Sample records for lpg distillate residual

  1. Hydroconversion of heavy oils. [Residue of tar sand bitumen distillation

    SciTech Connect (OSTI)

    Garg, D.

    1986-08-19T23:59:59.000Z

    A method is described for hydroconversion of feedstocks consisting essentially of at least one heavy hydrocarbon oil selected from the group consisting of residue of petroleum oil distillation and the residue of tar sand bitumen distillation to enhance the recovery of 350/sup 0/-650/sup 0/F boiling product fraction. The method comprises treating such feed stock with hydrogen at superatmospheric pressure and in the presence of finely divided active hydrogenation catalyst in consecutive reaction stages. An initial reaction stage is carried out at a temperature in the range of 780/sup 0/-825/sup 0/F, and a subsequent reaction stage is directly carried out after the initial reaction stage at a higher temperature in the range of 800/sup 0/F-860/sup 0/F, the temperature of the subsequent reaction stage being at least 20/sup 0/F higher than that of the initial reaction stage.

  2. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Gasoline and Diesel Fuel Update (EIA)

    A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

  3. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1999 441 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) - Continued...

  4. "Table A10. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocksa. AppliancesTotal" "(Data1.30. Total Consumption of

  5. "Table A2. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro IndustriesTownDells,1Stocksa. AppliancesTotal" "(Data1.30. Total6. Components.

  6. EXPERIMENTAL SIMULATION OF DISTILLATION COLUMN PROFILE MAPS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    EXPERIMENTAL SIMULATION OF DISTILLATION COLUMN PROFILE MAPS Tshepo Sehole David Modise A thesis or in combination, such as distillation, extraction, crystallization, ect. Among these, distillation is by far profiles for the preliminary design of distillation columns. Residue curves and column profile are not only

  7. Catalytic Distillation

    E-Print Network [OSTI]

    Smith, L. A., Jr.; Hearn, D.; Wynegar, D. P.

    1984-01-01T23:59:59.000Z

    Catalytic Distillation' refers to a chemical process which performs both a catalyzed reaction and primary fractionation of the reaction components simultaneously. A structured catalyst which also is an effective distillation component has been...

  8. Africa gaining importance in world LPG trade

    SciTech Connect (OSTI)

    Haun, R.R. [Purvin and Gertz Inc., Dallas, TX (United States); Otto, K.W.; Whitley, S.C. [Purvin and Gertz Inc., Houston, TX (United States)

    1997-05-12T23:59:59.000Z

    Major LPG projects planned or under way in Africa will increase the importance of that region`s presence in world LPG trade. Supplies will nearly double between 1995 and 2005, at which time they will remain steady for at least 10 years. At the same time that exports are leveling, however, increasing domestic demand for PG is likely to reduce export-market participation by Algeria, Nigeria, Egypt, and Libya. The growth of Africa`s participation in world LPG supply is reflected in comparisons for the next 15--20 years. Total world supply of LPG in 1995 was about 165 million metric tons (tonnes), of which Africans share was 7.8 million tonnes. By 2000, world supply will grow to slightly more than 200 million tonnes, with Africa`s share expected to increase to 13.2 million tonnes (6.6%). And by 2005, world LPG supply will reach nearly 230 million tonnes; Africa`s overall supply volumes by that year will be nearly 16.2 million tonnes (7%). World LPG supply for export in 1995 was on order of 44 million tonnes with Africa supply about 4 million tonnes (9%). By 2005, world export volumes of LPG will reach nearly 70 million tonnes; Africa`s share will have grown by nearly 10 million tonnes (14.3%).

  9. Distill, Distill_roll Distill for CASP10

    E-Print Network [OSTI]

    Pollastri, Gianluca

    Distill, Distill_roll Distill for CASP10 C. Mirabello1, G. Tradigo1,2 , P.Veltri2, and G. Pollastri1 1 ­ UCD Dublin, Ireland, 2 ­ Università di Cosenza, Italy gianluca.pollastri@ucd.ie Distill has to the distance maps of templates rather than to predicted contact maps. The difference between Distill

  10. Distillation 29 Chem 355 Jasperse DISTILLATION

    E-Print Network [OSTI]

    Jasperse, Craig P.

    Distillation 29 Chem 355 Jasperse DISTILLATION Background Distillation is a widely used technique for purifying liquids. The basic distillation process involves heating a liquid such that liquid molecules that is condensed and collected must be more pure than the original liquid mix. Distillation can be used to remove

  11. Fire safety of LPG in marine transportation

    SciTech Connect (OSTI)

    Martinsen, W.E.; Johnson, D.W.; Welker, J.R.

    1980-08-01T23:59:59.000Z

    This report contains an analytical examination of cargo spill and fire hazard potential associated with the marine handling of liquefied petroleum gas (LPG) as cargo. Principal emphasis was on cargo transfer operations for ships unloading at receiving terminals, and barges loading or unloading at a terminal. Major safety systems, including emergency shutdown systems, hazard detection systems, and fire extinguishment and control systems were included in the analysis. Spill probabilities were obtained from fault tree analyses utilizing composite LPG tank ship and barge designs. Failure rates for hardware in the analyses were generally taken from historical data on similar generic classes of hardware, there being very little historical data on the specific items involved. Potential consequences of cargo spills of various sizes are discussed and compared to actual LPG vapor cloud incidents. The usefulness of hazard mitigation systems (particularly dry chemical fire extinguishers and water spray systems) in controlling the hazards posed by LPG spills and spill fires is also discussed. The analysis estimates the probability of fatality for a terminal operator is about 10/sup -6/ to 10/sup -5/ per cargo transfer operation. The probability of fatality for the general public is substantially less.

  12. Application of Energy Saving Concepts to LPG Recovery Plants

    E-Print Network [OSTI]

    Carpenter, M. J.; Barnwell, J.

    1982-01-01T23:59:59.000Z

    Raw LPG extraction plants, designed prior to the 73/74 steep energy rise, offer opportunities for application of energy saving concepts. Many plants designed to recover raw LPG from associated gases and built prior to 1973/74 are relatively energy...

  13. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1984-01-01T23:59:59.000Z

    Catalytic distillation structure for use in reaction distillation columns, a providing reaction sites and distillation structure and consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and being present with the catalyst component in an amount such that the catalytic distillation structure consist of at least 10 volume % open space.

  14. LPG-recovery processes for baseload LNG plants examined

    SciTech Connect (OSTI)

    Chiu, C.H. [Bechtel Corp., Houston, TX (United States)

    1997-11-24T23:59:59.000Z

    With demand on the rise, LPG produced from a baseload LNG plant becomes more attractive as a revenue-earning product similar to LNG. Efficient use of gas expanders in baseload LNG plants for LPG production therefore becomes more important. Several process variations for LPG recovery in baseload LNG plants are reviewed here. Exergy analysis (based on the Second Law of Thermodynamics) is applied to three cases to compare energy efficiency resulting from integration with the main liquefaction process. The paper discusses extraction in a baseload plant, extraction requirements, process recovery parameters, extraction process variations, and exergy analysis.

  15. Monitoring, safety systems for LNG and LPG operators

    SciTech Connect (OSTI)

    True, W.R.

    1998-11-16T23:59:59.000Z

    Operators in Korea and Australia have chosen monitoring and control systems in recent contracts for LNG and LPG storage. Korea Gas Corp. (Kogas) has hired Whessoe Varec, Calais, to provide monitoring systems for four LNG storage tanks being built at Kogas` Inchon terminal. For Elgas Ltd., Port Botany, Australia, Whessoe Varec has already shipped a safety valve-shutdown system to a new LPG cavern-storage facility under construction. The paper describes the systems, terminal monitoring, dynamic approach to tank management, and meeting the growing demand for LPG.

  16. DistillationTheory.fm 2 September 1999 Distillation Theory.

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1 DistillationTheory.fm 2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway #12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . 8 Material Balance on a Distillation Stage

  17. Catalytic distillation structure

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1984-04-17T23:59:59.000Z

    Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

  18. INNOVATION EDUCATION EXCELLENCE DISTILLATIONS

    E-Print Network [OSTI]

    Chan, Hue Sun

    INNOVATION · EDUCATION · EXCELLENCE DISTILLATIONS University of Toronto CHEMISTRY ALUMNI MAGAZINE.utoronto.ca / distillations 2012 MessagefromtheChair Our Department of Chemistry has one of the finest collection of peo- ple to a better, more sustain- able future. This issue of Distillations highlights the accomplishments last year

  19. Canonical Distillation of Entanglement

    E-Print Network [OSTI]

    Tamoghna Das; Asutosh Kumar; Amit Kumar Pal; Namrata Shukla; Aditi Sen De; Ujjwal Sen

    2015-02-10T23:59:59.000Z

    Distilling highly entangled quantum states from weaker ones is a process that is crucial for efficient and long-distance quantum communication, and has implications for several other quantum information protocols. We introduce the notion of distillation under limited resources, and specifically focus on the energy constraint. The corresponding protocol, which we call the canonical distillation of entanglement, naturally leads to the set of canonically distillable states. We show that for non-interacting Hamiltonians, almost no states are canonically distillable, while the situation can be drastically different for interacting ones. Several paradigmatic Hamiltonians are considered for bipartite as well as multipartite canonical distillability. The results have potential applications for practical quantum communication devices.

  20. Distillation: The Efficient Workhorse

    E-Print Network [OSTI]

    Steinmeyer, D.

    DISTILLATION: THE EFFICIENT WORKHORSE Dan Steinmeyer Monsanto Company St. Louis, Missouri Distillation is inherently highly efficient: phase separation is clean it is relatively easy to build a mUltistage countercurrent device equilibrium... is closely approached on each stage Given the right perspective; the right application; and the right design - distillation is difficult to beat from an efficiency standpoint. ? The right perspective is that efficiency is the ratio of the work...

  1. SEPARATION OF TERNARY HETEROAZEOTROPIC MIXTURES IN A CLOSED MULTIVESSEL BATCH DISTILLATION-DECANTER HYBRID

    E-Print Network [OSTI]

    Skogestad, Sigurd

    SEPARATION OF TERNARY HETEROAZEOTROPIC MIXTURES IN A CLOSED MULTIVESSEL BATCH DISTILLATION, Trondheim, Norway The feasibility of a novel multivessel batch distillation-decanter hybrid for simultaneous enables us to make direct use of the distillation line (or residue curve) map. Simple rules for predicting

  2. Assessment of research and development (R and D) needs in LPG safety and environmental control

    SciTech Connect (OSTI)

    DeSteese, J.G.

    1982-05-01T23:59:59.000Z

    The report characterizes the LPG industry covering all operations from production to end use, reviews current knowledge of LPG release phenomenology, summarizes the status of current LPG release prevention and control methodology, and identifies any remaining safety and environmental problems and recommends R and D strategies that may mitigate these problems. (ACR)

  3. Generalized entanglement distillation

    E-Print Network [OSTI]

    Yu-Bo Sheng; Lan Zhou

    2014-04-14T23:59:59.000Z

    We present a way for the entanglement distillation of genuine mixed state. Different from the conventional mixed state in entanglement purification protocol, each components of the mixed state in our protocol is a less-entangled state, while it is always a maximally entangled state. With the help of the weak cross-Kerr nonlinearity, this entanglement distillation protocol does not require the sophisticated single-photon detectors. Moreover, the distilled high quality entangled state can be retained to perform the further distillation. These properties make it more convenient in practical applications.

  4. MULTIVESSEL BATCH DISTILLATION EXPERIMENTAL VERIFICATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION ­ EXPERIMENTAL VERIFICATION Bernd Wittgens and Sigurd Skogestad 1 The experimental verification of the operation of a multivessel batch distillation column, operated under total vessels, provides a generalization of previously proposed batch distillation schemes. We propose a simple

  5. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, Jr., Lawrence A. (Bellaire, TX)

    1982-01-01T23:59:59.000Z

    A method for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C.sub.4 feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  6. Catalytic distillation process

    DOE Patents [OSTI]

    Smith, L.A. Jr.

    1982-06-22T23:59:59.000Z

    A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

  7. Fire safety of LPG in marine transportation. Final report

    SciTech Connect (OSTI)

    Martinsen, W.E.; Johnson, D.W.; Welker, J.R.

    1980-06-01T23:59:59.000Z

    This report contains an analytical examination of cargo spill and fire hazard potential associated with the marine handling of liquefied petroleum gas (LPG) as cargo. Principal emphasis was on cargo transfer operations for ships unloading at receiving terminals, and barges loading or unloading at a terminal. Major safety systems, including emergency shutdown systems, hazard detection systems, and fire extinguishment and control systems were included in the analysis. Spill probabilities were obtained from fault tree analyses utilizing composite LPG tank ship and barge designs. Failure rates for hardware in the analyses were generally taken from historical data on similar generic classes of hardware, there being very little historical data on the specific items involved. Potential consequences of cargo spills of various sizes are discussed and compared to actual LPG vapor cloud incidents. The usefulness of hazard mitigation systems (particularly dry chemical fire extinguishers and water spray systems) in controlling the hazards posed by LPG spills and spill fires is also discussed. The analysis estimates the probability of fatality for a terminal operator is about 10/sup -6/ to 10/sup -5/ per cargo transfer operation. The probability of fatality for the general public is substantially less.

  8. 2000-32 V'B SAFETY PROVISIONS AND LPG

    E-Print Network [OSTI]

    Boyer, Edmond

    metres (m3 ) of LPG (exclusively butane and propane) not including the underground storage sites. Some 90% of these 95 sites were created between 1956 and 1975. These sites have over 300,000 m3 of storage capacity and 82 propane), 200 horizontal tanks and 2 vertical cryogenic tanks (35,000 and 20,000 m3

  9. Numerical Simulations of Leakage from Underground LPG Storage Caverns

    SciTech Connect (OSTI)

    Yamamoto, Hajime; Pruess, Karsten

    2004-09-01T23:59:59.000Z

    To secure a stable supply of petroleum gas, underground storage caverns for liquified petroleum gas (LPG) are commonly used in many countries worldwide. Storing LPG in underground caverns requires that the surrounding rock mass remain saturated with groundwater and that the water pressure be higher than the liquid pressure inside the cavern. In previous studies, gas containment criteria for underground gas storage based on hydraulic gradient and pressure have been discussed, but these studies do not consider the physicochemical characteristics and behavior of LPG such as vaporization and dissolution in groundwater. Therefore, while these studies are very useful for designing storage caverns, they do not provide better understanding of the either the environmental effects of gas contamination or the behavior of vaporized LPG. In this study, we have performed three-phase fluid flow simulations of gas leakage from underground LPG storage caverns, using the multiphase multicomponent nonisothermal simulator TMVOC (Pruess and Battistelli, 2002), which is capable of solving the three-phase nonisothermal flow of water, gas, and a multicomponent mixture of volatile organic chemicals (VOCs) in multidimensional heterogeneous porous media. A two-dimensional cross-sectional model resembling an actual underground LPG facility in Japan was developed, and gas leakage phenomena were simulated for three different permeability models: (1) a homogeneous model, (2) a single-fault model, and (3) a heterogeneous model. In addition, the behavior of stored LPG was studied for the special case of a water curtain suddenly losing its function because of operational problems, or because of long-term effects such as clogging of boreholes. The results of the study indicate the following: (1) The water curtain system is a very powerful means for preventing gas leakage from underground storage facilities. By operating with appropriate pressure and layout, gas containment can be ensured. (2) However , in highly heterogeneous media such as fractured rock and fault zones, local flow paths within which the gas containment criterion is not satisfied could be formed. To eliminate such zones, treatments such as pre/post grouting or an additional installment of water-curtain boreholes are essential. (3) Along highly conductive features such as faults, even partially saturated zones possess certain effects that can retard or prevent gas leakage, while a fully unsaturated fault connected to the storage cavern can quickly cause a gas blowout. This possibility strongly suggests that ensuring water saturation of the rock surrounding the cavern is a very important requirement. (4) Even if an accident should suddenly impair the water curtain, the gas plume does not quickly penetrate the ground surface. In these simulations, the plume takes several months to reach the ground surface.

  10. Advanced Distillation Final Report

    SciTech Connect (OSTI)

    Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

    2010-03-24T23:59:59.000Z

    The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were performed with the targeted mixture, ethane-ethylene, as well as with analogous low relative volatility systems: cyclohexane-hexane and cyclopentane-pentane. Devices and test stands were specifically designed for these efforts. Development progressed from experiments and models considering sections of a full scale device to the design, fabrication, and operation of a single-channel distillation unit with integrated heat transfer. Throughout the project, analytical and numerical models and Computational Fluid Dynamics (CFD) simulations were validated with experiments in the process of developing this platform technology. Experimental trials demonstrated steady and controllable distillation for a variety of process conditions. Values of Height-to-an-Equivalent Theoretical Plate (HETP) ranging from less than 0.5 inch to a few inches were experimentally proven, demonstrating a ten-fold performance enhancement relative to conventional distillation. This improvement, while substantial, is not sufficient for MPT distillation to displace very large scale distillation trains. Fortunately, parallel efforts in the area of business development have yielded other applications for MPT distillation, including smaller scale separations that benefit from the flowsheet flexibility offered by the technology. Talks with multiple potential partners are underway. Their outcome will also help determine the path ahead for MPT distillation.

  11. Random multiparty entanglement distillation

    E-Print Network [OSTI]

    Ben Fortescue; Hoi-Kwong Lo

    2008-01-15T23:59:59.000Z

    We describe various results related to the random distillation of multiparty entangled states - that is, conversion of such states into entangled states shared between fewer parties, where those parties are not predetermined. In previous work [Phys. Rev. Lett. 98, 260501 (2007)] we showed that certain output states (namely Einstein-Podolsky-Rosen (EPR) pairs) could be reliably acquired from a prescribed initial multipartite state (namely the W state) via random distillation that could not be reliably created between predetermined parties. Here we provide a more rigorous definition of what constitutes ``advantageous'' random distillation. We show that random distillation is always advantageous for W-class three-qubit states (but only sometimes for Greenberger-Horne-Zeilinger (GHZ)-class states). We show that the general class of multiparty states known as symmetric Dicke states can be readily converted to many other states in the class via random distillation. Finally we show that random distillation is provably not advantageous in the limit of multiple copies of pure states.

  12. Energy efficient distillation apparatus

    SciTech Connect (OSTI)

    Melton, J.D.

    1982-08-17T23:59:59.000Z

    An energy efficient distillation method is provided which is particularly adapted for use on a dairy farm, and which comprises a distilland evaporating receptacle, a distillate condensing receptacle, and a conduit interconnecting the evaporating receptacle and the condensing receptacle. A vacuum pump is provided for drawing a partial vacuum within the evaporating receptacle, and a vapor compression refrigeration system is provided which includes condenser coils disposed to heat and vaporize the distilland while it is within the evaporating receptacle, and evaporator coils for cooling and condensing the vaporized distilland in the condensing receptacle. A cooling distribution system is also provided whereby a variable portion of the cooling potential of the refrigeration system may be selectively directed to each of the condensing receptacle, a distillate receiver tank, or to a bulk milk container as utilized on a dairy farm or the like.

  13. Qutrit Magic State Distillation

    E-Print Network [OSTI]

    Anwar, Hussain; Browne, Dan E

    2012-01-01T23:59:59.000Z

    Magic state distillation (MSD) is a purification protocol that plays a central role in fault tolerant quantum computation. Repeated iteration of the steps of a MSD protocol, generates pure single non-stabilizer states, or magic states, from multiple copies of a mixed resource state using stabilizer operations only. Thus mixed resource states promote the stabilizer operations to full universality. Magic state distillation was introduced for qubit-based quantum computation, but little has been known concerning MSD in higher dimensional qudit-based computation. Here, we describe a general approach for studying MSD in higher dimensions. We use it to investigate the features of a qutrit MSD protocol based on the 5-qutrit stabilizer code. We show that this protocol distills non-stabilizer magic states, and identify two types of states, that are attractors of this iteration map. Finally, we show how these states may be converted, via stabilizer circuits alone, into a state suitable for state injected implementation ...

  14. Topological Quantum Distillation

    E-Print Network [OSTI]

    H. Bombin; M. A. Martin-Delgado

    2007-03-29T23:59:59.000Z

    We construct a class of topological quantum codes to perform quantum entanglement distillation. These codes implement the whole Clifford group of unitary operations in a fully topological manner and without selective addressing of qubits. This allows us to extend their application also to quantum teleportation, dense coding and computation with magic states.

  15. Low Energy Distillation Schemes

    E-Print Network [OSTI]

    Polley, G. T.

    of reducing energy consumption. We look at how the better integrated distillation schemes can be quickly identified. It is found that the design of integrated schemes is quicker than that of non-integrated schemes. We then look at how the use of heat pumps...

  16. Heteroazeotropic Batch Distillation Feasibility and Operation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Heteroazeotropic Batch Distillation Feasibility and Operation by Efstathios Skouras and distillation is the dominating unit operation for such separations. However, the presence of azeotropes and non distillation as the best suited process. Among, various techniques to enhance distillation, heterogeneous

  17. Fuel switching from wood to LPG can benefit the environment

    SciTech Connect (OSTI)

    Nautiyal, Sunil [Leibniz-Centre for Agricultural Landscape Research (ZALF), Institute of Socioeconomics, Eberswalder Str. 84, 15374 Muencheberg (Germany)], E-mail: sunil.nautiyal@zalf.de; Kaechele, Harald [Leibniz-Centre for Agricultural Landscape Research (ZALF), Institute of Socioeconomics, Eberswalder Str. 84, 15374 Muencheberg (Germany)

    2008-11-15T23:59:59.000Z

    The Himalaya in India is one of the world's biodiversity hotspots. Various scientific studies have reported and proven that many factors are responsible for the tremendous decline of the Himalayan forests. Extraction of wood biomass from the forests for fuel is one of the factors, as rural households rely entirely on this for their domestic energy. Efforts continue for both conservation and development of the Himalayan forests and landscape. It has been reported that people are still looking for more viable solutions that could help them to improve their lifestyle as well as facilitate ecosystem conservation and preservation of existing biodiversity. In this direction, we have documented the potential of the introduction of liquefied petroleum gas (LPG), which is one of the solutions that have been offered to the local people as a substitute for woodfuel to help meet their domestic energy demand. The results of the current study found dramatic change in per capita woodfuel consumption in the last two decades in the villages where people are using LPG. The outcome showed that woodfuel consumption had been about 475 kg per capita per year in the region, but after introduction of LPG, this was reduced to 285 kg per capita per year in 1990-1995, and was further reduced to 46 kg per capita per year in 2000-2005. Besides improving the living conditions of the local people, this transformation has had great environmental consequences. Empirical evidence shows that this new paradigm shift is having positive external effects on the surrounding forests. Consequently, we have observed a high density of tree saplings and seedlings in adjacent forests, which serves as an assessment indicator of forest health. With the help of the current study, we propose that when thinking about a top-down approach to conservation, better solutions, which are often ignored, should be offered to local people.

  18. Renormalising entanglement distillation

    E-Print Network [OSTI]

    Stephan Waeldchen; Janina Gertis; Earl T. Campbell; Jens Eisert

    2015-03-16T23:59:59.000Z

    Entanglement distillation refers to the task of transforming a collection of weakly entangled pairs into fewer highly entangled ones. It is a core ingredient in quantum repeater protocols, needed to transmit entanglement over arbitrary distances in order to realise quantum key distribution schemes. Usually, it is assumed that the initial entangled pairs are i.i.d. distributed and uncorrelated with each other, an assumption that might not be reasonable at all in any entanglement generation process involving memory channels. Here, we introduce a framework that captures entanglement distillation in the presence of natural correlations arising from memory channels. Conceptually, we bring together ideas from condensed-matter physics - that of renormalisation and of matrix-product states and operators - with those of local entanglement manipulation, Markov chain mixing, and quantum error correction. We identify meaningful parameter regions for which we prove convergence to maximally entangled states, arising as the fixed points of a matrix-product operator renormalisation flow.

  19. Reflux for multifeed distillation

    SciTech Connect (OSTI)

    Chou, S.M.; Yaws, C.L.

    1986-12-01T23:59:59.000Z

    Prior investigations have shown ways to determine minimum reflux for multicomponent distillation. This work extends earlier concepts in order to handle multifeeds. Reflux calculations for each feed, as though it were the only feed, are factored with the reflux effects of the other feeds to give an overall minimum reflux. Each factor has a finite value depending on the composition and thermal quality of the feed it represents.

  20. Intermediate Vapor Expansion Distillation and Nested Enrichment Cascade Distillation

    E-Print Network [OSTI]

    Erickson, D. C.

    INTERMEDIATE VAPOR EXPANSION DISTILLATION AND NESTED ENRICHMENT CASCADE DISTILLATION D.. C. Erickson Energy Concepts Company Annapolis, Maryland ABSTRACT Although it is known that incorporating an intermediate reboiler or reflux... condenser in a distillation ~olumn will improve column efficiency by 15 to 100%, there has been little use of this technique to date." Intermediate vapor compression heat pumping was recently introduced as one practical means of achieving this benefit...

  1. Evaluation of aftermarket LPG conversion kits in light-duty vehicle applications. Final report

    SciTech Connect (OSTI)

    Bass, E.A. [Southwest Research Inst., San Antonio, TX (US)] [Southwest Research Inst., San Antonio, TX (US)

    1993-06-01T23:59:59.000Z

    SwRI was contracted by NREL to evaluate three LPG conversion kits on a Chevrolet Lumina. The objective of the project was to measure the Federal Test Procedure (FTP) emissions and fuel economy of these kits, and compare their performance to gasoline-fueled operation and to each other. Varying LPG fuel blends allowed a preliminary look at the potential for fuel system disturbance. The project required kit installation and adjustment according to manufacturer`s instructions. A limited amount of trouble diagnosis was also performed on the fuel systems. A simultaneous contract from the Texas Railroad Commission, in cooperation with NREL, provided funds for additional testing with market fuels (HD5 propane and industry average gasoline) and hydrocarbon (HC) emissions speciation to determine the ozone-forming potential of LPG HC emissions. This report documents the procurement, installation, and testing of these LPG conversion kits.

  2. Influence of H{sub 2}O{sub 2} on LPG fuel performance evaluation

    SciTech Connect (OSTI)

    Khan, Muhammad Saad, E-mail: iqbalmouj@gmail.com; Ahmed, Iqbal, E-mail: iqbalmouj@gmail.com; Mutalib, Mohammad Ibrahim bin Abdul, E-mail: iqbalmouj@gmail.com; Nadeem, Saad, E-mail: iqbalmouj@gmail.com; Ali, Shahid, E-mail: iqbalmouj@gmail.com [Department of Chemical Engineering, Faculty of Engineering, Universiti Teknologi PETRONAS, Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia)

    2014-10-24T23:59:59.000Z

    The objective of this mode of combustion is to insertion of hydrogen peroxide (H{sub 2}O{sub 2}) to the Liquefied Petroleum Gas (LPG) combustion on spark plug ignition engines. The addition of hydrogen peroxide may probably decrease the formation of NO{sub x}, CO{sub x} and unburned hydrocarbons. Hypothetically, Studies have shown that addition of hydrogen peroxide to examine the performance of LPG/H{sub 2}O{sub 2} mixture in numerous volumetric compositions starting from lean LPG until obtaining a better composition can reduce the LPG fuel consumption. The theory behind this idea is that, the addition of H{sub 2}O{sub 2} can cover the lean operation limit, increase the lean burn ability, diminution the burn duration along with controlling the exhaust emission by significantly reducing the greenhouse gaseous.

  3. TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION BERND WITTGENS, RAJAB LITTO, EVA SØRENSEN in this paper provides a generalization of previously proposed batch distillation schemes. A simple feedback been built and the experiments verify the simulations. INTRODUCTION Although batch distillation

  4. Minimum Energy Diagrams for Multieffect Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Minimum Energy Diagrams for Multieffect Distillation Arrangements Hilde K. Engelien and Sigurd distillation arrangements for separating a ternary mixture have been considered. The focus is on a heat-integrated complex distillation configuration, called a multieffect prefractionator arrangement. The comparison

  5. Multivessel Batch Distillation Potential Energy Savings

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Multivessel Batch Distillation ­ Potential Energy Savings Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT ­ A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  6. Multivessel Batch Distillation -Potential Energy Savings

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Multivessel Batch Distillation - Potential Energy Savings Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT - A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  7. New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes

    SciTech Connect (OSTI)

    Agrawal, Rakesh

    2013-11-21T23:59:59.000Z

    This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

  8. Optimal Control of Distillation Systems

    E-Print Network [OSTI]

    Chatterjee, N.; Suchdeo, S. R.

    1984-01-01T23:59:59.000Z

    The optimum performance of a distillation system can be evaluated by examining the product purities, the product recoveries, and the system's capability to respond to small or large, expected or unexpected, plant disturbances. An optimal control...

  9. Momentive Performance Materials Distillation Intercharger

    E-Print Network [OSTI]

    Boucher, N.; Baisley, T.; Beers, C.; Cameron, R.; Holman, K.; Kotkoskie, T.; Norris, K.

    2013-01-01T23:59:59.000Z

    Care? Energy Efficiency Program Momentive Performance Materials Distillation Interchanger ESL-IE-13-05-20 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New Orleans, LA. May 21-24, 2013 Copyright 2013 Momentive Performance... Materials Inc. All rights reserved. CONFIDENTIAL IETC Energy Efficiency Award Winner Distillation Interchanger ? Waterford, NY Agenda ? Momentive Overview ? Waterford, NY Site Overview ? Project Overview ? Project Timeline ? NYSERDA ? Project Team...

  10. Distillation process using microchannel technology

    DOE Patents [OSTI]

    Tonkovich, Anna Lee (Dublin, OH); Simmons, Wayne W. (Dublin, OH); Silva, Laura J. (Dublin, OH); Qiu, Dongming (Carbondale, IL); Perry, Steven T. (Galloway, OH); Yuschak, Thomas (Dublin, OH); Hickey, Thomas P. (Dublin, OH); Arora, Ravi (Dublin, OH); Smith, Amanda (Galloway, OH); Litt, Robert Dwayne (Westerville, OH); Neagle, Paul (Westerville, OH)

    2009-11-03T23:59:59.000Z

    The disclosed invention relates to a distillation process for separating two or more components having different volatilities from a liquid mixture containing the components. The process employs microchannel technology for effecting the distillation and is particularly suitable for conducting difficult separations, such as the separation of ethane from ethylene, wherein the individual components are characterized by having volatilities that are very close to one another.

  11. Quantum universality by state distillation

    E-Print Network [OSTI]

    Ben W. Reichardt

    2009-07-13T23:59:59.000Z

    Quantum universality can be achieved using classically controlled stabilizer operations and repeated preparation of certain ancilla states. Which ancilla states suffice for universality? This "magic states distillation" question is closely related to quantum fault tolerance. Lower bounds on the noise tolerable on the ancilla help give lower bounds on the tolerable noise rate threshold for fault-tolerant computation. Upper bounds show the limits of threshold upper-bound arguments based on the Gottesman-Knill theorem. We extend the range of single-qubit mixed states that are known to give universality, by using a simple parity-checking operation. For applications to proving threshold lower bounds, certain practical stability characteristics are often required, and we also show a stable distillation procedure. No distillation upper bounds are known beyond those given by the Gottesman-Knill theorem. One might ask whether distillation upper bounds reduce to upper bounds for single-qubit ancilla states. For multi-qubit pure states and previously considered two-qubit ancilla states, the answer is yes. However, we exhibit two-qubit mixed states that are not mixtures of stabilizer states, but for which every postselected stabilizer reduction from two qubits to one outputs a mixture of stabilizer states. Distilling such states would require true multi-qubit state distillation methods.

  12. Distillation Column Flooding Predictor

    SciTech Connect (OSTI)

    George E. Dzyacky

    2010-11-23T23:59:59.000Z

    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid/vapor traffic that produce increased contact area and lead to substantial increases in separation efficiency – which translates to a 10% increase in energy efficiency on a BTU/bbl basis. The Flooding Predictor™ operates on the principle that between five to sixty minutes in advance of a flooding event, certain column variables experience an oscillation, a pre-flood pattern. The pattern recognition system of the Flooding Predictor™ utilizes the mathematical first derivative of certain column variables to identify the column’s pre-flood pattern(s). This pattern is a very brief, highly repeatable, simultaneous movement among the derivative values of certain column variables. While all column variables experience negligible random noise generated from the natural frequency of the process, subtle pre-flood patterns are revealed among sub-sets of the derivative values of column variables as the column approaches its hydraulic limit. The sub-set of column variables that comprise the pre-flood pattern is identified empirically through in a two-step process. First, 2ndpoint’s proprietary off-line analysis tool is used to mine historical data for pre-flood patterns. Second, the column is flood-tested to fine-tune the pattern recognition for commissioning. Then the Flooding Predictor™ is implemented as closed-loop advanced control strategy on the plant’s distributed control system (DCS), thus automating control of the column at its hydraulic limit.

  13. Entanglement distillation using particle statistics

    E-Print Network [OSTI]

    H. L. Huang; L. H. Cheng; X. X. Yi

    2005-10-25T23:59:59.000Z

    We extend the idea of entanglement concentration for pure states(Phys. Rev. Lett. {\\bf 88}, 187903) to the case of mixed states. The scheme works only with particle statistics and local operations, without the need of any other interactions. We show that the maximally entangled state can be distilled out when the initial state is pure, otherwise the entanglement of the final state is less than one. The distillation efficiency is a product of the diagonal elements of the initial state, it takes the maximum 50%, the same as the case for pure states.

  14. Distilling entanglement from arbitrary resources

    E-Print Network [OSTI]

    Francesco Buscemi; Nilanjana Datta

    2010-10-15T23:59:59.000Z

    We obtain the general formula for the optimal rate at which singlets can be distilled from any given noisy and arbitrarily correlated entanglement resource, by means of local operations and classical communication (LOCC). Our formula, obtained by employing the quantum information spectrum method, reduces to that derived by Devetak and Winter, in the special case of an i.i.d. resource. The proofs rely on a one-shot version of the so-called "hashing bound," which in turn provides bounds on the one-shot distillable entanglement under general LOCC.

  15. Entanglement distillation by extendible maps

    E-Print Network [OSTI]

    Lukasz Pankowski; Fernando G. S. L. Brandao; Michal Horodecki; Graeme Smith

    2013-08-25T23:59:59.000Z

    It is known that from entangled states that have positive partial transpose it is not possible to distill maximally entangled states by local operations and classical communication (LOCC). A long-standing open question is whether maximally entangled states can be distilled from every state with a non-positive partial transpose. In this paper we study a possible approach to the question consisting of enlarging the class of operations allowed. Namely, instead of LOCC operations we consider k-extendible operations, defined as maps whose Choi-Jamiolkowski state is k-extendible. We find that this class is unexpectedly powerful - e.g. it is capable of distilling EPR pairs even from product states. We also perform numerical studies of distillation of Werner states by those maps, which show that if we raise the extension index k simultaneously with the number of copies of the state, then the class of k-extendible operations is not that powerful anymore and provide a better approximation to the set of LOCC operations.

  16. Corrosion inhibition for distillation apparatus

    DOE Patents [OSTI]

    Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY); Schweighardt, Frank K. (Upper Macungie, PA)

    1985-01-01T23:59:59.000Z

    Tower material corrosion in an atmospheric or sub-atmospheric distillation tower in a coal liquefaction process is reduced or eliminated by subjecting chloride-containing tray contents to an appropriate ion-exchange resin to remove chloride from such tray contents materials.

  17. Process Svstems Enaineerina Instability of Distillation Columns

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Process Svstems Enaineerina , Instability of Distillation Columns Elling W. Jacobsen and Sigurd recognized, distillation columns, operating with reflux and boilup as independent inputs, may have The dynamic behavior of distillation columns has been stud- ied quite extensively over the past decades

  18. POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT ­ A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  19. POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    POTENTIAL ENERGY SAVINGS OF MULTIVESSEL BATCH DISTILLATION Bernd Wittgens and Sigurd Skogestad 1, Norway ABSTRACT - A conventional batch distillation column operated under feedback control applying the proposed policy is compared to the multivessel batch distillation column. In some cases we found

  20. Optimal distillation using thermodynamic geometry Bjarne Andresen

    E-Print Network [OSTI]

    Salamon, Peter

    Optimal distillation using thermodynamic geometry Bjarne Andresen Ørsted Laboratory, University of a distillation column may be improved by permitting heat exchange on every tray rather than only in the reboiler (temperature, pressure, etc.) define successive states in a sequence of equilibria. Fractional distillation [2

  1. Analysis and Control of Heteroazeotropic Batch Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Analysis and Control of Heteroazeotropic Batch Distillation S. Skouras and S. Skogestad Dept.interscience.wiley.com). The separation of close-boiling and azeotropic mixtures by heterogeneous azeotropic distillation is addressed. The results show that heteroazeotropic batch distillation exhibits substantial flexibility. The column profile

  2. Experimental entanglement distillation of mesoscopic quantum states

    E-Print Network [OSTI]

    Loss, Daniel

    LETTERS Experimental entanglement distillation of mesoscopic quantum states RUIFANG DONG1 , MIKAEL, entanglement distillation, a process of extracting a small set of highly entangled states from a large set of less entangled states, can be used4­14 . Here we report on the distillation of deterministically

  3. TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    TOTAL REFLUX OPERATION OF MULTIVESSEL BATCH DISTILLATION BERND WITTGENS, RAJAB LITTO, EVA S RENSEN a generalization of previously proposed batch distillation schemes. A simple feedback control strategy for total re verify the simulations. INTRODUCTION Although batch distillation generally is less energy e cient than

  4. Technical evaluation and assessment of CNG/LPG bi-fuel and flex-fuel vehicle viability

    SciTech Connect (OSTI)

    Sinor, J E [Sinor (J.E.) Consultants, Inc., Niwot, CO (United States)

    1994-05-01T23:59:59.000Z

    This report compares vehicles using compressed natural gas (CNG), liquefied petroleum gas (LPG), and combinations of the two in bi-fuel or flex-fuel configurations. Evidence shows that environmental and energy advantages can be gained by replacing two-fuel CNG/gasoline vehicles with two-fuel or flex-fuel systems to be economically competitive, it is necessary to develop a universal CNG/LPG pressure-regulator-injector and engine control module to switch from one tank to the other. For flex-fuel CNG/LPG designs, appropriate composition sensors, refueling pumps, fuel tanks, and vaporizers are necessary.

  5. Converting LPG caverns to natural-gas storage permits fast response to market

    SciTech Connect (OSTI)

    Crossley, N.G. [TransGas Ltd., Regina, Saskatchewan (Canada)

    1996-02-19T23:59:59.000Z

    Deregulation of Canada`s natural-gas industry in the late 1980s led to a very competitive North American natural-gas storage market. TransGas Ltd., Regina, Sask., began looking for method for developing cost-effective storage while at the same time responding to new market-development opportunities and incentives. Conversion of existing LPG-storage salt caverns to natural-gas storage is one method of providing new storage. To supply SaskEnergy Inc., the province`s local distribution company, and Saskatchewan customers, TransGas previously had developed solution-mined salt storage caverns from start to finish. Two Regina North case histories illustrate TransGas` experiences with conversion of LPG salt caverns to gas storage. This paper provides the testing procedures for the various caverns, cross-sectional diagrams of each cavern, and outlines for cavern conversion. It also lists storage capacities of these caverns.

  6. LIQUID PROPANE GAS (LPG) STORAGE AREA BOILING LIQUID EXPANDING VAPOR EXPLOSION (BLEVE) ANALYSIS

    SciTech Connect (OSTI)

    PACE, M.E.

    2004-01-13T23:59:59.000Z

    The PHA and the FHAs for the SWOC MDSA (HNF-14741) identified multiple accident scenarios in which vehicles powered by flammable gases (e.g., propane), or combustible or flammable liquids (e.g., gasoline, LPG) are involved in accidents that result in an unconfined vapor cloud explosion (UVCE) or in a boiling liquid expanding vapor explosion (BLEVE), respectively. These accident scenarios are binned in the Bridge document as FIR-9 scenarios. They are postulated to occur in any of the MDSA facilities. The LPG storage area will be in the southeast corner of CWC that is relatively remote from store distaged MAR. The location is approximately 30 feet south of MO-289 and 250 feet east of 2401-W by CWC Gate 10 in a large staging area for unused pallets and equipment.

  7. Distillation of Bell states in open systems

    E-Print Network [OSTI]

    E. Isasi; D. Mundarain

    2009-08-14T23:59:59.000Z

    In this work we review the entire classification of 2x2 distillable states for protocols with a finite numbers of copies. We show a distillation protocol that allows to distill Bell states with non zero probability at any time for an initial singlet in vacuum. It is shown that the same protocol used in non zero thermal baths yields a considerable recovering of entanglement.

  8. Heat Exchanger Technologies for Distillation Columns

    E-Print Network [OSTI]

    Polley, G. T.

    Heat Exchanger Technologies for Distillation Columns G.T.Polley Pinchtechnology.com In this paper we look at the challenges that improvements in energy efficiency of distillation systems presents the heat exchanger designer. We examine... condensate sub-cooling. So, if this condensate subsequently requires re-heating both energy and capital have been wasted. If the condensate forms a feed to another distillation column it results in increased energy consumption if that separation...

  9. Reducing Energy Usage in Extractive Distillation

    E-Print Network [OSTI]

    Saxena, A. C.; Bhandari, V. A.

    , .. ~ REDUCING ENERGY USAGE IN,EXTRACTIVE DISTILLATION A. C. Saxena V. A. Bhandari Polysar Limited Sarnia, Ontario, Canada Abstract Butadiene 1:3 is separated from other C. hydrocarbons by extractive distillation in a sieve plate tower.... To improve the energy efficiency, butadiene recovery and productivity of the extractive distillation process, many process changes have been made. Their rationale, the methodology used to implement the various changes, and how they affected the process...

  10. Entanglement distillation from quasifree Fermions

    E-Print Network [OSTI]

    Zoltan Kadar; Michael Keyl; Dirk Schlingemann

    2011-03-24T23:59:59.000Z

    We develop a scheme to distill entanglement from bipartite Fermionic systems in an arbitrary quasifree state. It can be applied if either one system containing infinite one-copy entanglement is available or if an arbitrary amount of equally prepared systems can be used. We show that the efficiency of the proposed scheme is in general very good and in some cases even optimal. Furthermore we apply it to Fermions hopping on an infinite lattice and demonstrate in this context that an efficient numerical analysis is possible for more then 10^6 lattice sites.

  11. CLOSED OPERATION OF MULTIVESSEL BATCH DISTILLATION -EXPERIMENTAL VERIFICATION

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1 CLOSED OPERATION OF MULTIVESSEL BATCH DISTILLATION - EXPERIMENTAL VERIFICATION Submitted to AICheÆcient operation, multicomponent distillation, batch distillation, total re ux operation ABSTRACT. The multivessel batch distillation column, as well as conven- tional batch distillation, may be operated in a closed

  12. Locally Accessible Information and Distillation of Entanglement

    E-Print Network [OSTI]

    Sibasish Ghosh; Pramod Joag; Guruprasad Kar; Samir Kunkri; Anirban Roy

    2004-03-18T23:59:59.000Z

    A new type of complementary relation is found between locally accessible information and final average entanglement for given ensemble. It is also shown that in some well known distillation protocol, this complementary relation is optimally satisfied. We discuss the interesting trade-off between locally accessible information and distillable entanglement for some states.

  13. Rigorous Synthesis and Simulation of Complex Distillation Networks

    E-Print Network [OSTI]

    Linninger, Andreas A.

    Rigorous Synthesis and Simulation of Complex Distillation Networks Gerardo J. Ruiz, Seon B. Kim energy-efficient distillation net- works. Complex column networks have substantial potential for energy column, networks, temperature collocation, inverse design, Aspen validation Introduction Distillation

  14. Shell middle distillate hydrogenation process

    SciTech Connect (OSTI)

    Lucien, J.P. [Companie Rhenane de Raffinage Reichstett, Reichstett Vendenheim (France); Berg, J.P. van den; Hooijdonk, H.M.J.H. van; Thielemans, G.L.B. [Shell Internationale Petroleum Mij., The Hague (Netherlands); Germaine, G. [Shell Recherche SA, Grand-Couronne (France); Gjers, M. [Shell Raffinaderi AB, Gothenburg (Sweden)

    1994-12-31T23:59:59.000Z

    The strive towards cleaner environment has lead to low sulfur specifications for middle distillate fuels. In addition compositional specifications are presently debated. Thus, to meet future emissions standards regarding, specifically, particulates emissions, the motor industry calls for improved automotive gasoil quality. Although automotive gasoil quality affects emissions from diesel engines it is considered less influential than engine design and maintenance. Sulfur, density and cetane number are the fuel properties having the greatest influence on diesel engine emissions although also aromatics and endpoint specifications have been defined in environmentally adopted government initiatives. This paper reviews the options which are available to tackle these new requirements. The high severity single stage concept (using conventional mixed sulfides catalysts) will be discussed in its potential to meet more severe product requirements as well as in terms of its limitations, especially at the point of aromatics saturation and cetaine upgrading. Furthermore, it is shown that the option of severe hydrotreating followed by hydrogenation with conventional noble metal catalysts is preferred if deep aromatics saturation is aimed at. However, this conventional two stage concept has limitations with respect to heaviness and sulfur and nitrogen content of feedstocks. The new Shell Middle Distillate Hydrogenation (SMDH) technology, applying a (semi) two stage approach based on the Shell developed hydrogenation catalyst is presented. The SMDH process will be discussed in its potential to break the limitations of the conventional options. The new catalyst is crucial in this process and allows a highly integrated mode of operation. A number of applications of this novel process will be discussed.

  15. atmospheric crude distillation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

  16. acrobat distiller job: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

  17. advanced distillation curve: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

  18. Pressurized release of liquefied fuel gases (LNG and LPG). Topical report, May 1993-February 1996

    SciTech Connect (OSTI)

    Atallah, S.; Janardhan, A.

    1996-02-01T23:59:59.000Z

    This report is an important contribution to the behavior of pressurized liquefied gases when accidentally released into the atmosphere. LNG vehicle fueling stations and LPG storage facilities operate at elevated pressures. Accidental releases could result in rainout and the formation of an aerosol in the vapor cloud. These factors must be considered when estimating the extent of the hazard zone of the vapor cloud using a heavier-than-air gas dispersion model such as DEGADIS (or its Windows equivalent DEGATEC). The DOS program PREL has been incorporated in the Windows program LFGRISK.

  19. Distillation: Still towering over other options

    SciTech Connect (OSTI)

    Kunesh, J.G. [Fractionation Research, Inc., Stillwater, OK (United States); Kister, H.Z. [Brown and Root, Inc., Alhambra (Canada); Lockett, M.J. [Praxair, Inc., Tonawanda, NY (United States); Fair, J.R. [Univ. of Texas, Austin, TX (United States)

    1995-10-01T23:59:59.000Z

    Distillation dominates separations in the chemical process industries (CPI), at least for mixtures that normally are processed as liquids. The authors fully expect that distillation will continue to be the method of choice for many separations, and the method against which other options must be compared. So, in this article, they will put into some perspective just why distillation continues to reign as the king of separations, and what steps are being taken to improve its applicability and performance, as well as basic understanding of the technique.

  20. Evaluation of aftermarket fuel delivery systems for natural gas and LPG vehicles

    SciTech Connect (OSTI)

    Willson, B. [Colorado State Univ., Fort Collins, CO (United States)

    1992-09-01T23:59:59.000Z

    This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a considerable body of emissions data for converted light-duty vehicles, and a smaller amount for medium- and heavy-duty vehicles. However, very few of these data involve real world conditions, and there is growing concern about in-use emissions. This report also attempts to assess factors that could allow in-use emissions to vary from the ``best-case`` results normally reported. The study also addresses issues of fuel supply, fuel composition, performance, safety, and warranty waivers. The report is based on an extensive literature and product survey and on the author`s experience with fuel delivery systems for light-duty vehicles.

  1. Evaluation of aftermarket fuel delivery systems for natural gas and LPG vehicles

    SciTech Connect (OSTI)

    Willson, B. (Colorado State Univ., Fort Collins, CO (United States))

    1992-09-01T23:59:59.000Z

    This study was designed to evaluate the effectiveness of aftermarket fuel delivery systems for vehicles fueled by compressed natural gas (CNG) and liquefied petroleum gas (LPG). Most of the CNG and LPG vehicles studied were converted to the alternative fuel after purchase. There are wide variations in the quality of the conversion hardware and the installation. This leads to questions about the overall quality of the converted vehicles, in terms of emissions, safety, and performance. There is a considerable body of emissions data for converted light-duty vehicles, and a smaller amount for medium- and heavy-duty vehicles. However, very few of these data involve real world conditions, and there is growing concern about in-use emissions. This report also attempts to assess factors that could allow in-use emissions to vary from the best-case'' results normally reported. The study also addresses issues of fuel supply, fuel composition, performance, safety, and warranty waivers. The report is based on an extensive literature and product survey and on the author's experience with fuel delivery systems for light-duty vehicles.

  2. Minimizing corrosion in coal liquid distillation

    DOE Patents [OSTI]

    Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY)

    1985-01-01T23:59:59.000Z

    In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

  3. Nonlocality Distillation for High-Dimensional System

    E-Print Network [OSTI]

    Pan, Guo-Zhu; Chen, Zheng-Gen; Yang, Ming; Cao, Zhuo-Liang

    2012-01-01T23:59:59.000Z

    The intriguing and powerful capability of nonlocality in communication field ignites the research of the nonlocality distillation. The first protocol presented in Ref[Phys. Rev. Lett. 102, 120401] shows that the nonlocality of bipartite binary-input and binary-output nonsignaling correlated boxes could be amplified by 'wiring' two copies of weaker-nonlocality boxes. Several optimized distillation protocols were presented later for bipartite binary-input and binary-output nonsignaling correlated boxes. In this paper, we focus on the bipartite binary-input and multi-nary-output nonsignaling correlated boxes---high-dimensional boxes, and design comparators-based protocols to achieve the distillation of high-dimensional nonlocality. The results show that the high-dimensional nonlocality can be distilled in different ways, and we find that the efficiencies of the protocols are influenced not only by the wirings but also by the classes the initial nonlocality boxes belongs to. Here, the initial nonlcalities may hav...

  4. Intelligent fuzzy supervisory control for distillation columns

    E-Print Network [OSTI]

    Santhanam, Srinivasan

    1993-01-01T23:59:59.000Z

    problem. Multivariable design techniques are used to control the column. Some of the different multivariable techniques which have been used in the distillation column control include decoupling control, optimal control and internal model control [5...

  5. Advanced Distillation: Programs Proposed to DOE

    E-Print Network [OSTI]

    Woinsky, S. G.

    EPRI has provided proposal preparation assistance and offered cost share funding assistance for two projects proposed in 2000. EPRI is highly interested, since this technology is applicable in all distillation systems, and since it will increase...

  6. An improved model for multiple effect distillation

    E-Print Network [OSTI]

    Mistry, Karan H.

    Increasing global demand for fresh water is driving research and development of advanced desalination technologies. As a result, a detailed model of multiple effect distillation (MED) is developed that is flexible, simple ...

  7. Development of energy efficient membrane distillation systems

    E-Print Network [OSTI]

    Summers, Edward K

    2013-01-01T23:59:59.000Z

    Membrane distillation (MD) has shown potential as a means of desalination and water purification. As a thermally driven membrane technology which runs at relatively low pressure, which can withstand high salinity feed ...

  8. Absorptive Recycle of Distillation Waste Heat 

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01T23:59:59.000Z

    When the heat source available to a distillation process is at a significantly higher temperature than the reboiler temperature, there is unused availability (ability to perform work) in the heat supplied to the reboiler. Similarly, if the reflux...

  9. Complex Fluid Analysis with the Advanced Distillation Curve Approach

    E-Print Network [OSTI]

    Complex Fluid Analysis with the Advanced Distillation Curve Approach Thomas J. Bruno, Lisa S. Ott for measuring distillation curves reveals the physicochemical properties of complex fluids such as fuels distillation curves of complex fluids. The distillation curve provides the only practical avenue to assess

  10. On the Communication Complexity of Correlation and Entanglement Distillation

    E-Print Network [OSTI]

    On the Communication Complexity of Correlation and Entanglement Distillation Ke Yang May 4th, 2004 distillation, entanglement distillation, communication complexity, EPR pairs, quantum key distribution #12) information, and then engage in a protocol to \\distill" the correlation/entanglement via communication. We

  11. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio blog distillation by adding a link analysis phase to the standard retrieval-by-topicality phase, where in blog distillation. 1 Introduction Blog distillation is a subtask of blog search. It is defined

  12. Solar Ethanol Distillation Oara Neumann,1,3

    E-Print Network [OSTI]

    O-9 Solar Ethanol Distillation Oara Neumann,1,3 Albert D. Neumann,2 Julius Müller,1 of separation, particularly distillation. The 40,000 commercial distillation columns in use in the U. S. consume or product purity. Distillation is the critical energy-consuming step accounting for 70-85% of the energy

  13. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA SØRENSEN 3 and RAJAB distillation schemes. A simple feedback control strategy for the total reflux operation of a multivessel column distillation generally is less energy efficient than continuous distillation, it has received increased

  14. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA S RENSEN 3 and RAJAB distillation schemes. A simple feedback control strategy for the total re ux operation of a multivessel column distillation generally is less energy e cient than continuous distillation, it has received increased attention

  15. Multipartite secret key distillation and bound entanglement

    E-Print Network [OSTI]

    Remigiusz Augusiak; Pawel Horodecki

    2009-09-25T23:59:59.000Z

    Recently it has been shown that quantum cryptography beyond pure entanglement distillation is possible and a paradigm for the associated protocols has been established. Here we systematically generalize the whole paradigm to the multipartite scenario. We provide constructions of new classes of multipartite bound entangled states, i.e., those with underlying twisted GHZ structure and nonzero distillable cryptographic key. We quantitatively estimate the key from below with help of the privacy squeezing technique.

  16. Multipartite secret key distillation and bound entanglement

    SciTech Connect (OSTI)

    Augusiak, Remigiusz; Horodecki, Pawel [Faculty of Applied Physics and Mathematics, Gdansk University of Technology, Narutowicza 11/12, 80-952 Gdansk (Poland) and ICFO-Institute Ciencies Fotoniques, Mediterranean Technology Park, 08860 Castelldefels (Barcelona) (Spain); Faculty of Applied Physics and Mathematics, Gdansk University of Technology, Narutowicza 11/12, 80-952 Gdansk (Poland)

    2009-10-15T23:59:59.000Z

    Recently it has been shown that quantum cryptography beyond pure entanglement distillation is possible and a paradigm for the associated protocols has been established. Here we systematically generalize the whole paradigm to the multipartite scenario. We provide constructions of new classes of multipartite bound entangled states, i.e., those with underlying twisted Greenberger-Horne-Zeilinger (GHZ) structure and nonzero distillable cryptographic key. We quantitatively estimate the key from below with the help of the privacy squeezing technique.

  17. Absorptive Recycle of Distillation Waste Heat

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01T23:59:59.000Z

    ABSORPTIVE RECYCLE OF DISTILLATION WASTE HEAT Donald C. Erickson and Edward J. Lutz Jr. Energy Concepts Company Annapolis, Maryland ABSTRACT When the heat source available to a distillation process is at a significantly higher temperature... which conserve 60 to 70%. Also, there are ver sions which incorporate separate low tem perature waste heat streams and thereby conserve over 90% of the required dis tillation energy. The main limitations of the R/AHP are the need for sufficient...

  18. Investigation on effects of surface morphologies on response of LPG sensor based on nanostructured copper ferrite system

    SciTech Connect (OSTI)

    Singh, Satyendra [Nanomaterials and Sensors Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, U.P. (India)] [Nanomaterials and Sensors Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, U.P. (India); Yadav, B.C., E-mail: balchandra_yadav@rediffmail.com [Nanomaterials and Sensors Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, U.P. (India); Department of Applied Physics, School for Physical Sciences, Babasaheb Bhimrao Ambedkar University, Lucknow 226025, U.P. (India); Gupta, V.D. [Nanomaterials and Sensors Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, U.P. (India)] [Nanomaterials and Sensors Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, U.P. (India); Dwivedi, Prabhat K. [DST Unit on Nanosciences, Department of Chemical Engineering, Indian Institute of Technology Kanpur, Kanpur, U.P. (India)] [DST Unit on Nanosciences, Department of Chemical Engineering, Indian Institute of Technology Kanpur, Kanpur, U.P. (India)

    2012-11-15T23:59:59.000Z

    Graphical abstract: Figure shows the variations in resistance with time for copper ferrite system synthesized in various molar ratio. A maximum variation in resistance was observed for copper ferrite prepared in 1:1 molar ratio. Highlights: ? Evaluation of structural, optical and surface morphologies. ? Significant variation in LPG sensing properties. ? Surface modification of ferric oxide pellet by copper ferrite. ? CuFe{sub 2}O{sub 4} pellets for LPG sensing at room temperature. -- Abstract: Synthesis of a copper ferrite system (CuFe{sub 2}O{sub 4}) via chemical co-precipitation method is characterized by X-ray diffraction, surface morphology (scanning electron microscope) and optical absorption spectroscopy. These characteristics show their dependence on the relative compositions of the two subsystems. They are further confirmed by the variation in the band gap. A study of gas sensing properties shows the spinel CuFe{sub 2}O{sub 4} synthesized in 1:1 molar ratio exhibit best response to LPG adsorption/resistance measurement. Thus resistance based LPG sensor is found robust, cheap and may be applied for kitchens and industrial applications.

  19. An evaluation of the potential end uses of a Utah tar sand bitumen. [Tar sand distillate

    SciTech Connect (OSTI)

    Thomas, K.P.; Harnsberger, P.M.; Guffey, F.D.

    1986-09-01T23:59:59.000Z

    To date the commercial application of tar sand deposits in the United States has been limited to their use as paving materials for county roads, parking lots, and driveways because the material, as obtained from the quarries, does not meet federal highway specifications. The bitumen in these deposits has also been the subject of upgrading and refining studies to produce transportation fuels, but the results have not been encouraging from an economic standpoint. The conversion of tar sand bitumen to transportation fuels cannot compete with crude oil refining. The purposes of this study were two-fold. The first was to produce vacuum distillation residues and determine if their properties met ASTM asphalt specifications. The second was to determine if the distillates could serve as potential feedstocks for the production of aviation turbine fuels. The bitumen used for this study was the oil produced during an in situ steamflood project at the Northwest Asphalt Ridge (Utah) tar sand deposit. Two distillation residues were produced, one at +316/sup 0/C and one at +399/sup 0/C. However, only the lower boiling residue met ASTM specifications, in this case as an AC-30 asphalt. The original oil sample met specifications as an AC-5 asphalt. These residue samples showed some unique properties in the area of aging; however, these properties need to be investigated further to determine the implications. It was also suggested that the low aging indexes and high flow properties of the asphalts may be beneficial for pavements that require good low-temperature performance. Two distillate samples were produced, one at IBP-316/sup 0/C and one at IBP-399/sup 0/C. The chemical and physical properties of these samples were determined, and it was concluded that both samples appear to be potential feedstocks for the production of aviation turbine fuels. However, hydrogenation studies need to be conducted and the properties of the finished fuels determined to verify the prediction. 14 refs., 12 tabs.

  20. Local purity distillation with bounded classical communication

    E-Print Network [OSTI]

    Hari Krovi; Igor Devetak

    2007-05-28T23:59:59.000Z

    Local pure states are an important resource for quantum computing. The problem of distilling local pure states from mixed ones can be cast in an information theoretic paradigm. The bipartite version of this problem where local purity must be distilled from an arbitrary quantum state shared between two parties, Alice and Bob, is closely related to the problem of separating quantum and classical correlations in the state and in particular, to a measure of classical correlations called the one-way distillable common randomness. In Phys. Rev. A 71, 062303 (2005), the optimal rate of local purity distillation is derived when many copies of a bipartite quantum state are shared between Alice and Bob, and the parties are allowed unlimited use of a unidirectional dephasing channel. In the present paper, we extend this result to the setting in which the use of the channel is bounded. We demonstrate that in the case of a classical-quantum system, the expression for the local purity distilled is efficiently computable and provide examples with their tradeoff curves.

  1. Energy Saving in Distillation Using Structured Packing and Vapor Recompression

    E-Print Network [OSTI]

    Hill, J.H.

    "Distillation is a big consumer of energy in process plant operations. A first step to energy cost savings is the use of high efficiency structured packing in place of trays or dumped packings in conventionally operated distillation columns. Larger...

  2. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) Geographic Area Month Kerosene No. 1 Distillate No. 2...

  3. Desalination Using Vapor-Compression Distillation

    E-Print Network [OSTI]

    Lubis, Mirna R.

    2010-07-14T23:59:59.000Z

    the outgoing salt concentration was 1.5% and 7%, respectively. Distillation was performed at 439 K (331oF) and 722 kPa (105 psia) for both brackish water feed and seawater feed. Water costs of the various conditions were calculated for brackish water...

  4. Distillation: Present Status and Future Directions

    E-Print Network [OSTI]

    Fair, J. R.; Humphrey, J. L.

    1984-01-01T23:59:59.000Z

    -pressure steam as a heat source. The steam has, very likely, been sent through one or more users (turbi ne dri ves) before reaching the distillation reboiler. It seems almost characteristic of large chemical and refining complexes that there is a chronic...

  5. Complex Distillation Arrangements : Extending the Petlyuk Ideas

    E-Print Network [OSTI]

    Skogestad, Sigurd

    to distillation columns ac- count for roughly 3 of the total energy consumption in the U.S. (Ognisty 1995 to reduce energy consumption at least two alternative approaches have been proposed both in the literature is also known as the Petlyuk column, due to a theoretical study of Pet- lyuk et al. (1965), or as a fully

  6. Forpeerreview Synthesis of Complex Thermally Coupled Distillation

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    consumption of 91 GW, or 54 million tons of crude oil. The distillation research is motivated by its major US energy consumption, which is equivalent to 2.87x10 18 J (2.87 million TJ) per year, or to a power

  7. Energy Conservation Options in Distillation Processes 

    E-Print Network [OSTI]

    Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

    1980-01-01T23:59:59.000Z

    I ENERGY CONSERVATION OPTIONS IN DISTILLATION PROCESSES G.E. Harris, W.R. Hearn, G.M. Blythe, and J.M. Stuart, Radian Corporation, Austin, Texas I This paper summarizes the results of a survey of energy conservation options applicable...

  8. Synthesis and design of optimal thermal membrane distillation networks 

    E-Print Network [OSTI]

    Nyapathi Seshu, Madhav

    2006-10-30T23:59:59.000Z

    of oil. An overview of Direct Contact Membrane Distillation (DCMD) reports the narrow range of applications of membrane distillation in the industry, such as desalination and water purification (Burgoyne and Vahdati, 2000; Cath et al., 2004). Gryta... crystalliser and air gap membrane distillation as a solution to geothermal water desalination. Desalination 152 (1-3), 237-244. Burgoyne, A, Vahdati, M.M. 2000. Direct contact membrane distillation.Separation Science and Technology 35 (8), 1257...

  9. Distilling one-qubit magic states into Toffoli states

    E-Print Network [OSTI]

    Bryan Eastin

    2013-02-21T23:59:59.000Z

    For certain quantum architectures and algorithms, most of the required resources are consumed during the distillation of one-qubit magic states for use in performing Toffoli gates. I show that the overhead for magic-state distillation can be reduced by merging distillation with the implementation of Toffoli gates. The resulting routine distills 8 one-qubit magic states directly to a Toffoli state, which can be used without further magic to perform a Toffoli gate.

  10. Nonresidential buildings energy consumption survey: 1979 consumption and expenditures. Part 2. Steam, fuel oil, LPG, and all fuels

    SciTech Connect (OSTI)

    Patinkin, L.

    1983-12-01T23:59:59.000Z

    This report presents data on square footage and on total energy consumption and expenditures for commercial buildings in the contiguous United States. Also included are detailed consumption and expenditures tables for fuel oil or kerosene, liquid petroleum gas (LPG), and purchased steam. Commercial buildings include all nonresidential buildings with the exception of those where industrial activities occupy more of the total square footage than any other type of activity. 7 figures, 23 tables.

  11. Integrated C3 Feedstock and Aggregated Distillation Model for

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Polypropylene Propane return Reactor effluent Distillation Polymerization FeedTank Propylene (91%) Goal: Select rates Constraints on composition of Propane Return, Distillation Overhead & Reactor Feed Limits Distillation Model Relates overhead composition of propane with flowrate of propane feed to the splitter

  12. Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens,

    E-Print Network [OSTI]

    to infinity. We call such protocols asymp- totic and the fraction of distilled Bell states per initial copy#12;#12;Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens, Jeroen: July 13, 2006) We present a new asymptotic bipartite entanglement distillation protocol

  13. Optimal Control of a Continuous Distillation Process under Probabilistic Constraints

    E-Print Network [OSTI]

    Henrion, René

    Optimal Control of a Continuous Distillation Process under Probabilistic Constraints René Henrion1 Universität Berlin, Germany Abstract A continuous distillation process with random inflow rate is considered model including the dynamics of the distillation process and proba- bilistic constraints under different

  14. Bloggers as Experts Feed Distillation using Expert Retrieval Models

    E-Print Network [OSTI]

    de Rijke, Maarten

    Bloggers as Experts Feed Distillation using Expert Retrieval Models Krisztian Balog kbalog Kruislaan 403, 1098 SJ Amsterdam ABSTRACT We address the task of (blog) feed distillation: to find blogs- ness as feed distillation strategies. The two models capture the idea that a human will often search

  15. DYNAMICS AND CONTROL OF DISTILLATION COLUMNS A CRITICAL SURVEY

    E-Print Network [OSTI]

    Skogestad, Sigurd

    DYNAMICS AND CONTROL OF DISTILLATION COLUMNS ­ A CRITICAL SURVEY Sigurd Skogestad \\Lambda Chemical, Identification and Control, 18, 177­217, 1997. Abstract Distillation column dynamics and control has been viewed these, the feasibility of using the distillate­bottom structure for control (which was believed

  16. CHEM333: Experiment 4: Steam Distillation of Essential Oils;

    E-Print Network [OSTI]

    Taber, Douglass

    CHEM­333: Experiment 4: Steam Distillation of Essential Oils; Experiments A, C, D and below. Reading: For this experiment read Chapter 10. This week you will get to use steam distillation to isolate may wait until you come to lab to find out which spice you get. Steam distillation is not a common

  17. DYNAMICS AND CONTROL OF DISTILLATION COLUMNS -A CRITICAL SURVEY

    E-Print Network [OSTI]

    Skogestad, Sigurd

    DYNAMICS AND CONTROL OF DISTILLATION COLUMNS - A CRITICAL SURVEY Sigurd Skogestad Chemical cation and Control, 18, 177-217, 1997. Abstract Distillation column dynamics and control has been viewed, the feasibility of using the distillate-bottomstructure for control which was believed to be impossible

  18. Column Initialization 1 Initializing Distillation Column Models 1

    E-Print Network [OSTI]

    Dundee, University of

    Column Initialization 1 Initializing Distillation Column Models 1 Roger Fletcher \\Lambda with the optimisation of distillation column models by non­ linear programming are considered. The paper presents of the distillation column model. A certain limiting case of the column model is examined, that of infinite reflux

  19. Energy efficient distillation Ivar J. Halvorsen a,*, Sigurd Skogestad b

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Energy efficient distillation Ivar J. Halvorsen a,*, Sigurd Skogestad b a SINTEF ICT, Applied Keywords: Distillation Minimum energy Energy saving Dividing wall column Petlyuk arrangement Vmin-diagram a b s t r a c t Distillation is responsible for a significant amount of the energy consumption

  20. Many copies may be required for entanglement distillation John Watrous

    E-Print Network [OSTI]

    Watrous, John

    Many copies may be required for entanglement distillation John Watrous Department of Computer state shared between two parties is said to be distillable if, by means of a protocol involving only |+ = (|00 + |11 )/ 2. In this paper it is proved that there exist states that are distillable

  1. Active constraint regions for optimal operation of distillation columns

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Active constraint regions for optimal operation of distillation columns Magnus G. Jacobsen the control structure of distillation columns, with optimal operation in mind, it is important to know how for distillation columns change with variations in energy cost and feed flow rate. The production of the most

  2. Multiple copy distillation and purification of phase diffused squeezed states

    E-Print Network [OSTI]

    Petr Marek; Jaromir Fiurasek; Boris Hage; Alexander Franzen; James DiGugliemo; Roman Schnabel

    2007-11-16T23:59:59.000Z

    We provide a detailed theoretical analysis of multiple copy purification and distillation protocols for phase diffused squeezed states of light. The standard iterative distillation protocol is generalized to a collective purification of an arbitrary number of N copies. We also derive a semi-analytical expression for the asymptotic limit of the iterative distillation and purification protocol and discuss its properties.

  3. CHEM333: Lab Experiment 3: Distillation and Gas Chromatography

    E-Print Network [OSTI]

    Taber, Douglass

    CHEM­333: Lab Experiment 3: Distillation and Gas Chromatography: Prelab-Assignment: read Chapters 5 and 6. Distillation is one of the most powerful techniques for purifying volatile organic compounds. Distillation is used to isolate many of life's essentials such as gasoline from oil or brandy from wine

  4. Blog Distillation via Sentiment-Sensitive Link Analysis

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Blog Distillation via Sentiment-Sensitive Link Analysis Giacomo Berardi, Andrea Esuli, Fabrizio report a new approach to blog distillation, defined as the task in which, given a user query, the system of the TREC Blog Track. 1 Introduction Blog distillation is a subtask of the blog search task. It is defined

  5. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA S RENSEN 3 and RAJAB distillation schemes, including the inverted column and the middle vessel column. The total re ux operation of the multivessel batch distillation column was presented recently, and the main contribution of this paper

  6. Analysis of Closed Multivessel Batch Distillation of Ternary Azeotropic Mixtures

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Analysis of Closed Multivessel Batch Distillation of Ternary Azeotropic Mixtures using Elementary) diagrams like distillation lines and isotherms maps may be used in analysis of the closed (total reflux) multivessel batch distillation column. An indirect level control strategy is implemented that eliminates

  7. Azeotropic Distillation as a Technique for Emulsion Size Reduction

    E-Print Network [OSTI]

    Petta, Jason

    Azeotropic Distillation as a Technique for Emulsion Size Reduction Taylor Emanuelle Sweet 2013 Prism/PCCM #12;Overview -Intro- What is Microfluidics? What is Heterogeneous Azeotropic Distillation microns in size and use Binary Heterogeneous Azeotropic Distillation to shrink droplets to 5-10 microns

  8. Model Predictive Control of a Kaibel Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Model Predictive Control of a Kaibel Distillation Column Martin Kvernland Ivar Halvorsen Sigurd (e-mail: skoge@ntnu.no) Abstract: This is a simulation study on controlling a Kaibel distillation column with model predictive control (MPC). A Kaibel distillation column has several advantages compared

  9. Multiple Steady States in Ideal Two-Product Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Multiple Steady States in Ideal Two-Product Distillation Elling W. Jacobsen and Sigurd Skogestad Chemical Engineering Dept., University of Trondheim-NTH, N-7034 Trondheim, Norway Simple distillation and compositions in the column. Introduction Multiple steady states (multiplicity) in distillation columns have

  10. Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S, Norway SCOPE OF THE PROJECT ·How can we separate ternary mixtures in closed batch distillation-up period is required, followed by a heteroazeotropic distillation step (Figure 3) Modified: The separation

  11. Effect of Number of Fractionating Trays on Reactive Distillation Performance

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

  12. MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS,

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION 1 SIGURD SKOGESTAD 2 , BERND WITTGENS, EVA SØRENSEN 3 and RAJAB distillation schemes, including the inverted column and the middle vessel column. The total reflux operation of the multivessel batch distillation column was presented recently, and the main contribution of this paper

  13. RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT

    E-Print Network [OSTI]

    RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT J. R. Taylor**, 0. Hansen*, C. Jensen*, 0. F. A risk analysis of a batch distillation unit is de- scribed. The analysis has been carried out at several.2. Objectives and organisation 5 1.2.2. Philosophy and approach 6 1.3.1. The distillation unit 8 1

  14. Solar thermal powered desalination: membrane versus distillation technologies

    E-Print Network [OSTI]

    Solar thermal powered desalination: membrane versus distillation technologies G. Burgess and K Canberra ACT 0200 AUSTRALIA E-mail: greg.burgess@anu.edu.au Multiple Effect Distillation (MED) is generally assisted) desalination has been conducted. Solar thermal driven Multiple Effect Distillation (MED) has been

  15. Human versus Machine in the Topic Distillation Task Mingfang Wu

    E-Print Network [OSTI]

    Wu, Mingfang

    Human versus Machine in the Topic Distillation Task Mingfang Wu 1 , Gheorghe Muresan2 , Alistair Mc. The focus is on comparing humans and machine algorithms in terms of performance in a topic distillation task demonstrated that machines can perform nearly as well as people on the topic distillation task. Given a system

  16. Economically Optimal Control of Kaibel Distillation Column: Fixed boilup rate

    E-Print Network [OSTI]

    Skogestad, Sigurd

    : In this study, a control structure is designed for a 4-product dividing wall (Kaibel) distillation column, basedEconomically Optimal Control of Kaibel Distillation Column: Fixed boilup rate Maryam Ghadrdan distillation column; Vapour split manipulation; Self-optimizing control. 1. INTRODUCTION Thermally coupled

  17. Optimal Synthesis of Complex Distillation ColumnsUsing Rigorous Models

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    a review of recent work for the optimal design of distillation of individual columns using tray review of the area of optimal design and synthesis of distillation columns, emphasizing recentOptimal Synthesis of Complex Distillation ColumnsUsing Rigorous Models Ignacio E. Grossmann1 , Pío

  18. THE DOS AND DONTS OF DISTILLATION COLUMN CONTROL

    E-Print Network [OSTI]

    Skogestad, Sigurd

    THE DOS AND DON·TS OF DISTILLATION COLUMN CONTROL S. Skogestadà Department of Chemical Engineering distillation column control within the general framework of plant- wide control. In addition, it aims at providing simple recommendations to assist the engineer in designing control systems for distillation

  19. Secret key distillation from shielded two-qubit states

    E-Print Network [OSTI]

    Joonwoo Bae

    2010-09-22T23:59:59.000Z

    The quantum states corresponding to a secret key are characterized using the so-called private states, where the key part consisting of a secret key is shielded by the additional systems. Based on the construction, it was shown that a secret key can be distilled from bound entangled states. In this work, I consider the shielded two-qubit states in a key-distillation scenario and derive the conditions under which a secret key can be distilled using the recurrence protocol or the two-way classical distillation, advantage distillation together with one-way postprocessing. From the security conditions, it is shown that a secret key can be distilled from bound entangled states in a much wider range. In addition, I consider the case that in which white noise is added to quantum states and show that the classical distillation protocol still works despite a certain amount of noise although the recurrence protocol does not.

  20. Qutrit Magic State Distillation Tight in Some Directions

    E-Print Network [OSTI]

    Hillary Dawkins; Mark Howard

    2015-04-22T23:59:59.000Z

    Magic state distillation is a crucial component in the leading approaches to implementing universal fault tolerant quantum computation, with existing protocols for both qubit and higher dimensional systems. Early work focused on determining the region of distillable states for qubit protocols, yet comparatively little is known about which states can be distilled and with what distillable region for d>2. Here we focus on d=3 and present new four-qutrit distillation schemes that improve upon the known distillable region, and achieve distillation tight to the boundary of undistillable states for some classes of state. As a consequence of recent results, this implies that there is a family of quantum states that enable universality if and only if they exhibit contextuality with respect to stabilizer measurements. We also identify a new routine whose fixed point is a magic state with maximal sum-negativity i.e., it is maximally non-stabilizer in a specific sense.

  1. Secret key distillation from shielded two-qubit states

    SciTech Connect (OSTI)

    Bae, Joonwoo [School of Computational Sciences, Korea Institute for Advanced Study, Seoul 130-722 (Korea, Republic of)

    2010-05-15T23:59:59.000Z

    The quantum states corresponding to a secret key are characterized using the so-called private states, where the key part consisting of a secret key is shielded by the additional systems. Based on the construction, it was shown that a secret key can be distilled from bound entangled states. In this work, I consider the shielded two-qubit states in a key-distillation scenario and derive the conditions under which a secret key can be distilled using the recurrence protocol or the two-way classical distillation, advantage distillation together with one-way postprocessing. From the security conditions, it is shown that a secret key can be distilled from bound entangled states in a much wider range. In addition, I consider the case that in which white noise is added to quantum states and show that the classical distillation protocol still works despite a certain amount of noise although the recurrence protocol does not.

  2. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1984-03-27T23:59:59.000Z

    A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  3. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1985-08-20T23:59:59.000Z

    A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  4. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1984-01-01T23:59:59.000Z

    A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  5. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1985-01-01T23:59:59.000Z

    A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  6. The attractor mechanism as a distillation procedure

    E-Print Network [OSTI]

    Péter Lévay; Szilárd Szalay

    2010-04-14T23:59:59.000Z

    In a recent paper it has been shown that for double extremal static spherically symmetric BPS black hole solutions in the STU model the well-known process of moduli stabilization at the horizon can be recast in a form of a distillation procedure of a three-qubit entangled state of GHZ-type. By studying the full flow in moduli space in this paper we investigate this distillation procedure in more detail. We introduce a three-qubit state with amplitudes depending on the conserved charges the warp factor, and the moduli. We show that for the recently discovered non-BPS solutions it is possible to see how the distillation procedure unfolds itself as we approach the horizon. For the non-BPS seed solutions at the asymptotically Minkowski region we are starting with a three-qubit state having seven nonequal nonvanishing amplitudes and finally at the horizon we get a GHZ state with merely four nonvanishing ones with equal magnitudes. The magnitude of the surviving nonvanishing amplitudes is proportional to the macroscopic black hole entropy. A systematic study of such attractor states shows that their properties reflect the structure of the fake superpotential. We also demonstrate that when starting with the very special values for the moduli corresponding to flat directions the uniform structure at the horizon deteriorates due to errors generalizing the usual bit flips acting on the qubits of the attractor states.

  7. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14T23:59:59.000Z

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  8. Surface code implementation of block code state distillation

    E-Print Network [OSTI]

    Austin G. Fowler; Simon J. Devitt; Cody Jones

    2013-01-29T23:59:59.000Z

    State distillation is the process of taking a number of imperfect copies of a particular quantum state and producing fewer better copies. Until recently, the lowest overhead method of distilling states |A>=(|0>+e^{i\\pi/4}|1>)/\\sqrt{2} produced a single improved |A> state given 15 input copies. New block code state distillation methods can produce k improved |A> states given 3k+8 input copies, potentially significantly reducing the overhead associated with state distillation. We construct an explicit surface code implementation of block code state distillation and quantitatively compare the overhead of this approach to the old. We find that, using the best available techniques, for parameters of practical interest, block code state distillation does not always lead to lower overhead, and, when it does, the overhead reduction is typically less than a factor of three.

  9. Iterative Entanglement Distillation: Approaching full Elimination of Decoherence

    E-Print Network [OSTI]

    Boris Hage; Aiko Samblowski; James DiGuglielmo; Jaromír Fiurášek; Roman Schnabel

    2010-07-09T23:59:59.000Z

    The distribution and processing of quantum entanglement form the basis of quantum communication and quantum computing. The realization of the two is difficult because quantum information inherently has a high susceptibility to decoherence, i.e. to uncontrollable information loss to the environment. For entanglement distribution, a proposed solution to this problem is capable of fully eliminating decoherence; namely iterative entanglement distillation. This approach builds on a large number of distillation steps each of which extracts a number of weakly decohered entangled states from a larger number of strongly decohered states. Here, for the first time, we experimentally demonstrate iterative distillation of entanglement. Already distilled entangled states were further improved in a second distillation step and also made available for subsequent steps.Our experiment displays the realization of the building blocks required for an entanglement distillation scheme that can fully eliminate decoherence.

  10. W-like bound entangled states and secure key distillation

    E-Print Network [OSTI]

    Remigiusz Augusiak; Pawel Horodecki

    2009-09-09T23:59:59.000Z

    We construct multipartite entangled states with underlying W-type structure satisfying positive partial transpose (PPT) condition under any (N-1)|1 partition. Then we show how to distill N-partite secure key form the states using two different methods: direct application of local filtering and novel random key distillation scheme in which we adopt the idea form recent results on entanglement distillation. Open problems and possible implications are also discussed.

  11. Quantum states representing perfectly secure bits are always distillable

    E-Print Network [OSTI]

    Pawel Horodecki; Remigiusz Augusiak

    2007-11-06T23:59:59.000Z

    It is proven that recently introduced states with perfectly secure bits of cryptographic key (private states representing secure bit) [K. Horodecki et al., Phys. Rev. Lett. 94, 160502 (2005)] as well as its multipartite and higher dimension generalizations always represent distillable entanglement. The corresponding lower bounds on distillable entanglement are provided. We also present a simple alternative proof that for any bipartite quantum state entanglement cost is an upper bound on distillable cryptographic key in bipartite scenario.

  12. Fusion Residues

    E-Print Network [OSTI]

    Kenneth Intriligator

    1991-08-19T23:59:59.000Z

    We discuss when and how the Verlinde dimensions of a rational conformal field theory can be expressed as correlation functions in a topological LG theory. It is seen that a necessary condition is that the RCFT fusion rules must exhibit an extra symmetry. We consider two particular perturbations of the Grassmannian superpotentials. The topological LG residues in one perturbation, introduced by Gepner, are shown to be a twisted version of the $SU(N)_k$ Verlinde dimensions. The residues in the other perturbation are the twisted Verlinde dimensions of another RCFT; these topological LG correlation functions are conjectured to be the correlation functions of the corresponding Grassmannian topological sigma model with a coupling in the action to instanton number.

  13. Energy Conservation Options in Distillation Processes

    E-Print Network [OSTI]

    Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

    1980-01-01T23:59:59.000Z

    ~itroo.? ':!OD.e~tell.,..ot!.k1 .'k..,.-.ottNltlu'..,. II ""'I'JI ..... ~I_ """-.4008l1"OO I ~.z.,. 1 ,1'1 (-frl-.'....u_~ R.da at AC~Ofllftl\\,J'ftlit...." ? I 5 "'-tlnc&! Tt.,.. ? 21.' \\lip Gilil.In31 j TnyE.'tIc>Mcy .11.1'llo I ~~TI""'.'2.at... I There are many options available to the engi*eer seeking to reduce the energy requirements of a distil lation process. The technology for most of these I, options has been available for many years, but it has only recently become economically...

  14. Use of computers for multicomponent distillation calculations

    E-Print Network [OSTI]

    Sullivan, Samuel Lane

    1959-01-01T23:59:59.000Z

    The corrected values for the b 's are best cal- i culated by multiplying (b. /d ) by (d. ) The compositions for each component in the vapor and liquid streams leaving plate j are calculated by use of the following equations. ('i/ i)ca ( i)co y. ji c Z (v... . . /b. ) (b. ) ji i ca i co i=1 , f a j x N+1 C (47-b) A temperature profile may be calculated by making either bubble or dew point calculations based on the compositions obtained by use of Equations (46) and (47). The specified distillate rate must...

  15. New Design Methods and Algorithms for Multi-component Distillation...

    Broader source: Energy.gov (indexed) [DOE]

    CX-100137 Categorical Exclusion Determination ITP Chemicals: Hybripd SeparationsDistillation Technology. Research Opportunities for Energy and Emissions Reduction ITP Energy...

  16. Integrated Thermal and Hydraulic Analysis of Distillation Columns

    E-Print Network [OSTI]

    Samant, K.; Sinclair, I.; Keady, G.

    . The paper outlines how bringing together the column thermal and hydraulics analysis provides significant additional insights to help screen the options for distillation column revamps....

  17. Local Gaussian operations can enhance continuous-variable entanglement distillation

    E-Print Network [OSTI]

    ShengLi Zhang; Peter van Loock

    2011-03-23T23:59:59.000Z

    Entanglement distillation is a fundamental building block in long-distance quantum communication. Though known to be useless on their own for distilling Gaussian entangled states, local Gaussian operations may still help to improve non-Gaussian entanglement distillation schemes. Here we show that by applying local squeezing operations, both the performance and the efficiency of existing distillation protocols can be enhanced. We derive the optimal enhancement through local Gaussian unitaries, which can be obtained even in the most natural scenario when Gaussian mixed entangled states are shared after their distribution through a lossy-fiber communication channel.

  18. advanced distillation control: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Morari California.Eng., Norwegian Institute of Technology (NTH), N-7034 Trondheim, Norway Paper presented at Symposium Distillation Skogestad, Sigurd 14 CONTROL AND ENERGY...

  19. azeotropic distillation columns: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S, Norway SCOPE OF THE PROJECT How can we separate ternary mixtures in closed batch...

  20. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1998 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  1. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  2. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1996 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  3. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1997 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  4. NONLINEAR MPC BASED ON MULTI-MODEL FOR DISTILLATION COLUMNS

    E-Print Network [OSTI]

    Foss, Bjarne A.

    NONLINEAR MPC BASED ON MULTI-MODEL FOR DISTILLATION COLUMNS Bjarne A. Foss1 , Song-Bo Cong established for a petroleum distillation column through first principle analysis, and its parameters have been-estimation and prediction in a MPC scheme. The controller has been applied to quality control of a FCCU fractionator

  5. A Decision Mechanism for the Selective Combination of Evidence in Topic Distillation

    E-Print Network [OSTI]

    Jose, Joemon M.

    A Decision Mechanism for the Selective Combination of Evidence in Topic Distillation Vassilis combination of evidence for Web Information Retrieval and particularly for topic distillation. We introduce. Keywords Web information retrieval, Topic distillation, decision mechanism, selective combination

  6. Temperature Collocation Algorithm for Fast and Robust Distillation Libin Zhang and Andreas A. Linninger*

    E-Print Network [OSTI]

    Linninger, Andreas A.

    Temperature Collocation Algorithm for Fast and Robust Distillation Design Libin Zhang and Andreas A mixtures that exhibit suitable volatility differences.1 Hence, continuous distillation columns, along commodity manufacturing. The common practice for distillation design often involves numerous trial

  7. Non-Gaussian entanglement distillation for continuous variables

    E-Print Network [OSTI]

    Hiroki Takahashi; Jonas S. Neergaard-Nielsen; Makoto Takeuchi; Masahiro Takeoka; Kazuhiro Hayasaka; Akira Furusawa; Masahide Sasaki

    2009-07-13T23:59:59.000Z

    Entanglement distillation is an essential ingredient for long distance quantum communications. In the continuous variable setting, Gaussian states play major roles in quantum teleportation, quantum cloning and quantum cryptography. However, entanglement distillation from Gaussian states has not yet been demonstrated. It is made difficult by the no-go theorem stating that no Gaussian operation can distill Gaussian states. Here we demonstrate the entanglement distillation from Gaussian states by using measurement-induced non-Gaussian operations, circumventing the fundamental restriction of the no-go theorem. We observed a gain of entanglement as a result of conditional local subtraction of a single photon or two photons from a two-mode Gaussian state. Furthermore we confirmed that two-photon subtraction also improves Gaussian-like entanglement as specified by the Einstein-Podolsky-Rosen (EPR) correlation. This distilled entanglement can be further employed to downstream applications such as high fidelity quantum teleportation and a loophole-free Bell test.

  8. Cr-free Fe-based metal oxide catalysts for high temperature water gas shift reaction of fuel processor using LPG

    SciTech Connect (OSTI)

    lee, Joon Y.; Lee, Dae-Won; Lee, Kwan Young; Wang, Yong

    2009-08-15T23:59:59.000Z

    The goal of this study was to identify the most suitable chromium-free iron-based catalysts for the HTS (high temperature shift) reaction of a fuel processor using LPG. Hexavalent chromium (Cr6+) in the commercial HTS catalyst has been regarded as hazardous material. We selected Ni and Co as the substitution for chromium in the Fe-based HTS catalyst and investigated the HTS activities of these Crfree catalysts at LPG reformate condition. Cr-free Fe-based catalysts which contain Ni, Zn, or Co instead of Cr were prepared by coprecipitation method and the performance of the catalysts in HTS was evaluated under gas mixture conditions (42% H2, 10% CO, 37% H2O, 8% CO2, and 3% CH4; R (reduction factor): about 1.2) similar to the gases from steam reforming of LPG (100% conversion at steam/carbon ratio = 3), which is higher than R (under 1) of typically studied LNG reformate condition. Among the prepared Cr-free Febased catalysts, the 5 wt%-Co/Fe/20 wt%-Ni and 5 wt%-Zn/Fe/20 wt%-Ni catalysts showed good catalytic activity under this reaction condition simulating LPG reformate gas.

  9. Structural group analysis of residues from Athabasca bitumen

    SciTech Connect (OSTI)

    Gray, M.R.; Choi, J.H.K.; Egiebor, N.O. (Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical Engineering); Kirchen, R.P.; Sanford, E.C. (Syncrude Canada Ltd., Edmonton, AB (Canada))

    1989-01-01T23:59:59.000Z

    Although the processability of bitumen from tar sand is dependent on its chemical composition, the details of this relationship are poorly understood. In this study, residue fractions from Athabasca bitumen (topped at different temperatures) and hydrocracker and coker residues were analyzed in detail. Separated class fractions were subjected to elemental analysis, NMR and IR spectroscopy, and potentiometric titration. These data were combined mathematically to obtain a structural profile of each oil. This analysis defines the structural changes in asphaltene precipitates due to distillation and processing, as well as the quantitative changes in the overall structural composition of the oil. Hydrocarbon structures such as paraffinic chains and naphthenes show definite trends with distillation and processing.

  10. Multilevel distillation of magic states for quantum computing

    E-Print Network [OSTI]

    Cody Jones

    2013-03-27T23:59:59.000Z

    We develop a procedure for distilling magic states used in universal quantum computing that requires substantially fewer initial resources than prior schemes. Our distillation circuit is based on a family of concatenated quantum codes that possess a transversal Hadamard operation, enabling each of these codes to distill the eigenstate of the Hadamard operator. A crucial result of this design is that low-fidelity magic states can be consumed to purify other high-fidelity magic states to even higher fidelity, which we call "multilevel distillation." When distilling in the asymptotic regime of infidelity $\\epsilon \\rightarrow 0$ for each input magic state, the number of input magic states consumed on average to yield an output state with infidelity $O(\\epsilon^{2^r})$ approaches $2^r+1$, which comes close to saturating the conjectured bound in [Phys. Rev. A 86, 052329]. We show numerically that there exist multilevel protocols such that the average number of magic states consumed to distill from error rate $\\epsilon_{\\mathrm{in}} = 0.01$ to $\\epsilon_{\\mathrm{out}}$ in the range $10^{-5}$ to $10^{-40}$ is about $14\\log_{10}(1/\\epsilon_{\\mathrm{out}}) - 40$; the efficiency of multilevel distillation dominates all other reported protocols when distilling Hadamard magic states from initial infidelity 0.01 to any final infidelity below $10^{-7}$. These methods are an important advance for magic-state distillation circuits in high-performance quantum computing, and they provide insight into the limitations of nearly resource-optimal quantum error correction.

  11. Distillation and Dehydro Reactors Advanced Process Conrol Freeport Texas PLant

    E-Print Network [OSTI]

    Eisele, D.

    2014-01-01T23:59:59.000Z

    Distillation and Dehydro Reactors Advanced Process Control Freeport Texas Plant ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation...-Sixth Industrial Energy Technology Conference New Orleans, LA. May 20-23, 2014 G-KTI, Polyamide and Intermediates Distillation APC – Control Matrix 6/2/2014 INTERNAL; CONFIDENTIAL 3 ESL-IE-14-05-16 Proceedings of the Thrity-Sixth Industrial Energy Technology...

  12. Construction and operation of a flash distillation apparatus

    E-Print Network [OSTI]

    Knezevich, Milan

    1940-01-01T23:59:59.000Z

    VII HElPEL D1STILLATIONS OF FLASH DISTILLATES OF OKLAHOMA CITY CRUDE Flash Temperature of Distillate XII DoE. F, 260 308 342 392 Volume Distilled per oent Telsp e deE. F. Temp e deE ~ Fs Toslp e doge Fo Tolllp Tolsp e deg. F, doE ~ F..., and they lose much of their kinetio energy to the high boiling molocules ~ Therefore, the solution does not start to vaporise at tho normal boiling point of the low boiling components At low percentages vaporissd flash vaporisation requires a higher vapor...

  13. Energy Use in Distillation Operation: Nonlinear Economic Effects

    E-Print Network [OSTI]

    White, D. C.

    2010-01-01T23:59:59.000Z

    Distillation operations are major consumers of energy, by some estimates comprising forty percent of the energy usage in the refining and chemicals industry. Obtaining the maximum energy efficiency from this unit operation is obviously very...

  14. Magic-state distillation with the four-qubit code

    E-Print Network [OSTI]

    Meier, Adam M; Knill, Emanuel

    2012-01-01T23:59:59.000Z

    The distillation of magic states is an often-cited technique for enabling universal quantum computing once the error probability for a special subset of gates has been made negligible by other means. We present a routine for magic-state distillation that reduces the required overhead for a range of parameters of practical interest. Each iteration of the routine uses a four-qubit error-detecting code to distill the +1 eigenstate of the Hadamard gate at a cost of ten input states per two improved output states. Use of this routine in combination with the 15-to-1 distillation routine described by Bravyi and Kitaev allows for further improvements in overhead.

  15. Heat Integrated Distillation through Use of Microchannel Technology

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose goal is to develop a breakthrough distillation process using Microchannel Process Technology to integrate heat transfer and separation into a single unit operation.

  16. Magic-state distillation with the four-qubit code

    E-Print Network [OSTI]

    Adam M. Meier; Bryan Eastin; Emanuel Knill

    2012-04-18T23:59:59.000Z

    The distillation of magic states is an often-cited technique for enabling universal quantum computing once the error probability for a special subset of gates has been made negligible by other means. We present a routine for magic-state distillation that reduces the required overhead for a range of parameters of practical interest. Each iteration of the routine uses a four-qubit error-detecting code to distill the +1 eigenstate of the Hadamard gate at a cost of ten input states per two improved output states. Use of this routine in combination with the 15-to-1 distillation routine described by Bravyi and Kitaev allows for further improvements in overhead.

  17. Synthesis and design of optimal thermal membrane distillation networks

    E-Print Network [OSTI]

    Nyapathi Seshu, Madhav

    2006-10-30T23:59:59.000Z

    Thermal membrane distillation is one of the novel separation methods in the process industry. It involves the simultaneous heat and mass transfer through a hydrophobic semipermeable membrane through the use of thermal energy to bring about...

  18. Absorption Cycle Fundamentals and Applications Guidelines for Distillation Energy Savings

    E-Print Network [OSTI]

    Erickson, D. C.; Davidson, W. F.

    1984-01-01T23:59:59.000Z

    The absorption cycle offers one of the most economic and widely applicable technologies for waste heat upgrading. It can use off-the-shelf hardware that is available now, at any required capacity rating. Fractional distillations, as a class...

  19. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11T23:59:59.000Z

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  20. Energy Use in Distillation Operation: Nonlinear Economic Effects 

    E-Print Network [OSTI]

    White, D. C.

    2010-01-01T23:59:59.000Z

    Distillation operations are major consumers of energy, by some estimates comprising forty percent of the energy usage in the refining and chemicals industry. Obtaining the maximum energy efficiency from this unit operation ...

  1. Reducing WWW Latency and Bandwidth Requirements by RealTime Distillation

    E-Print Network [OSTI]

    California at Berkeley, University of

    Reducing WWW Latency and Bandwidth Requirements by Real­Time Distillation Armando Fox and Eric A Distillation and Refinement Can Help 1. The Concept of Datatype­Specific Distillation 2. Refinement 3. Trading. Optimizing for Rendering on Impoverished Devices 3. An Implemented HTTP Proxy Based on Real­Time Distillation

  2. Control strategies for reactive batch distillation Eva Swensen and Sigurd Skogestad"

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Control strategies for reactive batch distillation Eva Swensen and Sigurd Skogestad" Department be combined directly with a distillation column by distilling off the light component product in order a maximum value in order to avoid break-through of an intermediate component in the distillate. This maximum

  3. Dividing wall columns for heterogeneous azeotropic distillation Quang-Khoa Le1

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Dividing wall columns for heterogeneous azeotropic distillation Quang-Khoa Le1 , Ivar J. Halvorsen2 of this work is to implement heterogeneous azeotropic distillation schemes in a dividing wall column (DWC distillation, Petlyuk arrangement, energy saving. 1. Introduction Distillation is one of the most energy

  4. Interferometric distillation and determination of unknown two-qubit entanglement

    E-Print Network [OSTI]

    S. -S. B. Lee; H. -S. Sim

    2010-06-08T23:59:59.000Z

    We propose a scheme for both distilling and quantifying entanglement, applicable to individual copies of an arbitrary unknown two-qubit state. It is realized in a usual two-qubit interferometry with local filtering. Proper filtering operation for the maximal distillation of the state is achieved, by erasing single-qubit interference, and then the concurrence of the state is determined directly from the visibilities of two-qubit interference. We compare the scheme with full state tomography.

  5. Heat Recovery in Distillation by Mechanical Vapor Recompression

    E-Print Network [OSTI]

    Becker, F. E.; Zakak, A. I.

    tower energy requirements can be achieved by mechanical vapor recompression. Three design approaches for heating a distillation tower reboiler by mechanical vapor recompression are presented. The advantages of using a screw compressor are discussed... for lowering energy consumption in the distillation process through various heat recovery techniques. (3-8) One such technique utilizes mechanical vapor recompression. (9-12) The principle of this ap proach involves the use of a compressor to recycle...

  6. Single-step distillation protocol with generalized beam splitters

    SciTech Connect (OSTI)

    Martin-Delgado, M. A.; Navascues, M. [Departamento de Fisica Teorica I, Universidad Complutense, 28040 Madrid, (Spain)

    2003-07-01T23:59:59.000Z

    We develop a distillation protocol for multilevel qubits (qudits) using generalized beam splitters like in the proposal of Pan et al. for ordinary qubits. We find an acceleration with respect to the scheme of Bennet et al. when extended to qudits. It is also possible to distill entangled pairs of photons carrying orbital angular momenta states that conserve the total angular momenta as those produced in recent experiments.

  7. Key Distillation and the Secret-Bit Fraction

    E-Print Network [OSTI]

    Nick S. Jones; Lluis Masanes

    2008-05-12T23:59:59.000Z

    We consider distillation of secret bits from partially secret noisy correlations P_ABE, shared between two honest parties and an eavesdropper. The most studied distillation scenario consists of joint operations on a large number of copies of the distribution (P_ABE)^N, assisted with public communication. Here we consider distillation with only one copy of the distribution, and instead of rates, the 'quality' of the distilled secret bits is optimized, where the 'quality' is quantified by the secret-bit fraction of the result. The secret-bit fraction of a binary distribution is the proportion which constitutes a secret bit between Alice and Bob. With local operations and public communication the maximal extractable secret-bit fraction from a distribution P_ABE is found, and is denoted by Lambda[P_ABE]. This quantity is shown to be nonincreasing under local operations and public communication, and nondecreasing under eavesdropper's local operations: it is a secrecy monotone. It is shown that if Lambda[P_ABE]>1/2 then P_ABE is distillable, thus providing a sufficient condition for distillability. A simple expression for Lambda[P_ABE] is found when the eavesdropper is decoupled, and when the honest parties' information is binary and the local operations are reversible. Intriguingly, for general distributions the (optimal) operation requires local degradation of the data.

  8. Table A3. Refiner/Reseller Prices of Distillate and Residual Fuel Oils,

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet)4. U.S. Vehicle FuelFoot,Effective PADA3.

  9. Table A3. Refiner/Reseller Prices of Distillate and Residual Fuel Oils,

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial ConsumersThousandCubic Feet)4. U.S. Vehicle FuelFoot,Effective PADA3.

  10. Non-Locality Distillation is Impossible for Isotropic Quantum Systems

    E-Print Network [OSTI]

    Dejan D. Dukaric

    2011-09-20T23:59:59.000Z

    Non-locality is a powerful resource for various communication and information theoretic tasks, e.g., to establish a secret key between two parties, or to reduce the communication complexity of distributed computing. Typically, the more non-local a system is, the more useful it is as a resource for such tasks. We address the issue of non-locality distillation, i.e., whether it is possible to create a strongly non-local system by local operations on several weakly non-local ones. More specifically, we consider a setting where non-local systems can be realized via measurements on underlying shared quantum states. The hardest instances for non-locality distillation are the isotropic quantum systems: if a certain isotropic system can be distilled, then all systems of the same non-locality can be distilled as well. The main result of this paper is that non-locality cannot be distilled from such isotropic quantum systems. Our results are based on the theory of cross norms defined over the tensor product of certain Banach spaces. In particular, we introduce a single-parameter family of cross norms, which is used to construct a hierarchy of convex sets that are closed under local operations. This hierarchy interpolates between the set of local systems and an approximation to the set of quantum systems.

  11. Kinetics and thermodynamics of hydrotreating synthetic middle distillates

    SciTech Connect (OSTI)

    Fisher, I.P. (Petro-Canada R and D Dept., Sheridan Park, Ontario (Canada)); Wilson, M.F. (CANMET, Ottawa, Ontario (Canada))

    1987-04-01T23:59:59.000Z

    Middle distillates from the Tar Sands deposits in Alberta are an important component of diesel and jet fuels in the Canadian market. Commercial catalysts based on sulfided Ni-Mo and Ni-W are currently used to hydrogenate synthetic distillates to improve the cetane number and smoke point. In previous work {sup 13}C NMR was used to study the kinetics of overall hydrogenation of aromatics over sulfided Co-Mo, Ni-Mo and Ni-W catalysts. Arrhenius parameters were obtained for hydrogenation over sulfided Ni-W catalyst for a similar distillate feedstock. In the latter study, mass spectrometry was used to quantitate the three major aromatic hydrocarbon group types in the feed and products. In this study, liquid products from hydrotreating experiments with a hydrotreated distillate from delayed coking of Athabasca bitumen and sulfided Co-Mo and Ni-Mo catalysts have been analyzed by mass spectrometry. This completes a preliminary comparison of the kinetics of hydrogenation of alkylbenzenes, benzocycloparaffins and benzodicycloparaffins, the three major aromatic hydrocarbon types in these distillates.

  12. A New Protocol of Continuous-Variable Entanglement Distillation

    E-Print Network [OSTI]

    Shi Jin; Xian-Min Jin; Joshua Nunn; Animesh Datta; Ian Walmsley

    2012-10-16T23:59:59.000Z

    We introduce a new protocol in continuous variable entanglement distillation that requires only linear temporal and constant physical or spatial resources.Compared with the existing protocols, our protocol uses atom-photon entanglement to substitute for atom-atom entanglement in existing protol, which will not only save the number of quantum memories, but also has the advantages in operation efficiency and temporal saving. The distillation can be realized by a fixed model of iterations, in which only three quantum memories and photon detectors are required.

  13. "Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department of Chemical Engineering

    E-Print Network [OSTI]

    Skogestad, Sigurd

    "Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department Distillation Arrangements by Ivar J. Halvorsen and Sigurd Skogestad Norwegian University of Science and Technology (NTNU) Department of Chemical Engineering Working Party on "Distillation, Absorption

  14. HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT

    E-Print Network [OSTI]

    Titov, Anatoly

    321 HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT I.A. Alekseev, E for manufacturing of ultra pure protium from hydrogen [2]. A principle of hydrogen cryogenic distillation was used

  15. December 13, 2012 The steady state model of a reactive distillation column for ethylene glycol

    E-Print Network [OSTI]

    Neumaier, Arnold

    December 13, 2012 The steady state model of a reactive distillation column for ethylene glycol in an ethylene glycol reactive distillation column. Ind. Eng. Chem. Res., 33:2738­2748, 1994. 3 #12;

  16. Application of a Plantwide Control Design Procedure to a Distillation Column with Heat Pump

    E-Print Network [OSTI]

    Skogestad, Sigurd

    (Larsson & Skogestad 2001) to a distillation column heat-integrated by using a heatpump. Top-down analysis) and apply it to a distillation column with heatpump. Plantwide control design should start by formulating

  17. Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S to obtain a light and a heavy fraction simultaneously from the top and the bottom of the column, while an intermediate fraction may also be recovered in the middle vessel. Two modifications of the multivessel

  18. Optimal distillation of three-qubit W states

    E-Print Network [OSTI]

    Ali Yildiz

    2010-07-19T23:59:59.000Z

    Some of the asymmetric three qubit $W$ states are used for perfect teleportation, superdense coding and quantum information splitting. We present the protocols for the optimal distillation of the asymmetric as well as the symmetric $W$ states from a single copy of any three qubit $W$ class pure state.

  19. The application of continuation methods in solving steady-state distillation problems

    E-Print Network [OSTI]

    Ellis, Mark Francis

    1985-01-01T23:59:59.000Z

    80 101 105 CHAPTER I INTRODUCTION Distillation is the most common separ ation process in the chemical and petroleum industr ies. A ma]or tool in the design of distillation columns is steady-state distillation simulation. Also, steady-stat. e...'s Equation 98 B BIFURCATION AND TURNING POINTS ON CONTINUATION PATHS 100 C FORMULATION OF MATHEMATICAI MODELS USED IN EXAMPLE PROBLEMS 104 Problem 1 ? A Conventional Distillation Column Separating an Ideal Solution Problem 2 ? A Conventional...

  20. Automated Dispersive Solid Phase Extraction of Pesticide Residues in Botanicals using Triple Quadrupole LC/MS/MS

    E-Print Network [OSTI]

    Heller, Barbara

    /g ·Distilled water (10 mL) was added to the sample and mixed for 1min. ·Samples were then extracted using 10 mAutomated Dispersive Solid Phase Extraction of Pesticide Residues in Botanicals using Triple analysis in food and food products. These methods use acetonitrile extraction followed by salting out

  1. Integrated Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Distillation Ivar J. Halvorsen1 and Sigurd Skogestad Norwegian University of Science and Technology, Department at the Topical conference on Separations Technology, Session 23 - Distillation Modeling and Processes II. 2001 Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation Ivar J

  2. Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Control Study of Ethyl tert-Butyl Ether Reactive Distillation Muhammad A. Al-Arfaj Department structures for ethyl tert-butyl ether (ETBE) reactive distillation columns are studied. Two process The use of reactive distillation has grown in recent years because it results in less expensive and more

  3. Rejection and fate of trace organic compounds (TrOCs) during membrane distillation

    E-Print Network [OSTI]

    Rejection and fate of trace organic compounds (TrOCs) during membrane distillation Kaushalya COCs) Direct contact membrane distillation (DCMD) Volatility Fate and transport Hydrophobicity/hydrophilicity a b s t r a c t In this study, we examined the feasibility of membrane distillation (MD) for removing

  4. The dos and don'ts of distillation column control Sigurd Skogestad*

    E-Print Network [OSTI]

    Skogestad, Sigurd

    The dos and don'ts of distillation column control Sigurd Skogestad* Department of Chemical discusses distillation column control within the general framework of plantwide control. In addition for distillation columns. The standard LV-configuration combined with a fast temperature loop is recommended

  5. Comparison of Alternative Control Structures for an Ideal Two-Product Reactive Distillation Column

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Comparison of Alternative Control Structures for an Ideal Two-Product Reactive Distillation Column distillation columns have been explored in many papers, very few papers have dealt with closed-loop control. Most of these control papers consider reactive distillation columns in which there is only one product

  6. MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA S RENSEN 2

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA S RENSEN 2 and RAJAB LITTO column presented in this paper provides a generalization of previously proposed batch distillation schemes. The economic potential of the multivessel batch distillation under total re ux is demon- strated

  7. Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1 Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements-integrated multi-effect and three non-integrated distillation arrangements for separating a ternary mixture have been considered. The focus of the paper is on a heat-integrated complex distillation configuration

  8. Experimental and Theoretical Studies on the Start-Up Operation of a Multivessel Batch Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Experimental and Theoretical Studies on the Start-Up Operation of a Multivessel Batch DistillationVersity of Science and Technology, Trondheim, Norway Multivessel batch distillation is a promising alternative to conventional batch distillation. Earlier studies proved the feasibility of temperature control in a closed

  9. On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal

    E-Print Network [OSTI]

    Skogestad, Sigurd

    On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal Binary Columns distillation processes. By considering the e ect of small changes in the operating parameters, e.g., initial-mail: jacobsen@elixir.e.kth.se 1 #12;1 Introduction Batch distillation has become of increasing importance

  10. Optimization of a Diabatic Distillation Column with Sequential Heat Edward Steven Jimenez and Peter Salamon*

    E-Print Network [OSTI]

    Salamon, Peter

    Optimization of a Diabatic Distillation Column with Sequential Heat Exchangers Edward Steven of Copenhagen, Copenhagen, Denmark Diabatic distillation is a separation process in which heat is transferred is enormous because distillation is the single largest energy degrading unit operation worldwide. Introduction

  11. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial heat integrated distillation column Truls Larsson Sigurd Skogestad ÝDepartment of Chemical. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process QH column

  12. THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES --WITH APPLICATION TO DISTILLATION COLUMNS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES --WITH APPLICATION TO DISTILLATION COLUMNS John Morud that a subsystem is influenced only by its nabor subsystems. An example of such a process is a distillation column in high purity distillation columns; in fact, the magnitude of these time constants may increase

  13. Topic Distillation with Query-Dependent Link Connections and Page Characteristics

    E-Print Network [OSTI]

    Wu, Mingfang

    6 Topic Distillation with Query-Dependent Link Connections and Page Characteristics MINGFANG WU about a topic. Finding such results is called topic distillation. Previous research has shown statistics. This article presents a new approach to improve topic distillation by exploring the use

  14. Use of Two Distillation Columns in Systems with Maximum Temperature Limitations

    E-Print Network [OSTI]

    Gilchrist, James F.

    Use of Two Distillation Columns in Systems with Maximum Temperature Limitations Rebecca H. Masel, Pennsylvania 18015, United States ABSTRACT: Maximum temperature limitations are encountered in distillation of the bottoms product fixes the column base pressure and, hence, the condenser pressure. The distillate

  15. On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal

    E-Print Network [OSTI]

    Skogestad, Sigurd

    On the Dynamics of Batch Distillation : A Study of Parametric Sensitivity in Ideal Binary Columns sensitivity in batch distillation processes. By considering the effect of small changes in the operating #12; 1 Introduction Batch distillation has become of increasing importance in industry during the last

  16. Know-Center at TREC 2009 Blog Distillation Task: A Notebook Paper

    E-Print Network [OSTI]

    Hammerton, James

    Know-Center at TREC 2009 Blog Distillation Task: A Notebook Paper Elisabeth Lex, Michael Granitzer,mgrani,ajuffinger}@know-center.at Abstract. This paper outlines our experiments carried out at TREC 2009 Blog Distillation Task. Our system, specifically the blog distillation task, exactly this problem is addressed. The goal of the track is to rank

  17. MULTIVESSEL BATCH DISTILLATION -EXPERIMENTAL VERIFICATION Bernd Wittgens and Sigurd Skogestad1

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION -EXPERIMENTAL VERIFICATION Bernd Wittgens and Sigurd Skogestad1 The experimental veri cation of the operation of a multivessel batch distillation column, operated under total re vessels, provides a generalization of previously proposed batch distillation schemes. We propose a simple

  18. Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column

    E-Print Network [OSTI]

    Salamon, Peter

    Optimal Allocation of Heat Exchanger Inventory in a Serial Type Diabatic Distillation Column Edward Abstract Diabatic distillation is a separation process in which heat is transferred on the trays inside savings is through diabatic distillation. Instead of just one heat source (the reboiler) and one heat sink

  19. Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel E. K distillation for separating homogeneous minimum-boiling azeotropic mixtures, where the extractive agent and a control structure for the batch extractive middle vessel distillation is proposed. In extractive

  20. Optimization of Distillation Processes. Jos A. Caballero* and Ignacio E. Grossmann**

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Optimization of Distillation Processes. José A. Caballero* and Ignacio E. Grossmann** *Dept and a single condenser in the entire sequence. We also review the rigorous design of distillation columns, or column sequences. In all the cases we focus on mathematical programming approaches. Keywords Distillation

  1. Enhanced Topic Distillation using Text, Markup Tags, and Hyperlinks Soumen Chakrabarti

    E-Print Network [OSTI]

    Chakrabarti, Soumen

    Enhanced Topic Distillation using Text, Markup Tags, and Hyperlinks Soumen Chakrabarti Mukul Joshi Vivek Tawde IIT Bombay ABSTRACT Topic distillation is the analysis of hyperlink graph structure to authorities). Topic distillation is becoming common in Web search engines, but the best-known algorithms model

  2. Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process system for TAME reactive distillation process using extraction column with water as a solvent. The design distillation column which was optimized to recover methanol and recycle water to the extraction column. Other

  3. DISTILLATION DES LIQUIDES SOUS L'INFLUENCE DE L'LECTRICIT STATIQUE; PAR M. D. GERNEZ.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    36I DISTILLATION DES LIQUIDES SOUS L'INFLUENCE DE L'ÉLECTRICITÉ STATIQUE; PAR M. D. GERNEZ. La décharge, la distillation se produit aussitôt en sens in- verse (2). Ce phénomène est extrêmemen t n e sens suivant lequel se produit cette distillation est contraire à celui que sem- bleraient indiquer les

  4. Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse Bonami-Beckner inequality

    E-Print Network [OSTI]

    O'Donnell, Ryan

    Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse Bonami In this paper we study non-interactive correlation distillation (NICD), a generalization of noise sen- sitivity distillation (NICD), previously considered in [5, 31, 39]. In its most general form the problem involves k

  5. Retrieval and Feedback Models for Blog Distillation Jonathan Elsas, Jaime Arguello, Jamie Callan, Jaime Carbonell

    E-Print Network [OSTI]

    Carbonell, Jaime

    Retrieval and Feedback Models for Blog Distillation Jonathan Elsas, Jaime Arguello, Jamie Callan and results for the Feed Distillation task in the Blog track at TREC 2007. Our experiments focus on two Wikipedia. 1 Introduction Blog distillation (or "feed search") is the task of finding blog feeds

  6. Assured Information Distillation in Social Sensing University of Illinois at Urbana-Champaign

    E-Print Network [OSTI]

    Garibaldi, Skip

    Colloquium Assured Information Distillation in Social Sensing Dong Wang University of Illinois. This opens up unprecedented challenges and opportunities in social sensing, where the goal is to distill, social and physical networks. The talk will also introduce a new information distillation system we built

  7. MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA SRENSEN 2

    E-Print Network [OSTI]

    Skogestad, Sigurd

    MULTIVESSEL BATCH DISTILLATION SIGURD SKOGESTAD 1 , BERND WITTGENS, EVA SØRENSEN 2 and RAJAB LITTO column presented in this paper provides a generalization of previously proposed batch distillation schemes. The economic potential of the multivessel batch distillation under total reflux is demon­ strated

  8. Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse

    E-Print Network [OSTI]

    Regev, Oded

    Non-interactive correlation distillation, inhomogeneous Markov chains, and the reverse Bonami In this paper we study non-interactive correlation distillation (NICD), a generalization of noise sensitivity in this paper is the problem of non-interactive correlation distil- lation (NICD), previously considered in [5

  9. Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating Vidar Trondheim, Norway Keywords: Distillation, Petlyuk, Divided-wall, Minimum energy Abstract This paper shows the unexpected result that over-fractionating one of the product streams in a Petlyuk distillation column may

  10. Sustainable operation of membrane distillation for enhancement of mineral recovery from hypersaline solutions

    E-Print Network [OSTI]

    Sustainable operation of membrane distillation for enhancement of mineral recovery from hypersaline December 2013 Available online 25 December 2013 Keywords: Membrane distillation Desalination Hypersaline brine Scaling Membrane cleaning Evaporation pond a b s t r a c t Membrane distillation (MD

  11. Noisy Processing and the Distillation of Private States Joseph M. Renes1

    E-Print Network [OSTI]

    Noisy Processing and the Distillation of Private States Joseph M. Renes1 and Graeme Smith2 1 general private state is distilled. Besides a more general target state, the usual entanglement distillation tools are employed (in par- ticular, Calderbank-Shor-Steane (CSS)-like codes), with the crucial

  12. THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES WITH APPLICATION TO DISTILLATION COLUMNS

    E-Print Network [OSTI]

    Skogestad, Sigurd

    THE DYNAMIC BEHAVIOR OF CASCADE PROCESSES WITH APPLICATION TO DISTILLATION COLUMNS John Morud that a subsystem is in uenced only by its nabor subsystems. An example of such a process is a distillation column in high purity distillation columns; in fact, the magnitude of these time constants may increase

  13. A globally convergent method for finding all steady-state solutions of distillation columns

    E-Print Network [OSTI]

    Neumaier, Arnold

    A globally convergent method for finding all steady-state solutions of distillation columns Ali distillation column with 7 steady-states show the robustness of the method. No published software known to the steady-state model of distillation columns as it returns the original system as a single large block

  14. Distillation Codes and Applications to DoS Resistant Multicast Authentication

    E-Print Network [OSTI]

    Perrig, Adrian

    Distillation Codes and Applications to DoS Resistant Multicast Authentication Chris Karlof UC We introduce distillation codes, a method for streaming and storing data. Like erasure codes, distillation codes allow information to be decoded from a sufficiently large quorum of symbols. In contrast

  15. Synthesizing Representative I/O Workloads Using Iterative Distillation Zachary Kurmas

    E-Print Network [OSTI]

    Kurmas, Zachary

    Synthesizing Representative I/O Workloads Using Iterative Distillation Zachary Kurmas College proper- ties are "key" for a given workload and storage system. We have developed a tool, the Distiller, that automati- cally identifies the key properties ("attribute-values") of the workload. The Distiller then uses

  16. Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel E. K distillation for separating homogeneous minimum­boiling azeotropic mixtures, where the extractive agent and a control structure for the batch extractive middle vessel distillation is proposed. In extractive

  17. Integrating the Document Object Model with Hyperlinks for Enhanced Topic Distillation and Information Extraction

    E-Print Network [OSTI]

    Chakrabarti, Soumen

    Integrating the Document Object Model with Hyperlinks for Enhanced Topic Distillation://www.cse.iitb.ernet.in/~soumen ABSTRACT Topic distillation is the process of finding authoritative Web pages and comprehensive "hubs distillation has been traditionally applied to a macroscopic Web model where documents are nodes in a directed

  18. Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio Sebastiani

    E-Print Network [OSTI]

    Sebastiani, Fabrizio

    Endorsements and rebuttals in blog distillation q Giacomo Berardi, Andrea Esuli, Fabrizio in revised form 10 May 2013 Accepted 30 May 2013 Available online 14 June 2013 Keywords: Blog distillation to blog distillation, defined as the task in which, given a user query, the system ranks the blogs

  19. Complex Distillation Arrangements 23.May 2001 by I.Halvorsen NTNU Department of Chemical Engineering

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Complex Distillation Arrangements 23.May 2001 by I.Halvorsen NTNU Department of Chemical Engineering 1 Minimum Energy Requirements in Complex Distillation Arrangements A thesis submitted for the degree of dr. ing. 23. May 2001 by Ivar J. Halvorsen #12;Complex Distillation Arrangements 23.May 2001

  20. T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial

    E-Print Network [OSTI]

    Skogestad, Sigurd

    T. Larsson, S. Skogestad Control of a industrial heat integrated distillation column Control of a industrial heat integrated distillation column Truls Larsson Sigurd Skogestad y Department of Chemical. Larsson, S. Skogestad Control of a industrial heat integrated distillation column The process Q H column

  1. Manifold-based starting point generation and its application to distillation

    E-Print Network [OSTI]

    Neumaier, Arnold

    Manifold-based starting point generation and its application to distillation Ali Baharev*, Ferenc-states in homogeneous azeotropic distillation . . . . . . . . . . 11 5.2 Multiple steady-states in ideal two-product distillation . . . . . . . . . . . . . . 11 6 Conclusion 13 A Ordering sparse matrices 14 A.1 Ordering to block

  2. Distillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Grak (Editors)

    E-Print Network [OSTI]

    Skogestad, Sigurd

    structure design. Keywords: Kaibel column, thermally coupled distillation columns, optimal operation 1J.Halvorsen@sintef.no Abstract The objective of this paper is to study the Kaibel distillation column from operability point. Introduction The thermally-coupled Petlyuk 1 distillation column separates the feed into three products

  3. Distillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Grak (Editors)

    E-Print Network [OSTI]

    Skogestad, Sigurd

    is a viable option in present case. Keywords: Distillation, Energy saving, Dividing wall column, Thermal challenge is to design distillation systems that at the same time are sustainable and economically feasibleDistillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Górak (Editors) All rights reserved

  4. Optimal Synthesis of Thermally Coupled Distillation Sequences Using a Novel MILP Approach.

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    . Pittsburgh, PA. USA. Abstract This paper introduces a novel MILP approach for the design of distillation Column; Superstructure optimization; GDP. Introduction Distillation is the most widely used method distillation (TCD), in which heat is directly transferred between columns through two streams (liquid a vapor

  5. Active Constraint Regions for Optimal Operation of Distillation Magnus G. Jacobsen and Sigurd Skogestad*

    E-Print Network [OSTI]

    Skogestad, Sigurd

    , NTNU, N-7491, Trondheim, Norway ABSTRACT: When designing the control structure of distillation columnsActive Constraint Regions for Optimal Operation of Distillation Columns Magnus G. Jacobsen presented in an earlier paper, to find how the active constraints for distillation columns change

  6. Model predictive control of a pilot-scale distillation column using a programmable automation controller

    E-Print Network [OSTI]

    Model predictive control of a pilot-scale distillation column using a programmable automation). The controller is tested on a pilot-scale binary distillation column to track reference temperatures. A majorRIO) to control a pilot-scale binary distillation col- umn. Both the PI-controllers and the supervising online MPC

  7. Distillation and purification of symmetric entangled Gaussian states

    E-Print Network [OSTI]

    Jaromir Fiurasek

    2010-11-03T23:59:59.000Z

    We propose an entanglement distillation and purification scheme for symmetric two-mode entangled Gaussian states that allows to asymptotically extract a pure entangled Gaussian state from any input entangled symmetric Gaussian state. The proposed scheme is a modified and extended version of the entanglement distillation protocol originally developed by [Browne et al., Phys. Rev. A 67, 062320 (2003)]. A key feature of the present protocol is that it utilizes a two-copy de-Gaussification procedure that involves a Mach-Zehnder interferometer with single-mode non-Gaussian filters inserted in its two arms. The required non-Gaussian filtering operations can be implemented by coherently combining two sequences of single-photon addition and subtraction operations.

  8. Distillation of entanglement by projection on permutationally invariant subspaces

    E-Print Network [OSTI]

    Czechlewski, Miko?aj; Horodecki, Micha?; Mozrzymas, Marek; Studzi?ski, Micha?

    2011-01-01T23:59:59.000Z

    We consider distillation of entanglement from two qubit states which are mixtures of three mutually orthogonal states: two pure entangled states and one pure product state. We distill entanglement from such states by projecting n copies of the state on permutationally invariant subspace and then applying one-way hashing protocol. We find analytical expressions for the rate of the protocol. We also generalize this method to higher dimensional systems. To get analytical expression for two qubit case, we faced a mathematical problem of diagonalizing a family of matrices enjoying some symmetries w.r.t. to symmetric group. We have solved this problem in two ways: (i) directly, by use of Schur-Weyl decomposition and Young symmetrizers (ii) showing that the problem is equivalent to a problem of diagonalizing adjacency matrices in a particular instance of a so called algebraic association scheme.

  9. Reducing the quantum computing overhead with complex gate distillation

    E-Print Network [OSTI]

    Guillaume Duclos-Cianci; David Poulin

    2014-03-20T23:59:59.000Z

    In leading fault-tolerant quantum computing schemes, accurate transformation are obtained by a two-stage process. In a first stage, a discrete, universal set of fault-tolerant operations is obtained by error-correcting noisy transformations and distilling resource states. In a second stage, arbitrary transformations are synthesized to desired accuracy by combining elements of this set into a circuit. Here, we present a scheme which merges these two stages into a single one, directly distilling complex transformations. We find that our scheme can reduce the total overhead to realize certain gates by up to a few orders of magnitude. In contrast to other schemes, this efficient gate synthesis does not require computationally intensive compilation algorithms, and a straightforward generalization of our scheme circumvents compilation and synthesis altogether.

  10. Distillation of hydrogen isotopes for polarized HD target

    E-Print Network [OSTI]

    T. Ohta; S. Bouchigny; J. -P. Didelez; M. Fujiwara; K. Fukuda; H. Kohri; T. Kunimatsu; C. Morisaki; S. Ono; G. Rouill'; M. Tanaka; K. Ueda; M. Uraki; M. Utsuro; S. Y. Wang; M. Yosoi

    2011-12-12T23:59:59.000Z

    We have developed a cryogenic distillation system to purify Hydrogen-Deuteride (HD) gas for a polarized HD target in LEPS experiments at SPring-8. A small amount of ortho-H$_2$ ($\\sim$0.01%) in the HD gas plays an important role in efficiently polarizing the HD target. Since there are 1$\\sim$5% impurities of H$_2$ and D$_2$ in commercially available HD gases, it is inevitable that the HD gas is purified up to $\\sim$99.99%. The distillation system has a cryogenic pot (17$\\sim$21 K) containing many small stainless steel cells called Heli-pack. Commercial HD gas with an amount of 5.2 mol is fed into the pot. We carried out three distillation runs by changing temperatures (17.5 K and 20.5 K) and gas extraction speeds (1.3 ml/min and 5.2 ml/min). The extracted gas was analyzed by using a gas analyzer system combining a quadrupole mass spectrometer with a gas chromatograph. The HD gas of 1 mol with a purity better than 99.99% has been successfully obtained. The effective NTS (Number of Theoretical Stages), which is an indicator of the distillator performances, is obtained as 37.2$\\pm$0.6. This value is in reasonable agreement with a designed value of 37.9. The HD target is expected to be efficiently polarized under a well-controlled condition by doping an optimal amount of ortho-H$_2$ to the purified HD gas.

  11. Enhanced Separation Efficiency in Olefin/Paraffin Distillation

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

  12. An experimental and mathematical investigation of hydrocarbon steam distillation

    E-Print Network [OSTI]

    Langhoff, John Allan

    1984-01-01T23:59:59.000Z

    the Holland and Welch method was very good. The agreement between experimental and predicted separation data indicated the Holland and Welch method could be extended to calculate crude oil-water -vapor separations. A practical procedure using the Holland... and Welch method and simulated distillation data was developed to predict crude oil-water-vapor separations. The method was compared to experimental crude oil-water-vapor separation data obtained at saturated steam conditions of 378 F and 456 F...

  13. Reactive Distillation for Esterification of Bio-based Organic Acids

    SciTech Connect (OSTI)

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23T23:59:59.000Z

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.

  14. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Dale, L; Opilla, R; Surles, T

    1980-09-01T23:59:59.000Z

    Technologies available for the production of ethanol from whole corn are reviewed. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. The use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - is reviewed as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. The environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass are covered. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  15. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Opilla, R.; Dale, L.; Surles, T.

    1980-05-01T23:59:59.000Z

    A variety of carbohydrate sources can be used as raw material for the production of ethanol. Section 1 is a review of technologies available for the production of ethanol from whole corn. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. Section 2 is a review of the use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. Section 3 deals with the environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  16. Distillation of hydrogen isotopes for polarized HD target

    E-Print Network [OSTI]

    Ohta, T; Didelez, J -P; Fujiwara, M; Fukuda, K; Kohri, H; Kunimatsu, T; Morisaki, C; Ono, S; Rouill', G; Tanaka, M; Ueda, K; Uraki, M; Utsuro, M; Wang, S Y; Yosoi, M

    2011-01-01T23:59:59.000Z

    We have developed a cryogenic distillation system to purify Hydrogen-Deuteride (HD) gas for a polarized HD target in LEPS experiments at SPring-8. A small amount of ortho-H$_2$ ($\\sim$0.01%) in the HD gas plays an important role in efficiently polarizing the HD target. Since there are 1$\\sim$5% impurities of H$_2$ and D$_2$ in commercially available HD gases, it is inevitable that the HD gas is purified up to $\\sim$99.99%. The distillation system has a cryogenic pot (17$\\sim$21 K) containing many small stainless steel cells called Heli-pack. Commercial HD gas with an amount of 5.2 mol is fed into the pot. We carried out three distillation runs by changing temperatures (17.5 K and 20.5 K) and gas extraction speeds (1.3 ml/min and 5.2 ml/min). The extracted gas was analyzed by using a gas analyzer system combining a quadrupole mass spectrometer with a gas chromatograph. The HD gas of 1 mol with a purity better than 99.99% has been successfully obtained. The effective NTS (Number of Theoretical Stages), which is...

  17. Bound States for Magic State Distillation in Fault-Tolerant Quantum Computation

    E-Print Network [OSTI]

    Earl T. Campbell; Dan E. Browne

    2010-02-01T23:59:59.000Z

    Magic state distillation is an important primitive in fault-tolerant quantum computation. The magic states are pure non-stabilizer states which can be distilled from certain mixed non-stabilizer states via Clifford group operations alone. Because of the Gottesman-Knill theorem, mixtures of Pauli eigenstates are not expected to be magic state distillable, but it has been an open question whether all mixed states outside this set may be distilled. In this Letter we show that, when resources are finitely limited, non-distillable states exist outside the stabilizer octahedron. In analogy with the bound entangled states, which arise in entanglement theory, we call such states bound states for magic state distillation.

  18. Multiple steady states during reactive distillation of methyl tert-butyl ether

    SciTech Connect (OSTI)

    Nijhuis, S.A. (Univ. of Amsterdam (Netherlands). Chemical Engineering Dept.); Kerkhof, F.P.J.M.; Mak, A.N.S. (Comprimo Engineers and Contractors, Amsterdam (Netherlands))

    1993-11-01T23:59:59.000Z

    This paper presents results of computer simulations of the synthesis of methyl tert-butyl ether (MTBE) in a fixed-bed reactor and in a reactive distillation column. These calculations clearly showed the advantages of MTBE synthesis in a catalytic distillation tower. Furthermore, the computer simulations showed that multiple steady states may occur in the reactive distillation column during MTBE synthesis in a broad range of operating conditions. An analysis of some sensitivity studies is presented.

  19. An approach for solvent selection in extractive distillation systems including safety considerations

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    of bioethanol, for which solvents that offer the best cost-safety compromise are identified. Keywords. Extractive distillation; Multiobjective optimization; Process safety; Solvents; Bioethanol 1. Introduction

  20. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1998 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  1. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1995 337 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  2. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  3. INTERIM VALIDATION REPORT MIDDLE DISTILLATE PRICE MONITORING SYSTEM

    E-Print Network [OSTI]

    Hopelain, D.G.

    2011-01-01T23:59:59.000Z

    dislocation-of crude oil and products could jeopardize theoil, residual fuel oil and petroleum products and resultantof users of such oil or product." 34 The EPCA also provided

  4. Effects of Ruminally Degradable Nitrogen in Diets Containing Wet Distiller’s Grains with Solubles and Steam-flaked Corn on Feedlot Cattle Performance and Carcass Characteristics

    E-Print Network [OSTI]

    Ponce, Christian

    2010-10-12T23:59:59.000Z

    plants, certain deviations of methods due to technologies employed at specific plants might explain some of the variation in nutritive value of the co-products. Holt and Pritchard (2004) determined nutrient variations of wet distiller?s grains... disappearance was 3.9%/h, and 47% of the CP present was ruminal escape protein. Crude protein values of up to 37.6% have been determined on samples collected directly from 4 plants (Holt and Pritchard, 2004). One nutritional limitation of WDGS...

  5. Optimal operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Optimal operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionation · The Petlyuk distillation column, see Figure 1(a), with a pre-fractionator (C1) and a main column (C21 and C22) N-7465 Trondheim, Norway Abstract This work shows the unexpected result that over-fractionating one

  6. Study of the Distillability of Werner States Using Entanglement Witnesses and Robust Semidefinite Programs

    E-Print Network [OSTI]

    Reinaldo O. Vianna; Andrew C. Doherty

    2006-08-11T23:59:59.000Z

    We use Robust Semidefinite Programs and Entanglement Witnesses to study the distillability of Werner states. We perform exact numerical calculations which show 2-undistillability in a region of the state space which was previously conjectured to be undistillable. We also introduce bases which yield interesting expressions for the {\\em distillability witnesses} and for a tensor product of Werner states with arbitrary number of copies.

  7. Use of Short-cut Methods to Analyse Optimal Operation of Petlyuk Distillation Columns

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Use of Short-cut Methods to Analyse Optimal Operation of Petlyuk Distillation Columns Ivar J: Petlyuk distillation column, dividing wall column, optimizing control, minimum energy 1. INTRODUCTION- ments for the level of automatic control and to the design of number of stages in each column section. 2

  8. Use of Shortcut Methods to Analyse Optimal Operation of Petlyuk Distillation Columns

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Use of Short­cut Methods to Analyse Optimal Operation of Petlyuk Distillation Columns Ivar J: Petlyuk distillation column, dividing wall column, optimizing control, minimum energy 1. INTRODUCTION­ ments for the level of automatic control and to the design of number of stages in each column section. 2

  9. Quantum distillation: Dynamical generation of low-entropy states of strongly correlated fermions in an optical lattice

    E-Print Network [OSTI]

    Tennessee, University of

    Quantum distillation: Dynamical generation of low-entropy states of strongly correlated fermions of double occupancies. We promote the notion of quantum distillation: during the expansion and in the case

  10. Low capital implementation of distributed distillation in ethylene recovery

    DOE Patents [OSTI]

    Reyneke, Rian; Foral, Michael J.; Lee, Guang-Chung

    2006-10-31T23:59:59.000Z

    An apparatus for recovering ethylene from a hydrocarbon feed stream, where the apparatus is a single distillation column pressure shell encasing an upper region and a lower region. The upper region houses an ethylene distributor rectifying section and the lower region houses a C2 distributor section and an ethylene distributor stripping section. Vapor passes from the lower region into the upper region, and liquid passes from the upper region to the lower region. The process for recovering the ethylene is also disclosed. The hydrocarbon feed stream is introduced into the C2 distributor section, and after a series of stripping and refluxing steps, distinct hydrocarbon products are recovered from the C2 distributor section, the ethylene distributor stripping section, and the ethylene distributor rectifying section, respectively.

  11. Comparison of advanced distillation control methods. Third annual report

    SciTech Connect (OSTI)

    Riggs, J.B.

    1997-07-01T23:59:59.000Z

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to study the issue of configuration selection for diagonal PI dual composition controls, feedforward from a feed composition analyzer, and decouplers. Auto Tune Variation (ATV) identification with on-line detuning for setpoint changes was used for tuning the diagonal proportional integral (PI) composition controls. In addition, robustness tests were conducted by inducting reboiler duty upsets. For single composition control, the (L, V) configuration was found to be best. For dual composition control, the optimum configuration changes from one column to another. Moreover, the use of analysis tools, such as RGA, appears to be of little value in identifying the optimum configuration for dual composition control. Using feedforward from a feed composition analyzer and using decouplers are shown to offer significant advantages for certain specific cases.

  12. Effects of system densities on distillation column performance

    SciTech Connect (OSTI)

    Fasesan, S.O.; Sanni, S.A.; Taiwo, E.A. [Obafemi Awolowo Univ., Ile-Ife (Nigeria). Dept. of Chemical Engineering

    1998-06-01T23:59:59.000Z

    Distillation experiments were carried out on three binary systems (ethanol-butanol, ethanol-propan-2-ol, and propan-2-ol-butanol) in a 0.1-m internal diameter glass column packed with 8 mm diameter Raschig rings. The experiments were performed under total reflux conditions and at atmospheric pressure. The data collected on column performance showed that performance declined with increasing average bulk liquid density. The results also lend credence to earlier reports on the behavior of column performance with respect to component concentration in the feed mixtures. The system densities of the three binary systems were measured at four different temperatures, 30, 40, 50, and 60 C. The data were compared with the predicted data of Yen-Woods and Multifluid models. The accuracy of the predictions of the Yen-Woods model was rather poor while that of the Multifluid model was very encouraging.

  13. Ind. Eng. Chem. Res. 1996,34, 4395-4405 4396 Multiple Steady States and Instability in Distillation. Implications

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Ind. Eng. Chem. Res. 1996,34, 4395-4405 4396 Multiple Steady States and Instability in Distillation-7034 Trondheim, Norway The fact that distillation columns, even in the ideal binary case, may display addresses some implications of these phenomena for the operation and control of distillation columns. Under

  14. Design of Hybrid Distillation-Vapor Membrane Separation Systems. Jose A. Caballero*; Ignacio E. Grossmann **; Majid Keyvani+

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Design of Hybrid Distillation-Vapor Membrane Separation Systems. Jose A. Caballero*; Ignacio E (ethane, propane) on a commercial scale is performed almost exclusively by cryogenic distillation to optimize and retrofit a hybrid separation system consisting of a distillation column and a parallel

  15. LA DISTILLATION a t introduite en Occident avec l'alchimie au cours du XIIe sicle. Par convention, on

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    LA DISTILLATION a été introduite en Occident avec l'alchimie au cours du XIIe siècle. Par Pseudo-Geber, distingue plusieurs façons de distiller et propose même une classi- fication de ces distillat (per descensum). La distillation par élévation des vapeurs, ou per ascensum, nécessite l

  16. MODELING, IDENTIFICATION AND CONTROL, 2000, VOL. 21, NO. 2, 83103 Evaluation of Dynamic Models of Distillation Columns with Emphasis

    E-Print Network [OSTI]

    Skogestad, Sigurd

    of Distillation Columns with Emphasis on the Initial Response BERND WITTGENS and SIGURD SKOGESTAD* Keywords: Distillation dynamics, tray hydraulics, experimental response The flow dynamics (tray hydraulics) are of key importance for the initial dynamic response of distillation columns. The most important parameters

  17. JMLR: Workshop and Conference Proceedings 29:116, 2014 ACML 2014 Sample Distillation for Object Detection and Image

    E-Print Network [OSTI]

    Fleuret, François

    JMLR: Workshop and Conference Proceedings 29:1­16, 2014 ACML 2014 Sample Distillation for Object different computer vision problems. First, we show that distillation can be used to improve the traditional bootstrap- ping approach to object detection. Second, we apply distillation to a classification problem

  18. Can the Operating Leaves of a Distillation Column Really Be Tshepo S. Modise, Michaela Tapp, Diane Hildebrandt,* and David Glasser

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Can the Operating Leaves of a Distillation Column Really Be Expanded? Tshepo S. Modise, Michaela to determine the operation leaves and hence the feasible region for distillation columns operating at a specific distillate and bottoms composition for all possible constant reflux and reboil ratios

  19. Measurement Reconciliation and Interpretation in Packed Distillation Column Operation Teck C. Lee and Colin S. Howat, Ph.D.

    E-Print Network [OSTI]

    Howat, Colin S. "Chip"

    . To overcome this limitation, a pilot plant scale, packed distillation column was designed, built, and tested plant scale, packed distillation column was designed, built, and tested. This column can be operatedMeasurement Reconciliation and Interpretation in Packed Distillation Column Operation Teck C. Lee

  20. An Adaptive Entanglement Distillation Scheme Using Quantum Low Density Parity Check Codes

    E-Print Network [OSTI]

    K. H. Ho; H. F. Chau

    2008-07-14T23:59:59.000Z

    Quantum low density parity check (QLDPC) codes are useful primitives for quantum information processing because they can be encoded and decoded efficiently. Besides, the error correcting capability of a few QLDPC codes exceeds the quantum Gilbert-Varshamov bound. Here, we report a numerical performance analysis of an adaptive entanglement distillation scheme using QLDPC codes. In particular, we find that the expected yield of our adaptive distillation scheme to combat depolarization errors exceed that of Leung and Shor whenever the error probability is less than about 0.07 or greater than about 0.28. This finding illustrates the effectiveness of using QLDPC codes in entanglement distillation.

  1. Lower Bound of Concurrence and Distillation for Arbitrary Dimensional Bipartite Quantum States

    E-Print Network [OSTI]

    Zhao, Ming-Jing; Fei, Shao-Ming; Li-Jost, Xianqing; 10.1103/PhysRevA.84.062322

    2011-01-01T23:59:59.000Z

    We present a lower bound of concurrence for arbitrary dimensional bipartite quantum states. This lower bound may be used to improve all the known lower bounds of concurrence. Moreover, the lower bound gives rise to an operational sufficient criterion of distillability of quantum entanglement. The significance of our result is illustrated by quantitative evaluation of entanglement for entangled states that fail to be identified by the usual concurrence estimation method, and by showing the distillability of mixed states that can not be recognized by other distillability criteria.

  2. On the distillation and purification of phase-diffused squeezed states

    E-Print Network [OSTI]

    B. Hage; A. Franzen; J. DiGuglielmo; P. Marek; J. Fiurášek; R. Schnabel

    2007-07-17T23:59:59.000Z

    Recently it was discovered that non-Gaussian decoherence processes, such as phase-diffusion, can be counteracted by purification and distillation protocols that are solely built on Gaussian operations. Here, we make use of this experimentally highly accessible regime, and provide a detailed experimental and theoretical analysis of several strategies for purification/distillation protocols on phase-diffused squeezed states. Our results provide valuable information for the optimization of such protocols with respect to the choice of the trigger quadrature, the trigger threshold value and the probability of generating a distilled state.

  3. Lower Bound of Concurrence and Distillation for Arbitrary Dimensional Bipartite Quantum States

    E-Print Network [OSTI]

    Ming-Jing Zhao; Xue-Na Zhu; Shao-Ming Fei; Xianqing Li-Jost

    2011-12-23T23:59:59.000Z

    We present a lower bound of concurrence for arbitrary dimensional bipartite quantum states. This lower bound may be used to improve all the known lower bounds of concurrence. Moreover, the lower bound gives rise to an operational sufficient criterion of distillability of quantum entanglement. The significance of our result is illustrated by quantitative evaluation of entanglement for entangled states that fail to be identified by the usual concurrence estimation method, and by showing the distillability of mixed states that can not be recognized by other distillability criteria.

  4. Quantum repeaters and quantum key distribution: the impact of entanglement distillation on the secret key rate

    E-Print Network [OSTI]

    Sylvia Bratzik; Silvestre Abruzzo; Hermann Kampermann; Dagmar Bruß

    2013-03-14T23:59:59.000Z

    We investigate quantum repeaters in the context of quantum key distribution. We optimize the secret key rate per memory per second with respect to different distillation protocols and distillation strategies. For this purpose, we also derive an analytical expression for the average number of entangled pairs created by the quantum repeater, including classical communication times for entanglement swapping and entanglement distillation. We investigate the impact of this classical communication time on the secret key rate. We finally study the effect of the detector efficiency on the secret key rate.

  5. Distillation sequence for the purification and recovery of hydrocarbons

    DOE Patents [OSTI]

    Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

    2007-12-25T23:59:59.000Z

    This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

  6. Comparison of advanced distillation control methods. Second annual report

    SciTech Connect (OSTI)

    NONE

    1996-11-01T23:59:59.000Z

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to study the issue of configuration selection for diagonal PI dual composition controls. ATV identification with on-line detuning was used for tuning the diagonal PI composition controllers. Each configuration was evaluated with respect to steady-state RGA values, sensitivity to feed composition changes, and open loop dynamic performance. Each configuration was tuned using setpoint changes over a wider range of operation for robustness and tested for feed composition upsets. Overall, configuration selection was shown to have a dominant effect upon control performance. Configuration analysis tools (e.g., RGA, condition number, disturbance sensitivity), were found to reject configuration choices that are obviously poor choices, but were unable to critically differentiate between the remaining viable choices. Configuration selection guidelines are given although it is demonstrated that the most reliable configuration selection approach is based upon testing the viable configurations using dynamic column simulators.

  7. Comparison of advanced distillation control methods. Second annual report

    SciTech Connect (OSTI)

    Riggs, J.B.

    1996-11-01T23:59:59.000Z

    Detailed dynamic simulations of two industrial distillation columns (a propylene/propane splitter and a xylene/toluene column) have been used to study the issue of configuration selection for diagonal PI dual composition controls. Auto Tune Variation (ATV) identification with on-line detuning was used for tuning the diagonal proportional integral (PI) composition controls. Each configuration was evaluated with respect to steady-state relative gain array (RGA) values, sensitivity to feed composition changes, and open loop dynamic performance. Each configuration was tuned using setpoint changes over a wider range of operation for robustness and tested for feed composition upsets. Overall, configuration selection was shown to have a dominant effect upon control performance. Configuration analysis tools (e.g., RGA, condition number, disturbance sensitivity) were found to reject configuration choices that are obviously poor choices, but were unable to critically differentiate between the remaining viable choices. Configuration selection guidelines are given although it is demonstrated that the most reliable configuration selection approach is based upon testing the viable configurations using dynamic column simulators.

  8. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation 

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    Simulation study has shown oil production is accelerated when propane is used as an additive during steam injection. To better understand this phenomenon, distillation experiments were performed using San Ardo crude oil (12oAPI). For comparison...

  9. Water distillation using waste engine heat from an internal combustion engine

    E-Print Network [OSTI]

    Mears, Kevin S

    2006-01-01T23:59:59.000Z

    To meet the needs of forward deployed soldiers and disaster relief personnel, a mobile water distillation system was designed and tested. This system uses waste engine heat from the exhaust flow of an internal combustion ...

  10. Multipartite continuous-variable entanglement distillation using local squeezing and only one photon-subtraction operation

    E-Print Network [OSTI]

    Song Yang; XuBo Zou; ShengLi Zhang; Bao-Sen Shi; Peter van Loock; GuangCan Guo

    2011-06-08T23:59:59.000Z

    In this paper, we study entanglement distillation of multipartite continuous-variable Gaussian entangled states. Following Opatrn\\'{y} \\emph{et al.}'s photon subtraction (PS) scheme, the probability of successful distillation decreases exponentially with the number of parties $N$. However, here, we shall propose an entanglement distillation scheme whose success probability scales as a constant with $N$. Our protocol employs several local squeezers, but it requires only a single PS operation. Using the logarithmic negativity as a measure of entanglement, we find that both the success probability and the distilled entanglement can be improved at the same time. Moreover, an $N$-mode transfer theorem (transferring states from phase space to Hilbert space) is presented.

  11. Feeding Value of Wet Sorghum Distillers Grains for Growing and Finishing Beef Cattle

    E-Print Network [OSTI]

    Feeding Value of Wet Sorghum Distillers Grains for Growing and Finishing Beef Cattle Ethanol, but sorghum grain is commonly either blended with corn before use or used as the sole grain for ethanol

  12. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    132.9 1,418.3 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  13. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    839.2 135.0 1,251.9 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  14. DYNAMIC MODELING AND CONTROL OF REACTIVE DISTILLATION FOR HYDROGENATION OF BENZENE 

    E-Print Network [OSTI]

    Aluko, Obanifemi

    2010-01-16T23:59:59.000Z

    This work presents a modeling and control study of a reactive distillation column used for hydrogenation of benzene. A steady state and a dynamic model have been developed to investigate control structures for the column. The most important aspects...

  15. Distillation: Energy Savings and Other Benefits From the Use of High Efficiency Packings

    E-Print Network [OSTI]

    Bravo, J. L.; Fair, J. R.; Humphrey, J. L.

    DISTILLATION: ENERGY SAVINGS AND OTHER BENEFITS. FROM THE USE OF HIGH-EFFICIENCY PACKINGS -. Jose L. Bravo, James R. Fair, and Jimmy L. Humpnrey The University of Texas at Austin Austin, Texas ABSTRACT A great deal of attention has been... focused lately on the use of high-efficiency packings for distillation applications. This paper discusses benefits that can be derived from the use of these devices. In parti~ular, the reduction in energy requirements for a given separation...

  16. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    EXPERIMENTAL AND ANALYTICAL STUDIES OF HYDROCARBON YIELDS UNDER DRY-, STEAM-, AND STEAM-WITH- PROPANE DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University...-WITH- PROPANE-DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved...

  17. Utilization of Structured Packing for Energy Savings in Distillation and Absorption Columns

    E-Print Network [OSTI]

    Berven, O. J.; Howard, W. E.

    "UTILIZATION OF STRUCTURED PACKING FOR ENERGY SAVINGS IN DISTILLATION AND ABSORPTION COLUMNS" O. Jeffrey Berven and Wendell E. Howard Koch Engineering Company, Inc. Wi chita, Kansas As the need to reduce production costs causes... manufacturers to re-evaluate process ing schemes, hi gh efficiency structured packings are increasingly recognized as an effective alternative for reducing energy consumption in heat and mass transfer operations. In distillation, the high efficiency and low...

  18. The Scaleup of Structured Packing from Distillation Pilot Plant Testing to Commercial Application

    E-Print Network [OSTI]

    Berven, O. J.; Ulowetz, M. A.

    The Scaleup of Structured Packing From Distillation Pilot Plant Testing to Commercial Application O. Jeffrey'Berven and Michael A. Ulowetz Koch Engineering Company, Inc. Wichita, Kansas Structured packing is being utilized more and more... in the process industry for increased efficiency, greater capacity, and energy savings in distillation columns. Pilot plant testing of the actual chemical system using commercially available structured packing is invaluable, but years of experience in pilot...

  19. PILOT-SCALE REMOVAL OF FLUORIDE FROM LEGACY PLUTONIUM MATERIALS USING VACUUM SALT DISTILLATION

    SciTech Connect (OSTI)

    Pierce, R. A.; Pak, D. J.

    2012-09-11T23:59:59.000Z

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000{deg}C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition.

  20. Comparison of Advanced Distillation Control Methods, Final Technical Report

    SciTech Connect (OSTI)

    Dr. James B. Riggs

    2000-11-30T23:59:59.000Z

    Detailed dynamic simulations of three industrial distillation columns (a propylene/propane splitter, a xylene/toluene column, and a depropanizer) have been used to evaluate configuration selections for single-ended and dual-composition control, as well as to compare conventional and advanced control approaches. In addition, a simulator of a main fractionator was used to compare the control performance of conventional and advanced control. For each case considered, the controllers were tuned by using setpoint changes and tested using feed composition upsets. Proportional Integral (PI) control performance was used to evaluate the configuration selection problem. For single ended control, the energy balance configuration was found to yield the best performance. For dual composition control, nine configurations were considered. It was determined that the use of dynamic simulations is required in order to identify the optimum configuration from among the nine possible choices. The optimum configurations were used to evaluate the relative control performance of conventional PI controllers, MPC (Model Predictive Control), PMBC (Process Model-Based Control), and ANN (Artificial Neural Networks) control. It was determined that MPC works best when one product is much more important than the other, while PI was superior when both products were equally important. PMBC and ANN were not found to offer significant advantages over PI and MPC. MPC was found to outperform conventional PI control for the main fractionator. MPC was applied to three industrial columns: one at Phillips Petroleum and two at Union Carbide. In each case, MPC was found to significantly outperform PI controls. The major advantage of the MPC controller is its ability to effectively handle a complex set of constraints and control objectives.

  1. Residuals, Sludge, and Composting (Maine)

    Broader source: Energy.gov [DOE]

    The Maine Department of Environmental Protection's Residuals, Sludge, and Composting program regulates the land application and post-processing of organic wastes, including sewage sludge, septage,...

  2. DEVELOPMENT AND DEPLOYMENT OF VACUUM SALT DISTILLATION AT THE SAVANNAH RIVER SITE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.; Edwards, T.

    2010-10-28T23:59:59.000Z

    The Savannah River Site has a mission to dissolve fissile materials and disposition them. The primary fissile material is plutonium dioxide (PuO{sub 2}). To support dissolution of these materials, the Savannah River National Laboratory (SRNL) designed and demonstrated a vacuum salt distillation (VSD) apparatus using both representative radioactive samples and non-radioactive simulant materials. Vacuum salt distillation, through the removal of chloride salts, increases the quantity of materials suitable for processing in the site's HB-Line Facility. Small-scale non-radioactive experiments at 900-950 C show that >99.8 wt % of the initial charge of chloride salt distilled from the sample boat with recovery of >99.8 wt % of the ceric oxide (CeO{sub 2}) - the surrogate for PuO{sub 2} - as a non-chloride bearing 'product'. Small-scale radioactive testing in a glovebox demonstrated the removal of sodium chloride (NaCl) and potassium chloride (KCl) from 13 PuO{sub 2} samples. Chloride concentrations were distilled from a starting concentration of 1.8-10.8 wt % to a final concentration <500 mg/kg chloride. Initial testing of a non-radioactive, full-scale production prototype is complete. A designed experiment evaluated the impact of distillation temperature, time at temperature, vacuum, product depth, and presence of a boat cover. Significant effort has been devoted to mechanical considerations to facilitate simplified operation in a glovebox.

  3. The cough response to ultrasonically nebulized distilled water in heart-lung transplantation patients

    SciTech Connect (OSTI)

    Higenbottam, T.; Jackson, M.; Woolman, P.; Lowry, R.; Wallwork, J.

    1989-07-01T23:59:59.000Z

    As a result of clinical heart-lung transplantation, the lungs are denervated below the level of the tracheal anastomosis. It has been questioned whether afferent vagal reinnervation occurs after surgery. Here we report the cough frequency, during inhalation of ultrasonically nebulized distilled water, of 15 heart-lung transplant patients studied 6 wk to 36 months after surgery. They were compared with 15 normal subjects of a similar age and sex. The distribution of the aerosol was studied in five normal subjects using /sup 99m/technetium diethylene triamine pentaacetate (/sup 99m/Tc-DTPA) in saline. In seven patients, the sensitivity of the laryngeal mucosa to instilled distilled water (0.2 ml) was tested at the time of fiberoptic bronchoscopy by recording the cough response. Ten percent of the aerosol was deposited onto the larynx and trachea, 56% on the central airways, and 34% in the periphery of the lung. The cough response to the aerosol was strikingly diminished in the patients compared with normal subjects (p less than 0.001), but all seven patients coughed when distilled water was instilled onto the larynx. As expected, the laryngeal mucosa of heart-lung transplant patients remains sensitive to distilled water. However, the diminished coughing when the distilled water is distributed by aerosol to the central airways supports the view that vagal afferent nerves do not reinnervate the lungs after heart-lung transplantation, up to 36 months after surgery.

  4. First Commissioning of a Cryogenic Distillation Column for Low Radioactivity Underground Argon

    E-Print Network [OSTI]

    Back, Henning O; Alton, Andrew; Condon, Christopher; de Haas, Ernst; Galbiati, Cristiano; Goretti, Augusto; Hohmann, Tristan; Ianni, Andrea; Kendziora, Cary; Loer, Ben; Montanari, David; Mosteiro, Pablo; Pordes, Stephen

    2012-01-01T23:59:59.000Z

    We report on the performance and commissioning of a cryogenic distillation column for low radioactivity underground argon at Fermi National Accelerator Laboratory. The distillation column is designed to accept a mixture of argon, helium, and nitrogen and return pure argon with a nitrogen contamination less than 10 ppm. In the first commissioning, we were able to run the distillation column in a continuous mode and produce argon that is 99.9% pure. After running in a batch mode, the argon purity was increased to 99.95%, with 500 ppm of nitrogen remaining. The efficiency of collecting the argon from the gas mixture was between 70% and 81%, at an argon production rate of 0.84-0.98 kg/day.

  5. First Commissioning of a Cryogenic Distillation Column for Low Radioactivity Underground Argon

    E-Print Network [OSTI]

    H. O. Back; T. Alexander; A. Alton; C. Condon; E. de Haas; C. Galbiati; A. Goretti; T. Hohmann; An. Ianni; C. Kendziora; B. Loer; D. Montanari; P. Mosteiro; S. Pordes

    2012-05-01T23:59:59.000Z

    We report on the performance and commissioning of a cryogenic distillation column for low radioactivity underground argon at Fermi National Accelerator Laboratory. The distillation column is designed to accept a mixture of argon, helium, and nitrogen and return pure argon with a nitrogen contamination less than 10 ppm. In the first commissioning, we were able to run the distillation column in a continuous mode and produce argon that is 99.9% pure. After running in a batch mode, the argon purity was increased to 99.95%, with 500 ppm of nitrogen remaining. The efficiency of collecting the argon from the gas mixture was between 70% and 81%, at an argon production rate of 0.84-0.98 kg/day.

  6. Magic state distillation in all prime dimensions using quantum Reed-Muller codes

    E-Print Network [OSTI]

    Campbell, Earl T; Browne, Dan E

    2012-01-01T23:59:59.000Z

    We propose families of protocols for magic state distillation -- important components of fault tolerance schemes --- for systems of odd prime dimension. Our protocols utilize quantum Reed-Muller codes with transversal non-Clifford gates. We find that in higher dimensions smaller codes can be used than one might expect based on qubit codes. All our protocols produce magic states at a resource cost that increases only polynomially with the inverse of the final ouput error probability. We give specific details for 3-dimensional systems, where we find that certain magic states can be distilled provided an initial error probability of less than 20.02% or a depolarizing noise rate of less than 31.7%. This is the largest error probability threshold of all known protocols with polynomial resource cost. For a depolarizing noise model we also give distillation thresholds for odd prime dimensions up-to 19.

  7. Source book for planning nuclear dual-purpose electric/distillation desalination plants

    SciTech Connect (OSTI)

    Reed, S.A.

    1981-02-01T23:59:59.000Z

    A source book on nuclear dual-purpose electric/distillation desalination plants was prepared to assist government and other planners in preparing broad evaluations of proposed applications of dual-purpose plants. The document is divided into five major sections. Section 1 presents general discussions relating to the benefits of dual-purpose plants, and spectrum for water-to-power ratios. Section 2 presents information on commercial nuclear plants manufactured by US manufacturers. Section 3 gives information on distillation desalting processes and equipment. Section 4 presents a discussion on feedwater pretreatment and scale control. Section 5 deals with methods for coupling the distillation and electrical generating plants to operate in the dual mode.

  8. Systems and methods for reactive distillation with recirculation of light components

    DOE Patents [OSTI]

    Stickney, Michael J. (Nassau Bay, TX); Jones, Jr., Edward M. (Friendswood, TX)

    2011-07-26T23:59:59.000Z

    Systems and methods for producing gas-to-liquids products using reactive distillation are provided. The method for producing gas-to-liquids products can include reacting a feedstock in a column having a distillation zone and a reaction zone to provide a bottoms stream and an overhead stream. A first portion of the overhead stream can be recycled to the column at the top of the reaction zone and second portion of the overhead stream can be recycled to the column at the bottom of the reaction zone.

  9. Z-States Algebra for a Tunable Multi-Party Entanglement-Distillation Protocol

    E-Print Network [OSTI]

    Exman, Iaakov

    2011-01-01T23:59:59.000Z

    W-States have achieved the status of the standard fully symmetric entangled states, for many entanglement application purposes. Z-States are a generalization of W-States that display an elegant algebra, enabling short paths to desired results. This paper describes Z-States algebra starting from neat definitions and laying down explicitly some fundamental theorems on composition and distillation, needed for applications. These theorems are synthesized into a generic tunable Entanglement-Distillation Protocol. Applications are readily developed based upon the tunable protocol. A few examples are provided to illustrate the approach generality. A concomitant graphical representation allows fast comprehension of the protocol inputs, operations and outcomes.

  10. Process for converting heavy oil deposited on coal to distillable oil in a low severity process

    DOE Patents [OSTI]

    Ignasiak, Teresa (417 Heffernan Drive, Edmonton, Alberta, CA); Strausz, Otto (13119 Grand View Drive, Edmonton, Alberta, CA); Ignasiak, Boleslaw (417 heffernan Drive, Edmonton, Alberta, CA); Janiak, Jerzy (17820 - 76 Ave., Edmonton, Alberta, CA); Pawlak, Wanda (3046 - 11465 - 41 Avenue, Edmonton, Alberta, CA); Szymocha, Kazimierz (3125 - 109 Street, Edmonton, Alberta, CA); Turak, Ali A. (Edmonton, CA)

    1994-01-01T23:59:59.000Z

    A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

  11. The Products of the Destructive Distillation of Keratin in the Form of Leather

    E-Print Network [OSTI]

    Rose, Reed Phillips

    1913-01-01T23:59:59.000Z

    ure to the air. After this came a white crystal­ line solid, fourth a reddish fciquid, fifth a red­ dish crystalline compound and sixth the black oil spoken of abovd. A volume of the distillate, equaling about a liter was collected and the two... the material the temperature rose to 200° C. and then reduction started and the temperature fell rapidly. The tar or oil constitutes from 3 to 4 per cent of the weight of the leather used. The aqueous portion of the distillate was subjected to a fractional...

  12. Chemical Characterization of Individual Particles and Residuals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Individual Particles and Residuals of Cloud Droplets and Ice Crystals Collected On Board Research Chemical Characterization of Individual Particles and Residuals of Cloud Droplets...

  13. Entanglement Distillation; A Discourse on Bound Entanglement in Quantum Information Theory

    E-Print Network [OSTI]

    Lieven Clarisse

    2006-12-10T23:59:59.000Z

    PhD thesis (University of York). The thesis covers in a unified way the material presented in quant-ph/0403073, quant-ph/0502040, quant-ph/0504160, quant-ph/0510035, quant-ph/0512012 and quant-ph/0603283. It includes two large review chapters on entanglement and distillation.

  14. Hybrid magic state distillation for universal fault-tolerant quantum computation

    E-Print Network [OSTI]

    Wenqiang Zheng; Yafei Yu; Jian Pan; Jingfu Zhang; Jun Li; Zhaokai Li; Dieter Suter; Xianyi Zhou; Xinhua Peng; Jiangfeng Du

    2014-12-11T23:59:59.000Z

    A set of stabilizer operations augmented by some special initial states known as 'magic states', gives the possibility of universal fault-tolerant quantum computation. However, magic state preparation inevitably involves nonideal operations that introduce noise. The most common method to eliminate the noise is magic state distillation (MSD) by stabilizer operations. Here we propose a hybrid MSD protocol by connecting a four-qubit H-type MSD with a five-qubit T-type MSD, in order to overcome some disadvantages of the previous MSD protocols. The hybrid MSD protocol further integrates distillable ranges of different existing MSD protocols and extends the T-type distillable range to the stabilizer octahedron edges. And it provides considerable improvement in qubit cost for almost all of the distillable range. Moreover, we experimentally demonstrate the four-qubit H-type MSD protocol using nuclear magnetic resonance technology, together with the previous five-qubit MSD experiment, to show the feasibility of the hybrid MSD protocol.

  15. Distillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Grak (Editors)

    E-Print Network [OSTI]

    Lucia, Angelo

    .al. The focus of this study is the stripping column. Table 1 gives some typical design results for the strippingDistillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Górak (Editors) All rights reserved by authors as per DA2010 copyright notice ENERGY EFFICIENT SYNTHESIS AND DESIGN FOR CARBON CAPTURE Angelo

  16. Minimum Energy Consumption in Multicomponent Distillation. 3. More Than Three Products and Generalized Petlyuk Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Minimum Energy Consumption in Multicomponent Distillation. 3. More Than Three Products products (where normally M e N). We derive the expressions for a generalized extended Pet- lyuk arrangement for the generalized Pet- lyuk column with more than three products. The Vmin diagram was presented in part 1

  17. Effects of petroleum distillate on viscosity, density and surface tension of intermediate and heavy crude oils

    E-Print Network [OSTI]

    Abdullayev, Azer

    2009-06-02T23:59:59.000Z

    : San Francisco oil from Columbia with specific gravity of 28o-29o API, Duri oil with gravity of 19o-21o API, Jobo oil with gravity of 8o-9o API and San Ardo oil gravity of 11o-13o API. The additive used in all of the experiments is petroleum distillate...

  18. Distillate fuel-oil processing for phosphoric acid fuel-cell power plants

    SciTech Connect (OSTI)

    Ushiba, K. K.

    1980-02-01T23:59:59.000Z

    The current efforts to develop distillate oil-steam reforming processes are reviewed, and the applicability of these processes for integration with the fuel cell are discussed. The development efforts can be grouped into the following processing approaches: high-temperature steam reforming (HTSR); autothermal reforming (ATR); autothermal gasification (AG); and ultra desulfurization followed by steam reforming. Sulfur in the feed is a key problem in the process development. A majority of the developers consider sulfur as an unavoidable contaminant of distillate fuel and are aiming to cope with it by making the process sulfur-tolerant. In the HTSR development, the calcium aluminate catalyst developed by Toyo Engineering represents the state of the art. United Technology (UTC), Engelhard, and Jet Propulsion Laboratory (JPL) are also involved in the HTSR research. The ATR of distillate fuel is investigated by UTC and JPL. The autothermal gasification (AG) of distillate fuel is being investigated by Engelhard and Siemens AG. As in the ATR, the fuel is catalytically gasified utilizing the heat generated by in situ partial combustion of feed, however, the goal of the AG is to accomplish the initial breakdown of the feed into light gases and not to achieve complete conversion to CO and H/sub 2/. For the fuel-cell integration, a secondary reforming of the light gases from the AG step is required. Engelhard is currently testing a system in which the effluent from the AG section enters the steam-reforming section, all housed in a single vessel. (WHK)

  19. Black-Box Identification for PLC based MPC of a Binary Distillation Column

    E-Print Network [OSTI]

    Black-Box Identification for PLC based MPC of a Binary Distillation Column B. Huyck ,, F. Logist J is to upgrade the control system with a linear MPC running on a PLC. However, before a model based controller can be used on a PLC, an accurate (but simple) process model has to be constructed. Hence, the aim

  20. Effect of Narrow Cut Oil Shale Distillates on HCCI Engine Performance

    SciTech Connect (OSTI)

    Eaton, Scott J [ORNL; Bunting, Bruce G [ORNL; Lewis Sr, Samuel Arthur [ORNL; Fairbridge, Craig [National Centre for Upgrading Technology, Canada

    2009-01-01T23:59:59.000Z

    In this investigation, oil shale crude obtained from the Green River Formation in Colorado using Paraho Direct retorting was mildly hydrotreated and distilled to produce 7 narrow boiling point fuels of equal volumes. The resulting derived cetane numbers ranged between 38.3 and 43.9. Fuel chemistry and bulk properties strongly correlated with boiling point.

  1. DISSOLUTION OF NEPTUNIUM OXIDE RESIDUES

    SciTech Connect (OSTI)

    Kyser, E

    2009-01-12T23:59:59.000Z

    This report describes the development of a dissolution flowsheet for neptunium (Np) oxide (NpO{sub 2}) residues (i.e., various NpO{sub 2} sources, HB-Line glovebox sweepings, and Savannah River National Laboratory (SRNL) thermogravimetric analysis samples). Samples of each type of materials proposed for processing were dissolved in a closed laboratory apparatus and the rate and total quantity of off-gas were measured. Samples of the off-gas were also analyzed. The quantity and type of solids remaining (when visible) were determined after post-dissolution filtration of the solution. Recommended conditions for dissolution of the NpO{sub 2} residues are: Solution Matrix and Loading: {approx}50 g Np/L (750 g Np in 15 L of dissolver solution), using 8 M nitric acid (HNO{sub 3}), 0.025 M potassium fluoride (KF) at greater than 100 C for at least 3 hours. Off-gas: Analysis of the off-gas indicated nitric oxide (NO), nitrogen dioxide (NO{sub 2}) and nitrous oxide (N{sub 2}O) as the only identified components. No hydrogen (H{sub 2}) was detected. The molar ratio of off-gas produced per mole of Np dissolved ranged from 0.25 to 0.4 moles of gas per mole of Np dissolved. A peak off-gas rate of {approx}0.1 scfm/kg bulk oxide was observed. Residual Solids: Pure NpO{sub 2} dissolved with little or no residue with the proposed flowsheet but the NpCo and both sweepings samples left visible solid residue after dissolution. For the NpCo and Part II Sweepings samples the residue amounted to {approx}1% of the initial material, but for the Part I Sweepings sample, the residue amounted to {approx}8 % of the initial material. These residues contained primarily aluminum (Al) and silicon (Si) compounds that did not completely dissolve under the flowsheet conditions. The residues from both sweepings samples contained minor amounts of plutonium (Pu) particles. Overall, the undissolved Np and Pu particles in the residues were a very small fraction of the total solids.

  2. Submitted to special issue ChERD. This version revised 22 Nov. 2006 The dos and don'ts of distillation column control

    E-Print Network [OSTI]

    Skogestad, Sigurd

    'ts of distillation column control Sigurd Skogestad* Department of Chemical Engineering Norwegian University of Science and Technology N-7491 Trondheim, Norway Abstract The paper discusses distillation column control recommendations to assist the engineer in designing control systems for distillation columns. The standard LV

  3. Start | Grid View | Browse by Day OR Group/Topical | Author Index | Keyword Index | Personal Scheduler Active Constraint Regions for Economically Optimal Operation of Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Scheduler Active Constraint Regions for Economically Optimal Operation of Distillation Columns Tuesday and operation of distillation columns has been widely studied, as illustrated by for example Skogestad (1993 operation of distillation columns has been studied relatively little. The issue of active constraints

  4. Distillation of Bose-Einstein condensates in a double-well potential The characteristic feature of Bose-Einstein condensation is the accumulation of a

    E-Print Network [OSTI]

    Distillation of Bose-Einstein condensates in a double-well potential The characteristic feature by preparing a Bose-Einstein condensate in an optical dipole trap and distilling it into a second empty dipole trap adjacent to the first one [2]. The distillation was driven by thermal atoms spilling over

  5. Wang Feng (2006). Comparison of languages in contact: The distillation method and the case of Bai. Language and linguistics monograph series B, Frontiers in linguistics III.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    2006-01-01T23:59:59.000Z

    Wang Feng (2006). Comparison of languages in contact: The distillation method and the case of Bai; Zhengzhang 2003). Wang Feng's Comparison of languages in contact: The distillation method and the case of Bai 2001). In Comparison of languages in contact: The distillation method and the case of Bai, Wang

  6. Start | Grid View | Browse by Day OR Group/Topical | Author Index | Keyword Index | Personal Scheduler Optimal Design of Energy-Efficient Integrated Distillation Processes for

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Scheduler Optimal Design of Energy-Efficient Integrated Distillation Processes for Multicomponent Ideal Optimal design of energy-efficient integrated distillation processes for multicomponent ideal and non, The Netherlands The dividing wall distillation columns (DWC) find increased use in industrial practice

  7. Residual activation of accelerator components

    SciTech Connect (OSTI)

    Rakhno, I.L.; Mokhov, N.V.; Striganov, S.I.; /Fermilab

    2008-02-01T23:59:59.000Z

    A method to calculate residual activation of accelerator components is presented. A model for residual dose estimation for thick objects made of arbitrary composite materials for arbitrary irradiation and cooling times is employed in this study. A scaling procedure is described to apply the model to thin objects with linear dimensions less than a fraction of a nuclear interaction length. The scaling has been performed for various materials and corresponding factors have been determined for objects of certain shapes (slab, solid and hollow cylinder) that can serve as models for beam pipes, magnets and collimators. Both contact residual dose and dose attenuation in the air outside irradiated objects are considered. A relation between continuous and impulse irradiation is accounted for as well.

  8. Structural group analysis of residues from Athabasca bitumen

    SciTech Connect (OSTI)

    Gray, M.R.; Choi, J.H.K.; Egiebor, N.O.; Kirchen, R.P.; Sanford, E.C.

    1988-06-01T23:59:59.000Z

    Non-distillable fractions of hydrocarbons such as bitumen are a challenge for analysis because of their molecular complexity and high heteroatom content. One method for characterizing their composition is by analysis for a relatively small number of structures expected to predominate in the mixture, i.e. for the significant structural groups. Because NMR spectroscopy can give quantitative data on the distribution of hydrogen and carbon types, it is an ideal method for group-based analysis. This study uses a structural group formalism which combines data from several analytical methods into a single profile. Residue fractions derived from Athabasca bitumen were investigated to determine the different chemical structures which could have an impact on subsequent processing. Structural analysis is the identification of key structures from analytical data that characterize a complex mixture. Higher accuracy data, from elemental, /sup 1/H-NMR, IR and titration analyses, are used to construct balance equations which must be satisfied. The spectral envelope of /sup 13/C-NMR is more difficult to resolve quantatitively, and hence /sup 13/C-NMR data are used as constraints to compute the concentrations of structural groups. The mathematical notation and methods have been presented previously. The structural analysis transforms the spectrometric data into a more useable form; the maximum number of groups that can be calculated is limited to the number of useful analytical measurements.

  9. Future perspectives of using hollow fibers as structured packings in light hydrocarbon distillation

    SciTech Connect (OSTI)

    Yang, Dali [Los Alamos National Laboratory; Orler, Bruce [Los Alamos National Laboratory; Tornga, Stephanie [Los Alamos National Laboratory; Welch, Cindy [Los Alamos National Laboratory

    2011-01-26T23:59:59.000Z

    Olefin and paraffin are the largest chemical commodities. Furthermore, they are major building blocks for the petrochemical industry. Each year, petroleum refining, consumes 4,500 TBtu/yr in separation energy, making it one of the most energy-intensive industries in the United States). Just considering liquefied petroleum gas (ethane/propane/butane) and olefins (ethylene and propylene) alone, the distillation energy consumption is about 400 TBtu/yr in the US. Since petroleum distillation is a mature technology, incremental improvements in column/tray design will only provide a few percent improvements in the performance. However, each percent saving in net energy use amounts to savings of 10 TBtu/yr and reduces CO{sub 2} emissions by 0.2 MTon/yr. In practice, distillation columns require 100 to 200 trays to achieve the desired separation. The height of a transfer unit (HTU) of conventional packings is typical in the range of 36-60 inch. Since 2006, we had explored using several non-selective membranes as the structured packings to replace the conventional packing materials used in propane and propylene distillation. We obtained the lowest HTU of < 8 inch for the hollow fiber column, which was >5 times shorter than that of the conventional packing materials. In 2008, we also investigated this type of packing materials in iso-/n-butane distillation. Because of a slightly larger relative volatility of iso-/n-butane than that of propane/propylene, a wider and a more stable operational range was obtained for the iso-/n-butane pair. However, all of the experiments were conducted on a small scale with flowrate of < 25 gram/min. Recently, we demonstrated this technology on a larger scale (<250 gram/min). Within the loading range of F-factor < 2.2 Pa{sup 0.5}, a pressure drop on the vapor side is below 50 mbar/m, which suggests that the pressure drop of hollow fibers packings is not an engineering barrier for the applications in distillations. The thermal stability study suggests that polypropylene hollow fibers are stable after a long time exposure to C{sub 2} - C{sub 4} mixtures. The effects of packing density on the separation efficiency will be discussed.

  10. APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.

    2011-08-10T23:59:59.000Z

    Vacuum distillation of chloride salts from plutonium oxide (PuO{sub 2}) and simulant PuO{sub 2} has been previously demonstrated at Department of Energy (DOE) sites using kilogram quantities of chloride salt. The apparatus for vacuum distillation contains a zone heated using a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attained, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile materials in the feed boat. The application of vacuum salt distillation (VSD) is of interest to the HB-Line Facility and the MOX Fuel Fabrication Facility (MFFF) at the Savannah River Site (SRS). Both facilities are involved in efforts to disposition excess fissile materials. Many of these materials contain chloride and fluoride salt concentrations which make them unsuitable for dissolution without prior removal of the chloride and fluoride salts. Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. Subsequent efforts are attempting to adapt the technology for the removal of fluoride. Fluoride salts of interest are less-volatile than the corresponding chloride salts. Consequently, an alternate approach is required for the removal of fluoride without significantly increasing the operating temperature. HB-Line Engineering requested SRNL to evaluate and demonstrate the feasibility of an alternate approach using both non-radioactive simulants and plutonium-bearing materials. Whereas the earlier developments targeted the removal of sodium chloride (NaCl) and potassium chloride (KCl), the current activities are concerned with the removal of the halide ions associated with plutonium trifluoride (PuF{sub 3}), plutonium tetrafluoride (PuF{sub 4}), calcium fluoride (CaF{sub 2}), and calcium chloride (CaCl{sub 2}). This report discusses non-radioactive testing of small-scale and pilot-scale systems and radioactive testing of a small-scale system. Experiments focused on demonstrating the chemistry for halide removal and addressing the primary engineering questions associated with a change in the process chemistry.

  11. Spinodal instabilities and the distillation effect in nuclear matter under strong magnetic fields

    E-Print Network [OSTI]

    A. Rabhi; C. Providencia; J. Da Providencia

    2008-11-19T23:59:59.000Z

    We study the effect of strong magnetic fields, of the order of $10^{18}$-$10^{19}$ G, on the instability region of nuclear matter at subsaturation densities. Relativistic nuclear models both with constant couplings and with density dependent parameters are considered. It is shown that a strong magnetic field can have large effects on the instability regions giving rise to bands of instability and wider unstable regions. As a consequence we predict larger transition densities at the inner edge of the crust of compact stars with strong magnetic field. The direction of instability gives rise to a very strong distillation effect if the last Landau level is only partially filled. However, for almost completed Landau levels an anti-distillation effect may occur.

  12. Negative Quasi-Probability Representation is a Necessary Resource for Magic State Distillation

    E-Print Network [OSTI]

    Veitch, Victor; Emerson, Joseph

    2012-01-01T23:59:59.000Z

    The magic state model of quantum computation gives a recipe for universal quantum computation using perfect Clifford operations and repeat preparations of a noisy ancilla state. It is an open problem to determine which ancilla states enable universal quantum computation in this model. Here we show that for systems of odd dimension a necessary condition for a state to enable universal quantum computation is that it have negative representation in a particular quasi-probability representation which is a discrete analogue to the Wigner function. This condition implies the existence of a large class of bound states for magic state distillation: states which cannot be prepared using Clifford operations but do not enable universal quantum computation. This condition also enables an efficient experimental test for distillability.

  13. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam with propane-distillation

    E-Print Network [OSTI]

    Ramirez Garnica, Marco Antonio

    2004-09-30T23:59:59.000Z

    from Instituto Mexicano del Petróleo (IMP), Dr. Fernando Rodriguez de la Garza, and Dr. Jose Luis Sanchez Bujanos from Petróleos Mexicanos (PEMEX), and Lawyer Rolando Rueda de Leon from Diario de Mexico, for their help and valuable advice. I would...-, and Steam with Propane-Distillation. (May 2004) Marco Antonio Ramírez-Garnica, B.S., Instituto Politécnico Nacional; M.S., Instituto Politécnico Nacional, México Chair of Advisory Committee: Dr. Daulat D. Mamora Recent experimental and simulation...

  14. Middle distillate hydrotreatment zeolite catalysts containing Pt/Pd or Ni

    E-Print Network [OSTI]

    Marin-Rosas, Celia

    2009-05-15T23:59:59.000Z

    was financially supported by Instituto Mexicano del Petroleo, Mexico. As a scholarship student, I would like to thank all managers for their help and services. The support provided by Dr. Kenneth Hall in the final step of my research when he was the department....S., Universidad Nacional Autonoma de Mexico, Mexico; M.S., Instituto Politecnico Nacional, Mexico Co-Chairs of Advisory Committee: Dr. Gilbert F. Froment Dr. Rayford G. Anthony A study on middle distillate hydrotreatment zeolite catalysts containing Pt...

  15. ,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources andPlant Liquids,+ LeasePrice SoldPlantGrossDistillateReserves+

  16. Energy Savings Accomplished by Replacing Steam Ejectors with Electric Driven Vacuum Pumps in Crude Distillation Vacuum Towers

    E-Print Network [OSTI]

    Nelson, R. E.

    1982-01-01T23:59:59.000Z

    The low cost of steam combined with the maintenance free operation of steam ejectors has assured their unquestioned use in providing the necessary vacuum for crude distillation vacuum towers. However, the cost of steam production has risen...

  17. Hydrogenation of aromatics in synthetic crude distillates catalyzed by platinum supported in molecular sieves

    SciTech Connect (OSTI)

    Kimbara, N.; Charland, J.P. [CANMET, Ottawa, Ontario (Canada)] [CANMET, Ottawa, Ontario (Canada); Wilson, M.F. [CANMET, Devon, Alberta (Canada)] [CANMET, Devon, Alberta (Canada)

    1996-11-01T23:59:59.000Z

    Catalytic hydrogenation of synthetic crude distillates from Canadian oil sands was carried out over platinum metal supported in pillared interlayered clay (PILC) and Y-zeolite. The molecular sieve supports were employed to modify the properties of dispersed platinum particles and improve their resistance to poisoning by sulfur. The objective was to reduce the distillate aromatic content to meet diesel emission control standards and cetane number requirements. Catalysts were prepared in a series of steps, and metal precursor was loaded using ion-exchange procedures. Characterization was done using X-ray diffraction, hydrogen chemisorption, and proton-induced X-ray emission elemental analysis. Catalytic hydrogenation reactions were carried out by processing distillate feedstocks both high (>100 ppm) and low (<10 ppm) in sulfur using a continuous-flow automated microreactor system. Experimental runs were performed to determine the reaction kinetics and Arrhenius parameters as a means of evaluating and comparing catalyst performance. Significant differences in catalyst activity were found. The Pt/Y-zeolite-alumina catalyst showed a much superior hydrogenation performance under conditions of high sulfur content. The extent of cracking and ring opening was also evaluated and was shown to be minimal under the operating conditions employed.

  18. A novel proportional--integral-derivative control configuration with application to the control of batch distillation

    SciTech Connect (OSTI)

    Alvarez-Ramirez, J.; Monroy-Loperena, R.; Cervantes, I.; Morales, A.

    2000-02-01T23:59:59.000Z

    The aim of this paper is to propose a novel proportional-integral-derivative (PID) control configuration based on an observer structure. Batch distillation is used as the base case study where the regulated output is the distillate composition. The proposed PID control law is derived in the framework of robust nonlinear control with modeling error compensation techniques. A reduced-order observer is proposed to estimate both the derivative of the regulated output and the underlying modeling error. These observations are subsequently used in a control loop to feedback variations of distillate composition (derivative feedback) and to counteract the effects of modeling errors. It is shown that, under certain conditions, the resulting control law is equivalent to a classical PID controller with an antireset windup scheme. Moreover, the tuning of the controller is performed very easily in terms of a prescribed closed-loop time constant and an estimation time constant. Numerical results are provided for binary and multicomponent separations. Sampled/delayed measurements and several sources of uncertainties are considered in order to provide a realistic test scenario for the proposed control design procedure.

  19. Magnetocaloric properties of distilled gadolinium: Effects of structural inhomogeneity and hydrogen impurity

    SciTech Connect (OSTI)

    Burkhanov, G. S.; Kolchugina, N. B.; Chzhan, V. B.; Chistyakov, O. D. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); Tereshina, E. A. [Institute of Physics ASCR, 18221 Prague (Czech Republic); Tereshina, I. S. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); International Laboratory of High Magnetic Fields and Low Temperatures PAS, 53-421 Wroclaw (Poland); Faculty of Physics, Lomonosov Moscow State University, 119991 Moscow (Russian Federation); Politova, G. A. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); International Laboratory of High Magnetic Fields and Low Temperatures PAS, 53-421 Wroclaw (Poland); Badurski, D.; Drulis, H. [Institute of Low Temperature and Structure Research PAS, 50-950 Wroclaw (Poland); Paukov, M.; Havela, L. [Department of Condensed Matter Physics, Faculty of Mathematics and Physics, Charles University, 12116 Prague (Czech Republic)

    2014-06-16T23:59:59.000Z

    High-purity Gd prepared by distillation is a structurally inhomogeneous system consisting of needle-shaped crystals of cross section 0.5–2.5??m with near-c-axis orientation embedded in a matrix of nanosized (30–100?nm) grains. By measuring the magnetocaloric effect (MCE) directly, we find that the MCE values differ markedly for the plate-shaped samples cut out of a distillate along and perpendicular to the crystals. The effect of small controlled amounts of impurity (hydrogen) on the properties of distilled Gd is further studied. We observe opposite trends in the MCE response to hydrogen charging with respect to the crystal's orientation within the samples and discuss mechanisms interrelating the unique structural morphology with the impurity behavior. As an overall assessment, the Curie temperatures of ?-GdH{sub x} solid solutions increase from 291?K up to 294?K when increasing hydrogen concentration x from 0 to 0.15. Hydrogenation is found to broaden the ferromagnetic-to-paramagnetic phase transition. Hydrogen-containing specimens demonstrate reversibility of MCE at these temperatures.

  20. Coprocessing of hydrocarbonaceous wastes and residual oil - a novel approach to recycling

    SciTech Connect (OSTI)

    Anderson, N.E. [Kilborn Inc., Toronto (Canada); Berger, D.J. [Canadian Energy Developments Inc., Edmonton (Canada)

    1993-12-31T23:59:59.000Z

    The Plastic and Rubber Recycling (PARR) Process being developed by Kilborn Inc., and Canadian Energy Developments Inc., offers a unique approach to the recovery and recycle of waste hydrocarbonaceous materials as they are simultaneously hydrogenated with low quality residual oil to yield basic petrochemicals and virgin plastic and synthetic rubber compounds. Laboratory scale experiments with used tire rubber crumb, scrap polystyrene and heavy oil residuum as the coprocessing medium gave encouraging results. In excess of 90 percent of the carbonaceous matter was converted to distillate oil product that, upon secondary hydrotreating, could be considered high quality ethylene cracking furnace feedstock or aromatics extraction plant feedstock. This presentation will discuss the technical and economic potential of the PARR Process, the planned technology development program and initial commercialization plans.

  1. Transforms for prediction residuals in video coding

    E-Print Network [OSTI]

    Kam??l?, Fatih

    2010-01-01T23:59:59.000Z

    Typically the same transform, the 2-D Discrete Cosine Transform (DCT), is used to compress both image intensities in image coding and prediction residuals in video coding. Major prediction residuals include the motion ...

  2. Residual Stresses in Weldments by Neutron Diffraction

    E-Print Network [OSTI]

    Bandara, Arosha

    Rectors and Pressurised Water Reactors Source of Problem · Internal Residual Stress · Material propertiesResidual Stresses in Weldments by Neutron Diffraction Shanmukha Rao M, Jon James, Shirley Northover of Residual Stress inside Materials Material: 3 Pass Weld Austenitic Stainless Steel Working Principle

  3. DRAINED RESIDUAL STRENGTH OF COHESIVE SOILSa

    E-Print Network [OSTI]

    that the residual friction angle is independent of the original shear strength, water content, and liquidity indexDRAINED RESIDUAL STRENGTH OF COHESIVE SOILSa Discussion by Robert W. Day,3 Fellow, ASCE The authors have preparcd an important paper on the drained residual shear strength of cohesive soil. The authors

  4. Rapid prediction of various physical properties for middle distillate fuel utilizing directly coupled liquid chromatography//sup 1/H nuclear magnetic resonance

    SciTech Connect (OSTI)

    Caswell, K.A.; Glass, T.E.; Swann, M.; Dorn, H.C.

    1989-02-01T23:59:59.000Z

    A group property approach has been developed to predict 17 physical properties of middle distillate (e.g., jet and diesel) fuels from experimentally derived liquid chromatography//sup 1/H nuclear magnetic resonance (LC//sup 1/H NMR) data. In the LC//sup 1/H NMR technique, the fuel is separated according to chemical class and the average molecular structure for each chemical class is then calculated. These average molecular structures form a basis set to predict the physical properties of the fuel. The physical properties that can be obtained in this manner are cetane number, cetane index, density, specific gravity, pour point, flash point, viscosity, filterability, heat of combustion, cloud point, volume percent aromatics, residual carbon content, and the initial, 10%, 50%, 90%, and end boiling points. Fourteen of the correlation coefficients for the predictions are better than 0.90 with 11 of the predictions falling either within or approximately equal to the ASTM method reproducibility for the measurement of the fuel property. The present method also provides chemical insight concerning the influence of chemical structural changes on the physical properties of the fuel as well as requiring much less analysis time and sample volume than corresponding ASTM methods.

  5. Vacuum Distillation

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5 Tables July 1996 Energy Information Administration Office ofthroughYear JanYear JanPropane, No.1Decade6,393 6,810 6,51540 235Day)

  6. A blending problem (Taha, Example 2.3-7, almost) An oil refinery has three stages of production: a distillation tower, which

    E-Print Network [OSTI]

    Galvin, David

    : a distillation tower, which takes in crude oil, up to a maximum of 650,000 barrels per day (bbl/day) and produces that maximizes profit. Note: Taha's Example 2.3-7 has distillation tower capacity 1,500,000 bbl/day, and is otherwise the same. 1 #12;Solution Let x1 be daily input to distillation tower Constraint: 0 x1 650000

  7. Process to recycle shredder residue

    DOE Patents [OSTI]

    Jody, Bassam J. (Chicago, IL); Daniels, Edward J. (Oak Lawn, IL); Bonsignore, Patrick V. (Channahon, IL)

    2001-01-01T23:59:59.000Z

    A system and process for recycling shredder residue, in which separating any polyurethane foam materials are first separated. Then separate a fines fraction of less than about 1/4 inch leaving a plastics-rich fraction. Thereafter, the plastics rich fraction is sequentially contacted with a series of solvents beginning with one or more of hexane or an alcohol to remove automotive fluids; acetone to remove ABS; one or more of EDC, THF or a ketone having a boiling point of not greater than about 125.degree. C. to remove PVC; and one or more of xylene or toluene to remove polypropylene and polyethylene. The solvents are recovered and recycled.

  8. Isospin Distillation with Radial Flow: a Test of the Nuclear Symmetry Energy

    E-Print Network [OSTI]

    M. Colonna; V. Baran; M. Di Toro; H. H. Wolter

    2007-07-20T23:59:59.000Z

    We discuss mechanisms related to isospin transport in central collisions between neutron-rich systems at Fermi energies. A fully consistent study of the isospin distillation and expansion dynamics in two-component systems is presented in the framework of a stochastic transport theory. We analyze correlations between fragment observables, focusing on the study of the average N/Z of fragments, as a function of their kinetic energy. We identify an EOS-dependent relation between these observables, allowing to better characterize the fragmentation path and to access new information on the low density behavior of the symmetry energy.

  9. Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant

    SciTech Connect (OSTI)

    Gambert, G.

    1996-12-31T23:59:59.000Z

    When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

  10. ,"U.S. Adjusted Sales of Distillate Fuel Oil by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources andPlant Liquids,+ LeasePrice SoldPlantGrossDistillate Fuel Oil by End

  11. Magic State Distillation and Gate Compilation in Quantum Algorithms for Quantum Chemistry

    E-Print Network [OSTI]

    Colin J. Trout; Kenneth R. Brown

    2015-01-29T23:59:59.000Z

    Quantum algorithms for quantum chemistry map the dynamics of electrons in a molecule to the dynamics of a coupled spin system. To reach chemical accuracy for interesting molecules, a large number of quantum gates must be applied which implies the need for quantum error correction and fault-tolerant quantum computation. Arbitrary fault-tolerant operations can be constructed from a small, universal set of fault-tolerant operations by gate compilation. Quantum chemistry algorithms are compiled by decomposing the dynamics of the coupled spin-system using a Trotter formula, synthesizing the decomposed dynamics using Clifford operations and single-qubit rotations, and finally approximating the single-qubit rotations by a sequence of fault-tolerant single-qubit gates. Certain fault-tolerant gates rely on the preparation of specific single-qubit states referred to as magic states. As a result, gate compilation and magic state distillation are critical for solving quantum chemistry problems on a quantum computer. We review recent progress that has improved the efficiency of gate compilation and magic state distillation by orders of magnitude.

  12. Optimum Requirements for the Synthesis of Biodiesel Using Fatty Acid Distillates

    E-Print Network [OSTI]

    Akunna E. Ejele

    The optimum requirements of temperature, retention time, mole ratio of reactants and catalyst for the direct synthesis of biodiesel from fatty acid distillates of palm kernel oil using tetraoxosulphate (VI) acid as catalyst was studied. The following parameters were used for the efficient and economic production of biodiesel: eight (8) moles of methanol per mole of fatty acid, 0.06 mole of tetraoxosulphate (VI) acid per mole of fatty acid, a retention time of sixty (60) minutes and reaction temperature of 65 OC. And this gave a maximum percentage yield of 98.4. Other parameters obtained include: an acid value of 0.1683 mg KOH/g, iodine value of 15.3549, flash point of 209 OC, viscosity of 3.7957 mm2s-1, density of 0.8776 g cm-3, water content of 400.05 mg kg-1, soap content of 2.30 mg/kg, and ester content of 98.804 %. From the obtained parameters, the biodiesel produced from fatty acid distillates of palm kernel oil reaches prescribed international standards for biodiesel production.

  13. Particulate residue separators for harvesting devices

    SciTech Connect (OSTI)

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29T23:59:59.000Z

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  14. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05T23:59:59.000Z

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  15. Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation 

    E-Print Network [OSTI]

    Plazas Garcia, Joyce Vivia

    2002-01-01T23:59:59.000Z

    Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

  16. A Novel Control Methodology for a Pilot Plant Azeotropic Distillation Column Lina M. Rueda, Thomas F. Edgar,* and Robert B. Eldridge

    E-Print Network [OSTI]

    Eldridge, R. Bruce

    A Novel Control Methodology for a Pilot Plant Azeotropic Distillation Column Lina M. Rueda, Thomas challenges to the design and operation of a separation process. Heterogeneous Azeotropic Distillation Most as entrainer. The study concluded that optimum design of the two column approach is more economical than

  17. Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation

    E-Print Network [OSTI]

    Plazas Garcia, Joyce Vivia

    2002-01-01T23:59:59.000Z

    Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

  18. Characterization Report on Sand, Slag, and Crucible Residues and on Fluoride Residues

    SciTech Connect (OSTI)

    Murray, A.M.

    1999-02-10T23:59:59.000Z

    This paper reports on the chemical characterization of the sand, slag, and crucible (SS and C) residues and the fluoride residues that may be shipped from the Rocky Flats Environmental Technology Site (RFETS) to Savannah River Site (SRS).

  19. Contributions to the development of residual discretizations

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Contributions to the development of residual discretizations for hyperbolic conservation laws with application to shallow water flows Manuscript submitted in fulfillment of the requirements for the obtention;Contents 1 Overview 9 1.1 Residual schemes for hyperbolic conservation laws

  20. Asymptotics for GARCH Squared Residual Correlations

    E-Print Network [OSTI]

    Kokoszka, Piotr

    Asymptotics for GARCH Squared Residual Correlations Istv'an Berkes \\Lambda A. R'enyi Institute a GARCH(p; q) model. Denoting by â?? r n (k); k â?? 1; these autocorrelations computed from a realization words and phrases: GARCH(p; q) sequence, quasi--maximum likelihood esti­ mator, squared residuals

  1. University of Pittsburgh Residual Funds on

    E-Print Network [OSTI]

    Sibille, Etienne

    University of Pittsburgh Residual Funds on FINANCIAL GUIDELINE Subject: Sponsored Projects I by the sponsor. Funds cannot be unilaterally retained by the University. Failure to return residual funds related funds on sponsored grants and contracts on the financial accounting records of the University

  2. Data Conversion in Residue Number System

    E-Print Network [OSTI]

    Zilic, Zeljko

    for direct conversion when interaction with the real analog world is required. We first develop two efficient schemes for direct analog-to-residue conversion. Another efficient scheme for direct residue analogique réel est nécessaire. Nous dévelopons deux systèmes efficaces pour la conversion directe du domaine

  3. The robustness of magic state distillation against errors in Clifford gates

    E-Print Network [OSTI]

    Jochym-O'Connor, Tomas; Helou, Bassam; Laflamme, Raymond

    2012-01-01T23:59:59.000Z

    Quantum error correction and fault-tolerance have provided the possibility for large scale quantum computations without a detrimental loss of quantum information. A very natural class of gates for fault-tolerant quantum computation is the Clifford gate set and as such their usefulness for universal quantum computation is of great interest. Clifford group gates augmented by magic state preparation give the possibility of simulating universal quantum computation. However, experimentally one cannot expect to perfectly prepare magic states. Nonetheless, it has been shown that by repeatedly applying operations from the Clifford group and measurements in the Pauli basis, the fidelity of noisy prepared magic states can be increased arbitrarily close to a pure magic state [1]. We investigate the robustness of magic state distillation to perturbations of the initial states to arbitrary locations in the Bloch sphere due to noise. Additionally, we consider a depolarizing noise model on the quantum gates in the decoding ...

  4. Why methyl tert-butyl ether production by reactive distillation may yield multiple solutions

    SciTech Connect (OSTI)

    Hauan, S.; Hertzberg, T.; Lien, K.M. [Univ. of Trondheim (Norway)

    1995-03-01T23:59:59.000Z

    This paper presents an explanation of why methyl tert-butyl ether (MTBE) production by reactive distillation may yield multiple solutions. Widely different composition profiles and conversions may, as already reported by Krishna and others, results with identical column specifications, depending on the initial estimates provided. A hypothesis yielding a qualitative understanding of this phenomenon has been developed. The inert n-butene plays a key role in the proposed explanation: As the reaction mixture is diluted with n-butene, the activity coefficient of methanol increases substantially and the temperature decreases. This dilution has a profound effect on the equilibrium conversion, enabling MTBE to escape from the reactive zone without decomposition. When methanol is fed below or in the lower part of the reactive zone of the column, the ``lifting capacity`` of the minimum boiling point MTBE-methanol azeotrope will also be important.

  5. Upgrading of middle distillate fractions of syncrudes from athabasca oil sands

    SciTech Connect (OSTI)

    Wilson, M.F.; Kriz, J.F.

    1983-03-01T23:59:59.000Z

    Middle distillate fractions of syncrudes from Athabasca Oil Sands were evaluated for suitability as feedstocks in the catalytic conversion to diesel fuel meeting cetane number specifications. Hydrogenation of aromatic components to napthenes under severe conditions (380 to 400/sup 0/C, 2500 psig) using sulfided CoO/MoO/sub 3/ and NiO/WO/sub 3/ over ..cap alpha.. . Al/sub 2/O/sub 3/ in a previously described catalyst testing system. Reaction products were analyzed for aromatic carbon content using C/sup 13/ NMR spectroscopy and pseudo first order rate constants and activation energies (15.0 and 14.2 kcal 1 g-mole, respectively) were determined by regression analysis. At optimum conditions 97% aromatic conversion was obtained with the Ni-W catalyst. Product diesel fuel cetane number (42) was within specifications. Co-Mo catalyst was significantly less active.

  6. Re-refining of Waste Oil Solvent Is Used in Treatment/Distillation Process

    E-Print Network [OSTI]

    unknown authors

    INDUSTRIAL APPLICATION. A combination solvent treatment/distillation process has been designed for re-refining industrial waste oil (such as equipment lubricants, metal-working oil, and process oil) and used automotive lubricants (engine oil, hydraulic oil, and gear oil) for reuse. WASTE ENERGY RECOVERY. Recycling of waste oil in the United States has the potential to save the energy equivalent of 7-12 million bbl of crude oil annually.1 WASTE OIL RECOVERY. Prior to 1960, a significant portion of the demand for automotive lubricating oil was met by re-relined used oil. At the time, 150 re-refineries produced 300 million gal of motor oil annually. Since 1960, however, the production of re-refined oil has steadily declined. In 1981, for example, out of about 1.2 billion gal of automobile lubricating oil and 1.6 billion gal of industrial lubricating oils purchased, 25 U.S. rerefineries

  7. On local indistinguishability of orthogonal pure states by using a bound on distillable entanglement

    E-Print Network [OSTI]

    Sibasish Ghosh; Guruprasad Kar; Anirban Roy; Debasis Sarkar; Aditi Sen De; Ujjwal Sen

    2001-11-25T23:59:59.000Z

    We show that the four states a|00>+b|11>, b^*|00>-a^*|11>, c|01>+d|10> and d^*|01>-c^*|10> cannot be discriminated with certainty if only local operations and classical communication (LOCC) are allowed and if only a single copy is provided, except in the case when they are simply |00>, |11>, |01> and |10> (in which case they are trivially distinguishable with LOCC). We go on to show that there exists a continuous range of values of a, b, c and d such that even three states among the above four are not locally distinguishable, if only a single copy is provided. The proof follows from the fact that logarithmic negativity is an upper bound of distillable entanglement.

  8. 2094 Ind. Eng. Chem. Res. 1995,34,2094-2103 Operation of Integrated Three-Product(Petlyuk)Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    studied the design of such columns,very little work has been done on the operation and control the Petlyuk column, compared to an ordinary distillation column,has many more degrees of freedomin both op- eration and design. This undoubtablymakes the design of both the column and its control system more

  9. Colorimetric Determination of Nitrite in Foods Principle: The sample is extracted with distilled water and the aqueous extract clarified

    E-Print Network [OSTI]

    Nazarenko, Alexander

    water and the aqueous extract clarified with zinc hydroxide. Sulfanilic acid is diazotisedColorimetric Determination of Nitrite in Foods Principle: The sample is extracted with distilled/50 mL. The absorbance range should extend from 0 to 0.6 approx. E. Extraction Procedure Weigh ca 100g

  10. Kinetics of hydrogenation of aromatics determined by carbon-13 NMR for Athabasca bitumen-derived middle distillates

    SciTech Connect (OSTI)

    Yui, S.M.; Sanford, E.C. (Syncrude Canada Ltd., Edmonton, Alberta (Canada))

    1987-04-01T23:59:59.000Z

    High aromatics content in middle distillates is detrimental to fuel quality, as shown in such properties as smoke point of jet fuel and cetane number of diesel fuel. In the petroleum and petrochemical industries the yields from fluid catalytic cracking or steam cracking units are adversely affected by high aromatics content in the feedstock. Distillates obtained from oil sand bitumen, heavy oils, or coal liquefaction products are particularly high in aromatics. Reducing the concentration of this class of compounds is important. Aromatics hydrogenation (AHYD) is one option to achieve this result. In the current Syncrude operation a primary objective of hydrotreating is to reduce product sulfur and nitrogen contents; reducing aromatics content is an incidental result. However, the expansion plan currently under study by Syncrude includes further AHYD to improve cetane number. Predicting the product aromatics content is an important issue for this study. In the present study, hydrotreating of five Athabasca-bitumen-derived gas oils was conducted in pilot scale trickle-bed reactors using alumina-based commercial NiMo catalysts. Feedstocks originated from the distillation of virgin bitumen, and from distillates derived from treating bitumen in a fluid coker and hydrocracking pilot plant. Aromatics content was determined by the {sup 13}C NMR method. The previously developed rate equation for AHYD was modified by including power terms for space velocity and hydrogen partial pressure. The data were analyzed using the modified equation.

  11. Process for treatment of residual gas

    SciTech Connect (OSTI)

    Nolden, K.

    1980-01-01T23:59:59.000Z

    A process is disclosed for the treatment of the residual gases which are produced when hydrogen sulfide is reduced, by combustion, to elementary sulfur by the Claus process. The residual gases are fed through a heated conduit and gas scrubber, wherein the temperature of those residual gases are maintained above the melting point of sulfur. A portion of the raw coke oven gas condensate is admitted to the gas scrubber to be returned to the coke oven battery main from the flushing liquid separator as flushing liquor. The residual gases are then conducted through the coke oven gas purification process equipment along with the raw coke oven gas where the residual gases are intermixed with the raw coke oven gas prior to tar separation.

  12. Distillation of Bose-Einstein Condensates in a Double-Well Potential Y. Shin, M. Saba, A. Schirotzek, T. A. Pasquini, A. E. Leanhardt, D. E. Pritchard, and W. Ketterle*

    E-Print Network [OSTI]

    Distillation of Bose-Einstein Condensates in a Double-Well Potential Y. Shin, M. Saba, A-Einstein condensates of sodium atoms, prepared in an optical dipole trap, were distilled into a second empty dipole trap adjacent to the first one. The distillation was driven by thermal atoms spilling over

  13. We study the continuous extractive distillation of minimum and maximum boiling azeotropic mixtures A-B with a heavy or a light entrainer E, intending to assess its feasibility based on thermodynamic insights.

    E-Print Network [OSTI]

    Mailhes, Corinne

    #12;#12;Abstract We study the continuous extractive distillation of minimum and maximum boiling on operating parameters: distillate product purity and recovery, reflux ratio R and entrainer ­ feed flow rate. For the 1.0-2 class both A and B can be distillated. For one of them there exists a maximum entrainer - feed

  14. Arabian crude-oil residues evaluated

    SciTech Connect (OSTI)

    Ali, M.F.; Bukhari, A.; Hasan, M.; Saleem, M.

    1985-08-12T23:59:59.000Z

    This article evaluates detailed physical and chemical characteristics for four important Saudi Arabian resids. Petroleum residues are composed of a mixture of large and complex hydrocarbon molecules along with one or more heteroatoms such as sulfur, oxygen, nitrogen, vanadium, and nickel. The amount of residue and its physical and chemical composition depend on the source of the crude oil and methods of processing. Residues from four Saudi Arabian crude oils produced by the Arabian American Oil Co. (Aramco) were evaluated. The crude oils are 38.5 degrees API Arabian Extra Light, 33.8 degrees API Arabian Light, 30.4 degrees Api Arabian Medium, and 28.03 degrees API Arabian Heavy. Results are presented and residue preparation, and physical and chemical characteristics are analyzed.

  15. California: Agricultural Residues Produce Renewable Fuel | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Logos Technologies and EERE partnered with EdeniQ of Visalia, California, to construct a pilot plant that processes 1.2 tons per day of agricultural residues, such as corn stover...

  16. Residual stress in nanocrystalline nickel tungsten electrodeposits

    E-Print Network [OSTI]

    Ziebell, Tiffany D. (Tiffany Dawn)

    2011-01-01T23:59:59.000Z

    Characterizing the residual stress of thick nanocrystalline electrodeposits poses several unique challenges due to their fine grain structure, thickness distribution, and matte surface. We employ a three-dimensional ...

  17. Residual Toxicities of Insecticides to Cotton Insects.

    E-Print Network [OSTI]

    Hightower, B. G.; Gaines, J. C.

    1960-01-01T23:59:59.000Z

    Summary Results of experiments conducted to determine leafworm, the salt-marsh caterpillar and the garden the effect of natural or simulated climatic conditions webworm. on the residual toxicities of several chlorinated hydro- carbon... variety of weathering conditions. Based on residual properties alone, toxaphene and dieldrin ranked with endrin and Sevin, but the initial toxicities of dieldrin and endrin to the boll weevil were appreciably greater than those of toxaphene...

  18. Residual Toxicities of Insecticides to Cotton Insects. 

    E-Print Network [OSTI]

    Hightower, B. G.; Gaines, J. C.

    1960-01-01T23:59:59.000Z

    Summary Results of experiments conducted to determine leafworm, the salt-marsh caterpillar and the garden the effect of natural or simulated climatic conditions webworm. on the residual toxicities of several chlorinated hydro- carbon... variety of weathering conditions. Based on residual properties alone, toxaphene and dieldrin ranked with endrin and Sevin, but the initial toxicities of dieldrin and endrin to the boll weevil were appreciably greater than those of toxaphene...

  19. ABSTRACT: Bioenergy Harvesting Technologies to Supply Crop Residues...

    Energy Savers [EERE]

    ABSTRACT: Bioenergy Harvesting Technologies to Supply Crop Residues In a Densified Large Square Bale Format ABSTRACT: Bioenergy Harvesting Technologies to Supply Crop Residues In a...

  20. Recovery of Navy distillate fuel from reclaimed product. Volume II. Literature review

    SciTech Connect (OSTI)

    Brinkman, D.W.; Whisman, M.L.

    1984-11-01T23:59:59.000Z

    In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). This first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in which experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 references and abstracts. This appendix, because of its volume, has been published separately as Volume 2.

  1. Recovery of Navy distillate fuel from reclaimed product. Volume I. Technical discussion

    SciTech Connect (OSTI)

    Brinkman, D.W.; Whisman, M.L.

    1984-11-01T23:59:59.000Z

    In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). The first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in which experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 referenvces and abstracts. This appendix, because of its volume, has been published separately as Volume 2. 18 figures, 4 tables.

  2. Investigation of the Potential for Biofuel Blends in Residual Oil-Fired Power Generation Units as an Emissions Reduction Strategy for New York State

    SciTech Connect (OSTI)

    Krishna, C.R.; McDonald, R.

    2009-05-01T23:59:59.000Z

    There is a significant amount of oil, about 12.6 million barrels per year, used for power generation in New York State. The majority of it is residual oil. The primary reason for using residual oil probably is economic, as these fuels are cheaper than distillates. However, the stack emissions from the use of such fuels, especially in densely populated urban areas, can be a cause for concern. The emissions of concern include sulfur and nitrogen oxides and particulates, particularly PM 2.5. Blending with distillate (ASTM No.2) fuels may not reduce some or all of these emissions. Hence, a case can be made for blending with biofuels, such as biodiesel, as they tend to have very little fuel bound sulfur and nitrogen and have been shown in prior work at Brookhaven National Laboratory (BNL) to reduce NOx emissions as well in small boilers. Some of the research carried out at CANMET in Canada has shown potential reductions in PM with blending of biodiesel in distillate oil. There is also the benefit obtaining from the renewable nature of biofuels in reducing the net carbon dioxide emitted thus contributing to the reduction of green house gases that would otherwise be emitted to the atmosphere. The present project was conceived to examine the potential for such benefits of blending biofuels with residual oil. A collaboration was developed with personnel at the New York City Poletti Power Plant of the New York Power Authority. Their interest arose from an 800 MW power plant that was using residual oil and which was mandated to be shut down in 2010 because of environmental concerns. A blend of 20% biodiesel in residual oil had also been tested for a short period of about two days in that boiler a couple of years back. In this project, emission measurements including particulate measurements of PM2.5 were made in the commercial boiler test facility at BNL described below. Baseline tests were done using biodiesel as the blending biofuel. Biodiesel is currently and probably in the foreseeable future more expensive than residual fuel. So, another task was to explore potential alternative biofuels that might confer emission benefits similar to those of biodiesel, while being potentially significantly cheaper. Of course, for power plant use, availability in the required quantities is also a significant criterion. A subsidiary study to determine the effect of the temperature of the filter used to collect and measure the PM 2.5 emissions was conducted. This was done for reasons of accuracy in a residential boiler using distillate fuel blends. The present report details the results obtained in these tests with the baseline ASTM No. 6 fuel and blends of biodiesel with it as well as the results of the filter temperature study. The search for the alternative 'cheaper' biofuel identified a potential candidate, but difficulties encountered with the equipment during the testing prevented testing of the alternative biofuel.

  3. Sustainable System for Residual Hazards Management

    SciTech Connect (OSTI)

    Kevin M. Kostelnik; James H. Clarke; Jerry L. Harbour

    2004-06-01T23:59:59.000Z

    Hazardous, radioactive and other toxic substances have routinely been generated and subsequently disposed of in the shallow subsurface throughout the world. Many of today’s waste management techniques do not eliminate the problem, but rather only concentrate or contain the hazardous contaminants. Residual hazards result from the presence of hazardous and/or contaminated material that remains on-site following active operations or the completion of remedial actions. Residual hazards pose continued risk to humans and the environment and represent a significant and chronic problem that require continuous longterm management (i.e. >1000 years). To protect human health and safeguard the natural environment, a sustainable system is required for the proper management of residual hazards. A sustainable system for the management of residual hazards will require the integration of engineered, institutional and land-use controls to isolate residual contaminants and thus minimize the associated hazards. Engineered controls are physical modifications to the natural setting and ecosystem, including the site, facility, and/or the residual materials themselves, in order to reduce or eliminate the potential for exposure to contaminants of concern (COCs). Institutional controls are processes, instruments, and mechanisms designed to influence human behavior and activity. System failure can involve hazardous material escaping from the confinement because of system degradation (i.e., chronic or acute degradation) or by externalintrusion of the biosphere into the contaminated material because of the loss of institutional control. An ongoing analysis of contemporary and historic sites suggests that the significance of the loss of institutional controls is a critical pathway because decisions made during the operations/remedial action phase, as well as decisions made throughout the residual hazards management period, are key to the longterm success of the prescribed system. In fact, given that society has become more reliant on and confident of engineered controls, there may be a growing tendency to be even less concerned with institutional controls.

  4. Resource cost results for one-way entanglement distillation and state merging of compound and arbitrarily varying quantum sources

    E-Print Network [OSTI]

    Holger Boche; Gisbert Janßen

    2014-08-26T23:59:59.000Z

    We consider one-way quantum state merging and entanglement distillation under compound and arbitrarily varying source models. Regarding quantum compound sources, where the source is memoryless, but the source state an unknown member of a certain set of density matrices, we continue investigations begun in the work of Bjelakovi\\'c et. al. [Universal quantum state merging, J. Math. Phys. 54, 032204 (2013)] and determine the classical as well as entanglement cost of state merging. We further investigate quantum state merging and entanglement distillation protocols for arbitrarily varying quantum sources (AVQS). In the AVQS model, the source state is assumed to vary in an arbitrary manner for each source output due to environmental fluctuations or adversarial manipulation. We determine the one-way entanglement distillation capacity for AVQS, where we invoke the famous robustification and elimination techniques introduced by R. Ahlswede. Regarding quantum state merging for AVQS we show by example, that the robustification and elimination based approach generally leads to suboptimal entanglement as well as classical communication rates.

  5. BY HOW MUCH CAN RESIDUAL MINIMIZATION ACCELERATE THE CONVERGENCE OF ORTHOGONAL RESIDUAL METHODS?

    E-Print Network [OSTI]

    Gutknecht, Martin H.

    . Examples of such pairs are the conjugate gradient (CG) and the conjugate residual (CR) methods, the full-minimal residual (QMR) methods. Also the pairs consisting of the (bi)conjugate gradient squared (CGS, iterative method, Krylov space method, conjugate gradient method, biconjugate gradient method, CG, CGNE

  6. Decay of rho and a1 mesons on the lattice using distillation

    E-Print Network [OSTI]

    S. Prelovsek; C. B. Lang; D. Mohler; M. Vidmar

    2011-11-02T23:59:59.000Z

    We extract the P-wave pi-pi phase shift for five values of pion relative momenta, which gives information on the rho resonance. The Breit-Wigner formula describes the pi-pi phase shift dependence nicely and we extract m(rho)=792(7)(8) MeV and the coupling g_{\\rho\\pi\\pi}=5.13(20) at our mpi=266 MeV. We extract the P-wave scattering length a_{l=1}^{\\pi\\pi}=0.082(10)(3) fm^3 from the state with the lowest pion relative momenta. We also determine the S-wave rho-pi phase shift for two values of relative momenta, which provides parameters of the lowest axial resonance a1(1260). Using the Breit-Wigner fit we extract m(a1)=1.44(4) GeV and the coupling g_{a_1\\rho\\pi}=1.1(3) GeV. From the lowest state we also extract the rho-pi scattering length a_{l=0}^{\\rho\\pi}=0.23(12) fm for our mpi. The simulation is performed using one Nf=2 ensemble of gauge configurations with clover-improved Wilson quarks. The phase shifts are determined from the lowest two energy-levels, which are obtained by the variational analysis with a number of quark-antiquark and meson-meson interpolators. The correlation functions are calculated using the distillation method with the Laplacian Heaviside (LapH) smearing of quarks.

  7. Update of distillers grains displacement ratios for corn ethanol life-cycle analysis.

    SciTech Connect (OSTI)

    Arora, S.; Wu, M.; Wang, M.; Energy Systems

    2011-02-01T23:59:59.000Z

    Production of corn-based ethanol (either by wet milling or by dry milling) yields the following coproducts: distillers grains with solubles (DGS), corn gluten meal (CGM), corn gluten feed (CGF), and corn oil. Of these coproducts, all except corn oil can replace conventional animal feeds, such as corn, soybean meal, and urea. Displacement ratios of corn-ethanol coproducts including DGS, CGM, and CGF were last updated in 1998 at a workshop at Argonne National Laboratory on the basis of input from a group of experts on animal feeds, including Prof. Klopfenstein (University of Nebraska, Lincoln), Prof. Berger (University of Illinois, Urbana-Champaign), Mr. Madson (Rapheal Katzen International Associates, Inc.), and Prof. Trenkle (Iowa State University) (Wang 1999). Table 1 presents current dry milling coproduct displacement ratios being used in the GREET model. The current effort focuses on updating displacement ratios of dry milling corn-ethanol coproducts used in the animal feed industry. Because of the increased availability and use of these coproducts as animal feeds, more information is available on how these coproducts replace conventional animal feeds. To glean this information, it is also important to understand how industry selects feed. Because of the wide variety of available feeds, animal nutritionists use commercial software (such as Brill Formulation{trademark}) for feed formulation. The software recommends feed for the animal on the basis of the nutritional characteristics, availability, and price of various animal feeds, as well as on the nutritional requirements of the animal (Corn Refiners Association 2006). Therefore, feed formulation considers both the economic and the nutritional characteristics of feed products.

  8. Residual dust charges in discharge afterglow

    SciTech Connect (OSTI)

    Coueedel, L.; Mikikian, M.; Boufendi, L.; Samarian, A. A. [GREMI - Groupe de Recherches sur l'Energetique des Milieux Ionises, CNRS/Universite d'Orleans, 14 rue d'Issoudun, 45067 Orleans Cedex 2 (France); School of Physics A28, University of Sydney, NSW 2006 (Australia)

    2006-08-15T23:59:59.000Z

    An on-ground measurement of dust-particle residual charges in the afterglow of a dusty plasma was performed in a rf discharge. An upward thermophoretic force was used to balance the gravitational force. It was found that positively charged, negatively charged, and neutral dust particles coexisted for more than 1 min after the discharge was switched off. The mean residual charge for 200-nm-radius particles was measured. The dust particle mean charge is about -5e at a pressure of 1.2 mbar and about -3e at a pressure of 0.4 mbar.

  9. Residual oil conversion in Ashland FCC Units

    SciTech Connect (OSTI)

    Barger, D.F.; Miller, C.B.

    1983-03-01T23:59:59.000Z

    Ashland Petroleum Company is a production-poor refining and marketing company. A company must have refining flexibility to compete in today's crude and marketing situation. Ashland has adopted a dual approach to achieving the required refining flexibility: development and construction of the RCC process, and development of techniques to practice residual oil conversion in Ashland FCC units. This paper discusses the operating techniques Ashland has used to allow residual oil conversion to be practiced in their present day FCC's and shows some of the yields which have been achieved.

  10. LPG Electrical, Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere I Geothermal Pwer Plant Jump to: navigation,working-groups < LEDSGP‎LEE Jump to:LNJ BhilwaraLOPPLPLPG

  11. Chemical Stabilization of Hanford Tank Residual Waste

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Um, Wooyong; Williams, Benjamin D.; Bowden, Mark E.; Gartman, Brandy N.; Lukens, Wayne W.; Buck, Edgar C.; Mausolf, Edward J.

    2014-03-01T23:59:59.000Z

    Three different chemical treatment methods were tested for their ability to stabilize residual waste from Hanford tank C-202 for reducing contaminant release (Tc, Cr, and U in particular). The three treatment methods tested were lime addition [Ca(OH)2], an in-situ Ceramicrete waste form based on chemically bonded phosphate ceramics, and a ferrous iron/goethite treatment. These approaches rely on formation of insoluble forms of the contaminants of concern (lime addition and ceramicrete) and chemical reduction followed by co-precipitation (ferrous iron/goethite incorporation treatment). The results have demonstrated that release of the three most significant mobile contaminants of concern from tank residual wastes can be dramatically reduced after treatment compared to contact with simulated grout porewater without treatment. For uranium, all three treatments methods reduced the leachable uranium concentrations by well over three orders of magnitude. In the case of uranium and technetium, released concentrations were well below their respective MCLs for the wastes tested. For tank C-202 residual waste, chromium release concentrations were above the MCL but were considerably reduced relative to untreated tank waste. This innovative approach has the potential to revolutionize Hanford’s tank retrieval process, by allowing larger volumes of residual waste to be left in tanks while providing an acceptably low level of risk with respect to contaminant release that is protective of the environment and human health. Such an approach could enable DOE to realize significant cost savings through streamlined retrieval and closure operations.

  12. Analysis of Oxygenated Compounds in Hydrotreated Biomass Fast Pyrolysis Oil Distillate Fractions

    SciTech Connect (OSTI)

    Christensen, Earl D.; Chupka, Gina; Luecke, Jon; Smurthwaite, Tricia D.; Alleman, Teresa L.; Iisa, Kristiina; Franz, James A.; Elliott, Douglas C.; McCormick, Robert L.

    2011-10-06T23:59:59.000Z

    Three hydrotreated bio-oils with different oxygen contents (8.2, 4.9, and 0.4 w/w) were distilled to produce Light, Naphtha, Jet, Diesel, and Gasoil boiling range fractions that were characterized for oxygen containing species by a variety of analytical methods. The bio-oils were originally generated from lignocellulosic biomass in an entrained-flow fast pyrolysis reactor. Analyses included elemental composition, carbon type distribution by {sup 13}C NMR, acid number, GC-MS, volatile organic acids by LC, and carbonyl compounds by DNPH derivatization and LC. Acid number titrations employed an improved titrant-electrode combination with faster response that allowed detection of multiple endpoints in many samples and for acid values attributable to carboxylic acids and to phenols to be distinguished. Results of these analyses showed that the highest oxygen content bio-oil fractions contained oxygen as carboxylic acids, carbonyls, aryl ethers, phenols, and alcohols. Carboxylic acids and carbonyl compounds detected in this sample were concentrated in the Light, Naphtha, and Jet fractions (<260 C boiling point). Carboxylic acid content of all of the high oxygen content fractions was likely too high for these materials to be considered as fuel blendstocks although potential for blending with crude oil or refinery intermediate streams may exist for the Diesel and Gasoil fractions. The 4.9 % oxygen sample contained almost exclusively phenolic compounds found to be present throughout the boiling range of this sample, but imparting measurable acidity primarily in the Light, Naphtha and Jet fractions. Additional study is required to understand what levels of the weakly acidic phenols could be tolerated in a refinery feedstock. The Diesel and Gasoil fractions from this upgraded oil had low acidity but still contained 3 to 4 wt% oxygen present as phenols that could not be specifically identified. These materials appear to have excellent potential as refinery feedstocks and some potential for blending into finished fuels. Fractions from the lowest oxygen content oil exhibited some phenolic acidity, but generally contained very low levels of oxygen functional groups. These materials would likely be suitable as refinery feedstocks and potentially as fuel blend components. PIONA analysis of the Light and Naphtha fractions shows benzene content of 0.5 and 0.4 vol%, and predicted (RON + MON)/2 of 63 and 70, respectively.

  13. Directional wavelet transforms for prediction residuals in video coding

    E-Print Network [OSTI]

    Kamisli, Fatih

    Various directional transforms have been developed recently to improve image compression. In video compression, however, prediction residuals of image intensities, such as the motion compensation residual or the resolution ...

  14. 1-D Transforms for the Motion Compensation Residual

    E-Print Network [OSTI]

    Kamisli, Fatih

    Transforms used in image coding are also commonly used to compress prediction residuals in video coding. Prediction residuals have different spatial characteristics from images, and it is useful to develop transforms that ...

  15. In-Situ Method for Treating Residual Sodium

    DOE Patents [OSTI]

    Sherman, Steven R.; Henslee, S. Paul

    2005-07-19T23:59:59.000Z

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  16. Fluidized bed gasification of agricultural residue 

    E-Print Network [OSTI]

    Groves, John David

    1979-01-01T23:59:59.000Z

    is the only energy derived from such a system. The biomass energy project, of' which this re- search into gasification is a part, was designed to investi- gate both combustion and gasification as means to recover energy from agricultural wastes...FLUIDIZED BED GASIFICATION OF AGRICULTURAL RESIDUES A Thesis by JOHN DAVID GROVES Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1979 Major...

  17. Thin layer chromatography residue applicator sampler

    DOE Patents [OSTI]

    Nunes, Peter J. (Danville, CA); Kelly, Fredrick R. (Modesto, CA); Haas, Jeffrey S. (San Ramon, CA); Andresen, Brian D. (Livermore, CA)

    2007-07-24T23:59:59.000Z

    A thin layer chromatograph residue applicator sampler. The residue applicator sampler provides for rapid analysis of samples containing high explosives, chemical warfare, and other analyses of interest under field conditions. This satisfied the need for a field-deployable, small, hand-held, all-in-one device for efficient sampling, sample dissolution, and sample application to an analytical technique. The residue applicator sampler includes a sampling sponge that is resistant to most chemicals and is fastened via a plastic handle in a hermetically sealed tube containing a known amount of solvent. Upon use, the wetted sponge is removed from the sealed tube and used as a swiping device across an environmental sample. The sponge is then replaced in the hermetically sealed tube where the sample remains contained and dissolved in the solvent. A small pipette tip is removably contained in the hermetically sealed tube. The sponge is removed and placed into the pipette tip where a squeezing-out of the dissolved sample from the sponge into the pipette tip results in a droplet captured in a vial for later instrumental analysis, or applied directly to a thin layer chromatography plate for immediate analysis.

  18. Two-stage hydrotreating of a bitumen-derived middle distillate to produce diesel and jet fuels, and kinetics of aromatics hydrogenation

    SciTech Connect (OSTI)

    Yui, S.M. [Syncrude Canada Ltd., Edmonton, Alberta (Canada)

    1994-12-31T23:59:59.000Z

    The middle distillate from a synthetic crude oil derived from Athabasca bitumen was further hydrotreated in a downflow pilot unit over a typical NiMo catalyst at 330 to 400 C, 7 to 11 MPa and 0.63 to 1.39 h{sup {minus}1} LHSV. Feed and liquid products were characterized for aromatics, cetane index (CI) and other diesel specification items. Aromatics were determined by a supercritical fluid chromatography method, while CI was determined using the correlation developed at Syncrude Canada Ltd. Also feed and selected products were distilled into a jet fuel cut (150/260 C) by spinning band distillation for the determination of smoke point and other jet fuel specification items. A good relationship between aromatics content and CI was obtained. Kinetics of aromatics hydrogenation were investigated, employing a simple-first order reversible reaction model.

  19. REVIEW ARTICLE Impacts of calcium water treatment residue

    E-Print Network [OSTI]

    Ma, Lena

    REVIEW ARTICLE Impacts of calcium water treatment residue on the soil-water-plant system in citrus of calcium water treatment residue (Ca-WTR) for stabilizing Cu in soil and its subsequent influence on Cu. Keywords Calcium water treatment residue . Citrus production . Copper contamination . Soil pH . Remediation

  20. UNCORRECTEDPROOF Effect of channel bifurcation on residual estuarine circulation

    E-Print Network [OSTI]

    Voulgaris, George

    western channel. This is the result of the fact that the magnitude of residual flow scales with the water throughout the water column of the channel while in the adjacent shoals the residual flow is directedUNCORRECTEDPROOF Effect of channel bifurcation on residual estuarine circulation: Winyah Bay, South

  1. Welding residual stresses in ferritic power plant steels

    E-Print Network [OSTI]

    Cambridge, University of

    REVIEW Welding residual stresses in ferritic power plant steels J. A. Francis*1 , H. K. D. H require therefore, an accounting of residual stresses, which often are introduced during welding. To do in the estimation of welding residual stresses in austenitic stainless steels. The progress has been less convincing

  2. Waste Heat Recovery and Recycling in Thermal Separation Processes: Distillation, Multi-Effect Evaporation (MEE) and Crystallization Processes

    SciTech Connect (OSTI)

    Emmanuel A. Dada; Chandrakant B. Panchal; Luke K. Achenie; Aaron Reichl; Chris C. Thomas

    2012-12-03T23:59:59.000Z

    Evaporation and crystallization are key thermal separation processes for concentrating and purifying inorganic and organic products with energy consumption over 1,000 trillion Btu/yr. This project focused on a challenging task of recovering low-temperature latent heat that can have a paradigm shift in the way thermal process units will be designed and operated to achieve high-energy efficiency and significantly reduce the carbon footprint as well as water footprint. Moreover, this project has evaluated the technical merits of waste-heat powered thermal heat pumps for recovery of latent heat from distillation, multi-effect evaporation (MEE), and crystallization processes and recycling into the process. The Project Team has estimated the potential energy, economics and environmental benefits with the focus on reduction in CO2 emissions that can be realized by 2020, assuming successful development and commercialization of the technology being developed. Specifically, with aggressive industry-wide applications of heat recovery and recycling with absorption heat pumps, energy savings of about 26.7 trillion Btu/yr have been estimated for distillation process. The direct environmental benefits of this project are the reduced emissions of combustible products. The estimated major reduction in environmental pollutants in the distillation processes is in CO2 emission equivalent to 3.5 billion lbs/year. Energy consumption associated with water supply and treatments can vary between 1,900 kWh and 23,700 kWh per million-gallon water depending on sources of natural waters [US DOE, 2006]. Successful implementation of this technology would significantly reduce the demand for cooling-tower waters, and thereby the use and discharge of water treatment chemicals. The Project Team has also identified and characterized working fluid pairs for the moderate-temperature heat pump. For an MEE process, the two promising fluids are LiNO3+KNO3+NANO3 (53:28:19 ) and LiNO3+KNO3+NANO2(53:35:12). And for an H2O2 distillation process, the two promising fluids are Trifluoroethanol (TFE) + Triethylene Glycol Dimethyl ether (DMETEG) and Ammonia+ Water. Thermo-physical properties calculated by Aspen+ are reasonably accurate. Documentation of the installation of pilot-plants or full commercial units were not found in the literature for validating thermo-physical properties in an operating unit. Therefore, it is essential to install a pilot-scale unit to verify thermo-physical properties of working fluid pairs and validate the overall efficiency of the thermal heat pump at temperatures typical of distillation processes. For an HO2 process, the ammonia-water heat pump system is more compact and preferable than the TFE-DMETEG heat pump. The ammonia-water heat pump is therefore recommended for the H2O2 process. Based on the complex nature of the heat recovery system, we anticipated that capital costs could make investments financially unattractive where steam costs are low, especially where co-generation is involved. We believe that the enhanced heat transfer equipment has the potential to significantly improve the performance of TEE crystallizers, independent of the absorption heat-pump recovery system. Where steam costs are high, more detailed design/cost engineering will be required to verify the economic viability of the technology. Due to the long payback period estimated for the TEE open system, further studies on the TEE system are not warranted unless there are significant future improvements to heat pump technology. For the H2O2 distillation cycle heat pump waste heat recovery system, there were no significant process constraints and the estimated 5 years payback period is encouraging. We therefore recommend further developments of application of the thermal heat pump in the H2O2 distillation process with the focus on the technical and economic viability of heat exchangers equipped with the state-of-the-art enhancements. This will require additional funding for a prototype unit to validate enhanced thermal performances of heat transfer equipment, evaluat

  3. PUFF TOO: a residual stress experiment

    SciTech Connect (OSTI)

    Smith, C.W.

    1980-04-01T23:59:59.000Z

    Following the passage of the dynamic effects in a contained explosive detonation, there remains a strong compressive stress field in the material about the cavity. In this experiment, a 454-kg (1000 lb) sphere of high explosive was detonated in saturated ashfall tuff. Instrumentation measured peak stresses over the range of 0.1 to 6.0 GPa (1 to 6 kbar) and the complete stress-time waveform, including the so-called residual stress, at the 0.1 GPa (1 kbar) peak stress range. Mineback revealed detonation-induced fractures and fractures induced by postevent work.

  4. Harvesting Residuals-Economic Energy Link

    E-Print Network [OSTI]

    Owens, E. T.; Curtis, D. B.

    HARVESTING RESIDUALS-ECONOMIC ENERGY LINK E.T. Owens, R.P.F. Research and Productivity Council, Fredericton, N.B. D.B. Curtis, P.Eng. Dept. Forests, Mines and ABSTRACT A description of systems used in integrated harvesting of quality...-for-energy. economics INTRODUCTION The conventional wisdom in efficient harvesting Was to leave the non-merchantable and marginal trees because they had no economic value in the market place. Current technology and a change in the relative values of energy from...

  5. Distilling two-atom distance information from intensity-intensity correlation functions RID A-5077-2009

    E-Print Network [OSTI]

    Chang, Jun-Tao; Evers, Joerg; Zubairy, M. Suhail

    2006-01-01T23:59:59.000Z

    can express the steady state of the first- and second-order correlation functions of the radiation field as follows: DISTILLING TWO-ATOM DISTANCE INFORMATION? PHYSICAL REVIEW A 74, 043820 #1;2006#2; 043820-3 G#1;1#2;#1;R,t#2;SS = X + X#19; cos#1;k...R? ? r12#2; + iX#3; sin#1;kR? ? r12#2; , #1;29#2; and G#1;2#2;#1;R1,R2,#17;#2;SS = #3;X + X#19; cos#1;kR? 1 ? r12#2; + iX#3; sin#1;kR? 1 ? r12#2;#4;#3;X + X#19; cos#1;kR? 2 ? r12#2; + iX#3; sin#1;kR? 2 ? r12#2;#4; + #6; j=1 15 Pjeqj j#17;. #1;30#2...

  6. Process for the hydroformylation of sulfur-containing thermally cracked petroleum residue and novel products thereof

    SciTech Connect (OSTI)

    Oswald, A.A.; Bhatia, R.N.; Mozeleski, E.J.; Glivicky, A.P.; Brueggeman, B.G.; Hooten, J.R.; Smith, C.M.; Hsu, C.S.

    1991-07-09T23:59:59.000Z

    This patent describes a hydroformylation-hydrogenation process comprising reacting an olefinic cracked petroleum distillate feed, produced from petroleum residue by high temperature thermal cracking, and containing C{sub 5} to C{sub 35}-1-n-alkyl olefins as the major type of olefin components, and organic sulfur compounds in concentrations exceeding 0.1% sulfur. It comprises at first with carbon monoxide and hydrogen at temperatures between about 50 and 250{degrees} C and pressures in the range of 50 to 6000 psi; in the presence of a Group VIII transition metal carbonyl complex catalyst in effective amounts to produce aldehydes of a semilinear character having an average of less than one alkyl branch per molecule and 20% by weight or more linear isomers, then with molecular hydrogen at temperatures between 100 and 250{degrees} C and pressures between 200 psi and 5000 psi (13.6 and 340 atm) in the presence of a hydrogenation catalyst in effective amounts the catalyst being sulfur resistant cobalt, molybdenum, nickel, or tungsten or a sulfide thereof to produce the corresponding alcohols of a semilinear character having an average of less than one alkyl branch per molecule and 20% by weight or more linear isomers, then with molecular hydrogen at temperatures between 100 and 250{degrees} C and pressures between 200 psi and 5000 psi (13.6 and 340 atm) in the presence of a hydrogenation catalyst in effective amounts the catalyst being sulfur resistant cobalt, molybdenum, nickel, or tungsten or a sulfide thereof to produce the corresponding alcohols of a semilinear character having an average of less than one alkyl branch per molecule.

  7. Combination process for upgrading residual oils

    SciTech Connect (OSTI)

    Busch, L.E.; Walters, P.W.; Zandona, O.

    1990-01-16T23:59:59.000Z

    This patent describes a method for upgrading high boiling residual portions of crude oils comprising metal contaminants, porphyrins, asphaltenes and high molecular weight multi-ring hydrocarbon material. It comprises: charging a high boiling residual portion of crude oil admixed with diluent in contact with suspended upflowing substantially inert fluidizable solids particulate material at an elevated thermal visbreaking temperature in a riser contact zone for a time sufficient to recover therefrom a vaporous hydrocarbon product higher boiling than gasoline partially decarbonized and demetallized to a lower contaminating metals level, quenching the vaporous product of thermal visbreaking below its dew point after separation from solids, charging quenched thermally modified high boiling hydrocarbon product with a crystalline zeolite cracking catalyst under cracking conditions for a hydrocarbon residence time in a riser cracking zone; recovering a hydrocarbon conversion product; separating a combined C{sub 4} minus wet gas product stream of the visbreaking and zeolite catalyst cracking operating to recover a C{sub 3}-C{sub 4} rich fraction separately from a C{sub 2} minus dry gas product fraction, and regenerating the crystalline zeolite contcontaining catalyst.

  8. Morphing of Geometric Composites via Residual Swelling

    E-Print Network [OSTI]

    Matteo Pezzulla; Steven A. Shillig; Paola Nardinocchi; Douglas P. Holmes

    2015-04-12T23:59:59.000Z

    Understanding and controlling the shape of thin, soft objects has been the focus of significant research efforts among physicists, biologists, and engineers in the last decade. These studies aim to utilize advanced materials in novel, adaptive ways such as fabricating smart actuators or mimicking living tissues. Here, we present the controlled growth-like morphing of 2D sheets into 3D shapes by introducing a new class of geometric composite structures that deform by residual swelling. The morphing of these geometric composites is dictated by both swelling and geometry, with diffusion controlling the swelling-induced actuation, and geometric confinement dictating the structure's deformed shape. Building on a simple mechanical analog, we develop an analytical model that quantitatively describes how the Gaussian and mean curvatures of a thin disk are affected by the interplay among geometry, mechanics, and swelling. This model is in excellent agreement with our experiments and numerics. We show that the dynamics of residual swelling is dictated by a competition between two characteristic diffusive length scales governed by geometry. Our results provide the first 2D analog of Timoshenko's classical formula for the thermal bending of bimetallic beams - our generalization explains how the Gaussian curvature of a 2D geometric composite is affected by geometry and elasticity. The understanding conferred by these results suggests that the controlled shaping of geometric composites may provide a simple complement to traditional manufacturing techniques.

  9. T-534: Vulnerability in the PDF distiller of the BlackBerry Attachment Service for the BlackBerry Enterprise Server

    Broader source: Energy.gov [DOE]

    BlackBerry advisory describes a security issue that the BlackBerry Attachment Service component of the BlackBerry Enterprise Server is susceptible to. The issue relates to a known vulnerability in the PDF distiller component of the BlackBerry Attachment Service that affects how the BlackBerry Attachment Service processes PDF files.

  10. Dissolution and compaction of albite sand in distilled water and pH-buffered carboxylic acid solutions: experiments at 100 degrees and 160 degrees C 

    E-Print Network [OSTI]

    Carpenter, Thomas Doyle

    1995-01-01T23:59:59.000Z

    and compaction were monitored to quantify the effects of organic acids on time-dependent compaction rates of albite. The effects of stress and fluid chemistry on the dissolution kinetics were also examined. Compared to distilled water, Si-based dissolution rates...

  11. Combustion turbine deposition observations from residual and simulated residual oil studies

    SciTech Connect (OSTI)

    Whitlow, G.A.; Cohn, A.; Lee, S.Y.; Mulik, P.R.; Sherlock, T.P.; Wenglarz, R.A.

    1983-01-01T23:59:59.000Z

    Burning residual oil in utility combustion turbines and the consequent deposition on blades and vanes may adversely affect reliability and operation. Corrosion and deposition data for combustion turbine materials have been obtained through dynamic testing in pressurized passages. The deposition produced by the 1900/sup 0/F (1038/sup 0/C) combustion gases from a simulated and a real residual oil on cooled Udimet 500 surfaces is described. Higher deposition rates for the doped fuel than for the real residual oil raised questions of whether true simulation with this approach can be achieved. Particles 4-8..mu.. m in diameter predominated in the gas stream, with some fraction in the 0.1-12 ..mu.. m range. Deposition rates seemed to be influenced by thermophoretic delivery of small molten particles, tentatively identified as magnesium pyro and metavanadates and free vanadium pentoxide, which may act to bond the larger solid particles arriving by inertial impaction to turbine surfaces. Estimated maintenance intervals for current utility turbines operating with washed and treated residual oil agreed well with field experience.

  12. Geothermal Energy Market Study on the Atlantic Coastal Plain: Technical Feasibility of use of Eastern Geothermal Energy in Vacuum Distillation of Ethanol Fuel

    SciTech Connect (OSTI)

    None

    1981-04-01T23:59:59.000Z

    The DOE is studying availability, economics, and uses of geothermal energy. These studies are being conducted to assure maximum cost-effective use of geothermal resources. The DOE is also aiding development of a viable ethanol fuel industry. One important point of the ethanol program is to encourage use of non-fossil fuels, such as geothermal energy, as process heat to manufacture ethanol. Geothermal waters available in the eastern US tend to be lower in temperature (180 F or less) than those available in the western states (above 250 F). Technically feasible use of eastern geothermal energy for ethanol process heat requires use of technology that lowers ethanol process temperature requirements. Vacuum (subatmospheric) distillation is one such technology. This study, then, addresses technical feasibility of use of geothermal energy to provide process heat to ethanol distillation units operated at vacuum pressures. They conducted this study by performing energy balances on conventional and vacuum ethanol processes of ten million gallons per year size. Energy and temperature requirements for these processes were obtained from the literature or were estimated (for process units or technologies not covered in available literature). Data on available temperature and energy of eastern geothermal resources was obtained from the literature. These data were compared to ethanol process requirements, assuming a 150 F geothermal resource temperature. Conventional ethanol processes require temperatures of 221 F for mash cooking to 240 F for stripping. Fermentation, conducted at 90 F, is exothermic and requires no process heat. All temperature requirements except those for fermentation exceed assumed geothermal temperatures of 150 F. They assumed a 130 millimeter distillation pressure for the vacuum process. It requires temperatures of 221 F for mash cooking and 140 F for distillation. Data indicate lower energy requirements for the vacuum ethanol process (30 million BTUs per hour) than for the conventional process (36 million BTUs per hour). Lower energy requirements result from improved process energy recovery. Data examined in this study indicate feasible use of eastern geothermal heated waters (150 F) to provide process heat for vacuum (130 mm Hg) ethanol distillation units. Data indicate additional heat sources are needed to raise geothermal temperatures to the 200 F level required by mash cooking. Data also indicate potential savings in overall process energy use through use of vacuum distillation technology. Further study is needed to confirm conclusions reached during this study. Additional work includes obtaining energy use data from vacuum ethanol distillation units currently operating in the 130 millimeter pressure range; economic analysis of different vacuum pressures to select an optimum; and operation of a pilot geothermally heated vacuum column to produce confirmatory process data.

  13. Method For Characterizing Residual Stress In Metals

    DOE Patents [OSTI]

    Jacobson, Loren A. (Santa Fe, NM); Michel, David J. (Alexandria, VA); Wyatt, Jeffrey R. (Burke, VA)

    2002-12-03T23:59:59.000Z

    A method is provided for measuring the residual stress in metals. The method includes the steps of drilling one or more holes in a metal workpiece to a preselected depth and mounting one or more acoustic sensors on the metal workpiece and connecting the sensors to an electronic detecting and recording device. A liquid metal capable of penetrating into the metal workpiece placed at the bottom of the hole or holes. A recording is made over a period of time (typically within about two hours) of the magnitude and number of noise events which occur as the liquid metal penetrates into the metal workpiece. The magnitude and number of noise events are then correlated to the internal stress in the region of the workpiece at the bottom of the hole.

  14. Recovery of gallium from aluminum industry residues

    SciTech Connect (OSTI)

    Carvalho, M.S.; Neto, K.C.M.; Nobrega, A.W.; Medeiros, J.A.

    2000-01-01T23:59:59.000Z

    A procedure is proposed to recover gallium from flue dust aluminum residues produced in plants by using solid-phase extraction with a commercial polyether-type polyurethane foam (PUF). Gallium can be separated from high concentrations of aluminum, iron, nickel, titanium, vanadium, copper, zinc, sulfate, fluoride, and chloride by extraction with PUF from 3 M sulfuric acid and 3 M sodium chloride concentration medium with at least a 92% efficiency. Gallium backextraction was fast and quantitative with ethanol solution. In all recovery steps commercial-grade reagents could be used, including tap water. The recovered gallium was precipitated with sodium hydroxide solution, purified by dissolution and precipitation, calcinated, and the final oxide was 98.6% pure.

  15. Process converts incineration slag into stabilized residue

    SciTech Connect (OSTI)

    Thauront, J.; Deneux-Mustin, S. (EMC-Services, Paris (France)); Durecu, S. (EMC-Services, Vandoeuvre-Les Nancy (France)); Fraysse, G. (EMC-Services, Saint-Vulbas (France)); Berthelin, J. (Centre de Pedologie Biologique, Vandoeuvre-Les Nancy (France))

    1994-12-01T23:59:59.000Z

    During 1973 and 1974, EMC-Services designed and built a physico-chemical treatment plant in Hombourg, in France's Alsatian region. The plant is still in operation. Since then, EMC-Services has developed substantial experience in environmental projects, becoming one of the top companies internationally with experience and practice in designing, building and operating hazardous waste treatment plants. EMC-Services operates in France in Salaise, Strasbourg, Mitry-Mory, and Saint-Vulbas, where eight incinerators treat solid, liquid, highly halogenated and nonhazardous industrial waste. The incinerators, built or updated by EMC-Services, have a total capacity of about 200,000 tons per year. In the new process, incineration of special industrial wastes produces non-volatilized solid residue or slag, which is sent for disposal, in compliance with regulations, to special disposal plants. Future European regulations will incorporate landfilling criteria requiring such slag to be stabilized.

  16. Bioassays of weathered residues of several organic phosphorus insecticides

    E-Print Network [OSTI]

    Hightower, Billie Gene

    1959-01-01T23:59:59.000Z

    at high temperatures on the residual toxicities of Gut hi on, Sevin, and toxaphene to the boll weevil, Anthonomus grandis Boh........................ . . . . ........ 3^ 3? The effects of simulated wind on the residual toxicities of Guthion, dieldrin..., and toxaphene dusts to the boll weevil, Anthonomus grandis Boh. 36 The effects of high temperatures on the residual toxicities of methyl parathion, malathion, and toxaphene to the boll weevil, Anthonomus grandis Boh...................... 3$ 5. The effects...

  17. Bioassays of weathered residues of several organic phosphorus insecticides 

    E-Print Network [OSTI]

    Hightower, Billie Gene

    1959-01-01T23:59:59.000Z

    at high temperatures on the residual toxicities of Gut hi on, Sevin, and toxaphene to the boll weevil, Anthonomus grandis Boh........................ . . . . ........ 3^ 3? The effects of simulated wind on the residual toxicities of Guthion, dieldrin..., and toxaphene dusts to the boll weevil, Anthonomus grandis Boh. 36 The effects of high temperatures on the residual toxicities of methyl parathion, malathion, and toxaphene to the boll weevil, Anthonomus grandis Boh...................... 3$ 5. The effects...

  18. antimicrobial residue monitoring: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    though no flow is present. The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The...

  19. acs residual ischemic: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    though no flow is present. The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The...

  20. acetamido trideoxyhexose residue: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The theory describes this...

  1. autophosphorylated residues required: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    though no flow is present. The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The...

  2. abradable coating residual: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The theory describes this...

  3. A Practical Model for Mobile, Residual, and Entrapped NAPL in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    phase. Residual NAPL is defined as immobile, nonwater entrapped NAPL that does not drain from the pore spaces and is conceptualized as being either continuous or...

  4. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22T23:59:59.000Z

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  5. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Prices," source for backcast estimates prior to January 1983. 19. U.S. Refiner Residual Fuel Oil Prices 36 Energy Information Administration Petroleum Marketing Annual 1997...

  6. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Prices," source for backcast estimates prior to January 1983. 19. U.S. Refiner Residual Fuel Oil Prices 36 Energy Information Administration Petroleum Marketing Annual 1996...

  7. active site residue: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in human transferrin and Tyr Oksana Lockridge 2008-01-01 140 RESEARCH ARTICLE Benefits of organic residues and chemical fertilizer Biology and Medicine Websites Summary: RESEARCH...

  8. active site residues: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in human transferrin and Tyr Oksana Lockridge 2008-01-01 140 RESEARCH ARTICLE Benefits of organic residues and chemical fertilizer Biology and Medicine Websites Summary: RESEARCH...

  9. acid residues determine: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tomihiro Takano; Yasuhiro Kojima; Tetsufumi Ohno 2013-01-01 206 EFFECTIVE RESIDUE-TILLAGE-MANURE Biology and Medicine Websites Summary: AS POSSIBLE KEEP RECORDS 12;SPREADER...

  10. Water dynamics clue to key residues in protein folding

    SciTech Connect (OSTI)

    Gao, Meng [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Zhu, Huaiqiu, E-mail: hqzhu@pku.edu.cn [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Yao, Xin-Qiu [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China) [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Department of Biophysics, Kyoto University, Sakyo Kyoto 606-8502 (Japan); She, Zhen-Su, E-mail: she@pku.edu.cn [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)

    2010-01-29T23:59:59.000Z

    A computational method independent of experimental protein structure information is proposed to recognize key residues in protein folding, from the study of hydration water dynamics. Based on all-atom molecular dynamics simulation, two key residues are recognized with distinct water dynamical behavior in a folding process of the Trp-cage protein. The identified key residues are shown to play an essential role in both 3D structure and hydrophobic-induced collapse. With observations on hydration water dynamics around key residues, a dynamical pathway of folding can be interpreted.

  11. Residual Stresses for Structural Analysis and Fatigue Life Prediction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stresses for Structural Analysis and Fatigue Life Prediction in Vehicle Components: Success stories from the High Temperature Materials Laboratory (HTML) User Program Residual...

  12. TEXAS LPG FUEL CELL DEVELOPMENT AND DEMONSTRATION PROJECT Full-Text - Submission contains both citation data and full-text of the journal article. Full-text can be either a pre-print or post-print, but not the copyrighted article.

    SciTech Connect (OSTI)

    SOUTHWEST RESEARCH LABORATORY SUBMITTED BY SUBCONTRACTOR, RAILROAD COMMISSION OF TEXAS

    2004-07-26T23:59:59.000Z

    The State Energy Conservation Office has executed its first Fuel Cell Project which was awarded under a Department of Energy competitive grant process. The Texas LPG Fuel Processor Development and Fuel Cell Demonstration Program is a broad-based public/private partnership led by the Texas State Energy Conservation Office (SECO). Partners include the Alternative Fuels Research and Education Division (AFRED) of the Railroad Commission of Texas; Plug Power, Inc., Latham, NY, UOP/HyRadix, Des Plaines, IL; Southwest Research Institute (SwRI), San Antonio, TX; the Texas Natural Resource Conservation Commission (TNRCC), and the Texas Department of Transportation (TxDOT). The team proposes to mount a development and demonstration program to field-test and evaluate markets for HyRadix?s LPG fuel processor system integrated into Plug Power?s residential-scale GenSys? 5C (5 kW) PEM fuel cell system in a variety of building types and conditions of service. The program?s primary goal is to develop, test, and install a prototype propane-fueled residential fuel cell power system supplied by Plug Power and HyRadix in Texas. The propane industry is currently funding development of an optimized propane fuel processor by project partner UOP/HyRadix through its national checkoff program, the Propane Education and Research Council (PERC). Following integration and independent verification of performance by Southwest Research Institute, Plug Power and HyRadix will produce a production-ready prototype unit for use in a field demonstration. The demonstration unit produced during this task will be delivered and installed at the Texas Department of Transportation?s TransGuide headquarters in San Antonio, Texas. Simultaneously, the team will undertake a market study aimed at identifying and quantifying early-entry customers, technical and regulatory requirements, and other challenges and opportunities that need to be addressed in planning commercialization of the units. For further information please contact Mary-Jo Rowan at mary-jo.rowan@cpa.state.tx.us

  13. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26T23:59:59.000Z

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

  14. RESIDUAL STRESS EFFECTS IN FRACTURE OF COMPOSITES AND ADHESIVES

    E-Print Network [OSTI]

    Nairn, John A.

    RESIDUAL STRESS EFFECTS IN FRACTURE OF COMPOSITES AND ADHESIVES JOHN A. NAIRN ABSTRACT Because composites and adhesive joints are made from different phases with different thermal expansion coefficients, they inevitably develop residual thermal stresses. When designing composites or adhesive joints, it is important

  15. Randomized Quantile Residuals Peter K. Dunn and Gordon K. Smyth

    E-Print Network [OSTI]

    Smyth, Gordon K.

    . Keywords: deviance residual; exponential regression; generalized linear model; lo- gistic regression, play a central role in the checking of statistical models. In normal linear regression the residuals are normally distributed and can be standardized to have equal variances. In non-normal regression situations

  16. Minimization of welding residual stress and distortion in large structures

    E-Print Network [OSTI]

    Michaleris, Panagiotis

    1 Minimization of welding residual stress and distortion in large structures P. Michaleris at Champaign Urbana, Urbana, IL Abstract Welding distortion in large structures is usually caused by buckling due to the residual stress. In cases where the design is fixed and minimum weld size requirements

  17. Modeling Sustainable Agricultural Residue Removal at the Subfield Scale

    SciTech Connect (OSTI)

    Muth, D.J.; McCorkle, D.S.; Koch, J.B.; Bryden, K.M.

    2012-05-02T23:59:59.000Z

    This study developed a computational strategy that utilizes data inputs from multiple spatial scales to investigate how variability within individual fields can impact sustainable residue removal for bioenergy production. Sustainable use of agricultural residues for bioenergy production requires consideration of the important role that residues play in limiting soil erosion and maintaining soil C, health, and productivity. Increased availability of subfield-scale data sets such as grain yield data, high-fidelity digital elevation models, and soil characteristic data provides an opportunity to investigate the impacts of subfield-scale variability on sustainable agricultural residue removal. Using three representative fields in Iowa, this study contrasted the results of current NRCS conservation management planning analysis with subfield-scale analysis for rake-and-bale removal of agricultural residue. The results of the comparison show that the field-average assumptions used in NRCS conservation management planning may lead to unsustainable residue removal decisions for significant portions of some fields. This highlights the need for additional research on subfield-scale sustainable agricultural residue removal including the development of real-time variable removal technologies for agricultural residue.

  18. Original article Residues in wax and honey after Apilife VAR®

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Original article Residues in wax and honey after Apilife VAR® treatment Stefan Bogdanov Anton and foundation were exposed to the air during storage. © Inra/DIB/AGIB/Elsevier, Paris honey / wax / residue to accumulation of these substances in beeswax and less so in honey [1, 17]. The accumulation in wax depends

  19. Computing Symmetrized Weight Enumerators for Lifted Quadratic Residue Codes

    E-Print Network [OSTI]

    Duursma, Iwan M.

    Computing Symmetrized Weight Enumerators for Lifted Quadratic Residue Codes I. M. Duursma Dept for the computation of structural parameters for ring-linear codes. This article therefore presents a method to eÃ?ciently compute weight enumerators of linear codes over primary integer residue rings. For the lifted QR-codes

  20. Residual Energy-Aware Cooperative Transmission (REACT) in Wireless Networks

    E-Print Network [OSTI]

    Leung, Kin K.

    Residual Energy-Aware Cooperative Transmission (REACT) in Wireless Networks Erwu Liu, Qinqing Zhang the lifetime of the network and we call the selection method a residual energy-aware cooperative transmission- works, where energy efficiency is a critical design consideration. We assume that multiple relay nodes

  1. Parallel FPGA Implementation of RSA with Residue Number Systems

    E-Print Network [OSTI]

    Parallel FPGA Implementation of RSA with Residue Number Systems --- Can side­channel threats Multiplication based on Residue Num­ ber Systems. Thanks to RNS, we develop a design able to perform an RSA signature in parallel on a set of identical and independent copro­ cessors. Of independent interest, we

  2. Parallel FPGA Implementation of RSA with Residue Number Systems

    E-Print Network [OSTI]

    Parallel FPGA Implementation of RSA with Residue Number Systems -- Can side-channel threats Multiplication based on Residue Num- ber Systems. Thanks to RNS, we develop a design able to perform an RSA signature in parallel on a set of identical and independent copro- cessors. Of independent interest, we

  3. Conversion of direct process high-boiling residue to monosilanes

    DOE Patents [OSTI]

    Brinson, Jonathan Ashley (Vale of Glamorgan, GB); Crum, Bruce Robert (Madison, IN); Jarvis, Jr., Robert Frank (Midland, MI)

    2000-01-01T23:59:59.000Z

    A process for the production of monosilanes from the high-boiling residue resulting from the reaction of hydrogen chloride with silicon metalloid in a process typically referred to as the "direct process." The process comprises contacting a high-boiling residue resulting from the reaction of hydrogen chloride and silicon metalloid, with hydrogen gas in the presence of a catalytic amount of aluminum trichloride effective in promoting conversion of the high-boiling residue to monosilanes. The present process results in conversion of the high-boiling residue to monosilanes. At least a portion of the aluminum trichloride catalyst required for conduct of the process may be formed in situ during conduct of the direct process and isolation of the high-boiling residue.

  4. Phase Chemistry of Tank Sludge Residual Components

    SciTech Connect (OSTI)

    J.L. Krumhansl

    2002-04-02T23:59:59.000Z

    The US Department of Energy (DOE) has millions of gallons of high level nuclear waste stored in underground tanks at Hanford, Washington and Savannah River, South Carolina. These tanks will eventually be emptied and decommissioned. This will leave a residue of sludge adhering to the interior tank surfaces that may contaminate nearby groundwaters with radionuclides and RCRA metals. Performance assessment (PA) calculations must be carried out prior to closing the tanks. This requires developing radionuclide release models from the sludges so that the PA calculations can be based on credible source terms. These efforts continued to be hindered by uncertainties regarding the actual nature of the tank contents and the distribution of radionuclides among the various phases. In particular, it is of vital importance to know what radionuclides are associated with solid sludge components. Experimentation on actual tank sludges can be difficult, dangerous and prohibitively expensive. The research funded under this grant for the past three years was intended to provide a cost-effective method for developing the needed radionuclide release models using non-radioactive artificial sludges. Insights gained from this work will also have more immediate applications in understanding the processes responsible for heel development in the tanks and in developing effective technologies for removing wastes from the tanks.

  5. DDT RESIDUES IN SEAWATER AND PARTICULATE MATTER IN THE CALIFORNIA CURRENT SYSTEM

    E-Print Network [OSTI]

    DDT RESIDUES IN SEAWATER AND PARTICULATE MATTER IN THE CALIFORNIA CURRENT SYSTEM JAMES L. COX in the California current system were analyzed for DDT residues. DDT residue concentrations in whole seawater are discussed in relation to mechanisms of land-sea DDT residue transfer. DDT residue concentrations

  6. Single-well experimental design for studying residual trapping of superciritcal carbon dioxide

    E-Print Network [OSTI]

    Zhang, Y.

    2010-01-01T23:59:59.000Z

    nonaqueous phase liquid and water residual. Environ. Sci.plume near residual saturation; and (4) water injection intoboth a water-saturated system and a system with residual gas

  7. Evaluation of approaches to quantify total residual oxidants in ballast water management systems employing chlorine for disinfection

    E-Print Network [OSTI]

    Zimmer-Faust, AG; Ambrose, RF; Ambrose, RF; Tamburri, MN

    2014-01-01T23:59:59.000Z

    quantify total residual oxidants in ballast water managementand discharge (residual concentrations) during ballast waterquantifying residual chlorine levels in natural waters (e.g.

  8. Residual zonal flows in tokamaks and stellarators at arbitrary wavelengths

    E-Print Network [OSTI]

    Monreal, P; Sánchez, E; Parra, F I; Bustos, A; Könies, A; Kleiber, R; Görler, T

    2015-01-01T23:59:59.000Z

    In the linear collisionless limit, a zonal potential perturbation in a toroidal plasma relaxes, in general, to a non-zero residual value. Expressions for the residual value in tokamak and stellarator geometries, and for arbitrary wavelengths, are derived. These expressions involve averages over the lowest order particle trajectories, that typically cannot be evaluated analytically. In this work, an efficient numerical method for the evaluation of such expressions is reported. It is shown that this method is faster than direct gyrokinetic simulations. Calculations of the residual value in stellarators are provided for much shorter wavelengths than previously available in the literature. Electrons must be treated kinetically in stellarators because, unlike in tokamaks, kinetic electrons modify the residual value even at long wavelengths. This effect, that had already been predicted theoretically, is confirmed by gyrokinetic simulations.

  9. An urban infill : a residual site in Boston

    E-Print Network [OSTI]

    Savvides, Andreas L. (Andreas Loucas)

    1996-01-01T23:59:59.000Z

    This thesis is concerned with the treatment of residual sites in the context of the urban environment and in particular with the wounds inflicted by the passage of the Massachusetts Turnpike through the city of Boston. The ...

  10. Residual dust charges in an afterglow plasma , M. Mikikian

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    plasma was performed in a rf discharge. An upward thermophoretic force was used to balance]. For the study concerning residual charges, the top electrode was cooled. An upward thermophoretic force

  11. Minimizing High Spatial Frequency Residual in Active Space Telescope Mirrors

    E-Print Network [OSTI]

    . Miller June 2008 SSL # 4-08 #12;#12;Minimizing High Spatial Frequency Residual in Active Space Telescope Mirrors Thomas Gray, David W. Miller June 2008 SSL # 4-08 This work is based on the unaltered text

  12. RetroFILL : residual spaces as urban infill

    E-Print Network [OSTI]

    Kobel, Marika

    2010-01-01T23:59:59.000Z

    In any city there are small slivers and chunks of awkward spaces - in between buildings, occupying edge conditions, not large enough to warrant many forms of traditional use - which can be termed residual. These areas of ...

  13. Residual stress in electrodeposited nanocrystalline nickel-tungsten coatings

    E-Print Network [OSTI]

    Ziebell, Tiffany D.

    Characterizing the residual stress of thick nanocrystalline electrodeposits poses several unique challenges due to their fine grain structure, thickness distribution, and matte surface. We use a three-dimensional ...

  14. Modeling, Optimization and Economic Evaluation of Residual Biomass Gasification 

    E-Print Network [OSTI]

    Georgeson, Adam

    2012-02-14T23:59:59.000Z

    Gasification is a thermo-chemical process which transforms biomass into valuable synthesis gas. Integrated with a biorefinery it can address the facility’s residue handling challenges and input demands. A number of feedstock, technology, oxidizer...

  15. Asphalt landscape after all : residual suburban surface as public infrastructure

    E-Print Network [OSTI]

    O'Connor, Joseph Michael, M. Arch. Massachusetts Institute of Technology

    2011-01-01T23:59:59.000Z

    The thesis proposes a hybridized commercial retail strip inserted into a residual suburban condition as a manner of investigating the latent potential of suburban logic, both its constituent elements and its formal rules ...

  16. Palatability of post-extraction algal residue as a protein supplement for cattle.

    SciTech Connect (OSTI)

    Drewery, M. L. [Texas A& M University; Sawyer, J. E. [Texas A& M University; Wickersham, T. A. [Texas A& M University

    2012-12-01T23:59:59.000Z

    Market value of post-extraction algal residue (PEAR) is driven by its ability to compete with commonly fed protein sources; for example cottonseed meal (CSM) and dried distillers’ grains (DDG). An initial step in evaluating PEAR (20% CP, 59% OM) is to determine palatability when fed as a protein supplement. Accordingly, we evaluated the palatability of PEAR-containing supplements in cattle consuming a basal diet of Bermudagrass (13% CP, 76% NDF). Twelve steers were used in a 12 × 12 Latin square experiment consisting of 12 4-d periods. Each period included 3-d where steers were fed a test supplement and a 1-d washout where steers were fed DDG. Supplements were formulated with different carrier ingredients (DDG, CSM, or liquid supplement, LS) and different levels of PEAR inclusion (0, 20, 40, and 60% for DDG and CSM and 0, 33, 66, and 100% for LS). Intake and time required for consumption were recorded daily. A significant (P < 0.05) treatment × day interaction for g consumed per min (GPM) was observed. This interaction resulted from changing rates of consumption as cattle adapted to supplements. Supplements containing DDG had the greatest rates of consumption (177 – 187 GPM), followed by CSM supplements (148 – 166 GPM). Blends including PEAR and LS had slower rates of consumption (58 – 93 GPM). Supplement formulation significantly (P < 0.05) affected the amount of supplement consumed and time required for complete consumption. Supplements which contained DDG or CSM were consumed in less than 11 min; complete consumption was observed 92 – 100% of the time. Treatments containing LS required more time for complete consumption (21 – 33 min) and were finished 77 – 96% of the time. Our results suggest PEAR can be blended (up to 60%) with existing ingredients utilized in beef rations to create suitable protein supplements. However, PEAR is not palatable when offered alone (complete consumption of 100% PEAR occurred 77.5% of the time and required 31.5 min) or incorporated into LS. Additional research is necessary to determine the impact of PEAR on nutrient utilization in cattle.

  17. An investigation of residual stress in welded joints

    E-Print Network [OSTI]

    Moffat, William Hugh

    1951-01-01T23:59:59.000Z

    . flummery and Conclusions VII. '-. &uggested Procedure for I"uture Investigation 18 o i' VIII. ? . Ppendix IX. Bibliography LIST OP EIGURES Ro. Title Page 1. 'welded Plates snd Gptical Gage Used by Soulton and Martin ~ ~ 6 2. Dr. Rao~s Method... AN INVESTIGATION OF RESIDUAL STRESS IN WELDED JOINTS INTRODUCTION The object of the research reported in this paper was to investigate the magnitude of transverse and longi- tudial residual stress in a welded Joint. These are the stresses in a direction...

  18. An investigation of residual stress in welded joints 

    E-Print Network [OSTI]

    Moffat, William Hugh

    1951-01-01T23:59:59.000Z

    . flummery and Conclusions VII. '-. &uggested Procedure for I"uture Investigation 18 o i' VIII. ? . Ppendix IX. Bibliography LIST OP EIGURES Ro. Title Page 1. 'welded Plates snd Gptical Gage Used by Soulton and Martin ~ ~ 6 2. Dr. Rao~s Method... AN INVESTIGATION OF RESIDUAL STRESS IN WELDED JOINTS INTRODUCTION The object of the research reported in this paper was to investigate the magnitude of transverse and longi- tudial residual stress in a welded Joint. These are the stresses in a direction...

  19. GEOCHEMICAL TESTING AND MODEL DEVELOPMENT - RESIDUAL TANK WASTE TEST PLAN

    SciTech Connect (OSTI)

    CANTRELL KJ; CONNELLY MP

    2010-03-09T23:59:59.000Z

    This Test Plan describes the testing and chemical analyses release rate studies on tank residual samples collected following the retrieval of waste from the tank. This work will provide the data required to develop a contaminant release model for the tank residuals from both sludge and salt cake single-shell tanks. The data are intended for use in the long-term performance assessment and conceptual model development.

  20. Residue disposal from waste-to-energy facilities

    SciTech Connect (OSTI)

    Walsh, P.; O'Leary, P.; Cross, F.

    1987-05-01T23:59:59.000Z

    When considering a waste-to-energy project, some local officials believe that waste-to-energy is a complete alternative to landfilling. While these projects can reduce waste volume substantially, the process will still produce residues that must be properly handled in order to protect the environment. All systems produce fly ash and bottom ash, and some systems also produce wastewater. This article discusses alternative methods for addressing these residue control problems.

  1. Residual stresses and stress corrosion cracking in pipe fittings

    SciTech Connect (OSTI)

    Parrington, R.J.; Scott, J.J.; Torres, F.

    1994-06-01T23:59:59.000Z

    Residual stresses can play a key role in the SCC performance of susceptible materials in PWR primary water applications. Residual stresses are stresses stored within the metal that develop during deformation and persist in the absence of external forces or temperature gradients. Sources of residual stresses in pipe fittings include fabrication processes, installation and welding. There are a number of methods to characterize the magnitude and orientation of residual stresses. These include numerical analysis, chemical cracking tests, and measurement (e.g., X-ray diffraction, neutron diffraction, strain gage/hole drilling, strain gage/trepanning, strain gage/section and layer removal, and acoustics). This paper presents 400 C steam SCC test results demonstrating that residual stresses in as-fabricated Alloy 600 pipe fittings are sufficient to induce SCC. Residual stresses present in as-fabricated pipe fittings are characterized by chemical cracking tests (stainless steel fittings tested in boiling magnesium chloride solution) and by the sectioning and layer removal (SLR) technique.

  2. (distillation) (Le Chatelier

    E-Print Network [OSTI]

    Hong, Deog Ki

    acetate(methyl-, ethyl-, butyl-) , methanol isobutene MTBE , ethanol isobutene ETBE , methanol 2-methyl-1% MTBE 3 DMC . 2% 1990 MTBE 1999 3 2002 MTBE . [ 1-1 ] Phosgene process polycarbonate(PC) 50/ . DMC DMC MTBE / . ( : Amoco, "Review of DMC Manufacture and its

  3. INNOVATION EDUCATION EXCELLENCE DISTILLATIONS

    E-Print Network [OSTI]

    Chan, Hue Sun

    more efficient solar energy devices. It turns out it could also help to design the next revolution of this work. Vy Dong and her students have devised ways to make double ring compounds. Mark Lautens and his that emit differ- ent colours depending on which DNA strand is pres- ent. Deborah Zamble's and Mark Nitz

  4. Measuring depth profiles of residual stress with Raman spectroscopy

    SciTech Connect (OSTI)

    Enloe, W.S.; Sparks, R.G.; Paesler, M.A.

    1988-12-01T23:59:59.000Z

    Knowledge of the variation of residual stress is a very important factor in understanding the properties of machined surfaces. The nature of the residual stress can determine a part`s susceptibility to wear deformation, and cracking. Raman spectroscopy is known to be a very useful technique for measuring residual stress in many materials. These measurements are routinely made with a lateral resolution of 1{mu}m and an accuracy of 0.1 kbar. The variation of stress with depth; however, has not received much attention in the past. A novel technique has been developed that allows quantitative measurement of the variation of the residual stress with depth with an accuracy of 10nm in the z direction. Qualitative techniques for determining whether the stress is varying with depth are presented. It is also demonstrated that when the stress is changing over the volume sampled, errors can be introduced if the variation of the stress with depth is ignored. Computer aided data analysis is used to determine the depth dependence of the residual stress.

  5. DDT residues in human milk samples from Delhi, India

    SciTech Connect (OSTI)

    Zaidi, S.S.A.; Bhatnagar, V.K.; Banerjee, B.D.; Balakrishnan, G.; Shah, M.P.

    1989-03-01T23:59:59.000Z

    The widespread use of DDT in India has resulted in increased levels of the insecticide in the ecosystem and, therefore, the potential possible health hazards has been voiced. DDT-residues excreted in milk have been reported from different parts of the world; however, very few reports did appear from India. In fact, there is no report on DDT-content in human milk from Delhi area where higher levels of DDT and BHC in human adipose tissues and blood have already been reported. Higher bioaccumulation of DDT might reflect the higher excretion of residues in milk. The authors have, therefore, attempted a systematic study to monitor DDT-residues in human milk samples collected from various hospitals of Delhi (India).

  6. Residual strain mapping of Roman styli from Iulia Concordia, Italy

    SciTech Connect (OSTI)

    Salvemini, Filomena, E-mail: floriana.salvemini@fi.isc.cnr.it [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Sesto Fiorentino, FI (Italy); Università degli Studi di Firenze, Dipartimento di Scienze della Terra (Italy); Grazzi, Francesco [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Sesto Fiorentino, FI (Italy); Angelini, Ivana [Università degli Studi di Padova, Dipartimento di Geoscienze (Italy); Davydov, Vadim; Vontobel, Peter [Paul Scherrer Institut, SINQ Spallation Neutron Source, Villigen (Switzerland); Vigoni, Alberto [Dedalo s.n.c., Vicolo dei Conti 6, I-35122 Padua (Italy); Artioli, Gilberto [Università degli Studi di Padova, Dipartimento di Geoscienze (Italy); Zoppi, Marco [Consiglio Nazionale delle Ricerche, Istituto dei Sistemi Complessi, Sesto Fiorentino, FI (Italy)

    2014-05-01T23:59:59.000Z

    Iulia Concordia is an important Roman settlement known for the production of iron objects and weapons during the Roman Empire. A huge number of well-preserved styli were found in the past century in the bed of an old channel. In order to shed light about the production processes used by Roman for stylus manufacturing, a neutron diffraction residual strain analysis was performed on the POLDI materials science diffractometer at the Paul Scherrer Institut in Switzerland. Here, we present results from our investigation conducted on 11 samples, allowing to define, in a non-invasive way, the residual strain map related to the ancient Roman working techniques. - Highlights: • We examined 11 Roman styli from the settlement of Iulia Concordia, Italy. • We performed a neutron diffraction residual strain analysis on POLDI at PSI (CH). • We identified the production processes used by Roman for stylus manufacturing. • We clarified the way and direction of working applied for different classes of styli.

  7. Wave induced residual pore-water pressures in sandbeds

    E-Print Network [OSTI]

    DeVries, Jack Walter

    1986-01-01T23:59:59.000Z

    Subject: Ocean Engineering WAVE INDUCED RESIDUAL PORE-WATER PRESSURES IN SANDBEDS A Thesis by Jack W. Deyries Approved as to style and content by: J. B. Her bich (Chairman of Committee) Y. K. Lou (Member) W. A. Dunlap (Member) R. O. Reid (Member... on a buried pipel1ne using both analytical and numerical approaches. Also, a few attempts have been made at describing the generation of residual pore-water pressures using numerical methods. These attempts do not have a data base to work from...

  8. The determination of thru-thickness residual bending stresses

    E-Print Network [OSTI]

    Rinehart, Adam James

    2000-01-01T23:59:59.000Z

    by Bidirectional Bending for the Case y?, & y, , 110 5-1 Finite Elemenl, Mesh Used in Study 116 5-2 Comparison ol Percent Deviation of 100 and 200 Element. FE Models from Exact Solution, 800 k-in Released Moment, No Initial Stresses 123 5-3 Comparison of 200... Elcmcnt FE Solution to Exact Solution for Residual Stress Distribution Produced by 800 k-in Released Momem. in an Initially Stress Free Cross Section, . 124 5-4 Residual Stress Distributions for Increasing Levels of Released Moment, Initially Stress...

  9. Wood residuals find big uses in small pieces

    SciTech Connect (OSTI)

    Glenn, J.

    1996-12-01T23:59:59.000Z

    With a history of finding economic uses for leftovers, the wood industry explores sustainable options for creating higher value products. Years ago, companies saw the use - any use - of residues as a sound, economic business practice. Today, many companies are looking to go beyond low value products such as mulch, animal bedding and fuel, and market to higher value end users. Additionally, with so much material from the primary industries already accounted for, consumers of wood residue are in need of additional supply from sources such as secondary mills (furniture manufacturers, etc.), as wells as the C&D and MSW streams. This paper discusses these products and markets.

  10. Prediction of middle-distillate fuel properties using liquid chromatography-proton nuclear magnetic resonance spectroscopy data. Final report, 1987-1988

    SciTech Connect (OSTI)

    Swann, M.

    1989-06-01T23:59:59.000Z

    This research was initiated to support the Army's capability to identify the components of fuels that contribute to low-temperature performance of fuels. It was discovered that various physical properties of middle-distillate fuels can be predicted. The LC-{sup 1}HNMR technique was developed to predict physical properties based on chemical structures present in the fuels. The prediction of properties is approached from a 'group property' point of view. In the group property approach, the structure of the molecule is examined for structural features that dictate the physical properties of the compounds. In other words, the physical properties of a molecule or compound are determined by the number of types of chemical groups, i.e., methyl, methylene, methine, etc., present. These LC-{sup 1}H NMR predicted property measurements were compared to measurements obtained by the ASTM fuel tests. Most measurements were found to be within experimental error. The research has demonstrated that the LC-{sup 1}H NMR approach for measuring various middle-distillate fuel properties can be used as an alternative to the ASTM methods of fuel property measurement.

  11. Single-Step Syngas-to-Distillates (S2D) Process Based on Biomass-Derived Syngas – A Techno-Economic Analysis

    SciTech Connect (OSTI)

    Zhu, Yunhua; Jones, Susanne B.; Biddy, Mary J.; Dagle, Robert A.; Palo, Daniel R.

    2012-08-01T23:59:59.000Z

    This study reports the comparison of biomass gasification based syngas-to-distillate (S2D) systems using techno-economic analysis (TEA). Three cases, state of technology (SOT) case, goal case, and conventional case, were compared in terms of performance and cost. The SOT case and goal case represent technology being developed at Pacific Northwest National Laboratory for a process starting with syngas using a single-step dual-catalyst reactor for distillate generation (S2D process). The conventional case mirrors the two-step S2D process previously utilized and reported by Mobil using natural gas feedstock and consisting of separate syngas-to-methanol and methanol-to-gasoline (MTG) processes. Analysis of the three cases revealed that the goal case could indeed reduce fuel production cost over the conventional case, but that the SOT was still more expensive than the conventional. The SOT case suffers from low one-pass yield and high selectivity to light hydrocarbons, both of which drive up production cost. Sensitivity analysis indicated that light hydrocarbon yield, single pass conversion efficiency, and reactor space velocity are the key factors driving the high cost for the SOT case.

  12. Single-Step Syngas-to-Distillates (S2D) Process Based on Biomass-Derived Syngas - A Techno-Economic Analysis

    SciTech Connect (OSTI)

    Zhu, Y.; Jones, S. B.; Biddy, M. J.; Dagle, R. A.; Palo, D. R.

    2012-08-01T23:59:59.000Z

    This study compared biomass gasification based syngas-to-distillate (S2D) systems using techno-economic analysis (TEA). Three cases, state of technology (SOT), goal, and conventional, were compared in terms of performance and cost. The SOT case represented the best available experimental results for a process starting with syngas using a single-step dual-catalyst reactor for distillate generation. The conventional case mirrored a conventional two-step S2D process consisting of separate syngas-to-methanol and methanol-to-gasoline (MTG) processes. The goal case assumed the same performance as the conventional, but with a single-step S2D technology. TEA results revealed that the SOT was more expensive than the conventional and goal cases. The SOT case suffers from low one-pass yield and high selectivity to light hydrocarbons, both of which drive up production cost. Sensitivity analysis indicated that light hydrocarbon yield and single pass conversion efficiency were the key factors driving the high cost for the SOT case.

  13. A Residual Mass Ballistic Testing Method to Compare Armor Materials or Components (Residual Mass Ballistic Testing Method)

    SciTech Connect (OSTI)

    Benjamin Langhorst; Thomas M Lillo; Henry S Chu

    2014-05-01T23:59:59.000Z

    A statistics based ballistic test method is presented for use when comparing multiple groups of test articles of unknown relative ballistic perforation resistance. The method is intended to be more efficient than many traditional methods for research and development testing. To establish the validity of the method, it is employed in this study to compare test groups of known relative ballistic performance. Multiple groups of test articles were perforated using consistent projectiles and impact conditions. Test groups were made of rolled homogeneous armor (RHA) plates and differed in thickness. After perforation, each residual projectile was captured behind the target and its mass was measured. The residual masses measured for each test group were analyzed to provide ballistic performance rankings with associated confidence levels. When compared to traditional V50 methods, the residual mass (RM) method was found to require fewer test events and be more tolerant of variations in impact conditions.

  14. PROPERTIES OF RESIDUALS FOR SPATIAL POINT PROCESSES A. BADDELEY,

    E-Print Network [OSTI]

    Baddeley, Adrian

    PROPERTIES OF RESIDUALS FOR SPATIAL POINT PROCESSES A. BADDELEY, University of Western Australia J. MØLLER, University of Aalborg A.G. PAKES, University of Western Australia Abstract For any point process & Statistics M019, University of Western Australia, 35 Stirling Highway, Nedlands WA 6009, Australia Postal

  15. AIAA-2001-0025 SPECTRUM FATIGUE LIFETIME AND RESIDUAL STRENGTH

    E-Print Network [OSTI]

    on a typical fiberglass laminate configuration turbine blade fiberglass material has been undertaken under at various fractions of the lifetime turbine blade materials.. are consistent with the residual strength of fiberglass spectrum have been studied. Data have been obtained for materials produce results that may

  16. Prompt optical emission from residual collisions in GRB outflows

    E-Print Network [OSTI]

    Zhuo Li; Eli Waxman

    2008-01-03T23:59:59.000Z

    The prompt gamma-ray emission in gamma-ray bursts is believed to be produced by internal shocks within a relativistic unsteady outflow. The recent detection of prompt optical emission accompanying the prompt gamma-ray emission appears to be inconsistent with this model since the out flowing plasma is expected to be highly optically thick to optical photons. We show here that fluctuations in flow properties on short, ~ 1 ms, time scale, which drive the gamma-ray producing collisions at small radii, are expected to lead to "residual" collisions at much larger radii, where the optical depth to optical photons is low. The late residual collisions naturally account for the relatively bright optical emission. The apparent simultaneity of gamma-ray and optical emission is due to the highly relativistic speed with which the plasma expands. Residual collisions may also account for the X-ray emission during the early "steep decline" phase, where the radius is inferred to be larger than the gamma-ray emission radius. Finally, we point out that inverse-Compton emission from residual collisions at large radii is expected to contribute significantly to the emission at high energy, and may therefore "smear" the pair production spectral cut-off.

  17. RESIDUAL TYPE A POSTERIORI ERROR ESTIMATES FOR ELLIPTIC OBSTACLE PROBLEMS

    E-Print Network [OSTI]

    Nochetto, Ricardo H.

    to double obstacle problems are briefly discussed. Key words. a posteriori error estimates, residual Science Foundation under the grant No.19771080 and China National Key Project ``Large Scale Scientific\\Gamma satisfies / Ÿ 0 on @ and K is the convex set of admissible displacements K := fv 2 H 1 0(\\Omega\\Gamma : v

  18. Computer aided analysis for residual stress measurement using ultrasonic techniques

    E-Print Network [OSTI]

    Kypa, Jagan Mohan

    1999-01-01T23:59:59.000Z

    to detect travel-times with a precision of 0. l nanoseconds and an accuracy of less than 2.5 nanoseconds. A residual stress reference standard developed for previous research was used as the sample to measure travel-times. The sample was designed...

  19. COMMUNICATION Are Residues in a Protein Folding Nucleus

    E-Print Network [OSTI]

    Dai, Yang

    COMMUNICATION Are Residues in a Protein Folding Nucleus Evolutionarily Conserved? Yan Yuan Tseng is the hallmark of life. It is important to understand how protein folding and evolution influence each other in protein folding nucleus as measured by experi- mental f-value and selection pressure as measured by v

  20. A PROBABILISTIC FINITE ELEMENT ANALYSIS OF RESIDUAL STRESS FORMATION

    E-Print Network [OSTI]

    Grujicic, Mica

    A PROBABILISTIC FINITE ELEMENT ANALYSIS OF RESIDUAL STRESS FORMATION IN SHRINK-FIT CERAMIC shrink fitting of the jacket over the lining is studied using a probabilistic finite element analysis structural analysis approach, known as the Advanced Mean Value (AMV) method, is used which enables

  1. FIXED PRICE RESIDUAL FUNDS POLICY Policy dated March 29, 1999

    E-Print Network [OSTI]

    Weston, Ken

    FIXED PRICE RESIDUAL FUNDS POLICY Policy dated March 29, 1999 After completion of all deliverables required under a fixed-price award, after costs in fulfilling the requirements of the award have been of the University. The request will be approved if the project is consistent with broader University priorities

  2. Removal of residual particulate matter from filter media

    DOE Patents [OSTI]

    Almlie, Jay C; Miller, Stanley J

    2014-11-11T23:59:59.000Z

    A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

  3. Residual stresses in weld overlay tubes: A finite element study

    SciTech Connect (OSTI)

    Taljat, B.; Zacharia, T.; Wang, X.L.; Keiser, J.R. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.; Feng, Z. [Edison Welding Inst., Columbus, OH (United States); Jirinec, M.J. [Welding Services, Inc., Norcross, GA (United States)

    1997-01-03T23:59:59.000Z

    Residual stresses and strains in a tube with circumferential weld overlay were analyzed by the finite element (FE) method. The objective of this work was to develop and verify a FE model, to determine the magnitude and distribution of residual stresses in the weld overlay tube, and to evaluate the significance of two contributing factors to residual stress: (1) difference in material properties between tube and weld material, and (2) thermal gradients in the weld. An axisymmetric FE model was developed to simulate the circumferential two-layer welding process of alloy 625 overlay on SA210 tube. The first layer was modeled as a gas metal arc welding process with filler metal, whereas the autogenous gas tungsten arc welding process was modeled for the second layer. Neutron diffraction technique was used to experimentally determine residual elastic strains in the weld overlay tube. Comparison with the FE results shows overall good agreement. Both the experimental and FE results show high compressive stresses at the inside tube surface and high tensile stresses in the weld overlay. This suggests that weld overlay may be used to relieve tensile or produce compressive stresses at the inside tube surface, which is significant for applications where crack initiation is found at the root pass of the joining weld.

  4. Ammonia volatilization from soils with surface rice straw residue

    E-Print Network [OSTI]

    Barghassa, Peyam

    1995-01-01T23:59:59.000Z

    rice residue and related factors on NH3 volatilization from an acid Beaumont clay (pH 5.4) and an alkaline Lake Charles clay (pH 7.4). The treatments in the greenhouse and lab consisted of all possible combinations of the following variables: surface...

  5. Modeling, Optimization and Economic Evaluation of Residual Biomass Gasification

    E-Print Network [OSTI]

    Georgeson, Adam

    2012-02-14T23:59:59.000Z

    . .............................................................................. 7 Table 2. Components Used in Simulation. ...................................................................... 20 Table 3. Composition of Biomass Feedstock to Biorefinery. ......................................... 43 Table 4. Operating... for optimizing gasification plant design from an economic perspective. Specifically, the problem addressed in this work is stated as follows: Given are: ? A set of biomass feedstocks {i|i = 1,2,?,I } which includes fresh as well as residue biomass ? A set...

  6. New Techniques for the Construction of Residue Potentials for Protein

    E-Print Network [OSTI]

    Neumaier, Arnold

    New Techniques for the Construction of Residue Potentials for Protein Folding Arnold Neumaier­lattice protein folding studies. Our potential is a function of the amino acid labels and of the distances between­ rium geometries can determine the true effective potential energy function. Keywords. protein folding

  7. CARBON ENRICHMENT IN RESIDUAL AUSTENITE DURING MARTENSITIC TRANSFORMATION

    E-Print Network [OSTI]

    Cambridge, University of

    179 CARBON ENRICHMENT IN RESIDUAL AUSTENITE DURING MARTENSITIC TRANSFORMATION S. W. Ooi1 , Y. R, retained austenite, autotempering and low carbon steel. Abstract Carbon enrichment of austenite and carbide enrich with carbon [9-11] and there has been recent work to exploit this process in the design of `quench

  8. Sorption characteristics of polycyclic aromatic hydrocarbons in aluminum smelter residues

    SciTech Connect (OSTI)

    Gijs D. Breedveld; Emilien Pelletier; Richard St. Louis; Gerard Cornelissen [Norwegian Geotechnical Institute, Oslo (Norway)

    2007-04-01T23:59:59.000Z

    High temperature carbon oxidation in primary aluminum smelters results in the release of polycyclic aromatic hydrocarbons (PAH) into the environment. The main source of PAH are the anodes, which are composed of petroleum coke (black carbon, BC) and coal tar pitch. To elucidate the dominant carbonaceous phase controlling the environmental fate of PAH in aluminum smelter residues (coke BC and/or coal tar), the sorptive behavior of PAHs has been determined, using passive samplers and infinite-sink desorption methods. Samples directly from the wet scrubber were studied as well as ones from an adjacent 20-year old storage lagoon and roof dust from the smelter. Carbon-normalized distribution coefficients of native PAHs were 2 orders of magnitude higher than expected based on amorphous organic carbon (AOC)/water partitioning, which is in the same order of magnitude as reported literature values for soots and charcoals. Sorption isotherms of laboratory-spiked deuterated phenanthrene showed strong (about 100 times stronger than AOC) but nonetheless linear sorption in both fresh and aged aluminum smelter residues. The absence of nonlinear behavior typical for adsorption to BC indicates that PAH sorption in aluminum smelter residues is dominated by absorption into the semi-solid coal tar pitch matrix. Desorption experiments using Tenax showed that fresh smelter residues had a relatively large rapidly desorbing fraction of PAH (35-50%), whereas this fraction was strongly reduced (11-16%) in the lagoon and roof dust material. Weathering of the coal tar residue and/or redistribution of PAH between coal tar and BC phases could explain the reduced availability in aged samples. 38 refs., 5 figs., 1 tab.

  9. VLSI implementation of output convertors for ASIC architectures based on the residual number system: an overview

    E-Print Network [OSTI]

    Godbole, Rajesh

    1992-01-01T23:59:59.000Z

    , . For example, 5 bit residues occupy only 32 locations with a word length equal to [log sM] = 18. The key to this output conversion is a quotient-remainder representation for the summands s?such that 0 & s, & M. If a particular modulus m~ is singled out... Systems 5. Mixed Radix Systems 6. Properties of Weighted and Residual Number Systems B. Algebra of Residue Classes 1. Residue Representation 2. Example: Calculation of Integer Values k Residue Digits 3. Identities Involving Residues and Integer...

  10. Residual Stresses in 21-6-9 Stainless Steel Warm Forgings

    SciTech Connect (OSTI)

    Everhart, Wesley A.; Lee, Jordan D.; Broecker, Daniel J.; Bartow, John P.; McQueen, Jamie M.; Switzner, Nathan T.; Neidt, Tod M.; Sisneros, Thomas A.; Brown, Donald W.

    2012-11-14T23:59:59.000Z

    Forging residual stresses are detrimental to the production and performance of derived machined parts due to machining distortions, corrosion drivers and fatigue crack drivers. Residual strains in a 21-6-9 stainless steel warm High Energy Rate Forging (HERF) were measured via neutron diffraction. The finite element analysis (FEA) method was used to predict the residual stresses that occur during forging and water quenching. The experimentally measured residual strains were used to calibrate simulations of the three-dimensional residual stress state of the forging. ABAQUS simulation tools predicted residual strains that tend to match with experimental results when varying yield strength is considered.

  11. Theoretical thermodynamic analysis of a closed-cycle process for the conversion of heat into electrical energy by means of a distiller and an electrochemical cell

    E-Print Network [OSTI]

    Carati, Andrea; Brogioli, Doriano

    2013-01-01T23:59:59.000Z

    We analyse a device aimed at the conversion of heat into electrical energy, based on a closed cycle in which a distiller generates two solutions at different concentrations, and an electrochemical cell consumes the concentration difference, converting it into electrical current. We first study an ideal model of such a process. We show that, if the device works at a single fixed pressure (i.e. with a "single effect"), then the efficiency of the conversion of heat into electrical power has an upper bound, given by the efficiency of a reversible Carnot engine operating between the boiling temperatures of the concentrated solution and of the pure solvent. When two heat reservoirs with a higher temperature difference are available, the overall efficiency can be incremented by employing an arrangement of multiple cells working at different pressures ("multiple effects"). We find that a given efficiency can be achieved with a reduced number of effects by using solutions with a high boiling point elevation.

  12. Residual stresses in dielectrics caused by metallization lines and pads

    SciTech Connect (OSTI)

    He, M.Y.; Lipkin, J.; Clarke, D.R. [Univ. of California, Santa Barbara, CA (United States). Materials Dept.] [Univ. of California, Santa Barbara, CA (United States). Materials Dept.; Evans, A.G. [Harvard Univ., Cambridge, MA (United States). Div. of Applied Sciences] [Harvard Univ., Cambridge, MA (United States). Div. of Applied Sciences; Tenhover, M. [Carborundum Co., Niagara Falls, NY (United States)] [Carborundum Co., Niagara Falls, NY (United States)

    1996-06-01T23:59:59.000Z

    Residual stresses in dielectrics and semiconductors induced by metal lines, pads and vias can have detrimental effects on the performance of devices and electronic packages. Analytical and numerical calculations of these stresses have been performed for two purposes. (1) To illustrate how these stresses relate to the residual stress in the metallization and its geometry; (2) to calibrate a piezo-spectroscopic method for measuring these stresses with high spatial resolution. The results of the calculations have been presented using non-dimensional parameters that both facilitate scaling and provide connections to the stresses in the metal, with or without yielding. Preliminary experimental results obtained for Au/Ge eutectic pads illustrate the potential of the method and the role of the stress analysis.

  13. Classification of lepton mixing matrices from finite residual symmetries

    E-Print Network [OSTI]

    Renato M. Fonseca; Walter Grimus

    2014-08-19T23:59:59.000Z

    Assuming that neutrinos are Majorana particles, we perform a complete classification of all possible mixing matrices which are fully determined by residual symmetries in the charged-lepton and neutrino mass matrices. The classification is based on the assumption that the residual symmetries originate from a finite flavour symmetry group. The mathematical tools which allow us to accomplish this classification are theorems on sums of roots of unity. We find 17 sporadic cases plus one infinite series of mixing matrices associated with three-flavour mixing, all of which have already been discussed in the literature. Only the infinite series contains mixing matrices which are compatible with the data at the 3 sigma level.

  14. THE METHOD OF CONJUGATE RESIDUALS FOR SOLVING THE GALERKIN EQUATIONS ASSOCIATED WITH SYMMETRIC

    E-Print Network [OSTI]

    Plato, Robert

    kind integral equations, conjugate gradient type methods, Galerkin method, regularization schemesTHE METHOD OF CONJUGATE RESIDUALS FOR SOLVING THE GALERKIN EQUATIONS ASSOCIATED WITH SYMMETRIC, the method of conjugate residuals is consid- ered. An a posteriori stopping rule is introduced

  15. Making Photosynthetic Biofuel Renewable: Recovering Phosphorus from Residual Biomass J. M. Gifford and P. Westerhoff

    E-Print Network [OSTI]

    Hall, Sharon J.

    Making Photosynthetic Biofuel Renewable: Recovering Phosphorus from Residual Biomass J. M. Gifford to global warming. Biofuel from phototrophic microbes like algae and bacteria provides a viable substitute improves biofuel sustainability by refining phosphorus recycling. Biomass Production Residual Biomass

  16. The Dissolution of Desicooler Residues in H-Canyon Dissolvers

    SciTech Connect (OSTI)

    Gray, J.H.

    2003-06-23T23:59:59.000Z

    A series of dissolution and characterization studies has been performed to determine if FB-Line residues stored in desicooler containers will dissolve using a modified H-Canyon processing flowsheet. Samples of desicooler materials were used to evaluate dissolving characteristics in the low-molar nitric acid solutions used in H-Canyon dissolvers. The selection for the H-Canyon dissolution of desicooler residues was based on their high-enriched uranium content and trace levels of plutonium. Test results showed that almost all of the enriched uranium will dissolve from the desicooler materials after extended boiling in one molar nitric acid solutions. The residue that contained uranium after completion of the extended boiling cycle consisted of brown solids that had agglomerated into large pieces and were floating on top of the dissolver solution. Addition of tenth molar fluoride to a three molar nitric acid solution containing boron did not dissolve remaining uranium from the brown solids. Only after boiling in an eight molar nitric acid-tenth molar fluoride solution without boron did remaining uranium and aluminum dissolve from the brown solids. The amount of uranium associated with brown solids would be approximately 1.4 percent of the total uranium content of the desicooler materials. The brown solids that remain in the First Uranium Cycle feed will accumulate at the organic/aqueous interface during solvent extraction operations. Most of the undissolved white residue that remained after extended boiling was aluminum oxide containing additional trace quantities of impurities. However, the presence of mercury used in H-Canyon dissolvers should complete the dissolution of these aluminum compounds.

  17. Type Ia supernova Hubble residuals and host-galaxy properties

    SciTech Connect (OSTI)

    Kim, A. G.; Aldering, G.; Aragon, C.; Bailey, S.; Fakhouri, H. K. [Physics Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Antilogus, P.; Bongard, S.; Canto, A.; Cellier-Holzem, F.; Fleury, M.; Guy, J. [Laboratoire de Physique Nucléaire et des Hautes Énergies, Université Pierre et Marie Curie Paris 6, Université Paris Diderot Paris 7, CNRS-IN2P3, 4 place Jussieu, F-75252 Paris Cedex 05 (France); Baltay, C. [Department of Physics, Yale University, New Haven, CT 06250-8121 (United States); Buton, C.; Feindt, U.; Greskovic, P.; Kowalski, M. [Physikalisches Institut, Universität Bonn, Nußallee 12, D-53115 Bonn (Germany); Childress, M. [Research School of Astronomy and Astrophysics, Australian National University, Canberra, ACT 2611 (Australia); Chotard, N.; Copin, Y.; Gangler, E. [Université de Lyon, F-69622 Lyon (France); Université de Lyon 1, Villeurbanne (France); CNRS/IN2P3, Institut de Physique Nucléaire de Lyon (France); and others

    2014-03-20T23:59:59.000Z

    Kim et al. introduced a new methodology for determining peak-brightness absolute magnitudes of type Ia supernovae from multi-band light curves. We examine the relation between their parameterization of light curves and Hubble residuals, based on photometry synthesized from the Nearby Supernova Factory spectrophotometric time series, with global host-galaxy properties. The K13 Hubble residual step with host mass is 0.013 ± 0.031 mag for a supernova subsample with data coverage corresponding to the K13 training; at <<1?, the step is not significant and lower than previous measurements. Relaxing the data coverage requirement of the Hubble residual step with the host mass is 0.045 ± 0.026 mag for the larger sample; a calculation using the modes of the distributions, less sensitive to outliers, yields a step of 0.019 mag. The analysis of this article uses K13 inferred luminosities, as distinguished from previous works that use magnitude corrections as a function of SALT2 color and stretch parameters: steps at >2? significance are found in SALT2 Hubble residuals in samples split by the values of their K13 x(1) and x(2) light-curve parameters. x(1) affects the light-curve width and color around peak (similar to the ?m {sub 15} and stretch parameters), and x(2) affects colors, the near-UV light-curve width, and the light-curve decline 20-30 days after peak brightness. The novel light-curve analysis, increased parameter set, and magnitude corrections of K13 may be capturing features of SN Ia diversity arising from progenitor stellar evolution.

  18. Ultrasonic detection of residual stress in a turbine disk 

    E-Print Network [OSTI]

    Pathak, Nitin

    1992-01-01T23:59:59.000Z

    in temperature and stresses during welding. Adapted from [4] . . Cracked steam turbine rotor disk segments. Adapted from [6] . . . . 5 Electrical block diagram of Barkhausen apparatus. Adapted from [11] 10 Snell's Law. 15 Stress field and speeds of plane... International B. Effects in Engineering Design Residual stresses may be introduced into materials in a variety of ways, e. g. , in manu- facturing and repairing processes such as casting, machining, or welding. The casting process has a high probability...

  19. The effect of magnetic flutter on residual flow

    SciTech Connect (OSTI)

    Terry, P. W.; Pueschel, M. J.; Carmody, D. [Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States)] [Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States); Nevins, W. M. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)] [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)

    2013-11-15T23:59:59.000Z

    The hypothesis that stochastic magnetic fields disrupt zonal flows associated with ion temperature gradient turbulence saturation is investigated analytically with a residual flow calculation in the presence of magnetic flutter. The calculation starts from the time-asymptotic zero-beta residual flow of Rosenbluth and Hinton [Phys. Rev. Lett. 80, 724 (1998)] with the sudden application of an externally imposed, fixed magnetic field perturbation. The short-time electron response from radial charge loss due to magnetic flutter is calculated from the appropriate gyrokinetic equation. The potential evolution has quadratic behavior, with a zero crossing at finite time. The crossing time and its parametric dependencies are compared with numerical results from a gyrokinetic simulation of residual flow in the presence of magnetic flutter. The numerical and analytical results are in good agreement and support the hypothesis that the high-beta runaway of numerical simulations is a result of the disabling of zonal flows by finite-beta charge losses associated with magnetic flutter.

  20. Residuals in steel products -- Impacts on properties and measures to minimize them

    SciTech Connect (OSTI)

    Emi, Toshihiko [Tohoku Univ., Sendai (Japan). Inst. for Advanced Materials Processing; Wijk, O. [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Process Metallurgy

    1996-12-31T23:59:59.000Z

    The effect of major residual elements on the properties of steel products is summarized. Measures to minimize these elements are discussed including the pretreatment of raw materials, innovative refining processes and environmental issues. This paper addresses (1) scrap situation, (2) upper limit of residual concentrations acceptable for processing and product quality, (3) possible means to reduce the residuals, and (4) consideration on the practicable measures to solve the residuals problem in a systematic way. 52 refs.