Sample records for magnesium aluminum silicon

  1. Electrodeposition of magnesium and magnesium/aluminum alloys

    DOE Patents [OSTI]

    Mayer, Anton (Los Alamos, NM)

    1988-01-01T23:59:59.000Z

    Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

  2. Electrodeposition of magnesium and magnesium/aluminum alloys

    DOE Patents [OSTI]

    Mayer, A.

    1988-01-21T23:59:59.000Z

    Electrolytes and plating solutions for use in processes for electroplating and electroforming pure magnesium and alloys of aluminum and magnesium and also electrodeposition processes. An electrolyte of this invention is comprised of an alkali metal fluoride or a quaternary ammonium halide, dimethyl magnesium and/or diethyl magnesium, and triethyl aluminum and/or triisobutyl aluminum. An electrolyte may be dissolved in an aromatic hydrocarbon solvent to form a plating solution. The proportions of the component compounds in the electrolyte are varied to produce essentially pure magnesium or magnesium/aluminum alloys having varying selected compositions.

  3. Final Report on the Safety Assessment of Aluminum Silicate, Calcium Silicate, Magnesium Aluminum

    E-Print Network [OSTI]

    Ahmad, Sajjad

    Final Report on the Safety Assessment of Aluminum Silicate, Calcium Silicate, Magnesium Aluminum Silicate, Magnesium Silicate, Magnesium Trisilicate, Sodium Magnesium Silicate, Zirconium Silicate, Attapulgite, Bentonite, Fuller's Earth, Hectorite, Kaolin, Lithium Magnesium Silicate, Lithium Magnesium

  4. Solid electrolyte based sensor for monitoring the magnesium level during reclamation of aluminum scrap

    SciTech Connect (OSTI)

    Fergus, J.W.; Hui, S. [Auburn Univ., AL (United States). Materials Research and Education Center

    1996-10-01T23:59:59.000Z

    Aluminum alloy scrap often contains excess magnesium which must be removed during recycling by a process referred to as demagging. The efficiency of this process could be improved with an in-situ magnesium sensor, which could be used to optimize the process parameters to the changing magnesium content. The sensor developed in this work consists of a galvanic cell with a magnesium fluoride (MgF{sub 2}) solid electrolyte and a molten magnesium reference electrode. The voltage output of the sensor changes by about 100 mV for the change in magnesium content which occurs during the demagging process (5 wt% to 0.1 wt%) and is in excellent agreement with thermodynamic measurements using molten chloride electrolytes. This paper focuses on the effect of silicon, which is a common alloying element in aluminum alloys, on the output of an electrochemical magnesium sensor.

  5. Magnesium Replacement of Aluminum Cast Components in a Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Replacement of Aluminum Cast Components in a Production V6 Engine to Effect Cost-Effective Mass Reduction Magnesium Replacement of Aluminum Cast Components in a Production V6...

  6. Ames Lab 101: BAM (Boron-Aluminum-Magnesium)

    ScienceCinema (OSTI)

    Bruce Cook

    2013-06-05T23:59:59.000Z

    Materials scientist, Bruce Cook, discusses the super hard, low friction, and lubricious alloy know as BAM (Boron-Aluminum-Magnesium). BAM was discovered by Bruce Cook and his team a

  7. The viability of aluminum Zintl anion moieties within magnesium-aluminum clusters

    SciTech Connect (OSTI)

    Wang, Haopeng; Jae Ko, Yeon; Zhang, Xinxing; Gantefoer, Gerd; Bowen, Kit H., E-mail: kiran@mcneese.edu, E-mail: akandalam@wcupa.edu, E-mail: kbowen@jhu.edu [Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Schnoeckel, Hansgeorg [Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany)] [Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany); Eichhorn, Bryan W. [Department of Chemistry, University of Maryland, College Park, Maryland 20742 (United States)] [Department of Chemistry, University of Maryland, College Park, Maryland 20742 (United States); Jena, Puru [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284 (United States); Kiran, Boggavarapu, E-mail: kiran@mcneese.edu, E-mail: akandalam@wcupa.edu, E-mail: kbowen@jhu.edu [Department of Chemistry, McNeese State University, Lake Charles, Louisiana 70609 (United States)] [Department of Chemistry, McNeese State University, Lake Charles, Louisiana 70609 (United States); Kandalam, Anil K., E-mail: kiran@mcneese.edu, E-mail: akandalam@wcupa.edu, E-mail: kbowen@jhu.edu [Department of Physics, West Chester University, West Chester, Pennsylvania 19383 (United States)

    2014-03-28T23:59:59.000Z

    Through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations, we have investigated the extent to which the aluminum moieties within selected magnesium-aluminum clusters are Zintl anions. Magnesium-aluminum cluster anions were generated in a pulsed arc discharge source. After mass selection, photoelectron spectra of Mg{sub m}Al{sub n}{sup ?} (m, n = 1,6; 2,5; 2,12; and 3,11) were measured by a magnetic bottle, electron energy analyzer. Calculations on these four stoichiometries provided geometric structures and full charge analyses for the cluster anions and their neutral cluster counterparts, as well as photodetachment transition energies (stick spectra). Calculations revealed that, unlike the cases of recently reported sodium-aluminum clusters, the formation of aluminum Zintl anion moieties within magnesium-aluminum clusters was limited in most cases by weak charge transfer between the magnesium atoms and their aluminum cluster moieties. Only in cases of high magnesium content, e.g., in Mg{sub 3}Al{sub 11} and Mg{sub 2}Al{sub 12}{sup ?}, did the aluminum moieties exhibit Zintl anion-like characteristics.

  8. A NEW A15 MULTIFILAMENTARY SUPERCONDUCTOR BASED ON THE NIOBIUM-ALUMINUM-SILICON SYSTEM

    E-Print Network [OSTI]

    Quinn, G.C.

    2011-01-01T23:59:59.000Z

    BASED ON THE NIOBIUM-ALUMINUM-SILICON SYSTEM Gary C. Quinnpsi. Photomicrograph of an Aluminum-Silicon eutectic filledmultifilimentary niobium-aluminum-silicon wire, a) sample #

  9. An investigation of magnesium production in silicon by neutron transmutation

    E-Print Network [OSTI]

    Davis, Freddie Joe

    1986-01-01T23:59:59.000Z

    OF SCIENCE May 1986 Major Subject: Nuclear Engineering AN INVESTIGATION OF MAGNESIUM PRODUCTION IN SILICON BY NEUTRON TRANSMUTATION A Thesis by FREDDIE JOE DAVIS, JR. Approved as to style and content by: Ron R. Har t (Chair of Committee) Donald L... University Chairman of Advisory Committee: Dr . Ron R. Hart An investigation of the production of' magnesium in silicon by neutron tr ansmutation is r eported. A 20 mil silicon wafer was irradiated at the Texas A&M University Nuclear Science Center...

  10. Simulation of Stresses during Casting of Binary Magnesium-Aluminum Alloys

    E-Print Network [OSTI]

    Beckermann, Christoph

    Simulation of Stresses during Casting of Binary Magnesium-Aluminum Alloys M.G. POKORNY, C.A. MONROE made for aluminum alloys.[6­8] Recently, Mathier and co-workers[9,10] performed a detailed com- parison between measured and predicted forces in the mush during solidification of dilute aluminum alloys

  11. aluminum silicon titanium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aluminum Paris-Sud XI, Universit de 7 HIGH-EFFICIENCY BACK-JUNCTION SILICON SOLAR CELL WITH AN IN-LINE EVAPORATED ALUMINUM FRONT GRID Renewable Energy Websites Summary:...

  12. SIMULATION OF STRESSES DURING CASTING OF BINARY MAGNESIUM-ALUMINUM ALLOYS M.G. Pokorny1

    E-Print Network [OSTI]

    Beckermann, Christoph

    SIMULATION OF STRESSES DURING CASTING OF BINARY MAGNESIUM-ALUMINUM ALLOYS M.G. Pokorny1 , C, Geesthacht, Germany Keywords: Magnesium Alloys, Casting, Stress Simulation Abstract A visco-plastic deformation model is used to predict thermal stresses during casting of binary Mg-Al alloys. The predictions

  13. Mechanical properties and microstructures of dual phase steels containing silicon, aluminum and molybdenum

    E-Print Network [OSTI]

    Neill, Thomas John O'

    2011-01-01T23:59:59.000Z

    STEELS CONTAINING SILICON, ALUMINUM AND MOLYBDENUM Thomasdeoxidizing action of aluminum results in grain refinementquench martensite, Both (a) and Aluminum particle within the

  14. aluminum alloy parts: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aluminum-magnesium-silicon alloy that may combine strength, extrudability, favorable corrosion resistance with low cost and scrap compatibility. The first (more) Li, Xiao, 1963-...

  15. aluminum alloy processed: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aluminum-magnesium-silicon alloy that may combine strength, extrudability, favorable corrosion resistance with low cost and scrap compatibility. The first (more) Li, Xiao, 1963-...

  16. aluminum alloys part: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aluminum-magnesium-silicon alloy that may combine strength, extrudability, favorable corrosion resistance with low cost and scrap compatibility. The first (more) Li, Xiao, 1963-...

  17. Impurity control and corrosion resistance of magnesium-aluminum alloy

    SciTech Connect (OSTI)

    Liu, M. [GM China Lab] [GM China Lab; Song, GuangLing [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    The corrosion resistance of magnesium alloys is very sensitive to the contents of impurity elements such as iron. In this study, a series of diecast AXJ530 magnesium alloy samples were prepared with additions of Mn and Fe. Through a comprehensive phase diagram calculation and corrosion evaluation, the mechanisms for the tolerance limit of Fe in magnesium alloy are discussed. This adds a new dimension to control the alloying impurity in terms of alloying composition design and casting conditions.

  18. Determination of the concentrations of magnesium and aluminum in alloys by laser produced atomic emission spectroscopy 

    E-Print Network [OSTI]

    Ashe, William Monroe

    1997-01-01T23:59:59.000Z

    DETERMINATION OF THE CONCENTRATIONS OF MAGNESIUM AND ALUiiINUM IN ALLOYS BY LASER PRODUCED ATOMIC EMISSION SPECTROSCOPY A Thesis by WILLIAM MONROE ASHE Submitted to the Office of Graduate Studies of Texas A&M University in partial... fulfillment of the reqmrements for the degree of MASTER OF SCIENCE December 1997 Major Subject: Physics DETERMINATION OF THE CONCENTRATIONS OF MAGNESIUM AND ALUMINUM ALLOYS BY LASER PRODUCED ATOMIC EMISSION SPECTROSCOPY A Thesis by WILLIAM MONROE ASHE...

  19. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide

    SciTech Connect (OSTI)

    Jiang, Weilin; Jung, Hee Joon; Kovarik, Libor; Wang, Zhaoying; Roosendaal, Timothy J.; Zhu, Zihua; Edwards, Danny J.; Hu, Shenyang Y.; Henager, Charles H.; Kurtz, Richard J.; Wang, Yongqiang

    2015-01-01T23:59:59.000Z

    As a candidate material for fusion reactor applications, silicon carbide (SiC) undergoes transmutation reactions under high-energy neutron irradiation with magnesium as the major metallic transmutant; the others include aluminum, beryllium and phosphorus in addition to helium and hydrogen gaseous species. The impact of these transmutants on SiC structural stability is currently unknown. This study uses ion implantation to introduce Mg into SiC. Multiaxial ion-channeling analysis of the as-produced damage state suggests that there are preferred Si <100> interstitial splits. The microstructure of the annealed sample was examined using high-resolution scanning transmission electron microscopy. The results show a high concentration of likely non-faulted tetrahedral voids and possible stacking fault tetrahedra near the damage peak. In addition to lattice distortion, dislocations and intrinsic and extrinsic stacking faults are also observed. Magnesium in 3C-SiC prefers to substitute for Si and it forms precipitates of cubic Mg2Si and tetragonal MgC2. The diffusion coefficient of Mg in 3C-SiC single crystal at 1573 K has been determined to be 3.8±0.4×10e-19 m2/sec.

  20. Lithium aluminum/iron sulfide battery having lithium aluminum and silicon as negative electrode

    DOE Patents [OSTI]

    Gilbert, Marian (Flossmoor, IL); Kaun, Thomas D. (New Lenox, IL)

    1984-01-01T23:59:59.000Z

    A method of making a negative electrode, the electrode made thereby and a secondary electrochemical cell using the electrode. Silicon powder is mixed with powdered electroactive material, such as the lithium-aluminum eutectic, to provide an improved electrode and cell.

  1. Carbothermic reduction and prereduced charge for producing aluminum-silicon alloys

    DOE Patents [OSTI]

    Stevenson, David T. (Washington Township, Armstrong County, PA); Troup, Robert L. (Murrysville, PA)

    1985-01-01T23:59:59.000Z

    Disclosed is a method for the carbothermic reduction of aluminum oxide to form an aluminum alloy including producing silicon carbide by heating a first mix of carbon and silicon oxide in a combustion reactor to an elevated temperature sufficient to produce silicon carbide at an accelerated rate, the heating being provided by an in situ combustion with oxygen gas, and then admixing the silicon carbide with carbon and aluminum oxide to form a second mix and heating the second mix in a second reactor to an elevated metal-forming temperature sufficient to produce aluminum-silicon alloy. The prereduction step includes holding aluminum oxide substantially absent from the combustion reactor. The metal-forming step includes feeding silicon oxide in a preferred ratio with silicon carbide.

  2. Carbothermic reduction and prereduced charge for producing aluminum-silicon alloys

    DOE Patents [OSTI]

    Stevenson, D.T.; Troup, R.L.

    1985-01-01T23:59:59.000Z

    Disclosed is a method for the carbothermic reduction of aluminum oxide to form an aluminum alloy including producing silicon carbide by heating a first mix of carbon and silicon oxide in a combustion reactor to an elevated temperature sufficient to produce silicon carbide at an accelerated rate, the heating being provided by an in situ combustion with oxygen gas, and then admixing the silicon carbide with carbon and aluminum oxide to form a second mix and heating the second mix in a second reactor to an elevated metal-forming temperature sufficient to produce aluminum-silicon alloy. The prereduction step includes holding aluminum oxide substantially absent from the combustion reactor. The metal-forming step includes feeding silicon oxide in a preferred ratio with silicon carbide. 1 fig.

  3. Synthesis and Characterization of Magnesium-Silicon and Magnesium-Tin Solid Solutions for Thermoelectric Applications

    E-Print Network [OSTI]

    Hu, Fang

    2012-07-16T23:59:59.000Z

    time curves have been researched in this thesis for fully reacted magnesium-silicide & magnesium-stannide green ingots with doping materials i.e. antimony, bismuth by different doping ratios. These ingots were ground by a high energy ball miller...

  4. Synthesis and Characterization of Magnesium-Silicon and Magnesium-Tin Solid Solutions for Thermoelectric Applications 

    E-Print Network [OSTI]

    Hu, Fang

    2012-07-16T23:59:59.000Z

    time curves have been researched in this thesis for fully reacted magnesium-silicide & magnesium-stannide green ingots with doping materials i.e. antimony, bismuth by different doping ratios. These ingots were ground by a high energy ball miller...

  5. Non-LTE Abundances of Magnesium, Aluminum and Sulfur in OB Stars Near the Solar Circle

    E-Print Network [OSTI]

    S. Daflon; K. Cunha; V. V. Smith; K. Butler

    2002-12-09T23:59:59.000Z

    Non-LTE abundances of magnesium, aluminum and sulfur are derived for a sample of 23 low-v \\sin i stars belonging to six northern OB associations of the Galactic disk within 1 kpc of the Sun. The abundances are obtained from the fitting of synthetic line profiles to high resolution spectra. A comparison of our results with HII region abundances indicates good agreement for sulfur while the cepheid abundances are higher. The derived abundances of Mg show good overlap with the cepheid results. The aluminum abundances for OB stars are significantly below the cepheid values. But, the OB star results show a dependence with effective temperature and need further investigation. The high Al abundances in the cepheids could be the result of mixing. A discussion of the oxygen abundance in objects near the solar circle suggests that the current mean galactic oxygen abundance in this region is 8.6-8.7 and in agreement with the recently revised oxygen abundance in the solar photosphere. Meaningful comparisons of the absolute S, Al and Mg abundances in OB stars with the Sun must await a reinvestigation of these elements, as well as the meteoritic reference element Si, with 3D hydrodynamical model atmospheres for the Sun. No abundance gradients are found within the limited range in galactocentric distances in the present study. Such variations would be expected only if there were large metallicity gradients in the disk.

  6. HIGH-EFFICIENCY BACK-JUNCTION SILICON SOLAR CELL WITH AN IN-LINE EVAPORATED ALUMINUM FRONT GRID

    E-Print Network [OSTI]

    HIGH-EFFICIENCY BACK-JUNCTION SILICON SOLAR CELL WITH AN IN-LINE EVAPORATED ALUMINUM FRONT GRID M-diffused back-junction emitter. The aluminum front side grid is evaporated in an industrial-type in-thick silicon shadow masks for the in-line evaporation of the aluminum front grid. The masks are fabricated

  7. An investigation of magnesium production in silicon by neutron transmutation 

    E-Print Network [OSTI]

    Davis, Freddie Joe

    1986-01-01T23:59:59.000Z

    irradiation of silicon may result in various combinations of products. These reactions are listed below. 28, 25 4Si (n, a) Ng la. 28 28 14Si (n, p) 1 Al 1b. 14Si (n, Y) 14Si 1c. 29 . 26 1 48 I (n o) 12rig 2a. 29 29 14Si (n, p) 13A1 29 14Si 2b. 29... efficiency is an effort to correct for those a's which do not. register as through'-etched holes. Consider a case very similar to that described in Figure 3, where there is a monoenergetic, isotr opic a source distributed uniformly throughout the silicon...

  8. CONCEPT: N-TYPE SILICON SOLAR CELLS WITH SURFACE-PASSIVATED SCREEN-PRINTED ALUMINUM-ALLOYED REAR EMITTER

    E-Print Network [OSTI]

    THE ALU+ CONCEPT: N-TYPE SILICON SOLAR CELLS WITH SURFACE- PASSIVATED SCREEN-PRINTED ALUMINUM-ALLOYED ABSTRACT Aluminum-doped p-type (Al-p + ) silicon emitters fabricated by means of screen-printing and firing-Si) and atomic-layer-deposited (ALD) aluminum oxide (Al2O3) as well as Al2O3/SiNx stacks, where the silicon

  9. Improved Irradiation Performance of Uranium-Molybdenum/Aluminum Dispersion Fuel by Silicon Addition in Aluminum

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; A. B. Robinson; D. M. Wachs

    2013-10-01T23:59:59.000Z

    Uranium-molybdenum fuel particle dispersion in aluminum is a form of fuel under development for conversion of high-power research and test reactors from highly enriched to low-enriched uranium in the U.S. Global Threat Reduction Initiative program (also known as the Reduced Enrichment for Research and Test Reactors program). Extensive irradiation tests have been conducted to find a solution for problems caused by interaction layer growth and pore formation between U-Mo and Al. Adding a small amount of Si (up to [approximately]5 wt%) in the Al matrix was one of the proposed remedies. The effect of silicon addition in the Al matrix was examined using irradiation test results by comparing side-by-side samples with different Si additions. Interaction layer growth was progressively reduced with increasing Si addition to the matrix Al, up to 4.8 wt%. The Si addition also appeared to delay pore formation and growth between the U-Mo and Al.

  10. Mineral interactions and absorption in the equine digestive tract: calcium, phosphorus, and magnesium interaction with aluminum, and calcium digestibility of alfalfa in ponies 

    E-Print Network [OSTI]

    Kapusniak, Linda J.

    1987-01-01T23:59:59.000Z

    MINERAL INTERACTIONS AND ABSORPTION IN THE EQUINE DIGESTIVE TRACT: CALCIUM, PHOSPHORUS, AND MAGNESIUM INTERACTION WITH ALUMINUM, AND CALCIUM DIGESTIBILITY OF ALFALFA IN PONIES A Thesis by LINDA J. KAPUSN IAK Subnitted to the Graduate College... of Texas ARM University. in partial fulfillment of the requirenent for the degree of MASTER OF SCIENCE August 1987 Major Subject: Nutrition MINERAL INTER4CTIONS AND ABSORPTION IN THE EQUINE DIGESTIVE TR4CT: C4LCIUM, PHOSPHORUS, AND MAGNESIUM...

  11. ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR CELLS

    E-Print Network [OSTI]

    ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR to those measured on reference cells passivated by an aluminum-annealed thermal SiO2, while those of the Al of aluminum ox- ide (Al2O3) grown by atomic layer deposition (ALD) pro- vide an excellent level of sur

  12. Structure and properties of a rapidly solidified dispersion strengthened aluminum-iron-vanadium-silicon alloy

    E-Print Network [OSTI]

    Little, Stafford Dean

    1991-01-01T23:59:59.000Z

    Dispersion Strengthened Aluminum-Iron-Vanadium-Silicon Alloy. (December 1991) Stafford Dean Little, B. S. , Texas A&M University Co-Chairs of Advisory Committee: Dr. M. N. Srinivasan Dr. A. Wolfenden A research program has been completed at Texas A...&M University in which the structure and properties of a rapidly solidified dispersion strengthened aluminum-iron- vanadium-silicon alloy were evaluated. A series of melt spun ribbons of FVS1212 (Fe- 11. 5%, V-1. 4%, Si-2. 2%, Al-bal) were produced...

  13. JOM Volume 63, Number 2 (2011): 48-52 High strain rate compressive response of magnesium-aluminum alloy/fly ash cenosphere composites

    E-Print Network [OSTI]

    Gupta, Nikhil

    2011-01-01T23:59:59.000Z

    , and sound and vibration damping. Low strength of open and closed-cell foams containing gas porosity distribution in syntactic foams is usually much more uniform compared to the gas filled foams. Presence half of which is dumped in landfills. In the present work, a cast magnesium-aluminum alloy, AZ91D

  14. Low alloy additions of iron, silicon, and aluminum to uranium: a literature survey

    SciTech Connect (OSTI)

    Ludwig, R.L.

    1980-12-31T23:59:59.000Z

    A survey of the literature has been made on the experimental results of small additions of iron, silicon, and aluminum to uranium. Information is also included on the constitution, mechanical properties, heat treatment, and deformation of various binary and ternary alloys. 42 references, 24 figures, 13 tables.

  15. Laser Welding of Aluminum and Aluminum Alloys

    E-Print Network [OSTI]

    Eagar, Thomas W.

    .. ) Laser Welding of Aluminum and Aluminum Alloys Welds made with sharp bevel-groove weld aluminum and by aluminum alloy 5456 have been studied. The results indicate that initial absorption varies, many aluminum alloys contain magnesium or zinc, which are easily vaporized and thereby form a plasma

  16. Influence of Aluminum Content on Grain Refinement and Strength of AZ31 Magnesium GTA Weld Metal

    SciTech Connect (OSTI)

    Babu, N. Kishore [Singapore Institute of Manufacturing Technology; Cross, Carl E. [Los Alamos National Laboratory

    2012-06-28T23:59:59.000Z

    The goal is to characterize the effect of Al content on AZ31 weld metal, the grain size and strength, and examine role of Al on grain refinement. The approach is to systematically vary the aluminum content of AZ31 weld metal, Measure average grain size in weld metal, and Measure cross-weld tensile properties and hardness. Conclusions are that: (1) increased Al content in AZ31 weld metal results in grain refinement Reason: higher undercooling during solidification; (2) weld metal grain refinement resulted in increased strength & hardness Reason: grain boundary strengthening; and (3) weld metal strength can be raised to wrought base metal levels.

  17. Energy-Saving Melting and Revert Reduction Technology (E-SMARRT): Lost Foam Thin Wall - Feasibility of Producing Lost Foam Castings in Aluminum and Magnesium Based Alloys

    SciTech Connect (OSTI)

    Fasoyinu, Yemi [CanmetMATERIALS] [CanmetMATERIALS; Griffin, John A. [University of Alabama - Birmingham] [University of Alabama - Birmingham

    2014-03-31T23:59:59.000Z

    With the increased emphasis on vehicle weight reduction, production of near-net shape components by lost foam casting will make significant inroad into the next-generation of engineering component designs. The lost foam casting process is a cost effective method for producing complex castings using an expandable polystyrene pattern and un-bonded sand. The use of un-bonded molding media in the lost foam process will impose less constraint on the solidifying casting, making hot tearing less prevalent. This is especially true in Al-Mg and Al-Cu alloy systems that are prone to hot tearing when poured in rigid molds partially due to their long freezing range. Some of the unique advantages of using the lost foam casting process are closer dimensional tolerance, higher casting yield, and the elimination of sand cores and binders. Most of the aluminum alloys poured using the lost foam process are based on the Al-Si system. Very limited research work has been performed with Al-Mg and Al-Cu type alloys. With the increased emphasis on vehicle weight reduction, and given the high-strength-to-weight-ratio of magnesium, significant weight savings can be achieved by casting thin-wall (? 3 mm) engineering components from both aluminum- and magnesium-base alloys.

  18. aluminum alloy produced: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for silicon metal comes primarily from the aluminum and chemical industries. Domestic secondary aluminum production--the primary materials source for aluminum-silicon alloys--was...

  19. An approach to modeling the cost-strength-weight tradeoff in aluminum and magnesium extrusions for automotive applications

    E-Print Network [OSTI]

    Komander, Johann Kasper

    2009-01-01T23:59:59.000Z

    In light of volatile fuel prices and tightening emissions regulations, automobile manufacturers have been increasingly considering the use of light-weight magnesium in their efforts to improve fuel economy. While mainly ...

  20. MICROSTRUCTURE AND MECHANICAL PROPERTIES OF AISI 4340 STEEL MODIFIED WITH ALUMINUM AND SILICON

    E-Print Network [OSTI]

    Bhat, M.S.

    2010-01-01T23:59:59.000Z

    Met. Trans. 1,2163 (1972). Aluminum_~n Iron~, S. L. Case andSTEEL MODIFIED WITH ALUMINUM AND SILIC ON ManjeshwarThe influence of additions of aluminum and combinations of

  1. Mechanical properties and microstructures of dual phase steels containing silicon, aluminum and molybdenum

    E-Print Network [OSTI]

    Neill, Thomas John O'

    2011-01-01T23:59:59.000Z

    AND MICROSTRUCTURES OF DUAL PHASE STEELS CONTAINING SILICON,and Microstructures of Dual Phase Steels Containing Silicon,microstructures of selected dual-phase steels in which the

  2. Development of High-Volume Warm Forming of Low-Cost Magnesium...

    Broader source: Energy.gov (indexed) [DOE]

    mccarty13.pdf More Documents & Publications Warm Forming of AluminumAMD 307 Magnesium Front End Research And Development (AMD604) Magnesium Front End Design And Development...

  3. Substrate and method for the formation of continuous magnesium diboride and doped magnesium diboride wire

    DOE Patents [OSTI]

    Suplinskas, Raymond J. (Haverhill, MA); Finnemore, Douglas (Ames, IA); Bud'ko, Serquei (Ames, IA); Canfield, Paul (Ames, IA)

    2007-11-13T23:59:59.000Z

    A chemically doped boron coating is applied by chemical vapor deposition to a silicon carbide fiber and the coated fiber then is exposed to magnesium vapor to convert the doped boron to doped magnesium diboride and a resultant superconductor.

  4. Texture Control by Selective Deformation Mechanism Activation in Magnesium Alloy

    E-Print Network [OSTI]

    Foley, David Christopher

    2014-07-01T23:59:59.000Z

    The need for high strength, light weight structures in automotive and aerospace applications has driven a resurgence of interest in magnesium and its alloys. Unlike aluminum, wrought magnesium typically has a high degree of mechanical anisotropy...

  5. Texture Control by Selective Deformation Mechanism Activation in Magnesium Alloy 

    E-Print Network [OSTI]

    Foley, David Christopher

    2014-07-01T23:59:59.000Z

    The need for high strength, light weight structures in automotive and aerospace applications has driven a resurgence of interest in magnesium and its alloys. Unlike aluminum, wrought magnesium typically has a high degree of mechanical anisotropy...

  6. AMD 601 High Integrity -Magnesium Automotive Components (HI-MAC...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Neutral or Less Than Current Aluminum Components USAMP AMD 601 - High Integrity Magnesium Automotive Components (HI-MAC) edm2@chrysler.com February 28, 2008 Approach Scientific...

  7. Magnesium behavior and structural defects in Mg+ ion implanted...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    irradiation with magnesium as the major metallic transmutant; the others include aluminum, beryllium and phosphorus in addition to helium and hydrogen gaseous species. The...

  8. aluminum oxide layer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR CELLS Renewable Energy Websites Summary: ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE...

  9. aluminum oleate layered: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR CELLS Renewable Energy Websites Summary: ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE...

  10. aluminum oxide layers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR CELLS Renewable Energy Websites Summary: ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR THE...

  11. aluminum high pressure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ALUMINUM OXIDE FOR THE SURFACE PASSIVATION OF HIGH-EFFICIENCY SILICON SOLAR CELLS Renewable Energy Websites Summary: ATOMIC-LAYER-DEPOSITED ALUMINUM OXIDE FOR...

  12. Aluminum battery alloys

    DOE Patents [OSTI]

    Thompson, David S. (Richmond, VA); Scott, Darwin H. (Mechanicsville, VA)

    1985-01-01T23:59:59.000Z

    Aluminum alloys suitable for use as anode structures in electrochemical cs are disclosed. These alloys include iron levels higher than previously felt possible, due to the presence of controlled amounts of manganese, with possible additions of magnesium and controlled amounts of gallium.

  13. Aluminum battery alloys

    DOE Patents [OSTI]

    Thompson, D.S.; Scott, D.H.

    1984-09-28T23:59:59.000Z

    Aluminum alloys suitable for use as anode structures in electrochemical cells are disclosed. These alloys include iron levels higher than previously felt possible, due to the presence of controlled amounts of manganese, with possible additions of magnesium and controlled amounts of gallium.

  14. Production of aluminum-silicon alloy and ferrosilicon and commercial-purity aluminum by the direct-reduction process. Third annual technical report, 1980 January 1-1980 December 31

    SciTech Connect (OSTI)

    Bruno, M.J.

    1981-01-01T23:59:59.000Z

    Progress on the program to demonstrate the technical feasibility of a pilot-sized Direct Reduction Process for producing aluminium and aluminium-silicon alloy is reported for Phase C. Progress is reported on reduction including the following tasks: supply burden material; burden beneficiation; effects of pilot operating parameters; pilot modifications; reactor scale-up design; calculating heat and mass balance; processing mathematical modeling; effects of process variables; information on supportive analytical, phase identification, and mechanical engineering data. Progress on alloy purification is reported in the following tasks: pilot unit installation; effects of pilot operating parameters; pilot unit modifications; and supportive mechanical engineering. Progress on purification to commercial grade aluminum is reported on: pilot unit installation; effects of pilot operating parameters; pilot unit modifications; support pilot operations; and supportive expended man-hours. Plans for Phase D are noted. (MCW)

  15. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

    2010-02-23T23:59:59.000Z

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  16. Studies of hydrogen embrittlement and stress-corrosion cracking in an aluminum-zinc-magnesium alloy. [5. 6 Zn - 2. 6 Mg

    SciTech Connect (OSTI)

    Ciaraldi, S.W.; Nelson, J.L.; Yeske, R.A.; Pugh, E.N.

    1980-01-01T23:59:59.000Z

    Tensile tests have been carried out on a high-purity A1-5.6 Zn-2.6 Mg alloy hydrogenated by exposure to moist air. Results indicate that internal hydrogen embrittlement occurs by the formation and rupture of a stress-induced hydride at the grain boundaries. The hydride, identified by electron diffraction as A1H/sub 3/, is shown to be unstable in laboratory air, reverting to aluminum. The hydride phase was not detected in specimens failed by SCC, despite evidence that hydrogen is transported ahead of advancing stress-corrosion cracks, and this leads to the possibility that a basically different mechanism may be responsible for SCC in this alloy.

  17. TIG welding of aluminum alloys for the APS storage ring - a UHV application

    SciTech Connect (OSTI)

    Goeppner, G.A.

    1996-05-29T23:59:59.000Z

    The Advanced Photon Source (APS) incorporates a 7-GeV positron storage ring 1104 meters in circumference. The storage ring vacuum system is designed to maintain a pressure of 1 nTorr or less with a circulating current of 300 mA to enable beam lifetimes of greater than 10 hours. The vacuum chamber is an aluminum extrusion of 6063T5 alloy. There are 235 separate aluminum vacuum chambers in the storage ring connected by stainless steel bellows assemblies. Aluminum was chosen for the vacuum chamber because it can be economically extruded and machined, has good thermal conductivity, low thermal emissivity, a low outgassing rate, low residual radioactivity, and is non-magnetic. The 6063 aluminum-silicon-magnesium alloy provides high strength combined with good machining and weldability characteristics. The extrusion process provides the interior surface finish needed for the ultrahigh vacuum (UHV) environments There are six different vacuum chambers with the same extrusion cross section. The average vacuum chamber length is 171.6 inches. The extruded vacuum chambers are welded to flange assemblies made up of machined 2219 aluminum alloy pieces and 2219 aluminum vacuum flanges from a commercial source.

  18. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

    2012-04-10T23:59:59.000Z

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  19. Assessment of the magnesium primary production technology. Final report

    SciTech Connect (OSTI)

    Flemings, M.C.; Kenney, G.B.; Sadoway, D.R.; Clark, J.P.; Szekely, J.

    1981-02-01T23:59:59.000Z

    At current production levels, direct energy savings achievable in primary magnesium production are 1.2 milliquads of energy per annum. Were magnesium to penetrate the automotive market to an average level of 50 pounds per vehicle, the resultant energy savings at the production stage would be somewhat larger, but the resulting savings in gasoline would conserve an estimated 325 milliquads of energy per year. The principal barrier to more widespread use of magnesium in the immediate future is its price. A price reduction of magnesium of 10% would lead to widespread conversion of aluminum die and permanent mold castings to magnesium. This report addresses the technology of electrolytic and thermic magnesium production and the economics of expanded magnesium production and use.

  20. Electrodeposition of aluminium, aluminium/magnesium alloys, and magnesium from organometallic electrolytes

    SciTech Connect (OSTI)

    Mayer, A.

    1988-01-01T23:59:59.000Z

    The electrodeposition of aluminum, magnesium, and the combination of these metals from nonaqueous media is discussed. Plating baths for depositing Al/Mg alloys or for plating essentially pure Mg were developed. These solutions contain alkali meal fluoride or quaternary ammonium halide/aluminium alkyl complexes and dialkyl magnesium dissolved in aromatic hydrocarbons. Alloy deposits over the whole composition range can be plated from these solutions by varying the relative quantities of the aluminium and magnesium alkyls and by changing the bath-operating parameters. 18 refs., 4 figs.

  1. Thermodynamics of copper-nickel alloys containing aluminum, silicon, titanium, and chromium relative to their use in ceramic brazing

    SciTech Connect (OSTI)

    Williams, R.O.

    1984-11-01T23:59:59.000Z

    By varying the copper-to-nickel ratio the activity coefficients of Al, Si, Ti, and Cr can be varied over a wide range. Thus to a degree one can tailor the behavior of such alloys for usefulness in brazing ceramics. Further, considerable amounts of these active elements can be present while the ability of carbon to reduce the surface oxide film in a high-vacuum system is retained. The critical aluminum concentrations required to prevent the formation of SiO/sub 2/, TiO, or Cr/sub 2/O/sub 3/ by reaction with Al/sub 2/O/sub 3/ are calculated. The simultaneous presence of the four active additions will presumably promote wetting without making the surface deoxidation more difficult.

  2. Selective Adsorption of Sodium Aluminum Fluoride Salts from Molten Aluminum

    SciTech Connect (OSTI)

    Leonard S. Aubrey; Christine A. Boyle; Eddie M. Williams; David H. DeYoung; Dawid D. Smith; Feng Chi

    2007-08-16T23:59:59.000Z

    Aluminum is produced in electrolytic reduction cells where alumina feedstock is dissolved in molten cryolite (sodium aluminum fluoride) along with aluminum and calcium fluorides. The dissolved alumina is then reduced by electrolysis and the molten aluminum separates to the bottom of the cell. The reduction cell is periodically tapped to remove the molten aluminum. During the tapping process, some of the molten electrolyte (commonly referred as “bath” in the aluminum industry) is carried over with the molten aluminum and into the transfer crucible. The carryover of molten bath into the holding furnace can create significant operational problems in aluminum cast houses. Bath carryover can result in several problems. The most troublesome problem is sodium and calcium pickup in magnesium-bearing alloys. Magnesium alloying additions can result in Mg-Na and Mg-Ca exchange reactions with the molten bath, which results in the undesirable pickup of elemental sodium and calcium. This final report presents the findings of a project to evaluate removal of molten bath using a new and novel micro-porous filter media. The theory of selective adsorption or removal is based on interfacial surface energy differences of molten aluminum and bath on the micro-porous filter structure. This report describes the theory of the selective adsorption-filtration process, the development of suitable micro-porous filter media, and the operational results obtained with a micro-porous bed filtration system. The micro-porous filter media was found to very effectively remove molten sodium aluminum fluoride bath by the selective adsorption-filtration mechanism.

  3. Fabrication and characterization of n-type aluminum-boron co-doped ZnO on p-type silicon (n-AZB/p-Si) heterojunction diodes

    SciTech Connect (OSTI)

    Kumar, Vinod, E-mail: vinod.phy@gmail.com [Department of Physics, University of the Free State, Bloemfontein ZA-9300 (South Africa); Singh, Neetu [Department of Electronic Science, University of Delhi South Campus, New Delhi 110 021 (India); Department of Electronics, Keshav Mahavidyalaya, University of Delhi 110 034 (India); Kapoor, Avinashi [Department of Electronic Science, University of Delhi South Campus, New Delhi 110 021 (India); Ntwaeaborwa, Odireleng M.; Swart, Hendrik C. [Department of Physics, University of the Free State, Bloemfontein ZA-9300 (South Africa)

    2013-11-15T23:59:59.000Z

    Graphical abstract: - Highlights: • n-AZB/p-Si heterojunction diodes were formed. • n-AZB/p-Si diode annealed at 700 °C showed best rectifying behavior. • Zn{sub 2}SiO{sub 4} was formed at 800 °C. • n and ?{sub b} were estimated to be 1.63 and 0.4 eV, respectively, at 700 °C. • Tailoring of BG was attributed to annealing induced stresses in the films. - Abstract: In this paper, the growth of n-type aluminum boron co-doped ZnO (n-AZB) on a p-type silicon (p-Si) substrate by sol–gel method using spin coating technique is reported. The n-AZB/p-Si heterojunctions were annealed at different temperatures ranging from 400 to 800 °C. The crystallite size of the AZB nanostructures was found to vary from 28 to 38 nm with the variation in annealing temperature. The band gap of the AZB decreased from 3.29 to 3.27 eV, with increasing annealing temperature from 400 to 700 °C and increased to 3.30 eV at 800 °C probably due to the formation of Zn{sub 2}SiO{sub 4} at the interface. The band gap variation is explained in terms of annealing induced stress in the AZB. The n-AZB/p-Si heterojunction exhibited diode behavior. The best rectifying behavior was exhibited at 700 °C.

  4. Influences on Burr Size During Face-Milling of Aluminum Alloys and Cast Iron

    E-Print Network [OSTI]

    Shefelbine, Wendy; Dornfeld, David

    2004-01-01T23:59:59.000Z

    burrs. As with the aluminum alloys, the machining conditionsON BURR FORMATION As with the aluminum alloys, there is someFACE-MILLING OF ALUMINUM-SILICON ALLOYS AND CAST IRON Wendy

  5. Aluminum-tungsten fiber composites with cylindrical geometry and controlled architecture of tungsten reinforcement

    E-Print Network [OSTI]

    Lucchese, Carl Joesph

    2010-01-01T23:59:59.000Z

    Chung, D. “Silicon-Aluminum Network Composites Fabricated byFigure 95 - Fine model with initial aluminum matrix failure.slight necking of the aluminum matrix. Note failed elements

  6. SciTech Connect: The determination of aluminum by atomic absorption...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: CHEMISTRY; ABSORPTION; ALUMINUM; CEMENTS; CHLORIDES; COMBUSTION; PHOTOMETRY; QUANTITATIVE ANALYSIS; SILICON OXIDES; SOLUTIONS; SPECTROSCOPY; STEELS...

  7. UNIVERSITY of CALIFORNIA ATOMIC LAYER DEPOSITION OF ALUMINUM OXIDE

    E-Print Network [OSTI]

    Belanger, David P.

    UNIVERSITY of CALIFORNIA SANTA CRUZ ATOMIC LAYER DEPOSITION OF ALUMINUM OXIDE A thesis submitted deposition (ALD) of aluminum oxide on crystalline silicon and anodized aluminum substrates. A homemade ALD system is used with trimethylaluminum (TMA) and water as precursors to deposit uniform aluminum oxide

  8. Effect of Texture on Formability and Mechanical Anisotropy of a Severe Plastically Deformed Magnesium Alloy

    E-Print Network [OSTI]

    Modarres Razavi, Sonia

    2012-02-14T23:59:59.000Z

    Magnesium and its alloys have been considered as alternatives to aluminum alloys and steels for structural applications in automotive and aerospace applications due to their superior specific strength and light-weight. However, they have hexagonal...

  9. Effect of Texture on Formability and Mechanical Anisotropy of a Severe Plastically Deformed Magnesium Alloy 

    E-Print Network [OSTI]

    Modarres Razavi, Sonia

    2012-02-14T23:59:59.000Z

    Magnesium and its alloys have been considered as alternatives to aluminum alloys and steels for structural applications in automotive and aerospace applications due to their superior specific strength and light-weight. However, they have hexagonal...

  10. Efficient One-Step Electrolytic Recycling of Low-Grade and Post-Consumer Magnesium Scrap

    SciTech Connect (OSTI)

    Adam C. Powell, IV

    2012-07-19T23:59:59.000Z

    Metal Oxygen Separation Technologies, Inc. (abbreviated MOxST, pronounced most) and Boston University (BU) have developed a new low-cost process for recycling post-consumer co-mingled and heavily-oxidized magnesium scrap, and discovered a new chemical mechanism for magnesium separations in the process. The new process, designated MagReGenTM, is very effective in laboratory experiments, and on scale-up promises to be the lowest-cost lowest-energy lowest-impact method for separating magnesium metal from aluminum while recovering oxidized magnesium. MagReGenTM uses as little as one-eighth as much energy as today's methods for recycling magnesium metal from comingled scrap. As such, this technology could play a vital role in recycling automotive non-ferrous metals, particularly as motor vehicle magnesium/aluminum ratios increase in order to reduce vehicle weight and increase efficiency.

  11. Silicon Nitride Ball Presented by: Mike Velez

    E-Print Network [OSTI]

    Mukhopadhyay, Sharmila M.

    , magnesium oxide ­ Nitrogen atmosphere @ 1750C ­ Atmospheric pressure · Syalon ­ Similar to SSN with aluminum · Performance automotive · Wind turbine · Rollerblades · Bicycles · Marine applications #12;Conclusion

  12. Materials Science and Engineering A 472 (2008) 242250 Shear behavior of aluminum lattice truss sandwich panel structures

    E-Print Network [OSTI]

    Wadley, Haydn

    2008-01-01T23:59:59.000Z

    ; Aluminum alloys; Brazing 1. Introduction Millimeter cell size, aluminum alloy lattice structures alloys such as copper/beryllium [26], aluminum/silicon [27­30] and silicon brass [27]. HoweverMaterials Science and Engineering A 472 (2008) 242­250 Shear behavior of aluminum lattice truss

  13. Process for strengthening aluminum based ceramics and material

    DOE Patents [OSTI]

    Moorhead, Arthur J. (Knoxville, TN); Kim, Hyoun-Ee (Seoul, KR)

    2000-01-01T23:59:59.000Z

    A process for strengthening aluminum based ceramics is provided. A gaseous atmosphere consisting essentially of silicon monoxide gas is formed by exposing a source of silicon to an atmosphere consisting essentially of hydrogen and a sufficient amount of water vapor. The aluminum based ceramic is exposed to the gaseous silicon monoxide atmosphere for a period of time and at a temperature sufficient to produce a continuous, stable silicon-containing film on the surface of the aluminum based ceramic that increases the strength of the ceramic.

  14. ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aluminum Industry Vision: Sustainable Solutions for a Dynamic World ITP Aluminum: Aluminum Industry Vision: Sustainable Solutions for a Dynamic World alumvision.pdf More Documents...

  15. Method for production of magnesium

    DOE Patents [OSTI]

    Diaz, A.F.; Howard, J.B.; Modestino, A.J.; Peters, W.A.

    1998-07-21T23:59:59.000Z

    A continuous process for the production of elemental magnesium is described. Magnesium is made from magnesium oxide and a light hydrocarbon gas. In the process, a feed stream of the magnesium oxide and gas is continuously fed into a reaction zone. There the magnesium oxide and gas are reacted at a temperature of about 1400 C or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental magnesium. The product stream is continuously quenched after leaving the reaction zone, and the elemental magnesium is separated from other reaction products. 12 figs.

  16. Method for production of magnesium

    DOE Patents [OSTI]

    Diaz, Alexander F. (Cambridge, MA); Howard, Jack B. (Winchester, MA); Modestino, Anthony J. (Hanson, MA); Peters, William A. (Lexington, MA)

    1998-01-01T23:59:59.000Z

    A continuous process for the production of elemental magnesium is described. Magnesium is made from magnesium oxide and a light hydrocarbon gas. In the process, a feed stream of the magnesium oxide and gas is continuously fed into a reaction zone. There the magnesium oxide and gas are reacted at a temperature of about 1400.degree. C. or greater in the reaction zone to provide a continuous product stream of reaction products, which include elemental magnesium. The product stream is continuously quenched after leaving the reaction zone, and the elemental magnesium is separated from other reaction products.

  17. Climate VISION: Private Sector Initiatives: Magnesium: Resources...

    Office of Scientific and Technical Information (OSTI)

    Industry Associations International Magnesium Association Founded in 1943, the mission of the International Magnesium Association (IMA) is to promote the use of the metal magnesium...

  18. aluminum hlw high: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 361 CONCEPT: N-TYPE SILICON SOLAR CELLS WITH SURFACE-PASSIVATED SCREEN-PRINTED ALUMINUM-ALLOYED REAR EMITTER Renewable...

  19. Electrical characterization of germanium-silicon alloy

    E-Print Network [OSTI]

    Kishore, Kumar P.

    1994-01-01T23:59:59.000Z

    . The fabrication procedure involved sputter deposition of silicon dioxide, oxide patterning, deposition of aluminum metal and metal patterning. Each test structure was square-shaped and consisted of eight sets of peripheral metal contacts. The results...

  20. Electrical characterization of germanium-silicon alloy 

    E-Print Network [OSTI]

    Kishore, Kumar P.

    1994-01-01T23:59:59.000Z

    . The fabrication procedure involved sputter deposition of silicon dioxide, oxide patterning, deposition of aluminum metal and metal patterning. Each test structure was square-shaped and consisted of eight sets of peripheral metal contacts. The results...

  1. The effect of cooling rate on thermophysical properties of magnesium alloys

    E-Print Network [OSTI]

    Medraj, Mamoun

    been in widespread use in the automotive industry processed mainly by casting. In designing cast automotive compo- nents, it is important to know how these alloys solidify at different cross sections magnesium and aluminum. The samples were cut and mechanically polished to remove any possible contaminated

  2. A Life Cycle Assessment of a Magnesium Automotive Front End

    SciTech Connect (OSTI)

    Das, Sujit [ORNL; Dubreuil, Alain [Natural Resources Canada; Bushi, Lindita [GreenhouseGasMeasurement.com; Tharumarajah, Ambalavanar [CSIRO/CAST-CRC

    2009-01-01T23:59:59.000Z

    The Magnesium Front End Research and Development (MFERD) project under the sponsorship of Canada, China and USA aims to develop key technologies and a knowledge base for increased use of magnesium in automobile. The goal of this life cycle assessment (LCA) study is to compare the energy and potential environmental impacts of advanced magnesium based front end parts of a North America built 2007 GM-Cadillac CTS with the standard carbon steel based design. This LCA uses the 'cradle-to-grave' approach by including primary material production, semi-fabrication production, autoparts manufacturing and assembly, transportation, use phase and end-of-life processing of autoparts. This LCA study was done in compliance with international standards ISO 14040:2006 and ISO 14044:2006. Furthermore, the LCA results for aluminum based front end autopart are presented. While weight savings result in reductions in energy use and carbon dioxide emissions during the use of the car, the impacts of fabrication and recycling of lightweight materials are substantial in regard to steel. Pathways for improving sustainability of magnesium use in automobiles through material management and technology improvements including recycling are also discussed.

  3. Dispersion toughened silicon carbon ceramics

    DOE Patents [OSTI]

    Wei, G.C.

    1984-01-01T23:59:59.000Z

    Fracture resistant silicon carbide ceramics are provided by incorporating therein a particulate dispersoid selected from the group consisting of (a) a mixture of boron, carbon and tungsten, (b) a mixture of boron, carbon and molybdenum, (c) a mixture of boron, carbon and titanium carbide, (d) a mixture of aluminum oxide and zirconium oxide, and (e) boron nitride. 4 figures.

  4. Synthesis of magnesium diboride by magnesium vapor infiltration process (MVIP)

    DOE Patents [OSTI]

    Serquis, Adriana C. (Los Alamos, NM); Zhu, Yuntian T. (Los Alamos, NM); Mueller, Frederick M. (Los Alamos, NM); Peterson, Dean E. (Los Alamos, NM); Liao, Xiao Zhou (Los Alamos, NM)

    2003-01-01T23:59:59.000Z

    A process of preparing superconducting magnesium diboride powder by heating an admixture of solid magnesium and amorphous boron powder or pellet under an inert atmosphere in a Mg:B ratio of greater than about 0.6:1 at temperatures and for time sufficient to form said superconducting magnesium diboride. The process can further include exposure to residual oxygen at high synthesis temperatures followed by slow cooling. In the cooling process oxygen atoms dissolved into MgB.sub.2 segregated to form nanometer-sized coherent Mg(B,O) precipitates in the MgB.sub.2 matrix, which can act as flux pinning centers.

  5. Metal electrode for amorphous silicon solar cells

    DOE Patents [OSTI]

    Williams, Richard (Princeton, NJ)

    1983-01-01T23:59:59.000Z

    An amorphous silicon solar cell having an N-type region wherein the contact to the N-type region is composed of a material having a work function of about 3.7 electron volts or less. Suitable materials include strontium, barium and magnesium and rare earth metals such as gadolinium and yttrium.

  6. accumulate magnesium protoporphyrin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    previous work that the exchangeable magnesium behaves similarly to exchangeable calcium. Daniel L. Gilbert 12 Constraining magnesium cycling in marine sediments using magnesium...

  7. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, D.R.

    1988-08-16T23:59:59.000Z

    A stable reference electrode is described for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na[sub 3]AlF[sub 6], wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution. 1 fig.

  8. Aluminum reference electrode

    DOE Patents [OSTI]

    Sadoway, Donald R. (Belmont, MA)

    1988-01-01T23:59:59.000Z

    A stable reference electrode for use in monitoring and controlling the process of electrolytic reduction of a metal. In the case of Hall cell reduction of aluminum, the reference electrode comprises a pool of molten aluminum and a solution of molten cryolite, Na.sub.3 AlF.sub.6, wherein the electrical connection to the molten aluminum does not contact the highly corrosive molten salt solution. This is accomplished by altering the density of either the aluminum (decreasing the density) or the electrolyte (increasing the density) so that the aluminum floats on top of the molten salt solution.

  9. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

    2008-12-09T23:59:59.000Z

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  10. Climate VISION: Private Sector Initiatives: Aluminum: Resources...

    Office of Scientific and Technical Information (OSTI)

    Industry Associations Aluminum Association The Aluminum Association, Inc. is the trade association for producers of primary aluminum, recyclers and semi-fabricated aluminum...

  11. Aluminum powder metallurgy processing

    SciTech Connect (OSTI)

    Flumerfelt, J.F.

    1999-02-12T23:59:59.000Z

    The objective of this dissertation is to explore the hypothesis that there is a strong linkage between gas atomization processing conditions, as-atomized aluminum powder characteristics, and the consolidation methodology required to make components from aluminum powder. The hypothesis was tested with pure aluminum powders produced by commercial air atomization, commercial inert gas atomization, and gas atomization reaction synthesis (GARS). A comparison of the GARS aluminum powders with the commercial aluminum powders showed the former to exhibit superior powder characteristics. The powders were compared in terms of size and shape, bulk chemistry, surface oxide chemistry and structure, and oxide film thickness. Minimum explosive concentration measurements assessed the dependence of explosibility hazard on surface area, oxide film thickness, and gas atomization processing conditions. The GARS aluminum powders were exposed to different relative humidity levels, demonstrating the effect of atmospheric conditions on post-atomization processing conditions. The GARS aluminum powders were exposed to different relative humidity levels, demonstrating the effect of atmospheric conditions on post-atomization oxidation of aluminum powder. An Al-Ti-Y GARS alloy exposed in ambient air at different temperatures revealed the effect of reactive alloy elements on post-atomization powder oxidation. The pure aluminum powders were consolidated by two different routes, a conventional consolidation process for fabricating aerospace components with aluminum powder and a proposed alternative. The consolidation procedures were compared by evaluating the consolidated microstructures and the corresponding mechanical properties. A low temperature solid state sintering experiment demonstrated that tap densified GARS aluminum powders can form sintering necks between contacting powder particles, unlike the total resistance to sintering of commercial air atomization aluminum powder.

  12. Synthesis of superconducting magnesium diboride objects

    DOE Patents [OSTI]

    Finnemore, Douglas K. (Ames, IA); Canfield, Paul C. (Ames, IA); Bud'ko, Sergey L. (Ames, IA); Ostenson, Jerome E. (Ames, IA); Petrovic, Cedomir (Ames, IA); Cunningham, Charles E. (Ames, IA); Lapertot, Gerard (Grenoble, FR)

    2003-08-15T23:59:59.000Z

    A process to produce magnesium diboride objects from boron objects with a similar form is presented. Boron objects are reacted with magnesium vapor at a predetermined time and temperature to form magnesium diboride objects having a morphology similar to the boron object's original morphology.

  13. Synthesis Of Superconducting Magnesium Diboride Objects.

    DOE Patents [OSTI]

    Finnemore, Douglas K. (Ames, IA); Canfield, Paul C. (Ames, IA); Bud'ko, Sergey L. (Ames, IA); Ostenson, Jerome E. (Ames, IA); Petrovic, Cedomir (Ames, IA); Cunningham, Charles E. (Ames, IA); Lapertot, Gerard (Grenoble, FR)

    2003-07-08T23:59:59.000Z

    A process to produce magnesium diboride objects from boron objects with a similar form is presented. Boron objects are reacted with magnesium vapor at a predetermined time and temperature to form magnesium diboride objects having a morphology similar to the boron object's original morphology.

  14. ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Roadmap for the Automotive Market (May 1999) ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market (May 1999) autoroadmap.pdf More Documents & Publications Vehicle...

  15. Carbothermic Aluminum Production Using Scrap Aluminum As A Coolant

    DOE Patents [OSTI]

    LaCamera, Alfred F. (Trafford, PA)

    2002-11-05T23:59:59.000Z

    A process for producing aluminum metal by carbothermic reduction of alumina ore. Alumina ore is heated in the presence of carbon at an elevated temperature to produce an aluminum metal body contaminated with about 10-30% by wt. aluminum carbide. Aluminum metal or aluminum alloy scrap then is added to bring the temperature to about 900-1000.degree. C. and precipitate out aluminum carbide. The precipitated aluminum carbide is filtered, decanted, or fluxed with salt to form a molten body having reduced aluminum carbide content.

  16. Aluminum-Catalyzed Intramolecular Hydroamination of Aminoalkenes

    E-Print Network [OSTI]

    Koller, Juergen

    2011-01-01T23:59:59.000Z

    Aluminum-catalyzed intramolecular hydroamination ofgroup 13 metals such as aluminum are exceedingly inexpensive

  17. Aluminum monocarbonyl and aluminum isocarbonyl Steve S. Wesolowski,a)

    E-Print Network [OSTI]

    Crawford, T. Daniel

    Aluminum monocarbonyl and aluminum isocarbonyl Steve S. Wesolowski,a) T. Daniel Crawford,b) Justin of the aluminum monocarbonyl species AlCO and AlOC have been performed to predict the geometries, fragmentation, Ogden, and Oswald6 first isolated aluminum dicarbonyls in solid krypton and identified the species

  18. Method for magnesium sulfate recovery

    DOE Patents [OSTI]

    Gay, R.L.; Grantham, L.F.

    1987-08-25T23:59:59.000Z

    A method is described for obtaining magnesium sulfate substantially free from radioactive uranium from a slag containing the same and having a radioactivity level of at least about 7,000 pCi/gm. The slag is ground to a particle size of about 200 microns or less. The ground slag is then contacted with a concentrated sulfuric acid under certain prescribed conditions to produce a liquid product and a solid product. The particulate solid product and a minor amount of the liquid is then treated to produce a solid residue consisting essentially of magnesium sulfate substantially free of uranium and having a residual radioactivity level of less than 1,000 pCi/gm. In accordance with the preferred embodiment of the invention, a catalyst and an oxidizing agent are used during the initial acid treatment and a final solid residue has a radioactivity level of less than about 50 pCi/gm.

  19. Aluminum ion batteries: electrolytes and cathodes

    E-Print Network [OSTI]

    Reed, Luke

    2015-01-01T23:59:59.000Z

    Anodes for Aluminum-Air Batteries. J. Electrochem. Soc.Anodes for Aluminum-Air Batteries. J. Electrochem. Soc.ALLOYS FOR ALUMINUM AIR BATTERIES. J. Electrochem. Soc.

  20. DEFLECTION MEASUREMENTS OF 25 mm ALUMINUM COLLARS

    E-Print Network [OSTI]

    Peters, C.

    2010-01-01T23:59:59.000Z

    MEASUREMENTS OF 25 mm ALUMINUM COLLARS· C. Peters LawrenceMEASUREMENTS OF 25 mm ALUMINUM COLLARS" C. Peters Lawrenceinch thick 7075- T6 aluminum alloy plate. Inside corners

  1. Creating a GPS for aluminum ions | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Creating a GPS for aluminum ions Creating a GPS for aluminum ions Released: August 14, 2014 New approach pinpoints locations in simple zeolite catalysts Aluminum EXAFS and zeolite...

  2. Climate VISION: Private Sector Initiatives: Magnesium

    Office of Scientific and Technical Information (OSTI)

    Leading magnesium producers and casting companies are working with the U.S. Environmental Protection Agency (EPA) to alleviate the global environmental threat of climate...

  3. Coordination Chemistry in magnesium battery electrolytes: how...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a safe, cost-effective, and high energy density technology for large scale energy storage. However, the development of magnesium battery has been hindered by the limited...

  4. Climate VISION: Private Sector Initiatives: Magnesium: Resources...

    Office of Scientific and Technical Information (OSTI)

    Washington in February of 2002. The paper briefly describes the issues surrounding climate change and the Magnesium Industry, and gives an overview of the SF6 Emission...

  5. Climate VISION: Private Sector Initiatives: Magnesium: Resources...

    Office of Scientific and Technical Information (OSTI)

    Plant Assessments Greenhouse Gas Protocol (PDF 190 KB) Download Acrobat Reader Paper written by Bill Palmer, Cheminfo Services, Inc. Molten magnesium and its alloys are volatile...

  6. ITP Aluminum: Energy and Environmental Profile of the U.S. Aluminum...

    Broader source: Energy.gov (indexed) [DOE]

    aluminum.pdf More Documents & Publications ITP Aluminum: Technical Working Group on Inert Anode Technologies...

  7. DIFFUSION OF MAGNESIUM AND MICROSTRUCTURES IN Mg+ IMPLANTED SILICON CARBIDE

    SciTech Connect (OSTI)

    Jiang, Weilin; Edwards, Danny J.; Jung, Hee Joon; Wang, Zheming; Zhu, Zihua; Roosendaal, Timothy J.; Hu, Shenyang Y.; Henager, Charles H.; Kurtz, Richard J.; Wang, Yongqiang

    2014-08-28T23:59:59.000Z

    Following our previous reports [ 1- 3], further isochronal annealing (2 hrs.) of the monocrystalline 6H-SiC and polycrystalline CVD 3C-SiC was performed at 1573 and 1673 K in Ar environment. SIMS data indicate that observable Mg diffusion in 6H-SiC starts and a more rapid diffusion in CVD 3C-SiC occurs at 1573 K. The implanted Mg atoms tend to diffuse deeper into the undamaged CVD 3C-SiC. The microstructure with Mg inclusions in the as-implanted SiC has been initially examined using high-resolution STEM. The presence of Mg in the TEM specimen has been confirmed based on EDS mapping. Additional monocrystalline 3C-SiC samples have been implanted at 673 K to ion fluence 3 times higher than the previous one. RBS/C analysis has been performed before and after thermal annealing at 1573 K for 12 hrs. Isothermal annealing at 1573 K is being carried out and Mg depth profiles being measured. Microstructures in both the as-implanted and annealed samples are also being examined using STEM.

  8. Aluminum recycling from reactor walls: A source of contamination in a-Si:H thin films

    SciTech Connect (OSTI)

    Longeaud, C.; Ray, P. P.; Bhaduri, A.; Daineka, D.; Johnson, E. V.; Roca i Cabarrocas, P. [Laboratoire de Genie Electrique de Paris (UMR 8507 CNRS), Supelec, Universites Paris VI and XI, 11 Rue Joliot-Curie, Plateau de Moulon, 91190 Gif sur Yvette (France); Laboratoire de Physique des Interfaces et des Couches Minces (UMR 7647 CNRS), Ecole Polytechnique, 91128 Palaiseau Cedex (France)

    2010-11-15T23:59:59.000Z

    In this article, the authors investigate the contamination of hydrogenated amorphous silicon thin films with aluminum recycled from the walls and electrodes of the deposition reactor. Thin films of hydrogenated amorphous silicon were prepared under various conditions by a standard radio frequency plasma enhanced chemical vapor deposition process in two reactors, the chambers of which were constructed of either aluminum or stainless steel. The authors have studied the electronic properties of these thin films and have found that when using an aluminum reactor chamber, the layers are contaminated with aluminum recycled from the chamber walls and electrode. This phenomenon is observed almost independently of the deposition conditions. The authors show that this contamination results in slightly p-doped films and could be detrimental to the deposition of device grade films. The authors also propose a simple way to control and eventually suppress this contamination.

  9. Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up Research and Engineering for Light-Weight Vehicles Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up Research...

  10. Climate VISION: Private Sector Initiatives: Magnesium: Work Plans

    Office of Scientific and Technical Information (OSTI)

    Magnesium Association has developed a work plan for achieving the industry's Climate VISION commitment. Read the International Magnesium Association Work Plan (PDF 92 KB)...

  11. Local environment and composition of magnesium gallium layered...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    environment and composition of magnesium gallium layered double hydroxides determined from solid-state 1H and 71Ga NMR Local environment and composition of magnesium gallium...

  12. Tissue magnesium and calcium concentration in relation to magnesium and calcium intake in rats 

    E-Print Network [OSTI]

    Pinkham, Carrie Stanton

    1987-01-01T23:59:59.000Z

    , gestation, and lactation. The diets fed were as follows: low magnesium (200 mg Ng/kg and 5, 000 mg Ca/kg); calcium? supplemented (1, 200 mg Ng/kg and 16, 000 mg Ca/kg); low magnesium, calcium-supplemented (200 mg Ng/kg and 16, 000 mg Ca/kg); and control... was affected adversely by magnesium restriction; litter size was smaller and mortality rates the highest in animals fed the 1 cw magnesium diet. Pups of the magnesium ? restricted dams were lightest on Days 3 and 6 of lactation, while the pups of the dams...

  13. Scientists ignite aluminum water mix

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scientists ignite aluminum water mix Scientists ignite aluminum water mix Don't worry, that beer can you're holding is not going to spontaneously burst into flames. June 30, 2014...

  14. Amorphous silicon passivated contacts for diffused junction silicon solar cells

    SciTech Connect (OSTI)

    Bullock, J., E-mail: james.bullock@anu.edu.au; Yan, D.; Wan, Y.; Cuevas, A. [Research School of Engineering, The Australian National University, Canberra, ACT 0200 (Australia); Demaurex, B.; Hessler-Wyser, A.; De Wolf, S. [École Polytechnique Fédérale de Lausanne (EPFL), Institute of micro engineering (IMT), Photovoltaics and Thin Film Electronic Laboratory, Maladière 71, CH-200 Neuchâtel (Switzerland)

    2014-04-28T23:59:59.000Z

    Carrier recombination at the metal contacts is a major obstacle in the development of high-performance crystalline silicon homojunction solar cells. To address this issue, we insert thin intrinsic hydrogenated amorphous silicon [a-Si:H(i)] passivating films between the dopant-diffused silicon surface and aluminum contacts. We find that with increasing a-Si:H(i) interlayer thickness (from 0 to 16?nm) the recombination loss at metal-contacted phosphorus (n{sup +}) and boron (p{sup +}) diffused surfaces decreases by factors of ?25 and ?10, respectively. Conversely, the contact resistivity increases in both cases before saturating to still acceptable values of ? 50 m? cm{sup 2} for n{sup +} and ?100 m? cm{sup 2} for p{sup +} surfaces. Carrier transport towards the contacts likely occurs by a combination of carrier tunneling and aluminum spiking through the a-Si:H(i) layer, as supported by scanning transmission electron microscopy–energy dispersive x-ray maps. We explain the superior contact selectivity obtained on n{sup +} surfaces by more favorable band offsets and capture cross section ratios of recombination centers at the c-Si/a-Si:H(i) interface.

  15. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan (Mastic, NY); Reilly, James J. (Bellport, NY)

    2009-04-21T23:59:59.000Z

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  16. Regeneration of aluminum hydride

    DOE Patents [OSTI]

    Graetz, Jason Allan; Reilly, James J; Wegrzyn, James E

    2012-09-18T23:59:59.000Z

    The present invention provides methods and materials for the formation of hydrogen storage alanes, AlH.sub.x, where x is greater than 0 and less than or equal to 6 at reduced H.sub.2 pressures and temperatures. The methods rely upon reduction of the change in free energy of the reaction between aluminum and molecular H.sub.2. The change in free energy is reduced by lowering the entropy change during the reaction by providing aluminum in a state of high entropy, and by increasing the magnitude of the change in enthalpy of the reaction or combinations thereof.

  17. Overview of Aluminum

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in ManyDepartmentOutreach to MultifamilyAluminum Overview of Aluminum

  18. TiN coated aluminum electrodes for DC high voltage electron guns

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01T23:59:59.000Z

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloymore »(Ti-6Al-4V). Following gas conditioning, each TiN-coated aluminum electrode reached ?225?kV bias voltage while generating less than 100?pA of field emission (« less

  19. Membrane Purification Cell for Aluminum Recycling

    SciTech Connect (OSTI)

    David DeYoung; James Wiswall; Cong Wang

    2011-11-29T23:59:59.000Z

    Recycling mixed aluminum scrap usually requires adding primary aluminum to the scrap stream as a diluent to reduce the concentration of non-aluminum constituents used in aluminum alloys. Since primary aluminum production requires approximately 10 times more energy than melting scrap, the bulk of the energy and carbon dioxide emissions for recycling are associated with using primary aluminum as a diluent. Eliminating the need for using primary aluminum as a diluent would dramatically reduce energy requirements, decrease carbon dioxide emissions, and increase scrap utilization in recycling. Electrorefining can be used to extract pure aluminum from mixed scrap. Some example applications include producing primary grade aluminum from specific scrap streams such as consumer packaging and mixed alloy saw chips, and recycling multi-alloy products such as brazing sheet. Electrorefining can also be used to extract valuable alloying elements such as Li from Al-Li mixed scrap. This project was aimed at developing an electrorefining process for purifying aluminum to reduce energy consumption and emissions by 75% compared to conventional technology. An electrolytic molten aluminum purification process, utilizing a horizontal membrane cell anode, was designed, constructed, operated and validated. The electrorefining technology could also be used to produce ultra-high purity aluminum for advanced materials applications. The technical objectives for this project were to: - Validate the membrane cell concept with a lab-scale electrorefining cell; - Determine if previously identified voltage increase issue for chloride electrolytes holds for a fluoride-based electrolyte system; - Assess the probability that voltage change issues can be solved; and - Conduct a market and economic analysis to assess commercial feasibility. The process was tested using three different binary alloy compositions (Al-2.0 wt.% Cu, Al-4.7 wt.% Si, Al-0.6 wt.% Fe) and a brazing sheet scrap composition (Al-2.8 wt.% Si-0.7 wt.% Fe-0.8 wt.% Mn),. Purification factors (defined as the initial impurity concentration divided by the final impurity concentration) of greater than 20 were achieved for silicon, iron, copper, and manganese. Cell performance was measured using its current and voltage characteristics and composition analysis of the anode, cathode, and electrolytes. The various cells were autopsied as part of the study. Three electrolyte systems tested were: LiCl-10 wt. % AlCl3, LiCl-10 wt. % AlCl3-5 wt.% AlF3 and LiF-10 wt.% AlF3. An extended four-day run with the LiCl-10 wt.% AlCl3-5 wt.% AlF3 electrolyte system was stable for the entire duration of the experiment, running at energy requirements about one third of the Hoopes and the conventional Hall-Heroult process. Three different anode membranes were investigated with respect to their purification performance and survivability: a woven graphite cloth with 0.05 cm nominal thickness & > 90 % porosity, a drilled rigid membrane with nominal porosity of 33%, and another drilled rigid graphite membrane with increased thickness. The latter rigid drilled graphite was selected as the most promising membrane design. The economic viability of the membrane cell to purify scrap is sensitive to primary & scrap aluminum prices, and the cost of electricity. In particular, it is sensitive to the differential between scrap and primary aluminum price which is highly variable and dependent on the scrap source. In order to be economically viable, any scrap post-processing technology in the U.S. market must have a total operating cost well below the scrap price differential of $0.20-$0.40 per lb to the London Metal Exchange (LME), a margin of 65%-85% of the LME price. The cost to operate the membrane cell is estimated to be < $0.24/lb of purified aluminum. The energy cost is estimated to be $0.05/lb of purified aluminum with the remaining costs being repair and maintenance, electrolyte, labor, taxes and depreciation. The bench-scale work on membrane purification cell process has demonstrated technological advantages and subs

  20. Differences of growth response to aluminum excess of two Melaleuca trees differing in aluminum resistance

    E-Print Network [OSTI]

    Houman, Yoshifumi; Tahara, Ko; Shinmachi, Fumie; Noguchi, Akira; Satohiko, Sasaki; Hasegawa, Isao

    2009-01-01T23:59:59.000Z

    M, Yamanoshita T, Kojima K. , Role of aluminum-bindingligands in aluminum resistance of Eucalyptus camaldulensissoils, low pH and excess aluminum are the primary factors

  1. Synthesis and structural characterization of Al{sub 7}C{sub 3}N{sub 3}-homeotypic aluminum silicon oxycarbonitride, (Al{sub 7-x}Si{sub x})(O{sub y}C{sub z}N{sub 6-y-z}) (x{approx}1.2, y{approx}1.0 and z{approx}3.5)

    SciTech Connect (OSTI)

    Urushihara, Daisuke; Kaga, Motoaki; Asaka, Toru [Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555 (Japan); Nakano, Hiromi [Cooperative Research Facility Center, Toyohashi University of Technology, Toyohashi 441-8580 (Japan); Fukuda, Koichiro, E-mail: fukuda.koichiro@nitech.ac.jp [Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555 (Japan)

    2011-08-15T23:59:59.000Z

    A new aluminum silicon oxycarbonitride, (Al{sub 5.8}Si{sub 1.2})(O{sub 1.0}C{sub 3.5}N{sub 1.5}), has been synthesized and characterized by X-ray powder diffraction (XRPD), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX) and electron energy loss spectroscopy (EELS). The title compound is hexagonal with space group P6{sub 3}/mmc and unit-cell dimensions a=0.322508(4) nm, c=3.17193(4) nm and V=0.285717(6) nm{sup 3}. The atom ratios of Al:Si and those of O:C:N were, respectively, determined by EDX and EELS. The initial structural model was successfully derived from the XRPD data by the direct methods and further refined by the Rietveld method. The crystal is most probably composed of four types of domains with nearly the same fraction, each of which is isotypic to Al{sub 7}C{sub 3}N{sub 3} with space group P6{sub 3}mc. The existence of another new oxycarbonitride (Al{sub 6.6}Si{sub 1.4})(O{sub 0.7}C{sub 4.3}N{sub 2.0}), which must be homeotypic to Al{sub 8}C{sub 3}N{sub 4}, has been also demonstrated by XRPD and TEM. - Graphical abstract: A new oxycarbonitride discovered in the Al-Si-O-C-N system, (Al{sub 7-x}Si{sub x})(O{sub y}C{sub z}N{sub 6-y-z}) (x{approx}1.2, y{approx}1.0 and z{approx}3.5). The crystal is composed of four types of domains (I, II, III and IV), and hence the structure is represented by a split-atom model. Individual crystal structures can be regarded as layered structures, which consist of A-type [(Al, Si){sub 4}(O, C, N){sub 4}] unit layers and B-type [(Al, Si)(O, C, N){sub 2}] single layers. Highlights: > (Al{sub 5.8}Si{sub 1.2})(O{sub 1.0}C{sub 3.5}N{sub 1.5}) as a new aluminum silicon oxycarbonitride. > Crystal structure is determined and represented by a split-atom model. > Existence of another new oxycarbonitride (Al{sub 6.6}Si{sub 1.4})(O{sub 0.7}C{sub 4.3}N{sub 2.0}) is demonstrated. > Both new materials are formed by oxidation and nitridation of (Al, Si){sub 6}(O, C){sub 5}.

  2. aluminum matrix composites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... ...... ..... ... . . 3 Conventional Aluminum Brazing ... 4 Aluminum Composite Joining ... 5 Aluminum Joining by Unconventional Methods Eagar, Thomas W. 2...

  3. The 22nd International Photovoltaic Science and Engineering Conference, November 05-09, 2012, Hangzhou, China Gettering of n-type multicrystalline silicon solar cells by

    E-Print Network [OSTI]

    , Hangzhou, China Gettering of n-type multicrystalline silicon solar cells by phosphorus diffusion, boron in heavily dislocated regions. 1. INTRODUCTION N-type multicrystalline silicon has great potential as solar+ diffused region in n- type silicon solar cells with either aluminum annealing or boron diffusion are good

  4. Magnesium Front End Design and Development

    Broader source: Energy.gov (indexed) [DOE]

    by: Alan A. Luo and R. C. McCune Presented by: James Quinn, General Motors Unibody Architecture 3-piece Mg front end (bodyframe) USAMP AMD 603 - Magnesium Front End Design and...

  5. Magnesium Research and Technology Development: Project 48976

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advise DOE on criticalkey funding areas for Mg 3 z z Approach Approach Approach Increase automotive industry awareness in the use of Mg Develop and maintain the Magnesium R&D...

  6. Climate VISION: Private Sector Initiatives: Magnesium

    Office of Scientific and Technical Information (OSTI)

    atmosphere, SF6 will persist for 3,200 years and is more than 23,000 times as strong a global warming gas as carbon dioxide (CO2). Read the U.S. and International Magnesium...

  7. Low-cost, deterministic quasi-periodic photonic structures for light trapping in thin film silicon solar cells

    E-Print Network [OSTI]

    Sheng, Xing

    Light trapping has been an important issue for thin film silicon solar cells because of the low absorption coefficient in the near infrared range. In this paper, we present a photonic structure which combines anodic aluminum ...

  8. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon metal and alloys (excluding semiconductor-grade silicon)

    E-Print Network [OSTI]

    metal: Brazil, 37%; South Africa, 25%; Canada, 14%; Norway, 6%; and other, 18%. Total: Brazil, 20%; China, 16%; South Africa, 13%; Canada, 12%; and other, 39%. Tariff: Item Number Normal Trade Relations energy costs. Demand for silicon metal comes primarily from the aluminum and chemical industries

  9. Magnesium-phosphate-glass cements with ceramic-type properties

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.

    1982-09-23T23:59:59.000Z

    Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate, exhibits rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

  10. Magnesium phosphate glass cements with ceramic-type properties

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY); Kukacka, Lawrence E. (Port Jefferson, NY)

    1984-03-13T23:59:59.000Z

    Rapid setting magnesium phosphate (Mg glass) cementitious materials consisting of magnesium phosphate cement paste, polyborax and water-saturated aggregate exhibiting rapid setting and high early strength characteristics. The magnesium glass cement is prepared from a cation-leachable powder and a bivalent metallic ion-accepting liquid such as an aqueous solution of diammonium phosphate and ammonium polyphosphate. The cation-leachable powder includes a mixture of two different magnesium oxide powders processed and sized differently which when mixed with the bivalent metallic ion-accepting liquid provides the magnesium glass cement consisting primarily of magnesium ortho phosphate tetrahydrate, with magnesium hydroxide and magnesium ammonium phosphate hexahydrate also present. The polyborax serves as a set-retarder. The resulting magnesium mono- and polyphosphate cements are particularly suitable for use as a cementing matrix in rapid repair systems for deteriorated concrete structures as well as construction materials and surface coatings for fireproof structures.

  11. Possible Reasons Why Aluminum is a Beneficial Element for Melastoma malabathricum, an Aluminum Accumulator

    E-Print Network [OSTI]

    Watanabe, Toshihiro; Osaki, Mitsuru

    2009-01-01T23:59:59.000Z

    of adaptation to high aluminum condition in native plantit has been well known that aluminum (Al) toxicity restricts

  12. Aluminum Carbothermic Technology

    SciTech Connect (OSTI)

    Bruno, Marshall J.

    2005-03-31T23:59:59.000Z

    This report documents the non-proprietary research and development conducted on the Aluminum Carbothermic Technology (ACT) project from contract inception on July 01, 2000 to termination on December 31, 2004. The objectives of the program were to demonstrate the technical and economic feasibility of a new carbothermic process for producing commercial grade aluminum, designated as the ''Advanced Reactor Process'' (ARP). The scope of the program ranged from fundamental research through small scale laboratory experiments (65 kW power input) to larger scale test modules at up to 1600 kW power input. The tasks included work on four components of the process, Stages 1 and 2 of the reactor, vapor recovery and metal alloy decarbonization; development of computer models; and economic analyses of capital and operating costs. Justification for developing a new, carbothermic route to aluminum production is defined by the potential benefits in reduced energy, lower costs and more favorable environmental characteristics than the conventional Hall-Heroult process presently used by the industry. The estimated metrics for these advantages include energy rates at approximately 10 kWh/kg Al (versus over 13 kWh/kg Al for Hall-Heroult), capital costs as low as $1250 per MTY (versus 4,000 per MTY for Hall-Heroult), operating cost reductions of over 10%, and up to 37% reduction in CO2 emissions for fossil-fuel power plants. Realization of these benefits would be critical to sustaining the US aluminum industries position as a global leader in primary aluminum production. One very attractive incentive for ARP is its perceived ability to cost effectively produce metal over a range of smelter sizes, not feasible for Hall-Heroult plants which must be large, 240,000 TPY or more, to be economical. Lower capacity stand alone carbothermic smelters could be utilized to supply molten metal at fabrication facilities similar to the mini-mill concept employed by the steel industry. Major accomplishments for the program include definition of the system thermo-chemistry, demonstration of reactor stage 1, development of reactor stage 2 critical components in a 500 kW module, experimental determination of the vapor recovery reactor fundamentals, detailed design and installation of an advanced stage 1/vapor recovery reactor, feasibility of efficient separation of Al-C metal alloy product, updated capital and operating cost estimates, and development of computer models for all steps of the Advanced Reactor Process.

  13. Amorphous Silicon

    Broader source: Energy.gov [DOE]

    DOE has a proven track record of funding successes in amorphous silicon (a-Si)research. A list of current projects, summary of the benefits, and discussion on the production and manufacturing of...

  14. Hydrogen storage characteristics of nanograined free-standing magnesium–nickel films

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    free-standing magnesium–nickel ?lms Matthew Rogers · StevenFree-standing magnesium–nickel (Mg–Ni) ?lms with extensivefree- standing magnesium–nickel ?lms. Magnesium hydride (MgH

  15. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys and metal produced in the United States in 2013

    E-Print Network [OSTI]

    .19 billion. Three companies produced silicon materials in seven plants, all east of the Mississippi River company produced both products at two plants. Most ferrosilicon was consumed in the ferrous foundry producers of aluminum and aluminum alloys and the chemical industry. The semiconductor and solar industries

  16. Modeling Texture Evolution during Recrystallization in Aluminum

    E-Print Network [OSTI]

    Rollett, Anthony D.

    Modeling Texture Evolution during Recrystallization in Aluminum Abhijit Brahme1,2 , Joseph Fridy3, Aluminum, Grain Boundary Mobility, Nucleation, Oriented Growth, Oriented Nucleation, Stored Energy, Monte Carlo Modeling. #12;Modeling Texture Evolution during Recrystallization in Aluminum 2 1. Introduction

  17. Production of aluminum metal by electrolysis of aluminum sulfide

    DOE Patents [OSTI]

    Minh, N.Q.; Loutfy, R.O.; Yao, N.P.

    1982-04-01T23:59:59.000Z

    Metallic aluminum may be produced by the electrolysis of Al/sub 2/S/sub 3/ at 700 to 800/sup 0/C in a chloride melt composed of one or more alkali metal chlorides, and one or more alkaline earth metal chlorides and/or aluminum chloride to provide improved operating characteristics of the process.

  18. Fabrication and testing of oxidized porous silicon field emitter strips 

    E-Print Network [OSTI]

    Madduri, Vasanta Bhanu

    1992-01-01T23:59:59.000Z

    Fig. 1 Cross-section of Thin-film Field Emission Structure (After Spindt, et al. [7] ). Mo Silicon dioxide Silicon substrate Axis of rotation ~' Evaporant Aluminum release layer Mo SiO Si Evaporant Deposition for cone formation Etch off... release layer Fig. 2 Fabrication Procedure to Produce Mo Cones silicon substrates with 1-1, 5 pm of thermally grown oxide on them. Holes of 1. 5-2 ltm diameter are micro-machined in the oxide layer using electron beam lithography. Mo serves as an etch...

  19. Aluminum | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platform is alwaysISOSource Heat PumpAllegations ofAlumina and Aluminum

  20. Climate VISION: Private Sector Initiatives: Aluminum

    Office of Scientific and Technical Information (OSTI)

    Voluntary Aluminum Industry Partnership (VAIP), representing 98% of primary aluminum production in the United States, have committed under the Climate VISION program to a direct...

  1. Aluminum-tungsten fiber composites with cylindrical geometry and controlled architecture of tungsten reinforcement

    E-Print Network [OSTI]

    Lucchese, Carl Joesph

    2010-01-01T23:59:59.000Z

    Aluminum……………………………………………………………………… Aluminum Alloy 6061-Figure 30 - Aluminum alloy 6061 tubes used to assembleencapsulated within the aluminum alloy 6061 matrix………………..

  2. Synthesis and structural characterization of Al{sub 4}Si{sub 2}C{sub 5}-homeotypic aluminum silicon oxycarbide, (Al{sub 6-x}Si{sub x})(O{sub y}C{sub 5-y}) (x{approx}0.8 and y{approx}1.6)

    SciTech Connect (OSTI)

    Kaga, Motoaki; Urushihara, Daisuke; Iwata, Tomoyuki; Sugiura, Keita [Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555 (Japan); Nakano, Hiromi [Cooperative Research Facility Center, Toyohashi University of Technology, Toyohashi 441-8580 (Japan); Fukuda, Koichiro, E-mail: fukuda.koichiro@nitech.ac.j [Department of Environmental and Materials Engineering, Nagoya Institute of Technology, Nagoya 466-8555 (Japan)

    2010-09-15T23:59:59.000Z

    We have prepared a new layered oxycarbide, [Al{sub 5.25(5)}Si{sub 0.75(5)}][O{sub 1.60(7)}C{sub 3.40(7)}], by isothermal heating of (Al{sub 4.4}Si{sub 0.6})(O{sub 1.0}C{sub 3.0}) at 2273 K near the carbon-carbon monoxide buffer. The crystal structure was characterized using X-ray powder diffraction, transmission electron microscopy and energy dispersive X-ray spectroscopy (EDX). The title compound is trigonal with space group R3m (centrosymmetric), Z=3, and hexagonal cell dimensions a=0.32464(2) nm, c=4.00527(14) nm and V=0.36556(3) nm{sup 3}. The atom ratios Al:Si were determined by EDX, and the initial structural model was derived by the direct methods. The final structural model showed the positional disordering of one of the three types of Al/Si sites. The reliability indices were R{sub wp}=4.45% (S=1.30), R{sub p}=3.48%, R{sub B}=2.27% and R{sub F}=1.25%. The crystal is composed of three types of domains with nearly the same fraction, one of which has the crystal structure of space group R3-bar m. The crystal structure of the remaining two domains, which are related by pseudo-symmetry inversion, is noncentrosymmetric with space group R3m. - Graphical Abstract: A new aluminum silicon oxycarbide, (Al{sub 6-x}Si{sub x})(O{sub y}C{sub 5-y}) (x{approx}0.8 and y{approx}1.6). The crystal is composed of three types of domains (I, II and III), and hence the structure is represented by a split-atom model. Individual crystal structures can be regarded as layered structures, which consist of A-type [(Al,Si){sub 4}(O,C){sub 4}] unit layers and B-type [(Al,Si)(O,C){sub 2}] single layers.

  3. Friction Stir and Ultrasonic Solid State Joining of Magnesium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Ultrasonic Solid State Joining of Magnesium to Steel Friction Stir and Ultrasonic Solid State Joining of Magnesium to Steel 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

  4. AMD 601 High Integrity -Magnesium Automotive Components (HI-MAC...

    Energy Savers [EERE]

    601 High Integrity -Magnesium Automotive Components (HI-MAC) AMD 601 High Integrity -Magnesium Automotive Components (HI-MAC) Presentation from the U.S. DOE Office of Vehicle...

  5. The magnesium nutrition of American upland and Egyptian cottons 

    E-Print Network [OSTI]

    Helmy, Hussein

    1956-01-01T23:59:59.000Z

    ~ ~ ~ ~ ~ ~ ~ ~ 19 ~ ~ ~ SS ~ ~ ~ ~ ~ ~ ~ S7 LIST OF TABLES Page Effect of magnesium on stem he1ghts . . . 52 Relation of magnesium supply to average fresh and dry weight of cotton plants at 45 days ~ ~ \\ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 55 Relation of magnesium supply... to average fresh and dry weight of cotton plants at 85 days ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 54 Relation of magnesium supply to average number of flowers produced per plant 1n three day intervals, percentage shedding, percentage boll-set and rel- ative...

  6. SOLID STATE JOINING OF MAGNESIUM TO STEEL

    SciTech Connect (OSTI)

    Jana, Saumyadeep; Hovanski, Yuri; Pilli, Siva Prasad; Field, David P.; Yu, Hao; Pan, Tsung-Yu; Santella, M. L.

    2012-06-04T23:59:59.000Z

    Friction stir welding and ultrasonic welding techniques were applied to join automotive magnesium alloys to steel sheet. The effect of tooling and process parameters on the post-weld microstructure, texture and mechanical properties was investigated. Static and dynamic loading were utilized to investigate the joint strength of both cast and wrought magnesium alloys including their susceptibility and degradation under corrosive media. The conditions required to produce joint strengths in excess of 75% of the base metal strength were determined, and the effects of surface coatings, tooling and weld parameters on weld properties are presented.

  7. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys and metal produced in the United States in 2012

    E-Print Network [OSTI]

    .44 billion. Three companies produced silicon materials in seven plants east of the Mississippi River. Ferrosilicon and metallurgical-grade silicon metal were each produced in four plants. One company produced both and aluminum alloys and the chemical industry. The semiconductor and solar industries, which manufacture chips

  8. (Data in thousand metric tons of silicon content unless otherwise noted) Domestic Production and Use: Estimated value of silicon alloys and metal produced in the United States in 2011

    E-Print Network [OSTI]

    ,400 million. Two companies produced silicon materials in seven plants east of the Mississippi River. Ferrosilicon and metallurgical-grade silicon metal were each produced in four plants. One company produced both and aluminum alloys and the chemical industry. The semiconductor and solar industries, which manufacture chips

  9. Aluminum Zintl anion moieties within sodium aluminum clusters

    SciTech Connect (OSTI)

    Wang, Haopeng; Zhang, Xinxing; Ko, Yeon Jae; Grubisic, Andrej; Li, Xiang; Ganteför, Gerd; Bowen, Kit H., E-mail: AKandalam@wcupa.edu, E-mail: kiran@mcneese.edu, E-mail: kbowen@jhu.edu [Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218 (United States); Schnöckel, Hansgeorg [Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany)] [Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, 76128 Karlsruhe (Germany); Eichhorn, Bryan W. [Department of Chemistry, University of Maryland at College Park, College Park, Maryland 20742 (United States)] [Department of Chemistry, University of Maryland at College Park, College Park, Maryland 20742 (United States); Lee, Mal-Soon; Jena, P. [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284 (United States)] [Department of Physics, Virginia Commonwealth University, Richmond, Virginia 23284 (United States); Kandalam, Anil K., E-mail: AKandalam@wcupa.edu, E-mail: kiran@mcneese.edu, E-mail: kbowen@jhu.edu [Department of Physics, West Chester University of Pennsylvania, West Chester, Pennsylvania 19383 (United States); Kiran, Boggavarapu, E-mail: AKandalam@wcupa.edu, E-mail: kiran@mcneese.edu, E-mail: kbowen@jhu.edu [Department of Chemistry, McNeese State University, Lake Charles, Louisiana 70609 (United States)] [Department of Chemistry, McNeese State University, Lake Charles, Louisiana 70609 (United States)

    2014-02-07T23:59:59.000Z

    Through a synergetic combination of anion photoelectron spectroscopy and density functional theory based calculations, we have established that aluminum moieties within selected sodium-aluminum clusters are Zintl anions. Sodium–aluminum cluster anions, Na{sub m}Al{sub n}{sup ?}, were generated in a pulsed arc discharge source. After mass selection, their photoelectron spectra were measured by a magnetic bottle, electron energy analyzer. Calculations on a select sub-set of stoichiometries provided geometric structures and full charge analyses for both cluster anions and their neutral cluster counterparts, as well as photodetachment transition energies (stick spectra), and fragment molecular orbital based correlation diagrams.

  10. Spray Rolling Aluminum Strip

    SciTech Connect (OSTI)

    Lavernia, E.J.; Delplanque, J-P; McHugh, K.M.

    2006-05-10T23:59:59.000Z

    Spray forming is a competitive low-cost alternative to ingot metallurgy for manufacturing ferrous and non-ferrous alloy shapes. It produces materials with a reduced number of processing steps, while maintaining materials properties, with the possibility of near-net-shape manufacturing. However, there are several hurdles to large-scale commercial adoption of spray forming: 1) ensuring strip is consistently flat, 2) eliminating porosity, particularly at the deposit/substrate interface, and 3) improving material yield. Through this program, a new strip/sheet casting process, termed spray rolling, has been developed, which is an innovative manufacturing technique to produce aluminum net-shape products. Spray rolling combines the benefits of twin-roll casting and conventional spray forming, showing a promising potential to overcome the above hurdles associated with spray forming. Spray rolling requires less energy and generates less scrap than conventional processes and, consequently, enables the development of materials with lower environmental impacts in both processing and final products. Spray Rolling was developed as a collaborative project between the University of California-Davis, the Colorado School of Mines, the Idaho National Engineering and Environmental Laboratory, and an industry team. The following objectives of this project were achieved: (1) Demonstration of the feasibility of the spray rolling process at the bench-scale level and evaluation of the materials properties of spray rolled aluminum strip alloys; and (2) Demonstration of 2X scalability of the process and documentation of technical hurdles to further scale up and initiate technology transfer to industry for eventual commercialization of the process.

  11. EUROSPF Conference APPLICATION TECHNOLOGY OF ALUMINUM BLOW

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    6th EUROSPF Conference APPLICATION TECHNOLOGY OF ALUMINUM BLOW FORMING FOR AUTOMOTIVE CLOSURE PANEL Replacement by aluminum for the closure panels is one of the common methods for lightening car body. However. As a solution to cover the low stamping formability of aluminum, Blow forming technology of aluminum which

  12. Rare-earth doped aluminum oxide lasers for silicon photonics

    E-Print Network [OSTI]

    Magden, Emir Salih

    2014-01-01T23:59:59.000Z

    A reliable and CMOS-compatible deposition process for amorphous Al2O3 based active photonic components has been developed. Al2O3 films were reactively sputtered, where process optimization was achieved at a temperature of ...

  13. Electrolyte treatment for aluminum reduction

    DOE Patents [OSTI]

    Brown, Craig W. (Seattle, WA); Brooks, Richard J. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA); Juric, Drago D. (Bulleen, AU)

    2002-01-01T23:59:59.000Z

    A method of treating an electrolyte for use in the electrolytic reduction of alumina to aluminum employing an anode and a cathode, the alumina dissolved in the electrolyte, the treating improving wetting of the cathode with molten aluminum during electrolysis. The method comprises the steps of providing a molten electrolyte comprised of ALF.sub.3 and at least one salt selected from the group consisting of NaF, KF and LiF, and treating the electrolyte by providing therein 0.004 to 0.2 wt. % of a transition metal or transition metal compound for improved wettability of the cathode with molten aluminum during subsequent electrolysis to reduce alumina to aluminum.

  14. Improved method of preparing p-i-n junctions in amorphous silicon semiconductors

    DOE Patents [OSTI]

    Madan, A.

    1984-12-10T23:59:59.000Z

    A method of preparing p/sup +/-i-n/sup +/ junctions for amorphous silicon semiconductors includes depositing amorphous silicon on a thin layer of trivalent material, such as aluminum, indium, or gallium at a temperature in the range of 200/sup 0/C to 250/sup 0/C. At this temperature, the layer of trivalent material diffuses into the amorphous silicon to form a graded p/sup +/-i junction. A layer of n-type doped material is then deposited onto the intrinsic amorphous silicon layer in a conventional manner to finish forming the p/sup +/-i-n/sup +/ junction.

  15. Process for fabricating device structures for real-time process control of silicon doping

    DOE Patents [OSTI]

    Weiner, Kurt H. (San Jose, CA)

    2001-01-01T23:59:59.000Z

    Silicon device structures designed to allow measurement of important doping process parameters immediately after the doping step has occurred. The test structures are processed through contact formation using standard semiconductor fabrication techniques. After the contacts have been formed, the structures are covered by an oxide layer and an aluminum layer. The aluminum layer is then patterned to expose the contact pads and selected regions of the silicon to be doped. Doping is then performed, and the whole structure is annealed with a pulsed excimer laser. But laser annealing, unlike standard annealing techniques, does not effect the aluminum contacts because the laser light is reflected by the aluminum. Once the annealing process is complete, the structures can be probed, using standard techniques, to ascertain data about the doping step. Analysis of the data can be used to determine probable yield reductions due to improper execution of the doping step and thus provide real-time feedback during integrated circuit fabrication.

  16. aluminum metal matrix: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Abstract Solidification of metal aluminum and aluminum alloys is modeled on uneven surfaces char- acterized by sinusoidal curves Zabaras, Nicholas J. 108 Aluminum-tungsten...

  17. Aluminum across the Americas: Caribbean Mobilities and Transnational American Studies

    E-Print Network [OSTI]

    Sheller, Mimi

    2013-01-01T23:59:59.000Z

    E. Jamaica in the World Aluminum Industry, 1838–1973, Vol.2007. Doordan, Dennis. “Promoting Aluminum: Designers andthe American Aluminum Industry. ” Design Issues 9, no. 2 (

  18. Aluminum-detoxifying compounds in roots of Eucalyptus camaldulensis

    E-Print Network [OSTI]

    Tahara, Ko; Hashida, Koh; Ohara, Seiji; Kojima, Katsumi; Shinohara, Kenji

    2009-01-01T23:59:59.000Z

    M, Yamanoshita T, Kojima K, Role of aluminum-bindingligands in aluminum resistance of Eucalyptus camaldulensisH, Sasaki S, Kojima K. Aluminum distribution and reactive

  19. Lithium aluminum/iron sulfide battery having lithium aluminum and silicon as negative electrode

    DOE Patents [OSTI]

    Gilbert, M.; Kaun, T.

    1984-01-20T23:59:59.000Z

    A method of making a negative electrode, the electrode made thereby and a secondary electrochemical c

  20. Processes for producing low cost, high efficiency silicon solar cells

    DOE Patents [OSTI]

    Rohatgi, Ajeet (Marietta, GA); Chen, Zhizhang (Duluth, GA); Doshi, Parag (Atlanta, GA)

    1996-01-01T23:59:59.000Z

    Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime .tau. and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. Silicon solar cell efficiencies of 16.9% have been achieved. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime .tau. and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO.sub.x.

  1. Determination of the concentrations of magnesium and aluminum in alloys by laser produced atomic emission spectroscopy

    E-Print Network [OSTI]

    Ashe, William Monroe

    1997-01-01T23:59:59.000Z

    in forensic studies. It would be able to analyze the residue left at a crime scene, or analyze the layers of paint on the ceiling of the Sistine Chapel. ~ It can be used to analyze the ratio of ionic to atomic species ejected by a sample that has been... density per pulse at the focus point of the laser are important. A "short" laser pulse will eject a relatively small amount of material. However, pulses that have a duration on the order of a millisecond can dig deep holes into the sample. In OES a...

  2. Magnesium Replacement of Aluminum Cast Components in a Production V6 Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment ofLetterEconomyDr. ErnestMID-CAREERofBacteriumto Effect

  3. Lead magnesium niobate actuator for micropositioning

    DOE Patents [OSTI]

    Swift, C.D.; Bergum, J.W.

    1994-10-25T23:59:59.000Z

    An improved lead magnesium niobate actuator is disclosed comprising a cylindrical lead magnesium niobate crystal stack mounted in a cylindrical casing wherein a bias means, such as one or more belleville washers, is located between one end of the crystal stack and a partially closed end of the casing; and adjustment means are provided which bear against the opposite end of the crystal stack, whereby an adjustable compressive force is constantly applied against the crystal stack, whether the crystal stack is actuated in an extended position, or is in an unactuated contracted position. In a preferred embodiment, cooling ports are provided for the circulation of coolant in the actuator to cool the crystal stack, and provision is made for removal and replacement of the crystal stack without disconnecting the actuator from the external device being actuated. 3 figs.

  4. Lead magnesium niobate actuator for micropositioning

    DOE Patents [OSTI]

    Swift, Charles D. (Livermore, CA); Bergum, John W. (Concord, CA)

    1994-01-01T23:59:59.000Z

    An improved lead magnesium niobate actuator is disclosed comprising a cylindrical lead magnesium niobate crystal stack mounted in a cylindrical casing wherein a bias means, such as one or more belleville washers, is located between one end of the crystal stack and a partially closed end of the casing; and adjustment means are provided which bear against the opposite end of the crystal stack, whereby an adjustable compressive force is constantly applied against the crystal stack, whether the crystal stack is actuated in an extended position, or is in an unactuated contracted position. In a preferred embodiment, cooling ports are provided for the circulation of coolant in the actuator to cool the crystal stack, and provision is made for removal and replacement of the crystal stack without disconnecting the actuator from the external device being actuated.

  5. Joining of 6061 Aluminum Matrix-Ceramic Particle Reinforced Composites

    E-Print Network [OSTI]

    Eagar, Thomas W.

    ) ) Joining of 6061 Aluminum Matrix-Ceramic Particle Reinforced Composites by R. Kiehn and T. W................... .. ....... ... ... 3 Literature Review ......... ...... ..... ... . . 3 Conventional Aluminum Brazing ........ 4 Aluminum Composite Joining ........... 5 Aluminum Joining by Unconventional Methods

  6. Electrolytic Cell For Production Of Aluminum From Alumina

    DOE Patents [OSTI]

    Bradford, Donald R (Underwood, WA); Barnett, Robert J. (Goldendale, WA); Mezner, Michael B. (Sandy, OR)

    2004-11-02T23:59:59.000Z

    An electrolytic cell for producing aluminum from alumina having a reservoir for collecting molten aluminum remote from the electrolysis.

  7. antenatal magnesium sulfate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    was reduced by 30 % at 48 hours of the treatment. Results. After magnesium sulfate infusion, 90 % prolonged their pregnancy for>48 hours. Combination therapy was effective in 95...

  8. Climate VISION: Private Sector Initiatives: Magnesium: GHG Inventory...

    Office of Scientific and Technical Information (OSTI)

    GHG Inventory Protocols The Magnesium Industry Partnership's SF6 emissions tracking and reporting software tool (Excel based) can be accessed by visiting the Partnership's...

  9. Climate VISION: Private Sector Initiatives: Magnesium: GHG Information

    Office of Scientific and Technical Information (OSTI)

    GHG Information The magnesium industry directly emits SF6 from its primary metal production, parts casting, and recycling operations. In 2005, the industry's SF6 emissions were...

  10. Magnesium Front End Research and Development AMD 604

    Broader source: Energy.gov (indexed) [DOE]

    and sheet forming Improved high-volume manufacturing techniques for joining and corrosion protection of magnesium structures. Improved knowledge base in Mg...

  11. Magnesium Front End Research and Development AMD 604

    Broader source: Energy.gov (indexed) [DOE]

    high volume manufacturing techniques for joining of Mg - Large- scale joining and corrosion protection of magnesium structures. * Corrosion: Durability of Mg-intensive...

  12. az31 wrought magnesium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MgOTiB2. Open Access Theses and Dissertations Summary: ??The stoichiometric Self-propagating High-temperature Synthesis (SHS) thermite reaction involving magnesium oxide...

  13. Current technologies and trends of aluminum design

    E-Print Network [OSTI]

    Chen, Michael, 1981-

    2004-01-01T23:59:59.000Z

    A literature review of current aluminum technology in the building and construction industry was carried out. Aluminum is an ideal material for building in corrosive environments and for building structures where small ...

  14. Micro Joining of Aluminum Graphite Composites 

    E-Print Network [OSTI]

    Velamati, Manasa

    2012-07-16T23:59:59.000Z

    Advanced aluminum graphite composites have unique thermal properties due to opposing coefficients of thermal expansion of aluminum and graphite. The thermal and mechanical properties of such composites are anisotropic due to directional properties...

  15. Reaction of Aluminum with Water to Produce Hydrogen

    E-Print Network [OSTI]

    Aluminum Alloys PROPERTIES OF THE ALUMINUM-WATER REACTIONS RELATIVE ........... 14 TO ON-BOARD SYSTEM aluminum alloys such as aluminum-lithium and aluminum-gallium has been studied. In this case, the molten nature of the alloy prevents the development of a coherent and adherent aluminum oxide layer. However

  16. Aluminum-carbon composite electrode

    DOE Patents [OSTI]

    Farahmandi, C.J.; Dispennette, J.M.

    1998-07-07T23:59:59.000Z

    A high performance double layer capacitor having an electric double layer formed in the interface between activated carbon and an electrolyte is disclosed. The high performance double layer capacitor includes a pair of aluminum impregnated carbon composite electrodes having an evenly distributed and continuous path of aluminum impregnated within an activated carbon fiber preform saturated with a high performance electrolytic solution. The high performance double layer capacitor is capable of delivering at least 5 Wh/kg of useful energy at power ratings of at least 600 W/kg. 3 figs.

  17. Transmissive metallic contact for amorphous silicon solar cells

    DOE Patents [OSTI]

    Madan, A.

    1984-11-29T23:59:59.000Z

    A transmissive metallic contact for amorphous silicon semiconductors includes a thin layer of metal, such as aluminum or other low work function metal, coated on the amorphous silicon with an antireflective layer coated on the metal. A transparent substrate, such as glass, is positioned on the light reflective layer. The metallic layer is preferably thin enough to transmit at least 50% of light incident thereon, yet thick enough to conduct electricity. The antireflection layer is preferably a transparent material that has a refractive index in the range of 1.8 to 2.2 and is approximately 550A to 600A thick.

  18. Preventing light-induced degradation in multicrystalline silicon

    SciTech Connect (OSTI)

    Lindroos, J., E-mail: jeanette.lindroos@aalto.fi; Boulfrad, Y.; Yli-Koski, M.; Savin, H. [Department of Micro and Nanosciences, Aalto University, Tietotie 3, 02150 Espoo (Finland)

    2014-04-21T23:59:59.000Z

    Multicrystalline silicon (mc-Si) is currently dominating the silicon solar cell market due to low ingot costs, but its efficiency is limited by transition metals, extended defects, and light-induced degradation (LID). LID is traditionally associated with a boron-oxygen complex, but the origin of the degradation in the top of the commercial mc-Si brick is revealed to be interstitial copper. We demonstrate that both a large negative corona charge and an aluminum oxide thin film with a built-in negative charge decrease the interstitial copper concentration in the bulk, preventing LID in mc-Si.

  19. Aluminum in Superconducting Magnets Robert J. Weggel

    E-Print Network [OSTI]

    McDonald, Kirk

    is aluminum, either ultrapure, as quenchstabilization matrix metal, and/or alloyed and coldworked and heat for magnets in which the stresses and strains are modest. The strongest aluminum alloy commercially available., "Mechanical properties of commercial aluminum alloys at 253o C (­423o F)," NATO ARW, Kiev 713 Sept. 2003

  20. MODELING OF ALUMINUM NANOPARTICLE FORMATION R. Schefflan

    E-Print Network [OSTI]

    MODELING OF ALUMINUM NANOPARTICLE FORMATION R. Schefflan D. Kalyon S. Kovenklioglu Stevens Picatinny Arsenal's process for making alumina coated nanoparticles of aluminum involves the conversion of gaseous aluminum, in the presence of helium carrier gas, to solid nanoparticles and their subsequent

  1. Aluminum: Principled Scenario Exploration through Minimality

    E-Print Network [OSTI]

    Dougherty, Daniel J.

    Aluminum: Principled Scenario Exploration through Minimality Tim Nelson1, Salman Saghafi1, Daniel J. We present Aluminum, a modification of Alloy that presents only minimal scenarios: those that contain no more than is necessary. Aluminum lets users explore the scenario space by adding to scenarios

  2. Aluminum--2004 5. Areferencethatincludesasectionmark()isfoundintheinternet

    E-Print Network [OSTI]

    Aluminum--2004 5. Areferencethatincludesasectionmark(§)isfoundintheinternet ReferenceCitedsection. Aluminum ByPatriciaA.Plunkert Domestic survey data and tables were prepared by Benjamin S. Goff.S.GeologicalSurvey(uSGS)requestforproductiondata. CommercialDevelopmentCo.(CDC)ofSt.louis,mO, boughtKaiserAluminumCorp.'s200,000-metric-ton-per-year (t

  3. Aluminum: Principled Scenario Exploration through Minimality

    E-Print Network [OSTI]

    Krishnamurthi, Shriram

    Aluminum: Principled Scenario Exploration through Minimality Tim Nelson1, Salman Saghafi1, Daniel J Aluminum, a modification of Alloy that presents only minimal scenarios: those that contain no more than is necessary. Aluminum lets users explore the scenario space by adding to scenarios and backtracking. It also

  4. Development of High-Volume Warm Forming of Low-Cost Magnesium...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Magnesium Sheet AMD 602 Project Team * OEM's - Chrysler, Ford , GM * Contracts - Troy Tooling Technologies - Materials Suppliers * Magnesium Elektron * POSCO * Thyssen * CSIRO *...

  5. Buried oxide layer in silicon

    DOE Patents [OSTI]

    Sadana, Devendra Kumar (Pleasantville, NY); Holland, Orin Wayne (Lenoir, TN)

    2001-01-01T23:59:59.000Z

    A process for forming Silicon-On-Insulator is described incorporating the steps of ion implantation of oxygen into a silicon substrate at elevated temperature, ion implanting oxygen at a temperature below 200.degree. C. at a lower dose to form an amorphous silicon layer, and annealing steps to form a mixture of defective single crystal silicon and polycrystalline silicon or polycrystalline silicon alone and then silicon oxide from the amorphous silicon layer to form a continuous silicon oxide layer below the surface of the silicon substrate to provide an isolated superficial layer of silicon. The invention overcomes the problem of buried isolated islands of silicon oxide forming a discontinuous buried oxide layer.

  6. Microstructure and properties of IN SITU toughened silicon carbide

    SciTech Connect (OSTI)

    De Jonghe, Lutgard C.; Ritchie, Robert O.; Zhang, Xiao Feng

    2003-05-01T23:59:59.000Z

    A silicon carbide with a fracture toughness as high as 9.1 MPa.m1/2 has been developed by hot pressing b-SiC powder with aluminum, boron, and carbon additions (ABC-SiC). Central in this material development has been systematic transmission electron microscopy (TEM) and mechanical characterizations. In particular, atomic-resolution electron microscopy and nanoprobe composition quantification were combined in analyzing grain boundary structure and nanoscale structural features.

  7. Formation of thin-film resistors on silicon substrates

    DOE Patents [OSTI]

    Schnable, George L. (Montgomery County, PA); Wu, Chung P. (Hamilton Township, Mercer County, NJ)

    1988-11-01T23:59:59.000Z

    The formation of thin-film resistors by the ion implantation of a metallic conductive layer in the surface of a layer of phosphosilicate glass or borophosphosilicate glass which is deposited on a silicon substrate. The metallic conductive layer materials comprise one of the group consisting of tantalum, ruthenium, rhodium, platinum and chromium silicide. The resistor is formed and annealed prior to deposition of metal, e.g. aluminum, on the substrate.

  8. Characterizatin of ultrafine aluminum nanoparticles

    SciTech Connect (OSTI)

    Sandstrom, M. M. (Mary M.); Jorgensen, B. S. (Betty S.); Mang, J. T. (Joseph T.); Smith, B. L. (Bettina L.); Son, S. F. (Steven F.)

    2004-01-01T23:59:59.000Z

    Aluminum nanopowders with particle sizes ranging from {approx}25 nm to 80 nm were characterized by a variety of methods. We present and compare the results from common powder characterization techniques including transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), BET gas adsorption surface area analysis, thermogravimetric analysis (TGA), photon correlation spectroscopy (PCS), and low angle laser light scattering (LALLS). Aluminum nanoparticles consist of an aluminum core with an aluminum oxide coating. HRTEM measurements of both the particle diameter and oxide layer thickness tend to be larger than those obtained from BET and TGA. LALLS measurements show a large degree of particle agglomeration in solution; therefore, primary particle sizes could not be determined. Furthermore, results from small-angle scattering techniques (SAS), including small-angle neutron (SANS) and x-ray (SAXS) scattering are presented and show excellent agreement with the BET, TGA, and HRTEM. The suite of analytical techniques presented in this paper can be used as a powerful tool in the characterization of many types of nanosized powders.

  9. as21 magnesium alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In particular, the aluminum washer offered each kg means approximately an emission reduction of 0.12 g CO2km. Aluminum as a lightweight material Maume-Deschamps, Vronique...

  10. az80 magnesium alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In particular, the aluminum washer offered each kg means approximately an emission reduction of 0.12 g CO2km. Aluminum as a lightweight material Maume-Deschamps, Vronique...

  11. am50 magnesium alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In particular, the aluminum washer offered each kg means approximately an emission reduction of 0.12 g CO2km. Aluminum as a lightweight material Maume-Deschamps, Vronique...

  12. az61 magnesium alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In particular, the aluminum washer offered each kg means approximately an emission reduction of 0.12 g CO2km. Aluminum as a lightweight material Maume-Deschamps, Vronique...

  13. az magnesium alloys: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In particular, the aluminum washer offered each kg means approximately an emission reduction of 0.12 g CO2km. Aluminum as a lightweight material Maume-Deschamps, Vronique...

  14. am60 magnesium alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In particular, the aluminum washer offered each kg means approximately an emission reduction of 0.12 g CO2km. Aluminum as a lightweight material Maume-Deschamps, Vronique...

  15. Casting Porosity-Free Grain Refined Magnesium Alloys

    SciTech Connect (OSTI)

    Schwam, David [Case Western Reserve University] [Case Western Reserve University

    2013-08-12T23:59:59.000Z

    The objective of this project was to identify the root causes for micro-porosity in magnesium alloy castings and recommend remedies that can be implemented in production. The findings confirm the key role played by utilizing optimal gating and risering practices in minimizing porosity in magnesium castings.?

  16. Promising Magnesium Battery Research at ALS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible forPortsmouth/Paducah47,193.70 HgPromising Magnesium Battery Research at ALS Promising

  17. Processes for producing low cost, high efficiency silicon solar cells

    DOE Patents [OSTI]

    Rohatgi, Ajeet (Marietta, GA); Doshi, Parag (Altanta, GA); Tate, John Keith (Lawrenceville, GA); Mejia, Jose (Atlanta, GA); Chen, Zhizhang (Duluth, GA)

    1998-06-16T23:59:59.000Z

    Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime .tau. and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime .tau. and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO.sub.x. In a fourth RTP process, the process of applying front and back contacts is broken up into two separate respective steps, which enhances the efficiency of the cells, at a slight time expense. In a fifth RTP process, a second RTP step is utilized to fire and adhere the screen printed or evaporated contacts to the structure.

  18. Processes for producing low cost, high efficiency silicon solar cells

    DOE Patents [OSTI]

    Rohatgi, A.; Doshi, P.; Tate, J.K.; Mejia, J.; Chen, Z.

    1998-06-16T23:59:59.000Z

    Processes which utilize rapid thermal processing (RTP) are provided for inexpensively producing high efficiency silicon solar cells. The RTP processes preserve minority carrier bulk lifetime {tau} and permit selective adjustment of the depth of the diffused regions, including emitter and back surface field (bsf), within the silicon substrate. In a first RTP process, an RTP step is utilized to simultaneously diffuse phosphorus and aluminum into the front and back surfaces, respectively, of a silicon substrate. Moreover, an in situ controlled cooling procedure preserves the carrier bulk lifetime {tau} and permits selective adjustment of the depth of the diffused regions. In a second RTP process, both simultaneous diffusion of the phosphorus and aluminum as well as annealing of the front and back contacts are accomplished during the RTP step. In a third RTP process, the RTP step accomplishes simultaneous diffusion of the phosphorus and aluminum, annealing of the contacts, and annealing of a double-layer antireflection/passivation coating SiN/SiO{sub x}. In a fourth RTP process, the process of applying front and back contacts is broken up into two separate respective steps, which enhances the efficiency of the cells, at a slight time expense. In a fifth RTP process, a second RTP step is utilized to fire and adhere the screen printed or evaporated contacts to the structure. 28 figs.

  19. Oxidation resistant high temperature thermal cycling resistant coatings on silicon-based substrates and process for the production thereof

    DOE Patents [OSTI]

    Sarin, V.K.

    1990-08-21T23:59:59.000Z

    An oxidation resistant, high temperature thermal cycling resistant coated ceramic article for ceramic heat engine applications is disclosed. The substrate is a silicon-based material, i.e. a silicon nitride- or silicon carbide-based monolithic or composite material. The coating is a graded coating of at least two layers: an intermediate AlN or Al[sub x]N[sub y]O[sub z] layer and an aluminum oxide or zirconium oxide outer layer. The composition of the coating changes gradually from that of the substrate to that of the AlN or Al[sub x]N[sub y]O[sub z] layer and further to the composition of the aluminum oxide or zirconium oxide outer layer. Other layers may be deposited over the aluminum oxide layer. A CVD process for depositing the graded coating on the substrate is also disclosed.

  20. Purified silicon production system

    DOE Patents [OSTI]

    Wang, Tihu; Ciszek, Theodore F.

    2004-03-30T23:59:59.000Z

    Method and apparatus for producing purified bulk silicon from highly impure metallurgical-grade silicon source material at atmospheric pressure. Method involves: (1) initially reacting iodine and metallurgical-grade silicon to create silicon tetraiodide and impurity iodide byproducts in a cold-wall reactor chamber; (2) isolating silicon tetraiodide from the impurity iodide byproducts and purifying it by distillation in a distillation chamber; and (3) transferring the purified silicon tetraiodide back to the cold-wall reactor chamber, reacting it with additional iodine and metallurgical-grade silicon to produce silicon diiodide and depositing the silicon diiodide onto a substrate within the cold-wall reactor chamber. The two chambers are at atmospheric pressure and the system is open to allow the introduction of additional source material and to remove and replace finished substrates.

  1. PROPERTIES OF DEFECTS AND IMPLANTS IN Mg+ IMPLANTED SILICON CARBIDE

    SciTech Connect (OSTI)

    Jiang, Weilin; Zhu, Zihua; Varga, Tamas; Bowden, Mark E.; Manandhar, Sandeep; Roosendaal, Timothy J.; Hu, Shenyang Y.; Henager, Charles H.; Kurtz, Richard J.; Wang, Yongqiang

    2013-09-25T23:59:59.000Z

    As a candidate material for fusion reactor designs, silicon carbide (SiC) under high-energy neutron irradiation undergoes atomic displacement damage and transmutation reactions that create magnesium as one of the major metallic products. The presence of Mg and lattice disorder in SiC is expected to affect structural stability and degrade thermo-mechanical properties that could limit SiC lifetime for service. We have initiated a combined experimental and computational study that uses Mg+ ion implantation and multiscale modeling to investigate the structural and chemical effects in Mg implanted SiC and explore possible property degradation mechanisms.

  2. Reaction of Aluminum with Water to Produce Hydrogen

    E-Print Network [OSTI]

    Aluminum Alloys PROPERTIES OF THE ALUMINUM-WATER REACTIONS RELATIVE ........... 14 TO ON-BOARD SYSTEM metal. In addition, the reaction of water with molten aluminum alloys such as aluminum-lithium and aluminum-gallium has been studied. In this case, the molten nature of the alloy prevents the development

  3. Production of anhydrous aluminum chloride composition

    DOE Patents [OSTI]

    Vandergrift, G.F. III; Krumpelt, M.; Horwitz, E.P.

    1981-10-08T23:59:59.000Z

    A process is described for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.

  4. Process for converting magnesium fluoride to calcium fluoride

    DOE Patents [OSTI]

    Kreuzmann, A.B.; Palmer, D.A.

    1984-12-21T23:59:59.000Z

    This invention is a process for the conversion of magnesium fluoride to calcium fluoride whereby magnesium fluoride is decomposed by heating in the presence of calcium carbonate, calcium oxide or calcium hydroxide. Magnesium fluoride is a by-product of the reduction of uranium tetrafluoride to form uranium metal and has no known commercial use, thus its production creates a significant storage problem. The advantage of this invention is that the quality of calcium fluoride produced is sufficient to be used in the industrial manufacture of anhydrous hydrogen fluoride, steel mill flux or ceramic applications.

  5. An EPR study of ¹?O? on magnesium oxide 

    E-Print Network [OSTI]

    Wong, Ning-Bew

    1971-01-01T23:59:59.000Z

    AN EPR STUDY OF 0 ON MAGNESIUM OXIDE A Thesis by NING-SEW WONG Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1971 Major Subject: Chemistry AN EPR... STUDY OF 0 ON MAGNESIUM OXIDE A Thesis by NING-BEN WONG Approved as to style and content by: (Chairman of Committe (Head of Department) (Member) (Member) May 1971 ABSTRACT 17 An EPR Study of 0 on Magnesium Oxide (May, 1971) Ning-Bew Wong, B...

  6. High resistivity aluminum antimonide radiation detector

    DOE Patents [OSTI]

    Sherohman, John W. (Livermore, CA); Coombs, III, Arthur W. (Patterson, CA); Yee, Jick H. (Livermore, CA)

    2007-12-18T23:59:59.000Z

    Bulk Aluminum Antimonide (AlSb)-based single crystal materials have been prepared for use as ambient (room) temperature X-ray and Gamma-ray radiation detection.

  7. Climate VISION: Private Sector Initiatives: Aluminum: Resources...

    Office of Scientific and Technical Information (OSTI)

    Resources & Links Industry Associations FederalState Programs Technical Information Plant Assessments Training Calendar Software Tools Energy Management Expertise Auto Aluminum...

  8. Climate VISION: Private Sector Initiatives: Aluminum: Resources...

    Office of Scientific and Technical Information (OSTI)

    Partnership The Voluntary Aluminum Industrial Partnership (VAIP) is an innovative pollution prevention program developed jointly by the U.S. Environmental Protection Agency...

  9. High resistivity aluminum antimonide radiation detector

    DOE Patents [OSTI]

    Sherohman, John W.; Coombs, III, Arthur W.; Yee, Jick H.

    2005-05-03T23:59:59.000Z

    Bulk Aluminum Antimonide (AlSb)-based single crystal materials have been prepared for use as ambient (room) temperature X-ray and Gamma-ray radiation detection.

  10. aluminum: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Repository Summary: Damping and Dynamic Modulus Measurements in Alumina and Tungsten Fibre-Reinforced Aluminium Composites. the damping capacity of aluminum tungsten fiber...

  11. The Pricing of Electricity to Aluminum Smelters in the Northwest 

    E-Print Network [OSTI]

    Foley, T. J.

    1986-01-01T23:59:59.000Z

    major industrial firms, primarily aluminum companies operating aluminum smelters in the region. These direct service industries (DSIs) have a contractual right to purchase up to 3.500 average megawatts annually from Bonneville. Because the aluminum...

  12. iCons, 2011 Alzheimers and Aluminum: Lesson Plan

    E-Print Network [OSTI]

    Auerbach, Scott M.

    © iCons, 2011 Alzheimers and Aluminum: Lesson Plan Handouts to explore mechanistic link between Alzheimer's and aluminum 5. Brief proposal expanding Points to Aluminum's Link With Alzheimer's Disease" from 1989. Provide handout

  13. az91 magnesium alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Page Last Page Topic Index 1 Studies on the inuence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy Engineering Websites Summary:...

  14. Glass-silicon column

    DOE Patents [OSTI]

    Yu, Conrad M.

    2003-12-30T23:59:59.000Z

    A glass-silicon column that can operate in temperature variations between room temperature and about 450.degree. C. The glass-silicon column includes large area glass, such as a thin Corning 7740 boron-silicate glass bonded to a silicon wafer, with an electrode embedded in or mounted on glass of the column, and with a self alignment silicon post/glass hole structure. The glass/silicon components are bonded, for example be anodic bonding. In one embodiment, the column includes two outer layers of silicon each bonded to an inner layer of glass, with an electrode imbedded between the layers of glass, and with at least one self alignment hole and post arrangement. The electrode functions as a column heater, and one glass/silicon component is provided with a number of flow channels adjacent the bonded surfaces.

  15. Formation of chemically bonded ceramics with magnesium dihydrogen phosphate binder

    DOE Patents [OSTI]

    Wagh, Arun S.; Jeong, Seung-Young

    2004-08-17T23:59:59.000Z

    A new method for combining magnesium oxide, MgO, and magnesium dihydrogen phosphate to form an inexpensive compactible ceramic to stabilize very low solubility metal oxides, ashes, swarfs, and other iron or metal-based additives, to create products and waste forms which can be poured or dye cast, and to reinforce and strengthen the ceramics formed by the addition of fibers to the initial ceramic mixture.

  16. Determination of carbon, nitrogen, and oxygen in high purity magnesium 

    E-Print Network [OSTI]

    Roche, Neil Gerard

    1981-01-01T23:59:59.000Z

    DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Submitted to the Graduate College of Texas A8cM University in partial i'ulfillment of the requirement for the degree of MASTER OF SCIENCE... December 1981 Major Subject: Chemistry DETERMINATION OF CARBON, NITROGEN, AND OXYGEN IN HIGH PURITY MAGNESIUM A Thesis by NEIL GERARD ROCHE Approved as to style and content by: E. A. Schweikert (Chairman of Committee) G. J. Bastiaans (Member) L...

  17. Scientists ignite aluminum water mix

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del Sol HomeFacebook Twitter PrincipalfuelTorus ExperimentScientists ignite aluminum

  18. aluminum matrix composite: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topic Index 1 Joining of 6061 Aluminum Matrix-Ceramic Particle Reinforced Composites Materials Science Websites Summary: ) ) Joining of 6061 Aluminum Matrix-Ceramic Particle...

  19. Commonwealth Aluminum: Manufacturer Conducts Plant-Wide Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Costs by Increasing Energy Efficiency in Process Heating Systems ITP Aluminum: Aluminum Industry Roadmap for the Automotive Market (May 1999) Improving Process Heating System...

  20. Energy Assessment Helps Kaiser Aluminum Save Energy and Improve...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Helps Kaiser Aluminum Save Energy and Improve Productivity Energy Assessment Helps Kaiser Aluminum Save Energy and Improve Productivity This case study describes how a DOE energy...

  1. Aluminum across the Americas: Caribbean Mobilities and Transnational American Studies

    E-Print Network [OSTI]

    Sheller, Mimi

    2013-01-01T23:59:59.000Z

    developed countries aluminum smelters consume up to 1/3 ordam to power an aluminum smelter in the 1960s, displacing

  2. aluminum alloy matrix: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: ccsd-00002835,version2-14Sep2004 Light scattering from cold rolled aluminum surfaces Damien experimental light scattering measurements from aluminum surfaces obtained...

  3. aluminum automotive components: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    set of the pn junction with self-assembled, anodic aluminum Anlage, Steven 375 EFFECT OF ENCAPSULANT ON HIGH-TEMPERATURE RELIABILITY OF THE GOLD WIREBOND ALUMINUM BONDPAD...

  4. aluminum hydride reduction: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University, Ankara 06531, Turkey Aluminum borate chemicals of aluminum sulphate and boric acid. The synthesis temperature of 1075C was found Tas, A. Cuneyt 300 A...

  5. aluminum reduction plant: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University, Ankara 06531, Turkey Aluminum borate chemicals of aluminum sulphate and boric acid. The synthesis temperature of 1075C was found Tas, A. Cuneyt 226 A...

  6. activated aluminum oxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    University, Ankara 06531, Turkey Aluminum borate chemicals of aluminum sulphate and boric acid. The synthesis temperature of 1075C was found Tas, A. Cuneyt 323 A...

  7. DOE - Office of Legacy Management -- Hunter Douglas Aluminum...

    Office of Legacy Management (LM)

    Hunter Douglas Aluminum Plant Div of Bridgeport Brass Co - CA 11 FUSRAP Considered Sites Site: HUNTER DOUGLAS ALUMINUM PLANT, DIV. OF BRIDGEPORT BRASS CO. (CA.11 ) Eliminated from...

  8. ALUMINUM DISTRIBUTIONSIN THE EURASIAN BASIN OF THE ARCTIC OCEAN

    E-Print Network [OSTI]

    Luther, Douglas S.

    ALUMINUM DISTRIBUTIONSIN THE EURASIAN BASIN OF THE ARCTIC OCEAN A THESISSUBMITTEDTO THE GRADUATE Section(1994)cruiseswere analyzed for their aluminum (Al) content; these two data setswere then combined

  9. Aluminum industry energy conservation workshop V papers

    SciTech Connect (OSTI)

    Not Available

    1980-01-01T23:59:59.000Z

    This book contains papers given at a recent meeting sponsored by The Aluminum Association. The focus of the meeting is on energy conservation in the aluminum industry. Topics include recovery of waste heat, more energy efficient design of plants, and government policies.

  10. Aluminum low temperature smelting cell metal collection

    DOE Patents [OSTI]

    Beck, Theodore R. (Seattle, WA); Brown, Craig W. (Seattle, WA)

    2002-07-16T23:59:59.000Z

    A method of producing aluminum in an electrolytic cell containing alumina dissolved in an electrolyte. The method comprises the steps of providing a molten salt electrolyte in an electrolytic cell having an anodic liner for containing the electrolyte, the liner having an anodic bottom and walls including at least one end wall extending upwardly from the anodic bottom, the anodic liner being substantially inert with respect to the molten electrolyte. A plurality of non-consumable anodes is provided and disposed vertically in the electrolyte. A plurality of cathodes is disposed vertically in the electrolyte in alternating relationship with the anodes. The anodes are electrically connected to the anodic liner. An electric current is passed through the anodic liner to the anodes, through the electrolyte to the cathodes, and aluminum is deposited on said cathodes. Oxygen bubbles are generated at the anodes and the anodic liner, the bubbles stirring the electrolyte. Molten aluminum is collected from the cathodes into a tubular member positioned underneath the cathodes. The tubular member is in liquid communication with each cathode to collect the molten aluminum therefrom while excluding electrolyte. Molten aluminum is delivered through the tubular member to a molten aluminum reservoir located substantially opposite the anodes and cathodes. The molten aluminum is collected from the cathodes and delivered to the reservoir while avoiding contact of the molten aluminum with the anodic bottom.

  11. Gating of Permanent Molds for ALuminum Casting

    SciTech Connect (OSTI)

    David Schwam; John F. Wallace; Tom Engle; Qingming Chang

    2004-03-30T23:59:59.000Z

    This report summarizes a two-year project, DE-FC07-01ID13983 that concerns the gating of aluminum castings in permanent molds. The main goal of the project is to improve the quality of aluminum castings produced in permanent molds. The approach taken was determine how the vertical type gating systems used for permanent mold castings can be designed to fill the mold cavity with a minimum of damage to the quality of the resulting casting. It is evident that somewhat different systems are preferred for different shapes and sizes of aluminum castings. The main problems caused by improper gating are entrained aluminum oxide films and entrapped gas. The project highlights the characteristic features of gating systems used in permanent mold aluminum foundries and recommends gating procedures designed to avoid common defects. The study also provides direct evidence on the filling pattern and heat flow behavior in permanent mold castings.

  12. Silicon rich nitride for silicon based laser devices

    E-Print Network [OSTI]

    Yi, Jae Hyung

    2008-01-01T23:59:59.000Z

    Silicon based light sources, especially laser devices, are the key components required to achieve a complete integrated silicon photonics system. However, the fundamental physical limitation of the silicon material as light ...

  13. PREDICTION OF LOW-CYCLE FATIGUE-LIFE BY ACOUSTIC EMISSION. PART 1: 2024-T3 ALUMINUM ALLOY PART 2: ALCLAD 7075-T6/ ALUMINUM ALLOY

    E-Print Network [OSTI]

    Baram, J.

    2013-01-01T23:59:59.000Z

    toughness of structural aluminum alloys. Fracture . Fracturetoughness of structural aluminum alloys, Eng. Fracture Mech.crack propagation r aluminum alloys, 2024~T3 at low and

  14. PREDICTION OF LOW-CYCLE FATIGUE-LIFE BY ACOUSTIC EMISSION. PART 1: 2024-T3 ALUMINUM ALLOY PART 2: ALCLAD 7075-T6/ ALUMINUM ALLOY

    E-Print Network [OSTI]

    Baram, J.

    2013-01-01T23:59:59.000Z

    low-cycle fatigue life of Aluminum sheet alloys by acoustictoughness of structural aluminum alloys. Fracture . Fracturetoughness of structural aluminum alloys, Eng. Fracture Mech.

  15. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and Catalytic Applications. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

  16. A Wideband 77GHz, 17.5dBm Power Amplifier in Silicon Abbas Komijani and Ali Hajimiri

    E-Print Network [OSTI]

    Hajimiri, Ali

    such as short-range communication (e.g., 60GHz band) and automotive radar (e.g., 77GHz band) [1 integrated 77GHz power amplifier in silicon. II. FREQUENCY BAND In a collision-avoidance automotive radar copper layers and a thick 4µm aluminum layer as top metal for low-loss interconnects. The breakdown

  17. Pulsed DC magnetron sputtered piezoelectric thin film aluminum nitride – Technology and piezoelectric properties

    SciTech Connect (OSTI)

    Stoeckel, C., E-mail: chris.stoeckel@zfm.tu-chemnitz.de; Kaufmann, C.; Hahn, R.; Schulze, R. [Center for Microtechnologies, Chemnitz University of Technology, Chemnitz 09126 (Germany); Billep, D. [Fraunhofer Institute for Electronic Nano Systems (ENAS), Chemnitz 09126 (Germany); Gessner, T. [Center for Microtechnologies, Chemnitz University of Technology, Chemnitz 09126 (Germany); Fraunhofer Institute for Electronic Nano Systems (ENAS), Chemnitz 09126 (Germany)

    2014-07-21T23:59:59.000Z

    Pulsed DC magnetron sputtered aluminum nitride (AlN) thin films are prepared on several seed layers and at different sputtering conditions. The piezoelectric c-axis (002) orientation of the AlN is analyzed with X-ray diffraction method. The transverse piezoelectric coefficient d{sub 31} is determined with a Laser-Doppler-Vibrometer at cantilevers and membranes by analytical calculations and finite element method. Additionally, thin film AlN on bulk silicon is used to characterize the longitudinal piezoelectric charge coefficient d{sub 33}.

  18. Micromachined silicon electrostatic chuck

    DOE Patents [OSTI]

    Anderson, Robert A. (Albuquerque, NM); Seager, Carleton H. (Albuquerque, NM)

    1996-01-01T23:59:59.000Z

    An electrostatic chuck is faced with a patterned silicon plate 11, created y micromachining a silicon wafer, which is attached to a metallic base plate 13. Direct electrical contact between the chuck face 15 (patterned silicon plate's surface) and the silicon wafer 17 it is intended to hold is prevented by a pattern of flat-topped silicon dioxide islands 19 that protrude less than 5 micrometers from the otherwise flat surface of the chuck face 15. The islands 19 may be formed in any shape. Islands may be about 10 micrometers in diameter or width and spaced about 100 micrometers apart. One or more concentric rings formed around the periphery of the area between the chuck face 15 and wafer 17 contain a low-pressure helium thermal-contact gas used to assist heat removal during plasma etching of a silicon wafer held by the chuck. The islands 19 are tall enough and close enough together to prevent silicon-to-silicon electrical contact in the space between the islands, and the islands occupy only a small fraction of the total area of the chuck face 15, typically 0.5 to 5 percent. The pattern of the islands 19, together with at least one hole 12 bored through the silicon veneer into the base plate, will provide sufficient gas-flow space to allow the distribution of the helium thermal-contact gas.

  19. Micromachined silicon electrostatic chuck

    DOE Patents [OSTI]

    Anderson, R.A.; Seager, C.H.

    1996-12-10T23:59:59.000Z

    An electrostatic chuck is faced with a patterned silicon plate, created by micromachining a silicon wafer, which is attached to a metallic base plate. Direct electrical contact between the chuck face (patterned silicon plate`s surface) and the silicon wafer it is intended to hold is prevented by a pattern of flat-topped silicon dioxide islands that protrude less than 5 micrometers from the otherwise flat surface of the chuck face. The islands may be formed in any shape. Islands may be about 10 micrometers in diameter or width and spaced about 100 micrometers apart. One or more concentric rings formed around the periphery of the area between the chuck face and wafer contain a low-pressure helium thermal-contact gas used to assist heat removal during plasma etching of a silicon wafer held by the chuck. The islands are tall enough and close enough together to prevent silicon-to-silicon electrical contact in the space between the islands, and the islands occupy only a small fraction of the total area of the chuck face, typically 0.5 to 5 percent. The pattern of the islands, together with at least one hole bored through the silicon veneer into the base plate, will provide sufficient gas-flow space to allow the distribution of the helium thermal-contact gas. 6 figs.

  20. Characterization of porous GASAR aluminum

    SciTech Connect (OSTI)

    Bonenberger, R.J. [FM Technologies, Inc., Fairfax, VA (United States); Kee, A.J. [Geo-Centers, Inc., Fort Washington, MD (United States); Everett, R.K.; Matic, P. [Naval Research Lab., Washington, DC (United States)

    1998-12-31T23:59:59.000Z

    Experimental and numerical analyses were performed on porous aluminum samples to evaluate microstructure and mechanical properties. Experiments considered of tensile tests on dog-bone specimens containing 9 to 17% porosity, which were instrumented with axial and transverse extensometers. Properties measured included Young`s modulus, Poisson`s ratio remained constant with porosity., For the numerical simulations, 3-D, mesoscale, multilayer models were constructed to evaluate the effects of pore morphology and interactions on material properties. The models allowed systematic spatial positioning of the pore within the cell and the ability to form solid zones. Pore arrangement, the effect of constraint, and gradients on the stress state were investigated. By using different combinations of hex cells as building blocks, several complicated microstructural arrangements were simulated.

  1. ALUMINUM--2003 5.1 By Patricia A. Plunkert

    E-Print Network [OSTI]

    metal and alloys held by the London Metal Exchange Ltd. (LME) also increased. Primary aluminumALUMINUM--2003 5.1 ALUMINUM By Patricia A. Plunkert Domestic survey data and tables were prepared, international data coordinator. In 2003, 7 domestic companies operated 15 primary aluminum reduction plants

  2. Aluminum Waste Reaction Indicators in a Municipal Solid Waste Landfill

    E-Print Network [OSTI]

    Aluminum Waste Reaction Indicators in a Municipal Solid Waste Landfill Timothy D. Stark, F.ASCE1 landfills may contain aluminum from residential and commercial solid waste, industrial waste, and aluminum American Society of Civil Engineers. CE Database subject headings: Solid wastes; Leaching; Aluminum

  3. Formulation and method for preparing gels comprising hydrous aluminum oxide

    SciTech Connect (OSTI)

    Collins, Jack L.

    2014-06-17T23:59:59.000Z

    Formulations useful for preparing hydrous aluminum oxide gels contain a metal salt including aluminum, an organic base, and a complexing agent. Methods for preparing gels containing hydrous aluminum oxide include heating a formulation to a temperature sufficient to induce gel formation, where the formulation contains a metal salt including aluminum, an organic base, and a complexing agent.

  4. ALUMINUM--1998 5.1 By Patricia A. Plunkert

    E-Print Network [OSTI]

    ALUMINUM--1998 5.1 ALUMINUM By Patricia A. Plunkert Domestic survey data and tables were prepared, international data coordinator. In 1998, 13 domestic companies operated 23 primary aluminum reduction plants to be $5.4 billion. Aluminum recovered from purchased scrap decreased to approximately 3.4 million tons

  5. Synthesis of nanocrystalline aluminum matrix composites reinforced with in situ devitrified Al-Ni-La amorphous particles

    E-Print Network [OSTI]

    Zhang, Zhihui H; Han, B Q; Witkin, D; Ajdelsztajn, L; Laverna, E J

    2006-01-01T23:59:59.000Z

    of nanocrystalline aluminum matrix composites reinforcedAbstract Nanocrystalline aluminum matrix composites wereamount of nanoscale aluminum oxide, nitride and carbide

  6. Cathode for aluminum producing electrolytic cell

    DOE Patents [OSTI]

    Brown, Craig W.

    2004-04-13T23:59:59.000Z

    A method of producing aluminum in an electrolytic cell comprising the steps of providing an anode in a cell, preferably a non-reactive anode, and also providing a cathode in the cell, the cathode comprised of a base material having low electrical conductivity reactive with molten aluminum to provide a highly electrically conductive layer on the base material. Electric current is passed from the anode to the cathode and alumina is reduced and aluminum is deposited at the cathode. The cathode base material is selected from boron carbide, and zirconium oxide.

  7. Nondestructive evaluation of an environmentally friendly conversion coating for magnesium alloys using optical measurement techniques

    E-Print Network [OSTI]

    Zuniga, David

    2006-10-30T23:59:59.000Z

    Magnesium alloys have one of the highest specific strengths of all construction metals used. Specifically, magnesium alloy castings are used in the aerospace industry to reduce the weight of aerospace vehicles. Coating systems must be employed...

  8. Nondestructive evaluation of an environmentally friendly conversion coating for magnesium alloys using optical measurement techniques 

    E-Print Network [OSTI]

    Zuniga, David

    2006-10-30T23:59:59.000Z

    Magnesium alloys have one of the highest specific strengths of all construction metals used. Specifically, magnesium alloy castings are used in the aerospace industry to reduce the weight of aerospace vehicles. Coating systems must be employed...

  9. Antifuse with a single silicon-rich silicon nitride insulating layer

    DOE Patents [OSTI]

    Habermehl, Scott D.; Apodaca, Roger T.

    2013-01-22T23:59:59.000Z

    An antifuse is disclosed which has an electrically-insulating region sandwiched between two electrodes. The electrically-insulating region has a single layer of a non-hydrogenated silicon-rich (i.e. non-stoichiometric) silicon nitride SiN.sub.X with a nitrogen content X which is generally in the range of 0aluminum and silicon. Arrays of antifuses can also be formed.

  10. Identification of aluminum scale with the aid of synthetically produced basic aluminum fluoride complexes

    SciTech Connect (OSTI)

    Shuchart, C.E. (Halliburton Services, Duncan, OK (United States)); Ali, S.A. (Chevron U.S.A. Inc., New Orleans, LA (United States))

    1993-11-01T23:59:59.000Z

    Aluminum scaling can be a problem following HF acidizing. In this paper, a series of synthetic aluminum scales was prepared and identified. The aluminum compounds of a field scale were identified with similar procedures. Recent field work showed that the use of acetic acid in the HF acidizing sequences significantly decreased scaling. The role of acetic acid is discussed on the basis of laboratory support of these field data.

  11. Aluminum (Al) Etch Instructions The CEPSR cleanroom stores Aluminum Etchant Type A, a pre-made product used for

    E-Print Network [OSTI]

    Kim, Philip

    Aluminum (Al) Etch Instructions The CEPSR cleanroom stores Aluminum Etchant Type A, a pre-made product used for removing or etching away aluminum. This etchant is stored inside the acid or corrosive a specific thickness of aluminum that is desired. Note: Once the bottle is empty or you find that it's etch

  12. Development of High-Volume Warm Forming of Low-Cost Magnesium...

    Broader source: Energy.gov (indexed) [DOE]

    Yingbing Luo, George Luckey * GM - Paul Krajewski, Ravi Verma Contracts * Troy Tooling Technologies - Dennis Cedar * Materials Suppliers - Magnesium Elektron - POSCO -...

  13. Blood pressure and red blood cell magnesium, potassium, and calcium responses to dietary fats

    E-Print Network [OSTI]

    Wehrman, Noreen Elaine

    1993-01-01T23:59:59.000Z

    of hypertension. The role of dietary fats in blood pressure regulation is being studied more closely, with careful consideration to their actions on prostaglandin synthesis, membrane fluidity and permeability, and electrolyte balance. This study examined... Page 111 . V1 V11 . 1X Problem Identification. Electrolytes. Magnesium . The Role of Magnesium and Ion Transport . The Relationship Between Magnesium and Potassium. The Relationship Between Magnesium and Calcium. The Relationship Between...

  14. Nanostructured material for advanced energy storage : magnesium battery cathode development.

    SciTech Connect (OSTI)

    Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

    2010-11-01T23:59:59.000Z

    Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

  15. Structure, defects, and strain in silicon-silicon oxide interfaces

    SciTech Connect (OSTI)

    Kova?evi?, Goran, E-mail: gkova@irb.hr; Pivac, Branko [Department of Materials Physics, Rudjer Boskovic Institute, Bijeni?ka 56, P.O.B. 180, HR-10002 Zagreb (Croatia)

    2014-01-28T23:59:59.000Z

    The structure of the interfaces between silicon and silicon-oxide is responsible for proper functioning of MOSFET devices while defects in the interface can deteriorate this function and lead to their failure. In this paper we modeled this interface and characterized its defects and strain. MD simulations were used for reconstructing interfaces into a thermodynamically stable configuration. In all modeled interfaces, defects were found in the form of three-coordinated silicon atom, five coordinated silicon atom, threefold-coordinated oxygen atom, or displaced oxygen atom. Three-coordinated oxygen atom can be created if dangling bonds on silicon are close enough. The structure and stability of three-coordinated silicon atoms (P{sub b} defect) depend on the charge as well as on the electric field across the interface. The negatively charged P{sub b} defect is the most stable one, but the electric field resulting from the interface reduces that stability. Interfaces with large differences in periodic constants of silicon and silicon oxide can be stabilized by buckling of silicon layer. The mechanical stress resulted from the interface between silicon and silicon oxide is greater in the silicon oxide layer. Ab initio modeling of clusters representing silicon and silicon oxide shows about three time larger susceptibility to strain in silicon oxide than in silicon if exposed to the same deformation.

  16. AMORPHOUS SILICON-BASED MINIMODULES WITH SILICONE ELASTOMER ENCAPSULATION

    E-Print Network [OSTI]

    Deng, Xunming

    -based polymers (silicones) may not show this effect. Although silicones were used to encapsulate solar cells improved, which may make them suitable for encapsulating solar cells once again. We have recentlyAMORPHOUS SILICON-BASED MINIMODULES WITH SILICONE ELASTOMER ENCAPSULATION Aarohi Vijh 1

  17. Regeneration of Aluminum Hydride - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the reduction of the change in free energy of the reaction between aluminum and molecular hydrogen. The change in free energy is reduced by providing Al in a state of high entropy...

  18. Electrometallurgical treatment of aluminum-based fuels.

    SciTech Connect (OSTI)

    Willit, J. L.

    1998-07-29T23:59:59.000Z

    We have successfully demonstrated aluminum electrorefining from a U-Al-Si alloy that simulates spent aluminum-based reactor fuel. The aluminum product contains less than 200 ppm uranium. All the results obtained have been in agreement with predictions based on equilibrium thermodynamics. We have also demonstrated the need for adequate stirring to achieve a low-uranium product. Most of the other process steps have been demonstrated in other programs. These include uranium electrorefining, transuranic fission product scrubbing, fission product oxidation, and product consolidation by melting. Future work will focus on the extraction of active metal and rare earth fission products by a molten flux salt and scale-up of the aluminum electrorefining.

  19. Dry lubricant films for aluminum forming.

    SciTech Connect (OSTI)

    Wei, J.; Erdemir, A.; Fenske, G. R.

    1999-03-30T23:59:59.000Z

    During metal forming process, lubricants are crucial to prevent direct contact, adhesion, transfer and scuffing of workpiece materials and tools. Boric acid films can be firmly adhered to the clean aluminum surfaces by spraying their methanol solutions and provide extremely low friction coefficient (about 0.04). The cohesion strengths of the bonded films vary with the types of aluminum alloys (6061, 6111 and 5754). The sheet metal forming tests indicate that boric acid films and the combined films of boric acid and mineral oil can create larger strains than the commercial liquid and solid lubricants, showing that they possess excellent lubricities for aluminum forming. SEM analyses indicate that boric acid dry films separate the workpiece and die materials, and prevent their direct contact and preserve their surface qualities. Since boric acid is non-toxic and easily removed by water, it can be expected that boric acid films are environmentally friendly, cost effective and very efficient lubricants for sheet aluminum cold forming.

  20. UV Curable Coatings in Aluminum Can Production 

    E-Print Network [OSTI]

    Donhowe, E. T.

    1994-01-01T23:59:59.000Z

    based coatings. The Coors Brewing Company Can Manufacturing Plant has been utilizing this technology in full scale aluminum can production since 1975, and therefore has had the opportunity to evaluate practical operations of the UV technology...

  1. High thermal conductivity aluminum nitride ceramic body

    SciTech Connect (OSTI)

    Huseby, I. C.; Bobik, C. F.

    1985-10-15T23:59:59.000Z

    A process for producing a polycrystalline aluminum nitride ceramic body having a porosity of less than about 10% by volume of said body and a thermal conductivity greater than 1.0 W/cm-K at 22/sup 0/ C., which comprises forming a mixture comprised of aluminum nitride powder and an yttrium additive selected from the group consisting of yttrium, yttrium hydride, yttrium nitride and mixtures thereof, said aluminum nitride and yttrium additive having a predetermined oxygen content, said mixture having a composition wherein the equivalent % of yttrium, aluminum, nitrogen and oxygen shapping said mixture into a compact and sintering said compact at a temperature ranging from about 1850/sup 0/ C. to about 2170/sup 0/ C. in an atmosphere selected from the group consisting of nitrogen, argon, hydrogen and mixtures thereof to produce said polycrystalline body.

  2. Effects of dietary potassium and sodium on magnesium and potassium balance in lambs

    E-Print Network [OSTI]

    Poe, Julie Hamilton

    1984-01-01T23:59:59.000Z

    . Molasses in a 1:1 mixture with magnesium oxide (Horvath et al. , 1967) or magnesium acetate (Ross and Gibson, 1969) has prevented low serum Mg levels. Magnesium alloy bullets have been designed to lodge in the reticulo-rumen and slowly release Mg...

  3. PITTING CORROSION ON MAGNESIUM ALLOYS : A COMPARATIVE STUDY OF FIELD DATA USING EXTREME VALUE

    E-Print Network [OSTI]

    Maume-Deschamps, Véronique

    PITTING CORROSION ON MAGNESIUM ALLOYS : A COMPARATIVE STUDY OF FIELD DATA USING EXTREME VALUE corrosion of the magnesium alloys AZ91D and AM60B combined with different coatings on steel bolts was investigated in field corrosion tests carried out by Volvo Car Corporation. Light metals like magnesium

  4. X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films

    E-Print Network [OSTI]

    X-ray Absorption Spectroscopy of Transition Metal-Magnesium Hydride Thin Films T. J. Richardsona@lbl.gov Abstract Mixed metal thin films containing magnesium and a first-row transition element exhibit very large of magnesium hydride. Keywords: A. hydrogen storage materials, thin films; C. EXAFS, NEXAFS, X-ray diffraction

  5. Evaluation of microstructural eects on corrosion behaviour of AZ91D magnesium

    E-Print Network [OSTI]

    Zhou, Wei

    . Magnesium and its alloys, with one quarter of the density of steel and only two thirds that of aluminium of the prerequisites for all these applications. The corrosion behaviour of cast magnesium±aluminium alloys couldEvaluation of microstructural eects on corrosion behaviour of AZ91D magnesium alloy Rajan Ambat

  6. An optimal replacement problem in aluminum production

    E-Print Network [OSTI]

    Spanks, Lisa Marie

    1992-01-01T23:59:59.000Z

    AN OPTIMAL REPLACEMENT PROBLEM IN ALUMINUM PRODUCTION Thesis by LISA MARIE SPANKS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 1992... Major Subject: Industrial Engineering AN OPTIMAL REPLACEMENT PROBLEM IN ALUMINUM PRODUCTION Thesis by LISA MARIE SPANKS Approved as to style and content by: Richard M. Feldman (Chair of Committee) James H. Matis (Member) ryan L. Deuermey r...

  7. Determination of carbon, nitrogen, and oxygen in high purity magnesium

    E-Print Network [OSTI]

    Roche, Neil Gerard

    1981-01-01T23:59:59.000Z

    the determination of low Z impurities (carbon, nitrogen, and oxygen) is a prerequisite for gaining an understanding of the effects of chemical imperfections on the physical, metallurgical, and chemical properties of magnesium (2). The purpose of this study... of nitrogen was accomplished with a 7. 8 MeV Be beam and 9 3 some modifications of the preceeding He procedure were necessary due to the nature of the ion beam. Sam les and Standards Eleven magnesium ingots were received from Dow Chemical Co. , Texas...

  8. The magnesium nutrition of cotton as influenced by sodium 

    E-Print Network [OSTI]

    Thenabadu, Mervyn Wellesly

    1964-01-01T23:59:59.000Z

    1964 Major Subject. Plant Physic logy THE MAGNESIUM NUTRITION OF COTTON AS INFLUENCED BY SODIUM A Thesis By MERVYN M. THENABADU Approved as to style and content by: Chairman of Commi. e Nun Head of Department Member Mem, er Member Member... REVIEW OF LITERATURE (a) Sodium as a plant nutrient (b) I'he role of magnesium in plant nutrition MATERIALS AND METHODS RESUL:S DISCUSSION 13 21 24 (a) The effect of treatments on grcwth and reproduction (b) The effect of treatments on the ccr...

  9. Aluminum Microfoams for Reduced Fuel Consumption and Pollutant Emissions of Transportation Systems

    E-Print Network [OSTI]

    Pilon, Laurent

    2008-01-01T23:59:59.000Z

    on the foamability of Aluminum alloy . Journal of Materialthe more conventional aluminum alloy, would have a higheraerospace technologies, aluminum alloys are the materials of

  10. SUBTHRESHOLD DISPLACEMENT DAMAGE IN COPPER-ALUMINUM ALLOYS DURING ELECTRON IRRADIATION

    E-Print Network [OSTI]

    Drosd, R.

    2010-01-01T23:59:59.000Z

    DAMAGE IN COPPER-ALUMINUM ALLOYS DURING ELECTRON IRRADIATIONDAMAGE IN COPPER-ALUMINUM ALLOYS DURING ELECTRON IRRADIATIONby irradiating copper-aluminum alloys at high tempera­ tures

  11. EFFECT OF GRAIN SIZE ON THE ACOUSTIC EMISSION GENERATED DURING PLASTIC DEFORMATION OF ALUMINUM

    E-Print Network [OSTI]

    Baram, J.

    2013-01-01T23:59:59.000Z

    PLASTIC DEFORMATION OF ALUMINUM LAWRENCE BERKELEY LABORATORYDURING PLASTIC DEFORMATION OF ALUMINUM J. Baram Materialsof polycrystalline aluminum, of different grain sizes and at

  12. Aluminum Microfoams for Reduced Fuel Consumption and Pollutant Emissions of Transportation Systems

    E-Print Network [OSTI]

    Pilon, Laurent

    2008-01-01T23:59:59.000Z

    on the foamability of Aluminum alloy . Journal of MaterialFoamability of particle reinforced Aluminum Melt. Ma. -wiss.particle-stabilised Aluminum foams . Advanced Engineering

  13. Aluminum and copper in drinking water enhance inflammatory oroxidative events specifically in the brain

    E-Print Network [OSTI]

    Bondy, Stephen Bondy C

    2006-01-01T23:59:59.000Z

    effects of iron and aluminum on stress-related genelopathy syndrome. Possible aluminum intoxication. N. Engl.Chronic exposure to aluminum in drinking water increases

  14. IMPROVED FORMABILITY OF ALUMINUM-GERMANIUM NEAR EUTECTIC COMPOSITIONS THROUGH THE APPLICATION OF SUPERPLASTICITY PRINCIPLES

    E-Print Network [OSTI]

    Pech, G.J.

    2011-01-01T23:59:59.000Z

    IMPROVED FORMABILITY OF ALUMINUM-GERMANIUM NEAR EUTECTICIMPROVED FORMABILITY OF ALUMINUM-GERMANIUM NEAR EUTECTICAl-Ge) wire. Al-Ge «00F Aluminum-Germanium Atomic Percentage

  15. Transcriptomic analysis reveals differential gene expression in common bean (Phaseoulus vulgaris) for aluminum resistance

    E-Print Network [OSTI]

    Eticha, Dejene; Zahn, Marc; Rao, Idupulapati M.; Horst, Walter J.

    2009-01-01T23:59:59.000Z

    transition zone is the most aluminum-sensitive apical rootsoils is mainly limited by aluminum toxicity. In addition,L. under conditions of aluminum stress. Plant Physiol 104:

  16. CHARACTERIZATION OF THE GASEOUS AND SOLID PRODUCTS OF DECOMPOSITION OF ALUMINUM SULFATE

    E-Print Network [OSTI]

    Knutsen, G.F.

    2010-01-01T23:59:59.000Z

    OF DECOMPOSITION OF ALUMINUM SULFATE Gary F. Knutsen (M. S.OF DECOMPOSITION OF ALUMINUM SULFATE Contents Abstract . .OF DECOMPOSITION OF ALUMINUM SULFATE Gary F. Knutsen

  17. A Study of Aluminum Dependent Root Growth Inhibition in Arabidopsis thaliana

    E-Print Network [OSTI]

    Nezames, Cynthia

    2011-01-01T23:59:59.000Z

    symptom triggered by aluminum, but not the primary cause ofRI (1986) Characterization of hydroxy-aluminum solutionsby aluminum-27 nuclear magnetic resonance spectroscopy. Soil

  18. [Aluminum coordination and active sites on aluminas, Y-zeolites and pillared layered silicates]. Progress report

    SciTech Connect (OSTI)

    Fripiat, J.J.

    1994-02-01T23:59:59.000Z

    This report is organized in four sections. In the first the authors will outline structural features which are common to all fine grained alumina, as well as to non-framework alumina in zeolites. This section will be followed by a study of the surface vs. bulk coordination of aluminum. The third section will deal with measurement of the number of acid sites and the scaling of their strength. The fourth and last section will describe three model reactions: the isomerization of 1-butene and of 2 cis-butene; the isomerization and disproportionation of oxtho-xylene; and the transformation of trichloroethane into vinyl chloride followed by the polymerization of the vinyl chloride. The relationship between chemical activity and selectivity and what is known of the local structure of the active catalytic sites will be underlined. Other kinds of zeolites besides Y zeolite have been studied. Instead of the aluminum pillared silicates they found it more interesting to study the substitution of silicon by aluminum in a layered structure containing a permanent porosity (aluminated sepiolite).

  19. The magnesium nutrition of American upland and Egyptian cottons

    E-Print Network [OSTI]

    Helmy, Hussein

    1956-01-01T23:59:59.000Z

    of phosphate, it is believed to be involved 1n phospholipM formation and in the synthesis of nucleo-proteins 1n plant cells accord- ing to Trucg gt al . (56). Bear et sic (4) found that oily seeds are especially h1gh in magnesium indicating some close...

  20. The Microstructure of Mechanically Alloyed Nanocrystalline Aluminium-Magnesium

    E-Print Network [OSTI]

    Gubicza, Jenõ

    The Microstructure of Mechanically Alloyed Nanocrystalline Aluminium-Magnesium Jen Gubicza1, mechanical alloying, nanocrystalline Al-Mg alloys Abstract. The effect of the nominal Mg content and the milling time on the microstructure of mechanically alloyed Al(Mg) solid solutions is studied

  1. The galvanic corrosion behavior of depleted uranium in synthetic seawater coupled to aluminum, magnesium, and mild steel

    SciTech Connect (OSTI)

    McIntyre, J.F.; LeFeave, E.P.; Musselman, K.A.

    1987-01-01T23:59:59.000Z

    The galvanic corrosion behavior of a depleted uranium-titanium alloy (Du-.75Ti) coupled to MgZk60A-T5, AA-7075-T6, bare steel-4340, and coated steel-4340 exposed to ASTM seawater was investigated by monitoring the galvanic current with time. Gravimetric measurements, polarization resistance measurements, and concepts of ''mixed-potential'' theory were used to calculate corrosion rates. It was demonstrated that galvanic currents must be monitored over extended periods of time to detect changes in the galvanic corrosion behavior. Good agreement was obtained for corrosion rates calculated using the concepts of ''mixed-potential'' theory and those obtained from gravimetric measurements.

  2. The effect of a prolonged magnesium restriction on the humoral immune response in maternal rats and their offspring 

    E-Print Network [OSTI]

    Cohill, Diane T

    1987-01-01T23:59:59.000Z

    and to observe alteration in these effects resulting from magnesium supplementation during gestation and lactation. Female weanling Sprague-Dawley rats were provided diets containing adequate (1200 mg Mg/kg diet) or inadequate (200 mg Mg/kg diet) magnesium...), was lower in the magnesium-restricted dams, In the group which had been magnesium restricted during growth but then received supplemental magnesium during gestation and lactation, dams had an improved immune r esponse; but pups did not lt was conc...

  3. The effects of process variations on residual stress in laser peened 7049 T73 aluminum alloy

    E-Print Network [OSTI]

    Rankin, Jon E; Hill, Michael R; Hackel, Lloyd A

    2003-01-01T23:59:59.000Z

    Handbook - Aluminum and Aluminum Alloys, ASM International,the Fatigue Life of 7050 Aluminum Alloy, Defence Science &in laser peened 7049 T73 aluminum alloy Jon E. Rankin and

  4. Rapid silicon outdiffusion from SiC substrates during molecular-beam epitaxial growth of AlGaN/GaN/AlN transistor structures

    SciTech Connect (OSTI)

    Hoke, W.E.; Torabi, A.; Mosca, J.J.; Hallock, R.B.; Kennedy, T.D. [Raytheon RF Components, 362 Lowell Street, Andover, Massachusetts 01810 (United States)

    2005-10-15T23:59:59.000Z

    AlGaN/GaN/AlN transistor structures were grown onto SiC substrates by molecular-beam epitaxy. Under aluminum-rich growth conditions for the AlN nucleation layer, undesirable n-type conduction is observed near the GaN/AlN interface for even thick (>1000 A) AlN layers. Silicon is identified as the unwanted dopant from secondary-ion mass spectroscopy measurements. Atomic force microscopy surface maps reveal free aluminum metal on AlN surfaces grown under modest aluminum-rich conditions. It is proposed that rapid silicon migration is caused by molten aluminum reacting with the SiC substrate resulting in dissolved silicon that rapidly migrates through the growing AlN layer. This behavior is significantly reduced using a growth flux ratio of aluminum to reactive nitrogen close to unity. The resulting buffer leakage current of the GaN high electron mobility transistor structure is reduced by more than four orders of magnitude.

  5. EFFECT OF MECHANICAL DISCONTINUITIES ON THE STRENGTH OF POLYCRYSTALLINE ALUMINUM OXIDE

    E-Print Network [OSTI]

    Wallace, J.S.

    2011-01-01T23:59:59.000Z

    THE STRENGTH OF POLYCRYSTALLINE ALUMINUM OXIDE S. Wallace ofThe variables and number of aluminum oxide (almnina). size~

  6. ALUMINUM AND CHROMIUM LEACHING WORKSHOP WHITEPAPER

    SciTech Connect (OSTI)

    McCabe, D; Jeff Pike, J; Bill Wilmarth, B

    2007-04-25T23:59:59.000Z

    A workshop was held on January 23-24, 2007 to discuss the status of processes to leach constituents from High Level Waste (HLW) sludges at the Hanford and Savannah River Sites. The objective of the workshop was to examine the needs and requirements for the HLW flowsheet for each site, discuss the status of knowledge of the leaching processes, communicate the research plans, and identify opportunities for synergy to address knowledge gaps. The purpose of leaching of non-radioactive constituents from the sludge waste is to reduce the burden of material that must be vitrified in the HLW melter systems, resulting in reduced HLW glass waste volume, reduced disposal costs, shorter process schedules, and higher facility throughput rates. The leaching process is estimated to reduce the operating life cycle of SRS by seven years and decrease the number of HLW canisters to be disposed in the Repository by 1000 [Gillam et al., 2006]. Comparably at Hanford, the aluminum and chromium leaching processes are estimated to reduce the operating life cycle of the Waste Treatment Plant by 20 years and decrease the number of canisters to the Repository by 15,000-30,000 [Gilbert, 2007]. These leaching processes will save the Department of Energy (DOE) billions of dollars in clean up and disposal costs. The primary constituents targeted for removal by leaching are aluminum and chromium. It is desirable to have some aluminum in glass to improve its durability; however, too much aluminum can increase the sludge viscosity, glass viscosity, and reduce overall process throughput. Chromium leaching is necessary to prevent formation of crystalline compounds in the glass, but is only needed at Hanford because of differences in the sludge waste chemistry at the two sites. Improving glass formulations to increase tolerance of aluminum and chromium is another approach to decrease HLW glass volume. It is likely that an optimum condition can be found by both performing leaching and improving formulations. Disposal of the resulting aluminum and chromium-rich streams are different at the two sites, with vitrification into Low Activity Waste (LAW) glass at Hanford, and solidification in Saltstone at SRS. Prior to disposal, the leachate solutions must be treated to remove radionuclides, resulting in increased operating costs and extended facility processing schedules. Interim storage of leachate can also add costs and delay tank closure. Recent projections at Hanford indicate that up to 40,000 metric tons of sodium would be needed to dissolve the aluminum and maintain it in solution, which nearly doubles the amount of sodium in the entire current waste tank inventory. This underscores the dramatic impact that the aluminum leaching can have on the entire system. A comprehensive view of leaching and the downstream impacts must therefore be considered prior to implementation. Many laboratory scale tests for aluminum and chromium dissolution have been run on Hanford wastes, with samples from 46 tanks tested. Three samples from SRS tanks have been tested, out of seven tanks containing high aluminum sludge. One full-scale aluminum dissolution was successfully performed on waste at SRS in 1982, but generated a very large quantity of liquid waste ({approx}3,000,000 gallons). No large-scale tests have been done on Hanford wastes. Although the data to date give a generally positive indication that aluminum dissolution will work, many issues remain, predominantly because of variable waste compositions and changes in process conditions, downstream processing, or storage limitations. Better approaches are needed to deal with the waste volumes and limitations on disposal methods. To develop a better approach requires a more extensive understanding of the kinetics of dissolution, as well as the factors that effect rates, effectiveness, and secondary species. Models of the dissolution rate that have been developed are useful, but suffer from limitations on applicable compositional ranges, mineral phases, and particle properties that are difficult to measure. The experimental

  7. Excimer laser interactions with an aluminum alloy

    SciTech Connect (OSTI)

    Koutsomichalis, A.; Kefalidou, A. [National Technical Univ. of Athens (Greece). Lab. of Physical Metallurgy

    1996-10-01T23:59:59.000Z

    An AlCuMg alloy was irradiated using a KrF pulsed excimer laser. A microstructural study showed the presence of a laser treated zone having a uniform depth of approximately 20 {micro}m. The surface layer of the laser treated aluminum alloy exhibited a wavy topography and its surface roughness was found to depend on the number of laser pulses per step. A X-ray diffraction analysis revealed the presence of aluminum oxides and nitrides on the surface of the laser irradiated specimens. Corrosion measurements showed that the laser treated aluminum alloy exhibited a higher corrosion resistance. The corrosion behavior of the irradiated specimens is related to the energy density of the incident laser pulses.

  8. Aluminum phosphate ceramics for waste storage

    SciTech Connect (OSTI)

    Wagh, Arun; Maloney, Martin D

    2014-06-03T23:59:59.000Z

    The present disclosure describes solid waste forms and methods of processing waste. In one particular implementation, the invention provides a method of processing waste that may be particularly suitable for processing hazardous waste. In this method, a waste component is combined with an aluminum oxide and an acidic phosphate component in a slurry. A molar ratio of aluminum to phosphorus in the slurry is greater than one. Water in the slurry may be evaporated while mixing the slurry at a temperature of about 140-200.degree. C. The mixed slurry may be allowed to cure into a solid waste form. This solid waste form includes an anhydrous aluminum phosphate with at least a residual portion of the waste component bound therein.

  9. Method of winning aluminum metal from aluminous ore

    DOE Patents [OSTI]

    Loutfy, Raouf O. (Naperville, IL); Keller, Rudolf (Naperville, IL); Yao, Neng-Ping (Clarendon Hills, IL)

    1981-01-01T23:59:59.000Z

    Aluminous ore such as bauxite containing alumina is blended with coke or other suitable form of carbon and reacted with sulfur gas at an elevated temperature. For handling, the ore and coke can be extruded into conveniently sized pellets. The reaction with sulfur gas produces molten aluminum sulfide which is separated from residual solid reactants and impurities. The aluminum sulfide is further increased in temperature to cause its decomposition or sublimation, yielding aluminum subsulfide liquid (AlS) and sulfur gas that is recycled. The aluminum monosulfide is then cooled to below its disproportionation temperature to again form molten aluminum sulfide and aluminum metal. A liquid-liquid or liquid-solid separation, depending on the separation temperature, provides product aluminum and aluminum sulfide for recycle to the disproportionation step.

  10. Reaction of Aluminum with Water to Produce Hydrogen - 2010 Update

    Fuel Cell Technologies Publication and Product Library (EERE)

    A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage The purpose of this White Paper is to describe and evaluate the potential of aluminum-water reactions for the

  11. aluminum pressure vessels: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    angular region on the surface Stokes, Yvonne 204 iCons, 2011 Alzheimers and Aluminum: Lesson Plan Chemistry Websites Summary: iCons, 2011 Alzheimers and Aluminum: Lesson Plan...

  12. Reaction of Aluminum with Water to Produce Hydrogen: A Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Produce Hydrogen: A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage. Version 2, 2010. Reaction of Aluminum with Water to Produce Hydrogen: A...

  13. Development of a Cosmetic Corrosion Test for Aluminum Autobody...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a Cosmetic Corrosion Test for Aluminum Autobody Panels AMD 309 Development of a Cosmetic Corrosion Test for Aluminum Autobody Panels AMD 309 Presentation from the U.S. DOE Office...

  14. Characterizing Microalgae (Nannochloris oculata) Harvesting by Aluminum Flocculation 

    E-Print Network [OSTI]

    Davis, Ryan T.

    2012-02-14T23:59:59.000Z

    oculata by aluminum chloride. N. oculata flocculation was studied by manipulating the culture pH and ionic strength before the addition of aluminum chloride. The removal efficiency, concentration factor, settling rate, and zeta potential of the culture...

  15. Strategies for aluminum recycling : insights from material system optimization

    E-Print Network [OSTI]

    Li, Preston Pui-Chuen

    2005-01-01T23:59:59.000Z

    The dramatic increase in aluminum consumption over the past decades necessitates a societal effort to recycle and reuse these materials to promote true sustainability and energy savings in aluminum production. However, the ...

  16. ALUMINUM--1997 5.1 By Patricia A. Plunkert

    E-Print Network [OSTI]

    aluminum smelter by February 1998 at an annual rate of 27,000 tons. The Troutdale smelter, which has at its 204,000-ton- per-year Longview, WA, primary aluminum smelter. The restart was expected

  17. New, More Efficient Technology for Remelting Aluminum Chips

    E-Print Network [OSTI]

    Hosek, D.

    step. Lastly, a new more efficient technology for stirring the molten aluminum during the recycling process will be introduce. A molten metal pump will be employed to stir the molten aluminum more completely....

  18. aluminum phosphate catalyst: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Chair... Balasubramanian, Rajasekaran 1991-01-01 213 The corrosion of aluminum in boric acid solutions Texas A&M University - TxSpace Summary: THE CORROSION OF ALUMINUM IN...

  19. aluminum sodium sulfate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Chair... Balasubramanian, Rajasekaran 1991-01-01 232 The corrosion of aluminum in boric acid solutions Texas A&M University - TxSpace Summary: THE CORROSION OF ALUMINUM IN...

  20. aluminum inorganic compounds: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Chair... Balasubramanian, Rajasekaran 1991-01-01 211 The corrosion of aluminum in boric acid solutions Texas A&M University - TxSpace Summary: THE CORROSION OF ALUMINUM IN...

  1. ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement ID:23278) ORNL: Low-Cost Direct Bonded Aluminum (DBA) Substrates (Agreement ID:23278) 2013 DOE Hydrogen and Fuel...

  2. Measurements of electrical and mechanical properties of aluminum composite cryoconductors

    E-Print Network [OSTI]

    Sundby, Paul C.

    1994-01-01T23:59:59.000Z

    The results of annealing on the residual resistance ratio (RRR) of five (5) composite aluminum cryoconductor wires and mechanical properties on fifteen (15) aluminum cryoconductor wires are presented. The independent variables of the study include...

  3. Does aluminum smelting cause lung disease

    SciTech Connect (OSTI)

    Abramson, M.J.; Wlodarczyk, J.H.; Saunders, N.A.; Hensley, M.J.

    1989-04-01T23:59:59.000Z

    The evidence concerning a relationship between work in the aluminum industry and lung disease has been reviewed using epidemiologic criteria. Adequate data on environmental exposure are rarely presented. Case series on aluminum potroom workers over the past 50 years have identified an asthmalike syndrome that appears to be due to an irritant rather than an allergic mechanism. These studies have been supported by evidence of within shift variability of measures of lung function. However, to date, there is inadequate evidence to resolve the question of whether potroom exposure initiates asthma or merely precipitates asthmalike symptoms in a predisposed individual. Cross-sectional studies have demonstrated evidence of reduced lung function, consistent with chronic airflow limitation. In exposed aluminum smelter workers compared to unexposed control subjects. Cigarette smoking, the major potential confounding variable, has been measured and accounted for in multivariate analyses. To date, evidence is lacking from longitudinal studies about the development of disabling chronic obstructive lung disease. Exposure to coal tar pitch volatiles in the production and consumption of anodes has biologic plausibility for an association of lung cancer with work in an aluminum smelter. Although retrospective mortality studies have failed to account for the probable high prevalence of smoking in blue collar workers, the relative risk of lung cancer is very low if present at all. Pulmonary fibrosis has not been shown to be a significant problem in aluminum smelter workers. Future research in the aluminum industry needs to concentrate on longitudinal studies, preferably with an inception cohort for the investigation of potroom asthma. 92 references.

  4. Optical properties of nanostructured silicon-rich silicon dioxide

    E-Print Network [OSTI]

    Stolfi, Michael Anthony

    2006-01-01T23:59:59.000Z

    We have conducted a study of the optical properties of sputtered silicon-rich silicon dioxide (SRO) thin films with specific application for the fabrication of erbium-doped waveguide amplifiers and lasers, polarization ...

  5. Method And Reactor For Production Of Aluminum By Carbothermic Reduction Of Alumina

    DOE Patents [OSTI]

    Aune, Jan Arthur (Ytre Enebakk, NO); Johansen, Kai (Kristiansand, NO)

    2004-10-19T23:59:59.000Z

    A hollow partition wall is employed to feed carbon material to an underflow of a carbothermic reduction furnace used to make aluminum. The partition wall divides a low temperature reaction zone where aluminum oxide is reacted with carbon to form aluminum carbide and a high temperature reaction zone where the aluminum carbide and remaining aluminum oxide are reacted to form aluminum and carbon monoxide.

  6. Aluminum across the Americas: Caribbean Mobilities and Transnational American Studies

    E-Print Network [OSTI]

    Sheller, Mimi

    2013-01-01T23:59:59.000Z

    zinc, bauxite, and the hydroelectric power needed to smeltthe Afobaka hydroelectric dam to power an aluminum smelter

  7. The corrosion of aluminum in boric acid solutions 

    E-Print Network [OSTI]

    Bass, Henry Kinsolving

    1956-01-01T23:59:59.000Z

    An investigation of the corrosion of aluminum in boric acid solutions was made. The total immersion, continuous agitation method of testing was used. Commercially pure aluminum and two aluminum alloys were exposed to various concentrations of boric acid...THE CORROSION OF ALUMINUM IN BORIC ACID SOLUTIONS A Thesis By HENRI KINSOLVING BASS, JR. Submitted to the Graduate School of the Agricultural and Mechanical College oi' Texas' in partial fulfillment of the requirements for the degree...

  8. Cathode Connector For Aluminum Low Temperature Smelting Cell

    DOE Patents [OSTI]

    Brown, Craig W. (Seattle, WA); Beck, Theodore R. (Seattle, WA); Frizzle, Patrick B. (Seattle, WA)

    2003-07-16T23:59:59.000Z

    Cathode connector means for low temperature aluminum smelting cell for connecting titanium diboride cathode or the like to bus bars.

  9. Review of technical literature and trends related to automobile mass-reduction technology

    E-Print Network [OSTI]

    Lutsey, Nicholas P.

    2010-01-01T23:59:59.000Z

    Similarly, lower density aluminum alloys continue to replacespaceframe Thinner, aluminum alloy Composite Aluminum-to aluminum or aluminum-magnesium alloy engine blocks (see,

  10. PREDICTION OF DEFORMATION AND HOT TEAR FORMATION USING A VISCOPLASTIC MODEL WITH DAMAGE

    E-Print Network [OSTI]

    Beckermann, Christoph

    of the hot tears. Introduction The automotive industry is showing greater interest in magnesium alloys as they have a high strength to weight ratio when compared to steel or aluminum alloys. Because of their low was 8.61% aluminum, 0.6% zinc, 0.23% manganese, 0.017% silicon, 0.003% copper, 0.0038% iron, 0

  11. Activated aluminum hydride hydrogen storage compositions and uses thereof

    DOE Patents [OSTI]

    Sandrock, Gary (Ringwood, NJ); Reilly, James (Bellport, NY); Graetz, Jason (Mastic, NY); Wegrzyn, James E. (Brookhaven, NY)

    2010-11-23T23:59:59.000Z

    In one aspect, the invention relates to activated aluminum hydride hydrogen storage compositions containing aluminum hydride in the presence of, or absence of, hydrogen desorption stimulants. The invention particularly relates to such compositions having one or more hydrogen desorption stimulants selected from metal hydrides and metal aluminum hydrides. In another aspect, the invention relates to methods for generating hydrogen from such hydrogen storage compositions.

  12. Aluminum Reactions and Problems in Municipal Solid Waste Landfills

    E-Print Network [OSTI]

    Aluminum Reactions and Problems in Municipal Solid Waste Landfills G. Vincent Calder, Ph.D.1 ; and Timothy D. Stark, Ph.D., P.E., F.ASCE2 Abstract: Aluminum enters municipal solid waste MSW landfills from: Solid wastes; Aluminum; Chemicals; Waste disposal; Landfills. Author keywords: Solid waste; Leachate

  13. Optical frequency standards based on mercury and aluminum ions

    E-Print Network [OSTI]

    Optical frequency standards based on mercury and aluminum ions W. M. Itano, J. C. Bergquist, A-16 . Keywords: aluminum, atomic clocks, frequency standards, ion traps, mercury 1. INTRODUCTION Optical frequency standards based on the mercury ion and, more recently, the aluminum ion are under devel- opment

  14. Mobilizing aluminum in crustal and mantle fluids Craig E. Manning

    E-Print Network [OSTI]

    Manning, Craig

    Mobilizing aluminum in crustal and mantle fluids Craig E. Manning Department of Earth and Space December 2005 Available online 9 March 2006 Abstract Aluminum is a major rock-forming element, but its low by formation of polynuclear Na­Al­Si­O clusters and/or polymers. Aluminum should not be assumed to be immobile

  15. Inhibition of Aluminum Oxyhydroxide Precipitation with Citric Acid

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    Inhibition of Aluminum Oxyhydroxide Precipitation with Citric Acid Daniel M. Dabbs, Usha as an agent for increasing the solubility of aluminum oxyhydroxides in aqueous solutions of high (>2.47 mol/mol) hydroxide-to-aluminum ratios. Conversely, citric acid also colloidally stabilizes particles in aqueous

  16. POST-SHOCK TEMPERATURE MEASUREMENTS OF ALUMINUM A. Seifter1

    E-Print Network [OSTI]

    Stewart, Sarah T.

    POST-SHOCK TEMPERATURE MEASUREMENTS OF ALUMINUM A. Seifter1 , S. T. Stewart2 , M. R. Furlanetto1 concurrent VISAR measurements in the same optical path, validation experiments on aluminum have been-shock temperature of 495 K ± 30 K was recorded from a polished free surface of aluminum 2024-T4 subject to a peak

  17. The Effects of Fe3+ Aluminum Silicate Phase Relations in

    E-Print Network [OSTI]

    Lee, Cin-Ty Aeolus

    The Effects of Fe3+ and Mn3+ on Aluminum Silicate Phase Relations in North-Central New Mexico, U, New Mexico 87131 (Received 28 November 1983; in revised form 2 October 1984) ABSTRACT Aluminum, then their equilibrium coexistence is invariant. However, the aluminum silicate minerals are not pure in highly oxidized

  18. Aluminum Removal from Photographic Waste Submitted to Dr. Tony Bi

    E-Print Network [OSTI]

    Aluminum Removal from Photographic Waste Submitted to Dr. Tony Bi By: Kristen Favel, Tiffany Jung, and Kenny Tam CHBE 484 University of British Columbia April 15, 2009 #12;ii "Aluminum Removal from photographic waste has shown elevated levels of aluminum in the fixer, which exceed sewer discharge standards

  19. ccsd00002835, Light scattering from cold rolled aluminum surfaces

    E-Print Network [OSTI]

    ccsd­00002835, version 2 ­ 14 Sep 2004 Light scattering from cold rolled aluminum surfaces Damien Camille Soula , 31400 Toulouse, France We present experimental light scattering measurements from aluminum scattering measurements of an s-polarized electromagnetic wave (632.8 nanometers) from a rough aluminum alloy

  20. Review Article Aluminum-Induced Entropy in Biological Systems

    E-Print Network [OSTI]

    Seneff, Stephanie

    Review Article Aluminum-Induced Entropy in Biological Systems: Implications for Neurological years, mining, smelting, and refining of aluminum (Al) in various forms have increasingly exposed living of the Al toxicants to which we are being exposed. 1. Introduction Aluminum (Al) is the most common metal

  1. CLASSIFICATION AND REACTIVITY OF SECONDARY ALUMINUM PRODUCTION WASTE

    E-Print Network [OSTI]

    environment.14 Keywords: Landfills, aluminum, hydrogen, salt cake, dross, calorimeter, waste disposal15 16 17CLASSIFICATION AND REACTIVITY OF SECONDARY ALUMINUM PRODUCTION WASTE Navid H. Jafari Student Member and Reactivity of Secondary Aluminum Production Waste1 Navid H. Jafari1 , Timothy D. Stark2 and Ralph Roper3 2 3

  2. Switchable mirrors based on nickel-magnesium films

    SciTech Connect (OSTI)

    Richardson,Thomas J.; Slack, Jonathan L.; Armitage, Robert D.; Kostecki, Robert; Farangis, Baker; Rubin, Michael D.

    2001-01-16T23:59:59.000Z

    A new type of electrochromic mirror electrode based on reversible uptake of hydrogen in nickel magnesium alloy films is reported. Thin,magnesium-rich Ni-Mg films prepared on glass substrates by cosputtering from Ni and Mg targets are mirror-like in appearance and have low visible transmittance. Upon exposure to hydrogen gas or on reduction in alkaline electrolyte, the films take up hydrogen and become transparent. When hydrogen is removed, the mirror properties are recovered. The transition is believed to result from reversible formation of Mg2NiH4 and MgH2. A thin overlayer of palladium was found to enhance the kinetics of hydrogen insertion and extraction,and to protect the metal surface against oxidation.

  3. Electrical transport behavior of nonstoichiometric magnesium-zinc ferrite

    SciTech Connect (OSTI)

    Ghatak, S. [Department of Physics, National Institute of Technology, Deemed University, Mahatma Gandhi Avenue, Durgapur 713209, West Bengal (India)] [Department of Physics, National Institute of Technology, Deemed University, Mahatma Gandhi Avenue, Durgapur 713209, West Bengal (India); Sinha, M. [Department of Physics, University of Burdwan, Golapbag, Burdwan 713104, West Bengal (India)] [Department of Physics, University of Burdwan, Golapbag, Burdwan 713104, West Bengal (India); Meikap, A.K., E-mail: meikapnitd@yahoo.com [Department of Physics, National Institute of Technology, Deemed University, Mahatma Gandhi Avenue, Durgapur 713209, West Bengal (India); Pradhan, S.K. [Department of Physics, University of Burdwan, Golapbag, Burdwan 713104, West Bengal (India)] [Department of Physics, University of Burdwan, Golapbag, Burdwan 713104, West Bengal (India)

    2010-08-15T23:59:59.000Z

    This paper presents the direct current conductivity, alternate current conductivity and dielectric properties of nonstoichiometric magnesium-zinc ferrite below room temperature. The frequency exponent (s) of conductivity shows an anomalous temperature dependency. The magnitude of the temperature exponent (n) of dielectric permittivity strongly depends on frequency and its value decreases with increasing frequency. The grain boundary contribution is dominating over the grain contribution in conduction process and the temperature dependence of resistance due to grain and grain boundary contribution exhibits two activation regions. The ferrite shows positive alternating current magnetoconductivity. The solid state processing technique was used for the preparation of nanocrystalline ferrite powder from oxides of magnesium, zinc and iron. The X-ray diffraction methods were used in determining the structure and composition of obtained ferrite, while multimeter, impedance analyzer, liquid nitrogen cryostat and electromagnet were used in the study of conducting and dielectric properties of ferrite.

  4. ECONOMIC IMPACT OF CENTURY ALUMINUM OF

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    ECONOMIC IMPACT OF CENTURY ALUMINUM OF WEST VIRGINIA, INC. By Randall A. Childs Bureau of Business and Economic Research College of Business and Economics West Virginia more than 660 employees with a production capacity of 170,000 tonnes per year. The economic impact

  5. Flash threshold of shocked aluminum silicofluoride

    SciTech Connect (OSTI)

    Bloom, G.H.

    1987-11-01T23:59:59.000Z

    For a 0.5-mm polycarbonate flier striking a 0.5-mm polycarbonate target, we found that a velocity of 1.42 km/s was necessary to cause aluminum silicofluoride sprayed on the far surface to flash. We calculated that the pressure in the polycarbonate was 2.93 GPa. 5 refs., 2 figs.

  6. Aluminum Solubility in Complex Electrolytes - 13011

    SciTech Connect (OSTI)

    Agnew, S.F. [Columbia Energy and Environmental Services, Inc., 1806 Terminal Dr., Richland, WA 99354 (United States)] [Columbia Energy and Environmental Services, Inc., 1806 Terminal Dr., Richland, WA 99354 (United States); Johnston, C.T. [Dept. of Crop, Soil, and Environmental Sciences, Purdue University, West Lafayette, IN 47907 (United States)] [Dept. of Crop, Soil, and Environmental Sciences, Purdue University, West Lafayette, IN 47907 (United States)

    2013-07-01T23:59:59.000Z

    Predicting aluminum solubility for Hanford and Savannah River waste liquids is very important for their disposition. It is a key mission goal at each Site to leach as much aluminum as practical from sludges in order to minimize the amount of vitrified high level waste. And it is correspondingly important to assure that any soluble aluminum does not precipitate during subsequent decontamination of the liquid leachates with ion exchange. This report shows a very simple and yet thermodynamic model for aluminum solubility that is consistent with a wide range of Al liquors, from simple mixtures of hydroxide and aluminate to over 300 Hanford concentrates and to a set of 19 Bayer liquors for temperatures from 20-100 deg. C. This dimer-dS{sub mix} (DDS) model incorporates an ideal entropy of mixing along with previous reports for the Al dimer, water activities, gibbsite, and bayerite thermodynamics. We expect this model will have broad application for nuclear wastes as well as the Bayer gibbsite process industry. (authors)

  7. Chemical vapor deposition of aluminum oxide

    DOE Patents [OSTI]

    Gordon, Roy (Cambridge, MA); Kramer, Keith (Cleveland, OH); Liu, Xinye (Cambridge, MA)

    2000-01-01T23:59:59.000Z

    An aluminum oxide film is deposited on a heated substrate by CVD from one or more alkylaluminum alkoxide compounds having composition R.sub.n Al.sub.2 (OR').sub.6-n, wherein R and R' are alkyl groups and n is in the range of 1 to 5.

  8. Floating Silicon Method

    SciTech Connect (OSTI)

    Kellerman, Peter

    2013-12-21T23:59:59.000Z

    The Floating Silicon Method (FSM) project at Applied Materials (formerly Varian Semiconductor Equipment Associates), has been funded, in part, by the DOE under a “Photovoltaic Supply Chain and Cross Cutting Technologies” grant (number DE-EE0000595) for the past four years. The original intent of the project was to develop the FSM process from concept to a commercially viable tool. This new manufacturing equipment would support the photovoltaic industry in following ways: eliminate kerf losses and the consumable costs associated with wafer sawing, allow optimal photovoltaic efficiency by producing high-quality silicon sheets, reduce the cost of assembling photovoltaic modules by creating large-area silicon cells which are free of micro-cracks, and would be a drop-in replacement in existing high efficiency cell production process thereby allowing rapid fan-out into the industry.

  9. FLOWSHEET FOR ALUMINUM REMOVAL FROM SLUDGE BATCH 6

    SciTech Connect (OSTI)

    Pike, J; Jeffrey Gillam, J

    2008-12-17T23:59:59.000Z

    Samples of Tank 12 sludge slurry show a substantially larger fraction of aluminum than originally identified in sludge batch planning. The Liquid Waste Organization (LWO) plans to formulate Sludge Batch 6 (SB6) with about one half of the sludge slurry in Tank 12 and one half of the sludge slurry in Tank 4. LWO identified aluminum dissolution as a method to mitigate the effect of having about 50% more solids in High Level Waste (HLW) sludge than previously planned. Previous aluminum dissolution performed in a HLW tank in 1982 was performed at approximately 85 C for 5 days and dissolved nearly 80% of the aluminum in the sludge slurry. In 2008, LWO successfully dissolved 64% of the aluminum at approximately 60 C in 46 days with minimal tank modifications and using only slurry pumps as a heat source. This report establishes the technical basis and flowsheet for performing an aluminum removal process in Tank 51 for SB6 that incorporates the lessons learned from previous aluminum dissolution evolutions. For SB6, aluminum dissolution process temperature will be held at a minimum of 65 C for at least 24 days, but as long as practical or until as much as 80% of the aluminum is dissolved. As planned, an aluminum removal process can reduce the aluminum in SB6 from about 84,500 kg to as little as 17,900 kg with a corresponding reduction of total insoluble solids in the batch from 246,000 kg to 131,000 kg. The extent of the reduction may be limited by the time available to maintain Tank 51 at dissolution temperature. The range of dissolution in four weeks based on the known variability in dissolution kinetics can range from 44 to more than 80%. At 44% of the aluminum dissolved, the mass reduction is approximately 1/2 of the mass noted above, i.e., 33,300 kg of aluminum instead of 66,600 kg. Planning to reach 80% of the aluminum dissolved should allow a maximum of 81 days for dissolution and reduce the allowance if test data shows faster kinetics. 47,800 kg of the dissolved aluminum will be stored in Tank 8 and 21,000 kg will be stored in saltcake via evaporation. Up to 77% of the total aluminum planned for SB6 may be removed via aluminum dissolution. Storage of the aluminum-laden supernate in Tank 8 will require routine evaluation of the free hydroxide concentration in order to maintain aluminum in solution. Periodic evaluation will be established on concurrent frequency with corrosion program samples as previously established for aluminum-laden supernate from SB5 that is stored in Tank 11.

  10. Electrochemical thinning of silicon

    DOE Patents [OSTI]

    Medernach, John W. (Albuquerque, NM)

    1994-01-01T23:59:59.000Z

    Porous semiconducting material, e.g. silicon, is formed by electrochemical treatment of a specimen in hydrofluoric acid, using the specimen as anode. Before the treatment, the specimen can be masked. The porous material is then etched with a caustic solution or is oxidized, depending of the kind of structure desired, e.g. a thinned specimen, a specimen, a patterned thinned specimen, a specimen with insulated electrical conduits, and so on. Thinned silicon specimen can be subjected to tests, such as measurement of interstitial oxygen by Fourier transform infra-red spectroscopy (FTIR).

  11. Electrochemical thinning of silicon

    DOE Patents [OSTI]

    Medernach, J.W.

    1994-01-11T23:59:59.000Z

    Porous semiconducting material, e.g. silicon, is formed by electrochemical treatment of a specimen in hydrofluoric acid, using the specimen as anode. Before the treatment, the specimen can be masked. The porous material is then etched with a caustic solution or is oxidized, depending of the kind of structure desired, e.g. a thinned specimen, a specimen, a patterned thinned specimen, a specimen with insulated electrical conduits, and so on. Thinned silicon specimen can be subjected to tests, such as measurement of interstitial oxygen by Fourier transform infra-red spectroscopy (FTIR). 14 figures.

  12. An examination of the relationship between calcium and magnesium and hypertension

    E-Print Network [OSTI]

    Georghiades, Mary Elizabeth

    1988-01-01T23:59:59.000Z

    !ae thr ee blood parameter s best corre)ated with the dietary intake of calcium and magnesium. No i gni f i cant cor r el at i ons (p (0. 05) were ob . , envs d between the calcium, magnesium, or ca)cium/magnesium ratio of the diet and blood tissues... in alterations in the calcium/magnesium ratio. This topic merits Further investigation. ACKNOWLEDGMENTS The author wishes to express her appreciation to Dr. Karen S. Kubena, her advisory committee chairman. For- pr oper guidance, constructive criticism...

  13. Magnesium and pyridoxine intake and mineral content of selected tissues and physical development in rats 

    E-Print Network [OSTI]

    Edgar, Susan Elaine

    1986-01-01T23:59:59.000Z

    lower f eed intake s than did rats from other dietary treatments. During lactation, dai ly feed consumpt ion was lower in an ima1 s depr ived of magnesium. Approximately 24 hr postpartum, in dams who consumed a magnesium-deficient diet, the heart... and kidney contained significantly more calcium, 150'% and 300% respectively. During lactation, mild magnesium restriction resulted in increased weight loss by dams and decreased weight gain by pupa. In the of f spring of rats dep1 et ed o f magnesium...

  14. Production of sodium-22 from proton irradiated aluminum

    DOE Patents [OSTI]

    Taylor, Wayne A. (Los Alamos, NM); Heaton, Richard C. (Los Alamos, NM); Jamriska, David J. (Los Alamos, NM)

    1996-01-01T23:59:59.000Z

    A process for selective separation of sodium-22 from a proton irradiated minum target including dissolving a proton irradiated aluminum target in hydrochloric acid to form a first solution including aluminum ions and sodium ions, separating a portion of the aluminum ions from the first solution by crystallization of an aluminum salt, contacting the remaining first solution with an anion exchange resin whereby ions selected from the group consisting of iron and copper are selectively absorbed by the anion exchange resin while aluminum ions and sodium ions remain in solution, contacting the solution with an cation exchange resin whereby aluminum ions and sodium ions are adsorbed by the cation exchange resin, and, contacting the cation exchange resin with an acid solution capable of selectively separating the adsorbed sodium ions from the cation exchange resin while aluminum ions remain adsorbed on the cation exchange resin is disclosed.

  15. Fabrication of nickel microbump on aluminum using electroless nickel plating

    SciTech Connect (OSTI)

    Watanabe, H.; Honma, H. [Kanto Gakuin Univ., Yokohama, Kanagawa (Japan). Faculty of Engineering

    1997-02-01T23:59:59.000Z

    Fabrication of nickel microbumps on an aluminum electrode using a nickel displacement and a direct nickel plating process was investigated. Electroless nickel plating reaction with hypophosphite as a reducing agent was not initiated on the aluminum substrate, because aluminum does not have catalytic action on the oxidation of hypophosphite. Accordingly, nickel was initially deposited on the aluminum using nickel displacement plating for the initiation of the electroless plating. Nickel bumps on the aluminum electrode were fabricated by treatment of the nickel displacement plating followed by electroless nickel plating. Nickel microbumps also can be formed on the aluminum electrode without the displacement plating process. Activation of the aluminum surface is an indispensable process to initiate electroless nickel plating. Uniform bumps 20 {micro}m wide and 15 {micro}m high with good configuration were obtained by direct nickel plating after being activated with dimethyl amine borane.

  16. Fabrication of porous silicon membranes 

    E-Print Network [OSTI]

    Yue, Wing Kong

    1988-01-01T23:59:59.000Z

    . Porous silicon layer is formed by the local dissolution which is initiated by the surface layer and is promoted by the hindrance layers composed of the silicic acid. Local etching or local dissolution is the cause of forming porous structure... of pores were 25 to 45 A with a mean value of 38 A. Microstructure of porous silicon studied by Besle et al. showed two distinct 17 patterns: the structure pattern of porous silicon film on heavily doped silicon and that on slightly doped silicon [26...

  17. Microarray Analysis on Human Neuroblastoma Cells Exposed to Aluminum, Beta1–42-Amyloid or the Beta1–42-Amyloid Aluminum Complex

    E-Print Network [OSTI]

    2011-01-01T23:59:59.000Z

    J (1992) Selective accumulation of aluminum and iron in theB, Tognon G, Zatta P (2005) Aluminum-triggered structuralrole of beta-amyloid(1-42)-aluminum complex in Alzheimer’s

  18. Amorphous silicon photovoltaic devices

    DOE Patents [OSTI]

    Carlson, David E.; Lin, Guang H.; Ganguly, Gautam

    2004-08-31T23:59:59.000Z

    This invention is a photovoltaic device comprising an intrinsic or i-layer of amorphous silicon and where the photovoltaic device is more efficient at converting light energy to electric energy at high operating temperatures than at low operating temperatures. The photovoltaic devices of this invention are suitable for use in high temperature operating environments.

  19. Recovery of gallium from aluminum industry residues

    SciTech Connect (OSTI)

    Carvalho, M.S.; Neto, K.C.M.; Nobrega, A.W.; Medeiros, J.A.

    2000-01-01T23:59:59.000Z

    A procedure is proposed to recover gallium from flue dust aluminum residues produced in plants by using solid-phase extraction with a commercial polyether-type polyurethane foam (PUF). Gallium can be separated from high concentrations of aluminum, iron, nickel, titanium, vanadium, copper, zinc, sulfate, fluoride, and chloride by extraction with PUF from 3 M sulfuric acid and 3 M sodium chloride concentration medium with at least a 92% efficiency. Gallium backextraction was fast and quantitative with ethanol solution. In all recovery steps commercial-grade reagents could be used, including tap water. The recovered gallium was precipitated with sodium hydroxide solution, purified by dissolution and precipitation, calcinated, and the final oxide was 98.6% pure.

  20. Fluorescence energy transfer enhancement in aluminum nanoapertures

    E-Print Network [OSTI]

    de Torres, Juan; Moparthi, Satish Babu; Grigoriev, Victor; Wenger, Jérome

    2015-01-01T23:59:59.000Z

    Zero-mode waveguides (ZMWs) are confining light into attoliter volumes, enabling single molecule fluorescence experiments at physiological micromolar concentrations. Among the fluorescence spectroscopy techniques that can be enhanced by ZMWs, F\\"{o}rster resonance energy transfer (FRET) is one of the most widely used in life sciences. Combining zero-mode waveguides with FRET provides new opportunities to investigate biochemical structures or follow interaction dynamics at micromolar concentration with single molecule resolution. However, prior to any quantitative FRET analysis on biological samples, it is crucial to establish first the influence of the ZMW on the FRET process. Here, we quantify the FRET rates and efficiencies between individual donor-acceptor fluorophore pairs diffusing in aluminum zero-mode waveguides. Aluminum ZMWs are important structures thanks to their commercial availability and the large literature describing their use for single molecule fluorescence spectroscopy. We also compare the ...

  1. Generation and structural characterization of aluminum cyanoacetylide

    SciTech Connect (OSTI)

    Cabezas, Carlos; Peña, Isabel; Alonso, José L., E-mail: alargo@qf.uva.es, E-mail: jlalonso@qf.uva.es [Grupo de Espectroscopia Molecular (GEM), Edificio Quifima, Laboratorios de Espectroscopia y Bioespectroscopia, Unidad Asociada CSIC, Parque Científico Uva, Universidad de Valladolid, Paseo de Belén 5, 47011 Valladolid (Spain); Barrientos, Carmen; Largo, Antonio, E-mail: alargo@qf.uva.es, E-mail: jlalonso@qf.uva.es [Departamento de Química Física y Química Inorgánica, Facultad de Ciencias, Universidad de Valladolid, Campus Miguel Delibes, Paseo de Belén 7, 47011 Valladolid (Spain); Guillemin, Jean-Claude [Institut des Sciences Chimiques de Rennes, École Nationale Supérieure de Chimie de Rennes, CNRS, UMR 6226, 11 Allée de Beaulieu, CS 50837, 35708 Rennes Cedex 7 (France); Cernicharo, José [Group of Molecular Astrophysics, ICMM C/Sor Juana Ines de la Cruz N3 Cantoblanco, 28049 Madrid (Spain)

    2014-09-14T23:59:59.000Z

    Combined spectroscopy measurements and theoretical calculations bring to light a first investigation of a metallic cyanoacetylide, AlC{sub 3}N, using laser ablation molecular beam Fourier transform microwave spectroscopy. This molecule was synthesized in a supersonic expansion by the reaction of aluminum vapour with C{sub 3}N, produced from solid aluminum rods and BrCCCN in a newly constructed ablation-heating nozzle device. A set of accurate rotational and {sup 27}Al and {sup 14}N nuclear quadrupole coupling constants have been determined from the analysis of the rotational spectrum and compared with those predicted in a high-level ab initio study, conducting to the assignment of the observed species to linear AlCCCN. We have searched for this species towards the carbon-rich evolved star IRC + 10216 but only an upper limit to its abundance has been obtained.

  2. Inert anodes and advanced smelting of aluminum

    SciTech Connect (OSTI)

    ASME Technical Working Group on Inert Anode Technologies

    1999-07-01T23:59:59.000Z

    This report provides a broad assessment of open literature and patents that exist in the area of inert anodes and their related cathode systems and cell designs, technologies that are relevant for the advanced smelting of aluminum. The report also discusses the opportunities, barriers, and issued associated with these technologies from a technical, environmental, and economic viewpoint. It discusses the outlook for the direct retrofit of advanced reduction technologies to existing aluminum smelters, and compares retrofits to ''brown field'' usage and ''green field'' adoption of the technologies. A number of observations and recommendations are offered for consideration concerning further research and development efforts that may be directed toward these advanced technologies. The opportunities are discussed in the context of incremental progress that is being made in conventional Hall-Heroult cell systems.

  3. Laser assisted arc welding for aluminum alloys

    SciTech Connect (OSTI)

    Fuerschbach, P.W.

    2000-01-01T23:59:59.000Z

    Experiments have been performed using a coaxial end-effector to combine a focused laser beam and a plasma arc. The device employs a hollow tungsten electrode, a focusing lens, and conventional plasma arc torch nozzles to co-locate the focused beam and arc on the workpiece. Plasma arc nozzles were selected to protect the electrode from laser generated metal vapor. The project goal is to develop an improved fusion welding process that exhibits both absorption robustness and deep penetration for small scale (<1.5 mm thickness) applications. On aluminum alloys 6061 and 6111, the hybrid process has been shown to eliminate hot cracking in the fusion zone. Fusion zone dimensions for both stainless steel and aluminum were found to be wider than characteristic laser welds, and deeper than characteristic plasma arc welds.

  4. Hybrid Silicon Evanescent Lasers John E. Bowersa

    E-Print Network [OSTI]

    Bowers, John

    [2]. Finally a 110 nm thick n-doped InP spacer is used as a bonding interface to silicon. The silicon factors of the silicon waveguide and the QWs can be manipulated by the silicon waveguide dimensions silicon waveguide. For the fabricated waveguide dimensions of a 0.7 µm height (H) and 0.6 µm rib

  5. Ignition of Aluminum Particles and Clouds

    SciTech Connect (OSTI)

    Kuhl, A L; Boiko, V M

    2010-04-07T23:59:59.000Z

    Here we review experimental data and models of the ignition of aluminum (Al) particles and clouds in explosion fields. The review considers: (i) ignition temperatures measured for single Al particles in torch experiments; (ii) thermal explosion models of the ignition of single Al particles; and (iii) the unsteady ignition Al particles clouds in reflected shock environments. These are used to develop an empirical ignition model appropriate for numerical simulations of Al particle combustion in shock dispersed fuel explosions.

  6. Experimental superplastic characterization of advanced aluminum alloys

    E-Print Network [OSTI]

    Kopp, Christopher Carl

    1991-01-01T23:59:59.000Z

    of America Chairman of Advisory Committee: Dr. R. E. Goforth An investigation into the experimental superplastic characterization of advanced aluminum alloys consisted of the design and assembly of an experimental test facility for measuring the effects... of strain-rate, temperature and hydrostatic pressure. The experimental apparatus was designed to accurately monitor these parameters while allowing for active control of the strain-rate and hydrostatic pressure. The results obtained from...

  7. Dissolved aluminum in the Gulf of Mexico

    E-Print Network [OSTI]

    Myre, Peggy Lynne

    1990-01-01T23:59:59.000Z

    in areas of minimum sediment resuspension. With limited data available it appears that the boundary of the sediment/water interface does release dissolved Al, but kinetically Al should decrease with depth in the sediment during authigenesis. The Al... DISSOLVED ALUMINUM IN THE GULF OF MEXICO A Thesis by PEGGY LYNNE MYRE Submitted to the Office of Graduate Studies of Texas A6M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 1990 Majo...

  8. az31b magnesium alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In particular, the aluminum washer offered each kg means approximately an emission reduction of 0.12 g CO2km. Aluminum as a lightweight material Maume-Deschamps, Vronique...

  9. am60b magnesium alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In particular, the aluminum washer offered each kg means approximately an emission reduction of 0.12 g CO2km. Aluminum as a lightweight material Maume-Deschamps, Vronique...

  10. Influence of argon and oxygen on charge-state-resolved ion energy distributions of filtered aluminum arcs

    E-Print Network [OSTI]

    Rosen, Johanna; Anders, Andre; Mraz, Stanislav; Atiser, Adil; Schneider, Jochen M.

    2006-01-01T23:59:59.000Z

    energy distributions of filtered aluminum arcs Johanna Roséndistributions (IEDs) in filtered aluminum vacuum arc plasmasfor vacuum arc plasmas. Aluminum plasma, for example,

  11. THE PROTOTYPE ALUMINUM - CARBON SINGLE, DOUBLE, AND TRIPLE BONDS: Al - CH3, Al = CH2, AND Al. = CH

    E-Print Network [OSTI]

    Fox, Douglas J.

    2011-01-01T23:59:59.000Z

    three prototype Table II. aluminum-carbon bonds and theirPhysics THE PROTOTYPE ALUMINUM - CARBON SINGLE, DOUBLE, ANDLBL-l0871 The Prototype Aluminum - Carbon Single, Double.

  12. Use of silicon in liquid sintered silicon nitrides and sialons

    DOE Patents [OSTI]

    Raj, Rishi (Ithaca, NY); Baik, Sunggi (Ithaca, NY)

    1984-12-11T23:59:59.000Z

    This invention relates to the production of improved high density nitrogen based ceramics by liquid-phase densification of silicon nitride or a compound of silicon-nitrogen-oxygen-metal, e.g. a sialon. In the process and compositions of the invention minor amounts of finely divided silicon are employed together with the conventional liquid phase producing additives to enhance the densification of the resultant ceramic.

  13. Use of silicon in liquid sintered silicon nitrides and sialons

    DOE Patents [OSTI]

    Raj, R.; Baik, S.

    1984-12-11T23:59:59.000Z

    This invention relates to the production of improved high density nitrogen based ceramics by liquid-phase densification of silicon nitride or a compound of silicon-nitrogen-oxygen-metal, e.g. a sialon. In the process and compositions of the invention minor amounts of finely divided silicon are employed together with the conventional liquid phase producing additives to enhance the densification of the resultant ceramic. 4 figs.

  14. Minerals to Dairy Cows with Focus on Calcium and Magnesium Balance

    E-Print Network [OSTI]

    Minerals to Dairy Cows with Focus on Calcium and Magnesium Balance Cecilia Kronqvist Faculty;Minerals to Dairy Cows with Focus on Calcium and Magnesium Balance Abstract Both clinical and subclinical decreased plasma calcium levels and activated the calcium homeostatic mechanisms. However, there were

  15. Reliability of Laser Welding Process for ZE41A-T5 Magnesium Alloy Sand Castings

    E-Print Network [OSTI]

    Medraj, Mamoun

    Reliability of Laser Welding Process for ZE41A-T5 Magnesium Alloy Sand Castings Haider Al-Kazzaz1, National Research Council Canada, Montreal, Canada Laser welding is a promising joining method for magnesium alloys. The process reliability of 2-mm ZE41A-T5 butt joints welded by a 4 kW Nd:YAG laser

  16. In vitro corrosion and biocompatibility of binary magnesium alloys Xuenan Gu a

    E-Print Network [OSTI]

    Zheng, Yufeng

    In vitro corrosion and biocompatibility of binary magnesium alloys Xuenan Gu a , Yufeng Zheng a Corrosion In vitro Cytotoxicity Hemocompatibility a b s t r a c t As bioabsorbable materials, magnesium was used as control. Their mechanical properties, corrosion properties and in vitro biocompatibilities

  17. Electroless iron plating on pure magnesium for biomedical applications Xingkai Zhang a

    E-Print Network [OSTI]

    Zheng, Yufeng

    : Biomaterials Deposition Corrosion Thin films a b s t r a c t Electroless nickel plating is usually adopted geometries. Electroless nickel plating [10] is usually used to protect the magnesium alloy from corrosionElectroless iron plating on pure magnesium for biomedical applications Xingkai Zhang a , Wei Han a

  18. INSTITUTE FOR SHOCK PHYSICSLaser-Shock Spall Experiments in Aluminum II: Interface Measurements

    E-Print Network [OSTI]

    Collins, Gary S.

    fracture in aluminum alloys at short time scales (10-8 s) · Role of PMMA backing material window -Changing. (2006) * Advised by Yoshi Toyoda and Y. M. Gupta Aluminum Thickness (m) Aluminum Alloy AluminumINSTITUTE FOR SHOCK PHYSICSLaser-Shock Spall Experiments in Aluminum II: Interface Measurements

  19. Friction Stir Weld Failure Mechanisms in Aluminum-Armor Structures Under Ballistic

    E-Print Network [OSTI]

    Grujicic, Mica

    in armor structures made of high-performance aluminum alloys (including solution-strengthened and age-hardenable aluminum alloy grades). It is argued that due to the large width of FSW joints found in thick aluminum-solution strengthened and cold-worked aluminum alloy armor FSW-weld test structure. Keywords aluminum armor, ballistic

  20. High Performance Batteries Based on Hybrid Magnesium and Lithium Chemistry

    SciTech Connect (OSTI)

    Cheng, Yingwen; Shao, Yuyan; Zhang, Jiguang; Sprenkle, Vincent L.; Liu, Jun; Li, Guosheng

    2014-01-01T23:59:59.000Z

    Magnesium and lithium (Mg/Li) hybrid batteries that combine Mg and Li electrochemistry, consisting of a Mg anode, a lithium-intercalation cathode and a dual-salt electrolyte with both Mg2+ and Li+ ions, were constructed and examined in this work. Our results show that hybrid (Mg/Li) batteries were able to combine the advantages of Li-ion and Mg batteries, and delivered outstanding rate performance (83% for capacities at 15C and 0.1C) and superior cyclic stability (~5% fade after 3000 cycles).

  1. Making silicon stronger.

    SciTech Connect (OSTI)

    Boyce, Brad Lee

    2010-11-01T23:59:59.000Z

    Silicon microfabrication has seen many decades of development, yet the structural reliability of microelectromechanical systems (MEMS) is far from optimized. The fracture strength of Si MEMS is limited by a combination of poor toughness and nanoscale etch-induced defects. A MEMS-based microtensile technique has been used to characterize the fracture strength distributions of both standard and custom microfabrication processes. Recent improvements permit 1000's of test replicates, revealing subtle but important deviations from the commonly assumed 2-parameter Weibull statistical model. Subsequent failure analysis through a combination of microscopy and numerical simulation reveals salient aspects of nanoscale flaw control. Grain boundaries, for example, suffer from preferential attack during etch-release thereby forming failure-critical grain-boundary grooves. We will discuss ongoing efforts to quantify the various factors that affect the strength of polycrystalline silicon, and how weakest-link theory can be used to make worst-case estimates for design.

  2. Amorphous silicon radiation detectors

    DOE Patents [OSTI]

    Street, Robert A. (Palo Alto, CA); Perez-Mendez, Victor (Berkeley, CA); Kaplan, Selig N. (El Cerrito, CA)

    1992-01-01T23:59:59.000Z

    Hydrogenated amorphous silicon radiation detector devices having enhanced signal are disclosed. Specifically provided are transversely oriented electrode layers and layered detector configurations of amorphous silicon, the structure of which allow high electric fields upon application of a bias thereby beneficially resulting in a reduction in noise from contact injection and an increase in signal including avalanche multiplication and gain of the signal produced by incoming high energy radiation. These enhanced radiation sensitive devices can be used as measuring and detection means for visible light, low energy photons and high energy ionizing particles such as electrons, x-rays, alpha particles, beta particles and gamma radiation. Particular utility of the device is disclosed for precision powder crystallography and biological identification.

  3. Amorphous silicon radiation detectors

    DOE Patents [OSTI]

    Street, R.A.; Perez-Mendez, V.; Kaplan, S.N.

    1992-11-17T23:59:59.000Z

    Hydrogenated amorphous silicon radiation detector devices having enhanced signal are disclosed. Specifically provided are transversely oriented electrode layers and layered detector configurations of amorphous silicon, the structure of which allow high electric fields upon application of a bias thereby beneficially resulting in a reduction in noise from contact injection and an increase in signal including avalanche multiplication and gain of the signal produced by incoming high energy radiation. These enhanced radiation sensitive devices can be used as measuring and detection means for visible light, low energy photons and high energy ionizing particles such as electrons, x-rays, alpha particles, beta particles and gamma radiation. Particular utility of the device is disclosed for precision powder crystallography and biological identification. 13 figs.

  4. Carbon dioxide adsorbents containing magnesium oxide suitable for use at high temperatures

    DOE Patents [OSTI]

    Mayorga, Steven Gerard (Allentown, PA); Weigel, Scott Jeffrey (Allentown, PA); Gaffney, Thomas Richard (Allentown, PA); Brzozowski, Jeffrey Richard (Macungie, PA)

    2001-01-01T23:59:59.000Z

    Adsorption of carbon dioxide from gas streams at temperatures in the range of 300 to 500.degree. C. is carried out with a solid adsorbent containing magnesium oxide, preferably promoted with an alkali metal carbonate or bicarbonate so that the atomic ratio of alkali metal to magnesium is in the range of 0.006 to 2.60. Preferred adsorbents are made from the precipitate formed on addition of alkali metal and carbonate ions to an aqueous solution of a magnesium salt. Atomic ratios of alkali metal to magnesium can be adjusted by washing the precipitate with water. Low surface area adsorbents can be made by dehydration and CO.sub.2 removal of magnesium hydroxycarbonate, with or without alkali metal promotion. The process is especially valuable in pressure swing adsorption operations.

  5. Diamond-silicon carbide composite

    DOE Patents [OSTI]

    Qian, Jiang; Zhao, Yusheng

    2006-06-13T23:59:59.000Z

    Fully dense, diamond-silicon carbide composites are prepared from ball-milled microcrystalline diamond/amorphous silicon powder mixture. The ball-milled powder is sintered (P=5–8 GPa, T=1400K–2300K) to form composites having high fracture toughness. A composite made at 5 GPa/1673K had a measured fracture toughness of 12 MPa.dot.m1/2. By contrast, liquid infiltration of silicon into diamond powder at 5 GPa/1673K produces a composite with higher hardness but lower fracture toughness. X-ray diffraction patterns and Raman spectra indicate that amorphous silicon is partially transformed into nanocrystalline silicon at 5 GPa/873K, and nanocrystalline silicon carbide forms at higher temperatures.

  6. Modified silicon carbide whiskers

    DOE Patents [OSTI]

    Tiegs, Terry N. (Lenoir City, TN); Lindemer, Terrence B. (Oak Ridge, TN)

    1991-01-01T23:59:59.000Z

    Silicon carbide whisker-reinforced ceramic composites are fabricated in a highly reproducible manner by beneficating the surfaces of the silicon carbide whiskers prior to their usage in the ceramic composites. The silicon carbide whiskers which contain considerable concentrations of surface oxides and other impurities which interact with the ceramic composite material to form a chemical bond are significantly reduced so that only a relatively weak chemical bond is formed between the whisker and the ceramic material. Thus, when the whiskers interact with a crack propagating into the composite the crack is diverted or deflected along the whisker-matrix interface due to the weak chemical bonding so as to deter the crack propagation through the composite. The depletion of the oxygen-containing compounds and other impurities on the whisker surfaces and near surface region is effected by heat treating the whiskers in a suitable oxygen sparaging atmosphere at elevated temperatures. Additionally, a sedimentation technique may be utilized to remove whiskers which suffer structural and physical anomalies which render them undesirable for use in the composite. Also, a layer of carbon may be provided on the surface of the whiskers to further inhibit chemical bonding of the whiskers to the ceramic composite material.

  7. Modified silicon carbide whiskers

    DOE Patents [OSTI]

    Tiegs, T.N.; Lindemer, T.B.

    1991-05-21T23:59:59.000Z

    Silicon carbide whisker-reinforced ceramic composites are fabricated in a highly reproducible manner by beneficating the surfaces of the silicon carbide whiskers prior to their usage in the ceramic composites. The silicon carbide whiskers which contain considerable concentrations of surface oxides and other impurities which interact with the ceramic composite material to form a chemical bond are significantly reduced so that only a relatively weak chemical bond is formed between the whisker and the ceramic material. Thus, when the whiskers interact with a crack propagating into the composite the crack is diverted or deflected along the whisker-matrix interface due to the weak chemical bonding so as to deter the crack propagation through the composite. The depletion of the oxygen-containing compounds and other impurities on the whisker surfaces and near surface region is effected by heat treating the whiskers in a suitable oxygen sparging atmosphere at elevated temperatures. Additionally, a sedimentation technique may be utilized to remove whiskers which suffer structural and physical anomalies which render them undesirable for use in the composite. Also, a layer of carbon may be provided on the surface of the whiskers to further inhibit chemical bonding of the whiskers to the ceramic composite material.

  8. Fabrication and properties of microporous silicon

    E-Print Network [OSTI]

    Shao, Jianzhong

    1994-01-01T23:59:59.000Z

    Microporous silicon layers were fabricated by electrochemical etching of single crystalline silicon wafers in HF-ethanol solutions. The pore properties of porous silicon were examined by physical adsorption of nitrogen and the relationship between...

  9. Fabrication and properties of microporous silicon 

    E-Print Network [OSTI]

    Shao, Jianzhong

    1994-01-01T23:59:59.000Z

    Microporous silicon layers were fabricated by electrochemical etching of single crystalline silicon wafers in HF-ethanol solutions. The pore properties of porous silicon were examined by physical adsorption of nitrogen and the relationship between...

  10. Vertical silicon nanowire arrays for gas sensing

    E-Print Network [OSTI]

    Zhao, Hangbo

    2014-01-01T23:59:59.000Z

    The goal of this research was to fabricate and characterize vertically aligned silicon nanowire gas sensors. Silicon nanowires are very attractive for gas sensing applications and vertically aligned silicon nanowires are ...

  11. Fabrication of porous silicon membranes

    E-Print Network [OSTI]

    Yue, Wing Kong

    1988-01-01T23:59:59.000Z

    efficiencies. The silicon difluoride, SiFq, is an unstable substance. It reacts with hydrofluoric acid forming silicic acid (HqSiFs) and hydrogen gas(Hq): SiFs + 2HF ? & SiF4+ Hs, (2) Si F4 + 2 H F ~ Hr Si Fs. In dilute HF solution, silicon can also react.... In step 1, the surface of silicon is covered with fluorine ions. In step 2, when an electric field is applied across the interface, holes move towards the surface. In step 3, some of the holes are trapped at the surface, and they weaken the silicon...

  12. aluminum equivalent approximation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - TxSpace Summary: based coatings. The Coors Brewing Company Can Manufacturing Plant has been utilizing this technology in full scale aluminum can production since 1975,...

  13. aluminum composites final: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Biological Systems: Implications for Neurological years, mining, smelting, and refining of aluminum (Al) in various forms have increasingly exposed living of the Al...

  14. aluminum calcium sodium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the pores Paris-Sud XI, Universit de 380 2009 SIMULIA Customer Conference 1 Aluminum Bottle Forming Simulation with Abaqus Engineering Websites Summary: 2009 SIMULIA Customer...

  15. aluminum alloy pressure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the pores Paris-Sud XI, Universit de 349 2009 SIMULIA Customer Conference 1 Aluminum Bottle Forming Simulation with Abaqus Engineering Websites Summary: 2009 SIMULIA Customer...

  16. Aluminum-stabilized Nb[sub 3]Sn superconductor

    DOE Patents [OSTI]

    Scanlan, R.M.

    1988-05-10T23:59:59.000Z

    Disclosed are an aluminum-stabilized Nb[sub 3]Sn superconductor and process for producing same, utilizing ultrapure aluminum. Ductile components are co-drawn with aluminum to produce a conductor suitable for winding magnets. After winding, the conductor is heated to convert it to the brittle Nb[sub 3]Sn superconductor phase, using a temperature high enough to perform the transformation but still below the melting point of the aluminum. This results in reaction of substantially all of the niobium, while providing stabilization and react-in-place features which are beneficial in the fabrication of magnets utilizing superconducting materials. 4 figs.

  17. Aluminum-stabilized Nb/sub 3/Sn superconductor

    DOE Patents [OSTI]

    Scanlan, R.M.

    1984-02-10T23:59:59.000Z

    This patent discloses an aluminum-stabilized Nb/sub 3/Sn superconductor and process for producing same, utilizing ultrapure aluminum. Ductile components are co-drawn with aluminum to produce a conductor suitable for winding magnets. After winding, the conductor is heated to convert it to the brittle Nb/sub 3/Sn superconductor phase, using a temperature high enough to perform the transformation but still below the melting point of the aluminum. This results in reaction of substantially all of the niobium, while providing stabilization and react-in-place features which are beneficial in the fabrication of magnets utilizing superconducting materials.

  18. aluminum microstructural features: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on aluminum. Fig: Prototype (direct machining- fluidic devices Metals can be used for tooling Mass and batch production of thermoplastic LOC devices Bone, Gary 9 Refinement of the...

  19. Joining of parts via magnetic heating of metal aluminum powders

    DOE Patents [OSTI]

    Baker, Ian

    2013-05-21T23:59:59.000Z

    A method of joining at least two parts includes steps of dispersing a joining material comprising a multi-phase magnetic metal-aluminum powder at an interface between the at least two parts to be joined and applying an alternating magnetic field (AMF). The AMF has a magnetic field strength and frequency suitable for inducing magnetic hysteresis losses in the metal-aluminum powder and is applied for a period that raises temperature of the metal-aluminum powder to an exothermic transformation temperature. At the exothermic transformation temperature, the metal-aluminum powder melts and resolidifies as a metal aluminide solid having a non-magnetic configuration.

  20. Fracture of welded aluminum thin-walled structures

    E-Print Network [OSTI]

    Zheng, Li, Ph. D. Massachusetts Institute of Technology

    2006-01-01T23:59:59.000Z

    A comprehensive methodology was developed in the thesis for damage prediction of welded aluminum thin-walled structures, which includes material modeling, calibration, numerical simulation and experimental verification. ...

  1. Aluminum nitrate recrystallization and recovery from liquid extraction raffinates

    SciTech Connect (OSTI)

    Griffith, W.L.; Compere, A.L.; Googin, J.M.; Huxtable, W.P.

    1991-09-01T23:59:59.000Z

    The solid sludges resulting form biodenitrification of discarded aluminum nitrate are the largest Y-12 Plant process solid waste. Aluminum nitrate feedstocks also represent a major plant materials cost. The chemical constraints on aluminum nitrate recycle were investigated to determine the feasibility of increasing recycle while maintaining acceptable aluminum nitrate purity. Reported phase behavior of analogous systems, together with bench research, indicated that it would be possible to raise the recycle rate from 35% to between 70 and 90% by successive concentration and recrystallization of the mother liquor. A full scale pilot test successfully confirmed the ability to obtain 70% recycle in existing process equipment.

  2. Microsoft PowerPoint - Aluminum Concentrations in Storm Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    It is never found free in nature and is found in most rocks, primarily in stable silicate mineral phases such as feldspars and phylosilicates. Aluminum enters environmental...

  3. Aluminum fluoride inhibition of glucocorticoid receptor inactivation and transformation

    SciTech Connect (OSTI)

    Housley, P.R. (Univ. of South Carolina School of Medicine, Columbia (USA))

    1990-04-10T23:59:59.000Z

    Fluoride, in the presence of aluminum ions, reversibly inhibits the temperature-mediated inactivation of unoccupied glucocorticoid receptors in cytosol preparations from mouse L cells. The effect is concentration-dependent, with virtually complete stabilization of specific glucocorticoid-binding capacity at 2 mM fluoride and 100 microM aluminum. These concentrations of aluminum and fluoride are ineffective when used separately. Aluminum fluoride also stabilizes receptors toward inactivation by gel filtration and ammonium sulfate precipitation. Aluminum fluoride prevents temperature-dependent transformation of steroid-receptor complexes to the DNA-binding state. Aluminum fluoride does not inhibit calf intestine alkaline phosphatase, and unoccupied receptors inactivated by this enzyme in the presence of aluminum fluoride can be completely reactivated by dithiothreitol. The effects of aluminum fluoride are due to stabilization of the complex between the glucocorticoid receptor and the 90-kDa mammalian heat-shock protein hsp90, which suggests that aluminum fluoride interacts directly with the receptor. Endogenous thermal inactivation of receptors in cytosol is not accompanied by receptor dephosphorylation. However, inactivation is correlated with dissociation of hsp90 from the unoccupied receptor. These results support the proposal that hsp90 is required for the receptor to bind steroid and dissociation of hsp90 is sufficient to inactivate the unoccupied receptor.

  4. aluminum oxide membrane: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aluminum oxide grown on the Fe at 850 C forms a homogeneous hexagonal oxide film with a thickness of approximately 10 ?. Core level 38 Development of novel...

  5. Climate VISION: Private Sector Initiatives: Aluminum: GHG Inventory...

    Office of Scientific and Technical Information (OSTI)

    Gas Protocol enhances and expands for the aluminum sector the World Business Council for Sustainable DevelopmentWorld Resources Institute greenhouse gas corporate accounting and...

  6. aluminum hydroxide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Repository Summary: Damping and Dynamic Modulus Measurements in Alumina and Tungsten Fibre-Reinforced Aluminium Composites. the damping capacity of aluminum tungsten fiber...

  7. aluminum weld strength: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Repository Summary: Damping and Dynamic Modulus Measurements in Alumina and Tungsten Fibre-Reinforced Aluminium Composites. the damping capacity of aluminum tungsten fiber...

  8. aluminum phthalocyanine tetrasulfonate: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Repository Summary: Damping and Dynamic Modulus Measurements in Alumina and Tungsten Fibre-Reinforced Aluminium Composites. the damping capacity of aluminum tungsten fiber...

  9. aluminum slag dross: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Repository Summary: Damping and Dynamic Modulus Measurements in Alumina and Tungsten Fibre-Reinforced Aluminium Composites. the damping capacity of aluminum tungsten fiber...

  10. aluminum buffing operation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Repository Summary: Damping and Dynamic Modulus Measurements in Alumina and Tungsten Fibre-Reinforced Aluminium Composites. the damping capacity of aluminum tungsten fiber...

  11. aluminum smelting plant: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Repository Summary: Damping and Dynamic Modulus Measurements in Alumina and Tungsten Fibre-Reinforced Aluminium Composites. the damping capacity of aluminum tungsten fiber...

  12. aluminum ingestion reduce: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Repository Summary: Damping and Dynamic Modulus Measurements in Alumina and Tungsten Fibre-Reinforced Aluminium Composites. the damping capacity of aluminum tungsten fiber...

  13. aluminum triiodide induced: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Repository Summary: Damping and Dynamic Modulus Measurements in Alumina and Tungsten Fibre-Reinforced Aluminium Composites. the damping capacity of aluminum tungsten fiber...

  14. aluminum vanadate ion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Repository Summary: Damping and Dynamic Modulus Measurements in Alumina and Tungsten Fibre-Reinforced Aluminium Composites. the damping capacity of aluminum tungsten fiber...

  15. aluminum alloy aa: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    For a wide Grujicic, Mica 2 Processing and Properties of Environmentally-Friendly Corrosion Resistant Hybrid Nanocomposite Coatings for Aluminum Alloy AA2024. Open Access...

  16. Single-electron shuttle based on a silicon quantum dot

    E-Print Network [OSTI]

    K. W. Chan; M. Mottonen; A. Kemppinen; N. S. Lai; K. Y. Tan; W. H. Lim; A. S. Dzurak

    2011-10-05T23:59:59.000Z

    We report on single-electron shuttling experiments with a silicon metal-oxide-semiconductor quantum dot at 300 mK. Our system consists of an accumulated electron layer at the Si/SiO_2 interface below an aluminum top gate with two additional barrier gates used to deplete the electron gas locally and to define a quantum dot. Directional single-electron shuttling from the source and to the drain lead is achieved by applying a dc source-drain bias while driving the barrier gates with an ac voltage of frequency f_p. Current plateaus at integer levels of ef_p are observed up to f_p = 240 MHz operation frequencies. The observed results are explained by a sequential tunneling model which suggests that the electron gas may be heated substantially by the ac driving voltage.

  17. Silicon on insulator with active buried regions

    DOE Patents [OSTI]

    McCarthy, Anthony M. (Menlo Park, CA)

    1998-06-02T23:59:59.000Z

    A method for forming patterned buried components, such as collectors, sources and drains, in silicon-on-insulator (SOI) devices. The method is carried out by epitaxially growing a suitable sequence of single or multiple etch stop layers ending with a thin silicon layer on a silicon substrate, masking the silicon such that the desired pattern is exposed, introducing dopant and activating in the thin silicon layer to form doped regions. Then, bonding the silicon layer to an insulator substrate, and removing the silicon substrate. The method additionally involves forming electrical contact regions in the thin silicon layer for the buried collectors.

  18. Silicon on insulator with active buried regions

    DOE Patents [OSTI]

    McCarthy, A.M.

    1996-01-30T23:59:59.000Z

    A method is disclosed for forming patterned buried components, such as collectors, sources and drains, in silicon-on-insulator (SOI) devices. The method is carried out by epitaxially growing a suitable sequence of single or multiple etch stop layers ending with a thin silicon layer on a silicon substrate, masking the silicon such that the desired pattern is exposed, introducing dopant and activating in the thin silicon layer to form doped regions. Then, bonding the silicon layer to an insulator substrate, and removing the silicon substrate. The method additionally involves forming electrical contact regions in the thin silicon layer for the buried collectors. 10 figs.

  19. Silicon on insulator with active buried regions

    DOE Patents [OSTI]

    McCarthy, Anthony M. (Menlo Park, CA)

    1996-01-01T23:59:59.000Z

    A method for forming patterned buried components, such as collectors, sources and drains, in silicon-on-insulator (SOI) devices. The method is carried out by epitaxially growing a suitable sequence of single or multiple etch stop layers ending with a thin silicon layer on a silicon substrate, masking the silicon such that the desired pattern is exposed, introducing dopant and activating in the thin silicon layer to form doped regions. Then, bonding the silicon layer to an insulator substrate, and removing the silicon substrate. The method additionally involves forming electrical contact regions in the thin silicon layer for the buried collectors.

  20. Silicon on insulator with active buried regions

    DOE Patents [OSTI]

    McCarthy, A.M.

    1998-06-02T23:59:59.000Z

    A method is disclosed for forming patterned buried components, such as collectors, sources and drains, in silicon-on-insulator (SOI) devices. The method is carried out by epitaxially growing a suitable sequence of single or multiple etch stop layers ending with a thin silicon layer on a silicon substrate, masking the silicon such that the desired pattern is exposed, introducing dopant and activating in the thin silicon layer to form doped regions. Then, bonding the silicon layer to an insulator substrate, and removing the silicon substrate. The method additionally involves forming electrical contact regions in the thin silicon layer for the buried collectors. 10 figs.

  1. Nanoscale Engineering Of Radiation Tolerant Silicon Carbide....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering Of Radiation Tolerant Silicon Carbide. Nanoscale Engineering Of Radiation Tolerant Silicon Carbide. Abstract: Radiation tolerance is determined by how effectively the...

  2. Ab Initio Study of the Interaction of Water with Cluster Models of the Aluminum Terminated (0001) r-Aluminum Oxide Surface

    E-Print Network [OSTI]

    Schlegel, H. Bernhard

    Ab Initio Study of the Interaction of Water with Cluster Models of the Aluminum Terminated (0001) r-Aluminum to hydroxylation of the aluminum terminated surface, the two water process was found to be the most exothermic, occurring within 10-2 s. I. Introduction As one of the most important ceramic materials, R-aluminum oxide

  3. aluminum alloy 6061-t6: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    resolution study of the impact of an aluminum sphere on an aluminum plate supported by a hollow aluminum cylinder. In a previous report, an optimal set of input parameters The...

  4. loading dir (MPa) Grain Boundary Decohesion and Particle-Matrix Debonding in Aluminum

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    loading dir (MPa) Grain Boundary Decohesion and Particle-Matrix Debonding in Aluminum Alloy 7075-T - matrix debonding occur in some aluminum alloys. · To model accurately MSFC behavior in aluminum

  5. Low-Cycle Fatigue of Ultra-Fine-Grained Cryomilled 5083 Aluminum Alloy

    E-Print Network [OSTI]

    Walley, J. L.; Lavernia, E. J.; Gibeling, J. C.

    2009-01-01T23:59:59.000Z

    an Ultra-Fine Grained Aluminum Alloy, Poster Session, TMS,with other MA aluminum alloys and is attributed to theGrained Cryomilled 5083 Aluminum Alloy J.L. WALLEY, E.J.

  6. Economic and environmental evaluation of end-of-life aerospace aluminum options using optimization methods

    E-Print Network [OSTI]

    Chen, Emily, S.B. Massachusetts Institute of Technology

    2008-01-01T23:59:59.000Z

    The benefits of recycling have long been understood and the conspicuous energy savings of secondary aluminum production have caused aluminum recycling to increase. Obsolete aircraft are a valuable source of aluminum scrap ...

  7. Fabrication and applications of nanocomposite structures using anodized aluminum oxide membranes

    E-Print Network [OSTI]

    Gapin, Andrew Isaac

    2007-01-01T23:59:59.000Z

    Hall, Process of Reducing Aluminum from its Fluoride SaltsFrary and Z. Jeffries, Aluminum and its Production, McGraw-1 (1948). J. E. Hatch, Aluminum Properties and Physical

  8. Long-term and Highly Aluminum-resistant Root Elongation in a Camphor Tree Cinnamomum camphora

    E-Print Network [OSTI]

    Osawa, Hiroki

    2009-01-01T23:59:59.000Z

    for the detoxification of aluminum in roots of tea plant (Oda A, Yamamoto F, Effects of aluminum on growth and biomassT, Beneficial effect of aluminum on growth of plants adapted

  9. Low-Cycle Fatigue of Ultra-Fine-Grained Cryomilled 5083 Aluminum Alloy

    E-Print Network [OSTI]

    Walley, J. L.; Lavernia, E. J.; Gibeling, J. C.

    2009-01-01T23:59:59.000Z

    of an Ultra-Fine Grained Aluminum Alloy, Poster Session,Grained Cryomilled 5083 Aluminum Alloy J.L. WALLEY, E.J.consistent with other MA aluminum alloys and is attributed

  10. Control of residual aluminum from conventional treatment to improve reverse osmosis performance

    E-Print Network [OSTI]

    Gabelich, C J; Ishida, K P; Gerringer, F W; Evangelista, R; Kalyan, M; Suffet, I H

    2006-01-01T23:59:59.000Z

    2005. The Role of Dissolved Aluminum in Silica Chemistry forDraft Public Health Goal for Aluminum in Drinking Water .1994. Control of Residual Aluminum in Filtered Water . AWWA,

  11. Report on Energy Deposition Calculations on the Magnesium Diboride Superconducting Links for the Cold Powering System Deliverable: D6.6

    E-Print Network [OSTI]

    Bignami, A; Santini, C

    2015-01-01T23:59:59.000Z

    Report on Energy Deposition Calculations on the Magnesium Diboride Superconducting Links for the Cold Powering System

  12. Geochemistry of Aluminum in High Temperature Brines

    SciTech Connect (OSTI)

    Benezeth, P.; Palmer, D.A.; Wesolowski, D.J.

    1999-05-18T23:59:59.000Z

    The objective ofthis research is to provide quantitative data on the equilibrium and thermodynamic properties of aluminum minerals required to model changes in permeability and brine chemistry associated with fluid/rock interactions in the recharge, reservoir, and discharge zones of active geothermal systems. This requires a precise knowledge of the thermodynamics and speciation of aluminum in aqueous brines, spanning the temperature and fluid composition rangesencountered in active systems. The empirical and semi-empirical treatments of the solubility/hydrolysis experimental results on single aluminum mineral phases form the basis for the ultimate investigation of the behavior of complex aluminosilicate minerals. The principal objective in FY 1998 was to complete the solubility measurements on boehmite (AIOOH) inNaC1 media( 1 .O and 5.0 molal ionic strength, IOO-250°C). However, additional measurements were also made on boehmite solubility in pure NaOH solutions in order to bolster the database for fitting in-house isopiestic data on this system. Preliminary kinetic Measurements of the dissolution/precipitation of boehmite was also carried out, although these were also not planned in the earlier objective. The 1999 objectives are to incorporate these treatments into existing codes used by the geothermal industry to predict the chemistry ofthe reservoirs; these calculations will be tested for reliability against our laboratory results and field observations. Moreover, based on the success of the experimental methods developed in this program, we intend to use our unique high temperature pH easurement capabilities to make kinetic and equilibrium studies of pH-dependent aluminosilicate transformation reactions and other pH-dependent heterogeneous reactions.

  13. Fast electromigration crack in nanoscale aluminum film

    SciTech Connect (OSTI)

    Emelyanov, O. A., E-mail: oaemel2@gmail.com; Ivanov, I. O. [St. Petersburg State Polytechnical University, Saint-Petersburg (Russian Federation)

    2014-08-14T23:59:59.000Z

    The current-induced breakage of 20?nm thin aluminum layers deposited onto capacitor grade polypropylene (PP) films is experimentally studied. Biexponential current pulses of different amplitude (10–15?A) and duration (0.1–1??s) were applied to the samples. Breakage occurred after fast development of electromigrating ?200?nm-wide cracks with initial propagation velocity of ?1?m/s under a high current density of ?10{sup 12?}A/m{sup 2}. The cracks stopped when their lengths reached 250–450??m. This behavior is explained by the balance of electromigration and stress-induced atomic fluxes.

  14. Process simulation of aluminum reduction cells

    SciTech Connect (OSTI)

    Tabsh, I. [CompuSIM Inc., Calgary, Alberta (Canada); Dupuis, M. [GeniSim, Jonquiere, Quebec (Canada); Gomes, A. [Alcan Aluminio do Brasil S.A., Salvador, Bahia (Brazil)

    1996-10-01T23:59:59.000Z

    A program was developed to model the dynamic behavior of an aluminum reduction cell. The program simulates the physical process by solving the heat and mass balance equations that characterize the behavior of eleven chemical species in the system. It also models operational events (such as metal tapping, anode change, etc.) and the process control logic including various alumina feeding policies and anode effect quenching. The program is a PC based Windows{reg_sign} application that takes full advantage of the Windows user interface. This paper describes the implementation of the process model and the control logic. Various results using the simulation are compared to measured data.

  15. Projectile enery dependence of aluminum and silicon K ga sx-ray satellites

    E-Print Network [OSTI]

    Sonobe, Blake Isamu

    1978-01-01T23:59:59.000Z

    and by electrons. In the late 13 1920's, Gerthsen performed experiments using protons and alpha 14 particles to study the production of inner-shell vacancies. Coates, in 1934, found x-rays resulting from heavy ion bombardment to be characteristic of the atoms... to 3 Mev) 16 on thick tantalum targets. Huus and Zupancic also observed large amounts of characteristic x-rays while studying gamma rays from proton bombardment. Energetic charged particles from accelerators have since been frequently used...

  16. A NEW A15 MULTIFILAMENTARY SUPERCONDUCTOR BASED ON THE NIOBIUM-ALUMINUM-SILICON SYSTEM

    E-Print Network [OSTI]

    Quinn, G.C.

    2011-01-01T23:59:59.000Z

    the Inter­ national Powder Metallurgy Conference, June 1976,ABSTRACT Based on Powder Metallurgy techniques, a process toIn contrast, the power metallurgy infiltration process

  17. MICROSTRUCTURE AND MECHANICAL PROPERTIES OF AISI 4340 STEEL MODIFIED WITH ALUMINUM AND SILICON

    E-Print Network [OSTI]

    Bhat, M.S.

    2010-01-01T23:59:59.000Z

    1968), G, Thomas. Iron and Steel Int, 46. 451 (1973), G,Containing High-Strength Steels, Cobalt Monograph Series, A.Strength Structural j Steels," ASTM Spec, Tech, PubL 498,

  18. Amorphous silicon ionizing particle detectors

    DOE Patents [OSTI]

    Street, R.A.; Mendez, V.P.; Kaplan, S.N.

    1988-11-15T23:59:59.000Z

    Amorphous silicon ionizing particle detectors having a hydrogenated amorphous silicon (a--Si:H) thin film deposited via plasma assisted chemical vapor deposition techniques are utilized to detect the presence, position and counting of high energy ionizing particles, such as electrons, x-rays, alpha particles, beta particles and gamma radiation. 15 figs.

  19. Amorphous silicon ionizing particle detectors

    DOE Patents [OSTI]

    Street, Robert A. (Palo Alto, CA); Mendez, Victor P. (Berkeley, CA); Kaplan, Selig N. (El Cerrito, CA)

    1988-01-01T23:59:59.000Z

    Amorphous silicon ionizing particle detectors having a hydrogenated amorphous silicon (a--Si:H) thin film deposited via plasma assisted chemical vapor deposition techniques are utilized to detect the presence, position and counting of high energy ionizing particles, such as electrons, x-rays, alpha particles, beta particles and gamma radiation.

  20. Method of forming aluminum oxynitride material and bodies formed by such methods

    DOE Patents [OSTI]

    Bakas, Michael P. (Ammon, ID) [Ammon, ID; Lillo, Thomas M. (Idaho Falls, ID) [Idaho Falls, ID; Chu, Henry S. (Idaho Falls, ID) [Idaho Falls, ID

    2010-11-16T23:59:59.000Z

    Methods of forming aluminum oxynitride (AlON) materials include sintering green bodies comprising aluminum orthophosphate or another sacrificial material therein. Such green bodies may comprise aluminum, oxygen, and nitrogen in addition to the aluminum orthophosphate. For example, the green bodies may include a mixture of aluminum oxide, aluminum nitride, and aluminum orthophosphate or another sacrificial material. Additional methods of forming aluminum oxynitride (AlON) materials include sintering a green body including a sacrificial material therein, using the sacrificial material to form pores in the green body during sintering, and infiltrating the pores formed in the green body with a liquid infiltrant during sintering. Bodies are formed using such methods.

  1. MATHEMATICAL MODELING OF THE LITHIUM-ALUMINUM, IRON SULFIDE BATTERY. I. GALVONOSTATIC DISCHARGE BEHAVIOR

    E-Print Network [OSTI]

    Pollard, Richard

    2012-01-01T23:59:59.000Z

    composition profiles in lithium/sulfur battery analogues hasTHE LITHIUM-ALUMINUM, IRON SULFIDE BATTERY. I. GALVONOSTATICthe Lithium-Aluminum, Iron Sulfide Battery I. Galvanostatic

  2. Ultraviolet selective silicon photodiode

    E-Print Network [OSTI]

    Chintapalli, Koteswara Rao

    1992-01-01T23:59:59.000Z

    (' silicon surfa&(& that n&ost of t h&) phologeneraied hole-el( & tron pairs are k&st by surface rccornbinai ion before being nolle&. trxl hy a pr). jun?i, ion. The major cause of surl'a&. e re?omhination is probably due Io lifetim(. shortening ol' Lhe... drpth corresponded to a high& r shor4wav? length rcsponsiv- ity tlirough liis ( xperimcnial diodes with junction dcpl ha ol'0. -'I to 2 0 pm. I indmayer and Allison [4I] I'abri&. ated n+-p solar cells with junction &lcpths of approximately 0. 1, 0. 15...

  3. Icosahedral phase formation in rapidly quenched aluminum-ruthenium alloys

    E-Print Network [OSTI]

    Anlage, Steven

    Icosahedral phase formation in rapidly quenched aluminum- ruthenium alloys Steven M. Anlagea phases as a function of composition. We have chosen the aluminum-ruthenium alloy system because. %. The solidified alloys have been studied by electron microscopy and x-ray diffraction to determine

  4. Characteristics of Aluminum Biosorption by Sargassum fluitans Biomass

    E-Print Network [OSTI]

    Volesky, Bohumil

    Characteristics of Aluminum Biosorption by Sargassum fluitans Biomass Hak Sung Lee1, * and Bohumil3A 2B2, Canada Abstract: Biomass of nonliving brown seaweed Sargassum fluitans pretreated.5. There are indications that the biomass hydroxyl groups were involved in sequestering the aluminum in the form

  5. BWeb Copy of the Aluminum Chapter from the 1st

    E-Print Network [OSTI]

    Ford, Andrew

    industry. It then exploits the power of arrays to develop a model which distinguishes between smelters for smelting aluminum on a commercial basis (Smith 1988, p. 17). In today's industry, a large smelter might produce around 0.2 million metric tons (mmt) of aluminum each year. The smelter would be located close

  6. ALUMINUM--2001 6.1 By Patricia A. Plunkert

    E-Print Network [OSTI]

    in the Pacific Northwest, and low metal prices led several aluminum smelters to continue to reduce production consumption in 2001. The recycling rate for aluminum UBCs decreased to 55.4%, compared with 62.1% in 2000 prices led smelters in the Pacific Northwest to continue the cutbacks in production that were begun last

  7. Electrolytic production of high purity aluminum using ceramic inert anodes

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Douglas A. (Murrysville, PA); DiMilia, Robert A. (Baton Rouge, LA); Dynys, Joseph M. (New Kensington, PA); Phelps, Frankie E. (Apollo, PA); LaCamera, Alfred F. (Trafford, PA)

    2002-01-01T23:59:59.000Z

    A method of producing commercial purity aluminum in an electrolytic reduction cell comprising ceramic inert anodes is disclosed. The method produces aluminum having acceptable levels of Fe, Cu and Ni impurities. The ceramic inert anodes used in the process may comprise oxides containing Fe and Ni, as well as other oxides, metals and/or dopants.

  8. Aluminum sulfate (alum; Al2 O) is used as a

    E-Print Network [OSTI]

    Sparks, Donald L.

    477 Aluminum sulfate (alum; Al2 (SO4 )3 ·14H2 O) is used as a chemical treatment of poultry litter, and pelletizing, the use of chemical amendments, primarily aluminum sulfate (alum, Al2 (SO4 )3 ·14H2 O), alter

  9. Molecular Scale Assessment of Methylarsenic Sorption on Aluminum

    E-Print Network [OSTI]

    Sparks, Donald L.

    Molecular Scale Assessment of Methylarsenic Sorption on Aluminum Oxide M A S A Y U K I S H I M I Z than AsV or AsIII , their reduction can produce very toxic MMAIII or DMAIII . Aluminum oxides

  10. Electrolytic production of high purity aluminum using inert anodes

    DOE Patents [OSTI]

    Ray, Siba P. (Murrysville, PA); Liu, Xinghua (Monroeville, PA); Weirauch, Jr., Douglas A. (Murrysville, PA)

    2001-01-01T23:59:59.000Z

    A method of producing commercial purity aluminum in an electrolytic reduction cell comprising inert anodes is disclosed. The method produces aluminum having acceptable levels of Fe, Cu and Ni impurities. The inert anodes used in the process preferably comprise a cermet material comprising ceramic oxide phase portions and metal phase portions.

  11. Honeywell Modular Automation System Computer Software Documentation for the Magnesium Hydroxide Precipitation Process

    SciTech Connect (OSTI)

    STUBBS, A.M.

    2001-06-25T23:59:59.000Z

    The purpose of this Computer Software Document (CSWD) is to provide configuration control of the Honeywell Modular Automation System (MAS) in use at the Plutonium Finishing Plant (PFP) for the Magnesium Hydroxide Precipitation Process in Rm 230C/234-5Z. The magnesium hydroxide process control software Rev 0 is being updated to include control programming for a second hot plate. The process control programming was performed by the system administrator. Software testing for the additional hot plate was performed per PFP Job Control Work Package 2Z-00-1703. The software testing was verified by Quality Control to comply with OSD-Z-184-00044, Magnesium Hydroxide Precipitation Process.

  12. Effects of dietary potassium and sodium on magnesium and potassium balance in lambs 

    E-Print Network [OSTI]

    Poe, Julie Hamilton

    1984-01-01T23:59:59.000Z

    of magnesium oxide and trace mineralized salt with either molasses, cottonseed meal, dry sugarcane or steamed bone meal was consumed by lactating beef cows at a significantly (P), 05) higher level than magnesium oxide and trace mineralized salt (1:1) alone...EFFECTS OF DIETARY POTASSIUM AND SODIUM ON MAGNESIUM AND POTASSIUM BALANCE IN LAMBS A Thesis by JULIE HAMILTON POE Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

  13. A silicon photomultiplier readout for time of flight neutron spectroscopy with {gamma}-ray detectors

    SciTech Connect (OSTI)

    Pietropaolo, A.; Gorini, G. [Dipartimento di Fisica ''G. Occhialini'' and CNISM, Universita Degli Studi di Milano-Bicocca, Piazza della Scienza 3, 20126 Milano (Italy); Festa, G.; Andreani, C.; De Pascale, M. P.; Reali, E. [Dipartimento di Fisica and Centro NAST, Universita degli Studi di Roma Tor Vergata, Via della Ricerca Scientifica 1, 00133, Roma (Italy); Grazzi, F. [Istituto dei Sistemi Complessi-Consiglio Nazionale delle Ricerche, Via Madonna del Piano n.10, I-50019 Sesto Fiorentino, Firenze (Italy); Schooneveld, E. M. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom)

    2009-09-15T23:59:59.000Z

    The silicon photomultiplier (SiPM) is a recently developed photosensor used in particle physics, e.g., for detection of minimum ionizing particles and/or Cherenkov radiation. Its performance is comparable to that of photomultiplier tubes, but with advantages in terms of reduced volume and magnetic field insensitivity. In the present study, the performance of a gamma ray detector made of an yttrium aluminum perovskite scintillation crystal and a SiPM-based readout is assessed for use in time of flight neutron spectroscopy. Measurements performed at the ISIS pulsed neutron source demonstrate the feasibility of {gamma}-detection based on the new device.

  14. Corrosion behavior of aluminum-lithium alloys

    SciTech Connect (OSTI)

    Garrard, W.N. (Defence Science and Technology Organization, Victoria (Australia))

    1994-03-01T23:59:59.000Z

    Corrosion behavior of three aluminum-lithium (Al-Li) alloys was investigated in aerated 0.5 M sodium sulfate (Na[sub 2]SO[sub 4]), deaerated 3.5% sodium chloride (NaCl), and aerated 3.5% NaCl. Corrosion behavior of the Aluminum Association (AA) alloys 2090-T8E41 (UNS A92090, sheet), AA 8090-T851 (UNS A98090, sheet), and AA 8090-T82551 (UNS A98090, bar) was compared to behavior of the conventional AA 7075-T6 (UNS A97075, sheet). Uniform corrosion was the predominant form of attack in aerated Na[sub 2]SO[sub 4] and deaerated NaCl, although some localized attack resulted from corrosion of intermetallics on specimen surfaces. Pitting was the main form of attack in aerated NaCl. In all three media, the sheet materials corroded at a similar rate, but the bar form of AA 8090 corroded at a lower rate. Pretreatment of the alloys by immersion in a cerium (Ce) solution inhibited pitting in aerated NaCl but only for a short period.

  15. Superconducting structure with layers of niobium nitride and aluminum nitride

    DOE Patents [OSTI]

    Murduck, James M. (Lisle, IL); Lepetre, Yves J. (Lauris, FR); Schuller, Ivan K. (Woodridge, IL); Ketterson, John B. (Evanston, IL)

    1989-01-01T23:59:59.000Z

    A superconducting structure is formed by depositing alternate layers of aluminum nitride and niobium nitride on a substrate. Deposition methods include dc magnetron reactive sputtering, rf magnetron reactive sputtering, thin-film diffusion, chemical vapor deposition, and ion-beam deposition. Structures have been built with layers of niobium nitride and aluminum nitride having thicknesses in a range of 20 to 350 Angstroms. Best results have been achieved with films of niobium nitride deposited to a thickness of approximately 70 Angstroms and aluminum nitride deposited to a thickness of approximately 20 Angstroms. Such films of niobium nitride separated by a single layer of aluminum nitride are useful in forming Josephson junctions. Structures of 30 or more alternating layers of niobium nitride and aluminum nitride are useful when deposited on fixed substrates or flexible strips to form bulk superconductors for carrying electric current. They are also adaptable as voltage-controlled microwave energy sources.

  16. Superconducting structure with layers of niobium nitride and aluminum nitride

    DOE Patents [OSTI]

    Murduck, J.M.; Lepetre, Y.J.; Schuller, I.K.; Ketterson, J.B.

    1989-07-04T23:59:59.000Z

    A superconducting structure is formed by depositing alternate layers of aluminum nitride and niobium nitride on a substrate. Deposition methods include dc magnetron reactive sputtering, rf magnetron reactive sputtering, thin-film diffusion, chemical vapor deposition, and ion-beam deposition. Structures have been built with layers of niobium nitride and aluminum nitride having thicknesses in a range of 20 to 350 Angstroms. Best results have been achieved with films of niobium nitride deposited to a thickness of approximately 70 Angstroms and aluminum nitride deposited to a thickness of approximately 20 Angstroms. Such films of niobium nitride separated by a single layer of aluminum nitride are useful in forming Josephson junctions. Structures of 30 or more alternating layers of niobium nitride and aluminum nitride are useful when deposited on fixed substrates or flexible strips to form bulk superconductors for carrying electric current. They are also adaptable as voltage-controlled microwave energy sources. 8 figs.

  17. Amorphous silicon/crystalline silicon heterojunctions: The future of high-efficiency silicon solar cells

    E-Print Network [OSTI]

    Firestone, Jeremy

    ;5 Record efficiencies #12;6 Diffused-junction solar cells Diffused-junction solar cell Chemical passivation to ~650 mV #12;7 Silicon heterojunction solar cells a-Si:H provides excellent passivation of c-Si surface Heterojunction solar cell Chemical passivation Chemical passivation #12;8 Voc and silicon heterojunction solar

  18. Silicon-doped boron nitride coated fibers in silicon melt infiltrated composites

    DOE Patents [OSTI]

    Corman, Gregory Scot (Ballston Lake, NY); Luthra, Krishan Lal (Schenectady, NY)

    1999-01-01T23:59:59.000Z

    A fiber-reinforced silicon--silicon carbide matrix composite having improved oxidation resistance at high temperatures in dry or water-containing environments is produced. The invention also provides a method for protecting the reinforcing fibers in the silicon--silicon carbide matrix composites by coating the fibers with a silicon-doped boron nitride coating.

  19. Silicon-doped boron nitride coated fibers in silicon melt infiltrated composites

    DOE Patents [OSTI]

    Corman, Gregory Scot (Ballston Lake, NY); Luthra, Krishan Lal (Schenectady, NY)

    2002-01-01T23:59:59.000Z

    A fiber-reinforced silicon-silicon carbide matrix composite having improved oxidation resistance at high temperatures in dry or water-containing environments is produced. The invention also provides a method for protecting the reinforcing fibers in the silicon-silicon carbide matrix composites by coating the fibers with a silicon-doped boron nitride coating.

  20. Silicon nitride/silicon carbide composite densified materials prepared using composite powders

    DOE Patents [OSTI]

    Dunmead, S.D.; Weimer, A.W.; Carroll, D.F.; Eisman, G.A.; Cochran, G.A.; Susnitzky, D.W.; Beaman, D.R.; Nilsen, K.J.

    1997-07-01T23:59:59.000Z

    Prepare silicon nitride-silicon carbide composite powders by carbothermal reduction of crystalline silica powder, carbon powder and, optionally, crystalline silicon nitride powder. The crystalline silicon carbide portion of the composite powders has a mean number diameter less than about 700 nanometers and contains nitrogen. The composite powders may be used to prepare sintered ceramic bodies and self-reinforced silicon nitride ceramic bodies.

  1. The magnesium nutrition of cotton as influenced by sodium

    E-Print Network [OSTI]

    Thenabadu, Mervyn Wellesly

    1964-01-01T23:59:59.000Z

    -oa:, cld c:t. r. p alit ir a. clans as inrluenced ty siagnesium ard s jiL I . -'?'g"rs f:ct:o" pi ants at weekls lr ti rvdls as it' flL1 reed oy Htdg;1. S1L'm dl. d s 'dium R eld ls. ? chlcr opr yl contet t 1;. inrlu?. . ced ty magnesium ard sc... 1 . au=? as ol m R La=. te carctencio cnt?nt c:r ir. flu reed by maga siu?m arid sc edt. S o LU'm 615 . be distr ibu" c rr c f day - Ld ccttcr pl Cd 10rs li. l;':LSS? Ci 30 at' s distr ibu7 ic. . cf 6G-day olo cct cn radgr. esrum ar. d...

  2. Silicon nitride ceramic comprising samaria and ytterbia

    DOE Patents [OSTI]

    Yeckley, Russell L. (Oakham, MA)

    1996-01-01T23:59:59.000Z

    This invention relates to a sintered silicon nitride ceramic comprising samaria and ytterbia for enhanced toughness.

  3. Amorphous Silicon-Carbon Nanostructure Photovoltaic Devices

    E-Print Network [OSTI]

    Schriver, Maria Christine

    2012-01-01T23:59:59.000Z

    and Photovoltaic Performance . . . . . . . . . . . . . . .Amorphous Silicon as a Photovoltaic Material 2.1.2ii Photovoltaic Model . . . . . . . . . . .

  4. Amorphous silicon enhanced metal-insulator-semiconductor contacts for silicon solar cells

    SciTech Connect (OSTI)

    Bullock, J., E-mail: james.bullock@anu.edu.au; Cuevas, A.; Yan, D. [Research School of Engineering, The Australian National University, Canberra, ACT 0200 (Australia); Demaurex, B.; Hessler-Wyser, A.; De Wolf, S. [Ecole Polytechnique Fédérale de Lausanne (EPFL), Institute of Micro Engineering (IMT), Photovoltaics and Thin Film Electronic Laboratory PVLab, Maladière 71b, CH-200 Neuchâtel (Switzerland)

    2014-10-28T23:59:59.000Z

    Carrier recombination at the metal-semiconductor contacts has become a significant obstacle to the further advancement of high-efficiency diffused-junction silicon solar cells. This paper provides the proof-of-concept of a procedure to reduce contact recombination by means of enhanced metal-insulator-semiconductor (MIS) structures. Lightly diffused n{sup +} and p{sup +} surfaces are passivated with SiO{sub 2}/a-Si:H and Al{sub 2}O{sub 3}/a-Si:H stacks, respectively, before the MIS contacts are formed by a thermally activated alloying process between the a-Si:H layer and an overlying aluminum film. Transmission/scanning transmission electron microscopy (TEM/STEM) and energy dispersive x-ray spectroscopy are used to ascertain the nature of the alloy. Idealized solar cell simulations reveal that MIS(n{sup +}) contacts, with SiO{sub 2} thicknesses of ?1.55?nm, achieve the best carrier-selectivity producing a contact resistivity ?{sub c} of ?3 m? cm{sup 2} and a recombination current density J{sub 0c} of ?40 fA/cm{sup 2}. These characteristics are shown to be stable at temperatures up to 350?°C. The MIS(p{sup +}) contacts fail to achieve equivalent results both in terms of thermal stability and contact characteristics but may still offer advantages over directly metallized contacts in terms of manufacturing simplicity.

  5. Process for forming retrograde profiles in silicon

    DOE Patents [OSTI]

    Weiner, K.H.; Sigmon, T.W.

    1996-10-15T23:59:59.000Z

    A process is disclosed for forming retrograde and oscillatory profiles in crystalline and polycrystalline silicon. The process consisting of introducing an n- or p-type dopant into the silicon, or using prior doped silicon, then exposing the silicon to multiple pulses of a high-intensity laser or other appropriate energy source that melts the silicon for short time duration. Depending on the number of laser pulses directed at the silicon, retrograde profiles with peak/surface dopant concentrations which vary are produced. The laser treatment can be performed in air or in vacuum, with the silicon at room temperature or heated to a selected temperature.

  6. Process for forming retrograde profiles in silicon

    DOE Patents [OSTI]

    Weiner, Kurt H. (San Jose, CA); Sigmon, Thomas W. (Phoenix, AZ)

    1996-01-01T23:59:59.000Z

    A process for forming retrograde and oscillatory profiles in crystalline and polycrystalline silicon. The process consisting of introducing an n- or p-type dopant into the silicon, or using prior doped silicon, then exposing the silicon to multiple pulses of a high-intensity laser or other appropriate energy source that melts the silicon for short time duration. Depending on the number of laser pulses directed at the silicon, retrograde profiles with peak/surface dopant concentrations which vary from 1-1e4 are produced. The laser treatment can be performed in air or in vacuum, with the silicon at room temperature or heated to a selected temperature.

  7. Silicon Oxynitride Thin Film Barriers for PV Packaging (Poster)

    SciTech Connect (OSTI)

    del Cueto, J. A.; Glick, S. H.; Terwilliger, K. M.; Jorgensen, G. J.; Pankow, J. W.; Keyes, B. M.; Gedvilas, L. M.; Pern, F. J.

    2006-10-03T23:59:59.000Z

    Dielectric, adhesion-promoting, moisture barriers comprised of silicon oxynitride thin film materials (SiOxNy with various material stoichiometric compositions x,y) were applied to: 1) bare and pre-coated soda-lime silicate glass (coated with transparent conductive oxide SnO2:F and/or aluminum), and polymer substrates (polyethylene terephthalate, PET, or polyethylene napthalate, PEN); plus 2) pre- deposited photovoltaic (PV) cells and mini-modules consisting of amorphous silicon (a-Si) and copper indium gallium diselenide (CIGS) thin-film PV technologies. We used plasma enhanced chemical vapor deposition (PECVD) process with dilute silane, nitrogen, and nitrous oxide/oxygen gas mixtures in a low-power (< or = 10 milliW per cm2) RF discharge at ~ 0.2 Torr pressure, and low substrate temperatures < or = 100(degrees)C, over deposition areas ~ 1000 cm2. Barrier properties of the resulting PV cells and coated-glass packaging structures were studied with subsequent stressing in damp-heat exposure at 85(degrees)C/85% RH. Preliminary results on PV cells and coated glass indicate the palpable benefits of the barriers in mitigating moisture intrusion and degradation of the underlying structures using SiOxNy coatings with thicknesses in the range of 100-200 nm.

  8. High specific activity silicon-32

    DOE Patents [OSTI]

    Phillips, D.R.; Brzezinski, M.A.

    1996-06-11T23:59:59.000Z

    A process for preparation of silicon-32 is provided and includes contacting an irradiated potassium chloride target, including spallation products from a prior irradiation, with sufficient water, hydrochloric acid or potassium hydroxide to form a solution, filtering the solution, adjusting pH of the solution from about 5.5 to about 7.5, admixing sufficient molybdate-reagent to the solution to adjust the pH of the solution to about 1.5 and to form a silicon-molybdate complex, contacting the solution including the silicon-molybdate complex with a dextran-based material, washing the dextran-based material to remove residual contaminants such as sodium-22, separating the silicon-molybdate complex from the dextran-based material as another solution, adding sufficient hydrochloric acid and hydrogen peroxide to the solution to prevent reformation of the silicon-molybdate complex and to yield an oxidation state of the molybdate adapted for subsequent separation by an anion exchange material, contacting the solution with an anion exchange material whereby the molybdate is retained by the anion exchange material and the silicon remains in solution, and optionally adding sufficient alkali metal hydroxide to adjust the pH of the solution to about 12 to 13. Additionally, a high specific activity silicon-32 product having a high purity is provided.

  9. High specific activity silicon-32

    DOE Patents [OSTI]

    Phillips, Dennis R. (Los Alamos, NM); Brzezinski, Mark A. (Santa Barbara, CA)

    1996-01-01T23:59:59.000Z

    A process for preparation of silicon-32 is provided and includes contacting an irradiated potassium chloride target, including spallation products from a prior irradiation, with sufficient water, hydrochloric acid or potassium hydroxide to form a solution, filtering the solution, adjusting pH of the solution to from about 5.5 to about 7.5, admixing sufficient molybdate-reagent to the solution to adjust the pH of the solution to about 1.5 and to form a silicon-molybdate complex, contacting the solution including the silicon-molybdate complex with a dextran-based material, washing the dextran-based material to remove residual contaminants such as sodium-22, separating the silicon-molybdate complex from the dextran-based material as another solution, adding sufficient hydrochloric acid and hydrogen peroxide to the solution to prevent reformation of the silicon-molybdate complex and to yield an oxidization state of the molybdate adapted for subsequent separation by an anion exchange material, contacting the solution with an anion exchange material whereby the molybdate is retained by the anion exchange material and the silicon remains in solution, and optionally adding sufficient alkali metal hydroxide to adjust the pH of the solution to about 12 to 13. Additionally, a high specific activity silicon-32 product having a high purity is provided.

  10. Occupancy and site distribution of europium in barium magnesium aluminate Eu Mossbauer spectroscopy

    E-Print Network [OSTI]

    Boolchand, Punit

    Occupancy and site distribution of europium in barium magnesium aluminate by 151 Eu Mo¨ssbauer Mo¨ssbauer spectroscopy. Analysis of the Mo¨ssbauer line shapes reveals a pentamodal or higher site

  11. High-strain-rate nanoindentation behavior of fine-grained magnesium alloys

    E-Print Network [OSTI]

    Somekawa, Hidetoshi

    The effects of temperature and alloying elements on deformation in the high-strain-rate regime were investigated by testing fine-grained magnesium alloys with an average grain size of 2 ? 3 ?m by a nanoindentation technique. ...

  12. Magnesium Silicate Dissolution Investigated by 29Si MAS, 1H-29Si...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Silicate Dissolution Investigated by 29Si MAS, 1H-29Si CP MAS, 25Mg QCPMG, and 1H-25Mg CP QCPMG NMR. Magnesium Silicate Dissolution Investigated by 29Si MAS, 1H-29Si CP MAS, 25Mg...

  13. Vehicle Technologies Office: Long-Term Lightweight Materials Research (Magnesium and Carbon Fiber)

    Broader source: Energy.gov [DOE]

    The Vehicle Technologies Office supports research into magnesium and carbon fiber reinforced composites, which could reduce the weight of some components by 50-75 percent in the long-term.

  14. az91d magnesium alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Page Last Page Topic Index 1 Studies on the inuence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy Engineering Websites Summary:...

  15. az91d magnesium alloys: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Page Last Page Topic Index 1 Studies on the inuence of chloride ion and pH on the corrosion and electrochemical behaviour of AZ91D magnesium alloy Engineering Websites Summary:...

  16. Vehicle Technologies Office Merit Review 2015: Magnesium-Intensive Front End Sub-Structure Development

    Broader source: Energy.gov [DOE]

    Presentation given by USAMP at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about magnesium-intensive front end sub...

  17. Method of forming buried oxide layers in silicon

    DOE Patents [OSTI]

    Sadana, Devendra Kumar (Pleasantville, NY); Holland, Orin Wayne (Lenoir City, TN)

    2000-01-01T23:59:59.000Z

    A process for forming Silicon-On-Insulator is described incorporating the steps of ion implantation of oxygen into a silicon substrate at elevated temperature, ion implanting oxygen at a temperature below 200.degree. C. at a lower dose to form an amorphous silicon layer, and annealing steps to form a mixture of defective single crystal silicon and polycrystalline silicon or polycrystalline silicon alone and then silicon oxide from the amorphous silicon layer to form a continuous silicon oxide layer below the surface of the silicon substrate to provide an isolated superficial layer of silicon. The invention overcomes the problem of buried isolated islands of silicon oxide forming a discontinuous buried oxide layer.

  18. Lithium Ion Battery Performance of Silicon Nanowires With Carbon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ion Battery Performance of Silicon Nanowires With Carbon Skin . Lithium Ion Battery Performance of Silicon Nanowires With Carbon Skin . Abstract: Silicon (Si) nanomaterials have...

  19. Magnesium and pyridoxine intake and mineral content of selected tissues and physical development in rats

    E-Print Network [OSTI]

    Edgar, Susan Elaine

    1986-01-01T23:59:59.000Z

    MAGNESIUM AND PYRIDOXINE INTAKE MINERAL CONTENT OF SELECTED TISSUES PHYSICAL DEVELOPMENT IN RATS A Thesis by SU S AN ELA I NE EDGAR Submitted to the Graduate College of Texas A8rM University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE August 1986 Major Subject: Nutrition MAGNESIUM AND PYRIDOXINE INTAKE MINERAL CONTENT OF SELECTED TISSUES PHYS ICAL DEVELOPMENT IN RATS A Thesis by SUSAN ELAINE EDGAR Approved as to style and content by: 'KAREN...

  20. The oxidative dimerization of methane over promoted and unpromoted magnesium oxide monoliths

    E-Print Network [OSTI]

    Aigler, Jane Marie

    1989-01-01T23:59:59.000Z

    for the degree of MASTER OF SCIENCE May 1989 Major Subject: Chemistry THE OXIDATIVE DIMERIZATION OF METHANE OVER PROMOTED AND UNPROMOTED MAGNESIUM OxiDE MONOLITHS A Thesis by JANE MARIE AIGLER Approved as to style and content by: uns or (Chair of Commi... ee) os e (Member) nt ony (Member) a (Head of Department) May 1989 ABSTRACT The Oxidative Dimerization of Methane over Promoted and Unpromoted Magnesium Oxide Monoliths. (May 1989) Jane Marie Aigier, B. S. , Pennsylvania State University...

  1. A study of the role of calcium and magnesium in casein micellar structure in human milk 

    E-Print Network [OSTI]

    Gallaway, Sheila Ann

    1988-01-01T23:59:59.000Z

    ) Karen . Kubena (Member) Wa ne L. R&cko11 (Member) G. C. Smith (Head of Department) December 1988 ABSTRACT A Study of the Role of Calcium and Magnesium in Casein Micellar Structure in Human Milk. (December 1988) Sheila Ann Gallaway, B, S.... , Texas ASM University; M. S. , Texas ASM University Chair of Advisory Committee: Dr. C. W. Dill The effects of EDTA, phosphatase hydrolysis, calcium chloride, and magnesium chloride on human casein micelles were observed using electron microscopy...

  2. Magnesium deficiency and type of protein during gestation and lactation in rats 

    E-Print Network [OSTI]

    Holmes, Kathryn Ellen Hughes

    1988-01-01T23:59:59.000Z

    MAGNESIUM DEFICIENCY AND TYPE OF PROTEIN DURING GESTATION AND LACTATION IN RATS A Thesis by KATHRYN ELLEN HUGHES HOLMES Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 1988 Major Subject: Nutrition MAGNESIUM DEFICIENCY AND TYPE OF PROTEIN DURING GESTATION AND LACTATION IN RATS A Thesis by KATHRYN ELLEN HUGHES HOLMES Approved as to style and content by: Karen S. Kubena (Chair...

  3. An examination of the relationship between calcium and magnesium and hypertension 

    E-Print Network [OSTI]

    Georghiades, Mary Elizabeth

    1988-01-01T23:59:59.000Z

    AN EXAMINATION QF Tl-IE RELATIONSHIP BETWEEN CALCILIM AND MAGNESIUM AND HYPERTENSION A Thesis by MARY ELIZABETH GEORGHIADES Submitted to the Graduate College of Texas ARM University in partial Fulfillment of the requirements For the degree... of MASTER QF SCIENCE May 1988 Major Subject. : Nutrition AN EXAMINATION OF THE RELATIONSHIP BETWEEN CALCIUM AND MAGNESIUM AND HYPERTENSION A Thesis by MARY ELIZABETH GEORGH I ADES Approved as to style and content by: Karen S. Kubena (Chair...

  4. The tolerance of two varieties of cotton to relatively high levels of sodium and magnesium 

    E-Print Network [OSTI]

    Parekh, Manhar C

    1969-01-01T23:59:59.000Z

    THE TO'ERANCE OF TNO VARIETIES OF COTTON TO RELATIVELY HIGH LEVELS OF SODIUM AND MAGNESIUM A Tnesis by Msnhar C. Parekh Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree...) (Nember) (Nemb ) August 1969 ABSTRACT The Tolerance of Two Varieties of Cotton to Relatively High Levels of Sodium and Magnesium. (August 1969) Masher C. Parekh, B. S. , Gujarat University, Directed by: Dr. H. E. Joham An experiment was conducted...

  5. Mechanical Flow Response and Anisotropy of Ultra-Fine Grained Magnesium and Zinc Alloys 

    E-Print Network [OSTI]

    Al Maharbi, Majid H.

    2011-02-22T23:59:59.000Z

    MECHANICAL FLOW RESPONSE AND ANISOTROPY IN ULTRA-FINE GRAINED MAGNESIUM AND ZINC ALLOYS A Dissertation by MAJID AL MAHARBI Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY December 2009 Major Subject: Materials Science and Engineering MECHANICAL FLOW RESPONSE AND ANISOTROPY IN ULTRA-FINE GRAINED MAGNESIUM AND ZINC ALLOYS A Dissertation by MAJID AL...

  6. Blood pressure and red blood cell magnesium, potassium, and calcium responses to dietary fats 

    E-Print Network [OSTI]

    Wehrman, Noreen Elaine

    1993-01-01T23:59:59.000Z

    for the degree of MASTER OF SCIENCE August 1993 Major Subject: Nutrition BLOOD PRESSURE AND RED BLOOD CELL MAGNESIUM, POTASSIUM, AND CALCIUM RESPONSES TO DIETARY FATS A Thesis by NOREEN ELAINE WEHRMAN Submitted to Texas A&M University in partial.... Edwards (Head of Department) August 1993 Major Subject: Nutrition ABSTRACT Blood Pressure and Red Blood Cell Magnesium, Potassium, and Calcium Responses to Dietary Fats, (August 1993) Noreen Elaine Wehrman, B. S. , Pennsylvania State University...

  7. Novel Nonflammable Electrolytes for Secondary Magnesium Batteries and High Voltage Electrolytes for Electrochemcial Supercapacitors

    SciTech Connect (OSTI)

    Dr. Brian Dixon

    2008-12-30T23:59:59.000Z

    Magnesium has been used successfully in primary batteries, but its use in rechargeable cells has been stymied by the lack of suitable non-aqueous electrolyte that can conduct Mg+2 species, combined with poor stripping and plating properties. The development of a suitable cathode material for rechargeable magnesium batteries has also been a roadblock, but a nonflammable electrolyte is key. Likewise, the development of safe high voltage electrochemical supercapaitors has been stymied by the use of flammable solvents in the liquid electrolyte; to wit, acetonitrile. The purpose of the research conducted in this effort was to identify useful compositions of magnesium salts and polyphosphate solvents that would enable magnesium ions to be cycled within a secondary battery design. The polyphosphate solvents would provide the solvent for the magnesium salts while preventing the electrolyte from being flammable. This would enable these novel electrolytes to be considered as an alternative to THF-based electrolytes. In addition, we explored several of these solvents together with lithium slats for use as high voltage electrolytes for carbon-based electrochemical supercapacitors. The research was successful in that: 1) Magnesium imide dissolved in a phosphate ester solvent that contains a halogented phosphate ester appears to be the preferred electrolyte for a rechargeable Mg cell. 2) A combination of B-doped CNTs and vanadium phosphate appear to be the cathode of choice for a rechargeable Mg cell by virtue of higher voltage and better reversibility. 3) Magnesium alloys appear to perform better than pure magnesium when used in combination with the novel polyphosphate electrolytes. Also, this effort has established that Phoenix Innovationâ??s family of phosphonate/phosphate electrolytes together with specific lithium slats can be used in supercapacitor systems at voltages of greater than 10V.

  8. Aluminum Tape Evaluation for Sealable Aluminum Tubes Containing Mark 22 Fuel Tubes

    SciTech Connect (OSTI)

    RHODES, WILLIAM

    2003-01-01T23:59:59.000Z

    As part of the HEU Blend Down project, aluminum tape is required to seal aluminum tubes that will hold contaminated Mark 22 fuel tubes for dissolution. From a large field of candidate tapes, Avery Dennison's Fasson 0802 tape (synthetic rubber adhesive system) was found to be acceptable for this application. This tape will disentangle in the normal H-Canyon dissolver solution and have no detrimental effect on the H-Canyon process. Upon placement of Fasson 0802 tape into the dissolver solution, nitric acid will attack and disentangle the block copolymer network and destroy the adhesive nature of the material, resulting in insoluble particles that can be removed via centrifuge operations (cake weight increase of no more than 1 percent). The addition of the tape will not generate off-gas products and the resultant solution characteristics (surface tension, viscosity, density, and disengagement time) will be unaffected. Further, the potential effect on the down-stream evaporation system is negligible. Since the tape will not be placed in a high radiation environment, radiation stability is not an issue. Through detailed discussions with Avery Dennison chemists and based on analytical tests, a fairly detailed understanding of the constituents comprising the proprietary adhesive system has been assembled. Most importantly, chlorine was not detected in the aluminum tape (neutron activation analysis detection limit is 16 ppm). Finally, application of this tape will not impact LEU specifications.

  9. Diode laser welding of aluminum to steel

    SciTech Connect (OSTI)

    Santo, Loredana; Quadrini, Fabrizio; Trovalusci, Federica [University of Rome Tor Vergata, Department of Mechanical Engineering, Via del Politecnico 1, 00133 Rome (Italy)

    2011-05-04T23:59:59.000Z

    Laser welding of dissimilar materials was carried out by using a high power diode laser to join aluminum to steel in a butt-joint configuration. During testing, the laser scan rate was changed as well as the laser power: at low values of fluence (i.e. the ratio between laser power and scan rate), poor joining was observed; instead at high values of fluence, an excess in the material melting affected the joint integrity. Between these limiting values, a good aesthetics was obtained; further investigations were carried out by means of tensile tests and SEM analyses. Unfortunately, a brittle behavior was observed for all the joints and a maximum rupture stress about 40 MPa was measured. Apart from the formation of intermeltallic phases, poor mechanical performances also depended on the chosen joining configuration, particularly because of the thickness reduction of the seam in comparison with the base material.

  10. Passivation of Aluminum in Lithium-ion Battery Electrolytes with LiBOB

    E-Print Network [OSTI]

    Zhang, Xueyuan; Devine, Thomas M.

    2008-01-01T23:59:59.000Z

    Passivation of Aluminum in Lithium-ion Battery Electrolytesin commercially available lithium-ion battery electrolytes,

  11. Grain Boundary Decohesion and Particle-Matrix Debonding in Aluminum Alloy 7075-

    E-Print Network [OSTI]

    Paulino, Glaucio H.

    Grain Boundary Decohesion and Particle- Matrix Debonding in Aluminum Alloy 7075- T651 using the PPR - matrix debonding occur in some aluminum alloys. o To model accurately MSFC behavior in aluminum. Aluminum: properties and physical metallurgy. ASM International, 1984. 3 120µm 120µm grain boundaries

  12. Molecular dynamics simulations of the nano-scale room-temperature oxidation of aluminum single crystals

    E-Print Network [OSTI]

    Southern California, University of

    films that form on aluminum and aluminum alloys in air protect the surface against further oxidationMolecular dynamics simulations of the nano-scale room-temperature oxidation of aluminum single Abstract The oxidation of aluminum single crystals is studied using molecular dynamics (MD) simulations

  13. Cast B2-phase iron-aluminum alloys with improved fluidity

    DOE Patents [OSTI]

    Maziasz, Philip J. (122 Clark La., Oak Ridge, TN 37830); Paris, Alan M. (P.O. Box 64, Tarrs, PA 15688); Vought, Joseph D. (124 Cove Point Rd., Rockwood, TN 37854)

    2002-01-01T23:59:59.000Z

    Systems and methods are described for iron aluminum alloys. A composition includes iron, aluminum and manganese. A method includes providing an alloy including iron, aluminum and manganese; and processing the alloy. The systems and methods provide advantages because additions of manganese to iron aluminum alloys dramatically increase the fluidity of the alloys prior to solidification during casting.

  14. 1 Research review paper 2 Metabolic reengineering invoked by microbial systems to decontaminate aluminum

    E-Print Network [OSTI]

    Appanna, Vasu

    by microbial systems to decontaminate aluminum: 3 Implications for bioremediation technologies 4 ChristopherQ1

  15. ALUMINUM-BRIDGED BISGLYOXIMATO COBALT COMPLEXES: SYNTHESIS AND ELECTROCHEMICAL PROTON REDUCTION PROPERTIES

    E-Print Network [OSTI]

    Winfree, Erik

    194 CHAPTER 6 ALUMINUM-BRIDGED BISGLYOXIMATO COBALT COMPLEXES: SYNTHESIS AND ELECTROCHEMICAL PROTON diglyoximato complexes connected by one or two aluminum bridges are described. The aluminum centers that the number of aluminum bridges and the nature of the substituents on the phenoxide ligands significantly

  16. GENETIC TRANSFORMATION AND HYBRIDIZATION Bacterial citrate synthase expression and soil aluminum tolerance

    E-Print Network [OSTI]

    Parrott, Wayne

    GENETIC TRANSFORMATION AND HYBRIDIZATION Bacterial citrate synthase expression and soil aluminum that were more aluminum-tolerant than the non-transgenic control, confirming that citrate synthase overexpression can be a useful tool to help achieve aluminum tolerance. Keywords Acid soils Á Aluminum toxicity Á

  17. Kinetics of aluminum fluoride complexation in acidic waters

    SciTech Connect (OSTI)

    Plankey, B.J.; Patterson, H.H.; Cronan, C.S.

    1986-02-01T23:59:59.000Z

    Acidic deposition has an important effect on the transport and speciation of soluble aluminum. Toxicity of aqueous aluminum seems to be strongly dependent on aluminum speciation and the presence of complexing ligands such as fluoride. A study is reported of the complex formation kinetics of AlF/sup 2 +/ in the environmentally significant pH range 2.9-4.9. The pH and temperature dependencies of the overall rate of reaction are discussed along with environmental implications for areas subjected to acidic deposition. 22 references, 6 figures, 4 tables.

  18. Arnold Schwarzenegger SINGLE CRYSTAL SILICON

    E-Print Network [OSTI]

    in this report. #12;ENERGY INNOVATIONS SMALL GRANT (EISG) PROGRAM INDEPENDENT ASSESSMENT REPORT (IAR) SINGLEArnold Schwarzenegger Governor SINGLE CRYSTAL SILICON SHEET GROWTH Prepared For: California Energy Commission Energy Innovations Small Grant Program Prepared By: Energy Materials Research

  19. Polarization manipulation in silicon photonics

    E-Print Network [OSTI]

    Su, Zhan, S.M. Massachusetts Institute of Technology

    2013-01-01T23:59:59.000Z

    Silicon photonics is moving fast toward industrialization. It satisfies the increasing demand for higher speed, larger bandwidth communication. Thus it has a wide range of applications including high-performance computing, ...

  20. Process for the deposition of high temperature stress and oxidation resistant coatings on silicon-based substrates

    DOE Patents [OSTI]

    Sarin, V.K.

    1991-07-30T23:59:59.000Z

    A process is disclosed for depositing a high temperature stress and oxidation resistant coating on a silicon nitride- or silicon carbide-based substrate body. A gas mixture is passed over the substrate at about 900--1500 C and about 1 torr to about ambient pressure. The gas mixture includes one or more halide vapors with other suitable reactant gases. The partial pressure ratios, flow rates, and process times are sufficient to deposit a continuous, fully dense, adherent coating. The halide and other reactant gases are gradually varied during deposition so that the coating is a graded coating of at least two layers. Each layer is a graded layer changing in composition from the material over which it is deposited to the material of the layer and further to the material, if any, deposited thereon, so that no clearly defined compositional interfaces exist. The gases and their partial pressures are varied according to a predetermined time schedule and the halide and other reactant gases are selected so that the layers include (a) an adherent, continuous intermediate layer about 0.5-20 microns thick of an aluminum nitride or an aluminum oxynitride material, over and chemically bonded to the substrate body, and (b) an adherent, continuous first outer layer about 0.5-900 microns thick including an oxide of aluminum or zirconium over and chemically bonded to the intermediate layer.

  1. The effect of sulfur, magnesium, and various rates of potassium on forage production in some sandy soils of East Texas

    E-Print Network [OSTI]

    Landua, Dennis Paul

    1969-01-01T23:59:59.000Z

    in most of these soils. In a field experiment on Lakeland sand, ryegrass responded to applications of sulfur, but not to potassium or maqnesium, Soil profile analyses indicate that appli- cations of potassium caused magnesium to be displaced downward... the exchangeable potassium and magnesium in a Lakeland fine sand 4 Distribution of potassium, magnesium, and sulfate in a Lakeland fine sand. 48 Effect of fertilizer treatments on total yield of Coastal bermudagrass grown in the field in 1968. . 51 10 Effect...

  2. aluminum alloy composite: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage U.S. Department of Energy Version 2 - 2010 1 12 Promoters Oxide Promoters...

  3. aluminum alloy composites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen A Study of Issues Related to the Use of Aluminum for On-Board Vehicular Hydrogen Storage U.S. Department of Energy Version 2 - 2010 1 12 Promoters Oxide Promoters...

  4. aluminum alloys surface: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for atomic layer deposition of aluminum oxide A. J. Kerr, E. Chagarov, S. Gu, T. Kaufman-Osborn, S. Madisetti, J. Wu, P. M. Asbeck, S. Oktyabrsky, and A. C. Chemistry Websites...

  5. aluminum alloy surfaces: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for atomic layer deposition of aluminum oxide A. J. Kerr, E. Chagarov, S. Gu, T. Kaufman-Osborn, S. Madisetti, J. Wu, P. M. Asbeck, S. Oktyabrsky, and A. C. Chemistry Websites...

  6. aluminum nitride powder: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for atomic layer deposition of aluminum oxide A. J. Kerr, E. Chagarov, S. Gu, T. Kaufman-Osborn, S. Madisetti, J. Wu, P. M. Asbeck, S. Oktyabrsky, and A. C. Chemistry Websites...

  7. aluminum garnet phosphor: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 161 UV Curable Coatings in Aluminum Can Production Texas A&M University - TxSpace Summary: based...

  8. Climate VISION: Private Sector Initiatives: Aluminum: GHG Information

    Office of Scientific and Technical Information (OSTI)

    GHG Information The primary aluminum industry emits PFCs and CO2 directly from the production process and indirectly emits CO2 from its energy consumption. In 2001, the U.S....

  9. aluminum extrusion die: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    motor where aluminum has been the material of Dale T. Peters; John G. Cowie; Edwin F. Brush; Stephen P. Midson 38 Die KP und die Komintern. Open Access Theses and...

  10. Energy Challenges and Conservation Achievements in the Aluminum Industry

    E-Print Network [OSTI]

    Sheldon, A. C.

    1979-01-01T23:59:59.000Z

    energy requirements. This talk reviews the aluminum industry's and Alcoa's conservation activities of the past five post-embargo years. It highlights smelting improvements, still in the research and development stage, which nonetheless promise significant...

  11. Climate VISION: Private Sector Initiatives: Aluminum: Work Plans

    Office of Scientific and Technical Information (OSTI)

    of EPA. The plan describes actions the industry intends to take to achieve its Climate VISION goal by 2010. Read the Aluminum Association Work Plan (PDF 109 KB) Download...

  12. Gas-tungsten arc welding of aluminum alloys

    DOE Patents [OSTI]

    Frye, Lowell D. (Kingston, TN)

    1984-01-01T23:59:59.000Z

    A gas-tungsten arc welding method for joining together structures formed of aluminum alloy with these structures disposed contiguously to a heat-damagable substrate of a metal dissimilar to the aluminum alloy. The method of the present invention is practiced by diamond machining the fay surfaces of the aluminum alloy structures to provide a mirror finish thereon having a surface roughness in the order of about one microinch. The fay surfaces are aligned and heated sufficiently by the tungsten electrode to fuse the aluminum alloy contiguous to the fay surfaces to effect the weld joint. The heat input used to provide an oxide-free weld is significantly less than that required if the fay surfaces were prepared by using conventional chemical and mechanical practices.

  13. Experimental and Numerical Studies of Aluminum-Alumina Composites 

    E-Print Network [OSTI]

    Gudlur, Pradeep

    2013-07-22T23:59:59.000Z

    The preliminary goal of this study is to determine the effects of processing conditions, compositions and microstructural morphologies of the constituents on the physical and thermo-mechanical properties of alumina (Al_2O_3) reinforced aluminum (Al...

  14. New, More Efficient Technology for Remelting Aluminum Chips 

    E-Print Network [OSTI]

    Hosek, D.

    1994-01-01T23:59:59.000Z

    This project will introduce a new, more efficient technology for remelting the considerable volume of aluminum by 6.5% . Automated conveyors will transport chips from the machining operation to the new remelting operation for recycling. A reduction...

  15. Consolidation of aluminum 6061 powder by equal channel angular extrusion 

    E-Print Network [OSTI]

    Pearson, John Montgomery

    1997-01-01T23:59:59.000Z

    Equal channel angular extrusion is a promising approach to obtaining full density in powder metallurgy applications. This method can impose large effective deformations through uniform shear strain. Aluminum alloy 6061 powder is used as a test...

  16. Primary aluminum production : climate policy, emissions and costs

    E-Print Network [OSTI]

    Harnisch, Jochen.; Sue Wing, Ian.; Jacoby, Henry D.; Prinn, Ronald G.

    Climate policy regarding perfluorocarbons (PFCs) may have a significant influence on investment decisions in the production of primary aluminum. This work demonstrates an integrated analysis of the effectiveness and likely ...

  17. Evaluation of heat stress in an aluminum smelter

    E-Print Network [OSTI]

    Rose, Stacy Rahkell

    1999-01-01T23:59:59.000Z

    of heat stress and heat strain was evaluated for the aluminum smelter workers at Alcoa, Rockdale Operations. Personal, environmental, and metabolic factors that contribute to heat-related illnesses were identified. The effectiveness of current...

  18. aa7075 aluminum alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the solid-state. (more) Pedrazas, Nicholas Alan 2010-01-01 5 ABSTRACT. The corrosion behavior of iron-aluminum alloys and their potential Materials Science Websites...

  19. a319 aluminum alloy: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the solid-state. (more) Pedrazas, Nicholas Alan 2010-01-01 5 ABSTRACT. The corrosion behavior of iron-aluminum alloys and their potential Materials Science Websites...

  20. aluminum alloy electrochemical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in the solid-state. (more) Pedrazas, Nicholas Alan 2010-01-01 5 ABSTRACT. The corrosion behavior of iron-aluminum alloys and their potential Materials Science Websites...