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Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Nuclear magnetic resonance apparatus having semitoroidal rf coil for use in topical NMR and NMR imaging  

DOE Patents [OSTI]

An improved nuclear magnetic resonance (NMR) apparatus for use in topical magnetic resonance (TMR) spectroscopy and other remote sensing NMR applications includes a semitoroidal radio-frequency (rf) coil. The semitoroidal rf coil produces an effective alternating magnetic field at a distance from the poles of the coil, so as to enable NMR measurements to be taken from selected regions inside an object, particularly including human and other living subjects. The semitoroidal rf coil is relatively insensitive to magnetic interference from metallic objects located behind the coil, thereby rendering the coil particularly suited for use in both conventional and superconducting NMR magnets. The semitoroidal NMR coil can be constructed so that it emits little or no excess rf electric field associated with the rf magnetic field, thus avoiding adverse effects due to dielectric heating of the sample or to any other interaction of the electric field with the sample.

Fukushima, Eiichi (Los Alamos, NM); Roeder, Stephen B. W. (La Mesa, CA); Assink, Roger A. (Albuquerque, NM); Gibson, Atholl A. V. (Bryan, TX)

1986-01-01T23:59:59.000Z

2

Nuclear Magnetic Resonance (NMR) is the only logging technique available to estimate pore-size  

E-Print Network [OSTI]

1 ABSTRACT Nuclear Magnetic Resonance (NMR) is the only logging technique available to estimate, Nuclear Magnetic Resonance (NMR) logging has been used to assess a handful of key petrophysical parameters

Torres-Verdín, Carlos

3

Superconducting Magnet Safety Nuclear Magnetic Resonance (NMR) facilities present unique hazards not found in most  

E-Print Network [OSTI]

Superconducting Magnet Safety Nuclear Magnetic Resonance (NMR) facilities present unique hazards not found in most laboratory environments. The NMR facilities maintain superconducting magnets which have for asphyxiation. Once energized the field of the superconducting magnet of the spectrometer is always present

Maroncelli, Mark

4

Improved nuclear magnetic resonance apparatus having semitoroidal rf coil for use in topical NMR and NMR imaging  

DOE Patents [OSTI]

An improved nuclear magnetic resonance (NMR) apparatus for use in topical magnetic resonance (TMR) spectroscopy and other remote sensing NMR applications includes a semitoroidal radio frequency (rf) coil. The semitoroidal rf coil produces an effective alternating magnetic field at a distance from the poles of the coil, so as to enable NMR measurements to be taken from selected regions inside an object, particularly including human and other living subjects. The semitoroidal rf coil is relatively insensitive to magnetic interference from metallic objects located behind the coil, thereby rendering the coil particularly suited for use in both conventional and superconducting NMR magnets. The semitoroidal NMR coil can be constructed so that it emits little or no excess rf electric field associated with the rf magnetic field, thus avoiding adverse effects due to dielectric heating of the sample or to any other interaction of the electric field with the sample.

Fukushima, E.; Roeder, S.B.W.; Assink, R.A.; Gibson, A.A.V.

1984-01-01T23:59:59.000Z

5

Study of Brazilian Gasoline Quality Using Hydrogen Nuclear Magnetic Resonance (1H NMR) Spectroscopy and Chemometrics  

E-Print Network [OSTI]

Study of Brazilian Gasoline Quality Using Hydrogen Nuclear Magnetic Resonance (1H NMR) Spectroscopy The identification of gasoline adulteration by organic solvents is not an easy task, because compounds that constitute the solvents are already in gasoline composition. In this work, the use of hydrogen nuclear

Ferreira, Márcia M. C.

6

Nanodiamond graphitization: a magnetic resonance study  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

on the first nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR) study of the high-temperature nanodiamond-to-onion transformation. 1 H, 13 C NMR and...

7

Magnetic Resonance Facility (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet provides information about Magnetic Resonance Facility capabilities and applications at NREL's National Bioenergy Center. Liquid and solid-state analysis capability for a variety of biomass, photovoltaic, and materials characterization applications across NREL. NREL scientists analyze solid and liquid samples on three nuclear magnetic resonance (NMR) spectrometers as well as an electron paramagnetic resonance (EPR) spectrometer.

Not Available

2012-03-01T23:59:59.000Z

8

Unentangling nuclear magnetic resonance Matthias Bechmann 1  

E-Print Network [OSTI]

Unentangling nuclear magnetic resonance computing Matthias Bechmann 1 , John A. Clark 2 , Angelika of York, UK, YO10 5DD Abstract. Nuclear magnetic resonance (NMR) is typically thought of as a possible could be used to perform non-quantum computation: from addressable 3D memory, to a programmable 3D

Stepney, Susan

9

Pulsed Nuclear Magnetic Resonance: Spin Echoes MIT Department of Physics  

E-Print Network [OSTI]

Pulsed Nuclear Magnetic Resonance: Spin Echoes MIT Department of Physics (Dated: February 5, 2014) In this experiment, the phenomenon of Nuclear Magnetic Resonance (NMR) is used to determine the magnetic moments-factor in atomic spectroscopy and is given by g = (µ/µN )/I, (2) and µN is the nuclear magneton, e /2mp

Seager, Sara

10

Rotating-frame gradient fields for magnetic resonance imaging and nuclear magnetic resonance in low fields  

DOE Patents [OSTI]

A system and method for Fourier encoding a nuclear magnetic resonance (NMR) signal is disclosed. A static magnetic field B.sub.0 is provided along a first direction. An NMR signal from the sample is Fourier encoded by applying a rotating-frame gradient field B.sub.G superimposed on the B.sub.0, where the B.sub.G comprises a vector component rotating in a plane perpendicular to the first direction at an angular frequency .omega.in a laboratory frame. The Fourier-encoded NMR signal is detected.

Bouchard, Louis-Serge; Pines, Alexander; Demas, Vasiliki

2014-01-21T23:59:59.000Z

11

Nuclear Magnetic Resonance based Characterization of the Protein Binding Pocket using Hyperpolarized Ligand  

E-Print Network [OSTI]

Polarization (DNP) combined with Nuclear Magnetic Resonance (NMR) has emerged as a new tool for studying interactions between different molecules. In this study, the DNP-NMR technique was employed for characterization of the protein binding pocket through...

Min, Hlaing

2014-08-04T23:59:59.000Z

12

Chemometric Analysis of Nuclear Magnetic Resonance Spectroscopy Data  

SciTech Connect (OSTI)

Chemometric analysis of nuclear magnetic resonance (NMR) spectroscopy has increased dramatically in recent years. A variety of different chemometric techniques have been applied to a wide range of problems in food, agricultural, medical, process and industrial systems. This article gives a brief review of chemometric analysis of NMR spectral data, including a summary of the types of mixtures and experiments analyzed with chemometric techniques. Common experimental problems encountered during the chemometric analysis of NMR data are also discussed.

ALAM,TODD M.; ALAM,M. KATHLEEN

2000-07-20T23:59:59.000Z

13

Non-invasive NMR thermometry and temperature monitering using the proton resonance frequenccy method  

E-Print Network [OSTI]

of research for the Magnetic Resonance Systems Laboratory (MRSL). The theory and principles of the PRF method are thoroughly investigated. The 2.OT MRI system is tested for phase and temporal stability and is determined whether it is capable of accurate NMR...

Naphuket, Sood Ratanadilok

1997-01-01T23:59:59.000Z

14

Optically Enhanced Magnetic Resonance  

E-Print Network [OSTI]

, like spatial structures or molecular dynamics. While the direct excitation of nuclear spin transitions.1 Motivation The physical mechanism of nuclear magnetic resonance spectroscopy, the excitation of transitions light for polarizing the spin system or for observing its dynamics. This possibility arises from

Suter, Dieter

15

Distinguishing carbonate reservoir pore facies with nuclear magnetic resonance as an aid to identify candidates for acid stimulation  

E-Print Network [OSTI]

patterns. This study integrates data from thin sections and core analyses with measurements of Nuclear Magnetic Resonance (NMR) T2 relaxation times. It exposes a novel approach to the use of NMR by applying geological and statistical analysis to define...

Genty, Coralie

2006-10-30T23:59:59.000Z

16

Abstract-In this study, imaging of electrical current density in conducting objects, which contain nuclear magnetic resonance  

E-Print Network [OSTI]

nuclear magnetic resonance (NMR) active nuclei is planned using 0.15T Magnetic Resonance Imaging (MRI at each cycle within the object. The applied current pulse creates a measurable magnetic flux density. The component of magnetic flux density parallel to the main magnetic field accumulates an additional phase

Eybolu, Murat

17

Nuclear magnetic resonance readable sensors  

E-Print Network [OSTI]

The monitoring of physiological biomarkers is fundamental to the diagnosis and treatment of disease. We describe here the development of molecular sensors which can be read by magnetic resonance (MR) relaxometry. MR is an ...

Ling, Yibo

2010-01-01T23:59:59.000Z

18

Noble gas magnetic resonator  

DOE Patents [OSTI]

Precise measurements of a precessional rate of noble gas in a magnetic field is obtained by constraining the time averaged direction of the spins of a stimulating alkali gas to lie in a plane transverse to the magnetic field. In this way, the magnetic field of the alkali gas does not provide a net contribution to the precessional rate of the noble gas.

Walker, Thad Gilbert; Lancor, Brian Robert; Wyllie, Robert

2014-04-15T23:59:59.000Z

19

Ultra-low field nuclear magnetic resonance and magnetic resonance imaging to discriminate and identify materials  

DOE Patents [OSTI]

An ultra-low magnetic field NMR system can non-invasively examine containers. Database matching techniques can then identify hazardous materials within the containers. Ultra-low field NMR systems are ideal for this purpose because they do not require large powerful magnets and because they can examine materials enclosed in conductive shells such as lead shells. The NMR examination technique can be combined with ultra-low field NMR imaging, where an NMR image is obtained and analyzed to identify target volumes. Spatial sensitivity encoding can also be used to identify target volumes. After the target volumes are identified the NMR measurement technique can be used to identify their contents.

Kraus, Robert H. (Los Alamos, NM); Matlashov, Andrei N. (Los Alamos, NM); Espy, Michelle A. (Los Alamos, NM); Volegov, Petr L. (Los Alamos, NM)

2010-03-30T23:59:59.000Z

20

Chapter 20. Magnetic Resonance Imaging Magnetic Resonance Imaging  

E-Print Network [OSTI]

, and software training from Siemens Medical Solutions; research funding through the Siemens-MIT Alliance and Technology (HST). 2 Siemens Medical Solutions, Erlangen, Germany. #12;Chapter 20. Magnetic Resonance Imaging, Siemens Medical Solutions, Siemens-MIT Alliance, HST Martinos Catalyst Fund. Project Staff: Audrey P. Fan

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Nuclear magnetic resonance imaging of water content in the subsurface  

SciTech Connect (OSTI)

Previous theoretical and experimental studies indicated that surface nuclear magnetic resonance (NMR) has the potential to provide cost-effective water content measurements in the subsurface and is a technology ripe for exploitation in practice. The objectives of this investigation are (a) to test the technique under a wide range of hydrogeological conditions and (b) to generalize existing NMR theories in order to correctly model NMR response from conductive ground and to assess properties of the inverse problem. Twenty-four sites with different hydrogeologic settings were selected in New Mexico and Colorado for testing. The greatest limitation of surface NMR technology appears to be the lack of understanding in which manner the NMR signal is influenced by soil-water factors such as pore size distribution, surface-to-volume ratio, paramagnetic ions dissolved in the ground water, and the presence of ferromagnetic minerals. Although the theoretical basis is found to be sound, several advances need to be made to make surface NMR a viable technology for hydrological investigations. There is a research need to investigate, under controlled laboratory conditions, how the complex factors of soil-water systems affect NMR relaxation times.

J. Hendricks; T. Yao; A. Kearns

1999-01-21T23:59:59.000Z

22

Magnetic resonance apparatus  

DOE Patents [OSTI]

Means for producing a region of homogeneous magnetic field remote from the source of the field, wherein two equal field sources are arranged axially so their fields oppose, producing a region near the plane perpendicular to the axis midway between the sources where the radial component of the field goes through a maximum. Near the maximum, the field is homogeneous over prescribed regions.

Jackson, Jasper A. (Los Alamos, NM); Cooper, Richard K. (Los Alamos, NM)

1982-01-01T23:59:59.000Z

23

Edward Purcell and Nuclear Magnetic Resonance (NMR)  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartmentNationalRestart ofMeasuring DopamineEnergy,6.DavidE-print NetworkUSE ANDEXPERIMENTAL

24

Magnetic resonance studies of cement based materials in inhomogeneous magnetic fields  

SciTech Connect (OSTI)

Single-sided magnets give hope that Nuclear Magnetic Resonance (NMR) might in future be used for in situ characterisation of hydration and water transport in the surface layers of concrete slabs. Towards that end, a portable NMR-MOUSE (MObile Universal Surface Explorer) has been used to follow the hydration of gypsum based plaster, a Portland cement paste and concrete mortar. The results compare favourably to those obtained using a standard laboratory bench-top spectrometer. Further, stray field imaging (STRAFI) based methods have been used with embedded NMR detector coils to study water transport across a mortar/topping interface. The measured signal amplitudes are found to correlate with varying sample conditions.

Boguszynska, Joanna [Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, Poznan (Poland); Brown, Marc C.A. [School of Physical Sciences, University of Kent, Canterbury, Kent, CT2 7NR (United Kingdom); McDonald, Peter J. [School of Electronics and Physical Sciences, University of Surrey, Surrey, GU2 7XH (United Kingdom)]. E-mail: p.mcdonald@surrey.ac.uk; Mitchell, Jonathan [School of Electronics and Physical Sciences, University of Surrey, Surrey, GU2 7XH (United Kingdom); Mulheron, Mike [School of Engineering, University of Surrey, Surrey, GU2 7XH (United Kingdom); Tritt-Goc, Jadwiga [Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, Poznan (Poland); Verganelakis, Dimitris A. [Department of Chemical Engineering, University of Cambridge, Cambridge, CB2 3RA (United Kingdom)

2005-10-01T23:59:59.000Z

25

Adjustable permanent magnet assembly for NMR and MRI  

DOE Patents [OSTI]

System and methods for designing and using single-sided magnet assemblies for magnetic resonance imaging (MRI) are disclosed. The single-sided magnet assemblies can include an array of permanent magnets disposed at selected positions. At least one of the permanent magnets can be configured to rotate about an axis of rotation in the range of at least +/-10 degrees and can include a magnetization having a vector component perpendicular to the axis of rotation. The single-sided magnet assemblies can further include a magnet frame that is configured to hold the permanent magnets in place while allowing the at least one of the permanent magnets to rotate about the axis of rotation.

Pines, Alexander; Paulsen, Jeffrey; Bouchard, Louis S; Blumich, Bernhard

2013-10-29T23:59:59.000Z

26

Surfactant based imbibition and induced solution gas drive process: investigation by nuclear magnetic resonance  

E-Print Network [OSTI]

drive mechanism. This imbibition and induced solution gas drive study employed nuclear magnetic resonance (NMR) spectroscopy techniques to monitor and characterize the progress of oil recovery inside the rock sample core. A specially designed core...SURFACTANT BASED IMBIBITION AND INDUCED SOLUTION GAS DRIVE PROCESS: INVESTIGATION BY NUCLEAR MAGNETIC RESONANCE A Thesis by JAMES CALVIN COX Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

Cox, James Calvin

1993-01-01T23:59:59.000Z

27

The study of skin permeation mechanism and terpene-skin lipid interaction via nuclear magnetic resonance  

E-Print Network [OSTI]

, lipid extraction, etc. In our case, the interaction between a terpene and a lipid was examinedwith nuclear magnetic resonance (NMR), which aims to provide some insight to enhancement in skin permeation. Palmitic acid (Fig 1), a 16-carbon fatty acid... and oxides were able to producea greater ??. National University of Singapore, 2006 PS77 -The Study of Skin Permeation Mechanism and Terpene-Lipid Interaction via Nuclear Magnetic Resonance Perry Fung Chye Lim a, Xiang Yang Liu b, Meng Huang a, Paul Chi...

Lim, P. F. C.; Liu, Xiang Yang; Huang, Meng; Ho, P. C. L.; Chan, S. Y.

2006-10-27T23:59:59.000Z

28

Fundamental investigations of supported monometallic and bimetallic catalysts by proton magnetic resonance spectroscopy  

SciTech Connect (OSTI)

Proton magnetic resonance spectroscopy, or nuclear magnetic resonance (NMR) of hydrogen, has been applied to investigate silica-supported Group VIII monometallic and Group VIII-Group IB bimetallic catalysts and alumina- and silica-supported platinum-rhenium bimetallic catalysts. Two adsorbed states of hydrogen, i.e., irreversible and reversible hydrogen, on the surfaces of monometallic Ru, Pt, and Cu particles and bimetallic Ru-Group Ib, Pt-Group Ib, and Pt-Re particles were observed directly via proton NMR. The same amounts of the irreversible hydrogen adsorbed on pure Ru catalysts were measured by both proton NMR and the volumetric technique. The electronic environments on surfaces of monometallic catalysts are sensitive to changes in metal dispersion, state of adsorbed hydrogen, and residual chlorine. Surface compositions for the Ru--Cu and Pt--Cu bimetallic catalysts were determined by NMR of adsorbed hydrogen. 297 refs., 96 figs., 19 tabs.

Wu, Xi.

1990-09-21T23:59:59.000Z

29

1,3-Alternate calix[4]arene nitronyl nitroxide tetraradical and diradical: synthesis, X-ray crystallography, paramagnetic NMR spectroscopy, EPR spectroscopy, and magnetic studies  

SciTech Connect (OSTI)

Calix[4]arenes constrained to 1,3-alternate conformation and functionalized at the upper rim with four and two nitronyl nitroxides have been synthesized, and characterized by X-ray crystallography, magnetic resonance (EPR and {sup 1}H NMR) spectroscopy, and magnetic studies. Such calix[4]arene tetraradicals and diradicals provide scaffolds for through-bond and through-space intramolecular exchange couplings.

Rajca, Andrzej; Pink, Maren; Mukherjee, Sumit; Rajca, Suchada; Das, Kausik (UNL); (Indiana)

2008-04-02T23:59:59.000Z

30

Experimental Test of Complementarity by Nuclear Magnetic Resonance Techniques  

E-Print Network [OSTI]

We have tested complementarity for the ensemble-averaged spin states of nuclei $^{13}$C in the molecule of $^{13}$CHCl$_{3}$ by the use of the spin states of another nuclei $^{1}$H as the path marker. It turns out that the wave-particle duality holds when one merely measures the probability density of quantum states, and that the wave- and particle-like behavior is simultaneously observed with the help of measuring populations and coherence in a single nuclear magnetic resonance(NMR) experiment. Effects of path-marking schemes and causes of the appearance and disappearance of the wave behavior are analysed.

Xiwen Zhu; Ximing Fang; Xinhua Peng; Mang Feng; Kelin Gao; Fei Du

2000-11-22T23:59:59.000Z

31

Nuclear Magnetic Resonance Studies on Vanadium(IV) Electrolyte...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Magnetic Resonance Studies on Vanadium(IV) Electrolyte Solutions for Vanadium Redox Flow Battery . Nuclear Magnetic Resonance Studies on Vanadium(IV) Electrolyte Solutions for...

32

Natural Abundance 43Ca NMR Spectroscopy of Tobermorite and Jennite...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

which has limited our ability to understand the structure of, for example, Casilicate hydrate (CSH). 43Ca nuclear magnetic resonance (NMR) spectroscopy has...

33

Magnetic resonance imaging (MRI) of solid materials entails numerous problems from short longitudinal relaxation (T2) times to  

E-Print Network [OSTI]

. Solid-State STRAFI NMR Probe for Material Imaging of Quadrupolar Nuclei, J. Magn. Reson. httpMagnetic resonance imaging (MRI) of solid materials entails numerous problems from short for broadband tuning, sample translation along z-axis, and electrodes for in situ battery studies. An Alderman

Weston, Ken

34

Single echo acquisition magnetic resonance imaging  

E-Print Network [OSTI]

The dramatic improvement in magnetic resonance imaging (MRI) scan time over the past fifteen years through gradient-based methods that sample k-space more efficiently and quickly cannot be sustained, as thresholds regarding hardware and safety...

McDougall, Mary Preston

2006-04-12T23:59:59.000Z

35

Solid-Cryogen Cooling Technique for Superconducting Magnets of NMR and MRI  

E-Print Network [OSTI]

This paper describes a solid-cryogen cooling technique currently being developed at the M.I.T. Francis Bitter Magnet Laboratory for application to superconducting magnets of NMR and MRI. The technique is particularly ...

Iwasa, Yukikazu

36

THz Dynamic Nuclear Polarization NMR  

E-Print Network [OSTI]

Dynamic nuclear polarization (DNP) increases the sensitivity of nuclear magnetic resonance (NMR) spectroscopy by using high frequency microwaves to transfer the polarization of the electrons to the nuclear spins. The ...

Nanni, Emilio Alessandro

37

A biofilm microreactor system for simultaneous electrochemical and nuclear magnetic resonance techniques  

SciTech Connect (OSTI)

In order to fully understand electrochemically active biofilms and the limitations to their scale-up in industrial biofilm reactors, a complete picture of the microenvironments inside the biofilm is needed. Nuclear magnetic resonance (NMR) techniques are ideally suited for the study of biofilms and for probing their microenvironments because these techniques allow for non-invasive interrogation and in situ monitoring with high resolution. By combining NMR with simultaneous electrochemical techniques, it is possible to sustain and study live electrochemically active biofilms. Here, we introduce a novel biofilm microreactor system that allows for simultaneous electrochemical and NMR techniques (EC-NMR) at the microscale. Microreactors were designed with custom radiofrequency resonator coils, which allowed for NMR measurements of biofilms growing on polarized gold electrodes. For an example application of this system, we grew Geobacter sulfurreducens biofilms. NMR was used to investigate growth media flow velocities, which were compared to simulated laminar flow, and electron donor concentrations inside the biofilms. We use Monte Carlo error analysis to estimate standard deviations of the electron donor concentration measurements within the biofilm. The EC-NMR biofilm microreactor system can ultimately be used to correlate extracellular electron transfer rates with metabolic reactions and explore extracellular electron transfer mechanisms.

Renslow, Ryan S.; Babauta, Jerome T.; Majors, Paul D.; Mehta, Hardeep S.; Ewing, R. James; Ewing, Thomas; Mueller, Karl T.; Beyenal, Haluk

2014-01-30T23:59:59.000Z

38

Superconducting quantum interference device microsusceptometer balanced over a wide bandwidth for nuclear magnetic resonance applications  

SciTech Connect (OSTI)

Superconducting Quantum Interference Device (SQUID) microsusceptometers have been widely used to study magnetic properties of materials at microscale. As intrinsically balanced devices, they could also be exploited for direct SQUID-detection of nuclear magnetic resonance (NMR) from micron sized samples, or for SQUID readout of mechanically detected NMR from submicron sized samples. Here, we demonstrate a double balancing technique that enables achievement of very low residual imbalance of a SQUID microsusceptometer over a wide bandwidth. In particular, we can generate ac magnetic fields within the SQUID loop as large as 1 mT, for frequencies ranging from dc up to a few MHz. As an application, we demonstrate direct detection of NMR from {sup 1}H spins in a glycerol droplet placed directly on top of the 20 ?m SQUID loops.

Vinante, A., E-mail: anvinante@fbk.eu; Falferi, P. [Istituto di Fotonica e Nanotecnologie, CNR - Fondazione Bruno Kessler, I-38123 Povo, Trento (Italy); Mezzena, R. [Dipartimento di Fisica, Universit di Trento, I-38123 Povo, Trento (Italy)

2014-10-15T23:59:59.000Z

39

A Polynomial-Time Nuclear Vector Replacement Algorithm for Automated NMR Resonance Assignments  

E-Print Network [OSTI]

A Polynomial-Time Nuclear Vector Replacement Algorithm for Automated NMR Resonance Assignments and refinement. A new algorithm, called Nuclear Vector Replacement (NVR) is introduced to compute assignments be acquired in a fraction of the time needed to record the traditional suite of ex- periments used to perform

Lilien, Ryan

40

Solid-State Nuclear Magnetic Resonance Evidence for an Extended Strand Conformation of the Membrane-Bound HIV-1 Fusion Peptide  

E-Print Network [OSTI]

Solid-State Nuclear Magnetic Resonance Evidence for an Extended Strand Conformation of the Membrane-Bound HIV-1 Fusion Peptide Jun Yang, Charles M. Gabrys, and David P. Weliky* Department of ChemistryVed May 4, 2001 ABSTRACT: Solid-state nuclear magnetic resonance (NMR) spectroscopy was applied

Weliky, David

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Nuclear magnetic resonance studies of quadrupolar nuclei and dipolar field effects  

SciTech Connect (OSTI)

Experimental and theoretical research conducted in two areas in the field of nuclear magnetic resonance (NMR) spectroscopy is presented: (1) studies of the coherent quantum-mechanical control of the angular momentum dynamics of quadrupolar (spin I > 1/2) nuclei and its application to the determination of molecular structure; and (2) applications of the long-range nuclear dipolar field to novel NMR detection methodologies.The dissertation is organized into six chapters. The first two chapters and associated appendices are intended to be pedagogical and include an introduction to the quantum mechanical theory of pulsed NMR spectroscopy and the time dependent theory of quantum mechanics. The third chapter describes investigations of the solid-state multiple-quantum magic angle spinning (MQMAS) NMR experiment applied to I = 5/2 quadrupolar nuclei. This work reports the use of rotary resonance-matched radiofrequency irradiation for sensitivity enhancement of the I = 5/2 MQMAS experiment. These experiments exhibited certain selective line narrowing effects which were investigated theoretically.The fourth chapter extends the discussion of multiple quantum spectroscopy of quadrupolar nuclei to a mostly theoretical study of the feasibility of enhancing the resolution of nitrogen-14 NMR of large biomolecules in solution via double-quantum spectroscopy. The fifth chapter continues to extend the principles of multiple quantum NMR spectroscopy of quadrupolar nuclei to make analogies between experiments in NMR/nuclear quadrupolar resonance (NQR) and experiments in atomic/molecular optics (AMO). These analogies are made through the Hamiltonian and density operator formalism of angular momentum dynamics in the presence of electric and magnetic fields.The sixth chapter investigates the use of the macroscopic nuclear dipolar field to encode the NMR spectrum of an analyte nucleus indirectly in the magnetization of a sensor nucleus. This technique could potentially serve as an encoding module for the recently developed NMR remote detection experiment. The feasibility of using hyperpolarized xenon-129 gas as a sensor is discussed. This work also reports the use of an optical atomic magnetometer to detect the nuclear magnetization of Xe-129 gas, which has potential applicability as a detection module for NMR remote detection experiments.

Urban, Jeffry Todd

2004-12-21T23:59:59.000Z

42

Nuclear magnetic resonance offers new insights into Pu 239  

E-Print Network [OSTI]

- 1 - Nuclear magnetic resonance offers new insights into Pu 239 May 29, 2012 Nuclear magnetic signal of plutonium 239's unique nuclear magnetic resonance signature has been detected by scientists on the subject, "Observation of 239 Pu Nuclear Magnetic Resonance," was published in the May 18 issue of Science

43

Magnetic Resonance Imaging (MRI) of PEM Dehydration and Gas Manifold...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Resonance Imaging (MRI) of PEM Dehydration and Gas Manifold Flooding During Continuous Fuel Cell Operation. Magnetic Resonance Imaging (MRI) of PEM Dehydration and Gas Manifold...

44

Co-Funding for the Conference on Magnetic Resonance in Biological Systems  

SciTech Connect (OSTI)

The XXIst International Conference on Magnetic Resonance in Biological Systems (ICMRBS 2005), '60th anniversary of the discovery of Nuclear Magnetic Resonance,' was held between 16 and 21 January 2005 in Hyderabad, India. The meeting focused on a broad range of magnetic resonance methods as applied to studies of biological processes related to human health. The biennial ICMRBS has become the major venue for discussion of advances in nuclear and electron magnetic resonance (NMR & EMR/EPR) studies of the structure, dynamics, and chemical properties of important classes of biomolecules. Magnetic resonance has become an established tool in structural biology, and its special importance derives from its ability to provide atomic level information. It is becoming increasingly evident that the dynamic features of biomolecules, their intermolecular interactions, and accessible conformations in solution are data of key importance in understanding molecular recognition and function. NMR, which is already contributing to approximately 25% of the new structures being deposited with the Protein Data Bank, is destined to be a major player in the post genomic structure age with its emphasis on structure and function. In-vivo magnetic resonance spectroscopy (MRS) and magnetic resonance imaging (MRI) results shed light on human metabolic processes and on the cellular ramifications of cancer, stroke, cardiovascular disease, and other pathologies. New methodologies in metabonomics may lead to development of new drugs and medical diagnosis. The ICMRBS is the one conference that brings together experts from high-resolution NMR, solid state NMR, EPR, in-vivo MRS and MRI, and developers of instrumentation, techniques, software, and databases. Symposia at this ICMRBS are designed to continue the fruitful cross-fertilization of ideas that has been so successful in driving the spectacular advances in this field. ICMRBS 2005 maintained the traditional format of poster sessions, and plenary lectures that highlight major advances in each of the major areas, and three parallel symposia that focused on particular biological systems, interfacial applications of magnetic resonance, and rapidly advancing technology. Funds provided partial travel support for 33 younger scientists from the U.S. (graduate students, postdoctoral research associates, and beginning faculty), selected from those who submitted accepted posters; 12 of these were invited to contribute oral presentations. Those receiving travel support were selected by a committee composed of the U.S. members of the International Advisory Committee for the meeting. Particular emphasis was placed on facilitating participation of minority and women scientists.

Alan McLaughlin, Ph.D., Director, Division of Applied Science & Technology, NIBIB, NIH

2008-10-01T23:59:59.000Z

45

Unraveling multi-spin effects in rotational resonance nuclear magnetic resonance using effective reduced density matrix theory  

SciTech Connect (OSTI)

A quantum-mechanical model integrating the concepts of reduced density matrix and effective Hamiltonians is proposed to explain the multi-spin effects observed in rotational resonance (R{sup 2}) nuclear magnetic resonance (NMR) experiments. Employing this approach, the spin system of interest is described in a reduced subspace inclusive of its coupling to the surroundings. Through suitable model systems, the utility of our theory is demonstrated and verified with simulations emerging from both analytic and numerical methods. The analytic results presented in this article provide an accurate description/interpretation of R{sup 2} experimental results and could serve as a test-bed for distinguishing coherent/incoherent effects in solid-state NMR.

SivaRanjan, Uppala; Ramachandran, Ramesh, E-mail: rramesh@iisermohali.ac.in [Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Mohali, Sector 81, Manauli, P.O. Box-140306, Mohali, Punjab (India)] [Department of Chemical Sciences, Indian Institute of Science Education and Research (IISER) Mohali, Sector 81, Manauli, P.O. Box-140306, Mohali, Punjab (India)

2014-02-07T23:59:59.000Z

46

Magnetic elliptical polarization of Schumann resonances  

SciTech Connect (OSTI)

Measurements of orthogonal, horizontal components of the magnetic field in the ELF range obtained during September 1985 show that the Schumann resonance eigenfrequencies determined separately for the north-south and east-west magnetic components differ by as much as 0.5 Hz, suggesting that the underlying magnetic signal is not linearly polarized at such times. The high degree of magnetic ellipticity found suggests that the side multiplets of the Schumann resonances corresponding to azimuthally inhomogeneous normal modes are strongly excited in the highly asymmetric earth-ionosphere cavity. The dominant sense of polarization over the measurement passband is found to be right-handed during local daylight hours, and to be left-handed during local nighttime hours. 16 references.

Sentman, D.D.

1987-08-01T23:59:59.000Z

47

Residual Dipolar Couplings in Zero-to-Ultra-Low-Field Nuclear Magnetic Resonance  

E-Print Network [OSTI]

Zero-to-ultra-low-field nuclear magnetic resonance (ZULF-NMR) provides a new regime for the measurement of nuclear spin-spin interactions free from effects of large magnetic fields, such as truncation of terms that do not commute with the Zeeman Hamiltonian. One such interaction, the magnetic dipole-dipole coupling, is a valuable source of spatial information in NMR, though many terms are unobservable in high-field NMR, and the interaction averages to zero under isotropic molecular tumbling. Under partial orientational ordering, this information is retained in the form of so-called residual dipolar couplings. We report zero-to-ultra-low-field NMR measurements of residual dipolar couplings in acetonitrile-2-$^{13}$C aligned in stretched polyvinyl acetate gels. This represents the first investigation of dipolar couplings as a perturbation on the indirect spin-spin $J$-coupling in the absence of an applied magnetic field. As a consequence of working at zero magnetic field, we observe terms of the dipole-dipole c...

Blanchard, John W; King, Jonathan P; Ledbetter, Micah P; Levine, Emma H; Bajaj, Vikram S; Budker, Dmitry; Pines, Alexander

2015-01-01T23:59:59.000Z

48

National High Magnetic Field Laboratory - NMR/MRIs Advisory Committee  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Research Interests: Solution NMR Term ending: 6302016 Myriam Cotten Hamilton College Department of Chemistry 1075 Science Center Clinton, NY 13323 Phone:...

49

High field DNP and cryogenic MAS NMR : novel instrumentation and applications  

E-Print Network [OSTI]

Solid State Nuclear Magnetic Resonance (ssNMR) spectroscopy has blossomed over the last two decades. As ssNMR is progressively applied to more challenging systems, the sensitivity remains one of its major limiting factors. ...

Markhasin, Evgeny

2014-01-01T23:59:59.000Z

50

Squid detected NMR and MRI at ultralow fields  

DOE Patents [OSTI]

Nuclear magnetic resonance (NMR) signals are detected in microtesla fields. Prepolarization in millitesla fields is followed by detection with an untuned dc superconducting quantum interference device (SQUID) magnetometer. Because the sensitivity of the SQUID is frequency independent, both signal-to-noise ratio (SNR) and spectral resolution are enhanced by detecting the NMR signal in extremely low magnetic fields, where the NMR lines become very narrow even for grossly inhomogeneous measurement fields. MRI in ultralow magnetic field is based on the NMR at ultralow fields. Gradient magnetic fields are applied, and images are constructed from the detected NMR signals.

Clarke, John (Berkeley, CA); Pines, Alexander (Berkeley, CA); McDermott, Robert F. (Monona, WI); Trabesinger, Andreas H. (London, GB)

2008-12-16T23:59:59.000Z

51

Squid detected NMR and MRI at ultralow fields  

DOE Patents [OSTI]

Nuclear magnetic resonance (NMR) signals are detected in microtesla fields. Prepolarization in millitesla fields is followed by detection with an untuned dc superconducting quantum interference device (SQUID) magnetometer. Because the sensitivity of the SQUID is frequency independent, both signal-to-noise ratio (SNR) and spectral resolution are enhanced by detecting the NMR signal in extremely low magnetic fields, where the NMR lines become very narrow even for grossly inhomogeneous measurement fields. MRI in ultralow magnetic field is based on the NMR at ultralow fields. Gradient magnetic fields are applied, and images are constructed from the detected NMR signals.

Clarke, John (Berkeley, CA); McDermott, Robert (Louisville, CO); Pines, Alexander (Berkeley, CA); Trabesinger, Andreas Heinz (CH-8006 Zurich, CH)

2007-05-15T23:59:59.000Z

52

SQUID detected NMR and MRI at ultralow fields  

DOE Patents [OSTI]

Nuclear magnetic resonance (NMR) signals are detected in microtesla fields. Prepolarization in millitesla fields is followed by detection with an untuned dc superconducting quantum interference device (SQUID) magnetometer. Because the sensitivity of the SQUID is frequency independent, both signal-to-noise ratio (SNR) and spectral resolution are enhanced by detecting the NMR signal in extremely low magnetic fields, where the NMR lines become very narrow even for grossly inhomogeneous measurement fields. MRI in ultralow magnetic field is based on the NMR at ultralow fields. Gradient magnetic fields are applied, and images are constructed from the detected NMR signals.

Clarke, John; McDermott, Robert; Pines, Alexander; Trabesinger, Andreas Heinz

2006-10-03T23:59:59.000Z

53

Squid detected NMR and MRI at ultralow fields  

DOE Patents [OSTI]

Nuclear magnetic resonance (NMR) signals are detected in microtesla fields. Prepolarization in millitesla fields is followed by detection with an untuned dc superconducting quantum interference device (SQUID) magnetometer. Because the sensitivity of the SQUID is frequency independent, both signal-to-noise ratio (SNR) and spectral resolution are enhanced by detecting the NMR signal in extremely low magnetic fields, where the NMR lines become very narrow even for grossly inhomogeneous measurement fields. MRI in ultralow magnetic field is based on the NMR at ultralow fields. Gradient magnetic fields are applied, and images are constructed from the detected NMR signals.

Clarke, John; McDermott, Robert; Pines, Alexander; Trabesinger, Andreas Heinz

2006-05-30T23:59:59.000Z

54

SQUID detected NMR and MRI at ultralow fields  

DOE Patents [OSTI]

Nuclear magnetic resonance (NMR) signals are detected in microtesla fields. Prepolarization in millitesla fields is followed by detection with an untuned de superconducting quantum interference device (SQUID) magnetometer. Because the sensitivity of the SQUID is frequency independent, both signal-to-noise ratio (SNR) and spectral resolution are enhanced by detecting the NMR signal in extremely low magnetic fields, where the NMR lines become very narrow even for grossly inhomogeneous measurement fields. MRI in ultralow magnetic field is based on the NMR at ultralow fields. Gradient magnetic fields are applied, and images are constructed from the detected NMR signals.

Clarke, John; McDermott, Robert; Pines, Alexander; Trabesinger, Andreas Heinz

2005-04-26T23:59:59.000Z

55

Journal of Magnetism and Magnetic Materials 286 (2005) 324328 Light-free magnetic resonance force microscopy for studies of  

E-Print Network [OSTI]

Journal of Magnetism and Magnetic Materials 286 (2005) 324­328 Light-free magnetic resonance force for Physical Sciences, College Park, MD, USA Available online 4 November 2004 Abstract Magnetic resonance force microscopy is a scanned probe technique capable of three-dimensional magnetic resonance imaging. Its

56

Resonant detection of axion mediated forces with Nuclear Magnetic Resonance  

E-Print Network [OSTI]

We describe a method based on precision magnetometry that can extend the search for axion-mediated spin-dependent forces by several orders of magnitude. By combining techniques used in nuclear magnetic resonance and short-distance tests of gravity, our approach can substantially improve upon current experimental limits set by astrophysics, and probe deep into the theoretically interesting regime for the Peccei-Quinn (PQ) axion. Our method is sensitive to PQ axion decay constants between 10^9 and 10^12 GeV or axion masses between 10^-6 and 10^-3 eV, independent of the cosmic axion abundance.

Asimina Arvanitaki; Andrew A. Geraci

2014-03-05T23:59:59.000Z

57

Advanced Magnetic Resonance Workshop Report | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUCProductstwrmrAre theAdministrator ReferencesalkaliAdvanced Magnetic Resonance

58

Electro-Mechanical Resonant Magnetic Field Sensor  

E-Print Network [OSTI]

We describe a new type of magnetic field sensor which is termed an Electro-Mechanical Resonant Sensor (EMRS). The key part of this sensor is a small conductive elastic element with low damping rate and therefore a high Q fundamental mode of frequency $f_1$. An AC current is driven through the elastic element which, in the presence of a magnetic field, causes an AC force on the element. When the frequency of the AC current matches the resonant frequency of the element, maximum vibration of the element occurs and this can be measured precisely by optical means. We have built and tested a model sensor of this type using for the elastic element a length of copper wire of diameter 0.030 mm formed into a loop shape. The wire motion was measured using a light emitting diode photo-transistor assembly. This sensor demonstrated a sensitivity better than 0.001G for an applied magnetic field of $ \\sim 1$G and a good selectivity for the magnetic field direction. The sensitivity can be easily improved by a factor of $\\sim ...

Temnykh, A B; Temnykh, Alexander B.; Lovelace, Richard V. E.

2002-01-01T23:59:59.000Z

59

Nuclear Magnetic Resonance: Portable and integrated Lead: P. Poulichet.  

E-Print Network [OSTI]

Nuclear Magnetic Resonance: Portable and integrated Lead: P. Poulichet. Permanent members: L. Rousseau, A. Fakri. Associated researchers: C. Delabie, A. Exertier. Portable Nuclear Magnetic Resonance : our work in the field of nuclear magneto resonance is focused on the design and the realization

Baudoin, Geneviève

60

Transverse Pulsed NMR of Superuid 3He in Aerogel| Unconventional Pairing in the Presence of Quenched Disorder.  

E-Print Network [OSTI]

?? This thesis reports the results of transverse pulsed nuclear magnetic resonance (NMR) experiments performed on superfluid He in a new class of highly uniform (more)

Pollanen, Johannes

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Appl. Magn. Reson. (2007) 32, 93112 DOI 10.1007/s00723-007-0002-7  

E-Print Network [OSTI]

Applied Magnetic Resonance Noninvasive Measurements of Gas Exchange in a Three- Dimensional Fluidized Bed 12 July 2006 Springer-Verlag 2007 Abstract. We present a novel nuclear magnetic resonance (NMR of nuclear magnetic resonance (NMR) as a noninvasive tool for studying the dy- namics of the solid particles

Walsworth, Ronald L.

2007-01-01T23:59:59.000Z

62

Magnetic levitation of metamaterial bodies enhanced with magnetostatic surface resonances  

E-Print Network [OSTI]

We propose that macroscopic objects built from negative-permeability metamaterials may experience resonantly enhanced magnetic force in low-frequency magnetic fields. Resonant enhancement of the time-averaged force originates from magnetostatic surface resonances (MSR) which are analogous to the electrostatic resonances of negative-permittivity particles, well known as surface plasmon resonances in optics. We generalize the classical problem of MSR of a homogeneous object to include anisotropic metamaterials, and consider the most extreme case of anisotropy where the permeability is negative in one direction but positive in the others. It is shown that deeply subwavelength objects made of such indefinite (hyperbolic) media exhibit a pronounced magnetic dipole resonance that couples strongly to uniform or weakly inhomogeneous magnetic field and provides strong enhancement of the magnetic force, enabling applications such as enhanced magnetic levitation.

Urzhumov, Yaroslav; Bingham, Chris; Padilla, Willie; Smith, David R

2011-01-01T23:59:59.000Z

63

Science Drivers and Technical Challenges for Advanced Magnetic Resonance  

SciTech Connect (OSTI)

This report recaps the "Science Drivers and Technical Challenges for Advanced Magnetic Resonance" workshop, held in late 2011. This exploratory workshop's goal was to discuss and address challenges for the next generation of magnetic resonance experimentation. During the workshop, participants from throughout the world outlined the science drivers and instrumentation demands for high-field dynamic nuclear polarization (DNP) and associated magnetic resonance techniques, discussed barriers to their advancement, and deliberated the path forward for significant and impactful advances in the field.

Mueller, Karl T.; Pruski, Marek; Washton, Nancy M.; Lipton, Andrew S.

2013-03-07T23:59:59.000Z

64

arthritis magnetic resonance: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

during magnetic resonance imaging (MRI) is the distortion of the ECG due to electromagnetic interference cardiac activity that, unlike the ECG, is immune to electromagnetic...

65

Magnetic resonance imaging of self-assembled biomaterial scaffolds  

DOE Patents [OSTI]

Compositions and/or mixtures comprising peptide amphiphile compounds comprising one or more contrast agents, as can be used in a range of magnetic resonance imaging applications.

Bull, Steve R; Meade, Thomas J; Stupp, Samuel I

2014-09-16T23:59:59.000Z

66

Compact orthogonal NMR field sensor  

DOE Patents [OSTI]

A Compact Orthogonal Field Sensor for emitting two orthogonal electro-magnetic fields in a common space. More particularly, a replacement inductor for existing NMR (Nuclear Magnetic Resonance) sensors to allow for NMR imaging. The Compact Orthogonal Field Sensor has a conductive coil and a central conductor electrically connected in series. The central conductor is at least partially surrounded by the coil. The coil and central conductor are electrically or electro-magnetically connected to a device having a means for producing or inducing a current through the coil and central conductor. The Compact Orthogonal Field Sensor can be used in NMR imaging applications to determine the position and the associated NMR spectrum of a sample within the electro-magnetic field of the central conductor.

Gerald, II, Rex E. (Brookfield, IL); Rathke, Jerome W. (Homer Glen, IL)

2009-02-03T23:59:59.000Z

67

I. I. Rabi, Nuclear Magnetic Resonance (NMR), and Radar  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr FlickrGuidedCH2MLLCBasics Hydropower BasicsDepartment

68

Direct imaging of neural currents using ultra-low field magnetic resonance techniques  

DOE Patents [OSTI]

Using resonant interactions to directly and tomographically image neural activity in the human brain using magnetic resonance imaging (MRI) techniques at ultra-low field (ULF), the present inventors have established an approach that is sensitive to magnetic field distributions local to the spin population in cortex at the Larmor frequency of the measurement field. Because the Larmor frequency can be readily manipulated (through varying B.sub.m), one can also envision using ULF-DNI to image the frequency distribution of the local fields in cortex. Such information, taken together with simultaneous acquisition of MEG and ULF-NMR signals, enables non-invasive exploration of the correlation between local fields induced by neural activity in cortex and more `distant` measures of brain activity such as MEG and EEG.

Volegov, Petr L. (Los Alamos, NM); Matlashov, Andrei N. (Los Alamos, NM); Mosher, John C. (Los Alamos, NM); Espy, Michelle A. (Los Alamos, NM); Kraus, Jr., Robert H. (Los Alamos, NM)

2009-08-11T23:59:59.000Z

69

Development of Nuclear Magnetic Resonance Imaging/spectroscopy for improved petroleum recovery. Final report  

SciTech Connect (OSTI)

The overall objectives of this program are to develop and apply Nuclear Magnetic Resonance Imaging (NMRI) and CT X-Ray Scanning methods for determining rock, fluid, and petrophysical properties and for fundamental studies of multiphase flow behavior in porous media. Specific objectives are divided into four subtasks: (1) development of NMRI and CT scanning for the determination of rock-fluid and petrophysical properties; (2) development of NMRI and CT scanning for characterizing conventional multiphase displacement processes; (3) development of NMR and CT scanning for characterizing dispersed phase processes; and (4) miscible displacement studies.

Barrufet, M.A.; Flumerfelt, F.W.; Walsh, M.P.; Watson, A.T.

1994-04-01T23:59:59.000Z

70

Controlling interactions between highly-magnetic atoms with Feshbach resonances  

E-Print Network [OSTI]

This paper reviews current experimental and theoretical progress in the study of dipolar quantum gases of ground and meta-stable atoms with a large magnetic moment. We emphasize the anisotropic nature of Feshbach resonances due to coupling to fast-rotating resonant molecular states in ultracold s-wave collisions between magnetic atoms in external magnetic fields. The dramatic differences in the distribution of resonances of magnetic $^7$S$_3$ chromium and magnetic lanthanide atoms with a submerged 4f shell and non-zero electron angular momentum is analyzed. We focus on Dysprosium and Erbium as important experimental advances have been recently made to cool and create quantum-degenerate gases for these atoms. Finally, we describe progress in locating resonances in collisions of meta-stable magnetic atoms in electronic P states with ground-state atoms, where an interplay between collisional anisotropies and spin-orbit coupling exists.

Svetlana Kotochigova

2014-10-14T23:59:59.000Z

71

Coherent dynamical recoupling of diffusion-driven decoherence in magnetic resonance  

E-Print Network [OSTI]

During recent years, dynamical decoupling (DD) has gained relevance as a tool for manipulating quantum systems and extracting information from them. This is particularly relevant for spins involved in nuclear magnetic resonance (NMR), where DD sequences can be used to prolong quantum coherences, or for selectively couple/decouple the effects imposed by random environmental fluctuations. In this Letter, we show that one can exploit these concepts in order to selectively recouple diffusion processes in restricted spaces. The ensuing method provides a novel tool to measure restriction lengths in confined systems such as capillaries, pores or cells. The principles of this method for selectively recoupling diffusion-driven decoherence, its standing within the context of diffusion NMR, and corroborating experiments, are presented.

Gonzalo A. Alvarez; Noam Shemesh; Lucio Frydman

2014-09-07T23:59:59.000Z

72

NMR and MRI apparatus and method  

DOE Patents [OSTI]

Nuclear magnetic resonance (NMR) signals are detected in microtesla fields. Prepolarization in millitesla fields is followed by detection with an untuned dc superconducting quantum interference device (SQUID) magnetometer. Because the sensitivity of the SQUID is frequency independent, both signal-to-noise ratio (SNR) and spectral resolution are enhanced by detecting the NMR signal in extremely low magnetic fields, where the NMR lines become very narrow even for grossly inhomogeneous measurement fields. Additional signal to noise benefits are obtained by use of a low noise polarization coil, comprising litz wire or superconducting materials. MRI in ultralow magnetic field is based on the NMR at ultralow fields. Gradient magnetic fields are applied, and images are constructed from the detected NMR signals.

Clarke, John; Kelso, Nathan; Lee, SeungKyun; Moessle, Michael; Myers, Whittier; McDermott, Robert; ten Haken, Bernard; Pines, Alexander; Trabesinger, Andreas

2007-03-06T23:59:59.000Z

73

Three dimensional nuclear magnetic resonance spectroscopic imaging of sodium ions using stochastic excitation and oscillating gradients  

SciTech Connect (OSTI)

Nuclear magnetic resonance (NMR) spectroscopic imaging of {sup 23}Na holds promise as a non-invasive method of mapping Na{sup +} distributions, and for differentiating pools of Na{sup +} ions in biological tissues. However, due to NMR relaxation properties of {sup 23}Na in vivo, a large fraction of Na{sup +} is not visible with conventional NMR imaging methods. An alternate imaging method, based on stochastic excitation and oscillating gradients, has been developed which is well adapted to measuring nuclei with short T{sub 2}. Contemporary NMR imaging techniques have dead times of up to several hundred microseconds between excitation and sampling, comparable to the shortest in vivo {sup 23}Na T{sub 2} values, causing significant signal loss. An imaging strategy based on stochastic excitation has been developed which greatly reduces experiment dead time by reducing peak radiofrequency (RF) excitation power and using a novel RF circuit to speed probe recovery. Continuously oscillating gradients are used to eliminate transient eddy currents. Stochastic {sup 1}H and {sup 23}Na spectroscopic imaging experiments have been performed on a small animal system with dead times as low as 25{mu}s, permitting spectroscopic imaging with 100% visibility in vivo. As an additional benefit, the encoding time for a 32x32x32 spectroscopic image is under 30 seconds. The development and analysis of stochastic NMR imaging has been hampered by limitations of the existing phase demodulation reconstruction technique. Three dimensional imaging was impractical due to reconstruction time, and design and analysis of proposed experiments was limited by the mathematical intractability of the reconstruction method. A new reconstruction method for stochastic NMR based on Fourier interpolation has been formulated combining the advantage of a several hundredfold reduction in reconstruction time with a straightforward mathematical form.

Frederick, B.deB. [California Univ., Berkeley, CA (United States)]|[Lawrence Berkeley Lab., CA (United States)

1994-12-01T23:59:59.000Z

74

Solution NMR of a 463-Residue Phosphohexomutase: Domain 4 Mobility...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the deep catalytic cleft. Nuclear magnetic resonance (NMR) spectra of the backbone of wild-type and S108C-inactivated enzymes were assigned to at least 90%. 13C secondary...

75

Protein MAS NMR methodology and structural analysis of protein assemblies  

E-Print Network [OSTI]

Methodological developments and applications of solid-state magic-angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy, with particular emphasis on the analysis of protein structure, are described in this thesis. ...

Bayro, Marvin J

2010-01-01T23:59:59.000Z

76

Ultra-low field nuclear magnetic resonance and magnetic resonance imaging to discriminate and identify materials  

DOE Patents [OSTI]

Method comprising obtaining an NMR measurement from a sample wherein an ultra-low field NMR system probes the sample and produces the NMR measurement and wherein a sampling temperature, prepolarizing field, and measurement field are known; detecting the NMR measurement by means of inductive coils; analyzing the NMR measurement to obtain at least one measurement feature wherein the measurement feature comprises T1, T2, T1.rho., or the frequency dependence thereof; and, searching for the at least one measurement feature within a database comprising NMR reference data for at least one material to determine if the sample comprises a material of interest.

Matlashov, Andrei Nikolaevich; Urbaitis, Algis V.; Savukov, Igor Mykhaylovich; Espy, Michelle A.; Volegov, Petr Lvovich; Kraus, Jr., Robert Henry

2013-03-05T23:59:59.000Z

77

A METHODOLOGY TO INTEGRATE MAGNETIC RESONANCE AND ACOUSTIC MEASUREMENTS FOR RESERVOIR CHARACTERIZATION  

SciTech Connect (OSTI)

The work reported herein represents the third year of development efforts on a methodology to interpret magnetic resonance and acoustic measurements for reservoir characterization. In this last phase of the project we characterize a vuggy carbonate aquifer in the Hillsboro Basin, Palm Beach County, South Florida, using two data sets--the first generated by velocity tomography and the second generated by reflection tomography. First, we integrate optical macroscopic (OM), scanning electron microscope (SEM) and x-ray computed tomography (CT) images, as well as petrography, as a first step in characterizing the aquifer pore system. This pore scale integration provides information with which to evaluate nuclear magnetic resonance (NMR) well log signatures for NMR well log calibration, interpret ultrasonic data, and characterize flow units at the field scale between two wells in the aquifer. Saturated and desaturated NMR core measurements estimate the irreducible water in the rock and the variable T{sub 2} cut-offs for the NMR well log calibration. These measurements establish empirical equations to extract permeability from NMR well logs. Velocity and NMR-derived permeability and porosity relationships integrated with velocity tomography (based on crosswell seismic measurements recorded between two wells 100 m apart) capture two flow units that are supported with pore scale integration results. Next, we establish a more detailed picture of the complex aquifer pore structures and the critical role they play in water movement, which aids in our ability to characterize not only carbonate aquifers, but reservoirs in general. We analyze petrography and cores to reveal relationships between the rock physical properties that control the compressional and shear wave velocities of the formation. A digital thin section analysis provides the pore size distributions of the rock matrix, which allows us to relate pore structure to permeability and to characterize flow units at the core and borehole scales. Vp, density, porosity, and permeability logs are integrated with crosswell reflection data to produce impedance, permeability, and porosity images. These images capture three flow units that are characterized at the pore and borehole scales. The upper flow units are thin, continuous beds, and the deeper flow unit is thicker and heterogeneous. NMR well log calibration data and thin section analysis demonstrate that interwell region permeability is controlled mainly by micropores and macropores, which represent the flow unit matrices of the confined aquifer. Reflection image-derived impedance provides lateral detail and the depth of the deeper confining unit. The permeable regions identified in both parts of this phase of the study are consistent with the hydrological results of high water production being monitored between two wells in the South Florida aquifer. Finally, we describe the two major methodologies developed to support the aquifer characterization efforts--(1) a method to estimate frequency-dependent scattering attenuation based on the volume fraction and typical size of vugs or karsts, and (2) a method to more accurately interpret NMR well logs by taking into account the diffusion of magnetization between large and small pores. For the first method, we take the exact vug structure from x-ray CT scans of two carbonate cores and use 3-D finite difference modeling to determine the P-wave scattering attenuation in these cores at ultrasonic frequencies. In spite of the sharp contrast in medium properties between cavity and rock and the violation of the small perturbation assumption, the computed scattering attenuation is roughly comparable to that predicted by various random medium scattering theories. For the second method, we investigate how the diffusion of magnetization between macropores and micropores influences NMR log interpretation through 2D simulation of magnetization diffusion in realistic macropore geometries derived from digital images of thin sections. In most cases, our simulations show that the resulting simulate

Jorge O. Parra; Chris L. Hackert; Lorna L. Wilson

2002-09-20T23:59:59.000Z

78

On the Dynamics of Magnetic Fluids in Magnetic Resonance Padraig J. Cantillon-Murphy  

E-Print Network [OSTI]

in Magnetic Resonance Imaging by Padraig J. Cantillon-Murphy B.E., Electrical and Electronic EngineeringOn the Dynamics of Magnetic Fluids in Magnetic Resonance Imaging by Padraig J. Cantillon-Murphy Submitted to the Department of Electrical Engineering and Computer Science in partial fulfillment

79

E-Print Network 3.0 - alternative magnetic resonance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

field provides a tool for tuning the dielectric resonance... resonator a magnetic field tunable dielectric resonances at frequencies much higher than usual ferromagnetic... , on...

80

Multi-rank nuclear magnetic resonance studies of half-integer quadrupolar nuclei in solids by three-dimensional dynamic-angle  

E-Print Network [OSTI]

Multi-rank nuclear magnetic resonance studies of half-integer quadrupolar nuclei in solids by three-integer quadrupolar nuclei in solids. The method is based on the multi-rank expansion of the high-field NMR, as well as by second- and fourth-rank anisotropies depending on the principal values and relative

Frydman, Lucio

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Purcell factor of Mie resonators featuring electric and magnetic modes  

E-Print Network [OSTI]

We present a modal approach to compute the Purcell factor in Mie resonators exhibiting both electric and magnetic resonances. The analytic expressions of the normal modes are used to calculate the effective volumes. We show that important features of the effective volume can be predicted thanks to the translation-addition coefficients of a displaced dipole. Using our formalism, it is easy to see that, in general, the Purcell factor of Mie resonators is not dominated by a single mode, but rather by a large superposition. Finally we consider a silicon resonator homogeneously doped with electric dipolar emitters, and we show that the average electric Purcell factor dominates over the magnetic one.

Zambrana-Puyalto, Xavier

2015-01-01T23:59:59.000Z

82

Detection of magnetic resonance signals using a magnetoresistive sensor  

DOE Patents [OSTI]

A method and apparatus are described wherein a micro sample of a fluidic material may be assayed without sample contamination using NMR techniques, in combination with magnetoresistive sensors. The fluidic material to be assayed is first subject to pre-polarization, in one embodiment, by passage through a magnetic field. The magnetization of the fluidic material is then subject to an encoding process, in one embodiment an rf-induced inversion by passage through an adiabatic fast-passage module. Thereafter, the changes in magnetization are detected by a pair of solid-state magnetoresistive sensors arranged in gradiometer mode. Miniaturization is afforded by the close spacing of the various modules.

Budker, Dmitry; Pines, Alexander; Xu, Shoujun; Hilty, Christian; Ledbetter, Micah P; Bouchard, Louis S

2013-10-01T23:59:59.000Z

83

Microfluidically Cryo-Cooled Planar Coils for Magnetic Resonance Imaging  

E-Print Network [OSTI]

High signal-to-noise ratio (SNR) is typically required for higher resolution and faster speed in magnetic resonance imaging (MRI). Planar microcoils as receiver probes in MRI systems offer the potential to be configured into array elements for fast...

Koo, Chiwan

2013-08-09T23:59:59.000Z

84

Target-specific contrast agents for magnetic resonance microscopy  

E-Print Network [OSTI]

High-resolution ex vivo magnetic resonance microscopy (MRM) can be used to delineate prominent architectonic features in the human brain, but increased contrast is required to visualize more subtle distinctions. The goal ...

Hepler Blackwell, Megan Leticia

2007-01-01T23:59:59.000Z

85

artery magnetic resonance: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Whole Brain Isotropic Arterial Spin Labeling Magnetic Resonance Imaging in a transgenic mouse...

86

Magnetism studies using resonant, coherent, x-ray scattering...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Magnetism studies using resonant, coherent, x-ray scattering Monday, September 10, 2012 - 10:00am SLAC, Bldg. 137, Room 226 Keoki Seu Seminar: With the advent of free electron...

87

RF Pulse Design for Parallel Excitation in Magnetic Resonance Imaging  

E-Print Network [OSTI]

Parallel excitation is an emerging technique to improve or accelerate multi-dimensional spatially selective excitations in magnetic resonance imaging (MRI) using multi-channel transmit arrays. The technique has potential in many applications...

Liu, Yinan

2012-07-16T23:59:59.000Z

88

acoustic nuclear magnetic resonance: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

acoustic nuclear magnetic resonance First Page Previous Page 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1...

89

Magnetic resonance spectroscopic imaging using parallel transmission at 7T  

E-Print Network [OSTI]

Conventional magnetic resonance spectroscopic imaging (MRSI), also known as phase-encoded (PE) chemical shift imaging (CSI), suffers from both low signal-to-noise ratio (SNR) of the brain metabolites, as well as inflexible ...

Gagoski, Borjan Aleksandar

2011-01-01T23:59:59.000Z

90

Modeling Left Ventricle Wall Motion Using Tagged Magnetic Resonance Imaging  

E-Print Network [OSTI]

A two-parameter computational model is proposed for the study of the regional motion of the left ventricle (LV) wall using tagged magnetic resonance imaging (tMRI) data. In this model, the LV wall motion is mathematically ...

Alenezy, Mohammed D.

2009-04-17T23:59:59.000Z

91

Improvements in magnetic resonance imaging excitation pulse design  

E-Print Network [OSTI]

This thesis focuses on the design of magnetic resonance imaging (MRI) radio-frequency (RF) excitation pulses, and its primary contributions are made through connections with the novel multiple-system single-output (MSSO) ...

Zelinski, Adam Charles

2008-01-01T23:59:59.000Z

92

Scalar operators in solid-state NMR  

SciTech Connect (OSTI)

Selectivity and resolution of solid-state NMR spectra are determined by dispersion of local magnetic fields originating from relaxation effects and orientation-dependent resonant frequencies of spin nuclei. Theoretically, the orientation-dependent resonant frequencies can be represented by a set of irreducible tensors. Among these tensors, only zero rank tensors (scalar operators) are capable of providing high resolution NMR spectra. This thesis presents a series of new developments in high resolution solid-state NMR concerning the reconstruction of various scalar operators motion in solid C{sub 60} is analyzed.

Sun, Boqin

1991-11-01T23:59:59.000Z

93

Nuclear magnetic resonance study of methane adsorbed on porous silicon  

E-Print Network [OSTI]

NUCLEAR MAGNETIC RESONANCE STUDY OF METHANE ADSORBED ON POROUS SILICON A Thesis by FENG I I Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE... May 1992 Major Subject: Physics NUCLEAR MAGNETIC RESONANCE STUDY OF METHANE ADSORBED ON POROUS SILICON A Thesis by FENG LI Approved as to style and content by: . P. Kirk (Chair of Committee) i G. Agnolet (Member) J. H. Ross, r (Member) M...

Li, Feng

1992-01-01T23:59:59.000Z

94

Method for nuclear magnetic resonance imaging  

DOE Patents [OSTI]

A method for in vivo NMR imaging of the blood vessels and organs of a patient characterized by using a dark dye-like imaging substance consisting essentially of a stable, high-purity concentration of D/sub 2/O in a solution with water.

Kehayias, J.J.; Joel, D.D.; Adams, W.H.; Stein, H.L.

1988-05-26T23:59:59.000Z

95

Fiber-Optic Stethoscope: A Cardiac Monitoring and Gating System for Magnetic Resonance Microscopy  

E-Print Network [OSTI]

during magnetic resonance imaging (MRI) is the distortion of the ECG due to electromagnetic interference

96

Magnetic structure of the low-dimensional magnet NaCu{sub 2}O{sub 2}: {sup 63,65}Cu and {sup 23}Na NMR studies  

SciTech Connect (OSTI)

The magnetic structure of a quasi-one-dimensional frustrated NaCu{sub 2}O{sub 2} magnet single crystal is studied by NMR. The spatial orientation of the planar spin spirals in the copper-oxygen Cu{sup 2+}-O chains is determined, and its evolution as a function of the applied magnetic field direction is analyzed.

Sadykov, A. F., E-mail: sadykov@imp.uran.ru; Gerashchenko, A. P.; Piskunov, Yu. V.; Ogloblichev, V. V.; Smolnikov, A. G.; Verkhovskii, S. V.; Buzlukov, A. L.; Arapova, I. Yu. [Russian Academy of Sciences, Institute of Metal Physics, Ural Branch (Russian Federation); Furukawa, Y. [Iowa State University, Ames Laboratory (United States); Yakubovskii, A. Yu. [National Research Centre Kurchatov Institute (Russian Federation); Bush, A. A. [Moscow State Technical University of Radio Engineering, Electronics, and Automation (Russian Federation)

2014-11-15T23:59:59.000Z

97

Advanced slow-magic angle spinning probe for magnetic resonance imaging and spectroscopy  

DOE Patents [OSTI]

The present invention relates to a probe and processes useful for magnetic resonance imaging and spectroscopy instruments. More particularly, the invention relates to a MR probe and processes for obtaining resolution enhancements of fluid objects, including live specimens, using an ultra-slow (magic angle) spinning (MAS) of the specimen combined with a modified phase-corrected magic angle turning (PHORMAT) pulse sequence. Proton NMR spectra were measured of the torso and the top part of the belly of a female BALBc mouse in a 2T field, while spinning the animal at a speed of 1.5 Hz. Results show that even in this relatively low field with PHORMAT, an isotropic spectrum is obtained with line widths that are a factor 4.6 smaller than those obtained in a stationary mouse. Resolution of 1H NMR metabolite spectra are thus significantly enhanced. Results indicate that PHORMAT has the potential to significantly increase the utility of 1H NMR spectroscopy for in vivo biochemical, biomedical and/or medical applications involving large-sized biological objects such as mice, rats and even humans within a hospital setting. For small-sized objects, including biological objects, such as excised tissues, organs, live bacterial cells, and biofilms, use of PASS at a spinning rate of 30 Hz and above is preferred.

Wind, Robert A.; Hu, Jian Zhi; Minard, Kevin R.; Rommereim, Donald N.

2006-01-24T23:59:59.000Z

98

Spin microscope based on optically detected magnetic resonance  

DOE Patents [OSTI]

The invention relates to scanning magnetic microscope which has a photoluminescent nanoprobe implanted in the tip apex of an atomic force microscope (AFM), a scanning tunneling microscope (STM) or a near-field scanning optical microscope (NSOM) and exhibits optically detected magnetic resonance (ODMR) in the vicinity of unpaired electron spins or nuclear magnetic moments in the sample material. The described spin microscope has demonstrated nanoscale lateral resolution and single spin sensitivity for the AFM and STM embodiments.

Berman, Gennady P. (Los Alamos, NM); Chernobrod, Boris M. (Los Alamos, NM)

2007-12-11T23:59:59.000Z

99

Spin microscope based on optically detected magnetic resonance  

DOE Patents [OSTI]

The invention relates to scanning magnetic microscope which has a photoluminescent nanoprobe implanted in the tip apex of an atomic force microscope (AFM), a scanning tunneling microscope (STM) or a near-field scanning optical microscope (NSOM) and exhibits optically detected magnetic resonance (ODMR) in the vicinity of unpaired electron spins or nuclear magnetic moments in the sample material. The described spin microscope has demonstrated nanoscale lateral resolution and single spin sensitivity for the AFM and STM embodiments.

Berman, Gennady P. (Los Alamos, NM); Chernobrod, Boris M. (Los Alamos, NM)

2010-06-29T23:59:59.000Z

100

Spin microscope based on optically detected magnetic resonance  

DOE Patents [OSTI]

The invention relates to scanning magnetic microscope which has a photoluminescent nanoprobe implanted in the tip apex of an atomic force microscope (AFM), a scanning tunneling microscope (STM) or a near-field scanning optical microscope (NSOM) and exhibits optically detected magnetic resonance (ODMR) in the vicinity of impaired electron spins or nuclear magnetic moments in the sample material. The described spin microscope has demonstrated nanoscale lateral resolution and single spin sensitivity for the AFM and STM embodiments.

Berman, Gennady P. (Los Alamos, NM); Chernobrod, Boris M. (Los Alamos, NM)

2009-11-10T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Spin microscope based on optically detected magnetic resonance  

DOE Patents [OSTI]

The invention relates to scanning magnetic microscope which has a photoluminescent nanoprobe implanted in the tip apex of an atomic force microscope (AFM), a scanning tunneling microscope (STM) or a near-field scanning optical microscope (NSOM) and exhibits optically detected magnetic resonance (ODMR) in the vicinity of unpaired electron spins or nuclear magnetic moments in the sample material. The described spin microscope has demonstrated nanoscale lateral resolution and single spin sensitivity for the AFM and STM embodiments.

Berman, Gennady P. (Los Alamos, NM); Chernobrod, Boris M. (Los Alamos, NM)

2009-10-27T23:59:59.000Z

102

Optical pumping magnetic resonance in high magnetic fields: Characterization of nuclear relaxation during pumping  

E-Print Network [OSTI]

Optical pumping magnetic resonance in high magnetic fields: Characterization of nuclear relaxation during pumping Matthew P. Augustine and Kurt W. Zilm Department of Chemistry, Yale University, New Haven exchange with optically pumped Rb vapor is investigated in high magnetic field. Operation in a high field

Augustine, Mathew P.

103

Integrated microchip incorporating atomic magnetometer and microfluidic channel for NMR and MRI  

DOE Patents [OSTI]

An integral microfluidic device includes an alkali vapor cell and microfluidic channel, which can be used to detect magnetism for nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI). Small magnetic fields in the vicinity of the vapor cell can be measured by optically polarizing and probing the spin precession in the small magnetic field. This can then be used to detect the magnetic field of in encoded analyte in the adjacent microfluidic channel. The magnetism in the microfluidic channel can be modulated by applying an appropriate series of radio or audio frequency pulses upstream from the microfluidic chip (the remote detection modality) to yield a sensitive means of detecting NMR and MRI.

Ledbetter, Micah P. (Oakland, CA); Savukov, Igor M. (Los Alamos, NM); Budker, Dmitry (El Cerrito, CA); Shah, Vishal K. (Plainsboro, NJ); Knappe, Svenja (Boulder, CO); Kitching, John (Boulder, CO); Michalak, David J. (Berkeley, CA); Xu, Shoujun (Houston, TX); Pines, Alexander (Berkeley, CA)

2011-08-09T23:59:59.000Z

104

On the dynamics of magnetic fluids in magnetic resonance imaging  

E-Print Network [OSTI]

The hydrodynamics of magnetic fluids, often termed ferrofluids, has been an active area of research since the mid 1960s. However, it is only in the past twenty years that these fluids have begun to be used in magnetic ...

Cantillon-Murphy, Pdraig J

2008-01-01T23:59:59.000Z

105

Rotor Design for High Pressure Magic Angle Spinning Nuclear Magnetic Resonance  

SciTech Connect (OSTI)

High pressure magic angle spinning (MAS) nuclear magnetic resonance (NMR) with a sample spinning rate exceeding 2.1 kHz and pressure greater than 165 bar has never been realized. In this work, a new sample cell design is reported, suitable for constructing cells of different sizes. Using a 7.5 mm high pressure MAS rotor as an example, internal pressure as high as 200 bar at a sample spinning rate of 6 kHz is achieved. The new high pressure MAS rotor is re-usable and compatible with most commercial NMR set-ups, exhibiting low 1H and 13C NMR background and offering maximal NMR sensitivity. As an example of its many possible applications, this new capability is applied to determine reaction products associated with the carbonation reaction of a natural mineral, antigorite ((Mg,Fe2+)3Si2O5(OH)4), in contact with liquid water in water-saturated supercritical CO2 (scCO2) at 150 bar and 50 deg C. This mineral is relevant to the deep geologic disposal of CO2, but its iron content results in too many sample spinning sidebands at low spinning rate. Hence, this chemical system is a good case study to demonstrate the utility of the higher sample spinning rates that can be achieved by our new rotor design. We expect this new capability will be useful for exploring solid-state, including interfacial, chemistry at new levels of high-pressure in a wide variety of fields.

Turcu, Romulus V.F.; Hoyt, David W.; Rosso, Kevin M.; Sears, Jesse A.; Loring, John S.; Felmy, Andrew R.; Hu, Jian Z.

2013-01-01T23:59:59.000Z

106

Determining diffusion coefficients of ionic liquids by means of field cycling nuclear magnetic resonance relaxometry  

SciTech Connect (OSTI)

Field Cycling Nuclear Magnetic Resonance (FC NMR) relaxation studies are reported for three ionic liquids: 1-ethyl-3- methylimidazolium thiocyanate (EMIM-SCN, 220258 K), 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM-BF{sub 4}, 243318 K), and 1-butyl-3-methylimidazolium hexafluorophosphate (BMIM-PF{sub 6}, 258323 K). The dispersion of {sup 1}H spin-lattice relaxation rate R{sub 1}(?) is measured in the frequency range of 10 kHz20 MHz, and the studies are complemented by {sup 19}F spin-lattice relaxation measurements on BMIM-PF{sub 6} in the corresponding frequency range. From the {sup 1}H relaxation results self-diffusion coefficients for the cation in EMIM-SCN, BMIM-BF{sub 4}, and BMIM-PF{sub 6} are determined. This is done by performing an analysis considering all relevant intra- and intermolecular relaxation contributions to the {sup 1}H spin-lattice relaxation as well as by benefiting from the universal low-frequency dispersion law characteristic of Fickian diffusion which yields, at low frequencies, a linear dependence of R{sub 1} on square root of frequency. From the {sup 19}F relaxation both anion and cation diffusion coefficients are determined for BMIM-PF{sub 6}. The diffusion coefficients obtained from FC NMR relaxometry are in good agreement with results reported from pulsed- field-gradient NMR. This shows that NMR relaxometry can be considered as an alternative route of determining diffusion coefficients of both cations and anions in ionic liquids.

Kruk, D. [Faculty of Mathematics and Computer Science, University of Warmia and Mazury in Olsztyn, S?oneczna 54, PL-10710 Olsztyn (Poland); Universitt Bayreuth, Experimentalphysik II, 95440 Bayreuth (Germany); Meier, R.; Rssler, E. A. [Universitt Bayreuth, Experimentalphysik II, 95440 Bayreuth (Germany); Rachocki, A. [Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Pozna? (Poland); Korpa?a, A. [Department of Biophysics, Jagiellonian University Medical College, ?azarza 16, 31-530 Krakw, Poland and Institute of Physics, Jagiellonian University, Reymonta 4, 30-059 Krakw (Poland); Singh, R. K. [Ionic Liquid and Solid State Ionics Laboratory, Department of Physics, Banaras Hindu University, Varanasi 221 005 (India)

2014-06-28T23:59:59.000Z

107

E-Print Network 3.0 - abdominal magnetic resonance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

between men and women at rest and during lower Summary: resonance-compatible exercise bicycle, magnetic resonance imaging techniques, and custom data processing... at all. We have...

108

On transition from Alfvn resonance to forced magnetic reconnection  

SciTech Connect (OSTI)

We revisit the transition from Alfvn resonance to forced magnetic reconnection with a focus on the property of their singularities. As the driven frequency tends to zero, the logarithmic singularity of Alfvn resonance shifts to the power-law singularity of forced reconnection, due to merging of the two resonance layers. The transition criterion depends on either kinetic effects or dissipations that resolve the singularity. As an example, a small but finite resistivity ? is introduced to investigate the transition process. The transition threshold is then obtained as the driven frequency reaches a level of ?O((?/k){sup 1/3})

Luan, Q. [MOE Key Lab of Materials Modification by Beams and School of Physics and Optoelectrical Technology, Dalian University of Technology, Dalian 116024 (China); Wang, X., E-mail: xgwang@hit.edu.cn [Department of Physics, Harbin Institute of Technology, Harbin 150001 (China)

2014-07-15T23:59:59.000Z

109

Capillary toroid cavity detector for high pressure NMR  

DOE Patents [OSTI]

A Toroid Cavity Detector (TCD) is provided for implementing nuclear magnetic resonance (NMR) studies of chemical reactions under conditions of high pressures and temperatures. A toroid cavity contains an elongated central conductor extending within the toroid cavity. The toroid cavity and central conductor generate an RF magnetic field for NMR analysis. A flow-through capillary sample container is located within the toroid cavity adjacent to the central conductor to subject a sample material flowing through the capillary to a static magnetic field and to enable NMR spectra to be recorded of the material in the capillary under a temperature and high pressure environment.

Gerald, II, Rex E. (Brookfield, IL); Chen, Michael J. (Downers Grove, IL); Klingler, Robert J. (Glenview, IL); Rathke, Jerome W. (Honer Glen, IL); ter Horst, Marc (Chapel Hill, NC)

2007-09-11T23:59:59.000Z

110

Study of gas flow dynamics in porous and granular media with laser-polarized ?Xe NMR  

E-Print Network [OSTI]

This thesis presents Nuclear Magnetic Resonance (NMR) studies of gas flow dynamics in porous and granular media by using laser-polarized ?Xe . Two different physical processes, the gas transport in porous rock cores and ...

Wang, Ruopeng, 1972-

2005-01-01T23:59:59.000Z

111

Development of new parameters for structure determination and dynamic investigations on biomacromolecules by NMR  

E-Print Network [OSTI]

Nuclear magnetic resonance (NMR) spectroscopy is unique in the content of structural as well as dynamic information that it can provide at atomic resolution. The aim of this PhD-thesis was to contribute to the understanding ...

Duchardt, Elke, 1975-

2005-01-01T23:59:59.000Z

112

The Application of Dynamic Nuclear Polarization Enhanced NMR to Non-Equilibrium Systems  

E-Print Network [OSTI]

Nuclear magnetic resonance (NMR) yields remarkably detailed structural information about virtually any molecule. However, its application to non-equilibrium systems is hampered by a lack of sensitivity. To increase the amount of signal that can...

Bowen, Sean Michael

2012-02-14T23:59:59.000Z

113

On the validation of magnetic resonance velocimetry in single-phase turbulent pipe flows  

SciTech Connect (OSTI)

A nuclear magnetic resonance imaging technique is used to measure velocity distributions in turbulent pipe flows up to Re = 24580. While turbulent intensity is usually determined from signal attenuation, we deduce turbulent intensity from velocity distribution with no need to suppose a Gaussian distribution for velocity fluctuations. Skewness and flatness measurements are also presented in this paper. Comparison with DNS show good agreement and we show that NMR data is sufficiently accurate to provide turbulent viscosity profile. The low field system used in this study allow the suppression of susceptibility artifacts and thus open its use for studying two-phase flows. We postulate that the method used here could be applied to two-phase flows and would thus provide valuable information on turbulent viscosity models. (authors)

Jullien, P.; Lemonnier, H. [CEA Grenoble, DTN LITA SE2T, F-38054 Grenoble 9, (France)

2012-03-15T23:59:59.000Z

114

Original Research In Vivo Magnetic Resonance Imaging of the Human  

E-Print Network [OSTI]

Original Research In Vivo Magnetic Resonance Imaging of the Human Cervical Spinal Cord at 3 Tesla is feasible at 3 T. Key Words: MRI; 3 Tesla; cervical spinal cord; gradient echo; gray matter; white matter J, and pulsatile flow (9,10). Deficits in motor and sensory function from damage to the spinal cord are mainly due

Gorassini, Monica

115

Original Research Magnetic Resonance Image-Guided Trans-Septal  

E-Print Network [OSTI]

vasculature. Key Words: interventional; magnetic resonance imaging; trans-septal catheterization; cardiac; MR with a pigtail catheter in the aorta and the use of His bundle/coronary sinus catheters (1), and, more recently from a percutaneous femoral vein ap- proach. MATERIALS AND METHODS Animal Model The Institutional

Atalar, Ergin

116

Magnetite-Loaded Polymeric Micelles as Ultrasensitive Magnetic-Resonance  

E-Print Network [OSTI]

Magnetite-Loaded Polymeric Micelles as Ultrasensitive Magnetic-Resonance Probes** By Hua Ai* Polymeric micelles offer a powerful multifunctional plat- form for drug delivery and diagnostic imaging- tions, polymeric micelles have also received increasing atten- tion in diagnostic imaging applications

Gao, Jinming

117

Application of magnetic resonance microscopy to tissue engineering: A polylactide model  

E-Print Network [OSTI]

Application of magnetic resonance microscopy to tissue engineering: A polylactide model K. J. L seeding; magnetic resonance mi- croscopy; polylactide; tissue engineering INTRODUCTION Absorbable polymers Engineering Research Center, Clemson University, Clemson, South Carolina 29634-0905 2 Department of Radiology

118

Instrumentation for parallel magnetic resonance imaging  

E-Print Network [OSTI]

of the art of parallel MR imaging. First, a low-cost desktop MR scanner was developed (2.54 cm fields-of view) at low magnetic field strengths (25 T). The performance of the prototype was verified through bench...

Brown, David Gerald

2007-04-25T23:59:59.000Z

119

Homometallic and Heterometallic Antiferromagnetic Rings: Magnetic Properties Studied by Nuclear Magnetic Resonance  

SciTech Connect (OSTI)

The aim of the present thesis is to investigate the local magnetic properties of homometallic Cr{sub 8} antiferromagnetic (AFM) ring and the changes occurring by replacing one Cr{sup 3+} ion with diamagnetic Cd{sup 2+} (Cr{sub 7}Cd) and with Ni{sup 2+} (Cr{sub 7}Ni). In the heterometallic ring a redistribution of the local magnetic moment is expected in the low temperature ground state. We have investigated those changes by both {sup 53}Cr-NMR and {sup 19}F-NMR. We have determined the order of magnitude of the transferred hyperfine coupling constant {sup 19}F - M{sup +} where M{sup +} = Cr{sup 3+}, Ni{sup 2+} in the different rings. This latter result gives useful information about the overlapping of the electronic wavefunctions involved in the coordinative bond.

Casadei, Cecilia

2012-05-09T23:59:59.000Z

120

Dynamics of water-alcohol mixtures: Insights from nuclear magnetic resonance, broadband dielectric spectroscopy, and triplet solvation dynamics  

SciTech Connect (OSTI)

We combine {sup 2}H nuclear magnetic resonance (NMR), broadband dielectric spectroscopy (BDS), and triplet solvation dynamics (TSD) to investigate molecular dynamics in glass-forming mixtures of water and propylene glycol in very broad time and temperature ranges. All methods yield consistent results for the ? process of the studied mixtures, which hardly depends on the composition and shows Vogel-Fulcher temperature dependence as well as Cole-Davidson spectral shape. The good agreement between BDS and TDS data reveals that preferential solvation of dye molecules in microheterogeneous mixtures does not play an important role. Below the glass transition temperature T{sub g}, NMR and BDS studies reveal that the ? process of the mixtures shows correlation times, which depend on the water concentration, but exhibit a common temperature dependence, obeying an Arrhenius law with an activation energy of E{sub a} = 0.54? eV, as previously reported for mixtures of water with various molecular species. Detailed comparison of NMR and BDS correlation functions for the ? process unravels that the former decay faster and more stretched than the latter. Moreover, the present NMR data imply that propylene glycol participates in the ? process and, hence, it is not a pure water process, and that the mechanism for molecular dynamics underlying the ? process differs in mixtures of water with small and large molecules.

Sauer, D.; Schuster, B.; Rosenstihl, M.; Schneider, S.; Blochowicz, T.; Sthn, B.; Vogel, M. [Institut fr Festkrperphysik, Technische Universitt Darmstadt, Hochschulstrae 6, 64289 Darmstadt (Germany)] [Institut fr Festkrperphysik, Technische Universitt Darmstadt, Hochschulstrae 6, 64289 Darmstadt (Germany); Talluto, V.; Walther, T. [Institut fr Angewandte Physik, Technische Universitt Darmstadt, Schlossgartenstrae 7, 64289 Darmstadt (Germany)] [Institut fr Angewandte Physik, Technische Universitt Darmstadt, Schlossgartenstrae 7, 64289 Darmstadt (Germany)

2014-03-21T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Characterization of proton exchange membrane materials for fuel cells by solid state nuclear magnetic resonance  

SciTech Connect (OSTI)

Solid-state nuclear magnetic resonance (NMR) has been used to explore the nanometer-scale structure of Nafion, the widely used fuel cell membrane, and its composites. We have shown that solid-state NMR can characterize chemical structure and composition, domain size and morphology, internuclear distances, molecular dynamics, etc. The newly-developed water channel model of Nafion has been confirmed, and important characteristic length-scales established. Nafion-based organic and inorganic composites with special properties have also been characterized and their structures elucidated. The morphology of Nafion varies with hydration level, and is reflected in the changes in surface-to-volume (S/V) ratio of the polymer obtained by small-angle X-ray scattering (SAXS). The S/V ratios of different Nafion models have been evaluated numerically. It has been found that only the water channel model gives the measured S/V ratios in the normal hydration range of a working fuel cell, while dispersed water molecules and polymer ribbons account for the structures at low and high hydration levels, respectively.

Kong, Zueqian

2010-03-15T23:59:59.000Z

122

Nuclear Magnetic Resonance Studies on Vanadium(IV) Electrolyte Solutions for Vanadium Redox Flow Battery  

SciTech Connect (OSTI)

The vanadium (IV) electrolyte solutions with various vanadium concentrations are studied by variable temperature 1H and 17O Nuclear Magnetic Resonance (NMR) spectroscopy. The structure and kinetics of vanadium (IV) species in the electrolyte solutions are explored with respect to vanadium concentration and temperature. It was found that the vanadium (IV) species exist as hydrated vanadyl ion, i.e. [VO(H2O)5]2+ forming an octahedral coordination with vanadyl oxygen in the axial position and the remaining positions occupied by water molecules. This hydrated vanadyl ion structure is stable in vanadium concentrations up to 3M and in the temperature range of 240 to 340 K. The sulfate anions in the electrolyte solutions are found to be weekly bound to this hydrated vanadyl ion and occupies its second coordination sphere. The possible effects of these sulfate anions in proton and water exchange between vanadyl ion and solvent molecules are discussed based on 1H and 17O NMR results.

Vijayakumar, M.; Burton, Sarah D.; Huang, Cheng; Li, Liyu; Yang, Zhenguo; Graff, Gordon L.; Liu, Jun; Hu, Jian Z.; Skyllas-Kazacos, Maria

2010-11-15T23:59:59.000Z

123

Optically Detected Magnetic Resonance Studies on ?-conjugated semiconductor systems  

SciTech Connect (OSTI)

Optically Detected Magnetic Resonance (ODMR) techniques were used to investigate the dynamics of excitons and charge carriers in ?-conjugated organic semiconductors. Degradation behavior of the negative spin-1/2 electroluminescence-detected magnetic resonance (ELDMR) was observed in Alq3 devices. The increase in the resonance amplitude implies an increasing bipolaron formation during degradation, which might be the result of growth of charge traps in the device. The same behavior of the negative spin-1/2 ELDMR was observed in 2wt% Rubrene doped Tris(8-hydroxyquinolinato)aluminium (Alq3) devices. However, with increasing injection current, a positive spin-1/2 ELDMR, together with positive spin 1 triplet powder patterns at {delta}m{sub S}={+-}1 and {delta}m{sub S}={+-}2, emerges. Due to the similarities in the frequency dependences of single and double modulated ELDMR and the photoluminescence-detected magnetic resonance (PLDMR) results in poly[2-methoxy-5-(2 -ethyl-hexyloxy)-1,4-phenyl ene vinylene] (MEH-PPV) films, the mechanism for this positive spin-1/2 ELDMR was assigned to enhanced triplet-polaron quenching under resonance conditions. The ELDMR in rubrene doped Alq3 devices provides a path to investigate charge distribution in the device under operational conditions. Combining the results of several devices with different carrier blocking properties and the results from transient EL, it was concluded trions not only exist near buffer layer but also exist in the electron transport layer. This TPQ model can also be used to explain the positive spin-1/2 PLDMR in poly(3-hexylthiophene) (P3HT) films at low temperature and in MEH-PPV films at various temperatures up to room temperature. Through quantitative analysis, TE-polaron quenching (TPQ) model is shown having the ability to explain most behaviors of the positive spin-1/2 resonance. Photocurrent detected magnetic resonance (PCDMR) studies on MEH-PPV devices revealed a novel transient resonance signal. The signal may originate from the higher concentration of deep traps near cathode. A quantitative analysis based on this assumption was carried out and found to be consistent with the experimental results.

Chen, Ying

2011-12-06T23:59:59.000Z

124

Precise wavefunction engineering with magnetic resonance  

E-Print Network [OSTI]

Controlling quantum fluids at their fundamental length scale will yield superlative quantum simulators, precision sensors, and spintronic devices. This scale is typically below the optical diffraction limit, precluding precise wavefunction engineering using optical potentials alone. We present a protocol to rapidly control the phase and density of a quantum fluid down to the healing length scale using strong time-dependent coupling between internal states of the fluid in a magnetic field gradient. We demonstrate this protocol by simulating the creation of a single stationary soliton and double soliton states in a Bose-Einstein condensate with control over the individual soliton positions and trajectories, using experimentally feasible parameters. Such states are yet to be realized experimentally, and are a path towards engineering soliton gases and exotic topological excitations.

L. M. Bennie; P. B. Wigley; S. S. Szigeti; M. Jasperse; J. J. Hope; L. D. Turner; R. P. Anderson

2014-12-22T23:59:59.000Z

125

Magnetic Resonance Imaging 1 A new global optimization algorithm and its application to a  

E-Print Network [OSTI]

Magnetic Resonance Imaging 1 A new global optimization algorithm and its application to a Magnetic-cost, low-field multipolar magnet for Magnetic Resonance Imaging with a high field uniformity, the proposed method em- ploys, as local search engine, a derivative free procedure. Under reasonable

Neumaier, Arnold

126

X-ray resonant magnetic scattering from structurally and magnetically rough interfaces in multilayered systems. I. Specular reflectivity  

E-Print Network [OSTI]

X-ray resonant magnetic scattering from structurally and magnetically rough interfaces formulation of x-ray resonant magnetic scattering from rough surfaces and interfaces is given for specular/Fe multilayer. DOI: 10.1103/PhysRevB.68.224409 PACS number s : 75.70.Cn, 61.10.Kw I. INTRODUCTION X-ray

Haskel, Daniel

127

Effect of energy and momentum conservation on fluid resonances for resonant magnetic perturbations in a tokamak  

SciTech Connect (OSTI)

In this paper, the impact of momentum and energy conservation of the collision operator in the kinetic description for Resonant Magnetic Perturbations (RMPs) in a tokamak is studied. The particle conserving differential collision operator of Ornstein-Uhlenbeck type is supplemented with integral parts such that energy and momentum are conserved. The application to RMP penetration in a tokamak shows that energy conservation in the electron collision operator is important for the quantitative description of plasma shielding effects at the resonant surface. On the other hand, momentum conservation in the ion collision operator does not significantly change the results.

Leitner, Peter; Heyn, Martin F.; Kernbichler, Winfried [Fusion@AW, Institut fr Theoretische PhysikComputational Physics, TU Graz, Petersgasse 16, A-8010 Graz (Austria); Ivanov, Ivan B. [Fusion@AW, Institut fr Theoretische PhysikComputational Physics, TU Graz, Petersgasse 16, A-8010 Graz (Austria); St. Petersburg State University, Institute of Physics, Ulyanovskaya 1, Petrodvoretz 198504 (Russian Federation); Petersburg Nuclear Physics Institute, 188300 Gatchina, Leningrad Oblast (Russian Federation); Kasilov, Sergei V. [Fusion@AW, Institut fr Theoretische PhysikComputational Physics, TU Graz, Petersgasse 16, A-8010 Graz (Austria); Institute of Plasma Physics, National Science Center Kharkov Institute of Physics and Technology, Ul. Akademicheskaya 1, 61108 Kharkov (Ukraine)

2014-06-15T23:59:59.000Z

128

Classical Computing in Nuclear Magnetic MARTA ROSELL O-MERINO, MATTHIAS BECHMANN,  

E-Print Network [OSTI]

Classical Computing in Nuclear Magnetic Resonance MARTA ROSELL O-MERINO, MATTHIAS BECHMANN of matter to perform non classical in materio computation, we show how to use NMR to perform classical, in materio computing, universal gates, trajectories 1 INTRODUCTION Nuclear Magnetic Resonance (NMR) is used

Stepney, Susan

129

Continuum resonance induced electromagnetic torque by a rotating plasma response to static resonant magnetic perturbation field  

SciTech Connect (OSTI)

A numerical study is carried out, based on a simple toroidal tokamak equilibrium, to demonstrate the radial re-distribution of the electromagnetic torque density, as a result of a rotating resistive plasma (linear) response to a static resonant magnetic perturbation field. The computed electromagnetic torque peaks at several radial locations even in the presence of a single rational surface, due to resonances between the rotating response, in the plasma frame, and both Alfven and sound continuum waves. These peaks tend to merge together to form a rather global torque distribution, when the plasma resistivity is large. The continuum resonance induced net electromagnetic torque remains finite even in the limit of an ideal plasma.

Liu Yueqiang; Connor, J. W.; Cowley, S. C.; Ham, C. J.; Hastie, R. J.; Hender, T. C. [Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon OX14 3DB (United Kingdom)

2012-10-15T23:59:59.000Z

130

Methods for magnetic resonance analysis using magic angle technique  

DOE Patents [OSTI]

Methods of performing a magnetic resonance analysis of a biological object are disclosed that include placing the object in a main magnetic field (that has a static field direction) and in a radio frequency field; rotating the object at a frequency of less than about 100 Hz around an axis positioned at an angle of about 54.degree.44' relative to the main magnetic static field direction; pulsing the radio frequency to provide a sequence that includes a phase-corrected magic angle turning pulse segment; and collecting data generated by the pulsed radio frequency. In particular embodiments the method includes pulsing the radio frequency to provide at least two of a spatially selective read pulse, a spatially selective phase pulse, and a spatially selective storage pulse. Further disclosed methods provide pulse sequences that provide extended imaging capabilities, such as chemical shift imaging or multiple-voxel data acquisition.

Hu, Jian Zhi (Richland, WA); Wind, Robert A. (Kennewick, WA); Minard, Kevin R. (Kennewick, WA); Majors, Paul D. (Kennewick, WA)

2011-11-22T23:59:59.000Z

131

NMR/MRI with hyperpolarized gas and high Tc SQUID  

DOE Patents [OSTI]

A method and apparatus for the detection of nuclear magnetic resonance (NMR) signals and production of magnetic resonance imaging (MRI) from samples combines the use of hyperpolarized inert gases to enhance the NMR signals from target nuclei in a sample and a high critical temperature (Tc) superconducting quantum interference device (SQUID) to detect the NMR signals. The system operates in static magnetic fields of 3 mT or less (down to 0.1 mT), and at temperatures from liquid nitrogen (77K) to room temperature. Sample size is limited only by the size of the magnetic field coils and not by the detector. The detector is a high Tc SQUID magnetometer designed so that the SQUID detector can be very close to the sample, which can be at room temperature.

Schlenga, Klaus (Eggenstein, DE); de Souza, Ricardo E. (Recife, BR); Wong-Foy, Annjoe (Berkeley, CA); Clarke, John (Berkeley, CA); Pines, Alexander (Berkeley, CA)

2000-01-01T23:59:59.000Z

132

High field nuclear magnetic resonance in transition metal substituted BaFe{sub 2}As{sub 2}  

SciTech Connect (OSTI)

We report high field {sup 75}As nuclear magnetic resonance (NMR) measurements on Co and Cu substituted BaFe{sub 2}As{sub 2} single crystals displaying same structural/magnetic transition T{sub 0}?128??K. From our anisotropy studies in the paramagnetic state, we strikingly found virtually identical quadrupolar splitting and consequently the quadrupole frequency ?{sub Q}?2.57(1)??MHz for both compounds, despite the claim that each Cu delivers 2 extra 3d electrons in BaFe{sub 2}As{sub 2} compared to Co substitution. These results allow us to conclude that a subtle change in the crystallographic structure, particularly in the FeAs tetrahedra, must be the most probable tuning parameter to determine T{sub 0} in this class of superconductors rather than electronic doping. Furthermore, our NMR data around T{sub 0} suggest coexistence of tetragonal/paramagnetic and orthorhombic/antiferromagnetic phases between the structural and the spin density wave magnetic phase transitions, similarly to what was reported for K-doped BaFe{sub 2}As{sub 2} [Urbano et al., Phys. Rev. Lett. 105, 107001 (2010)].

Garitezi, T. M., E-mail: thalesmg@ifi.unicamp.br; Lesseux, G. G.; Rosa, P. F. S.; Adriano, C.; Pagliuso, P. G.; Urbano, R. R. [Instituto de Fsica Gleb Wataghin, UNICAMP, Campinas, SP 13083-859 (Brazil); Reyes, A. P.; Kuhns, P. L. [National High Magnetic Field Laboratory, FSU, Tallahassee, Florida 32306-4005 (United States)

2014-05-07T23:59:59.000Z

133

The magnetic resonance force microscope: A new microscopic probe of magnetic materials  

SciTech Connect (OSTI)

The magnetic resonance force microscope (MRFM) marries the techniques of magnetic resonance imaging (MRI) and atomic force microscopy (AFM), to produce a three-dimensional imaging instrument with high, potentially atomic-scale, resolution. The principle of the MRFM has been successfully demonstrated in numerous experiments. By virtue of its unique capabilities the MRFM shows promise to make important contributions in fields ranging from three-dimensional materials characterization to bio-molecular structure determination. Here the authors focus on its application to the characterization and study of layered magnetic materials; the ability to illuminate the properties of buried interfaces in such materials is a particularly important goal. While sensitivity and spatial resolution are currently still far from their theoretical limits, they are nonetheless comparable to or superior to that achievable in conventional MRI. Further improvement of the MRFM will involve operation at lower temperature, application of larger field gradients, introduction of advanced mechanical resonators and improved reduction of the spurious coupling when the magnet is on the resonator.

Hammel, P.C.; Zhang, Z. [Los Alamos National Lab., NM (United States); Midzor, M.; Roukes, M.L. [California Inst. of Tech., Pasadena, CA (United States); Wigen, P.E. [Ohio State Univ., Columbus, OH (United States); Childress, J.R. [Univ. of Florida, Gainesville, FL (United States)

1997-08-06T23:59:59.000Z

134

Magnetic Resonant Coupling As a Potential Means for Wireless Power Transfer to Multiple Small Receivers  

E-Print Network [OSTI]

Wireless power transfer via magnetic resonant coupling is experimentally demonstrated in a system with a large source coil and either one or two small receivers. Resonance between source and load coils is achieved with ...

Cannon, Benjamin Louis

135

Carbon-13 nuclear magnetic resonance studies of glycolysis in protozoa  

E-Print Network [OSTI]

in the ratio of 1:2:8:3. 17 ~ ~ CHg-COSH CHg-COSH CHg-CO)H ~ CH2-COSH ~ CHg-COSH HACH)-CO(H FIGURE 7. Simulated coupling patterns for the C-2 of succinate. (a) [1, 2- C]; (b) [U- C]; (c) [1, 2, 3- C]; (d) 1:1:1 addition of (a), (b), and (c); (e) 1... May 1986 Major Subject: Chemistry CARBON-13 NUCLEAR MAGNETIC RESONANCE STUDIES OF GLYCOLYSIS IN PROTOZOA A Thesis by TERESA ANN RHOADES Approved as to style and content by: A. I. Scott (Chair of Committee) Marvin W. Rowe (h1ember) Neil E...

Rhoades, Teresa Ann

1986-01-01T23:59:59.000Z

136

Method of using a nuclear magnetic resonance spectroscopy standard  

SciTech Connect (OSTI)

(CH/sub 3/)/sub 3/SiNSO is produced by the reaction of ((CH/sub 3/)/sub 3/Si)/sub 2/NH with SO/sub 2/. Also produced in the reaction are ((CH/sub 3/)/sub 3/SI)/sub 2/O and a new solid compound (NH/sub 4/) ((CH/sub 3/)/sub 3/SiOSO/sub 2/). Both (CH/sub 3/)/sub 3/SiNSO and (NH/sub 4/) ((CH/sub 3/)/sub 3/SiOSO/sub 2/) have fluorescent properties. The reaction of the subject invention is used in a method of measuring the concentration of SO/sub 2/ pollutants in gases. By the method, a sample of gas is bubbled through a solution of ((CH/sub 3/)/sub 3/Si)/sub 2/NH, whereby any SO/sub 2/ present in the gas will react to produce the two fluorescent products. The measured fluorescence of these products can then be used to calculate the concentration of SO/sub 2/ in the original gas sample. The solid product (NH/sub 4/)(((CH/sub 3/)/sub 3/SiOSO/sub 2/) may be used as a standard in solid state NMR spectroscopy, wherein the resonance peaks of either /sup 1/H, /sup 13/C, /sup 15/N, or /sup 29/Si may be used as a reference.

Spicer, L. D.; Bennet, D. W.; Davis, J. F.

1985-07-16T23:59:59.000Z

137

Method of using a nuclear magnetic resonance spectroscopy standard  

DOE Patents [OSTI]

(CH.sub.3).sub.3 SiNSO is produced by the reaction of ((CH.sub.3).sub.3 Si).sub.2 NH with SO.sub.2. Also produced in the reaction are ((CH.sub.3).sub.3 Si).sub.2 O and a new solid compound [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ]. Both (CH.sub.3).sub.3 SiNSO and [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] have fluorescent properties. The reaction of the subject invention is used in a method of measuring the concentration of SO.sub.2 pollutants in gases. By the method, a sample of gas is bubbled through a solution of ((CH.sub.3).sub.3 Si).sub.2 NH, whereby any SO.sub.2 present in the gas will react to produce the two fluorescent products. The measured fluorescence of these products can then be used to calculate the concentration of SO.sub.2 in the original gas sample. The solid product [NH.sub.4 ][(CH.sub.3).sub.3 SiOSO.sub.2 ] may be used as a standard in solid state NMR spectroscopy, wherein the resonance peaks of either .sup.1 H, .sup.13 C, .sup.15 N, or .sup.29 Si may be used as a reference.

Spicer, Leonard D. (Salt Lake City, UT); Bennett, Dennis W. (Clemson, SC); Davis, Jon F. (Salt Lake City, UT)

1985-01-01T23:59:59.000Z

138

E-Print Network 3.0 - ankle magnetic resonance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Powered by Explorit Topic List Advanced Search Sample search results for: ankle magnetic resonance Page: << < 1 2 3 4 5 > >> 1 Evaluation of Methods That Locate the...

139

E-Print Network 3.0 - arch magnetic resonance Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The resonator having central frequency f0 5 GHz... are the development of magnetically tunable YIG band-pass ... Source: Srinivasan, Gopalan - Department of Physics, Oakland...

140

E-Print Network 3.0 - alzheimer-type magnetic resonance Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The resonator having central frequency f0 5 GHz... are the development of magnetically tunable YIG band-pass ... Source: Srinivasan, Gopalan - Department of Physics, Oakland...

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

E-Print Network 3.0 - acid-dcys-ser-lys-cys magnetic resonance...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The resonator having central frequency f0 5 GHz... are the development of magnetically tunable YIG band-pass ... Source: Srinivasan, Gopalan - Department of Physics, Oakland...

142

E-Print Network 3.0 - authentic magnetic resonance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The resonator having central frequency f0 5 GHz... are the development of magnetically tunable YIG band-pass ... Source: Srinivasan, Gopalan - Department of Physics, Oakland...

143

E-Print Network 3.0 - activatable magnetic resonance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

The resonator having central frequency f0 5 GHz... are the development of magnetically tunable YIG band-pass ... Source: Srinivasan, Gopalan - Department of Physics, Oakland...

144

Algorithmic Cooling in Liquid State NMR  

E-Print Network [OSTI]

Algorithmic cooling is a method that employs thermalization to increase the qubits' purification level, namely it reduces the qubit-system's entropy. We utilized gradient ascent pulse engineering (GRAPE), an optimal control algorithm, to implement algorithmic cooling in liquid state nuclear magnetic resonance. Various cooling algorithms were applied onto the three qubits of 13C2-trichloroethylene, cooling the system beyond Shannon's entropy bound in several different ways. For example, in one experiment a carbon qubit was cooled by a factor of 4.61. This work is a step towards potentially integrating tools of NMR quantum computing into in vivo magnetic resonance spectroscopy.

Yosi Atia; Yuval Elias; Tal Mor; Yossi Weinstein

2014-11-17T23:59:59.000Z

145

Investigating the Kinetics and Structural Effects of Azo Dye Photochemistry Using NMR With In Situ Laser Irradiation and Ab Initio (DFT) Calculations  

E-Print Network [OSTI]

Reversible cis-trans isomerisation of a series of commercially interesting yellow azo dyes has been studied using the technique of Nuclear Magnetic Resonance (NMR) spectroscopy with in situ laser irradiation. Photostationary ...

Gibson, David

2007-01-01T23:59:59.000Z

146

Nuclear quadrupole resonances in compact vapor cells: the crossover from the NMR to the NQR interaction regimes  

E-Print Network [OSTI]

We present the first experimental study that maps the transformation of nuclear quadrupole resonances from the pure nuclear quadrupole regime to the quadrupole-perturbed Zeeman regime. The transformation presents an interesting quantum-mechanical problem, since the quantization axis changes from being aligned along the axis of the electric-field gradient tensor to being aligned along the magnetic field. We achieve large nuclear quadrupole shifts for I = 3/2 131-Xe by using a 1 mm^3 cubic cell with walls of different materials. When the magnetic and quadrupolar interactions are of comparable size, perturbation theory is not suitable for calculating the transition energies. Rather than use perturbation theory, we compare our data to theoretical calculations using a Liouvillian approach and find excellent agreement.

E. A. Donley; J. L. Long; T. C. Liebisch; E. R. Hodby; T. A. Fisher; J. Kitching

2008-12-10T23:59:59.000Z

147

Three-dimensional nuclear magnetic resonance imaging of green-state ceramics  

SciTech Connect (OSTI)

Objective is the development of nuclear magnetic resonance imaging techniques and technology applicable to the nondestructive characterization of green-state ceramics. To this end, a three-dimensional (3-D) NMR imaging technique has been developed, based on a back-projection acquisition protocol in combination with image reconstruction techniques that are based on 3-D Radon transform inversion. The method incorporates the experimental flexibility to overcome many of the difficulties associated with imaging of solid and semisolid broad-line materials, and also provides contiguously sampled data in three dimensions. This technique has been evaluated as a nondestructive characterizauon method for determining the spatial distribution of organic additves in green-state injection-molded cylindrical Si{sub 3}N{sup 4} tensile specimens. The technique has been evaluated on the basis of providing moderate image resolution over large sample volumes, high resolution over smaller specimen volumes, and sensitivity to variations in the concentration of organics. Resolution of 200{mu}m has been obtained with excellent sensitivity to concentration. A detailed account of the 3-D imaging results obtained from the study, a discussion of the difficulties and limitations of the imaging technique, and suggestions for technique and system improvements are included.

Dieckman, S.L.; Gopalsami, N.; Ford, J.M.; Raptis, A.C.; Ellingson, W.A. (Argonne National Lab., IL (United States)); Rizo, P. (CEA Centre d'Etudes Nucleaires de Grenoble, 38 (France). Lab. d'Electronique et de Technologie de l'Informatique); Tracey, D.M.; Pujari, V.K. (Norton Co., Northboro, MA (United States))

1991-09-01T23:59:59.000Z

148

Molecular dynamics in liquid cyclopropane. Raman and magnetic nuclear resonance studies  

E-Print Network [OSTI]

723 Molecular dynamics in liquid cyclopropane. II. 2014 Raman and magnetic nuclear resonance as a function of temperature (155, 300 K) and pressure (up to 3 kilobars). 13C and 2H nuclear magnetic resonance experiments are performed in the same temperature range. The isotropic and anisotropic Raman profiles

Boyer, Edmond

149

A REAL TIME 3D VISUALIZATION PROTOTYPE FOR INTERVENTIONAL MAGNETIC RESONANCE IMAGING  

E-Print Network [OSTI]

A REAL TIME 3D VISUALIZATION PROTOTYPE FOR INTERVENTIONAL MAGNETIC RESONANCE IMAGING JENS FISCHER.weiss@pfh.research.philips.com HEIDRUN SCHUMANN University of Rostock, Computer Science Department, D­18051 Rostock,Germany schumann radiologists during invasive and non­invasive magnetic resonance imaging. We use pre­acquired and real time

Schumann, Heidrun

150

Saline absorption in calcium silicate brick observed by NMR scanning  

E-Print Network [OSTI]

Saline absorption in calcium silicate brick observed by NMR scanning L. Pel #3; , K. Kopinga #3 in calcium-silicate brick was investigated by nuclear magnetic resonance scanning. This method hasCl solution in a calcium silicate brick will be discussed. 2 Theory If gravity is neglected, the isothermal

Eindhoven, Technische Universiteit

151

Gravitational resonance spectroscopy with an oscillating magnetic field gradient in the GRANIT flow through arrangement  

E-Print Network [OSTI]

Gravitational resonance spectroscopy consists in measuring the energy spectrum of bouncing ultracold neutrons above a mirror by inducing resonant transitions between different discrete quantum levels. We discuss how to induce the resonances with a flow through arrangement in the GRANIT spectrometer, excited by an oscillating magnetic field gradient. The spectroscopy could be realized in two distinct modes (so called DC and AC) using the same device to produce the magnetic excitation. We present calculations demonstrating the feasibility of the newly proposed AC mode.

G. Pignol; S. Baessler; V. V. Nesvizhevsky; K. Protasov; D. Rebreyend; A. Yu. Voronin

2014-08-05T23:59:59.000Z

152

A 64-channel personal computer based image reconstruction system and applications in single echo acquisition magnetic resonance elastography and ultra-fast magnetic resonance imaging.  

E-Print Network [OSTI]

, this value is 2? x 42.5759 MHz/Tesla. This translates to a Larmor frequency of 200.238 MHz for the 4.7T magnet situated in the Magnetic Resonance Systems Lab (MRSL). In the presence of the static ????the proton population aligns itself according...

Yallapragada, Naresh

2009-05-15T23:59:59.000Z

153

Using NMR to Validate First-Principles Granular Flow Equations  

E-Print Network [OSTI]

Nuclear magnetic resonance (NMR) experiments are described for two granular-flow systems, the vibrofluidized bed and the gas-fluidized bed. Using pulsed field gradient, magnetic resonance imaging, and hyperpolarized gas NMR, detailed information is obtained for the density and motions of both grains and interstitial gas. For the vibrofluidized bed, the granular temperature profile is measured and compared with a first-principles formulation of granular hydrodynamics. For the gas-fluidized bed, dynamic correlations in the grain density are used to measure the bubble velocity and hyperpolarized xenon gas NMR is used to measure the bubble-emulsion exchange rate. A goal of these measurements is to verify in earth gravity first-principles theories of granular flows, which then can be used to make concrete predictions for granular flows in reduced gravity.

D. Candela; C. Huan; K. Facto; R. Wang; R. W. Mair; R. L. Walsworth

2005-10-23T23:59:59.000Z

154

Toroid cavity/coil NMR multi-detector  

DOE Patents [OSTI]

An analytical device for rapid, non-invasive nuclear magnetic resonance (NMR) spectroscopy of multiple samples using a single spectrometer is provided. A modified toroid cavity/coil detector (TCD), and methods for conducting the simultaneous acquisition of NMR data for multiple samples including a protocol for testing NMR multi-detectors are provided. One embodiment includes a plurality of LC resonant circuits including spatially separated toroid coil inductors, each toroid coil inductor enveloping its corresponding sample volume, and tuned to resonate at a predefined frequency using a variable capacitor. The toroid coil is formed into a loop, where both ends of the toroid coil are brought into coincidence. Another embodiment includes multiple micro Helmholtz coils arranged on a circular perimeter concentric with a central conductor of the toroid cavity.

Gerald, II, Rex E. (Brookfield, IL); Meadows, Alexander D. (Indianapolis, IN); Gregar, Joseph S. (Naperville, IL); Rathke, Jerome W. (Homer Glen, IL)

2007-09-18T23:59:59.000Z

155

Introduction to NMR Quantum Information Processing  

E-Print Network [OSTI]

After a general introduction to nuclear magnetic resonance (NMR), we give the basics of implementing quantum algorithms. We describe how qubits are realized and controlled with RF pulses, their internal interactions, and gradient fields. A peculiarity of NMR is that the internal interactions (given by the internal Hamiltonian) are always on. We discuss how they can be effectively turned off with the help of a standard NMR method called ``refocusing''. Liquid state NMR experiments are done at room temperature, leading to an extremely mixed (that is, nearly random) initial state. Despite this high degree of randomness, it is possible to investigate QIP because the relaxation time (the time scale over which useful signal from a computation is lost) is sufficiently long. We explain how this feature leads to the crucial ability of simulating a pure (non-random) state by using ``pseudopure'' states. We discuss how the ``answer'' provided by a computation is obtained by measurement and how this measurement differs from the ideal, projective measurement of QIP. We then give implementations of some simple quantum algorithms with a typical experimental result. We conclude with a discussion of what we have learned from NMR QIP so far and what the prospects for future NMR QIP experiments are.

R. Laflamme; E. Knill; D. G. Cory; E. M. Fortunato; T. Havel; C. Miquel; R. Martinez; C. Negrevergne; G. Ortiz; M. A. Pravia; Y. Sharf; S. Sinha; R. Somma; L. Viola

2002-07-30T23:59:59.000Z

156

Optical and magneto-optical properties of one-dimensional magnetized coupled resonator plasma photonic crystals  

SciTech Connect (OSTI)

In this paper, the optical and magneto-optical properties of one-dimensional magnetized coupled resonator plasma photonic crystals have been investigated. We use transfer matrix method to solve our magnetized coupled resonator plasma photonic crystals consist of dielectric and magnetized plasma layers. The results of the change in the optical and magneto-optical properties of structure as a result of the alteration in the structural properties such as thickness, plasma frequency and collision frequency, plasma filling factor, number of resonators and dielectric constant of dielectric layers and external magnetic field have been reported. The main feature of this structure is a good magneto-optical rotation that takes place at the defect modes and the edge of photonic band gap of our proposed optical magnetized plasma waveguide. Our outcomes demonstrate the potential applications of the device for tunable and adjustable filters or reflectors and active magneto-optic in microwave devices under structural parameter and external magnetic field.

Hamidi, S. M. [Laser and Plasma Research Institute, G. C., Shahid Beheshti University, Tehran 1983963113 (Iran, Islamic Republic of)

2012-01-15T23:59:59.000Z

157

Nanoscale NMR Spectroscopy and Imaging of Multiple Nuclear Species  

E-Print Network [OSTI]

Nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) are well-established techniques that provide valuable information in a diverse set of disciplines but are currently limited to macroscopic sample volumes. Here we demonstrate nanoscale NMR spectroscopy and imaging under ambient conditions of samples containing multiple nuclear species, using nitrogen-vacancy (NV) colour centres in diamond as sensors. With single, shallow NV centres in a diamond chip and samples placed on the diamond surface, we perform NMR spectroscopy and one-dimensional MRI on few-nanometre-sized samples containing $^1$H and $^{19}$F nuclei. Alternatively, we employ a high-density NV layer near the surface of a diamond chip to demonstrate wide-field optical NMR spectroscopy of nanoscale samples containing $^1$H, $^{19}$F, and $^{31}$P nuclei, as well as multi-species two-dimensional optical MRI with sub-micron resolution. For all diamond samples exposed to air, we identify a ubiquitous $^1$H NMR signal, consistent with a $\\sim 1$ nm layer of adsorbed hydrocarbons or water on the diamond surface and below any sample placed on the diamond. This work lays the foundation for nanoscale NMR and MRI applications such as studies of single proteins and functional biological imaging with subcellular resolution, as well as characterization of thin films with sub-nanometre resolution.

Stephen J. DeVience; Linh M. Pham; Igor Lovchinsky; Alexander O. Sushkov; Nir Bar-Gill; Chinmay Belthangady; Francesco Casola; Madeleine Corbett; Huiliang Zhang; Mikhail Lukin; Hongkun Park; Amir Yacoby; Ronald L. Walsworth

2014-06-12T23:59:59.000Z

158

Accelerating magnetic resonance imaging by unifying sparse models and multiple receivers  

E-Print Network [OSTI]

Magnetic resonance imaging (MRI) is an increasingly versatile diagnostic tool for a variety of medical purposes. During a conventional MRI scan, samples are acquired along a trajectory in the spatial Fourier transform ...

Weller, Daniel (Daniel Stuart)

2012-01-01T23:59:59.000Z

159

Highly Parallel Magnetic Resonance Imaging with a Fourth Gradient Channel for Compensation of RF Phase Patterns  

E-Print Network [OSTI]

A fourth gradient channel was implemented to provide slice dependent RF coil phase compensation for arrays in dual-sided or "sandwich" configurations. The use of highly parallel arrays for single echo acquisition magnetic resonance imaging allows...

Bosshard, John 1983-

2012-08-20T23:59:59.000Z

160

An iterative technique for refinement of selective excitations for magnetic resonance imaging  

E-Print Network [OSTI]

Selective RF pulses are needed or many application in magnetic resonance imaging (MRI). The desired excitation profile is omen used as the spectrum of the applied RF pulse; the modulation waveform of the RF pulse which approximately excites...

Lebsack, Eliot Todd

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

T2*-weighted magnetic resonance imaging used to detect coagulative necrosis in tissue  

E-Print Network [OSTI]

to prevent unnecessary collateral damage to surrounding healthy tissue. This research focuses on using T2*-weighted FLASH magnetic resonance imaging to detect irreversible changes in i . n vitro bovine liver tissue and tissuesimulating polyacrylamide gel...

Van Hyfte, John Bruce

1997-01-01T23:59:59.000Z

162

Eight-Channel Head Array and Control System for Parallel Transmit/Receive Magnetic Resonance Imaging  

E-Print Network [OSTI]

Interest in magnetic resonance imaging (MRI) at high fields strengths (3 Tesla and above) is driven by the associated improvements in signal-to-noise ratio and spectral resolution. In practice, however, technical challenges prevent these benefits...

Moody, Katherine

2014-08-11T23:59:59.000Z

163

A 16-Channel Receive Array Insert for Magnetic Resonance Imaging of the Breast at 7T  

E-Print Network [OSTI]

Breast cancer is the second leading cause of cancer death among females in the United States. Magnetic resonance imaging (MRI) has emerged as a powerful tool for detecting and evaluating the disease, with notable advantages over other modalities...

By, Samantha

2014-04-01T23:59:59.000Z

164

HST.583 Functional Magnetic Resonance Imaging: Data Acquisition and Analysis, Fall 2006  

E-Print Network [OSTI]

This team taught, multidisciplinary course covers the fundamentals of magnetic resonance imaging relevant to the conduct and interpretation of human brain mapping studies. The challenges inherent in advancing our knowledge ...

Gollub, Randy L.

165

Performing temperature feedback controlled tissue photo-coagulation using magnetic resonance thermometry  

E-Print Network [OSTI]

controlled photo-coagulation using magnetic resonance imaging as the non-invasive means of temperature feedback. The desired coagulation depth was controlled at a constant temperature of 40 degrees for different amounts of time and the actual coagulation...

Sampath, Smita

1999-01-01T23:59:59.000Z

166

Multimodal neuroimaging with simultaneous electroencephalogram and high-field functional magnetic resonance imaging  

E-Print Network [OSTI]

Simultaneous recording of electroencephalogram (EEG) and functional magnetic resonance imaging (tMRI) is an important emerging tool in functional neuroimaging with the potential to reveal new mechanisms for brain function ...

Purdon, Patrick L. (Patrick Lee), 1974-

2005-01-01T23:59:59.000Z

167

Magnetic resonance spectroscopic imaging with 2D spectroscopy for the detection of brain metabolites  

E-Print Network [OSTI]

While magnetic resonance imaging (MRI) derives its signal from protons in water, additional biochemical compounds are detectable in vivo within the proton spectrum. The detection and mapping of these much weaker signals ...

Kok, Trina

2012-01-01T23:59:59.000Z

168

Bounds on the entanglability of thermal states in liquid-state nuclear magnetic resonance  

E-Print Network [OSTI]

Theorists have recently shown that the states used in current nuclear magnetic resonance (NMIR) quantum computing experiments are not entangled. Yet it is widely believed that entanglement is a necessary resource in the ...

Yu, Terri M. (Terri Mak), 1981-

2003-01-01T23:59:59.000Z

169

Knowledge discovery using data mined from Nuclear Magnetic  

E-Print Network [OSTI]

Knowledge discovery using data mined from Nuclear Magnetic Resonance spectral images William J cyberinfrastructure Method Solid State ab initio calculations Nuclear Magnetic Resonance (NMR) Support Vector refined (and/or relaxed) structure, perform Self-Consistent Field calculation for electronic structure

Narasayya, Vivek

170

Developing improved nuclear magnetic resonance marginal oscillator spectrometers for advanced teaching laboratories  

E-Print Network [OSTI]

DEVELOPING IMPROVED NUCLEAR MAGNETIC RESONANCE MARGINAL OSCILLATOR SPECTROMETERS FOR ADVANCED TEACHING LABORATORIES A Thesis by FRANK PHILLIP WILLINGHAM Submitted to the Office of Graduate Studies of Texas ASM University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE D e cemb er 1988 Major Subject: Physics DEVELOPING IMPROVED NUCLEAR MAGNETIC RESONANCE MARGINAL OSCILLATOR SPECTROMETERS FOR ADVANCED TEACHING LABORATORIES A Thesis by FRANK PHILLIP...

Willingham, Frank Phillip

1988-01-01T23:59:59.000Z

171

Optically detected magnetic resonance studies on {pi}-conjugate polymers and novel carbon allotropes  

SciTech Connect (OSTI)

This report describes the following: introduction to photoluminescence detected magnetic resonance (PLDMR); introduction to {pi}-conjugated systems; PLDMR measurements on poly(p-phenylene)-type ladder polymers; PLMDR measurements on poly(p-phenylene ethylene); and PLDMR measurements on C{sub 70}, polythiophene, poly(p-phenylene vinylene) and Dan-40. Appendices to this report describe: Operation of ODMR (optically detected magnetic resonance) spectrometer; ODMR system parameters; and Special purpose circuitry.

Partee, J.

1999-02-12T23:59:59.000Z

172

The development of magnetic resonance imaging for the determination of porosity in reservoir core samples  

E-Print Network [OSTI]

THE DEVELOPMENT OF MAGNETIC RESONANCE IMAGING FOR THE DETERMINATION OF POROSITY IN RESERVOIR CORE SAMPLES A Thesis by BYRON BLAKE SHERMAN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1991 Major Subject: Petroleum Engineering THE DEVELOPMENT OF MAGNETIC RESONANCE IMAGING FOR THE DETERMINATION OF POROSITY IN RESERVOIR CORE SAMPLES A Thesis by BYRON BLAKE SHERMAN Approved...

Sherman, Byron Blake

1991-01-01T23:59:59.000Z

173

Application of nuclear magnetic resonance imaging and spectroscopy to fluids in porous media  

E-Print Network [OSTI]

APPLICATION OF NUCLEAR MAGNETIC RESONANCE IMAGING AND SPECTROSCOPY TO FLUIDS IN POROUS MEDIA A Thesis by SHANTHI SREE MANDAVA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1991 Major Subject: Chemical Engineering APPLICATION OF NUCLEAR MAGNETIC RESONANCE IMAGING AND SPECTROSCOPY TO FLUIDS IN POROUS MEDIA A Thesis by SHANTHI SREE MANDAVA Approved as to style and content by: A. Ted...

Mandava, Shanthi Sree

1991-01-01T23:59:59.000Z

174

Neutron resonance spin echo, bootstrap method for increasing the effective magnetic field  

E-Print Network [OSTI]

1195 Neutron resonance spin echo, bootstrap method for increasing the effective magnetic field R donné en spectrométrie d'echos de spins de neutrons. Les limites théoriques et techniques à l field intensity in Neutron Resonance Spin Echo (NRSE) spectrometry. The limits, theoretical as well

Paris-Sud XI, Université de

175

Syllabus Spring 2012 CHE 546 Nuclear Magnetic Resonance Spectroscopy  

E-Print Network [OSTI]

: (1) Two semesters of calculus-based physics, (2) Organic chemistry with an introduction to NMR (CHE 325/335) or equivalent experience, (3) Physical chemistry that includes an introduction to quantum have a book that you think is sufficient. Otherwise, we recommend the following text, which has very

Raina, Ramesh

176

Nuclear Magnetic Resonance Studies of Resorcinol-Formaldehyde Aerogels  

SciTech Connect (OSTI)

In this article we report a detailed study of resorcinol-formaldehyde (RF) aerogels prepared under different processing conditions, [resorcinol]/[catalyst] (R/C) ratios in the starting sol-gel solutions, using continuous flow hyperpolarized 129Xe NMR in combination with solid-state 13C and two-dimensional wide-line separation (2D-WISE) NMR techniques. The degree of polymerization and the mobility of the cross-linking functional groups in RF aerogels are examined and correlated with the R/C ratios. The origin of different adsorption regions is evaluated using both co-adsorption of chloroform and 2D EXSY 129Xe NMR. A hierarchical set of Xe exchange processes in RF aerogels is found using 2D EXSY 129Xe NMR. The exchange of Xe gas follows the sequence (from fastest to slowest): mesopores with free gas, gas in meso- and micro-pores, free gas with micropores, and, finally, among micropore sites. The volume-to-surface-area (Vg/S) ratios for aerogels are measured for the first time without the use of geometric models. The Vg/S parameter, which is related both to the geometry and the interconnectivity of the pore space, has been found to correlate strongly with the R/C ratio and exhibits an unusually large span: an increase in the R/C ratio from 50 to 500 results in about a 5-fold rise in Vg/S.

Moudrakovski, Igor L.; Ratcliffe, C I.; Ripmeester, J A.; Wang, Li Q.; Exarhos, Gregory J.; Baumann, T; Satcher, J H.

2005-06-09T23:59:59.000Z

177

Respiratory Amplitude Guided 4-Dimensional Magnetic Resonance Imaging  

SciTech Connect (OSTI)

Purpose: To evaluate the feasibility of prospectively guiding 4-dimensional (4D) magnetic resonance imaging (MRI) image acquisition using triggers at preselected respiratory amplitudes to achieve T{sub 2} weighting for abdominal motion tracking. Methods and Materials: A respiratory amplitude-based triggering system was developed and integrated into a commercial turbo spin echo MRI sequence. Initial feasibility tests were performed on healthy human study participants. Four respiratory states, the middle and the end of inhalation and exhalation, were used to trigger 4D MRI image acquisition of the liver. To achieve T{sub 2} weighting, the echo time and repetition time were set to 75 milliseconds and 4108 milliseconds, respectively. Single-shot acquisition, together with parallel imaging and partial k-space imaging techniques, was used to improve image acquisition efficiency. 4D MRI image sets composed of axial or sagittal slices were acquired. Results: Respiratory data measured and logged by the MRI scanner showed that the triggers occurred at the appropriate respiratory levels. Liver motion could be easily observed on both 4D MRI image datasets by sensing either the change of liver in size and shape (axial) or diaphragm motion (sagittal). Both 4D MRI image datasets were T{sub 2}-weighted as expected. Conclusions: This study demonstrated the feasibility of achieving T{sub 2}-weighted 4D MRI images using amplitude-based respiratory triggers. With the aid of the respiratory amplitude-based triggering system, the proposed method is compatible with most MRI sequences and therefore has the potential to improve tumor-tissue contrast in abdominal tumor motion imaging.

Hu, Yanle, E-mail: yhu@radonc.wustl.edu [Department of Radiation Oncology, Washington University School of Medicine, St. Louis, Missouri (United States)] [Department of Radiation Oncology, Washington University School of Medicine, St. Louis, Missouri (United States); Caruthers, Shelton D. [Department of Medicine, Washington University School of Medicine, St. Louis, Missouri (United States)] [Department of Medicine, Washington University School of Medicine, St. Louis, Missouri (United States); Low, Daniel A. [Department of Radiation Oncology, University of California Los Angeles, Los Angeles, California (United States)] [Department of Radiation Oncology, University of California Los Angeles, Los Angeles, California (United States); Parikh, Parag J.; Mutic, Sasa [Department of Radiation Oncology, Washington University School of Medicine, St. Louis, Missouri (United States)] [Department of Radiation Oncology, Washington University School of Medicine, St. Louis, Missouri (United States)

2013-05-01T23:59:59.000Z

178

Ferrite-ferroelectric layered structures for electrically and magnetically tunable microwave resonators  

E-Print Network [OSTI]

Ferrite-ferroelectric layered structures for electrically and magnetically tunable microwave It is demonstrated experimentally that a layered structure consisting of ferrite and ferroelectric thin films can constant , and a bias magnetic field to the ferrite layer. The resonator having central frequency f0 5 GHz

Demokritov, S.O.

179

White matter microstructure on diffusion tensor imaging is associated with conventional magnetic resonance imaging findings and  

E-Print Network [OSTI]

White matter microstructure on diffusion tensor imaging is associated with conventional magnetic to evaluate white matter architecture after preterm birth. The goals were (1) to compare white matter if sex, gestational age, birth- weight, white matter injury score from conventional magnetic resonance

Grill-Spector, Kalanit

180

Chemical analysis by ultrahigh-resolution nuclear magnetic resonance in the Earth's  

E-Print Network [OSTI]

LETTERS Chemical analysis by ultrahigh-resolution nuclear magnetic resonance in the Earth spectroscopy2 in the Earth's magnetic field. We show that in the Earth's field the transverse relaxation time T electronics Data acquisition d.c. transmission coil Earth's field N S B0 B0 = 1 T Figure 1 Setup of mobile

Loss, Daniel

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Characterizing Ligand-Protein Interactions by Ligand-Detected Nuclear Magnetic Resonance (NMR) Methods  

E-Print Network [OSTI]

2.2.3 Acetonitrile as a Chemical Shiftwith 7% 2-propanol and 5% acetonitrile at 1 mL/min. Figuresodium phosphate dibasic, and acetonitrile were from Fisher

Cruz, Jennifer

2010-01-01T23:59:59.000Z

182

The effect of diffusion in internal gradients on nuclear magnetic resonance transverse relaxation measurements  

SciTech Connect (OSTI)

In the present work we study the internal gradient effects on diffusion attenuation of the echo train appearing in the well-known Carr-Purcell-Meiboom-Gill (CPMG) technique, extensively used for transverse relaxation measurements. Our investigations are carried out on two porous ceramics, prepared with the same amount of magnetic impurities (Fe{sub 2}O{sub 3}) but different pore sizes. It is shown that diffusion effects on the CPMG echo train attenuation are strongly influenced by the pore size for the same magnetic susceptibility of the two samples. The experimental results were compared with a theoretical model taking into account the limit of free or restricted diffusion on echo train attenuation. The NMR experiments were performed on water filled samples using a low-field NMR instrument. The porous ceramics were prepared using both the replica technique and the powder compression technique. Magnetic susceptibility measurements indicated close values of the susceptibility constant for the two samples whereas the SEM images indicated different pore sizes. The results reported here may have impact in the interpretation of NMR relaxation measurements of water in soils or concrete samples.

Muncaci, S.; Ardelean, I. [Technical University of Cluj-Napoca, Physics and Chemistry Department, Cluj-Napoca (Romania)] [Technical University of Cluj-Napoca, Physics and Chemistry Department, Cluj-Napoca (Romania); Boboia, S. [Technical University of Cluj-Napoca, Physics and Chemistry Department, Cluj-Napoca, Romania and Babes Bolyai University, Raluca Ripan Chemistry Research Institute, Cluj-Napoca (Romania)] [Technical University of Cluj-Napoca, Physics and Chemistry Department, Cluj-Napoca, Romania and Babes Bolyai University, Raluca Ripan Chemistry Research Institute, Cluj-Napoca (Romania)

2013-11-13T23:59:59.000Z

183

Observation of the uranium 235 nuclear magnetic resonance signal (*)  

E-Print Network [OSTI]

liquid UF6, 93.5 % enriched in 23SU, has been studied at 380 K, in a 10 mm o.d, 6 mm i.d sealed silica tube. At this temperature, the UF6 vapour pressure is ca. 4 bars. The NMR spectra were recorded of 90 ~s. On the figure are compared the absorption spectra of UF6 93.5 % enriched in 231U (A), of UF6

Paris-Sud XI, Université de

184

A 4 K cryogenic probe for use in magnetic resonance force microscopy experiments  

SciTech Connect (OSTI)

The detailed design of a mechanically detected nuclear magnetic resonance probe using the SPAM (Springiness Preservation by Aligning Magnetization) geometry, operating at 4 K, in vacuum, and a several-Tesla magnetic field is described. The probe head is vibration-isolated well enough from the environment by a three-spring suspension system that the cantilever achieves thermal equilibrium with the environment without the aid of eddy current damping. The probe uses an ultra-soft Si cantilever with a Ni sphere attached to its tip, and magnetic resonance is registered as a change in the resonant frequency of the driven cantilever. The RF system uses frequency sweeps for adiabatic rapid passage using a 500 ?m diameter RF coil wound around a sapphire rod. The RF coil and optical fiber of the interferometer used to sense the cantilever's position are both located with respect to the cantilever using a Garbini micropositioner, and the sample stage is mounted on an Attocube nanopositioner.

Smith, Doran D.; Alexson, Dimitri A. [U.S. Army Research Laboratory, 2800 Powder Mill Road, Adelphi, Maryland 20783 (United States)] [U.S. Army Research Laboratory, 2800 Powder Mill Road, Adelphi, Maryland 20783 (United States); Garbini, Joseph L. [Mechanical Engineering, University of Washington, Seattle, Washington 98195 (United States)] [Mechanical Engineering, University of Washington, Seattle, Washington 98195 (United States)

2013-09-15T23:59:59.000Z

185

Resonant normal form and asymptotic normal form behavior in magnetic bottle Hamiltonians  

E-Print Network [OSTI]

We consider normal forms in `magnetic bottle' type Hamiltonians of the form $H=\\frac{1}{2}(\\rho^2_\\rho+\\omega^2_1\\rho^2) +\\frac{1}{2}p^2_z+hot$ (second frequency $\\omega_2$ equal to zero in the lowest order). Our main results are: i) a novel method to construct the normal form in cases of resonance, and ii) a study of the asymptotic behavior of both the non-resonant and the resonant series. We find that, if we truncate the normal form series at order $r$, the series remainder in both constructions decreases with increasing $r$ down to a minimum, and then it increases with $r$. The computed minimum remainder turns to be exponentially small in $\\frac{1}{\\Delta E}$, where $\\Delta E$ is the mirror oscillation energy, while the optimal order scales as an inverse power of $\\Delta E$. We estimate numerically the exponents associated with the optimal order and the remainder's exponential asymptotic behavior. In the resonant case, our novel method allows to compute a `quasi-integral' (i.e. truncated formal integral) valid both for each particular resonance as well as away from all resonances. We applied these results to a specific magnetic bottle Hamiltonian. The non resonant normal form yields theorerical invariant curves on a surface of section which fit well the empirical curves away from resonances. On the other hand the resonant normal form fits very well both the invariant curves inside the islands of a particular resonance as well as the non-resonant invariant curves. Finally, we discuss how normal forms allow to compute a critical threshold for the onset of global chaos in the magnetic bottle.

C. Efthymiopoulos; M. Harsoula; G. Contopoulos

2015-01-28T23:59:59.000Z

186

Method for high resolution magnetic resonance analysis using magic angle technique  

DOE Patents [OSTI]

A method of performing a magnetic resonance analysis of a biological object that includes placing the object in a main magnetic field (that has a static field direction) and in a radio frequency field; rotating the object at a frequency of less than about 100 Hz around an axis positioned at an angle of about 54.degree.44' relative to the main magnetic static field direction; pulsing the radio frequency to provide a sequence that includes a phase-corrected magic angle turning pulse segment; and collecting data generated by the pulsed radio frequency. The object may be reoriented about the magic angle axis between three predetermined positions that are related to each other by 120.degree.. The main magnetic field may be rotated mechanically or electronically. Methods for magnetic resonance imaging of the object are also described.

Wind, Robert A.; Hu, Jian Zhi

2003-12-30T23:59:59.000Z

187

Method for high resolution magnetic resonance analysis using magic angle technique  

DOE Patents [OSTI]

A method of performing a magnetic resonance analysis of a biological object that includes placing the object in a main magnetic field (that has a static field direction) and in a radio frequency field; rotating the object at a frequency of less than about 100 Hz around an axis positioned at an angle of about 54.degree.44' relative to the main magnetic static field direction; pulsing the radio frequency to provide a sequence that includes a phase-corrected magic angle turning pulse segment; and collecting data generated by the pulsed radio frequency. The object may be reoriented about the magic angle axis between three predetermined positions that are related to each other by 120.degree.. The main magnetic field may be rotated mechanically or electronically. Methods for magnetic resonance imaging of the object are also described.

Wind, Robert A.; Hu, Jian Zhi

2004-12-28T23:59:59.000Z

188

NMR apparatus for in situ analysis of fuel cells  

DOE Patents [OSTI]

The subject apparatus is a fuel cell toroid cavity detector for in situ analysis of samples through the use of nuclear magnetic resonance. The toroid cavity detector comprises a gas-tight housing forming a toroid cavity where the housing is exposed to an externally applied magnetic field B.sub.0 and contains fuel cell component samples to be analyzed. An NMR spectrometer is electrically coupled and applies a radiofrequency excitation signal pulse to the detector to produce a radiofrequency magnetic field B.sub.1 in the samples and in the toroid cavity. Embedded coils modulate the static external magnetic field to provide a means for spatial selection of the recorded NMR signals.

Gerald, II, Rex E; Rathke, Jerome W

2012-11-13T23:59:59.000Z

189

NMR and Transport Studies on Group IV Clathrates and Related Intermetallic Materials  

E-Print Network [OSTI]

challenge. In this work, Nuclear Magnetic Resonance (NMR), heat capacity and transport measurements have been used to study several clathrate systems, especially the well- known type-I Ba8Ga16Sn30, which has been reported to have one of the lowest thermal...

Zheng, Xiang

2012-10-19T23:59:59.000Z

190

Nondestructive NMR technique for moisture determination in radioactive materials.  

SciTech Connect (OSTI)

This progress report focuses on experimental and computational studies used to evaluate nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI) for detecting, quantifying, and monitoring hydrogen and other magnetically active nuclei ({sup 3}H, {sup 3}He, {sup 239}Pu, {sup 241}Pu) in Spent nuclear fuels and packaging materials. The detection of moisture by using a toroid cavity NMR imager has been demonstrated in SiO{sub 2} and UO{sub 2} systems. The total moisture was quantified by means of {sup 1}H NMR detection of H{sub 2}O with a sensitivity of 100 ppm. In addition, an MRI technique that was used to determine the moisture distribution also enabled investigators to discriminate between bulk and stationary water sorbed on the particles. This imaging feature is unavailable in any other nondestructive assay (NDA) technique. Following the initial success of this program, the NMR detector volume was scaled up from the original design by a factor of 2000. The capacity of this detector exceeds the size specified by DOE-STD-3013-96.

Aumeier, S.; Gerald, R.E. II; Growney, E.; Nunez, L.; Kaminski, M.

1998-12-04T23:59:59.000Z

191

Particle transport as a result of resonant magnetic perturbations  

E-Print Network [OSTI]

field of plasma physics with a particular focus on particlewe will focus on localized measurements at the plasma edgefocuses on the Magnetic confinement technique utilizing a Tokamak [91]. The goal of a burning plasma,

Mordijck, Saskia

2011-01-01T23:59:59.000Z

192

Nuclear magnetic resonance investigation of dynamics in poly(ethylene oxide)-based lithium polyether-ester-sulfonate ionomers  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Nuclear magnetic resonance (NMR) spectroscopy has been utilized to investigate the dynamics of poly(ethylene oxide)-based lithium sulfonate ionomer samples that have low glass transition temperatures. 1H and 7Li spin-lattice relaxation times (T1) of the bulk polymer and lithium ions, respectively, were measured and analyzed in samples with a range of ion contents. The temperature dependence of T1 values along with the presence of minima in T1 as a function of temperature enabled correlation times and activation energies to be obtained for both the segmental motion of the polymer backbone and the hopping motion of lithium cations. Similar activation energies for motion of both the polymer and lithium ions in the samples with lower ion content indicate that the polymer segmental motion and lithium ion hopping motion are correlated in these samples, even though their respective correlation times differ significantly. A divergent trend is observed for correlation times and activation energies of the highest ion content sample with 100% lithium sulfonation due to the presence of ionic aggregation. Details of the polymer and cation dynamics on the nanosecond timescale are discussed and complement the findings of X-ray scattering and Quasi Elastic Neutron Scattering experiments.

Roach, David J. [Pennsylvania State University, University Park, PA (United States); Dou, Shichen [Pennsylvania State University, University Park, PA (United States); Colby, Ralph H. [Pennsylvania State University, University Park, PA (United States); Mueller, Karl T. [Pacific Northwest Lab., Richland, WA (United States)

2012-01-06T23:59:59.000Z

193

Nuclear Magnetic Resonance Investigation of Dynamics in Poly(Ethylene Oxide) Based Lithium Polyether-ester-sulfonate Ionomers  

SciTech Connect (OSTI)

Nuclear magnetic resonance (NMR) spectroscopy has been utilized to investigate the dynamics of poly(ethylene oxide)-based lithium sulfonate ionomer samples that have low glass transition temperatures. 1H and 7Li spin-lattice relaxation times (T1) of the bulk polymer and lithium ions, respectively, were analyzed in samples with a range of ion contents. The temperature dependence of T1 values along with the presence of minima in T1 enabled correlation times and activation energies to be obtained for both the segmental motion of the polymer backbone and the hopping motion of lithium cations. Similar activation energies of both the polymer and lithium ions in the lower ion content samples indicate that the polymer segmental motion and lithium ion hopping motion are correlated even though their respective correlation times differ significantly. A divergent trend is observed for correlation times and activation energies of the highest ion content sample due to the presence of ionic aggregation. Details about the polymer and cation dynamics on the nanosecond timescale are discussed and complement the findings of X-ray scattering and Quasi Elastic Neutron Scattering experiments.

Roach, David J.; Dou, Shichen; Colby, Ralph H.; Mueller, Karl T.

2012-01-07T23:59:59.000Z

194

Solid-State Nuclear Magnetic Resonance Measurements of HIV Fusion Peptide 13  

E-Print Network [OSTI]

Solid-State Nuclear Magnetic Resonance Measurements of HIV Fusion Peptide 13 CO to Lipid 31 P ABSTRACT: Fusion of the human immunodeficiency virus (HIV) membrane and the host cell membrane is an initial step of infection of the host cell. Fusion is catalyzed by gp41, which is an integral membrane

Weliky, David

195

The Effect of Magnesium Coordination on the and "N Magnetic Resonance Spectra of Chlorophyll a.  

E-Print Network [OSTI]

7058 The Effect of Magnesium Coordination on the and "N Magnetic Resonance Spectra of Chlorophyll a magnesium-free derivative pheophytin a have been assigned. Emphasis is placed on the quaternary carbon atoms was developed to permit these assign- ments. On complexation with magnesium, large downfield chemical

Boxer, Steven G.

196

Electrical, optical and magnetic resonance studies of novel. pi. -conjugated polymers  

SciTech Connect (OSTI)

Conductivity, optical properties including visible and infrared absorption and photoluminescence, and magnetic resonance properties including electron spin resonance and optically detected magnetic resonance have been studied in polydiethynylsilanes (PDES) and poly(2,5-dibutoxyparaphenyleneacetylene) (PDBOPA), which have been recently synthesized. PDES and PDBOPA blend and PDBOPA-based electroluminescent preliminary diodes which were fabricated by the author were also explored. The undoped one-dimensional gap of PDES polymers, which have average molecular weight from {approximately}2{times}10{sup 5} to 1{times}10{sup 6}, is 2.0 eV in both films and solutions; photoluminescence is barely observed. I{sub 2} doping induces a single absorption band at {approximately}1.05 eV in solutions and lightly doped films, but another at {approximately}0.55 eV in heavily doped films. Both are correlated with strong IR-active vibrations associated with known lines in Raman scattering.

Ni, Qing-Xiao.

1992-04-20T23:59:59.000Z

197

Electrical, optical and magnetic resonance studies of novel {pi}-conjugated polymers  

SciTech Connect (OSTI)

Conductivity, optical properties including visible and infrared absorption and photoluminescence, and magnetic resonance properties including electron spin resonance and optically detected magnetic resonance have been studied in polydiethynylsilanes (PDES) and poly(2,5-dibutoxyparaphenyleneacetylene) (PDBOPA), which have been recently synthesized. PDES and PDBOPA blend and PDBOPA-based electroluminescent preliminary diodes which were fabricated by the author were also explored. The undoped one-dimensional gap of PDES polymers, which have average molecular weight from {approximately}2{times}10{sup 5} to 1{times}10{sup 6}, is 2.0 eV in both films and solutions; photoluminescence is barely observed. I{sub 2} doping induces a single absorption band at {approximately}1.05 eV in solutions and lightly doped films, but another at {approximately}0.55 eV in heavily doped films. Both are correlated with strong IR-active vibrations associated with known lines in Raman scattering.

Ni, Qing-Xiao

1992-04-20T23:59:59.000Z

198

Effect of Electric and Magnetic Fields on Spin Dynamics in the Resonant Electric Dipole Moment Experiment  

E-Print Network [OSTI]

A buildup of the vertical polarization in the resonant electric dipole moment (EDM) experiment [Y. F. Orlov, W. M. Morse, and Y. K. Semertzidis, Phys. Rev. Lett. 96, 214802 (2006)] is affected by a horizontal electric field in the particle rest frame oscillating at a resonant frequency. This field is defined by the Lorentz transformation of an oscillating longitudinal electric field and a uniform vertical magnetic one. The effect of a longitudinal electric field is significant, while the contribution from a magnetic field caused by forced coherent longitudinal oscillations of particles is dominant. The effect of electric field on the spin dynamics was not taken into account in previous calculations. This effect is considerable and leads to decreasing the EDM effect for the deuteron and increasing it for the proton. The formula for resonance strengths in the EDM experiment has been derived. The spin dynamics has been calculated.

Alexander J. Silenko

2007-10-02T23:59:59.000Z

199

Frequency stabilization of spin-torque-driven oscillations by coupling with a magnetic nonlinear resonator  

SciTech Connect (OSTI)

The fundamental function of any oscillator is to produce a waveform with a stable frequency. Here, we show a method of frequency stabilization for spin-torque nano-oscillators (STNOs) that relies on coupling with an adjacent nanomagnet through the magnetic dipoledipole interaction. It is numerically demonstrated that highly stable oscillations occur as a result of mutual feedback between an STNO and a nanomagnet. The nanomagnet acts as a nonlinear resonator for the STNO. This method is based on the nonlinear behavior of the resonator and can be considered as a magnetic analogue of an optimization scheme in nanoelectromechanical systems. The oscillation frequency is most stabilized when the nanomagnet is driven at a special feedback point at which the feedback noise between the STNO and resonator is completely eliminated.

Kudo, Kiwamu, E-mail: kiwamu.kudo@toshiba.co.jp; Suto, Hirofumi; Nagasawa, Tazumi; Mizushima, Koichi; Sato, Rie [Corporate Research and Development Center, Toshiba Corporation, Kawasaki 2128582 (Japan)

2014-10-28T23:59:59.000Z

200

All-optical high-resolution magnetic resonance using a nitrogen-vacancy spin in diamond  

E-Print Network [OSTI]

We propose an all-optical scheme to prolong the quantum coherence of a negatively charged nitrogen-vacancy (NV) center in diamond. Optical control of the NV spin suppresses energy fluctuations of the $^{3}\\text{A}_{2}$ ground states and forms an energy gap protected subspace. By optical control, the spectral linewidth of magnetic resonance is much narrower and the measurement of the frequencies of magnetic field sources has higher resolution. The optical control also improves the sensitivity of the magnetic field detection and can provide measurement of the directions of signal sources.

Zhen-Yu Wang; Jian-Ming Cai; Alex Retzker; Martin B. Plenio

2014-04-04T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

NMR of thin layers using a meanderline surface coil  

DOE Patents [OSTI]

A miniature meanderline sensor coil which extends the capabilities of nuclear magnetic resonance (NMR) to provide analysis of thin planar samples and surface layer geometries. The sensor coil allows standard NMR techniques to be used to examine thin planar (or curved) layers, extending NMRs utility to many problems of modern interest. This technique can be used to examine contact layers, non-destructively depth profile into films, or image multiple layers in a 3-dimensional sense. It lends itself to high resolution NMR techniques of magic angle spinning and thus can be used to examine the bonding and electronic structure in layered materials or to observe the chemistry associated with aging coatings. Coupling this sensor coil technology with an arrangement of small magnets will produce a penetrator probe for remote in-situ chemical analysis of groundwater or contaminant sediments. Alternatively, the sensor coil can be further miniaturized to provide sub-micron depth resolution within thin films or to orthoscopically examine living tissue. This thin-layer NMR technique using a stationary meanderline coil in a series-resonant circuit has been demonstrated and it has been determined that the flat meanderline geometry has about he same detection sensitivity as a solenoidal coil, but is specifically tailored to examine planar material layers, while avoiding signals from the bulk.

Cowgill, Donald F. (San Ramon, CA)

2001-01-01T23:59:59.000Z

202

Rapid prediction of various physical properties for middle distillate fuel utilizing directly coupled liquid chromatography//sup 1/H nuclear magnetic resonance  

SciTech Connect (OSTI)

A group property approach has been developed to predict 17 physical properties of middle distillate (e.g., jet and diesel) fuels from experimentally derived liquid chromatography//sup 1/H nuclear magnetic resonance (LC//sup 1/H NMR) data. In the LC//sup 1/H NMR technique, the fuel is separated according to chemical class and the average molecular structure for each chemical class is then calculated. These average molecular structures form a basis set to predict the physical properties of the fuel. The physical properties that can be obtained in this manner are cetane number, cetane index, density, specific gravity, pour point, flash point, viscosity, filterability, heat of combustion, cloud point, volume percent aromatics, residual carbon content, and the initial, 10%, 50%, 90%, and end boiling points. Fourteen of the correlation coefficients for the predictions are better than 0.90 with 11 of the predictions falling either within or approximately equal to the ASTM method reproducibility for the measurement of the fuel property. The present method also provides chemical insight concerning the influence of chemical structural changes on the physical properties of the fuel as well as requiring much less analysis time and sample volume than corresponding ASTM methods.

Caswell, K.A.; Glass, T.E.; Swann, M.; Dorn, H.C.

1989-02-01T23:59:59.000Z

203

Polarization transfer NMR imaging  

DOE Patents [OSTI]

A nuclear magnetic resonance (NMR) image is obtained with spatial information modulated by chemical information. The modulation is obtained through polarization transfer from a first element representing the desired chemical, or functional, information, which is covalently bonded and spin-spin coupled with a second element effective to provide the imaging data. First and second rf pulses are provided at first and second frequencies for exciting the imaging and functional elements, with imaging gradients applied therebetween to spatially separate the nuclei response for imaging. The second rf pulse is applied at a time after the first pulse which is the inverse of the spin coupling constant to select the transfer element nuclei which are spin coupled to the functional element nuclei for imaging. In a particular application, compounds such as glucose, lactate, or lactose, can be labeled with .sup.13 C and metabolic processes involving the compounds can be imaged with the sensitivity of .sup.1 H and the selectivity of .sup.13 C.

Sillerud, Laurel O. (Los Alamos, NM); van Hulsteyn, David B. (Santa Fe, NM)

1990-01-01T23:59:59.000Z

204

Magnetism studies using resonant, coherent, x-ray scattering | Stanford  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fund Las ConchasTrail5,722,326 Site Map PrintableMagnetism

205

Sub-surface characterization and three dimensional profiling of semiconductors by magnetic resonance force microscopy  

SciTech Connect (OSTI)

This is the final report of a two-year, Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). The project successfully developed a magnetic resonance force microscope (MRFM) instrument to mechanically detect magnetic resonance signals. This technique provides an intrinsically subsurface, chemical-species-specific probe of structure, constituent density and other properties of materials. As in conventional magnetic resonance imaging (MRI), an applied magnetic field gradient selects a well defined volume of the sample for study. However mechanical detection allows much greater sensitivity, and this in turn allows the reduction of the size of the minimum resolvable volume. This requires building an instrument designed to achieve nanometer-scale resolution at buried semiconductor interfaces. High-resolution, three-dimensional depth profiling of semiconductors is critical in the development and fabrication of semiconductor devices. Currently, there is no capability for direct, high-resolution observation and characterization of dopant density, and other critical features of semiconductors. The successful development of MRFM in conjunction with modifications to improve resolution will enable for the first time detailed structural and electronic studies in doped semiconductors and multilayered nanoelectronic devices, greatly accelerating the current pace of research and development.

Hammel, P.C.; Moore, G.; Roukes, M.; Zhenyong Zhang

1996-10-01T23:59:59.000Z

206

DC superconducting quantum interference device usable in nuclear quadrupole resonance and zero field nuclear magnetic spectrometers  

DOE Patents [OSTI]

A spectrometer for measuring the nuclear quadrupole resonance spectra or the zero-field nuclear magnetic resonance spectra generated by a sample is disclosed. The spectrometer uses an amplifier having a dc SQUID operating in a flux-locked loop for generating an amplified output as a function of the intensity of the signal generated by the sample. The flux-locked loop circuit includes an integrator. The amplifier also includes means for preventing the integrator from being driven into saturation. As a result, the time for the flux-locked loop to recover from the excitation pulses generated by the spectrometer is reduced. 7 figures.

Fan, N.Q.; Clarke, J.

1993-10-19T23:59:59.000Z

207

DC superconducting quantum interference device usable in nuclear quadrupole resonance and zero field nuclear magnetic spectrometers  

DOE Patents [OSTI]

A spectrometer for measuring the nuclear quadrupole resonance spectra or the zero-field nuclear magnetic resonance spectra generated by a sample is disclosed. The spectrometer uses an amplifier having a dc SQUID operating in a flux-locked loop for generating an amplified output as a function of the intensity of the signal generated by the sample. The flux-locked loop circuit includes an integrator. The amplifier also includes means for preventing the integrator from being driven into saturation. As a result, the time for the flux-locked loop to recover from the excitation pulses generated by the spectrometer is reduced.

Fan, Non Q. (San Diego, CA); Clarke, John (Berkeley, CA)

1993-01-01T23:59:59.000Z

208

NMR experiments on a three-dimensional vibrofluidized granular medium Chao Huan, Xiaoyu Yang,* and D. Candela  

E-Print Network [OSTI]

coupled with one-dimensional magnetic resonance imaging. The system consisted of mustard seeds vibrated-dimensional granular system fluidized by vertical container vibrations was studied using pulsed field gradient NMR.05.Rm I. INTRODUCTION One of the basic granular flow phenomena is the creation of a fluidized state

Walsworth, Ronald L.

209

Florence, 28/02/2011: Two applied inverse problems: Introduction 1 -Problem #1: Studying the protein fold via NMR constraints.  

E-Print Network [OSTI]

the protein fold via NMR constraints. In collaboration with the CERM (Centre for Magnetic Resonance problems. #12;Florence, 28/02/2011: Two applied inverse problems: The problem of protein folding 2 H CCN) Backbone #12;Florence, 28/02/2011: Two applied inverse problems: The problem of protein folding 3 Genoma

Pedicini, Marco

210

Identification of breast calcification using magnetic resonance imaging  

SciTech Connect (OSTI)

MRI phase and magnitude images provide information about local magnetic field variation ({Delta}B{sub 0}), which can consequently be used to understand tissue properties. Often, phase information is discarded. However, corrected phase images are able to produce contrast as a result of magnetic susceptibility differences and local field inhomogeneities due to the presence of diamagnetic and paramagnetic substances. Three-dimensional (3D) susceptibility weighted imaging (SWI) can be used to probe changes in MRI phase evolution and, subsequently, result in an alternate form of contrast between tissues. For example, SWI has been useful in the assessment of negative phase induced {Delta}B{sub 0} modulation due to the presence of paramagnetic substances such as iron. Very little, however, has been done to assess positive phase induced contrast changes resulting from the presence of diamagnetic substances such as precipitated calcium. As ductal carcinoma in situ, which is the precursor of invasive ductal cancer, is often associated with breast microcalcification, the authors proposed using SWI as a possible visualization technique. In this study, breast phantoms containing calcifications (0.4-1.5 mm) were imaged using mammography, computed tomography (CT), and SWI. Corrected phase and magnitude images acquired using SWI allowed identification and correlation of all calcifications seen on CT. As the approach is a 3D technique, it could potentially allow for more accurate localization and biopsy and maybe even reduce the use of gadolinium contrast. Furthermore, the approach may be beneficial to women with dense breast tissue where the ability to detect microcalcification with mammography is reduced.

Fatemi-Ardekani, Ali; Boylan, Colm; Noseworthy, Michael D. [Department of Medical Physics and Applied Radiation Sciences, McMaster University, Hamilton, Ontario L8S 4K1 (Canada) and Imaging Research Centre, Brain-Body Institute, St. Joseph's Healthcare, Hamilton, Ontario L8N 4A6 (Canada); Diagnostic Imaging, St. Joseph's Healthcare, Hamilton, Ontario L8N 4A6 (Canada) and Department of Radiology, McMaster University, Hamilton, Ontario L8N 3Z5 (Canada); Department of Medical Physics and Applied Radiation Sciences, McMaster University, Hamilton, Ontario L8S 4K1 (Canada); Imaging Research Centre, Brain-Body Institute, St. Joseph's Healthcare, Hamilton, Ontario L8N 4A6 (Canada); Diagnostic Imaging, St. Joseph's Healthcare, Hamilton, Ontario L8N 4A6 (Canada); Department of Radiology, McMaster University, Hamilton, Ontario L8N 3Z5 (Canada) and Electrical and Computer Engineering, and School of Biomedical Engineering, McMaster University, Hamilton, Ontario L8S 4K1 (Canada)

2009-12-15T23:59:59.000Z

211

Nuclear magnetic resonance: Its role as a microscopic probe of the electronic and magnetic properties of High-{Tc} superconductors and related materials  

SciTech Connect (OSTI)

NMR experiments are reported for Sr{sub 2}CuO{sub 2}Cl{sub 2}, HgBa{sub 2}CuO{sub 4+d}, YNi{sub 2}B{sub 2}C and YBa{sub 2}Cu{sub 3}O{sub 7}. NMR studies typify three different aspects of microscopic properties of HTSC. In non-superconducting antiferromagnetic (AF) prototype Sr{sub 2}CuO{sub 2}Cl{sub 2}, we used NMR to investigate Cu{sup 2+} correlated spin dynamics and AF phase transition in CuO2 layers. In the superconductors, we used NMR both to investigate the electronic properties of the Fermi-liquid in normal and superconducting states and to investigate flux lattice and flux-line dynamics in the superconducting state in presence of magnetic field. A summary of each study is given: {sup 35}Cl NMR was measured in Sr{sub 2}CuO{sub 2}Cl{sub 2} single crystals with T{sub N}=257K. {sub 35}Cl NMR relaxation rates showed crossover of Cu{sup 2+} spin dynamics from Heisenberg to XY-like correlation at 290 K well above T{sub N}. A field-dependent T{sub N} for H{perpendicular}c was observed and explained by a field-induced Ising-like anisotropy in ab plane. {sup 199}Hg NMR was measured in HgBa{sub 2}CuO{sub 4+d}. Properties of the Fermi-liquid are characterized by a single-spin fluid picture and opening of a spin pseudo-gap at q=0 above {Tc}. Below {Tc}, spin component of Knight shift decreases rapidly in agreement with prediction for d-wave pairing scheme. {sup 11}B and {sup 89}Y NMR/magnetization were measured in YNi{sub 2}B{sub 2}C. Temperature dependence of {sup 11}B Knight shift and of the NSLR gave a normal state which agrees with the Korringa relation, indicating that the AF fluctuations on the Ni sublattice are negligible. Opening of the superconducting gap obeys BCS. A NMR approach to investigate vortex thermal motion in HTSC is presented, based on contribution of thermal flux-lines motion to both T{sub 2}{sup {minus}1} and T{sub 1}{sup {minus}1}. Effects are demonstrated in YBa{sub 2}Cu{sub 3}O{sub 7} and HgBa{sub 2}CuO{sub 4+d}.

Suh, Byoung Jin

1995-12-27T23:59:59.000Z

212

Laboratory studies of the dynamic of resonance cones formation in magnetized plasmas  

SciTech Connect (OSTI)

The paper is devoted to experimental studies of formation of resonance cones in magnetized plasmas by pulsed RF source in the lower-hybrid (whistler) and the upper-hybrid frequency ranges. It is shown that in both frequency ranges, resonance cones exhibit similar dynamics after switching-on the RF source: at first, wide maxima of radiation are formed in non-resonance directions, which then become narrower, with their direction approaching the resonance one. While the resonance cones are being formed, one observes a fine structure in the form of secondary radiation maxima. It is shown that the characteristic formation time of stationary resonance cones is determined by the minimal value of the group velocity of the quasi-electrostatic waves excited by the antenna. In the low-temperature plasma, this value is limited in the lower-hybrid frequency range by the spatial spectrum of the emitting antenna and in the upper-hybrid range, by the effects of spatial plasma dispersion.

Nazarov, V. V.; Starodubtsev, M. V.; Kostrov, A. V. [Russian Academy of Sciences, Institute of Applied Physics, Nizhny Novgorod (Russian Federation)

2013-03-15T23:59:59.000Z

213

Method for high resolution magnetic resonance analysis using magic angle technique  

DOE Patents [OSTI]

A method of performing a magnetic resonance analysis of a biological object that includes placing the biological object in a main magnetic field and in a radio frequency field, the main magnetic field having a static field direction; rotating the biological object at a rotational frequency of less than about 100 Hz around an axis positioned at an angle of about 54.degree.44' relative to the main magnetic static field direction; pulsing the radio frequency to provide a sequence that includes a magic angle turning pulse segment; and collecting data generated by the pulsed radio frequency. According to another embodiment, the radio frequency is pulsed to provide a sequence capable of producing a spectrum that is substantially free of spinning sideband peaks.

Wind, Robert A.; Hu, Jian Zhi

2003-11-25T23:59:59.000Z

214

NMR studies of oriented molecules  

SciTech Connect (OSTI)

Deuterium and proton magnetic resonance are used in experiments on a number of compounds which either form liquid crystal mesophases themselves or are dissolved in a liquid crystal solvent. Proton multiple quantum NMR is used to simplify complicated spectra. The theory of nonselective multiple quantum NMR is briefly reviewed. Benzene dissolved in a liquid crystal are used to demonstrate several outcomes of the theory. Experimental studies include proton and deuterium single quantum (..delta..M = +-1) and proton multiple quantum spectra of several molecules which contain the biphenyl moiety. 4-Cyano-4'-n-pentyl-d/sub 11/-biphenyl (5CB-d/sub 11/) is studied as a pure compound in the nematic phase. The obtained chain order parameters and dipolar couplings agree closely with previous results. Models for the effective symmetry of the biphenyl group in 5CB-d/sub 11/ are tested against the experimental spectra. The dihedral angle, defined by the planes containing the rings of the biphenyl group, is found to be 30 +- 2/sup 0/ for 5DB-d/sub 11/. Experiments are also described for 4,4'-d/sub 2/-biphenyl, 4,4' - dibromo-biphenyl, and unsubstituted biphenyl.

Sinton, S.W.

1981-11-01T23:59:59.000Z

215

Amplification of Xenon NMR and MRI by remote detection  

SciTech Connect (OSTI)

A novel technique is proposed in which a nuclear magneticresonance (NMR) spectrum or magnetic resonance image (MRI) is encoded andstored as spin polarization and is then moved to a different physicallocation to be detected. Remote detection allows the separateoptimization of the encoding and detection steps, permitting theindependent choice of experimental conditions, and excitation anddetection methodologies. In the first experimental demonstration of thistechnique, we show that NMR signal can be amplified by taking diluted129Xe from a porous sample placed inside a large encoding coil, andconcentrating it into a smaller detection coil. In general, the study ofNMR active molecules at low concentration that have low physical fillingfactor is facilitated by remote detection. In the second experiment, MRIinformation encoded in a very low field magnet (4-7mT) is transferred toa high field magnet (4.2 T) in order to be detected under optimizedconditions. Furthermore, remote detection allows the utilization ofultra-sensitive optical or superconducting detection techniques, whichbroadens the horizon of NMR experimentation.

Moule, Adam J.; Spence, Megan M.; Han, Song-I.; Seeley, JulietteA.; Pierce, Kimberly L.; Saxena, Sunil; Pines, Alexander

2003-03-31T23:59:59.000Z

216

Spin counting in electrically detected magnetic resonance via low-field defect state mixing  

SciTech Connect (OSTI)

The work herein describes a method that allows one to measure paramagnetic defect densities in semiconductor and insulator based devices with electrically detected magnetic resonance (EDMR). The method is based upon the mixing of defect states which results from the dipolar coupling of paramagnetic sites at low magnetic fields. We demonstrate the measurement method with spin dependent tunneling in thin film dielectrics; however, the method should be equally applicable to paramagnetic defect density measurements in semiconductors via the more commonly utilized EDMR technique called spin dependent recombination.

Cochrane, Corey J.; Lenahan, Patrick M. [The Pennsylvania State University, University Park, Pennsylvania 16802 (United States)

2014-03-03T23:59:59.000Z

217

Flow units from integrated WFT and NMR data  

SciTech Connect (OSTI)

Reliable and continuous permeability profiles are vital as both hard and soft data required for delineating reservoir architecture. They can improve the vertical resolution of seismic data, well-to-well stratigraphic correlations, and kriging between the well locations. In conditional simulations, permeability profiles are imposed as the conditioning data. Variograms, covariance functions and other geostatistical indicators are more reliable when based on good quality permeability data. Nuclear Magnetic Resonance (NMR) logging and Wireline Formation Tests (WFT) separately generate a wealth of information, and their synthesis extends the value of this information further by providing continuous and accurate permeability profiles without increasing the cost. NMR and WFT data present a unique combination because WFTs provide discrete, in situ permeability based on fluid-flow, whilst NMR responds to the fluids in the pore space and yields effective porosity, pore-size distribution, bound and moveable fluid saturations, and permeability. The NMR permeability is derived from the T{sub 2}-distribution data. Several equations have been proposed to transform T{sub 2} data to permeability. Regardless of the transform model used, the NMR-derived permeabilities depend on interpretation parameters that may be rock specific. The objective of this study is to integrate WFT permeabilities with NMR-derived, T{sub 2} distribution-based permeabilities and thereby arrive at core quality, continuously measured permeability profiles. We outlined the procedures to integrate NMR and WFT data and applied the procedure to a field case. Finally, this study advocates the use of hydraulic unit concepts to extend the WFT-NMR derived, core quality permeabilities to uncored intervals or uncored wells.

Kasap, E.; Altunbay, M.; Georgi, D.

1997-08-01T23:59:59.000Z

218

Evaluation of Hydatid Disease of the Heart with Magnetic Resonance Imaging  

SciTech Connect (OSTI)

Two patients with cardiac involvement of hydatid disease are presented: one with hydatid cyst of the interventricular septum and pulmonary arteries and the other with multiple pulmonary cysts associated with intracardiac and pericardial cysts. The ability of magnetic resonance imaging (MRI) to provide a global view of cardiac anatomy in any plane with high contrast between flowing blood and soft tissue ensures it an important role in the diagnosis and preoperative assessment of hydatid disease of the heart.

Kotoulas, Grigoris K.; Magoufis, George L.; Gouliamos, Athanasios D.; Athanassopoulou, Alexandra K.; Roussakis, Arcadios C.; Koulocheri, Dimitra P.; Kalovidouris, Angelos; Vlahos, Labros [Department of Radiology, CT-MRI Unit, Areteion Hospital, University of Athens, 76 Vas. Sophias Ave., GR-115 28 Athens (Greece)

1996-05-15T23:59:59.000Z

219

Circularly polarized microwaves for magnetic resonance study in the GHz range: application to nitrogen-vacancy in diamonds  

E-Print Network [OSTI]

The ability to create time-dependent magnetic fields of controlled polarization is essential for many experiments with magnetic resonance. We describe a microstrip circuit that allows us to generate strong magnetic field at microwave frequencies with arbitrary adjusted polarization. The circuit performance is demonstrated by applying it to an optically detected magnetic resonance and Rabi nutation experiments in nitrogen-vacancy color centers in diamond. Thanks to high efficiency of the proposed microstrip circuit and degree of circular polarization of 85% it is possible to address the specific spin states of a diamond sample using a low power microwave generator.

Mrozek, Mariusz; Rudnicki, Daniel S; Gawlik, Wojciech

2015-01-01T23:59:59.000Z

220

JOURNAL OF MAGNETIC RESONANCE 87,620-627 ( 1990) Practical Aspectsof Proton-Carbon-Carbon-Proton Three-  

E-Print Network [OSTI]

JOURNAL OF MAGNETIC RESONANCE 87,620-627 ( 1990) Practical Aspectsof Proton-Carbon-Carbon and demonstrate improvements that greatly reduce their intensity. 0022-2364190 $3.00 Copyright 0 1990 by Academic

Clore, G. Marius

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Construction of a two-parameter empirical model of left ventricle wall motion using cardiac tagged magnetic resonance imaging data  

E-Print Network [OSTI]

visualized using cardiac tagged magnetic resonance imaging (tMRI) covering the contraction and relaxation phases. Based on the characteristics of the overall dynamics of the LV wall, its motion was represented by a combination of two components - radial...

Shi, Jack J; Alenezy, Mohammed D.; Smirnova, Irina V.; Bilgen, Mehmet

2012-10-24T23:59:59.000Z

222

Solid state nuclear magnetic resonance methodology and applications to structure determination of peptides, proteins and amyloid fibrils  

E-Print Network [OSTI]

Several methodological developments and applications of multidimensional solid-state nuclear magnetic resonance to biomolecular structure determination are presented. Studies are performed in uniformly 3C, 15N isotope ...

Jaroniec, Christopher P

2003-01-01T23:59:59.000Z

223

PUBLISHED ONLINE: 6 APRIL 2009 | DOI: 10.1038/NPHYS1232 Control of a magnetic Feshbach resonance  

E-Print Network [OSTI]

with ultracold gases. Magnetic Feshbach resonances1,2 are widely harnessed for this purpose, but future an optical Feshbach resonance. Using light to change the s-wave scattering length a in ultracold gases offers, Germany. *e-mail: stephan.duerr@mpq.mpg.de. Energy Internuclear distance Laser |g |a |e Figure 1 | Level

Loss, Daniel

224

Observations of thermally excited ferromagnetic resonance on spin torque oscillators having a perpendicularly magnetized free layer  

SciTech Connect (OSTI)

Measurements of thermally excited ferromagnetic resonance were performed on spin torque oscillators having a perpendicularly magnetized free layer and in-plane magnetized reference layer (abbreviated as PMF-STO in the following) for the purpose of obtaining magnetic properties in the PMF-STO structure. The measured spectra clearly showed a large main peak and multiple smaller peaks on the high frequency side. A Lorentzian fit on the main peak yielded Gilbert damping factor of 0.0041. The observed peaks moved in proportion to the out-of-plane bias field. From the slope of the main peak frequency as a function of the bias field, Lande g factor was estimated to be about 2.13. The mode intervals showed a clear dependence on the diameter of the PMF-STOs, i.e., intervals are larger for a smaller diameter. These results suggest that the observed peaks should correspond to eigenmodes of lateral spin wave resonance in the perpendicularly magnetized free layer.

Tamaru, S., E-mail: shingo.tamaru@aist.go.jp; Kubota, H.; Yakushiji, K.; Konoto, M.; Nozaki, T.; Fukushima, A.; Imamura, H.; Taniguchi, T.; Arai, H.; Tsunegi, S.; Yuasa, S. [Spintronics Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568 (Japan); Suzuki, Y. [Spintronics Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki 305-8568 (Japan); Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531 (Japan)

2014-05-07T23:59:59.000Z

225

x-ray resonant magnetic reflectivity of stratified magnetic structures: eigen-wave formalism and application to a Fe thin film  

E-Print Network [OSTI]

x-ray resonant magnetic reflectivity of stratified magnetic structures: eigen-wave formalism regime up to soft and hard x-rays. The originality of the present formalism lies in the use of eigen-waves throughout the treatment. An application to a Fe thin film illustrates the methodology. I. INTRODUCTION X-ray

226

Magnetic structure and domain conversion of the quasi-2D frustrated antiferromagnet CuCrO{sub 2} probed by NMR  

SciTech Connect (OSTI)

We have carried out {sup 63,65}Cu NMR spectra measurements in a magnetic field up to about 15.5 T on a single crystal of the multiferroic triangular-lattice antiferromagnet CuCrO{sub 2}. The measurements were performed for perpendicular and parallel orientations of the magnetic field with respect to the c axis of the crystal, and the detailed angle dependence of the spectra on the magnetic field direction in the ab plane was studied. The shape of the spectra can be well described in the model of spiral spin structure proposed by recent neutron diffraction experiments. When the field is rotated perpendicular to the crystal c axis, we observed, directly for the first time, a remarkable reorientation of the spin plane simultaneous with rotation of the incommensurate wavevector, by quantitatively deducing the conversion of the energetically less favorable domain to a more favorable one. At high enough fields parallel to the c axis, the data are consistent with either a field-induced commensurate spiral magnetic structure or an incommensurate spiral magnetic structure with a disorder in the c direction, suggesting that high fields may have influence on interplanar ordering.

Sakhratov, Yu. A. [National High Magnetic Field Laboratory (United States); Svistov, L. E., E-mail: svistov@kapitza.ras.ru [Russian Academy Sciences, Kapitza Institute for Physical Problems (Russian Federation); Kuhns, P. L.; Zhou, H. D.; Reyes, A. P. [National High Magnetic Field Laboratory (United States)

2014-11-15T23:59:59.000Z

227

An implementation of the Deutsch-Jozsa algorithm on a three-qubit NMR quantum computer  

E-Print Network [OSTI]

A new approach to the implementation of a quantum computer by high-resolution nuclear magnetic resonance (NMR) is described. The key feature is that two or more line-selective radio-frequency pulses are applied simultaneously. A three-qubit quantum computer has been investigated using the 400 MHz NMR spectrum of the three coupled protons in 2,3-dibromopropanoic acid. It has been employed to implement the Deutsch-Jozsa algorithm for distinguishing between constant and balanced functions. The extension to systems containing more coupled spins is straightforward and does not require a more protracted experiment.

N Linden H Barjat R Freeman

1998-08-21T23:59:59.000Z

228

Apparatus for preparing a solution of a hyperpolarized noble gas for NMR and MRI analysis  

DOE Patents [OSTI]

The present invention relates generally to nuclear magnetic resonance (NMR) techniques for both spectroscopy and imaging. More particularly, the present invention relates to methods in which hyperpolarized noble gases (e.g., Xe and He) are used to enhance and improve NMR and MRI. Additionally, the hyperpolarized gas solutions of the invention are useful both in vitro and in vivo to study the dynamics or structure of a system. When used with biological systems, either in vivo or in vitro, it is within the scope of the invention to target the hyperpolarized gas and deliver it to specific regions within the system.

Pines, Alexander (Berkeley, CA); Budinger, Thomas (Berkeley, CA); Navon, Gil (Ramat Gan, IL); Song, Yi-Qiao (Berkeley, CA); Appelt, Stephan (Waiblingen, DE); Bifone, Angelo (Rome, IT); Taylor, Rebecca (Berkeley, CA); Goodson, Boyd (Berkeley, CA); Seydoux, Roberto (Berkeley, CA); Room, Toomas (Albany, CA); Pietrass, Tanja (Socorro, NM)

2008-06-10T23:59:59.000Z

229

Received: 21 August 2008, Revised: 17 February 2009, Accepted: 13 March 2009, Published online in Wiley InterScience: 2009 H NMR metabolomics study of age profiling  

E-Print Network [OSTI]

of aging, as a vast number of effects such as stress, dietary choices, environmental factors, daily by 1 H NMR spectroscopy of urine. The effect of age on the urinary metabolite profile was observed profiling; metabolomics; metabonomics; nuclear magnetic resonance; orthogonal signal correction; principal

Xi, Bowei

230

Generation and control of resonance states in crossed magnetic and electric fields  

E-Print Network [OSTI]

A two-dimensional electron system interacting with an impurity and placed in crossed magnetic and electric fields is under investigation. Since it is assumed that an impurity center interacts as an attractive $\\delta$-like potential a renormalization procedure for the retarded Green's function has to be carried out. For the vanishing electric field we obtain a close analytical expression for the Green's function and we find one bound state localized between Landau levels. It is also shown by numerical investigations that switching on the electric field new long-living resonance states localized in the vicinity of Landau levels can be generated.

Katarzyna Krajewska; Jerzy Z. Kaminski

2002-05-17T23:59:59.000Z

231

E-Print Network 3.0 - acoustic nmr Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

flow in a nanoporous material using remote-detection NMR ELAD... use for the study of aerogels as they require optical access past the surface layer. NMR and magnetic... of NMR...

232

Pulmonary Hemorrhage: Imaging with a New Magnetic Resonance Blood Pool Agent in Conjunction with Breathheld Three-Dimensional Magnetic Resonance Angiography  

SciTech Connect (OSTI)

Purpose: To describe the three-dimensional magnetic resonance angiography (3D MRA) imaging appearance of the pulmonary arteries following administration of a superparamagnetic iron oxide blood pool agent to human volunteers, and to demonstrate in an animal model (pigs) how this technique can be used to detect pulmonary parenchymal hemorrhage. Methods: Two volunteers were examined following the intravenous administration of a superparamagnetic iron oxide blood pool agent (NC100150 Injection, Nycomed Amersham Imaging, Wayne, PA, USA). T1-weighted 3D gradient recalled echo (GRE) image sets (TR/TE 5.1/1.4 msec, flip angle 30 deg.) were acquired breathheld over 24 sec. To assess the detectability of pulmonary bleeding with intravascular MR contrast, pulmonary parenchymal injuries were created in two animals under general anesthesia, and fast T1-weighted 3D GRE image sets collected before and after the injury. Results: Administration of the intravascular contrast in the two volunteers resulted in selective enhancement of the pulmonary vasculature permitting complete visualization and excellent delineation of central, segmental, and subsegmental arteries. Following iatrogenic injury in the two animals, pulmonary hemorrhage was readily detected on the 3D image sets. Conclusion: The data presented illustrate that ultrafast 3D GRE MR imaging in conjunction with an intravenously administered intravascular blood pool agent can be used to perform high-quality pulmonary MRA as well as to detect pulmonary hemorrhage.

Weishaupt, Dominik; Hilfiker, Paul R.; Schmidt, Michaela; Debatin, Joerg F. [Institute of Diagnostic Radiology, University Hospital Zurich, Raemistrasse 100, CH-8091 Zurich (Switzerland)

1999-07-15T23:59:59.000Z

233

Nuclear magnetic resonance of laser-polarized noble gases in molecules, materials and organisms  

E-Print Network [OSTI]

r I- t of silica aerogels by Xe-129 NMR spectroscopy andcatalysts, ceramics, aerogels, food products, and antiquatedxenon penetration within an aerogel sample as a function of

Goodson, B.M.

2010-01-01T23:59:59.000Z

234

NMR Experiments on a Three-Dimensional Vibrofluidized Granular Medium  

E-Print Network [OSTI]

A three-dimensional granular system fluidized by vertical container vibrations was studied using pulsed field gradient (PFG) NMR coupled with one-dimensional magnetic resonance imaging (MRI). The system consisted of mustard seeds vibrated vertically at 50 Hz, and the number of layers N_ell <= 4 was sufficiently low to achieve a nearly time-independent granular fluid. Using NMR, the vertical profiles of density and granular temperature were directly measured, along with the distributions of vertical and horizontal grain velocities. The velocity distributions showed modest deviations from Maxwell-Boltzmann statistics, except for the vertical velocity distribution near the sample bottom which was highly skewed and non-Gaussian. Data taken for three values of N_ell and two dimensionless accelerations Gamma=15,18 were fit to a hydrodynamic theory, which successfully models the density and temperature profiles including a temperature inversion near the free upper surface.

Chao Huan; Xiaoyu Yang; D. Candela; R. W. Mair; R. L. Walsworth

2003-05-12T23:59:59.000Z

235

Two approaches to 3D reconstruction in NMR zeugmatography  

SciTech Connect (OSTI)

In nuclear magnetic resonance (NMR) zeugmatography, the primary data pertain to integrals of the unknown nuclear spin density f(x,y,z) over planes instead of lines in R/sup 3/. Two natural approaches to reconstructing f from such data are: (1) By numerical implementation of the inverse Radon transform in three dimensions (the direct approach), and (2) by application, in two successive stages, of existing well-known algorithms for inverting the two-dimensional Radon transform (the two-stage approach). These two approaches are discussed and compared, both from a theoretical standpoint and through computer results obtained with real NMR data. For the cases studied to date the two methods appear to produce qualitatively similar results.

Marr, R B; Chen, C N; Lauterbur, P C

1980-01-01T23:59:59.000Z

236

NMR CHARACTERIZATIONS OF PROPERTIES OF HETEROGENEOUS MEDIA  

SciTech Connect (OSTI)

A critical and long-standing need within the petroleum industry is the specification of suitable petrophysical properties for mathematical simulation of fluid flow in petroleum reservoirs (i.e., reservoir characterization). The development of accurate reservoir characterizations is extremely challenging. Property variations may be described on many scales, and the information available from measurements reflect different scales. In fact, experiments on laboratory core samples, well-log data, well-test data, and reservoir-production data all represent information potentially valuable to reservoir characterization, yet they all reflect information about spatial variations of properties at different scales. Nuclear magnetic resonance (NMR) spectroscopy and imaging (MRI) provide enormous potential for developing new descriptions and understandings of heterogeneous media. NMR has the rare capability to probe permeable media non-invasively, with spatial resolution, and it provides unique information about molecular motions and interactions that are sensitive to morphology. NMR well-logging provides the best opportunity ever to resolve permeability distributions within petroleum reservoirs. We develop MRI methods to determine, for the first time, spatially resolved distributions of porosity and permeability within permeable media samples that approach the intrinsic scale: the finest resolution of these macroscopic properties possible. To our knowledge, this is the first time that the permeability is actually resolved at a scale smaller than the sample. In order to do this, we have developed a robust method to determine of relaxation distributions from NMR experiments and a novel implementation and analysis of MRI experiments to determine the amount of fluid corresponding to imaging regions, which are in turn used to determine porosity and saturation distributions. We have developed a novel MRI experiment to determine velocity distributions within flowing experiments, and developed methodology using that data to determine spatially resolved permeability distributions. We investigate the use of intrinsic properties for developing improved correlations for predicting permeability from NMR well-logging data and for obtaining more accurate estimates of multiphase flow properties--the relative permeability and capillary pressure--from displacement experiments. We demonstrate the use of MRI measurements of saturation and relaxation for prediction wetting-phase relative permeability for unstable experiments. Finally, we developed an improved method for determining surface relaxivity with NMR experiments, which can provide better descriptions of permeable media microstructures and improved correlations for permeability predictions.

C.T. Philip Chang; Changho Choi; Jeromy T. Hollenshead; Rudi Michalak; Jack Phan; Ramon Saavedra; John C. Slattery; Jinsoo Uh; Randi Valestrand; A. Ted Watson; Song Xue

2005-01-01T23:59:59.000Z

237

A 200-MHz fully-differential CMOS front-end with an on-chip inductor for magnetic resonance imaging  

E-Print Network [OSTI]

A 200-MHZ FULLY-DIFFERENTIAL CMOS FRONT-END WITH AN ON-CHIP INDUCTOR FOR MAGNETIC RESONANCE IMAGING A Thesis by JULIO ENRIQUE AYALA II Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE December 2005 Major Subject: Electrical Engineering A 200-MHZ FULLY-DIFFERENTIAL CMOS FRONT-END WITH AN ON-CHIP INDUCTOR FOR MAGNETIC RESONANCE IMAGING A Thesis by JULIO ENRIQUE AYALA II Submitted to the Office of Graduate...

Ayala, Julio Enqrique, II

2007-04-25T23:59:59.000Z

238

Magnet options for sensors for the pulp and paper industry  

SciTech Connect (OSTI)

The Lawrence Berkeley National Laboratory (LBNL) has been developing sensors for the pulp and paper industry that uses a magnetic field. The applications for magnetic sensors that have studied include (1) sensors for the measurement of the water and ice content of wood chips entering the pulping mill, (2) sensors for measuring the water content and other constituents of the black liquor leaving the paper digester, and (3) sensors for measuring paper thickness and water content as the paper is being processed. These tasks can be done using nuclear magnetic resonance (NMR). The magnetic field used for doing the NMR can come from either permanent magnets or superconducting magnets. The choice of the magnet is dependent on a number of factors, which include the size of the sample and field strength needed to do the sensing task at hand. This paper describes some superconducting magnet options that can be used in the pulp and paper industry.

Green, M.A.; Barale, P.J.; Fong, C.G.; Luft, P.A.; Reimer, J.A.; Yahnke, M.S.

2001-05-05T23:59:59.000Z

239

Nuclear magnetic resonance (N.M.R.) studies of alkyl formates and of alcohol-water azeotropes  

E-Print Network [OSTI]

from Eq. 2 for 12 Alkyl Formates in Carbon tetrachloride at 37'. Typical N. M. R. Spectrum of a Non-Azeotropic Ethanol- Water Mixture . 16 N. M. R. Spectrum Occasionally Found for Azeotropic Ethanol-Water Mixtures 17 PART I. ALKYL FORMATES... CHAPTER I. INTRODUCTION 1 It has been shown that eq. 1 applies almost exactly to the data for the alkaline hydrolysis of 9 acetate eaters (CH COOR ) in 40% 0 aqueous p - dioxane at 35 . In eq. 1, k is the second-order rate log k = l. 35 + 0. 688 o + 0...

O'Brien, Patrick William

2012-06-07T23:59:59.000Z

240

Site-Selective Determination of Magnetic Helices in BaTiCoFe{sub 10}O{sub 19} by Resonant Magnetic Scattering  

SciTech Connect (OSTI)

Synchrotron radiation intensity measurements were made for single crystals of ferrimagnetic BaTiCoFe{sub 10}O{sub 19} at the BL-6C(3A) beamline of the Photon Factory. The resonant x-ray magnetic scattering (RXMS) method at the Fe K edge makes it possible to determine the magnetic crystal structure, having the magnetic helices for Fe ions in tetrahedral 4f{sub 1}, bipyramidal 2b, and octahedral 2a, 4f{sub 2} and 12k sites. Based on the information on x-ray magnetic circular dichroism (XMCD) and a resonant magnetic scattering factor f''{sub m} ( = 0.23) estimated from BaFe{sub 12}O{sub 19} at E = 7128.2 eV, the magnetic structures have been determined from an asymmetrical ratio {Delta}R (Y{sup +}-Y{sup -})/(Y{sup +}+Y{sup -}), where Y{sup +} and Y{sup -} are scattering intensities for left- and right-circular polarizations, respectively. Spin orientations were estimated in the least-squares procedure to minimize a residual factor of {Sigma}({Delta}R{sub obs}-{Delta}R{sub calc}){sup 2}. The canting angles estimated in this study are 180 deg., 19 deg., 118 deg., 180 deg. and 65 deg. for the magnetic moments of Fe ions in 4f{sub 1}, 2b, 2a, 4f{sub 2} and 12k sites, respectively.

Okube, Maki; Kaneko, Yuhei; Ohsawa, Seiji; Sasaki, Satoshi [Materials and Structures Laboratory, Tokyo Institute of Technology, Nagatsuta 4259, Yokohama 226-8503 (Japan); Toyoda, Takeshi [Industrial Research Institute of Ishikawa, Kuratsuki 2-1, Kanazawa 920-8203 (Japan); Mori, Takeharu [Photon Factory, Institute of Materials Structure Science, KEK, Oho 1-1, Tsukuba 305-0801 (Japan)

2010-06-23T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Nuclear spin conversion of water inside fullerene cages detected by low-temperature nuclear magnetic resonance  

SciTech Connect (OSTI)

The water-endofullerene H{sub 2}O@C{sub 60} provides a unique chemical system in which freely rotating water molecules are confined inside homogeneous and symmetrical carbon cages. The spin conversion between the ortho and para species of the endohedral H{sub 2}O was studied in the solid phase by low-temperature nuclear magnetic resonance. The experimental data are consistent with a second-order kinetics, indicating a bimolecular spin conversion process. Numerical simulations suggest the simultaneous presence of a spin diffusion process allowing neighbouring ortho and para molecules to exchange their angular momenta. Cross-polarization experiments found no evidence that the spin conversion of the endohedral H{sub 2}O molecules is catalysed by {sup 13}C nuclei present in the cages.

Mamone, Salvatore, E-mail: s.mamone@soton.ac.uk; Concistr, Maria; Carignani, Elisa; Meier, Benno; Krachmalnicoff, Andrea; Johannessen, Ole G.; Denning, Mark; Carravetta, Marina; Whitby, Richard J.; Levitt, Malcolm H., E-mail: mhl@soton.ac.uk [School of Chemistry, University of Southampton, Southampton SO17 1BJ (United Kingdom); Lei, Xuegong; Li, Yongjun [Department of Chemistry, Columbia University, New York, New York 10027 (United States)] [Department of Chemistry, Columbia University, New York, New York 10027 (United States); Goh, Kelvin; Horsewill, Anthony J. [School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom)] [School of Physics and Astronomy, University of Nottingham, Nottingham NG7 2RD (United Kingdom)

2014-05-21T23:59:59.000Z

242

Three path interference using nuclear magnetic resonance: a test of the consistency of Born's rule  

E-Print Network [OSTI]

The Born rule is at the foundation of quantum mechanics and transforms our classical way of understanding probabilities by predicting that interference occurs between pairs of independent paths of a single object. One consequence of the Born rule is that three way (or three paths) quantum interference does not exist. In order to test the consistency of the Born rule, we examine detection probabilities in three path intereference using an ensemble of spin-1/2 quantum registers in liquid state nuclear magnetic resonance (LSNMR). As a measure of the consistency, we evaluate the ratio of three way interference to two way interference. Our experiment bounded the ratio to the order of $10^{-3} \\pm 10^{-3}$, and hence it is consistent with Born's rule.

Daniel K. Park; Osama Moussa; Raymond Laflamme

2012-07-10T23:59:59.000Z

243

Preliminary tests using magnetic resonance imaging of two-phase flow patterns and transitions  

SciTech Connect (OSTI)

This paper presents the results of preliminary tests used to establish the feasibility of using magnetic resonance imaging (MRI) to examine and quantitatively characterize two-phase flow patterns and flow transitions. These tests were performed at the University of California, San Francisco (UCSF) School of Medicine MRI Center as a collaborative research effort with Oregon State University (OSU). Special scanning sequences designed by UCSF for flow imaging were implemented in the tests. UCSF operated the MRI facility, and OSU constructed and operated a cocurrent air-water flow loop consisting of a 1-in.-diam test section capable of producing air superficial velocities j[sub g] ranging from 0.3 to 14 m/s, and water superficial velocities j[sub l] ranging from 0.08 to 1.3 m/s.

Reyes, J.N. Jr.; Lafi, A.Y. (Oregon State Univ., Corvallis, OR (United States)); Saloner, D. (Univ. of California, San Francisco, CA (United States))

1993-01-01T23:59:59.000Z

244

Magnetic Resonance Flow Velocity and Temperature Mapping of a Shape Memory Polymer Foam Device  

SciTech Connect (OSTI)

Interventional medical devices based on thermally responsive shape memory polymer (SMP) are under development to treat stroke victims. The goals of these catheter-delivered devices include re-establishing blood flow in occluded arteries and preventing aneurysm rupture. Because these devices alter the hemodynamics and dissipate thermal energy during the therapeutic procedure, a first step in the device development process is to investigate fluid velocity and temperature changes following device deployment. A laser-heated SMP foam device was deployed in a simplified in vitro vascular model. Magnetic resonance imaging (MRI) techniques were used to assess the fluid dynamics and thermal changes associated with device deployment. Spatial maps of the steady-state fluid velocity and temperature change inside and outside the laser-heated SMP foam device were acquired. Though non-physiological conditions were used in this initial study, the utility of MRI in the development of a thermally-activated SMP foam device has been demonstrated.

Small IV, W; Gjersing, E; Herberg, J L; Wilson, T S; Maitland, D J

2008-10-29T23:59:59.000Z

245

NMR experimental realization of seventh-order coupling transformations and the seven-qubit modified Deutsch-Jozsa algorithm  

E-Print Network [OSTI]

We propose a scalable method on the basis of nth-order coupling operators to construct f-dependent phase transformations in the n-qubit modified Deutsch-Jozsa (D-J) quantum algorithm. The novel n-qubit entangling transformations are easily implemented via J-couplings between neighboring spins. The seven-qubit modified D-J quantum algorithm and seventh-order coupling transformations are then experimentally demonstrated with liquid state nuclear magnetic resonance (NMR) techniques. The method may offer the possibility of creating generally entangled states of n qubits and simulating n-body interactions on n-qubit NMR quantum computers.

Daxiu Wei; Jun Luo; Xiaodong Yang; Xianping Sun; Xizhi Zeng; Maili Liu; Shangwu Ding; Mingsheng Zhan

2003-01-10T23:59:59.000Z

246

K-space reconstruction of magnetic resonance inverse imaging (K-InI) of human visuomotor systems  

E-Print Network [OSTI]

MRI InI Visual MRI Neuroimaging K-InI Inverse solution MEG EEG Electroencephalography channels of a radio-frequency coil array, magnetic resonance inverse imaging (InI) can achieve ultra. Mathematically, the InI reconstruction is a generalization of parallel MRI (pMRI), which includes image space

247

Resonant  

Office of Scientific and Technical Information (OSTI)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinan antagonist Journal Article: CrystalFG36-08GO18149Speeding accessProposal Title:TechnicalSmall) Resonant

248

Diffusion-assisted selective dynamical recoupling: A new approach to measure background gradients in magnetic resonance  

SciTech Connect (OSTI)

Dynamical decoupling, a generalization of the original NMR spin-echo sequence, is becoming increasingly relevant as a tool for reducing decoherence in quantum systems. Such sequences apply non-equidistant refocusing pulses for optimizing the coupling between systems, and environmental fluctuations characterized by a given noise spectrum. One such sequence, dubbed Selective Dynamical Recoupling (SDR) [P. E. S. Smith, G. Bensky, G. A. lvarez, G. Kurizki, and L. Frydman, Proc. Natl. Acad. Sci. 109, 5958 (2012)], allows one to coherently reintroduce diffusion decoherence effects driven by fluctuations arising from restricted molecular diffusion [G. A. lvarez, N. Shemesh, and L. Frydman, Phys. Rev. Lett. 111, 080404 (2013)]. The fully-refocused, constant-time, and constant-number-of-pulses nature of SDR also allows one to filter out intrinsic T{sub 1} and T{sub 2} weightings, as well as pulse errors acting as additional sources of decoherence. This article explores such features when the fluctuations are now driven by unrestricted molecular diffusion. In particular, we show that diffusion-driven SDR can be exploited to investigate the decoherence arising from the frequency fluctuations imposed by internal gradients. As a result, SDR presents a unique way of probing and characterizing these internal magnetic fields, given an a priori known free diffusion coefficient. This has important implications in studies of structured systems, including porous media and live tissues, where the internal gradients may serve as fingerprints for the system's composition or structure. The principles of this method, along with full analytical solutions for the unrestricted diffusion-driven modulation of the SDR signal, are presented. The potential of this approach is demonstrated with the generation of a novel source of MRI contrast, based on the background gradients active in an ex vivo mouse brain. Additional features and limitations of this new method are discussed.

lvarez, Gonzalo A.; Shemesh, Noam; Frydman, Lucio, E-mail: lucio.frydman@weizmann.ac.il [Department of Chemical Physics, Weizmann Institute of Science, Rehovot 76100 (Israel)] [Department of Chemical Physics, Weizmann Institute of Science, Rehovot 76100 (Israel)

2014-02-28T23:59:59.000Z

249

Potential Applications of Microtesla Magnetic Resonance ImagingDetected Using a Superconducting Quantum Interference Device  

SciTech Connect (OSTI)

This dissertation describes magnetic resonance imaging (MRI) of protons performed in a precession field of 132 {micro}T. In order to increase the signal-to-noise ratio (SNR), a pulsed 40-300 mT magnetic field prepolarizes the sample spins and an untuned second-order superconducting gradiometer coupled to a low transition temperature superconducting quantum interference device (SQUID) detects the subsequent 5.6-kHz spin precession. Imaging sequences including multiple echoes and partial Fourier reconstruction are developed. Calculating the SNR of prepolarized SQUID-detected MRI shows that three-dimensional Fourier imaging yields higher SNR than slice-selection imaging. An experimentally demonstrated field-cycling pulse sequence and post-processing algorithm mitigate image artifacts caused by concomitant gradients in low-field MRI. The magnetic field noise of SQUID untuned detection is compared to the noise of SQUID tuned detection, conventional Faraday detection, and the Nyquist noise generated by conducting biological samples. A second-generation microtesla MRI system employing a low-noise SQUID is constructed to increase SNR. A 2.4-m cubic, eddy-current shield with 6-mm thick aluminum walls encloses the experiment to attenuate external noise. The measured noise is 0.75 fT Hz{sup -1/2} referred to the bottom gradiometer loop. Solenoids wound from 30-strand braided wire to decrease Nyquist noise and cooled by either liquid nitrogen or water polarize the spins. Copper wire coils wound on wooden supports produce the imaging magnetic fields and field gradients. Water phantom images with 0.8 x 0.8 x 10 mm{sup 3} resolution have a SNR of 6. Three-dimensional 1.6 x 1.9 x 14 mm{sup 3} images of bell peppers and 3 x 3 x 26 mm{sup 3} in vivo images of the human arm are presented. Since contrast based on the transverse spin relaxation rate (T{sub 1}) is enhanced at low magnetic fields, microtesla MRI could potentially be used for tumor imaging. The measured T{sub 1} of ex vivo normal and cancerous prostate tissue differ significantly at 132 {micro}T. A single-sided MRI system designed for prostate imaging could achieve 3 x 3 x 5 mm{sup 3} resolution in 8 minutes. Existing SQUID-based magnetoencephalography (MEG) systems could be used as microtesla MRI detectors. A commercial 275-channel MEG system could acquire 6-minute brain images with (4 mm){sup 3} resolution and SNR 16.

Myers, Whittier R.

2006-05-18T23:59:59.000Z

250

Quantitative Determination of Chemical Processes by Dynamic Nuclear Polarization Enhanced Nuclear Magnetic Resonance Spectroscopy  

E-Print Network [OSTI]

Dissolution dynamic nuclear polarization (DNP) provides several orders of magnitude of NMR signal enhancement by converting the much larger electron spin polarization to nuclear spin polarization. Polarization occurs at low temperature (1.4K...

Zeng, Haifeng

2012-07-16T23:59:59.000Z

251

Structure and dynamics studies by solid-state nuclear magnetic resonance spectroscopy  

E-Print Network [OSTI]

The major goal of this work is the development of high resolution solid state 205T1 NMR techniques and their application to the elucidation of the mechanism and dynamics of ion exchange in biological solids. The thesis ...

Itin, Boris

2002-01-01T23:59:59.000Z

252

Pore-structure determinations of silica aerogels by {sup 129}Xe NMR spectroscopy and imaging.  

SciTech Connect (OSTI)

Silica aerogels represent a new class of open-pore materials with pore dimensions on a scale of tens of nanometers, and are thus classified as mesoporous materials. In this work, we show that the combination of NMR spectroscopy and chemical-shift selective magnetic resonance imaging (MRI) can resolve some of the important aspects of the structure of silica aerogels. The use of xenon as a gaseous probe in combination with spatially resolved NMR techniques is demonstrated to be a powerful, new approach for characterizing the average pore structure and steady-state spatial distributions of xenon atoms in different physicochemical environments. Furthermore, dynamic NMR magnetization transfer experiments and pulsed-field gradient (PFG) measurements have been used to characterize exchange processes and diffusive motion of xenon in samples at equilibrium. In particular, this new NMR approach offers unique information and insights into the nanoscopic pore structure and microscopic morphology of aerogels and the dynamical behavior of occluded adsorbates. MRI provides spatially resolved information on the nature of the flaw regions found in these materials. Pseudo-first-order rate constants for magnetization transfer among the bulk and occluded xenon phases indicate xenon-exchange rate constants on the order of 1 s-1 for specimens having volumes of 0.03 cm3. PFG diffusion measurements show evidence of anisotropic diffusion for xenon occluded within aerogels, with nominal self-diffusivity coefficients on the order of D= 10-3cm2/s.

Gregory, D. M.; Gerald, R. E., II; Botto, R. E.; Chemistry

1998-04-01T23:59:59.000Z

253

NMR imaging techniques and applications in the flow behavior of fluids in porous media  

E-Print Network [OSTI]

proton magnetic resonance technique can be used to determine the oil saturation in the pores of a rock. The NMR system can produce images of the molecules under investigation because the signals recorded are obtained directly from fluids contained... in liquids as well. This should enable us to obtain additional information about the fluids in the rock '4. Spin-spin relaxation has a characteristic time T~. T~ is the time constant for the decay of the precessing R-Zo component of the magnetization...

Halimi, Hassan I

1990-01-01T23:59:59.000Z

254

The Magnetic Resonance Force Microscope P. Chris Hammel and Denis V. Pelekhov  

E-Print Network [OSTI]

, Zhang, Moore and Roukes, 1995; Bruland et al., 1998) and ferromagnetic resonance (FMR) experiments

Hammel, P. Chris

255

Suppression of electron correlations in the collapsed tetragonal phase of CaFe2As2 under ambient pressure demonstrated by As75 NMR/NQR measurements  

SciTech Connect (OSTI)

The static and the dynamic spin correlations in the low-temperature collapsed tetragonal and the high-temperature tetragonal phase in CaFe2As2 have been investigated by As75 nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements. Through the temperature (T) dependence of the nuclear spin lattice relaxation rates (1/T1) and the Knight shifts, although stripe-type antiferromagnetic (AFM) spin correlations are realized in the high-temperature tetragonal phase, no trace of the AFM spin correlations can be found in the nonsuperconducting, low-temperature, collapsed tetragonal (cT) phase. Given that there is no magnetic broadening in As75 NMR spectra, together with the T-independent behavior of magnetic susceptibility ? and the T dependence of 1/T1T?, we conclude that Fe spin correlations are completely quenched statically and dynamically in the nonsuperconducting cT phase in CaFe2As2.

Furukawa, Yuji [Ames Laboratory; Roy, Beas [Ames Laboratory; Ran, Sheng [Ames Laboratory; Budko, Sergey L. [Ames Laboratory; Canfield, Paul C. [Ames Laboratory

2014-03-20T23:59:59.000Z

256

Detection of electron energy distribution function anisotropy in a magnetized electron cyclotron resonance plasma by using a directional Langmuir probe  

SciTech Connect (OSTI)

Anisotropy in the electron energy distribution function (EEDF) in an electron cyclotron resonance plasma with magnetized electrons and weakly magnetized ions is experimentally investigated using a directional Langmuir probe. Under an assumption of independent EEDFs in the directions parallel and perpendicular to the magnetic field, the directional variation of the EEDF is evaluated. In the measured EEDFs, a significantly large population density of electrons with energies larger than 30?eV is found in one of the cross-field directions depending on the magnetic field direction. With the aid of an electron trajectory calculation, it is suggested that the observed anisotropic electrons originate from the EEDF anisotropy and the cross-field electron drift.

Shikama, T., E-mail: shikama@me.kyoto-u.ac.jp; Hasuo, M. [Department of Mechanical Engineering and Science, Graduate School of Engineering, Kyoto University, Kyoto 615-8540 (Japan); Kitaoka, H. [Faculty of Engineering, Undergraduate School of Engineering Science, Kyoto University, Kyoto 615-8540 (Japan)

2014-07-15T23:59:59.000Z

257

A nuclear magnetic resonance study of hydrogen in battery and chemically prepared material  

SciTech Connect (OSTI)

Solid-state magic-angle-spinning nuclear magnetic resonance studies have been undertaken on positive plate material from lead-acid batteries and on samples of both pure ..cap alpha..-PbO/sub 2/ and pure ..beta..-PbO/sub 2/ prepared by nonelectrochemical methods. Battery positive plate samples contain protons in two different surface and near surface configurations. One of these proton species is associated with mobile, isolated, adsorbed hydroxyl groups, and/or water molecules that can be removed by outgassing. The other proton species is not removed by outgassing; it probably corresponds to water molecules and/of closely spaced hydroxyl groups trapped on internal crystal surfaces. The proton species present in fresh (uncycled) positive plate material are not significantly different in either configuration or abundance from those in extensively cycled samples. Thus, it is unlikely that decline in battery capacity with cycling service is associated with a change in the hydrogen content of PbO/sub 2/.

Hill, R.J.; Jessel, A.M.

1987-06-01T23:59:59.000Z

258

Lithium-7 nuclear magnetic resonance investigation of lithium insertion in hard carbon  

SciTech Connect (OSTI)

Lithium battery anodes based on disordered, hard carbon were prepared by low-temperature (1,000 C) pyrolysis of cotton cloth. Samples were lithiated in an electrochemical cell. The Li insertion (potential vs. capacity) curve exhibits two different regions: a sloping one, from 1.1 to 0.1 V (vs Li/Li{sup +}) denoted as the high-voltage region (HVR), and a plateau between 0.1 and zero V, denoted as the low-voltage plateau (LVP). Lithium-7 high-resolution (magic angle spinning) nuclear magnetic resonance measurements in fully lithiated samples reveal three main features: a broad line at ca. 50 ppm, a relatively sharp line at 17 ppm, with a shoulder at about zero ppm (all shifts relative to aqueous LiCl). The 50 ppm component is attributed to Li intercalated between turbostratically disordered graphene planes and is associated with the LVP part of the potential curve. The 17 ppm signal arises from a Li site which resides in amorphous hydrogen-containing regions of the carbon and is correlated with the HVR part of the curve. The zero ppm component is attributed to the irreversible portion of the Li (up to {approximately} 20% of the total) which constitutes the solid electrolyte interphase on the surface of the carbon grains formed by electrochemical reduction of the electrolyte. These spectral assignments were verified by running other samples which were electrochemically delithiated to varying degrees.

Dai, Y.; Wang, Y.; Greenbaum, S.G. [City Univ. of New York, NY (United States). Dept. of Physics; Eshkenazi, V.; Peled, E. [Tel Aviv Univ., IL (United States). School of Chemistry

1998-04-01T23:59:59.000Z

259

Radiation-Induced Alterations in Mouse Brain Development Characterized by Magnetic Resonance Imaging  

SciTech Connect (OSTI)

Purpose: The purpose of this study was to identify regions of altered development in the mouse brain after cranial irradiation using longitudinal magnetic resonance imaging (MRI). Methods and Materials: Female C57Bl/6 mice received a whole-brain radiation dose of 7 Gy at an infant-equivalent age of 2.5 weeks. MRI was performed before irradiation and at 3 time points following irradiation. Deformation-based morphometry was used to quantify volume and growth rate changes following irradiation. Results: Widespread developmental deficits were observed in both white and gray matter regions following irradiation. Most of the affected brain regions suffered an initial volume deficit followed by growth at a normal rate, remaining smaller in irradiated brains compared with controls at all time points examined. The one exception was the olfactory bulb, which in addition to an early volume deficit, grew at a slower rate thereafter, resulting in a progressive volume deficit relative to controls. Immunohistochemical assessment revealed demyelination in white matter and loss of neural progenitor cells in the subgranular zone of the dentate gyrus and subventricular zone. Conclusions: MRI can detect regional differences in neuroanatomy and brain growth after whole-brain irradiation in the developing mouse. Developmental deficits in neuroanatomy persist, or even progress, and may serve as useful markers of late effects in mouse models. The high-throughput evaluation of brain development enabled by these methods may allow testing of strategies to mitigate late effects after pediatric cranial irradiation.

Gazdzinski, Lisa M.; Cormier, Kyle [Mouse Imaging Centre, Hospital for Sick Children, Toronto (Canada)] [Mouse Imaging Centre, Hospital for Sick Children, Toronto (Canada); Lu, Fred G. [Department of Radiation Oncology, Sunnybrook Health Sciences Centre, Toronto (Canada)] [Department of Radiation Oncology, Sunnybrook Health Sciences Centre, Toronto (Canada); Lerch, Jason P. [Mouse Imaging Centre, Hospital for Sick Children, Toronto (Canada) [Mouse Imaging Centre, Hospital for Sick Children, Toronto (Canada); Department of Medical Biophysics, University of Toronto, Toronto (Canada); Wong, C. Shun [Department of Radiation Oncology, Sunnybrook Health Sciences Centre, Toronto (Canada) [Department of Radiation Oncology, Sunnybrook Health Sciences Centre, Toronto (Canada); Department of Medical Biophysics, University of Toronto, Toronto (Canada); Department of Radiation Oncology, University of Toronto, Toronto (Canada); Nieman, Brian J., E-mail: bjnieman@phenogenomics.ca [Mouse Imaging Centre, Hospital for Sick Children, Toronto (Canada); Department of Medical Biophysics, University of Toronto, Toronto (Canada)

2012-12-01T23:59:59.000Z

260

Discrete magic angle turning system, apparatus, and process for in situ magnetic resonance spectroscopy and imaging  

DOE Patents [OSTI]

Described are a "Discrete Magic Angle Turning" (DMAT) system, devices, and processes that combine advantages of both magic angle turning (MAT) and magic angle hopping (MAH) suitable, e.g., for in situ magnetic resonance spectroscopy and/or imaging. In an exemplary system, device, and process, samples are rotated in a clockwise direction followed by an anticlockwise direction of exactly the same amount. Rotation proceeds through an angle that is typically greater than about 240 degrees but less than or equal to about 360 degrees at constant speed for a time applicable to the evolution dimension. Back and forth rotation can be synchronized and repeated with a special radio frequency (RF) pulse sequence to produce an isotropic-anisotropic shift 2D correlation spectrum. The design permits tubes to be inserted into the sample container without introducing plumbing interferences, further allowing control over such conditions as temperature, pressure, flow conditions, and feed compositions, thus permitting true in-situ investigations to be carried out.

Hu, Jian Zhi (Richland, WA); Sears, Jr., Jesse A. (Kennewick, WA); Hoyt, David W. (Richland, WA); Wind, Robert A. (Kennewick, WA)

2009-05-19T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Plasma studies of the permanent magnet electron cyclotron resonance ion source at Peking University  

SciTech Connect (OSTI)

At Peking University (PKU) we have developed several 2.45 GHz Permanent Magnet Electron Cyclotron Resonance ion sources for PKUNIFTY, SFRFQ, Coupled RFQ and SFRFQ, and Dielectric-Wall Accelerator (DWA) projects (respectively, 50 mA of D{sup +}, 10 mA of O{sup +}, 10 mA of He{sup +}, and 50 mA of H{sup +}). In order to improve performance of these ion sources, it is necessary to better understand the principal factors that influence the plasma density and the atomic ion fraction. Theoretical analysis about microwave transmission and cut-off inside the discharge chamber were carried out to study the influence of the discharge chamber diameters. As a consequence, experimental studies on plasma density and ion fraction with different discharge chamber sizes have been carried out. Due to the difficulties in measuring plasma density inside the discharge chamber, the output beam current was measured to reflect the plasma density. Experimental results show that the plasma density increases to the maximum and then decreases significantly as the diameter changed from 64 mm to 30 mm, and the atomic ion fraction has the same tendency. The maximum beam intensity was obtained with the diameter of 35 mm, but the maximum atomic ion fraction with a diameter of 40 mm. The experimental results are basically accordant with the theoretical calculation. Details are presented in this paper.

Ren, H. T.; Peng, S. X., E-mail: sxpeng@pku.edu.cn; Xu, Y.; Zhao, J.; Lu, P. N.; Chen, J.; Zhang, A. L.; Zhang, T.; Guo, Z. Y.; Chen, J. E. [State Key Laboratory of Nuclear Physics and Technology, Institute of Heavy Ion Physics, Peking University, Beijing 100871 (China)] [State Key Laboratory of Nuclear Physics and Technology, Institute of Heavy Ion Physics, Peking University, Beijing 100871 (China)

2014-02-15T23:59:59.000Z

262

E-Print Network 3.0 - advanced magnetic resonance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(Namikawa, 1985; Gibbs, 1988) channels. These include studies... weak, synchrotron radiation brightness, together with resonant ... Source: Haskel, Daniel - Advanced Photon...

263

Investigation of wettability by NMR microscopy and spin-lattice relaxation  

SciTech Connect (OSTI)

The wettability of reservoir rock has an important impact on the efficiency of oil recovery processes and the distribution of oil and water within the reservoir. One of the potentially useful tools for wettability measurements is nuclear magnetic resonance (NMR) and spin-lattice relaxation. More recently using NMR microscopy NIPER has developed the capability of imaging one- and two-phase fluid systems in reservoir rock at resolutions to 25 microns. Effects seen in the images of fluids within the pore space of rocks near the rock grain surfaces hinted at the possibility of using NMR microscopy to map the wettability variations at grain sites within the pore space. Investigations were begun using NMR microscopy and spin-lattice relaxation time measurements on rock/fluid systems and on well-defined fractional wet model systems to study these effects. Relaxation data has been modelled using the stretched exponential relationship recently introduced. Comparisons of the NMR microscopy results of the model system with the rock results indicate that the observed effects probably do not reflect actual wettability variations within the pore space. The results of the relaxation time measurements reveal that even in the simple model studied, the behavior of two phases is somewhat ambiguous and much more complex and requires more study.

Doughty, D.A.; Tomutsa, Liviu

1993-11-01T23:59:59.000Z

264

NbF{sub 5} and TaF{sub 5}: Assignment of {sup 19}F NMR resonances and chemical bond analysis from GIPAW calculations  

SciTech Connect (OSTI)

The {sup 19}F isotropic chemical shifts (?{sub iso}) of two isomorphic compounds, NbF{sub 5} and TaF{sub 5}, which involve six nonequivalent fluorine sites, have been experimentally determined from the reconstruction of 1D {sup 19}F MAS NMR spectra. In parallel, the corresponding {sup 19}F chemical shielding tensors have been calculated using the GIPAW method for both experimental and DFT-optimized structures. Furthermore, the [M{sub 4}F{sub 20}] units of NbF{sub 5} and TaF{sub 5} being held together by van der Waals interactions, the relevance of Grimme corrections to the DFT optimization processes has been evaluated. However, the semi-empirical dispersion correction term introduced by such a method does not show any significant improvement. Nonetheless, a complete and convincing assignment of the {sup 19}F NMR lines of NbF{sub 5} and TaF{sub 5} is obtained, ensured by the linearity between experimental {sup 19}F ?{sub iso} values and calculated {sup 19}F isotropic chemical shielding ?{sub iso} values. The effects of the geometry optimizations have been carefully analyzed, confirming among other matters, the inaccuracy of the experimental structure of NbF{sub 5}. The relationships between the fluorine chemical shifts, the nature of the fluorine atoms (bridging or terminal), the position of the terminal ones (opposite or perpendicular to the bridging ones), the fluorine charges, the ionicity and the length of the MF bonds have been established. Additionally, for three of the {sup 19}F NMR lines of NbF{sub 5}, distorted multiplets, arising from {sup 1}J-coupling and residual dipolar coupling between the {sup 19}F and {sup 93}Nb nuclei, were simulated yielding to values of {sup 93}Nb{sup 19}F {sup 1}J-coupling for the corresponding fluorine sites. - Graphical abstract: The complete assignment of the {sup 19}F NMR lines of NbF{sub 5} and TaF{sub 5} allow establishing relationships between the {sup 19}F ?{sub iso} values, the nature of the fluorine atoms (bridging or terminal), the position of the terminal ones (opposite or perpendicular to the bridging ones), the fluorine charges, the ionicity and the length of the MF bonds. Display Omitted - Highlights: The {sup 19}F ?{sub iso} values of NbF{sub 5} and TaF{sub 5} have been determined. The {sup 19}F chemical shielding tensors have been calculated using the GIPAW method. A confident assignment of the {sup 19}F NMR lines of NbF{sub 5} and TaF{sub 5} is obtained. The relationships between the {sup 19}F?{sub iso} values and the MF bonds features are established.

Biswal, Mamata, E-mail: Mamata.Biswal-Susanta_Kumar_Nayak.Etu@univ-lemans.fr [LUNAM Universit, Universit du Maine, CNRS UMR 6283, Institut des Molcules et des Matriaux du Mans, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9 (France); Body, Monique, E-mail: monique.body@univ-lemans.fr [LUNAM Universit, Universit du Maine, CNRS UMR 6283, Institut des Molcules et des Matriaux du Mans, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9 (France); Legein, Christophe, E-mail: christophe.legein@univ-lemans.fr [LUNAM Universit, Universit du Maine, CNRS UMR 6283, Institut des Molcules et des Matriaux du Mans, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9 (France); Sadoc, Aymeric, E-mail: Aymeric.Sadoc@cnrs-imn.fr [Institut des Matriaux Jean Rouxel (IMN), Universit de Nantes, CNRS, 2 rue de la Houssinire, BP 32229, 44322 Nantes Cedex 3 (France); Boucher, Florent, E-mail: Florent.Boucher@cnrs-imn.fr [Institut des Matriaux Jean Rouxel (IMN), Universit de Nantes, CNRS, 2 rue de la Houssinire, BP 32229, 44322 Nantes Cedex 3 (France)

2013-11-15T23:59:59.000Z

265

Nb3Sn superconducting magnets for electron cyclotron resonance ion sources  

E-Print Network [OSTI]

the design of a N b S n superconducting magnet system for aNbjSn superconducting magnets for electron cyclotron5 C H 1 1 2 3 1 . Nb Sn superconducting magnets for electron

Ferracin, P.

2011-01-01T23:59:59.000Z

266

Method for nuclear magnetic resonance imaging using deuterum as a contrast agent  

DOE Patents [OSTI]

A method for in vivo NMR imaging of the blood vessels and organs of a patient characterized by using a dark dye-like imaging substance consisting essentially of a stable, high-purity concentration of D.sub.2 O in a solution with water.

Kehayias, Joseph J. (Chestnut Hill, MA); Joel, Darrel D. (Setauket, NY); Adams, William H. (Eastport, NY); Stein, Harry L. (Glen Head, NY)

1990-01-01T23:59:59.000Z

267

Impact of screening of resonant magnetic perturbations in three dimensional edge plasma transport simulations for DIII-D  

SciTech Connect (OSTI)

The impact of resonant magnetic perturbations (RMPs) on the plasma edge can be analyzed in detail by three dimensional computer simulations, which take the underlying magnetic field structure as input. Previously, the 'vacuum approximation' has been used to calculate the magnetic field structure although plasma response effects may result in a screening (or even an amplification) of the external perturbations. Simulation results for an ITER similar shape plasma at the DIII-D tokamak are presented for the full vacuum perturbation field and an ad hoc screening case in comparison to the unperturbed configuration. It is shown that the RMP induced helical patterns in the plasma edge and on the divertor target shrink once screening is taken into account. However, a flat temperature profile is still found in the 'open field line domain' inside the separatrix, while the 'density pump out effect' found in the vacuum RMP case is considerably weakened.

Frerichs, H.; Reiter, D.; Schmitz, O. [Institute of Energy and Climate Research-Plasma Physics, Forschungszentrum Juelich GmbH, Association EURATOM-FZJ, Partner in the Trilateral Euregio Cluster, Juelich (Germany); Cahyna, P. [Institute of Plasma Physics AS CR, v.v.i., Association EURATOM/IPP.CR, Prague (Czech Republic); Evans, T. E. [General Atomics, P.O. Box 85608, San Diego, California 92186-5608 (United States); Feng, Y. [Max-Planck Institute for Plasma Physics, Greifswald (Germany); Nardon, E. [Association EURATOM-CEA, IRFM, CEA Cadarache, St-Paul-lez-Durance (France)

2012-05-15T23:59:59.000Z

268

Prediction of Liver Function by Using Magnetic Resonance-based Portal Venous Perfusion Imaging  

SciTech Connect (OSTI)

Purpose: To evaluate whether liver function can be assessed globally and spatially by using volumetric dynamic contrast-enhanced magnetic resonance imaging MRI (DCE-MRI) to potentially aid in adaptive treatment planning. Methods and Materials: Seventeen patients with intrahepatic cancer undergoing focal radiation therapy (RT) were enrolled in institution review board-approved prospective studies to obtain DCE-MRI (to measure regional perfusion) and indocyanine green (ICG) clearance rates (to measure overall liver function) prior to, during, and at 1 and 2 months after treatment. The volumetric distribution of portal venous perfusion in the whole liver was estimated for each scan. We assessed the correlation between mean portal venous perfusion in the nontumor volume of the liver and overall liver function measured by ICG before, during, and after RT. The dose response for regional portal venous perfusion to RT was determined using a linear mixed effects model. Results: There was a significant correlation between the ICG clearance rate and mean portal venous perfusion in the functioning liver parenchyma, suggesting that portal venous perfusion could be used as a surrogate for function. Reduction in regional venous perfusion 1 month after RT was predicted by the locally accumulated biologically corrected dose at the end of RT (P<.0007). Regional portal venous perfusion measured during RT was a significant predictor for regional venous perfusion assessed 1 month after RT (P<.00001). Global hypovenous perfusion pre-RT was observed in 4 patients (3 patients with hepatocellular carcinoma and cirrhosis), 3 of whom had recovered from hypoperfusion, except in the highest dose regions, post-RT. In addition, 3 patients who had normal perfusion pre-RT had marked hypervenous perfusion or reperfusion in low-dose regions post-RT. Conclusions: This study suggests that MR-based volumetric hepatic perfusion imaging may be a biomarker for spatial distribution of liver function, which could aid in individualizing therapy, particularly for patients at risk for liver injury after RT.

Cao Yue, E-mail: yuecao@umich.edu [Department of Radiation Oncology, University of Michigan, Ann Arbor, Michigan (United States); Department of Radiology, University of Michigan, Ann Arbor, Michigan (United States); Wang Hesheng [Department of Radiation Oncology, University of Michigan, Ann Arbor, Michigan (United States)] [Department of Radiation Oncology, University of Michigan, Ann Arbor, Michigan (United States); Johnson, Timothy D. [Department of Biostatistics, University of Michigan, Ann Arbor, Michigan (United States)] [Department of Biostatistics, University of Michigan, Ann Arbor, Michigan (United States); Pan, Charlie [Department of Radiation Oncology, University of Michigan, Ann Arbor, Michigan (United States)] [Department of Radiation Oncology, University of Michigan, Ann Arbor, Michigan (United States); Hussain, Hero [Department of Radiology, University of Michigan, Ann Arbor, Michigan (United States)] [Department of Radiology, University of Michigan, Ann Arbor, Michigan (United States); Balter, James M.; Normolle, Daniel; Ben-Josef, Edgar; Ten Haken, Randall K.; Lawrence, Theodore S.; Feng, Mary [Department of Radiation Oncology, University of Michigan, Ann Arbor, Michigan (United States)] [Department of Radiation Oncology, University of Michigan, Ann Arbor, Michigan (United States)

2013-01-01T23:59:59.000Z

269

Cardiac Magnetic Resonance Imaging Findings in 20-year Survivors of Mediastinal Radiotherapy for Hodgkin's Disease  

SciTech Connect (OSTI)

Purpose: The recognition of the true prevalence of cardiac toxicity after mediastinal radiotherapy requires very long follow-up and a precise diagnostic procedure. Cardiac magnetic resonance imaging (MRI) permits excellent quantification of cardiac function and identification of localized myocardial defects and has now been applied to a group of 20-year Hodgkin's disease survivors. Methods and materials: Of 143 patients treated with anterior mediastinal radiotherapy (cobalt-60, median prescribed dose 40 Gy) for Hodgkin's disease between 1978 and 1985, all 53 survivors were invited for cardiac MRI. Of those, 36 patients (68%) presented for MRI, and in 31 patients (58%) MRI could be performed 20-28 years (median, 24) after radiotherapy. The following sequences were acquired on a 1.5-T MRI: transversal T1-weighted TSE and T2-weighted half-fourier acquisition single-shot turbo-spin-echo sequences, a steady-state free precession (SSFP) cine sequence in the short heart axis and in the four-chamber view, SSFP perfusion sequences under rest and adenosine stress, and a SSFP inversion recovery sequence for late enhancement. The MRI findings were correlated with previously reconstructed doses to cardiac structures. Results: Clinical characteristics and reconstructed doses were not significantly different between survivors undergoing and not undergoing MRI. Pathologic findings were reduced left ventricular function (ejection fraction <55%) in 7 (23%) patients, hemodynamically relevant valvular dysfunction in 13 (42%), late myocardial enhancement in 9 (29%), and any perfusion deficit in 21 (68%). An association of regional pathologic changes and reconstructed dose to cardiac structures could not be established. Conclusions: In 20-year survivors of Hodgkin's disease, cardiac MRI detects pathologic findings in approximately 70% of patients. Cardiac MRI has a potential role in cardiac imaging of Hodgkin's disease patients after mediastinal radiotherapy.

Machann, Wolfram; Beer, Meinrad [Department of Radiology, University of Wuerzburg (Germany); Breunig, Margret; Stoerk, Stefan; Angermann, Christiane [Department of Cardiology, University of Wuerzburg (Germany); Seufert, Ines; Schwab, Franz; Koelbl, Oliver; Flentje, Michael [Department of Radiation Oncology, University of Wuerzburg (Germany); Vordermark, Dirk, E-mail: dirk.vordermark@medizin.uni-halle.d [Department of Radiation Oncology, University of Wuerzburg (Germany); Department of Radiation Oncology, Martin Luther University Halle-Wittenberg (Germany)

2011-03-15T23:59:59.000Z

270

Magnetic Resonance Imaging-Guided Osseous Biopsy in Children With Chronic Recurrent Multifocal Osteomyelitis  

SciTech Connect (OSTI)

Purpose: To report the safety and diagnostic performance of magnetic resonance (MRI)-guided core biopsy of osseous lesions in children with chronic recurrent multifocal osteomyelitis (CRMO) that were visible on MRI but were occult on radiography and computed tomography (CT). Materials and Methods: A retrospective analysis of MRI-guided osseous biopsy performed in seven children (four girls and three boys; mean age 13 years (range 11 to 14) with CRMO was performed. Indication for using MRI guidance was visibility of lesions by MRI only. MRI-guided procedures were performed with 0.2-Tesla (Magnetom Concerto; Siemens, Erlangen, Germany; n = 5) or 1.5-T (Magnetom Espree; Siemens; n = 2) open MRI systems. Core needle biopsy was obtained using an MRI-compatible 4-mm drill system. Conscious sedation or general anesthesia was used. Parameters evaluated were lesion visibility, technical success, procedure time, complications and microbiology, cytology, and histopathology findings. Results: Seven of seven (100%) targeted lesions were successfully visualized and sampled. All obtained specimens were sufficient for histopathological analysis. Length of time of the procedures was 77 min (range 64 to 107). No complications occurred. Histopathology showed no evidence of malignancy, which was confirmed at mean follow-up of 50 months (range 28 to 78). Chronic nonspecific inflammation characteristic for CRMO was present in four of seven (58%) patients, and edema with no inflammatory cells was found in three of seven (42%) patients. There was no evidence of infection in any patient. Conclusion: MRI-guided osseous biopsy is a safe and accurate technique for the diagnosis of pediatric CRMO lesions that are visible on MRI only.

Fritz, Jan, E-mail: jfritz9@jhmi.edu [Johns Hopkins University School of Medicine, Russell H. Morgan Department of Radiology and Radiological Science (United States); Tzaribachev, Nikolay [University Children's Hospital, Eberhard-Karls-University Tuebingen, Division of Pediatric Rheumatology (Germany); Thomas, Christoph [Eberhard-Karls-University Tuebingen, Department of Diagnostic and Interventional Radiology (Germany); Wehrmann, Manfred [Eberhard-Karls-University Tuebingen, Department of Pathology (Germany); Horger, Marius S. [Eberhard-Karls-University Tuebingen, Department of Diagnostic and Interventional Radiology (Germany); Carrino, John A. [Johns Hopkins University School of Medicine, Russell H. Morgan Department of Radiology and Radiological Science (United States); Koenig, Claudius W.; Pereira, Philippe L. [Eberhard-Karls-University Tuebingen, Department of Diagnostic and Interventional Radiology (Germany)

2012-02-15T23:59:59.000Z

271

Effect of Gold Marker Seeds on Magnetic Resonance Spectroscopy of the Prostate  

SciTech Connect (OSTI)

Purpose: Magnetic resonance stereoscopic imaging (MRSI) of the prostate is an emerging technique that may enhance targeting and assessment in radiotherapy. Current practices in radiotherapy invariably involve image guidance. Gold seed fiducial markers are often used to perform daily prostate localization. If MRSI is to be used in targeting prostate cancer and therapy assessment, the impact of gold seeds on MRSI must be investigated. The purpose of this study was to quantify the effects of gold seeds on the quality of MRSI data acquired in phantom experiments. Methods and Materials: A cylindrical plastic phantom with a spherical cavity 10 centimeters in diameter wss filled with water solution containing choline, creatine, and citrate. A gold seed fiducial marker was put near the center of the phantom mounted on a plastic stem. Spectra were acquired at 1.5 Tesla by use of a clinical MRSI sequence. The ratios of choline + creatine to citrate (CC/Ci) were compared in the presence and absence of gold seeds. Spectra in the vicinity of the gold seed were analyzed. Results: The maximum coefficient of variation of CC/Ci induced by the gold seed was found to be 10% in phantom experiments at 1.5 T. Conclusion: MRSI can be used in prostate radiotherapy in the presence of gold seed markers. Gold seeds cause small effects (in the order of the standard deviation) on the ratio of the metabolite's CC/Ci in the phantom study done on a 1.5-T scanner. It is expected that gold seed markers will have similar negligible effect on spectra from prostate patients. The maximum of 10% of variation in CC/Ci found in the phantom study also sets a limit on the threshold accuracy of CC/Ci values for deciding whether the tissue characterized by a local spectrum is considered malignant and whether it is a candidate for local boost in radiotherapy dose.

Hossain, Murshed, E-mail: Murshed.Hossain@fccc.edu [Department of Radiation Oncology, Fox Chase Cancer Center, Philadelphia, PA (United States); Schirmer, Timo [Global MR Applied Science Laboratory, GE Healthcare, Munich (Germany); Richardson, Theresa; Chen, Lili; Buyyounouski, Mark K.; Ma Changming [Department of Radiation Oncology, Fox Chase Cancer Center, Philadelphia, PA (United States)

2012-05-01T23:59:59.000Z

272

E-Print Network 3.0 - angio-magnetic resonance finding Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

resonator is placed in contact with soil medium and the real and imaginary parts of soil Source: Sarabandi, Kamal - Radiation Laboratory & Department of Electrical Engineering and...

273

E-Print Network 3.0 - alpha-chloroacetone nmr study Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

over the past... several years. Dual Volume Double Resonance Microcoil NMR Probe Dual Coil probe has the upper coil Source: Raftery, Dan - Department of Chemistry, Purdue...

274

Solid State Nuclear Magnetic Resonance Investigation of Polymer Backbone Dynamics in Poly(Ethylene Oxide) Based Lithium and Sodium Polyether-ester-sulfonate Ionomers  

SciTech Connect (OSTI)

Polymer backbone dynamics of single ion conducting poly(ethylene oxide) (PEO)-based ionomer samples with low glass transition temperatures (Tg) have been investigated using solid-state nuclear magnetic resonance (NMR). Experiments detecting 13C with 1H decoupling under magic angle spinning (MAS) conditions identified the different components of the polymer backbone (PEO spacer and isophthalate groups) and their relative mobilities for a suite of lithium- and sodium-containing ionomer samples with varying cation contents. Variable temperature (203-373 K) 1H-13C cross-polarization MAS (CP-MAS) experiments also provided qualitative assessment of the differences in the motions of the polymer backbone components as a function of cation content and identity. Each of the main backbone components exhibit distinct motions, following the trends expected for motional characteristics based on earlier Quasi Elastic Neutron Scattering and 1H spin-lattice relaxation rate measurements. Previous 1H and 7Li spin-lattice relaxation measurements focused on both the polymer backbone and cation motion on the nanosecond timescale. The studies presented here assess the slower timescale motion of the polymer backbone allowing for a more comprehensive understanding of the polymer dynamics. The temperature dependences of 13C linewidths were used to both qualitatively and quantitatively examine the effects of cation content and identity on PEO spacer mobility. Variable contact time 1H-13C CP-MAS experiments were used to further assess the motions of the polymer backbone on the microsecond timescale. The motion of the PEO spacer, reported via the rate of magnetization transfer from 1H to 13C nuclei, becomes similar for T ? 1.1 Tg in all ionic samples, indicating that at similar elevated reduced temperatures the motions of the polymer backbones on the microsecond timescale become insensitive to ion interactions. These results present an improved picture, beyond those of previous findings, for the dependence of backbone dynamics on cation density (and here, cation identity as well) in these amorphous PEO-based ionomer systems.

Roach, David J. [Penn State Univ., State College, PA (United States). Dept. of Chemistry; Dou, Shichen [Penn State Univ., State College, PA (United States). Dept. of Materials Science and Engineering; Colby, Ralph H. [Penn State Univ., State College, PA (United States). Dept. of Materials Science and Engineering; Mueller, Karl T. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Penn State Univ., State College, PA (United States). Dept. of Chemistry

2013-05-21T23:59:59.000Z

275

Magnetic fields at resonant conditions for the hydrogen ion affect neurite outgrowth in PC-12 cells: A test of the ion parametric resonance model  

SciTech Connect (OSTI)

PC-12 cells primed with nerve growth factor (NGF) were exposed to sinusoidal extremely-low-frequency (ELF) magnetic fields (MFs) selected to test the predictions of the ion parametric resonance (IPR) model under resonance conditions for a single ion (hydrogen). The authors examined the field effects on the neurite outgrowth (NO) induced by NGF using three different combinations of flux densities of the parallel components of the AC MF (B{sub ac}) and the static MF (B{sub dc}). The first test examined the NO response in cells exposed to 45 Hz at a B{sub dc} of 2.96 {micro}T with resonant conditions for H{sup +} according to the model. The B{sub ac} values ranged from 0.29 to 4.11 {micro}T root-mean-square (rms). In the second test, the MF effects at off-resonance conditions (i.e., no biologically significant ion at resonance) were examined using the frequency of 45 Hz with a B{sub dc} of 1.97 {micro}T and covering a B{sub ac} range between 0.79 and 2.05 {micro}T rms. In the third test, the Ac frequency was changed to 30 Hz with the subsequent change in B{sub dc} to 1.97 {micro}T to tune for H{sup +} as in the first test. The B{sub ac} values ranged from 0.79 to 2.05 {micro}T rms. After a 23 h incubation and exposure to the MF in the presence of NGF (5 ng/ml), the NO was analyzed using a stereoscopic microscope. The results showed that the NGF stimulation of neurite outgrowth (NSNO) was affected by MF combinations over most of the B{sub ac} exposure range generally consistent with the predictions of the IPR model. However, for a distinct range of B{sub ac} where the IPR model predicted maximal ionic influence, the observed pattern of NSNO contrasted sharply with those predictions. The symmetry of this response suggests that values of B{sub ac} within this distinct range may trigger alternate or additional cellular mechanisms that lead to an apparent lack of response to the MF stimulus.

Trillo, M.A.; Ubeda, A. [Hospital Ramon y Cajal, Madrid (Spain). Dept. Investigacion] [Hospital Ramon y Cajal, Madrid (Spain). Dept. Investigacion; Blanchard, J.P. [Bechtel Corp., San Francisco, CA (United States). Research and Development Dept.] [Bechtel Corp., San Francisco, CA (United States). Research and Development Dept.; House, D.E.; Blackman, C.F. [Environmental Protection Agency, Research Triangle Park, NC (United States)] [Environmental Protection Agency, Research Triangle Park, NC (United States)

1996-04-01T23:59:59.000Z

276

Magnetofossil spike during the Paleocene-Eocene thermal maximum: Ferromagnetic resonance, rock magnetic, and electron microscopy  

E-Print Network [OSTI]

Magnetofossil spike during the Paleocene-Eocene thermal maximum: Ferromagnetic resonance, rock,2 Timothy D. Raub,3,4 Dirk Schumann,5 Hojatollah Vali,5 Alexei V. Smirnov,3,6 and Joseph L. Kirschvink1 controversial hypothesis that a cometary impact triggered the PETM. Here we present ferromagnetic resonance (FMR

277

Interface defects in SiC power MOSFETs - An electrically detected magnetic resonance study based on spin dependent recombination  

SciTech Connect (OSTI)

This study presents electrically detected magnetic resonance (EDMR) measurements on a silicon carbide (SiC) MOSFET having the structure of a double-diffused silicon MOSFET (DMOS). The resonance pattern of a SiC DMOS was measured by monitoring the change of the recombination current between the source/body and the drain. The amplitude of the response has a maximum when the device is biased in depletion due to the equal concentrations of electrons and holes at the interface resulting in the most efficient recombination. The measured anisotropic g-tensor has axial symmetry with g{sub ?} = 2.0051(4) (B ? c-axis), and g{sub ?} = 2.0029(4) (B? c-axis) and the pattern shows several hyperfine (HF) peaks. We tentatively identify the observed defect as a silicon vacancy located directly at the interface.

Gruber, Gernot [KAI GmbH, Europastrasse 8, 9500 Villach, Austria and Graz University of Technology - Institute of Solid State Physics, Petersgasse 16, 8020 Graz (Austria); Hadley, Peter [Graz University of Technology - Institute of Solid State Physics, Petersgasse 16, 8020 Graz (Austria); Koch, Markus [Graz University of Technology - Institute of Experimental Physics, Petersgasse 16, 8020 Graz (Austria); Peters, Dethard [Infineon Technologies, Schottkystrasse 10, 91058 Erlangen (Germany); Aichinger, Thomas [Infineon Technologies, Siemensstrasse 2, 9500 Villach (Australia)

2014-02-21T23:59:59.000Z

278

Investigation of Mechanical Activation on Li-N-H Systems Using 6Li Magic Angle Spinning Nuclear Magnetic Resonance at Ultra-High Field  

SciTech Connect (OSTI)

Abstract The significantly enhanced spectral resolution in the 6Li MAS NMR spectra of Li-N-H systems at ultra-high field of 21.1 tesla is exploited, for the first time, to study the detailed electronic and chemical environmental changes associated with mechanical activation of Li-N-H system using high energy balling milling. Complementary to ultra-high field studies, the hydrogen discharge dynamics are investigated using variable temperature in situ 1H MAS NMR at 7.05 tesla field. The significantly enhanced spectral resolution using ultra-high filed of 21.1 tesla was demonstrated along with several major findings related to mechanical activation, including the upfield shift of the resonances in 6Li MAS spectra induced by ball milling, more efficient mechanical activation with ball milling at liquid nitrogen temperature than with ball milling at room temperature, and greatly enhanced hydrogen discharge exhibited by the liquid nitrogen ball milled samples.

Hu, Jian Zhi; Kwak, Ja Hun; Yang, Zhenguo; Osborn, William; Markmaitree, Tippawan; Shaw, Leonard D.

2008-07-15T23:59:59.000Z

279

Evaluating Swallowing Muscles Essential for Hyolaryngeal Elevation by Using Muscle Functional Magnetic Resonance Imaging  

SciTech Connect (OSTI)

Purpose: Reduced hyolaryngeal elevation, a critical event in swallowing, is associated with radiation therapy. Two muscle groups that suspend the hyoid, larynx, and pharynx have been proposed to elevate the hyolaryngeal complex: the suprahyoid and longitudinal pharyngeal muscles. Thought to assist both groups is the thyrohyoid, a muscle intrinsic to the hyolaryngeal complex. Intensity modulated radiation therapy guidelines designed to preserve structures important to swallowing currently exclude the suprahyoid and thyrohyoid muscles. This study used muscle functional magnetic resonance imaging (mfMRI) in normal healthy adults to determine whether both muscle groups are active in swallowing and to test therapeutic exercises thought to be specific to hyolaryngeal elevation. Methods and Materials: mfMRI data were acquired from 11 healthy subjects before and after normal swallowing and after swallowing exercise regimens (the Mendelsohn maneuver and effortful pitch glide). Whole-muscle transverse relaxation time (T2 signal, measured in milliseconds) profiles of 7 test muscles were used to evaluate the physiologic response of each muscle to each condition. Changes in effect size (using the Cohen d measure) of whole-muscle T2 profiles were used to determine which muscles underlie swallowing and swallowing exercises. Results: Post-swallowing effect size changes (where a d value of >0.20 indicates significant activity during swallowing) for the T2 signal profile of the thyrohyoid was a d value of 0.09; a d value of 0.40 for the mylohyoid, 0.80 for the geniohyoid, 0.04 for the anterior digastric, and 0.25 for the posterior digastric-stylohyoid in the suprahyoid muscle group; and d values of 0.47 for the palatopharyngeus and 0.28 for the stylopharyngeus muscles in the longitudinal pharyngeal muscle group. The Mendelsohn maneuver and effortful pitch glide swallowing exercises showed significant effect size changes for all muscles tested, except for the thyrohyoid. Conclusions: Muscles of both the suprahyoid and the longitudinal pharyngeal muscle groups are active in swallowing, and both swallowing exercises effectively target muscles elevating the hyolaryngeal complex. mfMRI is useful in testing swallowing muscle function.

Pearson, William G., E-mail: bp1@bu.edu [Department of Anatomy and Neurobiology, Boston University School of Medicine, Boston, Massachusetts (United States); Hindson, David F. [Department of Radiology, Boston Medical Center, Boston, Massachusetts (United States)] [Department of Radiology, Boston Medical Center, Boston, Massachusetts (United States); Langmore, Susan E. [Department of Otolaryngology, Boston Medical Center, Boston, Massachusetts (United States) [Department of Otolaryngology, Boston Medical Center, Boston, Massachusetts (United States); Speech and Hearing Sciences, Boston University, Boston, Massachusetts (United States); Zumwalt, Ann C. [Department of Anatomy and Neurobiology, Boston University School of Medicine, Boston, Massachusetts (United States)] [Department of Anatomy and Neurobiology, Boston University School of Medicine, Boston, Massachusetts (United States)

2013-03-01T23:59:59.000Z

280

MagLab - Meet the Magnets: 45 Tesla Hybrid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Features > Meet the Magnets Meet the Magnets Choose a Magnet 45 Tesla Hybrid 900 MHz NMR Magnet 25 Tesla Split Magnet 14.5 Tesla ICR Magnet 100 Tesla Multi-shot Magnet 600 MHz...

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
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281

Magnetic-dipolar-mode Fano resonances for microwave spectroscopy of high absorption matter  

E-Print Network [OSTI]

Study of interaction between high absorption matter and microwave radiated energy is a subject of great importance. Especially, this concerns microwave spectroscopic characterization of biological liquids. Use of effective testing methods to obtain information about physical properties of different liquids on the molecular level is one of the most important problems in biophysics. However, the standard methods based on the microwave resonant techniques are not sufficiently suitable for biological liquids because the resonance peak in a resonator with high-loss liquids is so broad that the material parameters cannot be measured correctly. Although molecular vibrations of biomolecules may have microwave frequencies, it is not thought that such resonant coupling is significant due to their low energy compared with thermal energy and the strongly dampening aqueous environment. This paper presents an innovative microwave sensing technique for different types of lossy materials, including biological liquids. The te...

Vaisman, G; Shavit, R

2015-01-01T23:59:59.000Z

282

Method of using a nuclear magnetic resonance spectroscopy standard. [SO/sub 2/ in gases by fluorescence  

DOE Patents [OSTI]

(CH/sub 3/)/sub 3/SiNSO is produced by the reaction of ((CH/sub 3/)/sub 3/SI)/sub 2/NH with SO/sub 2/. Also produced in the reaction are ((CH/sub 3/)/sub 3/Si)/sub 2/O and a new solid compound (NH/sub 4/)((CH/sub 3/)/sub 3/SiOSO/sub 2/). Both (CH/sub 3/)/sub 3/SiNSO and (NH/sub 4/)((CH/sub 3/)/sub 3/SiOSO/sub 2/) have fluorescent properties. The reaction of the subject invention is used in a method of measuring the concentration of SO/sub 2/ pollutants in gases. By the method, a sample of gas is bubbled through a solution of ((CH/sub 3/)/sub 3/Si)/sub 2/NH, whereby any SO/sub 2/ present in the gas will react to produce the two fluorescent products. The measured fluorescence of these products can then be used to calculate the concentration of SO/sub 2/ in the original gas sample. The solid product (NH/sub 4/)((CH/sub 3/)/sub 3/SiOSO/sub 2/) may be used as a standard in solid state NMR spectroscopy, wherein the resonance peaks of either /sup 1/H, /sup 13/C, /sup 15/N, or /sup 29/Si may be used as a reference.

Spicer, L.D.; Bennett, D.W.; Davis, J.F.

1983-05-09T23:59:59.000Z

283

Magnetic resonance as a structural probe of a uranium (VI) sol-gel process  

SciTech Connect (OSTI)

NMR investigations on the ORNL process for sol-gel synthesis of microspherical nuclear fuel (UO{sub 2}), has been useful in sorting out the chemical mechanism in the sol-gel steps. {sup 13}C, {sup 15}N, and {sup 1}H NMR studies on the HMTA gelation agent (Hexamethylene tetramine, C{sub 6}H{sub l2}N{sub 4}) has revealed near quantitative stability of this adamantane-like compound in the sol-Gel process, contrary to its historical role as an ammonia source for gelation from the worldwide technical literature. {sub 17}0 NMR of uranyl (UO{sub 2}{sup ++}) hydrolysis fragments produced in colloidal sols has revealed the selective formation of a uranyl trimer, ((UO{sub 2}){sub 3}({mu}{sub 3}-O)({mu}{sub 2}-OH){sub 3}){sup +}, induced by basic hydrolysis with the HMTA gelation agent. Spectroscopic results show that trimer condensation occurs during sol-gel processing leading to layered polyanionic hydrous uranium oxides in which HMTAH{sup +} is occluded as an intercalation'' cation. Subsequent sol-gel processing of microspheres by ammonia washing results in in-situ ion exchange and formation of a layered hydrous ammonium uranate with a proposed structural formula of (NH{sub 4}){sub 2}((UO{sub 2}){sub 8}O{sub 4}(OH){sub 10}) {center dot} 8H{sub 2}0. This compound is the precursor to sintered U0{sub 2} ceramic fuel.

King, C.M.; Thompson, M.C.; Buchanan, B.R. (Westinghouse Savannah River Co., Aiken, SC (United States)); King, R.B. (Georgia Univ., Athens, GA (United States). Dept. of Chemistry); Garber, A.R. (South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry)

1989-01-01T23:59:59.000Z

284

Magnetic resonance as a structural probe of a uranium (VI) sol-gel process  

SciTech Connect (OSTI)

NMR investigations on the ORNL process for sol-gel synthesis of microspherical nuclear fuel (UO{sub 2}), has been useful in sorting out the chemical mechanism in the sol-gel steps. {sup 13}C, {sup 15}N, and {sup 1}H NMR studies on the HMTA gelation agent (Hexamethylene tetramine, C{sub 6}H{sub l2}N{sub 4}) has revealed near quantitative stability of this adamantane-like compound in the sol-Gel process, contrary to its historical role as an ammonia source for gelation from the worldwide technical literature. {sub 17}0 NMR of uranyl (UO{sub 2}{sup ++}) hydrolysis fragments produced in colloidal sols has revealed the selective formation of a uranyl trimer, [(UO{sub 2}){sub 3}({mu}{sub 3}-O)({mu}{sub 2}-OH){sub 3}]{sup +}, induced by basic hydrolysis with the HMTA gelation agent. Spectroscopic results show that trimer condensation occurs during sol-gel processing leading to layered polyanionic hydrous uranium oxides in which HMTAH{sup +} is occluded as an ``intercalation`` cation. Subsequent sol-gel processing of microspheres by ammonia washing results in in-situ ion exchange and formation of a layered hydrous ammonium uranate with a proposed structural formula of (NH{sub 4}){sub 2}[(UO{sub 2}){sub 8}O{sub 4}(OH){sub 10}] {center_dot} 8H{sub 2}0. This compound is the precursor to sintered U0{sub 2} ceramic fuel.

King, C.M.; Thompson, M.C.; Buchanan, B.R. [Westinghouse Savannah River Co., Aiken, SC (United States); King, R.B. [Georgia Univ., Athens, GA (United States). Dept. of Chemistry; Garber, A.R. [South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry

1989-12-31T23:59:59.000Z

285

A solid-state nuclear magnetic resonance study of the reactions of propene on HY zeolite  

E-Print Network [OSTI]

, and condensation. The main objective of this study was to determine the reaction mechanism (including the observation of intermediates) for propane adsorbed on HY zeolite. C enriched propene was adsorbed on HY zeolite at room temperature, and it was observed..., as denoted by arrows C CP/MAS spectrum of propene-2- C 13 adsorbed on HY zeolite at room temperature 10 The polymerization reaction proposed in reference 13 for the adsorption of propene on HY zeolite The Bloch decay pulse sequence in NMR experiments...

Oshiro, Irene Sueko

1988-01-01T23:59:59.000Z

286

Evaluation of the toroidal torque driven by external non-resonant non-axisymmetric magnetic field perturbations in a tokamak  

SciTech Connect (OSTI)

The toroidal torque driven by external non-resonant magnetic perturbations (neoclassical toroidal viscosity) is an important momentum source affecting the toroidal plasma rotation in tokamaks. The well-known force-flux relation directly links this torque to the non-ambipolar neoclassical particle fluxes arising due to the violation of the toroidal symmetry of the magnetic field. Here, a quasilinear approach for the numerical computation of these fluxes is described, which reduces the dimension of a standard neoclassical transport problem by one without model simplifications of the linearized drift kinetic equation. The only limiting condition is that the non-axisymmetric perturbation field is small enough such that the effect of the perturbation field on particle motion within the flux surface is negligible. Therefore, in addition to most of the transport regimes described by the banana (bounce averaged) kinetic equation also such regimes as, e.g., ripple-plateau and resonant diffusion regimes are naturally included in this approach. Based on this approach, a quasilinear version of the code NEO-2 [W. Kernbichler et al., Plasma Fusion Res. 3, S1061 (2008).] has been developed and benchmarked against a few analytical and numerical models. Results from NEO-2 stay in good agreement with results from these models in their pertinent range of validity.

Kasilov, Sergei V. [Fusion@AW, Institut fr Theoretische PhysikComputational Physics, Technische Universitt Graz Petersgasse 16, A8010 Graz (Austria); Institute of Plasma Physics National Science Center Kharkov Institute of Physics and Technology ul. Akademicheskaya 1, 61108 Kharkov (Ukraine); Kernbichler, Winfried; Martitsch, Andreas F.; Heyn, Martin F. [Fusion@AW, Institut fr Theoretische PhysikComputational Physics, Technische Universitt Graz Petersgasse 16, A8010 Graz (Austria); Maassberg, Henning [Max-Planck Institut fr Plasmaphysik, D-17491 Greifswald (Germany)

2014-09-15T23:59:59.000Z

287

Fructose-induced aberration of metabolism in familial gout identified by sup 31 P magnetic resonance spectroscopy  

SciTech Connect (OSTI)

The hyperuricemia responsible for the development of gouty arthritis results from a wide range of environmental factors and underlying genetically determined aberrations of metabolism. {sup 31}P magnetic resonance spectroscopy studies of children with hereditary fructose intolerance revealed a readily detectable rise in phosphomonoesters with a marked fall in inorganic phosphate in their liver in vivo and a rise in serum urate in response to very low doses of oral fructose. Parents and some family members heterozygous for this enzyme deficiency showed a similar pattern when given a substantially larger dose of fructose. Three of the nine heterozygotes thus identified also had clinical gout, suggesting the possibility of this defect being a fairly common cause of gout. In the present study this same noninvasive technology was used to identify the same spectral pattern in 2 of the 11 families studied with hereditary gout. In one family, the index patient's three brothers and his mother all showed the fructose-induced abnormality of metabolism, in agreement with the maternal inheritance of metabolism, in agreement with the maternal inheritance of the gout in this family group. The test dose of fructose used produced a significantly larger increment in the concentration of serum urate in the patients showing the changes in {sup 31}P magnetic resonance spectra than in the other patients with familial gout or in nonaffected members, thus suggesting a simpler method for initial screening for the defect.

Seegmiller, J.E. (John Radcliffe Hospital, Oxford (England) Univ. of California, San Diego (United States)); Dixon, R.M.; Kemp, G.J.; Rajagopalan, B.; Radda, G.K. (John Radcliffe Hospital, Oxford (England)); Angus, P.W. (John Radcliffe Hospital, Oxford (England) Austin Hospital, Heidelburg, Victoria (Australia)); McAlindon, T.E.; Dieppe, P. (Univ. of Bristol (England))

1990-11-01T23:59:59.000Z

288

Assessment of Wall Shear Stress Changes in Arteries and Veins of Arteriovenous Polytetrafluoroethylene Grafts Using Magnetic Resonance Imaging  

SciTech Connect (OSTI)

The purpose of the study was to determine simultaneously the temporal changes in luminal vessel area, blood flow, and wall shear stress (WSS) in both the anastomosed artery (AA) and vein (AV) of arteriovenous polytetrafluoroethylene (PTFE) grafts. PTFE grafts were placed from the iliac artery to the ipsilateral iliac vein in 12 castrated juvenile male pigs. Contrast-enhanced magnetic resonance angiograpgy with cine phase-contrast magnetic resonance imaging was performed. Luminal vessel area, blood flow, and WSS in the aorta, AA, AV, and inferior vena cava were determined at 3 days (D3), 7 days (D7), and 14 days (D14) after graft placement. Elastin von Gieson staining of the AV was performed. The average WSS of the AA was highest at D3 and then decreased by D7 and D14. In contrast, the average WSS and intima-to-media ratio of the AV increased from D3 to D7 and peaked by D14. Similarly, the average area of the AA was highest by D7 and began to approximate the control artery by D14. The average area of the AV had decreased to its lowest by D7. High blood flows through the AA causes a decrease in average WSS and increase in the average luminal vessel area, whereas at the AV, the average WSS and intima-to-media ratio both increase while the average luminal vessel area decreases.

Misra, Sanjay, E-mail: Misra.sanjay@mayo.edu; Woodrum, David A. [Mayo Clinic, Department of Radiology (United States); Homburger, Jay [Medical College of Georgia, Department of Vascular Surgery (United States); Elkouri, Stephane [Centre Hospitalier de I'Universite de Montreal, Department of Vascular Surgery (Canada); Mandrekar, Jayawant N. [Mayo Clinic, Division of Biostatistics (United States); Barocas, Victor [University of Minnesota, Department of Biomedical Engineering (United States); Glockner, James F. [Mayo Clinic, Department of Radiology (United States); Rajan, Dheeraj K. [Toronto General Hospital, University Health Network, Department of Medical Imaging, Division of Vascular and Interventional Radiology (Canada); Mukhopadhyay, Debabrata [Mayo Clinic, Department of Biochemistry and Molecular Biology (United States)

2006-08-15T23:59:59.000Z

289

2H NMR | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NMR Leads No leads are available at this time. Local environment and composition of magnesium gallium layered double hydroxides determined from solid-state 1H and 71Ga NMR...

290

EMSL - 2H NMR  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

tags2h-nmr en Local environment and composition of magnesium gallium layered double hydroxides determined from solid-state 1H and 71Ga NMR http:www.emsl.pnl.govemslweb...

291

Free-Electron Laser-Powered Electron Paramagnetic Resonance Spectroscopy  

E-Print Network [OSTI]

Electron paramagnetic resonance (EPR) spectroscopy interrogates unpaired electron spins in solids and liquids to reveal local structure and dynamics; for example, EPR has elucidated parts of the structure of protein complexes that have resisted all other techniques in structural biology. EPR can also probe the interplay of light and electricity in organic solar cells and light-emitting diodes, and the origin of decoherence in condensed matter, which is of fundamental importance to the development of quantum information processors. Like nuclear magnetic resonance (NMR), EPR spectroscopy becomes more powerful at high magnetic fields and frequencies, and with excitation by coherent pulses rather than continuous waves. However, the difficulty of generating sequences of powerful pulses at frequencies above 100 GHz has, until now, confined high-power pulsed EPR to magnetic fields of 3.5 T and below. Here we demonstrate that ~1 kW pulses from a free-electron laser (FEL) can power a pulsed EPR spectrometer at 240 GHz...

Takahashi, S; Edwards, D T; van Tol, J; Ramian, G; Han, S; Sherwin, M S

2012-01-01T23:59:59.000Z

292

Two-channel R-matrix analysis of magnetic-field-induced Feshbach resonances  

SciTech Connect (OSTI)

A Feshbach resonance arises in cold atom scattering due to the complex interplay between several coupled channels. However, the essential physics of the resonance may be encapsulated in a simplified model consisting of just two coupled channels. In this paper we describe in detail how such an effective Feshbach model can be constructed from knowledge of a few key parameters, characterizing the atomic Born-Oppenheimer potentials and the low energy scattering near the resonance. These parameters may be obtained either from experiment or full coupled-channel calculations. Using R-matrix theory we analyze the bound state spectrum and the scattering properties of the two-channel model, and find it to be in good agreement with exact calculations.

Nygaard, Nicolai; Schneider, Barry I.; Julienne, Paul S. [Danish National Research Foundation Center for Quantum Optics, Department of Physics and Astronomy, University of Aarhus, DK-8000 Aarhus C (Denmark); Physics Division, National Science Foundation, Arlington, Virginia 22230 (United States) and Electron and Optical Physics Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Atomic Physics Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States)

2006-04-15T23:59:59.000Z

293

Fast and contrast-enhanced phase-sensitive magnetic resonance imaging  

E-Print Network [OSTI]

two signals if the resonance frequencies are close. For example, in MR mammography, it is difficult to separate silicone breast implants signals (4.0 ppm) from fat signals (3.5 ppm); (2) the signal dynamic range of images acquired using Dixon...

Son, Jong Bum

2009-05-15T23:59:59.000Z

294

Directed evolution of a magnetic resonance imaging contrast agent for noninvasive imaging of dopamine  

E-Print Network [OSTI]

The development of molecular probes that allow in vivo imaging of neural signaling processes with high temporal and spatial resolution remains challenging. Here we applied directed evolution techniques to create magnetic ...

Shapiro, Mikhail G.

295

Magnetic and microwave properties of U-type hexaferrite films with high remanence and low ferromagnetic resonance linewidth  

SciTech Connect (OSTI)

U-type barium hexaferrite films (Ba{sub 4}Ni{sub 1.4}Co{sub 0.6}Fe{sub 36}O{sub 60}) were deposited on (0001) sapphire substrates by pulsed laser deposition. Microstructure and magnetic properties of the films were characterized by X-ray diffraction, scanning electron microscopy and vibrating sample magnetometry. Ferromagnetic resonance (FMR) measurements were performed at X-band. The results indicate an anisotropy field of ?8 kOe, and the saturation magnetization (4?M{sub s}) of ?3.6 kG. An optimal post-deposition annealing of films results in a strong (0 0?n) crystallographic texture and a high hysteresis loop squareness (M{sub r}/M{sub s}?=?92%) leading to self biased properties. Furthermore, the highly self-biased ferrite films exhibited an FMR linewidth of ?200?Oe. The U-type hexaferrite films having low microwave loss, low magnetic anisotropy field, and high squareness are a suitable alternative to Sc or In doped BaM ferrites that have been the choice material for self-biased microwave devices at X-band frequencies.

Su, Zhijuan; Bennett, Steven; Hu, Bolin; Chen, Yajie, E-mail: y.chen@neu.edu; Harris, Vincent G. [Center for Microwave Magnetic Materials and Integrated Circuits, Northeastern University, Boston, Massachusetts 02115, USA and The Department of Electrical and Computer Engineering, Northeastern University, Boston, Massachusetts 02115 (United States)

2014-05-07T23:59:59.000Z

296

Quantum Information Processing by NMR using strongly coupled spins  

E-Print Network [OSTI]

The enormous theoretical potential of Quantum Information Processing (QIP) is driving the pursuit for its practical realization by various physical techniques. Currently Nuclear Magnetic Resonance (NMR) has been the forerunner by demonstrating a majority of quantum algorithms. In NMR, spin systems consisting of coupled nuclear spins are utilized as qubits. In order to carry out QIP, a spin system has to meet two major requirements: (i) qubit addressability and (ii) mutual coupling among the qubits. It has been demonstrated that the magnitude of the mutual coupling among qubits can be increased by orienting the spin-systems in a liquid crystal matrix and utilizing the residual dipolar couplings. While utilizing residual dipolar couplings may be useful to increase the number of qubits, nuclei of same species (homonuclei) might become strongly coupled. In strongly coupled spin-systems, spins loose their individual identity of being qubits. We propose that even such strongly coupled spin-systems can be used for QIP and the qubit-manipulation can be achieved by transition-selective pulses. We demonstrate experimental preparation of pseudopure states, creation of maximally entangled states, implementation logic gates and implementation of Deutsch-Jozsa (DJ) algorithm in strongly coupled 2,3 and 4 spin systems. The energy levels of the strongly coupled 3 and 4 spin systems were obtained by using a Z-COSY experiment.

T. S. Mahesh; Neeraj Sinha; Arindam Ghosh; Ranabir Das; N. Suryaprakash; Malcom H. Levitt; K. V. Ramanathan; Anil Kumar

2003-11-24T23:59:59.000Z

297

Development of a microwave ion and plasma source immersed in a multicusp electron-cyclotron-resonant magnetic field  

SciTech Connect (OSTI)

Experimental development and test of an electrodeless microwave (2.45 GHz)-generated plasma and ion source in a discharge pressure range of 6 x 10 /sup -4/-5 x 10/sup -1/ Torr and relatively low power (80-350 W CW) are presented. Also presented is a semi-empirical model applicable to low-pressure microwave discharges with no static magnetic field. Initial experiments studied the properties of variable diffusion length (0.43-1.22 cm) disk-shaped discharges generated and maintained in a cylindrical microwave resonant-cavity applicator for argon and oxygen gases without a static magnetic field. These discharges were characterized by measuring plasma densities and electron temperatures using a Langmuir double probe for different experimental conditions. The measured plasma densities and electron temperatures ranged for 8 x 10/sup 10/ to 5 x 10 /sup 11/ cm/sup -3/ and 2 x 10/sup 4/ to 8 x 10/sup 4/ /sup 0/K, respectively. The ion temperature was less than 500 /sup 0/K. Ion beams were extracted from these discharges using single and double grids. Argon ion-beam currents densities were measured to be 3.0 mA/cm/sup 2/ for the single grid and 5.8 mA/cm/sup 2/ for the double grids with a maximum extraction voltage of 1.7 kV. This applicator was then retrofitted with magnets to study the effect of a multicusp static magnetic field. Using this concept, a new cylindrical microwave applicator was designed and tested.

Dahimene, M.

1987-01-01T23:59:59.000Z

298

Two-dimensional resonant magnetic excitation in BaFe1.84Co0.16As2  

SciTech Connect (OSTI)

Inelastic neutron scattering measurements on single crystals of superconducting BaFe1.84Co0.16As2 clearly reveal a magnetic excitation located at wavevectors (1/2 1/2 L) in tetragonal notation. The scattering is much broader in L than are spin waves observed in the parent compound BaFe2As2 indicating that the excitations in the superconducting material are more two-dimensional in nature. The excitation appears gapless for T > TC and becomes gapped on cooling below TC. The observed gap energy is approximately 9.6 meV corresponding to 5 kBTC which is remarkably similar to the canonical value for the resonance energy in the cuprates.

Lumsden, Mark D [ORNL; Christianson, Andrew D [ORNL; Parshall, Daniel [ORNL; Stone, Matthew B [ORNL; Nagler, Stephen E [ORNL; Mook Jr, Herbert A [ORNL; Lokshin, Konstantin A [ORNL; Egami, Takeshi [ORNL; Abernathy, Douglas L [ORNL; Goremychkin, E. A. [ISIS Facility, Rutherford Appleton Laboratory; Osborn, R. [Argonne National Laboratory (ANL); McGuire, Michael A [ORNL; Safa-Sefat, Athena [ORNL; Jin, Rongying [ORNL; Sales, Brian C [ORNL; Mandrus, David [ORNL

2009-01-01T23:59:59.000Z

299

Dynamic T{sub 2}-mapping during magnetic resonance guided high intensity focused ultrasound ablation of bone marrow  

SciTech Connect (OSTI)

Focal bone tumor treatments include amputation, limb-sparing surgical excision with bone reconstruction, and high-dose external-beam radiation therapy. Magnetic resonance guided high intensity focused ultrasound (MR-HIFU) is an effective non-invasive thermotherapy for palliative management of bone metastases pain. MR thermometry (MRT) measures the proton resonance frequency shift (PRFS) of water molecules and produces accurate (<1 Degree-Sign C) and dynamic (<5s) thermal maps in soft tissues. PRFS-MRT is ineffective in fatty tissues such as yellow bone marrow and, since accurate temperature measurements are required in the bone to ensure adequate thermal dose, MR-HIFU is not indicated for primary bone tumor treatments. Magnetic relaxation times are sensitive to lipid temperature and we hypothesize that bone marrow temperature can be determined accurately by measuring changes in T{sub 2}, since T{sub 2} increases linearly in fat during heating. T{sub 2}-mapping using dual echo times during a dynamic turbo spin-echo pulse sequence enabled rapid measurement of T{sub 2}. Calibration of T{sub 2}-based thermal maps involved heating the marrow in a bovine femur and simultaneously measuring T{sub 2} and temperature with a thermocouple. A positive T{sub 2} temperature dependence in bone marrow of 20 ms/ Degree-Sign C was observed. Dynamic T{sub 2}-mapping should enable accurate temperature monitoring during MR-HIFU treatment of bone marrow and shows promise for improving the safety and reducing the invasiveness of pediatric bone tumor treatments.

Waspe, Adam C.; Looi, Thomas; Mougenot, Charles; Amaral, Joao; Temple, Michael; Sivaloganathan, Siv; Drake, James M. [Centre for Image Guided Innovation and Therapeutic Intervention, The Hospital for Sick Children, Toronto, ON, M5G 1X8 (Canada); Philips Healthcare Canada, Markham, ON, L6C 2S3 (Canada); Centre for Image Guided Innovation and Therapeutic Intervention, The Hospital for Sick Children, Toronto, ON, M5G 1X8 (Canada); Department of Applied Mathematics, University of Waterloo, Waterloo, ON, N2L 3G1 (Canada); Centre for Image Guided Innovation and Therapeutic Intervention, The Hospital for Sick Children, Toronto, ON, M5G 1X8 (Canada)

2012-11-28T23:59:59.000Z

300

Magnetic resonance investigation of Zn{sub 1?x}Fe{sub x}O properties influenced by annealing atmosphere  

SciTech Connect (OSTI)

ZnO is an attractive system for a wide variety of practical applications, being a chemically stable oxide semiconductor. It has been shown that Fe doping produces ferromagnetic semiconductor at room temperature. This material, therefore, has the potential for use in spintronic devices such as spin transistors, spin light emitting diodes, very high density nonvolatile semiconductor memory and optical emitters. It is believed that oxygen vacancies and substitutional incorporation are important to produce ferromagnetism in semiconductor oxide doped with transition metal ions. The present paper reports detailed electron paramagnetic resonance investigations (EPR) of the samples in order to investigate how annealing atmosphere (Air and Argon) influenced the magnetic behavior of the samples. X-band electron paramagnetic resonance (EPR) studies of Fe{sup 3+} ions in Zn{sub 1?x}Fe{sub x}O powders with x = 1%, 3% is reported. These samples are interesting to investigate as Fe doping produce ferromagnetism in ZnO, making a promising ferromagnetic semiconductor at room temperature.

Raita, O.; Popa, A.; Toloman, D.; Stan, M.; Giurgiu, L. M. [National Institute for Research and Development of Isotopic and Molecular Technologies Donath 65-103, 400293, Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies Donath 65-103, 400293, Cluj-Napoca (Romania)

2013-11-13T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
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301

Transport of phosphocholine in higher plant cells: sup 31 P nuclear magnetic resonance studies  

SciTech Connect (OSTI)

Phosphocholine (PC) is an abundant primary form of organic phosphate that is transported in plant xylem sap. Addition of PC to the perfusate of compressed P{sub i}-starved sycamore cells monitored by {sup 31}P NMR spectroscopy resulted in an accumulation of PC and all the other phosphate esters in the cytoplasmic compartment. Addition of hemicholinium-3, an inhibitor of choline uptake, to the perfusate inhibited PC accumulation but not inorganic phosphate (P{sub i}). When the P{sub i}-starved cells were perfused with a medium containing either P{sub i} or PC, the resulting P{sub i} distribution in the cell was the same. Addition of choline instead of PC to the perfusate of compressed cells resulted in an accumulation of PC in the cytoplasmic compartment from choline kinase activity. In addition, PC phosphatase activity has been discovered associated with the cell wall. These results indicate that PC was rapidly hydrolyzed outside the cell and that choline and P{sub i} entered the cytosolic compartment where choline kinase re-forms PC.

Gout, E.; Bligny, R.; Roby, C.; Douce, R. (Centre d'etudes Nucleaires de Grenoble et Universite Joseph Fourier (France))

1990-06-01T23:59:59.000Z

302

Automatic Landmarking of Magnetic Resonance brain Images Camille Izard*a,b, Bruno M. Jedynaka,b and Craig E.L. Starkc  

E-Print Network [OSTI]

Automatic Landmarking of Magnetic Resonance brain Images Camille Izard*a,b, Bruno M. JedynakaDepartment of Psychological and Brain Sciences, Johns Hopkins University, Baltimore, MD ABSTRACT Landmarking MR images is crucial in registering brain structures from different images. It consists in locating the voxel

Jedynak, Bruno M.

303

Solid-State Nuclear Magnetic Resonance Measurements of HIV Fusion Peptide to Lipid Distances Reveal the Intimate Contact of Strand Peptide with Membranes  

E-Print Network [OSTI]

Solid-State Nuclear Magnetic Resonance Measurements of HIV Fusion Peptide to Lipid Distances Reveal 23, 2007 ABSTRACT: Human immunodeficiency virus (HIV) infection begins with fusion between viral and host cell membranes and is catalyzed by the HIV gp41 fusion protein. The 20 N-terminal apolar residues

Weliky, David

304

Solid-State Nuclear Magnetic Resonance Evidence for Parallel and Antiparallel Strand Arrangements in the Membrane-Associated HIV-1 Fusion Peptide  

E-Print Network [OSTI]

Solid-State Nuclear Magnetic Resonance Evidence for Parallel and Antiparallel Strand Arrangements in the Membrane-Associated HIV-1 Fusion Peptide Jun Yang and David P. Weliky* Department of Chemistry, Michigan 7, 2003 ABSTRACT: The HIV-1 fusion peptide serves as a useful model system for understanding viral

Weliky, David

305

Prediction of the reversibility of the ultrasound-induced blood-brain barrier opening using passive cavitation detection with magnetic resonance imaging  

E-Print Network [OSTI]

cavitation detection with magnetic resonance imaging validation Tao Sun1 , Gesthimani Samiotaki1 and Elisa E (diameters: 1-2, 4-5, or 6-8 m). A 10-MHz passive cavitation detector was used to acquire cavitation signals that the stable cavitation dose increased with the number of days required for closing while it reached a plateau

Konofagou, Elisa E.

306

Effective Cerebral Connectivity during Silent Speech Reading Revealed by Functional Magnetic Resonance  

E-Print Network [OSTI]

Effective Cerebral Connectivity during Silent Speech Reading Revealed by Functional Magnetic Y-H, Lin F-H, Chou Y-J, Tsai KW-K, Kuo W-J, et al. (2013) Effective Cerebral Connectivity during that no competing interests exist. * E-mail: fhlin@ntu.edu.tw . These authors contributed equally to this work

307

A nuclear magnetic resonance probe of Fe-Al and Al20V2Eu intermetallics  

E-Print Network [OSTI]

Al-rich Fe-Al systems (FeAl2, Fe2 Al5 and Fe4Al13) and Al20V2Eu have complicated structures with quasicrystal-like features making these materials potentially of interest for magnetic behavior. However, there is not much work on these materials...

Chi, Ji

2009-05-15T23:59:59.000Z

308

Transmit field pattern control for high field magnetic resonance imaging with integrated RF current sources  

E-Print Network [OSTI]

in units of radians/tesla and B is the magnetic flux density of the applied field, expressed in units of tesla. The hydrogen nucleus, which consists of a single proton, is the most abundantly present in tissue and is most widely used for MRI...

Kurpad, Krishna Nagaraj

2005-11-01T23:59:59.000Z

309

Proton magnetic resonance studies of the chemical shifts occurring in propionic acid-dioxane solutions  

E-Print Network [OSTI]

, Nxperimentaliy Gutowsky 1'ound S to be a linear function of Pl, Howevers Bhar end Lindstrom(I~ found deviations from the linear de- pendence g1ven in Gutowsky's report, These deviat1ons occur in the range of 5Q of acid by volume. The shift does not decrease... lines are displayed as the f10IlL is swept through 'the resonant value Since it was desire4 to find if the cheaical shift is tesperature de pendent~ 1t vas decided to neasure the shift at two tenperatures, One of those vas to be roc' tenperatuze...

Oldham, William J. Bryan

1958-01-01T23:59:59.000Z

310

NMR and EPR | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sarah D Burton, David Hoyt View all NMR and EPR Instruments Publications Effect of Solar Radiation on the Optical Properties and Molecular Composition of Laboratory Proxies of...

311

NMR logging apparatus  

DOE Patents [OSTI]

Technologies including NMR logging apparatus and methods are disclosed. Example NMR logging apparatus may include surface instrumentation and one or more downhole probes configured to fit within an earth borehole. The surface instrumentation may comprise a power amplifier, which may be coupled to the downhole probes via one or more transmission lines, and a controller configured to cause the power amplifier to generate a NMR activating pulse or sequence of pulses. Impedance matching means may be configured to match an output impedance of the power amplifier through a transmission line to a load impedance of a downhole probe. Methods may include deploying the various elements of disclosed NMR logging apparatus and using the apparatus to perform NMR measurements.

Walsh, David O; Turner, Peter

2014-05-27T23:59:59.000Z

312

Measurement of laser heating in spin exchange optical pumping by NMR diffusion sensitization gradients  

SciTech Connect (OSTI)

This paper details pulsed gradient NMR measurements of the {sup 3}He diffusion coefficient in sealed cells during spin exchange optical pumping. The potential of ultra low field magnetic resonance imgaing (MRI) and NMR for noninvasive measurement of cell pressure is demonstrated. Diffusion sensitization gradients allow measurement of the {sup 3}He diffusion coefficient from which the pressure and/or temperature of the gas can be determined during optical pumping. The pressure measurements were compared with neutron time of flight transmission measurements. Good agreement was observed between the temperature/pressure measurements and predictions based on Chapman-Enskog theory. The technique had sufficient sensitivity to observe the diffusion coefficient increasing with temperature in a sealed cell. With this method, evidence for laser heating of the {sup 3}He during optical pumping was found. The results show that NMR diffusion measurements allow noninvasive measurement of the cell temperature and/or pressure in an optical pumping setup. The method can be expanded using MRI to probe the spatial distribution of the diffusion coefficient. These techniques can be applied to the further investigation of polarization limiting effects such as laser heating.

Parnell, Steven R.; Deppe, Martin H.; Ajraoui, Salma; Parra-Robles, Juan; Wild, Jim M. [Unit of Academic Radiology, University of Sheffield, Royal Hallamshire Hospital, Glossop Road, Sheffield, S10 2JF (United Kingdom); Boag, Stephen [ISIS, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom)

2010-05-15T23:59:59.000Z

313

Minimally Invasive Magnetic Resonance Imaging-Guided Free-Hand Aspiration of Symptomatic Nerve Route Compressing Lumbosacral Cysts Using a 1.0-Tesla Open Magnetic Resonance Imaging System  

SciTech Connect (OSTI)

Purpose: To evaluate the feasibility of minimally invasive magnetic resonance imaging (MRI)-guided free-hand aspiration of symptomatic nerve route compressing lumbosacral cysts in a 1.0-Tesla (T) open MRI system using a tailored interactive sequence. Materials and Methods: Eleven patients with MRI-evident symptomatic cysts in the lumbosacral region and possible nerve route compressing character were referred to a 1.0-T open MRI system. For MRI interventional cyst aspiration, an interactive sequence was used, allowing for near real-time position validation of the needle in any desired three-dimensional plane. Results: Seven of 11 cysts in the lumbosacral region were successfully aspirated (average 10.1 mm [SD {+-} 1.9]). After successful cyst aspiration, each patient reported speedy relief of initial symptoms. Average cyst size was 9.6 mm ({+-}2.6 mm). Four cysts (8.8 {+-} 3.8 mm) could not be aspirated. Conclusion: Open MRI systems with tailored interactive sequences have great potential for cyst aspiration in the lumbosacral region. The authors perceive major advantages of the MR-guided cyst aspiration in its minimally invasive character compared to direct and open surgical options along with consecutive less trauma, less stress, and also less side-effects for the patient.

Bucourt, Maximilian de, E-mail: mdb@charite.de; Streitparth, Florian, E-mail: florian.streitparth@charite.de; Collettini, Federico [Charite-University Medicine, Department of Radiology (Germany); Guettler, Felix [Jena University, Department of Radiology (Germany); Rathke, Hendrik; Lorenz, Britta; Rump, Jens; Hamm, Bernd [Charite-University Medicine, Department of Radiology (Germany); Teichgraeber, U. K. [Jena University, Department of Radiology (Germany)

2012-02-15T23:59:59.000Z

314

Pellet fuelling of plasmas with ELM mitigation by resonant magnetic perturbations in MAST  

E-Print Network [OSTI]

Shallow fuelling pellets are injected from the high field side into plasmas in which ELMs have been mitigated using external magnetic perturbation coils. The data are compared with ideal assumptions in the ITER fuelling model, namely that mitigated ELMs are not affected by fuelling pellets. Firstly it is shown that during the pellet evaporation an ELM is triggered, during which the amount particle loss could be larger (factor ~1.5) than the particle loss during an ELM which was not induced by pellet. Secondly, a favourable example is shown in which post-pellet particle losses due to mitigated ELMs are similar to the non-pellet case, however unfavourable counter-examples also exist.

Valovic, M; Garzotti, L; Gurl, C; Kirk, A; Naylor, G; Patel, A; Scannell, R; Thornton, A J

2013-01-01T23:59:59.000Z

315

The Structure of Hydrated Electron. Part 1. Magnetic Resonance of Internally Trapping Water Anions: A Density Functional Theory Study  

E-Print Network [OSTI]

Density functional theory (DFT) is used to rationalize magnetic parameters of hydrated electron trapped in alkaline glasses as observed using Electron Paramagnetic Resonance (EPR) and Electron Spin Echo Envelope Modulation (ESEEM) spectroscopies. To this end, model water cluster anions (n=4-8 and n=20,24) that localize the electron internally are examined. It is shown that EPR parameters of such water anions (such as hyperfine coupling tensors of H/D nuclei in the water molecules) are defined mainly by the cavity size and the coordination number of the electron; the water molecules in the second solvation shell play a relatively minor role. An idealized model of hydrated electron (that is usually attributed to L. Kevan) in which six hydroxyl groups arranged in an octahedral pattern point towards the common center is shown to provide the closest match to the experimental parameters, such as isotropic and anisotropic hyperfine coupling constants for the protons (estimated from ESEEM), the second moment of the EPR spectra, and the radius of gyration. The salient feature of these DFT models is the significant transfer (10-20%) of spin density into the frontal O 2p orbitals of water molecules. Spin bond polarization involving these oxygen orbitals accounts for small, negative hyperfine coupling constants for protons in hydroxyl groups that form the electron-trapping cavity. In Part 2, these results are generalized for more realistic geometries of core anions obtained using a dynamic one-electron mixed qunatum/classical molecular dynamics model.

I. A. Shkrob

2006-07-25T23:59:59.000Z

316

Calcium silicate hydrates investigated by solid-state high resolution {sup 1}H and {sup 29}Si nuclear magnetic resonance  

SciTech Connect (OSTI)

This work focuses on phases formed during cement hydration under high pressure and temperature: portlandite Ca(OH){sub 2} (CH); hillebrandite Ca{sub 2}(SiO{sub 3})(OH){sub 2} ({beta}-dicalcium silicate hydrate); calcium silicate hydrate (C-S-H); jaffeite Ca{sub 6}(Si{sub 2}O{sub 7})(OH){sub 6} (tricalcium silicate hydrate); {alpha}-C{sub 2}SH Ca{sub 2}(SiO{sub 3})(OH){sub 2} ({alpha}-dicalcium silicate hydrate); xonotlite Ca{sub 6}(Si{sub 6}O{sub 17})(OH){sub 2} and kilchoanite Ca{sub 6}(SiO{sub 4})(Si{sub 3}O{sub 10}). Portlandite and hillebrandite were synthesized and characterised by high resolution solid-state {sup 1}H and {sup 29}Si Nuclear Magnetic Resonance. In addition, information from the literature concerning the last five phases was gathered. In certain cases, a schematic 3D-structure could be determined. These data allow identification of the other phases present in a mixture. Their morphology was also observed by Scanning Electron Microscopy.

Meducin, Fabienne [Laboratoire de Physique et Mecanique des Milieux Heterogenes, Ecole Superieure de Physique et Chimie Industrielles, 75231 Paris Cedex 05 (France)]. E-mail: meducin@cnrs-orleans.fr; Bresson, Bruno [Laboratoire de Physique Quantique, ESPCI (France); Lequeux, Nicolas [Laboratoire de Physico-Chimie des polymeres et des milieux disperses, ESPCI (France); Noirfontaine, Marie-Noelle de [Laboratoire CECM-CNRS, 15, rue Georges Urbain, 94407 Vitry sur Seine (France); Zanni, Helene [Laboratoire de Physique et Mecanique des Milieux Heterogenes, Ecole Superieure de Physique et Chimie Industrielles, 75231 Paris Cedex 05 (France)

2007-05-15T23:59:59.000Z

317

Development of a System for Rapid Detection of Contaminants in Water Supplies Using Magnetic Resonance and Nanoparticles  

SciTech Connect (OSTI)

To keep the water supply safe and to ensure a swift and accurate response to a water supply contamination event, rapid and robust methods for microbial testing are necessary. Current technologies are complex, lengthy and costly and there is a need for rapid, reliable, and precise approaches that can readily address this fundamental security and safety issue. T2 Biosystems is focused on providing solutions to this problem by making breakthroughs in nanotechnology and biosensor techniques that address the current technical restrictions facing rapid, molecular analysis in complex samples. In order to apply the T2 Biosystems nucleic acid detection procedure to the analysis of nucleic acid targets in unprocessed water samples, Bacillus thuringeinsis was selected as a model organism and local river water was selected as the sample matrix. The initial assay reagent formulation was conceived with a manual magnetic resonance reader, was optimized using a high throughput system, and transferred back to the MR reader for potential field use. The final assay employing the designed and manufactured instruments was capable of detecting 10 CFU/mL of B. thuringiensis directly within the environmental water sample within 90 minutes. Further, discrimination of two closely related species of Bacilli was accomplished using the methods of this project; greater than 3-fold discrimination between B. cereus and B. thuringiensis at a concentrations spanning 10 CFU/mL to 10{sup 5} CFU/mL was observed.

Lowery, Thomas J; Neely, Lori; Chepin, James; Wellman, Parris; Toso, Ken; Murray, Paul; Audeh, Mark; Demas, Vasiliki; Palazzolo, Robert; Min, Michael; Phung, Nu; Blanco, Matt; Raphel, Jordan; O'Neil, Troy

2010-09-14T23:59:59.000Z

318

An NMR (nuclear magnetic resonance) investigation of the chemical association and molecular dynamics in asphalt ridge tar sand ore and bitumen  

SciTech Connect (OSTI)

Preliminary studies on tar sand bitumen given in this report have shown that the reassociation of tar sand bitumen to its original molecular configuration after thermal stressing is a first-order process requiring nearly a week to establish equilibrium. Studies were also conducted on the dissolution of tar sand bitumen in solvents of varying polarity. At a high-weight fraction of solute to solvent the apparent molecular weight of the bitumen molecules was greater than that of the original bitumen when dissolved in chloroform-d/sub 1/ and benzene-d/sub 6/. This increase in the apparent molecular weight may be due to micellar formation or a weak solute-solvent molecular complex. Upon further dilution with any of the solvents studied, the apparent molecular weight of the tar sand bitumen decreased because of reduced van der Waals forces of interaction and/or hydrogen bonding. To define the exact nature of the interactions, it will be necessary to have viscosity measurements of the solutions. 30 refs., 3 figs., 3 tabs.

Netzel, D.A.; Coover, P.T.

1987-09-01T23:59:59.000Z

319

Real-time high-resolution X-ray imaging and nuclear magnetic resonance study of the hydration of pure and Na-doped C3A in the presence of sulfates  

SciTech Connect (OSTI)

This study details the differences in real-time hydration between pure tricalcium aluminate (cubic C{sub 3}A or 3CaO {center_dot} Al{sub 2}O{sub 3}) and Na-doped tricalcium aluminate (orthorhombic C{sub 3}A or Na{sub 2}Ca{sub 8}Al{sub 6}O{sub 18}), in aqueous solutions containing sulfate ions. Pure phases were synthesized in the laboratory to develop an independent benchmark for the reactions, meaning that their reactions during hydration in a simulated early age cement pore solution (saturated with respect to gypsum and lime) were able to be isolated. Because the rate of this reaction is extremely rapid, most microscopy methods are not adequate to study the early phases of the reactions in the early stages. Here, a high-resolution full-field soft X-ray imaging technique operating in the X-ray water window, combined with solution analysis by {sup 27}Al nuclear magnetic resonance (NMR) spectroscopy, was used to capture information regarding the mechanism of C{sub 3}A hydration during the early stages. There are differences in the hydration mechanism between the two types of C{sub 3}A, which are also dependent on the concentration of sulfate ions in the solution. The reactions with cubic C{sub 3}A (pure) seem to be more influenced by higher concentrations of sulfate ions, forming smaller ettringite needles at a slower pace than the orthorhombic C{sub 3}A (Na-doped) sample. The rate of release of aluminate species into the solution phase is also accelerated by Na doping.

Kirchheim,, A. P.; Dal Molin, D.C.; Emwas, Abdul-Hamid; Provis, J.L.; Fischer, P.; Monteiro, P.J.M.

2010-12-01T23:59:59.000Z

320

A unified view of coherent and incoherent dihydrogen exchange in transition metal hydrides by nuclear resonance and inelastic neutron scattering  

SciTech Connect (OSTI)

In this paper a unified view of coherent and incoherent dihydrogen exchange in transition metal hydrides by nuclear magnetic resonance (NMR) and inelastic neutron scattering (INS) is presented. It is shown that both exchange processes coexist i.e. do not transform into each other although they may dominate the spectra in different temperature ranges. This superposition is the consequence of the incorporation of the tunnel frequency J of the coherent process into the nuclear two-spin hamiltonian of hydrogen pairs which allows to treat the problem using the well known density matrix theory of NMR line-shapes developed by Alexander and Binsch. It is shown that this theory can also be used to predict the line-shapes of the rotational tunneling transitions observed in the INS spectra of transition metal dihydrogen complexes and that both NMR and INS spectra depend on similar parameters.

Limbach, H.H.; Ulrich, S.; Buntkowsky, G. [Freie Univ. Berlin (Germany). Inst. fuer Organische Chemie; Sabo-Etienne, S.; Chaudret, B. [Toulouse-3 Univ., 31 (France). Lab. de Chimie de Coordination du C.N.R.S.; Kubas, G.J.; Eckert, J. [Los Alamos National Lab., NM (United States)

1995-08-12T23:59:59.000Z

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321

NMR-assignments of a cytosolic domain of the C-terminus of polycystin-2  

E-Print Network [OSTI]

ARTICLE NMR-assignments of a cytosolic domain of the C-terminus of polycystin-2 Frank H. Schumann ?. The backbone and side chain resonances were assigned by multidimensional NMR methods, the obtained chemical contained 1 g NH4Cl, 6 g glucose, F. H. Schumann Á M. Schmidt Á R. Bader Á H. R. Kalbitzer (&) Institute

Witzgall, Ralph - Naturwissenschaftliche Fakultät III

322

A Signal-Inducing Bone Cement for Magnetic Resonance Imaging-Guided Spinal Surgery Based on Hydroxyapatite and Polymethylmethacrylate  

SciTech Connect (OSTI)

The aim of this study was to develop a signal-inducing bone cement for magnetic resonance imaging (MRI)-guided cementoplasty of the spine. This MRI cement would allow precise and controlled injection of cement into pathologic lesions of the bone. We mixed conventional polymethylmethacrylate bone cement (PMMA; 5 ml methylmethacrylate and 12 g polymethylmethacrylate) with hydroxyapatite (HA) bone substitute (2-4 ml) and a gadolinium-based contrast agent (CA; 0-60 {mu}l). The contrast-to-noise ratio (CNR) of different CA doses was measured in an open 1.0-Tesla scanner for fast T1W Turbo-Spin-Echo (TSE) and T1W TSE pulse sequences to determine the highest signal. We simulated MRI-guided cementoplasty in cadaveric spines. Compressive strength of the cements was tested. The highest CNR was (1) 87.3 (SD 2.9) in fast T1W TSE for cements with 4 {mu}l CA/ml HA (4 ml) and (2) 60.8 (SD 2.4) in T1W TSE for cements with 1 {mu}l CA/ml HA (4 ml). MRI-guided cementoplasty in cadaveric spine was feasible. Compressive strength decreased with increasing amounts of HA from 46.7 MPa (2 ml HA) to 28.0 MPa (4 ml HA). An MRI-compatible cement based on PMMA, HA, and CA is feasible and clearly visible on MRI images. MRI-guided spinal cementoplasty using this cement would permit direct visualization of the cement, the pathologic process, and the anatomical surroundings.

Wichlas, Florian, E-mail: florian.wichlas@charite.de; Seebauer, Christian J.; Schilling, Rene [University Charite, Center for Musculoskeletal Surgery (Germany); Rump, Jens [University Charite, Department of Radiology (Germany); Chopra, Sascha S. [University Charite, Center for Musculoskeletal Surgery (Germany); Walter, Thula; Teichgraeber, Ulf K. M. [University Charite, Department of Radiology (Germany); Bail, Hermann J. [University Charite, Center for Musculoskeletal Surgery (Germany)

2012-06-15T23:59:59.000Z

323

Magnetic Resonance Lymphography Findings in Patients With Biochemical Recurrence After Prostatectomy and the Relation With the Stephenson Nomogram  

SciTech Connect (OSTI)

Purpose: To estimate the occurrence of positive lymph nodes on magnetic resonance lymphography (MRL) in patients with a prostate-specific antigen (PSA) recurrence after prostatectomy and to investigate the relation between score on the Stephenson nomogram and lymph node involvement on MRL. Methods and Materials: Sixty-five candidates for salvage radiation therapy were referred for an MRL to determine their lymph node status. Clinical and histopathologic features were recorded. For 49 patients, data were complete to calculate the Stephenson nomogram score. Receiver operating characteristic (ROC) analysis was performed to determine how well this nomogram related to the MRL result. Analysis was done for the whole group and separately for patients with a PSA <1.0 ng/mL to determine the situation in candidates for early salvage radiation therapy, and for patients without pathologic lymph nodes at initial lymph node dissection. Results: MRL detected positive lymph nodes in 47 patients. ROC analysis for the Stephenson nomogram yielded an area under the curve (AUC) of 0.78 (95% confidence interval, 0.61-0.93). Of 29 patients with a PSA <1.0 ng/mL, 18 had a positive MRL. Of 37 patients without lymph node involvement at initial lymph node dissection, 25 had a positive MRL. ROC analysis for the Stephenson nomogram showed AUCs of 0.84 and 0.74, respectively, for these latter groups. Conclusion: MRL detected positive lymph nodes in 72% of candidates for salvage radiation therapy, in 62% of candidates for early salvage radiation therapy, and in 68% of initially node-negative patients. The Stephenson nomogram showed a good correlation with the MRL result and may thus be useful for identifying patients with a PSA recurrence who are at high risk for lymph node involvement.

Meijer, Hanneke J.M., E-mail: H.Meijer@rther.umcn.nl [Department of Radiation Oncology, Radboud University Nijmegen Medical Centre, Nijmegen (Netherlands); Debats, Oscar A. [Department of Radiology, Radboud University Nijmegen Medical Centre, Nijmegen (Netherlands)] [Department of Radiology, Radboud University Nijmegen Medical Centre, Nijmegen (Netherlands); Roach, Mack [Department of Radiation Oncology and Urology, University of California San Francisco, San Francisco, California (United States)] [Department of Radiation Oncology and Urology, University of California San Francisco, San Francisco, California (United States); Span, Paul N. [Department of Radiation Oncology, Radboud University Nijmegen Medical Centre, Nijmegen (Netherlands)] [Department of Radiation Oncology, Radboud University Nijmegen Medical Centre, Nijmegen (Netherlands); Witjes, J. Alfred [Department of Urology, Radboud University Nijmegen Medical Centre, Nijmegen (Netherlands)] [Department of Urology, Radboud University Nijmegen Medical Centre, Nijmegen (Netherlands); Kaanders, Johannes H.A.M.; Lin, Emile N.J.Th. van [Department of Radiation Oncology, Radboud University Nijmegen Medical Centre, Nijmegen (Netherlands); Barentsz, Jelle O. [Department of Radiology, Radboud University Nijmegen Medical Centre, Nijmegen (Netherlands)] [Department of Radiology, Radboud University Nijmegen Medical Centre, Nijmegen (Netherlands)

2012-12-01T23:59:59.000Z

324

X-ray resonant magnetic scattering investigations of hexagonal multiferroics RMnO3 (R = Dy, Ho, Er)  

SciTech Connect (OSTI)

Electricity and magnetism were unified into a common subject by James Clerk Maxwell in the nineteenth century yielding the electromagnetic theory. Four equations govern the dynamics of electric charges and magnetic fields, commonly known as Maxwell's equations. Maxwell's equations demonstrate that an accelerated charged particle can produce magnetic fields and a time varying magnetic field can induce a voltage - thereby linking the two phenomena. However, in solids, electric and magnetic ordering are most often considered separately and usually with good reason: the electric charges of electrons and ions are responsible for the charge effects, whereas the electron spin governs magnetic properties.

Nandi, Shibabrata

2009-12-19T23:59:59.000Z

325

A method for the rapid, accurate prediction of the physical properties of middle distillate fuels from LC- sup 1 H NMR derived data  

SciTech Connect (OSTI)

A method has been developed whereby various physical properties of middle distillate fuels may be rapidly and accurately calculated by a group property approach from data obtained from a directly coupled Liquid Chromatograph - {sup 1}H Nuclear Magnetic Resonance Spectrometer (LC-{sup 1}H NMR). The physical properties include cetane number, cetane index, density, specific gravity, pour point, flash point, viscosity, filterability, heat of combustion, cloud point, volume percent aromatics, residual carbon content, and initial, 10%, 50%, 90%, and end boiling points. These property predictions have accuracies approaching the error for measurement of the experimental physical property and require less than two hours analysis time per fuel. An interface was developed between the NMR spectrometer and a personal computer to aid in automation of the LC-{sup 1}H NMR data collection and to perform off-line analysis of the LC-{sup 1}H NMR data. This interface and all associated software is described. Also presented is a series of model compounds studies in which the physical properties of pure hydrocarbons (i.e., alkanes, monocyclic and dicyclic aromatics) were predicted by a similar group property approach.

Caswell, K.A.

1988-01-01T23:59:59.000Z

326

A correlation of United States tar sand bitumen viscosities with NMR spectroscopic parameters  

SciTech Connect (OSTI)

A method has been developed whereby the viscosity of a tar sand bitumen at any temperature can be calculated from nuclear magnetic resonance parameters. The method is semiempirical but is based upon some fundamental theoretical concepts for molecular mobility and intermolecular interactions. Using this method, the viscosities of three United States tar sand bitumens have been correlated to the weighted average spin-spin relaxation rates for the semiliquid, solidlike mobile, and solidlike rigid phases of the bitumens. The results indicate that bitumens with a high viscosity have a greater amount of solidlike rigid phase and lesser amounts of solidlike mobile and semiliquid phases than do the bitumens with low viscosity. It is also shown that the viscosity of a tar sand bitumen over a 100 degree temperature range can be determined from a single NMR experiment conducted near room temperature. 18 refs., 3 figs., 4 tabs.

Netzel, D.A.; Turner, T.F.

1989-06-01T23:59:59.000Z

327

A correlation of United States tar sand bitumen viscosities with NMR spectroscopic parameters  

SciTech Connect (OSTI)

A method has been developed whereby the viscosity of a tar sand bitumen at any temperature can be calculated from nuclear magnetic resonance parameters. The method is semi empirical but is based upon some fundamental theoretical concepts for molecular mobility and intermolecular interactions. Using this method, the viscosities of three United States tar sand bitumens have been correlated to the weighted average spin-spin, relaxation rates for the semiliquid, solidlike mobile, and solidlike rigid phases of the bitumens. The results indicate that bitumens with a high viscosity have a greater amount of solidlike rigid phase and lesser amounts of solidlike mobile and semiliquid phases than do the bitumens with low viscosity. It is also shown that the viscosity of a tar sand bitumen over a 100 degree temperature range can be determined from a single NMR experiment conducted near room temperature.

Netzel, D.A.; Turner, T.F. (Western Research Institute, Box 3395, Laramie, WY (US))

1990-01-01T23:59:59.000Z

328

A firmware-defined digital direct-sampling NMR spectrometer for condensed matter physics  

SciTech Connect (OSTI)

We report on the design and implementation of a new digital, broad-band nuclear magnetic resonance (NMR) spectrometer suitable for probing condensed matter. The spectrometer uses direct sampling in both transmission and reception. It relies on a single, commercially-available signal processing device with a user-accessible field-programmable gate array (FPGA). Its functions are defined exclusively by the FPGA firmware and the application software. Besides allowing for fast replication, flexibility, and extensibility, our software-based solution preserves the option to reuse the components for other projects. The device operates up to 400?MHz without, and up to 800?MHz with undersampling, respectively. Digital down-conversion with 10?MHz passband is provided on the receiver side. The system supports high repetition rates and has virtually no intrinsic dead time. We describe briefly how the spectrometer integrates into the experimental setup and present test data which demonstrates that its performance is competitive with that of conventional designs.

Pikulski, M., E-mail: marekp@ethz.ch; Shiroka, T.; Ott, H.-R.; Mesot, J. [Laboratorium fr Festkrperphysik, ETH Hnggerberg, CH-8093 Zrich, Switzerland and Paul Scherrer Institut, CH-5232 Villigen PSI (Switzerland)

2014-09-15T23:59:59.000Z

329

740 IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY, VOL. 12, NO. 1, MARCH 2002 High-Resolution Nuclear Magnetic Resonance  

E-Print Network [OSTI]

740 IEEE TRANSACTIONS ON APPLIED SUPERCONDUCTIVITY, VOL. 12, NO. 1, MARCH 2002 High research depend on high- field superconducting magnets with outstanding homogeneity and excellent long term, superconducting magnets, TROSY. I. INTRODUCTION IN THE half century since its discovery, nuclear magnetic

Wider, Gerhard

330

Perturbation of nuclear spin polarizations in solid state NMR of nitroxide-doped samples by magic-angle spinning without microwaves  

SciTech Connect (OSTI)

We report solid state {sup 13}C and {sup 1}H nuclear magnetic resonance (NMR) experiments with magic-angle spinning (MAS) on frozen solutions containing nitroxide-based paramagnetic dopants that indicate significant perturbations of nuclear spin polarizations without microwave irradiation. At temperatures near 25 K, {sup 1}H and cross-polarized {sup 13}C NMR signals from {sup 15}N,{sup 13}C-labeled L-alanine in trinitroxide-doped glycerol/water are reduced by factors as large as six compared to signals from samples without nitroxide doping. Without MAS or at temperatures near 100 K, differences between signals with and without nitroxide doping are much smaller. We attribute most of the reduction of NMR signals under MAS near 25 K to nuclear spin depolarization through the cross-effect dynamic nuclear polarization mechanism, in which three-spin flips drive nuclear polarizations toward equilibrium with spin polarization differences between electron pairs. When T{sub 1e} is sufficiently long relative to the MAS rotation period, the distribution of electron spin polarization across the nitroxide electron paramagnetic resonance lineshape can be very different from the corresponding distribution in a static sample at thermal equilibrium, leading to the observed effects. We describe three-spin and 3000-spin calculations that qualitatively reproduce the experimental observations.

Thurber, Kent R., E-mail: thurberk@niddk.nih.gov; Tycko, Robert [Laboratory of Chemical Physics, National Institute of Diabetes and Digestive and Kidney Diseases, National Institutes of Health, Bethesda, Maryland 20892-0520 (United States)] [Laboratory of Chemical Physics, National Institute of Diabetes and Digestive and Kidney Diseases, National Institutes of Health, Bethesda, Maryland 20892-0520 (United States)

2014-05-14T23:59:59.000Z

331

A Prospective Study of the Utility of Magnetic Resonance Imaging in Determining Candidacy for Partial Breast Irradiation  

SciTech Connect (OSTI)

Purpose: Retrospective data have demonstrated that breast magnetic resonance imaging (MRI) may change a patient's eligibility for partial breast irradiation (PBI) by identifying multicentric, multifocal, or contralateral disease. The objective of the current study was to prospectively determine the frequency with which MRI identifies occult disease and to establish clinical factors associated with a higher likelihood of MRI prompting changes in PBI eligibility. Methods and Materials: At The University of Chicago, women with breast cancer uniformly undergo MRI in addition to mammography and ultrasonography. From June 2009 through May 2011, all patients were screened prospectively in a multidisciplinary conference for PBI eligibility based on standard imaging, and the impact of MRI on PBI eligibility according to National Surgical Adjuvant Breast and Bowel Project protocol B-39/Radiation Therapy Oncology Group protocol 0413 entry criteria was recorded. Univariable analysis was performed using clinical characteristics in both the prospective cohort and in a separate cohort of retrospectively identified patients. Pooled analysis was used to derive a scoring index predictive of the risk that MRI would identify additional disease. Results: A total of 521 patients were screened for PBI eligibility, and 124 (23.8%) patients were deemed eligible for PBI based on standard imaging. MRI findings changed PBI eligibility in 12.9% of patients. In the pooled univariable analysis, tumor size ?2 cm on mammography or ultrasonography (P=.02), age <50 years (P=.01), invasive lobular histology (P=.01), and HER-2/neu amplification (P=.01) were associated with a higher likelihood of MRI changing PBI eligibility. A predictive score was generated by summing the number of significant risk factors. Patients with a score of 0, 1, 2, and 3 had changes to eligibility based on MRI findings in 2.8%, 13.2%, 38.1%, and 100%, respectively (P<.0001). Conclusions: MRI identified additional disease in a significant number of patients eligible for PBI, based on standard imaging. Clinical characteristics may be useful in directing implementation of MRI in the staging of PBI candidates.

Dorn, Paige L.; Al-Hallaq, Hania A.; Haq, Farah; Goldberg, Mira [Department of Radiation and Cellular Oncology, University of Chicago Medical Center, Chicago, Illinois (United States)] [Department of Radiation and Cellular Oncology, University of Chicago Medical Center, Chicago, Illinois (United States); Abe, Hiroyuki [Department of Radiology, University of Chicago Medical Center, Chicago, Illinois (United States)] [Department of Radiology, University of Chicago Medical Center, Chicago, Illinois (United States); Hasan, Yasmin [Department of Radiation and Cellular Oncology, University of Chicago Medical Center, Chicago, Illinois (United States)] [Department of Radiation and Cellular Oncology, University of Chicago Medical Center, Chicago, Illinois (United States); Chmura, Steven J., E-mail: schmura@radonc.uchicago.edu [Department of Radiation and Cellular Oncology, University of Chicago Medical Center, Chicago, Illinois (United States)

2013-03-01T23:59:59.000Z

332

Whole-Body Magnetic Resonance Angiography at 3 Tesla Using a Hybrid Protocol in Patients with Peripheral Arterial Disease  

SciTech Connect (OSTI)

The purpose of this study was to determine the diagnostic performance of 3T whole-body magnetic resonance angiography (WB-MRA) using a hybrid protocol in comparison with a standard protocol in patients with peripheral arterial disease (PAD). In 26 consecutive patients with PAD two different protocols were used for WB-MRA: a standard sequential protocol (n = 13) and a hybrid protocol (n = 13). WB-MRA was performed using a gradient echo sequence, body coil for signal reception, and gadoterate meglumine as contrast agent (0.3 mmol/kg body weight). Two blinded observers evaluated all WB-MRA examinations with regard to presence of stenoses, as well as diagnostic quality and degree of venous contamination in each of the four stations used in WB-MRA. Digital subtraction angiography served as the method of reference. Sensitivity for detecting significant arterial disease (luminal narrowing {>=} 50%) using standard-protocol WB-MRA for the two observers was 0.63 (95%CI: 0.51-0.73) and 0.66 (0.58-0.78). Specificities were 0.94 (0.91-0.97) and 0.96 (0.92-0.98), respectively. In the hybrid protocol WB-MRA sensitivities were 0.75 (0.64-0.84) and 0.70 (0.58-0.8), respectively. Specificities were 0.93 (0.88-0.96) and 0.95 (0.91-0.97). Interobserver agreement was good using both the standard and the hybrid protocol, with {kappa} = 0.62 (0.44-0.67) and {kappa} = 0.70 (0.59-0.79), respectively. WB-MRA quality scores were significantly higher in the lower leg using the hybrid protocol compared to standard protocol (p = 0.003 and p = 0.03, observers 1 and 2). Distal venous contamination scores were significantly lower with the hybrid protocol (p = 0.02 and p = 0.01, observers 1 and 2). In conclusion, hybrid-protocol WB-MRA shows a better diagnostic performance than standard protocol WB-MRA at 3 T in patients with PAD.

Nielsen, Yousef W., E-mail: yujwni01@heh.regionh.d [University Hospital at Herlev, Department of Radiology (Denmark); Eiberg, Jonas P., E-mail: Eiberg@dadlnet.d [Rigshospitalet, Department of Vascular Surgery (Denmark); Logager, Vibeke B., E-mail: viloe@heh.regionh.d [University Hospital at Herlev, Department of Radiology (Denmark); Schroeder, Torben V., E-mail: tvs@dadlnet.d [Rigshospitalet, Department of Vascular Surgery (Denmark); Just, Sven, E-mail: svju@geh.regionh.d [University Hospital at Gentofte, Department of Radiology (Denmark); Thomsen, Henrik S., E-mail: hentho01@heh.regionh.d [University Hospital at Herlev, Department of Radiology (Denmark)

2009-09-15T23:59:59.000Z

333

Organic Light-Emitting Diodes (OLEDs) and Optically-Detected Magnetic Resonance (ODMR) studies on organic materials  

SciTech Connect (OSTI)

Organic semiconductors have evolved rapidly over the last decades and currently are considered as the next-generation technology for many applications, such as organic light-emitting diodes (OLEDs) in flat-panel displays (FPDs) and solid state lighting (SSL), and organic solar cells (OSCs) in clean renewable energy. This dissertation focuses mainly on OLEDs. Although the commercialization of the OLED technology in FPDs is growing and appears to be just around the corner for SSL, there are still several key issues that need to be addressed: (1) the cost of OLEDs is very high, largely due to the costly current manufacturing process; (2) the efficiency of OLEDs needs to be improved. This is vital to the success of OLEDs in the FPD and SSL industries; (3) the lifetime of OLEDs, especially blue OLEDs, is the biggest technical challenge. All these issues raise the demand for new organic materials, new device structures, and continued lower-cost fabrication methods. In an attempt to address these issues, we used solution-processing methods to fabricate highly efficient small molecule OLEDs (SMOLEDs); this approach is costeffective in comparison to the more common thermal vacuum evaporation. We also successfully made efficient indium tin oxide (ITO)-free SMOLEDs to further improve the efficiency of the OLEDs. We employed the spin-dependent optically-detected magnetic resonance (ODMR) technique to study the luminescence quenching processes in OLEDs and organic materials in order to understand the intrinsic degradation mechanisms. We also fabricated polymer LEDs (PLEDs) based on a new electron-accepting blue-emitting polymer and studied the effect of molecular weight on the efficiency of PLEDs. All these studies helped us to better understand the underlying relationship between the organic semiconductor materials and the OLEDs performance, and will subsequently assist in further enhancing the efficiency of OLEDs. With strongly improved device performance (in addition to other OLEDs' attributes such as mechanical flexibility and potential low cost), the OLED technology is promising to successfully compete with current technologies, such as LCDs and inorganic LEDs.

Cai, Min

2011-11-30T23:59:59.000Z

334

NMR STUDIES OF LIQUID CRYSTALS AND MOLECULES DISSOLVED IN LIQUID CRYSTAL SOLVENTS  

SciTech Connect (OSTI)

This thesis describes several studies in which nuclear magnetic resonance (nmr) spectroscopy has been used to probe the structure, orientation and dynamics of liquid crystal mesogens and molecules dissolved in liquid crystalline phases. In addition, a modern high field nmr spectrometer is described which has been used to perform such nmr studies. Chapter 1 introduces the quantum mechanical formalisms used throughout this thesis and briefly reviews the fundamentals of nuclear spin physics and pulsed nmr spectroscopy. First the density operator is described and a specific form for the canonical ensemble is derived. Then Clebsch-Gordon coefficients, Wigner rotation matrices, and irreducible tensor operators are reviewed. An expression for the equilibrium (Curie) magnetization is obtained and the linear response of a spin system to a strong pulsed r.f. irradiation is described. Finally, the spin interaction Hamiltonians relevant to this work are reviewed together with their truncated forms. Chapter 2 is a deuterium magnetic resonance study of two 'nom' liquid crystals which possess several low temperature mesomorphic phases. Specifically, deuterium quadrupolar echo spectroscopy is used to determine the orientation of the liquid crystal molecules in smectic phases, the changes in molecular orientation and motion that occur at smectic-smectic phase transitions, and the order of the phase transitions. For both compounds, the phase sequence is determined to be isotropic, nematic, smectic A, smectic C, smectic B{sub A}, smectic B{sub C}, and crystalline. The structure of the smectic A phase is found to be consistent with the well-known model of a two dimensional liquid in which molecules are rapidly rotating about their long axes and oriented at right angles to the plane of the layers. Molecules in the smectic C phase are found to have their long axes tilted with respect to the layer normal, and the tilt angle is temperature dependent, increasing from zero at the smectic A - smectic C transition and reaching a maximum at 9{sup o} at the smectic C - smectic B{sub A} transition. This finding contradicts the results of X-ray diffraction studies which indicate that the tilt angle is 18{sup o} and temperature independent. The smectic B{sub A} - smectic B{sub C} phase transition is observed for the first time, and is found to be first order, a result that contradicts the prediction of a mean theory by McMillian. Chapter 3 is a multiple quantum nmr study of n-hexane oriented in a nematic liquid crystal solvent. The basic three pulse multiple quantum experiment is discussed which enables the observation of transitions for which |{Delta}m|>1, and then the technique of the separation of multiple quantum orders by phase incrementation in the multiple quantum evolution period is reviewed (TPPI). An explicit example of multiple quantum nmr is given by the calculation of the multiple quantum spectrum of an oriented methyl group.

Drobny, G.P.

1982-11-01T23:59:59.000Z

335

Design of a compact, permanent magnet electron cyclotron resonance ion source for proton and H{sub 2}{sup +} beam production  

SciTech Connect (OSTI)

A 2.45 GHz microwave ion source was developed at China Institute of Atomic Energy (CIAE) for proton beam production of over 60 mA [B.-Q. Cui, Y.-W. Bao, L.-Q. Li, W.-S. Jiang, and R.-W. Wang, Proceedings of the High Current Electron Cyclotron Resonance (ECR) Ion Source for Proton Accelerator, APAC-2001, 2001 (unpublished)]. For various proton beam applications, another 2.45 GHz microwave ion source with a compact structure is designed and will be built at CIAE as well for high current proton beam production. It is also considered to be used for the test of H{sub 2}{sup +} beam, which could be injected into the central region model cyclotron at CIAE, and accelerated to 5 MeV before extraction by stripping. The required ECR magnetic field is supplied by all the permanent magnets rather than electrical solenoids and six poles. The magnetic field distribution provided by this permanent magnets configuration is a large and uniformly volume of ECR zone, with central magnetic field of a magnitude of {approx}875 Gs[T. Taylor and J. S. C. Wills, Nucl. Instrum. Methods Phys. Res. A 309, 37 (1991)]. The field adjustment at the extraction end can be implemented by moving the position of the magnet blocks. The results of plasma, coupling with 2.45 GHz microwave in the ECR zone inside the ion source are simulated by particle-in-cell code to optimize the density by adjusting the magnetic field distribution. The design configuration of the ion source will be summarized in the paper.

Jia Xianlu; Zhang Tianjue; Wang Chuan; Zheng Xia; Yin Zhiguo; Zhong Junqing; Wu Longcheng; Qin Jiuchang [China Institute of Atomic Energy, P.O. Box 275(3), Beijing 102413 (China); Luo Shan [The 6th Department, Communication Command Academy, Wuhan 430010 (China)

2010-02-15T23:59:59.000Z

336

Synthesis and characterization of low-OH?fluor-chlorapatite: A single-crystal XRD and NMR spectroscopic study  

SciTech Connect (OSTI)

Los-OH apatite of the compositional range Ca{sub 4.99-5.06}(PO{sub 4}){sub 2.98-3.00}F{sub 0.51-0.48}Cl{sub 0.38-0.36}OH{sub 0.14-0.12} was synthesized and characterized structurally by synchrotron-based single-crystal X-ray diffraction (XRD), and multiple nuclear magnetic resonance (NMR) spectroscopic techniques. the average structure is hexagonal with space group P6{sub 3}/m. The presence of scattering in the single-crystal diffraction data set, which is incommensurate within the average hexagonal structure, suggests the presence of localized short-range monoclinic domains. Complex lineshapes in the {sup 31}P and {sup 19}F MAS NMR spectra are also consistent with the presence of an incommensurate phase. No evidence was detected for splitting of the Ca2 site into two distinct sites (as had been previously reported for hexagonal ternary apatities). Structure refinement and {sup 19}F{l_brace}{sup 35}Cl{r_brace} TRAPDOR NMR experiments verified intercolumnal neighboring of F and Cl atoms (inter-column distance of 2.62 {angstrom}) within this low-OH{sup -} apatite suggesting that long-range neighboring of F and Cl within the apatite anion channels is feasible.

McCubbin, Francis M.; Mason, Harris E.; Park, Hyunsoo; Phillips, Brian L.; Parise, John B.; Nekvasil, Hanna; Lindsley, Donald H. (SBU)

2008-12-12T23:59:59.000Z

337

Parity violation in nuclear magnetic resonance frequencies of chiral tetrahedral tungsten complexes NWXYZ (X, Y, Z = H, F, Cl, Br or I)  

SciTech Connect (OSTI)

Density functional theory within the two-component quasi-relativistic zeroth-order regular approximation (ZORA) is used to predict parity violation shifts in {sup 183}W nuclear magnetic resonance shielding tensors of chiral, tetrahedrally bonded tungsten complexes of the form NWXYZ (X, Y, Z = H, F, Cl, Br or I), as well as for the heavier systems NWHAtF and NWH(117)F for comparison. The calculations reveal that sub-mHz accuracy is required to detect such tiny effects in this class of compounds, and that parity violation effects are very sensitive to the choice of ligands.

Nahrwold, Sophie, E-mail: nahrwold@fias.uni-frankfurt.de; Berger, Robert, E-mail: r.berger@fias.uni-frankfurt.de [Frankfurt Institute for Advanced Studies, Goethe-University Frankfurt am Main, Ruth-Moufang-Str. 1, D-60438 Frankfurt am Main (Germany) [Frankfurt Institute for Advanced Studies, Goethe-University Frankfurt am Main, Ruth-Moufang-Str. 1, D-60438 Frankfurt am Main (Germany); Clemens-Schpf-Institute, Technical University Darmstadt, Petersenstr. 22, D-64287 Darmstadt (Germany); Schwerdtfeger, Peter, E-mail: p.a.schwerdtfeger@massey.ac.nz [Centre for Theoretical Chemistry and Physics, The New Zealand Institute for Advanced Study, Massey University Albany, Private Bag 102904, North Shore City, Auckland 0745 (New Zealand) [Centre for Theoretical Chemistry and Physics, The New Zealand Institute for Advanced Study, Massey University Albany, Private Bag 102904, North Shore City, Auckland 0745 (New Zealand); Fachbereich Chemie, Philipps-Universitt Marburg, Hans-Meerwein-Str., D-35032 Marburg (Germany)

2014-01-14T23:59:59.000Z

338

Toroid cavities as NMR detectors in high pressure probes  

SciTech Connect (OSTI)

A cylindrical toroid cavity has been developed for application as an NMR detector for high sensitivity and high resolution spectroscopy in metal vessel probes. Those probes are used for in situ investigations at high temperature and pressure. Since the transmitted r.f. field is completely confined within the torus, the cavity can be placed inside the pressurized system without magnetic coupling to the metal vessel. Resonance frequencies up to 400 MHz make the toroid cavity detector especially suited for use in {sup 1}H and {sup 19}F spectroscopy. Typically achieved static {sup 1}H linewidths, measured on CHCl{sub 3} using cavities in Be-Cu pressure vessels, are 2.0 Hz. On the basis of theoretical considerations that include the radial dependence of the r.f. field within cylindrical or circular toroid detectors, equations were evolved to predict the signal intensity as a function of the pulse width. The equations precisely describe the deviations from the sinusoidal approximation, which is generally used for signal intensities derived from Helmholtz or solenoid coils.

Woelk, K.; Rathke, J.W.; Klingler, R.J.

1993-03-01T23:59:59.000Z

339

Benford distributions in NMR  

E-Print Network [OSTI]

Benford's Law is an empirical law which predicts the frequency of significant digits in databases corresponding to various phenomena, natural or artificial. Although counter intuitive at the first sight, it predicts a higher occurrence of digit 1, and decreasing occurrences to other larger digits. Here we report the Benford analysis of various NMR databases and draw several interesting inferences. We observe that, in general, NMR signals follow Benford distribution in time-domain as well as in frequency domain. Our survey included NMR signals of various nuclear species in a wide variety of molecules in different phases, namely liquid, liquid-crystalline, and solid. We also studied the dependence of Benford distribution on NMR parameters such as signal to noise ratio, number of scans, pulse angles, and apodization. In this process we also find that, under certain circumstances, the Benford analysis can distinguish a genuine spectrum from a visually identical simulated spectrum. Further we find that chemical-shift databases and amplitudes of certain radio frequency pulses generated using optimal control techniques also satisfy Benford's law to a good extent.

Gaurav Bhole; Abhishek Shukla; T. S. Mahesh

2014-06-27T23:59:59.000Z

340

NMR imaging of materials  

SciTech Connect (OSTI)

Interest in the area of NMR imaging has been driven by the widespread success of medical imaging. John M. Listerud of the Pendergrass Diagnostic Research Laboratories, Steven W. Sinton of Lockheed, and Gary P. Drobny of the University of Washington describe the principal image reconstruction methods, factors limiting spatial resolution, and applications of imaging to the study of materials.

Listerud, J.M.; Sinton, S.W.; Drobny, G.P.

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
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341

Determination of structural characteristics of saturates from diesel and kerosene fuels by carbon-13 nuclear magnetic resonance spectrometry  

SciTech Connect (OSTI)

Two saturated hydrocarbon fractions, one mainly consisting of n-alkanes and the other containing only branched plus cyclic saturates, have been separated from each of a variety of diesel fuels (approximate boiling range 230-320/sup 0/C) and kerosene fuels (approximately 190-230/sup 0/C) using silica chromatography and urea clathration. The n-alkane fractions have been simply characterized by using conventional /sup 13/C NMR spectrometry, yielding average carbon chain lengths. The branched plus cyclic saturates fractions have been characterized by using the gated spin echo (GASPE) /sup 13/C NMR subspectra for each CH/sub n/ group type (n = 0 to 3) and allows the fractional abundances of CH/sub n/ groups to be measured. These data have been employed in devising and calculating a number of novel average structure parameters which report on the extent of branching and occurrence of ring structures in the fractions investigated. Spectral data are also used to identify some specific submolecular structures. 29 references, 7 figures, 4 tables.

Cookson, D.J.; Smith, B.E.

1985-04-01T23:59:59.000Z

342

High-Resolution NMR of Quadrupolar Nuclei in the Solid State  

SciTech Connect (OSTI)

This dissertation describes recent developments in solid state nuclear magnetic resonance (NMR), for the most part involving the use of dynamic-angle spinning (DAS) NMR to study quadrupolar nuclei. Chapter 1 introduces some of the basic concepts and theory that will be referred to in later chapters, such as the density operator, product operators, rotations, coherence transfer pathways, phase cycling, and the various nuclear spin interactions, including the quadrupolar interaction. Chapter 2 describes the theory behind motional averaging experiments, including DAS, which is a technique where a sample is spun sequentially about two axis oriented at different angles with respect to the external magnetic field such that the chemical shift and quadrupolar anisotropy are averaged to zero. Work done on various rubidium-87 salts is presented as a demonstration of DAS. Chapter 3 explains how to remove sidebands from DAS and magic-angle spinning (MAS) experiments, which result from the time-dependence of the Hamiltonian under sample spinning conditions, using rotor-synchronized {pi}-pulses. Data from these experiments, known as DAH-180 and MAH-180, respectively, are presented for both rubidium and lead salts. In addition, the applicability of this technique to double rotation (DOR) experiments is discussed. Chapter 4 concerns the addition of cross-polarization to DAS (CPDAS). The theory behind spin locking and cross polarizing quadrupolar nuclei is explained and a method of avoiding the resulting problems by performing cross polarization at 0{sup o} (parallel) with respect to the magnetic field is presented. Experimental results are shown for a sodium-23 compound, sodium pyruvate, and for oxygen-17 labeled L-akmine. In Chapter 5, a method for broadening the Hartmann-Hahn matching condition under MAS, called variable effective field cross-polarization (VEFCI?), is presented, along with experimental work on adamantane and polycarbonate.

Gann, Sheryl Lee

1995-11-30T23:59:59.000Z

343

Remote NMR/MRI detection of laser polarized gases  

DOE Patents [OSTI]

An apparatus and method for remote NMR/MRI spectroscopy having an encoding coil with a sample chamber, a supply of signal carriers, preferably hyperpolarized xenon and a detector allowing the spatial and temporal separation of signal preparation and signal detection steps. This separation allows the physical conditions and methods of the encoding and detection steps to be optimized independently. The encoding of the carrier molecules may take place in a high or a low magnetic field and conventional NMR pulse sequences can be split between encoding and detection steps. In one embodiment, the detector is a high magnetic field NMR apparatus. In another embodiment, the detector is a superconducting quantum interference device. A further embodiment uses optical detection of Rb--Xe spin exchange. Another embodiment uses an optical magnetometer using non-linear Faraday rotation. Concentration of the signal carriers in the detector can greatly improve the signal to noise ratio.

Pines, Alexander; Saxena, Sunil; Moule, Adam; Spence, Megan; Seeley, Juliette A.; Pierce, Kimberly L.; Han, Song-I; Granwehr, Josef

2006-06-13T23:59:59.000Z

344

Investigations of the R5(SixGe1-x)4 Intermetallic Compounds by X-Ray Resonant Magnetic Scattering  

SciTech Connect (OSTI)

The XRMS experiment on the Gd{sub 5}Ge{sub 4} system has shown that, below the Neel temperature, T{sub N} = 127 K, the magnetic unit cells is the same as the chemical unit cell. From azimuth scans and the Q dependence of the magnetic scattering, all three Gd sites in the structure were determined to be in the same magnetic space group Pnma. The magnetic moments are aligned along the c-axis and the c-components of the magnetic moments at the three different sites are equal. The ferromagnetic slabs are stacked antiferromagnetically along the b-direction. They found an unusual order parameter curve in Gd{sub 5}Ge{sub 4}. A spin-reorientation transition is a possibility in Gd{sub 5}Ge{sub 4}, which is similar to the Tb{sub 5}Ge{sub 4} case. Tb{sub 5}Ge{sub 4} possesses the same Sm{sub 5}Ge{sub 4}-type crystallographic structure and the same magnetic space group as Gd{sub 5}Ge{sub 4} does. The difference in magnetic structure is that Tb{sub 5}Ge{sub 4} has a canted one but Gd{sub 5}Ge{sub 4} has nearly a collinear one in the low temperature antiferromagnetic phase. The competition between the magneto-crystalline anisotropy and the nearest-neighbor magnetic exchange interactions may allow a 3-dimensional canted antiferromagnetic structure in Tb{sub 5}Ge{sub 4}. The spin-reorientation transition in both Gd{sub 5}Ge{sub 4} and Tb{sub 5}Ge{sub 4} may arise from the competition between the magnetic anisotropy from the spin-orbit coupling of the conduction electrons and the dipolar interactions anisotropy.

Lizhi Tan

2008-08-18T23:59:59.000Z

345

Integrated, Multi-Scale Characterization of Imbibition and Wettability Phenomena Using Magnetic Resonance and Wide-Band Dielectric Measurements  

SciTech Connect (OSTI)

The petrophysical properties of rocks, particularly their relative permeability and wettability, strongly influence the efficiency and the time-scale of all hydrocarbon recovery processes. However, the quantitative relationships needed to account for the influence of wettability and pore structure on multi-phase flow are not yet available, largely due to the complexity of the phenomena controlling wettability and the difficulty of characterizing rock properties at the relevant length scales. This project brings together several advanced technologies to characterize pore structure and wettability. Grain-scale models are developed that help to better interpret the electric and dielectric response of rocks. These studies allow the computation of realistic configurations of two immiscible fluids as a function of wettability and geologic characteristics. These fluid configurations form a basis for predicting and explaining macroscopic behavior, including the relationship between relative permeability, wettability and laboratory and wireline log measurements of NMR and dielectric response. Dielectric and NMR measurements have been made show that the response of the rocks depends on the wetting and flow properties of the rock. The theoretical models can be used for a better interpretation and inversion of standard well logs to obtain accurate and reliable estimates of fluid saturation and of their producibility. The ultimate benefit of this combined theoretical/empirical approach for reservoir characterization is that rather than reproducing the behavior of any particular sample or set of samples, it can explain and predict trends in behavior that can be applied at a range of length scales, including correlation with wireline logs, seismic, and geologic units and strata. This approach can substantially enhance wireline log interpretation for reservoir characterization and provide better descriptions, at several scales, of crucial reservoir flow properties that govern oil recovery.

Mukul M. Sharma; Steven L. Bryant; Carlos Torres-Verdin; George Hirasaki

2007-09-30T23:59:59.000Z

346

Electro-mechanical energy conversion system having a permanent magnet machine with stator, resonant transfer link and energy converter controls  

DOE Patents [OSTI]

An electro-mechanical energy conversion system coupled between an energy source and an energy load comprising an energy converter device including a permanent magnet induction machine coupled between the energy source and the energy load to convert the energy from the energy source and to transfer the converted energy to the energy load and an energy transfer multiplexer to control the flow of power or energy through the permanent magnetic induction machine.

Skeist, S. Merrill; Baker, Richard H.

2006-01-10T23:59:59.000Z

347

Final Report: Characterization of Hydrogen Adsorption in Carbon-Based Materials by NMR  

SciTech Connect (OSTI)

In support of DOE/EERE's Fuel Cell Technologies Program Hydrogen Sorption Center of Excellence (HSCoE), UNC conducted Nuclear Magnetic Resonance (NMR) measurements that contributed spectroscopic information as well as quantitative analysis of adsorption processes. While NMR based Langmuir isotherms produce reliable H2 capacity measurements, the most astute contribution to the center is provided by information on dihydrogen adsorption on the scale of nanometers, including the molecular dynamics of hydrogen in micropores, and the diffusion of dihydrogen between macro and micro pores. A new method to assess the pore width using H2 as probe of the pore geometry was developed and is based on the variation of the observed chemical shift of adsorbed dihydrogen as function of H2 pressure. Adsorbents designed and synthesized by the Center were assessed for their H2 capacity, the binding energy of the adsorption site, their pore structure and their ability to release H2. Feedback to the materials groups was provided to improve the materials properties. To enable in situ NMR measurements as a function of H2 pressure and temperature, a unique, specialized NMR system was designed and built. Pressure can be varied between 10-4 and 107 Pa while the temperature can be controlled between 77K and room temperature. In addition to the 1H investigation of the H2 adsorption process, NMR was implemented to measure the atomic content of substituted elements, e.g. boron in boron substituted graphitic material as well as to determine the local environment and symmetry of these substituted nuclei. The primary findings by UNC are the following: Boron substituted for carbon in graphitic material in the planar BC3 configuration enhances the binding energy for adsorbed hydrogen. Arrested kinetics of H2 was observed below 130K in the same boron substituted carbon samples that combine enhanced binding energy with micropore structure. Hydrogen storage material made from activated PEEK is well suited for hydrogen storage due to its controlled microporous structure and large surface area. A new porosimetry method for evaluating the pore landscape using H2 as a probe was developed. 1H NMR can probe the nanoscale pore structure of synthesized material and can assess the pore dimension over a range covering 1.2 nm to 2.5 nm, the size that is desired for H2 adsorption. Analysis of 1H NMR spectra in conjunction with the characterization of the bonding structure of the adsorbent by 13C NMR distinguishes between a heterogeneous and homogeneous pore structure as evidenced by the work on AX21 and activated PEEK. Most of the sorbents studied are suited to hydrogen storage at low temperature (T < 100K). Of the materials investigated, only boron substituted graphite has the potential to work at higher temperatures if the boron content in the favorable planar BC3 configuration that actively contributes to adsorption can be increased.

Yue Wu; Alfred Kleinhammes

2011-07-11T23:59:59.000Z

348

NMR spectroscopic studies of "titanocene"  

E-Print Network [OSTI]

NMR SPECTROSCOPIC STUDIES OF "TITANOCENE" A Thea is by DONALD FLOYD BIRKELBACH Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1971 Ma)or Sub...)cot: Chemistry NMR SPECTROSCOPIC STUDIES OF "TITANOCENE" A Thesis by DONALD FLOYD BIRKELBACH Approved as to style and content by: (C ai"iman of Committee) (Head of Department) (Member) (Member) (Member) (Memb er) (Member) May 1971 ABSTRACT NMR...

Birkelbach, Donald Floyd

1971-01-01T23:59:59.000Z

349

NMR analysis on microfluidic devices by remote detection  

SciTech Connect (OSTI)

We present a novel approach to perform high-sensitivity NMR imaging and spectroscopic analysis on microfluidic devices. The application of NMR, the most information rich spectroscopic technique, to microfluidic devices remains a challenge because the inherently low sensitivity of NMR is aggravated by small fluid volumes leading to low NMR signal, and geometric constraints resulting in poor efficiency for inductive detection. We address the latter by physically separating signal detection from encoding of information with remote detection. Thereby, we use a commercial imaging probe with sufficiently large diameter to encompass the entire device, enabling encoding of NMR information at any location on the chip. Because large-diameter coils are too insensitive for detection, we store the encoded information as longitudinal magnetization and flow it into the outlet capillary. There, we detect the signal with optimal sensitivity using a solenoidal microcoil, and reconstruct the information encoded in the fluid. We present a generally applicable design for a detection-only microcoil probe that can be inserted into the bore of a commercial imaging probe. Using hyperpolarized 129Xe gas, we show that this probe enables sensitive reconstruction of NMR spectroscopic information encoded by the large imaging probe while keeping the flexibility of a large coil.

McDonnell, Erin E.; Han, SongI; Hilty, Christian; Pierce,Kimberly; Pines, Alexander

2005-08-15T23:59:59.000Z

350

Design and characterization of 2.45 GHz electron cyclotron resonance plasma source with magnetron magnetic field configuration for high flux of hyperthermal neutral beam  

SciTech Connect (OSTI)

A 2.45 GHz electron cyclotron resonance (ECR) source with a magnetron magnetic field configuration was developed to meet the demand of a hyperthermal neutral beam (HNB) flux on a substrate of more than 1x10{sup 15} cm{sup -2} s{sup -1} for industrial applications. The parameters of the operating pressure, ion density, electron temperature, and distance between the neutralization plate and the substrate for the HNB source are specified in a theoretical analysis. The electron temperature and the ion density are measured to characterize the ECR HNB source using a Langmuir probe and optical emission spectroscopy. The parameters of the ECR HNB source are in good agreement with the theoretically specified parameters.

Kim, Seong Bong [Department of Physics, Pohang University of Science and Technology, San 31, Hyoja-dong, Nam-gu, Pohang 790-784 (Korea, Republic of); Convergence Plasma Research Center, National Fusion Research Institute, Gwahangno 113, Yuseong-gu, Daejeon 305-333 (Korea, Republic of); Kim, Dae Chul; Yoo, Suk Jae [Convergence Plasma Research Center, National Fusion Research Institute, Gwahangno 113, Yuseong-gu, Daejeon 305-333 (Korea, Republic of); Namkung, Won; Cho, Moohyun [Department of Physics, Pohang University of Science and Technology, San 31, Hyoja-dong, Nam-gu, Pohang 790-784 (Korea, Republic of)

2010-08-15T23:59:59.000Z

351

Generating Squeezed States of Nanomechanical Resonator  

E-Print Network [OSTI]

We propose a scheme for generating squeezed states in solid state circuits consisting of a nanomechanical resonator (NMR), a superconducting Cooper-pair box (CPB) and a superconducting transmission line resonator (STLR). The nonlinear interaction between the NMR and the STLR can be implemented by setting the external biased flux of the CPB at certain values. The interaction Hamiltonian between the NMR and the STLR is derived by performing Fr$\\rm\\ddot o$hlich transformation on the total Hamiltonian of the combined system. Just by adiabatically keeping the CPB at the ground state, we get the standard parametric down-conversion Hamiltonian. The CPB plays the role of ``nonlinear media", and the squeezed states of the NMR can be easily generated in a manner similar to the three-wave mixing in quantum optics. This is the three-wave mixing in a solid-state circuit.

Wen Yi Huo; Gui Lu Long

2007-06-15T23:59:59.000Z

352

EMSL - NMR and EPR  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to UserProduct:DirectivesSAND2015-21271 7 6nmr_epr Interfacial and in situ

353

Repetitive resonant railgun power supply  

DOE Patents [OSTI]

A repetitive resonant railgun power supply provides energy for repetitively propelling projectiles from a pair of parallel rails. The supply comprises an energy storage capacitor, a storage inductor to form a resonant circuit with the energy storage capacitor and a magnetic switch to transfer energy between the resonant circuit and the pair of parallel rails for the propelling of projectiles.

Honig, E.M.; Nunnally, W.C.

1985-06-19T23:59:59.000Z

354

Real-Time Color-Flow Magnetic ResonanceImaging of Congenital Heart Disease E. De La Pena-Almaguer, K. S. Nayak, M. Terashima, P.C. Yang,  

E-Print Network [OSTI]

Real-Time Color-Flow Magnetic ResonanceImaging of Congenital Heart Disease E. De La Pena used for the diagnosis of congenital heart disease (CHD), although it has limitations. Conventional MRI flow pulse sequence.A low flip- angle water selective spectral-spatial excitation is followed

Southern California, University of

355

Advances in NMR Methodology  

E-Print Network [OSTI]

to masking tape, before casting in epoxy resin . . . . .material, such as epoxy resin, changing the concentration ofbefore casting in epoxy resin the magnetic permeability of

Trease, David Richard

2010-01-01T23:59:59.000Z

356

Neuroimaging at 1.5 T and 3.0 T: Comparison of Oxygenation-Sensitive Magnetic Resonance Imaging  

E-Print Network [OSTI]

and becomes a larger fraction of the total noise at 3.0 T. Activation of the primary motor and visual cortex a magnetic field strength of 1.5 Tesla (T) seems to represent a good compromise. Functional MRI (f

Glover, Gary H.

357

Role of dopant incorporation on the magnetic properties of Ce1-xNixO2 nanoparticles: An electron paramagnetic resonance study  

SciTech Connect (OSTI)

Nickel doping has been found to produce weak room-temperature ferromagnetism in CeO2 [1]. The saturation magnetization of the chemically synthesized Ce1-xNixO2 samples showed a maximum for x = 0.04, above which the magnetization decreased gradually. For Ce1-xNixO2 samples with x ? 0.04, an activation process involving slow annealing of the sample to 500 oC increased the saturation magnetization by more than two orders of magnitude [1]. However, no such activation effect was observed in samples with x < 0.04. Electron paramagnetic resonance (EPR), a sensitive technique to investigate the ionic states and local environments and interactions, has been used here in this work to investigate (i) why the ferromagnetic behavior gradually weakened and disappeared for x > 0.04 and (ii)_what causes the saturation magnetization to dramatically increase in the activated Ce1-xNixO2 samples with x ? 0.04 and why this process is absent in samples with x < 0.04. Our X-band (~9.4 GHz) EPR experiments and detailed simulation analysis on several as-prepared Ce1-xNixO2 samples with 0.01 ? x ? 0.10 at 5 K and 300 K indicate the presence of two magnetically inequivalent Ni2+ ions with the ionic spin of 1, one Ce3+ ion with spin , and three O2-. Spectra of samples with x < 0.04 are dominated by a single Ni2+ EPR line ascribed to dopant ions in substitutional sites whereas in samples with x ? 0.04, an additional signal attributed to Ni2+ ions in interstitial sites is also present. In the activated sample, the EPR line due to the interstitial Ni2+ is completely absent and only the lines due to substituional Ni2+ ions are present suggesting that the enhanced ferromagnetism results from conversion of interstitial Ni2+ ions to substitutional sites.

Misra, S. K.; Andronenko, S. I.; Engelhard, Mark H.; Thurber, Aaron P.; Reddy, K. M.; Punnoose, Alex

2008-04-01T23:59:59.000Z

358

Study of dibenzofuran-based amino acid nucleated antiparallel Beta-sheet using 1D- and 2D- nuclear magnetic resonance spectroscopy  

E-Print Network [OSTI]

Simple amides containing the conforrnationally restricted unnatural amino acid 4-(2-aminoethyl)-6-dibenzofuranpropanoic acid (1) were studied by NMR and FT-IR to ascertain the hydrogen bonding capabilities of 1. The preferred structure in non...

Espina, Jose Roberto

1994-01-01T23:59:59.000Z

359

Computational, electrochemical and {sup 7}Li NMR studies of lithiated disordered carbons electrodes in lithium ion cells.  

SciTech Connect (OSTI)

Disordered carbons that deliver high reversible capacity in electrochemical cells have been synthesized by using inorganic clays as templates to control the pore size and the surface area. The capacities obtained were much higher than those calculated if the resultant carbon had a graphitic-like structure. Computational chemistry was used to investigate the nature of lithium bonding in a carbon lattice unlike graphite. The lithium intercalated fullerene Li{sub n}-C{sub 60} was used as a model for our (non-graphitic) disordered carbon lattice. A dilithium-C{sub 60} system with a charge and multiplicity of (0,1) and a trilithium-C{sub 60} system with a charge and multiplicity of (0,4) were investigated. The spatial distribution of lithium ions in an electrochemical cell containing this novel disordered carbon material was investigated in situ by Li-7 NMR using an electrochemical cell that was incorporated into a toroid cavity nuclear magnetic resonance (NMR) imager. The concentration of solvated Li{sup +} ions in the carbon anode appears to be larger than in the bulk electrolyte, is substantially lower near the copper/carbon interface, and does not change with cell charging.

Sandi, G.; Gerald, R., II; Scanlon, L. G.; Carrado, K. A.; Winans, R. E.

1998-01-07T23:59:59.000Z

360

Permanent Magnet Ecr Plasma Source With Magnetic Field Optimization  

DOE Patents [OSTI]

In a plasma-producing device, an optimized magnet field for electron cyclotron resonance plasma generation is provided by a shaped pole piece. The shaped pole piece adjusts spacing between the magnet and the resonance zone, creates a convex or concave resonance zone, and decreases stray fields between the resonance zone and the workpiece. For a cylindrical permanent magnet, the pole piece includes a disk adjacent the magnet together with an annular cylindrical sidewall structure axially aligned with the magnet and extending from the base around the permanent magnet. The pole piece directs magnetic field lines into the resonance zone, moving the resonance zone further from the face of the magnet. Additional permanent magnets or magnet arrays may be utilized to control field contours on a local scale. Rather than a permeable material, the sidewall structure may be composed of an annular cylindrical magnetic material having a polarity opposite that of the permanent magnet, creating convex regions in the resonance zone. An annular disk-shaped recurve section at the end of the sidewall structure forms magnetic mirrors keeping the plasma off the pole piece. A recurve section composed of magnetic material having a radial polarity forms convex regions and/or magnetic mirrors within the resonance zone.

Doughty, Frank C. (Plano, TX); Spencer, John E. (Plano, TX)

2000-12-19T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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361

Solid state NMR method development and studies of biological and biomimetic nanocomposites  

SciTech Connect (OSTI)

This thesis describes application and development of advanced solid-state nuclear magnetic resonance techniques for complex materials, in particular organic-inorganic nanocomposites and thermoelectric tellurides. The apatite-collagen interface, essential for understanding the biomineralization process in bone and engineering the interface for controlled bio-mimetic synthesis and optimized mechanical properties, is buried within the nanocomposite of bone. We used multinuclear solid-state NMR to study the composition and structure of the interface. Citrate has been identified as the main organic molecule strongly bound to the apatite surface with a density of 1/(2 nm){sup 2}, covering 1/6 of the total surface area in bovine bone. Citrate provides more carboxylate groups, one of the key functional groups found to affect apatite nucleation and growth, than all the non-collagenous proteins all together in bone; thus we propose that citrate stabilizes apatite crystals at a very small thickness of {approx}3 nm (4 unit cells) to increase bone fracture tolerance. The hypothesis has been confirmed in vitro by adding citrate in the bio-mimetic synthesis of polymerhydroxyapatite nanocomposites. The results have shown that the size of hydroxyapatite nanocrystals decreases as increasing citrate concentration. With citrate concentrations comparable to that in body fluids, similar-sized nanocrystals as in bone have been produced. Besides the dimensions of the apatite crystals, the composition of bone also affects its biofunctional and macroscopic mechanical properties; therefore, our team also extended its effort to enhance the inorganic portion in our bio-mimetic synthesis from originally 15 wt% to current 50 wt% compared to 65 wt% in bovine bone, by using Lysine-Leucine hydroxyapatite nucleating diblock co-polypeptide, which forms a gel at very low concentration. In this thesis, various advanced solid state NMR techniques have been employed to characterize nanocomposites. Meanwhile, we have developed new methods to achieve broadband high resolution NMR and improve the accuracy of inter-nuclear distance measurements involving quadrupolar spins. Broadband high resolution NMR of spin-1/2 nuclei has been accomplished by the adaptation of the magic angle turning (MAT) method to fast magic angle spinning, termed fast MAT, by solving technical problems such as off resonance effects. Fast MAT separates chemical shift anisotropy and isotropic chemical shifts over a spectral range of {approx}1.8 {gamma}B{sub 1} without significant distortions. Fast MAT {sup 125}Te NMR has been applied to study technologically important telluride materials with spectra spreading up to 190 kHz. The signal-to-noise ratio of the spectra is significantly improved by using echo-matched Gaussian filtering in offline data processing. The accuracy of the measured distances between spin-1/2 and quadrupolar nuclei with methods such as SPIDER and REAPDOR has been improved by compensating for the fast longitudinal quadrupolar relaxation on the sub-millisecond with a modified S{sub 0} pulse sequence. Also, the T1Q effect on the spin coherence and its spinning speed dependency has been explored and documented with analytical and numerical simulations as well as experimental measurements.

Hu, Yanyan

2011-02-07T23:59:59.000Z

362

Localized In Vivo 1H NMR Detection of Neurotransmitter Labeling in Rat Brain During Infusion of [1-13C] D-Glucose  

E-Print Network [OSTI]

Localized In Vivo 1H NMR Detection of Neurotransmitter Labeling in Rat Brain During Infusion of [1 infusions of 13C-labeled glucose. Magn Reson Med 41:1077­1083, 1999. 1999 Wiley-Liss, Inc. Key words] glucose infusion In vivo 13C NMR spectroscopy with localization is emerg- ing as an important tool

Jegelka, Stefanie

363

Magnetic Resonance Angiography of the Peripheral Vessels in Patients with Peripheral Arterial Occlusive Disease: When Is an Additional Conventional Angiography Required?  

SciTech Connect (OSTI)

The purpose of this work was to find out how often the clinician asks for a conventional angiography (CA) in patients with peripheral arterial occlusive disease (PAOD) after a magnetic resonance angiography (MRA) has been performed and how often the CA reveals additional information for therapy planning. Quality criteria for the MRA were defined and tested to see whether they can predict the need for an additional CA. In this prospective study, 81 patients suffering from PAOD (Fontaine classification IIa, n = 13; IIb, n = 33; III, n = 10; IV, n = 25) were examined with a 1.5-T MR-scanner with dedicated coils using a step-by-step technique. The vascular surgeon decided whether he could plan the therapy on the basis of the MRA or if he needed an additional CA. The MRA was assessed in terms of the image quality of the MRA and regarding therapeutic management of the patient in a two-grade scale: sufficient and insufficient. In 27/81 (33%) patients, the clinician asked for a CA, which revealed new information in only 11 patients. The relative number of MRAs with insufficient image quality was significantly higher (p < 0.01) in the group with additional information on CA (8/11) compared to the group without additional information (0/16). The assessment of an MRA based on image quality and regarding therapeutic management of the patient might reduce the number of CAs for therapy planning in patients with PAOD.

Janka, R., E-mail: rolf.janka@idr.imed.uni-erlangen.de; Wenkel, E. [Friedrich-Alexander-University, Institute of Radiology (Germany); Fellner, C. [Institute of Radiology, Friedrich-Alexander-University Erlangen-Nuernberg (Germany); Lang, W. [Friedrich-Alexander-University Erlangen-Nuernberg, Vascular Surgery, Department of Surgery (Germany); Bautz, W.; Uder, M. [Friedrich-Alexander-University, Institute of Radiology (Germany)

2006-04-15T23:59:59.000Z

364

Cs{sub 4}P{sub 2}Se{sub 10}: A new compound discovered with the application of solid-state and high temperature NMR  

SciTech Connect (OSTI)

The new compound Cs{sub 4}P{sub 2}Se{sub 10} was serendipitously produced in high purity during a high-temperature synthesis done in a nuclear magnetic resonance (NMR) spectrometer. {sup 31}P magic angle spinning (MAS) NMR of the products of the synthesis revealed that the dominant phosphorus-containing product had a chemical shift of -52.8 ppm that could not be assigned to any known compound. Deep reddish brown well-formed plate-like crystals were isolated from the NMR reaction ampoule and the structure was solved with X-ray diffraction. Cs{sub 4}P{sub 2}Se{sub 10} has the triclinic space group P-1 with a=7.3587(11) A, b=7.4546(11) A, c=10.1420(15) A, {alpha}=85.938(2){sup o}, {beta}=88.055(2){sup o}, and {gamma}=85.609(2){sup o} and contains the [P{sub 2}Se{sub 10}]{sup 4-} anion. To our knowledge, this is the first compound containing this anion that is composed of two tetrahedral (PSe{sub 4}) units connected by a diselenide linkage. It was also possible to form a glass by quenching the melt in ice water, and Cs{sub 4}P{sub 2}Se{sub 10} was recovered upon annealing. The static {sup 31}P NMR spectrum at 350 deg. C contained a single peak with a -35 ppm chemical shift and a {approx}7 ppm peak width. This study highlights the potential of solid-state and high-temperature NMR for aiding discovery of new compounds and for probing the species that exist at high temperature. - Graphical abstract: The new compound Cs{sub 4}P{sub 2}Se{sub 10} was discovered following a high-temperature in situ synthesis in the NMR spectrometer and the structure was determined by single-crystal X-ray diffraction. It contains the new [P{sub 2}Se{sub 10}]{sup 4-} anion.

Gave, Matthew A.; Canlas, Christian G. [Department of Chemistry, Michigan State University, East Lansing, MI 48824 (United States); Chung, In [Department of Chemistry, Michigan State University, East Lansing, MI 48824 (United States); Department of Chemistry, Northwestern University, Evanston, IL 60208 (United States); Iyer, Ratnasabapathy G. [Department of Chemistry, Michigan State University, East Lansing, MI 48824 (United States); Kanatzidis, Mercouri G. [Department of Chemistry, Michigan State University, East Lansing, MI 48824 (United States); Department of Chemistry, Northwestern University, Evanston, IL 60208 (United States)], E-mail: m-kanatzidis@northwestern.edu; Weliky, David P. [Department of Chemistry, Michigan State University, East Lansing, MI 48824 (United States)], E-mail: weliky@chemistry.msu.edu

2007-10-15T23:59:59.000Z

365

Relationships between observed pore and pore-throat geometries, measured porosity and permeability, and indirect measures of pore volume by nuclear magnetic resonance  

E-Print Network [OSTI]

. Though NMR logging has been used to estimate pore sizes, it has not been used to identify genetic pore types or to aid in determinations of reservoir quality for different pore assemblages. Five genetic pore types identified in 40 carbonate and 7...

Adams, Aaron J.

2007-04-25T23:59:59.000Z

366

A magnetically shielded room with ultra low residual field and gradient  

SciTech Connect (OSTI)

A versatile and portable magnetically shielded room with a field of (700200) pT within a central volume of 1 m 1 m 1 m and a field gradient less than 300 pT/m, achieved without any external field stabilization or compensation, is described. This performance represents more than a hundredfold improvement of the state of the art for a two-layer magnetic shield and provides an environment suitable for a next generation of precision experiments in fundamental physics at low energies; in particular, searches for electric dipole moments of fundamental systems and tests of Lorentz-invariance based on spin-precession experiments. Studies of the residual fields and their sources enable improved design of future ultra-low gradient environments and experimental apparatus. This has implications for developments of magnetometry beyond the femto-Tesla scale in, for example, biomagnetism, geosciences, and security applications and in general low-field nuclear magnetic resonance (NMR) measurements.

Altarev, I.; Chesnevskaya, S.; Gutsmiedl, E.; Kuchler, F.; Lins, T.; Marino, M.; McAndrew, J.; Niessen, B.; Paul, S.; Petzoldt, G.; Singh, J.; Stoepler, R.; Stuiber, S.; Sturm, M.; Taubenheim, B. [Physikdepartment, Technische Universitt Mnchen, D-85748 Garching (Germany); Babcock, E. [Jlich Center for Neutron Science, Lichtenbergstrasse 1, D-85748 Garching (Germany); Beck, D.; Sharma, S. [Physics Department, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States); Burghoff, M.; Fan, I. [Physikalisch-Technische Bundesanstalt Berlin, D-10587 Berlin (Germany); and others

2014-07-15T23:59:59.000Z

367

Cerebral edema induced in mice by a convulsive dose of soman. Evaluation through diffusion-weighted magnetic resonance imaging and histology  

SciTech Connect (OSTI)

Purpose: In the present study, diffusion-weighted magnetic resonance imaging (DW-MRI) and histology were used to assess cerebral edema and lesions in mice intoxicated by a convulsive dose of soman, an organophosphate compound acting as an irreversible cholinesterase inhibitor. Methods: Three hours and 24 h after the intoxication with soman (172 {mu}g/kg), the mice were anesthetized with an isoflurane/N{sub 2}O mixture and their brain examined with DW-MRI. After the imaging sessions, the mice were sacrificed for histological analysis of their brain. Results: A decrease in the apparent diffusion coefficient (ADC) was detected as soon as 3 h after the intoxication and was found strongly enhanced at 24 h. A correlation was obtained between the ADC change and the severity of the overall brain damage (edema and cellular degeneration): the more severe the damage, the stronger the ADC drop. Anesthesia was shown to interrupt soman-induced seizures and to attenuate edema and cell change in certain sensitive brain areas. Finally, brain water content was assessed using the traditional dry/wet weight method. A significant increase of brain water was observed following the intoxication. Conclusions: The ADC decrease observed in the present study suggests that brain edema in soman poisoning is mainly intracellular and cytotoxic. Since entry of water into Brain was also evidenced, this type of edema is certainly mixed with others (vasogenic, hydrostatic, osmotic). The present study confirms the potential of DW-MRI as a non-invasive tool for monitoring the acute neuropathological consequences (edema and neurodegeneration) of soman-induced seizures.

Testylier, Guy [Centre de Recherches du Service Sante des Armees, Departement de Toxicologie, BP87, F-38702 La Tronche cedex (France)]. E-mail: guytestylier@crssa.net; Lahrech, Hana [Inserm, UMR-S 836-Grenoble Institut des Neurosciences, Grenoble, F-38043 (France); Universite Joseph Fourier, Grenoble, F-38043 (France); Montigon, Olivier [Inserm, UMR-S 836-Grenoble Institut des Neurosciences, Grenoble, F-38043 (France); Universite Joseph Fourier, Grenoble, F-38043 (France); Foquin, Annie [Centre de Recherches du Service Sante des Armees, Departement de Toxicologie, BP87, F-38702 La Tronche cedex (France); Delacour, Claire [Centre de Recherches du Service Sante des Armees, Departement de Toxicologie, BP87, F-38702 La Tronche cedex (France); Bernabe, Denis [Centre de Recherches du Service Sante des Armees, Departement de Toxicologie, BP87, F-38702 La Tronche cedex (France); Segebarth, Christoph [Inserm, UMR-S 836-Grenoble Institut des Neurosciences, Grenoble, F-38043 (France); Universite Joseph Fourier, Grenoble, F-38043 (France); Dorandeu, Frederic [Centre de Recherches du Service Sante des Armees, Departement de Toxicologie, BP87, F-38702 La Tronche cedex (France); Carpentier, Pierre [Centre de Recherches du Service Sante des Armees, Departement de Toxicologie, BP87, F-38702 La Tronche cedex (France)

2007-04-15T23:59:59.000Z

368

Determination of the chemistry of HF acidizing with the use of {sup 19}F NMR spectroscopy  

SciTech Connect (OSTI)

A more thorough understanding of the chemistry of HF acid and its reaction products on silica and alumino-silicates is essential to the design and optimization of HF acidizing treatments. To more clearly define the chemistry of HF acidizing, an in-depth investigation of the reaction of HF and H{sub 2}SiF{sub 6} with alumino-silicates was undertaken using {sup 19}F Nuclear Magnetic Resonance (NMR) spectroscopy. In addition to the fluosilicic acid (H{sub 2}SiF{sub 6}) and AlF{sup 2+} predicted by traditional theories, {sup 19}F NMR spectroscopy shows a complex mixture of silicon and aluminum fluoride species in reacted HF acidizing solutions. During a secondary reaction of silicon fluorides with alumino-silicates, a constant F/Al ratio was maintained until the silicon fluorides had reacted completely. The distribution of the fluoride species depends on the HCl concentration. In this investigation, a tertiary reaction of HF acid on alumino-silicates was identified. When the silicon fluorides have reacted completely to give silica gel, the aluminum fluoride complexes continue to react on fresh alumino-silicates. The reaction causes the aluminum content to increase and the F/Al ratio and acid concentration to decrease. The final F/Al ratio is dependent upon acid strength and temperature. Numerous HF acidizing well returns have been analyzed to verify the reactions conducted in the laboratory. The extent of the reaction of HF acid can be determined with the use of {sup 19}F NMR spectroscopy. In wells with temperatures of 150 to 200 F, the reaction of H{sub 2}SiF{sub 6} is complete. Silicon content was quite low, and pH levels were 2 to 3. The F/Al ratios of the returns were 0.5 to 1.3, depending on the concentration of HCl and HF used in the treatment. In wells less than 100 F, the secondary reaction did not go to completion. Silicon and aluminum fluoride complexes were present in the returns along with live HCl.

Shuchart, C.E.; Buster, D.C.

1995-11-01T23:59:59.000Z

369

Electronic Characterization of Lithographically Patterned Microcoils for High Sensitivity NMR Detection  

SciTech Connect (OSTI)

Nuclear magnetic resonance (NMR) offers a non-destructive, powerful, structure-specific analytical method for the identification of chemical and biological systems. The use of radio frequency (RF) microcoils has been shown to increase the sensitivity in mass limited samples. Recent advances in micro-receiver technology have further demonstrated a substantial increase in mass sensitivity [1]. Lithographic methods for producing solenoid microcoils possess a level of flexibility and reproducibility that exceeds previous production methods, such as hand winding microcoils. This paper presents electrical characterizations of RF microcoils produced by a unique laser lithography system that can pattern three dimensional surfaces and compares calculated and experimental results to those for wire wound RF microcoils. We show that existing optimization conditions for RF coil design still hold true for RF microcoils produced by lithography. Current lithographic microcoils show somewhat inferior performance to wire wound RF microcoils due to limitations in the existing electroplating technique. In principle, however, when the pitch of the RF microcoil is less than 100 {micro}m lithographic coils should show comparable performance to wire wound coils. In the cases of larger pitch, wire cross sections can be significantly larger and resistances lower than microfabricated conductors.

Demas, V; Bernhardt, A; Malba, V; Adams, K L; Evans, L; Harvey, C; Maxwell, R S; Herberg, J L

2009-01-13T23:59:59.000Z

370

Apparatus and method for generating a magnetic field by rotation of a charge holding object  

DOE Patents [OSTI]

A device and a method for the production of a magnetic field using a Charge Holding Object that is mechanically rotated. In a preferred embodiment, a Charge Holding Object surrounding a sample rotates and subjects the sample to one or more magnetic fields. The one or more magnetic fields are used by NMR Electronics connected to an NMR Conductor positioned within the Charge Holding Object to perform NMR analysis of the sample.

Gerald, II, Rex E. (Brookfield, IL); Vukovic, Lela (Westchester, IL); Rathke, Jerome W. (Homer Glenn, IL)

2009-10-13T23:59:59.000Z

371

E-Print Network 3.0 - ablation assisted resonance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

enhancement (LGE) mag- netic resonance imaging (MRI) immediately post-ablation (IPA... enhancement MRI magnetic resonance imaging NE nonenhancing RF radiofrequency RFA...

372

Decay of an ultracold fermionic lithium gas near a Feshbach resonance The interactions between atoms can be strongly modified by tuning magnetic fields to  

E-Print Network [OSTI]

Decay of an ultracold fermionic lithium gas near a Feshbach resonance The interactions between the interaction strength is crucial in the search for a superfluid phase transition. Otherwise, the phase lithium gas near a Feshbach resonance, Phys. Rev. Lett. 89, 203201 (2002). 2. K.M. O'Hara, S.L. Hemmer, S

373

Strong reduction of V{sup 4+} amount in vanadium oxide/hexadecylamine nanotubes by doping with Co{sup 2+} and Ni{sup 2+} ions: Electron paramagnetic resonance and magnetic studies  

SciTech Connect (OSTI)

In this work we present a complete characterization and magnetic study of vanadium oxide/hexadecylamine nanotubes (VO{sub x}/Hexa NT's) doped with Co{sup 2+} and Ni{sup 2+} ions. The morphology of the NT's has been characterized by transmission electron microscopy, while the metallic elements have been quantified by the instrumental neutron activation analysis technique. The static and dynamic magnetic properties were studied by collecting data of magnetization as a function of magnetic field and temperature and by electron paramagnetic resonance. At difference of the majority reports in the literature, we do not observe magnetic dimers in vanadium oxide nanotubes. Also, we observed that the incorporation of metallic ions (Co{sup 2+}, S = 3/2 and Ni{sup 2+}, S = 1) decreases notably the amount of V{sup 4+} ions in the system, from 14-16% (nondoped case) to 2%-4%, with respect to the total vanadium atoms (fact corroborated by XPS experiments) anyway preserving the tubular nanostructure. The method to decrease the amount of V{sup 4+} in the nanotubes improves considerably their potential technological applications as Li-ion batteries cathodes.

Saleta, M. E.; Troiani, H. E.; Ribeiro Guevara, S.; Ruano, G.; Sanchez, R. D. [Centro Atomico Bariloche, CNEA, (8400) S. C. de Bariloche (Argentina); Malta, M. [Depto. de Cs. Exatas e da Terra, Univ. do Estado da Bahia, Cabula Salvador CP 2555 (Brazil); Torresi, R. M. [Instituto de Quimica, Universidad de Sao Paulo, Sao Paulo CP 26077, 05513-970 (Brazil)

2011-05-01T23:59:59.000Z

374

Magnetic Resonance Imaging of concrete  

E-Print Network [OSTI]

velocity Relates Elastic modulus to speed of sound Assumes Concrete heterogeneous Can be affected by steel Modulus related to speed of sound Strength of concrete related to modulus Location of flaws structure In both cases procedure is destructive Systems to monitor concrete modulus Ultra-sonic pulse

Burgoyne, Chris

375

Whole-Body Magnetic Resonance Angiography with Additional Steady-State Acquisition of the Infragenicular Arteries in Patients with Peripheral Arterial Disease  

SciTech Connect (OSTI)

The purpose of this investigation was to determine if addition of infragenicular steady-state (SS) magnetic resonance angiography (MRA) to first-pass imaging improves diagnostic performance compared with first-pass imaging alone in patients with peripheral arterial disease (PAD) undergoing whole-body (WB) MRA. Twenty consecutive patients with PAD referred to digital-subtraction angiography (DSA) underwent WB-MRA. Using a bolus-chase technique, first-pass WB-MRA was performed from the supra-aortic vessels to the ankles. The blood-pool contrast agent gadofosveset trisodium was used at a dose of 0.03 mmol/kg body weight. Ten minutes after injection of the contrast agent, high-resolution (0.7-mm isotropic voxels) SS-MRA of the infragenicular arteries was performed. Using DSA as the 'gold standard,' sensitivities and specificities for detecting significant arterial stenoses ({>=}50% luminal narrowing) with first-pass WB-MRA, SS-MRA, and combined first-pass and SS-MRA were calculated. Kappa statistics were used to determine intermodality agreement between MRA and DSA. Overall sensitivity and specificity for detecting significant arterial stenoses with first-pass WB-MRA was 0.70 (95% confidence interval 0.61 to 0.78) and 0.97 (0.94 to 0.99), respectively. In first-pass WB-MRA, the lowest sensitivity was in the infragenicular region, with a value of 0.42 (0.23 to 0.63). Combined analysis of first-pass WB-MRA and SS-MRA increased sensitivity to 0.81 (0.60 to 0.93) in the infragenicular region, with specificity of 0.94 (0.88 to 0.97). Sensitivity and specificity for detecting significant arterial stenoses with isolated infragenicular SS-MRA was 0.47 (0.27 to 0.69) and 0.86 (0.78 to 0.91), respectively. Intermodality agreement between MRA and DSA in the infragenicular region was moderate for first-pass WB-MRA ({kappa} = 0.49), fair for SS-MRA ({kappa} = 0.31), and good for combined first-pass/SS-MRA ({kappa} = 0.71). Addition of infragenicular SS-MRA to first-pass WB MRA improves diagnostic performance.

Nielsen, Yousef W., E-mail: yujwni01@heh.regionh.d [University Hospital at Herlev, Department of Radiology (Denmark); Eiberg, Jonas P. [Rigshospitalet, Department of Vascular Surgery (Denmark); Logager, Vibeke B. [University Hospital at Herlev, Department of Radiology (Denmark); Just, Sven [University Hospital at Gentofte, Department of Radiology (Denmark); Schroeder, Torben V. [Rigshospitalet, Department of Vascular Surgery (Denmark); Thomsen, Henrik S. [University Hospital at Herlev, Department of Radiology (Denmark)

2010-06-15T23:59:59.000Z

376

Use of Non-Invasive Phase Contrast Magnetic Resonance Imaging for Estimation of Atrial Septal Defect Size and Morphology: A Comparison with Transesophageal Echo  

SciTech Connect (OSTI)

Background: Transesophageal echocardiography (TEE) is a trusted method of sizing atrial septal defect (ASD) prior to percutaneous closure but is invasive, uncomfortable, and may carry a small risk of morbidity and mortality. Magnetic resonance imaging (MRI) may be useful non-invasive alternative in such patients who refuse or are unable to tolerate TEE and may provide additional information on the shape of the A0SD. Purpose: To validate the accuracy of ASD sizing by MRI compared with TEE.Method: Twelve patients (mean age 30 years; range 11-60 years) scheduled for ASD closure underwent TEE, cine balanced fast field echo MRI (bFFE-MRI) in four-chamber and sagittal views and phase-contrast MRI (PC-MRI) with reconstruction using the two orthogonal planes of T2-weighted images as planning. The average of the three longest measurements for all imaging modalities was calculated for each patient. Results: Mean maximum ASD length on TEE was 18.8 {+-} 4.6 mm, mean length by bFFE-MRI was 20.0 {+-} 5.0 mm, and mean length by PC-MRI was 18.3 {+-} 3.6 mm. The TEE measurement was significantly correlated with the bFFE-MRI and PC-MRI measurements (Pearson r = 0.69, p = 0.02 and r = 0.59, p = 0.04, respectively). The mean difference between TEE and bFFE-MRI measurements was -1.2mm (95% CI: -3.7, 1.3) and between TEE and PC-MRI was 0.5 mm (95% CI: -1.9, 2.9). Bland-Altman analysis also determined general agreement between both MRI methods and TEE. The ASDs were egg-shaped in two cases, circular in 1 patient and oval in the remaining patients. Conclusion: ASD sizing by MRI using bFFE and phase-contrast protocols correlated well with TEE estimations. PC-MRI provided additional information on ASD shapes and proximity to adjacent structures.

Piaw, Chin Sze; Kiam, Ong Tiong [Sarawak General Hospital, Department of Cardiology (Malaysia); Rapaee, Annuar [University of Malaysia Sarawak (Malaysia)], E-mail: rannuar@fmhs.unimas.myp; Khoon, Liew Chee; Bang, Liew Houng; Ling, Chan Wei [Sarawak General Hospital, Department of Cardiology (Malaysia); Samion, Hasri [National Heart Institute, Pediatric of Cardiology (Malaysia); Hian, Sim Kui [Sarawak General Hospital, Department of Cardiology (Malaysia)

2006-04-15T23:59:59.000Z

377

JOURNAL OF MAGNETIC RESONANCE 28,383-390 (1977) High-Resolution `H and llB NMR Studiesof 1,2-and 1,7-B&H,,  

E-Print Network [OSTI]

,7-B&H,, A. R. GARBER,G. M. BODNER,AND L. J. TODD Department of Chemistry,' Indiana University, Bloomington, Indiana 47401 AND A. R. SIEDLE~ Inorganic Chemistry Section, National Bureau of Standards by butyllithium and quenching by slow addition of D,O. The deuterated carboranes were purified by sublimation

Bodner, George M.

378

SOLID STATE NMR STUDY SUPPORTING THE LITHIUM VACANCY DEFECT MODEL IN CONGRUENT LITHIUM  

E-Print Network [OSTI]

@ Pergamon SOLID STATE NMR STUDY SUPPORTING THE LITHIUM VACANCY DEFECT MODEL IN CONGRUENT LITHIUM performed on powdered and single crystal lithium niobate of defectivecongruent composition (48.4%LirO;51.6% NbrOr) using a magnetic field strength of 7.05 Tesla with the aim to distinguish between a lithium

Bluemel, Janet

379

Prediction of middle-distillate fuel properties using liquid chromatography-proton nuclear magnetic resonance spectroscopy data. Final report, 1987-1988  

SciTech Connect (OSTI)

This research was initiated to support the Army's capability to identify the components of fuels that contribute to low-temperature performance of fuels. It was discovered that various physical properties of middle-distillate fuels can be predicted. The LC-{sup 1}HNMR technique was developed to predict physical properties based on chemical structures present in the fuels. The prediction of properties is approached from a 'group property' point of view. In the group property approach, the structure of the molecule is examined for structural features that dictate the physical properties of the compounds. In other words, the physical properties of a molecule or compound are determined by the number of types of chemical groups, i.e., methyl, methylene, methine, etc., present. These LC-{sup 1}H NMR predicted property measurements were compared to measurements obtained by the ASTM fuel tests. Most measurements were found to be within experimental error. The research has demonstrated that the LC-{sup 1}H NMR approach for measuring various middle-distillate fuel properties can be used as an alternative to the ASTM methods of fuel property measurement.

Swann, M.

1989-06-01T23:59:59.000Z

380

NMR Quantum Information Processing with Para-Hydrogen  

E-Print Network [OSTI]

This thesis addresses the problems of initialization and separability in liquid state NMR based quantum information processors. We prepare pure quantum states lying above the entanglement threshold. Our pure state quantum computer derives its purity from the highly polarized nuclear spin states in the para-hydrogen molecule. The thesis begins with a critique of conventional NMR based quantum information processing outlining the major strengths and weaknesses of the technology. We describe the enhanced magnetic ordering of the nuclear spin states in para-hydrogen and an initialization experiment exploiting this effect to achieve pure, entangled states. These states can indeed be used as initial states in implementing quantum algorithms: we describe mplementations of the Deutsch and the Grover quantum algorithms. The "twirl" operation converts a completely arbitrary input state to a Werner singlet. The NMR implementation of this operation is taken up. We also analyze the possibility of sharing the purity of some highly polarized qubits in a quantum computer onto quantum subspaces of arbitrary dimensions, and whether these sharing operations increase or decrease the likelihood of entanglement.

M. S. Anwar

2005-09-07T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Dynamic control of spin states in interacting magnetic elements  

DOE Patents [OSTI]

A method for the control of the magnetic states of interacting magnetic elements comprising providing a magnetic structure with a plurality of interacting magnetic elements. The magnetic structure comprises a plurality of magnetic states based on the state of each interacting magnetic element. The desired magnetic state of the magnetic structure is determined. The active resonance frequency and amplitude curve of the desired magnetic state is determined. Each magnetic element of the magnetic structure is then subjected to an alternating magnetic field or electrical current having a frequency and amplitude below the active resonance frequency and amplitude curve of said desired magnetic state and above the active resonance frequency and amplitude curve of the current state of the magnetic structure until the magnetic state of the magnetic structure is at the desired magnetic state.

Jain, Shikha; Novosad, Valentyn

2014-10-07T23:59:59.000Z

382

Discrete analysis of stochastic NMR  

SciTech Connect (OSTI)

Stochastic NMR is an efficient technique for high field in vivo imaging and spectroscopic studies in cases where the peak rf power required may be prohibitively high for conventional pulsed NMR techniques. This dissertation presents a theoretical analysis of a stochastic NMR method of acquiring spectroscopy data. The spin system is excited with rf pulses where the flip angles or the phases of the pulses are samples of a discrete stochastic process. The method is formulated as a stochastic difference equation which is then converted to ordinary deterministic difference equations describing the input-output cross-correlation, average signal power and signal power spectrum. The solutions of these equations are used to evaluate the stochastic, technique in terms of peak rf power requirement, spectral distortions and signal-to-noise ratio. Experimental results are also presented which verify the results of the discrete analysis. The analysis shows that the maximum signal-to-noise ratio is achieved when the RMS flip angle is approximately the Ernst angle. When the RMS flip angle is below the Ernst angle, the input-output cross-correlation is a good estimate of the FID. Increase of excitation power causes line broadening. In addition, the use of random flip angle, fixed phase excitation causes a notch artifact and non-uniform response across the spectrum both of which are not found in two new types of excitation, the random phase excitation and the random quadrature excitation. The signal power spectrum is also a good estimate of the real spectrum. The approximation of the cross-correlation by a time average causes systematic noise. The amount of systematic noise is found to be significantly reduced when an entire maximum length sequence (MLS) is used for excitation. Noise-like distortion at high power MLS excitation is discovered to be related to the number of feedback paths in the MLS generator. 29 refs., 58 figs.

Wong, Sam Tak-Sum

1988-12-01T23:59:59.000Z

383

I: Low Frequency NMR and NQR Using a dc SQUID. II: Variable-temperature 13C CP/MAS of Organometallics  

SciTech Connect (OSTI)

NMR and NQR at low frequencies are difficult prospects due to small nuclear spin polarization. Furthermore, the sensitivity'of the inductive pickup circuitry of standard spectrometers is reduced as the frequency is lowered. I have used a cw-SQUID (Superconducting QUantum Interference Device) spectrometer, which has no such frequency dependence, to study the local atomic environment of {sup 14}N via the quadrupolar interaction. Because {sup 14}N has spin I = 1 and a 0-6 MHz frequency range, it is not possible to obtain well-resolved spectra in high magnetic fields. I have used a technique to observe {sup 14}N NQR resonances via their effect on neighboring protons mediated by the heteronuclear dipolar interaction to study peptides and narcotics. The sensitivity of the SQUID is not enough to measure low-frequency surface (or other low spin density) systems. The application of spin-polarized xenon has been previously used to enhance polarization in conventional NMR experiments. Because xenon only polarizes spins with which it is in contact, it is surface selective. While differences in chemical shifts between surface and bulk spins are not large, it is expected that the differences in quadrupole coupling constant should be very large due to the drastic change of the electric field gradient surrounding spins at the surface. With this in mind, I have taken preliminary steps to measure SQUID detected polarization transfer from Xe to another spin species at 4.2 K and in small magnetic fields (<50 G). In this regime, the spin-lattice relaxation of xenon is dependent on the applied magnetic field. The results of our efforts to characterize the relaxation of xenon are presented. The final section describes the solid-state variable-temperature (VT) one- and two-dimensional {sup 13}C cross polarization (CP)/magic angle spinning (MAS) NMR of Hf({eta}{sup 5}-C{sub 5}H{sub 5}){sub 2}({eta}{sup 1}-C{sub 5}H{sub 5}){sub 2}, Zr({eta}{sup 5}-C{sub 5}H{sub 5}){sub 3}({eta}{sup 1}-C{sub 5}H{sub 5}) and Sn({eta}{sup 1}-C{sub 5}H{sub 5}){sub 4}. This work was undertaken in the hope of gaining insight into the intramolecuhrr dynamics, specifically which fluxional processes exist in the solid state, by what mechanism rearrangements are occurring, and the activation energies by which these processes are governed.

Ziegeweid, M.A.

1995-11-29T23:59:59.000Z

384

A Simple Approach for Obtaining High Resolution, High Sensitivity H NMR Metabolite Spectra of Biofluids with Limited Mass Supply  

SciTech Connect (OSTI)

A simple approach is reported that yields high resolution, high sensitivity H NMR spectra of biofluids with limited mass supply. This is achieved by spinning a capillary sample tube containing a biofluid at the magic angle at a frequency of about 80Hz. A 2D pulse sequence called H PASS is then used to produce a high-resolution H NMR spectrum that is free from magnetic susceptibility induced line broadening. With this new approach a high resolution H NMR spectrum of biofluids with a volume less than 1.0 l can be easily achieved at a magnetic field strength as low as 7.05T. Furthermore, the methodology facilitates easy sample handling, i.e., the samples can be directly collected into inexpensive and disposable capillary tubes at the site of collection and subsequently used for NMR measurements. In addition, slow magic angle spinning improves magnetic field shimming and is especially suitable for high throughput investigations. In this paper first results are shown obtained in a magnetic field of 7.05T on urine samples collected from mice using a modified commercial NMR probe.

Hu, Jian Zhi; Rommereim, Donald N.; Wind, Robert A.; Minard, Kevin R.; Sears, Jesse A.

2006-11-01T23:59:59.000Z

385

Resonance expansions of propagators in the presence of potential ...  

E-Print Network [OSTI]

We consider energy levels at which there exists a potential barrier separating the ...... dynamics and nuclear magnetic resonance signals, J. Chem. Phys.

386

First Principles Calculations and NMR Spectroscopy of Electrode...  

Broader source: Energy.gov (indexed) [DOE]

nanoparticles. On schedule; (PDF and NMR data collected analysis ongoing) * Use solid-state NMR and diffraction based methods to characterize short, intermediate and longer-range...

387

A Solution NMR Investigation into the Early Events of Amelogenin...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solution NMR Investigation into the Early Events of Amelogenin Nanosphere Self-Assembly Initiated with Sodium Chloride or A Solution NMR Investigation into the Early Events of...

388

A solution NMR investigation into the impaired self-assembly...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

solution NMR investigation into the impaired self-assembly properties of two murine amelogenins containing the point mutations A solution NMR investigation into the impaired...

389

Improving NMR Protein Structure Quality by Rosetta Refinement...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NMR Protein Structure Quality by Rosetta Refinement: A Molecular Replacement Study. Improving NMR Protein Structure Quality by Rosetta Refinement: A Molecular Replacement Study....

390

A NMR-Based Carbon-Type Analysis of Diesel Fuel Blends From Various Sources  

SciTech Connect (OSTI)

In collaboration with participants of the Coordinating Research Council (CRC) Advanced Vehicle/Fuels/Lubricants (AVFL) Committee, and project AVFL-19, the characteristics of fuels from advanced and renewable sources were compared to commercial diesel fuels. The main objective of this study was to highlight similarities and differences among the fuel types, i.e. ULSD, renewables, and alternative fuels, and among fuels within the different fuel types. This report summarizes the carbon-type analysis from 1H and 13C{1H} nuclear magnetic resonance spectroscopy (NMR) of 14 diesel fuel samples. The diesel fuel samples come from diverse sources and include four commercial ultra-low sulfur diesel fuels (ULSD), one gas-to-liquid diesel fuel (GTL), six renewable diesel fuels (RD), two shale oil-derived diesel fuels, and one oil sands-derived diesel fuel. Overall, the fuels examined fall into two groups. The two shale oil-derived samples and the oil-sand-derived sample closely resemble the four commercial ultra-low sulfur diesels, with SO1 and SO2 most closely matched with ULSD1, ULSD2, and ULSD4, and OS1 most closely matched with ULSD3. As might be expected, the renewable diesel fuels, with the exception of RD3, do not resemble the ULSD fuels because of their very low aromatic content, but more closely resemble the gas-to-liquid sample (GTL) in this respect. RD3 is significantly different from the other renewable diesel fuels in that the aromatic content more closely resembles the ULSD fuels. Fused-ring aromatics are readily observable in the ULSD, SO, and OS samples, as well as RD3, and are noticeably absent in the remaining RD and GTL fuels. Finally, ULSD3 differs from the other ULSD fuels by having a significantly lower aromatic carbon content and higher cycloparaffinic carbon content. In addition to providing important comparative compositional information regarding the various diesel fuels, this report also provides important information about the capabilities of NMR spectroscopy for the detailed characterization and comparison of fuels and fuel blends.

Bays, J. Timothy; King, David L.

2013-05-10T23:59:59.000Z

391

Multiple resonant railgun power supply  

DOE Patents [OSTI]

A multiple repetitive resonant railgun power supply provides energy for repetitively propelling projectiles from a pair of parallel rails. A plurality of serially connected paired parallel rails are powered by similar power supplies. Each supply comprises an energy storage capacitor, a storage inductor to form a resonant circuit with the energy storage capacitor and a magnetic switch to transfer energy between the resonant circuit and the pair of parallel rails for the propelling of projectiles. The multiple serial operation permits relatively small energy components to deliver overall relatively large amounts of energy to the projectiles being propelled.

Honig, E.M.; Nunnally, W.C.

1985-06-19T23:59:59.000Z

392

High-resolution NMR process analyzer for oxygenates in gasoline  

SciTech Connect (OSTI)

We report a high-resolution 42-MHz[sup 1]HFT-NMR instrument that is suitable for use as a process analyzer and demonstrate its use in the determination of methyl tert-butyl ether (MTBE) in a flowing stream of gasoline. This spectrometer is based on a 55-kg permanent magnet with essentially no fringe field. A spectral resolution of 3 Hz was typically obtained for spinning samples, and this performance was only slightly degraded with flowing samples. We report a procedure for magnet drift compensation using a software procedure rather than a field-frequency lock channel. This procedure allowed signal averaging without loss of resolution. Regulatory changes to be implemented in the near future have created a need for the development of methods for the determination of MTBE and other oxygenates in reformulated gasolines. Existing methods employing gas chromatography are not fast enough for process control of a gasoline blender and suffer from other limitations. This study demonstrates that process analysis NMR is well-suited to the determination of MTBE in a simulated gasoline blender. The detection limit of 0.5 vol % MTBE was obtained with a measurement time of 1 min. The absolute standard deviation of independent determinations was 0.17% when the MTBE concentration was 10%, a nominal value. Preliminary results also suggest that the method may be applicable to gasolines containing mixtures of oxygenate additives as well as the measurement of aromatic and olefinic hydrogens. 33 refs., 9 figs.

Skloss, T.W.; Kim, A.J.; Haw, J.F. (Texas A M Univ., College Station, TX (United States))

1994-02-15T23:59:59.000Z

393

Resonant-cavity antenna for plasma heating  

DOE Patents [OSTI]

This invention relates generally to a method and apparatus for transferring energy to a plasma immersed in a magnetic field, and relates particularly to an apparatus for heating a plasma of low atomic number ions to high temperatures by transfer of energy to plasma resonances, particularly the fundamental and harmonics of the ion cyclotron frequency of the plasma ions. This invention transfers energy from an oscillating radio-frequency field to a plasma resonance of a plasma immersed in a magnetic field.

Perkins, F.W. Jr.; Chiu, S.C.; Parks, P.; Rawls, J.M.

1984-01-10T23:59:59.000Z

394

STRUCTUREu DITERPENE ELUCIDATION FROM 1 3 C NMR  

E-Print Network [OSTI]

in natural product chemistry. There are many useful spectroscopic methods of getting information about pro- ducts chemistry. NMR spectroscopy is the best method for complete structure elucidation products (not proteins), only 1 H NMR and 1 3 C NMR spectroscopy, including combined methods such as 2D NMR

Dzeroski, Saso

395

Transport and magnetic properties of rtx and related  

E-Print Network [OSTI]

Physical properties of RTX compounds (R = Rare earth, T = Transition metal and X = main group element from B, C or N group) compounds have been studied by means of electrical resistivity, heat capacity, dc magnetization and NMR. Searching for new...

Goruganti, Venkat

2009-05-15T23:59:59.000Z

396

Measurements of magnetic field alignment  

SciTech Connect (OSTI)

The procedure for installing Superconducting Super Collider (SSC) dipoles in their respective cryostats involves aligning the average direction of their field with the vertical to an accuracy of 0.5 mrad. The equipment developed for carrying on these measurements is described and the measurements performed on the first few prototypes SSC magnets are presented. The field angle as a function of position in these 16.6 m long magnets is a characteristic of the individual magnet with possible feedback information to its manufacturing procedure. A comparison of this vertical alignment characteristic with a magnetic field intensity (by NMR) characteristic for one of the prototypes is also presented. 5 refs., 7 figs.

Kuchnir, M.; Schmidt, E.E.

1987-11-06T23:59:59.000Z

397

Frontiers of NMR in Molecular Biology  

SciTech Connect (OSTI)

NMR spectroscopy is expanding the horizons of structural biology by determining the structures and describing the dynamics of blobular proteins in aqueous solution, as well as other classes of proteins including membrane proteins and the polypeptides that form the aggregates diagnostic of prion and amyloid diseases. Significant results are also emerging on DNA and RNA oligomers and their complexes with proteins. This meeting focused attention on key structural questions emanating from molecular biology and how NMR spectroscopy can be used to answer them.

NONE

1999-08-25T23:59:59.000Z

398

Linear dichroism and resonant photoemission in Gd 011  

SciTech Connect (OSTI)

Magnetic Linear Dichroism in Angular Distributions (MLDAD) from Photoelectron Emission was used to probe the nature of Resonant Photoemission. Gd 5p and Gd 4f emission were investigated. Using novel theoretical simulations, we were able to show that temporal matching is a requirement for ``True`` Resonant Photoemission, where the Resonant Photoemission retains the characteristics of Photoelectron Emission.

Mishra, S.R.; Cummins, T.R.; Gammon, W.J.; van der Laan, G.; Goodman, K.W.; Tobin, J.G.

1998-05-13T23:59:59.000Z

399

Stability of the electron cyclotron resonance  

E-Print Network [OSTI]

We consider the magnetic AC Stark effect for the quantum dynamics of a single particle in the plane under the influence of an oscillating homogeneous electric and a constant perpendicular magnetic field. We prove that the electron cyclotron resonance is insensitive to impurity potentials.

Joachim Asch; Olivier Bourget; Cdric Meresse

2014-12-30T23:59:59.000Z

400

Hepatic lipid profiling of deer mice fed ethanol using {sup 1}H and {sup 31}P NMR spectroscopy: A dose-dependent subchronic study  

SciTech Connect (OSTI)

Chronic alcohol abuse is a 2nd major cause of liver disease resulting in significant morbidity and mortality. Alcoholic liver disease (ALD) is characterized by a wide spectrum of pathologies starting from fat accumulation (steatosis) in early reversible stage to inflammation with or without fibrosis and cirrhosis in later irreversible stages. Previously, we reported significant steatosis in the livers of hepatic alcohol dehydrogenase (ADH)-deficient (ADH{sup ?}) vs. hepatic ADH-normal (ADH{sup +}) deer mice fed 4% ethanol daily for 2 months [Bhopale et al., 2006, Alcohol 39, 179188]. However, ADH{sup ?} deer mice fed 4% ethanol also showed a significant mortality. Therefore, a dose-dependent study was conducted to understand the mechanism and identify lipid(s) involved in the development of ethanol-induced fatty liver. ADH{sup ?} and ADH{sup +} deer mice fed 1, 2 or 3.5% ethanol daily for 2 months and fatty infiltration in the livers were evaluated by histology and by measuring dry weights of extracted lipids. Lipid metabolomic changes in extracted lipids were determined by proton ({sup 1}H) and {sup 31}phosphorus ({sup 31}P) nuclear magnetic resonance (NMR) spectroscopy. The NMR data was analyzed by hierarchical clustering (HC) and principle component analysis (PCA) for pattern recognition. Extensive vacuolization by histology and significantly increased dry weights of total lipids found only in the livers of ADH{sup ?} deer mice fed 3.5% ethanol vs. pair-fed controls suggest a dose-dependent formation of fatty liver in ADH{sup ?} deer mouse model. Analysis of NMR data of ADH{sup ?} deer mice fed 3.5% ethanol vs. pair-fed controls shows increases for total cholesterol, esterified cholesterol, fatty acid methyl esters (FAMEs), triacylglycerides and unsaturation, and decreases for free cholesterol, phospholipids and allylic and diallylic protons. Certain classes of neutral lipids (cholesterol esters, fatty acyl chain (-COCH{sub 2}-) and FAMEs) were also mildly increased in ADH{sup ?} deer mice fed 1 or 2% ethanol. Only small increases were observed for allylic and diallylic protons, FAMEs and unsaturations in ADH{sup +} deer mice fed 3.5% ethanol vs. pair-fed controls. PCA of NMR data showed increased clustering by gradual separation of ethanol-fed ADH{sup ?} deer mice groups from their respective pair-fed control groups and corresponding ethanol-fed ADH{sup +} deer mice groups. Our data indicate that dose of ethanol and hepatic ADH deficiency are two key factors involved in initiation and progression of alcoholic fatty liver disease. Further studies on characterization of individual lipid entities and associated metabolic pathways altered in our deer mouse model after different durations of ethanol feeding could be important to delineate mechanism(s) and identify potential biomarker candidate(s) of early stage ALD. -- Highlights: ? Dose-dependent ethanol-induced fatty liver was studied in deer mouse model. ? A NMR-based lipidomic approach with histology and dry lipid weights was used. ? We used principal component analysis (PCA) to analyze the NMR lipidomic data. ? Dose-dependent clustering patterns by PCA were compared among the groups.

Fernando, Harshica; Bhopale, Kamlesh K.; Boor, Paul J.; Ansari, G.A. Shakeel; Kaphalia, Bhupendra S., E-mail: bkaphali@utmb.edu

2012-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Instrument for in-situ orientation of superconducting thin-film resonators used for electron-spin resonance experiments  

E-Print Network [OSTI]

When used in Electron-Spin Resonance (ESR) measurements, superconducting thin-film resonators must be precisely oriented relative to the external magnetic field in order to prevent the trapping of magnetic flux and the associated degradation of resonator performance. We present a compact design solution for this problem that allows in-situ control of the orientation of the resonator at cryogenic temperatures. Tests of the apparatus show that when proper alignment is achieved, there is almost no hysteresis in the field dependence of the resonant frequency.

Mowry, Andrew; Kuabsek, James; Friedman, Jonathan R

2015-01-01T23:59:59.000Z

402

Granular Matter (2007) 9:331335 DOI 10.1007/s10035-007-0045-3  

E-Print Network [OSTI]

magnetic resonance (NMR) experim- ents are described for gas-fluidized granular beds, which are important Fluidized bed NMR Hyperpolarized gas 1 Introduction Nuclear magnetic resonance (NMR) enables noninvasive systems for many materials-processing operations. Using pulsed field gradient, magnetic resonance imaging

Walsworth, Ronald L.

2007-01-01T23:59:59.000Z

403

Resonance conditions  

E-Print Network [OSTI]

Non-linear parametric resonances occur frequently in nature. Here we summarize how they can be studied by means of perturbative methods. We show in particular how resonances can affect the motion of a test particle orbiting in the vicinity of a compact object. These mathematical toy-models find application in explaining the structure of the observed kHz Quasi-Periodic Oscillations: we discuss which aspects of the reality naturally enter in the theory, and which one still remain a puzzle.

P. Rebusco

2005-10-14T23:59:59.000Z

404

The use of a permanent magnet for water content measurements ofwood chips  

SciTech Connect (OSTI)

The Lawrence Berkeley National Laboratory has developed a device that measures the water content of wood chips, pulp and brown stock for the paper industry. This device employs a permanent magnet as the central part of a NMR measurement system. This report describes the magnet and the NMR measurement system. The results of water content measurements in wood chips in a magnetic field of 0.47 T are presented.

Barale, P.J.; Fong, C.G.; Green, M.A.; Luft, P.A.; McInturff,A.D.; Reimer, J.A.; Yahnke, M.

2001-09-20T23:59:59.000Z

405

Tumor Metabolism and Perfusion in Head and Neck Squamous Cell Carcinoma: Pretreatment Multimodality Imaging With {sup 1}H Magnetic Resonance Spectroscopy, Dynamic Contrast-Enhanced MRI, and [{sup 18}F]FDG-PET  

SciTech Connect (OSTI)

Purpose: To correlate proton magnetic resonance spectroscopy ({sup 1}H-MRS), dynamic contrast-enhanced magnetic resonance imaging (DCE-MRI), and {sup 18}F-labeled fluorodeoxyglucose positron emission tomography ([{sup 18}F]FDG PET) of nodal metastases in patients with head and neck squamous cell carcinoma (HNSCC) for assessment of tumor biology. Additionally, pretreatment multimodality imaging was evaluated for its efficacy in predicting short-term response to treatment. Methods and Materials: Metastatic neck nodes were imaged with {sup 1}H-MRS, DCE-MRI, and [{sup 18}F]FDG PET in 16 patients with newly diagnosed HNSCC, before treatment. Short-term patient radiological response was evaluated at 3 to 4 months. Correlations among {sup 1}H-MRS (choline concentration relative to water [Cho/W]), DCE-MRI (volume transfer constant [K{sup trans}]; volume fraction of the extravascular extracellular space [v{sub e}]; and redistribution rate constant [k{sub ep}]), and [{sup 18}F]FDG PET (standard uptake value [SUV] and total lesion glycolysis [TLG]) were calculated using nonparametric Spearman rank correlation. To predict short-term responses, logistic regression analysis was performed. Results: A significant positive correlation was found between Cho/W and TLG ({rho} = 0.599; p = 0.031). Cho/W correlated negatively with heterogeneity measures of standard deviation std(v{sub e}) ({rho} = -0.691; p = 0.004) and std(k{sub ep}) ({rho} = -0.704; p = 0.003). Maximum SUV (SUVmax) values correlated strongly with MRI tumor volume ({rho} = 0.643; p = 0.007). Logistic regression indicated that std(K{sup trans}) and SUVmean were significant predictors of short-term response (p < 0.07). Conclusion: Pretreatment multimodality imaging using {sup 1}H-MRS, DCE-MRI, and [{sup 18}F]FDG PET is feasible in HNSCC patients with nodal metastases. Additionally, combined DCE-MRI and [{sup 18}F]FDG PET parameters were predictive of short-term response to treatment.

Jansen, Jacobus F.A. [Department of Medical Physics, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Department of Radiology, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Department of Radiology, Maastricht University Medical Center, Maastricht (Netherlands); Schoeder, Heiko [Department of Radiology, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Lee, Nancy Y. [Department of Radiation Oncology, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Stambuk, Hilda E. [Department of Radiology, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Wang Ya [Department of Medical Physics, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Fury, Matthew G. [Department of Medical Oncology, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Patel, Senehal G. [Department of Surgery, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Pfister, David G. [Department of Medical Oncology, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Shah, Jatin P. [Department of Surgery, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Koutcher, Jason A. [Department of Medical Physics, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Department of Radiology, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Department of Medical Oncology, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Shukla-Dave, Amita, E-mail: davea@mskcc.org [Department of Medical Physics, Memorial Sloan-Kettering Cancer Center, New York, New York (United States); Department of Radiology, Memorial Sloan-Kettering Cancer Center, New York, New York (United States)

2012-01-01T23:59:59.000Z

406

High-precision evaluation of the magnetic moment of the helion  

SciTech Connect (OSTI)

NMR spectra of samples containing a mixture of hydrogen deuteride HD with pressure of about 80 atm and helium-3 with partial pressure of about 1 atm are analyzed. The ratio of the resonance frequencies of the nuclei, F({sup 3}He)/F(H{sub 2}), is determined to be 0.761786594(2), which is equal to the magnetic moment of the helion (bound in a helium atom) in the units of the magnetic moment of a proton (bound in molecular hydrogen). The uncertainty of two digits in the last place corresponds to a relative error of {delta}[F({sup 3}He)/F(H{sub 2})] = 2.6 Multiplication-Sign 10{sup -9}. The use of the known calculated data on the shielding of nuclei in the helium-3 atom ({sigma}({sup 3}He) = 59924(2) Multiplication-Sign 10{sup -9}) and on the shielding of protons in hydrogen ({sigma}(H{sub 2}) = 26288(2) Multiplication-Sign 10{sup -9}) yields a value of {mu}({sup 3}He)/{mu}{sub p} = -0.761812217(3) for the free magnetic moment of the helion in the units of the proton magnetic moment.

Neronov, Yu. I., E-mail: yineronov@mail.ru; Seregin, N. N. [Mendeleev All-Russia Research Institute of Metrology (Russian Federation)

2012-11-15T23:59:59.000Z

407

Measuring and shimming the magnetic field of a 4 Tesla MRI magnet  

E-Print Network [OSTI]

The Biomedical Magnetic Resonance Laboratory (BMRL) of the University of Illinois at Urbana-Champaign (UIUC) has ordered from the Texas Accelerator Center (TAC) a superconducting, self-shielded, solenoidal magnet with a maximum field of 4 Tesla...

Kyriazis, Georgios

2012-06-07T23:59:59.000Z

408

Structure and Dynamics of Biological Macromolecules using NMR Spectroscopy  

E-Print Network [OSTI]

However, in the solid sate NMR work discussed in thisthe contribution of this work to solid state NMR in solvingtwo distinct works are presented in both solid sate and

Tian, Ye

2010-01-01T23:59:59.000Z

409

Solid State NMR Studies of Li-Rich NMC Cathodes: Investigating...  

Broader source: Energy.gov (indexed) [DOE]

in dQdV plots center of mass of Li shifts in NMR spectra shift to lower frequencies. 2.0 2.5 3.0 3.5 4.0 4.5 dQdV Voltage NMR11 Cycle 2 NMR14 Cycle 11 NMR 14 NMR 11 NMR 15...

410

Framework Stability of Nanocrystalline NaY in Aqueous Solution...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(solid state nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR)) will be used to elucidate the structure and reactivity of nanocrystalline zeolites...

411

Solid-state NMR imaging system  

DOE Patents [OSTI]

An apparatus for use with a solid-state NMR spectrometer includes a special imaging probe with linear, high-field strength gradient fields and high-power broadband RF coils using a back projection method for data acquisition and image reconstruction, and a real-time pulse programmer adaptable for use by a conventional computer for complex high speed pulse sequences.

Gopalsami, Nachappa (Naperville, IL); Dieckman, Stephen L. (Elmhurst, IL); Ellingson, William A. (Naperville, IL)

1992-01-01T23:59:59.000Z

412

Negative compressibility observed in graphene containing resonant impurities  

SciTech Connect (OSTI)

We observed negative compressibility in monolayer graphene containing resonant impurities under different magnetic fields. Hydrogenous impurities were introduced into graphene by electron beam (e-beam) irradiation. Resonant states located in the energy region of {+-}0.04 eV around the charge neutrality point were probed in e-beam-irradiated graphene capacitors. Theoretical results based on tight-binding and Lifshitz models agreed well with experimental observations of graphene containing a low concentration of resonant impurities. The interaction between resonant states and Landau levels was detected by varying the applied magnetic field. The interaction mechanisms and enhancement of the negative compressibility in disordered graphene are discussed.

Chen, X. L.; Wang, L.; Li, W.; Wang, Y.; He, Y. H.; Wu, Z. F.; Han, Y.; Zhang, M. W.; Xiong, W.; Wang, N. [Department of Physics and The William Mong Institute of Nano Science and Technology, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong (China)] [Department of Physics and The William Mong Institute of Nano Science and Technology, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong (China)

2013-05-20T23:59:59.000Z

413

Nonlinear coupling of nano mechanical resonators to Josephson quantum circuits  

E-Print Network [OSTI]

We propose a technique to couple the position operator of a nano mechanical resonator to a SQUID device by modulating its magnetic flux bias. By tuning the magnetic field properly, either linear or quadratic couplings can be realized, with a discretely adjustable coupling strength. This provides a way to realize coherent nonlinear effects in a nano mechanical resonator by coupling it to a Josephson quantum circuit. As an example, we show how squeezing of the nano mechanical resonator state can be realized with this technique. We also propose a simple method to measure the uncertainty in the position of the nano mechanical resonator without quantum state tomography.

Xingxiang Zhou; Ari Mizel

2006-05-01T23:59:59.000Z

414

Fluid-Rock Characterization and Interactions in NMR Well Logging  

SciTech Connect (OSTI)

The objective of this project is to characterize the fluid properties and fluid-rock interactions that are needed for formation evaluation by NMR well logging. This is the first annual progress report submitted to the DOE. It reports on the work completed during the reporting period even if it may have started before this period. This project is a partnership between Professor George J. Hirasaki at Rice University and Professor Kishore Mohanty at University of Houston. In addition to the DOE, this project is supported by a consortium of oil companies and service companies. The fluid properties characterization has emphasized the departure of live oils from correlations based on dead oils. Also, asphaltic components can result in a difference between the T1 and T2 relaxation time distributions as well as reduce the hydrogen index. The fluid rock characterizations that are reported here are the effects of wettability and internal magnetic field gradients. A pore reconstruction method ha s been developed to recreate three-dimensional porous media from two-dimensional images that reproduce some of their key statistical properties. A Monte Carlo simulation technique has been developed to calculate the magnetization decay in fluid saturated porous media given their pore structure.

Hirasaki, George J.; Mohanty, Kishore, K.

2001-07-13T23:59:59.000Z

415

Resonant-cavity antenna for plasma heating  

DOE Patents [OSTI]

Disclosed is a resonant coil cavity wave launcher for energizing a plasma immersed in a magnetic field. Energization includes launching fast Alfven waves to excite ion cyclotron frequency resonances in the plasma. The cavity includes inductive and capacitive reactive members spaced no further than one-quarter wavelength from a first wall confinement chamber of the plasma. The cavity wave launcher is energized by connection to a waveguide or transmission line carrying forward power from a remote radio frequency energy source.

Perkins, Jr., Francis W. (Princeton, NJ); Chiu, Shiu-Chu (San Diego, CA); Parks, Paul (San Diego, CA); Rawls, John M. (Del Mar, CA)

1987-01-01T23:59:59.000Z

416

Applications of highly spin-polarized xenon in NMR  

SciTech Connect (OSTI)

The main goal of the work presented in this thesis is produce highly spin-polarized xenon to create much greater signal intensities (up to 54,000 times greater) so as to allow studies to be made on systems with low surface area and long spin-lattice relaxation times. The spin-exchange optical pumping technique used to create high nuclear spin polarization is described in detail in chapter two. This technique is initially applied to some multiple-pulse optically detected NMR experiments in low magnetic field (50G) that allow the study of quadrupoler interactions with a surface of only a few square centimeters. In chapter three the apparatus used to allow high field {sup 129}Xe NMR studies to be performed with extremely high sensitivity is described and applied to experiments on diamagnetic susceptibility effects in thin ({approximately}2000 layers) films of frozen xenon. Preliminary surface investigations of laser polarized {sup 129}Xe adsorbed an a variety of materials (salts, molecular crystals, amorphous carbon, graphite) are then discussed. A full detailed study of the surface of a particular polymer, poly(acrylic acid), is presented in chapter four which shows the kind of detailed information that can be obtained from this technique. Along with preliminary results for several similar polymers, a summary is given of xenon studies of a novel ultra-high surface area polymer, poly(triarylcarbinol). Finally in chapter five the exciting possibility of transferring the high spin order of the laser polarized xenon has been used to transfer nuclear spin order to {sup 13}CO{sub 2} in a xenon matrix and to protons on poly(triarylcarbinol).

Long, H.W. [Univ. of California, Berkeley, CA (United States). Dept. of Chemistry; [Lawrence Berkeley Lab., CA (United States)

1993-09-01T23:59:59.000Z

417

AN ASSESSMENT OF THE ACCURACY OF MAGENTIC RESONANCE PHASE VELOCITY MAPPING IN TURBULENT FLOW THROUGH ORIFICES.  

E-Print Network [OSTI]

?? Magnetic resonance phase velocity mapping (MRPVM) is an established clinical technique to measure blood flow. The acquired information can be used to diagnose a (more)

Pidaparthi, Sahitya

2011-01-01T23:59:59.000Z

418

Cyclotron resonance in plasma flow  

SciTech Connect (OSTI)

This paper is devoted to the mechanism of particle acceleration via resonant interaction with the electromagnetic circular wave propagating along the inhomogeneous background magnetic field in the presence of a plasma flow. We consider the system where the plasma flow velocity is large enough to change the direction of wave propagation in the rest frame. This system mimics a magnetic field configuration typical for inner structure of a quasi-parallel shock wave. We consider conditions of gyroresonant interaction when the force corresponding to an inhomogeneity of the background magnetic field is compensated by the Lorentz force of the wave-magnetic field. The wave-amplitude is assumed to be about 10% of the background magnetic field. We show that particles can gain energy if kv{sub sw}>?>kv{sub sw}??{sub c} where k is the wave number, v{sub sw} is a plasma flow velocity, and ? and ?{sub c} are the wave frequency and the particle gyrofrequency, respectively. This mechanism of acceleration resembles the gyrosurfing mechanism, but the effect of the electrostatic field is replaced by the effect of the magnetic field inhomogeneity.

Artemyev, A. V.; Agapitov, O. V.; Krasnoselskikh, V. V. [LPC2E/CNRS-University of Orleans, Orleans (France)] [LPC2E/CNRS-University of Orleans, Orleans (France)

2013-12-15T23:59:59.000Z

419

Regenerative feedback resonant circuit  

DOE Patents [OSTI]

A regenerative feedback resonant circuit for measuring a transient response in a loop is disclosed. The circuit includes an amplifier for generating a signal in the loop. The circuit further includes a resonator having a resonant cavity and a material located within the cavity. The signal sent into the resonator produces a resonant frequency. A variation of the resonant frequency due to perturbations in electromagnetic properties of the material is measured.

Jones, A. Mark; Kelly, James F.; McCloy, John S.; McMakin, Douglas L.

2014-09-02T23:59:59.000Z

420

Radio-frequency quadrupole resonator for linear accelerator  

DOE Patents [OSTI]

An RFQ resonator for a linear accelerator having a reduced level of interfering modes and producing a quadrupole mode for focusing, bunching and accelerating beams of heavy charged particles, with the construction being characterized by four elongated resonating rods within a cylinder with the rods being alternately shorted and open electrically to the shell at common ends of the rods to provide an LC parallel resonant circuit when activated by a magnetic field transverse to the longitudinal axis.

Moretti, A.

1982-10-19T23:59:59.000Z

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Electric-dipole-induced spin resonance in disordered semiconductors  

E-Print Network [OSTI]

ARTICLES Electric-dipole-induced spin resonance in disordered semiconductors MATHIAS DUCKHEIM One of the hallmarks of spintronics is the control of magnetic moments by electric fields enabled in such structures is electric-dipole-induced spin resonance (EDSR), where the radio-frequency fields driving

Loss, Daniel

422

Catheter based magnetic resonance compatible perfusion probe  

E-Print Network [OSTI]

Neurosurgeons are using a thermal based technique to quantify brain perfusion. The thermal diffusion probe (TDP) technology measures perfusion in a relatively small volume of brain tissue. The neurosurgeon chooses the ...

Toretta, Cara Lynne

2007-01-01T23:59:59.000Z

423

Tissue oxymetry using magnetic resonance spectroscopy  

E-Print Network [OSTI]

A noninvasive method for in vivo measurement of tissue oxygen concentration has been developed. Several techniques currently used suffer limitations that prevent their practical clinical use. Our method is to use the ...

Liu, Lisa Chiawen

2005-01-01T23:59:59.000Z

424

SELECTIVITY IN MULTIPLE QUANTUM NUCLEAR MAGNETIC RESONANCE  

E-Print Network [OSTI]

27-0ct-19&2 13 :11:14 :l VAX-II FOF.TP.A~ a? l~' .FOjt.12o-:. -'''''--': 27-0ct-~9:,0 VAX- II rOfiTRA~ IV-? LUS Vl.3-193~ :.J (:;PI'.f'O';'.12 VAX-I! FO? ~~At, IV-PL1S V1.3-22

Warren, Warren Sloan.

2008-01-01T23:59:59.000Z

425

Portable low-cost magnetic resonance imaging  

E-Print Network [OSTI]

Purpose: As the premiere modality for brain imaging, MRI could find wider applicability if lightweight, portable systems were available for siting in unconventional locations such as intensive care units (ICUs), physician ...

Cooley, Clarissa Zimmerman

2014-01-01T23:59:59.000Z

426

Nuclear magnetic resonances in weak fields  

E-Print Network [OSTI]

' The snalInr 30. voltages necessary in this case would allow the use of parallel banks of batteries, which should increase the stability of the cux xwnt. Lf batteries are used as a ycwsr source, no. 6 wire should be a convenient siss for prodcci...&g fields uy to 106 gauss in a sole noid of the dinensions used here. Pour banks of batterissx each bank containing five batteries in serissx should pxxxvide ~te stabili RIGDIILATTOM FXELUi 'Ae two wain difficulties with the pxesent nodulation scheme...

Mitchell, Richard Warren

1953-01-01T23:59:59.000Z

427

Parallel magnetic resonance imaging: characterization and comparison  

E-Print Network [OSTI]

[Sodickson, 1997], GRAPPA [Griswold, 2002] and SPACE RIP [Kyriakos, 2000]; developed in the past decade have been studied, simulated and compared in this research. Because of the dependence of the parallel imaging methods on numerous factors such as receiver...

Rane, Swati Dnyandeo

2005-11-01T23:59:59.000Z

428

Magnetic Resonance Pulse Sequences for Fluorine-19  

E-Print Network [OSTI]

successful cell tracking and quantification of cells. The primary objective of this work was to enable the study of ^(19)F MRI on the Siemens MAGNETOM Verio scanner located at the Texas A&M Institute for Preclinical Studies (TIPS) facility at Texas A...

Terry, Robin

2014-07-11T23:59:59.000Z

429

SELECTIVITY IN MULTIPLE QUANTUM NUCLEAR MAGNETIC RESONANCE  

E-Print Network [OSTI]

D. Wemmer, J. Tang and S. Sinton, Bull. Am. Phys. Soc.G. Drobny, A. Pines, S. Sinton, D. Weitekamp, and D. Wemmer,Perkin II 1541 (1975). S. Sinton and A. Pines, Chem. Phys.

Warren, Warren Sloan.

2008-01-01T23:59:59.000Z

430

Magnetic Resonance Facility (Fact Sheet), National Bioenergy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

scientists to run their own liquid sample analysis * Solid-state analysis of biomass feedstocks, biomass- related materials, and polymers * Analysis of compounds with...

431

Next Generation Magnetic Resonance Imaging Contrast Agents  

E-Print Network [OSTI]

E. A. ; MacRenaris, K. W. ; Parigi, G. ; Luchinat, C. ; Ho,R. ; Eckermann, A. L. ; Parigi, G. ; Luchinat, C. ; Meade,E. A. ; MacRenaris, K. W. ; Parigi, G. ; Luchinat, C. ; Ho,

Klemm, Piper Julia

2012-01-01T23:59:59.000Z

432

Plutonium less mysterious with nuclear magnetic resonance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar Home Design Passive SolarCenterYou are here:and Protein/RNAPitsPlutonium

433

Fluid-Rock Characterization and Interactions in NMR Well Logging  

SciTech Connect (OSTI)

The objective of this project was to characterize the fluid properties and fluid-rock interactions that are needed for formation evaluation by NMR well logging. The advances made in the understanding of NMR fluid properties are summarized in a chapter written for an AAPG book on NMR well logging. This includes live oils, viscous oils, natural gas mixtures, and the relation between relaxation time and diffusivity.

Hirasaki, George J.; Mohanty, Kishore K.

2003-02-10T23:59:59.000Z

434

The use of NMR techniques for the analysis of water in coal and the effect of different coal drying techniques on the structure and reactivity of coal. Final report  

SciTech Connect (OSTI)

Western Research Institute has conducted a study of different methods of coal drying as pretreatment steps before liquefaction. The objectives of this study were to develop a combined chemical dehydration/nuclear magnetic resonance (NMR) method for measuring the moisture content of coal, to measure the changes in coal structure that occur during drying, and to determine the effects of different drying methods on liquefaction reactivity of coals. Different methods of drying were investigated to determine whether coal drying can be accomplished without reducing the reactivity of coals toward liquefaction. Drying methods included thermal, microwave, and chemical dehydration. Coals of rank lignite to high volatile bituminous were studied. Coals that were dried or partially dried thermally and with microwaves had lower liquefaction conversions than coals containing equilibrium moisture contents. However, chemically dried coals had conversions equal to or greater than the premoisturized coals. The conversion behavior is consistent with changes in the physical structure and cross linking reactions because of drying. Thermal and microwave drying appear to cause a collapse in the pore structure, thus preventing donor solvents such as tetralin from contacting reactive sites inside the coals. Chemical dehydration does not appear to collapse the pore structure. These results are supported by the solvent swelling measurements in which the swelling ratios of thermally dried and microwave-dried coals were lower than those of premoisturized coals, indicating a greater degree of cross linking in the dried coals. The swelling ratios of the chemically dried coals were greater than those of the premoisturized coals because the pore structure remaining unchanged or increased when water was removed. These results are consistent with the NMR results, which did not show significant changes in coal chemical structure.

Netzel, D.A.; Miknis, F.P.; Wallace, J.C. Jr.; Butcher, C.H.; Mitzel, J.M.; Turner, T.F.; Hurtubise, R.J.

1995-02-01T23:59:59.000Z

435

Theory and Applications of NMR Spectroscopy Arthur S. Edison  

E-Print Network [OSTI]

. Prerequisites: Graduate student or advanced undergraduate status, physical chemistry, organic chemistry Spectroscopy Week 1: Introduction to the basics: Bloch equations References: Most NMR books. These notes were

Collins, Gary S.

436

First Principles Calculations and NMR Spectroscopy of Electrode...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Calculations and NMR Spectroscopy of Electrode Materials 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

437

Studying Cellulose Fiber Structure by SEM, XRD, NMR and Acid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Studying Cellulose Fiber Structure by SEM, XRD, NMR and Acid Hydrolysis. Abstract: Cotton linters were partially hydrolyzed in dilute acid and the morphology of remaining...

438

Realization of a 5-bit NMR Quantum Computer Using a New Molecular Architecture  

E-Print Network [OSTI]

We demonstrate a five-bit nuclear-magnetic-resonance quantum computer that distinguishes among various functions on four bits, making use of quantum parallelism. Its construction draws on the recognition of the sufficiency of linear coupling along a chain of nuclear spins, the synthesis of a suitably coupled molecule, and the use of a multi-channel spectrometer.

R. Marx; A. F. Fahmy; J. M. Myers; W. Bermel; S. J. Glaser

1999-05-25T23:59:59.000Z

439

NMR, MRI, and spectroscopic MRI in inhomogeneous fields  

DOE Patents [OSTI]

A method for locally creating effectively homogeneous or "clean" magnetic field gradients (of high uniformity) for imaging (with NMR, MRI, or spectroscopic MRI) both in in-situ and ex-situ systems with high degrees of inhomogeneous field strength. THe method of imaging comprises: a) providing a functional approximation of an inhomogeneous static magnetic field strength B.sub.0({right arrow over (r)}) at a spatial position {right arrow over (r)}; b) providing a temporal functional approximation of {right arrow over (G)}.sub.shim(t) with i basis functions and j variables for each basis function, resulting in v.sub.ij variables; c) providing a measured value .OMEGA., which is an temporally accumulated dephasing due to the inhomogeneities of B.sub.0({right arrow over(r)}); and d) minimizing a difference in the local dephasing angle .phi.({right arrow over (r)},t)=.gamma..intg..sub.0.sup.t{square root over (|{right arrow over (B)}.sub.1({right arrow over (r)},t')|.sup.2+({right arrow over (r)}{right arrow over (G)}.sub.shimG.sub.shim(t')+.parallel.{right arrow over (B)}.sub.0({right arrow over (r)}).parallel..DELTA..omega.({right arrow over (r)},t'/.gamma/).sup.2)}dt'-.OMEGA. by varying the v.sub.ij variables to form a set of minimized v.sub.ij variables. The method requires calibration of the static fields prior to minimization, but may thereafter be implemented without such calibration, may be used in open or closed systems, and potentially portable systems.

Demas, Vasiliki; Pines, Alexander; Martin, Rachel W; Franck, John; Reimer, Jeffrey A

2013-12-24T23:59:59.000Z

440

RadEMSL: NMR Capabilities | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar HomePromising Science for1 20115, 2001DataGeothermalRadEMSL: NMR

Note: This page contains sample records for the topic "magnetic resonance nmr" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

300 MHz NMR Mazama (Solids) | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011 Mon, Next2025 PowerNetwork8th300 MHz NMR Mazama

442

800 MHz NMR Denali (Liquids) | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert SouthwestTechnologies |November 2011 Mon, Next2025Steps to MakingImportance800 MHz NMR

443

Ultra-low field NMR for detection and characterization of 235 UF6  

SciTech Connect (OSTI)

We have demonstrated the first ultra-low field (ULF) nuclear magnetic resonance measurements of uranium hexafluoride (UF{sub 6}), both depleted and 70% enriched, which is used in the uranium enrichment process. A sensitive non-invasive detection system would have an important role in non-proliferation surveillance. A two-frequency technique was employed to remove the transients induced by rapidly switching off the 50 mT pre-polarization field. A mean transverse relaxation time T{sub 2} of 24 ms was estimated for the un-enriched UF{sub 6} sample measured at a mean temperature of 80 C. Nuclear magnetic resonance at ULF has several advantages including the ability to measure through metal, such as pipes, and simple magnetic field generation hardware. We present here recent data and discuss the potential for non-proliferation monitoring of enrichment and flow velocity.

Espy, Michelle A [Los Alamos National Laboratory; Magnelind, Per E [Los Alamos National Laboratory; Matlashov, Andrei N [Los Alamos National Laboratory; Urbaitis, Algis V [Los Alamos National Laboratory; Volegov, Petr L [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

444

Fluid-Rock Characterization and Interactions in NMR Well Logging  

SciTech Connect (OSTI)

The objective of this report is to characterize the fluid properties and fluid-rock interactions that are needed for formation evaluation by NMR well logging. The advances made in the understanding of NMR fluid properties are summarized in a chapter written for an AAPG book on NMR well logging. This includes live oils, viscous oils, natural gas mixtures, and the relation between relaxation time and diffusivity. Oil based drilling fluids can have an adverse effect on NMR well logging if it alters the wettability of the formation. The effect of various surfactants on wettability and surface relaxivity are evaluated for silica sand. The relation between the relaxation time and diffusivity distinguishes the response of brine, oil, and gas in a NMR well log. A new NMR pulse sequence in the presence of a field gradient and a new inversion technique enables the T{sub 2} and diffusivity distributions to be displayed as a two-dimensional map. The objectives of pore morphology and rock characterization are to identify vug connectivity by using X-ray CT scan, and to improve NMR permeability correlation. Improved estimation of permeability from NMR response is possible by using estimated tortuosity as a parameter to interpolate between two existing permeability models.

George J. Hirasaki; Kishore K. Mohanty

2005-09-05T23:59:59.000Z

445

Probe for high resolution NMR with sample reorientation  

DOE Patents [OSTI]

An improved NMR probe and method are described which substantially improve the resolution of NMR measurements made on powdered or amorphous or otherwise orientationally disordered samples. The apparatus mechanically varies the orientation of the sample such that the time average of two or more sets of spherical harmonic functions are zero.

Pines, Alexander (Berkeley, CA); Samoson, Ago (Tallinn, SU)

1990-01-01T23:59:59.000Z

446

Probe for high resolution NMR with sample reorientation  

DOE Patents [OSTI]

An improved NMR probe and method are described which substantially improve the resolution of NMR measurements made on powdered or amorphous or otherwise orientationally disordered samples. The apparatus mechanically varies the orientation of the sample such that the time average of two or more sets of spherical harmonic functions are zero. 8 figs.

Pines, A.; Samoson, A.

1990-02-06T23:59:59.000Z

447

Nanomechanical resonance detector  

DOE Patents [OSTI]

An embodiment of a nanomechanical frequency detector includes a support structure and a plurality of elongated nanostructures coupled to the support structure. Each of the elongated nanostructures has a particular resonant frequency. The plurality of elongated nanostructures has a range of resonant frequencies. An embodiment of a method of identifying an object includes introducing the object to the nanomechanical resonance detector. A resonant response by at least one of the elongated nanostructures of the nanomechanical resonance detector indicates a vibrational mode of the object. An embodiment of a method of identifying a molecular species of the present invention includes introducing the molecular species to the nanomechanical resonance detector. A resonant response by at least one of the elongated nanostructures of the nanomechanical resonance detector indicates a vibrational mode of the molecular species.

Grossman, Jeffrey C; Zettl, Alexander K

2013-10-29T23:59:59.000Z

448

Local structures of polar wurtzites Zn1-xMgxO studied by raman and 67Zn/25Mg NMR spectroscopies and by total neutron scattering  

SciTech Connect (OSTI)

Research in the area of polar semiconductor heterostructures has been growing rapidly, driven in large part by interest in two-dimensional electron gas (2DEG) systems. 2DEGs are known to form at heterojunction interfaces that bear polarization gradients. They can display extremely high electron mobilities, especially at low temperatures, owing to spatial confinement of carrier motions. Recent reports of 2DEG behaviors in Ga{sub 1-x}Al{sub x}N/GaN and Zn{sub 1-x}Mg{sub x}O/ZnO heterostructures have great significance for the development of quantum Hall devices and novel high-electron-mobility transistors (HEMTs). 2DEG structures are usually designed by interfacing a polar semiconductor with its less or more polar alloys in an epitaxial manner. Since the quality of the 2DEG depends critically on interface perfection, as well as the polarization gradient at the heterojunction, understanding compositional and structural details of the parent and alloy semiconductors is an important component in 2DEG design and fabrication. Zn{sub 1-x}Mg{sub x}O/ZnO is one of the most promising heterostructure types for studies of 2DEGs, due to the large polarization of ZnO, the relatively small lattice mismatch, and the large conduction band offsets in the Zn{sub 1-x}Mg{sub x}O/ZnO heterointerface. Although 2DEG formation in Zn{sub 1-x}Mg{sub x}O/ZnO heterostructures have been researched for some time, a clear understanding of the alloy structure of Zn{sub 1-x}Mg{sub x}O is currently lacking. Here, we conduct a detailed and more precise study of the local structure of Zn{sub 1-x}Mg{sub x}O alloys using Raman and solid-state nuclear magnetic resonance (NMR), in conjunction with neutron diffraction techniques.

Proffen, Thomas E [Los Alamos National Laboratory; Kim, Yiung- Il [UCSB; Cadars, Sylvian [UCSB; Shayib, Ramzy [UCSB; Feigerle, Charles S [UNIV OF TENNESSEE; Chmelka, Bradley F [UCSB; Seshadri, Ram [UCSB

2008-01-01T23:59:59.000Z

449

MULTIPLE-QUANTUM NMR IN SOLIDS  

E-Print Network [OSTI]

and R.R. A. Pines, S. Sinton, S ymp. D.P. Weitekamp, Drobny,Reson. Drobny, D A. Pines, S. Sinton, S y mp R.L. D.P.A. Pines, Wemmer, S. Sinton, Symp. D. P . Chem. Weitekamp,

Yen, Y-S.

2010-01-01T23:59:59.000Z

450

Ovenized microelectromechanical system (MEMS) resonator  

DOE Patents [OSTI]

An ovenized micro-electro-mechanical system (MEMS) resonator including: a substantially thermally isolated mechanical resonator cavity; a mechanical oscillator coupled to the mechanical resonator cavity; and a heating element formed on the mechanical resonator cavity.

Olsson, Roy H; Wojciechowski, Kenneth; Kim, Bongsang

2014-03-11T23:59:59.000Z

451

Shape of the coherent-population-trapping resonances and high-rank polarization moments S. Gateva,* L. Petrov, E. Alipieva, and G. Todorov  

E-Print Network [OSTI]

magnetic resonances. The comparison of the theoretical and experimental shapes of the CPT resonances operation, a good knowledge of the internal and external factors influencing the resonance shape is re- quired 4 . The CPT resonance shape has been studied experimen- tally and theoretically in many works see

452

Dynamic nuclear polarization for NMR : applications and hardware development  

E-Print Network [OSTI]

solid State NMR (SSNMR) can determine molecular as well as supermolecular structure and dynamics. The low signal intensities make many of these experiments prohibitively long. Dynamic Nuclear Polarization provides a method ...

Casey, Andrew (Andrew Byron)

2008-01-01T23:59:59.000Z

453

Investigation of Zeolite Nucleation and Growth Using NMR Spectroscopy  

E-Print Network [OSTI]

and control of the zeolite properties. The primary objective of this dissertation is to determine the strength of organicinorganic interactions (i.e., the adsorption Gibbs energy) in transparent synthesis mixtures using PFG NMR spectroscopy, in order...

Rivas Cardona, Alejandra

2012-02-14T23:59:59.000Z

454

Consistent blind protein structure generation from NMR chemical shift data  

E-Print Network [OSTI]

Consistent blind protein structure generation from NMR chemical shift data Yang Shen*, Oliver Lange been successfully applied in a blind manner to nine protein targets with molecular masses up to 15.4 k

Baker, David

455

Gas phase 129Xe NMR imaging and spectroscopy  

E-Print Network [OSTI]

5 l l Dynamic NMR microscopy of gas phase Poiseuille flowmetal vapors and noble gases can be used to efficientlypolarize the nuclei ofthe noble-gas atoms. As a result, the

Kaiser, Lana G.

2010-01-01T23:59:59.000Z

456

First Principles Calculations and NMR Spectroscopy of Electrode...  

Broader source: Energy.gov (indexed) [DOE]

Ducati, S. Hofmann, C. P. Grey, Nature Communications, 5:3217 | DOI: 10.1038ncomms4217 (2014). "Following Function in Real Time: New NMR and MRI Methods for Studying Structure...

457

Cost Effective Open Geometry HTS MRI System amended to BSCCO 2212 Wire for High Field Magnets  

SciTech Connect (OSTI)

The original goal of this Phase II Superconductivity Partnership Initiative project was to build and operate a prototype Magnetic Resonance Imaging (MRI) system using high temperature superconductor (HTS) coils wound from continuously processed dip-coated BSCCO 2212 tape conductor. Using dip-coated tape, the plan was for MRI magnet coils to be wound to fit an established commercial open geometry, 0.2 Tesla permanent magnet system. New electronics and imaging software for a prototype higher field superconducting system would have added significantly to the cost. However, the use of the 0.2 T platform would allow the technical feasibility and the cost issues for HTS systems to be fully established. Also it would establish the energy efficiency and savings of HTS open MRI compared with resistive and permanent magnet systems. The commercial goal was an open geometry HTS MRI running at 0.5 T and 20 K. This low field open magnet was using resistive normal metal conductor and its heat loss was rather high around 15 kolwatts. It was expected that an HTS magnet would dissipate around 1 watt, significantly reduce power consumption. The SPI team assembled to achieve this goal was led by Oxford Instruments, Superconducting Technology (OST), who developed the method of producing commercial dip coated tape. Superconductive Components Inc. (SCI), a leading US supplier of HTS powders, supported the conductor optimization through powder optimization, scaling, and cost reduction. Oxford Magnet Technology (OMT), a joint venture between Oxford Instruments and Siemens and the worlds leading supplier of MRI magnet systems, was involved to design and build the HTS MRI magnet and cryogenics. Siemens Magnetic Resonance Division, a leading developer and supplier of complete MRI imaging systems, was expected to integrate the final system and perform imaging trials. The original MRI demonstration project was ended in July 2004 by mutual consent of Oxford Instruments and Siemens. Between the project start and that date a substantial shift in the MRI marketplace occurred, with rapid growth for systems at higher fields (1.5 T and above) and a consequent decline in the low field market (<1.0 T). While the project aim appeared technically attainable at that time, the conclusion was reached that the system and market economics do not warrant additional investment. The program was redirected to develop BSCCO 2212 multifilament wire development for high field superconducting magnets for NMR and other scientific research upon an agreement between DOE and Oxford Instruments, Superconducting Technology. The work t took place between September, 2004 and the project end in early 2006 was focused on 2212 multifilamentary wire. This report summarizes the technical achievements both in 2212 dip coated for an HTS MRI system and in BSCCO 2212 multifilamentary wire for high field magnets.

Kennth Marken

2006-08-11T23:59:59.000Z

458

Fluid-Rock Characterization and Interactions in NMR Well Logging  

SciTech Connect (OSTI)

The objective of this project was to characterize the fluid properties and fluid-rock interactions which are needed for formation evaluation by NMR well logging. NMR well logging is finding wide use in formation evaluation. The formation parameters commonly estimated were porosity, permeability, and capillary bound water. Special cases include estimation of oil viscosity, residual oil saturation, location of oil/water contact, and interpretation on whether the hydrocarbon is oil or gas.

Hirasaki, George J.; Mohanty, Kishore K.

2003-02-10T23:59:59.000Z

459

The study of methane adsorbed on porous silicon by NMR  

E-Print Network [OSTI]

THE STUDY OF METHANE ADSORBED ON POROUS SILICON BY NMR A Thesis by ADAM KAZIMIERZ CZERMAK Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August 1986... Major Subject: Physics THE STUDY OF METHANE ADSORBED ON POROUS SILICON BY NMR A Thesis by ADAM KAZIMIERZ CZERMAK Approved as to style and content by: e Wile . Kirk (Chairman of Committee) J eevak M. Par pi a (Member) Randall L. Geiger...

Czermak, Adam Kazimierz

1986-01-01T23:59:59.000Z

460

Quantitative NMR Analysis of Partially Substituted Biodiesel Glycerols  

SciTech Connect (OSTI)

Phosphitylation of hydroxyl groups in biodiesel samples with 2-chloro-4,4,5,5-tetramethyl-1,3,2-dioxaphospholane followed by 31P-NMR analysis provides a rapid quantitative analytical technique for the determination of substitution patterns on partially esterified glycerols. The unique 31P-NMR chemical shift data was established with a series mono and di-substituted fatty acid esters of glycerol and then utilized to characterize an industrial sample of partially processed biodiesel.

Nagy, M.; Alleman, T. L.; Dyer, T.; Ragauskas, A. J.

2009-01-01T23:59:59.000Z