National Library of Energy BETA

Sample records for magnesium aluminum silicon

  1. Electrodeposition of magnesium and magnesium/aluminum alloys

    DOE Patents [OSTI]

    Mayer, A.

    1988-01-21

    Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

  2. Electrodeposition of magnesium and magnesium/aluminum alloys

    DOE Patents [OSTI]

    Mayer, Anton (Los Alamos, NM)

    1988-01-01

    Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

  3. Ames Lab 101: BAM (Boron-Aluminum-Magnesium)

    ScienceCinema (OSTI)

    Bruce Cook

    2013-06-05

    Materials scientist, Bruce Cook, discusses the super hard, low friction, and lubricious alloy know as BAM (Boron-Aluminum-Magnesium). BAM was discovered by Bruce Cook and his team a

  4. An investigation of magnesium production in silicon by neutron transmutation 

    E-Print Network [OSTI]

    Davis, Freddie Joe

    1986-01-01

    NEUTRON TRANSMUTATION DOPING CHAPTER II. THEORY APPROACH IRRADIATION AND PRODUCTS NUMERICAL PREDICTIONS 10 REGISTRATION EFFICIENCY CHAPTER III. EXPERIMENT FILM SELECTION 23 PRELIMINARY TESTS OF LR-115 FILM 25 TARGET CONFIGURATION 29 INHERENT... approach. CHAPTER II THEORY APPROACH The general procedure was to irradiate silicon target materially using the NSCR as a neutron source. The desired interaction, that producing magnesium, gives rise to an alpha particle, which may escape the silicon...

  5. Determination of the concentrations of magnesium and aluminum in alloys by laser produced atomic emission spectroscopy 

    E-Print Network [OSTI]

    Ashe, William Monroe

    1997-01-01

    It Works) 35 5 RESULTS Data Collection . . 38 Part One (Boxcar Averager in Fixed Mode) 38 Part Two (Boxcar Averager in Scanning Mode) . . 39 Magnesium Spectra . . 40 Aluminum Alloy Specna Sensitivity , . 46 Error Analysis . . 48 Part One.... This spectra has been averaged over 5 runs using the Bin and Hold method . 65 32 Plot of intensity ratio vs. concentration ratio for the various magnesium alloys, incluthng the Johnson Matthey magnesium alloy sample data point (circled) 33 Close up...

  6. Impurity control and corrosion resistance of magnesium-aluminum alloy

    SciTech Connect (OSTI)

    Liu, M. [GM China Lab] [GM China Lab; Song, GuangLing [ORNL] [ORNL

    2013-01-01

    The corrosion resistance of magnesium alloys is very sensitive to the contents of impurity elements such as iron. In this study, a series of diecast AXJ530 magnesium alloy samples were prepared with additions of Mn and Fe. Through a comprehensive phase diagram calculation and corrosion evaluation, the mechanisms for the tolerance limit of Fe in magnesium alloy are discussed. This adds a new dimension to control the alloying impurity in terms of alloying composition design and casting conditions.

  7. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide

    SciTech Connect (OSTI)

    Jiang, Weilin; Jung, Hee Joon; Kovarik, Libor; Wang, Zhaoying; Roosendaal, Timothy J.; Zhu, Zihua; Edwards, Danny J.; Hu, Shenyang Y.; Henager, Charles H.; Kurtz, Richard J.; Wang, Yongqiang

    2015-01-01

    As a candidate material for fusion reactor applications, silicon carbide (SiC) undergoes transmutation reactions under high-energy neutron irradiation with magnesium as the major metallic transmutant; the others include aluminum, beryllium and phosphorus in addition to helium and hydrogen gaseous species. The impact of these transmutants on SiC structural stability is currently unknown. This study uses ion implantation to introduce Mg into SiC. Multiaxial ion-channeling analysis of the as-produced damage state suggests that there are preferred Si <100> interstitial splits. The microstructure of the annealed sample was examined using high-resolution scanning transmission electron microscopy. The results show a high concentration of likely non-faulted tetrahedral voids and possible stacking fault tetrahedra near the damage peak. In addition to lattice distortion, dislocations and intrinsic and extrinsic stacking faults are also observed. Magnesium in 3C-SiC prefers to substitute for Si and it forms precipitates of cubic Mg2Si and tetragonal MgC2. The diffusion coefficient of Mg in 3C-SiC single crystal at 1573 K has been determined to be 3.8±0.4×10e-19 m2/sec.

  8. Lithium aluminum/iron sulfide battery having lithium aluminum and silicon as negative electrode

    DOE Patents [OSTI]

    Gilbert, Marian (Flossmoor, IL); Kaun, Thomas D. (New Lenox, IL)

    1984-01-01

    A method of making a negative electrode, the electrode made thereby and a secondary electrochemical cell using the electrode. Silicon powder is mixed with powdered electroactive material, such as the lithium-aluminum eutectic, to provide an improved electrode and cell.

  9. Non-LTE Abundances of Magnesium, Aluminum and Sulfur in OB Stars Near the Solar Circle

    E-Print Network [OSTI]

    S. Daflon; K. Cunha; V. V. Smith; K. Butler

    2002-12-09

    Non-LTE abundances of magnesium, aluminum and sulfur are derived for a sample of 23 low-v \\sin i stars belonging to six northern OB associations of the Galactic disk within 1 kpc of the Sun. The abundances are obtained from the fitting of synthetic line profiles to high resolution spectra. A comparison of our results with HII region abundances indicates good agreement for sulfur while the cepheid abundances are higher. The derived abundances of Mg show good overlap with the cepheid results. The aluminum abundances for OB stars are significantly below the cepheid values. But, the OB star results show a dependence with effective temperature and need further investigation. The high Al abundances in the cepheids could be the result of mixing. A discussion of the oxygen abundance in objects near the solar circle suggests that the current mean galactic oxygen abundance in this region is 8.6-8.7 and in agreement with the recently revised oxygen abundance in the solar photosphere. Meaningful comparisons of the absolute S, Al and Mg abundances in OB stars with the Sun must await a reinvestigation of these elements, as well as the meteoritic reference element Si, with 3D hydrodynamical model atmospheres for the Sun. No abundance gradients are found within the limited range in galactocentric distances in the present study. Such variations would be expected only if there were large metallicity gradients in the disk.

  10. Improved Irradiation Performance of Uranium-Molybdenum/Aluminum Dispersion Fuel by Silicon Addition in Aluminum

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; A. B. Robinson; D. M. Wachs

    2013-10-01

    Uranium-molybdenum fuel particle dispersion in aluminum is a form of fuel under development for conversion of high-power research and test reactors from highly enriched to low-enriched uranium in the U.S. Global Threat Reduction Initiative program (also known as the Reduced Enrichment for Research and Test Reactors program). Extensive irradiation tests have been conducted to find a solution for problems caused by interaction layer growth and pore formation between U-Mo and Al. Adding a small amount of Si (up to [approximately]5 wt%) in the Al matrix was one of the proposed remedies. The effect of silicon addition in the Al matrix was examined using irradiation test results by comparing side-by-side samples with different Si additions. Interaction layer growth was progressively reduced with increasing Si addition to the matrix Al, up to 4.8 wt%. The Si addition also appeared to delay pore formation and growth between the U-Mo and Al.

  11. Mineral interactions and absorption in the equine digestive tract: calcium, phosphorus, and magnesium interaction with aluminum, and calcium digestibility of alfalfa in ponies 

    E-Print Network [OSTI]

    Kapusniak, Linda J.

    1987-01-01

    MINERAL INTERACTIONS AND ABSORPTION IN THE EQUINE DIGESTIVE TRACT: CALCIUM, PHOSPHORUS, AND MAGNESIUM INTERACTION WITH ALUMINUM, AND CALCIUM DIGESTIBILITY OF ALFALFA IN PONIES A Thesis by LINDA J. KAPUSN IAK Subnitted to the Graduate College... of Texas ARM University. in partial fulfillment of the requirenent for the degree of MASTER OF SCIENCE August 1987 Major Subject: Nutrition MINERAL INTER4CTIONS AND ABSORPTION IN THE EQUINE DIGESTIVE TR4CT: C4LCIUM, PHOSPHORUS, AND MAGNESIUM...

  12. Structure and properties of a rapidly solidified dispersion strengthened aluminum-iron-vanadium-silicon alloy 

    E-Print Network [OSTI]

    Little, Stafford Dean

    1991-01-01

    of the requirements for the degree of MASTER OF SCIENCE December 1991 Major Subject: Mechanical Engineering STRUCTURE AND PROPERTIES OF A RAPIDLY SOLIDIFIED DISPERSION STRENGTHENED ALUMINUM-IRON-VANADIUM-SILICON ALLOY A Thesis by STAFFORD DEAN LITTLE Approved... Al-Fe-V-Si alloys II Three Component PUCOT Equations III Four Component PUCOT Equations 16 16 IV Melt Spinning Variables 19 V Young's Modulus Determined by PUCOT 27 VI Tensile Test Data VII Microhardness Measurements at Room Temperature 29...

  13. Influence of Aluminum Content on Grain Refinement and Strength of AZ31 Magnesium GTA Weld Metal

    SciTech Connect (OSTI)

    Babu, N. Kishore [Singapore Institute of Manufacturing Technology; Cross, Carl E. [Los Alamos National Laboratory

    2012-06-28

    The goal is to characterize the effect of Al content on AZ31 weld metal, the grain size and strength, and examine role of Al on grain refinement. The approach is to systematically vary the aluminum content of AZ31 weld metal, Measure average grain size in weld metal, and Measure cross-weld tensile properties and hardness. Conclusions are that: (1) increased Al content in AZ31 weld metal results in grain refinement Reason: higher undercooling during solidification; (2) weld metal grain refinement resulted in increased strength & hardness Reason: grain boundary strengthening; and (3) weld metal strength can be raised to wrought base metal levels.

  14. ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR CELLS

    E-Print Network [OSTI]

    ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR- contacted rear being either passivated by atomic-layer- deposited Al2O3 or by stacks consisting-Si passivation to thermal processes. ATOMIC-LAYER-DEPOSITED Al2O3 Recently, it was shown that thin films

  15. Energy-Saving Melting and Revert Reduction Technology (E-SMARRT): Lost Foam Thin Wall - Feasibility of Producing Lost Foam Castings in Aluminum and Magnesium Based Alloys

    SciTech Connect (OSTI)

    Fasoyinu, Yemi; Griffin, John A.

    2014-03-31

    With the increased emphasis on vehicle weight reduction, production of near-net shape components by lost foam casting will make significant inroad into the next-generation of engineering component designs. The lost foam casting process is a cost effective method for producing complex castings using an expandable polystyrene pattern and un-bonded sand. The use of un-bonded molding media in the lost foam process will impose less constraint on the solidifying casting, making hot tearing less prevalent. This is especially true in Al-Mg and Al-Cu alloy systems that are prone to hot tearing when poured in rigid molds partially due to their long freezing range. Some of the unique advantages of using the lost foam casting process are closer dimensional tolerance, higher casting yield, and the elimination of sand cores and binders. Most of the aluminum alloys poured using the lost foam process are based on the Al-Si system. Very limited research work has been performed with Al-Mg and Al-Cu type alloys. With the increased emphasis on vehicle weight reduction, and given the high-strength-to-weight-ratio of magnesium, significant weight savings can be achieved by casting thin-wall (? 3 mm) engineering components from both aluminum- and magnesium-base alloys.

  16. Mechanical properties and microstructures of dual phase steels containing silicon, aluminum and molybdenum

    E-Print Network [OSTI]

    Neill, Thomas John O'

    2011-01-01

    AND MICROSTRUCTURES OF DUAL PHASE STEELS CONTAINING SILICON,and Microstructures of Dual Phase Steels Containing Silicon,microstructures of selected dual-phase steels in which the

  17. Substrate and method for the formation of continuous magnesium diboride and doped magnesium diboride wire

    DOE Patents [OSTI]

    Suplinskas, Raymond J. (Haverhill, MA); Finnemore, Douglas (Ames, IA); Bud'ko, Serquei (Ames, IA); Canfield, Paul (Ames, IA)

    2007-11-13

    A chemically doped boron coating is applied by chemical vapor deposition to a silicon carbide fiber and the coated fiber then is exposed to magnesium vapor to convert the doped boron to doped magnesium diboride and a resultant superconductor.

  18. Texture Control by Selective Deformation Mechanism Activation in Magnesium Alloy 

    E-Print Network [OSTI]

    Foley, David Christopher

    2014-07-01

    The need for high strength, light weight structures in automotive and aerospace applications has driven a resurgence of interest in magnesium and its alloys. Unlike aluminum, wrought magnesium typically has a high degree ...

  19. LOST FOAM CASTING OF MAGNESIUM ALLOYS

    SciTech Connect (OSTI)

    Han, Qingyou [ORNL; Dinwiddie, Ralph Barton [ORNL; Sklad, Philip S [ORNL; Currie, Kenneth [Tennessee Technological University; Abdelrahman, Mohamed [Tennessee Technological University; Vondra, Fred [Tennessee Technological University; Walford, Graham [Walford Technologies; Nolan, Dennis J [Foseco-Morval

    2007-01-01

    The lost foam casting process has been successfully used for making aluminum and cast iron thin walled castings of complex geometries. Little work has been carried out on cast magnesium alloys using the lost foam process. The article describes the research activities at Oak Ridge National Laboratory and Tennessee Technological University on lost foam casting of magnesium alloys. The work was focused on castings of simple geometries such as plate castings and window castings. The plate castings were designed to investigate the mold filling characteristics of magnesium and aluminum alloys using an infrared camera. The pate castings were then characterized for porosity distribution. The window castings were made to test the castability of the alloys under lost foam conditions. Significant differences between lost foam aluminum casting and lost foam magnesium casting have been observed.

  20. Production of aluminum-silicon alloy and ferrosilicon and commercial-purity aluminum by the direct-reduction process. Third annual technical report, 1980 January 1-1980 December 31

    SciTech Connect (OSTI)

    Bruno, M.J.

    1981-01-01

    Progress on the program to demonstrate the technical feasibility of a pilot-sized Direct Reduction Process for producing aluminium and aluminium-silicon alloy is reported for Phase C. Progress is reported on reduction including the following tasks: supply burden material; burden beneficiation; effects of pilot operating parameters; pilot modifications; reactor scale-up design; calculating heat and mass balance; processing mathematical modeling; effects of process variables; information on supportive analytical, phase identification, and mechanical engineering data. Progress on alloy purification is reported in the following tasks: pilot unit installation; effects of pilot operating parameters; pilot unit modifications; and supportive mechanical engineering. Progress on purification to commercial grade aluminum is reported on: pilot unit installation; effects of pilot operating parameters; pilot unit modifications; support pilot operations; and supportive expended man-hours. Plans for Phase D are noted. (MCW)

  1. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

    2010-02-23

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  2. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

    2012-04-10

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  3. Thermodynamics of copper-nickel alloys containing aluminum, silicon, titanium, and chromium relative to their use in ceramic brazing

    SciTech Connect (OSTI)

    Williams, R.O.

    1984-11-01

    By varying the copper-to-nickel ratio the activity coefficients of Al, Si, Ti, and Cr can be varied over a wide range. Thus to a degree one can tailor the behavior of such alloys for usefulness in brazing ceramics. Further, considerable amounts of these active elements can be present while the ability of carbon to reduce the surface oxide film in a high-vacuum system is retained. The critical aluminum concentrations required to prevent the formation of SiO/sub 2/, TiO, or Cr/sub 2/O/sub 3/ by reaction with Al/sub 2/O/sub 3/ are calculated. The simultaneous presence of the four active additions will presumably promote wetting without making the surface deoxidation more difficult.

  4. Effect of Texture on Formability and Mechanical Anisotropy of a Severe Plastically Deformed Magnesium Alloy 

    E-Print Network [OSTI]

    Modarres Razavi, Sonia

    2012-02-14

    Magnesium and its alloys have been considered as alternatives to aluminum alloys and steels for structural applications in automotive and aerospace applications due to their superior specific strength and light-weight. ...

  5. Efficient One-Step Electrolytic Recycling of Low-Grade and Post-Consumer Magnesium Scrap

    SciTech Connect (OSTI)

    Adam C. Powell, IV

    2012-07-19

    Metal Oxygen Separation Technologies, Inc. (abbreviated MOxST, pronounced most) and Boston University (BU) have developed a new low-cost process for recycling post-consumer co-mingled and heavily-oxidized magnesium scrap, and discovered a new chemical mechanism for magnesium separations in the process. The new process, designated MagReGenTM, is very effective in laboratory experiments, and on scale-up promises to be the lowest-cost lowest-energy lowest-impact method for separating magnesium metal from aluminum while recovering oxidized magnesium. MagReGenTM uses as little as one-eighth as much energy as today's methods for recycling magnesium metal from comingled scrap. As such, this technology could play a vital role in recycling automotive non-ferrous metals, particularly as motor vehicle magnesium/aluminum ratios increase in order to reduce vehicle weight and increase efficiency.

  6. ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aluminum Industry Vision: Sustainable Solutions for a Dynamic World ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions for a Dynamic World alumvision.pdf More Documents...

  7. Process for strengthening aluminum based ceramics and material

    DOE Patents [OSTI]

    Moorhead, Arthur J. (Knoxville, TN); Kim, Hyoun-Ee (Seoul, KR)

    2000-01-01

    A process for strengthening aluminum based ceramics is provided. A gaseous atmosphere consisting essentially of silicon monoxide gas is formed by exposing a source of silicon to an atmosphere consisting essentially of hydrogen and a sufficient amount of water vapor. The aluminum based ceramic is exposed to the gaseous silicon monoxide atmosphere for a period of time and at a temperature sufficient to produce a continuous, stable silicon-containing film on the surface of the aluminum based ceramic that increases the strength of the ceramic.

  8. Overview of Aluminum

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aluminum Overview of Aluminum Overview of Aluminum Session Coordinator: Mark T. Smith Pacific Northwest National Laboratory VT Merit Review 2008 February 28, 2008 2 Overview of...

  9. Analysis of the potential for new automotive uses of magnesium

    SciTech Connect (OSTI)

    Stodolsky, F.; Gaines, L.; Cuenca, R.; Wu, S.

    1994-12-31

    This paper describes the scope of a new project, just initiated, for the Lightweight Materials Program within the Office of Transportation Materials. The Center for Transportation Research and the Energy Technology Division at Argonne National Laboratory will assess the feasibility and technical potential of using magnesium and its alloys in place of steel or aluminum for automotive structural and sheet applications in order to enable more energy-efficient, lightweight passenger vehicles. The analysis will provide an information base to help guide magnesium research and development in the most promising directions.

  10. Method for production of magnesium

    DOE Patents [OSTI]

    Diaz, Alexander F. (Cambridge, MA); Howard, Jack B. (Winchester, MA); Modestino, Anthony J. (Hanson, MA); Peters, William A. (Lexington, MA)

    1998-01-01

    A continuous process for the production of elemental magnesium is described. Magnesium is made from magnesium oxide and a light hydrocarbon gas. In the process, a feed stream of the magnesium oxide and gas is continuously fed into a reaction zone. There the magnesium oxide and gas are reacted at a temperature of about 1400.degree. C. or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental magnesium. The product stream is continuously quenched after leaving the reaction zone, and the elemental magnesium is separated from other reaction products.

  11. Method for production of magnesium

    DOE Patents [OSTI]

    Diaz, A.F.; Howard, J.B.; Modestino, A.J.; Peters, W.A.

    1998-07-21

    A continuous process for the production of elemental magnesium is described. Magnesium is made from magnesium oxide and a light hydrocarbon gas. In the process, a feed stream of the magnesium oxide and gas is continuously fed into a reaction zone. There the magnesium oxide and gas are reacted at a temperature of about 1400 C or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental magnesium. The product stream is continuously quenched after leaving the reaction zone, and the elemental magnesium is separated from other reaction products. 12 figs.

  12. Electrical characterization of germanium-silicon alloy 

    E-Print Network [OSTI]

    Kishore, Kumar P.

    1994-01-01

    . The fabrication procedure involved sputter deposition of silicon dioxide, oxide patterning, deposition of aluminum metal and metal patterning. Each test structure was square-shaped and consisted of eight sets of peripheral metal contacts. The results...

  13. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys and metal produced in the United States in 2011

    E-Print Network [OSTI]

    and aluminum alloys and the chemical industry. The semiconductor and solar industries, which manufacture chips%; and other, 4%. Silicon metal: Brazil, 39%; South Africa, 22%; Canada, 13%; Australia, 10%; and other, 16 secondary aluminum production--the primary materials source for aluminum-silicon alloys--was projected

  14. Magnesium fluoride recovery method

    DOE Patents [OSTI]

    Gay, Richard L. (Canoga Park, CA); McKenzie, Donald E. (Woodland Hills, CA)

    1989-01-01

    A method of obtaining magnesium fluoride substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is contacted with an acid under certain prescribed conditions to produce a liquid product and a particulate solid product. The particulate solid product is separated from the liquid and treated at least two more times with acid to produce a solid residue consisting essentially of magnesium fluoride substantially free of uranium and having a residual radioactivity level of less than about 1000 pCi/gm. In accordance with a particularly preferred embodiment of the invention a catalyst and an oxidizing agent are used during the acid treatment and preferably the acid is sulfuric acid having a strength of about 1.0 Normal.

  15. Potential applications of wrought magnesium alloys for passenger vehicles

    SciTech Connect (OSTI)

    Gaines, L.; Cuenca, R.; Stodolsky, F.; Wu, S.

    1995-12-31

    Vehicle weight reduction is one of the major means available for improving automotive fuel efficiency. Although high-strength steels, aluminum (Al), and polymers are already being used to achieve significant weight reductions, substantial additional weight reductions could be achieved by increased use of magnesium (Mg) and its alloys, which have very low density. Magnesium alloys are currently used in relatively small quantities for auto parts; use is generally limited to die castings, such as housings. The Center for Transportation Research at Argonne National Laboratory has performed a study for the Lightweight Materials Program within DOE`s Office of Transportation Materials to evaluate the suitability of wrought Mg and its alloys to replace steel or aluminum for automotive structural and sheet applications. This study identifies technical and economic barriers to this replacement and suggests R&D areas to enable economical large-volume use. Detailed results of the study will be published at a later date. Magnesium sheet could be used in body nonstructural and semi-structural applications, while extrusions could be used in such structural applications as spaceframes. Currently, Mg sheet has found limited use in the aerospace industry, where costs are not a major concern. The major barrier to greatly increased automotive use is high cost; two technical R&D areas are identified that could enable major reductions in costs. These are novel reduction technology and better hot-forming technology, possibly operating at lower temperatures and involving superplastic behavior.

  16. Method to decrease loss of aluminum and magnesium melts

    DOE Patents [OSTI]

    Hryn, John N. (Naperville, IL); Pellin, Michael J. (Naperville, IL); Calaway, Jr., Wallis F. (Woodridge, IL); Moore, Jerry F. (Naperville, IL); Krumdick, Gregory K. (Crete, IL)

    2002-01-01

    A method to minimize oxidation of metal during melting processes is provided, the method comprising placing solid phase metal into a furnace environ-ment, transforming the solid-phase metal into molten metal phase having a molten metal surface, and creating a barrier between the surface and the environment. Also provided is a method for isolating the surface of molten metal from its environment, the method comprising confining the molten metal to a controlled atmos-phere, and imposing a floating substrate between the surface and the atmosphere.

  17. Destabilization of magnesium hydride through interface engineering

    E-Print Network [OSTI]

    Dam, Bernard

    Destabilization of magnesium hydride through interface engineering Lennard Mooij #12;Destabilization of magnesium hydride through interface engineering PROEFSCHRIFT ter verkrijging van de graad van . . . . . . . . . . . . . . . . . . . . . . . . . 10 1.3 Magnesium hydride . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 1

  18. ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aluminum Industry Roadmap for the Automotive Market (May 1999) ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market (May 1999) autoroadmap.pdf More Documents &...

  19. Potential automotive uses of wrought magnesium alloys

    SciTech Connect (OSTI)

    Gaines, L.; Cuenca, R.; Wu, S. [Argonne National Lab., IL (United States); Stodolsky, F. [Argonne National Lab., IL (United States)]|[Argonne National Lab., Washington, DC (United States)

    1996-06-01

    Vehicle weight reduction is one of the major means available to improve automotive fuel efficiency. High-strength steels, aluminum (Al), and polymers are already being used to reduce weight significantly, but substantial additional reductions could be achieved by greater use of low-density magnesium (Mg) and its alloys. Mg alloys are currently used in relatively small quantities for auto parts, generally limited to die castings (e.g., housings). Argonne National Laboratory`s Center for Transportation Research has performed a study for the Lightweight Materials Program within DOE`s Office of Transportation Materials to evaluate the suitability of wrought Mg and its alloys to replace steel/aluminum for automotive structural and sheet applications. Mg sheet could be used in body nonstructural and semi-structural applications, while extrusions could be used in such structural applications as spaceframes. This study identifies high cost as the major barrier to greatly increased Mg use in autos. Two technical R and D areas, novel reduction technology and better hot-forming technology, could enable major cost reductions.

  20. Constraining magnesium cycling in marine sediments using magnesium isotopes

    E-Print Network [OSTI]

    Paytan, Adina

    . Extensive sampling of sedimentary pore-fluids by the Deep Sea Drilling Project (DSDP) and Ocean Drilling Abstract Magnesium concentrations in deep-sea sediment pore-fluids typically decrease down core due to net and differentiate these processes, we have measured magnesium isotopes in pore-fluids and sediment samples from

  1. Synthesis of magnesium diboride by magnesium vapor infiltration process (MVIP)

    DOE Patents [OSTI]

    Serquis, Adriana C. (Los Alamos, NM); Zhu, Yuntian T. (Los Alamos, NM); Mueller, Frederick M. (Los Alamos, NM); Peterson, Dean E. (Los Alamos, NM); Liao, Xiao Zhou (Los Alamos, NM)

    2003-01-01

    A process of preparing superconducting magnesium diboride powder by heating an admixture of solid magnesium and amorphous boron powder or pellet under an inert atmosphere in a Mg:B ratio of greater than about 0.6:1 at temperatures and for time sufficient to form said superconducting magnesium diboride. The process can further include exposure to residual oxygen at high synthesis temperatures followed by slow cooling. In the cooling process oxygen atoms dissolved into MgB.sub.2 segregated to form nanometer-sized coherent Mg(B,O) precipitates in the MgB.sub.2 matrix, which can act as flux pinning centers.

  2. Dispersion toughened silicon carbon ceramics

    DOE Patents [OSTI]

    Wei, G.C.

    1984-01-01

    Fracture resistant silicon carbide ceramics are provided by incorporating therein a particulate dispersoid selected from the group consisting of (a) a mixture of boron, carbon and tungsten, (b) a mixture of boron, carbon and molybdenum, (c) a mixture of boron, carbon and titanium carbide, (d) a mixture of aluminum oxide and zirconium oxide, and (e) boron nitride. 4 figures.

  3. Metal electrode for amorphous silicon solar cells

    DOE Patents [OSTI]

    Williams, Richard (Princeton, NJ)

    1983-01-01

    An amorphous silicon solar cell having an N-type region wherein the contact to the N-type region is composed of a material having a work function of about 3.7 electron volts or less. Suitable materials include strontium, barium and magnesium and rare earth metals such as gadolinium and yttrium.

  4. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, Donald R. (Belmont, MA)

    1988-01-01

    A stable reference electrode for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na.sub.3 AlF.sub.6, wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution.

  5. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, D.R.

    1988-08-16

    A stable reference electrode is described for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na[sub 3]AlF[sub 6], wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution. 1 fig.

  6. ITP Aluminum: Aluminum Industry Technology Roadmap

    Office of Energy Efficiency and Renewable Energy (EERE)

    In 2002, the industry created this updated Aluminum Industry Technology Roadmap to define the specific research and development priorities, performance targets, and milestones required to achieve the set vision.

  7. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

    2008-12-09

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  8. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys and metal produced in the United States in 2012

    E-Print Network [OSTI]

    and aluminum alloys and the chemical industry. The semiconductor and solar industries, which manufacture chips%; and other, 5%. Silicon metal: Brazil, 41%; South Africa, 20%; Canada, 12%; Australia, 9%; and other, 18 materials source for aluminum-silicon alloys--was projected to increase by 10% in 2012 compared

  9. Method for magnesium sulfate recovery

    DOE Patents [OSTI]

    Gay, R.L.; Grantham, L.F.

    1987-08-25

    A method is described for obtaining magnesium sulfate substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7,000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is then contacted with a concentrated sulfuric acid under certain prescribed conditions to produce a liquid product and a solid product. The particulate solid product and a minor amount of the liquid is then treated to produce a solid residue consisting essentially of magnesium sulfate substantially free of uranium and having a residual radioactivity level of less than 1,000 pCi/gm. In accordance with the preferred embodiment of the invention, a catalyst and an oxidizing agent are used during the initial acid treatment and a final solid residue has a radioactivity level of less than about 50 pCi/gm.

  10. Method for magnesium sulfate recovery

    DOE Patents [OSTI]

    Gay, Richard L. (Canoga Park, CA); Grantham, LeRoy F. (Calabasas, CA)

    1987-01-01

    A method of obtaining magnesium sulfate substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is then contacted with a concentrated sulfuric acid under certain prescribed conditions to produce a liquid product and a solid product. The particulate solid product and a minor amount of the liquid is then treated to produce a solid residue consisting essentially of magnesium sulfate substantially free of uranium and having a residual radioactivity level of less than 1000 pCi/gm. In accordance with the preferred embodiment of the invention, a catalyst and an oxidizing agent are used during the initial acid treatment and a final solid residue has a radioactivity level of less than about 50 pCi/gm.

  11. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01

    Anodes for Aluminum-Air Batteries. J. Electrochem. Soc.Anodes for Aluminum-Air Batteries. J. Electrochem. Soc.ALLOYS FOR ALUMINUM AIR BATTERIES. J. Electrochem. Soc.

  12. Synthesis and Characterization of Magnesium-Silicon and Magnesium-Tin Solid Solutions for Thermoelectric Applications 

    E-Print Network [OSTI]

    Hu, Fang

    2012-07-16

    The environmentally friendly n-type Mg2(Si, Sn) thermoelectric solid solutions have a strong potential of commercial utilization in thermoelectric (TE) energy conversion due to their availability, low density (~3.02 g/cm3), ...

  13. Tissue magnesium and calcium concentration in relation to magnesium and calcium intake in rats 

    E-Print Network [OSTI]

    Pinkham, Carrie Stanton

    1987-01-01

    TISSUE MAGNESIUM AND CALCIUM CONCENTRATION IN RELATION TO MAGNESIUM AND CALCIUM INTAKE IN RATS A Thesis by CARRIE STANTON PINKRAM Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirerrents... for the degree of MASTER OF SCIENCE August 1987 Major Subject: Nutrition TISSUE MAGNESIUM AND CALCIUM CONCENTRATION IN RELATION TO MAGNESIUM AND CALCIUM INTAKE IN RATS A Thesis by CARRIE STANTON PINKHAM Approved as to style and content by: Karen S...

  14. Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up...

    Office of Environmental Management (EM)

    for Lightweighting Materials Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis Scale-Up of Magnesium Production by Fully Stabilized Zirconia...

  15. Scale-Up of Magnesium Production by Fully Stabilized Zirconia...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis 2012 DOE Hydrogen and Fuel Cells...

  16. DEFLECTION MEASUREMENTS OF 25 mm ALUMINUM COLLARS

    E-Print Network [OSTI]

    Peters, C.

    2010-01-01

    DEFLECTION MEASUREMENTS OF 25 mm ALUMINUM COLLARS· C. PetersDEFLECTION MEASUREMENTS OF 25 mm ALUMINUM COLLARS" C. Peters

  17. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan (Mastic, NY); Reilly, James J. (Bellport, NY)

    2009-04-21

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  18. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan; Reilly, James J; Wegrzyn, James E

    2012-09-18

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, and by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  19. ITP Aluminum: Inert Anodes Roadmap

    Broader source: Energy.gov [DOE]

    Aluminum is one of the most versatile materials available today that can meet the demanding requirements of tomorrow's products.

  20. Amorphous silicon passivated contacts for diffused junction silicon solar cells

    SciTech Connect (OSTI)

    Bullock, J. Yan, D.; Wan, Y.; Cuevas, A.; Demaurex, B.; Hessler-Wyser, A.; De Wolf, S.

    2014-04-28

    Carrier recombination at the metal contacts is a major obstacle in the development of high-performance crystalline silicon homojunction solar cells. To address this issue, we insert thin intrinsic hydrogenated amorphous silicon [a-Si:H(i)] passivating films between the dopant-diffused silicon surface and aluminum contacts. We find that with increasing a-Si:H(i) interlayer thickness (from 0 to 16?nm) the recombination loss at metal-contacted phosphorus (n{sup +}) and boron (p{sup +}) diffused surfaces decreases by factors of ?25 and ?10, respectively. Conversely, the contact resistivity increases in both cases before saturating to still acceptable values of ? 50 m? cm{sup 2} for n{sup +} and ?100 m? cm{sup 2} for p{sup +} surfaces. Carrier transport towards the contacts likely occurs by a combination of carrier tunneling and aluminum spiking through the a-Si:H(i) layer, as supported by scanning transmission electron microscopy–energy dispersive x-ray maps. We explain the superior contact selectivity obtained on n{sup +} surfaces by more favorable band offsets and capture cross section ratios of recombination centers at the c-Si/a-Si:H(i) interface.

  1. Membrane Purification Cell for Aluminum Recycling

    SciTech Connect (OSTI)

    David DeYoung; James Wiswall; Cong Wang

    2011-11-29

    Recycling mixed aluminum scrap usually requires adding primary aluminum to the scrap stream as a diluent to reduce the concentration of non-aluminum constituents used in aluminum alloys. Since primary aluminum production requires approximately 10 times more energy than melting scrap, the bulk of the energy and carbon dioxide emissions for recycling are associated with using primary aluminum as a diluent. Eliminating the need for using primary aluminum as a diluent would dramatically reduce energy requirements, decrease carbon dioxide emissions, and increase scrap utilization in recycling. Electrorefining can be used to extract pure aluminum from mixed scrap. Some example applications include producing primary grade aluminum from specific scrap streams such as consumer packaging and mixed alloy saw chips, and recycling multi-alloy products such as brazing sheet. Electrorefining can also be used to extract valuable alloying elements such as Li from Al-Li mixed scrap. This project was aimed at developing an electrorefining process for purifying aluminum to reduce energy consumption and emissions by 75% compared to conventional technology. An electrolytic molten aluminum purification process, utilizing a horizontal membrane cell anode, was designed, constructed, operated and validated. The electrorefining technology could also be used to produce ultra-high purity aluminum for advanced materials applications. The technical objectives for this project were to: - Validate the membrane cell concept with a lab-scale electrorefining cell; - Determine if previously identified voltage increase issue for chloride electrolytes holds for a fluoride-based electrolyte system; - Assess the probability that voltage change issues can be solved; and - Conduct a market and economic analysis to assess commercial feasibility. The process was tested using three different binary alloy compositions (Al-2.0 wt.% Cu, Al-4.7 wt.% Si, Al-0.6 wt.% Fe) and a brazing sheet scrap composition (Al-2.8 wt.% Si-0.7 wt.% Fe-0.8 wt.% Mn),. Purification factors (defined as the initial impurity concentration divided by the final impurity concentration) of greater than 20 were achieved for silicon, iron, copper, and manganese. Cell performance was measured using its current and voltage characteristics and composition analysis of the anode, cathode, and electrolytes. The various cells were autopsied as part of the study. Three electrolyte systems tested were: LiCl-10 wt. % AlCl3, LiCl-10 wt. % AlCl3-5 wt.% AlF3 and LiF-10 wt.% AlF3. An extended four-day run with the LiCl-10 wt.% AlCl3-5 wt.% AlF3 electrolyte system was stable for the entire duration of the experiment, running at energy requirements about one third of the Hoopes and the conventional Hall-Heroult process. Three different anode membranes were investigated with respect to their purification performance and survivability: a woven graphite cloth with 0.05 cm nominal thickness & > 90 % porosity, a drilled rigid membrane with nominal porosity of 33%, and another drilled rigid graphite membrane with increased thickness. The latter rigid drilled graphite was selected as the most promising membrane design. The economic viability of the membrane cell to purify scrap is sensitive to primary & scrap aluminum prices, and the cost of electricity. In particular, it is sensitive to the differential between scrap and primary aluminum price which is highly variable and dependent on the scrap source. In order to be economically viable, any scrap post-processing technology in the U.S. market must have a total operating cost well below the scrap price differential of $0.20-$0.40 per lb to the London Metal Exchange (LME), a margin of 65%-85% of the LME price. The cost to operate the membrane cell is estimated to be < $0.24/lb of purified aluminum. The energy cost is estimated to be $0.05/lb of purified aluminum with the remaining costs being repair and maintenance, electrolyte, labor, taxes and depreciation. The bench-scale work on membrane purification cell process has demonstrated technological advantages and subs

  2. TiN coated aluminum electrodes for DC high voltage electron guns

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloymore »(Ti-6AI-4V). Following gas conditioning, each TiN-coated aluminum electrode reached -225 kV bias voltage while generating less than 100 pA of field emission (« less

  3. Tape casting of magnesium oxide.

    SciTech Connect (OSTI)

    Ayala, Alicia; Corral, Erica L.; Loehman, Ronald E.; Bencoe, Denise Nora; Reiterer, Markus; Shah, Raja A.

    2008-02-01

    A tape casting procedure for fabricating ceramic magnesium oxide tapes has been developed as a method to produce flat sheets of sintered MgO that are thin and porous. Thickness of single layer tapes is in the range of 200-400 {micro}m with corresponding surface roughness values in the range of 10-20 {micro}m as measured by laser profilometry. Development of the tape casting technique required optimization of pretreatment for the starting magnesium oxide (MgO) powder as well as a detailed study of the casting slurry preparation and subsequent heat treatments for sintering and final tape flattening. Milling time of the ceramic powder, plasticizer, and binder mixture was identified as a primary factor affecting surface morphology of the tapes. In general, longer milling times resulted in green tapes with a noticeably smoother surface. This work demonstrates that meticulous control of the entire tape casting operation is necessary to obtain high-quality MgO tapes.

  4. Synthesis and structural characterization of Al{sub 7}C{sub 3}N{sub 3}-homeotypic aluminum silicon oxycarbonitride, (Al{sub 7-x}Si{sub x})(O{sub y}C{sub z}N{sub 6-y-z}) (x{approx}1.2, y{approx}1.0 and z{approx}3.5)

    SciTech Connect (OSTI)

    Urushihara, Daisuke; Kaga, Motoaki; Asaka, Toru; Nakano, Hiromi; Fukuda, Koichiro

    2011-08-15

    A new aluminum silicon oxycarbonitride, (Al{sub 5.8}Si{sub 1.2})(O{sub 1.0}C{sub 3.5}N{sub 1.5}), has been synthesized and characterized by X-ray powder diffraction (XRPD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX) and electron energy loss spectroscopy (EELS). The title compound is hexagonal with space group P6{sub 3}/mmc and unit-cell dimensions a=0.322508(4) nm, c=3.17193(4) nm and V=0.285717(6) nm{sup 3}. The atom ratios of Al:Si and those of O:C:N were, respectively, determined by EDX and EELS. The initial structural model was successfully derived from the XRPD data by the direct methods and further refined by the Rietveld method. The crystal is most probably composed of four types of domains with nearly the same fraction, each of which is isotypic to Al{sub 7}C{sub 3}N{sub 3} with space group P6{sub 3}mc. The existence of another new oxycarbonitride (Al{sub 6.6}Si{sub 1.4})(O{sub 0.7}C{sub 4.3}N{sub 2.0}), which must be homeotypic to Al{sub 8}C{sub 3}N{sub 4}, has been also demonstrated by XRPD and TEM. - Graphical abstract: A new oxycarbonitride discovered in the Al-Si-O-C-N system, (Al{sub 7-x}Si{sub x})(O{sub y}C{sub z}N{sub 6-y-z}) (x{approx}1.2, y{approx}1.0 and z{approx}3.5). The crystal is composed of four types of domains (I, II, III and IV), and hence the structure is represented by a split-atom model. Individual crystal structures can be regarded as layered structures, which consist of A-type [(Al, Si){sub 4}(O, C, N){sub 4}] unit layers and B-type [(Al, Si)(O, C, N){sub 2}] single layers. Highlights: > (Al{sub 5.8}Si{sub 1.2})(O{sub 1.0}C{sub 3.5}N{sub 1.5}) as a new aluminum silicon oxycarbonitride. > Crystal structure is determined and represented by a split-atom model. > Existence of another new oxycarbonitride (Al{sub 6.6}Si{sub 1.4})(O{sub 0.7}C{sub 4.3}N{sub 2.0}) is demonstrated. > Both new materials are formed by oxidation and nitridation of (Al, Si){sub 6}(O, C){sub 5}.

  5. Cellulose-Bound Magnesium Diboride Superconductivity

    E-Print Network [OSTI]

    Ryan, Dominic

    Cellulose-Bound Magnesium Diboride Superconductivity Y.L. Lin and M.O. Pekguleryuz Department a cellulose based polymer. Cellulose tends to react only very weekly and is very robust, hence constitutes

  6. Promising Magnesium Battery Research at ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    charge, giving it potential as a more efficient energy source. Magnesium has a high volumetric capacity, which could mean more battery power in a smaller space. However, to bring...

  7. Nuclear reactor shield including magnesium oxide

    DOE Patents [OSTI]

    Rouse, Carl A. (Del Mar, CA); Simnad, Massoud T. (La Jolla, CA)

    1981-01-01

    An improvement in nuclear reactor shielding of a type used in reactor applications involving significant amounts of fast neutron flux, the reactor shielding including means providing structural support, neutron moderator material, neutron absorber material and other components as described below, wherein at least a portion of the neutron moderator material is magnesium in the form of magnesium oxide either alone or in combination with other moderator materials such as graphite and iron.

  8. Aluminum processing energy benchmark report

    SciTech Connect (OSTI)

    None, None

    2007-02-01

    Substantial energy efficiency gains have been made in the aluminum industry over the past forty years, resulting in a 58 percent decrease in energy utilization.

  9. Low-cost, deterministic quasi-periodic photonic structures for light trapping in thin film silicon solar cells

    E-Print Network [OSTI]

    Sheng, Xing

    Light trapping has been an important issue for thin film silicon solar cells because of the low absorption coefficient in the near infrared range. In this paper, we present a photonic structure which combines anodic aluminum ...

  10. Magnesium-phosphate-glass cements with ceramic-type properties

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.

    1982-09-23

    Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate, exhibits rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

  11. Magnesium phosphate glass cements with ceramic-type properties

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY); Kukacka, Lawrence E. (Port Jefferson, NY)

    1984-03-13

    Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate exhibiting rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

  12. Manufacturing of SiCp Reinforced Magnesium Composite Tubes by Hot Extrusion Processes

    SciTech Connect (OSTI)

    Hwang, Yeong-Maw [National Sun Yat-Sen University-Department of Mechanical and Electro-mechanical Engineering, No.70, Lien-Hai Rd., Kaohsiung, Taiwan (China); Huang, Song-Jeng; Huang, Yu-San [National Chung Cheng University-Department of Mechanical Engineering, 168 University Rd. Ming-Hsiung, ChiaYi, Taiwan (China)

    2011-05-04

    Magnesium alloys have higher specific strength compared with other metals, such as aluminum, copper and steel. Nevertheless, their ductility is still not good for further metal forming and their strength is not large enough for real structure applications. The aim of this paper is to develop magnesium alloy composite tubes reinforced with SiC particulates by the stir-casting method and hot extrusion processes. At first, AZ61/SiCp composite ingots reinforced with 5 wt% SiC particulates are fabricated by the melt-stirring technique. Then, finite element simulations are conducted to analyze the plastic flow of magnesium alloy AZ61 within the die and the temperature distribution of the products. AZ61/SiCp composite tubes are manufactured by hot extrusion using a specially designed die-set for obtaining uniform thickness distribution tubes. Finally, the mechanical properties of the reinforced AZ61/SiCp composite and Mg alloy AZ61 tubes are compared with those of the billets to manifest the advantages of extrusion processes and reinforcement of SiC particulates. The microstructures of the billet and extruded tubes are also observed. Through the improvement of the strength of the tube product, its life cycle can be extended and the energy consumption can be reduced, and eventually the environmental sustainability is achieved.

  13. Ultrahigh-Efficiency Aluminum Production Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultrahigh-Efficiency Aluminum Production Cells Saving Energy and Reducing Carbon Emissions with Cell Redesign and Novel Electrolytes This project will develop a multipolar aluminum...

  14. Synthesis and structural characterization of Al{sub 4}Si{sub 2}C{sub 5}-homeotypic aluminum silicon oxycarbide, (Al{sub 6-x}Si{sub x})(O{sub y}C{sub 5-y}) (x{approx}0.8 and y{approx}1.6)

    SciTech Connect (OSTI)

    Kaga, Motoaki; Urushihara, Daisuke; Iwata, Tomoyuki; Sugiura, Keita [Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555 (Japan); Nakano, Hiromi [Cooperative Research Facility Center, Toyohashi University of Technology, Toyohashi 441-8580 (Japan); Fukuda, Koichiro, E-mail: fukuda.koichiro@nitech.ac.j [Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555 (Japan)

    2010-09-15

    We have prepared a new layered oxycarbide, [Al{sub 5.25(5)}Si{sub 0.75(5)}][O{sub 1.60(7)}C{sub 3.40(7)}], by isothermal heating of (Al{sub 4.4}Si{sub 0.6})(O{sub 1.0}C{sub 3.0}) at 2273 K near the carbon-carbon monoxide buffer. The crystal structure was characterized using X-ray powder diffraction, transmission electron microscopy and energy dispersive X-ray spectroscopy (EDX). The title compound is trigonal with space group R3m (centrosymmetric), Z=3, and hexagonal cell dimensions a=0.32464(2) nm, c=4.00527(14) nm and V=0.36556(3) nm{sup 3}. The atom ratios Al:Si were determined by EDX, and the initial structural model was derived by the direct methods. The final structural model showed the positional disordering of one of the three types of Al/Si sites. The reliability indices were R{sub wp}=4.45% (S=1.30), R{sub p}=3.48%, R{sub B}=2.27% and R{sub F}=1.25%. The crystal is composed of three types of domains with nearly the same fraction, one of which has the crystal structure of space group R3-bar m. The crystal structure of the remaining two domains, which are related by pseudo-symmetry inversion, is noncentrosymmetric with space group R3m. - Graphical Abstract: A new aluminum silicon oxycarbide, (Al{sub 6-x}Si{sub x})(O{sub y}C{sub 5-y}) (x{approx}0.8 and y{approx}1.6). The crystal is composed of three types of domains (I, II and III), and hence the structure is represented by a split-atom model. Individual crystal structures can be regarded as layered structures, which consist of A-type [(Al,Si){sub 4}(O,C){sub 4}] unit layers and B-type [(Al,Si)(O,C){sub 2}] single layers.

  15. Oxide Film and Porosity Defects in Magnesium Alloy AZ91

    SciTech Connect (OSTI)

    Wang, Liang [Mississippi State University (MSU); Rhee, Hongjoo [Mississippi State University (MSU); Felicelli, Sergio D. [Mississippi State University (MSU); Sabau, Adrian S [ORNL; Berry, John T. [Mississippi State University (MSU)

    2009-01-01

    Porosity is a major concern in the production of light metal parts. This work aims to identify some of the mechanisms of microporosity formation in magnesium alloy AZ91. Microstructure analysis was performed on several samples obtained from gravity-poured ingots in graphite plate molds. Temperature data during cooling was acquired with type K thermocouples at 60 Hz at three locations of each casting. The microstructure of samples extracted from the regions of measured temperature was then characterized with optical metallography. Tensile tests and conventional four point bend tests were also conducted on specimens cut from the cast plates. Scanning electron microscopy was then used to observe the microstructure on the fracture surface of the specimens. The results of this study revealed the existence of abundant oxide film defects, similar to those observed in aluminum alloys. Remnants of oxide films were detected on some pore surfaces, and folded oxides were observed in fracture surfaces indicating the presence of double oxides entrained during pouring.

  16. Combustion Synthesis of Magnesium Aluminate

    SciTech Connect (OSTI)

    Kale, M. A. [Physics Department, S.V.S.S. College of Engineering and Research, Nagpur 4411 10 (India); Joshi, C. P. [Physics Department, Ramdeobaba Engineering College, Katol Road, Nagpur 440 013 (India); Moharil, S. V. [Physics Department, RTM Nagpur University, Nagpur, 440033 (India)

    2011-10-20

    In the system MgO-Al{sub 2}O{sub 3}, three compounds MgAl{sub 2}O{sub 4}, MgAl{sub 6}O{sub 10}(also expressed as-Mg{sub 0.4}Al{sub 2.4}O{sub 4}) and MgAl{sub 26}O{sub 40} are well known. Importance of the first two is well established. Magnesium aluminate (MgAl{sub 2}O{sub 4}) spinel is a technologically important material due to its interesting thermal properties. The MgAl{sub 2}O{sub 4} ceramics also find application as humidity sensors. Apart from the luminescence studies, the interest in MgAl{sub 2}O{sub 4} is due to various applications such as humidity-sensing and PEM fuel cells, TL/OSL dosimetry of the ionizing radiations, white light source. Interest in the MgAl{sub 6}O{sub 10} has aroused due to possible use as a substrate for GaN growth. Attempt was made to synthesize these compounds by the combustion synthesis using metal nitrates as oxidizer and urea as a fuel. Compounds MgAl{sub 2}O{sub 4} and MgAl{sub 6}O{sub 10} were formed in a single step, while MgAl{sub 26}O{sub 40} was not formed by this procedure. Activation of MgAl{sub 6}O{sub 10} by rare earth ions like Ce{sup 3+}, Eu{sup 3+} and Tb{sup 3+} and ns{sup 2} ion Pb{sup 2+} could be achieved. Excitation bands for MgAl{sub 6}O{sub 10} are at slightly shorter wavelengths compared to those reported for MgAl{sub 2}O{sub 4}.

  17. The Bolting of Magnesium Components in Car Engines

    E-Print Network [OSTI]

    Cambridge, University of

    1 The Bolting of Magnesium Components in Car Engines Sarennah J.P. Longworth Newnham College of bolting together magnesium alloys components at temperatures around 100o C, such as those found in car

  18. Spray Rolling Aluminum Strip

    SciTech Connect (OSTI)

    Lavernia, E.J.; Delplanque, J-P; McHugh, K.M.

    2006-05-10

    Spray forming is a competitive low-cost alternative to ingot metallurgy for manufacturing ferrous and non-ferrous alloy shapes. It produces materials with a reduced number of processing steps, while maintaining materials properties, with the possibility of near-net-shape manufacturing. However, there are several hurdles to large-scale commercial adoption of spray forming: 1) ensuring strip is consistently flat, 2) eliminating porosity, particularly at the deposit/substrate interface, and 3) improving material yield. Through this program, a new strip/sheet casting process, termed spray rolling, has been developed, which is an innovative manufacturing technique to produce aluminum net-shape products. Spray rolling combines the benefits of twin-roll casting and conventional spray forming, showing a promising potential to overcome the above hurdles associated with spray forming. Spray rolling requires less energy and generates less scrap than conventional processes and, consequently, enables the development of materials with lower environmental impacts in both processing and final products. Spray Rolling was developed as a collaborative project between the University of California-Davis, the Colorado School of Mines, the Idaho National Engineering and Environmental Laboratory, and an industry team. The following objectives of this project were achieved: (1) Demonstration of the feasibility of the spray rolling process at the bench-scale level and evaluation of the materials properties of spray rolled aluminum strip alloys; and (2) Demonstration of 2X scalability of the process and documentation of technical hurdles to further scale up and initiate technology transfer to industry for eventual commercialization of the process.

  19. SOLID STATE JOINING OF MAGNESIUM TO STEEL

    SciTech Connect (OSTI)

    Jana, Saumyadeep; Hovanski, Yuri; Pilli, Siva Prasad; Field, David P.; Yu, Hao; Pan, Tsung-Yu; Santella, M. L.

    2012-06-04

    Friction stir welding and ultrasonic welding techniques were applied to join automotive magnesium alloys to steel sheet. The effect of tooling and process parameters on the post-weld microstructure, texture and mechanical properties was investigated. Static and dynamic loading were utilized to investigate the joint strength of both cast and wrought magnesium alloys including their susceptibility and degradation under corrosive media. The conditions required to produce joint strengths in excess of 75% of the base metal strength were determined, and the effects of surface coatings, tooling and weld parameters on weld properties are presented.

  20. Lithium aluminum/iron sulfide battery having lithium aluminum and silicon as negative electrode

    DOE Patents [OSTI]

    Gilbert, M.; Kaun, T.

    1984-01-20

    A method of making a negative electrode, the electrode made thereby and a secondary electrochemical c

  1. Simulation of Stresses during Casting of Binary Magnesium-Aluminum Alloys

    E-Print Network [OSTI]

    Beckermann, Christoph

    , C. BECKERMANN, Z. ZHEN, and N. HORT A viscoplastic stress model is used to predict contraction, an attempt has been made to numerically simulate the deformations and stresses during permanent mold casting

  2. SIMULATION OF STRESSES DURING CASTING OF BINARY MAGNESIUM-ALUMINUM ALLOYS M.G. Pokorny1

    E-Print Network [OSTI]

    Beckermann, Christoph

    are often prone to hot tearing defects. Hot tears form during solidification due to tensile strains been made to numerically simulate the deformations and stresses during permanent mold casting of an AZ

  3. Chemistry between Magnesium and Multiple Molecules in Tris(8-hydroxyquinoline) Aluminum Films

    E-Print Network [OSTI]

    Schwartz, Jeffrey

    , and Department of Chemistry, Department of Electrical Engineering, and Princeton Materials Institute, Princeton donation of electronic charge to the Alq3. A simple interpretation of this process is the formation. Moreover, the measured N(1s) core level shift is as large (1.8 eV) as that recorded for K5, although the IP

  4. Improved method of preparing p-i-n junctions in amorphous silicon semiconductors

    DOE Patents [OSTI]

    Madan, A.

    1984-12-10

    A method of preparing p/sup +/-i-n/sup +/ junctions for amorphous silicon semiconductors includes depositing amorphous silicon on a thin layer of trivalent material, such as aluminum, indium, or gallium at a temperature in the range of 200/sup 0/C to 250/sup 0/C. At this temperature, the layer of trivalent material diffuses into the amorphous silicon to form a graded p/sup +/-i junction. A layer of n-type doped material is then deposited onto the intrinsic amorphous silicon layer in a conventional manner to finish forming the p/sup +/-i-n/sup +/ junction.

  5. Process for fabricating device structures for real-time process control of silicon doping

    DOE Patents [OSTI]

    Weiner, Kurt H. (San Jose, CA)

    2001-01-01

    Silicon device structures designed to allow measurement of important doping process parameters immediately after the doping step has occurred. The test structures are processed through contact formation using standard semiconductor fabrication techniques. After the contacts have been formed, the structures are covered by an oxide layer and an aluminum layer. The aluminum layer is then patterned to expose the contact pads and selected regions of the silicon to be doped. Doping is then performed, and the whole structure is annealed with a pulsed excimer laser. But laser annealing, unlike standard annealing techniques, does not effect the aluminum contacts because the laser light is reflected by the aluminum. Once the annealing process is complete, the structures can be probed, using standard techniques, to ascertain data about the doping step. Analysis of the data can be used to determine probable yield reductions due to improper execution of the doping step and thus provide real-time feedback during integrated circuit fabrication.

  6. Precipitation and Deposition of Aluminum-Containing Phases in Tank Wastes

    SciTech Connect (OSTI)

    Dabbs, Daniel M.; Aksay, I.A.

    2005-12-01

    In the first phase of our study, we focused on the use of simple organics to raise the solubility of aluminum oxyhydroxides in high alkaline aqueous solvents. In a limited survey of common organic acids, we determined that citric acid had the highest potential to achieve our goal. However, our subsequent investigation revealed that the citric acid appeared to play two roles in the solutions: first, raising the concentration of aluminum in highly alkaline solutions by breaking up or inhibiting ''seed'' polycations and thereby delaying the nucleation and growth of particles; and second, stabilizing nanometer-sized particles in suspension when nucleation did occur. The results of this work were recently published in Langmuir: D.M. Dabbs, U. Ramachandran, S. Lu, J. Liu, L.-Q. Wang, I.A. Aksay, ''Inhibition of Aluminum Oxyhydroxide Precipitation with Citric Acid'' Langmuir, 21, 11690-11695 (2005). The second phase of our work involved the solvation of silicon, again in solutions of high alkalinity. Citric acid, due to its unfavorable pKa values, was not expected to be useful with silicon-containing solutions. Here, the use of polyols was determined to be effective in maintaining silicon-containing particles under high pH conditions but at smaller size with respect to standard suspensions of silicon-containing particles. There were a number of difficulties working with highly alkaline silicon-containing solutions, particularly in solutions at or near the saturation limit. Small deviations in pH resulted in particle formation or dissolution in the absence of the organic agents. One of the more significant observations was that the polyols appeared to stabilize small particles of silicon oxyhydroxides across a wider range of pH, albeit this was difficult to quantify due to the instability of the solutions.

  7. Analysis of the potential for new automotive uses of wrought magnesium

    SciTech Connect (OSTI)

    Gaines, L.; Cuenca, R.; Wu, S.; Stodolsky, F.

    1996-02-01

    The Center for Transportation Research at Argonne National Laboratory has performed a study for the Lightweight Materials Program within the US Department of Energy`s Office of Transportation Materials to evaluate the suitability of wrought magnesium and its alloys to replace steel or aluminum for automotive structural and sheet applications. Vehicle weight reduction is one of the major means available for improving automotive fuel efficiency. Although high-strength steels, Al, and polymers are already being used to achieve significant weight reductions, substantial additional weight reductions could be achieved by increased use of Mg (whose density is less than one-fourth that of steel and only two-thirds that of Al). This study shows that Mg sheet could be used in automotive body nonstructural and semistructural applications, whereas extrusions could be used in such structural applications as spaceframes. The primary barrier to such uses of wrought Mg is high cost.

  8. Processes for producing low cost, high efficiency silicon solar cells

    DOE Patents [OSTI]

    Rohatgi, Ajeet (Marietta, GA); Chen, Zhizhang (Duluth, GA); Doshi, Parag (Atlanta, GA)

    1996-01-01

    Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime .tau. and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. Silicon solar cell efficiencies of 16.9% have been achieved. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime .tau. and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO.sub.x.

  9. Titanium Matrix Composite Tooling Material for Aluminum Die Castings

    Broader source: Energy.gov [DOE]

    In aluminum die-casting, molten aluminum is forced under high pressure into a die cavity. First a "shot" of molten aluminum is ladled into a shot sleeve and the shot of molten aluminum is forced by...

  10. Lead magnesium niobate actuator for micropositioning

    DOE Patents [OSTI]

    Swift, Charles D. (Livermore, CA); Bergum, John W. (Concord, CA)

    1994-01-01

    An improved lead magnesium niobate actuator is disclosed comprising a cylindrical lead magnesium niobate crystal stack mounted in a cylindrical casing wherein a bias means, such as one or more belleville washers, is located between one end of the crystal stack and a partially closed end of the casing; and adjustment means are provided which bear against the opposite end of the crystal stack, whereby an adjustable compressive force is constantly applied against the crystal stack, whether the crystal stack is actuated in an extended position, or is in an unactuated contracted position. In a preferred embodiment, cooling ports are provided for the circulation of coolant in the actuator to cool the crystal stack, and provision is made for removal and replacement of the crystal stack without disconnecting the actuator from the external device being actuated.

  11. Rechargeable Aluminum-Ion Batteries

    SciTech Connect (OSTI)

    Paranthaman, Mariappan Parans [ORNL; Liu, Hansan [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL; Brown, Gilbert M [ORNL

    2015-01-01

    This chapter reports on the development of rechargeable aluminum-ion batteries. A possible concept of rechargeable aluminum/aluminum-ion battery based on low-cost, earth-abundant Al anode, ionic liquid EMImCl:AlCl3 (1-ethyl-3-methyl imidazolium chloroaluminate) electrolytes and MnO2 cathode has been proposed. Al anode has been reported to show good reversibility in acid melts. However, due to the problems in demonstrating the reversibility in cathodes, alternate battery cathodes and battery concepts have also been presented. New ionic liquid electrolytes for reversible Al dissolution and deposition are needed in the future for replacing corrosive EMImCl:AlCl3 electrolytes.

  12. Energy and Technolgy Assessment of Zinc and Magnesium Casting Plants, Technical Report Close-out, August 25,2006

    SciTech Connect (OSTI)

    Twin City Die Castings Company; Tom Heider; North American Die Castings Association

    2006-08-25

    Twin City Die Castings Company of Minneapolis, Minnesota, Twin City Die Castings Company was awarded project No. DE-FG36-05GO15097 to perform plant wide assessments of ten (10) die casting facilities that produce zinc and magnesium alloy castings in order to determine improvements and potential cost savings in energy use. Mr. Heider filled the role of team leader for the project and utilized the North American Die Casting Association (NADCA) to conduct audits at team participant plants so as to hold findings specific to each plant proprietary. The intended benefits of the project were to improve energy use through higher operational and process efficiency for the plants assessed. An improvement in energy efficiency of 5 – 15% was targeted. The primary objectives of the project was to: 1) Expand an energy and technology tool developed by the NADCA under a previous DOE project titled, “Energy and Technology Assessment for Die Casting Plants” for assessing aluminum die casting plants to be more specifically applicable to zinc and magnesium die casting facilities. 2) Conduct ten (10) assessments of zinc and magnesium die casting plants, within eight (8) companies, utilizing the assessment tool to identify, evaluate and recommend opportunities to enhance energy efficiency, minimize waste, and improve productivity. 3) Transfer the assessment tool to the die casting industry at large.

  13. Synthesis of VACNFs on Aluminum Foil and Their Transfer to PDMS while Maintaining Alignment and Impalefection Functionality

    SciTech Connect (OSTI)

    Railsback, Justin [North Carolina State University; Pearce, Ryan [North Carolina State University; Sarac, Mehmet [North Carolina State University; ANDERSON, BRYAN [North Carolina State University; McKnight, Timothy E [ORNL; Tracy, Joseph B [North Carolina State University; Melechko, Anatoli [North Carolina State University

    2013-01-01

    Vertically aligned carbon nanofibers (VACNFs) are synthesized on 3003 aluminum substrates by direct current plasma enhanced chemical vapor deposition. Chemically synthesized nickel nanoparticles were used as the catalyst for growth. The silicon containing coating (SiNx) typically produced when VACNFs are grown on silicon was produced by adding silicon microparticles prior to growth. The fiber array was transferred to PDMS by spin casting a layer on the grown substrates, curing the PDMS, and etching away the aluminum in KOH. Energy dispersive x-ray spectroscopy, scanning electron microscopy, and fluorescence microscopy data are provided. The free standing array in PDMS was then loaded with pVENUS-C1 plasmid and human brain microcapillary endothelial cells (HCMECHBMEC)/d3 cells were successfully impalefected with the plasmid.

  14. Electrolytic Cell For Production Of Aluminum From Alumina

    DOE Patents [OSTI]

    Bradford, Donald R (Underwood, WA); Barnett, Robert J. (Goldendale, WA); Mezner, Michael B. (Sandy, OR)

    2004-11-02

    An electrolytic cell for producing aluminum from alumina having a reservoir for collecting molten aluminum remote from the electrolysis.

  15. Micro Joining of Aluminum Graphite Composites 

    E-Print Network [OSTI]

    Velamati, Manasa

    2012-07-16

    Advanced aluminum graphite composites have unique thermal properties due to opposing coefficients of thermal expansion of aluminum and graphite. The thermal and mechanical properties of such composites are anisotropic due ...

  16. Current technologies and trends of aluminum design

    E-Print Network [OSTI]

    Chen, Michael, 1981-

    2004-01-01

    A literature review of current aluminum technology in the building and construction industry was carried out. Aluminum is an ideal material for building in corrosive environments and for building structures where small ...

  17. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg. 3 figs.

  18. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C. Joseph (Auburn, AL); Dispennette, John M. (Auburn, AL)

    1998-07-07

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg.

  19. MAGNESIUM-BASED METHODS, SYSTEMS, AND DEVICES - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Materials for Magnesium Batteries and Metal Anodes Abstract: An aspect of the present invention is an electrical device, where the device includes a current collector and a porous...

  20. Rechargeable Magnesium Batteries: Low-Cost Rechargeable Magnesium Batteries with High Energy Density

    SciTech Connect (OSTI)

    2010-10-01

    BEEST Project: Pellion Technologies is developing rechargeable magnesium batteries that would enable an EV to travel 3 times farther than it could using Li-ion batteries. Prototype magnesium batteries demonstrate excellent electrochemical behavior; delivering thousands of charge cycles with very little fade. Nevertheless, these prototypes have always stored too little energy to be commercially viable. Pellion Technologies is working to overcome this challenge by rapidly screening potential storage materials using proprietary, high-throughput computer models. To date, 12,000 materials have been identified and analyzed. The resulting best materials have been electrochemically tested, yielding several very promising candidates.

  1. Stationary storage and purification of hydrogen using nickel-coated magnesium powder. Final technical report

    SciTech Connect (OSTI)

    NONE

    1999-12-30

    The following conclusions were reached: (1) The concept of a coating on a magnesium particle serving as a well-supported hydrogen-permselective membrane is sound. (2) Magnesium nitride can be made to coat magnesium particles through chemical vapor deposition within a fluidized bed. (3) Magnesium nitride exhibits the properties necessary for such a coating. (4) Magnesium nitride is not chemically inert to hydrogen in the absence of ammonia at temperatures typically used to hydride/dehydride magnesium.

  2. Transmissive metallic contact for amorphous silicon solar cells

    DOE Patents [OSTI]

    Madan, A.

    1984-11-29

    A transmissive metallic contact for amorphous silicon semiconductors includes a thin layer of metal, such as aluminum or other low work function metal, coated on the amorphous silicon with an antireflective layer coated on the metal. A transparent substrate, such as glass, is positioned on the light reflective layer. The metallic layer is preferably thin enough to transmit at least 50% of light incident thereon, yet thick enough to conduct electricity. The antireflection layer is preferably a transparent material that has a refractive index in the range of 1.8 to 2.2 and is approximately 550A to 600A thick.

  3. Single crystalline mesoporous silicon nanowires

    E-Print Network [OSTI]

    Hochbaum, A.I.

    2010-01-01

    effects in highly porous crystalline silicon, Nature 1991,J. , Fabrication of single-crystalline silicon nanowires bySingle crystalline mesoporous silicon nanowires Allon I.

  4. Single crystalline mesoporous silicon nanowires

    E-Print Network [OSTI]

    Hochbaum, Allon

    2010-01-01

    Quantum Dots: A General crystalline silicon, Nature 1991,1998, 31, 1927-1949. single-crystalline silicon nanowires byof their facilities. Single crystalline mesoporous silicon

  5. Buried oxide layer in silicon

    DOE Patents [OSTI]

    Sadana, Devendra Kumar (Pleasantville, NY); Holland, Orin Wayne (Lenoir, TN)

    2001-01-01

    A process for forming Silicon-On-Insulator is described incorporating the steps of ion implantation of oxygen into a silicon substrate at elevated temperature, ion implanting oxygen at a temperature below 200.degree. C. at a lower dose to form an amorphous silicon layer, and annealing steps to form a mixture of defective single crystal silicon and polycrystalline silicon or polycrystalline silicon alone and then silicon oxide from the amorphous silicon layer to form a continuous silicon oxide layer below the surface of the silicon substrate to provide an isolated superficial layer of silicon. The invention overcomes the problem of buried isolated islands of silicon oxide forming a discontinuous buried oxide layer.

  6. Low-aluminum-content iron-aluminum alloys

    SciTech Connect (OSTI)

    Sikka, V.K.; Baldwin, R.H.; Howell, C.R.

    1993-07-01

    The low room-temperature ductility Fe{sub 3}Al-based alloys is associated with their environmental embrittlement. Reducing the aluminum level from 29 to 16 at % has been found to be an effective method in essentially eliminating the environmental-embrittlement effect and increasing the room-temperature ductility value to over 25%. This paper will present data on alloy compositions, melting, casting and processing methods, and mechanical properties. Plans for future work on these alloys will also be described.

  7. Casting Porosity-Free Grain Refined Magnesium Alloys

    SciTech Connect (OSTI)

    Schwam, David

    2013-08-12

    The objective of this project was to identify the root causes for micro-porosity in magnesium alloy castings and recommend remedies that can be implemented in production. The findings confirm the key role played by utilizing optimal gating and risering practices in minimizing porosity in magnesium castings.?

  8. Purified silicon production system

    DOE Patents [OSTI]

    Wang, Tihu; Ciszek, Theodore F.

    2004-03-30

    Method and apparatus for producing purified bulk silicon from highly impure metallurgical-grade silicon source material at atmospheric pressure. Method involves: (1) initially reacting iodine and metallurgical-grade silicon to create silicon tetraiodide and impurity iodide byproducts in a cold-wall reactor chamber; (2) isolating silicon tetraiodide from the impurity iodide byproducts and purifying it by distillation in a distillation chamber; and (3) transferring the purified silicon tetraiodide back to the cold-wall reactor chamber, reacting it with additional iodine and metallurgical-grade silicon to produce silicon diiodide and depositing the silicon diiodide onto a substrate within the cold-wall reactor chamber. The two chambers are at atmospheric pressure and the system is open to allow the introduction of additional source material and to remove and replace finished substrates.

  9. TiN coated aluminum electrodes for DC high voltage electron guns

    SciTech Connect (OSTI)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-15

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloy (Ti-6Al-4V). Following gas conditioning, each TiN-coated aluminum electrode reached ?225?kV bias voltage while generating less than 100?pA of field emission (<10?pA) using a 40?mm cathode/anode gap, corresponding to field strength of 13.7?MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ?22.5 MV/m with field emission less than 100?pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.

  10. TiN coated aluminum electrodes for DC high voltage electron guns

    SciTech Connect (OSTI)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloy (Ti-6AI-4V). Following gas conditioning, each TiN-coated aluminum electrode reached -225 kV bias voltage while generating less than 100 pA of field emission (<10 pA) using a 40 mm cathode/anode gap, corresponding to field strength of 13.7 MV/m. Smaller gaps were studied to evaluate electrode performance at higher field strength with the best performing TiN-coated aluminum electrode reaching ~22.5 MV/m with field emission less than 100 pA. These results were comparable to those obtained from our best-performing electrodes manufactured from stainless steel, titanium alloy and niobium, as reported in references cited below. The TiN coating provided a very smooth surface and with mechanical properties of the coating (hardness and modulus) superior to those of stainless steel, titanium-alloy, and niobium electrodes. These features likely contributed to the improved high voltage performance of the TiN-coated aluminum electrodes.

  11. Processes for producing low cost, high efficiency silicon solar cells

    DOE Patents [OSTI]

    Rohatgi, Ajeet (Marietta, GA); Doshi, Parag (Altanta, GA); Tate, John Keith (Lawrenceville, GA); Mejia, Jose (Atlanta, GA); Chen, Zhizhang (Duluth, GA)

    1998-06-16

    Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime .tau. and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime .tau. and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO.sub.x. In a fourth RTP process, the process of applying front and back contacts is broken up into two separate respective steps, which enhances the efficiency of the cells, at a slight time expense. In a fifth RTP process, a second RTP step is utilized to fire and adhere the screen printed or evaporated contacts to the structure.

  12. Processes for producing low cost, high efficiency silicon solar cells

    DOE Patents [OSTI]

    Rohatgi, A.; Doshi, P.; Tate, J.K.; Mejia, J.; Chen, Z.

    1998-06-16

    Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime {tau} and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime {tau} and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO{sub x}. In a fourth RTP process, the process of applying front and back contacts is broken up into two separate respective steps, which enhances the efficiency of the cells, at a slight time expense. In a fifth RTP process, a second RTP step is utilized to fire and adhere the screen printed or evaporated contacts to the structure. 28 figs.

  13. Oxidation resistant high temperature thermal cycling resistant coatings on silicon-based substrates and process for the production thereof

    DOE Patents [OSTI]

    Sarin, V.K.

    1990-08-21

    An oxidation resistant, high temperature thermal cycling resistant coated ceramic article for ceramic heat engine applications is disclosed. The substrate is a silicon-based material, i.e. a silicon nitride- or silicon carbide-based monolithic or composite material. The coating is a graded coating of at least two layers: an intermediate AlN or Al[sub x]N[sub y]O[sub z] layer and an aluminum oxide or zirconium oxide outer layer. The composition of the coating changes gradually from that of the substrate to that of the AlN or Al[sub x]N[sub y]O[sub z] layer and further to the composition of the aluminum oxide or zirconium oxide outer layer. Other layers may be deposited over the aluminum oxide layer. A CVD process for depositing the graded coating on the substrate is also disclosed.

  14. Oxidation resistant high temperature thermal cycling resistant coatings on silicon-based substrates and process for the production thereof

    DOE Patents [OSTI]

    Sarin, Vinod K. (Lexington, MA)

    1990-01-01

    An oxidation resistant, high temperature thermal cycling resistant coated ceramic article for ceramic heat engine applications. The substrate is a silicon-based material, i.e. a silicon nitride- or silicon carbide-based monolithic or composite material. The coating is a graded coating of at least two layers: an intermediate AlN or Al.sub.x N.sub.y O.sub.z layer and an aluminum oxide or zirconium oxide outer layer. The composition of the coating changes gradually from that of the substrate to that of the AlN or Al.sub.x N.sub.y O.sub.z layer and further to the composition of the aluminum oxide or zirconium oxide outer layer. Other layers may be deposited over the aluminum oxide layer. A CVD process for depositing the graded coating on the substrate is also disclosed.

  15. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01

    in High-Power Lithium-Ion Batteries for Use in Hybridas Cathodes for Lithium-Ion Batteries. Chem. Mater. 2011,seen in magnesium or lithium ion batteries would operate at

  16. Production of anhydrous aluminum chloride composition

    DOE Patents [OSTI]

    Vandergrift, G.F. III; Krumpelt, M.; Horwitz, E.P.

    1981-10-08

    A process is described for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  17. Advanced silicon photonic modulators

    E-Print Network [OSTI]

    Sorace, Cheryl M

    2010-01-01

    Various electrical and optical schemes used in Mach-Zehnder (MZ) silicon plasma dispersion effect modulators are explored. A rib waveguide reverse biased silicon diode modulator is designed, tested and found to operate at ...

  18. Process for producing silicon

    DOE Patents [OSTI]

    Olson, Jerry M. (Lakewood, CO); Carleton, Karen L. (Boulder, CO)

    1984-01-01

    A process for producing silicon includes forming an alloy of copper and silicon and positioning the alloy in a dried, molten salt electrolyte to form a solid anode structure therein. An electrically conductive cathode is placed in the electrolyte for plating silicon thereon. The electrolyte is then purified to remove dissolved oxides. Finally, an electrical potential is applied between the anode and cathode in an amount sufficient to form substantially pure silicon on the cathode in the form of substantially dense, coherent deposits.

  19. Process for producing silicon

    DOE Patents [OSTI]

    Olson, J.M.; Carleton, K.L.

    1982-06-10

    A process of producing silicon includes forming an alloy of copper and silicon and positioning the alloy in a dried, molten salt electrolyte to form a solid anode structure therein. An electrically conductive cathode is placed in the electrolyte for plating silicon thereon. The electrolyte is then purified to remove dissolved oxides. Finally, an electrical potential is applied between the anode and cathode in an amount sufficient to form substantially pure silicon on the cathode in the form of substantially dense, coherent deposits.

  20. Creep of pure aluminum at cryogenic temperatures 

    E-Print Network [OSTI]

    McDonald, Lacy Clark

    1989-01-01

    are capable of producing stea. dy-state fields greater than 15 Tesla while conventional magnets are only capable of about 3 Tesla, . The second advantage is that superconducting magnets create very homogeneous fields. This is particularly important..., the resistivity of 99. 99% pure aluminum is lower than that of oxygen free high conductivity (OFHC) copper. 2. As magnetic field increases above about 6 Tesla, , copper continues to increase in resistivity whereas aluminum becomes saturated, i. e. , aluminum...

  1. Aluminum Nitride Thin Films on Titanium for Piezoelectric MEMS Applications Seth Boeshore, Emily Parker, Vanni Lughi, Noel C. MacDonald

    E-Print Network [OSTI]

    MacDonald, Noel C.

    Aluminum Nitride Thin Films on Titanium for Piezoelectric MEMS Applications Seth Boeshore, Emily piezoelectric MEMS. Titanium is a new and attractive platform for MEMS because of its corrosion resistance with standard silicon MEMS processing and has found widespread use in film bulk acoustic resonators (FBARs

  2. Electrodeposition of molten silicon

    DOE Patents [OSTI]

    De Mattei, Robert C. (Sunnyvale, CA); Elwell, Dennis (Palo Alto, CA); Feigelson, Robert S. (Saratoga, CA)

    1981-01-01

    Silicon dioxide is dissolved in a molten electrolytic bath, preferably comprising barium oxide and barium fluoride. A direct current is passed between an anode and a cathode in the bath to reduce the dissolved silicon dioxide to non-alloyed silicon in molten form, which is removed from the bath.

  3. The effects of a suboptimal intake of magnesium with soy protein concentrate on parturition, growth, and viability in the rat 

    E-Print Network [OSTI]

    Carson, Sonja D'Awn

    1985-01-01

    fed the magnesium- deficient diet. Magnesium deficiency did not lower femur calcium content, but it significantly decreased femur magnesium. Studies of the human situation would be of interest. ACKNOWLEDGEMENTS The author wishes to express thanks... of dietary magnesium and protein source on tissue 42 Table 11 Effects of dietary treatment on serum magnesium and femur magnesium and calcium 44 LIST OF FIGURES page Figure 1 Weights of dams fed control diet, low magnesium casein diet, soy diet...

  4. High resistivity aluminum antimonide radiation detector

    DOE Patents [OSTI]

    Sherohman, John W. (Livermore, CA); Coombs, III, Arthur W. (Patterson, CA); Yee, Jick H. (Livermore, CA)

    2007-12-18

    Bulk Aluminum Antimonide (AlSb)-based single crystal materials have been prepared for use as ambient (room) temperature X-ray and Gamma-ray radiation detection.

  5. High resistivity aluminum antimonide radiation detector

    DOE Patents [OSTI]

    Sherohman, John W.; Coombs, III, Arthur W.; Yee, Jick H.

    2005-05-03

    Bulk Aluminum Antimonide (AlSb)-based single crystal materials have been prepared for use as ambient (room) temperature X-ray and Gamma-ray radiation detection.

  6. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01

    Activators of Aluminum Electrochemistry in Organic Media. J.I. ; Neff, V. D. Electrochemistry of Polynuclear Transitionaluminum ion based electrochemistry. Closer investigation

  7. Process for converting magnesium fluoride to calcium fluoride

    DOE Patents [OSTI]

    Kreuzmann, A.B.; Palmer, D.A.

    1984-12-21

    This invention is a process for the conversion of magnesium fluoride to calcium fluoride whereby magnesium fluoride is decomposed by heating in the presence of calcium carbonate, calcium oxide or calcium hydroxide. Magnesium fluoride is a by-product of the reduction of uranium tetrafluoride to form uranium metal and has no known commercial use, thus its production creates a significant storage problem. The advantage of this invention is that the quality of calcium fluoride produced is sufficient to be used in the industrial manufacture of anhydrous hydrogen fluoride, steel mill flux or ceramic applications.

  8. Glass-silicon column

    DOE Patents [OSTI]

    Yu, Conrad M.

    2003-12-30

    A glass-silicon column that can operate in temperature variations between room temperature and about 450.degree. C. The glass-silicon column includes large area glass, such as a thin Corning 7740 boron-silicate glass bonded to a silicon wafer, with an electrode embedded in or mounted on glass of the column, and with a self alignment silicon post/glass hole structure. The glass/silicon components are bonded, for example be anodic bonding. In one embodiment, the column includes two outer layers of silicon each bonded to an inner layer of glass, with an electrode imbedded between the layers of glass, and with at least one self alignment hole and post arrangement. The electrode functions as a column heater, and one glass/silicon component is provided with a number of flow channels adjacent the bonded surfaces.

  9. Chloride-Magnesium Ratio of Shallow Groundwaters as a Regional...

    Open Energy Info (EERE)

    Chloride-Magnesium Ratio of Shallow Groundwaters as a Regional Geothermal Indicator in Hawaii Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  10. Interlayer-Expanded Molybdenum Disulfide Nanocomposites for Electrochemical Magnesium Storage

    E-Print Network [OSTI]

    and grid energy storage.1-4 Mg rechargeable batteries (MgRBs) stand out as a promising choice due for the development of advanced materials for next-generation energy storage. KEYWORDS: Magnesium rechargeable

  11. MECS 2006 - Alumina and Aluminum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    documents Manufacturing Energy and Carbon Footprint Alumina and Aluminum More Documents & Publications Alumina and Aluminum (2010 MECS) MECS 2006 - Cement MECS 2006 - Glass...

  12. Commonwealth Aluminum: Manufacturer Conducts Plant-Wide Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Costs by Increasing Energy Efficiency in Process Heating Systems ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market (May 1999) Improving Process Heating System...

  13. Rechargeable Aluminum Batteries with Conducting Polymers as Active...

    Office of Scientific and Technical Information (OSTI)

    Rechargeable Aluminum Batteries with Conducting Polymers as Active Cathode Materials. Citation Details In-Document Search Title: Rechargeable Aluminum Batteries with Conducting...

  14. Improved dual flow aluminum hydrogen peroxide battery

    SciTech Connect (OSTI)

    Marsh, C.; Licht, S.L.; Matthews, D.

    1993-11-30

    A novel dual flow battery configuration is provided comprising an aqueous hydrogen peroxide catholyte, an aqueous anolyte, a porous solid electrocatalyst capable of reducing said hydrogen peroxide and separating said anolyte, and an aluminum anode positioned within said anolyte. Separation of catholyte and anolyte chambers prevents hydrogen peroxide poisoning of the aluminum anode.

  15. Determination of carbon, nitrogen, and oxygen in high purity magnesium 

    E-Print Network [OSTI]

    Roche, Neil Gerard

    1981-01-01

    DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Submitted to the Graduate College of Texas A8cM University in partial i'ulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1981 Major Subject: Chemistry DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Approved as to style and content by: E. A. Schweikert (Chairman of Committee) G. J. Bastiaans (Member) L...

  16. Formation of chemically bonded ceramics with magnesium dihydrogen phosphate binder

    DOE Patents [OSTI]

    Wagh, Arun S.; Jeong, Seung-Young

    2004-08-17

    A new method for combining magnesium oxide, MgO, and magnesium dihydrogen phosphate to form an inexpensive compactible ceramic to stabilize very low solubility metal oxides, ashes, swarfs, and other iron or metal-based additives, to create products and waste forms which can be poured or dye cast, and to reinforce and strengthen the ceramics formed by the addition of fibers to the initial ceramic mixture.

  17. Gating of Permanent Molds for ALuminum Casting

    SciTech Connect (OSTI)

    David Schwam; John F. Wallace; Tom Engle; Qingming Chang

    2004-03-30

    This report summarizes a two-year project, DE-FC07-01ID13983 that concerns the gating of aluminum castings in permanent molds. The main goal of the project is to improve the quality of aluminum castings produced in permanent molds. The approach taken was determine how the vertical type gating systems used for permanent mold castings can be designed to fill the mold cavity with a minimum of damage to the quality of the resulting casting. It is evident that somewhat different systems are preferred for different shapes and sizes of aluminum castings. The main problems caused by improper gating are entrained aluminum oxide films and entrapped gas. The project highlights the characteristic features of gating systems used in permanent mold aluminum foundries and recommends gating procedures designed to avoid common defects. The study also provides direct evidence on the filling pattern and heat flow behavior in permanent mold castings.

  18. Silicon rich nitride for silicon based laser devices

    E-Print Network [OSTI]

    Yi, Jae Hyung

    2008-01-01

    Silicon based light sources, especially laser devices, are the key components required to achieve a complete integrated silicon photonics system. However, the fundamental physical limitation of the silicon material as light ...

  19. Silicon micro-mold

    DOE Patents [OSTI]

    Morales, Alfredo M. (Livermore, CA)

    2006-10-24

    The present invention describes a method for rapidly fabricating a robust 3-dimensional silicon-mold for use in preparing complex metal micro-components. The process begins by depositing a conductive metal layer onto one surface of a silicon wafer. A thin photoresist and a standard lithographic mask are then used to transfer a trace image pattern onto the opposite surface of the wafer by exposing and developing the resist. The exposed portion of the silicon substrate is anisotropically etched through the wafer thickness down to conductive metal layer to provide an etched pattern consisting of a series of rectilinear channels and recesses in the silicon which serve as the silicon micro-mold. Microcomponents are prepared with this mold by first filling the mold channels and recesses with a metal deposit, typically by electroplating, and then removing the silicon micro-mold by chemical etching.

  20. Micromachined silicon electrostatic chuck

    DOE Patents [OSTI]

    Anderson, Robert A. (Albuquerque, NM); Seager, Carleton H. (Albuquerque, NM)

    1996-01-01

    An electrostatic chuck is faced with a patterned silicon plate 11, created y micromachining a silicon wafer, which is attached to a metallic base plate 13. Direct electrical contact between the chuck face 15 (patterned silicon plate's surface) and the silicon wafer 17 it is intended to hold is prevented by a pattern of flat-topped silicon dioxide islands 19 that protrude less than 5 micrometers from the otherwise flat surface of the chuck face 15. The islands 19 may be formed in any shape. Islands may be about 10 micrometers in diameter or width and spaced about 100 micrometers apart. One or more concentric rings formed around the periphery of the area between the chuck face 15 and wafer 17 contain a low-pressure helium thermal-contact gas used to assist heat removal during plasma etching of a silicon wafer held by the chuck. The islands 19 are tall enough and close enough together to prevent silicon-to-silicon electrical contact in the space between the islands, and the islands occupy only a small fraction of the total area of the chuck face 15, typically 0.5 to 5 percent. The pattern of the islands 19, together with at least one hole 12 bored through the silicon veneer into the base plate, will provide sufficient gas-flow space to allow the distribution of the helium thermal-contact gas.

  1. Micromachined silicon electrostatic chuck

    DOE Patents [OSTI]

    Anderson, R.A.; Seager, C.H.

    1996-12-10

    An electrostatic chuck is faced with a patterned silicon plate, created by micromachining a silicon wafer, which is attached to a metallic base plate. Direct electrical contact between the chuck face (patterned silicon plate`s surface) and the silicon wafer it is intended to hold is prevented by a pattern of flat-topped silicon dioxide islands that protrude less than 5 micrometers from the otherwise flat surface of the chuck face. The islands may be formed in any shape. Islands may be about 10 micrometers in diameter or width and spaced about 100 micrometers apart. One or more concentric rings formed around the periphery of the area between the chuck face and wafer contain a low-pressure helium thermal-contact gas used to assist heat removal during plasma etching of a silicon wafer held by the chuck. The islands are tall enough and close enough together to prevent silicon-to-silicon electrical contact in the space between the islands, and the islands occupy only a small fraction of the total area of the chuck face, typically 0.5 to 5 percent. The pattern of the islands, together with at least one hole bored through the silicon veneer into the base plate, will provide sufficient gas-flow space to allow the distribution of the helium thermal-contact gas. 6 figs.

  2. Cathode for aluminum producing electrolytic cell

    DOE Patents [OSTI]

    Brown, Craig W.

    2004-04-13

    A method of producing aluminum in an electrolytic cell comprising the steps of providing an anode in a cell, preferably a non-reactive anode, and also providing a cathode in the cell, the cathode comprised of a base material having low electrical conductivity reactive with molten aluminum to provide a highly electrically conductive layer on the base material. Electric current is passed from the anode to the cathode and alumina is reduced and aluminum is deposited at the cathode. The cathode base material is selected from boron carbide, and zirconium oxide.

  3. Formulation and method for preparing gels comprising hydrous aluminum oxide

    SciTech Connect (OSTI)

    Collins, Jack L.

    2014-06-17

    Formulations useful for preparing hydrous aluminum oxide gels contain a metal salt including aluminum, an organic base, and a complexing agent. Methods for preparing gels containing hydrous aluminum oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including aluminum, an organic base, and a complexing agent.

  4. Inhibition of Aluminum Oxyhydroxide Precipitation with Citric Acid

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    /mol) hydroxide-to-aluminum ratios. Conversely, citric acid also colloidally stabilizes particles in aqueous particles in high pH suspension.7 Past work by our group dealt with the stabilization of aluminum oxide suspensions of aluminum-containing particles. Solutions of aluminum chloride, with and without citric acid

  5. ALUMINUM--2001 6.1 By Patricia A. Plunkert

    E-Print Network [OSTI]

    ALUMINUM--2001 6.1 ALUMINUM By Patricia A. Plunkert Domestic survey data and tables were prepared, international data coordinator. In 2001, 11 domestic companies operated 23 primary aluminum reduction plants consumption in 2001. The recycling rate for aluminum UBCs decreased to 55.4%, compared with 62.1% in 2000

  6. Measuring Speedy Electrons in Silicon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laser, Supercomputer Measure Speedy Electrons in Silicon Laser, Supercomputer Measure Speedy Electrons in Silicon Simulations at NERSC Help Illuminate Attosecond Laser Experiment...

  7. ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions for a Dynamic World

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Aluminum Vision is intended to stimulate a wide variety of R&D activities to accelerate technology development throughout industry.

  8. A scanning Kelvin probe analysis of aluminum and aluminum alloys

    SciTech Connect (OSTI)

    Hansen, D.C.; Grecsek, G.E.; Roberts, R.O.

    1999-07-01

    A scanning Kelvin probe was used to determine a correlation between work function measurements in air and corrosion potential measurements in solution of pure metals. Test panels of AA2024-T3 treated with various surface preparations and primer/coatings were also analyzed using this technique. Filiform corrosion was observed on a scribed panel that had been exposed to a humid environment, whereas on a non-scribed and non-exposed test panel, holidays in the coating were observed and clearly defined. Work function (wf) analysis yielded more noble values for areas within the scribe mark and more active values were observed for areas adjacent to the scribe mark where delamination of the coating and filiform corrosion was observed. The tips of corrosion filaments were found to be anodic in relation to the body of the filament, with areas of activity extending away from the filaments themselves. Measurements made on an aircraft access panel resulted in the detection of a potential gradient within the repair area. These results indicate that the scanning Kelvin probe is a useful non-destructive technique for the detection of delamination and disbanding of coatings, coating anomalies and corrosion susceptibility of coatings on aluminum aircraft alloys.

  9. Electrometallurgical treatment of aluminum-based fuels.

    SciTech Connect (OSTI)

    Willit, J. L.

    1998-07-29

    We have successfully demonstrated aluminum electrorefining from a U-Al-Si alloy that simulates spent aluminum-based reactor fuel. The aluminum product contains less than 200 ppm uranium. All the results obtained have been in agreement with predictions based on equilibrium thermodynamics. We have also demonstrated the need for adequate stirring to achieve a low-uranium product. Most of the other process steps have been demonstrated in other programs. These include uranium electrorefining, transuranic fission product scrubbing, fission product oxidation, and product consolidation by melting. Future work will focus on the extraction of active metal and rare earth fission products by a molten flux salt and scale-up of the aluminum electrorefining.

  10. UV Curable Coatings in Aluminum Can Production 

    E-Print Network [OSTI]

    Donhowe, E. T.

    1994-01-01

    based coatings. The Coors Brewing Company Can Manufacturing Plant has been utilizing this technology in full scale aluminum can production since 1975, and therefore has had the opportunity to evaluate practical operations of the UV technology...

  11. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01

    W. Sea Water Activated Aluminium-Air Cell. Electrochim. ActaADVANCES IN ALUMINUM - AIR SALT-WATER BATTERIES. Abstr. Pap.liquid has been shown to be air and water stable and allowed

  12. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01

    Benign Electrochemical Energy Storage and Conversion DevicesN. J. Aluminum as Anode for Energy Storage and Conversion: Awith other forms of energy storage. In light of this, there

  13. Aqueous recovery of actinides from aluminum alloys

    SciTech Connect (OSTI)

    Gray, J.H.; Chostner, D.F.; Gray, L.W.

    1989-01-01

    Early in the 1980's, a joint Rocky Flats/Savannah River program was established to recover actinides from scraps and residues generated during Rocky Flats purification operations. The initial program involved pyrochemical treatment of Molten Salt Extraction (MSE) chloride salts and Electrorefining (ER) anode heel metal to form aluminum alloys suitable for aqueous processing at Savannah River. Recently Rocky Flats has expressed interest in expanding the aluminum alloy program to include treatment of chloride salt residues from a modified Molten Salt Extraction process and from the Electrorefining purification operations. Samples of the current aluminum alloy buttons were prepared at Rocky Flats and sent to Savannah River Laboratory for flowsheet development and characterization of the alloys. A summary of the scrub alloy-anode heel alloy program will be presented along with recent results from aqueous dissolution studies of the new aluminum alloys. 2 figs., 4 tabs.

  14. Hydrothermal synthesis of hexagonal magnesium hydroxide nanoflakes

    SciTech Connect (OSTI)

    Wang, Qiang, E-mail: qwchem@gmail.com [Laboratory for Micro-sized Functional Materials and College of Elementary Education, Capital Normal University, Beijing 100048 (China); Li, Chunhong [National Laboratory for Superconductivity, Institute of Physics and Beijing National Laboratory for Condensed Matter Physics, Chinese Academy of Sciences, Beijing 100190 (China); Guo, Ming [Laboratory for Micro-sized Functional Materials and College of Elementary Education, Capital Normal University, Beijing 100048 (China); Sun, Lingna [ShenZhen Key Laboratory of Functional Polymer, College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060 (China); Hu, Changwen [Key Laboratory of Cluster Science of Ministry of Education of China, The Institute for Chemical Physics and Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China)

    2014-03-01

    Graphical abstract: Hexagonal Mg(OH){sub 2} nanoflakes were synthesized via hydrothermal method in the presence of PEG-20,000. Results show that PEG-20,000 plays an important role in the formation of this kind of nanostructure. The SAED patterns taken from the different positions on a single hexagonal Mg(OH){sub 2} nanoflake yielded different crystalline structures. The structure of the nanoflakes are polycrystalline and the probable formation mechanism of Mg(OH){sub 2} nanoflakes is discussed. - Highlights: • Hexagonal Mg(OH){sub 2} nanoflakes were synthesized via hydrothermal method. • PEG-20,000 plays an important role in the formation of hexagonal nanostructure. • Mg(OH){sub 2} nanoflakes show different crystalline structures at different positions. • The probable formation mechanism of hexagonal Mg(OH){sub 2} nanoflakes was reported. - Abstract: Hexagonal magnesium hydroxide (Mg(OH){sub 2}) nanoflakes were successfully synthesized via hydrothermal method in the presence of the surfactant polyethylene glycol 20,000 (PEG-20,000). Results show that PEG-20,000 plays an important role in the formation of this kind of nanostructure. The composition, morphologies and structure of the Mg(OH){sub 2} nanoflakes were characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HRTEM), and selected area electron diffraction (SAED). The SAED patterns taken from the different positions on a single hexagonal Mg(OH){sub 2} nanoflake show different crystalline structures. The structure of the nanoflakes are polycrystalline and the probable formation mechanism of Mg(OH){sub 2} nanoflakes is discussed. Brunauer–Emmett–Teller (BET) analysis were performed to investigate the porous structure and surface area of the as-obtained nanoflakes.

  15. Effect of Strain Rate and Temperature on Fracture and Damage of Magnesium Alloy AZ31B 

    E-Print Network [OSTI]

    Rodriguez Atencio, Ana Karina

    2015-04-29

    Due to their low density and high specific strength, magnesium and its alloys are structural metals attractive for the aerospace and automotive industries. However, wide spread use of wrought magnesium is challenged by its ...

  16. Nondestructive evaluation of an environmentally friendly conversion coating for magnesium alloys using optical measurement techniques 

    E-Print Network [OSTI]

    Zuniga, David

    2006-10-30

    Magnesium alloys have one of the highest specific strengths of all construction metals used. Specifically, magnesium alloy castings are used in the aerospace industry to reduce the weight of aerospace vehicles. Coating systems must be employed...

  17. Antifuse with a single silicon-rich silicon nitride insulating layer

    DOE Patents [OSTI]

    Habermehl, Scott D.; Apodaca, Roger T.

    2013-01-22

    An antifuse is disclosed which has an electrically-insulating region sandwiched between two electrodes. The electrically-insulating region has a single layer of a non-hydrogenated silicon-rich (i.e. non-stoichiometric) silicon nitride SiN.sub.X with a nitrogen content X which is generally in the range of 0aluminum and silicon. Arrays of antifuses can also be formed.

  18. Silicone-containing composition

    DOE Patents [OSTI]

    Mohamed, Mustafa

    2012-01-24

    A silicone-containing composition comprises the reaction product of a first component and an excess of an isocyanate component relative to the first component to form an isocyanated intermediary. The first component is selected from one of a polysiloxane and a silicone resin. The first component includes a carbon-bonded functional group selected from one of a hydroxyl group and an amine group. The isocyanate component is reactive with the carbon-bonded functional group of the first component. The isocyanated intermediary includes a plurality of isocyanate functional groups. The silicone-containing composition comprises the further reaction product of a second component, which is selected from the other of the polysiloxane and the silicone resin. The second component includes a plurality of carbon-bonded functional groups reactive with the isocyanate functional groups of the isocyanated intermediary for preparing the silicone-containing composition.

  19. Structure, defects, and strain in silicon-silicon oxide interfaces

    SciTech Connect (OSTI)

    Kova?evi?, Goran Pivac, Branko

    2014-01-28

    The structure of the interfaces between silicon and silicon-oxide is responsible for proper functioning of MOSFET devices while defects in the interface can deteriorate this function and lead to their failure. In this paper we modeled this interface and characterized its defects and strain. MD simulations were used for reconstructing interfaces into a thermodynamically stable configuration. In all modeled interfaces, defects were found in the form of three-coordinated silicon atom, five coordinated silicon atom, threefold-coordinated oxygen atom, or displaced oxygen atom. Three-coordinated oxygen atom can be created if dangling bonds on silicon are close enough. The structure and stability of three-coordinated silicon atoms (P{sub b} defect) depend on the charge as well as on the electric field across the interface. The negatively charged P{sub b} defect is the most stable one, but the electric field resulting from the interface reduces that stability. Interfaces with large differences in periodic constants of silicon and silicon oxide can be stabilized by buckling of silicon layer. The mechanical stress resulted from the interface between silicon and silicon oxide is greater in the silicon oxide layer. Ab initio modeling of clusters representing silicon and silicon oxide shows about three time larger susceptibility to strain in silicon oxide than in silicon if exposed to the same deformation.

  20. Aqueous Alteration and Silicon and Magnesium Isotope Measurements in CR and CV Chondrites

    E-Print Network [OSTI]

    Harju, Ellen Renee

    2015-01-01

    P. (2011) Mineralogy and petrography of MIL 090001, a highlyin CM2 Paris and the petrography of its refractory andWe have attempted to develop a petrography-based sequence of

  1. Nanostructured material for advanced energy storage : magnesium battery cathode development.

    SciTech Connect (OSTI)

    Sigmund, Wolfgang M.; Woan, Karran V.; Bell, Nelson Simmons

    2010-11-01

    Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

  2. Low Temperature Aluminum Dissolution Of Sludge Waste

    SciTech Connect (OSTI)

    Keefer, M.T.; Hamm, B.A.; Pike, J.A. [Washington Savannah River Company, Aiken, SC (United States)

    2008-07-01

    High Level Waste (HLW) at the Savannah River Site (SRS) is currently stored in aging underground storage tanks. This waste is a complex mixture of insoluble solids, referred to as sludge, and soluble salts. Continued long-term storage of these radioactive wastes poses an environmental risk. The sludge is currently being stabilized in the Defense Waste Processing Facility (DWPF) through a vitrification process immobilizing the waste in a borosilicate glass matrix for long-term storage in a federal repository. Without additional treatment, the existing volume of sludge would produce nearly 8000 canisters of vitrified waste. Aluminum compounds, along with other non-radioactive components, represent a significant portion of the sludge mass currently planned for vitrification processing in DWPF. Removing the aluminum from the waste stream reduces the volume of sludge requiring vitrification and improves production rates. Treating the sludge with a concentrated sodium hydroxide (caustic) solution at elevated temperatures (>90 deg. C) to remove aluminum is part of an overall sludge mass reduction effort to reduce the number of vitrified canisters, shorten the life cycle for the HLW system, and reduce the risk associated with the long term storage of radioactive wastes at SRS. A projected reduction of nearly 900 canisters will be achieved by performing aluminum dissolution on six targeted sludge batches; however, a project to develop and install equipment will not be ready for operation until 2013. The associated upgrades necessary to implement a high temperature process in existing facilities are costly and present many technical challenges. Efforts to better understand the characteristics of the sludge mass and dissolution kinetics are warranted to overcome these challenges. Opportunities to further reduce the amount of vitrified waste and increase production rates should also be pursued. Sludge staged in Tank 51 as the next sludge batch for feed to DWPF consisted primarily of radioactive wastes containing a very high aluminum concentration. Based on initial laboratory testing and previous sludge characterization, aluminum in this sludge could be dissolved at low temperature (no more than 65 deg. C) in a concentrated caustic solution. The amount of aluminum predicted to dissolve under these conditions ranged from 25% to 80%. An opportunity existed to remove a significant amount of aluminum prior to vitrification in DWPF and increase the level of understanding of the effects of caustic dissolution of aluminum at lower temperatures. This paper presents the results of a real waste laboratory demonstration and full-scale implementation of a low temperature aluminum dissolution process which should be considered as a viable means to reduce radioactive sludge mass and reduce the amount of waste to be vitrified. (authors)

  3. Polarization properties of real aluminum mirrors; I. Influence of the aluminum oxide layer

    E-Print Network [OSTI]

    van Harten, G; Keller, C U

    2009-01-01

    In polarimetry it is important to characterize the polarization properties of the instrument itself to disentangle real astrophysical signals from instrumental effects. This article deals with the accurate measurement and modeling of the polarization properties of real aluminum mirrors, as used in astronomical telescopes. Main goals are the characterization of the aluminum oxide layer thickness at different times after evaporation and its influence on the polarization properties of the mirror. The full polarization properties of an aluminum mirror are measured with Mueller matrix ellipsometry at different incidence angles and wavelengths. The best fit of theoretical Mueller matrices to all measurements simultaneously is obtained by taking into account a model of bulk aluminum with a thin aluminum oxide film on top of it. Full Mueller matrix measurements of a mirror are obtained with an absolute accuracy of ~1% after calibration. The determined layer thicknesses indicate logarithmic growth in the first few hou...

  4. Hybrid silicon evanescent approach to optical interconnects

    E-Print Network [OSTI]

    2009-01-01

    Big Island, HI, USA, 2006 Hybrid silicon evanescent approach10.1007/s00339-009-5118-1 Hybrid silicon evanescent approachthe recently developed hybrid silicon evanescent platform (

  5. Magnesium Replacement of Aluminum Cast Components in a Production V6 Engine to Effect Cost-Effective Mass Reduction

    Broader source: Energy.gov [DOE]

    Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

  6. NUCLEATION PHENOMENON IN SiC PARTICULATE REINFORCED MAGNESIUM COMPOSITE

    E-Print Network [OSTI]

    Zhou, Wei

    ) and grain refinement were observed in sand cast SiCp/Mg(AZ91) [7] and SiCp/Mg(ZCM630) composites [8 Avenue, Singapore 639798 (Received May 5, 1999) (Accepted June 24, 1999) Keywords: Casting; Nucleation performance of matrix metals and alloys. Most magnesium alloy based MMCs are produced via a casting process

  7. REVIEW ARTICLE A review on magnesium alloys as biodegradable materials

    E-Print Network [OSTI]

    Zheng, Yufeng

    to that of the bone (1.8­ 2.1 g/cm3 ) [1]. (ii) The fracture toughness of magnesium is greater than ceramic bone compared with the traditional Ti6Al4V, better ductility than the synthetic HA, and higher strength

  8. Magnesium oxide inserts for the LECO Carbon Analyzer

    SciTech Connect (OSTI)

    Bagaasen, L.M.; Jensen, C.M.

    1991-01-16

    LECO carbon analysis of plutonium metal and plutonium oxide at the Rocky Flats Plant generates several hundred kilograms of high silica residues each year. The plutonium in these residues is difficult and expensive to recover using production dissolution processes. A magnesium oxide (MgO) insert has been developed that significantly lowers the plutonium recovery costs without adversely affecting accuracy of the carbon analysis.

  9. Crystalline Silicon Photovoltaics Research

    Broader source: Energy.gov [DOE]

    DOE supports crystalline silicon photovoltaic (PV) research and development efforts that lead to market-ready technologies. Below are a list of the projects, summary of the benefits, and discussion...

  10. Metal organic chemical vapor deposition of 111-v compounds on silicon

    DOE Patents [OSTI]

    Vernon, Stanley M. (Wellesley, MA)

    1986-01-01

    Expitaxial composite comprising thin films of a Group III-V compound semiconductor such as gallium arsenide (GaAs) or gallium aluminum arsenide (GaAlAs) on single crystal silicon substrates are disclosed. Also disclosed is a process for manufacturing, by chemical deposition from the vapor phase, epitaxial composites as above described, and to semiconductor devices based on such epitaxial composites. The composites have particular utility for use in making light sensitive solid state solar cells.

  11. Aluminum phosphate ceramics for waste storage

    SciTech Connect (OSTI)

    Wagh, Arun; Maloney, Martin D

    2014-06-03

    The present disclosure describes solid waste forms and methods of processing waste. In one particular implementation, the invention provides a method of processing waste that may be particularly suitable for processing hazardous waste. In this method, a waste component is combined with an aluminum oxide and an acidic phosphate component in a slurry. A molar ratio of aluminum to phosphorus in the slurry is greater than one. Water in the slurry may be evaporated while mixing the slurry at a temperature of about 140-200.degree. C. The mixed slurry may be allowed to cure into a solid waste form. This solid waste form includes an anhydrous aluminum phosphate with at least a residual portion of the waste component bound therein.

  12. Roll Casting of Aluminum Alloy Clad Strip

    SciTech Connect (OSTI)

    Nakamura, R.; Tsuge, H. [Graduate School of Osaka Institute of Technology (Japan); Haga, T. [Osaka Institute of Technology, 5-16-1 Omiya Asahiku Osaka city 535-8585 (Japan); Watari, H. [Tokyo Institute of Technology, 4259 Nagatsuda Midoriku Yokohama city 226-8502 (Japan); Kumai, S. [Gunma University, 1-5-1 tenjin cho Kiryu city 376-8515 (Japan)

    2011-01-17

    Casting of aluminum alloy three layers of clad strip was tried using the two sets of twin roll casters, and effects of the casting parameters on the cladding conditions were investigated. One twin roll caster was mounted on the other twin roll caster. Base strip was 8079 aluminum alloy and overlay strips were 6022 aluminum alloy. Effects of roll-load of upper and lower casters and melt temperature of the lower caster were investigated. When the roll-load of the upper and lower caster was large enough, the overlay strip could be solidified and be connected. The overlay strip could be connected when the melt of the overlay strip cast by the lower caster was low enough. Sound three layers of clad strip could be cast by proper conditions.

  13. ALUMINUM AND CHROMIUM LEACHING WORKSHOP WHITEPAPER

    SciTech Connect (OSTI)

    McCabe, D; Jeff Pike, J; Bill Wilmarth, B

    2007-04-25

    A workshop was held on January 23-24, 2007 to discuss the status of processes to leach constituents from High Level Waste (HLW) sludges at the Hanford and Savannah River Sites. The objective of the workshop was to examine the needs and requirements for the HLW flowsheet for each site, discuss the status of knowledge of the leaching processes, communicate the research plans, and identify opportunities for synergy to address knowledge gaps. The purpose of leaching of non-radioactive constituents from the sludge waste is to reduce the burden of material that must be vitrified in the HLW melter systems, resulting in reduced HLW glass waste volume, reduced disposal costs, shorter process schedules, and higher facility throughput rates. The leaching process is estimated to reduce the operating life cycle of SRS by seven years and decrease the number of HLW canisters to be disposed in the Repository by 1000 [Gillam et al., 2006]. Comparably at Hanford, the aluminum and chromium leaching processes are estimated to reduce the operating life cycle of the Waste Treatment Plant by 20 years and decrease the number of canisters to the Repository by 15,000-30,000 [Gilbert, 2007]. These leaching processes will save the Department of Energy (DOE) billions of dollars in clean up and disposal costs. The primary constituents targeted for removal by leaching are aluminum and chromium. It is desirable to have some aluminum in glass to improve its durability; however, too much aluminum can increase the sludge viscosity, glass viscosity, and reduce overall process throughput. Chromium leaching is necessary to prevent formation of crystalline compounds in the glass, but is only needed at Hanford because of differences in the sludge waste chemistry at the two sites. Improving glass formulations to increase tolerance of aluminum and chromium is another approach to decrease HLW glass volume. It is likely that an optimum condition can be found by both performing leaching and improving formulations. Disposal of the resulting aluminum and chromium-rich streams are different at the two sites, with vitrification into Low Activity Waste (LAW) glass at Hanford, and solidification in Saltstone at SRS. Prior to disposal, the leachate solutions must be treated to remove radionuclides, resulting in increased operating costs and extended facility processing schedules. Interim storage of leachate can also add costs and delay tank closure. Recent projections at Hanford indicate that up to 40,000 metric tons of sodium would be needed to dissolve the aluminum and maintain it in solution, which nearly doubles the amount of sodium in the entire current waste tank inventory. This underscores the dramatic impact that the aluminum leaching can have on the entire system. A comprehensive view of leaching and the downstream impacts must therefore be considered prior to implementation. Many laboratory scale tests for aluminum and chromium dissolution have been run on Hanford wastes, with samples from 46 tanks tested. Three samples from SRS tanks have been tested, out of seven tanks containing high aluminum sludge. One full-scale aluminum dissolution was successfully performed on waste at SRS in 1982, but generated a very large quantity of liquid waste ({approx}3,000,000 gallons). No large-scale tests have been done on Hanford wastes. Although the data to date give a generally positive indication that aluminum dissolution will work, many issues remain, predominantly because of variable waste compositions and changes in process conditions, downstream processing, or storage limitations. Better approaches are needed to deal with the waste volumes and limitations on disposal methods. To develop a better approach requires a more extensive understanding of the kinetics of dissolution, as well as the factors that effect rates, effectiveness, and secondary species. Models of the dissolution rate that have been developed are useful, but suffer from limitations on applicable compositional ranges, mineral phases, and particle properties that are difficult to measure. The experimental

  14. Reaction of Aluminum with Water to Produce Hydrogen - 2010 Update

    Fuel Cell Technologies Publication and Product Library (EERE)

    A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage The purpose of this White Paper is to describe and evaluate the potential of aluminum-water reactions for the

  15. Energy Challenges and Conservation Achievements in the Aluminum Industry 

    E-Print Network [OSTI]

    Sheldon, A. C.

    1979-01-01

    Energy is a vital resource in the production of aluminum. It is economically essential that producers use it efficiently. The aluminum industry developed historically in an economy of energy surplus or abundance. It has responded to energy...

  16. Strategies for aluminum recycling : insights from material system optimization

    E-Print Network [OSTI]

    Li, Preston Pui-Chuen

    2005-01-01

    The dramatic increase in aluminum consumption over the past decades necessitates a societal effort to recycle and reuse these materials to promote true sustainability and energy savings in aluminum production. However, the ...

  17. Reaction of Aluminum with Water to Produce Hydrogen: A Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Produce Hydrogen: A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage. Version 2, 2010. Reaction of Aluminum with Water to Produce Hydrogen: A...

  18. Aluminum plasmonic metamaterials for structural color printing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cheng, Fei; Gao, Jie; Stan, Liliana; Rosenmann, Daniel; Czaplewski, David; Yang, Xiaodong

    2015-05-26

    We report a structural color printing platform based on aluminum plasmonic metamaterials supporting near perfect light absorption and narrow-band spectral response tunable across the visible spectrum to realize high-resolution, angle-insensitive color printing with high color purity and saturation. Additionally, the fabricated metamaterials can be protected by a transparent polymer thin layer for ambient use with further improved color performance. The demonstrated structural color printing with aluminum plasmonic metamaterials offers great potential for relevant applications such as security marking and information storage.

  19. Fabrication and properties of microporous silicon 

    E-Print Network [OSTI]

    Shao, Jianzhong

    1994-01-01

    structure as the wafer from which it was fabricated. Oxidization at 800'C converts the porous silicon totally to amorphous silicon dioxide. Oxidation at 600'C produces a mixture of crystalline silicon and amorphous silicon dioxide. The pore structure...

  20. Aluminum across the Americas: Caribbean Mobilities and Transnational American Studies

    E-Print Network [OSTI]

    Sheller, Mimi

    2013-01-01

    zinc, bauxite, and the hydroelectric power needed to smeltthe Afobaka hydroelectric dam to power an aluminum smelter

  1. The corrosion of aluminum in boric acid solutions 

    E-Print Network [OSTI]

    Bass, Henry Kinsolving

    1956-01-01

    An investigation of the corrosion of aluminum in boric acid solutions was made. The total immersion, continuous agitation method of testing was used. Commercially pure aluminum and two aluminum alloys were exposed to various concentrations of boric acid...THE CORROSION OF ALUMINUM IN BORIC ACID SOLUTIONS A Thesis By HENRI KINSOLVING BASS, JR. Submitted to the Graduate School of the Agricultural and Mechanical College oi' Texas' in partial fulfillment of the requirements for the degree...

  2. Method And Reactor For Production Of Aluminum By Carbothermic Reduction Of Alumina

    DOE Patents [OSTI]

    Aune, Jan Arthur (Ytre Enebakk, NO); Johansen, Kai (Kristiansand, NO)

    2004-10-19

    A hollow partition wall is employed to feed carbon material to an underflow of a carbothermic reduction furnace used to make aluminum. The partition wall divides a low temperature reaction zone where aluminum oxide is reacted with carbon to form aluminum carbide and a high temperature reaction zone where the aluminum carbide and remaining aluminum oxide are reacted to form aluminum and carbon monoxide.

  3. ALUMINUM--1999 5.1 By Patricia A. Plunkert

    E-Print Network [OSTI]

    ALUMINUM--1999 5.1 ALUMINUM By Patricia A. Plunkert Domestic survey data and tables were prepared, international data coordinator. In 1999, 12 domestic companies operated 23 primary aluminum reduction plants beverage can (UBC) scrap accounted for more than one-half of the reported old scrap consumption in 1999

  4. Activated aluminum hydride hydrogen storage compositions and uses thereof

    DOE Patents [OSTI]

    Sandrock, Gary (Ringwood, NJ); Reilly, James (Bellport, NY); Graetz, Jason (Mastic, NY); Wegrzyn, James E. (Brookhaven, NY)

    2010-11-23

    In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

  5. Commonwealth Aluminum: Manufacturer Conducts Plant-Wide Energy Assessments at Two Aluminum Sheet Production Operations

    Broader source: Energy.gov [DOE]

    This case study describes how Commonwealth Industries (now Aleris Rolled Products) conducted plant-wide energy assessments at its aluminum sheet rolling mills in Lewisport, Kentucky, and Uhrichsville, Ohio, to improve process and energy efficiency.

  6. July/August 20056 Casting aluminum

    E-Print Network [OSTI]

    Colton, Jonathan S.

    July/August 20056 Bob Rapp Casting aluminum Lay people unfamiliar with metallurgical processing to cast Al commercially. Perhaps I can interest the reader with a summary of this important process. I refer to casting large Al shapes suitable for rolling, forging, pressing, extruding, or drawing to make

  7. Floating Silicon Method

    SciTech Connect (OSTI)

    Kellerman, Peter

    2013-12-21

    The Floating Silicon Method (FSM) project at Applied Materials (formerly Varian Semiconductor Equipment Associates), has been funded, in part, by the DOE under a “Photovoltaic Supply Chain and Cross Cutting Technologies” grant (number DE-EE0000595) for the past four years. The original intent of the project was to develop the FSM process from concept to a commercially viable tool. This new manufacturing equipment would support the photovoltaic industry in following ways: eliminate kerf losses and the consumable costs associated with wafer sawing, allow optimal photovoltaic efficiency by producing high-quality silicon sheets, reduce the cost of assembling photovoltaic modules by creating large-area silicon cells which are free of micro-cracks, and would be a drop-in replacement in existing high efficiency cell production process thereby allowing rapid fan-out into the industry.

  8. FLOWSHEET FOR ALUMINUM REMOVAL FROM SLUDGE BATCH 6

    SciTech Connect (OSTI)

    Pike, J; Jeffrey Gillam, J

    2008-12-17

    Samples of Tank 12 sludge slurry show a substantially larger fraction of aluminum than originally identified in sludge batch planning. The Liquid Waste Organization (LWO) plans to formulate Sludge Batch 6 (SB6) with about one half of the sludge slurry in Tank 12 and one half of the sludge slurry in Tank 4. LWO identified aluminum dissolution as a method to mitigate the effect of having about 50% more solids in High Level Waste (HLW) sludge than previously planned. Previous aluminum dissolution performed in a HLW tank in 1982 was performed at approximately 85 C for 5 days and dissolved nearly 80% of the aluminum in the sludge slurry. In 2008, LWO successfully dissolved 64% of the aluminum at approximately 60 C in 46 days with minimal tank modifications and using only slurry pumps as a heat source. This report establishes the technical basis and flowsheet for performing an aluminum removal process in Tank 51 for SB6 that incorporates the lessons learned from previous aluminum dissolution evolutions. For SB6, aluminum dissolution process temperature will be held at a minimum of 65 C for at least 24 days, but as long as practical or until as much as 80% of the aluminum is dissolved. As planned, an aluminum removal process can reduce the aluminum in SB6 from about 84,500 kg to as little as 17,900 kg with a corresponding reduction of total insoluble solids in the batch from 246,000 kg to 131,000 kg. The extent of the reduction may be limited by the time available to maintain Tank 51 at dissolution temperature. The range of dissolution in four weeks based on the known variability in dissolution kinetics can range from 44 to more than 80%. At 44% of the aluminum dissolved, the mass reduction is approximately 1/2 of the mass noted above, i.e., 33,300 kg of aluminum instead of 66,600 kg. Planning to reach 80% of the aluminum dissolved should allow a maximum of 81 days for dissolution and reduce the allowance if test data shows faster kinetics. 47,800 kg of the dissolved aluminum will be stored in Tank 8 and 21,000 kg will be stored in saltcake via evaporation. Up to 77% of the total aluminum planned for SB6 may be removed via aluminum dissolution. Storage of the aluminum-laden supernate in Tank 8 will require routine evaluation of the free hydroxide concentration in order to maintain aluminum in solution. Periodic evaluation will be established on concurrent frequency with corrosion program samples as previously established for aluminum-laden supernate from SB5 that is stored in Tank 11.

  9. Switchable mirrors based on nickel-magnesium films

    SciTech Connect (OSTI)

    Richardson,Thomas J.; Slack, Jonathan L.; Armitage, Robert D.; Kostecki, Robert; Farangis, Baker; Rubin, Michael D.

    2001-01-16

    A new type of electrochromic mirror electrode based on reversible uptake of hydrogen in nickel magnesium alloy films is reported. Thin,magnesium-rich Ni-Mg films prepared on glass substrates by cosputtering from Ni and Mg targets are mirror-like in appearance and have low visible transmittance. Upon exposure to hydrogen gas or on reduction in alkaline electrolyte, the films take up hydrogen and become transparent. When hydrogen is removed, the mirror properties are recovered. The transition is believed to result from reversible formation of Mg2NiH4 and MgH2. A thin overlayer of palladium was found to enhance the kinetics of hydrogen insertion and extraction,and to protect the metal surface against oxidation.

  10. Electrochemical thinning of silicon

    DOE Patents [OSTI]

    Medernach, John W. (Albuquerque, NM)

    1994-01-01

    Porous semiconducting material, e.g. silicon, is formed by electrochemical treatment of a specimen in hydrofluoric acid, using the specimen as anode. Before the treatment, the specimen can be masked. The porous material is then etched with a caustic solution or is oxidized, depending of the kind of structure desired, e.g. a thinned specimen, a specimen, a patterned thinned specimen, a specimen with insulated electrical conduits, and so on. Thinned silicon specimen can be subjected to tests, such as measurement of interstitial oxygen by Fourier transform infra-red spectroscopy (FTIR).

  11. Electrochemical thinning of silicon

    DOE Patents [OSTI]

    Medernach, J.W.

    1994-01-11

    Porous semiconducting material, e.g. silicon, is formed by electrochemical treatment of a specimen in hydrofluoric acid, using the specimen as anode. Before the treatment, the specimen can be masked. The porous material is then etched with a caustic solution or is oxidized, depending of the kind of structure desired, e.g. a thinned specimen, a specimen, a patterned thinned specimen, a specimen with insulated electrical conduits, and so on. Thinned silicon specimen can be subjected to tests, such as measurement of interstitial oxygen by Fourier transform infra-red spectroscopy (FTIR). 14 figures.

  12. Process of electrolysis and fractional crystallization for aluminum purification

    DOE Patents [OSTI]

    Dawless, R.K.; Bowman, K.A.; Mazgaj, R.M.; Cochran, C.N.

    1983-10-25

    A method is described for purifying aluminum that contains impurities, the method including the step of introducing such aluminum containing impurities to a charging and melting chamber located in an electrolytic cell of the type having a porous diaphragm permeable by the electrolyte of the cell and impermeable to molten aluminum. The method includes further the steps of supplying impure aluminum from the chamber to the anode area of the cell and electrolytically transferring aluminum from the anode area to the cathode through the diaphragm while leaving impurities in the anode area, thereby purifying the aluminum introduced into the chamber. The method includes the further steps of collecting the purified aluminum at the cathode, and lowering the level of impurities concentrated in the anode area by subjecting molten aluminum and impurities in said chamber to a fractional crystallization treatment wherein eutectic-type impurities crystallize and precipitate out of the aluminum. The eutectic impurities that have crystallized are physically removed from the chamber. The aluminum in the chamber is now suited for further purification as provided in the above step of electrolytically transferring aluminum through the diaphragm. 2 figs.

  13. Production of sodium-22 from proton irradiated aluminum

    DOE Patents [OSTI]

    Taylor, Wayne A. (Los Alamos, NM); Heaton, Richard C. (Los Alamos, NM); Jamriska, David J. (Los Alamos, NM)

    1996-01-01

    A process for selective separation of sodium-22 from a proton irradiated minum target including dissolving a proton irradiated aluminum target in hydrochloric acid to form a first solution including aluminum ions and sodium ions, separating a portion of the aluminum ions from the first solution by crystallization of an aluminum salt, contacting the remaining first solution with an anion exchange resin whereby ions selected from the group consisting of iron and copper are selectively absorbed by the anion exchange resin while aluminum ions and sodium ions remain in solution, contacting the solution with an cation exchange resin whereby aluminum ions and sodium ions are adsorbed by the cation exchange resin, and, contacting the cation exchange resin with an acid solution capable of selectively separating the adsorbed sodium ions from the cation exchange resin while aluminum ions remain adsorbed on the cation exchange resin is disclosed.

  14. Issues for conversion coating of aluminum alloys with hydrotalcite

    SciTech Connect (OSTI)

    Drewien, C.A.; Buchheit, R.G.

    1993-12-01

    Hydrotalcite coatings on aluminum alloys are being developed for corrosion protection of aluminum in aggressive saline environments. Coating bath composition, surface pretreatment, and alloying elements in aluminum all influence the performance of these coatings during salt spray testing. The coating bath, comprised of lithium carbonate, requires aging by dissolution of aluminum into the bath in order to grow corrosion resistant coatings. Coatings formed in non- aged baths do not perform well in salt spray testing. The alloying elements in aluminum alloys, especially copper, influence the coating growth and formation leading to thin coatings. The effect of the alloy elements is to limit the supply of aluminum to the coating/electrolyte interface and hinder growth of hydrotalcite upon aluminum alloys.

  15. Fabrication of porous silicon membranes 

    E-Print Network [OSTI]

    Yue, Wing Kong

    1988-01-01

    . Porous silicon layer is formed by the local dissolution which is initiated by the surface layer and is promoted by the hindrance layers composed of the silicic acid. Local etching or local dissolution is the cause of forming porous structure... of pores were 25 to 45 A with a mean value of 38 A. Microstructure of porous silicon studied by Besle et al. showed two distinct 17 patterns: the structure pattern of porous silicon film on heavily doped silicon and that on slightly doped silicon [26...

  16. Low-Cost Magnesium Sheet Production using the Twin Roll Casting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Low-Cost Magnesium Sheet Production using the Twin Roll Casting Process and Asymmetric Rolling Materials Characterization Capabilities at the High...

  17. Magnesium and pyridoxine intake and mineral content of selected tissues and physical development in rats 

    E-Print Network [OSTI]

    Edgar, Susan Elaine

    1986-01-01

    lower f eed intake s than did rats from other dietary treatments. During lactation, dai ly feed consumpt ion was lower in an ima1 s depr ived of magnesium. Approximately 24 hr postpartum, in dams who consumed a magnesium-deficient diet, the heart... and kidney contained significantly more calcium, 150'% and 300% respectively. During lactation, mild magnesium restriction resulted in increased weight loss by dams and decreased weight gain by pupa. In the of f spring of rats dep1 et ed o f magnesium...

  18. Amorphous silicon photovoltaic devices

    DOE Patents [OSTI]

    Carlson, David E.; Lin, Guang H.; Ganguly, Gautam

    2004-08-31

    This invention is a photovoltaic device comprising an intrinsic or i-layer of amorphous silicon and where the photovoltaic device is more efficient at converting light energy to electric energy at high operating temperatures than at low operating temperatures. The photovoltaic devices of this invention are suitable for use in high temperature operating environments.

  19. Aluminum-doped Zinc Oxide Nanoink

    Energy Innovation Portal (Marketing Summaries) [EERE]

    2014-08-15

    Scientists at Berkeley Lab have developed a method for fabricating conductive aluminum-doped zinc oxide (AZO) nanocrystals that provide a lower cost, less toxic, earth-abundant alternative to the widely used transparent conductive oxide (TCO) indium tin oxide while offering comparable optical and electronic properties. TCOs are used in devices such as flat screen displays, photovoltaic cells, photochromic windows, chemical sensors, and biosensors....

  20. Degassing of Aluminum Alloys Using Ultrasonic Vibration

    SciTech Connect (OSTI)

    Meek, T. T.; Han, Q.; Xu, H.

    2006-06-01

    The research was intended to lead to a better fundamental understanding of the effect of ultrasonic energy on the degassing of liquid metals and to develop practical approaches for the ultrasonic degassing of alloys. The goals of the project described here were to evaluate core principles, establish a quantitative basis for the ultrasonic degassing of aluminum alloy melts, and demonstrate the application of ultrsaonic processing during ingot casting and foundry shape casting.

  1. Experimental superplastic characterization of advanced aluminum alloys 

    E-Print Network [OSTI]

    Kopp, Christopher Carl

    1991-01-01

    categories. The first category is experimental SPF testing procedures at a constant crosshead velocity without an applied hydrostatic pressure, where SPF test data does not accurately measure the superplastic . properties of the alloy under study... recrystallization and cavitation in the alloy. This research involves the design and development of a test system to characterize the SPF properties of advanced aluminum alloys. The system in this study is constructed around an Instron testing machine, high...

  2. On the dissolution of iridium by aluminum.

    SciTech Connect (OSTI)

    Hewson, John C.

    2009-08-01

    The potential for liquid aluminum to dissolve an iridium solid is examined. Substantial uncertainties exist in material properties, and the available data for the iridium solubility and iridium diffusivity are discussed. The dissolution rate is expressed in terms of the regression velocity of the solid iridium when exposed to the solvent (aluminum). The temperature has the strongest influence in the dissolution rate. This dependence comes primarily from the solubility of iridium in aluminum and secondarily from the temperature dependence of the diffusion coefficient. This dissolution mass flux is geometry dependent and results are provided for simplified geometries at constant temperatures. For situations where there is negligible convective flow, simple time-dependent diffusion solutions are provided. Correlations for mass transfer are also given for natural convection and forced convection. These estimates suggest that dissolution of iridium can be significant for temperatures well below the melting temperature of iridium, but the uncertainties in actual rates are large because of uncertainties in the physical parameters and in the details of the relevant geometries.

  3. Multicolored Vertical Silicon Nanowires

    SciTech Connect (OSTI)

    Seo, Kwanyong; Wober, Munib; Steinvurzel, P.; Schonbrun, E.; Dan, Yaping; Ellenbogen, T.; Crozier, K. B.

    2011-04-13

    We demonstrate that vertical silicon nanowires take on a surprising variety of colors covering the entire visible spectrum, in marked contrast to the gray color of bulk silicon. This effect is readily observable by bright-field microscopy, or even to the naked eye. The reflection spectra of the nanowires each show a dip whose position depends on the nanowire radii. We compare the experimental data to the results of finite difference time domain simulations to elucidate the physical mechanisms behind the phenomena we observe. The nanowires are fabricated as arrays, but the vivid colors arise not from scattering or diffractive effects of the array, but from the guided mode properties of the individual nanowires. Each nanowire can thus define its own color, allowing for complex spatial patterning. We anticipate that the color filter effect we demonstrate could be employed in nanoscale image sensor devices.

  4. Amorphous silicon radiation detectors

    DOE Patents [OSTI]

    Street, Robert A. (Palo Alto, CA); Perez-Mendez, Victor (Berkeley, CA); Kaplan, Selig N. (El Cerrito, CA)

    1992-01-01

    Hydrogenated amorphous silicon radiation detector devices having enhanced signal are disclosed. Specifically provided are transversely oriented electrode layers and layered detector configurations of amorphous silicon, the structure of which allow high electric fields upon application of a bias thereby beneficially resulting in a reduction in noise from contact injection and an increase in signal including avalanche multiplication and gain of the signal produced by incoming high energy radiation. These enhanced radiation sensitive devices can be used as measuring and detection means for visible light, low energy photons and high energy ionizing particles such as electrons, x-rays, alpha particles, beta particles and gamma radiation. Particular utility of the device is disclosed for precision powder crystallography and biological identification.

  5. Amorphous silicon radiation detectors

    DOE Patents [OSTI]

    Street, R.A.; Perez-Mendez, V.; Kaplan, S.N.

    1992-11-17

    Hydrogenated amorphous silicon radiation detector devices having enhanced signal are disclosed. Specifically provided are transversely oriented electrode layers and layered detector configurations of amorphous silicon, the structure of which allow high electric fields upon application of a bias thereby beneficially resulting in a reduction in noise from contact injection and an increase in signal including avalanche multiplication and gain of the signal produced by incoming high energy radiation. These enhanced radiation sensitive devices can be used as measuring and detection means for visible light, low energy photons and high energy ionizing particles such as electrons, x-rays, alpha particles, beta particles and gamma radiation. Particular utility of the device is disclosed for precision powder crystallography and biological identification. 13 figs.

  6. Making silicon stronger.

    SciTech Connect (OSTI)

    Boyce, Brad Lee

    2010-11-01

    Silicon microfabrication has seen many decades of development, yet the structural reliability of microelectromechanical systems (MEMS) is far from optimized. The fracture strength of Si MEMS is limited by a combination of poor toughness and nanoscale etch-induced defects. A MEMS-based microtensile technique has been used to characterize the fracture strength distributions of both standard and custom microfabrication processes. Recent improvements permit 1000's of test replicates, revealing subtle but important deviations from the commonly assumed 2-parameter Weibull statistical model. Subsequent failure analysis through a combination of microscopy and numerical simulation reveals salient aspects of nanoscale flaw control. Grain boundaries, for example, suffer from preferential attack during etch-release thereby forming failure-critical grain-boundary grooves. We will discuss ongoing efforts to quantify the various factors that affect the strength of polycrystalline silicon, and how weakest-link theory can be used to make worst-case estimates for design.

  7. A silicon electromechanical photodetector

    E-Print Network [OSTI]

    Tallur, Siddharth

    2013-01-01

    Opto-mechanical systems have enabled wide-band optical frequency conversion and multi-channel all-optical radio frequency amplification. Realization of an on-chip silicon communication platform is limited by photodetectors needed to convert optical information to electrical signals for further signal processing. In this paper we present a coupled silicon micro-resonator, which converts near-IR optical intensity modulation at 174.2MHz and 1.198GHz into motional electrical current. This device emulates a photodetector which detects intensity modulation of continuous wave laser light in the full-width-at-half-maximum bandwidth of the mechanical resonance. The resonant principle of operation eliminates dark current challenges associated with convetional photodetectors.

  8. High Performance Batteries Based on Hybrid Magnesium and Lithium Chemistry

    SciTech Connect (OSTI)

    Cheng, Yingwen; Shao, Yuyan; Zhang, Jiguang; Sprenkle, Vincent L.; Liu, Jun; Li, Guosheng

    2014-01-01

    Magnesium and lithium (Mg/Li) hybrid batteries that combine Mg and Li electrochemistry, consisting of a Mg anode, a lithium-intercalation cathode and a dual-salt electrolyte with both Mg2+ and Li+ ions, were constructed and examined in this work. Our results show that hybrid (Mg/Li) batteries were able to combine the advantages of Li-ion and Mg batteries, and delivered outstanding rate performance (83% for capacities at 15C and 0.1C) and superior cyclic stability (~5% fade after 3000 cycles).

  9. Structural properties and enthalpy of formation of magnesium hydride from quantum Monte Carlo calculations

    E-Print Network [OSTI]

    Alfè, Dario

    Structural properties and enthalpy of formation of magnesium hydride from quantum Monte Carlo calculations to study the structural properties of magnesium hydride MgH2 , including the pressure. INTRODUCTION The energetics of metal hydrides has recently become an issue of large scientific

  10. Diamond-silicon carbide composite

    DOE Patents [OSTI]

    Qian, Jiang; Zhao, Yusheng

    2006-06-13

    Fully dense, diamond-silicon carbide composites are prepared from ball-milled microcrystalline diamond/amorphous silicon powder mixture. The ball-milled powder is sintered (P=5–8 GPa, T=1400K–2300K) to form composites having high fracture toughness. A composite made at 5 GPa/1673K had a measured fracture toughness of 12 MPa.dot.m1/2. By contrast, liquid infiltration of silicon into diamond powder at 5 GPa/1673K produces a composite with higher hardness but lower fracture toughness. X-ray diffraction patterns and Raman spectra indicate that amorphous silicon is partially transformed into nanocrystalline silicon at 5 GPa/873K, and nanocrystalline silicon carbide forms at higher temperatures.

  11. Modified silicon carbide whiskers

    DOE Patents [OSTI]

    Tiegs, T.N.; Lindemer, T.B.

    1991-05-21

    Silicon carbide whisker-reinforced ceramic composites are fabricated in a highly reproducible manner by beneficating the surfaces of the silicon carbide whiskers prior to their usage in the ceramic composites. The silicon carbide whiskers which contain considerable concentrations of surface oxides and other impurities which interact with the ceramic composite material to form a chemical bond are significantly reduced so that only a relatively weak chemical bond is formed between the whisker and the ceramic material. Thus, when the whiskers interact with a crack propagating into the composite the crack is diverted or deflected along the whisker-matrix interface due to the weak chemical bonding so as to deter the crack propagation through the composite. The depletion of the oxygen-containing compounds and other impurities on the whisker surfaces and near surface region is effected by heat treating the whiskers in a suitable oxygen sparging atmosphere at elevated temperatures. Additionally, a sedimentation technique may be utilized to remove whiskers which suffer structural and physical anomalies which render them undesirable for use in the composite. Also, a layer of carbon may be provided on the surface of the whiskers to further inhibit chemical bonding of the whiskers to the ceramic composite material.

  12. Modified silicon carbide whiskers

    DOE Patents [OSTI]

    Tiegs, Terry N. (Lenoir City, TN); Lindemer, Terrence B. (Oak Ridge, TN)

    1991-01-01

    Silicon carbide whisker-reinforced ceramic composites are fabricated in a highly reproducible manner by beneficating the surfaces of the silicon carbide whiskers prior to their usage in the ceramic composites. The silicon carbide whiskers which contain considerable concentrations of surface oxides and other impurities which interact with the ceramic composite material to form a chemical bond are significantly reduced so that only a relatively weak chemical bond is formed between the whisker and the ceramic material. Thus, when the whiskers interact with a crack propagating into the composite the crack is diverted or deflected along the whisker-matrix interface due to the weak chemical bonding so as to deter the crack propagation through the composite. The depletion of the oxygen-containing compounds and other impurities on the whisker surfaces and near surface region is effected by heat treating the whiskers in a suitable oxygen sparaging atmosphere at elevated temperatures. Additionally, a sedimentation technique may be utilized to remove whiskers which suffer structural and physical anomalies which render them undesirable for use in the composite. Also, a layer of carbon may be provided on the surface of the whiskers to further inhibit chemical bonding of the whiskers to the ceramic composite material.

  13. Fracture of welded aluminum thin-walled structures

    E-Print Network [OSTI]

    Zheng, Li, Ph. D. Massachusetts Institute of Technology

    2006-01-01

    A comprehensive methodology was developed in the thesis for damage prediction of welded aluminum thin-walled structures, which includes material modeling, calibration, numerical simulation and experimental verification. ...

  14. Energy and Environmental Profile of the Aluminum Industry

    SciTech Connect (OSTI)

    Margolis, Nancy

    1997-07-01

    This detailed report (PDF 2.5 MB) benchmarks the energy and environmental characteristics of the key technologies used in the major processes of the aluminum industry.

  15. Aluminum-stabilized Nb/sub 3/Sn superconductor

    DOE Patents [OSTI]

    Scanlan, R.M.

    1984-02-10

    This patent discloses an aluminum-stabilized Nb/sub 3/Sn superconductor and process for producing same, utilizing ultrapure aluminum. Ductile components are co-drawn with aluminum to produce a conductor suitable for winding magnets. After winding, the conductor is heated to convert it to the brittle Nb/sub 3/Sn superconductor phase, using a temperature high enough to perform the transformation but still below the melting point of the aluminum. This results in reaction of substantially all of the niobium, while providing stabilization and react-in-place features which are beneficial in the fabrication of magnets utilizing superconducting materials.

  16. Aluminum-detoxifying compounds in roots of Eucalyptus camaldulensis

    E-Print Network [OSTI]

    Tahara, Ko; Hashida, Koh; Ohara, Seiji; Kojima, Katsumi; Shinohara, Kenji

    2009-01-01

    tips of Melaleuca and Eucalyptus species. J For Res. 2005;in aluminum resistance of Eucalyptus camaldulensis andplants (Kochian et al. 2004). Eucalyptus camaldulensis is a

  17. Five Ways Aluminum Foil Is Advancing Science | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    SLAC National Accelerator Laboratory uses massive quantities of aluminum foil to perform "bake out" of their equipment. In a typical bake out, the equipment is blanketed in foil,...

  18. Joining of parts via magnetic heating of metal aluminum powders

    SciTech Connect (OSTI)

    Baker, Ian

    2013-05-21

    A method of joining at least two parts includes steps of dispersing a joining material comprising a multi-phase magnetic metal-aluminum powder at an interface between the at least two parts to be joined and applying an alternating magnetic field (AMF). The AMF has a magnetic field strength and frequency suitable for inducing magnetic hysteresis losses in the metal-aluminum powder and is applied for a period that raises temperature of the metal-aluminum powder to an exothermic transformation temperature. At the exothermic transformation temperature, the metal-aluminum powder melts and resolidifies as a metal aluminide solid having a non-magnetic configuration.

  19. Aluminum-stabilized Nb[sub 3]Sn superconductor

    DOE Patents [OSTI]

    Scanlan, R.M.

    1988-05-10

    Disclosed are an aluminum-stabilized Nb[sub 3]Sn superconductor and process for producing same, utilizing ultrapure aluminum. Ductile components are co-drawn with aluminum to produce a conductor suitable for winding magnets. After winding, the conductor is heated to convert it to the brittle Nb[sub 3]Sn superconductor phase, using a temperature high enough to perform the transformation but still below the melting point of the aluminum. This results in reaction of substantially all of the niobium, while providing stabilization and react-in-place features which are beneficial in the fabrication of magnets utilizing superconducting materials. 4 figs.

  20. High Waste Loading Glass Formulations for Hanford High-Aluminum...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mixtures of aluminum (Al), chromium (Cr), bismuth (Bi), iron (Fe), phosphorous (P), zirconium (Zr), and sulfur (S) compounds as waste-limiting components. Glass compositions for...

  1. Microsoft PowerPoint - Aluminum Concentrations in Storm Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    guarantee its technical correctness. Title: Solid and Dissolved Phase Aluminum in Storm Water Runoff on the Pajarito Plateau, Poster, Individual Permit for Storm Water, NPDES...

  2. MATHEMATICAL MODELING OF THE LITHIUM-ALUMINUM, IRON SULFIDE BATTERY

    E-Print Network [OSTI]

    Pollard, Richard

    2012-01-01

    and J. Newman, Proc. Syrup. Battery Design and Optimization,123, 1364 (1976). Symp, Battery Design and Optimization, S.~ALUMINUM, IRON SULFIDE BATTERY Contents ACKNOWLEDGEMENTS

  3. Vertical silicon nanowire arrays for gas sensing

    E-Print Network [OSTI]

    Zhao, Hangbo

    2014-01-01

    The goal of this research was to fabricate and characterize vertically aligned silicon nanowire gas sensors. Silicon nanowires are very attractive for gas sensing applications and vertically aligned silicon nanowires are ...

  4. Nanotube Fabrication byNanotube Fabrication by Anodic Aluminum Oxide,Anodic Aluminum Oxide,

    E-Print Network [OSTI]

    Rubloff, Gary W.

    Self--Aligned Processing,Aligned Processing, and Atomic Layerand Atomic Layerand Atomic Layerand Atomic Layer Deposition synthesis by atomic layer deposition (ALD) Significance Realizing nanotechnology benefits requires new combined anodic aluminum oxide (AAO) nanostructures with atomic layer deposition (ALD) to fabricate

  5. Economic and environmental evaluation of end-of-life aerospace aluminum options using optimization methods

    E-Print Network [OSTI]

    Chen, Emily, S.B. Massachusetts Institute of Technology

    2008-01-01

    The benefits of recycling have long been understood and the conspicuous energy savings of secondary aluminum production have caused aluminum recycling to increase. Obsolete aircraft are a valuable source of aluminum scrap ...

  6. MECHANICAL TEST RESULTS ON DIPOLE MODEL C-l 25 mm ALUMINUM COLLARS

    E-Print Network [OSTI]

    Peters, C.

    2010-01-01

    RESULTS ON DIPOLE MODEL C-1 25 mm ALUMINUM COLLARS C. PetersRESULTS ON DIPOLE MODEL C-I 25 mm ALUMINUM COLLARS· CraigON DIPOLE MODEL C-I 25 mm ALUMINUM COLLARS Craig Peters

  7. Mechanical properties and microstructures of dual phase steels containing silicon, aluminum and molybdenum

    E-Print Network [OSTI]

    Neill, Thomas John O'

    2011-01-01

    K. (1977). G. E. Dieter, Mechanical Metallurgy, McGraw-Hill,LBL-9047 MECHANICAL PROPERTIES AND MICROSTRUCTURES OF DUALB. Heat Treatment C. Mechanical Testing D. Microscopy

  8. Elucidating the contact mechanics of aluminum silicon surfaces with Green's function molecular dynamics

    E-Print Network [OSTI]

    Mueser, Martin

    on the mesoscopic scales. Local overlap models are not accurate either, because they fail to describe the contact morphology. PACS numbers: 81.40.Pq,46.55.+d I. INTRODUCTION Making liner-less engine blocks cast directly operating conditions. Liner-less engine blocks made of a hypereutectic Al-Si alloy typically require

  9. A NEW A15 MULTIFILAMENTARY SUPERCONDUCTOR BASED ON THE NIOBIUM-ALUMINUM-SILICON SYSTEM

    E-Print Network [OSTI]

    Quinn, G.C.

    2011-01-01

    filaments. diffusion heat treatment to form A schematic of17 required 5 different heat treatments while the thinlyand temperatures. Although the heat-treatment parameters to

  10. Mechanical properties and microstructures of dual phase steels containing silicon, aluminum and molybdenum

    E-Print Network [OSTI]

    Neill, Thomas John O'

    2011-01-01

    annealing, This signifi- cantly increased the strength of commercial 1010 steel andtwo- phase annealing. The Mo containing steels (Figures 5(a)steels containing retained austenite in the martensitic structure, the austenite formed during the two-phase annealing

  11. MICROSTRUCTURE AND MECHANICAL PROPERTIES OF AISI 4340 STEEL MODIFIED WITH ALUMINUM AND SILICON

    E-Print Network [OSTI]

    Bhat, M.S.

    2010-01-01

    13 (1970) . R. A. Tewari and P. R, Dhar, Trans. 11M, p. 35 (C. Wells, Trans. ASM R. A. Tewari and P, R, Dhar, JISI 208,87 (1970) . R. A. Tewari and P. R. Dhar, Trans. 11M, p.

  12. Spray-formed tooling and aluminum strip

    SciTech Connect (OSTI)

    McHugh, K.M.

    1995-11-01

    Spray forming is an advanced materials processing technology that converts a bulk liquid metal to a near-net-shape solid by depositing atomized droplets onto a suitably shaped substrate. By combining rapid solidification processing with product shape control, spray forming can reduce manufacturing costs while improving product quality. De Laval nozzles offer an alternative method to the more conventional spray nozzle designs. Two applications are described: high-volume production of aluminum alloy strip, and the production of specialized tooling, such as injection molds and dies, for rapid prototyping.

  13. AMORPHOUS SILICON-BASED MINIMODULES WITH SILICONE ELASTOMER ENCAPSULATION

    E-Print Network [OSTI]

    Deng, Xunming

    improved, which may make them suitable for encapsulating solar cells once again. We have recently of terrestrial solar cells. It is well known that EVA turns yellow upon extended exposure to ultraviolet light-based polymers (silicones) may not show this effect. Although silicones were used to encapsulate solar cells

  14. Adhesion Impact of Silicone Contamination during Encapsulation...

    Office of Scientific and Technical Information (OSTI)

    Adhesion Impact of Silicone Contamination during Encapsulation. Citation Details In-Document Search Title: Adhesion Impact of Silicone Contamination during Encapsulation. Abstract...

  15. Single-electron shuttle based on a silicon quantum dot

    E-Print Network [OSTI]

    K. W. Chan; M. Mottonen; A. Kemppinen; N. S. Lai; K. Y. Tan; W. H. Lim; A. S. Dzurak

    2011-10-05

    We report on single-electron shuttling experiments with a silicon metal-oxide-semiconductor quantum dot at 300 mK. Our system consists of an accumulated electron layer at the Si/SiO_2 interface below an aluminum top gate with two additional barrier gates used to deplete the electron gas locally and to define a quantum dot. Directional single-electron shuttling from the source and to the drain lead is achieved by applying a dc source-drain bias while driving the barrier gates with an ac voltage of frequency f_p. Current plateaus at integer levels of ef_p are observed up to f_p = 240 MHz operation frequencies. The observed results are explained by a sequential tunneling model which suggests that the electron gas may be heated substantially by the ac driving voltage.

  16. MATHEMATICAL MODELING OF THE LITHIUM-ALUMINUM, IRON SULFIDE BATTERY. I. GALVONOSTATIC DISCHARGE BEHAVIOR

    E-Print Network [OSTI]

    Pollard, Richard

    2012-01-01

    composition profiles in lithium/sulfur battery analogues hasTHE LITHIUM-ALUMINUM, IRON SULFIDE BATTERY. I. GALVONOSTATICthe Lithium-Aluminum, Iron Sulfide Battery I. Galvanostatic

  17. Surface Preparation of Gallium Nitride for Atomic Layer Deposition of Aluminum Oxide /

    E-Print Network [OSTI]

    Kerr, Amanda J.

    2014-01-01

    Nitride for Atomic Layer Deposition of Aluminum Oxide AForce Microscopy Atomic Layer Deposition Capacitance-VoltageSurfaces for Atomic Layer Deposition of Aluminum Oxide” x

  18. Method of forming aluminum oxynitride material and bodies formed by such methods

    DOE Patents [OSTI]

    Bakas, Michael P. (Ammon, ID) [Ammon, ID; Lillo, Thomas M. (Idaho Falls, ID) [Idaho Falls, ID; Chu, Henry S. (Idaho Falls, ID) [Idaho Falls, ID

    2010-11-16

    Methods of forming aluminum oxynitride (AlON) materials include sintering green bodies comprising aluminum orthophosphate or another sacrificial material therein. Such green bodies may comprise aluminum, oxygen, and nitrogen in addition to the aluminum orthophosphate. For example, the green bodies may include a mixture of aluminum oxide, aluminum nitride, and aluminum orthophosphate or another sacrificial material. Additional methods of forming aluminum oxynitride (AlON) materials include sintering a green body including a sacrificial material therein, using the sacrificial material to form pores in the green body during sintering, and infiltrating the pores formed in the green body with a liquid infiltrant during sintering. Bodies are formed using such methods.

  19. Characteristics of Aluminum Biosorption by Sargassum fluitans Biomass

    E-Print Network [OSTI]

    Volesky, Bohumil

    Characteristics of Aluminum Biosorption by Sargassum fluitans Biomass Hak Sung Lee1, * and Bohumil3A 2B2, Canada Abstract: Biomass of nonliving brown seaweed Sargassum fluitans pretreated.5. There are indications that the biomass hydroxyl groups were involved in sequestering the aluminum in the form

  20. Compensated amorphous silicon solar cell

    DOE Patents [OSTI]

    Carlson, David E. (Yardley, PA)

    1980-01-01

    An amorphous silicon solar cell incorporates a region of intrinsic hydrogenated amorphous silicon fabricated by a glow discharge wherein said intrinsic region is compensated by P-type dopants in an amount sufficient to reduce the space charge density of said region under illumination to about zero.

  1. Amorphous silicon ionizing particle detectors

    DOE Patents [OSTI]

    Street, R.A.; Mendez, V.P.; Kaplan, S.N.

    1988-11-15

    Amorphous silicon ionizing particle detectors having a hydrogenated amorphous silicon (a--Si:H) thin film deposited via plasma assisted chemical vapor deposition techniques are utilized to detect the presence, position and counting of high energy ionizing particles, such as electrons, x-rays, alpha particles, beta particles and gamma radiation. 15 figs.

  2. Amorphous silicon ionizing particle detectors

    DOE Patents [OSTI]

    Street, Robert A. (Palo Alto, CA); Mendez, Victor P. (Berkeley, CA); Kaplan, Selig N. (El Cerrito, CA)

    1988-01-01

    Amorphous silicon ionizing particle detectors having a hydrogenated amorphous silicon (a--Si:H) thin film deposited via plasma assisted chemical vapor deposition techniques are utilized to detect the presence, position and counting of high energy ionizing particles, such as electrons, x-rays, alpha particles, beta particles and gamma radiation.

  3. High Areal Capacity Hybrid Magnesium-Lithium-Ion Battery with 99.9% Coulombic Efficiency for Large-Scale Energy Storage

    E-Print Network [OSTI]

    High Areal Capacity Hybrid Magnesium-Lithium-Ion Battery with 99.9% Coulombic Efficiency for Large, United States *S Supporting Information ABSTRACT: Hybrid magnesium-lithium-ion batteries (MLIBs magnesium-lithium-ion batteries (MLIBs), energy storage, Coulombic efficiency, dendrite-free magnesium

  4. Superconducting structure with layers of niobium nitride and aluminum nitride

    DOE Patents [OSTI]

    Murduck, J.M.; Lepetre, Y.J.; Schuller, I.K.; Ketterson, J.B.

    1989-07-04

    A superconducting structure is formed by depositing alternate layers of aluminum nitride and niobium nitride on a substrate. Deposition methods include dc magnetron reactive sputtering, rf magnetron reactive sputtering, thin-film diffusion, chemical vapor deposition, and ion-beam deposition. Structures have been built with layers of niobium nitride and aluminum nitride having thicknesses in a range of 20 to 350 Angstroms. Best results have been achieved with films of niobium nitride deposited to a thickness of approximately 70 Angstroms and aluminum nitride deposited to a thickness of approximately 20 Angstroms. Such films of niobium nitride separated by a single layer of aluminum nitride are useful in forming Josephson junctions. Structures of 30 or more alternating layers of niobium nitride and aluminum nitride are useful when deposited on fixed substrates or flexible strips to form bulk superconductors for carrying electric current. They are also adaptable as voltage-controlled microwave energy sources. 8 figs.

  5. Superconducting structure with layers of niobium nitride and aluminum nitride

    DOE Patents [OSTI]

    Murduck, James M. (Lisle, IL); Lepetre, Yves J. (Lauris, FR); Schuller, Ivan K. (Woodridge, IL); Ketterson, John B. (Evanston, IL)

    1989-01-01

    A superconducting structure is formed by depositing alternate layers of aluminum nitride and niobium nitride on a substrate. Deposition methods include dc magnetron reactive sputtering, rf magnetron reactive sputtering, thin-film diffusion, chemical vapor deposition, and ion-beam deposition. Structures have been built with layers of niobium nitride and aluminum nitride having thicknesses in a range of 20 to 350 Angstroms. Best results have been achieved with films of niobium nitride deposited to a thickness of approximately 70 Angstroms and aluminum nitride deposited to a thickness of approximately 20 Angstroms. Such films of niobium nitride separated by a single layer of aluminum nitride are useful in forming Josephson junctions. Structures of 30 or more alternating layers of niobium nitride and aluminum nitride are useful when deposited on fixed substrates or flexible strips to form bulk superconductors for carrying electric current. They are also adaptable as voltage-controlled microwave energy sources.

  6. Compensated amorphous silicon solar cell

    DOE Patents [OSTI]

    Devaud, Genevieve (629 S. Humphrey Ave., Oak Park, IL 60304)

    1983-01-01

    An amorphous silicon solar cell including an electrically conductive substrate, a layer of glow discharge deposited hydrogenated amorphous silicon over said substrate and having regions of differing conductivity with at least one region of intrinsic hydrogenated amorphous silicon. The layer of hydrogenated amorphous silicon has opposed first and second major surfaces where the first major surface contacts the electrically conductive substrate and an electrode for electrically contacting the second major surface. The intrinsic hydrogenated amorphous silicon region is deposited in a glow discharge with an atmosphere which includes not less than about 0.02 atom percent mono-atomic boron. An improved N.I.P. solar cell is disclosed using a BF.sub.3 doped intrinsic layer.

  7. Cordierite silicon nitride filters

    SciTech Connect (OSTI)

    Sawyer, J.; Buchan, B. ); Duiven, R.; Berger, M. ); Cleveland, J.; Ferri, J. )

    1992-02-01

    The objective of this project was to develop a silicon nitride based crossflow filter. This report summarizes the findings and results of the project. The project was phased with Phase I consisting of filter material development and crossflow filter design. Phase II involved filter manufacturing, filter testing under simulated conditions and reporting the results. In Phase I, Cordierite Silicon Nitride (CSN) was developed and tested for permeability and strength. Target values for each of these parameters were established early in the program. The values were met by the material development effort in Phase I. The crossflow filter design effort proceeded by developing a macroscopic design based on required surface area and estimated stresses. Then the thermal and pressure stresses were estimated using finite element analysis. In Phase II of this program, the filter manufacturing technique was developed, and the manufactured filters were tested. The technique developed involved press-bonding extruded tiles to form a filter, producing a monolithic filter after sintering. Filters manufactured using this technique were tested at Acurex and at the Westinghouse Science and Technology Center. The filters did not delaminate during testing and operated and high collection efficiency and good cleanability. Further development in areas of sintering and filter design is recommended.

  8. Amorphous silicon/crystalline silicon heterojunctions: The future of high-efficiency silicon solar cells

    E-Print Network [OSTI]

    Firestone, Jeremy

    ;5 Record efficiencies #12;6 Diffused-junction solar cells Diffused-junction solar cell Chemical passivation to ~650 mV #12;7 Silicon heterojunction solar cells a-Si:H provides excellent passivation of c-Si surface Heterojunction solar cell Chemical passivation Chemical passivation #12;8 Voc and silicon heterojunction solar

  9. A silicon photomultiplier readout for time of flight neutron spectroscopy with {gamma}-ray detectors

    SciTech Connect (OSTI)

    Pietropaolo, A.; Gorini, G.; Festa, G.; Andreani, C.; De Pascale, M. P.; Reali, E.; Grazzi, F.; Schooneveld, E. M.

    2009-09-15

    The silicon photomultiplier (SiPM) is a recently developed photosensor used in particle physics, e.g., for detection of minimum ionizing particles and/or Cherenkov radiation. Its performance is comparable to that of photomultiplier tubes, but with advantages in terms of reduced volume and magnetic field insensitivity. In the present study, the performance of a gamma ray detector made of an yttrium aluminum perovskite scintillation crystal and a SiPM-based readout is assessed for use in time of flight neutron spectroscopy. Measurements performed at the ISIS pulsed neutron source demonstrate the feasibility of {gamma}-detection based on the new device.

  10. The Role of Silicon Interstitials in the Formation of Boron-Oxygen Defects in Crystalline Silicon

    E-Print Network [OSTI]

    The Role of Silicon Interstitials in the Formation of Boron-Oxygen Defects in Crystalline Silicon@ise.fhg.de Keywords: crystalline silicon, Czochralski, boron-oxygen defect, silicon interstitial Abstract. Oxygen-rich crystalline silicon materials doped with boron are plagued by the presence of a well-known carrier

  11. Finite Ground Coplanar Lines on CMOS Grade Silicon with a Thick Embedded Silicon Oxide Layer Using

    E-Print Network [OSTI]

    Tentzeris, Manos

    Finite Ground Coplanar Lines on CMOS Grade Silicon with a Thick Embedded Silicon Oxide Layer Using grade silicon wafer (poxide layer have been developed using on a CMOS grade silicon substrate ( ~ 4 . 0 1Cl-cm) with an embedded thick silicon oxide layer using

  12. Amorphous Silicon-Carbon Nanostructure Photovoltaic Devices

    E-Print Network [OSTI]

    Schriver, Maria Christine

    2012-01-01

    and Photovoltaic Performance . . . . . . . . . . . . . . .Amorphous Silicon as a Photovoltaic Material 2.1.2ii Photovoltaic Model . . . . . . . . . . .

  13. Amorphous silicon enhanced metal-insulator-semiconductor contacts for silicon solar cells

    SciTech Connect (OSTI)

    Bullock, J. Cuevas, A.; Yan, D.; Demaurex, B.; Hessler-Wyser, A.; De Wolf, S.

    2014-10-28

    Carrier recombination at the metal-semiconductor contacts has become a significant obstacle to the further advancement of high-efficiency diffused-junction silicon solar cells. This paper provides the proof-of-concept of a procedure to reduce contact recombination by means of enhanced metal-insulator-semiconductor (MIS) structures. Lightly diffused n{sup +} and p{sup +} surfaces are passivated with SiO{sub 2}/a-Si:H and Al{sub 2}O{sub 3}/a-Si:H stacks, respectively, before the MIS contacts are formed by a thermally activated alloying process between the a-Si:H layer and an overlying aluminum film. Transmission/scanning transmission electron microscopy (TEM/STEM) and energy dispersive x-ray spectroscopy are used to ascertain the nature of the alloy. Idealized solar cell simulations reveal that MIS(n{sup +}) contacts, with SiO{sub 2} thicknesses of ?1.55?nm, achieve the best carrier-selectivity producing a contact resistivity ?{sub c} of ?3 m? cm{sup 2} and a recombination current density J{sub 0c} of ?40 fA/cm{sup 2}. These characteristics are shown to be stable at temperatures up to 350?°C. The MIS(p{sup +}) contacts fail to achieve equivalent results both in terms of thermal stability and contact characteristics but may still offer advantages over directly metallized contacts in terms of manufacturing simplicity.

  14. High specific activity silicon-32

    DOE Patents [OSTI]

    Phillips, Dennis R. (Los Alamos, NM); Brzezinski, Mark A. (Santa Barbara, CA)

    1996-01-01

    A process for preparation of silicon-32 is provided and includes contacting an irradiated potassium chloride target, including spallation products from a prior irradiation, with sufficient water, hydrochloric acid or potassium hydroxide to form a solution, filtering the solution, adjusting pH of the solution to from about 5.5 to about 7.5, admixing sufficient molybdate-reagent to the solution to adjust the pH of the solution to about 1.5 and to form a silicon-molybdate complex, contacting the solution including the silicon-molybdate complex with a dextran-based material, washing the dextran-based material to remove residual contaminants such as sodium-22, separating the silicon-molybdate complex from the dextran-based material as another solution, adding sufficient hydrochloric acid and hydrogen peroxide to the solution to prevent reformation of the silicon-molybdate complex and to yield an oxidization state of the molybdate adapted for subsequent separation by an anion exchange material, contacting the solution with an anion exchange material whereby the molybdate is retained by the anion exchange material and the silicon remains in solution, and optionally adding sufficient alkali metal hydroxide to adjust the pH of the solution to about 12 to 13. Additionally, a high specific activity silicon-32 product having a high purity is provided.

  15. Process for forming retrograde profiles in silicon

    DOE Patents [OSTI]

    Weiner, Kurt H. (San Jose, CA); Sigmon, Thomas W. (Phoenix, AZ)

    1996-01-01

    A process for forming retrograde and oscillatory profiles in crystalline and polycrystalline silicon. The process consisting of introducing an n- or p-type dopant into the silicon, or using prior doped silicon, then exposing the silicon to multiple pulses of a high-intensity laser or other appropriate energy source that melts the silicon for short time duration. Depending on the number of laser pulses directed at the silicon, retrograde profiles with peak/surface dopant concentrations which vary from 1-1e4 are produced. The laser treatment can be performed in air or in vacuum, with the silicon at room temperature or heated to a selected temperature.

  16. Diode laser welding of aluminum to steel

    SciTech Connect (OSTI)

    Santo, Loredana; Quadrini, Fabrizio; Trovalusci, Federica [University of Rome Tor Vergata, Department of Mechanical Engineering, Via del Politecnico 1, 00133 Rome (Italy)

    2011-05-04

    Laser welding of dissimilar materials was carried out by using a high power diode laser to join aluminum to steel in a butt-joint configuration. During testing, the laser scan rate was changed as well as the laser power: at low values of fluence (i.e. the ratio between laser power and scan rate), poor joining was observed; instead at high values of fluence, an excess in the material melting affected the joint integrity. Between these limiting values, a good aesthetics was obtained; further investigations were carried out by means of tensile tests and SEM analyses. Unfortunately, a brittle behavior was observed for all the joints and a maximum rupture stress about 40 MPa was measured. Apart from the formation of intermeltallic phases, poor mechanical performances also depended on the chosen joining configuration, particularly because of the thickness reduction of the seam in comparison with the base material.

  17. Silicon Oxynitride Thin Film Barriers for PV Packaging (Poster)

    SciTech Connect (OSTI)

    del Cueto, J. A.; Glick, S. H.; Terwilliger, K. M.; Jorgensen, G. J.; Pankow, J. W.; Keyes, B. M.; Gedvilas, L. M.; Pern, F. J.

    2006-10-03

    Dielectric, adhesion-promoting, moisture barriers comprised of silicon oxynitride thin film materials (SiOxNy with various material stoichiometric compositions x,y) were applied to: 1) bare and pre-coated soda-lime silicate glass (coated with transparent conductive oxide SnO2:F and/or aluminum), and polymer substrates (polyethylene terephthalate, PET, or polyethylene napthalate, PEN); plus 2) pre- deposited photovoltaic (PV) cells and mini-modules consisting of amorphous silicon (a-Si) and copper indium gallium diselenide (CIGS) thin-film PV technologies. We used plasma enhanced chemical vapor deposition (PECVD) process with dilute silane, nitrogen, and nitrous oxide/oxygen gas mixtures in a low-power (< or = 10 milliW per cm2) RF discharge at ~ 0.2 Torr pressure, and low substrate temperatures < or = 100(degrees)C, over deposition areas ~ 1000 cm2. Barrier properties of the resulting PV cells and coated-glass packaging structures were studied with subsequent stressing in damp-heat exposure at 85(degrees)C/85% RH. Preliminary results on PV cells and coated glass indicate the palpable benefits of the barriers in mitigating moisture intrusion and degradation of the underlying structures using SiOxNy coatings with thicknesses in the range of 100-200 nm.

  18. Ultraviolet selective silicon photodiode 

    E-Print Network [OSTI]

    Chintapalli, Koteswara Rao

    1992-01-01

    (' silicon surfa&(& that n&ost of t h&) phologeneraied hole-el( & tron pairs are k&st by surface rccornbinai ion before being nolle&. trxl hy a pr). jun?i, ion. The major cause of surl'a&. e re?omhination is probably due Io lifetim(. shortening ol' Lhe...Luation degrades by &legr(es during (xposure Io high-cncrgy photo(&s such as in ultraviolet light. The second approa?h is a S&:hottky-b))rricr Iype. ol' photodiodc consisting of a iranspar()nt, thin metal film [I I]. ln I. his d(vi?e, ii, is dif%?ult to a...

  19. Vehicle Technologies Office: Long-Term Lightweight Materials Research (Magnesium and Carbon Fiber)

    Broader source: Energy.gov [DOE]

    The Vehicle Technologies Office supports research into magnesium and carbon fiber reinforced composites, which could reduce the weight of some components by 50-75 percent in the long-term.

  20. Vehicle Technologies Office Merit Review 2015: Magnesium-Intensive Front End Sub-Structure Development

    Broader source: Energy.gov [DOE]

    Presentation given by USAMP at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about magnesium-intensive front end sub...

  1. SIMULATION OF POROSITY AND HOT TEARS IN A SQUEEZE CAST MAGNESIUM CONTROL ARM

    E-Print Network [OSTI]

    Beckermann, Christoph

    : Magnesium Alloys, Casting, Shrinkage Porosity, Hot Tears, Modeling Abstract Simulations are performed within commercial casting simulation software to predict shrinkage porosity and hot tears changes are introduced to mitigate the shrinkage and hot tear problems in these castings. The comparisons

  2. Novel Magnesium Alloys Developed for Biomedical Application: A Review Nan Li, Yufeng Zheng*

    E-Print Network [OSTI]

    Zheng, Yufeng

    of their high me- chanical strength as well as high fracture toughness. The den- sities of magnesium (1.738 g efficiency, so higher strength, and better ductility and corrosion resistance are required. Nevertheless

  3. Controlling the Biodegradation of Magnesium Implants Through Nanostructured Calcium-Phosphate Coating

    E-Print Network [OSTI]

    Iskandar, Maria Emil

    2012-01-01

    In-Seop L. Calcium phosphate coating on magnesium alloy forsimulated body fluid. Surface Coating Technology 2004:92-98.XN. Electrodeposition of Ca-P coatings on biodegradable Mg

  4. New Process for Grain Refinement of Aluminum. Final Report

    SciTech Connect (OSTI)

    Dr. Joseph A. Megy

    2000-09-22

    A new method of grain refining aluminum involving in-situ formation of boride nuclei in molten aluminum just prior to casting has been developed in the subject DOE program over the last thirty months by a team consisting of JDC, Inc., Alcoa Technical Center, GRAS, Inc., Touchstone Labs, and GKS Engineering Services. The Manufacturing process to make boron trichloride for grain refining is much simpler than preparing conventional grain refiners, with attendant environmental, capital, and energy savings. The manufacture of boride grain refining nuclei using the fy-Gem process avoids clusters, salt and oxide inclusions that cause quality problems in aluminum today.

  5. Method of forming buried oxide layers in silicon

    DOE Patents [OSTI]

    Sadana, Devendra Kumar (Pleasantville, NY); Holland, Orin Wayne (Lenoir City, TN)

    2000-01-01

    A process for forming Silicon-On-Insulator is described incorporating the steps of ion implantation of oxygen into a silicon substrate at elevated temperature, ion implanting oxygen at a temperature below 200.degree. C. at a lower dose to form an amorphous silicon layer, and annealing steps to form a mixture of defective single crystal silicon and polycrystalline silicon or polycrystalline silicon alone and then silicon oxide from the amorphous silicon layer to form a continuous silicon oxide layer below the surface of the silicon substrate to provide an isolated superficial layer of silicon. The invention overcomes the problem of buried isolated islands of silicon oxide forming a discontinuous buried oxide layer.

  6. The tolerance of two varieties of cotton to relatively high levels of sodium and magnesium 

    E-Print Network [OSTI]

    Parekh, Manhar C

    1969-01-01

    THE TO'ERANCE OF TNO VARIETIES OF COTTON TO RELATIVELY HIGH LEVELS OF SODIUM AND MAGNESIUM A Tnesis by Msnhar C. Parekh Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree...) (Nember) (Nemb ) August 1969 ABSTRACT The Tolerance of Two Varieties of Cotton to Relatively High Levels of Sodium and Magnesium. (August 1969) Masher C. Parekh, B. S. , Gujarat University, Directed by: Dr. H. E. Joham An experiment was conducted...

  7. A study of the role of calcium and magnesium in casein micellar structure in human milk 

    E-Print Network [OSTI]

    Gallaway, Sheila Ann

    1988-01-01

    ) Karen . Kubena (Member) Wa ne L. R&cko11 (Member) G. C. Smith (Head of Department) December 1988 ABSTRACT A Study of the Role of Calcium and Magnesium in Casein Micellar Structure in Human Milk. (December 1988) Sheila Ann Gallaway, B, S.... , Texas ASM University; M. S. , Texas ASM University Chair of Advisory Committee: Dr. C. W. Dill The effects of EDTA, phosphatase hydrolysis, calcium chloride, and magnesium chloride on human casein micelles were observed using electron microscopy...

  8. Novel Nonflammable Electrolytes for Secondary Magnesium Batteries and High Voltage Electrolytes for Electrochemcial Supercapacitors

    SciTech Connect (OSTI)

    Dr. Brian Dixon

    2008-12-30

    Magnesium has been used successfully in primary batteries, but its use in rechargeable cells has been stymied by the lack of suitable non-aqueous electrolyte that can conduct Mg+2 species, combined with poor stripping and plating properties. The development of a suitable cathode material for rechargeable magnesium batteries has also been a roadblock, but a nonflammable electrolyte is key. Likewise, the development of safe high voltage electrochemical supercapaitors has been stymied by the use of flammable solvents in the liquid electrolyte; to wit, acetonitrile. The purpose of the research conducted in this effort was to identify useful compositions of magnesium salts and polyphosphate solvents that would enable magnesium ions to be cycled within a secondary battery design. The polyphosphate solvents would provide the solvent for the magnesium salts while preventing the electrolyte from being flammable. This would enable these novel electrolytes to be considered as an alternative to THF-based electrolytes. In addition, we explored several of these solvents together with lithium slats for use as high voltage electrolytes for carbon-based electrochemical supercapacitors. The research was successful in that: 1) Magnesium imide dissolved in a phosphate ester solvent that contains a halogented phosphate ester appears to be the preferred electrolyte for a rechargeable Mg cell. 2) A combination of B-doped CNTs and vanadium phosphate appear to be the cathode of choice for a rechargeable Mg cell by virtue of higher voltage and better reversibility. 3) Magnesium alloys appear to perform better than pure magnesium when used in combination with the novel polyphosphate electrolytes. Also, this effort has established that Phoenix Innovationâ??s family of phosphonate/phosphate electrolytes together with specific lithium slats can be used in supercapacitor systems at voltages of greater than 10V.

  9. Polarization manipulation in silicon photonics

    E-Print Network [OSTI]

    Su, Zhan, S.M. Massachusetts Institute of Technology

    2013-01-01

    Silicon photonics is moving fast toward industrialization. It satisfies the increasing demand for higher speed, larger bandwidth communication. Thus it has a wide range of applications including high-performance computing, ...

  10. Mechanical Dissipation in Silicon Flexures

    E-Print Network [OSTI]

    S. Reid; G. Cagnoli; D. R. M. Crooks; J. Hough; P. Murray; S. Rowan; M. M. Fejer; R. Route; S. Zappe

    2005-10-28

    The thermo-mechanical properties of silicon make it of significant interest as a possible material for mirror substrates and suspension elements for future long-baseline gravitational wave detectors. The mechanical dissipation in 92um thick single-crystal silicon cantilevers has been observed over the temperature range 85 K to 300 K, with dissipation approaching levels down to phi = 4.4E-7.

  11. Gas-tungsten arc welding of aluminum alloys

    DOE Patents [OSTI]

    Frye, L.D.

    1982-03-25

    The present invention is directed to a gas-tungsten arc welding method for joining together structures formed of aluminum alloy with these structures disposed contiguously to a heat-damagable substrate of a metal dissimilar to the aluminum alloy. The method of the present invention is practiced by diamond machining the fay surfaces of the aluminum alloy structures to profice a mirror finish thereon having a surface roughness in the order of about one microinch. The fay surface are aligned and heated sufficiently by the tungsten electrode to fuse the aluminum alloy continguous to the fay surfaces to effect the weld joint. The heat input used to provide an oxide-free weld is significantly less than that required if the fay surfaces were prepared by using conventional chemical and mechanical practices.

  12. Primary aluminum production : climate policy, emissions and costs

    E-Print Network [OSTI]

    Harnisch, Jochen.; Sue Wing, Ian.; Jacoby, Henry D.; Prinn, Ronald G.

    Climate policy regarding perfluorocarbons (PFCs) may have a significant influence on investment decisions in the production of primary aluminum. This work demonstrates an integrated analysis of the effectiveness and likely ...

  13. Five Ways Aluminum Foil Is Advancing Science | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    practice for your x-ray laser Have you ever accidentally put aluminum foil in the microwave and turned it on? I imagine that is similar to experiments that researchers use to...

  14. Aluminum Surface Texturing by Means of Laser Interference Metallurgy...

    Office of Scientific and Technical Information (OSTI)

    laser interferometry produced by two beams of a pulsed Nd:YAG laser operating at 10Hz of frequency to clean aluminum surfaces, and meanwhile creating periodic and rough surface...

  15. New, More Efficient Technology for Remelting Aluminum Chips 

    E-Print Network [OSTI]

    Hosek, D.

    1994-01-01

    This project will introduce a new, more efficient technology for remelting the considerable volume of aluminum by 6.5% . Automated conveyors will transport chips from the machining operation to the new remelting operation for recycling. A reduction...

  16. The design of a power system using treated aluminum fuel

    E-Print Network [OSTI]

    Slocum, Jonathan (Jonathan T.)

    2015-01-01

    Aluminum is the most abundant metal in the Earth's crust and a highly sought after fuel source due to its extreme energy density. It has the ability to produce large quantities of hydrogen and heat when reacted with water ...

  17. Evaluation of heat stress in an aluminum smelter 

    E-Print Network [OSTI]

    Rose, Stacy Rahkell

    1999-01-01

    of heat stress and heat strain was evaluated for the aluminum smelter workers at Alcoa, Rockdale Operations. Personal, environmental, and metabolic factors that contribute to heat-related illnesses were identified. The effectiveness of current...

  18. Aluminum electroplating on steel from a fused bromide electrolyte

    SciTech Connect (OSTI)

    Prabhat K. Tripathy; Laura A. Wurth; Eric J. Dufek; Toni Y. Gutknecht; Natalie J. Gese; Paula Hahn; Steven M. Frank; Guy L. Frederickson; J. Stephen Herring

    2014-08-01

    A quaternary bromide bath (LiBr–KBr–CsBr–AlBr3) was used to electro-coat aluminum on steel substrates. The electrolytewas prepared by the addition of AlBr3 into the eutectic LiBr–KBr–CsBr melt. A smooth, thick, adherent and shiny aluminum coating could be obtained with 80 wt.% AlBr3 in the ternary melt. The SEM photographs of the coated surfaces suggest the formation of thick and dense coatings with good aluminum coverage. Both salt immersion and open circuit potential measurement suggested that the coatings did display a good corrosionresistance behavior. Annealing of the coated surfaces, prior to corrosion tests, suggested the robustness of the metallic aluminum coating in preventing the corrosion of the steel surfaces. Studies also indicated that the quaternary bromide plating bath can potentially provide a better aluminumcoating on both ferrous and non-ferrous metals, including complex surfaces/geometries.

  19. Consolidation of aluminum 6061 powder by equal channel angular extrusion 

    E-Print Network [OSTI]

    Pearson, John Montgomery

    1997-01-01

    Equal channel angular extrusion is a promising approach to obtaining full density in powder metallurgy applications. This method can impose large effective deformations through uniform shear strain. Aluminum alloy 6061 powder is used as a test...

  20. Aluminum Reactions and Problems in Municipal Solid Waste Landfills

    E-Print Network [OSTI]

    problematic for landfill operations by generating undesirable heat, liquid leachate, and gases reactions. Another source of water in a MSW landfill is leachate recirculation, which is not recommended: Solid wastes; Aluminum; Chemicals; Waste disposal; Landfills. Author keywords: Solid waste; Leachate

  1. HIGH ALUMINUM HLW GLASSES FOR HANFORDS WTP

    SciTech Connect (OSTI)

    KRUGER AA; JOSEPH I; BOWMAN BW; GAN H; KOT W; MATLACK KS; PEGG IL

    2009-08-19

    The world's largest radioactive waste vitrification facility is now under construction at the United State Department of Energy's (DOE's) Hanford site. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is designed to treat nearly 53 million gallons of mixed hazardous and radioactive waste now residing in 177 underground storage tanks. This multi-decade processing campaign will be one of the most complex ever undertaken because of the wide chemical and physical variability of the waste compositions generated during the cold war era that are stored at Hanford. The DOE Office of River Protection (ORP) has initiated a program to improve the long-term operating efficiency of the WTP vitrification plants with the objective of reducing the overall cost of tank waste treatment and disposal and shortening the duration of plant operations. Due to the size, complexity and duration of the WTP mission, the lifecycle operating and waste disposal costs are substantial. As a result, gains in High Level Waste (HLW) and Low Activity Waste (LAW) waste loadings, as well as increases in glass production rate, which can reduce mission duration and glass volumes for disposal, can yield substantial overall cost savings. EnergySolutions and its long-term research partner, the Vitreous State Laboratory (VSL) of the Catholic University of America, have been involved in a multi-year ORP program directed at optimizing various aspects of the HLW and LAW vitrification flow sheets. A number of Hanford HLW streams contain high concentrations of aluminum, which is challenging with respect to both waste loading and processing rate. Therefore, a key focus area of the ORP vitrification process optimization program at EnergySolutions and VSL has been development of HLW glass compositions that can accommodate high Al{sub 2}O{sub 3} concentrations while maintaining high processing rates in the Joule Heated Ceramic Melters (JHCMs) used for waste vitrification at the WTP. This paper, reviews the achievements of this program with emphasis on the recent enhancements in Al{sub 2}O{sub 3} loadings in HLW glass and its processing characteristics. Glass formulation development included crucible-scale preparation and characterization of glass samples to assess compliance with all melt processing and product quality requirements, followed by small-scale screening tests to estimate processing rates. These results were used to down-select formulations for subsequent engineering-scale melter testing. Finally, further testing was performed on the DM1200 vitrification system installed at VSL, which is a one-third scale (1.20 m{sup 2}) pilot melter for the WTP HLW melters and which is fitted with a fully prototypical off-gas treatment system. These tests employed glass formulations with high waste loadings and Al{sub 2}O{sub 3} contents of {approx}25 wt%, which represents a near-doubling of the present WTP baseline maximum Al{sub 2}O{sub 3} loading. In addition, these formulations were processed successfully at glass production rates that exceeded the present requirements for WTP HLW vitrification by up to 88%. The higher aluminum loading in the HLW glass has an added benefit in that the aluminum leaching requirements in pretreatment are reduced, thus allowing less sodium addition in pretreatment, which in turn reduces the amount of LAW glass to be produced at the WTP. The impact of the results from this ORP program in reducing the overall cost and schedule for the Hanford waste treatment mission will be discussed.

  2. Process for the deposition of high temperature stress and oxidation resistant coatings on silicon-based substrates

    DOE Patents [OSTI]

    Sarin, V.K.

    1991-07-30

    A process is disclosed for depositing a high temperature stress and oxidation resistant coating on a silicon nitride- or silicon carbide-based substrate body. A gas mixture is passed over the substrate at about 900--1500 C and about 1 torr to about ambient pressure. The gas mixture includes one or more halide vapors with other suitable reactant gases. The partial pressure ratios, flow rates, and process times are sufficient to deposit a continuous, fully dense, adherent coating. The halide and other reactant gases are gradually varied during deposition so that the coating is a graded coating of at least two layers. Each layer is a graded layer changing in composition from the material over which it is deposited to the material of the layer and further to the material, if any, deposited thereon, so that no clearly defined compositional interfaces exist. The gases and their partial pressures are varied according to a predetermined time schedule and the halide and other reactant gases are selected so that the layers include (a) an adherent, continuous intermediate layer about 0.5-20 microns thick of an aluminum nitride or an aluminum oxynitride material, over and chemically bonded to the substrate body, and (b) an adherent, continuous first outer layer about 0.5-900 microns thick including an oxide of aluminum or zirconium over and chemically bonded to the intermediate layer.

  3. Process for the deposition of high temperature stress and oxidation resistant coatings on silicon-based substrates

    DOE Patents [OSTI]

    Sarin, Vinod K. (Lexington, MA)

    1991-01-01

    A process for depositing a high temperature stress and oxidation resistant coating on a silicon nitride- or silicon carbide-based substrate body. A gas mixture is passed over the substrate at about 900.degree.-1500.degree. C. and about 1 torr to about ambient pressure. The gas mixture includes one or more halide vapors with other suitable reactant gases. The partial pressure ratios, flow rates, and process times are sufficient to deposit a continuous, fully dense, adherent coating. The halide and other reactant gases are gradually varied during deposition so that the coating is a graded coating of at least two layers. Each layer is a graded layer changing in composition from the material over which it is deposited to the material of the layer and further to the material, if any, deposited thereon, so that no clearly defined compositional interfaces exist. The gases and their partial pressures are varied according to a predetermined time schedule and the halide and other reactant gases are selected so that the layers include (a) an adherent, continuous intermediate layer about 0.5-20 microns thick of an aluminum nitride or an aluminum oxynitride material, over and chemically bonded to the substrate body, and (b) an adherent, continuous first outer layer about 0.5-900 microns thick including an oxide of aluminum or zirconium over and chemically bonded to the intermediate layer.

  4. Direct Production of Silicones From Sand

    SciTech Connect (OSTI)

    Larry N. Lewis; F.J. Schattenmann: J.P. Lemmon

    2001-09-30

    Silicon, in the form of silica and silicates, is the second most abundant element in the earth's crust. However the synthesis of silicones (scheme 1) and almost all organosilicon chemistry is only accessible through elemental silicon. Silicon dioxide (sand or quartz) is converted to chemical-grade elemental silicon in an energy intensive reduction process, a result of the exceptional thermodynamic stability of silica. Then, the silicon is reacted with methyl chloride to give a mixture of methylchlorosilanes catalyzed by cooper containing a variety of tract metals such as tin, zinc etc. The so-called direct process was first discovered at GE in 1940. The methylchlorosilanes are distilled to purify and separate the major reaction components, the most important of which is dimethyldichlorosilane. Polymerization of dimethyldichlorosilane by controlled hydrolysis results in the formation of silicone polymers. Worldwide, the silicones industry produces about 1.3 billion pounds of the basic silicon polymer, polydimethylsiloxane.

  5. Reactions of aluminum with uranium fluorides and oxyfluorides

    SciTech Connect (OSTI)

    Leitnaker, J.M.; Nichols, R.W.; Lankford, B.S. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States)

    1991-12-31

    Every 30 to 40 million operating hours a destructive reaction is observed in one of the {approximately}4000 large compressors that move UF{sub 6} through the gaseous diffusion plants. Despite its infrequency, such a reaction can be costly in terms of equipment and time. Laboratory experiments reveal that the presence of moderate pressures of UF{sub 6} actually cools heated aluminum, although thermodynamic calculations indicate the potential for a 3000-4000{degrees}C temperature rise. Within a narrow and rather low (<100 torr; 1 torr = 133.322 Pa) pressure range, however, the aluminum is seen to react with sufficient heat release to soften an alumina boat. Three things must occur in order for aluminum to react vigorously with either UF{sub 6} or UO{sub 2}F{sub 2}. 1. An initiating source of heat must be provided. In the compressors, this source can be friction, permitted by disruption of the balance of the large rotating part or by creep of the aluminum during a high-temperature treatment. In the absence of this heat source, compressors have operated for 40 years in UF{sub 6} without significant reaction. 2. The film protecting the aluminum must be breached. Melting (of UF{sub 5} at 620 K or aluminum at 930 K) can cause such a breach in laboratory experiments. In contrast, holding Al samples in UF{sub 6} at 870 K for several hours produces only moderate reaction. Rubbing in the cascade can undoubtedly breach the protective film. 3. Reaction products must not build up and smother the reaction. While uranium products tend to dissolve or dissipate in molten aluminum, AIF{sub 3} shows a remarkable tendency to surround and hence protect even molten aluminum. Hence the initial temperature rise must be rapid and sufficient to move reactants into a temperature region in which products are removed from the reaction site.

  6. Recovery of aluminum and other metal values from fly ash

    DOE Patents [OSTI]

    McDowell, William J. (Oak Ridge, TN); Seeley, Forest G. (Oak Ridge, TN)

    1981-01-01

    The invention described herein relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

  7. A. Bag, W. Zhou, D. Taplin and E. S. Dwarakadasa, Fatigue Behaviour of AZ91D Magnesium Alloy and its Composite Reinforced with SiC, in Magnesium Technology 2000, eds. H. I. Kaplan, J. N. Hryn

    E-Print Network [OSTI]

    Zhou, Wei

    and its Composite Reinforced with SiC, in Magnesium Technology 2000, eds. H. I. Kaplan, J. N. Hryn and B

  8. The effect of sulfur, magnesium, and various rates of potassium on forage production in some sandy soils of East Texas 

    E-Print Network [OSTI]

    Landua, Dennis Paul

    1969-01-01

    the exchangeable potassium and magnesium in a Lakeland fine sand 4 Distribution of potassium, magnesium, and sulfate in a Lakeland fine sand. 48 Effect of fertilizer treatments on total yield of Coastal bermudagrass grown in the field in 1968. . 51 10 Effect...THE EFFECT OF SULFUR, MAGNESIUM, AND VARIOUS RATES OF POTASSIUM ON FORAGE PRODUCTION IN SOME SANDy SOILS OF EAST TEXAS A Thesis by DENNIS PAUL LANDUA Submitted to the Graduate Collccje of Texas AFM Unive, sity in partial fulfillment...

  9. Silicon Tetrafluoride on Io

    E-Print Network [OSTI]

    Laura Schaefer; Bruce Fegley Jr

    2005-06-01

    Silicon tetrafluoride (SiF4) is observed in terrestrial volcanic gases and is predicted to be the major F - bearing species in low temperature volcanic gases on Io (Schaefer and Fegley, 2005b). SiF4 gas is also a potential indicator of silica-rich crust on Io. We used F/S ratios in terrestrial and extraterrestrial basalts, and gas/lava enrichment factors for F and S measured at terrestrial volcanoes to calculate equilibrium SiF4/SO2 ratios in volcanic gases on Io. We conclude that SiF4 can be produced at levels comparable to the observed NaCl/SO2 gas ratio. We also considered potential loss processes for SiF4 in volcanic plumes and in Io's atmosphere including ion-molecule reactions, electron chemistry, photochemistry, reactions with the major atmospheric constituents, and condensation. Photochemical destruction (tchem ~ 266 days) and/or condensation as Na2SiF6 (s) appear to be the major sinks for SiF4. We recommend searching for SiF4 with infrared spectroscopy using its 9.7 micron band as done on Earth.

  10. Effect Of Neodymium Substitution In Structural Characteristics Of Magnesium Ferrite

    SciTech Connect (OSTI)

    Thankachan, Smitha; Binu, P. J.; Xavier, Sheena; Mohammed, E. M. [Department of Physics, Maharaja's College, Ernakulam (India)

    2011-10-20

    The effect of Nd{sup 3+} substitution on the structural properties of Magnesium ferrite was studied in the series MgNd{sub x}Fe{sub 2-x}O{sub 4}, where x = 0 to 0.3 in steps of 0.05. The series was prepared by sol-gel technique which is one of the novel technique to prepare nanosized samples. Structural characterization was done using X-ray diffractometer and Fourier Transform Infrared Spectrometer. XRD analysis reveals the prepared samples are single phasic till x = 0.2. From x0 = .25, a secondary phase of iron neodymium oxide appears along with the spinel phase. Particle size calculation shows the prepared samples are in the 9nm to 11 nm regime. Lattice parameter was found to increase with concentration of Nd. XRD and FTIR analysis confirmed spinel structure of the prepared samples. XRF result shows the expected composition of prepared samples. The frequency dependence of the dielectric constant in the range 100 Hz--120MHz was also studied

  11. Ab Initio Thermodynamic Model for Magnesium Carbonates and Hydrates

    SciTech Connect (OSTI)

    Chaka, Anne M.; Felmy, Andrew R.

    2014-03-28

    An ab initio thermodynamic framework for predicting properties of hydrated magnesium carbonate minerals has been developed using density-functional theory linked to macroscopic thermodynamics through the experimental chemical potentials for MgO, water, and CO2. Including semiempirical dispersion via the Grimme method and small corrections to the generalized gradient approximation of Perdew, Burke, and Ernzerhof for the heat of formation yields a model with quantitative agreement for the benchmark minerals brucite, magnesite, nesquehonite, and hydromagnesite. The model shows how small differences in experimental conditions determine whether nesquehonite, hydromagnesite, or magnesite is the result of laboratory synthesis from carbonation of brucite, and what transformations are expected to occur on geological time scales. Because of the reliance on parameter-free first principles methods, the model is reliably extensible to experimental conditions not readily accessible to experiment and to any mineral composition for which the structure is known or can be hypothesized, including structures containing defects, substitutions, or transitional structures during solid state transformations induced by temperature changes or processes such as water, CO2, or O2 diffusion. Demonstrated applications of the ab initio thermodynamic framework include an independent means to evaluate differences in thermodynamic data for lansfordite, predicting the properties of Mg analogs of Ca-based hydrated carbonates monohydrocalcite and ikaite which have not been observed in nature, and an estimation of the thermodynamics of barringtonite from the stoichiometry and a single experimental observation.

  12. Analysis of candidate silicon carbide recuperator materials exposed to industrial furnace environments

    SciTech Connect (OSTI)

    Federer, J.I.; Tiegs, T.N.; Kotchick, D.M.; Petrak, D.

    1985-07-01

    Several SiC ceramics were exposed to the combustion environment in six industrial furnaces to determine their corrosion resistance. The matrials were sintered-..cap alpha.. (Hexoloy SA), Sintride, recrystallized (NC-400), CVD SiC coated NC-400, siliconized (NC-430), reaction sintered (SC-X and KT), and Si/sub 3/N/sub 4/-bounded (C/75 and CN-178). Tubes of these materials were exposed in two aluminum remelt furnaces, a forge furnace, a steel reheat furnace, and two steel soaking pits at temperatures of 925 to 1250/sup 0/C for periods of 530 to 5545 h. Significant corrosion occurred in specimens exposed to aluminum remelt furnaces and one of the steel soaking pits, whereas corrosion in the other furnaces was substantially less or negligible. The average C-ring fracture strengths of Hexoloy SA and NC-430, the only materials so tested, were substantially affected by the exposures. The lowest strength in Hexoloy SA occurred in specimens exposed in an aluminum remelt furnace, while the lowest strength in NC-430 occurred in specimens exposed in a steel soaking pit. These results show that SiC ceramics are susceptible to both corrosion and strength degradation when exposed to certain furnace environments.

  13. Three dimensional amorphous silicon/microcrystalline silicon solar cells

    DOE Patents [OSTI]

    Kaschmitter, J.L.

    1996-07-23

    Three dimensional deep contact amorphous silicon/microcrystalline silicon (a-Si/{micro}c-Si) solar cells are disclosed which use deep (high aspect ratio) p and n contacts to create high electric fields within the carrier collection volume material of the cell. The deep contacts are fabricated using repetitive pulsed laser doping so as to create the high aspect p and n contacts. By the provision of the deep contacts which penetrate the electric field deep into the material where the high strength of the field can collect many of the carriers, thereby resulting in a high efficiency solar cell. 4 figs.

  14. Three dimensional amorphous silicon/microcrystalline silicon solar cells

    DOE Patents [OSTI]

    Kaschmitter, James L. (Pleasanton, CA)

    1996-01-01

    Three dimensional deep contact amorphous silicon/microcrystalline silicon (a-Si/.mu.c-Si) solar cells which use deep (high aspect ratio) p and n contacts to create high electric fields within the carrier collection volume material of the cell. The deep contacts are fabricated using repetitive pulsed laser doping so as to create the high aspect p and n contacts. By the provision of the deep contacts which penetrate the electric field deep into the material where the high strength of the field can collect many of the carriers, thereby resulting in a high efficiency solar cell.

  15. Hybrid Silicon Photonic Integrated Circuit Technology

    E-Print Network [OSTI]

    2013-01-01

    and J. E. Bowers, “Hybrid silicon evanescent devices,”and J. E. Bowers, “A hybrid AlGaInAs-silicon evanescentColdren, and J. E. Bowers, “Hybrid III/V sili- con photonic

  16. Hybrid Silicon Photonics for Optical Interconnects

    E-Print Network [OSTI]

    2011-01-01

    Promising Technology for the hybrid silicon laser in 2007.Electrically pumped hybrid AlGaInAs-silicon evanescentA. Yariv, “Electrically pumped hybrid evanescent Si/InGaAsP

  17. Design of a silicon waver breaker

    E-Print Network [OSTI]

    Mukaddam, Kabir James, 1983-

    2005-01-01

    Usually multiple MEMS or IC devices are fabricated on a single silicon wafer. Manually separating the components from each other involves scribing and fracturing the silicon. This thesis presents a design for a tool to aid ...

  18. Nucleation and solidification of silicon for photovoltaics

    E-Print Network [OSTI]

    Appapillai, Anjuli T. (Anjuli Tara)

    2010-01-01

    The majority of solar cells produced today are made with crystalline silicon wafers, which are typically manufactured by growing a large piece of silicon and then sawing it into ~200 pm wafers, a process which converts ...

  19. Hydrogen storage in sodium aluminum hydride.

    SciTech Connect (OSTI)

    Ozolins, Vidvuds; Herberg, J.L.; McCarty, Kevin F.; Maxwell, Robert S.; Stumpf, Roland Rudolph; Majzoub, Eric H.

    2005-11-01

    Sodium aluminum hydride, NaAlH{sub 4}, has been studied for use as a hydrogen storage material. The effect of Ti, as a few mol. % dopant in the system to increase kinetics of hydrogen sorption, is studied with respect to changes in lattice structure of the crystal. No Ti substitution is found in the crystal lattice. Electronic structure calculations indicate that the NaAlH{sub 4} and Na{sub 3}AlH{sub 6} structures are complex-ionic hydrides with Na{sup +} cations and AlH{sub 4}{sup -} and AlH{sub 6}{sup 3-} anions, respectively. Compound formation studies indicate the primary Ti-compound formed when doping the material at 33 at. % is TiAl{sub 3} , and likely Ti-Al compounds at lower doping rates. A general study of sorption kinetics of NaAlH{sub 4}, when doped with a variety of Ti-halide compounds, indicates a uniform response with the kinetics similar for all dopants. NMR multiple quantum studies of solution-doped samples indicate solvent interaction with the doped alanate. Raman spectroscopy was used to study the lattice dynamics of NaAlH{sub 4}, and illustrated the molecular ionic nature of the lattice as a separation of vibrational modes between the AlH{sub 4}{sup -} anion-modes and lattice-modes. In-situ Raman measurements indicate a stable AlH{sub 4}{sup -} anion that is stable at the melting temperature of NaAlH{sub 4}, indicating that Ti-dopants must affect the Al-H bond strength.

  20. System and method for liquid silicon containment

    SciTech Connect (OSTI)

    Cliber, James A; Clark, Roger F; Stoddard, Nathan G; Von Dollen, Paul

    2014-06-03

    This invention relates to a system and a method for liquid silicon containment, such as during the casting of high purity silicon used in solar cells or solar modules. The containment apparatus includes a shielding ember adapted to prevent breaching molten silicon from contacting structural elements or cooling elements of a casting device, and a volume adapted to hold a quantity of breaching molten silicon with the volume formed by a bottom and one or more sides.

  1. Silicon crystal growing by oscillating crucible technique

    DOE Patents [OSTI]

    Schwuttke, G.H.; Kim, K.M.; Smetana, P.

    1983-08-03

    A process for growing silicon crystals from a molten melt comprising oscillating the container during crystal growth is disclosed.

  2. Copper doped polycrystalline silicon solar cell

    DOE Patents [OSTI]

    Lovelace, Alan M. Administrator of the National Aeronautics and Space (La Canada, CA); Koliwad, Krishna M. (La Canada, CA); Daud, Taher (La Crescenta, CA)

    1981-01-01

    Photovoltaic cells having improved performance are fabricated from polycrystalline silicon containing copper segregated at the grain boundaries.

  3. System and method for liquid silicon containment

    DOE Patents [OSTI]

    Cliber, James A; Clark, Roger F; Stoddard, Nathan G; Von Dollen, Paul

    2013-05-28

    This invention relates to a system and a method for liquid silicon containment, such as during the casting of high purity silicon used in solar cells or solar modules. The containment apparatus includes a shielding member adapted to prevent breaching molten silicon from contacting structural elements or cooling elements of a casting device, and a volume adapted to hold a quantity of breaching molten silicon with the volume formed by a bottom and one or more sides.

  4. Birefringence Measurements on Crystalline Silicon

    E-Print Network [OSTI]

    Krüger, Christoph; Khalaidovski, Alexander; Steinlechner, Jessica; Nawrodt, Ronny; Schnabel, Roman; Lück, Harald

    2015-01-01

    Crystalline silicon has been proposed as a new test mass material in third generation gravitational wave detectors such as the Einstein Telescope (ET). Birefringence can reduce the interferometric contrast and can produce dynamical disturbances in interferometers. In this work we use the method of polarisation-dependent resonance frequency analysis of Fabry-Perot-cavities containing silicon as a birefringent medium. Our measurements show a birefringence of silicon along the (111) axis of the order of $\\Delta\\, n \\approx 10^{-7}$ at a laser wavelength of 1550nm and room temperature. A model is presented that explains the results of different settings of our measurements as a superposition of elastic strains caused by external stresses in the sample and plastic strains possibly generated during the production process. An application of our theory on the proposed ET test mass geometry suggests no critical effect on birefringence due to elastic strains.

  5. Silicon Photonics: The Inside Story

    E-Print Network [OSTI]

    Jalali, Bahram

    2008-01-01

    The electronic chip industry embodies the height of technological sophistication and economics of scale. Fabricating inexpensive photonic components by leveraging this mighty manufacturing infrastructure has fueled intense interest in silicon photonics. If it can be done economically and in an energy efficient manner, empowering silicon with optical functionality will bring optical communications to the realm of computers where limitations of metallic interconnects are threatening the industry's future. The field is making stunning progress and stands to have a bright future, as long as the community recognizes the real challenges, and maintains an open mind with respect to its applications. This talk will review recent 'game changing' developments and discuss promising applications beyond data communication. It will conclude with recent observation of extreme-value statistical behavior in silicon photonics, a powerful example of how scientific discoveries can unexpectedly emerge in the course of technology d...

  6. Production of anhydrous aluminum chloride composition and process for electrolysis thereof

    DOE Patents [OSTI]

    Vandegrift, George F. (Bolingbrook, Naperville, IL); Krumpelt, Michael (Naperville, IL); Horwitz, E. Philip (Hinsdale, IL)

    1983-01-01

    A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  7. A quantitative determination of the conditions for hot cracking during welding for aluminum alloys 

    E-Print Network [OSTI]

    Steenbergen, James Everett

    1969-01-01

    REFERENCES ~ ~ ~ . ~ 12 23 23 46 55 56 VITA 58 vi LIST OP TABLES Table Page Properties of Aluminum Alloys Test Results for 6061-T6 Aluminum Test Results for 7075-T6 Aluminum Strain Data for 6061-T6 Aluminum Strain Data for 7075-T6 Aluminum 27...' These alloys were selected because of their usage in structural design applications and availability. Test specimens were machined from sheet stock in preparation for generation of the test data. The generation of the experimental test data for the aluminum...

  8. Tandem junction amorphous silicon solar cells

    DOE Patents [OSTI]

    Hanak, Joseph J. (Lawrenceville, NJ)

    1981-01-01

    An amorphous silicon solar cell has an active body with two or a series of layers of hydrogenated amorphous silicon arranged in a tandem stacked configuration with one optical path and electrically interconnected by a tunnel junction. The layers of hydrogenated amorphous silicon arranged in tandem configuration can have the same bandgap or differing bandgaps.

  9. SILICON--1999 681 By Thomas S. Jones

    E-Print Network [OSTI]

    SILICON--1999 681 SILICON By Thomas S. Jones Domestic survey data and tables were prepared by Lisa in the foreign trade statistics. For 1999, an overall domestic silicon production of 423,000 metric tons (t led to ongoing legal actions. In the first part of 1999, of three domestic producers involved in civil

  10. Process of preparing tritiated porous silicon

    DOE Patents [OSTI]

    Tam, S.W.

    1997-02-18

    A process of preparing tritiated porous silicon is described in which porous silicon is equilibrated with a gaseous vapor containing HT/T{sub 2} gas in a diluent for a time sufficient for tritium in the gas phase to replace hydrogen present in the pore surfaces of the porous silicon. 1 fig.

  11. Structural studies of magnesium nitride fluorides by powder neutron diffraction

    SciTech Connect (OSTI)

    Brogan, Michael A.; Hughes, Robert W.; Smith, Ronald I.; Gregory, Duncan H.

    2012-01-15

    Samples of ternary nitride fluorides, Mg{sub 3}NF{sub 3} and Mg{sub 2}NF have been prepared by solid state reaction of Mg{sub 3}N{sub 2} and MgF{sub 2} at 1323-1423 K and investigated by powder X-ray and powder neutron diffraction techniques. Mg{sub 3}NF{sub 3} is cubic (space group: Pm3m) and has a structure related to rock-salt MgO, but with one cation site vacant. Mg{sub 2}NF is tetragonal (space group: I4{sub 1}/amd) and has an anti-LiFeO{sub 2} related structure. Both compounds are essentially ionic and form structures in which nitride and fluoride anions are crystallographically ordered. The nitride fluorides show temperature independent paramagnetic behaviour between 5 and 300 K. - Graphical abstract: Definitive structures of the ternary magnesium nitride fluorides Mg{sub 3}NF{sub 3} and the lower temperature polymorph of Mg{sub 2}NF have been determined from powder neutron diffraction data. The nitride halides are essentially ionic and exhibit weak temperature independent paramagnetic behaviour. Highlights: Black-Right-Pointing-Pointer Definitive structures of Mg{sub 3}NF{sub 3} and Mg{sub 2}NF were determined by neutron diffraction. Black-Right-Pointing-Pointer Nitride and fluoride anions are crystallographically ordered in both structures. Black-Right-Pointing-Pointer Both compounds exhibit weak, temperature independent paramagnetic behaviour. Black-Right-Pointing-Pointer The compounds are essentially ionic with ionicity increasing with F{sup -} content.

  12. REAL TIME ULTRASONIC ALUMINUM SPOT WELD MONITORING SYSTEM

    SciTech Connect (OSTI)

    Regalado, W. Perez; Chertov, A. M.; Maev, R. Gr. [Institute for Diagnostic Imaging Research, Physics Department, University of Windsor, 292 Essex Hall, 401 Sunset Ave. N9B 3P4 Windsor, Ontario (Canada)

    2010-02-22

    Aluminum alloys pose several properties that make them one of the most popular engineering materials: they have excellent corrosion resistance, and high weight-to-strength ratio. Resistance spot welding of aluminum alloys is widely used today but oxide film and aluminum thermal and electrical properties make spot welding a difficult task. Electrode degradation due to pitting, alloying and mushrooming decreases the weld quality and adjustment of parameters like current and force is required. To realize these adjustments and ensure weld quality, a tool to measure weld quality in real time is required. In this paper, a real time ultrasonic non-destructive evaluation system for aluminum spot welds is presented. The system is able to monitor nugget growth while the spot weld is being made. This is achieved by interpreting the echoes of an ultrasound transducer located in one of the welding electrodes. The transducer receives and transmits an ultrasound signal at different times during the welding cycle. Valuable information of the weld quality is embedded in this signal. The system is able to determine the weld nugget diameter by measuring the delays of the ultrasound signals received during the complete welding cycle. The article presents the system performance on aluminum alloy AA6022.

  13. Hermetic aluminum radio frequency interconnection and method for making

    DOE Patents [OSTI]

    Kilgo, Riley D. (Albuquerque, NM); Kovacic, Larry (Albuquerque, NM); Brow, Richard K. (Rolla, MO)

    2000-01-01

    The present invention provides a light-weight, hermetic coaxial radio-frequency (RF) interconnection having an electrically conductive outer housing made of aluminum or an aluminum alloy, a central electrical conductor made of ferrous or non-ferrous material, and a cylinder of dielectric material comprising a low-melting-temperature, high-thermal-expansion aluminophosphate glass composition for hermetically sealing between the aluminum-alloy outer housing and the ferrous or non-ferrous center conductor. The entire RF interconnection assembly is made permanently hermetic by thermally fusing the center conductor, glass, and housing concurrently by bringing the glass to the melt point by way of exposure to an atmospheric temperature sufficient to melt the glass, less than 540.degree. C., but that does not melt the center conductor or the outer aluminum or aluminum alloy housing. The composition of the glass used is controlled to provide a suitable low dielectric constant so that an appropriate electrical characteristic impedance, for example 50 ohms, can be achieved for an electrical interconnection that performs well at high radio frequencies and also provides an interconnection maintaining a relatively small physical size.

  14. SILANE SAFETY IN AMORPHOUS SILICON AND SILICON NITRIDE OPERATIONS

    E-Print Network [OSTI]

    industries in Europe, the United States, and Japan. As PV manufacturing is scaled-up to meet a growing demand) and amorphous silicon (a-Si). In this paper, we review established methods for using this gas safely; they include risk-prevention strategies, passive and active protection systems, outdoor storage, and adequate

  15. Identity of Passive Film Formed on Aluminum in Li-ion Battery Electrolytes with LiPF6

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, T.M.

    2008-01-01

    Influence Formation of AlF 3 Passive Film on Aluminum in Li-Identity of Passive Film Formed on Aluminum in Li-ionEngineering Abstract The passive film that forms on aluminum

  16. COMPILATION OF LABORATORY SCALE ALUMINUM WASH AND LEACH REPORT RESULTS

    SciTech Connect (OSTI)

    HARRINGTON SJ

    2011-01-06

    This report compiles and analyzes all known wash and caustic leach laboratory studies. As further data is produced, this report will be updated. Included are aluminum mineralogical analysis results as well as a summation of the wash and leach procedures and results. Of the 177 underground storage tanks at Hanford, information was only available for five individual double-shell tanks, forty-one individual single-shell tanks (e.g. thirty-nine 100 series and two 200 series tanks), and twelve grouped tank wastes. Seven of the individual single-shell tank studies provided data for the percent of aluminum removal as a function of time for various caustic concentrations and leaching temperatures. It was determined that in most cases increased leaching temperature, caustic concentration, and leaching time leads to increased dissolution of leachable aluminum solids.

  17. Reactive self-heating model of aluminum spherical nanoparticles

    E-Print Network [OSTI]

    Karen S. Martirosyan; Maxim Zyskin

    2012-12-17

    Aluminum-oxygen reaction is important in many highly energetic, high pressure generating systems. Recent experiments with nanostructured thermites suggest that oxidation of aluminum nanoparticles occurs in a few microseconds. Such rapid reaction cannot be explained by a conventional diffusion-based mechanism. We present a rapid oxidation model of a spherical aluminum nanoparticle, using Cabrera-Mott moving boundary mechanism, and taking self-heating into account. In our model, electric potential solves the nonlinear Poisson equation. In contrast with the Coulomb potential, a "double-layer" type solution for the potential and self-heating leads to enhanced oxidation rates. At maximal reaction temperature of 2000 C, our model predicts overall oxidation time scale in microseconds range, in agreement with experimental evidence.

  18. Reactive self-heating model of aluminum spherical nanoparticles

    E-Print Network [OSTI]

    Martirosyan, Karen S

    2012-01-01

    Aluminum-oxygen reaction is important in many highly energetic, high pressure generating systems. Recent experiments with nanostructured thermites suggest that oxidation of aluminum nanoparticles occurs in a few microseconds. Such rapid reaction cannot be explained by a conventional diffusion-based mechanism. We present a rapid oxidation model of a spherical aluminum nanoparticle, using Cabrera-Mott moving boundary mechanism, and taking self-heating into account. In our model, electric potential solves the nonlinear Poisson equation. In contrast with the Coulomb potential, a "double-layer" type solution for the potential and self-heating leads to enhanced oxidation rates. At maximal reaction temperature of 2000 C, our model predicts overall oxidation time scale in microseconds range, in agreement with experimental evidence.

  19. Carbonaceous cathode with enhanced wettability for aluminum production

    DOE Patents [OSTI]

    Keller, Rudolf; Gatty, David G.; Barca, Brian J.

    2003-09-09

    A method of preparing carbonaceous blocks or bodies for use in a cathode in an electrolytic cell for producing aluminum wherein the cell contains an electrolyte and has molten aluminum contacting the cathode, the cathode having improved wettability with molten aluminum. The method comprises the steps of providing a carbonaceous block and a boron oxide containing melt. The carbonaceous block is immersed in the melt and pressure is applied to the melt to impregnate the melt into pores in the block. Thereafter, the carbonaceous block is withdrawn from the melt, the block having boron oxide containing melt intruded into pores therein, the boron oxide capable of reacting with a source of titanium or zirconium or like metal to form titanium or zirconium diboride during heatup or operation of said cell.

  20. Method for processing silicon solar cells

    DOE Patents [OSTI]

    Tsuo, Y. Simon (Golden, CO); Landry, Marc D. (Lafayette, CO); Pitts, John R. (Lakewood, CO)

    1997-01-01

    The instant invention teaches a novel method for fabricating silicon solar cells utilizing concentrated solar radiation. The solar radiation is concentrated by use of a solar furnace which is used to form a front surface junction and back-surface field in one processing step. The present invention also provides a method of making multicrystallline silicon from amorphous silicon. The invention also teaches a method of texturing the surface of a wafer by forming a porous silicon layer on the surface of a silicon substrate and a method of gettering impurities. Also contemplated by the invention are methods of surface passivation, forming novel solar cell structures, and hydrogen passivation.

  1. Method for processing silicon solar cells

    DOE Patents [OSTI]

    Tsuo, Y.S.; Landry, M.D.; Pitts, J.R.

    1997-05-06

    The instant invention teaches a novel method for fabricating silicon solar cells utilizing concentrated solar radiation. The solar radiation is concentrated by use of a solar furnace which is used to form a front surface junction and back-surface field in one processing step. The present invention also provides a method of making multicrystalline silicon from amorphous silicon. The invention also teaches a method of texturing the surface of a wafer by forming a porous silicon layer on the surface of a silicon substrate and a method of gettering impurities. Also contemplated by the invention are methods of surface passivation, forming novel solar cell structures, and hydrogen passivation. 2 figs.

  2. ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. T. van Duin, and William A. Goddard III*

    E-Print Network [OSTI]

    van Duin, Adri

    ReaxFFMgH Reactive Force Field for Magnesium Hydride Systems Sam Cheung, Wei-Qiao Deng, Adri C. T and Chemical Engineering, California Institute of Technology, Pasadena, California 91125 ReceiVed: September 3FFMgH) for magnesium and magnesium hydride systems. The parameters for this force field were derived from fitting

  3. Method for fabricating silicon cells

    DOE Patents [OSTI]

    Ruby, Douglas S. (Albuquerque, NM); Basore, Paul A. (Albuquerque, NM); Schubert, W. Kent (Albuquerque, NM)

    1998-08-11

    A process for making high-efficiency solar cells. This is accomplished by forming a diffusion junction and a passivating oxide layer in a single high-temperature process step. The invention includes the class of solar cells made using this process, including high-efficiency solar cells made using Czochralski-grown silicon.

  4. Method for fabricating silicon cells

    DOE Patents [OSTI]

    Ruby, D.S.; Basore, P.A.; Schubert, W.K.

    1998-08-11

    A process is described for making high-efficiency solar cells. This is accomplished by forming a diffusion junction and a passivating oxide layer in a single high-temperature process step. The invention includes the class of solar cells made using this process, including high-efficiency solar cells made using Czochralski-grown silicon. 9 figs.

  5. Narrow band gap amorphous silicon semiconductors

    DOE Patents [OSTI]

    Madan, A.; Mahan, A.H.

    1985-01-10

    Disclosed is a narrow band gap amorphous silicon semiconductor comprising an alloy of amorphous silicon and a band gap narrowing element selected from the group consisting of Sn, Ge, and Pb, with an electron donor dopant selected from the group consisting of P, As, Sb, Bi and N. The process for producing the narrow band gap amorphous silicon semiconductor comprises the steps of forming an alloy comprising amorphous silicon and at least one of the aforesaid band gap narrowing elements in amount sufficient to narrow the band gap of the silicon semiconductor alloy below that of amorphous silicon, and also utilizing sufficient amounts of the aforesaid electron donor dopant to maintain the amorphous silicon alloy as an n-type semiconductor.

  6. Epitaxial growth of silicon for layer transfer

    DOE Patents [OSTI]

    Teplin, Charles; Branz, Howard M

    2015-03-24

    Methods of preparing a thin crystalline silicon film for transfer and devices utilizing a transferred crystalline silicon film are disclosed. The methods include preparing a silicon growth substrate which has an interface defining substance associated with an exterior surface. The methods further include depositing an epitaxial layer of silicon on the silicon growth substrate at the surface and separating the epitaxial layer from the substrate substantially along the plane or other surface defined by the interface defining substance. The epitaxial layer may be utilized as a thin film of crystalline silicon in any type of semiconductor device which requires a crystalline silicon layer. In use, the epitaxial transfer layer may be associated with a secondary substrate.

  7. Influence of argon and oxygen on charge-state-resolved ion energy distributions of filtered aluminum arcs

    E-Print Network [OSTI]

    Rosen, Johanna; Anders, Andre; Mraz, Stanislav; Atiser, Adil; Schneider, Jochen M.

    2006-01-01

    in filtered aluminum vacuum arc plasmas were measured andI. INTRODUCTION Vacuum arc plasma is well known to be highlymeasured for vacuum arc plasmas. Aluminum plasma, for

  8. Energy Conservation Design Features of the ARCO Metals Logan County Aluminum Process Complex 

    E-Print Network [OSTI]

    Speer, J. A.

    1983-01-01

    ARCO Metals Company (Formerly Anaconda Aluminum Company) is proceeding as scheduled with the construction of a $400 Million aluminum processing complex in Logan County, Kentucky. When the initial construction phase is ...

  9. The Development of ALADIN,an Expert System for Aluminum Alloy Design

    E-Print Network [OSTI]

    Fox, Mark S.

    -Mel- lon Unit,., Pittsburgh, PA, USA 1. Introduction ALADIN (ALuminum Alloy Design INventor) is an expert publications in The- oretical Physics. Dr. Hulthage is working on The Aluminum Alloy Design Inventor (Aladin

  10. Field assessment of an aluminum intensive passenger car

    SciTech Connect (OSTI)

    Cuenca, R.M.

    1994-12-31

    Ford Motor Co. has made a small batch of ``aluminum intensive vehicles`` (AIV), consisting of mid-size cars (Taurus/Sable) with all-aluminum bodies. The first twenty vehicles were made for internal evaluation at Ford, but the second batch of twenty has been placed on the hands of selected independent users, primarily automotive suppliers, for long term field assessment. The mass reduction achieved in the body of an AIV is shown, and compared with an equivalent standard steel body. Argonne obtained one of these vehicles last October; this is an assessment of the fuel consumption and other operational characteristics of this type of car to date.

  11. Electrolytic Cell For Production Of Aluminum Employing Planar Anodes.

    DOE Patents [OSTI]

    Barnett, Robert J. (Goldendale, WA); Mezner, Michael B. (Sandy, OR); Bradford, Donald R (Underwood, WA)

    2004-10-05

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte, the method comprising providing a molten salt electrolyte having alumina dissolved therein in an electrolytic cell. A plurality of anodes and cathodes having planar surfaces are disposed in a generally vertical orientation in the electrolyte, the anodes and cathodes arranged in alternating or interleaving relationship to provide anode planar surfaces disposed opposite cathode planar surfaces, the anode comprised of carbon. Electric current is passed through anodes and through the electrolyte to the cathodes depositing aluminum at the cathodes and forming carbon containing gas at the anodes.

  12. Aluminum Surface Texturing by Means of Laser Interference Metallurgy

    SciTech Connect (OSTI)

    Chen, Jian; Sabau, Adrian S; Jones, Jonaaron F.; Hackett, Alexandra C.; Daniel, Claus; Warren, Charles David

    2015-01-01

    The increasing use of lightweight materials, such as aluminum alloys, in auto body structures requires more effective surface cleaning and texturing techniques to improve the quality of the structural components. The present work introduces a novel surface treatment method using laser interferometry produced by two beams of a pulsed Nd:YAG laser operating at 10Hz of frequency to clean aluminum surfaces, and meanwhile creating periodic and rough surface structures. The influences of beam size, laser fluence, wavelength, and pulse number per spot are investigated. High resolution optical profiler images reveal the change of the peak-to-valley height on the laser-treated surface.

  13. Optimization of transparent and reflecting electrodes for amorphous silicon solar cells. Annual technical report, April 1, 1995--March 31, 1996

    SciTech Connect (OSTI)

    Gordon, R.G.; Sato, H.; Liang, H.; Liu, X.; Thornton, J. [Harvard Univ., Cambridge, MA (United States)

    1996-08-01

    The general objective is to develop methods to deposit materials which can be used to make more efficient solar cells. The work is organized into three general tasks: Task 1. Develop improved methods for depositing and using transparent conductors of fluorine-doped zinc oxide in amorphous silicon solar cells Task 2. Deposit and evaluate titanium oxide as a reflection-enhancing diffusion barrier between amorphous silicon and an aluminum or silver back-reflector. Task 3. Deposit and evaluate electrically conductive titanium oxide as a transparent conducting layer on which more efficient and more stable superstrate cells can be deposited. About one-third of the current project resources are allocated to each of these three objectives.

  14. Passivation of Aluminum in Lithium-ion Battery Electrolytes with LiBOB

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, Thomas M.

    2008-01-01

    of Aluminum in Lithium-ion Battery Electrolytes with LiBOBin commercially available lithium-ion battery electrolytes,

  15. Mercury-free dissolution of aluminum-clad fuel in nitric acid

    DOE Patents [OSTI]

    Christian, Jerry D. (Idaho Falls, ID); Anderson, Philip A. (Pocatello, ID)

    1994-01-01

    A mercury-free dissolution process for aluminum involves placing the aluminum in a dissolver vessel in contact with nitric acid-fluoboric acid mixture at an elevated temperature. By maintaining a continuous flow of the acid mixture through the dissolver vessel, an effluent containing aluminum nitrate, nitric acid, fluoboric acid and other dissolved components are removed.

  16. Mercury-free dissolution of aluminum-clad fuel in nitric acid

    DOE Patents [OSTI]

    Christian, J.D.; Anderson, P.A.

    1994-11-15

    A mercury-free dissolution process for aluminum involves placing the aluminum in a dissolver vessel in contact with nitric acid-fluoboric acid mixture at an elevated temperature. By maintaining a continuous flow of the acid mixture through the dissolver vessel, an effluent containing aluminum nitrate, nitric acid, fluoboric acid and other dissolved components are removed. 5 figs.

  17. BWeb Copy of the Aluminum Chapter from the 1st

    E-Print Network [OSTI]

    Ford, Andrew

    to a cheap source of electric power, typically a large scale hydro-electric facility. With 2,204 pounds industry. It then exploits the power of arrays to develop a model which distinguishes between smelters Falls Power Company. The partnership between large scale aluminum production and power generation

  18. Effects of fluctuant magnesium concentration on phenotype of the primary chondrocytes

    E-Print Network [OSTI]

    Zheng, Yufeng

    , Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China 2 DepartmentM of MgCl2 solution set as the control group. Concentra- tions of Mg ions and pH values of the culture generally degrade to magnesium hydroxide, hydrogen gas, sulfate, and phosphate in aqueous environments via

  19. Hot cracking in tungsten inert gas welding of magnesium alloy AZ91D

    E-Print Network [OSTI]

    Zhou, Wei

    Hot cracking in tungsten inert gas welding of magnesium alloy AZ91D W. Zhou*, T. Z. Long and C. K of the plates were produced using tungsten inert gas (TIG) welding method. The TIG arc was also used to deposit welding beads on some of the thin plates. No cracking was found in the butt joints. However, hot cracking

  20. Enthalpies of formation of magnesium compounds from first-principles calculations

    E-Print Network [OSTI]

    Chen, Long-Qing

    Enthalpies of formation of magnesium compounds from first-principles calculations Hui Zhang, miscellaneous B. Thermodynamic and thermochemical properties E. Ab initio calculations a b s t r a c). The calculated lattice parameters and enthalpies of formation of binary compounds in these systems are compared

  1. Evaluation of Heat Shields from RTS Wright Industries Magnesium and Uranium Beds

    SciTech Connect (OSTI)

    Korinko, P.S.

    2002-10-29

    Heat shields from a factory test of the furnaces that will be used to heat the magnesium and uranium beds for the tritium extraction facility (TEF) were examined to determine the cause of discoloration. The samples were examined using visual, optical microscopy, electron microscopy, x-ray spectroscopy, and Auger electron spectroscopy.

  2. The CDF silicon vertex trigger

    SciTech Connect (OSTI)

    B. Ashmanskas; A. Barchiesi; A. Bardi

    2003-06-23

    The CDF experiment's Silicon Vertex Trigger is a system of 150 custom 9U VME boards that reconstructs axial tracks in the CDF silicon strip detector in a 15 {mu}sec pipeline. SVT's 35 {mu}m impact parameter resolution enables CDF's Level 2 trigger to distinguish primary and secondary particles, and hence to collect large samples of hadronic bottom and charm decays. We review some of SVT's key design features. Speed is achieved with custom VLSI pattern recognition, linearized track fitting, pipelining, and parallel processing. Testing and reliability are aided by built-in logic state analysis and test-data sourcing at each board's input and output, a common inter-board data link, and a universal ''Merger'' board for data fan-in/fan-out. Speed and adaptability are enhanced by use of modern FPGAs.

  3. A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction

    E-Print Network [OSTI]

    Mailoa, Jonathan P.

    With the advent of efficient high-bandgap metal-halide perovskite photovoltaics, an opportunity exists to make perovskite/silicon tandem solar cells. We fabricate a monolithic tandem by developing a silicon-based interband ...

  4. Enhanced room temperature oxidation in silicon and porous silicon under 10 keV x-ray irradiation

    E-Print Network [OSTI]

    Weiss, Sharon

    Enhanced room temperature oxidation in silicon and porous silicon under 10 keV x-ray irradiation been suggested that gamma irradiation accelerates oxidation of porous silicon.5 Irradiation silicon samples that occurs over three decades of 10 keV x-ray irradiation. II. SAMPLE PREPARATION Silicon

  5. AEC Lowman Station - coal switching and magnesium-enhanced lime scrubbing to lower operating costs

    SciTech Connect (OSTI)

    Inkenhaus, W.; Babu, M.; Smith, K. [Dravo Lime Co., Pittsburgh, PA (United States); Loper, L. [Alabama Electric Coopreative, Leroy, AL (United States)

    1997-12-31

    AEC`s Lowman Station is located in Leroy, Alabama. There are three coal-fired boilers at this station. Unit 1 is capable of generating 85 MW without a flue gas desulfurization, FGD, system. Units 2 and 3, with a total of 516 MW output capacity, are equipped with FGD systems. The FGD plant was designed for wet limestone FGD with natural oxidation. Lowman Station burned low sulfur, 1.3 to 1.8% sulfur, coal. In January of 1996 AEC switched Units 2 and 3 from limestone to magnesium-enhanced lime FGD operation. It was determined that the plant could take advantage of the higher SO{sub 2} removal efficiency of the magnesium-enhanced lime system. Major benefits resulting from this conversion were AEC`s ability to switch to a lower cost high sulfur coal while meeting the stringent SO{sub 2} emission requirements. Power cost savings resulted from the lower liquid to gas ratio required by the magnesium-enhanced lime process. Three recirculation pumps per module were reduced to a single operating pump per module, lowering the scrubber pressure drop. Significant cost reduction in the operating costs of the ball mill was realized due to modifications made to slake lime instead of grinding limestone. Prior to switching, personnel from AEC and Dravo Lime Company ran a four week test on magnesium-enhanced lime to obtain scrubber performance data including SO{sub 2} removal efficiencies on the modules while burning a 1.8% sulfur coal. This paper discusses the plant modifications that were needed to make the switch, cost justifications due to coal switching, and AEC`s operating experiences to date. AEC and Dravo Lime Company working together as a team conducted detailed cost studies, followed by extensive field tests and implemented the plant modifications. This plant continues to operate burning higher sulfur coal with the magnesium-enhanced lime FGD system.

  6. The ATLAS Silicon Pixel Sensors

    E-Print Network [OSTI]

    Alam, M S; Einsweiler, K F; Emes, J; Gilchriese, M G D; Joshi, A; Kleinfelder, S A; Marchesini, R; McCormack, F; Milgrome, O; Palaio, N; Pengg, F; Richardson, J; Zizka, G; Ackers, M; Andreazza, A; Comes, G; Fischer, P; Keil, M; Klasen, V; Kühl, T; Meuser, S; Ockenfels, W; Raith, B; Treis, J; Wermes, N; Gössling, C; Hügging, F G; Wüstenfeld, J; Wunstorf, R; Barberis, D; Beccherle, R; Darbo, G; Gagliardi, G; Gemme, C; Morettini, P; Musico, P; Osculati, B; Parodi, F; Rossi, L; Blanquart, L; Breugnon, P; Calvet, D; Clemens, J-C; Delpierre, P A; Hallewell, G D; Laugier, D; Mouthuy, T; Rozanov, A; Valin, I; Aleppo, M; Caccia, M; Ragusa, F; Troncon, C; Lutz, Gerhard; Richter, R H; Rohe, T; Brandl, A; Gorfine, G; Hoeferkamp, M; Seidel, SC; Boyd, GR; Skubic, P L; Sícho, P; Tomasek, L; Vrba, V; Holder, M; Ziolkowski, M; D'Auria, S; del Papa, C; Charles, E; Fasching, D; Becks, K H; Lenzen, G; Linder, C

    2001-01-01

    Prototype sensors for the ATLAS silicon pixel detector have been developed. The design of the sensors is guided by the need to operate them in the severe LHC radiation environment at up to several hundred volts while maintaining a good signal-to-noise ratio, small cell size, and minimal multiple scattering. The ability to be operated under full bias for electrical characterization prior to the attachment of the readout integrated circuit electronics is also desired.

  7. Light Emission in Silicon from Carbon Nanotubes

    E-Print Network [OSTI]

    Gaufrès, Etienne; Noury, Adrien; Roux, Xavier Le; Rasigade, Gilles; Beck, Alexandre; Vivien, Laurent

    2015-01-01

    The use of optics in microelectronic circuits to overcome the limitation of metallic interconnects is more and more considered as a viable solution. Among future silicon compatible materials, carbon nanotubes are promising candidates thanks to their ability to emit, modulate and detect light in the wavelength range of silicon transparency. We report the first integration of carbon nanotubes with silicon waveguides, successfully coupling their emission and absorption properties. A complete study of this coupling between carbon nanotubes and silicon waveguides was carried out, which led to the demonstration of the temperature-independent emission from carbon nanotubes in silicon at a wavelength of 1.3 {\\mu}m. This represents the first milestone in the development of photonics based on carbon nanotubes on silicon.

  8. Process for strengthening silicon based ceramics

    DOE Patents [OSTI]

    Kim, Hyoun-Ee; Moorhead, A. J.

    1993-04-06

    A process for strengthening silicon based ceramic monolithic materials and omposite materials that contain silicon based ceramic reinforcing phases that requires that the ceramic be exposed to a wet hydrogen atmosphere at about 1400.degree. C. The process results in a dense, tightly adherent silicon containing oxide layer that heals, blunts , or otherwise negates the detrimental effect of strength limiting flaws on the surface of the ceramic body.

  9. Process for strengthening silicon based ceramics

    DOE Patents [OSTI]

    Kim, Hyoun-Ee (Oak Ridge, TN); Moorhead, A. J. (Knoxville, TN)

    1993-01-01

    A process for strengthening silicon based ceramic monolithic materials and omposite materials that contain silicon based ceramic reinforcing phases that requires that the ceramic be exposed to a wet hydrogen atmosphere at about 1400.degree. C. The process results in a dense, tightly adherent silicon containing oxide layer that heals, blunts , or otherwise negates the detrimental effect of strength limiting flaws on the surface of the ceramic body.

  10. Method for fabricating pixelated silicon device cells

    DOE Patents [OSTI]

    Nielson, Gregory N.; Okandan, Murat; Cruz-Campa, Jose Luis; Nelson, Jeffrey S.; Anderson, Benjamin John

    2015-08-18

    A method, apparatus and system for flexible, ultra-thin, and high efficiency pixelated silicon or other semiconductor photovoltaic solar cell array fabrication is disclosed. A structure and method of creation for a pixelated silicon or other semiconductor photovoltaic solar cell array with interconnects is described using a manufacturing method that is simplified compared to previous versions of pixelated silicon photovoltaic cells that require more microfabrication steps.

  11. Diamond-silicon carbide composite and method

    DOE Patents [OSTI]

    Zhao, Yusheng (Los Alamos, NM)

    2011-06-14

    Uniformly dense, diamond-silicon carbide composites having high hardness, high fracture toughness, and high thermal stability are prepared by consolidating a powder mixture of diamond and amorphous silicon. A composite made at 5 GPa/1673K had a measured fracture toughness of 12 MPam.sup.1/2. By contrast, liquid infiltration of silicon into diamond powder at 5 GPa/1673K produces a composite with higher hardness but lower fracture toughness.

  12. Structural alloy with a protective coating containing silicon or silicon-oxide

    DOE Patents [OSTI]

    Natesan, K.

    1992-01-01

    This invention is comprised of an iron-based alloy containing chromium and optionally, nickel. The alloy has a surface barrier of silicon or silicon plus oxygen which converts at high temperature to a protective silicon compound. The alloy can be used in oxygen-sulfur mixed gases at temperatures up to about 1100{degrees}C.

  13. Toward accurate and large-scale silicon photonics

    E-Print Network [OSTI]

    Sun, Jie, Ph.D. Massachusetts Institute of Technology

    2013-01-01

    Silicon photonics, emerging from the interface of silicon technology and photonic technology, is expected to inherit the incredible integration ability of silicon technology that has boomed the microelectronic industry for ...

  14. THE STRUCTURE OF ULTRA-THIN OXIDE ON SILICON

    E-Print Network [OSTI]

    Krivanek, Ondrej L.

    2012-01-01

    Ultra-thin (10-lOOA) silicon oxide layers on silicon are ofcrystalline silicon. The oxide layer is seen to be sharplyundulation of the whole oxide layer with ~300A wavelength.

  15. Efficient light trapping structure in thin film silicon solar cells

    E-Print Network [OSTI]

    Sheng, Xing

    Thin film silicon solar cells are believed to be promising candidates for continuing cost reduction in photovoltaic panels because silicon usage could be greatly reduced. Since silicon is an indirect bandgap semiconductor, ...

  16. Apparatus for obtaining silicon from fluosilicic acid

    DOE Patents [OSTI]

    Sanjurjo, Angel (San Jose, CA)

    1986-05-20

    Apparatus for producing low cost, high purity solar grade silicon ingots in single crystal or quasi single crystal ingot form in a substantially continuous operation in a two stage reactor starting with sodium fluosilicate and a metal more electropositive than silicon (preferably sodium) in separate compartments having easy vapor transport therebetween and thermally decomposing the sodium fluosilicate to cause formation of substantially pure silicon and a metal fluoride which may be continuously separated in the melt and silicon may be directly and continuously cast from the melt.

  17. ULTRATHIN FLEXIBLE CRYSTALLINE SILICON: MICROSYSTEMS ENABLED PHOTOVOLTAICS

    E-Print Network [OSTI]

    ULTRATHIN FLEXIBLE CRYSTALLINE SILICON: MICROSYSTEMS ENABLED PHOTOVOLTAICS Jose L. Cruz Photovoltaics (MEPV) is a technique to create solar cells relying on tools from the microsystems and integrated

  18. Engineering Metal Impurities in Multicrystalline Silicon Solar...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Metal Impurities in Multicrystalline Silicon Solar Cells Print Transition metals are one of the main culprits in degrading the efficiency of multicrystalline solar...

  19. Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon...

    Office of Scientific and Technical Information (OSTI)

    Hydrogenation of Dislocation-Limited Heteroepitaxial Silicon Solar Cells: Preprint Bolen, M. L.; Grover, S.; Teplin, C. W.; Bobela, D.; Branz, H. M.; Stradins, P. 08 HYDROGEN; 14...

  20. Silicon Materials and Devices (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-06-01

    Capabilities fact sheet for the National Center for Photovoltaics: Silicon Materials and Devices that includes scope, core competencies and capabilities, and contact/web information.

  1. Silicon Materials and Devices (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-06-01

    This National Center for Photovoltaics sheet describes the capabilities of its silicon materials and devices research. The scope and core competencies and capabilities are discussed.

  2. Process for Polycrystalline film silicon growth

    DOE Patents [OSTI]

    Wang, Tihu (Littleton, CO); Ciszek, Theodore F. (Evergreen, CO)

    2001-01-01

    A process for depositing polycrystalline silicon on substrates, including foreign substrates, occurs in a chamber at about atmospheric pressure, wherein a temperature gradient is formed, and both the atmospheric pressure and the temperature gradient are maintained throughout the process. Formation of a vapor barrier within the chamber that precludes exit of the constituent chemicals, which include silicon, iodine, silicon diiodide, and silicon tetraiodide. The deposition occurs beneath the vapor barrier. One embodiment of the process also includes the use of a blanketing gas that precludes the entrance of oxygen or other impurities. The process is capable of repetition without the need to reset the deposition zone conditions.

  3. Protein separations using porous silicon membranes 

    E-Print Network [OSTI]

    Pass, Shannon Marie

    1992-01-01

    ) 61 IX LIST OF TABLES 1. The L9 Orthogonal Array 34 2. Experimental Factors and Levels . 3. Results of Silicon Etching Trials . 35 40 4. Results of Silicon Membrane Separation Experiments 44 5. Results of Single Solute Experiments Using... charge or as the absence of an electron in the crystal structure of silicon. The properties of boron doped siTicon are exploited experimentally by setting up an etch cell in which one surface of the silicon serves as the anode and by using...

  4. Solar cell with silicon oxynitride dielectric layer

    DOE Patents [OSTI]

    Shepherd, Michael; Smith, David D

    2015-04-28

    Solar cells with silicon oxynitride dielectric layers and methods of forming silicon oxynitride dielectric layers for solar cell fabrication are described. For example, an emitter region of a solar cell includes a portion of a substrate having a back surface opposite a light receiving surface. A silicon oxynitride (SiO.sub.xN.sub.y, 0silicon oxynitride dielectric layer.

  5. Enabling Thin Silicon Solar Cell Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    has spurred companies to reduce the cost and increase the reliability of their solar photovoltaics (SPVs). The use of thinner silicon in SPV technologies is being widely...

  6. Holey Silicon as an Efficient Thermoelectric Material

    E-Print Network [OSTI]

    Tang, Jinyao

    2011-01-01

    Silicon as Efficient Thermoelectric Material Jinyao Tang 1,This work investigated the thermoelectric properties of thinat room temperature, the thermoelectric performance of HS is

  7. Synthesis and tribological behavior of silicon oxycarbonitride...

    Office of Scientific and Technical Information (OSTI)

    Article: Synthesis and tribological behavior of silicon oxycarbonitride thin films derived from poly(urea)methyl vinyl silazane. Citation Details In-Document Search Title:...

  8. Site Environmental Report for 2009, Volume I

    E-Print Network [OSTI]

    Lackner, Regina

    2010-01-01

    demand (COD) Magnesium Arsenic, cadmium, lead, selenium, and silver Mercury Cyanide COD Aluminum, copper,

  9. The silicon/zinc oxide interface in amorphous silicon-based thin-film solar cells: Understanding an empirically optimized contact

    SciTech Connect (OSTI)

    Gerlach, D.; Wilks, R. G.; Wimmer, M.; Felix, R.; Gorgoi, M.; Lips, K.; Rech, B.; Wippler, D.; Mueck, A.; Meier, M.; Huepkes, J.; Lozac'h, M.; Ueda, S.; Sumiya, M.; Yoshikawa, H.; Kobayashi, K.; Baer, M.

    2013-07-08

    The electronic structure of the interface between the boron-doped oxygenated amorphous silicon 'window layer' (a-SiO{sub x}:H(B)) and aluminum-doped zinc oxide (ZnO:Al) was investigated using hard x-ray photoelectron spectroscopy and compared to that of the boron-doped microcrystalline silicon ({mu}c-Si:H(B))/ZnO:Al interface. The corresponding valence band offsets have been determined to be (-2.87 {+-} 0.27) eV and (-3.37 {+-} 0.27) eV, respectively. A lower tunnel junction barrier height at the {mu}c-Si:H(B)/ZnO:Al interface compared to that at the a-SiO{sub x}:H(B)/ZnO:Al interface is found and linked to the higher device performances in cells where a {mu}c-Si:H(B) buffer between the a-Si:H p-i-n absorber stack and the ZnO:Al contact is employed.

  10. Designing Silicon Nanostructures for High Energy Lithium Ion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Designing Silicon Nanostructures for High Energy Lithium Ion Battery Anodes Designing Silicon Nanostructures for High Energy Lithium Ion Battery Anodes 2012 DOE Hydrogen and Fuel...

  11. Low-temperature plasma-deposited silicon epitaxial films: Growth...

    Office of Scientific and Technical Information (OSTI)

    Low-temperature plasma-deposited silicon epitaxial films: Growth and properties Citation Details In-Document Search Title: Low-temperature plasma-deposited silicon epitaxial films:...

  12. Predicting fracture in micron-scale polycrystalline silicon MEMS...

    Office of Scientific and Technical Information (OSTI)

    Predicting fracture in micron-scale polycrystalline silicon MEMS structures. Citation Details In-Document Search Title: Predicting fracture in micron-scale polycrystalline silicon...

  13. Silicon Nanostructure-based Technology for Next Generation Energy...

    Office of Environmental Management (EM)

    Silicon Nanostructure-based Technology for Next Generation Energy Storage Silicon Nanostructure-based Technology for Next Generation Energy Storage 2013 DOE Hydrogen and Fuel Cells...

  14. Pore Collapse and Regrowth in Silicon Electrodes for Rechargeable...

    Office of Scientific and Technical Information (OSTI)

    Pore Collapse and Regrowth in Silicon Electrodes for Rechargeable Batteries Citation Details In-Document Search Title: Pore Collapse and Regrowth in Silicon Electrodes for...

  15. Vehicle Technologies Office Merit Review 2012: Silicon Nanostructure...

    Office of Environmental Management (EM)

    2: Silicon Nanostructure-based Technology for Next Generation Energy Storage Vehicle Technologies Office Merit Review 2012: Silicon Nanostructure-based Technology for Next...

  16. Guiyang Polysource Silicon Co Ltd Formerly Jiayuan Sunshine Guiyang...

    Open Energy Info (EERE)

    Guiyang Polysource Silicon Co Ltd Formerly Jiayuan Sunshine Guiyang Hi New Sunshine Technology Jump to: navigation, search Name: Guiyang Polysource Silicon Co Ltd (Formerly Jiayuan...

  17. Design and Implementation of Silicon Nitride Valves for Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Implementation of Silicon Nitride Valves for Heavy Duty Diesel Engines Design and Implementation of Silicon Nitride Valves for Heavy Duty Diesel Engines Poster presentation at the...

  18. Project Profile: Hybrid Organic Silicone HTF Utilizing Endothermic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hybrid Organic Silicone HTF Utilizing Endothermic Chemical Reactions for Latent Heat Storage Project Profile: Hybrid Organic Silicone HTF Utilizing Endothermic Chemical Reactions...

  19. All-electrical single-electron shuttle in a silicon quantum dot

    E-Print Network [OSTI]

    Chan, K W; Kemppinen, A; Lai, N S; Tan, K Y; Lim, W H; Dzurak, A S

    2011-01-01

    We report on single-electron shuttling experiments with a silicon metal-oxide-semiconductor quantum dot at 300 mK. Our system consists of an accumulated electron layer at the Si/SiO2 interface below an aluminum top gate with two additional barrier gates used to deplete the electron gas locally and to define a quantum dot. Directional single-electron shuttling from the source and to the drain lead is achieved by applying a dc source-drain bias while driving the barrier gates with an ac voltage of frequency fp. Current plateaus at integer levels of efp are observed up to fp = 240 MHz operation frequencies. The observed results are explained by a sequential tunneling model which suggests that the electron gas may be heated substantially by the ac driving voltage.

  20. Vehicle Technologies Office Merit Review 2014: Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis

    Broader source: Energy.gov [DOE]

    Presentation given by INFINIUM, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about scale-up of magnesium...

  1. Vehicle Technologies Office Merit Review 2015: Scale-Up of Magnesium Production by Fully Stabilized Zirconia Electrolysis

    Broader source: Energy.gov [DOE]

    Presentation given by INFINIUM, Inc. at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about scale-up of magnesium...

  2. Identifying barriers to the availability and use of Magnesium Sulphate Injection in resource poor countries: A case study in Zambia

    E-Print Network [OSTI]

    Ridge, Anna L; Bero, Lisa A; Hill, Suzanne R

    2010-01-01

    barriers to the availability and use of Magnesium Sulphateto identify barriers to the availability and use of MgSO4 infacilitators to the availability and use of MgSO4 identified

  3. Reduction of Annealing Times for Energy Conservation in Aluminum

    SciTech Connect (OSTI)

    Anthony D. Rollett; Hasso Weiland; Mohammed Alvi; Abhijit Brahme

    2005-08-31

    Carnegie Mellon University was teamed with the Alcoa Technical Center with support from the US Dept. of Energy (Office of Industrial Technology) and the Pennsylvania Technology Investment Authority (PTIA) to make processing of aluminum less costly and more energy efficient. Researchers in the Department of Materials Science and Engineering have investigated how annealing processes in the early stages of aluminum processing affect the structure and properties of the material. Annealing at high temperatures consumes significant amounts of time and energy. By making detailed measurements of the crystallography and morphology of internal structural changes they have generated new information that will provide a scientific basis for shortening processing times and consuming less energy during annealing.

  4. Influence of insulating coating on aluminum wire explosions

    SciTech Connect (OSTI)

    Li, Yang; Wu, Jian; Sheng, Liang; Zhao, Jizhen; Zhang, Mei; Yuan, Yuan; Peng, Bodong; Li, Xingwen

    2014-10-15

    Single wire explosions are widely used in understanding the early stages of z-pinch experiments. This paper presents a serial of experiments conducted on the pulse power generator with ?1?kA peak current and ?10?ns rising time in Xi'an Jiao Tong University. Polyimide coated aluminum wires and uncoated ones were tested under three different voltages to analyze the effect of insulating coating. Experimental results showed that insulating coating can increase the energy deposition 10%?30% in aluminum wires by delaying the voltage collapse and raising the maximum load resistance. The substantial energy deposition resulted in about 20% faster expansion rates for coated wires. Experimental evidence that plasma channel shunts the current from the wire core was observed by streak camera and schlieren graphs. This paper also briefly discussed the influence of nonuniform coating on the morphology of wire expansion.

  5. Amorphous silicon carbide passivating layers for crystalline-silicon-based heterojunction solar cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Boccard, Mathieu; Holman, Zachary C.

    2015-08-14

    With this study, amorphous silicon enables the fabrication of very high-efficiency crystalline-silicon-based solar cells due to its combination of excellent passivation of the crystalline silicon surface and permeability to electrical charges. Yet, amongst other limitations, the passivation it provides degrades upon high-temperature processes, limiting possible post-deposition fabrication possibilities (e.g., forcing the use of low-temperature silver pastes). We investigate the potential use of intrinsic amorphous silicon carbide passivating layers to sidestep this issue. The passivation obtained using device-relevant stacks of intrinsic amorphous silicon carbide with various carbon contents and doped amorphous silicon are evaluated, and their stability upon annealing assessed, amorphousmore »silicon carbide being shown to surpass amorphous silicon for temperatures above 300°C. We demonstrate open-circuit voltage values over 700 mV for complete cells, and an improved temperature stability for the open-circuit voltage. Transport of electrons and holes across the hetero-interface is studied with complete cells having amorphous silicon carbide either on the hole-extracting side or on the electron-extracting side, and a better transport of holes than of electrons is shown. Also, due to slightly improved transparency, complete solar cells using an amorphous silicon carbide passivation layer on the hole-collecting side are demonstrated to show slightly better performances even prior to annealing than obtained with a standard amorphous silicon layer.« less

  6. The effects of exercise and dietary fat on calcium, magnesium, iron, and zinc on selected tissues in rats 

    E-Print Network [OSTI]

    Nguyen, Thuy Huong

    1989-01-01

    of the requirements for the degree MASTER OF SCIENCE December 1989 Major Subject: Nutrition THE EFFECTS OF EXERCISE AND DIETARY FAT ON CALCIUM, MAGNESIUM, IRON, AND ZINC ON SELECTED TISSUES IN RATS A Thesis by THUY HUONG NGUYEN Approved as to style... and content by: Karen S. ubena (Chair of Committee) L. yne Greene (Member) Barbara C. O' Brien (Member) Gary C. Smith (Head of Department) December 1989 ABSTRACT The Effects of Exercise and Dietary Fat on Calcium, Magnesium, Iron, and Zinc...

  7. The interaction of nitrogen and magnesium deficiences in certain aspects of the physiology of the cotton plant 

    E-Print Network [OSTI]

    Ghosh, Debabrata

    1961-01-01

    THE INTERACTION OF NITROGEN AND MAGNESIUM DEFICIENCIES IN CERTAIN ASPECTS OF THE PHYSIOLOGY OF THE COTTON PLANT A Thesis By DEBABRATA GHOSH Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1961 Major Subject: plant physiology THE INTERACTION OF NITROGEN AND MAGNESIUM DEFICIENCIES IN CERTAIN ASPECTS OF THE PHYSIOLOGY OF THE COTTON PLANT A Thesis By DEBABRATA...

  8. The determination of the bioavailability and the site of absorption in lambs fed different sources of magnesium 

    E-Print Network [OSTI]

    Hurley, Leigh Anne

    1988-01-01

    of the animal influences Ng avail- ability. Grace (1972) found that older cows exhibited a sharper decrease in plasma Ng than did younger cows in the early stages of lactation. Magnesium Supplementation The adequacy of dietary Mg levels is probably...THE DETERMINATION OF THE BIOAVAILABILITY AND THE SITE OF ABSORPTION IN LAMBS FED DIFFERENT SOURCES OF MAGNESIUM A Thesis I, EIGH ANNE HURLEY Submitted to the Of f ice of Graduate Studies Texas AAM UniversitY in partial fulfillment...

  9. Ash, calcium, phosphorus and magnesium content of the metacarpus of hereford cows under different nutritional and physiological conditions 

    E-Print Network [OSTI]

    Haque, Mozammel

    1967-01-01

    ASH, CALCIUM, PHOSPHORUS AND MAGNESIUM CONTENT OF THE METACARPUS OF HEREFORD COWS UNDER DIFFERENT NUTRITIONAL AND PHYSIOLOGICAL CONDITIONS A Thesis By MOZAMMEL HAQUE Submitted to the Graduate College of the Texas A&M University in partial... centages of Calcium, Phosphorus snd Magnesium in Bone Ash for Cows Gi;en Different Treatments During Pre- And Post-Partum Periods 22 10 Analysis of Variance oi Calcium in Bone Ash Dun an's )tultiple tvange Test 1'or Calcium in Bone Ash. Analy...

  10. Analog Optical Computing Primitives in Silicon Photonics

    E-Print Network [OSTI]

    Jiang, Yunshan; Jalali, Bahram

    2015-01-01

    Optical computing accelerators may help alleviate bandwidth and power consumption bottlenecks in electronics. We show an approach to implementing logarithmic-type analog co-processors in silicon photonics and use it to perform the exponentiation operation. The function is realized by exploiting nonlinear-absorption-enhanced Raman amplification saturation in a silicon waveguide.

  11. Isentropic Compression Experiment on Aluminum Using the Z-Accelerator

    SciTech Connect (OSTI)

    Williamson, D.R.; Peterson, R.R.; Blanchard, J.P

    2003-07-15

    The capability of using the Z-Machine at Sandia to perform isentropic compression experiments has been discussed by Hall previously. Pressures exceeding 1.5 Mbar have been launched into materials and the pressure wave can be shaped by varying the load current in Z. In this paper, theoretical results will be presented for an aluminum sample in which we obtain isentropic equations of state (EOS) information.Obtaining the isentropic EOS is necessary in many scientific and technological fields for computer simulations. We will follow the procedure outlined by Reisman to determine the EOS. From these steps, we will determine the theoretical EOS of aluminum using data obtained from BUCKY. We will discuss any variances we have in our results due to the use of two different sets of EOS opacity data.The results presented here were obtained using BUCKY, a 1-D MHD code developed at University of Wisconsin-Madison. BUCKY is a code that simulates high energy density plasmas and target yields for Inertial Confinement Fusion (ICF). BUCKY was originally designed to study target physics and target chamber designs for ICF reactors but can be used to study Isentropic Compression Experiments.We will describe the procedure used to determine the velocity wave profile measurements that leads to determining EOS. From the velocity wave profile we will be able to determine the isentropic compression equations of state of the aluminum sample modeled.

  12. Preparation of silicon carbide fibers

    DOE Patents [OSTI]

    Wei, G.C.

    1983-10-12

    Silicon carbide fibers suitable for use in the fabrication of dense, high-strength, high-toughness SiC composites or as thermal insulating materials in oxidizing environments are fabricated by a new, simplified method wherein a mixture of short-length rayon fibers and colloidal silica is homogenized in a water slurry. Water is removed from the mixture by drying in air at 120/sup 0/C and the fibers are carbonized by (pyrolysis) heating the mixture to 800 to 1000/sup 0/C in argon. The mixture is subsequently reacted at 1550 to 1900/sup 0/C in argon to yield pure ..beta..-SiC fibers.

  13. Buckeye Silicon | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmentalBowerbank, Maine: EnergyEnergyOhio: Energy ResourcesSilicon BeSi Jump to:

  14. Micro benchtop optics by bulk silicon micromachining

    DOE Patents [OSTI]

    Lee, Abraham P. (Walnut Creek, CA); Pocha, Michael D. (Livermore, CA); McConaghy, Charles F. (Livermore, CA); Deri, Robert J. (Pleasanton, CA)

    2000-01-01

    Micromachining of bulk silicon utilizing the parallel etching characteristics of bulk silicon and integrating the parallel etch planes of silicon with silicon wafer bonding and impurity doping, enables the fabrication of on-chip optics with in situ aligned etched grooves for optical fibers, micro-lenses, photodiodes, and laser diodes. Other optical components that can be microfabricated and integrated include semi-transparent beam splitters, micro-optical scanners, pinholes, optical gratings, micro-optical filters, etc. Micromachining of bulk silicon utilizing the parallel etching characteristics thereof can be utilized to develop miniaturization of bio-instrumentation such as wavelength monitoring by fluorescence spectrometers, and other miniaturized optical systems such as Fabry-Perot interferometry for filtering of wavelengths, tunable cavity lasers, micro-holography modules, and wavelength splitters for optical communication systems.

  15. Compensated amorphous-silicon solar cell

    DOE Patents [OSTI]

    Devaud, G.

    1982-06-21

    An amorphous silicon solar cell including an electrically conductive substrate, a layer of glow discharge deposited hydrogenated amorphous silicon having regions of differing conductivity with at least one region of intrinsic hydrogenated amorphous silicon. The layer of hydrogenated amorphous silicon has opposed first and second major surfaces where the first major surface contacts the elecrically conductive substrate and an electrode for electrically contacting the second major surface. The intrinsic hydrogenated amorphous silicon region is deposited in a glow discharge with an atmosphere which includes not less than about 0.02 atom percent mono-atomic boron. An improved N.I.P. solar cell is disclosed using a BF/sub 3/ doped intrinsic layer.

  16. Fabricating solar cells with silicon nanoparticles

    DOE Patents [OSTI]

    Loscutoff, Paul; Molesa, Steve; Kim, Taeseok

    2014-09-02

    A laser contact process is employed to form contact holes to emitters of a solar cell. Doped silicon nanoparticles are formed over a substrate of the solar cell. The surface of individual or clusters of silicon nanoparticles is coated with a nanoparticle passivation film. Contact holes to emitters of the solar cell are formed by impinging a laser beam on the passivated silicon nanoparticles. For example, the laser contact process may be a laser ablation process. In that case, the emitters may be formed by diffusing dopants from the silicon nanoparticles prior to forming the contact holes to the emitters. As another example, the laser contact process may be a laser melting process whereby portions of the silicon nanoparticles are melted to form the emitters and contact holes to the emitters.

  17. Sol-gel preparation of lead magnesium niobate (PMN) powders and thin films

    DOE Patents [OSTI]

    Boyle, T.J.

    1999-01-12

    A method of preparing a lead magnesium niobium oxide (PMN), Pb(Mg{sub 1/3}Nb{sub 2/3})O{sub 3}, precursor solution by a solvent method wherein a liquid solution of a lead-complex PMN precursor is combined with a liquid solution of a niobium-complex PMN precursor, the combined lead- and niobium-complex liquid solutions are reacted with a magnesium-alkyl solution, forming a PMN precursor solution and a lead-based precipitate, and the precipitate is separated from the reacted liquid PMN precursor solution to form a precipitate-free PMN precursor solution. This precursor solution can be processed to form both ferroelectric powders and thin films. 3 figs.

  18. Sol-Gel Preparation Of Lead Magnesium Ni Obate (Pmn) Powdersand Thin Films

    DOE Patents [OSTI]

    Boyle, Timothy J. (Albuquerque, NM)

    1999-01-12

    A method of preparing a lead magnesium niobium oxide (PMN), Pb(Mg.sub.1/3 Nb.sub.2/3)O.sub.3, precursor solution by a solvent method wherein a liquid solution of a lead-complex PMN precursor is combined with a liquid solution of a niobium-complex PMN precursor, the combined lead- and niobium-complex liquid solutions are reacted with a magnesium-alkyl solution, forming a PMN precursor solution and a lead-based precipitate, and the precipitate is separated from the reacted liquid PMN precursor solution to form a precipitate-free PMN precursor solution. This precursor solution can be processed to form both ferroelectric powders and thin films.

  19. The effect of rare earth elements on the texture and formability of asymmetrically rolled magnesium sheet

    SciTech Connect (OSTI)

    Alderman, Dr. Martyn [Magnesium Elektron North America; Cavin, Odis Burl [ORNL; Davis, Dr. Bruce [Magnesium Elektron North America; Muralidharan, Govindarajan [ORNL; Muth, Thomas R [ORNL; Peter, William H [ORNL; Randman, David [Magnesium Elektron North America; Watkins, Thomas R [ORNL

    2011-01-01

    The lack of formability is a serious issue when considering magnesium alloys for various applications. Standard symmetric rolling introduces a strong basal texture that decreases the formability; however, asymmetric rolling has been put forward as a possible route to produce sheet with weaker texture and greater ductility. It has also been shown in recent work that weaker textures can be produced through the addition of rare earth elements to magnesium alloys. Therefore, this study has been carried out to investigate the effect of rare earth additions on the texture changes during asymmetric rolling. Two alloys have been used, AZ31B and ZEK100. The effect that the rare earth additions have on the texture of asymmetrically rolled sheet and the subsequent changes in formability will be discussed.

  20. An examination of the relationship between calcium and magnesium and hypertension 

    E-Print Network [OSTI]

    Georghiades, Mary Elizabeth

    1988-01-01

    of MASTER QF SCIENCE May 1988 Major Subject. : Nutrition AN EXAMINATION OF THE RELATIONSHIP BETWEEN CALCIUM AND MAGNESIUM AND HYPERTENSION A Thesis by MARY ELIZABETH GEORGH I ADES Approved as to style and content by: Karen S. Kubena (Chair... of Committee) Gary Smith (Head of Department) j fj Joanne R. Lupton (Member) W. Alex Mclntosh (Member) May l988 ABSTRACT An Examination of the Relationship between Calcium and Hagnesiurn and Hypertension. (Nay 19BB) Nary Elizabeth Geor ghiades, B. S...

  1. Blood pressure and red blood cell magnesium, potassium, and calcium responses to dietary fats 

    E-Print Network [OSTI]

    Wehrman, Noreen Elaine

    1993-01-01

    influences the activities of several membrane transport systems, including the sodium pump which exchanges three sodium ions for two potassium ions, the Na+-K+-Cl cotransport system which moves these three ions across the cell membrane, and the K... for the degree of MASTER OF SCIENCE August 1993 Major Subject: Nutrition BLOOD PRESSURE AND RED BLOOD CELL MAGNESIUM, POTASSIUM, AND CALCIUM RESPONSES TO DIETARY FATS A Thesis by NOREEN ELAINE WEHRMAN Submitted to Texas A&M University in partial...

  2. Large scale two-dimensional arrays of magnesium diboride superconducting quantum interference devices

    SciTech Connect (OSTI)

    Cybart, Shane A. Dynes, R. C.; Wong, T. J.; Cho, E. Y.; Beeman, J. W.; Yung, C. S.; Moeckly, B. H.

    2014-05-05

    Magnetic field sensors based on two-dimensional arrays of superconducting quantum interference devices were constructed from magnesium diboride thin films. Each array contained over 30?000 Josephson junctions fabricated by ion damage of 30?nm weak links through an implant mask defined by nano-lithography. Current-biased devices exhibited very large voltage modulation as a function of magnetic field, with amplitudes as high as 8?mV.

  3. Microstructure-properties correlation of pressure die cast eutectic aluminum-silicon alloys for escalator steps (Part I)

    SciTech Connect (OSTI)

    Asensio-Lozano, J. [Department of Materials Science and Metallurgical Engineering, The School of Mines, University of Oviedo, 13 Independence St., Oviedo, E-33004 Asturias (Spain)]. E-mail: jasensio@etsimo.uniovi.es; Suarez-Pena, B. [Department of Materials Science and Metallurgical Engineering, Technical School of Industrial Engineering, University of Oviedo, Viesques University Campus, Carretera de Castiello de Bernueces, s/n, Gijon, E-33203 Asturias (Spain)

    2006-04-15

    This paper is a study of the roles of strontium as a modifier and titanium as a refiner of the Al-12%Si commercial alloy for escalator steps processed by a hot-chamber pressure-die casting method. Specifically, two objectives were pursued. First, the detection of the level at which the modifier and the refiner become effective in altering the relevant microstructural parameters, namely, the volume fraction, grain size and shape of proeutectic phases. Second, investigation of the morphology of the eutectic matrix.

  4. Characterization of fold defects in AZ91D and AE42 magnesium alloy permanent mold castings

    SciTech Connect (OSTI)

    Bichler, L. [Centre for Near-net-shape Processing of Materials, Ryerson University, 101 Gerrard St. E., Toronto, M5B 2K3 (Canada); Ravindran, C., E-mail: rravindr@ryerson.ca [Centre for Near-net-shape Processing of Materials, Ryerson University, 101 Gerrard St. E., Toronto, M5B 2K3 (Canada)

    2010-03-15

    Casting premium-quality magnesium alloy components for aerospace and automotive applications poses unique challenges. Magnesium alloys are known to freeze rapidly prior to filling a casting cavity, resulting in misruns and cold shuts. In addition, melt oxidation, solute segregation and turbulent metal flow during casting contribute to the formation of fold defects. In this research, formation of fold defects in AZ91D and AE42 magnesium alloys cast via the permanent mold casting process was investigated. Computer simulations of the casting process predicted the development of a turbulent metal flow in a critical casting region with abrupt geometrical transitions. SEM and light optical microscopy examinations revealed the presence of folds in this region for both alloys. However, each alloy exhibited a unique mechanism responsible for fold formation. In the AZ91D alloy, melt oxidation and velocity gradients in the critical casting region prevented fusion of merging metal front streams. In the AE42 alloy, limited solubility of rare-earth intermetallic compounds in the {alpha}-Mg phase resulted in segregation of Al{sub 2}RE particles at the leading edge of a metal front and created microstructural inhomogeneity across the fold.

  5. Yield Asymmetry Design of Magnesium Alloys by Integrated Computational Materials Engineering

    SciTech Connect (OSTI)

    Li, Dongsheng; Joshi, Vineet V.; Lavender, Curt A.; Khaleel, Mohammad A.; Ahzi, Said

    2013-11-01

    Deformation asymmetry of magnesium alloys is an important factor on machine design in automobile industry. Represented by the ratio of compressive yield stress (CYS) against tensile yield stress (TYS), deformation asymmetry is strongly related to microstructure, characterized by texture and grain size. Modified intermediate phi-model, a polycrystalline viscoplasticity model, is used to predict the deformation behavior of magnesium alloys with different grain sizes. Validated with experimental results, integrated computational materials engineering is applied to find out the route in achieving desired asymmetry by thermomechanical processing. In some texture, for example, rolled texture, CYS/TYS is smaller than 1 under different loading directions. In some texture, for example, extruded texture, asymmetry is large along normal direction. Starting from rolled texture, the asymmetry will increased to close to 1 along rolling direction after compressed to a strain of 0.2. Our model shows that grain refinement increases CYS/TYS. Besides texture control, grain refinement can also optimize the yield asymmetry. After the grain size decreased to a critical value, CYS/TYS reaches to 1 since CYS increases much faster than TYS. By tailoring the microstructure using texture control and grain refinement, it is achievable to optimize yield asymmetry in wrought magnesium alloys.

  6. Process for CO.sub.2 capture using a regenerable magnesium hydroxide sorbent

    DOE Patents [OSTI]

    Siriwardane, Ranjani V; Stevens, Jr., Robert W

    2013-06-25

    A process for CO.sub.2 separation using a regenerable Mg(OH).sub.2 sorbent. The process absorbs CO.sub.2 through the formation of MgCO.sub.3 and releases water product H.sub.2O. The MgCO.sub.3 is partially regenerated through direct contact with steam, which acts to heat the magnesium carbonate to a higher temperature, provide heat duty required to decompose the magnesium carbonate to yield MgO and CO.sub.2, provide an H.sub.2O environment over the magnesium carbonate thereby shifting the equilibrium and increasing the potential for CO.sub.2 desorption, and supply H.sub.2O for rehydroxylation of a portion of the MgO. The mixture is polished in the absence of CO.sub.2 using water product H.sub.2O produced during the CO.sub.2 absorption to maintain sorbent capture capacity. The sorbent now comprised substantially of Mg(OH).sub.2 is then available for further CO.sub.2 absorption duty in a cyclic process.

  7. Susceptibility of Aluminum Alloys to Corrosion in Simulated Fuel Blends Containing Ethanol

    SciTech Connect (OSTI)

    Thomson, Jeffery K; Pawel, Steven J; Wilson, Dane F

    2013-01-01

    The compatibility of aluminum and aluminum alloys with synthetic fuel blends comprised of ethanol and reference fuel C (a 50/50 mix of toluene and iso-octane) was examined as a function of water content and temperature. Commercially pure wrought aluminum and several cast aluminum alloys were observed to be similarly susceptible to substantial corrosion in dry (< 50 ppm water) ethanol. Corrosion rates of all the aluminum materials examined was accelerated by increased temperature and ethanol content in the fuel mixture, but inhibited by increased water content. Pretreatments designed to stabilize passive films on aluminum increased the incubation time for onset of corrosion, suggesting film stability is a significant factor in the mechanism of corrosion.

  8. Deformation Behavior of Multilayer Aluminum Oxide/Molybdenum Composite

    E-Print Network [OSTI]

    Collins, Gary S.

    on the silicon wafer. The formula calculates the fracture toughness (Kc) of bulk brittle materials by measuring2O3 should be able to be made tougher by the addition of a more ductile material. In this experiment, molybdenum (Mo) was chosen as this ductile material. The deformation behavior of the multilayer coating

  9. Impact of Aluminum on Anticipated Corrosion in a Flooded SNF Multi Canister Overpack (MCO)

    SciTech Connect (OSTI)

    DUNCAN, D.R.

    1999-07-06

    Corrosion reactions in a flooded MCO are examined to determine the impact of aluminum corrosion products (from aluminum basket grids and spacers) on bound water estimates and subsequent fuel/environment reactions during storage. The mass and impact of corrosion products were determined to be insignificant, validating the choice of aluminum as an MCO component and confirming expectations that no changes to the Technical Databook or particulate mass or water content are necessary.

  10. Femtosecond-laser Microstructuring of Silicon: Dopants and Defects

    E-Print Network [OSTI]

    Mazur, Eric

    -laser Microstructuring of Silicon: Dopants and Defects Cynthia Friend Michael A. Sheehy Abstract This dissertation deals

  11. EFFECT OF GRAIN SIZE ON THE ACOUSTIC EMISSION GENERATED DURING PLASTIC DEFORMATION OF ALUMINUM

    E-Print Network [OSTI]

    Baram, J.

    2013-01-01

    EMISSION GENERATED DURING PLASTIC DEFORMATION OF ALUMINUMEMISSION GENERATED DURING PLASTIC DEFORMATION OF ALUMINUM J.Al 1100 samples during plastic deformation were analyzed

  12. Updated Life-Cycle Assessment of Aluminum Production and Semi-fabrication for the GREET Model

    SciTech Connect (OSTI)

    Dai, Qiang; Kelly, Jarod C.; Burnham, Andrew; Elgowainy, Amgad

    2015-09-01

    This report serves as an update for the life-cycle analysis (LCA) of aluminum production based on the most recent data representing the state-of-the-art of the industry in North America. The 2013 Aluminum Association (AA) LCA report on the environmental footprint of semifinished aluminum products in North America provides the basis for the update (The Aluminum Association, 2013). The scope of this study covers primary aluminum production, secondary aluminum production, as well as aluminum semi-fabrication processes including hot rolling, cold rolling, extrusion and shape casting. This report focuses on energy consumptions, material inputs and criteria air pollutant emissions for each process from the cradle-to-gate of aluminum, which starts from bauxite extraction, and ends with manufacturing of semi-fabricated aluminum products. The life-cycle inventory (LCI) tables compiled are to be incorporated into the vehicle cycle model of Argonne National Laboratory’s Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) Model for the release of its 2015 version.

  13. Investigation of Opportunities for High-Temperature Solar Energy in the Aluminum Industry

    SciTech Connect (OSTI)

    Murray, J.

    2006-05-01

    This report gives the conclusions drawn from a study of the potential application of high-temperature solar process heat for production of aluminum.

  14. Analytical and experimental evaluation of joining silicon carbide to silicon carbide and silicon nitride to silicon nitride for advanced heat engine applications Phase 2. Final report

    SciTech Connect (OSTI)

    Sundberg, G.J.; Vartabedian, A.M.; Wade, J.A.; White, C.S. [Norton Co., Northboro, MA (United States). Advanced Ceramics Div.

    1994-10-01

    The purpose of joining, Phase 2 was to develop joining technologies for HIP`ed Si{sub 3}N{sub 4} with 4wt% Y{sub 2}O{sub 3} (NCX-5101) and for a siliconized SiC (NT230) for various geometries including: butt joins, curved joins and shaft to disk joins. In addition, more extensive mechanical characterization of silicon nitride joins to enhance the predictive capabilities of the analytical/numerical models for structural components in advanced heat engines was provided. Mechanical evaluation were performed by: flexure strength at 22 C and 1,370 C, stress rupture at 1,370 C, high temperature creep, 22 C tensile testing and spin tests. While the silicon nitride joins were produced with sufficient integrity for many applications, the lower join strength would limit its use in the more severe structural applications. Thus, the silicon carbide join quality was deemed unsatisfactory to advance to more complex, curved geometries. The silicon carbide joining methods covered within this contract, although not entirely successful, have emphasized the need to focus future efforts upon ways to obtain a homogeneous, well sintered parent/join interface prior to siliconization. In conclusion, the improved definition of the silicon carbide joining problem obtained by efforts during this contract have provided avenues for future work that could successfully obtain heat engine quality joins.

  15. Production of high specific activity silicon-32

    DOE Patents [OSTI]

    Phillips, Dennis R. (Los Alamos, NM); Brzezinski, Mark A. (Santa Barbara, CA)

    1994-01-01

    A process for preparation of silicon-32 is provide and includes contacting an irradiated potassium chloride target, including spallation products from a prior irradiation, with sufficient water, hydrochloric acid or potassium hydroxide to form a solution, filtering the solution, adjusting pH of the solution to from about 5.5 to about 7.5, admixing sufficient molybdate-reagent to the solution to adjust the pH of the solution to about 1.5 and to form a silicon-molybdate complex, contacting the solution including the silicon-molybdate complex with a dextran-based material, washing the dextran-based material to remove residual contaminants such as sodium-22, separating the silicon-molybdate complex from the dextran-based material as another solution, adding sufficient hydrochloric acid and hydrogen peroxide to the solution to prevent reformation of the silicon-molybdate complex and to yield an oxidization state of the molybdate adapted for subsequent separation by an anion exchange material, contacting the solution with an anion exchange material whereby the molybdate is retained by the anion exchange material and the silicon remains in solution, and optionally adding sufficient alkali metal hydroxide to adjust the pH of the solution to about 12 to 13. Additionally, a high specific activity silicon-32 product having a high purity is provided.

  16. Process for forming silicon carbide films and microcomponents

    DOE Patents [OSTI]

    Hamza, Alex V. (Livermore, CA); Balooch, Mehdi (Berkeley, CA); Moalem, Mehran (Berkeley, CA)

    1999-01-01

    Silicon carbide films and microcomponents are grown on silicon substrates at surface temperatures between 900 K and 1700 K via C.sub.60 precursors in a hydrogen-free environment. Selective crystalline silicon carbide growth can be achieved on patterned silicon-silicon oxide samples. Patterned SiC films are produced by making use of the high reaction probability of C.sub.60 with silicon at surface temperatures greater than 900 K and the negligible reaction probability for C.sub.60 on silicon dioxide at surface temperatures less than 1250 K.

  17. Impact of solid-phase crystallization of amorphous silicon on the chemical structure of the buried Si/ZnO thin film solar cell interface

    SciTech Connect (OSTI)

    Bar, M.; Wimmer, M.; Wilks, R. G.; Roczen, M.; Gerlach, D.; Ruske, F.; Lips, K.; Rech, B.; Weinhardt, L.; Blum, M.; Pookpanratana, S.; Krause, S.; Zhang, Y.; Heske, C.; Yang, W.; Denlinger, J. D.

    2010-04-30

    The chemical interface structure between phosphorus-doped hydrogenated amorphous silicon and aluminum-doped zinc oxide thin films is investigated with soft x-ray emission spectroscopy (XES) before and after solid-phase crystallization (SPC) at 600C. In addition to the expected SPC-induced phase transition from amorphous to polycrystalline silicon, our XES data indicates a pronounced chemical interaction at the buried Si/ZnO interface. In particular, we find an SPC-enhanced formation of Si-O bonds and the accumulation of Zn in close proximity to the interface. For an assumed closed and homogeneous SiO2 interlayer, an effective thickness of (5+2)nm after SPC could be estimated.

  18. CRYSTALLINE SILICON THIN-FILM SOLAR CELLS FROM THE POROUS SILICON PROCESS APPLYING CONVECTION ASSISTED CHEMICAL VAPOR DEPOSITION

    E-Print Network [OSTI]

    CRYSTALLINE SILICON THIN-FILM SOLAR CELLS FROM THE POROUS SILICON PROCESS APPLYING CONVECTION for the first time to monocrystalline Si thin-film solar cells from the porous silicon (PSI) layer transfer for manufacturing high efficiency silicon thin-film solar cells. Industrially feasible epitaxy systems therefore

  19. Manufacture of silicon carbide using solar energy

    DOE Patents [OSTI]

    Glatzmaier, Gregory C. (Boulder, CO)

    1992-01-01

    A method is described for producing silicon carbide particles using solar energy. The method is efficient and avoids the need for use of electrical energy to heat the reactants. Finely divided silica and carbon are admixed and placed in a solar-heated reaction chamber for a time sufficient to cause a reaction between the ingredients to form silicon carbide of very small particle size. No grinding of silicon carbide is required to obtain small particles. The method may be carried out as a batch process or as a continuous process.

  20. High Efficiency, Low Cost Solar Cells Manufactured Using 'Silicon Ink' on Thin Crystalline Silicon Wafers

    SciTech Connect (OSTI)

    Antoniadis, H.

    2011-03-01

    Reported are the development and demonstration of a 17% efficient 25mm x 25mm crystalline Silicon solar cell and a 16% efficient 125mm x 125mm crystalline Silicon solar cell, both produced by Ink-jet printing Silicon Ink on a thin crystalline Silicon wafer. To achieve these objectives, processing approaches were developed to print the Silicon Ink in a predetermined pattern to form a high efficiency selective emitter, remove the solvents in the Silicon Ink and fuse the deposited particle Silicon films. Additionally, standard solar cell manufacturing equipment with slightly modified processes were used to complete the fabrication of the Silicon Ink high efficiency solar cells. Also reported are the development and demonstration of a 18.5% efficient 125mm x 125mm monocrystalline Silicon cell, and a 17% efficient 125mm x 125mm multicrystalline Silicon cell, by utilizing high throughput Ink-jet and screen printing technologies. To achieve these objectives, Innovalight developed new high throughput processing tools to print and fuse both p and n type particle Silicon Inks in a predetermined pat-tern applied either on the front or the back of the cell. Additionally, a customized Ink-jet and screen printing systems, coupled with customized substrate handling solution, customized printing algorithms, and a customized ink drying process, in combination with a purchased turn-key line, were used to complete the high efficiency solar cells. This development work delivered a process capable of high volume producing 18.5% efficient crystalline Silicon solar cells and enabled the Innovalight to commercialize its technology by the summer of 2010.

  1. Characterisation Studies of Silicon Photomultipliers

    E-Print Network [OSTI]

    Patrick Eckert; Hans-Christian Schultz-Coulon; Wei Shen; Rainer Stamen; Alexander Tadday

    2010-04-01

    This paper describes an experimental setup that has been developed to measure and characterise properties of Silicon Photomultipliers (SiPM). The measured SiPM properties are of general interest for a multitude of potential applications and comprise the Photon Detection Efficiency (PDE), the voltage dependent cross-talk and the after-pulse probabilities. With the described setup the absolute PDE can be determined as a function of wavelength covering a spectral range from 350 to 1000nm. In addition, a method is presented which allows to study the pixel uniformity in terms of the spatial variations of sensitivity and gain. The results from various commercially available SiPMs - three HAMAMATSU MPPCs and one SensL SPM - are presented and compared.

  2. Characterisation Studies of Silicon Photomultipliers

    E-Print Network [OSTI]

    Eckert, Patrick; Shen, Wei; Stamen, Rainer; Tadday, Alexander

    2010-01-01

    This paper describes an experimental setup that has been developed to measure and characterise properties of Silicon Photomultipliers (SiPM). The measured SiPM properties are of general interest for a multitude of potential applications and comprise the Photon Detection Efficiency (PDE), the voltage dependent cross-talk and the after-pulse probabilities. With the described setup the absolute PDE can be determined as a function of wavelength covering a spectral range from 350 to 1000nm. In addition, a method is presented which allows to study the pixel uniformity in terms of the spatial variations of sensitivity and gain. The results from various commercially available SiPMs - three HAMAMATSU MPPCs and one SensL SPM - are presented and compared.

  3. Optical absorption of silicon nanowires

    SciTech Connect (OSTI)

    Xu, T. [Key Laboratory of Advanced Display and System Application, Shanghai University, 149 Yanchang Road, Shanghai 200072 (China); Institut d'Electronique et de Microelectronique et de Nanotechnologies, IEMN (CNRS, UMR 8520), Groupe de Physique, Cite scientifique, avenue Poincare, 59652 Villeneuve d'Ascq (France); Lambert, Y.; Krzeminski, C.; Grandidier, B.; Stievenard, D.; Leveque, G.; Akjouj, A.; Pennec, Y.; Djafari-Rouhani, B. [Institut d'Electronique et de Microelectronique et de Nanotechnologies, IEMN (CNRS, UMR 8520), Groupe de Physique, Cite scientifique, avenue Poincare, 59652 Villeneuve d'Ascq (France)

    2012-08-01

    We report on simulations and measurements of the optical absorption of silicon nanowires (NWs) versus their diameter. We first address the simulation of the optical absorption based on two different theoretical methods: the first one, based on the Green function formalism, is useful to calculate the scattering and absorption properties of a single or a finite set of NWs. The second one, based on the finite difference time domain (FDTD) method, is well-adapted to deal with a periodic set of NWs. In both cases, an increase of the onset energy for the absorption is found with increasing diameter. Such effect is experimentally illustrated, when photoconductivity measurements are performed on single tapered Si nanowires connected between a set of several electrodes. An increase of the nanowire diameter reveals a spectral shift of the photocurrent intensity peak towards lower photon energies that allow to tune the absorption onset from the ultraviolet radiations to the visible light spectrum.

  4. FRICTION STIR SPOT WELDING OF 6016 ALUMINUM ALLOY

    SciTech Connect (OSTI)

    Mishra, Rajiv S.; Webb, S.; Freeney, T. A.; Chen, Y. L.; Gayden, X.; Grant, Glenn J.; Herling, Darrell R.

    2007-01-08

    Friction stir spot welding (FSSW) of 6016 aluminum alloy was evaluated with conventional pin tool and new off-center feature tools. The off-center feature tool provides significant control over the joint area. The tool rotation rate was varied between 1000 and 2500 rpm. Maximum failure strength was observed in the tool rotation range of 1200-1500 rpm. The results are interpreted in the context of material flow in the joint and influence of thermal input on microstructural changes. The off-center feature tool concept opens up new possibilities for plunge-type friction stir spot welding.

  5. The Pricing of Electricity to Aluminum Smelters in the Northwest 

    E-Print Network [OSTI]

    Foley, T. J.

    1986-01-01

    prompted Bonneville to search for Innovative pnClng schemes designed to maintain its revenue base Bonneville's proposed strategy Includes tYing the price of electricity it seilS to tne alumlr,u~ smelters to the world price of aluminum. This paper wili... examine Bonneville's proposed pnClng strategy; it will also examine other strategies to reduce uncertainty In the region's future electriC load. BACKGROUND For well over half a century, electrical power has been a cornerstone of the PaCific Northwest...

  6. Standard specification for nuclear-grade aluminum oxide pellets

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01

    1.1 This specification applies to pellets of aluminum oxide that may be ultimately used in a reactor core, for example, as filler or spacers within fuel, burnable poison, or control rods. In order to distinguish between the subject pellets and “burnable poison” pellets, it is established that the subject pellets are not intended to be used as neutron-absorbing material. 1.2 The values stated in inch-pound units are to be regarded as standard. The values given in parentheses are mathematical conversions to SI units that are provided for information only and are not considered standard.

  7. Sampling Artifacts from Conductive Silicone Tubing

    E-Print Network [OSTI]

    Timko, Michael T.

    2009-01-01

    the soot from the filter with water and collecting it in aof water placed on the “heated silicone tubing” filter (water drop placed on the “unheated stainless steel tubing” filter

  8. Femtosecond laser processing of crystalline silicon

    E-Print Network [OSTI]

    Tran, D. V.

    This paper reports the surface morphologies and ablation of crystalline silicon wafers irradiated by infra-red 775 nm Ti:sapphire femtosecond laser. The effects of energy fluences (below and above single-pulse modification) ...

  9. High index contrast platform for silicon photonics

    E-Print Network [OSTI]

    Akiyama, Shoji, 1972-

    2004-01-01

    This thesis focuses on silicon-based high index contrast (HIC) photonics. In addition to mature fiber optics or low index contrast (LIC) platform, which is often referred to as Planar Lightwave Cirrcuit (PLC) or Silica ...

  10. Texturization of multicrystalline silicon solar cells

    E-Print Network [OSTI]

    Li, Dai-Yin

    2010-01-01

    A significant efficiency gain for crystalline silicon solar cells can be achieved by surface texturization. This research was directed at developing a low-cost, high-throughput and reliable texturing method that can create ...

  11. Lithium ion batteries based on nanoporous silicon

    DOE Patents [OSTI]

    Tolbert, Sarah H.; Nemanick, Eric J.; Kang, Chris Byung-Hwa

    2015-09-22

    A lithium ion battery that incorporates an anode formed from a Group IV semiconductor material such as porous silicon is disclosed. The battery includes a cathode, and an anode comprising porous silicon. In some embodiments, the anode is present in the form of a nanowire, a film, or a powder, the porous silicon having a pore diameters within the range between 2 nm and 100 nm and an average wall thickness of within the range between 1 nm and 100 nm. The lithium ion battery further includes, in some embodiments, a non-aqueous lithium containing electrolyte. Lithium ion batteries incorporating a porous silicon anode demonstrate have high, stable lithium alloying capacity over many cycles.

  12. Method for silicon nitride precursor solids recovery

    DOE Patents [OSTI]

    Crosbie, Gary M. (Dearborn, MI); Predmesky, Ronald L. (Livonia, MI); Nicholson, John M. (Wayne, MI)

    1992-12-15

    Method and apparatus are provided for collecting reaction product solids entrained in a gaseous outflow from a reaction situs, wherein the gaseous outflow includes a condensable vapor. A condensate is formed of the condensable vapor on static mixer surfaces within a static mixer heat exchanger. The entrained reaction product solids are captured in the condensate which can be collected for further processing, such as return to the reaction situs. In production of silicon imide, optionally integrated into a production process for making silicon nitride caramic, wherein reactant feed gas comprising silicon halide and substantially inert carrier gas is reacted with liquid ammonia in a reaction vessel, silicon imide reaction product solids entrained in a gaseous outflow comprising residual carrier gas and vaporized ammonia can be captured by forming a condensate of the ammonia vapor on static mixer surfaces of a static mixer heat exchanger.

  13. Apparatus for silicon nitride precursor solids recovery

    DOE Patents [OSTI]

    Crosbie, Gary M. (Dearborn, MI); Predmesky, Ronald L. (Livonia, MI); Nicholson, John M. (Wayne, MI)

    1995-04-04

    Method and apparatus are provided for collecting reaction product solids entrained in a gaseous outflow from a reaction situs, wherein the gaseous outflow includes a condensable vapor. A condensate is formed of the condensable vapor on static mixer surfaces within a static mixer heat exchanger. The entrained reaction product solids are captured in the condensate which can be collected for further processing, such as return to the reaction situs. In production of silicon imide, optionally integrated into a production process for making silicon nitride caramic, wherein reactant feed gas comprising silicon halide and substantially inert carrier gas is reacted with liquid ammonia in a reaction vessel, silicon imide reaction product solids entrained in a gaseous outflow comprising residual carrier gas and vaporized ammonia can be captured by forming a condensate of the ammonia vapor on static mixer surfaces of a static mixer heat exchanger.

  14. Silicon nitride having a high tensile strength

    DOE Patents [OSTI]

    Pujari, V.K.; Tracey, D.M.; Foley, M.R.; Paille, N.I.; Pelletier, P.J.; Sales, L.C.; Willkens, C.A.; Yeckley, R.L.

    1998-06-02

    A ceramic body is disclosed comprising at least about 80 w/o silicon nitride and having a mean tensile strength of at least about 800 MPa. 4 figs.

  15. INTERNATIONAL CONFERENCE ON EXOTIC FORMS OF SILICON

    E-Print Network [OSTI]

    ` e INTERNATIONAL CONFERENCE ON EXOTIC FORMS OF SILICON Renewable Energy Materials Research Science Laboratory TOYOTA Central R&D Labs., Inc. Japan George S. Nolas Department of Physics University of South

  16. Silicon cast wafer recrystallization for photovoltaic applications

    E-Print Network [OSTI]

    Hantsoo, Eerik T. (Eerik Torm)

    2008-01-01

    Current industry-standard methods of manufacturing silicon wafers for photovoltaic (PV) cells define the electrical properties of the wafer in a first step, and then the geometry of the wafer in a subsequent step. The ...

  17. An ultralow power athermal silicon modulator

    E-Print Network [OSTI]

    Timurdogan, Erman

    Silicon photonics has emerged as the leading candidate for implementing ultralow power wavelength–division–multiplexed communication networks in high-performance computers, yet current components (lasers, modulators, filters ...

  18. Polycrystalline silicon resistor trimming by laser annealing 

    E-Print Network [OSTI]

    Crowley, Robert Terrence

    1989-01-01

    . ~ The single crystal band structure of silicon is applicable inside each grain. ~ Carrier trapping sites exist at the grain boundary with an area density of qq cm . These traps are filled with a density of n, cm ~ The traps are monovalent and located..., and (b) Kelvin resistors. luminum Top oxide Polysilicon Initial oxide ubstrate 26 Fig. 7. Cross sectional view of test cell. an oxidized silicon wafer. The polysilicon was oxidized for passivation, and contact windows were etched for the metal...

  19. Microtextured Silicon Surfaces for Detectors, Sensors & Photovoltaics

    SciTech Connect (OSTI)

    Carey, JE; Mazur, E

    2005-05-19

    With support from this award we studied a novel silicon microtexturing process and its application in silicon-based infrared photodetectors. By irradiating the surface of a silicon wafer with intense femtosecond laser pulses in the presence of certain gases or liquids, the originally shiny, flat surface is transformed into a dark array of microstructures. The resulting microtextured surface has near-unity absorption from near-ultraviolet to infrared wavelengths well below the band gap. The high, broad absorption of microtextured silicon could enable the production of silicon-based photodiodes for use as inexpensive, room-temperature multi-spectral photodetectors. Such detectors would find use in numerous applications including environmental sensors, solar energy, and infrared imaging. The goals of this study were to learn about microtextured surfaces and then develop and test prototype silicon detectors for the visible and infrared. We were extremely successful in achieving our goals. During the first two years of this award, we learned a great deal about how microtextured surfaces form and what leads to their remarkable optical properties. We used this knowledge to build prototype detectors with high sensitivity in both the visible and in the near-infrared. We obtained room-temperature responsivities as high as 100 A/W at 1064 nm, two orders of magnitude higher than standard silicon photodiodes. For wavelengths below the band gap, we obtained responsivities as high as 50 mA/W at 1330 nm and 35 mA/W at 1550 nm, close to the responsivity of InGaAs photodiodes and five orders of magnitude higher than silicon devices in this wavelength region.

  20. Electrical and mechanical studies of high purity aluminum single crystals at 4.2 K under cyclic strain 

    E-Print Network [OSTI]

    Zou, Hong

    1995-01-01

    The objective of this research is to investigate the effects of orientation on strain hardening and resistivity degradation in high purity aluminum single crystals resulting from uniaxial cyclic strain at 4.2 K. Aluminum crystals with various...

  1. Life-cycle energy savings potential from aluminum-intensive vehicles

    SciTech Connect (OSTI)

    Stodolsky, F.; Vyas, A.; Cuenca, R.; Gaines, L.

    1995-07-01

    The life-cycle energy and fuel-use impacts of US-produced aluminum-intensive passenger cars and passenger trucks are assessed. The energy analysis includes vehicle fuel consumption, material production energy, and recycling energy. A model that stimulates market dynamics was used to project aluminum-intensive vehicle market shares and national energy savings potential for the period between 2005 and 2030. We conclude that there is a net energy savings with the use of aluminum-intensive vehicles. Manufacturing costs must be reduced to achieve significant market penetration of aluminum-intensive vehicles. The petroleum energy saved from improved fuel efficiency offsets the additional energy needed to manufacture aluminum compared to steel. The energy needed to make aluminum can be reduced further if wrought aluminum is recycled back to wrought aluminum. We find that oil use is displaced by additional use of natural gas and nonfossil energy, but use of coal is lower. Many of the results are not necessarily applicable to vehicles built outside of the United States, but others could be used with caution.

  2. Study of Dislocation Densities Through the Thickness of 7050 Aluminum Cory Parker, David Field

    E-Print Network [OSTI]

    Collins, Gary S.

    Study of Dislocation Densities Through the Thickness of 7050 Aluminum Cory Parker, David Field WSU number DMR-1062898. Introduction 7050 Aluminum is a lightweight, yet strong, alloy primarily used rather difficult due to the presence of a wide range of particles in the substrate. 7050 goes through

  3. Screening Methods to Develop Alfalfa Germplasms Tolerant of Acid, Aluminum Toxic Soils

    E-Print Network [OSTI]

    Parrott, Wayne

    Screening Methods to Develop Alfalfa Germplasms Tolerant of Acid, Aluminum Toxic Soils M. Dall'Agnol, J. H. Bouton,* and W. A. Parrott ABSTRACT Soil acidity and aluminum (Al)toxicity are major problems different screening methods for selection of acid soil tolerant alfalfa germplasms in the greenhouse during

  4. Fracture response of externally flawed aluminum cylindrical shells under internal gaseous detonation loading

    E-Print Network [OSTI]

    Barr, Al

    Fracture response of externally flawed aluminum cylindrical shells under internal gaseous. Experiments were performed to observe the fracture behavior of thin- wall and initially-flawed aluminum tubes to different fracture events are analyzed. Keywords: tube fracture, detonation, crack branching, crack curving

  5. Anodic Aluminum Oxide Templated Channel Electrodes via Atomic Layer A. B. F. Martinsona,b

    E-Print Network [OSTI]

    Anodic Aluminum Oxide Templated Channel Electrodes via Atomic Layer Deposition A. B. F. Martinsona of transparent, semiconducting oxides via atomic layer deposition may allow for significantly faster charge aluminum oxide membranes via atomic layer deposition. Introduction Dye sensitized solar cells (DSSCs

  6. Comparative study of the growth of sputtered aluminum oxide films on organic and inorganic substrates

    E-Print Network [OSTI]

    Schreiber, Frank

    coatings as they are used, e.g., in gas-turbine engines [2]. Ultrathin and well-ordered aluminum oxide material aluminum oxide in inorganic and also organic heterostructures. Atomic force microscopy studies such as microelectronics, optics and coating technology. Because of its extraordinary mechanical, electrical, thermal

  7. A thermomechanical study of the effects of mold topography on the solidification of Aluminum alloys

    E-Print Network [OSTI]

    Zabaras, Nicholas J.

    1 A thermomechanical study of the effects of mold topography on the solidification of Aluminum-3801, USA A thermomechanical study of the effects of mold topography on the solidification of Aluminum alloys at early times is provided. The various coupling mechanisms between the solid-shell and mold

  8. Chemical Preparation of Aluminum Borate Whiskers I. Erkin GNENLI and A. Cneyt TAS

    E-Print Network [OSTI]

    Tas, A. Cuneyt

    of Metallurgical and Materials Engineering, Middle East Technical University, Ankara 06531, Turkey Aluminum borate Aluminum sulphate (Al2(SO4)3.18H2O, 99.9%, Riedel de-Haen, Seelze, Germany), boric acid (H3BO3: 99.9%, Riedel de-Haen, Germany) and potassium sulphate (K2SO4: 99.9%, Merck, Darmstadt, Germany) were accurately

  9. Interfacial charging phenomena of aluminum (hydr)oxides

    SciTech Connect (OSTI)

    Hiemstra, T.; Yong, H.; Van Riemsdijk, W.H.

    1999-08-31

    The interfacial charging of Al(OH){sub 3} (gibbsite and bayerite) and Al{sub 2}O{sub 3} has been studied. For Al(OH){sub 3} it can be shown that the very strong variation in charging behavior for different preparations is related to the relative presence of differently reacting crystal planes. The edge faces of the hexagonal gibbsite crystals are proton reactive over the whole pH range, in contrast to the 001 plane, which is mainly uncharged below pH = 10. On this 001 face only doubly coordinated surface groups are found, in contrast to the edges which also have singly coordinated surface groups. The results are fully in agreement with the predictions of the Multi site complexation (MUSIC) model. The proton adsorption, electrolyte ion adsorption, and shift of the IEP of gibbsite and aluminum oxide have been modeled simultaneously. For gibbsite, the ion pair formation of Na is larger than that of Cl, as is evidenced by modeling the experimentally observed upward shift on the IEP and charge reversal at high electrolyte concentrations. All these experimental results can be satisfactorily modeled with the MUSIC model, including the experimental surface potential of aluminum oxide (ISFET).

  10. Radiation tolerance of piezoelectric bulk single-crystal aluminum nitride

    SciTech Connect (OSTI)

    David A. Parks; Bernhard R. Tittmann

    2014-07-01

    For practical use in harsh radiation environments, we pose selection criteria for piezoelectric materials for nondestructive evaluation (NDE) and material characterization. Using these criteria, piezoelectric aluminum nitride is shown to be an excellent candidate. The results of tests on an aluminumnitride-based transducer operating in a nuclear reactor are also presented. We demonstrate the tolerance of single-crystal piezoelectric aluminum nitride after fast and thermal neutron fluences of 1.85 × 1018 neutron/cm2 and 5.8 × 1018 neutron/cm2, respectively, and a gamma dose of 26.8 MGy. The radiation hardness of AlN is most evident from the unaltered piezoelectric coefficient d33, which measured 5.5 pC/N after a fast and thermal neutron exposure in a nuclear reactor core for over 120 MWh, in agreement with the published literature value. The results offer potential for improving reactor safety and furthering the understanding of radiation effects on materials by enabling structural health monitoring and NDE in spite of the high levels of radiation and high temperatures, which are known to destroy typical commercial ultrasonic transducers.

  11. Metastable phases in mechanically alloyed aluminum germanium powders

    SciTech Connect (OSTI)

    Yvon, P.J.; Schwarz, R.B.

    1993-03-01

    Aluminum and germanium form a simple eutectic system with no stable intermetallic phase, and limited mutual solubility. We report the formation of a metastable rhombohedral,{gamma}{sub 1} phase by mechanically alloying aluminum and germanium powders. This phase, which appears for compositions between 20 and 50 at. % germanium, has also been observed in rapidly quenched alloys, but there is disagreement as to its composition. By measuring the heat of crystallization as a function of composition, we determined the composition of the {gamma}{sub 1} phase to be Al{sub 70}Ge{sub 30}. We also produced Al{sub 70}Ge{sub 30} by arc melting the pure elements, followed by splat-quenching at a cooling rate in the range of 10{sup 8} K s{sup {minus}1}. This method produced two metastable phases, one of which was found to be the {gamma}{sub 1} phase obtained by mechanical alloying. The other was a monoclinic phase reported earlier in the literature as {gamma}{sub 2}.

  12. Process for mitigating corrosion and increasing the conductivity of steel studs in soderberg anodes of aluminum reduction cells

    DOE Patents [OSTI]

    Oden, Laurance L. (Albany, OR); White, Jack C. (Albany, OR); Ramsey, James A. (The Dalles, OR)

    1994-01-01

    A corrosion resistant electrically conductive coating on steel anode studs used in the production of aluminum by electrolysis.

  13. Magnesium deficiency and type of protein during gestation and lactation in rats 

    E-Print Network [OSTI]

    Holmes, Kathryn Ellen Hughes

    1988-01-01

    those fed the CD diet, but only for one day (day 8). No physical changes were noted during week 1 of lactation. One dam from group CD exhibited bright pink ears and a slightly pink tail during week 2 of lactation, but these signs were not apparent... with deficient males produced smaller litters. Restricted diets during gestation and lactation in rats have also been shown to cause reduced serum and bone magnesium levels in dams and reduced viability and body weights of offspring (2). Ma nesium and Protein...

  14. MAGNESIUM OXIDE AN ENGINEERED BARRIER 2009 EPA WIPP RECERTIFICATION FACT SHEET United States Environmental Protection Agency | Office of Air and Radiation (6608J) | June 2009

    E-Print Network [OSTI]

    MAGNESIUM OXIDE ­ AN ENGINEERED BARRIER 2009 EPA WIPP RECERTIFICATION FACT SHEET United States Environmental Protection Agency | Office of Air and Radiation (6608J) | June 2009 http://www.epa.gov/radiation/wipp/index.html MAGNESIUM OXIDE ­ AN ENGINEERED BARRIER Why is MgO Used At WIPP? The U.S. Department of Energy (DOE

  15. Methods and apparatus for manufacturing monocrystalline cast silicon and monocrystalline cast silicon bodies for photovoltaics

    DOE Patents [OSTI]

    Stoddard, Nathan G

    2014-01-14

    Methods and apparatuses are provided for casting silicon for photovoltaic cells and other applications. With such methods and apparatuses, a cast body of monocrystalline silicon may be formed that is free of, or substantially free of, radially-distributed impurities and defects and having at least two dimensions that are each at least about 35 cm is provided.

  16. CHARGE STABILITY IN LPCVD SILICON NITRIDE FOR SURFACE PASSIVATION OF SILICON SOLAR CELLS

    E-Print Network [OSTI]

    to be mainly concentrated at the oxide/nitride interface. The thermal stability of the charge is shown silicon nitride layers can lead to a significant improvement in surface recombination at lightly doped of a tunnel oxide, a silicon nitride layer and optionally, a barrier oxide or other dielectric material. As

  17. Combustion Synthesis of Silicon Carbide 389 Combustion Synthesis of Silicon Carbide

    E-Print Network [OSTI]

    Mukasyan, Alexander

    Combustion Synthesis of Silicon Carbide 389 X Combustion Synthesis of Silicon Carbide Alexander S. Mukasyan University of Notre Dame USA 1. Introduction Combustion synthesis (CS) is an effective technique by which combustion synthesis can occur: self - propagating high-temperature synthesis (SHS) and volume

  18. Methods and apparatuses for manufacturing monocrystalline cast silicon and monocrystalline cast silicon bodies for photovoltaics

    DOE Patents [OSTI]

    Stoddard, Nathan G. (Gettysburg, PA)

    2011-11-01

    Methods and apparatuses are provided for casting silicon for photovoltaic cells and other applications. With such methods and apparatuses, a cast body of monocrystalline silicon may be formed that is free of, or substantially free of, radially-distributed impurities and defects and having at least two dimensions that are each at least about 35 cm is provided.

  19. Polycrystalline Silicon Solar Cells Fabricated by Pulsed Rapid Thermal Annealing of Amorphous Silicon 

    E-Print Network [OSTI]

    Lee, I-Syuan

    2014-05-07

    effect were also investigated. It has been demonstrated that a 30 nm thick amorphous silicon could be transformed into polycrystalline with 70%-80% of crystalline volume fraction in a short time. The thin-film polycrystalline silicon solar cells were...

  20. BACK CONTACT MONOCRYSTALLINE THIN-FILM SILICON SOLAR CELLS FROM THE POROUS SILICON PROCESS

    E-Print Network [OSTI]

    BACK CONTACT MONOCRYSTALLINE THIN-FILM SILICON SOLAR CELLS FROM THE POROUS SILICON PROCESS F. Haase contact cells. Kraiem et al [7] made a back contact thin film monocrystalline solar cell with cell), Am Ohrberg 1, D-31860 Emmerthal, Germany ABSTRACT We develop a back contact monocrystalline thin-film

  1. Anti-reflection zinc oxide nanocones for higher efficiency thin-film silicon solar cells

    E-Print Network [OSTI]

    Mailoa, Jonathan P

    2012-01-01

    Thin film silicon solar cells, which are commonly made from microcrystalline silicon ([mu]c-Si) or amorphous silicon (a-Si), have been considered inexpensive alternatives to thick polycrystalline silicon (polysilicon) solar ...

  2. Metallic coatings on silicon substrates, and methods of forming metallic coatings on silicon substrates

    DOE Patents [OSTI]

    Branagan, Daniel J. (Idaho Falls, ID); Hyde, Timothy A. (Idaho Falls, ID); Fincke, James R. (Los Alamos, NM)

    2008-03-11

    The invention includes methods of forming a metallic coating on a substrate which contains silicon. A metallic glass layer is formed over a silicon surface of the substrate. The invention includes methods of protecting a silicon substrate. The substrate is provided within a deposition chamber along with a deposition target. Material from the deposition target is deposited over at least a portion of the silicon substrate to form a protective layer or structure which contains metallic glass. The metallic glass comprises iron and one or more of B, Si, P and C. The invention includes structures which have a substrate containing silicon and a metallic layer over the substrate. The metallic layer contains less than or equal to about 2 weight % carbon and has a hardness of at least 9.2 GPa. The metallic layer can have an amorphous microstructure or can be devitrified to have a nanocrystalline microstructure.

  3. Silicon-based nanoenergetic composites

    SciTech Connect (OSTI)

    Asay, Blaine; Son, Steven; Mason, Aaron; Yarrington, Cole; Cho, K Y; Gesner, J; Yetter, R A

    2009-01-01

    Fundamental combustion properties of silicon-based nano-energetic composites was studied by performing equilibrium calculations, 'flame tests', and instrumented burn-tube tests. That the nominal maximum flame temperature and for many Si-oxidizer systems is about 3000 K, with exceptions. Some of these exceptions are Si-metal oxides with temperatures ranging from 2282 to 2978 K. Theoretical maximum gas production of the Si composites ranged from 350-6500 cm{sup 3}/g of reactant with NH{sub 4}ClO{sub 4} - Si producing the most gas at 6500 cm{sup 3}/g and Fe{sub 2}O{sub 3} producing the least. Of the composites tested NH{sub 4}ClO{sub 4} - Si showed the fastest burning rates with the fastest at 2.1 km/s. The Si metal oxide burning rates where on the order of 0.03-75 mls the slowest of which was nFe{sub 2}O{sub 3} - Si.

  4. Effect of dietary magnesium and calcium on blood lipids and minerals in tissues in rats fed a high fat diet 

    E-Print Network [OSTI]

    Conboy-Downs, Jean

    1991-01-01

    EFFECT OF DIETARY MAGNESIUM AND CALCIUM ON BLOOD LIPIDS AND MINERALS ZN TISSUES IN BATS FED A HIGH FAT DIET A Thesis by JEAN CONBOY-DONNS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 1991 Major Subject: Nutrition EFFECT OF DIETARY MAGNESIUM AND CALCIUM ON BLOOD LIPZDS AND MZNERALS ZN TISSUES IN RATS FED A BIGS FAT DIET A Thesis by JEAN CONBOY-DOWNS Approved as to style...

  5. The effects of a marginal intake of magnesium with soy protein concentrate on growth, gestation, and lactation in the rat 

    E-Print Network [OSTI]

    McLaughlin, Cynthia Anne

    1986-01-01

    THE EFFECTS OF A MARGINAL INTAKE OF MAGNESIUM WITH SOY PROTEIN CONCENTRATE ON GROWTH, GESTATION, AND LACTATION IN THE RAT A Thesis by CYNTHIA ANNE MCLAUGHLIN Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 19B6 Major Subject: Nutrrtion THE EFFECTS OF A MARGINAL INTAKE OF MAGNESIUM WITH SOY PROTEIN CONCENTRATE ON GROWTH, GESTATION, AND LACTATION IN THE RAT A Thesis by CYNTHIA ANNE MCLAUGHLIN Approved...

  6. The effect of a prolonged magnesium restriction on the humoral immune response in maternal rats and their offspring 

    E-Print Network [OSTI]

    Cohill, Diane T

    1987-01-01

    TIIE EFFECT 0F A PR0L0NGED MAGNESIUM RESTRI CTI0N ON THE HUMORAL IMMUNE RESPONSE IN HATERHAL RATS AHD THEIR OFFSPRING A Thesis by DIANE T. COHILL Submitted to the Graduate College of Texas ASM University in Partial fulfillment... of the requirements for the degree of MASTER OF SC IENCE May 1987 Major Subject: Nutrition THE EFFECT OF A PROLONGED MAGNESIUM RESTRICTION ON THE HUMORAL IMMUNE RESPONSE IN MATERNAL RATS AND THEIR OFFSPRING A Thesis by DIANE T. COHILL Approved as to sty le...

  7. Synthesis, deposition and characterization of magnesium hydroxide nanostructures on zeolite 4A

    SciTech Connect (OSTI)

    Koh, Pei-Yoong; Yan, Jing; Ward, Jason; Koros, William J.; Teja, Amyn S.; Xu, Bo

    2011-03-15

    Research highlights: {yields} Reports a simple precipitation-growth method to produce nanostructures of Mg(OH){sub 2} on the surface of zeolite 4A. {yields} Able to control the growth of the nanostructures by manipulating the experimental procedure. {yields} Able to deposit Mg(OH){sub 2} onto specific sites namely bridging hydroxyl protons (SiOHAl) on the surface of zeolite 4A. -- Abstract: The precipitation and self-assembly of magnesium hydroxide Mg(OH){sub 2} nanopetals on dispersed zeolite 4A particles was investigated. Mg(OH){sub 2}/zeolite nanocomposites were produced from magnesium chloride solutions and characterized via X-ray powder diffraction (XRD), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), Fourier transform infrared analysis (FTIR), and solid state NMR. It was determined that Mg(OH){sub 2} interacted with bridging hydroxyl protons (SiOHAl) on the zeolite surface, but not with silanol or aluminol groups. NMR analysis showed that 13% of the tetrahedral Al sites on the zeolite were converted to octahedral Al. The zeolite structure and crystallinity remained intact after treatment, and no dealumination reactions were detected. This suggests that the deposition-precipitation process at ambient conditions is a facile method for controlling Mg(OH){sub 2} nanostructures on zeolites.

  8. Manufacture of gradient micro-structures of magnesium alloys using two stage extrusion dies

    SciTech Connect (OSTI)

    Hwang, Yeong-Maw; Huang, Tze-Hui [Department of Mechanical and Electro-Mechanical Engineering, National Sun Yat-Sen University, No. 70, Lien-Hai Rd., Kaohsiung, 804, Taiwan (China); Alexandrov, Sergei [Institute for Problems in Mechanics, Russian Academy of Sciences, Moscow (Russian Federation); Naimark, Oleg Borisovich [Institute of Continuous Media Mechanics, Russian Academy of Sciences, Perm (Russian Federation); Jeng, Yeau-Ren [Department of Mechanical Engineering and Advanced Institute of Manufacturing with High-tech Innovations, National Chung Cheng University, Ming-Hsiung, Chia-Yi 621, Taiwan (China)

    2013-12-16

    This paper aims to manufacture magnesium alloy metals with gradient micro-structures using hot extrusion process. The extrusion die was designed to have a straight channel part combined with a conical part. Materials pushed through this specially-designed die generate a non-uniform velocity distribution at cross sections inside the die and result in different strain and strain rate distributions. Accordingly, a gradient microstructure product can be obtained. Using the finite element analysis, the forming temperature, effective strain, and effective strain rate distributions at the die exit were firstly discussed for various inclination angles in the conical die. Then, hot extrusion experiments with a two stage die were conducted to obtain magnesium alloy products with gradient micro-structures. The effects of the inclination angle on the grain size distribution at cross sections of the products were also discussed. Using a die of an inclination angle of 15°, gradient micro-structures of the grain size decreasing gradually from 17 ?m at the center to 4 ?m at the edge of product were achieved.

  9. Optimization of transparent and reflecting electrodes for amorphous silicon solar cells. Annual subcontract report, April 1, 1994--March 31, 1995

    SciTech Connect (OSTI)

    Gordon, R.G.

    1995-10-01

    Transparent and reflecting electrodes are important parts of the structure of amorphous silicon solar cells. We report improved methods for depositing zinc oxide, deposition of tin nitride as a potential reflection-enhancing diffusion barrier between the a-Si and back metal electrodes. Highly conductive and transparent fluorine-doped zinc oxide was successfully produced on small areas by atmospheric pressure CVD from a less hazardous zinc precursor, zinc acetylacetonate. The optical properties measured for tin nitride showed that the back-reflection would be decreased if tin nitride were used instead of zinc oxide as a barrier layer over silver on aluminum. Niobium-doped titanium dioxide was produced with high enough electrical conductivity so that normal voltages and fill factors were obtained for a-Si cells made on it.

  10. Method of manufacturing a niobium-aluminum-germanium superconductive material

    DOE Patents [OSTI]

    Wang, John L. (San Francisco, CA); Pickus, Milton R. (Oakland, CA); Douglas, Kent E. (Redondo Beach, CA)

    1980-01-01

    A method for manufacturing flexible Nb.sub.3 (Al,Ge) multifilamentary superconductive material in which a sintered porous niobium compact is infiltrated with an aluminum-germanium alloy and thereafter deformed and heat treated in a series of steps at different successively higher temperatures preferably below 1000.degree. C. to produce filaments composed of Nb.sub.3 (Al,G3) within the compact. By avoiding temperatures in excess of 1000.degree. C. during the heat treatment, cladding material such as copper can be applied to facilitate a deformation step preceding the heat treatment and can remain in place through the heat treatment to also serve as a temperature stabilizer for supeconductive material produced. Further, these lower heat treatment temperatures favor formation of filaments with reduced grain size and, hence with more grain boundaries which in turn increase the current-carrying capacity of the superconductive material.

  11. TEST RESULTS FROM GAMMA IRRADIATION OF ALUMINUM OXYHYDROXIDES

    SciTech Connect (OSTI)

    Fisher, D.; Westbrook, M.; Sindelar, R.

    2012-02-01

    Hydrated metal oxides or oxyhydroxides boehmite and gibbsite that can form on spent aluminum-clad nuclear fuel assemblies during in-core and post-discharge wet storage were exposed as granular powders to gamma irradiation in a {sup 60}Co irradiator in closed laboratory test vessels with air and with argon as separate cover gases. The results show that boehmite readily evolves hydrogen with exposure up to a dose of 1.8 x 10{sup 8} rad, the maximum tested, in both a full-dried and moist condition of the powder, whereas only a very small measurable quantity of hydrogen was generated from the granular powder of gibbsite. Specific information on the test setup, sample characteristics, sample preparation, irradiation, and gas analysis are described.

  12. Structure of stagnated plasma in aluminum wire array Z pinches

    SciTech Connect (OSTI)

    Hall, G. N.; Pikuz, S. A.; Shelkovenko, T. A.; Bland, S. N.; Lebedev, S. V.; Ampleford, D. J.; Palmer, J. B. A.; Bott, S. C.; Rapley, J.; Chittenden, J. P.; Apruzese, J. P.

    2006-08-15

    Experiments with aluminum wire array Z pinches have been carried out on the mega-ampere generator for plasma implosion experiments (MAGPIE) at Imperial College London [I. H. Mitchell et al., Rev. Sci. Instrum. 67, 1533 (1996)]. It has been shown that in these arrays, there are two intense sources of radiation during stagnation; Al XII line emission from a precursor-sized object, and both continuum and Al XIII radiation from bright spots of either significantly higher temperature or density randomly distributed around this object so as to produce a hollow emission profile. Spatially resolved spectra produced by spherically bent crystals were recorded, both time-integrated and time-resolved, and were used to show that these two sources of radiation peak at the same time.

  13. Development Program for Natural Aging Aluminum Casting Alloys

    SciTech Connect (OSTI)

    Dr. Geoffrey K. Sigworth

    2004-05-14

    A number of 7xx aluminum casting alloys are based on the ternary Al-Zn-Mg system. These alloys age naturally to high strength at room temperature. A high temperature solution and aging treatment is not required. Consequently, these alloys have the potential to deliver properties nearly equivalent to conventional A356-T6 (Al-Si-Mg) castings, with a significant cost saving. An energy savings is also possible. In spite of these advantages, the 7xx casting alloys are seldom used, primarily because of their reputation for poor castibility. This paper describes the results obtained in a DOE-funded research study of these alloys, which is part of the DOE-OIT ''Cast Metals Industries of the Future'' Program. Suggestions for possible commercial use are also given.

  14. Formability Prediction Of Aluminum Sheet In Automotive Applications

    SciTech Connect (OSTI)

    Leppin, Christian; Daniel, Dominique; Shahani, Ravi; Gese, Helmut; Dell, Harry

    2007-05-17

    In the following paper, a full mechanical characterization of the AA6016 T4 aluminum alloy car body sheet DR100 is presented. A comprehensive experimental program was performed to identify and model the orthotopic elasto-plastic deformation behavior of the material and its fracture characteristics including criteria for localized necking, ductile fracture and shear fracture. The commercial software package MF GenYld + CrachFEM in combination with the explicit finite element code Ls-Dyna is used to validate the quality of the material model with experiments, namely, prediction of the FLD, deep drawing with a cross-shaped punch and finally, analysis of a simplified hemming process using a solid discretization of the problem. The focus is on the correct prediction of the limits of the material in such processes.

  15. Single-crystalline aluminum film for ultraviolet plasmonic nanolasers

    E-Print Network [OSTI]

    Chou, Bo-Tsun; Wu, Yen-Mo; Chung, Yi-Chen; Hsueh, Wei-Jen; Lin, Shih-Wei; Lu, Tien-Chang; Lin, Tzy-Rong; Lin, Sheng-Di

    2015-01-01

    Plasmonic devices have advanced significantly in the past decade. Being one of the most intriguing devices, plamonic nanolasers plays an important role in biomedicine, chemical sensor, information technology, and optical integrated circuits. However, nanoscale plasmonic devices, particularly in ultraviolet regime, are extremely sensitive to metal and interface quality, which renders the development of ultraviolet plasmonics. Here, by addressing the material issues, we demonstrate a low threshold, high characteristic temperature metal-oxide-semiconductor ZnO nanolaser working at room temperature. The template for ZnO nanowires consists of a flat single-crystalline aluminum film grown by molecular beam epitaxy and an ultra-smooth Al2O3 spacer layer prepared by atomic layer deposition. By effectively reducing surface plasmon scattering loss and metal intrinsic absorption loss, the high-quality metal film and sharp interfaces between layers boost the device performance. Our work paves the way for future applicati...

  16. Advanced manufacturing by spray forming: Aluminum strip and microelectromechanical systems

    SciTech Connect (OSTI)

    McHugh, K.M.

    1994-12-31

    Spray forming is an advanced materials processing technology that converts a bulk liquid metal to a near-net-shape solid by depositing atomized droplets onto a suitably shaped substrate. By combining rapid solidification processing with product shape control, spray forming can reduce manufacturing costs while improving product quality. INEL is developing a unique spray-forming method based on de Laval (converging/diverging) nozzle designs to produce near-net-shape solids and coatings of metals, polymers, and composite materials. Properties of the spray-formed material are tailored by controlling the characteristics of the spray plume and substrate. Two examples are described: high-volume production of aluminum alloy strip, and the replication of micron-scale features in micropatterned polymers during the production of microelectromechanical systems.

  17. Laser assisted high entropy alloy coating on aluminum: Microstructural evolution

    SciTech Connect (OSTI)

    Katakam, Shravana; Joshi, Sameehan S.; Mridha, Sanghita; Mukherjee, Sundeep; Dahotre, Narendra B.

    2014-09-14

    High entropy alloy (Al-Fe-Co-Cr-Ni) coatings were synthesized using laser surface engineering on aluminum substrate. Electron diffraction analysis confirmed the formation of solid solution of body centered cubic high entropy alloy phase along with phases with long range periodic structures within the coating. Evolution of such type of microstructure was a result of kinetics associated with laser process, which generates higher temperatures and rapid cooling resulting in retention of high entropy alloy phase followed by reheating and/or annealing in subsequent passes of the laser track giving rise to partial decomposition. The partial decomposition resulted in formation of precipitates having layered morphology with a mixture of high entropy alloy rich phases, compounds, and long range ordered phases.

  18. Amorphous silicon detectors in positron emission tomography

    SciTech Connect (OSTI)

    Conti, M. (Istituto Nazionale di Fisica Nucleare, Pisa (Italy) Lawrence Berkeley Lab., CA (USA)); Perez-Mendez, V. (Lawrence Berkeley Lab., CA (USA))

    1989-12-01

    The physics of the detection process is studied and the performances of different Positron Emission Tomography (PET) system are evaluated by theoretical calculation and/or Monte Carlo Simulation (using the EGS code) in this paper, whose table of contents can be summarized as follows: a brief introduction to amorphous silicon detectors and some useful equation is presented; a Tantalum/Amorphous Silicon PET project is studied and the efficiency of the systems is studied by Monte Carlo Simulation; two similar CsI/Amorphous Silicon PET projects are presented and their efficiency and spatial resolution are studied by Monte Carlo Simulation, light yield and time characteristics of the scintillation light are discussed for different scintillators; some experimental result on light yield measurements are presented; a Xenon/Amorphous Silicon PET is presented, the physical mechanism of scintillation in Xenon is explained, a theoretical estimation of total light yield in Xenon and the resulting efficiency is discussed altogether with some consideration of the time resolution of the system; the amorphous silicon integrated electronics is presented, total noise and time resolution are evaluated in each of our applications; the merit parameters {epsilon}{sup 2}{tau}'s are evaluated and compared with other PET systems and conclusions are drawn; and a complete reference list for Xenon scintillation light physics and its applications is presented altogether with the listing of the developed simulation programs.

  19. Silicon ball grid array chip carrier

    DOE Patents [OSTI]

    Palmer, David W. (Albuquerque, NM); Gassman, Richard A. (Greensboro, NC); Chu, Dahwey (Albuquerque, NM)

    2000-01-01

    A ball-grid-array integrated circuit (IC) chip carrier formed from a silicon substrate is disclosed. The silicon ball-grid-array chip carrier is of particular use with ICs having peripheral bond pads which can be reconfigured to a ball-grid-array. The use of a semiconductor substrate such as silicon for forming the ball-grid-array chip carrier allows the chip carrier to be fabricated on an IC process line with, at least in part, standard IC processes. Additionally, the silicon chip carrier can include components such as transistors, resistors, capacitors, inductors and sensors to form a "smart" chip carrier which can provide added functionality and testability to one or more ICs mounted on the chip carrier. Types of functionality that can be provided on the "smart" chip carrier include boundary-scan cells, built-in test structures, signal conditioning circuitry, power conditioning circuitry, and a reconfiguration capability. The "smart" chip carrier can also be used to form specialized or application-specific ICs (ASICs) from conventional ICs. Types of sensors that can be included on the silicon ball-grid-array chip carrier include temperature sensors, pressure sensors, stress sensors, inertia or acceleration sensors, and/or chemical sensors. These sensors can be fabricated by IC processes and can include microelectromechanical (MEM) devices.

  20. Aluminum Leaching of ''Archived'' Sludge from Tanks 8F, 11H, and 12H

    SciTech Connect (OSTI)

    FONDEUR, FERNANDOF.

    2004-03-12

    Aluminum can promote formation or dissolution of networks in hydroxide solid solutions. When present in large amounts it will act as a network former increasing both the viscosity and the surface tension of melts. This translates into poor free flow properties that affect pour rate of glass production in the Defense Waste Processing Facility (DWPF). To mitigate this situation, DWPF operations limit the amount of aluminum contained in sludge. This study investigated the leaching of aluminum compounds from archived sludge samples. The conclusions found boehmite present as the predominant aluminum compound in sludge from two tanks. We did not identify an aluminum compound in sludge from the third tank. We did not detect any amorphous aluminum hydroxide in the samples. The amount of goethite measured 4.2 percentage weight while hematite measured 3.7 percentage weight in Tank 11H sludge. The recommended recipe for removing gibbsite in sludge proved inefficient for digesting boehmite, removing less than 50 per cent of the compound within 48 hours. The recipe did remove boehmite when the test ran for 10 days (i.e., 7 more days than the recommended baseline leaching period). Additions of fluoride and phosphate to Tank 12H archived sludge did not improve the aluminum leaching efficiency of the baseline recipe.

  1. Iron-oxide catalyzed silicon photoanode for water splitting

    E-Print Network [OSTI]

    Jun, Kimin

    2011-01-01

    This thesis presents an integrated study of high efficiency photoanodes for water splitting using silicon and iron-oxide. The fundamental limitations of silicon to water splitting applications were overcome by an ultrathin ...

  2. Sputtered silicon oxynitride for microphotonics : a materials study

    E-Print Network [OSTI]

    Sandland, Jessica Gene, 1977-

    2005-01-01

    Silicon oxynitride (SiON) is an ideal waveguide material because the SiON materials system provides substantial flexibility in composition and refractive index. SiON can be varied in index from that of silicon dioxide ...

  3. Flaw-limited transport in germanium-on-silicon photodiodes

    E-Print Network [OSTI]

    Orcutt, Jason S. (Jason Scott)

    2008-01-01

    Epitaxial germanium growth on silicon substrates has enabled a new class of photodiodes that can be integrated with traditional silicon electronics. Previous workers using lowthroughput growth techniques have demonstrated ...

  4. Harmful Shunting Mechanisms Found in Silicon Solar Cells (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-05-01

    Scientists developed near-field optical microscopy for imaging electrical breakdown in solar cells and identified critical electrical breakdown mechanisms operating in industrial silicon and epitaxial silicon solar cells.

  5. And the Award Goes to... Silicon Ink Solar Technology Supported...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    And the Award Goes to... Silicon Ink Solar Technology Supported by SunShot's PV Incubator And the Award Goes to... Silicon Ink Solar Technology Supported by SunShot's PV Incubator...

  6. NREL: Technology Transfer - The Quest for Inexpensive Silicon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Quest for Inexpensive Silicon Solar Cells Get the Adobe Flash Player to see this video. In this video, NREL scientists Howard Branz and Chaz Teplin talk more about the silicon...

  7. Direct-Write of Silicon and Germanium Nanostructures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    using photoemission electron microscopes at ALS Beamlines 7.3.1 and 11.0.1. From Sand to Processor Modern electronic integrated circuits are made of silicon. Silicon is the...

  8. Process for manufacture of semipermeable silicon nitride membranes

    DOE Patents [OSTI]

    Galambos, Paul Charles; Shul, Randy J.; Willison, Christi Gober

    2003-12-09

    A new class of semipermeable membranes, and techniques for their fabrication, have been developed. These membranes, formed by appropriate etching of a deposited silicon nitride layer, are robust, easily manufacturable, and compatible with a wide range of silicon micromachining techniques.

  9. Deposition method for producing silicon carbide high-temperature semiconductors

    DOE Patents [OSTI]

    Hsu, George C. (La Crescenta, CA); Rohatgi, Naresh K. (W. Corine, CA)

    1987-01-01

    An improved deposition method for producing silicon carbide high-temperature semiconductor material comprising placing a semiconductor substrate composed of silicon carbide in a fluidized bed silicon carbide deposition reactor, fluidizing the bed particles by hydrogen gas in a mildly bubbling mode through a gas distributor and heating the substrate at temperatures around 1200.degree.-1500.degree. C. thereby depositing a layer of silicon carbide on the semiconductor substrate.

  10. Porous silicon membranes as ultrafiltration devices: a feasibility study 

    E-Print Network [OSTI]

    Hong, Xiangrong

    1993-01-01

    in the integrated circuits. According to research results, porous silicon layers are formed by local dissolution of silicon during anodization in hydrofluoric acid solution. Memming and Schwandt (1966) proposed the following model for the etching process... results in the formation of the etched pores. Beale (1984) investigated the microstructure of porous silicon using cross-sectional transmission electron microscopy. The studies show that the structure of porous silicon is not perfectly cylindrical...

  11. Efficiency of silicon solar cells containing chromium

    DOE Patents [OSTI]

    Frosch, Robert A. Administrator of the National Aeronautics and Space (New Port Beach, CA); Salama, Amal M. (New Port Beach, CA)

    1982-01-01

    Efficiency of silicon solar cells containing about 10.sup.15 atoms/cm.sup.3 of chromium is improved about 26% by thermal annealing of the silicon wafer at a temperature of 200.degree. C. to form chromium precipitates having a diameter of less than 1 Angstrom. Further improvement in efficiency is achieved by scribing laser lines onto the back surface of the wafer at a spacing of at least 0.5 mm and at a depth of less than 13 micrometers to preferentially precipitate chromium near the back surface and away from the junction region of the device. This provides an economical way to improve the deleterious effects of chromium, one of the impurities present in metallurgical grade silicon material.

  12. Electrically tunable hot-silicon terahertz attenuator

    SciTech Connect (OSTI)

    Wang, Minjie; Vajtai, Robert; Ajayan, Pulickel M.; Kono, Junichiro

    2014-10-06

    We have developed a continuously tunable, broadband terahertz attenuator with a transmission tuning range greater than 10{sup 3}. Attenuation tuning is achieved electrically, by simply changing the DC voltage applied to a heating wire attached to a bulk silicon wafer, which controls its temperature between room temperature and ?550?K, with the corresponding free-carrier density adjusted between ?10{sup 11?}cm{sup ?3} and ?10{sup 17?}cm{sup ?3}. This “hot-silicon”-based terahertz attenuator works most effectively at 450–550?K (corresponding to a DC voltage variation of only ?7?V) and completely shields terahertz radiation above 550?K in a frequency range of 0.1–2.5 THz. Both intrinsic and doped silicon wafers were tested and demonstrated to work well as a continuously tunable attenuator. All behaviors can be understood quantitatively via the free-carrier Drude model taking into account thermally activated intrinsic carriers.

  13. Comparing Laser Welding Technologies with Friction Stir Welding for Production of Aluminum Tailor-Welded Blanks

    SciTech Connect (OSTI)

    Hovanski, Yuri; Carsley, John; Carlson, Blair; Hartfield-Wunsch, Susan; Pilli, Siva Prasad

    2014-01-15

    A comparison of welding techniques was performed to determine the most effective method for producing aluminum tailor-welded blanks for high volume automotive applications. Aluminum sheet was joined with an emphasis on post weld formability, surface quality and weld speed. Comparative results from several laser based welding techniques along with friction stir welding are presented. The results of this study demonstrate a quantitative comparison of weld methodologies in preparing tailor-welded aluminum stampings for high volume production in the automotive industry. Evaluation of nearly a dozen welding variations ultimately led to down selecting a single process based on post-weld quality and performance.

  14. Enhanced structural color generation in aluminum metamaterials coated with a thin polymer layer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cheng, Fei; Yang, Xiaodong; Rosenmann, Daniel; Stan, Liliana; Czaplewski, David; Gao, Jie

    2015-09-18

    A high-resolution and angle-insensitive structural color generation platform is demonstrated based on triple-layer aluminum-silica-aluminum metamaterials supporting surface plasmon resonances tunable across the entire visible spectrum. The color performances of the fabricated aluminum metamaterials can be strongly enhanced by coating a thin transparent polymer layer on top. The results show that the presence of the polymer layer induces a better impedance matching for the plasmonic resonances to the free space so that strong light absorption can be obtained, leading to the generation of pure colors in cyan, magenta, yellow and black (CMYK) with high color saturation.

  15. Salt-soda sinter process for recovering aluminum from fly ash

    DOE Patents [OSTI]

    McDowell, William J. (Oak Ridge, TN); Seeley, Forest G. (Oak Ridge, TN)

    1981-01-01

    A method for recovering aluminum values from fly ash comprises sintering the fly ash with a mixture of NaCl and Na.sub.2 CO.sub.3 to a temperature in the range 700.degree.-900.degree. C. for a period of time sufficient to convert greater than 90% of the aluminum content of the fly ash into an acid-soluble fraction and then contacting the thus-treated fraction with an aqueous solution of nitric or sulfuric acid to effect dissolution of aluminum and other metal values in said solution.

  16. Molybdenum enhanced low-temperature deposition of crystalline silicon nitride

    DOE Patents [OSTI]

    Lowden, Richard A. (Powell, TN)

    1994-01-01

    A process for chemical vapor deposition of crystalline silicon nitride which comprises the steps of: introducing a mixture of a silicon source, a molybdenum source, a nitrogen source, and a hydrogen source into a vessel containing a suitable substrate; and thermally decomposing the mixture to deposit onto the substrate a coating comprising crystalline silicon nitride containing a dispersion of molybdenum silicide.

  17. ARC Centre of Excellence for Advanced Silicon Photovoltaics

    E-Print Network [OSTI]

    New South Wales, University of

    ARC Centre of Excellence for Advanced Silicon Photovoltaics and Photonics Annual Report 2005 ARC Centre of Excellence for Advanced Silicon Photovoltaics and Photonics Annual Report 2005 #12;Centre of Excellence for Advanced Silicon Photovoltaics and Photonics is a Centre of Excellence of The Australian

  18. Silicon nitride ceramic having high fatigue life and high toughness

    DOE Patents [OSTI]

    Yeckley, Russell L. (Oakham, MA)

    1996-01-01

    A sintered silicon nitride ceramic comprising between about 0.6 mol % and about 3.2 mol % rare earth as rare earth oxide, and between about 85 w/o and about 95 w/o beta silicon nitride grains, wherein at least about 20% of the beta silicon nitride grains have a thickness of greater than about 1 micron.

  19. Neutron and X-ray diffraction and empirical potential structure refinement modelling of magnesium stabilised amorphous calcium

    E-Print Network [OSTI]

    Benning, Liane G.

    Neutron and X-ray diffraction and empirical potential structure refinement modelling of magnesium online xxxx Keywords: Amorphous calcium carbonate; EPSR modelling; Neutron diffraction; X-ray diffraction Amorphous calcium carbonate (ACC) plays a key role in biomineralisation processes in sea organisms. Neutron

  20. In Situ Measurement of Magnesium Carbonate Formation from CO2 Using Static High-Pressure and -Temperature 13

    E-Print Network [OSTI]

    Skemer, Philip

    method that possesses the ability to monitor the chemical evolution of supercritical CO2 in relevant(OH)2, with supercritical CO2 (88 bar) in aqueous conditions at 80 °C. The in situ conversion of CO2In Situ Measurement of Magnesium Carbonate Formation from CO2 Using Static High