Sample records for lpg distillate residual

  1. Hydroconversion of heavy oils. [Residue of tar sand bitumen distillation

    SciTech Connect (OSTI)

    Garg, D.

    1986-08-19T23:59:59.000Z

    A method is described for hydroconversion of feedstocks consisting essentially of at least one heavy hydrocarbon oil selected from the group consisting of residue of petroleum oil distillation and the residue of tar sand bitumen distillation to enhance the recovery of 350/sup 0/-650/sup 0/F boiling product fraction. The method comprises treating such feed stock with hydrogen at superatmospheric pressure and in the presence of finely divided active hydrogenation catalyst in consecutive reaction stages. An initial reaction stage is carried out at a temperature in the range of 780/sup 0/-825/sup 0/F, and a subsequent reaction stage is directly carried out after the initial reaction stage at a higher temperature in the range of 800/sup 0/F-860/sup 0/F, the temperature of the subsequent reaction stage being at least 20/sup 0/F higher than that of the initial reaction stage.

  2. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Gasoline and Diesel Fuel Update (EIA)

    A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2...

  3. Table A3. Refiner/Reseller Prices of Distillate and Residual...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1999 441 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) - Continued...

  4. "Table A10. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ <Information Administration (EIA) 103. Relative Standard Errors for Table N8.3;"0. Total

  5. "Table A2. Total Consumption of LPG, Distillate Fuel Oil, and Residual Fuel"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ <Information Administration (EIA) 103. Relative Standard Errors for Table N8.3;"0. Total1.6.7..

  6. Advancing Biorefining of Distillers Grain and Corn Stover Blends

    Broader source: Energy.gov (indexed) [DOE]

    pretreatment process for distiller's grains and corn stover to convert residual starch, cellulose, and hemicellulose to ethanol and high- converting residual starch in order to...

  7. Africa gaining importance in world LPG trade

    SciTech Connect (OSTI)

    Haun, R.R. [Purvin and Gertz Inc., Dallas, TX (United States); Otto, K.W.; Whitley, S.C. [Purvin and Gertz Inc., Houston, TX (United States)

    1997-05-12T23:59:59.000Z

    Major LPG projects planned or under way in Africa will increase the importance of that region`s presence in world LPG trade. Supplies will nearly double between 1995 and 2005, at which time they will remain steady for at least 10 years. At the same time that exports are leveling, however, increasing domestic demand for PG is likely to reduce export-market participation by Algeria, Nigeria, Egypt, and Libya. The growth of Africa`s participation in world LPG supply is reflected in comparisons for the next 15--20 years. Total world supply of LPG in 1995 was about 165 million metric tons (tonnes), of which Africans share was 7.8 million tonnes. By 2000, world supply will grow to slightly more than 200 million tonnes, with Africa`s share expected to increase to 13.2 million tonnes (6.6%). And by 2005, world LPG supply will reach nearly 230 million tonnes; Africa`s overall supply volumes by that year will be nearly 16.2 million tonnes (7%). World LPG supply for export in 1995 was on order of 44 million tonnes with Africa supply about 4 million tonnes (9%). By 2005, world export volumes of LPG will reach nearly 70 million tonnes; Africa`s share will have grown by nearly 10 million tonnes (14.3%).

  8. Catalytic Distillation

    E-Print Network [OSTI]

    Smith, L. A., Jr.; Hearn, D.; Wynegar, D. P.

    1984-01-01T23:59:59.000Z

    removing both will occur in the temperature range ne~ded high and low boilers to maintain the tower for reaction. One limitation may be .I the composition profile, exothermic reactions critical point of the system, above w~ich can be easily temperature... with significantly less energy. There are two primary reasons for energy reduction: 1. The heat of reaction for exothermic reactions is fully re covered as useful boilup for fractionation. 2. Fewer attendant distillations are normally required than for a...

  9. LPG Electrical, Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429 ThrottledInformationparticipants < LEDSGP‎Hoying, LLC Jump to:LPG

  10. 2000-32 V'B SAFETY PROVISIONS AND LPG

    E-Print Network [OSTI]

    Boyer, Edmond

    on a single site). Four operators account for 54 of these sites ; chemical firms and refineries operate 15 Author manuscript, published in "15. Hazards Symposium "The Process its Safety and the Environment UTILISING LPG The French sites utilising LPG can be subdivided into 7 main categories : · Refineries

  11. INNOVATION EDUCATION EXCELLENCE DISTILLATIONS

    E-Print Network [OSTI]

    Chan, Hue Sun

    INNOVATION · EDUCATION · EXCELLENCE DISTILLATIONS University of Toronto CHEMISTRY ALUMNI MAGAZINE.utoronto.ca / distillations 2012 MessagefromtheChair Our Department of Chemistry has one of the finest collection of peo- ple to a better, more sustain- able future. This issue of Distillations highlights the accomplishments last year

  12. Assessment of research and development (R and D) needs in LPG safety and environmental control

    SciTech Connect (OSTI)

    DeSteese, J.G.

    1982-05-01T23:59:59.000Z

    The report characterizes the LPG industry covering all operations from production to end use, reviews current knowledge of LPG release phenomenology, summarizes the status of current LPG release prevention and control methodology, and identifies any remaining safety and environmental problems and recommends R and D strategies that may mitigate these problems. (ACR)

  13. Numerical Simulations of Leakage from Underground LPG Storage Caverns

    SciTech Connect (OSTI)

    Yamamoto, Hajime; Pruess, Karsten

    2004-09-01T23:59:59.000Z

    To secure a stable supply of petroleum gas, underground storage caverns for liquified petroleum gas (LPG) are commonly used in many countries worldwide. Storing LPG in underground caverns requires that the surrounding rock mass remain saturated with groundwater and that the water pressure be higher than the liquid pressure inside the cavern. In previous studies, gas containment criteria for underground gas storage based on hydraulic gradient and pressure have been discussed, but these studies do not consider the physicochemical characteristics and behavior of LPG such as vaporization and dissolution in groundwater. Therefore, while these studies are very useful for designing storage caverns, they do not provide better understanding of the either the environmental effects of gas contamination or the behavior of vaporized LPG. In this study, we have performed three-phase fluid flow simulations of gas leakage from underground LPG storage caverns, using the multiphase multicomponent nonisothermal simulator TMVOC (Pruess and Battistelli, 2002), which is capable of solving the three-phase nonisothermal flow of water, gas, and a multicomponent mixture of volatile organic chemicals (VOCs) in multidimensional heterogeneous porous media. A two-dimensional cross-sectional model resembling an actual underground LPG facility in Japan was developed, and gas leakage phenomena were simulated for three different permeability models: (1) a homogeneous model, (2) a single-fault model, and (3) a heterogeneous model. In addition, the behavior of stored LPG was studied for the special case of a water curtain suddenly losing its function because of operational problems, or because of long-term effects such as clogging of boreholes. The results of the study indicate the following: (1) The water curtain system is a very powerful means for preventing gas leakage from underground storage facilities. By operating with appropriate pressure and layout, gas containment can be ensured. (2) However , in highly heterogeneous media such as fractured rock and fault zones, local flow paths within which the gas containment criterion is not satisfied could be formed. To eliminate such zones, treatments such as pre/post grouting or an additional installment of water-curtain boreholes are essential. (3) Along highly conductive features such as faults, even partially saturated zones possess certain effects that can retard or prevent gas leakage, while a fully unsaturated fault connected to the storage cavern can quickly cause a gas blowout. This possibility strongly suggests that ensuring water saturation of the rock surrounding the cavern is a very important requirement. (4) Even if an accident should suddenly impair the water curtain, the gas plume does not quickly penetrate the ground surface. In these simulations, the plume takes several months to reach the ground surface.

  14. Advanced Distillation Final Report

    SciTech Connect (OSTI)

    Maddalena Fanelli; Ravi Arora; Annalee Tonkovich; Jennifer Marco; Ed Rode

    2010-03-24T23:59:59.000Z

    The Advanced Distillation project was concluded on December 31, 2009. This U.S. Department of Energy (DOE) funded project was completed successfully and within budget during a timeline approved by DOE project managers, which included a one year extension to the initial ending date. The subject technology, Microchannel Process Technology (MPT) distillation, was expected to provide both capital and operating cost savings compared to conventional distillation technology. With efforts from Velocys and its project partners, MPT distillation was successfully demonstrated at a laboratory scale and its energy savings potential was calculated. While many objectives established at the beginning of the project were met, the project was only partially successful. At the conclusion, it appears that MPT distillation is not a good fit for the targeted separation of ethane and ethylene in large-scale ethylene production facilities, as greater advantages were seen for smaller scale distillations. Early in the project, work involved flowsheet analyses to discern the economic viability of ethane-ethylene MPT distillation and develop strategies for maximizing its impact on the economics of the process. This study confirmed that through modification to standard operating processes, MPT can enable net energy savings in excess of 20%. This advantage was used by ABB Lumus to determine the potential impact of MPT distillation on the ethane-ethylene market. The study indicated that a substantial market exists if the energy saving could be realized and if installed capital cost of MPT distillation was on par or less than conventional technology. Unfortunately, it was determined that the large number of MPT distillation units needed to perform ethane-ethylene separation for world-scale ethylene facilities, makes the targeted separation a poor fit for the technology in this application at the current state of manufacturing costs. Over the course of the project, distillation experiments were performed with the targeted mixture, ethane-ethylene, as well as with analogous low relative volatility systems: cyclohexane-hexane and cyclopentane-pentane. Devices and test stands were specifically designed for these efforts. Development progressed from experiments and models considering sections of a full scale device to the design, fabrication, and operation of a single-channel distillation unit with integrated heat transfer. Throughout the project, analytical and numerical models and Computational Fluid Dynamics (CFD) simulations were validated with experiments in the process of developing this platform technology. Experimental trials demonstrated steady and controllable distillation for a variety of process conditions. Values of Height-to-an-Equivalent Theoretical Plate (HETP) ranging from less than 0.5 inch to a few inches were experimentally proven, demonstrating a ten-fold performance enhancement relative to conventional distillation. This improvement, while substantial, is not sufficient for MPT distillation to displace very large scale distillation trains. Fortunately, parallel efforts in the area of business development have yielded other applications for MPT distillation, including smaller scale separations that benefit from the flowsheet flexibility offered by the technology. Talks with multiple potential partners are underway. Their outcome will also help determine the path ahead for MPT distillation.

  15. Carbon footprints of heating oil and LPG heating systems

    SciTech Connect (OSTI)

    Johnson, Eric P., E-mail: ejohnson@ecosite.co.uk

    2012-07-15T23:59:59.000Z

    For European homes without access to the natural gas grid, the main fuels-of-choice for heating are heating oil and LPG. How do the carbon footprints of these compare? Existing literature does not clearly answer this, so the current study was undertaken to fill this gap. Footprints were estimated in seven countries that are representative of the EU and constitute two-thirds of the EU-27 population: Belgium, France, Germany, Ireland, Italy, Poland and the UK. Novelties of the assessment were: systems were defined using the EcoBoiler model; well-to-tank data were updated according to most-recent research; and combustion emission factors were used that were derived from a survey conducted for this study. The key finding is that new residential heating systems fuelled by LPG are 20% lower carbon and 15% lower overall-environmental-impact than those fuelled by heating oil. An unexpected finding was that an LPG system's environmental impact is about the same as that of a bio heating oil system fuelled by 100% rapeseed methyl ester, Europe's predominant biofuel. Moreover, a 20/80 blend (by energy content) with conventional heating oil, a bio-heating-oil system generates a footprint about 15% higher than an LPG system's. The final finding is that fuel switching can pay off in carbon terms. If a new LPG heating system replaces an ageing oil-fired one for the final five years of its service life, the carbon footprint of the system's final five years is reduced by more than 50%.

  16. Distillation: The Efficient Workhorse

    E-Print Network [OSTI]

    Steinmeyer, D.

    DISTILLATION: THE EFFICIENT WORKHORSE Dan Steinmeyer Monsanto Company St. Louis, Missouri Distillation is inherently highly efficient: phase separation is clean it is relatively easy to build a mUltistage countercurrent device equilibrium... of separation to the work pmbedded in the reboiler and condenser thermal flows. The right application is one where the streams ? separated both exceed la' of the feed, relative volatility exceeds 1.2, and separation is complete - i.e. pure products...

  17. Energy efficient distillation apparatus

    SciTech Connect (OSTI)

    Melton, J.D.

    1982-08-17T23:59:59.000Z

    An energy efficient distillation method is provided which is particularly adapted for use on a dairy farm, and which comprises a distilland evaporating receptacle, a distillate condensing receptacle, and a conduit interconnecting the evaporating receptacle and the condensing receptacle. A vacuum pump is provided for drawing a partial vacuum within the evaporating receptacle, and a vapor compression refrigeration system is provided which includes condenser coils disposed to heat and vaporize the distilland while it is within the evaporating receptacle, and evaporator coils for cooling and condensing the vaporized distilland in the condensing receptacle. A cooling distribution system is also provided whereby a variable portion of the cooling potential of the refrigeration system may be selectively directed to each of the condensing receptacle, a distillate receiver tank, or to a bulk milk container as utilized on a dairy farm or the like.

  18. Fuel switching from wood to LPG can benefit the environment

    SciTech Connect (OSTI)

    Nautiyal, Sunil [Leibniz-Centre for Agricultural Landscape Research (ZALF), Institute of Socioeconomics, Eberswalder Str. 84, 15374 Muencheberg (Germany)], E-mail: sunil.nautiyal@zalf.de; Kaechele, Harald [Leibniz-Centre for Agricultural Landscape Research (ZALF), Institute of Socioeconomics, Eberswalder Str. 84, 15374 Muencheberg (Germany)

    2008-11-15T23:59:59.000Z

    The Himalaya in India is one of the world's biodiversity hotspots. Various scientific studies have reported and proven that many factors are responsible for the tremendous decline of the Himalayan forests. Extraction of wood biomass from the forests for fuel is one of the factors, as rural households rely entirely on this for their domestic energy. Efforts continue for both conservation and development of the Himalayan forests and landscape. It has been reported that people are still looking for more viable solutions that could help them to improve their lifestyle as well as facilitate ecosystem conservation and preservation of existing biodiversity. In this direction, we have documented the potential of the introduction of liquefied petroleum gas (LPG), which is one of the solutions that have been offered to the local people as a substitute for woodfuel to help meet their domestic energy demand. The results of the current study found dramatic change in per capita woodfuel consumption in the last two decades in the villages where people are using LPG. The outcome showed that woodfuel consumption had been about 475 kg per capita per year in the region, but after introduction of LPG, this was reduced to 285 kg per capita per year in 1990-1995, and was further reduced to 46 kg per capita per year in 2000-2005. Besides improving the living conditions of the local people, this transformation has had great environmental consequences. Empirical evidence shows that this new paradigm shift is having positive external effects on the surrounding forests. Consequently, we have observed a high density of tree saplings and seedlings in adjacent forests, which serves as an assessment indicator of forest health. With the help of the current study, we propose that when thinking about a top-down approach to conservation, better solutions, which are often ignored, should be offered to local people.

  19. Reflux for multifeed distillation

    SciTech Connect (OSTI)

    Chou, S.M.; Yaws, C.L.

    1986-12-01T23:59:59.000Z

    Prior investigations have shown ways to determine minimum reflux for multicomponent distillation. This work extends earlier concepts in order to handle multifeeds. Reflux calculations for each feed, as though it were the only feed, are factored with the reflux effects of the other feeds to give an overall minimum reflux. Each factor has a finite value depending on the composition and thermal quality of the feed it represents.

  20. Low Energy Distillation Schemes

    E-Print Network [OSTI]

    Polley, G. T.

    an important means of reducing energy consumption in distillation processes. However, its conventional use requires the installation of piping (and pipes carrying vapour streams tend to be of large diameter and are consequently expensive). So, finally we.... However, its conventional use requires the installation of piping (and pipes carrying vapour streams tend to be of large diameter and are consequently expensive). In the late eighties engineers in Germany [e.g. Kaibel, 1987] looked at one way in which...

  1. Evaluation of aftermarket LPG conversion kits in light-duty vehicle applications. Final report

    SciTech Connect (OSTI)

    Bass, E.A. [Southwest Research Inst., San Antonio, TX (US)] [Southwest Research Inst., San Antonio, TX (US)

    1993-06-01T23:59:59.000Z

    SwRI was contracted by NREL to evaluate three LPG conversion kits on a Chevrolet Lumina. The objective of the project was to measure the Federal Test Procedure (FTP) emissions and fuel economy of these kits, and compare their performance to gasoline-fueled operation and to each other. Varying LPG fuel blends allowed a preliminary look at the potential for fuel system disturbance. The project required kit installation and adjustment according to manufacturer`s instructions. A limited amount of trouble diagnosis was also performed on the fuel systems. A simultaneous contract from the Texas Railroad Commission, in cooperation with NREL, provided funds for additional testing with market fuels (HD5 propane and industry average gasoline) and hydrocarbon (HC) emissions speciation to determine the ozone-forming potential of LPG HC emissions. This report documents the procurement, installation, and testing of these LPG conversion kits.

  2. New Design Methods And Algorithms For High Energy-Efficient And Low-cost Distillation Processes

    SciTech Connect (OSTI)

    Agrawal, Rakesh

    2013-11-21T23:59:59.000Z

    This project sought and successfully answered two big challenges facing the creation of low-energy, cost-effective, zeotropic multi-component distillation processes: first, identification of an efficient search space that includes all the useful distillation configurations and no undesired configurations; second, development of an algorithm to search the space efficiently and generate an array of low-energy options for industrial multi-component mixtures. Such mixtures are found in large-scale chemical and petroleum plants. Commercialization of our results was addressed by building a user interface allowing practical application of our methods for industrial problems by anyone with basic knowledge of distillation for a given problem. We also provided our algorithm to a major U.S. Chemical Company for use by the practitioners. The successful execution of this program has provided methods and algorithms at the disposal of process engineers to readily generate low-energy solutions for a large class of multicomponent distillation problems in a typical chemical and petrochemical plant. In a petrochemical complex, the distillation trains within crude oil processing, hydrotreating units containing alkylation, isomerization, reformer, LPG (liquefied petroleum gas) and NGL (natural gas liquids) processing units can benefit from our results. Effluents from naphtha crackers and ethane-propane crackers typically contain mixtures of methane, ethylene, ethane, propylene, propane, butane and heavier hydrocarbons. We have shown that our systematic search method with a more complete search space, along with the optimization algorithm, has a potential to yield low-energy distillation configurations for all such applications with energy savings up to 50%.

  3. Oil recovery from condensed corn distillers solubles.

    E-Print Network [OSTI]

    Majoni, Sandra

    2009-01-01T23:59:59.000Z

    ??Condensed corn distillers solubles (CCDS) contains more oil than dried distillers grains with solubles (DDGS), 20 vs. 12% (dry weight basis). Therefore, significant amount of… (more)

  4. An analysis of weep holes as a product detection device for underground compensated LPG storage systems

    SciTech Connect (OSTI)

    Sarica, C.; Demir, H.M.; Brill, J.P.

    1996-09-01T23:59:59.000Z

    Weep holes have been used widely to detect the presence of Liquefied Petroleum Gases (LPG) in brine for underground compensated storage systems. When the brine level drops below the weep hole, LPG product enters the brine production system causing an increase in both tubing head pressure and flow rate. To prevent cavern overfill, a cavern shutdown is initiated upon detection of LPG in the surface brine system by pressure or flow instruments at the tubing head. In this study, we have investigated the multiphase flow characteristics of weep hole LPG detection systems to correctly estimate the operating limits. A simple and easy to use model has been developed to predict the tubing head pressure and flow rate increases. The model can be used to implement safer and more efficient operation procedures for underground compensated LPG storage systems. The model predictions for a typical field case are presented. An analysis of weep holes as product detection devices for LPG storage reservoirs has been carried out. It was found that the increases in pressure and flow rates at the tubing head change as a function of injection flow rate of the product. Therefore, a thorough consideration of cavern operating parameters is necessary to evaluate the use constant pressure and flow rate values to initiate emergency shut down of the cavern.

  5. Optimal Control of Distillation Systems

    E-Print Network [OSTI]

    Chatterjee, N.; Suchdeo, S. R.

    1984-01-01T23:59:59.000Z

    The optimum performance of a distillation system can be evaluated by examining the product purities, the product recoveries, and the system's capability to respond to small or large, expected or unexpected, plant disturbances. An optimal control...

  6. SRC Residual fuel oils

    DOE Patents [OSTI]

    Tewari, Krishna C. (Whitehall, PA); Foster, Edward P. (Macungie, PA)

    1985-01-01T23:59:59.000Z

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  7. Fractionation studies on the unidentified growth factor(s) in distillers dried solubles

    E-Print Network [OSTI]

    Dannenburg, Warren Nathaniel

    1955-01-01T23:59:59.000Z

    . This was called "methyl aloohol soluble fraction of distillers dried solublesi The residue wss air drie4 and labeled "aetna 1 alcohol insoluble fraotion of distillers drie4 solubles". $. r fo m at nt ist e i o ubl s Five hundred gm of distillexs dried... fraction ox Ms- tillers Cried solubles (pH 1)"L "water soluole fr~ction of distillers dried solubles (PH '/)"L ~ "water soluble fxaction of dis~illers dried solubles (pH 11)". ur h r Pra tionatio f th Sate 8 lub e }raut of 9 still rs ed Soluo es a...

  8. Distilling entanglement from arbitrary resources

    E-Print Network [OSTI]

    Francesco Buscemi; Nilanjana Datta

    2010-10-15T23:59:59.000Z

    We obtain the general formula for the optimal rate at which singlets can be distilled from any given noisy and arbitrarily correlated entanglement resource, by means of local operations and classical communication (LOCC). Our formula, obtained by employing the quantum information spectrum method, reduces to that derived by Devetak and Winter, in the special case of an i.i.d. resource. The proofs rely on a one-shot version of the so-called "hashing bound," which in turn provides bounds on the one-shot distillable entanglement under general LOCC.

  9. Corrosion inhibition for distillation apparatus

    DOE Patents [OSTI]

    Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY); Schweighardt, Frank K. (Upper Macungie, PA)

    1985-01-01T23:59:59.000Z

    Tower material corrosion in an atmospheric or sub-atmospheric distillation tower in a coal liquefaction process is reduced or eliminated by subjecting chloride-containing tray contents to an appropriate ion-exchange resin to remove chloride from such tray contents materials.

  10. Optimal distillation using thermodynamic geometry Bjarne Andresen

    E-Print Network [OSTI]

    Salamon, Peter

    (temperature, pressure, etc.) define successive states in a sequence of equilibria. Fractional distillation [2Optimal distillation using thermodynamic geometry Bjarne Andresen Ørsted Laboratory, University of a distillation column may be improved by permitting heat exchange on every tray rather than only in the reboiler

  11. Momentive Performance Materials Distillation Intercharger

    E-Print Network [OSTI]

    Boucher, N.; Baisley, T.; Beers, C.; Cameron, R.; Holman, K.; Kotkoskie, T.; Norris, K.

    2013-01-01T23:59:59.000Z

    Presenter: Nicki (Collins) Boucher Project Team: T. Baisley, C. Beers, R. Cameron, K. Holman, T. Kotkoskie, K. Norris Momentive Performance Materials Inc. Waterford, NY May 23, 2013 Industrial Energy Technology Conference ACC Responsible... Care? Energy Efficiency Program Momentive Performance Materials Distillation Interchanger ESL-IE-13-05-20 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New Orleans, LA. May 21-24, 2013 Copyright 2013 Momentive Performance...

  12. LIQUID PROPANE GAS (LPG) STORAGE AREA BOILING LIQUID EXPANDING VAPOR EXPLOSION (BLEVE) ANALYSIS

    SciTech Connect (OSTI)

    PACE, M.E.

    2004-01-13T23:59:59.000Z

    The PHA and the FHAs for the SWOC MDSA (HNF-14741) identified multiple accident scenarios in which vehicles powered by flammable gases (e.g., propane), or combustible or flammable liquids (e.g., gasoline, LPG) are involved in accidents that result in an unconfined vapor cloud explosion (UVCE) or in a boiling liquid expanding vapor explosion (BLEVE), respectively. These accident scenarios are binned in the Bridge document as FIR-9 scenarios. They are postulated to occur in any of the MDSA facilities. The LPG storage area will be in the southeast corner of CWC that is relatively remote from store distaged MAR. The location is approximately 30 feet south of MO-289 and 250 feet east of 2401-W by CWC Gate 10 in a large staging area for unused pallets and equipment.

  13. Converting LPG caverns to natural-gas storage permits fast response to market

    SciTech Connect (OSTI)

    Crossley, N.G. [TransGas Ltd., Regina, Saskatchewan (Canada)

    1996-02-19T23:59:59.000Z

    Deregulation of Canada`s natural-gas industry in the late 1980s led to a very competitive North American natural-gas storage market. TransGas Ltd., Regina, Sask., began looking for method for developing cost-effective storage while at the same time responding to new market-development opportunities and incentives. Conversion of existing LPG-storage salt caverns to natural-gas storage is one method of providing new storage. To supply SaskEnergy Inc., the province`s local distribution company, and Saskatchewan customers, TransGas previously had developed solution-mined salt storage caverns from start to finish. Two Regina North case histories illustrate TransGas` experiences with conversion of LPG salt caverns to gas storage. This paper provides the testing procedures for the various caverns, cross-sectional diagrams of each cavern, and outlines for cavern conversion. It also lists storage capacities of these caverns.

  14. Rank three bipartite entangled states are distillable

    E-Print Network [OSTI]

    Lin Chen; Yi-Xin Chen

    2008-03-07T23:59:59.000Z

    We prove that the bipartite entangled state of rank three is distillable. So there is no rank three bipartite bound entangled state. By using this fact, We present some families of rank four states that are distillable. We also analyze the relation between the low rank state and the Werner state.

  15. Locally Accessible Information and Distillation of Entanglement

    E-Print Network [OSTI]

    Sibasish Ghosh; Pramod Joag; Guruprasad Kar; Samir Kunkri; Anirban Roy

    2004-03-18T23:59:59.000Z

    A new type of complementary relation is found between locally accessible information and final average entanglement for given ensemble. It is also shown that in some well known distillation protocol, this complementary relation is optimally satisfied. We discuss the interesting trade-off between locally accessible information and distillable entanglement for some states.

  16. Forpeerreview Synthesis of Complex Thermally Coupled Distillation

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    US energy consumption, which is equivalent to 2.87x10 18 J (2.87 million TJ) per year, or to a power; Divided Wall Column; Superstructure optimization; GDP. Introduction Distillation is one of the most limitations. Distillation columns use very large amounts of energy because the evaporation steps involved

  17. Distillability of entanglement in accelerated frames

    E-Print Network [OSTI]

    Shahpoor Moradi

    2012-01-02T23:59:59.000Z

    We study the entanglement distillability of bipartite mixed states of two modes of a free Dirac field as seen by two relatively accelerated parties. It is shown that there are states that will change from distillable into separable for a certain value of acceleration. We exemplify these criteria in the context of Werner states.

  18. New Design Methods and Algorithms for Multi-component Distillation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    New Design Methods and Algorithms for Multi-component Distillation Processes New Design Methods and Algorithms for Multi-component Distillation Processes multicomponent.pdf More...

  19. acrobat distiller job: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 September 1999 Distillation Theory. by Ivar J. Halvorsen and Sigurd, Norway 12;2 DistillationTheory.fm 2 September 1999 Table of Contents Introduction . . . . ....

  20. Distillation: Still towering over other options

    SciTech Connect (OSTI)

    Kunesh, J.G. [Fractionation Research, Inc., Stillwater, OK (United States); Kister, H.Z. [Brown and Root, Inc., Alhambra (Canada); Lockett, M.J. [Praxair, Inc., Tonawanda, NY (United States); Fair, J.R. [Univ. of Texas, Austin, TX (United States)

    1995-10-01T23:59:59.000Z

    Distillation dominates separations in the chemical process industries (CPI), at least for mixtures that normally are processed as liquids. The authors fully expect that distillation will continue to be the method of choice for many separations, and the method against which other options must be compared. So, in this article, they will put into some perspective just why distillation continues to reign as the king of separations, and what steps are being taken to improve its applicability and performance, as well as basic understanding of the technique.

  1. Pressurized release of liquefied fuel gases (LNG and LPG). Topical report, May 1993-February 1996

    SciTech Connect (OSTI)

    Atallah, S.; Janardhan, A.

    1996-02-01T23:59:59.000Z

    This report is an important contribution to the behavior of pressurized liquefied gases when accidentally released into the atmosphere. LNG vehicle fueling stations and LPG storage facilities operate at elevated pressures. Accidental releases could result in rainout and the formation of an aerosol in the vapor cloud. These factors must be considered when estimating the extent of the hazard zone of the vapor cloud using a heavier-than-air gas dispersion model such as DEGADIS (or its Windows equivalent DEGATEC). The DOS program PREL has been incorporated in the Windows program LFGRISK.

  2. Development of energy efficient membrane distillation systems

    E-Print Network [OSTI]

    Summers, Edward K

    2013-01-01T23:59:59.000Z

    Membrane distillation (MD) has shown potential as a means of desalination and water purification. As a thermally driven membrane technology which runs at relatively low pressure, which can withstand high salinity feed ...

  3. Minimizing corrosion in coal liquid distillation

    DOE Patents [OSTI]

    Baumert, Kenneth L. (Emmaus, PA); Sagues, Alberto A. (Lexington, KY); Davis, Burtron H. (Georgetown, KY)

    1985-01-01T23:59:59.000Z

    In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.

  4. Absorptive Recycle of Distillation Waste Heat

    E-Print Network [OSTI]

    Erickson, D. C.; Lutz, E. J., Jr.

    1982-01-01T23:59:59.000Z

    condenser operates above ambient temperature, the rejected heat also contains unused availability. By incorporating an absorption heat pump (AHP) into the distillation process, these sources of unused availability can be tapped so as to recycle (and hence...

  5. An improved model for multiple effect distillation

    E-Print Network [OSTI]

    Mistry, Karan H.

    Increasing global demand for fresh water is driving research and development of advanced desalination technologies. As a result, a detailed model of multiple effect distillation (MED) is developed that is flexible, simple ...

  6. Complex Fluid Analysis with the Advanced Distillation Curve Approach

    E-Print Network [OSTI]

    of a complex fluid is a graph of boiling temperature versus volume fraction distilled, a procedure embodied for each distillate fraction (for both qualitative and quantitative analysis); (2) temperature measurements) an assessment of the energy content of each distillate fraction; (6) trace chemical analysis of each distillate

  7. Investigation on effects of surface morphologies on response of LPG sensor based on nanostructured copper ferrite system

    SciTech Connect (OSTI)

    Singh, Satyendra [Nanomaterials and Sensors Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, U.P. (India)] [Nanomaterials and Sensors Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, U.P. (India); Yadav, B.C., E-mail: balchandra_yadav@rediffmail.com [Nanomaterials and Sensors Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, U.P. (India); Department of Applied Physics, School for Physical Sciences, Babasaheb Bhimrao Ambedkar University, Lucknow 226025, U.P. (India); Gupta, V.D. [Nanomaterials and Sensors Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, U.P. (India)] [Nanomaterials and Sensors Research Laboratory, Department of Physics, University of Lucknow, Lucknow 226007, U.P. (India); Dwivedi, Prabhat K. [DST Unit on Nanosciences, Department of Chemical Engineering, Indian Institute of Technology Kanpur, Kanpur, U.P. (India)] [DST Unit on Nanosciences, Department of Chemical Engineering, Indian Institute of Technology Kanpur, Kanpur, U.P. (India)

    2012-11-15T23:59:59.000Z

    Graphical abstract: Figure shows the variations in resistance with time for copper ferrite system synthesized in various molar ratio. A maximum variation in resistance was observed for copper ferrite prepared in 1:1 molar ratio. Highlights: ? Evaluation of structural, optical and surface morphologies. ? Significant variation in LPG sensing properties. ? Surface modification of ferric oxide pellet by copper ferrite. ? CuFe{sub 2}O{sub 4} pellets for LPG sensing at room temperature. -- Abstract: Synthesis of a copper ferrite system (CuFe{sub 2}O{sub 4}) via chemical co-precipitation method is characterized by X-ray diffraction, surface morphology (scanning electron microscope) and optical absorption spectroscopy. These characteristics show their dependence on the relative compositions of the two subsystems. They are further confirmed by the variation in the band gap. A study of gas sensing properties shows the spinel CuFe{sub 2}O{sub 4} synthesized in 1:1 molar ratio exhibit best response to LPG adsorption/resistance measurement. Thus resistance based LPG sensor is found robust, cheap and may be applied for kitchens and industrial applications.

  8. Testimony on Impacts of Proposed LPG Tank Development in Searsport, Maine on Property Values and Tourism-based Economic Activity

    E-Print Network [OSTI]

    Thomas, Andrew

    Testimony on Impacts of Proposed LPG Tank Development in Searsport, Maine on Property Values and Tourism-based Economic Activity Prepared for Thanks But No Tank (TBNT) for Presentation to the Searsport At the request of Counsel for Thanks But No Tanks (TBNT) and the Islesboro Island Trust (IIT), I have reviewed

  9. An evaluation of the potential end uses of a Utah tar sand bitumen. [Tar sand distillate

    SciTech Connect (OSTI)

    Thomas, K.P.; Harnsberger, P.M.; Guffey, F.D.

    1986-09-01T23:59:59.000Z

    To date the commercial application of tar sand deposits in the United States has been limited to their use as paving materials for county roads, parking lots, and driveways because the material, as obtained from the quarries, does not meet federal highway specifications. The bitumen in these deposits has also been the subject of upgrading and refining studies to produce transportation fuels, but the results have not been encouraging from an economic standpoint. The conversion of tar sand bitumen to transportation fuels cannot compete with crude oil refining. The purposes of this study were two-fold. The first was to produce vacuum distillation residues and determine if their properties met ASTM asphalt specifications. The second was to determine if the distillates could serve as potential feedstocks for the production of aviation turbine fuels. The bitumen used for this study was the oil produced during an in situ steamflood project at the Northwest Asphalt Ridge (Utah) tar sand deposit. Two distillation residues were produced, one at +316/sup 0/C and one at +399/sup 0/C. However, only the lower boiling residue met ASTM specifications, in this case as an AC-30 asphalt. The original oil sample met specifications as an AC-5 asphalt. These residue samples showed some unique properties in the area of aging; however, these properties need to be investigated further to determine the implications. It was also suggested that the low aging indexes and high flow properties of the asphalts may be beneficial for pavements that require good low-temperature performance. Two distillate samples were produced, one at IBP-316/sup 0/C and one at IBP-399/sup 0/C. The chemical and physical properties of these samples were determined, and it was concluded that both samples appear to be potential feedstocks for the production of aviation turbine fuels. However, hydrogenation studies need to be conducted and the properties of the finished fuels determined to verify the prediction. 14 refs., 12 tabs.

  10. LPG recovery from refinery flare by waste heat powered absorption refrigeration

    SciTech Connect (OSTI)

    Erickson, D.C.; Kelly, F.

    1998-07-01T23:59:59.000Z

    A waste heat powered ammonia Absorption Refrigeration Unit (ARU) has commenced operation at the Colorado Refining Company in Commerce City, Colorado. The ARU provides 85 tons of refrigeration at 30 F to refrigerate the net gas/treat gas stream, thereby recovering 65,000 barrels per year of LPG which formerly was flared or burned as fuel. The ARU is powered by the 290 F waste heat content of the reform reactor effluent. An additional 180 tons of refrigeration is available at the ARU to debottleneck the FCC plant wet gas compressors by cooling their inlet vapor. The ARU is directly integrated into the refinery processes, and uses enhanced, highly compact heat and mass exchange components. The refinery's investment will pay back in less than two years from increased recovery of salable product, and CO{sub 2} emissions are decreased by 10,000 tons per year in the Denver area.

  11. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) Geographic Area Month Kerosene No. 1 Distillate No. 2...

  12. Desalination Using Vapor-Compression Distillation

    E-Print Network [OSTI]

    Lubis, Mirna R.

    2010-07-14T23:59:59.000Z

    and MSF, this research investigates a high-efficiency mechanical vapor-compression distillation system that employs an improved water flow arrangement. The incoming salt concentration was 0.15% salt for brackish water and 3.5% salt for seawater, whereas...

  13. Complex Distillation Arrangements : Extending the Petlyuk Ideas

    E-Print Network [OSTI]

    Skogestad, Sigurd

    to distillation columns ac- count for roughly 3 of the total energy consumption in the U.S. (Ognisty 1995 to reduce energy consumption at least two alternative approaches have been proposed both in the literature is also known as the Petlyuk column, due to a theoretical study of Pet- lyuk et al. (1965), or as a fully

  14. Minimum Energy Diagrams for Multieffect Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    and the energy use from this process accounts for an estimated 3% of the world energy consumption.1 With rising on the overall plant energy consumption. The use of heat integration combined with complex config- urations distillation ar- rangements. An easy form of comparison for energy consumption is the minimum vapor flow rate

  15. Naphthenic acid corrosion in crude distillation units

    SciTech Connect (OSTI)

    Piehl, R.L.

    1988-01-01T23:59:59.000Z

    This paper summarizes corrosion experience in crude distillation units processing highly naphthenic California crude oils. Correlations have been developed relating corrosion rates to temperature and total acid number. There is a threshold acid number in the range of 1.5 to 2 mg KOH/g below which corrosion is minimal. High concentrations of hydrogen sulfide may raise this threshold value.

  16. Distillation: Present Status and Future Directions

    E-Print Network [OSTI]

    Fair, J. R.; Humphrey, J. L.

    1984-01-01T23:59:59.000Z

    -pressure steam as a heat source. The steam has, very likely, been sent through one or more users (turbi ne dri ves) before reaching the distillation reboiler. It seems almost characteristic of large chemical and refining complexes that there is a chronic...

  17. Construction and operation of a flash distillation apparatus

    E-Print Network [OSTI]

    Knezevich, Milan

    2012-06-07T23:59:59.000Z

    , Calibration Data of Orifioe ~, i, . ~ ~ ~ . ~ ~ . ~ 13 III. Equilibrium Data of Ethanol-Eater Mixtures . ~ * ~ ~ , 17 IV, . Flash Vaporieation Data of Ethanol Hater hIlxtures& + , 18 VI ~ Hempel Distillation of Oklahoma City Crude ~ . . . Flash... Vaporiration of Oklahoma City Crude ~ . ~ 21 22 VII' Hempel Distillations of Flash Distillates of Oklahoma City Crude . ~ ~ ~ ~ ~ ~ ~ i ~ ~ ~ ~ ~ ~ ~ ~ 24 VIII+ Hompel Distillations of Flash Residuums of Oklahoma City Crude ~ ~ ~ ~ ~ i ~ ~ o...

  18. Integrated C3 Feedstock and Aggregated Distillation Model for

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Polypropylene Propane return Reactor effluent Distillation Polymerization FeedTank Propylene (91%) Goal: Select rates Constraints on composition of Propane Return, Distillation Overhead & Reactor Feed Limits Distillation Model Relates overhead composition of propane with flowrate of propane feed to the splitter

  19. Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens,

    E-Print Network [OSTI]

    to infinity. We call such protocols asymp- totic and the fraction of distilled Bell states per initial copy#12;#12;Asymptotic adaptive bipartite entanglement distillation protocol Erik Hostens, Jeroen: July 13, 2006) We present a new asymptotic bipartite entanglement distillation protocol

  20. DYNAMICS AND CONTROL OF DISTILLATION COLUMNS -A CRITICAL SURVEY

    E-Print Network [OSTI]

    Skogestad, Sigurd

    : 47-7-594080 Figure 1: Typical simple distillation column. zF, yD and xB are mole fractions. tureDYNAMICS AND CONTROL OF DISTILLATION COLUMNS - A CRITICAL SURVEY Sigurd Skogestad Chemical cation and Control, 18, 177-217, 1997. Abstract Distillation column dynamics and control has been viewed

  1. Effect of Number of Fractionating Trays on Reactive Distillation Performance

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    Effect of Number of Fractionating Trays on Reactive Distillation Performance Muhammad A. Al and rectifying sec- tions of a reacti®e distillation column can degrade performance. This effect, if true®e distillation columns cannot use conser®ati®e estimates of tray numbers, that is, we cannot simply add excess

  2. DYNAMICS AND CONTROL OF DISTILLATION COLUMNS A CRITICAL SURVEY

    E-Print Network [OSTI]

    Skogestad, Sigurd

    distillation column. z F , yD and xB are mole fractions. ture review, but a few new ideas are also presentedDYNAMICS AND CONTROL OF DISTILLATION COLUMNS ­ A CRITICAL SURVEY Sigurd Skogestad \\Lambda Chemical, Identification and Control, 18, 177­217, 1997. Abstract Distillation column dynamics and control has been viewed

  3. Model Predictive Control of a Kaibel Distillation Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    column with model predictive control (MPC). A Kaibel distillation column has several advantages comparedModel Predictive Control of a Kaibel Distillation Column Martin Kvernland Ivar Halvorsen Sigurd only a single column shell. The distillation process is a multivariable process which leads

  4. RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT

    E-Print Network [OSTI]

    RIS0-M-2319 RISK ANALYSIS OF A DISTILLATION UNIT J. R. Taylor**, 0. Hansen*, C. Jensen*, 0. F. A risk analysis of a batch distillation unit is de- scribed. The analysis has been carried out at several.2. Objectives and organisation 5 1.2.2. Philosophy and approach 6 1.3.1. The distillation unit 8 1

  5. CHEM333: Experiment 4: Steam Distillation of Essential Oils;

    E-Print Network [OSTI]

    Taber, Douglass

    CHEM­333: Experiment 4: Steam Distillation of Essential Oils; Experiments A, C, D and below. Reading: For this experiment read Chapter 10. This week you will get to use steam distillation to isolate may wait until you come to lab to find out which spice you get. Steam distillation is not a common

  6. Nonresidential buildings energy consumption survey: 1979 consumption and expenditures. Part 2. Steam, fuel oil, LPG, and all fuels

    SciTech Connect (OSTI)

    Patinkin, L.

    1983-12-01T23:59:59.000Z

    This report presents data on square footage and on total energy consumption and expenditures for commercial buildings in the contiguous United States. Also included are detailed consumption and expenditures tables for fuel oil or kerosene, liquid petroleum gas (LPG), and purchased steam. Commercial buildings include all nonresidential buildings with the exception of those where industrial activities occupy more of the total square footage than any other type of activity. 7 figures, 23 tables.

  7. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1984-03-27T23:59:59.000Z

    A method is described for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor, contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  8. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, E.M. Jr.

    1985-08-20T23:59:59.000Z

    A method and apparatus are disclosed for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column. 7 figs.

  9. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1984-01-01T23:59:59.000Z

    A method for conducting catalytic chemical reactions and fractionation of the reaction mixture comprising feeding reactants into a distillation column reactor contracting said reactant in liquid phase with a fixed bed catalyst in the form of a contact catalyst structure consisting of closed porous containers containing the catatlyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  10. Contact structure for use in catalytic distillation

    DOE Patents [OSTI]

    Jones, Jr., Edward M. (Friendswood, TX)

    1985-01-01T23:59:59.000Z

    A method and apparatus for conducting catalytic chemical reactions and fractionation of the reaction mixture, comprising and feeding reactants into a distillation column reactor contracting said reactant in a liquid phase with a fixed bed catalyst in the form of a contact catalyst structure, consisting of closed porous containers containing the catalyst for the reaction and a clip means to hold and support said containers, which are disposed above, i.e., on the distillation trays in the tower. The trays have weir means to provide a liquid level on the trays to substantially cover the containers. In other words, the trays function in their ordinary manner with the addition thereto of the catalyst. The reaction mixture is concurrently fractionated in the column.

  11. Fuel-blending stocks from the hydrotreatment of a distillate formed by direct coal liquefaction

    SciTech Connect (OSTI)

    Andile B. Mzinyati [Sasol Technology Research and Development, Sasolburg (South Africa). Fischer-Tropsch Refinery Catalysis

    2007-09-15T23:59:59.000Z

    The direct liquefaction of coal in the iron-catalyzed Suplex process was evaluated as a technology complementary to Fischer-Tropsch synthesis. A distinguishing feature of the Suplex process, from other direct liquefaction processes, is the use of a combination of light- and heavy-oil fractions as the slurrying solvent. This results in a product slate with a small residue fraction, a distillate/naphtha mass ratio of 6, and a 65.8 mass % yield of liquid fuel product on a dry, ash-free coal basis. The densities of the resulting naphtha (C{sub 5}-200{sup o}C) and distillate (200-400{sup o}C) fractions from the hydroprocessing of the straight-run Suplex distillate fraction were high (0.86 and 1.04 kg/L, respectively). The aromaticity of the distillate fraction was found to be typical of coal liquefaction liquids, at 60-65%, with a Ramsbottom carbon residue content of 0.38 mass %. Hydrotreatment of the distillate fraction under severe conditions (200{sup o}C, 20.3 MPa, and 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1}) with a NiMo/Al{sub 2}O{sub 3} catalyst gave a product with a phenol content of {lt}1 ppm, a nitrogen content {lt}200 ppm, and a sulfur content {lt}25 ppm. The temperature was found to be the main factor affecting diesel fraction selectivity when operating at conditions of WHSV = 0.41 g{sub feed} h{sup -1} g{sub catalyst}{sup -1} and PH{sub 2} = 20.3 MPa, with excessively high temperatures (T {gt} 420{sup o}C) leading to a decrease in diesel selectivity. The fuels produced by the hydroprocessing of the straight-run Suplex distillate fraction have properties that make them desirable as blending components, with the diesel fraction having a cetane number of 48 and a density of 0.90 kg/L. The gasoline fraction was found to have a research octane number (RON) of 66 and (N + 2A) value of 100, making it ideal as a feedstock for catalytic reforming and further blending with Fischer-Tropsch liquids. 44 refs., 9 figs., 12 tabs.

  12. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14T23:59:59.000Z

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  13. Energy conservation in distillation: a technology applications manual

    SciTech Connect (OSTI)

    Not Available

    1980-05-01T23:59:59.000Z

    Distillation is the most widely practiced technique for separating mixtures of chemical species, but it is an energy intensive process. A 10% reduction in distillation energy consumption would effect a significant savings. On a national basis this would be an annual savings of 200 trillion Btu, or the equivalent of 36.5 million barrels of oil per year. Technology to achieve these savings in distillation energy is available and measures are presented to assist process engineers in technical and economic analysis of the energy conservation measures most suitable for particular distillation applications. The manual catalogs all of the energy conservation options applicable to distillation and the options by the investment required; describes in detail the options having a significant potential to reduce distillation energy requirements economically; provides guidelines that will allow the plant engineer to quickly screen each option for his application; and provides short-cut calculation procedures for use in a preliminary economic analysis of promising options.

  14. Energy Conservation Options in Distillation Processes

    E-Print Network [OSTI]

    Harris, G. E.; Hearn, W. R.; Blythe, G. M.; Stuart, J. M.

    1980-01-01T23:59:59.000Z

    ~itroo.? ':!OD.e~tell.,..ot!.k1 .'k..,.-.ottNltlu'..,. II ""'I'JI ..... ~I_ """-.4008l1"OO I ~.z.,. 1 ,1'1 (-frl-.'....u_~ R.da at AC~Ofllftl\\,J'ftlit...." ? I 5 "'-tlnc&! Tt.,.. ? 21.' \\lip Gilil.In31 j TnyE.'tIc>Mcy .11.1'llo I ~~TI""'.'2.at... I There are many options available to the engi*eer seeking to reduce the energy requirements of a distil lation process. The technology for most of these I, options has been available for many years, but it has only recently become economically...

  15. Use of computers for multicomponent distillation calculations

    E-Print Network [OSTI]

    Sullivan, Samuel Lane

    1959-01-01T23:59:59.000Z

    The corrected values for the b 's are best cal- i culated by multiplying (b. /d ) by (d. ) The compositions for each component in the vapor and liquid streams leaving plate j are calculated by use of the following equations. ('i/ i)ca ( i)co y. ji c Z (v... . . /b. ) (b. ) ji i ca i co i=1 , f a j x N+1 C (47-b) A temperature profile may be calculated by making either bubble or dew point calculations based on the compositions obtained by use of Equations (46) and (47). The specified distillate rate must...

  16. Advanced Distillation: Programs Proposed to DOE

    E-Print Network [OSTI]

    Woinsky, S. G.

    to the foremost practitioner of the Advanced Distillation art, due to a 30 year continuity in Ule area as both a consultant and a university professor. His consulting assignments lu1ve been long-ternl

  17. Fusion Residues

    E-Print Network [OSTI]

    Kenneth Intriligator

    1991-08-19T23:59:59.000Z

    We discuss when and how the Verlinde dimensions of a rational conformal field theory can be expressed as correlation functions in a topological LG theory. It is seen that a necessary condition is that the RCFT fusion rules must exhibit an extra symmetry. We consider two particular perturbations of the Grassmannian superpotentials. The topological LG residues in one perturbation, introduced by Gepner, are shown to be a twisted version of the $SU(N)_k$ Verlinde dimensions. The residues in the other perturbation are the twisted Verlinde dimensions of another RCFT; these topological LG correlation functions are conjectured to be the correlation functions of the corresponding Grassmannian topological sigma model with a coupling in the action to instanton number.

  18. advanced distillation control: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Morari California.Eng., Norwegian Institute of Technology (NTH), N-7034 Trondheim, Norway Paper presented at Symposium Distillation Skogestad, Sigurd 14 CONTROL AND ENERGY...

  19. azeotropic distillation columns: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S, Norway SCOPE OF THE PROJECT How can we separate ternary mixtures in closed batch...

  20. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1998 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  1. Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1999 359 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  2. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Gasoline and Diesel Fuel Update (EIA)

    Marketing Annual 1996 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  3. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Marketing Annual 1997 401 Table 50. Prime Supplier Sales Volumes of Distillate Fuel Oils and Kerosene by PAD District and State (Thousand Gallons per Day) - Continued...

  4. Energy Use in Distillation Operation: Nonlinear Economic Effects

    E-Print Network [OSTI]

    White, D. C.

    2010-01-01T23:59:59.000Z

    important. For many distillation columns there is a tradeoff in operation between energy usage and product recovery and setting the proper usage target involves a calculation of the economic tradeoff between these two factors. However, distillation is a non-linear...

  5. Pyrolysis of shale oil vacuum distillate fractions

    SciTech Connect (OSTI)

    Hazlett, R.N.; Beal, E.

    1983-01-01T23:59:59.000Z

    The freezing point of US Navy jet fuel (JP-5) has been related to the amounts of large n-alkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how the n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30, and 32 ppM in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

  6. Pyrolysis of shale oil vacuum distillate fractions

    SciTech Connect (OSTI)

    Hazlett, R.N.; Beal, E.

    1983-02-01T23:59:59.000Z

    The freezing point of U.S. Navy jet fuel (JP-5) has been related to the amounts of large nalkanes present in the fuel. This behavior applies to jet fuels derived from alternate fossil fuel resources, such as shale oil, coal, and tar sands, as well as those derived from petroleum. In general, jet fuels from shale oil have the highest and those from coal the lowest n-alkane content. The origin of these n-alkanes in the amounts observed, especially in shale-derived fuels, is not readily explained on the basis of literature information. Studies of the processes, particularly the ones involving thermal stress, used to produce these fuels are needed to define how th n-alkanes form from larger molecules. The information developed will significantly contribute to the selection of processes and refining techniques for future fuel production from shale oil. Carbon-13 nmr studies indicate that oil shale rock contains many long unbranched straight chain hydrocarbon groups. The shale oil derived from the rock also gives indication of considerable straight chain material with large peaks at 14, 23, 30 and 32 ppm in the C-13 nmr spectrum. Previous pyrolysis studies stressed fractions of shale crude oil residua, measured the yields of JP-5, and determined the content of potential n-alkanes in the JP-5 distillation range (4). In this work, a shale crude oil vacuum distillate (Paraho) was separated into three chemical fractions. The fractions were then subjected to nmr analysis to estimate the potential for n-alkane production and to pyrolysis studies to determine an experimental n-alkane yield.

  7. Structural group analysis of residues from Athabasca bitumen

    SciTech Connect (OSTI)

    Gray, M.R.; Choi, J.H.K.; Egiebor, N.O. (Alberta Univ., Edmonton, AB (Canada). Dept. of Chemical Engineering); Kirchen, R.P.; Sanford, E.C. (Syncrude Canada Ltd., Edmonton, AB (Canada))

    1989-01-01T23:59:59.000Z

    Although the processability of bitumen from tar sand is dependent on its chemical composition, the details of this relationship are poorly understood. In this study, residue fractions from Athabasca bitumen (topped at different temperatures) and hydrocracker and coker residues were analyzed in detail. Separated class fractions were subjected to elemental analysis, NMR and IR spectroscopy, and potentiometric titration. These data were combined mathematically to obtain a structural profile of each oil. This analysis defines the structural changes in asphaltene precipitates due to distillation and processing, as well as the quantitative changes in the overall structural composition of the oil. Hydrocarbon structures such as paraffinic chains and naphthenes show definite trends with distillation and processing.

  8. Heat Integrated Distillation through Use of Microchannel Technology

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose goal is to develop a breakthrough distillation process using Microchannel Process Technology to integrate heat transfer and separation into a single unit operation.

  9. CHEM333: Lab Experiment 3: Distillation and Gas Chromatography

    E-Print Network [OSTI]

    Taber, Douglass

    . Distillation is used to isolate many of life's essentials such as gasoline from oil or brandy from wine much about the mathematics of Raoult's Law; you will see it again in physical chemistry. Pay particular

  10. Absorption Cycle Fundamentals and Applications Guidelines for Distillation Energy Savings

    E-Print Network [OSTI]

    Erickson, D. C.; Davidson, W. F.

    1984-01-01T23:59:59.000Z

    The absorption cycle offers one of the most economic and widely applicable technologies for waste heat upgrading. It can use off-the-shelf hardware that is available now, at any required capacity rating. Fractional distillations, as a class...

  11. Membrane augmented distillation to separate solvents from water

    DOE Patents [OSTI]

    Huang, Yu; Baker, Richard W.; Daniels, Rami; Aldajani, Tiem; Ly, Jennifer H.; Alvarez, Franklin R.; Vane, Leland M.

    2012-09-11T23:59:59.000Z

    Processes for removing water from organic solvents, such as ethanol. The processes include distillation to form a rectified overhead vapor, compression of the rectified vapor, and treatment of the compressed vapor by two sequential membrane separation steps.

  12. An experimental and mathematical investigation of hydrocarbon steam distillation

    E-Print Network [OSTI]

    Langhoff, John Allan

    1984-01-01T23:59:59.000Z

    of Committee) Dr. Pau B. Crawford (Member) r. William D. McCain Jr. r. A ber t T. Watson (Member) Dr. i l. iam D. on Gonten ead of Department) December 1984 ABSTRACT An Experimental and Mathematical Investigation of Hydrocarbon Steam Distillation... mechanism associated with steam flooding and in-situ combustion enhanced oil recovery projects. It also takes place in hydrocarbon recovery from deep volatile oil reservoirs. Nethods for predicting the recovery of hydrocarbons by steam distillation have...

  13. Determination of plate efficiencies for conventional distillation columns

    E-Print Network [OSTI]

    Harris, Thomas Raymond

    2012-06-07T23:59:59.000Z

    DETERMINATION OF PLATE EFFICIENCIES FOR CONVENTIONAL DISTILLATION COIUMNS A Thesis By Thomas Raymond Harris Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1962 Ma)or Sub)ect t Chemical Engineering DETERMINATION OF PLATE EFFICIENCIES FOR CONVENTIONAL DISTILLATION COLUMNS A Thesis Thomas Raymond Harris Approred as to style and content bye Chairman of ommittee Head...

  14. Single-step distillation protocol with generalized beam splitters

    SciTech Connect (OSTI)

    Martin-Delgado, M. A.; Navascues, M. [Departamento de Fisica Teorica I, Universidad Complutense, 28040 Madrid, (Spain)

    2003-07-01T23:59:59.000Z

    We develop a distillation protocol for multilevel qubits (qudits) using generalized beam splitters like in the proposal of Pan et al. for ordinary qubits. We find an acceleration with respect to the scheme of Bennet et al. when extended to qudits. It is also possible to distill entangled pairs of photons carrying orbital angular momenta states that conserve the total angular momenta as those produced in recent experiments.

  15. Integrated Thermal and Hydraulic Analysis of Distillation Columns

    E-Print Network [OSTI]

    Samant, K.; Sinclair, I.; Keady, G.

    significant additional insights to help screen the options for distillation column revamps. Column Targeting Aspen Plus Column Targeting tool offers capabilities for thermal and hydraulic analysis of distillation columns. During design or retrofit analysis...). Aspen Plus Column Targeting Tool generates the CGCCs based on the Practical Near-Minimum Thermodynamic Condition (PNMTC) approximation (Dhole and Linnhoff). The enthalpies used in plotting the CGCCs are calculated at a given stage of the column...

  16. Synthesis and design of optimal thermal membrane distillation networks

    E-Print Network [OSTI]

    Nyapathi Seshu, Madhav

    2006-10-30T23:59:59.000Z

    distillation as a technology that can be driven by thermal energy at low enthalpy, such as geothermal energy, by using a hybrid air gap membrane distillation- fluidized bed crystallization assembly for desalination. Tomaszewska (2000) has studied... of pre-pressurizing of the membrane pores and control of dissolved gas concentrations in the feed and recycled permeate in order to prevent pore penetration and wetting (Agashichev and Sivakov, 1993). Temperature polarization effects have been...

  17. Key Distillation and the Secret-Bit Fraction

    E-Print Network [OSTI]

    Nick S. Jones; Lluis Masanes

    2008-05-12T23:59:59.000Z

    We consider distillation of secret bits from partially secret noisy correlations P_ABE, shared between two honest parties and an eavesdropper. The most studied distillation scenario consists of joint operations on a large number of copies of the distribution (P_ABE)^N, assisted with public communication. Here we consider distillation with only one copy of the distribution, and instead of rates, the 'quality' of the distilled secret bits is optimized, where the 'quality' is quantified by the secret-bit fraction of the result. The secret-bit fraction of a binary distribution is the proportion which constitutes a secret bit between Alice and Bob. With local operations and public communication the maximal extractable secret-bit fraction from a distribution P_ABE is found, and is denoted by Lambda[P_ABE]. This quantity is shown to be nonincreasing under local operations and public communication, and nondecreasing under eavesdropper's local operations: it is a secrecy monotone. It is shown that if Lambda[P_ABE]>1/2 then P_ABE is distillable, thus providing a sufficient condition for distillability. A simple expression for Lambda[P_ABE] is found when the eavesdropper is decoupled, and when the honest parties' information is binary and the local operations are reversible. Intriguingly, for general distributions the (optimal) operation requires local degradation of the data.

  18. Process for removing naphthenic acids from petroleum distillates

    SciTech Connect (OSTI)

    Danzik, M.

    1987-01-06T23:59:59.000Z

    A liquid extraction process is described for removing naphthenic acids from naphthenic acid containing petroleum distillates boiling within the range of about 180/sup 0/-600/sup 0/C. and having an acid number of at least about 0.2 which process comprises the steps of: (a) intimately contacting the petroleum distillates with a solvent consisting essentially of methanol, water, and about from 2-20 wt. % ammonia and having a methanol: water ratio in the range of about from 0.2 to 3 parts by weight of methanol per part by weight of water and using an ammonia to petroleum distillate ratio of about 0.1-1 part by weight of ammonia per 100 parts by weight of the petroleum distillate. This selectively extracts the naphthenic acids into the solvent and yielding an immiscible two-phase liquid mixture, one of which is naphthenic acid-rich solvent phase and the other of which is a substantially napthenic acid-free petroleum distillate phase; and (b) separating and respectively recovering the naphtenic acid-rich solvent phase and petroleum distillate phase.

  19. Table A3. Refiner/Reseller Prices of Distillate and Residual Fuel Oils,

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet)per Thousand Cubic4,630.2 10,037.24. U.S. VehicleFoot,EffectiveA3.

  20. Table A3. Refiner/Reseller Prices of Distillate and Residual Fuel Oils,

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProved ReservesFeet)per Thousand Cubic4,630.2 10,037.24. U.S. VehicleFoot,EffectiveA3.

  1. Kinetics and thermodynamics of hydrotreating synthetic middle distillates

    SciTech Connect (OSTI)

    Fisher, I.P. (Petro-Canada R and D Dept., Sheridan Park, Ontario (Canada)); Wilson, M.F. (CANMET, Ottawa, Ontario (Canada))

    1987-04-01T23:59:59.000Z

    Middle distillates from the Tar Sands deposits in Alberta are an important component of diesel and jet fuels in the Canadian market. Commercial catalysts based on sulfided Ni-Mo and Ni-W are currently used to hydrogenate synthetic distillates to improve the cetane number and smoke point. In previous work {sup 13}C NMR was used to study the kinetics of overall hydrogenation of aromatics over sulfided Co-Mo, Ni-Mo and Ni-W catalysts. Arrhenius parameters were obtained for hydrogenation over sulfided Ni-W catalyst for a similar distillate feedstock. In the latter study, mass spectrometry was used to quantitate the three major aromatic hydrocarbon group types in the feed and products. In this study, liquid products from hydrotreating experiments with a hydrotreated distillate from delayed coking of Athabasca bitumen and sulfided Co-Mo and Ni-Mo catalysts have been analyzed by mass spectrometry. This completes a preliminary comparison of the kinetics of hydrogenation of alkylbenzenes, benzocycloparaffins and benzodicycloparaffins, the three major aromatic hydrocarbon types in these distillates.

  2. Application of a Plantwide Control Design Procedure to a Distillation Column with Heat Pump

    E-Print Network [OSTI]

    Skogestad, Sigurd

    (Larsson & Skogestad 2001) to a distillation column heat-integrated by using a heatpump. Top-down analysis) and apply it to a distillation column with heatpump. Plantwide control design should start by formulating

  3. ORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried

    E-Print Network [OSTI]

    . Physical properties . Protein . Twin-screw extruder Introduction As a consequence of changes in energyORIGINAL PAPER Twin-Screw Extrusion Processing of Distillers Dried Grains with Solubles (DDGS. Twin- screw extrusion studies were performed to investigate the production of nutritionally balanced

  4. Rigorous Synthesis and Simulation of Complex Distillation Networks

    E-Print Network [OSTI]

    Linninger, Andreas A.

    energy-efficient distillation net- works. Complex column networks have substantial potential for energy- thesizing such complex energy-efficient networks. A robust feasibility criterion drives the selection foundations of se st in exploring energy-efficient distillatin exploring energy-efficient distillat ave

  5. Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Separation of Azeotropic Mixtures in Closed Batch Distillation Arrangements S. Skouras and S to obtain a light and a heavy fraction simultaneously from the top and the bottom of the column, while an intermediate fraction may also be recovered in the middle vessel. Two modifications of the multivessel

  6. Solar Ethanol Distillation Oara Neumann,1,3

    E-Print Network [OSTI]

    requiring no energy input by conventional sources, with the potential to replace, or significantly reduce-harvesting nanoparticles that capture solar energy for direct liquid-vapor conversion, eliminating the energy O-9 Solar Ethanol Distillation Oara Neumann,1,3 Albert D. Neumann,2 Julius Müller,1

  7. Design of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

    E-Print Network [OSTI]

    Al-Arfaj, Muhammad A.

    , methanol recovery 1. Introduction A process of producing TAME via reactive distillation has been presented the bulk of the reaction between C5 and methanol to produce TAME and a reactive distillation. MethanolDesign of Extraction Column Methanol Recovery System for the TAME Reactive Distillation Process

  8. Improved Swing-Cut Modeling for Planning and Scheduling of Oil-Refinery Distillation Units

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    , Pennsylvania 15213, United States. Crude-oil assays, Distillation, Fractionation, Swing-cuts, Temperature cut with in the nonlinear optimization. 1. INTRODUCTION Distillation or fractionation models for planning and scheduling1 Improved Swing-Cut Modeling for Planning and Scheduling of Oil-Refinery Distillation Units Brenno

  9. Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Optimal Operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionating Vidar the unexpected result that over-fractionating one of the product streams in a Petlyuk distillation column may is optimal in some cases. 1. Introduction The Petlyuk distillation column, see Figure 1(a), with a pre-fractionator

  10. Integrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel

    E-Print Network [OSTI]

    Skogestad, Sigurd

    into a number of product fractions in a single batch column whereas, in continuous distillation several columnsIntegrated Design, Operation and Control of Batch Extractive Distillation with a Middle Vessel E. K distillation for separating homogeneous minimum-boiling azeotropic mixtures, where the extractive agent

  11. Model predictive control of a pilot-scale distillation column using a programmable automation controller

    E-Print Network [OSTI]

    Model predictive control of a pilot-scale distillation column using a programmable automation). The controller is tested on a pilot-scale binary distillation column to track reference temperatures. A majorRIO) to control a pilot-scale binary distillation col- umn. Both the PI-controllers and the supervising online MPC

  12. Reactive Distillation for Esterification of Bio-based Organic Acids

    SciTech Connect (OSTI)

    Fields, Nathan; Miller, Dennis J.; Asthana, Navinchandra S.; Kolah, Aspi K.; Vu, Dung; Lira, Carl T.

    2008-09-23T23:59:59.000Z

    The following is the final report of the three year research program to convert organic acids to their ethyl esters using reactive distillation. This report details the complete technical activities of research completed at Michigan State University for the period of October 1, 2003 to September 30, 2006, covering both reactive distillation research and development and the underlying thermodynamic and kinetic data required for successful and rigorous design of reactive distillation esterification processes. Specifically, this project has led to the development of economical, technically viable processes for ethyl lactate, triethyl citrate and diethyl succinate production, and on a larger scale has added to the overall body of knowledge on applying fermentation based organic acids as platform chemicals in the emerging biorefinery. Organic acid esters constitute an attractive class of biorenewable chemicals that are made from corn or other renewable biomass carbohydrate feedstocks and replace analogous petroleum-based compounds, thus lessening U.S. dependence on foreign petroleum and enhancing overall biorefinery viability through production of value-added chemicals in parallel with biofuels production. Further, many of these ester products are candidates for fuel (particularly biodiesel) components, and thus will serve dual roles as both industrial chemicals and fuel enhancers in the emerging bioeconomy. The technical report from MSU is organized around the ethyl esters of four important biorenewables-based acids: lactic acid, citric acid, succinic acid, and propionic acid. Literature background on esterification and reactive distillation has been provided in Section One. Work on lactic acid is covered in Sections Two through Five, citric acid esterification in Sections Six and Seven, succinic acid in Section Eight, and propionic acid in Section Nine. Section Ten covers modeling of ester and organic acid vapor pressure properties using the SPEAD (Step Potential Equilibrium and Dynamics) method.

  13. Enhanced Separation Efficiency in Olefin/Paraffin Distillation

    Broader source: Energy.gov [DOE]

    This factsheet describes a research project whose main objective is to develop technologies to enhance separation efficiencies by replacing the conventional packing materials with hollow fiber membranes, which have a high specific area and separated channels for both liquid and vapor phases. The use of hollow fibers in distillation columns can help refineries decrease operating costs, reduce greenhouse gas emissions through reduced heating costs, and help expand U.S. refining capacity through improvements to existing sites, without large scale capital investment.

  14. "Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department of Chemical Engineering

    E-Print Network [OSTI]

    Skogestad, Sigurd

    distillation · Underwood (1946, 1948a,b), Fractional distillation of multicomponent mixtures · Shiras (1950"Distillation, Absorption and Extraction" April 5-6, 2001 in Bamberg,, Halvorsen NTNU Department Distillation Arrangements by Ivar J. Halvorsen and Sigurd Skogestad Norwegian University of Science

  15. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Dale, L; Opilla, R; Surles, T

    1980-09-01T23:59:59.000Z

    Technologies available for the production of ethanol from whole corn are reviewed. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. The use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - is reviewed as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. The environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass are covered. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  16. Alcohol production from agricultural and forestry residues

    SciTech Connect (OSTI)

    Opilla, R.; Dale, L.; Surles, T.

    1980-05-01T23:59:59.000Z

    A variety of carbohydrate sources can be used as raw material for the production of ethanol. Section 1 is a review of technologies available for the production of ethanol from whole corn. Particular emphasis is placed on the environmental aspects of the process, including land utilization and possible air and water pollutants. Suggestions are made for technological changes intended to improve the economics of the process as well as to reduce some of the pollution from by-product disposal. Ethanol may be derived from renewable cellulosic substances by either enzymatic or acid hydrolysis of cellulose to sugar, followed by conventional fermentation and distillation. Section 2 is a review of the use of two agricultural residues - corn stover (field stalks remaining after harvest) and straw from wheat crops - as a cellulosic feedstock. Two processes have been evaluated with regard to environmental impact - a two-stage acid process developed by G.T. Tsao of Purdue University and an enzymatic process based on the laboratory findings of C.R. Wilke of the University of California, Berkeley. Section 3 deals with the environmental residuals expected from the manufacture of methyl and ethyl alcohols from woody biomass. The methanol is produced in a gasification process, whereas ethanol is produced by hydrolysis and fermentation processes similar to those used to derive ethanol from cellulosic materials.

  17. Heat Recovery in Distillation by Mechanical Vapor Recompression

    E-Print Network [OSTI]

    Becker, F. E.; Zakak, A. I.

    matc~ can be made between low-grade waste energy sourc~s and process uses, thereby improving plant energ~ efficiency. I A relatively high rate of return on invest-JI ment is expected in most cases. The optimum op, erating conditions are dictated...," Chem. Eng. Prog., Vol. 76:7, pp. 44-49, July 1980. I 2. Anon, "Di,stillation Prime Target for Energ~ Conservation," Oil & Gas Journal, Vol. 76:~6, pp. 92-94, April 17, 1978. I 3. W. F. Kenne'y, "Reducing the Energy Demand o~ Separation Processes...

  18. Multiple steady states during reactive distillation of methyl tert-butyl ether

    SciTech Connect (OSTI)

    Nijhuis, S.A. (Univ. of Amsterdam (Netherlands). Chemical Engineering Dept.); Kerkhof, F.P.J.M.; Mak, A.N.S. (Comprimo Engineers and Contractors, Amsterdam (Netherlands))

    1993-11-01T23:59:59.000Z

    This paper presents results of computer simulations of the synthesis of methyl tert-butyl ether (MTBE) in a fixed-bed reactor and in a reactive distillation column. These calculations clearly showed the advantages of MTBE synthesis in a catalytic distillation tower. Furthermore, the computer simulations showed that multiple steady states may occur in the reactive distillation column during MTBE synthesis in a broad range of operating conditions. An analysis of some sensitivity studies is presented.

  19. E-Print Network 3.0 - advanced distillation curve Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    58 (2003) 26712680 www.elsevier.comlocateces Summary: distillation: Advanced simulation and experimental validation. Computers and Chemical Engineering, 22, S371-S......

  20. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1998 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  1. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    Petroleum Marketing Annual 1995 337 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  2. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    U.S. Energy Information Administration (EIA) Indexed Site

    Petroleum Marketing Annual 1999 295 Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State (Thousand Gallons per Day) - Continued...

  3. E-Print Network 3.0 - atmospheric crude distillation Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Problems Summary: and atmospheric distillations of crude-oil mixtures from charging tanks. The crude is then processed in order... of resources: crude marine vessels, storage...

  4. Development of a Fuzzy Logic Controller for a Distillation Column using Rockwell Software .

    E-Print Network [OSTI]

    Nizami, Muhammad

    2011-01-01T23:59:59.000Z

    ??In this thesis, an alternative control method based on Fuzzy Inference System (FIS) is proposed to keep the product composition of a distillation column constant.… (more)

  5. Minimum Energy Consumption in Multicomponent Distillation. 1. Vmin Diagram for a Two-Product Column

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Minimum Energy Consumption in Multicomponent Distillation. 1. Vmin Diagram for a Two-Product Column how the minimum energy consumption is related to the feed-component distribution for all possible operating points in a two-product distillation column with a multicomponent feed. The classical Underwood

  6. Minimum Energy Consumption in Multicomponent Distillation. 3. More Than Three Products and Generalized Petlyuk Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Minimum Energy Consumption in Multicomponent Distillation. 3. More Than Three Products-component feed into M products has been derived. Interestingly, the minimum-energy solution in a complex solution of minimum energy for distillation of a multicomponent feed into multiple products has not been

  7. Study of the Distillability of Werner States Using Entanglement Witnesses and Robust Semidefinite Programs

    E-Print Network [OSTI]

    Reinaldo O. Vianna; Andrew C. Doherty

    2006-08-11T23:59:59.000Z

    We use Robust Semidefinite Programs and Entanglement Witnesses to study the distillability of Werner states. We perform exact numerical calculations which show 2-undistillability in a region of the state space which was previously conjectured to be undistillable. We also introduce bases which yield interesting expressions for the {\\em distillability witnesses} and for a tensor product of Werner states with arbitrary number of copies.

  8. Optimal operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Optimal operation of a Petlyuk Distillation Column: Energy Savings by Over-fractionation · The Petlyuk distillation column, see Figure 1(a), with a pre-fractionator (C1) and a main column (C21 and C22) N-7465 Trondheim, Norway Abstract This work shows the unexpected result that over-fractionating one

  9. Distillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Grak (Editors)

    E-Print Network [OSTI]

    Skogestad, Sigurd

    coupling 1. Introduction Separation by distillation is responsible for a large fraction of immense amountDistillation Absorption 2010 A.B. de Haan, H. Kooijman and A. Górak (Editors) All rights reserved indicated that a 15 component aromatic's mixture can be separated very efficiently into four fractions

  10. Optimization of Distillation Processes. Jos A. Caballero* and Ignacio E. Grossmann**

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    that handle more than 90% of separations and purifications. The capital investment for these distillation.87 million TJ) per year, or to a power consumption of 91 GW, or 54 million tons of crude oil. Distillation conditions to minimize the total investment and operating cost. Continuous decisions are related

  11. Hanford tank residual waste – contaminant source terms and release models

    SciTech Connect (OSTI)

    Deutsch, William J.; Cantrell, Kirk J.; Krupka, Kenneth M.; Lindberg, Michael J.; Serne, R. Jeffrey

    2011-08-23T23:59:59.000Z

    Residual waste is expected to be left in 177 underground storage tanks after closure at the U.S. Department of Energy’s Hanford Site in Washington State (USA). In the long term, the residual wastes represent a potential source of contamination to the subsurface environment. Residual materials that cannot be completely removed during the tank closure process are being studied to identify and characterize the solid phases and estimate the release of contaminants from these solids to water that might enter the closed tanks in the future. As of the end of 2009, residual waste from five tanks has been evaluated. Residual wastes from adjacent tanks C-202 and C-203 have high U concentrations of 24 and 59 wt%, respectively, while residual wastes from nearby tanks C-103 and C-106 have low U concentrations of 0.4 and 0.03 wt%, respectively. Aluminum concentrations are high (8.2 to 29.1 wt%) in some tanks (C-103, C-106, and S-112) and relatively low (<1.5 wt%) in other tanks (C-202 and C-203). Gibbsite is a common mineral in tanks with high Al concentrations, while non-crystalline U-Na-C-O-P±H phases are common in the U-rich residual wastes from tanks C-202 and C-203. Iron oxides/hydroxides have been identified in all residual waste samples studied to date. Contaminant release from the residual wastes was studied by conducting batch leach tests using distilled deionized water, a Ca(OH)2-saturated solution, or a CaCO3-saturated water. Uranium release concentrations are highly dependent on waste and leachant compositions with dissolved U concentrations one or two orders of magnitude higher in the tests with high U residual wastes, and also higher when leached with the CaCO3-saturated solution than with the Ca(OH)2-saturated solution. Technetium leachability is not as strongly dependent on the concentration of Tc in the waste, and it appears to be slightly more leachable by the Ca(OH)2-saturated solution than by the CaCO3-saturated solution. In general, Tc is much less leachable (<10 wt% of the available mass in the waste) than previously predicted. This may be due to the coprecipitation of trace concentrations of Tc in relatively insoluble phases such as Fe oxide/hydroxide solids.

  12. Distillation sequence for the purification and recovery of hydrocarbons

    DOE Patents [OSTI]

    Reyneke, Rian (Katy, TX); Foral, Michael (Aurora, IL); Papadopoulos, Christos G. (Naperville, IL); Logsdon, Jeffrey S. (Naperville, IL); Eng, Wayne W. Y. (League City, TX); Lee, Guang-Chung (Houston, TX); Sinclair, Ian (Warrington, GB)

    2007-12-25T23:59:59.000Z

    This invention is an improved distillation sequence for the separation and purification of ethylene from a cracked gas. A hydrocarbon feed enters a C2 distributor column. The top of the C2 distributor column is thermally coupled to an ethylene distributor column, and the bottoms liquid of a C2 distributor column feeds a deethanizer column. The C2 distributor column utilizes a conventional reboiler. The top of the ethylene distributor is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor feeds a C2 splitter column. The ethylene distributor column utilizes a conventional reboiler. The deethanizer and C2 splitter columns are also thermally coupled and operated at a substantially lower pressure than the C2 distributor column, the ethylene distributor column, and the demethanizer column. Alternatively, a hydrocarbon feed enters a deethanizer column. The top of the deethanizer is thermally coupled to an ethylene distributor column, and the ethylene distributor column utilizes a conventional reboiler. The top of the ethylene distributor column is thermally coupled with a demethanizer column, and the bottoms liquid of the ethylene distributor column feeds a C2 splitter column. The C2 splitter column operates at a pressure substantially lower than the ethylene distributor column, the demethanizer column, and the deethanizer column.

  13. Simple rules help select best hydrocarbon distillation scheme

    SciTech Connect (OSTI)

    Sanchezllanes, M.T.; Perez, A.L.; Martinez, M.P.; Aguilar-Rodriguez, E.; Rosal, R. del (Inst. Mexicano del Petroleo, Mexico City (Mexico))

    1993-12-06T23:59:59.000Z

    Separation economics depend mainly on investment for major equipment and energy consumption. This relationship, together with the fact that, in most cases, many alternative schemes will be proposed, make it essential to find an optimum scheme that minimizes overall costs. Practical solutions are found by applying heuristics -- exploratory problem-solving techniques that eliminate alternatives without applying rigorous mathematical procedures. These techniques have been applied to a case study. In the case study, a hydrocarbon mixture will be transported through a pipeline to a fractionation plant, where it will be separated into commercial products for distribution. The fractionation will consist of a simple train of distillation columns, the sequence of which will be defined by applying heuristic rules and determining the required thermal duties for each column. The facility must separate ethane, propane and mixed butanes, natural gasoline (light straight-run, or LSR, gasoline), and condensate (heavy naphtha). The ethane will be delivered to an ethylene plant as a gaseous stream, the propane and butanes will be stored in cryogenic tanks, and the gasoline and heavy naphtha also will be stored.

  14. Water distillation using waste engine heat from an internal combustion engine

    E-Print Network [OSTI]

    Mears, Kevin S

    2006-01-01T23:59:59.000Z

    To meet the needs of forward deployed soldiers and disaster relief personnel, a mobile water distillation system was designed and tested. This system uses waste engine heat from the exhaust flow of an internal combustion ...

  15. Feeding Value of Wet Sorghum Distillers Grains for Growing and Finishing Beef Cattle

    E-Print Network [OSTI]

    Feeding Value of Wet Sorghum Distillers Grains for Growing and Finishing Beef Cattle Ethanol, but sorghum grain is commonly either blended with corn before use or used as the sole grain for ethanol

  16. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    132.9 1,418.3 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  17. Table 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil...

    Gasoline and Diesel Fuel Update (EIA)

    839.2 135.0 1,251.9 See footnotes at end of table. 46. Refiner No. 2 Distillate, Diesel Fuel, and Fuel Oil Volumes by PAD District and State Energy Information Administration ...

  18. Overview of used antifreeze and industrial glycol recycling by vacuum distillation

    SciTech Connect (OSTI)

    Frye, D.K. [Filter Recovery Services, Alexandria, VA (United States); Chan, K.; Pourhassanian, C. [DeMenno/Kerdoon, Inc., Compton, CA (United States)

    1999-08-01T23:59:59.000Z

    A leading method of reclaiming ethylene glycol from both used automotive coolants and waste industrial glycol streams is vacuum distillation. Over 15 million gallons per year of total glycols are recovered by this technology, which are marketed for use in antifreeze and industrial chemicals. It is a robust technology, tolerant of many common feed contaminants, and producing minimum waste. This paper presents an overview of vacuum distillation as one part of a multistep process for recovering glycols from a wide variety of feedstreams. Described are industry practices for laboratory prescreening of feedstreams, process adjustments and pretreatments, distillation technologies and post-distillation polishing methods. In each section, information and data are presented from two independent facilities and for several streams processed at each facility. It is concluded that the facilities participating in this study can reliably produce ethylene glycol suitable for the production of ASTM specification engine coolants.

  19. The Scaleup of Structured Packing from Distillation Pilot Plant Testing to Commercial Application

    E-Print Network [OSTI]

    Berven, O. J.; Ulowetz, M. A.

    fractionator was performed, it was necessary to inventory the column with feed and, under total reflux conditions, draw off distillate or bottoms product until the proper composition profile was achieved. To investigate various design options, both... stream by a factor of five. In summary, from the customer's point of view, the application of structured packing to the main fractionator in the SFP fractionation train is a cOOluercial success. NEW DISTILLATION DEVELOPMENT PILOT PLANT Since...

  20. Experimental and analytical studies of hydrocarbon yields under dry-, steam-, and steam-with-propane distillation

    E-Print Network [OSTI]

    Jaiswal, Namit

    2007-09-17T23:59:59.000Z

    EXPERIMENTAL AND ANALYTICAL STUDIES OF HYDROCARBON YIELDS UNDER DRY-, STEAM-, AND STEAM-WITH- PROPANE DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University...-WITH- PROPANE-DISTILLATION A Dissertation by NAMIT JAISWAL Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved...

  1. PILOT-SCALE REMOVAL OF FLUORIDE FROM LEGACY PLUTONIUM MATERIALS USING VACUUM SALT DISTILLATION

    SciTech Connect (OSTI)

    Pierce, R. A.; Pak, D. J.

    2012-09-11T23:59:59.000Z

    Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000{deg}C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition.

  2. Distribution of higher n-alkanes in partially frozen middle-distillate fuels. Final report, October 1982-September 1984

    SciTech Connect (OSTI)

    Van Winkle, T.L.; Affens, W.A.; Beal, E.J.; Hazlett, R.N.; DeGuzman, J.

    1985-04-10T23:59:59.000Z

    In conjunction with continuing studies on the effect of composition on the freezing points of middle distillate fuels, attention was directed to partially frozen fuels. The crystals and residual liquid from partially frozen JP-5 and DFM fuel samples derived from both petroleum and shale were separated from each other and collected by means of the NRL liquid-solid separator apparatus (LSS) at several temperatures below the freezing points of the original samples. The original fuel samples, the solid material (precipitate), and liquid (filtrate) were characterized by gas chromatography (GC). The filtrate data were straightforward. As expected, Van't Hoff plot of the n-alkanes concentrations (log concentrations vs reciprocal absolute temperature) formed straight lines, and their slopes demonstrated the importance of the higher n-alkanes in fuel crystallization at cold temperatures. The precipitate data presented some problems of interpretation since it was observed that the waxy crystal precipitate matrix entrapped significant amounts of liquid (filtrate). The data on solid which were obtained by these methods demonstrated that the higher n-alkanes play the key role in fuel crystallization at low temperatures, concentrating as much as tenfold in the crystallized solids compared to the liquid. Also, it was clearly shown that the n-alkanes form the major part, up to least 95% by weight in some fuels, of the solid crystals formed.

  3. Residuals, Sludge, and Composting (Maine)

    Broader source: Energy.gov [DOE]

    The Maine Department of Environmental Protection's Residuals, Sludge, and Composting program regulates the land application and post-processing of organic wastes, including sewage sludge, septage,...

  4. The cough response to ultrasonically nebulized distilled water in heart-lung transplantation patients

    SciTech Connect (OSTI)

    Higenbottam, T.; Jackson, M.; Woolman, P.; Lowry, R.; Wallwork, J.

    1989-07-01T23:59:59.000Z

    As a result of clinical heart-lung transplantation, the lungs are denervated below the level of the tracheal anastomosis. It has been questioned whether afferent vagal reinnervation occurs after surgery. Here we report the cough frequency, during inhalation of ultrasonically nebulized distilled water, of 15 heart-lung transplant patients studied 6 wk to 36 months after surgery. They were compared with 15 normal subjects of a similar age and sex. The distribution of the aerosol was studied in five normal subjects using /sup 99m/technetium diethylene triamine pentaacetate (/sup 99m/Tc-DTPA) in saline. In seven patients, the sensitivity of the laryngeal mucosa to instilled distilled water (0.2 ml) was tested at the time of fiberoptic bronchoscopy by recording the cough response. Ten percent of the aerosol was deposited onto the larynx and trachea, 56% on the central airways, and 34% in the periphery of the lung. The cough response to the aerosol was strikingly diminished in the patients compared with normal subjects (p less than 0.001), but all seven patients coughed when distilled water was instilled onto the larynx. As expected, the laryngeal mucosa of heart-lung transplant patients remains sensitive to distilled water. However, the diminished coughing when the distilled water is distributed by aerosol to the central airways supports the view that vagal afferent nerves do not reinnervate the lungs after heart-lung transplantation, up to 36 months after surgery.

  5. Source book for planning nuclear dual-purpose electric/distillation desalination plants

    SciTech Connect (OSTI)

    Reed, S.A.

    1981-02-01T23:59:59.000Z

    A source book on nuclear dual-purpose electric/distillation desalination plants was prepared to assist government and other planners in preparing broad evaluations of proposed applications of dual-purpose plants. The document is divided into five major sections. Section 1 presents general discussions relating to the benefits of dual-purpose plants, and spectrum for water-to-power ratios. Section 2 presents information on commercial nuclear plants manufactured by US manufacturers. Section 3 gives information on distillation desalting processes and equipment. Section 4 presents a discussion on feedwater pretreatment and scale control. Section 5 deals with methods for coupling the distillation and electrical generating plants to operate in the dual mode.

  6. Characteristics of naphthenic and paraffinic hydrocarbons of residual oil from West Siberian crudes

    SciTech Connect (OSTI)

    Detusheva, E.P.; Khramtsova, L.P.; Muchinskii, T.D.; Shkol'nikov, V.M.

    1984-05-01T23:59:59.000Z

    This article examines the naphthenic/paraffinic hydrocarbons segregated by liquid chromatography from a residual oil after removal of the resins and solid hydrocarbons. The studied hydrocarbons were fractionated on the basis of molecular weight (by molecular distillation) and on the basis of the content of rings (by thermal diffusion separation in a laboratory column). The results of mass-spectrometric analysis indicate that the first fraction consists mainly of isoparaffins and naphthenes with few rings. The polycyclic condensed naphthenes are concentrated in the last fraction. The content of isoparaffins drops off and the content of condensed polycyclic naphthenic structures increases from the second fraction to the next to the last. It is concluded that the naphthenic/paraffinic hydrocarbons of the residual oil from mixed West Siberian crudes have a relatively narrow composition and therefore have similar physicochemical properties.

  7. The Products of the Destructive Distillation of Keratin in the Form of Leather

    E-Print Network [OSTI]

    Rose, Reed Phillips

    1913-01-01T23:59:59.000Z

    ure to the air. After this came a white crystal­ line solid, fourth a reddish fciquid, fifth a red­ dish crystalline compound and sixth the black oil spoken of abovd. A volume of the distillate, equaling about a liter was collected and the two... the material the temperature rose to 200° C. and then reduction started and the temperature fell rapidly. The tar or oil constitutes from 3 to 4 per cent of the weight of the leather used. The aqueous portion of the distillate was subjected to a fractional...

  8. Process for converting heavy oil deposited on coal to distillable oil in a low severity process

    DOE Patents [OSTI]

    Ignasiak, Teresa (417 Heffernan Drive, Edmonton, Alberta, CA); Strausz, Otto (13119 Grand View Drive, Edmonton, Alberta, CA); Ignasiak, Boleslaw (417 heffernan Drive, Edmonton, Alberta, CA); Janiak, Jerzy (17820 - 76 Ave., Edmonton, Alberta, CA); Pawlak, Wanda (3046 - 11465 - 41 Avenue, Edmonton, Alberta, CA); Szymocha, Kazimierz (3125 - 109 Street, Edmonton, Alberta, CA); Turak, Ali A. (Edmonton, CA)

    1994-01-01T23:59:59.000Z

    A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

  9. Efficient use of an intermediate reboiler or condenser in a binary distillation

    SciTech Connect (OSTI)

    Agrawal, R.; Herron, D.M. [Air Products and Chemicals, Inc., Allentown, PA (United States)] [Air Products and Chemicals, Inc., Allentown, PA (United States)

    1998-06-01T23:59:59.000Z

    The impact of an intermediate reboiler or condenser on the distillation of ideal binary mixtures into pure product streams is studied using a simplified model. The advantage of heuristics derived from this study is that they can quickly tell a process engineer if an intermediate reboiler or condenser is going to be effective in improving the efficiency and, of the two options, which one would be more effective. The heuristics simply states that if the actual fraction of liquid in a given feed is less than that with the maximum thermodynamic efficiency for distillation with no intermediate reboiler or condenser, then an intermediate condenser not only substantially improves the thermodynamic efficiency but is also more effective than an intermediate reboiler. An analogous heuristics exists for the intermediate reboiler when the fraction of liquid in the feed is greater than the optimum. Quick identification of cases that can achieve a substantial improvement in efficiency provides an incentive to search for the proper utilities needed for the intermediate reboiler or condenser. When relatively pure feed streams (concentration of either component greater than 90%) are distilled, the extremely low efficiencies of distillation can be remarkably improved by using an intermediate reboiler or condenser.

  10. Integrated Column Designs for Minimum Energy and Entropy Requirements in Multicomponent Distillation

    E-Print Network [OSTI]

    Skogestad, Sigurd

    prefer a process where the energy may be supplied at a low temperature and cooling may be supplied law). This leads us to the reversible Petlyuk arrangement. However the total required heat supply). A characteristic of the reversible distillation column is that some of the heat is supplied continuously along

  11. Middle distillate hydrotreatment zeolite catalysts containing Pt/Pd or Ni

    E-Print Network [OSTI]

    Marin-Rosas, Celia

    2009-05-15T23:59:59.000Z

    A study on middle distillate hydrotreatment zeolite catalysts containing Pt/Pd and/or Ni was performed. The effect of the addition of the corresponding CoMo, CoMoPd, CoMoPtPd and CoMoNi in PdNiPt-zeolite, Pt-zeolite, Ni-zeolite, and Pd...

  12. UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates*

    E-Print Network [OSTI]

    Asher, Sanford A.

    UV Resonance Raman Characterization of Polycyclic Aromatic Hydrocarbons in Coal Liquid Distillates samples, such as petroleum and coal, or for man-made samples, such as coal liquids, a major desire- nique for studying coal-liquid samples. 1-4 We demon- strated that the Raman spectra of polycyclic

  13. Distillate fuel-oil processing for phosphoric acid fuel-cell power plants

    SciTech Connect (OSTI)

    Ushiba, K. K.

    1980-02-01T23:59:59.000Z

    The current efforts to develop distillate oil-steam reforming processes are reviewed, and the applicability of these processes for integration with the fuel cell are discussed. The development efforts can be grouped into the following processing approaches: high-temperature steam reforming (HTSR); autothermal reforming (ATR); autothermal gasification (AG); and ultra desulfurization followed by steam reforming. Sulfur in the feed is a key problem in the process development. A majority of the developers consider sulfur as an unavoidable contaminant of distillate fuel and are aiming to cope with it by making the process sulfur-tolerant. In the HTSR development, the calcium aluminate catalyst developed by Toyo Engineering represents the state of the art. United Technology (UTC), Engelhard, and Jet Propulsion Laboratory (JPL) are also involved in the HTSR research. The ATR of distillate fuel is investigated by UTC and JPL. The autothermal gasification (AG) of distillate fuel is being investigated by Engelhard and Siemens AG. As in the ATR, the fuel is catalytically gasified utilizing the heat generated by in situ partial combustion of feed, however, the goal of the AG is to accomplish the initial breakdown of the feed into light gases and not to achieve complete conversion to CO and H/sub 2/. For the fuel-cell integration, a secondary reforming of the light gases from the AG step is required. Engelhard is currently testing a system in which the effluent from the AG section enters the steam-reforming section, all housed in a single vessel. (WHK)

  14. Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements

    E-Print Network [OSTI]

    Skogestad, Sigurd

    1 Graphical Visualisation of Minimum Energy Requirements for Multi-Effect Distillation Arrangements of this paper is to present a simple graphical method for obtaining the energy usage and to compare the energy of Chemical Engineering, 7491 Trondheim, Norway Abstract The minimum energy requirements of six different heat

  15. Hybrid magic state distillation for universal fault-tolerant quantum computation

    E-Print Network [OSTI]

    Wenqiang Zheng; Yafei Yu; Jian Pan; Jingfu Zhang; Jun Li; Zhaokai Li; Dieter Suter; Xianyi Zhou; Xinhua Peng; Jiangfeng Du

    2014-12-11T23:59:59.000Z

    A set of stabilizer operations augmented by some special initial states known as 'magic states', gives the possibility of universal fault-tolerant quantum computation. However, magic state preparation inevitably involves nonideal operations that introduce noise. The most common method to eliminate the noise is magic state distillation (MSD) by stabilizer operations. Here we propose a hybrid MSD protocol by connecting a four-qubit H-type MSD with a five-qubit T-type MSD, in order to overcome some disadvantages of the previous MSD protocols. The hybrid MSD protocol further integrates distillable ranges of different existing MSD protocols and extends the T-type distillable range to the stabilizer octahedron edges. And it provides considerable improvement in qubit cost for almost all of the distillable range. Moreover, we experimentally demonstrate the four-qubit H-type MSD protocol using nuclear magnetic resonance technology, together with the previous five-qubit MSD experiment, to show the feasibility of the hybrid MSD protocol.

  16. Effect of Narrow Cut Oil Shale Distillates on HCCI Engine Performance

    SciTech Connect (OSTI)

    Eaton, Scott J [ORNL; Bunting, Bruce G [ORNL; Lewis Sr, Samuel Arthur [ORNL; Fairbridge, Craig [National Centre for Upgrading Technology, Canada

    2009-01-01T23:59:59.000Z

    In this investigation, oil shale crude obtained from the Green River Formation in Colorado using Paraho Direct retorting was mildly hydrotreated and distilled to produce 7 narrow boiling point fuels of equal volumes. The resulting derived cetane numbers ranged between 38.3 and 43.9. Fuel chemistry and bulk properties strongly correlated with boiling point.

  17. Black-Box Identification for PLC based MPC of a Binary Distillation Column

    E-Print Network [OSTI]

    Black-Box Identification for PLC based MPC of a Binary Distillation Column B. Huyck ,, F. Logist J is to upgrade the control system with a linear MPC running on a PLC. However, before a model based controller can be used on a PLC, an accurate (but simple) process model has to be constructed. Hence, the aim

  18. HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT

    E-Print Network [OSTI]

    Titov, Anatoly

    321 HYDROGEN DISTILLATION AT THE DEUTERIUM REMOVAL UNIT OF MuCap EXPERIMENT I.A. Alekseev, E hydrogen gas (so- called protium) must be used. It is necessary to avoid transfers of - to impurities imposes strict and critical requirements on the hydrogen gas system supporting the detector. Desirable

  19. Chemical Characterization of Individual Particles and Residuals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Individual Particles and Residuals of Cloud Droplets and Ice Crystals Collected On Board Research Chemical Characterization of Individual Particles and Residuals of Cloud Droplets...

  20. DISSOLUTION OF NEPTUNIUM OXIDE RESIDUES

    SciTech Connect (OSTI)

    Kyser, E

    2009-01-12T23:59:59.000Z

    This report describes the development of a dissolution flowsheet for neptunium (Np) oxide (NpO{sub 2}) residues (i.e., various NpO{sub 2} sources, HB-Line glovebox sweepings, and Savannah River National Laboratory (SRNL) thermogravimetric analysis samples). Samples of each type of materials proposed for processing were dissolved in a closed laboratory apparatus and the rate and total quantity of off-gas were measured. Samples of the off-gas were also analyzed. The quantity and type of solids remaining (when visible) were determined after post-dissolution filtration of the solution. Recommended conditions for dissolution of the NpO{sub 2} residues are: Solution Matrix and Loading: {approx}50 g Np/L (750 g Np in 15 L of dissolver solution), using 8 M nitric acid (HNO{sub 3}), 0.025 M potassium fluoride (KF) at greater than 100 C for at least 3 hours. Off-gas: Analysis of the off-gas indicated nitric oxide (NO), nitrogen dioxide (NO{sub 2}) and nitrous oxide (N{sub 2}O) as the only identified components. No hydrogen (H{sub 2}) was detected. The molar ratio of off-gas produced per mole of Np dissolved ranged from 0.25 to 0.4 moles of gas per mole of Np dissolved. A peak off-gas rate of {approx}0.1 scfm/kg bulk oxide was observed. Residual Solids: Pure NpO{sub 2} dissolved with little or no residue with the proposed flowsheet but the NpCo and both sweepings samples left visible solid residue after dissolution. For the NpCo and Part II Sweepings samples the residue amounted to {approx}1% of the initial material, but for the Part I Sweepings sample, the residue amounted to {approx}8 % of the initial material. These residues contained primarily aluminum (Al) and silicon (Si) compounds that did not completely dissolve under the flowsheet conditions. The residues from both sweepings samples contained minor amounts of plutonium (Pu) particles. Overall, the undissolved Np and Pu particles in the residues were a very small fraction of the total solids.

  1. APPLICATION OF VACUUM SALT DISTILLATION TECHNOLOGY FOR THE REMOVAL OF FLUORIDE

    SciTech Connect (OSTI)

    Pierce, R.; Pak, D.

    2011-08-10T23:59:59.000Z

    Vacuum distillation of chloride salts from plutonium oxide (PuO{sub 2}) and simulant PuO{sub 2} has been previously demonstrated at Department of Energy (DOE) sites using kilogram quantities of chloride salt. The apparatus for vacuum distillation contains a zone heated using a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attained, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile materials in the feed boat. The application of vacuum salt distillation (VSD) is of interest to the HB-Line Facility and the MOX Fuel Fabrication Facility (MFFF) at the Savannah River Site (SRS). Both facilities are involved in efforts to disposition excess fissile materials. Many of these materials contain chloride and fluoride salt concentrations which make them unsuitable for dissolution without prior removal of the chloride and fluoride salts. Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. Subsequent efforts are attempting to adapt the technology for the removal of fluoride. Fluoride salts of interest are less-volatile than the corresponding chloride salts. Consequently, an alternate approach is required for the removal of fluoride without significantly increasing the operating temperature. HB-Line Engineering requested SRNL to evaluate and demonstrate the feasibility of an alternate approach using both non-radioactive simulants and plutonium-bearing materials. Whereas the earlier developments targeted the removal of sodium chloride (NaCl) and potassium chloride (KCl), the current activities are concerned with the removal of the halide ions associated with plutonium trifluoride (PuF{sub 3}), plutonium tetrafluoride (PuF{sub 4}), calcium fluoride (CaF{sub 2}), and calcium chloride (CaCl{sub 2}). This report discusses non-radioactive testing of small-scale and pilot-scale systems and radioactive testing of a small-scale system. Experiments focused on demonstrating the chemistry for halide removal and addressing the primary engineering questions associated with a change in the process chemistry.

  2. Future perspectives of using hollow fibers as structured packings in light hydrocarbon distillation

    SciTech Connect (OSTI)

    Yang, Dali [Los Alamos National Laboratory; Orler, Bruce [Los Alamos National Laboratory; Tornga, Stephanie [Los Alamos National Laboratory; Welch, Cindy [Los Alamos National Laboratory

    2011-01-26T23:59:59.000Z

    Olefin and paraffin are the largest chemical commodities. Furthermore, they are major building blocks for the petrochemical industry. Each year, petroleum refining, consumes 4,500 TBtu/yr in separation energy, making it one of the most energy-intensive industries in the United States). Just considering liquefied petroleum gas (ethane/propane/butane) and olefins (ethylene and propylene) alone, the distillation energy consumption is about 400 TBtu/yr in the US. Since petroleum distillation is a mature technology, incremental improvements in column/tray design will only provide a few percent improvements in the performance. However, each percent saving in net energy use amounts to savings of 10 TBtu/yr and reduces CO{sub 2} emissions by 0.2 MTon/yr. In practice, distillation columns require 100 to 200 trays to achieve the desired separation. The height of a transfer unit (HTU) of conventional packings is typical in the range of 36-60 inch. Since 2006, we had explored using several non-selective membranes as the structured packings to replace the conventional packing materials used in propane and propylene distillation. We obtained the lowest HTU of < 8 inch for the hollow fiber column, which was >5 times shorter than that of the conventional packing materials. In 2008, we also investigated this type of packing materials in iso-/n-butane distillation. Because of a slightly larger relative volatility of iso-/n-butane than that of propane/propylene, a wider and a more stable operational range was obtained for the iso-/n-butane pair. However, all of the experiments were conducted on a small scale with flowrate of < 25 gram/min. Recently, we demonstrated this technology on a larger scale (<250 gram/min). Within the loading range of F-factor < 2.2 Pa{sup 0.5}, a pressure drop on the vapor side is below 50 mbar/m, which suggests that the pressure drop of hollow fibers packings is not an engineering barrier for the applications in distillations. The thermal stability study suggests that polypropylene hollow fibers are stable after a long time exposure to C{sub 2} - C{sub 4} mixtures. The effects of packing density on the separation efficiency will be discussed.

  3. Structural group analysis of residues from Athabasca bitumen

    SciTech Connect (OSTI)

    Gray, M.R.; Choi, J.H.K.; Egiebor, N.O.; Kirchen, R.P.; Sanford, E.C.

    1988-06-01T23:59:59.000Z

    Non-distillable fractions of hydrocarbons such as bitumen are a challenge for analysis because of their molecular complexity and high heteroatom content. One method for characterizing their composition is by analysis for a relatively small number of structures expected to predominate in the mixture, i.e. for the significant structural groups. Because NMR spectroscopy can give quantitative data on the distribution of hydrogen and carbon types, it is an ideal method for group-based analysis. This study uses a structural group formalism which combines data from several analytical methods into a single profile. Residue fractions derived from Athabasca bitumen were investigated to determine the different chemical structures which could have an impact on subsequent processing. Structural analysis is the identification of key structures from analytical data that characterize a complex mixture. Higher accuracy data, from elemental, /sup 1/H-NMR, IR and titration analyses, are used to construct balance equations which must be satisfied. The spectral envelope of /sup 13/C-NMR is more difficult to resolve quantatitively, and hence /sup 13/C-NMR data are used as constraints to compute the concentrations of structural groups. The mathematical notation and methods have been presented previously. The structural analysis transforms the spectrometric data into a more useable form; the maximum number of groups that can be calculated is limited to the number of useful analytical measurements.

  4. Interactive chemical effects and instability of shale derived middle distillate fuels

    SciTech Connect (OSTI)

    Mushrush, G.W.; Beal, E.J.; Watkins, J.M.; Morris, R.E.; Hardy, D.R. (Fuels Section, Naval Research Lab., Washington, DC (US))

    1989-01-01T23:59:59.000Z

    This paper presents a study of instability of shale-derived fuels. Changes in fuel properties with time have been a continuing problem in the use of middle distillate fuels. The authors define instability as the formation of insoluble sediments and gums as well as the production of peroxides and color bodies. Nitrogen and sulfur heterocycles have long been implicated in fuel degradation, but present knowledge is limited regarding the chemistry of their autoxidation reactions in the complex fuel media. Based on the GC/MS identification of nitrogen heterocyclic constituents in several shale-derived middle distillate fuels, the authors have conducted gravimetric instability tests employing three model nitrogen heterocycles in shale-derived diesel fuels. Model sulfur compound dopant studies on shale-derived jet fuels were conducted by monitoring hydroperoxide formation/decomposition and the decreased quantity of sulfur compound. Potential interactive effects have been defined for these model dopants.

  5. The distribution of n-alkanes in partially frozen middle distillate fuels

    SciTech Connect (OSTI)

    Van Winkle, T.L.; Affens, W.A.; Beal, E.J.; Hazlett, R.N.; Guzman, J.

    1986-04-01T23:59:59.000Z

    This work on partially frozen fuels is one of a continuing series of studies on the effect of composition on the freezing properties of hydrocarbon fuels. The method used for this purpose was reported previously. By means of this method the authors were able to determine the composition of the liquid and solid phases in partially frozen mixtures consisting of liquid and of solid crystals plus entrapped liquid. This paper presents the results of this study on five different middle distillate fuels.

  6. Energy Savings Accomplished by Replacing Steam Ejectors with Electric Driven Vacuum Pumps in Crude Distillation Vacuum Towers

    E-Print Network [OSTI]

    Nelson, R. E.

    1982-01-01T23:59:59.000Z

    The low cost of steam combined with the maintenance free operation of steam ejectors has assured their unquestioned use in providing the necessary vacuum for crude distillation vacuum towers. However, the cost of steam production has risen...

  7. Hydrogenation of aromatics in synthetic crude distillates catalyzed by platinum supported in molecular sieves

    SciTech Connect (OSTI)

    Kimbara, N.; Charland, J.P. [CANMET, Ottawa, Ontario (Canada)] [CANMET, Ottawa, Ontario (Canada); Wilson, M.F. [CANMET, Devon, Alberta (Canada)] [CANMET, Devon, Alberta (Canada)

    1996-11-01T23:59:59.000Z

    Catalytic hydrogenation of synthetic crude distillates from Canadian oil sands was carried out over platinum metal supported in pillared interlayered clay (PILC) and Y-zeolite. The molecular sieve supports were employed to modify the properties of dispersed platinum particles and improve their resistance to poisoning by sulfur. The objective was to reduce the distillate aromatic content to meet diesel emission control standards and cetane number requirements. Catalysts were prepared in a series of steps, and metal precursor was loaded using ion-exchange procedures. Characterization was done using X-ray diffraction, hydrogen chemisorption, and proton-induced X-ray emission elemental analysis. Catalytic hydrogenation reactions were carried out by processing distillate feedstocks both high (>100 ppm) and low (<10 ppm) in sulfur using a continuous-flow automated microreactor system. Experimental runs were performed to determine the reaction kinetics and Arrhenius parameters as a means of evaluating and comparing catalyst performance. Significant differences in catalyst activity were found. The Pt/Y-zeolite-alumina catalyst showed a much superior hydrogenation performance under conditions of high sulfur content. The extent of cracking and ring opening was also evaluated and was shown to be minimal under the operating conditions employed.

  8. Magnetocaloric properties of distilled gadolinium: Effects of structural inhomogeneity and hydrogen impurity

    SciTech Connect (OSTI)

    Burkhanov, G. S.; Kolchugina, N. B.; Chzhan, V. B.; Chistyakov, O. D. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); Tereshina, E. A. [Institute of Physics ASCR, 18221 Prague (Czech Republic); Tereshina, I. S. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); International Laboratory of High Magnetic Fields and Low Temperatures PAS, 53-421 Wroclaw (Poland); Faculty of Physics, Lomonosov Moscow State University, 119991 Moscow (Russian Federation); Politova, G. A. [Baikov Institute of Metallurgy and Materials Science RAS, 119991 Moscow (Russian Federation); International Laboratory of High Magnetic Fields and Low Temperatures PAS, 53-421 Wroclaw (Poland); Badurski, D.; Drulis, H. [Institute of Low Temperature and Structure Research PAS, 50-950 Wroclaw (Poland); Paukov, M.; Havela, L. [Department of Condensed Matter Physics, Faculty of Mathematics and Physics, Charles University, 12116 Prague (Czech Republic)

    2014-06-16T23:59:59.000Z

    High-purity Gd prepared by distillation is a structurally inhomogeneous system consisting of needle-shaped crystals of cross section 0.5–2.5??m with near-c-axis orientation embedded in a matrix of nanosized (30–100?nm) grains. By measuring the magnetocaloric effect (MCE) directly, we find that the MCE values differ markedly for the plate-shaped samples cut out of a distillate along and perpendicular to the crystals. The effect of small controlled amounts of impurity (hydrogen) on the properties of distilled Gd is further studied. We observe opposite trends in the MCE response to hydrogen charging with respect to the crystal's orientation within the samples and discuss mechanisms interrelating the unique structural morphology with the impurity behavior. As an overall assessment, the Curie temperatures of ?-GdH{sub x} solid solutions increase from 291?K up to 294?K when increasing hydrogen concentration x from 0 to 0.15. Hydrogenation is found to broaden the ferromagnetic-to-paramagnetic phase transition. Hydrogen-containing specimens demonstrate reversibility of MCE at these temperatures.

  9. A novel proportional--integral-derivative control configuration with application to the control of batch distillation

    SciTech Connect (OSTI)

    Alvarez-Ramirez, J.; Monroy-Loperena, R.; Cervantes, I.; Morales, A.

    2000-02-01T23:59:59.000Z

    The aim of this paper is to propose a novel proportional-integral-derivative (PID) control configuration based on an observer structure. Batch distillation is used as the base case study where the regulated output is the distillate composition. The proposed PID control law is derived in the framework of robust nonlinear control with modeling error compensation techniques. A reduced-order observer is proposed to estimate both the derivative of the regulated output and the underlying modeling error. These observations are subsequently used in a control loop to feedback variations of distillate composition (derivative feedback) and to counteract the effects of modeling errors. It is shown that, under certain conditions, the resulting control law is equivalent to a classical PID controller with an antireset windup scheme. Moreover, the tuning of the controller is performed very easily in terms of a prescribed closed-loop time constant and an estimation time constant. Numerical results are provided for binary and multicomponent separations. Sampled/delayed measurements and several sources of uncertainties are considered in order to provide a realistic test scenario for the proposed control design procedure.

  10. Copolymers useful as additives for lowering the cloud point of middle hydrocarbon distillates, and compositions of middle hydrocarbon distillates comprising them

    SciTech Connect (OSTI)

    Durand, J. P.; Damin, B.; Dawans, F.; Leger, R.

    1985-03-05T23:59:59.000Z

    Products useful as additives for lowering the cloud point of middle distillates have a molecular weight from 1,000 to 50,000, and are obtained by reacting a compound of the formula R-Z((CH/sub 2/) /SUB n/ NH) /SUB m/ H or HO-CH/sub 2/-R'-NH/sub 2/ where R is a monovalent saturated aliphatic radical of 1-30 carbon atoms, Z is -NH- or oxygen, n is 2 to 4, m is zero or 1 to 4 and R' is a saturated divalent aliphatic radical of 1-18 carbon atoms, with a copolymer comprising recurrent units (A) from an alkyl ester of an unsaturated monocarboxylic acid and/or a vinyl ester of a saturated monocarboxylic acid, recurrent units (B) from diisobutylene and recurrent units (C) from an unsaturated a,b-dicarboxylic compound.

  11. Transforms for prediction residuals in video coding

    E-Print Network [OSTI]

    Kam??l?, Fatih

    2010-01-01T23:59:59.000Z

    Typically the same transform, the 2-D Discrete Cosine Transform (DCT), is used to compress both image intensities in image coding and prediction residuals in video coding. Major prediction residuals include the motion ...

  12. Vacuum Distillation

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines About U.S. NaturalA. Michael SchaalNovember1. Foreign sales of uraniumE. GreatVENTURADay)

  13. Rapid prediction of various physical properties for middle distillate fuel utilizing directly coupled liquid chromatography//sup 1/H nuclear magnetic resonance

    SciTech Connect (OSTI)

    Caswell, K.A.; Glass, T.E.; Swann, M.; Dorn, H.C.

    1989-02-01T23:59:59.000Z

    A group property approach has been developed to predict 17 physical properties of middle distillate (e.g., jet and diesel) fuels from experimentally derived liquid chromatography//sup 1/H nuclear magnetic resonance (LC//sup 1/H NMR) data. In the LC//sup 1/H NMR technique, the fuel is separated according to chemical class and the average molecular structure for each chemical class is then calculated. These average molecular structures form a basis set to predict the physical properties of the fuel. The physical properties that can be obtained in this manner are cetane number, cetane index, density, specific gravity, pour point, flash point, viscosity, filterability, heat of combustion, cloud point, volume percent aromatics, residual carbon content, and the initial, 10%, 50%, 90%, and end boiling points. Fourteen of the correlation coefficients for the predictions are better than 0.90 with 11 of the predictions falling either within or approximately equal to the ASTM method reproducibility for the measurement of the fuel property. The present method also provides chemical insight concerning the influence of chemical structural changes on the physical properties of the fuel as well as requiring much less analysis time and sample volume than corresponding ASTM methods.

  14. A method for the rapid, accurate prediction of the physical properties of middle distillate fuels from LC- sup 1 H NMR derived data

    SciTech Connect (OSTI)

    Caswell, K.A.

    1988-01-01T23:59:59.000Z

    A method has been developed whereby various physical properties of middle distillate fuels may be rapidly and accurately calculated by a group property approach from data obtained from a directly coupled Liquid Chromatograph - {sup 1}H Nuclear Magnetic Resonance Spectrometer (LC-{sup 1}H NMR). The physical properties include cetane number, cetane index, density, specific gravity, pour point, flash point, viscosity, filterability, heat of combustion, cloud point, volume percent aromatics, residual carbon content, and initial, 10%, 50%, 90%, and end boiling points. These property predictions have accuracies approaching the error for measurement of the experimental physical property and require less than two hours analysis time per fuel. An interface was developed between the NMR spectrometer and a personal computer to aid in automation of the LC-{sup 1}H NMR data collection and to perform off-line analysis of the LC-{sup 1}H NMR data. This interface and all associated software is described. Also presented is a series of model compounds studies in which the physical properties of pure hydrocarbons (i.e., alkanes, monocyclic and dicyclic aromatics) were predicted by a similar group property approach.

  15. Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant

    SciTech Connect (OSTI)

    Gambert, G.

    1996-12-31T23:59:59.000Z

    When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

  16. ,"U.S. Distillate Fuel Oil and Kerosene Sales by End Use"

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National and Regional Data; Row: NAICS Codes; Column: EnergyShale ProvedTexas"Brunei (Dollars perReserves (Billion Cubic Feet)"+ LeaseDistillate

  17. Method and apparatus for assessing distillate-fuel stability by oxygen overpressure

    SciTech Connect (OSTI)

    Hardy, D.R.; Beal, E.J.; Burnett, J.C.

    1989-06-27T23:59:59.000Z

    Reactions leading to insoluble sediments formation in distillate fuel are accelerated by forcing oxygen into solution in the fuel at pressures of between about 90 and 110 psig and then stressing the fuel under conditions of accelerated storage at temperatures of between about 40 C to 100 C. The method then makes use of gravimetric determination of the total insoubles formed. The stability of the fuel over a period of time as well as its comparitive stability to other fuels can then be predicted from the amount of insolubles formed. The method can be carried out by using a specialized pressure vessel.

  18. Process to recycle shredder residue

    DOE Patents [OSTI]

    Jody, Bassam J. (Chicago, IL); Daniels, Edward J. (Oak Lawn, IL); Bonsignore, Patrick V. (Channahon, IL)

    2001-01-01T23:59:59.000Z

    A system and process for recycling shredder residue, in which separating any polyurethane foam materials are first separated. Then separate a fines fraction of less than about 1/4 inch leaving a plastics-rich fraction. Thereafter, the plastics rich fraction is sequentially contacted with a series of solvents beginning with one or more of hexane or an alcohol to remove automotive fluids; acetone to remove ABS; one or more of EDC, THF or a ketone having a boiling point of not greater than about 125.degree. C. to remove PVC; and one or more of xylene or toluene to remove polypropylene and polyethylene. The solvents are recovered and recycled.

  19. Magic State Distillation and Gate Compilation in Quantum Algorithms for Quantum Chemistry

    E-Print Network [OSTI]

    Colin J. Trout; Kenneth R. Brown

    2015-01-29T23:59:59.000Z

    Quantum algorithms for quantum chemistry map the dynamics of electrons in a molecule to the dynamics of a coupled spin system. To reach chemical accuracy for interesting molecules, a large number of quantum gates must be applied which implies the need for quantum error correction and fault-tolerant quantum computation. Arbitrary fault-tolerant operations can be constructed from a small, universal set of fault-tolerant operations by gate compilation. Quantum chemistry algorithms are compiled by decomposing the dynamics of the coupled spin-system using a Trotter formula, synthesizing the decomposed dynamics using Clifford operations and single-qubit rotations, and finally approximating the single-qubit rotations by a sequence of fault-tolerant single-qubit gates. Certain fault-tolerant gates rely on the preparation of specific single-qubit states referred to as magic states. As a result, gate compilation and magic state distillation are critical for solving quantum chemistry problems on a quantum computer. We review recent progress that has improved the efficiency of gate compilation and magic state distillation by orders of magnitude.

  20. Magic State Distillation and Gate Compilation in Quantum Algorithms for Quantum Chemistry

    E-Print Network [OSTI]

    Colin J. Trout; Kenneth R. Brown

    2015-01-07T23:59:59.000Z

    Quantum algorithms for quantum chemistry map the dynamics of electrons in a molecule to the dynamics of a coupled spin system. To reach chemical accuracy for interesting molecules, a large number of quantum gates must be applied which implies the need for quantum error correction and fault-tolerant quantum computation. Arbitrary fault-tolerant operations can be constructed from a small, universal set of fault-tolerant operations by gate compilation. Quantum chemistry algorithms are compiled by decomposing the dynamics of the coupled spin-system using a Trotter formula, synthesizing the decomposed dynamics using Clifford operations and single-qubit rotations, and finally approximating the single-qubit rotations by a sequence of fault-tolerant single-qubit gates. Certain fault-tolerant gates rely on the preparation of specific single-qubit states referred to as magic states. As a result, gate compilation and magic state distillation are critical for solving quantum chemistry problems on a quantum computer. We review recent progress that has improved the efficiency of gate compilation and magic state distillation by orders of magnitude.

  1. Optimum Requirements for the Synthesis of Biodiesel Using Fatty Acid Distillates

    E-Print Network [OSTI]

    Akunna E. Ejele

    The optimum requirements of temperature, retention time, mole ratio of reactants and catalyst for the direct synthesis of biodiesel from fatty acid distillates of palm kernel oil using tetraoxosulphate (VI) acid as catalyst was studied. The following parameters were used for the efficient and economic production of biodiesel: eight (8) moles of methanol per mole of fatty acid, 0.06 mole of tetraoxosulphate (VI) acid per mole of fatty acid, a retention time of sixty (60) minutes and reaction temperature of 65 OC. And this gave a maximum percentage yield of 98.4. Other parameters obtained include: an acid value of 0.1683 mg KOH/g, iodine value of 15.3549, flash point of 209 OC, viscosity of 3.7957 mm2s-1, density of 0.8776 g cm-3, water content of 400.05 mg kg-1, soap content of 2.30 mg/kg, and ester content of 98.804 %. From the obtained parameters, the biodiesel produced from fatty acid distillates of palm kernel oil reaches prescribed international standards for biodiesel production.

  2. Residual stress patterns in steel welds

    SciTech Connect (OSTI)

    Spooner, S.; Hubbard, C.R.; Wang, X.L.; David, S.A.; Holden, T.M. [Oak Ridge National Lab., TN (United States); Root, J.H.; Swainson, I. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada)

    1994-12-31T23:59:59.000Z

    Neutron strain scanning of residual stress is a valuable nondestructive tool for evaluation of residual stress in welds. The penetrating characteristic of neutrons permits mapping of strain patterns with a spatial resolution approaching 1mm at depths of 20mm in steels. While the overall patterns of the residual stress tensor in a weld are understood, the detailed patterns depend on welding process parameters and the effects of solid state transformation. The residual strain profiles in two multi-pass austenitic welds and a ferritic steel weld are presented. The stress-free lattice parameters within the fusion zone and the adjacent heat affected zone in the two austenitic welds show that the interpretation of residual stress from strains are affected by welding parameters. An interpretation of the residual strain pattern in the ferritic steel plate can be made using the strain measurements of a Gleeble test bar which has undergone the solid state austenite decomposition.

  3. Residual Toxicities of Insecticides to Cotton Insects.

    E-Print Network [OSTI]

    Hightower, B. G.; Gaines, J. C.

    1960-01-01T23:59:59.000Z

    the effects of simulated wind and rain on the residues. Tempera- ture and humidity conditions incident to the holding period were sufficient to destroy most of the residual toxicity of this material. Effect of Simulated Wind Among the chlorinated... hydrocarbon insecticides, there was little difference between the effects of simu- lated wind and rain on residual toxicities. However, it is likely that under field conditions the effects of rain would be more noticeable. Simulated wind was less damaging...

  4. Methods of separating particulate residue streams

    DOE Patents [OSTI]

    Hoskinson, Reed L. (Rigby, ID); Kenney, Kevin L. (Idaho Falls, ID); Wright, Christopher T. (Idaho Falls, ID); Hess, J. Richard (Idaho Falls, ID)

    2011-04-05T23:59:59.000Z

    A particulate residue separator and a method for separating a particulate residue stream may include an air plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams that are formed by the harvesting device and that travel, at least in part, along the air plenum and in a direction of the second, exhaust end; and a baffle assembly that is located in partially occluding relation relative to the air plenum and that substantially separates the first and second particulate residue air streams.

  5. Particulate residue separators for harvesting devices

    SciTech Connect (OSTI)

    Hoskinson, Reed L.; Kenney, Kevin L.; Wright, Christopher T.; Hess, John R.

    2010-06-29T23:59:59.000Z

    A particulate residue separator and a method for separating a particulate residue stream may include a plenum borne by a harvesting device, and have a first, intake end and a second, exhaust end; first and second particulate residue air streams which are formed by the harvesting device and which travel, at least in part, along the plenum and in a direction of the second, exhaust end; and a baffle assembly which is located in partially occluding relation relative to the plenum, and which substantially separates the first and second particulate residue air streams.

  6. Experimental study of oil yields and properties of light and medium Venezuelan crude oils under steam and steam-propane distillation

    E-Print Network [OSTI]

    Plazas Garcia, Joyce Vivia

    2002-01-01T23:59:59.000Z

    Six experimental runs were carried out to study the yields for a light crude oil (34.2°API) and an intermediate crude oil (25.1°API) under steam distillation and steam-propane distillation. Yields, were measured at five temperatures, 110, 150, 200...

  7. Theoretical Analysis of an Ideal Noiseless Linear Amplifier for Einstein-Podolsky-Rosen Entanglement Distillation

    E-Print Network [OSTI]

    J. Bernu; S. Armstrong; T. Symul; T. C. Ralph; P. K. Lam

    2014-11-03T23:59:59.000Z

    We study the operational regime of a noiseless linear amplifier based on quantum scissors that can nondeterministically amplify the one photon component of a quantum state with weak excitation. It has been shown that an arbitrarily large quantum state can be amplified by first splitting it into weak excitation states using a network of beamsplitters. The output states of the network can then be coherently recombined. In this paper, we analyse the performance of such a device for distilling entanglement after transmission through a lossy quantum channel, and look at two measures to determine the efficacy of the noiseless linear amplifier. The measures used are the amount of entanglement achievable and the final purity of the output amplified entangled state. We study the performances of both a single and a two-element noiseless linear amplifier for amplifying weakly excited states. Practically, we show that it may be advantageous to work with a limited number of stages.

  8. Upgrading of middle distillate fractions of syncrudes from athabasca oil sands

    SciTech Connect (OSTI)

    Wilson, M.F.; Kriz, J.F.

    1983-03-01T23:59:59.000Z

    Middle distillate fractions of syncrudes from Athabasca Oil Sands were evaluated for suitability as feedstocks in the catalytic conversion to diesel fuel meeting cetane number specifications. Hydrogenation of aromatic components to napthenes under severe conditions (380 to 400/sup 0/C, 2500 psig) using sulfided CoO/MoO/sub 3/ and NiO/WO/sub 3/ over ..cap alpha.. . Al/sub 2/O/sub 3/ in a previously described catalyst testing system. Reaction products were analyzed for aromatic carbon content using C/sup 13/ NMR spectroscopy and pseudo first order rate constants and activation energies (15.0 and 14.2 kcal 1 g-mole, respectively) were determined by regression analysis. At optimum conditions 97% aromatic conversion was obtained with the Ni-W catalyst. Product diesel fuel cetane number (42) was within specifications. Co-Mo catalyst was significantly less active.

  9. Dynamics and control of a heterogeneous azeotropic distillation column: Conventional control approach

    SciTech Connect (OSTI)

    Chien, I.L. [National Taiwan Univ. of Science and Technology, Taipei (Taiwan, Province of China). Dept. of Chemical Engineering; Wang, C.J.; Wong, D.S.H. [National Tsing Hua Univ., Hsinchu (Taiwan, Province of China). Dept. of Chemical Engineering

    1999-02-01T23:59:59.000Z

    In this work, bifurcation analysis and dynamic simulation were used to investigate the optimum conventional control strategy of an isopropyl alcohol (IPA), cyclohexane (CyH), and water (H{sub 2}O) heterogeneous azeotropic column. Steady-state process analysis shows that the optimal operation point should be located at a critical reflux, a transition point at which the distillation path switches from a route that passes through the IPA + H{sub 2}O azeotrope to one that passes through the IPA + CyH azeotrope. A good control strategy must be able to maintain a steady column temperature profile that shows a plateau near 70 C to ensure passage around the IPA + CyH azeotrope. An inverse double-loop control strategy is proposed based on principal component analysis. This scheme is capable of maintaining the desired column temperature profile given all kinds of feed disturbances, thus keeping the product IPA purity at the desired level.

  10. Re-refining of Waste Oil Solvent Is Used in Treatment/Distillation Process

    E-Print Network [OSTI]

    unknown authors

    INDUSTRIAL APPLICATION. A combination solvent treatment/distillation process has been designed for re-refining industrial waste oil (such as equipment lubricants, metal-working oil, and process oil) and used automotive lubricants (engine oil, hydraulic oil, and gear oil) for reuse. WASTE ENERGY RECOVERY. Recycling of waste oil in the United States has the potential to save the energy equivalent of 7-12 million bbl of crude oil annually.1 WASTE OIL RECOVERY. Prior to 1960, a significant portion of the demand for automotive lubricating oil was met by re-relined used oil. At the time, 150 re-refineries produced 300 million gal of motor oil annually. Since 1960, however, the production of re-refined oil has steadily declined. In 1981, for example, out of about 1.2 billion gal of automobile lubricating oil and 1.6 billion gal of industrial lubricating oils purchased, 25 U.S. rerefineries

  11. On local indistinguishability of orthogonal pure states by using a bound on distillable entanglement

    E-Print Network [OSTI]

    Sibasish Ghosh; Guruprasad Kar; Anirban Roy; Debasis Sarkar; Aditi Sen De; Ujjwal Sen

    2001-11-25T23:59:59.000Z

    We show that the four states a|00>+b|11>, b^*|00>-a^*|11>, c|01>+d|10> and d^*|01>-c^*|10> cannot be discriminated with certainty if only local operations and classical communication (LOCC) are allowed and if only a single copy is provided, except in the case when they are simply |00>, |11>, |01> and |10> (in which case they are trivially distinguishable with LOCC). We go on to show that there exists a continuous range of values of a, b, c and d such that even three states among the above four are not locally distinguishable, if only a single copy is provided. The proof follows from the fact that logarithmic negativity is an upper bound of distillable entanglement.

  12. Why methyl tert-butyl ether production by reactive distillation may yield multiple solutions

    SciTech Connect (OSTI)

    Hauan, S.; Hertzberg, T.; Lien, K.M. [Univ. of Trondheim (Norway)

    1995-03-01T23:59:59.000Z

    This paper presents an explanation of why methyl tert-butyl ether (MTBE) production by reactive distillation may yield multiple solutions. Widely different composition profiles and conversions may, as already reported by Krishna and others, results with identical column specifications, depending on the initial estimates provided. A hypothesis yielding a qualitative understanding of this phenomenon has been developed. The inert n-butene plays a key role in the proposed explanation: As the reaction mixture is diluted with n-butene, the activity coefficient of methanol increases substantially and the temperature decreases. This dilution has a profound effect on the equilibrium conversion, enabling MTBE to escape from the reactive zone without decomposition. When methanol is fed below or in the lower part of the reactive zone of the column, the ``lifting capacity`` of the minimum boiling point MTBE-methanol azeotrope will also be important.

  13. Characterization Report on Sand, Slag, and Crucible Residues and on Fluoride Residues

    SciTech Connect (OSTI)

    Murray, A.M.

    1999-02-10T23:59:59.000Z

    This paper reports on the chemical characterization of the sand, slag, and crucible (SS and C) residues and the fluoride residues that may be shipped from the Rocky Flats Environmental Technology Site (RFETS) to Savannah River Site (SRS).

  14. Assigning a Value to Dried Distillers' Grains as a Protein Supplement in Cattle Consuming Low-Quality Forage

    E-Print Network [OSTI]

    Rambo, Zachary Joseph

    2011-08-08T23:59:59.000Z

    Cattle consuming low-quality forage may have decreased forage organic matter intake as a result of decreased nitrogen (N) intake. To date, a value has not been assigned to dried distillers' grains as a protein supplement to cattle consuming low...

  15. Kinetics of hydrogenation of aromatics determined by carbon-13 NMR for Athabasca bitumen-derived middle distillates

    SciTech Connect (OSTI)

    Yui, S.M.; Sanford, E.C. (Syncrude Canada Ltd., Edmonton, Alberta (Canada))

    1987-04-01T23:59:59.000Z

    High aromatics content in middle distillates is detrimental to fuel quality, as shown in such properties as smoke point of jet fuel and cetane number of diesel fuel. In the petroleum and petrochemical industries the yields from fluid catalytic cracking or steam cracking units are adversely affected by high aromatics content in the feedstock. Distillates obtained from oil sand bitumen, heavy oils, or coal liquefaction products are particularly high in aromatics. Reducing the concentration of this class of compounds is important. Aromatics hydrogenation (AHYD) is one option to achieve this result. In the current Syncrude operation a primary objective of hydrotreating is to reduce product sulfur and nitrogen contents; reducing aromatics content is an incidental result. However, the expansion plan currently under study by Syncrude includes further AHYD to improve cetane number. Predicting the product aromatics content is an important issue for this study. In the present study, hydrotreating of five Athabasca-bitumen-derived gas oils was conducted in pilot scale trickle-bed reactors using alumina-based commercial NiMo catalysts. Feedstocks originated from the distillation of virgin bitumen, and from distillates derived from treating bitumen in a fluid coker and hydrocracking pilot plant. Aromatics content was determined by the {sup 13}C NMR method. The previously developed rate equation for AHYD was modified by including power terms for space velocity and hydrogen partial pressure. The data were analyzed using the modified equation.

  16. Asymptotics for GARCH Squared Residual Correlations

    E-Print Network [OSTI]

    Kokoszka, Piotr

    Asymptotics for GARCH Squared Residual Correlations Istv'an Berkes \\Lambda A. R'enyi Institute a GARCH(p; q) model. Denoting by â?? r n (k); k â?? 1; these autocorrelations computed from a realization words and phrases: GARCH(p; q) sequence, quasi--maximum likelihood esti­ mator, squared residuals

  17. University of Pittsburgh Residual Funds on

    E-Print Network [OSTI]

    Sibille, Etienne

    University of Pittsburgh Residual Funds on FINANCIAL GUIDELINE Subject: Sponsored Projects I by the sponsor. Funds cannot be unilaterally retained by the University. Failure to return residual funds related funds on sponsored grants and contracts on the financial accounting records of the University

  18. Data Conversion in Residue Number System

    E-Print Network [OSTI]

    Zilic, Zeljko

    for direct conversion when interaction with the real analog world is required. We first develop two efficient schemes for direct analog-to-residue conversion. Another efficient scheme for direct residue analogique réel est nécessaire. Nous dévelopons deux systèmes efficaces pour la conversion directe du domaine

  19. Residual stress in nanocrystalline nickel tungsten electrodeposits

    E-Print Network [OSTI]

    Ziebell, Tiffany D. (Tiffany Dawn)

    2011-01-01T23:59:59.000Z

    Characterizing the residual stress of thick nanocrystalline electrodeposits poses several unique challenges due to their fine grain structure, thickness distribution, and matte surface. We employ a three-dimensional ...

  20. SAR impulse response with residual chirps.

    SciTech Connect (OSTI)

    Doerry, Armin Walter

    2009-06-01T23:59:59.000Z

    A Linear Frequency-Modulated (LFM) chirp is a function with unit amplitude and quadratic phase characteristic. In a focused Synthetic Aperture Radar (SAR) image, a residual chirp is undesired for targets of interest, as it coarsens the manifested resolution. However, for undesired spurious signals, a residual chirp is often advantageous because it spreads the energy and thereby diminishes its peak value. In either case, a good understanding of the effects of a residual LFM chirp on a SAR Impulse Response (IPR) is required to facilitate system analysis and design. This report presents an analysis of the effects of a residual chirp on the IPR. As reference, there is a rich body of publications on various aspects of LFM chirps. A quick search reveals a plethora of articles, going back to the early 1950s. We mention here purely as trivia one of the earlier analysis papers on this waveform by Klauder, et al.

  1. Microwave pyrolysis of distillers dried grain with solubles (DDGS) for biofuel production

    SciTech Connect (OSTI)

    Lei, Hanwu; Ren, Shoujie; Wang, Lu; Bu, Quan; Julson, James; Holladay, Johnathan E.; Ruan, Roger

    2011-05-01T23:59:59.000Z

    Microwave pyrolysis of distillers dried grain with solubles (DDGS) was investigated to determine the effects of pyrolytic conditions on the yields of bio-oil, syngas, and biochar. Pyrolysis process variables included reaction temperature, time, and power input. Microwave pyrolysis of DDGS was analyzed using response surface methodology to ?nd out the effect of process variables on the biofuel (bio-oil and syn- gas) conversion yield and establish prediction models. Bio-oil recovery was in the range of 26.5–50.3 wt.% of the biomass. Biochar yields were 23.5–62.2% depending on the pyrolysis conditions. The energy con- tent of DDGS bio-oils was 28 MJ/kg obtained at the 650 oC and 8 min, which was about 66.7% of the heat- ing value of gasoline. GC/MS analysis indicated that the biooil contained a series of important and useful chemical compounds: aliphatic and aromatic hydrocarbons. At least 13% of DDGS bio-oil was the same hydrocarbon compounds found in regular unleaded gasoline.

  2. Recovery of Navy distillate fuel from reclaimed product. Volume II. Literature review

    SciTech Connect (OSTI)

    Brinkman, D.W.; Whisman, M.L.

    1984-11-01T23:59:59.000Z

    In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). This first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in which experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 references and abstracts. This appendix, because of its volume, has been published separately as Volume 2.

  3. Recovery of Navy distillate fuel from reclaimed product. Volume I. Technical discussion

    SciTech Connect (OSTI)

    Brinkman, D.W.; Whisman, M.L.

    1984-11-01T23:59:59.000Z

    In an effort to assist the Navy to better utilize its waste hydrocarbons, NIPER, with support from the US Department of Energy, is conducting research designed to ultimately develop a practical technique for converting Reclaimed Product (RP) into specification Naval Distillate Fuel (F-76). The first phase of the project was focused on reviewing the literature and available information from equipment manufacturers. The literature survey has been carefully culled for methodology applicable to the conversion of RP into diesel fuel suitable for Navy use. Based upon the results of this study, a second phase has been developed and outlined in which experiments will be performed to determine the most practical recycling technologies. It is realized that the final selection of one particular technology may be site-specific due to vast differences in RP volume and available facilities. A final phase, if funded, would involve full-scale testing of one of the recommended techniques at a refueling depot. The Phase I investigations are published in two volumes. Volume 1, Technical Discussion, includes the narrative and Appendices I and II. Appendix III, a detailed Literature Review, includes both a narrative portion and an annotated bibliography containing about 800 referenvces and abstracts. This appendix, because of its volume, has been published separately as Volume 2. 18 figures, 4 tables.

  4. ABSTRACT: Bioenergy Harvesting Technologies to Supply Crop Residues...

    Energy Savers [EERE]

    ABSTRACT: Bioenergy Harvesting Technologies to Supply Crop Residues In a Densified Large Square Bale Format ABSTRACT: Bioenergy Harvesting Technologies to Supply Crop Residues In a...

  5. Sustainable System for Residual Hazards Management

    SciTech Connect (OSTI)

    Kevin M. Kostelnik; James H. Clarke; Jerry L. Harbour

    2004-06-01T23:59:59.000Z

    Hazardous, radioactive and other toxic substances have routinely been generated and subsequently disposed of in the shallow subsurface throughout the world. Many of today’s waste management techniques do not eliminate the problem, but rather only concentrate or contain the hazardous contaminants. Residual hazards result from the presence of hazardous and/or contaminated material that remains on-site following active operations or the completion of remedial actions. Residual hazards pose continued risk to humans and the environment and represent a significant and chronic problem that require continuous longterm management (i.e. >1000 years). To protect human health and safeguard the natural environment, a sustainable system is required for the proper management of residual hazards. A sustainable system for the management of residual hazards will require the integration of engineered, institutional and land-use controls to isolate residual contaminants and thus minimize the associated hazards. Engineered controls are physical modifications to the natural setting and ecosystem, including the site, facility, and/or the residual materials themselves, in order to reduce or eliminate the potential for exposure to contaminants of concern (COCs). Institutional controls are processes, instruments, and mechanisms designed to influence human behavior and activity. System failure can involve hazardous material escaping from the confinement because of system degradation (i.e., chronic or acute degradation) or by externalintrusion of the biosphere into the contaminated material because of the loss of institutional control. An ongoing analysis of contemporary and historic sites suggests that the significance of the loss of institutional controls is a critical pathway because decisions made during the operations/remedial action phase, as well as decisions made throughout the residual hazards management period, are key to the longterm success of the prescribed system. In fact, given that society has become more reliant on and confident of engineered controls, there may be a growing tendency to be even less concerned with institutional controls.

  6. Investigation of the Potential for Biofuel Blends in Residual Oil-Fired Power Generation Units as an Emissions Reduction Strategy for New York State

    SciTech Connect (OSTI)

    Krishna, C.R.; McDonald, R.

    2009-05-01T23:59:59.000Z

    There is a significant amount of oil, about 12.6 million barrels per year, used for power generation in New York State. The majority of it is residual oil. The primary reason for using residual oil probably is economic, as these fuels are cheaper than distillates. However, the stack emissions from the use of such fuels, especially in densely populated urban areas, can be a cause for concern. The emissions of concern include sulfur and nitrogen oxides and particulates, particularly PM 2.5. Blending with distillate (ASTM No.2) fuels may not reduce some or all of these emissions. Hence, a case can be made for blending with biofuels, such as biodiesel, as they tend to have very little fuel bound sulfur and nitrogen and have been shown in prior work at Brookhaven National Laboratory (BNL) to reduce NOx emissions as well in small boilers. Some of the research carried out at CANMET in Canada has shown potential reductions in PM with blending of biodiesel in distillate oil. There is also the benefit obtaining from the renewable nature of biofuels in reducing the net carbon dioxide emitted thus contributing to the reduction of green house gases that would otherwise be emitted to the atmosphere. The present project was conceived to examine the potential for such benefits of blending biofuels with residual oil. A collaboration was developed with personnel at the New York City Poletti Power Plant of the New York Power Authority. Their interest arose from an 800 MW power plant that was using residual oil and which was mandated to be shut down in 2010 because of environmental concerns. A blend of 20% biodiesel in residual oil had also been tested for a short period of about two days in that boiler a couple of years back. In this project, emission measurements including particulate measurements of PM2.5 were made in the commercial boiler test facility at BNL described below. Baseline tests were done using biodiesel as the blending biofuel. Biodiesel is currently and probably in the foreseeable future more expensive than residual fuel. So, another task was to explore potential alternative biofuels that might confer emission benefits similar to those of biodiesel, while being potentially significantly cheaper. Of course, for power plant use, availability in the required quantities is also a significant criterion. A subsidiary study to determine the effect of the temperature of the filter used to collect and measure the PM 2.5 emissions was conducted. This was done for reasons of accuracy in a residential boiler using distillate fuel blends. The present report details the results obtained in these tests with the baseline ASTM No. 6 fuel and blends of biodiesel with it as well as the results of the filter temperature study. The search for the alternative 'cheaper' biofuel identified a potential candidate, but difficulties encountered with the equipment during the testing prevented testing of the alternative biofuel.

  7. Update of distillers grains displacement ratios for corn ethanol life-cycle analysis.

    SciTech Connect (OSTI)

    Arora, S.; Wu, M.; Wang, M.; Energy Systems

    2011-02-01T23:59:59.000Z

    Production of corn-based ethanol (either by wet milling or by dry milling) yields the following coproducts: distillers grains with solubles (DGS), corn gluten meal (CGM), corn gluten feed (CGF), and corn oil. Of these coproducts, all except corn oil can replace conventional animal feeds, such as corn, soybean meal, and urea. Displacement ratios of corn-ethanol coproducts including DGS, CGM, and CGF were last updated in 1998 at a workshop at Argonne National Laboratory on the basis of input from a group of experts on animal feeds, including Prof. Klopfenstein (University of Nebraska, Lincoln), Prof. Berger (University of Illinois, Urbana-Champaign), Mr. Madson (Rapheal Katzen International Associates, Inc.), and Prof. Trenkle (Iowa State University) (Wang 1999). Table 1 presents current dry milling coproduct displacement ratios being used in the GREET model. The current effort focuses on updating displacement ratios of dry milling corn-ethanol coproducts used in the animal feed industry. Because of the increased availability and use of these coproducts as animal feeds, more information is available on how these coproducts replace conventional animal feeds. To glean this information, it is also important to understand how industry selects feed. Because of the wide variety of available feeds, animal nutritionists use commercial software (such as Brill Formulation{trademark}) for feed formulation. The software recommends feed for the animal on the basis of the nutritional characteristics, availability, and price of various animal feeds, as well as on the nutritional requirements of the animal (Corn Refiners Association 2006). Therefore, feed formulation considers both the economic and the nutritional characteristics of feed products.

  8. BY HOW MUCH CAN RESIDUAL MINIMIZATION ACCELERATE THE CONVERGENCE OF ORTHOGONAL RESIDUAL METHODS?

    E-Print Network [OSTI]

    Gutknecht, Martin H.

    . Examples of such pairs are the conjugate gradient (CG) and the conjugate residual (CR) methods, the full-minimal residual (QMR) methods. Also the pairs consisting of the (bi)conjugate gradient squared (CGS, iterative method, Krylov space method, conjugate gradient method, biconjugate gradient method, CG, CGNE

  9. Residual oil conversion in Ashland FCC Units

    SciTech Connect (OSTI)

    Barger, D.F.; Miller, C.B.

    1983-03-01T23:59:59.000Z

    Ashland Petroleum Company is a production-poor refining and marketing company. A company must have refining flexibility to compete in today's crude and marketing situation. Ashland has adopted a dual approach to achieving the required refining flexibility: development and construction of the RCC process, and development of techniques to practice residual oil conversion in Ashland FCC units. This paper discusses the operating techniques Ashland has used to allow residual oil conversion to be practiced in their present day FCC's and shows some of the yields which have been achieved.

  10. Residual dust charges in discharge afterglow

    SciTech Connect (OSTI)

    Coueedel, L.; Mikikian, M.; Boufendi, L.; Samarian, A. A. [GREMI - Groupe de Recherches sur l'Energetique des Milieux Ionises, CNRS/Universite d'Orleans, 14 rue d'Issoudun, 45067 Orleans Cedex 2 (France); School of Physics A28, University of Sydney, NSW 2006 (Australia)

    2006-08-15T23:59:59.000Z

    An on-ground measurement of dust-particle residual charges in the afterglow of a dusty plasma was performed in a rf discharge. An upward thermophoretic force was used to balance the gravitational force. It was found that positively charged, negatively charged, and neutral dust particles coexisted for more than 1 min after the discharge was switched off. The mean residual charge for 200-nm-radius particles was measured. The dust particle mean charge is about -5e at a pressure of 1.2 mbar and about -3e at a pressure of 0.4 mbar.

  11. Automatic Methods for Predicting Functionally Important Residues

    E-Print Network [OSTI]

    Pazos, Florencio

    Pazos and Alfonso Valencia* Protein Design Group National Center for Biotechnology, Cantoblanco Madrid of protein families into subfamilies in the search for those positions that could have some functional families, testing the statistical meaning of the Tree-determinant residues predicted by three different

  12. Residual Energy Spectrum of Solar Wind Turbulence

    E-Print Network [OSTI]

    Chen, C H K; Salem, C S; Maruca, B A

    2013-01-01T23:59:59.000Z

    It has long been known that the energy in velocity and magnetic field fluctuations in the solar wind is not in equipartition. In this paper, we present an analysis of 5 years of Wind data at 1 AU to investigate the reason for this. The residual energy (difference between energy in velocity and magnetic field fluctuations) was calculated using both the standard magnetohydrodynamic (MHD) normalization for the magnetic field and a kinetic version, which includes temperature anisotropies and drifts between particle species. It was found that with the kinetic normalization, the fluctuations are closer to equipartition, with a mean normalized residual energy of sigma_r = -0.19 and mean Alfven ratio of r_A = 0.71. The spectrum of residual energy, in the kinetic normalization, was found to be steeper than both the velocity and magnetic field spectra, consistent with some recent MHD turbulence predictions and numerical simulations, having a spectral index close to -1.9. The local properties of residual energy and cros...

  13. Chemical Stabilization of Hanford Tank Residual Waste

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Um, Wooyong; Williams, Benjamin D.; Bowden, Mark E.; Gartman, Brandy N.; Lukens, Wayne W.; Buck, Edgar C.; Mausolf, Edward J.

    2014-03-01T23:59:59.000Z

    Three different chemical treatment methods were tested for their ability to stabilize residual waste from Hanford tank C-202 for reducing contaminant release (Tc, Cr, and U in particular). The three treatment methods tested were lime addition [Ca(OH)2], an in-situ Ceramicrete waste form based on chemically bonded phosphate ceramics, and a ferrous iron/goethite treatment. These approaches rely on formation of insoluble forms of the contaminants of concern (lime addition and ceramicrete) and chemical reduction followed by co-precipitation (ferrous iron/goethite incorporation treatment). The results have demonstrated that release of the three most significant mobile contaminants of concern from tank residual wastes can be dramatically reduced after treatment compared to contact with simulated grout porewater without treatment. For uranium, all three treatments methods reduced the leachable uranium concentrations by well over three orders of magnitude. In the case of uranium and technetium, released concentrations were well below their respective MCLs for the wastes tested. For tank C-202 residual waste, chromium release concentrations were above the MCL but were considerably reduced relative to untreated tank waste. This innovative approach has the potential to revolutionize Hanford’s tank retrieval process, by allowing larger volumes of residual waste to be left in tanks while providing an acceptably low level of risk with respect to contaminant release that is protective of the environment and human health. Such an approach could enable DOE to realize significant cost savings through streamlined retrieval and closure operations.

  14. Analysis of Oxygenated Compounds in Hydrotreated Biomass Fast Pyrolysis Oil Distillate Fractions

    SciTech Connect (OSTI)

    Christensen, Earl D.; Chupka, Gina; Luecke, Jon; Smurthwaite, Tricia D.; Alleman, Teresa L.; Iisa, Kristiina; Franz, James A.; Elliott, Douglas C.; McCormick, Robert L.

    2011-10-06T23:59:59.000Z

    Three hydrotreated bio-oils with different oxygen contents (8.2, 4.9, and 0.4 w/w) were distilled to produce Light, Naphtha, Jet, Diesel, and Gasoil boiling range fractions that were characterized for oxygen containing species by a variety of analytical methods. The bio-oils were originally generated from lignocellulosic biomass in an entrained-flow fast pyrolysis reactor. Analyses included elemental composition, carbon type distribution by {sup 13}C NMR, acid number, GC-MS, volatile organic acids by LC, and carbonyl compounds by DNPH derivatization and LC. Acid number titrations employed an improved titrant-electrode combination with faster response that allowed detection of multiple endpoints in many samples and for acid values attributable to carboxylic acids and to phenols to be distinguished. Results of these analyses showed that the highest oxygen content bio-oil fractions contained oxygen as carboxylic acids, carbonyls, aryl ethers, phenols, and alcohols. Carboxylic acids and carbonyl compounds detected in this sample were concentrated in the Light, Naphtha, and Jet fractions (<260 C boiling point). Carboxylic acid content of all of the high oxygen content fractions was likely too high for these materials to be considered as fuel blendstocks although potential for blending with crude oil or refinery intermediate streams may exist for the Diesel and Gasoil fractions. The 4.9 % oxygen sample contained almost exclusively phenolic compounds found to be present throughout the boiling range of this sample, but imparting measurable acidity primarily in the Light, Naphtha and Jet fractions. Additional study is required to understand what levels of the weakly acidic phenols could be tolerated in a refinery feedstock. The Diesel and Gasoil fractions from this upgraded oil had low acidity but still contained 3 to 4 wt% oxygen present as phenols that could not be specifically identified. These materials appear to have excellent potential as refinery feedstocks and some potential for blending into finished fuels. Fractions from the lowest oxygen content oil exhibited some phenolic acidity, but generally contained very low levels of oxygen functional groups. These materials would likely be suitable as refinery feedstocks and potentially as fuel blend components. PIONA analysis of the Light and Naphtha fractions shows benzene content of 0.5 and 0.4 vol%, and predicted (RON + MON)/2 of 63 and 70, respectively.

  15. Two-stage hydrotreating of a bitumen-derived middle distillate to produce diesel and jet fuels, and kinetics of aromatics hydrogenation

    SciTech Connect (OSTI)

    Yui, S.M. [Syncrude Canada Ltd., Edmonton, Alberta (Canada)

    1994-12-31T23:59:59.000Z

    The middle distillate from a synthetic crude oil derived from Athabasca bitumen was further hydrotreated in a downflow pilot unit over a typical NiMo catalyst at 330 to 400 C, 7 to 11 MPa and 0.63 to 1.39 h{sup {minus}1} LHSV. Feed and liquid products were characterized for aromatics, cetane index (CI) and other diesel specification items. Aromatics were determined by a supercritical fluid chromatography method, while CI was determined using the correlation developed at Syncrude Canada Ltd. Also feed and selected products were distilled into a jet fuel cut (150/260 C) by spinning band distillation for the determination of smoke point and other jet fuel specification items. A good relationship between aromatics content and CI was obtained. Kinetics of aromatics hydrogenation were investigated, employing a simple-first order reversible reaction model.

  16. Thin layer chromatography residue applicator sampler

    DOE Patents [OSTI]

    Nunes, Peter J. (Danville, CA); Kelly, Fredrick R. (Modesto, CA); Haas, Jeffrey S. (San Ramon, CA); Andresen, Brian D. (Livermore, CA)

    2007-07-24T23:59:59.000Z

    A thin layer chromatograph residue applicator sampler. The residue applicator sampler provides for rapid analysis of samples containing high explosives, chemical warfare, and other analyses of interest under field conditions. This satisfied the need for a field-deployable, small, hand-held, all-in-one device for efficient sampling, sample dissolution, and sample application to an analytical technique. The residue applicator sampler includes a sampling sponge that is resistant to most chemicals and is fastened via a plastic handle in a hermetically sealed tube containing a known amount of solvent. Upon use, the wetted sponge is removed from the sealed tube and used as a swiping device across an environmental sample. The sponge is then replaced in the hermetically sealed tube where the sample remains contained and dissolved in the solvent. A small pipette tip is removably contained in the hermetically sealed tube. The sponge is removed and placed into the pipette tip where a squeezing-out of the dissolved sample from the sponge into the pipette tip results in a droplet captured in a vial for later instrumental analysis, or applied directly to a thin layer chromatography plate for immediate analysis.

  17. A Practical Model for Mobile, Residual, and Entrapped NAPL in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Practical Model for Mobile, Residual, and Entrapped NAPL in Water-Wet Porous Media. A Practical Model for Mobile, Residual, and Entrapped NAPL in Water-Wet Porous Media....

  18. In-situ method for treating residual sodium

    SciTech Connect (OSTI)

    Sherman, Steven R. (Idaho Falls, ID); Henslee, S. Paul (Idaho Falls, ID)

    2005-07-19T23:59:59.000Z

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  19. Testing regression models with residuals as data by Xia Hua.

    E-Print Network [OSTI]

    Hua, Xia, Ph. D. Massachusetts Institute of Technology

    2010-01-01T23:59:59.000Z

    Abstract In polynomial regression ... . In this thesis, I developed a residual based test, the turning point test for residuals, which tests the hypothesis that the kth order polynomial regression holds with ... while the ...

  20. NEURAL NETWORK RESIDUAL STOCHASTIC COSIMULATION FOR ENVIRONMENTAL DATA ANALYSIS

    E-Print Network [OSTI]

    on radioactive soil contamination from the Chernobyl fallout. Introduction The problem of analysing environmentalNEURAL NETWORK RESIDUAL STOCHASTIC COSIMULATION FOR ENVIRONMENTAL DATA ANALYSIS V. Demyanov, M original method of stochastic simulation of environmental data -- Neural Network Residual Sequential

  1. In-Situ Method for Treating Residual Sodium

    DOE Patents [OSTI]

    Sherman, Steven R.; Henslee, S. Paul

    2005-07-19T23:59:59.000Z

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  2. 1-D Transforms for the Motion Compensation Residual

    E-Print Network [OSTI]

    Kamisli, Fatih

    Transforms used in image coding are also commonly used to compress prediction residuals in video coding. Prediction residuals have different spatial characteristics from images, and it is useful to develop transforms that ...

  3. Bioassays of weathered residues of several organic phosphorus insecticides

    E-Print Network [OSTI]

    Hightower, Billie Gene

    2013-10-04T23:59:59.000Z

    residues on fruit, forage crops, and animals. The effects of temperature, relative humid? ity, light, wind, and simulated rain on the residual toxicities of many of the chlorinated hydrocarbon insecticides used for the control of cotton insects were... humidity. Sunlight was found to be an important factor in reducing the residual effectiveness of dieldrin. Wind and simulated rain reduced the period of residual effectiveness of many of the compounds tested. These investigators have shown...

  4. Pyrolysis of shale oil residual fractions

    SciTech Connect (OSTI)

    Hazlett, R.N.; Beal, E.; Vetter, T.; Sonntag, R.; Moniz, W.

    1980-01-01T23:59:59.000Z

    The freezing point of JP-5, the Navy jet fuel, has been related to the n-alkane content, specifically n-hexadecane. In general, jet fuels from shale oil have the highest n-alkanes. The formation of n-alkanes in the jet fuel distillation range can be explained if large n-alkanes are present in the crude oil source. Quantities of large n-alkanes are insufficient, however, to explain the amounts found - up to 37% n-alkanes in the jet fuel range. Other possible precursors to small straight chain molecules are substituted cyclic compounds. Attack in the side chain obviously afford a path to an n-alkane. Aromatic hydrocarbons, esters, acids, amines, and ethers also have the potential to form n-alkanes if an unbranched alkyl chain is present in the molecule. Investigations showed that the best yield of the JP-5 cut comes at different times for the various fractions, but a time in the 60 to 120 min range would appear to be the optimum time for good yield at 450/sup 0/C. The longer time would be preferred with respect to lower potential n-alkane yield. None of the fractions gave n-alkane yields approaching the 37% amount found in the Shale-I JP-5. A temperature different than the 450/sup 0/C used here might affect the conversion percentage. Further the combined saturate, aromatic, and polar fractions may interact under pyrolysis conditions to give higher potential n-alkane yields than the fractions stressed independently.

  5. RESIDUAL STRESS AND YOUNG'S MODULUS MEASUREMENT OF CAPACITIVE MICROMACHINED ULTRASONIC

    E-Print Network [OSTI]

    Khuri-Yakub, Butrus T. "Pierre"

    deposition technique yields residual stress of around 100 MPa and Young's modulus of around 300 GPa. Keywords's modulus, Poisson's ratio, and residual stress of the deposited thin films. In this paper, we propose a newRESIDUAL STRESS AND YOUNG'S MODULUS MEASUREMENT OF CAPACITIVE MICROMACHINED ULTRASONIC TRANSDUCER

  6. SUPERLAYER RESIDUAL STRESS EFFECT ON THE INDENTATION ADHESION MEASUREMENTS

    E-Print Network [OSTI]

    Volinsky, Alex A.

    as a function of film thickness and residual stress. These films were sputter deposited onto thermally oxidized deposition parameters were controlled to produce either a compressive residual stress of 1 GPa or a tensile in a study of compressive and tensile residual stresses created during sputter deposition of tungsten

  7. Welding residual stresses in ferritic power plant steels

    E-Print Network [OSTI]

    Cambridge, University of

    REVIEW Welding residual stresses in ferritic power plant steels J. A. Francis*1 , H. K. D. H require therefore, an accounting of residual stresses, which often are introduced during welding. To do in the estimation of welding residual stresses in austenitic stainless steels. The progress has been less convincing

  8. Waste Heat Recovery and Recycling in Thermal Separation Processes: Distillation, Multi-Effect Evaporation (MEE) and Crystallization Processes

    SciTech Connect (OSTI)

    Emmanuel A. Dada; Chandrakant B. Panchal; Luke K. Achenie; Aaron Reichl; Chris C. Thomas

    2012-12-03T23:59:59.000Z

    Evaporation and crystallization are key thermal separation processes for concentrating and purifying inorganic and organic products with energy consumption over 1,000 trillion Btu/yr. This project focused on a challenging task of recovering low-temperature latent heat that can have a paradigm shift in the way thermal process units will be designed and operated to achieve high-energy efficiency and significantly reduce the carbon footprint as well as water footprint. Moreover, this project has evaluated the technical merits of waste-heat powered thermal heat pumps for recovery of latent heat from distillation, multi-effect evaporation (MEE), and crystallization processes and recycling into the process. The Project Team has estimated the potential energy, economics and environmental benefits with the focus on reduction in CO2 emissions that can be realized by 2020, assuming successful development and commercialization of the technology being developed. Specifically, with aggressive industry-wide applications of heat recovery and recycling with absorption heat pumps, energy savings of about 26.7 trillion Btu/yr have been estimated for distillation process. The direct environmental benefits of this project are the reduced emissions of combustible products. The estimated major reduction in environmental pollutants in the distillation processes is in CO2 emission equivalent to 3.5 billion lbs/year. Energy consumption associated with water supply and treatments can vary between 1,900 kWh and 23,700 kWh per million-gallon water depending on sources of natural waters [US DOE, 2006]. Successful implementation of this technology would significantly reduce the demand for cooling-tower waters, and thereby the use and discharge of water treatment chemicals. The Project Team has also identified and characterized working fluid pairs for the moderate-temperature heat pump. For an MEE process, the two promising fluids are LiNO3+KNO3+NANO3 (53:28:19 ) and LiNO3+KNO3+NANO2(53:35:12). And for an H2O2 distillation process, the two promising fluids are Trifluoroethanol (TFE) + Triethylene Glycol Dimethyl ether (DMETEG) and Ammonia+ Water. Thermo-physical properties calculated by Aspen+ are reasonably accurate. Documentation of the installation of pilot-plants or full commercial units were not found in the literature for validating thermo-physical properties in an operating unit. Therefore, it is essential to install a pilot-scale unit to verify thermo-physical properties of working fluid pairs and validate the overall efficiency of the thermal heat pump at temperatures typical of distillation processes. For an HO2 process, the ammonia-water heat pump system is more compact and preferable than the TFE-DMETEG heat pump. The ammonia-water heat pump is therefore recommended for the H2O2 process. Based on the complex nature of the heat recovery system, we anticipated that capital costs could make investments financially unattractive where steam costs are low, especially where co-generation is involved. We believe that the enhanced heat transfer equipment has the potential to significantly improve the performance of TEE crystallizers, independent of the absorption heat-pump recovery system. Where steam costs are high, more detailed design/cost engineering will be required to verify the economic viability of the technology. Due to the long payback period estimated for the TEE open system, further studies on the TEE system are not warranted unless there are significant future improvements to heat pump technology. For the H2O2 distillation cycle heat pump waste heat recovery system, there were no significant process constraints and the estimated 5 years payback period is encouraging. We therefore recommend further developments of application of the thermal heat pump in the H2O2 distillation process with the focus on the technical and economic viability of heat exchangers equipped with the state-of-the-art enhancements. This will require additional funding for a prototype unit to validate enhanced thermal performances of heat transfer equipment, evaluat

  9. Distillation of Bose-Einstein Condensates in a Double-Well Potential Y. Shin, M. Saba, A. Schirotzek, T. A. Pasquini, A. E. Leanhardt, D. E. Pritchard, and W. Ketterle*

    E-Print Network [OSTI]

    Distillation of Bose-Einstein Condensates in a Double-Well Potential Y. Shin, M. Saba, A-Einstein condensates of sodium atoms, prepared in an optical dipole trap, were distilled into a second empty dipole the potential barrier separating the two wells and then forming a new condensate. This process serves as a model

  10. Ashot Minasyan SQ-universality and residual properties. . . -slide #1 The SQ-universality and residual properties of

    E-Print Network [OSTI]

    Minasyan, Ashot

    Ashot Minasyan SQ-universality and residual properties. . . - slide #1 The SQ-universality Main Results Ashot Minasyan SQ-universality and residual properties. . . - slide #2 SQ-universality and residual properties. . . - slide #2 SQ-universality A group G is called SQ-universal if any countable group

  11. A characterization and evaluation of coal liquefaction process streams. The kinetics of coal liquefaction distillation resid conversion

    SciTech Connect (OSTI)

    Klein, M.T.; Calkins, W.H.; Huang, H.; Wang, S.; Campbell, D.

    1998-03-01T23:59:59.000Z

    Under subcontract from CONSOL Inc., the University of Delaware studied the mechanism and kinetics of coal liquefaction resid conversion. The program at Delaware was conducted between August 15, 1994, and April 30, 1997. It consisted of two primary tasks. The first task was to develop an empirical test to measure the reactivity toward hydrocracking of coal-derived distillation resids. The second task was to formulate a computer model to represent the structure of the resids and a kinetic and mechanistic model of resid reactivity based on the structural representations. An introduction and Summary of the project authored by CONSOL and a report of the program findings authored by the University of Delaware researchers are presented here.

  12. T-534: Vulnerability in the PDF distiller of the BlackBerry Attachment Service for the BlackBerry Enterprise Server

    Broader source: Energy.gov [DOE]

    BlackBerry advisory describes a security issue that the BlackBerry Attachment Service component of the BlackBerry Enterprise Server is susceptible to. The issue relates to a known vulnerability in the PDF distiller component of the BlackBerry Attachment Service that affects how the BlackBerry Attachment Service processes PDF files.

  13. Distillation of Bose-Einstein condensates in a double-well potential The characteristic feature of Bose-Einstein condensation is the accumulation of a

    E-Print Network [OSTI]

    Distillation of Bose-Einstein condensates in a double-well potential The characteristic feature of Bose-Einstein condensation is the accumulation of a macroscopic number of particles in the lowest quantum state. Condensate fragmentation, the macroscopic occupation of two or more quantum states

  14. Combination process for upgrading residual oils

    SciTech Connect (OSTI)

    Busch, L.E.; Walters, P.W.; Zandona, O.

    1990-01-16T23:59:59.000Z

    This patent describes a method for upgrading high boiling residual portions of crude oils comprising metal contaminants, porphyrins, asphaltenes and high molecular weight multi-ring hydrocarbon material. It comprises: charging a high boiling residual portion of crude oil admixed with diluent in contact with suspended upflowing substantially inert fluidizable solids particulate material at an elevated thermal visbreaking temperature in a riser contact zone for a time sufficient to recover therefrom a vaporous hydrocarbon product higher boiling than gasoline partially decarbonized and demetallized to a lower contaminating metals level, quenching the vaporous product of thermal visbreaking below its dew point after separation from solids, charging quenched thermally modified high boiling hydrocarbon product with a crystalline zeolite cracking catalyst under cracking conditions for a hydrocarbon residence time in a riser cracking zone; recovering a hydrocarbon conversion product; separating a combined C{sub 4} minus wet gas product stream of the visbreaking and zeolite catalyst cracking operating to recover a C{sub 3}-C{sub 4} rich fraction separately from a C{sub 2} minus dry gas product fraction, and regenerating the crystalline zeolite contcontaining catalyst.

  15. Combustion turbine deposition observations from residual and simulated residual oil studies

    SciTech Connect (OSTI)

    Whitlow, G.A.; Cohn, A.; Lee, S.Y.; Mulik, P.R.; Sherlock, T.P.; Wenglarz, R.A.

    1983-01-01T23:59:59.000Z

    Burning residual oil in utility combustion turbines and the consequent deposition on blades and vanes may adversely affect reliability and operation. Corrosion and deposition data for combustion turbine materials have been obtained through dynamic testing in pressurized passages. The deposition produced by the 1900/sup 0/F (1038/sup 0/C) combustion gases from a simulated and a real residual oil on cooled Udimet 500 surfaces is described. Higher deposition rates for the doped fuel than for the real residual oil raised questions of whether true simulation with this approach can be achieved. Particles 4-8..mu.. m in diameter predominated in the gas stream, with some fraction in the 0.1-12 ..mu.. m range. Deposition rates seemed to be influenced by thermophoretic delivery of small molten particles, tentatively identified as magnesium pyro and metavanadates and free vanadium pentoxide, which may act to bond the larger solid particles arriving by inertial impaction to turbine surfaces. Estimated maintenance intervals for current utility turbines operating with washed and treated residual oil agreed well with field experience.

  16. Distillation 29 Chem 355 Jasperse DISTILLATION

    E-Print Network [OSTI]

    Jasperse, Craig P.

    vaporize. The vapors produced are subsequently passed through a water-cooled condenser. Upon cooling liquid doesn't change, only the rate of vaporization. The energy supplied by heating is used

  17. Recovery of gallium from aluminum industry residues

    SciTech Connect (OSTI)

    Carvalho, M.S.; Neto, K.C.M.; Nobrega, A.W.; Medeiros, J.A.

    2000-01-01T23:59:59.000Z

    A procedure is proposed to recover gallium from flue dust aluminum residues produced in plants by using solid-phase extraction with a commercial polyether-type polyurethane foam (PUF). Gallium can be separated from high concentrations of aluminum, iron, nickel, titanium, vanadium, copper, zinc, sulfate, fluoride, and chloride by extraction with PUF from 3 M sulfuric acid and 3 M sodium chloride concentration medium with at least a 92% efficiency. Gallium backextraction was fast and quantitative with ethanol solution. In all recovery steps commercial-grade reagents could be used, including tap water. The recovered gallium was precipitated with sodium hydroxide solution, purified by dissolution and precipitation, calcinated, and the final oxide was 98.6% pure.

  18. Method For Characterizing Residual Stress In Metals

    DOE Patents [OSTI]

    Jacobson, Loren A. (Santa Fe, NM); Michel, David J. (Alexandria, VA); Wyatt, Jeffrey R. (Burke, VA)

    2002-12-03T23:59:59.000Z

    A method is provided for measuring the residual stress in metals. The method includes the steps of drilling one or more holes in a metal workpiece to a preselected depth and mounting one or more acoustic sensors on the metal workpiece and connecting the sensors to an electronic detecting and recording device. A liquid metal capable of penetrating into the metal workpiece placed at the bottom of the hole or holes. A recording is made over a period of time (typically within about two hours) of the magnitude and number of noise events which occur as the liquid metal penetrates into the metal workpiece. The magnitude and number of noise events are then correlated to the internal stress in the region of the workpiece at the bottom of the hole.

  19. Process converts incineration slag into stabilized residue

    SciTech Connect (OSTI)

    Thauront, J.; Deneux-Mustin, S. (EMC-Services, Paris (France)); Durecu, S. (EMC-Services, Vandoeuvre-Les Nancy (France)); Fraysse, G. (EMC-Services, Saint-Vulbas (France)); Berthelin, J. (Centre de Pedologie Biologique, Vandoeuvre-Les Nancy (France))

    1994-12-01T23:59:59.000Z

    During 1973 and 1974, EMC-Services designed and built a physico-chemical treatment plant in Hombourg, in France's Alsatian region. The plant is still in operation. Since then, EMC-Services has developed substantial experience in environmental projects, becoming one of the top companies internationally with experience and practice in designing, building and operating hazardous waste treatment plants. EMC-Services operates in France in Salaise, Strasbourg, Mitry-Mory, and Saint-Vulbas, where eight incinerators treat solid, liquid, highly halogenated and nonhazardous industrial waste. The incinerators, built or updated by EMC-Services, have a total capacity of about 200,000 tons per year. In the new process, incineration of special industrial wastes produces non-volatilized solid residue or slag, which is sent for disposal, in compliance with regulations, to special disposal plants. Future European regulations will incorporate landfilling criteria requiring such slag to be stabilized.

  20. active site residue: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in human transferrin and Tyr Oksana Lockridge 2008-01-01 140 RESEARCH ARTICLE Benefits of organic residues and chemical fertilizer Biology and Medicine Websites Summary: RESEARCH...

  1. active site residues: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in human transferrin and Tyr Oksana Lockridge 2008-01-01 140 RESEARCH ARTICLE Benefits of organic residues and chemical fertilizer Biology and Medicine Websites Summary: RESEARCH...

  2. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Prices," source for backcast estimates prior to January 1983. 19. U.S. Refiner Residual Fuel Oil Prices 36 Energy Information Administration Petroleum Marketing Annual 1996...

  3. Table 19. U.S. Refiner Residual Fuel Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Prices," source for backcast estimates prior to January 1983. 19. U.S. Refiner Residual Fuel Oil Prices 36 Energy Information Administration Petroleum Marketing Annual 1997...

  4. Residual Stresses for Structural Analysis and Fatigue Life Prediction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Stresses for Structural Analysis and Fatigue Life Prediction in Vehicle Components: Success stories from the High Temperature Materials Laboratory (HTML) User Program Residual...

  5. Wet Gasification of Ethanol Residue: A Preliminary Assessment

    SciTech Connect (OSTI)

    Brown, Michael D.; Elliott, Douglas C.

    2008-09-22T23:59:59.000Z

    A preliminary technoeconomic assessment has been made of several options for the application of catalytic hydrothermal gasification (wet gasification) to ethanol processing residues.

  6. Disappearance of fusionlike residues and the nuclear equation of state

    SciTech Connect (OSTI)

    Xu, H.M.; Lynch, W.G.; Danielewicz, P.; Bertsch, G.F. (National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, MI (USA) Department of Physics, Michigan State University, East Lansing, MI (USA))

    1990-08-13T23:59:59.000Z

    The cross sections for massive residues from {sup 40}Ca+{sup 40}Ca and {sup 40}Ar+{sup 27}Al collisions were calculated with an improved Boltzmann-Uehling-Uhlenbeck equation. The calculated residue cross sections decrease with incident energy, an effect which does not appear related to the residue excitation energy. Larger residue cross sections result from calculations with larger in-medium nucleon-nucleon cross sections or with equations of state which are less attractive at subnuclear density. This dual sensitivity may be eliminated by measurements of observables associated with the coincident light particles.

  7. acetamido trideoxyhexose residue: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The theory describes this...

  8. autophosphorylated residues required: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    though no flow is present. The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The...

  9. abradable coating residual: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The theory describes this...

  10. Water dynamics clue to key residues in protein folding

    SciTech Connect (OSTI)

    Gao, Meng [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Zhu, Huaiqiu, E-mail: hqzhu@pku.edu.cn [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Yao, Xin-Qiu [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China) [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China); Department of Biophysics, Kyoto University, Sakyo Kyoto 606-8502 (Japan); She, Zhen-Su, E-mail: she@pku.edu.cn [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)] [State Key Laboratory for Turbulence and Complex Systems, and Department of Biomedical Engineering, and Center for Theoretical Biology, and Center for Protein Science, Peking University, Beijing 100871 (China)

    2010-01-29T23:59:59.000Z

    A computational method independent of experimental protein structure information is proposed to recognize key residues in protein folding, from the study of hydration water dynamics. Based on all-atom molecular dynamics simulation, two key residues are recognized with distinct water dynamical behavior in a folding process of the Trp-cage protein. The identified key residues are shown to play an essential role in both 3D structure and hydrophobic-induced collapse. With observations on hydration water dynamics around key residues, a dynamical pathway of folding can be interpreted.

  11. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26T23:59:59.000Z

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

  12. TEXAS LPG FUEL CELL DEVELOPMENT AND DEMONSTRATION PROJECT Full-Text - Submission contains both citation data and full-text of the journal article. Full-text can be either a pre-print or post-print, but not the copyrighted article.

    SciTech Connect (OSTI)

    SOUTHWEST RESEARCH LABORATORY SUBMITTED BY SUBCONTRACTOR, RAILROAD COMMISSION OF TEXAS

    2004-07-26T23:59:59.000Z

    The State Energy Conservation Office has executed its first Fuel Cell Project which was awarded under a Department of Energy competitive grant process. The Texas LPG Fuel Processor Development and Fuel Cell Demonstration Program is a broad-based public/private partnership led by the Texas State Energy Conservation Office (SECO). Partners include the Alternative Fuels Research and Education Division (AFRED) of the Railroad Commission of Texas; Plug Power, Inc., Latham, NY, UOP/HyRadix, Des Plaines, IL; Southwest Research Institute (SwRI), San Antonio, TX; the Texas Natural Resource Conservation Commission (TNRCC), and the Texas Department of Transportation (TxDOT). The team proposes to mount a development and demonstration program to field-test and evaluate markets for HyRadix?s LPG fuel processor system integrated into Plug Power?s residential-scale GenSys? 5C (5 kW) PEM fuel cell system in a variety of building types and conditions of service. The program?s primary goal is to develop, test, and install a prototype propane-fueled residential fuel cell power system supplied by Plug Power and HyRadix in Texas. The propane industry is currently funding development of an optimized propane fuel processor by project partner UOP/HyRadix through its national checkoff program, the Propane Education and Research Council (PERC). Following integration and independent verification of performance by Southwest Research Institute, Plug Power and HyRadix will produce a production-ready prototype unit for use in a field demonstration. The demonstration unit produced during this task will be delivered and installed at the Texas Department of Transportation?s TransGuide headquarters in San Antonio, Texas. Simultaneously, the team will undertake a market study aimed at identifying and quantifying early-entry customers, technical and regulatory requirements, and other challenges and opportunities that need to be addressed in planning commercialization of the units. For further information please contact Mary-Jo Rowan at mary-jo.rowan@cpa.state.tx.us

  13. Phase Chemistry of Tank Sludge Residual Components

    SciTech Connect (OSTI)

    J.L. Krumhansl

    2002-04-02T23:59:59.000Z

    The US Department of Energy (DOE) has millions of gallons of high level nuclear waste stored in underground tanks at Hanford, Washington and Savannah River, South Carolina. These tanks will eventually be emptied and decommissioned. This will leave a residue of sludge adhering to the interior tank surfaces that may contaminate nearby groundwaters with radionuclides and RCRA metals. Performance assessment (PA) calculations must be carried out prior to closing the tanks. This requires developing radionuclide release models from the sludges so that the PA calculations can be based on credible source terms. These efforts continued to be hindered by uncertainties regarding the actual nature of the tank contents and the distribution of radionuclides among the various phases. In particular, it is of vital importance to know what radionuclides are associated with solid sludge components. Experimentation on actual tank sludges can be difficult, dangerous and prohibitively expensive. The research funded under this grant for the past three years was intended to provide a cost-effective method for developing the needed radionuclide release models using non-radioactive artificial sludges. Insights gained from this work will also have more immediate applications in understanding the processes responsible for heel development in the tanks and in developing effective technologies for removing wastes from the tanks.

  14. Rapid Protein Structure Detection and Assignment using Residual Dipolar Couplings

    E-Print Network [OSTI]

    Rapid Protein Structure Detection and Assignment using Residual Dipolar Couplings Michael A substructures by exploiting the orientational constraint of residual dipolar coupling (RDC). PEPMORPH reverses: We have tested PEPMORPH on a variety of real proteins deposited in the Protein Data Base (PDB), using

  15. Computing Symmetrized Weight Enumerators for Lifted Quadratic Residue Codes

    E-Print Network [OSTI]

    Duursma, Iwan M.

    Computing Symmetrized Weight Enumerators for Lifted Quadratic Residue Codes I. M. Duursma Dept for the computation of structural parameters for ring-linear codes. This article therefore presents a method to eÃ?ciently compute weight enumerators of linear codes over primary integer residue rings. For the lifted QR-codes

  16. Minimization of welding residual stress and distortion in large structures

    E-Print Network [OSTI]

    Michaleris, Panagiotis

    1 Minimization of welding residual stress and distortion in large structures P. Michaleris at Champaign Urbana, Urbana, IL Abstract Welding distortion in large structures is usually caused by buckling due to the residual stress. In cases where the design is fixed and minimum weld size requirements

  17. Modeling Sustainable Agricultural Residue Removal at the Subfield Scale

    SciTech Connect (OSTI)

    Muth, D.J.; McCorkle, D.S.; Koch, J.B.; Bryden, K.M.

    2012-05-02T23:59:59.000Z

    This study developed a computational strategy that utilizes data inputs from multiple spatial scales to investigate how variability within individual fields can impact sustainable residue removal for bioenergy production. Sustainable use of agricultural residues for bioenergy production requires consideration of the important role that residues play in limiting soil erosion and maintaining soil C, health, and productivity. Increased availability of subfield-scale data sets such as grain yield data, high-fidelity digital elevation models, and soil characteristic data provides an opportunity to investigate the impacts of subfield-scale variability on sustainable agricultural residue removal. Using three representative fields in Iowa, this study contrasted the results of current NRCS conservation management planning analysis with subfield-scale analysis for rake-and-bale removal of agricultural residue. The results of the comparison show that the field-average assumptions used in NRCS conservation management planning may lead to unsustainable residue removal decisions for significant portions of some fields. This highlights the need for additional research on subfield-scale sustainable agricultural residue removal including the development of real-time variable removal technologies for agricultural residue.

  18. Residual Energy-Aware Cooperative Transmission (REACT) in Wireless Networks

    E-Print Network [OSTI]

    Leung, Kin K.

    Residual Energy-Aware Cooperative Transmission (REACT) in Wireless Networks Erwu Liu, Qinqing Zhang the lifetime of the network and we call the selection method a residual energy-aware cooperative transmission- works, where energy efficiency is a critical design consideration. We assume that multiple relay nodes

  19. RESIDUAL STRESS EFFECTS IN FRACTURE OF COMPOSITES AND ADHESIVES

    E-Print Network [OSTI]

    Nairn, John A.

    RESIDUAL STRESS EFFECTS IN FRACTURE OF COMPOSITES AND ADHESIVES JOHN A. NAIRN ABSTRACT Because composites and adhesive joints are made from different phases with different thermal expansion coefficients, they inevitably develop residual thermal stresses. When designing composites or adhesive joints, it is important

  20. Conversion of direct process high-boiling residue to monosilanes

    DOE Patents [OSTI]

    Brinson, Jonathan Ashley (Vale of Glamorgan, GB); Crum, Bruce Robert (Madison, IN); Jarvis, Jr., Robert Frank (Midland, MI)

    2000-01-01T23:59:59.000Z

    A process for the production of monosilanes from the high-boiling residue resulting from the reaction of hydrogen chloride with silicon metalloid in a process typically referred to as the "direct process." The process comprises contacting a high-boiling residue resulting from the reaction of hydrogen chloride and silicon metalloid, with hydrogen gas in the presence of a catalytic amount of aluminum trichloride effective in promoting conversion of the high-boiling residue to monosilanes. The present process results in conversion of the high-boiling residue to monosilanes. At least a portion of the aluminum trichloride catalyst required for conduct of the process may be formed in situ during conduct of the direct process and isolation of the high-boiling residue.

  1. DDT RESIDUES IN SEAWATER AND PARTICULATE MATTER IN THE CALIFORNIA CURRENT SYSTEM

    E-Print Network [OSTI]

    DDT RESIDUES IN SEAWATER AND PARTICULATE MATTER IN THE CALIFORNIA CURRENT SYSTEM JAMES L. COX in the California current system were analyzed for DDT residues. DDT residue concentrations in whole seawater are discussed in relation to mechanisms of land-sea DDT residue transfer. DDT residue concentrations

  2. A manual for implementing residual radioactive material guidelines

    SciTech Connect (OSTI)

    Gilbert, T.L.; Yu, C.; Yuan, Y.C.; Zielen, A.J.; Jusko, M.J.; Wallo, A. III

    1989-06-01T23:59:59.000Z

    This manual presents information for implementing US Department of Energy (DOE) guidelines for residual radioactive material at sites identified by the Formerly Utilized Sites Remedial Action Program (FUSRAP) and the Surplus Facilities Management Program (SFMP). It describes the analysis and models used to derive site-specific guidelines for allowable residual concentrations of radionuclides in soil and the design and use of the RESRAD computer code for calculating guideline values. It also describes procedures for implementing DOE policy for reducing residual radioactivity to levels that are as low as reasonably achievable. 36 refs., 16 figs, 22 tabs.

  3. Asphalt landscape after all : residual suburban surface as public infrastructure

    E-Print Network [OSTI]

    O'Connor, Joseph Michael, M. Arch. Massachusetts Institute of Technology

    2011-01-01T23:59:59.000Z

    The thesis proposes a hybridized commercial retail strip inserted into a residual suburban condition as a manner of investigating the latent potential of suburban logic, both its constituent elements and its formal rules ...

  4. Residual stress in electrodeposited nanocrystalline nickel-tungsten coatings

    E-Print Network [OSTI]

    Ziebell, Tiffany D.

    Characterizing the residual stress of thick nanocrystalline electrodeposits poses several unique challenges due to their fine grain structure, thickness distribution, and matte surface. We use a three-dimensional ...

  5. FIXED PRICE RESIDUAL FUNDS POLICY Policy dated March 29, 1999

    E-Print Network [OSTI]

    Weston, Ken

    FIXED PRICE RESIDUAL FUNDS POLICY Policy dated March 29, 1999 After completion of all deliverables required under a fixed-price award, after costs in fulfilling the requirements of the award have been

  6. Minimizing High Spatial Frequency Residual in Active Space Telescope Mirrors

    E-Print Network [OSTI]

    . Miller June 2008 SSL # 4-08 #12;#12;Minimizing High Spatial Frequency Residual in Active Space Telescope Mirrors Thomas Gray, David W. Miller June 2008 SSL # 4-08 This work is based on the unaltered text

  7. An urban infill : a residual site in Boston

    E-Print Network [OSTI]

    Savvides, Andreas L. (Andreas Loucas)

    1996-01-01T23:59:59.000Z

    This thesis is concerned with the treatment of residual sites in the context of the urban environment and in particular with the wounds inflicted by the passage of the Massachusetts Turnpike through the city of Boston. The ...

  8. RetroFILL : residual spaces as urban infill

    E-Print Network [OSTI]

    Kobel, Marika

    2010-01-01T23:59:59.000Z

    In any city there are small slivers and chunks of awkward spaces - in between buildings, occupying edge conditions, not large enough to warrant many forms of traditional use - which can be termed residual. These areas of ...

  9. Residual dust charges in an afterglow plasma , M. Mikikian

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    plasma was performed in a rf discharge. An upward thermophoretic force was used to balance]. For the study concerning residual charges, the top electrode was cooled. An upward thermophoretic force

  10. RELATIVE RESIDUAL BOUNDS FOR INDEFINITE SINGULAR HERMITIAN MATRICES

    E-Print Network [OSTI]

    Truhar, Ninoslav

    residual bounds, indefinite Hermitian matrix, eigen- values, perturbation theory, relative perturbations. These theorems are proper generalization of results on a semi-definite Hermitian matrix SIAM Journal on Matrix

  11. Palatability of post-extraction algal residue as a protein supplement for cattle.

    SciTech Connect (OSTI)

    Drewery, M. L. [Texas A& M University; Sawyer, J. E. [Texas A& M University; Wickersham, T. A. [Texas A& M University

    2012-12-01T23:59:59.000Z

    Market value of post-extraction algal residue (PEAR) is driven by its ability to compete with commonly fed protein sources; for example cottonseed meal (CSM) and dried distillers’ grains (DDG). An initial step in evaluating PEAR (20% CP, 59% OM) is to determine palatability when fed as a protein supplement. Accordingly, we evaluated the palatability of PEAR-containing supplements in cattle consuming a basal diet of Bermudagrass (13% CP, 76% NDF). Twelve steers were used in a 12 × 12 Latin square experiment consisting of 12 4-d periods. Each period included 3-d where steers were fed a test supplement and a 1-d washout where steers were fed DDG. Supplements were formulated with different carrier ingredients (DDG, CSM, or liquid supplement, LS) and different levels of PEAR inclusion (0, 20, 40, and 60% for DDG and CSM and 0, 33, 66, and 100% for LS). Intake and time required for consumption were recorded daily. A significant (P < 0.05) treatment × day interaction for g consumed per min (GPM) was observed. This interaction resulted from changing rates of consumption as cattle adapted to supplements. Supplements containing DDG had the greatest rates of consumption (177 – 187 GPM), followed by CSM supplements (148 – 166 GPM). Blends including PEAR and LS had slower rates of consumption (58 – 93 GPM). Supplement formulation significantly (P < 0.05) affected the amount of supplement consumed and time required for complete consumption. Supplements which contained DDG or CSM were consumed in less than 11 min; complete consumption was observed 92 – 100% of the time. Treatments containing LS required more time for complete consumption (21 – 33 min) and were finished 77 – 96% of the time. Our results suggest PEAR can be blended (up to 60%) with existing ingredients utilized in beef rations to create suitable protein supplements. However, PEAR is not palatable when offered alone (complete consumption of 100% PEAR occurred 77.5% of the time and required 31.5 min) or incorporated into LS. Additional research is necessary to determine the impact of PEAR on nutrient utilization in cattle.

  12. GEOCHEMICAL TESTING AND MODEL DEVELOPMENT - RESIDUAL TANK WASTE TEST PLAN

    SciTech Connect (OSTI)

    CANTRELL KJ; CONNELLY MP

    2010-03-09T23:59:59.000Z

    This Test Plan describes the testing and chemical analyses release rate studies on tank residual samples collected following the retrieval of waste from the tank. This work will provide the data required to develop a contaminant release model for the tank residuals from both sludge and salt cake single-shell tanks. The data are intended for use in the long-term performance assessment and conceptual model development.

  13. Characterization of flue gas residues from municipal solid waste combustors

    SciTech Connect (OSTI)

    Forestier, L.L. [CRPG-CNRS, Vandoeuvre-les-Nancy (France)] [CRPG-CNRS, Vandoeuvre-les-Nancy (France); [ENSG, Vandoeuvre-les-Nancy (France); Libourel, G. [CRPG-CNRS, Vandoeuvre-les-Nancy (France)] [CRPG-CNRS, Vandoeuvre-les-Nancy (France); [Univ. H. Poincare, Vandoeuvre-les-Nancy (France)

    1998-08-01T23:59:59.000Z

    Solid residues recovered from treatment of flue gas resulting from the combustion of municipal solid waste (MSW) are of particular concern because of ever-increasing worldwide production rates and their concentrations of potentially hazardous transition elements and heavy metals. Three main residue types have been studied in this study: electrostatic precipitator ashes, wet filter cakes, and semidry scrubber residues. Using a large number of residues from two French MSW combustion (MSWC) facilities, the aim of this work is to determine their chemistry and mineralogy in order to shed light on their potential toxicity. The authors find that pollutant concentrations are dependent not only on the composition of MSW but also on the size of particles and flue gas treatment process. Using a procedure based on leaching, grain-size, density, and magnetic separations, the authors present a detailed description of the mineralogy of MSWC solid residues. These residues consist of a very heterogeneous assemblage of glasses, metals, and other crystals in which polluting elements are distributed. The results of this characterization will therefore help to contribute to the development of adequate waste management strategies.

  14. Residual stresses and stress corrosion cracking in pipe fittings

    SciTech Connect (OSTI)

    Parrington, R.J.; Scott, J.J.; Torres, F.

    1994-06-01T23:59:59.000Z

    Residual stresses can play a key role in the SCC performance of susceptible materials in PWR primary water applications. Residual stresses are stresses stored within the metal that develop during deformation and persist in the absence of external forces or temperature gradients. Sources of residual stresses in pipe fittings include fabrication processes, installation and welding. There are a number of methods to characterize the magnitude and orientation of residual stresses. These include numerical analysis, chemical cracking tests, and measurement (e.g., X-ray diffraction, neutron diffraction, strain gage/hole drilling, strain gage/trepanning, strain gage/section and layer removal, and acoustics). This paper presents 400 C steam SCC test results demonstrating that residual stresses in as-fabricated Alloy 600 pipe fittings are sufficient to induce SCC. Residual stresses present in as-fabricated pipe fittings are characterized by chemical cracking tests (stainless steel fittings tested in boiling magnesium chloride solution) and by the sectioning and layer removal (SLR) technique.

  15. Opportunities and Challenges for Nondestructive Residual Stress Assessment

    SciTech Connect (OSTI)

    Nagy, P. B. [Department of Aerospace Engineering and Engineering Mechanics, University of Cincinnati, Cincinnati, Ohio 45221-0070 (United States)

    2006-03-06T23:59:59.000Z

    For a long time, nondestructive residual stress assessment has been one of the greatest opportunities as well as one of the greatest challenges for the NDE community, and probably it will remain so in the foreseeable future. The most critical issue associated with nondestructive residual stress assessment seems to be that of selectivity. Numerous NDE methods have been found to be sufficiently sensitive to the presence of residual stress, but unfortunately also rather sensitive to other spurious variations that usually accompany residual stresses, such as anisotropic texture, microstructural inhomogeneity, plastic deformation, etc., which could interfere with, or even overshadow, the elastic strain caused by the sought residual stress. The only sufficiently selective NDE method that is more or less immune from these spurious effects is X-ray diffraction measurement, which however does not have the required penetration depth in most applications unless high-energy neutron radiation is used. It is timely for the community to sit back and ask where we are in this important area. This paper presents an overview of the various indirect techniques that have been used to measure residual stress in the past. It is shown that traditional techniques have a number of limitations, which have spurred several recent research programs. Some of the new techniques that are presently being examined in the NDE community are reviewed and the current status of these research efforts is assessed.

  16. E-Print Network 3.0 - assess residue contributions Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Waste Incinerators in England and Summary: . To assess the risks to health from ash and air pollution control residues, the Agency assessed the risks... Solid Residues from...

  17. E-Print Network 3.0 - acceptable residual magnetic Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    residual limb. A small Neodymium-Iron-Boron magnet... of a small permanent magnet into the distal residual ... Source: Peshkin, Michael A.- Department of Mechanical...

  18. INNOVATION EDUCATION EXCELLENCE DISTILLATIONS

    E-Print Network [OSTI]

    Chan, Hue Sun

    . Our Department is a powerhouse in the area of chem- istry applied to medicine. Andrei Yudin and his

  19. (distillation) (Le Chatelier

    E-Print Network [OSTI]

    Hong, Deog Ki

    acetate(methyl-, ethyl-, butyl-) , methanol isobutene MTBE , ethanol isobutene ETBE , methanol 2-methyl-1% MTBE 3 DMC . 2% 1990 MTBE 1999 3 2002 MTBE . [ 1-1 ] Phosgene process polycarbonate(PC) 50/ . DMC DMC MTBE / . ( : Amoco, "Review of DMC Manufacture and its

  20. A Characterization and Evaluation of Coal Liquefaction Process Streams. Results of Inspection Tests on Nine Coal-Derived Distillation Cuts in the Jet Fuel Boiling Range

    SciTech Connect (OSTI)

    S. D. Brandes; R. A. Winschel

    1999-12-30T23:59:59.000Z

    This report describes the assessment of the physical and chemical properties of the jet fuel (180-300 C) distillation fraction of nine direct coal liquefaction products and compares those properties to the corresponding specifications for aviation turbine fuels. These crude coal liquids were compared with finished fuel specifications specifically to learn what the refining requirements for these crudes will be to make them into finished fuels. The properties of the jet fuel fractions were shown in this work to require extensive hydrotreating to meet Jet A-1 specifications. However, these materials have a number of desirable qualities as feedstocks for the production of high energy-density jet fuels.

  1. Dissolution and compaction of albite sand in distilled water and pH-buffered carboxylic acid solutions: experiments at 100 degrees and 160 degrees C

    E-Print Network [OSTI]

    Carpenter, Thomas Doyle

    1995-01-01T23:59:59.000Z

    . The confining fluid was either distilled water or a mixture of 3 parts Kerosene and 1 part SAE-30 non-detergent motor oil; confining pressure was controlled by an air- operated Sprague? pump. Inside the pressure vessel, the reaction cell (10 cm x 4. 4 cm O. D... sand. Fluid flows in and out of the reaction cell through Hastelloy C-276? lines. Slow flow rates (0. 08 ml/hr) and pore fluid pressures were controlled by an Isco? micro-processor syringe pump and a manually operated HiP? synnge pump. Rapid flow...

  2. Start up results from a specialized flue gas cleaning facility in a power station using refinery residues

    SciTech Connect (OSTI)

    Beiers, H.G.; Gilgen, R.; Weiler, H.

    1998-07-01T23:59:59.000Z

    In eastern Germany STEAG--the biggest German IPP--has erected a power plant consisting of three combustion lines burning oil distillation residues from the new Mider refinery to provide the refinery with power, steam, water and compressed air. Each of the three flue gas cleaning lines consists of a high dust SCR-system, quench, wet electrostatic precipitator, scrubber, steam reheater and ID-fan. Common systems are the storage and handling of the absorbent, the gypsum dewatering and the waste water treatment. The installed high dust SCR system attains the expected NO{sub x}-reduction efficiency and an excellent NO{sub x} outlet distribution and low ammonia slip. After commissioning problems occurred with the wet ESP in all three lines due to improper function of the upstream quenches. Modifications of the quench system have been made which assure a temperature of the flue gas after quench near saturation temperature and correct functioning of the quench and wet ESP. To reduce pressure loss of the absorber concurrent spray nozzles were installed. Strong vibrations of the absorber tower, the connected pipes and the steel structure along with an insufficient SO{sub x} removal efficiency at high inlet concentration were observed. After changing the concurrent operation of the spray nozzles to counter current operation the vibrations of the absorber tower became smaller and the removal efficiency achieved the guaranteed value. Problems arose in the waste water treatment plant caused by the high solid concentration of up to 1,000 g/l in the thickener. By diluting the settled sludge with overflow water from the thickener the problems in the waste water treatment plant could be minimized to an acceptable degree. Despite these problems the flue gas cleaning system is in continuous operation and the emission values of flue gas and waste water meet the required standards.

  3. Measuring depth profiles of residual stress with Raman spectroscopy

    SciTech Connect (OSTI)

    Enloe, W.S.; Sparks, R.G.; Paesler, M.A.

    1988-12-01T23:59:59.000Z

    Knowledge of the variation of residual stress is a very important factor in understanding the properties of machined surfaces. The nature of the residual stress can determine a part`s susceptibility to wear deformation, and cracking. Raman spectroscopy is known to be a very useful technique for measuring residual stress in many materials. These measurements are routinely made with a lateral resolution of 1{mu}m and an accuracy of 0.1 kbar. The variation of stress with depth; however, has not received much attention in the past. A novel technique has been developed that allows quantitative measurement of the variation of the residual stress with depth with an accuracy of 10nm in the z direction. Qualitative techniques for determining whether the stress is varying with depth are presented. It is also demonstrated that when the stress is changing over the volume sampled, errors can be introduced if the variation of the stress with depth is ignored. Computer aided data analysis is used to determine the depth dependence of the residual stress.

  4. DDT residues in human milk samples from Delhi, India

    SciTech Connect (OSTI)

    Zaidi, S.S.A.; Bhatnagar, V.K.; Banerjee, B.D.; Balakrishnan, G.; Shah, M.P.

    1989-03-01T23:59:59.000Z

    The widespread use of DDT in India has resulted in increased levels of the insecticide in the ecosystem and, therefore, the potential possible health hazards has been voiced. DDT-residues excreted in milk have been reported from different parts of the world; however, very few reports did appear from India. In fact, there is no report on DDT-content in human milk from Delhi area where higher levels of DDT and BHC in human adipose tissues and blood have already been reported. Higher bioaccumulation of DDT might reflect the higher excretion of residues in milk. The authors have, therefore, attempted a systematic study to monitor DDT-residues in human milk samples collected from various hospitals of Delhi (India).

  5. Prediction of middle-distillate fuel properties using liquid chromatography-proton nuclear magnetic resonance spectroscopy data. Final report, 1987-1988

    SciTech Connect (OSTI)

    Swann, M.

    1989-06-01T23:59:59.000Z

    This research was initiated to support the Army's capability to identify the components of fuels that contribute to low-temperature performance of fuels. It was discovered that various physical properties of middle-distillate fuels can be predicted. The LC-{sup 1}HNMR technique was developed to predict physical properties based on chemical structures present in the fuels. The prediction of properties is approached from a 'group property' point of view. In the group property approach, the structure of the molecule is examined for structural features that dictate the physical properties of the compounds. In other words, the physical properties of a molecule or compound are determined by the number of types of chemical groups, i.e., methyl, methylene, methine, etc., present. These LC-{sup 1}H NMR predicted property measurements were compared to measurements obtained by the ASTM fuel tests. Most measurements were found to be within experimental error. The research has demonstrated that the LC-{sup 1}H NMR approach for measuring various middle-distillate fuel properties can be used as an alternative to the ASTM methods of fuel property measurement.

  6. Single-Step Syngas-to-Distillates (S2D) Process Based on Biomass-Derived Syngas – A Techno-Economic Analysis

    SciTech Connect (OSTI)

    Zhu, Yunhua; Jones, Susanne B.; Biddy, Mary J.; Dagle, Robert A.; Palo, Daniel R.

    2012-08-01T23:59:59.000Z

    This study reports the comparison of biomass gasification based syngas-to-distillate (S2D) systems using techno-economic analysis (TEA). Three cases, state of technology (SOT) case, goal case, and conventional case, were compared in terms of performance and cost. The SOT case and goal case represent technology being developed at Pacific Northwest National Laboratory for a process starting with syngas using a single-step dual-catalyst reactor for distillate generation (S2D process). The conventional case mirrors the two-step S2D process previously utilized and reported by Mobil using natural gas feedstock and consisting of separate syngas-to-methanol and methanol-to-gasoline (MTG) processes. Analysis of the three cases revealed that the goal case could indeed reduce fuel production cost over the conventional case, but that the SOT was still more expensive than the conventional. The SOT case suffers from low one-pass yield and high selectivity to light hydrocarbons, both of which drive up production cost. Sensitivity analysis indicated that light hydrocarbon yield, single pass conversion efficiency, and reactor space velocity are the key factors driving the high cost for the SOT case.

  7. Single-Step Syngas-to-Distillates (S2D) Process Based on Biomass-Derived Syngas - A Techno-Economic Analysis

    SciTech Connect (OSTI)

    Zhu, Y.; Jones, S. B.; Biddy, M. J.; Dagle, R. A.; Palo, D. R.

    2012-08-01T23:59:59.000Z

    This study compared biomass gasification based syngas-to-distillate (S2D) systems using techno-economic analysis (TEA). Three cases, state of technology (SOT), goal, and conventional, were compared in terms of performance and cost. The SOT case represented the best available experimental results for a process starting with syngas using a single-step dual-catalyst reactor for distillate generation. The conventional case mirrored a conventional two-step S2D process consisting of separate syngas-to-methanol and methanol-to-gasoline (MTG) processes. The goal case assumed the same performance as the conventional, but with a single-step S2D technology. TEA results revealed that the SOT was more expensive than the conventional and goal cases. The SOT case suffers from low one-pass yield and high selectivity to light hydrocarbons, both of which drive up production cost. Sensitivity analysis indicated that light hydrocarbon yield and single pass conversion efficiency were the key factors driving the high cost for the SOT case.

  8. Wave induced residual pore-water pressures in sandbeds

    E-Print Network [OSTI]

    DeVries, Jack Walter

    1986-01-01T23:59:59.000Z

    Subject: Ocean Engineering WAVE INDUCED RESIDUAL PORE-WATER PRESSURES IN SANDBEDS A Thesis by Jack W. Deyries Approved as to style and content by: J. B. Her bich (Chairman of Committee) Y. K. Lou (Member) W. A. Dunlap (Member) R. O. Reid (Member...-Water Pressure . . . . . 43 Development of Residual Pore-Mater Pressure 46 14 15 16 17 18 19 20 Wave Height Recording Pore-Water Pressure Recording Permeability of Sand Permeability of Glass Beads Wave Form (least steep) Wave Form (middle steepness...

  9. A Residual Mass Ballistic Testing Method to Compare Armor Materials or Components (Residual Mass Ballistic Testing Method)

    SciTech Connect (OSTI)

    Benjamin Langhorst; Thomas M Lillo; Henry S Chu

    2014-05-01T23:59:59.000Z

    A statistics based ballistic test method is presented for use when comparing multiple groups of test articles of unknown relative ballistic perforation resistance. The method is intended to be more efficient than many traditional methods for research and development testing. To establish the validity of the method, it is employed in this study to compare test groups of known relative ballistic performance. Multiple groups of test articles were perforated using consistent projectiles and impact conditions. Test groups were made of rolled homogeneous armor (RHA) plates and differed in thickness. After perforation, each residual projectile was captured behind the target and its mass was measured. The residual masses measured for each test group were analyzed to provide ballistic performance rankings with associated confidence levels. When compared to traditional V50 methods, the residual mass (RM) method was found to require fewer test events and be more tolerant of variations in impact conditions.

  10. Computer aided analysis for residual stress measurement using ultrasonic techniques

    E-Print Network [OSTI]

    Kypa, Jagan Mohan

    1999-01-01T23:59:59.000Z

    to detect travel-times with a precision of 0. l nanoseconds and an accuracy of less than 2.5 nanoseconds. A residual stress reference standard developed for previous research was used as the sample to measure travel-times. The sample was designed...

  11. Removal of residual particulate matter from filter media

    DOE Patents [OSTI]

    Almlie, Jay C; Miller, Stanley J

    2014-11-11T23:59:59.000Z

    A method for removing residual filter cakes that remain adhered to a filter after typical particulate removal methodologies have been employed, such as pulse-jet filter element cleaning, for all cleanable filters used for air pollution control, dust control, or powder control.

  12. Modeling, Optimization and Economic Evaluation of Residual Biomass Gasification

    E-Print Network [OSTI]

    Georgeson, Adam

    2012-02-14T23:59:59.000Z

    . .............................................................................. 7 Table 2. Components Used in Simulation. ...................................................................... 20 Table 3. Composition of Biomass Feedstock to Biorefinery. ......................................... 43 Table 4. Operating... for optimizing gasification plant design from an economic perspective. Specifically, the problem addressed in this work is stated as follows: Given are: ? A set of biomass feedstocks {i|i = 1,2,?,I } which includes fresh as well as residue biomass ? A set...

  13. PROPERTIES OF RESIDUALS FOR SPATIAL POINT PROCESSES A. BADDELEY,

    E-Print Network [OSTI]

    Baddeley, Adrian

    PROPERTIES OF RESIDUALS FOR SPATIAL POINT PROCESSES A. BADDELEY, University of Western Australia J. MØLLER, University of Aalborg A.G. PAKES, University of Western Australia Abstract For any point process & Statistics M019, University of Western Australia, 35 Stirling Highway, Nedlands WA 6009, Australia Postal

  14. COMMUNICATION Are Residues in a Protein Folding Nucleus

    E-Print Network [OSTI]

    Dai, Yang

    COMMUNICATION Are Residues in a Protein Folding Nucleus Evolutionarily Conserved? Yan Yuan Tseng is the hallmark of life. It is important to understand how protein folding and evolution influence each other in protein folding nucleus as measured by experi- mental f-value and selection pressure as measured by v

  15. Trigeneration in a northern Chinese village using crop residues

    E-Print Network [OSTI]

    Gasification of crop residues can provide modern energy carriers to rural areas at potentially at- tractive in rural areas of developing countries by the introduction of mod- ern, clean energy carriers (e.g., fluid the prospects for providing such energy carriers to a rural village in Jilin province, China: clean gas

  16. AIAA-2001-0025 SPECTRUM FATIGUE LIFETIME AND RESIDUAL STRENGTH

    E-Print Network [OSTI]

    on a typical fiberglass laminate configuration turbine blade fiberglass material has been undertaken under at various fractions of the lifetime turbine blade materials.. are consistent with the residual strength of fiberglass spectrum have been studied. Data have been obtained for materials produce results that may

  17. Ammonia volatilization from soils with surface rice straw residue

    E-Print Network [OSTI]

    Barghassa, Peyam

    1995-01-01T23:59:59.000Z

    rice residue and related factors on NH3 volatilization from an acid Beaumont clay (pH 5.4) and an alkaline Lake Charles clay (pH 7.4). The treatments in the greenhouse and lab consisted of all possible combinations of the following variables: surface...

  18. Sorption characteristics of polycyclic aromatic hydrocarbons in aluminum smelter residues

    SciTech Connect (OSTI)

    Gijs D. Breedveld; Emilien Pelletier; Richard St. Louis; Gerard Cornelissen [Norwegian Geotechnical Institute, Oslo (Norway)

    2007-04-01T23:59:59.000Z

    High temperature carbon oxidation in primary aluminum smelters results in the release of polycyclic aromatic hydrocarbons (PAH) into the environment. The main source of PAH are the anodes, which are composed of petroleum coke (black carbon, BC) and coal tar pitch. To elucidate the dominant carbonaceous phase controlling the environmental fate of PAH in aluminum smelter residues (coke BC and/or coal tar), the sorptive behavior of PAHs has been determined, using passive samplers and infinite-sink desorption methods. Samples directly from the wet scrubber were studied as well as ones from an adjacent 20-year old storage lagoon and roof dust from the smelter. Carbon-normalized distribution coefficients of native PAHs were 2 orders of magnitude higher than expected based on amorphous organic carbon (AOC)/water partitioning, which is in the same order of magnitude as reported literature values for soots and charcoals. Sorption isotherms of laboratory-spiked deuterated phenanthrene showed strong (about 100 times stronger than AOC) but nonetheless linear sorption in both fresh and aged aluminum smelter residues. The absence of nonlinear behavior typical for adsorption to BC indicates that PAH sorption in aluminum smelter residues is dominated by absorption into the semi-solid coal tar pitch matrix. Desorption experiments using Tenax showed that fresh smelter residues had a relatively large rapidly desorbing fraction of PAH (35-50%), whereas this fraction was strongly reduced (11-16%) in the lagoon and roof dust material. Weathering of the coal tar residue and/or redistribution of PAH between coal tar and BC phases could explain the reduced availability in aged samples. 38 refs., 5 figs., 1 tab.

  19. Residual stresses in dielectrics caused by metallization lines and pads

    SciTech Connect (OSTI)

    He, M.Y.; Lipkin, J.; Clarke, D.R. [Univ. of California, Santa Barbara, CA (United States). Materials Dept.] [Univ. of California, Santa Barbara, CA (United States). Materials Dept.; Evans, A.G. [Harvard Univ., Cambridge, MA (United States). Div. of Applied Sciences] [Harvard Univ., Cambridge, MA (United States). Div. of Applied Sciences; Tenhover, M. [Carborundum Co., Niagara Falls, NY (United States)] [Carborundum Co., Niagara Falls, NY (United States)

    1996-06-01T23:59:59.000Z

    Residual stresses in dielectrics and semiconductors induced by metal lines, pads and vias can have detrimental effects on the performance of devices and electronic packages. Analytical and numerical calculations of these stresses have been performed for two purposes. (1) To illustrate how these stresses relate to the residual stress in the metallization and its geometry; (2) to calibrate a piezo-spectroscopic method for measuring these stresses with high spatial resolution. The results of the calculations have been presented using non-dimensional parameters that both facilitate scaling and provide connections to the stresses in the metal, with or without yielding. Preliminary experimental results obtained for Au/Ge eutectic pads illustrate the potential of the method and the role of the stress analysis.

  20. The Dissolution of Desicooler Residues in H-Canyon Dissolvers

    SciTech Connect (OSTI)

    Gray, J.H.

    2003-06-23T23:59:59.000Z

    A series of dissolution and characterization studies has been performed to determine if FB-Line residues stored in desicooler containers will dissolve using a modified H-Canyon processing flowsheet. Samples of desicooler materials were used to evaluate dissolving characteristics in the low-molar nitric acid solutions used in H-Canyon dissolvers. The selection for the H-Canyon dissolution of desicooler residues was based on their high-enriched uranium content and trace levels of plutonium. Test results showed that almost all of the enriched uranium will dissolve from the desicooler materials after extended boiling in one molar nitric acid solutions. The residue that contained uranium after completion of the extended boiling cycle consisted of brown solids that had agglomerated into large pieces and were floating on top of the dissolver solution. Addition of tenth molar fluoride to a three molar nitric acid solution containing boron did not dissolve remaining uranium from the brown solids. Only after boiling in an eight molar nitric acid-tenth molar fluoride solution without boron did remaining uranium and aluminum dissolve from the brown solids. The amount of uranium associated with brown solids would be approximately 1.4 percent of the total uranium content of the desicooler materials. The brown solids that remain in the First Uranium Cycle feed will accumulate at the organic/aqueous interface during solvent extraction operations. Most of the undissolved white residue that remained after extended boiling was aluminum oxide containing additional trace quantities of impurities. However, the presence of mercury used in H-Canyon dissolvers should complete the dissolution of these aluminum compounds.

  1. Combustion of textile residues in a packed bed

    SciTech Connect (OSTI)

    Ryu, Changkook; Phan, Anh N.; Sharifi, Vida N.; Swithenbank, Jim [Sheffield University Waste Incineration Centre (SUWIC), Department of Chemical and Process Engineering, The University of Sheffield, Mappin Street, Sheffield S1 3JD (United Kingdom)

    2007-08-15T23:59:59.000Z

    Textile is one of the main components in the municipal waste which is to be diverted from landfill for material and energy recovery. As an initial investigation for energy recovery from textile residues, the combustion of cotton fabrics with a minor fraction of polyester was investigated in a packed bed combustor for air flow rates ranging from 117 to 1638 kg/m{sup 2} h (0.027-0.371 m/s). Tests were also carried out in order to evaluate the co-combustion of textile residues with two segregated waste materials: waste wood and cardboard. Textile residues showed different combustion characteristics when compared to typical waste materials at low air flow rates below 819 kg/m{sup 2} h (0.186 m/s). The ignition front propagated fast along the air channels randomly formed between packed textile particles while leaving a large amount of unignited material above. This resulted in irregular behaviour of the temperature profile, ignition rate and the percentage of weight loss in the ignition propagation stage. A slow smouldering burn-out stage followed the ignition propagation stage. At air flow rates of 1200-1600 kg/m{sup 2} h (0.272-0.363 m/s), the bed had a maximum burning rate of about 240 kg/m{sup 2} h consuming most of the combustibles in the ignition propagation stage. More uniform combustion with an increased burning rate was achieved when textile residues were co-burned with cardboard that had a similar bulk density. (author)

  2. The effect of magnetic flutter on residual flow

    SciTech Connect (OSTI)

    Terry, P. W.; Pueschel, M. J.; Carmody, D. [Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States)] [Department of Physics, University of Wisconsin-Madison, Madison, Wisconsin 53706 (United States); Nevins, W. M. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)] [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)

    2013-11-15T23:59:59.000Z

    The hypothesis that stochastic magnetic fields disrupt zonal flows associated with ion temperature gradient turbulence saturation is investigated analytically with a residual flow calculation in the presence of magnetic flutter. The calculation starts from the time-asymptotic zero-beta residual flow of Rosenbluth and Hinton [Phys. Rev. Lett. 80, 724 (1998)] with the sudden application of an externally imposed, fixed magnetic field perturbation. The short-time electron response from radial charge loss due to magnetic flutter is calculated from the appropriate gyrokinetic equation. The potential evolution has quadratic behavior, with a zero crossing at finite time. The crossing time and its parametric dependencies are compared with numerical results from a gyrokinetic simulation of residual flow in the presence of magnetic flutter. The numerical and analytical results are in good agreement and support the hypothesis that the high-beta runaway of numerical simulations is a result of the disabling of zonal flows by finite-beta charge losses associated with magnetic flutter.

  3. Residual Stress Evaluation within a Crimped Splice Connector Assembly

    SciTech Connect (OSTI)

    Wang, Jy-An John [ORNL; An, Ke [ORNL; Lara-Curzio, Edgar [ORNL; Hubbard, Camden R [ORNL; King Jr, Thomas J [ORNL; Graziano, Joe [Tennessee Valley Authority (TVA); Chan, John [Electric Power Research Institute (EPRI)

    2006-01-01T23:59:59.000Z

    In power transmission, connectors play an important role in the efficiency and reliability of the system. Due to the increase of power demand and lack of new infrastructure, existing overhead power transmission lines often need to operate at temperatures higher than the original design criteria. However, this had led to the accelerated aging and degradation of splice connectors, which has been manifested by the formation of hot-spots that have been revealed by infrared imaging during inspection of transmission lines operating at elevated temperatures. The implications of connector aging is two-fold: (1) significant increase in resistivity of the splice connector (i.e., less efficient transmission of electricity) and (2) significant reduction in the connector clamping strength, which ultimately results in separation of the power transmission line at the joint. Therefore, the splice connector has become the weakest link in the electric power transmission infrastructure. The compressive residual stresses induced by the crimping process within the splice provide the clamping forces to secure the conductor and therefore, the determination of the state of residual stresses in splice connectors is a necessary requirement to provide an accurate estimate of their service lifetime. This paper presents a protocol of utilizing finite-element analysis and neutron scattering experiments for evaluating the residual stress fields within a crimped single-stage splice connector assembly.

  4. THE METHOD OF CONJUGATE RESIDUALS FOR SOLVING THE GALERKIN EQUATIONS ASSOCIATED WITH SYMMETRIC

    E-Print Network [OSTI]

    Plato, Robert

    kind integral equations, conjugate gradient type methods, Galerkin method, regularization schemesTHE METHOD OF CONJUGATE RESIDUALS FOR SOLVING THE GALERKIN EQUATIONS ASSOCIATED WITH SYMMETRIC, the method of conjugate residuals is consid- ered. An a posteriori stopping rule is introduced

  5. Making Photosynthetic Biofuel Renewable: Recovering Phosphorus from Residual Biomass J. M. Gifford and P. Westerhoff

    E-Print Network [OSTI]

    Hall, Sharon J.

    Making Photosynthetic Biofuel Renewable: Recovering Phosphorus from Residual Biomass J. M. Gifford to global warming. Biofuel from phototrophic microbes like algae and bacteria provides a viable substitute improves biofuel sustainability by refining phosphorus recycling. Biomass Production Residual Biomass

  6. E-Print Network 3.0 - aspartic acid residues Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scott1 and Barry LStoddard 2* Summary: -links are each consistent with a parallel coiled coil structure, residues 1-36 of the aspartate receptor were... residues 23-180 of the...

  7. E-Print Network 3.0 - acid residues involved Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    contacts, however... acid residues with small side-chains (Gly, Ala, Ser, Cys) allow tight helix packing by mediating strong... ) amino acid residues. We propose the use of the...

  8. E-Print Network 3.0 - air-pollution-control residues leaching...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    leaching Search Powered by Explorit Topic List Advanced Search Sample search results for: air-pollution-control residues leaching Page: << < 1 2 3 4 5 > >> 1 Solid Residues from...

  9. Residuals in steel products -- Impacts on properties and measures to minimize them

    SciTech Connect (OSTI)

    Emi, Toshihiko [Tohoku Univ., Sendai (Japan). Inst. for Advanced Materials Processing; Wijk, O. [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Process Metallurgy

    1996-12-31T23:59:59.000Z

    The effect of major residual elements on the properties of steel products is summarized. Measures to minimize these elements are discussed including the pretreatment of raw materials, innovative refining processes and environmental issues. This paper addresses (1) scrap situation, (2) upper limit of residual concentrations acceptable for processing and product quality, (3) possible means to reduce the residuals, and (4) consideration on the practicable measures to solve the residuals problem in a systematic way. 52 refs.

  10. Burning Forest Residues231 Corstorphine Road www.forestry.gov.uk

    E-Print Network [OSTI]

    , for disposal of coppice, to reduce specific weeds and to aid land use conversion. BURNING RESIDUES: TYPES

  11. Numerical Simulations of Leakage from Underground LPG Storage Caverns

    E-Print Network [OSTI]

    Yamamoto, Hajime; Pruess, Karsten

    2004-01-01T23:59:59.000Z

    model contains three propane storage caverns, 10 m wide and3.2.9. The loss of propane from storage is not significant,liquefied propane) was placed in the storage caverns, and

  12. Application of Energy Saving Concepts to LPG Recovery Plants

    E-Print Network [OSTI]

    Carpenter, M. J.; Barnwell, J.

    1982-01-01T23:59:59.000Z

    inefficient compared to current standards. This paper deals with energy savings that may be effected for one such plant. Three basic ideas are evaluated:- o Use of Multi-Component Chilling (MCC). o Addition of an Expander. o Heat Recovery from Gas Turbine...

  13. Waste Heat Powered Ammonia Absorption Refrigeration Unit for LPG Recovery

    SciTech Connect (OSTI)

    Donald C, Energy Concepts Co.; Lauber, Eric, Western Refining Co.

    2008-06-20T23:59:59.000Z

    An emerging DOE-sponsored technology has been deployed. The technology recovers light ends from a catalytic reformer plant using waste heat powered ammonia absorption refrigeration. It is deployed at the 17,000 bpd Bloomfield, New Mexico refinery of Western Refining Company. The technology recovers approximately 50,000 barrels per year of liquefied petroleum gas that was formerly being flared. The elimination of the flare also reduces CO2 emissions by 17,000 tons per year, plus tons per year reductions in NOx, CO, and VOCs. The waste heat is supplied directly to the absorption unit from the Unifiner effluent. The added cooling of that stream relieves a bottleneck formerly present due to restricted availability of cooling water. The 350oF Unifiner effluent is cooled to 260oF. The catalytic reformer vent gas is directly chilled to minus 25oF, and the FCC column overhead reflux is chilled by 25oF glycol. Notwithstanding a substantial cost overrun and schedule slippage, this project can now be considered a success: it is both profitable and highly beneficial to the environment. The capabilities of directly-integrated waste-heat powered ammonia absorption refrigeration and their benefits to the refining industry have been demonstrated.

  14. Microsoft Word - 0615DOE-LPG-wd6.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department ofT ib l L d F S i DOE Tribal Leader ForumStatus ofStephenEnergy SectorMay

  15. Residual Stress Relaxation and Microstructure in ZnO Thin Films Istem Ozena

    E-Print Network [OSTI]

    Yanikoglu, Berrin

    to be eliminated during deposition. Introduction In this study, the decay of the residual stressesResidual Stress Relaxation and Microstructure in ZnO Thin Films Istem Ozena and Mehmet Ali Gulgunb. a istem@sabanciuniv.edu b m-gulgun@sabanciuniv.edu Keywords: ZnO, thin films, residual stress

  16. NONLINEAR SAW PROPAGATION IN THIN-FILM SYSTEMS WITH RESIDUAL STRESS* R. E. Kumon

    E-Print Network [OSTI]

    harmonics. I. INTRODUCTION AND MOTIVATION The thin-film deposition process can create large residualNONLINEAR SAW PROPAGATION IN THIN-FILM SYSTEMS WITH RESIDUAL STRESS* R. E. Kumon National Institute is the residual stress. The effective elas- tic constants and density are given by Ceff ijkl = Cijkl(1 - eres

  17. Microstructure, residual stress, and fracture of sputtered TiN films Liqiang Zhang a

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Microstructure, residual stress, and fracture of sputtered TiN films Liqiang Zhang a , Huisheng Keywords: TiN films Residual stress Hardness Fracture toughness Morphology, structure, residual stress, hardness, and fracture toughness of magnetron sputtered titanium nitride (TiN) thin films, deposited at 300

  18. Using mobile distributed pyrolysis facilities to deliver a forest residue resource for bio-fuel production

    E-Print Network [OSTI]

    Victoria, University of

    reduces the energy content of forest residues delivered to a bio-fuel facility as mobile facilities use by bio-oil, bio-slurry and torrefied wood is 45%, 65% and 87% of the initial forest residue energyUsing mobile distributed pyrolysis facilities to deliver a forest residue resource for bio

  19. Prediction of Protein Interaction Sites From Sequence Profile and Residue Neighbor List

    E-Print Network [OSTI]

    Weston, Ken

    Prediction of Protein Interaction Sites From Sequence Profile and Residue Neighbor List Huan Protein­protein interaction sites are predicted from a neural network with sequence profiles correctly predicted residues account for 65% of the 11,805 residues making up the 129 interfaces. The main

  20. Environmental and economic evaluation of energy recovery from agricultural and forestry residues

    SciTech Connect (OSTI)

    None

    1980-09-01T23:59:59.000Z

    Four conversion methods and five residues are examined in this report, which describes six model systems: hydrolysis of corn residues, pyrolysis of corn residues, combustion of cotton-ginning residues, pyrolysis of wheat residues, fermentation of molasses, and combustion of pulp and papermill wastes. Estimates of material and energy flows for those systems are given per 10/sup 12/ Btu of recovered energy. Regional effects are incorporated by addressing the regionalized production of the residues. A national scope cannot be provided for every residue considered because of the biological and physical constraints of crop production. Thus, regionalization of the model systems to the primary production region for the crop from which the residue is obtained has been undertaken. The associated environmental consequences of residue utilization are then assessed for the production region. In addition, the environmental impacts of operating the model systems are examined by quantifying the residuals generated and the land, water, and material requirements per 10/sup 12/ Btu of energy generated. On the basis of estimates found in the literature, capital, operating, and maintenance cost estimates are given for the model systems. These data are also computed on the basis of 10/sup 12/ Btu of energy recovered. The cost, residual, material, land, and water data were then organized into a format acceptable for input into the SEAS data management program. The study indicates that the most serious environmental impacts arise from residue removal rather than from conversion.

  1. Submillimeter residual losses in high-{Tc} superconductors

    SciTech Connect (OSTI)

    Miller, D.

    1993-09-01T23:59:59.000Z

    Bolometry was used obtain accurate submillimeter residual loss data for epitaxial films of YBa{sub 2}Cu{sub 3}O{sub 7} (YBCO), Tl{sub 2}Ca{sub 2}Ba{sub 2}Cu{sub 3}O{sub 10}, Tl{sub 2}CaBa{sub 2}Cu{sub 2}O{sub 8} (TCBCO), and Ba{sub 0.6}K{sub 0.4}BiO{sub 3} (BKBO). We were able to fit the absorptivity measured for Nb films to an Eliashberg strong coupling calculation; excellent agreement resulted between parameters from best fits and measured Residual Resistivity Ratio. Microwave surface resistance measurements made on the same YBCO and TCBCO films are in excellent agreement with submillimeter measurements. Absorptivities for all YBCO films studied are qualitatively similar, increasing smoothly with frequency, with no gap-like features below the well known absorption edge at 450 cm{sup {minus}1}. Losses in YBCO films were fit to a weakly coupled grain model for the a-b plane conductivity. Strong phonon structure was observed in TCBCO films between 60 and 700 cm{sup {minus}1} (2 THz and 23 THz); these losses could not be fitted to the simple weakly coupled grain model, in contrast to the case for other high-{Tc} superconductors where phonon structure observed in ceramics are is absent in epitaxial oriented films and crystals because of electronic screening due to high conductivity of a-b planes. Absorptivity data for the BKBO films all show a strong absorption onset near the BCS tunneling gap of 3.5 k{sub B}{Tc}. Comparison with strong coupling Eliashberg predictions and of a Kramers-Kronig analysis indicate that the absorption onset is consistent with a superconducting energy gap. Effects of magnetic field on residual losses in YBCO films show a resonant absorption feature in vicinity of predicted

  2. Residual stresses in bakelite models induced by quenching

    E-Print Network [OSTI]

    Jarvi, Ray Victor

    1952-01-01T23:59:59.000Z

    and the bellows was extended to six inobes. Lifter proper focusing and using a Kodachrome type 4 film, separate piotures were made at openings f8, fll, f16, and f22 in order to provide for a suitable spread of exposure. Sodium vapor was used as the source... for determining the residual stresses or the elastic redistribution of stresses that occurs after the prototype has undergone some plastio deformation or heat treatment. The creep characteristics of bakelite, BT-61-893, become appreciable with temperatures...

  3. Radon transform on a space over a residue class ring

    SciTech Connect (OSTI)

    Molchanov, Vladimir F [Tambov State University, Tambov (Russian Federation)

    2012-05-31T23:59:59.000Z

    The functions on a space of dimension N over the residue class ring Z{sub n} modulo n that are invariant with respect to the group GL(N,Z{sub n}) form a commutative convolution algebra. We describe the structure of this algebra and find the eigenvectors and eigenvalues of the operators of multiplication by elements of this algebra. The results thus obtained are applied to solve the inverse problem for the hyperplane Radon transform on Z{sup N}{sub n}. Bibliography: 2 titles.

  4. Quarry residuals RI/FS scoping document. [Weldon Spring quarry

    SciTech Connect (OSTI)

    Not Available

    1991-10-01T23:59:59.000Z

    The purpose of this document is to serve as a planning tool for the implementation of the Quarry Residual Remedial Investigation/Feasibility Study (RI/FS) process and to provide direct input to revising and updating the 1988 Work Plan for the Weldon Spring Site Remedial Action Project (WSSRAP) Remedial Investigation/Feasibility Study-Environmental Impact Statement for the Weldon Spring Site (RI/FS-EIS) (Peterson et al. 1988) for this effort. The scoping process is intended to outline the tasks necessary to develop and implement activities in compliance with the Comprehensive Environmental Response, Compensation and Liability Act-National Environmental Policy Act (CERCLA-NEPA) process from detailed planning through the appropriate decision document. In addition to scoping the entire process, this document will serve as the primary tool for planning and accomplishing all activities to be developed in the Quarry Residual RI/FS Work Plan. Subsequent tasks are difficult to plan at this time. 10 refs., 5 figs., 5 tabs.

  5. Estimating Residual Solids Volume In Underground Storage Tanks

    SciTech Connect (OSTI)

    Clark, Jason L.; Worthy, S. Jason; Martin, Bruce A.; Tihey, John R.

    2014-01-08T23:59:59.000Z

    The Savannah River Site liquid waste system consists of multiple facilities to safely receive and store legacy radioactive waste, treat, and permanently dispose waste. The large underground storage tanks and associated equipment, known as the 'tank farms', include a complex interconnected transfer system which includes underground transfer pipelines and ancillary equipment to direct the flow of waste. The waste in the tanks is present in three forms: supernatant, sludge, and salt. The supernatant is a multi-component aqueous mixture, while sludge is a gel-like substance which consists of insoluble solids and entrapped supernatant. The waste from these tanks is retrieved and treated as sludge or salt. The high level (radioactive) fraction of the waste is vitrified into a glass waste form, while the low-level waste is immobilized in a cementitious grout waste form called saltstone. Once the waste is retrieved and processed, the tanks are closed via removing the bulk of the waste, chemical cleaning, heel removal, stabilizing remaining residuals with tailored grout formulations and severing/sealing external penetrations. The comprehensive liquid waste disposition system, currently managed by Savannah River Remediation, consists of 1) safe storage and retrieval of the waste as it is prepared for permanent disposition; (2) definition of the waste processing techniques utilized to separate the high-level waste fraction/low-level waste fraction; (3) disposition of LLW in saltstone; (4) disposition of the HLW in glass; and (5) closure state of the facilities, including tanks. This paper focuses on determining the effectiveness of waste removal campaigns through monitoring the volume of residual solids in the waste tanks. Volume estimates of the residual solids are performed by creating a map of the residual solids on the waste tank bottom using video and still digital images. The map is then used to calculate the volume of solids remaining in the waste tank. The ability to accurately determine a volume is a function of the quantity and quality of the waste tank images. Currently, mapping is performed remotely with closed circuit video cameras and still photograph cameras due to the hazardous environment. There are two methods that can be used to create a solids volume map. These methods are: liquid transfer mapping / post transfer mapping and final residual solids mapping. The task is performed during a transfer because the liquid level (which is a known value determined by a level measurement device) is used as a landmark to indicate solids accumulation heights. The post transfer method is primarily utilized after the majority of waste has been removed. This method relies on video and still digital images of the waste tank after the liquid transfer is complete to obtain the relative height of solids across a waste tank in relation to known and usable landmarks within the waste tank (cooling coils, column base plates, etc.). In order to accurately monitor solids over time across various cleaning campaigns, and provide a technical basis to support final waste tank closure, a consistent methodology for volume determination has been developed and implemented at SRS.

  6. A Multi-Factor Analysis of Sustainable Agricultural Residue Removal Potential

    SciTech Connect (OSTI)

    Jared Abodeely; David Muth; Paul Adler; Eleanor Campbell; Kenneth Mark Bryden

    2012-10-01T23:59:59.000Z

    Agricultural residues have significant potential as a near term source of cellulosic biomass for bioenergy production, but sustainable removal of agricultural residues requires consideration of the critical roles that residues play in the agronomic system. Previous work has developed an integrated model to evaluate sustainable agricultural residue removal potential considering soil erosion, soil organic carbon, greenhouse gas emission, and long-term yield impacts of residue removal practices. The integrated model couples the environmental process models WEPS, RUSLE2, SCI, and DAYCENT. This study uses the integrated model to investigate the impact of interval removal practices in Boone County, Iowa, US. Residue removal of 4.5 Mg/ha was performed annually, bi-annually, and tri-annually and were compared to no residue removal. The study is performed at the soil type scale using a national soil survey database assuming a continuous corn rotation with reduced tillage. Results are aggregated across soil types to provide county level estimates of soil organic carbon changes and individual soil type soil organic matter content if interval residue removal were implemented. Results show interval residue removal is possible while improving soil organic matter. Implementation of interval removal practices provide greater increases in soil organic matter while still providing substantial residue for bioenergy production.

  7. Quantification of residual stress from photonic signatures of fused silica

    SciTech Connect (OSTI)

    Cramer, K. Elliott; Yost, William T. [NASA Langley Research Center, Hampton, VA 23681 (United States); Hayward, Maurice [College of William and Mary, Williamsburg, VA 23185 (United States)

    2014-02-18T23:59:59.000Z

    A commercially available grey-field polariscope (GFP) instrument for photoelastic examination is used to assess impact damage inflicted upon the outer-most pane of Space Shuttle windows made from fused silica. A method and apparatus for calibration of the stress-optic coefficient using four-point bending is discussed. The results are validated on known material (acrylic) and are found to agree with literature values to within 6%. The calibration procedure is then applied to fused-silica specimens and the stress-optic coefficient is determined to be 2.43 ± 0.54 × 10{sup ?12} Pa{sup ?1}. Fused silica specimens containing impacts artificially made at NASA’s Hypervelocity Impact Technology Facility (HIT-F), to simulate damage typical during space flight, are examined. The damage sites are cored from fused silica window carcasses and examined with the GFP. The calibrated GFP measurements of residual stress patterns surrounding the damage sites are presented.

  8. Description of the prototype diagnostic residual gas analyzer for ITER

    SciTech Connect (OSTI)

    Younkin, T. R., E-mail: tyounkin@gatech.edu [Fusion and Materials for Nuclear Systems Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6169 (United States); Georgia Institute of Technology, Woodruff School of Mechanical Engineering – Nuclear and Radiological Engineering Program, Atlanta, Georgia 30332 (United States); Biewer, T. M.; Klepper, C. C.; Marcus, C. [Fusion and Materials for Nuclear Systems Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831-6169 (United States)

    2014-11-15T23:59:59.000Z

    The diagnostic residual gas analyzer (DRGA) system to be used during ITER tokamak operation is being designed at Oak Ridge National Laboratory to measure fuel ratios (deuterium and tritium), fusion ash (helium), and impurities in the plasma. The eventual purpose of this instrument is for machine protection, basic control, and physics on ITER. Prototyping is ongoing to optimize the hardware setup and measurement capabilities. The DRGA prototype is comprised of a vacuum system and measurement technologies that will overlap to meet ITER measurement requirements. Three technologies included in this diagnostic are a quadrupole mass spectrometer, an ion trap mass spectrometer, and an optical penning gauge that are designed to document relative and absolute gas concentrations.

  9. Evaluation of the residue from microset on various metal surfaces.

    SciTech Connect (OSTI)

    Brumbach, Michael Todd

    2011-04-01T23:59:59.000Z

    Fast-curing impression materials are sometimes used to cast negative-mold replications of physical defects on material surfaces. The negative-mold impressions can then be used for further measurements to record the nature of the defect. These impression materials have been designed to cure quickly, and with very low adhesion, so that they can be easily removed from the surface leaving little residual contamination. Unfortunately, some contaminant is retained by the substrate material. This investigation seeks to identify the composition and quantity of the remaining material upon removal of Microset Synthetic Rubber Replicating Compound from several material surfaces. Coe-Flex was used as a relative comparison to Microset. On fifteen different substrate materials the Microset leaves no visible trace of contaminant, however, X-ray photoelectron spectroscopy shows evidence of a thin silicone-based contaminant film of approximately 2 nm thickness.

  10. Cost Methodology for Biomass Feedstocks: Herbaceous Crops and Agricultural Residues

    SciTech Connect (OSTI)

    Turhollow Jr, Anthony F [ORNL; Webb, Erin [ORNL; Sokhansanj, Shahabaddine [ORNL

    2009-12-01T23:59:59.000Z

    This report describes a set of procedures and assumptions used to estimate production and logistics costs of bioenergy feedstocks from herbaceous crops and agricultural residues. The engineering-economic analysis discussed here is based on methodologies developed by the American Society of Agricultural and Biological Engineers (ASABE) and the American Agricultural Economics Association (AAEA). An engineering-economic analysis approach was chosen due to lack of historical cost data for bioenergy feedstocks. Instead, costs are calculated using assumptions for equipment performance, input prices, and yield data derived from equipment manufacturers, research literature, and/or standards. Cost estimates account for fixed and variable costs. Several examples of this costing methodology used to estimate feedstock logistics costs are included at the end of this report.

  11. Residual Stress Determination for A Ferritic Steel Weld Plate

    SciTech Connect (OSTI)

    Wang, D.-Q.; Hubbard, C.R.; Spooner, S.

    1999-10-01T23:59:59.000Z

    The primary objective of this experiment is to demonstrate the capability of neutron diffraction technique to reproducibly map residual strains in a ferritic steel weld. The objective includes the identification of corrections for variations in metal composition due to the welding process which produces changes in lattice parameter that are not due to mechanical effects. The second objective is to develop and demonstrate a best practice for neutron diffraction strain mapping of steel welds. The appropriate coordinate system for the measurement of a weld, which is strongly distorted from planar geometry, has to be defined. The coordinate system is important in determining the procedures for mounting and positioning of the weld so that mapping details, especially in regions of high gradients, can be conveniently inter-compared between laboratories.

  12. Residue temperatures in intermediate energy nucleus-nucleus collisions

    SciTech Connect (OSTI)

    Xu, H.M.; Lynch, W.G.; Danielewicz, P. (National Superconducting Cyclotron Laboratory and Department of Physics, Michigan State University, East Lansing, Michigan 48824 (United States) Cyclotron Institute, Texas A M University, College Station, Texas 77843 (United States))

    1994-09-01T23:59:59.000Z

    With an improved Boltzmann-Uehling-Uhlenbeck (BUU) model, we have investigated the reaction dynamics leading to the thermal freeezout for [sup 40]Ar+[sup 124]Sn collisions. Several criteria are assessed for defining the proper thermal freezout time which separates preequilibrium processes from equilbrium processes. One of these criteria, the time dependence of the thermal excitation energy, provides consistent results for defining the thermal freezeout. The other two criteria, the emission rate of nucleons and the quadrupole moment of the momentum distributions, do not consistently provide accurate freezeout times due to the existence of long time scale collective vibrations. The predicted values for the excitation energies and temperatures, obtained assuming Fermi gas level densities, are quite sensitive to the equation of state and the impact parameter. Surprisingly, both the thermal excitation energies and the residue temperatures, in the limit of a large ensemble of parallel collisions, show little sensitivity to the in-medium nucleon-nucleon cross section.

  13. Residual energy in magnetohydrodynamic turbulence and in the solar wind

    E-Print Network [OSTI]

    Stanislav Boldyrev; Jean Carlos Perez; Vladimir Zhdankin

    2011-08-30T23:59:59.000Z

    Recent observations indicate that kinetic and magnetic energies are not in equipartition in the solar wind turbulence. Rather, magnetic fluctuations are more energetic and have somewhat steeper energy spectrum compared to the velocity fluctuations. This leads to the presence of the so-called residual energy E_r=E_v-E_b in the inertial interval of turbulence. This puzzling effect is addressed in the present paper in the framework of weak turbulence theory. Using a simple model of weakly colliding Alfv\\'en waves, we demonstrate that the kinetic-magnetic equipartition indeed gets broken as a result of nonlinear interaction of Alfv\\'en waves. We establish that magnetic energy is indeed generated more efficiently as a result of these interactions, which proposes an explanation for the solar wind observations.

  14. E-Print Network 3.0 - agricultural residues Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Use in the United States Summary: , livestock commodities, agricultural residues, and bioenergy crops. Drawing on ORNL and APAC county... , developed and maintained at the...

  15. E-Print Network 3.0 - automobile shredder residue Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Search Powered by Explorit Topic List Advanced Search Sample search results for: automobile shredder residue Page: << < 1 2 3 4 5 > >> 1 NASHVILLE INCINERATOR PERFORMANCE TESTS...

  16. Neutron scattering residual stress measurements on gray cast iron brake discs

    SciTech Connect (OSTI)

    Spooner, S.; Payzant, E.A.; Hubbard, C.R. [and others

    1996-11-01T23:59:59.000Z

    Neutron diffraction was used to investigate the effects of a heat treatment designed to remove internal residual stresses in brake discs. It is believed that residual stresses may change the rate of deformation of the discs during severe braking conditions when the disc temperature is increased significantly. Neutron diffraction was used to map out residual strain distributions in a production disc before and after a stress-relieving heat treatment. Results from these neutron diffraction experiments show that some residual strains were reduced by as much as 400 microstrain by stress relieving. 5 refs., 5 figs., 1 tab.

  17. Table 42. Residual Fuel Oil Prices by PAD District and State

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 1999 203 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  18. Table 42. Residual Fuel Oil Prices by PAD District and State

    Gasoline and Diesel Fuel Update (EIA)

    Information AdministrationPetroleum Marketing Annual 1998 203 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  19. Table 42. Residual Fuel Oil Prices by PAD District and State

    Gasoline and Diesel Fuel Update (EIA)

    Information Administration Petroleum Marketing Annual 1995 245 Table 42. Residual Fuel Oil Prices by PAD District and State (Cents per Gallon Excluding Taxes) - Continued...

  20. E-Print Network 3.0 - acs residual ischemic Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Search Sample search results for: acs residual ischemic Page: << < 1 2 3 4 5 > >> 1 Brain Research 961 (2003) 2231 www.elsevier.comlocatebrainres Summary: further...

  1. E-Print Network 3.0 - acid residues required Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering, Columbia University Collection: Engineering ; Biology and Medicine 13 Protein folding with stochastic L-systems Gemma Danks1 Summary: 70 amino acid residues to 1000s...

  2. E-Print Network 3.0 - acid residues determine Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Engineering, Columbia University Collection: Engineering ; Biology and Medicine 14 Protein folding with stochastic L-systems Gemma Danks1 Summary: 70 amino acid residues to 1000s...

  3. alters less-conserved residues: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The macroscopic stress evolution is connected to a length scale of residual liquefaction displayed by microscopic mean-squared displacements. The theory describes this...

  4. POST-OPERATIONAL TREATMENT OF RESIDUAL NA COOLLANT IN EBR-2 USING CARBONATION

    SciTech Connect (OSTI)

    Sherman, S.; Knight, C.

    2011-03-08T23:59:59.000Z

    At the end of 2002, the Experimental Breeder Reactor Two (EBR-II) facility became a U.S. Resource Conservation and Recovery Act (RCRA) permitted site, and the RCRA permit1 compelled further treatment of the residual sodium in order to convert it into a less reactive chemical form and remove the by-products from the facility, so that a state of RCRA 'closure' for the facility may be achieved (42 U.S.C. 6901-6992k, 2002). In response to this regulatory driver, and in recognition of project budgetary and safety constraints, it was decided to treat the residual sodium in the EBR-II primary and secondary sodium systems using a process known as 'carbonation.' In early EBR-II post-operation documentation, this process is also called 'passivation.' In the carbonation process (Sherman and Henslee, 2005), the system containing residual sodium is flushed with humidified carbon dioxide (CO{sub 2}). The water vapor in the flush gas reacts with residual sodium to form sodium hydroxide (NaOH), and the CO{sub 2} in the flush gas reacts with the newly formed NaOH to make sodium bicarbonate (NaHCO{sub 3}). Hydrogen gas (H{sub 2}) is produced as a by-product. The chemical reactions occur at the exposed surface of the residual sodium. The NaHCO{sub 3} layer that forms is porous, and humidified carbon dioxide can penetrate the NaHCO{sub 3} layer to continue reacting residual sodium underneath. The rate of reaction is controlled by the thickness of the NaHCO{sub 3} surface layer, the moisture input rate, and the residual sodium exposed surface area. At the end of carbonation, approximately 780 liters of residual sodium in the EBR-II primary tank ({approx}70% of original inventory), and just under 190 liters of residual sodium in the EBR-II secondary sodium system ({approx}50% of original inventory), were converted into NaHCO{sub 3}. No bare surfaces of residual sodium remained after treatment, and all remaining residual sodium deposits are covered by a layer of NaHCO{sub 3}. From a safety standpoint, the inventory of residual sodium in these systems was greatly reduced by using the carbonation process. From a regulatory standpoint, the process was not able to achieve deactivation of all residual sodium, and other more aggressive measures will be needed if the remaining residual sodium must also be deactivated to meet the requirements of the existing environmental permit. This chapter provides a project history and technical summary of the carbonation of EBR-II residual sodium. Options for future treatment are also discussed.

  5. An Integrated Model for Assessment of Sustainable Agricultural Residue Removal Limits for Bioenergy Systems

    SciTech Connect (OSTI)

    D. Muth; K. M. Bryden

    2003-12-01T23:59:59.000Z

    Agricultural residues have been identified as a significant potential resource for bioenergy production, but serious questions remain about the sustainability of harvesting residues. Agricultural residues play an important role in limiting soil erosion from wind and water and in maintaining soil organic carbon. Because of this, multiple factors must be considered when assessing sustainable residue harvest limits. Validated and accepted modeling tools for assessing these impacts include the Revised Universal Soil Loss Equation Version 2 (RUSLE2), the Wind Erosion Prediction System (WEPS), and the Soil Conditioning Index. Currently, these models do not work together as a single integrated model. Rather, use of these models requires manual interaction and data transfer. As a result, it is currently not feasible to use these computational tools to perform detailed sustainable agricultural residue availability assessments across large spatial domains or to consider a broad range of land management practices. This paper presents an integrated modeling strategy that couples existing datasets with the RUSLE2 water erosion, WEPS wind erosion, and Soil Conditioning Index soil carbon modeling tools to create a single integrated residue removal modeling system. This enables the exploration of the detailed sustainable residue harvest scenarios needed to establish sustainable residue availability. Using this computational tool, an assessment study of residue availability for the state of Iowa was performed. This study included all soil types in the state of Iowa, four representative crop rotation schemes, variable crop yields, three tillage management methods, and five residue removal methods. The key conclusions of this study are that under current management practices and crop yields nearly 26.5 million Mg of agricultural residue are sustainably accessible in the state of Iowa, and that through the adoption of no till practices residue removal could sustainably approach 40 million Mg. However, when considering the economics and logistics of residue harvest, yields below 2.25 Mg ha-1 are generally considered to not be viable for a commercial bioenergy system. Applying this constraint, the total agricultural residue resource available in Iowa under current management practices is 19 million Mg. Previously published results have shown residue availability from 22 million Mg to over 50 million Mg in Iowa.

  6. The influence of quench sensitivity on residual stresses in the aluminium alloys 7010 and 7075

    SciTech Connect (OSTI)

    Robinson, J.S., E-mail: jeremy.robinson@ul.ie [Materials and Surface Science Institute, University of Limerick (Ireland); Tanner, D.A. [Materials and Surface Science Institute, University of Limerick (Ireland); Truman, C.E. [Department of Mechanical Engineering, University of Bristol (United Kingdom); Paradowska, A.M. [ISIS Facility, Rutherford Appleton Laboratory, Didcot (United Kingdom); Wimpory, R.C. [Helmholtz Centre Berlin for Materials and Energy, Hahn Meitner Platz 1, Berlin (Germany)

    2012-03-15T23:59:59.000Z

    The most critical stage in the heat treatment of high strength aluminium alloys is the rapid cooling necessary to form a supersaturated solid solution. A disadvantage of quenching is that the thermal gradients can be sufficient to cause inhomogeneous plastic deformation which in turn leads to the development of large residual stresses. Two 215 mm thick rectilinear forgings have been made from 7000 series alloys with widely different quench sensitivity to determine if solute loss in the form of precipitation during quenching can significantly affect residual stress magnitudes. The forgings were heat treated and immersion quenched using cold water to produce large magnitude residual stresses. The through thickness residual stresses were measured by neutron diffraction and incremental deep hole drilling. The distribution of residual stresses was found to be similar for both alloys varying from highly triaxial and tensile in the interior, to a state of biaxial compression in the surface. The 7010 forging exhibited larger tensile stresses in the interior. The microstructural variation from surface to centre for both forgings was determined using optical and transmission electron microscopy. These observations were used to confirm the origin of the hardness variation measured through the forging thickness. When the microstructural changes were accounted for in the through thickness lattice parameter, the residual stresses in the two forgings were found to be very similar. Solute loss in the 7075 forging appeared to have no significant effect on the residual stress magnitudes when compared to 7010. - Highlights: Black-Right-Pointing-Pointer Through thickness residual stress measurements made on large Al alloy forgings. Black-Right-Pointing-Pointer Residual stress characterised using neutron diffraction and deep hole drilling. Black-Right-Pointing-Pointer Biaxial compressive surface and triaxial subsurface residual stresses. Black-Right-Pointing-Pointer Quench sensitivity of 7075 promotes significant microstructural differences to 7010. Black-Right-Pointing-Pointer When precipitation is accounted for, residual stress in both forgings are similar.

  7. Intermediate Vapor Expansion Distillation and Nested Enrichment Cascade Distillation

    E-Print Network [OSTI]

    Erickson, D. C.

    requiring either compressors or expanders. function of feed composition. The simple column has a single reboiler, single condenser, and is idealized to the extent that column pressure differential and heat exchanger temperature differential are set... Separation Z. Nested Enrichment Cascade For separating liquid mixtures above ambient temperature, both full 'cascade~ and also enrichment cascades have been used. They reduce the heat throughput by about 40% but do not decrease the energy consumption...

  8. DistillationTheory.fm 2 September 1999 Distillation Theory.

    E-Print Network [OSTI]

    Skogestad, Sigurd

    . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32 The Energy Balance and the Assumption of Constant Molar flows . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 Assumption about Constant Molar Flows . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15 Minimum Number of Stages -- Infinite Energy

  9. A3.

    U.S. Energy Information Administration (EIA) Indexed Site

    A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD...

  10. Recovery of flexible polyurethane foam from shredder residue.

    SciTech Connect (OSTI)

    Daniels, E. J.; Jody, b. J.

    1999-06-29T23:59:59.000Z

    Argonne National Laboratory has developed a patented, continuous process for the recovery of flexible polyurethane foam (PUF) from auto shredder residue (ASR). To test the process, Argonne researchers conceived of, designed, and built a continuous foam washing and drying system that was pilot-tested at a shredder facility for six months. Economic analysis of the process, using manufacturers' quotes and operating data from Argonne's pilot plant, indicates a payback of less than two years for a plant producing about 1,000 ton/yr of foam. Samples of clean foam were shipped to three major foam reprocessors; all three indicated that the quality of the PUF recovered by the Argonne process met their requirements. Tests of the recovered foam by an independent testing laboratory showed that the recycled foam met the specifications for several automotive applications, including carpet padding, headliner, and sound-suppression support materials. Recovery of foam reduces the mass and the volume of material going to the landfill by about 5% and 30%, respectively. Annually, recovery will save about 1.2 x 10{sup 12} Btu of energy, cut the amount of solid waste being landfilled by about 150,000 tons, and eliminate the emission of about 250 tons of volatile organic compounds (VOCs) into the air.

  11. Processing Effects for Integrated PZT: Residual Stress, Thickness, and Dielectric Properties

    E-Print Network [OSTI]

    Sottos, Nancy R.

    Processing Effects for Integrated PZT: Residual Stress, Thickness, and Dielectric Properties Ryan J (PZT) films integrated onto Pt/Ti/SiO2//Si substrates are reported. Sol­gel synthesis and deposition orientation (nominally (111) fiber tex- tured), and measured residual stress. The Stoney method, using laser

  12. UPTAKE, ASSIMILATION, AND LOSS OF DDT RESIDUES BY Euphausia pacifica, A EUPHAUSIID SHRIMP

    E-Print Network [OSTI]

    UPTAKE, ASSIMILATION, AND LOSS OF DDT RESIDUES BY Euphausia pacifica, A EUPHAUSIID SHRIMP ABSTRACT acquire sufficient DDT residue from its food to account for amounts found in its tissues. Assimilation effii- ciencies for DDT in ingested food are similar to published figures for assimilation of carbon

  13. Speciation of Sb in airborne particulate matter, vehicle brake linings, and brake pad wear residues

    E-Print Network [OSTI]

    Short, Daniel

    Speciation of Sb in airborne particulate matter, vehicle brake linings, and brake pad wear residues: XAS XANES EXAFS Antimony Particulate matter Brake linings a b s t r a c t Insights into the speciation of Sb in samples of brake linings, brake pad wear residues, road dust, and atmospheric particulate

  14. Measuring the Residual Ferrite Content of Rapidly Solidified Stainless Steel Alloys-

    E-Print Network [OSTI]

    Eagar, Thomas W.

    -Gage and ferrite meters have been developed to measure the amount of residual ferrite in duplex stainless steel) ) Measuring the Residual Ferrite Content of Rapidly Solidified Stainless Steel Alloys. Electron beam welds, laser beam welds and rapidly solidified stainless steel alloys have small physical

  15. Prediction of catalytic residues in proteins using machine-learning techniques

    E-Print Network [OSTI]

    Prediction of catalytic residues in proteins using machine-learning techniques Natalia V. Petrova) and prediction of protein function using various properties of proteins and amino acids (2). Prediction of the functional residues is a challenging and interesting task. The results of such prediction could

  16. Prediction of Interface Residues in ProteinProtein Complexes by a Consensus Neural Network Method: Test

    E-Print Network [OSTI]

    Weston, Ken

    Prediction of Interface Residues in Protein­Protein Complexes by a Consensus Neural Network Method important information for predicting struc- tures of new protein complexes. This motivated us to develop the PPISP method for predicting inter- face residues in protein­protein complexes. In PPISP, sequence

  17. Management of high sulfur coal combustion residues, issues and practices: Proceedings

    SciTech Connect (OSTI)

    Chugh, Y.P.; Beasley, G.A. [eds.

    1994-10-01T23:59:59.000Z

    Papers presented at the following sessions are included in this proceedings: (1) overview topic; (2) characterization of coal combustion residues; (3) environmental impacts of residues management; (4) materials handling and utilization, Part I; and (5) materials handling and utilization, Part II. Selected paper have been processed separately for inclusion in the Energy Science and Technology Database.

  18. Residual Magnetic Flux Leakage: A Possible Tool for Studying Pipeline Defects

    E-Print Network [OSTI]

    Clapham, Lynann

    Residual Magnetic Flux Leakage: A Possible Tool for Studying Pipeline Defects Vijay Babbar1 weaker flux signals. KEY WORDS: Magnetic flux leakage; residual magnetization; pipeline defects; pipeline pipelines, which may develop defects such as corrosion pits as they age in service.(1) Under the ef- fect

  19. MALATHION RESIDUES IN GREEK HONEY Andreas T. THRASYVOULOU Michael D. IFANTIDIS Nikos L. PAPPAS*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    -1982 were analyzed for malathion residues. Residues were extracted with acetonitrile/water solution, parti the north, the south, and some Greek islands as well. Reagents Acetonitrile - Nanograde (Mallinckrodt, Inc. Fifty ml of a 10/90 wa- ter/acetonitrile solution was added and the funnel shaken vigorously until

  20. Pharmacokinetic and residue studies of quinolone compounds and olaquindox in poultry

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Pharmacokinetic and residue studies of quinolone compounds and olaquindox in poultry A Anadón MR of these quinolones and fluoroquinolones for which clinical experience or experimental informa- tion exists in poultry residues in poultry. This paper presents information about the pharmacokinetic profile of olaquindox

  1. Justification of RHIC EBIS vacuum system. 1. Requirements to the pressure of residual gas inside the

    E-Print Network [OSTI]

    volume, the influx and accumulation of residual gas ions reduces the number of working ions in a trap for internal elements, technology of processing and equipment should be adequate. The components of the gasJustification of RHIC EBIS vacuum system. A. Pikin 1. Requirements to the pressure of residual gas

  2. Experimental determination of residual stress by neutron diffraction in a boiling water reactor core shroud

    SciTech Connect (OSTI)

    Payzant, A.; Spooner, S.; Zhu, Xiaojing; Hubbard, C.R. [and others

    1996-06-01T23:59:59.000Z

    Residual strains in a 51 mm (2-inch) thick 304L stainless steel plate have been measured by neutron diffraction and interpreted in terms of residual stress. The plate, measuring (300 mm) in area, was removed from a 6m (20-ft.) diameter unirradiated boiling water reactor core shroud, and included a multiple-pass horizontal weld which joined two of the cylindrical shells which comprise the core shroud. Residual stress mapping was undertaken in the heat affected zone, concentrating on the outside half of the plate thickness. Variations in residual stresses with location appeared consistent with trends expected from finite element calculations, considering that a large fraction of the residual hoop stress was released upon removal of the plate from the core shroud cylinder.

  3. Neutron diffraction measurements of residual stresses in friction stir welding: a review

    SciTech Connect (OSTI)

    Woo, Wan Chuck [ORNL; Feng, Zhili [ORNL; Wang, Xun-Li [ORNL; David, Stan A [ORNL

    2011-01-01T23:59:59.000Z

    Significant amounts of residual stresses are often generated during welding and result in critical degradation of the structural integrity and performance of components. Neutron diffraction has become a well established technique for the determination of residual stresses in welds because of the unique deep penetration, three-dimensional mapping capability, and volume averaged bulk measurements characteristic of the scattering neutron beam. Friction stir welding has gained prominence in recent years. The authors reviewed a number of neutron diffraction measurements of residual stresses in friction stir welds and highlighted examples addressing how the microstructures and residual stresses are correlated with each other. An example of in situ neutron diffraction measurement result shows the evolution of the residual stresses during welding.

  4. Application of neutron diffraction to measure residual strains in high temperature composites

    SciTech Connect (OSTI)

    Saigal, A. (Tufts Univ., Medford, MA (USA). Dept. of Mechanical Engineering); Kupperman, D.S. (Argonne National Lab., IL (USA))

    1991-01-01T23:59:59.000Z

    An experimental neutron diffraction technique was used to measure residual thermal strains developed in high temperature composites during postfabrication cooling. Silicon carbide fiber-reinforced titanium aluminide (over the temperature range 20--950{degree}C) and tungsten and saphikon fiber-reinforced nickel aluminide composites (at room temperature) were investigated. As a result of thermal expansion mismatch, compressive residual strains and stresses were generated in the silicon carbide fibers during cooldown. The axial residual strains were tensile in the matrix and were lower in nickel aluminide matrix as compared to those in titanium aluminide matrix. The average transverse residual strains in the matrix were compressive. Liquid-nitrogen dipping and thermal-cycling tend to reduce the fabrication-induced residual strains in silicon carbide fiber-reinforced titanium aluminide matrix composite. However, matrix cracking can occur as a result of these processes. 10 refs., 5 figs., 2 tabs.

  5. No. 2 Distillate Prices - Residential

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recoveryLaboratory | NationalJohn CyberNeutronsNewNewsNickNiriConnecticut - - - -

  6. Imports of Distillate Fuel Oil

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecember 2005 (Thousand9,0, 1997Environment >7,992000Implications ofU.S.270 300

  7. No. 2 Distillate Prices - Industrial

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing ReservoirsYear-Month WeekReserves (Billion Cubic1.878 2.358 - -

  8. No. 2 Distillate Prices - Residential

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia,(Million Barrels) Crude Oil Reserves in Nonproducing ReservoirsYear-Month WeekReserves (Billion Cubic1.878 2.358 -

  9. Stocks of Distillate Fuel Oil

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"Click worksheet9,1,50022,3,,,,6,1,,781 2,328AdministrationRelease ScheduleU.S. Energy(EIA)

  10. Tidal Residual Eddies and their Effect on Water Exchange in Puget Sound

    SciTech Connect (OSTI)

    Yang, Zhaoqing; Wang, Taiping

    2013-08-30T23:59:59.000Z

    Tidal residual eddies are one of the important hydrodynamic features in tidally dominant estuaries and coastal bays, and they could have significant effects on water exchange in a tidal system. This paper presents a modeling study of tides and tidal residual eddies in Puget Sound, a tidally dominant fjord-like estuary in the Pacific Northwest coast, using a three-dimensional finite-volume coastal ocean model. Mechanisms of vorticity generation and asymmetric distribution patterns around an island/headland were analyzed using the dynamic vorticity transfer approach and numerical experiments. Model results of Puget Sound show that a number of large twin tidal residual eddies exist in the Admiralty Inlet because of the presence of major headlands in the inlet. Simulated residual vorticities near the major headlands indicate that the clockwise tidal residual eddy (negative vorticity) is generally stronger than the anticlockwise eddy (positive vorticity) because of the effect of Coriolis force. The effect of tidal residual eddies on water exchange in Puget Sound and its sub-basins were evaluated by simulations of dye transport. It was found that the strong transverse variability of residual currents in the Admiralty Inlet results in a dominant seaward transport along the eastern shore and a dominant landward transport along the western shore of the Inlet. A similar transport pattern in Hood Canal is caused by the presence of tidal residual eddies near the entrance of the canal. Model results show that tidal residual currents in Whidbey Basin are small in comparison to other sub-basins. A large clockwise residual circulation is formed around Vashon Island near entrance of South Sound, which can potentially constrain the water exchange between the Central Basin and South Sound.

  11. PCB (polychlorinated biphenyl) residues in transformer carcasses: Final report

    SciTech Connect (OSTI)

    Rouse, T.O.; Raymond, C.T.; Fessler, W.A.

    1989-08-01T23:59:59.000Z

    This project had three objectives. The first was to assess the population of PCB-containing transformers remaining in service in the US in 1988. While this could not be done with great precision, it appears that the population of oil-filled transformers containing > 50 /mu/g PCB/g oil has decreased by some 15% since 1982 and that the population of askarel-filled transformers has decreased by some 40% in the same time period. This progress could be continued and accelerated if additional reliable and accepted routes for disposal of PCBs contained in transformers would be developed. The second and third objectives of this project have been to examine two simplified approaches to this end. The second objective was to determine if, by draining PCB-containing oil from transformers and refilling with PCB-free oil, a level of PCBs below 50 ppM (/mu/g/g oil) could be reached with assurance. It appears that reclassification of ''PCB-contaminated'' oil-filled transformers (50--500 /mu/g PCB/g oil) of all ratings by draining and refilling could be done routinely. The third objective was to determine the level of residual PCBs left on the metallic surfaces of askarel-filled transformers which, if these units were refilled with PCB-free mineral transformer oil, would have resulted in concentrations of <50 /mu/g PCB/g oil. It appears that cleaning the surfaces of the metallic components, after careful separation and disposal of the liquid and impregnated solid insulations, to a level of 400 /mu/gPCB/100 cm/sup 2/ would result in transformer carcasses of all sizes which would contain less PCBs than would be found were these transformers to have contained oil at the level of 50 /mu/gPCB/g oil. 7 refs., 6 figs., 9 tabs.

  12. Auto shredder residue recycling: Mechanical separation and pyrolysis

    SciTech Connect (OSTI)

    Santini, Alessandro [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Passarini, Fabrizio, E-mail: fabrizio.passarini@unibo.it [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Vassura, Ivano [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy); Serrano, David; Dufour, Javier [Department of Chemical and Energy Technology, ESCET, Universidad Rey Juan Carlos, c/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Instituto IMDEA Energy, c/Tulipan s/n, 28933 Mostoles, Madrid (Spain); Morselli, Luciano [Department of Industrial Chemistry and Materials, University of Bologna, Viale Risorgimento 4, I-40136 Bologna (Italy)

    2012-05-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer In this work, we exploited mechanical separation and pyrolysis to recycle ASR. Black-Right-Pointing-Pointer Pyrolysis of the floating organic fraction is promising in reaching ELV Directive targets. Black-Right-Pointing-Pointer Zeolite catalyst improve pyrolysis oil and gas yield. - Abstract: sets a goal of 85% material recycling from end-of-life vehicles (ELVs) by the end of 2015. The current ELV recycling rate is around 80%, while the remaining waste is called automotive shredder residue (ASR), or car fluff. In Europe, this is mainly landfilled because it is extremely heterogeneous and often polluted with car fluids. Despite technical difficulties, in the coming years it will be necessary to recover materials from car fluff in order to meet the ELV Directive requirement. This study deals with ASR pretreatment and pyrolysis, and aims to determine whether the ELV material recycling target may be achieved by car fluff mechanical separation followed by pyrolysis with a bench scale reactor. Results show that flotation followed by pyrolysis of the light, organic fraction may be a suitable ASR recycling technique if the oil can be further refined and used as a chemical. Moreover, metals are liberated during thermal cracking and can be easily separated from the pyrolysis char, amounting to roughly 5% in mass. Lastly, pyrolysis can be a good starting point from a 'waste-to-chemicals' perspective, but further research should be done with a focus on oil and gas refining, in order both to make products suitable for the chemical industry and to render the whole recycling process economically feasible.

  13. Effects of weld residual stresses on crack-opening area analysis of pipes for LBB applications

    SciTech Connect (OSTI)

    Dong, P.; Rahman, S.; Wilkowski, G. [and others

    1997-04-01T23:59:59.000Z

    This paper summarizes four different studies undertaken to evaluate the effects of weld residual stresses on the crack-opening behavior of a circumferential through-wall crack in the center of a girth weld. The effect of weld residual stress on the crack-opening-area and leak-rate analyses of a pipe is not well understood. There are no simple analyses to account for these effects, and, therefore, they are frequently neglected. The four studies involved the following efforts: (1) Full-field thermoplastic finite element residual stress analyses of a crack in the center of a girth weld, (2) A comparison of the crack-opening displacements from a full-field thermoplastic residual stress analysis with a crack-face pressure elastic stress analysis to determine the residual stress effects on the crack-opening displacement, (3) The effects of hydrostatic testing on the residual stresses and the resulting crack-opening displacement, and (4) The effect of residual stresses on crack-opening displacement with different normal operating stresses.

  14. Sustainable Agricultural Residue Removal for Bioenergy: A Spatially Comprehensive National Assessment

    SciTech Connect (OSTI)

    D. Muth, Jr.; K. M. Bryden; R. G. Nelson

    2013-02-01T23:59:59.000Z

    This study provides a spatially comprehensive assessment of sustainable agricultural residue removal potential across the United States. Earlier assessments determining the quantity of agricultural residue that could be sustainably removed for bioenergy production at the regional and national scale faced a number of computational limitations. These limitations included the number of environmental factors, the number of land management scenarios, and the spatial fidelity and spatial extent of the assessment. This study utilizes integrated multi-factor environmental process modeling and high fidelity land use datasets to perform a spatially comprehensive assessment of sustainably removable agricultural residues across the conterminous United States. Soil type represents the base spatial unit for this study and is modeled using a national soil survey database at the 10 – 100 m scale. Current crop rotation practices are identified by processing land cover data available from the USDA National Agricultural Statistics Service Cropland Data Layer database. Land management and residue removal scenarios are identified for each unique crop rotation and crop management zone. Estimates of county averages and state totals of sustainably available agricultural residues are provided. The results of the assessment show that in 2011 over 150 million metric tons of agricultural residues could have been sustainably removed across the United States. Projecting crop yields and land management practices to 2030, the assessment determines that over 207 million metric tons of agricultural residues will be able to be sustainably removed for bioenergy production at that time.

  15. Injection, flow, and mixing of CO2 in porous media with residual gas.

    SciTech Connect (OSTI)

    Oldenburg, C.M.; Doughty, C.A.

    2010-09-01T23:59:59.000Z

    Geologic structures associated with depleted natural gas reservoirs are desirable targets for geologic carbon sequestration (GCS) as evidenced by numerous pilot and industrial-scale GCS projects in these environments world-wide. One feature of these GCS targets that may affect injection is the presence of residual CH{sub 4}. It is well known that CH{sub 4} drastically alters supercritical CO{sub 2} density and viscosity. Furthermore, residual gas of any kind affects the relative permeability of the liquid and gas phases, with relative permeability of the gas phase strongly dependent on the time-history of imbibition or drainage, i.e., dependent on hysteretic relative permeability. In this study, the effects of residual CH{sub 4} on supercritical CO{sub 2} injection were investigated by numerical simulation in an idealized one-dimensional system under three scenarios: (1) with no residual gas; (2) with residual supercritical CO{sub 2}; and (3) with residual CH{sub 4}. We further compare results of simulations that use non-hysteretic and hysteretic relative permeability functions. The primary effect of residual gas is to decrease injectivity by decreasing liquid-phase relative permeability. Secondary effects arise from injected gas effectively incorporating residual gas and thereby extending the mobile gas plume relative to cases with no residual gas. Third-order effects arise from gas mixing and associated compositional effects on density that effectively create a larger plume per unit mass. Non-hysteretic models of relative permeability can be used to approximate some parts of the behavior of the system, but fully hysteretic formulations are needed to accurately model the entire system.

  16. Evaluation of low-residue soldering for military and commercial applications: A report from the Low-Residue Soldering Task Force

    SciTech Connect (OSTI)

    Iman, R.L.; Anderson, D.J. [Sandia National Labs., Albuquerque, NM (United States); Burress, R.V. [SEHO (United States)] [and others

    1995-06-01T23:59:59.000Z

    The LRSTF combined the efforts of industry, military, and government to evaluate low-residue soldering processes for military and commercial applications. These processes were selected for evaluation because they provide a means for the military to support the presidential mandate while producing reliable hardware at a lower cost. This report presents the complete details and results of a testing program conducted by the LRSTF to evaluate low-residue soldering for printed wiring assemblies. A previous informal document provided details of the test plan used in this evaluation. Many of the details of that test plan are contained in this report. The test data are too massive to include in this report, however, these data are available on disk as Excel spreadsheets upon request. The main purpose of low-residue soldering is to eliminate waste streams during the manufacturing process.

  17. Community-wide benefits of targeted indoor residual spray for malaria control in the Western Kenya Highland

    E-Print Network [OSTI]

    Zhou, Guofa; Githeko, Andrew K; Minakawa, Noboru; Yan, Guiyun

    2010-01-01T23:59:59.000Z

    ecological settings [4]. Among those control measures, insecticide- treated bed nets (ITNs) and indoor residual-house

  18. 3D residual stress field in arteries: novel inverse method based on optical full-field measurements

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    -stretch and residual stresses arise in arteries largely due to the deposition of stable, highly elastic, elastin during1 3D residual stress field in arteries: novel inverse method based on optical full over time. This gives rise to residual stresses contributing to the homeostatic state of stress in vivo

  19. Close electric field signatures of dart leader//return stroke sequences in rocket-triggered lightning showing residual fields

    E-Print Network [OSTI]

    Florida, University of

    to 30 m deposited by the leader but presumably left unneutralized by the return stroke. This residual-triggered lightning showing residual fields V. A. Rakov and V. Kodali Department of Electrical and Computer and 30 m from the negative lightning channel are used to examine the so-called residual electric field

  20. Experimental study of the residual stress-induced self-assembly of MEMS structures during deposition

    E-Print Network [OSTI]

    Kim, Sang-Hyun

    2005-11-01T23:59:59.000Z

    The possibility of using residual stresses favorably as a means of self-assembling MEMS during material deposition is experimentally investigated. Two atomic force microscope cantilevers are placed in contact at their free ends. Material...

  1. Vehicle Technologies Office Merit Review 2014: Residual Stress of Bimetallic Joints and Characterization

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about residual stress...

  2. Hanford Tank 241-S-112 Residual Waste Composition and Leach Test Data

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Krupka, Kenneth M.; Geiszler, Keith N.; Lindberg, Michael J.; Arey, Bruce W.; Schaef, Herbert T.

    2008-08-29T23:59:59.000Z

    This report presents the results of laboratory characterization and testing of two samples (designated 20406 and 20407) of residual waste collected from tank S-112 after final waste retrieval. These studies were completed to characterize the residual waste and assess the leachability of contami¬nants from the solids. This is the first report from this PNNL project to describe the composition and leach test data for residual waste from a salt cake tank. All previous PNNL reports (Cantrell et al. 2008; Deutsch et al. 2006, 2007a, 2007b, 2007c) describing contaminant release models, and characterization and testing results for residual waste in single-shell tanks were based on samples from sludge tanks.

  3. Root cause analysis of solder flux residue incidence in the manufacture of electronic power modules

    E-Print Network [OSTI]

    Jain, Pranav

    2011-01-01T23:59:59.000Z

    This work investigates the root causes of the incidence of solder flux residue underneath electronic components in the manufacture of power modules. The existing deionized water-based centrifugal cleaning process was ...

  4. Residual stresses and retained austenite distribution and evolution in SAE 52100 steel under rolling contact loading

    SciTech Connect (OSTI)

    Dommarco, R.C. [Univ. Nac Mar del Plata (Argentina); Kozaczek, K.J. [Oak Ridge National Lab., TN (United States); Hahn, G.T. [Vanderbilt Univ., Nashville, TN (United States)

    1996-07-01T23:59:59.000Z

    Residual stresses are introduced and modified during manufacturing and also by normal use. In this paper the changes in magnitude and distribution of residual stresses, attending the strain induced transformation of retained austenite are examined. Tests were conducted on SAE 52100 bearing steel with different amounts of retained austenite in a 5-ball-rod rolling contact fatigue machine. The tests were accelerated by applying well-controlled micro- indentations on the wear track and using rough balls. The magnitude and distribution of residual stresses and retained austenite were measured using x-ray diffraction techniques. The contribution of the residual stresses and amount of retained austenite to the rolling contact fatigue life is analyzed.

  5. E-Print Network 3.0 - atp binding residues Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Search Powered by Explorit Topic List Advanced Search Sample search results for: atp binding residues Page: << < 1 2 3 4 5 > >> 1 Asymmetric deceleration of ClpB or Hsp104...

  6. Minimizing Actuator-Induced Residual Error in Active Space Telescope Primary Mirrors

    E-Print Network [OSTI]

    . Smith, David W. Miller September 2010 SSL #12-10 #12;#12;Minimizing Actuator-Induced Residual Error in Active Space Telescope Primary Mirrors Matthew W. Smith, David W. Miller September 2010 SSL #12

  7. Rangeland Risk Management for Texans: Managing Residual Forage for Rangeland Health

    E-Print Network [OSTI]

    Hanselka, C. Wayne; White, Larry D.; Holechek, Jerry L.

    2002-01-11T23:59:59.000Z

    Livestock grazing is a tool for managing economic and climatic risk. Overgrazing increases a producer's risk should drought occur or market prices decline. This publication explains the importance of leaving enough forage residue to protect against...

  8. Table 42. Residual Fuel Oil Prices by PAD District and State

    Gasoline and Diesel Fuel Update (EIA)

    45.5 49.2 W W 44.5 45.4 See footnotes at end of table. 42. Residual Fuel Oil Prices by PAD District and State Energy Information Administration Petroleum...

  9. Table 42. Residual Fuel Oil Prices by PAD District and State

    U.S. Energy Information Administration (EIA) Indexed Site

    55.1 47.1 W W 55.1 46.2 See footnotes at end of table. 42. Residual Fuel Oil Prices by PAD District and State Energy Information Administration Petroleum...

  10. Evaluation of residual stress gradients in ductile cast iron using critical refracted longitudinal (Lcr) wave technique

    E-Print Network [OSTI]

    Pfluger, Ron Atlan

    1995-01-01T23:59:59.000Z

    improper or unnecessary heat-treatments extremely costly. Knowledge of the residual stress ipudient can make production of the component much more efficient and economicaL This knowledge could also be used to predict service life of components...

  11. US Apple Association Having an Impact Insecticide Residues in Apple Juice

    E-Print Network [OSTI]

    Ginzel, Matthew

    weeks ago we would have said two weeks early, right now we're saying maybe a week early. The cool syrup, soybeans, and milk for residues of a number of different pesticides. While I hate to bore you

  12. E-Print Network 3.0 - acid residues responsible Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    King Fahd University of Petroleum and Minerals Collection: Fossil Fuels 4 Protein folding with stochastic L-systems Gemma Danks1 Summary: 70 amino acid residues to 1000s...

  13. Using mobile distributed pyrolysis facilities to deliver a forest residue resource for bio-fuel production.

    E-Print Network [OSTI]

    Brown, Duncan

    2013-01-01T23:59:59.000Z

    ??Distributed mobile conversion facilities using either fast pyrolysis or torrefaction processes can be used to convert forest residues to more energy dense substances (bio-oil, bio-slurry… (more)

  14. Characterization of residual stress relaxation in welded steel plate using TAP-NDE and wavelets.

    E-Print Network [OSTI]

    Jhun, Choon-Sik

    2012-01-01T23:59:59.000Z

    ??This thesis presents the characterization of residual stress relaxation in a welded ASTM 1018 steel plate by using the Thermo-Acousto-Photonic Nondestructive Evaluation (TAP-NDE) technique and… (more)

  15. Control of residual aluminum from conventional treatment to improve reverse osmosis performance

    E-Print Network [OSTI]

    Gabelich, C J; Ishida, K P; Gerringer, F W; Evangelista, R; Kalyan, M; Suffet, I H

    2006-01-01T23:59:59.000Z

    2005. The Role of Dissolved Aluminum in Silica Chemistry forDraft Public Health Goal for Aluminum in Drinking Water .1994. Control of Residual Aluminum in Filtered Water . AWWA,

  16. Recovery of the Shear Modulus and Residual Stress of Hyperelastic Soft Tissues by Inverse Spectral Techniques

    E-Print Network [OSTI]

    Gou, Kun 1981-

    2012-11-15T23:59:59.000Z

    frequencies of the vessel wall material. As the IVUS is interrogating inside the artery, it produces small amplitude, high frequency time harmonic vibrations superimposed on the quasistatic deformation of the blood pressure pre-stressed and residually...

  17. A New Analytical Method to Quantify Residual Fluid Cleanup in Hydraulic Fractures

    E-Print Network [OSTI]

    Zarrin, Tahira

    2014-04-17T23:59:59.000Z

    hydraulic fracturing fluid has always been a major issue, and is believed to drastically undermine the performance of hydraulically fractured wells. Several attempts have been made to quantify the damage associated with residual fluid, with varying level...

  18. A survey of DDT residues in fish from the Brazos and Navasota Rivers and Somerville Reservoir

    E-Print Network [OSTI]

    Kramer, Robert Edwin

    1971-01-01T23:59:59.000Z

    A SURVEY OF DDT RESIDUES IN FISH FROM THE BRAZOS AND NAVASOTA RIVERS AND SOMERVILLE RESERVOIR A Thesis by ROBERT EDNIN KRAMER Submitted to the Graduate College of Texas AKIM University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE December 1971 Major Subject: Entomology A SURVEY OF DDT RESIDUES IN FISH FROM THE BRAZOS AND NAVASOTA RIVERS AND SOMERVILLE RESERVOIR A Thesis by ROBERT EDWIN KRAMER Approved as to style and content by (Chai rman of Committee...

  19. Deformations associated with relaxation of residual stresses in the Barre Granite of Vermont

    E-Print Network [OSTI]

    Nichols, Thomas Chester

    1972-01-01T23:59:59.000Z

    DEFORMATIONS ASSOCIATED WITH RELAXATION OF RESIDUAL STRESSES IN THE BARRE GRANITE OF VERMONT A Thesis by THOMAS CHESTER NICHOLS, JR. Submitted to the Graduate College of Texas AfM University in Partial fulfillment of the requirements... for the degree of MASTER QF SCIENCE May, 1972 Major Subject: Geology DEFORMATIONS ASSOCIATED WITH RELAXATION OF RESIDUAL STRESSES IN THE BARRE GRANITE OF VERMONT A Thesis THOMAS CHESTER NICHOLS, JR. Approved as to style and content by: airman o Committee...

  20. Time dependent ellipsoidal residual velocity distributions for self-gravitating systems of collisionless particles

    E-Print Network [OSTI]

    Simms, Frank Robert

    1973-01-01T23:59:59.000Z

    TIME DEPENDENT ELLIPSOIDAL RESIDUAL VELOCITY DISTRIBUTIONS FOR SELF-GRAVITATING SYSTEMS OF COLLISIONLESS PARTICLES A Thesis by FRANK ROBERT SINS Submitted to the Graduate College of Texas A&M University in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE May 1973 Major Subject: Physi cs TIME DEPENDENT ELLIPSOIDAL RESIDUAL VELOCITY DISTRIBUTIONS FOR SELF-GRAVITATING SYSTEMS OF COLLISIONLESS PARTICLES A Thesis by FRANK ROBERT SIMMS Approved as to style...

  1. Polymorphisms at amino acid residues 141 and 154 influence conformational variation in ovine PrP

    E-Print Network [OSTI]

    Yang, Sujeong; Thackray, Alana M.; Hopkins, Lee; Monie, Tom P.; Burke, David F.; Bujdoso, Raymond

    2014-07-14T23:59:59.000Z

    of helix-2, and the N- terminal region of helix-3. This central core is bound by an intramolecular disulphide bond between amino acid residues in helix-2 and helix-3. Characterisation of the protein folding events that occur during the conformational change... requirements of the particular protein fold or to particular functions mediated by interactions with other molecules. Crescendo conservation scores associated with every amino acid residue was assigned to the three-dimensional coordi- nate of the atommost...

  2. Determine metrics and set targets for soil quality on agriculture residue and energy crop pathways

    SciTech Connect (OSTI)

    Ian Bonner; David Muth

    2013-09-01T23:59:59.000Z

    There are three objectives for this project: 1) support OBP in meeting MYPP stated performance goals for the Sustainability Platform, 2) develop integrated feedstock production system designs that increase total productivity of the land, decrease delivered feedstock cost to the conversion facilities, and increase environmental performance of the production system, and 3) deliver to the bioenergy community robust datasets and flexible analysis tools for establishing sustainable and viable use of agricultural residues and dedicated energy crops. The key project outcome to date has been the development and deployment of a sustainable agricultural residue removal decision support framework. The modeling framework has been used to produce a revised national assessment of sustainable residue removal potential. The national assessment datasets are being used to update national resource assessment supply curves using POLYSIS. The residue removal modeling framework has also been enhanced to support high fidelity sub-field scale sustainable removal analyses. The framework has been deployed through a web application and a mobile application. The mobile application is being used extensively in the field with industry, research, and USDA NRCS partners to support and validate sustainable residue removal decisions. The results detailed in this report have set targets for increasing soil sustainability by focusing on primary soil quality indicators (total organic carbon and erosion) in two agricultural residue management pathways and a dedicated energy crop pathway. The two residue pathway targets were set to, 1) increase residue removal by 50% while maintaining soil quality, and 2) increase soil quality by 5% as measured by Soil Management Assessment Framework indicators. The energy crop pathway was set to increase soil quality by 10% using these same indicators. To demonstrate the feasibility and impact of each of these targets, seven case studies spanning the US are presented. The analysis has shown that the feedstock production systems are capable of simultaneously increasing productivity and soil sustainability.

  3. Growth response of selected vegetable species to plant residue of guar (Cyamopsis tetragonoloba (L.) Taub.)

    E-Print Network [OSTI]

    Reid, Debbie John

    1992-01-01T23:59:59.000Z

    GROWTH RESPONSE OF SELECTED VEGETABLE SPECIES TO PLANT RESIDUE OF GUAR (Cyamopsis tetragonoloba (L. ) Taub. ) A Thesis by DEBBIE JOHN REID Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1992 Major Subject: Horticulture GROWTH RESPONSE OF SELECTED VEGETABLE SPECIES TO PLANT RESIDUE OF GUAR (Cyamopsis tetragonoloba (L. ) Taub. ) A Thesis by DEBBIE JOHN REID Approved as to style...

  4. Residual thermal stresses in an unsymmetrical cross-ply graphite/epoxy laminate

    E-Print Network [OSTI]

    Harper, Brian Douglas

    2012-06-07T23:59:59.000Z

    RESIDUAL THERMAL STRESSES IN AN UNSYMMETRICAL CROSS-PLY GRAPHITE/EPOXY LAMINATE A Thesis by BRIAN DOUGLAS HARPER Submitted to the Graduate College of Texas A&M University in parrial fulfillment of the requirement for the degree of MASTER... OF SCIENCE August 1980 Major Subject: Mechanical Engineering RESIDUAL THERMAL STRESSES IN AN UNSYMMETRICAL CROSS-PLY GRAPHITE/EPOXY LAMINATE A Thesis by BRIAN DOUGLAS HARPER Approved as to style and content by: r. Y. N itsman (Chair of Committee) Dr...

  5. Development of source functions for modeling dissolution of residual DNAPL fingers in the saturated zone

    E-Print Network [OSTI]

    Johnson, Brian Scott

    2012-06-07T23:59:59.000Z

    DEVELOPMENT OF SOURCE FUNCTIONS FOR MODELING DISSOLUTION OF RESIDUAL DNAPL FINGERS IN THE SATURATED ZONE A Thesis by BRIAN SCOTT JOHNSON Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1993 Major Subject: Geology DEVELOPMENT OF SOURCE FUNCTIONS FOR MODELING DISSOLUTION OF RESIDUAL DNAPL FINGERS IN THE SATURATED ZONE A Thesis by BRIAN SCOTI' JOHNSON Submitted to Texas Agt...

  6. DISPOSAL OF EMPTY CHEMICAL CONTAINERS Empty chemical containers can contain residual amounts of chemicals. In an effort to ensure that this residue is

    E-Print Network [OSTI]

    Maroncelli, Mark

    containers or any plastic containers, plastic tubing, or plastic beakers that do not meet the recyclingDISPOSAL OF EMPTY CHEMICAL CONTAINERS Empty chemical containers can contain residual amounts or properly dispose of these containers, the following procedure has been developed by EHS in conjunction

  7. All auto shredding: evaluation of automotive shredder residue generated by shredding only vehicles.

    SciTech Connect (OSTI)

    Duranceau, C. M.; Spangenberger, J. S. (Energy Systems); (Vehicle Recycling Partnership, LLC); (American Chemistry Counsel, Plastics Division)

    2011-09-26T23:59:59.000Z

    A well developed infrastructure exists for the reuse and recycling of automotive parts and materials. At the end of a vehicle's useful life many parts are removed and sold for reuse and fluids are recovered for recycling or proper disposal. What remains is shredded, along with other metal bearing scrap such as home appliances, demolition debris and process equipment, and the metals are separated out and recycled. The remainder of the vehicle materials is call shredder residue which ends up in the landfill. As energy and natural resources becomes more treasured, increased effort has been afforded to find ways to reduce energy consumption and minimize the use of our limited resources. Many of the materials found in shredder residue could be recovered and help offset the use of energy and material consumption. For example, the energy content of the plastics and rubbers currently landfilled with the shredder residue is equivalent to 16 million barrels of oil per year. However, in the United States, the recovered materials, primarily polymers, cannot be recycled due to current regulatory barriers which preclude the re-introduction into commerce of certain materials because of residual contamination with substances of concern (SOCs) such as polychlorinated biphenyls (PCBs). The source of the PCBs is not well understood. Old transformers, capacitors, white goods and ballasts from lighting fixtures are likely contributing factors. The project was designed to evaluate whether vehicles of varying age and manufacturing origin contribute to the PCB content in shredder residue. Additionally, the project was designed to determine if there are any trends in material composition of the shredder residue from varied age and manufacturing groups. This information would aid in future material recovery facility strategy and design. The test utilized a newly installed shredder plant to shred four categories of automobiles. The categories were defined by vehicle age and the manufacturing company and location. Each category of vehicles was processed individually through the shredder plant and the resulting shredder residue was analyzed for its materials composition and presence of PCBs and leachable metals. The results show that shredder residue from all vehicle categories tested are not significant contributors of PCBs and leachable metals. It was evident that leachable cadmium levels have decreased in newer vehicles. The composition of the shredder residue from each of the four categories is similar to the others. In addition, these compositions are approximately equal to the composition of typical shredder residues, not limited to automotive materials.

  8. Thermodynamic Model for Uranium Release from Hanford Site Tank Residual Waste

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Deutsch, William J.; Lindberg, Michael J.

    2011-01-26T23:59:59.000Z

    A thermodynamic model of U phase solubility and paragenesis was developed for Hanford tank residual waste that will remain after tank closure. The model was developed using a combination of waste composition data, waste leach test data, and thermodynamic modeling of the leach test data. The testing and analyses were conducted using actual Hanford tank residual waste. Positive identification of the U phases by X-ray diffraction (XRD) was generally not possible because solids in the waste were amorphous, or below the detection limit of XRD for both as-received residual waste and leached residual waste. Three leachant solutions were used in the studies, dionized water, CaCO3 saturated solution, and Ca(OH)2 saturated solution. Thermodynamic modeling verified that equilibrium between U phases in the initial residual waste samples and the leachants was attained in less than a month. The paragenetic sequence of secondary phases that occur as waste leaching progresses for two closure scenarios was identified. These results have significant implications for tank closure design.

  9. Cofiring lignite with hazelnut shell and cotton residue in a pilot-scale fluidized bed combustor

    SciTech Connect (OSTI)

    Zuhal Gogebakan; Nevin Selcuk [Middle East Technical University, Ankara (Turkey). Department of Chemical Engineering

    2008-05-15T23:59:59.000Z

    In this study, cofiring of high ash and sulfur content lignite with hazelnut shell and cotton residue was investigated in 0.3 MWt METU Atmospheric Bubbling Fluidized Bed Combustion (ABFBC) Test Rig in terms of combustion and emission performance of different fuel blends. The results reveal that cofiring of hazelnut shell and cotton residue with lignite increases the combustion efficiency and freeboard temperatures compared to those of lignite firing with limestone addition only. CO{sub 2} emission is not found sensitive to increase in hazelnut shell and cotton residue share in fuel blend. Cofiring lowers SO{sub 2} emissions considerably. Cofiring of hazelnut shell reduces NO and N{sub 2}O emissions; on the contrary, cofiring cotton residue results in higher NO and N{sub 2}O emissions. Higher share of biomass in the fuel blend results in coarser cyclone ash particles. Hazelnut shell and cotton residue can be cofired with high ash and sulfur-containing lignite without operational problems. 32 refs., 12 figs., 11 tabs.

  10. Evaluation of filter media for clarification of partially dissolved residues containing plutonium

    SciTech Connect (OSTI)

    Foley, E.S.

    1989-10-09T23:59:59.000Z

    A common process in the chemical industry employs the leaching of a desirable component from an insoluble substrate, followed by filtration to produce a clarified solution of the desirable component and a discardable residue. The work described here involved evaluating sintered metal filter media for separating dissolved plutonium from undissolved residues generated at various locations owned by the Department of Energy throughout the United States. The work was performed during a six-week assignment at the Savannah River Laboratory as part of a high school science enrichment program conducted in the summer of 1989. The leach step used included dissolving the plutonium-containing solids in a solution of nitric-hydrofluoric acid. To simulate the partial solubility of the actual plutonium-containing residues, a non-radioactive power plant flyash was used. 6 refs., 14 figs., 1 tab.

  11. Diagnosing residual motion via the x-ray self emission from indirectly driven inertial confinement implosions

    SciTech Connect (OSTI)

    Pak, A., E-mail: pak5@llnl.gov; Field, J. E.; Benedetti, L. R.; Caggiano, J.; Hatarik, R.; Izumi, N.; Khan, S. F.; Ma, T.; Spears, B. K.; Town, R. P. J.; Bradley, D. K. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Knauer, J. [Laboratory for Laser Energetics, Rochester, New York 14623 (United States)

    2014-11-15T23:59:59.000Z

    In an indirectly driven implosion, non-radial translational motion of the compressed fusion capsule is a signature of residual kinetic energy not coupled into the compressional heating of the target. A reduction in compression reduces the peak pressure and nuclear performance of the implosion. Measuring and reducing the residual motion of the implosion is therefore necessary to improve performance and isolate other effects that degrade performance. Using the gated x-ray diagnostic, the x-ray Bremsstrahlung emission from the compressed capsule is spatially and temporally resolved at x-ray energies of >8.7 keV, allowing for measurements of the residual velocity. Here details of the x-ray velocity measurement and fitting routine will be discussed and measurements will be compared to the velocities inferred from the neutron time of flight detectors.

  12. Method for using global optimization to the estimation of surface-consistent residual statics

    DOE Patents [OSTI]

    Reister, David B. (Knoxville, TN); Barhen, Jacob (Oak Ridge, TN); Oblow, Edward M. (Knoxville, TN)

    2001-01-01T23:59:59.000Z

    An efficient method for generating residual statics corrections to compensate for surface-consistent static time shifts in stacked seismic traces. The method includes a step of framing the residual static corrections as a global optimization problem in a parameter space. The method also includes decoupling the global optimization problem involving all seismic traces into several one-dimensional problems. The method further utilizes a Stochastic Pijavskij Tunneling search to eliminate regions in the parameter space where a global minimum is unlikely to exist so that the global minimum may be quickly discovered. The method finds the residual statics corrections by maximizing the total stack power. The stack power is a measure of seismic energy transferred from energy sources to receivers.

  13. The National Nuclear Laboratory's Approach to Processing Mixed Wastes and Residues - 13080

    SciTech Connect (OSTI)

    Greenwood, Howard; Docrat, Tahera; Allinson, Sarah J.; Coppersthwaite, Duncan P.; Sultan, Ruqayyah; May, Sarah [National Nuclear Laboratory, Springfields, Preston, UK, PR4 0XJ (United Kingdom)] [National Nuclear Laboratory, Springfields, Preston, UK, PR4 0XJ (United Kingdom)

    2013-07-01T23:59:59.000Z

    The National Nuclear Laboratory (NNL) treats a wide variety of materials produced as by-products of the nuclear fuel cycle, mostly from uranium purification and fuel manufacture but also including materials from uranium enrichment and from the decommissioning of obsolete plants. In the context of this paper, treatment is defined as recovery of uranium or other activity from residues, the recycle of uranium to the fuel cycle or preparation for long term storage and the final disposal or discharge to the environment of the remainder of the material. NNL's systematic but flexible approach to residue assessment and treatment is described in this paper. The approach typically comprises up to five main phases. The benefits of a systematic approach to waste and residue assessments and processing are described in this paper with examples used to illustrate each phase of work. Benefits include early identification of processing routes or processing issues and the avoidance of investment in inappropriate and costly plant or processes. (authors)

  14. Distribution and fate of technical chlordane and mirex residues in a central Texas aquatic ecosystem

    E-Print Network [OSTI]

    Janssen, Harold Erle

    1976-01-01T23:59:59.000Z

    DIST!(IDU!'IO;l AitlD l=A! E OF TEC;lN!CAL CNLOROAN. Al, 'D illREX RESIDUES IiN A CEiNTRAL TLXAS AQUA IC ECOSYSTEH A Thesis by HAROLD ERLE JANSSEN, JR. Submitted to the Graduate College o F Texas Anil Universi ty in partia1 fulfillment... of the requirement for the dec!ree of NASTER OF SC1El&CE Nay 1976 Najor Subject: Civil Engineering DISTRIBUTION AND FATE OF TECHNICAL CHLORDAI'lE AND llIREX RESIDUES IN A CENTRAl TEXAS AQUATIC ECOSYSTEM A Thesis by HAROLD ERLE JANSSEN, JR. Approved...

  15. The investigation of the effects of wettability on residual oil after water flooding

    E-Print Network [OSTI]

    Burja, Edward Oscar

    1953-01-01T23:59:59.000Z

    THE INVESTIGATION OF THE EFFECTS OF WETTABILITY ON RESIDUAL OIL AFTER WATER FLOODING A Thesis BY E. 0, BUR JA Approved as to style and content by: (Cha rman of C mmittee (Head of Department) (Mo th (Year) THE INVESTIGATION OF THE EFFECTS... OF WETTABILITY ON RESIDUAL OIL AFTER WATER FLOODING By E. O. Burja A Thesis Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Major Subject...

  16. An efficient method to compute the residual phase on a Lefschetz thimble

    E-Print Network [OSTI]

    M. Cristoforetti; F. Di Renzo; G. Eruzzi; A. Mukherjee; C. Schmidt; L. Scorzato; C. Torrero

    2014-06-14T23:59:59.000Z

    We propose an efficient method to compute the so-called residual phase that appears when performing Monte Carlo calculations on a Lefschetz thimble. The method is stochastic and its cost scales linearly with the physical volume, linearly with the number of stochastic estimators and quadratically with the length of the extra dimension along the gradient flow. This is a drastic improvement over previous estimates of the cost of computing the residual phase. We also report on basic tests of correctness and scaling of the code.

  17. Hanford Site Tank 241-C-108 Residual Waste Contaminant Release Models and Supporting Data

    SciTech Connect (OSTI)

    Cantrell, Kirk J.; Krupka, Kenneth M.; Geiszler, Keith N.; Arey, Bruce W.; Schaef, Herbert T.

    2010-06-18T23:59:59.000Z

    This report presents the results of laboratory characterization, testing, and analysis for a composite sample (designated 20578) of residual waste collected from single-shell tank C-108 during the waste retrieval process after modified sluicing. These studies were completed to characterize concentration and form of contaminant of interest in the residual waste; assess the leachability of contaminants from the solids; and develop release models for contaminants of interest. Because modified sluicing did not achieve 99% removal of the waste, it is expected that additional retrieval processing will take place. As a result, the sample analyzed here is not expected to represent final retrieval sample.

  18. Apparatus and method for rapid detection of explosives residue from the deflagration signature thereof

    DOE Patents [OSTI]

    Funsten, H.O.; McComas, D.J.

    1999-06-15T23:59:59.000Z

    Apparatus and method are disclosed for rapid detection of explosives residue from the deflagration signature thereof. A property inherent to most explosives is their stickiness, resulting in a strong tendency of explosive particulate to contaminate the environment of a bulk explosive. An apparatus for collection of residue particulate, burning the collected particulate, and measurement of the ultraviolet emission produced thereby, is described. The present invention can be utilized for real-time screening of personnel, cars, packages, suspected devices, etc., and provides an inexpensive, portable, and noninvasive means for detecting explosives. 4 figs.

  19. Natural Gamma Emitters after a Selective Chemical Separation of a TENORM residue: Preliminary Results

    SciTech Connect (OSTI)

    Alves de Freitas, Antonio; Abrao, Alcidio [Centro de Quimica e do Meio Ambiente (Brazil); Godoy dos Santos, Adir Janete; Pecequilo, Brigitte Roxana Soreanu [Centro de Metrologia das Radiacoes Instituto de Pesquisas Energeticas e Nucleares Av. Prof. Lineu Prestes, 2242-Cidade Universitaria-Zip Code 05508-000 Sao Paulo-SP (Brazil)

    2008-08-07T23:59:59.000Z

    An analytical procedure was established in order to obtain selective fractions containing radium isotopes ({sup 228}Ra), thorium ({sup 232}Th), and rare earths from RETOTER (REsiduo de TOrio e TErras Raras), a solid residue rich in rare earth elements, thorium isotopes and small amount of natural uranium generated from the operation of a thorium pilot plant for purification and production of pure thorium nitrate at IPEN -CNEN/SP. The paper presents preliminary results of {sup 228}Ra, {sup 226}Ra, {sup 238}U, {sup 210}Pb, and {sup 40}K concentrations in the selective fractions and total residue determined by high-resolution gamma spectroscopy, considering radioactive equilibrium of the samples.

  20. Application of the residue number system to the matrix multiplication problem

    E-Print Network [OSTI]

    Chard, Gary Franklin

    2012-06-07T23:59:59.000Z

    Global Considerations 96 97 98 98 100 Design Comparison 6. 4. 1 Comparison Structure 101 102 TABLE OF CONTENTS (Continued) 6. d. 2 Time and Area Comparison VII CONCLUSION Page 103 105 7. 1 Contributions 7. 2 Future Research 106 108... to Residue 2. 4 The Chinese Remainder Theorem 2. 5 Sign Representation of a Residue Number 2. 6 Introduction to Matrix Multiplication 15 16 18 19 21 22 2. 7 The Matrix Multiplication Algorithm 2. 7. 1 The Multiply and Add Cell 2. 7. 2 Formulation...

  1. JOURNAL OF MATERIALS SCIENCE: MATERIALS IN ELECTRONICS 12 (2001) 143146 Residual strain and texture in strontium-doped

    E-Print Network [OSTI]

    Garmestani, Hamid

    of the residual strain/stress is needed because most deposited thin ®lms are under some kind of residual (internalJOURNAL OF MATERIALS SCIENCE: MATERIALS IN ELECTRONICS 12 (2001) 143±146 Residual strain@magnet.fsu.edu Thin ®lms of La0:67Sr0:33MnO3 (LSMO) have been deposited using liquid-delivery metal- organic chemical

  2. HOST GALAXY PROPERTIES AND HUBBLE RESIDUALS OF TYPE Ia SUPERNOVAE FROM THE NEARBY SUPERNOVA FACTORY

    SciTech Connect (OSTI)

    Childress, M.; Aldering, G.; Aragon, C.; Bailey, S.; Fakhouri, H. K.; Hsiao, E. Y.; Kim, A. G.; Loken, S. [Physics Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Antilogus, P.; Bongard, S.; Canto, A.; Cellier-Holzem, F.; Guy, J. [Laboratoire de Physique Nucleaire et des Hautes Energies, Universite Pierre et Marie Curie Paris 6, Universite Paris Diderot Paris 7, CNRS-IN2P3, 4 place Jussieu, F-75252 Paris Cedex 05 (France); Baltay, C. [Department of Physics, Yale University, New Haven, CT 06250-8121 (United States); Buton, C.; Kerschhaggl, M.; Kowalski, M. [Physikalisches Institut, Universitaet Bonn, Nussallee 12, D-53115 Bonn (Germany); Chotard, N.; Copin, Y.; Gangler, E. [Universite de Lyon, F-69622, Lyon (France); Universite de Lyon 1, Villeurbanne (France); CNRS/IN2P3, Institut de Physique Nucleaire de Lyon (France); and others

    2013-06-20T23:59:59.000Z

    We examine the relationship between Type Ia supernova (SN Ia) Hubble residuals and the properties of their host galaxies using a sample of 115 SNe Ia from the Nearby Supernova Factory. We use host galaxy stellar masses and specific star formation rates fitted from photometry for all hosts, as well as gas-phase metallicities for a subset of 69 star-forming (non-active galactic nucleus) hosts, to show that the SN Ia Hubble residuals correlate with each of these host properties. With these data we find new evidence for a correlation between SN Ia intrinsic color and host metallicity. When we combine our data with those of other published SN Ia surveys, we find the difference between mean SN Ia brightnesses in low- and high-mass hosts is 0.077 {+-} 0.014 mag. When viewed in narrow (0.2 dex) bins of host stellar mass, the data reveal apparent plateaus of Hubble residuals at high and low host masses with a rapid transition over a short mass range (9.8 {<=} log (M{sub *}/M{sub Sun }) {<=} 10.4). Although metallicity has been a favored interpretation for the origin of the Hubble residual trend with host mass, we illustrate how dust in star-forming galaxies and mean SN Ia progenitor age both evolve along the galaxy mass sequence, thereby presenting equally viable explanations for some or all of the observed SN Ia host bias.

  3. Nuclear reactor with makeup water assist from residual heat removal system

    DOE Patents [OSTI]

    Corletti, Michael M. (New Kensington, PA); Schulz, Terry L. (Murrysville, PA)

    1993-01-01T23:59:59.000Z

    A pressurized water nuclear reactor uses its residual heat removal system to make up water in the reactor coolant circuit from an in-containment refueling water supply during staged depressurization leading up to passive emergency cooling by gravity feed from the refueling water storage tank, and flooding of the containment building. When depressurization commences due to inadvertence or a manageable leak, the residual heat removal system is activated manually and prevents flooding of the containment when such action is not necessary. Operation of the passive cooling system is not impaired. A high pressure makeup water storage tank is coupled to the reactor coolant circuit, holding makeup coolant at the operational pressure of the reactor. The staged depressurization system vents the coolant circuit to the containment, thus reducing the supply of makeup coolant. The level of makeup coolant can be sensed to trigger opening of successive depressurization conduits. The residual heat removal pumps move water from the refueling water storage tank into the coolant circuit as the coolant circuit is depressurized, preventing reaching the final depressurization stage unless the makeup coolant level continues to drop. The residual heat removal system can also be coupled in a loop with the refueling water supply tank, for an auxiliary heat removal path.

  4. Nuclear reactor with makeup water assist from residual heat removal system

    DOE Patents [OSTI]

    Corletti, M.M.; Schulz, T.L.

    1993-12-07T23:59:59.000Z

    A pressurized water nuclear reactor uses its residual heat removal system to make up water in the reactor coolant circuit from an in-containment refueling water supply during staged depressurization leading up to passive emergency cooling by gravity feed from the refueling water storage tank, and flooding of the containment building. When depressurization commences due to inadvertence or a manageable leak, the residual heat removal system is activated manually and prevents flooding of the containment when such action is not necessary. Operation of the passive cooling system is not impaired. A high pressure makeup water storage tank is coupled to the reactor coolant circuit, holding makeup coolant at the operational pressure of the reactor. The staged depressurization system vents the coolant circuit to the containment, thus reducing the supply of makeup coolant. The level of makeup coolant can be sensed to trigger opening of successive depressurization conduits. The residual heat removal pumps move water from the refueling water storage tank into the coolant circuit as the coolant circuit is depressurized, preventing reaching the final depressurization stage unless the makeup coolant level continues to drop. The residual heat removal system can also be coupled in a loop with the refueling water supply tank, for an auxiliary heat removal path. 2 figures.

  5. A METHODOLOGY FOR THE CONTROL OF THE RESIDUAL LIFETIMES OF CARBON FIBRE

    E-Print Network [OSTI]

    Boyer, Edmond

    on composite materials, France (2005)" #12;carbon fibre composites are considered by these authors as beingA METHODOLOGY FOR THE CONTROL OF THE RESIDUAL LIFETIMES OF CARBON FIBRE REINFORCED COMPOSITE of their loading history with precision. KEYWORDS: pressure vessels, carbon fibre composites, life time prediction

  6. An Experimental/Computational Approach to Identify Moduli and Residual Stress

    E-Print Network [OSTI]

    Espinosa, Horacio D.

    and uniformity of measured load­deflection curves on a number of switches with both wedge and Berkovich tips has a strong effect on load­ deflection curves; hence, its accurate characterization is crit- ical stress state affect the load­deflection curve in dif- ferent regimes. Changes in residual stress state

  7. CSER 96-027: storage of cemented plutonium residue containers in 55 gallon drums

    SciTech Connect (OSTI)

    Watson, W.T.

    1997-01-20T23:59:59.000Z

    A nuclear criticality safety analysis has been performed for the storage of residual plutonium cementation containers, produced at the Plutonium Finishing Plant, in 55 gallon drums. This CSER increases the limit of total plutonium stored in each 55 gallon drum from 100 to 200 grams.

  8. The effect of residuals on the presence of intergranular surface cracks on continuously cast billets

    SciTech Connect (OSTI)

    Wijngaarden, M.J.U.T. van; Visagie, G.P.

    1996-12-31T23:59:59.000Z

    During 1991, Iscor Vereeniging experienced a dramatic increase in the rejection rate of specialty steel bars rolled from continuously cast billets due to the presence of seams on the bars. The seams originated from tearing of the billets during the first 2 passes in the roughing mill during hot rolling. The defective billets were found to contain fine intergranular cracks on the surface. Such cracks have been described in the literature and have been attributed to the presence of high levels of residuals resulting in the well-known phenomenon of surface hot shortness which results from the enrichment of residuals at the grain boundaries after preferential oxidation of iron during scaling of the steel. The present investigation revealed that the effect of residuals on intergranular surface cracking is a complex interaction between steel composition and casting conditions such as casting speed, intensity of secondary cooling, section size, and mold type. This paper quantifies the effect of residuals on the intergranular surface cracking of continuously cast billets and quantitatively relates the incidence of these cracks to parameters which can be controlled during steelmaking and continuous casting.

  9. REUSE AND RECYCLE OF BIO-RESIDUE (PERCOLATE) FROM CONSTRUCTED WETLAND TREATING SEPTAGE

    E-Print Network [OSTI]

    Richner, Heinz

    REUSE AND RECYCLE OF BIO-RESIDUE (PERCOLATE) FROM CONSTRUCTED WETLAND TREATING SEPTAGE by Sukon of percolate from constructed wetland (CW) treating septage in agricultural application with the specific focus CW treating septage could exhibit positive responses of the plant growth which increase seed yield

  10. Relationship between Hot Spot Residues and Ligand Binding Hot Spots in Protein-Protein Interfaces

    E-Print Network [OSTI]

    Vajda, Sandor

    , while identification of a hot spot by alanine scanning establishes the potential to generate substantial, termed "hot spots", that comprise the subset of residues that contribute the bulk of the binding free proposed as prime targets for drug binding.1,4 The established approach to the identification of such hot

  11. A Comparative Study of Amyloid Fibril Formation by Residues 1519 of the Human Calcitonin Hormone: A

    E-Print Network [OSTI]

    Haspel, Nurit

    A Comparative Study of Amyloid Fibril Formation by Residues 15­19 of the Human Calcitonin Hormone highly ordered fibrils, similar to those formed by the entire hormone sequence. However-sheet amyloid fibril. We observe that the most important chemical interactions contributing to the stability

  12. Estimates of the Loss of Main-Chain Conformational Entropy of Different Residues on Protein Folding

    E-Print Network [OSTI]

    Pal, Debnath

    Estimates of the Loss of Main-Chain Conformational Entropy of Different Residues on Protein Folding energy of protein folding is not well understood. We have developed empirical scales for the loss; protein folding; pro- tein engineering INTRODUCTION When a protein folds into a compact globule, the resi

  13. Logging Residue Volumes and Characteristics following Integrated Roundwood and Energy-Wood

    E-Print Network [OSTI]

    Wagner, Robert G.

    considered waste material. In recent years, however, the reemergence of the bioenergy industry has revived the market for these residues, and demand for this ma- terial is likely to increase with increasing oil are projected to provide one-third of the billion-ton biomass feedstock needed for the emerging bioenergy

  14. RESIDUAL STRESS DISTRIBUTIONS FOR MULTI-PASS WELDS IN PRESSURE VESSEL AND PIPING COMPONENTS

    E-Print Network [OSTI]

    Michaleris, Panagiotis

    RESIDUAL STRESS DISTRIBUTIONS FOR MULTI-PASS WELDS IN PRESSURE VESSEL AND PIPING COMPONENTS distributions in common pressure vessel and piping components is generated by using the multi-pass finite-walled pipes with various radius to thickness ratios. Both single- and double-V weld joints are investigated

  15. Hanford Tank 241-C-106: Impact of Cement Reactions on Release of Contaminants from Residual Waste

    SciTech Connect (OSTI)

    Deutsch, William J.; Krupka, Kenneth M.; Lindberg, Michael J.; Cantrell, Kirk J.; Brown, Christopher F.; Schaef, Herbert T.

    2006-09-01T23:59:59.000Z

    The CH2M HILL Hanford Group, Inc. (CH2M HILL) is producing risk/performance assessments to support the closure of single-shell tanks at the U.S. Department of Energy's Hanford Site. As part of this effort, staff at Pacific Northwest National Laboratory were asked to develop release models for contaminants of concern that are present in residual sludge remaining in tank 241-C-106 (C-106) after final retrieval of waste from the tank. Initial work to produce release models was conducted on residual tank sludge using pure water as the leaching agent. The results were reported in an earlier report. The decision has now been made to close the tanks after waste retrieval with a cementitious grout to minimize infiltration and maintain the physical integrity of the tanks. This report describes testing of the residual waste with a leaching solution that simulates the composition of water passing through the grout and contacting the residual waste at the bottom of the tank.

  16. Characterization of residual stress relaxation in welded steel plate using TAP-NDE and wavelets

    E-Print Network [OSTI]

    Jhun, Choon-Sik

    2001-01-01T23:59:59.000Z

    residual stresses. Immediately after each oven-curing procedure, laser-generated surface acoustic waves (SAW) were initiated in the welded steel plate using a Q-switched Nd:YAG (neodymium-doped yttrium aluminum garnet) pulsed laser and then acquired using...

  17. Residual eye-movements in macaque and their effects on visual responses of neurons

    E-Print Network [OSTI]

    Nottingham, University of

    Residual eye-movements in macaque and their effects on visual responses of neurons JASON FORTE, with high precision, the positions of the eyes in anesthetized macaque monkeys prepared for physiological recording. Most recordings were made after the infusion of muscle relaxant to immobilize the eyes; in some

  18. The nuclear density of states and the role of the residual interaction

    E-Print Network [OSTI]

    Calvin W. Johnson; Edgar Teran

    2005-12-02T23:59:59.000Z

    We discuss the role of mean-field and moment methods in microscopic models for calculating the nuclear density of states (also known as the nuclear level density). Working in a shell-model framework, we use moments of the nuclear many-body Hamiltonian to illustrate the importance of the residual interaction for accurate representations.

  19. Cold drawn steel wires--processing, residual stresses and ductility Part II: Synchrotron and neutron diffraction

    E-Print Network [OSTI]

    Cold drawn steel wires--processing, residual stresses and ductility Part II: Synchrotron Received in final form 29 September 2005 ABSTRACT Cold drawing of steel wires leads to an increase proposed that cold drawing would induce a phase transformation of the steel, possibly a martensitic

  20. Ultrasonic measurement of the residual stresses in patch welded steel plates

    E-Print Network [OSTI]

    Junghans, Paul Gerard

    1994-01-01T23:59:59.000Z

    , structural steel plates. The two 1.2 in (48 in.) square plates were patch welded in the center to create a residual stress field; and subsequently, one of the plates was stress relieved. The LCR travel-time measurements on the plates not only differentiated...

  1. Species-specific residues calibrate SoxR sensitivity to redox-active molecules

    E-Print Network [OSTI]

    Dietrich, Lars

    to viologens, which have redox potentials below -350 mV. Using a mutagenic approach, we pin- pointed threeSpecies-specific residues calibrate SoxR sensitivity to redox-active molecules Rebecca Sheplock,1, the transcription factor SoxR triggers a global stress response by sensing a broad spectrum of redox

  2. PROTEIN FOLD RECOGNITION USING RESIDUE-BASED ALIGNMENTS OF SEQUENCE AND SECONDARY STRUCTURE

    E-Print Network [OSTI]

    Erdogan, Hakan

    PROTEIN FOLD RECOGNITION USING RESIDUE-BASED ALIGNMENTS OF SEQUENCE AND SECONDARY STRUCTURE Zafer methods [3,4]. Index Terms- protein fold recognition, secondary structure alignment, amino acid alignment &sabanciuniv.edu culated for each sequence-structure alignment. Protein fold recog- nition problem can

  3. Electric charge trapping, residual stresses and properties of ceramics after metal/ceramics bonding

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    and diffusion of metallic species in the ceramics, during the bonding process. Keywords: Joining; ToughnessElectric charge trapping, residual stresses and properties of ceramics after metal/ceramics bonding applications is rapidly increasing. Most of these applications require the use of ceramics bonded with metal

  4. Energy-Efficient Reliable Routing Considering Residual Energy in Wireless Ad Hoc Networks

    E-Print Network [OSTI]

    Langendoen, Koen

    Energy-Efficient Reliable Routing Considering Residual Energy in Wireless Ad Hoc Networks Javad minimum energy routing (RMER). RMECR addresses three important requirements of ad hoc networks: energy-efficiency energy of nodes as well as quality of links to find energy-efficient and reliable routes that increase

  5. Engineered Heart Tissue Enables Study of Residual Undifferentiated Embryonic Stem Cell Activity in a

    E-Print Network [OSTI]

    Zandstra, Peter W.

    ARTICLE Engineered Heart Tissue Enables Study of Residual Undifferentiated Embryonic Stem Cell, Canada, M5S 3G9 6 Heart and Stroke/Richard Lewar Centre of Excellence, Toronto, Ontario, Canada, M5S 3G9 cell survival. As an alternative, we have used an engineered heart tissue (EHT) based on neonatal rat

  6. PROPERTIES OF RESIDUALS FOR SPATIAL POINT PROCESSES A. BADDELEY, # University of Western Australia

    E-Print Network [OSTI]

    Baddeley, Adrian

    PROPERTIES OF RESIDUALS FOR SPATIAL POINT PROCESSES A. BADDELEY, # University of Western Australia J. MØLLER, ## University of Aalborg A.G. PAKES, # University of Western Australia Abstract For any address: School of Mathematics & Statistics M019, University of Western Australia, 35 Stirling Highway

  7. Investigation of residual stresses induced during the selective laser melting process

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    jean-claude.boyer@insa-lyon.fr Keywords: Selective laser melting, layer additional method, Residual stresses. Abstract. The selective laser melting process (SLM), belonging to the family of additive manufacturing processes, can create complex geometry parts from a CAD file. Previously, only prototypes were

  8. From residue matching patterns to protein folding topographies: General model and bovine

    E-Print Network [OSTI]

    Berry, R. Stephen

    From residue matching patterns to protein folding topographies: General model and bovine pancreatic-grained model for protein-folding dynamics is introduced based on a discretized representation of torsional, pattern recognition, and general characteristics of protein folding kinetics. Topology here implies

  9. Incineration of Residue from Paint Stripping Operations Using Plastic Media Blasting

    E-Print Network [OSTI]

    Helt, J. E.; Mallya, N.

    i INCINERATION OF RESIDUE FROH PAINT STRIPPING OPERATIONS USING PLASTIC MEDIA BLASTING J. E. HELT N. MALLYA Group Leader Chemist Chemical Technology Division Chemical Technology Division Argonne National Laboratory Argonne National... Laboratory Argonne, Illinois Argonne, Illinois ABSTRACT A preliminary investigation has been performed on the environmental consequences of incinerating plastic-media-blasting (PHB) wastes from paint removal operations. PHB is similar to sandblasting...

  10. SOLID PHASE MICROEXTRACTION SAMPLING OF FIRE DEBRIS RESIDUES IN THE PRESENCE OF RADIONUCLIDE SURROGATE METALS

    SciTech Connect (OSTI)

    Duff, M; Keisha Martin, K; S Crump, S

    2007-03-23T23:59:59.000Z

    The Federal Bureau of Investigation (FBI) Laboratory currently does not have on site facilities for handling radioactive evidentiary materials and there are no established FBI methods or procedures for decontaminating highly radioactive fire debris (FD) evidence while maintaining evidentiary value. One experimental method for the isolation of FD residue from radionuclide metals involves using solid phase microextraction (SPME) fibers to remove the residues of interest. Due to their high affinity for organics, SPME fibers should have little affinity for most (radioactive) metals. The focus of this research was to develop an examination protocol that was applicable to safe work in facilities where high radiation doses are shielded from the workers (as in radioactive shielded cells or ''hot cells''). We also examined the affinity of stable radionuclide surrogate metals (Co, Ir, Re, Ni, Ba, Cs, Nb, Zr and Nd) for sorption by the SPME fibers. This was done under exposure conditions that favor the uptake of FD residues under conditions that will provide little contact between the SPME and the FD material (such as charred carpet or wood that contains commonly-used accelerants). Our results from mass spectrometric analyses indicate that SPME fibers show promise for use in the room temperature head space uptake of organic FD residue (namely, diesel fuel oil, kerosene, gasoline and paint thinner) with subsequent analysis by gas chromatography (GC) with mass spectrometric (MS) detection. No inorganic forms of ignitable fluids were included in this study.

  11. Molecular gas in early-type galaxies: Fuel for residual star formation

    E-Print Network [OSTI]

    Bureau, Martin

    Abstract: Molecular gas in early-type galaxies: Fuel for residual star formation Timothy A. Davis Survey 2. The ATLAS3D CARMA Survey 3. Kinematic Misalignments 4. Origin of the molecular gas The ATLAS3D is to determine how (major and minor) mergers, gas, star formation and feedback affect the transformation

  12. Investigating citizens' preferences for recycling Residual Organic Products in agriculture: a choice experiment approach

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    in France (excluding agriculture waste) [1], the recycling of urban organic waste is a strong environmentalInvestigating citizens' preferences for recycling Residual Organic Products in agriculture or mineral fertilizers. The paper addresses in particular 3 environmental effects: the organic waste

  13. FISHERY WASTE EFFLUENTS: A METHOD TO DETERMINE RELATIONSHIPS BETWEEN CHEMICAL OXYGEN DEMAND AND RESIDUE

    E-Print Network [OSTI]

    FISHERY WASTE EFFLUENTS: A METHOD TO DETERMINE RELATIONSHIPS BETWEEN CHEMICAL OXYGEN DEMAND effluents, especially for total suspended and settleable solids, and oil and grease. The relationship between chemical oxygen demand and residue was determined on a limited number of samples from four types

  14. Determination of residual monomers resulting from the chemical polymerization process of dental materials

    SciTech Connect (OSTI)

    Boboia, S. [Babes Bolyai University, Raluca Ripan Chemistry Research Institute, Department of Polymer Composites, 400294 Cluj-Napoca, Romania and Technical University of Cluj-Napoca, Physics and Chemistry Department, 400114 Cluj-Napoca (Romania)] [Babes Bolyai University, Raluca Ripan Chemistry Research Institute, Department of Polymer Composites, 400294 Cluj-Napoca, Romania and Technical University of Cluj-Napoca, Physics and Chemistry Department, 400114 Cluj-Napoca (Romania); Moldovan, M. [Babes Bolyai University, Raluca Ripan Chemistry Research Institute, Department of Polymer Composites, 400294 Cluj-Napoca (Romania)] [Babes Bolyai University, Raluca Ripan Chemistry Research Institute, Department of Polymer Composites, 400294 Cluj-Napoca (Romania); Ardelean, I. [Technical University of Cluj-Napoca, Physics and Chemistry Department, 400114 Cluj-Napoca (Romania)] [Technical University of Cluj-Napoca, Physics and Chemistry Department, 400114 Cluj-Napoca (Romania)

    2013-11-13T23:59:59.000Z

    The residual monomer present in post-polymerized dental materials encourages premature degradation of the reconstructed tooth. That is why the residual monomer should be quantified in a simple, fast, accurate and reproducible manner. In our work we propose such an approach for accurate determination of the residual monomer in dental materials which is based on low-field nuclear magnetic resonance (NMR) relaxometry. The results of the NMR approach are compared with those of the high performance liquid chromatography (HPLC) technique. The samples under study contain the main monomers (2,2-bis[4-(2-hydroxy-3-methacryloyloxypropoxy)phenyl]propane and triethylene glycol dimethacrylate) constituting the liquid phase of most dental materials and an initiator. Two samples were analyzed with different ratios of chemical initiation systems: N,N-dimethyl-p-toluide: benzoyl peroxide (1:2 and 0.7:1.2). The results obtained by both techniques highlight that by reducing the initiator the polymerization process slows down and the amount of residual monomer reduces. This prevents the premature degradation of the dental fillings and consequently the reduction of the biomaterial resistance.

  15. Stereochemistry Determination by Powder X-ray Diffraction Analysis and NMR Spectroscopy Residual Dipolar Couplings

    SciTech Connect (OSTI)

    Garcia, M.; Pagola, S; Navarro-Vasquez, A; Phillips, D; Gayathri, C; Krakauer, H; Stephens, P; Nicotra, V; Gil, R

    2009-01-01T23:59:59.000Z

    A matter of technique: For a new steroidal lactol, jaborosalactol 24 (1), isolated from Jaborosa parviflora, NMR spectroscopy residual dipolar couplings and powder X-ray diffraction analysis independently gave the same stereochemistry at C23-C26. Conventional NMR spectroscopic techniques, such as NOE and {sup 3}J coupling-constant analysis failed to unambiguously determine this stereochemistry.

  16. End-of-life vehicle recycling : state of the art of resource recovery from shredder residue.

    SciTech Connect (OSTI)

    Jody, B. J.; Daniels, E. J.; Energy Systems

    2007-03-21T23:59:59.000Z

    Each year, more than 50 million vehicles reach the end of their service life throughout the world. More than 95% of these vehicles enter a comprehensive recycling infrastructure that includes auto parts recyclers/dismantlers, remanufacturers, and material recyclers (shredders). Today, about 75% of automotive materials are profitably recycled via (1) parts reuse and parts and components remanufacturing and (2) ultimately by the scrap processing (shredding) industry. The process by which the scrap processors recover metal scrap from automobiles involves shredding the obsolete automobiles, along with other obsolete metal-containing products (such as white goods, industrial scrap, and demolition debris), and recovering the metals from the shredded material. The single largest source of recycled ferrous scrap for the iron and steel industry is obsolete automobiles. The non-metallic fraction that remains after the metals are recovered from the shredded materials (about 25% of the weight of the vehicle)--commonly called shredder residue--is disposed of in landfills. Over the past 10 to 15 years, a significant amount of research and development has been undertaken to enhance the recycle rate of end-of-life vehicles (ELVs), including enhancing dismantling techniques and improving remanufacturing operations. However, most of the effort has focused on developing technology to recover materials, such as polymers, from shredder residue. To make future vehicles more energy efficient, more lighter-weight materials--primarily polymers and polymer composites--will be used in manufacturing these vehicles. These materials increase the percentage of shredder residue that must be disposed of, compared with the percentage of metals. Therefore, as the complexity of automotive materials and systems increases, new technologies will be required to sustain and maximize the ultimate recycling of these materials and systems at end-of-life. Argonne National Laboratory (Argonne), in cooperation with the Vehicle Recycling Partnership (VRP) and the American Plastics Council (APC), is working to develop technology for recycling materials from shredder residue. Several other organizations worldwide are also working on developing technology for recycling shredder residue. Without a commercially viable shredder industry, our nation may face greater environmental challenges and a decreased supply of quality scrap and be forced to turn to primary ores for the production of finished metals. This document presents a review of the state of the art in shredder residue recycling. Available technologies and emerging technologies for the recycling of materials from shredder residue are discussed.

  17. The Effect of Weld Residual Stress on Life of Used Nuclear Fuel Dry Storage Canisters

    SciTech Connect (OSTI)

    Ronald G. Ballinger; Sara E. Ferry; Bradley P. Black; Sebastien P. Teysseyre

    2013-08-01T23:59:59.000Z

    With the elimination of Yucca Mountain as the long-term storage facility for spent nuclear fuel in the United States, a number of other storage options are being explored. Currently, used fuel is stored in dry-storage cask systems constructed of steel and concrete. It is likely that used fuel will continue to be stored at existing open-air storage sites for up to 100 years. This raises the possibility that the storage casks will be exposed to a salt-containing environment for the duration of their time in interim storage. Austenitic stainless steels, which are used to construct the canisters, are susceptible to stress corrosion cracking (SCC) in chloride-containing environments if a continuous aqueous film can be maintained on the surface and the material is under stress. Because steel sensitization in the canister welds is typically avoided by avoiding post-weld heat treatments, high residual stresses are present in the welds. While the environment history will play a key role in establishing the chemical conditions for cracking, weld residual stresses will have a strong influence on both crack initiation and propagation. It is often assumed for modeling purposes that weld residual stresses are tensile, high and constant through the weld. However, due to the strong dependence of crack growth rate on stress, this assumption may be overly conservative. In particular, the residual stresses become negative (compressive) at certain points in the weld. The ultimate goal of this research project is to develop a probabilistic model with quantified uncertainties for SCC failure in the dry storage casks. In this paper, the results of a study of the residual stresses, and their postulated effects on SCC behavior, in actual canister welds are presented. Progress on the development of the model is reported.

  18. Plant foliar disease suppression mediated by composted forms of paper mill residuals exhibits molecular features of induced resistance

    E-Print Network [OSTI]

    Goodman, Robert M.

    Plant foliar disease suppression mediated by composted forms of paper mill residuals exhibits Arabidopsis thaliana grown in soil from field plots amended with composted forms of paper mill residuals (PMR with plants grown in soil from field plots amended with a non-composted PMR or non-amended soils. Similar

  19. Effects of residual stress on the thin-film elastic moduli calculated from surface acoustic wave spectroscopy experimentsB

    E-Print Network [OSTI]

    Effects of residual stress on the thin-film elastic moduli calculated from surface acoustic wave 23 February 2005 Available online 26 April 2005 Abstract We describe a method to examine how residual equibiaxial stress. The five test samples consisted of TiN films deposited on single-crystal Si substrate

  20. AN IMPROVED TREATMENT OF RESIDUAL STRESSES IN FLAW ASSESSMENT OF PIPES AND PRESSURE VESSELS FABRICATED FROM FERRITIC STEELS

    E-Print Network [OSTI]

    Michaleris, Panagiotis

    FABRICATED FROM FERRITIC STEELS William C. Mohr, Panagiotis Michaleris, and Mark T. Kirk Edison Welding ferritic steels. Information on these residual stresses are drawn from the literature; both measured treatment of residual stresses produced by welding in pipes and pressure vessels fabricated from ferritic

  1. Mobilisation of arsenic from bauxite residue (red mud) affected soils: Effect of pH and redox conditions

    E-Print Network [OSTI]

    Burke, Ian

    ). Typically, it comprises residual iron oxides, quartz, sodium aluminosilicates, titanium dioxide, calciumMobilisation of arsenic from bauxite residue (red mud) affected soils: Effect of pH and redox elements, including arsenic. Aerobic and anaer- obic batch experiments were prepared using soils from near

  2. Microbial community response to a release of neat ethanol onto residual hydrocarbons in a pilot-scale

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    Microbial community response to a release of neat ethanol onto residual hydrocarbons in a pilot ethanol release (E100, 76 l) onto residual hydrocarbons in sandy soil was evaluated in a continuous-flow 8 shifts were assessed using quantitative real-time PCR analysis. High ethanol concentrations

  3. Supply Assessment of Forest Logging Residues and Non-Sawlog Biomass in the Vicinity of Missoula, Montana, 2011-2013

    E-Print Network [OSTI]

    Vonessen, Nikolaus

    1 Supply Assessment of Forest Logging Residues and Non-Sawlog Biomass in the Vicinity of Missoula logging slash and non-sawlog biomass are commonly disposed of in the forest through piling and open biomass sources such as forest inventories, planned projects on other landownerships, and mill residues

  4. Assessment of the PCDD/F fate from MSWI residues used1 in road construction in France2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Assessment of the PCDD/F fate from MSWI residues used1 in road construction in France2 3 R of these alternative materials is that of the Municipal59 Solid Waste Incinerator (MSWI) residue which is produced from the household60 wastes combustion and used for road and car-park construction.61 In France, the use of MSWI

  5. WEEE and portable batteries in residual household waste: Quantification and characterisation of misplaced waste

    SciTech Connect (OSTI)

    Bigum, Marianne, E-mail: mkkb@env.dtu.dk [Technical University of Denmark, Department of Environmental Engineering, Miljøvej 113, 2500 Kgs. Lyngby (Denmark); Petersen, Claus, E-mail: claus_petersen@econet.dk [Econet A/S, Strandboulevarden 122, 5, 2100 København Ø (Denmark); Christensen, Thomas H., E-mail: thho@env.dtu.dk [Technical University of Denmark, Department of Environmental Engineering, Miljøvej 113, 2500 Kgs. Lyngby (Denmark); Scheutz, Charlotte, E-mail: chas@env.dtu.dk [Technical University of Denmark, Department of Environmental Engineering, Miljøvej 113, 2500 Kgs. Lyngby (Denmark)

    2013-11-15T23:59:59.000Z

    Highlights: • We analyse 26.1 Mg of residual waste from 3129 Danish households. • We quantify and characterise misplaced WEEE and portable batteries. • We compare misplaced WEEE and batteries to collection through dedicated schemes. • Characterisation showed that primarily small WEEE and light sources are misplaced. • Significant amounts of misplaced batteries were discarded as built-in WEEE. - Abstract: A total of 26.1 Mg of residual waste from 3129 households in 12 Danish municipalities was analysed and revealed that 89.6 kg of Waste Electrical and Electronic Equipment (WEEE), 11 kg of batteries, 2.2 kg of toners and 16 kg of cables had been wrongfully discarded. This corresponds to a Danish household discarding 29 g of WEEE (7 items per year), 4 g of batteries (9 batteries per year), 1 g of toners and 7 g of unidentifiable cables on average per week, constituting 0.34% (w/w), 0.04% (w/w), 0.01% (w/w) and 0.09% (w/w), respectively, of residual waste. The study also found that misplaced WEEE and batteries in the residual waste constituted 16% and 39%, respectively, of what is being collected properly through the dedicated special waste collection schemes. This shows that a large amount of batteries are being discarded with the residual waste, whereas WEEE seems to be collected relatively successfully through the dedicated special waste collection schemes. Characterisation of the misplaced batteries showed that 20% (w/w) of the discarded batteries were discarded as part of WEEE (built-in). Primarily alkaline batteries, carbon zinc batteries and alkaline button cell batteries were found to be discarded with the residual household waste. Characterisation of WEEE showed that primarily small WEEE (WEEE directive categories 2, 5a, 6, 7 and 9) and light sources (WEEE directive category 5b) were misplaced. Electric tooth brushes, watches, clocks, headphones, flashlights, bicycle lights, and cables were items most frequently found. It is recommended that these findings are taken into account when designing new or improving existing special waste collection schemes. Improving the collection of WEEE is also recommended as one way to also improve the collection of batteries due to the large fraction of batteries found as built-in. The findings in this study were comparable to other western European studies, suggesting that the recommendations made in this study could apply to other western European countries as well.

  6. untitled

    Gasoline and Diesel Fuel Update (EIA)

    Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate No. 2 Distillate a No. 4 Fuel b Residual Fuel Oil Sales to End Users Sales for Resale Sales to End Users Sales for...

  7. Energy Information Administration/Petroleum Marketing Annual

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    39 Table A3. RefinerReseller Prices of Distillate and Residual Fuel Oils, by PAD District, 1983-Present (Cents per Gallon Excluding Taxes) Geographic Area Year No. 1 Distillate...

  8. Energy Information Administration/Petroleum Marketing Annual

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    per Day Motor Gasoline No. 2 Distillate Residual Fuel Oil Figure 5. U.S. Refiner Wholesale Petroleum Product Volumes Motor Gasoline 62.0% No. 2 Distillate 24.6% Other 0.9%...

  9. Energy Information Administration/Petroleum Marketing Annual

    U.S. Energy Information Administration (EIA) Indexed Site

    per Day Motor Gasoline No. 2 Distillate Residual Fuel Oil Figure 5. U.S. Refiner Wholesale Petroleum Product Volumes Motor Gasoline 62.4% No. 2 Distillate 24.4% Other 1.0%...

  10. X:\\Data_Publication\\Pma\\current\\ventura\\pma00.vp

    U.S. Energy Information Administration (EIA) Indexed Site

    per Day Motor Gasoline No. 2 Distillate Residual Fuel Oil Figure 5. U.S. Refiner Wholesale Petroleum Product Volumes Motor Gasoline 61.9% No. 2 Distillate 24.8% Other 0.9%...

  11. untitled

    Gasoline and Diesel Fuel Update (EIA)

    per Day Motor Gasoline No. 2 Distillate Residual Fuel Oil Figure 5. U.S. Refiner Wholesale Petroleum Product Volumes Motor Gasoline 61.9% No. 2 Distillate 26.8% Other 0.8%...

  12. untitled

    U.S. Energy Information Administration (EIA) Indexed Site

    per Day Motor Gasoline No. 2 Distillate Residual Fuel Oil Figure 5. U.S. Refiner Wholesale Petroleum Product Volumes Motor Gasoline 60.7% No. 2 Distillate 26.9% Other 0.7%...

  13. X:\\L6046\\Data_Publication\\Pma\\current\\ventura\\pma.vp

    U.S. Energy Information Administration (EIA) Indexed Site

    per Day Motor Gasoline No. 2 Distillate Residual Fuel Oil Figure 5. U.S. Refiner Wholesale Petroleum Product Volumes Motor Gasoline 61.5% No. 2 Distillate 26.5% Other 0.5%...

  14. Organochlorine insecticide residues in soil and earthworms in the Delhi area, India, August-October 1974

    SciTech Connect (OSTI)

    Yadav, D.V.; Mittal, P.K.; Agarwal, H.C.; Pillai, M.K.

    1981-09-01T23:59:59.000Z

    DDT residues in soil and earthworms from 50 sites in Delhi were monitored. DDT was detected in all but two samples each of soil and earthworms. Among DDT residues, p,p'-DDE was most common and was found in 48 samples each of soil and earthworms; p,p'-DDT was detected in only 43 soil samples and 46 earthworm samples. p,p'-TDE and o,p'-DDT were also present in smaller concentrations in 29 and 15 soil samples and in 43 and 25 earthworm samples, respectively. Maximum total DDT concentration of 2.6 ppm was detected in the soil from Durga Nagar in the vicinity of a DDT factory. The highest concentration of 37.7 ppm total DDT in earthworms was also obtained from the same site. The maximum concentration factor found in the earthworms was 551. The total DDT concentration in the earthworms and soil showed significant correlation.

  15. End-of-life vehicle recycling : state of the art of resource recovery from shredder residue.

    SciTech Connect (OSTI)

    Jody, B. J.; Daniels, E. J.; Duranceau, C. M.; Pomykala, J. A.; Spangenberger, J. S. (Energy Systems)

    2011-02-22T23:59:59.000Z

    Each year, more than 25 million vehicles reach the end of their service life throughout the world, and this number is rising rapidly because the number of vehicles on the roads is rapidly increasing. In the United States, more than 95% of the 10-15 million scrapped vehicles annually enter a comprehensive recycling infrastructure that includes auto parts recyclers/dismantlers, remanufacturers, and material recyclers (shredders). Today, over 75% of automotive materials, primarily the metals, are profitably recycled via (1) parts reuse and parts and components remanufacturing and (2) ultimately by the scrap processing (shredding) industry. The process by which the scrap processors recover metal scrap from automobiles involves shredding the obsolete automobile hulks, along with other obsolete metal-containing products (such as white goods, industrial scrap, and demolition debris), and recovering the metals from the shredded material. The single largest source of recycled ferrous scrap for the iron and steel industry is obsolete automobiles. The non-metallic fraction that remains after the metals are recovered from the shredded materials - commonly called shredder residue - constitutes about 25% of the weight of the vehicle, and it is disposed of in landfills. This practice is not environmentally friendly, wastes valuable resources, and may become uneconomical. Therefore, it is not sustainable. Over the past 15-20 years, a significant amount of research and development has been undertaken to enhance the recycle rate of end-of-life vehicles, including enhancing dismantling techniques and improving remanufacturing operations. However, most of the effort has been focused on developing technology to separate and recover non-metallic materials, such as polymers, from shredder residue. To make future vehicles more energy efficient, more lightweighting materials - primarily polymers, polymer composites, high-strength steels, and aluminum - will be used in manufacturing these vehicles. Many of these materials increase the percentage of shredder residue that must be disposed of, compared with the percentage of metals that are recovered. In addition, the number of hybrid vehicles and electric vehicles on the road is rapidly increasing. This trend will also introduce new materials for disposal at the end of their useful lives, including batteries. Therefore, as the complexity of automotive materials and systems increases, new technologies will be required to sustain and maximize the ultimate recycling of these materials and systems. Argonne National Laboratory (Argonne), the Vehicle Recycling Partnership, LLC. (VRP) of the United States Council for Automotive Research, LLC. (USCAR), and the American Chemistry Council-Plastics Division (ACC-PD) are working to develop technology for recovering materials from end-of-life vehicles, including separating and recovering polymers and residual metals from shredder residue. Several other organizations worldwide are also working on developing technology for recycling materials from shredder residue. Without a commercially viable shredder industry, our nation and the world will most likely face greater environmental challenges and a decreased supply of quality scrap, and thereby be forced to turn to primary ores for the production of finished metals. This will result in increased energy consumption and increased damage to the environment, including increased greenhouse gas emissions. The recycling of polymers, other organics, and residual metals in shredder residue saves the equivalent of over 23 million barrels of oil annually. This results in a 12-million-ton reduction in greenhouse gas emissions. This document presents a review of the state-of-the-art in the recycling of automotive materials.

  16. Residual stress determination in an overlay dissimilar welded pipe by neutron diffraction

    SciTech Connect (OSTI)

    Woo, Wan Chuck [ORNL; Em, Vyacheslav [Korea Atomic Energy Research Institute; Hubbard, Camden R [ORNL; Lee, Ho-Jin [Korea Atomic Energy Research Institute; Park, Kwang Soo [Doosan Heavy Industries & Construction

    2011-01-01T23:59:59.000Z

    Residual stresses were determined through the thickness of a dissimilar weld overlay pipe using neutron diffraction. The specimen has a complex joining structure consisting of a ferritic steel (SA508), austenitic steel (F316L), Ni-based consumable (Alloy 182), and overlay of Ni-base superalloy (Alloy 52M). It simulates pressurized nozzle components, which have been a critical issue under the severe crack condition of nuclear power reactors. Two neutron diffractometers with different spatial resolutions have been utilized on the identical specimen for comparison. The macroscopic 'stress-free' lattice spacing (d{sub o}) was also obtained from both using a 2-mm width comb-like coupon. The results show significant changes in residual stresses from tension (300-400 MPa) to compression (-600 MPa) through the thickness of the dissimilar weld overlay pipe specimen.

  17. Fault detection in an air-handling unit using residual and recursive parameter identification methods

    SciTech Connect (OSTI)

    Lee, W.Y. [Korea Inst. of Energy Research, Taejon (Korea, Republic of); Park, C.; Kelly, G.E. [National Inst. of Standards and Technology, Gaithersburg, MD (United States)

    1996-11-01T23:59:59.000Z

    A scheme for detecting faults in an air-handling unit using residual and parameter identification methods is presented. Faults can be detected by comparing the normal or expected operating condition data with the abnormal, measured data using residuals. Faults can also be detected by examining unmeasurable parameter changes in a model of a controlled system using a system parameter identification technique. In this study, autoregressive moving average with exogenous input (ARMAX) and autoregressive with exogenous input (ARX) models with both single-input/single-output (SISO) and multi-input/single-output (MISO) structures are examined. Model parameters are determined using the Kalman filter recursive identification method. This approach is tested using experimental data from a laboratory`s variable-air-volume (VAV) air-handling unit operated with and without faults.

  18. Residual stress measurement on ductile cast iron using critically refracted longitudinal (Lcr) wave technique

    E-Print Network [OSTI]

    Chundu, Srinivasulu Naidu

    1991-01-01T23:59:59.000Z

    of requirements for the degree of MASTER OF SCIENCE December 1991 Major Subject: Mechanical Engineering RESIDUAL STRESS MEASUREMENT IN DUCTILE CAST IRON USING CRITICALLY REFRACTED LONGITUDINAL (Lcm) WAVE TECHNIQUE A Thesis by SRINIVASULU NAIDU CHUNDU.... In an attempt to study the effect of heat-treatment on the acoustoelastic behavior of ductile cast iron, four continuously cast ductile iron bars were investigated. While one bar was retained as-cast, the other three bars were subjected to heat...

  19. Recovery of fissile materials from plutonium residues, miscellaneous spent nuclear fuel, and uranium fissile wastes

    SciTech Connect (OSTI)

    Forsberg, C.W.

    1997-03-01T23:59:59.000Z

    A new process is proposed that converts complex feeds containing fissile materials into a chemical form that allows the use of existing technologies (such as PUREX and ion exchange) to recover the fissile materials and convert the resultant wastes to glass. Potential feed materials include (1) plutonium scrap and residue, (2) miscellaneous spent nuclear fuel, and (3) uranium fissile wastes. The initial feed materials may contain mixtures of metals, ceramics, amorphous solids, halides, and organics. 14 refs., 4 figs.

  20. Residual New Physics Effects in the Heavy Quark Sector, Tests at LEP2 and Higher Energies

    E-Print Network [OSTI]

    F. M. Renard

    1997-07-07T23:59:59.000Z

    We discuss the sensitivity of the processes $e^+e^-\\to t\\bar t$ and $e^+e^-\\to b\\bar b$ to special sets of operators describing residual New Physics effects. Experimental data in this sector together with those expected in the bosonic sector should allow to constrain possible New Physics schemes with effective scales in the 10 TeV range.

  1. Hanford Tank 241-C-106: Residual Waste Contaminant Release Model and Supporting Data

    SciTech Connect (OSTI)

    Deutsch, William J.; Krupka, Kenneth M.; Lindberg, Michael J.; Cantrell, Kirk J.; Brown, Christopher F.; Schaef, Herbert T.

    2005-06-03T23:59:59.000Z

    CH2M HILL is producing risk/performance assessments to support the closure of single-shell tanks at the DOE's Hanford Site. As part of this effort, staff at PNNL were asked to develop release models for contaminants of concern that are present in residual sludge remaining in tank 241-C-106 (C-106) after final retrieval of waste from the tank. This report provides the information developed by PNNL.

  2. An insoluble residue study of the Comanche Peak and Edwards limestones of Kimble County, Texas

    E-Print Network [OSTI]

    Jurik, Paul Peter

    1961-01-01T23:59:59.000Z

    . . . . . . . . . . . . . . . . . . . . . . . Previous investigations Comanche Peak and Edwards limestones. . Insoluble res idues 1 1 3 5 6 S tratigraphy Wa)nut clay. Conanche Peak limestone Edwards limestone. Georgetown limestone. 8 9 9 12 Paleontology Macropaleontology... on the basis of tha silt?clay insoluble residua y. Tectonic map of Early Cretaceous. Plate I. Vertical variation in insoluble residua content. . . . pocket vertical variation in sand-siss insoluble residue content Vertical vari. stion in sand...

  3. Engineering evaluation of alternatives for the disposition of Niagara Falls Storage Site, its residues and wastes

    SciTech Connect (OSTI)

    Not Available

    1984-01-01T23:59:59.000Z

    The final disposition scenarios selected by DOE for assessment in this document are consistent with those stated in the Notice of Intent to prepare an Environmental Impact Statement (EIS) for the Niagara Falls Storage Site (NFSS) (DOE, 1983d) and the modifications to the alternatives resulting from the public scoping process. The scenarios are: take no action beyond interim remedial measures other than maintenance and surveillance of the NFSS; retain and manage the NFSS as a long-term waste management facility for the wastes and residues on the site; decontaminate, certify, and release the NFSS for other use, with long-term management of the wastes and residues at other DOE sites; and partially decontaminate the NFSS by removal and transport off site of only the more radioactive residues, and upgrade containment of the remaining wastes and residues on site. The objective of this document is to present to DOE the conceptual engineering, occupational radiation exposure, construction schedule, maintenance and surveillance requirements, and cost information relevant to design and implementation of each of the four scenarios. The specific alternatives within each scenario used as the basis for discussion in this document were evaluated on the bases of engineering considerations, technical feasibility, and regulatory requirements. Selected alternatives determined to be acceptable for each of the four final disposition scenarios for the NFSS were approved by DOE to be assessed and costed in this document. These alternatives are also the subject of the EIS for the NFSS currently being prepared by Argonne National Laboratory (ANL). 40 figures, 38 tables.

  4. Technoeconomic Comparison of Biofuels: Ethanol, Methanol, and Gasoline from Gasification of Woody Residues (Presentation)

    SciTech Connect (OSTI)

    Tarud, J.; Phillips, S.

    2011-08-01T23:59:59.000Z

    This presentation provides a technoeconomic comparison of three biofuels - ethanol, methanol, and gasoline - produced by gasification of woody biomass residues. The presentation includes a brief discussion of the three fuels evaluated; discussion of equivalent feedstock and front end processes; discussion of back end processes for each fuel; process comparisons of efficiencies, yields, and water usage; and economic assumptions and results, including a plant gate price (PGP) for each fuel.

  5. THE IMPACT OF POINT-SOURCE SUBTRACTION RESIDUALS ON 21 cm EPOCH OF REIONIZATION ESTIMATION

    SciTech Connect (OSTI)

    Trott, Cathryn M.; Wayth, Randall B.; Tingay, Steven J., E-mail: cathryn.trott@curtin.edu.au [International Centre for Radio Astronomy Research, Curtin University, Bentley, WA (Australia) and ARC Centre of Excellence for All-Sky Astrophysics (CAASTRO) (Australia)

    2012-09-20T23:59:59.000Z

    Precise subtraction of foreground sources is crucial for detecting and estimating 21 cm H I signals from the Epoch of Reionization (EoR). We quantify how imperfect point-source subtraction due to limitations of the measurement data set yields structured residual signal in the data set. We use the Cramer-Rao lower bound, as a metric for quantifying the precision with which a parameter may be measured, to estimate the residual signal in a visibility data set due to imperfect point-source subtraction. We then propagate these residuals into two metrics of interest for 21 cm EoR experiments-the angular power spectrum and two-dimensional power spectrum-using a combination of full analytic covariant derivation, analytic variant derivation, and covariant Monte Carlo simulations. This methodology differs from previous work in two ways: (1) it uses information theory to set the point-source position error, rather than assuming a global rms error, and (2) it describes a method for propagating the errors analytically, thereby obtaining the full correlation structure of the power spectra. The methods are applied to two upcoming low-frequency instruments that are proposing to perform statistical EoR experiments: the Murchison Widefield Array and the Precision Array for Probing the Epoch of Reionization. In addition to the actual antenna configurations, we apply the methods to minimally redundant and maximally redundant configurations. We find that for peeling sources above 1 Jy, the amplitude of the residual signal, and its variance, will be smaller than the contribution from thermal noise for the observing parameters proposed for upcoming EoR experiments, and that optimal subtraction of bright point sources will not be a limiting factor for EoR parameter estimation. We then use the formalism to provide an ab initio analytic derivation motivating the 'wedge' feature in the two-dimensional power spectrum, complementing previous discussion in the literature.

  6. Radionuclide Leaching from Residual Solids Remaining after Acid Dissolution of Composite K East Canister Sludge

    SciTech Connect (OSTI)

    Delegard, C.H.; Rinehart, D.E.; Soderquist, C.Z.; Fadeff, S.K.

    1999-04-02T23:59:59.000Z

    Laboratory tests were performed to examine mixed nitric/hydrofluoric acid leach treatments for decontaminating dissolver residual solids (KECDVSR24H-2) produced during a 20- to 24-hr dissolution of a composite K East (KE) Basin canister sludge in 95 C 6 M nitric acid (HNO{sub 3}). The scope of this testing has been described in Section 4.5 of ''Testing Strategy to Support the Development of K Basin Sludge Treatment Process'' (Flament 1998). Radionuclides sorbed or associated with the residual solids generated in the K Basin sludge treatment process can restrict disposal of this solid to the Environmental Restoration Disposal Facility (ERDF). The starting dissolver residual solid for this testing, KECDVSR24H-2, contains radionuclides at concentrations which exceed the ERDF Waste Acceptance Criteria for TRU by about a factor of 70, for {sup 239}Pu by a factor of 200, and for {sup 241}Am by a factor of 50. The solids also exceed the ERDF criterion for {sup 137}Cs by a factor of 2 and uranium by a factor of 5. Therefore, the radionuclides of greatest interest in this leaching study are first {sup 239}Pu and {sup 241}Am (both components of TRU) and then uranium and {sup 137}Cs.

  7. Separation of thorium (IV) from lanthanide concentrate (LC) and water leach purification (WLP) residue

    SciTech Connect (OSTI)

    AL-Areqi, Wadeeah M.; Majid, Amran Ab.; Sarmani, Sukiman [Nuclear Science Programme, School of Applied Physics, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

    2014-09-03T23:59:59.000Z

    Thorium (IV) content in industrial residue produced from rare earth elements production industry is one of the challenges to Malaysian environment. Separation of thorium from the lanthanide concentrate (LC) and Water Leach Purification (WLP) residue from rare earth elements production plant is described. Both materials have been tested by sulphuric acid and alkaline digestions. Th concentrations in LC and WLP were determined to be 1289.7 ± 129 and 1952.9±17.6 ppm respectively. The results of separation show that the recovery of Th separation from rare earth in LC after concentrated sulphuric acid dissolution and reduction of acidity to precipitate Th was found 1.76-1.20% whereas Th recovery from WLP was less than 4% after concentrated acids and alkali digestion processes. Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS) was used to determine Th concentrations in aqueous phase during separation stages. This study indicated that thorium maybe exists in refractory and insoluble form which is difficult to separate by these processes and stays in WLP residue as naturally occurring radioactive material (NORM)

  8. Residue-free fabrication of high-performance graphene devices by patterned PMMA stencil mask

    SciTech Connect (OSTI)

    Shih, Fu-Yu [Department of Physics, National Taiwan University, Taipei 10617, Taiwan (China); Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan (China); Chen, Shao-Yu; Wu, Tsuei-Shin; Wang, Wei-Hua, E-mail: wwang@sinica.edu.tw [Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei 10617, Taiwan (China); Liu, Cheng-Hua; Chen, Yang-Fang [Department of Physics, National Taiwan University, Taipei 10617, Taiwan (China); Ho, Po-Hsun; Chen, Chun-Wei [Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan (China)

    2014-06-15T23:59:59.000Z

    Two-dimensional (2D) atomic crystals and their hybrid structures have recently attracted much attention due to their potential applications. The fabrication of metallic contacts or nanostructures on 2D materials is very common and generally achieved by performing electron-beam (e-beam) lithography. However, e-beam lithography is not applicable in certain situations, e.g., cases in which the e-beam resist does not adhere to the substrates or the intrinsic properties of the 2D materials are greatly altered and degraded. Here, we present a residue-free approach for fabricating high-performance graphene devices by patterning a thin film of e-beam resist as a stencil mask. This technique can be generally applied to substrates with varying surface conditions, while causing negligible residues on graphene. The technique also preserves the design flexibility offered by e-beam lithography and therefore allows us to fabricate multi-probe metallic contacts. The graphene field-effect transistors fabricated by this method exhibit smooth surfaces, high mobility, and distinct magnetotransport properties, confirming the advantages and versatility of the presented residue-free technique for the fabrication of devices composed of 2D materials.

  9. The effects of machine parameters on residual stress determined using micro-Raman spectroscopy

    SciTech Connect (OSTI)

    Sparks, R.G.; Enloe, W.S.; Paesler, M.A.

    1988-12-01T23:59:59.000Z

    The effects of machine parameters on residual stresses in single point diamond turned silicon and germanium have been investigated using micro-Raman spectroscopy. Residual stresses were sampled across ductile feed cuts in < 100 > silicon and germanium which were single point diamond turned using a variety of feed rates, rake angles and clearance angles. High spatial resolution micro-Raman spectra (1{mu}m spot) were obtained in regions of ductile cutting where no visible surface damage was present. The use of both 514-5nm and 488.0nm excitation wavelengths, by virtue of their differing characteristic penetration depths in the materials, allowed determinations of stress profiles as a function of depth into the sample. Previous discussions have demonstrated that such Raman spectra will exhibit asymmetrically broadened peaks which are characteristic of the superposition of a continuum of Raman scatterers from the various depths probed. Depth profiles of residual stress were obtained using computer deconvolution of the resulting asymmetrically broadened raman spectra.

  10. Manual for implementing residual radioactive material guidelines using RESRAD, Version 5.0

    SciTech Connect (OSTI)

    Yu, C.; Zielen, A.J.; Cheng, J.J. [and others

    1993-09-01T23:59:59.000Z

    This manual presents information for implementing US Department of Energy (DOE) guidelines for residual radioactive material. It describes the analysis and models used to derive site-specific guidelines for allowable residual concentrations of radionuclides in soil and the design and use of the RESRAD computer code for calculating doses, risks, and guideline values. It also describes procedures for implementing DOE policy for reducing residual radioactivity to levels that are as low as reasonably achievable. Two new pathways, radon inhalation and soil ingestion, have been added to RESRAD. Twenty-seven new radionuclides have also been added, and the cutoff half-life for associated radionuclides has been reduced to six months. Other major improvements to the RESRAD code include the ability to run sensitivity analyses, the addition of graphical output, user-specified dose factors, updated databases, an improved groundwater transport model, optional input of a groundwater concentration and a solubility constant, special models for tritium and carbon-14, calculation of cancer incidence risk, and the use of a mouse with menus.

  11. Isomer residual ratio of odd-odd isotope {sup 180}Ta in supernova nucleosynthsis

    SciTech Connect (OSTI)

    Hayakawa, Takehito [Japan Atomic Energy Agency, Kizugawa, Kyoto 619-0215 (Japan); Kajino, Toshitaka [National Astronomical Observatory, Osawa, Mitaka, Tokyo 181-8588 (Japan); Chiba, Satoshi [Japan Atomic Energy Agency, Tokai, Naka, Ibaraki 319-11 (Japan); Mathews, Grant [Enter for Astrophysics, Department of Physics, University of Notre Dame, Notre Dame, IN 46556 (United States)

    2010-06-01T23:59:59.000Z

    The nucleosynthesis of {sup 180}Ta has remained an unsolved problem and as its origin many nucleosynthesis mechanisms have been proposed. This isotope has the unique feature that the naturally occurring abundance of {sup 180}Ta is actually a meta-stable isomer (half-life of >=10{sup 15} yr), while the ground state is a 1{sup +} unstable state which beta-decays with a half-life of only 8.15 hr. We have made a new time-dependent calculation of {sup 180}Ta meta-stable isomer residual ratio after supernova neutrino-induced reactions. This residual isomer ratio is crucial for understanding the production and survival of this naturally occurring rare isotope. We have constructed a new model under temperature evolution after type II supernova explosion. We include the explicit linking between the isomer and all known excited states and found that the residual ratio is insensitive to astrophysical parameters such as neutrino energy spectrum, explosion energy, decay time constant. We find that the explicit time evolution of the synthesis of {sup 180}Ta avoids the overproduction relative to {sup 138}La for a neutrino process neutrino temperature of 4 MeV.

  12. On-matrix Derivatization for Dynamic Headspace Sampling of Nonvolatile Surface Residues

    SciTech Connect (OSTI)

    Harvey, Scott D.; Wahl, Jon H.

    2012-09-01T23:59:59.000Z

    The goal of this study is to extend sampling by the field and laboratory emission cell (FLEC) purge-and-trap technique to applications that target nonvolatile residues. On-matrix derivatization of residues to render analytes stable and more volatile is explored to achieve this goal. Results show that on-matrix derivatizations of nerve agent hydrolysis products (monoalkyl methylphosphonic acids and methylphosphonic acid [MPA]) with diazomethane were successful on glass and painted wallboard (at the 10-µg level). It also was successful on the more difficult concrete (at the 500-µg level) and carpet (at the 20-µg level) substrates that cannot be successfully sampled using swipe techniques. Analysis of additional chemical warfare (CW)-associated residues can be approached by on-matrix derivatization with trifluoroacetic anhydride (TFAA). For example, amines (used as stabilizers or present as decomposition products of the nerve agent VX) or thiodiglycol (hydrolysis product of sulfur mustard) could be sampled as their TFAA derivatives from glass, painted wallboard, and concrete (at the 40-µg level), as well as carpet (at the 80-µg level) surfaces. Although the amine and thiodiglycol are semi-volatile and could be sampled directly, derivatization improves the recovery and chromatographic behavior of these analytes.

  13. A C. elegans-based foam for rapid on-site detection of residual live virus.

    SciTech Connect (OSTI)

    Negrete, Oscar A.; Branda, Catherine; Hardesty, Jasper O. E. (Sandia National Laboratories, Albuquerque, NM); Tucker, Mark David (Sandia National Laboratories, Albuquerque, NM); Kaiser, Julia N. (Global Product Management, Hilden, Germany); Kozina, Carol L.; Chirica, Gabriela S.

    2012-02-01T23:59:59.000Z

    In the response to and recovery from a critical homeland security event involving deliberate or accidental release of biological agents, initial decontamination efforts are necessarily followed by tests for the presence of residual live virus or bacteria. Such 'clearance sampling' should be rapid and accurate, to inform decision makers as they take appropriate action to ensure the safety of the public and of operational personnel. However, the current protocol for clearance sampling is extremely time-intensive and costly, and requires significant amounts of laboratory space and capacity. Detection of residual live virus is particularly problematic and time-consuming, as it requires evaluation of replication potential within a eukaryotic host such as chicken embryos. The intention of this project was to develop a new method for clearance sampling, by leveraging Sandia's expertise in the biological and material sciences in order to create a C. elegans-based foam that could be applied directly to the entire contaminated area for quick and accurate detection of any and all residual live virus by means of a fluorescent signal. Such a novel technology for rapid, on-site detection of live virus would greatly interest the DHS, DoD, and EPA, and hold broad commercial potential, especially with regard to the transportation industry.

  14. An evaluation on the environmental consequences of residual CFCs from obsolete household refrigerators in China

    SciTech Connect (OSTI)

    Zhao Xiangyang; Duan Huabo [Department of Environmental Science and Engineering, Tsinghua University, Beijing (China); Li Jinhui, E-mail: jinhui@tsinghua.edu.cn [Department of Environmental Science and Engineering, Tsinghua University, Beijing (China)

    2011-03-15T23:59:59.000Z

    Chlorofluorocarbons (CFCs) contained in household refrigerators consist mainly of CFC-11 and CFC-12, which will be eventually released into the environment. Consequentially, environmental releases of these refrigerants will lead to ozone depletion and contribute significantly to the greenhouse effect, if waste refrigerators are not disposed of properly. In the present paper, the potential release of residual CFCs and their substitutes from obsolete household refrigerators in China is examined, and their contributions to ozone depletion and greenhouse effect are compared with those of other recognized ozone-depleting substances (ODS) and greenhouse gases (GHGs). The results imply that annual potential amounts of released residual CFC-11 and CFC-12 will reach their maximums at 4600 and 2300 tons, respectively in 2011, and then decrease gradually to zero until 2020. Meanwhile, the amounts of their most widely used substitutes HCFC-141b and HFC-134a will keep increasing. Subsequently, the contribution ratio of these CFCs and their substitutes to ozone depletion will remain at 25% through 2011, and reach its peak value of 34% by 2018. The contribution to greenhouse effect will reach its peak value of 0.57% by 2010. Moreover, the contribution ratio of these CFCs to the total global release of CFCs will steadily increase, reaching its peak of 15% by 2018. Thus, this period from 2010 to 2018 is a crucial time during which residual CFCs and their substitutes from obsolete household refrigerators in China will contribute significantly to ozone depletion.

  15. Mixed-waste treatment -- What about the residuals? A comparative analysis of MSO and incineration

    SciTech Connect (OSTI)

    NONE

    1993-06-01T23:59:59.000Z

    This report examines the issues concerning final waste forms, or residuals, that result from the treatment of mixed waste in molten salt oxidation (MSO) and incinerator systems. MSO is a technology with the potential to treat a certain segment of the waste streams at US Department of Energy (DOE) sites. MSO was compared with incineration because incineration is the best demonstrated available technology (BDAT) for the same waste streams. The Grand Junction Projects Office (GJPO) and Oak Ridge National Laboratory (ORNL) prepared this report for the DOE Office of Environmental Restoration (OER). The goals of this study are to objectively evaluate the anticipated residuals from MSO and incineration, examine regulatory issues for these final waste forms, and determine secondary treatment options. This report, developed to address concerns that MSO residuals present unique disposal difficulties, is part of a larger effort to successfully implement MSO as a treatment technology for mixed and hazardous waste. A Peer Review Panel reviewed the MSO technology in November 1991, and the implementation effort is ongoing under the guidance of the MSO Task Force.

  16. Developing an Integrated Model Framework for the Assessment of Sustainable Agricultural Residue Removal Limits for Bioenergy Systems

    SciTech Connect (OSTI)

    David Muth, Jr.; Jared Abodeely; Richard Nelson; Douglas McCorkle; Joshua Koch; Kenneth Bryden

    2011-08-01T23:59:59.000Z

    Agricultural residues have significant potential as a feedstock for bioenergy production, but removing these residues can have negative impacts on soil health. Models and datasets that can support decisions about sustainable agricultural residue removal are available; however, no tools currently exist capable of simultaneously addressing all environmental factors that can limit availability of residue. The VE-Suite model integration framework has been used to couple a set of environmental process models to support agricultural residue removal decisions. The RUSLE2, WEPS, and Soil Conditioning Index models have been integrated. A disparate set of databases providing the soils, climate, and management practice data required to run these models have also been integrated. The integrated system has been demonstrated for two example cases. First, an assessment using high spatial fidelity crop yield data has been run for a single farm. This analysis shows the significant variance in sustainably accessible residue across a single farm and crop year. A second example is an aggregate assessment of agricultural residues available in the state of Iowa. This implementation of the integrated systems model demonstrates the capability to run a vast range of scenarios required to represent a large geographic region.

  17. The effect of inter-pass temperature on residual stresses in multi-pass welds produced using a low transformation temperature filler alloy

    E-Print Network [OSTI]

    Cambridge, University of

    , the deposition of new metal with a relatively low inter-pass temperature leads to increased residual stressesThe effect of inter-pass temperature on residual stresses in multi-pass welds produced using a low-to-martensite transformation temperatures offer an effective method of reducing residual stresses in strong, steel welds

  18. Page 1 of 1 This policy establishes an institutional procedure for residual revenue earned on restricted fixed-price or fee-for-

    E-Print Network [OSTI]

    Hutcheon, James M.

    be deposited in this account. Georgia Southern University invoices the Research Foundation monthly for residualPage 1 of 1 I. Purpose This policy establishes an institutional procedure for residual revenue completion, deficit or surplus (residual) balances must be transferred to a non-sponsored account. Because

  19. Journal of Pressure Vessel Technology, Vol. 131, 2009, 041401 The Effects of Filler Metal Transformation Temperature on Residual Stresses in a

    E-Print Network [OSTI]

    Cambridge, University of

    . Residual stresses arise as a result of welding operations because they involve the deposition of molten Transformation Temperature on Residual Stresses in a High Strength Steel Weld J. A. Francis School of Materials Gothenburg, Sweden ABSTRACT Residual stress in the vicinity of a weld can have a large influence

  20. Pulp and paper mill fibrous residuals in excavatable flowable fill Y.-m. Chun, T.R. Naik, & R.N. Kraus

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    biological treatment of wastewater. Fiber reclaim is composed of wood cellulose fibers and moisture mills Fibrous residuals from pulp and paper mills include wastewater-treatment residuals (also called sludge), fiber reclaim, and screening rejects. The basic components of the wastewater-treatment residuals