National Library of Energy BETA

Sample records for low-e glass layers

  1. Engineering Glass Passivation Layers -Model Results

    SciTech Connect (OSTI)

    Skorski, Daniel C.; Ryan, Joseph V.; Strachan, Denis M.; Lepry, William C.

    2011-08-08

    The immobilization of radioactive waste into glass waste forms is a baseline process of nuclear waste management not only in the United States, but worldwide. The rate of radionuclide release from these glasses is a critical measure of the quality of the waste form. Over long-term tests and using extrapolations of ancient analogues, it has been shown that well designed glasses exhibit a dissolution rate that quickly decreases to a slow residual rate for the lifetime of the glass. The mechanistic cause of this decreased corrosion rate is a subject of debate, with one of the major theories suggesting that the decrease is caused by the formation of corrosion products in such a manner as to present a diffusion barrier on the surface of the glass. Although there is much evidence of this type of mechanism, there has been no attempt to engineer the effect to maximize the passivating qualities of the corrosion products. This study represents the first attempt to engineer the creation of passivating phases on the surface of glasses. Our approach utilizes interactions between the dissolving glass and elements from the disposal environment to create impermeable capping layers. By drawing from other corrosion studies in areas where passivation layers have been successfully engineered to protect the bulk material, we present here a report on mineral phases that are likely have a morphological tendency to encrust the surface of the glass. Our modeling has focused on using the AFCI glass system in a carbonate, sulfate, and phosphate rich environment. We evaluate the minerals predicted to form to determine the likelihood of the formation of a protective layer on the surface of the glass. We have also modeled individual ions in solutions vs. pH and the addition of aluminum and silicon. These results allow us to understand the pH and ion concentration dependence of mineral formation. We have determined that iron minerals are likely to form a complete incrustation layer and we plan

  2. Multi-pane glass unit having seal with adhesive and hermetic coating layer

    DOE Patents [OSTI]

    Miller, Seth A; Stark, David H; Francis, IV, William H; Puligandla, Viswanadham; Boulos, Edward N; Pernicka, John

    2015-02-10

    A vacuum insulated glass unit (VIGU) comprises a first pane of a transparent material and a second pane of a transparent material. The second pane is spaced apart from the first pane to define a cavity therebetween. At least one of a spacer and an array of stand-off members is disposed between the first and second panes to maintain separation therebetween. A first adhesive layer forms at least a portion of a gas-tight connection between the first pane and the second pane. A highly hermetic coating is disposed over the adhesive layer, where the coating is an inorganic layer.

  3. Low-cost, highly transparent flexible low-e coating film to enable electrochromic windows with increased energy savings

    SciTech Connect (OSTI)

    Berland, Brian; Hollingsworth, Russell

    2015-03-31

    Five Quads of energy are lost through windows annually in the U.S. Low-e coatings are increasingly employed to reduce the wasted energy. Most commonly, the low-e coating is an oxide material applied directly to the glass at high temperature. With over 100,000,000 existing homes, a retrofit product is crucial to achieve widespread energy savings. Low-e films, i.e. coatings on polymeric substrates, are now also available to meet this need. However, the traditional oxide materials and process is incompatible with low temperature plastics. Alternate high performing low-e films typically incorporate materials that limit visible transmission to 35% or less. Further, the cost is high. The objective of this award was to develop a retrofit, integrated low-e/electrochromic window film to dramatically reduce energy lost through windows. While field testing of state-of-the-art electrochromic (EC) windows show the energy savings are maximized if a low-e coating is used in conjunction with the EC, available low-e films have a low visible transmission (~70% or less) that limits the achievable clear state and therefore, appearance and energy savings potential. Comprehensive energy savings models were completed at Lawrence Berkeley National Lab (LBNL). A parametric approach was used to project energy usage for windows with a large range of low-e properties across all U.S. climate zones, without limiting the study to materials that had already been produced commercially or made in a lab. The model enables projection of energy savings for low-e films as well as integrated low-e/EC products. This project developed a novel low-e film, optimized for compatibility with EC windows, using low temperature, high deposition rate processes for the growth of low-e coatings on plastic films by microwave plasma enhanced chemical vapor deposition. Silica films with good density and optical properties were demonstrated at deposition rates as high as 130Å/sec. A simple bi-layer low-e stack of

  4. Glass

    Broader source: Energy.gov [DOE]

    Glass production requires considerable energy to sustain the very high temperatures needed to melt the glass batch. The U.S. glass industry has worked cooperatively with AMO to develop a range of resources for improving energy efficiency and reducing emissions.

  5. Low-E Retrofit Demonstration and Educational Program

    SciTech Connect (OSTI)

    Culp, Thomas D; Wiehagen, Joseph; Drumheller, S Craig; Siegel, John; Stratmoen, Todd

    2013-11-16

    The objective of this project was to demonstrate the capability of low-emissivity (low-E) storm windows / panels and low-E retrofit glazing systems to significantly and cost effectively improve the energy efficiency of both existing residential and commercial buildings. The key outcomes are listed below: RESIDENTIAL CASE STUDIES: (a) A residential case study in two large multifamily apartment buildings in Philadelphia showed a substantial 18-22% reduction in heating energy use and a 9% reduction in cooling energy use by replacing old clear glass storm windows with modern low-E storm windows. Furthermore, the new low-E storm windows reduced the overall apartment air leakage by an average of 10%. (b) Air leakage testing on interior low-E panels installed in a New York City multifamily building over windows with and without AC units showed that the effective leakage area of the windows was reduced by 77-95%. (c) To study the use of low-E storm windows in a warmer mixed climate with a balance of both heating and cooling, 10 older homes near Atlanta with single pane windows were tested with three types of exterior storm windows: clear glass, low-E glass with high solar heat gain, and low-E glass with lower solar heat gain. The storm windows significantly reduced the overall home air leakage by an average of 17%, or 3.7 ACH50. Considerably high variability in the data made it difficult to draw strong conclusions about the overall energy usage, but for heating periods, the low-E storm windows showed approximately 15% heating energy savings, whereas clear storm windows were neutral in performance. For cooling periods, the low-E storm windows showed a wide range of performance from 2% to over 30% cooling energy savings. Overall, the study showed the potential for significantly more energy savings from using low-E glass versus no storm window or clear glass storm windows in warmer mixed climates, but it is difficult to conclusively say whether one type of low-E performed

  6. Performance Validation of Low-e Storm Windows Paves Way for Market Acceptance

    Broader source: Energy.gov [DOE]

    One recent addition to the arsenal of cost-effective efficiency measures is low-emissivity (low-e) storm windows. A low-e coating or glazing is a thin layer deposited directly on the surface of one...

  7. Effect of Stainless Steel Can/Glass-Ceramic Interaction Layer on Aqueous Durability

    SciTech Connect (OSTI)

    McGlinn, Peter J.; Zhang, Yingjie; Li, Huijun; Payne, Timothy E.

    2007-07-01

    Calcined high-level radioactive waste (HLW) stored at the Idaho National Laboratory (INL) will eventually be immobilised in a suitable wasteform before disposal. A tailored glass-ceramic wasteform, produced by hot isostatic pressing (HIPing) in stainless steel (SS) cans, has been developed at the Australian Nuclear Science and Technology Organisation (ANSTO) as a cost-saving alternative to glass which would improve waste loading and density, and reduce waste volume. We have studied the SS/wasteform interactions under HIPing conditions to understand whether such interactions would have any detrimental effect on long-term wasteform stability. This has been demonstrated by carrying out aqueous durability tests, under near-neutral and alkaline conditions, on the wasteform at the interaction layer, and on the wasteform distal to this reaction edge. Reaction during HIPing resulted in verifiable Cr diffusion from the can wall into the wasteform, yet without any detectable detrimental impact on the HIP can or the aqueous durability of the wasteform. (authors)

  8. Evaluation of Low-E Storm Windows in the PNNL Lab Homes

    SciTech Connect (OSTI)

    Knox, Jake R.; Widder, Sarah H.

    2014-05-31

    This study examines the performance of exterior and interior low-e storm panels with a controlled whole home experimental design using PNNL's Lab Homes. Summing the estimated annual average heating and cooling savings, the installation of low-e storm panels resulted in approximately 10% annual energy savings. The results of the experiment will be used to determine and validate performance of low-e storm windows over double pane clear glass windows in a whole home setting.

  9. An enriched finite element model with q-refinement for radiative boundary layers in glass cooling

    SciTech Connect (OSTI)

    Mohamed, M. Shadi; Seaid, Mohammed; Trevelyan, Jon; Laghrouche, Omar

    2014-02-01

    Radiative cooling in glass manufacturing is simulated using the partition of unity finite element method. The governing equations consist of a semi-linear transient heat equation for the temperature field and a stationary simplified P{sub 1} approximation for the radiation in non-grey semitransparent media. To integrate the coupled equations in time we consider a linearly implicit scheme in the finite element framework. A class of hyperbolic enrichment functions is proposed to resolve boundary layers near the enclosure walls. Using an industrial electromagnetic spectrum, the proposed method shows an immense reduction in the number of degrees of freedom required to achieve a certain accuracy compared to the conventional h-version finite element method. Furthermore the method shows a stable behaviour in treating the boundary layers which is shown by studying the solution close to the domain boundaries. The time integration choice is essential to implement a q-refinement procedure introduced in the current study. The enrichment is refined with respect to the steepness of the solution gradient near the domain boundary in the first few time steps and is shown to lead to a further significant reduction on top of what is already achieved with the enrichment. The performance of the proposed method is analysed for glass annealing in two enclosures where the simplified P{sub 1} approximation solution with the partition of unity method, the conventional finite element method and the finite difference method are compared to each other and to the full radiative heat transfer as well as the canonical Rosseland model.

  10. EERE Success Story—Performance Validation of Low-e Storm Windows Paves Way for Market Acceptance

    Broader source: Energy.gov [DOE]

    One recent addition to the arsenal of cost-effective efficiency measures is low-emissivity (low-e) storm windows. A low-e coating or glazing is a thin layer deposited directly on the surface of one...

  11. Spin-glass-like freezing of inner and outer surface layers in hollow γ-Fe2O3 nanoparticles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khurshid, Hafsa; Lampen-Kelley, Paula; Iglesias, Òscar; Alonso, Javier; Phan, Manh-Huong; Sun, Cheng-Jun; Saboungi, Marie-Louise; Srikanth, Hariharan

    2015-10-27

    Disorder among surface spins largely dominates the magnetic response of ultrafine magnetic particle systems. In this work, we examine time-dependent magnetization in high-quality, monodisperse hollow maghemite nanoparticles (NPs) with a 14.8±0.5 nm outer diameter and enhanced surface-to-volume ratio. The nanoparticle ensemble exhibits spin-glass-like signatures in dc magnetic aging and memory protocols and ac magnetic susceptibility. The dynamics of the system slow near 50 K, and becomes frozen on experimental time scales below 20 K. Remanence curves indicate the development of magnetic irreversibility concurrent with the freezing of the spin dynamics. A strong exchange-bias effect and its training behavior point tomore » highly frustrated surface spins that rearrange much more slowly than interior spins with bulk coordination. Monte Carlo simulations of a hollow particle reproducing the experimental morphology corroborate strongly disordered surface layers with complex energy landscapes that underlie both glass-like dynamics and magnetic irreversibility. Calculated hysteresis loops reveal that magnetic behavior is not identical at the inner and outer surfaces, with spins at the outer surface layer of the 15 nm hollow particles exhibiting a higher degree of frustration. Lastly, our combined experimental and simulated results shed light on the origin of spin-glass-like phenomena and the important role played by the surface spins in magnetic hollow nanostructures.« less

  12. Chemical composition analysis and product consistency tests to support enhanced Hanford waste glass models. Results for the third set of high alumina outer layer matrix glasses

    SciTech Connect (OSTI)

    Fox, K. M.; Edwards, T. B.

    2015-12-01

    In this report, the Savannah River National Laboratory provides chemical analyses and Product Consistency Test (PCT) results for 14 simulated high level waste glasses fabricated by the Pacific Northwest National Laboratory. The results of these analyses will be used as part of efforts to revise or extend the validation regions of the current Hanford Waste Treatment and Immobilization Plant glass property models to cover a broader span of waste compositions. The measured chemical composition data are reported and compared with the targeted values for each component for each glass. All of the measured sums of oxides for the study glasses fell within the interval of 96.9 to 100.8 wt %, indicating recovery of all components. Comparisons of the targeted and measured chemical compositions showed that the measured values for the glasses met the targeted concentrations within 10% for those components present at more than 5 wt %. The PCT results were normalized to both the targeted and measured compositions of the study glasses. Several of the glasses exhibited increases in normalized concentrations (NCi) after the canister centerline cooled (CCC) heat treatment. Five of the glasses, after the CCC heat treatment, had NCB values that exceeded that of the Environmental Assessment (EA) benchmark glass. These results can be combined with additional characterization, including X-ray diffraction, to determine the cause of the higher release rates.

  13. Glass-silicon column

    DOE Patents [OSTI]

    Yu, Conrad M.

    2003-12-30

    A glass-silicon column that can operate in temperature variations between room temperature and about 450.degree. C. The glass-silicon column includes large area glass, such as a thin Corning 7740 boron-silicate glass bonded to a silicon wafer, with an electrode embedded in or mounted on glass of the column, and with a self alignment silicon post/glass hole structure. The glass/silicon components are bonded, for example be anodic bonding. In one embodiment, the column includes two outer layers of silicon each bonded to an inner layer of glass, with an electrode imbedded between the layers of glass, and with at least one self alignment hole and post arrangement. The electrode functions as a column heater, and one glass/silicon component is provided with a number of flow channels adjacent the bonded surfaces.

  14. Cr-doped TiSe2 - A layered dichalcogenide spin glass

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Luo, Huixia; Tao, Jing; Krizan, Jason W.; Seibel, Elizabeth M.; Xie, Weiwei; Sahasrabudhe, Girija S.; Bergman, Susanna L.; Phelan, Brendan F.; Wang, Zhen; Zhang, Jiandi; et al

    2015-09-17

    We report the magnetic characterization of the Cr-doped layered dichalcogenide TiSe2. The temperature dependent magnetic susceptibilities are typical of those seen in geometrically frustrated insulating antiferromagnets. The Cr moment is close to the spin-only value, and the Curie–Weiss temperatures (θcw) are between –90 and –230 K. Freezing of the spin system, which is glassy, characterized by peaks in the ac and dc susceptibility and specific heat, does not occur until below T/θcw = 0.05. The CDW transition seen in the resistivity for pure TiSe2 is still present for 3% Cr substitution but is absent by 10% substitution, above which themore » materials are metallic and p-type. Structural refinements, magnetic characterization, and chemical considerations indicate that the materials are of the type Ti1–xCrxSe2-x/2 for 0 ≤ x ≤ 0.6.« less

  15. Cr-doped TiSe2 - A layered dichalcogenide spin glass

    SciTech Connect (OSTI)

    Luo, Huixia; Tao, Jing; Krizan, Jason W.; Seibel, Elizabeth M.; Xie, Weiwei; Sahasrabudhe, Girija S.; Bergman, Susanna L.; Phelan, Brendan F.; Wang, Zhen; Zhang, Jiandi; Cava, R. J.

    2015-09-17

    We report the magnetic characterization of the Cr-doped layered dichalcogenide TiSe2. The temperature dependent magnetic susceptibilities are typical of those seen in geometrically frustrated insulating antiferromagnets. The Cr moment is close to the spin-only value, and the Curie–Weiss temperatures (θcw) are between –90 and –230 K. Freezing of the spin system, which is glassy, characterized by peaks in the ac and dc susceptibility and specific heat, does not occur until below T/θcw = 0.05. The CDW transition seen in the resistivity for pure TiSe2 is still present for 3% Cr substitution but is absent by 10% substitution, above which the materials are metallic and p-type. Structural refinements, magnetic characterization, and chemical considerations indicate that the materials are of the type Ti1–xCrxSe2-x/2 for 0 ≤ x ≤ 0.6.

  16. Plasmonic Three-Dimensional Transparent Conductor Based on Al-Doped Zinc Oxide-Coated Nanostructured Glass Using Atomic Layer Deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malek, Gary A.; Aytug, Tolga; Liu, Qingfeng; Wu, Judy

    2015-04-02

    Transparent nanostructured glass coatings, fabricated on glass substrates, with a unique three-dimensional (3D) architecture were utilized as the foundation for the design of plasmonic 3D transparent conductors. Transformation of the non-conducting 3D structure to a conducting 3D network was accomplished through atomic layer deposition of aluminum-doped zinc oxide (AZO). After AZO growth, gold nanoparticles (AuNPs) were deposited by electronbeam evaporation to enhance light trapping and decrease the overall sheet resistance. Field emission scanning electron microscopy and atomic force microcopy images revealed the highly porous, nanostructured morphology of the AZO coated glass surface along with the in-plane dimensions of the depositedmore » AuNPs. Sheet resistance measurements conducted on the coated samples verified that the electrical properties of the 3D network are comparable to that of the untextured two-dimensional AZO coated glass substrates. In addition, transmittance measurements of the glass samples coated with various AZO thicknesses showed preservation of the highly transparent nature of each sample, while the AuNPs demonstrated enhanced light scattering as well as light-trapping capability.« less

  17. Plasmonic Three-Dimensional Transparent Conductor Based on Al-Doped Zinc Oxide-Coated Nanostructured Glass Using Atomic Layer Deposition

    SciTech Connect (OSTI)

    Malek, Gary A.; Aytug, Tolga; Liu, Qingfeng; Wu, Judy

    2015-04-02

    Transparent nanostructured glass coatings, fabricated on glass substrates, with a unique three-dimensional (3D) architecture were utilized as the foundation for the design of plasmonic 3D transparent conductors. Transformation of the non-conducting 3D structure to a conducting 3D network was accomplished through atomic layer deposition of aluminum-doped zinc oxide (AZO). After AZO growth, gold nanoparticles (AuNPs) were deposited by electronbeam evaporation to enhance light trapping and decrease the overall sheet resistance. Field emission scanning electron microscopy and atomic force microcopy images revealed the highly porous, nanostructured morphology of the AZO coated glass surface along with the in-plane dimensions of the deposited AuNPs. Sheet resistance measurements conducted on the coated samples verified that the electrical properties of the 3D network are comparable to that of the untextured two-dimensional AZO coated glass substrates. In addition, transmittance measurements of the glass samples coated with various AZO thicknesses showed preservation of the highly transparent nature of each sample, while the AuNPs demonstrated enhanced light scattering as well as light-trapping capability.

  18. Spin-glass-like freezing of inner and outer surface layers in hollow ?-Fe2O3 nanoparticles

    SciTech Connect (OSTI)

    Khurshid, Hafsa; Lampen-Kelley, Paula; Iglesias, scar; Alonso, Javier; Phan, Manh-Huong; Sun, Cheng-Jun; Saboungi, Marie-Louise; Srikanth, Hariharan

    2015-10-27

    Disorder among surface spins largely dominates the magnetic response of ultrafine magnetic particle systems. In this work, we examine time-dependent magnetization in high-quality, monodisperse hollow maghemite nanoparticles (NPs) with a 14.80.5 nm outer diameter and enhanced surface-to-volume ratio. The nanoparticle ensemble exhibits spin-glass-like signatures in dc magnetic aging and memory protocols and ac magnetic susceptibility. The dynamics of the system slow near 50 K, and becomes frozen on experimental time scales below 20 K. Remanence curves indicate the development of magnetic irreversibility concurrent with the freezing of the spin dynamics. A strong exchange-bias effect and its training behavior point to highly frustrated surface spins that rearrange much more slowly than interior spins with bulk coordination. Monte Carlo simulations of a hollow particle reproducing the experimental morphology corroborate strongly disordered surface layers with complex energy landscapes that underlie both glass-like dynamics and magnetic irreversibility. Calculated hysteresis loops reveal that magnetic behavior is not identical at the inner and outer surfaces, with spins at the outer surface layer of the 15 nm hollow particles exhibiting a higher degree of frustration. Our combined experimental and simulated results shed light on the origin of spin-glass-like phenomena and the important role played by the surface spins in magnetic hollow nanostructures.

  19. Spin-glass-like freezing of inner and outer surface layers in hollow γ-Fe2O3 nanoparticles

    SciTech Connect (OSTI)

    Khurshid, Hafsa; Lampen-Kelley, Paula; Iglesias, Òscar; Alonso, Javier; Phan, Manh-Huong; Sun, Cheng-Jun; Saboungi, Marie-Louise; Srikanth, Hariharan

    2015-10-27

    Disorder among surface spins largely dominates the magnetic response of ultrafine magnetic particle systems. In this work, we examine time-dependent magnetization in high-quality, monodisperse hollow maghemite nanoparticles (NPs) with a 14.8±0.5 nm outer diameter and enhanced surface-to-volume ratio. The nanoparticle ensemble exhibits spin-glass-like signatures in dc magnetic aging and memory protocols and ac magnetic susceptibility. The dynamics of the system slow near 50 K, and becomes frozen on experimental time scales below 20 K. Remanence curves indicate the development of magnetic irreversibility concurrent with the freezing of the spin dynamics. A strong exchange-bias effect and its training behavior point to highly frustrated surface spins that rearrange much more slowly than interior spins with bulk coordination. Monte Carlo simulations of a hollow particle reproducing the experimental morphology corroborate strongly disordered surface layers with complex energy landscapes that underlie both glass-like dynamics and magnetic irreversibility. Calculated hysteresis loops reveal that magnetic behavior is not identical at the inner and outer surfaces, with spins at the outer surface layer of the 15 nm hollow particles exhibiting a higher degree of frustration. Lastly, our combined experimental and simulated results shed light on the origin of spin-glass-like phenomena and the important role played by the surface spins in magnetic hollow nanostructures.

  20. PLZT capacitor on glass substrate

    DOE Patents [OSTI]

    Fairchild, M. Ray; Taylor, Ralph S.; Berlin, Carl W.; Wong, Celine W. K.; Ma, Beihai; Balachandran, Uthamalingam

    2016-01-05

    A lead-lanthanum-zirconium-titanate (PLZT) capacitor on a substrate formed of glass. The first metallization layer is deposited on a top side of the substrate to form a first electrode. The dielectric layer of PLZT is deposited over the first metallization layer. The second metallization layer deposited over the dielectric layer to form a second electrode. The glass substrate is advantageous as glass is compatible with an annealing process used to form the capacitor.

  1. PLZT capacitor on glass substrate

    DOE Patents [OSTI]

    Fairchild, Manuel Ray; Taylor, Ralph S.; Berlin, Carl W.; Wong, Celine Wk; Ma, Beihai; Balachandran, Uthamalingam

    2016-03-29

    A lead-lanthanum-zirconium-titanate (PLZT) capacitor on a substrate formed of glass. The first metallization layer is deposited on a top side of the substrate to form a first electrode. The dielectric layer of PLZT is deposited over the first metallization layer. The second metallization layer deposited over the dielectric layer to form a second electrode. The glass substrate is advantageous as glass is compatible with an annealing process used to form the capacitor.

  2. Interior and Exterior Low-E Storm Window Installation

    SciTech Connect (OSTI)

    Witters, Sarah

    2014-09-03

    Until recently, energy-efficient window retrofit options have largely been limited to repair or replacement; leaving the homeowner to decide between affordability and deeper energy savings. A new and improved low-e storm window boasts a combination of curb appeal and energy efficiency, all for a fraction of the cost of window replacement. A recent whole-home experiment performed by PNNL suggests that attaching low-e storm windows can result in as much energy savings replacing the windows.

  3. Highly Insulating Glazing Systems using Non-Structural Center Glazing Layers

    SciTech Connect (OSTI)

    Kohler, Christian; Arasteh, Dariush; Goudey, Howdy; Kohler, Christian

    2008-04-09

    Three layer insulating glass units with two low-e coatings and an effective gas fill are known to be highly insulating, with center-of-glass U-factors as low as 0.57 W/m{sup 2}-K (0.10 Btu/h-ft{sup 2}- F). Such units have historically been built with center layers of glass or plastic which extend all the way through the spacer system. This paper shows that triple glazing systems with non-structural center layers which do not create a hermetic seal at the edge have the potential to be as thermally efficient as standard designs, while potentially removing some of the production and product integration issues that have discouraged the use of triples.

  4. Millimeter-Wave Measurements at 137 GHZ of DWPF Black Frit Glass Flow and Salt Layer Pooling in a Pilot Scale Melter

    SciTech Connect (OSTI)

    Woskov, Paul P.; Sundaram, S.K.; Miller, Don; Daniel, Gene; Harden, John

    2004-03-31

    Nuclear waste vitrification in joule-heated melters would be greatly facilitated by the availability of on-line monitoring instrumentation for critical process parameters such as viscosity and salt accumulation. A field test of the applicability of millimeter-wave (MMW) technology to providing such tools was carried out on a pilot scale melter (EV-16) at the Clemson Environmental Technology Laboratory. Flow measurements of Defense Waste Processing Facility (DWPF) black frit glass over a temperature (T) range of 800-1150 C and to depths of over 7 inches (17.8 cm) were made with an immersed ceramic waveguide. Pressure induced melt flow inside the waveguide was observed over an average velocity range of 0.1-10 mm/s consistent with a 1/T viscosity scaling. In another test, sodium sulfate salt (NaSO4) was added to the melt to demonstrate salt layer detection. A 30% decrease in MMW melt emissivity was clearly observed as pools of salt formed and flowed under the waveguide.

  5. EERE Success Story-Performance Validation of Low-e Storm Windows...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Validation of Low-e Storm Windows Paves Way for Market Acceptance EERE Success Story-Performance Validation of Low-e Storm Windows Paves Way for Market Acceptance September 30, ...

  6. R-5 Highly-Insulating Windows and Low-e Storm Windows Volume Purchase Program

    SciTech Connect (OSTI)

    2009-09-30

    Introduces DOE's Building Technologies fenestration RD&D program, and describes the highly insulated R-5 Windows and Low-e Storm Windows Volume Purchase solicitation.

  7. Evaluation of Interior Low-E Storm Windows in the PNNL Lab Homes...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION Lab Homes; Storm; Windows; Low-e; ...

  8. Low-E Storms: The Next "Big Thing" in Window Retrofits

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    America Low-E Storms: The Next "Big Thing" in Window ... compliance with residential and commercial national ... information about window coverings: http:...

  9. Building America's Low-e Storm Window Adoption Program Plan (FY2014)

    SciTech Connect (OSTI)

    Cort, Katherine A.

    2013-12-23

    Low emissivity (low-e) storm windows/panels appear to hold promise for effectively reducing existing home heating, ventilation, and air-conditioning (HVAC) consumption. Due to the affordability of low-e storm windows and the large numbers of existing homes that have low-performing single-pane or double-pane clear windows, a tremendous opportunity exists to provide energy savings by transforming the low-e storm window market and increasing market adoption. This report outlines U.S. Department of Energy (DOE) Building America’s planned market transformation activities in support of low-e storm window adoption during fiscal year (FY) 2014.

  10. Text-Alternative Version of Building America Webinar: Low-e Storms...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-e Storms: The Next "Big Thing" in Window Retrofits ... to show compliance for residential and commercial buildings. ... Also there is information on the efficient window coverings ...

  11. Spontaneous and strong multi-layer graphene n-doping on soda-lime glass and its application in graphene-semiconductor junctions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dissanayake, D. M. N. M.; Ashraf, A.; Dwyer, D.; Kisslinger, K.; Zhang, L.; Pang, Y.; Efstathiadis, H.; Eisaman, M. D.

    2016-02-12

    Scalable and low-cost doping of graphene could improve technologies in a wide range of fields such as microelectronics, optoelectronics, and energy storage. While achieving strong p-doping is relatively straightforward, non-electrostatic approaches to n-dope graphene, such as chemical doping, have yielded electron densities of 9.5 × 1012 e/cm2 or below. Furthermore, chemical doping is susceptible to degradation and can adversely affect intrinsic graphene’s properties. Here we demonstrate strong (1.33 × 1013 e/cm2), robust, and spontaneous graphene n-doping on a soda-lime-glass substrate via surface-transfer doping from Na without any external chemical, high-temperature, or vacuum processes. Remarkably, the n-doping reaches 2.11 × 1013more » e/cm2 when graphene is transferred onto a p-type copper indium gallium diselenide (CIGS) semiconductor that itself has been deposited onto soda-lime-glass, via surface-transfer doping from Na atoms that diffuse to the CIGS surface. Using this effect, we demonstrate an n-graphene/p-semiconductor Schottky junction with ideality factor of 1.21 and strong photo-response. As a result, the ability to achieve strong and persistent graphene n-doping on low-cost, industry-standard materials paves the way toward an entirely new class of graphene-based devices such as photodetectors, photovoltaics, sensors, batteries, and supercapacitors.« less

  12. Storm Windows (Even with a Low-E Coating!) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Storm Windows (Even with a Low-E Coating) November 11, 2008 - 3:45pm Addthis John Lippert ... Alex is one of the world's experts on green building materials, so I'm always glad to see ...

  13. Building America Webinar: Low-E Storms: The Next Big Thing in...

    Energy Savers [EERE]

    This Building America webinar presented a new and improved low-e storm window that boasts a combination of curb appeal and energy efficiency, all for a fraction of the cost of ...

  14. Low-e Storm Windows: Market Assessment and Pathways to Market Transformation

    SciTech Connect (OSTI)

    Cort, Katherine A.

    2013-06-08

    Field studies sponsored by the U.S. Department of Energy (DOE) have shown that the use of low-e storm windows can lead to significant heating and cooling energy savings in residential homes. This study examines the market for low-e storm windows based on market data, case studies, and recent experience with weatherization deployment programs. It uses information from interviews conducted with DOE researchers and industry partners involved in case studies and early deployment efforts related to low-e storm windows. In addition, this study examines potential barriers to market acceptance, assesses the market and energy savings potential, and identifies opportunities to transform the market for low-e storm windows and overcome market adoption barriers.

  15. Building America Webinar: Low-E Storms: The Next Big Thing in Window Retrofits

    Office of Energy Efficiency and Renewable Energy (EERE)

    This Building America webinar presented a new and improved low-e storm window that boasts a combination of curb appeal and energy efficiency, all for a fraction of the cost of window replacement, on Sept. 9, 2014.

  16. ITP Glass: Glass Industry of the Future: Energy and Environmental...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007 ITP Glass: A Clear Vision for a Bright Future ITP Glass: Glass Industry Technology Roadmap; April 2002

  17. Building America Webinar: High Performance Enclosure Strategies, Part II: Low-E Storm Windows and Window Attachments

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation from Building America Webinar: High Performance Enclosure Strategies, Part II: Low-E Storm Windows and Window Attachments.

  18. Energy Savings of Low-E Storm Windows and Panels across US Climate Zones

    SciTech Connect (OSTI)

    Culp, Thomas D.; Cort, Katherine A.

    2015-10-01

    This report builds off of previous modeling work related to low-e storm windows used to create a "Database of U.S. Climate-Based Analysis for Low-E Storm Windows." This work updates similar studies using new fuel costs and examining the separate contributions of reduced air leakage and reduced coefficients of overall heat transfer and solar heat gain. In this report we examine the energy savings and cost effectiveness of low-E storm windows in residential homes across a broad range of U.S. climates, excluding the impact from infiltration reductions, which tend to vary using the National Energy Audit Tool (NEAT) and RESFEN model calculations. This report includes a summary of the results, NEAT and RESFEN background, methodology, and input assumptions, and an appendix with detailed results and assumptions by climate zone.

  19. Thermal and Optical Properties of Low-E Storm Windows and Panels

    SciTech Connect (OSTI)

    Culp, Thomas D.; Widder, Sarah H.; Cort, Katherine A.

    2015-07-17

    Installing low-emissivity (low-E) storm windows and panels over existing windows has been identified as a cost-effective new approach for improving the energy efficiency of existing buildings where window replacement is impractical or too expensive. As such, it is desirable to characterize the key energy performance properties of low-E storm windows and panels when installed over different types of existing primary windows. this paper presents the representative U-factors, solar heat gain coefficients (SGHCs) and visible transmittance properties of the combined assemblies of various storm windows and panel types installed over different primary windows.

  20. Database of Low-e Storm Window Energy Performance across U.S. Climate Zones

    SciTech Connect (OSTI)

    Culp, Thomas D.; Cort, Katherine A.

    2014-09-04

    This is an update of a report that describes process, assumptions, and modeling results produced Create a Database of U.S. Climate-Based Analysis for Low-E Storm Windows. The scope of the overall effort is to develop a database of energy savings and cost effectiveness of low-E storm windows in residential homes across a broad range of U.S. climates using the National Energy Audit Tool (NEAT) and RESFEN model calculations. This report includes a summary of the results, NEAT and RESFEN background, methodology, and input assumptions, and an appendix with detailed results and assumptions by cliamte zone.

  1. Pd/Ni-WO3 anodic double layer gasochromic device

    DOE Patents [OSTI]

    Lee, Se-Hee; Tracy, C. Edwin; Pitts, J. Roland; Liu, Ping

    2004-04-20

    An anodic double layer gasochromic sensor structure for optical detection of hydrogen in improved response time and with improved optical absorption real time constants, comprising: a glass substrate; a tungsten-doped nickel oxide layer coated on the glass substrate; and a palladium layer coated on the tungsten-doped nickel oxide layer.

  2. Low-Cost, Highly Transparent Flexible low-e Coating Film to Enable Electrochromic Windows with Increased Energy Savings

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Berland, bberland@itnes.com ITN Energy Systems Low-Cost, Highly Transparent Flexible low-e Coating Film to Enable Electrochromic Windows with Increased Energy Savings 2014 Building Technologies Office Peer Review 2 Project Summary Timeline: Start date: October 1, 2013 Planned end date: September 30, 2014 Key Milestones 1.Low-e Film: 90% T,vis & R,ir (100 cm 2 ) (Q2) 2.Low-e Film: 90% T,vis & R,ir (2m long, %T,%R variation < 2% cross web) (Q3) 3.Demonstrate Low-e/EC Film (Q3) Budget:

  3. Text-Alternative Version of Building America Webinar: Low-e Storms: The Next "Big Thing" in Window Retrofits

    Broader source: Energy.gov [DOE]

    Low-e Storms:  The Next “Big Thing” in Window RetrofitsOfficial Webinar Transcript (September 9, 2014)

  4. Encapsulant Material For Solar Cell Module And Laminated Glass Applications

    DOE Patents [OSTI]

    Hanoka, Jack I.

    2000-09-05

    An encapsulant material includes a layer of metallocene polyethylene disposed between two layers of ionomer. More specifically, the layer of metallocene polyethylene is disposed adjacent a rear surface of the first ionomer layer, and a second layer of ionomer is disposed adjacent a rear surface of the layer of metallocene polyethylene. The encapsulant material can be used in solar cell module and laminated glass applications.

  5. Encapsulant Material For Solar Cell Module And Laminated Glass Applications

    DOE Patents [OSTI]

    Hanoka, Jack I.; Klemchuk, Peter P.

    2001-02-13

    An encapsulant material includes a layer of metallocene polyethylene disposed between two layers of an acid copolymer of polyethylene. More specifically, the layer of metallocene polyethylene is disposed adjacent a rear surface of the first layer of the acid copolymer of polyethylene, and a second layer of the acid copolymer of polyethlene is disposed adjacent a rear surface of the layer of metallocene polyethylene. The encapsulant material can be used in solar cell module and laminated glass applications.

  6. ITP Glass: Industrial Glass Bandwidth Analysis Final Report,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ITP Glass: Glass Industry of the Future: Energy and Environmental Profile of the U.S. Glass Industry; April, 2002 ITP Glass: Glass Industry Technology Roadmap; April 2002 ITP ...

  7. Bioactive glass coatings for orthopedic metallic implants

    SciTech Connect (OSTI)

    Lopez-Esteban, Sonia; Saiz, Eduardo; Fujino, Sigheru; Oku, Takeo; Suganuma, Katsuaki; Tomsia, Antoni P.

    2003-06-30

    The objective of this work is to develop bioactive glass coatings for metallic orthopedic implants. A new family of glasses in the SiO2-Na2O-K2O-CaO-MgO-P2O5 system has been synthesized and characterized. The glass properties (thermal expansion, softening and transformation temperatures, density and hardness) are in line with the predictions of established empirical models. The optimized firing conditions to fabricate coatings on Ti-based and Co-Cr alloys have been determined and related to the glass properties and the interfacial reactions. Excellent adhesion to alloys has been achieved through the formation of 100-200 nm thick interfacial layers (Ti5Si3 on Ti-based alloys and CrOx on Co-Cr). Finally, glass coatings, approximately 100 mu m thick, have been fabricated onto commercial Ti alloy-based dental implants.

  8. ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Industrial Glass Bandwidth Analysis Final Report, August 2007 ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007 industrial_bandwidth.pdf (360.99 KB) More Documents & Publications ITP Glass: Glass Industry of the Future: Energy and Environmental Profile of the U.S. Glass Industry; April, 2002 ITP Glass: Glass Industry Technology Roadmap; April 2002 ITP Glass: A Clear Vision for a Bright Future

  9. Method for forming glass-to-metal seals

    DOE Patents [OSTI]

    Kramer, Daniel P.; Massey, Richard T.

    1986-01-01

    A method for forming a glass-to-metal seal in which the glass has a higher melting point than the metal. The molten glass is vacuum injection molded onto the metal, thus melting a very thin layer of the surface of the metal long enough to form a seal, but not long enough to cause a distortion in the shape of the metal component.

  10. Using sputter coated glass to stabilize microstrip gas chambers

    DOE Patents [OSTI]

    Gong, Wen G.

    1997-01-01

    By sputter coating a thin-layer of low-resistive, electronically-conductive glass on various substrates (including quartz and ceramics, thin-film Pestov glass), microstrip gas chambers (MSGC) of high gain stability, low leakage current, and a high rate capability can be fabricated. This design can make the choice of substrate less important, save the cost of ion-implantation, and use less glass material.

  11. Method for forming glass-to-metal seals

    DOE Patents [OSTI]

    Kramer, D.P.; Massey, R.T.

    1985-08-26

    Disclosed is a method for forming a glass-to-metal seal in which the glass has a higher melting point than the metal. The molten glass is vacuum injection molded onto the metal, thus melting a very thin layer of the surface of the metal long enough to form a seal, but not long enough to cause a distortion in the shape of the metal component.

  12. GlassForm

    Energy Science and Technology Software Center (OSTI)

    2011-09-16

    GlassForm is a software tool for generating preliminary waste glass formulas for a given waste stream. The software is useful because it reduces the number of verification melts required to develop a suitable additive composition. The software includes property models that calculate glass properties of interest from the chemical composition of the waste glass. The software includes property models for glass viscosity, electrical conductivity, glass transition temperature, and leach resistance as measured by the 7-daymore » product consistency test (PCT).« less

  13. Ammonia-treated phosphate glasses useful for sealing to metals

    DOE Patents [OSTI]

    Brow, R.K.; Day, D.E.

    1991-09-03

    A method of improving surface-dependent properties of phosphate glass such as durability and wear resistance without significantly affecting its thermal expansion coefficient is provided which comprises annealing the glass in a dry ammonia atmosphere at temperatures approximating the transition temperature of the glass. The ammonia annealing treatment of the present invention is carried out for a time sufficient to allow incorporation of a thin layer of nitrogen into the surface of the phosphate glass, and the treatment improves the durability of the glass without the reduction in the thermal expansion coefficient that has restricted the effectiveness of prior ammonia treatments. The improved phosphate glass resulting from this method is superior in wear resistance, yet maintains suitable thermal expansion properties so that it may be used effectively in a variety of applications requiring hermetic glass-metal seals.

  14. MECS 2006- Glass

    Office of Energy Efficiency and Renewable Energy (EERE)

    Manufacturing Energy and Carbon Footprint for Glass (NAICS 3272, 327993) Sector with Total Energy Input, October 2012 (MECS 2006)

  15. Radiation coloration resistant glass

    DOE Patents [OSTI]

    Tomozawa, M.; Watson, E.B.; Acocella, J.

    1986-11-04

    A radiation coloration resistant glass is disclosed which is used in a radiation environment sufficient to cause coloration in most forms of glass. The coloration resistant glass includes higher proportions by weight of water and has been found to be extremely resistant to color change when exposed to such radiation levels. The coloration resistant glass is free of cerium oxide and has more than about 0.5% by weight water content. Even when exposed to gamma radiation of more than 10[sup 7] rad, the coloration resistant glass does not lose transparency. 3 figs.

  16. Radiation coloration resistant glass

    DOE Patents [OSTI]

    Tomozawa, Minoru; Watson, E. Bruce; Acocella, John

    1986-01-01

    A radiation coloration resistant glass is disclosed which is used in a radiation environment sufficient to cause coloration in most forms of glass. The coloration resistant glass includes higher proportions by weight of water and has been found to be extremely resistant to color change when exposed to such radiation levels. The coloration resistant glass is free of cerium oxide and has more than about 0.5% by weight water content. Even when exposed to gamma radiation of more than 10.sup.7 rad, the coloration resistant glass does not lose transparency.

  17. Oxynitride glass production procedure

    DOE Patents [OSTI]

    Weidner, Jerry R. (Idaho Falls, ID); Schuetz, Stanley T. (Idaho Falls, ID); O'Brien, Michael H. (Idaho Falls, ID)

    1991-01-01

    The invention is a process for the preparation of high quality oxynitride glasses without resorting to high pressures. Nitrogen-containing compounds such as Si.sub.3 N.sub.4 are first encapsulated in a low melting temperature glass. Particles of the encapsulated nitrogen-containing compound are mixed with other oxide glass-formers and melted in an atmosphere of flowing nitrogen and in the presence of buffering gas to form the oxynitride glass. Glasses containing up to 15 at % nitrogen have been prepared by this method.

  18. Aligned crystalline semiconducting film on a glass substrate and method of making

    DOE Patents [OSTI]

    Findikoglu, Alp T. (Los Alamos, NM)

    2010-08-24

    A semiconducting structure having a glass substrate. In one embodiment, the glass substrate has a softening temperature of at least about 750.degree. C. The structure includes a nucleation layer formed on a surface of the substrate, a template layer deposited on the nucleation layer by one of ion assisted beam deposition and reactive ion beam deposition, at least on biaxially oriented buffer layer epitaxially deposited on the template layer, and a biaxially oriented semiconducting layer epitaxially deposited on the buffer layer. A method of making the semiconducting structure is also described.

  19. Transistors using crystalline silicon devices on glass

    DOE Patents [OSTI]

    McCarthy, Anthony M.

    1995-01-01

    A method for fabricating transistors using single-crystal silicon devices on glass. This method overcomes the potential damage that may be caused to the device during high voltage bonding and employs a metal layer which may be incorporated as part of the transistor. This is accomplished such that when the bonding of the silicon wafer or substrate to the glass substrate is performed, the voltage and current pass through areas where transistors will not be fabricated. After removal of the silicon substrate, further metal may be deposited to form electrical contact or add functionality to the devices. By this method both single and gate-all-around devices may be formed.

  20. Diamond turning of glass

    SciTech Connect (OSTI)

    Blackley, W.S.; Scattergood, R.O.

    1988-12-01

    A new research initiative will be undertaken to investigate the critical cutting depth concepts for single point diamond turning of brittle, amorphous materials. Inorganic glasses and a brittle, thermoset polymer (organic glass) are the principal candidate materials. Interrupted cutting tests similar to those done in earlier research are Ge and Si crystals will be made to obtain critical depth values as a function of machining parameters. The results will provide systematic data with which to assess machining performance on glasses and amorphous materials

  1. HLW Glass Waste Loadings

    Office of Environmental Management (EM)

    HLW Glass Waste Loadings Ian L. Pegg Vitreous State Laboratory The Catholic University of ... (JHCM) technology Factors affecting waste loadings Waste loading requirements ...

  2. ITP Glass: Glass Industry Technology Roadmap; April 2002

    Broader source: Energy.gov [DOE]

    Glass is a unique material that has been produced for thousands of years. The glass industry's products are an integral part of the American economy and everyday life. Glass products are used in food and beverage packaging, lighting, communications, etc.

  3. SLUDGE BATCH 7B GLASS VARIABILITY STUDY

    SciTech Connect (OSTI)

    Johnson, F.; Edwards, T.

    2011-10-25

    The Defense Waste Processing Facility (DWPF) is preparing to initiate processing Sludge Batch 7b (SB7b). In support of the upcoming processing, the Savannah River National Laboratory (SRNL) provided a recommendation to utilize Frits 418 with a 6% Na{sub 2}O addition (26 wt% Na{sub 2}O in sludge) and 702 with a 4% Na{sub 2}O addition (24 wt% Na{sub 2}O in sludge) to process SB7b. This recommendation was based on assessments of the compositional projections for SB7b available at the time from the Savannah River Remediation (SRR). To support qualification of SB7b, SRNL executed a variability study to assess the applicability of the current durability models for SB7b. The durability models were assessed over the expected composition range of SB7b, including potential caustic additions, combined with Frits 702 and 418 over a 32-40% waste loading (WL) range. Thirty four glasses were selected based on Frits 418 and 702 coupled with the sludge projections with an additional 4-6% Na{sub 2}O to reflect the potential caustic addition. Six of these glasses, based on average nominal sludge compositions including the appropriate caustic addition, were developed for both Frit 418 and Frit 702 at 32, 36 and 40% WL to provide coverage in the center of the anticipated SB7b glass region. All glasses were fabricated and characterized using chemical composition analysis, X-ray diffraction (XRD) and the Product Consistency Test (PCT). To comply with the DWPF Glass Product Control Program, a total of thirty four glasses were fabricated to assess the applicability of the current DWPF PCCS durability models. Based on the measured PCT response, all of the glasses were acceptable with respect to the Environmental Assessment (EA) benchmark glass regardless of thermal history. The NL[B] values of the SB7b variability study glasses were less than 1.99 g/L as compared to 16.695 g/L for EA. A small number of the D-optimally selected 'outer layer' extreme vertices (EV) glasses were not predictable

  4. ITP Glass: Glass Industry of the Future: Energy and Environmental...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Glass plants remove air pollutants through the use of aqueous media, filters, and precipitators. Air pollution control technologies used in the glass industry commonly transfer ...

  5. Versa Glass | Open Energy Information

    Open Energy Info (EERE)

    search Name: Versa Glass Place: Columbus, Ohio Zip: 43220 Product: Versa is manufacturing a new technology privacy glass in Ohio that is LEED and has cleantech properties...

  6. Text-Alternative Version of Building America Webinar: High Performance Enclosure Strategies, Part II: Low-E Storm Windows and Window Attachments

    Broader source: Energy.gov [DOE]

    Text-Alternative Version of Building America Webinar: High Performance Enclosure Strategies, Part II: Low-E Storm Windows and Window Attachments

  7. Glass electrolyte composition

    DOE Patents [OSTI]

    Kucera, Gene H.; Roche, Michael F.

    1985-01-01

    An ionically conductive glass is disclosed for use as electrolyte in a high temperature electrochemical cell, particularly a cell with sodium anode and sulfur cathode. The glass includes the constituents Na.sub.2 O, ZrO.sub.2, Al.sub.2 O.sub.3 and SiO.sub.2 in selected proportions to be a single phase solid solution substantially free of crystalline regions and undissolved constituents. Other advantageous properties are an ionic conductivity in excess of 2.times.10.sup.-3 (ohm-cm).sup.-1 at 300.degree. C. and a glass transition temperature in excess of 500.degree. C.

  8. EXELFS of Metallic Glasses

    SciTech Connect (OSTI)

    Ito, Y.; Alamgir, F.M.; Schwarz, R.B.; Jain, H.; Williams, D.B.

    1999-11-30

    The feasibility of using extended energy-loss fine structure (EXELFS) obtained from {approximately}1 nm regions of metallic glasses to study their short-range order has been examined. Ionization edges of the metallic glasses in the electron energy-loss spectrum (EELS) have been obtained from PdNiP bulk metallic glass and Ni{sub 2}P polycrystalline powder in a transmission electron microscope. The complexity of EXELFS analysis of L- and M-ionization edges of heavy elements (Z>22, i.e. Ni and Pd) is addressed by theoretical calculations using an ab initio computer code, and its results are compared with the experimental data.

  9. Glass electrolyte composition

    DOE Patents [OSTI]

    Kucera, G.H.; Roche, M.F.

    1985-01-08

    An ionically conductive glass is disclosed for use as electrolyte in a high temperature electrochemical cell, particularly a cell with sodium anode and sulfur cathode. The glass includes the constituents Na/sub 2/O, ZrO/sub 2/, Al/sub 2/O/sub 3/ and SiO/sub 2/ in selected proportions to be a single phase solid solution substantially free of crystalline regions and undissolved constituents. Other advantageous properties are an ionic conductivity in excess of 2 x 10/sup -3/ (ohm-cm)/sup -1/ at 300/sup 0/C and a glass transition temperature in excess of 500/sup 0/C.

  10. Glass Stronger than Steel

    DOE R&D Accomplishments [OSTI]

    Yarris, Lynn

    2011-03-28

    A new type of damage-tolerant metallic glass, demonstrating a strength and toughness beyond that of steel or any other known material, has been developed and tested by a collaboration of researchers from Berkeley Lab and Caltech.

  11. Super ionic conductive glass

    DOE Patents [OSTI]

    Susman, S.; Volin, K.J.

    Described is an ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A/sub 1 + x/D/sub 2-x/3/Si/sub x/P/sub 3 - x/O/sub 12 - 2x/3/, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.

  12. Super ionic conductive glass

    DOE Patents [OSTI]

    Susman, Sherman; Volin, Kenneth J.

    1984-01-01

    An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.

  13. Method for making glass nonfogging

    DOE Patents [OSTI]

    Lord, David E.; Carter, Gary W.; Petrini, Richard R.

    1979-01-01

    A method for rendering glass nonfogging (to condensation fog) by sandwiching the glass between two electrodes such that the glass functions as the dielectric of a capacitor, a large alternating current (AC) voltage is applied across the electrodes for a selected time period causing the glass to absorb a charge, and the electrodes are removed. The glass absorbs a charge from the electrodes rendering it nonfogging. The glass surface is undamaged by application of the AC voltage, and normal optical properties are unaffected. This method can be applied to optical surfaces such as lenses, auto windshields, mirrors, etc., wherever condensation fog on glass is a problem.

  14. Baseline LAW Glass Formulation Testing

    SciTech Connect (OSTI)

    Kruger, Albert A.; Mooers, Cavin; Bazemore, Gina; Pegg, Ian L.; Hight, Kenneth; Lai, Shan Tao; Buechele, Andrew; Rielley, Elizabeth; Gan, Hao; Muller, Isabelle S.; Cecil, Richard

    2013-06-13

    The major objective of the baseline glass formulation work was to develop and select glass formulations that are compliant with contractual and processing requirements for each of the LAW waste streams. Other objectives of the work included preparation and characterization of glasses with respect to the properties of interest, optimization of sulfate loading in the glasses, evaluation of ability to achieve waste loading limits, testing to demonstrate compatibility of glass melts with melter materials of construction, development of glass formulations to support ILAW qualification activities, and identification of glass formulation issues with respect to contract specifications and processing requirements.

  15. Experimental Design for Hanford Low-Activity Waste Glasses with High Waste Loading

    SciTech Connect (OSTI)

    Piepel, Gregory F.; Cooley, Scott K.; Vienna, John D.; Crum, Jarrod V.

    2015-07-24

    This report discusses the development of an experimental design for the initial phase of the Hanford low-activity waste (LAW) enhanced glass study. This report is based on a manuscript written for an applied statistics journal. Appendices A, B, and E include additional information relevant to the LAW enhanced glass experimental design that is not included in the journal manuscript. The glass composition experimental region is defined by single-component constraints (SCCs), linear multiple-component constraints (MCCs), and a nonlinear MCC involving 15 LAW glass components. Traditional methods and software for designing constrained mixture experiments with SCCs and linear MCCs are not directly applicable because of the nonlinear MCC. A modification of existing methodology to account for the nonlinear MCC was developed and is described in this report. One of the glass components, SO3, has a solubility limit in glass that depends on the composition of the balance of the glass. A goal was to design the experiment so that SO3 would not exceed its predicted solubility limit for any of the experimental glasses. The SO3 solubility limit had previously been modeled by a partial quadratic mixture model expressed in the relative proportions of the 14 other components. The partial quadratic mixture model was used to construct a nonlinear MCC in terms of all 15 components. In addition, there were SCCs and linear MCCs. This report describes how a layered design was generated to (i) account for the SCCs, linear MCCs, and nonlinear MCC and (ii) meet the goals of the study. A layered design consists of points on an outer layer, and inner layer, and a center point. There were 18 outer-layer glasses chosen using optimal experimental design software to augment 147 existing glass compositions that were within the LAW glass composition experimental region. Then 13 inner-layer glasses were chosen with the software to augment the existing and outer-layer

  16. Integrated Disposal Facility FY 2012 Glass Testing Summary Report

    SciTech Connect (OSTI)

    Pierce, Eric M.; Kerisit, Sebastien N.; Krogstad, Eirik J.; Burton, Sarah D.; Bjornstad, Bruce N.; Freedman, Vicky L.; Cantrell, Kirk J.; Snyder, Michelle MV; Crum, Jarrod V.; Westsik, Joseph H.

    2013-03-29

    PNNL is conducting work to provide the technical basis for estimating radionuclide release from the engineered portion of the disposal facility for Hanford immobilized low-activity waste (ILAW). Before the ILAW can be disposed, DOE must conduct a performance assessment (PA) for the Integrated Disposal Facility (IDF) that describes the long-term impacts of the disposal facility on public health and environmental resources. As part of the ILAW glass testing program, PNNL is implementing a strategy, consisting of experimentation and modeling, to provide the technical basis for estimating radionuclide release from the glass waste form in support of future IDF PAs. Key activities in FY12 include upgrading the STOMP/eSTOMP codes to do near-field modeling, geochemical modeling of PCT tests to determine the reaction network to be used in the STOMP codes, conducting PUF tests on selected glasses to simulate and accelerate glass weathering, developing a Monte Carlo simulation tool to predict the characteristics of the weathered glass reaction layer as a function of glass composition, and characterizing glasses and soil samples exhumed from an 8-year lysimeter test. The purpose of this report is to summarize the progress made in fiscal year (FY) 2012 and the first quarter of FY 2013 toward implementing the strategy with the goal of developing an understanding of the long-term corrosion behavior of LAW glasses.

  17. DWPF GLASS BEADS AND GLASS FRIT TRANSPORT DEMONSTRATION

    SciTech Connect (OSTI)

    Adamson, D; Bradley Pickenheim, B

    2008-11-24

    DWPF is considering replacing irregularly shaped glass frit with spherical glass beads in the Slurry Mix Evaporator (SME) process to decrease the yield stress of the melter feed (a non-Newtonian Bingham Plastic). Pilot-scale testing was conducted on spherical glass beads and glass frit to determine how well the glass beads would transfer when compared to the glass frit. Process Engineering Development designed and constructed the test apparatus to aid in the understanding and impacts that spherical glass beads may have on the existing DWPF Frit Transfer System. Testing was conducted to determine if the lines would plug with the glass beads and the glass frit slurry and what is required to unplug the lines. The flow loop consisted of vertical and horizontal runs of clear PVC piping, similar in geometry to the existing system. Two different batches of glass slurry were tested: a batch of 50 wt% spherical glass beads and a batch of 50 wt% glass frit in process water. No chemicals such as formic acid was used in slurry, only water and glass formers. The glass beads used for this testing were commercially available borosilicate glass of mesh size -100+200. The glass frit was Frit 418 obtained from DWPF and is nominally -45+200 mesh. The spherical glass beads did not have a negative impact on the frit transfer system. The transferring of the spherical glass beads was much easier than the glass frit. It was difficult to create a plug with glass bead slurry in the pilot transfer system. When a small plug occurred from setting overnight with the spherical glass beads, the plug was easy to displace using only the pump. In the case of creating a man made plug in a vertical line, by filling the line with spherical glass beads and allowing the slurry to settle for days, the plug was easy to remove by using flush water. The glass frit proved to be much more difficult to transfer when compared to the spherical glass beads. The glass frit impacted the transfer system to the point

  18. Topography and Mechanical Property Mapping of International Simple Glass Surfaces with Atomic Force Microscopy

    SciTech Connect (OSTI)

    Pierce, Eric M

    2014-01-01

    Quantitative Nanomechanical Peak Force (PF-QNM) TappingModeTM atomic force microscopy measurements are presented for the first time on polished glass surfaces. The PF-QNM technique allows for topography and mechanical property information to be measured simultaneously at each pixel. Results for the international simple glass which represents a simplified version of SON68 glass suggests an average Young s modulus of 78.8 15.1 GPa is within the experimental error of the modulus measured for SON68 glass (83.6 2 GPa) with conventional approaches. Application of the PF-QNM technique will be extended to in situ glass corrosion experiments with the goal of gaining atomic-scale insights into altered layer development by exploiting the mechanical property differences that exist between silica gel (e.g., altered layer) and pristine glass surface.

  19. Reduction of Glass Surface Reflectance by Ion Beam Surface Modification

    SciTech Connect (OSTI)

    Mark Spitzer

    2011-03-11

    This is the final report for DOE contract DE-EE0000590. The purpose of this work was to determine the feasibility of the reduction of the reflection from the front of solar photovoltaic modules. Reflection accounts for a power loss of approximately 4%. A solar module having an area of one square meter with an energy conversion efficiency of 18% generates approximately 180 watts. If reflection loss can be eliminated, the power output can be increased to 187 watts. Since conventional thin-film anti-reflection coatings do not have sufficient environmental stability, we investigated the feasibility of ion beam modification of the glass surface to obtain reduction of reflectance. Our findings are generally applicable to all solar modules that use glass encapsulation, as well as commercial float glass used in windows and other applications. Ion implantation of argon, fluorine, and xenon into commercial low-iron soda lime float glass, standard float glass, and borosilicate glass was studied by implantation, annealing, and measurement of reflectance. The three ions all affected reflectance. The most significant change was obtained by argon implantation into both low-iron and standard soda-lime glass. In this way samples were formed with reflectance lower than can be obtained with a single-layer coatings of magnesium fluoride. Integrated reflectance was reduced from 4% to 1% in low-iron soda lime glass typical of the glass used in solar modules. The reduction of reflectance of borosilicate glass was not as large; however borosilicate glass is not typically used in flat plate solar modules. Unlike conventional semiconductor ion implantation doping, glass reflectance reduction was found to be tolerant to large variations in implant dose, meaning that the process does not require high dopant uniformity. Additionally, glass implantation does not require mass analysis. Simple, high current ion implantation equipment can be developed for this process; however, before the process

  20. Glass matrix armor

    DOE Patents [OSTI]

    Calkins, Noel C.

    1991-01-01

    An armor system which utilizes glass. A plurality of constraint cells are mounted on a surface of a substrate, which is metal armor plate or a similar tough material, such that the cells almost completely cover the surface of the substrate. Each constraint cell has a projectile-receiving wall parallel to the substrate surface and has sides which are perpendicular to and surround the perimeter of the receiving wall. The cells are mounted such that, in one embodiment, the substrate surface serves as a sixth side or closure for each cell. Each cell has inside of it a plate, termed the front plate, which is parallel to and in contact with substantially all of the inside surface of the receiving wall. The balance of each cell is completely filled with a projectile-abrading material consisting of glass and a ceramic material and, in certain embodiments, a polymeric material. The glass may be in monolithic form or particles of ceramic may be dispersed in a glass matrix. The ceramic material may be in monolithic form or may be in the form of particles dispersed in glass or dispersed in said polymer.

  1. Taiwan Glass Industry Corp | Open Energy Information

    Open Energy Info (EERE)

    Taiwan Glass Industry Corp Place: Taipei, Taiwan Zip: 10566 Product: Engaged in the manufacturing, processing and selling of various types of glass. References: Taiwan Glass...

  2. Xinyi Glass Holdings Limited | Open Energy Information

    Open Energy Info (EERE)

    in the produciton of float glass, automobile glass, construction glass and curtain wall. Coordinates: 23.046499, 113.735817 Show Map Loading map... "minzoom":false,"mappi...

  3. Glass strengthening and patterning methods

    SciTech Connect (OSTI)

    Harper, David C; Wereszczak, Andrew A; Duty, Chad E

    2015-01-27

    High intensity plasma-arc heat sources, such as a plasma-arc lamp, are used to irradiate glass, glass ceramics and/or ceramic materials to strengthen the glass. The same high intensity plasma-arc heat source may also be used to form a permanent pattern on the glass surface--the pattern being raised above the glass surface and integral with the glass (formed of the same material) by use of, for example, a screen-printed ink composition having been irradiated by the heat source.

  4. Ammonia-treated phosphate glasses useful for sealing to metals metals

    DOE Patents [OSTI]

    Brow, Richard K.; Day, Delbert E.

    1991-01-01

    A method of improving surface-dependent properties of phosphate glass such as durability and wear resistance without significantly affecting its thermal expansion coefficient is provided which comprises annealing the glass in a dry ammonia atmosphere at temperatures approximating the transition temperature of the glass. The ammonia annealing treatment of the present invention is carried out for a time sufficient to allow incorporation of a thin layer of nitrogen into the surface of the phosphate glass, and the treatment improves the durability of the glass without the reduction in the thermal expansion coefficient that has restricted the effectiveness of prior ammonia treatments. The improved phosphate glass resulting from this method is superior in wear resistance, yet maintains suitable thermal expansion properties so that it may be used effectively in a variety of applications requiring hermetic glass-metal seals.

  5. GRADIENT INDEX SPHERES BY THE SEQUENTIAL ACCRETION OF GLASS POWDERS

    SciTech Connect (OSTI)

    MARIANO VELEZ

    2008-06-15

    The Department of Energy is seeking a method for fabricating mm-scale spheres having a refractive index that varies smoothly and continuously from the center to its surface [1]. The fabrication procedure must allow the creation of a range of index profiles. The spheres are to be optically transparent and have a refractive index differential greater than 0.2. The sphere materials can be either organic or inorganic and the fabrication technique must be capable of scaling to low cost production. Mo-Sci Corporation proposed to develop optical quality gradient refractive index (GRIN) glass spheres of millimeter scale (1 to 2 mm diameter) by the sequential accretion and consolidation of glass powders. Other techniques were also tested to make GRIN spheres as the powder-accretion method produced non-concentric layers and poor optical quality glass spheres. Potential ways to make the GRIN spheres were (1) by "coating" glass spheres (1 to 2 mm diameter) with molten glass in a two step process; and (2) by coating glass spheres with polymer layers.

  6. Transistors using crystalline silicon devices on glass

    DOE Patents [OSTI]

    McCarthy, A.M.

    1995-05-09

    A method is disclosed for fabricating transistors using single-crystal silicon devices on glass. This method overcomes the potential damage that may be caused to the device during high voltage bonding and employs a metal layer which may be incorporated as part of the transistor. This is accomplished such that when the bonding of the silicon wafer or substrate to the glass substrate is performed, the voltage and current pass through areas where transistors will not be fabricated. After removal of the silicon substrate, further metal may be deposited to form electrical contact or add functionality to the devices. By this method both single and gate-all-around devices may be formed. 13 figs.

  7. CADMIUM PHOSPHATE GLASS

    DOE Patents [OSTI]

    Carpenter, H.W.; Johnson, P.D.

    1963-04-01

    A method of preparing a cadmium phosphate glass that comprises providing a mixture of solid inorganic compounds of cadmuim and phosphate having vaporizable components and heating the resulting composition to a temperature of at least 850 un. Concent 85% C is presented. (AEC)

  8. Barstow heliostat mirror glass characterization

    SciTech Connect (OSTI)

    Lind, M.A.; Buckwalter, C.Q.

    1980-09-01

    The technical analysis performed on the special run of low iron float glass procured from the Ford Glass Division for the ten megawatt solar thermal/electric pilot power plant to be constructed at Barstow, California is discussed. The topics that are addressed include the optical properties and the relative durability of the glass. Two optical parameters, solar transmittance and optical flatness, were measured as referenced in the specification and found to be better than the stated tolerances. The average solar transmittance exceeded 0.890 transmittance units. The glass also exhibited optical angular flatness deviations less than +-1.0 mrad as required. Both qualitative and quantitative accelerated weathering tests were performed on the glass in order to compare its durability to other soda lime float glass and alternate composition glasses of interest to the solar community. In both the quantitative leaching experiments and the more qualitative room temperature and elevated temperature water vapor exposure experiments the heliostat glass exhibited the same characteristics as the other soda-lime silicate float glasses. As a final test for mirroring compatability, selected samples of the production run of the glass were sent to four different commercial manufacturers for mirror coating. None of the manufacturers reported any difficulty silvering the glass. Based on the tests performed, the glass meets or exceeds all optical specifications for the Barstow heliostat field.

  9. Optical Properties of Zn(O,S) Thin Films Deposited by RF Sputtering, Atomic Layer Deposition, and Chemical Bath Deposition: Preprint

    SciTech Connect (OSTI)

    Li, J.; Glynn, S.; Christensen, S.; Mann, J.; To, B.; Ramanathan, K.; Noufi, R.; Furtak, T. E.; Levi, D.

    2012-06-01

    Zn(O,S) thin films 27 - 100 nm thick were deposited on glass or Cu(InxGa1-x)Se2/Molybdenum/glass with RF sputtering, atomic layer deposition, and chemical bath deposition.

  10. Glass-water interactions: Effect of high-valence cations on glass structure and chemical durability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pierce, Eric M.; Kerisit, Sebastien N.; Charpentier, Thibault; Angeli, Frederic; Icenhower, J. P.; McGrail, B. Pete; Charles F. Windisch; Burton, Sarah D.; Hopf, Juliane

    2016-02-27

    Spectroscopic measurements, dissolution experiments, and Monte Carlo simulations were performed to investigate the effect of high valence cations (HVC) on the mechanisms of glass dissolution under dilute and near-saturated conditions. Raman and NMR spectroscopy were used to determine the structural changes that occur in glass, specifically network formers (e.g., Al, Si, and B), with the addition of the HVC element hafnium in the Na2O Al2O3 B2O3 HfO2 SiO2 system (e.g., Na/(Al+B) = 1.0 and HfO2/SiO2 from 0.0 to 0.42). Spectroscopic measurements revealed that increasing hafnium content decreases N4 and increases the amount of Si–O–Hf moieties in the glass. Results frommore » flow through experiments conducted under dilute and near saturated conditions show a decrease of approximately 100 or more in the dissolution rate over the series from 0 to 20 mol% HfO2. Comparing the average steady-state rates obtained under dilute conditions to the rates obtained for near-saturated conditions reveal a divergence in the magnitude between the average steady state rates measured in these different conditions. The reason for this divergence was investigated more thoroughly using Monte Carlo simulations. Simulations indicate that the divergence in glass dissolution behavior under dilute and near-saturated conditions result from the formation of a low coordination Si sites when Si from the saturated solution adsorbs to Hf on the glass surface. The residence time of the newly formed low coordination Si sites is longer at the glass surface and increases the density of anchor sites from which altered layers with higher Si densities can form than in the absence of Hf. These results illustrate the importance of understanding solid water/solid-fluid interactions by linking macroscopic reaction kinetics to nanometer scale interfacial processes.« less

  11. Profiles in garbage glass containers

    SciTech Connect (OSTI)

    Miller, C.

    1997-09-01

    Glass containers are made from sand, limestone, soda ash, cullet (crushed bottles), and various additives, including those used to color brown, green, or blue bottles. Sixty percent of the glass used in the US is clear (flint) and one-fourth is brown (amber). Almost half of the green bottles are imported wind and beer bottles. Other glass products include flat glass such as windows; fiberglass insulation; and glassware. These products use different manufacturing processes and different additives than container glass. This profile covers only container glass. Glass bottles are commonly collected in curb-side programs. Losses due to breakage and the abrasiveness of glass during collection and processing offset their low collection and processing costs. Breakage solutions include installation of interior baffles or nets in the collection trucks, special glass-only truck compartments, and limiting the number of times glass is transferred after collection before final processing. Ten states require deposits on glass bottles for beer and soft drinks and related items.

  12. Production of glass or glass-ceramic to metal seals with the application of pressure

    DOE Patents [OSTI]

    Kelly, Michael D.; Kramer, Daniel P.

    1987-11-10

    In a process for preparing a glass or glass-ceramic to metal seal comprising contacting the glass with the metal and heat-treating the glass and metal under conditions whereby the glass to metal seal is effected and, optionally, the glass is converted to a glass-ceramic, an improvement comprises carrying out the heat-treating step using hot isostatic pressing.

  13. Production of glass or glass-ceramic to metal seals with the application of pressure

    DOE Patents [OSTI]

    Kelly, M.D.; Kramer, D.P.

    1985-01-04

    In a process for preparing a glass or glass-ceramic to metal seal comprising contacting the glass with the metal and heat-treating the glass and metal under conditions whereby the glass to metal seal is effected and, optionally, the glass is converted to a glass-ceramic, an improvement comprises carrying out the heat-treating step using hot isostatic pressing.

  14. ITP Glass: Glass Industry of the Future: Energy and Environmental Profile

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of the U.S. Glass Industry; April, 2002 | Department of Energy Glass Industry of the Future: Energy and Environmental Profile of the U.S. Glass Industry; April, 2002 ITP Glass: Glass Industry of the Future: Energy and Environmental Profile of the U.S. Glass Industry; April, 2002 glass2002profile.pdf (4.73 MB) More Documents & Publications ITP Glass: Industrial Glass Bandwidth Analysis Final Report, August 2007 ITP Glass: A Clear Vision for a Bright Future ITP Glass: Glass Industry

  15. Mixed polyanion glass cathodes: Glass-state conversion reactions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kercher, Andrew K.; Kolopus, James A.; Carroll, Kyler; Unocic, Raymond R.; Kirklin, S.; Wolverton, C.; Stooksbury, Shelby L.; Boatner, Lynn A.; Dudney, Nancy J.

    2015-01-01

    Mixed polyanion (MP) glasses can undergo glass-state conversion (GSC) reactions to provide an alternate class of high-capacity cathode materials. GSC reactions have been demonstrated in phosphate/vanadate glasses with Ag, Co, Cu, Fe, and Ni cations. These MP glasses provided high capacity and good high power performance, but suffer from moderate voltages, large voltage hysteresis, and significant capacity fade with cycling. Details of the GSC reaction have been revealed by x-ray absorption spectroscopy, electron microscopy, and energy dispersive x-ray spectroscopy of ex situ cathodes at key states of charge. Using the Open Quantum Materials Database (OQMD), a computational thermodynamic model hasmore » been developed to predict the near-equilibrium voltages of glass-state conversion reactions in MP glasses.« less

  16. Mixed polyanion glass cathodes: Glass-state conversion reactions

    SciTech Connect (OSTI)

    Kercher, Andrew K.; Kolopus, James A.; Carroll, Kyler; Unocic, Raymond R.; Kirklin, S.; Wolverton, C.; Stooksbury, Shelby L.; Boatner, Lynn A.; Dudney, Nancy J.

    2015-01-01

    Mixed polyanion (MP) glasses can undergo glass-state conversion (GSC) reactions to provide an alternate class of high-capacity cathode materials. GSC reactions have been demonstrated in phosphate/vanadate glasses with Ag, Co, Cu, Fe, and Ni cations. These MP glasses provided high capacity and good high power performance, but suffer from moderate voltages, large voltage hysteresis, and significant capacity fade with cycling. Details of the GSC reaction have been revealed by x-ray absorption spectroscopy, electron microscopy, and energy dispersive x-ray spectroscopy of ex situ cathodes at key states of charge. Using the Open Quantum Materials Database (OQMD), a computational thermodynamic model has been developed to predict the near-equilibrium voltages of glass-state conversion reactions in MP glasses.

  17. ITP Glass: Industrial Glass Bandwidth Analysis Final Report,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wolf Gas Technology Institute Energy Utilization Center August 2007 Industrial Glass Bandwidth Analysis FINAL REPORT Prepared by: David M. Rue James Servaites Dr. Warren Wolf ...

  18. Glass Property Models and Constraints for Estimating the Glass...

    Office of Scientific and Technical Information (OSTI)

    Plus the models do not currently address the prediction uncertainties that would be needed ... glass volume projections due to model prediction uncertainties that has to be considered ...

  19. Method for fabricating transistors using crystalline silicon devices on glass

    DOE Patents [OSTI]

    McCarthy, Anthony M.

    1997-01-01

    A method for fabricating transistors using single-crystal silicon devices on glass. This method overcomes the potential damage that may be caused to the device during high voltage bonding and employs a metal layer which may be incorporated as part of the transistor. This is accomplished such that when the bonding of the silicon wafer or substrate to the glass substrate is performed, the voltage and current pass through areas where transistors will not be fabricated. After removal of the silicon substrate, further metal may be deposited to form electrical contact or add functionality to the devices. By this method both single and gate-all-around devices may be formed.

  20. Electronic structure of metallic glasses

    SciTech Connect (OSTI)

    Oelhafen, P.; Lapka, R.; Gubler, U.; Krieg, J.; DasGupta, A.; Guentherodt, H.J.; Mizoguchi, T.; Hague, C.; Kuebler, J.; Nagel, S.R.

    1981-01-01

    This paper is organized in six sections and deals with (1) the glassy transition metal alloys, their d-band structure, the d-band shifts on alloying and their relation to the alloy heat of formation (..delta..H) and the glass forming ability, (2) the glass to crystal phase transition viewed by valence band spectroscopy, (3) band structure calculations, (4) metallic glasses prepared by laser glazing, (5) glassy normal metal alloys, and (6) glassy hydrides.

  1. Database of Low-E Storm Window Energy Performance across U.S. Climate Zones (Task ET-WIN-PNNL-FY13-01_5.3)

    SciTech Connect (OSTI)

    Cort, Katherine A.; Culp, Thomas D.

    2013-09-01

    This report describes process, assumptions, and modeling results produced in support of the Emerging Technologies Low-e Storm Windows Task 5.3: Create a Database of U.S. Climate-Based Analysis for Low-E Storm Windows. The scope of the overall effort is to develop a database of energy savings and cost effectiveness of low-E storm windows in residential homes across a broad range of U.S. climates using the National Energy Audit Tool (NEAT) and RESFEN model calculations. This report includes a summary of the results, NEAT and RESFEN background, methodology, and input assumptions, and an appendix with detailed results and assumptions by cliamte zone. Both sets of calculation results will be made publicly available through the Building America Solution Center.

  2. Glass rupture disk

    DOE Patents [OSTI]

    Glass, S. Jill; Nicolaysen, Scott D.; Beauchamp, Edwin K.

    2002-01-01

    A frangible rupture disk and mounting apparatus for use in blocking fluid flow, generally in a fluid conducting conduit such as a well casing, a well tubing string or other conduits within subterranean boreholes. The disk can also be utilized in above-surface pipes or tanks where temporary and controllable fluid blockage is required. The frangible rupture disk is made from a pre-stressed glass with controllable rupture properties wherein the strength distribution has a standard deviation less than approximately 5% from the mean strength. The frangible rupture disk has controllable operating pressures and rupture pressures.

  3. Compositional threshold for Nuclear Waste Glass Durability

    SciTech Connect (OSTI)

    Kruger, Albert A.; Farooqi, Rahmatullah; Hrma, Pavel R.

    2013-04-24

    Within the composition space of glasses, a distinct threshold appears to exist that separates "good" glasses, i.e., those which are sufficiently durable, from "bad" glasses of a low durability. The objective of our research is to clarify the origin of this threshold by exploring the relationship between glass composition, glass structure and chemical durability around the threshold region.

  4. Method for heating a glass sheet

    DOE Patents [OSTI]

    Boaz, Premakaran Tucker (Livonia, MI)

    1998-01-01

    A method for heating a glass sheet includes the steps of heating a glass sheet to a first predetermined temperature and applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature to allow the glass sheet to be formed.

  5. Method for heating a glass sheet

    DOE Patents [OSTI]

    Boaz, P.T.

    1998-07-21

    A method for heating a glass sheet includes the steps of heating a glass sheet to a first predetermined temperature and applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature to allow the glass sheet to be formed. 5 figs.

  6. POROUS WALL, HOLLOW GLASS MICROSPHERES

    SciTech Connect (OSTI)

    Sexton, W.

    2012-06-30

    Hollow Glass Microspheres (HGM) is not a new technology. All one has to do is go to the internet and Google{trademark} HGM. Anyone can buy HGM and they have a wide variety of uses. HGM are usually between 1 to 100 microns in diameter, although their size can range from 100 nanometers to 5 millimeters in diameter. HGM are used as lightweight filler in composite materials such as syntactic foam and lightweight concrete. In 1968 a patent was issued to W. Beck of the 3M{trademark} Company for 'Glass Bubbles Prepared by Reheating Solid Glass Particles'. In 1983 P. Howell was issued a patent for 'Glass Bubbles of Increased Collapse Strength' and in 1988 H. Marshall was issued a patent for 'Glass Microbubbles'. Now Google{trademark}, Porous Wall, Hollow Glass Microspheres (PW-HGMs), the key words here are Porous Wall. Almost every article has its beginning with the research done at the Savannah River National Laboratory (SRNL). The Savannah River Site (SRS) where SRNL is located has a long and successful history of working with hydrogen and its isotopes for national security, energy, waste management and environmental remediation applications. This includes more than 30 years of experience developing, processing, and implementing special ceramics, including glasses for a variety of Department of Energy (DOE) missions. In the case of glasses, SRS and SRNL have been involved in both the science and engineering of vitreous or glass based systems. As a part of this glass experience and expertise, SRNL has developed a number of niches in the glass arena, one of which is the development of porous glass systems for a variety of applications. These porous glass systems include sol gel glasses, which include both xerogels and aerogels, as well as phase separated glass compositions, that can be subsequently treated to produce another unique type of porosity within the glass forms. The porous glasses can increase the surface area compared to 'normal glasses of a 1 to 2 order of

  7. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, X.; Johnson, W.L.

    1998-04-07

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3}K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf){sub a}(Al,Zn){sub b}(Ti,Nb){sub c}(Cu{sub x}Fe{sub y}(Ni,Co){sub z}){sub d} wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d{hor_ellipsis}y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  8. Quinary metallic glass alloys

    DOE Patents [OSTI]

    Lin, Xianghong; Johnson, William L.

    1998-01-01

    At least quinary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise zirconium and/or hafnium in the range of 45 to 65 atomic percent, titanium and/or niobium in the range of 4 to 7.5 atomic percent, and aluminum and/or zinc in the range of 5 to 15 atomic percent. The balance of the alloy compositions comprise copper, iron, and cobalt and/or nickel. The composition is constrained such that the atomic percentage of iron is less than 10 percent. Further, the ratio of copper to nickel and/or cobalt is in the range of from 1:2 to 2:1. The alloy composition formula is: (Zr,Hf).sub.a (Al,Zn).sub.b (Ti,Nb).sub.c (Cu.sub.x Fe.sub.y (Ni,Co).sub.z).sub.d wherein the constraints upon the formula are: a ranges from 45 to 65 atomic percent, b ranges from 5 to 15 atomic percent, c ranges from 4 to 7.5 atomic percent, d comprises the balance, d.multidot.y is less than 10 atomic percent, and x/z ranges from 0.5 to 2.

  9. Method of forming crystalline silicon devices on glass

    DOE Patents [OSTI]

    McCarthy, A.M.

    1995-03-21

    A method is disclosed for fabricating single-crystal silicon microelectronic components on a silicon substrate and transferring same to a glass substrate. This is achieved by utilizing conventional silicon processing techniques for fabricating components of electronic circuits and devices on bulk silicon, wherein a bulk silicon surface is prepared with epitaxial layers prior to the conventional processing. The silicon substrate is bonded to a glass substrate and the bulk silicon is removed leaving the components intact on the glass substrate surface. Subsequent standard processing completes the device and circuit manufacturing. This invention is useful in applications requiring a transparent or insulating substrate, particularly for display manufacturing. Other applications include sensors, actuators, optoelectronics, radiation hard electronics, and high temperature electronics. 7 figures.

  10. Method of forming crystalline silicon devices on glass

    DOE Patents [OSTI]

    McCarthy, Anthony M.

    1995-01-01

    A method for fabricating single-crystal silicon microelectronic components on a silicon substrate and transferring same to a glass substrate. This is achieved by utilizing conventional silicon processing techniques for fabricating components of electronic circuits and devices on bulk silicon, wherein a bulk silicon surface is prepared with epitaxial layers prior to the conventional processing. The silicon substrate is bonded to a glass substrate and the bulk silicon is removed leaving the components intact on the glass substrate surface. Subsequent standard processing completes the device and circuit manufacturing. This invention is useful in applications requiring a transparent or insulating substrate, particularly for display manufacturing. Other applications include sensors, actuators, optoelectronics, radiation hard electronics, and high temperature electronics.

  11. Isuzu Glass Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Glass Co Ltd Jump to: navigation, search Name: Isuzu Glass Co Ltd Place: Osaka, Osaka, Japan Zip: 557-0063 Product: Japan-based manufacturer of glass products such as Fresnel lens...

  12. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, Carol Maryanne; Pickett, John Butler; Brown, Kevin George; Edwards, Thomas Barry

    1998-01-01

    A process for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, .DELTA.G.sub.p, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, .DELTA.G.sub.a, based upon the free energy associated with weak acid dissociation, .DELTA.G.sub.a.sup.WA, and accelerated matrix dissolution at high pH, .DELTA.G.sub.a.sup.SB associated with solution strong base formation, and determining a final hydration free energy, .DELTA.G.sub.f. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log.sub.10 (N C.sub.i (g/L))=a.sub.i +b.sub.i .DELTA.G.sub.f. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained.

  13. Holder for rotating glass body

    DOE Patents [OSTI]

    Kolleck, Floyd W.

    1978-04-04

    A device is provided for holding and centering a rotating glass body such as a rod or tube. The device includes a tubular tip holder which may be held in a lathe chuck. The device can utilize a variety of centering tips each adapted for a particular configuration, such as a glass O-ring joint or semi-ball joint.

  14. Method of determining glass durability

    DOE Patents [OSTI]

    Jantzen, C.M.; Pickett, J.B.; Brown, K.G.; Edwards, T.B.

    1998-12-08

    A process is described for determining one or more leachate concentrations of one or more components of a glass composition in an aqueous solution of the glass composition by identifying the components of the glass composition, including associated oxides, determining a preliminary glass dissolution estimator, {Delta}G{sub p}, based upon the free energies of hydration for the component reactant species, determining an accelerated glass dissolution function, {Delta}G{sub a}, based upon the free energy associated with weak acid dissociation, {Delta}G{sub a}{sup WA}, and accelerated matrix dissolution at high pH, {Delta}G{sub a}{sup SB} associated with solution strong base formation, and determining a final hydration free energy, {Delta}G{sub f}. This final hydration free energy is then used to determine leachate concentrations for elements of interest using a regression analysis and the formula log{sub 10}(N C{sub i}(g/L))=a{sub i} + b{sub i}{Delta}G{sub f}. The present invention also includes a method to determine whether a particular glass to be produced will be homogeneous or phase separated. The present invention is also directed to methods of monitoring and controlling processes for making glass using these determinations to modify the feedstock materials until a desired glass durability and homogeneity is obtained. 4 figs.

  15. Refractory Glass Seals for SOFC

    SciTech Connect (OSTI)

    Chou, Y. S.; Stevenson, Jeffry W.

    2011-07-01

    One of the critical challenges facing planar solid oxide fuel cell (SOFC) technology is the need for reliable sealing technology. Seals must exhibit long-term stability and mechanical integrity in the high temperature SOFC environment during normal and transient operation. Several different approaches for sealing SOFC stacks are under development, including glass or glass-ceramic seals, metallic brazes, and compressive seals. Among glass seals, rigid glass-ceramics, self-healing glass, and composite glass approaches have been investigated under the SECA Core Technology Program. The U.S. Department of Energy's Pacific Northwest National Laboratory (PNNL) has developed the refractory glass approach in light of the fact that higher sealing temperatures (e.g., 930-1000 degrees C) may enhance the ultimate in-service bulk strength and electrical conductivity of contact materials, as well as the bonding strength between contact materials and adjacent SOFC components, such as interconnect coatings and electrodes. This report summarizes the thermal, chemical, mechanical, and electrical properties of the refractory sealing glass.

  16. The BRAG and GM2003 Models for Glass Dissolution

    SciTech Connect (OSTI)

    Aertsens, Marc

    2007-07-01

    The GM2003 model extends the r(t) glass dissolution model with water diffusion through the diffusion layer. Boron and alkali diffusion through the diffusion layer is described by introducing a retention factor K{sub d,i} between boron/alkali and water in the diffusion layer. Introducing a boron/alkali diffusion coefficient, the BRAG model describes boron/alkali diffusion in the diffusion layer as well. It is shown that both models are consistent with each other and an expression is derived for the boron/alkali diffusion coefficient (BRAG) as a function of both parameters of GM2003: the retention factor K{sub d,i} and the water diffusion coefficient D{sub H{sub 2}}{sub O} in the diffusion layer. From dissolution data only, it is possible to fit the value for the boron/alkali diffusion coefficient in the diffusion layer but due to correlations the individual values of both parameters K{sub d,i} and DH{sub 2}O of GM2003 cannot be determined. From theoretical considerations follows that the K{sub d,i} value for boron/alkali should be slightly larger than 0.1 kg/liter. A user friendly code for the BRAG model allows automatic fits of glass dissolution data in water. (authors)

  17. Glass Ceramic Formulation Data Package

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Rodriguez, Carmen P.; McCloy, John S.; Vienna, John D.; Chung, Chul-Woo

    2012-06-17

    A glass ceramic waste form is being developed for treatment of secondary waste streams generated by aqueous reprocessing of commercial used nuclear fuel (Crum et al. 2012b). The waste stream contains a mixture of transition metals, alkali, alkaline earths, and lanthanides, several of which exceed the solubility limits of a single phase borosilicate glass (Crum et al. 2009; Caurant et al. 2007). A multi-phase glass ceramic waste form allows incorporation of insoluble components of the waste by designed crystallization into durable heat tolerant phases. The glass ceramic formulation and processing targets the formation of the following three stable crystalline phases: (1) powellite (XMoO4) where X can be (Ca, Sr, Ba, and/or Ln), (2) oxyapatite Yx,Z(10-x)Si6O26 where Y is alkaline earth, Z is Ln, and (3) lanthanide borosilicate (Ln5BSi2O13). These three phases incorporate the waste components that are above the solubility limit of a single-phase borosilicate glass. The glass ceramic is designed to be a single phase melt, just like a borosilicate glass, and then crystallize upon slow cooling to form the targeted phases. The slow cooling schedule is based on the centerline cooling profile of a 2 foot diameter canister such as the Hanford High-Level Waste canister. Up to this point, crucible testing has been used for glass ceramic development, with cold crucible induction melter (CCIM) targeted as the ultimate processing technology for the waste form. Idaho National Laboratory (INL) will conduct a scaled CCIM test in FY2012 with a glass ceramic to demonstrate the processing behavior. This Data Package documents the laboratory studies of the glass ceramic composition to support the CCIM test. Pacific Northwest National Laboratory (PNNL) measured melt viscosity, electrical conductivity, and crystallization behavior upon cooling to identify a processing window (temperature range) for melter operation and cooling profiles necessary to crystallize the targeted phases in the

  18. Lead phosphate glass compositions for optical components

    DOE Patents [OSTI]

    Sales, Brian C.; Boatner, Lynn A.

    1987-01-01

    A lead phosphate glass to which has been added indium oxide or scandium oe to improve chemical durability and provide a lead phosphate glass with good optical properties.

  19. ^Rhenium solubility in HLW glasses-05072012 (1)

    Office of Scientific and Technical Information (OSTI)

    into high-volume low-activity waste (LAW) and ... melts exhibited different physical and chemical features ... test method for measuring waste glass or glass ...

  20. Method for forming silicon on a glass substrate

    DOE Patents [OSTI]

    McCarthy, Anthony M.

    1995-01-01

    A method by which single-crystal silicon microelectronics may be fabricated on glass substrates at unconventionally low temperatures. This is achieved by fabricating a thin film of silicon on glass and subsequently forming the doped components by a short wavelength (excimer) laser doping procedure and conventional patterning techniques. This method may include introducing a heavily boron doped etch stop layer on a silicon wafer using an excimer laser, which permits good control of the etch stop layer removal process. This method additionally includes dramatically reducing the remaining surface roughness of the silicon thin films after etching in the fabrication of silicon on insulator wafers by scanning an excimer laser across the surface of the silicon thin film causing surface melting, whereby the surface tension of the melt causes smoothing of the surface during recrystallization. Applications for this method include those requiring a transparent or insulating substrate, such as display manufacturing. Other applications include sensors, actuators, optoelectronics, radiation hard and high temperature electronics.

  1. Flexible cadmium telluride thin films grown on electron-beam-irradiated graphene/thin glass substrates

    SciTech Connect (OSTI)

    Seo, Won-Oh; Kim, Jihyun; Koo, Yong Hwan; Kim, Byungnam; Lee, Byung Cheol; Kim, Donghwan

    2014-08-25

    We demonstrate the close-spaced sublimation growth of polycrystalline cadmium telluride (CdTe) thin films on a flexible graphene electrode/thin glass substrate structure. Prior to the growth of CdTe films, chemical-vapor-deposited graphene was transferred onto a flexible glass substrate and subjected to electron-beam irradiation at an energy of 0.2 MeV in order to intentionally introduce the defects into it in a controlled manner. Micro-Raman spectroscopy and sheet resistance measurements were employed to monitor the damage and disorder in the electron-beam irradiated graphene layers. The morphology and optical properties of the CdTe thin films deposited on a graphene/flexible glass substrate were systematically characterized. The integration of the defective graphene layers with a flexible glass substrate can be a useful platform to grow various thin-film structures for flexible electronic and optoelectronic devices.

  2. Progress toward bridging from atomistic to continuum modeling to predict nuclear waste glass dissolution.

    SciTech Connect (OSTI)

    Zapol, Peter; Bourg, Ian; Criscenti, Louise Jacqueline; Steefel, Carl I.; Schultz, Peter Andrew

    2011-10-01

    This report summarizes research performed for the Nuclear Energy Advanced Modeling and Simulation (NEAMS) Subcontinuum and Upscaling Task. The work conducted focused on developing a roadmap to include molecular scale, mechanistic information in continuum-scale models of nuclear waste glass dissolution. This information is derived from molecular-scale modeling efforts that are validated through comparison with experimental data. In addition to developing a master plan to incorporate a subcontinuum mechanistic understanding of glass dissolution into continuum models, methods were developed to generate constitutive dissolution rate expressions from quantum calculations, force field models were selected to generate multicomponent glass structures and gel layers, classical molecular modeling was used to study diffusion through nanopores analogous to those in the interfacial gel layer, and a micro-continuum model (K{mu}C) was developed to study coupled diffusion and reaction at the glass-gel-solution interface.

  3. Glass ceramic seals to inconel

    DOE Patents [OSTI]

    McCollister, Howard L.; Reed, Scott T.

    1983-11-08

    A glass ceramic composition prepared by subjecting a glass composition comprising, by weight, 65-80% SiO.sub.2, 8-16%, Li.sub.2 O, 2-8% , Al.sub.2 O.sub.3, 1-8% K.sub.2 O, 1-5% P.sub.2 O.sub.5 and 1.5-7% B.sub.2 O.sub.3, to the following processing steps of heating the glass composition to a temperature sufficient to crystallize lithium metasilicate therein, holding the glass composition at a temperature and for a time period sufficient to dissolve the lithium metasilicate therein thereby creating cristobalite nucleii, cooling the glass composition and maintaining the composition at a temperature and for a time period sufficient to recrystallize lithium metasilicate therein, and thermally treating the glass composition at a temperature and for a time period sufficient to cause growth of cristobalite and further crystallization of lithium metasilicate producing a glass ceramic composition having a specific thermal expansion coefficient and products containing said composition.

  4. Method for manufacturing glass frit

    DOE Patents [OSTI]

    Budrick, Ronald G.; King, Frank T.; Nolen, Jr., Robert L.; Solomon, David E.

    1977-01-01

    A method of manufacturing a glass frit for use in the manufacture of uniform glass microspheres to serve as containers for laser fusion fuel to be exposed to laser energy which includes the formation of a glass gel which is then dried, pulverized, and very accurately sized to particles in a range of, for example, 125 to 149 micrometers. The particles contain an occluded material such as urea which expands when heated. The sized particles are washed, dried, and subjected to heat to control the moisture content prior to being introduced into a system to form microspheres.

  5. Multi-layer micro/nanofluid devices with bio-nanovalves

    DOE Patents [OSTI]

    Li, Hao; Ocola, Leonidas E.; Auciello, Orlando H.; Firestone, Millicent A.

    2013-01-01

    A user-friendly multi-layer micro/nanofluidic flow device and micro/nano fabrication process are provided for numerous uses. The multi-layer micro/nanofluidic flow device can comprise: a substrate, such as indium tin oxide coated glass (ITO glass); a conductive layer of ferroelectric material, preferably comprising a PZT layer of lead zirconate titanate (PZT) positioned on the substrate; electrodes connected to the conductive layer; a nanofluidics layer positioned on the conductive layer and defining nanochannels; a microfluidics layer positioned upon the nanofluidics layer and defining microchannels; and biomolecular nanovalves providing bio-nanovalves which are moveable from a closed position to an open position to control fluid flow at a nanoscale.

  6. Crystal-Tolerant Glass Approach For Mitigation Of Crystal Accumulation In Continuous Melters Processing Radioactive Waste

    SciTech Connect (OSTI)

    Kruger, Albert A.; Rodriguez, Carmen P.; Lang, Jesse B.; Huckleberry, Adam R.; Matyas, Josef; Owen, Antoinette T.

    2012-08-28

    High-level radioactive waste melters are projected to operate in an inefficient manner as they are subjected to artificial constraints, such as minimum liquidus temperature (T{sub L}) or maximum equilibrium fraction of crystallinity at a given temperature. These constraints substantially limit waste loading, but were imposed to prevent clogging of the melter with spinel crystals [(Fe, Ni, Mn, Zn)(Fe, Cr){sub 2}O{sub 4}]. In the melter, the glass discharge riser is the most likely location for crystal accumulation during idling because of low glass temperatures, stagnant melts, and small diameter. To address this problem, a series of lab-scale crucible tests were performed with specially formulated glasses to simulate accumulation of spinel in the riser. Thicknesses of accumulated layers were incorporated into empirical model of spinel settling. In addition, T{sub L} of glasses was measured and impact of particle agglomeration on accumulation rate was evaluated. Empirical model predicted well the accumulation of single crystals and/or smallscale agglomerates, but, excessive agglomeration observed in high-Ni-Fe glass resulted in an under-prediction of accumulated layers, which gradually worsen over time as an increased number of agglomerates formed. Accumulation rate of ~14.9 +- 1 nm/s determined for this glass will result in ~26 mm thick layer in 20 days of melter idling.

  7. Turning nuclear waste into glass

    SciTech Connect (OSTI)

    Pegg, Ian L.

    2015-02-15

    Vitrification has emerged as the treatment option of choice for the most dangerous radioactive waste. But dealing with the nuclear waste legacy of the Cold War will require state-of-the-art facilities and advanced glass formulations.

  8. Glass Furnace Model Version 2

    Energy Science and Technology Software Center (OSTI)

    2003-05-06

    GFM2.0 is a derivative of the GFM code with substantially altered and enhanced capabilities. Like its predecessor, it is a fully three-dimensional, furnace simulation model that provides a more accurate representation of the entire furnace, and specifically, the glass melting process, by coupling the combustion space directly to the glass batch and glass melt via rigorous radiation heat transport models for both the combustion space and the glass melt. No assumptions are made with regardmore » to interfacial parameters of heat, flux, temperature distribution, and batch coverage as must be done using other applicable codes available. These critical parameters are calculated. GFM2.0 contains a processor structured to facilitate use of the code, including the entry of teh furnace geometry and operating conditions, the execution of the program, and display of the computational results. Furnace simulations can therefore be created in a straightforward manner.« less

  9. BNFL Report Glass Formers Characterization

    SciTech Connect (OSTI)

    Schumacher, R.F.

    2000-07-27

    The objective of this task was to obtain powder property data on candidate glass former materials, sufficient to guide conceptual design and estimate the cost of glass former handling facilities as requested under Part B1 of BNFL Technical and Development Support. Twenty-nine glass forming materials were selected and obtained from vendors for the characterization of their physical properties, durability in caustic solution, and powder flow characteristics. A glass former was selected based on the characterization for each of the ten oxide classes required for Envelope A, B, and C mixtures. Three blends (A, B, and C) were prepared based on formulations provided by Vitreous State Laboratory and evaluated with the same methods employed for the glass formers. The properties obtained are presented in a series of attached Tables. It was determined that five of the ten glass formers, (kyanite, iron oxide, titania, zircon, and zinc oxide) have the potential to cause some level of solids f low problems. The problems might include arching or ratholing in the silo/hopper. In addition, all of the blends may require consideration for their handling.

  10. BNFL Report Glass Formers Characterization

    SciTech Connect (OSTI)

    Schumacher, R.F.

    2000-07-27

    The objective of this task was to obtain powder property data on candidate glass former materials, sufficient to guide conceptual design and estimate the cost of glass former handling facilities as requested under Part B1 of BNFL Technical and Development Support. Twenty-nine glass forming materials were selected and obtained from vendors for the characterization of their physical properties, durability in caustic solution, and powder flow characteristics. A glass former was selected based on the characterization for each of the ten oxide classes required for Envelope A, B, and C mixtures. Three blends (A, B, and C) were prepared based on formulations provided by Vitreous State Laboratory and evaluated with the same methods employed for the glass formers. The properties obtained are presented in a series of attached Tables. It was determined that five of the ten glass formers, (kyanite, iron oxide, titania, zircon, and zinc oxide) have the potential to cause some level of solids f low problems. In addition, all of the blends may require consideration for their handling. A number of engineering considerations and recommendations were prepared based on the experimental findings, experience, and other process considerations. Recommendations for future testing are included. In conjunction with future work, it is recommended that a professional consultant be engaged to guide and assist with testing and design input.

  11. Conversion of Nuclear Waste into Nuclear Waste Glass: Experimental Investigation and Mathematical Modeling

    SciTech Connect (OSTI)

    Hrma, Pavel

    2014-12-18

    The melter feed, slurry, or calcine charged on the top of a pool of molten glass forms a floating layer of reacting material called the cold cap. Between the cold-cap top, which is covered with boiling slurry, and its bottom, where bubbles separate it from molten glass, the temperature changes by up to 1000 K. The processes that occur over this temperature interval within the cold cap include liberation of gases, conduction and consumption of heat, dissolution of quartz particles, formation and dissolution of intermediate crystalline phases, and generation of foam and gas cavities. These processes have been investigated using thermal analyses, optical and electronic microscopies, x-ray diffraction, as well as other techniques. Properties of the reacting feed, such as heat conductivity and density, were measured as functions of temperature. Investigating the structure of quenched cold caps produced in a laboratory-scale melter complemented the crucible studies. The cold cap consists of two main layers. The top layer contains solid particles dissolving in the glass-forming melt and open pores through which gases are escaping. The bottom layer contains bubbly melt or foam where bubbles coalesce into larger cavities that move sideways and release the gas to the atmosphere. The feed-to-glass conversion became sufficiently understood for representing the cold-cap processes via mathematical models. These models, which comprise heat transfer, mass transfer, and reaction kinetics models, have been developed with the final goal to relate feed parameters to the rate of glass melting.

  12. Glass Membrane For Controlled Diffusion Of Gases

    DOE Patents [OSTI]

    Shelby, James E.; Kenyon, Brian E.

    2001-05-15

    A glass structure for controlled permeability of gases includes a glass vessel. The glass vessel has walls and a hollow center for receiving a gas. The glass vessel contains a metal oxide dopant formed with at least one metal selected from the group consisting of transition metals and rare earth metals for controlling diffusion of the gas through the walls of the glass vessel. The vessel releases the gas through its walls upon exposure to a radiation source.

  13. Fabrication of glass microspheres with conducting surfaces

    DOE Patents [OSTI]

    Elsholz, William E.

    1984-01-01

    A method for making hollow glass microspheres with conducting surfaces by adding a conducting vapor to a region of the glass fabrication furnace. As droplets or particles of glass forming material pass through multiple zones of different temperature in a glass fabrication furnace, and are transformed into hollow glass microspheres, the microspheres pass through a region of conducting vapor, forming a conducting coating on the surface of the microspheres.

  14. Fabrication of glass microspheres with conducting surfaces

    DOE Patents [OSTI]

    Elsholz, W.E.

    1982-09-30

    A method for making hollow glass microspheres with conducting surfaces by adding a conducting vapor to a region of the glass fabrication furnace. As droplets or particles of glass forming material pass through multiple zones of different temperature in a glass fabrication furnace, and are transformed into hollow glass microspheres, the microspheres pass through a region of conducting vapor, forming a conducting coating on the surface of the microspheres.

  15. HIGH-LEVEL WASTE GLASS FORMULATION MODEL SENSITIVITY STUDY 2009 GLASS FORMULATION MODEL VERSUS 1996 GLASS FORMULATION MODEL

    SciTech Connect (OSTI)

    BELSHER JD; MEINERT FL

    2009-12-07

    This document presents the differences between two HLW glass formulation models (GFM): The 1996 GFM and 2009 GFM. A glass formulation model is a collection of glass property correlations and associated limits, as well as model validity and solubility constraints; it uses the pretreated HLW feed composition to predict the amount and composition of glass forming additives necessary to produce acceptable HLW glass. The 2009 GFM presented in this report was constructed as a nonlinear optimization calculation based on updated glass property data and solubility limits described in PNNL-18501 (2009). Key mission drivers such as the total mass of HLW glass and waste oxide loading are compared between the two glass formulation models. In addition, a sensitivity study was performed within the 2009 GFM to determine the effect of relaxing various constraints on the predicted mass of the HLW glass.

  16. Weihai Blue Star Glass Holding Co Ltd aka Shandong Lanxing Glass...

    Open Energy Info (EERE)

    aka Shandong Lanxing Glass Group Co Ltd Jump to: navigation, search Name: Weihai Blue Star Glass Holding Co Ltd (aka Shandong Lanxing Glass Group Co Ltd) Place: Weihai City,...

  17. Alternate protection concepts for second surface silver/glass solar mirrors

    SciTech Connect (OSTI)

    Buckwalter, C.Q.; Dake, L.S.; Hartman, J.S.; Lind, M.A.

    1980-10-01

    Investigations into three technologies having the potential of significantly enhancing the durability of solar mirrors are reported. The approaches are based on the assumption that sealing the silver layer on second surface mirrors from the external environment with protective overcoats will significantly extend their useful service life. Considered are: (1) edge sealing a second sheet of glass over the silver layer using solder glasses, (2) overcoating the silver layer with liquid applied SiO/sub 2/ or TiO/sub 2/ coatings, and (3) overcoating the silver layer with an electroless nickel film. Preliminary experiments were performed using Sb/sub 2/O/sub 5/-K/sub 2/O and PbO based solder glasses to edge seal a second sheet of glass over the silver mirror surface. Problems encountered in the formulation of the Sb/sub 2/O/sub 5/-K/sub 2/O glasses forced abandonment of these low melting point solder glass experiments. Materials compatibility problems were encountered when using several of the commercially available PbO based solder glasses alternatives. A cursory evaluation of liquid SiO/sub 2/ and TiO/sub 2/ coatings was also undertaken. The films were applied as direct overcoats on both silver only and silver/copper mirror substrates. Although the process appeared to yield visually acceptable coatings, under microscopic examination the films were found to be porous and pinhole riddled after the final curing step. Consequently, they did not stand up well to salt spray and HCl vapor tests. Background data were collected in an investigation of overcoating the silver or silver/copper mirrors with an electroless deposited nickel film. Two formulations, one a basic solution, the other a commercial acidic solution, were attempted. Film integrity problems were encountered for fairly thick films in the feasibility experiments attempted. Nevertheless, the concept appears sound and merits further investigation.

  18. Modeling Interfacial Glass-Water Reactions: Recent Advances and Current Limitations

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pierce, Eric M.; Frugier, Pierre; Criscenti, Louise J.; Kwon, Kideok D.; Kerisit, Sebastien N.

    2014-07-12

    Describing the reactions that occur at the glass-water interface and control the development of the altered layer constitutes one of the main scientific challenges impeding existing models from providing accurate radionuclide release estimates. Radionuclide release estimates are a critical component of the safety basis for geologic repositories. The altered layer (i.e., amorphous hydrated surface layer and crystalline reaction products) represents a complex region, both physically and chemically, sandwiched between two distinct boundaries pristine glass surface at the inner most interface and aqueous solution at the outer most interface. Computational models, spanning different length and time-scales, are currently being developed tomore » improve our understanding of this complex and dynamic process with the goal of accurately describing the pore-scale changes that occur as the system evolves. These modeling approaches include geochemical simulations [i.e., classical reaction path simulations and glass reactivity in allowance for alteration layer (GRAAL) simulations], Monte Carlo simulations, and Molecular Dynamics methods. Finally, in this manuscript, we discuss the advances and limitations of each modeling approach placed in the context of the glass-water reaction and how collectively these approaches provide insights into the mechanisms that control the formation and evolution of altered layers.« less

  19. Surface plasmon resonance assisted rapid laser joining of glass

    SciTech Connect (OSTI)

    Zolotovskaya, Svetlana A.; Tang, Guang; Abdolvand, Amin, E-mail: a.abdolvand@dundee.ac.uk [School of Engineering, Physics and Mathematics, University of Dundee, Dundee DD1 4HN (United Kingdom); Wang, Zengbo [School of Electronic Engineering, Bangor University, Bangor LL57 1UT (United Kingdom)

    2014-08-25

    Rapid and strong joining of clear glass to glass containing randomly distributed embedded spherical silver nanoparticles upon nanosecond pulsed laser irradiation (?40?ns and repetition rate of 100?kHz) at 532?nm is demonstrated. The embedded silver nanoparticles were ?3040?nm in diameter, contained in a thin surface layer of ?10??m. A joint strength of 12.5?MPa was achieved for a laser fluence of only ?0.13?J/cm{sup 2} and scanning speed of 10?mm/s. The bonding mechanism is discussed in terms of absorption of the laser energy by nanoparticles and the transfer of the accumulated localised heat to the surrounding glass leading to the local melting and formation of a strong bond. The presented technique is scalable and overcomes a number of serious challenges for a widespread adoption of laser-assisted rapid joining of glass substrates, enabling applications in the manufacture of microelectronic devices, sensors, micro-fluidic, and medical devices.

  20. HLW Glass Studies: Development of Crystal-Tolerant HLW Glasses

    SciTech Connect (OSTI)

    Matyas, Josef; Huckleberry, Adam R.; Rodriguez, Carmen P.; Lang, Jesse B.; Owen, Antionette T.; Kruger, Albert A.

    2012-04-02

    In our study, a series of lab-scale crucible tests were performed on designed glasses of different compositions to further investigate and simulate the effect of Cr, Ni, Fe, Al, Li, and RuO2 on the accumulation rate of spinel crystals in the glass discharge riser of the HLW melter. The experimental data were used to expand the compositional region covered by an empirical model developed previously (Maty et al. 2010b), improving its predictive performance. We also investigated the mechanism for agglomeration of particles and impact of agglomerates on accumulation rate. In addition, the TL was measured as a function of temperature and composition.

  1. Bengbu Sanxin Solar Photovoltaic Glass Co Ltd | Open Energy Informatio...

    Open Energy Info (EERE)

    Bengbu Sanxin Solar Photovoltaic Glass Co Ltd Jump to: navigation, search Name: Bengbu Sanxin Solar Photovoltaic Glass Co Ltd Place: Bengbu, Anhui Province, China Product: Glass...

  2. Mineralogical textural and compositional data on the alteration of basaltic glass from Kilauea, Hawaii to 300 degrees C: Insights to the corrosion of a borosilicate glass waste-form. [Yucca Mountain Project

    SciTech Connect (OSTI)

    Smith, D.K.

    1990-01-01

    Mineralogical, textural and compositional data accompanying greenschist facies metamorphism (to 300{degrees}C) of basalts of the East Rift Zone (ERZ), Kilauea, Hawaii may be evaluated relative to published and experimental results for the surface corrosion of borosilicate glass. The ERZ alteration sequence is dominated by intermittent palagonite, interlayered smectite-chlorite, chlorite, and actinolite-epidote-anhydrite. Alteration is best developed in fractures and vesicles where surface reaction layers root on the glass matrix forming rinds in excess of 100 microns thick. Fractures control fluid circulation and the alteration sequence. Proximal to the glass surface, palagonite, Fe-Ti oxides and clays replace fresh glass as the surface reaction layer migrates inwards; away from the surface, amphibole, anhydrite, quartz and calcite crystallize from hydrothermal fluids in contact with the glass. The texture and composition of basaltic glass surfaces are similar to those of a SRL-165 glass leached statically for sixty days at 150 {degrees}C. While the ERZ reservoir is a complex open system, conservative comparisons between the alteration of ERZ and synthetic borosilicate glass are warranted. 31 refs., 2 figs.

  3. Characteristics of colloids generated during the corrosion of nuclear waste glasses in groundwater

    SciTech Connect (OSTI)

    Feng, X.; Buck, E.C.; Mertz, C.; Bates, J.K.; Cunnane, J.C.; Chaiko, D.

    1993-10-01

    Aqueous colloidal suspensions were generated by reacting nuclear waste glasses with groundwater at 90{degrees}C at different ratios of the glass surface area to solution volume (S/V). The colloids have been characterized in terms of size, charge, identity, and stability with respect to salt concentration, pH, and time, by examination using dynamic light scattering, electrophoretic mobility, and transmission electron microscopy. The colloids are predominately produced by precipitation from solution, possibly with contribution from reacted layers that have spallated from the glass. These colloids are silicon-rich minerals. The colloidal suspensions agglomerate when the salinity of the solutions increase. The following implications for modeling the colloidal transport of contaminants have been derived from this study: (1) The sources of the colloids are not only solubility-limited real colloids and the pseudo colloids formed by adsorption of radionuclides onto a groundwater colloid, but also from the spalled surface layers of reacted waste glasses. (2) In a repository, the local environment is likely to be glass-reaction dominated and the salt concentration is likely to be high, leading to rapid colloid agglomeration and settling; thus, colloid transport may be insignificant. (3) If large volumes of groundwater contact the glass reaction site, the precipitated colloids may become resuspended, and colloid transport may become important. (4) Under most conditions, the colloids are negatively charged and will deposit readily on positively charged surfaces. Negatively charged surfaces will, in general, facilitate colloid stability and transport.

  4. Method for fabricating transistors using crystalline silicon devices on glass

    DOE Patents [OSTI]

    McCarthy, A.M.

    1997-09-02

    A method for fabricating transistors using single-crystal silicon devices on glass. This method overcomes the potential damage that may be caused to the device during high voltage bonding and employs a metal layer which may be incorporated as part of the transistor. This is accomplished such that when the bonding of the silicon wafer or substrate to the glass substrate is performed, the voltage and current pass through areas where transistors will not be fabricated. After removal of the silicon substrate, further metal may be deposited to form electrical contact or add functionality to the devices. By this method both single and gate-all-around devices may be formed. 13 figs.

  5. Advances in Glass Chemistry - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Structural and Chemical Incorporation of ReO4- and TcO4- in Borosilicate Glasses Submitted for publication the Journal of Raman Spectroscopy Iron phosphate glass for immobilization ...

  6. Measurement and Control of Glass Feedstocks

    SciTech Connect (OSTI)

    2005-08-01

    Laser-induced breakdown spectroscopy (LIBS) promises a new way for glass manufacturers to significantly increase productivity. By measuring the chemical makeup in raw materials and recycled glass cullet, LIBS can quickly detect contaminants and batch non...

  7. Energy-Efficient Glass Melting: Submerged Combustion

    SciTech Connect (OSTI)

    2004-01-01

    Oxy-gas-fired submerged combustion melter offers simpler, improved performance. For the last 100 years, the domestic glass industry has used the same basic equipment for melting glass on an industrial scale.

  8. Heating-induced glass-glass and glass-liquid transformations in computer simulations of water

    SciTech Connect (OSTI)

    Chiu, Janet; Giovambattista, Nicolas; Starr, Francis W.

    2014-03-21

    Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T “phase diagram” for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related

  9. Low-temperature lithium diffusion in simulated high-level boroaluminosilicate nuclear waste glasses

    SciTech Connect (OSTI)

    Neeway, James J.; Kerisit, Sebastien N.; Gin, Stephane; Wang, Zhaoying; Zhu, Zihua; Ryan, Joseph V.

    2014-12-01

    Ion exchange is recognized as an integral, if underrepresented, mechanism influencing glass corrosion. However, due to the formation of various alteration layers in the presence of water, it is difficult to conclusively deconvolute the mechanisms of ion exchange from other processes occurring simultaneously during corrosion. In this work, an operationally inert non-aqueous solution was used as an alkali source material to isolate ion exchange and study the solid-state diffusion of lithium. Specifically, the experiments involved contacting glass coupons relevant to the immobilization of high-level nuclear waste, SON68 and CJ-6, which contained Li in natural isotope abundance, with a non-aqueous solution of 6LiCl dissolved in dimethyl sulfoxide at 90 C for various time periods. The depth profiles of major elements in the glass coupons were measured using time-of-flight secondary ion mass spectrometry (ToF-SIMS). Lithium interdiffusion coefficients, DLi, were then calculated based on the measured depth profiles. The results indicate that the penetration of 6Li is rapid in both glasses with the simplified CJ-6 glass (D6Li ? 4.0-8.0 10-21 m2/s) exhibiting faster exchange than the more complex SON68 glass (DLi ? 2.0-4.0 10-21 m2/s). Additionally, sodium ions present in the glass were observed to participate in ion exchange reactions; however, different diffusion coefficients were necessary to fit the diffusion profiles of the two alkali ions. Implications of the diffusion coefficients obtained in the absence of alteration layers to the long-term performance of nuclear waste glasses in a geological repository system are also discussed.

  10. Ionic Transport Across Interfaces of Solid Glass and Polymer Electrolytes

    SciTech Connect (OSTI)

    Tenhaeff, Wyatt E; Yu, Xiang; Hong, Kunlun; Perry, Kelly A; Dudney, Nancy J

    2011-01-01

    A study of lithium cation transport across solid-solid electrolyte interfaces to identify critical resistances in nanostructured solid electrolytes is reported. Bilayers of glass and polymer thin film electrolytes were fabricated and characterized for this study. The glass electrolyte was lithium phosphorous oxynitride (Lipon), and two polymer electrolytes were studied: poly(methyl methacrylate-co-poly(ethylene glycol) methyl ether methacrylate) and poly(styrene-co-poly(ethylene glycol) methyl ether methacrylate). Both copolymers contained LiClO{sub 4} salt. In bilayers where polymer electrolyte layers are fabricated on top of Lipon, the interfacial resistance dominates transport. At 25 C, the interfacial resistance is at least three times greater than the sum of the Lipon and polymer electrolyte resistances. By reversing the structure and fabricating Lipon on top of the polymer electrolytes, the interfacial resistance is eliminated. Experiments to elucidate the origin of the interfacial resistance in the polymer-on-Lipon bilayers reveal that the solvent mixtures used to fabricate the polymer layers do not degrade the Lipon layer. The importance of the polymer electrolytes' mechanical properties is also discussed.

  11. Glass needs for a growing photovoltaics industry

    SciTech Connect (OSTI)

    Burrows, Keith; Fthenakis, Vasilis

    2014-10-18

    With the projected growth in photovoltaics, the demand for glass for the solar industry will far exceed the current supply, and thousands of new float-glass plants will have to be built to meet its needs over the next 20 years. Such expansion will provide an opportunity for the solar industry to obtain products better suited to their needs, such as low-iron glass and borosilicate glass at the lowest possible price. While there are no significant technological hurdles that would prevent the flat glass industry from meeting the solar industry’s projected needs, to do so will require advance planning and substantial investments.

  12. Glass needs for a growing photovoltaics industry

    SciTech Connect (OSTI)

    Burrows, Keith; Fthenakis, Vasilis

    2015-01-01

    With the projected growth in photovoltaics, the demand for glass for the solar industry will far exceed the current supply, and thousands of new float-glass plants will have to be built to meet its needs over the next 20 years. Such expansion will provide an opportunity for the solar industry to obtain products better suited to their needs, such as low-iron glass and borosilicate glass at the lowest possible price. While there are no significant technological hurdles that would prevent the flat glass industry from meeting the solar industrys projected needs, to do so will require advance planning and substantial investments.

  13. Methods of making metallic glass foil laminate composites

    DOE Patents [OSTI]

    Vianco, Paul T.; Fisher, Robert W.; Hosking, Floyd M.; Zanner, Frank J.

    1996-01-01

    A process for the fabrication of a rapidly solidified foil laminate composite. An amorphous metallic glass foil is flux treated and coated with solder. Before solidification of the solder the foil is collected on a take-up spool which forms the composite into a solid annular configuration. The resulting composite exhibits high strength, resiliency and favorable magnetic and electrical properties associated with amorphous materials. The composite also exhibits bonding strength between the foil layers which significantly exceeds the bulk strength of the solder alone.

  14. Methods of making metallic glass foil laminate composites

    DOE Patents [OSTI]

    Vianco, P.T.; Fisher, R.W.; Hosking, F.M.; Zanner, F.J.

    1996-08-20

    A process for the fabrication of a rapidly solidified foil laminate composite. An amorphous metallic glass foil is flux treated and coated with solder. Before solidification of the solder the foil is collected on a take-up spool which forms the composite into a solid annular configuration. The resulting composite exhibits high strength, resiliency and favorable magnetic and electrical properties associated with amorphous materials. The composite also exhibits bonding strength between the foil layers which significantly exceeds the bulk strength of the solder alone. 6 figs.

  15. Recirculation bubbler for glass melter apparatus

    DOE Patents [OSTI]

    Guerrero, Hector (Evans, GA); Bickford, Dennis (Folly Beach, SC)

    2007-06-05

    A gas bubbler device provides enhanced recirculation of molten glass within a glass melter apparatus. The bubbler device includes a tube member disposed within a pool of molten glass contained in the melter. The tube member includes a lower opening through which the molten glass enters and upper slots disposed close to (above or below) the upper surface of the pool of molten glass and from which the glass exits. A gas (air) line is disposed within the tube member and extends longitudinally thereof. A gas bubble distribution device, which is located adjacent to the lower end of the tube member and is connected to the lower end of the gas line, releases gas through openings therein so as to produce gas bubbles of a desired size in the molten glass and in a distributed pattern across the tube member.

  16. Pressurized heat treatment of glass ceramic

    DOE Patents [OSTI]

    Kramer, D.P.

    1984-04-19

    A method of producing a glass-ceramic having a specified thermal expansion value is disclosed. The method includes the step of pressurizing the parent glass material to a predetermined pressure during heat treatment so that the glass-ceramic produced has a specified thermal expansion value. Preferably, the glass-ceramic material is isostatically pressed. A method for forming a strong glass-ceramic to metal seal is also disclosed in which the glass-ceramic is fabricated to have a thermal expansion value equal to that of the metal. The determination of the thermal expansion value of a parent glass material placed in a high-temperature environment is also used to determine the pressure in the environment.

  17. Lid heater for glass melter

    DOE Patents [OSTI]

    Phillips, T.D.

    1993-12-14

    A glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes. 3 figures.

  18. Lid heater for glass melter

    DOE Patents [OSTI]

    Phillips, Terrance D.

    1993-01-01

    A glass melter having a lid electrode for heating the glass melt radiantly. The electrode comprises a series of INCONEL 690 tubes running above the melt across the melter interior and through the melter walls and having nickel cores inside the tubes beginning where the tubes leave the melter interior and nickel connectors to connect the tubes electrically in series. An applied voltage causes the tubes to generate heat of electrical resistance for melting frit injected onto the melt. The cores limit heat generated as the current passes through the walls of the melter. Nickel bus connection to the electrical power supply minimizes heat transfer away from the melter that would occur if standard copper or water-cooled copper connections were used between the supply and the INCONEL 690 heating tubes.

  19. Melter Glass Removal and Dismantlement

    SciTech Connect (OSTI)

    Richardson, BS

    2000-10-31

    The U.S. Department of Energy (DOE) has been using vitrification processes to convert high-level radioactive waste forms into a stable glass for disposal in waste repositories. Vitrification facilities at the Savannah River Site (SRS) and at the West Valley Demonstration Project (WVDP) are converting liquid high-level waste (HLW) by combining it with a glass-forming media to form a borosilicate glass, which will ensure safe long-term storage. Large, slurry fed melters, which are used for this process, were anticipated to have a finite life (on the order of two to three years) at which time they would have to be replaced using remote methods because of the high radiation fields. In actuality the melters useable life spans have, to date, exceeded original life-span estimates. Initial plans called for the removal of failed melters by placing the melter assembly into a container and storing the assembly in a concrete vault on the vitrification plant site pending size-reduction, segregation, containerization, and shipment to appropriate storage facilities. Separate facilities for the processing of the failed melters currently do not exist. Options for handling these melters include (1) locating a facility to conduct the size-reduction, characterization, and containerization as originally planned; (2) long-term storing or disposing of the complete melter assembly; and (3) attempting to refurbish the melter and to reuse the melter assembly. The focus of this report is to look at methods and issues pertinent to size-reduction and/or melter refurbishment in particular, removing the glass as a part of a refurbishment or to reduce contamination levels (thus allowing for disposal of a greater proportion of the melter as low level waste).

  20. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    SciTech Connect (OSTI)

    Shawn M. Allan; Patricia M. Strickland; Holly S. Shulman

    2009-11-11

    Ceralink Inc. developed FastFuse, a rapid, new, energy saving process for lamination of glass and composites using radio frequency (RF) heating technology. The Inventions and Innovations program supported the technical and commercial research and development needed to elevate the innovation from bench scale to a self-supporting technology with significant potential for growth. The attached report provides an overview of the technical and commerical progress achieved for FastFuse during the course of the project. FastFuse has the potential to revolutionize the laminate manufacturing industries by replacing energy intensive, multi-step processes with an energy efficient, single-step process that allows higher throughput. FastFuse transmits RF energy directly into the interlayer to generate heat, eliminating the need to directly heat glass layers and the surrounding enclosures, such as autoclaves or vacuum systems. FastFuse offers lower start-up and energy costs (up to 90% or more reduction in energy costs), and faster cycles times (less than 5 minutes). FastFuse is compatible with EVA, TPU, and PVB interlayers, and has been demonstrated for glass, plastics, and multi-material structures such as photovoltaics and transparent armor.

  1. Chemical bath deposition of cadmium sulfide on graphene-coated flexible glass substrate

    SciTech Connect (OSTI)

    Seo, Won-Oh; Jung, Younghun; Kim, Jihyun, E-mail: hyunhyun7@korea.ac.kr [Department of Chemical and Biological Engineering, Korea University, Anam-dong, Sungbuk-gu, Seoul 136-713 (Korea, Republic of); Kim, Jiwan [Flexible Display Research Center, Korea Electronics Technology Institute, Yatap-dong, Bundang-gu, Seongnam-si, Gyeonggi-do 463-816 (Korea, Republic of); Kim, Donghwan [Department of Materials Science and Engineering, Korea University, Seoul 136-701 (Korea, Republic of)

    2014-03-31

    We demonstrate a flexible structure of cadmium sulfide (CdS) on graphene-coated glass substrate, where CdS was deposited by the chemical bath deposition method on defective tri-layer graphene. The defects in graphene, confirmed by micro-Raman spectroscopy, were created by a ultra-violet treatment with varying exposure time from 10 to 60?min. The number of defect sites in the graphene as a seed layer was related to the quality of the CdS thin films determined from the results from X-ray diffraction, optical transmittance, scanning electron microscopy, and room temperature micro-photoluminescence. Our film-on-substrate structure of CdS-graphene-on-glass was maintained up to a tensile strain of 0.3%, where graphene with a high failure strain was employed as a transparent conductive layer.

  2. Manufacturing laser glass by continuous melting

    SciTech Connect (OSTI)

    Campbell, J H; Suratwala, T; krenitsky, S; Takeuchi, K

    2000-07-01

    A novel, continuous melting process is being used to manufacture meter-sized plates of laser glass at a rate 20-times faster, 5-times cheaper, and with 2-3 times better optical quality than with previous one-at-a-time, ''discontinuous'' technology processes. This new technology for manufacturing laser glass, which is arguably the most difficult continuously-melted optical material ever produced, comes as a result of a $60 million, six-year joint R&D program between government and industry. The glasses manufactured by the new continuous melting process are Nd-doped phosphate-based glasses and are marketed under the product names LG-770 (Schott Glass Technologies) and LHG-8 (Hoya Corporation USA). With this advance in glass manufacturing technology, it is now possible to construct high-energy, high-peak-power lasers for use in fusion energy development, national defense, and basic physics research that would have been impractical to build using the old melting technology. The development of continuously melted laser glass required technological advances that have lead to improvements in the manufacture of other optical glass products as well. For example, advances in forming, annealing, and conditioning steps of the laser glass continuous melting process are now being used in manufacture of other large-size optical glasses.

  3. Creep Behavior of Glass/Ceramic Sealant and its Effect on Long-term Performance of Solid Oxide Fuel Cells

    SciTech Connect (OSTI)

    Liu, Wenning N.; Sun, Xin; Koeppel, Brian J.; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2009-10-14

    The creep behavior of glass or glass-ceramic sealant materials used in solid oxide fuel cells (SOFCs) becomes relevant under SOFC operating temperatures. In this paper, the creep of glass-ceramic sealants was experimentally examined, and a standard linear solid model was applied to capture the creep behavior of glass ceramic sealant materials developed for planar SOFCs at high temperatures. The parameters of this model were determined based on the creep test results. Furthermore, the creep model was incorporated into finite-element software programs SOFC-MP and Mentat-FC developed at Pacific Northwest National Laboratory for multi-physics simulation of SOFCs. The effect of creep of glass ceramic sealant materials on the long-term performance of SOFC stacks was investigated by studying the stability of the flow channels and the stress redistribution in the glass seal and on the various interfaces of the glass seal with other layers. Finite element analyses were performed to quantify the stresses in various parts. The stresses in glass seals were released because of creep behavior during operations.

  4. Method for heating, forming and tempering a glass sheet

    DOE Patents [OSTI]

    Boaz, P.T.; Sitzman, G.W.

    1998-10-27

    A method for heating, forming and tempering a glass sheet is disclosed including the steps of heating at least one glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, forming the glass sheet to a predetermined configuration, and cooling an outer surface of the glass sheet to at least a third predetermined temperature to temper the glass sheet. 2 figs.

  5. Method for heating, forming and tempering a glass sheet

    DOE Patents [OSTI]

    Boaz, Premakaran Tucker (Livonia, MI); Sitzman, Gary W. (Walled Lake, MI)

    1998-01-01

    A method for heating, forming and tempering a glass sheet including the steps of heating at least one glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, forming the glass sheet to a predetermined configuration, and cooling an outer surface of the glass sheet to at least a third predetermined temperature to temper the glass sheet.

  6. Glass-coating and cleaning system to prevent carbon deposition on coke oven walls

    SciTech Connect (OSTI)

    Takahira, Takuya; Ando, Takeshi; Kasaoka, Shizuki; Yamauchi, Yutaka

    1997-12-31

    The new technology for protecting the coking chamber bricks from damage by hard-pushing is described. The technology consists of the glass coating on the wall bricks and a wall cleaner to blow deposited carbon. For the glass coating, a specially developed glaze is sprayed onto the wall bricks by a spraying device developed to completely spray one coking chamber in a few minutes. The wall cleaner is installed on a pusher ram in the facility to automatically blow air at a sonic speed during coke pushing. The life of the glazed layer is estimated to be over two years.

  7. (a, n) Neutron Emission from DWPF Glass

    SciTech Connect (OSTI)

    Pellarin, D.J.

    2001-03-23

    In the Defense Waste Processing Facility (DWPF) of Savannah River Plant site waste will be immobilized in borosilicate glass. A knowledge of the neutron emission from DWPF glass is necessary to assess shielding requirements for the DWPF canister and to determine the response characteristics of the Neutron Transmission Glass Level Detection System. Excellent agreement was obtained between measured and calculated neutron emissions (yields) from Pu spiked black frit glasses using West's method of weighting components based on relative stopping power. The calculated values for the three glasses were 2-7 percent higher than measured. Calculations using a Nj Zj weighting method were 19-22 percent lower than measured. The good agreement between measurement and calculation using West's method lends confidence in its use to calculate the neutron source term for DWPF glass.

  8. Conversion of Nuclear Waste into Nuclear Waste Glass: Experimental Investigation and Mathematical Modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hrma, Pavel

    2014-12-18

    The melter feed, slurry, or calcine charged on the top of a pool of molten glass forms a floating layer of reacting material called the cold cap. Between the cold-cap top, which is covered with boiling slurry, and its bottom, where bubbles separate it from molten glass, the temperature changes by up to 1000 K. The processes that occur over this temperature interval within the cold cap include liberation of gases, conduction and consumption of heat, dissolution of quartz particles, formation and dissolution of intermediate crystalline phases, and generation of foam and gas cavities. These processes have been investigated usingmore » thermal analyses, optical and electronic microscopies, x-ray diffraction, as well as other techniques. Properties of the reacting feed, such as heat conductivity and density, were measured as functions of temperature. Investigating the structure of quenched cold caps produced in a laboratory-scale melter complemented the crucible studies. The cold cap consists of two main layers. The top layer contains solid particles dissolving in the glass-forming melt and open pores through which gases are escaping. The bottom layer contains bubbly melt or foam where bubbles coalesce into larger cavities that move sideways and release the gas to the atmosphere. The feed-to-glass conversion became sufficiently understood for representing the cold-cap processes via mathematical models. These models, which comprise heat transfer, mass transfer, and reaction kinetics models, have been developed with the final goal to relate feed parameters to the rate of glass melting.« less

  9. Method for forming silicon on a glass substrate

    DOE Patents [OSTI]

    McCarthy, A.M.

    1995-03-07

    A method by which single-crystal silicon microelectronics may be fabricated on glass substrates at unconventionally low temperatures. This is achieved by fabricating a thin film of silicon on glass and subsequently forming the doped components by a short wavelength (excimer) laser doping procedure and conventional patterning techniques. This method may include introducing a heavily boron doped etch stop layer on a silicon wafer using an excimer laser, which permits good control of the etch stop layer removal process. This method additionally includes dramatically reducing the remaining surface roughness of the silicon thin films after etching in the fabrication of silicon on insulator wafers by scanning an excimer laser across the surface of the silicon thin film causing surface melting, whereby the surface tension of the melt causes smoothing of the surface during recrystallization. Applications for this method include those requiring a transparent or insulating substrate, such as display manufacturing. Other applications include sensors, actuators, optoelectronics, radiation hard and high temperature electronics. 15 figs.

  10. Method for making glass-ceramic articles exhibiting high frangibility

    DOE Patents [OSTI]

    Beall, George H.; Brydges, III., William T.; Ference, Joseph; Kozlowski, Theodore R.

    1976-02-03

    This invention is concerned with glass-ceramic articles having compositions within a very narrowly-delimited area of the MgO-Al.sub.2 O.sub.3 -B.sub.2 O.sub.3 -SiO.sub.2 field and having alpha-quartz and sapphirine as the principal crystal phases, resulting from nucleation through a combination of TiO.sub.2 and ZrO.sub.2. Upon contacting such articles with lithium ions at an elevated temperature, said lithium ions will replace magnesium ions on a two Li.sup.+-for-one Mg.sup..sup.+2 basis within the crystal structures, thereby providing a unitary glass-ceramic article having an integral surface layer wherein the principal crystal phase is a lithium-stuffed beta-quartz solid solution. That transformation of crystal phases results in compressive stresses being set up within the surface layer as the articles are cooled. Through the careful control of composition, crystallization treatment, and the parameters of the replacement reaction in the crystal structures, a tremendous degree of stored elastic energy can be developed within the articles such that they will demonstrate frangibility when fractured but will not exhibit undesirable spontaneous breakage and/or spalling.

  11. Process for preparing improved silvered glass mirrors

    DOE Patents [OSTI]

    Buckwalter, C.Q. Jr.

    1980-01-28

    Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

  12. Process for preparing improved silvered glass mirrors

    DOE Patents [OSTI]

    Buckwalter, Jr., Charles Q. (Benton, WA)

    1981-01-01

    Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

  13. Glass Property Data and Models for Estimating High-Level Waste Glass Volume

    SciTech Connect (OSTI)

    Vienna, John D.; Fluegel, Alexander; Kim, Dong-Sang; Hrma, Pavel R.

    2009-10-05

    This report describes recent efforts to develop glass property models that can be used to help estimate the volume of high-level waste (HLW) glass that will result from vitrification of Hanford tank waste. The compositions of acceptable and processable HLW glasses need to be optimized to minimize the waste-form volume and, hence, to save cost. A database of properties and associated compositions for simulated waste glasses was collected for developing property-composition models. This database, although not comprehensive, represents a large fraction of data on waste-glass compositions and properties that were available at the time of this report. Glass property-composition models were fit to subsets of the database for several key glass properties. These models apply to a significantly broader composition space than those previously publised. These models should be considered for interim use in calculating properties of Hanford waste glasses.

  14. Prestressed glass, aezoelectric electrical power source

    DOE Patents [OSTI]

    Newson, Melvin M.

    1976-01-01

    An electrical power source which comprises a body of prestressed glass having a piezoelectric transducer supported on the body in direct mechanical coupling therewith.

  15. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of ions from bioactive glasses reportedly activates the expression of osteogenic genes and stimulates bone growth, or angiogenesis. The ease and efficiency with which...

  16. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with cortical and trabecular bone and literature values of porous glass and hydroxyapatite scaffolds. Each style of point corresponds to a different literature value....

  17. Electrochemical cell with high conductivity glass electrolyte

    DOE Patents [OSTI]

    Nelson, P.A.; Bloom, I.D.; Roche, M.F.

    1986-04-17

    A secondary electrochemical cell with sodium-sulfur or other molten reactants is provided with an ionically conductive glass electrolyte. The cell is contained within an electrically conductive housing with a first portion at negative potential and a second portion insulated therefrom at positive electrode potential. The glass electrolyte is formed into a plurality of elongated tubes and placed lengthwise within the housing. The positive electrode material, for instance sulfur, is sealed into the glass electrolyte tubes and is provided with an elongated axial current collector. The glass electrolyte tubes are protected by shield tubes or sheets that also define narrow annuli for wicking of the molten negative electrode material.

  18. Electrochemical cell with high conductivity glass electrolyte

    DOE Patents [OSTI]

    Nelson, P.A.; Bloom, I.D.; Roche, M.F.

    1987-04-21

    A secondary electrochemical cell with sodium-sulfur or other molten reactants is provided with a ionically conductive glass electrolyte. The cell is contained within an electrically conductive housing with a first portion at negative potential and a second portion insulated therefrom at positive electrode potential. The glass electrolyte is formed into a plurality of elongated tubes and placed lengthwise within the housing. The positive electrode material, for instance sulfur, is sealed into the glass electrolyte tubes and is provided with an elongated axial current collector. The glass electrolyte tubes are protected by shield tubes or sheets that also define narrow annuli for wicking of the molten negative electrode material. 6 figs.

  19. Electrochemical cell with high conductivity glass electrolyte

    DOE Patents [OSTI]

    Nelson, Paul A.; Bloom, Ira D.; Roche, Michael F.

    1987-01-01

    A secondary electrochemical cell with sodium-sulfur or other molten reactants is provided with a ionically conductive glass electrolyte. The cell is contained within an electrically conductive housing with a first portion at negative potential and a second portion insulated therefrom at positive electrode potential. The glass electrolyte is formed into a plurality of elongated tubes and placed lengthwise within the housing. The positive electrode material, for instance sulfur, is sealed into the glass electrolyte tubes and is provided with an elongated axial current collector. The glass electrolyte tubes are protected by shield tubes or sheets that also define narrow annuli for wicking of the molten negative electrode material.

  20. Compliant Glass Seals for SOFC Stacks

    SciTech Connect (OSTI)

    Chou, Y. S.; Choi, Jung-Pyung; Xu, Wei; Stephens, Elizabeth V.; Koeppel, Brian J.; Stevenson, Jeffry W.; Lara-Curzio, Edgar

    2014-04-01

    This report summarizes results from experimental and modeling studies performed by participants in the Solid-State Energy Conversion Alliance (SECA) Core Technology Program, which indicate that compliant glass-based seals offer a number of potential advantages over conventional seals based on de-vitrifying glasses, including reduced stresses during stack operation and thermal cycling, and the ability to heal micro-damage induced during thermal cycling. The properties and composition of glasses developed and/or investigated in these studies are reported, along with results from long-term (up to 5,800h) evaluations of seals based on a compliant glass containing ceramic particles or ceramic fibers.

  1. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    have been used for the fabrication of glass scaffolds, including polymer foam replication, sol-gel, and freeze-casting; however, the low compressive strength of these...

  2. Photonic layered media

    DOE Patents [OSTI]

    Fleming, James G.; Lin, Shawn-Yu

    2002-01-01

    A new class of structured dielectric media which exhibit significant photonic bandstructure has been invented. The new structures, called photonic layered media, are easy to fabricate using existing layer-by-layer growth techniques, and offer the ability to significantly extend our practical ability to tailor the properties of such optical materials.

  3. Scintillator reflective layer coextrusion

    DOE Patents [OSTI]

    Yun, Jae-Chul; Para, Adam

    2001-01-01

    A polymeric scintillator has a reflective layer adhered to the exterior surface thereof. The reflective layer comprises a reflective pigment and an adhesive binder. The adhesive binder includes polymeric material from which the scintillator is formed. A method of forming the polymeric scintillator having a reflective layer adhered to the exterior surface thereof is also provided. The method includes the steps of (a) extruding an inner core member from a first amount of polymeric scintillator material, and (b) coextruding an outer reflective layer on the exterior surface of the inner core member. The outer reflective layer comprises a reflective pigment and a second amount of the polymeric scintillator material.

  4. SRNL POROUS WALL GLASS MICROSPHERES

    SciTech Connect (OSTI)

    Wicks, G; Leung Heung, L; Ray Schumacher, R

    2008-04-15

    The Savannah River National Laboratory (SRNL) has developed a new medium for storage of hydrogen and other gases. This involves fabrication of thin, Porous Walled, Hollow Glass Microspheres (PW-HGMs), with diameters generally in the range of 1 to several hundred microns. What is unique about the glass microballons is that porosity has been induced and controlled within the thin, one micron thick walls, on the scale of 10 to several thousand Angstroms. This porosity results in interesting properties including the ability to use these channels to fill the microballons with special absorbents and other materials, thus providing a contained environment even for reactive species. Gases can now enter the microspheres and be retained on the absorbents, resulting in solid-state and contained storage of even reactive species. Also, the porosity can be altered and controlled in various ways, and even used to filter mixed gas streams within a system. SRNL is involved in about a half dozen different programs involving these PW-HGMs and an overview of some of these activities and results emerging are presented.

  5. Control of radioactive waste-glass melters

    SciTech Connect (OSTI)

    Bickford, D.F. ); Hrma, P. ); Bowan, B.W. II )

    1990-01-01

    Slurries of simulated high level radioactive waste and glass formers have been isothermally reacted and analyzed to identify the sequence of the major chemical reactions in waste vitrification, their effect on glass production rate, and the development of leach resistance. Melting rates of waste batches have been increased by the addition of reducing agents (formic acid, sucrose) and nitrates. The rate increases are attributable in part to exothermic reactions which occur at critical stages in the vitrification process. Nitrates must be balanced by adequate reducing agents to avoid the formation of persistent foam, which would destabilize the melting process. The effect of foaming on waste glass production rates is analyzed, and melt rate limitations defined for waste-glass melters, based upon measurable thermophysical properties. Minimum melter residence times required to homogenize glass and assure glass quality are much smaller than those used in current practice. Thus, melter size can be reduced without adversely affecting glass quality. Physical chemistry and localized heat transfer of the waste-glass melting process are examined, to refine the available models for predicting and assuring glass production rate. It is concluded that the size of replacement melters and future waste processing facilities can be significantly decreased if minimum heat transfer requirements for effective melting are met by mechanical agitation. A new class of waste glass melters has been designed, and proof of concept tests completed on simulated High Level Radioactive Waste slurry. Melt rates have exceeded 155 kg m{sup {minus}2} h{sup {minus}1} with slurry feeds (32 lb ft{sup {minus}2} h{sup {minus}1}), and 229 kg kg m{sup {minus}2} h{sup {minus}1} with dry feed (47 lb ft{sup {minus}2} h{sup {minus}1}). This is about 8 times the melt rate possible in conventional waste- glass melters of the same size. 39 refs., 5 figs., 9 tabs.

  6. Monitoring and analyzing waste glass compositions

    DOE Patents [OSTI]

    Schumacher, R.F.

    1994-03-01

    A device and method are described for determining the viscosity of a fluid, preferably molten glass. The apparatus and method use the velocity of rising bubbles, preferably helium bubbles, within the molten glass to determine the viscosity of the molten glass. The bubbles are released from a tube positioned below the surface of the molten glass so that the bubbles pass successively between two sets of electrodes, one above the other, that are continuously monitoring the conductivity of the molten glass. The measured conductivity will change as a bubble passes between the electrodes enabling an accurate determination of when a bubble has passed between the electrodes. The velocity of rising bubbles can be determined from the time interval between a change in conductivity of the first electrode pair and the second, upper electrode pair. The velocity of the rise of the bubbles in the glass melt is used in conjunction with other physical characteristics, obtained by known methods, to determine the viscosity of the glass melt fluid and, hence, glass quality. 2 figures.

  7. Monitoring and analyzing waste glass compositions

    DOE Patents [OSTI]

    Schumacher, Ray F.

    1994-01-01

    A device and method for determining the viscosity of a fluid, preferably molten glass. The apparatus and method uses the velocity of rising bubbles, preferably helium bubbles, within the molten glass to determine the viscosity of the molten glass. The bubbles are released from a tube positioned below the surface of the molten glass so that the bubbles pass successively between two sets of electrodes, one above the other, that are continuously monitoring the conductivity of the molten glass. The measured conductivity will change as a bubble passes between the electrodes enabling an accurate determination of when a bubble has passed between the electrodes. The velocity of rising bubbles can be determined from the time interval between a change in conductivity of the first electrode pair and the second, upper electrode pair. The velocity of the rise of the bubbles in the glass melt is used in conjunction with other physical characteristics, obtained by known methods, to determine the viscosity of the glass melt fluid and, hence, glass quality.

  8. Sealing glasses for titanium and titanium alloys

    DOE Patents [OSTI]

    Brow, Richard K.; Watkins, Randall D.

    1992-01-01

    Glass compositions containing CaO, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, SrO and BaO of various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with titanium and titanium alloys, for use in components such as seals for battery headers.

  9. Sealing glasses for titanium and titanium alloys

    DOE Patents [OSTI]

    Brow, R.K.; Watkins, R.D.

    1988-01-21

    Glass compositions containing CaO, Al/sub 2/O/sub 3/, B/sub 2/O/sub 3/, SrO and BaO of various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with titanium and titanium alloys, for use in components such as seals for battery headers.

  10. Viscous Glass Sealants for SOFC Applications

    SciTech Connect (OSTI)

    Scott Misture

    2012-09-30

    Two series of silicate glasses that contain gallium as the primary critical component have been identified and optimized for viscous sealing of solid oxide fuel cells operating from 650 to 850°C. Both series of glass sealants crystallize partially upon heat treatment and yield multiphase microstructures that allow viscous flow at temperatures as low as 650°C. A fully amorphous sealant was also developed by isolating, synthesizing and testing a silicate glass of the same composition as the remnant glassy phase in one of the two glass series. Of ~40 glasses tested for longer than 500 hours, a set of 5 glasses has been further tested for up to 1000h in air, wet hydrogen, and against both yttria-stabilized zirconia and aluminized stainless steel. In some cases the testing times reached 2000h. The reactivity testing has provided new insight into the effects of Y, Zr, and Al on bulk and surface crystallization in boro-gallio-silicate glasses, and demonstrated that at least 5 of the newly-developed glasses are viable viscous sealants.

  11. Low loss laser glass: Final report

    SciTech Connect (OSTI)

    Izumitani, T.; Toratani, H.; Meissner, H.E.

    1987-01-15

    The objective of this work was a process development on making a laser glass with loss coefficient of 10/sup -4/cm/sup -1/ at 1.05..mu... The key issues for making such a low loss glass will be to use pure raw materials, to reduce OH content and to prevent contamination from the melting environment. A sublimation method was tried to prepare pure P/sub 2/O/sub 5/ batch material. In an attempt to distinguish contributions to the overall loss, glasses were melted in furnaces which were controlled in moisture as well as contamination. Evaluation of glass samples at LLNL are expected to provide guidance on the importance of various process parameters. A new 0.5 liter furnace which almost completely prevents contamination by the furnace environment has been constructed to obtain useful information for making a low loss glass on a production scale.

  12. Glass needs for a growing photovoltaics industry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Burrows, Keith; Fthenakis, Vasilis

    2014-10-18

    With the projected growth in photovoltaics, the demand for glass for the solar industry will far exceed the current supply, and thousands of new float-glass plants will have to be built to meet its needs over the next 20 years. Such expansion will provide an opportunity for the solar industry to obtain products better suited to their needs, such as low-iron glass and borosilicate glass at the lowest possible price. While there are no significant technological hurdles that would prevent the flat glass industry from meeting the solar industry’s projected needs, to do so will require advance planning and substantialmore » investments.« less

  13. Titanium sealing glasses and seals formed therefrom

    DOE Patents [OSTI]

    Brow, Richard K.; McCollister, Howard L.; Phifer, Carol C.; Day, Delbert E.

    1997-01-01

    Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La.sub.2 O.sub.3, B.sub.2 O.sub.3, TiO.sub.2 and Al.sub.2 O.sub.3 in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

  14. Titanium sealing glasses and seals formed therefrom

    DOE Patents [OSTI]

    Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

    1997-12-02

    Alkaline-earth lanthanoborate sealing-glass compositions containing CaO, La{sub 2}O{sub 3}, B{sub 2}O{sub 3}, TiO{sub 2} and Al{sub 2}O{sub 3} in various combinations of mole-% are provided. These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys that have a high aqueous durability for component or device applications requiring exposure to moisture, water or body fluids. Particular applications of the titanium sealing-glass compositions include forming glass-to-metal seals for lithium batteries and implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 2 figs.

  15. Glass heat pipe evacuated tube solar collector

    DOE Patents [OSTI]

    McConnell, Robert D.; Vansant, James H.

    1984-01-01

    A glass heat pipe is adapted for use as a solar energy absorber in an evacuated tube solar collector and for transferring the absorbed solar energy to a working fluid medium or heat sink for storage or practical use. A capillary wick is formed of granular glass particles fused together by heat on the inside surface of the heat pipe with a water glass binder solution to enhance capillary drive distribution of the thermal transfer fluid in the heat pipe throughout the entire inside surface of the evaporator portion of the heat pipe. Selective coatings are used on the heat pipe surface to maximize solar absorption and minimize energy radiation, and the glass wick can alternatively be fabricated with granular particles of black glass or obsidian.

  16. Gaseous Sulfate Solubility in Glass: Experimental Method

    SciTech Connect (OSTI)

    Bliss, Mary

    2013-11-30

    Sulfate solubility in glass is a key parameter in many commercial glasses and nuclear waste glasses. This report summarizes key publications specific to sulfate solubility experimental methods and the underlying physical chemistry calculations. The published methods and experimental data are used to verify the calculations in this report and are expanded to a range of current technical interest. The calculations and experimental methods described in this report will guide several experiments on sulfate solubility and saturation for the Hanford Waste Treatment Plant Enhanced Waste Glass Models effort. There are several tables of sulfate gas equilibrium values at high temperature to guide experimental gas mixing and to achieve desired SO3 levels. This report also describes the necessary equipment and best practices to perform sulfate saturation experiments for molten glasses. Results and findings will be published when experimental work is finished and this report is validated from the data obtained.

  17. Method for heating and forming a glass sheet

    DOE Patents [OSTI]

    Boaz, Premakaran Tucker (Livonia, MI)

    1997-01-01

    A method for heating and forming a glass sheet includes the steps of heating a glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, cooling an outer surface of the glass sheet to at least a third predetermined temperature and forming the glass sheet using forming rollers to a predetermined configuration.

  18. Method for heating and forming a glass sheet

    DOE Patents [OSTI]

    Boaz, P.T.

    1997-08-12

    A method for heating and forming a glass sheet includes the steps of heating a glass sheet to at least a first predetermined temperature, applying microwave energy to the glass sheet to heat the glass sheet to at least a second predetermined temperature, cooling an outer surface of the glass sheet to at least a third predetermined temperature and forming the glass sheet using forming rollers to a predetermined configuration. 5 figs.

  19. Process for direct conversion of reactive metals to glass (Patent...

    Office of Scientific and Technical Information (OSTI)

    is contacted with silica powder introduced in an air stream to form in one step a glass. ... contacted; silica; powder; introduced; air; stream; form; step; glass; cyclone; ...

  20. Development Wells At Glass Buttes Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Development Wells At Glass Buttes Area (DOE GTP) Exploration Activity...

  1. Asahi Glass Co Ltd AGC | Open Energy Information

    Open Energy Info (EERE)

    Ltd AGC Jump to: navigation, search Name: Asahi Glass Co Ltd (AGC) Place: Tokyo, Tokyo, Japan Zip: 100-8405 Sector: Efficiency Product: Japanese glass manufacturer; produces cover...

  2. Magnetotellurics At Glass Mountain Area (Cumming And Mackie,...

    Open Energy Info (EERE)

    Magnetotellurics At Glass Mountain Area (Cumming And Mackie, 2007) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Magnetotellurics At Glass...

  3. Metal and Glass Manufacturers Reduce Costs by Increasing Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metal and Glass Manufacturers Reduce Costs by Increasing Energy Efficiency in Process Heating Systems Metal and Glass Manufacturers Reduce Costs by Increasing Energy Efficiency in...

  4. Multispectral Imaging At Glass Buttes Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Multispectral Imaging At Glass Buttes Area (DOE GTP) Exploration...

  5. Aeromagnetic Survey At Glass Buttes Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Aeromagnetic Survey At Glass Buttes Area (DOE GTP) Exploration...

  6. Cuttings Analysis At Glass Buttes Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Cuttings Analysis At Glass Buttes Area (DOE GTP) Exploration Activity...

  7. China Glass Solar aka CG Solar formerly Weihai Bluestar Terra...

    Open Energy Info (EERE)

    Glass Solar aka CG Solar formerly Weihai Bluestar Terra Photovoltaic Co Ltd Jump to: navigation, search Name: China Glass Solar (aka CG Solar, formerly Weihai Bluestar Terra...

  8. Static Temperature Survey At Glass Buttes Area (DOE GTP) | Open...

    Open Energy Info (EERE)

    to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Static Temperature Survey At Glass Buttes Area (DOE GTP) Exploration Activity Details Location Glass...

  9. Pressure Temperature Log At Glass Buttes Area (DOE GTP) | Open...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Pressure Temperature Log At Glass Buttes Area (DOE GTP) Exploration Activity Details Location Glass...

  10. Study Builds Knowledge of Nuclear Waste Glass, Provides Insight...

    Office of Environmental Management (EM)

    Study Builds Knowledge of Nuclear Waste Glass, Provides Insight to Facility Design Study Builds Knowledge of Nuclear Waste Glass, Provides Insight to Facility Design April 14, 2016 ...

  11. EA-1996: Glass Buttes Radio Station, Lake County, Oregon | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6: Glass Buttes Radio Station, Lake County, Oregon EA-1996: Glass Buttes Radio Station, Lake County, Oregon SUMMARY The Bureau of Land Management (BLM), with DOE's Bonneville Power...

  12. Advanced Manufacture of Second-Surface, Silvered Glass Reflectors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacture of Second-Surface, Silvered Glass Reflectors for High-Performance, Low-Cost CSP Collector Systems Advanced Manufacture of Second-Surface, Silvered Glass Reflectors for ...

  13. Viscoelasticity of Glass-Forming Materials: What about inorganic...

    Office of Scientific and Technical Information (OSTI)

    Viscoelasticity of Glass-Forming Materials: What about inorganic sealing glasses?. ... Exposition on Experimental and Applied Mechanics held June 8-11, 2015 in Costa Mesa, CA

  14. Guangfeng Solar Glass Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Solar Glass Co Ltd Place: Zhangjiagang, Jiangsu Province, China Zip: 215600 Product: Chinese PV glass maker Coordinates: 31.950001, 120.449997 Show Map Loading map......

  15. Glass for sealing lithium cells

    DOE Patents [OSTI]

    Leedecke, C.J.

    1981-08-28

    Glass compositions resistant to corrosion by lithium cell electrolyte and having an expansion coefficient of 45 to 85 x 10/sup -70/C/sup -1/ have been made with SiO/sub 2/, 25 to 55% by weight; B/sub 2/O/sub 3/, 5 to 12%; Al/sub 2/O/sub 3/, 12 to 35%; CaO, 5 to 15%; MgO, 5 to 15%; SrO, 0 to 10%; and La/sub 2/O/sub 3/, 0 to 5%. Preferred compositions within that range contain 3 to 8% SrO and 0.5 to 2.5% La/sub 2/O/sub 3/.

  16. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    SciTech Connect (OSTI)

    Allan, Shawn M.

    2012-02-27

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North

  17. Energy Saving Glass Lamination via Selective Radio Frequency Heating

    SciTech Connect (OSTI)

    Allan, Shawn M.; Baranova, Inessa; Poley, Joseph; Reis, Henrique

    2012-02-27

    This project focused on advancing radio-frequency (RF) lamination technology closer to commercial implementation, in order to reduce the energy intensity of glass lamination by up to 90%. Lamination comprises a wide range of products including autoglass, architectural safety and innovative design glass, transparent armor (e.g. bullet proof glass), smart glass, mirrors, and encapsulation of photovoltaics. Lamination is also the fastest growing segment of glass manufacturing, with photovoltaics, architectural needs, and an anticipated transition to laminated side windows in vehicles. The state-of-the-art for glass lamination is to use autoclaves, which apply heat and uniform gas pressure to bond the laminates over the course of 1 to 18 hours. Laminates consist of layers of glass or other materials bonded with vinyl or urethane interlayers. In autoclaving, significant heat energy is lost heating the chamber, pressurized air, glass racks, and the glass. In RF lamination, the heat is generated directly in the vinyl interlayer, causing it to heat and melt quickly, in just 1 to 10 minutes, without significantly heating the glass or the equipment. The main purpose of this project was to provide evidence that low energy, rapid RF lamination quality met the same standards as conventionally autoclaved windows. The development of concepts for laminating curved glass with RF lamination was a major goal. Other primary goals included developing a stronger understanding of the lamination product markets described above, and to refine the potential benefits of commercial implementation. The scope of the project was to complete implementation concept studies in preparation for continuation into advanced development, pilot studies, and commercial implementation. The project consisted of 6 main tasks. The first dealt with lamination with poly-vinyl butyral (PVB) interlayers, which prior work had shown difficulties in achieving good quality laminates, working with Pilkington North

  18. Minor component study for simulated high-level nuclear waste glasses (Draft)

    SciTech Connect (OSTI)

    Li, H.; Langowskim, M.H.; Hrma, P.R.; Schweiger, M.J.; Vienna, J.D.; Smith, D.E.

    1996-02-01

    Hanford Site single-shell tank (SSI) and double-shell tank (DSI) wastes are planned to be separated into low activity (or low-level waste, LLW) and high activity (or high-level waste, HLW) fractions, and to be vitrified for disposal. Formulation of HLW glass must comply with glass processibility and durability requirements, including constraints on melt viscosity, electrical conductivity, liquidus temperature, tendency for phase segregation on the molten glass surface, and chemical durability of the final waste form. A wide variety of HLW compositions are expected to be vitrified. In addition these wastes will likely vary in composition from current estimates. High concentrations of certain troublesome components, such as sulfate, phosphate, and chrome, raise concerns about their potential hinderance to the waste vitrification process. For example, phosphate segregation in the cold cap (the layer of feed on top of the glass melt) in a Joule-heated melter may inhibit the melting process (Bunnell, 1988). This has been reported during a pilot-scale ceramic melter run, PSCM-19, (Perez, 1985). Molten salt segregation of either sulfate or chromate is also hazardous to the waste vitrification process. Excessive (Cr, Fe, Mn, Ni) spinel crystal formation in molten glass can also be detrimental to melter operation.

  19. Layered plasma polymer composite membranes

    DOE Patents [OSTI]

    Babcock, W.C.

    1994-10-11

    Layered plasma polymer composite fluid separation membranes are disclosed, which comprise alternating selective and permeable layers for a total of at least 2n layers, where n is [>=]2 and is the number of selective layers. 2 figs.

  20. Layered plasma polymer composite membranes

    DOE Patents [OSTI]

    Babcock, Walter C.

    1994-01-01

    Layered plasma polymer composite fluid separation membranes are disclosed, which comprise alternating selective and permeable layers for a total of at least 2n layers, where n is .gtoreq.2 and is the number of selective layers.

  1. Solid oxide fuel cell having a glass composite seal

    DOE Patents [OSTI]

    De Rose, Anthony J.; Mukerjee, Subhasish; Haltiner, Jr., Karl Jacob

    2013-04-16

    A solid oxide fuel cell stack having a plurality of cassettes and a glass composite seal disposed between the sealing surfaces of adjacent cassettes, thereby joining the cassettes and providing a hermetic seal therebetween. The glass composite seal includes an alkaline earth aluminosilicate (AEAS) glass disposed about a viscous glass such that the AEAS glass retains the viscous glass in a predetermined position between the first and second sealing surfaces. The AEAS glass provides geometric stability to the glass composite seal to maintain the proper distance between the adjacent cassettes while the viscous glass provides for a compliant and self-healing seal. The glass composite seal may include fibers, powders, and/or beads of zirconium oxide, aluminum oxide, yttria-stabilized zirconia (YSZ), or mixtures thereof, to enhance the desirable properties of the glass composite seal.

  2. HGMS: Glasses and Nanocomposites for Hydrogen Storage.

    SciTech Connect (OSTI)

    Lipinska, Kris; Hemmers, Oliver

    2013-02-17

    The primary goal of this project is to fabricate and investigate different glass systems and glass-derived nanocrystalline composite materials. These glass-based, two-phased materials will contain nanocrystals that can attract hydrogen and be of potential interest as hydrogen storage media. The glass materials with intrinsic void spaces that are able to precipitate functional nanocrystals capable to attract hydrogen are of particular interest. Proposed previously, but never practically implemented, one of promising concepts for storing hydrogen are micro-containers built of glass and shaped into hollow microspheres. The project expanded this concept to the exploration of glass-derived nanocrystalline composites as potential hydrogen storage media. It is known that the most desirable materials for hydrogen storage do not interact chemically with hydrogen and possess a high surface area to host substantial amounts of hydrogen. Glasses are built of disordered networks with ample void spaces that make them permeable to hydrogen even at room temperature. Glass-derived nanocrystalline composites (two-phased materials), combination of glasses (networks with ample voids) and functional nanocrystals (capable to attract hydrogen), appear to be promising candidates for hydrogen storage media. Key advantages of glass materials include simplicity of preparation, flexibility of composition, chemical durability, non-toxicity and mechanical strength, as well as low production costs and environmental friendliness. This project encompasses a fundamental research into physics and chemistry of glasses and nanocrystalline composite materials, derived from glass. Studies are aimed to answer questions essential for considering glass-based materials and composites as potential hydrogen storage media. Of particular interest are two-phased materials that combine glasses with intrinsic voids spaces for physisorption of hydrogen and nanocrystals capable of chemisorption. This project does not

  3. Crystallization in high-level waste glass: A review of glass theory and noteworthy literature

    SciTech Connect (OSTI)

    Christian, J. H.

    2015-08-01

    There is a fundamental need to continue research aimed at understanding nepheline and spinel crystal formation in high-level waste (HLW) glass. Specifically, the formation of nepheline solids (K/NaAlSiO₄) during slow cooling of HLW glass can reduce the chemical durability of the glass, which can cause a decrease in the overall durability of the glass waste form. The accumulation of spinel solids ((Fe, Ni, Mn, Zn)(Fe,Cr)₂O₄), while not detrimental to glass durability, can cause an array of processing problems inside of HLW glass melters. In this review, the fundamental differences between glass and solid-crystals are explained using kinetic, thermodynamic, and viscosity arguments, and several highlights of glass-crystallization research, as it pertains to high-level waste vitrification, are described. In terms of mitigating spinel in the melter and both spinel and nepheline formation in the canister, the complexity of HLW glass and the intricate interplay between thermal, chemical, and kinetic factors further complicates this understanding. However, new experiments seeking to elucidate the contributing factors of crystal nucleation and growth in waste glass, and the compilation of data from older experiments, may go a long way towards helping to achieve higher waste loadings while developing more efficient processing strategies.

  4. Crystallization in high-level waste glass: A review of glass theory and noteworthy literature

    SciTech Connect (OSTI)

    Christian, J. H.

    2015-08-18

    There is a fundamental need to continue research aimed at understanding nepheline and spinel crystal formation in high-level waste (HLW) glass. Specifically, the formation of nepheline solids (K/NaAlSiO4) during slow cooling of HLW glass can reduce the chemical durability of the glass, which can cause a decrease in the overall durability of the glass waste form. The accumulation of spinel solids ((Fe, Ni, Mn, Zn)(Fe, Cr)2O4), while not detrimental to glass durability, can cause an array of processing problems inside HLW glass melters. In this review, the fundamental differences between glass and solid-crystals are explained using kinetic, thermodynamic, and viscosity arguments, and several highlights of glass-crystallization research, as it pertains to high-level waste vitrification, are described. In terms of mitigating spinel in the melter and both spinel and nepheline formation in the canister, the complexity of HLW glass and the intricate interplay between thermal, chemical, and kinetic factors further complicates this understanding. However, new experiments seeking to elucidate the contributing factors of crystal nucleation and growth in waste glass, and the compilation of data from older experiments, may go a long way towards helping to achieve higher waste loadings while developing more efficient processing strategies. Higher waste loadings and more efficient processing strategies will reduce the overall HLW Hanford Tank Waste Treatment and Immobilization Plant (WTP) vitrification facilities mission life.

  5. Energy implications of glass-container recycling

    SciTech Connect (OSTI)

    Gaines, L L; Mintz, M M

    1994-03-01

    This report addresses the question of whether glass-container recycling actually saves energy. Glass-container production in 1991 was 10{sup 7} tons, with cullet making up about 30% of the input to manufacture. Two-thirds of the cullet is postconsumer waste; the remainder is in-house scrap (rejects). Most of the glass recycled is made into new containers. Total primary energy consumption includes direct process-energy use by the industry (adjusted to account for the efficiency of fuel production) plus fuel and raw-material transportation and production energies; the grand total for 1991 is estimated to be about 168 {times} 10{sup 12} Btu. The total primary energy use decreases as the percent of glass recycled rises, but the maximum energy saved is only about 13%. If distance to the landfill is kept fixed and that to the recovery facility multiplied by about eight, to 100 mi, a break-even point is reached, and recycling saves no energy. Previous work has shown that to save energy when using glass bottles, reuse is the clear choice. Recycling of glass does not save much energy or valuable raw material and does not reduce air or water pollution significantly. The most important impacts are the small reduction of waste sent to the landfill and increased production rates at glass plants.

  6. Glass ceramic-to-metal seals

    DOE Patents [OSTI]

    Not Available

    1982-04-19

    A glass ceramic composition prepared by subjecting a glass composition comprising, by weight, 65 to 80% SiO/sub 2/, 8 to 16% Li/sub 2/O, 2 to 8% Al/sub 2/O/sub 3/, 1 to 8% K/sub 2/O, 1 to 5% P/sub 2/O/sub 5/ and 1.5 to 7% B/sub 2/O/sub 3/, to the following processing steps of heating the glass composition to a temperature sufficient to crystallize lithium metasilicate therein, holding the glass composition at a temperature and for a time period sufficient to dissolve the lithium metasilicate therein thereby creating cristobalite nucleii, cooling the glass composition and maintaining the composition at a temperature and for a time period sufficient to recrystallize lithium metasilicate therein, and thermally treating the glass composition at a temperature and for a time period sufficient to caus growth of cristobalite and further crystallization of lithium metasilicate producing a glass ceramic composition having a specific thermal expansion coefficient and products containing said composition.

  7. Contribution of atom-probe tomography to a better understanding of glass alteration mechanisms: Application to a nuclear glass specimen altered 25 years in a granitic environment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gin, Stephane; Ryan, Joseph V.; Schreiber, Daniel K.; Neeway, James J.; Cabie, M.

    2013-04-08

    Here, we report and discuss results of atom probe tomography (APT) and energy-filtered transmission electron microscopy (EFTEM) applied to a borosilicate glass sample of nuclear interest altered for nearly 26 years at 90°C in a confined granitic medium in order to better understand the rate-limiting mechanisms under conditions representative of a deep geological repository for vitrified radioactive waste. The APT technique allows the 3D reconstruction of the elemental distribution at the reactive interphase with sub-nanometer precision. Profiles of the B distribution at pristine glass/hydrated glass interface obtained by different techniques are compared to show the challenge of accurate measurements ofmore » diffusion profiles at this buried interface on the nanometer length scale. Our results show that 1) Alkali from the glass and hydrogen from the solution exhibit anti-correlated 15 ± 3 nm wide gradients located between the pristine glass and the hydrated glass layer, 2) boron exhibits an unexpectedly sharp profile located just at the outside of the alkali/H interdiffusion layer; this sharp profile is more consistent with a dissolution front than a diffusion-controlled release of boron. The resulting apparent diffusion coefficients derived from the Li and H profiles are DLi = 1.5 × 10-22 m2.s-1 and DH = 6.8 × 10-23 m2.s-1. These values are around two orders of magnitude lower than those observed at the very beginning of the alteration process, which suggests that interdiffusion is slowed at high reaction progress by local conditions that could be related to the porous structure of the interphase. As a result, the accessibility of water to the pristine glass could be the rate-limiting step in these conditions. More generally, these findings strongly support the importance of interdiffusion coupled with hydrolysis reactions of the silicate network on the long-term dissolution rate, contrary to what has been suggested by recent interfacial dissolution

  8. Contribution of atom-probe tomography to a better understanding of glass alteration mechanisms: application to a nuclear glass specimen altered 25 years in a granitic environment

    SciTech Connect (OSTI)

    Gin, Stephane; Ryan, Joseph V.; Schreiber, Daniel K.; Neeway, James J.; Cabie, M.

    2013-06-26

    We report and discuss results of atom probe tomography (APT) and energy-filtered transmission electron microscopy (EFTEM) applied to a borosilicate glass sample of nuclear interest altered for nearly 26 years at 90°C in a confined granitic medium in order to better understand the rate-limiting mechanisms under conditions representative of a deep geological repository for vitrified radioactive waste. The APT technique allows the 3D reconstruction of the elemental distribution at the reactive interphase with sub-nanometer precision. Profiles of the B distribution at pristine glass/hydrated glass interface obtained by different techniques are compared to show the challenge of accurate measurements of diffusion profiles at this buried interface on the nanometer length scale. Our results show that 1) Alkali from the glass and hydrogen from the solution exhibit anti-correlated 15 ± 3 nm wide gradients located between the pristine glass and the hydrated glass layer, 2) boron exhibits an unexpectedly sharp profile located just at the outside of the alkali/H interdiffusion layer; this sharp profile is more consistent with a dissolution front than a diffusion-controlled release of boron. The resulting apparent diffusion coefficients derived from the Li and H profiles are DLi = 1.5 × 10-22 m2.s-1 and DH = 6.8 × 10-23 m2.s-1. These values are around two orders of magnitude lower than those observed at the very beginning of the alteration process, which suggests that interdiffusion is slowed at high reaction progress by local conditions that could be related to the porous structure of the interphase. As a result, the accessibility of water to the pristine glass could be the rate-limiting step in these conditions. More generally, these findings strongly support the importance of interdiffusion coupled with hydrolysis reactions of the silicate network on the long-term dissolution rate, contrary to what has been suggested by recent interfacial dissolution-precipitation models

  9. Designing aluminum sealing glasses for manufacturability

    SciTech Connect (OSTI)

    Kovacic, L.; Crowder, S.V.; Brow, R.K.; Bencoe, D.N.

    1993-12-31

    Manufacturability issues involved in the development of new sealing glasses include tailoring glass compositions to meet material and component requirements and determining the optimum seal processing parameters. For each of these issues, statistical analysis can be used to shorten the time between concept and product in the development of what is essentially a new manufacturing technology. We use the development of our new family of phosphate-based glasses for aluminum/stainless steel and aluminum/CuBe hermetic sealing, the ALSG family, to illustrate the statistical approach.

  10. Stress in shaped glass evacuated collectors

    SciTech Connect (OSTI)

    Garrison, J.D.; Fischer-Cripps, A.

    1997-02-01

    Shaped glass evacuated collectors have the lower vacuum envelope formed with a CPC shape. The internal surface is silvered. This surface concentrates solar radiation onto an internal absorbing tube. The upper part of the vacuum envelope is a window to pass the solar radiation in to the absorbing tube. A computer program using analytical equations is used to design these collectors while keeping the glass tensile stress arising from evacuation below acceptable limits. A finite element computer program is used to test the accuracy of the stress calculated analytically. The calculations agree within about 1 MPa. Wind and thermal stresses in the glass are lower than the stresses caused by evacuation.

  11. Novel lead-iron phosphate glass

    DOE Patents [OSTI]

    Boatner, Lynn A.; Sales, Brian C.

    1989-01-01

    The invention described and claimed in the specification relates to the discovery that effective addition of Fe.sub.2 O.sub.3 to a lead phosphate glass results in a glass having enhanced chemical durability and physical stability, and consists essentially of the glass resulting from melting a mixture consisting essentially of, in weight percent, 40-66 percent PbO, 30-55 percent P.sub.2 O.sub.5 and an effective concentration up to 12 percent Fe.sub.2 O.sub.3.

  12. Novel lead-iron phosphate glass

    DOE Patents [OSTI]

    Boatner, L.A.; Sales, B.C.

    1989-07-11

    The invention described and claimed in the specification relates to the discovery that effective addition of Fe[sub 2]O[sub 3] to a lead phosphate glass results in a glass having enhanced chemical durability and physical stability, and consists essentially of the glass resulting from melting a mixture consisting essentially of, in weight percent, 40--66 percent PbO, 30--55 percent P[sub 2]O[sub 5] and an effective concentration up to 12 percent Fe[sub 2]O[sub 3].

  13. GLASS COMPOSITION AND PROCESS OF MAKING

    DOE Patents [OSTI]

    Bishay, A.M.

    1962-09-01

    Glass compositions are described which are suitable for scintillators of thermal-neutron counters. The glass consists of from 70 to 75 mole% of B/sub 2/O/ sub 3/, from 7 to 9 mole% of Ce/sub 2/O/sub 3/, and from 23 to 16 mole% of Al/sub 2/O/sub 3/ plus Na/sub 2 /O in a mole ratio of 1 to 1.5. The process of making the glass from cerous oxalate, ammonium pentaborate, sodium carbonate, and hydrated alumina in a nonoxidizing atmosphere at 1400-1500 deg C is given. (AEC)

  14. Spin Glasses: Old and New Complexity

    SciTech Connect (OSTI)

    Stein, D. L.

    2011-09-22

    Spin glasses are disordered magnetic systems that exhibit a variety of properties that are characteristic of 'complex systems'. After a brief review of the systems themselves, I will discuss how spin glass concepts have found use in and, in some cases, further advanced areas such as computer science, biology, and other fields: what one might term 'old complexity'. I will then turn to a discussion of more recent concepts and ideas that have flowed from studies of spin glasses, and using these introduce a proposal for a kind of 'new complexity'.

  15. Multiple density layered insulator

    DOE Patents [OSTI]

    Alger, Terry W.

    1994-01-01

    A multiple density layered insulator for use with a laser is disclosed wh provides at least two different insulation materials for a laser discharge tube, where the two insulation materials have different thermoconductivities. The multiple layer insulation materials provide for improved thermoconductivity capability for improved laser operation.

  16. Multiple density layered insulator

    DOE Patents [OSTI]

    Alger, T.W.

    1994-09-06

    A multiple density layered insulator for use with a laser is disclosed which provides at least two different insulation materials for a laser discharge tube, where the two insulation materials have different thermoconductivities. The multiple layer insulation materials provide for improved thermoconductivity capability for improved laser operation. 4 figs.

  17. Impact Of Particle Agglomeration On Accumulation Rates In The Glass Discharge Riser Of HLW Melter

    SciTech Connect (OSTI)

    Kruger, A. A.; Rodriguez, C. A.; Matyas, J.; Owen, A. T.; Jansik, D. P.; Lang, J. B.

    2012-11-12

    The major factor limiting waste loading in continuous high-level radioactive waste (HLW) melters is an accumulation of particles in the glass discharge riser during a frequent and periodic idling of more than 20 days. An excessive accumulation can produce robust layers a few centimeters thick, which may clog the riser, preventing molten glass from being poured into canisters. Since the accumulation rate is driven by the size of particles we investigated with x-ray microtomography, scanning electron microscopy, and image analysis the impact of spinel forming components, noble metals, and alumina on the size, concentration, and spatial distribution of particles, and on the accumulation rate. Increased concentrations of Fe and Ni in the baseline glass resulted in the formation of large agglomerates that grew over the time to an average size of ~185+-155 {mu}m, and produced >3 mm thick layer after 120 h at 850 deg C. The noble metals decreased the particle size, and therefore significantly slowed down the accumulation rate. Addition of alumina resulted in the formation of a network of spinel dendrites which prevented accumulation of particles into compact layers.

  18. Analysis of the Younger Dryas Impact Layer

    SciTech Connect (OSTI)

    Firestone, Richard B.; West, Allen; Revay, Zsolt; Hagstrum, Jonathon T,; Belgya, Thomas; Hee, Shane S. Que; Smith, Alan R.

    2010-02-27

    We have uncovered a thin layer of magnetic grains and microspherules, carbon spherules, and glass-like carbon at nine sites across North America, a site in Belgium, and throughout the rims of 16 Carolina Bays. It is consistent with the ejecta layer from an impact event and has been dated to 12.9 ka BP coinciding with the onset of Younger Dryas (YD) cooling and widespread megafaunal extinctions in North America. At many locations the impact layer is directly below a black mat marking the sudden disappearance of the megafauna and Clovis people. The distribution pattern of the Younger Dryas boundary (YDB) ejecta layer is consistent with an impact near the Great Lakes that deposited terrestrial-like ejecta near the impact site and unusual, titanium-rich projectile-like ejecta further away. High water content associated with the ejecta, up to 28 at. percent hydrogen (H), suggests the impact occurred over the Laurentide Ice Sheet. YDB microspherules and magnetic grains are highly enriched in TiO{sub 2}. Magnetic grains from several sites are enriched in iridium (Ir), up to 117 ppb. The TiO{sub 2}/FeO, K/Th, TiO{sub 2}/Zr, Al{sub 2}O{sub 3}/FeO+MgO, CaO/Al{sub 2}O{sub 3}, REE/ chondrite, FeO/MnO ratios and SiO{sub 2}, Na{sub 2}O, K{sub 2}O, Cr{sub 2}O{sub 3}, Ni, Co, U, Th and other trace element abundances are inconsistent with all terrestrial and extraterrestrial (ET) sources except for KREEP, a lunar igneous rock rich in potassium (K), rare-earth elements (REE), phosphorus (P), and other incompatible elements including U and Th. Normal Fe, Ti, and {sup 238}U/{sup 235}U isotopic abundances were found in the magnetic grains, but {sup 234}U was enriched over equilibrium values by 50 percent in Murray Springs and by 130 percent in Belgium. 40K abundance is enriched by up to 100 percent in YDB sediments and Clovis chert artifacts. Highly vesicular carbon spherules containing nanodiamonds, glass-like carbon, charcoal and soot found in large quantities in the YDB layer are

  19. Multiple layer insulation cover

    DOE Patents [OSTI]

    Farrell, James J.; Donohoe, Anthony J.

    1981-11-03

    A multiple layer insulation cover for preventing heat loss in, for example, a greenhouse, is disclosed. The cover is comprised of spaced layers of thin foil covered fabric separated from each other by air spaces. The spacing is accomplished by the inflation of spaced air bladders which are integrally formed in the cover and to which the layers of the cover are secured. The bladders are inflated after the cover has been deployed in its intended use to separate the layers of the foil material. The sizes of the material layers are selected to compensate for sagging across the width of the cover so that the desired spacing is uniformly maintained when the cover has been deployed. The bladders are deflated as the cover is stored thereby expediting the storage process and reducing the amount of storage space required.

  20. Development of Advanced CdTe Solar Cells Based on High Temperature Corning Glass Substrates: Cooperative Research and Development Final Report, CRADA Number CRD-10-373

    SciTech Connect (OSTI)

    Barnes, T.

    2013-08-01

    NREL has developed advanced processes for CdTe solar cells, but because of the temperature limitations of conventional soda lime glass, many of these processes have not been transferred to manufacturing. Corning is developing high temperature substrate glasses that are believed to be manufacturable and will lead to lower $/watt modules costs. The purpose of this CRADA is to evaluate these glasses in the advanced NREL processes. In addition, the CRADA seeks to develop manufacturable processes for transparent conductive oxide layers based on cadmium stannate.

  1. Multilayered Glass Fibre-reinforced Composites In Rotational Moulding

    SciTech Connect (OSTI)

    Chang, W. C.; Harkin-Jones, E. [School of Mechanical and Aerospace Engineering, Queen's University Belfast, Ashby Building, Stranmillis Road, Belfast BT9 5AH, Northern Ireland (United Kingdom); Kearns, M.; McCourt, M. [Polymer Processing Research Centre, Queen's University Belfast, Ashby Building, Stranmillis Road, Belfast BT9 5AH Northern Ireland (United Kingdom)

    2011-05-04

    The potential of multiple layer fibre-reinforced mouldings is of growing interest to the rotational moulding industry because of their cost/performance ratio. The particular problem that arises when using reinforcements in this process relate to the fact that the process is low shear and good mixing of resin and reinforcement is not optimum under those conditions. There is also a problem of the larger/heavier reinforcing agents segregating out of the powder to lay up on the inner part surface. In this study, short glass fibres were incorporated and distributed into a polymer matrix to produce fibre-reinforced polymer composites using the rotational moulding process and characterised in terms of morphology and mechanical properties.

  2. Structure and constitution of glass and steel compound in glass-metal composite

    SciTech Connect (OSTI)

    Lyubimova, Olga N.; Morkovin, Andrey V.; Dryuk, Sergey A.; Nikiforov, Pavel A.

    2014-11-14

    The research using methods of optical and scanning electronic microscopy was conducted and it discovered common factors on structures and diffusing zone forming after welding glass C49-1 and steel Ct3sp in technological process of creating new glass-metal composite. Different technological modes of steel surface preliminary oxidation welded with and without glass were investigated. The time of welding was varied from minimum encountering time to the time of stabilizing width of diffusion zone.

  3. Properties of a solar alumina-borosilicate sheet glass

    SciTech Connect (OSTI)

    Coyle, R.T.; Lind, M.A.; Shelby, J.E.; Vitko, J.; Shoemaker, A.F.

    1980-01-01

    Solar energy applications place unique requirements on sheet glass including very low solar absorption, outstanding stability of absorption in the outdoor environment, low cost, and elastic formability for making concentrating mirrors. The Solar Energy Research Institute and Corning Glass Works have developed a new solar sheet glass. In evaluations reported the new glass has shown outstanding chemical durability and optical and mechanical properties.

  4. Community Geothermal Technology Program: Hawaii glass project. Final report

    SciTech Connect (OSTI)

    Miller, N.; Irwin, B.

    1988-01-20

    Objective was to develop a glass utilizing the silica waste material from geothermal energy production, and to supply local artists with this glass to make artistic objects. A glass composed of 93% indigenous Hawaiian materials was developed; 24 artists made 110 objects from this glass. A market was found for art objects made from this material.

  5. Glass/polymer composites and methods of making

    DOE Patents [OSTI]

    Samuels, W. D.; Exarhos, Gregory J.

    1995-01-01

    The present invention relates to new glass/polymer composites and methods for making them. More specifically, the invention is glass/polymer composites having phases that are at the molecular level and thereby practicably indistinguishable. The invention further discloses making molecular phase glass/polymer composites by mixing a glass and a polymer in a compatible solvent.

  6. Glass/polymer composites and methods of making

    DOE Patents [OSTI]

    Samuels, W.D.; Exarhos, G.J.

    1995-06-06

    The present invention relates to new glass/polymer composites and methods for making them. More specifically, the invention is glass/polymer composites having phases that are at the molecular level and thereby practicably indistinguishable. The invention further discloses making molecular phase glass/polymer composites by mixing a glass and a polymer in a compatible solvent.

  7. Model for TCLP Releases from Waste Glasses

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Vienna, John D.

    2003-05-01

    A first-order property model for normalized Toxicity Characteristic Leaching Procedure (TCLP) release as a function of glass composition was developed using data collected from various studies. The normalized boron release is used to estimate the release of toxic elements based on the observation that the boron release represents the conservative release for those constituents of interest. The current TCLP model has two targeted application areas: (1) delisting of waste-glass product as radioactive (not mixed) waste and (2) designating the glass wastes generated from waste-glass research activities as hazardous or non-hazardous. This report describes the data collection and model development for TCLP releases and discusses the issues related to the application of the model.

  8. The Thermal Collector With Varied Glass Covers

    SciTech Connect (OSTI)

    Luminosu, I.; Pop, N.

    2010-08-04

    The thermal collector with varied glass covers represents an innovation realized in order to build a collector able to reach the desired temperature by collecting the solar radiation from the smallest surface, with the highest efficiency. In the case of the thermal collector with variable cover glasses, the number of the glass plates covering the absorber increases together with the length of the circulation pipe for the working fluid. The thermal collector with varied glass covers compared to the conventional collector better meet user requirements because: for the same temperature increase, has the collecting area smaller; for the same collection area, realizes the highest temperature increase and has the highest efficiency. This works is addressed to researchers in the solar energy and to engineers responsible with air-conditioning systems design or industrial and agricultural products drying.

  9. Preparation of fullerene/glass composites

    DOE Patents [OSTI]

    Mattes, B.R.; McBranch, D.W.; Robinson, J.M.; Koskelo, A.C.; Love, S.P.

    1995-05-30

    Synthesis of fullerene/glass composites is described. A direct method for preparing solid solutions of C{sub 60} in silicon dioxide (SiO{sub 2}) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these ``guests`` in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C{sub 60}. Depending upon the preparative procedure, C{sub 60} dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C{sub 60} in a solid glass matrix, is generated by the present method.

  10. Preparation of fullerene/glass composites

    DOE Patents [OSTI]

    Mattes, Benjamin R.; McBranch, Duncan W.; Robinson, Jeanne M.; Koskelo, Aaron C.; Love, Steven P.

    1995-01-01

    Synthesis of fullerene/glass composites. A direct method for preparing solid solutions of C.sub.60 in silicon dioxide (SiO.sub.2) glass matrices by means of sol-gel chemistry is described. In order to produce highly concentrated fullerene-sol-gel-composites it is necessary to increase the solubility of these "guests" in a delivery solvent which is compatible with the starter sol (receiving solvent). Sonication results in aggregate disruption by treatment with high frequency sound waves, thereby accelerating the rate of hydrolysis of the alkoxide precursor, and the solution process for the C.sub.60. Depending upon the preparative procedure, C.sub.60 dispersed within the glass matrix as microcrystalline domains, or dispersed as true molecular solutions of C.sub.60 in a solid glass matrix, is generated by the present method.

  11. Superhydrophilic Nanostructure for Antifogging Glass - Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Publication LBNL Commercial Analysis Report (103 KB) A glass slide was placed in a freezer (at -15C) and then exposed to humid air at room temperature. The uncoated...

  12. Tiny Glass Bubbles With Big Potential

    Broader source: Energy.gov [DOE]

    If these glass microspheres' walls could talk…They would explain how their tiny pores allow the potential for handling, storing and transporting a variety of materials, including drugs that have...

  13. Glass Furnace Combustion and Melting Research Facility.

    SciTech Connect (OSTI)

    Connors, John J.; McConnell, John F.; Henry, Vincent I.; MacDonald, Blake A.; Gallagher, Robert J.; Field, William B.; Walsh, Peter M.; Simmons, Michael C.; Adams, Michael E.; Leadbetter, James M.; Tomasewski, Jack W.; Operacz, Walter J.; Houf, William G.; Davis, James W.; Marvin, Bart G.; Gunner, Bruce E.; Farrell, Rick G.; Bivins, David P.; Curtis, Warren; Harris, James E.

    2004-08-01

    The need for a Combustion and Melting Research Facility focused on the solution of glass manufacturing problems common to all segments of the glass industry was given high priority in the earliest version of the Glass Industry Technology Roadmap (Eisenhauer et al., 1997). Visteon Glass Systems and, later, PPG Industries proposed to meet this requirement, in partnership with the DOE/OIT Glass Program and Sandia National Laboratories, by designing and building a research furnace equipped with state-of-the-art diagnostics in the DOE Combustion Research Facility located at the Sandia site in Livermore, CA. Input on the configuration and objectives of the facility was sought from the entire industry by a variety of routes: (1) through a survey distributed to industry leaders by GMIC, (2) by conducting an open workshop following the OIT Glass Industry Project Review in September 1999, (3) from discussions with numerous glass engineers, scientists, and executives, and (4) during visits to glass manufacturing plants and research centers. The recommendations from industry were that the melting tank be made large enough to reproduce the essential processes and features of industrial furnaces yet flexible enough to be operated in as many as possible of the configurations found in industry as well as in ways never before attempted in practice. Realization of these objectives, while still providing access to the glass bath and combustion space for optical diagnostics and measurements using conventional probes, was the principal challenge in the development of the tank furnace design. The present report describes a facility having the requirements identified as important by members of the glass industry and equipped to do the work that the industry recommended should be the focus of research. The intent is that the laboratory would be available to U.S. glass manufacturers for collaboration with Sandia scientists and engineers on both precompetitive basic research and the

  14. High thermal expansion, sealing glass

    DOE Patents [OSTI]

    Brow, Richard K.; Kovacic, Larry

    1993-01-01

    A glass composition for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na.sub.2 O, between about 10 and about 25 mole percent K.sub.2 O, between about 5 and about 15 mole percent Al.sub.2 O.sub.3, between about 35 and about 50 mole percent P.sub.2 O.sub.5 and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe.sub.2 O.sub.3 and between 0 and about 10 mole percent B.sub.2 O.sub.3, has a thermal expansion coefficient in a range of between about 160 and 210.times.10-7/.degree.C. and a dissolution rate in a range of between about 2.times.10.sup.- 7 and 2.times.10.sup.-9 g/cm.sup.2 -min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.

  15. High thermal expansion, sealing glass

    DOE Patents [OSTI]

    Brow, R.K.; Kovacic, L.

    1993-11-16

    A glass composition is described for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na[sub 2]O, between about 10 and about 25 mole percent K[sub 2]O, between about 5 and about 15 mole percent Al[sub 2]O[sub 3], between about 35 and about 50 mole percent P[sub 2]O[sub 5] and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe[sub 2]O[sub 3] and between 0 and about 10 mole percent B[sub 2]O[sub 3], has a thermal expansion coefficient in a range of between about 160 and 210[times]10[sup [minus]7]/C and a dissolution rate in a range of between about 2[times]10[sup [minus]7] and 2[times]10[sup [minus]9]g/cm[sup 2]-min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.

  16. Compositional Models of Glass/Melt Properties and their Use for Glass Formulation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vienna, John D.; USA, Richland Washington

    2014-12-18

    Nuclear waste glasses must simultaneously meet a number of criteria related to their processability, product quality, and cost factors. The properties that must be controlled in glass formulation and waste vitrification plant operation tend to vary smoothly with composition allowing for glass property-composition models to be developed and used. Models have been fit to the key glass properties. The properties are transformed so that simple functions of composition (e.g., linear, polynomial, or component ratios) can be used as model forms. The model forms are fit to experimental data designed statistically to efficiently cover the composition space of interest. Examples ofmore » these models are found in literature. The glass property-composition models, their uncertainty definitions, property constraints, and optimality criteria are combined to formulate optimal glass compositions, control composition in vitrification plants, and to qualify waste glasses for disposal. An overview of current glass property-composition modeling techniques is summarized in this paper along with an example of how those models are applied to glass formulation and product qualification at the planned Hanford high-level waste vitrification plant.« less

  17. Compositional Models of Glass/Melt Properties and their Use for Glass Formulation

    SciTech Connect (OSTI)

    Vienna, John D. [Pacific Northwest National Laboratory; Richland Washington USA

    2014-12-18

    Nuclear waste glasses must simultaneously meet a number of criteria related to their processability, product quality, and cost factors. The properties that must be controlled in glass formulation and waste vitrification plant operation tend to vary smoothly with composition allowing for glass property-composition models to be developed and used. Models have been fit to the key glass properties. The properties are transformed so that simple functions of composition (e.g., linear, polynomial, or component ratios) can be used as model forms. The model forms are fit to experimental data designed statistically to efficiently cover the composition space of interest. Examples of these models are found in literature. The glass property-composition models, their uncertainty definitions, property constraints, and optimality criteria are combined to formulate optimal glass compositions, control composition in vitrification plants, and to qualify waste glasses for disposal. An overview of current glass property-composition modeling techniques is summarized in this paper along with an example of how those models are applied to glass formulation and product qualification at the planned Hanford high-level waste vitrification plant.

  18. THE COLOUR GLASS CONDENSATE: AN INTRODUCTION

    SciTech Connect (OSTI)

    IANCU,E.; LEONIDOV,A.; MCLERRAN,L.

    2001-08-06

    In these lectures, the authors develop the theory of the Colour Glass Condensate. This is the matter made of gluons in the high density environment characteristic of deep inelastic scattering or hadron-hadron collisions at very high energy. The lectures are self contained and comprehensive. They start with a phenomenological introduction, develop the theory of classical gluon fields appropriate for the Colour Glass, and end with a derivation and discussion of the renormalization group equations which determine this effective theory.

  19. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bioactive Glass Scaffolds for Bone Regeneration Bioactive Glass Scaffolds for Bone Regeneration Print Wednesday, 28 September 2011 00:00 Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their

  20. High expansion, lithium corrosion resistant sealing glasses

    DOE Patents [OSTI]

    Brow, Richard K.; Watkins, Randall D.

    1991-01-01

    Glass compositions containing CaO, Al.sub.2 O.sub.3, B.sub.2 O.sub.3, SrO and BaO in various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with pin materials of 446 Stainless Steel and Alloy-52 rather than molybdenum, for use in harsh chemical environments, specifically in lithium batteries.

  1. High expansion, lithium corrosion resistant sealing glasses

    DOE Patents [OSTI]

    Brow, R.K.; Watkins, R.D.

    1991-06-04

    Glass compositions containing CaO, Al[sub 2]O[sub 3], B[sub 2]O[sub 3], SrO and BaO in various combinations of mole % are provided. These compositions are capable of forming stable glass-to-metal seals with pin materials of 446 Stainless Steel and Alloy-52 rather than molybdenum, for use in harsh chemical environments, specifically in lithium batteries.

  2. Quarks in the looking glass | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quarks in the looking glass Quarks in the looking glass Jefferson Lab's Experimental Hall A The electron-quark scattering experiment was carried out in Jefferson Lab's Experimental Hall A. In this view from the floor of the hall, the two High Resolution Spectrometers are shown with their shield house doors (white) open. Photo: Jefferson Lab NEWPORT NEWS, VA, Feb. 5, 2014 - From matching wings on butterflies to the repeating six-point pattern of snowflakes, symmetries echo through nature, even

  3. Structural rejuvenation in bulk metallic glasses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tong, Yang; Iwashita, T.; Dmowski, Wojciech; Bei, Hongbin; Yokoyama, Y.; Egami, Takeshi

    2015-01-05

    Using high-energy X-ray diffraction we study structural changes in bulk metallic glasses after uniaxial compressive homogeneous deformation at temperatures slightly below the glass transition. We observe that deformation results in structural disordering corresponding to an increase in the fictive, or effective, temperature. However, the structural disordering saturates after yielding. Lastly, examination of the experimental structure and molecular dynamics simulation suggests that local changes in the atomic connectivity network are the main driving force of the structural rejuvenation.

  4. Compliant layer chucking surface

    DOE Patents [OSTI]

    Blaedel, Kenneth L.; Spence, Paul A.; Thompson, Samuel L.

    2004-12-28

    A method and apparatus are described wherein a thin layer of complaint material is deposited on the surface of a chuck to mitigate the deformation that an entrapped particle might cause in the part, such as a mask or a wafer, that is clamped to the chuck. The harder particle will embed into the softer layer as the clamping pressure is applied. The material composing the thin layer could be a metal or a polymer for vacuum or electrostatic chucks. It may be deposited in various patterns to affect an interrupted surface, such as that of a "pin" chuck, thereby reducing the probability of entrapping a particle.

  5. Boundary Layer Structure:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Boundary Layer Structure: a comparison between methods and sites Thiago Biscaro Suzane de Sá Jae-In Song Shaoyue "Emily" Qiu Mentors: Virendra Ghate and Ewan O'Connor July 24 2015 1 st ever ARM Summer Training Outline * IntroducQon * Methodology * Results - SGP - MAO - Comparison between the 2 sites * Conclusions INTRODUCTION Focus: esQmates of PBL height Boundary Layer: "The boUom layer of the troposphere that is in contact with the surface of the earth." (AMS, Glossary of

  6. ROAD MAP FOR DEVELOPMENT OF CRYSTAL-TOLERANT HIGH LEVEL WASTE GLASSES

    SciTech Connect (OSTI)

    Fox, K.; Peeler, D.; Herman, C.

    2014-05-15

    The U.S. Department of Energy (DOE) is building a Tank Waste Treatment and Immobilization Plant (WTP) at the Hanford Site in Washington to remediate 55 million gallons of radioactive waste that is being temporarily stored in 177 underground tanks. Efforts are being made to increase the loading of Hanford tank wastes in glass while meeting melter lifetime expectancies and process, regulatory, and product quality requirements. This road map guides the research and development for formulation and processing of crystaltolerant glasses, identifying near- and long-term activities that need to be completed over the period from 2014 to 2019. The primary objective is to maximize waste loading for Hanford waste glasses without jeopardizing melter operation by crystal accumulation in the melter or melter discharge riser. The potential applicability to the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF) will also be addressed in this road map. The planned research described in this road map is motivated by the potential for substantial economic benefits (significant reductions in glass volumes) that will be realized if the current constraints (T1% for WTP and TL for DWPF) are approached in an appropriate and technically defensible manner for defense waste and current melter designs. The basis of this alternative approach is an empirical model predicting the crystal accumulation in the WTP glass discharge riser and melter bottom as a function of glass composition, time, and temperature. When coupled with an associated operating limit (e.g., the maximum tolerable thickness of an accumulated layer of crystals), this model could then be integrated into the process control algorithms to formulate crystal-tolerant high-level waste (HLW) glasses targeting high waste loadings while still meeting process related limits and melter lifetime expectancies. The modeling effort will be an iterative process, where model form and a broader range of conditions, e.g., glass

  7. Innovative Exploration Technologies Maui Hawaii & Glass Buttes, Oregon |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Maui Hawaii & Glass Buttes, Oregon Innovative Exploration Technologies Maui Hawaii & Glass Buttes, Oregon Innovative Exploration Technologies Maui Hawii & Glass Buttes, Oregon presentation at the April 2013 peer review meeting held in Denver, Colorado. moui_glass_buttes_ormat_peer2013.pdf (1.01 MB) More Documents & Publications Innovative Exploration Technologies Maui Hawaii & Glass Buttes, Oregon Blind Geothermal System Exploration in Active Volcanic

  8. Innovative Exploration Technologies Maui Hawaii & Glass Buttes, Oregon |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Technologies Maui Hawaii & Glass Buttes, Oregon Innovative Exploration Technologies Maui Hawaii & Glass Buttes, Oregon Innovative Exploration Technologies Maui Hawii & Glass Buttes, Oregon presentation at the April 2013 peer review meeting held in Denver, Colorado. maui_glass_buttes_ormat_peer2013.pdf (1.01 MB) More Documents & Publications Innovative Exploration Technologies Maui Hawaii & Glass Buttes, Oregon Blind Geothermal System Exploration in

  9. Sealed glass coating of high temperature ceramic superconductors

    DOE Patents [OSTI]

    Wu, Weite; Chu, Cha Y.; Goretta, Kenneth C.; Routbort, Jules L.

    1995-01-01

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

  10. Joint EM-NE-International Study of Glass Behavior over Geologic Time Scales - 12303

    SciTech Connect (OSTI)

    Ryan, J.V.; Schreiber, D.K.; Strachan, D.M.; Vienna, J.D. [Pacific Northwest National Laboratory, P. O. Box 999, Richland, WA 99352 (United States); Ebert, W.L. [Argonne National Laboratory, Argonne, IL 60439 (United States); Icenhower, J.P. [Lawrence Berkeley National Laboratory, One Cyclotron Road, Berkeley, CA 94720 (United States)

    2012-07-01

    Vitrification has been chosen as the best demonstrated available technology for waste immobilization worldwide. To date, the contributions of physical and chemical processes controlling the long-term glass dissolution rate in geologic disposal remain uncertain, leading to a lack of international consensus on a rate law for glass corrosion. Existing rate laws have overcome uncertainty through conservatism, but a thorough mechanistic understanding of waste form durability in geologic environments would improve public and regulator confidence. If it is possible to take credit for the true durability of the waste form in repository system evaluations, then it is possible to design the repository with less conservatism with concomitant cost savings. To gain a fundamental understanding of the dissolution rate law, six nations have joined together to formulate a joint plan for collaborative research into the mechanisms controlling the long-term corrosion of glass. This report highlights the technical program plan behind the US portion of this effort, with an emphasis on the current understanding (and limitations) of several mechanistic theories for glass corrosion. Some recent results are presented to provide an example of the ongoing research. Atom probe tomography has been used to provide a high-resolution analysis of elemental concentration gradients present at the hydrated glass / pristine glass interface in SON68 after 25.75 years of corrosion in a simulated granitic groundwater at 90 deg. C. The most valuable result of these initial studies is the success of the technique. Characterization by APT had never been previously demonstrated for glass corrosion layers. The resolution of APT is a powerful addition to the tools with which we can investigate the mechanisms dominating glass corrosion. Some other key results of this study include the observation that the elemental interfacial width between the hydrated glass and pristine glass appears to be much sharper (?2 nm

  11. Exploration and Modeling of Structural changes in Waste Glass Under Corrosion

    SciTech Connect (OSTI)

    Pantano, Carlos; Ryan, Joseph; Strachan, Denis

    2013-11-10

    Vitrification is currently the world-wide treatment of choice for the disposition of high-level nuclear wastes. In glasses, radionuclides are atomistically bonded into the solid, resulting in a highly durable product, with borosilicate glasses exhibiting particularly excellent durability in water. Considering that waste glass is designed to retain the radionuclides within the waste form for long periods, it is important to understand the long-term stability of these materials when they react in the environment, especially in the presence of water. Based on a number of previous studies, there is general consensus regarding the mechanisms controlling the initial rate of nuclear waste glass dissolution. Agreement regarding the cause of the observed decrease in dissolution rate at extended times, however, has been elusive. Two general models have been proposed to explain this behavior, and it has been concluded that both concepts are valid and must be taken into account when considering the decrease in dissolution rate. Furthermore, other processes such as water diffusion, ion exchange, and precipitation of mineral phases onto the glass surface may occur in parallel with dissolution of the glass and can influence long-term performance. Our proposed research will address these issues through a combination of aqueous-phase dissolution/reaction experiments and probing of the resulting surface layers with state-of-the-art analytical methods. These methods include solid-state nuclear magnetic resonance (SSNMR) and time-of-flight secondary ion mass spectrometry (TOF-SIMS). The resulting datasets will then be coupled with computational chemistry and reaction-rate modeling to address the most persistent uncertainties in the understanding of glass corrosion, which indeed have limited the performance of the best corrosion models to date. With an improved understanding of corrosion mechanisms, models can be developed and improved that, while still conservative, take advantage of

  12. Structured luminescence conversion layer

    DOE Patents [OSTI]

    Berben, Dirk; Antoniadis, Homer; Jermann, Frank; Krummacher, Benjamin Claus; Von Malm, Norwin; Zachau, Martin

    2012-12-11

    An apparatus device such as a light source is disclosed which has an OLED device and a structured luminescence conversion layer deposited on the substrate or transparent electrode of said OLED device and on the exterior of said OLED device. The structured luminescence conversion layer contains regions such as color-changing and non-color-changing regions with particular shapes arranged in a particular pattern.

  13. Silicon-on-glass pore network micromodels with oxygen-sensing fluorophore films for chemical imaging and defined spatial structure

    SciTech Connect (OSTI)

    Grate, Jay W.; Kelly, Ryan T.; Suter, Jonathan D.; Anheier, Norman C.

    2012-11-21

    Pore network microfluidic models were fabricated by a silicon-on-glass technique that provides the precision advantage of dry etched silicon while creating a structure that is transparent across all microfluidic channels and pores, and can be imaged from either side. A silicon layer is bonded to an underlying borosilicate glass substrate and thinned to the desired height of the microfluidic channels and pores. The silicon is then patterned and through-etched by deep reactive ion etching (DRIE), with the underlying glass serving as an etch stop. After bonding on a transparent glass cover plate, one obtains a micromodel in oxygen impermeable materials with water wet surfaces where the microfluidic channels are transparent and structural elements such as the pillars creating the pore network are opaque. The micromodel can be imaged from either side. The advantageous features of this approach in a chemical imaging application are demonstrated by incorporating a Pt porphyrin fluorophore in a PDMS film serving as the oxygen sensing layer and a bonding surface, or in a polystyrene film coated with a PDMS layer for bonding. The sensing of a dissolved oxygen gradient was demonstrated using fluorescence lifetime imaging, and it is shown that different matrix polymers lead to optimal use in different ranges dissolved oxygen concentration. Imaging with the opaque pillars in between the observation direction and the continuous fluorophore film yields images that retain spatial information in the sensor image.

  14. An Insulating Glass Knowledge Base

    SciTech Connect (OSTI)

    Michael L. Doll; Gerald Hendrickson; Gerard Lagos; Russell Pylkki; Chris Christensen; Charlie Cureija

    2005-08-01

    This report will discuss issues relevant to Insulating Glass (IG) durability performance by presenting the observations and developed conclusions in a logical sequential format. This concluding effort discusses Phase II activities and focuses on beginning to quantifying IG durability issues while continuing the approach presented in the Phase I activities (Appendix 1) which discuss a qualitative assessment of durability issues. Phase II developed a focus around two specific IG design classes previously presented in Phase I of this project. The typical box spacer and thermoplastic spacer design including their Failure Modes and Effect Analysis (FMEA) and Fault Tree diagrams were chosen to address two currently used IG design options with varying components and failure modes. The system failures occur due to failures of components or their interfaces. Efforts to begin quantifying the durability issues focused on the development and delivery of an included computer based IG durability simulation program. The focus/effort to deliver the foundation for a comprehensive IG durability simulation tool is necessary to address advancements needed to meet current and future building envelope energy performance goals. This need is based upon the current lack of IG field failure data and the lengthy field observation time necessary for this data collection. Ultimately, the simulation program is intended to be used by designers throughout the current and future industry supply chain. Its use is intended to advance IG durability as expectations grow around energy conservation and with the growth of embedded technologies as required to meet energy needs. In addition the tool has the immediate benefit of providing insight for research and improvement prioritization. Included in the simulation model presentation are elements and/or methods to address IG materials, design, process, quality, induced stress (environmental and other factors), validation, etc. In addition, acquired data

  15. Glass science tutorial: Lecture No. 4, commercial glass melting and associated air emission issues

    SciTech Connect (OSTI)

    Kruger, A.A.

    1995-01-01

    This document serves as a manual for a workshop on commercial glass melting and associated air emission issues. Areas covered include: An overview of the glass industry; Furnace design and construction practices; Melting furnace operation; Energy input methods and controls; Air legislation and regulations; Soda lime emission mechanisms; and, Post furnace emission controls. Supporting papers are also included.

  16. Magnetic behavior of erbium-zinc-borate glasses and glass ceramics

    SciTech Connect (OSTI)

    Borodi, G.; Pascuta, P.; Bosca, M.; Pop, V.; Stefan, R.; Tetean, R.; Radulescu, D.

    2013-11-13

    Glasses of the system (Er{sub 2}O{sub 3}){sub x}⋅(B{sub 2}O{sub 3}){sub (60−x)}⋅(ZnO){sub 40} (3 ≤ x ≤ 15 mol%) were prepared by conventional melt quenching and subsequently converted to glass ceramics by heat treatment of glass samples at 860 °C for 2 h. The magnetic behaviour of the studied glasses and glass ceramics were investigated using a vibrating sample magnetometer (VSM) and a Faraday-type magnetic balance. Magnetic data show that erbium ions are involved in negative superexchange interactions in all the investigated samples, being antiferromagnetically coupled. For all studied samples the experimental values obtained for the effective magnetic moments are lower than the value corresponding to free Er{sup 3+} ions and decrease with the increasing of Er{sub 2}O{sub 3} content. The decrease is more pronounced in heat treated samples than untreated ones.

  17. Transport properties of lithium- lead-vanadium-telluride glass and glass ceramics

    SciTech Connect (OSTI)

    Sathish, M.; Eraiah, B.

    2014-04-24

    Glasses with the chemical composition 35Li{sub 2}O-(45-x)V{sub 2}O{sub 5?}20PbO-xTeO{sub 2} (where x = 2.5, 5, 7.5, 10, 15 mol %) have prepared by conventional melt quenching method. The electrical conductivity of Li{sup +} ion conducting lead vanadium telluride glass samples has been carried out both as a function of temperature and frequency in the temperature range 503K-563K and over frequencies 40 Hz to 10 MHz. The electronic conduction has been observed in the present systems. When these samples annealed around 400C for 2hour become the glass ceramic, which also shows increase tendency of conductivity. SEM confines glass and glass ceramic nature of the prepared samples.

  18. GLASS AND GLASS-DERIVATIVE SEALS FOR USE IN ENERGY-EFFICIENT FUEL CELLS AND LAMPS

    SciTech Connect (OSTI)

    Scott Misture; Arun Varshneya; Matthew Hall; Sylvia DeCarr; Steve Bancheri

    2004-08-15

    As the project approaches the end of the first year, the materials screening components of the work are ahead of schedule, while all other tasks are on schedule. For solid oxide fuel cells (SOFC), a series of 16 sealing glasses have been prepared and characterized. Traditional melting was used to prepare all of the glasses, and the sol-gel approach has been used to prepare some of the glasses as well as other compositions that might be viable because of the low processing temperatures afforded by the sol-gel method. The glass characterization included measurements of the viscosity and thermal expansion of the glasses, as well as the thermal expansion of the partly crystalline glass ceramics. In addition, the wetting and sintering behavior of all glasses has been measured, as well as the crystallization behavior. The time and temperature at which crystalline phases form from the glasses has been determined for all of the glasses. Each glass ceramic contains at least two crystalline phases, and most of the crystalline phases have been positively identified. Room temperature leak testing has been completed for all sealants, and experiments are in progress to determine the DC electrochemical degradation and degradation in wet hydrogen. The second component of the work, focused on seals for higher-temperature discharge lighting, has focused on determining the phase relations in the yttria--alumina--silica system at various silica levels. Again, traditional melting and sol-gel synthesis have been employed, and the sol-gel method was successful for preparing new phases that were discovered during the work. High temperature diffraction and annealing studies have clarified the phase relations for the samples studies, although additional work remains. Four new phases have been identified and synthesized in pure form, from which full structure solutions were obtained as well as the anisotropic thermal expansion for each phase. Functional testing of lamps are on on-going and

  19. Measurement and Control of Glass Feedstocks

    SciTech Connect (OSTI)

    Arel Weisberg

    2007-04-26

    ERCo has developed a laser-based technology for rapid compositional measurements of batch, real-time sorting of cullet, and in-situ measurements of molten glass. This technology, termed LIBS (Laser Induced Breakdown Spectroscopy) can determine whether or not the batch was formulated accurately in order to control glass quality. It can also be used to determine if individual batch ingredients are within specifications. In the case of cullet feedstocks, the sensor can serve as part of a system to sort cullet by color and ensure that it is free of contaminants. In-situ compositional measurements of molten glass are achieved through immersing a LIBS probe directly into the melt in a glass furnace. This technology has been successfully demonstrated in ERCo’s LIBS laboratory for batch analysis, cullet sorting, and glass melt measurements. A commercial batch analyzer has been operating in a PPG fiberglass plant since August 2004. LIBS utilizes a highly concentrated laser pulse to rapidly vaporize and ionize nanograms of the material being studied. As this vapor cools, it radiates light at specific wavelengths corresponding to the elemental constituents (e.g. silicon, aluminum, iron) of the material. The strengths of the emissions correlate to the concentrations of each of the elemental constituents. By collecting the radiated light with a spectrometer capable of resolving and measuring these wavelengths, the elemental composition of the sample is found.

  20. Sealing glasses for titanium and titanium alloys

    DOE Patents [OSTI]

    Brow, R.K.; McCollister, H.L.; Phifer, C.C.; Day, D.E.

    1997-07-15

    Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B{sub 2}O{sub 3}), barium oxide (BaO), lanthanum oxide (La{sub 2}O{sub 3}), and at least one other oxide selected from the group consisting of aluminum oxide (Al{sub 2}O{sub 3}), calcium oxide (CaO), lithium oxide (Li{sub 2}O), sodium oxide (Na{sub 2}O), silicon dioxide (SiO{sub 2}), or titanium dioxide (TiO{sub 2}). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900 C, and generally about 700--800 C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps). 1 fig.

  1. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P.; Davidson, James C.; Balch, Joseph W.

    2001-01-01

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  2. Vacuum fusion bonding of glass plates

    DOE Patents [OSTI]

    Swierkowski, Steve P.; Davidson, James C.; Balch, Joseph W.

    2000-01-01

    An improved apparatus and method for vacuum fusion bonding of large, patterned glass plates. One or both glass plates are patterned with etched features such as microstructure capillaries and a vacuum pumpout moat, with one plate having at least one hole therethrough for communication with a vacuum pumpout fixture. High accuracy alignment of the plates is accomplished by a temporary clamping fixture until the start of the fusion bonding heat cycle. A complete, void-free fusion bond of seamless, full-strength quality is obtained through the plates; because the glass is heated well into its softening point and because of a large, distributed force that is developed that presses the two plates together from the difference in pressure between the furnace ambient (high pressure) and the channeling and microstructures in the plates (low pressure) due to the vacuum drawn. The apparatus and method may be used to fabricate microcapillary arrays for chemical electrophoresis; for example, any apparatus using a network of microfluidic channels embedded between plates of glass or similar moderate melting point substrates with a gradual softening point curve, or for assembly of glass-based substrates onto larger substrates, such as in flat panel display systems.

  3. Sealing glasses for titanium and titanium alloys

    DOE Patents [OSTI]

    Brow, Richard K.; McCollister, Howard L.; Phifer, Carol C.; Day, Delbert E.

    1997-01-01

    Barium lanthanoborate sealing-glass compositions are provided comprising various combinations (in terms of mole-%) of boron oxide (B.sub.2 O.sub.3), barium oxide (BaO), lanthanum oxide (La.sub.2 O.sub.3), and at least one other oxide selected from the group consisting of aluminum oxide (Al.sub.2 O.sub.3), calcium oxide (CaO), lithium oxide (Li.sub.2 O), sodium oxide (Na.sub.2 O), silicon dioxide (SiO.sub.2), or titanium dioxide (TiO.sub.2). These sealing-glass compositions are useful for forming hermetic glass-to-metal seals with titanium and titanium alloys having an improved aqueous durability and favorable sealing characteristics. Examples of the sealing-glass compositions are provided having coefficients of thermal expansion about that of titanium or titanium alloys, and with sealing temperatures less than about 900.degree. C., and generally about 700.degree.-800.degree. C. The barium lanthanoborate sealing-glass compositions are useful for components and devices requiring prolonged exposure to moisture or water, and for implanted biomedical devices (e.g. batteries, pacemakers, defibrillators, pumps).

  4. Retention of Halogens in Waste Glass

    SciTech Connect (OSTI)

    Hrma, Pavel R.

    2010-05-01

    In spite of their potential roles as melting rate accelerators and foam breakers, halogens are generally viewed as troublesome components for glass processing. Of five halogens, F, Cl, Br, I, and At, all but At may occur in nuclear waste. A nuclear waste feed may contain up to 10 g of F, 4 g of Cl, and ?100 mg of Br and I per kg of glass. The main concern is halogen volatility, producing hazardous fumes and particulates, and the radioactive iodine 129 isotope of 1.7x10^7-year half life. Because F and Cl are soluble in oxide glasses and tend to precipitate on cooling, they can be retained in the waste glass in the form of dissolved constituents or as dispersed crystalline inclusions. This report compiles known halogen-retention data in both high-level waste (HLW) and low-activity waste (LAW) glasses. Because of its radioactivity, the main focus is on I. Available data on F and Cl were compiled for comparison. Though Br is present in nuclear wastes, it is usually ignored; no data on Br retention were found.

  5. Layered electrode for electrochemical cells

    DOE Patents [OSTI]

    Swathirajan, Swathy; Mikhail, Youssef M.

    2001-01-01

    There is provided an electrode structure comprising a current collector sheet and first and second layers of electrode material. Together, the layers improve catalyst utilization and water management.

  6. Research and development of new ultraphosphate laser glasses

    SciTech Connect (OSTI)

    Izumitani, T.; Toratani, H.; Matsukawa, T.; Kanamori, C.; Miyade, H.

    1985-01-30

    Requirements for Zeus laser glass and HAP laser glass were small {sigma}, low water, low concentration quenching and high mechanical and thermal strength in the former and high {sigma}, low water, low concentration quenching and high mechanical, thermal shock resistance in the later. In order to get a high mechanical and thermal shock resistance, we introduced SiO{sub 2} into phosphate glass, because SiO{sub 2} gives a low expansion coefficient. In this report, we discuss the research and development of the laser glass. Chemical durability, water content, lasing properties, mechanical and thermo-mechanical properties, glass composition and glass structures are discussed.

  7. Opal photonic crystals infiltrated with chalcogenide glasses

    SciTech Connect (OSTI)

    Astratov, V. N.; Adawi, A. M.; Skolnick, M. S.; Tikhomirov, V. K.; Lyubin, V.; Lidzey, D. G.; Ariu, M.; Reynolds, A. L.

    2001-06-25

    Composite opal structures for nonlinear applications are obtained by infiltration with chalcogenide glasses As{sub 2}S{sub 3} and AsSe by precipitation from solution. Analysis of spatially resolved optical spectra reveals that the glass aggregates into submillimeter areas inside the opal. These areas exhibit large shifts in the optical stop bands by up to 80 nm, and by comparison with modelling are shown to have uniform glass filling factors of opal pores up to 40%. Characterization of the domain structure of the opals prior to infiltration by large area angle-resolved spectroscopy is an important step in the analysis of the properties of the infiltrated regions. {copyright} 2001 American Institute of Physics.

  8. Glass/ceramic coatings for implants

    DOE Patents [OSTI]

    Tomsia, Antoni P.; Saiz, Eduardo; Gomez-Vega, Jose M.; Marshall, Sally J.; Marshall, Grayson W.

    2011-09-06

    Glass coatings on metals including Ti, Ti6A14V and CrCo were prepared for use as implants. The composition of the glasses was tailored to match the thermal expansion of the substrate metal. By controlling the firing atmosphere, time, and temperature, it was possible to control the reactivity between the glass and the alloy and to fabricate coatings (25-150 .mu.m thick) with excellent adhesion to the substrate. The optimum firing temperatures ranged between 800 and 840.degree. C. at times up to 1 min in air or 15 min in N.sub.2. The same basic technique was used to create multilayered coatings with concentration gradients of hydroxyapatite (HA) particles and SiO.sub.2.

  9. Spectroscopic studies of silver boro tellurite glasses

    SciTech Connect (OSTI)

    Kumar, E. Ramesh Kumari, K. Rajani Rao, B. Appa Bhikshamaiah, G.

    2014-04-24

    The FTIR absorption and Raman scattering studies were used to obtain the structural information of AgI−Ag{sub 2}O−[(1−x)B{sub 2}O{sub 3}−xTeO{sub 2}] (x=0 to 1 mol% in steps of 0.2) glasses. The glassy nature of the compounds has been confirmed by X-ray diffraction. FTIR and Raman spectra were recorded for all samples at room temperature. FTIR spectra which provides the information about the change in bond structure of the glasses. Raman spectra provide the effect of TeO{sub 2} on SBT glass system is that as increasing the concentration of TeO{sub 2} the band intensity at 707 cm{sup −1} increase.

  10. Layered semiconductor neutron detectors

    DOE Patents [OSTI]

    Mao, Samuel S; Perry, Dale L

    2013-12-10

    Room temperature operating solid state hand held neutron detectors integrate one or more relatively thin layers of a high neutron interaction cross-section element or materials with semiconductor detectors. The high neutron interaction cross-section element (e.g., Gd, B or Li) or materials comprising at least one high neutron interaction cross-section element can be in the form of unstructured layers or micro- or nano-structured arrays. Such architecture provides high efficiency neutron detector devices by capturing substantially more carriers produced from high energy .alpha.-particles or .gamma.-photons generated by neutron interaction.

  11. Method of bonding silver to glass and mirrors produced according to this method

    DOE Patents [OSTI]

    Pitts, J.R.; Thomas, T.M.; Czanderna, A.W.

    1984-07-31

    A method for adhering silver to a glass substrate for producing mirrors includes attaining a silicon enriched substrate surface by reducing the oxygen therein in a vacuum and then vacuum depositing a silver layer onto the silicon enriched surface. The silicon enrichment can be attained by electron beam bombardment, ion beam bombardment, or neutral beam bombardment. It can also be attained by depositing a metal, such as aluminum, on the substrate surface, allowing the metal to oxidize by pulling oxygen from the substrate surface, thereby leaving a silicon enriched surface, and then etching or eroding the metal oxide layer away to expose the silicon enriched surface. Ultraviolet rays can be used to maintain dangling silicon bonds on the enriched surface until covalent bonding with the silver can occur. This disclosure also includes encapsulated mirrors with diffusion layers built therein. One of these mirrors is assembled on a polymer substrate.

  12. Method of bonding silver to glass and mirrors produced according to this method

    DOE Patents [OSTI]

    Pitts, John R.; Thomas, Terence M.; Czanderna, Alvin W.

    1985-01-01

    A method for adhering silver to a glass substrate for producing mirrors includes attaining a silicon enriched substrate surface by reducing the oxygen therein in a vacuum and then vacuum depositing a silver layer onto the silicon enriched surface. The silicon enrichment can be attained by electron beam bombardment, ion beam bombardment, or neutral beam bombardment. It can also be attained by depositing a metal, such as aluminum, on the substrate surface, allowing the metal to oxidize by pulling oxygen from the substrate surface, thereby leaving a silicon enriched surface, and then etching or eroding the metal oxide layer away to expose the silicon enriched surface. Ultraviolet rays can be used to maintain dangling silicon bonds on the enriched surface until covalent bonding with the silver can occur. This disclosure also includes encapsulated mirrors with diffusion layers built therein. One of these mirrors is assembled on a polymer substrate.

  13. Two glass transitions in miscible polymer blends?

    SciTech Connect (OSTI)

    Dudowicz, Jacek; Freed, Karl F.; Douglas, Jack F.

    2014-06-28

    In contrast to mixtures of two small molecule fluids, miscible binary polymer blends often exhibit two structural relaxation times and two glass transition temperatures. Qualitative explanations postulate phenomenological models of local concentration enhancements due to chain connectivity in ideal, fully miscible systems. We develop a quantitative theory that explains qualitative trends in the dynamics of real miscible polymer blends which are never ideal mixtures. The theory is a synthesis of the lattice cluster theory of blend thermodynamics, the generalized entropy theory for glass-formation in polymer materials, and the Kirkwood-Buff theory for concentration fluctuations in binary mixtures.

  14. PLUTONIUM SOLUBILITY IN HIGH-LEVEL WASTE ALKALI BOROSILICATE GLASS

    SciTech Connect (OSTI)

    Marra, J.; Crawford, C.; Fox, K.; Bibler, N.

    2011-01-04

    The solubility of plutonium in a Sludge Batch 6 (SB6) reference glass and the effect of incorporation of Pu in the glass on specific glass properties were evaluated. A Pu loading of 1 wt % in glass was studied. Prior to actual plutonium glass testing, surrogate testing (using Hf as a surrogate for Pu) was conducted to evaluate the homogeneity of significant quantities of Hf (Pu) in the glass, determine the most appropriate methods to evaluate homogeneity for Pu glass testing, and to evaluate the impact of Hf loading in the glass on select glass properties. Surrogate testing was conducted using Hf to represent between 0 and 1 wt % Pu in glass on an equivalent molar basis. A Pu loading of 1 wt % in glass translated to {approx}18 kg Pu per Defense Waste Processing Facility (DWPF) canister, or about 10X the current allowed limit per the Waste Acceptance Product Specifications (2500 g/m{sup 3} of glass or about 1700 g/canister) and about 30X the current allowable concentration based on the fissile material concentration limit referenced in the Yucca Mountain Project License Application (897 g/m{sup 3}3 of glass or about 600 g Pu/canister). Based on historical process throughput data, this level was considered to represent a reasonable upper bound for Pu loading based on the ability to provide Pu containing feed to the DWPF. The task elements included evaluating the distribution of Pu in the glass (e.g. homogeneity), evaluating crystallization within the glass, evaluating select glass properties (with surrogates), and evaluating durability using the Product Consistency Test -- Method A (PCT-A). The behavior of Pu in the melter was evaluated using paper studies and corresponding analyses of DWPF melter pour samples.The results of the testing indicated that at 1 wt % Pu in the glass, the Pu was homogeneously distributed and did not result in any formation of plutonium-containing crystalline phases as long as the glass was prepared under 'well-mixed' conditions. The

  15. Zirconia-coated carbonyl-iron-particle-based magnetorheological fluid for polishing optical glasses and ceramics

    SciTech Connect (OSTI)

    Shafrir, Shai N.; Romanofsky, Henry J.; Skarlinski, Michael; Wang, Mimi; Miao, Chunlin; Salzman, Sivan; Chartier, Taylor; Mici, Joni; Lambropoulos, John C.; Shen Rui; Yang Hong; Jacobs, Stephen D.

    2009-12-10

    We report on magnetorheological finishing (MRF) spotting experiments performed on glasses and ceramics using a zirconia-coated carbonyl-iron (CI)-particle-based magnetorheological (MR) fluid. The zirconia-coated magnetic CI particles were prepared via sol-gel synthesis in kilogram quantities. The coating layer was {approx}50-100 nm thick, faceted in surface structure, and well adhered. Coated particles showed long-term stability against aqueous corrosion. ''Free'' nanocrystalline zirconia polishing abrasives were cogenerated in the coating process, resulting in an abrasive-charged powder for MRF. A viable MR fluid was prepared simply by adding water. Spot polishing tests were performed on a variety of optical glasses and ceramics over a period of nearly three weeks with no signs of MR fluid degradation or corrosion. Stable material removal rates and smooth surfaces inside spots were obtained.

  16. CNEEC - Atomic Layer Deposition Tutorial by Stacey Bent

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atomic Layer Deposition

  17. Hubei Feilihua Quartz Glass Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Glass Co Ltd Place: Jingzhou, Hubei Province, China Zip: 434001 Product: China-based manufacture of glass fiber and quartz crucibles. Coordinates: 30.299219, 112.274071 Show...

  18. Low energy detectors: 6Li-glass scintillators (Conference) |...

    Office of Scientific and Technical Information (OSTI)

    Low energy detectors: 6Li-glass scintillators Citation Details In-Document Search Title: Low energy detectors: 6Li-glass scintillators You are accessing a document from the ...

  19. Kinetics of Cold-Cap Reactions for Vitrification of Nuclear Waste Glass Based on Simultaneous Differential Scanning Calorimetry - Thermogravimetry (DSC-TGA) and Evolved Gas Analysis (EGA)

    SciTech Connect (OSTI)

    Rodriguez, Carmen P.; Pierce, David A.; Schweiger, Michael J.; Kruger, Albert A.; Chun, Jaehun; Hrma, Pavel R.

    2013-12-03

    For vitrifying nuclear waste glass, the feed, a mixture of waste with glass-forming and modifying additives, is charged onto the cold cap that covers 90-100% of the melt surface. The cold cap consists of a layer of reacting molten glass floating on the surface of the melt in an all-electric, continuous glass melter. As the feed moves through the cold cap, it undergoes chemical reactions and phase transitions through which it is converted to molten glass that moves from the cold cap into the melt pool. The process involves a series of reactions that generate multiple gases and subsequent mass loss and foaming significantly influence the mass and heat transfers. The rate of glass melting, which is greatly influenced by mass and heat transfers, affects the vitrification process and the efficiency of the immobilization of nuclear waste. We studied the cold-cap reactions of a representative waste glass feed using both the simultaneous differential scanning calorimetry thermogravimetry (DSC-TGA) and the thermogravimetry coupled with gas chromatography-mass spectrometer (TGA-GC-MS) as complementary tools to perform evolved gas analysis (EGA). Analyses from DSC-TGA and EGA on the cold-cap reactions provide a key element for the development of an advanced cold-cap model. It also helps to formulate melter feeds for higher production rate.

  20. Proposed Route to Thin Film Crystal Si Using Biaxially Textured Foreign Template Layers

    SciTech Connect (OSTI)

    Teplin, C. W.; Ginley, D. S.; van Hest, M.F.A.M.; Perkins, J. D.; Young, D. L.; Stradins, P.; Wang, Q.; Al-Jassim, M.; Iwaniczko, E.; Leenheer, A.; Jones, K. M.; Branz, H. M.

    2005-11-01

    We have developed a new approach to growing photovoltaic-quality crystal silicon (c-Si) films on glass. Other approaches to film c-Si focus on increasing grain size in order to reduce the deleterious effects of grain boundaries. Instead, we have developed an approach to align the silicon grains biaxially (both in and out of plane) so that 1) grain boundaries are "low-angle" and have less effect on the electronic properties of the material and 2) subsequent epitaxial thickening is simplified. They key to our approach is the use of a foreign template layer that can be grown with biaxial texture directly on glass.

  1. Microsoft PowerPoint - ORP Glass Effort TWC HAB

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vit 101 & WTP Glass Formulations Name: Albert A. Kruger, Glass Scientist Date 12 March 2014 Hanford Advisory Board Tank Waste Committee Presentation Outline * Background, Hanford Waste & Glass * Office of River Protection Advanced Glass Formulations Development * Challenges and Approaches for Hanford HLW Vitrification * Challenges and Approaches for Hanford LAW Vitrification * Studies to Develop 99 Tc Management Strategy for Hanford LAW Vitrification * Potential Approaches for Further

  2. DWPF Glass Melter Technology Manual: Volume 3

    SciTech Connect (OSTI)

    Iverson, D.C.

    1993-12-31

    This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Site. Topics discussed include: Information collected during testing, equipment, materials, design basis, feed tubes, and an evaluation of the performance of various components. Information is conveyed using many diagrams and photographs.

  3. Glass Science Could Boost Hanford Cleanup

    Broader source: Energy.gov [DOE]

    RICHLAND, Wash. – As EM’s Office of River Protection (ORP) continues with design and construction of the Waste Treatment and Immobilization Plant (WTP) project at the Hanford Site, tests continue to enhance the predicted results of turning waste into glass.

  4. DWPF Glass Melter Technology Manual: Volume 4

    SciTech Connect (OSTI)

    Iverson, D.C.

    1993-12-31

    This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Plant. Information contained in this document consists solely of a machine drawing and parts list and purchase orders with specifications of equipment used in the development of the melter.

  5. Molybdenum sealing glass-ceramic composition

    DOE Patents [OSTI]

    Eagan, Robert J.

    1976-01-01

    The invention relates to a glass-ceramic composition having low hydrogen and helium permeability properties, along with high fracture strength, a thermal coefficient of expansion similar to that of molybdenum, and adaptable for hermetically sealing to molybdenum at temperatures of between about 900.degree. and about 950.degree.C. to form a hermatically sealed insulator body.

  6. HIGH ALUMINUM HLW GLASSES FOR HANFORDS WTP

    SciTech Connect (OSTI)

    KRUGER AA; JOSEPH I; BOWMAN BW; GAN H; KOT W; MATLACK KS; PEGG IL

    2009-08-19

    The world's largest radioactive waste vitrification facility is now under construction at the United State Department of Energy's (DOE's) Hanford site. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is designed to treat nearly 53 million gallons of mixed hazardous and radioactive waste now residing in 177 underground storage tanks. This multi-decade processing campaign will be one of the most complex ever undertaken because of the wide chemical and physical variability of the waste compositions generated during the cold war era that are stored at Hanford. The DOE Office of River Protection (ORP) has initiated a program to improve the long-term operating efficiency of the WTP vitrification plants with the objective of reducing the overall cost of tank waste treatment and disposal and shortening the duration of plant operations. Due to the size, complexity and duration of the WTP mission, the lifecycle operating and waste disposal costs are substantial. As a result, gains in High Level Waste (HLW) and Low Activity Waste (LAW) waste loadings, as well as increases in glass production rate, which can reduce mission duration and glass volumes for disposal, can yield substantial overall cost savings. EnergySolutions and its long-term research partner, the Vitreous State Laboratory (VSL) of the Catholic University of America, have been involved in a multi-year ORP program directed at optimizing various aspects of the HLW and LAW vitrification flow sheets. A number of Hanford HLW streams contain high concentrations of aluminum, which is challenging with respect to both waste loading and processing rate. Therefore, a key focus area of the ORP vitrification process optimization program at EnergySolutions and VSL has been development of HLW glass compositions that can accommodate high Al{sub 2}O{sub 3} concentrations while maintaining high processing rates in the Joule Heated Ceramic Melters (JHCMs) used for waste vitrification at the WTP. This paper, reviews

  7. CADMIUM-RARE EARTH BORATE GLASS AS REACTOR CONTROL MATERIAL

    DOE Patents [OSTI]

    Ploetz, G.L.; Ray, W.E.

    1958-11-01

    A reactor control rod fabricated from a cadmiumrare earth-borate glass is presented. The rare earth component of this glass is selected from among those rare earths having large neutron capture cross sections, such as samarium, gadolinium or europium. Partlcles of this glass are then dispersed in a metal matrix by standard powder metallurgy techniques.

  8. Energy efficient residential new construction: market transformation. Spectral selective glass. Final project report

    SciTech Connect (OSTI)

    Hammon, Robert

    2000-12-18

    This final report describes the following tasks associated with this project: cost and availability of spectrally selective glass (SSG); window labeling problem and field verification of glass; availability of SSG replacement glass and tempered glass; HVAC load reduction due to spectrally selective glass; and comsumer appreciation of spectrally selective glass. Also included in the report are four attachments: builder and HVAC subcontractor presentation, sample advertisements, spectrally selective glass demonstration model, and invitation to SCE Glass mini trade-show.

  9. Blocking effect of crystalglass interface in lanthanum doped barium strontium titanate glassceramics

    SciTech Connect (OSTI)

    Wang, Xiangrong; Zhang, Yong; Baturin, Ivan; Liang, Tongxiang

    2013-10-15

    Graphical abstract: The blocking effect of the crystalglass interface on the carrier transport behavior in the lanthanum doped barium strontium titanate glassceramics: preparation and characterization. - Highlights: La{sub 2}O{sub 3} addition promotes the crystallization of the major crystalline phase. The Z? and M? peaks exist a significant mismatch for 0.5 mol% La{sub 2}O{sub 3} addition. The Z? and M? peaks separate obviously for 1.0 mol% La{sub 2}O{sub 3} addition. Crystallite impedance decreases while crystalglass interface impedance increases. La{sub 2}O{sub 3} addition increases blocking factor of the crystalglass interface. - Abstract: The microstructures and dielectric properties in La{sub 2}O{sub 3}-doped barium strontium titanate glassceramics have been investigated by scanning electron microscopy (SEM) and impedance spectroscopy. SEM analysis indicated that La{sub 2}O{sub 3} additive decreases the average crystallite size. Impedance spectroscopy revealed that the positions of Z? and M? peaks are close for undoped samples. When La{sub 2}O{sub 3} concentration is 0.5 mol%, the Z? and M? peaks show a significant mismatch. Furthermore, these peaks separate obviously for 1.0 mol% La{sub 2}O{sub 3} addition. With increasing La{sub 2}O{sub 3} concentration, the contribution of the crystallite impedance becomes smaller, while the contribution of the crystalglass interface impedance becomes larger. More interestingly, it was found that La{sub 2}O{sub 3} additive increases blocking factor of the crystalglass interface in the temperature range of 250450 C. This may be attributed to a decrease of activation energy of the crystallite and an increase of the crystalglass interface area.

  10. Layered seal for turbomachinery

    DOE Patents [OSTI]

    Sarawate, Neelesh Nandkumar; Morgan, Victor John; Weber, David Wayne

    2015-11-20

    The present application provides seal assemblies for reducing leakages between adjacent components of turbomachinery. The seal assemblies may include outer shims, and at least a portion of the outer shims may be substantially impervious. At least one of the outer shims may be configured for sealing engagement with seal slots of the adjacent components. The seal assemblies may also include at least one of an inner shim and a filler layer positioned between the outer shims. The at least one inner shim may be substantially solid and the at least one filler layer may be relatively porous. The seal assemblies may be sufficiently flexible to account for misalignment between the adjacent components, sufficiently stiff to meet assembly requirements, and sufficiently robust to operating meet requirements associated with turbomachinery.

  11. Application of a computational glass model to the shock response of soda-lime glass

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gorfain, Joshua E.; Key, Christopher T.; Alexander, C. Scott

    2016-04-20

    This article details the implementation and application of the glass-specific computational constitutive model by Holmquist and Johnson [1] to simulate the dynamic response of soda-lime glass under high rate and high pressure shock conditions. The predictive capabilities of this model are assessed through comparison of experimental data with numerical results from computations using the CTH shock physics code. The formulation of this glass model is reviewed in the context of its implementation within CTH. Using a variety of experimental data compiled from the open literature, a complete parameterization of the model describing the observed behavior of soda-lime glass is developed.more » Simulation results using the calibrated soda-lime glass model are compared to flyer plate and Taylor rod impact experimental data covering a range of impact and failure conditions spanning an order of magnitude in velocity and pressure. In conclusion, the complex behavior observed in the experimental testing is captured well in the computations, demonstrating the capability of the glass model within CTH.« less

  12. Tandem photovoltaic cells with a composite intermediate layer

    SciTech Connect (OSTI)

    Travkin, V. V. Pakhomov, G. L.; Luk’anov, A. Yu.; Stuzhin, P. A.

    2015-11-15

    We have fabricated and tested tandem photovoltaic cells containing series-connected subcells of the “oxide–organic semiconductor–metal” type. The organic semiconductors were two phthalocyanine dyes (SubPc and PcVO); Al or Ag:Mg were used as capping metallic electrodes. A semitransparent composite metal–oxide layer formed by molybdenum oxide MoO{sub x} deposited over an ultrathin Al layer is used to join the subcells. Additionally, a MoO{sub x} layer deposited onto glass/ITO substrates serves as an anode buffer in the front subcell, and LiF deposited onto the dye layers serves as a cathode buffer in the front or rear subcells. Upon optimization of the thickness and composition of the intermediate layer, the open circuit voltage U{sub oc} amounts to 1.6 V reflecting total summation of the contributions from the each of the subcells at a wide spectral coating from 300–1000 nm. The fill factor in the tandem cell is not worse than in individually made single cells with the same scheme or in disconnected subcells.

  13. Energy Efficient Glass Melting - The Next Generation Melter

    SciTech Connect (OSTI)

    David Rue

    2008-03-01

    The objective of this project is to demonstrate a high intensity glass melter, based on the submerged combustion melting technology. This melter will serve as the melting and homogenization section of a segmented, lower-capital cost, energy-efficient Next Generation Glass Melting System (NGMS). After this project, the melter will be ready to move toward commercial trials for some glasses needing little refining (fiberglass, etc.). For other glasses, a second project Phase or glass industry research is anticipated to develop the fining stage of the NGMS process.

  14. Rapid process for producing transparent, monolithic porous glass

    DOE Patents [OSTI]

    Coronado, Paul R. (Livermore, CA)

    2006-02-14

    A process for making transparent porous glass monoliths from gels. The glass is produced much faster and in much larger sizes than present technology for making porous glass. The process reduces the cost of making large porous glass monoliths because: 1) the process does not require solvent exchange nor additives to the gel to increase the drying rates, 2) only moderate temperatures and pressures are used so relatively inexpensive equipment is needed, an 3) net-shape glass monoliths are possible using this process. The process depends on the use of temperature to control the partial pressure of the gel solvent in a closed vessel, resulting in controlled shrinking during drying.

  15. Sealed glass coating of high temperature ceramic superconductors

    DOE Patents [OSTI]

    Wu, W.; Chu, C.Y.; Goretta, K.C.; Routbort, J.L.

    1995-05-02

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor is disclosed. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor. 8 figs.

  16. DEVELOPMENT OF GLASS MATRICES FOR HLW RADIOACTIVE WASTES

    SciTech Connect (OSTI)

    Jantzen, C.

    2010-03-18

    Vitrification is currently the most widely used technology for the treatment of high level radioactive wastes (HLW) throughout the world. Most of the nations that have generated HLW are immobilizing in either borosilicate glass or phosphate glass. One of the primary reasons that glass has become the most widely used immobilization media is the relative simplicity of the vitrification process, e.g. melt waste plus glass forming frit additives and cast. A second reason that glass has become widely used for HLW is that the short range order (SRO) and medium range order (MRO) found in glass atomistically bonds the radionuclides and governs the melt properties such as viscosity, resistivity, sulphate solubility. The molecular structure of glass controls contaminant/radionuclide release by establishing the distribution of ion exchange sites, hydrolysis sites, and the access of water to those sites. The molecular structure is flexible and hence accounts for the flexibility of glass formulations to waste variability. Nuclear waste glasses melt between 1050-1150 C which minimizes the volatility of radioactive components such as Tc{sup 99}, Cs{sup 137}, and I{sup 129}. Nuclear waste glasses have good long term stability including irradiation resistance. Process control models based on the molecular structure of glass have been mechanistically derived and have been demonstrated to be accurate enough to control the world's largest HLW Joule heated ceramic melter in the US since 1996 at 95% confidence.

  17. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

    2003-09-23

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste uranium oxides The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  18. Laboratory work in support of West Valley glass development

    SciTech Connect (OSTI)

    Bunnell, L.R.

    1988-05-01

    Over the past six years, Pacific Northwest Laboratory (PNL) has conducted several studies in support of waste glass composition development and testing of glass compositions suitable for immobilizing the nuclear wastes stored at West Valley, New York. As a result of pilot-scale testing conducted by PNL, the glass composition was changed from that originally recommended in response to changes in the waste stream, and several processing-related problems were discovered. These problems were solved, or sufficiently addressed to determine their likely effect on the glass melting operations to be conducted at West Valley. This report describes the development of the waste glass composition, WV-205, and discusses solutions to processing problems such as foaming and insoluble sludges, as well as other issues such as effects of feed variations on processing of the resulting glass. An evaluation of the WV-205 glass from a repository perspective is included in the appendix to this report.

  19. System and method for glass processing and temperature sensing

    DOE Patents [OSTI]

    Shepard, Chester L.; Cannon, Bret D.; Khaleel, Mohammad A.

    2004-09-28

    Techniques for measuring the temperature at various locations through the thickness of glass products and to control the glass processing operation with the sensed temperature information are disclosed. Fluorescence emission of iron or cerium in glass is excited and imaged onto segmented detectors. Spatially resolved temperature data are obtained through correlation of the detected photoluminescence signal with location within the glass. In one form the detected photoluminescence is compared to detected scattered excitation light to determine temperature. Stress information is obtained from the time history of the temperature profile data and used to evaluate the quality of processed glass. A heating or cooling rate of the glass is also controlled to maintain a predetermined desired temperature profile in the glass.

  20. Li.sub.2 O-Al.sub.2 O.sub.3 -SiO.sub.2 glass ceramic-aluminum containing austenitic stainless steel composite body and a method of producing the same

    DOE Patents [OSTI]

    Cassidy, Roger T.

    1990-05-01

    The present invention relates to a hermetically sealed Li.sub.2 O-Al.sub.2 O.sub.3 -SiO.sub.2 glass ceramic-aluminum containing stainless steel composite body and a method of producing the body. The composite body includes an oxide interfacial region between the glass ceramic and metal, wherein the interfacial region consists essentially of an Al.sub.2 O.sub.3 layer. The interfacial Al.sub.2 O.sub.3 region includes constituents of both the metal and glass ceramic.

  1. Glass ceramic toughened with tetragonal zirconia

    DOE Patents [OSTI]

    Keefer, K.D.

    1984-02-10

    A phase transformation-toughened glass ceramic and a process for making it are disclosed. A mixture of particulate network-forming oxide, network-modifying oxide, and zirconium oxide is heated to yield a homogeneous melt, and this melt is then heat treated to precipitate an appreciable quantity of tetragonal zirconia, which is retained at ambient temperature to form a phase transformation-toughened glass ceramic. Nuclearing agents and stabilizing agents may be added to the mixture to facilitate processing and improve the ceramic's properties. Preferably, the mixture is first melted at a temperature from 1200 to 1700/sup 0/C and is then heat-treated at a temperature within the range of 800 to 1200/sup 0/C in order to precipitate tetragonal ZrO/sub 2/. The composition, as well as the length and temperature of the heat treatment, must be carefully controlled to prevent solution of the precipitated tetragonal zirconia and subsequent conversion to the monoclinic phase.

  2. DWPF Glass Melter Technology Manual: Volume 1

    SciTech Connect (OSTI)

    Iverson, D.C.

    1993-12-31

    This document details information about the design of a glass melter to be used at the Defense Waste Processing Facility located at the Savannah River Site. Topics include: melter overview, design basis, materials, vessel configuration, insulation, refractory configuration, electrical isolation, electrodes, riser and pour spout heater design, dome heaters, feed tubes, drain valves, differential pressure pouring, and melter test results. Information is conveyed using many diagrams and photographs.

  3. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density

  4. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density

  5. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density

  6. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density

  7. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density

  8. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density

  9. Bioactive Glass Scaffolds for Bone Regeneration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bioactive Glass Scaffolds for Bone Regeneration Print Natural materials are renowned for their unique combination of outstanding mechanical properties and exquisite microstructure. For example, bone, cork, and wood are porous biological materials with high specific stiffness (stiffness per unit weight) and specific strength. The outstanding mechanical properties of these materials are attributed to their anisotropic structures, which have optimized strength-to-density and stiffness-to-density

  10. Phosphate glass useful in high power lasers

    DOE Patents [OSTI]

    Hayden, Joseph S.; Sapak, David L.; Ward, Julia M.

    1990-01-01

    A low- or no-silica phosphate glass useful as a laser medium and having a high thermal conductivity, K.sub.90.degree. C. >0.8 W/mK, and a low coefficient of thermal expansion, .alpha..sub.20.degree.-40.degree. C. <80.times.10.sup.-7 /.degree.C., consists essentially of (on a batch composition basis): the amounts of Li.sub.2 O and Na.sub.2 O providing an average alkali metal ionic radius sufficiently low whereby said glass has K.sub.90.degree. C. >0.8 W/mK and .alpha..sub.20.degree.-40.degree. C. <80.times.10.sup.-7 /.degree.C., and wherein, when the batch composition is melted in contact with a silica-containing surface, the final glass composition contains at most about 3.5 mole % of additional silica derived from such contact during melting. The Nd.sub.2 O.sub.3 can be replaced by other lasing species.

  11. Chemical segregation in metallic glass nanowires

    SciTech Connect (OSTI)

    Zhang, Qi; Li, Mo; Li, Qi-Kai

    2014-11-21

    Nanowires made of metallic glass have been actively pursued recently due to the superb and unique properties over those of the crystalline materials. The amorphous nanowires are synthesized either at high temperature or via mechanical disruption using focused ion beam. These processes have potential to cause significant changes in structure and chemical concentration, as well as formation of defect or imperfection, but little is known to date about the possibilities and mechanisms. Here, we report chemical segregation to surfaces and its mechanisms in metallic glass nanowires made of binary Cu and Zr elements from molecular dynamics simulation. Strong concentration deviation are found in the nanowires under the conditions similar to these in experiment via focused ion beam processing, hot imprinting, and casting by rapid cooling from liquid state. Our analysis indicates that non-uniform internal stress distribution is a major cause for the chemical segregation, especially at low temperatures. Extension is discussed for this observation to multicomponent metallic glass nanowires as well as the potential applications and side effects of the composition modulation. The finding also points to the possibility of the mechanical-chemical process that may occur in different settings such as fracture, cavitation, and foams where strong internal stress is present in small length scales.

  12. Sink property of metallic glass free surfaces

    SciTech Connect (OSTI)

    Shao, Lin; Fu, Engang; Price, Lloyd; Chen, Di; Chen, Tianyi; Wang, Yongqiang; Xie, Guoqiang; Lucca, Don A.

    2015-03-16

    When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences. For ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.

  13. Sink property of metallic glass free surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, Lin; Fu, Engang; Price, Lloyd; Chen, Di; Chen, Tianyi; Wang, Yongqiang; Xie, Guoqiang; Lucca, Don A.

    2015-03-16

    When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences.more » For ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.« less

  14. Sink property of metallic glass free surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, Lin; Fu, Engang; Price, Lloyd; Chen, Di; Chen, Tianyi; Wang, Yongqiang; Xie, Guoqiang; Lucca, Don A.

    2015-03-16

    When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences.moreFor ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.less

  15. Medium-range structure and glass forming ability in Zr–Cu–Al bulk metallic glasses

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Pei; Maldonis, Jason J.; Besser, M. F.; Kramer, M. J.; Voyles, Paul M.

    2016-03-05

    Fluctuation electron microscopy experiments combined with hybrid reverse Monte Carlo modeling show a correlation between medium-range structure at the nanometer scale and glass forming ability in two Zr–Cu–Al bulk metallic glass (BMG) alloys. Both Zr50Cu35Al15 and Zr50Cu45Al5 exhibit two nanoscale structure types, one icosahedral and the other more crystal-like. In Zr50Cu35Al15, the poorer glass former, the crystal-like structure is more stable under annealing below the glass transition temperature, Tg, than in Zr50Cu45Al5. Variable resolution fluctuation microscopy of the MRO clusters show that in Zr50Cu35Al15 on sub-Tg annealing, the crystal-like clusters shrink even as they grow more ordered, while icosahedral-like clustersmore » grow. Furthermore, the results suggest that achieving better glass forming ability in this alloy system may depend more on destabilizing crystal-like structures than enhancing non-crystalline structures.« less

  16. Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition

    SciTech Connect (OSTI)

    Sunny, Steffi; Vogel, Nicolas; Howell, Caitlin; Vu, Thy L.; Aizenberg, Joanna

    2014-09-01

    Omniphobic coatings are designed to repel a wide range of liquids without leaving stains on the surface. A practical coating should exhibit stable repellency, show no interference with color or transparency of the underlying substrate and, ideally, be deposited in a simple process on arbitrarily shaped surfaces. We use layer-by-layer (LbL) deposition of negatively charged silica nanoparticles and positively charged polyelectrolytes to create nanoscale surface structures that are further surface-functionalized with fluorinated silanes and infiltrated with fluorinated oil, forming a smooth, highly repellent coating on surfaces of different materials and shapes. We show that four or more LbL cycles introduce sufficient surface roughness to effectively immobilize the lubricant into the nanoporous coating and provide a stable liquid interface that repels water, low-surface-tension liquids and complex fluids. The absence of hierarchical structures and the small size of the silica nanoparticles enables complete transparency of the coating, with light transmittance exceeding that of normal glass. The coating is mechanically robust, maintains its repellency after exposure to continuous flow for several days and prevents adsorption of streptavidin as a model protein. As a result, the LbL process is conceptually simple, of low cost, environmentally benign, scalable, automatable and therefore may present an efficient synthetic route to non-fouling materials.

  17. Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sunny, Steffi; Vogel, Nicolas; Howell, Caitlin; Vu, Thy L.; Aizenberg, Joanna

    2014-09-01

    Omniphobic coatings are designed to repel a wide range of liquids without leaving stains on the surface. A practical coating should exhibit stable repellency, show no interference with color or transparency of the underlying substrate and, ideally, be deposited in a simple process on arbitrarily shaped surfaces. We use layer-by-layer (LbL) deposition of negatively charged silica nanoparticles and positively charged polyelectrolytes to create nanoscale surface structures that are further surface-functionalized with fluorinated silanes and infiltrated with fluorinated oil, forming a smooth, highly repellent coating on surfaces of different materials and shapes. We show that four or more LbL cycles introducemore » sufficient surface roughness to effectively immobilize the lubricant into the nanoporous coating and provide a stable liquid interface that repels water, low-surface-tension liquids and complex fluids. The absence of hierarchical structures and the small size of the silica nanoparticles enables complete transparency of the coating, with light transmittance exceeding that of normal glass. The coating is mechanically robust, maintains its repellency after exposure to continuous flow for several days and prevents adsorption of streptavidin as a model protein. As a result, the LbL process is conceptually simple, of low cost, environmentally benign, scalable, automatable and therefore may present an efficient synthetic route to non-fouling materials.« less

  18. Lubricant-Infused Nanoparticulate Coatings Assembled by Layer-by-Layer Deposition

    SciTech Connect (OSTI)

    Sunny, S; Vogel, N; Howell, C; Vu, TL; Aizenberg, J

    2014-09-01

    Omniphobic coatings are designed to repel a wide range of liquids without leaving stains on the surface. A practical coating should exhibit stable repellency, show no interference with color or transparency of the underlying substrate and, ideally, be deposited in a simple process on arbitrarily shaped surfaces. We use layer-by-layer (LbL) deposition of negatively charged silica nanoparticles and positively charged polyelectrolytes to create nanoscale surface structures that are further surface-functionalized with fluorinated silanes and infiltrated with fluorinated oil, forming a smooth, highly repellent coating on surfaces of different materials and shapes. We show that four or more LbL cycles introduce sufficient surface roughness to effectively immobilize the lubricant into the nanoporous coating and provide a stable liquid interface that repels water, low-surface-tension liquids and complex fluids. The absence of hierarchical structures and the small size of the silica nanoparticles enables complete transparency of the coating, with light transmittance exceeding that of normal glass. The coating is mechanically robust, maintains its repellency after exposure to continuous flow for several days and prevents adsorption of streptavidin as a model protein. The LbL process is conceptually simple, of low cost, environmentally benign, scalable, automatable and therefore may present an efficient synthetic route to non-fouling materials.

  19. Glass Property Models and Constraints for Estimating the Glass to be Produced at Hanford by Implementing Current Advanced Glass Formulation Efforts

    SciTech Connect (OSTI)

    Vienna, John D.; Kim, Dong-Sang; Skorski, Daniel C.; Matyas, Josef

    2013-07-31

    Recent glass formulation and melter testing data have suggested that significant increases in waste loading in HLW and LAW glasses are possible over current system planning estimates. The data (although limited in some cases) were evaluated to determine a set of constraints and models that could be used to estimate the maximum loading of specific waste compositions in glass. It is recommended that these models and constraints be used to estimate the likely HLW and LAW glass volumes that would result if the current glass formulation studies are successfully completed. It is recognized that some of the models are preliminary in nature and will change in the coming years. Plus the models do not currently address the prediction uncertainties that would be needed before they could be used in plant operations. The models and constraints are only meant to give an indication of rough glass volumes and are not intended to be used in plant operation or waste form qualification activities. A current research program is in place to develop the data, models, and uncertainty descriptions for that purpose. A fundamental tenet underlying the research reported in this document is to try to be less conservative than previous studies when developing constraints for estimating the glass to be produced by implementing current advanced glass formulation efforts. The less conservative approach documented herein should allow for the estimate of glass masses that may be realized if the current efforts in advanced glass formulations are completed over the coming years and are as successful as early indications suggest they may be. Because of this approach there is an unquantifiable uncertainty in the ultimate glass volume projections due to model prediction uncertainties that has to be considered along with other system uncertainties such as waste compositions and amounts to be immobilized, split factors between LAW and HLW, etc.

  20. Peculiarities and application perspectives of metal-ion implants in glasses

    SciTech Connect (OSTI)

    Mazzoldi, P.; Gonella, F.; Arnold, G.W.; Battaglin, G.; Bertoncello, R.

    1993-12-31

    Ion implantation in insulators causes modifications in the refractive-index as a result of radiation damage, phase separation, or compound formation. As a consequence, light waveguides may be formed with interesting applications in the field of optoelectronics. Recently implantation of metals ions (e.g. silver, copper, gold, lead,...) showed the possibility of small radii colloidal particles formation, in a thin surface layer of the glass substrate. These particles exhibit an electron plasmon resonance which depends on the optical constants of the implanted metal and on the refractive-index of the glass host. The non-linear optical properties of such colloids, in particular the enhancement of optical Kerr susceptibility, suggest that the, ion implantation technique may play an important role for the production of all-optical switching devices. In this paper an analysis of the state-of-the-art of the research in this field will be presented in the framework of ion implantation in glass physics and chemistry.

  1. Characterization of Epitaxial Film Silicon Solar Cells Grown on Seeded Display Glass: Preprint

    SciTech Connect (OSTI)

    Young, D. L.; Grover, S.; Teplin, C.; Stradins, P.; LaSalvia, V.; Chuang, T. K.; Couillard, J. G.; Branz, H. M.

    2012-06-01

    We report characterizations of epitaxial film crystal silicon (c-Si) solar cells with open-circuit voltages (Voc) above 560 mV. The 2-um absorber cells are grown by low-temperature (<750 degrees C) hot-wire CVD (HWCVD) on Corning EAGLE XG display glass coated with a layer-transferred (LT) Si seed. The high Voc is a result of low-defect epitaxial Si (epi-Si) growth and effective hydrogen passivation of defects. The quality of HWCVD epitaxial growth on seeded glass substrates depends on the crystallographic quality of the seed and the morphology of the epitaxial growth surface. Heterojunction devices consist of glass/c-Si LT seed/ epi n+ Si:P/epi n- Si:P/intrinsic a-Si:H/p+ a-Si:H/ITO. Similar devices grown on electronically 'dead' n+ wafers have given Voc {approx}630 mV and {approx}8% efficiency with no light trapping features. Here we study the effects of the seed surface polish on epi-Si quality, how hydrogenation influences the device character, and the dominant junction transport physics.

  2. Development of high strength hydroxyapatite for bone tissue regeneration using nanobioactive glass composites

    SciTech Connect (OSTI)

    Shrivastava, Pragya; Dalai, Sridhar; Vijayalakshmi, S.; Sudera, Prerna; Sivam, Santosh Param; Sharma, Pratibha

    2013-02-05

    With an increasing demand of biocompatible bone substitutes for the treatment of bone diseases and bone tissue regeneration, bioactive glass composites are being tested to improvise the osteoconductive as well as osteoinductive properties. Nanobioactive glass (nBG) composites, having composition of SiO{sub 2} 70 mol%, CaO 26 mol % and P{sub 2}O{sub 5} 4 mol% were prepared by Freeze drying method using PEG-PPG-PEG co-polymer. Polymer addition improves the mechanical strength and porosity of the scaffold of nBG. Nano Bioactive glass composites upon implantation undergo specific reactions leading to the formation of crystalline hydroxyapatite (HA). This is tested in vitro using Simulated Body Fluid (SBF). This high strength hydroxyapatite (HA) layer acts as osteoconductive in cellular environment, by acting as mineral base of bones, onto which new bone cells proliferate leading to new bone formation. Strength of the nBG composites as well as HA is in the range of cortical and cancellous bone, thus proving significant for bone tissue regeneration substitutes.

  3. High-Intensity Plasma Glass Melter Final Technical Report

    SciTech Connect (OSTI)

    Gonterman, J. Ronald; Weinstein, Michael A.

    2006-10-27

    The purpose of this project was to demonstrate the energy efficiency and reduced emissions that can be obtained with a dual torch DC plasma transferred arc-melting system. Plasmelt Glass Technologies, LLC was formed to solicit and execute the project, which utilize a full-scale test melter system. The system is similar to the one that was originally constructed by Johns Manville, but Plasmelt has added significant improvements to the torch design and melter system that has extended the original JM short torch lives. The original JM design has been shown to achieve melt rates 5 to 10 times faster than conventional gas or electric melting, with improved energy efficiency and reduced emissions. This project began on 7/28/2003 and ended 7/27/06. A laboratory scale melter was designed, constructed, and operated to conduct multiple experimental melting trials on various glass compositions. Glass quality was assessed. Although the melter design is generic and equally applicable to all sectors within the glass industry, the development of this melter has focused primarily on fiberglass with additional exploratory melting trials of frits, specialty, and minerals-melting applications. Throughput, energy efficiency, and glass quality have been shown to be heavily dependent on the selected glass composition. During this project, Plasmelt completed the proof-of-concept work in our Boulder, CO Lab to show the technical feasibility of this transferred-arc plasma melter. Late in the project, the work was focused on developing the processes and evaluating the economic viability of plasma melting aimed at the specific glasses of interest to specific client companies. Post project work is on going with client companies to address broader non-glass materials such as refractories and industrial minerals. Exploratory melting trials have been conducted on several glasses of commercial interest including: C-glass, E-glass, S-Glass, AR-Glass, B-glass, Lighting Glass, NE-Glass, and various

  4. Buried oxide layer in silicon

    DOE Patents [OSTI]

    Sadana, Devendra Kumar; Holland, Orin Wayne

    2001-01-01

    A process for forming Silicon-On-Insulator is described incorporating the steps of ion implantation of oxygen into a silicon substrate at elevated temperature, ion implanting oxygen at a temperature below 200.degree. C. at a lower dose to form an amorphous silicon layer, and annealing steps to form a mixture of defective single crystal silicon and polycrystalline silicon or polycrystalline silicon alone and then silicon oxide from the amorphous silicon layer to form a continuous silicon oxide layer below the surface of the silicon substrate to provide an isolated superficial layer of silicon. The invention overcomes the problem of buried isolated islands of silicon oxide forming a discontinuous buried oxide layer.

  5. Metal deposition using seed layers

    DOE Patents [OSTI]

    Feng, Hsein-Ping; Chen, Gang; Bo, Yu; Ren, Zhifeng; Chen, Shuo; Poudel, Bed

    2013-11-12

    Methods of forming a conductive metal layers on substrates are disclosed which employ a seed layer to enhance bonding, especially to smooth, low-roughness or hydrophobic substrates. In one aspect of the invention, the seed layer can be formed by applying nanoparticles onto a surface of the substrate; and the metallization is achieved by electroplating an electrically conducting metal onto the seed layer, whereby the nanoparticles serve as nucleation sites for metal deposition. In another approach, the seed layer can be formed by a self-assembling linker material, such as a sulfur-containing silane material.

  6. Templated, layered manganese phosphate

    DOE Patents [OSTI]

    Thoma, Steven G.; Bonhomme, Francois R.

    2004-08-17

    A new crystalline maganese phosphate composition having an empirical formula: O). The compound was determined to crystallize in the trigonal space group P-3c1 with a=8.8706(4) .ANG., c=26.1580(2) .ANG., and V (volume)=1783 .ANG..sup.3. The structure consists of sheets of corner sharing Mn(II)O.sub.4 and PO.sub.4 tetrahedra with layers of (H.sub.3 NCH.sub.2 CH.sub.2).sub.3 N and water molecules in-between. The pronated (H.sub.3 NCH.sub.2 CH.sub.2).sub.3 N molecules provide charge balancing for the inorganic sheets. A network of hydrogen bonds between water molecules and the inorganic sheets holds the structure together.

  7. SUMMARY OF FY11 SULFATE RETENTION STUDIES FOR DEFENSE WASTE PROCESSING FACILITY GLASS

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2012-05-08

    This report describes the results of studies related to the incorporation of sulfate in high level waste (HLW) borosilicate glass produced at the Savannah River Site (SRS) Defense Waste Processing Facility (DWPF). A group of simulated HLW glasses produced for earlier sulfate retention studies was selected for full chemical composition measurements to determine whether there is any clear link between composition and sulfate retention over the compositional region evaluated. In addition, the viscosity of several glasses was measured to support future efforts in modeling sulfate solubility as a function of predicted viscosity. The intent of these studies was to develop a better understanding of sulfate retention in borosilicate HLW glass to allow for higher loadings of sulfate containing waste. Based on the results of these and other studies, the ability to improve sulfate solubility in DWPF borosilicate glasses lies in reducing the connectivity of the glass network structure. This can be achieved, as an example, by increasing the concentration of alkali species in the glass. However, this must be balanced with other effects of reduced network connectivity, such as reduced viscosity, potentially lower chemical durability, and in the case of higher sodium and aluminum concentrations, the propensity for nepheline crystallization. Future DWPF processing is likely to target higher waste loadings and higher sludge sodium concentrations, meaning that alkali concentrations in the glass will already be relatively high. It is therefore unlikely that there will be the ability to target significantly higher total alkali concentrations in the glass solely to support increased sulfate solubility without the increased alkali concentration causing failure of other Product Composition Control System (PCCS) constraints, such as low viscosity and durability. No individual components were found to provide a significant improvement in sulfate retention (i.e., an increase of the magnitude

  8. Effect of Sulfate on Rhenium Partitioning during Melting of Low-Activity Waste Glass Feeds

    SciTech Connect (OSTI)

    Jin, Tongan; Kim, Dong-Sang; Schweiger, Michael J.

    2015-10-01

    The volatile loss of technetium-99 (99Tc) is a major concern of the low-activity waste (LAW) vitrification at Hanford. We investigated the incorporation and volatile loss of Re (a nonradioactive surrogate for 99Tc) during batch-to-glass conversion up to 1100°C. The AN-102 feed, which is one of the representative Hanford LAW feeds, containing 0.59 wt% of SO3 (in glass if 100% retained) was used. The modified sulfate-free AN-102_0S feed was also tested to investigate the effect of sulfate on Re partitioning and retention during melting. After heating of the dried melter feed (mixture of LAW simulant and glass forming/modifying additives) to different temperatures, the heat-treated samples were quenched. For each heat-treated sample, the salts (soluble components in room temperature leaching), early glass forming melt (soluble components in 80°C leaching), and insoluble solids were separated by a two-step leaching and the chemical compositions of each phase were quantitatively analyzed. The final retention ratio of AN-102 and AN-102_0S in glass (insoluble solids) are 32% and 63% respectively. The presence of sulfate in the salt phase between 600 and 800°C leads to a significantly higher Re loss via volatilization from the salt layer. At ≥800°C, for both samples, there is no more incorporation of Re into the insoluble phase because: for AN-102_0S there is no salt left i.e., the split into the insoluble and gas phases is complete by 800°C and for AN-102 all the Re contained in the remaining salt phase is lost through volatilization. The present results on the effect of sulfate, although not directly applicable to LAW vitrification in the melter, will be used to understand the mechanism of Re incorporation into glass to eventually develop the methods that can increase the 99Tc retention during LAW vitrification at Hanford.

  9. Processes for multi-layer devices utilizing layer transfer

    DOE Patents [OSTI]

    Nielson, Gregory N; Sanchez, Carlos Anthony; Tauke-Pedretti, Anna; Kim, Bongsang; Cederberg, Jeffrey; Okandan, Murat; Cruz-Campa, Jose Luis; Resnick, Paul J

    2015-02-03

    A method includes forming a release layer over a donor substrate. A plurality of devices made of a first semiconductor material are formed over the release layer. A first dielectric layer is formed over the plurality of devices such that all exposed surfaces of the plurality of devices are covered by the first dielectric layer. The plurality of devices are chemically attached to a receiving device made of a second semiconductor material different than the first semiconductor material, the receiving device having a receiving substrate attached to a surface of the receiving device opposite the plurality of devices. The release layer is etched to release the donor substrate from the plurality of devices. A second dielectric layer is applied over the plurality of devices and the receiving device to mechanically attach the plurality of devices to the receiving device.

  10. Hanford SPA Glasses: Fabrication, Characterization, and Chemical Analysis

    SciTech Connect (OSTI)

    Peeler, D.K.

    2002-04-03

    The U.S. Department of Energy is formulating plans to vitrify the 204,400 m3 of radioactive waste contained in the 177 waste storage tanks at the Hanford Site in Washington State. Interim Hanford high-level waste glass TL models for use in the site flowsheet software are currently being updated (Vienna et al. [2001]). An integral part of this approach involves fabrication and testing of specific properties for glasses that adequately cover the compositional region of interest. As a result, Pacific Northwest National Laboratory (PNNL) developed a 45-glass test matrix (referred to as the SPA glass test matrix or SPA glasses) for which liquidus temperature (TL) will be measured. The Savannah River Technology Center (SRTC) is supporting PNNL efforts by (1) fabricating the SPA glasses and (2) analyzing their chemical composition.

  11. Ion dynamics and mixed mobile ion effect in fluoride glasses

    SciTech Connect (OSTI)

    Ghosh, S.; Ghosh, A.

    2005-06-15

    We report the ionic relaxation and mixed mobile ion effect in 50ZrF{sub 4}-10BaF{sub 2}-10YF{sub 3}-(30-x)LiF-xNaF fluoride glass series, where fluorine anions participate in the diffusion process in addition to alkali cations, unlike mixed alkali oxide glasses and crystals. By analyzing the ion dynamics in the framework of a power-law model as well as modulus formalism we have observed mixed mobile ion effect in the dc conductivity and its activation energy, the crossover frequency and its activation energy, the conductivity relaxation frequency and its activation energy, and also in the decoupling index. We have correlated these phenomena with the fractal dimension of the conduction pathways in the mixed alkali fluoride glasses compared to the single alkali glasses. We have shown that the relaxation dynamics in mixed alkali fluoride glasses is independent of temperature but dependent on glass composition.

  12. EMPIRICAL MODEL FOR FORMULATION OF CRYSTAL-TOLERANT HLW GLASSES

    SciTech Connect (OSTI)

    KRUGER AA; MATYAS J; HUCKLEBERRY AR; VIENNA JD; RODRIGUEZ CA

    2012-03-07

    Historically, high-level waste (HLW) glasses have been formulated with a low liquideus temperature (T{sub L}), or temperature at which the equilibrium fraction of spinel crystals in the melt is below 1 vol % (T{sub 0.01}), nominally below 1050 C. These constraints cannot prevent the accumulation of large spinel crystals in considerably cooler regions ({approx} 850 C) of the glass discharge riser during melter idling and significantly limit the waste loading, which is reflected in a high volume of waste glass, and would result in high capital, production, and disposal costs. A developed empirical model predicts crystal accumulation in the riser of the melter as a function of concentration of spinel-forming components in glass, and thereby provides guidance in formulating crystal-tolerant glasses that would allow high waste loadings by keeping the spinel crystals small and therefore suspended in the glass.

  13. Nonlinear dynamics and instability of aqueous dissolution of silicate glasses and minerals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Yifeng; Jove-Colon, Carlos F.; Kuhlman, Kristopher L.

    2016-07-22

    Aqueous dissolution of silicate glasses and minerals plays a critical role in global biogeochemical cycles and climate evolution. The reactivity of these materials is also important to numerous engineering applications including nuclear waste disposal. The dissolution process has long been considered to be controlled by a leached surface layer in which cations in the silicate framework are gradually leached out and replaced by protons from the solution. This view has recently been challenged by observations of extremely sharp corrosion fronts and oscillatory zonings in altered rims of the materials, suggesting that corrosion of these materials may proceed directly through congruentmore » dissolution followed by secondary mineral precipitation. Here we show that complex silicate material dissolution behaviors can emerge from a simple positive feedback between dissolution-induced cation release and cation-enhanced dissolution kinetics. This self-accelerating mechanism enables a systematic prediction of the occurrence of sharp dissolution fronts (vs. leached surface layers), oscillatory dissolution behaviors and multiple stages of glass dissolution (in particular the alteration resumption at a late stage of a corrosion process). In conclusion, our work provides a new perspective for predicting long-term silicate weathering rates in actual geochemical systems and developing durable silicate materials for various engineering applications.« less

  14. Laser stimulated emission cross sections of Nd glasses

    SciTech Connect (OSTI)

    Tucker, A.W.; Birnbaum, M.; Fincher, C.L.

    1982-01-01

    A laser-comparison method was used to determine the emission cross sections at 1060 nm of Nd glasses used in laser fusion systems. The values obtained for two phosphate glasses (LHG-8) and (Q-88) were 4.0 +- 0.8 x 10/sup -20/ cm/sup 2/ and 1.7 +- 0.5 x 10/sup -20/ cm/sup 2/ for a silicate glass (LG-650).

  15. Formulation and Characterization of Waste Glasses with Varying Processing Temperature

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Schweiger, M. J.; Rodriguez, Carmen P.; Lepry, William C.; Lang, Jesse B.; Crum, Jarrod V.; Vienna, John D.; Johnson, Fabienne; Marra, James C.; Peeler, David K.

    2011-10-17

    This report documents the preliminary results of glass formulation and characterization accomplished within the finished scope of the EM-31 technology development tasks for WP-4 and WP-5, including WP-4.1.2: Glass Formulation for Next Generation Melter, WP-5.1.2.3: Systematic Glass Studies, and WP-5.1.2.4: Glass Formulation for Specific Wastes. This report also presents the suggested studies for eventual restart of these tasks. The initial glass formulation efforts for the cold crucible induction melter (CCIM), operating at {approx}1200 C, with selected HLW (AZ-101) and LAW (AN-105) successfully developed glasses with significant increase of waste loading compared to that is likely to be achieved based on expected reference WTP formulations. Three glasses formulated for AZ-101HLW and one glass for AN-105 LAW were selected for the initial CCIM demonstration melter tests. Melter tests were not performed within the finished scope of the WP-4.1.2 task. Glass formulations for CCIM were expanded to cover additional HLWs that have high potential to successfully demonstrate the unique advantages of the CCIM technologies based on projected composition of Hanford wastes. However, only the preliminary scoping tests were completed with selected wastes within the finished scope. Advanced glass formulations for the reference WTP melter, operating at {approx}1200 C, were initiated with selected specific wastes to determine the estimated maximum waste loading. The incomplete results from these initial formulation efforts are summarized. For systematic glass studies, a test matrix of 32 high-aluminum glasses was completed based on a new method developed in this study.

  16. Specs should increase use of fiber glass downhole

    SciTech Connect (OSTI)

    Biro, J.P. )

    1989-08-21

    Several American Petroleum Institute (API) committees are at work to develop product specifications for fiber glass tubulars. Specifications for low-pressure line pipe were issued in 1986. Specifications for high-pressure line pipe followed in 1988. A specification for fiber glass downhole tubing is expected to be issued in 1990. Finally, a specification for fiber glass casing is planned to be issued in 1991. The status of the specification is summarized in this paper.

  17. Phosphate glass useful in high power lasers

    DOE Patents [OSTI]

    Hayden, J.S.; Sapak, D.L.; Ward, J.M.

    1990-05-29

    A low- or no-silica phosphate glass useful as a laser medium and having a high thermal conductivity, K[sub 90 C] > 0.8 W/mK, and a low coefficient of thermal expansion, [alpha][sub 20--40 C] < 80[times]10[sup [minus]7]/C, consists essentially of (on a batch composition basis Mole %): P[sub 2]O[sub 5], 45-70; Li[sub 2]O, 15-35; Na[sub 2]O, 0-10; Al[sub 2]O[sub 3], 10-15; Nd[sub 2]O[sub 3], 0.01-6; La[sub 2]O[sub 3], 0-6; SiO[sub 2], 0-8; B[sub 2]O[sub 3], 0-8; MgO, 0-18; CaO, 0-15; SrO, 0-9; BaO, 0-9; ZnO, 0-15; the amounts of Li[sub 2]O and Na[sub 2]O providing an average alkali metal ionic radius sufficiently low whereby said glass has K[sub 90 C] > 0.8 W/mK and [alpha][sub 20--40 C] < 80[times]10[sup [minus]7]/C, and wherein, when the batch composition is melted in contact with a silica-containing surface, the final glass composition contains at most about 3.5 mole % of additional silica derived from such contact during melting. The Nd[sub 2]O[sub 3] can be replaced by other lasing species. 3 figs.

  18. Piezooptic coefficients of four neodymium-doped laser glasses

    SciTech Connect (OSTI)

    Waxler, R.M.; Feldman, A.

    1980-08-01

    The stress-induced birefringence was measured for the phosphate glasses Q-88, LG-812, E-181, and LHG-10. (AIP)

  19. Economic manufacturing of bulk metallic glass compositions by microalloying

    DOE Patents [OSTI]

    Liu, Chain T.

    2003-05-13

    A method of making a bulk metallic glass composition includes the steps of:a. providing a starting material suitable for making a bulk metallic glass composition, for example, BAM-11; b. adding at least one impurity-mitigating dopant, for example, Pb, Si, B, Sn, P, to the starting material to form a doped starting material; and c. converting the doped starting material to a bulk metallic glass composition so that the impurity-mitigating dopant reacts with impurities in the starting material to neutralize deleterious effects of the impurities on the formation of the bulk metallic glass composition.

  20. Glass-like thermal conductivity in high efficiency thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    thermal conductivity in high efficiency thermoelectric materials Glass-like thermal conductivity in high efficiency thermoelectric materials Discusses strategies to design ...

  1. Structural transition and orbital glass physics in near-itinerant...

    Office of Scientific and Technical Information (OSTI)

    Title: Structural transition and orbital glass physics in ... which can be driven metallic with moderate applied pressure. ... Type: Accepted Manuscript Journal Name: Physical Review B ...

  2. SAND REPORT Material Characterization of Glass, Carbon, and Hybrid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Material Characterization of Glass, Carbon, and Hybrid-Fiber SCRIMP Panels Akira Kuraishi, Stanford Unive m a l Laboratories w. e w Mexico 871 fuwer dissemination unlimited. @...

  3. Metal and Glass Manufacturers Reduce Costs by Increasing Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process heating plays a key role in producing steel, aluminum, and glass and in ... More Documents & Publications Commonwealth Aluminum: Manufacturer Conducts Plant-Wide ...

  4. Bandwidth Study U.S. Glass Fiber Reinforced Polymer Manufacturing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The study examines energy consumption and potential energy savings opportunities in U.S. glass fiber reinforced polymer manufacturing. The study relies on multiple sources to ...

  5. Potential for energy conservation in the glass industry

    SciTech Connect (OSTI)

    Garrett-Price, B.A.; Fassbender, A.G.; Bruno, G.A.

    1986-06-01

    While the glass industry (flat glass, container glass, pressed and blown glass, and insulation fiber glass) has reduced its specific energy use (Btu/ton) by almost 30% since 1972, significant potential for further reduction still remains. State-of-the-art technologies are available which could lead to incremental improvements in glass industry energy productivity; however, these technologies must compete for capital with projects undertaken for other reasons (e.g., capacity expansion, equipment rebuild, labor cost reduction, product quality improvement, or compliance with environmental, health or safety regulations). Narrowing profit margins in the large tonnage segments of the glass industry in recent years and the fact that energy costs represent less than 25% of the value added in glass manufacture have combined to impede the widespread adoption of many state-of-the-art conservation technologies. Savings in energy costs alone have not provided the incentive to justify the capital expenditures required to realize the energy savings. Beyond implementation of state-of-the-art technologies, significant potential energy savings could accrue from advanced technologies which represent a radical departure from current glass making technology. Long-term research and development (R and D) programs, which address the technical and economic barriers associated with advanced, energy-conserving technologies, offer the opportunity to realize this energy-saving potential.

  6. Rhenium volatilization in waste glasses (Journal Article) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Rhenium volatilization in waste glasses Citation Details In-Document ... OSTI Identifier: 1252517 Type: Publisher's Accepted Manuscript Journal Name: Journal of ...

  7. Shenzhen Sanxin Glass Technology Co Ltd SGT | Open Energy Information

    Open Energy Info (EERE)

    (SGT) Place: Shenzhen, Guangdong Province, China Product: Glass manufacturer for energy-saving curtain wall, and electronics. Coordinates: 22.546789, 114.112556 Show Map...

  8. Glass fiber composition. [for use as thermal insulation

    DOE Patents [OSTI]

    Wolf, G.A.; Kupfer, M.J.

    1980-12-19

    The invention relates to a glass fiber composition useful for thermal insulation having a low melting temperature and high chemical durability.

  9. Time-Domain Electromagnetics At Glass Mountain Area (Cumming...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Time-Domain Electromagnetics At Glass Mountain Area (Cumming And Mackie, 2007) Exploration...

  10. Thermal Predictions of the Cooling of Waste Glass Canisters

    SciTech Connect (OSTI)

    Donna Post Guillen

    2014-11-01

    Radioactive liquid waste from five decades of weapons production is slated for vitrification at the Hanford site. The waste will be mixed with glass forming additives and heated to a high temperature, then poured into canisters within a pour cave where the glass will cool and solidify into a stable waste form for disposal. Computer simulations were performed to predict the heat rejected from the canisters and the temperatures within the glass during cooling. Four different waste glass compositions with different thermophysical properties were evaluated. Canister centerline temperatures and the total amount of heat transfer from the canisters to the surrounding air are reported.

  11. Method of processing ``BPS`` glass ceramic and seals made therewith

    DOE Patents [OSTI]

    Reed, S.T.; Stone, R.G.; McCollister, H.L.; Wengert, P.R.

    1998-10-13

    A glass ceramic composition, a glass ceramic-to-metal seal, and more specifically a hermetic glass ceramic-to-metal seal prepared by subjecting a glass composition comprising, by weight percent, SiO{sub 2} (65--80%), LiO{sub 2} (8--16%), Al{sub 2}O{sub 3} (2--8%), K{sub 2}O (1--8%), P{sub 2}O{sub 5} (1--5%), B{sub 2}O{sub 3} (0.5--7%), and ZnO (0--5%) to the following processing steps: (1) heating the glass composition in a belt furnace to a temperature sufficient to melt the glass and crystallize lithium phosphate, (2) holding at a temperature and for a time sufficient to create cristobalite nuclei, (3) cooling at a controlled rate and to a temperature to cause crystallization of lithium silicates and growth of cristobalite, and (4) still further cooling in stages to ambient temperature. This process produces a glass ceramic whose high coefficient of thermal expansion (up to 200{times}10{sup {minus}7} in/in/C) permits the fabrication of glass ceramic-to-metal seals, and particularly hermetic glass ceramic seals to nickel-based and stainless steel alloys and copper. 5 figs.

  12. Dongguan CSG Solar Glass Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Guangdong Province, China Product: Chinese manufacturer of PV glass. Coordinates: 23.046499, 113.735817 Show Map Loading map... "minzoom":false,"mappingservice":"google...

  13. Method of processing "BPS" glass ceramic and seals made therewith

    DOE Patents [OSTI]

    Reed, Scott T.; Stone, Ronald G.; McCollister, Howard L.; Wengert, deceased, Paul R.

    1998-01-01

    A glass ceramic composition, a glass ceramic-to-metal seal, and more specifically a hermetic glass ceramic-to-metal seal prepared by subjecting a glass composition comprising, by weight percent, SiO.sub.2 (65-80%), LiO.sub.2 (8-16%), Al.sub.2 O.sub.3 (2-8%), K.sub.2 O (1-8%), P.sub.2 O.sub.5 (1-5%), B.sub.2 O.sub.3 (0.5-7%), and ZnO (0-5%) to the following processing steps: 1) heating the glass composition in a belt furnace to a temperature sufficient to melt the glass and crystallize lithium phosphate, 2) holding at a temperature and for a time sufficient to create cristobalite nuclei, 3) cooling at a controlled rate and to a temperature to cause crystallization of lithium silicates and growth of cristobalite, and 4) still further cooling in stages to ambient temperature. This process produces a glass ceramic whose high coefficient of thermal expansion (up to 200.times.10.sup.-7 in/in/.degree.C.) permits the fabrication of glass ceramic-to-metal seals, and particularly hermetic glass ceramic seals to nickel-based and stainless steel alloys and copper.

  14. Refraction and dispersion in optical glass. (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Refraction and dispersion in optical glass. No abstract prepared. Authors: Smith, D. Y. ; Shiles, E. ; Inokuti, M. Publication Date: ...

  15. Fabrication of anatase precipitated glass-ceramics possessing high transparency

    SciTech Connect (OSTI)

    Masai, Hirokazu; Toda, Tatsuya; Takahashi, Yoshihiro; Fujiwara, Takumi

    2009-04-13

    Transparent anatase precipitated glass-ceramics were fabricated using ZnO as a component. The particle size of precipitated anatase is several nanometers enough to possess high transparency. The preparation of the Bi-free transparent TiO{sub 2} glass-ceramic was attained by substitution of two different kinds of oxides for bismuth oxide. It is also noteworthy that we have demonstrated the crystallization of metastable anatase in the glass-ceramics as a main phase. The present bulk anatase glass-ceramics will open up an application field for a TiO{sub 2}-containing photocatalyst.

  16. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, L.A.; Sales, B.C.; Franco, S.C.S.

    1994-03-29

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications. 6 figures.

  17. Welding/sealing glass-enclosed space in a vacuum

    DOE Patents [OSTI]

    Tracy, C.E.; Benson, D.K.

    1996-02-06

    A method of welding and sealing the edges of two juxtaposed glass sheets together to seal a vacuum space between the sheets comprises the steps of positioning a radiation absorbent material, such as FeO, VO{sub 2}, or NiO, between the radiation transmissive glass sheets adjacent the edges and then irradiating the absorbent material, preferably with a laser beam, through at least one of the glass sheets. Heat produced by the absorbed radiation in the absorbent material melts glass in the portions of both glass sheets that are adjacent the absorbent material, and the melted glass from both sheets flows together to create the weld when the melted glass cools and hardens. The absorbent material can be dissolved and diffused into the melted glass to the extent that it no longer absorbs enough energy to keep the glass melted, thus, with appropriate proportioning of absorbent material to source energy power and welding heat needed, the process can be made self-stopping. 8 figs.

  18. Welding/sealing glass-enclosed space in a vacuum

    DOE Patents [OSTI]

    Tracy, C. Edwin; Benson, David K.

    1996-01-01

    A method of welding and sealing the edges of two juxtaposed glass sheets together to seal a vacuum space between the sheets comprises the steps of positioning a radiation absorbant material, such as FeO, VO.sub.2, or NiO, between the radiation transmissive glass sheets adjacent the edges and then irradiating the absorbant material, preferably with a laser beam, through at least one of the glass sheets. Heat produced by the absorbed radiation in the absorbant material melts glass in the portions of both glass sheets that are adjacent the absorbant material, and the melted glass from both sheets flows together to create the weld when the melted glass cools and hardens. The absorbant material can be dissolved and diffused into the melted glass to the extent that it no longer absorbs enough energy to keep the glass melted, thus, with appropriate proportioning of absorbant material to source energy power and welding heat needed, the process can be made self-stopping.

  19. Compliant Glass-Polymer Hybrid Single Ion-ConductingElectrolytes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Compliant Glass-Polymer Hybrid Single Ion-ConductingElectrolytes for Lithium Batteries ... excellent electrochemical stability, and limit the dissolution of lithium polysulfides. ...

  20. Alkali-lead-iron phosphate glass and associated method

    DOE Patents [OSTI]

    Boatner, Lynn A.; Sales, Brian C.; Franco, Sofia C. S.

    1994-01-01

    A glass composition and method of preparation utilizes a mixture consisting of phosphorus oxide within the range of about 40 to 49 molar percent, lead oxide within the range of about 10 to 25 molar percent, iron oxide within the range of about 10 to 17 molar percent and an alkali oxide within the range of about 23 to 30 molar percent. The glass resulting from the melting and subsequent solidifying of the mixture possesses a high degree of durability and a coefficient of thermal expansion as high as that of any of a number of metals. Such features render this glass highly desirable in glass-to-metal seal applications.

  1. Rhenium Solubility in Borosilicate Nuclear Waste Glass: Implications...

    Office of Scientific and Technical Information (OSTI)

    In this context, the present article reports on the solubilityretention of rhenium, a nonradioactive surrogate for 99Tc, in a LAW borosilicate glass. Due to the radioactive nature ...

  2. Controlled permeation of hydrogen through glass. Final report

    SciTech Connect (OSTI)

    Halvorson, T.; Shelby, J.E. Jr.

    1998-03-01

    Storing hydrogen inside of hollow glass spheres requires that the gas permeate through the glass walls. Hydrogen permeation through glass is relatively slow and the time to charge a sphere or bed of spheres is dependent on many factors. Permeation processes are strongly temperature dependent with behavior that follows an Arrhenius function., Rate is also dependent on the pressure drop driving force across a membrane wall and inversely proportional to thickness. Once filled, glass spheres will immediately begin to leak once the pressure driving force is reversed. Practical systems would take advantage of the fact that keeping the glass at ambient temperatures can minimize outboard leakage even with significant internal pressures. If hydrogen could be loaded and unloaded from glass microspheres with significantly less energy and particularly at near ambient temperature, some of the key barriers to commercializing this storage concept would be broken and further system engineering efforts may make this approach cost-effective. There were two key objectives for this effort. The first was to evaluate the application of hollow glass microspheres for merchant hydrogen storage and distribution and then determine the hydrogen permeation performance required for practical commercial use. The second objective was to identify, through a series of fundamental experiments, a low energy, low temperature field effect that could significantly enhance hydrogen permeation through glass without application of heat. If such an effect could be found, hollow glass microspheres could be much more attractive for hydrogen storage or possibly gas separation applications.

  3. Thermal Gradient Holes At Glass Mountain Area (Cumming And Mackie...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal Gradient Holes At Glass Mountain Area (Cumming And Mackie, 2007) Exploration Activity...

  4. Advanced radioactive waste-glass melters

    SciTech Connect (OSTI)

    Bickford, D.F.

    1990-01-01

    During pilot scale operations of the Scale Glass Melter for the US Department of Energy a team of engineers and scientists was formed to assess the need for continued melter design development to support the Defense Waste Processing Facility (DWPF), and prioritize future efforts. Recently this has taken on new importance because of selection of the DWPF Melter design as the reference for the Hanford Waste Vitrification Project (HWVP), and increased interest at the West Valley Demonstration Project on melter life and replacement. Results of the study are summarized, and goals produced by the study are compared to the results of current programs at the Savannah River Laboratory (SRL).

  5. Advanced radioactive waste-glass melters

    SciTech Connect (OSTI)

    Bickford, D.F.

    1990-12-31

    During pilot scale operations of the Scale Glass Melter for the US Department of Energy a team of engineers and scientists was formed to assess the need for continued melter design development to support the Defense Waste Processing Facility (DWPF), and prioritize future efforts. Recently this has taken on new importance because of selection of the DWPF Melter design as the reference for the Hanford Waste Vitrification Project (HWVP), and increased interest at the West Valley Demonstration Project on melter life and replacement. Results of the study are summarized, and goals produced by the study are compared to the results of current programs at the Savannah River Laboratory (SRL).

  6. Hydrogen in an oscillating porous vycor glass

    SciTech Connect (OSTI)

    Kondo, Y.; Schindler, M.; Pobell, F.

    1995-10-01

    The authors investigate hydrogen in porous Vycor glass with a torsional oscillator technique. Although our primary purpose is searching for a superfluid transition of hydrogen supercooled in Vycor, we find that hydrogen molecules which are adsorbed and liquefied in Vycor at T > T{sub 3} (triple point of bulk H{sub 2}) leave the Vycor when decreasing the temperature to below a characteristic value T{sub c} < T{sub 3}. We discuss this phenomenon in terms of a free enregy balance between solid/liquid hydrogen inside and outside the Vycor.

  7. Oxygen-reducing catalyst layer

    DOE Patents [OSTI]

    O'Brien, Dennis P.; Schmoeckel, Alison K.; Vernstrom, George D.; Atanasoski, Radoslav; Wood, Thomas E.; Yang, Ruizhi; Easton, E. Bradley; Dahn, Jeffrey R.; O'Neill, David G.

    2011-03-22

    An oxygen-reducing catalyst layer, and a method of making the oxygen-reducing catalyst layer, where the oxygen-reducing catalyst layer includes a catalytic material film disposed on a substrate with the use of physical vapor deposition and thermal treatment. The catalytic material film includes a transition metal that is substantially free of platinum. At least one of the physical vapor deposition and the thermal treatment is performed in a processing environment comprising a nitrogen-containing gas.

  8. Molten Glass for Thermal Storage: Advanced Molten Glass for Heat Transfer and Thermal Energy Storage

    SciTech Connect (OSTI)

    2012-01-01

    HEATS Project: Halotechnics is developing a high-temperature thermal energy storage system using a new thermal-storage and heat-transfer material: earth-abundant and low-melting-point molten glass. Heat storage materials are critical to the energy storage process. In solar thermal storage systems, heat can be stored in these materials during the day and released at night—when the sun is not out—to drive a turbine and produce electricity. In nuclear storage systems, heat can be stored in these materials at night and released to produce electricity during daytime peak-demand hours. Halotechnics new thermal storage material targets a price that is potentially cheaper than the molten salt used in most commercial solar thermal storage systems today. It is also extremely stable at temperatures up to 1200°C—hundreds of degrees hotter than the highest temperature molten salt can handle. Being able to function at high temperatures will significantly increase the efficiency of turning heat into electricity. Halotechnics is developing a scalable system to pump, heat, store, and discharge the molten glass. The company is leveraging technology used in the modern glass industry, which has decades of experience handling molten glass.

  9. Crystallization In High Level Waste (HLW) Glass Melters: Operational Experience From The Savannah River Site

    SciTech Connect (OSTI)

    Fox, K. M.

    2014-02-27

    processing strategy for the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The basis of this alternative approach is an empirical model predicting the crystal accumulation in the WTP glass discharge riser and melter bottom as a function of glass composition, time, and temperature. When coupled with an associated operating limit (e.g., the maximum tolerable thickness of an accumulated layer of crystals), this model could then be integrated into the process control algorithms to formulate crystal tolerant high level waste (HLW) glasses targeting higher waste loadings while still meeting process related limits and melter lifetime expectancies. This report provides a review of the scaled melter testing that was completed in support of the Defense Waste Processing Facility (DWPF) melter. Testing with scaled melters provided the data to define the DWPF operating limits to avoid bulk (volume) crystallization in the un-agitated DWPF melter and provided the data to distinguish between spinels generated by K-3 refractory corrosion versus spinels that precipitated from the HLW glass melt pool. This report includes a review of the crystallization observed with the scaled melters and the full scale DWPF melters (DWPF Melter 1 and DWPF Melter 2). Examples of actual DWPF melter attainment with Melter 2 are given. The intent is to provide an overview of lessons learned, including some example data, that can be used to advance the development and implementation of an empirical model and operating limit for crystal accumulation for WTP. Operation of the first and second (current) DWPF melters has demonstrated that the strategy of using a liquidus temperature predictive model combined with a 100 °C offset from the normal melter operating temperature of 1150 °C (i.e., the predicted liquidus temperature (TL) of the glass must be 1050 °C or less) has been successful in preventing any detrimental accumulation of spinel in the DWPF melt pool, and spinel has not been

  10. Layer-by-Layer Assembly of Enzymes on Carbon Nanotubes

    SciTech Connect (OSTI)

    Wang, Jun; Liu, Guodong; Lin, Yuehe

    2008-06-01

    The use of Layer-by-layer techniques for immobilizing several types of enzymes, e.g. glucose oxidase (GOx), horse radish oxidases(HRP), and choline oxidase(CHO) on carbon nanotubes and their applications for biosenseing are presented. The enzyme is immobilized on the negatively charged CNT surface by alternatively assembling a cationic polydiallyldimethyl-ammonium chloride (PDDA) layer and a enzyme layer. The sandwich-like layer structure (PDDA/enzyme/PDDA/CNT) formed by electrostatic assembling provides a favorable microenvironment to keep the bioactivity of enzyme and to prevent enzyme molecule leakage. The morphologies and electrocatalytic acitivity of the resulted enzyme film were characterized using TEM and electrochemical techniques, respectively. It was found that these enzyme-based biosensors are very sensitive, selective for detection of biomolecules, e.g. glucose, choline.

  11. Leakage pathway layer for solar cell

    SciTech Connect (OSTI)

    Luan, Andy; Smith, David; Cousins, Peter; Sun, Sheng

    2015-12-01

    Leakage pathway layers for solar cells and methods of forming leakage pathway layers for solar cells are described.

  12. Glass ceramic toughened with tetragonal zirconia

    DOE Patents [OSTI]

    Keefer, Keith D. (Albuquerque, NM); Michalske, Terry A. (Sandia Park, NM)

    1986-01-01

    A phase transformation-toughened glass ceramic and a process for making it are disclosed. A mixture of particulate network-forming oxide, network-modifying oxide, and zirconium oxide is heated to yield a homogeneous melt, and this melt is then heat-treated to precipitate an appreciable quantity of tetragonal zirconia, which is retained at ambient temperature to form a phase transformation-toughened glass ceramic. Nucleating agents and stabilizing agents may be added to the mixture to facilitate processing and improve the ceramic's properties. Preferably, the mixture is first melted at a temperature from 1200.degree. to 1700.degree. C. and is then heat-treated at a temperature within the range of 800.degree. to 1200.degree. C. in order to precipitate tetragonal ZrO.sub.2. The composition, as well as the length and temperature of the heat-treatment, must be carefully controlled to prevent solution of the precipitated tetragonal zirconia and subsequent conversion to the monoclinic phase.

  13. Optical Basicity and Nepheline Crystallization in High Alumina Glasses

    SciTech Connect (OSTI)

    Rodriguez, Carmen P.; McCloy, John S.; Schweiger, M. J.; Crum, Jarrod V.; Winschell, Abigail E.

    2011-02-25

    The purpose of this study was to find compositions that increase waste loading of high-alumina wastes beyond what is currently acceptable while avoiding crystallization of nepheline (NaAlSiO4) on slow cooling. Nepheline crystallization has been shown to have a large impact on the chemical durability of high-level waste glasses. It was hypothesized that there would be some composition regions where high-alumina would not result in nepheline crystal production, compositions not currently allowed by the nepheline discriminator. Optical basicity (OB) and the nepheline discriminator (ND) are two ways of describing a given complex glass composition. This report presents the theoretical and experimental basis for these models. They are being studied together in a quadrant system as metrics to explore nepheline crystallization and chemical durability as a function of waste glass composition. These metrics were calculated for glasses with existing data and also for theoretical glasses to explore nepheline formation in Quadrant IV (passes OB metric but fails ND metric), where glasses are presumed to have good chemical durability. Several of these compositions were chosen, and glasses were made to fill poorly represented regions in Quadrant IV. To evaluate nepheline formation and chemical durability of these glasses, quantitative X-ray diffraction (XRD) analysis and the Product Consistency Test were conducted. A large amount of quantitative XRD data is collected here, both from new glasses and from glasses of previous studies that had not previously performed quantitative XRD on the phase assemblage. Appendix A critically discusses a large dataset to be considered for future quantitative studies on nepheline formation in glass. Appendix B provides a theoretical justification for choice of the oxide coefficients used to compute the OB criterion for nepheline formation.

  14. Initial Examination of Low Velocity Sphere Impact of Glass Ceramics

    SciTech Connect (OSTI)

    Morrissey, Timothy G; Fox, Ethan E; Wereszczak, Andrew A; Ferber, Mattison K

    2012-06-01

    This report summarizes US Army TARDEC sponsored work at Oak Ridge National Laboratory (ORNL) involving low velocity (< 30 m/s or < 65 mph) sphere impact testing of two materials from the lithium aluminosilicate family reinforced with different amounts of ceramic particulate, i.e., glass-ceramic materials, SCHOTT Resistan{trademark}-G1 and SCHOTT Resistan{trademark}-L. Both materials are provided by SCHOTT Glass (Duryea, PA). This work is a follow-up to similar sphere impact studies completed by the authors on PPG's Starphire{reg_sign} soda-lime silicate glass and SCHOTT BOROFLOAT{reg_sign} borosilicate glass. A gas gun or a sphere-drop test setup was used to produce controlled velocity delivery of silicon nitride (Si{sub 3}N{sub 4}) spheres against the glass ceramic tile targets. Minimum impact velocities to initiate fracture in the glass-ceramics were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between sphere and target material. Quasistatic spherical indentation was also performed on both glass ceramics and their contact damage responses were compared to those of soda-lime silicate and borosilicate glasses. Lastly, variability of contact damage response was assessed by performing spherical indentation testing across the area of an entire glass ceramic tile. The primary observations from this low velocity (< 30 m/s or < 65 mph) testing were: (1) Resistan{trademark}-L glass ceramic required the highest velocity of sphere impact for damage to initiate. Starphire{reg_sign} soda-lime silicate glass was second best, then Resistan{trademark}-G1 glass ceramic, and then BOROFLOAT{reg_sign} borosilicate glass. (2) Glass-ceramic Resistan{trademark}-L also required the largest force to initiate ring crack from quasi-static indentation. That ranking was followed, in descending order, by Starphire{reg_sign} soda-lime silicate glass, Resistan{trademark}-G1 glass ceramic, and BOROFLOAT{reg_sign} borosilicate glass. (3

  15. Photocatalytic activity of glass ceramics containing Nasicon-type crystals

    SciTech Connect (OSTI)

    Fu, Jie

    2013-01-15

    Graphical abstract: Display Omitted Highlights: ? Glass ceramics containing Nasicon-type crystals were prepared. ? The glass ceramics showed photocatalytic activity under UV irradiation. ? Higher activity was observed in the MgTi{sub 4}(PO{sub 4}){sub 6}- and CaTi{sub 4}(PO{sub 4}){sub 6}-containing glass ceramics. -- Abstract: Glass ceramics were prepared by heat-treating MOTiO{sub 2}P{sub 2}O{sub 5} (M = Mg, Ca, Sr and Ba) and R{sub 2}OTiO{sub 2}P{sub 2}O{sub 5}SiO{sub 2} (R = Li, Na and K) glasses, and their photocatalytic activity was investigated. The crystalline phases precipitated in the glasses were only Nasicon-type crystals, MTi{sub 4}(PO{sub 4}){sub 6} or RTi{sub 2}(PO{sub 4}){sub 3}. Decomposition experiments of both methylene blue (MB) and acetaldehyde showed that the glass ceramics exhibited effective photocatalytic activity. The activity did not depend on the radius of the M{sup 2+} or R{sup +} ion, and higher activity was observed in the MgTi{sub 4}(PO{sub 4}){sub 6} and CaTi{sub 4}(PO{sub 4}){sub 6} precipitated glass ceramics.

  16. Computational fluid dynamics simulations of a glass melting furnace

    SciTech Connect (OSTI)

    Egelja, A.; Lottes, S. A.

    2000-05-09

    The glass production industry is one of the major users of natural gas in the US, and approximately 75% of the energy produced from natural gas is used in the melting process. Industrial scale glass melting furnaces are large devices, typically 5 or more meters wide, and twice as long. To achieve efficient heat transfer to the glass melt below, the natural gas flame must extend over a large portion of the glass melt. Therefore modern high efficiency burners are not used in these furnaces. The natural gas is injected as a jet, and a jet flame forms in the flow of air entering the furnace. In most current glass furnaces the energy required to melt the batch feed stock is about twice the theoretical requirement. An improved understanding of the heat transfer and two phase flow processes in the glass melt and solid batch mix offers a substantial opportunity for energy savings and consequent emission reductions. The batch coverage form and the heat flux distribution have a strong influence on the glass flow pattern. This flow pattern determines to a significant extent the melting rate and the quality of glass.

  17. The recycling of the coal fly ash in glass production

    SciTech Connect (OSTI)

    Erol, M.M.; Kucukbayrak, S.; Ersoy-Mericboyu, A.

    2006-09-15

    The recycling of fly ash obtained from the combustion of coal in thermal power plant has been studied. Coal fly ash was vitrified by melting at 1773 K for 5 hours without any additives. The properties of glasses produced from coal fly ash were investigated by means of Differential Thermal Analysis (DTA), X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) techniques. DTA study indicated that there was only one endothermic peak at 1003 K corresponding to the glass transition temperature. XRD analysis showed the amorphous state of the glass sample produced from coal fly ash. SEM investigations revealed that the coal fly ash based glass sample had smooth surface. The mechanical, physical and chemical properties of the glass sample were also determined. Recycling of coal fly ash by using vitrification technique resulted to a glass material that had good mechanical, physical and chemical properties. Toxicity characteristic leaching procedure (TCLP) results showed that the heavy metals of Pb, Cr, Zn and Mn were successfully immobilized into the glass. It can be said that glass sample obtained by the recycling of coal fly ash can be taken as a non-hazardous material. Overall, results indicated that the vitrification technique is an effective way for the stabilization and recycling of coal fly ash.

  18. Assessment, development, and testing of glass for blast environments.

    SciTech Connect (OSTI)

    Glass, Sarah Jill

    2003-06-01

    Glass can have lethal effects including fatalities and injuries when it breaks and then flies through the air under blast loading (''the glass problem''). One goal of this program was to assess the glass problem and solutions being pursued to mitigate it. One solution to the problem is the development of new glass technology that allows the strength and fragmentation to be controlled or selected depending on the blast performance specifications. For example the glass could be weak and fail, or it could be strong and survive, but it must perform reliably. Also, once it fails it should produce fragments of a controlled size. Under certain circumstances it may be beneficial to have very small fragments, in others it may be beneficial to have large fragments that stay together. The second goal of this program was to evaluate the performance (strength, reliability, and fragmentation) of Engineered Stress Profile (ESP) glass under different loading conditions. These included pseudo-static strength and pressure tests and free-field blast tests. The ultimate goal was to provide engineers and architects with a glass whose behavior under blast loading is less lethal. A near-term benefit is a new approach for improving the reliability of glass and modifying its fracture behavior.

  19. Glass Development for Treatment of LANL Evaporator Bottoms Waste

    SciTech Connect (OSTI)

    DE Smith; GF Piepel; GW Veazey; JD Vienna; ML Elliott; RK Nakaoka; RP Thimpke

    1998-11-20

    Vitrification is an attractive treatment option for meeting the stabilization and final disposal requirements of many plutonium (Pu) bearing materials and wastes at the Los Alamos National Laboratory (LANL) TA-55 facility, Rocky Flats Environmental Technology Site (RFETS), Hanford, and other Department of Energy (DOE) sites. The Environmental Protection Agency (EPA) has declared that vitrification is the "best demonstrated available technology" for high- level radioactive wastes (HLW) (Federal Register 1990) and has produced a handbook of vitriilcation technologies for treatment of hazardous and radioactive waste (US EPA, 1992). This technology has been demonstrated to convert Pu-containing materials (Kormanos, 1997) into durable (Lutze, 1988) and accountable (Forsberg, 1995) waste. forms with reduced need for safeguarding (McCulhun, 1996). The composition of the Evaporator Bottoms Waste (EVB) at LANL, like that of many other I%-bearing materials, varies widely and is generally unpredictable. The goal of this study is to optimize the composition of glass for EVB waste at LANL, and present the basic techniques and tools for developing optimized glass compositions for other Pu-bearing materials in the complex. This report outlines an approach for glass formulation with fixed property restrictions, using glass property-composition databases. This approach is applicable to waste glass formulation for many variable waste streams and vitrification technologies.. Also reported are the preliminary property data for simulated evaporator bottom glasses, including glass viscosity and glass leach resistance using the Toxicity Characteristic Leaching Procedure (TCLP).

  20. Solubility effects in waste-glass/demineralized-water systems

    SciTech Connect (OSTI)

    Fullam, H.T.

    1981-06-01

    Aqueous systems involving demineralized water and four glass compositions (including standins for actinides and fission products) at temperatures of up to 150/sup 0/C were studied. Two methods were used to measure the solubility of glass components in demineralized water. One method involved approaching equilibrium from subsaturation, while the second method involved approaching equilibrium from supersaturation. The aqueous solutions were analyzed by induction-coupled plasma spectrometry (ICP). Uranium was determined using a Scintrex U-A3 uranium analyzer and zinc and cesium were determined by atomic absorption. The system that results when a waste glass is contacted with demineralized water is a complex one. The two methods used to determine the solubility limits gave very different results, with the supersaturation method yielding much higher solution concentrations than the subsaturation method for most of the elements present in the waste glasses. The results show that it is impossible to assign solubility limits to the various glass components without thoroughly describing the glass-water systems. This includes not only defining the glass type and solution temperature, but also the glass surface area-to-water volume ratio (S/V) of the system and the complete thermal history of the system. 21 figures, 22 tables. (DLC)

  1. Iron Phosphate Glasses: An Alternative for Vitrifying Certain Nuclear Wastes

    SciTech Connect (OSTI)

    Delbert E. Day; Chandra S. Ray; Cheol-Woon Kim

    2004-12-28

    Vitrification of nuclear waste in a glass is currently the preferred process for waste disposal. DOE currently approves only borosilicate (BS) type glasses for such purposes. However, many nuclear wastes, presently awaiting disposal, have complex and diverse chemical compositions, and often contain components that are poorly soluble or chemically incompatible in BS glasses. Such problematic wastes can be pre-processed and/or diluted to compensate for their incompatibility with a BS glass matrix, but both of these solutions increases the wasteform volume and the overall cost for vitrification. Direct vitrification using alternative glasses that utilize the major components already present in the waste is preferable, since it avoids pre-treating or diluting the waste, and, thus, minimizes the wasteform volume and overall cost.

  2. Recent advances in phosphate laser glasses for high power applications

    SciTech Connect (OSTI)

    Campbell, J.H.

    1996-05-14

    Recent advances in Nd-doped phosphate laser glasses for high-peak-power and high-average-power applications are reviewed. Compositional studies have progressed to the point that glasses can be tailored to have specific properties for specific applications. Non-radiative relaxation effects can be accurately modeled and empirical expressions have been developed to evaluate both intrinsic (structural) and extrinsic (contamination induced) relaxation effects. Losses due to surface scattering and bulk glass absorption have been carefully measured and can be accurately predicted. Improvements in processing have lead to high damage threshold (e.g. Pt inclusion free) and high thermal shock resistant glasses with improved edge claddings. High optical quality pieces up to 79 x 45 x 4cm{sup 3} have been made and methods for continuous melting laser glass are under development.

  3. Removal Rate Model for Magnetorheological Finishing of Glass

    SciTech Connect (OSTI)

    DeGroote, J.E.; Marino, A.E.; WIlson, J.P.; Bishop, A.L.; Lambropoulos, J.C.; Jacobs, S.D.

    2007-11-14

    Magnetorheological finishing (MRF) is a deterministic subaperture polishing process. The process uses a magntorheological (MR) fluid that consists of micrometer-sized, spherical, magnetic carbonyl iron (CI) particles, nonmagnetic polishing abrasives, water, and stabilizers. Material removal occurs when the CI and nonmagnetic polishing abrasives shear material off the surface being polished. We introduce a new MRF material removal rate model for glass. This model contains terms for the near surface mechanical properties of glass, drag force, polishing abrasive size and concentration, chemical durability of the glass, MR fluid pH, and the glass composition. We introduce quantitative chemical predictors for the first time, to the best of our knowledge, into an MRF removal rate model. We validate individual terms in our model separately and then combine all of the terms to show the whole MRF material removal model compared with experimental data. All of our experimental data were obtained using nanodiamond MR fluids and a set of six optical glasses.

  4. Glass capable of ionic conduction and method of preparation

    DOE Patents [OSTI]

    Susman, Sherman (Park Forest, IL); Boehm, Leah (Jerusalem, IL); Volin, Kenneth J. (Fort Collins, CO); Delbacq, Charles J. (Downers Grove, IL)

    1985-01-01

    Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS.sub.2, B.sub.2 S.sub.3 and SiS.sub.2 in mixture with a glass modifier such as Na.sub.2 S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1-X) Na.sub.2 O:XB.sub.2 S.sub.3 is disclosed.

  5. Glass capable of ionic conduction and method of preparation

    DOE Patents [OSTI]

    Susman, Sherman (Park Forest, IL); Delbecq, Charles J. (Downers Grove, IL); Volin, Kenneth J. (Fort Collins, CO); Boehm, Leah (Jerusalem, IL)

    1984-01-01

    Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS.sub.2, B.sub.2 S.sub.3 and SiS.sub.2 in mixture with a glass modifier such as Na.sub.2 S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1-X) Na.sub.2 O:XB.sub.2 S.sub.3 is disclosed.

  6. Glass capable of ionic conduction and method of preparation

    DOE Patents [OSTI]

    Susman, S.; Boehm, L.; Volin, K.J.; Delbecq, C.J.

    1982-05-06

    Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS/sub 2/, B/sub 2/S/sub 2/ and SiS/sub 2/ in mixture with a glass modifier such as Na/sub 2/S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1 - X) Na/sub 2/O:XB/sub 2/S/sub 3/ is disclosed.

  7. Glass capable of ionic conduction and method of preparation

    DOE Patents [OSTI]

    Susman, S.; Delbecq, C.J.; Volin, K.J.; Boehm, L.

    1984-02-21

    Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS[sub 2], B[sub 2]S[sub 3] and SiS[sub 2] in mixture with a glass modifier such as Na[sub 2]S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1-X) Na[sub 2]O:XB[sub 2]S[sub 3] is disclosed. 4 figs.

  8. Elimination of platinum inclusions in phosphate laser glasses

    SciTech Connect (OSTI)

    Campbell, J.H.; Wallerstein, E.P. ); Hayden, J.S.; Sapak, D.L.; Warrington, D.E.; Marker, A.J. III ); Toratani, H.; Meissner, H.; Nakajima, S.; Izumitani, T. )

    1989-05-26

    Results from small-scale glass melting experiments aimed at reducing the density of platinum particles in phosphate laser glasses are discussed. The platinum particles originate from the crucibles used to melt the laser glass and can cause optical damage in glasses used in high-peak-power lasers; this problem was particularly acute in the LLNL 120 kJ, 100 TW Nova laser. The melting experiments examine the effects of (i) N{sub 2}, O{sub 2}, and Cl{sub 2} gas atmospheres; (ii) temperature and temperature gradients; (iii) processing time; and (iv) platinum alloys on the formation and dissolution of platinum inclusions in LHG-8 and LG-750 phosphate laser glasses. Results show that most platinum inclusions originate early in the melt cycle, with thermal gradients within the melter being one of the major causes. By using oxidizing gas conditions (O{sub 2}, Cl{sub 2}, or O{sub 2} + Cl{sub 2}), the platinum inclusions can be dissolved into the glass during the course of the melt cycle. The dissolution rate of platinum under oxidizing conditions has been measured, and a model is used to quantify the description of the dissolution process. The effect of ionic platinum on the transmission spectra of the laser glasses produced under various oxidizing conditions has also been measured. Results from the above laboratory-scale melting experiments have been incorporated into proprietary laser-glass melting processes. The laser glasses prepared under these conditions have an average of less than 0.1 platinum inclusions/liter, which represents a 1000-fold reduction over the previously available phosphate laser glasses. 52 refs., 56 figs., 15 tabs.

  9. Semiconducting glasses: A new class of thermoelectric materials?

    SciTech Connect (OSTI)

    Goncalves, A.P.; Vaney, J.B.; Lenoir, B.; Piarristeguy, A.; Pradel, A.; Monnier, J.; Ochin, P.; Godart, C.

    2012-09-15

    The deeper understanding of the factors that affect the dimensionless figure of merit, ZT, and the use of new synthetic methods has recently led to the development of novel systems with improved thermoelectric performances. Albeit up to now with ZT values lower than the conventional bulk materials, semiconducting glasses have also emerged as a new family of potential thermoelectric materials. This paper reviews the latest advances on semiconducting glasses for thermoelectric applications. Key examples of tellurium-based glasses, with high Seebeck coefficients, very low thermal conductivities and tunable electrical conductivities, are presented. ZT values as high as 0.2 were obtained at room temperature for several tellurium-based glasses with high copper concentrations, confirming chalcogenide semiconducting glasses as good candidates for high-performance thermoelectric materials. However, the temperature stability and electrical conductivity of the reported glasses are still not good enough for practical applications and further studies are still needed to enhance them. - Graphical abstract: Power factor as a function of the temperature for the Cu{sub 27.5}Ge{sub 2.5}Te{sub 70} and Cu{sub 30}As{sub 15}Te{sub 55} seniconducting glasses. Highlights: Black-Right-Pointing-Pointer A review of semiconducting glasses for thermoelectrics applications is presented. Black-Right-Pointing-Pointer The studied semiconducting glasses present very low thermal conductivities. Black-Right-Pointing-Pointer Composition can tune electrical conductivity and Seebeck coefficient. Black-Right-Pointing-Pointer ZT=0.2 is obtained at 300 K for different semiconducting glasses.

  10. Effects of Nanodiamond Abrasive Friability in Experimental MR Fluids with Phosphate Laser Glass LHG-8 and Other Optical Glasses

    SciTech Connect (OSTI)

    DeGroote, J.E.; Marino, A.E.; Wilson, J.P.; Spencer, K.E.; Jacobs, S.D.

    2005-09-22

    Research is currently being conducted to better understand the role that nanodiamond abrasives play in the removal process of Magnetorheological Finishing (MRF). The following presents removal rate data for a set of six optical glasses that were spotted (not polished out) with four different MR fluids, as well as texturing/smoothing data for phosphate laser glass LHG-8.

  11. Gas Sampling At Glass Buttes Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Glass Buttes Area (DOE GTP) (Redirected from Water-Gas Samples At Glass Buttes Area (DOE GTP)) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home...

  12. Gas Sampling At Glass Buttes Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Gas Sampling At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Gas Sampling At Glass Buttes Area (DOE GTP)...

  13. FMI Log At Glass Buttes Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: FMI Log At Glass Buttes Area (DOE GTP) Exploration Activity Details...

  14. LiDAR At Glass Buttes Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: LiDAR At Glass Buttes Area (DOE GTP) Exploration Activity Details...

  15. Slim Holes At Glass Buttes Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Slim Holes At Glass Buttes Area (DOE GTP) Exploration Activity...

  16. Field Mapping At Glass Buttes Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Field Mapping At Glass Buttes Area (DOE GTP) Exploration Activity...

  17. Flow Test At Glass Buttes Area (DOE GTP) | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Flow Test At Glass Buttes Area (DOE GTP) Exploration Activity Details Location Glass Buttes Area...

  18. Ground Gravity Survey At Glass Buttes Area (DOE GTP) | Open Energy...

    Open Energy Info (EERE)

    Ground Gravity Survey At Glass Buttes Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Ground Gravity Survey At Glass Buttes Area...

  19. The Honorable Deborah L. Wince-Smith Discusses Breaking the Glass...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Honorable Deborah L. Wince-Smith Discusses Breaking the Glass Ceiling in Manufacturing The Honorable Deborah L. Wince-Smith Discusses Breaking the Glass Ceiling in ...

  20. Development of a glass polymer composite sewer pipe from waste glass. Final report

    SciTech Connect (OSTI)

    Rayfiel, R.; Kukacka, L.E.

    1980-02-01

    A range of polymer-aggregate composites for applications in industry which appear to be economically attractive and contribute to energy conservation were developed at BNL. Waste glass is the aggregate in one such material, which is called glass-polymer-composite (GPC). This report assays the economics and durability of GPC in piping for storm drains and sewers. The properties of the pipe are compared statistically with the requirements of industrial specifications. These establish the raw materials requirements. The capital and operating costs for producing pipe are then estimated. Using published sales values for competing materials, the return on investment is calculated for two cases. The ultimate energy requirement of the raw materials in GPC is compared with the corresponding requirement for vitrified clay pipe. The strengths of GPC, reinforced concrete, vitrified clay and asbestos cement pipe are compared after extended exposure to various media. The status of process and product development is reviewed and recommendations are made for future work.

  1. Fabrication of Emissible Metallic Layer-by-Layer Photonic Crystals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    polymer is coated on the first polymer. A substrate or a multi-layer polymer structure is placed on the filled mold and the resulting structure is exposed to UV light (i.e., is UV...

  2. D0 layer 0 innermost layer of silicon microstrip tracker

    SciTech Connect (OSTI)

    Hanagaki, K.; /Fermilab

    2006-01-01

    A new inner layer silicon strip detector has been built and will be installed in the existing silicon microstrip tracker in D0. They report on the motivation, design, and performance of this new detector.

  3. Precision diamond grinding of ceramics and glass

    SciTech Connect (OSTI)

    Smith, S.; Paul, H.; Scattergood, R.O.

    1988-12-01

    A new research initiative will be undertaken to investigate the effect of machine parameters and material properties on precision diamond grinding of ceramics and glass. The critical grinding depth to initiate the plastic flow-to-brittle fracture regime will be directly measured using plunge-grind tests. This information will be correlated with machine parameters such as wheel bonding and diamond grain size. Multiaxis grinding tests will then be made to provide data more closely coupled with production technology. One important aspect of the material property studies involves measuring fracture toughness at the very short crack sizes commensurate with grinding damage. Short crack toughness value`s can be much less than the long-crack toughness values measured in conventional fracture tests.

  4. Glass-ceramic composition for hermetic seals

    DOE Patents [OSTI]

    Ballard, Jr., Clifford P.

    1979-01-01

    The invention relates to a glass-ceramic composition having a high fracture strength adaptable for hermetically sealing to chromium bearing iron or nickel base alloys at temperatures of between about 950.degree. C to about 1100.degree. C to form a hermetically sealed insulator body, comprising from about 55 to about 65 weight percent SiO.sub.2, from about 0 to about 5 weight percent Al.sub.2 O.sub.3, from about 6 to about 11 weight % Li.sub.2 O, from about 25 to about 32 weight percent BaO, from about 0.5 to about 1.0 weight percent CoO and from about 1.5 to about 3.5 weight percent P.sub.2 O.sub.5.

  5. Thermally efficient melting for glass making

    DOE Patents [OSTI]

    Chen, Michael S. K.; Painter, Corning F.; Pastore, Steven P.; Roth, Gary; Winchester, David C.

    1991-01-01

    The present invention is an integrated process for the production of glass utilizing combustion heat to melt glassmaking materials in a glassmaking furnace. The fuel combusted to produce heat sufficient to melt the glassmaking materials is combusted with oxygen-enriched oxidant to reduce heat losses from the offgas of the glassmaking furnace. The process further reduces heat losses by quenching hot offgas from the glassmaking furnace with a process stream to retain the heat recovered from quench in the glassmaking process with subsequent additional heat recovery by heat exchange of the fuel to the glassmaking furnace, as well as the glassmaking materials, such as batch and cullet. The process includes recovery of a commercially pure carbon dioxide product by separatory means from the cooled, residual offgas from the glassmaking furnace.

  6. Phosphate glass useful in high energy lasers

    DOE Patents [OSTI]

    Hayden, Y.T.; Payne, S.A.; Hayden, J.S.; Campbell, J.H.; Aston, M.K.; Elder, M.L.

    1996-06-11

    In a high energy laser system utilizing phosphate laser glass components to amplify the laser beam, the laser system requires a generated laser beam having an emission bandwidth of less than 26 nm and the laser glass components consist essentially of (on an oxide composition basis) in mole percent: P{sub 2}O{sub 5}, 50--75; Al{sub 2}O{sub 3}, {gt}0--10; K{sub 2}O, {gt}0--30; MgO, 0--30; CaO, 0--30; Li{sub 2}O, 0--20; Na{sub 2}O, 0--20; Rb{sub 2}O, 0--20; Cs{sub 2}O, 0--20; BeO, 0--20; SrO, 0--20; BaO, 0--20; ZnO, 0--20; PbO, 0--20; B{sub 2}O{sub 3}, 0--10; Y{sub 2}O{sub 3}, 0--10; La{sub 2}O{sub 3}, 0--8; Ln{sub 2}O{sub 3}, 0.01--8; wherein the sum of MgO and CaO is >0--30; the sum of Li{sub 2}O, Na{sub 2}O, Rb{sub 2}O, and Cs{sub 2}O is 0--20; the sum of BeO, SrO, BaO, ZnO, and PbO is 0--20; the sum of B{sub 2}O{sub 3} and Y{sub 2}O{sub 3} is 0--10; and Ln{sub 2}O{sub 3} represents the sum of the oxides of active lasing lanthanides of atomic number 58--71. 21 figs.

  7. Phosphate glass useful in high energy lasers

    DOE Patents [OSTI]

    Hayden, Yuiko T.; Payne, Stephen A.; Hayden, Joseph S.; Campbell, John H.; Aston, Mary Kay; Elder, Melanie L.

    1996-01-01

    In a high energy laser system utilizing phosphate laser glass components to amplify the laser beam, the laser system requires a generated laser beam having an emission bandwidth of less than 26 nm and the laser glass components consist essentially of (on an oxide composition basis) in mole percent: P{sub 2}O{sub 5}, 50--75; Al{sub 2}O{sub 3}, {gt}0--10; K{sub 2}O, {gt}0--30; MgO, 0--30; CaO, 0--30; Li{sub 2}O, 0--20; Na{sub 2}O, 0--20; Rb{sub 2}O, 0--20; Cs{sub 2}O, 0--20; BeO, 0--20; SrO, 0--20; BaO, 0--20; ZnO, 0--20; PbO, 0--20; B{sub 2}O{sub 3}, 0--10; Y{sub 2}O{sub 3}, 0--10; La{sub 2}O{sub 3}, 0--8; Ln{sub 2}O{sub 3}, 0.01--8; wherein the sum of MgO and CaO is >0--30; the sum of Li{sub 2}O, Na{sub 2}O, Rb{sub 2}O, and Cs{sub 2}O is 0--20; the sum of BeO, SrO, BaO, ZnO, and PbO is 0--20; the sum of B{sub 2}O{sub 3} and Y{sub 2}O{sub 3} is 0--10; and Ln{sub 2}O{sub 3} represents the sum of the oxides of active lasing lanthanides of atomic number 58--71. 21 figs.

  8. Compliant alkali silicate sealing glass for solid oxide fuel cell applications: the effect of protective YSZ coating on electrical stability in dual environment

    SciTech Connect (OSTI)

    Chou, Y. S.; Thomsen, Edwin C.; Choi, Jung-Pyung; Stevenson, Jeffry W.

    2012-03-15

    Recently, compliant sealing glass has been proposed as a potential candidate sealant for solid oxide fuel cell (SOFC) applications. In a previous paper, the thermal stability and chemical compatibility were reported for a compliant alkali-containing silicate glass sealed between anode supported YSZ bi-layer and YSZ-coated stainless steel interconnect. In this paper, we will report the electrical stability of the compliant glass under a DC load and dual environment at 700-800 degrees C. Apparent electrical resistivity was measured with a 4-point method for the glass sealed between two plain SS441 metal coupons or YSZ-coated aluminized substrates. The results showed instability with plain SS441 at 800 degrees C, but stable behavior of increasing resistivity with time was observed with the YSZ coated SS441. In addition, results of interfacial microstructure analysis with scanning electron microscopy will be correlated with the measured resistivity results. Overall, the YSZ coating demonstrated chemically stability with the alkali-containing compliant silicate sealing glass under electrical field and dual environments.

  9. Boundary Layer Cloud Turbulence Characteristics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Boundary Layer Cloud Turbulence Characteristics Virendra Ghate Bruce Albrecht Parameter Observational Readiness (/10) Modeling Need (/10) Cloud Boundaries 9 9 Cloud Fraction Variance Skewness Up/Downdraft coverage Dominant Freq. signal Dissipation rate ??? Observation-Modeling Interface

  10. Low Velocity Sphere Impact of a Borosilicate Glass

    SciTech Connect (OSTI)

    Morrissey, Timothy G; Ferber, Mattison K; Wereszczak, Andrew A; Fox, Ethan E

    2012-05-01

    This report summarizes US Army TARDEC sponsored work at Oak Ridge National Laboratory (ORNL) involving low velocity (< 30 m/s or < 65 mph) ball impact testing of Borofloat borosilicate glass, and is a follow-up to a similar study completed by the authors on Starphire soda-lime silicate glass last year. The response of the borosilicate glass to impact testing at different angles was also studied. The Borofloat glass was supplied by the US Army Research Laboratory and its tin-side was impacted or indented. The intent was to better understand low velocity impact response in the Borofloat. Seven sphere materials were used whose densities bracket that of rock: borosilicate glass, soda-lime silicate glass, silicon nitride, aluminum oxide, zirconium oxide, carbon steel, and a chrome steel. A gas gun or a ball-drop test setup was used to produce controlled velocity delivery of the spheres against the glass tile targets. Minimum impact velocities to initiate fracture in the Borofloat were measured and interpreted in context to the kinetic energy of impact and the elastic property mismatch between the seven sphere-Borofloat-target combinations. The primary observations from this low velocity (< 30 m/s or < 65 mph) testing were: (1) BS glass responded similarly to soda-lime silicate glass when spherically indented but quite differently under sphere impact conditions; (2) Frictional effects contributed to fracture initiation in BS glass when it spherically indented. This effect was also observed with soda-lime silicate glass; (3) The force necessary to initiate fracture in BS glass under spherical impact decreases with increasing elastic modulus of the sphere material. This trend is opposite to what was observed with soda-lime silicate glass. Friction cannot explain this trend and the authors do not have a legitimate explanation for it yet; (4) The force necessary to initiate contact-induced fracture is higher under dynamic conditions than under quasi-static conditions. That

  11. Enabling Tool for Innovative Glass Applications - Final Report

    SciTech Connect (OSTI)

    James M. Gillis

    2005-11-16

    The use of abrasive waterjet (AWJ) cutting systems in the industrial sector has been limited to applications that are difficult to machine using conventional methods. A major factor for this limited use is the high cost of the garnet abrasive currently used. Initial studies indicated that glass can be processed to produce particles with the desired characteristics at a fraction of the existing price of garnet. Inexpensive abrasive waterjet cutting systems would allow a wider array of glass products to be produced while eliminating many existing design limitations. Availability of low-cost abrasive waterjet cutting media would open new markets for glass applications by making glass a more versatile material. A fundamental goal of this project was to scale up and refine the circuit that was established in the initial phase of this project, which using waste glass as a feed stream, could economically produce glass particles displaying high angularity, sharp edges and a low aspect ratio which would prove suitable for use in abrasive waterjet (AWJ) cutting systems. Using commercial scale equipment, demonstration runs were conducted at various manufacturers facilities to further establish that waste glass is a viable source for the production of an inexpensive AWJ media for use in cutting glass and a variety of other materials. The glass abrasive produced was used to demonstrate that processed waste glass could serve as a less costly alternative to garnet in many AWJ cutting applications. Studies indicated that glass can be processed to produce particles with the desired characteristics at less than 1% of the existing price of garnet. The waste stream resulting from the use of the glass abrasive in an AWJ system was in turn used as a source for inexpensive fillers in various polymers. The reduced energy requirements needed to produce glass abrasives and lower cost associated with the use of waste glass over garnet, as well as the environmental benefits associated with

  12. Soldering of Thin Film-Metallized Glass Substrates

    SciTech Connect (OSTI)

    Hosking, F.M.; Hernandez, C.L.; Glass, S.J.

    1999-03-31

    The ability to produce reliable electrical and structural interconnections between glass and metals by soldering was investigated. Soldering generally requires premetallization of the glass. As a solderable surface finish over soda-lime-silicate glass, two thin films coatings, Cr-Pd-Au and NiCr-Sn, were evaluated. Solder nettability and joint strengths were determined. Test samples were processed with Sn60-Pb40 solder alloy at a reflow temperature of 210 C. Glass-to-cold rolled steel single lap samples yielded an average shear strength of 12 MPa. Solder fill was good. Control of the Au thickness was critical in minimizing the formation of AuSn{sub 4} intermetallic in the joint, with a resulting joint shear strength of 15 MPa. Similar glass-to-glass specimens with the Cr-Pd-Au finish failed at 16.5 MPa. The NiCr-Sn thin film gave even higher shear strengths of 20-22.5 MPa, with failures primarily in the glass.

  13. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

    2003-10-07

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  14. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

    2004-11-02

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  15. Low melting high lithia glass compositions and methods

    DOE Patents [OSTI]

    Jantzen, Carol M.; Pickett, John B.; Cicero-Herman, Connie A.; Marra, James C.

    2000-01-01

    The invention relates to methods of vitrifying waste and for lowering the melting point of glass forming systems by including lithia formers in the glass forming composition in significant amounts, typically from about 0.16 wt % to about 11 wt %, based on the total glass forming oxides. The lithia is typically included as a replacement for alkali oxide glass formers that would normally be present in a particular glass forming system. Replacement can occur on a mole percent or weight percent basis, and typically results in a composition wherein lithia forms about 10 wt % to about 100 wt % of the alkali oxide glass formers present in the composition. The present invention also relates to the high lithia glass compositions formed by these methods. The invention is useful for stabilization of numerous types of waste materials, including aqueous waste streams, sludge solids, mixtures of aqueous supernate and sludge solids, combinations of spent filter aids from waste water treatment and waste sludges, supernate alone, incinerator ash, incinerator offgas blowdown, or combinations thereof, geological mine tailings and sludges, asbestos, inorganic filter media, cement waste forms in need of remediation, spent or partially spent ion exchange resins or zeolites, contaminated soils, lead paint, etc. The decrease in melting point achieved by the present invention desirably prevents volatilization of hazardous or radioactive species during vitrification.

  16. Intermetallic Layers in Soldered Joints

    Energy Science and Technology Software Center (OSTI)

    1998-12-10

    ILAG solves the one-dimensional partial differential equations describing the multiphase, multicomponent, solid-state diffusion-controlled growth of intermetallic layers in soldered joints. This software provides an analysis capability for materials researchers to examine intermetallic growth mechanisms in a wide variety of defense and commercial applications involving both traditional and advanced materials. ILAG calculates the interface positions of the layers, as well as the spatial distribution of constituent mass fractions, and outputs the results at user-prescribed simulation times.

  17. New Glass Vial Procedure | Stanford Synchrotron Radiation Lightsource

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Glass Vial Procedure In general, crimp vials are not intended for low temperature use. The rubber septa may become brittle at low temperatures, thus compromising the air-tight seal. If it becomes necessary to transport samples in crimp vials at low temperatures, the following guidelines must be followed: Crimp vials consist of 3 pieces: 1) a glass vial, 2) a rubber septum, and 3) an aluminum cap. The sample is introduced into the glass vial in an inert atmosphere glove box, the mouth of the

  18. Specific heat loading in Nd:glass lasers

    SciTech Connect (OSTI)

    Krupke, W.F.

    1985-08-07

    The specific thermal load parameter, chi, for xenon flashlamp-pumped Nd:glass gain media is written as a function of neodymium concentration, pump pulse duration, and energy extraction efficiency. The currently available data on radiative and nonradiative decay probabilities of several commercial Nd:glasses are used to calculate and graph specific thermal load parameter values. By factoring these results into performance scaling relationships for zig-zag and disk lasers, specific Nd:glasses can be selected for optimized laser performance.

  19. Tamper-indicating device having a glass body

    DOE Patents [OSTI]

    Johnston, Roger G.; Garcia, Anthony R. E.

    2003-04-29

    A tamper-indicating device is described. The device has a first glass body member and a second glass body member that are attached to each other through a hasp. The glass body members of the device can be tempered. The body members can be configured with hollow volumes into which powders, microparticles, liquids, gels, or combinations thereof are sealed. The choice, the amount, and the location of these materials can produce a visible, band pattern to provide each body member with a unique fingerprint identifier, which makes it extremely difficult to repair or replace once it is damaged in order to avoid tamper detection.

  20. Ductility and work hardening in nano-sized metallic glasses

    SciTech Connect (OSTI)

    Chen, D. Z.; Gu, X. W.; An, Q.; Goddard, W. A.; Greer, J. R.

    2015-02-09

    In-situ nano-tensile experiments on 70 nm-diameter free-standing electroplated NiP metallic glass nanostructures reveal tensile true strains of ∼18%, an amount comparable to compositionally identical 100 nm-diameter focused ion beam samples and ∼3 times greater than 100 nm-diameter electroplated samples. Simultaneous in-situ observations and stress-strain data during post-elastic deformation reveal necking and work hardening, features uncharacteristic for metallic glasses. The evolution of free volume within molecular dynamics-simulated samples suggests a free surface-mediated relaxation mechanism in nano-sized metallic glasses.

  1. Ceramic-glass-metal seal by microwave heating

    DOE Patents [OSTI]

    Meek, T.T.; Blake, R.D.

    1983-10-04

    A method for producing a ceramic-glass-metal seal by microwaving, mixes a slurry of glass sealing material and coupling agent and applies same to ceramic and metal workpieces. The slurry and workpieces are then insulated and microwaved at a power, time and frequency sufficient to cause a liquid-phase reaction in the slurry. The reaction of the glass sealing material forms a chemically different seal than that which would be formed by conventional heating because it is formed by diffusion rather than by wetting of the reactants.

  2. Ceramic-glass-ceramic seal by microwave heating

    DOE Patents [OSTI]

    Meek, T.T.; Blake, R.D.

    1983-10-04

    A method for producing a ceramic-glass-ceramic seal by microwaving, mixes a slurry of glass sealing material and coupling agent and applies same to ceramic workpieces. The slurry and workpieces are placed together, insulated and then microwaved at a power, time and frequency sufficient to cause a liquid phase reaction in the slurry. The reaction of the glass sealing material forms a chemically different seal than that which would be formed by conventional heating because it is formed by a diffusion rather than by wetting of the reactants.

  3. Process for direct conversion of reactive metals to glass

    DOE Patents [OSTI]

    Rajan, John B.; Kumar, Romesh; Vissers, Donald R.

    1990-01-01

    Radioactive alkali metal is introduced into a cyclone reactor in droplet form by an aspirating gas. In the cyclone metal reactor the aspirated alkali metal is contacted with silica powder introduced in an air stream to form in one step a glass. The sides of the cyclone reactor are preheated to ensure that the initial glass formed coats the side of the reactor forming a protective coating against the reactants which are maintained in excess of 1000.degree. C. to ensure the formation of glass in a single step.

  4. Solar films seen as cheaper alternative to reflective glass

    SciTech Connect (OSTI)

    Andrews, W.

    1982-06-28

    It costs only one-third as much to install solar film used with clear glass as it does to install reflective glass, and further savings will come in maintenance and replacement costs. Except for the Sunbelt, architects and builders are less enthusiastic about the solar films and reluctant to use them in quality construction because of their reputation for deteriorating. Manufacturers note that field-applied films are not as durable as factory-bonded reflective glass. Several users and architects report their experiences with solar-film performance. Two directories list 116 major manufacturers of doors and windows and 33 suppliers of window-treatment products. (DCK)

  5. Ultrafast pulsed laser utilizing broad bandwidth laser glass

    DOE Patents [OSTI]

    Payne, S.A.; Hayden, J.S.

    1997-09-02

    An ultrafast laser uses a Nd-doped phosphate laser glass characterized by a particularly broad emission bandwidth to generate the shortest possible output pulses. The laser glass is composed primarily of P{sub 2}O{sub 5}, Al{sub 2}O{sub 3} and MgO, and possesses physical and thermal properties that are compatible with standard melting and manufacturing methods. The broad bandwidth laser glass can be used in modelocked oscillators as well as in amplifier modules. 7 figs.

  6. Ultrafast pulsed laser utilizing broad bandwidth laser glass

    DOE Patents [OSTI]

    Payne, Stephen A.; Hayden, Joseph S.

    1997-01-01

    An ultrafast laser uses a Nd-doped phosphate laser glass characterized by a particularly broad emission bandwidth to generate the shortest possible output pulses. The laser glass is composed primarily of P.sub.2 O.sub.5, Al.sub.2 O.sub.3 and MgO, and possesses physical and thermal properties that are compatible with standard melting and manufacturing methods. The broad bandwidth laser glass can be used in modelocked oscillators as well as in amplifier modules.

  7. Reference commercial high-level waste glass and canister definition.

    SciTech Connect (OSTI)

    Slate, S.C.; Ross, W.A.; Partain, W.L.

    1981-09-01

    This report presents technical data and performance characteristics of a high-level waste glass and canister intended for use in the design of a complete waste encapsulation package suitable for disposal in a geologic repository. The borosilicate glass contained in the stainless steel canister represents the probable type of high-level waste product that will be produced in a commercial nuclear-fuel reprocessing plant. Development history is summarized for high-level liquid waste compositions, waste glass composition and characteristics, and canister design. The decay histories of the fission products and actinides (plus daughters) calculated by the ORIGEN-II code are presented.

  8. Ceramic-glass-metal seal by microwave heating

    DOE Patents [OSTI]

    Meek, Thomas T.; Blake, Rodger D.

    1985-01-01

    A method for producing a ceramic-glass-metal seal by microwaving mixes a slurry of glass sealing material and coupling agent and applies same to ceramic and metal workpieces. The slurry and workpieces are then insulated and microwaved at a power, time and frequency sufficient to cause a liquid phase reaction in the slurry. The reaction of the glass sealing material forms a chemically different seal than that which would be formed by conventional heating because it is formed by diffusion rather than by wetting of the reactants.

  9. Ceramic-glass-ceramic seal by microwave heating

    DOE Patents [OSTI]

    Meek, Thomas T.; Blake, Rodger D.

    1985-01-01

    A method for producing a ceramic-glass-ceramic seal by microwaving, mixes a slurry of glass sealing material and coupling agent and applies same to ceramic workpieces. The slurry and workpieces are placed together, insulated and then microwaved at a power, time and frequency sufficient to cause a liquid phase reaction in the slurry. The reaction of the glass sealing material forms a chemically different seal than that which would be formed by conventional heating because it is formed by a diffusion rather than by wetting of the reactants.

  10. Ferrule and use thereof for cooling a melt spun hollow glass fiber as it emerges from a spinnerette

    DOE Patents [OSTI]

    Brown, William E.

    1977-01-01

    An improvement in the process of melt spinning thin walled, hollow fibers from relatively low melting glasses results if cooling of the emerging fiber is accomplished by use of a thin layer of gas to transfer heat from the fiber to a ferrule which fits closely to the spinnerette face and the individual fiber. The ferrule incorporates or is in contact with a heat sink and is slotted or segmented so that it may be brought into position around the moving fiber. Thinner walled, more uniform fibers may be spun when this method of cooling is employed.

  11. Application of Argonne's Glass Furnace Model to longhorn glass corporation oxy-fuel furnace for the production of amber glass.

    SciTech Connect (OSTI)

    Golchert, B.; Shell, J.; Jones, S.; Energy Systems; Shell Glass Consulting; Anheuser-Busch Packaging Group

    2006-09-06

    The objective of this project is to apply the Argonne National Laboratory's Glass Furnace Model (GFM) to the Longhorn oxy-fuel furnace to improve energy efficiency and to investigate the transport of gases released from the batch/melt into the exhaust. The model will make preliminary estimates of the local concentrations of water, carbon dioxide, elemental oxygen, and other subspecies in the entire combustion space as well as the concentration of these species in the furnace exhaust gas. This information, along with the computed temperature distribution in the combustion space may give indications on possible locations of crown corrosion. An investigation into the optimization of the furnace will be performed by varying several key parameters such as the burner firing pattern, exhaust number/size, and the boost usage (amount and distribution). Results from these parametric studies will be analyzed to determine more efficient methods of operating the furnace that reduce crown corrosion. Finally, computed results from the GFM will be qualitatively correlated to measured values, thus augmenting the validation of the GFM.

  12. Hybrid window layer for photovoltaic cells

    DOE Patents [OSTI]

    Deng, Xunming

    2010-02-23

    A novel photovoltaic solar cell and method of making the same are disclosed. The solar cell includes: at least one absorber layer which could either be a lightly doped layer or an undoped layer, and at least a doped window-layers which comprise at least two sub-window-layers. The first sub-window-layer, which is next to the absorber-layer, is deposited to form desirable junction with the absorber-layer. The second sub-window-layer, which is next to the first sub-window-layer, but not in direct contact with the absorber-layer, is deposited in order to have transmission higher than the first-sub-window-layer.

  13. Hybrid window layer for photovoltaic cells

    DOE Patents [OSTI]

    Deng, Xunming; Liao, Xianbo; Du, Wenhui

    2011-10-04

    A novel photovoltaic solar cell and method of making the same are disclosed. The solar cell includes: at least one absorber layer which could either be a lightly doped layer or an undoped layer, and at least a doped window-layers which comprise at least two sub-window-layers. The first sub-window-layer, which is next to the absorber-layer, is deposited to form desirable junction with the absorber-layer. The second sub-window-layer, which is next to the first sub-window-layer, but not in direct contact with the absorber-layer, is deposited in order to have transmission higher than the first-sub-window-layer.

  14. Hybrid window layer for photovoltaic cells

    DOE Patents [OSTI]

    Deng, Xunming; Liao, Xianbo; Du, Wenhui

    2011-02-01

    A novel photovoltaic solar cell and method of making the same are disclosed. The solar cell includes: at least one absorber layer which could either be a lightly doped layer or an undoped layer, and at least a doped window-layers which comprise at least two sub-window-layers. The first sub-window-layer, which is next to the absorber-layer, is deposited to form desirable junction with the absorber-layer. The second sub-window-layer, which is next to the first sub-window-layer, but not in direct contact with the absorber-layer, is deposited in order to have transmission higher than the first-sub-window-layer.

  15. Reentrant spin-glass state in a geometrical frustrated multiferroic system: Role of disorder

    SciTech Connect (OSTI)

    Chattopadhyay, S.; Giri, S.; Majumdar, S.; Ganesan, V.; Venkateshwarlu, D.

    2014-05-07

    We investigated the effect of magnetic (Mn) and nonmagnetic (Ga) doping at the Cr site of the layered geometrically frustrated antiferromagnetic compound LiCrO{sub 2}. 10% Ga doping at the Cr site does not invoke any metastability typical of a glassy magnetic state. However, similar amount of Mn doping drives the system to a spin glass (SG) state which is particularly evident from the magnetic memory and heat capacity studies. The onset of glassy state in 10% Mn doped sample is of reentrant type developing out of higher temperature antiferromagnetic state. The SG state in the Mn-doped sample shows a true reentry with the complete disappearance of the antiferromagnetic phase below the SG transition. The lack of SG state on Ga doping indicates the importance of random ferromagnetic/antiferromagnetic bonds for the glassy ground state in LiCrO{sub 2}.

  16. Thin film GaAs solar cells on glass substrates by epitaxial liftoff

    SciTech Connect (OSTI)

    Lee, X.Y.; Goertemiller, M.; Boroditsky, M.; Ragan, R.; Yablonovitch, E.

    1997-02-01

    In this work, we describe the fabrication and operating characteristics of GaAs/AlGaAs thin film solar cells processed by the epitaxial liftoff (ELO) technique. This technique allows the transfer of these cells onto glass substrates. The performance of the lifted-off solar cell is demonstrated by means of electrical measurements under both dark and illuminated conditions. We have also optimized the light trapping conditions in this direct-gap material. The results show that good solar absorption is possible in active layers as thin as 0.32 {mu}m. In such a thin solar cell, the open circuit voltage would be enhanced. We believe that the combination of an epitaxial liftoff thin GaAs film, and nano-texturing can lead to record breaking performance. {copyright} {ital 1997 American Institute of Physics.}

  17. Glass Buttes Exploration and Drilling: 2010 Geothermal Technologies Program Peer Review Presentation, Walsh, et al, Ormat

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Zemach, Ezra

    Glass Buttes Exploration and Drilling: 2010 Geothermal Technologies Program Peer Review Presentation, Walsh, et al, Ormat

  18. Alkaline resistant phosphate glasses and method of preparation and use thereof

    DOE Patents [OSTI]

    Brow, Richard K.; Reis, Signo T.; Velez, Mariano; Day, Delbert E.

    2010-01-26

    A substantially alkaline resistant calcium-iron-phosphate (CFP) glass and methods of making and using thereof. In one application, the CFP glass is drawn into a fiber and dispersed in cement to produce glass fiber reinforced concrete (GFRC) articles having the high compressive strength of concrete with the high impact, flexural and tensile strength associated with glass fibers.

  19. Material Removal Rate for Magnetorheological Finishing (MRF) of Optical Glasses with Nanodiamond MR Fluid

    SciTech Connect (OSTI)

    DeGroote, J.E.; Marino, A.E.; Wilson, J.P.; Bishop, A.L.; Jacobs, S.D.

    2007-07-13

    We present a material removal rate model for MRF of optical glasses using nanodiamond MR fluid. The new model incorporates terms for drag force, polishing particle properties, chemical durability and glass composition into an existing model that contains only terms for the glass mechanical properties. Experimental results for six optical glasses are given that support this model.

  20. Durability of Polymeric Encapsulation Materials in a PMMA/glass Concentrator Photovoltaic System

    SciTech Connect (OSTI)

    Miller, David; Kempe, Michael; Muller, Matthew; Gray, Matthew; Araki, Kenji; Kurtz, Sarah

    2014-04-08

    Durability of Polymeric Polymeric Encapsulation Encapsulation Materials for a PMMA/glass Concentrator Photovoltaic System

  1. Preparation of Bi-Sr-Ca-Cu-O superconductors from oxide-glass precursors

    DOE Patents [OSTI]

    Hinks, David G.; Capone, II, Donald W.

    1992-01-01

    A superconductor and precursor therefor from oxide mixtures of Ca, Sr, Bi and Cu. Glass precursors quenched to elevated temperatures result in glass free of crystalline precipitates having enhanced mechanical properties. Superconductors are formed from the glass precursors by heating in the presence of oxygen to a temperature below the melting point of the glass.

  2. Glass Buttes Exploration and Drilling: 2010 Geothermal Technologies Program Peer Review Presentation, Walsh, et al, Ormat

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Zemach, Ezra

    2010-01-01

    Glass Buttes Exploration and Drilling: 2010 Geothermal Technologies Program Peer Review Presentation, Walsh, et al, Ormat

  3. Glasses having a low non-linear refractive index for laser applications

    DOE Patents [OSTI]

    Faulstich, Marga; Jahn, Walter; Krolla, Georg; Neuroth, Norbert

    1980-01-01

    Glass composition ranges are described which permit the introduction of laser activators into fluorphosphate glass with exceptionally high fluorine content while forming glasses of high crystallization stability and permitting the realization of large melt volumes. The high fluorine content imparts to the glasses an exceptionally low nonlinear refractive index n.sub.2 down to O,4 .times.10.sup.-13 esu.

  4. Research Needs: Glass Solar Reflectance and Vinyl Siding

    SciTech Connect (OSTI)

    Hart, Robert; Curcija, Charlie; Arasteh, Dariush; Goudey, Howdy; Kohler, Christian; Selkowitz, Stephen

    2011-07-07

    The subject of glass solar reflectance and its contribution to permanent vinyl siding distortion has not been extensively studied, and some phenomena are not yet well understood. This white paper presents what is known regarding the issue and identifies where more research is needed. Three primary topics are discussed: environmental factors that control the transfer of heat to and from the siding surface; vinyl siding properties that may affect heat build-up and permanent distortion; and factors that determine the properties of reflected solar radiation from glass surfaces, including insulating window glass. Further research is needed to fully characterize the conditions associated with siding distortion, the scope of the problem, physical properties of vinyl siding, insulating window glass reflection characteristics, and possible mitigation or prevention strategies.

  5. Low-temperature mechanical properties of glass/epoxy laminates

    SciTech Connect (OSTI)

    Reed, R. P. [Cryogenic Materials, Inc., Boulder, CO 80305 (United States); Madhukar, M.; Thaicharoenporn, B. [Magnet Development Laboratory, Knoxville, TN 37996 (United States); Martovetsky, N. N. [US-ITER Project, Oak Ridge National Laboratory, Oak Ridge, TN 37830 (United States)

    2014-01-27

    Selected mechanical properties of glass/epoxy laminate candidates for use in the electrical turn and ground insulation of the ITER Central solenoid (CS) modules were measured. Short-beam shear and flexural tests have been conducted on various E-glass cloth weaves/epoxy laminates at 295 and 77 K. Types of glass weave include 1581, 7500, 7781, and 38050, which represent both satin and plain weaves. The epoxy, planned for use for vacuum-pressure impregnation of the CS module, consists of an anhydride-cured bisphenol F resin system. Inter-laminar shear strength, flexural elastic modulus, and flexural strength have been measured. The data indicate that these properties are dependent on the volume percent of glass. Short-beam shear strength was measured as a function of the span-to-thickness ratio for all laminates at 77 K. Comprehensive fractography was conducted to obtain the failure mode of each short-beam shear test sample.

  6. GAMMA RADIATION DOSAGE-MEASURING GLASSES AND METHOD OF USING

    DOE Patents [OSTI]

    Bishay, A.M.

    1963-05-14

    A dosimeter glass for gamma radiation characterized by a borate base, a substantial amount of bismuth trioxide and a minor amount of either arsenic or antimony trioxides is presented. (AEC)

  7. Hollow porous-wall glass microspheres for hydrogen storage

    DOE Patents [OSTI]

    Heung, Leung K.; Schumacher, Ray F.; Wicks, George G.

    2010-02-23

    A porous wall hollow glass microsphere is provided having a diameter range of between 1 to 200 microns, a density of between 1.0 to 2.0 gm/cc, a porous-wall structure having wall openings defining an average pore size of between 10 to 1000 angstroms, and which contains therein a hydrogen storage material. The porous-wall structure facilitates the introduction of a hydrogen storage material into the interior of the porous wall hollow glass microsphere. In this manner, the resulting hollow glass microsphere can provide a membrane for the selective transport of hydrogen through the porous walls of the microsphere, the small pore size preventing gaseous or liquid contaminants from entering the interior of the hollow glass microsphere.

  8. ITP Glass: A Clear Vision for a Bright Future

    Broader source: Energy.gov [DOE]

    This document presents perspectives on the glass industry's past, present and future, with special attention to competitive challenges now facing the industry and technological responses that will reinforce its continuing contribution...

  9. Composite polymer: Glass edge cladding for laser disks

    DOE Patents [OSTI]

    Powell, H.T.; Wolfe, C.A.; Campbell, J.H.; Murray, J.E.; Riley, M.O.; Lyon, R.E.; Jessop, E.S.

    1987-11-02

    Large neodymium glass laser disks for disk amplifiers such as those used in the Nova laser require an edge cladding which absorbs at 1 micrometer. This cladding prevents edge reflections from causing parasitic oscillations which would otherwise deplete the gain. Nova now utilizes volume-absorbing monolithic-glass claddings which are fused at high temperature to the disks. These perform quite well but are expensive to produce. Absorbing glass strips are adhesively bonded to the edges of polygonal disks using a bonding agent whose index of refraction matches that of both the laser and absorbing glass. Optical finishing occurs after the strips are attached. Laser disks constructed with such claddings have shown identical gain performance to the previous Nova disks and have been tested for hundreds of shots without significant degradation. 18 figs.

  10. Structure of RheniumContaining Sodium Borosilicate Glass

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    not problem- atic in evaporation and drying processes but does creates trouble in high temperature molten glass pro- cessing from either liquid or dried feed. 2 Other sources of 99...

  11. Iron speciation in minerals and glasses probed by M [subscript...

    Office of Scientific and Technical Information (OSTI)

    Title: Iron speciation in minerals and glasses probed by M subscript 23 -edge X-ray Raman scattering spectroscopy Authors: Nyrow, A. ; Sternemann, C. ; Wilke, M. ; Gordon, R. A. ...

  12. Low energy detectors: 6Li-glass scintillators (Conference) |...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Low energy detectors: 6Li-glass scintillators Authors: Lee, Hye Young 1 ; Taddeucci, Terry N 1 + Show Author Affiliations Los Alamos ...

  13. Composite polymer-glass edge cladding for laser disks

    DOE Patents [OSTI]

    Powell, Howard T.; Riley, Michael O.; Wolfe, Charles R.; Lyon, Richard E.; Campbell, John H.; Jessop, Edward S.; Murray, James E.

    1989-01-01

    Large neodymium glass laser disks for disk amplifiers such as those used in the Nova laser require an edge cladding which absorbs at 1 micrometer. This cladding prevents edge reflections from causing parasitic oscillations which would otherwise deplete the gain. Nova now utilizes volume-absorbing monolithic-glass claddings which are fused at high temperature to the disks. These perform quite well but are expensive to produce. Absorbing glass strips are adhesively bonded to the edges of polygonal disks using a bonding agent whose index of refraction matches that of both the laser and absorbing glass. Optical finishing occurs after the strips are attached. Laser disks constructed with such claddings have shown identical gain performance to the previous Nova disks and have been tested for hundreds of shots without significant degradation.

  14. Ancient Glass in Swedish Hillforts May Shed Light on Immobilizing...

    Office of Environmental Management (EM)

    the results of accelerated aging tests on various types of low-activity waste (LAW) glass. ... accelerated aging tests of ORP's vitrified LAW. This project is funded by EM's ...

  15. RETENTION OF SULFATE IN HIGH LEVEL RADIOACTIVE WASTE GLASS

    SciTech Connect (OSTI)

    Fox, K.

    2010-09-07

    High level radioactive wastes are being vitrified at the Savannah River Site for long term disposal. Many of the wastes contain sulfate at concentrations that can be difficult to retain in borosilicate glass. This study involves efforts to optimize the composition of a glass frit for combination with the waste to improve sulfate retention while meeting other process and product performance constraints. The fabrication and characterization of several series of simulated waste glasses are described. The experiments are detailed chronologically, to provide insight into part of the engineering studies used in developing frit compositions for an operating high level waste vitrification facility. The results lead to the recommendation of a specific frit composition and a concentration limit for sulfate in the glass for the next batch of sludge to be processed at Savannah River.

  16. Energy-Efficient Glass Melting - Next Generation Melter

    SciTech Connect (OSTI)

    2006-08-01

    This factsheet describes an R&D project focused on an oxy-gas-fired submerged combustion melter for glass industry that offers decreased operating and capital costs, decreased energy use, simple design, and high reliability.

  17. THERMAL ANALYSIS OF WASTE GLASS MELTER FEEDS

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR; POKORNY R; PIERCE DA

    2011-10-21

    Melter feeds for high-level nuclear waste (HLW) typically contain a large number of constituents that evolve gas on heating, Multiple gas-evolving reactions are both successive and simultaneous, and include the release of chemically bonded water, reactions of nitrates with organics, and reactions of molten salts with solid silica. Consequently, when a sample of a HLW feed is subjected to thermogravimetric analysis (TGA), the rate of change of the sample mass reveals multiple overlapping peaks. In this study, a melter feed, formulated for a simulated high-alumina HLW to be vitrified in the Waste Treatment and Immobilization Plant, currently under construction at the Hanford Site in Washington State, USA, was subjected to TGA. In addition, a modified melter feed was prepared as an all-nitrate version of the baseline feed to test the effect of sucrose addition on the gas-evolving reactions. Activation energies for major reactions were determined using the Kissinger method. The ultimate aim of TGA studies is to obtain a kinetic model of the gas-evolving reactions for use in mathematical modeling of the cold cap as an element of the overall model of the waste-glass melter. In this study, we focused on computing the kinetic parameters of individual reactions without identifying their actual chemistry, The rough provisional model presented is based on the first-order kinetics.

  18. Lithium Loaded Glass Fiber Neutron Detector Tests

    SciTech Connect (OSTI)

    Ely, James H.; Erikson, Luke E.; Kouzes, Richard T.; Lintereur, Azaree T.; Stromswold, David C.

    2009-11-12

    Radiation portal monitors used for interdiction of illicit materials at borders include highly sensitive neutron detection systems. The main reason for having neutron detection capability is to detect fission neutrons from plutonium. The currently deployed radiation portal monitors (RPMs) from Ludlum and Science Applications International Corporation (SAIC) use neutron detectors based upon 3He-filled gas proportional counters, which are the most common large neutron detector. There is a declining supply of 3He in the world and, thus, methods to reduce the use of this gas in RPMs with minimal changes to the current system designs and sensitivity to cargo-borne neutrons are being investigated. Four technologies have been identified as being currently commercially available, potential alternative neutron detectors to replace the use of 3He in RPMs. Reported here are the results of tests of the lithium-loaded glass fibers option. This testing measured the neutron detection efficiency and gamma ray rejection capabilities of a small system manufactured by Nucsafe (Oak Ridge, TN).

  19. Phosphate glass useful in high energy lasers

    DOE Patents [OSTI]

    Hayden, Yuiko T.; Guesto-Barnak, Donna

    1992-01-01

    A low-or no-silica, low- or no-alkali phosphate glass useful as a laser amplifier in a multiple pass, high energy laser system having a high thermal conductivity, K.sub.90.degree. C. >0.85 W/mK, a low coefficient of thermal expansion, .alpha..sub.20.degree.-300.degree. C. <80.times.10.sup.-7 /.degree.C., low emission cross section, .sigma.<2.5.times.10.sup.-20 cm.sup.2, and a high fluorescence lifetime, .tau.>325 .mu.secs at 3 wt. % Nd doping, consisting essentially of (on an oxide composition basis): wherein Ln.sub.2 O.sub.3 is the sum of lanthanide oxides; .SIGMA.R.sub.2 O is <5, R being Li, Na, K, Cs, and Rb; the sum of Al.sub.2 O.sub.3 and MgO is <24 unless .SIGMA.R.sub.2 O is 0, then the sum of Al.sub.2 O.sub.3 and MgO is <42; and the ratio of MgO to B.sub.2 O.sub.3 is 0.48-4.20.

  20. Open-cell glass crystalline porous material

    DOE Patents [OSTI]

    Anshits, Alexander G.; Sharonova, Olga M.; Vereshchagina, Tatiana A.; Zykova, Irina D.; Revenko, Yurii A.; Tretyakov, Alexander A.; Aloy, Albert S.; Lubtsev, Rem I.; Knecht, Dieter A.; Tranter, Troy J.; Macheret, Yevgeny

    2003-12-23

    An open-cell glass crystalline porous material made from hollow microspheres which are cenospheres obtained from fly ash, having an open-cell porosity of up to 90 vol. % is produced. The cenospheres are separated into fractions based on one or more of grain size, density, magnetic or non-magnetic, and perforated or non-perforated. Selected fractions are molded and agglomerated by sintering with a binder at a temperature below the softening temperature, or without a binder at a temperature about, or above, the softening temperature but below the temperature of liquidity. The porous material produced has an apparent density of 0.3-0.6 g/cm.sup.3, a compressive strength in the range of 1.2-3.5 MPa, and two types of openings: through-flow wall pores in the cenospheres of 0.1-30 micrometers, and interglobular voids between the cenospheres of 20-100 micrometers. The porous material of the invention has properties useful as porous matrices for immobilization of liquid radioactive waste, heat-resistant traps and filters, supports for catalysts, adsorbents and ion-exchangers.

  1. Open-cell glass crystalline porous material

    DOE Patents [OSTI]

    Anshits, Alexander G.; Sharonova, Olga M.; Vereshchagina, Tatiana A.; Zykova, Irina D.; Revenko, Yurii A.; Tretyakov, Alexander A.; Aloy, Albert S.; Lubtsev, Rem I.; Knecht, Dieter A.; Tranter, Troy J.; Macheret, Yevgeny

    2002-01-01

    An open-cell glass crystalline porous material made from hollow microspheres which are cenospheres obtained from fly ash, having an open-cell porosity of up to 90 vol. % is produced. The cenospheres are separated into fractions based on one or more of grain size, density, magnetic or non-magnetic, and perforated or non-perforated. Selected fractions are molded and agglomerated by sintering with a binder at a temperature below the softening temperature, or without a binder at a temperature about, or above, the softening temperature but below the temperature of liquidity. The porous material produced has an apparent density of 0.3-0.6 g/cm.sup.3, a compressive strength in the range of 1.2-3.5 MPa, and two types of openings: through-flow wall pores in the cenospheres of 0.1-30 micrometers, and interglobular voids between the cenospheres of 20-100 micrometers. The porous material of the invention has properties useful as porous matrices for immobilization of liquid radioactive waste, heat-resistant traps and filters, supports for catalysts, adsorbents and ion-exchangers.

  2. Final Report. Baseline LAW Glass Formulation Testing, VSL-03R3460-1, Rev. 0

    SciTech Connect (OSTI)

    Muller, Isabelle S.; Pegg, Ian L.; Gan, Hao; Buechele, Andrew; Rielley, Elizabeth; Bazemore, Gina; Cecil, Richard; Hight, Kenneth; Mooers, Cavin; Lai, Shan-Tao T.; Kruger, Albert A.

    2015-06-18

    The major objective of the baseline glass formulation work was to develop and select glass formulations that are compliant with contractual and processing requirements for each of the LAW waste streams. Other objectives of the work included preparation and characterization of glasses with respect to the properties of interest, optimization of sulfate loading in the glasses, evaluation of ability to achieve waste loading limits, testing to demonstrate compatibility of glass melts with melter materials of construction, development of glass formulations to support ILAW qualification activities, and identification of glass formulation issues with respect to contract specifications and processing requirements.

  3. Glass Capacitor for High-Temperature Applications - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Energy Storage Energy Storage Find More Like This Return to Search Glass Capacitor for High-Temperature Applications Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryTo meet the demand for smaller, lighter capacitors that have high energy densities, an ORNL researcher developed a capacitor made of glass rods that is constructed like insulated wire. This device can be used for power factor correction, high-voltage capacitors, power electronic

  4. Metallic glass composition. [That does not embrittle upon annealing

    DOE Patents [OSTI]

    Kroeger, D.M.; Koch, C.C.

    1984-09-14

    This patent pertains to a metallic glass alloy that is either iron-based or nickel-based or based on a mixture of iron and nickel, containing lesser amounts of elements selected from the group boron, silicon, carbon and phosphorous to which is added an amount of a ductility-enhancing element selected from the group cerium, lanthanum, praseodymium and neodymium sufficient to increase ductility of the metallic glass upon annealing.

  5. Defect Migration and Recombination in Nanoindentation of Silica Glass |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Defect Migration and Recombination in Nanoindentation of Silica Glass Authors: Nomura, K., Chen, Y., Kalia, R.K., Nakano, A., Vashishta, P. Deformation, plasticity, and flow in silica-based glasses have been studied for decades, and yet important questions remain about the atomistic mechanisms underlying these processes. Our molecular dynamics simulations of nanoindentation indicate that these mechanical processes have a unified underlying atomistic

  6. Innovative Exploration Technologies Maui Hawaii & Glass Buttes, Oregon

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Innovative Exploration Technologies Maui Hawaii & Glass Buttes, Oregon Kyle Snyder Ezra Zemach Ormat Nevada Inc. Project Officer: Ava Coy Total Project Funding: Maui-$4.9M, GB- $4.4M April 23rd, 2013 This presentation does not contain any proprietary confidential, or otherwise restricted information. Ulupalakua, Maui Glass Buttes, Oregon 2 | US DOE Geothermal Program eere.energy.gov Maui Overview * Timeline * Project start date 10/29/2009 * Project end date Q3 2013 * Well sites permitting:

  7. Phosphate glasses for radioactive, hazardous and mixed waste immobilization

    DOE Patents [OSTI]

    Cao, H.; Adams, J.W.; Kalb, P.D.

    1998-11-24

    Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900 C include mixtures from about 1--6 mole % iron (III) oxide, from about 1--6 mole % aluminum oxide, from about 15--20 mole % sodium oxide or potassium oxide, and from about 30--60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400 C to about 450 C and which includes from about 3--6 mole % sodium oxide, from about 20--50 mole % tin oxide, from about 30--70 mole % phosphate, from about 3--6 mole % aluminum oxide, from about 3--8 mole % silicon oxide, from about 0.5--2 mole % iron (III) oxide and from about 3--6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided. 8 figs.

  8. Phosphate glasses for radioactive, hazardous and mixed waste immobilization

    DOE Patents [OSTI]

    Cao, Hui; Adams, Jay W.; Kalb, Paul D.

    1998-11-24

    Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole % iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.5 mole % to about 2 mole % iron (III) oxide and from about 3 mole % to about 6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided.

  9. Phosphate glasses for radioactive, hazardous and mixed waste immobilization

    DOE Patents [OSTI]

    Cao, H.; Adams, J.W.; Kalb, P.D.

    1999-03-09

    Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900 C include mixtures from about 1 mole % to about 6 mole % iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400 C to about 450 C and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.5 mole % to about 2 mole % iron (III) oxide and from about 3 mole % to about 6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided. 8 figs.

  10. Phosphate glasses for radioactive, hazardous and mixed waste immobilization

    DOE Patents [OSTI]

    Cao, Hui; Adams, Jay W.; Kalb, Paul D.

    1999-03-09

    Lead-free phosphate glass compositions are provided which can be used to immobilize low level and/or high level radioactive wastes in monolithic waste forms. The glass composition may also be used without waste contained therein. Lead-free phosphate glass compositions prepared at about 900.degree. C. include mixtures from about 1 mole % to about 6 mole %.iron (III) oxide, from about 1 mole % to about 6 mole % aluminum oxide, from about 15 mole % to about 20 mole % sodium oxide or potassium oxide, and from about 30 mole % to about 60 mole % phosphate. The invention also provides phosphate, lead-free glass ceramic glass compositions which are prepared from about 400.degree. C. to about 450.degree. C. and which includes from about 3 mole % to about 6 mole % sodium oxide, from about 20 mole % to about 50 mole % tin oxide, from about 30 mole % to about 70 mole % phosphate, from about 3 mole % to about 6 mole % aluminum oxide, from about 3 mole % to about 8 mole % silicon oxide, from about 0.5 mole % to about 2 mole % iron (III) oxide and from about 3 mole % to about 6 mole % potassium oxide. Method of making lead-free phosphate glasses are also provided.

  11. Development of a process control sensor for the glass industry

    SciTech Connect (OSTI)

    Gardner, M.; Candee, A.; Kramlich, J.; Koppang, R.

    1991-05-01

    This project was initiated to fill a need in the glass industry for a non-contact temperature sensor for glass melts. At present, the glass forming industry (e.g., bottle manufacture) consumes significant amounts of energy. Careful control of temperature at the point the bottle is molded is necessary to prevent the bottle from being rejected as out-of-specification. In general, the entire glass melting and conditioning process is designed to minimize this rejection rate, maximize throughput and thus control energy and production costs. This program focuses on the design, development and testing of an advanced optically based pyrometer for glass melts. The pyrometer operates simultaneously at four wavelengths; through analytical treatment of the signals, internal temperature profiles within the glass melt can be resolved. A novel multiplexer alloys optical signals from a large number of fiber-optic sensors to be collected and resolved by a single detector at a location remote from the process. This results in a significant cost savings on a per measurement point basis. The development program is divided into two phases. Phase 1 involves the construction of a breadboard version on the instrument and its testing on a pilot-scale furnace. In Phase 2, a prototype analyzer will be constructed and tested on a commercial forehearth. This report covers the Phase 1 activities.

  12. Archeological Applications of XAFS: Prehistorical Paintings And Medieval Glasses

    SciTech Connect (OSTI)

    Farges, F.; Chalmin, E.; Vignaud, C.; Pallot-Frossard, I.; Susini, J.; Bargar, J.; Brown, G.E., Jr.; Menu, M.; /SLAC, SSRL

    2006-10-27

    High-resolution manganese and iron K-edges XANES spectra were collected on several samples of archeological interest: prehistorical paintings and medieval glasses. XANES spectra were collected at the ID21 facility (ESRF, Grenoble, France) using a micro-beam device and at the 11-2 beamline (SSRL, Stanford, USA) using a submillimetric beam. The medieval glasses studied are from gothic glass windows from Normandy (XIVth century). The aim of this study is to help understand the chemical durability of these materials, exposed to weathering since the XIVth century. They are used as analogues of weathered glasses used to dump metallic wastes. These glasses show surficial enrichment in manganese, due to its oxidation from II (glass) to III/IV (surface), which precipitates as amorphous oxy-hydroxides. Similarly, iron is oxidized on the surface and forms ferrihydrite-type aggregates. The prehistorical paintings are from Lascaux and Ekain (Basque country). We choose in that study the black ones, rich in manganese to search for potential evidences of some 'savoir-faire' that the Paleolithic men could have used to realize their paint in rock art, as shown earlier for Fe-bearing pigments. A large number of highly valuable samples, micrometric scaled, were extracted from these frescoes and show large variation in the mineralogical nature of the black pigments used, from an amorphous psilomelane-type to a well-crystallized pyrolusite. Correlation with the crystals morphology helps understanding the know-how of these early artists.

  13. Letter report on PCT/Monolith glass ceramic corrosion tests

    SciTech Connect (OSTI)

    Crawford, Charles L.

    2015-09-24

    The Savannah River National Laboratory (SRNL) is collaborating with personnel from Pacific Northwest National Laboratory (PNNL) to study advanced waste form glass ceramics for immobilization of waste from Used Nuclear Fuel (UNF) separations processes. The glass ceramic waste forms take advantage of both crystalline and glassy phases where troublesome elements (e.g., low solubility in glass or very long-lived) partition to highly durable ceramic phases with the remainder of elements residing in the glassy phase. The ceramic phases are tailored to create certain minerals or unique crystalline structures that can host the radionuclides by binding them in their specific crystalline network while not adversely impacting the residual glass network (Crum et al., 2011). Glass ceramics have been demonstrated using a scaled melter test performed in a pilot scale (1/4 scale) cold crucible induction melter (CCIM) (Crum et al., 2014; Maio et al., 2015). This report summarizes recent results from both Phase I and Phase II bench scale tests involving crucible fabrication and corrosion testing of glass ceramics using the Product Consistency Test (PCT). Preliminary results from both Phase I and Phase II bench scale tests involving statistically designed matrices have previously been reported (Crawford, 2013; Crawford, 2014).

  14. Ruthenium Behavior at Phase Separation of Borosilicate Glass-12259

    SciTech Connect (OSTI)

    Enokida, Youichi [Graduate School of Engineering, Nagoya University, Nagoya, 463-8603 (Japan); Sawada, Kayo [EcoTopia Science Institute, Nagoya University, Nagoya, 463-8603 (Japan)

    2012-07-01

    The Rokkasho reprocessing plant (RRP) located in Aomori, Japan, vitrifies high level waste (HLW) into a borosilicate glass. The HLW is generated from the reprocessing of spent fuel and contains ruthenium (Ru) and other platinum group metals (PGMs). Based on the recent consequences after a huge earthquake that occurred in Japan, a hypothetical blackout was postulated for the RRP to address additional safety analysis requirements. During a prolonged blackout, the borosilicate glass could phase separate due to cooling of the glass in the melter. The Ru present in the glass matrix could migrate into separate phases and impact the durability of the borosilicate glass. The durability of the glass is important for quality assurance and performance assessment of the vitrified HLW. A fundamental study was performed at an independent university to understand the impact of a prolonged blackout. Simulated HLW glasses were prepared for the RRP, and the Ru behavior in phase separated glasses was studied. The simulated HLW glasses contained nonradioactive elements and PGMs. The glass compositions were then altered to enhance the formation of the phase-separated glasses when subjected to thermal treatment at 700 deg. C for 24 hours. The synthesized simulated glasses contained 1.1 % Ru by weight as ruthenium dioxide (RuO{sub 2}). A portion of the RuO{sub 2} formed needle-shaped crystals in the glass specimens. After the thermal treatment, the glass specimen had separated into two phases. One of the two phases was a B{sub 2}O{sub 3} rich phase, and the other phase was a SiO{sub 2} rich phase. The majority of the chemical species in the B{sub 2}O{sub 3} rich phase was leached away with the Material Characterization Center-3 (MCC-3) protocol standardized by the Pacific Northwest National Laboratory using an aqueous low-concentrated nitric acid solution, but the leaching of the Ru fraction was very limited; less than 1% of the original Ru content. The Ru leaching was much less than

  15. Advanced High-Level Waste Glass Research and Development Plan

    SciTech Connect (OSTI)

    Peeler, David K.; Vienna, John D.; Schweiger, Michael J.; Fox, Kevin M.

    2015-07-01

    The U.S. Department of Energy Office of River Protection (ORP) has implemented an integrated program to increase the loading of Hanford tank wastes in glass while meeting melter lifetime expectancies and process, regulatory, and product quality requirements. The integrated ORP program is focused on providing a technical, science-based foundation from which key decisions can be made regarding the successful operation of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) facilities. The fundamental data stemming from this program will support development of advanced glass formulations, key process control models, and tactical processing strategies to ensure safe and successful operations for both the low-activity waste (LAW) and high-level waste (HLW) vitrification facilities with an appreciation toward reducing overall mission life. The purpose of this advanced HLW glass research and development plan is to identify the near-, mid-, and longer-term research and development activities required to develop and validate advanced HLW glasses and their associated models to support facility operations at WTP, including both direct feed and full pretreatment flowsheets. This plan also integrates technical support of facility operations and waste qualification activities to show the interdependence of these activities with the advanced waste glass (AWG) program to support the full WTP mission. Figure ES-1 shows these key ORP programmatic activities and their interfaces with both WTP facility operations and qualification needs. The plan is a living document that will be updated to reflect key advancements and mission strategy changes. The research outlined here is motivated by the potential for substantial economic benefits (e.g., significant increases in waste throughput and reductions in glass volumes) that will be realized when advancements in glass formulation continue and models supporting facility operations are implemented. Developing and applying advanced

  16. Conversion of shale and slate wastes to glass and glass-ceramic products. Open file report 20 Oct 76-19 Sep 79

    SciTech Connect (OSTI)

    MacKenzie, J.D.

    1980-10-20

    Experiments were conducted to convert spent oil shale, waste slate, and copper slag into glass and glass-ceramic products. Spent oil shale was easily melted at 1,300C and converted into glass wool for insulation application. Glass-ceramics were prepared by the use of domestic chrome ore as a nucleating agent. Waste slate from Vermont was readily melted when mixed with limestone. The resultant glass fibers were highly resistant to alkali attack. Iron metal was recovered from copper slags by the use of coal powder as a reducing agent in the molten slag. The lowering of the iron content resulted ina melt that was glass-forming. Combinations of spent oil shale and copper slag also yielded useful glass and glass ceramic compositions.

  17. Evaluation Of Glass Density To Support The Estimation Of Fissile Mass Loadings From Iron Concentrations In SB8 Glasses

    SciTech Connect (OSTI)

    Edwards, T. B.; Peeler, D. K.; Kot, W. K.; Gan, H.; Pegg, I. L.

    2013-04-30

    The Department of Energy Savannah River (DOE-SR) has provided direction to Savannah River Remediation (SRR) to maintain fissile concentration in glass below 897 g/m{sup 3}. In support of that guidance, the Savannah River National Laboratory (SRNL) provided a technical basis and a supporting Microsoft Excel spreadsheet for the evaluation of fissile loading in Sludge Batch 5 (SB5), Sludge Batch 6 (SB6), Sludge Batch 7a (SB7a), and Sludge Batch 7b (SB7b) glass based on the iron (Fe) concentration in glass as determined by the measurements from the Slurry Mix Evaporator (SME) acceptability analysis. SRR has since requested that the necessary density information be provided to allow SRR to update the Excel spreadsheet so that it may be used to maintain fissile concentration in glass below 897 g/m{sup 3} during the processing of Sludge Batch 8 (SB8). One of the primary inputs into the fissile loading spreadsheet includes an upper bound for the density of SB8-based glasses. Thus, these bounding density values are to be used to assess the fissile concentration in this glass system. It should be noted that no changes are needed to the underlying structure of the Excel-based spreadsheet to support fissile assessments for SB8. However, SRR should update the other key inputs to the spreadsheet that are based on fissile and Fe concentrations reported from the SB8 Waste Acceptance Product Specification (WAPS) sample.

  18. Doped LZO buffer layers for laminated conductors

    DOE Patents [OSTI]

    Paranthaman, Mariappan Parans [Knoxville, TN; Schoop, Urs [Westborough, MA; Goyal, Amit [Knoxville, TN; Thieme, Cornelis Leo Hans [Westborough, MA; Verebelyi, Darren T [Oxford, MA; Rupich, Martin W [Framingham, MA

    2010-03-23

    A laminated conductor includes a metallic substrate having a surface, a biaxially textured buffer layer supported by the surface of the substrate, the biaxially textured buffer layer comprising LZO and a dopant for mitigating metal diffusion through the LZO, and a biaxially textured conductor layer supported by the biaxially textured buffer layer.

  19. Lubricant-infused nanoparticulate coatings assembled by layer...

    Office of Scientific and Technical Information (OSTI)

    Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition Title: Lubricant-infused nanoparticulate coatings assembled by layer-by-layer deposition ...

  20. Final Report on Actinide Glass Scintillators for Fast Neutron Detection

    SciTech Connect (OSTI)

    Bliss, Mary; Stave, Jean A.

    2012-10-01

    This is the final report of an experimental investigation of actinide glass scintillators for fast-neutron detection. It covers work performed during FY2012. This supplements a previous report, PNNL-20854 “Initial Characterization of Thorium-loaded Glasses for Fast Neutron Detection” (October 2011). The work in FY2012 was done with funding remaining from FY2011. As noted in PNNL-20854, the glasses tested prior to July 2011 were erroneously identified as scintillators. The decision was then made to start from “scratch” with a literature survey and some test melts with a non-radioactive glass composition that could later be fabricated with select actinides, most likely thorium. The normal stand-in for thorium in radioactive waste glasses is cerium in the same oxidation state. Since cerium in the 3+ state is used as the light emitter in many scintillating glasses, the next most common substitute was used: hafnium. Three hafnium glasses were melted. Two melts were colored amber and a third was clear. It barely scintillated when exposed to alpha particles. The uses and applications for a scintillating fast neutron detector are important enough that the search for such a material should not be totally abandoned. This current effort focused on actinides that have very high neutron capture energy releases but low neutron capture cross sections. This results in very long counting times and poor signal to noise when working with sealed sources. These materials are best for high flux applications and access to neutron generators or reactors would enable better test scenarios. The total energy of the neutron capture reaction is not the only factor to focus on in isotope selection. Many neutron capture reactions result in energetic gamma rays that require large volumes or high densities to detect. If the scintillator is to separate neutrons from gamma rays, the capture reactions should produce heavy particles and few gamma rays. This would improve the detection of a