National Library of Energy BETA

Sample records for magnesium oxide sa

  1. Tape casting of magnesium oxide.

    SciTech Connect (OSTI)

    Ayala, Alicia; Corral, Erica L.; Loehman, Ronald E.; Bencoe, Denise Nora; Reiterer, Markus; Shah, Raja A.

    2008-02-01

    A tape casting procedure for fabricating ceramic magnesium oxide tapes has been developed as a method to produce flat sheets of sintered MgO that are thin and porous. Thickness of single layer tapes is in the range of 200-400 {micro}m with corresponding surface roughness values in the range of 10-20 {micro}m as measured by laser profilometry. Development of the tape casting technique required optimization of pretreatment for the starting magnesium oxide (MgO) powder as well as a detailed study of the casting slurry preparation and subsequent heat treatments for sintering and final tape flattening. Milling time of the ceramic powder, plasticizer, and binder mixture was identified as a primary factor affecting surface morphology of the tapes. In general, longer milling times resulted in green tapes with a noticeably smoother surface. This work demonstrates that meticulous control of the entire tape casting operation is necessary to obtain high-quality MgO tapes.

  2. Nuclear reactor shield including magnesium oxide

    DOE Patents [OSTI]

    Rouse, Carl A. (Del Mar, CA); Simnad, Massoud T. (La Jolla, CA)

    1981-01-01

    An improvement in nuclear reactor shielding of a type used in reactor applications involving significant amounts of fast neutron flux, the reactor shielding including means providing structural support, neutron moderator material, neutron absorber material and other components as described below, wherein at least a portion of the neutron moderator material is magnesium in the form of magnesium oxide either alone or in combination with other moderator materials such as graphite and iron.

  3. Magnesium oxide inserts for the LECO Carbon Analyzer

    SciTech Connect (OSTI)

    Bagaasen, L.M.; Jensen, C.M.

    1991-01-16

    LECO carbon analysis of plutonium metal and plutonium oxide at the Rocky Flats Plant generates several hundred kilograms of high silica residues each year. The plutonium in these residues is difficult and expensive to recover using production dissolution processes. A magnesium oxide (MgO) insert has been developed that significantly lowers the plutonium recovery costs without adversely affecting accuracy of the carbon analysis.

  4. Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up...

    Office of Environmental Management (EM)

    for Lightweighting Materials Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis Scale-Up of Magnesium Production by Fully Stabilized Zirconia...

  5. Oxide Film and Porosity Defects in Magnesium Alloy AZ91

    SciTech Connect (OSTI)

    Wang, Liang [Mississippi State University (MSU); Rhee, Hongjoo [Mississippi State University (MSU); Felicelli, Sergio D. [Mississippi State University (MSU); Sabau, Adrian S [ORNL; Berry, John T. [Mississippi State University (MSU)

    2009-01-01

    Porosity is a major concern in the production of light metal parts. This work aims to identify some of the mechanisms of microporosity formation in magnesium alloy AZ91. Microstructure analysis was performed on several samples obtained from gravity-poured ingots in graphite plate molds. Temperature data during cooling was acquired with type K thermocouples at 60 Hz at three locations of each casting. The microstructure of samples extracted from the regions of measured temperature was then characterized with optical metallography. Tensile tests and conventional four point bend tests were also conducted on specimens cut from the cast plates. Scanning electron microscopy was then used to observe the microstructure on the fracture surface of the specimens. The results of this study revealed the existence of abundant oxide film defects, similar to those observed in aluminum alloys. Remnants of oxide films were detected on some pore surfaces, and folded oxides were observed in fracture surfaces indicating the presence of double oxides entrained during pouring.

  6. MAGNESIUM OXIDE AN ENGINEERED BARRIER 2009 EPA WIPP RECERTIFICATION FACT SHEET United States Environmental Protection Agency | Office of Air and Radiation (6608J) | June 2009

    E-Print Network [OSTI]

    MAGNESIUM OXIDE ­ AN ENGINEERED BARRIER 2009 EPA WIPP RECERTIFICATION FACT SHEET United States Environmental Protection Agency | Office of Air and Radiation (6608J) | June 2009 http://www.epa.gov/radiation/wipp/index.html MAGNESIUM OXIDE ­ AN ENGINEERED BARRIER Why is MgO Used At WIPP? The U.S. Department of Energy (DOE

  7. Method for production of magnesium

    DOE Patents [OSTI]

    Diaz, Alexander F. (Cambridge, MA); Howard, Jack B. (Winchester, MA); Modestino, Anthony J. (Hanson, MA); Peters, William A. (Lexington, MA)

    1998-01-01

    A continuous process for the production of elemental magnesium is described. Magnesium is made from magnesium oxide and a light hydrocarbon gas. In the process, a feed stream of the magnesium oxide and gas is continuously fed into a reaction zone. There the magnesium oxide and gas are reacted at a temperature of about 1400.degree. C. or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental magnesium. The product stream is continuously quenched after leaving the reaction zone, and the elemental magnesium is separated from other reaction products.

  8. Method for production of magnesium

    DOE Patents [OSTI]

    Diaz, A.F.; Howard, J.B.; Modestino, A.J.; Peters, W.A.

    1998-07-21

    A continuous process for the production of elemental magnesium is described. Magnesium is made from magnesium oxide and a light hydrocarbon gas. In the process, a feed stream of the magnesium oxide and gas is continuously fed into a reaction zone. There the magnesium oxide and gas are reacted at a temperature of about 1400 C or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental magnesium. The product stream is continuously quenched after leaving the reaction zone, and the elemental magnesium is separated from other reaction products. 12 figs.

  9. Pulse-height distributions of neutron and gamma rays from plutonium-oxide S.A. Pozzi a,, S.D. Clarke a

    E-Print Network [OSTI]

    Eustice, Ryan

    Pulse-height distributions of neutron and gamma rays from plutonium-oxide samples S.A. Pozzi a,Ã, S Digital data processing Plutonium oxide 252 Cf a b s t r a c t We present new results on neutron and gamma-ray pulse-height distributions (PHDs) measured with liquid scintillators from five plutonium-oxide samples

  10. Detection of the adsorption of water monolayers through the ion oscillation frequency in the magnesium oxide lattice by means of Low Energy Electron Diffraction

    E-Print Network [OSTI]

    Guevara-Bertsch, M; Chavarría-Sibaja, A; Avendaño, E; Araya-Pochet, J A; Herrera-Sancho, O A

    2015-01-01

    We investigate the variation of the oscillation frequency of the Mg$^{2+}$ and O$^{2-}$ ions in the magnesium oxide lattice due to the interactions of the surface with water monolayers by means of Low Energy Electron Diffraction. Our key result is a new technique to determine the adsorbate vibrations produced by the water monolayers on the surface lattice as a consequence of their change in the surface Debye temperature and its chemical shift. The latter was systematically investigated for different annealing times and for a constant external thermal perturbation in the range of 110-300 K in order to accomplish adsorption or desorption of water monolayers in the surface lattice.

  11. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

    2010-02-23

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  12. United States Environmental Protection Agency | Office of Radiation and Indoor Air (6608J) | EPA 402-F-07-010 | May 2007 WIPP: Planned Change Request for Magnesium Oxide (MgO)

    E-Print Network [OSTI]

    402-F-07-010 | May 2007 WIPP: Planned Change Request for Magnesium Oxide (MgO) The U.S. Department to the Waste Isolation Pilot Plant (WIPP). Specifically, DOE is requesting a reduction in the amount of MgO, an engineered barrier, to be placed within the WIPP repository. Background & Summary As part of EPA's WIPP

  13. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

    2012-04-10

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  14. Magnesium fluoride recovery method

    DOE Patents [OSTI]

    Gay, Richard L. (Canoga Park, CA); McKenzie, Donald E. (Woodland Hills, CA)

    1989-01-01

    A method of obtaining magnesium fluoride substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is contacted with an acid under certain prescribed conditions to produce a liquid product and a particulate solid product. The particulate solid product is separated from the liquid and treated at least two more times with acid to produce a solid residue consisting essentially of magnesium fluoride substantially free of uranium and having a residual radioactivity level of less than about 1000 pCi/gm. In accordance with a particularly preferred embodiment of the invention a catalyst and an oxidizing agent are used during the acid treatment and preferably the acid is sulfuric acid having a strength of about 1.0 Normal.

  15. Magnesium-phosphate-glass cements with ceramic-type properties

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.

    1982-09-23

    Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate, exhibits rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

  16. Magnesium phosphate glass cements with ceramic-type properties

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY); Kukacka, Lawrence E. (Port Jefferson, NY)

    1984-03-13

    Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate exhibiting rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

  17. Heterogeneous-phase reactions of nitrogen dioxide with vermiculite-supported magnesium oxide (as applied to the control of jet engine test cell emissions). Doctoral thesis

    SciTech Connect (OSTI)

    Kimm, L.T.

    1995-11-01

    Controlling nitrogen oxides (NOx) from a non-steady-state stationary source like a jet engine test cell (JETC) requires a method that is effective over a wide range of conditions. A heterogeneous, porous, high surface area sorbent material comprised of magnesium oxide powder attached to a vermiculite substrate has been commercially developed for this purpose. Data from extensive laboratory testing of this material in a packed-bed flow system are presented. NO2 removal efficiencies, kinetics, and proposed NO2 removal mechanisms over a range of representative JETC exhaust gas characteristics are described. Exhaust gas variables evaluated included: NO2 concentration, temperature, flow rate (retention time), oxygen content, and moisture content. Availability of water and oxygen were found to be important variables. It is probable that water is necessary for the conversion of MgO to Mg(OH)2, which is a more reactive compound having thermal stability over the range of temperatures evaluated. Gaseous oxygen serves to oxidize NO to NO2, the latter being more readily removed from the gas stream. The presence of oxygen also serves to offset thermal decomposition of NO2 or surface nitrite/nitrate. Effective `lifetime` and regenerability of the exposed sorbent material were also evaluated. NO2 removal efficiencies were found to greatly exceed those for NO, with a maximum value greater than 90 percent. The effective conversion of NO to NO2 is a crucial requirement for removal of the former. The reaction between NO2 and MgO-vermiculite is first-order with respect to NO2.

  18. Method for magnesium sulfate recovery

    DOE Patents [OSTI]

    Gay, R.L.; Grantham, L.F.

    1987-08-25

    A method is described for obtaining magnesium sulfate substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7,000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is then contacted with a concentrated sulfuric acid under certain prescribed conditions to produce a liquid product and a solid product. The particulate solid product and a minor amount of the liquid is then treated to produce a solid residue consisting essentially of magnesium sulfate substantially free of uranium and having a residual radioactivity level of less than 1,000 pCi/gm. In accordance with the preferred embodiment of the invention, a catalyst and an oxidizing agent are used during the initial acid treatment and a final solid residue has a radioactivity level of less than about 50 pCi/gm.

  19. Method for magnesium sulfate recovery

    DOE Patents [OSTI]

    Gay, Richard L. (Canoga Park, CA); Grantham, LeRoy F. (Calabasas, CA)

    1987-01-01

    A method of obtaining magnesium sulfate substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is then contacted with a concentrated sulfuric acid under certain prescribed conditions to produce a liquid product and a solid product. The particulate solid product and a minor amount of the liquid is then treated to produce a solid residue consisting essentially of magnesium sulfate substantially free of uranium and having a residual radioactivity level of less than 1000 pCi/gm. In accordance with the preferred embodiment of the invention, a catalyst and an oxidizing agent are used during the initial acid treatment and a final solid residue has a radioactivity level of less than about 50 pCi/gm.

  20. Formation of chemically bonded ceramics with magnesium dihydrogen phosphate binder

    DOE Patents [OSTI]

    Wagh, Arun S.; Jeong, Seung-Young

    2004-08-17

    A new method for combining magnesium oxide, MgO, and magnesium dihydrogen phosphate to form an inexpensive compactible ceramic to stabilize very low solubility metal oxides, ashes, swarfs, and other iron or metal-based additives, to create products and waste forms which can be poured or dye cast, and to reinforce and strengthen the ceramics formed by the addition of fibers to the initial ceramic mixture.

  1. Process for converting magnesium fluoride to calcium fluoride

    DOE Patents [OSTI]

    Kreuzmann, A.B.; Palmer, D.A.

    1984-12-21

    This invention is a process for the conversion of magnesium fluoride to calcium fluoride whereby magnesium fluoride is decomposed by heating in the presence of calcium carbonate, calcium oxide or calcium hydroxide. Magnesium fluoride is a by-product of the reduction of uranium tetrafluoride to form uranium metal and has no known commercial use, thus its production creates a significant storage problem. The advantage of this invention is that the quality of calcium fluoride produced is sufficient to be used in the industrial manufacture of anhydrous hydrogen fluoride, steel mill flux or ceramic applications.

  2. Electrodeposition of magnesium and magnesium/aluminum alloys

    DOE Patents [OSTI]

    Mayer, A.

    1988-01-21

    Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

  3. Electrodeposition of magnesium and magnesium/aluminum alloys

    DOE Patents [OSTI]

    Mayer, Anton (Los Alamos, NM)

    1988-01-01

    Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

  4. Efficient One-Step Electrolytic Recycling of Low-Grade and Post-Consumer Magnesium Scrap

    SciTech Connect (OSTI)

    Adam C. Powell, IV

    2012-07-19

    Metal Oxygen Separation Technologies, Inc. (abbreviated MOxST, pronounced most) and Boston University (BU) have developed a new low-cost process for recycling post-consumer co-mingled and heavily-oxidized magnesium scrap, and discovered a new chemical mechanism for magnesium separations in the process. The new process, designated MagReGenTM, is very effective in laboratory experiments, and on scale-up promises to be the lowest-cost lowest-energy lowest-impact method for separating magnesium metal from aluminum while recovering oxidized magnesium. MagReGenTM uses as little as one-eighth as much energy as today's methods for recycling magnesium metal from comingled scrap. As such, this technology could play a vital role in recycling automotive non-ferrous metals, particularly as motor vehicle magnesium/aluminum ratios increase in order to reduce vehicle weight and increase efficiency.

  5. ZIRCONIA-BASED MIXED POTENTIAL CARBON MONOXIDE/HYDROCARBON SENSORS WITH LANTHANUM MAGNESIUM OXIDE, AND TERBIUM-DOPED YTTRIUM STABILIZED ZIRCONIA ELECTRODES

    SciTech Connect (OSTI)

    E. L. BROSHA; R. MUKUNDAN; ET AL

    2000-10-01

    We have investigated the performance of dual metal oxide electrode mixed potential sensors in an engine-out, dynamometer environment. Sensors were fabricated by sputtering thin films of LaMnO{sub 3} and Tb-doped YSZ onto YSZ electrolyte. Au gauze held onto the metal oxide thin films with Au ink was used for current collection. The exhaust gas from a 4.8L, V8 engine operated in open loop, steady-state mode around stoichiometry at 1500 RPM and 50 Nm. The sensor showed a stable EMF response (with no hysteresis) to varying concentrations of total exhaust gas HC content. The sensor response was measured at 620 and 670 C and shows temperature behavior characteristic of mixed potential-type sensors. The results of these engine-dynamometer tests are encouraging; however, the limitations associated with Au current collection present the biggest impediment to automotive use.

  6. Hydrothermal synthesis of hexagonal magnesium hydroxide nanoflakes

    SciTech Connect (OSTI)

    Wang, Qiang, E-mail: qwchem@gmail.com [Laboratory for Micro-sized Functional Materials and College of Elementary Education, Capital Normal University, Beijing 100048 (China); Li, Chunhong [National Laboratory for Superconductivity, Institute of Physics and Beijing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guo, Ming [Laboratory for Micro-sized Functional Materials and College of Elementary Education, Capital Normal University, Beijing 100048 (China); Sun, Lingna [ShenZhen Key Laboratory of Functional Polymer, College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060 (China); Hu, Changwen [Key Laboratory of Cluster Science of Ministry of Education of China, The Institute for Chemical Physics and Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China)

    2014-03-01

    Graphical abstract: Hexagonal Mg(OH){sub 2} nanoflakes were synthesized via hydrothermal method in the presence of PEG-20,000. Results show that PEG-20,000 plays an important role in the formation of this kind of nanostructure. The SAED patterns taken from the different positions on a single hexagonal Mg(OH){sub 2} nanoflake yielded different crystalline structures. The structure of the nanoflakes are polycrystalline and the probable formation mechanism of Mg(OH){sub 2} nanoflakes is discussed. - Highlights: • Hexagonal Mg(OH){sub 2} nanoflakes were synthesized via hydrothermal method. • PEG-20,000 plays an important role in the formation of hexagonal nanostructure. • Mg(OH){sub 2} nanoflakes show different crystalline structures at different positions. • The probable formation mechanism of hexagonal Mg(OH){sub 2} nanoflakes was reported. - Abstract: Hexagonal magnesium hydroxide (Mg(OH){sub 2}) nanoflakes were successfully synthesized via hydrothermal method in the presence of the surfactant polyethylene glycol 20,000 (PEG-20,000). Results show that PEG-20,000 plays an important role in the formation of this kind of nanostructure. The composition, morphologies and structure of the Mg(OH){sub 2} nanoflakes were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HRTEM), and selected area electron diffraction (SAED). The SAED patterns taken from the different positions on a single hexagonal Mg(OH){sub 2} nanoflake show different crystalline structures. The structure of the nanoflakes are polycrystalline and the probable formation mechanism of Mg(OH){sub 2} nanoflakes is discussed. Brunauer–Emmett–Teller (BET) analysis were performed to investigate the porous structure and surface area of the as-obtained nanoflakes.

  7. Destabilization of magnesium hydride through interface engineering

    E-Print Network [OSTI]

    Dam, Bernard

    Destabilization of magnesium hydride through interface engineering Lennard Mooij #12;Destabilization of magnesium hydride through interface engineering PROEFSCHRIFT ter verkrijging van de graad van . . . . . . . . . . . . . . . . . . . . . . . . . 10 1.3 Magnesium hydride . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 1

  8. Constraining magnesium cycling in marine sediments using magnesium isotopes

    E-Print Network [OSTI]

    Paytan, Adina

    . Extensive sampling of sedimentary pore-fluids by the Deep Sea Drilling Project (DSDP) and Ocean Drilling Abstract Magnesium concentrations in deep-sea sediment pore-fluids typically decrease down core due to net and differentiate these processes, we have measured magnesium isotopes in pore-fluids and sediment samples from

  9. Synthesis of magnesium diboride by magnesium vapor infiltration process (MVIP)

    DOE Patents [OSTI]

    Serquis, Adriana C. (Los Alamos, NM); Zhu, Yuntian T. (Los Alamos, NM); Mueller, Frederick M. (Los Alamos, NM); Peterson, Dean E. (Los Alamos, NM); Liao, Xiao Zhou (Los Alamos, NM)

    2003-01-01

    A process of preparing superconducting magnesium diboride powder by heating an admixture of solid magnesium and amorphous boron powder or pellet under an inert atmosphere in a Mg:B ratio of greater than about 0.6:1 at temperatures and for time sufficient to form said superconducting magnesium diboride. The process can further include exposure to residual oxygen at high synthesis temperatures followed by slow cooling. In the cooling process oxygen atoms dissolved into MgB.sub.2 segregated to form nanometer-sized coherent Mg(B,O) precipitates in the MgB.sub.2 matrix, which can act as flux pinning centers.

  10. Combustion Synthesis of Magnesium Aluminate

    SciTech Connect (OSTI)

    Kale, M. A. [Physics Department, S.V.S.S. College of Engineering and Research, Nagpur 4411 10 (India); Joshi, C. P. [Physics Department, Ramdeobaba Engineering College, Katol Road, Nagpur 440 013 (India); Moharil, S. V. [Physics Department, RTM Nagpur University, Nagpur, 440033 (India)

    2011-10-20

    In the system MgO-Al{sub 2}O{sub 3}, three compounds MgAl{sub 2}O{sub 4}, MgAl{sub 6}O{sub 10}(also expressed as-Mg{sub 0.4}Al{sub 2.4}O{sub 4}) and MgAl{sub 26}O{sub 40} are well known. Importance of the first two is well established. Magnesium aluminate (MgAl{sub 2}O{sub 4}) spinel is a technologically important material due to its interesting thermal properties. The MgAl{sub 2}O{sub 4} ceramics also find application as humidity sensors. Apart from the luminescence studies, the interest in MgAl{sub 2}O{sub 4} is due to various applications such as humidity-sensing and PEM fuel cells, TL/OSL dosimetry of the ionizing radiations, white light source. Interest in the MgAl{sub 6}O{sub 10} has aroused due to possible use as a substrate for GaN growth. Attempt was made to synthesize these compounds by the combustion synthesis using metal nitrates as oxidizer and urea as a fuel. Compounds MgAl{sub 2}O{sub 4} and MgAl{sub 6}O{sub 10} were formed in a single step, while MgAl{sub 26}O{sub 40} was not formed by this procedure. Activation of MgAl{sub 6}O{sub 10} by rare earth ions like Ce{sup 3+}, Eu{sup 3+} and Tb{sup 3+} and ns{sup 2} ion Pb{sup 2+} could be achieved. Excitation bands for MgAl{sub 6}O{sub 10} are at slightly shorter wavelengths compared to those reported for MgAl{sub 2}O{sub 4}.

  11. Range Sustainability (VSP) PNWD-SA-7032 25

    E-Print Network [OSTI]

    Range Sustainability (VSP) PNWD-SA-7032 25 PNWD-SA-7032 / 25 Sampling Goals Establish Boundary of Contamination Partial Boundary #12;Range Sustainability (VSP) PNWD-SA-7032 26 PNWD-SA-7032 / 26 Required Samples #12;Range Sustainability (VSP) PNWD-SA-7032 27 PNWD-SA-7032 / 27 Specify Constituents of Concern

  12. Range Sustainability (VSP) PNWD-SA-7032 17

    E-Print Network [OSTI]

    Range Sustainability (VSP) PNWD-SA-7032 17 PNWD-SA-7032 / 17 Edit Sample Areas Define New Sample Area Defined Sample Area #12;Range Sustainability (VSP) PNWD-SA-7032 18 PNWD-SA-7032 / 18 "New Area" button on the Toolbar Defined Sample Area #12;Range Sustainability (VSP) PNWD-SA-7032 19 PNWD-SA-7032

  13. Range Sustainability (VSP) PNWD-SA-7032 49

    E-Print Network [OSTI]

    Range Sustainability (VSP) PNWD-SA-7032 49 PNWD-SA-7032 / 49 Hypothetical Case Study (Continued Sustainability (VSP) PNWD-SA-7032 50 PNWD-SA-7032 / 50 Hypothetical Case Study (Continued)Hypothetical Case Study Save #12;Range Sustainability (VSP) PNWD-SA-7032 51 PNWD-SA-7032 / 51 Coordinate View X and Y

  14. Range Sustainability (VSP) PNWD-SA-7032 33

    E-Print Network [OSTI]

    Range Sustainability (VSP) PNWD-SA-7032 33 PNWD-SA-7032 / 33 Map View Sample Information Box Click in this Column #12;Range Sustainability (VSP) PNWD-SA-7032 34 PNWD-SA-7032 / 34 Sample Information Box Sustainability (VSP) PNWD-SA-7032 35 PNWD-SA-7032 / 35 Segment Sample Results Box Enter Measurements

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  20. Nolaris SA | Open Energy Information

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland:NPI VenturesNew Hampshire: EnergyReservoir | Open EnergyNodawayNolaris SA Jump

  1. Clealco SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar EnergyLawler, IowaScottsboro,KansasKansasWindom,Wray,County RuralClealco SA

  2. Prorener SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavyAgency (IRENA)OptionsEquivalent URI Jump to:Prorener SA Jump to:

  3. Theolia SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavyAgencyTendo New Energy EquipmentSvendborgTecsisAreaSA Jump to:

  4. Venergia SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavyAgencyTendo New EnergyWind PowerUnison CoJweersVaauVenergia SA

  5. Veronagest SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavyAgencyTendo New EnergyWind PowerUnisonEnergiaVeronagest SA Jump

  6. Luzboa SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EAInvervarLeeds,Asia-PacificInformationLuxcara AssetLuximLuzboa SA

  7. Montebalito SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to: navigation,Mereg GmbHMontebalito SA Jump to: navigation, search Name:

  8. IDESA SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA JumpDuimen RiverScoringUtilities Comm JumpImagingICFICeLIDESA SA

  9. Inceisa SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA JumpDuimen RiverScoringUtilitiesRenovInceisa SA Jump to: navigation,

  10. Solaronix SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter BatterySolarfin Jump to: navigation, searchSolaronix SA Jump to:

  11. Solems SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter BatterySolarfin Jump to: navigation,Solarvalue AGSolazymeSolems SA

  12. Synova SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter BatterySolarfinMarketMember CorpSunviePtySwatchSylacaugaCoSynova SA

  13. Sener SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-bRenewableSMUDSectional ModelofSener SA Jump to:

  14. Silcio SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS ReportEurope GmbH Jump to: navigation,ShowSikes Act Jump to:Silcio SA

  15. Avanzit SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowaWisconsin: EnergyYork Jump|LineMaine: EnergyAvanzit SA Jump to: navigation,

  16. Abasol SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowa (UtilityMichigan)data bookresult9)ATS Lighting Inc JumpAbasol SA Jump to:

  17. WHC-SA-1619-FP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking WithTelecentricN A 035(92/02) nerg *4 o** 0, WF* W3 rd MWHC-SA-1619-FP

  18. Abengoa SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'S FUTURE.EnergyWoodenDateSA Jump to: navigation, search Name:

  19. Fiberblade SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavy ElectricalsFTL Solar Jump to:Fenglilai TechnologyFiberblade SA

  20. Iberdrola SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavy ElectricalsFTLTechnologySA Jump to: navigation, search Name:

  1. DOE/EIS-0391-SA-01

    Office of Environmental Management (EM)

    D-SA-01 SUPPLEMENT ANALYSIS of the Draft Tank Closure and Waste Management Environmental Impact Statement for the Hanford Site, Richland, Washington February 2012 FEBRUARY 2012 i...

  2. Range Sustainability (VSP) PNWD-SA-7032 41

    E-Print Network [OSTI]

    Range Sustainability (VSP) PNWD-SA-7032 41 PNWD-SA-7032 / 41 Assumptions Underlying the UCLs. #12;Range Sustainability (VSP) PNWD-SA-7032 42 PNWD-SA-7032 / 42 Hypothetical Case Study that the action limit for the RDX mean (4.4 ppm) is not exceeded. #12;Range Sustainability (VSP) PNWD-SA-7032 43

  3. Range Sustainability (VSP) PNWD-SA-7032 57

    E-Print Network [OSTI]

    Range Sustainability (VSP) PNWD-SA-7032 57 PNWD-SA-7032 / 57 Sample Information Box for Segment 4 the RDX Measurements for the 2 MI Samples in Segment 4 #12;Range Sustainability (VSP) PNWD-SA-7032 58 PNWD;Range Sustainability (VSP) PNWD-SA-7032 59 PNWD-SA-7032 / 59 Sample Information Box for Segment 4 UCL

  4. Switchable mirrors based on nickel-magnesium films

    SciTech Connect (OSTI)

    Richardson,Thomas J.; Slack, Jonathan L.; Armitage, Robert D.; Kostecki, Robert; Farangis, Baker; Rubin, Michael D.

    2001-01-16

    A new type of electrochromic mirror electrode based on reversible uptake of hydrogen in nickel magnesium alloy films is reported. Thin,magnesium-rich Ni-Mg films prepared on glass substrates by cosputtering from Ni and Mg targets are mirror-like in appearance and have low visible transmittance. Upon exposure to hydrogen gas or on reduction in alkaline electrolyte, the films take up hydrogen and become transparent. When hydrogen is removed, the mirror properties are recovered. The transition is believed to result from reversible formation of Mg2NiH4 and MgH2. A thin overlayer of palladium was found to enhance the kinetics of hydrogen insertion and extraction,and to protect the metal surface against oxidation.

  5. EIS-0421-SA-2: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EIS-0421-SA-2: Supplement Analysis EIS-0421-SA-2: Supplement Analysis The Bonneville Power Administration evaluated: design adjustments to minimize impacts to an area of high...

  6. EIS-0350-SA-02: Final Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    350-SA-02: Final Supplement Analysis EIS-0350-SA-02: Final Supplement Analysis Chemistry and Metallurgy Research Building Replacement Project at Los Alamos National Laboratory, Los...

  7. Substrate and method for the formation of continuous magnesium diboride and doped magnesium diboride wire

    DOE Patents [OSTI]

    Suplinskas, Raymond J. (Haverhill, MA); Finnemore, Douglas (Ames, IA); Bud'ko, Serquei (Ames, IA); Canfield, Paul (Ames, IA)

    2007-11-13

    A chemically doped boron coating is applied by chemical vapor deposition to a silicon carbide fiber and the coated fiber then is exposed to magnesium vapor to convert the doped boron to doped magnesium diboride and a resultant superconductor.

  8. Tissue magnesium and calcium concentration in relation to magnesium and calcium intake in rats 

    E-Print Network [OSTI]

    Pinkham, Carrie Stanton

    1987-01-01

    TISSUE MAGNESIUM AND CALCIUM CONCENTRATION IN RELATION TO MAGNESIUM AND CALCIUM INTAKE IN RATS A Thesis by CARRIE STANTON PINKRAM Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirerrents... for the degree of MASTER OF SCIENCE August 1987 Major Subject: Nutrition TISSUE MAGNESIUM AND CALCIUM CONCENTRATION IN RELATION TO MAGNESIUM AND CALCIUM INTAKE IN RATS A Thesis by CARRIE STANTON PINKHAM Approved as to style and content by: Karen S...

  9. SA3654 Component characterization. Final report

    SciTech Connect (OSTI)

    Meir, G.W.

    1996-06-01

    AlliedSignal Inc., Federal Manufacturing & Technologies (FM&T), was provided with production capability assurance program (PCAP) funding to develop, characterize, and qualify purchased product components for use on the PRESS-A program. The SA3654, N-Channel, Power MOSFET was identified as a component needing such activity to support PRESS-A. This report presents the characterization activities and results for the SA3654.

  10. Scale-Up of Magnesium Production by Fully Stabilized Zirconia...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis 2012 DOE Hydrogen and Fuel Cells...

  11. Range Sustainability (VSP) PNWD-SA-7032 1

    E-Print Network [OSTI]

    Range Sustainability (VSP) PNWD-SA-7032 1 PNWD-SA-7032 Range Sustainability Module Using Visual Sample Plan (VSP) Software Range Sustainability ModuleRange Sustainability Module Using Visual Sample Sustainability (VSP) PNWD-SA-7032 2 PNWD-SA-7032 / 2 ObjectiveObjectiveObjective Learn how to use the Range

  12. Range Sustainability (VSP) PNWD-SA-7032 9

    E-Print Network [OSTI]

    Range Sustainability (VSP) PNWD-SA-7032 9 PNWD-SA-7032 / 9 What are the Steps in Using the VSP Sustainability (VSP) PNWD-SA-7032 10 PNWD-SA-7032 / 10 Hypotheses Being TestedHypotheses Being Tested is false., i.e., on showing that the segment does not need to be bumped out. #12;Range Sustainability (VSP

  13. Stream Temperatu Timing of Coho Sa

    E-Print Network [OSTI]

    McMahon, Thomas E.

    and the ini- tiation of feeding involves leaving secure?low energy environ- ments in the interstices of stream bed gravels and entering the high energy environment of the stream, Among populationssf coho salmon (0Stream Temperatu Timing of Coho Sa from Carnation Creek, British L. Blair Holtby, Thomas E. Mc

  14. LOST FOAM CASTING OF MAGNESIUM ALLOYS

    SciTech Connect (OSTI)

    Han, Qingyou [ORNL; Dinwiddie, Ralph Barton [ORNL; Sklad, Philip S [ORNL; Currie, Kenneth [Tennessee Technological University; Abdelrahman, Mohamed [Tennessee Technological University; Vondra, Fred [Tennessee Technological University; Walford, Graham [Walford Technologies; Nolan, Dennis J [Foseco-Morval

    2007-01-01

    The lost foam casting process has been successfully used for making aluminum and cast iron thin walled castings of complex geometries. Little work has been carried out on cast magnesium alloys using the lost foam process. The article describes the research activities at Oak Ridge National Laboratory and Tennessee Technological University on lost foam casting of magnesium alloys. The work was focused on castings of simple geometries such as plate castings and window castings. The plate castings were designed to investigate the mold filling characteristics of magnesium and aluminum alloys using an infrared camera. The pate castings were then characterized for porosity distribution. The window castings were made to test the castability of the alloys under lost foam conditions. Significant differences between lost foam aluminum casting and lost foam magnesium casting have been observed.

  15. Cellulose-Bound Magnesium Diboride Superconductivity

    E-Print Network [OSTI]

    Ryan, Dominic

    Cellulose-Bound Magnesium Diboride Superconductivity Y.L. Lin and M.O. Pekguleryuz Department a cellulose based polymer. Cellulose tends to react only very weekly and is very robust, hence constitutes

  16. Promising Magnesium Battery Research at ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    charge, giving it potential as a more efficient energy source. Magnesium has a high volumetric capacity, which could mean more battery power in a smaller space. However, to bring...

  17. Achievements and Outlook 2012 SA Water Centre for Water

    E-Print Network [OSTI]

    Mayer, Wolfgang

    Achievements and Outlook 2012 SA Water Centre for Water Management and Reuse #12;Contents Our Breaking News 35 SA Water Centre for Water Management and Reuse University of South Australia Mawson Lakes Campus Mawson Lakes SA 5095 Telephone: +61 (08) 8302 3338 Fax: +61 (08) 8302 3386 Web: unisa.edu.au/water

  18. SA Water Centre for Water Management and Reuse

    E-Print Network [OSTI]

    Li, Jiuyong "John"

    SA Water Centre for Water Management and Reuse #12;2 The SA Water Centre for Water Management and Reuse was established in 2004 as a joint venture between the South Australian Water Corporation and the University of South Australia (UniSA), adding significant expertise to the water research capability in South

  19. Supplement Analyses (SA) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternational Affairs, Before theFebruary 1, 2006 EIS-0348-SA-01: Supplement

  20. Supplement Analyses (SA) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternational Affairs, Before theFebruary 1, 2006 EIS-0348-SA-01:

  1. DOE/EIS-0290-SA-03

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8, 20153 METHODS DERIVATION-2013,3O190-SA-03 Supplement

  2. DOE/EIS-0350-SA-2

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8, 20153 METHODS DERIVATION-2013,3O190-SA-03

  3. The Bolting of Magnesium Components in Car Engines

    E-Print Network [OSTI]

    Cambridge, University of

    1 The Bolting of Magnesium Components in Car Engines Sarennah J.P. Longworth Newnham College of bolting together magnesium alloys components at temperatures around 100o C, such as those found in car

  4. Texture Control by Selective Deformation Mechanism Activation in Magnesium Alloy 

    E-Print Network [OSTI]

    Foley, David Christopher

    2014-07-01

    The need for high strength, light weight structures in automotive and aerospace applications has driven a resurgence of interest in magnesium and its alloys. Unlike aluminum, wrought magnesium typically has a high degree ...

  5. SOLID STATE JOINING OF MAGNESIUM TO STEEL

    SciTech Connect (OSTI)

    Jana, Saumyadeep; Hovanski, Yuri; Pilli, Siva Prasad; Field, David P.; Yu, Hao; Pan, Tsung-Yu; Santella, M. L.

    2012-06-04

    Friction stir welding and ultrasonic welding techniques were applied to join automotive magnesium alloys to steel sheet. The effect of tooling and process parameters on the post-weld microstructure, texture and mechanical properties was investigated. Static and dynamic loading were utilized to investigate the joint strength of both cast and wrought magnesium alloys including their susceptibility and degradation under corrosive media. The conditions required to produce joint strengths in excess of 75% of the base metal strength were determined, and the effects of surface coatings, tooling and weld parameters on weld properties are presented.

  6. DOE/EIS-0391-SA-01

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding Low-Cost2 DOE HQSiteo n n e v i l l e2Q)1 ergy0291D-SA-01

  7. Entaban Ecoenergeticas SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbH JumpEllenville, NewLtdEnergypediaEntaban Ecoenergeticas SA Jump to:

  8. Solaire Direct SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing Capacity forSilicium deEnergy Information North|Solaire Direct SA Jump

  9. Solarig Energias SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-Enhancing Capacity forSilicium deEnergyCompanySolarLabSolarcomplexSolarig Energias SA

  10. MES DEA SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas:Montezuma, Arizona:Oregon:Lowell Point,Massachusetts:Kansas:M1Remains2MES DEA SA Jump

  11. DOE/EIS-0200-SA01

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HAB Packet HanfordDOE ProjectREMOTE-HANDLED TRU WASTE026-SA-08

  12. Destilaria Americana SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to: navigation,Department of Defense 3 GWAmericana SA Jump to:

  13. EHN ETVE SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:of the NationalDynetek Europe GmbHED FETVE SA Jump to:

  14. Tudostar Energia Eolica SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavyAgencyTendo New EnergyWind Power Co LtdTudostar Energia Eolica SA

  15. Maxwell Technologies SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to: navigation, searchScotland JumpPlantation Elec CoSA Jump to:

  16. NV Bekaert SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to: navigation,MeregNIFE BateriasInternationalNTT AdvancedNV Bekaert SA

  17. FBA Franco Brasileira SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:ofEnia SpA JumpGmbH EFCFBA Franco Brasileira SA Jump to:

  18. Silicio Energia SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter Battery Technology CoWanping HydropowerYongxiangPVJumpSpa Jump to:SA

  19. Supplement Analyses (SA) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternational Affairs, Before theFebruary 1, 2006 EIS-0348-SA-01: Supplement Analysis

  20. Supplement Analyses (SA) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternational Affairs, Before theFebruary 1, 2006 EIS-0348-SA-01: SupplementApril 29,

  1. Supplement Analyses (SA) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternational Affairs, Before theFebruary 1, 2006 EIS-0348-SA-01: SupplementApril

  2. Supplement Analyses (SA) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternational Affairs, Before theFebruary 1, 2006 EIS-0348-SA-01:August 13, 2002

  3. Lion Energy SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History ViewInformationWinds JumpOxiranchemRemodelers CouncilLink toEnergy SA

  4. DOE/EIS-0200-SA-04 August

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8, 20153 METHODS DERIVATION-2013,3 DOE/CF-0073EA132-F0-SA-04

  5. Becosa Energias Renovables SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'S FUTURE.EnergyWoodenDateSAEngineeringBecosa Energias Renovables SA

  6. Characterization of fold defects in AZ91D and AE42 magnesium alloy permanent mold castings

    SciTech Connect (OSTI)

    Bichler, L. [Centre for Near-net-shape Processing of Materials, Ryerson University, 101 Gerrard St. E., Toronto, M5B 2K3 (Canada); Ravindran, C., E-mail: rravindr@ryerson.ca [Centre for Near-net-shape Processing of Materials, Ryerson University, 101 Gerrard St. E., Toronto, M5B 2K3 (Canada)

    2010-03-15

    Casting premium-quality magnesium alloy components for aerospace and automotive applications poses unique challenges. Magnesium alloys are known to freeze rapidly prior to filling a casting cavity, resulting in misruns and cold shuts. In addition, melt oxidation, solute segregation and turbulent metal flow during casting contribute to the formation of fold defects. In this research, formation of fold defects in AZ91D and AE42 magnesium alloys cast via the permanent mold casting process was investigated. Computer simulations of the casting process predicted the development of a turbulent metal flow in a critical casting region with abrupt geometrical transitions. SEM and light optical microscopy examinations revealed the presence of folds in this region for both alloys. However, each alloy exhibited a unique mechanism responsible for fold formation. In the AZ91D alloy, melt oxidation and velocity gradients in the critical casting region prevented fusion of merging metal front streams. In the AE42 alloy, limited solubility of rare-earth intermetallic compounds in the {alpha}-Mg phase resulted in segregation of Al{sub 2}RE particles at the leading edge of a metal front and created microstructural inhomogeneity across the fold.

  7. AEC Lowman Station - coal switching and magnesium-enhanced lime scrubbing to lower operating costs

    SciTech Connect (OSTI)

    Inkenhaus, W.; Babu, M.; Smith, K. [Dravo Lime Co., Pittsburgh, PA (United States); Loper, L. [Alabama Electric Coopreative, Leroy, AL (United States)

    1997-12-31

    AEC`s Lowman Station is located in Leroy, Alabama. There are three coal-fired boilers at this station. Unit 1 is capable of generating 85 MW without a flue gas desulfurization, FGD, system. Units 2 and 3, with a total of 516 MW output capacity, are equipped with FGD systems. The FGD plant was designed for wet limestone FGD with natural oxidation. Lowman Station burned low sulfur, 1.3 to 1.8% sulfur, coal. In January of 1996 AEC switched Units 2 and 3 from limestone to magnesium-enhanced lime FGD operation. It was determined that the plant could take advantage of the higher SO{sub 2} removal efficiency of the magnesium-enhanced lime system. Major benefits resulting from this conversion were AEC`s ability to switch to a lower cost high sulfur coal while meeting the stringent SO{sub 2} emission requirements. Power cost savings resulted from the lower liquid to gas ratio required by the magnesium-enhanced lime process. Three recirculation pumps per module were reduced to a single operating pump per module, lowering the scrubber pressure drop. Significant cost reduction in the operating costs of the ball mill was realized due to modifications made to slake lime instead of grinding limestone. Prior to switching, personnel from AEC and Dravo Lime Company ran a four week test on magnesium-enhanced lime to obtain scrubber performance data including SO{sub 2} removal efficiencies on the modules while burning a 1.8% sulfur coal. This paper discusses the plant modifications that were needed to make the switch, cost justifications due to coal switching, and AEC`s operating experiences to date. AEC and Dravo Lime Company working together as a team conducted detailed cost studies, followed by extensive field tests and implemented the plant modifications. This plant continues to operate burning higher sulfur coal with the magnesium-enhanced lime FGD system.

  8. An EPR study of ¹?O? on magnesium oxide 

    E-Print Network [OSTI]

    Wong, Ning-Bew

    1971-01-01

    intensity curves, I(H), and their first derivative curves, I'(H), for the paramagnetic species with an axially symmetric g-tensor, with a fully anisotropic g-tensor, and with an axially symmetric g-tensor 25 and one spin-Q nucleus are shown in Figs. 10(a...'(H), for the Paramagnetic Species with (a) an Axially Symmetric g-Tensor (b) a Fully Anisotropic g-Tensor (c) an Axi. ally Symmetric g-Tensor and One 1 Spin- ? Nucleus 2 46 g I ( I-I ) ~II 11 IH I'(I-I) H (c) Figure 11, The Absorption Curve, I(H), Constructed...

  9. Appendix MgO: Magnesium Oxide as an Engineered Barrier

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D B L O O D SFederal Facility Agreement andMON-2014 WIPP

  10. Sol-gel preparation of lead magnesium niobate (PMN) powders and thin films

    DOE Patents [OSTI]

    Boyle, T.J.

    1999-01-12

    A method of preparing a lead magnesium niobium oxide (PMN), Pb(Mg{sub 1/3}Nb{sub 2/3})O{sub 3}, precursor solution by a solvent method wherein a liquid solution of a lead-complex PMN precursor is combined with a liquid solution of a niobium-complex PMN precursor, the combined lead- and niobium-complex liquid solutions are reacted with a magnesium-alkyl solution, forming a PMN precursor solution and a lead-based precipitate, and the precipitate is separated from the reacted liquid PMN precursor solution to form a precipitate-free PMN precursor solution. This precursor solution can be processed to form both ferroelectric powders and thin films. 3 figs.

  11. Sol-Gel Preparation Of Lead Magnesium Ni Obate (Pmn) Powdersand Thin Films

    DOE Patents [OSTI]

    Boyle, Timothy J. (Albuquerque, NM)

    1999-01-12

    A method of preparing a lead magnesium niobium oxide (PMN), Pb(Mg.sub.1/3 Nb.sub.2/3)O.sub.3, precursor solution by a solvent method wherein a liquid solution of a lead-complex PMN precursor is combined with a liquid solution of a niobium-complex PMN precursor, the combined lead- and niobium-complex liquid solutions are reacted with a magnesium-alkyl solution, forming a PMN precursor solution and a lead-based precipitate, and the precipitate is separated from the reacted liquid PMN precursor solution to form a precipitate-free PMN precursor solution. This precursor solution can be processed to form both ferroelectric powders and thin films.

  12. SA Water Centre for Water Management and Reuse

    E-Print Network [OSTI]

    Li, Jiuyong "John"

    SA Water Centre for Water Management and Reuse #12;' Our Mission The SA Water Centre for Water Management and Reuse aims to advance the science and technology of sustainable water management through fundamental and applied research. Our Vision To be Australia's leading research centre for water reuse

  13. Hospices Civils de Lyon -Documentation Centrale sa.documentationcentrale@chu

    E-Print Network [OSTI]

    Maume-Deschamps, Véronique

    Hospices Civils de Lyon - Documentation Centrale Tel : 04 sa.documentationcentrale@chu Manuel d Centrale - 3-5 avenue Esquirol - 69424 Lyon cedex 03 : 04-72-11-29-99 Fax : 04 72 11 29 87 sa.documentationcentrale@chu-lyon.fr http://portailsante.univ-lyon1.fr 1/103 Manuel d'utilisation de Pubmed Utilisation de la base

  14. Lead magnesium niobate actuator for micropositioning

    DOE Patents [OSTI]

    Swift, Charles D. (Livermore, CA); Bergum, John W. (Concord, CA)

    1994-01-01

    An improved lead magnesium niobate actuator is disclosed comprising a cylindrical lead magnesium niobate crystal stack mounted in a cylindrical casing wherein a bias means, such as one or more belleville washers, is located between one end of the crystal stack and a partially closed end of the casing; and adjustment means are provided which bear against the opposite end of the crystal stack, whereby an adjustable compressive force is constantly applied against the crystal stack, whether the crystal stack is actuated in an extended position, or is in an unactuated contracted position. In a preferred embodiment, cooling ports are provided for the circulation of coolant in the actuator to cool the crystal stack, and provision is made for removal and replacement of the crystal stack without disconnecting the actuator from the external device being actuated.

  15. The characterization of eight tyrosine to phenylalanine mutations in ribonuclease SA

    E-Print Network [OSTI]

    Horn, Geoffrey William

    2000-01-01

    An investigation of the contribution of hydrogen bonding to protein stability was performed using Ribonuclease Sa3 as a model system. Ribonuclease Sa3 (RNase Sa3) has eight tyrosine residues. Eight mutants were constructed ...

  16. The spontaneous ignition potential of a super-light crude oil S.A. Abu-Khamsin*, A. Iddris1

    E-Print Network [OSTI]

    Abu-Khamsin, Sidqi

    pressure were varied to determine the set of conditions that would cause the sand±oil mixture to ignite successful [1,2]. The feasibility of this method depends on low-temperature oxidation (LTO) of the oilU N C O R R EC TED PR O O F The spontaneous ignition potential of a super-light crude oil S.A. Abu

  17. Impurity control and corrosion resistance of magnesium-aluminum alloy

    SciTech Connect (OSTI)

    Liu, M. [GM China Lab] [GM China Lab; Song, GuangLing [ORNL] [ORNL

    2013-01-01

    The corrosion resistance of magnesium alloys is very sensitive to the contents of impurity elements such as iron. In this study, a series of diecast AXJ530 magnesium alloy samples were prepared with additions of Mn and Fe. Through a comprehensive phase diagram calculation and corrosion evaluation, the mechanisms for the tolerance limit of Fe in magnesium alloy are discussed. This adds a new dimension to control the alloying impurity in terms of alloying composition design and casting conditions.

  18. MAGNESIUM-BASED METHODS, SYSTEMS, AND DEVICES - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials for Magnesium Batteries and Metal Anodes Abstract: An aspect of the present invention is an electrical device, where the device includes a current collector and a porous...

  19. Rechargeable Magnesium Batteries: Low-Cost Rechargeable Magnesium Batteries with High Energy Density

    SciTech Connect (OSTI)

    2010-10-01

    BEEST Project: Pellion Technologies is developing rechargeable magnesium batteries that would enable an EV to travel 3 times farther than it could using Li-ion batteries. Prototype magnesium batteries demonstrate excellent electrochemical behavior; delivering thousands of charge cycles with very little fade. Nevertheless, these prototypes have always stored too little energy to be commercially viable. Pellion Technologies is working to overcome this challenge by rapidly screening potential storage materials using proprietary, high-throughput computer models. To date, 12,000 materials have been identified and analyzed. The resulting best materials have been electrochemically tested, yielding several very promising candidates.

  20. Stationary storage and purification of hydrogen using nickel-coated magnesium powder. Final technical report

    SciTech Connect (OSTI)

    NONE

    1999-12-30

    The following conclusions were reached: (1) The concept of a coating on a magnesium particle serving as a well-supported hydrogen-permselective membrane is sound. (2) Magnesium nitride can be made to coat magnesium particles through chemical vapor deposition within a fluidized bed. (3) Magnesium nitride exhibits the properties necessary for such a coating. (4) Magnesium nitride is not chemically inert to hydrogen in the absence of ammonia at temperatures typically used to hydride/dehydride magnesium.

  1. Determining SQL Server 2012 Core Licensing Requirements at SA Renewal

    E-Print Network [OSTI]

    Chaudhuri, Surajit

    Determining SQL Server 2012 Core Licensing Requirements at SA Renewal June 2012 #12;2 Table......................................................................................................................................................................................................4 How to Create a SQL Server 2012 Transition Report .............................................................................................11 Discover SQL Server installations

  2. Effect Of Neodymium Substitution In Structural Characteristics Of Magnesium Ferrite

    SciTech Connect (OSTI)

    Thankachan, Smitha; Binu, P. J.; Xavier, Sheena; Mohammed, E. M. [Department of Physics, Maharaja's College, Ernakulam (India)

    2011-10-20

    The effect of Nd{sup 3+} substitution on the structural properties of Magnesium ferrite was studied in the series MgNd{sub x}Fe{sub 2-x}O{sub 4}, where x = 0 to 0.3 in steps of 0.05. The series was prepared by sol-gel technique which is one of the novel technique to prepare nanosized samples. Structural characterization was done using X-ray diffractometer and Fourier Transform Infrared Spectrometer. XRD analysis reveals the prepared samples are single phasic till x = 0.2. From x0 = .25, a secondary phase of iron neodymium oxide appears along with the spinel phase. Particle size calculation shows the prepared samples are in the 9nm to 11 nm regime. Lattice parameter was found to increase with concentration of Nd. XRD and FTIR analysis confirmed spinel structure of the prepared samples. XRF result shows the expected composition of prepared samples. The frequency dependence of the dielectric constant in the range 100 Hz--120MHz was also studied

  3. Casting Porosity-Free Grain Refined Magnesium Alloys

    SciTech Connect (OSTI)

    Schwam, David

    2013-08-12

    The objective of this project was to identify the root causes for micro-porosity in magnesium alloy castings and recommend remedies that can be implemented in production. The findings confirm the key role played by utilizing optimal gating and risering practices in minimizing porosity in magnesium castings.?

  4. DOE/EIS-0203-SA-07 DOE/EA-1148-SA-01 DOE/EIS-0250F-S-1-SA-02

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HAB Packet HanfordDOE ProjectREMOTE-HANDLED TRU WASTE026-SA-08SA-07

  5. The effects of a suboptimal intake of magnesium with soy protein concentrate on parturition, growth, and viability in the rat 

    E-Print Network [OSTI]

    Carson, Sonja D'Awn

    1985-01-01

    fed the magnesium- deficient diet. Magnesium deficiency did not lower femur calcium content, but it significantly decreased femur magnesium. Studies of the human situation would be of interest. ACKNOWLEDGEMENTS The author wishes to express thanks... of dietary magnesium and protein source on tissue 42 Table 11 Effects of dietary treatment on serum magnesium and femur magnesium and calcium 44 LIST OF FIGURES page Figure 1 Weights of dams fed control diet, low magnesium casein diet, soy diet...

  6. EIS-0243-SA-02: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2:Decision (April|2:-SA-01:Hood River-SA-02:

  7. EIS-0245-SA-03: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2:Decision (April|2:-SA-01:Hood5-SA-03:

  8. EIS-0246-SA-20: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2:Decision (April|2:-SA-01:Hood5-SA-03:0:

  9. EIS-0246-SA-23: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2:Decision (April|2:-SA-01:Hood5-SA-03:0:3:

  10. EIS-0246-SA-24: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2:Decision (April|2:-SA-01:Hood5-SA-03:0:3:4:

  11. EIS-0312-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3:2:-SA-01: SupplementRecord-SA-01: Supplement

  12. EIS-0312-SA-02: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3:2:-SA-01: SupplementRecord-SA-01:

  13. EIS-0312-SA-03: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3:2:-SA-01: SupplementRecord-SA-01:3:

  14. EIS-0332-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3:2:-SA-01:DepartmentRecord-SA-01: Supplement

  15. Chloride-Magnesium Ratio of Shallow Groundwaters as a Regional...

    Open Energy Info (EERE)

    Chloride-Magnesium Ratio of Shallow Groundwaters as a Regional Geothermal Indicator in Hawaii Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  16. Interlayer-Expanded Molybdenum Disulfide Nanocomposites for Electrochemical Magnesium Storage

    E-Print Network [OSTI]

    and grid energy storage.1-4 Mg rechargeable batteries (MgRBs) stand out as a promising choice due for the development of advanced materials for next-generation energy storage. KEYWORDS: Magnesium rechargeable

  17. Ames Lab 101: BAM (Boron-Aluminum-Magnesium)

    ScienceCinema (OSTI)

    Bruce Cook

    2013-06-05

    Materials scientist, Bruce Cook, discusses the super hard, low friction, and lubricious alloy know as BAM (Boron-Aluminum-Magnesium). BAM was discovered by Bruce Cook and his team a

  18. Determination of carbon, nitrogen, and oxygen in high purity magnesium 

    E-Print Network [OSTI]

    Roche, Neil Gerard

    1981-01-01

    DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Submitted to the Graduate College of Texas A8cM University in partial i'ulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1981 Major Subject: Chemistry DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Approved as to style and content by: E. A. Schweikert (Chairman of Committee) G. J. Bastiaans (Member) L...

  19. Duncan Taylor duncan.taylor@sa.gov.au

    E-Print Network [OSTI]

    1 Duncan Taylor duncan.taylor@sa.gov.au Continuous systems and their implementation Before contact proportion of these were mixtures ·There were many instances of incomplete profiles Added to this: ·DNA that determined what proportion of the population would not be excluded from an observed mixed profile ·Likelihood

  20. {~.~ DEPARTMENT Of HEALTH & HUMAN ERVICES Public Health SaMea

    E-Print Network [OSTI]

    {~.~ DEPARTMENT Of HEALTH & HUMAN ERVICES "~~ Public Health SaMea Centers for Disease Control and Prevention (CDC) AUanta GA 30341-3724 February 27, 2004 Dear Environmental Health Colleague: The Environmental Health Services Branch is pleased to provide your agency with a copy of the Volusia County Health

  1. Potential automotive uses of wrought magnesium alloys

    SciTech Connect (OSTI)

    Gaines, L.; Cuenca, R.; Wu, S. [Argonne National Lab., IL (United States); Stodolsky, F. [Argonne National Lab., IL (United States)]|[Argonne National Lab., Washington, DC (United States)

    1996-06-01

    Vehicle weight reduction is one of the major means available to improve automotive fuel efficiency. High-strength steels, aluminum (Al), and polymers are already being used to reduce weight significantly, but substantial additional reductions could be achieved by greater use of low-density magnesium (Mg) and its alloys. Mg alloys are currently used in relatively small quantities for auto parts, generally limited to die castings (e.g., housings). Argonne National Laboratory`s Center for Transportation Research has performed a study for the Lightweight Materials Program within DOE`s Office of Transportation Materials to evaluate the suitability of wrought Mg and its alloys to replace steel/aluminum for automotive structural and sheet applications. Mg sheet could be used in body nonstructural and semi-structural applications, while extrusions could be used in such structural applications as spaceframes. This study identifies high cost as the major barrier to greatly increased Mg use in autos. Two technical R and D areas, novel reduction technology and better hot-forming technology, could enable major cost reductions.

  2. University of Hawai`i at Mnoa Impormasyong Pang-undergraduate para sa

    E-Print Network [OSTI]

    . Ang UHM ay may sariling isla ng marine research na tinatawag na Coconut Island, 15 milya ang layo sa

  3. Gas sensing properties of magnesium doped SnO{sub 2} thin films in relation to AC conduction

    SciTech Connect (OSTI)

    Deepa, S.; Skariah, Benoy Thomas, Boben; Joseph, Anisha

    2014-01-28

    Conducting magnesium doped (0 to 1.5 wt %) tin oxide thin films prepared by Spray Pyrolysis technique achieved detection of 1000 ppm of LPG. The films deposited at 304 °C exhibit an enhanced response at an operating temperature of 350 °C. The microstructural properties are studied by means of X-ray diffraction. AC conductivity measurements are carried out using precision LCR meter to analyze the parameters that affect the variation in sensing. The results are correlated with compositional parameters and the subsequent modification in the charge transport mechanism facilitating an enhanced LPG sensing action.

  4. Effect of Strain Rate and Temperature on Fracture and Damage of Magnesium Alloy AZ31B 

    E-Print Network [OSTI]

    Rodriguez Atencio, Ana Karina

    2015-04-29

    Due to their low density and high specific strength, magnesium and its alloys are structural metals attractive for the aerospace and automotive industries. However, wide spread use of wrought magnesium is challenged by its ...

  5. Nondestructive evaluation of an environmentally friendly conversion coating for magnesium alloys using optical measurement techniques 

    E-Print Network [OSTI]

    Zuniga, David

    2006-10-30

    Magnesium alloys have one of the highest specific strengths of all construction metals used. Specifically, magnesium alloy castings are used in the aerospace industry to reduce the weight of aerospace vehicles. Coating systems must be employed...

  6. Using SA508/533 for the HTGR Vessel Material

    SciTech Connect (OSTI)

    Larry Demick

    2012-06-01

    This paper examines the influence of High Temperature Gas-cooled Reactor (HTGR) module power rating and normal operating temperatures on the use of SA508/533 material for the HTGR vessel system with emphasis on the calculated times at elevated temperatures approaching or exceeding ASME Code Service Limits (Levels B&C) to which the reactor pressure vessel could be exposed during postulated pressurized and depressurized conduction cooldown events over its design lifetime.

  7. EIS-0407-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5Department oftoStatement |Scoping EIS-0403:-SA-01:

  8. EIS-0218-SA-07: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergy Webinar:IAboutReuben Sarkar,18-SA-07: Supplement Analysis

  9. EIS-0222-SA-02: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels DataEnergy Webinar:IAboutReuben Sarkar,18-SA-07: Supplement

  10. Arsenic augments the uptake of oxidized LDL by upregulating the expression of lectin-like oxidized LDL receptor in mouse aortic endothelial cells

    SciTech Connect (OSTI)

    Hossain, Ekhtear; Ota, Akinobu; Karnan, Sivasundaram; Damdindorj, Lkhagvasuren; Takahashi, Miyuki; Konishi, Yuko; Konishi, Hiroyuki; Hosokawa, Yoshitaka

    2013-12-15

    Although chronic arsenic exposure is a well-known risk factor for cardiovascular diseases, including atherosclerosis, the molecular mechanism underlying arsenic-induced atherosclerosis remains obscure. Therefore, this study aimed to elucidate this molecular mechanism. We examined changes in the mRNA level of the lectin-like oxidized LDL (oxLDL) receptor (LOX-1) in a mouse aortic endothelial cell line, END-D, after sodium arsenite (SA) treatment. SA treatment significantly upregulated LOX-1 mRNA expression; this finding was also verified at the protein expression level. Flow cytometry and fluorescence microscopy analyses showed that the cellular uptake of fluorescence (Dil)-labeled oxLDL was significantly augmented with SA treatment. In addition, an anti-LOX-1 antibody completely abrogated the augmented uptake of Dil-oxLDL. We observed that SA increased the levels of the phosphorylated forms of nuclear factor of kappa light polypeptide gene enhancer in B cells (NF-?B)/p65. SA-induced upregulation of LOX-1 protein expression was clearly prevented by treatment with an antioxidant, N-acetylcysteine (NAC), or an NF-?B inhibitor, caffeic acid phenethylester (CAPE). Furthermore, SA-augmented uptake of Dil-oxLDL was also prevented by treatment with NAC or CAPE. Taken together, our results indicate that arsenic upregulates LOX-1 expression through the reactive oxygen species-mediated NF-?B signaling pathway, followed by augmented cellular oxLDL uptake, thus highlighting a critical role of the aberrant LOX-1 signaling pathway in the pathogenesis of arsenic-induced atherosclerosis. - Highlights: • Sodium arsenite (SA) increases LOX-1 expression in mouse aortic endothelial cells. • SA enhances cellular uptake of oxidized LDL in dose-dependent manner. • SA-induced ROS generation enhances phosphorylation of NF-?B. • SA upregulates LOX-1 expression through ROS-activated NF-?B signaling pathway.

  11. Nanostructured material for advanced energy storage : magnesium battery cathode development.

    SciTech Connect (OSTI)

    Sigmund, Wolfgang M.; Woan, Karran V.; Bell, Nelson Simmons

    2010-11-01

    Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

  12. Analysis of the potential for new automotive uses of magnesium

    SciTech Connect (OSTI)

    Stodolsky, F.; Gaines, L.; Cuenca, R.; Wu, S.

    1994-12-31

    This paper describes the scope of a new project, just initiated, for the Lightweight Materials Program within the Office of Transportation Materials. The Center for Transportation Research and the Energy Technology Division at Argonne National Laboratory will assess the feasibility and technical potential of using magnesium and its alloys in place of steel or aluminum for automotive structural and sheet applications in order to enable more energy-efficient, lightweight passenger vehicles. The analysis will provide an information base to help guide magnesium research and development in the most promising directions.

  13. A new approach to studying aqueous reactions using diffuse reflectance infrared Fourier transform spectrometry: application to the uptake and oxidation of SO2 on OH-processed model sea salt aerosol.

    E-Print Network [OSTI]

    Shaka', Huda; Robertson, W H; Finlayson-Pitts, Barbara J

    2007-01-01

    2 on OH-processed model sea salt aerosolw Huda Shaka’, W. H.point of the magnesium salt but below that of NaCl. ThisOH-processing of the salt. Further uptake and oxidation of

  14. NUCLEATION PHENOMENON IN SiC PARTICULATE REINFORCED MAGNESIUM COMPOSITE

    E-Print Network [OSTI]

    Zhou, Wei

    ) and grain refinement were observed in sand cast SiCp/Mg(AZ91) [7] and SiCp/Mg(ZCM630) composites [8 Avenue, Singapore 639798 (Received May 5, 1999) (Accepted June 24, 1999) Keywords: Casting; Nucleation performance of matrix metals and alloys. Most magnesium alloy based MMCs are produced via a casting process

  15. REVIEW ARTICLE A review on magnesium alloys as biodegradable materials

    E-Print Network [OSTI]

    Zheng, Yufeng

    to that of the bone (1.8­ 2.1 g/cm3 ) [1]. (ii) The fracture toughness of magnesium is greater than ceramic bone compared with the traditional Ti6Al4V, better ductility than the synthetic HA, and higher strength

  16. EIS-0310-SA-02: Supplement Analysis | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-inPPL EnergyPlus, LLC to5USC787 Rhode Islandand9::DOEMixed prepared this SA

  17. C:\Imaging\EIS-0203-F-SA-02.tif

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room News PublicationsAudits &Bradbury Science Museum6 Shares ofDOE/WIPP-97-2238 PeriodicF-SA-02

  18. Parque Eolico Altos del Voltoya SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to:Newberg,Energy LLC Jump to:3 ofAltos del Voltoya SA Jump to:

  19. Genesa HidroCantabrico SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:ofEnia SpAFlexStock|Genesa HidroCantabrico SA Jump to:

  20. EIS-0082-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse of HeAgenda1: Finalof EnergySA-01:

  1. EIS-0218-SA-02: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2: Supplement Analysis EIS-0218-SA-02:

  2. EIS-0218-SA-03: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2: Supplement Analysis EIS-0218-SA-02:3:

  3. EIS-0218-SA-04: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2: Supplement Analysis EIS-0218-SA-02:3:4:

  4. EIS-0240-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2:Decision (April|2:-SA-01: Supplement

  5. EIS-0246-SA-39: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2:Decision6: Supplement7: SupplementSA-39:

  6. EIS-0250-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2:Decision6: Supplement7::PublicImpact-SA-01:

  7. EIS-0251-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2:Decision6:Notice of Preferred-SA-01:

  8. EIS-0285-SA-453: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3: Supplement Analysis EIS-0285-SA-453:

  9. EIS-0285-SA-58: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3: Supplement Analysis EIS-0285-SA-453:58:

  10. EIS-0285-SA-65: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3: Supplement Analysis EIS-0285-SA-453:58:65:

  11. EIS-0290-SA-02: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3:2: Supplement Analysis EIS-0290-SA-02:

  12. EIS-0308-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3:2:-SA-01: Supplement Analysis

  13. EIS-0309-SA-02: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3:2:-SA-01: Supplement AnalysisEnergy

  14. EIS-0310-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3:2:-SA-01: SupplementRecord of Decision1:

  15. EIS-0340-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecordRecord of Decision EIS-0332:DraftRecord-SA-01:

  16. EIS-0378-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecordRecordStatementDepartment ofRecord of-SA-01:

  17. EIS-0385-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5Department of Energy Notice ofSA-01: Supplement Analysis

  18. Aries Ingeniera y Sistemas SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'S FUTURE.EnergyWoodenDateSA JumpSolarAeolis Geracao

  19. Energia Eolica de Sisante SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavy Electricals LtdEcowind Jump to:ElkemEolica de Sisante SA Jump

  20. DOE/EIS-0279-SA-01 DOE/EIS-0218-SA-06 Supplement Analysis Savannah River Site

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department8, 20153 METHODS DERIVATION-2013,3O1 Supplement79-SA-01

  1. NEW YOUNG STAR CANDIDATES IN CG4 AND Sa101

    SciTech Connect (OSTI)

    Rebull, L. M.; Laine, S.; Laher, R.; Legassie, M.; Hoette, V.; Kim, J. S.; Foster, M.; Mallory, C. R.; McCarron, K.; Sherry, W. H.

    2011-07-15

    The CG4 and Sa101 regions together cover a region of {approx}0.5 deg{sup 2} in the vicinity of a 'cometary globule' that is part of the Gum Nebula. There are seven previously identified young stars in this region; we have searched for new young stars using mid- and far-infrared data (3.6-70 {mu}m) from the Spitzer Space Telescope, combined with ground-based optical data and near-infrared data from the Two Micron All Sky Survey. We find infrared excesses in all six of the previously identified young stars in our maps and identify 16 more candidate young stars based on apparent infrared excesses. Most (73%) of the new young stars are Class II objects. There is a tighter grouping of young stars and young star candidates in the Sa101 region, in contrast to the CG4 region, where there are fewer young stars and young star candidates, and they are more dispersed. Few likely young objects are found in the 'fingers' of the dust being disturbed by the ionization front from the heart of the Gum Nebula.

  2. EIS(DOE/EIS-0246/SA-20) Supplement Analysis for the Wildlife...

    Office of Environmental Management (EM)

    for the Wildlife Mitigation Program EIS (DOEEIS-0246SA-20) Allyn Meuleman, KEWU-4 Fish and Wildlife Project Manager Proposed Action: Camas Prairie Acquisition, Anderson Ranch...

  3. An investigation of magnesium production in silicon by neutron transmutation 

    E-Print Network [OSTI]

    Davis, Freddie Joe

    1986-01-01

    NEUTRON TRANSMUTATION DOPING CHAPTER II. THEORY APPROACH IRRADIATION AND PRODUCTS NUMERICAL PREDICTIONS 10 REGISTRATION EFFICIENCY CHAPTER III. EXPERIMENT FILM SELECTION 23 PRELIMINARY TESTS OF LR-115 FILM 25 TARGET CONFIGURATION 29 INHERENT... approach. CHAPTER II THEORY APPROACH The general procedure was to irradiate silicon target materially using the NSCR as a neutron source. The desired interaction, that producing magnesium, gives rise to an alpha particle, which may escape the silicon...

  4. Potential applications of wrought magnesium alloys for passenger vehicles

    SciTech Connect (OSTI)

    Gaines, L.; Cuenca, R.; Stodolsky, F.; Wu, S.

    1995-12-31

    Vehicle weight reduction is one of the major means available for improving automotive fuel efficiency. Although high-strength steels, aluminum (Al), and polymers are already being used to achieve significant weight reductions, substantial additional weight reductions could be achieved by increased use of magnesium (Mg) and its alloys, which have very low density. Magnesium alloys are currently used in relatively small quantities for auto parts; use is generally limited to die castings, such as housings. The Center for Transportation Research at Argonne National Laboratory has performed a study for the Lightweight Materials Program within DOE`s Office of Transportation Materials to evaluate the suitability of wrought Mg and its alloys to replace steel or aluminum for automotive structural and sheet applications. This study identifies technical and economic barriers to this replacement and suggests R&D areas to enable economical large-volume use. Detailed results of the study will be published at a later date. Magnesium sheet could be used in body nonstructural and semi-structural applications, while extrusions could be used in such structural applications as spaceframes. Currently, Mg sheet has found limited use in the aerospace industry, where costs are not a major concern. The major barrier to greatly increased automotive use is high cost; two technical R&D areas are identified that could enable major reductions in costs. These are novel reduction technology and better hot-forming technology, possibly operating at lower temperatures and involving superplastic behavior.

  5. Fire Department, City of New York Fire SaFety education

    E-Print Network [OSTI]

    Schindler, Christian

    Fire Department, City of New York Fire SaFety education reSidential apartment Building Fire SaFety #7 Bill De Blasio, Mayor Daniel A. Nigro, Fire Commissioner Fire safety begins in your own apartment! Is your family fire safe? Protect yourself, your family and your neighbors. T here are special areas

  6. Best Practices Case Study: S&A Homes, East Liberty, PIttsburgh, PA

    SciTech Connect (OSTI)

    2010-12-01

    S&A Homes worked with Building America's IBACOS and architects Pfaffmann & Associates and Moss Associates to design energy-efficient homes for urban in-fill lots. This is a new market for S&A Homes, which builds over 500 homes a year using suburban designs.

  7. Characteristics and development report for the SA3871 Intent Controller application specific integrated circuit (ASIC)

    SciTech Connect (OSTI)

    Simpson, R.L.; Meyer, B.T.

    1995-08-01

    This report describes the design and development activities that were involved in the SA3871 Intent Controller ASIC. The SA3871 is a digital gate array component developed for the MC4396 Trajectory Sensing Signal Generator for use in the B61-3/4/10 system as well as a possible future B61-MAST system.

  8. OC and LA-LB-SA Merchandise Exports December 2012 ii IEES, California State University Fullerton

    E-Print Network [OSTI]

    de Lijser, Peter

    #12;OC and LA-LB-SA Merchandise Exports December 2012 ii IEES, California State University Exports By Mira Farka, Ph.D. Adrian R. Fleissig, Ph.D. December 2012 California State University Fullerton © Institute for Economic and Environmental Studies (IEES) #12;OC and LA-LB-SA Merchandise Exports December

  9. WSN-SA: Design Foundations for Situational Awareness Systems Based on Sensor Networks

    E-Print Network [OSTI]

    Liu, Mingyan

    WSN-SA: Design Foundations for Situational Awareness Systems Based on Sensor Networks Agnelo R EE - Electrophysics Univ. of Southern California Los Angeles, CA Email: mahta@usc.edu Abstract--WSN-SA is a Wireless Sensor Networks (WSN) framework that is been proposed to support rescue operations in collapsed

  10. Date: 30 Octobre 2014........ PAGE 1 OF 2 CONFIDENTIEL CONTINENTAL Automotive S.A.

    E-Print Network [OSTI]

    Tourneret, Jean-Yves

    Date: 30 Octobre 2014........ PAGE 1 OF 2 CONFIDENTIEL CONTINENTAL Automotive S.A. Proposition de 2015 Rémunération : 800 par mois (montant brut mensuel) Lieu: Continental Automotive France, 1 avenue.daurenjou@continental-corporation.com #12;Date: 30 Octobre 2014........ PAGE 2 OF 2 CONFIDENTIEL CONTINENTAL Automotive S.A. Internship

  11. s Less than 40 nanoseconds rms accuracy to UTC during Selective Availability (SA)*

    E-Print Network [OSTI]

    Berns, Hans-Gerd

    ® s Less than 40 nanoseconds rms accuracy to UTC during Selective Availability (SA)* s Better than and frequency accuracy available in a GPS timing receiver. Standard outputs include a 1 PPS, analog IRIG B time to UTC even during Selective Availability (SA). This superior oscilla- tor disciplining to GPS enables

  12. Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa

    E-Print Network [OSTI]

    El-Alfy, El-Sayed

    © Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa A Heuristic. of Pet. & Miner., Dhahran; Advanced Communication Technology, The 9th International conference of Petroleum & Minerals http://www.kfupm.edu.sa Summary A primary goal of this paper is to develop a heuristic

  13. Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa

    E-Print Network [OSTI]

    El-Alfy, El-Sayed

    © Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa On Optimal SYSTEMS AND APPLICATIONS, VOLS 1 AND 2; pp: 819-824; Vol: ## King Fahd University of Petroleum & Minerals: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa 15. YU F, 2004, EFFICIENT MULTI

  14. Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa

    E-Print Network [OSTI]

    El-Alfy, El-Sayed

    © Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa A Learning-Dong Yao Heffes, H.;Dept. of Comput. Sci., King Fahd Univ. of Pet. & Miner., Dhahran; Wireless & Minerals http://www.kfupm.edu.sa Summary An efficient channel allocation policy that prioritizes handoffs

  15. Determination of the concentrations of magnesium and aluminum in alloys by laser produced atomic emission spectroscopy 

    E-Print Network [OSTI]

    Ashe, William Monroe

    1997-01-01

    It Works) 35 5 RESULTS Data Collection . . 38 Part One (Boxcar Averager in Fixed Mode) 38 Part Two (Boxcar Averager in Scanning Mode) . . 39 Magnesium Spectra . . 40 Aluminum Alloy Specna Sensitivity , . 46 Error Analysis . . 48 Part One.... This spectra has been averaged over 5 runs using the Bin and Hold method . 65 32 Plot of intensity ratio vs. concentration ratio for the various magnesium alloys, incluthng the Johnson Matthey magnesium alloy sample data point (circled) 33 Close up...

  16. Low-Cost Magnesium Sheet Production using the Twin Roll Casting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Low-Cost Magnesium Sheet Production using the Twin Roll Casting Process and Asymmetric Rolling Materials Characterization Capabilities at the High...

  17. Magnesium and pyridoxine intake and mineral content of selected tissues and physical development in rats 

    E-Print Network [OSTI]

    Edgar, Susan Elaine

    1986-01-01

    lower f eed intake s than did rats from other dietary treatments. During lactation, dai ly feed consumpt ion was lower in an ima1 s depr ived of magnesium. Approximately 24 hr postpartum, in dams who consumed a magnesium-deficient diet, the heart... and kidney contained significantly more calcium, 150'% and 300% respectively. During lactation, mild magnesium restriction resulted in increased weight loss by dams and decreased weight gain by pupa. In the of f spring of rats dep1 et ed o f magnesium...

  18. Chemical and mechanical consequences of environmental barrier coating exposure to calcium-magnesium-aluminosilicate.

    SciTech Connect (OSTI)

    Harder, B.; Ramirez-Rico, J.; Almer, J. D.; Kang, L.; Faber, K.

    2011-06-01

    The success of Si-based ceramics as high-temperature structural materials for gas turbine applications relies on the use of environmental barrier coatings (EBCs) with low silica activity, such as Ba{sub 1-x}Sr{sub x}Al{sub 2}Si{sub 2}O{sub 8} (BSAS), which protect the underlying components from oxidation and corrosion in combustion environments containing water vapor. One of the current challenges concerning EBC lifetime is the effect of sandy deposits of calcium-magnesium-aluminosilicate (CMAS) glass that melt during engine operation and react with the EBC, changing both its composition and stress state. In this work, we study the effect of CMAS exposure at 1300 C on the residual stress state and composition in BSAS-mullite-Si-SiC multilayers. Residual stresses were measured in BSAS multilayers exposed to CMAS for different times using high-energy X-ray diffraction. Their microstructure was studied using a combination of scanning electron microscopy and transmission electron microscopy techniques. Our results show that CMAS dissolves the BSAS topcoat preferentially through the grain boundaries, dislodging the grains and changing the residual stress state in the topcoat to a nonuniform and increasingly compressive stress state with increasing exposure time. The presence of CMAS accelerates the hexacelsian-to-celsian phase transformation kinetics in BSAS, which reacts with the glass by a solution-reprecipitation mechanism. Precipitates have crystallographic structures consistent with Ca-doped celsian and Ba-doped anorthite.

  19. Ann bay lodyans 13 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    , li pa kite anyen deye. Mouche ale ak ni jwet zo li, ni kat li, ni boutey tafya, menm ti bout tanbou a li pa bliye mete. Konsa, kon mouche rive anwo a, li tabli yon jwet zo ak yon jwet kat, ansanm ak yon konmes kleren. Sa fe, pyes travay pa ka fet... sa a se yon danje piblik. Fok yo jwenn bout li. Depi Telisfo vini an, lanfe a vin tounen yon peyi pleziyis. Abitan yo pwofite fe parese. Men tou, Telisfo pa kite yo gen anyen, menm bout sigaret pa ka rete. Sa ki pi red, se chak jou yon moun...

  20. Ann bay lodyans 6 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    ("Tonton Liben") ki pare ti liv sa a. AYITI SE PEP AYISYEN PM 7 8 5 4 .H39 A 5 6 2 0 0 0 V . 6 Enstiti Etid Ayisyen - Inivesite Kannzas Bon Nouvel Fondasyon Alfa Lwes 1997 PINGALOT AK ELIFET Vwala te gen yon wa ki rele Pingalot. Men wa sa a... te yon neg sitelman rayisab tout peyi a t ap soufri. Nan peyi sa a te gen yon msye ki rele Elifet. Se te yon bon moun ki te konn travay di, e ki te fe ekonomi jous li rive monte yon gwo kay menm pi bel pase kay wa a. Konsa, Pingalot moveanpil...

  1. Ann bay lodyans 16 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    ofisye yo. Genyen yon gwo pyano pou nou pote nan sal la." Pye Wolen, Senlwidino TET DESALIN Yon blan rantre an Ayiti. Li mande yon neg: "Fe m jwenn tet Jan Jak Desalin, pou souvni." Neg la, sa li gen pou fe, li rantre nan yon simitye, li pran yon... tet byen vit. Li pote I bay blan an. Blan an di konsa: "Sa a pa tet Desalin. Tet Desalin pa kapab piti konsa." Neg la di: "Sa a se tet Desalin le I te timoun!" 8 MANGO A Ml Se Bouki ak Malis ki t ap pwonmennen. Bouki di Malis: "Men yon pye mango...

  2. High Performance Batteries Based on Hybrid Magnesium and Lithium Chemistry

    SciTech Connect (OSTI)

    Cheng, Yingwen; Shao, Yuyan; Zhang, Jiguang; Sprenkle, Vincent L.; Liu, Jun; Li, Guosheng

    2014-01-01

    Magnesium and lithium (Mg/Li) hybrid batteries that combine Mg and Li electrochemistry, consisting of a Mg anode, a lithium-intercalation cathode and a dual-salt electrolyte with both Mg2+ and Li+ ions, were constructed and examined in this work. Our results show that hybrid (Mg/Li) batteries were able to combine the advantages of Li-ion and Mg batteries, and delivered outstanding rate performance (83% for capacities at 15C and 0.1C) and superior cyclic stability (~5% fade after 3000 cycles).

  3. Structural properties and enthalpy of formation of magnesium hydride from quantum Monte Carlo calculations

    E-Print Network [OSTI]

    Alfè, Dario

    Structural properties and enthalpy of formation of magnesium hydride from quantum Monte Carlo calculations to study the structural properties of magnesium hydride MgH2 , including the pressure. INTRODUCTION The energetics of metal hydrides has recently become an issue of large scientific

  4. Combining Formal Methods and Safety Analysis -The ForMoSA Approach

    E-Print Network [OSTI]

    Reif, Wolfgang

    and quantitative analysis. The For- MoSA approach combines these techniques to answer these safety rele- vant level of con- fidence formal methods from software engineering have been used. Safety rele- vant

  5. Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa

    E-Print Network [OSTI]

    El-Alfy, El-Sayed

    © Copyright: King Fahd University of Petroleum & Minerals; http://www.kfupm.edu.sa MPLS Network SYSTEMS AND APPLICATIONS, VOLS 1-3; pp: 1058-1064; Vol: ## King Fahd University of Petroleum & Minerals

  6. High Areal Capacity Hybrid Magnesium-Lithium-Ion Battery with 99.9% Coulombic Efficiency for Large-Scale Energy Storage

    E-Print Network [OSTI]

    High Areal Capacity Hybrid Magnesium-Lithium-Ion Battery with 99.9% Coulombic Efficiency for Large, United States *S Supporting Information ABSTRACT: Hybrid magnesium-lithium-ion batteries (MLIBs magnesium-lithium-ion batteries (MLIBs), energy storage, Coulombic efficiency, dendrite-free magnesium

  7. Structure of an n-butane monolayer adsorbed on magnesium oxide (100)

    SciTech Connect (OSTI)

    Arnold, T.; Chanaa, S.; Cook, R. E.; Clarke, S. M.; Larese, J. Z.

    2006-08-15

    Neutron diffraction has been used to characterize the structure of the solid phase of the completed monolayer of n butane on the MgO(100) surface at low temperature. The monolayer is found to adopt a commensurate (7{radical}(2)x{radical}(2)R45 deg. ) structure with lattice constants a=29.47 A ring and b=4.21 A ring , P{sub 2gg} symmetry and four molecules in the unit cell. Excellent agreement with the experimental diffraction pattern is realized, using a Lorenztian profile to describe the line shape.

  8. Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up Research and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy BillsNo.Hydrogen4Energy SmoothEquipmentSolarDOE-SponsoredEngineering for

  9. Vehicle Technologies Office: Long-Term Lightweight Materials Research (Magnesium and Carbon Fiber)

    Broader source: Energy.gov [DOE]

    The Vehicle Technologies Office supports research into magnesium and carbon fiber reinforced composites, which could reduce the weight of some components by 50-75 percent in the long-term.

  10. Vehicle Technologies Office Merit Review 2015: Magnesium-Intensive Front End Sub-Structure Development

    Broader source: Energy.gov [DOE]

    Presentation given by USAMP at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about magnesium-intensive front end sub...

  11. Effect of Texture on Formability and Mechanical Anisotropy of a Severe Plastically Deformed Magnesium Alloy 

    E-Print Network [OSTI]

    Modarres Razavi, Sonia

    2012-02-14

    Magnesium and its alloys have been considered as alternatives to aluminum alloys and steels for structural applications in automotive and aerospace applications due to their superior specific strength and light-weight. ...

  12. SIMULATION OF POROSITY AND HOT TEARS IN A SQUEEZE CAST MAGNESIUM CONTROL ARM

    E-Print Network [OSTI]

    Beckermann, Christoph

    : Magnesium Alloys, Casting, Shrinkage Porosity, Hot Tears, Modeling Abstract Simulations are performed within commercial casting simulation software to predict shrinkage porosity and hot tears changes are introduced to mitigate the shrinkage and hot tear problems in these castings. The comparisons

  13. Novel Magnesium Alloys Developed for Biomedical Application: A Review Nan Li, Yufeng Zheng*

    E-Print Network [OSTI]

    Zheng, Yufeng

    of their high me- chanical strength as well as high fracture toughness. The den- sities of magnesium (1.738 g efficiency, so higher strength, and better ductility and corrosion resistance are required. Nevertheless

  14. Controlling the Biodegradation of Magnesium Implants Through Nanostructured Calcium-Phosphate Coating

    E-Print Network [OSTI]

    Iskandar, Maria Emil

    2012-01-01

    In-Seop L. Calcium phosphate coating on magnesium alloy forsimulated body fluid. Surface Coating Technology 2004:92-98.XN. Electrodeposition of Ca-P coatings on biodegradable Mg

  15. The tolerance of two varieties of cotton to relatively high levels of sodium and magnesium 

    E-Print Network [OSTI]

    Parekh, Manhar C

    1969-01-01

    THE TO'ERANCE OF TNO VARIETIES OF COTTON TO RELATIVELY HIGH LEVELS OF SODIUM AND MAGNESIUM A Tnesis by Msnhar C. Parekh Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree...) (Nember) (Nemb ) August 1969 ABSTRACT The Tolerance of Two Varieties of Cotton to Relatively High Levels of Sodium and Magnesium. (August 1969) Masher C. Parekh, B. S. , Gujarat University, Directed by: Dr. H. E. Joham An experiment was conducted...

  16. A study of the role of calcium and magnesium in casein micellar structure in human milk 

    E-Print Network [OSTI]

    Gallaway, Sheila Ann

    1988-01-01

    ) Karen . Kubena (Member) Wa ne L. R&cko11 (Member) G. C. Smith (Head of Department) December 1988 ABSTRACT A Study of the Role of Calcium and Magnesium in Casein Micellar Structure in Human Milk. (December 1988) Sheila Ann Gallaway, B, S.... , Texas ASM University; M. S. , Texas ASM University Chair of Advisory Committee: Dr. C. W. Dill The effects of EDTA, phosphatase hydrolysis, calcium chloride, and magnesium chloride on human casein micelles were observed using electron microscopy...

  17. Novel Nonflammable Electrolytes for Secondary Magnesium Batteries and High Voltage Electrolytes for Electrochemcial Supercapacitors

    SciTech Connect (OSTI)

    Dr. Brian Dixon

    2008-12-30

    Magnesium has been used successfully in primary batteries, but its use in rechargeable cells has been stymied by the lack of suitable non-aqueous electrolyte that can conduct Mg+2 species, combined with poor stripping and plating properties. The development of a suitable cathode material for rechargeable magnesium batteries has also been a roadblock, but a nonflammable electrolyte is key. Likewise, the development of safe high voltage electrochemical supercapaitors has been stymied by the use of flammable solvents in the liquid electrolyte; to wit, acetonitrile. The purpose of the research conducted in this effort was to identify useful compositions of magnesium salts and polyphosphate solvents that would enable magnesium ions to be cycled within a secondary battery design. The polyphosphate solvents would provide the solvent for the magnesium salts while preventing the electrolyte from being flammable. This would enable these novel electrolytes to be considered as an alternative to THF-based electrolytes. In addition, we explored several of these solvents together with lithium slats for use as high voltage electrolytes for carbon-based electrochemical supercapacitors. The research was successful in that: 1) Magnesium imide dissolved in a phosphate ester solvent that contains a halogented phosphate ester appears to be the preferred electrolyte for a rechargeable Mg cell. 2) A combination of B-doped CNTs and vanadium phosphate appear to be the cathode of choice for a rechargeable Mg cell by virtue of higher voltage and better reversibility. 3) Magnesium alloys appear to perform better than pure magnesium when used in combination with the novel polyphosphate electrolytes. Also, this effort has established that Phoenix Innovationâ??s family of phosphonate/phosphate electrolytes together with specific lithium slats can be used in supercapacitor systems at voltages of greater than 10V.

  18. Ann bay lodyans 10 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    KU ScholarWorks | http://kuscholarworks.ku.edu Ann Bay Lodyans 10 se Bryant Freeman (“Tonton Liben”) ki pare ti liv sa a 2000 by Bryant C. Freeman, ed. This work has been made available by the University of Kansas Libraries’ Office of Scholarly... Freeman (“Tonton Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml Tl CHENN LO A Te gen yon nonm ki te...

  19. Ann bay lodyans 12 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    KU ScholarWorks | http://kuscholarworks.ku.edu Ann Bay Lodyans 12 se Bryant Freeman (“Tonton Liben”) ki pare ti liv sa a 2000 by Bryant C. Freeman, ed. This work has been made available by the University of Kansas Libraries’ Office of Scholarly... Freeman (“Tonton Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml EPI BONDYE KREYE PREMYE FS A Nan...

  20. Ann bay lodyans 4 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    KU ScholarWorks | http://kuscholarworks.ku.edu Ann Bay Lodyans 4 se Bryant Freeman (“Tonton Liben”) ki pare ti liv sa a 2000 by Bryant C. Freeman, ed. This work has been made available by the University of Kansas Libraries’ Office of Scholarly... Freeman (“Tonton Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml Tl CHAT: PI PITI PI RED Vwala se te...

  1. Ann bay lodyans 1 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    KU ScholarWorks | http://kuscholarworks.ku.edu Ann Bay Lodyans 1 se Bryant Freeman (“Tonton Liben”) ki pare ti liv sa a 2000 by Bryant C. Freeman, ed. This work has been made available by the University of Kansas Libraries’ Office of Scholarly... Freeman (“Tonton Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml ANN BAY LODYANS 1 Se Bryant Freeman...

  2. Ann bay lodyans 11 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml ANN BAY LODYANS 11 Se Bryant Freeman ("Tonton Liben...") ki pare ti liv sa a. AYITI SE PEP AYISYEN PM 7854 .H39 A56 2000 PM Enstiti Etid Ayisyen - Inivesite Kannzas Bon Nouvel Fondasyon Alfa Lwes 1997 YON PWASON KI RELE TEZEN Vwala se yon jennfi yo rele Wozilya ak yon jennjan yo rele Tezen ki...

  3. Ann bay lodyans 9 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml MARYAJ MALIS TWOUKOUKOU Vwala se Malis ki gen yon sel... rantre nan chanm Ian ak yon lanp. Yo gade, epi yo we moun ak mouchwa wouj la. Yo peze kou moun ak foula a jous li toufe, epi yo ale. Nan denmen maten, Malis leve. L al di yo: "Mezanmi, mesi anpil. M gen lontan m pa gen yon bon nwit kon sa...

  4. Ann bay lodyans 15 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml ANN BAY LODYANS15 Se Bryant Freeman ("Tonton Liben...") ki pare ti liv sa a. H ^ AYITI SE PEP AYISYEN 2 0 0 0 Enstiti Etid Ayisyen - Inivesite Kannzas Bon Nouvel Fondasyon Alfa Lwes 2000 PM 7854 .H39 A56 2000 v. 15 YON KONTRA AK LEDJAB Vwala te gen yon malerez ki te deja gen douz pitit, e...

  5. Ann bay lodyans 14 / Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml fcjNlVfcHto" r ' K A N S A S L lBf iAH.r ANN BAY... LODYANS1 4 Se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a. A 51* AYITI SE PEP AYISYEN PM 7854 .H39 A56 2000 v. 14 Enstiti Etid Ayisyen - Inivesite Kannzas Bon Nouvel Fondasyon Alfa Lwes 2000 YON TI PYE ZORANJ Se istwa yon ti fi ki...

  6. Ann bay lodyans 3 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml ANN BAY LODYANS 3 Se Bryant Freeman ("Tonton Liben...") ki pare ti liv sa a. AYITI SE PEP AYISYEN Enstiti Etid Ayisyen - Inivesite Kannzas Bon Nouvel Fondasyon Alfa Lwes 2000 PM 7854 • H39 A56 KUAN POU M JWENN KOB? Vwala te gen yon zarenyen ki te raze net. Li di nan tet li: "M bezwen jwenn kob...

  7. A. Bag, W. Zhou, D. Taplin and E. S. Dwarakadasa, Fatigue Behaviour of AZ91D Magnesium Alloy and its Composite Reinforced with SiC, in Magnesium Technology 2000, eds. H. I. Kaplan, J. N. Hryn

    E-Print Network [OSTI]

    Zhou, Wei

    and its Composite Reinforced with SiC, in Magnesium Technology 2000, eds. H. I. Kaplan, J. N. Hryn and B

  8. The effect of sulfur, magnesium, and various rates of potassium on forage production in some sandy soils of East Texas 

    E-Print Network [OSTI]

    Landua, Dennis Paul

    1969-01-01

    the exchangeable potassium and magnesium in a Lakeland fine sand 4 Distribution of potassium, magnesium, and sulfate in a Lakeland fine sand. 48 Effect of fertilizer treatments on total yield of Coastal bermudagrass grown in the field in 1968. . 51 10 Effect...THE EFFECT OF SULFUR, MAGNESIUM, AND VARIOUS RATES OF POTASSIUM ON FORAGE PRODUCTION IN SOME SANDy SOILS OF EAST TEXAS A Thesis by DENNIS PAUL LANDUA Submitted to the Graduate Collccje of Texas AFM Unive, sity in partial fulfillment...

  9. Ab Initio Thermodynamic Model for Magnesium Carbonates and Hydrates

    SciTech Connect (OSTI)

    Chaka, Anne M.; Felmy, Andrew R.

    2014-03-28

    An ab initio thermodynamic framework for predicting properties of hydrated magnesium carbonate minerals has been developed using density-functional theory linked to macroscopic thermodynamics through the experimental chemical potentials for MgO, water, and CO2. Including semiempirical dispersion via the Grimme method and small corrections to the generalized gradient approximation of Perdew, Burke, and Ernzerhof for the heat of formation yields a model with quantitative agreement for the benchmark minerals brucite, magnesite, nesquehonite, and hydromagnesite. The model shows how small differences in experimental conditions determine whether nesquehonite, hydromagnesite, or magnesite is the result of laboratory synthesis from carbonation of brucite, and what transformations are expected to occur on geological time scales. Because of the reliance on parameter-free first principles methods, the model is reliably extensible to experimental conditions not readily accessible to experiment and to any mineral composition for which the structure is known or can be hypothesized, including structures containing defects, substitutions, or transitional structures during solid state transformations induced by temperature changes or processes such as water, CO2, or O2 diffusion. Demonstrated applications of the ab initio thermodynamic framework include an independent means to evaluate differences in thermodynamic data for lansfordite, predicting the properties of Mg analogs of Ca-based hydrated carbonates monohydrocalcite and ikaite which have not been observed in nature, and an estimation of the thermodynamics of barringtonite from the stoichiometry and a single experimental observation.

  10. Mechanistic Studies on the Formation of Trifluoromethyl Sulfur Pentafluoride, SF5CF3sa Greenhouse Gas

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    Mechanistic Studies on the Formation of Trifluoromethyl Sulfur Pentafluoride, SF5CF3sa Greenhouse that a source for this potentially dangerous greenhouse gas might be the recombination of SF5(X2A1) and CF3(X2A1 the strongest greenhouse gas trifluoromethyl sulfur pentafluoride (SF5CF3) with a radiative force of 0.59 W m-2

  11. Techgen S.A. de C.V.- 14-94-NG

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy gives notice of receipt of an Application filed July 15, 2014, by Techgen S.A. de C.V.(Techgen), seeking a long-term multi-contract authorization to export up to 56.2...

  12. PC>MPT SA Non-Commercial 20141030 Page 1 Invoice and Payment Instructions

    E-Print Network [OSTI]

    Ungerleider, Leslie G.

    accelerated payments to its small business subcontractors under this contract, to the maximum extentPC>MPT SA Non-Commercial 20141030 Page 1 Invoice and Payment Instructions for Contracts and Awards) The following is applicable to all contracts and awards above the micro-purchase threshold where

  13. PNNL-SA-38977 Measurement Uncertainty in Visual Sample Plan (VSP)

    E-Print Network [OSTI]

    a Threshold Pulsipher Page 1 7/18/2003 #12;PNNL-SA-38977 · Compare Proportion Against a Threshold · Compare Average or Proportion Against Reference Data (background) · Find Hot Spot · Find UXO Target Area Sampling · Continuous Transect Sampling · Judgmental Sampling VSP has a number of unique, special features

  14. 08 September 2014 Judge Navi Pillay to speak on advancing human rights in SA and

    E-Print Network [OSTI]

    Jarrett, Thomas H.

    08 September 2014 Judge Navi Pillay to speak on advancing human rights in SA and the world Annual Navanethem (Navi) Pillay ahead of delivering the 15th Annual Steve Biko Memorial Lecture at the University the caste-based system. About Judge Navi Pillay Judge Pillay has had an illustrious career. She became

  15. Transport impacts on atmosphere and climate: Shipping Veronika Eyring a,*, Ivar S.A. Isaksen b

    E-Print Network [OSTI]

    Stevenson, David

    by these emissions. Regulating ship emissions requires comprehensive knowledge of current fuel consumption and emisTransport impacts on atmosphere and climate: Shipping Veronika Eyring a,*, Ivar S.A. Isaksen b Accepted 6 April 2009 Keywords: Transport Oceangoing shipping Ozone Climate change Radiative forcing Air

  16. MEMS Deformable Mirrors for Astronomical Adaptive Optics S.A. Cornelissen1

    E-Print Network [OSTI]

    Bifano, Thomas

    on the development of high actuator count, micro-electromechanical (MEMS) deformable mirrors designed for high order Microelectromechanical systems (MEMS) based deformable mirrors (DMs) are an emerging class of wavefront correctors usedMEMS Deformable Mirrors for Astronomical Adaptive Optics S.A. Cornelissen1 , A.L. Hartzell1 , J

  17. SaCS: A Method and a Pattern Language for the Development of Conceptual Safety Designs

    E-Print Network [OSTI]

    Stølen, Ketil

    , and nuclear reactor protection systems are examples of safety critical systems from different industrial.D.) in Computer Science June 2014 #12;ii #12;Abstract Flight control systems, railway interlocking systems. In this thesis we present a method and a pattern language called Safe Control Systems (SaCS) for development

  18. ASP 79 makes a large, unfavorable contribution to the conformational stability of Ribonuclease SA 

    E-Print Network [OSTI]

    Trevino, Saul Rene

    2013-02-22

    the stability of the protein. Also, the stability was measured as a function of pH for RNase Sa and the D79F mutant. The pK of Asp 79 was found to be 7.2 in the native state and 4.7 in the denatured state....

  19. PORTFOLIO RISK ASSESSMENT OF SA WATER'S LARGE DAMS by David S. Bowles1

    E-Print Network [OSTI]

    Bowles, David S.

    PORTFOLIO RISK ASSESSMENT OF SA WATER'S LARGE DAMS by David S. Bowles1 , Andrew M. Parsons2 , Loren R. Anderson3 and Terry F. Glover4 ABSTRACT This paper summarises the Portfolio Risk Assessment (PRA a reconnaissance-level engineering assessment and risk assessment. These assessments were performed for floods

  20. MLE IN THE PROPORTIONAL ODDS MODEL BY S.A. MURPHY1, A.J. ROSSINI

    E-Print Network [OSTI]

    Murphy, Susan A.

    MLE IN THE PROPORTIONAL ODDS MODEL BY S.A. MURPHY1, A.J. ROSSINI AND A.W. VAN DER VAART maximumlikelihood estimation of the parameters in the proportional odds model with right censored data Pettitt 1982 and Bennett 1983ab generalized the proportional odds model to the survival analysis context

  1. MEMS Deformable Mirror Actuators with Enhanced Reliability S.A. Cornelissena

    E-Print Network [OSTI]

    Bifano, Thomas

    MEMS Deformable Mirror Actuators with Enhanced Reliability S.A. Cornelissena , T.G. Bifanoa,b , P, 15 St. Mary's St., Boston, MA 02215 ABSTRACT MEMS deformable mirrors with thousands of actuators due to electrical overstress. We report on advances made in the development of MEMS deformable mirror

  2. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

    1989-01-01

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  3. Fabrication of solid oxide fuel cell by electrochemical vapor deposition

    DOE Patents [OSTI]

    Riley, B.; Szreders, B.E.

    1988-04-26

    In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

  4. Structural studies of magnesium nitride fluorides by powder neutron diffraction

    SciTech Connect (OSTI)

    Brogan, Michael A.; Hughes, Robert W.; Smith, Ronald I.; Gregory, Duncan H.

    2012-01-15

    Samples of ternary nitride fluorides, Mg{sub 3}NF{sub 3} and Mg{sub 2}NF have been prepared by solid state reaction of Mg{sub 3}N{sub 2} and MgF{sub 2} at 1323-1423 K and investigated by powder X-ray and powder neutron diffraction techniques. Mg{sub 3}NF{sub 3} is cubic (space group: Pm3m) and has a structure related to rock-salt MgO, but with one cation site vacant. Mg{sub 2}NF is tetragonal (space group: I4{sub 1}/amd) and has an anti-LiFeO{sub 2} related structure. Both compounds are essentially ionic and form structures in which nitride and fluoride anions are crystallographically ordered. The nitride fluorides show temperature independent paramagnetic behaviour between 5 and 300 K. - Graphical abstract: Definitive structures of the ternary magnesium nitride fluorides Mg{sub 3}NF{sub 3} and the lower temperature polymorph of Mg{sub 2}NF have been determined from powder neutron diffraction data. The nitride halides are essentially ionic and exhibit weak temperature independent paramagnetic behaviour. Highlights: Black-Right-Pointing-Pointer Definitive structures of Mg{sub 3}NF{sub 3} and Mg{sub 2}NF were determined by neutron diffraction. Black-Right-Pointing-Pointer Nitride and fluoride anions are crystallographically ordered in both structures. Black-Right-Pointing-Pointer Both compounds exhibit weak, temperature independent paramagnetic behaviour. Black-Right-Pointing-Pointer The compounds are essentially ionic with ionicity increasing with F{sup -} content.

  5. ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. T. van Duin, and William A. Goddard III*

    E-Print Network [OSTI]

    van Duin, Adri

    ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. T and Chemical Engineering, California Institute of Technology, Pasadena, California 91125 ReceiVed: September 3FFMgH) for magnesium and magnesium hydride systems. The parameters for this force field were derived from fitting

  6. An evaluation of the spring finger solder joints on SA1358-10 and SA2052-4 connector assemblies (MC3617,W87).

    SciTech Connect (OSTI)

    Kilgo, Alice C.; Vianco, Paul Thomas; Hlava, Paul Frank; Zender, Gary L.

    2006-08-01

    The SA1358-10 and SA2052-4 circular JT Type plug connectors are used on a number of nuclear weapons and Joint Test Assembly (JTA) systems. Prototype units were evaluated for the following specific defects associated with the 95Sn-5Sb (Sn-Sb, wt.%) solder joint used to attach the beryllium-copper (BeCu) spring fingers to the aluminum (Al) connector shell: (1) extended cracking within the fillet; (2) remelting of the solder joint during the follow-on, soldering step that attached the EMR adapter ring to the connector shell (and/or soldering the EMR shell to the adapter ring) that used the lower melting temperature 63Sn-37Pb (Sn-Pb) alloy; and (3) spalling of the Cd (Cr) layer overplating layer from the fillet surface. Several pedigrees of connectors were evaluated, which represented older fielded units as well as those assemblies that were recently constructed at Kansas City Plant. The solder joints were evaluated that were in place on connectors made with the current soldering process as well as an alternative induction soldering process for attaching the EMR adapter ring to the shell. Very similar observations were made, which crossed the different pedigrees of parts and processes. The extent of cracking in the top side fillets varied between the different connector samples and likely the EMR adapter ring to the shell. Very similar observations were made, which crossed the different pedigrees of parts and processes. The extent of cracking in the top side fillets varied between the different connector samples and likely reflected the different extents to which the connector was mated to its counterpart assembly. In all cases, the spring finger solder joints on the SA1358-10 connectors were remelted as a result of the subsequent EMR adapter ring attachment process. Spalling of the Cd (Cr) overplating layer was also observed for these connectors, which was a consequence of the remelting activity. On the other hand, the SA2052-4 connector did not exhibit evidence of remelting of the spring finger solder joint. The Cd (Cr) layer did not show signs of spalling. These results suggested that, due to the size of the SA1358-10 connector, any of the former or current soldering processes used to attach the EMR adapter ring and/or EMR shell to the connector shell, requires a level of heat energy that will always result in the remelting of the spring finger solder joint attached with either the Sn-Ag or the Sn-Sb alloy. Lastly, it was construed that the induction soldering process, which is used to attach the EMR adapter ring onto the shell, was more likely to have caused the remelting event rather than the more localized heat source of the hand soldering iron used to attach the EMR shell to the adapter ring.

  7. The folding kinetics of ribonuclease Sa and a charge-reversal variant 

    E-Print Network [OSTI]

    Trefethen, Jared M.

    2005-02-17

    ) 2.12 4.84 2.43 6.01 ?G(H2O) (kcal/mol) 3.42 4.62 3.71 5.75 20 Kinetic Analysis The refolding and unfolding kinetics of WT* and WT*(D17R) RNase Sa were performed at 25?C and at pH 7 and pH 3. Chevron plots were generated by plotting the natural.... To further characterize the kinetics at pH 3, additional experiments should be performed. 25 0 2 4 6 8 10 12 14 3 4 5 6 7 8 9 10 Fluorescence Signal 0 2 4 6 8 10 12 14-0.10 0.00 0.10 time (s) FIGURE 11: Unfolding progress curve data of WT*(D17R) RNase Sa...

  8. Oxidation catalyst

    DOE Patents [OSTI]

    Ceyer, Sylvia T. (Cambridge, MA); Lahr, David L. (Cambridge, MA)

    2010-11-09

    The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

  9. Magnesium transport extraction of transuranium elements from LWR fuel

    DOE Patents [OSTI]

    Ackerman, John P. (Downers Grove, IL); Battles, James E. (Oak Forest, IL); Johnson, Terry R. (Wheaton, IL); Miller, William E. (Naperville, IL); Pierce, R. Dean (Naperville, IL)

    1992-01-01

    A process of separating transuranium actinide values from uranium values present in spent nuclear oxide fuels which contain rare earth and noble metal fission products. The oxide fuel is reduced with Ca metal in the presence of CaCl.sub.2 and a U-Fe alloy containing not less than about 84% by weight uranium at a temperature in the range of from about 800.degree. C. to about 850.degree. C. to produce additional uranium metal which dissolves in the U-Fe alloy raising the uranium concentration and having transuranium actinide metals and rare earth fission product metals and the noble metal fission products dissolved therein. The CaCl.sub.2 having CaO and fission products of alkali metals and the alkali earth metals and iodine dissolved therein is separated and electrolytically treated with a carbon electrode to reduce the CaO to Ca metal while converting the carbon electrode to CO and CO.sub.2. The Ca metal and CaCl.sub.2 is recycled to reduce additional oxide fuel. The U-Fe alloy having transuranium actinide metals and rare earth fission product metals and the noble metal fission products dissolved therein is contacted with Mg metal which takes up the actinide and rare earth fission product metals. The U-Fe alloy retains the noble metal fission products and is stored while the Mg is distilled and recycled leaving the transuranium actinide and rare earth fission products isolated.

  10. Effects of fluctuant magnesium concentration on phenotype of the primary chondrocytes

    E-Print Network [OSTI]

    Zheng, Yufeng

    , Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China 2 DepartmentM of MgCl2 solution set as the control group. Concentra- tions of Mg ions and pH values of the culture generally degrade to magnesium hydroxide, hydrogen gas, sulfate, and phosphate in aqueous environments via

  11. Hot cracking in tungsten inert gas welding of magnesium alloy AZ91D

    E-Print Network [OSTI]

    Zhou, Wei

    Hot cracking in tungsten inert gas welding of magnesium alloy AZ91D W. Zhou*, T. Z. Long and C. K of the plates were produced using tungsten inert gas (TIG) welding method. The TIG arc was also used to deposit welding beads on some of the thin plates. No cracking was found in the butt joints. However, hot cracking

  12. Enthalpies of formation of magnesium compounds from first-principles calculations

    E-Print Network [OSTI]

    Chen, Long-Qing

    Enthalpies of formation of magnesium compounds from first-principles calculations Hui Zhang, miscellaneous B. Thermodynamic and thermochemical properties E. Ab initio calculations a b s t r a c). The calculated lattice parameters and enthalpies of formation of binary compounds in these systems are compared

  13. Evaluation of Heat Shields from RTS Wright Industries Magnesium and Uranium Beds

    SciTech Connect (OSTI)

    Korinko, P.S.

    2002-10-29

    Heat shields from a factory test of the furnaces that will be used to heat the magnesium and uranium beds for the tritium extraction facility (TEF) were examined to determine the cause of discoloration. The samples were examined using visual, optical microscopy, electron microscopy, x-ray spectroscopy, and Auger electron spectroscopy.

  14. Student Administration System Q&A: Logging into the SA System with NetID Updated 08/15/2013

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Student Administration System Q&A: Logging into the SA System with NetID Updated 08/15/2013 Q&A: Logging into the Student Administration (SA) System with Your NetID (Effective 08/09/2013) Q: What-numeric NetID and NetID password. Q: Who is not affected by this change? A: Administrative users who currently

  15. Aerosol chemical vapor deposition of metal oxide films

    DOE Patents [OSTI]

    Ott, K.C.; Kodas, T.T.

    1994-01-11

    A process of preparing a film of a multicomponent metal oxide including: forming an aerosol from a solution comprised of a suitable solvent and at least two precursor compounds capable of volatilizing at temperatures lower than the decomposition temperature of said precursor compounds; passing said aerosol in combination with a suitable oxygen-containing carrier gas into a heated zone, said heated zone having a temperature sufficient to evaporate the solvent and volatilize said precursor compounds; and passing said volatilized precursor compounds against the surface of a substrate, said substrate having a sufficient temperature to decompose said volatilized precursor compounds whereby metal atoms contained within said volatilized precursor compounds are deposited as a metal oxide film upon the substrate is disclosed. In addition, a coated article comprising a multicomponent metal oxide film conforming to the surface of a substrate selected from the group consisting of silicon, magnesium oxide, yttrium-stabilized zirconium oxide, sapphire, or lanthanum gallate, said multicomponent metal oxide film characterized as having a substantially uniform thickness upon said substrate.

  16. Method to decrease loss of aluminum and magnesium melts

    DOE Patents [OSTI]

    Hryn, John N. (Naperville, IL); Pellin, Michael J. (Naperville, IL); Calaway, Jr., Wallis F. (Woodridge, IL); Moore, Jerry F. (Naperville, IL); Krumdick, Gregory K. (Crete, IL)

    2002-01-01

    A method to minimize oxidation of metal during melting processes is provided, the method comprising placing solid phase metal into a furnace environ-ment, transforming the solid-phase metal into molten metal phase having a molten metal surface, and creating a barrier between the surface and the environment. Also provided is a method for isolating the surface of molten metal from its environment, the method comprising confining the molten metal to a controlled atmos-phere, and imposing a floating substrate between the surface and the atmosphere.

  17. WREP SA

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematics And Statistics » USAJobs SearchAMERICA'S FUTURE. regulators02-03 AUDIT REPORT U.S. United States

  18. Ann bay lodyans 8 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml YON TOTI K AP CHANTE Vwala te gen yon neg yo rele... Gwoje. Msye te konn plante diri. Chak ane li pa janm ka fe bon rekot. Bet yo pran tout plezi yo nan manje jaden diri a. Se konsa, Gwoje blije mete veye pou trape vole k ap depafini jaden I la. Yon jou, pandan Pijon ak Kanna ap soti pou al nan jaden...

  19. Ann bay lodyans 5 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    Liben”) ki pare ti liv sa a. [Lawrence, Kan.] : Institute of Haitian Studies ; [Port-au-Prince] : Bon Nouvèl : Fondasyon Alfa Lwès, 2000. Terms of Use: http://www2.ku.edu/~scholar/docs/license.shtml ANN BAY LODYANS 5 Se Bryant Freeman ("Tonton Liben.... Tijo we yon tig ki te tonbe nan yon gwo twou. Li pa t kapab soti paske twou a fon. Kounye a tig la prizonye. Li di Tijo: "Ou se yon bon ti gason, ede m soti, souple." Tijo reponn: "Si mwen retire ou nan twou a, ou ap manje m." Tig la di: "O non...

  20. EIS-0241-SA-01: Supplement Analysis for the Hood River Fisheries Project,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 Peer ReviewUse2:Decision (April|2:-SA-01:Hood River County,

  1. EIS-0310-SA-02: Notice of Availability of Supplement Analysis and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based|Department of5 PeerRecord of3:2:-SA-01: SupplementRecord of

  2. Microsoft Word - Final SA-Nov 2012 Camera Ready.doc

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematicsEnergyInterested Parties - WAPAEnergy May2.docTechnicalBARACK OBAMA AND JOEEIS-0225-SA-05

  3. Vehicle Technologies Office Merit Review 2014: Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis

    Broader source: Energy.gov [DOE]

    Presentation given by INFINIUM, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about scale-up of magnesium...

  4. Vehicle Technologies Office Merit Review 2015: Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis

    Broader source: Energy.gov [DOE]

    Presentation given by INFINIUM, Inc. at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about scale-up of magnesium...

  5. Identifying barriers to the availability and use of Magnesium Sulphate Injection in resource poor countries: A case study in Zambia

    E-Print Network [OSTI]

    Ridge, Anna L; Bero, Lisa A; Hill, Suzanne R

    2010-01-01

    barriers to the availability and use of Magnesium Sulphateto identify barriers to the availability and use of MgSO4 infacilitators to the availability and use of MgSO4 identified

  6. The effects of exercise and dietary fat on calcium, magnesium, iron, and zinc on selected tissues in rats 

    E-Print Network [OSTI]

    Nguyen, Thuy Huong

    1989-01-01

    of the requirements for the degree MASTER OF SCIENCE December 1989 Major Subject: Nutrition THE EFFECTS OF EXERCISE AND DIETARY FAT ON CALCIUM, MAGNESIUM, IRON, AND ZINC ON SELECTED TISSUES IN RATS A Thesis by THUY HUONG NGUYEN Approved as to style... and content by: Karen S. ubena (Chair of Committee) L. yne Greene (Member) Barbara C. O' Brien (Member) Gary C. Smith (Head of Department) December 1989 ABSTRACT The Effects of Exercise and Dietary Fat on Calcium, Magnesium, Iron, and Zinc...

  7. The interaction of nitrogen and magnesium deficiences in certain aspects of the physiology of the cotton plant 

    E-Print Network [OSTI]

    Ghosh, Debabrata

    1961-01-01

    THE INTERACTION OF NITROGEN AND MAGNESIUM DEFICIENCIES IN CERTAIN ASPECTS OF THE PHYSIOLOGY OF THE COTTON PLANT A Thesis By DEBABRATA GHOSH Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1961 Major Subject: plant physiology THE INTERACTION OF NITROGEN AND MAGNESIUM DEFICIENCIES IN CERTAIN ASPECTS OF THE PHYSIOLOGY OF THE COTTON PLANT A Thesis By DEBABRATA...

  8. The determination of the bioavailability and the site of absorption in lambs fed different sources of magnesium 

    E-Print Network [OSTI]

    Hurley, Leigh Anne

    1988-01-01

    of the animal influences Ng avail- ability. Grace (1972) found that older cows exhibited a sharper decrease in plasma Ng than did younger cows in the early stages of lactation. Magnesium Supplementation The adequacy of dietary Mg levels is probably...THE DETERMINATION OF THE BIOAVAILABILITY AND THE SITE OF ABSORPTION IN LAMBS FED DIFFERENT SOURCES OF MAGNESIUM A Thesis I, EIGH ANNE HURLEY Submitted to the Of f ice of Graduate Studies Texas AAM UniversitY in partial fulfillment...

  9. Ash, calcium, phosphorus and magnesium content of the metacarpus of hereford cows under different nutritional and physiological conditions 

    E-Print Network [OSTI]

    Haque, Mozammel

    1967-01-01

    ASH, CALCIUM, PHOSPHORUS AND MAGNESIUM CONTENT OF THE METACARPUS OF HEREFORD COWS UNDER DIFFERENT NUTRITIONAL AND PHYSIOLOGICAL CONDITIONS A Thesis By MOZAMMEL HAQUE Submitted to the Graduate College of the Texas A&M University in partial... centages of Calcium, Phosphorus snd Magnesium in Bone Ash for Cows Gi;en Different Treatments During Pre- And Post-Partum Periods 22 10 Analysis of Variance oi Calcium in Bone Ash Dun an's )tultiple tvange Test 1'or Calcium in Bone Ash. Analy...

  10. The effect of rare earth elements on the texture and formability of asymmetrically rolled magnesium sheet

    SciTech Connect (OSTI)

    Alderman, Dr. Martyn [Magnesium Elektron North America; Cavin, Odis Burl [ORNL; Davis, Dr. Bruce [Magnesium Elektron North America; Muralidharan, Govindarajan [ORNL; Muth, Thomas R [ORNL; Peter, William H [ORNL; Randman, David [Magnesium Elektron North America; Watkins, Thomas R [ORNL

    2011-01-01

    The lack of formability is a serious issue when considering magnesium alloys for various applications. Standard symmetric rolling introduces a strong basal texture that decreases the formability; however, asymmetric rolling has been put forward as a possible route to produce sheet with weaker texture and greater ductility. It has also been shown in recent work that weaker textures can be produced through the addition of rare earth elements to magnesium alloys. Therefore, this study has been carried out to investigate the effect of rare earth additions on the texture changes during asymmetric rolling. Two alloys have been used, AZ31B and ZEK100. The effect that the rare earth additions have on the texture of asymmetrically rolled sheet and the subsequent changes in formability will be discussed.

  11. An examination of the relationship between calcium and magnesium and hypertension 

    E-Print Network [OSTI]

    Georghiades, Mary Elizabeth

    1988-01-01

    of MASTER QF SCIENCE May 1988 Major Subject. : Nutrition AN EXAMINATION OF THE RELATIONSHIP BETWEEN CALCIUM AND MAGNESIUM AND HYPERTENSION A Thesis by MARY ELIZABETH GEORGH I ADES Approved as to style and content by: Karen S. Kubena (Chair... of Committee) Gary Smith (Head of Department) j fj Joanne R. Lupton (Member) W. Alex Mclntosh (Member) May l988 ABSTRACT An Examination of the Relationship between Calcium and Hagnesiurn and Hypertension. (Nay 19BB) Nary Elizabeth Geor ghiades, B. S...

  12. Blood pressure and red blood cell magnesium, potassium, and calcium responses to dietary fats 

    E-Print Network [OSTI]

    Wehrman, Noreen Elaine

    1993-01-01

    influences the activities of several membrane transport systems, including the sodium pump which exchanges three sodium ions for two potassium ions, the Na+-K+-Cl cotransport system which moves these three ions across the cell membrane, and the K... for the degree of MASTER OF SCIENCE August 1993 Major Subject: Nutrition BLOOD PRESSURE AND RED BLOOD CELL MAGNESIUM, POTASSIUM, AND CALCIUM RESPONSES TO DIETARY FATS A Thesis by NOREEN ELAINE WEHRMAN Submitted to Texas A&M University in partial...

  13. Large scale two-dimensional arrays of magnesium diboride superconducting quantum interference devices

    SciTech Connect (OSTI)

    Cybart, Shane A. Dynes, R. C.; Wong, T. J.; Cho, E. Y.; Beeman, J. W.; Yung, C. S.; Moeckly, B. H.

    2014-05-05

    Magnetic field sensors based on two-dimensional arrays of superconducting quantum interference devices were constructed from magnesium diboride thin films. Each array contained over 30?000 Josephson junctions fabricated by ion damage of 30?nm weak links through an implant mask defined by nano-lithography. Current-biased devices exhibited very large voltage modulation as a function of magnetic field, with amplitudes as high as 8?mV.

  14. Yield Asymmetry Design of Magnesium Alloys by Integrated Computational Materials Engineering

    SciTech Connect (OSTI)

    Li, Dongsheng; Joshi, Vineet V.; Lavender, Curt A.; Khaleel, Mohammad A.; Ahzi, Said

    2013-11-01

    Deformation asymmetry of magnesium alloys is an important factor on machine design in automobile industry. Represented by the ratio of compressive yield stress (CYS) against tensile yield stress (TYS), deformation asymmetry is strongly related to microstructure, characterized by texture and grain size. Modified intermediate phi-model, a polycrystalline viscoplasticity model, is used to predict the deformation behavior of magnesium alloys with different grain sizes. Validated with experimental results, integrated computational materials engineering is applied to find out the route in achieving desired asymmetry by thermomechanical processing. In some texture, for example, rolled texture, CYS/TYS is smaller than 1 under different loading directions. In some texture, for example, extruded texture, asymmetry is large along normal direction. Starting from rolled texture, the asymmetry will increased to close to 1 along rolling direction after compressed to a strain of 0.2. Our model shows that grain refinement increases CYS/TYS. Besides texture control, grain refinement can also optimize the yield asymmetry. After the grain size decreased to a critical value, CYS/TYS reaches to 1 since CYS increases much faster than TYS. By tailoring the microstructure using texture control and grain refinement, it is achievable to optimize yield asymmetry in wrought magnesium alloys.

  15. Process for CO.sub.2 capture using a regenerable magnesium hydroxide sorbent

    DOE Patents [OSTI]

    Siriwardane, Ranjani V; Stevens, Jr., Robert W

    2013-06-25

    A process for CO.sub.2 separation using a regenerable Mg(OH).sub.2 sorbent. The process absorbs CO.sub.2 through the formation of MgCO.sub.3 and releases water product H.sub.2O. The MgCO.sub.3 is partially regenerated through direct contact with steam, which acts to heat the magnesium carbonate to a higher temperature, provide heat duty required to decompose the magnesium carbonate to yield MgO and CO.sub.2, provide an H.sub.2O environment over the magnesium carbonate thereby shifting the equilibrium and increasing the potential for CO.sub.2 desorption, and supply H.sub.2O for rehydroxylation of a portion of the MgO. The mixture is polished in the absence of CO.sub.2 using water product H.sub.2O produced during the CO.sub.2 absorption to maintain sorbent capture capacity. The sorbent now comprised substantially of Mg(OH).sub.2 is then available for further CO.sub.2 absorption duty in a cyclic process.

  16. Manufacturing of SiCp Reinforced Magnesium Composite Tubes by Hot Extrusion Processes

    SciTech Connect (OSTI)

    Hwang, Yeong-Maw [National Sun Yat-Sen University-Department of Mechanical and Electro-mechanical Engineering, No.70, Lien-Hai Rd., Kaohsiung, Taiwan (China); Huang, Song-Jeng; Huang, Yu-San [National Chung Cheng University-Department of Mechanical Engineering, 168 University Rd. Ming-Hsiung, ChiaYi, Taiwan (China)

    2011-05-04

    Magnesium alloys have higher specific strength compared with other metals, such as aluminum, copper and steel. Nevertheless, their ductility is still not good for further metal forming and their strength is not large enough for real structure applications. The aim of this paper is to develop magnesium alloy composite tubes reinforced with SiC particulates by the stir-casting method and hot extrusion processes. At first, AZ61/SiCp composite ingots reinforced with 5 wt% SiC particulates are fabricated by the melt-stirring technique. Then, finite element simulations are conducted to analyze the plastic flow of magnesium alloy AZ61 within the die and the temperature distribution of the products. AZ61/SiCp composite tubes are manufactured by hot extrusion using a specially designed die-set for obtaining uniform thickness distribution tubes. Finally, the mechanical properties of the reinforced AZ61/SiCp composite and Mg alloy AZ61 tubes are compared with those of the billets to manifest the advantages of extrusion processes and reinforcement of SiC particulates. The microstructures of the billet and extruded tubes are also observed. Through the improvement of the strength of the tube product, its life cycle can be extended and the energy consumption can be reduced, and eventually the environmental sustainability is achieved.

  17. Characterization and Surface Treatment of Materials Used in MADEAL S.A. Industry Productive Process of Rims by Plasma Assisted Repetitive Pulsed Arcs Technique

    SciTech Connect (OSTI)

    Jimenez, H.; Salazar, V. H.; Devia, A.; Jaramillo, S.; Velez, G.

    2006-12-04

    A study of materials used in the molds production to aluminium rims manufacture in the MADEAL S.A. factory was carried out for apply a plasma assisted surface treatment consists in growing TiAlN hard coatings that it protects this molds in the productive process. This coating resists high oxidation temperatures, of the other of 800 deg. C, high hardness (2800 Vickers) and low friction coefficient. A plasma assisted repetitive pulsed arcs mono-evaporator system was used in the grow of the TiAlN coatings, the TiAlN target is a sinterized 50% Ti and 50% Al, in the substrate they were used two types of steel that compose the molds injection pieces for the rims production. These materials were subjected to linear and fluctuating thermal changes in the Bruker axs X-Ray diffractometer temperature chamber, what simulated the molds thermal variation in the rims production process and they were compared with TiAlN coatings subjected to same thermal changes. The Materials characterization, before and later of thermal process, was carried out using XRD, SPM and EDS techniques, to analyze the crystallographic, topographic and chemical surface structure behaviours.

  18. Ann bay lodyans 7 / se Bryant Freeman ("Tonton Liben") ki pare ti liv sa a

    E-Print Network [OSTI]

    Freeman, Bryant C.

    2000-01-01

    la. Ti nonm Ian pa souke ko I tou. Wa a mete de men nan tet pou I rele. Konsa Wa a fe yo pran Malis, yo mete I nan yon sak, yo pandye I nan yon pyebwa annatandan yo voye I nan lanme. Malis t ap kalkile kisa pou I ta fe pou I chape, le de vole...." De vole yo tire oso, e se vole ki pi malen an ki antre nan sak la. Se konsa Malis rive chape anko. Sa gen kek jou depi yo te voye sak la nan lanme. Wa a t ap fe yon pwomnad, li pase devan kay Malis. Le I voye je I nan lakou a, sezisman manke touye...

  19. CarolinaTiesA newsletter for University of South Carolina parents www.sa.sc.edu/parents

    E-Print Network [OSTI]

    CarolinaTiesA newsletter for University of South Carolina parents www.sa.sc.edu/parents In this ever-changing economy, more University of South Carolina students are searching for and accepting part House Information Center #12;Dear friends: In this issue of Carolina Ties, we're providing you

  20. CarolinaTiesA newsletter for University of South Carolina parents www.sa.sc.edu/parents

    E-Print Network [OSTI]

    CarolinaTiesA newsletter for University of South Carolina parents www.sa.sc.edu/parents Nestled a few recommendations. "Students should visit the Columbia Visitor's Bureau (CVB) website, www up-to-date with the CVB's online calendar of events, as well as like "Experience Columbia, SC

  1. Life Sciaacse vol. 17, pp . 323-328 Pargamoa Prass Printed in the D .S.A.

    E-Print Network [OSTI]

    Hammock, Bruce D.

    Life Sciaacse vol. 17, pp . 323-328 Pargamoa Prass Printed in the D .S.A. NADPH DEPENDENT is NADPH dependent, requires molecular ozygen and is inhibited by carbon monozids, methylene blna, SEF S25A be a useful peat control tool, especially if the larval stage wre dsstructiva. Aa a possible step

  2. Sulfate adsorption and its relationships with properties of representative soils of the Sa~o Paulo State, Brazil

    E-Print Network [OSTI]

    Sparks, Donald L.

    State, Brazil M.E. Alves, A. Lavorenti* Departamento de Cie^ncias Exatas, Escola Superior de Agricultura ``Luiz de Queiroz''--ESALQ/USP, Caixa Postal 09, 13418-900, Piracicaba (SP), Brazil Received 27 August, electrochemical and mineralogical properties of representative soils of the Sa~o Paulo State, Brazil, were

  3. Photo-oxidation catalysts

    DOE Patents [OSTI]

    Pitts, J. Roland (Lakewood, CO); Liu, Ping (Irvine, CA); Smith, R. Davis (Golden, CO)

    2009-07-14

    Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

  4. Magnesium deficiency and type of protein during gestation and lactation in rats 

    E-Print Network [OSTI]

    Holmes, Kathryn Ellen Hughes

    1988-01-01

    those fed the CD diet, but only for one day (day 8). No physical changes were noted during week 1 of lactation. One dam from group CD exhibited bright pink ears and a slightly pink tail during week 2 of lactation, but these signs were not apparent... with deficient males produced smaller litters. Restricted diets during gestation and lactation in rats have also been shown to cause reduced serum and bone magnesium levels in dams and reduced viability and body weights of offspring (2). Ma nesium and Protein...

  5. Phase Discrimination through Oxidant Selection for Iron Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Phase Discrimination through Oxidant Selection for Iron Oxide Ultrathin Films Home > Research > ANSER Research Highlights > Phase Discrimination through Oxidant Selection for Iron...

  6. Cerium Oxide Coating for Oxidation Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Award In order to produce power more efficiently and cleanly, the next generation of power plant boilers, turbines, solid oxide fuel cells (SOFCs) and other essential equipment...

  7. Effect of dietary magnesium and calcium on blood lipids and minerals in tissues in rats fed a high fat diet 

    E-Print Network [OSTI]

    Conboy-Downs, Jean

    1991-01-01

    EFFECT OF DIETARY MAGNESIUM AND CALCIUM ON BLOOD LIPIDS AND MINERALS ZN TISSUES IN BATS FED A HIGH FAT DIET A Thesis by JEAN CONBOY-DONNS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 1991 Major Subject: Nutrition EFFECT OF DIETARY MAGNESIUM AND CALCIUM ON BLOOD LIPZDS AND MZNERALS ZN TISSUES IN RATS FED A BIGS FAT DIET A Thesis by JEAN CONBOY-DOWNS Approved as to style...

  8. The effects of a marginal intake of magnesium with soy protein concentrate on growth, gestation, and lactation in the rat 

    E-Print Network [OSTI]

    McLaughlin, Cynthia Anne

    1986-01-01

    THE EFFECTS OF A MARGINAL INTAKE OF MAGNESIUM WITH SOY PROTEIN CONCENTRATE ON GROWTH, GESTATION, AND LACTATION IN THE RAT A Thesis by CYNTHIA ANNE MCLAUGHLIN Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 19B6 Major Subject: Nutrrtion THE EFFECTS OF A MARGINAL INTAKE OF MAGNESIUM WITH SOY PROTEIN CONCENTRATE ON GROWTH, GESTATION, AND LACTATION IN THE RAT A Thesis by CYNTHIA ANNE MCLAUGHLIN Approved...

  9. The effect of a prolonged magnesium restriction on the humoral immune response in maternal rats and their offspring 

    E-Print Network [OSTI]

    Cohill, Diane T

    1987-01-01

    TIIE EFFECT 0F A PR0L0NGED MAGNESIUM RESTRI CTI0N ON THE HUMORAL IMMUNE RESPONSE IN HATERHAL RATS AHD THEIR OFFSPRING A Thesis by DIANE T. COHILL Submitted to the Graduate College of Texas ASM University in Partial fulfillment... of the requirements for the degree of MASTER OF SC IENCE May 1987 Major Subject: Nutrition THE EFFECT OF A PROLONGED MAGNESIUM RESTRICTION ON THE HUMORAL IMMUNE RESPONSE IN MATERNAL RATS AND THEIR OFFSPRING A Thesis by DIANE T. COHILL Approved as to sty le...

  10. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide

    SciTech Connect (OSTI)

    Jiang, Weilin; Jung, Hee Joon; Kovarik, Libor; Wang, Zhaoying; Roosendaal, Timothy J.; Zhu, Zihua; Edwards, Danny J.; Hu, Shenyang Y.; Henager, Charles H.; Kurtz, Richard J.; Wang, Yongqiang

    2015-01-01

    As a candidate material for fusion reactor applications, silicon carbide (SiC) undergoes transmutation reactions under high-energy neutron irradiation with magnesium as the major metallic transmutant; the others include aluminum, beryllium and phosphorus in addition to helium and hydrogen gaseous species. The impact of these transmutants on SiC structural stability is currently unknown. This study uses ion implantation to introduce Mg into SiC. Multiaxial ion-channeling analysis of the as-produced damage state suggests that there are preferred Si <100> interstitial splits. The microstructure of the annealed sample was examined using high-resolution scanning transmission electron microscopy. The results show a high concentration of likely non-faulted tetrahedral voids and possible stacking fault tetrahedra near the damage peak. In addition to lattice distortion, dislocations and intrinsic and extrinsic stacking faults are also observed. Magnesium in 3C-SiC prefers to substitute for Si and it forms precipitates of cubic Mg2Si and tetragonal MgC2. The diffusion coefficient of Mg in 3C-SiC single crystal at 1573 K has been determined to be 3.8±0.4×10e-19 m2/sec.

  11. Synthesis, deposition and characterization of magnesium hydroxide nanostructures on zeolite 4A

    SciTech Connect (OSTI)

    Koh, Pei-Yoong; Yan, Jing; Ward, Jason; Koros, William J.; Teja, Amyn S.; Xu, Bo

    2011-03-15

    Research highlights: {yields} Reports a simple precipitation-growth method to produce nanostructures of Mg(OH){sub 2} on the surface of zeolite 4A. {yields} Able to control the growth of the nanostructures by manipulating the experimental procedure. {yields} Able to deposit Mg(OH){sub 2} onto specific sites namely bridging hydroxyl protons (SiOHAl) on the surface of zeolite 4A. -- Abstract: The precipitation and self-assembly of magnesium hydroxide Mg(OH){sub 2} nanopetals on dispersed zeolite 4A particles was investigated. Mg(OH){sub 2}/zeolite nanocomposites were produced from magnesium chloride solutions and characterized via X-ray powder diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), Fourier transform infrared analysis (FTIR), and solid state NMR. It was determined that Mg(OH){sub 2} interacted with bridging hydroxyl protons (SiOHAl) on the zeolite surface, but not with silanol or aluminol groups. NMR analysis showed that 13% of the tetrahedral Al sites on the zeolite were converted to octahedral Al. The zeolite structure and crystallinity remained intact after treatment, and no dealumination reactions were detected. This suggests that the deposition-precipitation process at ambient conditions is a facile method for controlling Mg(OH){sub 2} nanostructures on zeolites.

  12. Manufacture of gradient micro-structures of magnesium alloys using two stage extrusion dies

    SciTech Connect (OSTI)

    Hwang, Yeong-Maw; Huang, Tze-Hui [Department of Mechanical and Electro-Mechanical Engineering, National Sun Yat-Sen University, No. 70, Lien-Hai Rd., Kaohsiung, 804, Taiwan (China); Alexandrov, Sergei [Institute for Problems in Mechanics, Russian Academy of Sciences, Moscow (Russian Federation); Naimark, Oleg Borisovich [Institute of Continuous Media Mechanics, Russian Academy of Sciences, Perm (Russian Federation); Jeng, Yeau-Ren [Department of Mechanical Engineering and Advanced Institute of Manufacturing with High-tech Innovations, National Chung Cheng University, Ming-Hsiung, Chia-Yi 621, Taiwan (China)

    2013-12-16

    This paper aims to manufacture magnesium alloy metals with gradient micro-structures using hot extrusion process. The extrusion die was designed to have a straight channel part combined with a conical part. Materials pushed through this specially-designed die generate a non-uniform velocity distribution at cross sections inside the die and result in different strain and strain rate distributions. Accordingly, a gradient microstructure product can be obtained. Using the finite element analysis, the forming temperature, effective strain, and effective strain rate distributions at the die exit were firstly discussed for various inclination angles in the conical die. Then, hot extrusion experiments with a two stage die were conducted to obtain magnesium alloy products with gradient micro-structures. The effects of the inclination angle on the grain size distribution at cross sections of the products were also discussed. Using a die of an inclination angle of 15°, gradient micro-structures of the grain size decreasing gradually from 17 ?m at the center to 4 ?m at the edge of product were achieved.

  13. Generalized Uhlenbeck-Goudsmit hypothesis 'Magnetic' S^{a} and 'Electric' Z^{a} Spins

    E-Print Network [OSTI]

    Tomislav Ivezic

    2010-03-23

    In this paper, the connection between the dipole moment tensor D^{ab} and the spin four-tensor S^{ab} is formulated in the form of the generalized Uhlenbeck-Goudsmit hypothesis, D^{ab}=g_{S}S^{ab}. It is also found that the spin four-tensor S^{ab} can be decomposed into two 4-vectors, the usual `space-space' intrinsic angular momentum S^{a}, which will be called `magnetic' spin (mspin), and a new one, the `time-space' intrinsic angular momentum Z^{a}, which will be called `electric' spin (espin). Both spins are equally good physical quantities. Taking into account the generalized Uhlenbeck-Goudsmit hypothesis, the decomposition of S^{ab} and the decomposition of D^{ab} into the dipole moments m^{a} and d^{a}, we find that an electric dipole moment (EDM) of a fundamental particle, as a four-dimensional (4D) geometric quantity, is determined by Z^{a} and not, as generally accepted, by the spin $\\mathbf{S}$ as a 3-vector. Also it is shown that neither the T inversion nor the P inversion are good symmetries in the 4D spacetime. In this geometric approach, only the world parity W, Wx^{a}=-x^{a}, is well defined in the 4D spacetime. Some consequences for elementary particle theories and experiments that search for EDM are briefly discussed.

  14. Leak before break evaluation for main steam piping system made of SA106 Gr.C

    SciTech Connect (OSTI)

    Yang, Kyoung Mo; Jee, Kye Kwang; Pyo, Chang Ryul; Ra, In Sik

    1997-04-01

    The basis of the leak before break (LBB) concept is to demonstrate that piping will leak significantly before a double ended guillotine break (DEGB) occurs. This is demonstrated by quantifying and evaluating the leak process and prescribing safe shutdown of the plant on the basis of the monitored leak rate. The application of LBB for power plant design has reduced plant cost while improving plant integrity. Several evaluations employing LBB analysis on system piping based on DEGB design have been completed. However, the application of LBB on main steam (MS) piping, which is LBB applicable piping, has not been performed due to several uncertainties associated with occurrence of steam hammer and dynamic strain aging (DSA). The objective of this paper is to demonstrate the applicability of the LBB design concept to main steam lines manufactured with SA106 Gr.C carbon steel. Based on the material properties, including fracture toughness and tensile properties obtained from the comprehensive material tests for base and weld metals, a parametric study was performed as described in this paper. The PICEP code was used to determine leak size crack (LSC) and the FLET code was used to perform the stability assessment of MS piping. The effects of material properties obtained from tests were evaluated to determine the LBB applicability for the MS piping. It can be shown from this parametric study that the MS piping has a high possibility of design using LBB analysis.

  15. Neutron and X-ray diffraction and empirical potential structure refinement modelling of magnesium stabilised amorphous calcium

    E-Print Network [OSTI]

    Benning, Liane G.

    Neutron and X-ray diffraction and empirical potential structure refinement modelling of magnesium online xxxx Keywords: Amorphous calcium carbonate; EPSR modelling; Neutron diffraction; X-ray diffraction Amorphous calcium carbonate (ACC) plays a key role in biomineralisation processes in sea organisms. Neutron

  16. In Situ Measurement of Magnesium Carbonate Formation from CO2 Using Static High-Pressure and -Temperature 13

    E-Print Network [OSTI]

    Skemer, Philip

    method that possesses the ability to monitor the chemical evolution of supercritical CO2 in relevant(OH)2, with supercritical CO2 (88 bar) in aqueous conditions at 80 °C. The in situ conversion of CO2In Situ Measurement of Magnesium Carbonate Formation from CO2 Using Static High

  17. Methane oxidation rates by AMS

    E-Print Network [OSTI]

    Pack, M; Heintz, M; ReeburGh, WS; Trumbore, SE; Valentine, DL; Xu, X

    2009-01-01

    second case. Number of cases Methane oxidation rates by AMSIn the marine environment methane (CH 4 ) oxidation consumes

  18. A empresa PETRLEO BRASILEIRO S.A. (PETROBRAS) realizou no primeiro semestre deste ano um processo seletivo pblico para provimento de vagas e formao de cadastro (Edital

    E-Print Network [OSTI]

    Paraná, Universidade Federal do

    A empresa PETRÓLEO BRASILEIRO S.A. (PETROBRAS) realizou no primeiro semestre deste ano um processo quinto lugar em Concurso da Petrobras. Figura 2: Guilherme Boemeke, Vitor Ferreira do Nascimento (os dois

  19. Partial oxidation catalyst

    DOE Patents [OSTI]

    Krumpelt, Michael (Naperville, IL); Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Doshi, Rajiv (Downers Grove, IL)

    2000-01-01

    A two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion. The dehydrogenation portion is a group VIII metal and the oxide-ion conducting portion is selected from a ceramic oxide crystallizing in the fluorite or perovskite structure. There is also disclosed a method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

  20. Effects of soil treatments supplemented with two rates of magnesium sulfate on the availability of soil nutrients and on the yield and chemical composition of coastal Bermuda grass 

    E-Print Network [OSTI]

    Evatt, Nathan S

    1951-01-01

    'ZATZ ON THE AVAILABILITY OF SOIL NUTRIENTS AND ON TH YIELD AND CHENICAL COMPOSITICN GF CO. iSTAL BERNUDA GHASS INTRODUCTION It is known that magnesium is one of' the elements essential for plant growth; however much is to be learned concerning its specific functions... within the plant, Host Texas soils are not deficient, in magnesium (23). Magnesium is reported to be a carrier of the phos- phorus used by the plant. It is entirely possible that the failure to obtain crops of higher phosphorus content upon...

  1. Analysis of the potential for new automotive uses of wrought magnesium

    SciTech Connect (OSTI)

    Gaines, L.; Cuenca, R.; Wu, S.; Stodolsky, F.

    1996-02-01

    The Center for Transportation Research at Argonne National Laboratory has performed a study for the Lightweight Materials Program within the US Department of Energy`s Office of Transportation Materials to evaluate the suitability of wrought magnesium and its alloys to replace steel or aluminum for automotive structural and sheet applications. Vehicle weight reduction is one of the major means available for improving automotive fuel efficiency. Although high-strength steels, Al, and polymers are already being used to achieve significant weight reductions, substantial additional weight reductions could be achieved by increased use of Mg (whose density is less than one-fourth that of steel and only two-thirds that of Al). This study shows that Mg sheet could be used in automotive body nonstructural and semistructural applications, whereas extrusions could be used in such structural applications as spaceframes. The primary barrier to such uses of wrought Mg is high cost.

  2. The effect of magnesium added at C{sub 60}/Rubrene heterointerfaces

    SciTech Connect (OSTI)

    Cheng, Chiu-Ping; Lee, Cheng-Wei; Chu, Yu-Ya [Department of Electrophysics, National Chiayi University, Chiayi 60004, Taiwan (China)] [Department of Electrophysics, National Chiayi University, Chiayi 60004, Taiwan (China); Wei, Ching-Hsuan [Department of Material Science, National Chiao-Tung University, Hsinchu 30076, Taiwan (China)] [Department of Material Science, National Chiao-Tung University, Hsinchu 30076, Taiwan (China); Pi, Tun-Wen [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China)] [National Synchrotron Radiation Research Center, Hsinchu 30076, Taiwan (China)

    2013-12-28

    This study examines the effect of adding magnesium (Mg) at C{sub 60}/rubrene heterointerfaces by using synchrotron-radiation photoemission spectroscopy. The heterointerface was obtained by depositing C{sub 60} on a 4-Å Mg/rubrene surface. The photoemission spectra showed that the added Mg preferentially interacts with and transfers negative charges to C{sub 60}. The interfacial dipole potential was significantly enlarged, as was the separation between the lowest unoccupied molecular orbital of C{sub 60} and the highest occupied molecular orbital of rubrene. The results demonstrate that the addition of Mg should be an effective method for improving the efficiency of light- and current-generating devices.

  3. ZIRCONIUM OXIDE NANOSTRUCTURES PREPARED BY ANODIC OXIDATION

    SciTech Connect (OSTI)

    Dang, Y. Y.; Bhuiyan, M.S.; Paranthaman, M. P.

    2008-01-01

    Zirconium oxide is an advanced ceramic material highly useful for structural and electrical applications because of its high strength, fracture toughness, chemical and thermal stability, and biocompatibility. If highly-ordered porous zirconium oxide membranes can be successfully formed, this will expand its real-world applications, such as further enhancing solid-oxide fuel cell technology. Recent studies have achieved various morphologies of porous zirconium oxide via anodization, but they have yet to create a porous layer where nanoholes are formed in a highly ordered array. In this study, electrochemical methods were used for zirconium oxide synthesis due to its advantages over other coating techniques, and because the thickness and morphology of the ceramic fi lms can be easily tuned by the electrochemical parameters, such as electrolyte solutions and processing conditions, such as pH, voltage, and duration. The effects of additional steps such as pre-annealing and post-annealing were also examined. Results demonstrate the formation of anodic porous zirconium oxide with diverse morphologies, such as sponge-like layers, porous arrays with nanoholes ranging from 40 to 75 nm, and nanotube layers. X-ray powder diffraction analysis indicates a cubic crystallographic structure in the zirconium oxide. It was noted that increased voltage improved the ability of the membrane to stay adhered to the zirconium substrate, whereas lower voltages caused a propensity for the oxide fi lm to fl ake off. Further studies are needed to defi ne the parameters windows that create these morphologies and to investigate other important characteristics such as ionic conductivity.

  4. Oxidation Resistant Graphite Studies

    SciTech Connect (OSTI)

    W. Windes; R. Smith

    2014-07-01

    The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

  5. METAL OXIDE NANOPARTICLES

    SciTech Connect (OSTI)

    FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

    2007-10-01

    This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

  6. Barium oxide, calcium oxide, magnesia, and alkali oxide free glass

    DOE Patents [OSTI]

    Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

    2013-09-24

    A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

  7. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott (Dublin, CA); Wang, Ruiping (Fremont, CA); Derouane, Eric (Liverpool, GB)

    2003-01-01

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  8. The effect of modifications of dietary fat, fiber and sodium with magnesium deficiency on serum lipids and minerals, tissue and femur minerals and femur load force 

    E-Print Network [OSTI]

    Howe, Cathlyn Ann

    1992-01-01

    concentration of selected tissues and femur, and load force of femurs. The minerals investigated were magnesium, calcium, phosphorus and zinc. The control (C) diet was based upon the AIM-76 diet formulation; the American (A) included average fat, fiber... in those in the A and R groups, respectively. Renal calcium was not affected by magnesium deficiency except in the rats fed the recommended diets. The RL rats had higher renal calcium than R animals. Cardiac mineral concentrations were higher in the C...

  9. Mineral interactions and absorption in the equine digestive tract: calcium, phosphorus, and magnesium interaction with aluminum, and calcium digestibility of alfalfa in ponies 

    E-Print Network [OSTI]

    Kapusniak, Linda J.

    1987-01-01

    MINERAL INTERACTIONS AND ABSORPTION IN THE EQUINE DIGESTIVE TRACT: CALCIUM, PHOSPHORUS, AND MAGNESIUM INTERACTION WITH ALUMINUM, AND CALCIUM DIGESTIBILITY OF ALFALFA IN PONIES A Thesis by LINDA J. KAPUSN IAK Subnitted to the Graduate College... of Texas ARM University. in partial fulfillment of the requirenent for the degree of MASTER OF SCIENCE August 1987 Major Subject: Nutrition MINERAL INTER4CTIONS AND ABSORPTION IN THE EQUINE DIGESTIVE TR4CT: C4LCIUM, PHOSPHORUS, AND MAGNESIUM...

  10. Efficient reversible electrodes for solid oxide electrolyzer cells

    DOE Patents [OSTI]

    Elangovan, Singaravelu (South Jordan, UT); Hartvigsen, Joseph J. (Kaysville, UT)

    2011-07-12

    An electrolyzer cell is disclosed which includes a cathode to reduce an oxygen-containing molecule, such as H2O, CO2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H2, CO, or a combination thereof. An electrolyte is coupled to the cathode to transport the oxygen ion to an anode. The anode is coupled to the electrolyte to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(1-x)Lax)(z-y)A'yBO(3-.differential.), wherein 0.ltoreq.x.ltoreq.0.5, 0.ltoreq.y.ltoreq.0.5, and 0.8.ltoreq.z.ltoreq.1.1. In another embodiment, the cathode includes an electron-conducting phase that contains nickel oxide intermixed with magnesium oxide.

  11. Efficient reversible electrodes for solid oxide electrolyzer cells

    DOE Patents [OSTI]

    Elangovan, S.; Hartvigsen, Joseph J.; Zhao, Feng

    2013-01-15

    An electrolyzer cell is disclosed which includes a cathode to reduce an oxygen-containing molecule, such as H2O, CO.sub.2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H.sub.2, CO, or a combination thereof. An electrolyte is coupled to the cathode to transport the oxygen ion to an anode. The anode is coupled to the electrolyte to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(.sub.1-x)La.sub.x)(z-y)A'.sub.yBO(3-.differential.), wherein 0oxide intermixed with magnesium oxide.

  12. Displacement of the proton in hydrogen-bonded complexes of hydrogen fluoride by beryllium and magnesium ions

    SciTech Connect (OSTI)

    McDowell, Sean A. C. [Department of Biological and Chemical Sciences, University of the West Indies, Cave Hill Campus (Barbados)

    2009-05-14

    The displacement of the proton by a beryllium ion and by a magnesium ion from hydrogen-bonded complexes of hydrogen fluoride, of varying hydrogen bond strengths, was investigated theoretically using ab initio methods. Stable metal-containing species were obtained from all of the hydrogen-bonded complexes regardless of the strength of the hydrogen bond. It was found that the beryllium ion was energetically very effective in displacing the proton from hydrogen bonds, whereas the magnesium ion was unable to do so. The high stability of the beryllium-containing complexes is mainly due to the strong electrostatic bonding between the beryllium and fluoride atoms. This work supports the recent finding from a multidisciplinary bioinorganic study that beryllium displaces the proton in many strong hydrogen bonds.

  13. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

    1988-01-01

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  14. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Nyaiesh, A.R.; Garwin, E.L.

    1986-08-04

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  15. Energy and Technolgy Assessment of Zinc and Magnesium Casting Plants, Technical Report Close-out, August 25,2006

    SciTech Connect (OSTI)

    Twin City Die Castings Company; Tom Heider; North American Die Castings Association

    2006-08-25

    Twin City Die Castings Company of Minneapolis, Minnesota, Twin City Die Castings Company was awarded project No. DE-FG36-05GO15097 to perform plant wide assessments of ten (10) die casting facilities that produce zinc and magnesium alloy castings in order to determine improvements and potential cost savings in energy use. Mr. Heider filled the role of team leader for the project and utilized the North American Die Casting Association (NADCA) to conduct audits at team participant plants so as to hold findings specific to each plant proprietary. The intended benefits of the project were to improve energy use through higher operational and process efficiency for the plants assessed. An improvement in energy efficiency of 5 – 15% was targeted. The primary objectives of the project was to: 1) Expand an energy and technology tool developed by the NADCA under a previous DOE project titled, “Energy and Technology Assessment for Die Casting Plants” for assessing aluminum die casting plants to be more specifically applicable to zinc and magnesium die casting facilities. 2) Conduct ten (10) assessments of zinc and magnesium die casting plants, within eight (8) companies, utilizing the assessment tool to identify, evaluate and recommend opportunities to enhance energy efficiency, minimize waste, and improve productivity. 3) Transfer the assessment tool to the die casting industry at large.

  16. Surface composition, microstructure and corrosion resistance of AZ31 magnesium alloy irradiated by high-intensity pulsed ion beam

    SciTech Connect (OSTI)

    Li, P., E-mail: pli@sqnc.edu.cn [Department of Physics and Information Engineering, Shangqiu Normal University, Shangqiu 476000 (China); Surface Engineering Laboratory, School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024 (China); Lei, M.K., E-mail: surfeng@dlut.edu.cn [Surface Engineering Laboratory, School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024 (China); Zhu, X.P. [Surface Engineering Laboratory, School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024 (China)

    2011-06-15

    High-intensity pulsed ion beam (HIPIB) irradiation of AZ31 magnesium alloy is performed and electrochemical corrosion experiment of irradiated samples is carried out by using potentiodynamic polarization technology in order to explore the effect of HIPIB irradiation on corrosion resistance of magnesium alloy. The surface composition, cross-sectional morphology and microstructure are characterized by using electron probe microanalyzer, optical microscope and transmission electron microscope, respectively. The results indicated that HIPIB irradiation leads to a significant improvement in corrosion resistance of magnesium alloy, in terms of the considerable increase in both corrosion potential and pitting breakdown potential. The microstructural refinement and surface purification induced by HIPIB irradiation are responsible for the improved corrosion resistance. - Research Highlights: {yields} A modified layer about 30 {mu}m thick is obtained by HIPIB irradiation. {yields} Selective ablation of element/impurity phase having lower melting point is observed. {yields} More importantly, microstructural refinement occurred on the irradiated surface. {yields} The modified layer exhibited a significantly improved corrosion resistance. {yields} Improved corrosion resistance is ascribed to the combined effect induced by HIPIB.

  17. Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide

    E-Print Network [OSTI]

    Kim, Sehun

    Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide catalytic systems.12,13 On the other hand, the reduced graphene oxide (rGO) is functionalized graphene Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO

  18. Effects of Pore Distributions on Ductility of Thin-Walled High Pressure Die-Cast Magnesium

    SciTech Connect (OSTI)

    Choi, Kyoo Sil; Li, Dongsheng; Sun, Xin; Li, Mei; Allison, John

    2013-06-01

    In this paper, a microstructure-based three-dimensional (3D) finite element modeling method is adopted to investigate the effects of porosity in thin-walled high pressure die-cast (HPDC) Magnesium alloys on their ductility. For this purpose, the cross-sections of AM60 casting samples are first examined using optical microscope and X-ray tomography to obtain the general information on the pore distribution features. The experimentally observed pore distribution features are then used to generate a series of synthetic microstructure-based 3D finite element models with different pore volume fractions and pore distribution features. Shear and ductile damage models are adopted in the finite element analyses to induce the fracture by element removal, leading to the prediction of ductility. The results in this study show that the ductility monotonically decreases as the pore volume fraction increases and that the effect of ‘skin region’ on the ductility is noticeable under the condition of same local pore volume fraction in the center region of the sample and its existence can be beneficial for the improvement of ductility. The further synthetic microstructure-based 3D finite element analyses are planned to investigate the effects of pore size and pore size distribution.

  19. CHARACTERIZATION AND FORMABILITY OF CONTINUOUS-CAST AZ31B MAGNESIUM ALLOY SHEETS

    SciTech Connect (OSTI)

    Rohatgi, Aashish; Herling, Darrell R.; Nyberg, Eric A.

    2009-09-24

    The goal of this work is to understand the inter-relationship between the initial properties of continuous-cast magnesium alloy (AZ31B) sheets and their subsequent formability and post-formed mechanical performance for use in cost-effective, lightweight, automotive body panels. As-received sheets, provided by the Automotive Metals Division (AMD-602) team, were characterized by surface roughness measurements using mechanical profilometry. The arithmetic mean deviation of profile (Ra) and the maximum two-point height of profile (Ry) of the as-received sheets ranged from ~0.2-2 ?m and ~2-15 ?m, respectively. Several commercial lubricants were evaluated by thermal analysis and the liquid phase of the lubricants was found to evaporate/decompose upon heating leaving behind a solid residue upon heating to temperatures exceeding ~125-150°C. Elevated temperature bending-under-tension (BUT) friction tests were conducted at 350°C and the coefficient-of-friction values ranged from a minimum of ~0.1 (for tungsten disulfide lubricant) to ~0.7 when no lubricant was used. These results, in conjunction with those from the forming trials conducted by the AMD-602 team, will be eventually used to determine the role of sheet-die friction in determining the formability of AZ31B sheets.

  20. Assessment of Computer Simulation Software and Process Data for High Pressure Die Casting of Magnesium

    SciTech Connect (OSTI)

    Sabau, Adrian S; Hatfield, Edward C; Dinwiddie, Ralph Barton; Kuwana, Kazunori; Viti, Valerio; Hassan, Mohamed I; Saito, Kozo

    2007-09-01

    Computer software for the numerical simulation of solidification and mold filling is an effective design tool for cast structural automotive magnesium components. A review of commercial software capabilities and their validation procedures was conducted. Aside form the software assessment, the program addressed five main areas: lubricant degradation, lubricant application, gate atomization, and heat transfer at metal mold interfaces. A test stand for lubricant application was designed. A sensor was used for the direct measurement of heat fluxes during lubricant application and casting solidification in graphite molds. Spray experiments were conducted using pure deionized water and commercial die lubricants. The results show that the sensor can be used with confidence for measuring heat fluxes under conditions specific to the die lube application. The data on heat flux was presented in forms suitable for use in HPDC simulation software. Severe jet breakup and atomization phenomena are likely to occur due to high gate velocities in HPDC. As a result of gate atomization, droplet flow affects the mold filling pattern, air entrapment, skin formation, and ensuing defects. Warm water analogue dies were designed for obtaining experimental data on mold filling phenomena. Data on break-up jet length, break-up pattern, velocities, and droplet size distribution were obtained experimentally and was used to develop correlations for jet break-up phenomena specific to die casting gate configurations.

  1. Magnesium and Manganese Silicides For Efficient And Low Cost Thermo-Electric Power Generation

    SciTech Connect (OSTI)

    Trivedi, Sudhir B.; Kutcher, Susan W.; Rosemeier, Cory A.; Mayers, David; Singh, Jogender

    2013-12-02

    Thermoelectric Power Generation (TEPG) is the most efficient and commercially deployable power generation technology for harvesting wasted heat from such things as automobile exhausts, industrial furnaces, and incinerators, and converting it into usable electrical power. We investigated the materials magnesium silicide (Mg2Si) and manganese silicide (MnSi) for TEG. MgSi2 and MnSi are environmentally friendly, have constituent elements that are abundant in the earth's crust, non-toxic, lighter and cheaper. In Phase I, we successfully produced Mg2Si and MnSi material with good TE properties. We developed a novel technique to synthesize Mg2Si with good crystalline quality, which is normally very difficult due to high Mg vapor pressure and its corrosive nature. We produced n-type Mg2Si and p-type MnSi nanocomposite pellets using FAST. Measurements of resistivity and voltage under a temperature gradient indicated a Seebeck coefficient of roughly 120 V/K on average per leg, which is quite respectable. Results indicated however, that issues related to bonding resulted in high resistivity contacts. Determining a bonding process and bonding material that can provide ohmic contact from room temperature to the operating temperature is an essential part of successful device fabrication. Work continues in the development of a process for reproducibly obtaining low resistance electrical contacts.

  2. Non-LTE Abundances of Magnesium, Aluminum and Sulfur in OB Stars Near the Solar Circle

    E-Print Network [OSTI]

    S. Daflon; K. Cunha; V. V. Smith; K. Butler

    2002-12-09

    Non-LTE abundances of magnesium, aluminum and sulfur are derived for a sample of 23 low-v \\sin i stars belonging to six northern OB associations of the Galactic disk within 1 kpc of the Sun. The abundances are obtained from the fitting of synthetic line profiles to high resolution spectra. A comparison of our results with HII region abundances indicates good agreement for sulfur while the cepheid abundances are higher. The derived abundances of Mg show good overlap with the cepheid results. The aluminum abundances for OB stars are significantly below the cepheid values. But, the OB star results show a dependence with effective temperature and need further investigation. The high Al abundances in the cepheids could be the result of mixing. A discussion of the oxygen abundance in objects near the solar circle suggests that the current mean galactic oxygen abundance in this region is 8.6-8.7 and in agreement with the recently revised oxygen abundance in the solar photosphere. Meaningful comparisons of the absolute S, Al and Mg abundances in OB stars with the Sun must await a reinvestigation of these elements, as well as the meteoritic reference element Si, with 3D hydrodynamical model atmospheres for the Sun. No abundance gradients are found within the limited range in galactocentric distances in the present study. Such variations would be expected only if there were large metallicity gradients in the disk.

  3. In situ XANES Spectroscopic Investigation of the Pre-Reduction of Iron-Based Catalysts for Non-Oxidative Alkane Dehydrogenation

    SciTech Connect (OSTI)

    Huggins, F.; Shen, W; Cprek, N; Shah, N; Marinkovic, N; Huffman, G

    2008-01-01

    The reduction in a methane atmosphere of two as-prepared ferric oxide catalysts for the non-oxidative dehydrogenation of alkanes has been investigated by in situ X-ray absorption near-edge structure (XANES) spectroscopy using a novel X-ray transmission reaction cell. The two catalysts were prepared by different synthesis methods (incipient wetness and nanoparticle impregnation) and were supported on Al-substituted magnesium oxide obtained by decomposition of a synthetic hydrotalcite. The reduction of the ferric oxides by methane was followed by iron XANES spectroscopy at temperatures up to 650 C complemented by a residual gas analyzer (RGA) used to track changes in the product gas. Results showed that the ferric oxides in the two catalysts underwent a stepwise reduction to first ferrous oxide, releasing mainly H{sub 2}O in the case of the nanoparticle catalyst but H{sub 2} and CO in the case of the incipient wetness formulation at temperatures between 200 and 550 C, and then more slowly to metallic iron at higher temperatures. Reaction of the ferrous oxide with the support to form magnesiowstite also occurred in conjunction with the reduction. This in situ investigation confirms that metallic iron is the active catalytic phase for alkane dehydrogenation and that observations of ferric iron in samples investigated at room temperature after reduction and reaction are most likely due to re-oxidation of the iron in the catalyst upon exposure to air rather than incomplete reduction of the original ferric iron in the catalyst.

  4. NEPTUNIUM OXIDE PROCESSING

    SciTech Connect (OSTI)

    Jordan, J; Watkins, R; Hensel, S

    2009-05-27

    The Savannah River Site's HB-Line Facility completed a campaign in which fifty nine cans of neptunium oxide were produced and shipped to the Idaho National Laboratory in the 9975 shipping container. The neptunium campaign was divided into two parts: Part 1 which consisted of oxide made from H-Canyon neptunium solution which did not require any processing prior to conversion into an oxide, and Part 2 which consisted of oxide made from additional H-Canyon neptunium solutions which required processing to purify the solution prior to conversion into an oxide. The neptunium was received as a nitrate solution and converted to oxide through ion-exchange column extraction, precipitation, and calcination. Numerous processing challenges were encountered in order make a final neptunium oxide product that could be shipped in a 9975 shipping container. Among the challenges overcome was the issue of scale: translating lab scale production into full facility production. The balance between processing efficiency and product quality assurance was addressed during this campaign. Lessons learned from these challenges are applicable to other processing projects.

  5. Oxidative Tritium Decontamination System

    DOE Patents [OSTI]

    Gentile, Charles A. (Plainsboro, NJ), Guttadora, Gregory L. (Highland Park, NJ), Parker, John J. (Medford, NJ)

    2006-02-07

    The Oxidative Tritium Decontamination System, OTDS, provides a method and apparatus for reduction of tritium surface contamination on various items. The OTDS employs ozone gas as oxidizing agent to convert elemental tritium to tritium oxide. Tritium oxide vapor and excess ozone gas is purged from the OTDS, for discharge to atmosphere or transport to further process. An effluent stream is subjected to a catalytic process for the decomposition of excess ozone to diatomic oxygen. One of two configurations of the OTDS is employed: dynamic apparatus equipped with agitation mechanism and large volumetric capacity for decontamination of light items, or static apparatus equipped with pressurization and evacuation capability for decontamination of heavier, delicate, and/or valuable items.

  6. Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction

    SciTech Connect (OSTI)

    Scofield, Megan E.; Koenigsmann, Christopher; Wang, Lei; Lui, Haiqing; Wong, Stanislaus S.

    2014-11-25

    In the search for alternatives to conventional Pt electrocatalysts, we have synthesized ultrathin, ternary PtRuFe nanowires (NW), possessing different chemical compositions in order to probe their CO tolerance as well as electrochemical activity as a function of composition for both (i) the methanol oxidation reaction (MOR) and (ii) the formic acid oxidation reaction (FAOR). As-prepared ‘multifunctional’ ternary NW catalysts exhibited both higher MOR and FAOR activity as compared with binary Pt?Ru? NW, monometallic Pt NW, and commercial catalyst control samples. In terms of synthetic novelty, we utilized a sustainably mild, ambient wet-synthesis method never previously applied to the fabrication of crystalline, pure ternary systems in order to fabricate ultrathin, homogeneous alloy PtRuFe NWs with a range of controlled compositions. These NWs were subsequently characterized using a suite of techniques including XRD, TEM, SAED, and EDAX in order to verify not only the incorporation of Ru and Fe into the Pt lattice but also their chemical homogeneity, morphology, as well as physical structure and integrity. Lastly, these NWs were electrochemically tested in order to deduce the appropriateness of conventional explanations such as (i) the bi-functional mechanism as well as (ii) the ligand effect to account for our MOR and FAOR reaction data. Specifically, methanol oxidation appears to be predominantly influenced by the Ru content, whereas formic acid oxidation is primarily impacted by the corresponding Fe content within the ternary metal alloy catalyst itself.

  7. Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Scofield, Megan E. [State Univ. of New York at Stony Brook, Stony Brook, NY (United States); Koenigsmann, Christopher [State Univ. of New York at Stony Brook, Stony Brook, NY (United States); Wang, Lei [State Univ. of New York at Stony Brook, Stony Brook, NY (United States); Lui, Haiqing [State Univ. of New York at Stony Brook, Stony Brook, NY (United States); Wong, Stanislaus S. [State Univ. of New York at Stony Brook, Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01

    In the search for alternatives to conventional Pt electrocatalysts, we have synthesized ultrathin, ternary PtRuFe nanowires (NW), possessing different chemical compositions in order to probe their CO tolerance as well as electrochemical activity as a function of composition for both (i) the methanol oxidation reaction (MOR) and (ii) the formic acid oxidation reaction (FAOR). As-prepared ‘multifunctional’ ternary NW catalysts exhibited both higher MOR and FAOR activity as compared with binary Pt?Ru? NW, monometallic Pt NW, and commercial catalyst control samples. In terms of synthetic novelty, we utilized a sustainably mild, ambient wet-synthesis method never previously applied to the fabrication of crystalline, pure ternary systems in order to fabricate ultrathin, homogeneous alloy PtRuFe NWs with a range of controlled compositions. These NWs were subsequently characterized using a suite of techniques including XRD, TEM, SAED, and EDAX in order to verify not only the incorporation of Ru and Fe into the Pt lattice but also their chemical homogeneity, morphology, as well as physical structure and integrity. Lastly, these NWs were electrochemically tested in order to deduce the appropriateness of conventional explanations such as (i) the bi-functional mechanism as well as (ii) the ligand effect to account for our MOR and FAOR reaction data. Specifically, methanol oxidation appears to be predominantly influenced by the Ru content, whereas formic acid oxidation is primarily impacted by the corresponding Fe content within the ternary metal alloy catalyst itself.

  8. Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Scofield, Megan E.; Koenigsmann, Christopher; Wang, Lei; Liu, Haiqing; Wong, Stanislaus S.

    2014-11-25

    In the search for alternatives to conventional Pt electrocatalysts, we have synthesized ultrathin, ternary PtRuFe nanowires (NW), possessing different chemical compositions in order to probe their CO tolerance as well as electrochemical activity as a function of composition for both (i) the methanol oxidation reaction (MOR) and (ii) the formic acid oxidation reaction (FAOR). As-prepared ‘multifunctional’ ternary NW catalysts exhibited both higher MOR and FAOR activity as compared with binary Pt?Ru? NW, monometallic Pt NW, and commercial catalyst control samples. In terms of synthetic novelty, we utilized a sustainably mild, ambient wet-synthesis method never previously applied to the fabrication ofmore »crystalline, pure ternary systems in order to fabricate ultrathin, homogeneous alloy PtRuFe NWs with a range of controlled compositions. Thus, these NWs were subsequently characterized using a suite of techniques including XRD, TEM, SAED, and EDAX in order to verify not only the incorporation of Ru and Fe into the Pt lattice but also their chemical homogeneity, morphology, as well as physical structure and integrity. Lastly, these NWs were electrochemically tested in order to deduce the appropriateness of conventional explanations such as (i) the bi-functional mechanism as well as (ii) the ligand effect to account for our MOR and FAOR reaction data. Specifically, methanol oxidation appears to be predominantly influenced by the Ru content, whereas formic acid oxidation is primarily impacted by the corresponding Fe content within the ternary metal alloy catalyst itself.« less

  9. Tailoring the composition of ultrathin, ternary alloy PtRuFe nanowires for the methanol oxidation reaction and formic acid oxidation reaction

    SciTech Connect (OSTI)

    Scofield, Megan E.; Koenigsmann, Christopher; Wang, Lei; Liu, Haiqing; Wong, Stanislaus S.

    2014-11-25

    In the search for alternatives to conventional Pt electrocatalysts, we have synthesized ultrathin, ternary PtRuFe nanowires (NW), possessing different chemical compositions in order to probe their CO tolerance as well as electrochemical activity as a function of composition for both (i) the methanol oxidation reaction (MOR) and (ii) the formic acid oxidation reaction (FAOR). As-prepared ‘multifunctional’ ternary NW catalysts exhibited both higher MOR and FAOR activity as compared with binary Pt?Ru? NW, monometallic Pt NW, and commercial catalyst control samples. In terms of synthetic novelty, we utilized a sustainably mild, ambient wet-synthesis method never previously applied to the fabrication of crystalline, pure ternary systems in order to fabricate ultrathin, homogeneous alloy PtRuFe NWs with a range of controlled compositions. Thus, these NWs were subsequently characterized using a suite of techniques including XRD, TEM, SAED, and EDAX in order to verify not only the incorporation of Ru and Fe into the Pt lattice but also their chemical homogeneity, morphology, as well as physical structure and integrity. Lastly, these NWs were electrochemically tested in order to deduce the appropriateness of conventional explanations such as (i) the bi-functional mechanism as well as (ii) the ligand effect to account for our MOR and FAOR reaction data. Specifically, methanol oxidation appears to be predominantly influenced by the Ru content, whereas formic acid oxidation is primarily impacted by the corresponding Fe content within the ternary metal alloy catalyst itself.

  10. Controlled CO preferential oxidation

    DOE Patents [OSTI]

    Meltser, M.A.; Hoch, M.M.

    1997-06-10

    Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

  11. Notice of Construction for the Magnesium Hydroxide Precipitation Process at the Plutonium Finishing Plant (PFP)

    SciTech Connect (OSTI)

    JANSKY, M.T.

    1999-12-01

    The following description and any attachments and references are provided to the Washington State Department of Health (WDOH), Division of Radiation Protection, Air Emissions & Defense Waste (WAC) 246-247, Radiation Protection-Air Emissions. The WAC 246-247-060, ''Applications, registration, and licensing'', states ''This section describes the information requirements for approval to construct, modify, and operate an emission unit. Any NOC requires the submittal of information listed in Appendix A.'' Appendix A (WAC 246-247-1 10) lists the requirements that must be addressed. Additionally, the following description, attachments and references are provided to the US Environmental Protection Agency (EPA) as an NOC, in accordance with Title 40, Code of Federal Regulations (CFR), Part 61, ''National Emission Standards for Hazardous Air Pollutants.'' The information required for submittal to the EPA is specified in 40 CFR 61.07. The potential emissions from this activity are estimated to provide greater than 0.1 millirem per year total effective dose equivalent (TEDE) to the hypothetical offsite maximally exposed individual (MEI), and commencement is needed within a short time. Therefore, this application also is intended to provide notification of the anticipated date of initial startup in accordance with the requirement listed in 40 CFR 61.09(a)(1), and it is requested that approval of this application also will constitute EPA acceptance of this initial startup notification. Written notification of the actual date of initial startup, in accordance with the requirement listed in 40 CFR 61.09(a)(2) will be provided at a later date. This NOC covers the activities associated with the Construction and operation activities involving the magnesium hydroxide precipitation process of plutonium solutions within the Plutonium Finishing Plant (PFP).

  12. The scope of SaCoNet is to deal with the growing smart communications fields embedded in complex systems for a wide variety of applications in the future generation of network and cloud

    E-Print Network [OSTI]

    Politècnica de Catalunya, Universitat

    emerging networks: sky of clouds, Internet of things, Smart Grids, Smart Cities, etc. The evolutionThe scope of SaCoNet is to deal with the growing smart communications fields embedded in complex technologies. SaCoNet focuses on how smart communications and ICT networks impact not only on network

  13. A GIS based Decision Support Tool for the Management of Industrial Risk S.A Karkanis and G.S.Bonanos

    E-Print Network [OSTI]

    Athens, University of

    A GIS based Decision Support Tool for the Management of Industrial Risk S.A Karkanis and G that are based on geographical considerations of the extent of risk. A tool has been developed on a GIS. The tool uses the capabilities of a GIS platform to combine each map with the corresponding information

  14. Alvin Fine SA305: Spring 2013 Alvin Fine produces three perfumes from raw material. Thirty thousand ounces of raw material is available. Each

    E-Print Network [OSTI]

    Phillips, David

    Alvin Fine SA305: Spring 2013 Alvin Fine produces three perfumes from raw material. Thirty thousand ounces of raw material is available. Each ounce of raw material can be transformed into 0.4 ounces producing enough perfume. Let R = ounces of raw material bought P1 = ounces of perfume 1 made and sold P1T

  15. A Feasibility Study of Steelmaking by Molten Oxide Electrolysis (TRP9956)

    SciTech Connect (OSTI)

    Donald R. Sadoway; Gerbrand Ceder

    2009-12-31

    Molten oxide electrolysis (MOE) is an extreme form of molten salt electrolysis, a technology that has been used to produce tonnage metals for over 100 years - aluminum, magnesium, lithium, sodium and the rare earth metals specifically. The use of carbon-free anodes is the distinguishing factor in MOE compared to other molten salt electrolysis techniques. MOE is totally carbon-free and produces no CO or CO2 - only O2 gas at the anode. This project is directed at assessing the technical feasibility of MOE at the bench scale while determining optimum values of MOE operating parameters. An inert anode will be identified and its ability to sustain oxygen evalution will be demonstrated.

  16. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    1999-01-01

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  17. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    2001-01-01

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  18. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-24

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  19. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-17

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  20. Tetraalykylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

    1998-01-01

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  1. Tetraalklylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

    1998-10-06

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  2. Atomistic modeling of nanowires, small-scale fatigue damage in cast magnesium, and materials for MEMS.

    SciTech Connect (OSTI)

    Dunn, Martin L.; Talmage, Mellisa J.; McDowell, David L., 1956- (,-Georgia Institute of Technology, Atlanta, GA); West, Neil (University of Colorado, Boulder, CO); Gullett, Philip Michael (Mississippi State University , MS); Miller, David C. (University of Colorado, Boulder, CO); Spark, Kevin (University of Colorado, Boulder, CO); Diao, Jiankuai (University of Colorado, Boulder, CO); Horstemeyer, Mark F. (Mississippi State University , MS); Zimmerman, Jonathan A.; Gall, K

    2006-10-01

    Lightweight and miniaturized weapon systems are driving the use of new materials in design such as microscale materials and ultra low-density metallic materials. Reliable design of future weapon components and systems demands a thorough understanding of the deformation modes in these materials that comprise the components and a robust methodology to predict their performance during service or storage. Traditional continuum models of material deformation and failure are not easily extended to these new materials unless microstructural characteristics are included in the formulation. For example, in LIGA Ni and Al-Si thin films, the physical size is on the order of microns, a scale approaching key microstructural features. For a new potential structural material, cast Mg offers a high stiffness-to-weight ratio, but the microstructural heterogeneity at various scales requires a structure-property continuum model. Processes occurring at the nanoscale and microscale develop certain structures that drive material behavior. The objective of the work presented in this report was to understand material characteristics in relation to mechanical properties at the nanoscale and microscale in these promising new material systems. Research was conducted primarily at the University of Colorado at Boulder to employ tightly coupled experimentation and simulation to study damage at various material size scales under monotonic and cyclic loading conditions. Experimental characterization of nano/micro damage will be accomplished by novel techniques such as in-situ environmental scanning electron microscopy (ESEM), 1 MeV transmission electron microscopy (TEM), and atomic force microscopy (AFM). New simulations to support experimental efforts will include modified embedded atom method (MEAM) atomistic simulations at the nanoscale and single crystal micromechanical finite element simulations. This report summarizes the major research and development accomplishments for the LDRD project titled 'Atomistic Modeling of Nanowires, Small-scale Fatigue Damage in Cast Magnesium, and Materials for MEMS'. This project supported a strategic partnership between Sandia National Laboratories and the University of Colorado at Boulder by providing funding for the lead author, Ken Gall, and his students, while he was a member of the University of Colorado faculty.

  3. Nanostructured transition metal oxides useful for water oxidation catalysis

    DOE Patents [OSTI]

    Frei, Heinz M; Jiao, Feng

    2013-12-24

    The present invention provides for a composition comprising a nanostructured transition metal oxide capable of oxidizing two H.sub.2O molecules to obtain four protons. In some embodiments of the invention, the composition further comprises a porous matrix wherein the nanocluster of the transition metal oxide is embedded on and/or in the porous matrix.

  4. Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide

    E-Print Network [OSTI]

    Collins, Gary S.

    molybdenum dioxide displays excellent behavior as catalytic material for the oxidative reforming of bothOxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide Jessica Whalen, Oscar Marin Flores, Su candidate as an effective catalyst for biodiesel. Few papers have been published on the topic of catalytic

  5. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D. (Oak Ridge, TN); Bond, Walter D. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1993-01-01

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel.

  6. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-12-14

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

  7. Conformations of Organophosphine Oxides

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    De Silva, Nuwan; Zahariev, Federico; Hay, Benjamin P.; Gordon, Mark S.; Windus, Theresa L.

    2015-07-29

    The conformations of a series of organophosphine oxides, OP(CH3)2R, where R = methyl, ethyl, isopropyl, tert-butyl, vinyl, and phenyl, are predicted using the MP2/cc-pVTZ level of theory. Comparison of potential energy surfaces for rotation about P–C bonds with crystal structure data reveals a strong correlation between predicted location and energetics of minima and histograms of dihedral angle distributions observed in the solid state. In addition, the most stable conformers are those that minimize the extent of steric repulsion between adjacent rotor substituents, and the torsional barriers tend to increase with the steric bulk of the rotating alkyl group. MM3 forcemore »field parameters were adjusted to fit the MP2 results, providing a fast and accurate model for predicting organophosphine oxides shapes—an essential part of understanding the chemistry of these compounds. The predictive power of the modified MM3 model was tested against MP2/cc-pVTZ conformations for triethylphosphine oxide, OP(CH2CH3)3, and triphenylphosphine oxide, OP(Ph)3.« less

  8. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2012-09-11

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  9. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2014-05-20

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  10. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2013-04-16

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  11. REVIEW OF PLUTONIUM OXIDATION LITERATURE

    SciTech Connect (OSTI)

    Korinko, P.

    2009-11-12

    A brief review of plutonium oxidation literature was conducted. The purpose of the review was to ascertain the effect of oxidation conditions on oxide morphology to support the design and operation of the PDCF direct metal oxidation (DMO) furnace. The interest in the review was due to a new furnace design that resulted in oxide characteristics that are different than those of the original furnace. Very little of the published literature is directly relevant to the DMO furnace operation, which makes assimilation of the literature data with operating conditions and data a convoluted task. The oxidation behavior can be distilled into three regimes, a low temperature regime (RT to 350 C) with a relatively slow oxidation rate that is influenced by moisture, a moderate temperature regime (350-450 C) that is temperature dependent and relies on more or less conventional oxidation growth of a partially protective oxide scale, and high temperature oxidation (> 500 C) where the metal autocatalytically combusts and oxidizes. The particle sizes obtained from these three regimes vary with the finest being from the lowest temperature. It is surmised that the slow growth rate permits significant stress levels to be achieved that help break up the oxides. The intermediate temperatures result in a fairly compact scale that is partially protective and that grows to critical thickness prior to fracturing. The growth rate in this regime may be parabolic or paralinear, depending on the oxidation time and consequently the oxide thickness. The high temperature oxidation is invariant in quiescent or nearly quiescent conditions due to gas blanketing while it accelerates with temperature under flowing conditions. The oxide morphology will generally consist of fine particles (<15 {micro}m), moderately sized particles (15 < x < 250 {micro}m) and large particles (> 250 {micro}m). The particle size ratio is expected to be < 5%, 25%, and 70% for fine, medium and large particles, respectively, for metal temperatures in the 500-600 C range.

  12. Mg{sub 2}MTaO{sub 6} (M=Nd or La): a group of new pyrochlore oxides

    SciTech Connect (OSTI)

    Senthil Kumar, S. [Electronic Ceramics Group, Regional Research Laboratory, Council of Scientific and Industrial Research, Trivandrum-695 019, Kerala (India); Nair, K.V.O. [Electronic Ceramics Group, Regional Research Laboratory, Council of Scientific and Industrial Research, Trivandrum-695 019, Kerala (India); James, J. [Electronic Ceramics Group, Regional Research Laboratory, Council of Scientific and Industrial Research, Trivandrum-695 019, Kerala (India)]. E-mail: jamesj21058@yahoo.com

    2004-11-01

    Preparation of two novel mixed metal oxide ceramic materials, namely magnesium neodymium tantalum oxide (Mg{sub 2}NdTaO{sub 6}) and magnesium lanthanum tantalum oxide (Mg{sub 2}LaTaO{sub 6}) by conventional solid-state reaction method is reported in this paper. The crystal structure of these new compounds, were studied by indexing the X-ray diffraction patterns, powder pattern calculation and profile fitting. They were found to have a defective cubic pyrochlore structure, with the A site being randomly occupied by Mg and La/Nd, while, Ta and Mg are randomly distributed at the B site. The formula assigned were (MgNd)(MgTa)O{sub 6} and (MgLa)(MgTa)O{sub 6}. The variation of dielectric constant, dielectric loss and conductivity of sintered pellets of these materials with applied frequencies in the range of 30 Hz-1 MHz were studied at room temperature. These room temperature studies at 1 MHz gave dielectric constant values of 24.8 and 25.35; conductivity values of 7.75x10{sup -6} and 8.27x10{sup -6} S/m as well as dielectric loss values of 0.0055 and 0.006 for Mg{sub 2}NdTaO{sub 6} and Mg{sub 2}LaTaO{sub 6}, respectively. These new pyrochlore compounds were found to have dielectric constant, dielectric loss and conductivity values in the range suitable for possible electronic ceramic applications.

  13. Doped palladium containing oxidation catalysts

    DOE Patents [OSTI]

    Mohajeri, Nahid

    2014-02-18

    A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

  14. Electron-Atom Superelastic Scattering in Magnesium at Millielectron Volt Energies T. Baynard, A. C. Reber, R. F. Niedziela,| S. A. Darveau, B. Prutzman,# and R. S. Berry*,

    E-Print Network [OSTI]

    Berry, R. Stephen

    Electron-Atom Superelastic Scattering in Magnesium at Millielectron Volt Energies T. Baynard, A. C ReceiVed: July 17, 2007; In Final Form: September 16, 2007 The energy dependence of superelastic electron source to collide with excited atoms. Measurements are made at energies as low as 1.5 me

  15. Research and Education of CO{sub 2} Separation from Coal Combustion Flue Gases with Regenerable Magnesium Solutions

    SciTech Connect (OSTI)

    Lee, Joo-Youp

    2013-09-30

    A novel method using environment-friendly chemical magnesium hydroxide (Mg(OH){sub 2}) solution to capture carbon dioxide from coal-fired power plants flue gas has been studied under this project in the post-combustion control area. The project utilizes the chemistry underlying the CO{sub 2}-Mg(OH){sub 2} system and proven and well-studied mass transfer devices for high levels of CO{sub 2} removal. The major goals of this research were to select and design an appropriate absorber which can absorb greater than 90% CO{sub 2} gas with low energy costs, and to find and optimize the operating conditions for the regeneration step. During the project period, we studied the physical and chemical characteristics of the scrubbing agent, the reaction taking place in the system, development and evaluation of CO{sub 2} gas absorber, desorption mechanism, and operation and optimization of continuous operation. Both batch and continuous operations were performed to examine the effects of various parameters including liquid-to-gas ratio, residence time, lean solvent concentration, pressure drop, bed height, CO{sub 2} partial pressure, bubble size, pH, and temperature on the absorption. The dissolution of Mg(OH){sub 2} particles, formation of magnesium carbonate (MgCO{sub 3}), and vapor-liquid-solid equilibrium (VLSE) of the system were also studied. The dissolution of Mg(OH){sub 2} particles and the steady release of magnesium ions into the solution was a crucial step to maintain a level of alkalinity in the CO{sub 2} absorption process. The dissolution process was modeled using a shrinking core model, and the dissolution reaction between proton ions and Mg(OH){sub 2} particles was found to be a rate-controlling step. The intrinsic surface reaction kinetics was found to be a strong function of temperature, and its kinetic expression was obtained. The kinetics of MgCO{sub 3} formation was also studied in terms of different pH values and temperatures, and was enhanced under high pH and temperatures.

  16. Controlled CO preferential oxidation

    DOE Patents [OSTI]

    Meltser, Mark A. (Pittsford, NY); Hoch, Martin M. (Webster, NY)

    1997-01-01

    Method for controlling the supply of air to a PROX reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference therebetween correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference.

  17. Millisecond Oxidation of Alkanes

    Broader source: Energy.gov [DOE]

    This factsheet describes a project whose goal is to commercialize a production process for propylene and acrylic acid from propane using a catalytic auto-thermal oxydehydrogenation process operating at short contact times. Auto-thermal oxidation for conversion of propane to propylene and acrylic acid promises energy savings of 20 trillion Btu per year by 2020. In addition to reducing energy consumption, this technology can reduce manufacturing costs by up to 25 percent, and reduce a variety of greenhouse gas emissions.

  18. Nonisostructural complex oxide heteroepitaxy

    SciTech Connect (OSTI)

    Wong, Franklin J. Ramanathan, Shriram

    2014-07-01

    The authors present an overview of the fundamentals and representative examples of the growth of epitaxial complex oxide thin films on structurally dissimilar substrates. The authors will delineate how the details of particular crystal structures and symmetry of different oxide surfaces can be employed for a rational approach to the synthesis of nonisostructural epitaxial heterostructures. The concept of oxygen eutaxy can be widely applied. Materials combinations will be split into three categories, and in all cases the films and substrates occur in different crystal structures: (1) common translational and rotational symmetry between the film and substrate planes; (2) translational symmetry mismatch between the substrates and films that is distinct from a simple mismatch in lattice parameters; and (3) rotational symmetry mismatch. In case (1), in principle single-crystalline thin films can be attained despite the films and substrates possessing different crystal structures. In case (2), antiphase boundaries will be prevalent in the thin films. In case (3), thin-film rotational variants that are joined by tilt boundaries will be present. Diffraction techniques to determine crystallographic alignment and epitaxial variants are discussed, and transmission electron microscopy studies to investigate extended defects in the thin films will also be reviewed. The authors end with open problems in this field regarding the structure of oxide interfaces that can be topics for future research.

  19. Effects of Variations in Salt-Spray Conditions on the Corrosion Mechanisms of an AE44 Magnesium Alloy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Martin, Holly J.; Horstemeyer, M. F.; Wang, Paul T.

    2010-01-01

    The understanding of how corrosion affects magnesium alloys is of utmost importance as the automotive and aerospace industries have become interested in the use of these lightweight alloys. However, the standardized salt-spray test does not produce adequate corrosion results when compared with field data, due to the lack of multiple exposure environments. This research explored four test combinations through three sets of cycles to determine how the corrosion mechanisms of pitting, intergranular corrosion, and general corrosion were affected by the environment. Of the four test combinations, Humidity-Drying was the least corrosive, while the most corrosive test condition was Salt Spray-Humidity-Drying.more »The differences in corrosivity of the test conditions are due to the various reactions needed to cause corrosion, including the presence of chloride ions to cause pit nucleation, the presence of humidity to cause galvanic corrosion, and the drying phase which trapped chloride ions beneath the corrosion by-products.« less

  20. Hysteresis-free high rate reactive sputtering of niobium oxide, tantalum oxide, and aluminum oxide

    SciTech Connect (OSTI)

    Särhammar, Erik, E-mail: erik.sarhammar@angstrom.uu.se; Berg, Sören; Nyberg, Tomas [Department of Solid State Electronics, The Ångström Laboratory, Uppsala University, Box 534, SE-751 21 Uppsala (Sweden)

    2014-07-01

    This work reports on experimental studies of reactive sputtering from targets consisting of a metal and its oxide. The composition of the targets varied from pure metal to pure oxide of Al, Ta, and Nb. This combines features from both the metal target and oxide target in reactive sputtering. If a certain relation between the metal and oxide parts is chosen, it may be possible to obtain a high deposition rate, due to the metal part, and a hysteresis-free process, due to the oxide part. The aim of this work is to quantify the achievable boost in oxide deposition rate from a hysteresis-free process by using a target consisting of segments of a metal and its oxide. Such an increase has been previously demonstrated for Ti using a homogeneous substoichiometric target. The achievable gain in deposition rate depends on transformation mechanisms from oxide to suboxides due to preferential sputtering of oxygen. Such mechanisms are different for different materials and the achievable gain is therefore material dependent. For the investigated materials, the authors have demonstrated oxide deposition rates that are 1.5–10 times higher than what is possible from metal targets in compound mode. However, although the principle is demonstrated for oxides of Al, Ta, and Nb, a similar behavior is expected for most oxides.

  1. Microstructure of amorphous indium oxide and tin oxide thin films

    SciTech Connect (OSTI)

    Rauf, I.A.; Brown, L.M. (Univ. of Cambridge (United Kingdom))

    1994-03-15

    Indium oxide, tin oxide, and some other doped and undoped oxide semiconductors show an interesting and technologically important combination of properties. They have high luminous transparency, good electrical conductivity and high infrared reflectivity. Numerous techniques for depositing these materials have been developed and have undergone a number of changes during last two decades. An understanding of the basic physics of these materials has begun to dawn. Most of the literature on transparent conducting oxides consists of studying the dependence of the properties on the composition, preparation conditions, such as deposition rate, substrate temperature or post-deposition heat treatment. In this paper the authors have employed the transmission electron microscopy to study the microstructure of reactively evaporated, electron beam evaporated, ion-beam sputtered amorphous indium oxide and reactively evaporated amorphous tin oxide thin films. These films, which have received little attention in the past, can have enormous potential as transparent conductive coatings on heat-sensitive substrates and inexpensive solar cells.

  2. Oxidation resistant alloys, method for producing oxidation resistant alloys

    DOE Patents [OSTI]

    Dunning, John S.; Alman, David E.

    2002-11-05

    A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800 C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800 C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700 C. at a low cost

  3. Oxidation resistant alloys, method for producing oxidation resistant alloys

    DOE Patents [OSTI]

    Dunning, John S. (Corvallis, OR); Alman, David E. (Salem, OR)

    2002-11-05

    A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800.degree. C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800.degree. C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700.degree. C. at a low cost

  4. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D. (Oak Ridge, TN); Bond, Walter D. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1993-01-01

    Varistors and/or resistors that includes doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  5. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-07-27

    Varistors and/or resistors are described that include doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  6. Stratospheric sulfur oxidation kinetics

    SciTech Connect (OSTI)

    Jayne, J.T.; Worsnop, D.R.; Kolb, C.E. [Aerodyne Research, Inc., Billerica, MA (United States)] [and others

    1995-12-31

    Oxidation of SO2 to H2SO4 in the atmosphere is believed to involve the reaction of SO3 with water. It is commonly assumed that this is an important step leading to homogeneous nucleation of H2SO4 aerosol particles. Heterogeneous chemistry on sulfuric acid aerosols regulate much of the ozone photochemistry in the lower stratosphere and are also believed to have significant effect on the climate. Understanding aerosol loading requires a detailed knowledge of the stratospheric sulfur budget, including its oxidation kinetics. Here we present results of a laboratory project studying a key step in the oxidation process, the homogeneous reaction between SO3 and H2O vapor. Kinetic measurements are performed in a high-pressure turbulent fast-flow reactor (fabricated at MIT) which minimizes heterogeneous loss of SO3 on reactorwalls. The rate of decay of SO3 and the appearance of H2SO4 is monitored in the presence of excess water vapor. Gas phase reactants and products are detected via an atmospheric pressure chemical ionization mass spectrometer which is coupled to the exit of the flow reactor. Sulfuric acid nucleation studies can also be performed using the turbulent flow reactor. Initial measurements using a particle detector (based on Mie scattering) showed that aerosol formation and particle size distribution are controlled by varying the SO3/H2O gas ratio and the reactor temperature. Results for the reaction SO3J+ H2O show a second order dependence in water vapor density and a strong negative temperature dependence. The results, measured in the range -30C to +95C, imply that an SO3.H2O adduct and/or a water dimer species is likely involved in the reaction mechanism. Results of recent theoretical calculations on the SO3 + H2O system also support the finding that two water molecules are involved. Implications for the gas phase production of sulfuric acid in the atmosphere will be discussed.

  7. ARM - Oxides of Nitrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Comments?govInstrumentsnoaacrnBarrow, Alaska OutreachCalendar NSA Related LinksOxides of Nitrogen Outreach Home

  8. Buried oxide layer in silicon

    DOE Patents [OSTI]

    Sadana, Devendra Kumar (Pleasantville, NY); Holland, Orin Wayne (Lenoir, TN)

    2001-01-01

    A process for forming Silicon-On-Insulator is described incorporating the steps of ion implantation of oxygen into a silicon substrate at elevated temperature, ion implanting oxygen at a temperature below 200.degree. C. at a lower dose to form an amorphous silicon layer, and annealing steps to form a mixture of defective single crystal silicon and polycrystalline silicon or polycrystalline silicon alone and then silicon oxide from the amorphous silicon layer to form a continuous silicon oxide layer below the surface of the silicon substrate to provide an isolated superficial layer of silicon. The invention overcomes the problem of buried isolated islands of silicon oxide forming a discontinuous buried oxide layer.

  9. PNNL-SA-84872

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Research Society, Pittsburgh, PA. Matlack, K.S., H. Gan, M. Chaudhuri, W.K. Kot, W. Gong, T. Bardakci, I.L. Pegg, and I. Joseph. 2008. Melt Rate Enhancement for High Aluminum...

  10. Clough-SA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsiclouddenDVA N C E D BGene NetworkNuclearDNP 20082 P r o jJ. linn Space

  11. HySA Infrastructure

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancingR Walls - BuildingofDepartment

  12. Effects of variable nitrogen and phosphorus treatments with and without magnesium sulfate on the availability of soil nutrients and the percentage composition and yield of Coastal Bermuda grass forage 

    E-Print Network [OSTI]

    Cain, Nathan Jackson

    1952-01-01

    EFFECTS OF VARIABLE NITROGEN AND PHOSPHORUS TREATMENTS WITH AND WITHOUT MAGNESIUM SULFATE ON THE AVAILABILITY OF SOIL NUTRIENTS AND THE PERCENI'AGE COMPOSITION AND YIELD OF COASTAL BERMUDA GRASS FORAGE A Thesis Nathan J ~ Cain Approved...'i~see o ' . ~lant tissue data IV. Analysis of variance of soil phosphorus (P) data V. Analysis of variance of' soil calcium (Ca) data VI. Analysis of variance of soil magnesium (Mg) data VII. Analysis of variance of scil potassium (K) data 34 35 36...

  13. CO oxidation on gold-supported iron oxides: New insights into strong oxide–metal interactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Liang; Liu, Yun; Yang, Fan; Evans, Jaime; Rodriguez, José A.; Liu, Ping

    2015-07-14

    Very active FeOx–Au catalysts for CO oxidation are obtained after depositing nanoparticles of FeO, Fe3O4, and Fe2O3 on a Au(111) substrate. Neither FeO nor Fe2O3 is stable under the reaction conditions. Under an environment of CO/O2, they undergo oxidation (FeO) or reduction (Fe2O3) to yield nanoparticles of Fe3O4 that are not formed in a bulk phase. Using a combined experimental and theoretical approach, we show a strong oxide–metal interaction (SOMI) between Fe3O4 nanostructures and Au(111), which gives the oxide special properties, allows the formation of an active phase, and provides a unique interface to facilitate a catalytic reaction. This workmore »highlights the important role that the SOMI can play in enhancing the catalytic performance of the oxide component in metal–oxide catalysts.« less

  14. Operation of staged membrane oxidation reactor systems

    DOE Patents [OSTI]

    Repasky, John Michael

    2012-10-16

    A method of operating a multi-stage ion transport membrane oxidation system. The method comprises providing a multi-stage ion transport membrane oxidation system with at least a first membrane oxidation stage and a second membrane oxidation stage, operating the ion transport membrane oxidation system at operating conditions including a characteristic temperature of the first membrane oxidation stage and a characteristic temperature of the second membrane oxidation stage; and controlling the production capacity and/or the product quality by changing the characteristic temperature of the first membrane oxidation stage and/or changing the characteristic temperature of the second membrane oxidation stage.

  15. Arsenite Oxidation by a Poorly Crystalline Manganese-Oxide 1.

    E-Print Network [OSTI]

    Sparks, Donald L.

    N J . L A F F E R T Y , * M A T T H E W G I N D E R - V O G E L , A N D D O N A L D L . S P A R KArsenite Oxidation by a Poorly Crystalline Manganese-Oxide 1. Stirred-Flow Experiments B R A N D O

  16. Ceramic oxide powders and the formation thereof

    DOE Patents [OSTI]

    Katz, Joseph L. (Baltimore, MD); Hung, Cheng-Hung (Baltimore, MD)

    1993-01-01

    Ceramic oxide powders and a method for their preparation. Ceramic oxide powders are obtained using a flame process whereby two or more precursors of ceramic oxides are introduced into a counterflow diffusion flame burner wherein said precursors are converted into ceramic oxide powders. The morphology, particle size, and crystalline form of the ceramic oxide powders are determined by process conditions.

  17. Ceramic oxide powders and the formation thereof

    DOE Patents [OSTI]

    Katz, J.L.; Chenghung Hung.

    1993-12-07

    Ceramic oxide powders and a method for their preparation. Ceramic oxide powders are obtained using a flame process whereby two or more precursors of ceramic oxides are introduced into a counterflow diffusion flame burner wherein said precursors are converted into ceramic oxide powders. The morphology, particle size, and crystalline form of the ceramic oxide powders are determined by process conditions. 14 figures.

  18. Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications

    E-Print Network [OSTI]

    Nicholas, Jason.D.

    2007-01-01

    Temperature Solid Oxide Fuel Cells, In: S.C. Singhal and M.Tubular Solid Oxide Fuel Cell Technology, U.S. Department ofOxide Films for Solid Oxide Fuel Cell Applications by Jason

  19. Ultra Supercritical Steamside Oxidation

    SciTech Connect (OSTI)

    Holcomb, Gordon R.; Cramer, Stephen D.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, Malgorzata

    2005-01-01

    Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions, which are goals of the U.S. Department of Energy's Advanced Power Systems Initiatives. Most current coal power plants in the U.S. operate at a maximum steam temperature of 538 C. However, new supercritical plants worldwide are being brought into service with steam temperatures of up to 620 C. Current Advanced Power Systems goals include coal generation at 60% efficiency, which require steam temperatures of up to 760 C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections. Initial results of this research are presented.

  20. SOOT-CATALYZED OXIDATION OF SULFUR DIOXIDE

    E-Print Network [OSTI]

    Chang, S.G.

    2010-01-01

    and T. Novakov, "Catalytic oxidation of S02 on carbon inThe mechanism of catalytic oxidation on activated carbon;of water in the catalytic oxidation of S02 on carbonaceous

  1. Detection of oxidation in human serum lipoproteins 

    E-Print Network [OSTI]

    Myers, Christine Lee

    2006-04-12

    A method for the oxidation of lipoproteins in vitro was developed using the free radical initiator, 2,2?-azobis-(2-amidinopropane) dihydrochloride (AAPH). Following in vitro oxidation, the susceptibility to oxidation of the serum samples...

  2. Ethanol oxidation on metal oxide-supported platinum catalysts

    SciTech Connect (OSTI)

    L. M. Petkovic 090468; Sergey N. Rashkeev; D. M. Ginosar

    2009-09-01

    Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on the standard three-way catalysts, the conversion of unburned ethanol is low because both ethanol and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of “stoves” that burn ethanol molecules and their partially oxidized derivatives to the “final” products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of “stoves” that burn ethanol molecules and their partially oxidized derivatives to the “final” products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.

  3. Gold catalyst Styrene Benzaldehyde Styrene oxide Acetophenone

    E-Print Network [OSTI]

    Rouyer, Francois

    O O O + + O2 Gold catalyst Styrene Benzaldehyde Styrene oxide Acetophenone studies. However styrene. The reaction chiefly yielded benzaldehyde, with smaller amounts of styrene oxide and acetophenone

  4. New manganese catalyst for light alkane oxidation

    DOE Patents [OSTI]

    Durante, Vincent A. (West Chester, PA); Lyons, James E. (Wallingford, PA); Walker, Darrell W. (Visalia, CA); Marcus, Bonita K. (Radnor, PA)

    1994-01-01

    Aluminophosphates containing manganese in the structural framework are employed for the oxidation of alkanes, for example the vapor phase oxidation of methane to methanol.

  5. Transmission Electron Microscope In Situ Straining Technique to Directly Observe Defects and Interfaces During Deformation in Magnesium

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Morrow, Benjamin M.; Cerreta, E. K.; McCabe, R. J.; Tomé, C. N.

    2015-05-14

    In-situ straining was used to study deformation behavior of hexagonal close-packed (hcp) metals.Twinning and dislocation motion, both essential to plasticity in hcp materials, were observed.Typically, these processes are characterized post-mortem by examining remnant microstructural features after straining has occurred. By imposing deformation during imaging, direct observation of active deformation mechanisms is possible. This work focuses on straining of structural metals in a transmission electron microscope (TEM), and a recently developed technique that utilizes familiar procedures and equipment to increase ease of experiments. In-situ straining in a TEM presents several advantages over conventional post-mortem characterization, most notably time-resolution of deformation andmore »streamlined identification of active deformation mechanisms. Drawbacks to the technique and applicability to other studies are also addressed. In-situ straining is used to study twin boundary motion in hcp magnesium. A {101¯2} twin was observed during tensile and compressive loading. Twin-dislocation interactions are directly observed. Notably, dislocations are observed to remain mobile, even after multiple interactions with twin boundaries, a result which suggests that Basinki’s dislocation transformation mechanism by twinning is not present in hcp metals. The coupling of in-situ straining with traditional post-mortem characterization yields more detailed information about material behavior during deformation than either technique alone.« less

  6. Synthesis of nanocrystalline magnesium titanate by an auto-igniting combustion technique and its structural, spectroscopic and dielectric properties

    SciTech Connect (OSTI)

    Suresh, M.K. [Electronic Materials Research Laboratory, DST-FIST Sponsored Postgraduate and Research Department of Physics, Mar Ivanios College, Nalanchira, Thiruvananthapuram 695015, Kerala (India)] [Electronic Materials Research Laboratory, DST-FIST Sponsored Postgraduate and Research Department of Physics, Mar Ivanios College, Nalanchira, Thiruvananthapuram 695015, Kerala (India); Thomas, J.K., E-mail: jkthomasemrl@yahoo.com [Electronic Materials Research Laboratory, DST-FIST Sponsored Postgraduate and Research Department of Physics, Mar Ivanios College, Nalanchira, Thiruvananthapuram 695015, Kerala (India); Sreemoolanadhan, H. [Vikram Sarabai Space Centre, Indian Space Research Organization, Department of Space, Thiruvananthapuram (India)] [Vikram Sarabai Space Centre, Indian Space Research Organization, Department of Space, Thiruvananthapuram (India); George, C.N. [Department of Physics, Bishop Moore College, Mavelikkara (India)] [Department of Physics, Bishop Moore College, Mavelikkara (India); John, Annamma; Solomon, Sam [Dielectric Materials Research Laboratory, Department of Physics, St. John's College, Anchal 691306, Kerala (India)] [Dielectric Materials Research Laboratory, Department of Physics, St. John's College, Anchal 691306, Kerala (India); Wariar, P.R.S. [Department of Physics, University College, Thiruvananthapuram, Kerala (India)] [Department of Physics, University College, Thiruvananthapuram, Kerala (India); Koshy, J. [Electronic Materials Research Laboratory, DST-FIST Sponsored Postgraduate and Research Department of Physics, Mar Ivanios College, Nalanchira, Thiruvananthapuram 695015, Kerala (India)] [Electronic Materials Research Laboratory, DST-FIST Sponsored Postgraduate and Research Department of Physics, Mar Ivanios College, Nalanchira, Thiruvananthapuram 695015, Kerala (India)

    2010-07-15

    Nanocrystalline magnesium titanate was synthesized through an auto-ignited combustion method. The phase purity of the powder was examined using X-ray diffraction, thermo gravimetric analysis, differential thermal analysis, Fourier transform infrared spectroscopy and Raman spectroscopy. The transmission electron microscopy study showed that the particle size of the as-prepared powder was in between 20 and 40 nm. The nanopowder could be sintered to 98% of the theoretical density at 1200 {sup o}C for 3 h. The microstructure of the sintered surface was examined using scanning electron microscopy. The dielectric constant ({epsilon}{sub r}) of 16.7 and loss factor (tan {delta}) of the order of 10{sup -4} were obtained at 5 MHz when measured using LCR meter. The quality factor (Q{sub u} x f) 73,700 and temperature coefficient of resonant frequency ({tau}{sub f}) -44.3 ppm/{sup o}C, at 6.5 GHz are the best reported values for sintered pellets obtained from phase pure nanocrystalline MgTiO{sub 3} powder.

  7. Film Breakdown and Nano-Porous Mg(OH)2 Formation from Corrosion of Magnesium Alloys in Salt Solutions

    SciTech Connect (OSTI)

    Brady, Michael P; Rother, Gernot; Anovitz, Lawrence {Larry} M; Littrell, Ken; Unocic, Kinga A; Elsentriecy, Hassan H; Song, GuangLing; Thomson, Jeffery K; Gallego, Nidia C; Davis, Dr. Bruce

    2015-01-01

    Small angle neutron scattering (SANS) and cross-section scanning transmission electron microscopy (STEM) were used to study film formation by magnesium alloys AZ31B (Mg-3Al-1Zn base) and ZE10A (Elektron 717, E717: Mg-1Zn + Nd, Zr) in H2O and D2O with and without 1 or 5 wt.% NaCl. No SANS scattering changes were observed after 24 h D2O or H2O exposures compared with unreacted alloy, consistent with relatively dense MgO-base film formation. However, exposure to 5 wt.% NaCl resulted in accelerated corrosion, with resultant SANS scattering changes detected. The SANS data indicated both particle and rough surface scattering, but with no preferential size features. The films formed in 5 wt.% NaCl consisted of a thin, inner MgO-base layer, and a nano-porous and filamentous Mg(OH)2 outer region tens of microns thick. Chlorine was detected extending to the inner MgO-base film region, with segregation of select alloying elements also observed in the inner MgO, but not the outer Mg(OH)2. Modeling of the SANS data suggested that the outer Mg(OH)2 films had very high surface areas, consistent with loss of film protectiveness. Implications for the NaCl corrosion mechanism, and the potential utility of SANS for Mg corrosion, are discussed.

  8. X-Ray Absorption Studies of Vanadium-Containing Metal Oxide Nanocrystals

    SciTech Connect (OSTI)

    Hohn, Keith, L.

    2006-01-09

    Metal oxide nanocrystals offer significant potential for use as catalysts or catalyst supports due to their high surface areas and unique chemical properties that result from the high number of exposed corners and edges. However, little is known about the catalytic activity of these materials, especially as oxidation catalysts. This research focused on the preparation, characterization and use of vanadium-containing nanocrystals as selective oxidation catalysts. Three vanadium-containing nanocrystals were prepared using a modified sol-gel procedure: V/MgO, V/SiO2, and vanadium phosphate (VPO). These represent active oxidation catalysts for a number of industrially relevant reactions. The catalysts were characterized by x-ray diffraction and Raman, UV-VIS, infrared and x-ray absorption spectroscopies with the goal of determining the primary structural and chemical differences between nanocrystals and microcrystals. The catalytic activity of these catalysts was also studied in oxidative dehydrogenation of butane and methanol oxidation to formaldehyde. V/MgO nanocrystals were investigated for activity in oxidative dehydrogenation of butane and compared to conventional V/MgO catalysts. Characterization of V/MgO catalysts using Raman spectroscopy and x-ray absorption spectroscopy showed that both types of catalysts contained magnesium orthovanadate at vanadium loadings below 15 weight%, but above that loading, magnesium pyrovanadate may have been present. In general, MgO nanocrystals had roughly half the crystal size and double the surface area of the conventional MgO. In oxidative dehydrogenation of butane, nanocrystalline V/MgO gave higher selectivity to butene than conventional V/MgO at the same conversion. This difference was attributed to differences in vanadium domain size resulting from the higher surface areas of the nanocrystalline support, since characterization suggested that similar vanadium phases were present on both types of catalysts. Experiments in methanol oxidation were used to probe the chemical differences between sol-gel prepared and conventionally prepared metal oxides. Both V/MgO and V/SiO2 were studied. For both catalysts, similar product selectivities were noted for either preparation method, suggesting similar acid/base and redox properties for the catalysts. At lower weight loadings (<5%), activity was also similar, but at higher weight loadings the sol-gel prepared catalysts were more active. This was attributed to the greater dispersion of vanadium on sol-gel prepared catalysts, and it was suggested that small vanadium oxide domains were more active in methanol oxidation than polymeric and bulk domains. A novel sol-gel method was developed for preparation of VPO catalysts, which are used industrially in butane oxidation to maleic anhydride. In this method vanadium (V) triisopropoxide was reacted with orthophosphoric acid in THF to form a gel. Drying this gel under air resulted in an intercalated VOPO4 compound, where solvent molecules were trapped between layers of the vanadium phosphate compound. Higher surface areas could be achieved by drying this gel at high pressure in an autoclave. The amount of solvent (THF) placed in the autoclave was important in this process. Low amounts of solvent led to a lower surface area, as the solvent evaporated before reaching the critical point and collapsed the gel's pores. In addition, vanadium reduction occurred in the autoclave due to reaction of isopropanol with the vanadium phosphate. Higher amounts of THF reduced the concentration of isopropanol, leading to less reduction. Surfaces areas in excess of 100 m2/g were achieved with this method, and the product was confirmed through XPS and IR to be VOHPO4*0.5H2O, the common precursor for industrial VPO catalysts. Furthermore, this product displayed a platelet morphology, which is desirable for butane oxidation. Further work showed that this material could be transformed to (VO)2P2O7 (the industrial catalyst for butane oxidation to maleic anhydride) by heating under nitrogen without losing much surface are

  9. Investigation of Mixed Oxide Catalysts for NO Oxidation

    SciTech Connect (OSTI)

    Szanyi, Janos; Karim, Ayman M.; Pederson, Larry R.; Kwak, Ja Hun; Mei, Donghai; Tran, Diana N.; Herling, Darrell R.; Muntean, George G.; Peden, Charles HF; Howden, Ken; Qi, Gongshin; Li, Wei

    2014-12-09

    The oxidation of engine-generated NO to NO2 is an important step in the reduction of NOx in lean engine exhaust because NO2 is required for the performance of the LNT technology [2], and it enhances the activities of ammonia selective catalytic reduction (SCR) catalysts [1]. In particular, for SCR catalysts an NO:NO2 ratio of 1:1 is most effective for NOx reduction, whereas for LNT catalysts, NO must be oxidized to NO2 before adsorption on the storage components. However, NO2 typically constitutes less than 10% of NOx in lean exhaust, so catalytic oxidation of NO is essential. Platinum has been found to be especially active for NO oxidation, and is widely used in DOC and LNT catalysts. However, because of the high cost and poor thermal durability of Pt-based catalysts, there is substantial interest in the development of alternatives. The objective of this project, in collaboration with partner General Motors, is to develop mixed metal oxide catalysts for NO oxidation, enabling lower precious metal usage in emission control systems. [1] M. Koebel, G. Madia, and M. Elsener, Catalysis Today 73, 239 (2002). [2] C. H. Kim, G. S. Qi, K. Dahlberg, and W. Li, Science 327, 1624 (2010).

  10. Nanostructured Metal Oxide Anodes (Presentation)

    SciTech Connect (OSTI)

    Dillon, A. C.; Riley, L. A.; Lee, S.-H.; Kim, Y.-H.; Ban, C.; Gillaspie, D. T.; Pesaran, A.

    2009-05-01

    This summarizes NREL's FY09 battery materials research activity in developing metal oxide nanostructured anodes to enable high-energy, durable and affordable li-ion batteries for HEVs and PHEVs.

  11. Oxides having high energy densities

    DOE Patents [OSTI]

    Ceder, Gerbrand; Kang, Kisuk

    2013-09-10

    Certain disclosed embodiments generally relate to oxide materials having relatively high energy and/or power densities. Various aspects of the embodiments are directed to oxide materials having a structure B.sub.i(M.sub.jY.sub.k)O.sub.2, for example, a structure Li.sub.j(Ni.sub.jY.sub.k)O.sub.2 such as Li(Ni.sub.0.5Mn.sub.0.5)O.sub.2. In this structure, Y represents one or more atoms, each independently selected from the group consisting of alkaline earth metals, transition metals, Group 14 elements, Group 15, or Group 16 elements. In some embodiments, such an oxide material may have an O3 crystal structure, and/or a layered structure such that the oxide comprises a plurality of first, repeating atomic planes comprising Li, and a plurality of second, repeating atomic planes comprising Ni and/or Y.

  12. Introduction Transparent conducting oxides (TCOs)

    E-Print Network [OSTI]

    Poeppelmeier, Kenneth R.

    , In3 , Ga3 , and Sn4 ). Four of these form TCOs as single-cation oxides (ZnO, CdO, In2O3, and SnO2 for more than 50 years, pri- marily in the form of doped single-cation oxides such as In2O3 and SnO2) when appro- priately doped, whereas Ga2O3 is a wide- bandgap insulator. There are 10 binary, 10 ternary

  13. Thin film hydrous metal oxide catalysts

    DOE Patents [OSTI]

    Dosch, Robert G. (Albuquerque, NM); Stephens, Howard P. (Albuquerque, NM)

    1995-01-01

    Thin film (<100 nm) hydrous metal oxide catalysts are prepared by 1) synthesis of a hydrous metal oxide, 2) deposition of the hydrous metal oxide upon an inert support surface, 3) ion exchange with catalytically active metals, and 4) activating the hydrous metal oxide catalysts.

  14. Electronic Transitions in Perovskite Oxide Heterostructures

    E-Print Network [OSTI]

    Wong, Franklin

    2011-01-01

    perovskite . . . . . . . . . . . . . . . . . . . . . . . . . . . . .21 i The distorted perovskite . . . . . . . .Basic Aspects of Correlated Perovskite Oxides The Perovskite

  15. Millisecond Oxidation of Alkanes

    SciTech Connect (OSTI)

    Scott Han

    2011-09-30

    This project was undertaken in response to the Department of Energy's call to research and develop technologies 'that will reduce energy consumption, enhance economic competitiveness, and reduce environmental impacts of the domestic chemical industry.' The current technology at the time for producing 140 billion pounds per year of propylene from naphtha and Liquified Petroleum Gas (LPG) relied on energy- and capital-intensive steam crackers and Fluidized Catalytic Cracking (FCC) units. The propylene is isolated from the product stream in a costly separation step and subsequently converted to acrylic acid and other derivatives in separate production facilities. This project proposed a Short Contact Time Reactor (SCTR)-based catalytic oxydehydrogenation process that could convert propane to propylene and acrylic acid in a cost-effective and energy-efficient fashion. Full implementation of this technology could lead to sizeable energy, economic and environmental benefits for the U. S. chemical industry by providing up to 45 trillion BTUs/year, cost savings of $1.8 billion/year and a combined 35 million pounds/year reduction in environmental pollutants such as COx, NOx, and SOx. Midway through the project term, the program directive changed, which approval from the DOE and its review panel, from direct propane oxidation to acrylic acid at millisecond contact times to a two-step process for making acrylic acid from propane. The first step was the primary focus, namely the conversion of propane to propylene in high yields assisted by the presence of CO2. The product stream from step one was then to be fed directly into a commercially practiced propylene-to-acrylic acid tandem reactor system.

  16. In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM A. Faes1. C. Singhal, K. Kendall, High Temperature Solid Oxide Fuel Cell - Fundamentals, Design, Denmark antonin.faes@epfl.ch Keywords: In situ ETEM, nickel oxide, reduction, RedOx, SOFC Solid Oxide Fuel

  17. Method for plating with metal oxides

    DOE Patents [OSTI]

    Silver, G.L.; Martin, F.S.

    1994-08-23

    A method is disclosed of plating hydrous metal oxides on at least one substrate, which method is indifferent to the electrochemical properties of the substrate, and comprises reacting metallic ions in aqueous solution with an appropriate oxidizing agent such as sodium hypochlorite or calcium sulfite with oxygen under suitable conditions of pH and concentration such that oxidation and precipitation of metal oxide are sufficiently slow to allow satisfactory plating of metal oxide on the substrate. 1 fig.

  18. Method for plating with metal oxides

    DOE Patents [OSTI]

    Silver, Gary L. (Centerville, OH); Martin, Frank S. (Farmersville, OH)

    1994-08-23

    A method of plating hydrous metal oxides on at least one substrate, which method is indifferent to the electrochemical properties of the substrate, and comprises reacting metallic ions in aqueous solution with an appropriate oxidizing agent such as sodium hypochlorite or calcium sulfite with oxygen under suitable conditions of pH and concentration such that oxidation and precipitation of metal oxide are sufficiently slow to allow satisfactory plating of metal oxide on the substrate.

  19. Low temperature synthesis of nanocrystalline magnesium aluminate with high surface area by surfactant assisted precipitation method: Effect of preparation conditions

    SciTech Connect (OSTI)

    Mosayebi, Zeinab; Rezaei, Mehran; Catalyst and Advanced Materials Research Laboratory, Chemical Engineering Department, Faculty of Engineering, University of Kashan, Kashan ; Hadian, Narges; Kordshuli, Fazlollah Zareie; Meshkani, Fereshteh

    2012-09-15

    Highlights: ? MgAl{sub 2}O{sub 4} showed a high surface area and nanocrystalline structure. ? Addition of polymeric surfactant affected the structural properties of MgAl{sub 2}O{sub 4}. ? MgAl{sub 2}O{sub 4} prepared with surfactant showed a hollow cylindrical shape. -- Abstract: A surfactant assisted co-precipitation method was employed for the low temperature synthesis of magnesium aluminate spinel with nanocrystalline size and high specific surface area. Pluronic P123 triblock copolymer and ammonia solution were used as surfactant and precipitation agent, respectively. The prepared samples were characterized by thermal gravimetric and differential thermal gravimetric analyses (TG/DTG), X-ray diffraction (XRD), N{sub 2} adsorption (BET) and transmission electron microscopy (TEM) techniques. The effects of several process parameters such as refluxing temperature, refluxing time, pH, P123 to metals mole ratio (P123/metals) and calcination temperature on the structural properties of the samples were investigated. The obtained results showed that, among the process parameters pH and refluxing temperature have a significant effect on the structural properties of samples. The results revealed that increase in pH from 9.5 to 11 and refluxing temperature from 40 °C to 80 °C increased the specific surface area of prepared samples in the range of 157–188 m{sup 2} g{sup ?1} and 162–184 m{sup 2} g{sup ?1}, respectively. The XRD analysis showed the single-phase MgAl{sub 2}O{sub 4} was formed at 700 °C.

  20. Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications

    E-Print Network [OSTI]

    Nicholas, Jason.D.

    2007-01-01

    Films for Solid Oxide Fuel Cell Applications by Jason Dalefor Solid Oxide Fuel Cell Applications Copyright 2007 byFilms for Solid Oxide Fuel Cell Applications by Jason Dale

  1. Solid oxide electrochemical reactor science.

    SciTech Connect (OSTI)

    Sullivan, Neal P.; Stechel, Ellen Beth; Moyer, Connor J.; Ambrosini, Andrea; Key, Robert J.

    2010-09-01

    Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

  2. Microstructure and corrosion behavior of die-cast AM60B magnesium alloys in a complex salt solution: A slow positron beam study

    SciTech Connect (OSTI)

    Liu, Y.F. [Wuhan University] [Wuhan University; Qin, Q.L. [Wuhan University] [Wuhan University; Yang, W. [Wuhan University] [Wuhan University; Wen, W. [University of Kentucky] [University of Kentucky; Zhai, T. [University of Kentucky] [University of Kentucky; Yu, B. [University of Alberta] [University of Alberta; Liu, D.Y. [University of Alberta] [University of Alberta; Luo, A. [GM Research and Development Center] [GM Research and Development Center; Song, GuangLing [ORNL] [ORNL

    2014-01-01

    The microstructure and corrosion behavior of high pressure die-cast (HPDC) and super vacuum die-cast (SVDC) AM60B magnesium alloys were investigated in a complex salt solution using slow positron beam technique and potentiodynamic polarization tests. The experiments revealed that a CaCO3 film was formed on the surface of the alloys and that the rate of CaCO3 formation for the SVDC alloy with immersion time was slower than that of the HPDC alloy. The larger volume fraction of b-phase in the skin layer of the SVDC alloy than that of the HPDC alloy was responsible for the better corrosion resistance.

  3. Method for hot pressing beryllium oxide articles

    DOE Patents [OSTI]

    Ballard, Ambrose H. (Oak Ridge, TN); Godfrey, Jr., Thomas G. (Oak Ridge, TN); Mowery, Erb H. (Clinton, TN)

    1988-01-01

    The hot pressing of beryllium oxide powder into high density compacts with little or no density gradients is achieved by employing a homogeneous blend of beryllium oxide powder with a lithium oxide sintering agent. The lithium oxide sintering agent is uniformly dispersed throughout the beryllium oxide powder by mixing lithium hydroxide in an aqueous solution with beryllium oxide powder. The lithium hydroxide is converted in situ to lithium carbonate by contacting or flooding the beryllium oxide-lithium hydroxide blend with a stream of carbon dioxide. The lithium carbonate is converted to lithium oxide while remaining fixed to the beryllium oxide particles during the hot pressing step to assure uniform density throughout the compact.

  4. Patterning by area selective oxidation

    DOE Patents [OSTI]

    Nam, Chang-Yong; Kamcev, Jovan; Black, Charles T.; Grubbs, Robert

    2015-12-29

    Technologies are described for methods for producing a pattern of a material on a substrate. The methods may comprise receiving a patterned block copolymer on a substrate. The patterned block copolymer may include a first polymer block domain and a second polymer block domain. The method may comprise exposing the patterned block copolymer to a light effective to oxidize the first polymer block domain in the patterned block copolymer. The method may comprise applying a precursor to the block copolymer. The precursor may infuse into the oxidized first polymer block domain and generate the material. The method may comprise applying a removal agent to the block copolymer. The removal agent may be effective to remove the first polymer block domain and the second polymer block domain from the substrate, and may not be effective to remove the material in the oxidized first polymer block domain.

  5. Aromatic-radical oxidation chemistry

    SciTech Connect (OSTI)

    Glassman, I.; Brezinsky, K. [Princeton Univ., NJ (United States)

    1993-12-01

    The research effort has focussed on discovering an explanation for the anomalously high CO{sub 2} concentrations observed early in the reaction sequence of the oxidation of cyclopentadiene. To explain this observation, a number of plausible mechanisms have been developed which now await experimental verification. One experimental technique for verifying mechanisms is to probe the reacting system by perturbing the radical concentrations. Two forms of chemical perturbation of the oxidation of cyclopentadiene were begun during this past year--the addition of NO{sub 2} and CO to the reacting mixture.

  6. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, R.; George, R.A.; Shockling, L.A.

    1993-04-06

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  7. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

    1993-01-01

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  8. SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL

    E-Print Network [OSTI]

    Mease, Kenneth D.

    module Gas turbine module (compressor and turbine sub-modules) Combustor module Catalytic oxidizer module, MCFC, PEM, Gas Turbine General Model Assumptions · 1D process flow · Well-stirred within nodal volume Nerst Potential · Ideal operating voltage with respect to partial pressures of cell reactants Steam

  9. Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

    E-Print Network [OSTI]

    Joo, Sang Hoon

    2011-01-01

    sensitivity The catalytic oxidation of carbon monoxide (CO)stabilizer. The catalytic activity of CO oxidation overintriguing catalytic behavior for CO oxidation 5-15 ; while

  10. Biomimetic C-H Oxidation Catalysis in Aqueous Solution

    E-Print Network [OSTI]

    Djernes, Katherine Elizabeth

    2013-01-01

    Y. ; Breslow, R. "Catalytic Oxidations of Steroid Substratesapplicable catalytic methods for hydrocarbon oxidation haveof hydrocarbon oxidation catalysts 1.7 and 1.8 The catalytic

  11. Chemically Modified Metal Oxide Nanostructure for Photoelectrochemical Water Splitting

    E-Print Network [OSTI]

    Wang, Gongming

    2013-01-01

    be good catalysts for catalytic oxidation of small organicsolution, indicative of catalytic oxidation of urea presentactive catalytic species for water oxidation. The catalytic

  12. Evaluation of ultramafic deposits in the Eastern United States and Puerto Rico as sources of magnesium for carbon dioxide sequestration

    SciTech Connect (OSTI)

    Fraser Goff; George Guthrie; Bruce Lipin; Melissa Fite; Steve Chipera; Dale Counce; Emily Kluk; Hans Ziock

    2000-04-01

    In this report, the authors evaluate the resource potential of extractable magnesium from ultramafic bodies located in Vermont, the Pennsylvania-Maryland-District-of-Columbia (PA-MD-DC) region, western North Carolina, and southwestern Puerto Rico. The first three regions occur in the Appalachian Mountains and contain the most attractive deposits in the eastern United States. They were formed during prograde metamorphism of serpentinized peridotite fragments originating from an ophiolite protolith. The ultramafic rocks consist of variably serpentinized dunite, harzburgite, and minor iherzolite generally containing antigorite and/or lizardite as the major serpentine minor phases. Chrysotile contents vary from minor to major, depending on occurrence. Most bodies contain an outer sheath of chlorite-talc-tremolite rock. Larger deposits in Vermont and most deposits in North Carolina contain a core of dunite. Magnesite and other carbonates are common accessories. In these deposits, MgO ranges from 36 to 48 wt % with relatively pure dunite having the highest MgO and lowest H{sub 2}O contents. Ultramafic deposits in southwestern Puerto Rico consist of serpentinized dunite and harzburgite thought to be emplaced as large diapirs or as fragments in tectonic melanges. They consist of nearly pure, low-grade serpentinite in which lizardite and chrysotile are the primary serpentine minerals. Chlorite is ubiquitous in trace amounts. Magnesite is a common accessory. Contents of MgO and H{sub 2}O are rather uniform at roughly 36 and 13 wt %. Dissolution experiments show that all serpentinites and dunite-rich rocks are soluble in 1:1 mixtures of 35% HCl and water by volume. The experiments suggest that low-grade serpentinites from Puerto Rico are slightly more reactive than the higher grade, antigorite-bearing serpentinites of the Appalachian Mountains. The experiments also show that the low-grade serpentinites and relatively pure dunites contain the least amounts of undesirable insoluble silicates. Individual ultramafic bodies in the Appalachian Mountains are as great as 7 km{sup 3} although typically they are {le}1 km{sup 3}. In contrast, ultramafic deposits in southwestern Puerto Rico have an estimated volume of roughly 150 km{sup 3}. Based on the few detailed geophysical studies in North Carolina and Puerto Rico, it is evident that volume estimates of any ultramafic deposit would benefit greatly from gravity and magnetic investigations, and from corehole drilling. Nevertheless, the data show that the ultramafic deposits of the eastern United States and southwestern Puerto Rico could potentially sequester many years of annual CO{sub 2} emissions if favorable geotechnical, engineering, and environmental conditions prevail.

  13. The Abundance Evolution of Oxygen, Sodium and Magnesium in Extremely Metal-Poor Intermediate Mass Stars: Implications for the Self-Polution Scenario in Globular Clusters

    E-Print Network [OSTI]

    Pavel A. Denissenkov; Falk Herwig

    2003-05-26

    We present full stellar evolution and parametric models of the surface abundance evolution of O16, Ne22, Na23 and the magnesium isotopes in an extremely metal-poor intermediate mass star M_ZAMS=5M_sun, Z=0.0001. O16 and Ne22 are injected into the envelope by the third dredge-up following thermal pulses on the asymptotic giant branch. These species and the initially present Mg24 are depleted by hot bottom burning (HBB) during the interpulse phase. As a result, Na23, Mg25 and Mg26 are enhanced. If the HBB temperatures are sufficiently high for this process to deplete oxygen efficiently, Na23 is first produced and then depleted during the interpulse phase. Although the simultaneous depletion of O16 and enhancement of Na23 is possible, the required fine tuning of the dredge-up and HBB casts some doubt on the robustness of this process as the origin of the O-Na anti-correlation observed in globular cluster stars. However, a very robust prediction of our models are low Mg24/Mg25 and Mg24/Mg26 ratios whenever significant O16 depletion can be achieved. This seems to be in stark contrast with recent observations of the magnesium isotopic ratios in the globular cluster NGC6752.

  14. Energy-Saving Melting and Revert Reduction Technology (E-SMARRT): Lost Foam Thin Wall - Feasibility of Producing Lost Foam Castings in Aluminum and Magnesium Based Alloys

    SciTech Connect (OSTI)

    Fasoyinu, Yemi; Griffin, John A.

    2014-03-31

    With the increased emphasis on vehicle weight reduction, production of near-net shape components by lost foam casting will make significant inroad into the next-generation of engineering component designs. The lost foam casting process is a cost effective method for producing complex castings using an expandable polystyrene pattern and un-bonded sand. The use of un-bonded molding media in the lost foam process will impose less constraint on the solidifying casting, making hot tearing less prevalent. This is especially true in Al-Mg and Al-Cu alloy systems that are prone to hot tearing when poured in rigid molds partially due to their long freezing range. Some of the unique advantages of using the lost foam casting process are closer dimensional tolerance, higher casting yield, and the elimination of sand cores and binders. Most of the aluminum alloys poured using the lost foam process are based on the Al-Si system. Very limited research work has been performed with Al-Mg and Al-Cu type alloys. With the increased emphasis on vehicle weight reduction, and given the high-strength-to-weight-ratio of magnesium, significant weight savings can be achieved by casting thin-wall (? 3 mm) engineering components from both aluminum- and magnesium-base alloys.

  15. Ferroelectricity in undoped hafnium oxide

    SciTech Connect (OSTI)

    Polakowski, Patrick; Müller, Johannes

    2015-06-08

    We report the observation of ferroelectric characteristics in undoped hafnium oxide thin films in a thickness range of 4–20?nm. The undoped films were fabricated using atomic layer deposition (ALD) and embedded into titanium nitride based metal-insulator-metal (MIM) capacitors for electrical evaluation. Structural as well as electrical evidence for the appearance of a ferroelectric phase in pure hafnium oxide was collected with respect to film thickness and thermal budget applied during titanium nitride electrode formation. Using grazing incidence X-Ray diffraction (GIXRD) analysis, we observed an enhanced suppression of the monoclinic phase fraction in favor of an orthorhombic, potentially, ferroelectric phase with decreasing thickness/grain size and for a titanium nitride electrode formation below crystallization temperature. The electrical presence of ferroelectricity was confirmed using polarization measurements. A remanent polarization P{sub r} of up to 10??C?cm{sup ?2} as well as a read/write endurance of 1.6?×?10{sup 5} cycles was measured for the pure oxide. The experimental results reported here strongly support the intrinsic nature of the ferroelectric phase in hafnium oxide and expand its applicability beyond the doped systems.

  16. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A. Michael (Murrysville, PA); Draper, Robert (Churchill Boro, PA)

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row.

  17. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A.M.; Draper, R.

    1993-11-02

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

  18. Perovskite catalysts for oxidative coupling

    DOE Patents [OSTI]

    Campbell, Kenneth D. (Charleston, WV)

    1991-01-01

    Perovskites of the structure A.sub.2 B.sub.2 C.sub.3 O.sub.10 are useful as catalysts for the oxidative coupling of lower alkane to heavier hydrocarbons. A is alkali metal; B is lanthanide or lanthanum, cerium, neodymium, samarium, praseodymium, gadolinium or dysprosium; and C is titanium.

  19. Perovskite catalysts for oxidative coupling

    DOE Patents [OSTI]

    Campbell, K.D.

    1991-06-25

    Perovskites of the structure A[sub 2]B[sub 2]C[sub 3]O[sub 10] are useful as catalysts for the oxidative coupling of lower alkane to heavier hydrocarbons. A is alkali metal; B is lanthanide or lanthanum, cerium, neodymium, samarium, praseodymium, gadolinium or dysprosium; and C is titanium.

  20. Genomic consequences of DNA oxidation by peroxynitrite

    E-Print Network [OSTI]

    Neeley, William Louis

    2006-01-01

    The radicals nitric oxide and superoxide are produced endogenously by activated macrophages and neutrophils and combine in a diffusion-limited reaction to form peroxynitrite, a powerful oxidizing and nitrating agent capable ...

  1. Complex oxides useful for thermoelectric energy conversion

    DOE Patents [OSTI]

    Majumdar, Arunava (Orinda, CA); Ramesh, Ramamoorthy (Moraga, CA); Yu, Choongho (College Station, TX); Scullin, Matthew L. (Berkeley, CA); Huijben, Mark (Enschede, NL)

    2012-07-17

    The invention provides for a thermoelectric system comprising a substrate comprising a first complex oxide, wherein the substrate is optionally embedded with a second complex oxide. The thermoelectric system can be used for thermoelectric power generation or thermoelectric cooling.

  2. Rare Iron Oxide in Ancient Chinese Pottery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Iron Oxide in Ancient Chinese Pottery Rare Iron Oxide in Ancient Chinese Pottery Print Friday, 26 September 2014 14:37 Jian ware (or Tenmoku) ceramic bowls, famous for their...

  3. Solid Oxide Fuel Cell Manufacturing Overview

    E-Print Network [OSTI]

    Solid Oxide Fuel Cell Manufacturing Overview Hydrogen and Fuel Cell Technologies Manufacturing R Reserved. 3 The Solid Oxide Fuel Cell Electrochemistry #12;Copyright © 2011 Versa Power Systems. All Rights

  4. Nanostructured Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Sholklapper, Tal Zvi

    2007-01-01

    post-Doping of Solid Oxide Fuel Cell Cathodes,? P.h.D.and Technology of Ceramic Fuel Cells, p. 209, Elsevier, NewI. Birss, in Solid Oxide Fuel Cells (SOFC IX), S. C. Singhal

  5. Nanostructured Solid Oxide Fuel Cell Electrodes

    E-Print Network [OSTI]

    Sholklapper, Tal Zvi

    2007-01-01

    in Solid Oxide Fuel Cells (SOFC IX), S. C. Singhal and J.create connected nanostructured SOFC electrodes is reviewed.of Solid Oxide Fuel Cells (SOFC) to directly and efficiently

  6. High quality oxide films on substrates

    DOE Patents [OSTI]

    Ruckman, Mark W. (Middle Island, NY); Strongin, Myron (Center Moriches, NY); Gao, Yong L. (Henrietta, NY)

    1994-01-01

    A method for providing an oxide film of a material on the surface of a substrate using a reactive deposition of the material onto the substrate surface in the presence of a solid or liquid layer of an oxidizing gas. The oxidizing gas is provided on the substrate surface in an amount sufficient to dissipate the latent heat of condensation occurring during deposition as well as creating a favorable oxidizing environment for the material.

  7. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, Barbara K. (Charleston, WV)

    1991-01-01

    Volatilized metal compounds retard vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  8. High quality oxide films on substrates

    DOE Patents [OSTI]

    Ruckman, M.W.; Strongin, M.; Gao, Y.L.

    1994-02-01

    A method is described for providing an oxide film of a material on the surface of a substrate using a reactive deposition of the material onto the substrate surface in the presence of a solid or liquid layer of an oxidizing gas. The oxidizing gas is provided on the substrate surface in an amount sufficient to dissipate the latent heat of condensation occurring during deposition as well as creating a favorable oxidizing environment for the material. 4 figures.

  9. Comment on "Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111)

    E-Print Network [OSTI]

    Goodman, Wayne

    . Obviously, heating Rh in pure oxygen to T ) 230 °C and above will lead to the formation of surface Rh oxideComment on "Catalytic Activity of the Rh Surface Oxide: CO Oxidation over Rh(111) under Realistic suggest the importance of a surface oxide phase for high CO2 formation in CO-O2 reactions. However

  10. Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt Nanoparticles

    E-Print Network [OSTI]

    Kik, Pieter

    Correlating Catalytic Methanol Oxidation with the Structure and Oxidation State of Size-Selected Pt nanoparticles (NPs) prepared by micelle encapsulation and supported on -Al2O3 during the oxidation of methanol the pretreatment. KEYWORDS: platinum, methanol oxidation, operando, XAFS, EXAFS, XANES, alumina, nanoparticle, size

  11. Dense high temperature ceramic oxide superconductors

    DOE Patents [OSTI]

    Landingham, R.L.

    1993-10-12

    Dense superconducting ceramic oxide articles of manufacture and methods for producing these articles are described. Generally these articles are produced by first processing these superconducting oxides by ceramic processing techniques to optimize materials properties, followed by reestablishing the superconducting state in a desired portion of the ceramic oxide composite.

  12. Dense high temperature ceramic oxide superconductors

    DOE Patents [OSTI]

    Landingham, Richard L. (Livermore, CA)

    1993-01-01

    Dense superconducting ceramic oxide articles of manufacture and methods for producing these articles are described. Generally these articles are produced by first processing these superconducting oxides by ceramic processing techniques to optimize materials properties, followed by reestablishing the superconducting state in a desired portion of the ceramic oxide composite.

  13. Fluidized-bed copper oxide process

    SciTech Connect (OSTI)

    Shah, P.P.; Takahashi, G.S.; Leshock, D.G.

    1991-10-14

    The fluidized-bed copper oxide process was developed to simultaneously remove sulfur dioxide and nitrogen oxide contaminants from the flue gas of coal-fired utility boilers. This dry and regenerable process uses a copper oxide sorbent in a fluidized-bed reactor. Contaminants are removed without generating waste material. (VC)

  14. Electrochemistry, Photoelectrochemistry And Photoelectron Spectroscopy Of Nanostructured Metal Oxides

    E-Print Network [OSTI]

    Södergren, S

    1997-01-01

    Electrochemistry, Photoelectrochemistry And Photoelectron Spectroscopy Of Nanostructured Metal Oxides

  15. Electronic structure of graphene oxide and reduced graphene oxide monolayers

    SciTech Connect (OSTI)

    Sutar, D. S.; Singh, Gulbagh; Divakar Botcha, V.

    2012-09-03

    Graphene oxide (GO) monolayers obtained by Langmuir Blodgett route and suitably treated to obtain reduced graphene oxide (RGO) monolayers were studied by photoelectron spectroscopy. Upon reduction of GO to form RGO C1s x-ray photoelectron spectra showed increase in graphitic carbon content, while ultraviolet photoelectron spectra showed increase in intensity corresponding to C2p-{pi} electrons ({approx}3.5 eV). X-ray excited Auger transitions C(KVV) and plasmon energy loss of C1s photoelectrons have been analyzed to elucidate the valence band structure. The effective number of ({pi}+{sigma}) electrons as obtained from energy loss spectra was found to increase by {approx}28% on reduction of GO.

  16. Superconductivity of magnesium diboride

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bud’ko, Sergey L.; Canfield, Paul C.

    2015-07-15

    Over the past 14 years MgB2 has gone from a startling discovery to a promising, applied superconductor. In our article we present a brief overview of the synthesis and the basic superconducting properties of this remarkable compound. Specifically, the effect of pressure, substitutions and neutron irradiation on superconducting properties are discussed.

  17. THE ROLE OF ACTIVE ELEMENTS AND OXIDE DISPERSIONS IN THE DEVELOPMENT OF OXIDATION-RESISTANT ALLOYS AND COATINGS

    E-Print Network [OSTI]

    Allam, I.M.

    2010-01-01

    rate, and sec- ondly this oxide layer must remain adherentFormation of a compound oxide layer (11) between scale andof Y- or Hf-rich compound oxide layers at the oxide/alloy

  18. Catalytic oxidizers and Title V requirements

    SciTech Connect (OSTI)

    Uberoi, M.; Rach, S.E.

    1999-07-01

    Catalytic oxidizers have been used to reduce VOC emissions from various industries including printing, chemical, paint, coatings, etc. A catalytic oxidizer uses a catalyst to reduce the operating temperature for combustion to approximately 600 F, which is substantially lower than thermal oxidation unit. Title V requirements have renewed the debate on the best methods to assure compliance of catalytic oxidizers, with some suggesting the need for continuous emission monitoring equipment. This paper will discuss the various aspects of catalytic oxidation and consider options such as monitoring inlet/outlet temperatures, delta T across the catalyst, periodic laboratory testing of catalyst samples, and preventive maintenance procedures as means of assuring continuous compliance.

  19. THE ROLE OF ACTIVE ELEMENTS AND OXIDE DISPERSIONS IN THE DEVELOPMENT OF OXIDATION-RESISTANT ALLOYS AND COATINGS

    E-Print Network [OSTI]

    Allam, I.M.

    2010-01-01

    of the oxide and alloy and these lead to spallation of theleads to a uniform distribution of fine internal oxide

  20. Coal combustion by wet oxidation

    SciTech Connect (OSTI)

    Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

    1980-11-15

    The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

  1. Graphene oxide oxidizes stannous ions to synthesize tin sulfidegraphene nanocomposites with small crystal size for high performance lithium ion

    E-Print Network [OSTI]

    Cao, Guozhong

    Graphene oxide oxidizes stannous ions to synthesize tin sulfide­graphene nanocomposites with small September 2012 DOI: 10.1039/c2jm34864k This study reports a novel strategy of preparing graphene composites by employing graphene oxide as precursor and oxidizer. It is demonstrated that graphene oxide can oxidize

  2. Poly(ethylene oxide) functionalization

    DOE Patents [OSTI]

    Pratt, Russell Clayton

    2014-04-08

    A simple procedure is provided by which the hydroxyl termini of poly(ethylene oxide) can be appended with functional groups to a useful extent by reaction and precipitation. The polymer is dissolved in warmed toluene, treated with an excess of organic base and somewhat less of an excess of a reactive acylating reagent, reacted for several hours, then precipitated in isopropanol so that the product can be isolated as a solid, and salt byproducts are washed away. This procedure enables functionalization of the polymer while not requiring laborious purification steps such as solvent-solvent extraction or dialysis to remove undesirable side products.

  3. Aluminum-doped Zinc Oxide Nanoink

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2014-08-15

    Scientists at Berkeley Lab have developed a method for fabricating conductive aluminum-doped zinc oxide (AZO) nanocrystals that provide a lower cost, less toxic, earth-abundant alternative to the widely used transparent conductive oxide (TCO) indium tin oxide while offering comparable optical and electronic properties. TCOs are used in devices such as flat screen displays, photovoltaic cells, photochromic windows, chemical sensors, and biosensors....

  4. Metal oxide composite dosimeter method and material

    DOE Patents [OSTI]

    Miller, Steven D. (Richland, WA)

    1998-01-01

    The present invention is a method of measuring a radiation dose wherein a radiation responsive material consisting essentially of metal oxide is first exposed to ionizing radiation. The metal oxide is then stimulating with light thereby causing the radiation responsive material to photoluminesce. Photons emitted from the metal oxide as a result of photoluminescence may be counted to provide a measure of the ionizing radiation.

  5. Predicting the radiation tolerance of oxides

    SciTech Connect (OSTI)

    Sickafus, K. (Kurt E.); Grimes, R. W. (Robin W.)

    2001-01-01

    We have used atomistic computer simulations and ion beam irradiations to examine radiation damage accumulation in multicomponent oxides, We have developed contour energy maps via computer simulations to predict the effects of oxide structure and chemical composition on radiation-induced atomic disorder, defect migration, and swelling. Ion irradiation damage experiments have been perfonned on, pyrochlore and fluorite-structured oxide ceramics to test the predictions from computer models.

  6. Solid-oxide fuel cell electrolyte

    DOE Patents [OSTI]

    Bloom, Ira D. (Bolingbrook, IL); Hash, Mark C. (Joliet, IL); Krumpelt, Michael (Naperville, IL)

    1993-01-01

    A solid-oxide electrolyte operable at between 600.degree. C. and 800.degree. C. and a method of producing the solid-oxide electrolyte are provided. The solid-oxide electrolyte comprises a combination of a compound having weak metal-oxygen interactions with a compound having stronger metal-oxygen interactions whereby the resulting combination has both strong and weak metal-oxygen interaction properties.

  7. Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum, and Tungsten Oxides

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum catalysts confirmed that oxidative dehydrogenation of propane occurs via similar pathways, which involve for propane dehydrogenation and for propene combustion increase in the sequence VOx/ZrO2

  8. Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications

    E-Print Network [OSTI]

    Nicholas, Jason.D.

    2007-01-01

    Temperature Solid Oxide Fuel Cells, In: S.C. Singhal and M.Tubular Solid Oxide Fuel Cell Technology, U.S. Department ofare provided to the fuel cell, electrons are constantly

  9. EIA - Greenhouse Gas Emissions - Nitrous Oxide Emissions

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    U.S. nitrous oxide emissions include agriculture, energy use, industrial processes, and waste management (Figure 22). The largest source is agriculture (73 percent), and the...

  10. Selective deposition of nanostructured ruthenium oxide using...

    Office of Scientific and Technical Information (OSTI)

    Selective deposition of nanostructured ruthenium oxide using Tobacco mosaic virus for micro-supercapacitors in solid Nafion electrolyte Citation Details In-Document Search Title:...

  11. Vapor phase modifiers for oxidative coupling

    DOE Patents [OSTI]

    Warren, B.K.

    1991-12-17

    Volatilized metal compounds are described which are capable of retarding vapor phase alkane conversion reactions in oxidative coupling processes that convert lower alkanes to higher hydrocarbons.

  12. Double perovskite catalysts for oxidative coupling

    DOE Patents [OSTI]

    Campbell, Kenneth D. (Charleston, WV)

    1991-01-01

    Alkali metal doped double perovskites containing manganese and at least one of cobalt, iron and nickel are useful in the oxidative coupling of alkane to higher hydrocarbons.

  13. Siderite, oxidation, and neutralization potential determination 

    E-Print Network [OSTI]

    Porter, Elizabeth Brooke

    2001-01-01

    in the soil. However, dissolution of minerals other than FeCO? may increase NP if 0.5 M HCl is for digestion before oxidation....

  14. Lanthanide doped barium phosphorous oxide scintillators

    DOE Patents [OSTI]

    Borade, Ramesh B; Bourret-Courchesne, Edith; Denzo, Stephen E

    2013-02-26

    The present invention provides for a composition comprising an inorganic scintillator comprising a lanthanide-doped barium phosphorous oxide useful for detecting nuclear material.

  15. Photochemical Water Oxidation by Crystalline Polymorphs of Manganese Oxides: Structural Requirements for Catalysis

    E-Print Network [OSTI]

    Garfunkel, Eric

    potential (1.23 V vs SHE). Commercial water electrolyzers are typically limited by the oxidation reaction

  16. Quantitative room-temperature mineralization of airborne formaldehyde using manganese oxide catalysts

    E-Print Network [OSTI]

    Sidheswaran, Meera A.

    2012-01-01

    temperature thermo-catalytic oxidation reactor. Proceedingsarea. Room temperature catalytic oxidation of airborneand their catalytic activity for formaldehyde oxidation.

  17. The oxidative dehydrogenation of ethane with nitrous oxide by molybdenum oxide supported on silica gel 

    E-Print Network [OSTI]

    Yang, Tsong-Jen

    1979-01-01

    or indirectly from 02, thus tne difference between the two oxidants becomes less sig- nificant. Both rates of formation for C2H4 and C0 were enhanced in the presence of a very small amount of oxygen in the mixture of C2B& and N 0. A radical mechanism... process because of the large and expanding demand for alkenes and dialkenes which are used in the manufacture of various chemical prod- ucts such as detergents, plastics, synthetic rubber, anc high octane gasoline. One example of this type of reaction...

  18. Polysaccharide Nanocomposites Reinforced with Graphene Oxide and Keratin-Grafted Graphene Oxide

    E-Print Network [OSTI]

    Polysaccharide Nanocomposites Reinforced with Graphene Oxide and Keratin-Grafted Graphene Oxide, chitosan-starch, and carboxymethyl cellulose-starch reinforced with graphene oxide and graphene grafted with keratin were developed. Composites films had been prepared for the casting/solvent evaporation method

  19. Comparison of a thermospheric photochemical model with Student Nitric Oxide Explorer (SNOE) observations of nitric oxide

    E-Print Network [OSTI]

    Bailey, Scott

    and of time. There are two principal energy sources that lead to the production of nitric oxideComparison of a thermospheric photochemical model with Student Nitric Oxide Explorer (SNOE) observations of nitric oxide C. A. Barth Laboratory for Atmospheric and Space Physics, University of Colorado

  20. Book: Aging and Oxidants in Animals and Plants Aging and oxidants in the nematode Caenorhabditis elegans

    E-Print Network [OSTI]

    Gems, David

    Book: Aging and Oxidants in Animals and Plants Aging and oxidants in the nematode Caenorhabditis;1.1 Testing the oxidative damage theory of aging in C. elegans The biology of aging remains poorly understood. For example, it remains unclear what sort of biological processes are the primary determinants of aging

  1. Applied Materials Switzerland SA Formerly HCT Shaping Systems SA | Open

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EAandAmminex A S Jump to:AngolaEnergy Management Jump to:Inc AMAT Jump

  2. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2008-07-31

    The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases using empirical approaches. To address this, rate constants for the entire 8-step homogeneous Hg oxidation sequence were developed using an internally consistent transition state approach. These rate constants when combined with the appropriate sub-mechanisms produced lower estimates of the overall extent of homogeneous oxidation, further suggesting that heterogeneous pathways play an important role in Hg oxidation in coal-fired systems.

  3. A Calibration to Predict the Concentrations of Impurities in Plutonium Oxide by Prompt Gamma Analysis Revision 2

    SciTech Connect (OSTI)

    Narlesky, Joshua Edward; Kelly, Elizabeth J.

    2015-09-10

    This report documents the new PG calibration regression equation. These calibration equations incorporate new data that have become available since revision 1 of “A Calibration to Predict the Concentrations of Impurities in Plutonium Oxide by Prompt Gamma Analysis” was issued [3] The calibration equations are based on a weighted least squares (WLS) approach for the regression. The WLS method gives each data point its proper amount of influence over the parameter estimates. This gives two big advantages, more precise parameter estimates and better and more defensible estimates of uncertainties. The WLS approach makes sense both statistically and experimentally because the variances increase with concentration, and there are physical reasons that the higher measurements are less reliable and should be less influential. The new magnesium calibration includes a correction for sodium and separate calibration equation for items with and without chlorine. These additional calibration equations allow for better predictions and smaller uncertainties for sodium in materials with and without chlorine. Chlorine and sodium have separate equations for RICH materials. Again, these equations give better predictions and smaller uncertainties chlorine and sodium for RICH materials.

  4. Sulfur oxide adsorbents and emissions control

    DOE Patents [OSTI]

    Li, Liyu (Richland, WA); King, David L. (Richland, WA)

    2006-12-26

    High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

  5. Plutonium Oxide Process Capability Work Plan

    SciTech Connect (OSTI)

    Meier, David E.; Tingey, Joel M.

    2014-02-28

    Pacific Northwest National Laboratory (PNNL) has been tasked to develop a Pilot-scale Plutonium-oxide Processing Unit (P3U) providing a flexible capability to produce 200g (Pu basis) samples of plutonium oxide using different chemical processes for use in identifying and validating nuclear forensics signatures associated with plutonium production. Materials produced can also be used as exercise and reference materials.

  6. NEMI MEASUREMENT OF AURORAL NITRIC OXIDE PRODUCTION

    E-Print Network [OSTI]

    Ulich, Thomas

    NEMI MEASUREMENT OF AURORAL NITRIC OXIDE PRODUCTION Carl-Fredrik Enell1 Esa Turunen1 Antti Kero1 measurements for a sodium emission experiment. The main purpose of SGO in the NEMI project is in-situ quantification of the auroral production of nitric oxide (NO). The retrieval requires inverse modelling

  7. Nanocomposite of graphene and metal oxide materials

    DOE Patents [OSTI]

    Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon; Wang, Donghai; Yang, Zhenguo

    2012-09-04

    Nanocomposite materials comprising a metal oxide bonded to at least one graphene material. The nanocomposite materials exhibit a specific capacity of at least twice that of the metal oxide material without the graphene at a charge/discharge rate greater than about 10C.

  8. Nanocomposite of graphene and metal oxide materials

    DOE Patents [OSTI]

    Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon; Wang, Donghai; Yang, Zhenguo

    2013-10-15

    Nanocomposite materials comprising a metal oxide bonded to at least one graphene material. The nanocomposite materials exhibit a specific capacity of at least twice that of the metal oxide material without the graphene at a charge/discharge rate greater than about 10 C.

  9. Ammonia release method for depositing metal oxides

    DOE Patents [OSTI]

    Silver, G.L.; Martin, F.S.

    1994-12-13

    A method is described for depositing metal oxides on substrates which is indifferent to the electrochemical properties of the substrates and which comprises forming ammine complexes containing metal ions and thereafter effecting removal of ammonia from the ammine complexes so as to permit slow precipitation and deposition of metal oxide on the substrates. 1 figure.

  10. Ammonia release method for depositing metal oxides

    DOE Patents [OSTI]

    Silver, Gary L. (Centerville, OH); Martin, Frank S. (Farmersville, OH)

    1994-12-13

    A method of depositing metal oxides on substrates which is indifferent to the electrochemical properties of the substrates and which comprises forming ammine complexes containing metal ions and thereafter effecting removal of ammonia from the ammine complexes so as to permit slow precipitation and deposition of metal oxide on the substrates.

  11. Packaging and Transportation of Additional Neptunium Oxide

    SciTech Connect (OSTI)

    Watkins, R.; Jordan, J.; Hensel, S.

    2010-05-05

    The Savannah River Site's HB-Line Facility completed a second neptunium oxide production campaign in which nine (9) additional cans of neptunium oxide were produced and shipped to the Idaho National Laboratory and Oak Ridge National Laboratory in the 9975 shipping container. These additional cans were from a different feed solution than the first fifty (50) cans of neptunium oxide that were previously produced and shipped via a Letter of Amendment to the 9975 Safety Analysis Report for Packaging (SARP) content table. This paper will address the challenges associated with demonstrating the neptunium oxide produced from the additional feed solution was equivalent to the original neptunium oxide and within the content description of the Letter of Amendment.

  12. Electro-deposition of superconductor oxide films

    DOE Patents [OSTI]

    Bhattacharya, Raghu N. (Littleton, CO)

    2001-01-01

    Methods for preparing high quality superconducting oxide precursors which are well suited for further oxidation and annealing to form superconducting oxide films. The method comprises forming a multilayered superconducting precursor on a substrate by providing an electrodeposition bath comprising an electrolyte medium and a substrate electrode, and providing to the bath a plurality of precursor metal salts which are capable of exhibiting superconducting properties upon subsequent treatment. The superconducting precursor is then formed by electrodepositing a first electrodeposited (ED) layer onto the substrate electrode, followed by depositing a layer of silver onto the first electrodeposited (ED) layer, and then electrodepositing a second electrodeposited (ED) layer onto the Ag layer. The multilayered superconducting precursor is suitable for oxidation at a sufficient annealing temperature in air or an oxygen-containing atmosphere to form a crystalline superconducting oxide film.

  13. WHC-SA-1619-FP

    Office of Scientific and Technical Information (OSTI)

    close to the top flange. The maximum local primary membrane stress plus the primary bending stress, a value of 9,048 Ibfin' (62,386 KPa), occurs at the location of the stay...

  14. SA TEC Meeting Notes -- Final

    Office of Environmental Management (EM)

    by Short Line railroads. In addition, several Short Lines provide connections and switching between Class I railroads that serve power plants. The FRA initiated a study of...

  15. Innamincka SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy ResourcesOrder at 8, 13 (Vt.Infinifuel Biodieself

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  17. Prosolmed SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource HistoryPotentialRuralUtilityScalePVGeneration Jump to:SpatialResolutionWidth (m) JumpLine and

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  19. Enerloja SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar2-0057-EA Jump to:of theClimateElgin,WindMap:Weather Data Jump to:Enerley

  20. Cerbranorte SA | Open Energy Information

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtd Jump to: navigation,CauveryGas &Centroalcool

  1. Cetrel SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtd Jump to: navigation,CauveryGasCesOn Compania

  2. Chelonia SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar Energy LLCLtd Jump to:Changing World TechnologiesCharts for other

  3. Naturener SA | Open Energy Information

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavyAgency (IRENA) JumpLiteratureMengdongDNRThermal Power

  4. Preneal SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to:Newberg,Energy LLC JumpPhonoSolar and WindPrayag

  5. Solaer sa | Open Energy Information

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  6. Acciona SA | Open Energy Information

    Open Energy Info (EERE)

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  7. Heliodomi SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam: Energyarea, California | Open Energyreport

  8. MWL SA | Open Energy Information

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource HistoryScenarios Towards 2050Enermar <OMISPowerTurbine forMHKMP2MSEMVP

  9. Zabalgarbi SA | Open Energy Information

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    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowa (UtilityMichigan) JumpZhuyuan Electric Development Co LtdZZTEKZabalgarbi

  10. Prointec SA | Open Energy Information

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  11. smith-sa-99.PDF

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorkingLosThe 26thI D- 6 0 4 2 r m m mDiurnal Variations of9smc1 Ames05

  12. Enerstar SA | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OFAMERICA'SHeavy Electricals LtdEcowind Jump(Redirected

  13. Looking at Transistor Gate Oxide Formation in Real Time

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    using this beamline were able to chart the rate of oxidation of silicon in the gate oxide layer for the first time. Understanding the rate of oxidation in this crucial layer...

  14. Regular paper Search for intermediates of photosynthetic water oxidation

    E-Print Network [OSTI]

    Junge, Wolfgang

    II of cyanobacteria and plants incorporates the catalytic centre of water oxidation. PoweredRegular paper Search for intermediates of photosynthetic water oxidation Juergen Clausen & Wolfgang Key words: intermediate, photosynthesis, Photosystem II, S-state, water oxidation Abstract Photosystem

  15. THE STRUCTURE OF ULTRA-THIN OXIDE ON SILICON

    E-Print Network [OSTI]

    Krivanek, Ondrej L.

    2012-01-01

    Ultra-thin (10-lOOA) silicon oxide layers on silicon are ofcrystalline silicon. The oxide layer is seen to be sharplyundulation of the whole oxide layer with ~300A wavelength.

  16. Physiology and Diversity of Ammonia-Oxidizing Archaea

    E-Print Network [OSTI]

    de la Torre, José R.

    -oxidizing archaea (AOA), now generally recog- nized to exert primary control over ammonia oxidation in terrestrial, the unusually high affinity of marine and terrestrial AOA for ammonia indicates that this group may determine . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 88 Kinetics and Stoichiometry of Ammonia Oxidation

  17. Oxidized film structure and method of making epitaxial metal oxide structure

    DOE Patents [OSTI]

    Gan, Shupan [Richland, WA; Liang, Yong [Richland, WA

    2003-02-25

    A stable oxidized structure and an improved method of making such a structure, including an improved method of making an interfacial template for growing a crystalline metal oxide structure, are disclosed. The improved method comprises the steps of providing a substrate with a clean surface and depositing a metal on the surface at a high temperature under a vacuum to form a metal-substrate compound layer on the surface with a thickness of less than one monolayer. The compound layer is then oxidized by exposing the compound layer to essentially oxygen at a low partial pressure and low temperature. The method may further comprise the step of annealing the surface while under a vacuum to further stabilize the oxidized film structure. A crystalline metal oxide structure may be subsequently epitaxially grown by using the oxidized film structure as an interfacial template and depositing on the interfacial template at least one layer of a crystalline metal oxide.

  18. Catalytic oxidation of hydrocarbons and alcohols by carbon dioxide on oxide catalysts

    SciTech Connect (OSTI)

    Krylov, O.V. . N.N. Semenov Inst. of Chemical Physics); Mamedov, A.Kh.; Mirzabekova, S.R. . Yu.G. Mamedaliev Inst. of Petrochemical Processes)

    1995-02-01

    The great interest displayed lately in heterogeneous catalytic reactions of carbon dioxide is caused by two reasons: (1) the necessity to fight the greenhouse effect and (2) the exhaust of carbon raw material sources. Reactions of oxidative transformation of organic compounds of different classes (alkanes, alkenes, and alcohols) with a nontraditional oxidant, carbon dioxide, were studied on oxide catalysts Fe-O, Cr-O, Mn-O and on multicomponent systems based on manganese oxide. The supported manganese oxide catalysts are active, selective, and stable in conversion of the CH[sub 4] + CO[sub 2] mixture into synthesis gas and in oxidative dehydrogenation of C[sub 2] [minus] C[sub 7] hydrocarbons and the lower alcohols. Unlike metal catalysts manganese oxide based catalysts do not form a carbon layer during the reaction.

  19. Diesel Particulate Oxidation Model: Combined Effects of Fixed...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxidation Model: Combined Effects of Fixed & Volatile Carbon Diesel Particulate Oxidation Model: Combined Effects of Fixed & Volatile Carbon Poster presented at the 16th Directions...

  20. Low-Temperature Hydrocarbon/CO Oxidation Catalysis in Support...

    Energy Savers [EERE]

    HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Low-Temperature HydrocarbonCO Oxidation Catalysis in Support of HCCI Emission Control Presentation from the...