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Sample records for lsc floorplan lsc

  1. United States Geological Survey, LSC | Open Energy Information

    Open Energy Info (EERE)

    Testing Facilities Name United States Geological Survey, LSC Address Leetown Science Center, Conte Anadromous Fish Laboratory, 1 Migratory Way Place Turners Falls,...

  2. Facility Floorplan

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    facility floorplan Facility Floorplan

  3. DOE Tour of Zero Floorplans: Reclaimed Modern by Dwell Development...

    Energy Savers [EERE]

    Zero Floorplans: Reclaimed Modern by Dwell Development DOE Tour of Zero Floorplans: Reclaimed Modern by Dwell Development DOE Tour of Zero Floorplans: Reclaimed Modern by Dwell...

  4. DOE Tour of Zero Floorplans: Bates Avenue by Sunroc Builders...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bates Avenue by Sunroc Builders DOE Tour of Zero Floorplans: Bates Avenue by Sunroc Builders DOE Tour of Zero Floorplans: Bates Avenue by Sunroc Builders

  5. DOE Tour of Zero Floorplans: Hickory Drive by Glastonbury Housesmith...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hickory Drive by Glastonbury Housesmith DOE Tour of Zero Floorplans: Hickory Drive by Glastonbury Housesmith DOE Tour of Zero Floorplans: Hickory Drive by Glastonbury Housesmith...

  6. DOE Tour of Zero Floorplans: Candlewood Hills Rebuild by BPC...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Candlewood Hills Rebuild by BPC Green Builders DOE Tour of Zero Floorplans: Candlewood Hills Rebuild by BPC Green Builders DOE Tour of Zero Floorplans: Candlewood Hills Rebuild by ...

  7. DOE Tour of Zero Floorplans: Euclid Avenue by Heirloom Design...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Euclid Avenue by Heirloom Design Build DOE Tour of Zero Floorplans: Euclid Avenue by Heirloom Design Build DOE Tour of Zero Floorplans: Euclid Avenue by Heirloom Design Build

  8. DOE Tour of Zero Floorplans: Green Acres #28 by Greenhill Contracting...

    Energy Savers [EERE]

    Zero Floorplans: Green Acres 28 by Greenhill Contracting DOE Tour of Zero Floorplans: Green Acres 28 by Greenhill Contracting DOE Tour of Zero Floorplans: Green Acres 28 by...

  9. DOE Tour of Zero Floorplans: Green Acres #20 by Greenhill Contracting...

    Energy Savers [EERE]

    Zero Floorplans: Green Acres 20 by Greenhill Contracting DOE Tour of Zero Floorplans: Green Acres 20 by Greenhill Contracting DOE Tour of Zero Floorplans: Green Acres 20 by...

  10. DOE Tour of Zero Floorplans: Green Acres #26 by Greenhill Contracting...

    Energy Savers [EERE]

    Zero Floorplans: Green Acres 26 by Greenhill Contracting DOE Tour of Zero Floorplans: Green Acres 26 by Greenhill Contracting DOE Tour of Zero Floorplans: Green Acres 26 by...

  11. DOE Tour of Zero Floorplans: Options for Community Living by...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Options for Community Living by United Way of Long Island DOE Tour of Zero Floorplans: Options for Community Living by United Way of Long Island DOE Tour of Zero Floorplans: ...

  12. DOE Tour of Zero Floorplans: Shenandoah Circle by Mantell-Hecathorn...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shenandoah Circle by Mantell-Hecathorn Builders DOE Tour of Zero Floorplans: Shenandoah Circle by Mantell-Hecathorn Builders DOE Tour of Zero Floorplans: Shenandoah Circle by ...

  13. DOE Tour of Zero Floorplans: Taft School by BPC Green Builders...

    Energy Savers [EERE]

    Taft School by BPC Green Builders DOE Tour of Zero Floorplans: Taft School by BPC Green Builders DOE Tour of Zero Floorplans: Taft School by BPC Green

  14. DOE Tour of Zero Floorplans: Chamberlain Court #75 by High Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Chamberlain Court 75 by High Performance Homes DOE Tour of Zero Floorplans: Chamberlain Court 75 by High Performance Homes DOE Tour of Zero Floorplans: Chamberlain Court 75 by...

  15. DOE Tour of Zero Floorplans: Marine Drive by Clifton View Homes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Marine Drive by Clifton View Homes DOE Tour of Zero Floorplans: Marine Drive by Clifton View Homes DOE Tour of Zero Floorplans: Marine Drive by Clifton View...

  16. DOE Tour of Zero Floorplans: Port Hadlock by Clifton View Homes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Port Hadlock by Clifton View Homes DOE Tour of Zero Floorplans: Port Hadlock by Clifton View Homes DOE Tour of Zero Floorplans: Port Hadlock by Clifton View Homes...

  17. DOE Tour of Zero Floorplans: Mutual Housing at Spring Lake by...

    Energy Savers [EERE]

    DOE Tour of Zero Floorplans: Mutual Housing at Spring Lake by Mutual Housing California DOE Tour of Zero Floorplans: Mutual Housing at Spring Lake by Mutual Housing California DOE ...

  18. DOE Tour of Zero Floorplans: Bellingham Power House by TC Legend...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bellingham Power House by TC Legend Homes DOE Tour of Zero Floorplans: Bellingham Power House by TC Legend Homes DOE Tour of Zero Floorplans: Bellingham Power House by TC Legend

  19. DOE Tour of Zero Floorplans: Pumpkin Ridge Passive House by Hammer...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Pumpkin Ridge Passive House by Hammer and Hand DOE Tour of Zero Floorplans: Pumpkin Ridge Passive House by Hammer and Hand DOE Tour of Zero Floorplans: Pumpkin Ridge Passive House ...

  20. DOE Tour of Zero Floorplans: McKinley Project by Carl Franklin...

    Energy Savers [EERE]

    Zero Floorplans: McKinley Project by Carl Franklin Homes and Green Extreme Homes DOE Tour of Zero Floorplans: McKinley Project by Carl Franklin Homes and Green Extreme Homes DOE...

  1. DOE Tour of Zero Floorplans: Vision Hill Lot 1 by Mandalay Homes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vision Hill Lot 1 by Mandalay Homes DOE Tour of Zero Floorplans: Vision Hill Lot 1 by Mandalay Homes DOE Tour of Zero Floorplans: Vision Hill Lot 1 by Mandalay Homes

  2. DOE Tour of Zero Floorplans: Row Homes at Perrin's Row by New...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Row Homes at Perrin's Row by New Town Builders DOE Tour of Zero Floorplans: Row Homes at Perrin's Row by New Town Builders DOE Tour of Zero Floorplans: Row Homes at Perrin's Row by ...

  3. DOE Tour of Zero Floorplans: Via del Cielo by Palo Duro Homes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Via del Cielo by Palo Duro Homes DOE Tour of Zero Floorplans: Via del Cielo by Palo Duro Homes DOE Tour of Zero Floorplans: Via del Cielo by Palo Duro

  4. DOE Tour of Zero Floorplans: Laurel Gardens #794 by Habitat for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laurel Gardens 794 by Habitat for Humanity South Sarasota County DOE Tour of Zero Floorplans: Laurel Gardens 794 by Habitat for Humanity South Sarasota County DOE Tour of Zero...

  5. Argonne Physics Division - ATLAS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Floorplan ATLAS Floorplan

  6. Oxygen surface exchange kinetics and stability of (La,Sr)2 CoO4±δ/La 1-xSrxMO3-δ (M = Co and Fe) hetero-interfaces at intermediate temperatures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lee, Dongkyu; Lee, Yueh-Lin; Hong, Wesley T.; Biegalski, Michael D.; Morgan, Dane; Shao-Horn, Yang

    2015-01-01

    Heterostructured oxide interfaces created by decorating Ruddlesden-Popper phases (A2BO4) or perovskites on perovskites have shown not only pronounced cation segregation at the interface and in the A2BO4 structure but also much enhanced kinetics for oxygen electrocatalysis at elevated temperatures. In this study, we report and compare the time-dependent surface exchange kinetics and stability of (La0.5Sr0.5)2CoO4 -decorated (LSC214) La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF113) and La0.8Sr0.2CoO3-δ (LSC113) thin films. While LSC214 decoration on LSC113 greatly reduced the degradation in the surface exchange kinetics as a function of time relative to LSC113, LSCF113 with LSC214 coverage showed comparable surface exchange kinetics and stability to LSCF113. Thismore » difference can be explained by greater surface stability of LSCF113 than LSC113 under testing conditions, and that LSC214 decoration on LSC113 reduced the decomposition of LSC113 to form secondary phases that impedes oxygen exchange kinetics, and thus resulted in enhanced stability. This hypothesis is supported by the observations that annealing at 550 °C led to the formation of Sr-rich secondary particles on LSC113 while no such particles were observed on LSCF113. Density functional theory (DFT) computation provides further support, which revealed greater capacity of surface Sr segregation for LSCF113 having SrO termination than LSC113 having (La0.25Sr0.75)O termination for the experimental conditions, and lower energy gain to move Sr from LSCF113 into LSC214 relative to the LSC214-LSC113 system.« less

  7. CO Substitution in HOs3(CO)10(l-SC6H4Me-4) by the Diphosphine 4,5-Bis(diphenylphosphino)-4-cyclopentadiene-1,3-dione (bpcd): Structural and DFT Evaluation of the Isomeric Clusters HOs3(CO)8(bpcd)(mu-SC6H4Me-4)

    SciTech Connect (OSTI)

    Yang, Li; Nesterov, Vladimir; Wang, Xiaoping; Richmond, Michael G.

    2012-01-01

    The reaction of the cluster HOs{sub 3}(CO){sub 10}({mu}-SC{sub 6}H{sub 4}Me-4) (1) with the diphosphine 4,5-bis(diphenylphosphino)-4-cyclopentadiene-1,3-dione (bpcd) has been investigated. 1 reacts with bpcd at room temperature in the presence of Me{sub 3}NO to give the isomeric clusters 1,2-HOs{sub 3}(CO)8(bpcd)({mu}-SC{sub 6}H{sub 4}Me-4) (2a) and 1,1-HOs{sub 3}(CO)8(bpcd)({mu}-SC{sub 6}H{sub 4}Me-4) (2b). Clusters 2a and 2b have been isolated, and the molecular structure of each compound has been established by X-ray crystallography. The X-ray structure of 2a confirms the coordination of one of the non-hydride-bridged Os-Os vectors by the bpcd ligand, while the structure of 2b exhibits a chelating bpcd ligand that is bound to one of the osmium centers ligated by the thiolate and hydrido ligands. 2a and 2b are stable in refluxing toluene and show no evidence for bridge-to-chelate isomerization of the ancillary bpcd ligand. DFT calculations on 2a and 2b indicate that the former cluster is the thermodynamically more stable isomer. Near-UV irradiation of 2b leads to CO loss and ortho metalation of the thiolate moiety, yielding the dihydride cluster H{sub 2}Os{sub 3}(CO)7(bpcd)({mu},{sigma}-SC{sub 6}H{sub 3}Me-4) (3). The conversion of 2b to 3 and free CO is computed to be endothermic by 14.1 kcal/mol and the reaction is driven by the entropic release of CO. The photochemically promoted ortho-metalation reaction is isomer dependent since cluster 2a is inert under identical conditions.

  8. Category:Testing Facility Operators | Open Energy Information

    Open Energy Info (EERE)

    Survey, LSC United States Naval Surface Warfare Center University of California, Berkeley University of California, San Diego (Scripps) U cont. University of Iowa University...

  9. Electrochemically influenced cation inter-diffusion and Co3O4 formation on La0.6Sr0.4CoO3 infiltrated into SOFC cathodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Song, Xueyan; Lee, Shiwoo; Chen, Yun; Gerdes, Kirk

    2015-06-18

    Nanosized LSC electrocatalyst was infiltrated into a porous scaffold cathode composed of Sm2O3-doped CeO2 (SDC) and La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) in a commercial button solid oxide fuel cell (SOFC). To understand the stability of cathodes infiltrated with LSC, the infiltrated composite cells were subjected to both electrochemical operating and thermal aging states at 750 °C for 1500 h. Nanostructure and local chemistry evolution of La0.6Sr0.4CoO3 (LSC) infiltrated cathodes upon operation and aging were investigated by transmission electron microscopy. After operation, the LSC remained a cubic perovskite, and the crystal grains exhibit comparable size to as-infiltrated LSC grains. Inter-diffusion of Fe from themore » LSCF to a Fe-incorporated LSC layer developed on the LSCF backbone. However, only sharp interfaces were observed between LSC and SDC backbone in the as-infiltrated cathode and such interfaces remain after operation. The infiltrated LSC on the SDC backbone also retains granular particle morphology. Furthermore, newly grown Co3O4 nanocrystals were found in the operated cathode. After thermal aging, on the other hand, cation inter-diffusion across the interfaces of the infiltrate particles and the cathode backbones is less than that from the operated cells. Lastly, the following hypothesis is proposed: Co3O4 forms on LSC arising from local charge balancing between cobalt and oxygen vacancies.« less

  10. Promising future of quantum dots explored in conference

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Promising future of quantum dots explored Promising future of quantum dots explored in conference Researchers are gathering to reflect on two decades of quantum dot research at a special topical conference, "20 Years of Quantum Dots at Los Alamos" April 13, 2015 Quantum dot LSC devices under ultraviolet illumination. Quantum dot LSC devices under ultraviolet illumination. Contact Los Alamos National Laboratory Nancy Ambrosiano Communications Office (505) 667-0471 Email "This

  11. Shiny quantum dots brighten future of solar cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shiny quantum dots brighten future of solar cells Shiny quantum dots brighten future of solar cells The project demonstrates that superior light-emitting properties of quantum dots can be applied in solar energy by helping more efficiently harvest sunlight. April 14, 2014 Quantum dot LSC devices under ultraviolet illumination. Quantum dot LSC devices under ultraviolet illumination. Contact Nancy Ambrosiano Communications Office (505) 667-0471 Email "The key accomplishment is the

  12. Simulation of a cascaded longitudinal space charge amplifier for coherent radiation generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Halavanau, A.; Piot, P.

    2016-03-03

    Longitudinal space charge (LSC) effects are generally considered as harmful in free-electron lasers as they can seed unfavorable energy modulations that can result in density modulations with associated emittance dilution. It was pointed out, however, that such \\micro-bunching instabilities" could be potentially useful to support the generation of broadband coherent radiation. Therefore there has been an increasing interest in devising accelerator beam lines capable of controlling LSC induced density modulations. In the present paper we augment these previous investigations by combining a grid-less space charge algorithm with the popular particle-tracking program elegant. This high-fidelity model of the space charge ismore » used to benchmark conventional LSC models. We then employ the developed model to optimize the performance of a cascaded longitudinal space charge amplifier using beam parameters comparable to the ones achievable at Fermilab Accelerator Science & Technology (FAST) facility currently under commissioning at Fermilab.« less

  13. Simulation of a cascaded longitudinal space charge amplifier for broadband radiation production using a superconducting linac

    SciTech Connect (OSTI)

    Halavanau, A.; Piot, P.

    2015-10-02

    Longitudinal space charge (LSC) effects are generally considered as harmful in free-electron lasers as they can seed unfavorable energy modulations that can result in density modulations with associated emittance dilution. It was pointed out, however, that such \\micro-bunching instabilities" could be potentially useful to support the generation of broadband coherent radiation. Therefore there has been an increasing interest in devising accelerator beam lines capable of controlling LSC induced density modulations. In the present paper we augment these previous investigations by combining a grid-less space charge algorithm with the popular particle-tracking program elegant. This high-fidelity model of the space charge is used to benchmark conventional LSC models. We then employ the developed model to optimize the performance of a cascaded longitudinal space charge amplifier using beam parameters comparable to the ones achievable at Fermilab Accelerator Science & Technology (FAST) facility currently under commissioning at Fermilab

  14. Lighting system combining daylight concentrators and an artificial source

    DOE Patents [OSTI]

    Bornstein, Jonathan G.; Friedman, Peter S.

    1985-01-01

    A combined lighting system for a building interior includes a stack of luminescent solar concentrators (LSC), an optical conduit made of preferably optical fibers for transmitting daylight from the LSC stack, a collimating lens set at an angle, a fixture for receiving the daylight at one end and for distributing the daylight as illumination inside the building, an artificial light source at the other end of the fixture for directing artifical light into the fixture for distribution as illumination inside the building, an automatic dimmer/brightener for the artificial light source, and a daylight sensor positioned near to the LSC stack for controlling the automatic dimmer/brightener in response to the daylight sensed. The system also has a reflector positioned behind the artificial light source and a fan for exhausting heated air out of the fixture during summer and for forcing heated air into the fixture for passage into the building interior during winter.

  15. Numerical Study of Three Dimensional Effects in Longitudinal Space-Charge Impedance

    SciTech Connect (OSTI)

    Halavanau, A.; Piot, P.

    2015-06-01

    Longitudinal space-charge (LSC) effects are generally considered as detrimental in free-electron lasers as they can seed instabilities. Such “microbunching instabilities” were recently shown to be potentially useful to support the generation of broadband coherent radiation pulses [1, 2]. Therefore there has been an increasing interest in devising accelerator beamlines capable of sustaining this LSC instability as a mechanism to produce a coherent light source. To date most of these studies have been carried out with a one-dimensional impedance model for the LSC. In this paper we use a N-body “Barnes-Hut” algorithm [3] to simulate the 3D space charge force in the beam combined with elegant [4] and explore the limitation of the 1D model often used

  16. Test of the consistency of various linearized semiclassical initial value time correlation functions in application to inelastic neutron scattering from liquid para-hydrogen

    SciTech Connect (OSTI)

    Miller, William; Liu, Jian; Miller, William H.

    2008-03-15

    The linearized approximation to the semiclassical initial value representation (LSC-IVR) is used to calculate time correlation functions relevant to the incoherent dynamic structure factor for inelastic neutron scattering from liquid para-hydrogen at 14 K. Various time correlations functions were used which, if evaluated exactly, would give identical results, but they do not because the LSC-IVR is approximate. Some of the correlation functions involve only linear operators, and others involve non-linear operators. The consistency of the results obtained with the various time correlation functions thus provides a useful test of the accuracy of the LSC-IVR approximation and its ability to treat correlation functions involving both linear and nonlinear operators in realistic anharmonic systems. The good agreement of the results obtained from different correlation functions, their excellent behavior in the spectral moment tests based on the exact moment constraints, and their semi-quantitative agreement with the inelastic neutron scattering experimental data all suggest that the LSC-IVR is indeed a good short-time approximation for quantum mechanical correlation functions.

  17. Cathode side hardware for carbonate fuel cells

    DOE Patents [OSTI]

    Xu, Gengfu; Yuh, Chao-Yi

    2011-03-29

    Carbonate fuel cathode side hardware having a thin coating of a conductive ceramic formed from one of LSC (La.sub.0.8Sr.sub.0.2CoO.sub.3) and lithiated NiO (Li.sub.xNiO, where x is 0.1 to 1).

  18. Development of an Ultra-Low Background Liquid Scintillation Counter for Trace Level Analysis

    SciTech Connect (OSTI)

    Erchinger, Jennifer L.; Orrell, John L.; Aalseth, Craig E.; Bernacki, Bruce E.; Douglas, Matthew; Finn, Erin C.; Fuller, Erin S.; Keillor, Martin E.; Morley, Shannon M.; Mullen, Crystal A.; Panisko, Mark E.; Shaff, Sarah M.; Warren, Glen A.; Wright, Michael E.

    2015-09-01

    Low-level liquid scintillation counting (LSC) has been established as one of the radiation detection techniques useful in elucidating environmental processes and environmental monitoring around nuclear facilities. The Ultra-Low Background Liquid Scintillation Counter (ULB-LSC) under construction in the Shallow Underground Laboratory at Pacific Northwest National Laboratory aims to further reduce the MDAs and/or required sample processing. Through layers of passive shielding in conjunction with an active veto and 30 meters water equivalent overburden, the background reduction is expected to be 10 to 100 times below typical analytic low-background liquid scintillation systems. Simulations have shown an expected background of around 14 counts per day. A novel approach to the light collection will use a coated hollow light guide cut into the inner copper shielding. Demonstration LSC measurements will show low-energy detection, spectral deconvolution, and alpha/beta discrimination capabilities, from trials with standards of tritium, strontium-90, and actinium-227, respectively. An overview of the system design and expected demonstration measurements will emphasize the potential applications of the ULB-LSC in environmental monitoring for treaty verification, reach-back sample analysis, and facility inspections.

  19. Ultra-short longitudinal spatial coherence length of laser light with the combined effect of spatial, angular, and temporal diversity

    SciTech Connect (OSTI)

    Ahmad, Azeem E-mail: mehtads@physics.iitd.ac.in; Dubey, Vishesh; Mehta, D. S. E-mail: mehtads@physics.iitd.ac.in; Srivastava, Vishal

    2015-03-02

    We demonstrate ultra-high axial-resolution topography and tomography of multilayered objects using pseudo thermal light source, i.e., laser. The longitudinal spatial coherence (LSC) length of light was significantly reduced by synthesizing a pseudo thermal source with the combined effect of spatial, angular, and temporal diversity. Thus, generating a low spatially coherent (i.e., broad angular frequency spectrum) light source having narrow temporal frequency spectrum. The LSC length was reduced less than 10 μm using a very low magnification lens. Experimental results of optical sectioning of multilayer objects with high axial-resolution of the order of 4 μm was achieved which is comparable to broadband light source. The present system does not require any dispersion compensation optical system for biological samples as a highly monochromatic light source is used.

  20. Center for Advanced Solar Photophysics | News

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    EFRC News & Press Releases Department of Energy Highlight: Turning Windows into Solar Panels LANL Press Release: Capture sunlight with your windows R&D Magazine: Capture sunlight with your windows Phys.org: Quantum dot solar windows go non-toxic, colorless, with record efficiency Laser Focus World: Non-toxic quantum dots promise efficient LSC-based building-integrated solar windows and lighting IEEE Spectrum: A Clearer Outlook for Quantum Dot-Enabled Solar Windows LANL Press Release:

  1. Bubble nucleation in simple and molecular liquids via the largest spherical cavity method

    SciTech Connect (OSTI)

    Gonzalez, Miguel A.; Abascal, José L. F.; Valeriani, Chantal; Bresme, Fernando

    2015-04-21

    In this work, we propose a methodology to compute bubble nucleation free energy barriers using trajectories generated via molecular dynamics simulations. We follow the bubble nucleation process by means of a local order parameter, defined by the volume of the largest spherical cavity (LSC) formed in the nucleating trajectories. This order parameter simplifies considerably the monitoring of the nucleation events, as compared with the previous approaches which require ad hoc criteria to classify the atoms and molecules as liquid or vapor. The combination of the LSC and the mean first passage time technique can then be used to obtain the free energy curves. Upon computation of the cavity distribution function the nucleation rate and free-energy barrier can then be computed. We test our method against recent computations of bubble nucleation in simple liquids and water at negative pressures. We obtain free-energy barriers in good agreement with the previous works. The LSC method provides a versatile and computationally efficient route to estimate the volume of critical bubbles the nucleation rate and to compute bubble nucleation free-energies in both simple and molecular liquids.

  2. Liquid scintillation counting methodology for 99Tc analysis. A remedy for radiopharmaceutical waste

    SciTech Connect (OSTI)

    Khan, Mumtaz; Um, Wooyong

    2015-08-13

    This paper presents a new approach for liquid scintillation counting (LSC) analysis of single-radionuclide samples containing appreciable organic or inorganic quench. This work offers better analytical results than existing LSC methods for technetium-99 (99gTc) analysis with significant savings in analysis cost and time. The method was developed to quantify 99gTc in environmental liquid and urine samples using LSC. Method efficiency was measured in the presence of 1.9 to 11,900 ppm total dissolved solids. The quench curve was proved to be effective in the case of spiked 99gTc activity calculation for deionized water, tap water, groundwater, seawater, and urine samples. Counting efficiency was found to be 91.66% for Ultima Gold LLT (ULG-LLT) and Ultima Gold (ULG). Relative error in spiked 99gTc samples was ±3.98% in ULG and ULG-LLT cocktails. Minimum detectable activity was determined to be 25.3 mBq and 22.7 mBq for ULG-LLT and ULG cocktails, respectively. A pre-concentration factor of 1000 was achieved at 100°C for 100% chemical recovery.

  3. Bioprocessing of a stored mixed liquid waste

    SciTech Connect (OSTI)

    Wolfram, J.H.; Rogers, R.D.; Finney, R.

    1995-12-31

    This paper describes the development and results of a demonstration for a continuous bioprocess for mixed waste treatment. A key element of the process is an unique microbial strain which tolerates high levels of aromatic solvents and surfactants. This microorganism is the biocatalysis of the continuous flow system designed for the processing of stored liquid scintillation wastes. During the past year a process demonstration has been conducted on commercial formulation of liquid scintillation cocktails (LSC). Based on data obtained from this demonstration, the Ohio EPA granted the Mound Applied Technologies Lab a treatability permit allowing the limited processing of actual mixed waste. Since August 1994, the system has been successfully processing stored, {open_quotes}hot{close_quotes} LSC waste. The initial LSC waste fed into the system contained 11% pseudocumene and detectable quantities of plutonium. Another treated waste stream contained pseudocumene and tritium. Data from this initial work shows that the hazardous organic solvent, and pseudocumene have been removed due to processing, leaving the aqueous low level radioactive waste. Results to date have shown that living cells are not affected by the dissolved plutonium and that 95% of the plutonium was sorbed to the biomass. This paper discusses the bioprocess, rates of processing, effluent, and the implications of bioprocessing for mixed waste management.

  4. Background studies for NaI(Tl) detectors in the ANAIS dark matter project

    SciTech Connect (OSTI)

    Amaré, J.; Borjabad, S.; Cebrián, S.; Cuesta, C.; Fortuño, D.; García, E.; Ginestra, C.; Gómez, H.; Martínez, M.; Oliván, M. A.; Ortigoza, Y.; Solórzano, A. Ortiz de; Pobes, C.; Puimedón, J.; Sarsa, M. L.; Villar, J. A.; Villar, P.

    2013-08-08

    Several large NaI(Tl) detectors, produced by different companies, have been operated in the Canfranc Underground Laboratory (LSC) in the frame of the ANAIS (Annual modulation with NaI Scintillators) project devoted to the direct detection of dark matter. A complete background model has been developed for a 9.6 kg detector (referred as ANAIS-0 prototype) after a long data taking at LSC. Activities from the natural chains of {sup 238}U and {sup 232}Th, and {sup 40}K in the NaI(Tl) crystal were evaluated applying different methods: discrimination of alpha particles vs beta/gamma background by Pulse Shape Analysis for quantifying the content of the natural chains and coincidence techniques for {sup 40}K. Radioactive contaminations in the detector and shielding components were also determined by HPGe spectrometry. Monte Carlo simulations using Geant4 package were carried out to evaluate their contribution. At high energies, most of the measured background is nicely reproduced; at low energy some non-explained components are still present, although some plausible background sources have been analyzed. The {sup 40}K content of the NaI(Tl) crystal has been confirmed to be the dominant contributor to the measured background with this detector. In addition, preliminary results of the background characterization, presently underway at the LSC, of two recently produced NaI(Tl) detectors, with 12.5 kg mass each, will be presented: cosmogenic induced activity has been clearly observed and is being quantified, and {sup 40}K activity at a level ten times lower than in ANAIS-0 has been determined.

  5. Background analysis and status of the ANAIS dark matter project

    SciTech Connect (OSTI)

    Amaré, J.; Cebrián, S.; Cuesta, C.; García, E.; Ginestra, C.; Martínez, M.; Oliván, M. A.; Ortigoza, Y.; Ortiz de Solórzano, A.; Pobes, C.; Puimedón, J.; Sarsa, M. L.; Villar, J. A.; Villar, P.

    2015-08-17

    ANAIS (Annual modulation with NaI Scintillators) is a project aiming to set up at the new facilities of the Canfranc Underground Laboratory (LSC), a large scale NaI(Tl) experiment in order to explore the DAMA/LIBRA annual modulation positive result using the same target and technique. Two 12.5 kg each NaI(Tl) crystals provided by Alpha Spectra took data at the LSC in the ANAIS-25 set-up. The comparison of the background model for the ANAIS-25 prototypes with the experimental results is presented. ANAIS crystal radiopurity goals have been achieved for {sup 232}Th and {sup 238}U chains, but a {sup 210}Pb contamination out-of-equilibrium was identified, whose origin has been studied. The high light collection efficiency obtained with these prototypes allows to anticipate an energy threshold of the order of 1 keVee. A new detector, with improved performances, was received in March 2015 and very preliminary results are shown.

  6. Evaluation of three passive-integrating charcoal detectors for measuring radon concentrations. Master's thesis

    SciTech Connect (OSTI)

    Sharp, D.L.

    1990-03-01

    Three types of passive-integrating detectors that determine Radon-222 (Radon) concentrations in air samples were studied. Each detector type examined uses activated charcoal to adsorb radon from air samples that enter through a diffusion barrier. This results in a time-integrated sample. The three detector types analyzed were liquid-scintillation vials and canisters with and without moisture-absorbing desiccant. The LS vials contain a mixture of charcoal and desiccant. All three types of detectors were calibrated in a chamber of known radon concentration. Since the LS vials had not previously been studied at AFIT, the optimum procedure for exposing, processing, and counting the vials was established. An automated liquid-scintillation counter (LSC) was used for determining the radon levels of the LS vials. The variability in the radon concentrations computed by the LSC for repeated counting of a single vial was examined and was found to be between 1 and 4%. Reproducibility of radon adsorption by a group of vials exposed simultaneously was examined. Reproducibility values for a group of ten vials counted for 4 cycles had a standard error of 1.4%. A blind test was performed where the detectors were exposed to a known concentration, prepared, counted, and then the concentrations measured were compared to actual values. The measured values were within 0.2% to about 8% of the actual concentrations. Exposure times of 24 to 48 hours were recommended for the vials and 3 to 7 days for the canisters.

  7. Local Sensitivity of Predicted CO2 Injectivity and Plume Extent to Model Inputs for the FutureGen 2.0 site

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Z. Fred; White, Signe K.; Bonneville, Alain; Gilmore, Tyler J.

    2014-12-31

    Numerical simulations have been used for estimating CO2 injectivity, CO2 plume extent, pressure distribution, and Area of Review (AoR), and for the design of CO2 injection operations and monitoring network for the FutureGen project. The simulation results are affected by uncertainties associated with numerous input parameters, the conceptual model, initial and boundary conditions, and factors related to injection operations. Furthermore, the uncertainties in the simulation results also vary in space and time. The key need is to identify those uncertainties that critically impact the simulation results and quantify their impacts. We introduce an approach to determine the local sensitivity coefficientmore » (LSC), defined as the response of the output in percent, to rank the importance of model inputs on outputs. The uncertainty of an input with higher sensitivity has larger impacts on the output. The LSC is scalable by the error of an input parameter. The composite sensitivity of an output to a subset of inputs can be calculated by summing the individual LSC values. We propose a local sensitivity coefficient method and applied it to the FutureGen 2.0 Site in Morgan County, Illinois, USA, to investigate the sensitivity of input parameters and initial conditions. The conceptual model for the site consists of 31 layers, each of which has a unique set of input parameters. The sensitivity of 11 parameters for each layer and 7 inputs as initial conditions is then investigated. For CO2 injectivity and plume size, about half of the uncertainty is due to only 4 or 5 of the 348 inputs and 3/4 of the uncertainty is due to about 15 of the inputs. The initial conditions and the properties of the injection layer and its neighbour layers contribute to most of the sensitivity. Overall, the simulation outputs are very sensitive to only a small fraction of the inputs. However, the parameters that are important for controlling CO2 injectivity are not the same as those controlling

  8. Local Sensitivity of Predicted CO2 Injectivity and Plume Extent to Model Inputs for the FutureGen 2.0 site

    SciTech Connect (OSTI)

    Zhang, Z. Fred; White, Signe K.; Bonneville, Alain; Gilmore, Tyler J.

    2014-12-31

    Numerical simulations have been used for estimating CO2 injectivity, CO2 plume extent, pressure distribution, and Area of Review (AoR), and for the design of CO2 injection operations and monitoring network for the FutureGen project. The simulation results are affected by uncertainties associated with numerous input parameters, the conceptual model, initial and boundary conditions, and factors related to injection operations. Furthermore, the uncertainties in the simulation results also vary in space and time. The key need is to identify those uncertainties that critically impact the simulation results and quantify their impacts. We introduce an approach to determine the local sensitivity coefficient (LSC), defined as the response of the output in percent, to rank the importance of model inputs on outputs. The uncertainty of an input with higher sensitivity has larger impacts on the output. The LSC is scalable by the error of an input parameter. The composite sensitivity of an output to a subset of inputs can be calculated by summing the individual LSC values. We propose a local sensitivity coefficient method and applied it to the FutureGen 2.0 Site in Morgan County, Illinois, USA, to investigate the sensitivity of input parameters and initial conditions. The conceptual model for the site consists of 31 layers, each of which has a unique set of input parameters. The sensitivity of 11 parameters for each layer and 7 inputs as initial conditions is then investigated. For CO2 injectivity and plume size, about half of the uncertainty is due to only 4 or 5 of the 348 inputs and 3/4 of the uncertainty is due to about 15 of the inputs. The initial conditions and the properties of the injection layer and its neighbour layers contribute to most of the sensitivity. Overall, the simulation outputs are very sensitive to only a small fraction of the inputs. However, the parameters that are important for controlling CO2 injectivity are not the same as those controlling the plume

  9. Biodecontamination of concrete

    SciTech Connect (OSTI)

    Rogers, R.D.

    1995-12-31

    This paper describes the development and results of a demonstration for a continuous bioprocess for mixed waste treatment. A key element of the process is a unique microbial strain, which tolerates high levels of aromatic solvents and surfactants. This microorganism is the biocatalysis of the continuous flow system designed for processing stored liquid scintillation wastes. During the past year, a process demonstration has been conducted on commercial formulation of liquid scintillation cocktails (LSQ). Based on data obtained from this demonstration, the Ohio Environmental Protection Agency granted the Mound Applied Technologies Laboratory a treatability permit allowing the limited processing of actual mixed waste. Since August 1994, the system has been successfully processing stored {open_quotes}hot{close_quotes} LSC waste. This paper discusses the bioprocess, rates of processing, effluent, and implications of bioprocessing for mixed waste management.

  10. Characterization of Atomic and Electronic Structures of Electrochemically Active SOFC Cathode Surfaces

    SciTech Connect (OSTI)

    Kevin Blinn; Yongman Choi; Meilin Liu

    2009-08-11

    The objective of this project is to gain a fundamental understanding of the oxygen-reduction mechanism on mixed conducting cathode materials by means of quantum-chemical calculations coupled with direct experimental measurements, such as vibrational spectroscopy. We have made progress in the elucidation of the mechanisms of oxygen reduction of perovkite-type cathode materials for SOFCs using these quantum chemical calculations. We established computational framework for predicting properties such as oxygen diffusivity and reaction rate constants for adsorption, incorporation, and TPB reactions, and formulated predictions for LSM- and LSC-based cathode materials. We have also further developed Raman spectroscopy as well as SERS as a characterization tool for SOFC cathode materials. Raman spectroscopy was used to detect chemical changes in the cathode from operation conditions, and SERS was used to probe for pertinent adsorbed species in oxygen reduction. However, much work on the subject of unraveling oxygen reduction for SOFC cathodes remains to be done.

  11. Power flow controller with a fractionally rated back-to-back converter

    DOE Patents [OSTI]

    Divan, Deepakraj M.; Kandula, Rajendra Prasad; Prasai, Anish

    2016-03-08

    A power flow controller with a fractionally rated back-to-back (BTB) converter is provided. The power flow controller provide dynamic control of both active and reactive power of a power system. The power flow controller inserts a voltage with controllable magnitude and phase between two AC sources at the same frequency; thereby effecting control of active and reactive power flows between the two AC sources. A transformer may be augmented with a fractionally rated bi-directional Back to Back (BTB) converter. The fractionally rated BTB converter comprises a transformer side converter (TSC), a direct-current (DC) link, and a line side converter (LSC). By controlling the switches of the BTB converter, the effective phase angle between the two AC source voltages may be regulated, and the amplitude of the voltage inserted by the power flow controller may be adjusted with respect to the AC source voltages.

  12. Development of characterization protocol for mixed liquid radioactive waste classification

    SciTech Connect (OSTI)

    Zakaria, Norasalwa; Wafa, Syed Asraf; Wo, Yii Mei; Mahat, Sarimah

    2015-04-29

    Mixed liquid organic waste generated from health-care and research activities containing tritium, carbon-14, and other radionuclides posed specific challenges in its management. Often, these wastes become legacy waste in many nuclear facilities and being considered as problematic waste. One of the most important recommendations made by IAEA is to perform multistage processes aiming at declassification of the waste. At this moment, approximately 3000 bottles of mixed liquid waste, with estimated volume of 6000 litres are currently stored at the National Radioactive Waste Management Centre, Malaysia and some have been stored for more than 25 years. The aim of this study is to develop a characterization protocol towards reclassification of these wastes. The characterization protocol entails waste identification, waste screening and segregation, and analytical radionuclides profiling using various analytical procedures including gross alpha/ gross beta, gamma spectrometry, and LSC method. The results obtained from the characterization protocol are used to establish criteria for speedy classification of the waste.

  13. Luminescent solar concentrator development: Final subcontract report, 1 June 1982-31 December 1984

    SciTech Connect (OSTI)

    Friedman, P.S.; Parent, C.R.

    1987-04-01

    An investigation of luminescent solar concentrators (LSCs) was begun by the US Department of Energy (DOE) at Owens-Illinois, Inc., in 1978. Experimental and theoretical results of that investigation are summarized in this report. An assessment of the LSC technology was compiled to provide a concise description to guide future research in this field. Since 1978, tremendous progress was made in the development of this device as a practical nonimaging concentrator for achieving solar concentration ratios on the order of 10X. The two most important technical achievements appear to be first, the understanding that dye self-absorption of radiated energy is not as serious a problem as originally thought; and second, the demonstration that organic dyes in polymeric hosts are capable of surviving outdoors in bright sunlight for years without serious degradation. System efficiencies approaching 4% have been achieved for photovoltaic conversion and theoretical efficiencies on the order of 9% appear feasible for large-area devices.

  14. OXYGEN TRANSPORT CERAMIC MEMBRANES

    SciTech Connect (OSTI)

    Dr. Sukumar Bandopadhyay; Dr. Nagendra Nagabhushana

    2003-01-01

    In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Processing of perovskites of LSC, LSF and LSCF composition for evaluation of mechanical properties as a function of environment are begun. The studies are to be in parallel with LSFCO composition to characterize the segregation of cations and slow crack growth in environmental conditions. La{sub 1-x}Sr{sub x}FeO{sub 3-d} has also been characterized for paramagnetic ordering at room temperature and the evolution of magnetic moments as a function of temperature are investigated. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport.

  15. Synchrotron Investigations of SOFC Cathode Degradation

    SciTech Connect (OSTI)

    Idzerda, Yves

    2013-09-30

    The atomic variations occurring in cathode/electrolyte interface regions of La{sub 1-x}Sr{sub x}Co{sub y}Fe{sub 1-y}O{sub 3-?} (LSCF) cathodes and other SOFC related materials have been investigated and characterized using soft X-ray Absorption Spectroscopy (XAS) and diffuse soft X-ray Resonant Scattering (XRS). X-ray Absorption Spectroscopy in the soft X-ray region (soft XAS) is shown to be a sensitive technique to quantify the disruption that occurs and can be used to suggest a concrete mechanism for the degradation. For LSC, LSF, and LSCF films, a significant degradation mechanism is shown to be Sr out-diffusion. By using the XAS spectra of hexavalent Cr in SrCrO4 and trivalent Cr in Cr2O3, the driving factor for Sr segregation was identified to be the oxygen vacancy concentration at the anode and cathode side of of symmetric LSCF/GDC/LSCF heterostructures. This is direct evidence of vacancy induced cation diffusion and is shown to be a significant indicator of cathode/electrolyte interfacial degradation. X-ray absorption spectroscopy is used to identify the occupation of the A-sites and B-sites for LSC, LSF, and LSCF cathodes doped with other transition metals, including doping induced migration of Sr to the anti-site for Sr, a significant cathode degradation indicator. By using spatially resolved valence mapping of Co, a complete picture of the surface electrochemistry can be determined. This is especially important in identifying degradation phenomena where the degradation is spatially localized to the extremities of the electrochemistry and not the average. For samples that have electrochemical parameters that are measured to be spatially uniform, the Co valence modifications were correlated to the effects of current density, overpotential, and humidity.

  16. Selective Extraction of Uranium from Liquid or Supercritical Carbon Dioxide

    SciTech Connect (OSTI)

    Farawila, Anne F.; O'Hara, Matthew J.; Wai, Chien M.; Taylor, Harry Z.; Liao, Yu-Jung

    2012-07-31

    Current liquid-liquid extraction processes used in recycling irradiated nuclear fuel rely on (1) strong nitric acid to dissolve uranium oxide fuel, and (2) the use of aliphatic hydrocarbons as a diluent in formulating the solvent used to extract uranium. The nitric acid dissolution process is not selective. It dissolves virtually the entire fuel meat which complicates the uranium extraction process. In addition, a solvent washing process is used to remove TBP degradation products, which adds complexity to the recycling plant and increases the overall plant footprint and cost. A liquid or supercritical carbon dioxide (l/sc -CO2) system was designed to mitigate these problems. Indeed, TBP nitric acid complexes are highly soluble in l/sc -CO2 and are capable of extracting uranium directly from UO2, UO3 and U3O8 powders. This eliminates the need for total acid dissolution of the irradiated fuel. Furthermore, since CO2 is easily recycled by evaporation at room temperature and pressure, it eliminates the complex solvent washing process. In this report, we demonstrate: (1) A reprocessing scheme starting with the selective extraction of uranium from solid uranium oxides into a TBP-HNO3 loaded Sc-CO2 phase, (2) Back extraction of uranium into an aqueous phase, and (3) Conversion of recovered purified uranium into uranium oxide. The purified uranium product from step 3 can be disposed of as low level waste, or mixed with enriched uranium for use in a reactor for another fuel cycle. After an introduction on the concept and properties of supercritical fluids, we first report the characterization of the different oxides used for this project. Our extraction system and our online monitoring capability using UV-Vis absorbance spectroscopy directly in sc-CO2 is then presented. Next, the uranium extraction efficiencies and kinetics is demonstrated for different oxides and under different physical and chemical conditions: l/sc -CO2 pressure and temperature, TBP/HNO3 complex used

  17. Mitigation Plans for the Microbunching-Instability-Related COTR at ASTA/FNAL

    SciTech Connect (OSTI)

    Lumpkin, A. H.; Johnson, A. M.

    2013-05-01

    At the Advanced Superconducting Test Accelerator (ASTA) now under construction at Fermilab, we anticipate the appearance of the microbunching instability related to the longitudinal space charge (LSC) impedances. With a photoinjector source and up to two chicane compressors planned, the conditions should result in the shift of some microbunched features into the visible light regime. The presence of longitudinal microstructures (microbunching) in the electron beam or the leading edge spikes can result in strong, spatially localized coherent enhancements of optical transition radiation (COTR) that mask the actual beam profile. Several efforts on mitigation of the effects in the diagnostics task have been identified. At ASTA we have designed the beam profiling stations to have mitigation features based on spectral filtering, scintillator choice, and the timing of the trigger to the digital camera's CCD chip. Since the COTR is more intense in the NIR than UV we have selectable bandpass filters centered at 420 nm which also overlap the spectral emissions of the LYSO:Ce scintillators. By delaying the CCD trigger timing of the integration window by 40-50 ns, we can reject the prompt OTR signal and integrate on the delayed scintillator light predominately. This combination of options should allow mitigation of COTR enhancements of order 100-1000 in the distribution.

  18. Overview of mixed waste issues

    SciTech Connect (OSTI)

    Piciulo, P.L.; Bowerman, B.S.; Kempf, C.R.; MacKenzie, D.R.; Siskind, B.

    1986-01-01

    Based on BNL's study it was concluded that there are LLWs which contain chemically hazardous components. Scintillation liquids may be considered an EPA listed hazardous waste and are, therefore, potential mixed wastes. Since November, 1985 no operating LLW disposal site will accept these wastes for disposal. Unless such wastes contain de minimis quantities of radionuclides, they cannot be disposed of at an EPA an EPA permitted site. Currently generators of LSC wastes can ship de minimis wastes to be burned at commercial facilities. Oil wastes will also eventually be an EPA listed waste and thus will have to be considered a potential radioactive mixed wasted unless NRC establishes de minimis levels of radionuclides below which oils can be managed as hazardous wastes. Regarding wastes containing lead metal there is some question as to the extent of the hazard posed by lead disposed in a LLW burial trench. Chromium-containing wastes would have to be tested to determine whether they are potential mixed wastes. There may be other wastes that are mixed wastes; the responsibility for determining this rests with the waste generator. It is believed that there are management options for handling potential mixed wastes but there is no regulatory guidance. BNL has identified and evaluated a variety of treatment options for the management of potential radioactive mixed wastes. The findings of that study showed that application of a management option with the purpose of addressing EPA concern can, at the same time, address stabilization and volume reduction concerns of NRC.

  19. Next Generation Print-based Manufacturing for Photovoltaics and Solid State Lighting

    SciTech Connect (OSTI)

    Sue A. Carter

    2012-09-07

    For the grand challenge of reducing our energy and carbon footprint, the development of renewable energy and energy efficient technologies offer a potential solution. Energy technologies can reduce our dependence on foreign oil as well as the energy consumed by the petroleum industry, the leading consumer of energy by a U.S. industry sector. Nonetheless, the manufacturing processes utilized to manufacture equipment for alternative energy technologies often involve energy-intensive processes. This undermines some of the advantages to moving to 'green' technologies in the first place. Our answer to the Industrial Technology Program's (ITP) Grand Challenge FOA was to develop a transformational low cost manufacturing process for plastic-based photovoltaics that will lower by over 50% both energy consumption and greenhouse emissions and offer a return-of-investment of over 20%. We demonstrated a Luminescent Solar Concentrator fabricated on a plastic acrylic substrate (i.e. no glass) that increases the power output of the PV cell by 2.2x with a 2% power efficiency as well as an LSC with a 7% power efficiency that increased the power output from the PV cells by 35%. S large area 20-inch x 60-inch building-integrated photovoltaic window was fabricated using contract manufacturing with a 4% power efficiency which improved the power output of the PV cell by over 50%. In addition, accelerated lifetimes of the luminescent material demonstrate lifetimes of 20-years.

  20. A Bunch Compression Method for Free Electron Lasers that Avoids Parasitic Compressions

    SciTech Connect (OSTI)

    Benson, Stephen V.; Douglas, David R.; Tennant, Christopher D.; Wilson, Frederick G.; Nguyen, Dinh

    2015-09-01

    Virtually all existing high energy (>few MeV) linac-driven FELs compress the electron bunch length though the use of off-crest acceleration on the rising side of the RF waveform followed by transport through a magnetic chicane. This approach has at least three flaws: 1) it is difficult to correct aberrations- particularly RF curvature, 2) rising side acceleration exacerbates space charge-induced distortion of the longitudinal phase space, and 3) all achromatic "negative compaction" compressors create parasitic compression during the final compression process, increasing the CSR-induced emittance growth. One can avoid these deficiencies by using acceleration on the falling side of the RF waveform and a compressor with M56>0. This approach offers multiple advantages: 1) It is readily achieved in beam lines supporting simple schemes for aberration compensation, 2) Longitudinal space charge (LSC)-induced phase space distortion tends, on the falling side of the RF waveform, to enhance the chirp, and 3) Compressors with M56>0 can be configured to avoid spurious over-compression. We will discuss this bunch compression scheme in detail and give results of a successful beam test in April 2012 using the JLab UV Demo FEL

  1. Leak before break evaluation for main steam piping system made of SA106 Gr.C

    SciTech Connect (OSTI)

    Yang, Kyoung Mo; Jee, Kye Kwang; Pyo, Chang Ryul; Ra, In Sik

    1997-04-01

    The basis of the leak before break (LBB) concept is to demonstrate that piping will leak significantly before a double ended guillotine break (DEGB) occurs. This is demonstrated by quantifying and evaluating the leak process and prescribing safe shutdown of the plant on the basis of the monitored leak rate. The application of LBB for power plant design has reduced plant cost while improving plant integrity. Several evaluations employing LBB analysis on system piping based on DEGB design have been completed. However, the application of LBB on main steam (MS) piping, which is LBB applicable piping, has not been performed due to several uncertainties associated with occurrence of steam hammer and dynamic strain aging (DSA). The objective of this paper is to demonstrate the applicability of the LBB design concept to main steam lines manufactured with SA106 Gr.C carbon steel. Based on the material properties, including fracture toughness and tensile properties obtained from the comprehensive material tests for base and weld metals, a parametric study was performed as described in this paper. The PICEP code was used to determine leak size crack (LSC) and the FLET code was used to perform the stability assessment of MS piping. The effects of material properties obtained from tests were evaluated to determine the LBB applicability for the MS piping. It can be shown from this parametric study that the MS piping has a high possibility of design using LBB analysis.

  2. Development of the Low Swirl Injector for Fuel-Flexible GasTurbines

    SciTech Connect (OSTI)

    Littlejohn, D.; Cheng, R.K.; Nazeer,W.A.; Smith, K.O

    2007-02-14

    Industrial gas turbines are primarily fueled with natural gas. However, changes in fuel cost and availability, and a desire to control carbon dioxide emissions, are creating pressure to utilize other fuels. There is an increased interest in the use of fuels from coal gasification, such as syngas and hydrogen, and renewable fuels, such as biogas and biodiesel. Current turbine fuel injectors have had years of development to optimize their performance with natural gas. The new fuels appearing on the horizon can have combustion properties that differ substantially from natural gas. Factors such as turbulent flame speed, heat content, autoignition characteristics, and range of flammability must be considered when evaluating injector performance. The low swirl injector utilizes a unique flame stabilization mechanism and is under development for gas turbine applications. Its design and mode of operation allow it to operate effectively over a wide range of conditions. Studies conducted at LBNL indicate that the LSI can operate on fuels with a wide range of flame speeds, including hydrogen. It can also utilize low heat content fuels, such as biogas and syngas. We will discuss the low swirl injector operating parameters, and how the LSC performs with various alternative fuels.

  3. Complete chloroplast genome of Trachelium caeruleum: extensiverearrangements are associated with repeats and tRNAs

    SciTech Connect (OSTI)

    Haberle, Rosemarie C.; Fourcade, Matthew L.; Boore, Jeffrey L.; Jansen, Robert K.

    2006-01-09

    Chloroplast genome structure, gene order and content arehighly conserved in land plants. We sequenced the complete chloroplastgenome sequence of Trachelium caeruleum (Campanulaceae) a member of anangiosperm family known for highly rearranged chloroplast genomes. Thetotal genome size is 162,321 bp with an IR of 27,273 bp, LSC of 100,113bp and SSC of 7,661 bp. The genome encodes 115 unique genes, with 19duplicated in the IR, a tRNA (trnI-CAU) duplicated once in the LSC and aprotein coding gene (psbJ) duplicated twice, for a total of 137 genes.Four genes (ycf15, rpl23, infA and accD) are truncated and likelynonfunctional; three others (clpP, ycf1 and ycf2) are so highly divergedthat they may now be pseudogenes. The most conspicuous feature of theTrachelium genome is the presence of eighteen internally unrearrangedblocks of genes that have been inverted or relocated within the genome,relative to the typical gene order of most angiosperm chloroplastgenomes. Recombination between repeats or tRNAs has been suggested as twomeans of chloroplast genome rearrangements. We compared the relativenumber of repeats in Trachelium to eight other angiosperm chloroplastgenomes, and evaluated the location of repeats and tRNAs in relation torearrangements. Trachelium has the highest number and largest repeats,which are concentrated near inversion endpoints or other rearrangements.tRNAs occur at many but not all inversion endpoints. There is likely nosingle mechanism responsible for the remarkable number of alterations inthis genome, but both repeats and tRNAs are clearly associated with theserearrangements. Land plant chloroplast genomes are highly conserved instructure, gene order and content. The chloroplast genomes of ferns, thegymnosperm Ginkgo, and most angiosperms are nearly collinear, reflectingthe gene order in lineages that diverged from lycopsids and the ancestralchloroplast gene order over 350 million years ago (Raubeson and Jansen,1992). Although earlier mapping studies

  4. Chancellor Water Colloids: Characterization and Radionuclide Association

    SciTech Connect (OSTI)

    Abdel-Fattah, Amr I.

    2012-06-18

    Concluding remarks about this paper are: (1) Gravitational settling, zeta potential, and ultrafiltration data indicate the existence of a colloidal phase of both the alpha and beta emitters in the Chancellor water; (2) The low activity combined with high dispersion homogeneity of the Chancellor water indicate that both alpha and beta emitters are not intrinsic colloids; (3) Radionuclides in the Chancellor water, particularly Pu, coexist as dissolved aqueous and sorbed phases - in other words the radionuclides are partitioned between the aqueous phase and the colloidal phase; (4) The presence of Pu as a dissolved species in the aqueous phase, suggests the possibility of Pu in the (V) oxidation state - this conclusion is supported by the similarity of the k{sub d} value of Pu determined in the current study to that determined for Pu(V) sorbed onto smectite colloids, and the similar electrokinetic behavior of the Chancellor water colloids to smectite colloids; (5) About 50% of the Pu(V) is in the aqueous phase and 50% is sorbed on colloids (mass concentration of colloids in the Chancellor water is 0.12 g/L); (6) The k{sub d} of the Pu and the beta emitters (fission products) between aqueous and colloidal phases in the Chancellor water is {approx}8.0 x 10{sup 3} mL/g using two different activity measurement techniques (LSC and alpha spectroscopy); (7) The gravitational settling and size distributions of the association colloids indicate that the properties (at least the physical ones) of the colloids to which the alpha emitters are associated with seem to be different that the properties of the colloids to which the beta emitters are associated with - the beta emitters are associated with very small particles ({approx}50 - 120 nm), while the alpha emitters are associated with relatively larger particles; and (8) The Chancellor water colloids are extremely stable under the natural pH and ionic strength conditions, indicating high potential for transport in the

  5. Oxygen Transport Ceramic Membranes

    SciTech Connect (OSTI)

    S. Bandopadhyay; N. Nagabhushana

    2003-08-07

    In the present quarter, experiments are presented on ceramic/metal interactions of Zirconia/ Ni-B-Si system and with a thin Ti coating deposited on zirconia surface. Existing facilities were modified for evaluation of environmental assisted slow crack growth and creep in flexural mode. Processing of perovskites of LSC, LSF and LSCF composition were continued for evaluation of mechanical properties as a function of environment. These studies in parallel to those on the LSFCO composition is expect to yield important information on questions such as the role of cation segregation and the stability of the perovskite structure on crack initiation vs. crack growth. Studies have been continued on the La{sub 1-x}Sr{sub x}FeO{sub 3-d} composition using neutron diffraction and TGA studies. A transition from p-type to n-type of conductor was observed at relative low pO{sub 2}, at which the majority carriers changed from the holes to electrons because of the valence state decreases in Fe due to the further loss of oxygen. Investigation on the thermodynamic properties of the membrane materials are continued to develop a complete model for the membrane transport. Data obtained at 850 C show that the stoichiometry in La{sub 0.2}Sr{sub 0.8}Fe{sub 0.8}Cr{sub 0.2}O{sub 3-x} vary from {approx}2.85 to 2.6 over the pressure range studied. From the stoichiometry a lower limit of 2.6 corresponding to the reduction of all Fe{sup 4+} to Fe{sup 3+} and no reduction of Cr{sup 3+} is expected.

  6. Dead reckoning pedometer

    DOE Patents [OSTI]

    Eakle, Jr., Robert F.; Hofstetter, Kenneth J.

    2003-04-15

    A system to determine the location of a person within a structure utilizes a magnetometer, magnets, pressure sensors and a CPU to calculate the length and direction of each step. The data may be displayed to the wearer, preferably on a map or floorplan and may be broadcast to persons outside the structure.

  7. Critical Causes of Degradation in Integrated Laboratory Scale Cells during High Temperature Electrolysis

    SciTech Connect (OSTI)

    M.S. Sohal; J.E. O'Brien; C.M. Stoots; J. J. Hartvigsen; D. Larsen; S. Elangovan; J.S. Herring; J.D. Carter; V.I. Sharma; B. Yildiz

    2009-05-01

    An ongoing project at Idaho National Laboratory involves generating hydrogen from steam using solid oxide electrolysis cells (SOEC). This report describes background information about SOECs, the Integrated Laboratory Scale (ILS) testing of solid-oxide electrolysis stacks, ILS performance degradation, and post-test examination of SOECs by various researchers. The ILS test was a 720- cell, three-module test comprised of 12 stacks of 60 cells each. A peak H2 production rate of 5.7 Nm3/hr was achieved. Initially, the module area-specific resistance ranged from 1.25 Ocm2 to just over 2 Ocm2. Total H2 production rate decreased from 5.7 Nm3/hr to a steady state value of 0.7 Nm3/hr. The decrease was primarily due to cell degradation. Post test examination by Ceramatec showed that the hydrogen electrode appeared to be in good condition. The oxygen evolution electrode does show delamination in operation and an apparent foreign layer deposited at the electrolyte interface. Post test examination by Argonne National Laboratory showed that the O2-electrode delaminated from the electrolyte near the edge. One possible reason for this delamination is excessive pressure buildup with high O2 flow in the over-sintered region. According to post test examination at the Massachusetts Institute of Technology, the electrochemical reactions have been recognized as one of the prevalent causes of their degradation. Specifically, two important degradation mechanisms were examined: (1) transport of Crcontaining species from steel interconnects into the oxygen electrode and LSC bond layers in SOECs, and (2) cation segregation and phase separation in the bond layer. INL conducted a workshop October 27, 2008 to discuss possible causes of degradation in a SOEC stack. Generally, it was agreed that the following are major degradation issues relating to SOECs: Delamination of the O2-electrode and bond layer on the steam/O2-electrode side Contaminants (Ni, Cr, Si, etc.) on reaction sites (triple

  8. Development of Tc(IV)-Incorporated Fe Minerals to Enhance 99Tc Retention in Glass Waste Form

    SciTech Connect (OSTI)

    Um, Wooyong; Luksic, Steven A.; Wang, Guohui; Kim, Dong-Sang; Schweiger, Michael J.; Hrma, Pavel R.; Kruger, Albert A.

    2015-03-17

    Iron minerals have been considered to be good hosts for Tc immobilization because the Tc(IV) ion substitutes for Fe(III) in the crystal structure of the Fe oxide due to similarities in (1) cation size [Tc(IV) = 78.5 pm ; Fe(III) = 69 or 78.5 pm], (2) metal-oxygen interatomic distance (Tc—O = 0.199 nm, Fe—O = 0.203 nm), (3) number of coordinating oxygen atoms (both 6-fold coordinated), and (4) the redox potential (Eh=ca. +20 mV at pH = 7) for a redox couple between Tc(VII)/Tc(IV) and Fe(III)/Fe(II). Magnetite, maghemite, and trevorite are iron oxide minerals and all belong to spinel mineral group. Laboratory testing shows that Tc can be removed from aqueous waste solutions by a process of Tc reduction from Tc(VII) to Tc(IV) followed by co-precipitation with iron oxide minerals during recrystallization of Fe(OH)2(s) used as an initial solid precursor. X-ray absorption near edge structure (XANES) spectroscopy confirmed that Tc was in the +4 oxidation state in final Tc-Fe minerals. The Tc-incorporated Fe minerals were also tested for Tc retention in glass melts at different temperatures between 600 – 1,000 oC in a furnace. After being cooled in air, the solid glass specimens collected at different temperatures were analyzed for Tc oxidation state using XANES and Tc retention using liquid scintillation counting (LSC). Even though Tc(IV) started to reoxidize at 600 oC, Tc retention in the final glass specimen prepared with Tc-incorporated Fe mineral even at high temperatures was at least two times higher than glass prepared with KTcO4 salt. Higher Tc retention in glass is considered to result from limited and delayed Tc volatilization process due to Fe mineral encapsulation for Tc. Therefore, the results showing the presence of Tc(IV) in the Fe mineral structure indicate strong possibility to enhance Tc retention in borosilicate glass as well as to reduce the remediation costs at the Hanford Site.

  9. $50 and up underground house book

    SciTech Connect (OSTI)

    Oehler, M.

    1981-01-01

    Earth-sheltered housing can be livable, compatible with nature, and inexpensive. Plans and designs for low-cost houses that are integrated with their environment make up most of this book. The author begins by outlining 23 advantages of underground housing and describing the histories of several unconventional buildings in the $50 to $500 price range. He also suggests where building materials can be bought and scrounged, describes construction techniques, and explains how to cope with building codes. Sketches, floorplans, and photographs illustrate the text. 8 references, 4 tables. (DCK)