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Sample records for low-pressure sodium daylighting

  1. Daylighting Basics

    Broader source: Energy.gov [DOE]

    Daylighting is the use of windows and skylights to bring sunlight into buildings. Daylighting in businesses and commercial buildings can result in substantial savings on electric bills, and not only provides a higher quality of light but also improves productivity and health.

  2. Low pressure carbonylation of heterocycles

    DOE Patents [OSTI]

    Coates, Geoffrey W. (Lansing, NY); Kramer, John W. (Mt. Pleasant, MI); Schmidt, Joseph A. R. (Sylvania, OH)

    2011-01-25

    Heterocycles, e.g., epoxides, are carbonylated at low pressure with high percentage conversion to cyclic, ring expanded products using the catalyst ##STR00001## where L is tetrahydrofuran (THF).

  3. MANDATORY MEASURES DAYLIGHTING

    E-Print Network [OSTI]

    California at Davis, University of

    a general lighting system with a power density greater than 0.5 watts per square foot 10/31/2014 DAYLIGHTING, the automatic daylighting controls requirements for primary sidelit zones also apply to general lighting

  4. Daylighting | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electricity & Fuel Lighting Daylighting Daylighting An error occurred. Try watching this video on www.youtube.com, or enable JavaScript if it is disabled in your browser....

  5. Energy 101: Daylighting

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    Daylighting—the use of windows or skylights for natural lighting and temperature regulation—is one building strategy that can save money for homeowners and businesses.

  6. Energy 101: Daylighting

    ScienceCinema (OSTI)

    None

    2013-05-29

    Daylighting?the use of windows or skylights for natural lighting and temperature regulation?is one building strategy that can save money for homeowners and businesses. Highly efficient, strategically placed windows maximize the use of natural daylight in a building, lowering the need for artificial lighting without causing heating or cooling problems.

  7. Energy 101: Daylighting

    Broader source: Energy.gov [DOE]

    Daylighting—the use of windows or skylights for natural lighting and temperature regulation—is one building strategy that can save money for homeowners and businesses. Highly efficient,...

  8. Daylighting Calculation in DOE-2

    E-Print Network [OSTI]

    Winkelmann, F.C

    2013-01-01

    2.9) DAYLIGHTING CALCULATION IN DOE-2 Table of Contents 1.55 —-17:-.. LBL-11353 (III.2.9 only) EEB-DOE-2 83—3DAYLIGHTING CALCULATION IN DOE-2 Frederick C. Winkelmann

  9. DAYLIGHTING DIRECTORY 1/1980

    E-Print Network [OSTI]

    ,

    2012-01-01

    Daylighting and Passive Solar Buildings", Proceedings of theOptimize the building shell for passive heating or cooling

  10. Daylight metrics and energy savings

    E-Print Network [OSTI]

    Mardaljevic, John

    2011-01-01

    Daylighting and energy saving Electric lighting energy usefor predicting energy savings from photo-electric control ofelectric lighting displacement, rather than predicting ?nal energy savings.

  11. Daylighting Calculation in DOE-2

    E-Print Network [OSTI]

    Winkelmann, F.C

    2013-01-01

    46 3.2.2 Luminous Efficacy of Solar Radiation . . . . . . .The Availability of Solar Radiation. and Daylight",clear sky diffuse solar radiation, and overcast sky diffuse

  12. Daylighting | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, Alabama (UtilityInstruments Inc JumpIowa:Minnesota:Daylighting Jump to: navigation,

  13. Propagation of light in low pressure gas

    E-Print Network [OSTI]

    Jacques Moret-Bailly

    2012-04-13

    The criticism by W. E. Lamb, W. Schleich, M. Scully, C. Townes of a simplified quantum electrodynamics which represents the photon as a true particle is illustrated. Collisions being absent in low-pressure gas, exchanges of energy are radiative and coherent. Thin shells of plasma containing atoms in a model introduced by Str\\"omgren are superradiant, seen as circles possibly dotted. Spectral radiance of novae has magnitude of laser radiance, and column densities are large in nebulae: Superradiance, multiphoton effects, etc., work in astrophysics. The superradiant beams induce multiphotonic scatterings of light emitted by the stars, brightening the limbs of plasma bubbles and darkening the stars. In excited atomic hydrogen, impulsive Raman scatterings shift frequencies of light. Microwaves exchanged with the Pioneer probes are blueshifted, simulating anomalous accelerations. Substituting coherence for wrong calculations in astrophysical papers, improves results, avoids "new physics".

  14. Lighting and Daylighting Products and Services | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lighting and Daylighting Products and Services Lighting and Daylighting Products and Services Lighting and Daylighting Products and Services Use the following links to get product...

  15. Do Daylight-Saving Time Adjustments Really Impact Stock Returns?

    E-Print Network [OSTI]

    Steigerwald, Douglas G; Conte, Marc

    2007-01-01

    Taylor, 1935, World Daylight Saving Time, Chicago: Cur- ranthe Market: The Daylight Saving Anomaly”, American Economicat the Market: The Daylight Saving Anomaly: Reply”, American

  16. Lighting and Daylighting Products and Services | Department of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Daylighting Products and Services Lighting and Daylighting Products and Services July 1, 2015 - 5:06pm Addthis Lighting and Daylighting Products and Services Use the following...

  17. 4.430 Daylighting, Fall 2006

    E-Print Network [OSTI]

    Andersen, Marilyne

    This class provides the tools necessary for an efficient integration of daylighting issues in the overall design of a building. The fundamentals of daylighting and electric lighting are introduced and their relevance to ...

  18. Alternative Strategies for Low-Pressure End Uses; Industrial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    lower pressures. The ones that can operate at low pressure could be supported with alternative methods. * Consider a professional compressed air system evaluation. Such an exam...

  19. Low pressure cooling seal system for a gas turbine engine

    DOE Patents [OSTI]

    Marra, John J

    2014-04-01

    A low pressure cooling system for a turbine engine for directing cooling fluids at low pressure, such as at ambient pressure, through at least one cooling fluid supply channel and into a cooling fluid mixing chamber positioned immediately downstream from a row of turbine blades extending radially outward from a rotor assembly to prevent ingestion of hot gases into internal aspects of the rotor assembly. The low pressure cooling system may also include at least one bleed channel that may extend through the rotor assembly and exhaust cooling fluids into the cooling fluid mixing chamber to seal a gap between rotational turbine blades and a downstream, stationary turbine component. Use of ambient pressure cooling fluids by the low pressure cooling system results in tremendous efficiencies by eliminating the need for pressurized cooling fluids for sealing this gap.

  20. A Multiscale Simulator for Low Pressure Chemical Vapor Deposition

    E-Print Network [OSTI]

    A Multiscale Simulator for Low Pressure Chemical Vapor Deposition Matthias K. Gobbert Institute-6206 ABSTRACT An integrated simulator for chemical vapor deposition is introduced. In addition to a reactor

  1. Daylight metrics and energy savings

    SciTech Connect (OSTI)

    Mardaljevic, John; Heschong, Lisa; Lee, Eleanor

    2009-12-31

    The drive towards sustainable, low-energy buildings has increased the need for simple, yet accurate methods to evaluate whether a daylit building meets minimum standards for energy and human comfort performance. Current metrics do not account for the temporal and spatial aspects of daylight, nor of occupants comfort or interventions. This paper reviews the historical basis of current compliance methods for achieving daylit buildings, proposes a technical basis for development of better metrics, and provides two case study examples to stimulate dialogue on how metrics can be applied in a practical, real-world context.

  2. International Symposium on Daylighting Buildings (IEA SHC TASK 31) Integrating Automated Shading and Smart Glazings with Daylight

    E-Print Network [OSTI]

    and Smart Glazings with Daylight Controls Stephen Selkowitz Eleanor Lee Lawrence Berkeley National Laboratory Keywords: daylighting, controls, smart glazing, shading, field testing, IEA31 1. INTRODUCTION Most

  3. The Summer Plateau Low Pressure System of Mexico

    E-Print Network [OSTI]

    Tucker, Donna F.

    1999-04-01

    Average July heights and winds over a 10-yr period are computed at 850 mb over Mexico using both surface and radiosonde data. During the day central Mexico at this level is dominated by low pressure, with some smaller areas of high pressure...

  4. Daylighting Application and Effectiveness in Industrial Facilities 

    E-Print Network [OSTI]

    McCowan, B.; Birleanu, D.

    2005-01-01

    during the industrial revolution, architects utilized various daylighting strategies such as window walls, skylighting, monitors, etc. However, glazing technologies were primitive compared with our modern choices, When more efficient and effective...

  5. Energy 101: Daylighting | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    but save you money as well. For more information on daylighting and other home energy-saving tips that can benefit the environment and save you money, visit the Office of...

  6. Experimental Evaluation of Innovative Wall Daylighting Systems 

    E-Print Network [OSTI]

    Place, J. W.; Howard, T. C.; Paulos, S.; Chung, K.

    1988-01-01

    resource information and simple, reliable methods of testing daylighting designs. To surmount these obstacles, facilities for collecting illuminance data and for testing small-scale and full-size models have been established. These are (1) an extensively...

  7. 4.492 Daylighting, Fall 2004

    E-Print Network [OSTI]

    Andersen, Marilyne

    The course focuses on the use and optimization of daylight in buildings and on its complementarity to artificial (electric) lighting, to aim at reducing the building's environmental impact while improving the visual comfort ...

  8. Ion optical effects in a low pressure rf plasma

    SciTech Connect (OSTI)

    Oechsner, Hans; Paulus, Hubert [Institute for Surface and Thin Film Analysis IFOS and Department of Physics, Technical University of Kaiserslautern, D-67663 Kaiserslautern (Germany)] [Institute for Surface and Thin Film Analysis IFOS and Department of Physics, Technical University of Kaiserslautern, D-67663 Kaiserslautern (Germany)

    2013-11-15

    Ion optical effects in low pressure gas discharges are introduced as a novel input into low pressure plasma technology. They are based on appropriate geometrical plasma confinements which enable a control of the shape of internal density and potential distributions and, hence, the ion motion in the plasma bulk. Such effects are exemplified for an electron cyclotron wave resonance plasma in Ar at 1–5 × 10{sup ?3} millibars. The geometry of the plasma chamber is modified by a conical and a cylindrical insert. Computer simulations display spherical plasma density contours to be formed around the conical confinement. This effects an increase of the ratio of the ion currents into the conical and the cylindrical inserts which depends on the fourth power of the plasma electron temperature. A quantitative understanding of this behavior is presented. As another essential result, the shape of the internal plasma contours is found to be independent of the pressure controlled plasma parameters.

  9. Microlaminate composite structures by low pressure plasma spray deposition

    SciTech Connect (OSTI)

    Castro, R.G.; Stanek, P.W.

    1988-01-01

    The low pressure plasma spray (LPPS) process has been utilized in the development and fabrication of metal/metal, metal/carbide, and metal/oxide composite structures; including particulate dispersion and both continuous and discontinuous laminates. This report describes the LPPS process and the development of copper/tungsten microlaminate structures utilizing this processing method. Microstructures and mechanical properties of the Cu/W composites are compared to conventionally produced constituent material properties. 4 refs., 6 figs., 2 tabs.

  10. Method of gettering hydrogen under conditions of low pressure

    DOE Patents [OSTI]

    Mendelsohn, M.H.; Gruen, D.M.

    1983-08-09

    A ternary intermetallic compound having the formula Zr(V[sub 1[minus]x]Cr[sub x])[sub 2] where x is in the range of 0.01 to 0.90 is capable of reversibly sorbing hydrogen at temperatures ranging from room temperature to 200 C, at pressures down to 10[sup [minus]6] Torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices. 3 figs.

  11. Method of gettering hydrogen under conditions of low pressure

    DOE Patents [OSTI]

    Mendelsohn, Marshall H. (Woodridge, IL); Gruen, Dieter M. (Downers Grove, IL)

    1983-01-01

    A ternary intermetallic compound having the formula Zr(V.sub.1-x Cr.sub.x).sub.2 where x is in the range of 0.01 to 0.90 is capable of reversibly sorbing hydrogen at temperatures ranging from room temperature to 200.degree. C., at pressures down to 10.sup.-6 Torr. The compound is suitable for use as a hydrogen getter in low pressure, high temperature applications such as magnetic confinement fusion devices.

  12. LOW-PRESSURE MEMBRANE CONTACTORS FOR CARBON DIOXIDE CAPTURE

    SciTech Connect (OSTI)

    Baker, Richard; Kniep, Jay; Hao, Pingjiao; Chan, Chi Cheng; Nguyen, Vincent; Huang, Ivy; Amo, Karl; Freeman, Brice; Fulton, Don; Ly, Jennifer; Lipscomb, Glenn; Lou, Yuecun; Gogar, Ravikumar

    2014-09-30

    This final technical progress report describes work conducted by Membrane Technology and Research, Inc. (MTR) for the Department of Energy (DOE NETL) on development of low-pressure membrane contactors for carbon dioxide (CO2) capture from power plant flue gas (award number DE-FE0007553). The work was conducted from October 1, 2011 through September 30, 2014. The overall goal of this three-year project was to build and operate a prototype 500 m2 low-pressure sweep membrane module specifically designed to separate CO2 from coal-fired power plant flue gas. MTR was assisted in this project by a research group at the University of Toledo, which contributed to the computational fluid dynamics (CFD) analysis of module design and process simulation. This report details the work conducted to develop a new type of membrane contactor specifically designed for the high-gas-flow, low-pressure, countercurrent sweep operation required for affordable membrane-based CO2 capture at coal power plants. Work for this project included module development and testing, design and assembly of a large membrane module test unit at MTR, CFD comparative analysis of cross-flow, countercurrent, and novel partial-countercurrent sweep membrane module designs, CFD analysis of membrane spacers, design and fabrication of a 500 m2 membrane module skid for field tests, a detailed performance and cost analysis of the MTR CO2 capture process with low-pressure sweep modules, and a process design analysis of a membrane-hybrid separation process for CO2 removal from coal-fired flue gas. Key results for each major task are discussed in the report.

  13. Low pressure storage of natural gas on activated carbon

    SciTech Connect (OSTI)

    Wegrzyn, J.; Wiesmann, H.; Lee, T.

    1992-12-31

    The introduction of natural gas to the transportation energy sector offers the possibility of displacing imported oil with an indigenous fuel. The barrier to the acceptance of natural gas vehicles (NGV) is the limited driving range due to the technical difficulties of on-board storage of a gaseous fuel. In spite of this barrier, compressed natural gas (CNG) vehicles are today being successfully introduced into the market place. The purpose of this work is to demonstrate an adsorbent natural gas (ANG) storage system as a viable alternative to CNG storage. It can be argued that low pressure ANG has reached near parity with CNG, since the storage capacity of CNG (2400 psi) is rated at 190 V/V, while low pressure ANG (500 psi) has reached storage capacities of 180 V/V in the laboratory. A program, which extends laboratory results to a full-scale vehicle test, is necessary before ANG technology will receive widespread acceptance. The objective of this program is to field test a 150 V/V ANG vehicle in FY 1994. As a start towards this goal, carbon adsorbents have been screened by Brookhaven for their potential use in a natural gas storage system. This paper reports on one such carbon, trade name Maxsorb, manufactured by Kansai Coke under an Amoco license.

  14. Low pressure storage of natural gas on activated carbon

    SciTech Connect (OSTI)

    Wegrzyn, J.; Wiesmann, H.; Lee, T.

    1992-01-01

    The introduction of natural gas to the transportation energy sector offers the possibility of displacing imported oil with an indigenous fuel. The barrier to the acceptance of natural gas vehicles (NGV) is the limited driving range due to the technical difficulties of on-board storage of a gaseous fuel. In spite of this barrier, compressed natural gas (CNG) vehicles are today being successfully introduced into the market place. The purpose of this work is to demonstrate an adsorbent natural gas (ANG) storage system as a viable alternative to CNG storage. It can be argued that low pressure ANG has reached near parity with CNG, since the storage capacity of CNG (2400 psi) is rated at 190 V/V, while low pressure ANG (500 psi) has reached storage capacities of 180 V/V in the laboratory. A program, which extends laboratory results to a full-scale vehicle test, is necessary before ANG technology will receive widespread acceptance. The objective of this program is to field test a 150 V/V ANG vehicle in FY 1994. As a start towards this goal, carbon adsorbents have been screened by Brookhaven for their potential use in a natural gas storage system. This paper reports on one such carbon, trade name Maxsorb, manufactured by Kansai Coke under an Amoco license.

  15. Flash High-Pressure Condensate to Regenerate Low-Pressure Steam...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Flash High-Pressure Condensate to Regenerate Low-Pressure Steam Low-pressure process steam requirements are usually met by throttling high- pressure steam, but a portion of the...

  16. On-Site Wastewater Treatment Systems: Low-Pressure Dosing System (Spanish) 

    E-Print Network [OSTI]

    Lesikar, Bruce J.

    1999-08-12

    A low-pressure dosing system treats wastewater and then pumps it into the soil several times daily. This publication explains the advantages, disadvantages, maintenance steps and estimated costs of low-pressure dosing systems.

  17. On-Site Wastewater Treatment Systems: Low-Pressure Dosing System 

    E-Print Network [OSTI]

    Lesikar, Bruce J.

    1999-09-06

    A low-pressure dosing system treats wastewater and then pumps it into the soil several times daily. This publication explains the advantages and disadvantages of low-pressure dosing systems as well as estimated costs and ...

  18. Daylighting, dimming, and the electricity crisis in California

    E-Print Network [OSTI]

    Rubinstein, Francis; Neils, Danielle; Colak, Nesrin

    2001-01-01

    and California Electricity Crisis Rubinstein, Neils & Colak daylighting system is saving energy when it is most critical, because electricity costsCalifornia’s energy crisis and the consequent increases in electricity rates, is daylighting now a cost-California and then investigate the potential of daylight-linked controls to reduce peak demand and lower energy costs

  19. A HOMOGENIZATION TECHNIQUE FOR THE BOLTZMANN EQUATION FOR LOW PRESSURE CHEMICAL VAPOR DEPOSITION 1

    E-Print Network [OSTI]

    Markowich, Peter A.

    A HOMOGENIZATION TECHNIQUE FOR THE BOLTZMANN EQUATION FOR LOW PRESSURE CHEMICAL VAPOR DEPOSITION 1 the approach. The setup models low pressure chemical vapor deposition processes in the manufacturing. Low pressure chemical vapor deposition is used in the manufactur- ing of integrated circuits

  20. Selective Growth of Straight Carbon Nanotubes by Low-Pressure Thermal Chemical Vapor Deposition

    E-Print Network [OSTI]

    Hasegawa, Shuji

    Selective Growth of Straight Carbon Nanotubes by Low-Pressure Thermal Chemical Vapor Deposition) were grown by low-pressure thermal chemical vapor deposition using pure ethylene. It was found preferentially bridged between Fe nanoparticles under a low pressure of 100 Pa. Moreover, utilizing this method

  1. Effective Daylighting: Evaluating Daylighting Performance in the San Francisco Federal Building from the Perspective of Building Occupants

    E-Print Network [OSTI]

    Konis, Kyle Stas

    2012-01-01

    of Understanding between BREEAM, LEED, the UK Green Building300 lux (HMG, 2010; LEED/BREEAM Daylighting credit, 2012),

  2. Effective Daylighting: Evaluating Daylighting Performance in the San Francisco Federal Building from the Perspective of Building Occupants

    E-Print Network [OSTI]

    Konis, Kyle Stas

    2011-01-01

    of Understanding between BREEAM, LEED, the UK Green Building300 lux (HMG, 2010; LEED/BREEAM Daylighting credit, 2012),

  3. Does Daylight Savings Time Affect Traffic Accidents? 

    E-Print Network [OSTI]

    Deen, Sophia 1988-

    2012-04-20

    This paper studies the effect of changes in accident pattern due to Daylight Savings Time (DST). The extension of the DST in 2007 provides a natural experiment to determine whether the number of traffic accidents is affected by shifts in hours...

  4. Daylighting systems for the Kuwait National Museum 

    E-Print Network [OSTI]

    Ahn, Byoungsoo

    2005-08-29

    May 2005 Major Subject: Architecture ii DAYLIGHTING SYSTEMS FOR THE KUWAIT NATIONAL MUSEUM A Thesis by BYOUNGSOO AHN Submitted to Texas A&M University in partial fulfillment of the requirements for the degree... Phillip J. Tabb (Member) (Head of Department) May 2005 Major Subject: Architecture iii ABSTRACT...

  5. daylight 12/17/2007 1 Tracking the change in the amount of daylight

    E-Print Network [OSTI]

    Taylor, Peter

    daylight 12/17/2007 1 Tracking the change in the amount of daylight Ever notice that at some times the sun is up for exactly half the time. For (a) and (b) you are to use old-fashioned technology (pencil the sun rise on day x=61 then it did on day x=60? (b) At what point is the loss of sunlight hours from one

  6. Spatio-temporal characteristics of Trichel pulse at low pressure

    SciTech Connect (OSTI)

    He, Shoujie, E-mail: hedajingdian@126.com [College of Physics Science and Technology, Hebei University, Baoding (China)] [College of Physics Science and Technology, Hebei University, Baoding (China); Jing, Ha [Institute of Science, Hebei Agriculture University, Baoding (China)] [Institute of Science, Hebei Agriculture University, Baoding (China)

    2014-01-15

    Trichel pulses are investigated using a needle-to-plane electrode geometry at low pressure. The evolution of current and voltage, the spatio-temporal discharge images of Trichel pulse are measured. The rising time and duration time in a pulse are about 10??s and several tens of microseconds, respectively. One period of pulse can be divided into three stages: the stage preceding cathode breakdown, cathode glow formation, and discharge decaying process. Besides a cathode glow and a dark space, an anode glow is also observed. The emission spectra mainly originate from the C{sup 3}?{sub u} ? B{sup 3}?{sub g} transition for nitrogen. In addition, the capacitances in parallel connected with the discharge cell have important influence on the pulsing frequency.

  7. Very low pressure high power impulse triggered magnetron sputtering

    DOE Patents [OSTI]

    Anders, Andre; Andersson, Joakim

    2013-10-29

    A method and apparatus are described for very low pressure high powered magnetron sputtering of a coating onto a substrate. By the method of this invention, both substrate and coating target material are placed into an evacuable chamber, and the chamber pumped to vacuum. Thereafter a series of high impulse voltage pulses are applied to the target. Nearly simultaneously with each pulse, in one embodiment, a small cathodic arc source of the same material as the target is pulsed, triggering a plasma plume proximate to the surface of the target to thereby initiate the magnetron sputtering process. In another embodiment the plasma plume is generated using a pulsed laser aimed to strike an ablation target material positioned near the magnetron target surface.

  8. Low pressure high speed Stirling air engine. Final technical report

    SciTech Connect (OSTI)

    Ross, M.A.

    1980-06-16

    The purpose of this project was to design, construct and test a simple, appropriate technology low pressure, high speed, wood-fired Stirling air engine of 100 W output. The final design was a concentric piston/displacer engine of 454 in. bore and 1 in. stroke with a rhombic drive mechanism. The project engine was ultimately completed and tested, using a propane burner for all tests as a matter of convenience. The 100 W aim was exceeded, at atmospheric pressure, over a wide range of engine speed with the maximum power being 112 W at 1150 rpm. A pressure can was constructed to permit pressurization; however the grant funds were running out, and the only pressurized power test attempted was unsuccessful due to seal difficulties. This was a disappointment because numerous tests on the 4 cubic inch engine suggested power would be more than doubled with pressurization at 25 psig. A manifold was designed and constructed to permit operation of the engine over a standard No. 40 pot bellied stove. The engine was run successfully, but at reduced speed and power, over this stove. The project engine started out being rather noisy in operation, but modifications ultimately resulted in a very quiet engine. Various other difficulties and their solutions also are discussed. (LCL)

  9. Downhole steam generator using low pressure fuel and air supply

    DOE Patents [OSTI]

    Fox, Ronald L. (Albuquerque, NM)

    1983-01-01

    An apparatus for generation of steam in a borehole for penetration into an earth formation wherein a spiral, tubular heat exchanger is used in the combustion chamber to isolate the combustion process from the water being superheated for conversion into steam. The isolation allows combustion of a relatively low pressure oxidant and fuel mixture for generating high enthalpy steam. The fuel is preheated by feedback of combustion gases from the top of the combustion chamber through a fuel preheater chamber. The hot exhaust gases of combustion at the bottom of the combustion chamber, after flowing over the heat exchanger enter an exhaust passage and pipe. The exhaust pipe is mounted inside the water supply line heating the water flowing into the heat exchanger. After being superheated in the heat exchanger, the water is ejected through an expansion nozzle and converts into steam prior to penetration into the earth formation. Pressure responsive doors are provided at a steam outlet downstream of the nozzle and close when the steam pressure is lost due to flameout.

  10. Daylighting simulation: methods, algorithms, and resources

    SciTech Connect (OSTI)

    Carroll, William L.

    1999-12-01

    This document presents work conducted as part of Subtask C, ''Daylighting Design Tools'', Subgroup C2, ''New Daylight Algorithms'', of the IEA SHC Task 21 and the ECBCS Program Annex 29 ''Daylight in Buildings''. The search for and collection of daylighting analysis methods and algorithms led to two important observations. First, there is a wide range of needs for different types of methods to produce a complete analysis tool. These include: Geometry; Light modeling; Characterization of the natural illumination resource; Materials and components properties, representations; and Usability issues (interfaces, interoperability, representation of analysis results, etc). Second, very advantageously, there have been rapid advances in many basic methods in these areas, due to other forces. They are in part driven by: The commercial computer graphics community (commerce, entertainment); The lighting industry; Architectural rendering and visualization for projects; and Academia: Course materials, research. This has led to a very rich set of information resources that have direct applicability to the small daylighting analysis community. Furthermore, much of this information is in fact available online. Because much of the information about methods and algorithms is now online, an innovative reporting strategy was used: the core formats are electronic, and used to produce a printed form only secondarily. The electronic forms include both online WWW pages and a downloadable .PDF file with the same appearance and content. Both electronic forms include live primary and indirect links to actual information sources on the WWW. In most cases, little additional commentary is provided regarding the information links or citations that are provided. This in turn allows the report to be very concise. The links are expected speak for themselves. The report consists of only about 10+ pages, with about 100+ primary links, but with potentially thousands of indirect links. For purposes of the printed version, a list of the links is explicitly provided. This document exists in HTML form at the URL address: http://eande.lbl.gov/Task21/dlalgorithms.html. An equivalent downloadable PDF version, also with live links, at the URL address: http://eande.lbl.gov/Task21/dlalgorithms.pdf. A printed report can be derived directly from either of the electronic versions by simply printing either of them. In addition to the live links in the electronic forms, all report forms, electronic and paper, also have explicitly listed link addresses so that they can be followed up or referenced manually.

  11. Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam

    SciTech Connect (OSTI)

    Not Available

    2005-09-01

    Industrial Technologies Program's BestPractices tip sheet on improving efficiency of industrial steam systems by recovery latent heat from low-pressure steam.

  12. Stratigraphy-related, low-pressure metamorphism in the Hardey Syncline, Hamersley Province, Western Australia

    E-Print Network [OSTI]

    Ikegami, Takashi

    Stratigraphy-related, low-pressure metamorphism in the Hardey Syncline, Hamersley Province, Western. Furthermore, the change of metamorphic grade strongly correlates with stratigraphy, and the metamorphic

  13. CBEI - Enhancing OpenStudio for Airflow and Daylight Modeling

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    information science and technology. The team also works closely with building design professions in industry. 6 Our Approach ENHANCE Daylighting Airflow Modeling Energy Model...

  14. Integrating automated shading and smart glazings with daylight controls

    E-Print Network [OSTI]

    Selkowitz, Stephen; Lee, Eleanor

    2004-01-01

    Automated Shading and Smart Glazings with Daylight Controlsdaylighting, controls, smart glazing, shading, fielddeveloping switchable “smart glazings” for over a decade and

  15. OpenStudio Enhancements for Whole-Building Daylighting, Airflow...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Whole-Building Daylighting, Airflow, and Energy Modeling Leveraging Interoperable Building Information Modeling Data - 2014 BTO Peer Review OpenStudio Enhancements for...

  16. CBEI: Enhancing OpenStudio for Airflow and Daylight Modeling...

    Broader source: Energy.gov (indexed) [DOE]

    for Whole-Building Daylighting, Airflow, and Energy Modeling Leveraging Interoperable Building Information Modeling Data - 2014 BTO Peer Review Building Energy Modeling...

  17. Impact of Extended Daylight Saving Time on National Energy Consumption...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Report to Congress Impact of Extended Daylight Saving Time on National Energy Consumption, Report to Congress This report presents the detailed results, data, and analytical...

  18. Impact of Extended Daylight Saving Time on National Energy Consumption...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technical Documentation Impact of Extended Daylight Saving Time on National Energy Consumption, Technical Documentation This report presents the detailed results, data, and...

  19. The New York Times headquarters daylighting mockup: Monitoredperformance of the daylighting control system

    SciTech Connect (OSTI)

    Lee, Eleanor S.; Selkowitz, Stephen E.

    2006-02-24

    A nine-month monitored field study of the performance of automated roller shades and daylighting controls was conducted in a 401 m{sup 2} unoccupied, furnished daylighting mockup. The mockup mimicked the southwest corner of a new 110 km{sub 2} commercial building in New York, New York, where The New York Times will be the major tenant. This paper focuses on evaluating the performance of two daylighting control systems installed in separate areas of an open plan office with 1.2-m high workstation partitions: (1) Area A had 0-10 V dimmable ballasts with an open-loop proportional control system and an automated shade controlled to reduce window glare and increase daylight, and (2) Area B had digital addressable lighting interface (DALI) ballasts with a closed-loop integral reset control system and an automated shade controlled to block direct sun. Daylighting control system performance and lighting energy use were monitored. The daylighting control systems demonstrated very reliable performance after they were commissioned properly. Work plane illuminance levels were maintained above 90% of the maximum fluorescent illuminance level for 99.9{+-}0.5% and 97.9{+-}6.1% of the day on average over the monitored period, respectively, in Areas A and B. Daily lighting energy use savings were significant in both Areas over the equinox-to-equinox period compared to a non-daylit reference case. At 3.35 m from the window, 30% average savings were achieved with a sidelit west-facing condition in Area A while 50-60% were achieved with a bilateral daylit south-facing condition in Area B. At 4.57-9.14 m from the window, 5-10% and 25-40% savings were achieved in Areas A and B, respectively. Average savings for the 7-m deep dimming zone were 20-23% and 52-59% for Areas A and B, respectively, depending on the lighting schedule. The large savings and good reliability can be attributed to the automatic management of the interior shades. The DALI-based system exhibited faulty behavior that remains unexplained, but operational errors are expected to be resolved as DALI products reach full maturity. The building owner received very competitive bids ($30-75 US/DALI ballast) and was able to justify use of the daylighting control system based on operational cost savings and increased amenity. Additional energy savings due to reduced solar and lighting heat gains were not quantified but will add to the total operational cost savings.

  20. Lighting system combining daylight concentrators and an artificial source

    DOE Patents [OSTI]

    Bornstein, Jonathan G. (Miami, FL); Friedman, Peter S. (Toledo, OH)

    1985-01-01

    A combined lighting system for a building interior includes a stack of luminescent solar concentrators (LSC), an optical conduit made of preferably optical fibers for transmitting daylight from the LSC stack, a collimating lens set at an angle, a fixture for receiving the daylight at one end and for distributing the daylight as illumination inside the building, an artificial light source at the other end of the fixture for directing artifical light into the fixture for distribution as illumination inside the building, an automatic dimmer/brightener for the artificial light source, and a daylight sensor positioned near to the LSC stack for controlling the automatic dimmer/brightener in response to the daylight sensed. The system also has a reflector positioned behind the artificial light source and a fan for exhausting heated air out of the fixture during summer and for forcing heated air into the fixture for passage into the building interior during winter.

  1. Daylighting, dimming, and the electricity crisis in California

    SciTech Connect (OSTI)

    Rubinstein, Francis; Neils, Danielle; Colak, Nesrin

    2001-09-17

    Dimming controls for electric lighting have been one of the mainstays of the effort to use daylighting to reduce annual lighting energy consumption. The coincidence of daylighting with electric utility peak demand makes daylighting controls an effective strategy for reducing commercial building peak electric loads. During times of energy shortage, there is a greatly increased need to reduce electricity use during peak periods, both to ease the burden on electricity providers and to control the operating costs of buildings. The paper presents a typical commercial building electric demand profile during summer, and shows how daylighting-linked lighting controls and load shedding techniques can reduce lighting at precisely those times when electricity is most expensive. We look at the importance of dimming for increasing the reliability of the electricity grid in California and other states, as well as examine the potential cost-effectiveness of widespread use of daylighting to save energy and reduce monthly electricity bills.

  2. Effect of daylighting on energy consumption and daylight quality in an existing elementary school 

    E-Print Network [OSTI]

    Atre, Umesh Vinayak

    2005-08-29

    .36 Comparison between outdoor daily dry bulb temperatures from the actual school building and the Houston TMY2 weather file..............................96 Fig 4.1 Hourly whole building electricity use comparison for the first six weeks between the actual... and the proposed clerestory cases................................................................................132 Fig 4.32 Hourly lighting electricity use comparison between the base case model with daylighting and the proposed skylight cases on March 21...

  3. Simulation of subcooled boiling at low pressure conditions with RELAP5-3D computer program 

    E-Print Network [OSTI]

    Reza, S.M. Mohsin

    2002-01-01

    at low-pressure conditions were underestimated. The same model was used to simulate high pressure subcooled boiling data. High pressure subcooled boiling experiments of Bartolomey and Sabotinov were simulated. The axial void fraction distribution results...

  4. Bilayer graphene growth by low pressure chemical vapor deposition on copper foil

    E-Print Network [OSTI]

    Fang, Wenjing, S.M. Massachusetts Institute of Technology

    2012-01-01

    Successfully integrating graphene in standard processes for applications in electronics relies on the synthesis of high-quality films. In this work we study Low Pressure Chemical Vapor Deposition (LPCVD) growth of bilayer ...

  5. Use Vapor Recompression to Recover Low-Pressure Waste - Steam Tip Sheet #11

    SciTech Connect (OSTI)

    None

    2012-01-31

    This revised AMO tip sheet on recovering low-pressure waste steam provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  6. Building Information Modeling (BIM)-Based Daylighting Simulation and Analysis 

    E-Print Network [OSTI]

    Kota, S.; Haberl, J.S.; Clayton, M.; Yan, W.

    2014-01-01

    ESL-PA-14-07-03 Building Information Modeling (BIM)-Based Daylighting Simulation and Analysis Authors: Sandeep Kota; Jeff S. Haberl, Ph.D.; Mark J. Clayton, Ph.D.; Wei Yan, Ph.D. Corresponding Author: Wei Yan, Ph.D. Telephone: 1 979 8450584.... Email: wyan@tamu.edu Department of Architecture, Texas A&M University, College Station, Texas. ESL-PA-14-07-03 Building Information Modeling (BIM)-Based Daylighting Simulation and Analysis Abstract: Daylighting is an important aspect...

  7. Characterization of Drip Emitters and Computing Distribution Uniformity in a Drip Irrigation System at Low Pressure Under Uniform Land Slopes 

    E-Print Network [OSTI]

    Dutta, Deba P.

    2010-01-15

    Characteristics of emitters under low pressure are essential for designing drip irrigation systems. Low pressure data for drip emitters are not available from manufacturers. A laboratory test was conducted to evaluate the ...

  8. 2110 IEEE TRANSACTIONS ON PLASMA SCIENCE, VOL. 37, NO. 11, NOVEMBER 2009 Low-Pressure Helicon-Plasma Discharge Initiation

    E-Print Network [OSTI]

    Scharer, John E.

    -temperature plasma research. Low- pressure (as low as 1 millitorr) inductively coupled plasmas are used for plasma

  9. CALCULATING INTERIOR DAYLIGHT ILLUMINATION WITH A PROGRAMMABLE HAND CALCULATOR

    E-Print Network [OSTI]

    Bryan, Harvey J.

    2013-01-01

    reflection Component or IRC). The total the daylight factor,components as: SC + ERC + IRC THE SKY COMPONENT The skyformula for the average IRC is as: X where T ~ Transmittance

  10. CALCULATING INTERIOR DAYLIGHT ILLUMINATION WITH A PROGRAMMABLE HAND CALCULATOR

    E-Print Network [OSTI]

    Bryan, Harvey J.

    2013-01-01

    Reflected Component or IRC). The total for these threeDaylight Factor m SC + ERC + IRC THE SKY COMPONENT The skyThe formula for the average IRC is given as: IRC "" T X W A(

  11. Automated support for experimental approaches in daylighting performances assessment

    E-Print Network [OSTI]

    Ljubicic, Dean M

    2006-01-01

    The study of daylight and solar reflection has been a topic of increasing interest over the past two decades. A novel mechanical support has been constructed to help better understand this topic that consists of a five ...

  12. Daylight variability and contrast-driven architectural effect

    E-Print Network [OSTI]

    Rockcastle, Siobhan Francois

    2011-01-01

    Natural light is a dynamic and ephemeral tool for expressing the quality of architectural space. As a compliment to more traditional avenues of daylighting research that assess performance in terms of quantitative illuminance ...

  13. An intuitive daylighting performance analysis and optimization approach

    E-Print Network [OSTI]

    Andersen, Marilyne

    The effective integration of daylighting considerations into the design process requires many issues to be considered simultaneously, such as daily and seasonal variations, illumination, and thermal comfort. To address the ...

  14. Improving the daylighting conditions of existing buildings : the benefits and limitations of integrating anidolic daylighting systems using the American classroom as a model

    E-Print Network [OSTI]

    Kleindienst, Siân A. (Siân Alexandra)

    2006-01-01

    Awareness of the benefits of good daylighting has risen in recent years, and the designs of many new buildings take daylighting into consideration. However, the majority of our built environment is older than this recent ...

  15. Effective Daylighting: Evaluating Daylighting Performance in the San Francisco Federal Building from the Perspective of Building Occupants

    E-Print Network [OSTI]

    Konis, Kyle Stas

    2012-01-01

    Annex 29, Daylight in Buildings. October, 1997. Atif. M.R.case studies. Energy and Buildings 35 441-461. Attmann,George. 2010. Sustainable Buildings in Practice: What the

  16. DGA proves out as a low pressure gas sweetener in Saudi Arabia

    SciTech Connect (OSTI)

    Huval, M.; van de Venne, H.

    1981-08-17

    Aramco is successfully using diglycolamine (DGA) to treat low-pressure associated sour gases to 1/4 gr H/sub 2/S/100 SCF specifications. The DGA process meets the design criteria of (1) handling high acid-gas-content (up to 15%) feed gases, (2) sweetening at high temperatures (120/sup 0/-140/sup 0/F) and low pressures (120-180 psig), (3) removing both H/sub 2/S and CO/sub 2/ in a single step and (4) providing a Claus-plant feed suitable for the production of bright-yellow (rather than black) sulfur.

  17. Nanoparticles designed from low pressure plasmas as identification tool for astrophysical observations

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    interstellar media. The particles were polymerised in a low pressure capacitively coupled radio-frequency molecule production and reprocesses UV and optical radiation. The C-H stretch vibration of aliphatic coupled the radiofrequency discharge in argon/acetylene mixtures [Kovacevic submitted]. The particles

  18. Engine having a high pressure hydraulic system and low pressure lubricating system

    DOE Patents [OSTI]

    Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

    2000-01-01

    An engine includes a high pressure hydraulic system having a high pressure pump and at least one hydraulically-actuated device attached to an engine housing. A low pressure engine lubricating system is attached to the engine housing and includes a circulation conduit fluidly connected to an outlet from the high pressure pump.

  19. Alternated high-and low-pressure nitriding of austenitic stainless steel: Mechanisms and results

    E-Print Network [OSTI]

    Alternated high- and low-pressure nitriding of austenitic stainless steel: Mechanisms and results G a gas mixture of (N2 /H2):(50/50) in pressure, was applied to stainless-steel AISI 304. In the first penetrate far beyond the compound layer. These nitrogen atoms, uptaken into the austenitic stainless-steel

  20. The Soralux Daylighting System : passive solar illumination for deep-plan building spaces

    E-Print Network [OSTI]

    Thuot, Kevin W. (Kevin William)

    2011-01-01

    Daylight is a valuable resource for both energy and human health. However, this resource is often underutilized in buildings due to the difficulty of controlling the changing qualities of daylight. Deep-plan building spaces ...

  1. DOES DAYLIGHT SAVING TIME SAVE ENERGY? EVIDENCE FROM A NATURAL EXPERIMENT IN INDIANA

    E-Print Network [OSTI]

    Kotchen, Matthew J.

    DOES DAYLIGHT SAVING TIME SAVE ENERGY? EVIDENCE FROM A NATURAL EXPERIMENT IN INDIANA Matthew J to estimate the effect of daylight saving time (DST) on residential electricity consumption. Our main finding prompted temporary changes, when the Emergency Daylight Saving Time Energy Conservation Act of 1973 imposed

  2. Analysis of Daylighting Requirements within ASHRAE Standard 90.1

    SciTech Connect (OSTI)

    Athalye, Rahul A.; Xie, YuLong; Liu, Bing; Rosenberg, Michael I.

    2013-08-01

    Pacific Northwest National Laboratory (PNNL), under the Building Energy Codes Program (BECP) funded by U.S. Department of Energy (DOE), provides support to the ASHRAE/IES/IESNA Standard 90.1(Standard 90.1) Standing Standards Project Committee (SSPC 90.1) and its subcommittees. In an effort to provide the ASHRAE SSPC 90.1 with data that will improve the daylighting and fenestration requirements in the Standard, PNNL collaborated with Heschong Mahone Group (HMG), now part of TRC Solutions. Combining EnergyPlus, a whole-building energy simulation software developed by DOE, with Radiance, a highly accurate illumination modeling software (Ward 1994), the daylighting requirements within Standard 90.1 were analyzed in greater detail. The initial scope of the study was to evaluate the impact of the fraction of window area compared to exterior wall area (window-to-wall ratio (WWR)) on energy consumption when daylighting controls are implemented. This scope was expanded to study the impact of fenestration visible transmittance (VT), electric lighting controls and daylighted area on building energy consumption.

  3. Energy and daylight performance of angular selective glazings

    SciTech Connect (OSTI)

    Sullivan, R.; Beltran,; Lee, E.S.; Rubin, M.; Selkowitz, S.E.

    1998-11-01

    This paper presents the results of a study investigating the energy and daylight performance of anisotropic angular selective glazings. The DOE-2.1E energy simulation program was used to determine the annual cooling, lighting and total electricity use, and peak electric demand. RADIANCE, a lighting simulation program, was used to determine daylight illuminance levels and distribution. We simulated a prototypical commercial office building module located in Blythe, California. We chose three hypothetical conventional windows for comparison: a single-pane tinted window, a double-pane low-E window, and a double-pane spectrally selective window. Daylighting controls were used. No interior shades were modeled in order to isolate the energy effects of the angular selective glazing. Our results show that the energy performance of the prototype angular selective windows is about the same as conventional windows for a 9.14 m (30 ft) deep south-facing perimeter zone with a large-area window in the hot, sunny climate of Blythe. It is theoretically possible to tune the angular selectivity of the glazing to achieve annual cooling energy reductions of 18%, total electricity use reductions of 15%, and peak electric demand reductions of 11% when compared to a conventional glazing with the same solar-optical properties at normal incidence. Angular selective glazings can provide more uniformly distributed daylight, particularly in the area next to the window, which will result in a more visually comfortable work environment.

  4. Instantaneous and efficient surface wave excitation of a low pressure gas or gases

    DOE Patents [OSTI]

    Levy, Donald J. (Berkeley, CA); Berman, Samuel M. (San Francisco, CA)

    1988-01-01

    A system for instantaneously ionizing and continuously delivering energy in the form of surface waves to a low pressure gas or mixture of low pressure gases, comprising a source of rf energy, a discharge container, (such as a fluorescent lamp discharge tube), an rf shield, and a coupling device responsive to rf energy from the source to couple rf energy directly and efficiently to the gas or mixture of gases to ionize at least a portion of the gas or gases and to provide energy to the gas or gases in the form of surface waves. The majority of the rf power is transferred to the gas or gases near the inner surface of the discharge container to efficiently transfer rf energy as excitation energy for at least one of the gases. The most important use of the invention is to provide more efficient fluorescent and/or ultraviolet lamps.

  5. Heat pump employing optimal refrigerant compressor for low pressure ratio applications

    DOE Patents [OSTI]

    Ecker, Amir L. (Dallas, TX)

    1982-01-01

    What is disclosed is a heat pump apparatus for conditioning a fluid characterized by a fluid handler for circulating the fluid in heat exchange relationship with a refrigerant fluid; two refrigerant heat exchangers; one for effecting the heat exchange with the fluid and a second refrigerant-heat exchange fluid heat exchanger for effecting a low pressure ratio of compression of the refrigerant; a rotary compressor for compressing the refrigerant with low power consumption at the low pressure ratio; at least one throttling valve connecting at the inlet side of heat exchanger in which liquid refrigerant is vaporized; a refrigerant circuit serially connecting the above elements; refrigerant in the circuit; a source of heat exchange fluid; heat exchange fluid circulating device and heat exchange fluid circuit for circulating the heat exchange fluid in heat exchange relationship with the refrigerant.

  6. Simulation of the shielding of dust particles in low pressure glow Seung J. Choi and Mark J. Kushner

    E-Print Network [OSTI]

    Kushner, Mark

    Simulation of the shielding of dust particles in low pressure glow discharges Seung J. Choi) The dynamics of the shielding of particulates ("dust") in low pressure glow discharges have been investigated sections represented by the geometrical obscuration of the charged dust particles and their shield- ing

  7. Control system performance in a modern daylighted office building

    SciTech Connect (OSTI)

    Benton, C.; Fountain, M., Selkowitz, S.; Jewell, J.

    1990-10-01

    Lockheed Building 157 is one of the United States' largest experiments in contemporary daylighting. Built in 1983, the five story structure houses 3,000 employees and uses daylight for ambient illumination throughout its 56,000-m{sup 2} office interior. A continuously dimmable fluorescent lighting system supplements interior daylight under the control of open-loop ceiling-mounted photosensors. In 1985 Lawrence Berkeley Laboratory (LBL) began a year-long program to measure lighting system performance in the building. Data from this study indicated that architectural features of the building performed admirably, admitting significant daylight to large areas of the open plan interior. Operational savings, however, were limited by inappropriate performance of the control system in many of the building's lighting circuits. LBL recently completed a follow-up investigation of the lighting systems in Building 157 addressing the interaction between daylight and the lighting control system with the goal of improving control system performance. We modified a 1,700-m{sup 2} test zone by relocating the photosensors, attenuating the photosensor control signal, changing the response pattern of the photosensors, and implementing a LBL-developed calibration procedure, Following these modifications, we installed four data-acquisition systems and collected detailed data describing illuminance and lighting power demand during two week periods in the summer, equinox, and winter seasons. This paper presents a comparison of lighting system performance before and after the LBL modifications. Analysis of the data indicates our modifications were successful in maintaining interior illuminance at the target of 350 lux with minimal electric energy consumption. 10 refs., 9 figs.

  8. Downhole steam generator using low-pressure fuel and air supply

    DOE Patents [OSTI]

    Fox, R.L.

    1981-01-07

    For tertiary oil recovery, an apparatus for downhole steam generation is designed in which water is not injected directly onto the flame in the combustor, the combustion process is isolated from the reservoir pressure, the fuel and oxidant are supplied to the combustor at relatively low pressures, and the hot exhaust gases is prevented from entering the earth formation but is used to preheat the fuel and oxidant and water. The combustion process is isolated from the steam generation process. (DLC)

  9. Low pressure arc discharge lamp apparatus with magnetic field generating means

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.; Maya, J.

    1987-10-06

    A low-pressure arc discharge apparatus having a magnetic field generating means for increasing the output of a discharge lamp is disclosed. The magnetic field generating means, which in one embodiment includes a plurality of permanent magnets, is disposed along the lamp for applying a constant transverse magnetic field over at least a portion of the positive discharge column produced in the arc discharge lamp operating at an ambient temperature greater than about 25 C. 3 figs.

  10. MELCOR calculations for a low-pressure short-term station blackout in a BWR-6

    SciTech Connect (OSTI)

    Carbajo, J.J. [Martin Marietta Energy Systems, Oak Ridge, TN (United States)

    1995-12-31

    A postulated, low-pressure, short term station blackout severe accident has been analyzed using the MELCOR code for the Grand Gulf nuclear power plant. Different versions have been used with three different models of the plant. This paper presents results of the effects of different plant models and versions of MELCOR on the calculated results and to present the best-estimating timing of events for this transient.

  11. Determination of the Electron Temperature in a Low Pressure Dusty Radiofrequency Methane Plasma

    SciTech Connect (OSTI)

    Massereau-Guilbaud, Veronique; Geraud-Grenier, Isabelle; Plain, Andre [GREMI, UMR6606, Universite d'Orleans/CNRS (France) and GREMI, Faculte des Sciences, Site de Bourges, rue G.Berger, BP 4043, 18028 BOURGES cedex (France); Mikikian, Maxime [GREMI, Polytech'Orleans, 14 rue d'Issoudun, BP 6744, 45067 Orleans cedex 2 (France)

    2011-11-29

    The particles are obtained by PECVD in radiofrequency (13.56 MHz) low pressure plasmas (90%CH4-10%Ar). During the particle growth, the particles trap electrons and modify the EEDF, and the electrical and optical characteristics of the plasma. The plasma is analyzed by Optical Emission Spectroscopy. The excitation temperature and the electron temperature are calculated from the H{sub {alpha}}, H{sub {beta}}, H{sub {gamma}} Balmer hydrogen line intensities and from Ar ones. The temporal evolutions of the temperatures during the particle formation are compared and discussed.

  12. A laser and molecular beam mass spectrometer study of low-pressure dimethyl ether flames

    SciTech Connect (OSTI)

    Andrew McIlroy; Toby D. Hain; Hope A. Michelsen; Terrill A. Cool

    2000-12-15

    The oxidation of dimethyl ether (DME) is studied in low-pressure flames using new molecular beam mass spectrometer and laser diagnostics. Two 30.0-Torr, premixed DME/oxygen/argon flames are investigated with stoichiometries of 0.98 and 1.20. The height above burner profiles of nine stable species and two radicals are measured. These results are compared to the detailed chemical reaction mechanism of Curran and coworkers. Generally good agreement is found between the model and data. The largest discrepancies are found for the methyl radical profiles where the model predicts qualitatively different trends in the methyl concentration with stoichiometry than observed in the experiment.

  13. Ductile phase toughening of molybdenum disilicide by low pressure plasma spraying

    SciTech Connect (OSTI)

    Castro, R.G.; Rollett, A.D.; Stanek, P.W. ); Smith, R.W. . Dept. of Materials Engineering)

    1992-01-01

    The low fracture toughness of MoSi{sub 2} at ambient temperature has prompted investigations into new processing methods in order to impart some degree of fracture toughness into this inherently brittle material. In the following investigation, low pressure plasma spraying was employed as a fabricating technique to produce spray-formed deposits of MoSi{sub 2} and ductile reinforced MoSi{sub 2} composites containing approximately 10 and 20 volume percent of a discontinuous tantalum lamelli reinforcement. Fracture toughness (K{sub 1C}) measurements of MoSi{sub 2} and the MoSi{sub 2}/Ta composites were done using a chevron notched 4-point bend fracture toughness test in both the as-sprayed condition and after hot isostatic pressing at 1200{degrees}C/206 MPa for 1 hour. Results from the ductile reinforced MoSi{sub 2}/Ta composites have shown fracture toughness increases on the order of 200% over the as-sprayed MoSi{sub 2}. In addition, a marked anisotropy in fracture toughness was observed in the spray-formed deposits due to the layered splat structure produced by the low pressure plasma spray process.

  14. Ductile phase toughening of molybdenum disilicide by low pressure plasma spraying

    SciTech Connect (OSTI)

    Castro, R.G.; Rollett, A.D.; Stanek, P.W.; Smith, R.W.

    1992-02-01

    The low fracture toughness of MoSi{sub 2} at ambient temperature has prompted investigations into new processing methods in order to impart some degree of fracture toughness into this inherently brittle material. In the following investigation, low pressure plasma spraying was employed as a fabricating technique to produce spray-formed deposits of MoSi{sub 2} and ductile reinforced MoSi{sub 2} composites containing approximately 10 and 20 volume percent of a discontinuous tantalum lamelli reinforcement. Fracture toughness (K{sub 1C}) measurements of MoSi{sub 2} and the MoSi{sub 2}/Ta composites were done using a chevron notched 4-point bend fracture toughness test in both the as-sprayed condition and after hot isostatic pressing at 1200{degrees}C/206 MPa for 1 hour. Results from the ductile reinforced MoSi{sub 2}/Ta composites have shown fracture toughness increases on the order of 200% over the as-sprayed MoSi{sub 2}. In addition, a marked anisotropy in fracture toughness was observed in the spray-formed deposits due to the layered splat structure produced by the low pressure plasma spray process.

  15. Simplified configuration for the combustor of an oil burner using a low pressure, high flow air-atomizing nozzle

    DOE Patents [OSTI]

    Butcher, Thomas A. (Port Jefferson, NY); Celebi, Yusuf (Middle Island, NY); Fisher, Leonard (Colrain, MA)

    2000-09-15

    The invention relates to clean burning of fuel oil with air. More specifically, to a fuel burning combustion head using a low-pressure, high air flow atomizing nozzle so that there will be a complete combustion of oil resulting in a minimum emission of pollutants. The improved fuel burner uses a low pressure air atomizing nozzle that does not result in the use of additional compressors or the introduction of pressurized gases downstream, nor does it require a complex design. Inventors:

  16. Lighting energy savings potential of split-pane electrochromic windows controlled for daylighting with visual comfort

    E-Print Network [OSTI]

    Fernandes, Luis

    2014-01-01

    Daylight Coefficients, Lighting Research and Technology,America, 1999, The IESNA lighting handbook: reference andcontrol of electric lighting and blinds, Solar Energy, 77(

  17. Gravity Control by means of Electromagnetic Field through Gas or Plasma at Ultra-Low Pressure

    E-Print Network [OSTI]

    Fran De Aquino

    2013-12-02

    It is shown that the gravity acceleration just above a chamber filled with gas or plasma at ultra-low pressure can be strongly reduced by applying an Extra Low-Frequency (ELF) electromagnetic field across the gas or the plasma. This Gravitational Shielding Effect is related to recent discovery of quantum correlation between gravitational mass and inertial mass. According to the theory samples hung above the gas or the plasma should exhibit a weight decrease when the frequency of the electromagnetic field is decreased or when the intensity of the electromagnetic field is increased. This Gravitational Shielding Effect is unprecedented in the literature and can not be understood in the framework of the General Relativity. From the technical point of view, there are several applications for this discovery; possibly it will change the paradigms of energy generation, transportation and telecommunications.

  18. The effect of discharge chamber geometry on the ignition of low-pressure rf capacitive discharges

    SciTech Connect (OSTI)

    Lisovskiy, V.; Martins, S.; Landry, K.; Douai, D.; Booth, J.-P.; Cassagne, V.; Yegorenkov, V. [Laboratoire de Physique et Technologie des Plasmas, Ecole Polytechnique, Palaiseau 91128, France and Kharkov National University, Kharkov 61077 (Ukraine); Unaxis Displays Division France SAS, 5, Rue Leon Blum, Palaiseau 91120 (France); Laboratoire de Physique et Technologie des Plasmas, Ecole Polytechnique, Palaiseau 91128 (France); Unaxis Displays Division France SAS, 5, Rue Leon Blum, Palaiseau 91120 (France); Kharkov National University, Kharkov 61077 (Ukraine)

    2005-09-15

    This paper reports measured and calculated breakdown curves in several gases of rf capacitive discharges excited at 13.56 MHz in chambers of three different geometries: parallel plates surrounded by a dielectric cylinder ('symmetric parallel plate'), parallel plates surrounded by a grounded metallic cylinder ('asymmetric parallel plate'), and parallel plates inside a much larger grounded metallic chamber ('large chamber'). The breakdown curves for the symmetric chamber have a multivalued section at low pressure. For the asymmetric chamber the breakdown curves are shifted to lower pressures and rf voltages, but the multivalued feature is still present. At higher pressures the breakdown voltages are much lower than for the symmetric geometry. For the large chamber geometry the multivalued behavior is not observed. The breakdown curves were also calculated using a numerical model based on fluid equations, giving results that are in satisfactory agreement with the measurements.

  19. Direct current-self-sustained non-ambipolar plasma at low pressure

    SciTech Connect (OSTI)

    Chen, Zhiying; Chen, Lee; Funk, Merritt

    2013-12-16

    For decades, non-ambipolar diffusion has been observed and studied in laboratory plasmas that contain a double layer. However, self-sustained non-ambipolar plasma has yet to be demonstrated. This article reports the method and results for achieving such a condition at low pressure, with a wide power range (as low as 6 W). The findings reveal that to achieve self-sustained non-ambipolar plasma, both the balance between electron and ion heating and the space-potential gradient are critical. The plasma reactor developed in this work has potential applications that include microelectronic surface processing and space propulsion, via space-charge-neutral plasma-beam thruster, when operated in the high power regime.

  20. Study of flow fields induced by surface dielectric barrier discharge actuator in low-pressure air

    SciTech Connect (OSTI)

    Che, Xueke E-mail: st@mail.iee.ac.cn; Nie, Wansheng; Tian, Xihui; Hou, Zhiyong; He, Haobo; Zhou, Penghui; Zhou, Siyin; Yang, Chao; Shao, Tao E-mail: st@mail.iee.ac.cn

    2014-04-15

    Surface dielectric barrier discharge (SDBD) is a promising method for a flow control. Flow fields induced by a SDBD actuator driven by the ac voltage in static air at low pressures varying from 1.0 to 27.7?kPa are measured by the particle image velocimetry method. The influence of the applied ac voltage frequency and magnitude on the induced flow fields is studied. The results show that three different classes of flow fields (wall jet flow field, complex flow field, and vortex-shape flow field) can be induced by the SDBD actuator in the low-pressure air. Among them, the wall jet flow field is the same as the tangential jet at atmospheric pressure, which is, together with the vertical jet, the complex flow field. The vortex-shape flow field is composed of one vertical jet which points towards the wall and two opposite tangential jets. The complex and the vortex-shape flow fields can be transformed to the wall jet flow field when the applied ac voltage frequency and magnitude are changed. It is found that the discharge power consumption increases initially, decreases, and then increases again at the same applied ac voltage magnitude when the air pressure decreases. The tangential velocity of the wall jet flow field increases when the air pressure decreases. It is however opposite for the complex flow field. The variation of the applied ac voltage frequency influences differently three different flow fields. When the applied ac voltage magnitude increases at the same applied ac voltage frequency, the maximal jet velocity increases, while the power efficiency increases only initially and then decreases again. The discharge power shows either linear or exponential dependences on the applied ac voltage magnitude.

  1. Daylight in façade renewal : using new metrics to inform the retrofitting of aging modern-ear façade types

    E-Print Network [OSTI]

    Rice, Edward Oren

    2006-01-01

    New methods for quantifying daylight are increasingly accessible to designers and planners. While these methods have enabled new building facades to better balance the admission of daylight with the maintenance of thermal ...

  2. A new approach in data visualization to integrate time and space variability of daylighting in the design process

    E-Print Network [OSTI]

    Yi, Lu, S.M. Massachusetts Institute of Technology

    2008-01-01

    Daylighting design has great impact on the performance and aesthetical quality of a work of architecture but requires many issues to be addressed during the design process. The way existing daylighting tools deliver data ...

  3. Invited paper for the 2001 IESNA National Conference Daylighting, Dimming, and the Electricity Crisis in California

    E-Print Network [OSTI]

    of California's energy crisis and the consequent increases in electricity rates, is daylighting now a cost, and the Electricity Crisis in California Francis Rubinstein, Danielle Neils and Nesrin Colak Ernest Orlando Lawrence Contract No. DE-AC03-76SF00098. #12;Daylighting, Dimming and California Electricity Crisis Rubinstein

  4. P5.60B DERIVATION OF DAYLIGHT AND SOLAR IRRADIANCE DATA FROM SATELLITE OBSERVATIONS

    E-Print Network [OSTI]

    Heinemann, Detlev

    P5.60B DERIVATION OF DAYLIGHT AND SOLAR IRRADIANCE DATA FROM SATELLITE OBSERVATIONS A. Hammer, D of the downward surface shortwave irradiance from satellite observations has been subject to numerous project SATELLIGHT an attempt is made to use satellite methods to derive daylight and solar irradiance

  5. Evaluation of Lightshelf Daylighting Systems for Office Buildings in Hot Climates 

    E-Print Network [OSTI]

    Abdulmohsen, A.; Boyer, L. L.; Degelman, L. O.

    1994-01-01

    This paper presents part of an on-going research project in the College of Architecture at Texas A&M University. This research investigates how lightshelf daylighting delivery systems can manipulate sunlight and daylight both in terms of their light...

  6. Towards Embedded Wireless-Networked Intelligent Daylighting Systems for Commercial Buildings

    E-Print Network [OSTI]

    Agogino, Alice M.

    Towards Embedded Wireless-Networked Intelligent Daylighting Systems for Commercial Buildings Yao, daylighting systems are not widely used in the commercial office building. Barriers prohibiting adoption) `Smart Dust motes' wireless platforms is explored. Due to their small size, they can be placed directly

  7. Sodium Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01

    for  Sodium  Ion  Batteries   One   of   the   challenges  of   sodium   ion   batteries   is   identification   of  for   use   in   batteries.   Our   recent   work   has  

  8. Transient growth mechanisms of low Reynolds number flow over a low-pressure turbine blade

    E-Print Network [OSTI]

    Sharma, AS; Sherwin, SJ; Theofilis, V; 10.1007/s00162-010-0183-9

    2013-01-01

    A direct transient growth analysis for three-dimensional perturbations to flow past a periodic array of T-106/300 low-pressure turbine fan blades is presented. The methodology is based on a singular value decomposition of the flow evolution operator, linearised about a steady or periodic base flow. This analysis yields the optimal growth modes. Previous work on global mode stability analysis of this flow geometry showed the flow is asymptotically stable, indicating a non-modal explanation of transition may be more appropriate. The present work extends previous investigations into the transient growth around a steady base flow, to higher Reynolds numbers and periodic base flows. It is found that the notable transient growth of the optimal modes suggests a plausible route to transition in comparison to modal growth for this configuration. The spatial extent and localisation of the optimal modes is examined and possible physical triggering mechanisms are discussed. It is found that for longer times and longer sp...

  9. Exhaust Aftertreatment and Low Pressure Loop EGR Applied to an Off-Highway Engine

    SciTech Connect (OSTI)

    Baumgard, Kirby; Triana, Antonio; Johnson, John; Yang, Song; Premchand, Kiran

    2006-01-30

    The goal of the project was to demonstrate that low pressure loop EGR incorporating a diesel oxidation catalyst (DOC) and a diesel particulate filter (DPF) can be applied to an off-highway engine to meet Tier 3 (Task I) and Interim Tier 4 (Task II) off-road emissions standards. Task I data was collected using a John Deere 8.1 liter engine modified with a low pressure loop EGR system. The engine and EGR system was optimized and final data over the ISO 8178 eight mode test indicated the NOx emissions were less than 4 g/kWh and the PM was less than 0.02 g/kWh which means the engine met the Tier 3 off-road standard. Considerable experimental data was collected and used by Michigan Tech University to develop and calibrate the MTU-Filter 1D DPF model. The MTU-Filter 1D DPF code predicts the particulate mass evolution (deposition and oxidation) in the diesel particulate filter (DPF) during simultaneous loading and during thermal and NO{sub 2}-assisted regeneration conditions. It also predicts the pressure drop across the DPF, the flow and temperature fields, the solid filtration efficiency and the particle number distribution downstream of the DPF. A DOC model was also used to predict the NO{sub 2} upstream of the DPF. The DPF model was calibrated to the experimental data at temperatures from 230 C to 550 C, and volumetric flow rates from 9 to 39 actual m{sup 3}/min. Model predictions of the solid particulate mass deposited in the DPF after each loading and regeneration case were in agreement within +/-10g (or +/-10%) of experimental measurements at the majority of the engine operating conditions. The activation temperatures obtained from the model calibration are in good agreement with values reported in the literature and gave good results in the model calibration by using constant pre-exponential factors throughout the entire range of conditions evaluated. The average clean filter permeability was 2.372 x 10{sup -13} m{sup 2}. Estimates of the solid particulate mass packing density inside the porous wall were 1 to 5 kg/m{sup 3}; and percolation factors were 0.81 to 0.97. Average particulate layer permeability was 1.95 x 10{sup -14} m{sup 2}. Solid particulate layer packing density values were between 11 and 128 kg/m{sup 3}. These values were in good agreement with the Peclet number correlation theory reported in the literature. NO{sub 2}-assisted oxidation of PM in the DPF showed experimentally that a significant reduction of the pressure drop can be achieved (<8 kPa) when sufficient NO{sub 2} (>120 ppm) is available and high exhaust gas temperatures ({approx}360-460 C) can be maintained, even at high PM loadings (low NO{sub 2}/solid PM ratios). The CRT{trademark} (DOC-DPF system) showed limited advantages when used with high PM rates (low NOx/PM ratios) in combination with a low pressure loop EGR strategy for a continuous operation of an engine-exhaust aftertreatment system. The 8.1-liter engine was not designed for low-pressure loop EGR and when the EGR was added the NOx emissions were reduced but the PM emissions increased. This corresponds to the well known NOx to PM relationship in which if the NOx is reduced the PM emissions increase. In order for this technology to be successful on this engine family, the engine out PM emissions must be reduced. These results led to Task II. Task II objective was to meet the interim Tier 4 standards using the CCRT{trademark} technology applied to an advanced 6.8 liter John Deere engine. The advanced engine incorporated a 4 valve head, required additional EGR, an advanced high pressure common rail fuel system and a better matched turbocharger. The EGR system was optimized and the goal of less than 2 g/kWh NOx and less than 0.02 g/kWh PM were achieved over the 8 mode test. Again, experimental data was provided to Michigan Tech to study the passive regeneration of the CCRT{trademark} technology. Two computer models, i.e., the MTU 1-D DOC model and the MTU 1-D 2-layer CPF model were developed as part of this research and calibrated using the data obtained from experiments. The 1-D D

  10. Thermodynamics of methane adsorption on copper HKUST-1 at low pressure

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wu, Di; Guo, Xiaofeng; Sun, Hui; Navrotsky, Alexandra

    2015-06-11

    Metal–organic frameworks (MOFs) can be engineered as natural gas storage materials by tuning the pore structures and surface properties. Here we report the direct measurement of CH? adsorption enthalpy on a paddlewheel MOF (Cu HKUST-1) using gas adsorption calorimetry at 25 °C at low pressures (below 1 bar). In this pressure region, the CH?–CH? intermolecular interactions are minimized and the energetics solely reflects the CH?–MOF interactions. Our results suggest moderately exothermic physisorption with an enthalpy of -21.1 ± 1.1 kJ/mol CH? independent of coverage. The calorimetric investigation complements previous computational and crystallographic studies by providing zero coverage enthalpies of CH?more »adsorption. The analysis of the new and literature data suggests that in initial stages of adsorption the CH?–HKUST-1 interaction tends to be more sensitive to the pore dimension than to the guest polarizability, suggesting a less specific chemical binding role for the open Cu site.« less

  11. Low-pressure hydrocracking of coal-derived Fischer-Tropsch waxes to diesel

    SciTech Connect (OSTI)

    Dieter Leckel [Sasol Technology Research and Development, Sasolburg (South Africa). Fischer-Tropsch Refinery Catalysis

    2007-06-15

    Coal-derived low-temperature Fischer-Tropsch (LTFT) wax was hydrocracked at pressures of 3.5-7.0 MPa using silica-alumina-supported sulfided NiW/NiMo and an unsulfided noble metal catalyst, modified with MoO{sub 3}. A low-pressure operation at 3.5 MPa produced a highly isomerized diesel, having low cloud points (from -12 to -28{sup o}C) combined with high cetane numbers (69-73). These properties together with the extremely low sulfur ({lt}5 ppm) and aromatic ({lt}0.5%) contents place coal/liquid (CTL) derived distillates as highly valuable blending components to achieve Eurograde diesel specifications. The upgrading of coal-based LTFT waxes through hydrocracking to high-quality diesel fuel blend components in combination with commercial-feasible coal-integrated gasification combined cycle (coal-IGCC) CO{sub 2} capture and storage schemes should make CTL technology more attractive. 28 refs., 7 figs., 8 tabs.

  12. Studies on hydrogen plasma and dust charging in low-pressure filament discharge

    SciTech Connect (OSTI)

    Kakati, B. Kalita, D.; Kausik, S. S.; Saikia, B. K.; Bandyopadhyay, M.

    2014-08-15

    The effect of working gas pressure and dust charging on electron energy probability function has been studied for hydrogen plasma in a multi-dipole dusty plasma device. A cylindrical Langmuir probe is used to evaluate the plasma parameters and electron energy probability function (EEPF) for different working pressures. For lower energy range (below 10?eV), the EEPF follows a bi-Maxwellian shape at very low pressure (6 × 10{sup ?5}?mbar), while elevating the working pressure up to ?2 × 10{sup ?3} mbar, the shape of the EEPF transforms into a single Maxwellian. Some dip structures are observed at high energy range (??>?10?eV) in the EEPF of hydrogen plasma at all the working conditions. In presence of dust particles, it is observed that the shape of the EEPF changes due to the redistribution of the high and low-energy electron populations. Finally, the effect of working pressure on charge accumulation on dust particles is studied with the help of a Faraday cup and electrometer. From the observations, a strong influence of working pressure on plasma parameters, EEPF and dust charging is observed.

  13. Effect of confining wall potential on charged collimated dust beam in low-pressure plasma

    SciTech Connect (OSTI)

    Kausik, S. S.; Kakati, B.; Saikia, B. K. [Centre of Plasma Physics, Institute for Plasma Research, Sonapur 782 402 (India)] [Centre of Plasma Physics, Institute for Plasma Research, Sonapur 782 402 (India)

    2013-05-15

    The effect of confining wall potential on charged collimated dust beam in low-pressure plasma has been studied in a dusty plasma experimental setup by applying electrostatic field to each channel of a multicusp magnetic cage. Argon plasma is produced by hot cathode discharge method at a pressure of 5×10{sup ?4} millibars and is confined by a full line cusped magnetic field confinement system. Silver dust grains are produced by gas-evaporation technique and move upward in the form of a collimated dust beam due to differential pressure maintained between the dust and plasma chambers. The charged grains in the beam after coming out from the plasma column enter into the diagnostic chamber and are deflected by a dc field applied across a pair of deflector plates at different confining potentials. Both from the amount of deflection and the floating potential, the number of charges collected by the dust grains is calculated. Furthermore, the collimated dust beam strikes the Faraday cup, which is placed above the deflector plates, and the current (?pA) so produced is measured by an electrometer at different confining potentials. The experimental results demonstrate the significant effect of confining wall potential on charging of dust grains.

  14. Simulation of an Ar/NH{sub 3} low pressure magnetized direct current discharge

    SciTech Connect (OSTI)

    Li Zhi [School of Science, University of Science and Technology Liaoning, Anshan 114051 (China); School of Physics and Optoelectronic Engineering, Dalian University of Technology, Dalian 116024 (China); Zhao Zhen [School of Chemistry and Life Science, Anshan Normal University, Anshan 114007 (China); School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051 (China); Li Xuehui [Physiccal Science and Technical College, Dalian University, Dalian 116622 (China)

    2013-01-15

    A two-dimensional fluid model has been used to investigate the properties of plasma in an Ar/NH{sub 3} low pressure magnetized direct current discharge. We compared the simulation results with the theoretical and experimental results of the other gas discharge in which the magnetic field is considered. Results that obtained using this method are in good agreement with literature. The simulation results show that the positive ammonia ion density follows the positive argon ion density. The Ar{sub 2}{sup +} density is slightly higher than the Ar{sup +} density at 100 mTorr. The largest ammonia ion is NH{sub 3}{sup +} ion, followed by NH{sub 2}{sup +}, NH{sub 4}{sup +}, and NH{sup +} ions. The contribution of NH{sup +} ions to the density of the positive ammonia ions is marginal. The influence of pressure on the plasma discharge has been studied by simulation, and the mechanisms have been discussed. The average plasma density increases as pressure increased. The plasma density appears to be more inhomogeneous than that at the lower pressure. The ratio of charge particles changed as pressure increased. The Ar{sup +} density is slightly higher than the Ar{sub 2}{sup +} density as the pressure increased. It makes NH{sub 4}{sup +} ratio increase as pressure increased. It shows that the electron temperature drops with rising pressure by numerical calculation.

  15. Transport of low pressure electronegative SF{sub 6} plasma through a localized magnetic filter

    SciTech Connect (OSTI)

    Levko, D.; Garrigues, L.; Hagelaar, G. J. M. [LAPLACE (Laboratoire Plasma et Conversion d'Energie), Universite de Toulouse, UPS, INPT Toulouse, 118 route de Narbonne, F-31062 Toulouse Cedex 9, France and CNRS, LAPLACE, F-31062 Toulouse (France)

    2014-08-15

    The generation of an ion-ion plasma where only few electrons are present in the discharge could be appropriated in the context of ion plasma source applications. We present in this paper results obtained with a one-dimensional fluid model in the context of low pressure electronegative SF{sub 6} plasma. Without magnetic field, results show that the electron density is still large in the discharge. With a localized magnetic filter, where the magnetic field strength is such that the transport of the electrons is affected while the transport of ion species remains unmagnetized, we show that a region with a negative–positive ion plasma is found downstream the magnetic filter. The negative ions are produced in the filter due to the decrease of electron temperature. We also find conditions when the plasma sheath near the biased electrode collapses and the negative ion extraction from the plasma becomes possible. In addition, the influence of E?×?B electron transport on the one-dimensional model results is discussed.

  16. High-beta plasma effects in a low-pressure helicon plasma

    SciTech Connect (OSTI)

    Corr, C. S.; Boswell, R. W. [Space Plasma, Power and Propulsion Group (SP3), Research School of Physical Science and Engineering, Australian National University, Canberra ACT 0200 (Australia)

    2007-12-15

    In this work, high-beta plasma effects are investigated in a low-pressure helicon plasma source attached to a large volume diffusion chamber. When operating above an input power of 900 W and a magnetic field of 30 G a narrow column of bright blue light (due to Ar II radiation) is observed along the axis of the diffusion chamber. With this blue mode, the plasma density is axially very uniform in the diffusion chamber; however, the radial profiles are not, suggesting that a large diamagnetic current might be induced. The diamagnetic behavior of the plasma has been investigated by measuring the temporal evolution of the magnetic field (B{sub z}) and the plasma kinetic pressure when operating in a pulsed discharge mode. It is found that although the electron pressure can exceed the magnetic field pressure by a factor of 2, a complete expulsion of the magnetic field from the plasma interior is not observed. In fact, under our operating conditions with magnetized ions, the maximum diamagnetism observed is {approx}2%. It is observed that the magnetic field displays the strongest change at the plasma centre, which corresponds to the maximum in the plasma kinetic pressure. These results suggest that the magnetic field diffuses into the plasma sufficiently quickly that on a long time scale only a slight perturbation of the magnetic field is ever observed.

  17. Simulation study of nanoparticle coating in a low pressure plasma reactor

    SciTech Connect (OSTI)

    Pourali, N.; Foroutan, G.

    2015-02-15

    A self-consistent combination of plasma fluid model, nanoparticle heating model, and surface deposition model is used to investigate the coating of nanosize particles by amorphous carbon layers in a low pressure plasma reactor. The numerical results show that, owing to the net heat release in the surface reactions, the particle temperature increases and its equilibrium value remains always 50?K above the background gas temperature. The deposition rate decreases with increasing of the particle temperature and the corresponding time scale is of the order of 10?ms. The deposition rate is also strongly affected by the change in plasma parameters. When the electron temperature is increased, the deposition rate first increases due to the enhanced ion and radical generation, shows a maximum and then declines as the particle temperature rises above the gas temperature. An enhancement in the background gas pressure and/or temperature leads to a reduction in the deposition rate, which can be explained in terms of the enhanced etching by atomic hydrogen and particle heating by the background gas.

  18. Characterizing the Separation and Reattachment of Suction Surface Boundary Layer in Low Pressure Turbine Using Massively Parallel Large Eddy Simulations 

    E-Print Network [OSTI]

    Jagannathan, Shriram

    2012-02-14

    The separation and reattachment of the suction surface boundary layer in a low pressure turbine is characterized using large-eddy simulation at Re=68,000 based on freestream velocity and suction surface length. A high pass filtered Smagorinsky model...

  19. Daylight Analysis with Microcomputers for School Buildings in a Hot, Humid Climate 

    E-Print Network [OSTI]

    Leaver, J.; McQueen, T.

    1987-01-01

    Daylighting and other passive energy technologies are critical issues that should be considered in the early stages of building planning and architectural design. Both new design and retrofit of existing buildings benefit greatly by use...

  20. A PROCEDURE FOR CALCULATING INTERIOR DAYLIGHT ILLUMINATION WITH A PROGRAMMABLE HAND CALCULATOR

    E-Print Network [OSTI]

    Bryan, H.J.

    2010-01-01

    Reflected Component or IRC). The total for these threeDaylight Factor = SC + ERC + IRC THE SKY COMPONENT The skyfrom ground Overcast Sky The IRC is the ratio between the

  1. A SIMPLIFIED PROCEDURE FOR CALCULATING THE EFFECTS OF DAYLIGHT FROM CLEAR SKIES

    E-Print Network [OSTI]

    Bryan, Harvey J.

    2012-01-01

    Reflected Component or IRC). The total for these threeDaylight Factor SC + ERC + IRC The Sky Component: The skycomponent is given as: Average IRC where T Transmittance of

  2. Daylighting and solar shading performances of an innovative automated reflective louver system

    E-Print Network [OSTI]

    Hashemi, Arman

    2014-08-07

    follows initial investigations into the design and applicability of an automated retrofitted panel thermal shutters which can also act as a sunshade and daylighting system. The system has a patented function which allows each shutter...

  3. Experience of light : the use of an inverse method and a genetic algorithm in daylight design

    E-Print Network [OSTI]

    Chutarat, Acharawan

    2001-01-01

    Integration of daylight availability in time and architectural space is a critical element in achieving optimal comfort and productivity, as well as in minimizing energy consumption. In recent years, there has been an ...

  4. Energy, Shading and Daylighting Analysis for the Austin Bergstrom International Airport Terminal 

    E-Print Network [OSTI]

    Holder, L. M. III; Holder, L. M. IV

    2002-01-01

    Our firm was under contract with the City of Austin, Texas to perform energy analysis and analysis of the daylighting potential within the New Austin Bergstrom International Airport Terminal. Design of the Passenger Terminal Facility for the New...

  5. Energy efficient commercial buildings : a study of natural daylighting in the context of adaptive reuse

    E-Print Network [OSTI]

    Crowley, John Stephen

    1982-01-01

    Daylighting is a powerful design element which can have a dramatic impact on people's perception of space, physical and psychological well-being as well as a building's annual and daily energy requirements. Understanding ...

  6. Performance-based assessment of daylight on tropical buildings- a case Study

    E-Print Network [OSTI]

    Szu Cheng, CHIEN

    2013-01-01

    Sustainability in the Tropics For the visual performance ofSustainability in the Tropics Table 3 Metrics conducted to assess dayliglzting performanceSustainability in the Tropics APPROACH Description of the case study model Daylight performance

  7. A system for optimizing interior daylight distribution using reflective Venetian blinds with independent blind angle control

    E-Print Network [OSTI]

    McGuire, Molly E

    2005-01-01

    An operational algorithm for blind angle control is developed to optimize the daylighting performance of a system of reflective Venetian blinds. Numerical modeling and experiment confirm that independent control of alternating ...

  8. Economic and design analysis of daylighting a commercial tower in a hot and humid climate

    E-Print Network [OSTI]

    Roscow, Robert F

    1981-01-01

    A forty story commercial office tower in Tampa, Florida was redesigned for daylighting. The methods are outlined and results illustrated, A cooling load comparison is done to determine the economic feasibility of such a ...

  9. Cooling Energy and Cost Savings with Daylighting in a Hot and Humid Climate 

    E-Print Network [OSTI]

    Arasteh, D.; Johnson, R.; Selkowitz, S.; Connell, D.

    1985-01-01

    Fenestration performance in nonresidential buildings in hot climates is often a large cooling load liability. Proper fenestration design and the use of daylight-responsive dimming controls on electric lights can, in addition to drastically reducing...

  10. Question of the Week: How Do You Feel About the Extended Daylight...

    Energy Savers [EERE]

    in April. The Energy Policy Act of 2005 changed the start and end dates of Daylight Saving Time in order to save energy, and DOE has found that it worked. The savings from...

  11. Form and daylight as a creative medium : Church of John Paul II in South End, Boston

    E-Print Network [OSTI]

    Gruzewski, Jaroslaw

    1992-01-01

    This thesis is an architectural design project of a Catholic Church dedicated to Pope John Paul II. The main intention of this Thesis is to explore and clearly present daylighting methods and techniques and how important ...

  12. Time-varied daylighting performance to enable a goal-driven design process

    E-Print Network [OSTI]

    Kleindienst, Siân A. (Siân Alexandra)

    2010-01-01

    Due to the overwhelming number of decisions to be made during early stage design, there is a need for intuitive methods to communicate data so that it is quickly and easily understood by the designer. In daylighting analysis, ...

  13. Highly stable silicon dioxide films deposited by means of rapid thermal -low-pressure chemical vapor deposition onto InP

    E-Print Network [OSTI]

    Florida, University of

    grown by rapid thermal, low-pressure chemical vapor deposition (RT-LPCVD), using pure oxygen (0,) and 2Highly stable silicon dioxide films deposited by means of rapid thermal - low-pressure chemical vapor deposition onto InP A. Katz, A. Feingold, U. K. Chakrabarti, and S. J. Peat-ton AT&T Bell

  14. The influence of ammonia on rapid-ther al low-pressure metalorganic chemical vapor deposited TIN, films from tetrakis (dimethylamido) titanium

    E-Print Network [OSTI]

    Florida, University of

    The influence of ammonia on rapid-ther al low-pressure metalorganic chemical vapor deposited TIN, and stress of rapid- thermal low pressure metalorganic chemical vapor deposited (RT-LPMOCVD) TiN, films on In) liquid precursors, were studied. Enhanced deposition rates of l-3 nm s- ' at total chamber pressures

  15. Graphene chemical vapor deposition at very low pressure: The impact of substrate surface self-diffusion in domain shape

    SciTech Connect (OSTI)

    Cunha, T. H. R.; Ek-Weis, J.; Lacerda, R. G.; Ferlauto, A. S., E-mail: ferlauto@fisica.ufmg.br [Department of Physics, Federal University of Minas Gerais, Belo Horizonte 31270-901 (Brazil)

    2014-08-18

    The initial stages of graphene chemical vapor deposition at very low pressures (<10{sup ?5?}Torr) were investigated. The growth of large graphene domains (?up to 100??m) at very high rates (up to 3??m{sup 2} s{sup ?1}) has been achieved in a cold-wall reactor using a liquid carbon precursor. For high temperature growth (>900?°C), graphene grain shape and symmetry were found to depend on the underlying symmetry of the Cu crystal, whereas for lower temperatures (<900?°C), mostly rounded grains are observed. The temperature dependence of graphene nucleation density was determined, displaying two thermally activated regimes, with activation energy values of 6?±?1?eV for temperatures ranging from 900?°C to 960?°C and 9?±?1?eV for temperatures above 960?°C. The comparison of such dependence with the temperature dependence of Cu surface self-diffusion suggests that graphene growth at high temperatures and low pressures is strongly influenced by copper surface rearrangement. We propose a model that incorporates Cu surface self-diffusion as an essential process to explain the orientation correlation between graphene and Cu crystals, and which can clarify the difference generally observed between graphene domain shapes in atmospheric-pressure and low-pressure chemical vapor deposition.

  16. Sodium Titanates as Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01

    Anodes  for  Sodium  Ion  Batteries   Marca  M.  Doeff,  dual   intercalation   batteries   based   on   sodium  future   of   sodium  ion  batteries  will  be  discussed  

  17. Combining Feedback Absorption Spectroscopy, Amplified Resonance and Low Pressure Sampling for the Measurement of Nitrogen-Containing Compounds in Automotive Emissions

    Broader source: Energy.gov [DOE]

    Discusses a novel combination of multi-component scanning direct absorption spectroscopy, resonant cavity and low-pressure sampling to systematically improve the performance of a specific gas analyzer.

  18. Study of the relationship between indoor daylight environments and patient average length of stay (ALOS) in healthcare facilities 

    E-Print Network [OSTI]

    Choi, Joon Ho

    2007-04-25

    of indoor daylight variables in type A from 8:00 AM to 6:00 PM. ...........................................................97 xiii TABLE Page 36 Summary of the average values of indoor... daylight variables in type B from 8:00 AM to 6:00 PM.............................................................98 37 Significant ALOS comparisons and average illuminance between SE and NW...

  19. Monitored Energy Performance of Electrochromic Windows Controlledfor Daylight and Visual Comfort

    SciTech Connect (OSTI)

    Lee, Eleanor S.; DiBartolomeo, Dennis L.; Klems, Joseph; Yazdanian, Mehry; Selkowitz, Stephen E.

    2005-09-23

    A 20-month field study was conducted to measure the energy performance of south-facing large-area tungsten-oxide absorptive electrochromic (EC) windows with a broad switching range in a private office setting. The EC windows were controlled by a variety of means to bring in daylight while minimizing window glare. For some cases, a Venetian blind was coupled with the EC window to block direct sun. Some tests also involved dividing the EC window wall into zones where the upper EC zone was controlled to admit daylight while the lower zone was controlled to prevent glare yet permit view. If visual comfort requirements are addressed by EC control and Venetian blinds, a 2-zone EC window configuration provided average daily lighting energy savings of 10 {+-} 15% compared to the reference case with fully lowered Venetian blinds. Cooling load reductions were 0 {+-} 3%. If the reference case assumes no daylighting controls, lighting energy savings would be 44 {+-} 11%. Peak demand reductions due to window cooling load, given a critical demand-response mode, were 19-26% maximum on clear sunny days. Peak demand reductions in lighting energy use were 0% or 72-100% compared to a reference case with and without daylighting controls, respectively. Lighting energy use was found to be very sensitive to how glare and sun is controlled. Additional research should be conducted to fine-tune EC control for visual comfort based on solar conditions so as to increase lighting energy savings.

  20. A Concept for a Low Pressure Noble Gas Fill Intervention in the IFE Fusion Test Facility (FTF) Target Chamber

    SciTech Connect (OSTI)

    Gentile, C. A.; Blanchard, W. R.; Kozub, T. A.; Aristova, M.; McGahan, C.; Natta, S.; Pagdon, K.; Zelenty, J.

    2010-01-14

    An engineering evaluation has been initiated to investigate conceptual engineering methods for implementing a viable gas shield strategy in the Fusion Test Facility (FTF) target chamber. The employment of a low pressure noble gas in the target chamber to thermalize energetic helium ions prior to interaction with the wall could dramatically increase the useful life of the first wall in the FTF reactor1. For the purpose of providing flexibility, two target chamber configurations are addressed: a five meter radius sphere and a ten meter radius sphere. Experimental studies at Nike have indicated that a low pressure, ambient gas resident in the target chamber during laser pulsing does not appear to impair the ability of laser light from illuminating targets2. In addition, current investigations into delivering, maintaining, and processing low pressure gas appear to be viable with slight modification to current pumping and plasma exhaust processing technologies3,4. Employment of a gas fill solution for protecting the dry wall target chamber in the FTF may reduce, or possibly eliminate the need for other attenuating technologies designed for keeping He ions from implanting in first wall structures and components. The gas fill concept appears to provide an effective means of extending the life of the first wall while employing mostly commercial off the shelf (COTS) technologies. Although a gas fill configuration may provide a methodology for attenuating damage inflicted on chamber surfaces, issues associated with target injection need to be further analyzed to ensure that the gas fill concept is viable in the integrated FTF design5. In the proposed system, the ambient noble gas is heated via the energetic helium ions produced by target detonation. The gas is subsequently cooled by the chamber wall to approximately 800oC, removed from the chamber, and processed by the chamber gas processing system (CGPS). In an optimized scenario of the above stated concept, the chamber wall acts as the primary heat exchanger. During removal, gas is pumped through the laser ports by turbo molecular-drag pumps (TM-DP). For the purpose of reducing organic based lubricants and seals, a magnetically levitated TM-DP is being investigated with pump manufacturers. Currently, magnetically levitated turbo molecular pumps are commercially available. The pumps will be exposed to thermal loads and ionizing radiation (tritium, Ar-41, post detonation neutrons). Although the TM-DP's will be subjected to these various radiations, current designs for similar pumping devices have been hardened and have the ability of locating control electronics in remote radiation shielded enclosures4. The radiation hardened TM-DP's will be 5 required to operate with minimal maintenance for periods of up to 18 continuous months. As part of this initial investigation for developing a conceptual engineering strategy for a gas fill solution, commercial suppliers of low pressure gas pumping systems have been contacted and engaged in this evaluation. Current technology in the area of mechanical pumping systems indicates that the development of a robust pumping system to meet the requirements of the FTF gas fill concept is within the limits of COTS equipment3,4.

  1. Experimental investigation of supersonic low pressure air plasma flows obtained with different arc-jet operating conditions

    SciTech Connect (OSTI)

    Lago, Viviana; Ndiaye, Abdoul-Aziz

    2012-11-27

    A stationary arc-jet plasma flow at low pressure is used to simulate some properties of the gas flow surrounding a vehicle during its entry into celestial body's atmospheres. This paper presents an experimental study concerning plasmas simulating a re-entry into our planet. Optical measurements have been carried out for several operating plasma conditions in the free stream, and in the shock layer formed in front of a flat cylindrical plate, placed in the plasma jet. The analysis of the spectral radiation enabled the identification of the emitting species, the determination of the rotational and vibrational temperatures in the free-stream and in the shock layer and the determination of the distance of the shock to the flat plate face. Some plasma fluid parameters like, stagnation pressure, specific enthalpy and heat flux have been determined experimentally along the plasma-jet axis.

  2. Low pressure CO? hydrogenation to methanol over gold nanoparticles activated on a CeOx/TiO? interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Xiaofang; Boscoboinik, J. Anibal; Kattel, Shyam; Senanayake, Sanjaya D.; Nie, Xiaowa; Graciani, Jesus; Rodriguez, Jose A.; Liu, Ping; Stacchiola, Dario J.; Chen, Jingguang G.

    2015-07-28

    Capture and recycling of CO? into valuable chemicals such as alcohols could help mitigate its emissions into the atmosphere. Due to its inert nature, the activation of CO? is a critical step in improving the overall reaction kinetics during its chemical conversion. Although pure gold is an inert noble metal and cannot catalyze hydrogenation reactions, it can be activated when deposited as nanoparticles on the appropriate oxide support. In this combined experimental and theoretical study, it is shown that an electronic polarization at the metal–oxide interface of Au nanoparticles anchored and stabilized on a CeOx/TiO? substrate generates active centers formore »CO? adsorption and its low pressure hydrogenation, leading to a higher selectivity toward methanol. In conclusion, this study illustrates the importance of localized electronic properties and structure in catalysis for achieving higher alcohol selectivity from CO? hydrogenation.« less

  3. Modelling for post-dryout heat transfer and droplet sizes at low pressure and low flow conditions

    SciTech Connect (OSTI)

    Jeong, H.Y.; No, H.C. [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Nuclear Engineering] [Korea Advanced Inst. of Science and Technology, Taejon (Korea, Republic of). Dept. of Nuclear Engineering

    1996-10-01

    A correlation describing the initial droplet size just after the CHF position at low mass flux is suggested through regression analysis. The history-dependent post-dryout model of Varone and Rohsenow replaced by the Webb-Chen model for wall-vapor heat transfer is used as a reference model in the analysis. In the post-dryout region at low pressure and low flow, it is found that the suggested one-dimensional mechanistic model is valid only in the churn-turbulent flow regime (j*{sub g} = 0.5 {approximately} 4.5). It is also suggested that the droplet size generated from the churn-turbulent surface is dependent not only on the pressure but also on the vapor velocity. It turns out that the present model can predict the measured cladding and vapor temperatures within 20% and 15%, respectively.

  4. Low pressure hydrocyclone separator

    SciTech Connect (OSTI)

    Flanigan, D.A.; Stolhand, J.E.

    1989-07-04

    This patent describes a method of separating a dispersed phase liquid from a bulk phase liquid of a liquid-liquid mixture, the dispersed phase and bulk phase liquids having different densities. The method comprises the steps of: providing a supply of the liquid-liquid mixture at a first pressure; providing a pump means including means for minimizing degradation of the volumetric means size of droplets of the dispersed phase further including a pump size for maintaining the pump means at substantially near maximum flow rate capacity; pumping the liquid-liquid mixture with at least one pump means to a second pressure such that a differential between the first and second pressures is not substantially greater than a differential pressure at which the pump means begins to substantially degrade the volumetric mean size of droplets of the dispersed phase liquid passing therethrough, the pumping without substantial droplet degradation being achieved by operating the pump means at relatively near its maximum flow rate capacity to substantially reduce on a percentage basis the effect of fluid slippage within the pump means; directing the liquid-liquid mixture from the pump means to a hydrocyclone; and separating a substantial portion of the dispersed phase liquid from the liquid-liquid mixture in the hydrocyclone.

  5. Acceleration of the matrix multiplication of Radiance three phase daylighting simulations with parallel computing on heterogeneous hardware of personal computer

    SciTech Connect (OSTI)

    University of Miami; Zuo, Wangda; McNeil, Andrew; Wetter, Michael; Lee, Eleanor S.

    2013-04-30

    Building designers are increasingly relying on complex fenestration systems to reduce energy consumed for lighting and HVAC in low energy buildings. Radiance, a lighting simulation program, has been used to conduct daylighting simulations for complex fenestration systems. Depending on the configurations, the simulation can take hours or even days using a personal computer. This paper describes how to accelerate the matrix multiplication portion of a Radiance three-phase daylight simulation by conducting parallel computing on heterogeneous hardware of a personal computer. The algorithm was optimized and the computational part was implemented in parallel using OpenCL. The speed of new approach was evaluated using various daylighting simulation cases on a multicore central processing unit and a graphics processing unit. Based on the measurements and analysis of the time usage for the Radiance daylighting simulation, further speedups can be achieved by using fast I/O devices and storing the data in a binary format.

  6. Space, light, and time : prospective analysis of Circadian illumination for health-based daylighting with applications to healthcare architecture

    E-Print Network [OSTI]

    Pechacek, Christopher S. (Christopher Scott)

    2008-01-01

    Light in architecture can be studied for its objective or perceptual effects. This thesis describes an objective link between human health and architectural design. Specifically, the link between daylight and human circadian ...

  7. Solid oxide fuel cell electrolytes produced by a combination of suspension plasma spray and very low pressure plasma spray.

    SciTech Connect (OSTI)

    Slamovich, Elliot (Purdue University, West Lafayette, IN); Fleetwood, James (Purdue University, West Lafayette, IN); McCloskey, James F.; Hall, Aaron Christopher; Trice, Rodney Wayne (Purdue University, West Lafayette, IN)

    2010-07-01

    Plasma spray coating techniques allow unique control of electrolyte microstructures and properties as well as facilitating deposition on complex surfaces. This can enable significantly improved solid oxide fuel cells (SOFCs), including non-planar designs. SOFCs are promising because they directly convert the oxidization of fuel into electrical energy. However, electrolytes deposited using conventional plasma spray are porous and often greater than 50 microns thick. One solution to form dense, thin electrolytes of ideal composition for SOFCs is to combine suspension plasma spray (SPS) with very low pressure plasma spray (VLPPS). Increased compositional control is achieved due to dissolved dopant compounds in the suspension that are incorporated into the coating during plasma spraying. Thus, it is possible to change the chemistry of the feed stock during deposition. In the work reported, suspensions of sub-micron diameter 8 mol.% Y2O3-ZrO2 (YSZ) powders were sprayed on NiO-YSZ anodes at Sandia National Laboratories (SNL) Thermal Spray Research Laboratory (TSRL). These coatings were compared to the same suspensions doped with scandium nitrate at 3 to 8 mol%. The pressure in the chamber was 2.4 torr and the plasma was formed from a combination of argon and hydrogen gases. The resultant electrolytes were well adhered to the anode substrates and were approximately 10 microns thick. The microstructure of the resultant electrolytes will be reported as well as the electrolyte performance as part of a SOFC system via potentiodynamic testing and impedance spectroscopy.

  8. Collisional kinetics of non-uniform electric field, low-pressure, direct-current discharges in H$_{2}$

    E-Print Network [OSTI]

    Phelps, A V

    2010-01-01

    A model of the collisional kinetics of energetic hydrogen atoms, molecules, and ions in pure H$_2$ discharges is used to predict H$_\\alpha$ emission profiles and spatial distributions of emission from the cathode regions of low-pressure, weakly-ionized discharges for comparison with a wide variety of experiments. Positive and negative ion energy distributions are also predicted. The model developed for spatially uniform electric fields and current densities less than $10^{-3}$ A/m$^2$ is extended to non-uniform electric fields, current densities of $10^{3}$ A/m$^2$, and electric field to gas density ratios $E/N = 1.3$ MTd at 0.002 to 5 Torr pressure. (1 Td = $10^{-21}$ V m$^2$ and 1 Torr = 133 Pa) The observed far-wing Doppler broadening and spatial distribution of the H$_\\alpha$ emission is consistent with reactions among H$^+$, H$_2^+$, H$_3^+$, and H$^-H$ ions, fast H atoms, and fast H$_2$ molecules, and with reflection, excitation, and attachment to fast H atoms at surfaces. The H$_\\alpha$ excitation and ...

  9. Experimental and numerical investigations of electron density in low-pressure dual-frequency capacitively coupled oxygen discharges

    SciTech Connect (OSTI)

    Liu, Jia; Wen, De-Qi; Liu, Yong-Xin; Gao, Fei; Lu, Wen-Qi; Wang, You-Nian [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2013-11-15

    The electron density is measured in low-pressure dual-frequency (2/60 MHz) capacitively coupled oxygen discharges by utilizing a floating hairpin probe. The dependence of electron density at the discharge center on the high frequency (HF) power, low frequency (LF) power, and gas pressure are investigated in detail. A (1D) particle-in-cell/Monte Carlo method is developed to calculate the time-averaged electron density at the discharge center and the simulation results are compared with the experimental ones, and general agreements are achieved. With increasing HF power, the electron density linearly increases. The electron density exhibits different changes with the LF power at different HF powers. At low HF powers (e.g., 30 W in our experiment), the electron density increases with increasing LF power while the electron density decreases with increasing LF power at relatively high HF powers (e.g., 120 W in our experiment). With increasing gas pressure the electron density first increases rapidly to reach a maximum value and then decreases slowly due to the combined effect of the production process by the ionization and the loss processes including the surface and volume losses.

  10. Numerical study of effect of secondary electron emission on discharge characteristics in low pressure capacitive RF argon discharge

    SciTech Connect (OSTI)

    Liu, Qian; Liu, Yue, E-mail: liuyue@dlut.edu.cn; Samir, Tagra; Ma, Zhaoshuai [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Ministry of Education, School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)

    2014-08-15

    Based on the drift and diffusion approximation theory, a 1D fluid model on capacitively coupled RF argon glow discharge at low pressure is established to study the effect of secondary electron emission (SEE) on the discharge characteristics. The model is numerically solved by using a finite difference method and the numerical results are obtained. The numerical results indicate that when the SEE coefficient is larger, the plasma density is higher and the time of reaching steady state is longer. It is also found that the cycle-averaged electric field, electric potential, and electron temperature change a little as the SEE coefficient is increased. Moreover, the discharge characteristics in some nonequilibrium discharge processes with different SEE coefficients have been compared. The analysis shows that when the SEE coefficient is varied from 0.01 to 0.3, the cycle-averaged electron net power absorption, electron heating rate, thermal convective term, electron energy dissipation, and ionization all have different degrees of growth. While the electron energy dissipation and ionization are quite special, there appear two peaks near each sheath region in the discharge with a relatively larger SEE coefficient. In this case, the discharge is certainly operated in a hybrid ?-?-mode.

  11. An Analysis of Energy Reductions from the Use of Daylighting in Low-Cost Housing 

    E-Print Network [OSTI]

    Rungchareonrat, N.

    2003-01-01

    .39 Global horizontal, direct normal and diffuse solar radiation from Houston TMY2 weather tape of March 21…………………………………………………………….. 130 4.40 Exterior horizontal illuminance from clear, overcast portion of the sky, and from direct sun of March 21....3.3. The Simulation of the Basecase Model: Multi-zone Model with an Attic Zone with Daylighting Controls………………………………… 64 3.3.4. Solar Radiation and Exterior Horizontal Illuminance Data from the Houston TMY2 Weather Tape...

  12. Minimizing lighting power density in office rooms equipped with Anidolic Daylighting Systems

    SciTech Connect (OSTI)

    Linhart, Friedrich; Scartezzini, Jean-Louis [Solar Energy and Building Physics Laboratory (LESO-PB), Ecole Polytechnique Federale de Lausanne (EPFL), 1015 Lausanne (Switzerland)

    2010-04-15

    Electric lighting is responsible for up to one third of an office building's electricity needs. Making daylight more available in office buildings can not only contribute to significant energy savings but also enhance the occupants' performance and wellbeing. Anidolic Daylighting Systems (ADS) are one type of very effective facade-integrated daylighting systems. All south-facing office rooms within the LESO solar experimental building in Lausanne (Switzerland) are equipped with a given type of ADS. A recent study has shown that these offices' occupants are highly satisfied with their lighting environment. The most energy-efficient south-facing offices have a lighting power density of less than 5W/m{sup 2}. The lighting situation within these ''best practice''-offices has been assessed using the lighting simulation software RELUX Vision. Because this lighting situation is very much appreciated by the occupants, it was used as a starting point for developing even more energy-efficient office lighting designs. Two new lighting designs, leading to lighting power densities of 3.9W/m{sup 2} and 3W/m{sup 2}, respectively, have been suggested and simulated with RELUX Vision. Simulation results have shown that the expected performances of these new systems are comparable to that of the current lighting installation within the ''best practice''-offices or even better. These simulation results have been confirmed during experiments on 20 human subjects in a test office room recently set up within the LESO building. This article gives engineers, architects and light planers valuable information and ideas on how to design energy-efficient and comfortable electric lighting systems in office rooms with abundant access to daylight. (author)

  13. Gasoline from coal in the state of Illinois: feasibility study. Volume I. Design. [KBW gasification process, ICI low-pressure methanol process and Mobil M-gasoline process

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Volume 1 describes the proposed plant: KBW gasification process, ICI low-pressure methanol process and Mobil M-gasoline process, and also with ancillary processes, such as oxygen plant, shift process, RECTISOL purification process, sulfur recovery equipment and pollution control equipment. Numerous engineering diagrams are included. (LTN)

  14. Surface roughening in low-pressure chemical vapor deposition Jason T. Drotar, Y.-P. Zhao, T.-M. Lu, and G.-C. Wang

    E-Print Network [OSTI]

    Wang, Gwo-Ching

    Surface roughening in low-pressure chemical vapor deposition Jason T. Drotar, Y.-P. Zhao, T.-M. Lu etching, the pressure is usually low enough so that the mean free path of the vapor particles is much of a reemission model for chemical vapor deposition. We find that, for pure first-order reemission, the interface

  15. Laboratory tests to evaluate and study formation damage with low-density drill-in fluids (LDDIF) for horizontal well completions in low pressure and depleted reservoirs 

    E-Print Network [OSTI]

    Chen, Guoqiang

    2002-01-01

    The increasing number of open hole horizontal well completions in low-pressure and depleted reservoirs requires the use of non-damaging low-density drill-in fluids (LDDIF) to avoid formation damage and realize optimum well productivity. To address...

  16. Experimental investigation on the flow instability behavior of a multi-channel boiling natural circulation loop at low-pressures

    SciTech Connect (OSTI)

    Jain, Vikas; Nayak, A.K.; Vijayan, P.K.; Saha, D.; Sinha, R.K.

    2010-09-15

    Natural circulation as a mode of heat removal is being considered as a prominent passive feature in the innovative nuclear reactor designs, particularly in boiling-water-reactors, due to its simplicity and economy. However, boiling natural circulation system poses many challenges to designer due to occurrence of various kinds of instabilities such as excursive instability, density wave oscillations, flow pattern transition instability, geysering and metastable states in parallel channels. This problem assumes greater significance particularly at low-pressures i.e. during startup, where there is great difference in the properties of two phases. In light of this, a parallel channel loop has been designed and installed that has a geometrical resemblance to the pressure-tube-type boiling-water-reactor, to investigate into the behavior of boiling natural circulation. The loop comprises of four identical parallel channels connected between two common plenums i.e. steam drum and header. The recirculation path is provided by a single downcomer connected between steam drum and header. Experiments have been conducted over a wide range of power and pressures (1-10 bar). Two distinct unstable zones are observed with respect to power i.e. corresponding to low power (Type-I) and high power (Type-II) with a stable zone at intermediate powers. The nature of oscillations in terms of their amplitude and frequency and their evolution for Type-I and Type-II instabilities are studied with respect to the effect of heater power and pressure. This paper discusses the evolution of unstable and stable behavior along with the nature of flow oscillation in the channels and the effect of pressure on it. (author)

  17. Investigation of effect of excitation frequency on electron energy distribution functions in low pressure radio frequency bounded plasmas

    SciTech Connect (OSTI)

    Bhattacharjee, Sudeep [Space plasma, Power and Propulsion, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia); Department of Physics, Indian Institute of Technology, Kanpur 208 016 (India); Lafleur, Trevor; Charles, Christine; Boswell, Rod [Space plasma, Power and Propulsion, Research School of Physics and Engineering, Australian National University, Canberra ACT 0200 (Australia)

    2011-07-15

    Particle in cell (PIC) simulations are employed to investigate the effect of excitation frequency {omega} on electron energy distribution functions (EEDFs) in a low pressure radio frequency (rf) discharge. The discharge is maintained over a length of 0.10 m, bounded by two infinite parallel plates, with the coherent heating field localized at the center of the discharge over a distance of 0.05 m and applied perpendicularly along the y and z directions. On varying the excitation frequency f (={omega}/2{pi}) in the range 0.01-50 MHz, it is observed that for f {<=} 5 MHz the EEDF shows a trend toward a convex (Druyvesteyn-like) distribution. For f > 5 MHz, the distribution resembles more like a Maxwellian with the familiar break energy visible in most of the distributions. A prominent ''hot tail'' is observed at f{>=} 20 MHz and the temperature of the tail is seen to decrease with further increase in frequency (e.g., at 30 MHz and 50 MHz). The mechanism for the generation of the ''hot tail'' is considered to be due to preferential transit time heating of energetic electrons as a function of {omega}, in the antenna heating field. There exists an optimum frequency for which high energy electrons are maximally heated. The occurrence of the Druyvesteyn-like distributions at lower {omega} may be explained by a balance between the heating of the electrons in the effective electric field and elastic cooling due to electron neutral collision frequency {nu}{sub en}; the transition being dictated by {omega} {approx} 2{pi}{nu}{sub en}.

  18. Submersible sodium pump

    DOE Patents [OSTI]

    Brynsvold, G.V.; Lopez, J.T.; Olich, E.E.; West, C.W.

    1989-11-21

    An electromagnetic submerged pump has an outer cylindrical stator with an inner cylindrical conductive core for the submerged pumping of sodium in the cylindrical interstitial volume defined between the stator and core. The cylindrical interstitial volume is typically vertically oriented, and defines an inlet at the bottom and an outlet at the top. The outer stator generates upwardly conveyed toroidal magnetic fields, which fields convey preferably from the bottom of the pump to the top of the pump liquid sodium in the cold leg of a sodium cooled nuclear reactor. The outer cylindrical stator has a vertically disposed duct surrounded by alternately stacked layers of coil units and laminates. 14 figs.

  19. On the Use of Integrated Daylighting and Energy Simulations to Drive the Design of a Large Net-Zero Energy Office Building: Preprint

    SciTech Connect (OSTI)

    Guglielmetti, R.; Pless, S.; Torcellini, P.

    2010-08-01

    This paper illustrates the challenges of integrating rigorous daylight and electric lighting simulation data with whole-building energy models, and defends the need for such integration to achieve aggressive energy savings. Through a case study example, we examine the ways daylighting -- and daylighting simulation -- drove the design of a large net-zero energy project. We give a detailed review of the daylighting and electric lighting design process for the National Renewable Energy Laboratory's Research Support Facility (RSF), a 220,000 ft2 net-zero energy project the author worked on as a daylighting consultant. A review of the issues involved in simulating and validating the daylighting performance of the RSF will be detailed, including daylighting simulation, electric lighting control response, and integration of Radiance simulation data into the building energy model. Daylighting was a key strategy in reaching the contractual energy use goals for the RSF project; the building's program, layout, orientation and interior/furniture design were all influenced by the daylighting design, and simulation was critical in ensuring these many design components worked together in an integrated fashion, and would perform as required to meet a very aggressive energy performance goal, as expressed in a target energy use intensity.

  20. VOLUME 87, NUMBER 13 P H Y S I C A L R E V I E W L E T T E R S 24 SEPTEMBER 2001 Morphology Transition during Low-Pressure Chemical Vapor Deposition

    E-Print Network [OSTI]

    Wang, Gwo-Ching

    Transition during Low-Pressure Chemical Vapor Deposition Y.-P. Zhao, Jason T. Drotar, G.-C. Wang, and T have studied, in detail, the effect of sticking coefficient on the morphology evolution in low-pressure chemical vapor deposition processes. We have shown that the surface morphology changes from a self

  1. HOx radical chemistry in oxidation flow reactors with low-pressure mercury lamps systematically examined by modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peng, Z.; Day, D. A.; Stark, H.; Li, R.; Palm, B. B.; Brune, W. H.; Jimenez, J. L.

    2015-04-20

    Oxidation flow reactors (OFRs) using OH produced from low-pressure Hg lamps at 254 nm (OFR254) or both 185 and 254 nm (OFR185) are commonly used in atmospheric chemistry and other fields. OFR254 requires the addition of externally formed O3 since OH is formed from O3 photolysis, while OFR185 does not since O2 can be photolyzed to produce O3 and OH can also be formed from H2O photolysis. In this study, we use a plug-flow kinetic model to investigate OFR properties under a very wide range of conditions applicable to both field and laboratory studies. We show that the radical chemistrymore »in OFRs can be characterized as a function of UV light intensity, H2O concentration, and total external OH reactivity (OHRext, e.g., from VOCs, NOx, and SO2). OH exposure is decreased by added external OH reactivity. OFR185 is especially sensitive to this effect at low UV intensity due to low primary OH production. OFR254 can be more resilient against OH suppression at high injected O3 (e.g., 70 ppm), as a larger primary OH source from O3, as well as enhanced recycling of HO2 to OH, make external perturbations to the radical chemistry less significant. However if the external OH reactivity in OFR254 is much larger than OH reactivity from injected O3, OH suppression can reach two orders of magnitude. For a typical input of 7 ppm O3 (OHRO3 = 10 s?1) ten-fold OH suppression is observed at OHRext ? 100 s?1, which is similar or lower than used in many laboratory studies. This finding may have important implications for the interpretation of past laboratory studies, as applying OHexp measurements acquired under different conditions could lead to over an order-of-magnitude error in the estimated OHexp. The uncertainties of key model outputs due to uncertainty in all rate constants and absorption cross-sections in the model are within ± 25% for OH exposure and within ± 60% for other parameters. These uncertainties are small relative to the dynamic range of outputs. Uncertainty analysis shows that most of the uncertainty is contributed by photolysis rates of O3, O2, and H2O and reactions of OH and HO2 with themselves or with some abundant species, i.e., O3 and H2O2. Using HOx-recycling vs. destructive external OH reactivity only leads to small changes in OHexp under most conditions. Changing the identity (rate constant) of external OH reactants can result in substantial changes in OHexp due to different reductions in OH suppression as the reactant is consumed. We also report two equations for estimating OH exposure in OFR254. We find that the equation estimating OHexp from measured O3 consumption performs better than an alternative equation that does not use it, and thus recommend measuring both input and output O3 concentrations in OFR254 experiments. This study contributes to establishing a firm and systematic understanding of the gas-phase HOx and Ox chemistry in these reactors, and enables better experiment planning and interpretation as well as improved design of future reactors.« less

  2. Empirical assessment of a prismatic daylight-redirecting window film in a full-scale office testbed

    SciTech Connect (OSTI)

    Thanachareonkit, Anothai; Lee, Eleanor S.; McNeil, Andrew

    2013-08-31

    Daylight redirecting systems with vertical windows have the potential to offset lighting energy use in deep perimeter zones. Microstructured prismatic window films can be manufactured using low-cost, roll-to-roll fabrication methods and adhered to the inside surface of existing windows as a retrofit measure or installed as a replacement insulating glass unit in the clerestory portion of the window wall. A clear film patterned with linear, 50-250 micrometer high, four-sided asymmetrical prisms was fabricated and installed in the south-facing, clerestory low-e, clear glazed windows of a full-scale testbed facility. Views through the film were distorted. The film was evaluated in a sunny climate over a two-year period to gauge daylighting and visual comfort performance. The daylighting aperture was small (window-towall ratio of 0.18) and the lower windows were blocked off to isolate the evaluation to the window film. Workplane illuminance measurements were made in the 4.6 m (15 ft) deep room furnished as a private office. Analysis of discomfort glare was conducted using high dynamic range imaging coupled with the evalglare software tool, which computes the daylight glare probability and other metrics used to evaluate visual discomfort. The window film was found to result in perceptible levels of discomfort glare on clear sunny days from the most conservative view point in the rear of the room looking toward the window. Daylight illuminance levels at the rear of the room were significantly increased above the reference window condition, which was defined as the same glazed clerestory window but with an interior Venetian blind (slat angle set to the cut-off angle), for the equinox to winter solstice period on clear sunny days. For partly cloudy and overcast sky conditions, daylight levels were improved slightly. To reduce glare, the daylighting film was coupled with a diffusing film in an insulating glazing unit. The diffusing film retained the directionality of the redirected light spreading it within a small range of outgoing angles. This solution was found to reduce glare to imperceptible levels while retaining for the most part the illuminance levels achieved solely by the daylighting film.

  3. The Sodium-Restricted Diet 

    E-Print Network [OSTI]

    Anonymous,

    1979-01-01

    the body of excess sodium and water. When certain diuretics are used, the doctor may suggest including foods in the diet which are high in potassium but low in sodium. This is to counteract the diuretic's side-effect of washing out the body's potassium...-sodium dietetic ./ Group C Cheese, Eggs, Nuts Cheese, cottage, unsalted Cheese, processed low-sodium dietetic Egg (limit 1 per day only) Peanut butter, low-sodium dietetic AVOID Cheese, except low-sodium dietetic Fish fillets, frozen Fish, canned...

  4. Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01

    Anodes for Sodium Ion Batteries Identification of a suitabledevelopment of sodium ion batteries, because graphite, theanode for lithium ion batteries, does not undergo sodium

  5. HOx radical chemistry in oxidation flow reactors with low-pressure mercury lamps systematically examined by modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peng, Z.; Day, D. A.; Stark, H.; Li, R.; Lee-Taylor, J.; Palm, B. B.; Brune, W. H.; Jimenez, J. L.

    2015-11-20

    Oxidation flow reactors (OFRs) using OH produced from low-pressure Hg lamps at 254 nm (OFR254) or both 185 and 254 nm (OFR185) are commonly used in atmospheric chemistry and other fields. OFR254 requires the addition of externally formed O3 since OH is formed from O3 photolysis, while OFR185 does not since O2 can be photolyzed to produce O3, and OH can also be formed from H2O photolysis. In this study, we use a plug-flow kinetic model to investigate OFR properties under a very wide range of conditions applicable to both field and laboratory studies. We show that the radical chemistrymore »in OFRs can be characterized as a function of UV light intensity, H2O concentration, and total external OH reactivity (OHRext, e.g., from volatile organic compounds (VOCs), NOx, and SO2). OH exposure is decreased by added external OH reactivity. OFR185 is especially sensitive to this effect at low UV intensity due to low primary OH production. OFR254 can be more resilient against OH suppression at high injected O3 (e.g., 70 ppm), as a larger primary OH source from O3, as well as enhanced recycling of HO2 to OH, make external perturbations to the radical chemistry less significant. However if the external OH reactivity in OFR254 is much larger than OH reactivity from injected O3, OH suppression can reach 2 orders of magnitude. For a typical input of 7 ppm O3 (OHRO3 = 10 s?1), 10-fold OH suppression is observed at OHRext ~ 100 s?1, which is similar or lower than used in many laboratory studies. The range of modeled OH suppression for literature experiments is consistent with the measured values except for those with isoprene. The finding on OH suppression may have important implications for the interpretation of past laboratory studies, as applying OHexp measurements acquired under different conditions could lead to over a 1-order-of-magnitude error in the estimated OHexp. The uncertainties of key model outputs due to uncertainty in all rate constants and absorption cross-sections in the model are within ±25 % for OH exposure and within ±60 % for other parameters. These uncertainties are small relative to the dynamic range of outputs. Uncertainty analysis shows that most of the uncertainty is contributed by photolysis rates of O3, O2, and H2O and reactions of OH and HO2 with themselves or with some abundant species, i.e., O3 and H2O2. OHexp calculated from direct integration and estimated from SO2 decay in the model with laminar and measured residence time distributions (RTDs) are generally within a factor of 2 from the plug-flow OHexp. However, in the models with RTDs, OHexp estimated from SO2 is systematically lower than directly integrated OHexp in the case of significant SO2 consumption. We thus recommended using OHexp estimated from the decay of the species under study when possible, to obtain the most appropriate information on photochemical aging in the OFR. Using HOx-recycling vs. destructive external OH reactivity only leads to small changes in OHexp under most conditions. Changing the identity (rate constant) of external OH reactants can result in substantial changes in OHexp due to different reductions in OH suppression as the reactant is consumed. We also report two equations for estimating OH exposure in OFR254. We find that the equation estimating OHexp from measured O3 consumption performs better than an alternative equation that does not use it, and thus recommend measuring both input and output O3 concentrations in OFR254 experiments. This study contributes to establishing a firm and systematic understanding of the gas-phase HOx and Ox chemistry in these reactors, and enables better experiment planning and interpretation as well as improved design of future reactors.« less

  6. Daylighting: Measuring the Performance of Light Shelves and Occupant-Controlled Blinds on a Dimmed Lighting Systems 

    E-Print Network [OSTI]

    Floyd, D. B.; Parker, D. S.

    1998-01-01

    , and poor shading devices (such as opaque blinds). References Floyd, D. B. and D. S. Parker. 1995. "Feld Commissioning of a Daylight-Dimming Lighting System", Proceedings of the 3d European Conference on Energy-Efficient Lighting, pp. 83- 89...

  7. Comparison of MELCOR and SCDAP/RELAP5 results for a low-pressure, short-term station blackout at Browns Ferry

    SciTech Connect (OSTI)

    Carbajo, J.J. [Oak Ridge National Lab., TN (United States)

    1995-12-31

    This study compares results obtained with two U.S. Nuclear Regulatory Commission (NRC)-sponsored codes, MELCOR version 1.8.3 (1.8PQ) and SCDAP/RELAP5 Mod3.1 release C, for the same transient - a low-pressure, short-term station blackout accident at the Browns Ferry nuclear plant. This work is part of MELCOR assessment activities to compare core damage progression calculations of MELCOR against SCDAP/RELAP5 since the two codes model core damage progression very differently.

  8. Economic analysis of the daylight-linked lighting control system in office buildings

    SciTech Connect (OSTI)

    Yang, In-Ho; Nam, Eun-Ji [Department of Architectural Engineering, College of Engineering, Dongguk University, 26-3, Pil-dong, Chung-gu, Seoul 100-715 (Korea)

    2010-08-15

    The objective of this study is to perform an economic analysis of the daylight-linked automatic on/off lighting control system installed for the purpose of energy savings in office buildings. For this, a building was chosen as a typical example, and the energy cost was calculated by using the daylight and building energy analysis simulation. When the lighting control was utilized, an economic analysis was performed using a payback period that was calculated by comparing the initial cost of installing the lighting control system with the annual energy cost which was reduced thanks to the application of the lighting control. The results showed that the lighting energy consumption, when the lighting control was applied, was reduced by an average of 30.5% compared with the case that there was not lighting control applied. Also, the result for total energy consumption showed that, when lighting control was applied, this was reduced by 8.5% when the glazing ratio was 100%, 8.2% for 80%, and 7.6% for 60% when compared to non-application. The payback period was analyzed in terms of the number of floors in a building; 10 floors, 20 floors, 30 floors, and 40 floors. Hence, the building with 40 floors and glazing ratio 100% resulted in the shortest payback period of 8.8 years, the building with 10 floors and glazing ratio 60% resulted in the longest period of 12.7 years. In other words, the larger the glazing ratio and the number of building floors are, the shorter the payback period is. (author)

  9. The use of daylight in the design of a controlled environment for food production in the Caribbean and other equatorial climates

    E-Print Network [OSTI]

    Charles, Curtis B

    1989-01-01

    This thesis addresses the use of daylight in the design of a controlled environment for food production in the Caribbean and other Equatorial climates. An expanding population has put a tremendous burden on the food ...

  10. Identification of combustion intermediates in a low-pressure premixed laminar 2,5-dimethylfuran/oxygen/argon flame with tunable synchrotron photoionization

    SciTech Connect (OSTI)

    Wu, Xuesong; Huang, Zuohua; Wei, Lixia [State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an 710049 (China); Yuan, Tao; Zhang, Kuiwen [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China)

    2009-07-15

    Low-pressure (4.0 kPa) premixed laminar 2,5-dimethylfuran (DMF)/oxygen/argon flame with an equivalence ratio of 2.0 was studied with tunable vacuum ultraviolet (VUV) synchrotron radiation photoionization and molecular-beam mass spectrometry. Photoionization mass spectra of DMF/O{sub 2}/Ar flame were recorded and the photoionization efficiency curves of the combustion intermediates were measured. Flame species, including isomeric intermediates, are identified by comparing the measured ionization energies with those reported in literatures or those calculated with Gaussian-3 procedure. More than 70 species have been detected, including furan and its derivatives, aromatics, and free radicals. Possible reaction pathways of DMF, 2-methylfuran, and furan are proposed based on the intermediates identified. DMF can be consumed by H-abstraction and pyrolysis reactions. 2-Methylfuran and furan can be consumed by H-abstraction, H-addition and pyrolysis reactions. (author)

  11. Containment failure time and mode for a low-pressure short-term station blackout in a BWR-4 with Mark-I containment

    SciTech Connect (OSTI)

    Carbajo, J.J.; Greene, S.R. (Oak Ridge National Lab., TN (United States))

    1993-01-01

    This study investigates containment failure time and mode for a low-pressure, short-term station blackout severe accident sequence in a boiling water reactor (BWR-4) with a Mark-I containment. The severe accident analysis code MELCOR, version 1.8.1, was used in these calculations. Other results using the MELCOR/CORBH package and the BWRSAR and CONTAIN codes are also presented and compared to the MELCOR results. The plant analyzed is the Peach Bottom atomic station, a BWR-4 with a Mark-I containment. The automatic depressurization system was used to depressurize the vessel in accordance with the Emergency Procedure Guidelines. Two different variations of the station blackout were studied: one with a dry cavity and the other with a flooded cavity. For the flooded cavity, it is assumed that a control rod drive (CRD) pump becomes operational after vessel failure, and it is used to pump water into the cavity.

  12. Roof aperture system for selective collection and control of solar energy for building heating, cooling and daylighting

    DOE Patents [OSTI]

    Sanders, William J. (Kansas City, KS); Snyder, Marvin K. (Overland Park, KS); Harter, James W. (Independence, MO)

    1983-01-01

    The amount of building heating, cooling and daylighting is controlled by at least one pair of solar energy passing panels, with each panel of the pair of panels being exposed to a separate direction of sun incidence. A shutter-shade combination is associated with each pair of panels and the shutter is connected to the shade so that rectilinear movement of the shutter causes pivotal movement of the shade.

  13. Roof aperture system for selective collection and control of solar energy for building heating, cooling and daylighting

    SciTech Connect (OSTI)

    Sanders, W.J.; Harter, J.W.; Snyder, M.K.

    1983-12-06

    The amount of building heating, cooling and daylighting is controlled by at least one pair of solar energy passing panels, with each panel of the pair of panels being exposed to a separate direction of sun incidence. A shutter-shade combination is associated with each pair of panels and the shutter is connected to the shade so that rectilinear movement of the shutter causes pivotal movement of the shade.

  14. Study of metallic powder behavior in very low pressure plasma spraying (VLPPS) — Application to the manufacturing of titanium–aluminum coatings

    SciTech Connect (OSTI)

    Vautherin, B.; Planche, M.-P.; Montavon, G.; Lapostolle, F.; Quet, A.; Bianchi, L.

    2015-08-28

    In this study, metallic materials made of aluminum and titanium were manufactured implementing very low pressure plasma spraying (VLPPS). Aluminum was selected at first as a demonstrative material due to its rather low vaporization enthalpy (i.e., 381.9 kJ·mol?¹). Developments were then carried out with titanium which exhibits a higher vaporization enthalpy (i.e., 563.6 kJ·mol?¹). Optical emission spectroscopy (OES) was implemented to analyze the behavior of each solid precursor (metallic powders) when it is injected into the plasma jet under very low pressure (i.e., in the 150 Pa range). Besides, aluminum, titanium and titanium–aluminum coatings were deposited in the same conditions implementing a stick-cathode plasma torch operated at 50 kW, maximum power. Coating phase compositions were identified by X-Ray Diffraction (XRD). Coating elementary compositions were quantified by Glow Discharge Optical Emission Spectroscopy (GDOES) and Energy Dispersive Spectroscopy (EDS) analyses. The coating structures were observed by Scanning Electron Microscopy (SEM). The coating void content was determined by Ultra-Small Angle X-ray Scattering (USAXS). The coatings exhibit a two-scale structure corresponding to condensed vapors (smaller scale) and solidified areas (larger scale). Titanium–aluminum sprayed coatings, with various Ti/Al atomic ratios, are constituted of three phases: metastable ?-Ti, Al and metastable ??-Ti?Al. This latter is formed at elevated temperature in the plasma flow, before being condensed. Its rather small fraction, impeded by the rather small amount of vaporized Ti, does not allow modifying however the coating hardness.

  15. Energy Use Intensity and its Influence on the Integrated Daylighting Design of a Large Net Zero Energy Building: Preprint

    SciTech Connect (OSTI)

    Guglielmetti , R.; Scheib, J.; Pless, S. D.; Torcellini , P.; Petro, R.

    2011-03-01

    Net-zero energy buildings generate as much energy as they consume and are significant in the sustainable future of building design and construction. The role of daylighting (and its simulation) in the design process becomes critical. In this paper we present the process the National Renewable Energy Laboratory embarked on in the procurement, design, and construction of its newest building, the Research Support Facility (RSF) - particularly the roles of daylighting, electric lighting, and simulation. With a rapid construction schedule, the procurement, design, and construction had to be tightly integrated; with low energy use. We outline the process and measures required to manage a building design that could expect to operate at an efficiency previously unheard of for a building of this type, size, and density. Rigorous simulation of the daylighting and the electric lighting control response was a given, but the oft-ignored disconnect between lighting simulation and whole-building energy use simulation had to be addressed. The RSF project will be thoroughly evaluated for its performance for one year; preliminary data from the postoccupancy monitoring efforts will also be presented with an eye toward the current efficacy of building energy and lighting simulation.

  16. Processing of Sodium-Potassium Niobate Ceramics

    E-Print Network [OSTI]

    Power Jr., Bob R.

    1971-01-01

    SODIUM-POTASSIUM NIOBATE CERAMICS Bob R. Powell, Jr. (M.S.OF SODIUM-POTASSIUM NIOBATE CERAMICS Index Page ABSTRACT ofOF SODIUM-POTASSIUM NIOBATE CERAMICS Bob R. Powell, Jr.

  17. Tables of thermodynamic properties of sodium

    SciTech Connect (OSTI)

    Fink, J.K.

    1982-06-01

    The thermodynamic properties of saturated sodium, superheated sodium, and subcooled sodium are tabulated as a function of temperature. The temperature ranges are 380 to 2508 K for saturated sodium, 500 to 2500 K for subcooled sodium, and 400 to 1600 K for superheated sodium. Tabulated thermodynamic properties are enthalpy, heat capacity, pressure, entropy, density, instantaneous thermal expansion coefficient, compressibility, and thermal pressure coefficient. Tables are given in SI units and cgs units.

  18. Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca

    2014-01-01

    Company-v3832/Lithium-Ion-Batteries- Outlook-Alternative-Anodes for Sodium Ion Batteries Marca M. Doeff * , Jordirechargeable sodium ion batteries, particularly for large-

  19. Simulation of sodium boiling experiments with THERMIT sodium version

    E-Print Network [OSTI]

    Huh, Kang Yul

    1982-01-01

    Natural and forced convection experiments(SBTF and French) are simulated with the sodium version of the thermal-hydraulic computer code THERMIT. Simulation is done for the test secti- -on with the pressure-velocity boundary ...

  20. Low-pressure injection molding

    SciTech Connect (OSTI)

    Mangels, J.A. (Ceradyne Inc., Costa Mesa, CA (United States))

    1994-05-01

    Ceramic injection molding experienced a revival in the 1970s and 1980s with the application of ceramics for gas turbine components. Concurrently, techniques were being developed for the injection molding of powdered metal compositions into complex shaped articles. The impetus for the development of injection molding as a ceramic fabrication process lay in the potential to produce complex-shaped components to near-net shape. In the ceramic injection molding process, ceramic powders are processed to obtain the desired particle size, distribution and morphology and blended to obtain a homogeneous distribution. These powders are then mixed with the organic binders, generally in a heated, highshear mixer at temperatures above the melting point of the organic binders. The injection molding mix is pelletized, cooled and fed into an injection molding machine. The molding mix is reheated to a fluid state and injected under high pressure (7--70 MPa) into a die cavity. The molded part is removed from the tooling after the molding mix has solidified in the die. The organic binders are then removed from the component at temperatures up to 400 C, generally by some combination of wicking and thermal decomposition. Finally, the component is sintered to obtain its final ceramic properties, using conventional ceramic processes.

  1. Ground beef shelf life assessment as influenced by sodium lactate, sodium propionate, sodium diacetate, and soy protein concentrate 

    E-Print Network [OSTI]

    Grones, Kelly Leann

    2000-01-01

    In phase I all-beef and soy-added ground beef patties containing sodium lactate, sodium propionate, and sodium diacetate at various levels and combinations were stored for nine months at -10°C. Upon cooking, the addition of sodium lactate increased...

  2. Investigation of the effects of a thin dielectric layer on low-pressure hydrogen capacitive discharges driven by combined radio frequency and pulse power sources

    SciTech Connect (OSTI)

    Sun, Jizhong; Fan, Yu; Zou, Ying; Wang, Dezhen [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Ministry of Education), School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Stirner, Thomas [Department of Electronic Engineering, University of Applied Sciences Deggendorf, Edlmairstr. 6-8, D-94469 Deggendorf (Germany)] [Department of Electronic Engineering, University of Applied Sciences Deggendorf, Edlmairstr. 6-8, D-94469 Deggendorf (Germany)

    2013-11-15

    Negative hydrogen ion sources, for instance for fusion devices, currently attract considerable attention. To generate the precursors—highly rovibrationally excited hydrogen molecules—for negative hydrogen ions effectively by electron excitation, a thin dielectric layer is introduced to cover the surface of the electrically grounded electrode of two parallel metal plates in a low-pressure hydrogen capacitive discharge driven by combined rf and pulse power sources. To understand the characteristics of such discharges, particle-in-cell simulations are conducted to study the effects that the single dielectric layer would bring onto the discharges. The simulation results show that the dielectric layer leads to a much higher plasma density and a much larger production rate of highly vibrationally excited hydrogen molecules compared to discharges without the dielectric layer on the electrode. Further investigation indicates that the nonlinear oscillation of the electrons induced by the nanosecond-pulse continues until it is finally damped down and does not show any dependence on the pulse plateau-time, which is in stark contrast to the case without the dielectric layer present. The physical reason for this phenomenon is explored and explained.

  3. Comparison of MELCOR modeling techniques and effects of vessel water injection on a low-pressure, short-term, station blackout at the Grand Gulf Nuclear Station

    SciTech Connect (OSTI)

    Carbajo, J.J.

    1995-06-01

    A fully qualified, best-estimate MELCOR deck has been prepared for the Grand Gulf Nuclear Station and has been run using MELCOR 1.8.3 (1.8 PN) for a low-pressure, short-term, station blackout severe accident. The same severe accident sequence has been run with the same MELCOR version for the same plant using the deck prepared during the NUREG-1150 study. A third run was also completed with the best-estimate deck but without the Lower Plenum Debris Bed (BH) Package to model the lower plenum. The results from the three runs have been compared, and substantial differences have been found. The timing of important events is shorter, and the calculated source terms are in most cases larger for the NUREG-1150 deck results. However, some of the source terms calculated by the NUREG-1150 deck are not conservative when compared to the best-estimate deck results. These results identified some deficiencies in the NUREG-1150 model of the Grand Gulf Nuclear Station. Injection recovery sequences have also been simulated by injecting water into the vessel after core relocation started. This marks the first use of the new BH Package of MELCOR to investigate the effects of water addition to a lower plenum debris bed. The calculated results indicate that vessel failure can be prevented by injecting water at a sufficiently early stage. No pressure spikes in the vessel were predicted during the water injection. The MELCOR code has proven to be a useful tool for severe accident management strategies.

  4. Demonstration with Energy and Daylighting Assessment of Sunlight Responsive Thermochromic (SRT) Window Systems

    SciTech Connect (OSTI)

    Broekhuis, Michael; Liposcak, Curtis; Witte, Michael; Henninger, Robert; Zhou, Xiaohui; Petzen, George; Buchanan, Michael; Kumar, Sneh

    2012-03-31

    Pleotint, LLC was able to successfully extrude thermochromic interlayer for use in the fenestration industry. Pleotint has developed a thermochromic sytem that requires two thermochromic colors to make a neutral color when in the tinted state. These two colors were assembled into a single interlayer called a tri-layer prelam by Crown Operations for use in the glass lamination industry. Various locations, orientations, and constructions of thermochromic windows were studied with funds from this contract. Locations included Australia, California, Costa Rica, Indiana, Iowa, Mexico. Installed orientations included vertical and skylight glazing applications. Various constructions included monolithic, double pane, triple pane constructions. A daylighting study was conducted at LinEl Signature. LinEl Signature has a conference room with a sylight roof system that has a west orientation. The existing LinEl Signature conference room had constant tint 40% VLT transparent skylights. Irradiance meters were installed on the interior and exterior sides of a constant tint skylight. After a month and a half of data collection, the irradiance meters were removed and the constant tint skylights were replaced with Pleotint thermochromic skylight windows. The irradiance meters were reinstalled in the same locations and irradiance data was collected. Both data sets were compared. The data showed that there was a linear relationship with exterior and interior irradiance for the existing constant tint skylights. The thermochromic skylights have a non-linear relationship. The thermochromic skylights were able to limit the amount of irradiance that passed through the thermochromic skylight. A second study of the LinEl Signature conference was performed using EnergyPlus to calculate the amount of Illuminance that passed through constant tint skylights as compared to thermochromic skylights. The constant tint skylights transmitted Illuminance is 2.8 times higher than the thermochromic skylights during the months of May, June, July, August and 1.9 times higher than the thermochromic skylight during the months of March, April, September, October. Calculated illuminance levels were much more consistent as compared to the existing constant tint skylights installed at LinEl Signature. This allows for a more comfortable interior space in regard to glare discomfort and interior lighting control. Lawrence Berkeley National Laboratory was contracted to characterize the performance of the thermochromic interlayer and thermochromic window systems. Thermochromic interlayer was characterized with spectrometer equipment. The thermochromic window systems were characterized using LBNL’s Advanced Window Test Facility. A copy of the report can be found in the Appendix. Iowa State University was contracted to compare thermochromic window technology to constant tint technology. Iowa State University conducted the testing at the Energy Resource Station (ERS). The ERS has the ability to simultaneously test side-by-side competing building technologies. The building is equipped with two identical air handling units, each with its own dedicated and identical chiller. One air handling unit supplies the four test rooms designated as the A rooms and the other unit serves the four test rooms designated as the B rooms. There is one A test room and one B test rooms arranged as pairs in a side-by-side design with each pair having a different exposure. There is a pair of test rooms that face the south, an east and west facing pair. Each of the test rooms is a mirror image of its match with identical construction. The rooms are unoccupied; however, the capability to impose false loads on the rooms exists. The false loads and room lighting can be scheduled to simulate various usage patterns. A copy of the report can be found in the Appendix. GARD Analytics was contracted to compare EnergyPlus building simulations to the data recorded at the Iowa ERS. The goal of this research was to validate the building simulation software developed by the US Department of Energy. EnergyPlus is

  5. BUILDING RESEARCH & INFORMATION (2008) Paper in press (mock proof) expected to appear in Vol 36 No 6 (Nov 2008) An intuitive daylighting performance

    E-Print Network [OSTI]

    Varela, Carlos

    2008-01-01

    importance. Careful management of daylighting in a building is crucial in minimizing the environmental impact relies on optimization techniques to generate these suggestions. Lightsolve allows the designer solar radiation, amongst others. Only if this integration happens early in the design process can

  6. Volume efficient sodium sulfur battery

    DOE Patents [OSTI]

    Mikkor, Mati (Ann Arbor, MI)

    1980-01-01

    In accordance with the teachings of this specification, a sodium sulfur battery is formed as follows. A plurality of box shaped sulfur electrodes are provided, the outer surfaces of which are defined by an electrolyte material. Each of the electrodes have length and width dimensions substantially greater than the thicknesses thereof as well as upwardly facing surface and a downwardly facing surface. An electrode structure is contained in each of the sulfur electrodes. A holding structure is provided for holding the plurality of sulfur electrodes in a stacked condition with the upwardly facing surface of one sulfur electrode in facing relationship to the downwardly facing surface of another sulfur electrode thereabove. A small thickness dimension separates each of the stacked electrodes thereby defining between each pair of sulfur electrodes a volume which receives the sodium reactant. A reservoir is provided for containing sodium. A manifold structure interconnects the volumes between the sulfur electrodes and the reservoir. A metering structure controls the flow of sodium between the reservoir and the manifold structure.

  7. Liquid sodium dip seal maintenance system

    DOE Patents [OSTI]

    Briggs, Richard L. (Hempfield Township, Westmoreland County, PA); Meacham, Sterling A. (Hempfield Township, Westmoreland County, PA)

    1980-01-01

    A system for spraying liquid sodium onto impurities associated with liquid dip seals of nuclear reactors. The liquid sodium mixing with the impurities dissolves the impurities in the liquid sodium. The liquid sodium having dissolved and diluted the impurities carries the impurities away from the site thereby cleaning the liquid dip seal and surrounding area. The system also allows wetting of the metallic surfaces of the dip seal thereby reducing migration of radioactive particles across the wetted boundary.

  8. The Sodium Content of Your Food. 

    E-Print Network [OSTI]

    Anonymous,

    1982-01-01

    ............................ ............................. Pear nectar Pineapple juice .......................... Prune juice .............................. ................ Mineral Water. imported Tea ............................. Hot brewed .............................. Hot instant... .................................... Condiments, fats and oils 2t ........ Sodium Content of Selected Non-prescription Drugs 2t The Sodium Content of Your Food Extension food and nutrition specialists, The Texas A&M University System. Introduction Sodium is a mineral element necessary...

  9. Results of a research study on the impact of active daylighting on operating results of a retail business

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    In preliminary evaluations of So-Luminaire's (SI) product in 1985 and 1986, DOE concluded that it warranted further research and evaluation and was worthy of receiving governmental financial and structural support therefor. SI, along with Safeway, had known intuitively that the So-Luminaire systems which had been previously installed in several of their Phoenix-area stores had resulted in a marked reduction in electrical energy consumption. However, a definitive determination of energy savings had been utilized in previous installations. Further, SI and Safeway both hypothesized that the high quality of natural light provided by these systems displayed goods to greater advantage and contributed to an overall increase in store sales, all other factors being held constant. A study to attempt to objectively determine these two presumed benefits of active daylighting in a commercial application was begun.

  10. Results of a research study on the impact of active daylighting on operating results of a retail business. Final report

    SciTech Connect (OSTI)

    Not Available

    1993-04-01

    In preliminary evaluations of So-Luminaire`s (SI) product in 1985 and 1986, DOE concluded that it warranted further research and evaluation and was worthy of receiving governmental financial and structural support therefor. SI, along with Safeway, had known intuitively that the So-Luminaire systems which had been previously installed in several of their Phoenix-area stores had resulted in a marked reduction in electrical energy consumption. However, a definitive determination of energy savings had been utilized in previous installations. Further, SI and Safeway both hypothesized that the high quality of natural light provided by these systems displayed goods to greater advantage and contributed to an overall increase in store sales, all other factors being held constant. A study to attempt to objectively determine these two presumed benefits of active daylighting in a commercial application was begun.

  11. Fire suppressing apparatus. [sodium fires

    DOE Patents [OSTI]

    Buttrey, K.E.

    1980-12-19

    Apparatus for smothering a liquid sodium fire comprises a pan, a perforated cover on the pan, and tubed depending from the cover and providing communication between the interior of the pan and the ambient atmosphere through the perforations in the cover. Liquid caught in the pan rises above the lower ends of the tubes and thus serves as a barrier which limits the amount of air entering the pan.

  12. Liquid-sodium thermoacoustic engine

    SciTech Connect (OSTI)

    Migliori, A.; Swift, G.W.

    1988-08-01

    We have constructed a thermoacoustic engine that uses liquid sodium as its working substance. The engine generates acoustic power using heat flowing from a high-temperature source to a low-temperature sink. The measured performance of this engine disagrees significantly with numerical calculations based on our theory of thermoacoustic engines. The efficiency of the engine is a substantial fraction of Carnot's efficiency, and its power density is comparable to that of the conventional heat engines in widespread use. Thus we expect this type of engine to be of practical, economic importance.

  13. Sodium Battery | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation ofAlbuquerque|Sensitive Species3performedValley | Department ofAboutMitchSodium

  14. Electrolytic process to produce sodium hypochlorite using sodium ion conductive ceramic membranes

    DOE Patents [OSTI]

    Balagopal, Shekar; Malhotra, Vinod; Pendleton, Justin; Reid, Kathy Jo

    2012-09-18

    An electrochemical process for the production of sodium hypochlorite is disclosed. The process may potentially be used to produce sodium hypochlorite from seawater or low purity un-softened or NaCl-based salt solutions. The process utilizes a sodium ion conductive ceramic membrane, such as membranes based on NASICON-type materials, in an electrolytic cell. In the process, water is reduced at a cathode to form hydroxyl ions and hydrogen gas. Chloride ions from a sodium chloride solution are oxidized in the anolyte compartment to produce chlorine gas which reacts with water to produce hypochlorous and hydrochloric acid. Sodium ions are transported from the anolyte compartment to the catholyte compartment across the sodium ion conductive ceramic membrane. Sodium hydroxide is transported from the catholyte compartment to the anolyte compartment to produce sodium hypochlorite within the anolyte compartment.

  15. TOXICOLOGICAL AND STRUCTURAL CONSEQUENCES FROM SODIUM-WATER REACTION IN CELL CONTAINING THE SECONDARY SODIUM TANK

    SciTech Connect (OSTI)

    MARUSICH RM

    2008-06-25

    The analysis will show the consequences should the solid sodium in the Secondary Sodium Tank react with a presumed layer of water in the cell. The Peer Review Checklist is attached.

  16. A layered sodium titanate as promising anode material for sodium ion batteries

    E-Print Network [OSTI]

    Wu, Di, S.M. Massachusetts Institute of Technology

    2014-01-01

    Sodium ion batteries have recently received great attention for large-scale energy applications because of the abundance and low cost of sodium source. Although some cathode materials with desirable electrochemical properties ...

  17. Sodium Titanate Anodes for Dual Intercalation Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01

    for Dual Intercalation Batteries Lithium supply securityinterest in sodium-ion batteries. These devices operate muchsodium-ion or lithium-ion batteries that utilize them as

  18. Independent Oversight Review, Sodium Bearing Waste Treatment...

    Office of Environmental Management (EM)

    2012 Review of the Sodium Bearing Waste Treatment Project - Integrated Waste Treatment Unit Federal Operational Readiness Review This report documents the results of an...

  19. Independent Oversight Review, Sodium Bearing Waste Treatment...

    Office of Environmental Management (EM)

    2012 Review of the Sodium Bearing Waste Treatment Project - Integrated Waste Treatment Unit Contractor Operational Readiness Review This report documents the results of an...

  20. Sodium-layer laser guide stars

    SciTech Connect (OSTI)

    Friedman, H.W.

    1993-08-03

    The requirements and design of a laser system to generate a sodium- layer beacon is presented. Early results of photometry and wavefront sensing are given.

  1. Daylight photocatalysis performance of biomorphic CeO{sub 2} hollow fibers prepared with lens cleaning paper as biotemplate

    SciTech Connect (OSTI)

    Qian, Junchao; Chen, Feng [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China)] [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China); Wang, Fang; Zhao, Xiaobing [Department of Materials Science and Engineering, Changzhou University, 213164 Changzhou (China)] [Department of Materials Science and Engineering, Changzhou University, 213164 Changzhou (China); Chen, Zhigang, E-mail: ziyou1900@gmail.com [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China) [Department of Material Science and Engineering, Jiangsu University, 212013 Zhenjiang (China); Jiangsu Key Laboratory for Environment Functional Materials, 215009 Suzhou University of Science and Technology, Suzhou (China); State Key laboratory of Crystal Material, Shandong University, 250100 Jinan (China)

    2012-08-15

    Highlights: ? A novel, simple and eco-friendly approach for hierarchical, biomorphic CeO{sub 2} hollow fibers with mesoporous tube walls is presented by using paper as template. ? The biomorphic CeO{sub 2} fibers was composed of nanosheets with bimodal pore-size mesoporous distribution and exhibited high light-harvesting under sunlight irradiation. ? The CeO{sub 2} microfibers biomimicking the natural plant structures have promising application for photodegradation of organic pollutants in water. -- Abstract: Hierarchical, biomorphic CeO{sub 2} hollow fibers with mesoporous tube walls have been fabricated using lens cleaning paper as biotemplates. After sintered at 550 °C in air, the cellulosic fibers of paper were converted into micro-tubes composing of CeO{sub 2} crystallites with grain size about 8 nm. The photocatalytic activity of the CeO{sub 2} fibers was evaluated by photodegradation efficiency of methylene blue in aqueous solution under daylight irradiation. The characterized results show that the CeO{sub 2} fibers faithfully replicated micro-fibrous structure derived from original template and possessed dramatic enhanced photocatalytic activity compared with bulk CeO{sub 2}. This simple biotemplate method provides a cost-effective and eco-friendly route to obtain high performance photocatalysts.

  2. In-situ method for treating residual sodium

    DOE Patents [OSTI]

    Sherman, Steven R. (Idaho Falls, ID); Henslee, S. Paul (Idaho Falls, ID)

    2005-07-19

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  3. In-Situ Method for Treating Residual Sodium

    DOE Patents [OSTI]

    Sherman, Steven R.; Henslee, S. Paul

    2005-07-19

    A unique process for deactivating residual sodium in Liquid Metal Fast Breeder Reactor (LMFBR) systems which uses humidified (but not saturated) carbon dioxide at ambient temperature and pressure to convert residual sodium into solid sodium bicarbonate.

  4. United States, France and Japan Increase Cooperation on Sodium...

    Energy Savers [EERE]

    United States, France and Japan Increase Cooperation on Sodium-Cooled Fast Reactor Prototypes United States, France and Japan Increase Cooperation on Sodium-Cooled Fast Reactor...

  5. TRACE IDENTIFICATION OF CESIUM AND SODIUM IN NEUTRAL BEAM RESEARCH

    E-Print Network [OSTI]

    Ruby, L.

    2010-01-01

    TRACE IDENTIFICATION OF CESIUM AND Lawrence Ruby LawrenceBerkeley, California 94720 Cesium and sodium in vapor formthe extent to which the cesium and sodium migrate in the

  6. Thermodynamic and transport properties of sodium liquid and vapor...

    Office of Scientific and Technical Information (OSTI)

    sodium liquid and vapor. Recently published Russian recommendations and results of equation of state calculations on thermophysical properties of sodium have been included in...

  7. Calculation of thermophysical properties of sodium. [LMFBR

    SciTech Connect (OSTI)

    Fink, J.K.; Leibowitz, L.

    1981-01-01

    The thermodynamic properties of sodium previously recommended by Padilla have been updated. As much as possible, the approach described by Padilla has been used. For sodium in the states of saturated liquid and vapor, subcooled liquid and superheated vapor, the following thermodynamic properties were determined: enthalpy, heat capacity (constant pressure and constant volume), pressure, density, thermal-expansion coefficient, and compressibility (adiabatic and isothermal). In addition to the above properties, thermodynamic properties including heat of fusion, heat of vaporization, surface tension, speed of sound and transport properties of themal conductivity, thermal diffusivity, emissivity, and viscosity were determined for saturated sodium.

  8. Kinetics of wet sodium vapor complex plasma

    SciTech Connect (OSTI)

    Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

    2014-04-15

    In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

  9. Radial power flattening in sodium fast reactors

    E-Print Network [OSTI]

    Krentz-Wee, Rebecca (Rebecca Elizabeth)

    2012-01-01

    In order to improve a new design for a uranium startup sodium cooled fast reactor which was proposed at MIT, this thesis evaluated radial power flattening by varying the fuel volume fraction at a fixed U-235 enrichment of ...

  10. Method and system for producing hydrogen using sodium ion separation membranes

    DOE Patents [OSTI]

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M; Frost, Lyman

    2013-05-21

    A method of producing hydrogen from sodium hydroxide and water is disclosed. The method comprises separating sodium from a first aqueous sodium hydroxide stream in a sodium ion separator, feeding the sodium produced in the sodium ion separator to a sodium reactor, reacting the sodium in the sodium reactor with water, and producing a second aqueous sodium hydroxide stream and hydrogen. The method may also comprise reusing the second aqueous sodium hydroxide stream by combining the second aqueous sodium hydroxide stream with the first aqueous sodium hydroxide stream. A system of producing hydrogen is also disclosed.

  11. Daylighting | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    of the house. For example: South-facing windows allow most winter sunlight into the home but little direct sun during the summer, especially when properly shaded North-facing...

  12. THE DAYLIGHTING SOLUTION

    E-Print Network [OSTI]

    Selkowitz, Stephen

    2013-01-01

    sho\\l'rooms. Use of solar energy for thermal control insolar applications in buildings has focused on providing thermal energy

  13. Lighting and Daylight Harvesting 

    E-Print Network [OSTI]

    Bos, J.

    2011-01-01

    in 1992 to serve the lighting design needs of the architectural and interior design communities. With over fifty years of combined experience, our areas of expertise range from architectural and theatrical lighting to custom fixture design. Bos... Lighting Design We are active members of the International Association of Lighting Designers, the American Institute of Architects, the Illuminating Engineering Society, International Dark Skies Association and the United States Green Building Council...

  14. Daylight Savings Time Starts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HAB Packet HanfordDOEDaniel ShechtmanDepartmentSecurityDavid1

  15. Daylighting | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformation Current HAB Packet HanfordDOEDaniel

  16. Window Daylighting Demo

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on DeliciousMathematics And Statistics » USAJobs SearchAMERICA'S FUTURE.ProjectsLeaders |3 0 0 N S T Rand WaterWindow

  17. Nanodiamonds in dusty low-pressure plasmas

    SciTech Connect (OSTI)

    Vandenbulcke, L.; Gries, T.; Rouzaud, J. N.

    2009-01-26

    Dusty plasmas composed of carbon, hydrogen, and oxygen have been evidenced by optical emission spectroscopy and microwave interferometry, due to the increase in electron energy and the decrease in electron density. These plasmas allow homogeneous synthesis of nanodiamond grains composed of either pure diamond nanocrystals only (2-10 nm in size) or of diamond nanocrystals and some sp{sup 2}-hybridized carbon entities. The control of their size and their microstructure could open ways for a wide range of fields. Their formation from a plasma-activated gaseous phase is also attractive because the formation of nanodiamonds in the universe is still a matter of controversy.

  18. Low pressure mild hydrocracking: Room for improvement

    SciTech Connect (OSTI)

    Johns, W.F.; Hall, L.L. [Texaco Refining and Marketing Inc., Bakersfield, CA (United States); Lamourelle, A.P. [Haldor Topsoe, Inc., Mission Viejo, CA (United States); Moyse, B.M.; Rasmussen, H.W. [Haldor Topsoe, Inc., Houston, TX (United States)

    1996-12-01

    In Europe and some other areas of the world, mild hydrocracking (MHC) is quite popular. Here in the US, this option has not been utilized by many refiners. This is inherently due to the different process schemes which are prevalent on each continent. In Europe, there is a predominance of the hydroskimming refinery type, which means that MHC can fulfill a need even with a limited amount of conversion to lighter boiling components. In the US, the situation is reversed in that conversion to lighter products is common, as evidenced by the number of FCC units, cokers, and dedicated hydrocrackers. There are, however, some refineries in the US, where a MHC operation can make sense both financially and logistically. Here, the authors focus on one such unit.

  19. Emergency Filter for Low Pressure EGR

    Broader source: Energy.gov [DOE]

    This project uses CFD simulation and laboratory tests to design single- and multi-layer mesh as an EGR emergency filter to prevent combustion particles from passing back to the engine.

  20. Laser-induced fluorescence measurements of NCN in low-pressure CH{sub 4}/O{sub 2}/N{sub 2} flames and its role in prompt NO formation

    SciTech Connect (OSTI)

    Sutton, Jeffrey A.; Williams, Bradley A.; Fleming, James W. [Navy Technology Center for Safety and Survivability, Chemistry Division, Combustion Dynamics Section, Code 6185, Naval Research Laboratory, Washington, DC 20375-5342 (United States)

    2008-05-15

    NCN profiles were measured for five rich and lean premixed, low-pressure methane flames using laser-induced fluorescence (LIF). A semiquantitative determination of the NCN mole fractions as a function of spatial height above the burner is made by calibrating the NCN LIF signals using highly accurate OH LIF measurements in an adjacent spectral region. The resulting calibration yields an uncertainty estimate of a factor of 3 for the absolute values, but only {+-}25% for the relative NCN profiles. For all flame conditions, the NCN profiles occur immediately downstream of previously measured CH profiles. In addition, high correlations are found between the peak CH and peak NCN concentrations and the peak NCN and postflame NO concentrations over all equivalence ratios. These observations are consistent with NCN being the primary product channel from the CH + N{sub 2} reaction and the initial intermediate in the prompt NO formation. This is the first mechanistic study in hydrocarbon flames that provides such experimental evidence. The experimental profiles are compared to numerical calculations using modified versions of two well-established hydrocarbon kinetic mechanisms. Reasonable agreement between the calculations and experiment is found for NCN profile shape, location of peak NCN concentrations, and absolute mole fractions. However, the dependence on stoichiometry of the peak NCN concentration is overestimated. Further work is required on NCN kinetics for modeling prompt NO in laminar premixed flames. (author)

  1. High-Resolution Numerical Simulation and Analysis of Mach Reflection Structures in Detonation Waves in Low-Pressure H2–O2–Ar Mixtures: A Summary of Results Obtained with the Adaptive Mesh Refinement Framework AMROC

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Deiterding, Ralf

    2011-01-01

    Numerical simulation can be key to the understanding of the multidimensional nature of transient detonation waves. However, the accurate approximation of realistic detonations is demanding as a wide range of scales needs to be resolved. This paper describes a successful solution strategy that utilizes logically rectangular dynamically adaptive meshes. The hydrodynamic transport scheme and the treatment of the nonequilibrium reaction terms are sketched. A ghost fluid approach is integrated into the method to allow for embedded geometrically complex boundaries. Large-scale parallel simulations of unstable detonation structures of Chapman-Jouguet detonations in low-pressure hydrogen-oxygen-argon mixtures demonstrate the efficiency of the described techniquesmore »in practice. In particular, computations of regular cellular structures in two and three space dimensions and their development under transient conditions, that is, under diffraction and for propagation through bends are presented. Some of the observed patterns are classified by shock polar analysis, and a diagram of the transition boundaries between possible Mach reflection structures is constructed.« less

  2. Sodium-tetravalent sulfur molten chloroaluminate cell

    DOE Patents [OSTI]

    Mamantov, Gleb (Knoxville, TN)

    1985-04-02

    A sodium-tetravalent sulfur molten chloroaluminate cell with a .beta."-alumina sodium ion conductor having a S-Al mole ratio of above about 0.15 in an acidic molten chloroaluminate cathode composition is disclosed. The cathode composition has an AlCl.sub.3 -NaCl mole percent ratio of above about 70-30 at theoretical full charge. The cell provides high energy densities at low temperatures and provides high energy densities and high power densities at moderate temperatures.

  3. Method of making a sodium sulfur battery

    DOE Patents [OSTI]

    Elkins, P. E.

    1981-09-22

    A method of making a portion of a sodium sulfur battery is disclosed. The battery portion made is a portion of the container which defines the volume for the cathodic reactant materials which are sulfur and sodium polysulfide materials. The container portion is defined by an outer metal casing with a graphite liner contained therein, the graphite liner having a coating on its internal diameter for sealing off the porosity thereof. The steel outer container and graphite pipe are united by a method which insures that at the operating temperature of the battery, relatively low electrical resistance exists between the two materials because they are in intimate contact with one another. 3 figs.

  4. Measurements of Droplet Pinch-Off In Liquid Sodium

    E-Print Network [OSTI]

    Anlage, Steven

    than Mercury ­ 10X BETTER RESOLUTION · Study Effect of Magnetic Fields #12;Experimental Design SHIELDING · Reduces Electrical Noise · Coaxial Ground · Distributes Heat · Containment/ Structural Support #12;Running the Experiment · Sodium Melting? · Sodium Purity · Contact Wetting · Sampling Rate Gah

  5. Gypsum and Polyacrylamide Soil Amendments Used With High Sodium Wastewater 

    E-Print Network [OSTI]

    Gardiner, Duane

    1996-01-01

    Using wastewater for irrigation of crops represents an attractive alternative to disposal. Typically, municipal wastewaters are high in sodium, and the resulting high sodium absorption ratio (SAR) alters the soil structure making it more impermeable...

  6. In sodium tests of ultrasonic transducers

    SciTech Connect (OSTI)

    Lhuillier, C.; Descombin, O.; Baque, F. [CEA, DTN, 13108 Saint Paul lez Durance Cedex (France); Marchand, B. [CEA, LIST, 91191 Gif-sur-Yvette (France); Saillant, J. F. [AREVA/NDE Solutions, 4 rue Thomas Dumorey, 71109 Chalon sur Saone Cedex (France); Augem, J. M. [EDF, 12-14 avenue Dutrievoz, 69628 Villeurbanne (France)

    2011-07-01

    Ultrasonic techniques are seen as suitable candidates for the in-service inspection and for the continuous surveillance of sodium cooled reactors (SFR). These techniques need the development and the qualification of immersed ultrasonic transducers, and materials. This paper presents some developments performed by CEA (DTN and LIST) and AREVA (NDE Solutions), and some results. (authors)

  7. The magnesium nutrition of cotton as influenced by sodium 

    E-Print Network [OSTI]

    Thenabadu, Mervyn Wellesly

    1964-01-01

    sodium has not yet found a place among the elements generally considered essential for plant growth. Although the lithosphere is relatively more abundant in this element than in potassium (17), plants generally contain much less sodium than potassium... of all traces of sodium in these classical experiments may be doubted they showed that this ele- ment was not required by plants in amounts comparable to the requirements of potassium or calcium. The sodium content of plants varies appreciably. Plants...

  8. Corrosion performance of advanced structural materials in sodium.

    SciTech Connect (OSTI)

    Natesan, K.; Momozaki, Y.; Li, M.; Rink, D.L.

    2012-05-16

    This report gives a description of the activities in design, fabrication, construction, and assembling of a pumped sodium loop for the sodium compatibility studies on advanced structural materials. The work is the Argonne National Laboratory (ANL) portion of the effort on the work project entitled, 'Sodium Compatibility of Advanced Fast Reactor Materials,' and is a part of Advanced Materials Development within the Reactor Campaign. The objective of this project is to develop information on sodium corrosion compatibility of advanced materials being considered for sodium reactor applications. This report gives the status of the sodium pumped loop at Argonne National Laboratory, the specimen details, and the technical approach to evaluate the sodium compatibility of advanced structural alloys. This report is a deliverable from ANL in FY2010 (M2GAN10SF050302) under the work package G-AN10SF0503 'Sodium Compatibility of Advanced Fast Reactor Materials.' Two reports were issued in 2009 (Natesan and Meimei Li 2009, Natesan et al. 2009) which examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design specifications for the ANL pumped loop for testing advanced structural materials. Available information was presented on solubility of several metallic and nonmetallic elements along with a discussion of the possible mechanisms for the accumulation of impurities in sodium. That report concluded that the solubility of many metals in sodium is low (<1 part per million) in the temperature range of interest in sodium reactors and such trace amounts would not impact the mechanical integrity of structural materials and components. The earlier report also analyzed the solubility and transport mechanisms of nonmetallic elements such as oxygen, nitrogen, carbon, and hydrogen in laboratory sodium loops and in reactor systems such as Experimental Breeder Reactor-II, Fast Flux Test Facility, and Clinch River Breeder Reactor. Among the nonmetallic elements discussed, oxygen is deemed controllable and its concentration in sodium can be maintained in sodium for long reactor life by using cold-trap method. It was concluded that among the cold-trap and getter-trap methods, the use of cold trap is sufficient to achieve oxygen concentration of the order of 1 part per million. Under these oxygen conditions in sodium, the corrosion performance of structural materials such as austenitic stainless steels and ferritic steels will be acceptable at a maximum core outlet sodium temperature of {approx}550 C. In the current sodium compatibility studies, the oxygen concentration in sodium will be controlled and maintained at {approx}1 ppm by controlling the cold trap temperature. The oxygen concentration in sodium in the forced convection sodium loop will be controlled and monitored by maintaining the cold trap temperature in the range of 120-150 C, which would result in oxygen concentration in the range of 1-2 ppm. Uniaxial tensile specimens are being exposed to flowing sodium and will be retrieved and analyzed for corrosion and post-exposure tensile properties. Advanced materials for sodium exposure include austenitic alloy HT-UPS and ferritic-martensitic steels modified 9Cr-1Mo and NF616. Among the nonmetallic elements in sodium, carbon was assessed to have the most influence on structural materials since carbon, as an impurity, is not amenable to control and maintenance by any of the simple purification methods. The dynamic equilibrium value for carbon in sodium systems is dependent on several factors, details of which were discussed in the earlier report. The current sodium compatibility studies will examine the role of carbon concentration in sodium on the carburization-decarburization of advanced structural materials at temperatures up to 650 C. Carbon will be added to the sodium by exposure of carbon-filled iron tubes, which over time will enable carbon to diffuse through iron and dissolve into sodium. The method enables addition of dissolved carbon (without carb

  9. Effects of sodium lactate and sodium propionate on the sensory, microbial, and chemical characteristics of fresh aerobically stored ground beef 

    E-Print Network [OSTI]

    Eckert, Laura Anne

    1995-01-01

    EFFECTS OF SODIUM LACTATE AND SODIUM PROPIONATE ON THE SENSORY, MICROBIAL, AND CHEMICAL CHARACTERISTICS OF FRESH AEROBICALLY STORED GROUND BEEF A Thesis by LAURA ANNE ECKERT Submitted to the Office of Graduate Studies of Texas A&M University... in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE December 1995 Major Subject: Food Science and Technology EFFECTS OF SODIUM LACTATE AND SODIUM PROPIONATE ON THE SENSORY, MICROBIAL, AND CHEMICAL CHARACTERISTICS OF FRESH...

  10. Cast Stone Formulation At Higher Sodium Concentrations

    SciTech Connect (OSTI)

    Fox, K. M.; Roberts, K. A.; Edwards, T. B.

    2014-02-28

    A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leachability indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the l

  11. Cast Stone Formulation At Higher Sodium Concentrations

    SciTech Connect (OSTI)

    Fox, K. M.; Edwards, T. A.; Roberts, K. B.

    2013-10-02

    A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leach indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the limited

  12. Cast Stone Formulation At Higher Sodium Concentrations

    SciTech Connect (OSTI)

    Fox, K. M.; Roberts, K. A.; Edwards, T. B.

    2013-09-17

    A low temperature waste form known as Cast Stone is being considered to provide supplemental Low Activity Waste (LAW) immobilization capacity for the Hanford site. Formulation of Cast Stone at high sodium concentrations is of interest since a significant reduction in the necessary volume of Cast Stone and subsequent disposal costs could be achieved if an acceptable waste form can be produced with a high sodium molarity salt solution combined with a high water to premix (or dry blend) ratio. The objectives of this study were to evaluate the factors involved with increasing the sodium concentration in Cast Stone, including production and performance properties and the retention and release of specific components of interest. Three factors were identified for the experimental matrix: the concentration of sodium in the simulated salt solution, the water to premix ratio, and the blast furnace slag portion of the premix. The salt solution simulants used in this study were formulated to represent the overall average waste composition. The cement, blast furnace slag, and fly ash were sourced from a supplier in the Hanford area in order to be representative. The test mixes were prepared in the laboratory and fresh properties were measured. Fresh density increased with increasing sodium molarity and with decreasing water to premix ratio, as expected given the individual densities of these components. Rheology measurements showed that all of the test mixes produced very fluid slurries. The fresh density and rheology data are of potential value in designing a future Cast Stone production facility. Standing water and density gradient testing showed that settling is not of particular concern for the high sodium compositions studied. Heat of hydration measurements may provide some insight into the reactions that occur within the test mixes, which may in turn be related to the properties and performance of the waste form. These measurements showed that increased sodium concentration in the salt solution reduced the time to peak heat flow, and reducing the amount of slag in the premix increased the time to peak heat flow. These observations may help to describe some of the cured properties of the samples, in particular the differences in compressive strength observed after 28 and 90 days of curing. Samples were cured for at least 28 days at ambient temperature in the laboratory prior to cured properties analyses. The low activity waste form for disposal at the Hanford Site is required to have a compressive strength of at least 500 psi. After 28 days of curing, several of the test mixes had mean compressive strengths that were below the 500 psi requirement. Higher sodium concentrations and higher water to premix ratios led to reduced compressive strength. Higher fly ash concentrations decreased the compressive strength after 28 days of curing. This may be explained in that the cementitious phases matured more quickly in the mixes with higher concentrations of slag, as evidenced by the data for the time to peak heat generation. All of the test mixes exhibited higher mean compressive strengths after 90 days of curing, with only one composition having a mean compressive strength of less than 500 psi. Leach indices were determined for the test mixes for contaminants of interest. The leaching performance of the mixes evaluated in this study was not particularly sensitive to the factors used in the experimental design. This may be beneficial in demonstrating that the performance of the waste form is robust with respect to changes in the mix composition. The results of this study demonstrate the potential to achieve significantly higher waste loadings in Cast Stone and other low temperature, cementitious waste forms. Additional work is needed to elucidate the hydration mechanisms occurring in Cast Stone formulated with highly concentrated salt solutions since these reactions are responsible for determining the performance of the cured waste form. The thermal analyses completed in this study provide some preliminary insight, although the limited

  13. Report on sodium compatibility of advanced structural materials.

    SciTech Connect (OSTI)

    Li, M.; Natesan, K.; Momozaki, Y.; Rink, D.L.; Soppet, W.K.; Listwan, J.T.

    2012-07-09

    This report provides an update on the evaluation of sodium compatibility of advanced structural materials. The report is a deliverable (level 3) in FY11 (M3A11AN04030403), under the Work Package A-11AN040304, 'Sodium Compatibility of Advanced Structural Materials' performed by Argonne National Laboratory (ANL), as part of Advanced Structural Materials Program for the Advanced Reactor Concepts. This work package supports the advanced structural materials development by providing corrosion and tensile data from the standpoint of sodium compatibility of advanced structural alloys. The scope of work involves exposure of advanced structural alloys such as G92, mod.9Cr-1Mo (G91) ferritic-martensitic steels and HT-UPS austenitic stainless steels to a flowing sodium environment with controlled impurity concentrations. The exposed specimens are analyzed for their corrosion performance, microstructural changes, and tensile behavior. Previous reports examined the thermodynamic and kinetic factors involved in the purity of liquid sodium coolant for sodium reactor applications as well as the design, fabrication, and construction of a forced convection sodium loop for sodium compatibility studies of advanced materials. This report presents the results on corrosion performance, microstructure, and tensile properties of advanced ferritic-martensitic and austenitic alloys exposed to liquid sodium at 550 C for up to 2700 h and at 650 C for up to 5064 h in the forced convection sodium loop. The oxygen content of sodium was controlled by the cold-trapping method to achieve {approx}1 wppm oxygen level. Four alloys were examined, G92 in the normalized and tempered condition (H1 G92), G92 in the cold-rolled condition (H2 G92), G91 in the normalized and tempered condition, and hot-rolled HT-UPS. G91 was included as a reference to compare with advanced alloy, G92. It was found that all four alloys showed weight loss after sodium exposures at 550 and 650 C. The weight loss of the four alloys was comparable after sodium exposures at 550 C; the weight loss of ferritic-martensitic steels, G92 and G91 is more significant than that of austenitic stainless steel, HT-UPS after sodium exposures at 650 C. Sodium exposures up to 2700 h at 550 C had no significant influence on tensile properties, while sodium exposures up to 5064 h at 650 C dramatically lowered the tensile strengths of the four alloys. The ultimate tensile strength of H1 G92, H2 G92, and G91 ferritic-martensitic steels was reduced to as much as nearly half of its initial value after sodium exposures at 650 C. Though the uniform elongation was recovered to some extent, these three ferritic-martensitic steels showed considerable strain softening after sodium exposures. The yield stress of HT-UPS austenitic stainless steel increased, the ultimate tensile strength decreased, and the total elongation was reduced after sodium exposures at 650 C. The dynamic strain aging effect observed in the as-received HT-UPS specimens became less pronounced after sodium exposures at 650 C. Microstructural characterization of sodium-exposed specimens showed no appreciable surface deterioration or grain structure changes under an optical microscope, except for the H2 G92 steel, in which the martensite structure transformed to large grain ferrite after sodium exposures at 650 C. TEM observations of the sodium-exposed H2 G92 steel showed significant recrystallization after sodium exposure for 2700 h at 550 C, and transformation of martensite to ferrite and high density of precipitates in nearly dislocation-free matrix after sodium exposures at 650 C. Further microstructural analysis and evaluation of decarburization/carburization behavior is needed to understand the dramatic changes in the tensile strengths of advanced ferritic-martensitic and austenitic steels after sodium exposures at 650 C.

  14. Super-radiance in the sodium resonance lines from sodium iodide arc lamps

    SciTech Connect (OSTI)

    Karabourniotis, D.; Drakakis, E.

    2010-08-09

    Super-radiance observed within the centers of the sodium resonance D lines emitted by arc lamps containing sodium iodide as additive in a high-pressure mercury plasma environment was studied by high-resolution emission spectroscopy. The spectral radiance of these self-reversed lines including super-radiance was simulated by considering a local enhancement of the source function due to the presence of an additional source of radiation near the arc wall. Causes of this hitherto unrecognized source of radiation are given.

  15. The Salt or Sodium Chloride Content of Feeds 

    E-Print Network [OSTI]

    Fraps, G. S. (George Stronach); Lomanitz, S. (Sebastian)

    1920-01-01

    STATION AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS W. B. BIZZELL, Preeident BULLETIN NO. 271 OCTOBER, 1920 DIVISION OF CHEMISTRY THE SALT OR SODIUM CHLORIDE CONTENT OF FEEDS B. YOUNGBLOOD, DIRECTOK COLLEGE STATION, BRAZOS COUNTT, TEXAS I..... ................... Summary ancl conclusions. Page. l1 [Blank Page in Original Bulletin] BULLETIN XO. 271. OCTOBE- '"On THE SALT OR SODIUM CHLORIDE CONTENT OF FEI The Texas feed law requires the statement of the ingredients of many mixed feeds. Common salt or sodium...

  16. Idaho Site Obtains Patent for Nuclear Reactor Sodium Cleanup Treatment

    Broader source: Energy.gov [DOE]

    IDAHO FALLS, Idaho – An innovative idea for cleaning up sodium in a decommissioned nuclear reactor at EM’s Idaho site grew from a carpool discussion.

  17. Fact Sheet: Sodium-Beta Batteries (October 2012) | Department...

    Office of Environmental Management (EM)

    Batteries (October 2012) Fact Sheet: Sodium-Beta Batteries (October 2012) DOE's Energy Storage Program is funding research to further develop a novel planar design for...

  18. Sodium cobalt bronze batteries and a method for making same

    DOE Patents [OSTI]

    Doeff, M.M.; Ma, Y.; Visco, S.J.; DeJonghe, L.

    1999-06-29

    A solid state secondary battery utilizing a low cost, environmentally sound, sodium cobalt bronze electrode is described. A method is provided for producing same. 11 figs.

  19. Sodium fast reactor safety and licensing research plan. Volume II.

    SciTech Connect (OSTI)

    Ludewig, H.; Powers, D. A.; Hewson, John C.; LaChance, Jeffrey L.; Wright, A.; Phillips, J.; Zeyen, R.; Clement, B.; Garner, Frank; Walters, Leon; Wright, Steve; Ott, Larry J.; Suo-Anttila, Ahti Jorma; Denning, Richard; Ohshima, Hiroyuki; Ohno, S.; Miyhara, S.; Yacout, Abdellatif; Farmer, M.; Wade, D.; Grandy, C.; Schmidt, R.; Cahalen, J.; Olivier, Tara Jean; Budnitz, R.; Tobita, Yoshiharu; Serre, Frederic; Natesan, Ken; Carbajo, Juan J.; Jeong, Hae-Yong; Wigeland, Roald; Corradini, Michael; Thomas, Justin; Wei, Tom; Sofu, Tanju; Flanagan, George F.; Bari, R.; Porter D.; Lambert, J.; Hayes, S.; Sackett, J.; Denman, Matthew R.

    2012-05-01

    Expert panels comprised of subject matter experts identified at the U.S. National Laboratories (SNL, ANL, INL, ORNL, LBL, and BNL), universities (University of Wisconsin and Ohio State University), international agencies (IRSN, CEA, JAEA, KAERI, and JRC-IE) and private consultation companies (Radiation Effects Consulting) were assembled to perform a gap analysis for sodium fast reactor licensing. Expert-opinion elicitation was performed to qualitatively assess the current state of sodium fast reactor technologies. Five independent gap analyses were performed resulting in the following topical reports: (1) Accident Initiators and Sequences (i.e., Initiators/Sequences Technology Gap Analysis), (2) Sodium Technology Phenomena (i.e., Advanced Burner Reactor Sodium Technology Gap Analysis), (3) Fuels and Materials (i.e., Sodium Fast Reactor Fuels and Materials: Research Needs), (4) Source Term Characterization (i.e., Advanced Sodium Fast Reactor Accident Source Terms: Research Needs), and (5) Computer Codes and Models (i.e., Sodium Fast Reactor Gaps Analysis of Computer Codes and Models for Accident Analysis and Reactor Safety). Volume II of the Sodium Research Plan consolidates the five gap analysis reports produced by each expert panel, wherein the importance of the identified phenomena and necessities of further experimental research and code development were addressed. The findings from these five reports comprised the basis for the analysis in Sodium Fast Reactor Research Plan Volume I.

  20. Synthesis and Characterization of a Novel Sodium Transition Metal...

    Office of Scientific and Technical Information (OSTI)

    Synthesis and Characterization of a Novel Sodium Transition Metal Oxyfluoride: NaMnMoOsubscript 3Fsubscript 3Hsubscript 2O Citation Details In-Document Search Title:...

  1. High-Compression-Ratio; Atkinson-Cycle Engine Using Low-Pressure Direct Injection and Pneumatic-Electronic Valve Actuation Enabled by Ionization Current and Foward-Backward Mass Air Flow Sensor Feedback

    SciTech Connect (OSTI)

    Harold Schock; Farhad Jaberi; Ahmed Naguib; Guoming Zhu; David Hung

    2007-12-31

    This report describes the work completed over a two and one half year effort sponsored by the US Department of Energy. The goal was to demonstrate the technology needed to produce a highly efficient engine enabled by several technologies which were to be developed in the course of the work. The technologies included: (1) A low-pressure direct injection system; (2) A mass air flow sensor which would measure the net airflow into the engine on a per cycle basis; (3) A feedback control system enabled by measuring ionization current signals from the spark plug gap; and (4) An infinitely variable cam actuation system based on a pneumatic-hydraulic valve actuation These developments were supplemented by the use of advanced large eddy simulations as well as evaluations of fuel air mixing using the KIVA and WAVE models. The simulations were accompanied by experimental verification when possible. In this effort a solid base has been established for continued development of the advanced engine concepts originally proposed. Due to problems with the valve actuation system a complete demonstration of the engine concept originally proposed was not possible. Some of the highlights that were accomplished during this effort are: (1) A forward-backward mass air flow sensor has been developed and a patent application for the device has been submitted. We are optimistic that this technology will have a particular application in variable valve timing direct injection systems for IC engines. (2) The biggest effort on this project has involved the development of the pneumatic-hydraulic valve actuation system. This system was originally purchased from Cargine, a Swedish supplier and is in the development stage. To date we have not been able to use the actuators to control the exhaust valves, although the actuators have been successfully employed to control the intake valves. The reason for this is the additional complication associated with variable back pressure on the exhaust valves when they are opened. As a result of this effort, we have devised a new design and have filed for a patent on a method of control which is believed to overcome this problem. The engine we have been working with originally had a single camshaft which controlled both the intake and exhaust valves. Single cycle lift and timing control was demonstrated with this system. (3) Large eddy simulations and KIVA based simulations were used in conjunction with flow visualizations in an optical engine to study fuel air mixing. During this effort we have devised a metric for quantifying fuel distribution and it is described in several of our papers. (4) A control system has been developed to enable us to test the benefits of the various technologies. This system used is based on Opal-RT hardware and is being used in a current DOE sponsored program.

  2. Sodium dichromate expedited response action assessment

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The US Environmental Protection Agency (EPA) and Washington Department of Ecology (Ecology) recommended that the US Department of Energy (DOE) perform an expedited response action (ERA) for the Sodium Dichromate Barrel Disposal Landfill. The ERA lead regulatory agency is Ecology and EPA is the support agency. The ERA was categorized as non-time-critical, which required preparation of an engineering evaluation and cost analysis (EE/CA). The EE/CA was included in the ERA proposal. The EE/CA is a rapid, focused evaluation of available technologies using specific screening factors to assess feasibility, appropriateness, and cost. The ERA goal is to reduce the potential for any contaminant migration from the landfill to the soil column, groundwater, and Columbia River. Since the Sodium Dichromate Barrel Disposal Landfill is the only waste site within the operable unit, the removal action may be the final remediation of the 100-IU-4 Operable Unit. This ERA process started in March 1992. The ERA proposal went through a parallel review process with Westinghouse Hanford Company (WHC), DOE Richland Operations (RL), EPA, Ecology, and a 30-day public comment period. Ecology and EPA issued an Action Agreement Memorandum in March 1993 (Appendix A). The memorandum directed excavation of all anomalies and disposal of the collected materials at the Hanford Site Central Landfill. Primary field activities were completed by the end of April 1993. Final waste disposal of a minor quantity of hazardous waste was completed in July 1993.

  3. Sodium Reactor Experiment decommissioning. Final report

    SciTech Connect (OSTI)

    Carroll, J.W.; Conners, C.C.; Harris, J.M.; Marzec, J.M.; Ureda, B.F.

    1983-08-15

    The Sodium Reactor Experiment (SRE) located at the Rockwell International Field Laboratories northwest of Los Angeles was developed to demonstrate a sodium-cooled, graphite-moderated reactor for civilian use. The reactor reached full power in May 1958 and provided 37 GWh to the Southern California Edison Company grid before it was shut down in 1967. Decommissioning of the SRE began in 1974 with the objective of removing all significant radioactivity from the site and releasing the facility for unrestricted use. Planning documentation was prepared to describe in detail the equipment and techniques development and the decommissioning work scope. A plasma-arc manipulator was developed for remotely dissecting the highly radioactive reactor vessels. Other important developments included techniques for using explosives to cut reactor vessel internal piping, clamps, and brackets; decontaminating porous concrete surfaces; and disposing of massive equipment and structures. The documentation defined the decommissioning in an SRE dismantling plan, in activity requirements for elements of the decommissioning work scope, and in detailed procedures for each major task.

  4. SODIUM CYANIDE AS A FISH POISON Marine Biological Laboratory

    E-Print Network [OSTI]

    SODIUM CYANIDE AS A FISH POISON Marine Biological Laboratory APR 2 '^ 1958 WOODS HOLE, MASS CYANIDE AS A FISH POISON By W. R. Bridges Cooperative Fishery Research Laboratory Southern Illinois as a fish poison. At concentrations of 1 p. p.m. sodium cyanide and at a variety of temperature and p

  5. Computer analysis of sodium cold trap design and performance. [LMFBR

    SciTech Connect (OSTI)

    McPheeters, C.C.; Raue, D.J.

    1983-11-01

    Normal steam-side corrosion of steam-generator tubes in Liquid Metal Fast Breeder Reactors (LMFBRs) results in liberation of hydrogen, and most of this hydrogen diffuses through the tubes into the heat-transfer sodium and must be removed by the purification system. Cold traps are normally used to purify sodium, and they operate by cooling the sodium to temperatures near the melting point, where soluble impurities including hydrogen and oxygen precipitate as NaH and Na/sub 2/O, respectively. A computer model was developed to simulate the processes that occur in sodium cold traps. The Model for Analyzing Sodium Cold Traps (MASCOT) simulates any desired configuration of mesh arrangements and dimensions and calculates pressure drops and flow distributions, temperature profiles, impurity concentration profiles, and impurity mass distributions.

  6. Production of sodium-22 from proton irradiated aluminum

    DOE Patents [OSTI]

    Taylor, Wayne A. (Los Alamos, NM); Heaton, Richard C. (Los Alamos, NM); Jamriska, David J. (Los Alamos, NM)

    1996-01-01

    A process for selective separation of sodium-22 from a proton irradiated minum target including dissolving a proton irradiated aluminum target in hydrochloric acid to form a first solution including aluminum ions and sodium ions, separating a portion of the aluminum ions from the first solution by crystallization of an aluminum salt, contacting the remaining first solution with an anion exchange resin whereby ions selected from the group consisting of iron and copper are selectively absorbed by the anion exchange resin while aluminum ions and sodium ions remain in solution, contacting the solution with an cation exchange resin whereby aluminum ions and sodium ions are adsorbed by the cation exchange resin, and, contacting the cation exchange resin with an acid solution capable of selectively separating the adsorbed sodium ions from the cation exchange resin while aluminum ions remain adsorbed on the cation exchange resin is disclosed.

  7. Low temperature sodium-beta battery

    DOE Patents [OSTI]

    Farmer, Joseph C

    2013-11-19

    A battery that will operate at ambient temperature or lower includes an enclosure, a current collector within the enclosure, an anode that will operate at ambient temperature or lower within the enclosure, a cathode that will operate at ambient temperature or lower within the enclosure, and a separator and electrolyte within the enclosure between the anode and the cathode. The anode is a sodium eutectic anode that will operate at ambient temperature or lower and is made of a material that is in a liquid state at ambient temperature or lower. The cathode is a low melting ion liquid cathode that will operate at ambient temperature or lower and is made of a material that is in a liquid state at ambient temperature or lower.

  8. Update; Sodium advanced fast reactor (SAFR) concept

    SciTech Connect (OSTI)

    Oldenkamp, R.D.; Brunings, J.E. ); Guenther, E. ); Hren, R. )

    1988-01-01

    This paper reports on the sodium advanced fast reactor (SAFR) concept developed by the team of Rockwell International, Combustion Engineering, and Bechtel during the 3-year period extending from January 1985 to December 1987 as one element in the U.S. Department of Energy's Advanced Liquid Metal Reactor Program. In January 1988, the team was expanded to include Duke Engineering and Services, Inc., and the concept development was extended under DOE's Program for Improvement in Advanced Modular LMR Design. The SAFR plant concept employs a 450-MWe pool-type liquid metal cooled reactor as its basic module. The reactor assembly module is a standardized shop-fabricated unit that can be shipped to the plant site by barge for installation. Shop fabrication minimizes nuclear-grade field fabrication and reduces the plant construction schedule. Reactor modules can be used individually or in multiples at a given site to supply the needed generating capacity.

  9. Hydrogen generation systems utilizing sodium silicide and sodium silica gel materials

    DOE Patents [OSTI]

    Wallace, Andrew P.; Melack, John M.; Lefenfeld, Michael

    2015-07-14

    Systems, devices, and methods combine reactant materials and aqueous solutions to generate hydrogen. The reactant materials can sodium silicide or sodium silica gel. The hydrogen generation devices are used in fuels cells and other industrial applications. One system combines cooling, pumping, water storage, and other devices to sense and control reactions between reactant materials and aqueous solutions to generate hydrogen. Multiple inlets of varied placement geometries deliver aqueous solution to the reaction. The reactant materials and aqueous solution are churned to control the state of the reaction. The aqueous solution can be recycled and returned to the reaction. One system operates over a range of temperatures and pressures and includes a hydrogen separator, a heat removal mechanism, and state of reaction control devices. The systems, devices, and methods of generating hydrogen provide thermally stable solids, near-instant reaction with the aqueous solutions, and a non-toxic liquid by-product.

  10. Hydrogen generation systems and methods utilizing sodium silicide and sodium silica gel materials

    DOE Patents [OSTI]

    Wallace, Andrew P.; Melack, John M.; Lefenfeld, Michael

    2015-08-11

    Systems, devices, and methods combine thermally stable reactant materials and aqueous solutions to generate hydrogen and a non-toxic liquid by-product. The reactant materials can sodium silicide or sodium silica gel. The hydrogen generation devices are used in fuels cells and other industrial applications. One system combines cooling, pumping, water storage, and other devices to sense and control reactions between reactant materials and aqueous solutions to generate hydrogen. Springs and other pressurization mechanisms pressurize and deliver an aqueous solution to the reaction. A check valve and other pressure regulation mechanisms regulate the pressure of the aqueous solution delivered to the reactant fuel material in the reactor based upon characteristics of the pressurization mechanisms and can regulate the pressure of the delivered aqueous solution as a steady decay associated with the pressurization force. The pressure regulation mechanism can also prevent hydrogen gas from deflecting the pressure regulation mechanism.

  11. Decommissioning of Experimental Breeder Reactor - II Complex, Post Sodium Draining

    SciTech Connect (OSTI)

    J. A. Michelbacher; S. Paul Henslee; Collin J. Knight; Steven R. sherman

    2005-09-01

    The Experimental Breeder Reactor - II (EBR-II) was shutdown in September 1994 as mandated by the United States Department of Energy. This sodium-cooled reactor had been in service since 1964. The bulk sodium was drained from the primary and secondary systems and processed. Residual sodium remaining in the systems after draining was converted into sodium bicarbonate using humid carbon dioxide. This technique was tested at Argonne National Laboratory in Illinois under controlled conditions, then demonstrated on a larger scale by treating residual sodium within the EBR-II secondary cooling system, followed by the primary tank. This process, terminated in 2002, was used to place a layer of sodium bicarbonate over all exposed surfaces of sodium. Treatment of the remaining EBR-II sodium is governed by the Resource Conservation and Recovery Act (RCRA). The Idaho Department of Environmental Quality issued a RCRA Operating Permit in 2002, mandating that all hazardous materials be removed from EBR-II within a 10 year period, with the ability to extend the permit and treatment period for another 10 years. A preliminary plan has been formulated to remove the remaining sodium and NaK from the primary and secondary systems using moist carbon dioxide, steam and nitrogen, and a water flush. The moist carbon dioxide treatment was resumed in May 2004. As of August 2005, approximately 60% of the residual sodium within the EBR-II primary tank had been treated. This process will continue through the end of 2005, when it is forecast that the process will become increasingly ineffective. At that time, subsequent treatment processes will be planned and initiated. It should be noted that the processes and anticipated costs associated with these processes are preliminary. Detailed engineering has not been performed, and approval for these methods has not been obtained from the regulator or the sponsors.

  12. Sodium Recycle Economics for Waste Treatment Plant Operations

    SciTech Connect (OSTI)

    Sevigny, Gary J.; Poloski, Adam P.; Fountain, Matthew S.

    2008-08-31

    Sodium recycle at the Hanford Waste Treatment Plant (WTP) would reduce the number of glass canisters produced, and has the potential to significantly reduce the cost to the U.S. Department of Energy (DOE) of treating the tank wastes by hundreds of millions of dollars. The sodium, added in the form of sodium hydroxide, was originally added to minimize corrosion of carbon-steel storage tanks from acidic reprocessing wastes. In the baseline Hanford treatment process, sodium hydroxide is required to leach gibbsite and boehmite from the high level waste (HLW) sludge. In turn, this reduces the amount of HLW glass produced. Currently, a significant amount of additional sodium hydroxide will be added to the process to maintain aluminate solubility at ambient temperatures during ion exchange of cesium. The vitrification of radioactive waste is limited by sodium content, and this additional sodium mass will increase low-activity waste-glass mass. An electrochemical salt-splitting process, based on sodium-ion selective ceramic membranes, is being developed to recover and recycle sodium hydroxide from high-salt radioactive tank wastes in DOE’s complex. The ceramic membranes are from a family of materials known as sodium (Na)—super-ionic conductors (NaSICON)—and the diffusion of sodium ions (Na+) is allowed, while blocking other positively charged ions. A cost/benefit evaluation was based on a strategy that involves a separate caustic-recycle facility based on the NaSICON technology, which would be located adjacent to the WTP facility. A Monte Carlo approach was taken, and several thousand scenarios were analyzed to determine likely economic results. The cost/benefit evaluation indicates that 10,000–50,000 metric tons (MT) of sodium could be recycled, and would allow for the reduction of glass production by 60,000–300,000 MT. The cost of the facility construction and operation was scaled to the low-activity waste (LAW) vitrification facility, showing cost would be roughly $150 million to $400 million for construction and $10 million to $40 million per year for operations. Depending on the level of aluminate supersaturation allowed in the storage tanks in the LAW Pretreatment Facility, these values indicate a return on investment of up to 25% to 60%.

  13. Risk Management for Sodium Fast Reactors.

    SciTech Connect (OSTI)

    Denman, Matthew R; Groth, Katrina; Cardoni, Jeffrey N; Wheeler, Timothy A.

    2015-01-01

    Accident management is an important component to maintaining risk at acceptable levels for all complex systems, such as nuclear power plants. With the introduction of self - correcting, or inherently safe, reactor designs the focus has shifted from management by operators to allowing the syste m's design to manage the accident. While inherently and passively safe designs are laudable, extreme boundary conditions can interfere with the design attributes which facilitate inherent safety , thus resulting in unanticipated and undesirable end states. This report examines an inherently safe and small sodium fast reactor experiencing a beyond design basis seismic event with the intend of exploring two issues : (1) can human intervention either improve or worsen the potential end states and (2) can a Bayes ian Network be constructed to infer the state of the reactor to inform (1). ACKNOWLEDGEMENTS The author s would like to acknowledge the U.S. Department of E nergy's Office of Nuclear Energy for funding this research through Work Package SR - 14SN100303 under the Advanced Reactor Concepts program. The authors also acknowledge the PRA teams at A rgonne N ational L aborator y , O ak R idge N ational L aborator y , and I daho N ational L aborator y for their continue d contributions to the advanced reactor PRA mission area.

  14. GLASS FORMULATION FOR INEEL SODIUM BEARING WASTE

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Peeler, David K.

    2002-10-31

    Studies were performed to develop and test a glass formulation for immobilization of sodium-bearing waste (SBW), which is a high soda, acidic, high-activity waste stored at the Idaho National Engineering and Environmental Laboratory (INEEL) in 10 underground tanks. It was determined in previous studies that SBW?s sulfur content dictates its loading in borosilicate glasses to be melted by currently assumed processes. If the sulfur content (which is ~4.5 mass% SO3 on a non-volatile oxide basis in SBW) of the melter feed is too high, then a molten, alkali-sulfate-containing salt phase accumulates on the melt surface. The avoidance of salt accumulation during the melter process and the maximization of sulfur incorporation into the glass melt were the main focus of this development work. A glass was developed for 20 mass% SBW (on a non-volatile oxide basis), which contained 0.91 mass% SO3, that met all the processing and product-quality constraints determined for SBW vitrification at a planned INEEL treatment plant?SBW-22-20. This paper summarizes the formulation efforts and presents the data developed on a series of glasses with simulated SBW.

  15. Cotton response to over-the-top trifloxysulfuron sodium applications 

    E-Print Network [OSTI]

    Hoffman, Steven Matthew,1978-

    2003-01-01

    Envoke® (common name: trifloxysulfuron sodium), is a new sulfonylurea herbicide developed by Syngenta for over-the-top application to cotton. A two-year study was conducted with concurrent field and greenhouse experiments ...

  16. SLAM: a sodium-limestone concrete ablation model

    SciTech Connect (OSTI)

    Suo-Anttila, A.J.

    1983-12-01

    SLAM is a three-region model, containing a pool (sodium and reaction debris) region, a dry (boundary layer and dehydrated concrete) region, and a wet (hydrated concrete) region. The model includes a solution to the mass, momentum, and energy equations in each region. A chemical kinetics model is included to provide heat sources due to chemical reactions between the sodium and the concrete. Both isolated model as well as integrated whole code evaluations have been made with good results. The chemical kinetics and water migration models were evaluated separately, with good results. Several small and large-scale sodium limestone concrete experiments were simulated with reasonable agreement between SLAM and the experimental results. The SLAM code was applied to investigate the effects of mixing, pool temperature, pool depth and fluidization. All these phenomena were found to be of significance in the predicted response of the sodium concrete interaction. Pool fluidization is predicted to be the most important variable in large scale interactions.

  17. Loop simulation capability for sodium-cooled systems

    E-Print Network [OSTI]

    Adekugbe, Oluwole A.

    1984-01-01

    A one-dimensional loop simulation capability has been implemented in the thermal-hydraulic analysis code, THERMIT-4E. This code had been used to simulate and investigate flow in test sections of experimental sodium loops ...

  18. Reactor protection system design alternatives for sodium fast reactors

    E-Print Network [OSTI]

    DeWitte, Jacob D. (Jacob Dominic)

    2011-01-01

    Historically, unprotected transients have been viewed as design basis events that can significantly challenge sodium-cooled fast reactors. The perceived potential consequences of a severe unprotected transient in a ...

  19. Probabilistic transient analysis of fuel choices for sodium fast reactors

    E-Print Network [OSTI]

    Denman, Matthew R

    2011-01-01

    This thesis presents the implications of using a risk-informed licensing framework to inform the design of Sodium Fast Reactors. NUREG-1860, more commonly known as the Technology Neutral Framework (TNF), is a risk-informed ...

  20. Advanced sodium fast reactor accident source terms : research needs.

    SciTech Connect (OSTI)

    Powers, Dana Auburn; Clement, Bernard; Ohno, Shuji; Zeyen, Roland

    2010-09-01

    An expert opinion elicitation has been used to evaluate phenomena that could affect releases of radionuclides during accidents at sodium-cooled fast reactors. The intent was to identify research needed to develop a mechanistic model of radionuclide release for licensing and risk assessment purposes. Experts from the USA, France, the European Union, and Japan identified phenomena that could affect the release of radionuclides under hypothesized accident conditions. They qualitatively evaluated the importance of these phenomena and the need for additional experimental research. The experts identified seven phenomena that are of high importance and have a high need for additional experimental research: High temperature release of radionuclides from fuel during an energetic eventEnergetic interactions between molten reactor fuel and sodium coolant and associated transfer of radionuclides from the fuel to the coolantEntrainment of fuel and sodium bond material during the depressurization of a fuel rod with breached claddingRates of radionuclide leaching from fuel by liquid sodiumSurface enrichment of sodium pools by dissolved and suspended radionuclidesThermal decomposition of sodium iodide in the containment atmosphereReactions of iodine species in the containment to form volatile organic iodides. Other issues of high importance were identified that might merit further research as development of the mechanistic model of radionuclide release progressed.

  1. Adiabatic calorimetry (RSST and VSP) tests with sodium acetate

    SciTech Connect (OSTI)

    Kirch, N.W.

    1993-09-01

    As requested in the subject reference, adiabatic calorimetry (RSST and VSP) tests have been performed with sodium acetate covering TOC concentrations from 3 to 7% with the following results: Exothermic activity noted around 200{degrees}C. Propagating reaction initiated at about 300{degrees}C. Required TOC concentration for propagation estimated at about 6 w% (dry mixture) or about 20 w% sodium acetate. Heat of reaction estimated to be 3.7 MJ per kg of sodium acetate (based on VSP test with 3 w% TOC and using a dry mixture specific heat of 1000 J kg{sup {minus}1} K{sup {minus}1}). Based upon the above results we estimate that a moisture content in excess of 14 w% would prevent a propagating reaction of a stoichiometric mixture of fuel and oxidizer ({approximately} 38 w% sodium acetate and {approximately}62 w% sodium nitrate). Assuming that the fuel can be treated as sodium acetate equivalent, and considering that the moisture content in the organic containing waste generally is believed to be in excess of 14 w%, it follows that the possibility of propagating reactions in the Hanford waste tanks can be ruled out.

  2. Hydrogen storage in sodium aluminum hydride.

    SciTech Connect (OSTI)

    Ozolins, Vidvuds; Herberg, J.L.; McCarty, Kevin F.; Maxwell, Robert S.; Stumpf, Roland Rudolph; Majzoub, Eric H.

    2005-11-01

    Sodium aluminum hydride, NaAlH{sub 4}, has been studied for use as a hydrogen storage material. The effect of Ti, as a few mol. % dopant in the system to increase kinetics of hydrogen sorption, is studied with respect to changes in lattice structure of the crystal. No Ti substitution is found in the crystal lattice. Electronic structure calculations indicate that the NaAlH{sub 4} and Na{sub 3}AlH{sub 6} structures are complex-ionic hydrides with Na{sup +} cations and AlH{sub 4}{sup -} and AlH{sub 6}{sup 3-} anions, respectively. Compound formation studies indicate the primary Ti-compound formed when doping the material at 33 at. % is TiAl{sub 3} , and likely Ti-Al compounds at lower doping rates. A general study of sorption kinetics of NaAlH{sub 4}, when doped with a variety of Ti-halide compounds, indicates a uniform response with the kinetics similar for all dopants. NMR multiple quantum studies of solution-doped samples indicate solvent interaction with the doped alanate. Raman spectroscopy was used to study the lattice dynamics of NaAlH{sub 4}, and illustrated the molecular ionic nature of the lattice as a separation of vibrational modes between the AlH{sub 4}{sup -} anion-modes and lattice-modes. In-situ Raman measurements indicate a stable AlH{sub 4}{sup -} anion that is stable at the melting temperature of NaAlH{sub 4}, indicating that Ti-dopants must affect the Al-H bond strength.

  3. Natural Daylighting - An Energy Analysis 

    E-Print Network [OSTI]

    Jarrell, R. P.

    1987-01-01

    humid summer air is reduced. In winter, AS stated, thearchitectwascharged thep~~~iblel~~~~fheatthr~~ghe~fil- with designing a facility with two iden- tration is reduced by eliminatijlg the tical towers. To improve the constructs- large amount... AASSH-R A Fi--l ~oad 9-779 ~alcul -,-- - -- ation --- ------ MU LWD m LORD TOT& LWD --------- --------- --- JH 67,134,003 -2,787,923 69,921,926 FEB M, 161,188 -1,583,624 65,744,812 WIR 76,496,995 -648,647 77,195,642 R 80,936,670 -2,400 80...

  4. Tips for Daylighting with Windows

    SciTech Connect (OSTI)

    Robinson, Alastair; Selkowitz, Stephen

    2013-10-01

    These guidelines provide an integrated approach to the cost-effective design of perimeter zones in new commercial buildings and existing building retrofits. They function as a quick reference for building designers, through a set of easy steps and rules-of-thumb, emphasizing “how-to” practical details. References are given to more detailed sources of information, should the reader wish to go further. The design method used in this document emphasizes that building decisions should be made within the context of the whole building as a single functioning system rather than as an assembly of distinct parts. This integrated design approach looks at the ramifications of each individual system decision on the whole building. For example, the decision on glazing selection will have an effect on lighting, mechanical systems, and interior design. Therefore, the entire design team should participate and influence this glazing decision—which typically rests with the architect alone. The benefit of an integrated design approach is a greater chance of success towards long-term comfort and sustained energy savings in the building.

  5. DAYLIGHTING DIRECTORY 1/1980

    E-Print Network [OSTI]

    ,

    2012-01-01

    ~solar Radiation Data, Natural Lighting, and Building EnergySolar Radiation Data, Natural Lighting, and Building Energy

  6. Daylight metrics and energy savings

    E-Print Network [OSTI]

    Mardaljevic, John

    2011-01-01

    Research Establishment. BREEAM - The BRE Environmentalmost used rating systems are BREEAM (The BRE Environmentalof Understanding between BREEAM, LEED, the UK Green Building

  7. DAYLIGHTING DIRECTORY 1/1980

    E-Print Network [OSTI]

    ,

    2012-01-01

    PRESENTATIONS ' ~solar Radiation Data, Natural Lighting, andJUROVICS, S.A. "Solar Radiation Data, Natural Lighting, and

  8. Impact of Extended Daylight Saving

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing Tool Fits the Bill FinancingDepartmentDatabase|BlogProfile:Water Heaters |843 Impact

  9. Nanolens Window Coatings for Daylighting

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecialAPPENDIX FOrigin ofAllenDepartmentNYSERDA

  10. daylight | OpenEI Community

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop IncIowa (UtilityMichigan)data book Home Graham7781's picture

  11. OpenEI Community - daylight

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII JumpQuarterly Smart Grid Data available for download onst,/0 en BigArtby

  12. Sodium removal process development for LMFBR fuel subassemblies

    SciTech Connect (OSTI)

    Simmons, C.R.; Taylor, G.R.

    1981-10-01

    Two 37-pin scale models of Clinch River Breeder Reactor Plant fuel subassemblies were designed, fabricated and used at Westinghouse Advanced Reactors Division in the development and proof-testing of a rapid water-based sodium removal process for the ORNL Hot Experimental Facility, Liquid Metal Fast Breeder Reactor Fuel Reprocessing Cycle. Through a series of development tests on one of the models, including five (5) sodium wettings and three (3) high temperature sodium removal operations, optimum process parameters for a rapid water vapor-argon-water rinse process were identified and successfully proof-tested on a second model containing argon-pressurized, sodium-corroded model fuel pins simulating the gas plenum and cladding conditions expected for spent fuel pins in full scale subassemblies. Based on extrapolations of model proof test data, preliminary process parameters for a water vapor-nitrogen-water rinse process were calculated and recommended for use in processing full scale fuel subassemblies in the Sodium Removal Facility of the Fuel Receiving Cell, ORNL HEF.

  13. Intermediate-scale sodium-concrete reaction tests with basalt and limestone concrete

    SciTech Connect (OSTI)

    Hassberger, J.A.; Muhlestein, L.D.

    1981-01-01

    Ten tests were performed to investigate the chemical reactions and rate and extent of attack between sodium and basalt and limestone concretes. Test temperatures ranged from 510 to 870/sup 0/C (950 to 1600/sup 0/F) and test times from 2 to 24 hours. Sodium hydroxide was added to some of the tests to assess the impact of a sodium hydroxide-aided reaction on the overall penetration characteristics. Data suggest that the sodium penetration of concrete surfaces is limited. Penetration of basalt concrete in the presence of sodium hydroxide is shown to be less severe than attack by the metallic sodium alone. Presence of sodium hydroxide changes the characteristics of sodium penetration of limestone concrete, but no major differences in bulk penetration were observed as compared to penetration by metallic sodium.

  14. Thermodynamic assessment of microencapsulated sodium carbonate slurry for carbon capture

    SciTech Connect (OSTI)

    Stolaroff, Joshuah K.; Bourcier, William L.

    2014-01-01

    Micro-encapsulated Carbon Sorbents (MECS) are a new class of carbon capture materials consisting of a CO?- absorbing liquid solvent contained within solid, CO?-permeable, polymer shells. MECS enhance the rate of CO? absorption for solvents with slow kinetics and prevent solid precipitates from scaling and fouling equipment, two factors that have previously limited the use of sodium carbonate solution for carbon capture. Here, we examine the thermodynamics of sodium carbonate slurries for carbon capture. We model the vapour-liquid-solid equilibria of sodium carbonate and find several features that can contribute to an energy-efficient capture process: very high CO? pressures in stripping conditions, relatively low water vapour pressures in stripping conditions, and good swing capacity. The potential energy savings compared with an MEA system are discussed.

  15. Towards optimization of pulsed sodium laser guide stars

    E-Print Network [OSTI]

    Rampy, Rachel; Rochester, Simon M; Holzlohner, Ronald

    2015-01-01

    Pulsed sodium laser guide stars (LGS) are useful because they allow for Rayleigh blanking and fratricide avoidance in multiple-LGS systems. Bloch-equation simulations of sodium-light interactions show that these may be able to achieve photon returns nearly equal to, and in some cases greater than, what is seen from continuous-wave (CW) excitation. In this work, we study the time-dependent characteristics of sodium fluorescence, and investigate the optimal format for the new fiber laser LGS that will be part of the upgraded adaptive optics (AO) system on the Shane telescope at Mt. Hamilton. Results of this analysis are examined in the context of their general applicability to other LGS systems and the potential benefits of uplink correction are considered. Comparisons of simulation predictions with measurements from existing LGS are also presented and discussed.

  16. Thermodynamic assessment of microencapsulated sodium carbonate slurry for carbon capture

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stolaroff, Joshuah K.; Bourcier, William L.

    2014-01-01

    Micro-encapsulated Carbon Sorbents (MECS) are a new class of carbon capture materials consisting of a CO?- absorbing liquid solvent contained within solid, CO?-permeable, polymer shells. MECS enhance the rate of CO? absorption for solvents with slow kinetics and prevent solid precipitates from scaling and fouling equipment, two factors that have previously limited the use of sodium carbonate solution for carbon capture. Here, we examine the thermodynamics of sodium carbonate slurries for carbon capture. We model the vapour-liquid-solid equilibria of sodium carbonate and find several features that can contribute to an energy-efficient capture process: very high CO? pressures in stripping conditions,more »relatively low water vapour pressures in stripping conditions, and good swing capacity. The potential energy savings compared with an MEA system are discussed.« less

  17. An empirical modeling approach to high sodium glass durability

    SciTech Connect (OSTI)

    Shine, E.P.; Sadler, A.L.K. [Westinghouse Savannah River Company, Aiken, SC (United States)

    1996-12-31

    Empirical mixture models have been developed for chemical durability of high sodium borosilicate glass. The response of boron to a seven-day Product Consistency Test (PCT) was chosen as the measure of durability. The objective of the model development was to support the proposed vitrification of Hanford low-level waste (LLW), the bulk of which is primarily sodium oxide. A full first-order model and a second order model were developed from a database of high-sodium borosilicate glasses. First-order models proved to be satisfactory in a qualitative sense, but root mean squared errors were fairly large for quantitative predictive purposes. The results imply that mechanistic models relating durability to composition should include higher order compositional interactions; a second-order model yielded much improved statistics. The modeling results also suggest that calcium, which is considered a network modifier yet is also regarded as a glass {open_quotes}stiffener{close_quotes}, may improve durability.

  18. Method of forming and starting a sodium sulfur battery

    DOE Patents [OSTI]

    Paquette, David G. (Costa Mesa, CA)

    1981-01-01

    A method of forming a sodium sulfur battery and of starting the reactive capability of that battery when heated to a temperature suitable for battery operation is disclosed. An anodic reaction zone is constructed in a manner that sodium is hermetically sealed therein, part of the hermetic seal including fusible material which closes up openings through the container of the anodic reaction zone. The hermetically sealed anodic reaction zone is assembled under normal atmospheric conditions with a suitable cathodic reaction zone and a cation-permeable barrier. When the entire battery is heated to an operational temperature, the fusible material of the hermetically sealed anodic reaction zone is fused, thereby allowing molten sodium to flow from the anodic reaction zone into reactive engagement with the cation-permeable barrier.

  19. Simulation of ultrasonic inspection for sodium cooled reactors using CIVA

    SciTech Connect (OSTI)

    Reverdy, F. [CEA, LIST, Departement Imagerie et Simulation Pour Le Controle, F-91191 Gif-sur-Yvette (France); Baque, F. [CEA, DEN DTN, 13108 Saint Paul lez Durance Cedex (France); Lu, B.; Jezzine, K.; Dorval, V. [CEA, LIST, Departement Imagerie et Simulation Pour Le Controle, F-91191 Gif-sur-Yvette (France); Augem, J. M. [EDF, 12-14 avenue dutrievoz, 69628 Villeurbanne (France)

    2011-07-01

    In-service inspection of sodium fast reactors (SFR) requires the development of non-destructive techniques adapted to the harsh conditions of the environment (opaque and hot) and the complexity of the examination (large and littered reactor block). Ultrasonic techniques are seen as suitable candidates for the inspection of SFRs and two approaches are being followed: inside inspection where transducers are directly immersed in sodium coolant and inspection from outside with transducers positioned along the wall of the main vessel. Probe design and inspection performances can be predicted by using comprehensive models that can take into account the various variables of the problem. These models are explained in this paper. (authors)

  20. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.; Bonnesen, Peter V.; Bryan, Jeffrey C.; Haverlock, Tamara J.

    2002-03-30

    This research has focused on new liquid-liquid extraction chemistry applicable to separation of major sodium salts from alkaline tank waste. It was the overall goal to provide the scientific foundation upon which the feasibility of liquid-liquid extraction chemistry for bulk reduction of the volume of tank waste can be evaluated. Sodium hydroxide represented the initial test case and primary focus. It is a primary component of the waste1 and has the most value for recycle. A full explanation of the relevance of this research to USDOE Environmental Management needs will be given in the Relevance, Impact, and Technology Transfer section below. It should be noted that this effort was predicated on the need for sodium removal primarily from low-activity waste, whereas evolving needs have shifted attention to volume reduction of the high-activity waste. The results of the research to date apply to both applications, though treatment of high-activity wastes raises new questions that will be addressed in the renewal period. Toward understanding the extractive chemistry of sodium hydroxide and other sodium salts, it was the intent to identify candidate extractants and determine their applicable basic properties regarding selectivity, efficiency, speciation, and structure. A hierarchical strategy was to be employed in which the type of liquid-liquid-extraction system varied in sophistication from simple, single-component solvents to solvents containing designer host molecules. As an aid in directing this investigation toward addressing the fundamental questions having the most value, a conceptualization of an ideal process was advanced. Accordingly, achieving adequate selectivity for sodium hydroxide represented a primary goal, but this result is worthwhile for waste applications only if certain conditions are met.

  1. Agrin regulation of alpha3 sodium-potassium ATPase activity modulates cardiac myocyte contraction.

    E-Print Network [OSTI]

    2009-01-01

    in the U.S.A. Agrin Regulation of ? 3 Sodium-Potassiumis modulated by agrin regulation of ? 3 Na,K-ATPasegated sodium channels, capa- regulation of cardiac myocyte

  2. 4June2013 Page 1 of 8 Sodium Hydroxide (Pellets) SOP Standard Operating Procedures

    E-Print Network [OSTI]

    Cohen, Ronald C.

    4June2013 Page 1 of 8 Sodium Hydroxide (Pellets) SOP Standard Operating Procedures Strong Corrosives ­ Strong Bases (SB) Sodium Hydroxide (Pellets) PrintOH Form: pellets Color: white Melting point/freezing point: 318 °C (604 °F

  3. Sodium-Doped Molybdenum Targets for Controllable Sodium Incorporation in CIGS Solar Cells: Preprint

    SciTech Connect (OSTI)

    Mansfield, L. M.; Repins, I. L.; Glynn, S.; Carducci, M. D.; Honecker, D. M.; Pankow, J.; Young, M.; DeHart, C.; Sundaramoorthy, R.; Beall, C. L.; To, B.

    2011-07-01

    The efficiency of Cu(In,Ga)Se2 (CIGS) solar cells is enhanced when Na is incorporated in the CIGS absorber layer. This work examines Na incorporation in CIGS utilizing Na-doped Mo sputtered from targets made with sodium molybdate-doped (MONA) powder. Mo:Na films with varying thicknesses were sputtered onto Mo-coated borosilicate glass (BSG) or stainless steel substrates for CIGS solar cells. By use of this technique, the Na content of CIGS can be varied from near-zero to higher than that obtained from a soda-lime glass (SLG) substrate. Targets and deposition conditions are described. The doped Mo films are analyzed, and the resulting devices are compared to devices fabricated on Mo-coated SLG as well as Mo-coated BSG with NaF. Completed devices utilizing MONA exceeded 15.7% efficiency without anti-reflective coating, which was consistently higher than devices prepared with the NaF precursor. Strategies for minimizing adhesion difficulties are presented.

  4. Fluorescence Probe Studies of Gelatin-Sodium Dodecyl Sulfate Interactions

    E-Print Network [OSTI]

    Bales, Barney

    Fluorescence Probe Studies of Gelatin-Sodium Dodecyl Sulfate Interactions P. C. Griffiths* and J. A dodecyl sulfate (SDS) micelles bound to gelatin have been studied by fluorescence using 8-anilino-1-naphththalene sulfonic acid (ANS) as probe. Like gelatin, ANS binds in the region of the micelle occupied

  5. Laboratory-scale sodium-carbonate aggregate concrete interactions. [LMFBR

    SciTech Connect (OSTI)

    Westrich, H.R.; Stockman, H.W.; Suo-Anttila, A.

    1983-09-01

    A series of laboratory-scale experiments was made at 600/sup 0/C to identify the important heat-producing chemical reactions between sodium and carbonate aggregate concretes. Reactions between sodium and carbonate aggregate were found to be responsible for the bulk of heat production in sodium-concrete tests. Exothermic reactions were initiated at 580+-30/sup 0/C for limestone and dolostone aggregates as well as for hydrated limestone concrete, and at 540+-10/sup 0/C for dehydrated limestone concrete, but were ill-defined for dolostone concrete. Major reaction products included CaO, MgO, Na/sub 2/CO/sub 3/, Na/sub 2/O, NaOH, and elemental carbon. Sodium hydroxide, which forms when water is released from cement phases, causes slow erosion of the concrete with little heat production. The time-temperature profiles of these experiments have been modeled with a simplified version of the SLAM computer code, which has allowed derivation of chemical reaction rate coefficients.

  6. Method of Manufacturing Micro-Disperse Particles of Sodium Borohydride

    DOE Patents [OSTI]

    Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester. Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

    2008-09-23

    A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

  7. Method of generating hydrogen gas from sodium borohydride

    DOE Patents [OSTI]

    Kravitz, Stanley H. (Placitas, NM); Hecht, Andrew M. (Sandia Park, NM); Sylwester, Alan P. (Albuquerque, NM); Bell, Nelson S. (Albuquerque, NM)

    2007-12-11

    A compact solid source of hydrogen gas, where the gas is generated by contacting water with micro-disperse particles of sodium borohydride in the presence of a catalyst, such as cobalt or ruthenium. The micro-disperse particles can have a substantially uniform diameter of 1-10 microns, and preferably about 3-5 microns. Ruthenium or cobalt catalytic nanoparticles can be incorporated in the micro-disperse particles of sodium borohydride, which allows a rapid and complete reaction to occur without the problems associated with caking and scaling of the surface by the reactant product sodium metaborate. A closed loop water management system can be used to recycle wastewater from a PEM fuel cell to supply water for reacting with the micro-disperse particles of sodium borohydride in a compact hydrogen gas generator. Capillary forces can wick water from a water reservoir into a packed bed of micro-disperse fuel particles, eliminating the need for using an active pump.

  8. Immobilization of sodium nitrate waste with polymers: Topical report

    SciTech Connect (OSTI)

    Franz, E.M.; Heiser, J.H. III; Colombo, P.

    1987-04-01

    This report describes the development of solidification systems for sodium nitrate waste. Sodium nitrate waste was solidified in the polymers polyethylene, polyester-styrene (PES), and water-extendible polyester-styrene (WEP). Evaluations were made of the properties of waste forms containing various amounts of sodium nitrate by leaching immersion in water, measuring compressive strengths and by the EPA Extraction Procedure. Results of the leaching test are presented as cumulative fraction leached (CFL), incremental leaching rate, and average leaching indices (LI). For waste forms containing 30 to 70 wt% sodium nitrate, the CFL ranged from 9.0 x 10/sup -3/ to 7.3 x 10/sup -1/ and the LI from 11 to 7.8. After ninety days immersion in water, the compressive strengths ranged from 720 psi to 2550 psi. The nitrate releases from these samples using the EPA Extraction Procedure were below 500 ppM. The nitrate releases from PES waste forms were similar to those from polyethylene waste forms at the same waste loadings. The compressive yield strengths, measured after ninety-day immersion in water, ranged between 2070 and 7710 psi. In the case of WEP waste forms, only 30 wt% loaded samples passed the immersion test. 23 refs., 24 figs., 12 tabs.

  9. Go No-Go Recommendation for Sodium Borohydride for On-Board Vehicular Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    Independent review panel recommendation for go/no go decision on use of hydrolysis of sodium borohydride for hydrogen storage.

  10. Method of and apparatus for removing silicon from a high temperature sodium coolant

    DOE Patents [OSTI]

    Yunker, W.H.; Christiansen, D.W.

    1983-11-25

    This patent discloses a method of and system for removing silicon from a high temperature liquid sodium coolant system for a nuclear reactor. The sodium is cooled to a temperature below the silicon saturation temperature and retained at such reduced temperature while inducing high turbulence into the sodium flow for promoting precipitation of silicon compounds and ultimate separation of silicon compound particles from the liquid sodium.

  11. Ultracold Molecules from Ultracold Atoms: Interactions in Sodium and Lithium Gas

    E-Print Network [OSTI]

    Ultracold Molecules from Ultracold Atoms: Interactions in Sodium and Lithium Gas by Caleb from Ultracold Atoms: Interactions in Sodium and Lithium Gas by Caleb A Christensen Submitted of Philosophy Abstract The thesis presents results from experiments in which ultracold Sodium-6 and Lithium-23

  12. Fluctuations and State Preparation in Quantum Degenerate Gases of Sodium and Lithium

    E-Print Network [OSTI]

    Fluctuations and State Preparation in Quantum Degenerate Gases of Sodium and Lithium by Edward Su and State Preparation in Quantum Degenerate Gases of Sodium and Lithium by Edward Su Submitted- periments with sodium and lithium in optical lattices. We describe progress towards the implementation

  13. A study of boiling water flow regimes at low pressures

    E-Print Network [OSTI]

    Fiori, Mario P.

    1966-01-01

    "A comprehensive experimental program to examine flow regimes at pressures below 100 psia for boiling of water in tubes was carried out. An electrical probe, which measures the resistance of the fluid between the centerline ...

  14. Stable levitation and dynamics of ice particles at low pressures

    E-Print Network [OSTI]

    Nicholas Kowalski; Bernard Xie; Colin V. Parker; Cheng Chin

    2015-04-13

    We demonstrate stable levitation and trapping of ice particles of 30~200 micon at low background gas pressures in the presence of a temperature gradient. The thermophoretic force levitates the particles, which have long lifetimes of over an hour. The equilibrium position depends on the background pressure and temperature gradient, which is consistent with theoretical expectations. Furthermore, we investigate interesting launching and merging dynamics of the levitated particles, as well as the development of instability at high background pressures. Our system provides a robust platform to investigate the aggregation of floating ice particles in air, and potentially chemical and biological processes in a microgravity environment.

  15. Low-pressure debris dispersal from scaled reactor cavities

    SciTech Connect (OSTI)

    Nichols, R.T.; Tarbell, W.W.

    1988-01-01

    During a severe nuclear reactor accident, degradation of the core may result in debris accumulating in the lower head. Upon failure of the head, the melt may be ejected under pressure through the cavity and into the containment building. Under low system pressure conditions, understanding the mechanisms of debris dispersal is instrumental in assessing the response of the containment to pressurized melt ejection. Current analytical approaches rely on empirical correlations for debris entrainment criteria and very simple gas flow patterns in the cavity. The work reported here is directed toward performing scaled experiments that will develop a data base for refined scaling analyses. Subsequently, extrapolations from the analyses to reactor scale may be performed to provide insight for accident predictions. Mechanistic models for gas flow through the cavity and entrainment of the debris are also being developed from the results presented here. The objective of the test matrix is to vary key parameters to assess the effect on the physical processes of dispersal of the melt from the reactor cavity at low system pressures.

  16. Giant barocaloric effect at low pressure in ferrielectric ammonium sulphate

    E-Print Network [OSTI]

    Lloveras, P.; Stern-Taulats, E.; Barrio, M.; Tamarit, J.-Ll.; Crossley, S.; Li, W.; Pomjakushin, V.; Planes, A.; Mañosa, Ll.; Mathur, N. D.; Moya, X.

    2015-08-11

    ,3,* 1 Departament de Física i Enginyeria Nuclear, ETSEIB, Universitat Politècnica de Catalunya, Diagonal 647, Barcelona, 08028 Catalonia, Spain. 2 Facultat de Física, Departament d’Estructura i Constituents de la Matèria, Universitat de Barcelona... cooling, but existing refrigeration and air-conditioning units rely primarily on the compression and expansion of environmentally harmful fluids. Resurgent interest in solid materials that display magnetically, electrically and mechanically driven phase...

  17. Exhaust Aftertreatment and Low Pressure Loop EGR Applied to an...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Full Useful Life (120,000 miles) Exhaust Emission Performance of a NOx Adsorber and Diesel Particle Filter Equipped Passenger Car...

  18. THE ABSORPTION OF HYDROGEN ON LOW PRESSURE HYDRIDE MATERIALS

    SciTech Connect (OSTI)

    Morgan, G.; Korinko, P.

    2012-04-03

    For this study, hydrogen getter materials (Zircaloy-4 and pure zirconium) that have a high affinity for hydrogen (and low overpressure) have been investigated to determine the hydrogen equilibrium pressure on Zircaloy-4 and pure zirconium. These materials, as with most getter materials, offered significant challenges to overcome given the low hydrogen equilibrium pressure for the temperature range of interest. Hydrogen-zirconium data exists for pure zirconium at 500 C and the corresponding hydrogen overpressure is roughly 0.01 torr. This manuscript presents the results of the equilibrium pressures for the absorption and desorption of hydrogen on zirconium materials at temperatures ranging from 400 C to 600 C. The equilibrium pressures in this temperature region range from 150 mtorr at 600 C to less than 0.1 mtorr at 400 C. It has been shown that the Zircaloy-4 and zirconium samples are extremely prone to surface oxidation prior to and during heating. This oxidation precludes the hydrogen uptake, and therefore samples must be heated under a minimum vacuum of 5 x 10{sup -6} torr. In addition, the Zircaloy-4 samples should be heated at a sufficiently low rate to maintain the system pressure below 0.5 mtorr since an increase in pressure above 0.5 mtorr could possibly hinder the H{sub 2} absorption kinetics due to surface contamination. The results of this study and the details of the testing protocol will be discussed.

  19. Low pressure EGR system having full range capability

    DOE Patents [OSTI]

    Easley, Jr. William Lanier (West Peoria, IL); Milam, David Michael (Dunlap, IL); Roozenboom, Stephan Donald (Washington, IL); Bond, Michael Steven (Chillicothe, IL); Kapic, Amir (Dunlap, IL)

    2009-09-22

    An exhaust treatment system for an engine is disclosed and may have an air induction circuit, an exhaust circuit, and an exhaust recirculation circuit. The air induction circuit may be configured to direct air into the engine. The exhaust circuit may be configured to direct exhaust from the engine and include a turbine driven by the exhaust, a particulate filter disposed in series with and downstream of the turbine, and a catalytic device disposed in series with and downstream of the particulate filter. The exhaust recirculation circuit may be configured to selectively redirect at least some of the exhaust from between the particulate filter and the catalytic device to the air induction circuit. The catalytic device is selected to create backpressure within the exhaust circuit sufficient to ensure that, under normal engine operating conditions above low idle, exhaust can flow into the air induction circuit without throttling of the air.

  20. Use Vapor Recompression to Recover Low-Pressure Waste Steam,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    that it can be reused. Vapor recompression relies upon a mechanical compressor or steam jet ejector to increase the temperature of the latent heat in steam to render it usable for...

  1. Low-pressure-ratio regenerative exhaust-heated gas turbine

    SciTech Connect (OSTI)

    Tampe, L.A.; Frenkel, R.G.; Kowalick, D.J.; Nahatis, H.M.; Silverstein, S.M.; Wilson, D.G.

    1991-01-01

    A design study of coal-burning gas-turbine engines using the exhaust-heated cycle and state-of-the-art components has been completed. In addition, some initial experiments on a type of rotary ceramic-matrix regenerator that would be used to transfer heat from the products of coal combustion in the hot turbine exhaust to the cool compressed air have been conducted. Highly favorable results have been obtained on all aspects on which definite conclusions could be drawn.

  2. Synthesis of YBCO Superconductors Using Low-Pressure Processing - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With LivermoreSustainable Land Lab TourSwitchSynopticHydrogen

  3. Alternative Strategies for Low Pressure End Uses | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p a l De p u t y AEfficiency Rebate ProgramsAlpena<fuelalternative

  4. Effects of the mycotoxin penicillic acid on electrogenic sodium transport 

    E-Print Network [OSTI]

    Wilczynski, Teresa Anne

    1983-01-01

    OF SCIENCE May 1983 Major Subject: Food Science and Technology EFFECTS OF THE MYCOTOXIN PENICILLIC ACID ON ELECTRUUENIC SOUIUM TRANSPORT A Thesis by TERESA ANNE WILCZYNSKI Approved as to style and content by: T. D. Phi ll ps (Chairman of Committee...) E. E. ms (Hem~) N. D. Hei del baug (Member ) C. W. Uill (Member ) N. D. Heidelbaugh (Head of Department) May 1983 ABSTRACT Effects of the Mycotoxin Penici1 lie Acid on Electrogeni c Sodium Transport (May 1983) Teresa Anne Wilczynski, B...

  5. Sodium Dichromate Barrel Landfill expedited response action proposal

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The US Environmental Protection Agency (EPA) and Washington State Department of Ecology (Ecology) recommended that the US Department of Energy (DOE) prepare an expedited response action (ERA) for the Sodium Dichromate Barrel Landfill. The Sodium Dichromate Barrel Disposal Site was used in 1945 for disposal of crushed barrels. The site location is the sole waste site within the 100-IU-4 Operable Unit. The Waste Information Data System (WIDS 1992) assumes that the crushed barrels contained 1% residual sodium dichromate at burial time and that only buried crushed barrels are at the site. Burial depth is shallow since visual inspection finds numerous barrel debris on the surface. A non-time-critical ERA proposal includes preparation of an engineering evaluation and cost analysis (EE/CA) section. The EE/CA is a rapid, focused evaluation of available technologies using specific screening factors to assess feasibility, appropriateness, and cost. The ERA goal is to reduce the potential for any contaminant migration from the landfill to the soil column, groundwater, and Columbia River. Since the landfill is the only waste site within the operable unit, the ERA will present a final remediation of the 100-IU-4 operable unit.

  6. Sodium meta-autunite colloids: Synthesis, characterization,stability

    SciTech Connect (OSTI)

    zzuoping@lbl.gov

    2004-04-10

    Waste forms of U such as those in the United States Department of Energy's Hanford Site often contain high concentrations of Na and P. Low solubility sodium uranyl phosphates such as sodium meta-autunite have the potential to form mobile colloids that can facilitate transport of this radionuclide. In order to understand the geochemical behavior of uranyl phosphate colloids, we synthesized sodiummeta-autunite colloids, and characterized their morphology, chemical composition, structure, dehydration, and surface charge. The stability of these synthetic plate-shaped colloids was tested with respect to time and pH. The highest aggregation rate was observed at pH 3, and the rate decreases as pH increases, indicating that higher stability of colloid dispersion under neutral and alkaline pH conditions. The synthetic colloids are all negatively charged and no isoelectric points were found over a pH range of 3 to 9. The zeta-potentials of the colloids in the phosphate solution show a strong pH-dependence in the more acidic range over time, but are relatively constant in the neutral and alkaline pH range. The geochemical behavior of the synthetic colloids can be interpreted using DLVO theory. The results suggest that formation of mobile sodium meta-autunite colloids can enhance the transport of U in some contaminated sediments.

  7. Sodium-Bearing Waste Treatment, Applied Technology Plan

    SciTech Connect (OSTI)

    Lance Lauerhass; Vince C. Maio; S. Kenneth Merrill; Arlin L. Olson; Keith J. Perry

    2003-06-01

    Settlement Agreement between the Department of Energy and the State of Idaho mandates treatment of sodium-bearing waste at the Idaho Nuclear Technology and Engineering Center within the Idaho National Engineering and Environmental Laboratory. One of the requirements of the Settlement Agreement is to complete treatment of sodium-bearing waste by December 31, 2012. Applied technology activities are required to provide the data necessary to complete conceptual design of four identified alternative processes and to select the preferred alternative. To provide a technically defensible path forward for the selection of a treatment process and for the collection of needed data, an applied technology plan is required. This document presents that plan, identifying key elements of the decision process and the steps necessary to obtain the required data in support of both the decision and the conceptual design. The Sodium-Bearing Waste Treatment Applied Technology Plan has been prepared to provide a description/roadmap of the treatment alternative selection process. The plan details the results of risk analyzes and the resulting prioritized uncertainties. It presents a high-level flow diagram governing the technology decision process, as well as detailed roadmaps for each technology. The roadmaps describe the technical steps necessary in obtaining data to quantify and reduce the technical uncertainties associated with each alternative treatment process. This plan also describes the final products that will be delivered to the Department of Energy Idaho Operations Office in support of the office's selection of the final treatment technology.

  8. Sodium Chloride interaction with solvated and crystalline cellulose : sodium ion affects the tetramer and fibril in aqueous solution

    E-Print Network [OSTI]

    Bellesia, Giovanni

    2013-01-01

    Inorganic salts are a natural component of biomass which have a significant effect on the product yields from a variety of biomass conversion processes. Understanding their effect on biomass at the microscopic level can help discover their mechanistic role. We present a study of the effect of aqueous sodium chloride (NaCl) on the largest component of biomass, cellulose, focused on the thermodynamic and structural effect of a sodium ion on the cellulose tetramer, and fibril. Replica exchange molecular dynamics simulations of a cellulose tetramer reveal a number of preferred cellulose-Na contacts and bridging positions. Large scale MD simulations on a model cellulose fibril find that Na+ perturbs the hydroxymethyl rotational state population and consequently disrupts the "native" hydrogen bonding network.

  9. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2001-06-01

    Disposal of high-level nuclear waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  10. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.

    2000-06-01

    Disposal of high- level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Treatment processes themselves can exacerbate the problem by adding further volume to the waste. Waste retrieval and sludge washing, for example, will require copious amounts of sodium hydroxide. If the needed sodium hydroxide could be separated from the waste and recycled, however, the addition of fresh sodium hydroxide could be avoided, ultimately reducing the final waste volume and associated disposal costs. The major objective of this research is to explore new liquid- liquid extraction approaches to the selective separation of sodium hydroxide from alkaline high-level wastes stored in underground tanks at the Hanford and Savannah River sites. Consideration is also given to separating potassium and abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  11. Modelling of ultrasonic propagation in turbulent liquid sodium with temperature gradient

    SciTech Connect (OSTI)

    Massacret, N. [CEA, DEN, Nuclear Technology Department, F-13108 Saint-Paul-Lez-Durance (France); Aix-Marseille Université, LMA UPR 7051 CNRS, site LCND, 13625 Aix-en-Provence (France); Moysan, J., E-mail: joseph.moysan@univ-amu.fr; Ploix, M. A.; Corneloup, G. [Aix-Marseille Université, LMA UPR 7051 CNRS, site LCND, 13625 Aix-en-Provence (France); Jeannot, J. P. [CEA, DEN, Nuclear Technology Department, F-13108 Saint-Paul-Lez-Durance (France)

    2014-05-28

    The use of ultrasonic instrumentation in sodium-cooled fast reactors requires to understand and to predict how ultrasonic waves can be deflected, slowed down or speeded up, depending on the thermo-hydraulic characteristics of the liquid sodium. These thermo-hydraulic characteristics are mainly the local temperature and flow speed of the sodium. In this study we show that ray theory can be used to simulate ultrasonic propagation in a medium similar to the core of a sodium-cooled fast reactor, in order to study ultrasonic instrumentation and prepare it installation and utilisation in the sodium of the nuclear reactor. A suitable model has been developed and a set of thermo-hydraulics data has been created, taking account of the particularities of the sodium flow. The results of these simulations are then analysed within the framework of acoustic thermometry, in order to determine which disturbance must be taken into account for the correct operation of the temperature measurement.

  12. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.; Bonnesen, Peter V.

    2006-06-01

    The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of low-activity waste immobilization. Principles of ion recognition are being researched toward discovery of liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudohydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Studies at PNNL are directed toward new solvent formulation for the practical sodium pseudohydroxide extraction systems.

  13. Validation of CONTAIN-LMR code for accident analysis of sodium-cooled fast reactor containments

    SciTech Connect (OSTI)

    Gordeev, S.; Hering, W.; Schikorr, M.; Stieglitz, R.

    2012-07-01

    CONTAIN-LMR 1 is an analytical tool for the containment performance of sodium cooled fast reactors. In this code, the modelling for the sodium fire is included: the oxygen diffusion model for the sodium pool fire, and the liquid droplet model for the sodium spray fire. CONTAIN-LMR is also able to model the interaction of liquid sodium with concrete structure. It may be applicable to different concrete compositions. Testing and validation of these models will help to qualify the simulation results. Three experiments with sodium performed in the FAUNA facility at FZK have been used for the validation of CONTAIN-LMR. For pool fire tests, calculations have been performed with two models. The first model consists of one gas cell representing the volume of the burn compartment. The volume of the second model is subdivided into 32 coupled gas cells. The agreement between calculations and experimental data is acceptable. The detailed pool fire model shows less deviation from experiments. In the spray fire, the direct heating from the sodium burning in the media is dominant. Therefore, single cell modeling is enough to describe the phenomena. Calculation results have reasonable agreement with experimental data. Limitations of the implemented spray model can cause the overestimation of predicted pressure and temperature in the cell atmosphere. The ability of the CONTAIN-LMR to simulate the sodium pool fire accompanied by sodium-concrete reactions was tested using the experimental study of sodium-concrete interactions for construction concrete as well as for shielding concrete. The model provides a reasonably good representation of chemical processes during sodium-concrete interaction. The comparison of time-temperature profiles of sodium and concrete shows, that the model requires modifications for predictions of the test results. (authors)

  14. DRESDYN - A new facility for MHD experiments with liquid sodium

    E-Print Network [OSTI]

    Stefani, F; Gerbeth, G; Giesecke, A; Gundrum, Th; Steglich, C; Weier, T; Wustmann, B

    2012-01-01

    The DREsden Sodium facility for DYNamo and thermohydraulic studies (DRESDYN) is intended as a platform both for large scale experiments related to geo- and astrophysics as well as for experiments related to thermohydraulic and safety aspects of liquid metal batteries and liquid metal fast reactors. The most ambitious projects in the framework of DRESDYN are a homogeneous hydromagnetic dynamo driven solely by precession and a large Taylor-Couette type experiment for the combined investigation of the magnetorotational instability and the Tayler instability. In this paper we give a short summary about the ongoing preparations and delineate the next steps for the realization of DRESDYN.

  15. Nanofriction on Sodium Polystyrene Sulfonate Brushes in Water

    E-Print Network [OSTI]

    Takuya Fujima; Eitaro Futakuchi; Fumihiro Kino

    2014-02-19

    We investigated the frictional properties of sodium polystyrene sulfonate (NaPSS) brushes in water by frictional force microscopy (FFM). Polyelectrolyte brushes were prepared on silicon wafers by the grafting-to method. The brushes considerably reduce the frictional force and coefficient of kinetic friction compared to hydrodynamic lubrication on a smooth Si wafer. Frictional force is independent of sliding speed, but is lower for lower degrees of NaPSS polymerization. Nanoindentation tests indicate that the polymer chains in a brush are stretched strongly away from the substrate. These results suggest that polymer chains point support the FFM probe tip in water and reduced contact area and friction.

  16. Startup of the FFTF sodium cooled reactor. [Acceptance Test Program

    SciTech Connect (OSTI)

    Redekopp, R.D.; Umek, A.M.

    1981-03-01

    The Fast Flux Test Facility (FFTF), located on the Department of Energy (DOE) Hanford Reservation near Richland, Washington, is a 3 Loop 400 MW(t) sodium cooled fast reactor with a primary mission to test fuels and materials for development of the Liquid Metal Fast Breeder Reactor (LMFBR). Bringing FFTF to a condition to accomplish this mission is the goal of the Acceptance Test Program (ATP). This program was the mechanism for achieving startup of the FFTF. Highlights of the ATP involving the system inerting, liquid metal and inerted cell testing and initial ascent to full power are discussed.

  17. EIS-0306: Treatment and Management of Sodium-Bonded Spent Nuclear Fuel

    Broader source: Energy.gov [DOE]

    DOE prepared a EIS that evaluated the potential environmental impacts of treatment and management of DOE-owned sodium bonded spent nuclear fuel.

  18. PERFORMANCE OF SODIUM-BETA ALUMINA SOLID ELECTROLYTE IN Na/S CELLS

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2014-01-01

    SODIUM-BETA ALUMINA SOLID ELECTROLYTE IN Na/S CELLS Lutgardium-be ta alumina type solid electrolytes i s limit ed by

  19. Sodium fast reactor safety and licensing research plan. Volume I.

    SciTech Connect (OSTI)

    Sofu, Tanju; LaChance, Jeffrey L.; Bari, R.; Wigeland, Roald; Denman, Matthew R.; Flanagan, George F.

    2012-05-01

    This report proposes potential research priorities for the Department of Energy (DOE) with the intent of improving the licensability of the Sodium Fast Reactor (SFR). In support of this project, five panels were tasked with identifying potential safety-related gaps in available information, data, and models needed to support the licensing of a SFR. The areas examined were sodium technology, accident sequences and initiators, source term characterization, codes and methods, and fuels and materials. It is the intent of this report to utilize a structured and transparent process that incorporates feedback from all interested stakeholders to suggest future funding priorities for the SFR research and development. While numerous gaps were identified, two cross-cutting gaps related to knowledge preservation were agreed upon by all panels and should be addressed in the near future. The first gap is a need to re-evaluate the current procedures for removing the Applied Technology designation from old documents. The second cross-cutting gap is the need for a robust Knowledge Management and Preservation system in all SFR research areas. Closure of these and the other identified gaps will require both a reprioritization of funding within DOE as well as a re-evaluation of existing bureaucratic procedures within the DOE associated with Applied Technology and Knowledge Management.

  20. Non destructive examination of immersed structures within liquid sodium

    SciTech Connect (OSTI)

    Baque, F.; Paumel, K.; Corneloup, G.; Ploix, M. A.; Augem, J. M.

    2011-07-01

    The In Service Inspection of internal structures of future liquid sodium cooled fast reactors implies, among different options, the use of ultrasounds from the outside of sodium circuit. In these conditions, ultrasounds have to propagate through the metallic envelope of main vessel, then other immersed plates. Thus the study aims at mastering ultrasonic propagation in these multilayered structures in order to determine the best conditions allowing NDT of a plate behind some screens. The necessity of propagating a maximum of energy through bounded media orientated the study towards Lamb waves. Those are often employed for singles plates or solid layers but they are less usual for liquid/solid alternations. Theoretical results are obtained using transfer matrix method. They are compared to in water experimental measurements. Cases with one, two and three parallel plates without then with an artificial defect are presented for identical and different thicknesses of plates. Results show that an artificial crack defect is obviously detected in a plate located behind one and two screens. Measured attenuation is compatible with industrial NDT conditions. Thus a promising potential is shown for this inspection technique. (authors)

  1. SODIUM ALUMINOSILICATE FOULING AND CLEANING OF DECONTAMINATED SALT SOLUTION COALESCERS

    SciTech Connect (OSTI)

    Poirier, M; Thomas Peters, T; Fernando Fondeur, F; Samuel Fink, S

    2008-10-28

    During initial non-radioactive operations at the Modular Caustic Side Solvent Extraction Unit (MCU), the pressure drop across the decontaminated salt solution coalescer reached {approx}10 psi while processing {approx}1250 gallons of salt solution, indicating possible fouling or plugging of the coalescer. An analysis of the feed solution and the 'plugged coalescer' concluded that the plugging was due to sodium aluminosilicate solids. MCU personnel requested Savannah River National Laboratory (SRNL) to investigate the formation of the sodium aluminosilicate solids (NAS) and the impact of the solids on the decontaminated salt solution coalescer. Researchers performed developmental testing of the cleaning protocols with a bench-scale coalescer container 1-inch long segments of a new coalescer element fouled using simulant solution. In addition, the authors obtained a 'plugged' Decontaminated Salt Solution coalescer from non-radioactive testing in the MCU and cleaned it according to the proposed cleaning procedure. Conclusions from this testing include the following: (1) Testing with the bench-scale coalescer showed an increase in pressure drop from solid particles, but the increase was not as large as observed at MCU. (2) Cleaning the bench-scale coalescer with nitric acid reduced the pressure drop and removed a large amount of solid particles (11 g of bayerite if all aluminum is present in that form or 23 g of sodium aluminosilicate if all silicon is present in that form). (3) Based on analysis of the cleaning solutions from bench-scale test, the 'dirt capacity' of a 40 inch coalescer for the NAS solids tested is calculated as 450-950 grams. (4) Cleaning the full-scale coalescer with nitric acid reduced the pressure drop and removed a large amount of solid particles (60 g of aluminum and 5 g of silicon). (5) Piping holdup in the full-scale coalescer system caused the pH to differ from the target value. Comparable hold-up in the facility could lead to less effective cleaning and precipitation of bayerite solid particles. (6) Based on analysis of the cleaning solutions from the full-scale test, the 'dirt capacity' of a 40 inch coalescer for these NAS solids was calculated to be 40-170 grams.

  2. Better than crystalline: amorphous vanadium oxide for sodium-ion batteries

    E-Print Network [OSTI]

    Cao, Guozhong

    Better than crystalline: amorphous vanadium oxide for sodium-ion batteries E. Uchaker, Y. Z. Zheng and investigated as cathodes for sodium- ion batteries. Amorphous V2O5 demonstrated superior electro- chemical development.1,2 Among commercially available energy storage media, lithium-ion (Li-ion) batteries constitute

  3. Chemistry of Petroleum Crude Oil Deposits: Sodium Naphthenates 2009 NHMFL Science Highlight for NSF

    E-Print Network [OSTI]

    Weston, Ken

    Chemistry of Petroleum Crude Oil Deposits: Sodium Naphthenates 2009 NHMFL Science Highlight for NSF DMR-Award 0654118 Ion Cyclotron Resonance User Program Solid deposits and emulsions from crude oil can-355. Chemistry of Petroleum Crude Oil Deposits: Sodium Naphthenates 2009 NHMFL Science Highlight for NSF DMR

  4. Ice iron/sodium film as cause for high noctilucent cloud radar reflectivity

    E-Print Network [OSTI]

    Bellan, Paul M.

    Ice iron/sodium film as cause for high noctilucent cloud radar reflectivity P. M. Bellan1 Received by assuming the ice grains are coated by a thin metal film; substantial evidence exists indicating that such a film exists and is caused by the deposition of iron and sodium atoms on the ice grain from iron

  5. Combustion process and nitrogen oxides emission of Shenmu coal added with sodium acetate

    SciTech Connect (OSTI)

    Yang Weijuan; Zhou Junhu; Liu Maosheng; Zhou Zhijun; Liu Jianzhong; Cen Kefa

    2007-09-15

    Shenmu bituminous coal with 4% sodium acetate added was used to investigate the characteristics of combustion and nitrogen oxide (NOx) release in a fixed bed reactor heated by a tube furnace. The composition of the flue gas was analyzed to investigate the effects of sodium acetate on the combustion process and NOx emission. The experiments were carried out in a partial reductive atmosphere and a strong oxidative atmosphere. The O{sub 2} valley value in the partial reductive atmosphere was reduced by the added sodium acetate. Sodium acetate accelerated the combustion and shortened the combustion process. The experimental results showed that the emissions of NO, NO{sub 2}, and N{sub 2}O were affected by the reacting atmosphere and the combustion temperature. In the strong oxidative atmosphere, sodium acetate resulted in a slight NOx reduction. In the partial reductive atmosphere, sodium acetate reduced both the peak value of NO concentration and the total NO emission significantly. An over 30% NOx reduction efficiency was achieved at 900{sup o}C in the partial reductive atmosphere, which decreased with the increase in temperature. Sodium acetate was decomposed into hydrocarbon radicals and sodium hydroxide, which can both reduce NOx emissions due to their special reactions with the nitrogen component. 17 refs., 11 figs., 2 tabs.

  6. Design Considerations for Economically Competitive Sodium Cooled Fast Reactors

    SciTech Connect (OSTI)

    Hongbin Zhang; Haihua Zhao

    2009-05-01

    The technological viability of sodium cooled fast reactors (SFR) has been established by various experimental and prototype (demonstration) reactors such as EBR-II, FFTF, Phénix, JOYO, BN-600 etc. However, the economic competitiveness of SFR has not been proven yet. The perceived high cost premium of SFRs over LWRs has been the primary impediment to the commercial expansion of SFR technologies. In this paper, cost reduction options are discussed for advanced SFR designs. These include a hybrid loop-pool design to optimize the primary system, multiple reheat and intercooling helium Brayton cycle for the power conversion system and the potential for suppression of intermediate heat transport system. The design options for the fully passive decay heat removal systems are also thoroughly examined. These include direct reactor auxiliary cooling system (DRACS), reactor vessel auxiliary cooling system (RVACS) and the newly proposed pool reactor auxiliary cooling system (PRACS) in the context of the hybrid loop-pool design.

  7. Diffusion motions in hydrated sodium alginate by QENS

    SciTech Connect (OSTI)

    Tripadus, V.; Statescu, M.; Aranghel, D.; Gugiu, M.; Petre, M.; Precup, I. [Institute of Physics and Nuclear Engineerig, Bucuresti (Romania); Zanotti, J. M.; Mitra, S. [Laboratoire Leon Brillouin, CEA Saclay (France)

    2010-01-21

    QENS experiments are very suitable for the study of water-polysaccharides systems both for slow polymer chains dynamics as well as for faster solvent molecules dynamics. By a suitable choice of experimental conditions as well as a properly data processing we can get information about the motion modes of various molecular groups of polymer chains in aqueous solutions presumes. Virtually we can distinguish the polymer protons motions at nanosecond time scale by choosing a narrow energy resolution window. The present work presents the QENS measurements performed at LLB, MIBEMOL neutron spectrometer on sodium alginate hydrated samples. The experimental spectra were fitted using one lorentzian fit. At high polymer concentration the quasielastic part of the line is given by the translational-rotational diffusion performed by heavy water molecules in confined spaces created by the polymer coils. The experimental data are well described by Chudley Elliot and Hall-Ross models.

  8. Sodium fast reactor fuels and materials : research needs.

    SciTech Connect (OSTI)

    Denman, Matthew R.; Porter, Douglas; Wright, Art; Lambert, John; Hayes, Steven; Natesan, Ken; Ott, Larry J.; Garner, Frank; Walters, Leon; Yacout, Abdellatif

    2011-09-01

    An expert panel was assembled to identify gaps in fuels and materials research prior to licensing sodium cooled fast reactor (SFR) design. The expert panel considered both metal and oxide fuels, various cladding and duct materials, structural materials, fuel performance codes, fabrication capability and records, and transient behavior of fuel types. A methodology was developed to rate the relative importance of phenomena and properties both as to importance to a regulatory body and the maturity of the technology base. The technology base for fuels and cladding was divided into three regimes: information of high maturity under conservative operating conditions, information of low maturity under more aggressive operating conditions, and future design expectations where meager data exist.

  9. Feasibility Study for Vitrification of Sodium-Bearing Waste

    SciTech Connect (OSTI)

    J. J. Quigley; B. D. Raivo; S. O. Bates; S. M. Berry; D. N. Nishioka; P. J. Bunnell

    2000-09-01

    Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated under a Settlement Agreement between the Department of Energy and the State of Idaho. One of the requirements of the Settlement Agreement is the complete calcination (i.e., treatment) of all SBW by December 31, 2012. One of the proposed options for treatment of SBW is vitrification. This study will examine the viability of SBW vitrification. This study describes the process and facilities to treat the SBW, from beginning waste input from INTEC Tank Farm to the final waste forms. Schedules and cost estimates for construction and operation of a Vitrification Facility are included. The study includes a facility layout with drawings, process description and flow diagrams, and preliminary equipment requirements and layouts.

  10. Sodium-Bearing Waste Treatment Alternatives Implementation Study

    SciTech Connect (OSTI)

    Charles M. Barnes; James B. Bosley; Clifford W. Olsen

    2004-07-01

    The purpose of this document is to discuss issues related to the implementation of each of the five down-selected INEEL/INTEC radioactive liquid waste (sodium-bearing waste - SBW) treatment alternatives and summarize information in three main areas of concern: process/technical, environmental permitting, and schedule. Major implementation options for each treatment alternative are also identified and briefly discussed. This report may touch upon, but purposely does not address in detail, issues that are programmatic in nature. Examples of these include how the SBW will be classified with respect to the Nuclear Waste Policy Act (NWPA), status of Waste Isolation Pilot Plant (WIPP) permits and waste storage availability, available funding for implementation, stakeholder issues, and State of Idaho Settlement Agreement milestones. It is assumed in this report that the SBW would be classified as a transuranic (TRU) waste suitable for disposal at WIPP, located in New Mexico, after appropriate treatment to meet transportation requirements and waste acceptance criteria (WAC).

  11. Hybrid sodium heat pipe receivers for dish/Stirling systems

    SciTech Connect (OSTI)

    Laing, D.; Reusch, M.

    1997-12-31

    The design of a hybrid solar/gas heat pipe receiver for the SBP 9 kW dish/Stirling system using a United Stirling AB V160 Stirling engine and the results of on-sun testing in alternative and parallel mode will be reported. The receiver is designed to transfer a thermal power of 35 kW. The heat pipe operates at around 800 C, working fluid is sodium. Operational options are solar-only, gas augmented and gas-only mode. Also the design of a second generation hybrid heat pipe receiver currently developed under a EU-funded project, based on the experience gained with the first hybrid receiver, will be reported. This receiver is designed for the improved SPB/L. and C.-10 kW dish/Stirling system with the reworked SOLO V161 Stirling engine.

  12. 105-DR Large Sodium Fire Facility closure plan. Revision 1

    SciTech Connect (OSTI)

    Not Available

    1993-05-01

    The Hanford Site, located northwest of the city of Richland, Washington, houses reactors, chemical-separation systems, and related facilities used for the production of special nuclear materials, and activities associated with nuclear energy development. The 105-DR Large Sodium Fire Facility (LSFF), which was in operation from about 1972 to 1986, was a research laboratory that occupied the former ventilation supply room on the southwest side of the 105-DR Reactor facility. The LSFF was established to provide a means of investigating fire and safety aspects associated with large sodium or other metal alkali fires in the liquid metal fast breeder reactor (LMFBR) facilities. The 105-DR Reactor facility was designed and built in the 1950`s and is located in the 100-D Area of the Hanford Site. The building housed the 105-DR defense reactor, which was shut down in 1964. The LSFF was initially used only for engineering-scale alkali metal reaction studies. In addition, the Fusion Safety Support Studies program sponsored intermediate-size safety reaction tests in the LSFF with lithium and lithium lead compounds. The facility has also been used to store and treat alkali metal waste, therefore the LSFF is subject to the regulatory requirements for the storage and treatment of dangerous waste. Closure will be conducted pursuant to the requirements of the Washington Administrative Code (WAC) 173-303-610. This closure plan presents a description of the facility, the history of waste managed, and the procedures that will be followed to close the LSFF as an Alkali Metal Treatment Facility. No future use of the LSFF is expected.

  13. Sodium Heat Engine Development Program. Phase 1, Final report

    SciTech Connect (OSTI)

    Singh, J.P.; Kupperman, D.S.; Majumdar, S.; Dorris, S.; Gopalsami, N.; Dieckman, S.L.; Jaross, R.A.; Johnson, D.L.; Gregar, J.S.; Poeppel, R.B.; Raptis, A.C.; Valentin, R.A.

    1992-01-01

    The Sodium Heat Engine (SHE) is an efficient thermoelectric conversion device which directly generates electricity from a thermally regenerative electrochemical cell that relies on the unique conduction properties of {beta}{double_prime}-alumina solid electrolyte (BASE). Laboratory models of a variety of SHE devices have demonstrated the feasibility and efficiency of the system, engineering development of large prototype devices has been slowed by a series of materials and fabrication problems. Failure of the electrolyte tubes has been a recurring problem and a number of possible causes have been postulated. To address these issues, a two-phase engineering development program was undertaken. This report summarizes the final results of the first phase of the program, which included extensive materials characterization activities, a study of applicable nondestructive evaluation methods, an investigation of possible stress states that would contribute to fracture, and certain operational issues associated with the electromagnetic pumps used in the SHE prototype. Mechanical and microstructural evaluation of commercially obtained BASE tubes revealed that they should be adequate for SHE applications and that sodium exposure produced no appreciable deleterious strength effects. Processing activities to produce a more uniform and smaller grain size for the BASE tubes were completed using isostatic pressing, extrusion, and slip casting. Green tubes were sintered by conventional and microwave plasma methods. Of particular interest is the residual stress state in the BASE tubes, and both analysis and nondestructive evaluation methods were employed to evaluate these stresses. X-ray and neutron diffraction experiments were performed to determine the bulk residual stresses in commercially fabricated BASE tubes; however, tube-to-tube variations and variations among the various methods employed did not allow formulation of a definitive definition of the as-fabricated stress state.

  14. Sodium-Beta Batteries for Grid-Scale Storage: Planar Sodium-Beta Batteries for Renewable Integration and Grid Applications

    SciTech Connect (OSTI)

    None

    2010-02-01

    Broad Funding Opportunity Announcement Project: EaglePicher is developing a sodium-beta alumina (Na-Beta) battery for grid-scale energy storage. High-temperature Na-Beta batteries are a promising grid-scale energy storage technology, but existing approaches are expensive and unreliable. EaglePicher has modified the shape of the traditional, tubular-shaped Na-Beta battery. It is using an inexpensive stacked design to improve performance at lower temperatures, leading to a less expensive overall storage technology. The new design greatly simplifies the manufacturing process for beta alumina membranes (a key enabling technology), providing a subsequent pathway to the production of scalable, modular batteries at half the cost of the existing tubular designs.

  15. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation and Recycle of Sodium Hydroxide and Sodium Nitrate

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.; Bryan, Jeffrey C.; Bonnesen, Peter V.

    1999-06-01

    The objective of this research is to explore new liquid-liquid extraction approaches to the selective separation of major sodium salts from alkaline high-level wastes stored in underground tanks at Hanford, Savannah River, and Oak Ridge sites. Disposal of high level waste is horrendously expensive, in large part because the actual radioactive matter in the tanks has been diluted over 1000-fold by ordinary inorganic chemicals. Since the residual bulk chemicals must still undergo expensive treatment and disposal after most of the hazardous radionuclides have been removed, large cost savings will result from processes that reduce the overall waste volume. It is proposed that major cost savings can be expected if sodium hydroxide needed for sludge washing can be obtained from the waste itself, thus avoiding the addition of yet another bulk chemical to the waste and still further increase of the waste volume and disposal cost. Secondary priority is given to separating potassium an d abundant anions, including nitrate, nitrite, aluminate, and carbonate. Salts of these ions represent possible additional value for recycle, alternative disposal, or even use as commodity chemicals. A comprehensive approach toward understanding the extractive chemistry of these salts is envisioned, involving systems of varying complexity, from use of simple solvents to new bifunctional host molecules for ion-pair recognition. These extractants will ideally require no adjustment of the waste composition and will release the extracted salt into water, thereby consuming no additional chemicals and producing no additional waste volume. The overall goal of this research is to provide a scientific foundation upon which the feasibility of new liquid-liquid extraction chemistry applicable to the bulk reduction of the volume of tank waste can be evaluated.

  16. Example Work Domain Analysis for a Reference Sodium Fast Reactor

    SciTech Connect (OSTI)

    Hugo, Jacques; Oxstrand, Johanna

    2015-01-01

    The nuclear industry is currently designing and building a new generation of reactors that will include different structural, functional, and environmental aspects, all of which are likely to have a significant impact on the way these plants are operated. In order to meet economic and safety objectives, these new reactors will all use advanced technologies to some extent, including new materials and advanced digital instrumentation and control systems. New technologies will affect not only operational strategies, but will also require a new approach to how functions are allocated to humans or machines to ensure optimal performance. Uncertainty about the effect of large scale changes in plant design will remain until sound technical bases are developed for new operational concepts and strategies. Up-to-date models and guidance are required for the development of operational concepts for complex socio-technical systems. This report describes how the classical Work Domain Analysis method was adapted to develop operational concept frameworks for new plants. This adaptation of the method is better able to deal with the uncertainty and incomplete information typical of first-of-a-kind designs. Practical examples are provided of the systematic application of the method in the operational analysis of sodium-cooled reactors. Insights from this application and its utility are reviewed and arguments for the formal adoption of Work Domain Analysis as a value-added part of the Systems Engineering process are presented.

  17. Structure of rhenium-containing sodium borosilicate glass

    SciTech Connect (OSTI)

    Goel, Ashutosh; McCloy, John S.; Windisch, Charles F.; Riley, Brian J.; Schweiger, Michael J.; Rodriguez, Carmen P.; Ferreira, Jose M.

    2013-03-01

    A series of sodium borosilicate glasses were synthesized with increasing fractions of KReO4 or Re2O7, to 10000 ppm (1 mass%) target Re in glass, to assess the effects of large concentrations of rhenium on glass structure and to estimate the solubility of technetium, a radioactive component in typical low active waste nuclear waste glasses. Magic angle spinning nuclear magnetic resonance (MAS-NMR), Fourier transform infrared (FTIR) spectroscopy, and Raman spectroscopy were performed to characterize the glasses as a function of Re source additions. In general, silicon was found coordinated in a mixture of Q2 and Q3 structural units, while Al was 4-coordinated and B was largely 3-coordinate and partially 4-coordinated. The rhenium source did not appear to have significant effects on the glass structure. Thus, at the up to the concentrations that remain in dissolved in glass, ~3000 ppm Re by mass maximum. , the Re appeared to be neither a glass-former nor a strong glass modifier., Rhenium likely exists in isolated ReO4- anions in the interstices of the glass network, as evidenced by the polarized Raman spectrum of the Re glass in the absence of sulfate. Analogous to SO42-¬ in similar glasses, ReO4- is likely a network modifier and forms alkali salt phases on the surface and in the bulk glass above solubility.

  18. Sodium-bearing Waste Treatment Technology Evaluation Report

    SciTech Connect (OSTI)

    Charles M. Barnes; Arlin L. Olson; Dean D. Taylor

    2004-05-01

    Sodium-bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Office’s (NE-ID) and State of Idaho’s top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL has been working over the past several years to identify a treatment technology that meets NE-ID and regulatory treatment requirements, including consideration of stakeholder input. Many studies, including the High-Level Waste and Facilities Disposition Environmental Impact Statement (EIS), have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. This report presents a summary of the applied technology and process design activities performed through February 2004. The SBW issue and the five alternatives are described in Sections 2 and 3, respectively. Details of preliminary process design activities for three of the alternatives (steam reforming, CsIX, and direct evaporation) are presented in three appendices. A recent feasibility study provides the details for calcination. There have been no recent activities performed with regard to vitrification; that section summarizes and references previous work.

  19. EXTENDING SODIUM FAST REACTOR DRIVER FUEL USE TO HIGHER TEMPERATURES

    SciTech Connect (OSTI)

    Douglas L. Porter

    2011-02-01

    Calculations of potential sodium-cooled fast reactor fuel temperatures were performed to estimate the effects of increasing the outlet temperature of a given fast reactor design by increasing pin power, decreasing assembly flow, or increasing inlet temperature. Based upon experience in the U.S., both metal and mixed oxide (MOX) fuel types are discussed in terms of potential performance effects created by the increased operating temperatures. Assembly outlet temperatures of 600, 650 and 700 °C were used as goal temperatures. Fuel/cladding chemical interaction (FCCI) and fuel melting, as well as challenges to the mechanical integrity of the cladding material, were identified as the limiting phenomena. For example, starting with a recent 1000 MWth fast reactor design, raising the outlet temperature to 650 °C through pin power increase increased the MOX centerline temperature to more than 3300 °C and the metal fuel peak cladding temperature to more than 700 °C. These exceeded limitations to fuel performance; fuel melting was limiting for MOX and FCCI for metal fuel. Both could be alleviated by design ‘fixes’, such as using a barrier inside the cladding to minimize FCCI in the metal fuel, or using annular fuel in the case of MOX. Both would also require an advanced cladding material with improved stress rupture properties. While some of these are costly, the benefits of having a high-temperature reactor which can support hydrogen production, or other missions requiring high process heat may make the extra costs justified.

  20. Glass Formulation Development for INEEL Sodium-Bearing Waste

    SciTech Connect (OSTI)

    Vienna, John D.; Buchmiller, William C.; Crum, Jarrod V.; Graham, Dennis D.; Kim, Dong-Sang; Macisaac, Brett D.; Schweiger, Michael J.; Peeler, David K.; Edwards, Tommy B.; Reamer, Irene A.; Workman, R. J.

    2002-08-01

    Studies were performed to develop and test a glass formulation for immobilization of sodium-bearing waste (SBW). SBW is a high soda, acid high activity waste stored at the INEEL in 10 underground tanks. It was determined in previous studies that SBW?s sulfur content dictates the its loading in borosilicate glasses to be melted by currently assumed processes. If the sulfur content (which is ~4.5 mass% SO3 on a non-volatile oxide basis in SBW) of the melter feed is too high then a molten alkali sulfate containing salt phase accumulates on the melt surface. The avoidance of salt accumulation during the melter process and the maximization of sulfur incorporation into the glass melt were the main focus of this development work. A glass was developed for 20 mass% SBW (on a non-volatile oxide basis), which contained 0.91 mass% SO3, that met all the processing and product quality constraint determined for SBW vitrification at a planned INEEL treatment plant?SBW-22-20. This report summarizes the formulation efforts and presents the data developed on a series of glasses with simulated SBW. Summary

  1. Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques

    E-Print Network [OSTI]

    Doeff, Marca M.

    2013-01-01

    Rechargeable Sodium-Ion Batteries: Potential Alternatives toCurrent Lithium-Ion Batteries. Adv. Energy Mater. 2 (2012):J. , Rojo, T. Na-ion Batteries, Recent Advances and Present

  2. COST-EFFECTIVENESS OF INTRAVENOUS NICARDIPINE VERSUS SODIUM NITROPRUSSIDE FOR POSTOPERATIVE HYPERTENSION AFTER CARDIAC SURGERY.

    E-Print Network [OSTI]

    Barnes, Brian Joseph

    2010-11-23

    Postoperative hypertension after cardiac surgery is common and associated with substantial morbidity. Both sodium nitroprusside (SNP) and nicardipine (NIC) are effective in its management. SNP is inexpensive, but associated with labile blood...

  3. Review of Chemical Processes for the Synthesis of Sodium Borohydride Millennium Cell Inc.

    E-Print Network [OSTI]

    Review of Chemical Processes for the Synthesis of Sodium Borohydride Millennium Cell Inc. Prepared........................................................................................... 6 Methane (or Natural Gas) as Reducing Agent remained the same since it became commercial in the 1950s and is based on synthetic pathways developed

  4. No sodium in the vapour plumes of Enceladus Nicholas M. Schneider1

    E-Print Network [OSTI]

    Brown, Michael E.

    be ice warmed, melted or crushed by tectonic motions4 . Sodium chloride (that is, salt) is expected, together with the small fraction of salt-bearing particles6 , argues against a situation in which a near

  5. Metal corrosion in a supercritical carbon dioxide - liquid sodium power cycle.

    SciTech Connect (OSTI)

    Moore, Robert Charles; Conboy, Thomas M.

    2012-02-01

    A liquid sodium cooled fast reactor coupled to a supercritical carbon dioxide Brayton power cycle is a promising combination for the next generation nuclear power production process. For optimum efficiency, a microchannel heat exchanger, constructed by diffusion bonding, can be used for heat transfer from the liquid sodium reactor coolant to the supercritical carbon dioxide. In this work, we have reviewed the literature on corrosion of metals in liquid sodium and carbon dioxide. The main conclusions are (1) pure, dry CO{sub 2} is virtually inert but can be highly corrosive in the presence of even ppm concentrations of water, (2) carburization and decarburization are very significant mechanism for corrosion in liquid sodium especially at high temperature and the mechanism is not well understood, and (3) very little information could be located on corrosion of diffusion bonded metals. Significantly more research is needed in all of these areas.

  6. Development of a novel method to measure sodium azide using the vitamin B?? precursor cobinamide

    E-Print Network [OSTI]

    Lin, Jeffrey

    2012-01-01

    sodium azide using the vitamin B 12 precursor cobinamide Asodium azide using the vitamin B 12 precursor cobinamide byazide binds to cobinamide, a vitamin B 12 analogue. The K a

  7. Sodium sulfate heptahydrate: a synchrotron energy-dispersive diffraction study of an elusive metastable hydrated salt 

    E-Print Network [OSTI]

    Hamilton, Andrea; Hall, Christopher

    2008-01-01

    We describe an unusual application of synchrotron energy-dispersive diffraction with hard X-rays to obtain structural information on metastable sodium sulfate heptahydrate. This hydrate was often mentioned in nineteenth ...

  8. Application of the technology neutral framework to sodium cooled fast reactors

    E-Print Network [OSTI]

    Johnson, Brian C. (Brian Carl)

    2010-01-01

    Sodium cooled fast reactors (SFRs) are considered as a novel example to exercise the Technology Neutral Framework (TNF) proposed in NUREG- 1860. One reason for considering SFRs is that they have historically had a licensing ...

  9. An Evaluation of the Annular Fuel and Bottle-Shaped Fuel Concepts for Sodium Fast Reactors

    E-Print Network [OSTI]

    Memmott, Matthew

    Two innovative fuel concepts, the internally and externally cooled annular fuel and the bottle-shaped fuel, were investigated with the goal of increasing the power density and reduce the pressure drop in the sodium-cooled ...

  10. Application of the Technology Neutral Framework to Sodium-­Cooled Fast Reactors

    E-Print Network [OSTI]

    Johnson, Brian C.

    Sodium cooled fast reactors (SFRs) are considered as a novel example to exercise the Technology Neutral Framework (TNF) proposed in NUREG-1860. One reason for considering SFRs is that they have historically had a licensing ...

  11. Development of a model to predict flow oscillations in low-flow sodium boiling

    E-Print Network [OSTI]

    Levin, Alan Edward

    1980-01-01

    An experimental and analytical program has been carried out in order to better understand the cause and effect of flow oscillations in boiling sodium systems. These oscillations have been noted in previous experiments with ...

  12. Chemically Bonded Phosphorus/Graphene Hybrid as a High Performance Anode for Sodium-Ion Batteries

    SciTech Connect (OSTI)

    Song, Jiangxuan; Yu, Zhaoxin; Gordin, Mikhail; Hu, Shilin; Yi, Ran; Tang, Duihai; Walter, Timothy; Regula, Michael; Choi, Daiwon; Li, Xiaolin; Manivannan, Ayyakkannu; Wang, Donghai

    2014-11-12

    Room temperature sodium-ion batteries are of great interest for high-energy-density energy storage systems because of low-cost, natural abundance of sodium. Here, we report a novel graphene nanosheets-wrapped phosphorus composite as an anode for high performance sodium-ion batteries though a facile ball-milling of red phosphorus and graphene nanosheets. Not only can the graphene nanosheets significantly improve the electrical conductivity, but they also serve as a buffer layer to accommodate the large volume change of phosphorus in the charge-discharge process. As a result, the graphene wrapped phosphorus composite anode delivers a high reversible capacity of 2077 mAh/g with excellent cycling stability (1700 mAh/g after 60 cycles) and high Coulombic efficiency (>98%). This simple synthesis approach and unique nanostructure can potentially extend to other electrode materials with unstable solid electrolyte interphases in sodium-ion batteries.

  13. Dispersion Stability of Functionalized Graphene in Aqueous Sodium Dodecyl Sulfate Solutions

    E-Print Network [OSTI]

    Aksay, Ilhan A.

    States *S Supporting Information ABSTRACT: The colloidal stability of functionalized graphene sheets of reaggregation decreased with increasing SDS concentration; above 40 M, the suspensions were colloidally stableDispersion Stability of Functionalized Graphene in Aqueous Sodium Dodecyl Sulfate Solutions Andrew

  14. Supplementary Information: Desalination and Hydrogen, Chlorine, and Sodium Hydroxide Production via Electrophoretic Ion

    E-Print Network [OSTI]

    Santiago, Juan G.

    the Solvay process SI 13: Method scale-up with multiple channels in parallel SI 14: Scale-up concept using continuous free flow process SI 1. Composion of the sodium carbonate zone (trailing zone of anion exchange

  15. Ultracold molecules from ultracold atoms : interactions in sodium and lithium gas

    E-Print Network [OSTI]

    Christensen, Caleb A

    2011-01-01

    The thesis presents results from experiments in which ultracold Sodium-6 and Lithium-23 atomic gases were studied near a Feshbach resonance at high magnetic fields. The enhanced interactions between atoms in the presence ...

  16. Materials Issues in High Temperature Ultrasonic Transducers for Under-Sodium Viewing

    SciTech Connect (OSTI)

    Bond, Leonard J.; Griffin, Jeffrey W.; Posakony, Gerald J.; Harris, Robert V.; Baldwin, David L.

    2012-06-12

    Liquid sodium is used as the coolant in some fast spectrum nuclear reactors. This material is optically opaque. To facilitate operations and maintenance activities, an ultrasonic under-sodium viewing system has been developed. In the USA, the technology was successfully demonstrated in the 1970's, and, over the intervening 30+ years the capability was lost. This paper reports materials challenges encountered in developing both single-element and linear phased array 2 MHz transducers that must operate at temperatures up to 260C. The critical issues are fundamentally material selection: the ability of a transducer to be immersed into liquid sodium and function at 260C, to achieve wetting and transmission of ultrasound into the sodium, and to be able to be removed and re-used.

  17. Tools for supercritical carbon dioxide cycle analysis and the cycle's applicability to sodium fast reactors

    E-Print Network [OSTI]

    Ludington, Alexander R. (Alexander Rockwell)

    2009-01-01

    The Sodium-Cooled Fast Reactor (SFR) and the Supercritical Carbon Dioxide (S-C0?) Recompression cycle are two technologies that have the potential to impact the power generation landscape of the future. In order for their ...

  18. Thermal-hydraulic analysis of innovative fuel configurations for the sodium fast reactor

    E-Print Network [OSTI]

    Memmott, Matthew J

    2009-01-01

    The sodium fast reactor (SFR) is currently being reconsidered as an instrument for actinide management throughout the world, thanks in part to international programs such as the Generation-IV and especially the Global ...

  19. Sodium sulfate heptahydrate: direct observation of crystallization in a porous material 

    E-Print Network [OSTI]

    Hamilton, Andrea; Hall, Christopher; Pel, Leo

    2008-10-15

    It is well known that sodium sulfate causes salt crystallization damage in building materials and rocks. However since the early 1900s the existence of the metastable heptahydrate has been largely forgotten and almost ...

  20. Design of pulse stretching cell for a sodium guide star optical system

    SciTech Connect (OSTI)

    Friedman, H.W.; Horton, J.A.; Kuklo, T.J.; Wong, N.J.

    1992-11-10

    A pulse stretcher has been designed for the LLNL sodium guide star experiment to lower the laser flux and avoid saturation effects. The optical design, mechanical layout and wavefront error analysis are presented.

  1. Process for sodium sulfide/ferrous sulfate treatment of hexavalent chromium and other heavy metals

    DOE Patents [OSTI]

    Suciu, Dan F. (Idaho Falls, ID); Wikoff, Penny M. (Idaho Falls, ID); Beller, John M. (Idaho Falls, ID); Carpenter, Charles J. (Lynn Haven, FL)

    1991-01-01

    433 of 9384 ) United States Patent 5,000,859 Suciu ,   et al. March 19, 1991 Process for sodium sulfide/ferrous sulfate treatment of hexavalent chromium and other heavy metals

  2. Applying risk informed methodologies to improve the economics of sodium-cooled fast reactors

    E-Print Network [OSTI]

    Nitta, Christopher C

    2010-01-01

    In order to support the increasing demand for clean sustainable electricity production and for nuclear waste management, the Sodium-Cooled Fast Reactor (SFR) is being developed. The main drawback has been its high capital ...

  3. The use of sodium and/or potassium lactate to extend shelf-life and reduce sodium levels in precooked beef systems 

    E-Print Network [OSTI]

    Pagach, Denise Ann

    1992-01-01

    that potassium exchange for pmtons, possibly thmugh an antiport in the cell's membrane could be a component of pH homeostasis, If a higher amount of potassium was available to be exchanged with protons, the pH would increase because of the decrease...THE USE OF SODIUM AND/OR POTASSIUM LACI'ATE TO EXTEND SHELF-LIFE AND REDUCE SODIUM LEVELS IN PRECOOKED BEEF SYSTEMS A Thesis by DENISE ANN PAGACH Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment...

  4. Utilizing Daylighting Controls in a Manufacturing Facility 

    E-Print Network [OSTI]

    Shrestha, S. S.; Maxwell, G. M.

    2009-01-01

    to various stages of lighting reduction. This paper examines these lighting control strategies for a 90,000 square foot manufacturing facility in Iowa. Using the EnergyPlus building energy simulation code, annual lighting energy savings associated...) Energy Cost Savings ($/yr) Six-Lamp Fixture With 32 Watt 4 Foot Super T8 Lamps 222 43.512 191,191 46.6 204,971 2,295 9,757 * Per fixture including ballast power ESL-IE-09-05-29 Proceedings of the Thirty-First Industrial Energy Technology...

  5. Times are in Mountain Daylight Savings Time

    Energy Savers [EERE]

    Update on FY 12 NEET projects Lead 8:00 AM 8:15 AM Welcome and Webinar Rules Maloy 8:15 AM 8:20 AM NEET Introduction Lesica 8:20 AM 8:40 AM Radiation tolerance and mechanical...

  6. Times are in Mountain Daylight Savings Time

    Energy Savers [EERE]

    Modifications for Improved Accident Tolerance of LWR Fuel Heuser 11:30 AM 11:50 AM Integral Inherently Safe Light Water Reactor (I2S- LWR) Petrovic 11:50 AM 12:20 PM Discussion...

  7. Daylight control system, device and method

    SciTech Connect (OSTI)

    Paton, John Douglas

    2012-08-28

    A system and device for and a method of programming and controlling light fixtures is disclosed. A system in accordance with the present invention includes a stationary controller unit that is electrically coupled to the light fixtures. The stationary controller unit is configured to be remotely programmed with a portable commissioning device to automatically control the lights fixtures. The stationary controller unit and the portable commissioning device include light sensors, micro-computers and transceivers for measuring light levels, running programs, storing data and transmitting data between the stationary controller unit and the portable commissioning device. In operation, target light levels selected with the portable commissioning device and the controller unit is remotely programmed to automatically maintain the target level.

  8. Daylight control system device and method

    DOE Patents [OSTI]

    Paton, John Douglas

    2009-12-01

    A system and device for and a method of programming and controlling light fixtures is disclosed. A system in accordance with the present invention includes a stationary controller unit that is electrically coupled to the light fixtures. The stationary controller unit is configured to be remotely programmed with a portable commissioning device to automatically control the lights fixtures. The stationary controller unit and the portable commissioning device include light sensors, micro-computers and transceivers for measuring light levels, running programs, storing data and transmitting data between the stationary controller unit and the portable commissioning device. In operation, target light levels selected with the portable commissioning device and the controller unit is remotely programmed to automatically maintain the target level.

  9. Daylighting Prediction Software: Comparative Analysis and Application 

    E-Print Network [OSTI]

    Estes, J. M. Jr.; Schreppler, S.; Newsom, T.

    2004-01-01

    for the calibrated modeling of light scattered in enclosed spaces. These software packages used algorithms based on either total radiosity (flux transfer) computations or physically accurate ray tracing. A summary of this survey along with the selection criteria used...

  10. Daylight control system device and method

    DOE Patents [OSTI]

    Paton, John Douglas

    2007-03-13

    A system and device for and a method of programming and controlling light fixtures is disclosed. A system in accordance with the present invention includes a stationary controller unit that is electrically coupled to the light fixtures. The stationary controller unit is configured to be remotely programmed with a portable commissioning device to automatically control the lights fixtures. The stationary controller unit and the portable commissioning device include light sensors, micro-computers and transceivers for measuring light levels, running programs, storing data and transmitting data between the stationary controller unit and the portable commissioning device. In operation, target light levels selected with the portable commissioning device and the controller unit is remotely programmed to automatically maintain the target level.

  11. Advanced Facades, Daylighting, and Complex Fenestration Systems

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternationalReportOfficeAcqguide18pt0Department ofHigh2 DOEFactory-Built

  12. Window Daylighting Demo | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternationalReport FY2014 -Energy Costs by IncreasingWholeWindAwardEnergy 1

  13. List of Daylighting Incentives | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History ViewInformationWindsCompressed air Incentives Jump to:Data

  14. Advanced Facades, Daylighting, and Complex Fenestration Systems |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsofProgram:Y-12 Beta-3AUDITLeslie Pezzullo Office of the BiomassEnergy

  15. Lighting and Daylighting Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative Fuels Data CenterFinancialInvesting in Minority Banks InvestingLabLighting and

  16. Experimental investigations of rheological properties of sodium carboxymethyl cellulose and polyvinyl alcohol 

    E-Print Network [OSTI]

    Fort, Ben Franklin

    1966-01-01

    EXPERIMENTAL INVESTIGATIONS OF RHEOLOGICAL PROPERTIES OF SODIUM CARBOXYMETHYL CELLULOSE AND POLYVINYL ALCOHOL A Thesis By BEN F. FORT, JR. Submitted to the Graduate College of the Texas AfkM University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 1966 Major Subject: Chemical Engineering EXPERIMENTAL INVESTIGATIONS OF RHEOLOGICAL PROPERTIES OF SODIUM CARBOXYMETHYL CELLULOSE AND POLYVINYL ALCOHOL A Thesis By BEN F. FORT, JR. Approved...

  17. The substitution of sodium for calcium in the mineral nutrition of cotton 

    E-Print Network [OSTI]

    Whitenberg, David Calvin

    1959-01-01

    LIBRARY A & M O' LLEOE OF TEXA5 THE SUBSTITUTION OF SODIUM FOR CALCIUM IN THE MINERAL NUTRITION OF COTTON A Thesis By DAVID CALVIN WHITENBERG Submit. ted to the Graduate School of the Agricultural and Mechanical College of Texas in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE January 19 59 Major Subject: Plant Physiology THE SUBSTITUTION OF SODIUM FOR CALCIUM IN THE MINERAL NUTRITION OF COTTON A Thesis By DAVID CALVIN WHITENBERG Approved as to style...

  18. The tolerance of two varieties of cotton to relatively high levels of sodium and magnesium 

    E-Print Network [OSTI]

    Parekh, Manhar C

    1969-01-01

    THE TO'ERANCE OF TNO VARIETIES OF COTTON TO RELATIVELY HIGH LEVELS OF SODIUM AND MAGNESIUM A Tnesis by Msnhar C. Parekh Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirements for the degree...) (Nember) (Nemb ) August 1969 ABSTRACT The Tolerance of Two Varieties of Cotton to Relatively High Levels of Sodium and Magnesium. (August 1969) Masher C. Parekh, B. S. , Gujarat University, Directed by: Dr. H. E. Joham An experiment was conducted...

  19. Characterization of the liquid sodium spray generated by a pipework hole

    SciTech Connect (OSTI)

    Torsello, G.; Parozzi, F.; Nericcio, L.; Araneo, L.; Cozzi, F.; Carcassi, M.; Mattei, N.

    2012-07-01

    Due to its advantageous thermodynamic characteristics at high temperature (550 deg. C), liquid sodium is the main candidate to be the cooling fluid for Generation TV nuclear reactors SFR (Sodium-cooled Fast Reactors). Now, sodium reacts very violently, both with the water and the oxygen of the air. Only few data were known about the liquid sodium behaviour when spread in the environment through micro defects. These are often present in a cooling circuit in welded or sealed joints and more rarely in the pipes. Micro defects, on the other hand, can be also generated in a cooling circuit because of the vibrations always present in a circuit into which a fluid runs. A new set-up, named LISOF, was built for testing high temperature liquid sodium when passing through micro defects and generating sprays or jets. Sprays and jets were generated by means of nozzles embedding sub milli-metric holes the diameter of which was: 0.2 mm, 0.4 mm, 0.5 mm. Tests were performed by pressurizing liquid sodium (550 deg. C) at: 3, 6 and 9 barg. Normal and high speed cinematography were used for the direct observation of the liquid sodium sprays while Phase Doppler Interferometry was used for the measurement of the droplets characteristics and velocity. Tests concerning the behaviour of the high temperature liquid sodium firing in air or in contact with the cement cover applied to a scaled down core catcher simulacrum were also performed. The paper presents the built set-up and the collected results. (authors)

  20. The effect of sodium chloride in the irrigation water on the growth of selected ornamental plants 

    E-Print Network [OSTI]

    Apps, Gary Edward

    1976-01-01

    THE EFFECT OF SODIUM CHLORIDE IN THE IRRIGATION WATER ON THE GROWTH OF SELECTED ORNAMENTAL PLANTS A Thesis by GARY EDWARD APPS Submitted to the Graduate College of Texas A6M University in partial fulfillment of the requirement for the degree... of MASTER OF SCIENCE December 1976 Major Subject: Floriculture THE EFFECT OF SODIUM CHLORIDE IN THE IRRIGATION WATER ON THE GROWTH OF SELECTED ORNAMENTAL PLANTS A Thesis by GARY EDWARD APPS Approved as to style and content by: (Chairman of Committee...

  1. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.; Bonnesen, Peter V.

    2005-06-01

    The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of low-activity waste immobilization. Principles of ion recognition are being researched toward discovery of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudohydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Synthesis efforts are being directed toward enhanced sodium binding by crown ethers, both neutral and proton-ionizable. Studies with real tank waste at PNNL will provide feedback toward solvent compositions that have promising properties.

  2. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Bonnesen, Peter V.; Custelcean, Radu; Delmau, Laetitia H.; Engle, Nancy L.; Kang, Hyun-Ah; Keever, Tamara J.; Marchand, Alan P.; Gadthula, Srinivas; Gore, Vinayak K.; Huang, Zilin; Sivappa, Rasapalli; Tirunahari, Pavan K.; Levitskaia, Tatiana G.; Lumetta, Gregg J.

    2005-09-26

    The purpose of this research involving collaboration between Oak Ridge National Laboratory (ORNL) and Pacific Northwest National Laboratory (PNNL) is to explore new approaches to the separation of sodium hydroxide, sodium nitrate, and other sodium salts from high-level alkaline tank waste. The principal potential benefit is a major reduction in disposed waste volume, obviating the building of expensive new waste tanks and reducing the costs of vitrification. Principles of ion recognition are being researched toward discovery of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium nitrate from other waste components. The successful concept of pseudo hydroxide extraction using fluorinated alcohols and phenols is being developed at ORNL and PNNL toward a greater understanding of the controlling equilibria, role of solvation, and of synergistic effects involving crown ethers. Synthesis efforts are being directed toward enhanced sodium binding by crown ethers, both neutral and proton-ionizable. Studies with real tank waste at PNNL will provide feedback toward solvent compositions that have promising properties.

  3. Solar-thermal Water Splitting Using the Sodium Manganese Oxide Process & Preliminary H2A Analysis

    SciTech Connect (OSTI)

    Todd M. Francis, Paul R. Lichty, Christopher Perkins, Melinda Tucker, Peter B. Kreider, Hans H. Funke, Allan Lewandowski, and Alan W. Weimer

    2012-10-24

    There are three primary reactions in the sodium manganese oxide high temperature water splitting cycle. In the first reaction, Mn2O3 is decomposed to MnO at 1,500°C and 50 psig. This reaction occurs in a high temperature solar reactor and has a heat of reaction of 173,212 J/mol. Hydrogen is produced in the next step of this cycle. This step occurs at 700°C and 1 atm in the presence of sodium hydroxide. Finally, water is added in the hydrolysis step, which removes NaOH and regenerates the original reactant, Mn2O3. The high temperature solar�driven step for decomposing Mn2O3 to MnO can be carried out to high conversion without major complication in an inert environment. The second step to produce H2 in the presence of sodium hydroxide is also straightforward and can be completed. The third step, the low temperature step to recover the sodium hydroxide is the most difficult. The amount of energy required to essentially distill water to recover sodium hydroxide is prohibitive and too costly. Methods must be found for lower cost recovery. This report provides information on the use of ZnO as an additive to improve the recovery of sodium hydroxide.

  4. An evaluation of neutralization for processing sodium-bearing liquid waste

    SciTech Connect (OSTI)

    Chipman, N.A.; Engelgau, G.O.; Berreth, J.R.

    1989-01-01

    This report addresses an alternative concept for potentially managing the sodium-bearing liquid waste generated at the Idaho Chemical Processing Plant from the current method of calcining a blend of sodium waste and high-level liquid waste. The concept is based on removing the radioactive components from sodium-bearing waste by neutralization and grouting the resulting low-level waste for on-site near-surface disposal. Solidifying the sodium waste as a remote-handled transuranic waste is not considered to be practical because of excessive costs and inability to dispose of the waste in a timely fashion. Although neutralization can remove most radioactive components to provide feed for a solidified low-level waste, and can reduce liquid inventories four to nine years more rapidly than the current practice of blending sodium-bearing liquid waste with first-cycle raffinite, the alternative will require major new facilities and will generate large volumes of low-level waste. Additional facility and operating costs are estimated to be at least $500 million above the current practice of blending and calcining. On-site, low-level waste disposal may be technically difficult and conflict which national and state policies. Therefore, it is recommended that the current practice of calcining a blend of sodium-bearing liquid waste and high-level liquid waste be continued to minimize overall cost and process complexities. 17 refs., 4 figs., 16 tabs.

  5. Dynamic processes and polarizability of sodium atom in Debye plasmas

    SciTech Connect (OSTI)

    Qi, Yue-Ying Ning, Li-Na

    2014-03-15

    Dynamic processes including excitation and ionization, and spectrum parameters including the oscillator strengths, dipole polarizabilities from the orbital 3s,3p of sodium atom embedded in weakly coupled plasma are investigated in the entire energy range of a non-relativistic regime. The interaction between the valence electron and the atomic core is simulated by a model potential, and the plasma screening of the Coulomb interaction between charged particles is described by the Debye-Hückel model. The screening of Coulomb interactions reduces the number of bound states, decreases their binding energies, broadens their radial distribution of electron wave functions, and significantly changes the continuum wave functions including the amplitudes and phase-shift. These changes strongly affect the dipole matrix elements between the bound-bound and bound-continuum states, and even the oscillator strengths, the photo-ionization cross sections and the dipole polarizabilities. The plasma screening effect changes the interaction between the valence electron and the atomic core into a short-range potential. The energy behaviors of photo-ionization cross sections are unfolded, for instance, its low-energy behavior (obeying Wigner threshold law), and the appearance of multiple shape and virtual-state resonances when the upper bound states emerge into the continuum. The Combet-Farnoux and Cooper minima in the photo-ionization cross sections are also investigated, and here, the Cooper minima appear not only for the l?l+1 channel but also for l?l?1 one, different from that of hydrogen-like ions in a Debye plasma, which appear only in the l?l+1 channel. The total static electric dipole polarizabilities monotonously and dramatically increase with the plasma screening effect increasing, which are similar to those of hydrogen-like ions and lithium atom. Comparison of calculated results for the oscillator strength, the photo-ionization cross section and polarizability with the results of other authors, when available, is made.

  6. Sodium channel activation mechanisms. Insights from deuterium oxide substitution

    SciTech Connect (OSTI)

    Alicata, D.A.; Rayner, M.D.; Starkus, J.G. )

    1990-04-01

    Schauf and Bullock, using Myxicola giant axons, demonstrated that solvent substitution with deuterium oxide (D2O) significantly affects both sodium channel activation and inactivation kinetics without corresponding changes in gating current or tail current rates. They concluded that (a) no significant component of gating current derives from the final channel opening step, and (b) channels must deactivate (during tail currents) by a different pathway from that used in channel opening. By contrast, Oxford found in squid axons that when a depolarizing pulse is interrupted by a brief (approximately 100 microseconds) return to holding potential, subsequent reactivation (secondary activation) is very rapid and shows almost monoexponential kinetics. Increasing the interpulse interval resulted in secondary activation rate returning towards control, sigmoid (primary activation) kinetics. He concluded that channels open and close (deactivate) via the same pathway. We have repeated both sets of observations in crayfish axons, confirming the results obtained in both previous studies, despite the apparently contradictory conclusions reached by these authors. On the other hand, we find that secondary activation after a brief interpulse interval (50 microseconds) is insensitive to D2O, although reactivation after longer interpulse intervals (approximately 400 microseconds) returns towards a D2O sensitivity similar to that of primary activation. We conclude that D2O-sensitive primary activation and D2O-insensitive tail current deactivation involve separate pathways. However, D2O-insensitive secondary activation involves reversal of the D2O-insensitive deactivation step. These conclusions are consistent with parallel gate models, provided that one gating particle has a substantially reduced effective valence.

  7. A Novel Low-Cost Sodium-Zinc Chloride Battery

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

    2013-02-28

    The sodium-metal halide (ZEBRA) battery has been considered as one of the most attractive energy storage systems for stationary and transportation applications. Even though Na-NiCl2 battery has been widely investigated, there is still a need to develop a more economical system to make this technology more attractive for commercialization. In the present work, a novel low-cost Na-ZnCl2 battery with a thin planar ??-Al2O3 solid electrolyte (BASE) was proposed, and its electrochemical reactions and battery performance were investigated. Compared to the Na-NiCl2 chemistry, the ZnCl2-based chemistry was more complicated, in which multiple electrochemical reactions including liquid-phase formation occurred at temperatures above 253°C. During the first stage of charge, NaCl reacted with Zn to form Na in the anode and Na2ZnCl4 in the cathode. Once all the residual NaCl was consumed, further charging led to the formation of a NaCl-ZnCl2 liquid phase. At the end of charge, the liquid phase reacted with Zn to produce solid ZnCl2. To identify the effects of liquid-phase formation on electrochemical performance, button cells were assembled and tested at 280°C and 240°C. At 280°C where the liquid phase formed during cycling, cells revealed quite stable cyclability. On the other hand, more rapid increase in polarization was observed at 240°C where only solid-state electrochemical reactions occurred. SEM analysis indicated that the stable performance at 280°C was due to the suppressed growth of Zn and NaCl particles, which were generated from the liquid phase during discharge of each cycle.

  8. Ion Recognition Approach to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Moyer, Bruce A.; Marchand, Alan P.; Lumetta, Gregg J.

    2004-06-30

    In this project, now completing its third year of its second renewal period, a collaborative project involving Oak Ridge National Laboratory, Pacific Northwest National Laboratory, and the University of North Texas has been addressing outstanding questions regarding the separation of the bulk sodium constituents of alkaline tank waste. The principal potential benefit of this research is a major reduction in the volume of radioactive tank waste, obviating the building of expensive new tanks and reducing the costs of vitrification. As a general approach, principles of ion recognition are being explored toward discovery and basic understanding of liquid-liquid extraction systems that selectively separate sodium hydroxide and sodium salts from waste-like matrices. Questions being addressed pertain to applicable extraction equilibria and how extraction properties relate to extractant structure. Progress has included the elucidation of the promising concept of pseudo hydroxide extraction (PHE), demonstration of crown-ether synergized PHE, demonstration of combined sodium hydroxide/sodium nitrate separation, and synthesis of novel ditopic receptors for ditopic PHE. In future efforts (pending renewal), a thermochemical study of PHE relating extractant acidity to extraction strength is proposed, and this study will be extended to systems containing crown ethers, including proton-ionizable ones. A series of crown ethers will be synthesized for this purpose and to investigate the extraction of bulk sodium salts (e.g., nitrate, nitrite, and sulfate), possibly in combination with sodium hydroxide. Simple proof-of-principle tests with real tank waste at PNNL will provide feedback toward solvent designs that have desirable properties. In view of the upcoming milestone of completion of the second renewal period, this report will, in addition to providing a summary of the past year's progress, summarize all of the work completed since the start of this project.

  9. Sustained Recycle in Light Water and Sodium-Cooled Reactors

    SciTech Connect (OSTI)

    Steven J. Piet; Samuel E. Bays; Michael A. Pope; Gilles J. Youinou

    2010-11-01

    From a physics standpoint, it is feasible to sustain recycle of used fuel in either thermal or fast reactors. This paper examines multi-recycle potential performance by considering three recycling approaches and calculating several fuel cycle parameters, including heat, gamma, and neutron emission of fresh fuel; radiotoxicity of waste; and uranium utilization. The first recycle approach is homogeneous mixed oxide (MOX) fuel assemblies in a light water reactor (LWR). The transuranic portion of the MOX was varied among Pu, NpPu, NpPuAm, or all-TRU. (All-TRU means all isotopes through Cf-252.) The Pu case was allowed to go to 10% Pu in fresh fuel, but when the minor actinides were included, the transuranic enrichment was kept below 8% to satisfy the expected void reactivity constraint. The uranium portion of the MOX was enriched uranium. That enrichment was increased (to as much as 6.5%) to keep the fuel critical for a typical LWR irradiation. The second approach uses heterogeneous inert matrix fuel (IMF) assemblies in an LWR - a mix of IMF and traditional UOX pins. The uranium-free IMF fuel pins were Pu, NpPu, NpPuAm, or all-TRU. The UOX pins were limited to 4.95% U-235 enrichment. The number of IMF pins was set so that the amount of TRU in discharged fuel from recycle N (from both IMF and UOX pins) was made into the new IMF pins for recycle N+1. Up to 60 of the 264 pins in a fuel assembly were IMF. The assembly-average TRU content was 1-6%. The third approach uses fast reactor oxide fuel in a sodium-cooled fast reactor with transuranic conversion ratio of 0.50 and 1.00. The transuranic conversion ratio is the production of transuranics divided by destruction of transuranics. The FR at CR=0.50 is similar to the CR for the MOX case. The fast reactor cases had a transuranic content of 33-38%, higher than IMF or MOX.

  10. The Effects of Temperature on the Electrochemical Performance of Sodium-Nickel Chloride Batteries

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Lemmon, John P.; Sprenkle, Vincent L.; Yang, Zhenguo

    2012-10-01

    The sodium-nickel chloride (ZEBRA) battery is typically fabricated with a thick tubular ?"-alumina solid electrolyte (BASE) and operated at relatively high temperatures (? 300ºC) to achieve adequate electrochemical performance. In the present work, a planar-type sodium-nickel chloride battery possessing a thin BASE (~600 ?m thick) was tested in order to evaluate the feasibility of the battery operation at low temperatures (?200°C). Electrochemical test results revealed that the battery was able to be cycled at C/3 rate at as low as 175°C despite the higher cell polarization at the reduced temperature. Overall, low operating temperature resulted in a considerable improvement in the stability of cell performance. Cell degradation was negligible at 175°C, while 55% increase in end-of-charge polarization was observed at 280°C after 60 cycles. SEM analysis indicated that the performance degradation at higher temperatures was related to the particle growth of both nickel and sodium chloride in the cathode. The cells tested at lower temperatures (e.g., 175 and 200°C), however, exhibited a sharp drop in cell voltage at the end of discharge due to the diffusion limitation, possibly caused by the limited ionic conductivity of NaAlCl4 melt or the poor wettability of sodium on the BASE. Therefore, improvements in the ionic conductivity of a secondary electrolyte and sodium wetting are desirable to further enhance the battery performance at low temperatures.

  11. Combined Utilization of Cation Exchanger and Neutral Receptor to Volume Reduction of Alkaline Tank Waste by Separation of Sodium Salts

    SciTech Connect (OSTI)

    Levitskaia, Tatiana G.; Lumetta, Gregg J.; Moyer, Bruce A.

    2004-03-29

    In this report, novel approaches to the selective liquid-liquid extraction separation of sodium hydroxide and sodium nitrate from high-level alkaline tank waste will be discussed. Sodium hydroxide can be successfully separated from alkaline tank-waste supernatants by weakly acidic lipophilic hydroxy compounds via a cation-exchange mechanism referred to as pseudo hydroxide extraction. In a multi-cycle process, as sodium hydroxide in the aqueous phase becomes depleted, it is helpful to have a neutral sodium receptor in the extraction system to exploit the high nitrate concentration in the waste solution to promote sodium removal by an ion-pair extraction process. Simultaneous utilization of an ionizable organic hydroxy compound and a neutral extractant (crown ether) in an organic phase results in the synergistic enhancement of ion exchange and improved separation selectivity due to the receptor's strong and selective sodium binding. Moreover, combination of the hydroxy compound and the crown ether provides for mutually increased solubility, even in a non-polar organic solvent. Accordingly, application of Isopar{reg_sign} L, a kerosene-like alkane solvent, becomes feasible. This investigation involves examination of such dual-mechanism extraction phases for sodium extraction from simulated and actual salt cake waste solutions. Sodium salts can be regenerated upon the contact of the loaded extraction phases with water. Finally, conditions of potential extraction/strip cycling will be discussed.

  12. Caustic Recycling Pilot Unit to Separate Sodium from LLW at Hanford Site - 12279

    SciTech Connect (OSTI)

    Pendleton, Justin; Bhavaraju, Sai; Priday, George; Desai, Aditya; Duffey, Kean; Balagopal, Shekar [Ceramatec Inc., Salt Lake City, UT 84119 (United States)

    2012-07-01

    As part of the Department of Energy (DOE) sponsored Advanced Remediation Technologies initiative, a scheme was developed to combine Continuous Sludge Leaching (CSL), Near-Tank Cesium Removal (NTCR), and Caustic Recycling Unit (CRU) using Ceramatec technology, into a single system known as the Pilot Near-Tank Treatment System (PNTTS). The Cesium (Cs) decontaminated effluent from the NTCR process will be sent to the caustic recycle process for recovery of the caustic which will be reused in another cycle of caustic leaching in the CSL process. Such an integrated mobile technology demonstration will give DOE the option to insert this process for sodium management at various sites in Hanford, and will minimize the addition of further sodium into the waste tanks. This allows for recycling of the caustic used to remove aluminum during sludge washing as a pretreatment step in the vitrification of radioactive waste which will decrease the Low Level Waste (LLW) volume by as much as 39%. The CRU pilot process was designed to recycle sodium in the form of pure sodium hydroxide. The basis for the design of the 1/4 scale pilot caustic recycling unit was to demonstrate the efficient operation of a larger scale system to recycle caustic from the NTCR effluent stream from the Parsons process. The CRU was designed to process 0.28 liter/minute of NTCR effluent, and generate 10 M concentration of 'usable' sodium hydroxide. The proposed process operates at 40 deg. C to provide additional aluminum solubility and then recover the sodium hydroxide to the point where the aluminum is saturated at 40 deg. C. A system was developed to safely separate and vent the gases generated during operation of the CRU with the production of 10 M sodium hydroxide. Caustic was produced at a rate between 1.9 to 9.3 kg/hr. The CRU was located inside an ISO container to allow for moving of the unit close to tank locations to process the LLW stream. Actual tests were conducted with the NTCR effluent simulant from the Parsons process in the CRU. The modular CRU is easily scalable as a standalone system for caustic recycling, or for NTTS integration or for use as an In-Tank Treatment System to process sodium bearing waste to meet LLW processing needs at the Hanford site. The standalone pilot operation of the CRU to recycle sodium from NTCR effluent places the technology demonstration at TRL level 6. Multiple operations were performed with the CRU to process up to 500 gallons of the NTCR effluent and demonstrate an efficient separation of up to 70 % of the sodium without solids precipitation while producing 10 M caustic. Batch mode operation was conducted to study the effects of chemistry variation, establish the processing rate, and optimize the process operating conditions to recycle caustic from the NTCR effluent. The performance of the CRU was monitored by tracking the density parameter to control the concentration of caustic produced. Different levels of sodium were separated in tests from the effluent at a fixed operating current density and temperature. The voltage of the modules remained stable during the unit operation which demonstrated steady operation to separate sodium from the NTCR effluent. The sodium transfer current efficiency was measured in testing based on the concentration of caustic produced. Measurements showed a current efficiency of 99.8% for sodium transfer from the NTCR effluent to make sodium hydroxide. The sodium and hydroxide contents of the anolyte (NTCR feed) and catholyte (caustic product) were measured before and after each batch test. In two separate batch tests, samples were taken at different levels of sodium separation and analyzed to determine the stability of the NTCR effluent after sodium separation. The stability characteristics and changes in physical and chemical properties of the NTCR effluent chemistry after separation of sodium hydroxide as a function of storage time were evaluated. Parameters such as level of precipitated alumina, total alkalinity, analysis of Al, Na, K, Cs, Fe, OH, nitrate, nitrite, total dissolved and

  13. Development and application of modeling tools for sodium fast reactor inspection

    SciTech Connect (OSTI)

    Le Bourdais, Florian; Marchand, Benoît; Baronian, Vahan

    2014-02-18

    To support the development of in-service inspection methods for the Advanced Sodium Test Reactor for Industrial Demonstration (ASTRID) project led by the French Atomic Energy Commission (CEA), several tools that allow situations specific to Sodium cooled Fast Reactors (SFR) to be modeled have been implemented in the CIVA software and exploited. This paper details specific applications and results obtained. For instance, a new specular reflection model allows the calculation of complex echoes from scattering structures inside the reactor vessel. EMAT transducer simulation models have been implemented to develop new transducers for sodium visualization and imaging. Guided wave analysis tools have been developed to permit defect detection in the vessel shell. Application examples and comparisons with experimental data are presented.

  14. Survey of sodium removal methods: LMFBR conceptual design study, Phase 3

    SciTech Connect (OSTI)

    none,

    1981-09-01

    At the project design review of the nuclear island maintenance on May 5, 1981, DOE requested a survey of current sodium cleaning methods and facilities. Stone & Webster provided a plan and schedule for providing this survey. This plan was approved by Boeing Engineering and Construction Company. The purpose of this survey is to document the sodium removal technology and experience as it relates to the CDS Large Developmental Plant, summarize the information, and provide a prospective for the CDS project. The recommendations generated are intended to provide input for a design and layout review of the Nuclear Island Maintenance Building (NIMB).

  15. Method of making a current collector for a sodium/sulfur battery

    DOE Patents [OSTI]

    Tischer, R.P.; Winterbottom, W.L.; Wroblowa, H.S.

    1987-03-10

    This specification is directed to a method of making a current collector for a sodium/sulfur battery. The current collector so-made is electronically conductive and resistant to corrosive attack by sulfur/polysulfide melts. The method includes the step of forming the current collector for the sodium/sulfur battery from a composite material formed of aluminum filled with electronically conductive fibers selected from the group of fibers consisting essentially of graphite fibers having a diameter up to 10 microns and silicon carbide fibers having a diameter in a range of 500--1,000 angstroms. 2 figs.

  16. L-sodium lactate in cooked beef top rounds: differing levels of incorporation and cookery 

    E-Print Network [OSTI]

    Evans, Lori Leigh

    1992-01-01

    L-SODIUM LACTATE IN COOKED BEEF TOP ROUNDS; DIFFERING LEVELS OF INCORPORATION AND COOKERY A Thesis by LORI LEIGH EVANS Submitted to the Office of Graduate Studies of Texas A8 M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE May 1992 Major Subject: Animal Science L-SODIUM LACTATE IN COOKED BEEF TOP ROUNDS; DIFFERING LEVELS OF INCORPORATION AND COOKERY A Thesis by LORI LEIGH EVANS Approved as to style and content by: R. K. Miller (Chair...

  17. Effect of glycine on chromosomal aberrations of Allium cepa L. root tips caused by sodium fluoride 

    E-Print Network [OSTI]

    Abid, Adeeba Al-Shahwani

    1967-01-01

    EFFECT OF GLYCINE ON CHROMOSOMAL ABERRATIONS OF ALLIUM CEPA L ~ ROOT TIPS CAUSED BY SODIUM FLUORIDE A Thesis By Adeeba Al-Shahvani Abid Submitted to the Graduate College of the Texas A&M University in partial fulfillment of the requirements... for the degree of MASTER OF SCIENCE August 1967 Major Subject Genetics EFFECT OF GLYCINE ON CHROMOSOMAL ABERRATIONS OF ALLIUM CEPA L, ROOT TIPS CAUSED BY SODIUM FLUORIDE A Thesis By Adeeba Al-Shahwani Abid Approved as to style and content by: ( airman...

  18. Preliminary analysis of patent trends for sodium/sulfur battery technology

    SciTech Connect (OSTI)

    Triplett, M.B.; Winter, C.; Ashton, W.B.

    1985-07-01

    This document summarizes development trends in sodium/sulfur battery technology based on data from US patents. Purpose of the study was to use the activity, timing and ownership of 285 US patents to identify and describe broad patterns of change in sodium/sulfur battery technology. The analysis was conducted using newly developed statistical and computer graphic techniques for describing technology development trends from patent data. This analysis suggests that for some technologies trends in patent data provide useful information for public and private R and D planning.

  19. Health and Safety Considerations Associated with Sodium-Cooled Experimental Nuclear Fuel Dismantlement

    SciTech Connect (OSTI)

    Carvo, Alan E.

    2015-04-01

    Between the mid-1970s and the mid-1980s Sandia National Laboratory constructed eleven experimental assemblies to simulate debris beds formed in a sodium-cooled fast breeder reactor. All but one of the assemblies were irradiated. The experimental assemblies were transferred to the Idaho National Laboratory (INL) in 2007 and 2008 for storage, dismantlement, recovery of the uranium for reuse in the nuclear fuel cycle, and disposal of unneeded materials. This paper addresses the effort to dismantle the assemblies down to the primary containment vessel and repackage them for temporary storage until such time as equipment necessary for sodium separation is in place.

  20. PHYSICAL REVIEW B 84, 054203 (2011) Electrical and thermal conductivity of liquid sodium from first-principles calculations

    E-Print Network [OSTI]

    Alfè, Dario

    2011-01-01

    and technological point of view. For example, it is used as coolant in fast-breeding nuclear reactors, and in heatPHYSICAL REVIEW B 84, 054203 (2011) Electrical and thermal conductivity of liquid sodium from first on the electrical and thermal conductivity of liquid sodium at 400 K, calculated using density functional theory

  1. Deformation by dissolution and plastic flow of a single crystal sodium chloride indenter: An experimental study under the confocal

    E-Print Network [OSTI]

    Einat, Aharonov

    Deformation by dissolution and plastic flow of a single crystal sodium chloride indenter. H. Scholz (2008), Deformation by dissolution and plastic flow of a single crystal sodium chloride is undercutting dissolution that reduces the area of the contact, and the second is probably plastic flow

  2. Tin Anode for Sodium-Ion Batteries Using Natural Wood Fiber as a Mechanical Buffer and Electrolyte Reservoir

    E-Print Network [OSTI]

    Rubloff, Gary W.

    Tin Anode for Sodium-Ion Batteries Using Natural Wood Fiber as a Mechanical Buffer and Electrolyte Information ABSTRACT: Sodium (Na)-ion batteries offer an attractive option for low cost grid scale storage due to the abundance of Na. Tin (Sn) is touted as a high capacity anode for Na-ion batteries with a high theoretical

  3. F POWER MEASUREMENT FOR GENERATION IV SODIUM FAST R. COULON, S. NORMAND, M. MICHEL, L. BARBOT, T. DOMENECH,

    E-Print Network [OSTI]

    Boyer, Edmond

    20 F POWER MEASUREMENT FOR GENERATION IV SODIUM FAST REACTORS R. COULON, S. NORMAND, M. MICHEL, L.F-84500 Bollène, France. ABSTRACT The Phénix nuclear power plant has been a French Sodium Fast Reactor at the Phénix reactor shows that the use of 20 F as power tagging agent gives a fast and accurate power

  4. Review of FY 2001 Development Work for Vitrification of Sodium Bearing Waste

    SciTech Connect (OSTI)

    Taylor, Dean Dalton; Barnes, Charles Marshall

    2002-09-01

    Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated by the Settlement Agreement between the Department of Energy and the State of Idaho. This report discusses significant findings from vitrification technology development during 2001 and their impacts on the design basis for SBW vitrification.

  5. Review of FY2001 Development Work for Vitrification of Sodium Bearing Waste

    SciTech Connect (OSTI)

    Barnes, C.M.; Taylor, D.D.

    2002-09-09

    Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated by the Settlement Agreement between the Department of Energy and the State of Idaho. This report discusses significant findings from vitrification technology development during 2001 and their impacts on the design basis for SBW vitrification.

  6. HORTSCIENCE 47(10):15041511. 2012. Sodium Distribution in Salt-stressed

    E-Print Network [OSTI]

    Burns, Jacqueline K.

    HORTSCIENCE 47(10):1504­1511. 2012. Sodium Distribution in Salt-stressed Citrus Rootstock Seedlings 33850 Additional index words. Na+ exclusion, Na+ transport, salinity tolerance, salt stress, vacuole sequestration Abstract. Although citrus trees are considered relatively salt-sensitive, there are consistent

  7. Recovery of Ammonium and Cesium Ions from Aqueous Waste Streams by Sodium Tetraphenylborate

    E-Print Network [OSTI]

    Recovery of Ammonium and Cesium Ions from Aqueous Waste Streams by Sodium Tetraphenylborate Sherman of ammonium and cesium ions from aqueous waste stream simulants. The cesium or ammonium salts precipitated of cesium, the TPB anion is precipitated by addition of tripropylamine and HCl, and the Cs cation

  8. The sodium tail of the Moon M. Matta a,b,*, S. Smith a,1

    E-Print Network [OSTI]

    Mendillo, Michael

    , solar wind sputtering and meteoroid impact. Neutral sodium atoms escaping lunar gravity experience solar 2009 Available online xxxx Keywords: Moon Meteors Solar wind Solar radiation Image processing a b s t r wind proton energy flux and solar near ultra violet (NUV) patterns for possible correlations. Results

  9. Water Permeation through the Sodium-Dependent Galactose Cotransporter vSGLT

    E-Print Network [OSTI]

    Grabe, Michael

    Water Permeation through the Sodium-Dependent Galactose Cotransporter vSGLT Seungho Choe, John M It is well accepted that cotransporters facilitate water movement by two independent mechanisms: osmotic flow through a water channel in the protein and flow driven by ion/substrate cotransport. However

  10. Room-temperature stationary sodium-ion batteries for large-scale electric energy storage

    E-Print Network [OSTI]

    Wang, Wei Hua

    Room-temperature stationary sodium-ion batteries for large-scale electric energy storage Huilin Pan attention particularly in large- scale electric energy storage applications for renewable energy and smart, such as the wind and the sun, large-scale electric energy storage systems are becoming extremely important

  11. Continuous-wave sodium D2 resonance radiation generated in single-pass sum-frequency

    E-Print Network [OSTI]

    Continuous-wave sodium D2 resonance radiation generated in single-pass sum-frequency generation 4 Faculty of Engineering, Shinshu Universityl, Nagano, Japan 380-8553 5 STE Laboratory, Nagoya University, Japan 464-8601 *Corresponding author: jyue@lamar.colostate.edu Received January 5, 2009; accepted

  12. Modeling Zinc and Sodium Chloride Migration in Vadose Zone Soils Beneath Stormwater Infiltration Devices

    E-Print Network [OSTI]

    Clark, Shirley E.

    Modeling Zinc and Sodium Chloride Migration in Vadose Zone Soils Beneath Stormwater Infiltration in stormwater runoff and a decrease in groundwater recharge. Stormwater runoff contains pollutants (nutrients to the degradation of surface waters below stormwater pipe outfalls. Infiltrating stormwater has been shown

  13. THE CHANGES IN GROWTH AND COMPOSITION OF MARINE MICROALGAE IN RESPONSE TO SODIUM BICARBONATE AND NITROGEN 

    E-Print Network [OSTI]

    Nunez, Marcella M.M

    2013-02-04

    of renewable energy. In this biofuels research, two marine phytoplankton (Phaeodactylum tricornutum and Nannochloropsis salina) were grown in various sodium bicarbonate (NaHCO3) concentrations (0, 0.5, 1.0, 2.0, 5.0 gL-1) in f/2 medium during the growth phase...

  14. First results of a polychromatic artificial sodium star for the correction of tilt

    SciTech Connect (OSTI)

    Friedman, H.; Foy, R..; Tallon, M.; Migus, A.

    1996-03-06

    This paper presents the first results of a joint experiment carried out at Lawrence Livermore National Laboratory during January, 1996. Laser and optical systems were tested to provide a polychromatic artificial sodium star for the correction of tilt. This paper presents the results of that experiment.

  15. indirect study, coal was oxidatively de-graded with sodium dichromate and the

    E-Print Network [OSTI]

    Howat, Ian M.

    indirect study, coal was oxidatively de- graded with sodium dichromate and the esterified products- vestigators concluded (17, p. 380) that "thiophene derivatives must be indige- nous to coal." The direct XANES conmpounds yielded spectra that bore little resemblance to the coal spec- trum. For example, simulations

  16. The New York Times headquarters daylighting mockup: Monitored performance of the daylighting control system

    E-Print Network [OSTI]

    Lee, Eleanor S.; Selkowitz, Stephen E.

    2006-01-01

    is to instead achieve net “zero energy buildings” (ZEB) bysystems to achieve net zero energy use. Switchable windows,

  17. The New York Times headquarters daylighting mockup: Monitored performance of the daylighting control system

    E-Print Network [OSTI]

    Lee, Eleanor S.; Selkowitz, Stephen E.

    2006-01-01

    W, respectively. Lighting power density at full power levelssavings and average lighting power density savings for astandard deviation Lighting power density at full power:

  18. The New York Times headquarters daylighting mockup: Monitored performance of the daylighting control system

    E-Print Network [OSTI]

    Lee, Eleanor S.; Selkowitz, Stephen E.

    2006-01-01

    use savings were significant in both Areas over the equinox-to-equinox period compared to a non-daylit reference case.collected for only the equinox-to-equinox solar condition (

  19. The New York Times headquarters daylighting mockup: Monitored performance of the daylighting control system

    E-Print Network [OSTI]

    Lee, Eleanor S.; Selkowitz, Stephen E.

    2006-01-01

    sun down. The average work plane illuminance at 100% powersun down. However, the average work plane illuminance at 100% powersun in the afternoon. The fluorescent lights dimmed down gradually to minimum power (

  20. The New York Times headquarters daylighting mockup: Monitored performance of the daylighting control system

    E-Print Network [OSTI]

    Lee, Eleanor S.; Selkowitz, Stephen E.

    2006-01-01

    daily area lighting energy savings (%) sun up day of year BA Daily lighting energy use savings (sun up schedule) forarea lighting energy savings (%) L3 Sun up L4 L5 L6 day of

  1. Conceptual Design of a MEDE Treatment System for Sodium Bonded Fuel

    SciTech Connect (OSTI)

    Carl E. Baily; Karen A. Moore; Collin J. Knight; Peter B. Wells; Paul J. Petersen; Ali S. Siahpush; Matthew T. Weseman

    2008-05-01

    Unirradiated sodium bonded metal fuel and casting scrap material containing highly enriched uranium (HEU) is stored at the Materials and Fuels Complex (MFC) on the Idaho National Laboratory (INL). This material, which includes intact fuel assemblies and elements from the Fast Flux Test Facility (FFTF) and Experimental Breeder Reactor-II (EBR-II) reactors as well as scrap material from the casting of these fuels, has no current use under the terminated reactor programs for both facilities. The Department of Energy (DOE), under the Sodium-Bonded Spent Nuclear Fuel Treatment Record of Decision (ROD), has determined that this material could be prepared and transferred to an off-site facility for processing and eventual fabrication of fuel for commercial nuclear reactors. A plan is being developed to prepare, package and transfer this material to the DOE High Enriched Uranium Disposition Program Office (HDPO), located at the Y-12 National Security Complex in Oak Ridge, Tennessee. Disposition of the sodium bonded material will require separating the elemental sodium from the metallic uranium fuel. A sodium distillation process known as MEDE (Melt-Drain-Evaporate), will be used for the separation process. The casting scrap material needs to be sorted to remove any foreign material or fines that are not acceptable to the HDPO program. Once all elements have been cut and loaded into baskets, they are then loaded into an evaporation chamber as the first step in the MEDE process. The chamber will be sealed and the pressure reduced to approximately 200 mtorr. The chamber will then be heated as high as 650 ºC, causing the sodium to melt and then vaporize. The vapor phase sodium will be driven into an outlet line where it is condensed and drained into a receiver vessel. Once the evaporation operation is complete, the system is de-energized and returned to atmospheric pressure. This paper describes the MEDE process as well as a general overview of the furnace systems, as necessary, to complete the MEDE process.

  2. Sulfanegen sodium treatment in a rabbit model of sub-lethal cyanide toxicity

    SciTech Connect (OSTI)

    Brenner, Matthew; Kim, Jae G.; Lee, Jangwoen; Mahon, Sari B.; Lemor, Daniel; Ahdout, Rebecca; Boss, Gerry R.; Blackledge, William; Jann, Lauren; Nagasawa, Herbert T.; Patterson, Steven E.

    2010-11-01

    The aim of this study is to investigate the ability of intramuscular and intravenous sulfanegen sodium treatment to reverse cyanide effects in a rabbit model as a potential treatment for mass casualty resulting from cyanide exposure. Cyanide poisoning is a serious chemical threat from accidental or intentional exposures. Current cyanide exposure treatments, including direct binding agents, methemoglobin donors, and sulfur donors, have several limitations. Non-rhodanese mediated sulfur transferase pathways, including 3-mercaptopyruvate sulfurtransferase (3-MPST) catalyze the transfer of sulfur from 3-MP to cyanide, forming pyruvate and less toxic thiocyanate. We developed a water-soluble 3-MP prodrug, 3-mercaptopyruvatedithiane (sulfanegen sodium), with the potential to provide a continuous supply of substrate for CN detoxification. In addition to developing a mass casualty cyanide reversal agent, methods are needed to rapidly and reliably diagnose and monitor cyanide poisoning and reversal. We use non-invasive technology, diffuse optical spectroscopy (DOS) and continuous wave near infrared spectroscopy (CWNIRS) to monitor physiologic changes associated with cyanide exposure and reversal. A total of 35 animals were studied. Sulfanegen sodium was shown to reverse the effects of cyanide exposure on oxyhemoglobin and deoxyhemoglobin rapidly, significantly faster than control animals when administered by intravenous or intramuscular routes. RBC cyanide levels also returned to normal faster following both intramuscular and intravenous sulfanegen sodium treatment than controls. These studies demonstrate the clinical potential for the novel approach of supplying substrate for non-rhodanese mediated sulfur transferase pathways for cyanide detoxification. DOS and CWNIRS demonstrated their usefulness in optimizing the dose of sulfanegen sodium treatment.

  3. Liquid-Metal Electrode to Enable Ultra-Low Temperature Sodium-Beta Alumina Batteries for Renewable Energy Storage

    SciTech Connect (OSTI)

    Lu, Xiaochuan; Li, Guosheng; Kim, Jin Yong; Mei, Donghai; Lemmon, John P.; Sprenkle, Vincent L.; Liu, Jun

    2014-08-01

    Metal electrodes have a high capacity for energy storage but have found limited applications in batteries because of dendrite formation and other problems. In this paper, we report a new alloying strategy that can significantly reduce the melting temperature and improve wetting with the electrolyte to allow the use of liquid metal as anode in sodium-beta alumina batteries (NBBs) at much lower temperatures (e.g., 95 to 175°C). Commercial NBBs such as sodium-sulfur (Na-S) battery and sodium-metal halide (ZEBRA) batteries typically operate at relatively high temperatures (e.g., 300-350°C) due to poor wettability of sodium on the surface of ?"-Al2O3. Our combined experimental and computational studies suggest that Na-Cs alloy can replace pure sodium as the anode material, which provides a significant improvement in wettability, particularly at lower temperatures (i.e., <200°C). Single cells with the Na-Cs alloy anode exhibit excellent cycling life over those with pure sodium anode at 175 and 150°C. The cells can even operate at 95°C, which is below the melting temperature of pure sodium. These results demonstrate that NBB can be operated at ultra lower temperatures with successfully solving the wetting issue. This work also suggests a new strategy to use liquid metal as the electrode materials for advanced batteries that can avoid the intrinsic safety issues associated with dendrite formation on the anode.

  4. Induction of apoptotic death and retardation of neuronal differentiation of human neural stem cells by sodium arsenite treatment

    SciTech Connect (OSTI)

    Ivanov, Vladimir N., E-mail: vni3@columbia.edu [Center for Radiological Research, Department of Radiation Oncology, College of Physicians and Surgeons, Columbia University, 630 West 168th Street, NY 10032 (United States); Hei, Tom K. [Center for Radiological Research, Department of Radiation Oncology, College of Physicians and Surgeons, Columbia University, 630 West 168th Street, NY 10032 (United States)

    2013-04-01

    Chronic arsenic toxicity is a global health problem that affects more than 100 million people worldwide. Long-term health effects of inorganic sodium arsenite in drinking water may result in skin, lung and liver cancers and in severe neurological abnormalities. We investigated in the present study whether sodium arsenite affects signaling pathways that control cell survival, proliferation and neuronal differentiation of human neural stem cells (NSC). We demonstrated that the critical signaling pathway, which was suppressed by sodium arsenite in NSC, was the protective PI3K–AKT pathway. Sodium arsenite (2–4 ?M) also caused down-regulation of Nanog, one of the key transcription factors that control pluripotency and self-renewal of stem cells. Mitochondrial damage and cytochrome-c release induced by sodium arsenite exposure was followed by initiation of the mitochondrial apoptotic pathway in NSC. Beside caspase-9 and caspase-3 inhibitors, suppression of JNK activity decreased levels of arsenite-induced apoptosis in NSC. Neuronal differentiation of NSC was substantially inhibited by sodium arsenite exposure. Overactivation of JNK1 and ERK1/2 and down-regulation of PI3K–AKT activity induced by sodium arsenite were critical factors that strongly affected neuronal differentiation. In conclusion, sodium arsenite exposure of human NSC induces the mitochondrial apoptotic pathway, which is substantially accelerated due to the simultaneous suppression of PI3K–AKT. Sodium arsenite also negatively affects neuronal differentiation of NSC through overactivation of MEK–ERK and suppression of PI3K–AKT. - Highlights: ? Arsenite induces the mitochondrial apoptotic pathway in human neural stem cells. ? Arsenite-induced apoptosis is strongly upregulated by suppression of PI3K–AKT. ? Arsenite-induced apoptosis is strongly down-regulated by inhibition of JNK–cJun. ? Arsenite negatively affects neuronal differentiation by inhibition of PI3K–AKT.

  5. The feasibility of meeting the World Health Organization guidelines for sodium and potassium: a cross-national comparison study

    E-Print Network [OSTI]

    Drewnowski, Adam; Rehm, Colin D.; Maillot, Matthieu; Mendoza, Alfonso; Monsivais, Pablo

    2015-03-20

    dietary costs, while decreasing sodium intakes can likely be achieved in a cost neutral manner. Calorie-indexed dietary guidelines could also help. Population-wide sodium and potassium goals continue to be framed in mg per person per day, regardless... have numerous benefits.35–37 Perceived or actual food costs may be one reason why the observed sodium–potassium ratio is excessively high.38 Merging dietary intakes from the 2001 to 2002 NHANES with a national food price database showed that more...

  6. Proton conducting sodium alginate electrolyte laterally coupled low-voltage oxide-based transistors

    SciTech Connect (OSTI)

    Liu, Yang Hui; Wan, Qing; Qiang Zhu, Li; Shi, Yi

    2014-03-31

    Solution-processed sodium alginate electrolyte film shows a high proton conductivity of ?5.5?×?10{sup ?3} S/cm and a high lateral electric-double-layer (EDL) capacitance of ?2.0??F/cm{sup 2} at room temperature with a relative humidity of 57%. Low-voltage in-plane-gate indium-zinc-oxide-based EDL transistors laterally gated by sodium alginate electrolytes are fabricated on glass substrates. The field-effect mobility, current ON/OFF ratio, and subthreshold swing of such EDL transistors are estimated to be 4.2 cm{sup 2} V{sup ?1} s{sup ?1}, 2.8?×?10{sup 6}, and 130?mV/decade, respectively. At last, a low-voltage driven resistor-load inverter is also demonstrated. Such in-plane-gate EDL transistors have potential applications in portable electronics and low-cost biosensors.

  7. Experimental study of the effect of sodium carbonate on the conversion of cellulose to oil 

    E-Print Network [OSTI]

    Chu, Siu-Hung

    1981-01-01

    precipitated very fast, the mixture should be stirred up continuously until the slurry vas fed into the feed tank immediately after the reactor reached the desired preheated temperature. Once the feed vas fed, the feed tank was pressurized with nitrogen...) (Me mbe r) (He ber) (H d of Department- December 1981 ABSTHACT Experimental Study of the Effect of Sodium Carbonate on the Conversion of Cellulose to Oil. (December 19B1) Siu-Hunq Chu, B. A. , National Taiwan University Chairman of Advisory...

  8. Predictors and outcome impact of perioperative serum sodium changes in a high risk population

    E-Print Network [OSTI]

    Klinck, J.; McNeill, L.; Di Angelantonio, E.; Menon, D.

    2014-01-01

    Statistical analysis Summary statistics were computed for baseline characteristics and outcomes of the cohort. Hospital admissions were fitted in a multivariate logistic regression model to investigate the association between maximum change in sodium... drugs, selective serotonin re-uptake inhibitors, proton pump inhibitors, narcotics and numerous others.34-38 However, we suggest that when a cause is not apparent any abnormality found before major elective surgery should be investigated...

  9. Comparative effects of sodium channel blockers in short term rat whole embryo culture

    SciTech Connect (OSTI)

    Nilsson, Mats F, E-mail: Mats.Nilsson@farmbio.uu.se [Department of Pharmaceutical Biosciences, Uppsala University (Sweden); Sköld, Anna-Carin; Ericson, Ann-Christin; Annas, Anita; Villar, Rodrigo Palma [AstraZeneca R and D Södertälje (Sweden); Cebers, Gvido [AstraZeneca R and D, iMed, 141 Portland Street, Cambridge, MA 02139 (United States); Hellmold, Heike; Gustafson, Anne-Lee [AstraZeneca R and D Södertälje (Sweden); Webster, William S [Department of Anatomy and Histology, University of Sydney (Australia)

    2013-10-15

    This study was undertaken to examine the effect on the rat embryonic heart of two experimental drugs (AZA and AZB) which are known to block the sodium channel Nav1.5, the hERG potassium channel and the L-type calcium channel. The sodium channel blockers bupivacaine, lidocaine, and the L-type calcium channel blocker nifedipine were used as reference substances. The experimental model was the gestational day (GD) 13 rat embryo cultured in vitro. In this model the embryonic heart activity can be directly observed, recorded and analyzed using computer assisted image analysis as it responds to the addition of test drugs. The effect on the heart was studied for a range of concentrations and for a duration up to 3 h. The results showed that AZA and AZB caused a concentration-dependent bradycardia of the embryonic heart and at high concentrations heart block. These effects were reversible on washout. In terms of potency to cause bradycardia the compounds were ranked AZB > bupivacaine > AZA > lidocaine > nifedipine. Comparison with results from previous studies with more specific ion channel blockers suggests that the primary effect of AZA and AZB was sodium channel blockage. The study shows that the short-term rat whole embryo culture (WEC) is a suitable system to detect substances hazardous to the embryonic heart. - Highlights: • Study of the effect of sodium channel blocking drugs on embryonic heart function • We used a modified method rat whole embryo culture with image analysis. • The drugs tested caused a concentration dependent bradycardia and heart block. • The effect of drugs acting on multiple ion channels is difficult to predict. • This method may be used to detect cardiotoxicity in prenatal development.

  10. Relative fluorescent efficiency of sodium salicylate between 90 and 800 eV

    SciTech Connect (OSTI)

    Angel, G.C.; Samson, J.A.R.; Williams, G.

    1986-01-01

    The relative fluorescent quantum efficiency of sodium salicylate was measured between 90 and 800 eV (138 -15 A) by the use of synchrotron radiation. A general increase in efficiency was observed in this spectral range except for abrupt decreases in efficiency at the carbon and oxygen K-edges. Beyond the oxygen K-edge (532 eV) the efficiency increased linearly with the incident photon energy to the limit of the present observations.

  11. Laser system design for the generation of a sodium-layer laser guide star

    SciTech Connect (OSTI)

    Friedman, H.W.

    1993-01-01

    The design considerations for a laser system used to generate a sodium-layer guide star are presented. Laser technology developed for the Atomic Vapor Laser Isotope Separation (AVLIS) Program is shown to be directly relevant to this problem and results of a demonstration using the AVLIS laser to generate such a guide star are shown. The design of a compact laser suitable for use at a large telescope such as the Keck is also presented.

  12. Response of rat brain protein synthesis to ethanol and sodium barbital

    SciTech Connect (OSTI)

    Tewari, S.; Greenberg, S.A.; Do, K.; Grey, P.A.

    1987-01-01

    Central nervous system (CNS) depressants such as ethanol and barbiturates under acute or chronic conditions can induce changes in rat brain protein synthesis. While these data demonstrate the individual effects of drugs on protein synthesis, the response of brain protein synthesis to alcohol-drug interactions is not known. The goal of the present study was to determine the individual and combined effects of ethanol and sodium barbital on brain protein synthesis and gain an understanding of the mechanisms by which these alterations in protein synthesis are produced. Specifically, the in vivo and in vitro effects of sodium barbital (one class of barbiturates which is not metabolized by the hepatic tissue) were examined on brain protein synthesis in rats made physically dependent upon ethanol. Using cell free brain polysomal systems isolated from Control, Ethanol and 24 h Ethanol Withdrawn rats, data show that sodium barbital, when intubated intragastrically, inhibited the time dependent incorporation of /sup 14/C) leucine into protein by all three groups of ribosomes. Under these conditions, the Ethanol Withdrawn group displayed the largest inhibition of the /sup 14/C) leucine incorporation into protein when compared to the Control and Ethanol groups. In addition, sodium barbital when added at various concentrations in vitro to the incubation medium inhibited the incorporation of /sup 14/C) leucine into protein by Control and Ethanol polysomes. The inhibitory effects were also obtained following preincubation of ribosomes in the presence of barbital but not cycloheximide. Data suggest that brain protein synthesis, specifically brain polysomes, through interaction with ethanol or barbital are involved in the functional development of tolerance. These interactions may occur through proteins or polypeptide chains or alterations in messenger RNA components associated with the ribosomal units.

  13. Mechanical relaxation behavior of polyurethanes reinforced with the in situ-generated sodium silica-polyphosphate nanophase

    E-Print Network [OSTI]

    V. O. Dupanov; S. M. Ponomarenko

    2014-10-31

    Further exploration of hybrid organic/inorganic composites (polyurethane based with inorganic material sodium silica polyphosphate) properties with mechanical relaxometer gives ability to analyze microstructure of such materials in terms of chain reptation tubes filler's fractal aggregates and stress amplification.

  14. Effect of different ratios of sodium to chloride using isokalemic diets for growing and finishing swine raised during hot weather 

    E-Print Network [OSTI]

    Serna-Saldivar, Sergio Othon

    1982-01-01

    ABSTBXCT Effect of Different Ratios of Sodium to Chloride Using Isokalemic Diets for Growing and Pinishing Swine Raised During Hot Weather {Bay 1982) Sergio Othon Serna-Saldivar B. S, Inn tituto Tecnologico y de Estudios Superiores de monterrey...

  15. Palladium-Catalyzed Cross-Coupling of Aryl Chlorides and Triflates with Sodium Cyanate: A Practical Synthesis of Unsymmetrical Ureas

    E-Print Network [OSTI]

    Fors, Brett P.

    An efficient method for palladium-catalyzed cross-coupling of aryl chlorides and triflates with sodium cyanate is reported. The protocol allows for the synthesis of unsymmetrical N,N?-di- and N,N,N?-trisubstituted ureas ...

  16. A four-equation two-phase flow model for sodium boiling simulation of LMFBR fuel assemblies

    E-Print Network [OSTI]

    Schor, Andrei L.

    1982-01-01

    A three-dimensional numerical model for the simulation of sodium boiling transients has been developed. The model uses mixture mass and energy equations, while employing a separate momentum equation for each phase. Thermal ...

  17. Development of models for the two-dimensional, two-fluid code for sodium boiling NATOF-2D

    E-Print Network [OSTI]

    Zielinski, R. G.

    1981-01-01

    Several features were incorporated into NATOF-2D, a twodimensional, two fluid code developed at M.I.T. for the purpose of analysis of sodium boiling transients under LMFBR conditions. They include improved interfacial mass, ...

  18. Modelling of thermo-mechanical and irradiation behavior of metallic and oxide fuels for sodium fast reactors

    E-Print Network [OSTI]

    Karahan, Aydin

    2009-01-01

    A robust and reliable code to model the irradiation behavior of metal and oxide fuels in sodium cooled fast reactors is developed. Modeling capability was enhanced by adopting a non-empirical mechanistic approach to the ...

  19. Under-sodium viewing technology for improvement of fast-reactor safeguards

    SciTech Connect (OSTI)

    Beddingfield, David H; Gerhart, Jeremy J; Kawakubo, Yoko

    2009-01-01

    The current safeguards approach for fast reactors relies exclusively on maintenance of continuity of knowledge to track the movement of fuel assemblies through these facilities. The remote handling of fuel assemblies, the visual opacity of the liquid metal coolant. and the chemical reactivity of sodium all combine and result in significant limitations on the available options to verify fuel assembly identification numbers or the integrity of these assemblies. These limitations also serve to frustrate attempts to restore the continuity-of-knowledge in instances where the information is under a variety of scenarios. The technology of ultrasonic under-sodium viewing offers new options to the safeguards community for recovering continuity-of-knowledge and applying more traditional item accountancy to fast reactor facilities. We have performed a literature review to investigate the development of under-sodium viewing technologies. In this paper we will summarize our findings and report the state of development of this technology and we will present possible applications to the fast reactor system to improve the existing safeguards approach at these reactors and in future fast reactors.

  20. Intermediate-scale tests of sodium interactions with calcite and dolomite aggregate concretes. [LMFBR

    SciTech Connect (OSTI)

    Randich, E.; Acton, R.U.

    1983-09-01

    Two intermediate-scale tests were performed to compare the behavior of calcite and dolomite aggregate concretes when attacked by molten sodium. The tests were performed as part of an interlaboratory comparison between Sandia National Laboratories and Hanford Engineering Development Laboratories. Results of the tests at Sandia National Laboratories are reported here. The results show that both concretes exhibit similar exothermic reactions with molten sodium. The large difference in reaction vigor suggested by thermodynamic considerations of CO/sub 2/ release from calcite and dolomite was not realized. Penetration rates of 1.4 to 1.7 mm/min were observed for short periods of time with reaction zone temperatures in excess of 800/sup 0/C during the energetic attack. The penetration was not uniform over the entire sodium-concrete contact area. Rapid attack may be localized due to inhomogeneities in the concrete. The chemical reaction zone is less then one cm thick for the calcite concrete but is about seven cm thick for the dolomite concrete.

  1. A Non-isothermal Theory for Interpreting Sodium Lines in Transmission Spectra of Exoplanets

    E-Print Network [OSTI]

    Heng, Kevin; Lavie, Baptiste; Sing, David K; Ehrenreich, David; Lovis, Christophe

    2015-01-01

    We present a theory for interpreting the sodium lines detected in transmission spectra of exoplanetary atmospheres. Previous analyses employed the isothermal approximation and dealt only with the transit radius. By recognising the absorption depth and the transit radius as being independent observables, we develop a theory for jointly interpreting both quantities, which allows us to infer the temperatures and number densities associated with the sodium lines. We are able to treat a non-isothermal situation with a constant temperature gradient. Our novel diagnostics take the form of simple-to-use algebraic formulae and require measurements of the transit radii (and their corresponding absorption depths) at line center and in the line wing for both sodium lines. We apply our diagnostics to the HARPS data of HD 189733b, confirm the upper atmospheric heating reported by Huitson et al. (2012), derive a temperature gradient of $0.4376 \\pm 0.0154$ K km$^{-1}$ and find densities $\\sim 1$ to $10^4$ cm$^{-3}$.

  2. Reliability Engineering Approach to Probabilistic Proliferation Resistance Analysis of the Example Sodium Fast Reactor Fuel Cycle Facility 

    E-Print Network [OSTI]

    Cronholm, Lillian Marie

    2012-10-19

    ENGINEERING APPROACH TO PROBABILISTIC PROLIFERATION RESISTANCE ANALYSIS OF THE EXAMPLE SODIUM FAST REACTOR FUEL CYCLE FACILITY A Thesis by LILLIAN MARIE CRONHOLM Submitted to the Office of Graduate Studies of Texas A&M University in partial... fulfillment of the requirements for the degree of MASTER OF SCIENCE August 2011 Major Subject: Health Physics RELIABILITY ENGINEERING APPROACH TO PROBABILISTIC PROLIFERATION RESISTANCE ANALYSIS OF THE EXAMPLE SODIUM FAST REACTOR FUEL...

  3. Evaluation of whole plant grain sorghum silage processing methods and lasalocid sodium levels on stocker calf performance and rumen fermentation 

    E-Print Network [OSTI]

    Gutierrez Garza, Gerardo

    1980-01-01

    EVALUATION OF WHOLE PLANT GRAIN SORGHUM SILAGE PROCESSING METHODS AND LASALOCID SODIUM LEVELS ON STOCKER CALF PERFORMANCE AND RUMEN FERMENTATION A Thesis GERARDO GUTIERREZ GARZA Submitted to the Graduate College of Texas ABM University... in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE December 1980 Major Subject: Animal Science EVALUATION OF WHOLE PLANT GRAIN SORGHUM SILAGE PROCESSING METHODS AND LASALOCID SODIUM LEVELS ON STOCKER CALF PERFORMANCE AND RUMEN...

  4. Probing the Failure Mechanism of SnO2 Nanowires for Sodium-ion Batteries

    SciTech Connect (OSTI)

    Gu, Meng; Kushima, Akihiro; Shao, Yuyan; Zhang, Jiguang; Liu, Jun; Browning, Nigel D.; Li, Ju; Wang, Chong M.

    2013-09-30

    Non-lithium metals such as sodium have attracted wide attention as a potential charge carrying ion for rechargeable batteries, performing the same role as lithium in lithium- ion batteries. As sodium and lithium have the same +1 charge, it is assumed that what has been learnt about the operation of lithium ion batteries can be transferred directly to sodium batteries. Using in-situ TEM, in combination with DFT calculations, we probed the structural and chemical evolution of SnO2 nanowire anodes in Na-ion batteries and compared them quantitatively with results from Li-ion batteries [Science 330 (2010) 1515]. Upon Na insertion into SnO2, a displacement reaction occurs, leading to the formation of amorphous NaxSn nanoparticles covered by crystalline Na2O shell. With further Na insertion, the NaxSn core crystallized into Na15Sn4 (x=3.75). Upon extraction of Na (desodiation), the NaxSn core transforms to Sn nanoparticles. Associated with a volume shrinkage, nanopores appear and metallic Sn particles are confined in hollow shells of Na2O, mimicking a peapod structure. These pores greatly increase electrical impedance, therefore naturally accounting for the poor cyclability of SnO2. DFT calculations indicate that Na+ diffuses 30 times slower than Li+ in SnO2, in agreement with in-situ TEM measurement. Insertion of Na can chemo-mechanically soften the reaction product to greater extent than in lithiation. Therefore, in contrast to the lithiation of SnO2, no dislocation plasticity was seen ahead of the sodiation front. This direct comparison of the results from Na and Li highlights the critical role of ionic size and electronic structure of different ionic species on the charge/discharge rate and failure mechanisms in these batteries.

  5. Production of high brightness H- beam by charge exchange of hydrogen atom beam in sodium jet

    SciTech Connect (OSTI)

    Davydenko, V.; Zelenski, A.; Ivanov, A.; Kolmogorov, A.

    2010-11-16

    Production of H{sup -} beam for accelerators applications by charge exchange of high brightness hydrogen neutral beam in a sodium jet cell is experimentally studied in joint BNL-BINP experiment. In the experiment, a hydrogen-neutral beam with 3-6 keV energy, equivalent current up to 5 A and 200 microsecond pulse duration is used. The atomic beam is produced by charge exchange of a proton beam in a pulsed hydrogen target. Formation of the proton beam is performed in an ion source by four-electrode multiaperture ion-optical system. To achieve small beam emittance, the apertures in the ion-optical system have small enough size, and the extraction of ions is carried out from the surface of plasma emitter with a low transverse ion temperature of {approx}0.2 eV formed as a result of plasma jet expansion from the arc plasma generator. Developed for the BNL optically pumped polarized ion source, the sodium jet target with recirculation and aperture diameter of 2 cm is used in the experiment. At the first stage of the experiment H{sup -} beam with 36 mA current, 5 keV energy and {approx}0.15 cm {center_dot} mrad normalized emittance was obtained. To increase H{sup -} beam current ballistically focused hydrogen neutral beam will be applied. The effects of H{sup -} beam space-charge and sodium-jet stability will be studied to determine the basic limitations of this approach.

  6. Multi-scale Patterns formed by Sodium Sulphate in a Drying Droplet of Gelatin

    E-Print Network [OSTI]

    Biswajit Roy; Moutushi Dutta Choudhuri; Tapati Dutta; Sujata Tarafdar

    2015-06-20

    We present a study of patterns, formed in drying drops of aqueous gelatin solution containing sodium sulphate. The patterns are highly complex, consisting of a hierarchical sequence of rings which form concentric bands as well as dendritic crystalline aggregates. When the preparation of the complex fluid is done by mixing an aqueous solution of the salt with an aqueous solution of gelatin prepared separately, another feature is observed in the pattern on the dried out drop. This is a viscous fingering pattern, superposed on the series of rings. We try to explain the origin of these two features from a simple physical approach.

  7. Neutronic/Thermalhydraulic Coupling Technigues for Sodium Cooled Fast Reactor Simulations

    SciTech Connect (OSTI)

    Jean Ragusa; Andrew Siegel; Jean-Michel Ruggieri

    2010-09-28

    The objective of this project was to test new coupling algorithms and enable efficient and scalable multi-physics simulations of advanced nuclear reactors, with considerations regarding the implementation of such algorithms in massively parallel environments. Numerical tests were carried out to verify the proposed approach and the examples included some reactor transients. The project was directly related to the Sodium Fast Reactor program element of the Generation IV Nuclear Energy Systems Initiative and the Advanced Fuel cycle Initiative, and, supported the requirement of high-fidelity simulation as a mean of achieving the goals of the presidential Global Nuclear Energy Partnership (GNEP) vision.

  8. A parametric study of the breeding ratio in sodium cooled fast breeder reactors 

    E-Print Network [OSTI]

    Sobey, Thomas Milburn

    1969-01-01

    of fuel as opposed to the destruction of it on an isotopic level, rather than an elemental level. The objective of this -thesis is to investigate the dependence of the breeding ratio i. n a Sodium Cooled Fast Breeder Reactor on the 5sotopic composii.... 'FPHETRIC STIJDY OF THE BREEDING RATIO SODIlnnJ COOL J'. P FAST BREEJ)ER REACTORS A Tgesis TEO'. ~YS ', ~JILBlJRY SUBEY Sugmitt d to tlso Graduate College of Icxa~ ASH I'niversity in '. artia1 Iuliiliniost of t!ns reguireeents for tge deg ee...

  9. Sodium and potassium levels in the serum of acutely irradiated and non-irradiated rats 

    E-Print Network [OSTI]

    Shepherd, David Preston

    1967-01-01

    . The rats were exposed separately for a period of two minutes. The dose rate measurements were determined prior to this study by using lithium fluoride dosimeter s, and were brought up to date by calculation. Twenty-four hours before irradiation, one ml... carbonate 10 drops Magnesium sulfate 25 mgm Manganese sulfate 7. 5 mgm Iron phosphate 500 gm Sodium fluoride 1 mgm Potassium iodide 25 mcgm Potassium phosphate 1 mgm Potassium chloride 10 mgm 10 mgm Copper Sulfate 40 rngm Aluminum potassium s ul...

  10. Galvanic corrosion of structural aluminum coupled with mild steel in a dilute sodium dichromate electrolyte 

    E-Print Network [OSTI]

    Ford, Robert Franklin

    1970-01-01

    or the requirement for' the deqr, e of MASTER OF SCIl-NCI= Jaruary IgiO Major Sub ect: Civii I. ngineering GALVANIC CORROSION GF STRUCTURAI. ALUMINUM COUPLED WITH MILD STI:EL IN A DILUTE SODIUii DICIIROMA1'E ELECTROLTTE A Thesis ROBERT FRANKLIN FORD, JR.... Approved as to style and content by: + ~J Co-Chairman of Commii:t C Co-Chair n of Committe~e Member+ I Head of D=p rtm t) Januar; IDIO ABSTRACT Calvanic Corrosion of Structural Aluminum Coup'led with Mild Steel in a Dilute Sodium Dichromate...

  11. Under-Sodium Viewing: A Review of Ultrasonic Imaging Technology for Liquid Metal Fast Reactors

    SciTech Connect (OSTI)

    Griffin, Jeffrey W.; Peters, Timothy J.; Posakony, Gerald J.; Chien, Hual-Te; Bond, Leonard J.; Denslow, Kayte M.; Sheen, Shuh-Haw; Raptis, Paul

    2009-03-27

    This current report is a summary of information obtained in the "Information Capture" task of the U.S. DOE-funded "Under Sodium Viewing (USV) Project." The goal of the multi-year USV project is to design, build, and demonstrate a state-of-the-art prototype ultrasonic viewing system tailored for periodic reactor core in-service monitoring and maintenance inspections. The study seeks to optimize system parameters, improve performance, and re-establish this key technology area which will be required to support any new U.S. liquid-metal cooled fast reactors.

  12. Tracers for monitoring the activity of sodium/glucose cotransporters in health and disease

    DOE Patents [OSTI]

    Wright, Ernest M; Barrio, Jorge R; Hirayama, Bruce A; Kepe, Vladimir

    2014-09-30

    Radiolabeled tracers for sodium/glucose cotransporters (SGLTs), their synthesis, and their use are provided. The tracers are methyl or ethyl pyranosides having an equatorial hydroxyl group at carbon-2 and a C 1 preferred conformation, radiolabeled with .sup.18F, .sup.123I, or .sup.124I, or free hexoses radiolabeled with .sup.18F, .sup.123I, or .sup.124. Also provided are in vivo and in vitro techniques for using these and other tracers as analytical and diagnostic tools to study glucose transport, in health and disease, and to evaluate therapeutic interventions.

  13. Hugoniot Measurements at Low Pressures in Tin Using 800 MeV proton Radiography

    SciTech Connect (OSTI)

    Schwartz, Cynthia; Hogan, Gary E; King, Nicholas S. P.; Kwiathowski, Kris K.; Mariam, Fesseha G.; Marr-Lyon, Mark; McNeil, Wendy Vogan; Merrill, Frank E.; Morris, Christopher; Rightley, Paul; Saunders, Alexander

    2009-08-05

    A 2cm long 8 mm diameter cylindrical tin target has been shocked to a pressure in the region of the {beta} {yields} {gamma} phase change using a small, low density PETN charge mounted on the opposite side of a stainless steel diaphragm. The density jump and shock velocity were measured radiographically as the shock wave moved through the sample and the pressure dropped, using the proton radiography facility at LANL. This provided a quasi-continuous record of the equations of state along the Hugoniot for the P1 wave from a shock velocity of 3.25 km/sec down to near the sound speed. Edge release effects were removed from the data using tomographic techniques. The data show evidence for a phase transition that extends over a broad pressure range. The data and analysis will be presented.

  14. HUGONIOT MEASUREMENTS AT LOW PRESSURES IN TIN USING 800 MeV PROTON RADIOGRAPHY

    SciTech Connect (OSTI)

    Schwartz, C. L.; Hogan, G. E.; King, N. S. P.; Kwiatkowski, K.; Mariam, F. G.; Merrill, F. E.; Morris, C. L.; Saunders, A.; Marr-Lyon, M.; Rightley, P. M.; McNeil, W. V.

    2009-12-28

    A 20 mm long 8 mm diameter cylindrical tin target has been shocked to a pressure just below the beta->gamma phase change, using a small, low density PETN charge mounted on the opposite side of a thin stainless steel diaphragm. The density jump and shock velocity were measured radiographically at multiple points as the shock wave moved though the sample and the pressure dropped, using the proton radiography facility at LANL. This provided a quasi-continuous record along the principal Hugoniot from a peak shock velocity of 3.27 km/sec to a minimum of 3.09 km/sec. Edge release effects were removed from the data using simple tomographic reconstruction techniques. The data and analysis are presented.

  15. ULTRA LOW PRESSURE-DROP HELIUM-COOLED POROUS-TUNGSTEN PFC S. Sharafat1

    E-Print Network [OSTI]

    Ghoniem, Nasr M.

    heat flux tests show maximum heat loads of 22.4 MW/m2 using 4 MPa helium at a flow rate of 27 g in magnetically confined plasma devices will be subject to high thermal heat loads. The next step ITER Tokamak heat-flux plasma facing heat exchanger (HX) concept is presented. These unique "Foam-In-Tube" HX

  16. Low pressure electrospray ionization system and process for effective transmission of ions

    DOE Patents [OSTI]

    Tang, Keqi (Richland, WA); Page, Jason S. (Kennewick, WA); Kelly, Ryan T. (Wet Richland, WA); Smith, Richard D. (Richland, WA)

    2010-03-02

    A system and method are disclosed that provide up to complete transmission of ions between coupled stages with low effective ion losses. A novel "interfaceless" electrospray ionization system is further described that operates the electrospray at a reduced pressure such that standard electrospray sample solutions can be directly sprayed into an electrodynamic ion funnel which provides ion focusing and transmission of ions into a mass analyzer.

  17. Low pressure electrospray ionization system and process for effective transmission of ions

    DOE Patents [OSTI]

    Tang, Keqi (Richland, WA); Page, Jason S (Kennewick, WA); Kelly, Ryan T (West Richland, WA); Smith, Richard D (Richland, WA)

    2012-05-08

    Systems and methods that provide up to complete transmission of ions between coupled stages with low effective ion losses. An "interfaceless" electrospray ionization system is further described that operates an electrospray at a reduced pressure such that standard electrospray sample solutions can be directly sprayed into an electrodynamic ion funnel which provides ion focusing and transmission of ions into a mass analyzer. Furthermore, chambers maintained at different pressures can allow for more optimal operating conditions for an electrospray emitter and an ion guide.

  18. Electrical time resolved metrology of dust particles growing in low pressure cold plasmas

    SciTech Connect (OSTI)

    Wattieaux, Gaeetan [PRISME, Orleans University, 12 rue de Blois BP 6744, 45067 Orleans cedex 2 (France); Mezeghrane, Abdelaziz [LPCQ, Mouloud Mammeri University, Tizi-Ouzou (Algeria); Boufendi, Laiefa [GREMI, Orleans University, 14 rue d'Issoudun BP 6744, 45067 Orleans cedex 2 (France)

    2011-09-15

    The electrical parameters of a capacitively coupled radiofrequency (CCRF) discharge change significantly when dust arises in the discharge. This work demonstrates the ability to follow in real time the evolution of the size and of the concentration of dust particles forming in a CCRF discharge from the variation of the electron density and of the self-bias voltage of the active electrode. According to experimental findings, it appears that the variation of this self-bias voltage depends on the surface of the dust particles. This trend is confirmed by an analytical modelling considering the low frequency behaviour of the phenomenon.

  19. Measurement of effective sheath width around cutoff probe in low-pressure plasmas

    SciTech Connect (OSTI)

    Kim, D. W.; Oh, W. Y. [Department of Mechanical Engineering, Korea Advanced Institute of Science and Technology, Daejeon 305-701 (Korea, Republic of)] [Department of Mechanical Engineering, Korea Advanced Institute of Science and Technology, Daejeon 305-701 (Korea, Republic of); You, S. J., E-mail: sjyou@kriss.re.kr; Kim, J. H. [Center for Vacuum Technology, Korea Research Institute of Standards and Science, Daejeon 305-306 (Korea, Republic of)] [Center for Vacuum Technology, Korea Research Institute of Standards and Science, Daejeon 305-306 (Korea, Republic of); Chang, H. Y. [Department of Physics, Korea Advanced Institute of Science and Technology, Daejeon 305-701 (Korea, Republic of)] [Department of Physics, Korea Advanced Institute of Science and Technology, Daejeon 305-701 (Korea, Republic of)

    2014-05-15

    Previous studies indicated that the measurement results of microwave probes can be improved by applying the adequate sheath width to their measurement models, and consequently the sheath width around the microwave probe tips has become very important information for microwave probe diagnostics. In this paper, we propose a method for measuring the argon plasma sheath width around the cutoff probe tips by applying the circuit model to the cutoff probe phase spectrum. The measured sheath width of the cutoff probe was found to be in good agreement with the floated sheath width calculated from the Child-Langmuir sheath law. The physical reasons for a discrepancy between the two measurements are also discussed.

  20. POSITION TRACKING CONTROL OF MINIATURE LOW PRESSURE WATER HYDRAULIC CYLINDERS Russell Sindrey and Gary M. Bone

    E-Print Network [OSTI]

    Bone, Gary

    diameter cylinders. Four off-the-shelf, low cost, 2/2 on-off miniature solenoid valves were used to control, which allowed the on-off valves to approximate the behaviour of proportional solenoid valves, increasing mechanism to power a small rotary joint. Advantages of hydraulic cylinders include their high power

  1. Microwave ECR plasma electron flood for low pressure wafer charge neutralization

    SciTech Connect (OSTI)

    Vanderberg, Bo; Nakatsugawa, Tomoya; Divergilio, William

    2012-11-06

    Modern ion implanters typically use dc arc discharge Plasma Electron Floods (PEFs) to neutralize wafer charge. The arc discharge requires using at least some refractory metal hardware, e.g. a thermionically emitting filament, which can be undesirable in applications where no metallic contamination is critical. rf discharge PEFs have been proposed to mitigate contamination risks but the gas flows required can result in high process chamber pressures. Axcelis has developed a microwave electron cyclotron resonance (ECR) PEF to provide refractory metals contamination-free wafer neutralization with low gas flow requirement. Our PEF uses a custom, reentrant cusp magnet field providing ECR and superior electron confinement. Stable PEF operation with extraction slits sized for 300 mm wafers can be attained at Xe gas flows lower than 0.2 sccm. Electron extraction currents can be as high as 20 mA at absorbed microwave powers < 70 W. On Axcelis' new medium current implanter, plasma generation has proven robust against pressure transients caused by, for example, photoresist outgassing by high power ion beams. Charge monitor and floating potential measurements along the wafer surface corroborate adequate wafer charge neutralization for low energy, high current ion beams.

  2. Some effects of low-pressure steam curing on some of the physical properties of concrete 

    E-Print Network [OSTI]

    Burleson, Kerry Edward

    1958-01-01

    Standards~ 1955, Part 3t ASTN Designa- tion - C-293-54. T ~ os"Compressive Strength of Concrete &sing Port1ons of Beams Broken in Flexure ~ American Society of Testing Materials Standards, 1955, Part 3& ASTM Designation - 0-116-49, FIGURE 6 COMPRESSION... 3i ASTM Designation - C215-55T ' ", "dl!&&, ): ". i&s ! , . gN, , X', t, ??jN, l1!+3 KfP8E K5f &~, ~' h5 OF R '. . S. SF. " Ill(I'fllilf IKJA, ';?. . f 1 20, The second test was the determ1nat1on of the modulus of rupture. The center...

  3. Low pressure shock initiation of porous HMX for two grain size distributions and two densities

    SciTech Connect (OSTI)

    Gustavsen, R.L.; Sheffield, S.A.; Alcon, R.R.

    1995-09-01

    Shock initiation measurements have been made on granular HMX (octotetramethylene tetranitrainine) for two particle size distributions and two densities. Samples were pressed to either 65% or 73% of crystal density from fine ({approx} 10 {mu}m grain size) and coarse (broad distribution of grain sizes peaking at {approx} 150 {mu}m) powders. Planar shocks of 0.2--1 GPa were generated by impacting gas gun driven projectiles on plastic targets containing the HMX. Wave profiles were measured at the input and output of the {approx} 3.9 mm thick HMX layer using electromagnetic particle velocity gauges. The initiation behavior for the two particle size distributions was very different. The coarse HMX began initiating at input pressures as low as 0.5 GPa. Transmitted wave profiles showed relatively slow reaction with most of the buildup occurring at the shock front. In contrast, the fine particle HMX did not begin to initiate at pressures below 0.9 GPa. When the fine powder did react, however, it did so much faster than the coarse HMX. These observations are consistent with commonly held ideas about bum rates being correlated to surface area, and initiation thresholds being correlated with the size and temperature of the hot spots created by shock passage. For each size, the higher density pressings were less sensitive than the lower density pressings.

  4. Decay of a low-pressure oxygen magnetized and unmagnetized plasma

    SciTech Connect (OSTI)

    Levko, Dmitry [LAPLACE (Laboratoire Plasma et Conversion d'Energie), Universite de Toulouse, UPS, INPT Toulouse, 118 route de Narbonne, F-31062 Toulouse cedex 9 (France)

    2014-09-14

    Extraction of negative ions from electronegative plasmas is one of the key issues addressed during the study of these plasmas. One of the widely used methods is the turn off of the electron heating power. This results in the escape of electrons from the plasma and results in the formation of almost pure ion-ion plasma. In the latter case, the plasma sheath collapses, which enables the extraction of negative ions from the plasma. Another method is the application of a large magnetic field to the plasma. If the electrons become magnetized and trapped near the center of discharge chamber, the plasma sheaths near the walls collapse. This also enables the negative ion extraction from the plasma even during the power-on stage. The aim of the present paper is the comparison of these two methods.

  5. A model of the directional sensitivity of low-pressure CF? dark matter detectors

    E-Print Network [OSTI]

    Deaconu, Cosmin ?tefan

    2015-01-01

    Identification of the composition of dark matter is one of the major unsolved puzzles in modern physics. Detectors with sensitivity to the direction of certain classes of dark matter particles have potentially very powerful ...

  6. Experimental study of the effects of wakes on separation in low pressure turbine flow 

    E-Print Network [OSTI]

    O?ztu?rk, Burak

    2003-01-01

    the underlying physics of the inception, onset, and extent of the separation zone. A detailed experimental study on the behavior of the separation zone on the suction surface of a highly loaded LPTblade under periodic unsteady wake flow is presented...

  7. Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on steam jet ejectors and thermocompressors provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  8. Low pressure chemical vapor deposition synthesis of hexagonal boron nitride on

    E-Print Network [OSTI]

    Zettl, Alex

    deposition (LPCVD) from borazine, with nickel, copper and platinum employed as catalytic substrates], and nanotubes [10]. Although many fundamental studies of graphene, and to a much lesser extent, h-BN, have been

  9. Experimental observation of standing wave effect in low-pressure very-high-frequency capacitive discharges

    SciTech Connect (OSTI)

    Liu, Yong-Xin; Gao, Fei; Liu, Jia; Wang, You-Nian

    2014-07-28

    Radial uniformity measurements of plasma density were carried out by using a floating double probe in a cylindrical (21?cm in electrode diameter) capacitive discharge reactor driven over a wide range of frequencies (27–220 MHz). At low rf power, a multiple-node structure of standing wave effect was observed at 130?MHz. The secondary density peak caused by the standing wave effect became pronounced and shifts toward the axis as the driving frequency further to increase, indicative of a much more shortened standing-wave wavelength. With increasing rf power, the secondary density peak shift toward the radial edge, namely, the standing-wave wavelength was increased, in good qualitative agreement with the previous theory and simulation results. At higher pressures and high frequencies, the rf power was primarily deposited at the periphery of the electrode, due to the fact that the waves were strongly damped as they propagated from the discharge edge into the center.

  10. Low pressure epitaxial growth, fabrication and characterizion of Ge-on-Si photodiodes

    E-Print Network [OSTI]

    Olubuyide, Oluwamuyiwa Oluwagbemiga, 1979-

    2007-01-01

    In order to facilitate the integration of photonic systems onto an electronic chip, near infrared photodiodes utilizing novel materials such as germanium must be monolithically integrated onto the Si CMOS platform. Such ...

  11. Low-pressure-ratio regenerative exhaust-heated gas turbine. Final report

    SciTech Connect (OSTI)

    Tampe, L.A.; Frenkel, R.G.; Kowalick, D.J.; Nahatis, H.M.; Silverstein, S.M.; Wilson, D.G.

    1991-01-01

    A design study of coal-burning gas-turbine engines using the exhaust-heated cycle and state-of-the-art components has been completed. In addition, some initial experiments on a type of rotary ceramic-matrix regenerator that would be used to transfer heat from the products of coal combustion in the hot turbine exhaust to the cool compressed air have been conducted. Highly favorable results have been obtained on all aspects on which definite conclusions could be drawn.

  12. Performance characteristics of a low pressure cyclone for axial-flow fan exhausts 

    E-Print Network [OSTI]

    Simpson, Shay Lynn

    1996-01-01

    on axial-flow fan exhausts to significantly reduce particulate emissions. Average emission concentrations, cut-point diameters, PMIO emission concentrations, and fractional efficiencies from this cyclone operating at different cyclone inlet velocities...

  13. Method of low pressure and/or evaporative drying of aerogel

    SciTech Connect (OSTI)

    Mayer, Steven T.; Kaschmitter, James L.; Pekala, Richard W.

    1995-01-01

    A process whereby Resorcinol/Formaldehyde (RF) aerogel having a density of about 0.4-1.2 g/cc can be manufactured using a simple air drying procedure. This process is inherently simpler, quicker, and less expensive than the more conventional supercritical or subcritical CO.sub.2 extraction procedures. RF aerogels can be used as produced, such as in insulation applications, or pyrolyzed to form carbon aerogels with a density of about 0.9 g/cc for use in applications such as batteries, supercapacitors, etc.

  14. Method of low pressure and/or evaporative drying of aerogel

    SciTech Connect (OSTI)

    Mayer, S.T.; Kaschmitter, J.L.; Pekala, R.W.

    1995-05-30

    A process is described whereby Resorcinol/Formaldehyde (RF) aerogel having a density of about 0.4--1.2 g/cc can be manufactured using a simple air drying procedure. This process is inherently simpler, quicker, and less expensive than the more conventional supercritical or subcritical CO{sub 2} extraction procedures. RF aerogels can be used as produced, such as in insulation applications, or pyrolyzed to form carbon aerogels with a density of about 0.9 g/cc for use in applications such as batteries, supercapacitors, etc.

  15. Use Vapor Recompression to Recover Low-Pressure Waste Steam | Department of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefield Municipal Gas &SCE-Sessions | Department ofVP ofof EnergyFact Sheet UraniumEfficiencyEnergy

  16. Flash High-Pressure Condensate to Regenerate Low-Pressure Steam |

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i nA Guide to Tapping into Funding forFY'17 Projects for theDepartment of

  17. Low-Pressure Solubility of Gases in Liquid Water | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource HistoryScenarios Towards 2050 Jump to: navigation, search Tool

  18. Thermal analysis for fuel handling system for sodium cooled reactor considering minor actinide-bearing metal fuel.

    SciTech Connect (OSTI)

    Chikazawa, Y.; Grandy, C.; Nuclear Engineering Division

    2009-03-01

    The Advanced Burner Reactor (ABR) is one of the components of the Global Nuclear Energy Partnership (GNEP) used to close the fuel cycle. ABR is a sodium-cooled fast reactor that is used to consume transuranic elements resulting from the reprocessing of light water reactor spent nuclear fuel. ABR-1000 [1000 MW(thermal)] is a fast reactor concept created at Argonne National Laboratory to be used as a reference concept for various future trade-offs. ABR-1000 meets the GNEP goals although it uses what is considered base sodium fast reactor technology for its systems and components. One of the considerations of any fast reactor plant concept is the ability to perform fuel-handling operations with new and spent fast reactor fuel. The transmutation fuel proposed as the ABR fuel has a very little experience base, and thus, this paper investigates a fuel-handling concept and potential issues of handling fast reactor fuel containing minor actinides. In this study, two thermal analyses supporting a conceptual design study on the ABR-1000 fuel-handling system were carried out. One analysis investigated passive dry spent fuel storage, and the other analysis investigated a fresh fuel shipping cask. Passive dry storage can be made suitable for the ABR-1000 spent fuel storage with sodium-bonded metal fuel. The thermal analysis shows that spent fast reactor fuel with a decay heat of 2 kW or less can be stored passively in a helium atmosphere. The 2-kW value seems to be a reasonable and practical level, and a combination of reasonably-sized in-sodium storage followed by passive dry storage could be a candidate for spent fuel storage for the next-generation sodium-cooled reactor with sodium-bonded metal fuel. Requirements for the shipping casks for minor actinide-bearing fuel with a high decay heat level are also discussed in this paper. The shipping cask for fresh sodium-cooled-reactor fuel should be a dry type to reduce the reaction between residual moisture on fresh fuel and the sodium coolant. The cladding temperature requirement is maintained below the creep temperature limit to avoid any damage before core installation. The thermal analysis shows that a helium gas-filled cask can accommodate ABR-1000 fresh minor actinide-bearing fuel with 700-W decay heat. The above analysis results revealed the overall requirement for minor actinide-bearing metal fuel handling. The information is thought to be helpful in the design of the ABR-1000 and future sodium-cooled-reactor fuel-handling system.

  19. Effect of Sodium on the Catalytic Properties of VOx/CeO2 Catalysts for Oxidative Dehydrogenation of Methanol

    SciTech Connect (OSTI)

    Li, Yan; Wei, Zhehao; Sun, Junming; Gao, Feng; Peden, Charles HF; Wang, Yong

    2013-03-21

    A series of VOx/CeO2 catalysts with various sodium loadings (Na/V ratio from 0 to 1) has been studied for oxidative dehydrogenation (ODH) of methanol. The effect of sodium on the surface structure, redox properties, and surface acidity/basicity of VOx/CeO2 was investigated using hydrogen temperature-programmed reduction (H2-TPR), Raman spectroscopy, and Diffuse Reflectance Infrared Fourier Transform spectroscopy (DRIFT). The experimental results indicate that the effect of sodium on VOx/CeO2 is highly dependent on the Na/V ratio. At a low Na/V ratio (Na/V<0.25), sodium addition only slightly decreases the redox properties of VOx/CeO2 and has little effect on its activity and selectivity to formaldehyde, even though the Brönsted acidity is almost completely eliminated at a Na/V ratio of 0.25. At a high Na/V ratio (Na/V>0.25), sodium addition greatly alters the nature of the active sites by V-O-Ce bond cleavage and V-O-Na bond formation, leading to significantly reduced activity of the VOx/CeO2 catalysts. At Na/V>0.25, the selectivity to formaldehyde also decreases with increasing Na/V ratio due to: (1) the suppressed reducibility of VOx, and (2) increased basicity leading to increased CO2.

  20. A novel high capacity positive electrode material with tunnel-type structure for aqueous sodium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Yuesheng; Mu, Linqin; Liu, Jue; Yang, Zhenzhong; Yu, Xiqian; Gu, Lin; Hu, Yong -Sheng; Li, Hong; Yang, Xiao -Qing; Chen, Liquan; et al

    2015-08-06

    In this study, aqueous sodium-ion batteries have shown desired properties of high safety characteristics and low-cost for large-scale energy storage applications such as smart grid, because of the abundant sodium resources as well as the inherently safer aqueous electrolytes. Among various Na insertion electrode materials, tunnel-type Na0.44MnO2 has been widely investigated as a positive electrode for aqueous sodium-ion batteries. However, the low achievable capacity hinders its practical applications. Here we report a novel sodium rich tunnel-type positive material with a nominal composition of Na0.66[Mn0.66Ti0.34]O2. The tunnel-type structure of Na0.44MnO2 obtained for this compound was confirmed by XRD and atomic-scale STEM/EELS.more »When cycled as positive electrode in full cells using NaTi2(PO4)3/C as negative electrode in 1M Na2SO4 aqueous electrolyte, this material shows the highest capacity of 76 mAh g-1 among the Na insertion oxides with an average operating voltage of 1.2 V at a current rate of 2C. These results demonstrate that Na0.66[Mn0.66Ti0.34]O2 is a promising positive electrode material for rechargeable aqueous sodium-ion batteries.« less

  1. Experimental Development and Demonstration of Ultrasonic Measurement Diagnostics for Sodium Fast Reactor Thermal-hydraulics

    SciTech Connect (OSTI)

    Tokuhiro, Akira; Jones, Byron

    2013-09-13

    This research project will address some of the principal technology issues related to sodium-cooled fast reactors (SFR), primarily the development and demonstration of ultrasonic measurement diagnostics linked to effective thermal convective sensing under normatl and off-normal conditions. Sodium is well-suited as a heat transfer medium for the SFR. However, because it is chemically reactive and optically opaque, it presents engineering accessibility constraints relative to operations and maintenance (O&M) and in-service inspection (ISI) technologies that are currently used for light water reactors. Thus, there are limited sensing options for conducting thermohydraulic measurements under normal conditions and off-normal events (maintenance, unanticipated events). Acoustic methods, primarily ultrasonics, are a key measurement technology with applications in non-destructive testing, component imaging, thermometry, and velocimetry. THis project would have yielded a better quantitative and qualitative understanding of the thermohydraulic condition of solium under varied flow conditions. THe scope of work will evaluate and demonstrate ultrasonic technologies and define instrumentation options for the SFR.

  2. Neutronic Assessment of Transmutation Target Compositions in Heterogeneous Sodium Fast Reactor Geometries

    SciTech Connect (OSTI)

    Samuel E. Bays; Rodolfo M. Ferrer; Michael A. Pope; Benoit Forget; Mehdi Asgari

    2008-02-01

    The sodium fast reactor is under consideration for consuming the transuranic waste in the spent nuclear fuel generated by light water reactors. This work is concerned with specialized target assemblies for an oxide-fueled sodium fast reactor that are designed exclusively for burning the americium and higher mass actinide component of light water reactor spent nuclear fuel (SNF). The associated gamma and neutron radioactivity, as well as thermal heat, associated with decay of these actinides may significantly complicate fuel handling and fabrication of recycled fast reactor fuel. The objective of using targets is to isolate in a smaller number of assemblies these concentrations of higher actinides, thus reducing the volume of fuel having more rigorous handling requirements or a more complicated fabrication process. This is in contrast to homogeneous recycle where all recycled actinides are distributed among all fuel assemblies. Several heterogeneous core geometries were evaluated to determine the fewest target assemblies required to burn these actinides without violating a set of established fuel performance criteria. The DIF3D/REBUS code from Argonne National Laboratory was used to perform the core physics and accompanying fuel cycle calculations in support of this work. Using the REBUS code, each core design was evaluated at the equilibrium cycle condition.

  3. Testing of inductively coupled Eddy current position sensor of diverse safety rod in sodium

    SciTech Connect (OSTI)

    Vijayashree, R.; Veeraswamy, R.; Nashine, B. K.; Dash, S. K.; Sharma, P.; Rajan, K. K.; Vijayakumar, G.; Rao, C. B.; Sosamma, S.; Kalyanasundaram, P. [Indira Gandhi Centre for Atomic Research, Dept. of Atomic Energy, Kalpakkam - 603 102 (India)

    2011-07-01

    Prototype Fast Breeder Reactor (PFBR) is 500 MWe sodium cooled reactor under construction at Kalpakkam (India)). To improve the reliability of shutdown, Diverse Safety Rods (DSRs) are used in-addition to normal Control and Safety rods. During reactor operating condition, the DSR is parked above the active core and held in its top position by an electromagnet. In the event of a scram signal from the safety logic, the electromagnet holding the DSR is de-energised. Hence the DSR is released into the active core and at the end of travel DSR gets deposited in its bottom position. Because of the mechanical constraints, hard wired connectivity is not permitted from the DSR subassembly to the instrumentation outside the reactor. Hence an inductively coupled Eddy Current Position Sensor (ECPS) has been conceptualized to detect that the DSR has reached its bottom most position and to measure the drop time. Results of feasibility study on laboratory model have been reported earlier. Testing of a 1:1 scale engineering model of ECPS is reported in this paper. Results obtained from the high temperature sodium testing of ECPS indicate a clearly measurable change in pick up voltage with sensitivity of 11 % at 675 Hz. The ECPS is in advanced stage of implementation in DSRDM of PFBR. (authors)

  4. Pseudo-hydroxide extraction in the separation of sodium hydroxide from aqueous solutions using alkyl phenols

    SciTech Connect (OSTI)

    Kang, Hyun Ah; Moyer, Bruce A

    2006-01-01

    Pseudo-hydroxide extraction of sodium hydroxide from aqueous solution using four alkyl phenols of nearly identical molecular weight in 1-octanol at 25 degrees C was examined to understand the effect of alkyl substituents. The order of extraction strength among the four alkyl phenols tested was 4-tert-octylphenol. 3,5-di-tertbutylphenol. 2,4-di-tert-butylphenol. 2,6-di-tert-butyl-4-methylphenol. A good correlation with phenol pK(a) was observed, indicating that extraction strength is determined by phenol acidity, as modified by steric effects in proximity to the phenol - OH group. The effective partition ratios (P-eff) of two phenols from 1 M NaOH solution were determined, showing that the phenols remain predominantly in the 1-octanol phase even when converted to their sodium salts. However, the hydrophobicity of the tested phenols may not be sufficient for process purposes. The equilibrium constants for the governing extraction equilibria were determined by modeling the data using the program SXLSQI, supporting the cation-exchange extraction mechanism. The proposed mechanism consists of two simple sets of equilibria for a. Ion-pair extraction to give Na+OH- ion pairs and corresponding free ions in 1-octanol the phase and b. Cation exchange by monomeric phenol molecules (HAs) to form monomeric organic-phase Na(+)A(-) ion pairs and corresponding free organic-phase ions.

  5. Beyond the detergent effect: a binding site for sodium dodecyl sulfate (SDS) in mammalian apoferritin

    SciTech Connect (OSTI)

    Liu, Renyu Bu, Weiming; Xi, Jin; Mortazavi, Shirin R.; Cheung-Lau, Jasmina C.; Dmochowski, Ivan J.; Loll, Patrick J.

    2012-05-01

    Using X-ray crystallography and isothermal titration calorimetry, we show that sodium dodecyl sulfate (SDS) binds specifically to a pre-formed internal cavity in horse-spleen apoferritin. Although sodium dodecyl sulfate (SDS) is widely used as an anionic detergent, it can also exert specific pharmacological effects that are independent of the surfactant properties of the molecule. However, structural details of how proteins recognize SDS are scarce. Here, it is demonstrated that SDS binds specifically to a naturally occurring four-helix bundle protein: horse apoferritin. The X-ray crystal structure of the apoferritin–SDS complex was determined at a resolution of 1.9 Å and revealed that the SDS binds in an internal cavity that has previously been shown to recognize various general anesthetics. A dissociation constant of 24 ± 9 µM at 293 K was determined by isothermal titration calorimetry. SDS binds in this cavity by bending its alkyl tail into a horseshoe shape; the charged SDS head group lies in the opening of the cavity at the protein surface. This crystal structure provides insights into the protein–SDS interactions that give rise to binding and may prove useful in the design of novel SDS-like ligands for some proteins.

  6. Synthesis and radiosensitization properties of hydrogen peroxide and sodium hyaluronate complex

    SciTech Connect (OSTI)

    Rosli, Nur Ratasha Alia Md.; Mohamed, Faizal; Heng, Cheong Kai; Rahman, Irman Abdul; Ahmad, Ainee Fatimah; Mohamad, Hur Munawar Kabir

    2014-09-03

    Cancer cells which are large in size are resistant towards radiation therapy due to the presence of large amount of anti-oxidative enzymes and hypoxic cancer cells. Thus radiosensitizer agents have been developed to enhance the therapeutic effect of radiotherapy by increasing the sensitivity of these cancer cells towards radiation. This study is conducted to investigate the radiosensitization properties of radiosensitizer complex containing hydrogen peroxide and sodium hyaluronate. Combination with sodium hyaluronate may decrease reactivity of hydrogen peroxide but maintain the oxygen concentration needed for radiosensitizing effect. HepG2 cancer cells are cultured as the mean of test subject. Cancer cell samples which are targeted and not targeted with these radiosensitizers are irradiated with 2Gy single fractionated dose. Results obtained shows that the cancer cells which are not targeted with radiosensitizers has a cell viability of 98.80±0.37% after a time interval of 48 hours and has even repopulated over 100% after a 72 hour time interval. This shows that the cancer cells are resistant towards radiation. However, when the cancer cells are targeted with radiosensitizers prior to irradiation, there is a reduction of cell viability by 25.50±10.81% and 10.30±5.10% at time intervals of 48 and 72 hours respectively. This indicates that through the use of these radiosensitizers, cancer cells are more sensitive towards radiation.

  7. Selecting the suitable dopants: electronic structures of transition metal and rare earth doped thermoelectric sodium cobaltate

    E-Print Network [OSTI]

    Assadi, M H N; Yu, A B

    2012-01-01

    Engineered Na0.75CoO2 is considered a prime candidate to achieve high efficiency thermoelectric systems to regenerate electricity from waste heat. In this work, three elements with outmost electronic configurations, (1) an open d shell (Ni), (2) a closed d shell (Zn), and (3) an half fill f shell (Eu) with a maximum unpaired electrons, were selected to outline the dopants' effects on electronic and crystallographic structures of Na0.75CoO2. Systematic ab initio density functional calculations showed that the formation energy of these dopants was found to be lowest when residing on sodium layer and ranked as -1.1 eV, 0.44 eV and 3.44 eV for Eu, Ni and Zn respectively. Furthermore Ni was also found to be stable when substituting Co ion. As these results show great harmony with existing experimental data, they provide new insights into the fundamental principle of dopant selection for manipulating the physical properties in the development of high performance sodium cobaltate based thermoelectric materials.

  8. Final report-passive safety optimization in liquid sodium-cooled reactors.

    SciTech Connect (OSTI)

    Cahalana, J. E.; Hahn, D.; Nuclear Engineering Division; Korea Atomic Energy Research Inst.

    2007-08-13

    This report summarizes the results of a three-year collaboration between Argonne National Laboratory (ANL) and the Korea Atomic Energy Research Institute (KAERI) to identify and quantify the performance of innovative design features in metallic-fueled, sodium-cooled fast reactor designs. The objective of the work was to establish the reliability and safety margin enhancements provided by design innovations offering significant potential for construction, maintenance, and operating cost reductions. The project goal was accomplished with a combination of advanced model development (Task 1), analysis of innovative design and safety features (Tasks 2 and 3), and planning of key safety experiments (Task 4). Task 1--Computational Methods for Analysis of Passive Safety Design Features: An advanced three-dimensional subassembly thermal-hydraulic model was developed jointly and implemented in ANL and KAERI computer codes. The objective of the model development effort was to provide a high-accuracy capability to predict fuel, cladding, coolant, and structural temperatures in reactor fuel subassemblies, and thereby reduce the uncertainties associated with lower fidelity models previously used for safety and design analysis. The project included model formulation, implementation, and verification by application to available reactor tests performed at EBR-II. Task 2--Comparative Analysis and Evaluation of Innovative Design Features: Integrated safety assessments of innovative liquid metal reactor designs were performed to quantify the performance of inherent safety features. The objective of the analysis effort was to identify the potential safety margin enhancements possible in a sodium-cooled, metal-fueled reactor design by use of passive safety mechanisms to mitigate low-probability accident consequences. The project included baseline analyses using state-of-the-art computational models and advanced analyses using the new model developed in Task 1. Task 3--Safety Implications of Advanced Technology Power Conversion and Design Innovations and Simplifications: Investigations of supercritical CO{sub 2} gas turbine Brayton cycles coupled to the sodium-cooled reactors and innovative concepts for sodium-to-CO{sub 2} heat exchangers were performed to discover new designs for high efficiency electricity production. The objective of the analyses was to characterize the design and safety performance of equipment needed to implement the new power cycle. The project included considerations of heat transfer and power conversion systems arrangements and evaluations of systems performance. Task 4--Post Accident Heat Removal and In-Vessel Retention: Test plans were developed to evaluate (1) freezing and plugging of molten metallic fuel in subassembly geometry, (2) retention of metallic fuel core melt debris within reactor vessel structures, and (3) consequences of intermixing of high pressure CO{sub 2} and sodium. The objective of the test plan development was to provide planning for measurements of data needed to characterize the consequences of very low probability accident sequences unique to metallic fuel and CO{sub 2} Brayton power cycles. The project produced three test plans ready for execution.

  9. Physical and chemical characteristics of fluorinel/sodium calcine generated during 30 cm Pilot-Plant Run 17

    SciTech Connect (OSTI)

    Brewer, K.N.; Kessinger, G.F.; Littleton, L.L.; Olson, A.L.

    1993-07-01

    The 30 centimeter (cm) pilot plant calciner Run 17, of March 9, 1987, was performed to study the calcination of fluroinel-sodium blended waste blended at the ratio 3.5:1 fluorinel to sodium, respectively. The product of the run was analyzed by a variety of analytical techniques that included X-ray powder diffraction (XRD), inductively coupled plasma spectroscopy (ICP), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) to deduce physical and chemical characteristics. The analytical data, as well as data analyses and conclusions drawn from the data, are presented.

  10. EFFECTS OF SODIUM AND CALCIUM IN LIGNITE ON THE PERFORMANCE OF ACTIVATED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Edwin S. Olson; Kurt E. Eylands; Daniel J. Stepan

    2001-12-01

    New federal drinking water regulations have been promulgated to restrict the levels of disinfection by-products (DBPs) in finished public water supplies. DBPs are suspected carcinogens and are formed when organic material is partially oxidized by disinfectants commonly used in the water treatment industry. Additional federal mandates are expected in the near future that will also affect public water suppliers with respect to DBPs. These new federal drinking water regulations may require public water suppliers to adjust treatment practices or incorporate additional treatment operations into their existing treatment trains. Many options have been identified, including membrane processes, granular activated carbon, powered activated carbon (PAC), enhanced coagulation and/or softening, and alternative disinfectants (e.g., chlorine dioxide, ozone, and chloramines). Of the processes being considered, PAC appears to offer an attractive benefit-to-cost advantage for many water treatment plants, particularly small systems (those serving fewer than 10,000 customers). PAC has traditionally been used by the water treatment industry for the removal of compounds contributing to taste and odor problems. PAC also has the potential to remove naturally occurring organic matter (NOM) from raw waters prior to disinfection, thus controlling the formation of regulated DBPs. Many small water systems are currently using PAC for taste and odor control and have the potential to use PAC for controlling DBPs. Activated carbons can be produced from a variety of raw materials, including wood, peat, coconut husks, and numerous types of coal. The Energy & Environmental Research Center (EERC) has been working on the development of a PAC product to remove NOM from surface water supplies to prevent the formation of carcinogenic DBPs during chlorination. During that study, the sodium and calcium content of the lignites showed a significant effect on the sorption capacity of the activated carbon product. As much as a 130% increase in the humic acid sorption capacity of a PAC produced from a high-sodium-content lignite was observed. We hypothesize that the sodium and calcium content of the coal plays a significant role in the development of pore structures and pore-size distribution, ultimately producing activated carbon products that have greater sorption capacity for specific contaminants, depending on molecular size.

  11. Calcium-Mediated Regulation of Proton-Coupled Sodium Transport - Final Report

    SciTech Connect (OSTI)

    Schumaker, Karen S

    2013-10-24

    The long-term goal of our experiments was to understand mechanisms that regulate energy coupling by ion currents in plants. Activities of living organisms require chemical, mechanical, osmotic or electrical work, the energy for which is supplied by metabolism. Adenosine triphosphate (ATP) has long been recognized as the universal energy currency, with metabolism supporting the synthesis of ATP and the hydrolysis of ATP being used for the subsequent work. However, ATP is not the only energy currency in living organisms. A second and very different energy currency links metabolism to work by the movement of ions passing from one side of a membrane to the other. These ion currents play a major role in energy capture and they support a range of physiological processes from the active transport of nutrients to the spatial control of growth and development. In Arabidopsis thaliana (Arabidopsis), the activity of a plasma membrane Na+/H+ exchanger, SALT OVERLY SENSITIVE1 (SOS1), is essential for regulation of sodium ion homeostasis during plant growth in saline conditions. Mutations in SOS1 result in severely reduced seedling growth in the presence of salt compared to the growth of wild type. SOS1 is a secondary active transporter coupling movement of sodium ions out of the cell using energy stored in the transplasma membrane proton gradient, thereby preventing the build-up of toxic levels of sodium in the cytosol. SOS1 is regulated by complexes containing the SOS2 and CALCINEURIN B-LIKE10 (CBL10) or SOS3 proteins. CBL10 and SOS3 (also identified as CBL4) encode EF-hand calcium sensors that interact physically with and activate SOS2, a serine/threonine protein kinase. The CBL10/SOS2 or SOS3/SOS2 complexes then activate SOS1 Na+/H+ exchange activity. We completed our studies to understand how SOS1 activity is regulated. Specifically, we asked: (1) how does CBL10 regulate SOS1 activity? (2) What role do two putative CBL10-interacting proteins play in SOS1 regulation? (3) Are there differences in the regulation and/or activity of SOS1 in plants differing in their adaptation to salinity?

  12. Sodium laser guide star system at Lawrence Livermore National Laboratory: System description and experimental results

    SciTech Connect (OSTI)

    Avicola, K.; Brase, J.; Morris, J.

    1994-03-02

    The architecture and major system components of the sodium-layer kw guide star system at LLNL will be described, and experimental results reported. The subsystems include the laser system, the beam delivery system including a pulse stretcher and beam pointing control, the beam director, and the telescope with its adaptive-optics package. The laser system is one developed for the Atomic Vapor Laser Isotope Separation (AVLIS) Program. This laser system can be configured in various ways in support of the AVLIS program objectives, and was made available to the guide star program at intermittent times on a non-interference basis. The first light transmitted into the sky was in July of 1992, at a power level of 1. 1 kW. The laser pulse width is about 32 ns, and the pulse repetition rate was 26 kHz for the 1. 1 kW configuration and 13 kHz for a 400 W configuration. The laser linewidth is tailored to match the sodium D{sub 2} absorption line, and the laser system has active control of beam pointing and wavefront quality. Because of the short pulse length the sodium transition is saturated and the laser power is not efficiently utilized. For this reason a pulse stretcher was developed, and the results of this effort will be reported. The beam is delivered via an evacuated pipe from the laser building to the guide star site, a distance of about 100 meters, and then launched vertically. A beam director provides the means to track the sky in the full AO system, but was not used in the experiments reported here. The return signal is collected by a 1/2 meter telescope with the AO package. This telescope is located 5 meters from the km launch tube. Smaller packages for photometry, wavefront measurement, and spot image and motion analysis have been used. Although the unavailability of the AVLIS laser precluded a full AO system demonstration, data supporting feasibility and providing input to the system design for a Lick Observatory AO system was obtained.

  13. Sodium pumps adapt spike bursting to stimulus Sara Arganda1,2,4, Raul Guantes1,3,4 & Gonzalo G de Polavieja1,2

    E-Print Network [OSTI]

    Guantes, Raúl

    Sodium pumps adapt spike bursting to stimulus statistics Sara Arganda1,2,4, Rau´l Guantes1,3,4 & Gonzalo G de Polavieja1,2 Pump activity is a homeostatic mechanism that maintains ionic gradients. Here we examined whether the slow reduction in excitability induced by sodium-pump activity that has been seen

  14. The effect of potassium lactate and sodium diacetate on the microbial, sensory, color and chemical characteristics of vacuum-packaged beef top loin steaks 

    E-Print Network [OSTI]

    Anwar, Najia

    2000-01-01

    Beef strip loins were injected with potassium lactate (1.5, 2.0, and 2.5%), sodium diacetate (0.1%), and combination of sodium diacetate (0.1%) with 1.5 or 2.0% potassium lactate. Top loin steaks were vacuum-packaged and stored for up to 49 days...

  15. Selective Catalytic Oxidation of Hydrogen Sulfide on Activated Carbons Impregnated with Sodium Hydroxide

    SciTech Connect (OSTI)

    Schwartz, Viviane [ORNL; Baskova, Svetlana [ORNL; Armstrong, Timothy R. [ORNL

    2009-01-01

    Two activated carbons of different origin were impregnated with the solution of sodium hydroxide (NaOH) of various concentrations up to 10 wt %, and the effect of impregnation on the catalytic performance of the carbons was evaluated. The catalytic activity was analyzed in terms of the capacity of carbons for hydrogen sulfide (H2S) conversion and removal from hydrogen-rich fuel streams and the emission times of H2S and the products of its oxidation [e.g., sulfur dioxide (SO2) and carbonyl sulfide (COS)]. The results of impregnation showed a significant improvement in the catalytic activity of both carbons proportional to the amount of NaOH introduced. NaOH introduces hydroxyl groups (OH-) on the surface of the activated carbon that increase its surface reactivity and its interaction with sulfur-containing compounds.

  16. Process Options Description for Vitrification Flowsheet Model of INEEL Sodium Bearing Waste

    SciTech Connect (OSTI)

    Nichols, Todd Travis; Taylor, Dean Dalton; Lauerhass, Lance; Barnes, Charles Marshall

    2001-02-01

    The purpose of this document is to provide the technical information to Savannah River Site (SRS) personnel that is required for the development of a basic steady-state process simulation of the vitrification treatment train of sodium bearing waste (SBW) at Idaho National Engineering and nvironmental Laboratory (INEEL). INEEL considers simulation to have an important role in the integration/optimization of treatment process trains for the High Level Waste (HLW) Program. This project involves a joint Technical Task Plan (TTP ID77WT31, Subtask C) between SRS and INEEL. The work scope of simulation is different at the two sites. This document addresses only the treatment of SBW at INEEL. The simulation model(s) is to be built by SRS for INEEL in FY-2001.

  17. Modeling of NOx Destruction Options for INEEL Sodium-Bearing Waste Vitrification

    SciTech Connect (OSTI)

    Wood, Richard Arthur

    2001-09-01

    Off-gas NOx concentrations in the range of 1-5 mol% are expected as a result of the proposed vitrification of sodium-bearing waste at the Idaho National Engineering and Environmental Laboratory. An existing kinetic model for staged combustion (originally developed for NOx abatement from the calcination process) was updated for application to vitrification offgas. In addition, two new kinetic models were developed to assess the feasibility of using selective non-catalytic reduction (SNCR) or high-temperature alone for NOx abatement. Each of the models was developed using the Chemkin code. Results indicate that SNCR is a viable option, reducing NOx levels to below 1000 ppmv. In addition, SNCR may be capable of simultaneously reducing CO emissions to below 100 ppmv. Results for using high-temperature alone were not as promising, indicating that a minimum NOx concentration of 3950 ppmv is achievable at 3344°F.

  18. Minor Actinide Recycle in Sodium Cooled Fast Reactors Using Heterogeneous Targets

    SciTech Connect (OSTI)

    Samuel Bays; Pavel Medvedev; Michael Pope; Rodolfo Ferrer; Benoit Forget; Mehdi Asgari

    2009-04-01

    This paper investigates the plausible design of transmutation target assemblies for minor actinides (MA) in Sodium Fast Reactors (SFR). A heterogeneous recycling strategy is investigated, whereby after each reactor pass, un-burned MAs from the targets are blended with MAs produced by the driver fuel and additional MAs from Spent Nuclear Fuel (SNF). A design iteration methodology was adopted for customizing the core design, target assembly design and matrix composition design. The overall design was constrained against allowable peak or maximum in-core performances. While respecting these criteria, the overall design was adjusted to reduce the total number of assemblies fabricated per refueling cycle. It was found that an inert metal-hydride MA-Zr-Hx target matrix gave the highest transmutation efficiency, thus allowing for the least number of targets to be fabricated per reactor cycle.

  19. FLOWSHEET EVALUATION FOR THE DISSOLVING AND NEUTRALIZATION OF SODIUM REACTOR EXPERIMENT USED NUCLEAR FUEL

    SciTech Connect (OSTI)

    Daniel, W. E.; Hansen, E. K.; Shehee, T. C.

    2012-10-30

    This report includes the literature review, hydrogen off-gas calculations, and hydrogen generation tests to determine that H-Canyon can safely dissolve the Sodium Reactor Experiment (SRE; thorium fuel), Ford Nuclear Reactor (FNR; aluminum alloy fuel), and Denmark Reactor (DR-3; silicide fuel, aluminum alloy fuel, and aluminum oxide fuel) assemblies in the L-Bundles with respect to the hydrogen levels in the projected peak off-gas rates. This is provided that the number of L-Bundles charged to the dissolver is controlled. Examination of SRE dissolution for potential issues has aided in predicting the optimal batching scenario. The calculations detailed in this report demonstrate that the FNR, SRE, and DR-3 used nuclear fuel (UNF) are bounded by MURR UNF and may be charged using the controls outlined for MURR dissolution in a prior report.

  20. Effect of sodium monofluorophosphate treatment on microstructure and frost salt scaling durability of slag cement paste

    SciTech Connect (OSTI)

    Copuroglu, O. . E-mail: o.copuroglu@citg.tudelft.nl; Fraaij, A.L.A.; Bijen, J.M.J.M.

    2006-08-15

    Sodium-monofluorophosphate (Na-MFP) is currently in use as a surface applied corrosion inhibitor in the concrete industry. Its basic mechanism is to protect the passive layer of the reinforcement steel against disruption due to carbonation. Carbonation is known as the most detrimental environmental effect on blast furnace slag cement (BFSC) concrete with respect to frost salt scaling. In this paper the effect of Na-MFP on the microstructure and frost salt scaling resistance of carbonated BFSC paste is presented. The results of electron microscopy, mercury intrusion porosimetry (MIP) and X-ray diffraction (XRD) are discussed. It is found that the treatment modifies the microstructure and improves the resistance of carbonated BFSC paste against frost salt attack.