couple O2/O2•- are very fast, therefore no catalyst seems necessary to assist the charge transfer process. Apparently, the main source of the overpotential for the O2 reduction reaction is from mass diffusion. Li2O2 becomes soluble in non-aqueous electrolytes in the presence of the tetraethylammonium tetrafluoroborate additive. The soluble B-O22- ions can be oxidized electro-catalytically. The edge orientation of graphite demonstrates superior catalytic activity for the oxidation over basal orientation. The findings reveal an opportunity for recharging Li-air batteries efficiently and a new strategy of developing the catalyst for oxygen evolution reaction.

  13. Vehicle Technologies Office Merit Review 2015: Basic Energy Sciences Overview

    Broader source: Energy.gov [DOE]

    Presentation given by U.S. Department of Energy  at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation meeting about Basic Energy...

  14. OPVs and Solar Cells: The Basics | University of Texas Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OPVs AND SOLAR CELLS: THE BASICS Harvesting solar energy is a key endeavor for this century as we face ever-decreasing fossil fuel world reserves and ever-increasing environmental...

  15. 1. INTRODUCTION Smith (1979) reviewed the basic ways in which

    E-Print Network [OSTI]

    Houze Jr., Robert A.

    1. INTRODUCTION Smith (1979) reviewed the basic ways in which upslope flow can affect precipitation is by how closely it achieves Smith's sim- plified model. One of the factors identified by Smith (1979

  16. Basic concepts defining the property of ''reliability'' for energy systems

    SciTech Connect (OSTI)

    Rudenko, Yu.N.; Sin'chugov, F.I.; Smirnov, E.P.

    1981-01-01T23:59:59.000Z

    The basic concepts defining the complex property of ''reliability'' for energy systems (electric-power and pipeline systems) are considered; they include the properties, states, and events that characterize reliability as well as the reliability indices.

  17. Tutorial: The Basics of SAXS Data Analysis | Stanford Synchrotron...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tutorial: The Basics of SAXS Data Analysis Thursday, November 17, 2011 - 1:00pm SLAC, Redtail Hawk Conference Room 108A Dr. Alexander V. Shkumatov, Biological Small Angle...

  18. 1.12 Basic Theory of Differential Equations

    E-Print Network [OSTI]

    PRETEX (Halifax NS) #1 1054 1999 Mar 05 10:59:16

    2010-01-20T23:59:59.000Z

    Feb 16, 2007 ... Table 1.12.1: A summary of the basic solution techniques for y = f(x,y). Example ... A racquetball player standing at the back wall of the court hits ...

  19. Basic Integrative Models for Offshore Wind Turbine Systems

    E-Print Network [OSTI]

    Aljeeran, Fares

    2012-07-16T23:59:59.000Z

    This research study developed basic dynamic models that can be used to accurately predict the response behavior of a near-shore wind turbine structure with monopile, suction caisson, or gravity-based foundation systems. The marine soil conditions...

  20. Efficacy of Learning Strategies Instruction in Adult Basic Education

    E-Print Network [OSTI]

    Hock, Mike; Mellard, Daryl

    2011-01-01T23:59:59.000Z

    Results from randomized controlled trials of learning strategies instruction with 375 adult basic education (AE) participants are reported. Reading outcomes from whole group strategic instruction in one of four learning ...

  1. Personal Finance Make Your Money Matter

    E-Print Network [OSTI]

    Stevenson, Mark

    Personal Finance Make Your Money Matter Name: Registration number: Department: Year of study of your portfolio. #12;Personal Finance Make Your Money Matter2 Contents Timetable Page 3 Introduction 16 #12;Personal Finance Make Your Money Matter3 Timetable Friday 6.00 pm Introduction

  2. The Mechanisms of Oxygen Reduction and Evolution Reactions in Nonaqueous Lithium-Oxygen Batteries

    SciTech Connect (OSTI)

    Cao, Ruiguo; Walter, Eric D.; Xu, Wu; Nasybulin, Eduard N.; Bhattacharya, Priyanka; Bowden, Mark E.; Engelhard, Mark H.; Zhang, Jiguang

    2014-09-01T23:59:59.000Z

    The oxygen reduction/evolution reaction (ORR/OER) mechanisms in nonaqueous Li-O2 batteries have been investigated by using electron paramagnetic resonance spectroscopy in this work. We identified the superoxide radical anion (O2•-) as an intermediate in the ORR process using 5,5-dimethyl-pyrroline N-oxide as a spin trap, while no O2•- in OER was detected during the charge process. These findings provide insightful understanding on the fundamental oxygen reaction mechanisms in rechargeable nonaqueous Li-O2 batteries.

  3. Bayesian decision making in human collectives with binary choices

    E-Print Network [OSTI]

    Eguíluz, Víctor M; Fernández-Gracia, J

    2015-01-01T23:59:59.000Z

    Here we focus on the description of the mechanisms behind the process of information aggregation and decision making, a basic step to understand emergent phenomena in society, such as trends, information spreading or the wisdom of crowds. In many situations, agents choose between discrete options. We analyze experimental data on binary opinion choices in humans. The data consists of two separate experiments in which humans answer questions with a binary response, where one is correct and the other is incorrect. The questions are answered without and with information on the answers of some previous participants. We find that a Bayesian approach captures the probability of choosing one of the answers. The influence of peers is uncorrelated with the difficulty of the question. The data is inconsistent with Weber's law, which states that the probability of choosing an option depends on the proportion of previous answers choosing that option and not on the total number of those answers. Last, the present Bayesian ...

  4. Oxygen stabilized zirconium-vanadium-iron alloy

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

    1982-01-01T23:59:59.000Z

    An oxygen stabilized intermetallic compound having the formula (Zr.sub.1-x Ti.sub.x).sub.2-u (V.sub.1-y Fe.sub.y)O.sub.z where x=0.0 to 0.9, y=0.01 to 0.9, z=0.25 to 0.5 and u=0 to 1. The compound is capable of reversibly sorbing hydrogen at temperatures from -196.degree. C. to 200.degree. C. at pressures down to 10.sup.-6 torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

  5. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect (OSTI)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01T23:59:59.000Z

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

  6. OXYGEN DEPLETION IN THE INTERSTELLAR MEDIUM: IMPLICATIONS FOR GRAIN MODELS AND THE DISTRIBUTION OF ELEMENTAL OXYGEN

    SciTech Connect (OSTI)

    Whittet, D. C. B. [New York Center for Astrobiology, and Department of Physics, Applied Physics and Astronomy, Rensselaer Polytechnic Institute, 110 Eighth Street, Troy, NY 12180 (United States)

    2010-02-20T23:59:59.000Z

    This paper assesses the implications of a recent discovery that atomic oxygen is being depleted from diffuse interstellar gas at a rate that cannot be accounted for by its presence in silicate and metallic oxide particles. To place this discovery in context, the uptake of elemental O into dust is considered over a wide range of environments, from the tenuous intercloud gas and diffuse clouds sampled by the depletion observations to dense clouds where ice mantles and gaseous CO become important reservoirs of O. The distribution of O in these contrasting regions is quantified in terms of a common parameter, the mean number density of hydrogen (n{sub H}). At the interface between diffuse and dense phases (just before the onset of ice-mantle growth) as much as {approx}160 ppm of the O abundance is unaccounted for. If this reservoir of depleted oxygen persists to higher densities it has implications for the oxygen budget in molecular clouds, where a shortfall of the same order is observed. Of various potential carriers, the most plausible appears to be a form of O-bearing carbonaceous matter similar to the organics found in cometary particles returned by the Stardust mission. The 'organic refractory' model for interstellar dust is re-examined in the light of these findings, and it is concluded that further observations and laboratory work are needed to determine whether this class of material is present in quantities sufficient to account for a significant fraction of the unidentified depleted oxygen.

  7. Oxygen Abundance Measurements of SHIELD Galaxies

    E-Print Network [OSTI]

    Haurberg, Nathalie C; Cannon, John M; Marshall, Melissa V

    2015-01-01T23:59:59.000Z

    We have derived oxygen abundances for 8 galaxies from the Survey of HI in Extremely Low-mass Dwarfs (SHIELD). The SHIELD survey is an ongoing study of very low-mass galaxies, with M$_{\\rm HI}$ between 10$^{6.5}$ and 10$^{7.5}$ M$_{\\odot}$, that were detected by the Arecibo Legacy Fast ALFA (ALFALFA) survey. H$\\alpha$ images from the WIYN 3.5m telescope show that these 8 SHIELD galaxies each possess one or two active star-forming regions which were targeted with long-slit spectral observations using the Mayall 4m telescope at KPNO. We obtained a direct measurement of the electron temperature by detection of the weak [O III] $\\lambda$4363 line in 2 of the HII regions. Oxygen abundances for the other HII regions were estimated using a strong-line method. When the SHIELD galaxies are plotted on a B-band luminosity-metallicity diagram they appear to suggest a slightly shallower slope to the relationship than normally seen. However, that offset is systematically reduced when the near-infrared luminosity is used ins...

  8. Dilute Oxygen Combustion Phase I Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    1997-10-31T23:59:59.000Z

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  9. Dilute oxygen combustion. Phase I report

    SciTech Connect (OSTI)

    NONE

    1997-10-01T23:59:59.000Z

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NO{sub x}) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NO{sub x} through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NO{sub x} production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature ({approximately}1366 K) oxidant (7-27% O{sub 2} vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d{sup +} scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d{sup +} scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW ({approximately}0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NO{sub x} emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NO{sub x} emissions below 5{times}10{sup -3} g/MJ (10 ppm-air equivalent at 3% O{sub 2} dry) were obtained for furnace temperatures below 1533 K (2300{degree}F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in- furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, with increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, requires additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  10. Dilute Oxygen Combustion Phase 2 Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    2005-09-30T23:59:59.000Z

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  11. Heat release analysis of oxygen-enriched diesel combustion

    SciTech Connect (OSTI)

    Assanis, D.; Karvounis, E. (Univ. of Illinois, Urbana, IL (United States)); Sekar, R.; Marr, W. (Argonne National Lab., IL (United States))

    1993-10-01T23:59:59.000Z

    A heat release correlation for oxygen-enriched diesel combustion is being developed through heat release analysis of cylinder pressure data from a single-cylinder diesel engine operating under various levels of oxygen enrichment. Results show that standard combustion correlations available in the literature do not accurately describe oxygen-enriched diesel combustion. A novel functional form is therefore proposed, which is shown to reproduce measured heat release profiles closely, under different operating conditions and levels of oxygen enrichment. The mathematical complexity of the associated curve-fitting problem is maintained at the same level of difficulty as for standard correlations. When the novel correlation is incorporated into a computer simulation of diesel engine operation with oxygen enrichment, the latter predicts pressure traces in excellent agreement with measured pressure data. This demonstrates the potential of the proposed combustion simulation to guide the application of oxygen-enriched technology successfully to a variety of multicylinder diesel systems.

  12. A fiber optic probe for oxygen partial pressure sensing 

    E-Print Network [OSTI]

    Schlain, Leslie Ariel

    1986-01-01T23:59:59.000Z

    of the electronic circuitry, and Steve Spar for software development. TABLE OF CONTENTS INTRODUCTION Purpose Current Status of Conventional Oxygen Sensors Optical Sensors Technical Obj ect ives 1 5 10 MATERIAL AND METHODS 14 Transducer Design... the partial pressure of oxygen (p02) in solutions. The research effort was specifically aimed at the development of an oxygen sensor suitable for physiological applications. The sensor described in this thesis is an application of a generic fiber optic...

  13. Nanoscale Phase Separation, Cation Ordering, and Surface Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    been identified to be attributed to the oxygen deficiency near the particle surfaces. Characterization of the nanoscale phase separation and cation ordering in the pristine...

  14. atomic oxygen erosion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Chemistry Websites Summary: OXYGEN ADSORPTION ON NITROGEN CONTAINING CARBON SURFACES Alejandro Montoya, Jorge O. Gil,...

  15. Microbial metatranscriptomics in a permanent marine oxygen minimum zone

    E-Print Network [OSTI]

    Stewart, Frank J.

    Simultaneous characterization of taxonomic composition, metabolic gene content and gene expression in marine oxygen minimum zones (OMZs) has potential to broaden perspectives on the microbial and biogeochemical dynamics ...

  16. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    - - - - - - - - - - - - See footnotes at end of table. 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State 116 Energy Information...

  17. Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type...

    Gasoline and Diesel Fuel Update (EIA)

    Information Administration Petroleum Marketing Annual 1995 Table 33. Oxygenated Motor Gasoline Prices by Grade, Sales Type, PAD District, and State (Cents per Gallon...

  18. atmospheric oxygenation recorded: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    cores may contain high quality records of atmospheric deposition. The qualitative Short, Daniel 3 Bistability of atmospheric oxygen and the Great Oxidation Geosciences Websites...

  19. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen...

    Broader source: Energy.gov (indexed) [DOE]

    Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors....

  20. Electron-Stimulated Production of Molecular Oxygen in Amorphous...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water on Pt(111): Precursor Transport Through the Hydrogen Electron-Stimulated Production of Molecular Oxygen in Amorphous Solid Water on Pt(111): Precursor Transport Through the...

  1. Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the efficiency of solid oxide fuel cells can be improved. Citation: Edmondson PD, WJ Weber, F Namavar, and Y Zhang.2011."Lattice Distortions and Oxygen Vacancies Produced in...

  2. active oxygen probe: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: I present here the results of the first principles studies of the adsorption energetics of the intermediates of the oxygen electro-reduction reaction (ORR)...

  3. Catalytic reduction system for oxygen-rich exhaust

    DOE Patents [OSTI]

    Vogtlin, G.E.; Merritt, B.T.; Hsiao, M.C.; Wallman, P.H.; Penetrante, B.M.

    1999-04-13T23:59:59.000Z

    Non-thermal plasma gas treatment is combined with selective catalytic reduction to enhance NO{sub x} reduction in oxygen-rich vehicle engine exhausts. 8 figs.

  4. Geothermal reservoir temperatures estimated from the oxygen isotope...

    Open Energy Info (EERE)

    reservoir temperatures estimated from the oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes Jump to: navigation, search OpenEI...

  5. Geothermal Reservoir Temperatures Estimated from the Oxygen Isotope...

    Open Energy Info (EERE)

    Temperatures Estimated from the Oxygen Isotope Compositions of Dissolved Sulfate and Water from Hot Springs and Shallow Drillholes Jump to: navigation, search OpenEI Reference...

  6. An Oxygen Isotope Study Of Silicates In The Larderello Geothermal...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: An Oxygen Isotope Study Of Silicates In The Larderello Geothermal Field, Italy Abstract...

  7. activated sludge oxygen: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Effects of oxygen transport limitation on nitrification in the activated sludge process Environmental Management and Restoration Websites Summary: sludge age (MCRT), pH,...

  8. Combustion in a multiburner furnace with selective flow of oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in a multiburner furnace with selective flow of oxygen Re-direct Destination: Improved operational characteristics such as improved fuel efficiency, reduction of NOx formation,...

  9. Thickness Dependency of Thin Film Samaria Doped Ceria for Oxygen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High temperature oxygen sensors are widely used for exhaust gas monitoring in automobiles. This particular study explores the use of thin film single crystalline samaria...

  10. Method of making carbon nanotube composite materials

    DOE Patents [OSTI]

    O'Bryan, Gregory; Skinner, Jack L; Vance, Andrew; Yang, Elaine Lai; Zifer, Thomas

    2014-05-20T23:59:59.000Z

    The present invention is a method of making a composite polymeric material by dissolving a vinyl thermoplastic polymer, un-functionalized carbon nanotubes and hydroxylated carbon nanotubes and optionally additives in a solvent to make a solution and removing at least a portion of the solvent after casting onto a substrate to make thin films. The material has enhanced conductivity properties due to the blending of the un-functionalized and hydroxylated carbon nanotubes.

  11. Process for selection of oxygen-tolerant algal mutants that produce H{sub 2}

    DOE Patents [OSTI]

    Ghirardi, M.L.; Seibert, M.

    1999-02-16T23:59:59.000Z

    A process for selection of oxygen-tolerant, H{sub 2}-producing algal mutant cells comprises: (a) growing algal cells photoautotrophically under fluorescent light to mid log phase; (b) inducing algal cells grown photoautotrophically under fluorescent light to mid log phase in step (a) anaerobically by (1) resuspending the cells in a buffer solution and making said suspension anaerobic with an inert gas and (2) incubating the suspension in the absence of light at ambient temperature; (c) treating the cells from step (b) with metronidazole, sodium azide, and added oxygen to controlled concentrations in the presence of white light; (d) washing off metronidazole and sodium azide to obtain final cell suspension; (e) plating said final cell suspension on a minimal medium and incubating in light at a temperature sufficient to enable colonies to appear; (f) counting the number of colonies to determine the percent of mutant survivors; and (g) testing survivors to identify oxygen-tolerant H{sub 2}-producing mutants. 5 figs.

  12. Carbon nanohoops and methods of making

    DOE Patents [OSTI]

    Jasti, Ramesh; Bertozzi, Carolyn

    2013-06-11T23:59:59.000Z

    The present invention provides cycloparaphenylene compounds, their macrocyclic precursors, and methods for making the compounds. The cycloparaphenylene compounds can be used to prepare armchair carbon nanotubes.

  13. Korean oxygenates rule sparks MTBE capacity plans

    SciTech Connect (OSTI)

    Kim, Hyung-Jin

    1994-06-15T23:59:59.000Z

    The Korean government`s strict standard for gasoline sold domestically is expected to have a significant impact on the methyl tert-butyl ether (MTBE) market. The mandate-requiring gasoline oxygen content of 0.5% this year, 0.75% by 1996, and 1.0% by 1998-has sparked a rush by Korean refineries to build new MTBE plants. If expansion plans are carried out, Korea`s MTBE capacity will increase from 280,000 m.t./year to 650,000 m.t./year by 1996, far surpassing predicted demand. Honam Oil, part of the Lucky Group, plans startup of a 100,000-m.t./year unit at Yeochon by early 1996. In addition, by the end of 1996 Ssangyong Oil will bring a 100,000-m.t./year unit onstream.

  14. Assessment of the basic energy sciences program. Volume II. Appendices

    SciTech Connect (OSTI)

    Not Available

    1982-03-01T23:59:59.000Z

    A list of experts reviewing the Basic Energy Sciences (BES) program and their organizations are given. The assessment plan is explained; the program examined the following: quality of science being conducted in the program, quality of performers supported by the Basic Energy Sciences (BES) program, and the impact of the research on mission oriented needs. The intent of the assessment is to provide an indication of general status relative to these questions for the BES divisions. The approach to the assessment is described. The sampling plan which was used as a guide in determining the sample size and selecting the sample to evaluate the research program of the Office of Basic Energy Sciences are discussed. Special analyses were conducted on the dispersion of reviewers' ratings, the ratings of the lower funded projects, and the amount of time the principal investigator devoted to the project. These are presented in the final appendix together with histograms for individual rating variables for each program area. (MCW)

  15. Dilute Oxygen Combustion - Phase 3 Report

    SciTech Connect (OSTI)

    Riley, Michael F.

    2000-05-31T23:59:59.000Z

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good, and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel's standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion on furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  16. Dilute Oxygen Combustion Phase 3 Final Report

    SciTech Connect (OSTI)

    Riley, M.F.; Ryan, H.M.

    2000-05-31T23:59:59.000Z

    Dilute Oxygen Combustion (DOC) burners have been successfully installed and operated in the reheat furnace at Auburn Steel Co., Inc., Auburn, NY, under Phase 3 of the Dilute Oxygen Combustion project. Two new preheat zones were created employing a total of eight 6.5 MMBtu/hr capacity burners. The preheat zones provide a 30 percent increase in maximum furnace production rate, from 75 tph to 100 tph. The fuel rate is essentially unchanged, with the fuel savings expected from oxy-fuel combustion being offset by higher flue gas temperatures. When allowance is made for the high nitrogen level and high gas phase temperature in the furnace, measured NOx emissions are in line with laboratory data on DOC burners developed in Phase 1 of the project. Burner performance has been good and there have been no operating or maintenance problems. The DOC system continues to be used as part of Auburn Steel?s standard reheat furnace practice. High gas phase temperature is a result of the high firing density needed to achieve high production rates, and little opportunity exists for improvement in that area. However, fuel and NOx performance can be improved by further conversion of furnace zones to DOC burners, which will lower furnace nitrogen levels. Major obstacles are cost and concern about increased formation of oxide scale on the steel. Oxide scale formation may be enhanced by exposure of the steel to higher concentrations of oxidizing gas components (primarily products of combustion) in the higher temperature zones of the furnace. Phase 4 of the DOC project will examine the rate of oxide scale formation in these higher temperature zones and develop countermeasures that will allow DOC burners to be used successfully in these furnace zones.

  17. Introduction Two Applications Basic Operations Tools Overview of the Tools A Survey of Techniques Used in

    E-Print Network [OSTI]

    Agrawal, Manindra

    Introduction Two Applications Basic Operations Tools Overview of the Tools A Survey of Techniques and IIT Kanpur Kunming Tutorial, May 2005 #12;Introduction Two Applications Basic Operations Tools Cryptography Application: RSA Cryptosystem Complexity of Basic Operations Tools for Designing Algorithms

  18. Oximeter for reliable clinical determination of blood oxygen saturation in a fetus

    DOE Patents [OSTI]

    Robinson, Mark R. (Albuquerque, NM); Haaland, David M. (Albuquerque, NM); Ward, Kenneth J. (Madison, WI)

    1996-01-01T23:59:59.000Z

    With the crude instrumentation now in use to continuously monitor the status of the fetus at delivery, the obstetrician and labor room staff not only over-recognize the possibility of fetal distress with the resultant rise in operative deliveries, but at times do not identify fetal distress which may result in preventable fetal neurological harm. The invention, which addresses these two basic problems, comprises a method and apparatus for non-invasive determination of blood oxygen saturation in the fetus. The apparatus includes a multiple frequency light source which is coupled to an optical fiber. The output of the fiber is used to illuminate blood containing tissue of the fetus. In the preferred embodiment, the reflected light is transmitted back to the apparatus where the light intensities are simultaneously detected at multiple frequencies. The resulting spectrum is then analyzed for determination of oxygen saturation. The analysis method uses multivariate calibration techniques that compensate for nonlinear spectral response, model interfering spectral responses and detect outlier data with high sensitivity.

  19. Oxygen Chemistry in the Circumstellar Envelope of the Carbon-Rich Star IRC+10216

    E-Print Network [OSTI]

    Marcelino Agundez; Jose Cernicharo

    2006-05-25T23:59:59.000Z

    In this paper we study the oxygen chemistry in the C-rich circumstellar shells of IRC+10216. The recent discoveries of oxygen bearing species (water, hydroxyl radical and formaldehyde) toward this source challenge our current understanding of the chemistry in C-rich circumstellar envelopes. The presence of icy comets surrounding the star or catalysis on iron grain surfaces have been invoked to explain the presence of such unexpected species. This detailed study aims at evaluating the chances of producing O-bearing species in the C-rich circumstellar envelope only by gas phase chemical reactions. For the inner hot envelope, it is shown that although most of the oxygen is locked in CO near the photosphere (as expected for a C/O ratio greater than 1), some stellar radii far away species such as H2O and CO2 have large abundances under the assumption of thermochemical equilibrium. It is also shown how non-LTE chemistry makes very difficult the CO-->H2O,CO2 transformation predicted in LTE. Concerning the chemistry in the outer and colder envelope, we show that formaldehyde can be formed through gas phase reactions. However, in order to form water vapor it is necessary to include a radiative association between atomic oxygen and molecular hydrogen with a quite high rate constant. The chemical models explain the presence of HCO+ and predict the existence of SO and H2CS (which has been detected in a 3 mm line survey to be published). We have modeled the line profiles of H2CO, H2O, HCO+, SO and H2CS using a non-local radiative transfer model and the abundance profiles predicted by our chemical model. The results have been compared to the observations and discussed.

  20. Utrecht University's High Potential Programme Making Room

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Utrecht University's High Potential Programme Making Room for Talent 2 #12;Making Room for Talent Utrecht University has a worldwide reputation for excellence in research across a broad range. This is why in 2003 Utrecht University created the High Potential Programme, an incentive scheme which gives

  1. Make the Grade General Test Taking Tips

    E-Print Network [OSTI]

    Kasman, Alex

    Make the Grade General Test Taking Tips Adapted from: The Academic Skills Center At California Polytechnic State University Tips Before, During, and After the Test Here are some tips you can implement to help you through tests. Try implementing these techniques to make the grade! Before Start to prepare

  2. Preferences, Information, and Group Decision Making

    E-Print Network [OSTI]

    Espinoza, Alejandro

    2009-05-15T23:59:59.000Z

    This study will examine how the structure of preferences of group members in a decision-making group, as well as the information they have, affects the collection and the processing of information by individual members of a decision making group...

  3. Preferences, Information, and Group Decision Making 

    E-Print Network [OSTI]

    Espinoza, Alejandro

    2009-05-15T23:59:59.000Z

    This study will examine how the structure of preferences of group members in a decision-making group, as well as the information they have, affects the collection and the processing of information by individual members of a decision making group...

  4. Job Dislocation Making Smart Financial Choices

    E-Print Network [OSTI]

    Job Dislocation Making Smart Financial Choices after a Job Loss #12;Who We Are FINRA FINRA.workforceatm.org. #12;Job Dislocation MAKING SMART FINANCIAL CHOICES AFTER A JOB LOSS You may not be able to control in the event of unemployment; protect yourself when getting financial advice during a period of job dislocation

  5. Hypolimnetic Oxygen Depletion in Eutrophic Lakes Beat Muller,*,

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Hypolimnetic Oxygen Depletion in Eutrophic Lakes Beat Muller,*, Lee D. Bryant,, Andreas Matzinger obtained from 11 eutrophic lakes and suggests a model describing the consumption of dissolved oxygen (O2) in the hypolimnia of eutrophic lakes as a result of only two fundamental processes: O2 is consumed (i) by settled

  6. Anoxygenic photosynthesis modulated Proterozoic oxygen and sustained Earth's middle age

    E-Print Network [OSTI]

    Macalady, Jenn

    Anoxygenic photosynthesis modulated Proterozoic oxygen and sustained Earth's middle age D. T photosynthesis to overall primary production would have influ- enced oceanic redox and the Proterozoic O2 budget time in Earth's history, complete dominance of oxygenic photosynthesis in the oceans. This paved

  7. Reactive oxygen species deglycosilate glomerular a-dystroglycan

    E-Print Network [OSTI]

    Campbell, Kevin P.

    Reactive oxygen species deglycosilate glomerular a-dystroglycan NPJ Vogtla¨nder1 , WPM Tamboer1 open. Reactive oxygen species (ROS) are known to degrade and depolymerize carbohydrates, and to playDa in skeletal muscle, ranging from 120 kDa in brain to 190 kDa in the Torpedo electric organ.8

  8. Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence Ruby N. Ghosh,a) Gregory L on a reflection-mode fiber-optic oxygen sensor based on the 3 O2 quenching of the red emission from hexanuclear, and medical applications. In these en- vironments the advantages of fiber-optic chemical sensors are that they

  9. Singlet oxygen luminescence detection with a fibre-coupled superconducting

    E-Print Network [OSTI]

    Greenaway, Alan

    Singlet oxygen luminescence detection with a fibre-coupled superconducting nanowire single luminescence detection Fibre-based singlet oxygen luminescence detection References Superconducting Detector, is an intermediate in many biological processes. We employ a superconducting nanowire single-photon detector (SNSPD

  10. Unexpected Nondissociative Binding of N2O on Oxygen Vacancies...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile TiO2(110)-1×1 . Unexpected Nondissociative Binding of N2O on Oxygen Vacancies on a Rutile TiO2(110)-1×1 ....

  11. Palladium-cobalt particles as oxygen-reduction electrocatalysts

    DOE Patents [OSTI]

    Adzic, Radoslav (East Setauket, NY); Huang, Tao (Manorville, NY)

    2009-12-15T23:59:59.000Z

    The present invention relates to palladium-cobalt particles useful as oxygen-reducing electrocatalysts. The invention also relates to oxygen-reducing cathodes and fuel cells containing these palladium-cobalt particles. The invention additionally relates to methods for the production of electrical energy by using the palladium-cobalt particles of the invention.

  12. On the thermo-elastostatics of heterogeneous materials. II. Analyze and generalization of some basic hypotheses

    E-Print Network [OSTI]

    Valeriy A. Buryachenko

    2009-12-21T23:59:59.000Z

    One considers linearly thermoelastic composite media, which consist of a homogeneous matrix containing a statistically homogeneous random set of ellipsoidal uncoated or coated inclusions. Effective properties (such as compliance and thermal expansion) as well as the first statistical moments of stresses in the phases are estimated for the general case of nonhomogeneity of the thermoelastic inclusion properties. At first, one shortly reproduces both the basic assumptions and propositions of micromechanics used in most popular methods, namely: effective field hypothesis, quasi-crystallite approximation, and the hypothesis of "ellipsoidal symmetry". The explicit new representations of the effective thermoelastic properties and stress concentration factor are expressed through some building blocks described by numerical solutions for both the one and two inclusions inside the infinite medium subjected to both the homogeneous and inhomogeneous remote loading. The method uses as a background the new general integral equation proposed in the accompanied paper and makes it possible to abandon the basic concepts of micromechanics mentioned above. The results of this abandonment are quantitatively estimated for some modeled composite reinforced by aligned continously inhomogeneous fibers. Some new effects are detected that are impossible in the framework of a classical background of micromechanics.

  13. Summary proceedings of a workshop on Bioremediation and its Societal Implications and Concerns (BASIC)

    SciTech Connect (OSTI)

    Drell, D.W. [Department of Energy, Germantown, MD (United States). Office of Health and Environmental Research, Health Effects and Life Sciences Research Division; Metting, F.B. Jr. [Pacific Northwest National Lab., Richland, WA (United States); Wuy, L.D. [ed.] [Lawrence Berkeley National Lab., CA (United States)

    1996-11-01T23:59:59.000Z

    This document summarizes the proceedings of a workshop on Bioremediation and Its Societal Implications and Concerns (BASIC) held July 18-19, 1996 at the Airlie Center near Warrenton, Virginia. The workshop was sponsored by the Office of Health and Environmental Research (OHER), U.S. Department of Energy (DOE), as part of its fundamental research program in Natural and Accelerated Bioremediation Research (NABIR). The information summarized in these proceedings represents the general conclusions of the workshop participants, and not the opinions of workshop organizers or sponsors. Neither are they consensus opinions, as opinions differed among participants on a number of points. The general conclusions presented below were reached through a review, synthesis, and condensation of notes taken by NABIR Program Office staff and OHER program managers throughout the workshop. Specific contributions by participants during breakout sessions are recorded in bullet form in the appropriate sections, without attribution to the contributors. These contributions were transcribed as faithfully as possible from notes about the original discussions. They were edited only to make them grammatically correct, parallel in structure, and understandable to someone not familiar with the NABIR Program or BASIC element.

  14. Export Control Basics The Johns Hopkins University Community

    E-Print Network [OSTI]

    Connor, Ed

    Export Control Basics for The Johns Hopkins University Community Export Controls at JHU address Introduction to Export Controls and to contact JHU's Export Control Officer whenever they expect to be involved with any of these issues: Frank Barker, Export Control Officer Wyman Park Center W-400 410-516-0415 fwb

  15. Basic Notation and Background Chi-Kwong Li

    E-Print Network [OSTI]

    Li, Chi-Kwong

    and Mary, Williamsburg, Virginia, USA; Department of Mathematics, Taiyuan University of Technology, Taiyuan Let Mn be the set (vector space/algebra) of n � n matrices. (a) One can perform A + B, AB and µA for A, B Mn and µ C. (b) One can compute the eigenvalues and eigenvectors of A Mn. Chi-Kwong Li Basic

  16. Original article Stem basic density and bark proportion

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    -scale operation at Burkina Faso for the supply of fuel-wood to the capital Ougadougou [5]. In fact, large forest coppice forests in Burkina Faso Robert Nygård* and Björn Elfving SLU, Department of Silviculture, 901 83 sampled, the stem basic density varied between 301­854 kg m-3. Bark proportion of stem biomass varied

  17. Auction Basics for Wholesale Power Markets: Objectives and Pricing Rules

    E-Print Network [OSTI]

    Tesfatsion, Leigh

    1 Auction Basics for Wholesale Power Markets: Objectives and Pricing Rules Leigh Tesfatsion, Member to U.S. restructured wholesale power markets, i.e., centrally-administered wholesale power markets and illustrated. Complicating factors specific to wholesale power markets are clarified, and recent advances

  18. Lesson Summary Students will participate in a very basic

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    to introduce the topic of global warming. Prior Knowledge & Skills · Basic knowledge about the sun's warming Models NSES Science Standards Physical Science Light, Heat, Electricity, Magnetism Science in Personal warms the Earth. Enter Sun. Enter Earth. Enter two Heats. The Sun sends both Heats toward the Earth

  19. Estimation of steady-state basic parameters of stars

    B. V. Vasiliev

    2000-03-30T23:59:59.000Z

    From a minimum of total energy of celestial bodies, their basic parameters are obtained. The steady-state values of the mass, radius, and temperature of stars and white dwarfs, as well as masses of pulsars are calculated. The luminosity and giromagnetic ratio of celestial bodies are estimated. All the obtained values are in a satisfactory agreement with observation data.

  20. FWP executive summaries: Basic energy sciences materials sciences programs

    SciTech Connect (OSTI)

    Samara, G.A.

    1996-02-01T23:59:59.000Z

    This report provides an Executive Summary of the various elements of the Materials Sciences Program which is funded by the Division of Materials Sciences, Office of Basic Energy Sciences, U.S. Department of Energy at Sandia National Laboratories, New Mexico.

  1. Japan, EU reach basic agreement over ITER The Yomiuri Shimbun

    E-Print Network [OSTI]

    Japan, EU reach basic agreement over ITER The Yomiuri Shimbun The government and the European Union to the unsuccessful candidate country. Japan and France, the EU's candidate, have been bidding to host the facility bidder's country. The ITER project participants--Japan, China, the EU, Russia, South Korea and the United

  2. East Carolina University RADIATION SAFETY BASIC SCIENCE COMMITTEE

    E-Print Network [OSTI]

    for the Protection Against Radiation dictates that a radiation safety committee will provide oversight for all11/27/2013 East Carolina University RADIATION SAFETY ­ BASIC SCIENCE COMMITTEE Membership: 16 members Members are recommended by the Radiation Safety Officer but the Vice Chancellor of Health Sciences

  3. TruLifesaver American Heart Association Basic Life Support Course

    E-Print Network [OSTI]

    Gering, Jon C.

    TruLifesaver American Heart Association Basic Life Support Course The Truman Institute P: 660 concepts of high-quality CPR · The American Heart Association Chain of Survival · Differences between Cost includes all instruction, materials and two year certification with the American Heart Association

  4. KRNFYSIK AK FKF 011 Nuclear Physics, Basic Course

    E-Print Network [OSTI]

    K�RNFYSIK AK FKF 011 Nuclear Physics, Basic Course Antal poäng: 3.0. Obligatorisk för: F3. Valfri för: E4. Kursansvarig: Docent Per Kristiansson, per.kristiansson@nuclear.lu.se Förkunskapskrav. Neutroners egenskaper, framställning och registrering. Kärnreaktioner. Fission och fusion. Acceleratorer

  5. KRNFYSIK AK FKF011 Nuclear Physics, Basic Course

    E-Print Network [OSTI]

    K�RNFYSIK AK FKF011 Nuclear Physics, Basic Course Poäng: 3.0 Betygskala: TH Obligatorisk för: F3 Valfri för: E4 Kursansvarig: Docent Per Kristiansson, per.kristiansson@nuclear.lu.se Förkunskapskrav. Neutroners egenskaper, framställning och registrering. Kärnreaktioner. Fission och fusion. Acceleratorer

  6. Start-Ups for Smarties Introduction and Basics

    E-Print Network [OSTI]

    Arnold, Jonathan

    Start-Ups for Smarties 4 Introduction and Basics Introduction Academic researchers frequently suspect that a discovery of theirs may have what it takes to spawn a start-up company. Usually be missing the boat by not being in- volved in a start-up. This is a dramatic change from the situation

  7. 1. Introduction The atmospheric greenhouse effect is the basic mechanism

    E-Print Network [OSTI]

    1. Introduction The atmospheric greenhouse effect is the basic mechanism whereby absorbed solar system of the Earth is endowed with a moderately strong greenhouse effect that is characterized by non CO2. There is a strong feedback contribution to the greenhouse effect by water vapor and clouds

  8. Proceedings of the ARO Rotorcraft Wake Prediction Basic Research Workshop

    E-Print Network [OSTI]

    Wake Structure Of A Horizontal-Axis Wind Turbine 7 A.G. Brand BHTI The Nature Of Vortex Ring State 8 S Disk Model For Interacting Wind Turbine Wakes 15 R.B. Haehnel, Y. Wenren, J. Steinhoff USA CRREL, FProceedings of the ARO Rotorcraft Wake Prediction Basic Research Workshop Daniel Guggenheim School

  9. SECURITY BASICS FOR MOBILE DEVICES UNH IT SECURITY, DECEMBER 2011

    E-Print Network [OSTI]

    SECURITY BASICS FOR MOBILE DEVICES UNH IT SECURITY, DECEMBER 2011 Choose brands and models of mobile devices that have the options referenced below. Use all available security options that your or sensitive university information in un-approved off-campus services, such as public cloud based services

  10. Class 16: Basics of Functional Dependencies and Normalization for

    E-Print Network [OSTI]

    Yang, Jing

    11/17/2010 1 ITCS 3160 Jing Yang 2010 Fall Class 16: Basics of Functional Dependencies Functional Dependency (cont'd.) · Given a populated relation ­ Cannot determine which FDs hold and which do not ­ Unless meaning of and relationships among attributes known ­ Can state that FD does not hold

  11. KH Computational Physics-2006 Basic Numerical Algorithms Integration

    E-Print Network [OSTI]

    Glashausser, Charles

    KH Computational Physics- 2006 Basic Numerical Algorithms Integration Numerical integration competing factors one needs to consider · speed - number of function evaluations or grid points · precision or "smart" meshes with lower order routines Kristjan Haule, 2006 ­1­ #12;KH Computational Physics- 2006

  12. Supporting Advanced Scientific Computing Research Basic Energy Sciences Biological

    E-Print Network [OSTI]

    Supporting Advanced Scientific Computing Research · Basic Energy Sciences · Biological and Environmental Research · Fusion Energy Sciences · High Energy Physics · Nuclear Physics What my students Code ­http://code.google.com/p/net-almanac/ ­Beta release this week #12;Contact Information Jon Dugan

  13. basic student budget 2014 |2015 LIVING ON CAMPUS

    E-Print Network [OSTI]

    Painter, Kevin

    basic student budget 2014 |2015 #12;LIVING ON CAMPUS HALL FEES £ 119.18 ­ average cost x 40 weeks at £119.18 per week, and may be cheaper depending on type of accommodation. This budget is meant months (whether you live in the flat over the summer or not). This budget is meant as a realistic guide

  14. Tutorial on seismic interferometry: Part 1 --Basic principles and applications

    E-Print Network [OSTI]

    Snieder, Roel

    Tutorial on seismic interferometry: Part 1 -- Basic principles and applications Kees Wapenaar1 , Deyan Draganov1 , Roel Snieder2 , Xander Campman3 , and Arie Verdel3 ABSTRACT Seismic interferometry is the retrieval of seismic surface-wave responses from ambient noise and the subsequent tomographic determination

  15. Process Hijacking Process checkpointing is a basic mechanism required for

    E-Print Network [OSTI]

    Wisconsin at Madison, University of

    Process Hijacking Abstract Process checkpointing is a basic mechanism required for providing High Throughput Computing service on distributively owned resources. We present a new process checkpoint and migration technique, called process hijacking, that uses dynamic program re­writing techniques to add

  16. Process Hijacking Process checkpointing is a basic mechanism required for

    E-Print Network [OSTI]

    Miller, Barton P.

    Process Hijacking Abstract Process checkpointing is a basic mechanism required for providing High Throughput Computing service on distributively owned resources. We present a new process checkpoint and migration technique, called process hijacking, that uses dynamic program re-writing techniques to add

  17. Prospects for future projections of the basic energy sources in Turkey

    SciTech Connect (OSTI)

    Sozen, A.; Arcaklioglu, E. [Gazi University, Ankara (Turkey). Technical Education Facility

    2007-07-01T23:59:59.000Z

    The main goal of this study is to develop the energy sources estimation equations in order to estimate the future projections and make correct investments in Turkey using artificial neural network (ANN) approach. It is also expected that this study will be helpful in demonstrating energy situation of Turkey in amount of EU countries. Basic energy indicators such as population, gross generation, installed capacity, net energy consumption, import, export are used in input layer of ANN. Basic energy sources such as coal, lignite, fuel-oil, natural gas and hydro are in output layer. Data from 1975 to 2003 are used to train. Three years (1981, 1994 and 2003) are only used as test data to confirm this method. Also, in this study, the best approach was investigated for each energy sources by using different learning algorithms (scaled conjugate gradient (SCG) and Levenberg-Marquardt (LM)) and a logistic sigmoid transfer function in the ANN with developed software. The statistical coefficients of multiple determinations (R{sup 2}-value) for training data are equal to 0.99802, 0.99918, 0.997134, 0.998831 and 0.995681 for natural gas, lignite, coal, hydraulic, and fuel-oil, respectively. Similarly, these values for testing data are equal to 0.995623, 0.999456, 0.998545, 0.999236, and 0.99002. The best approach was found for lignite by SCG algorithm with seven neurons so mean absolute percentage error (MAPE) is equal to 1.646753 for lignite. According to the results, the future projections of energy indicators using ANN technique have been obviously predicted within acceptable errors. Apart from reducing the whole time required, the importance of the ANN approach is possible to find solutions that make energy applications more viable and thus more attractive to potential users.

  18. Direct tuyere injection of oxygen for enhanced coal combustion

    SciTech Connect (OSTI)

    Riley, M.F. [Praxair, Inc., Tarrytown, NY (United States)

    1996-12-31T23:59:59.000Z

    Injecting oxygen directly into the tuyere blowpipe can enhance the ignition and combustion of injected pulverized coal, allowing the efficient use of higher coal rates at high furnace production levels. The effects of direct oxygen injection have been estimated from an analysis of the factors controlling the dispersion, heating, ignition, and combustion of injected coal. Injecting ambient temperature oxygen offers mechanical improvements in the dispersion of coal but provides little thermochemical benefit over increased blast enrichment. Injecting hot oxygen through a novel, patented thermal nozzle lance offers both mechanical and thermochemical benefits over increased enrichment or ambient oxygen injection. Plans for pilot-scale and commercial-scale testing of this new lance are described.

  19. HERSCHEL MEASUREMENTS OF MOLECULAR OXYGEN IN ORION

    SciTech Connect (OSTI)

    Goldsmith, Paul F.; Chen, Jo-Hsin; Li Di [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Liseau, Rene; Black, John H. [Department of Earth and Space Sciences, Chalmers University of Technology, Onsala Space Observatory, SE-439 92 Onsala (Sweden); Bell, Tom A. [Centro de Astrobiologia, CSIC-INTA, 28850 Madrid (Spain); Hollenbach, David [SETI Institute, Mountain View, CA 94043 (United States); Kaufman, Michael J. [Department of Physics and Astronomy, San Jose State University, San Jose, CA 95192 (United States); Lis, Dariusz C. [California Institute of Technology, Cahill Center for Astronomy and Astrophysics 301-17, Pasadena, CA 91125 (United States); Melnick, Gary [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, MS 66, Cambridge, MA 02138 (United States); Neufeld, David [Department of Physics and Astronomy, Johns Hopkins University, 3400 North Charles Street, Baltimore, MD 21218 (United States); Pagani, Laurent; Encrenaz, Pierre [LERMA and UMR8112 du CNRS, Observatoire de Paris, 61 Av. de l'Observatoire, 75014 Paris (France); Snell, Ronald [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States); Benz, Arnold O.; Bruderer, Simon [Institute of Astronomy, ETH Zurich, Zurich (Switzerland); Bergin, Edwin [Department of Astronomy, University of Michigan, 500 Church Street, Ann Arbor, MI 48109 (United States); Caselli, Paola [School of Physics and Astronomy, University of Leeds, Leeds (United Kingdom); Caux, Emmanuel [Universite de Toulouse, UPS-OMP, IRAP, Toulouse (France); Falgarone, Edith, E-mail: Paul.F.Goldsmith@jpl.nasa.gov [LRA/LERMA, CNRS, UMR8112, Observatoire de Paris and Ecole Normale Superieure, 24 rue Lhomond, 75231 Paris Cedex 05 (France)

    2011-08-20T23:59:59.000Z

    We report observations of three rotational transitions of molecular oxygen (O{sub 2}) in emission from the H{sub 2} Peak 1 position of vibrationally excited molecular hydrogen in Orion. We observed the 487 GHz, 774 GHz, and 1121 GHz lines using the Heterodyne Instrument for the Far Infrared on the Herschel Space Observatory, having velocities of 11 km s{sup -1} to 12 km s{sup -1} and widths of 3 km s{sup -1}. The beam-averaged column density is N(O{sub 2}) = 6.5 x 10{sup 16} cm{sup -2}, and assuming that the source has an equal beam-filling factor for all transitions (beam widths 44, 28, and 19''), the relative line intensities imply a kinetic temperature between 65 K and 120 K. The fractional abundance of O{sub 2} relative to H{sub 2} is (0.3-7.3) x 10{sup -6}. The unusual velocity suggests an association with a {approx}5'' diameter source, denoted Peak A, the Western Clump, or MF4. The mass of this source is {approx}10 M{sub sun} and the dust temperature is {>=}150 K. Our preferred explanation of the enhanced O{sub 2} abundance is that dust grains in this region are sufficiently warm (T {>=} 100 K) to desorb water ice and thus keep a significant fraction of elemental oxygen in the gas phase, with a significant fraction as O{sub 2}. For this small source, the line ratios require a temperature {>=}180 K. The inferred O{sub 2} column density {approx_equal}5 x 10{sup 18} cm{sup -2} can be produced in Peak A, having N(H{sub 2}) {approx_equal} 4 x 10{sup 24} cm{sup -2}. An alternative mechanism is a low-velocity (10-15 km s{sup -1}) C-shock, which can produce N(O{sub 2}) up to 10{sup 17} cm{sup -2}.

  20. Faraday Discuss., 1997, 108, 115130 Excited state dynamics in clusters of oxygen

    E-Print Network [OSTI]

    Continetti, Robert E.

    Faraday Discuss., 1997, 108, 115È130 Excited state dynamics in clusters of oxygen Runjun Li, Karl A clusters of oxygen. Oxygen clusters and liquid oxygen have a com- plicated chemistry due to numerous low) dynamics of small anionic clusters of oxygen. We Ðnd that the dynamics of the neutral DPD pathway

  1. Normal muscle oxygen consumption and fatigability in sickle cell patients despite reduced microvascular oxygenation and hemorheological abnormalities

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    sickle cell anemia (SS) patients. Results: Muscle microvascular oxygenation was reduced in SS patients;4 Introduction Patients with sickle cell disease (SCD) are characterized by anemia and altered blood rheology1 Normal muscle oxygen consumption and fatigability in sickle cell patients despite reduced

  2. Dispersoid reinforced alloy powder and method of making

    DOE Patents [OSTI]

    Anderson, Iver E; Rieken, Joel

    2013-12-10T23:59:59.000Z

    A method of making dispersion-strengthened alloy particles involves melting an alloy having a corrosion and/or oxidation resistance-imparting alloying element, a dispersoid-forming element, and a matrix metal wherein the dispersoid-forming element exhibits a greater tendency to react with an introduced reactive species than does the alloying element and wherein one or more atomizing parameters is/are modified to controllably reduce the amount of the reactive species, such as oxygen, introduced into the atomized particles so as to reduce anneal times and improve reaction (conversion) to the desired strengthening dispersoids in the matrix. The atomized alloy particles are solidified as solidified alloy particles or as a solidified deposit of alloy particles. Bodies are made from the dispersion strengthened alloy particles, deposit thereof, exhibit enhanced fatigue and creep resistance and reduced wear as well as enhanced corrosion and/or oxidation resistance at high temperatures by virtue of the presence of the corrosion and/or oxidation resistance imparting alloying element in solid solution in the particle alloy matrix.

  3. Evidence-based Decision Making: Influences on Central-Office Administrators' Decision-Making Practices

    E-Print Network [OSTI]

    Haecker, Bonnie Minnia

    2013-12-05T23:59:59.000Z

    administrators across the state of Texas were surveyed to obtain information about their evidence-based decision-making practices and the factors that influenced them when making decisions about interventions for their districts. The purpose...

  4. Oxygen Modulation via Microfluidic Devices Oxygen is a key but under-studied metabolic variable. It influences biological phenomena as diverse as

    E-Print Network [OSTI]

    Ben-Arie, Jezekiel

    Oxygen Modulation via Microfluidic Devices Oxygen is a key but under-studied metabolic variable methods to modulate oxygen are crude and inefficient. Our lab has developed a suite of devices which can rapidly alter oxygen conditions surrounding cells in both position and time.[1-3]. Moreover, because

  5. Oxygen diffusion, surface exchange and oxygen semi-permeation performances of Ln2NiO4+ membranes (Ln = La, Pr and Nd)

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Oxygen diffusion, surface exchange and oxygen semi-permeation performances of Ln2NiO4+ membranes the rate determining step (rds) in oxygen semi-permeation of dense Ln2NiO4+ membranes (with Ln = La, Pr and Nd), a specific setup has been designed, which allowed measuring the oxygen semi-permeation flux

  6. Impact of oxygenates on petroleum refining

    SciTech Connect (OSTI)

    Unzelman, G.H. [HyOx Inc., Fallbrook, CA (United States)

    1995-05-01T23:59:59.000Z

    The concept of an oxygenate, primarily ethanol, as motor fuel or as a blending agent with gasoline has been around for a long time. The idea started with the development of the internal combustion engine. Experiments in Germany almost 100 years ago. The inventor of the four-stroke-cycle combustion engine, Nikolaus Otto, originally recommended ethyl alcohol as fuel. So did Henry Ford early in his career as an automobile manufacturer. However, gasoline was readily available from crude oil at a time when the kerosene market was fading. Since it was the lowest-cost approach to satisfy a growing market, the idea of alcohol as a primary fuel was set aside. Early gasoline was simply distilled from the {open_quotes}top of the barrel.{close_quotes} While it was satisfactory for the {open_quotes}horseless carriage,{close_quotes} quality was insufficient for innovations such as higher-compression engines. Knock became a serious problem, which prompted research and the discovery of tetraethyllead as an octane improver. Had this event not taken place, the alcohols probably would have been alternatives to solve the antiknock dilemma. Instead, it took another 60 years for the octane value of alcohols and ethers to resurface and exert a commercial impact on gasoline.

  7. Nanoparticulate-catalyzed oxygen transfer processes

    DOE Patents [OSTI]

    Hunt, Andrew T. (Atlanta, GA); Breitkopf, Richard C. (Dunwoody, GA)

    2009-12-01T23:59:59.000Z

    Nanoparticulates of oxygen transfer materials that are oxides of rare earth metals, combinations of rare earth metals, and combinations of transition metals and rare earth metals are used as catalysts in a variety of processes. Unexpectedly large thermal efficiencies are achieved relative to micron sized particulates. Processes that use these catalysts are exemplified in a multistage reactor. The exemplified reactor cracks C6 to C20 hydrocarbons, desulfurizes the hydrocarbon stream and reforms the hydrocarbons in the stream to produce hydrogen. In a first reactor stage the steam and hydrocarbon are passed through particulate mixed rare earth metal oxide to crack larger hydrocarbon molecules. In a second stage, the steam and hydrocarbon are passed through particulate material that desulfurizes the hydrocarbon. In a third stage, the hydrocarbon and steam are passed through a heated, mixed transition metal/rare earth metal oxide to reform the lower hydrocarbons and thereby produce hydrogen. Stages can be alone or combined. Parallel reactors can provide continuous reactant flow. Each of the processes can be carried out individually.

  8. Making the most of Responsive Electricity Customer. Energy Efficiency...

    Broader source: Energy.gov (indexed) [DOE]

    Making the most of Responsive Electricity Customer. Energy Efficiency and Demand Response: How do we make the most out of using less energy? Making the most of Responsive...

  9. Decision making process and factors routing

    E-Print Network [OSTI]

    Sun, Yichen, S.M. Massachusetts Institute of Technology

    2013-01-01T23:59:59.000Z

    This research studies the decision-making process and the factors that affect truck routing. The data collection involved intercept interviews with truck drivers at three rest area and truck stops along major highways in ...

  10. Rock Slopes from Mechanics to Decision Making

    E-Print Network [OSTI]

    Einstein, Herbert H.

    Rock slope instabilities are discussed in the context of decision making for risk assessment and management. Hence, the state of the slope and possible failure mechanism need to be defined first. This is done with geometrical ...

  11. Going To Work: Make a Good Impression

    E-Print Network [OSTI]

    Hoffman, Rosemarie

    2000-01-07T23:59:59.000Z

    Edited by Rosemarie Hoffman Assistant Professor and Extension Individual and Family Development Specialist, The Texas A&M University System L-2364 12-99 Make a Good Impression Y our goals, self-image, personality, attitude, cleanliness and concern...

  12. Method for making spherical binderless pellets

    DOE Patents [OSTI]

    Grubbs, Donald K. (Rector, PA); Kochanowski, Andrew T. (Spring Church, PA)

    1983-01-01T23:59:59.000Z

    A method for making spherical binderless pellets using a rotating drum mixer whereby at least a portion of the particles comprising the pellets is comprised of coking coal particles.

  13. Experiments on decision making and auctions

    E-Print Network [OSTI]

    Watson, Elizabeth Ann

    2009-06-02T23:59:59.000Z

    with the idea of making the priceprobability tradeoff, the central consideration in auctions, more salient to subjects. I approach this in two different ways. First, I use a customdesigned graphical interface which displays all results both visually...

  14. Flammability of selected heat resistant alloys in oxygen gas mixtures

    SciTech Connect (OSTI)

    Zawierucha, R.; McIlroy, K.; Million, J.F. [Praxair, Inc., Tonawanda, NY (United States)

    1995-12-31T23:59:59.000Z

    Within recent years, the use of oxygen has increased in applications where elevated temperatures and corrosion may be significant factors. In such situations, traditional alloys used in oxygen systems will not be adequate. Where alternative alloys must be utilized, based upon environmental requirements, it is essential that they may be characterized with respect to their ignition and combustion resistance in oxygen. Promoted ignition and promoted ignition-combustion are terms which have been used to describe a situation where a substance with low oxygen supports the combustion of a compatibility ignites and more ignition resistant material. In this paper, data will be presented on the promoted ignition-combustion behavior of selected heat resistant engineering alloys that may be considered for gaseous oxygen applications in severe environments. In this investigation, alloys have been evaluated via both flowing and static (fixed volume) approaches using a rod configuration. Oxygen-nitrogen gas mixtures with compositions ranging from approximately 40 to 99.7% oxygen at pressures of 3.55 to 34.6 MPa were used in the comparative studies.

  15. Measuring oxygen reduction/evolution reactions on the nanoscale

    SciTech Connect (OSTI)

    Kalinin, Sergei V [ORNL; Jesse, Stephen [ORNL; Kumar, Amit [ORNL; Morozovska, A. N. [National Academy of Science of Ukraine, Kiev, Ukraine; Ciucci, Francesco [Harvard-Smithsonian Center for Astrophysics

    2011-01-01T23:59:59.000Z

    The efficiency of fuel cells and metal-air batteries is significantly limited by the activation of oxygen reduction and evolution reactions (ORR/OER). Despite the well-recognized role of oxygen reaction kinetics on the viability of energy technologies, the governing mechanisms remain elusive and until now addressable only by macroscopic studies. This lack of nanoscale understanding precludes optimization of material architecture. Here we report direct measurements of oxygen reduction/evolution reactions and oxygen vacancy diffusion on oxygen-ion conductive solid surfaces with sub-10 nanometer resolution. In electrochemical strain microscopy (ESM), the biased scanning probe microscopy tip acts as a moving, electrocatalytically active probe exploring local electrochemical activity. The probe concentrates an electric field in a nanometer-scale volume of material, and bias-induced, picometer-level surface displacements provide information on local electrochemical processes. Systematic mapping of oxygen activity on bare and Pt-functionalized yttria-stabilized zirconia (YSZ) surfaces is demonstrated. This approach allows directly visualization of ORR/OER activation process at the triple-phase boundary, and can be extended to broad spectrum of oxygen-conductive and electrocatalytic materials.

  16. Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Nitrated and oxygenated derivatives of polycyclic aromatic hydrocarbons in the ambient air of two aromatic hydrocarbons, 17 nitrated PAHs (NPAHs) and 8 oxygenated PAHs (OPAHs) were carried out during hydrocarbons; Nitrated polycyclic aromatic hydrocarbons; Oxygenated polycyclic aromatic hydrocarbons

  17. Atomic oxygen flux determined by mixed-phase Ag/Ag2O deposition...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    oxygen flux determined by mixed-phase AgAg2O deposition. Atomic oxygen flux determined by mixed-phase AgAg2O deposition. Abstract: The flux of atomic oxygen generated in a...

  18. Oxygen Loss from Venus and the Influence of Extreme Solar Wind Conditions

    E-Print Network [OSTI]

    McEnulty, Tess

    2012-01-01T23:59:59.000Z

    and I. Sillanpää (2009), Oxygen ion escape from Venus in aobservations of atmospheric oxygen escape during the passageI. F. Stewart (1981), Hot oxygen BIBLIOGRAPHY atoms in the

  19. Seasonal and interannual oxygen variability on the Washington and Oregon continental shelves

    E-Print Network [OSTI]

    2015-01-01T23:59:59.000Z

    A. Pe~ na (2013), Declining oxygen on the British ColumbiaE. , and L. I. Gordon (1992), Oxygen solubility in seawater:10.1002/2014JC010254 Key Points: Oxygen model presented for

  20. Triple Oxygen Isotope Measurement of Nitrate to Analyze Impact of Aircraft Emissions

    E-Print Network [OSTI]

    Chan, Sharleen

    P. ; Craig, H. Atmospheric oxygen: isotopic composition andM.H. 1986. A non-mass-dependent oxygen isotope effect in theof ozone from molecular oxygen: the role of symmetry in

  1. Deadlock Detection in Basic Models of MPI Synchronization Communication Programs

    E-Print Network [OSTI]

    Liao, Ming-xue

    2007-01-01T23:59:59.000Z

    A model of MPI synchronization communication programs is presented and its three basic simplified models are also defined. A series of theorems and methods for deciding whether deadlocks will occur among the three models are given and proved strictly. These theories and methods for simple models' deadlock detection are the necessary base for real MPI program deadlock detection. The methods are based on a static analysis through programs and with runtime detection in necessary cases and they are able to determine before compiling whether it will be deadlocked for two of the three basic models. For another model, some deadlock cases can be found before compiling and others at runtime. Our theorems can be used to prove the correctness of currently popular MPI program deadlock detection algorithms. Our methods may decrease codes that those algorithms need to change to MPI source or profiling interface and may detects deadlocks ahead of program execution, thus the overheads can be reduced greatly.

  2. Solid phases of spatially nanoconfined oxygen: A neutron scattering study

    SciTech Connect (OSTI)

    Kojda, Danny [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany) [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany); Freie Universität Berlin, 14195 Berlin (Germany); Wallacher, Dirk; Hofmann, Tommy, E-mail: tommy.hofmann@helmholtz-berlin.de [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany)] [Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, 14109 Berlin (Germany); Baudoin, Simon; Hansen, Thomas [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France)] [Institut Laue-Langevin, BP 156, 38042 Grenoble Cedex 9 (France); Huber, Patrick [Technische Universität Hamburg-Harburg, 21073 Hamburg (Germany)] [Technische Universität Hamburg-Harburg, 21073 Hamburg (Germany)

    2014-01-14T23:59:59.000Z

    We present a comprehensive neutron scattering study on solid oxygen spatially confined in 12 nm wide alumina nanochannels. Elastic scattering experiments reveal a structural phase sequence known from bulk oxygen. With decreasing temperature cubic ?-, orthorhombic ?- and monoclinic ?-phases are unambiguously identified in confinement. Weak antiferromagnetic ordering is observed in the confined monoclinic ?-phase. Rocking scans reveal that oxygen nanocrystals inside the tubular channels do not form an isotropic powder. Rather, they exhibit preferred orientations depending on thermal history and the very mechanisms, which guide the structural transitions.

  3. Hydrogen Production Using Hydrogenase-Containing Oxygenic Photosynthetic Organisms

    DOE Patents [OSTI]

    Melis, A.; Zhang, L.; Benemann, J. R.; Forestier, M.; Ghirardi, M.; Seibert, M.

    2006-01-24T23:59:59.000Z

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  4. Boron nitride nanosheets as oxygen-atom corrosion protective coatings

    SciTech Connect (OSTI)

    Yi, Min [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Shen, Zhigang, E-mail: shenzhg@buaa.edu.cn [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); School of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Zhao, Xiaohu [Plasma Laboratory, Ministry-of-Education Key Laboratory of Fluid Mechanics, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Liang, Shuaishuai [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); Liu, Lei [Beijing Key Laboratory for Powder Technology Research and Development, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China); School of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, Beijing 100191 (China)

    2014-04-07T23:59:59.000Z

    The research of two-dimensional nanomaterials for anticorrosion applications is just recently burgeoning. Herein, we demonstrate the boron nitride nanosheets (BNNSs) coatings for protecting polymer from oxygen-atom corrosion. High-quality BNNSs, which are produced by an effective fluid dynamics method with multiple exfoliation mechanisms, can be assembled into coatings with controlled thickness by vacuum filtration. After exposed in atom oxygen, the naked polymer is severely corroded with remarkable mass loss, while the BNNSs-coated polymer remains intact. Barrier and bonding effects of the BNNSs are responsible for the coating's protective performance. These preliminary yet reproducible results pave a way for resisting oxygen-atom corrosion.

  5. Production of Ultra-Cold-Neutrons in Solid ?-Oxygen

    E-Print Network [OSTI]

    E. Gutsmiedl; A. Frei; F. Boehle; A. Maier; S. Paul; H. Schober; A. Orecchini

    2010-07-30T23:59:59.000Z

    Our recent neutron scattering measurements of phonons and magnons in solid \\alpha-oxygen have led us to a new understanding of the production mechanismen of ultra-cold-neutrons (UCN) in this super-thermal converter. The UCN production in solid \\alpha-oxygen is dominated by the excitation of phonons. The contribution of magnons to UCN production becomes only slightly important above E >10 meV and at E >4 meV. Solid \\alpha-oxygen is in comparison to solid deuterium less effcient in the down-scattering of thermal or cold neutrons into the UCN energy regime.

  6. THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-01T23:59:59.000Z

    At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

  7. Hydrogen production using hydrogenase-containing oxygenic photosynthetic organisms

    DOE Patents [OSTI]

    Melis, Anastasios; Zhang, Liping; Benemann, John R.; Forestier, Marc; Ghirardi, Maria; Seibert, Michael

    2006-01-24T23:59:59.000Z

    A reversible physiological process provides for the temporal separation of oxygen evolution and hydrogen production in a microorganism, which includes the steps of growing a culture of the microorganism in medium under illuminated conditions to accumulate an endogenous substrate, depleting from the medium a nutrient selected from the group consisting of sulfur, iron, and/or manganese, sealing the culture from atmospheric oxygen, incubating the culture in light whereby a rate of light-induced oxygen production is equal to or less than a rate of respiration, and collecting an evolved gas. The process is particularly useful to accomplish a sustained photobiological hydrogen gas production in cultures of microorganisms, such as Chlamydomonas reinhardtii.

  8. A basic result on the integral for birthdeath Markov processes

    E-Print Network [OSTI]

    in changing the death rate or state n, ¯ n , from n¯ to (n \\Gamma 1)¯. The other approximation consists(t) be a birth­death process on a subset of N = 0; 1;2; :::, with birth and death rates â?? i ; and ¯ iA basic result on the integral for birth­death Markov processes Carlos M. Hern'andez­Su'arez CGIC

  9. Space Heating and Cooling Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterEnergyGlossaryProgramRussiaSpace Heating and Cooling Basics Space

  10. Influence of geometry on liquid oxygen magnetohydrodynamics

    SciTech Connect (OSTI)

    Boulware, Jeffrey C.; Ban, Heng [Department of Mechanical and Aerospace Engineering, Utah State University, 4130 Old Main Hill, Logan, UT 84322-4130 (United States); Jensen, Scott; Wassom, Steve [Space Dynamics Laboratory, Utah State University Research Foundation, 1695 North Research Park Way, North Logan, UT 84341 (United States)

    2010-11-15T23:59:59.000Z

    Magnetic fluid actuators have performed well in industrial applications, but have a limited temperature range due to the freezing point of the carrier fluid. Liquid oxygen (LOX) presents a pure, paramagnetic fluid suitable for use in a cryogenic magnetic fluid system; therefore, it is a potential solution to increasing the thermal range of magnetic fluid technology without the need for magnetic particles. The current study presents experimental work regarding the influence of geometry on the dynamics of a LOX slug in a 1.9 mm quartz tube when pulsed by a solenoid in a closed volume. A numerical analysis calculated the optimal solenoid geometry and balanced the magnetic, damping, and pressure forces to determine optimal slug lengths. Three configurations comprised the experiment: (1) a 24-gauge wire solenoid with an optimized 2.7 cm length slug, (2) a 30-gauge wire solenoid with an optimized 1.3 cm length slug, and (3) a 30-gauge wire solenoid with a nonoptimized 2.5 cm length slug. Typically, the hydrodynamic breakdown limit is calculated and used to determine the system range; however the experiment showed that the hydrodynamic breakdown limit was never reached by the slug. This implied that, instead, the system range should factor in a probabilistic risk of failure calculated as a function of the induced pressure change from its oscillations. The experimental data were also used to establish a nondimensional relationship between the maximum displacement and initial magnetic pressure on the slug. The average initial velocity of the slug was found to be proportional to the initial magnetic pressure, Mason number, and slug length. The results of this study can be used in the design and optimization of a LOX fluid system for space or low-temperature applications. (author)

  11. Oxidized film structure and method of making epitaxial metal oxide structure

    DOE Patents [OSTI]

    Gan, Shupan [Richland, WA; Liang, Yong [Richland, WA

    2003-02-25T23:59:59.000Z

    A stable oxidized structure and an improved method of making such a structure, including an improved method of making an interfacial template for growing a crystalline metal oxide structure, are disclosed. The improved method comprises the steps of providing a substrate with a clean surface and depositing a metal on the surface at a high temperature under a vacuum to form a metal-substrate compound layer on the surface with a thickness of less than one monolayer. The compound layer is then oxidized by exposing the compound layer to essentially oxygen at a low partial pressure and low temperature. The method may further comprise the step of annealing the surface while under a vacuum to further stabilize the oxidized film structure. A crystalline metal oxide structure may be subsequently epitaxially grown by using the oxidized film structure as an interfacial template and depositing on the interfacial template at least one layer of a crystalline metal oxide.

  12. Oxygen enriched combustion system performance study. Phase 2: 100 percent oxygen enriched combustion in regenerative glass melters, Final report

    SciTech Connect (OSTI)

    Tuson, G.B.; Kobayashi, H.; Campbell, M.J.

    1994-08-01T23:59:59.000Z

    The field test project described in this report was conducted to evaluate the energy and environmental performance of 100% oxygen enriched combustion (100% OEC) in regenerative glass melters. Additional objectives were to determine other impacts of 100% OEC on melter operation and glass quality, and to verify on a commercial scale that an on-site Pressure Swing Adsorption oxygen plant can reliably supply oxygen for glass melting with low electrical power consumption. The tests constituted Phase 2 of a cooperative project between the United States Department of Energy, and Praxair, Inc. Phase 1 of the project involved market and technical feasibility assessments of oxygen enriched combustion for a range of high temperature industrial heating applications. An assessment of oxygen supply options for these applications was also performed during Phase 1, which included performance evaluation of a pilot scale 1 ton per day PSA oxygen plant. Two regenerative container glass melters were converted to 100% OEC operation and served as host sites for Phase 2. A 75 ton per day end-fired melter at Carr-Lowrey Glass Company in Baltimore, Maryland, was temporarily converted to 100% OEC in mid- 1990. A 350 tpd cross-fired melter at Gallo Glass Company in Modesto, California was rebuilt for permanent commercial operation with 100% OEC in mid-1991. Initially, both of these melters were supplied with oxygen from liquid storage. Subsequently, in late 1992, a Pressure Swing Adsorption oxygen plant was installed at Gallo to supply oxygen for 100% OEC glass melting. The particular PSA plant design used at Gallo achieves maximum efficiency by cycling the adsorbent beds between pressurized and evacuated states, and is therefore referred to as a Vacuum/Pressure Swing Adsorption (VPSA) plant.

  13. Microfluidic advantage : novel techniques for protein folding and oxygen control in cell cultures

    E-Print Network [OSTI]

    Polinkovsky, Mark E.; Polinkovsky, Mark E.

    2012-01-01T23:59:59.000Z

    Novel Techniques for Protein Folding and Oxygen Control inTemperature Jump System to Study Fast Protein FoldingNovel Techniques for Protein Folding and Oxygen Control in

  14. Aging Enhances the Production of Reactive Oxygen Species andBactericid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhances the Production of Reactive Oxygen Species andBactericidal Activity in Peritoneal Macrophages by Aging Enhances the Production of Reactive Oxygen Species andBactericidal...

  15. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

  16. Low-Oxygen Induction of Normally Cryptic psbA Genes in Cyanobacteria...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oxygen Induction of Normally Cryptic psbA Genes in Cyanobacteria. Low-Oxygen Induction of Normally Cryptic psbA Genes in Cyanobacteria. Abstract: Microarray analysis indicated...

  17. A method of determining the dissolved oxygen in the moisture of a porous medium and some oxygen diffusion studies

    E-Print Network [OSTI]

    Runkles, Jack Ralph

    1952-01-01T23:59:59.000Z

    this dissolved oxygen The sample chamber apparatus gives ocnsplcte seal of the bottle from the atmosphere The ohsabor does not require a large ameunt Of nitrogen Sb remove all the oxygen from it, It is easily portable and light in weight The proposed method... METHOD QF DETRHRIUIHO THE DISSOLVED OXmEK IE THE MOISTURE OF A POROUS ERDD% @AD SMfE QXYOEB DKFFUSIOE STUDIES ' INTRO DUO fQRF, I Oxygen, bas been known to be important in plant growth fox maay years There has been a great deal of xesearoh...

  18. D0 Detector Collision Hall Oxygen Deficiancy Hazard Analysis

    SciTech Connect (OSTI)

    Wu, J.; /Fermilab

    1992-08-06T23:59:59.000Z

    EN-258, D0 Platform ODH Analysts. provided the oxygen deficiency hazard analysts for the D0 detector in the Assembly Hall. This note covers the same analysis. but revised for the Collision Hall. Liquid cryogens. released and warming to atmosphere conditions, expand to, on average, seven hundred times their liquid volume, and displace vital atmospheric oxygen. An oxygen deficiency hazard analysis assesses the increased risk to personnel in areas containing cryogenic systems. The D0 detector Collision Hall ODH analysis has been approached five different ways using established methods. If the low beta quad magnets are powered, and the exhaust rate is below 4220 scfm, the area is ODH class 1. In any other case, the analysis shows the area to be ODH class 0 as equipped (with ventilation fans) and requiring no special safety provisions. System designers have provided for a reduced oxygen level detection and warning system as well as emergency procedures to address fault conditions.

  19. Hybrid membrane--PSA system for separating oxygen from air

    DOE Patents [OSTI]

    Staiger, Chad L. (Albuquerque, NM); Vaughn, Mark R. (Albuquerque, NM); Miller, A. Keith (Albuquerque, NM); Cornelius, Christopher J. (Blackburg, VA)

    2011-01-25T23:59:59.000Z

    A portable, non-cryogenic, oxygen generation system capable of delivering oxygen gas at purities greater than 98% and flow rates of 15 L/min or more is described. The system consists of two major components. The first component is a high efficiency membrane capable of separating argon and a portion of the nitrogen content from air, yielding an oxygen-enriched permeate flow. This is then fed to the second component, a pressure swing adsorption (PSA) unit utilizing a commercially available, but specifically formulated zeolite compound to remove the remainder of the nitrogen from the flow. The system is a unique gas separation system that can operate at ambient temperatures, for producing high purity oxygen for various applications (medical, refining, chemical production, enhanced combustion, fuel cells, etc . . . ) and represents a significant advance compared to current technologies.

  20. atmospheric oxygen concentration: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: can be combined into a tracer known as atmospheric potential oxygen (APO % O2N2 + CO2) that is conservative with respect to terrestrial biological activity....