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1

Rechargeable lithium-ion cell  

DOE Patents (OSTI)

The invention relates to a rechargeable lithium-ion cell, a method for its manufacture, and its application. The cell is distinguished by the fact that it has a metallic housing (21) which is electrically insulated internally by two half shells (15), which cover electrode plates (8) and main output tabs (7) and are composed of a non-conductive material, where the metallic housing is electrically insulated externally by means of an insulation coating. The cell also has a bursting membrane (4) which, in its normal position, is located above the electrolyte level of the cell (1). In addition, the cell has a twisting protection (6) which extends over the entire surface of the cover (2) and provides centering and assembly functions for the electrode package, which comprises the electrode plates (8).

Bechtold, Dieter (Bad Vilbel, DE); Bartke, Dietrich (Kelkheim, DE); Kramer, Peter (Konigstein, DE); Kretzschmar, Reiner (Kelkheim, DE); Vollbert, Jurgen (Hattersheim, DE)

1999-01-01T23:59:59.000Z

2

Performance of Lithium Ion Cell Anode Graphites Under Various Cycling Conditions  

E-Print Network (OSTI)

CA 94720 Performance of Lithium Ion Cell Anode Graphitesevaluated (in coin cells with lithium counter electrodes) asanode materials for lithium-ion cells intended for use in

Ridgway, Paul

2010-01-01T23:59:59.000Z

3

The Lithium-Ion Cell: Model, State Of Charge Estimation  

E-Print Network (OSTI)

The Lithium-Ion Cell: Model, State Of Charge Estimation and Battery Management System Tutor degradation mechanisms of a Li-ion cell based on LiCoO2", Journal of Power Sources #12;Lithium ions and e and Y. Fuentes. Computer simulations of a lithium-ion polymer battery and implications for higher

Schenato, Luca

4

Calorimetric Studies of Lithium Ion Cells and Their Constructing ...  

Science Conference Proceedings (OSTI)

Commercial Lithium-ion pouch cells, several types of 18650 cylindrical cells and coin cells were cycled at different charge and discharge rates. Heat capacities ...

5

Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.  

DOE Green Energy (OSTI)

Redox shuttle is a promising mechanism for intrinsic overcharge protection in lithium-ion cells and batteries. Two lithium borate cluster salts are reported to function as both the main salt for a nonaqueous electrolyte and the redox shuttle for overcharge protection. Lithium borate cluster salts with a tunable redox potential are promising candidates for overcharge protection for most positive electrodes in state-of-the-art lithium-ion cells.

Chen, Z.; Liu, J.; Jansen, A. N.; Casteel, B.; Amine, K.; GirishKumar, G.; Air Products and Chemicals, Inc.

2010-01-01T23:59:59.000Z

6

Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites  

NLE Websites -- All DOE Office Websites (Extended Search)

Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites Title Comparison of Cycling Performance of Lithium Ion Cell Anode Graphites Publication Type Journal Article Year of Publication 2012 Authors Ridgway, Paul L., Honghe Zheng, A. F. Bello, Xiangyun Song, Shidi Xun, Jin Chong, and Vincent S. Battaglia Journal Journal of The Electrochemical Society Volume 159 Issue 5 Pagination A520 Date Published 2012 ISSN 00134651 Abstract Battery grade graphite products from major suppliers to the battery industry were evaluated in 2325 coin cells with lithium counter electrodes. First and ongoing cycle efficiency, total and reversible capacity, cycle life and discharge rate performance were measured to compare these anode materials. We then ranked the graphites using a formula which incorporates these performance measures to estimate the cost of the overall system, relative to the cost of a system using MCMB. This analysis indicates that replacing MCMB with CCP-G8 (Conoco Phillips) would add little to no cost, whereas each of the other graphites would lead to a more costly system. Therefore we chose CCP-G8 as the new baseline graphite for the BATT program.

7

Quantifying Cell-to-Cell Variations in Lithium Ion Batteries  

DOE Green Energy (OSTI)

Lithium ion batteries have conventionally been manufactured in small capacities but large volumes for consumer electronics applications. More recently, the industry has seen a surge in the individual cell capacities, as well as the number of cells used to build modules and packs. Reducing cell-to-cell and lot-to-lot variations has been identified as one of the major means to reduce the rejection rate when building the packs as well as to improve pack durability. The tight quality control measures have been passed on from the pack manufactures to the companies building the individual cells and in turn to the components. This paper identifies a quantitative procedure utilizing impedance spectroscopy, a commonly used tool, to determine the effects of material variability on the cell performance, to compare the relative importance of uncertainties in the component properties, and to suggest a rational procedure to set quality control specifications for the various components of a cell, that will reduce cell-to-cell variability, while preventing undue requirements on uniformity that often result in excessive cost of manufacturing but have a limited impact on the cells performance.

Santhanagopalan, S.; White, R. E.

2012-01-01T23:59:59.000Z

8

Structural Integration of Silicon Solar Cells and Lithium-ion Batteries Using Printed Electronics  

E-Print Network (OSTI)

Lithium-Ion Polymer Battery ..Performance of Lithium-Ion Polymer Battery Introduction Assolid state lithium-ion (Li-ion) battery were adhesively

Kang, Jin Sung

2012-01-01T23:59:59.000Z

9

Thermal stability of electrodes in Lithium-ion cells  

DOE Green Energy (OSTI)

Differential scanning calorimetry (DSC) analysis was used to identify thermal reactions in Sony-type lithium-ion cells and to correlate these reactions with interactions of cell constituents and reaction products. An electrochemical half-cell was used to cycle the anode and cathode materials and to set the state-of-charge (SOC). Three temperature regions of interaction were identified and associated with the SOC (degree of Li intercalation) of the cell. Anodes were shown to undergo exothermic reactions as low as 80 C involving decomposition of the solid electrolyte interphase (SEI) layer. The LiPF{sub 6} salt in the electrolyte (EC:PC:DEC/1M LiPF{sub 6}) was seen to play an essential role in this reaction. DSC analysis of the anodes from disassembled Sony cells showed similar behavior to the half-cell anodes with a strong exotherm beginning in the 80 C--90 C range. Exothermic reactions were also observed in the 200 C--300 C region between the intercalated lithium anodes, the LiPF{sub 6} salt, and the PVDF binder. These reactions were followed by a high-temperature reaction region, 300 C--400 C, also involving the PVDF binder and the intercalated lithium anodes. Cathode exothermic reactions with the PVDF binder were observed above 200 C and increased with the SOC (decreasing Li content in the cathode). No thermal reactions were seen at lower temperatures suggesting that thermal runaway reactions in this type of cell are initiated at the anode. An Accelerating Rate Calorimeter (ARC) was used to perform measurements of thermal runaway on commercial Sony Li-ion cells as a function of SOC. The cells showed sustained thermal output as low as 80 C in agreement with the DSC observations of anode materials but the heating rate was strongly dependent on the SOC.

ROTH,EMANUEL P.; NAGASUBRAMANIAN,GANESAN

2000-02-07T23:59:59.000Z

10

Side Reactions in Lithium-Ion Batteries  

E-Print Network (OSTI)

Model for Aging of Lithium-Ion Battery Cells. Journal of TheSalts Formed on the Lithium-Ion Battery Negative Electrodeion batteries In a lithium ion battery, positively charged

Tang, Maureen Han-Mei

2012-01-01T23:59:59.000Z

11

Lithium Ion Accomplishments  

NLE Websites -- All DOE Office Websites (Extended Search)

Lithium ion Battery Commercialization Lithium ion Battery Commercialization Johnson Controls-Saft Advanced Power Solutions, of Milwaukee, Wisconsin: Johnson Controls-Saft (JCS) will supply lithium-ion batteries to Mercedes for their S Class Hybrid to be introduced in October 2009. Technology developed with DOE support (the VL6P cell) will be used in the S Class battery. In May 2006, the Johnson Controls-Saft Joint Venture was awarded a 24 month $14.4 million contract by the DOE/USABC to develop a 40kW Li ion HEV battery system offering improved safety, low temperature performance, and cost. JCS has reported a 40% cost reduction of the 40kW system being developed in their DOE/USABC contract while maintaining performance. Lithium Ion Battery Material Commercialization Argonne National Laboratory has licensed cathode materials and associated processing

12

Lithium Ion Cell Development for Photovoltaic Energy Storage Applications  

Science Conference Proceedings (OSTI)

The overall project goal is to reduce the cost of home and neighborhood photovoltaic storage systems by reducing the single largest cost component â?? the energy storage cells. Solar power is accepted as an environmentally advantaged renewable power source. Its deployment in small communities and integrated into the grid, requires a safe, reliable and low cost energy storage system. The incumbent technology of lead acid cells is large, toxic to produce and dispose of, and offer limited life even with significant maintenance. The ideal PV storage battery would have the safety and low cost of lead acid but the performance of lithium ion chemistry. Present lithium ion batteries have the desired performance but cost and safety remain the two key implementation barriers. The purpose of this project is to develop new lithium ion cells that can meet PVES cost and safety requirements using A123Systems phosphate-based cathode chemistries in commercial PHEV cell formats. The cost target is a cell design for a home or neighborhood scale at <$25/kWh. This DOE program is the continuation and expansion of an initial MPSC (Michigan Public Service Commission) program towards this goal. This program further pushes the initial limits of some aspects of the original program â?? even lower cost anode and cathode actives implemented at even higher electrode loadings, and as well explores new avenues of cost reduction via new materials â?? specifically our higher voltage cathode. The challenge in our materials development is to achieve parity in the performance metrics of cycle life and high temperature storage, and to produce quality materials at the production scale. Our new cathode material, M1X, has a higher voltage and so requires electrolyte reformulation to meet the high temperature storage requirements. The challenge of thick electrode systems is to maintain adequate adhesion and cycle life. The composite separator has been proven in systems having standard loading electrodes; the challenge with this material will be to maintain proven performance when this composite is coated onto a thicker electrode; as well the high temperature storage must meet application requirements. One continuing program challenge was the lack of specific performance variables for this PV application and so the low power requirements of PHEV/EV transportation markets were again used.

Susan Babinec

2012-02-08T23:59:59.000Z

13

Modeling capacity fade in lithium-ion cells.  

SciTech Connect

Battery life is an important, yet technically challenging, issue for battery development and application. Adequately estimating battery life requires a significant amount of testing and modeling effort to validate the results. Integrated battery testing and modeling is quite feasible today to simulate battery performance, and therefore applicable to predict its life. A relatively simple equivalent-circuit model (ECM) is used in this work to show that such an integrated approach can actually lead to a high-fidelity simulation of a lithium-ion cell's performance and life. The methodology to model the cell's capacity fade during thermal aging is described to illustrate its applicability to battery calendar life prediction.

Liaw, Bor Yann (University of Hawaii, Honolulu, HI); Doughty, Daniel Harvey; Nagasubramanian, Ganesan; Jungst, Rudolph George

2003-09-01T23:59:59.000Z

14

Rate-based degradation modeling of lithium-ion cells  

DOE Green Energy (OSTI)

Accelerated degradation testing is commonly used as the basis to characterize battery cell performance over a range of stress conditions (e.g., temperatures). Performance is measured by some response that is assumed to be related to the state of health of the cell (e.g., discharge resistance). Often, the ultimate goal of such testing is to predict cell life at some reference stress condition, where cell life is defined to be the point in time where performance has degraded to some critical level. These predictions are based on a degradation model that expresses the expected performance level versus the time and conditions under which a cell has been aged. Usually, the degradation model relates the accumulated degradation to the time at a constant stress level. The purpose of this article is to present an alternative framework for constructing a degradation model that focuses on the degradation rate rather than the accumulated degradation. One benefit of this alternative approach is that prediction of cell life is greatly facilitated in situations where the temperature exposure is not isothermal. This alternative modeling framework is illustrated via a family of rate-based models and experimental data acquired during calendar-life testing of high-power lithium-ion cells.

E.V. Thomas; I. Bloom; J.P. Christophersen; V.S. Battaglia

2012-05-01T23:59:59.000Z

15

Multi-Dimensional Electrochemical-Thermal Coupled Model of Large Format Cylindrical Lithium Ion Cells (Presentation)  

DOE Green Energy (OSTI)

Presentation on 3-D modeling of lithium-ion cells used in plug-in hyybrid electric vehicle batteries. 3-D models provide better understanding of cell design, operation, and management.

Kim, G.-H.; Smith, K.

2007-10-01T23:59:59.000Z

16

Novel carbonaceous materials used as anodes in lithium ion cells  

DOE Green Energy (OSTI)

The objective of this work is to synthesize disordered carbons used as anodes in lithium ion batteries, where the porosity and surface area are controlled. Both parameters are critical since the irreversible capacity obtained in the first cycle seems to be associated with the surface area (an exfoliation mechanism occurs in which the exposed surface area continues to increase).

Sandi, G.; Winans, R.E.; Carrado, K.A.

1997-09-01T23:59:59.000Z

17

Performance of Lithium Ion Cell Anode Graphites Under Various Cycling Conditions  

Science Conference Proceedings (OSTI)

Graphites MCMB-2810 and OMAC-15 (made by Osaka Gas Inc.), and SNG12 (Hydro Quebec, Inc.) were evaluated (in coin cells with lithium counter electrodes) as anode materials for lithium-ion cells intended for use in hybrid electric vehicles. Though the reversible capacity obtained for SNG was slightly higher than that of OMAC or MCMB, its 1st cycle efficiency was lower. Voltage vs capacity plots of cycling data show that the discharge and charge limits shift to higher capacity values due to continuation of anode side reactions. Varying the cycle charge and discharge limits was found to have no significant effect on fractional capacity shift per cycle.

Ridgway, Paul; Zheng, Honghe; Liu, Gao; Song, Xiangun; Guerfi, Abdelbast; Charest, Patrick; Zaghib, Karim; Battaglia, Vincent

2009-06-15T23:59:59.000Z

18

Parameter Estimation and Life Modeling of Lithium-Ion Cells Shriram Santhanagopalan,*,a  

E-Print Network (OSTI)

for solid phase diffusion in lithium ion battery electrodes: Variable diffusion coefficient Sindhuja online 30 June 2010 Keywords: Integral transform technique Semianalytical method Lithium ion battery of diffusion process in lithium ion battery electrode. The solutions obtained using the method presented

19

ForPeerReview A Validation Study of Lithium-ion Cell Constant C-Rate  

E-Print Network (OSTI)

and Engineering, Engineering and Public Policy Keywords: Battery Design Studio®, Lithium-ion, Battery Performance compare battery performance simulations from a commercial lithium-ion battery modeling software package in discharge performance simulations for many applications. Keywords: Battery Design Studio®; Lithium-ion

Michalek, Jeremy J.

20

Impact of tripropyl borate on life and impedance of lithium-ion cells.  

DOE Green Energy (OSTI)

Tripropyl borate was investigated as a low cost anion receptor to improve the performance of lithium-ion cells. The impact of tripropyl borate was examined using lithium-ion cells comprising a negative electrode of mesocarbon microbeads, a positive electrode of Li{sub 1.1}[Mn{sub 1/3}Ni{sub 1/3}Co{sub 1/3}]{sub 0.9}O{sub 2} and an LiPF{sub 6}-based electrolyte. It was found that the performance of the cells was improved by adding a proper amount of tripropyl borate ({le} 0.1 wt%) to the LiPF{sub 6}-based electrolyte. However, a small amount of gas was observed from cells with high contents of tripropyl borate when cycled at 55 C, and as a result, the performance of the cells deteriorated.

Chen, Z.; Liu, J.; Amine, K.; Chemical Sciences and Engineering Division

2008-03-10T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Eeffect of electrolyte composition on initial cycling and impedance characteristics of lithium-ion-cells.  

SciTech Connect

Hybrid-electric vehicles require lithium-battery electrolytes that form stable, low impedance passivation layers to protect the electrodes, while allowing rapid lithium-ion transport under high current charge/discharge pulses. In this article, we describe data acquired on cells containing LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2}-based positive electrodes, graphite-based negative electrodes, and electrolytes with lithium hexafluorophosphate (LiPF{sub 6}), lithium tetrafluoroborate (LiBF{sub 4}), lithium bis(oxalato)borate (LiBOB) and lithium difluoro(oxalato) borate (LiF{sub 2}OB) salts. The impedance data were collected in cells containing a Li-Sn reference electrode to determine effect of electrolyte composition and testing temperature on individual electrode impedance. The full cell impedance data showed the following trend: LiBOB > LiBF{sub 4} > LiF{sub 2}OB > LiPF{sub 6}. The negative electrode impedance showed a trend similar to that of the full cell; this electrode was the main contributor to impedance in the LiBOB and LiBF{sub 4} cells. The positive electrode impedance values for the LiBF{sub 4}, LiF{sub 2}OB, and LiPF{sub 6} cells were comparable; the values were somewhat higher for the LiBOB cell. Cycling and impedance data were also obtained for cells containing additions of LiBF{sub 4}, LiBOB, LiF{sub 2}OB, and vinylene carbonate (VC) to the EC:EMC (3:7 by wt.) + 1.2 M LiPF{sub 6} electrolyte. Our data indicate that the composition and morphology of the graphite SEI formed during the first lithiation cycle is an important determinant of the negative electrode impedance, and hence full cell impedance.

Abraham, D. P.; Furczon, M. M.; Kang, S.-H.; Dees, D. W.; Jansen, A. N.; Chemical Sciences and Engineering Division

2008-01-01T23:59:59.000Z

22

Recent advances in lithium ion technology  

Science Conference Proceedings (OSTI)

Lithium ion technology is based on the use of lithium intercalating electrodes. Carbon is the most commonly used anode material, while the cathode materials of choice have been layered lithium metal chalcogenides (LiMX{sub 2}) and lithium spinel-type compounds. Electrolytes may be either organic liquids or polymers. Although the first practical use of graphite intercalation compounds as battery anodes was reported in 1981 for molten salt cells (1) and in 1983 for ambient temperature systems (2) it was not until Sony Energytech announced a new lithium ion rechargeable cell containing a lithium ion intercalating carbon anode in 1990, that interest peaked. The reason for this heightened interest is that these cells have the high energy density, high voltage and fight weight of metallic lithium systems plus a very long cycle life, but without the disadvantages of dendrite formation on charge and the safety considerations associated with metallic lithium.

Levy, S.C.

1995-01-01T23:59:59.000Z

23

Diagnostic examination of Generation 2 lithium-ion cells and assessment ofperformance degradation mechanisms.  

DOE Green Energy (OSTI)

The Advanced Technology Development (ATD) Program is a multilaboratory effort to assist industrial developers of high-power lithium-ion batteries overcome the barriers of cost, calendar life, abuse tolerance, and low-temperature performance so that this technology may be rendered practical for use in hybrid electric vehicles (HEVs). Included in the ATD Program is a comprehensive diagnostics effort conducted by researchers at Argonne National Laboratory (ANL), Brookhaven National Laboratory (BNL), and Lawrence Berkeley National Laboratory (LBNL). The goals of this effort are to identify and characterize processes that limit lithium-ion battery performance and calendar life, and ultimately to describe the specific mechanisms that cause performance degradation. This report is a compilation of the diagnostics effort conducted since spring 2001 to characterize Generation 2 ATD cells and cell components. The report is divided into a main body and appendices. Information on the diagnostic approach, details from individual diagnostic techniques, and details on the phenomenological model used to link the diagnostic data to the loss of 18650-cell electrochemical performance are included in the appendices. The main body of the report includes an overview of the 18650-cell test data, summarizes diagnostic data and modeling information contained in the appendices, and provides an assessment of the various mechanisms that have been postulated to explain performance degradation of the 18650 cells during accelerated aging. This report is intended to serve as a ready reference on ATD Generation 2 18650-cell performance and provide information on the tools for diagnostic examination and relevance of the acquired data. A comprehensive account of our experimental procedures and resulting data may be obtained by consulting the various references listed in the text. We hope that this report will serve as a roadmap for the diagnostic analyses of other lithium-ion technologies being evaluated for HEV applications. It is our hope that the information contained in this report will lead to the development of new lithium-ion cell chemistries and designs that will meet the 15-year cell calendar-life goal established by DOE's FreedomCar and Fuel Partnership.

Abraham, D. P.; Dees, D. W.; Knuth, J.; Reynolds, E.; Gerald, R.; Hyung,Y.-E.; Belharouak, I.; Stoll, M.; Sammann, E.; MacLaren, S.; Haasch, R.; Twesten,R.; Sardela, M.; Battaglia, V.; Cairns, E.; Kerr, J.; Kerlau, M.; Kostecki, R.; Lei,J.; McCarthy, K.; McLarnon, F.; Reimer, J.; Richardson, T.; Ross, P.; Sloop,S.; Song, X.; Zhuang, V.; Balasubramanian, M.; McBreen, J.; Chung, K.-Y.; Yang, X.Q.; Yoon, W.-S.; Norin, L.

2005-07-15T23:59:59.000Z

24

Microscopy and spectroscopy of lithium nickel oxide based particles used in high-power lithium-ion cells.  

DOE Green Energy (OSTI)

Structural and electronic investigations were conducted on lithium nickel oxide-based particles used in positive electrodes of 18650-type high-power Li-ion cells. K-edge X-ray absorption spectroscopy (XAS) revealed trivalent Ni and Co ions in the bulk LiNi{sub 0.8}Co{sub 0.2}O{sub 2} powder used to prepare the high power electrode laminates. Using oxygen K-edge XAS, high resolution electron microscopy, nanoprobe diffraction, and electron energy-loss spectroscopy, we identified a <5 nm thick modified layer on the surface of the oxide particles, which results from the loss of Ni and Li ordering in the layered R{bar 3}m structure. This structural change was accompanied by oxygen loss and a lowering of the Ni- and Co-oxidation states in the surface layer. Growth of this surface layer may contribute to the impedance rise observed during accelerated aging of these Li-ion cells.

Abraham, D. P.; Twesten, R. D.; Balasubramanian, M.; Kropf, A. J.; Fischer, D.; McBreen, J.; Petrov, I.; Amine, K.; Chemical Engineering; Univ. of Illinois; BNL; NIST

2003-11-01T23:59:59.000Z

25

Lithium ion rechargeable systems studies  

Science Conference Proceedings (OSTI)

Lithium ion systems, although relatively new, have attracted much interest worldwide. Their high energy density, long cycle life and relative safety, compared with metallic lithium rechargeable systems, make them prime candidates for powering portable electronic equipment. Although lithium ion cells are presently used in a few consumer devices, e.g., portable phones, camcorders, and laptop computers, there is room for considerable improvement in their performance. Specific areas that need to be addressed include: (1) carbon anode--increase reversible capacity, and minimize passivation; (2) cathode--extend cycle life, improve rate capability, and increase capacity. There are several programs ongoing at Sandia National Laboratories which are investigating means of achieving the stated objectives in these specific areas. This paper will review these programs.

Levy, S.C.; Lasasse, R.R.; Cygan, R.T.; Voigt, J.A.

1995-02-01T23:59:59.000Z

26

Instability of Polyvinylidene Fluoride-Based Polymeric Binder in Lithium-Ion Cells: Final Report  

DOE Green Energy (OSTI)

Thermal instabilities were identified in SONY-type lithium-ion cells and correlated with interactions of cell constituents and reaction products. Three temperature regions of interaction were identified and associated with the state of charge (degree of Li intercalation) of the cell. Anodes were shown to undergo exothermic reactions as low as 100 degree C involving the solid electrolyte interface (SEI) layer and the LiPF(6) salt in the electrolyte (EC-PC:DEC/IM LiPF(6)). These reactions could account for the thermal runaway observed in these cells beginning at 100 degree C. Exothermic reactions were also observed in the 200 degree C to 300 degree C region between the intercalated lithium anodes, the LiPF(6) salt, and the PVDF. These reactions were followed by a high-temperature reaction region, 300 degree C to 400 degree C, also involving the PVDF binder and the intercalated lithium anodes. The solvent was not directly involved in these reactions but served as a moderator and transport medium. Cathode exothermic reactions with the PVDF binder were observed above 200 degree C and increased with the state of charge (decreasing Li content). The stability of the PVDF binder as a function of electrochemical cycling was studied using FTIR. The infrared spectra from the extracts of both electrodes indicate that PVDF is chemically modified by exposure to the lithium cell electrolyte (as well as electrochemical cycling) in conjunction with NMP extraction. Preconditioning of PVDF to dehydrohalogenation, which may be occurring by reaction with LiPf(6), makes the PVDF susceptible to attack by a range of nucleophiles.

Garcia, M.; Nagasubramanian, G.; Tallant, D.R.; Roth, E.P.

1999-05-01T23:59:59.000Z

27

Investigation of elevated temperature aging effects on lithium-ion cells  

DOE Green Energy (OSTI)

Electrical and chemical measurements have been made on 18650-size lithium-ion cells that have been exposed to calendar and cycle life aging at temperatures up to 70 C. Aging times ranged from 2 weeks at the highest temperature to several months under more moderate conditions. After aging, the impedance behavior of the cells was reversed from that found originally, with lower impedance at low state of charge and the total impedance was significantly increased. Investigations using a reference electrode showed that these changes are primarily due to the behavior of the cathode. Measurements of cell impedance as a function of cell voltage reveal a pronounced minimum in the total impedance at approximately 40--50% state-of-charge (SOC). Chemical analysis data are presented to support the SOC assignments for aged and unaged cells. Electrochemical impedance spectroscopy (EIS) data have been recorded at several intermediate states of charge to construct the impedance vs. open circuit voltage curve for the cell. This information has not previously been available for the LiNi{sub 0.85}Co{sub 0.15}O{sub 2} cathode material. Structural and chemical analysis information obtained from cell components removed during postmortems will also be discussed in order to reveal the true state of charge of the cathode and to develop a more complete lithium inventory for the cell.

JUNGST,RUDOLPH G.; NAGASUBRAMANIAN,GANESAN; INGERSOLL,DAVID

2000-04-17T23:59:59.000Z

28

Graphene-based Electrochemical Energy Conversion and Storage: Fuel cells, Supercapacitors and Lithium Ion Batteries  

SciTech Connect

Graphene has attracted extensive research interest due to its strictly 2-dimensional (2D) structure, which results in its unique electronic, thermal, mechanical, and chemical properties and potential technical applications. These remarkable characteristics of graphene, along with the inherent benefits of a carbon material, make it a promising candidate for application in electrochemical energy devices. This article reviews the methods of graphene preparation, introduces the unique electrochemical behavior of graphene, and summarizes the recent research and development on graphene-based fuel cells, supercapacitors and lithium ion batteries. In addition, promising areas are identified for the future development of graphene-based materials in electrochemical energy conversion and storage systems.

Hou, Junbo; Shao, Yuyan; Ellis, Michael A.; Moore, Robert; Yi, Baolian

2011-09-14T23:59:59.000Z

29

Review of lithium-ion technology  

DOE Green Energy (OSTI)

The first practical use of graphite intercalation compounds (GIC) as battery anodes was reported in a 1981 patent by Basu in which a molten salt cell was described having a negative electrode that consisted of lithium intercalated in graphite. A second patent by Basu, issued in 1983, described an ambient temperature rechargeable system which also utilized lithium intercalated in graphite as the anode. Work in this area progressed at a low level, however, until interest was sparked in 1990 when Sony Corporation announced a new ``lithium-ion`` rechargeable cell containing a lithium ion intercalating carbon anode. These cells have the advantages of metallic lithium systems; i.e., high energy density, high voltage, and light weight, without the disadvantages of dendrite formation on charge and the safety considerations associated with metallic lithium. Materials other than carbon have been studied as intercalation anodes. Examples are Fe{sub 2}O{sub 3}, WO{sub 2} and TiS{sub 2}. Although these alternate anode materials are of interest academically and for specialty applications, they do not hold much promise for widespread general use due to their increased weight and lower cell voltage. Studies of cathode materials for lithium-ion systems have centered on the transition metal chalcogenides. A number of these materials are capable of reversibly intercalating lithium ions at a useful potential versus lithium. Both organic liquids and polymers are candidate electrolytes for this technology.

Levy, S.C.; Cieslak, W.R.

1993-12-31T23:59:59.000Z

30

I-V analysis of high-energy lithium-ion-irradiated Si and GaAs solar cells  

E-Print Network (OSTI)

Space-grade Si and GaAs solar cells were irradiated with 15 and 40 MeV lithium ions. Dark-IV analysis (with and without illumination) reveals differences in the effects of such irradiation on the different cell types

A. Meulenberg Jr; B. Jayashree; Ramani; M. C. Radhakrishna; A. K. Saif

2007-09-07T23:59:59.000Z

31

Design of a testing device for quasi-confined compression of lithium-ion battery cells  

E-Print Network (OSTI)

The Impact and Crashworthiness Laboratory at MIT has formed a battery consortium to promote research concerning the crash characteristics of new lithium-ion battery technologies as used in automotive applications. Within ...

Roselli, Eric (Eric J.)

2011-01-01T23:59:59.000Z

32

Cyanoethylated Compounds as Additives in Lithium/Lithium Ion Batteries  

DOE Patents (OSTI)

The power loss of lithium/lithium ion battery cells is significantly reduced, especially at low temperatures, when about 1% by weight of an additive is incorporated in the electrolyte layer of the cells. The usable additives are organic solvent soluble cyanoethylated polysaccharides and poly(vinyl alcohol). The power loss decrease results primarily from the decrease in the charge transfer resistance at the interface between the electrolyte and the cathode.

Nagasubramanian, Ganesan

1998-05-08T23:59:59.000Z

33

Simplified Electrode Formation using Stabilized Lithium Metal Powder (SLMP) Doping of Lithium Ion Battery Electrodes  

lithium ion battery electrode formation that can boost a cell’s charge capacity and lower its cost while improving reliability and safety.

34

Lithium-Ion Battery Issues  

NLE Websites -- All DOE Office Websites (Extended Search)

Lithium-Ion Battery Issues IEA Workshop on Battery Recycling Hoboken, Belgium September 26-27, 2011 Linda Gaines Center for Transportation Research Argonne National Laboratory...

35

Accelerated Degradation Assessment of 18650 Lithium-Ion Batteries  

Science Conference Proceedings (OSTI)

Power fade of lithium cells due to accelerated factors of temperature and charging-discharging rate was assessed. A lithium-ion battery aging model for predicting the power fade of 18650-size cells was applied, and then statistically accelerated degradation ... Keywords: accelerated degradation test, lithium-ion battery aging, power fade, state of charge (SOC)

Kuan-Jung Chung; Chueh-Chien Hsiao

2012-06-01T23:59:59.000Z

36

Advances in lithium-ion batteries  

E-Print Network (OSTI)

current reviews of the lithium ion battery literature byof view of the lithium ion battery scientist and engineer,lithium ion batteries. The chapter on aging summarizes the effects of the chemistry on the battery

Kerr, John B.

2003-01-01T23:59:59.000Z

37

Molten salt lithium cells  

DOE Patents (OSTI)

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell which may be operated at temperatures between about 100 to 170/sup 0/C. The cell is comprised of an electrolyte, which preferably includes lithium nitrate, and a lithium or lithium alloy electrode.

Raistrick, I.D.; Poris, J.; Huggins, R.A.

1980-07-18T23:59:59.000Z

38

Molten salt lithium cells  

DOE Patents (OSTI)

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

1983-01-01T23:59:59.000Z

39

Molten salt lithium cells  

DOE Patents (OSTI)

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and is operated in the temperature range of about 400.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems and a substantial amount of energy is lost through heat transfer. The present invention provides an electrochemical cell (10) which may be operated at temperatures between about 100.degree.-170.degree. C. Cell (10) comprises an electrolyte (16), which preferably includes lithium nitrate, and a lithium or lithium alloy electrode (12).

Raistrick, Ian D. (Menlo Park, CA); Poris, Jaime (Portola Valley, CA); Huggins, Robert A. (Stanford, CA)

1982-02-09T23:59:59.000Z

40

electrodes in lithium ion batteries  

E-Print Network (OSTI)

Nickel oxide (NiO) nanotubes have been produced for the first time via a template processing method. The synthesis involved a two step chemical reaction in which nickel hydroxide (Ni(OH)2) nanotubes were firstly formed within the walls of an anodic aluminium oxide (AAO) template. The template was then dissolved away using concentrated NaOH, and the freed nanotubes were converted to NiO by heat treatment in air at 350 ? C. Individual nanotubes measured 60 ?m in length with a 200 nm outer diameter and a wall thickness of 20–30 nm. The NiO nanotube powder was used in Li-ion cells for assessment of the lithium storage ability. Preliminary testing indicates that the cells demonstrate controlled and sustainable lithium diffusion after the formation of an SEI. Reversible capacities in the 300 mAh g ?1 range were typical.

S. A. Needham; G. X. Wang; H. K. Liu

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Solid lithium-ion electrolyte  

DOE Patents (OSTI)

The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li.sub.2 O--CeO.sub.2 --SiO.sub.2 system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications.

Zhang, Ji-Guang (Golden, CO); Benson, David K. (Golden, CO); Tracy, C. Edwin (Golden, CO)

1998-01-01T23:59:59.000Z

42

Solid lithium-ion electrolyte  

DOE Patents (OSTI)

The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li{sub 2}O--CeO{sub 2}--SiO{sub 2} system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications. 12 figs.

Zhang, J.G.; Benson, D.K.; Tracy, C.E.

1998-02-10T23:59:59.000Z

43

Lithium Hexamethyldisilazide: A View of Lithium Ion Solvation  

E-Print Network (OSTI)

Lithium Hexamethyldisilazide: A View of Lithium Ion Solvation through a Glass-Bottom Boat BRETT L and reactivities, we were drawn to lithium hexamethyldisilazide (LiHMDS; (Me3Si)2NLi) by its promi- nence principles of lithium ion coordination chemistry.2 Understanding how solvation influences organolithium

Collum, David B.

44

Towards Safer Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

Towards Safer Lithium-Ion Batteries Towards Safer Lithium-Ion Batteries Speaker(s): Guoying Chen Date: October 25, 2007 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Venkat Srinivasan Safety problems associated with rechargeable lithium batteries are now well recognized. Recent spectacular fires involving cell phones, laptops, and (here at LBNL) AA cells have made the news. These events are generally caused by overcharging and subsequent development of internal shorts. Before these batteries can be used in vehicle applications, improvement in cell safety is a must. We have been active in the area of lithium battery safety for many years. For example, a versatile, inexpensive overcharge protection approach developed in our laboratory, uses an electroactive polymer to act as a reversible, self-actuating, low resistance internal

45

Materials and Processing for Lithium-Ion Batteries (Originally  

Science Conference Proceedings (OSTI)

... safe and reliable lithium ion batteries will soon be on board hybrid electric and electric vehicles and connected to solar cells and windmills. However, safety of ...

46

High Power Performance Lithium Ion Battery - Energy Innovation Portal  

... “Optimization of Acetylene Black Conductive Additive and Polyvinylidene Fluoride Composition for high Power Rechargeable Lithium-Ion Cells,” The 211th ...

47

Anodes Improve Safety and Performance in Lithium-ion Batteries ...  

Rechargeable lithium-ion batteries have become the battery of choice for everything from cell phones to electric cars, but there is still much room ...

48

Anodes Improve Safety and Performance in Lithium-ion Batteries ...  

Rechargeable lithium-ion batteries have become the battery of choice for everything from cell phones to electric cars, but there is still much room for improvement.

49

Available Technologies: High Power Performance Lithium Ion Battery  

Cell 1, which has the highest binder (PVDF) to acetylene black ratio, displays the most favorable discharge ASI. Lithium ion batteries with high power ...

50

Characterization of high-power lithium-ion cells-performance and diagnostic analysis  

DOE Green Energy (OSTI)

Lithium-ion cells, with graphite anodes and LiNi0.8Co0.15Al0.05O2 cathodes, were cycled for up to 1000 cycles over different ranges of SOC and temperatures. The decline in cell performance increases with the span of SOC and temperature during cycling. Capacity fade was caused by a combination of the loss of cycleable Li and degradation of the cathode. The room temperature anodes showed SEI compositions and degrees of graphite disorder that correlated with the extent of the Li consumption, which was linear in cell test time. TEM of the cathodes showed evidence of crystalline defects, though no major new phases were identified, consistent with XRD. No evidence of polymeric deposits on the cathode particles (FTIR) was detected although both Raman and TEM showed evidence of P-containing deposits from electrolyte salt degradation. Raman microscopy showed differences in relative carbon contents of the cycled cathodes, which is blamed for part of the cathode degradation.

Striebel, K.A.; Shim, J.; Kostecki, R.; Richardson, T.J.; Ross, P.N.; Song, X.; Zhuang, G.V.

2003-11-25T23:59:59.000Z

51

Design and modeling of cylindrical and falt-wound lithium-ion cells for the PNGV application.  

DOE Green Energy (OSTI)

In this study, 10-Ah cylindrical and flat-wound cells were designed and studied for use in batteries for the Partnership for a New Generation of Vehicles (PNGV). A low-cost current collection system was devised that results in a low resistance. Heat rejection from flat cells is much better than that from cylindrical cells and is an important safety factor. Very compact, powerful batteries of about 1.5 kW/L can be designed with wound lithium-ion cells.

Nelson, P. A.; Henriksen, G. L.; Amine, K.

2000-11-10T23:59:59.000Z

52

Differential voltage analyses of high-power lithium-ion cells 4. Cells containing NMC.  

DOE Green Energy (OSTI)

Cells with and without a LiC{sub 2}O{sub 4}BF{sub 2} electrolyte additive and that contained Li{sub 1.05}(Mn{sub 1/3}Co{sub 1/3}Ni{sub 1/3}){sub 0.95}O{sub 2} (NMC) positive electrodes were tested for calendar and cycle life at 60% state of charge. The temperatures used in these tests were 25 and 45 C (cycle life) and 45 and 55 C (calendar life). An analysis of the C/25 capacity data shows that the C/25 capacity decreases with the square root of time. The additive slowed down the rate of capacity decline. The C/25 data were subjected to differential voltage analysis to determine the possible cause of the capacity decrease and at which electrode the capacity decrease was occurring. Data from full cells and half-cells were compared to elucidate individual electrode contributions. This analysis indicated that lithium-capacity-consuming side reactions were occurring primarily at the negative electrode.

Bloom, I.; Walker, L. K.; Basco, J. K.; Abraham, D. P.; Christophersen, J. P.; Ho, C. D.; Chemical Sciences and Engineering Division; INL

2010-02-01T23:59:59.000Z

53

Computational, electrochemical and {sup 7}Li NMR studies of lithiated disordered carbons electrodes in lithium ion cells.  

DOE Green Energy (OSTI)

Disordered carbons that deliver high reversible capacity in electrochemical cells have been synthesized by using inorganic clays as templates to control the pore size and the surface area. The capacities obtained were much higher than those calculated if the resultant carbon had a graphitic-like structure. Computational chemistry was used to investigate the nature of lithium bonding in a carbon lattice unlike graphite. The lithium intercalated fullerene Li{sub n}-C{sub 60} was used as a model for our (non-graphitic) disordered carbon lattice. A dilithium-C{sub 60} system with a charge and multiplicity of (0,1) and a trilithium-C{sub 60} system with a charge and multiplicity of (0,4) were investigated. The spatial distribution of lithium ions in an electrochemical cell containing this novel disordered carbon material was investigated in situ by Li-7 NMR using an electrochemical cell that was incorporated into a toroid cavity nuclear magnetic resonance (NMR) imager. The concentration of solvated Li{sup +} ions in the carbon anode appears to be larger than in the bulk electrolyte, is substantially lower near the copper/carbon interface, and does not change with cell charging.

Sandi, G.; Gerald, R., II; Scanlon, L. G.; Carrado, K. A.; Winans, R. E.

1998-01-07T23:59:59.000Z

54

Lithium metal oxide electrodes for lithium cells and batteries  

DOE Patents (OSTI)

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0ion with at least one ion being Mn or Ni, and where M' is one or more tetravalent ion. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

2004-01-13T23:59:59.000Z

55

Lithium ion conducting electrolytes  

DOE Patents (OSTI)

The present invention relates generally to highly conductive alkali-metal ion non-crystalline electrolyte systems, and more particularly to novel and unique molten (liquid), rubbery, and solid electrolyte systems which are especially well suited for use with high current density electrolytic cells such as primary and secondary batteries.

Angell, Charles Austen (Mesa, AZ); Liu, Changle (Midland, MI); Xu, Kang (Montgomery Village, MD); Skotheim, Terje A. (Tucson, AZ)

1999-01-01T23:59:59.000Z

56

Evaluation Study for Large Prismatic Lithium-Ion Cell Designs Using Multi-Scale Multi-Dimensional Battery Model (Presentation)  

Science Conference Proceedings (OSTI)

Addresses battery requirements for electric vehicles using a model that evaluates physical-chemical processes in lithium-ion batteries, from atomic variations to vehicle interface controls.

Kim, G. H.; Smith, K.

2009-05-01T23:59:59.000Z

57

Electrothermal Analysis of Lithium Ion Batteries  

DOE Green Energy (OSTI)

This report presents the electrothermal analysis and testing of lithium ion battery performance. The objectives of this report are to: (1) develop an electrothermal process/model for predicting thermal performance of real battery cells and modules; and (2) use the electrothermal model to evaluate various designs to improve battery thermal performance.

Pesaran, A.; Vlahinos, A.; Bharathan, D.; Duong, T.

2006-03-01T23:59:59.000Z

58

Graphene Fabrication and Lithium Ion Batteries Applications  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, 2013 TMS Annual Meeting & Exhibition. Symposium , Nanostructured Materials for Lithium Ion Batteries and for Supercapacitors.

59

Solid Lithium Ion Conducting Electrolytes Suitable for ...  

Batteries with solid lithium ion conducting electrolytes would ... The invention is cost-effective and suitable for manufacturing solid electrolyte ...

60

Batteries - Beyond Lithium Ion Breakout session  

NLE Websites -- All DOE Office Websites (Extended Search)

BEYOND LITHIUM ION BREAKOUT BEYOND LITHIUM ION BREAKOUT Breakout Session #1 - Discussion of Performance Targets and Barriers Comments on the Achievability of the Targets * 1 - Zn-Air possible either w/ or w/o electric-hybridization; also possible with a solid electrolyte variant * 2 - Multivalent systems (e.g Mg), potentially needing hybrid-battery * 3 - Advanced Li-ion with hybridization @ cell / molecular level for high-energy and high- power * 4 - MH-air, Li-air, Li-S, all show promise * 5 - High-energy density (e.g. Na-metal ) flow battery can meet power and energy goals * 6 - Solid-state batteries (all types) * 7 - New cathode chemistries (beyond S) to increase voltage * 8 - New high-voltage non-flammable electrolytes (both li-ion and beyond li-ion) * 9 - Power to energy ratio of >=12 needed for fast charge (10 min)  So liquid refill capable

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

UNDERSTANDING DEGRADATION AND LITHIUM DIFFUSION IN LITHIUM ION BATTERY ELECTRODES.  

E-Print Network (OSTI)

??Lithium-ion batteries with higher capacity and longer cycle life than that available today are required as secondary energy sources for a wide range of emerging… (more)

Li, Juchuan

2012-01-01T23:59:59.000Z

62

Lithium ion conducting electrolytes  

DOE Patents (OSTI)

A liquid, predominantly lithium-conducting, ionic electrolyte having exceptionally high conductivity at temperatures of 100.degree. C. or lower, including room temperature, and comprising the lithium salts selected from the group consisting of the thiocyanate, iodide, bromide, chloride, perchlorate, acetate, tetrafluoroborate, perfluoromethane sulfonate, perfluoromethane sulfonamide, tetrahaloaluminate, and heptahaloaluminate salts of lithium, with or without a magnesium-salt selected from the group consisting of the perchlorate and acetate salts of magnesium. Certain of the latter embodiments may also contain molecular additives from the group of acetonitrile (CH.sub.3 CN) succinnonitrile (CH.sub.2 CN).sub.2, and tetraglyme (CH.sub.3 --O--CH.sub.2 --CH.sub.2 --O--).sub.2 (or like solvents) solvated to a Mg.sup.+2 cation to lower the freezing point of the electrolyte below room temperature. Other particularly useful embodiments contain up to about 40, but preferably not more than about 25, mol percent of a long chain polyether polymer dissolved in the lithium salts to provide an elastic or rubbery solid electrolyte of high ambient temperature conductivity and exceptional 100.degree. C. conductivity. Another embodiment contains up to about but not more than 10 mol percent of a molecular solvent such as acetone.

Angell, C. Austen (Tempe, AZ); Liu, Changle (Tempe, AZ)

1996-01-01T23:59:59.000Z

63

Characterization of high-power lithium-ion cells during constant current cycling. Part I. Cycle performance and electrochemical diagnostics  

DOE Green Energy (OSTI)

Twelve-cm{sup 2} pouch type lithium-ion cells were assembled with graphite anodes, LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} cathodes and 1M LiPF{sub 6}/EC/DEC electrolyte. These pouch cells were cycled at different depths of discharge (100 percent and 70 percent DOD) at room temperature to investigate cycle performance and pulse power capability. The capacity loss and power fade of the cells cycled over 100 percent DOD was significantly faster than the cell cycled over 70 percent DOD. The overall cell impedance increased with cycling, although the ohmic resistance from the electrolyte was almost constant. From electrochemical analysis of each electrode after cycling, structural and/or impedance changes in the cathode are responsible for most of the capacity and power fade, not the consumption of cycleable Li from side-reactions.

Shim, Joongpyo; Striebel, Kathryn A.

2003-01-24T23:59:59.000Z

64

Design Principles for the Use of Electroactive Polymers for Overcharge Protection of Lithium-Ion Batteries  

E-Print Network (OSTI)

environment of the lithium- ion battery. The model, in bothlithium-ion batteries. The model shows how the cell is transformed upon overcharge from a battery

Thomas-Alyea, Karen E.; Newman, John; Chen, Guoying; Richardson, Thomas J.

2005-01-01T23:59:59.000Z

65

Gel electrolyte for lithium-ion batteries.  

DOE Green Energy (OSTI)

The electrochemical performance of gel electrolytes based on crosslinked poly[ethyleneoxide-co-2-(2-methoxyethyoxy)ethyl glycidyl ether-co-allyl glycidyl ether] was investigated using graphite/Li{sub 1.1}[Ni{sub 1/3}Mn{sub 1/3}Co{sub 1/3}]{sub 0.9}O{sub 2} lithium-ion cells. It was found that the conductivity of the crosslinked gel electrolytes was as high as 5.9 mS/cm at room temperature, which is very similar to that of the conventional organic carbonate liquid electrolytes. Moreover, the capacity retention of lithium-ion cells comprising gel electrolytes was also similar to that of cells with conventional electrolytes. Despite of the high conductivity of the gel electrolytes, the rate capability of lithium-ion cells comprising gel electrolytes is inferior to that of the conventional cells. The difference was believed to be caused by the poor wettability of gel electrolytes on the electrode surfaces.

Chen, Z.; Zhang, L. Z.; West, R.; Amine, K.; Chemical Sciences and Engineering Division; Univ. of Wisconsin-Madison

2008-03-10T23:59:59.000Z

66

Lithium K(1s) synchrotron NEXAFS spectra of lithium-ion battery...  

NLE Websites -- All DOE Office Websites (Extended Search)

Lithium K(1s) synchrotron NEXAFS spectra of lithium-ion battery cathode, anode and electrolyte materials Title Lithium K(1s) synchrotron NEXAFS spectra of lithium-ion battery...

67

Development of a constitutive model predicting the point of short-circuit within lithium-ion battery cells  

E-Print Network (OSTI)

The use of Lithium Ion batteries continues to grow in electronic devices, the automotive industry in hybrid and electric vehicles, as well as marine applications. Such batteries are the current best for these applications ...

Campbell, John Earl, Jr

2012-01-01T23:59:59.000Z

68

Computer-Aided Optimization of Macroscopic Design Factors for Lithium-Ion Cell Performance and Life (Presentation)  

DOE Green Energy (OSTI)

Electric-drive vehicles enabled by power- and energy-dense batteries promise to improve vehicle efficiency and help reduce society's dependence on fossil fuels. Next generation plug-in hybrid vehicles and battery electric vehicles may also enable vehicles to be powered by electricity generated from clean, renewable resources; however, to increase the commercial viability of such vehicles, the cost, performance and life of the vehicles batteries must be further improved. This work illustrates a virtual design process to optimize the performance and life of large-format lithium ion batteries. Beginning with material-level kinetic and transport properties, the performance and life of multiple large-format cell designs are evaluated, demonstrating the impact of macroscopic design parameters such as foil thickness, tab location, and cell size and shape under various cycling conditions. Challenges for computer-aided engineering of large-format battery cells, such as competing requirements and objectives, are discussed.

Smith, K.; Kim, G. H.; Pesaran, A.

2010-04-01T23:59:59.000Z

69

Three-Dimensional Lithium-Ion Battery Model (Presentation)  

DOE Green Energy (OSTI)

Nonuniform battery physics can cause unexpected performance and life degradations in lithium-ion batteries; a three-dimensional cell performance model was developed by integrating an electrode-scale submodel using a multiscale modeling scheme.

Kim, G. H.; Smith, K.

2008-05-01T23:59:59.000Z

70

Intercalation-Induced Stress and Heat Generation within Single Lithium-Ion Battery Cathode Particles  

E-Print Network (OSTI)

Intercalation-Induced Stress and Heat Generation within Single Lithium-Ion Battery Cathode sur- faces in postmortem analysis of batteries.5-7 Stress generation results from lithium-ion, as will be discussed later. Heat transfer analyses of lithium-ion batteries have stemmed from work on full cells.10

Sastry, Ann Marie

71

Abstract--This paper describes experimental results aiming at analyzing lithium-ion batteries performances  

E-Print Network (OSTI)

Abstract--This paper describes experimental results aiming at analyzing lithium-ion batteries (SOH) of cells. Index Terms--Lithium-ion batteries, Aging, EIS, State Of Charge, State Of Health, Fuzzy Logic System. I. INTRODUCTION Lithium ion secondary batteries are now being used in wide applications

Paris-Sud XI, Université de

72

Advances in lithium-ion battery research and technology.  

Science Conference Proceedings (OSTI)

The lithium-ion battery market has undergone trememdous growth ever since Sony Corporation introduced the first commercial cell in 1990. In less than a decade, the field has become a front-runner in rechargeable battery technology. Sales of lithium-ion cells exceeded 400 million units in 1999, and the market is expected to exceed 1.1 billion units valued at more than $4 billion by 2005.

Abraham, D. P.; Chemical Engineering

2002-03-01T23:59:59.000Z

73

STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES  

E-Print Network (OSTI)

as cathode materials for lithium ion battery. ElectrochimicaCapacity, High Rate Lithium-Ion Battery Electrodes Utilizinghours. 1.4 Lithium Ion Batteries Lithium battery technology

Wilcox, James D.

2010-01-01T23:59:59.000Z

74

Transparent lithium-ion batteries , Sangmoo Jeongb  

E-Print Network (OSTI)

Transparent lithium-ion batteries Yuan Yanga , Sangmoo Jeongb , Liangbing Hua , Hui Wua , Seok Woo in capillaries. Adv Mater 8:245­247. 24. Kim DK, et al. (2008) Spinel LiMn2O4 nanorods as lithium ion battery voltage window. For example, LiCoO2 and graphite, the most common cathode and anode in Li-ion batteries

Cui, Yi

75

Lithium-Ion Batteries: Possible Materials Issues  

NLE Websites -- All DOE Office Websites (Extended Search)

Argonne, IL Abstract The transition to plug-in hybrid vehicles and possibly pure battery electric vehicles will depend on the successful development of lithium-ion batteries....

76

Lithium Metal Oxide Electrodes For Lithium Cells And Batteries  

DOE Patents (OSTI)

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0ion with an average trivalent oxidation state and with at least one ion being Mn or Ni, and where M' is one or more ion with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

2004-01-20T23:59:59.000Z

77

Lithium metal oxide electrodes for lithium cells and batteries  

DOE Patents (OSTI)

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2M'O.sub.3 in which 0ion with an average trivalent oxidation state and with at least one ion being Mn or Ni, and where M' is one or more ion with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Oakbrook, IL)

2008-12-23T23:59:59.000Z

78

Thermal Characteristic Analysis of Power Lithium-ion Battery System for Electric Vehicle  

Science Conference Proceedings (OSTI)

With the electric vehicles used lithium manganese lithium-ion power battery (LiMn2O4 power battery) as the research object, the paper researched on the parameter identification of battery cell, has built the finite element model of single cell and completed ... Keywords: Lithium-ion battery, Thermal characteristic analysis, Electric Vehicle

Wang Wenwei; Lin Cheng; Tang Peng; Zhou Chengjun

2012-07-01T23:59:59.000Z

79

Carbons for lithium ion cells prepared using sepiolite as an inorganic template.  

DOE Green Energy (OSTI)

Carbon anodes for Li ion cells have been prepared by the in situ polymerization of olefins such as propylene and ethylene in the channels of sepiolite clay mineral. Upon dissolution of the inorganic framework, a disordered carbon was obtained. The carbon was tested as anode in coin cells, yielding a reversible capacity of 633 mAh/g, 1.70 times higher than the capacity delivered by graphitic carbon, assuming 100% efficiency. The coulombic efficiency was higher than 90%.

Sandi, G.

1998-12-09T23:59:59.000Z

80

Modeling the Performance of Lithium-Ion Batteries and Capacitors...  

NLE Websites -- All DOE Office Websites (Extended Search)

Modeling the Performance of Lithium-Ion Batteries and Capacitors during Hybird Electric-Vehicle Operation Title Modeling the Performance of Lithium-Ion Batteries and Capacitors...

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Nanostructured Materials for Lithium Ion Batteries and for ...  

Science Conference Proceedings (OSTI)

Mar 6, 2013 ... Nanostructured Materials for Lithium Ion Batteries and for ... to control capacity loss and enhance energy efficiency of lithium-ion batteries.

82

Secretary Chu Celebrates Expansion of Lithium-Ion Battery Production...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Celebrates Expansion of Lithium-Ion Battery Production in North Carolina Secretary Chu Celebrates Expansion of Lithium-Ion Battery Production in North Carolina July 26, 2011 -...

83

Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage...  

NLE Websites -- All DOE Office Websites (Extended Search)

Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage (October 2012) Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage (October 2012) DOE's Energy Storage...

84

Nanocomposite Carbon/Tin Anodes for Lithium Ion Batteries  

Ceramic-Metal Composites for Electrodes of Lithium Ion Batteries, IB-2253; Lower Cost Lithium Ion Batteries from Aluminum Substituted Cathode ...

85

Available Technologies: Lower Cost Lithium Ion Batteries from ...  

Lower Cost Lithium Ion Batteries from ... Although lithium ion batteries are the most promising candidates for plug-in hybrid electric vehicles, the u ...

86

Performance and degradation evaluation of five different commercial lithium-ion cells  

DOE Green Energy (OSTI)

The initial performance of five different types of Li-ion rechargeable batteries, from Quallion Corp, UltraLife Battery and Toshiba, was measured and compared. Cell characterization included variable-rate constant-current cycling, various USDOE pulse-test protocols and full-spectrum electrochemical impedance spectroscopy. Changes in impedance and capacity were monitored during electrochemical cycling under various conditions, including constant-current cycling over 100 percent DOD at a range of temperature and pulse profile cycling over a very narrow range of DOD at room temperature. All cells were found to maintain more than 80 percent of their rated capacity for more than 400 constant current 100 percent DOD cycles. The power fade (or impedance rise) of the cells varied considerably. New methods for interpreting the pulse resistance data were evaluated for their usefulness in interpreting performance mechanism as a function of test protocol and cell design.

Striebel, Kathryn A.; Shim, Joongpyo

2004-04-20T23:59:59.000Z

87

Advanced technology development program for lithium-ion batteries : thermal abuse performance of 18650 Li-ion cells.  

SciTech Connect

Li-ion cells are being developed for high-power applications in hybrid electric vehicles currently being designed for the FreedomCAR (Freedom Cooperative Automotive Research) program. These cells offer superior performance in terms of power and energy density over current cell chemistries. Cells using this chemistry are the basis of battery systems for both gasoline and fuel cell based hybrids. However, the safety of these cells needs to be understood and improved for eventual widespread commercial application in hybrid electric vehicles. The thermal behavior of commercial and prototype cells has been measured under varying conditions of cell composition, age and state-of-charge (SOC). The thermal runaway behavior of full cells has been measured along with the thermal properties of the cell components. We have also measured gas generation and gas composition over the temperature range corresponding to the thermal runaway regime. These studies have allowed characterization of cell thermal abuse tolerance and an understanding of the mechanisms that result in cell thermal runaway.

Crafts, Chris C.; Doughty, Daniel Harvey; McBreen, James. (Bookhaven National Lab, Upton, NY); Roth, Emanuel Peter

2004-03-01T23:59:59.000Z

88

Low temperature hydrothermally synthesized nanocrystalline orthorhombic LiMnO2 cathode material for lithium-ion cells  

Science Conference Proceedings (OSTI)

Nanocrystalline orthorhombic LiMnO2 particles with an average particle size of about 35 nm in diameter were successfully synthesized by a hydrothermal process at 160-180 °C from trimanganese tetroxide (Mn3O4) prepared ... Keywords: hydrothermal process, lithium ion battery, nanocrystalline, orthorhombic LiMnO2, solvothermal process

Mengqiang Wu; Ai Chen; Rongqing Xu; Yue Li

2003-05-01T23:59:59.000Z

89

Surface-Modified Active Materials for Lithium Ion Battery Electrodes  

lithium ion battery electrodes that lowers binder cost without sacrificing performance and reliability.

90

Innovative copper-tin electrodes provide improved capacity and cycle life for lithium-ion batteries  

lithium-ion batteries have become the battery of choice for everything from cell phones to electric cars, but there is still much room for ...

91

Layered electrodes for lithium cells and batteries  

DOE Patents (OSTI)

Lithium metal oxide compounds of nominal formula Li.sub.2MO.sub.2, in which M represents two or more positively charged metal ions, selected predominantly and preferably from the first row of transition metals are disclosed herein. The Li.sub.2MO.sub.2 compounds have a layered-type structure, which can be used as positive electrodes for lithium electrochemical cells, or as a precursor for the in-situ electrochemical fabrication of LiMO.sub.2 electrodes. The Li.sub.2MO.sub.2 compounds of the invention may have additional functions in lithium cells, for example, as end-of-discharge indicators, or as negative electrodes for lithium cells.

Johnson, Christopher S. (Naperville, IL); Thackeray, Michael M. (Naperville, IL); Vaughey, John T. (Elmhurst, IL); Kahaian, Arthur J. (Chicago, IL); Kim, Jeom-Soo (Naperville, IL)

2008-04-15T23:59:59.000Z

92

Materials Processing for Lithium-Ion Batteries  

SciTech Connect

Extensive efforts have been undertaken to develop and optimize new materials for lithium-ion batteries to address power and energy demands of mobile electronics and electric vehicles. However, the introduction of large-format lithium-ion batteries is hampered by high cost, safety concerns, and deficiencies in energy density and calendar life. Advanced materials-processing techniques can contribute solutions to such issues. From that perspective, this work summarizes the materials-processing techniques used to fabricate the cathodes, anodes, and separators used in lithium-ion batteries.

Li, Jianlin [ORNL; Daniel, Claus [ORNL; Wood III, David L [ORNL

2010-01-01T23:59:59.000Z

93

Performance and Characterization of Lithium-Ion Type Polymer Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

Performance and Characterization of Lithium-Ion Type Polymer Batteries Performance and Characterization of Lithium-Ion Type Polymer Batteries Speaker(s): Myung D. Cho Date: January 18, 2002 - 12:00pm Location: Bldg. 90 Seminar Host/Point of Contact: Frank McLarnon A new process for the preparation of lithium-polymer batteries with crosslinked gel-polymer electrolyte will be introduced. The new process employs a thermal crosslinking method rather than cell lamination, and is termed "lithium ion type polymer battery (ITPB)". This thermal crosslinking process has many advantages over the standard lamination method, such as fusing the polymer into the electrodes and better adhesion between the electrolyte and electrodes. The new method results in improved high-temperature stability and a simpler process, as well as the improved

94

Nanostructured lithium nickel manganese oxides for lithium-ion batteries.  

DOE Green Energy (OSTI)

Nanostructured lithium nickel manganese oxides were investigated as advanced positive electrode materials for lithium-ion batteries designated to power plug-in hybrid electric vehicles and all-electric vehicles. The investigation included material characterization and electrochemical testing. In cell tests, the Li{sub 1.375}Ni{sub 0.25}Mn{sub 0.75}O{sub 2.4375} composition achieved high capacity (210 mAh g{sup -1}) at an elevated rate (230 mA g{sup -1}), which makes this material a promising candidate for high energy density Li-ion batteries, as does its being cobalt-free and uncoated. The material has spherical morphology with nanoprimary particles embedded in micrometer-sized secondary particles, possesses a multiphase character (spinel and layered), and exhibits a high packing density (over 2 g cm{sup -3}) that is essential for the design of high energy density positive electrodes. When combined with the Li{sub 4}Ti{sub 5}O{sub 12} stable anode, the cell showed a capacity of 225 mAh g{sup -1} at the C/3 rate (73 mA g{sup -1}) with no capacity fading for 200 cycles. Other chemical compositions, Li{sub (1+x)}Ni{sub 0.25}Mn{sub 0.75}O{sub (2.25+x/2)} (0.32 {le} x {le} 0.65), were also studied, and the relationships among their structural, morphological, and electrochemical properties are reported.

Deng, H.; Belharouak, I.; Cook, R. E.; Wu, H.; Sun, Y.-K.; Amine, K.; Hanyang Univ.

2010-02-25T23:59:59.000Z

95

Materials issues in lithium ion rechargeable battery technology  

DOE Green Energy (OSTI)

Lithium ion rechargeable batteries are predicted to replace Ni/Cd as the workhorse consumer battery. The pace of development of this battery system is determined in large part by the availability of materials and the understanding of interfacial reactions between materials. Lithium ion technology is based on the use of two lithium intercalating electrodes. Carbon is the most commonly used anode material, while the cathode materials of choice have been layered lithium metal chalcogenides (LiMX{sub 2}) and lithium spinel-type compounds. Electrolytes may be either organic liquids or polymers. Although the first practical use of graphite intercalation compounds as battery anodes was reported in 1981 for molten salt cells and in 1983 for ambient temperature systems, it was not until Sony Energytech announced a new lithium ion intercalating carbon anode in 1990, that interest peaked. The reason for this heightened interest is that these electrochemical cells have the high energy density, high voltage and light weight of metallic lithium, but without the disadvantages of dendrite formation on charge, improving their safety and cycle life.

Doughty, D.H.

1995-07-01T23:59:59.000Z

96

Synthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium-Ion Batteries  

E-Print Network (OSTI)

Synthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium** Department of Materials Science and Engineering, Stanford University, Stanford, California 94305, USA Lithium cells that use organic electrolytes. The equilibrium reaction potential of lithium titanium phosphate

Cui, Yi

97

Studies On Electrode Materials For Lithium-Ion Batteries.  

E-Print Network (OSTI)

??In the early 1970s, research carried out on rechargeable lithium batteries at the Exxon Laboratories in the US established that lithium ions can be intercalated… (more)

Palale, Suresh

2006-01-01T23:59:59.000Z

98

NANOTUBE COMPOSITE ANODE MATERIALS SUITABLE FOR LITHIUM ION ...  

The present invention provides a composite material suitable for use in an anode for a lithium ion battery, the composite material comprising a layer of a lithium ...

99

Lithium-Ion Batteries: Examining Material Demand and Recycling ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Use of vehicles with electric drive, which could reduce our oil dependence, will depend on lithium–ion batteries. But is there enough lithium?

100

Understanding Diffusion-Induced-Stresses in Lithium Ion Battery ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Lithium insertion and removal in lithium ion battery electrodes can result in large volume expansion and contraction which may cause fracture ...

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Lithium-ion batteries : an unexpected advance.  

DOE Green Energy (OSTI)

The discovery that the electronic conductivity of LiFePO{sub 4} can be increased by eight orders of magnitude may have a profound impact on the next generation of lithium-ion batteries.

Thackeray, M. M.; Chemical Engineering

2002-10-01T23:59:59.000Z

102

Carbon fiber paper cathodes for lithium ion batteries  

Science Conference Proceedings (OSTI)

A novel lithium ion battery cathode structure was produced which has the potential for excellent capacity retention and good thermal management. In these cathodes, the active cathode material (lithium iron phosphate) was carbon bonded to a thermally and electrically conductive carbon fiber paper (CFP) support. Electrochemical testing was performed on Swagelok cells consisting of CFP cathodes and lithium anodes. High specific energy, near-theoretical capacity, and good cycling performance were demonstrated for 0.11 mm and 0.37 mm thick CFP cathodes.

Kercher, Andrew K [ORNL; Kiggans, Jim [ORNL; Dudney, Nancy J [ORNL

2010-01-01T23:59:59.000Z

103

Real-time observation of lithium fibers growth inside a nanoscale lithium-ion battery  

E-Print Network (OSTI)

Real-time observation of lithium fibers growth inside a nanoscale lithium-ion battery Hessam August 2011; accepted 29 August 2011; published online 22 September 2011) Formation of lithium dendrite to observe the real-time nucleation and growth of the lithium fibers inside a nanoscale Li-ion battery. Our

Endres. William J.

104

Mechanical Properties of Lithium-Ion Battery Separator Materials  

E-Print Network (OSTI)

facing Li-ion batteries · Increase energy & power density · Decrease cost · Increase operating lifeMechanical Properties of Lithium-Ion Battery Separator Materials Patrick Sinko B.S. Materials and motivation ­ Why study lithium-ion batteries? ­ Lithium-ion battery fundamentals ­ Why study the mechanical

Petta, Jason

105

Passivation of Aluminum in Lithium-ion Battery Electrolytes with LiBOB  

E-Print Network (OSTI)

of Aluminum in Lithium-ion Battery Electrolytes with LiBOBin commercially available lithium-ion battery electrolytes,

Zhang, Xueyuan; Devine, Thomas M.

2008-01-01T23:59:59.000Z

106

Materials and Processing for Lithium-Ion batteries  

Science Conference Proceedings (OSTI)

Lithium ion battery technology is projected to be the leapfrog technology for the electrification of the drivetrain and to provide stationary storage solutions to enable the effective use of renewable energy sources. The technology is already in use for low-power applications such as consumer electronics and power tools. Extensive research and development has enhanced the technology to a stage where it seems very likely that safe and reliable lithium ion batteries will soon be on board hybrid electric and electric vehicles and connected to solar cells and windmills. However, safety of the technology is still a concern, service life is not yet sufficient, and costs are too high. This paper summarizes the state of the art of lithium ion battery technology for nonexperts. It lists materials and processing for batteries and summarizes the costs associated with them. This paper should foster an overall understanding of materials and processing and the need to overcome the remaining barriers for a successful market introduction.

Daniel, Claus [ORNL

2008-01-01T23:59:59.000Z

107

Lithium ion conducting ionic electrolytes  

DOE Patents (OSTI)

A liquid, predominantly lithium-conducting, ionic electrolyte is described which has exceptionally high conductivity at temperatures of 100.degree. C. or lower, including room temperature. It comprises molten lithium salts or salt mixtures in which a small amount of an anionic polymer lithium salt is dissolved to stabilize the liquid against recrystallization. Further, a liquid ionic electrolyte which has been rubberized by addition of an extra proportion of anionic polymer, and which has good chemical and electrochemical stability, is described. This presents an attractive alternative to conventional salt-in-polymer electrolytes which are not cationic conductors.

Angell, C. Austen (Mesa, AZ); Xu, Kang (Tempe, AZ); Liu, Changle (Tulsa, OK)

1996-01-01T23:59:59.000Z

108

Nanostructured lithium-aluminum alloy electrodes for lithium-ion batteries.  

DOE Green Energy (OSTI)

Electrodeposited aluminum films and template-synthesized aluminum nanorods are examined as negative electrodes for lithium-ion batteries. The lithium-aluminum alloying reaction is observed electrochemically with cyclic voltammetry and galvanostatic cycling in lithium half-cells. The electrodeposition reaction is shown to have high faradaic efficiency, and electrodeposited aluminum films reach theoretical capacity for the formation of LiAl (1 Ah/g). The performance of electrodeposited aluminum films is dependent on film thickness, with thicker films exhibiting better cycling behavior. The same trend is shown for electron-beam deposited aluminum films, suggesting that aluminum film thickness is the major determinant in electrochemical performance regardless of deposition technique. Synthesis of aluminum nanorod arrays on stainless steel substrates is demonstrated using electrodeposition into anodic aluminum oxide templates followed by template dissolution. Unlike nanostructures of other lithium-alloying materials, the electrochemical performance of these aluminum nanorod arrays is worse than that of bulk aluminum.

Hudak, Nicholas S.; Huber, Dale L.

2010-12-01T23:59:59.000Z

109

Materials Challenges and Opportunities of Lithium Ion Battery ...  

Science Conference Proceedings (OSTI)

... Lithium ion batteries have revolutionized the portable electronics market, ... Cost, safety, and energy and power densities are some of the major issues in ... Analysis of Cycling Induced Fatigue in Electrode Materials for Lithium Ion Batteries.

110

High Rate Performing lithium-ion Batteries - Programmaster.org  

Science Conference Proceedings (OSTI)

Symposium, Nanostructured Materials for Rechargeable Batteries and for Supercapacitors, II. Presentation Title, High Rate Performing lithium-ion Batteries.

111

Ceramic-Metal Composites for Electrodes of Lithium Ion ...  

Ceramic-Metal Composites for Electrodes of Lithium Ion Batteries ... Applications and Industries. Anodes for primary and secondary (rechargeable) ...

112

Lower Cost Lithium Ion Batteries From Aluminum Substituted ...  

Lower Cost Lithium Ion Batteries From Aluminum Substituted Cathode Materials Lawrence Berkeley National Laboratory. Contact LBL About This Technology

113

Multilayer Graphene-Silicon Structures for Lithium Ion Battery ...  

Automotive industry: electric vehicles, hybrid electric vehicles; High performance lithium ion battery manufacturers; Aerospace industry, for lightweight power storage;

114

Non-Cross-Linked Gel Polymer Electrolytes for Lithium Ion ...  

Rechargeable lithium ion batteries for cellular phones, laptop computers and other consumer electronics; Batteries for electrically-powered vehicles;

115

Characterization of the passivation layer on disordered carbons in lithium-ion cells  

DOE Green Energy (OSTI)

Intercalation anodes of graphite or disordered carbon in rechargeable Li-ion batteries (based on aprotic organic solvents) develop a passivating film during the first intercalation of Li{sup +}. The formation of this film reduces the cycling efficiency and results in excessive consumption of Li{sup +}. The exact nature of this film is not well defined, although there are many similarities in properties to the films that form on Li anodes under similar cycling conditions. In this study we report on characterization studies of films formed during galvanostatic cycling of disordered carbons derived from polymethylacryolintrile (PMAN) in a 1M LiPF{sub 6} solution in ethylene carbonateldimethyl carbonate solution (1:1 by vol.). Complementary tests were also conducted with glass carbon, where intercalation cannot occur. Complex-impedance spectroscopy was the primary measurement technique, supplemented by cyclic voltammetry.

Guidotti, R.; Johnson, B.

1995-12-01T23:59:59.000Z

116

Effect of anode film resistance on the charge/discharge capacity of a lithium-ion battery  

DOE Green Energy (OSTI)

Lithium-ion batteries are prone to failure, because both their capacity and rate capability decrease with cycling. Side reactions, which decrease the cell's cyclable lithium content, can be responsible for capacity fade. An increase in cyclable lithium content is also possible, but is limited by the initial overall lithium content. Formation of a solid electrolyte interphase film on the carbonaceous anode not only consumes cyclable lithium, but also increases the anode resistance, thus reducing the rate capability of the cell, as demonstrated via computer simulation of a lithium-ion cell. Simulations also suggest that the use of cutoff potentials may not effectively prevent undesired irreversible side reactions on overcharge or overdischarge.

Christensen, J.; Newman, J.

2003-04-10T23:59:59.000Z

117

The Inside Story of the Lithium Ion Battery  

E-Print Network (OSTI)

The Inside Story of the Lithium Ion Battery John Dunning, Research Scholar in Residence Daniel. #12;Separator Cathode:Anode: e-e- Li++e-+C6LiC6 Li+ Lithium-ion battery e- Binder Conductive additives with charging and discharging a lithium ion battery · Research available devices · Test device to verify

Sze, Lawrence

118

Virus-Enabled Silicon Anode for Lithium-Ion Batteries  

E-Print Network (OSTI)

Virus-Enabled Silicon Anode for Lithium-Ion Batteries Xilin Chen, Konstantinos Gerasopoulos emerged as one of the most promising next-generation anode materials for lithium-ion batteries due to its with remarkable cycling stability. KEYWORDS: silicon anode · lithium-ion battery · Tobacco mosaic virus · physical

Ghodssi, Reza

119

Microstructural Modeling and Design of Rechargeable Lithium-Ion Batteries  

E-Print Network (OSTI)

. The cathode architectures and materials have a large influence on the performance of lithium-ion batteries battery design. The cathode of a lithium-ion battery is a large contributor to its overall performance power density and energy density of lithium-ion batteries. 1.3 Basic Ideal Cathode Structure

García, R. Edwin

120

Solid lithium ion conducting electrolytes and methods of preparation  

SciTech Connect

A composition comprised of nanoparticles of lithium ion conducting solid oxide material, wherein the solid oxide material is comprised of lithium ions, and at least one type of metal ion selected from pentavalent metal ions and trivalent lanthanide metal ions. Solution methods useful for synthesizing these solid oxide materials, as well as precursor solutions and components thereof, are also described. The solid oxide materials are incorporated as electrolytes into lithium ion batteries.

Narula, Chaitanya K; Daniel, Claus

2013-05-28T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide (LiHMDS)  

E-Print Network (OSTI)

Lithium Ion Solvation: Amine and Unsaturated Hydrocarbon Solvates of Lithium Hexamethyldisilazide, and 13C NMR spectroscopic studies of 6Li-15N labeled lithium hexamethyldisilazide ([6Li,15N]- Li ligand structure and lithium amide aggregation state is a complex and sensitive function of amine alkyl

Collum, David B.

122

Solid Electrolyte Developed for Safer Lithium-Ion Batteries  

Science Conference Proceedings (OSTI)

Feb 19, 2013 ... Today's lithium-ion batteries rely on a liquid electrolyte to conduct ions between the negatively charged anode and positive cathode.

123

Observation of Lithium Ions at Atomic Resolution Using an ...  

Science Conference Proceedings (OSTI)

Presentation Title, Observation of Lithium Ions at Atomic Resolution Using an ... at atomic resolution in several important electrode materials for Li-ion batteries.

124

NREL Evaluates Secondary Uses for Lithium Ion Vehicle Batteries  

NREL Evaluates Secondary Uses for Lithium Ion Vehicle Batteries ... of PHEVs and EVs is limited by the current high cost of Li-ion batteries.

125

Chemical overcharge protection of lithium and lithium-ion secondary batteries  

DOE Patents (OSTI)

This invention features the use of redox reagents, dissolved in non-aqueous electrolytes, to provide overcharge protection for cells having lithium metal or lithium-ion negative electrodes (anodes). In particular, the invention features the use of a class of compounds consisting of thianthrene and its derivatives as redox shuttle reagents to provide overcharge protection. Specific examples of this invention are thianthrene and 2,7-diacetyl thianthrene. One example of a rechargeable battery in which 2,7-diacetyl thianthrene is used has carbon negative electrode (anode) and spinet LiMn{sub 2}O{sub 4} positive electrode (cathode). 8 figs.

Abraham, K.M.; Rohan, J.F.; Foo, C.C.; Pasquariello, D.M.

1999-01-12T23:59:59.000Z

126

Chemical overcharge protection of lithium and lithium-ion secondary batteries  

DOE Patents (OSTI)

This invention features the use of redox reagents, dissolved in non-aqueous electrolytes, to provide overcharge protection for cells having lithium metal or lithium-ion negative electrodes (anodes). In particular, the invention features the use of a class of compounds consisting of thianthrene and its derivatives as redox shuttle reagents to provide overcharge protection. Specific examples of this invention are thianthrene and 2,7-diacetyl thianthrene. One example of a rechargeable battery in which 2,7-diacetyl thianthrene is used has carbon negative electrode (anode) and spinet LiMn.sub.2 O.sub.4 positive electrode (cathode).

Abraham, Kuzhikalail M. (Needham, MA); Rohan, James F. (Cork City, IE); Foo, Conrad C. (Dedham, MA); Pasquariello, David M. (Pawtucket, RI)

1999-01-01T23:59:59.000Z

127

Lithium-ion Energy Storage Market Opportunities  

Science Conference Proceedings (OSTI)

Lithium-ion (Li-ion) batteries have garnered major investment in R&D and manufacturing as the initial chemistry of choice for the electric transportation industry. This report presents granular cost/benefit analysis for Li-ion based energy storage systems for utility and customer-side of the meter stationary applications. Li-ion batteries have desirable performance characteristics with the potential for kW- and MW-scale systems with flexible functionality to address multiple benefit streams from a single...

2010-12-31T23:59:59.000Z

128

The Influence of High-Energy Lithium Ion Irradiation on Electrical Characteristics of Silicon and GaAs Solar Cells  

E-Print Network (OSTI)

Space-grade Si and GaAs solar cells were irradiated with 15 & 40 MeV Li ions. Illuminated (AM0 condition) and unilluminated I-V curves reveal that the effect of high-energy Li ion irradiation has produced similar effects to that of proton irradiation. However, an additional, and different, defect mechanism is suggested to dominate in the heavier-ion results. Comparison is made with proton-irradiated solar-cell work and with non-ionizing energy-loss (NIEL) radiation-damage models.

B. Jayashree; Ramani; M. C. Radhakrishna; Anil Agrawal; Saif Ahmad Khan; A. Meulenberg

2006-10-20T23:59:59.000Z

129

Ab initio screening of lithium diffusion rates in transition metal oxide cathodes for lithium ion batteries  

E-Print Network (OSTI)

A screening metric for diffusion limitations in lithium ion battery cathodes is derived using transition state theory and common materials properties. The metric relies on net activation barrier for lithium diffusion. ...

Moore, Charles J. (Charles Jacob)

2012-01-01T23:59:59.000Z

130

Nanowire Lithium-Ion Battery  

Science Conference Proceedings (OSTI)

... workings of Li-ion batteries, they either lack the nanoscale spatial resolution commensurate with the morphology of the active battery materials and ...

2012-10-02T23:59:59.000Z

131

Material characterization of high-voltage lithium-ion battery models for crashworthiness analysis  

E-Print Network (OSTI)

A three-phased study of the material properties and post-impact behavior of prismatic pouch lithium-ion battery cells was conducted to refine computational finite element models and explore the mechanisms of thermal runaway ...

Meier, Joseph D. (Joseph David)

2013-01-01T23:59:59.000Z

132

Improving high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-based lithium-ion cells by modifiying the positive electrode with alumina  

E-Print Network (OSTI)

;1. Introduction For lithium-ion batteries to widely power plug-in hybrid electric and all-electric vehicles (PHEVs-cell degradation during extended cycling. a r t i c l e i n f o Article history: Received 7 December 2012 Received

Spila, Timothy P.

133

Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Secretary  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Secretary of Energy Poneman Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Secretary of Energy Poneman February 9, 2012 - 4:25pm Addthis Washington, D.C. - Today, U.S. Deputy Secretary of Energy Daniel Poneman toured Dow Kokam's new global battery research and development center, located in Lee's Summit, Missouri, outside of Kansas City, to highlight America's investments in cutting-edge energy innovations that are laying the building blocks for an American economy built to last. The R&D center aims to bring next-generation lithium-ion battery solutions to the market faster, increase battery performance and reduce their overall cost. Lithium batteries are used in a variety of everyday products from laptops to cell

134

Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Secretary  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Secretary of Energy Poneman Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Secretary of Energy Poneman February 9, 2012 - 4:25pm Addthis Washington, D.C. - Today, U.S. Deputy Secretary of Energy Daniel Poneman toured Dow Kokam's new global battery research and development center, located in Lee's Summit, Missouri, outside of Kansas City, to highlight America's investments in cutting-edge energy innovations that are laying the building blocks for an American economy built to last. The R&D center aims to bring next-generation lithium-ion battery solutions to the market faster, increase battery performance and reduce their overall cost. Lithium batteries are used in a variety of everyday products from laptops to cell

135

Evaluation of commercial lithium-ion cells based on composite positive electrode for plug-in hybrid electric vehicle applications. Part I: Initial characterizations  

Science Conference Proceedings (OSTI)

Evaluating commercial Li-ion batteries presents some unique benefits. One of them is to use cells made from established fabrication process and form factor, such as those offered by the 18650 cylindrical configuration, to provide a common platform to investigate and understand performance deficiency and aging mechanism of target chemistry. Such an approach shall afford us to derive relevant information without influence from processing or form factor variability that may skew our understanding on cell-level issues. A series of 1.9 Ah 18650 lithium ion cells developed by a commercial source using a composite positive electrode comprising (LiMn1/3Ni1/3Co1/3O2 + LiMn2O4) is being used as a platform for the investigation of certain key issues, particularly path-dependent aging and degradation in future plug-in hybrid electric vehicle (PHEV) applications, under the US Department of Energy's Applied Battery Research (ABR) program. Here we report in Part I the initial characterizations of the cell performance and Part II some aspects of cell degradation in 2C cycle aging. The initial characterizations, including cell-to-cell variability, are essential for life cycle performance characterization in the second part of the report when cell-aging phenomena are discussed. Due to the composite nature of the positive electrode, the features (or signature) derived from the incremental capacity (IC) of the cell appear rather complex. In this work, the method to index the observed IC peaks is discussed. Being able to index the IC signature in details is critical for analyzing and identifying degradation mechanism later in the cycle aging study.

Matthieu Dubarry; Cyril Truchot; Mikael Cugnet; Bor Yann Liaw; Kevin Gering; Sergiy Sazhin; David Jamison; Christopher Michelbacher

2011-12-01T23:59:59.000Z

136

Electrode Materials for Rechargeable Lithium-Ion Batteries: A...  

NLE Websites -- All DOE Office Websites (Extended Search)

Electrode Materials for Rechargeable Lithium-Ion Batteries: A New Synthetic Approach Technology available for licensing: New high-energy cathode materials for use in rechargeable...

137

Novel Redox Shuttles for Overcharge Protection of Lithium-Ion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Novel Redox Shuttles for Overcharge Protection of Lithium-Ion Batteries Technology available for licensing: Electrolytes containing novel redox shuttles (electron transporters) for...

138

Surface Modification Agents for Lithium-Ion Batteries | Argonne...  

NLE Websites -- All DOE Office Websites (Extended Search)

Surface Modification Agents for Lithium-Ion Batteries Technology available for licensing: A process to modify the surface of the active material used in an electrochemical device...

139

Novel Redox Shuttles for Overcharge Protection of Lithium-Ion ...  

Increases the safety of lithium-ion batteries; ... Electric and plug-in hybrid electric vehicles; Portable electronic devices; Medical devices; and

140

CUBICON Materials that Outperform Lithium-Ion Batteries  

and high-energy system applications has resulted in substantial research and development activities. Lithium-ion batteries are a chief contender ...

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

High Capacity Lithium-Ion Battery Characterization for Vehicular Applications.  

E-Print Network (OSTI)

?? A lithium-ion battery is one of the key research topics in energy storage technologies. Major characterization tests such as static capacity, open circuit voltage… (more)

Ahmed, Sazzad Hossain

2012-01-01T23:59:59.000Z

142

Lithium-Ion Batteries: When Mechanics Meets Chemistry  

Science Conference Proceedings (OSTI)

Symposium, Fatigue and Fracture of Thin Films and Nanomaterials. Presentation Title, Lithium-Ion Batteries: When Mechanics Meets Chemistry. Author(s), Joost ...

143

Students race lithium ion battery powered cars in Pantex competition...  

National Nuclear Security Administration (NNSA)

skip to the main content Facebook Flickr RSS Twitter YouTube Students race lithium ion battery powered cars in Pantex competition | National Nuclear Security Administration Our...

144

Nanostructured Materials for Lithium Ion Batteries and for ...  

Science Conference Proceedings (OSTI)

Mar 5, 2013 ... Since lithium sources are concentrated in only few countries and sodium is available worldwide, there is interest to develop a Na-ion battery ...

145

Novel Electrolyte Enables Stable Graphite Anodes in Lithium Ion Batteries  

Berkeley Lab researchers led by Gao Liu have developed an improved lithium ion battery electrolyte containing a solvent that remains liquid at typical ...

146

Nanotube composite anode materials improve lithium-ion battery ...  

Rechargeable lithium-ion batteries are a critical technology for many applications, ... while simultaneously providing enhanced stability at a lower c ...

147

Advanced Lithium Ion Battery Materials for Fast Charging and ...  

Advanced Lithium Ion Battery Materials for Fast Charging and Improved Safety Technology Summary ... a great low cost substitute for cobalt, were

148

Surface-Modified Active Materials for Lithium Ion Battery ...  

Berkeley Lab researcher Gao Liu has developed a new fabrication technique for lithium ion battery electrodes that lowers binder cost without ...

149

Hybrid Aluminum-Lithium Ion Battery having Enhanced Power Density  

Hybrid Aluminum-Lithium Ion Battery having Enhanced Power Density Note: The technology described above is an early stage opportunity. Licensing rights to this ...

150

Nanostructured Anodes for Lithium-Ion Batteries - Energy ...  

New Anodes for Lithium-ion Batteries Increase Energy Density Four-Fold Savannah River Nuclear Solutions (SRNS), managing contractor of the Savannah River Site (SRS ...

151

Performance Characteristics of Lithium-ion Batteries of Various Chemistries for Plug-in Hybrid Vehicles  

E-Print Network (OSTI)

for vehicle applications. 2 Lithium-ion battery chemistriesThe lithium-ion battery technology used for consumerfrom EIG Figure 4: Lithium-ion battery modules for testing

Burke, Andrew; Miller, Marshall

2009-01-01T23:59:59.000Z

152

X-ray photoelectron spectroscopy of negative electrodes from high-power lithium-ion cells showing various levels of power fade  

DOE Green Energy (OSTI)

High-power lithium-ion cells for transportation applications are being developed and studied at Argonne National Laboratory. The current generation of cells containing LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2}-based cathodes, graphite-based anodes, and LiPF6-based electrolytes show loss of capacity and power during accelerated testing at elevated temperatures. Negative electrode samples harvested from some cells that showed varying degrees of power and capacity fade were examined by X-ray photoelectron spectroscopy (XPS). The samples exhibited a surface film on the graphite, which was thicker on samples from cells that showed higher fade. Furthermore, solvent-based compounds were dominant on samples from low power fade cells, whereas LiPF{sub 6}-based products were dominant on samples from high power fade cells. The effect of sample rinsing and air exposure is discussed. Mechanisms are proposed to explain the formation of compounds suggested by the XPS data.

Herstedt, Marie; Abraham, Daniel P.; Kerr, John B.

2004-02-28T23:59:59.000Z

153

Technical Specification for a Transportable Lithium-Ion Energy Storage System for Grid Support Using Commercially Available Lithium- Ion Technology  

Science Conference Proceedings (OSTI)

The impressive global scale of lithium-ion battery production and investment in R&D is driving cost reduction and performance improvements that could make lithium-ion technology desirable for certain grid-scale storage applications in the near term. Although many stationary grid market applications can be configured using lithium-ion batteries, Electric Power Research Institute (EPRI) research identified a 1-MW, 2-hour containerized substation grid support storage system as a key electric utility product...

2012-07-31T23:59:59.000Z

154

Ternary compound electrode for lithium cells  

DOE Patents (OSTI)

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350 to 500/sup 0/C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

Raistrick, I.D.; Godshall, N.A.; Huggins, R.A.

1980-07-30T23:59:59.000Z

155

Ternary compound electrode for lithium cells  

DOE Patents (OSTI)

Lithium-based cells are promising for applications such as electric vehicles and load-leveling for power plants since lithium is very electropositive and of light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated in the temperature range of about 350.degree.-500.degree. C. Such high temperature operation accelerates corrosion problems. The present invention provides an electrochemical cell in which lithium is the electroactive species. The cell has a positive electrode which includes a ternary compound generally represented as Li-M-O, wherein M is a transition metal. Corrosion of the inventive cell is considerably reduced.

Raistrick, Ian D. (Menlo Park, CA); Godshall, Ned A. (Stanford, CA); Huggins, Robert A. (Stanford, CA)

1982-01-01T23:59:59.000Z

156

Model for the Fabrication of Tailored Materials for Lithium-Ion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Model for the Fabrication of Tailored Materials for Lithium-Ion Batteries Technology available for licensing: Safe, stable and high-capacity cathodes for lithium-ion batteries...

157

Ion-exchanged MnO2 nanoparticles as cathodes of lithium ion ...  

Science Conference Proceedings (OSTI)

Presentation Title, Ion-exchanged MnO2 nanoparticles as cathodes of lithium ion batteries at elevated temperatures. Author(s), Dawei Liu, Jasper Wright, Wei ...

158

Lithium Ion Batteries: Materials Processing and Mechanical ...  

Science Conference Proceedings (OSTI)

Assessing Cast Alloys for Use in Advanced Ultra-supercritical Steam Turbines · Cathode/Anode Selection and Full Cell Performance for Stationary Li-ion Battery

159

Lithium-Ion Batteries - Energy Innovation Portal  

Understanding the impact of hot and cold domains on ion transport within the battery can lead to significant ... This model takes into account cell .. ...

160

Thin film method of conducting lithium-ions  

DOE Patents (OSTI)

The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li.sub.2 O--CeO.sub.2 --SiO.sub.2 system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications.

Zhang, Ji-Guang (Golden, CO); Benson, David K. (Golden, CO); Tracy, C. Edwin (Golden, CO)

1998-11-10T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Thin film method of conducting lithium-ions  

DOE Patents (OSTI)

The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li{sub 2}O-CeO{sub 2}-SiO{sub 2} system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications. 12 figs.

Zhang, J.G.; Benson, D.K.; Tracy, C.E.

1998-11-10T23:59:59.000Z

162

REACTIVE FLOW IN LARGE-DEFORMATION ELECTRODES OF LITHIUM-ION BATTERIES  

E-Print Network (OSTI)

8/3/2012 1 REACTIVE FLOW IN LARGE-DEFORMATION ELECTRODES OF LITHIUM-ION BATTERIES LAURENCE BRASSART;8/3/2012 2 1. Introduction In a lithium-ion battery, each electrode is a host of lithium. When the battery to 4.4 lithium atoms. By comparison, in the commonly used anodes in lithium-ion batteries made

Suo, Zhigang

163

Electrode for a lithium cell  

SciTech Connect

This invention relates to a positive electrode for an electrochemical cell or battery, and to an electrochemical cell or battery; the invention relates more specifically to a positive electrode for a non-aqueous lithium cell or battery when the electrode is used therein. The positive electrode includes a composite metal oxide containing AgV.sub.3O.sub.8 as one component and one or more other components consisting of LiV.sub.3O.sub.8, Ag.sub.2V.sub.4O.sub.11, MnO.sub.2, CF.sub.x, AgF or Ag.sub.2O to increase the energy density of the cell, optionally in the presence of silver powder and/or silver foil to assist in current collection at the electrode and to improve the power capability of the cell or battery.

Thackeray, Michael M. (Naperville, IL); Vaughey, John T. (Elmhurst, IL); Dees, Dennis W. (Downers Grove, IL)

2008-10-14T23:59:59.000Z

164

Lithium-Ion Battery Teacher Workshop  

NLE Websites -- All DOE Office Websites (Extended Search)

Lithium Ion Battery Teacher Workshop Lithium Ion Battery Teacher Workshop 2012 2 2 screw eyes 2 No. 14 rubber bands 2 alligator clips 1 plastic gear font 2 steel axles 4 nylon spacers 2 Pitsco GT-R Wheels 2 Pitsco GT-F Wheels 2 balsa wood sheets 1 No. 280 motor Also: Parts List 3 Tools Required 1. Soldering iron 2. Hobby knife or coping saw 3. Glue gun 4. Needlenose pliers 5. 2 C-clamps 6. Ruler 4 1. Using a No. 2 pencil, draw Line A down the center of a balsa sheet. Making the Chassis 5 2. Turn over the balsa sheet and draw Line B ¾ of an inch from one end of the sheet. Making the Chassis 6 3. Draw a 5/8" x ½" notch from 1" from the top of the sheet. Making the Chassis 7 4. Draw Line C 2 ½" from the other end of the same sheet of balsa. Making the Chassis 8 5. Using a sharp utility knife or a coping saw, cut

165

Better Lithium-Ion Batteries Are On The Way From Berkeley Lab  

NLE Websites -- All DOE Office Websites (Extended Search)

Lithium-Ion Batteries A Better Lithium-ion Battery on the Way Simulations Reveal How New Polymer Absorbs Eight Times the Lithium of Current Designs September 23, 2011 Paul Preuss,...

166

A Better Anode Design to Improve Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

A Better Anode Design to Improve A Better Anode Design to Improve Lithium-Ion Batteries A Better Anode Design to Improve Lithium-Ion Batteries Print Friday, 23 March 2012 13:53 Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds

167

1 Kinetics of Initial Lithiation of Crystalline Silicon Electrodes of 2 Lithium-Ion Batteries  

E-Print Network (OSTI)

1 Kinetics of Initial Lithiation of Crystalline Silicon Electrodes of 2 Lithium-Ion Batteries 3 the lithiated silicon phase. 20 KEYWORDS: Lithium-ion batteries, silicon, kinetics, plasticity 21 Lithium-ion by the National Science Foundation 648through a grant on Lithium-ion Batteries (CMMI-1031161). 649This work

Liu, X. Shirley

168

Stochastic model of lithium ion conduction in poly,,ethylene oxide... L. Gitelman,1  

E-Print Network (OSTI)

as described above. III. THE CONDUCTIVITY The basic electrochemistry of the lithium ion battery in- volves only the transfer of lithium ions between the two insertion electrodes. Typical lithium ion battery consistsStochastic model of lithium ion conduction in poly,,ethylene oxide... L. Gitelman,1 A. Averbuch,2,a

Averbuch, Amir

169

Recycling of Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

B. Dunn B. Dunn Center for Transportation Research Argonne National Laboratory Recycling of Lithium-Ion Batteries Plug-In 2013 San Diego, CA October 2, 2013 The submitted manuscript has been created by UChicago Argonne, LLC, Operator of Argonne National Laboratory ("Argonne"). Argonne, a U.S. Department of Energy Office of Science laboratory, is operated under Contract No. DE-AC02-06CH11357. The U.S. Government retains for itself, and others acting on its behalf, a paid-up nonexclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display publicly, by or on behalf of the Government.

170

Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage (October 2012)  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Pacific Northwest National Laboratory Pacific Northwest National Laboratory Current Li-Ion Battery Improved Li-Ion Battery Novel Synthesis New Electrode Candidates Coin Cell Test Stability and Safety Full Cell Fabrication and Optimization Lithium-ion (Li-ion) batteries offer high energy and power density, making them popular in a variety of mobile applications from cellular telephones to electric vehicles. Li-ion batteries operate by migrating positively charged lithium ions through an electrolyte from one electrode to another, which either stores or discharges energy, depending on the direction of the flow. They can employ several different chemistries, each offering distinct benefits and limitations. Despite their success in mobile applications, Li-ion technologies have not demonstrated

171

Layered Electrodes for Lithium Cells and Batteries | Argonne...  

NLE Websites -- All DOE Office Websites (Extended Search)

Layered Electrodes for Lithium Cells and Batteries Technology available for licensing: Layered lithium metal oxide compounds for ultra-high-capacity, rechargeable cathodes...

172

Students race lithium ion battery powered cars in Pantex competition |  

NLE Websites -- All DOE Office Websites (Extended Search)

race lithium ion battery powered cars in Pantex competition | race lithium ion battery powered cars in Pantex competition | National Nuclear Security Administration Our Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Continuing Management Reform Countering Nuclear Terrorism About Us Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Media Room Congressional Testimony Fact Sheets Newsletters Press Releases Speeches Events Social Media Video Gallery Photo Gallery NNSA Archive Federal Employment Apply for Our Jobs Our Jobs Working at NNSA Blog Home > NNSA Blog > Students race lithium ion battery powered cars ... Students race lithium ion battery powered cars in Pantex competition Posted By Greg Cunningham, Pantex Public Affairs

173

Composite Electrodes for Rechargeable Lithium-Ion Batteries ...  

NLE Websites -- All DOE Office Websites (Extended Search)

Composite Electrodes for Rechargeable Lithium-Ion Batteries Technology available for licensing: Electrodes having composite xLi2M'O3(1-x)LiMO2 structures in which an...

174

Performance and Characterization of Lithium-Ion Type Polymer...  

NLE Websites -- All DOE Office Websites (Extended Search)

Performance and Characterization of Lithium-Ion Type Polymer Batteries Speaker(s): Myung D. Cho Date: January 18, 2002 - 12:00pm Location: Bldg. 90 Seminar HostPoint of Contact:...

175

Design and Optimization of Lithium-ion Batteries for Vehicular...  

NLE Websites -- All DOE Office Websites (Extended Search)

Design and Optimization of Lithium-ion Batteries for Vehicular Applications Speaker(s): Venkat Srinivasan Date: September 16, 2003 - 12:00pm Location: Bldg. 90 Seminar HostPoint...

176

A Better Anode Design to Improve Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy....

177

Solid-state Inorganic Lithium-Ion Conductors  

A research team at the University of Colorado Boulder led by Se-Hee Lee has developed an advanced single step, high energy ball milling system for preparation of electrodes for use in a solid state lithium-ion battery.

178

NREL: News - Solar and Lithium Ion Car Race Winners Announced  

NLE Websites -- All DOE Office Websites (Extended Search)

913 Solar and Lithium Ion Car Race Winners Announced May 18, 2013 Ninety-seven teams from 28 Colorado schools participated in today's car competitions hosted by the U.S. Department...

179

Aluminum-doped lithium nickel cobalt oxide electrodes for high-power lithium-ion batteries.  

DOE Green Energy (OSTI)

Non-doped and aluminum-doped LiNi{sub 0.8}Co{sub 0.2}O{sub 2} cathodes from three industrial developers coupled with graphite anodes were made into lithium-ion cells for high-power applications. The powder morphology of the active cathode materials was examined by a scanning electron microscope. The electrochemical performance of these cells was investigated by hybrid pulse power characterization (HPPC) testing, accelerated aging, and AC impedance measurement of symmetric cells. Although all of the fresh cells are found to meet and exceed the power requirements set by PNGV, the power capability of those cells with non-doped LiNi {sub 0.8}Co{sub 0.2}O{sub 2} cathodes fades rapidly due to the rise of the cell impedance. Al-doping is found very effective to suppress the cell impedance rise by stabilizing the charge-transfer impedance on the cathode side. The stabilization mechanism may be related to the low average oxidation state of nickel ions in the cathode. The powder morphology also plays a secondary role in determining the impedance stabilization.

Chen, C. H.; Liu, J.; Stoll, M. E.; Henriksen, G.; Vissers, D. R.; Amine, K.; Chemical Engineering; Univ. of Science and Technology of China

2004-04-05T23:59:59.000Z

180

Lithium Ion Technology Status and Directions: 2013 Update  

Science Conference Proceedings (OSTI)

This report describes the state of the art in lithium ion battery technology with respect to the electric transportation and utility energy storage fields. Although lithium ion batteries have become widely accepted as the dominant energy storage technology to be used in electric vehicles, at least for the next decade, their improvement in terms of performance and cost will be an important factor in the adoption of electric vehicles.This report provides a brief review of the technical and ...

2013-12-27T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Redox shuttles for safer lithium-ion batteries.  

DOE Green Energy (OSTI)

Overcharge protection is not only critical for preventing the thermal runaway of lithium-ion batteries during operation, but also important for automatic capacity balancing during battery manufacturing and repair. A redox shuttle is an electrolyte additive that can be used as intrinsic overcharge protection mechanism to enhance the safety characteristics of lithium-ion batteries. The advances on stable redox shuttles are briefly reviewed. Fundamental studies for designing stable redox shuttles are also discussed.

Chen, Z.; Qin, Y.; Amine, K.; Chemical Sciences and Engineering Division

2009-10-01T23:59:59.000Z

182

Large-Format Lithium-Ion Battery Costs Analysis  

Science Conference Proceedings (OSTI)

The high cost of lithium ion batteries poses a serious problem for the competitiveness of Plug-In Hybrid Electric Vehicles (PHEVs) and Battery Electric Vehicles (BEVs). The problem is complicated by the fact that the lithium ion battery cost projections developed by a number of apparently credible organizations over the past 5 years or so differ so much that different conclusions regarding the economic competitiveness of PHEVs (and even more so BEVs) have been stated. This situation creates confusion and...

2010-12-15T23:59:59.000Z

183

Novel Cell Design for Combined In Situ Acoustic Emission and X-ray Diffraction of Cycling Lithium Ion Batteries  

SciTech Connect

An in situ acoustic emission (AE) and X-ray diffraction (XRD) cell for use in the study of battery electrode materials has been devised and tested. This cell uses commercially available coin cell hardware retrofitted with a metalized polyethylene terephthalate (PET) disk which acts as both an X-ray window and a current collector. In this manner the use of beryllium and its associated cost and hazard is avoided. An AE sensor may be affixed to the cell face opposite the PET window in order to monitor degradation effects, such as particle fracture, during cell cycling. Silicon particles which were previously studied by the AE technique were tested in this cell as a model material. The performance of these cells compared well with unmodified coin cells while providing information about structural changes in the active material as the cell is repeatedly charged and discharged.

Rhodes, Kevin J [ORNL; Kirkham, Melanie J [ORNL; Meisner, Roberta Ann [ORNL; Parish, Chad M [ORNL; Dudney, Nancy J [ORNL; Daniel, Claus [ORNL

2011-01-01T23:59:59.000Z

184

Modeling of Transport in Lithium Ion Battery Electrodes  

E-Print Network (OSTI)

Lithium ion battery systems are promising solutions to current energy storage needs due to their high operating voltage and capacity. Numerous efforts have been conducted to model these systems in order to aid the design process and avoid expensive and time consuming prototypical experiments. Of the numerous processes occurring in these systems, solid state transport in particular has drawn a large amount of attention from the research community, as it tends to be one of the rate limiting steps in lithium ion battery performance. Recent studies have additionally indicated that purposeful design of battery electrodes using 3D microstructures offers new freedoms in design, better use of available cell area, and increased battery performance. The following study is meant to serve as a first principles investigation into the behaviors of 3D electrode architectures by monitoring concentration and cycle behaviors under realistic operating conditions. This was accomplished using computational tools to model the solid state diffusion behavior in several generated electrode morphologies. Developed computational codes were used to generate targeted structures under prescribed conditions of particle shape, size, and overall morphology. The diffusion processes in these morphologies were simulated under conditions prescribed from literature. Primary results indicate that parameters usually employed to describe electrode geometry, such as volume to surface area ratio, cannot be solely relied upon to predict or characterize performance. Additionally, the interaction between particle shapes implies some design aspects that may be exploited to improve morphology behavior. Of major importance is the degree of particle isolation and overlap in 3D architectures, as these govern gradient development and lithium depletion within the electrode structures. The results of this study indicate that there are optimum levels of these parameters, and so purposeful design must make use of these behaviors.

Martin, Michael

2012-05-01T23:59:59.000Z

185

Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries...  

NLE Websites -- All DOE Office Websites (Extended Search)

Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries: Innovation and Optimization Speaker(s): Jordi Cabana-Jimenez Date: January 14, 2008 - 12:00pm Location: 90-3122...

186

The development and fabrication of miniaturized direct methanol fuel cells and thin-film lithium ion battery hybrid system for portable applications .  

E-Print Network (OSTI)

??In this work, a hybrid power module comprising of a direct methanol fuel cell (DMFC) and a Li-ion battery has been proposed for low power… (more)

Prakash, Shruti

2009-01-01T23:59:59.000Z

187

Nanostructured materials for lithium-ion batteries: Surface conductivity vs. bulk  

E-Print Network (OSTI)

Nanostructured materials for lithium-ion batteries: Surface conductivity vs. bulk ion cathode materials for high capacity lithium-ion batteries. Owing to their inherently low electronic in these materials is also to unravel the factors governing ion and electron transport within the lattice. Lithium de

Ryan, Dominic

188

Laser-Cooled Lithium Atoms: A New Source for Focused Ion Beams  

E-Print Network (OSTI)

Laser-Cooled Lithium Atoms: A New Source for Focused Ion Beams P R O J E C T L E A D E R : Jabez Mc E N T S Designed and constructed a laser-cooled, magneto-optical trap-based lithium ion source mounted on a commercial focused ion beam system, creating the world's first lithium ion microscope

Magee, Joseph W.

189

LITHIUM-ION BATTERY CHARGING REPORT G. MICHAEL BARRAMEDA  

E-Print Network (OSTI)

LITHIUM-ION BATTERY CHARGING REPORT G. MICHAEL BARRAMEDA 1. Abstract This report introduces how to handle the Powerizer Li-Ion rechargeable Battery Packs. It will bring reveal battery specifications the amount of "de-Rating" the batteries have experienced. 2. Safety Guidelines · Must put battery

Ruina, Andy L.

190

Atomic resolution of Lithium Ions in LiCoO  

SciTech Connect

LiCoO2 is the most common lithium storage material for lithium rechargeable batteries, used widely to power portable electronic devices such as laptop computers. Lithium arrangements in the CoO2 framework have a profound effect on the structural stability and electrochemical properties of LixCoO2 (0 < x < 1), however, probing lithium ions has been difficult using traditional X-ray and neutron diffraction techniques. Here we have succeeded in simultaneously resolving columns of cobalt, oxygen, and lithium atoms in layered LiCoO2 battery material using experimental focal series of LiCoO2 images obtained at sub-Angstrom resolution in a mid-voltage transmission electron microscope. Lithium atoms are the smallest and lightest metal atoms, and scatter electrons only very weakly. We believe our observations of lithium to be the first by electron microscopy, and that they show promise to direct visualization of the ordering of lithium and vacancy in LixCoO2.

Shao-Horn, Yang; Croguennec, Laurence; Delmas, Claude; Nelson, Chris; O' Keefe, Michael A.

2003-03-18T23:59:59.000Z

191

Modeling temperature distribution in cylindrical lithium ion batteries for use in electric vehicle cooling system design  

E-Print Network (OSTI)

Recent advancements in lithium ion battery technology have made BEV's a more feasible alternative. However, some safety concerns still exist. While the energy density of lithium ion batteries has all but made them the ...

Jasinski, Samuel Anthony

2008-01-01T23:59:59.000Z

192

Modeling and Simulation of Lithium-Ion Batteries from a Systems Engineering Perspective  

E-Print Network (OSTI)

The lithium-ion battery is an ideal candidate for a wide variety of applications due to its high energy/power density and operating voltage. Some limitations of existing lithium-ion battery technology include underutilization, ...

Braatz, Richard D.

193

Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Marketing Administration Other Agencies You are here Home Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy Secretary of Energy Poneman Missouri Lithium-Ion...

194

with Open Structure for Applications in High-Rate Lithium-ion Batteries  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, 2013 TMS Annual Meeting & Exhibition. Symposium , Nanostructured Materials for Lithium Ion Batteries and for Supercapacitors.

195

Silicon Anode Materials for All-Solid-State Lithium-ion Microbatteries  

Science Conference Proceedings (OSTI)

Symposium, Nanostructured Materials for Lithium Ion Batteries and for Supercapacitors. Presentation Title, Silicon Anode Materials for All-Solid-State ...

196

Negative Electrodes Improve Safety in Lithium Cells and Batteries...  

NLE Websites -- All DOE Office Websites (Extended Search)

Negative Electrodes Improve Safety in Lithium Cells and Batteries Technology available for licensing: Enhanced stability at a lower cost negativeelectrodes...

197

Lithium based electrochemical cell systems having a degassing agent  

SciTech Connect

A lithium based electrochemical cell system includes a positive electrode; a negative electrode; an electrolyte; and a degassing agent.

Hyung, Yoo-Eup (Naperville, IL); Vissers, Donald R. (Naperville, IL); Amine, Khalil (Downers Grove, IL)

2012-05-01T23:59:59.000Z

198

An Analytical Model for Predicting the Remaining Battery Capacity of Lithium-Ion Batteries  

E-Print Network (OSTI)

An Analytical Model for Predicting the Remaining Battery Capacity of Lithium-Ion Batteries Peng cycle-life tends to shrink significantly. The capacities of commercial lithium-ion batteries fade by 10 prediction model to estimate the remaining capacity of a Lithium-Ion battery. The proposed analytical model

Pedram, Massoud

199

Reduction of Model Order Based on Proper Orthogonal Decomposition for Lithium-Ion Battery Simulations  

E-Print Network (OSTI)

) by eliminating components such as the separator.3 Among commercially available batteries, lithium ion batteriesTunable Networks from Thiolene Chemistry for Lithium Ion Conduction Catherine N. Walker, Craig. This system provides a route to optimize lithium ion conduction and mechanical properties. Access

200

Diagnostic Characterization of High-Power Lithium-Ion Batteries For Use in Hybrid Electric Vehicles  

E-Print Network (OSTI)

Diagnostic Characterization of High-Power Lithium-Ion Batteries For Use in Hybrid Electric Vehicles Lithium-ion batteries are a fast-growing technology that is attractive for use in portable electronics of lithium-ion batteries for hybrid electric vehicle (HEV) applications. The ATD Program is a joint effort

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Large Plastic Deformation in High-Capacity Lithium-Ion Batteries Caused by Charge and Discharge  

E-Print Network (OSTI)

Large Plastic Deformation in High-Capacity Lithium-Ion Batteries Caused by Charge and Discharge, Massachusetts 02138 Evidence has accumulated recently that a high-capacity elec- trode of a lithium-ion battery in the particle is high, possibly leading to fracture and cavitation. I. Introduction LITHIUM-ION batteries

Suo, Zhigang

202

Diagnostic Characterization of High Power Lithium-Ion Batteries for Use in Hybrid Electric Vehicles  

E-Print Network (OSTI)

Diagnostic Characterization of High Power Lithium-Ion Batteries for Use in Hybrid Electric Vehicles. Manuscript submitted May 15, 2000; revised manuscript received January 15, 2001. Lithium-ion batteries effort by the U.S. Department of Energy to aid the development of lithium-ion batteries for hybrid

203

2012 Jonathan G. Lange IMPROVING LITHIUM-ION BATTERY POWER AND ENERGY DENSITIES USING  

E-Print Network (OSTI)

1 ©2012 Jonathan G. Lange #12;1 IMPROVING LITHIUM-ION BATTERY POWER AND ENERGY DENSITIES USING ABSTRACT Lithium-ion batteries are commonly used as energy storage devices in a variety of applications. The cathode architectures and materials have a large influence on the performance of lithium-ion batteries

Braun, Paul

204

Design of a Lithium-ion Battery Pack for PHEV Using a Hybrid Optimization Method  

E-Print Network (OSTI)

Design of a Lithium-ion Battery Pack for PHEV Using a Hybrid Optimization Method Nansi Xue1 Abstract This paper outlines a method for optimizing the design of a lithium-ion battery pack for hy- brid, volume or material cost. Keywords: Lithium-ion, Optimization, Hybrid vehicle, Battery pack design

Papalambros, Panos

205

Conflicting Roles Of Nickel In Controlling Cathode Performance In Lithium-ion Batteries  

SciTech Connect

A variety of approaches are being made to enhance the performance of lithium ion batteries. Incorporating multi-valence transition metal ions into metal oxide cathodes has been identified as an essential approach to achieve the necessary high voltage and high capacity. However, the fundamental mechanism that limits their power rate and cycling stability remains unclear. The power rate strongly depends on the lithium ion drift speed in the cathode. Crystallographically, these transition metal-based cathodes frequently have a layered structure. In the classic wisdom, it is accepted that lithium ion travels swiftly within the layers moving out/in of the cathode during the charge/discharge. Here, we report the unexpected discovery of a thermodynamically driven, yet kinetically controlled, surface modification in the widely explored lithium nickel manganese oxide cathode material, which may inhibit the battery charge/discharge rate. We found that during cathode synthesis and processing before electrochemical cycling in the cell nickel can preferentially move along the fast diffusion channels and selectively segregate at the surface facets terminated with a mix of anions and cations. This segregation essentially blocks the otherwise fast out/in pathways for lithium ions during the charge/discharge. Therefore, it appears that the transition metal dopant may help to provide high capacity and/or high voltage, but can be located in a “wrong” location that blocks or slows lithium diffusion, limiting battery performance. In this circumstance, limitations in the properties of Li-ion batteries using these cathode materials can be determined more by the materials synthesis issues than by the operation within the battery itself.

Gu, Meng; Belharouak, Ilias; Genc, Arda; Wang, Zhiguo; Wang, Dapeng; Amine, Khalil; Gao, Fei; Zhou, Guangwen; Thevuthasan, Suntharampillai; Baer, Donald R.; Zhang, Jiguang; Browning, Nigel D.; Liu, Jun; Wang, Chong M.

2012-09-17T23:59:59.000Z

206

The development of low cost LiFePO4-based high power lithium-ion batteries  

DOE Green Energy (OSTI)

The cycling performance of low-cost LiFePO4-based high-power lithium-ion cells was investigated and the components were analyzed after cycling to determine capacity fade mechanisms. Pouch type LiFePO4/natural graphite cells were assembled and evaluated by constant C/2 cycling, pulse-power and impedance measurements. From post-test electrochemical analysis after cycling, active materials, LiFePO4 and natural graphite, showed no degradation structurally or electrochemically. The main reasons for the capacity fade of cell were lithium inventory loss by side reaction and possible lithium deposition on the anode.

Shim, Joongpyo; Sierra, Azucena; Striebel, Kathryn A.

2003-11-25T23:59:59.000Z

207

Negative Electrodes Improve Safety in Lithium Cells and Batteries  

To help improve the stability and safety of lithium-ion batteries, Argonne researchers have developed a new intermetallic structure type that can be ...

208

Lithium ion batteries with titania/graphene anodes  

DOE Patents (OSTI)

Lithium ion batteries having an anode comprising at least one graphene layer in electrical communication with titania to form a nanocomposite material, a cathode comprising a lithium olivine structure, and an electrolyte. The graphene layer has a carbon to oxygen ratio of between 15 to 1 and 500 to 1 and a surface area of between 400 and 2630 m.sup.2/g. The nanocomposite material has a specific capacity at least twice that of a titania material without graphene material at a charge/discharge rate greater than about 10 C. The olivine structure of the cathode of the lithium ion battery of the present invention is LiMPO.sub.4 where M is selected from the group consisting of Fe, Mn, Co, Ni and combinations thereof.

Liu, Jun; Choi, Daiwon; Yang, Zhenguo; Wang, Donghai; Graff, Gordon L; Nie, Zimin; Viswanathan, Vilayanur V; Zhang, Jason; Xu, Wu; Kim, Jin Yong

2013-05-28T23:59:59.000Z

209

NANOWIRE CATHODE MATERIAL FOR LITHIUM-ION BATTERIES  

DOE Green Energy (OSTI)

Assuming the issues of nanowires removal can be solved, the technique does offer potential for creating high-power lithium-ion battery cathode needed for advanced EV and HEVs. Several technical advancements will still be required to meet this goal, and are likely topics for future SBIR feasibility studies.

John Olson, PhD

2004-07-21T23:59:59.000Z

210

Megawatt-Class Lithium Ion Energy Storage Systems  

Science Conference Proceedings (OSTI)

This project describes the most recent developments in the use of energy storage in frequency regulation and other ancillary service applications. This includes an analysis of limited storage in frequency regulation applications in the Pennsylvania-New Jersey-Maryland Interconnection (PJM), as well as a case study of a lithium ion energy storage system installed in California.

2009-12-22T23:59:59.000Z

211

Developments in lithium-ion battery technology in the Peoples Republic of China.  

SciTech Connect

Argonne National Laboratory prepared this report, under the sponsorship of the Office of Vehicle Technologies (OVT) of the U.S. Department of Energy's (DOE's) Office of Energy Efficiency and Renewable Energy, for the Vehicles Technologies Team. The information in the report is based on the author's visit to Beijing; Tianjin; and Shanghai, China, to meet with representatives from several organizations (listed in Appendix A) developing and manufacturing lithium-ion battery technology for cell phones and electronics, electric bikes, and electric and hybrid vehicle applications. The purpose of the visit was to assess the status of lithium-ion battery technology in China and to determine if lithium-ion batteries produced in China are available for benchmarking in the United States. With benchmarking, DOE and the U.S. battery development industry would be able to understand the status of the battery technology, which would enable the industry to formulate a long-term research and development program. This report also describes the state of lithium-ion battery technology in the United States, provides information on joint ventures, and includes information on government incentives and policies in the Peoples Republic of China (PRC).

Patil, P. G.; Energy Systems

2008-02-28T23:59:59.000Z

212

Developments in lithium-ion battery technology in the Peoples Republic of China.  

DOE Green Energy (OSTI)

Argonne National Laboratory prepared this report, under the sponsorship of the Office of Vehicle Technologies (OVT) of the U.S. Department of Energy's (DOE's) Office of Energy Efficiency and Renewable Energy, for the Vehicles Technologies Team. The information in the report is based on the author's visit to Beijing; Tianjin; and Shanghai, China, to meet with representatives from several organizations (listed in Appendix A) developing and manufacturing lithium-ion battery technology for cell phones and electronics, electric bikes, and electric and hybrid vehicle applications. The purpose of the visit was to assess the status of lithium-ion battery technology in China and to determine if lithium-ion batteries produced in China are available for benchmarking in the United States. With benchmarking, DOE and the U.S. battery development industry would be able to understand the status of the battery technology, which would enable the industry to formulate a long-term research and development program. This report also describes the state of lithium-ion battery technology in the United States, provides information on joint ventures, and includes information on government incentives and policies in the Peoples Republic of China (PRC).

Patil, P. G.; Energy Systems

2008-02-28T23:59:59.000Z

213

The development of low cost LiFePO4-based high power lithium-ion batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

development of low cost LiFePO4-based high power lithium-ion batteries development of low cost LiFePO4-based high power lithium-ion batteries Title The development of low cost LiFePO4-based high power lithium-ion batteries Publication Type Journal Article Year of Publication 2005 Authors Striebel, Kathryn A., Joongpyo Shim, Azucena Sierra, Hui Yang, Xiangyun Song, Robert Kostecki, and Kathryn N. McCarthy Journal Journal of Power Sources Volume 146 Pagination 33-38 Keywords libob, lifepo4, lithium-ion, post-test, raman spectroscopy Abstract Pouch type LiFePO4-natural graphite lithium-ion cells were cycled at constant current with periodic pulse-power testing in several different configurations. Components were analyzed after cycling with electrochemical, Raman and TEM techniques to determine capacity fade mechanisms. The cells with carbon-coated current collectors in the cathode and LiBOB-salt electrolyte showed the best performance stability. In many cases, iron species were detected on the anodes removed from cells with both TEM and Raman spectroscopy. The LiFePO4 electrodes showed unchanged capacity suggesting that the iron is migrating in small quantities and is acting as a catalyst to destabilize the anode SEI in these cells.

214

A Better Anode Design to Improve Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

A Better Anode Design to Improve Lithium-Ion Batteries Print A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds The anode achievement described in this highlight provides a rare scientific showcase, combining advanced tools of synthesis, characterization, and simulation in a novel approach to materials development. Gao Liu's original research team, part of Berkeley Lab's Environmental Energy Technologies Division (EETD), got the ball rolling by designing the original series of polyfluorene-based conducting polymers. Then, Wanli Yang of the ALS suggested soft x-ray absorption spectroscopy to determine their key electronic properties. To better understand these results, and their relevance to the conductivity of the polymer, the growing team sought a theoretical explanation from Lin-Wang Wang of Berkeley Lab's Materials Sciences Division (MSD). By conducting calculations on the promising polymers at Berkeley Lab's National Energy Research Scientific Computing Center (NERSC), the team gained insight into what was really happening in the PF with the carbonyl functional group, singling it out for further development.

215

A Better Anode Design to Improve Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

A Better Anode Design to Improve Lithium-Ion Batteries Print A Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds The anode achievement described in this highlight provides a rare scientific showcase, combining advanced tools of synthesis, characterization, and simulation in a novel approach to materials development. Gao Liu's original research team, part of Berkeley Lab's Environmental Energy Technologies Division (EETD), got the ball rolling by designing the original series of polyfluorene-based conducting polymers. Then, Wanli Yang of the ALS suggested soft x-ray absorption spectroscopy to determine their key electronic properties. To better understand these results, and their relevance to the conductivity of the polymer, the growing team sought a theoretical explanation from Lin-Wang Wang of Berkeley Lab's Materials Sciences Division (MSD). By conducting calculations on the promising polymers at Berkeley Lab's National Energy Research Scientific Computing Center (NERSC), the team gained insight into what was really happening in the PF with the carbonyl functional group, singling it out for further development.

216

A Better Anode Design to Improve Lithium-Ion Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

Better Anode Design to Improve Lithium-Ion Batteries Print Better Anode Design to Improve Lithium-Ion Batteries Print Lithium-ion batteries are in smart phones, laptops, most other consumer electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing energy. A team of Berkeley Lab scientists has designed a new kind of anode that absorbs eight times the lithium of current designs, and has maintained its greatly increased energy capacity after more than a year of testing and many hundreds of charge-discharge cycles. Cyclical Science Succeeds The anode achievement described in this highlight provides a rare scientific showcase, combining advanced tools of synthesis, characterization, and simulation in a novel approach to materials development. Gao Liu's original research team, part of Berkeley Lab's Environmental Energy Technologies Division (EETD), got the ball rolling by designing the original series of polyfluorene-based conducting polymers. Then, Wanli Yang of the ALS suggested soft x-ray absorption spectroscopy to determine their key electronic properties. To better understand these results, and their relevance to the conductivity of the polymer, the growing team sought a theoretical explanation from Lin-Wang Wang of Berkeley Lab's Materials Sciences Division (MSD). By conducting calculations on the promising polymers at Berkeley Lab's National Energy Research Scientific Computing Center (NERSC), the team gained insight into what was really happening in the PF with the carbonyl functional group, singling it out for further development.

217

Cycle life testing of lithium-ion batteries for small satellite LEO space missions  

DOE Green Energy (OSTI)

In 1990, Sony corporation announced their intention to manufacture a rechargeable lithium ion battery, based on the intercalation of lithium ions into a carbonaceous anode. The cells were first introduced for portable telephone use in June, 1991. (1) A 3.6V average cell voltage (4.1-2.75V range); (2) Excellent cycle life (1200 @ 100% DOD); (3) Good capacity retention (70% after 6 months); (4) Wide temperature range performance ({minus}20 to +60{degrees}C); (5) Excellent Discharge rate (82% capacity at 30 min. discharge rate); (6) Excellent Charge rate (100% Charge in <3 hrs); and (7) High energy density (264 W*hr/1 and 120 Whr/kg for ``D`` size cell. These specifications show significant promise for application of these batteries in low earth orbit (LEO) small satellites, particularly when compared to existing NiH{sub 2} and NiCd technology. The very high energy density and specific energy will reduce power system volume and weight. The wide temperature range enables simpler thermal design, particularly for new, small, high power satellites. The materials used in the lithium ion batteries are relatively inexpensive and benign, so that we expect costs to come down substantially in the future. The specified cycle life at 100% DOD is also 50% longer than most NiCds, so low DOD (depth of discharge) performance could be substantial. This study was undertaken to: (a) assess the feasibility for using lithium ion cells on small satellite LEO missions and (b) verify the claims of the manufacturer. This was accomplished by performing a detailed autopsy and various depth of discharge and rate tests on the cells. Of special interest was the cycle life performance of these cell at various depths of discharge DOD`s, to get an initial measure of the reduction in capacity fade with cycle conditions. Low DOD`s are used to extend the life of all batteries used in a space application.

Mayer, S.T.; Feikert, J.H.; Kaschmitter, J.L.

1993-08-16T23:59:59.000Z

218

Fail-Safe Design for Large Capacity Lithium-Ion Battery Systems  

Science Conference Proceedings (OSTI)

A fault leading to a thermal runaway in a lithium-ion battery is believed to grow over time from a latent defect. Significant efforts have been made to detect lithium-ion battery safety faults to proactively facilitate actions minimizing subsequent losses. Scaling up a battery greatly changes the thermal and electrical signals of a system developing a defect and its consequent behaviors during fault evolution. In a large-capacity system such as a battery for an electric vehicle, detecting a fault signal and confining the fault locally in the system are extremely challenging. This paper introduces a fail-safe design methodology for large-capacity lithium-ion battery systems. Analysis using an internal short circuit response model for multi-cell packs is presented that demonstrates the viability of the proposed concept for various design parameters and operating conditions. Locating a faulty cell in a multiple-cell module and determining the status of the fault's evolution can be achieved using signals easily measured from the electric terminals of the module. A methodology is introduced for electrical isolation of a faulty cell from the healthy cells in a system to prevent further electrical energy feed into the fault. Experimental demonstration is presented supporting the model results.

Kim, G. H.; Smith, K.; Ireland, J.; Pesaran, A.

2012-07-15T23:59:59.000Z

219

NREL Enhances the Performance of a Lithium-Ion Battery Cathode (Fact Sheet)  

DOE Green Energy (OSTI)

Scientists from NREL and the University of Toledo have combined theoretical and experimental studies to demonstrate a promising approach to significantly enhance the performance of lithium iron phosphate (LiFePO4) cathodes for lithium-ion batteries.

Not Available

2012-10-01T23:59:59.000Z

220

Mechanics of Electrodes in Lithium-ion Batteries A dissertation presented  

E-Print Network (OSTI)

#12;Mechanics of Electrodes in Lithium-ion Batteries A dissertation presented by Kejie Zhao, Joost J. Vlassak Kejie Zhao Mechanics of Electrodes in Lithium-ion Batteries Abstract This thesis investigates the mechanical behavior of electrodes in Li-ion batteries. Each electrode in a Li-ion battery

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Batteries - EnerDel Lithium-Ion Battery  

NLE Websites -- All DOE Office Websites (Extended Search)

EnerDel/Argonne Advanced High-Power Battery for Hybrid Electric Vehicles EnerDel/Argonne Advanced High-Power Battery for Hybrid Electric Vehicles EnerDel lithium-ion battery The EnerDel Lithium-Ion Battery The EnerDel/Argonne lithium-ion battery is a highly reliable and extremely safe device that is lighter in weight, more compact, more powerful and longer-lasting than the nickel-metal hydride (Ni-MH) batteries in today's hybrid electric vehicles (HEVs). The battery is expected to meet the U.S. Advanced Battery Consortium's $500 manufacturing price criterion for a 25-kilowatt battery, which is almost a sixth of the cost to make comparable Ni-MH batteries intended for use in HEVs. It is also less expensive to make than comparable Li-ion batteries. That cost reduction is expected to help make HEVs more competitive in the marketplace and enable consumers to receive an immediate payback in

222

Cyclic plasticity and shakedown in high-capacity electrodes of lithium-ion batteries Laurence Brassart, Kejie Zhao, Zhigang Suo  

E-Print Network (OSTI)

Cyclic plasticity and shakedown in high-capacity electrodes of lithium-ion batteries Laurence for lithium-ion batteries. Upon absorbing a large amount of lithium, the electrode swells greatly rights reserved. 1. Introduction Rechargeable lithium-ion batteries are energy-storage systems of choice

Suo, Zhigang

223

Intercalation dynamics in lithium-ion batteries  

E-Print Network (OSTI)

A new continuum model has been proposed by Singh, Ceder, and Bazant for the ion intercalation dynamics in a single crystal of rechargeable-battery electrode materials. It is based on the Cahn-Hilliard equation coupled to ...

Burch, Damian

2009-01-01T23:59:59.000Z

224

Development of a high-power lithium-ion battery.  

DOE Green Energy (OSTI)

Safety is a key concern for a high-power energy storage system such as will be required in a hybrid vehicle. Present lithium-ion technology, which uses a carbon/graphite negative electrode, lacks inherent safety for two main reasons: (1) carbon/graphite intercalates lithium at near lithium potential, and (2) there is no end-of-charge indicator in the voltage profile that can signal the onset of catastrophic oxygen evolution from the cathode (LiCoO{sub 2}). Our approach to solving these safety/life problems is to replace the graphite/carbon negative electrode with an electrode that exhibits stronger two-phase behavior further away from lithium potential, such as Li{sub 4}Ti{sub 5}O{sub 12}. Cycle-life and pulse-power capability data are presented in accordance with the Partnership for a New Generation of Vehicles (PNGV) test procedures, as well as a full-scale design based on a spreadsheet model.

Jansen, A. N.

1998-09-02T23:59:59.000Z

225

Experimental Cell for Neutron Reflection on Lithium Manganese ...  

Science Conference Proceedings (OSTI)

Presentation Title, Experimental Cell for Neutron Reflection on Lithium Manganese Oxide to Study the Electrode/Electrolyte Interface. Author(s), Brian Kitchen.

226

Available Technologies: Lithium / Sulfur Cells with Long Cycle ...  

A team of Berkeley Lab battery researchers led by Elton Cairns has invented an advanced lithium/sulfur (Li/S) cell that, for the first time, offers ...

227

New Electrode Manufacturing Process Equipment: Novel High Energy Density Lithium-Ion Cell Designs via Innovative Manufacturing Process Modules for Cathode and Integrated Separator  

Science Conference Proceedings (OSTI)

BEEST Project: Applied Materials is developing new tools for manufacturing Li-Ion batteries that could dramatically increase their performance. Traditionally, the positive and negative terminals of Li-Ion batteries are mixed with glue-like materials called binders, pressed onto electrodes, and then physically kept apart by winding a polymer mesh material between them called a separator. With the Applied Materials system, many of these manually intensive processes will be replaced by next generation coating technology to apply each component. This process will improve product reliability and performance of the cells at a fraction of the current cost. These novel manufacturing techniques will also increase the energy density of the battery and reduce the size of several of the battery’s components to free up more space within the cell for storage.

None

2010-07-01T23:59:59.000Z

228

Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries: Innovation  

NLE Websites -- All DOE Office Websites (Extended Search)

Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries: Innovation Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries: Innovation and Optimization Speaker(s): Jordi Cabana-Jimenez Date: January 14, 2008 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Venkat Srinivasan The advent of Li-ion batteries has played a central role in the impressive development of portable digital and wireless technology. Such success has triggered further efforts to utilize them as key components in other applications with an even larger impact on society, which include electric vehicles and energy backup for renewable energy sources. However, several challenges need to be met before these expectations can be realized, as Li-ion batteries currently do not meet the power and energy density requirements of these devices. New and better materials for the electrodes

229

STRUCTURE AND PERFORMANCE RELATIONSHIP IN HIGH PERFORMANCE LITHIUM ION BATTERY CATHODES.  

E-Print Network (OSTI)

??The goal of this dissertation is to study the structure and performance relationship in cathodes material used in lithium-ion battery applications. In addition, functional materials… (more)

Zhu, Pengyu

2013-01-01T23:59:59.000Z

230

Single potential electrodeposition of nanostructured battery materials for lithium-ion batteries.  

E-Print Network (OSTI)

??The increasing reliance on portable electronics is continuing to fuel research in the area of low power lithium-ion batteries, while a new surge in research… (more)

Mosby, James Matthew

2010-01-01T23:59:59.000Z

231

UNDERSTANDING AND IMPROVING LITHIUM ION BATTERIES THROUGH MATHEMATICAL MODELING AND EXPERIMENTS.  

E-Print Network (OSTI)

??There is an intense, worldwide effort to develop durable lithium ion batteries with high energy and power densities for a wide range of applications, including… (more)

Deshpande, Rutooj D.

2011-01-01T23:59:59.000Z

232

Hybrid neural net and physics based model of a lithium ion battery.  

E-Print Network (OSTI)

??Lithium ion batteries have become one of the most popular types of battery in consumer electronics as well as aerospace and automotive applications. The efficient… (more)

Refai, Rehan

2011-01-01T23:59:59.000Z

233

Minimization of Circuitry in Large Format Lithium-ion Battery Management Systems.  

E-Print Network (OSTI)

??Lithium-ion based batteries are the most energy and power dense rechargeable batteries currently available. However, to operate within safety limits battery voltages, currents, and temperatures… (more)

Miller, Jerin

2012-01-01T23:59:59.000Z

234

A Platform Towards In Situ Stress/Strain Measurement in Lithium Ion Battery Electrodes.  

E-Print Network (OSTI)

??This thesis demonstrates the design, fabrication and testing of a platform for in situ stress/strain measurement in lithium ion battery electrodes. The platform - consisting… (more)

Baron, Sergio Daniel

2012-01-01T23:59:59.000Z

235

Improving lithium-ion battery power and energy densities using novel cathode architectures and materials.  

E-Print Network (OSTI)

??Lithium-ion batteries are commonly used as energy storage devices in a variety of applications. The cathode architectures and materials have a large influence on the… (more)

Lange, Jonathan

2012-01-01T23:59:59.000Z

236

3D thermal-electrochemical lithium-ion battery computational modeling.  

E-Print Network (OSTI)

??The thesis presents a modeling framework for simulating three dimensional effects in lithium-ion batteries. This is particularly important for understanding the performance of large scale… (more)

Gerver, Rachel Ellen

2010-01-01T23:59:59.000Z

237

Modeling temperature distribution in cylindrical lithium ion batteries for use in electric vehicle cooling system design.  

E-Print Network (OSTI)

??Recent advancements in lithium ion battery technology have made BEV's a more feasible alternative. However, some safety concerns still exist. While the energy density of… (more)

Jasinski, Samuel Anthony

2008-01-01T23:59:59.000Z

238

TransForum v9n2 - Lithium-ion Battery Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Working With Argonne Contact TTRDC TransForum Vol. 9, No. 2 Argonne's Lithium-ion Battery Research Produces New Materials and Technology Transfer Successes li-ionbattery...

239

Aligned TiO2 Nanotubes as Long Durability Anodes for Lithium-Ion ...  

Science Conference Proceedings (OSTI)

Aligned TiO2 Nanotubes as Long Durability Anodes for Lithium-Ion Batteries · Aniline Coated Carbon Cryogel with Improved Cyclic Stability for Supercapacitor  ...

240

Catching Lithium Ions in Action in a Battery Electrode | U.S...  

Office of Science (SC) Website

Catching Lithium Ions in Action in a Battery Electrode Basic Energy Sciences (BES) BES Home About BES Research Facilities Science Highlights Benefits of BES Funding Opportunities...

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

High Conductivity Single-ion Cross-linked Polymers for Lithium ...  

Sun, X. and Kerr, J..Synthesis and Characterization of Network Single Ion ConductorsBased on Comb-Branched Polyepoxide Ethers and Lithium Bis(allylmalonato)borate.

242

The Effect of Single Walled Carbon Nanotubes on Lithium-Ion Batteries and Electric Double Layer Capacitors  

E-Print Network (OSTI)

The Effect of Single Walled Carbon Nanotubes on Lithium- Ion Batteries and Electric Double Layer on the overall performance of Li-ion batteries and EDLCs. SWNTs were incorporated into the anode of the Lithium-ion is used because of its high surface area. Lithium-ion Batteries ·Higher energy density than other

Mellor-Crummey, John

243

Lithium-ion batteries with intrinsic pulse overcharge protection  

SciTech Connect

The present invention relates in general to the field of lithium rechargeable batteries, and more particularly relates to the positive electrode design of lithium-ion batteries with improved high-rate pulse overcharge protection. Thus the present invention provides electrochemical devices containing a cathode comprising at least one primary positive material and at least one secondary positive material; an anode; and a non-aqueous electrolyte comprising a redox shuttle additive; wherein the redox potential of the redox shuttle additive is greater than the redox potential of the primary positive material; the redox potential of the redox shuttle additive is lower than the redox potential of the secondary positive material; and the redox shuttle additive is stable at least up to the redox potential of the secondary positive material.

Chen, Zonghai; Amine, Khalil

2013-02-05T23:59:59.000Z

244

Improving the performance of soft carbon for lithium-ion batteries.  

DOE Green Energy (OSTI)

A novel technique for designing a robust solid electrolyte interface (SEI) on the negative electrodes of lithium-ion batteries has been developed using a silane coating. Two silane compounds, 3,3,3-trifluoropropyltrimethoxysilane (TFPTMS) and dimethoxybis(2-(2-(2-mothoxyethoxy)ethoxy)ethoxy)silane (1ND3(MeO)), have been investigated with respect to improving the capacity retention of lithium manganese oxide spinel/soft carbon cells. The impact of the silane coating on the soft carbon electrode will be attributed to (1) changes in surface functional groups, (2) compositional change of the SEI, and (3) changes in the kinetics of manganese deposition. The impact of the upper cutoff voltage on the capacity retention of the cell was also discussed.

Chen, Z.; Wang, Q.; Amine, K.; Chemical Engineering

2006-01-01T23:59:59.000Z

245

Mesoporous TiO2-B Microspheres with Superior Rate Performance for Lithium Ion Batteries  

SciTech Connect

Mesoporous TiO2-B microsperes with a favorable material architecture are designed and synthesized for high power lithium ion batteries. This material, combining the advantages of fast lithium transport with a pseudocapacitive mechanism, adequate electrode-electrolyte contact and compact particle packing in electrode layer, shows superior high-rate charge-discharge capability and long-time cyclability for lithium ion batteries.

Liu, Hansan [ORNL; Bi, Zhonghe [ORNL; Sun, Xiao-Guang [ORNL; Unocic, Raymond R [ORNL; Paranthaman, Mariappan Parans [ORNL; Dai, Sheng [ORNL; Brown, Gilbert M [ORNL

2011-01-01T23:59:59.000Z

246

Internal Resistance Identification in Vehicle Power Lithium-Ion Battery and Application in Lifetime Evaluation  

Science Conference Proceedings (OSTI)

According to the characteristic analysis of lithium-ion power battery, battery accelerate life test is carried out to obtain the relevant conclusions such as the changing trend of battery ohmic resistance in different conditions. Battery ohmic resistance ... Keywords: Lithium-ion battery, Internal resistance, Equivalent model, Lifetime evaluation

Xuezhe Wei; Bing Zhu; Wei Xu

2009-04-01T23:59:59.000Z

247

Fault Prediction and Fault-Tolerant of Lithium-ion Batteries Temperature Failure for Electric Vehicle  

Science Conference Proceedings (OSTI)

Design and implementation of dual-redundancy was developed to predict Lithium-ion battery failure for electric vehicle. Data fusion unit, prediction unit and determination unit were designed. Outputs from original and redundant sensors were integrated ... Keywords: Lithium-ion battery, dual-redundancy, data fusion, prediction, Fault-tolerant

Hu Chunhua; He Ren; Wang Runcai; Yu Jianbo

2012-07-01T23:59:59.000Z

248

Modeling of DFIG Wind Turbine and Lithium Ion Energy Storage System  

Science Conference Proceedings (OSTI)

The paper is aimed at describing the dynamic models of DFIG equipped wind turbine and Lithium Ion Energy System. The purpose of the energy storage system is to be coupled to the wind generation system in order to smooth its power output. Depending on ... Keywords: Renewable Generation, Embedded Generation, Wind Power, DFIG, Lithium Ion, Storage

Mattia Marinelli; Andrea Morini; Federico Silvestro

2010-02-01T23:59:59.000Z

249

UV and EB Curable Binder Technology for Lithium Ion Batteries and UltraCapacitors  

DOE Green Energy (OSTI)

the basic feasibility of using UV curing technology to produce Lithium ion battery electrodes at speeds over 200 feet per minute has been shown. A unique set of UV curable chemicals were discovered that were proven to be compatible with a Lithium ion battery environment with the adhesion qualities of PVDF.

Voelker, Gary

2012-04-30T23:59:59.000Z

250

Paper-Based Lithium-Ion Battery Nojan Aliahmad, Mangilal Agarwal, Sudhir Shrestha, and Kody Varahramyan  

E-Print Network (OSTI)

Paper-Based Lithium-Ion Battery Nojan Aliahmad, Mangilal Agarwal, Sudhir Shrestha, and Kody Indianapolis (IUPUI), Indianapolis, IN 46202 Lithium-ion batteries have a wide range of applications including present day portable consumer electronics and large-scale energy storage. Realization of these batteries

Zhou, Yaoqi

251

Solution-Grown Silicon Nanowires for Lithium-Ion Battery Anodes  

E-Print Network (OSTI)

that lower- ing the price of batteries is a major goal, the cost of the processing and fabricationSolution-Grown Silicon Nanowires for Lithium-Ion Battery Anodes Candace K. Chan, Reken N. Patel interest in using nanomaterials for advanced lithium-ion battery electrodes, par- ticularly for increasing

Cui, Yi

252

Prediction of Multi-Physics Behaviors of Large Lithium-Ion Batteries During Internal and External Short Circuit (Presentation)  

DOE Green Energy (OSTI)

This presentation describes the multi-physics behaviors of internal and external short circuits in large lithium-ion batteries.

Kim, G. H.; Lee, K. J.; Chaney, L.; Smith, K.; Darcy, E.; Pesaran, A.; Darcy, E.

2010-11-01T23:59:59.000Z

253

Simplified Electrode Formation using Stabilized Lithium Metal ...  

A team of Berkeley Lab researchers led by Gao Liu has developed a doping process for lithium ion battery electrode formation that can boost a cell’s ...

254

Kinetics-controlled growth of aligned mesocrystalline SnO2 nanorod arrays for lithium-ion batteries with  

E-Print Network (OSTI)

and operating potential, lithium ion batteries have been widely adopted in portable electronics. However in lithium ion batteries.2 The use of a liquid electrolyte restricts battery shape and processing while also and proton conductivity14 have also been reported. While the intercalation of lithium ions

Qi, Limin

255

High-Capacity Micrometer-Sized Li2S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries  

E-Print Network (OSTI)

Lithium-Ion Batteries Yuan Yang, Guangyuan Zheng, Sumohan Misra,§ Johanna Nelson,§ Michael F. Toney as the cathode material for rechargeable lithium-ion batteries with high specific energy. INTRODUCTION Rechargeable lithium-ion batteries have been widely used in portable electronics and are promising

Cui, Yi

256

Electrochemical behavior of LiCoO2 as aqueous lithium-ion battery electrodes Riccardo Ruffo a  

E-Print Network (OSTI)

Electrochemical behavior of LiCoO2 as aqueous lithium-ion battery electrodes Riccardo Ruffo 2008 Available online xxxx Keywords: LiCoO2 Aqueous electrolyte LiNO3 Lithium-ion battery Cathode substrate using the procedures typical for the study of electrodes for lithium-ion batteries in organic

Cui, Yi

257

The Effect of Single Walled Carbon Nanotubes on Lithium-Ion Batteries and Electric Double Layer Capacitors  

E-Print Network (OSTI)

The Effect of Single Walled Carbon Nanotubes on Lithium-Ion Batteries and Electric Double Layer power. #12;The Effect of Single Walled Carbon Nanotubes on Lithium- Ion Batteries and Electric Double of the Lithium-ion Battery (LIB). A LIB using only graphite in the anode was the control. SWNTs were mixed

Mellor-Crummey, John

258

Kinetic Monte Carlo Simulation of Surface Heterogeneity in Graphite Anodes for Lithium-Ion Batteries: Passive Layer  

E-Print Network (OSTI)

, but was lower at later cycles. The temperature that optimizes the active surface in a lithium-ion battery. Published February 14, 2011. Rechargeable lithium-ion batteries have been extensively used in mobile-discharge rate. The lithium-ion battery is also promising for electric (plug-in and hybrid) vehicles

Barton, Paul I.

259

Method for producing a secondary lithium cell comprising a heat-sensitive protective mechanism  

DOE Patents (OSTI)

A method for producing a secondary lithium cell which has at least one lithium-cycling negative electrode, at least one lithium-intercalating positive electrode, at least one separator disposed between the positive and the negative electrode, and a nonaqueous lithium ion-conducting electrolyte. The method is carried out by the electrodes and/or the separator being coated, by means of electrostatic powder coating, with wax particles which are insoluble in the electrolyte and have a melting temperature of from about 50 to about 150 .degree. C. and a mean particle size of from about 6 to about 20 .mu.m, the amount of wax being between about 0.5 and about 2.5 mg/cm.sup.2 of electrode area.

Ullrich, Matthias (Kelkheim, DE); Bechtold, Dieter (Bad Vilbel, DE); Rabenstein, Heinrich (Frankfurt, DE); Brohm, Thomas (Kelkheim, DE)

2003-01-01T23:59:59.000Z

260

Costs of lithium-ion batteries for vehicles  

DOE Green Energy (OSTI)

One of the most promising battery types under development for use in both pure electric and hybrid electric vehicles is the lithium-ion battery. These batteries are well on their way to meeting the challenging technical goals that have been set for vehicle batteries. However, they are still far from achieving the current cost goals. The Center for Transportation Research at Argonne National Laboratory undertook a project for the US Department of Energy to estimate the costs of lithium-ion batteries and to project how these costs might change over time, with the aid of research and development. Cost reductions could be expected as the result of material substitution, economies of scale in production, design improvements, and/or development of new material supplies. The most significant contributions to costs are found to be associated with battery materials. For the pure electric vehicle, the battery cost exceeds the cost goal of the US Advanced Battery Consortium by about $3,500, which is certainly enough to significantly affect the marketability of the vehicle. For the hybrid, however, the total cost of the battery is much smaller, exceeding the cost goal of the Partnership for a New Generation of Vehicles by only about $800, perhaps not enough to deter a potential buyer from purchasing the power-assist hybrid.

Gaines, L.; Cuenca, R.

2000-08-21T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Protective lithium ion conducting ceramic coating for lithium metal anodes and associate method  

SciTech Connect

A battery structure including a cathode, a lithium metal anode and an electrolyte disposed between the lithium anode and the cathode utilizes a thin-film layer of lithium phosphorus oxynitride overlying so as to coat the lithium anode and thereby separate the lithium anode from the electrolyte. If desired, a preliminary layer of lithium nitride may be coated upon the lithium anode before the lithium phosphorous oxynitride is, in turn, coated upon the lithium anode so that the separation of the anode and the electrolyte is further enhanced. By coating the lithium anode with this material lay-up, the life of the battery is lengthened and the performance of the battery is enhanced.

Bates, John B. (Oak Ridge, TN)

1994-01-01T23:59:59.000Z

262

High-Power Electrodes for Lithium-Ion Batteries | U.S. DOE Office of  

Office of Science (SC) Website

High-Power Electrodes for Lithium-Ion High-Power Electrodes for Lithium-Ion Batteries Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights Highlight Archives News & Events Publications Contact BES Home 04.27.12 High-Power Electrodes for Lithium-Ion Batteries Print Text Size: A A A RSS Feeds FeedbackShare Page Scientific Achievement For novel 3-D anodes made of sheets of carbon (graphene) and silicon nanoparticles, transport studies found much shorter lithium diffusion paths throughout the electrode and fast lithiation/delithiation of the nanoparticles. Significance and Impact This anode design holds a greater charge than conventional lithium-ion anodes and charges/discharges more rapidly while maintaining mechanical stability. Research Details Electrochemical studies: 83% of theoretical capacity (3200 mAh g-1)

263

Better Lithium-Ion Batteries Are On The Way From Berkeley Lab  

NLE Websites -- All DOE Office Websites (Extended Search)

Lithium-Ion Lithium-Ion Batteries A Better Lithium-ion Battery on the Way Simulations Reveal How New Polymer Absorbs Eight Times the Lithium of Current Designs September 23, 2011 Paul Preuss, +1 510 486 6249, paul_preuss@lbl.gov traditional-new.jpg At left, the traditional approach to composite anodes using silicon (blue spheres) for higher energy capacity has a polymer binder such as PVDF (light brown) plus added particles of carbon to conduct electricity (dark brown spheres). Silicon swells and shrinks while acquiring and releasing lithium ions, and repeated swelling and shrinking eventually break contacts among the conducting carbon particles. At right, the new Berkeley Lab polymer (purple) is itself conductive and continues to bind tightly to the silicon particles despite repeated swelling and shrinking.

264

Electrochemical modeling of lithium-ion positive electrodes during hybrid pulse power characterization tests.  

DOE Green Energy (OSTI)

An electrochemical model was developed to examine hybrid pulsed power characterization (HPPC) tests on the positive electrode of lithium-ion cells. By utilizing the same fundamental equations as in previous electrochemical impedance spectroscopy studies, this investigation serves as an extension of the earlier work and a comparison of the two techniques. The electrochemical model was used to examine performance characteristics and limitations for the positive electrode during HPPC tests. Parametric studies using the electrochemical model and focusing on the positive electrode thickness were employed to examine methods of slowing electrode aging and improving performance.

Dees, D.; Gunen, E.; Abraham, D.; Jansen, A.; Prakash, J.; Chemical Sciences and Engineering Division; Illinois Inst. of Tech.

2008-01-01T23:59:59.000Z

265

Observation of State of Charge Distributions in Lithium-ion Battery Electrodes  

Science Conference Proceedings (OSTI)

Current lithium-ion battery technology is gearing towards meeting the robust demand of power and energy requirements for all-electric transportation without compromising on the safety, performance, and cycle life. The state-of-charge (SOC) of a Li-ion cell can be a macroscopic indicator of the state-of-health of the battery. The microscopic origin of the SOC relates to the local lithium content in individual electrode particles and the effective ability of Li-ions to transport or shuttle between the redox couples through the cell geometric boundaries. Herein, micrometer-resolved Raman mapping of a transition-metal-based oxide positive electrode, Li{sub 1-x}(Ni{sub y}Co{sub z}Al{sub 1-y-z})O{sub 2}, maintained at different SOCs, is shown. An attempt has been made to link the underlying changes to the composition and structural integrity at the individual particle level. Furthermore, an SOC distribution at macroscopic length scale of the electrodes is presented.

Remillard, Jeffrey [Ford Research and Advanced Engineering, Ford Motor Company; O'Neil, Ann E [Ford Research and Advanced Engineering, Ford Motor Company; Bernardi, Dawn [Ford Research and Advanced Engineering, Ford Motor Company; Ro, Tina J [Massachusetts Institute of Technology (MIT); Miller, Ted [Ford Motor Company; Neitering, Ken [Ford Research and Advanced Engineering, Ford Motor Company; Go, Joo-Young [SB Limotive, Korea; Nanda, Jagjit [ORNL

2011-01-01T23:59:59.000Z

266

Ion cyclotron resonance cell  

DOE Patents (OSTI)

An ion cyclotron resonance cell is disclosed having two adjacent sections separated by a center trapping plate. The first section is defined by the center trapping plate, a first end trapping plate, and excitation and detector electrodes. The second section includes a second end trapping plate spaced apart from the center plate, a mirror, and an analyzer. The analyzer includes a wavelength-selective light detector, such as a detector incorporating an acousto-optical device (AOD) and a photodetector. One or more ion guides, grounded plates with holes for the ion beam, are positioned within the vacuum chamber of the mass spectrometer between the ion source and the cell. After ions are trapped and analyzed by ion cyclotron resonance techniques in the first section, the ions of interest are selected according to their mass and passed into the second section for optical spectroscopic studies. The trapped ions are excited by light from a laser and caused thereby to fluoresce. The fluorescent light emitted by the excited ions is reflected by the mirror and directed onto the detector. The AOD is scanned, and the photodetector output is recorded and analyzed. The ions remain in the second section for an extended period, enabling multiple studies to be carried out on the same ensemble of ions. 5 figs.

Weller, R.R.

1995-02-14T23:59:59.000Z

267

Cycling Degradation of Lithium Iron Phosphate Cells  

Science Conference Proceedings (OSTI)

Abstract Scope, Significant improvement of electronic conductivity of lithium iron ... commercialization in many applications especially in plug-in electric vehicles.

268

Layered Electrodes for Lithium Cells and Batteries  

AV AILABLE FOR LICENSING Layered lithium metal oxide compounds for ultra-high capacity, rechargeable cathodes. The Invention High-capacity, rechargeable cathodes made ...

269

Modeling and Simulation of Lithium-Ion Batteries from a Systems Engineering Perspective  

Science Conference Proceedings (OSTI)

The lithium-ion battery is an ideal candidate for a wide variety of applications due to its high energy/power density and operating voltage. Some limitations of existing lithium-ion battery technology include underutilization, stress-induced material damage, capacity fade, and the potential for thermal runaway. This paper reviews efforts in the modeling and simulation of lithium-ion batteries and their use in the design of better batteries. Likely future directions in battery modeling and design including promising research opportunities are outlined.

Ramadesigan, V.; Northrop, P. W. C.; De, S.; Santhanagopalan, S.; Braatz, R. D.; Subramanian, Venkat R.

2012-01-01T23:59:59.000Z

270

Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage (October  

NLE Websites -- All DOE Office Websites (Extended Search)

Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage (October 2012) Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage (October 2012) DOE's Energy Storage Program is funding research to develop longer-lifetime, lower-cost Li-ion batteries. Researchers at Pacific Northwest National Laboratory are investigating cost-effective electrode materials and electrolytes, as well as novel low-cost synthesis approaches for making highly efficient electrode materials using additives such as graphine, oleic acid, and paraffin. To address safety issues, researchers will also identify materials with better thermal stability. Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage (October 2012) More Documents & Publications Battery SEAB Presentation

271

Advanced Mitigating Measures for the Cell Internal Short Risk (Presentation)  

DOE Green Energy (OSTI)

This presentation describes mitigation measures for internal short circuits in lithium-ion battery cells.

Darcy, E.; Smith, K.

2010-04-01T23:59:59.000Z

272

Advanced Lithium Ion Battery Technologies - Energy Innovation Portal  

The Berkeley Lab technology contributes to improved battery safety by circumventing lithium metal dendrite formation. Benefits. ... hybrid electric vehicles;

273

Conductive Binder for Lithium Ion Battery Electrode - IB-2643 ...  

The Berkeley Lab electrode technology contributes to improved battery safety by circumventing lithium metal dendrite ... Scalable manufacturing using ...

274

A study of lithium ion intercalation induced fracture of silicon particles used as anode material in Li-ion battery  

Science Conference Proceedings (OSTI)

The fracture of Si particles due to internal stresses formed during the intercalation of lithium ions was described by means of thermal analogy model and brittle fracture damage parameter. The stresses were calculated following the diffusion equation and equations of elasticity with appropriate volumetric expansion term. The damage parameter takes into account triaxiality of the stress state and change in elasticity upon tension and compression, and represents the probability of fracture under given stress state, - an approach suitable for brittle materials. The results were compared with the acoustic emission data from the experiments on electrochemical cycling of Li ion half-cells with silicon electrodes. A good correlation between experiment and prediction was observed.

Daniel, Claus [ORNL; Kalnaus, Sergiy [ORNL; Rhodes, Kevin [University of Tennessee, Knoxville (UTK)

2011-01-01T23:59:59.000Z

275

Process for manufacturing a lithium alloy electrochemical cell  

DOE Patents (OSTI)

A process for manufacturing a lithium alloy, metal sulfide cell tape casts slurried alloy powders in an organic solvent containing a dissolved thermoplastic organic binder onto casting surfaces. The organic solvent is then evaporated to produce a flexible tape removable adhering to the casting surface. The tape is densified to increase its green strength and then peeled from the casting surface. The tape is laminated with a separator containing a lithium salt electrolyte and a metal sulfide electrode to form a green cell. The binder is evaporated from the green cell at a temperature lower than the melting temperature of the lithium salt electrolyte. Lithium alloy, metal sulfide and separator powders may be tape cast.

Bennett, William R. (North Olmstead, OH)

1992-10-13T23:59:59.000Z

276

Understanding the Degredation of Silicion Electrodes for Lithium Ion Batteries Using Acoustic Emission  

Science Conference Proceedings (OSTI)

Silicon is a promising anode material for lithium ion battery application due to its high specific capacity, low cost, and abundance. However, when silicon is lithiated at room temperature it can undergo a volume expansion in excess of 280% which leads to extensive fracturing. This is thought to be a primary cause of the rapid decay in cell capacity routinely observed. Acoustic emission (AE) was employed to monitor activity in composite silicon electrodes while cycling in lithium ion half-cells using a constant current-constant voltage procedure. The major source of AE was identified as the brittle fracture of silicon particles resulting from the alloying reaction that gives rise to LixSi phases. The largest number of emissions occurred on the first lithiation corresponding to surface fracture of the silicon particles, followed by distinct emission bursts on subsequent charge and discharge steps. Furthermore, a difference in the average parameters describing emission during charge and discharge steps was observed. Potential diagnostic and materials development applications of the presented AE techniques are discussed.

Rhodes, Kevin J [ORNL; Dudney, Nancy J [ORNL; Lara-Curzio, Edgar [ORNL; Daniel, Claus [ORNL

2010-01-01T23:59:59.000Z

277

Current status of environmental, health, and safety issues of lithium ion electric vehicle batteries  

DOE Green Energy (OSTI)

The lithium ion system considered in this report uses lithium intercalation compounds as both positive and negative electrodes and has an organic liquid electrolyte. Oxides of nickel, cobalt, and manganese are used in the positive electrode, and carbon is used in the negative electrode. This report presents health and safety issues, environmental issues, and shipping requirements for lithium ion electric vehicle (EV) batteries. A lithium-based electrochemical system can, in theory, achieve higher energy density than systems using other elements. The lithium ion system is less reactive and more reliable than present lithium metal systems and has possible performance advantages over some lithium solid polymer electrolyte batteries. However, the possibility of electrolyte spills could be a disadvantage of a liquid electrolyte system compared to a solid electrolyte. The lithium ion system is a developing technology, so there is some uncertainty regarding which materials will be used in an EV-sized battery. This report reviews the materials presented in the open literature within the context of health and safety issues, considering intrinsic material hazards, mitigation of material hazards, and safety testing. Some possible lithium ion battery materials are toxic, carcinogenic, or could undergo chemical reactions that produce hazardous heat or gases. Toxic materials include lithium compounds, nickel compounds, arsenic compounds, and dimethoxyethane. Carcinogenic materials include nickel compounds, arsenic compounds, and (possibly) cobalt compounds, copper, and polypropylene. Lithiated negative electrode materials could be reactive. However, because information about the exact compounds that will be used in future batteries is proprietary, ongoing research will determine which specific hazards will apply.

Vimmerstedt, L.J.; Ring, S.; Hammel, C.J.

1995-09-01T23:59:59.000Z

278

Secretary Chu Celebrates Expansion of Lithium-Ion Battery Production in  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Celebrates Expansion of Lithium-Ion Battery Celebrates Expansion of Lithium-Ion Battery Production in North Carolina Secretary Chu Celebrates Expansion of Lithium-Ion Battery Production in North Carolina July 26, 2011 - 3:15pm Addthis Secretary Chu joins local officials and dignitaries for Celgard's ribbon-cutting. | Photo courtesy of Celgard Secretary Chu joins local officials and dignitaries for Celgard's ribbon-cutting. | Photo courtesy of Celgard Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs What are the key facts? Celgard received $49 million in Recovery Act funding to help expand its Charlotte operations and build a new lithium-ion battery separator facility in Concord. With the help of Recovery Act-funded expansions, Celgard expects to double its production capacity by 2012 and since January 2010, the company

279

Secretary Chu Celebrates Expansion of Lithium-Ion Battery Production in  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Celebrates Expansion of Lithium-Ion Battery Celebrates Expansion of Lithium-Ion Battery Production in North Carolina Secretary Chu Celebrates Expansion of Lithium-Ion Battery Production in North Carolina July 26, 2011 - 3:15pm Addthis Secretary Chu joins local officials and dignitaries for Celgard's ribbon-cutting. | Photo courtesy of Celgard Secretary Chu joins local officials and dignitaries for Celgard's ribbon-cutting. | Photo courtesy of Celgard Niketa Kumar Niketa Kumar Public Affairs Specialist, Office of Public Affairs What are the key facts? Celgard received $49 million in Recovery Act funding to help expand its Charlotte operations and build a new lithium-ion battery separator facility in Concord. With the help of Recovery Act-funded expansions, Celgard expects to double its production capacity by 2012 and since January 2010, the company

280

Amorphous Metallic Glass as New High Power and Energy Density Anodes For Lithium Ion Rechargeable Batteries  

E-Print Network (OSTI)

We have investigated the use of aluminum based amorphous metallic glass as the anode in lithium ion rechargeable batteries. Amorphous metallic glasses have no long-range ordered microstructure; the atoms are less closely ...

Meng, Shirley Y.

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Highly - conductive cathode for lithium-ion battery using M13 phage - SWCNT complex  

E-Print Network (OSTI)

Lithium-ion batteries are commonly used in portable electronics, and the rapid growth of mobile technology calls for an improvement in battery capabilities. Reducing the particle size of electrode materials in synthesis ...

Adams, Melanie Chantal

2013-01-01T23:59:59.000Z

282

Investigation on Aluminum-Based Amorphous Metallic Glass as New Anode Material in Lithium Ion Batteries  

E-Print Network (OSTI)

Aluminum based amorphous metallic glass powders were produced and tested as the anode materials for the lithium ion rechargeable batteries. Ground Al??Ni₁?La₁? was found to have a ...

Meng, Shirley Y.

283

State-of-Charge Estimations for Lead-Acid and Lithium-Ion Batteries.  

E-Print Network (OSTI)

??This thesis studies State-of-Charge (SOC) method for widely used lead-acid batteries and the most prospective lithium-ion batteries. First, the relationship between the battery capacity and… (more)

Chen, Yi-Ping

2007-01-01T23:59:59.000Z

284

Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries  

E-Print Network (OSTI)

Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium ...

Davis, Robin M. (Robin Manes)

2005-01-01T23:59:59.000Z

285

Virus constructed iron phosphate lithium ion batteries in unmanned aircraft systems  

E-Print Network (OSTI)

FePO? lithium ion batteries that have cathodes constructed by viruses are scaled up in size to examine potential for use as an auxiliary battery in the Raven to power the payload equipment. These batteries are assembled ...

Kolesnikov-Lindsey, Rachel

286

Llife-Cycle Analysis for Lithium-Ion Battery Production and Recycling  

NLE Websites -- All DOE Office Websites (Extended Search)

No. 11-3891 Life-Cycle Analysis for Lithium-Ion Battery Production and Recycling By Linda Gaines (630) 252-4919 E-mail: lgaines@anl.gov John Sullivan (734) 945-1261 E-mail:...

287

Graphene-based composites as cathode materials for lithium ion batteries  

Science Conference Proceedings (OSTI)

Owing to the superior mechanical, thermal, and electrical properties, graphene was a perfect candidate to improve the performance of lithium ion batteries. Herein, we review the recent advances in graphene-based composites and their application as cathode ...

Libao Chen, Ming Zhang, Weifeng Wei

2013-01-01T23:59:59.000Z

288

A New Family of Two Dimensional Materials for Use in Lithium Ion ...  

Science Conference Proceedings (OSTI)

More recently, we reported on the use of Ti2C as an anode material in lithium-ion batteries (LIBs) that can be cycled at high rates. Herein, we report for first time ...

289

Surface-Modified Membrane as A Separator for Lithium-Ion Polymer Battery  

E-Print Network (OSTI)

This paper describes the fabrication of novel modified polyethylene (PE) membranes using plasma technology to create high-performance and cost-effective separator membranes for practical applications in lithium-ion polymer ...

Kim, Jun Young

290

Parameter Estimation and Capacity Fade Analysis of Lithium-Ion Batteries Using Reformulated Models  

E-Print Network (OSTI)

Many researchers have worked to develop methods to analyze and characterize capacity fade in lithium-ion batteries. As a complement to approaches to mathematically model capacity fade that require detailed understanding ...

Braatz, Richard D.

291

Surface-Modified Copper Current Collector for Lithium Ion Battery Anode  

A team of Berkeley Lab researchers led by Gao Liu has developed an innovative approach to improve the adhesion of anode laminate to copper current collectors in lithium ion batteries. This nanotechnology directly addresses delamination of graphite ...

292

Development of a representative volume element of lithium-ion batteries for thermo-mechanical integrity  

E-Print Network (OSTI)

The importance of Lithium-ion batteries continues to grow with the introduction of more electronic devices, electric cars, and energy storage. Yet the optimization approach taken by the manufacturers and system designers ...

Hill, Richard Lee, Sr

2011-01-01T23:59:59.000Z

293

Fracture of electrodes in lithium-ion batteries caused by fast charging Kejie Zhao, Matt Pharr, Joost J. Vlassak, and Zhigang Suoa  

E-Print Network (OSTI)

Fracture of electrodes in lithium-ion batteries caused by fast charging Kejie Zhao, Matt Pharr; published online 8 October 2010 During charging or discharging of a lithium-ion battery, lithium batteries.3 A lithium-ion battery contains an electrolyte and two electrodes. Each electrode is an atomic

Suo, Zhigang

294

Inelastic hosts as electrodes for high-capacity lithium-ion batteries Kejie Zhao, Matt Pharr, Joost J. Vlassak, and Zhigang Suoa  

E-Print Network (OSTI)

Inelastic hosts as electrodes for high-capacity lithium-ion batteries Kejie Zhao, Matt Pharr, Joost for high-capacity lithium-ion batteries. Upon absorbing lithium, silicon swells several times its volume strength. © 2011 American Institute of Physics. doi:10.1063/1.3525990 Lithium-ion batteries

295

Plug-In Electric Vehicle Lithium-Ion Battery Cost and Advanced Battery Technologies Forecasts  

Science Conference Proceedings (OSTI)

Batteries are a critical cost factor for plug-in electric vehicles, and the current high cost of lithium ion batteries poses a serious challenge for the competitiveness of Plug-In Electric Vehicles (PEVs). Because the market penetration of PEVs will depend heavily on future battery costs, determining the direction of battery costs is very important. This report examines the cost drivers for lithium-ion PEV batteries and also presents an assessment of recent advancements in the growing attempts to ...

2012-12-12T23:59:59.000Z

296

Role of surface coating on cathode materials for lithium-ion batteries.  

Science Conference Proceedings (OSTI)

Surface coating of cathode materials has been widely investigated to enhance the life and rate capability of lithium-ion batteries. The surface coating discussed here was divided into three different configurations which are rough coating, core shell structure coating and ultra thin film coating. The mechanism of surface coating in achieving improved cathode performance and strategies to carry out this surface modification is discussed. An outlook on atomic layer deposition for lithium ion battery is also presented.

Chen, Z.; Qin, Y.; Amine, K.; Sun, Y.-K. (Chemical Sciences and Engineering Division); (Hanyang Univ.)

2010-01-01T23:59:59.000Z

297

Temperature-Dependent Battery Models for High-Power Lithium-Ion Batteries  

DOE Green Energy (OSTI)

In this study, two battery models for a high-power lithium ion (Li-Ion) cell were compared for their use in hybrid electric vehicle simulations in support of the U.S. Department of Energy's Hybrid Electric Vehicle Program. Saft America developed the high-power Li-Ion cells as part of the U.S. Advanced Battery Consortium/U.S. Partnership for a New Generation of Vehicles programs. Based on test data, the National Renewable Energy Laboratory (NREL) developed a resistive equivalent circuit battery model for comparison with a 2-capacitance battery model from Saft. The Advanced Vehicle Simulator (ADVISOR) was used to compare the predictions of the two models over two different power cycles. The two models were also compared to and validated with experimental data for a US06 driving cycle. The experimental voltages on the US06 power cycle fell between the NREL resistive model and Saft capacitance model predictions. Generally, the predictions of the two models were reasonably close to th e experimental results; the capacitance model showed slightly better performance. Both battery models of high-power Li-Ion cells could be used in ADVISOR with confidence as accurate battery behavior is maintained during vehicle simulations.

Johnson, V.H.; Pesaran, A.A. (National Renewable Energy Laboratory); Sack, T. (Saft America)

2001-01-10T23:59:59.000Z

298

Comb-shaped single ion conductors based on polyacrylate ethers and lithium  

NLE Websites -- All DOE Office Websites (Extended Search)

Comb-shaped single ion conductors based on polyacrylate ethers and lithium Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Title Comb-shaped single ion conductors based on polyacrylate ethers and lithium alkyl sulfonate Publication Type Journal Article Year of Publication 2005 Authors Sun, Xiao-Guang, Jun Hou, and John B. Kerr Journal Electrochimica Acta Volume 50 Pagination 1139-1147 Keywords ionic conductivity, plasticizer, polyacrylate ethers, single ion conductor Abstract Comb-shaped single ion conductors have been synthesized by sulfonation of small molecule chloroethyleneglycols, which, after ion exchange to the Li+ salt were then converted to the acrylate by reaction with acryloyl chloride and copolymerized with polyethylene glycol monomethyl ether acrylate (Mn = 454, n = 8) (PAE8-co-E3SO3Li);

299

Chloromethyl chlorosulfate as a voltage delay inhibitor in lithium cells  

DOE Patents (OSTI)

Chloromethyl chlorosulfate (CMCS) is used as a passive film growth inhibitor in electrochemical cells to minimize voltage delay and low-voltage discharge. Film growth on lithium anodes is significantly diminished when CMCS is added to SOCl.sub.2 and SO.sub.2 Cl.sub.2 electrolytes of lithium batteries. The CMCS also has the effect of extending the shelf-life of Li/SOCl.sub.2 and Li/SO.sub.2 Cl.sub.2 batteries.

Delnick, Frank M. (Albuquerque, NM)

1993-01-01T23:59:59.000Z

300

Chloromethyl chlorosulfate as a voltage delay inhibitor in lithium cells  

DOE Patents (OSTI)

Chloromethyl chlorosulfate (CMCS) is used as a passive film growth inhibitor in electrochemical cells to minimize voltage delay and low-voltage discharge. Film growth on lithium anodes is significantly diminished when CMCS is added to SOCl[sub 2] and SO[sub 2]Cl[sub 2] electrolytes of lithium batteries. The CMCS also has the effect of extending the shelf-life of Li/SOCl[sub 2] and Li/SO[sub 2]Cl[sub 2] batteries.

Delnick, F.M.

1993-04-13T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Chloromethyl chlorosulfate as a voltage delay inhibitor in lithium cells  

DOE Patents (OSTI)

Chloromethyl chlorosulfate (CMCS) is used as a passive film growth inhibitor in electrochemical cells to minimize voltage delay and low-voltage discharge. Film growth on lithium anodes is significantly diminished when CMCS is added to SOCl{sub 2} and SO{sub 2}Cl{sub 2} electrolytes of lithium batteries. The CMCS also has the effect of extending the shelf-life of Li/SOCl{sub 2} and Li/SO{sub 2}Cl{sub 2} batteries.

Delnick, F.M.

1991-04-05T23:59:59.000Z

302

Microwave-assisted hydrothermal synthesis of porous SnO{sub 2} nanotubes and their lithium ion storage properties  

SciTech Connect

Porous SnO{sub 2} nanotubes have been synthesized by a rapid microwave-assisted hydrothermal process followed by annealing in air. The detailed morphological and structural studies indicate that the SnO{sub 2} tubes typically have diameters from 200 to 400 nm, lengths from 0.5 to 1.5 {mu}m and wall thicknesses from 50 to 100 nm. The SnO{sub 2} nanotubes are self-assembled by interconnected nanocrystals with sizes {approx}8 nm resulting in a specific surface area of {approx}54 m{sup 2} g{sup -1}. The pristine SnO{sub 2} nanotubes are used to fabricate lithium half cells to evaluate their lithium ion storage properties. The porous SnO{sub 2} nanotubes are characteristic with high lithium ion storage capacity, that is found to be 1258, 951, 757, 603, 458, and 288 mAh g{sup -1}, at 0.1, 0.2, 0.5, 1, 2, and 4C, respectively. The enhanced electrochemical properties of the SnO{sub 2} nanotubes can be ascribed to their unique geometry and porous structures. - Graphical abstract: Porous SnO{sub 2} nanotubes are synthesized by a fast microwave-assisted hydrothermal process and exhibit high lithium ion storage properties due to their unique geometry and porous characteristics. Highlights: Black-Right-Pointing-Pointer A microwave-assisted hydrothermal method was used to prepare porous SnO{sub 2} nanotubes. Black-Right-Pointing-Pointer The porous SnO{sub 2} nanotubes have abundant mesopores on their tube walls. Black-Right-Pointing-Pointer The porous SnO{sub 2} nanotubes possess high lithium ion storage properties. Black-Right-Pointing-Pointer Our results may promote the development of high-performance anode materials.

Wang, H.E., E-mail: hongen.wang@gmail.com [Department of Physics and Materials Science, City University of Hong Kong (Hong Kong); Center of Super-Diamond and Advanced Films (COSDAF), City University of Hong Kong (Hong Kong); Xi, L.J.; Ma, R.G. [Department of Physics and Materials Science, City University of Hong Kong (Hong Kong); Lu, Z.G. [School of Chemistry and Chemical Engineering, Central South University, Changsha 410083 (China); Chung, C.Y. [Department of Physics and Materials Science, City University of Hong Kong (Hong Kong); Bello, I. [Department of Physics and Materials Science, City University of Hong Kong (Hong Kong); Center of Super-Diamond and Advanced Films (COSDAF), City University of Hong Kong (Hong Kong); Zapien, J.A., E-mail: apjazs@cityu.edu.hk [Department of Physics and Materials Science, City University of Hong Kong (Hong Kong); Center of Super-Diamond and Advanced Films (COSDAF), City University of Hong Kong (Hong Kong)

2012-06-15T23:59:59.000Z

303

Lithium-Ion Batteries: Examining Material Demand and Recycling...  

NLE Websites -- All DOE Office Websites (Extended Search)

ISSUES Linda Gaines and Paul Nelson Argonne National Laboratory, Argonne, IL Keywords: battery materials, lithium, recycling Abstract Use of vehicles with electric drive, which...

304

Lithium-Sulfur Batteries: Development of High Energy Lithium-Sulfur Cells for Electric Vehicle Applications  

SciTech Connect

BEEST Project: Sion Power is developing a lithium-sulfur (Li-S) battery, a potentially cost-effective alternative to the Li-Ion battery that could store 400% more energy per pound. All batteries have 3 key parts—a positive and negative electrode and an electrolyte—that exchange ions to store and release electricity. Using different materials for these components changes a battery’s chemistry and its ability to power a vehicle. Traditional Li-S batteries experience adverse reactions between the electrolyte and lithium-based negative electrode that ultimately limit the battery to less than 50 charge cycles. Sion Power will sandwich the lithium- and sulfur-based electrode films around a separator that protects the negative electrode and increases the number of charges the battery can complete in its lifetime. The design could eventually allow for a battery with 400% greater storage capacity per pound than Li-Ion batteries and the ability to complete more than 500 recharge cycles.

2010-10-01T23:59:59.000Z

305

Advanced Technology Development Program for Lithium-Ion Batteries: Gen 2 Performance Evaluation Final Report  

Science Conference Proceedings (OSTI)

The Advanced Technology Development Program has completed performance testing of the second generation of lithium-ion cells (i.e., Gen 2 cells). The 18650-size Gen 2 cells, with a baseline and variant chemistry, were distributed over a matrix consisting of three states-of-charge (SOCs) (60, 80, and 100% SOC), four temperatures (25, 35, 45, and 55°C), and three life tests (calendar-, cycle-, and accelerated-life). The calendar- and accelerated-life cells were clamped at an open-circuit voltage corresponding to the designated SOC and were subjected to a once-per-day pulse profile. The cycle-life cells were continuously pulsed using a profile that was centered around 60% SOC. Life testing was interrupted every four weeks for reference performance tests (RPTs), which were used to quantify changes in cell degradation as a function of aging. The RPTs generally consisted of C1/1 and C1/25 static capacity tests, a low-current hybrid pulse power characterization test, and electrochemical impedance spectroscopy. The rate of cell degradation generally increased with increasing test temperature, and SOC. It was also usually slowest for the calendar-life cells and fastest for the accelerated-life cells. Detailed capacity-, power-, and impedance-based performance results are reported.

Jon P. Christophersen; Ira Bloom; Edward V. Thomas; Kevin L. Gering; Gary L. Henriksen; Vincent S. Battaglia; David Howell

2006-07-01T23:59:59.000Z

306

Calendar and PHEV Cycle Life Aging of High-Energy, Lithium-Ion Cells Containing Blended Spinel and Layered-Oxide Cathodes  

DOE Green Energy (OSTI)

One hundred seven commercially available, off-the-shelf, 1.2-Ah cells were tested for calendar life and CS cycle- and CD cycle-life using the new USABC PHEV Battery Test Manual. Here, the effects of temperature on calendar life, on CS cycle life, and on CD cycle life; the effects of SOC on calendar life and on CS cycle life; and the effects of rest time on CD cycle life were investigated. The results indicated that the test procedures caused performance decline in the cells in an expected manner, calendar < CS cycling < CD cycling. In some cases, the kinetic law changed with test type, from linear-with-time to about t2. Additionally, temperature was found to stress the cells more than SOC, causing increased changes in performance with increasing temperature.

Jeffrey R. Belt; I. Bloom

2011-12-01T23:59:59.000Z

307

Calendar and PHEV Cycle Life Aging of High-Energy, Lithium-Ion Cells Containing Blended Spinel and Layered Oxide Cathodes  

DOE Green Energy (OSTI)

One hundred seven commercially available, off-the-shelf, 1.2-Ah cells were tested for calendar life and CS cycle- and CD cycle-life using the new USABC PHEV Battery Test Manual. Here, the effects of temperature on calendar life, on CS cycle life, and on CD cycle life; the effects of SOC on calendar life and on CS cycle life; and the effects of rest time on CD cycle life were investigated. The results indicated that the test procedures caused performance decline in the cells in an expected manner, calendar < CS cycling < CD cycling. In some cases, the kinetic law changed with test type, from linear-with-time to about t2. Additionally, temperature was found to stress the cells more than SOC, causing increased changes in performance with increasing temperature.

J. Belt

2011-12-01T23:59:59.000Z

308

SISGR: Linking Ion Solvation and Lithium Battery Electrolyte Properties  

DOE Green Energy (OSTI)

The solvation and phase behavior of the model battery electrolyte salt lithium trifluoromethanesulfonate (LiCF3SO3) in commonly used organic solvents; ethylene carbonate (EC), gamma-butyrolactone (GBL), and propylene carbonate (PC) was explored. Data from differential scanning calorimetry (DSC), Raman spectroscopy, and X-ray diffraction were correlated to provide insight into the solvation states present within a sample mixture. Data from DSC analyses allowed the construction of phase diagrams for each solvent system. Raman spectroscopy enabled the determination of specific solvation states present within a solvent-Ã?Â?Ã?Â?salt mixture, and X-ray diffraction data provided exact information concerning the structure of a solvates that could be isolated Thermal analysis of the various solvent-salt mixtures revealed the phase behavior of the model electrolytes was strongly dependent on solvent symmetry. The point groups of the solvents were (in order from high to low symmetry): C2V for EC, CS for GBL, and C1 for PC(R). The low symmetry solvents exhibited a crystallinity gap that increased as solvent symmetry decreased; no gap was observed for EC-LiTf, while a crystallinity gap was observed spanning 0.15 to 0.3 mole fraction for GBL-LiTf, and 0.1 to 0.33 mole fraction for PC(R)-LiTf mixtures. Raman analysis demonstrated the dominance of aggregated species in almost all solvent compositions. The AGG and CIP solvates represent the majority of the species in solutions for the more concentrated mixtures, and only in very dilute compositions does the SSIP solvate exist in significant amounts. Thus, the poor charge transport characteristics of CIP and AGG account for the low conductivity and transport properties of LiTf and explain why is a poor choice as a source of Li+ ions in a Li-ion battery.

Trulove, Paul C; Foley, Matthew P

2013-03-14T23:59:59.000Z

309

Block copolymer electrolytes for lithium batteries  

E-Print Network (OSTI)

Ethylene Carbonate for Lithium Ion Battery Use. Journal oflithium atoms in lithium-ion battery electrolyte. Chemicalcapacity fading of a lithium-ion battery cycled at elevated

Hudson, William Rodgers

2011-01-01T23:59:59.000Z

310

Effects of Silicon and Carbon Composition on Carbon Nanotubes in Lithium-Ion Batteries Sadie Roberts, Georgia Institute of Technology Georgia Tech SURF 2011 Fellow  

E-Print Network (OSTI)

Effects of Silicon and Carbon Composition on Carbon Nanotubes in Lithium-Ion Batteries Sadie Graduate Mentor: Kara Evanoff Introduction Lithium-ion (Li-ion) batteries are attractive for many] Magasinki, A.; Dixon, P.; Hertzberg, B.; Kvit, A.; Ayala, J.; Yushin, G., "High-performance lithium-ion

Li, Mo

311

Improving the Performance of Lithium Ion Batteries at Low Temperature  

DOE Green Energy (OSTI)

The ability for Li-ion batteries to operate at low temperatures is extremely critical for the development of energy storage for electric and hybrid electric vehicle technologies. Currently, Li-ion cells have limited success in operating at temperature below –10 deg C. Electrolyte conductivity at low temperature is not the main cause of the poor performance of Li-ion cells. Rather the formation of a tight interfacial film between the electrolyte and the electrodes has often been an issue that resulted in a progressive capacity fading and limited discharge rate capability. The objective of our Phase I work is to develop novel electrolytes that can form low interfacial resistance solid electrolyte interface (SEI) films on carbon anodes and metal oxide cathodes. From the results of our Phase I work, we found that the interfacial impedance of Fluoro Ethylene Carbonate (FEC) electrolyte at the low temperature of –20degC is astonishingly low, compared to the baseline 1.2M LiPFEMC:EC:PC:DMC (10:20:10:60) electrolyte. We found that electrolyte formulations with fluorinated carbonate co-solvent have excellent film forming properties and better de-solvation characteristics to decrease the interfacial SEI film resistance and facilitate the Li-ion diffusion across the SEI film. The very overwhelming low interfacial impedance for FEC electrolytes will translate into Li-ion cells with much higher power for cold cranking and high Regen/charge at the low temperature. Further, since the SEI film resistance is low, Li interaction kinetics into the electrode will remain very fast and thus Li plating during Regen/charge period be will less likely to happen.

Trung H. Nguyen; Peter Marren; Kevin Gering

2007-04-20T23:59:59.000Z

312

Evaluation of commercial lithium-ion cells based on composite positive electrode for plug-in hybrid electric vehicle applications. Part II. Degradation mechanism under 2 C cycle aging  

Science Conference Proceedings (OSTI)

Degradation phenomena and inference of their underlying mechanisms during 2 C cycle aging in a cell design comprising {l_brace}LiMn1/3Ni1/3Co1/3O2 + LiMn2O4{r_brace} composite positive electrode are studied and reported in this work. We describe how aging phenomena in the cells were studied and incremental capacity analysis applied to infer cell degradation mechanisms in the cycle aging process. Two stages of degradation were observed in the life cycle under this aging regime. In the first stage, we conclude that loss of lithium inventory was the cause of capacity fade. As a result of such parasitic loss, the cell further suffered from loss of active materials in the second stage, in which the positive electrode kinetics was hampered and the capacity loss accelerated.

Matthieu Dubarry; Cyril Truchot; Bor Yann Liaw; Kevin Gering; Sergiy Sazhin; David Jamison; Christopher Michelbacher

2011-12-01T23:59:59.000Z

313

Metal hydrides: Relevant Materials for Lithium-ion Batteries ...  

Science Conference Proceedings (OSTI)

Reactivity of MgH2 with lithium is a reversible conversion reaction (reversible capacity of 1500 mAh/g) generalized to many hydrides as: MHx + xLi+ + xe- ? M + ...

314

Implementations of electric vehicle system based on solar energy in Singapore assessment of lithium ion batteries for automobiles  

E-Print Network (OSTI)

In this thesis report, both quantitative and qualitative approaches are used to provide a comprehensive analysis of lithium ion (Li-ion) batteries for plug-in hybrid electric vehicle (PHEV) and battery electric vehicle ...

Fu, Haitao

2009-01-01T23:59:59.000Z

315

Cycle Life Studies of Advanced Technology Development Program Gen 1 Lithium Ion Batteries  

SciTech Connect

This report presents the test results of a special calendar-life test conducted on 18650-size, prototype, lithium-ion battery cells developed to establish a baseline chemistry and performance for the Advanced Technology Development Program. As part of electrical performance testing, a new calendar-life test protocol was used. The test consisted of a once-per-day discharge and charge pulse designed to have minimal impact on the cell yet establish the performance of the cell over a period of time such that the calendar life of the cell could be determined. The calendar life test matrix included two states of charge (i.e., 60 and 80%) and four temperatures (40, 50, 60, and 70°C). Discharge and regen resistances were calculated from the test data. Results indicate that both discharge and regen resistance increased nonlinearly as a function of the test time. The magnitude of the discharge and regen resistance depended on the temperature and state of charge at which the test was conducted. The calculated discharge and regen resistances were then used to develop empirical models that may be useful to predict the calendar life or the cells.

Wright, Randy Ben; Motloch, Chester George

2001-03-01T23:59:59.000Z

316

Calendar Life Studies of Advanced Technology Development Program Gen 1 Lithium Ion Batteries  

SciTech Connect

This report presents the test results of a special calendar-life test conducted on 18650-size, prototype, lithium-ion battery cells developed to establish a baseline chemistry and performance for the Advanced Technology Development Program. As part of electrical performance testing, a new calendar-life test protocol was used. The test consisted of a once-per-day discharge and charge pulse designed to have minimal impact on the cell yet establish the performance of the cell over a period of time such that the calendar life of the cell could be determined. The calendar life test matrix included two states of charge (i.e., 60 and 80%) and four temperatures (40, 50, 60, and 70°C). Discharge and regen resistances were calculated from the test data. Results indicate that both discharge and regen resistance increased nonlinearly as a function of the test time. The magnitude of the discharge and regen resistance depended on the temperature and state of charge at which the test was conducted. The calculated discharge and regen resistances were then used to develop empirical models that may be useful to predict the calendar life or the cells.

Wright, Randy Ben; Motloch, Chester George

2001-03-01T23:59:59.000Z

317

Commuter simulation of lithium-ion battery performance in hybrid electric vehicles.  

SciTech Connect

In this study, a lithium-ion battery was designed for a hybrid electric vehicle, and the design was tested by a computer program that simulates driving of a vehicle on test cycles. The results showed that the performance goals that have been set for such batteries by the Partnership for a New Generation of Vehicles are appropriate. The study also indicated, however, that the heat generation rate in the battery is high, and that the compact lithium-ion battery would probably require cooling by a dielectric liquid for operation under conditions of vigorous vehicle driving.

Nelson, P. A.; Henriksen, G. L.; Amine, K.

2000-12-04T23:59:59.000Z

318

Bicyclic imidazolium ionic liquids as potential electrolytes for rechargeable lithium ion batteries  

Science Conference Proceedings (OSTI)

A bicyclic imidazolium ionic liquids, 1-ethyl-2,3-trimethyleneimidazolium bis(tri fluoromethane sulfonyl)imide ([ETMIm][TFSI]), and reference imidazolium compounds, 1-ethyl-3-methylimidazolium bis(trifluoromethane sulfonyl)imide ([EMIm][TFSI]) and 1, 2-dimethyl-3-butylimidazolium bis(trifluoromethane sulfonyl)imide ([DMBIm][TFSI]), were synthesized and investigated as solvents for lithium ion batteries. Although the alkylation at the C-2 position of the imidazolium ring does not affect the thermal stability of the ionic liquids, with or without the presence of 0.5 molar lithium bis(trifluoromethane sulfonyl)imide (LiTFSI), the stereochemical structure of the molecules has shown profound influences on the electrochemical properties of the corresponding ionic liquids. [ETMIm][TFSI] shows better reduction stability than do [EMIm][TFSI] and [DMBIm][TFSI], as confirmed by both linear sweep voltammery (LSV) and theoretical calculation. The Li||Li cell impedance of 0.5M LiTFSI/[ETMIm][TFSI] is stabilized, whereas that of 0.5M LiTFSI/[DMBIm][TFSI] is still fluctuating after 20 hours, indicating a relatively stable solid electrolyte interphase (SEI) is formed in the former. Furthermore, the Li||graphite half-cell based on 0.5M LiTFSI/[BTMIm][TFSI] exhibits reversible capacity of 250mAh g-1 and 70mAh g-1 at 25 C, which increases to 330 mAh g-1 and 250 mAh g-1 at 50 C, under the current rate of C/20 and C/10, respectively. For comparison, the Li||graphite half-cell based on 0.5M LiTFSI/[DMBIm][TFSI] exhibits poor capacity retention under the same current rate at both temperatures.

Liao, Chen [ORNL; Shao, Nan [ORNL; Bell, Jason R [ORNL; Guo, Bingkun [ORNL; Luo, Huimin [ORNL; Jiang, Deen [ORNL; Dai, Sheng [ORNL

2013-01-01T23:59:59.000Z

319

Block copolymer with simultaneous electric and ionic conduction for use in lithium ion batteries  

SciTech Connect

Redox reactions that occur at the electrodes of batteries require transport of both ions and electrons to the active centers. Reported is the synthesis of a block copolymer that exhibits simultaneous electronic and ionic conduction. A combination of Grignard metathesis polymerization and click reaction was used successively to synthesize the block copolymer containing regioregular poly(3-hexylthiophene) (P3HT) and poly(ethylene oxide) (PEO) segments. The P3HT-PEO/LiTFSI mixture was then used to make a lithium battery cathode with LiFePO.sub.4 as the only other component. All-solid lithium batteries of the cathode described above, a solid electrolyte and a lithium foil as the anode showed capacities within experimental error of the theoretical capacity of the battery. The ability of P3HT-PEO to serve all of the transport and binding functions required in a lithium battery electrode is thus demonstrated.

2013-10-08T23:59:59.000Z

320

Studies of ionic liquids in lithium-ion battery test systems  

SciTech Connect

In this work, thermal and electrochemical properties of neat and mixed ionic liquid - lithium salt systems have been studied. The presence of a lithium salt causes both thermal and phase-behavior changes. Differential scanning calorimeter DSC and thermal gravimetric analysis TGA were used for thermal analysis for several imidazolium bis(trifluoromethylsulfonyl)imide, trifluoromethansulfonate, BF{sub 4}, and PF{sub 6} systems. Conductivities and diffusion coefficient have been measured for some selected systems. Chemical reactions in electrode - ionic liquid electrolyte interfaces were studied by interfacial impedance measurements. Lithium-lithium and lithium-carbon cells were studied at open circuit and a charged system. The ionic liquids studied include various imidazolium systems that are already known to be electrochemically unstable in the presence of lithium metal. In this work the development of interfacial resistance is shown in a Li|BMIMBF{sub 4} + LiBF{sub 4}|Li cell as well as results from some cycling experiments. As the ionic liquid reacts with the lithium electrode the interfacial resistance increases. The results show the magnitude of reactivity due to reduction of the ionic liquid electrolyte that eventually has a detrimental effect on battery performance.

Salminen, Justin; Prausnitz, John M.; Newman, John

2006-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Failure modes in high-power lithium-ion batteries for use inhybrid electric vehicles  

DOE Green Energy (OSTI)

The Advanced Technology Development (ATD) Program seeks to aid the development of high-power lithium-ion batteries for hybrid electric vehicles. Nine 18650-size ATD baseline cells were tested under a variety of conditions. The cells consisted of a carbon anode, LiNi{sub 0.8}Co{sub 0.2}O{sub 2} cathode and DEC-EC-LiPF{sub 6} electrolyte, and they were engineered for high-power applications. Selected instrumental techniques such as synchrotron IR microscopy, Raman spectroscopy, scanning electron microscopy, atomic force microscopy, gas chromatography, etc. were used to characterize the anode, cathode, current collectors and electrolyte from these cells. The goal was to identify detrimental processes which lead to battery failure under a high-current cycling regime as well as during storage at elevated temperatures. The diagnostic results suggest that the following factors contribute to the cell power loss: (a) SEI deterioration and non-uniformity on the anode, (b) morphology changes, increase of impedance and phase separation on the cathode, (c) pitting corrosion on the cathode Al current collector, and (d) decomposition of the LiPF{sub 6} salt in the electrolyte at elevated temperature.

Kostecki, R.; Zhang, X.; Ross Jr., P.N.; Kong, F.; Sloop, S.; Kerr, J.B.; Striebel, K.; Cairns, E.; McLarnon, F.

2001-06-22T23:59:59.000Z

322

The Self-Improvement of Lithium-Ion Batteries | Advanced Photon Source  

NLE Websites -- All DOE Office Websites (Extended Search)

Architecture and Viral Disease Architecture and Viral Disease RNA Folding: A Little Cooperation Goes a Long Way A New Phase in Cellular Communication Engineering Thin-Film Oxide Interfaces Novel Materials Become Multifunctional at the Ultimate Quantum Limit Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed The Self-Improvement of Lithium-Ion Batteries NOVEMBER 30, 2012 Bookmark and Share Amorphous titanium oxide nanotubes, upon lithium insertion in a Li-ion battery, self-create the highest capacity cubic lithium titanium oxide structure. The search for clean and green energy in the 21st century requires a better and more efficient battery technology. The key to attaining that goal may

323

Batteries - Lithium-ion - Developing Better High-Energy Batteries for  

NLE Websites -- All DOE Office Websites (Extended Search)

Argonne's Lithium-Ion Battery Technology Offers Reliability, Greater Safety Argonne's Lithium-Ion Battery Technology Offers Reliability, Greater Safety Michael Thackeray holds a model of the molecular structure associated with Argonne's advanced cathode material. Researcher Michael Thackeray holds a model of the molecular structure associated with Argonne's advanced cathode material, a key element of the material licensed to NanoeXa. Argonne's an internationally recognized leader in the development of lithium-battery technology. "Our success reflects a combined effort with a materials group and a technology group to exploit the concept to tackle key safety and energy problems associated with conventional technology," said Argonne's Michael Thackeray. Recently, Argonne announced a licensing agreement with NanoeXa (see

324

Artificial SEI Enables High-Voltage Lithium-ion Batteries | ornl.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Functional Materials for Energy Functional Materials for Energy Artificial SEI Enables High-Voltage Lithium-ion Batteries September 03, 2013 Efficacy of Lipon coating as an artificial SEI for suppression of electrolyte decomposition on a 5V spinel cathode: coulombic efficiency was measured versus cycle numbers at samples with different coating thickness. An artificial solid electrolyte interphase (SEI) of lithium phosphorus oxynitride (Lipon) enables the use of 5V cathode materials with conventional carbonate electrolytes in lithium-ion batteries. Five volt cathode materials, such as LiNi0.5Mn1.5O4, are desirable to provide higher energy, however conventional carbonate electrolytes decompose above 4.5V compromising the battery performance. This work shows that Lipon coating suppresses the electrolyte decomposition, as measured by the

325

Lithium Balance | Open Energy Information  

Open Energy Info (EERE)

navigation, search Name Lithium Balance Place Copenhagen, Denmark Product Lithium ion battery developer. References Lithium Balance1 LinkedIn Connections CrunchBase Profile No...

326

Surface Modification Agents Increase Safety, Security of Lithium-Ion Batteries  

Argonne National Laboratory has developed a process to modify the surface of the active material used in lithium-ion batteries. The modification agent can be a silane, an organometallic compound, or a mixture of two or more of such compounds. Both ...

327

Phase transformations and microstructural design of lithiated metal anodes for lithium-ion rechargeable batteries  

E-Print Network (OSTI)

There has been great recent interest in lithium storage at the anode of Li-ion rechargeable battery by alloying with metals such as Al, Sn, and Sb, or metalloids such as Si, as an alternative to the intercalation of graphite. ...

Limthongkul, Pimpa, 1975-

2002-01-01T23:59:59.000Z

328

Doped LiFePO? cathodes for high power density lithium ion batteries  

E-Print Network (OSTI)

Olivine LiFePO4 has received much attention recently as a promising storage compound for cathodes in lithium ion batteries. It has an energy density similar to that of LiCoO 2, the current industry standard for cathode ...

Bloking, Jason T. (Jason Thompson), 1979-

2003-01-01T23:59:59.000Z

329

Silicon-tin oxynitride glassy composition and use as anode for lithium-ion battery  

DOE Patents (OSTI)

Disclosed are silicon-tin oxynitride glassy compositions which are especially useful in the construction of anode material for thin-film electrochemical devices including rechargeable lithium-ion batteries, electrochromic mirrors, electrochromic windows, and actuators. Additional applications of silicon-tin oxynitride glassy compositions include optical fibers and optical waveguides.

Neudecker, Bernd J. (Knoxville, TN); Bates, John B. (Oak Ridge, TN)

2001-01-01T23:59:59.000Z

330

Arrays of Sealed Silicon Nanotubes As Anodes for Lithium Ion Batteries  

E-Print Network (OSTI)

,12 nanowires13-17 (NW), bundled Si nanotubes,18 and thin films19 as candidate anode materials in lithium ion morphology change. In particular, the axial void spaces of the Si NTs provide additional free surfaces physics, to account for experimental observations and to derive optimized dimen- sions in the tubes

Rogers, John A.

331

Lithium/V6O13 cells using silica nanoparticle-based composite electrolyte  

E-Print Network (OSTI)

Lithium/V6O13 cells using silica nanoparticle-based composite electrolyte Yangxing Li, Peter S) both in liquid electrolyte consisting of oligomeric poly(ethyleneglycol)dimethylether'/lithium bis of suppressing lithium dendrite growth due to the rigidity and immobility of the electrolyte structure

Khan, Saad A.

332

Success Stories: Solid Electrolyte Lithium Ion Batteries - Seeo, Inc.  

NLE Websites -- All DOE Office Websites (Extended Search)

Solid Electrolyte May Usher in a New Generation of Solid Electrolyte May Usher in a New Generation of Rechargeable Lithium Batteries For Vehicles With sky rocketing gasoline prices and exploding laptops, there could not have been a better time for a new rechargeable battery breakthrough. Enter Lawrence Berkeley National Laboratory's (LBNL) nanostructured polymer electrolyte (NPE). NPE is a solid electrolyte designed for use in rechargeable lithium batteries. The unique material was developed by LBNL researchers Nitash Balsara, Hany Eitouni, Enrique Gomez, and Mohit Singh and licensed to startup company Seeo Inc. in 2007. With solid financial backing from Khosla Ventures, located in Menlo Park, California, and an impressive scientific team recruited from LBNL, University of California, Berkeley, and the battery industry, Seeo is now

333

Development of a bipolar cell for lithium production  

SciTech Connect

The authors report development and bench-scale testing of an electrolytic process for reduction of LiOH to lithium metal through an amalgam intermediate. The amalgam is formed in an aqueous-electrolyte cell and stripped in a molten salt cell using a LiI-CsI eutectic at 225 C. Total energy efficiency is >70%. The process obviates high temperature materials problems, chlorine evolution and anhydrous feedstocks. While the principle is proven, sustained operation of the cell is now needed to obtain statistical data on reliability and maintainability.

Cooper, J.F.; Ebbinghaus, B.B.; Peterman, K.; Weinland, S. [Lawrence Livermore National Lab., CA (United States); McKenzie, P. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States)

1995-07-01T23:59:59.000Z

334

A rapid method for the determination of lithium transference numbers  

DOE Green Energy (OSTI)

Lithium ion-conducting polymer electrolytes are of increasing interest for use in lithium-polymer batteries. Lithium transference numbers, the net fraction of current carried by lithium in a cell, are key figures of merit for potential lithium battery electrolytes. The authors describe the Electrophoretic NMR (ENMR) method for the determination of lithium ion transference numbers (T{sub Li}). The work presented is a proof-of-concept of the application of the ENMR method to lithium ion transference measurements for several different lithium salts in gelled electrolytes. The NMR method allows accurate determination of T{sub Li} values, as indicated by the similarity of T{sub Li} in the gelled electrolytes to those in aqueous electrolyte solutions at low salt concentration. Based on calculated tradeoffs of various experimental parameters, they also discuss some conclusions concerning the range of applicability of the method to other electrolytes with lower lithium mobility.

Zawodzinski, T.A. Jr.; Dai, H.; Sanderson, S.; Davey, J.; Uribe, F. [Los Alamos National Lab., NM (United States). Electronics Materials and Device Research Group

1997-05-01T23:59:59.000Z

335

Fused ring and linking groups effect on overcharge protection for lithium-ion batteries.  

DOE Green Energy (OSTI)

The derivatives of 1,3-benzodioxan (DBBD1) and 1,4-benzodioxan (DBBD2) bearing two tert-butyl groups have been synthesized as new redox shuttle additives for overcharge protection of lithium-ion batteries. Both compounds exhibit a reversible redox wave over 4 V vs Li/Li{sup +} with better solubility in a commercial electrolyte (1.2 M LiPF{sub 6}) dissolved in ethylene carbonate/ethyl methyl carbonate (EC/EMC 3/7) than the di-tert-butyl-substituted 1,4-dimethoxybenzene (DDB). The electrochemical stability of DBBD1 and DBBD2 was tested under charge/discharge cycles with 100% overcharge at each cycle in MCMB/LiFePO{sub 4} and Li{sub 4}Ti{sub 5}O{sub 12}/LiFePO{sub 4} cells. DBBD2 shows significantly better performance than DBBD1 for both cell chemistries. The structural difference and reaction energies for decomposition have been studied by density functional calculations.

Weng, W.; Zhang, Z.; Redfern, P. C.; Curtiss, L. A.; Amine, K.

2011-02-01T23:59:59.000Z

336

Modeling the performance and cost of lithium-ion batteries for electric-drive vehicles.  

DOE Green Energy (OSTI)

This report details the Battery Performance and Cost model (BatPaC) developed at Argonne National Laboratory for lithium-ion battery packs used in automotive transportation. The model designs the battery for a specified power, energy, and type of vehicle battery. The cost of the designed battery is then calculated by accounting for every step in the lithium-ion battery manufacturing process. The assumed annual production level directly affects each process step. The total cost to the original equipment manufacturer calculated by the model includes the materials, manufacturing, and warranty costs for a battery produced in the year 2020 (in 2010 US$). At the time this report is written, this calculation is the only publically available model that performs a bottom-up lithium-ion battery design and cost calculation. Both the model and the report have been publically peer-reviewed by battery experts assembled by the U.S. Environmental Protection Agency. This report and accompanying model include changes made in response to the comments received during the peer-review. The purpose of the report is to document the equations and assumptions from which the model has been created. A user of the model will be able to recreate the calculations and perhaps more importantly, understand the driving forces for the results. Instructions for use and an illustration of model results are also presented. Almost every variable in the calculation may be changed by the user to represent a system different from the default values pre-entered into the program. The distinct advantage of using a bottom-up cost and design model is that the entire power-to-energy space may be traversed to examine the correlation between performance and cost. The BatPaC model accounts for the physical limitations of the electrochemical processes within the battery. Thus, unrealistic designs are penalized in energy density and cost, unlike cost models based on linear extrapolations. Additionally, the consequences on cost and energy density from changes in cell capacity, parallel cell groups, and manufacturing capabilities are easily assessed with the model. New proposed materials may also be examined to translate bench-scale values to the design of full-scale battery packs providing realistic energy densities and prices to the original equipment manufacturer. The model will be openly distributed to the public in the year 2011. Currently, the calculations are based in a Microsoft{reg_sign} Office Excel spreadsheet. Instructions are provided for use; however, the format is admittedly not user-friendly. A parallel development effort has created an alternate version based on a graphical user-interface that will be more intuitive to some users. The version that is more user-friendly should allow for wider adoption of the model.

Nelson, P. A.

2011-10-20T23:59:59.000Z

337

Lithium / Sulfur Cells with Long Cycle Life and High Specific Energy  

A team of Berkeley Lab battery researchers led by Elton Cairns has invented an advanced lithium/sulfur (Li/S) cell that, for the first time, offers ...

338

Self-discharge rate of lithium thionyl-chloride cells  

DOE Green Energy (OSTI)

Our low-rate lithium/thionyl-chloride ``D`` cell is required to provide power continuously for up to 10 years. The cell was designed at Sandia National Laboratories and manufactured at Eagle-Picher Industries, Joplin, Missouri. We have conducted accelerated aging studies at elevated temperatures to predict long-term performance of cells fabricated in 1992. Cells using 1.0M LiAlCl{sub 4} electrolyte follow Arrhenius kinetics with an activation energy of 14.6 Kcal/mol. This results in an annual capacity loss to self-discharge of 0.13 Ah at 25 C. Cells using a 1.0M LiAlCl{sub 4}{sm_bullet}SO{sub 2} electrolyte do not follow Arrhenius behavior. The performance of aged cells from an earlier fabrication lot is variable.

Cieslak, W.R.

1993-12-31T23:59:59.000Z

339

Effect of oxide nanoparticles on thermal and mechanical properties of electrospun separators for lithium-ion batteries  

Science Conference Proceedings (OSTI)

This study reports the fabrication and characterization of poly(ethylene oxide) (PEO) and poly(vinylidenefluoride-cochlorotrifluoroethylene) (PVDF-CTFE) nanofibrous separators for lithium-ion batteries loaded with different amounts of fumedsilica and ...

Marco Zaccaria, Chiara Gualandi, Davide Fabiani, Maria Letizia Focarete, Fausto Croce

2012-01-01T23:59:59.000Z

340

Evaluation of Tavorite-Structured Cathode Materials for Lithium-Ion Batteries Using High-Throughput Computing  

E-Print Network (OSTI)

Cathode materials with structure similar to the mineral tavorite have shown promise for use in lithium-ion batteries, but this class of materials is relatively unexplored. We use high-throughput density-functional-theory ...

Mueller, Tim

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Fail Safe Design for Large Capacity Lithium-ion Batteries  

NATIONAL RENEWABLE ENERGY LABORATORY! Challenges for Large LIB Systems 2 • Li-ion batteries are flammable, require expensive manufacturing to reduce defects

342

Low Temperature Electrical Performance Characteristics of Li-Ion Cells  

DOE Green Energy (OSTI)

Advanced rechargeable lithium-ion batteries are presently being developed and commercialized worldwide for use in consumer electronics, military and space applications. The motivation behind these efforts involves, among other things, a favorable combination of energy and power density. For some of the applications the power sources may need to perform at a reasonable rate at subambient temperatures. Given the nature of the lithium-ion cell chemistry the low temperature performance of the cells may not be very good. At Sandia National Laboratories, we have used different electrochemical techniques such as impedance and charge/discharge at ambient and subambient temperatures to probe the various electrochemical processes that are occurring in Li-ion cells. The purpose of this study is to identify the component that reduces the cell performance at subambient temperatures. We carried out 3-electrode impedance measurements on the cells which allowed us to measure the anode and cathode impedances separately. Our impedance data suggests that while the variation in the electrolyte resistance between room temperature and -20"C is negligible, the cathode electrolyte interracial resistance increases substantially in the same temperature span. We believe that the slow interracial charge transfer kinetics at the cathode electrolyte may be responsible for the increase in cell impedance and poor cell performance.

Nagasubramanian, Ganesan

1999-04-29T23:59:59.000Z

343

Lithium-ion Batteries for Stationary Energy Storage  

DOE Green Energy (OSTI)

The use of Li-ion batteries for stationary energy storage systems to complement renewable energy sources such as solar and wind power has recently attracted great interest. Currently available Li-ion battery electrode materials suitable for such stationary applications have been discussed, along with optimum cathode and anode combinations, limitations and future research directions.

Xu, Terrence (Tianren); Wang, Wei; Gordin, Mikhail; Wang, Donghai; Choi, Daiwon

2010-09-01T23:59:59.000Z

344

Safety testing of 18650-style Li-Ion cells  

DOE Green Energy (OSTI)

To address lithium-ion cell safety issues in demanding power applications, electrical and thermal abuse tests were performed on 18650 sized cells. Video and electrically monitored abuse tests in air included short circuit, forced overcharge, forced reversal, and controlled overheating (thermal) modes. Controlled overheating tests to 200 C were performed in a sealed chamber under a helium atmosphere and the gases released from the cell during thermal runaway were analyzed at regular intervals using gas chromatography and mass spectrometry. In addition to alkane and alkene solvent breakdown fragments, significant H{sub 2} was detected and evidence that HF was evolved was also found.

CRAFTS,CHRIS C.; BOREK III,THEODORE T.; MOWRY,CURTIS DALE

2000-06-08T23:59:59.000Z

345

Phosphazene Based Additives for Improvement of Safety and Battery Lifetimes in Lithium-Ion Batteries  

DOE Green Energy (OSTI)

There need to be significant improvements made in lithium-ion battery technology, principally in the areas of safety and useful lifetimes to truly enable widespread adoption of large format batteries for the electrification of the light transportation fleet. In order to effect the transition to lithium ion technology in a timely fashion, one promising next step is through improvements to the electrolyte in the form of novel additives that simultaneously improve safety and useful lifetimes without impairing performance characteristics over wide temperature and cycle duty ranges. Recent efforts in our laboratory have been focused on the development of such additives with all the requisite properties enumerated above. We present the results of the study of novel phosphazene based electrolytes additives.

Mason K Harrup; Kevin L Gering; Harry W Rollins; Sergiy V Sazhin; Michael T Benson; David K Jamison; Christopher J Michelbacher

2011-10-01T23:59:59.000Z

346

An analytical model for predicting the remaining battery capacity of lithium-ion batteries  

E-Print Network (OSTI)

Abstract—Predicting the residual energy of the battery source that powers a portable electronic device is imperative in designing and applying an effective dynamic power management policy for the device. This paper starts up by showing that a 30 % error in predicting the battery capacity of a lithium-ion battery can result in up to 20 % performance degradation for a dynamic voltage and frequency scaling algorithm. Next, this paper presents a closed form analytical expression for predicting the remaining capacity of a lithium-ion battery. The proposed high-level model, which relies on online current and voltage measurements, correctly accounts for the temperature and cycle aging effects. The accuracy of the highlevel model is validated by comparing it with DUALFOIL simulation results, demonstrating a maximum of 5 % error between simulated and predicted data. Index Terms—Accelerated rate capacity, cycle aging and dynamic voltage scaling, remaining battery capacity, temperature. I.

Peng Rong; Student Member; Massoud Pedram

2003-01-01T23:59:59.000Z

347

Carbon-coated silicon nanowire array films for high-performance lithium-ion battery anodes  

Science Conference Proceedings (OSTI)

Carbon-coated silicon nanowire array films prepared by metal catalytic etching of silicon wafers and pyrolyzing of carbon aerogel were used for lithium-ion battery anodes. The films exhibited an excellent first discharge capacity of 3344 ? mAh ? g ? 1 with a Coulombic efficiency of 84% at a rate of 150 ? mA ? g ? 1 between 2 and 0.02 V and a significantly enhanced cycling performance

Rui Huang; Xing Fan; Wanci Shen; Jing Zhu

2009-01-01T23:59:59.000Z

348

Internal Short Circuit Device Helps Improve Lithium-Ion ...  

result in the cells getting very hot, in extreme cases cells go into thermal runaway, igniting the device in which they are installed.

349

Porous electrolyte retainer for molten carbonate fuel cell. [lithium aluminate  

DOE Patents (OSTI)

A porous tile for retaining molten electrolyte within a fuel cell is prepared by sintering particles of lithium aluminate into a stable structure. The tile is assembled between two porous metal plates which serve as electrodes with fuels gases such as H/sub 2/ and CO opposite to oxidant gases such as O/sub 2/ and CO/sub 2/. The tile is prepared with a porosity of 55 to 65% and a pore size distribution selected to permit release of sufficient molten electrolyte to wet but not to flood the adjacent electrodes.

Singh, R.N.; Dusek, J.T.

1979-12-27T23:59:59.000Z

350

Grafted polyelectrolyte membranes for lithium batteries and fuel cells  

DOE Green Energy (OSTI)

Polyelectrolyte materials have been developed for lithium battery systems in response to the severe problems due to salt concentration gradients that occur in composite electrodes (aka membrane-electrode assemblies). Comb branch polymer architectures are described which allow for grafting of appropriate anions on to the polymer and also for cross-linking to provide for appropriate mechanical properties. The interactions of the polymers with the electrode surfaces are critical for the performance of the system and some of the structural features that influence this will be described. Parallels with the fuel cell MEA structures exist and will also be discussed.

Kerr, John B.

2003-06-24T23:59:59.000Z

351

Lithium metal oxide electrodes for lithium batteries  

DOE Patents (OSTI)

An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

Thackeray, Michael M. (Naperville, IL); Kim, Jeom-Soo (Naperville, IL); Johnson, Christopher S. (Naperville, IL)

2008-01-01T23:59:59.000Z

352

Synthesis of Titania Nanotubes for Lithium Ion Batteries  

Science Conference Proceedings (OSTI)

Application of Biomass Waste Materials in the Nano Mineral Synthesis ... Effect of Initial Microstructure on the Processing of Titanium Using Equal ... Effect of Reinforcement Volume Fraction on the Properties of Nanocrystalline Mg .... Sonochemistry as a Tool for Synthesis of Ion-Substituted Calcium Phosphate Nanoparticles.

353

Integrated Lithium-Ion Battery Model Encompassing Multi-Physics in Varied Scales: An Integrated Computer Simulation Tool for Design and Development of EDV Batteries (Presentation)  

Science Conference Proceedings (OSTI)

This presentation discusses the physics of lithium-ion battery systems in different length scales, from atomic scale to system scale.

Kim, G. H.; Smith, K.; Lee, K. J.; Santhanagopalan, S.; Pesaran, A.

2011-01-01T23:59:59.000Z

354

Lithium-aluminum-iron electrode composition  

DOE Patents (OSTI)

A negative electrode composition is presented for use in a secondary electrochemical cell. The cell also includes an electrolyte with lithium ions such as a molten salt of alkali metal halides or alkaline earth metal halides that can be used in high-temperature cells. The cell's positive electrode contains a a chalcogen or a metal chalcogenide as the active electrode material. The negative electrode composition includes up to 50 atom percent lithium as the active electrode constituent in an alloy of aluminum-iron. Various binary and ternary intermetallic phases of lithium, aluminum and iron are formed. The lithium within the intermetallic phase of Al.sub.5 Fe.sub.2 exhibits increased activity over that of lithium within a lithium-aluminum alloy to provide an increased cell potential of up to about 0.25 volt.

Kaun, Thomas D. (Mokena, IL)

1979-01-01T23:59:59.000Z

355

Analysis of the Galvanostatic Intermittent Titration Technique (GITT) as applied to a lithium-Ion porous electrode.  

SciTech Connect

Galvanostatic Intermittent Titration Technique (GITT) experiments were conducted to determine the lithium diffusion coefficient of LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2}, used as the active material in a lithium-ion battery porous composite positive electrode. An electrochemical model, based on concentrated solution porous electrode theory, was developed to analyze the GITT experimental results and compare to the original GITT analytical theory. The GITT experimental studies on the oxide active material were conducted between 3.5 and 4.5 V vs. lithium, with the maximum lithium diffusion coefficient value being 10{sup -10} cm{sup 2} s{sup -1} at 3.85 V. The lithium diffusion coefficient values obtained from this study agree favorably with the values obtained from an earlier electrochemical impedance spectroscopy study.

Dees, D. W.; Kawauchi, S.; Abraham, D. P.; Prakash, J.; Chemical Sciences and Engineering Division; Toyota Central R& D Labs Inc.; Illinois Inst. of Tech.

2009-04-01T23:59:59.000Z

356

The Application of Synchrotron Techniques to the Study of Lithium-ion Batteries  

SciTech Connect

This paper gives a brief review of the application of synchrotron X-ray techniques to the study of lithium-ion battery materials. The two main techniques are X-ray absorption spectroscopy (XAS) and high-resolution X-ray diffraction (XRD). Examples are given for in situ XAS and XRD studies of lithium-ion battery cathodes during cycling. This includes time-resolved methods. The paper also discusses the application of soft X-ray XAS to do ex situ studies on battery cathodes. By applying two signal detection methods, it is possible to probe the surface and the bulk of cathode materials simultaneously. Another example is the use of time-resolved XRD studies of the decomposition of reactions of charged cathodes at elevated temperatures. Measurements were done both in the dry state and in the presence of electrolyte. Brief reports are also given on two new synchrotron techniques. One is inelastic X-ray scattering, and the other is synchrotron X-ray reflectometry studies of the surface electrode interface (SEI) on highly oriented single crystal lithium battery cathode surfaces.

McBreen, J.

2009-07-01T23:59:59.000Z

357

Cyanoethylated compounds as additives in lithium/lithium batteries  

SciTech Connect

The power loss of lithium/lithium ion battery cells is significantly reduced, especially at low temperatures, when about 1% by weight of an additive is incorporated in the electrolyte layer of the cells. The usable additives are organic solvent soluble cyanoethylated polysaccharides and poly(vinyl alcohol). The power loss decrease results primarily from the decrease in the charge transfer resistance at the interface between the electrolyte and the cathode.

Nagasubramanian, Ganesan (Albuquerque, NM)

1999-01-01T23:59:59.000Z

358

Failure Analysis of Commercial Silicon Materials for Lithium-ion ...  

Science Conference Proceedings (OSTI)

Symposium, Energy Storage III: Materials, Systems and Applications Symposium ... Electrochemical impedance spectra (EIS) reveal the possible reasons of unsatisfactory ... High Efficiency Materials for Dye-Sensitized Solar Cells.

359

Design and Fabrication of the Lithium Beam Ion Injector for NDCX-II  

SciTech Connect

A 130 keV injector is developed for the NDCX-II facility. It consists of a 10.9 cm diameter lithium doped alumina-silicate ion source heated to {approx}1300 C and 3 electrodes. Other components include a segmented Rogowski coil for current and beam position monitoring, a gate valve, pumping ports, a focusing solenoid, a steering coil and space for inspection and maintenance access. Significant design challenges including managing the 3-4 kW of power dissipation from the source heater, temperature uniformity across the emitter surface, quick access for frequent ion source replacement, mechanical alignment with tight tolerance, and structural stabilization of the cantilevered 27-inch OD graded HV ceramic column. The injector fabrication is scheduled to complete by May 2011, and assembly and installation is scheduled to complete by the beginning of July. The Neutralized Drift Compression eXperiment (NDCX-II) is for the study of high energy density physics and inertial fusion energy research utilizing a lithium ion (Li+) beam with a current of 93 mA and a pulse length of 500 ns (compressed to 1 ns at the target). The injector is one of the most complicated sections of the NDCX-II accelerator demanding significant design and fabrication resources. It needs to accommodate a relatively large ion source (10.9 cm), a high heat load (3-4 kW) and specific beam optics developed from the physics model. Some specific design challenges are noted in this paper.

Takakuwa, J.

2011-03-01T23:59:59.000Z

360

Improved cell design for lithium alloy/metal sulfide battery  

DOE Patents (OSTI)

The disclosed lithium alloy/iron sulfide cell design provides loop-like positive and negative sheet metal current collectors electrically insulated from one another by separator means, the positive collector being located outwardly of the negative collector. The collectors are initially secured within an open-ended cell housing, which allows for collector pretesting for electrical shorts prior to adding any electrode materials and/or electrolyte to the cell. Separate chambers are defined outwardly of the positive collector and inwardly of the negative collector open respectively in opposite directions toward the open ends of the cell housing; and positive and negative electrode materials can be extruded into these respective chambers via the opposite open housing ends. The chambers and cell housing ends can then be sealed closed. A cross wall structurally reinforces the cell housing and also thereby defines two cavities, and paired positive and negative collectors are disposed in each cavity and electrically connected in parallel. The cell design provides for a high specific energy output and improved operating life in that any charge-discharge cycle swelling of the positive electrode material will be inwardly against only the positive collector to minimize shorts caused by the collectors shifting relative to one another.

Kaun, T.D.

1984-03-30T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Cell design for lithium alloy/metal sulfide battery  

DOE Patents (OSTI)

The disclosed lithium alloy/iron sulfide cell design provides loop-like positive and negative sheet metal current collectors electrically insulated from one another by separator means, the positive collector being located outwardly of the negative collector. The collectors are initially secured within an open-ended cell housing, which allows for collector pretesting for electrical shorts prior to adding any electrode materials and/or electrolyte to the cell. Separate chambers are defined outwardly of the positive collector and inwardly of the negative collector open respectively in opposite directions toward the open ends of the cell housing; and positive and negative electrode materials can be extruded into these respective chambers via the opposite open housing ends. The chambers and cell housing ends can then be sealed closed. A cross wall structurally reinforces the cell housing and also thereby defines two cavities, and paired positive and negative collectors are disposed in each cavity and electrically connected in parallel. The cell design provides for a high specific energy output and improved operating life in that any charge-discharge cycle swelling of the positive electrode material will be inwardly against only the positive collector to minimize shorts caused by the collectors shifting relative to one another.

Kaun, Thomas D. (New Lennox, IL)

1985-01-01T23:59:59.000Z

362

Magnetism in Lithium–Oxygen Discharge Product  

SciTech Connect

Nonaqueous lithium–oxygen batteries have a much superior theoretical gravimetric energy density compared to conventional lithium-ion batteries, and thus could render long-range electric vehicles a reality. A molecular-level understanding of the reversible formation of lithium peroxide in these batteries, the properties of major/minor discharge products, and the stability of the nonaqueous electrolytes is required to achieve successful lithium–oxygen batteries. We demonstrate that the major discharge product formed in the lithium–oxygen cell, lithium peroxide, exhibits a magnetic moment. These results are based on dc-magnetization measurements and a lithium– oxygen cell containing an ether-based electrolyte. The results are unexpected because bulk lithium peroxide has a significant band gap. Density functional calculations predict that superoxide- type surface oxygen groups with unpaired electrons exist on stoichiometric lithium peroxide crystalline surfaces and on nanoparticle surfaces; these computational results are consistent with the magnetic measurement of the discharged lithium peroxide product as well as EPR measurements on commercial lithium peroxide. The presence of superoxide-type surface oxygen groups with spin can play a role in the reversible formation and decomposition of lithium peroxide as well as the reversible formation and decomposition of electrolyte molecules.

Lu, Jun; Jung, Hun-Ji; Lau, Kah Chun; Zhang, Zhengcheng; Schlueter, John A.; Du, Peng; Assary, Rajeev S.; Greeley, Jeffrey P.; Ferguson, Glen A.; Wang, Hsien-Hau; Hassoun, Jusef; Iddir, Hakim; Zhou, Jigang; Zuin, Lucia; Hu, Yongfeng; Sun, Yang-Kook; Scrosati, Bruno; Curtiss, Larry A.; Amine, Khalil

2013-05-13T23:59:59.000Z

363

Voltage, Stability and Diffusion Barrier Differences between Sodium-ion and Lithium-ion Intercalation Materials  

E-Print Network (OSTI)

To evaluate the potential of Na-ion batteries, we contrast in this work the difference between Na-ion and Li-ion based intercalation chemistries in terms of three key battery properties—voltage, phase stability and diffusion ...

Ong, Shyue Ping

364

Anode material for lithium batteries  

DOE Patents (OSTI)

Primary and secondary Li-ion and lithium-metal based electrochemical cell systems. The suppression of gas generation is achieved through the addition of an additive or additives to the electrolyte system of respective cell, or to the cell itself whether it be a liquid, a solid- or plasticized polymer electrolyte system. The gas suppression additives are primarily based on unsaturated hydrocarbons.

Belharouak, Ilias (Westmont, IL); Amine, Khalil (Downers Grove, IL)

2012-01-31T23:59:59.000Z

365

Anode material for lithium batteries  

DOE Patents (OSTI)

Primary and secondary Li-ion and lithium-metal based electrochemical cell system. The suppression of gas generation is achieved through the addition of an additive or additives to the electrolyte system of respective cell, or to the cell itself whether it be a liquid, a solid- or plastized polymer electrolyte system. The gas suppression additives are primarily based on unsaturated hydrocarbons.

Belharouak, Ilias (Bolingbrook, IL); Amine, Khalil (Downers Grove, IL)

2008-06-24T23:59:59.000Z

366

Anode material for lithium batteries  

DOE Patents (OSTI)

Primary and secondary Li-ion and lithium-metal based electrochemical cell systems. The suppression of gas generation is achieved through the addition of an additive or additives to the electrolyte system of respective cell, or to the cell itself whether it be a liquid, a solid- or plasticized polymer electrolyte system. The gas suppression additives are primarily based on unsaturated hydrocarbons.

Belharouak, Ilias (Bolingbrook, IL); Amine, Khalil (Oak Brook, IL)

2011-04-05T23:59:59.000Z

367

Lithium-ferrate-based cathodes for molten carbonate fuel cells  

DOE Green Energy (OSTI)

Argonne National Laboratory is developing advanced cathodes for pressurized operation of the molten carbonate fuel cell (MCFC) at approximately 650 degrees Centigrade. These cathodes are based on lithium ferrate (LiFeO[sub 2]) which is attractive because of its very low solubility in the molten (Li,K)[sub 2]CO[sub 3] electrolyte. Because of its high resistivity, LiFeO[sub 2] cannot be used as a direct substitute for NiO. Cation substitution is, therefore, necessary to decrease resistivity. The effect of cation substitution on the resistivity and deformation of LiFeO[sub 2] was determined. The substitutes were chosen because their respective oxides as well as LiFeO[sub 2] crystallize with the rock-salt structure.

Lanagan, M.T.; Wolfenstine, J. [Argonne National Lab., IL (United States). Energy Technology Div.; Bloom, I.; Kaun, T.D.; Krumpelt, M. [Argonne National Lab., IL (United States). Chemical Technology Div.

1996-12-31T23:59:59.000Z

368

Approach to make macroporous metal sheets as current collectors for lithium-ion batteries  

SciTech Connect

A new approach and simple method is described to produce macroporous metal sheet as current collector for anode in lithium ion battery. This method, based on slurry blending, tape casting, sintering, and reducing of metal oxides, produces a uniform, macroporous metal sheet. Silicon film sputter-coated on such porous copper substrate shows much higher capacity and longer cycle life than on smooth Cu foil. This methodology produces very limited wastes and is also adaptable to many other materials. It is easy for industrial scale production.

Xu, Wu; Canfield, Nathan L.; Wang, Deyu; Xiao, Jie; Nie, Zimin; Li, Xiaohong S.; Bennett, Wendy D.; Bonham, Charles C.; Zhang, Jiguang

2010-05-05T23:59:59.000Z

369

Organic oxalate as leachant and precipitant for the recovery of valuable metals from spent lithium-ion batteries  

Science Conference Proceedings (OSTI)

Graphical abstract: Display Omitted Highlights: Black-Right-Pointing-Pointer Vacuum pyrolysis as a pretreatment was used to separate cathode material from aluminum foils. Black-Right-Pointing-Pointer Cobalt and lithium can be leached using oxalate while cobalt can be directly precipitated as cobalt oxalate. Black-Right-Pointing-Pointer Cobalt and lithium can be separated efficiently from each other only in the oxalate leaching process. Black-Right-Pointing-Pointer High reaction efficiency of LiCoO{sub 2} was obtained with oxalate. - Abstract: Spent lithium-ion batteries containing lots of strategic resources such as cobalt and lithium are considered as an attractive secondary resource. In this work, an environmentally compatible process based on vacuum pyrolysis, oxalate leaching and precipitation is applied to recover cobalt and lithium from spent lithium-ion batteries. Oxalate is introduced as leaching reagent meanwhile as precipitant which leaches and precipitates cobalt from LiCoO{sub 2} and CoO directly as CoC{sub 2}O{sub 4}{center_dot}2H{sub 2}O with 1.0 M oxalate solution at 80 Degree-Sign C and solid/liquid ratio of 50 g L{sup -1} for 120 min. The reaction efficiency of more than 98% of LiCoO{sub 2} can be achieved and cobalt and lithium can also be separated efficiently during the hydrometallurgical process. The combined process is simple and adequate for the recovery of valuable metals from spent lithium-ion batteries.

Sun Liang [College of Chemistry and Chemical Engineering, Central South University, Changsha 410083 (China); Key Laboratory of Resources Chemistry of Nonferrous Metals, Central South University, Ministry of Education of the People's Republic of China (China); Qiu Keqiang, E-mail: qiuwhs@sohu.com [College of Chemistry and Chemical Engineering, Central South University, Changsha 410083 (China); Key Laboratory of Resources Chemistry of Nonferrous Metals, Central South University, Ministry of Education of the People's Republic of China (China)

2012-08-15T23:59:59.000Z

370

Electrodeposition of Ni5Sb2 nanowires array and its application as a high-performance anode material for lithium ion batteries  

Science Conference Proceedings (OSTI)

Single crystal Ni"5Sb"2 nanowires array is synthesized by direct-current electrodeposition technique. The initial specific discharge and charge capacity of the as-produced Ni"5Sb"2 nanowires array electrode as an anode material for lithium-ion batteries ... Keywords: Anode, Array structure, Charge/discharge capacity, Lithium-ion batteries, Nanowires

You-Wen Yang; Tian-Ying Li; Fei Liu; Wen-Bin Zhu; Xue-Liang Li; Yu-Cheng Wu; Ming-Guang Kong

2013-04-01T23:59:59.000Z

371

Comparative study of a structured neural network and an extended Kalman filter for state of health determination of lithium-ion batteries in hybrid electricvehicles  

Science Conference Proceedings (OSTI)

State of health (SOH) determination becomes an increasingly important issue for a safe and reliable operation of lithium-ion batteries in hybrid electric vehicles (HEVs). Characteristic performance parameters as capacity and resistance change over lifetime ... Keywords: Extended Kalman filter, Hybrid electric vehicle, Internal resistance estimation, Lithium-ion batteries, State of health, Structured neural networks

D. Andre, A. Nuhic, T. Soczka-Guth, D. U. Sauer

2013-03-01T23:59:59.000Z

372

Design and Simulation of Lithium Rechargeable Batteries  

E-Print Network (OSTI)

The LiNiOiCarbon Lithium-Ion Battery," S. S. lonics, 69,238-the mid-1980's, the lithium-ion battery based on a carboncommercialization of the lithium-ion battery, several other

Doyle, C.M.

2010-01-01T23:59:59.000Z

373

Effects of Entropy Changes in Anode and Cathode on Thermo Behavior of Lithium Ion Batteries  

SciTech Connect

The entropies (?S) in various cathode and anode materials, as well as complete lithium ion bat-teries, were investigated by Electrochemical Thermodynamic Measurement System (ETMS). A thermodynamic model based on the fundamental properties of individual electrodes is used to obtain the transient and equilibrium temperature distribution of lithium ion batteries. The results from theoretical simulations are compared with the results obtained in experimental measure-ments. It is found that detailed shape of the entropy curves strongly depends on the manufac-turer of the materials even for the same nominal compositions. LiCoO2 has a much larger en-tropy change than those of LiNixCoyMnzO2. This means that LiNixCoyMnzO2 is much more thermodynamically stable than LiCoO2. The temperatures around the positive terminal of a prismatic battery are consistently higher than those at the negative terminal. When all other simulation parameters are the same, the effects of using battery-averaged entropy in the simulation tends to overestimate the predicted temperatures than using individual entropies for anode and cathode.

Williford, Ralph E.; Vishwanathan, Vilanyur V.; Zhang, Jiguang

2009-04-01T23:59:59.000Z

374

Target diagnostics for intense lithium ion hohlraum experiments on PBFA II  

SciTech Connect

A review of the diagnostics used at Sandia National Laboratories to measure the parameters of intense lithium ion-beam hohlraum target experiments on PBFA II will be presented. This diagnostic package contains an extensive suite of x-ray spectral and imaging diagnostics that enable measurements of target temperature and x-ray output. The x-ray diagnostics include time-integrated and time-resolved pinhole cameras, energy-resolved I-D streaked imaging, diagnostics, time-integrated and time-resolved grazing, incidence spectrographs, a transmission grating spectrograph, an elliptical crystal spectrograph, a bolometer array, an eleven-element x-ray diode (XRD) array, and an eleven-element PIN diode detector array. The incident Li beam symmetry and an estimate of incident Li beam power density can be measured from ion beam-induced characteristic x-ray line emission and neutron emission.

Leeper, R.J.; Bailey, J.E.; Carlson, A.L. [and others

1994-12-31T23:59:59.000Z

375

Block copolymer electrolytes for lithium batteries  

E-Print Network (OSTI)

in the energy equation, battery capacity, is defined as theperformance and capacity fading of a lithium-ion batteryof large-capacity lithium- ion battery systems. With new

Hudson, William Rodgers

2011-01-01T23:59:59.000Z

376

NREL Enhances the Performance of a Lithium-Ion Battery Cathode (Fact Sheet), Innovation: The Spectrum of Clean Energy Innovation, NREL (National Renewable Energy Laboratory)  

NLE Websites -- All DOE Office Websites (Extended Search)

Enhances the Performance of Enhances the Performance of a Lithium-Ion Battery Cathode Scientists from NREL and the University of Toledo have combined theoretical and experimental studies to demonstrate a promising approach to significantly enhance the performance of lithium iron phosphate (LiFePO 4 ) cathodes for lithium-ion batteries. In the most common commercial design for lithium-ion (Li-ion) batteries, the positive electrode or cathode is lithium cobalt oxide (LiCoO 2 ). This material exhibits high electrical conductivity, meaning that it can transport electrons very effectively. However, the cobalt in LiCoO 2 has at least two detrimental characteristics-it is relatively expensive, which leads to higher battery costs, and it is toxic, which poses potential environmental and safety issues.

377

Observations of Oxygen Ion Behavior in the Lithium-Based Electrolytic Reduction of Uranium Oxide  

Science Conference Proceedings (OSTI)

Parametric studies were performed on a lithium-based electrolytic reduction process at bench-scale to investigate the behavior of oxygen ions in the reduction of uranium oxide for various electrochemical cell configurations. Specifically, a series of eight electrolytic reduction runs was performed in a common salt bath of LiCl – 1 wt% Li2O. The variable parameters included fuel basket containment material (i.e., stainless steel wire mesh and sintered stainless steel) and applied electrical charge (i.e., 75 – 150% of the theoretical charge for complete reduction of uranium oxide in a basket to uranium metal). Samples of the molten salt electrolyte were taken at regular intervals throughout each run and analyzed to produce a time plot of Li2O concentrations in the bulk salt over the course of the runs. Following each run, the fuel basket was sectioned and the fuel was removed. Samples of the fuel were analyzed for the extent of uranium oxide reduction to metal and for the concentration of salt constituents, i.e., LiCl and Li2O. Extents of uranium oxide reduction ranged from 43 – 70% in stainless steel wire mesh baskets and 8 – 33 % in sintered stainless steel baskets. The concentrations of Li2O in the salt phase of the fuel product from the stainless steel wire mesh baskets ranged from 6.2 – 9.2 wt%, while those for the sintered stainless steel baskets ranged from 26 – 46 wt%. Another series of tests was performed to investigate the dissolution of Li2O in LiCl at 650 °C across various cathode containment materials (i.e., stainless steel wire mesh, sintered stainless steel and porous magnesia) and configurations (i.e., stationary and rotating cylindrical baskets). Dissolution of identical loadings of Li2O particulate reached equilibrium within one hour for stationary stainless steel wire mesh baskets, while the same took several hours for sintered stainless steel and porous magnesia baskets. Rotation of an annular cylindrical basket of stainless steel wire mesh accelerated the Li2O dissolution rate by more than a factor of six.

Steven D. Herrmann; Shelly X. Li; Brenda E. Serrano-Rodriguez

2009-09-01T23:59:59.000Z

378

Lithium Ion Transport Mechanism in Ternary Polymer Electrolyte-Ionic Liquid Mixtures - A Molecular Dynamics Simulation Study  

E-Print Network (OSTI)

The lithium transport mechanism in ternary polymer electrolytes, consisting of PEO/LiTFSI and various fractions of the ionic liquid N-methyl-N-propylpyrrolidinium bis(trifluoromethane)sulfonimide, are investigated by means of MD simulations. This is motivated by recent experimental findings [Passerini et al., Electrochim. Acta 2012, 86, 330-338], which demonstrated that these materials display an enhanced lithium mobility relative to their binary counterpart PEO/LiTFSI. In order to grasp the underlying microscopic scenario giving rise to these observations, we employ an analytical, Rouse-based cation transport model [Maitra at al., PRL 2007, 98, 227802], which has originally been devised for conventional polymer electrolytes. This model describes the cation transport via three different mechanisms, each characterized by an individual time scale. It turns out that also in the ternary electrolytes essentially all lithium ions are coordinated by PEO chains, thus ruling out a transport mechanism enhanced by the presence of ionic-liquid molecules. Rather, the plasticizing effect of the ionic liquid contributes to the increased lithium mobility by enhancing the dynamics of the PEO chains and consequently also the motion of the attached ions. Additional focus is laid on the prediction of lithium diffusion coefficients from the simulation data for various chain lengths and the comparison with experimental data, thus demonstrating the broad applicability of our approach.

Diddo Diddens; Andreas Heuer

2012-11-14T23:59:59.000Z

379

A Simulation Study of the Lithium Ion Transport Mechanism in Ternary Polymer Electrolytes - The Critical Role of the Segmental Mobility  

E-Print Network (OSTI)

We present an extensive molecular dynamics (MD) simulation study of the lithium ion transport in ternary polymer electrolytes consisting of poly(ethylene oxide) (PEO), lithium-bis(trifluoromethane)sulfonimide (LiTFSI) and the ionic liquid N-methyl-N-propylpyrrolidinium bis(trifluoromethane)sulfonimide (PYR13TFSI). In particular, we focus on two different strategies by which the ternary electrolytes can be devised, namely by (a) adding the ionic liquid to PEO20LiTFSI, and (b) substituting the PEO chains in PEO20LiTFSI by the ionic liquid. In order to grasp the changes of the overall lithium transport mechanism, we employ an analytical, Rouse-based cation transport model (Maitra et al., Phys. Rev. Lett., 2007, 98, 227802), which has originally been devised for binary PEO-based electrolytes. This model distinguishes three different microscopic transport mechanisms, each quantified by an individual time scale. In the course of our analysis, we extend this mathematical description to account for an entirely new transport mechanism, namely the TFSI-supported diffusion of lithium ions decoupled from the PEO chains, which emerges for certain stoichiometries. We find that the segmental mobility plays a decisive role in PEO-based polymer electrolytes. That is, whereas the addition of the ionic liquid to PEO20LiTFSI plasticizes the polymer network and thus also increases the lithium diffusion, the amount of free, mobile ether oxygens reduces when substituting the PEO chains by the ionic liquid, which compensates the plasticizing effect. In total, our observations allow us to formulate some general principles about the lithium ion transport mechanism in ternary polymer electrolytes. Moreover, our insights also shed light on recent experimental observations (Joost et al., Electrochim. Acta, 2012, 86, 330).

Diddo Diddens; Andreas Heuer

2012-11-14T23:59:59.000Z

380

Ion transport through cell membrane channels  

E-Print Network (OSTI)

We discuss various models of ion transport through cell membrane channels. Recent experimental data shows that sizes of ion channels are compared to those of ions and that only few ions may be simultaneously in any single channel. Theoretical description of ion transport in such channels should therefore take into account interactions between ions and between ions and channel proteins. This is not satisfied by macroscopic continuum models based on Poisson-Nernst-Planck equations. More realistic descriptions of ion transport are offered by microscopic Brownian and molecular dynamics. One should also take into account a dynamical character of the channel structure. This is not yet addressed in the literature

Jan Gomulkiewicz; Jacek Miekisz; Stanislaw Miekisz

2007-06-05T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Multiscale Multiphysics Lithium-Ion Battery Model with Multidomain Modular Framework  

Science Conference Proceedings (OSTI)

Lithium-ion batteries (LIBs) powering recent wave of personal ubiquitous electronics are also believed to be a key enabler of electrification of vehicle powertrain on the path toward sustainable transportation future. Over the past several years, National Renewable Energy Laboratory (NREL) has developed the Multi-Scale Multi-Domain (MSMD) model framework, which is an expandable platform and a generic modularized flexible framework resolving interactions among multiple physics occurring in varied length and time scales in LIB[1]. NREL has continued to enhance the functionality of the framework and to develop constituent models in the context of the MSMD framework responding to U.S. Department of Energy's CAEBAT program objectives. This talk will introduce recent advancements in NREL's LIB modeling research in regards of scale-bridging, multi-physics integration, and numerical scheme developments.

Kim, G. H.

2013-01-01T23:59:59.000Z

382

Mesoporous carbon -Cr2O3 composite as an anode material for lithium ion batteries  

SciTech Connect

Mesoporous carbon-Cr2O3 (M-C-Cr2O3) composite was prepared by co-assembly of in-situ formed phenolic resin, chromium precursor, and Pluronic block copolymer under acidic conditions, followed by carbonization at 750oC under Argon. The TEM results confirmed that the Cr2O3 nanoparticles, ranging from 10 to 20 nm, were well dispersed in the matrix of mesoporous carbon. The composite exhibited an initial reversible capacity of 710 mAh g-1 and good cycling stability, which is mainly due to the synergic effects of carbons within the composites, i.e. confining the crystal growth of Cr2O3 during the high temperature treatment step and buffering the volume change of Cr2O3 during the cycling step. This composite material is a promising anode material for lithium ion batteries.

Guo, Bingkun [ORNL; Chi, Miaofang [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL

2012-01-01T23:59:59.000Z

383

Six Thousand Electrochemical Cycles of Double-Walled Silicon Nanotube Anodes for Lithium Ion Batteries  

DOE Green Energy (OSTI)

Despite remarkable progress, lithium ion batteries still need higher energy density and better cycle life for consumer electronics, electric drive vehicles and large-scale renewable energy storage applications. Silicon has recently been explored as a promising anode material for high energy batteries; however, attaining long cycle life remains a significant challenge due to materials pulverization during cycling and an unstable solid-electrolyte interphase. Here, we report double-walled silicon nanotube electrodes that can cycle over 6000 times while retaining more than 85% of the initial capacity. This excellent performance is due to the unique double-walled structure in which the outer silicon oxide wall confines the inner silicon wall to expand only inward during lithiation, resulting in a stable solid-electrolyte interphase. This structural concept is general and could be extended to other battery materials that undergo large volume changes.

Wu, H

2011-08-18T23:59:59.000Z

384

Lithium Insertion Chemistry of Some Iron Vanadates  

E-Print Network (OSTI)

in A. Nazri, G.Pistoia (Eds. ), Lithium batteries, Science &structure materials in lithium cells, for a lower limitLithium Insertion Chemistry of Some Iron Vanadates Sébastien

Patoux, Sebastien; Richardson, Thomas J.

2008-01-01T23:59:59.000Z

385

STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES  

E-Print Network (OSTI)

material prepared by molten- salt synthesis. Journal ofthe sodium for lithium in a molten salt. 13 The large ionic

Wilcox, James D.

2010-01-01T23:59:59.000Z

386

Improve Performance and Reduce Cost of Any Lithium-Ion Battery  

TM Microstructured components for high-performance lithium batteries www.porouspower.com Symmetrix™ - Improve Performance & Reduce Cost of Any ...

387

Comparative costs of flexible package cells and rigid cells for lithium-ionhybrid electric vehicle batteries.  

DOE Green Energy (OSTI)

We conducted a design study to compare the manufacturing costs at a level of 100,000 hybrid vehicle batteries per year for flexible package (Flex) cells and for rigid aluminum container (Rigid) cells. Initially, the Rigid cells were considered to have welded closures and to be deep-drawn containers of about the same shape as the Flex cells. As the study progressed, the method of fabricating and sealing the Rigid cells was expanded to include lower cost options including double seaming and other mechanically fastened closures with polymer sealants. Both types of batteries were designed with positive electrodes containing Li(Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3})O{sub 2} and graphite negative electrodes. The use of a different combination of lithium-ion electrodes would have little effect on the difference in costs for the two types of cells. We found that 20-Ah cells could be designed with excellent performance and heat rejection capabilities for either type of cell. Many parts in the design of the Flex cells are identical or nearly identical to those of the Rigid Cell, so for these features there would be no difference in the cost of manufacturing the two types of batteries. We judged the performance, size and weight of the batteries to be sufficiently similar that the batteries would have the same value for their application. Some of the design features of the Flex cells were markedly different than those of the deep-drawn and welded Rigid cells and would result in significant cost savings. Fabrication and processing steps for which the Flex cells appear to have a cost advantage over these Rigid cells are (1) container fabrication and sealing, (2) terminal fabrication and sealing, and (3) intercell connections. The costs of providing cooling channels adjacent to the cells and for module and battery hardware appear to favor Rigid cell batteries slightly. Overall, Flex cell batteries appear to have an advantage of about $1.20-$3.70 per cell for a 25-kW Battery of 20 cells or about $24 to $74 per battery. Container experts assisted with this study, including a paid consultant and personnel at container manufacturing companies. Some of the companies are considering entering the business of manufacturing containers for hybrid vehicle battery manufacturers. For this reason they provided valuable guidance on overall approaches to reducing the costs of the cell containers. They have retained the description of some specific designs and procedures for future possible work with battery manufacturers, with whom they are now in contact. Through the guidance of these experts, we determined that a new type of container could be manufactured that would have the best features of performance and low cost of both the Rigid and Flex containers. For instance, the aluminum layer in a tri-layer sheet can be sufficiently thick to form a rigid container that can be fabricated in two halves, much like a Flex container, and mechanically joined at the edges for strength. In addition to the mechanical joint, this container can be sealed at the edges, much like a Flex container, by means of an inner polymer liner that can be heat-sealed or ultrasonically welded. The terminals can be flat strips of metal sealed into the top of the container as part of the edge sealing of the container, as for the Flex cell. Ridges can be stamped into one side of the container to provide cooling channels and the exterior layer of the container stock can be coated with a thin, electrically insulating, polymer layer. We expect this type of container will provide excellent sealing and durability and be less expensive than either the Flex or the Rigid container, which the study initially considered. A major cost for the original Rigid container is the welding required for sealing the container. However, the welding of the current collector tabs to the terminal piece may be even more complex and costly than welding the container. It is important, therefore, to develop an inexpensive procedure for attachment of the foils to the terminal pieces. A lower-cost procedure, such as

Nelson, P. A.; Jansen, A. N.

2006-11-28T23:59:59.000Z

388

Fabrication of carbon microcapsules containing silicon nanoparticles-carbon nanotubes nanocomposite by sol-gel method for anode in lithium ion battery  

Science Conference Proceedings (OSTI)

Carbon microcapsules containing silicon nanoparticles (Si NPs)-carbon nanotubes (CNTs) nanocomposite (Si-CNT-C) have been fabricated by a surfactant mediated sol-gel method followed by a carbonization process. Silicon nanoparticles-carbon nanotubes (Si-CNT) nanohybrids were produced by a wet-type beadsmill method. To obtain Si-CNT nanocomposites with spherical morphologies, a silica precursor (tetraethylorthosilicate, TEOS) and polymer (PMMA) mixture was employed as a structure-directing medium. Thus the Si-CNT/Silica-Polymer microspheres were prepared by an acid catalyzed sol-gel method. Then a carbon precursor such as polypyrrole (PPy) was incorporated onto the surfaces of pre-existing Si-CNT/silica-polymer to generate Si-CNT/Silica-Polymer-PPy microspheres. Subsequent thermal treatment of the precursor followed by wet etching of silica produced Si-CNT-C microcapsules. The intermediate silica/polymer must disappear during the carbonization and etching process resulting in the formation of an internal free space. The carbon precursor polymer should transform to carbon shell to encapsulate remaining Si-CNT nanocomposites. Therefore, hollow carbon microcapsules containing Si-CNT nanocomposites could be obtained (Si-CNT-C). The successful fabrication was confirmed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). These final materials were employed for anode performance improvement in lithium ion battery. The cyclic performances of these Si-CNT-C microcapsules were measured with a lithium battery half cell tests. - Graphical Abstract: Carbon microcapsules containing silicon nanoparticles (Si NPs)-carbon nanotubes (CNTs) nanocomposite (Si-CNT-C) have been fabricated by a surfactant mediated sol-gel method. Highlights: > Polymeric microcapsules containing Si-CNT transformed to carbon microcapsules. > Accommodate volume changes of Si NPs during Li ion charge/discharge. > Sizes of microcapsules were controlled by experimental parameters. > Lithium storage capacity and coulombic efficiency were demonstrated. > Use of sol-gel procedure as intermediate reaction.

Bae, Joonwon, E-mail: joonwonbae@gmail.com [Samsung Advanced Institute of Technology, Yong-In City 446-712, Gyeong-Gi Province (Korea, Republic of)

2011-07-15T23:59:59.000Z

389

The UC Davis Emerging Lithium Battery Test Project  

E-Print Network (OSTI)

Miller, M. , Emerging Lithium-ion Battery Technologies forSymposium on Large Lithium-ion Battery Technology andAltairnano EIG Lithium-ion battery modules available for

Burke, Andy; Miller, Marshall

2009-01-01T23:59:59.000Z

390

Atomic resolution of lithium ions in LiCoO{sub 2}  

SciTech Connect

LiCoO{sub 2} is the most common lithium storage material used as positive electrode in lithium rechargeable batteries. Ordering of lithium and vacancies has a profound effect on the physical properties of Li{sub x}CoO{sub 2} and the electrochemical performances of lithium batteries. An exit surface wave (ESW) phase image reconstructed from experimental images obtained on the LBNL One-Angstrom Microscope (OAM) shows all three types of atoms in LiCoO{sub 2}.

Shao-Horn, Yang; Croguennec, Laurence; Delmas, Claude; Nelson, E. Chris; O' Keefe, Michael A.

2003-06-05T23:59:59.000Z

391

Titanium Oxides Thin Film Anodes for All-Solid-State Lithium Ion ...  

Science Conference Proceedings (OSTI)

Metallic lithium is not a suitable anode material for all-solid-state thin film batteries ... Application of Biomass Waste Materials in the Nano Mineral Synthesis.

392

Layered Li1+x(Ni0.425Mn0.425Co0.15)1xO2 Positive Electrode Materials for Lithium-Ion Batteries  

E-Print Network (OSTI)

Layered Li1+x(Ni0.425Mn0.425Co0.15)1­xO2 Positive Electrode Materials for Lithium-Ion Batteries range decreased with overlithiation Keywords : Although LiCoO2 is suitable for the lithium-ion battery by Ohzuku et al. to deliver a high discharge capacity close to 200 mAh/g,21 a lot of research in the lithium-ion

Paris-Sud XI, Université de

393

Enhanced Lithium-Ion Intercalation Properties of V[subscript 2]O[subscript 5] Xerogel Electrodes with Surface Defects  

SciTech Connect

V{sub 2}O{sub 5} xerogel films were fabricated by casting V{sub 2}O{sub 5} sols onto fluorine-doped tin oxide (FTO) glass substrates and annealing at 300 C for 3 h in different annealing atmospheres of air and nitrogen. Films prepared in different annealing conditions possess different grain sizes and crystallinity, while the vanadium ion oxidation state also varies, as identified by X-ray absorption spectroscopy. A nitrogen annealing atmosphere induces the presence of defects, such as V{sup 4+} ions, and associated oxygen vacancies. Thus, the presence of defects, whether on the film surface or in the bulk, can be controlled by using air and nitrogen annealing atmospheres in the proper order. Electrochemical impedance analyses reveal enhanced charge-transfer conductivity in films with more V{sup 4+} and oxygen vacancies on the film surface, that is, a film annealed, first, for 0.5 h in air and then for 2.5 h in nitrogen. Lithium-ion intercalation measurements show that, at a charge/discharge current density of 600 mA g{sup -1}, this film possesses a noticeably better lithium-ion storage capability than films without surface defects. This sample starts with an initial discharge capacity of 139 mA h g{sup -1}, and the capacity increases slowly to a maximum value of 156 mA h g{sup -1} in the 15th cycle, followed by a mild capacity degradation in later cycles. After 50 cycles, the discharge capacity is still as high as 136 mA h g{sup -1}. A much improved lithium-ion intercalation capacity and cyclic stability are attributed to V{sup 4+} surface defects and associated oxygen vacancies introduced by N{sub 2} annealing.

Liu, Dawei; Liu, Yanyi; Pan, Anquiang; Nagle, Kenneth P.; Seidler, Gerald T.; Jeong, Yoon-Ha; Cao, Guozhong (UWASH); (POSTECH)

2011-09-15T23:59:59.000Z

394

Fluoro-Carbonate Solvents for Li-Ion Cells  

DOE Green Energy (OSTI)

A number of fluoro-carbonate solvents were evaluated as electrolytes for Li-ion cells. These solvents are fluorine analogs of the conventional electrolyte solvents such as dimethyl carbonate, ethylene carbonate, diethyl carbonate in Li-ion cells. Conductivity of single and mixed fluoro carbonate electrolytes containing 1 M LiPF{sub 6} was measured at different temperatures. These electrolytes did not freeze at -40 C. We are evaluating currently, the irreversible 1st cycle capacity loss in carbon anode in these electrolytes and the capacity loss will be compared to that in the conventional electrolytes. Voltage stability windows of the electrolytes were measured at room temperature and compared with that of the conventional electrolytes. The fluoro-carbon electrolytes appear to be more stable than the conventional electrolytes near Li voltage. Few preliminary electrochemical data of the fluoro-carbonate solvents in full cells are reported in the literature. For example, some of the fluorocarbonate solvents appear to have a wider voltage window than the conventional electrolyte solvents. For example, methyl 2,2,2 trifluoro ethyl carbonate containing 1 M LiPF{sub 6} electrolyte has a decomposition voltage exceeding 6 V vs. Li compared to <5 V for conventional electrolytes. The solvent also appears to be stable in contact with lithium at room temperature.

NAGASUBRAMANIAN,GANESAN

1999-09-17T23:59:59.000Z

395

American Lithium Energy Corp | Open Energy Information  

Open Energy Info (EERE)

San Marcos, California Zip 92069 Product California-based developer of lithium ion battery technology. References American Lithium Energy Corp1 LinkedIn Connections...

396

Development of Low Cost Carbonaceous Materials for Anodes in Lithium-Ion Batteries for Electric and Hybrid Electric Vehicles  

DOE Green Energy (OSTI)

Final report on the US DOE CARAT program describes innovative R & D conducted by Superior Graphite Co., Chicago, IL, USA in cooperation with researchers from the Illinois Institute of Technology, and defines the proper type of carbon and a cost effective method for its production, as well as establishes a US based manufacturer for the application of anodes of the Lithium-Ion, Lithium polymer batteries of the Hybrid Electric and Pure Electric Vehicles. The three materials each representing a separate class of graphitic carbon, have been developed and released for field trials. They include natural purified flake graphite, purified vein graphite and a graphitized synthetic carbon. Screening of the available on the market materials, which will help fully utilize the graphite, has been carried out.

Barsukov, Igor V.

2002-12-10T23:59:59.000Z

397

Self-Organized Amorphous TiO2 Nanotube Arrays on Porous Ti Foam for Rechargeable Lithium and Sodium Ion Batteries  

SciTech Connect

Self-organized amorphous TiO2 nanotube arrays (NTAs) were successfully fabricated on both Ti foil and porous Ti foam through electrochemical anodization techniques. The starting Ti foams were fabricated using ARCAM s Electron Beam Melting (EBM) technology. The TiO2 NTAs on Ti foam were used as anodes in lithium ion batteries; they exhibited high capacities of 103 Ahcm-2 at 10 Acm-2 and 83 Ahcm-2 at 500 Acm-2, which are two to three times higher than those achieved on the standard Ti foil, which is around 40 Ahcm-2 at 10 Acm-2 and 24 Ahcm-2 at 500 Acm-2, respectively. This improvement is mainly attributed to higher surface area of the Ti foam and higher porosity of the nanotube arrays layer grown on the Ti foam. In addition, a Na-ion half-cell composed of these NTAs anodes and Na metal showed a self-improving specific capacity upon cycling at 10 Acm-2. These results indicate that TiO2 NTAs grown on Ti porous foam are promising electrodes for Li-ion or Na-ion rechargeable batteries.

Bi, Zhonghe [ORNL; Paranthaman, Mariappan Parans [ORNL; Menchhofer, Paul A [ORNL; Dehoff, Ryan R [ORNL; Bridges, Craig A [ORNL; Chi, Miaofang [ORNL; Guo, Bingkun [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL

2013-01-01T23:59:59.000Z

398

Novel carbon-ion fuel cells  

DOE Green Energy (OSTI)

This report details acitvities by the Duke University Department of Mechanical Engineering and Material Science on the Novel Carbon-Ion Fuel Cells for the Department of Energy Advanced Coal Research Program grant for the third quarter of 1995.

Cocks, F.H.; LaViers, H.

1995-10-03T23:59:59.000Z

399

3D Thermal and Electrochemical Model for Spirally Wound Large Format Lithium-ion Batteries (Presentation)  

DOE Green Energy (OSTI)

In many commercial cells, long tabs at both cell sides, leading to uniform potentials along the spiral direction of wound jelly rolls, are rarely seen because of their high manufacturing cost. More often, several metal strips are welded at discrete locations along both current collector foils. With this design, the difference of electrical potentials is easily built up along current collectors in the spiral direction. Hence, the design features of the tabs, such as number, location and size, can be crucial factors for spiral-shaped battery cells. This paper presents a Li-ion battery cell model having a 3-dimensional spiral mesh involving a wound jellyroll structure. Further results and analysis will be given regarding impacts of tab location, number, and size.

Lee, K. J.; Kim, G. H.; Smith, K.

2010-10-14T23:59:59.000Z

400

Self-assembly of conformal polymer electrolyte film for lithium ion microbatteries  

E-Print Network (OSTI)

I apply the theory of polar and apolar intermolecular interactions to predict the behavior of combinations of common battery materials, specifically the cathode substrate lithium cobalt oxide (LCO) and the polymer separator ...

Bieber, Christalee

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Effect of entropy of lithium intercalation in cathodes and anodes on Li-ion battery thermal management  

Science Conference Proceedings (OSTI)

The entropy changes (?S) in various cathode and anode materials, as well as complete Li-ion batteries, were measured using an electrochemical thermodynamic measurement system (ETMS). LiCoO2 has a much larger entropy change than electrodes based on LiNixCoyMnzO2 and LiFePO4, while lithium titanate based anode has lower entropy change compared to graphite anodes. Reversible heat generation rate was found to be a significant portion of the total heat generation rate. The appropriate combinations of cathode and anode were investigated to minimize reversible heat.

Viswanathan, Vilayanur V.; Choi, Daiwon; Wang, Donghai; Xu, Wu; Towne, Silas A.; Williford, Ralph E.; Zhang, Jiguang; Liu, Jun; Yang, Zhenguo

2010-06-01T23:59:59.000Z

402

Nanowire Lithium-Ion Battery P R O J E C T L E A D E R : Alec Talin (NIST)  

E-Print Network (OSTI)

Nanowire Lithium-Ion Battery P R O J E C T L E A D E R : Alec Talin (NIST) C O L L A B O R A T O R To fabricate a single nanowire Li-ion battery and observe it charging and discharging. K E Y A C C O M P L I S H M E N T S Designed, fabricated, and tested complete Li-ion nanowire batteries measuring

Magee, Joseph W.

403

Intermetallic insertion anodes for lithium batteries.  

DOE Green Energy (OSTI)

Binary intermetallic compounds containing lithium, or lithium alloys, such as Li{sub x}Al, Li{sub x}Si and Li{sub x}Sn have been investigated in detail in the past as negative electrode materials for rechargeable lithium batteries. It is generally acknowledged that the major limitation of these systems is the large volumetric expansion that occurs when lithium reacts with the host metal. Such large increases in volume limit the practical use of lithium-tin electrodes in electrochemical cells. It is generally recognized that metal oxide electrodes, MO{sub y}, in lithium-ion cells operate during charge and discharge by means of a reversible lithium insertion/extraction process, and that the cells offer excellent cycling behavior when the crystallographic changes to the unit cell parameters and unit cell volume of the Li{sub x}MO{sub y} electrode are kept to a minimum. An excellent example of such an electrode is the spinel Li{sub 4}Ti{sub 5}O{sub 12}, which maintains its cubic symmetry without any significant change to the lattice parameter (and hence unit cell volume) during lithium insertion to the rock-salt composition Li{sub 7}Ti{sub 5}O{sub 12}. This spinel electrode is an example of a ternary Li{sub x}MO{sub y} system in which a binary MO{sub y} framework provides a stable host structure for lithium. With this approach, the authors have turned their attention to exploring ternary intermetallic systems Li{sub x}MM{prime} in the hope of finding a system that is not subject to the high volumetric expansion that typifies many binary systems. In this paper, the authors present recent data of their investigations of lithium-copper-tin and lithium-indium-antimonide electrodes in lithium cells. The data show that lithium can be inserted reversibly into selected intermetallic compounds with relatively small expansion of the lithiated intermetallic structures.

Thackeray, M. M.; Vaughey, J.; Johnson, C. S.; Kepler, K. D.

1999-11-12T23:59:59.000Z

404

Design and simulation of lithium rechargeable batteries  

DOE Green Energy (OSTI)

Lithium -based rechargeable batteries that utilize insertion electrodes are being considered for electric-vehicle applications because of their high energy density and inherent reversibility. General mathematical models are developed that apply to a wide range of lithium-based systems, including the recently commercialized lithium-ion cell. The modeling approach is macroscopic, using porous electrode theory to treat the composite insertion electrodes and concentrated solution theory to describe the transport processes in the solution phase. The insertion process itself is treated with a charge-transfer process at the surface obeying Butler-Volmer kinetics, followed by diffusion of the lithium ion into the host structure. These models are used to explore the phenomena that occur inside of lithium cells under conditions of discharge, charge, and during periods of relaxation. Also, in order to understand the phenomena that limit the high-rate discharge of these systems, we focus on the modeling of a particular system with well-characterized material properties and system parameters. The system chosen is a lithium-ion cell produced by Bellcore in Red Bank, NJ, consisting of a lithium-carbon negative electrode, a plasticized polymer electrolyte, and a lithium-manganese-oxide spinel positive electrode. This battery is being marketed for consumer electronic applications. The system is characterized experimentally in terms of its transport and thermodynamic properties, followed by detailed comparisons of simulation results with experimental discharge curves. Next, the optimization of this system for particular applications is explored based on Ragone plots of the specific energy versus average specific power provided by various designs.

Doyle, C.M.

1995-08-01T23:59:59.000Z

405

Battery capacity measurement and analysis using lithium coin cell battery  

Science Conference Proceedings (OSTI)

Keywords: DC/DC converter, battery, coin cell, data acquisition, embedded system, energy estimation, power estimation

Sung Park; Andreas Savvides; Mani Srivastava

2001-08-01T23:59:59.000Z

406

Imara Corp formerly Lion Cells | Open Energy Information  

Open Energy Info (EERE)

Menlo Park, California Zip 94025 Product California-based developer of lithium-ion battery technologies formerly known as Lion Cells. References Imara Corp (formerly Lion...

407

Two Studies Reveal Details of Lithium-Battery Function  

NLE Websites -- All DOE Office Websites (Extended Search)

Two Studies Reveal Details of Lithium-Battery Function Print Two Studies Reveal Details of Lithium-Battery Function Print Our way of life is deeply intertwined with battery technologies that have enabled a mobile revolution powering cell phones, laptops, medical devices, and cars. As conventional lithium-ion batteries approach their theoretical energy-storage limits, new technologies are emerging to address the long-term energy-storage improvements needed for mobile systems, electric vehicles in particular. Battery performance depends on the dynamics of evolving electronic and chemical states that, despite advances in material synthesis and structural probes, remain elusive and largely unexplored. At Beamlines 8.0.1 and 9.3.2, researchers studied lithium-ion and lithium-air batteries, respectively, using soft x-ray spectroscopy techniques. The detailed information they obtained about the evolution of electronic and chemical states will be indispensable for understanding and optimizing better battery materials.

408

Two Studies Reveal Details of Lithium-Battery Function  

NLE Websites -- All DOE Office Websites (Extended Search)

Two Studies Reveal Details of Lithium-Battery Function Print Two Studies Reveal Details of Lithium-Battery Function Print Our way of life is deeply intertwined with battery technologies that have enabled a mobile revolution powering cell phones, laptops, medical devices, and cars. As conventional lithium-ion batteries approach their theoretical energy-storage limits, new technologies are emerging to address the long-term energy-storage improvements needed for mobile systems, electric vehicles in particular. Battery performance depends on the dynamics of evolving electronic and chemical states that, despite advances in material synthesis and structural probes, remain elusive and largely unexplored. At Beamlines 8.0.1 and 9.3.2, researchers studied lithium-ion and lithium-air batteries, respectively, using soft x-ray spectroscopy techniques. The detailed information they obtained about the evolution of electronic and chemical states will be indispensable for understanding and optimizing better battery materials.

409

Innovative lithium-titanium-oxide anodes improve battery safety and performance (IN-98-069)  

Rechargeable lithium-ion batteries have become the battery of choice for everything from cell phones to electric cars, but there is still much room for improvement. Scientists at Argonne National Laboratory are leading efforts to revolutionize battery ...

410

Corrosion of current-collector materials in Li-ion cells  

DOE Green Energy (OSTI)

The primary current-collector materials being used in lithium-ion cells are susceptible to environmental degradation: aluminum to pitting corrosion and copper to environmentally assisted cracking. Pitting occurs at the highly oxidizing potentials associated with the positive-electrode charge condition. However, the pitting mechanism is more complex than that typically observed in aqueous systems in that the pits are filled with a mixed metal/oxide product and exist as mounds or nodules on the surface. Electrochemical impedance was shown to be an effective analytical tool for quantification and verification of visual observations and trends. Two fluorocarbon-based coatings were shown to improve the resistance of Al to localized pitting. Finally, environmental cracking of copper can occur at or near the lithium potential and only if specific metallurgical conditions exist (work hardening and large grain size).

Braithwaite, J.; Nagasubramanian, G.; Gonzales, A.; Lucero, S.; Cieslak, W.

1996-12-01T23:59:59.000Z

411

Composite electrodes for lithium batteries.  

DOE Green Energy (OSTI)

The stability of composite positive and negative electrodes for rechargeable lithium batteries is discussed. Positive electrodes with spinel-type structures that are derived from orthorhombic-LiMnO{sub 2} and layered-MnO{sub 2} are significantly more stable than standard spinel Li[Mn{sub 2}]O{sub 4} electrodes when cycled electrochemically over both the 4-V and 3-V plateaus in lithium cells. Transmission electron microscope data of cycled electrodes have indicated that a composite domain structure accounts for this greater electrochemical stability. The performance of composite Cu{sub x}Sn materials as alternative negative electrodes to amorphous SnO{sub x} electrodes for lithium-ion batteries is discussed in terms of the importance of the concentration of the electrochemically inactive copper component in the electrode.

Hackney, S. A.; Johnson, C. S.; Kahaian, A. J.; Kepler, K. D.; Shao-Horn, Y.; Thackeray, M. M.; Vaughey, J. T.

1999-02-03T23:59:59.000Z

412

Office of Technology Transfer Composite Electrodes for Rechargeable Lithium-  

E-Print Network (OSTI)

of this technology. Page 6 Lithium-ion Batteries Could Hold the Key to 100-MPG Hybrids Lithium-ion batteries are a promising alternative to the nickel metal hydride batteries used in current-generation HEVs. Lithium-ion batteries pack more power and energy into a smaller battery package. But there's work to do before lithium-ion

Kemner, Ken

413

Structural micro-porous carbon anode for rechargeable lithium-ion batteries  

DOE Patents (OSTI)

A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc. 6 figs.

Delnick, F.M.; Even, W.R. Jr.; Sylwester, A.P.; Wang, J.C.F.; Zifer, T.

1995-06-20T23:59:59.000Z

414

Structural micro-porous carbon anode for rechargeable lithium-ion batteries  

DOE Patents (OSTI)

A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc.

Delnick, Frank M. (Albuquerque, NM); Even, Jr., William R. (Livermore, CA); Sylwester, Alan P. (Washington, DC); Wang, James C. F. (Livermore, CA); Zifer, Thomas (Manteca, CA)

1995-01-01T23:59:59.000Z

415

Lithium Rechargeable Batteries  

DOE Green Energy (OSTI)

In order to obviate the deficiencies of currently used electrolytes in lithium rechargeable batteries, there is a compelling need for the development of solvent-free, highly conducting solid polymer electrolytes (SPEs). The problem will be addressed by synthesizing a new class of block copolymers and plasticizers, which will be used in the formulation of highly conducting electrolytes for lithium-ion batteries. The main objective of this Phase-I effort is to determine the efficacy and commercial prospects of new specifically designed SPEs for use in electric and hybrid electric vehicle (EV/HEV) batteries. This goal will be achieved by preparing the SPEs on a small scale with thorough analyses of their physical, chemical, thermal, mechanical and electrochemical properties. SPEs will play a key role in the formulation of next generation lithium-ion batteries and will have a major impact on the future development of EVs/HEVs and a broad range of consumer products, e.g., computers, camcorders, cell phones, cameras, and power tools.

Robert Filler, Zhong Shi and Braja Mandal

2004-10-21T23:59:59.000Z

416

Fuzzy Clustering Based Multi-model Support Vector Regression State of Charge Estimator for Lithium-ion Battery of Electric Vehicle  

Science Conference Proceedings (OSTI)

Based on fuzzy clustering and multi-model support vector regression, a novel lithium-ion battery state of charge (SOC) estimating model for electric vehicle is proposed. Fuzzy C-means and Subtractive clustering combined algorithm is employed to implement ...

Xiaosong Hu; Fengchun Sun

2009-08-01T23:59:59.000Z

417

Synthesis and Characterization of Simultaneous Electronic and Ionic Conducting Block Copolymers for Lithium Battery Electrodes  

E-Print Network (OSTI)

9 Figure 1.9. Schematic of a traditional lithium-ion batterythan traditional lithium-ion battery batteries. OrganicBattery Design A lithium-ion battery consists of a negative

Patel, Shrayesh

2013-01-01T23:59:59.000Z

418

Performance, Charging, and Second-use Considerations for Lithium Batteries for Plug-in Electric Vehicles  

E-Print Network (OSTI)

Miller, M. , Emerging Lithium-ion Battery Technologies forMid-size Full (1) Lithium-ion battery with an energy densitypresent study. The lithium-ion battery technology used for

Burke, Andrew

2009-01-01T23:59:59.000Z

419

Composition-tailored synthesis of gradient transition metal precursor particles for lithium-ion battery cathode materials.  

DOE Green Energy (OSTI)

We report the tailored synthesis of particles with internal gradients in transition metal composition aided by the use of a general process model. Tailored synthesis of transition metal particles was achieved using a coprecipitation reaction with tunable control over the process conditions. Gradients in the internal composition of the particles was monitored and confirmed experimentally by analysis of particles collected during regularly timed intervals. Particles collected from the reactor at the end of the process were used as the precursor material for the solid-state synthesis of Li{sub 1.2}(Mn{sub 0.62}Ni{sub 0.38}){sub 0.8}O{sub 2}, which was electrochemically evaluated as the active cathode material in a lithium battery. The Li{sub 1.2}(Mn{sub 0.62}Ni{sub 0.38}){sub 0.8}O{sub 2} material was the first example of a structurally integrated multiphase material with a tailored internal gradient in relative transition metal composition as the active cathode material in a lithium-ion battery. We believe our general synthesis strategy may be applied to produce a variety of new cathode materials with tunable interior, surface, and overall relative transition metal compositions.

Koenig, G. M.; Belharouak, I.; Deng, H.; Amine, K.; Sun, Y. K. (Chemical Sciences and Engineering Division)

2011-04-12T23:59:59.000Z

420

Multi-Scale Multi-Dimensional Model for Better Cell Design and Management (Presentation)  

DOE Green Energy (OSTI)

Describes NREL's R&D to develop a multi-scale model to assist in designing better, more reliable lithium-ion battery cells for advanced vehicles.

Kim, G.-H.; Smith, K.

2008-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
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they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Material and energy flows in the materials production, assembly, and end-of-life stages of the automotive lithium-ion battery life cycle  

DOE Green Energy (OSTI)

This document contains material and energy flows for lithium-ion batteries with an active cathode material of lithium manganese oxide (LiMn{sub 2}O{sub 4}). These data are incorporated into Argonne National Laboratory's Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, replacing previous data for lithium-ion batteries that are based on a nickel/cobalt/manganese (Ni/Co/Mn) cathode chemistry. To identify and determine the mass of lithium-ion battery components, we modeled batteries with LiMn{sub 2}O{sub 4} as the cathode material using Argonne's Battery Performance and Cost (BatPaC) model for hybrid electric vehicles, plug-in hybrid electric vehicles, and electric vehicles. As input for GREET, we developed new or updated data for the cathode material and the following materials that are included in its supply chain: soda ash, lime, petroleum-derived ethanol, lithium brine, and lithium carbonate. Also as input to GREET, we calculated new emission factors for equipment (kilns, dryers, and calciners) that were not previously included in the model and developed new material and energy flows for the battery electrolyte, binder, and binder solvent. Finally, we revised the data included in GREET for graphite (the anode active material), battery electronics, and battery assembly. For the first time, we incorporated energy and material flows for battery recycling into GREET, considering four battery recycling processes: pyrometallurgical, hydrometallurgical, intermediate physical, and direct physical. Opportunities for future research include considering alternative battery chemistries and battery packaging. As battery assembly and recycling technologies develop, staying up to date with them will be critical to understanding the energy, materials, and emissions burdens associated with batteries.

Dunn, J.B.; Gaines, L.; Barnes, M.; Wang, M.; Sullivan, J. (Energy Systems)

2012-06-21T23:59:59.000Z

422

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network (OSTI)

Coating for Lithium-Ion Battery Cathodes", Chemistry ofas the cathode of the lithium ion battery by Thackeray et

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

423

Synthesis of polycrystalline SnO{sub 2} nanotubes on carbon nanotube template for anode material of lithium-ion battery  

Science Conference Proceedings (OSTI)

Polycrystalline tin oxide nanotubes have been prepared by a layer-by-layer technique on carbon nanotubes template. Firstly, the surface of carbon nanotubes was modified by polyelectrolyte. Then, a uniform layer of tin oxide nanoparticles was formed on the positive charged surface of carbon nanotubes via a redox process. At last, the polycrystalline tin oxide nanotubes were synthesized after calcination at 650 deg. C in air for 3 h. The as-synthesized polycrystalline nanotubes with large surface area exhibit finer lithium storage capacity and cycling performance, which shows the potentially interesting application in lithium-ion battery.

Du Ning; Zhang Hui; Chen Bindi; Ma Xiangyang; Huang Xiaohua; Tu Jiangping [State Key Lab of Silicon Materials and Department of Material Science and Engineering, Zhejiang University, Hangzhou 310027 (China); Yang Deren [State Key Lab of Silicon Materials and Department of Material Science and Engineering, Zhejiang University, Hangzhou 310027 (China)], E-mail: mseyang@zju.edu.cn

2009-01-08T23:59:59.000Z

424

Three-Dimensional Thermal-Electrochemical Coupled Model for Spirally Wound Large-Format Lithium-Ion Batteries (Presentation)  

DOE Green Energy (OSTI)

This presentation discusses the behavior of spirally wound large-format Li-ion batteries with respect to their design. The objectives of the study include developing thermal and electrochemical models resolving 3-dimensional spirally wound structures of cylindrical cells, understanding the mechanisms and interactions between local electrochemical reactions and macroscopic heat and electron transfers, and developing a tool and methodology to support macroscopic designs of cylindrical Li-ion battery cells.

Lee, K. J.; Smith K.; Kim, G. H.

2011-04-01T23:59:59.000Z

425

Calorimetric Investigation of the Lithium–Manganese–Oxygen ...  

Science Conference Proceedings (OSTI)

Presentation Title, Calorimetric Investigation of the Lithium–Manganese–Oxygen Cathode Material System for Lithium Ion Batteries. Author(s), Damian M. Cupid, ...

426

A general solution-chemistry route to the synthesis LiMPO{sub 4} (M=Mn, Fe, and Co) nanocrystals with [010] orientation for lithium ion batteries  

SciTech Connect

A general and efficient solvothermal strategy has been developed for the preparation of lithium transition metal phosphate microstructures (LiMnPO{sub 4}, LiFePO{sub 4}, and LiCoPO{sub 4}), employing ethanol as the solvent, LiI as the Li source, metal salts as the M sources, H{sub 3}PO{sub 4} as the phosphorus source, and poly(vinyl pyrrolidone) (PVP) as the carbon source and template. This route features low cost, environmental benign, and one-step process for the cathode material production of Li-ion batteries without any complicated experimental setups and sophisticated operations. The as-synthesized LiMPO{sub 4} microstructures exhibit unique, well-shaped and favorable structures, which are self-assembled from microplates or microrods. The b axis is the preferred crystal growth orientation of the products, resulting in a shorter lithium ion diffusion path. The LiFePO{sub 4} microstructures show an excellent cycling stability without capacity fading up to 50 cycles when they are used as a cathode material in lithium-ion batteries. - Graphical abstract: A general and efficient solvothermal strategy has been developed for the preparation of lithium transition metal phosphate microstructures under solvothermal conditions in the presence of PVP. Highlights: > A general and efficient solvothermal strategy has been developed for the preparation of LiMPO{sub 4} microstructures. > This route features low cost, environmental benign, and one-step process. > The LiMPO{sub 4} microstructures exhibit unique, well-shaped, and favorable structures. > The LiFePO{sub 4} microstructures show an excellent cycling stability up to 50 cycles as a cathode material of lithium-ion batteries.

Su Jing [Key Laboratory of Cluster Science, Ministry of Education of China, Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China); Wei Bingqing; Rong Jiepeng [Department of Mechanical Engineering, University of Delaware, Newark, DE 19716 (United States); Yin Wenyan; Ye Zhixia; Tian Xianqing; Ren Ling [Key Laboratory of Cluster Science, Ministry of Education of China, Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China); Cao Minhua, E-mail: caomh@bit.edu.cn [Key Laboratory of Cluster Science, Ministry of Education of China, Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China); Hu Changwen [Key Laboratory of Cluster Science, Ministry of Education of China, Department of Chemistry, Beijing Institute of Technology, Beijing 100081 (China)

2011-11-15T23:59:59.000Z

427

Spinel electrodes for rechargeable lithium batteries.  

DOE Green Energy (OSTI)

This paper gives a historical account of the development of spinel electrodes for rechargeable lithium batteries. Research in the late 1970's and early 1980's on high-temperature . Li/Fe{sub 3}O{sub 4} cells led to the evaluation of lithium spinels Li[B{sub 2}]X{sub 4} at room temperature (B = metal cation). This work highlighted the importance of the [B{sub 2}]X{sub 4}spinel framework as a host electrode structure and the ability to tailor the cell voltage by selection of different B cations. Examples of lithium-ion cells that operate with spinel anode/spinel cathode couples are provided. Particular attention is paid to spinels within the solid solution system Li{sub 1+x}Mn{sub 2-x}O{sub 4} (0 {le} x {le} 0.33).

Thackeray, M. M.

1999-11-10T23:59:59.000Z

428

Screening report on cell materials for high-power Li-Ion HEV batteries.  

DOE Green Energy (OSTI)

The Battery Technology Department at Argonne National Laboratory is a major participant in the U.S. Department of Energy's Advanced Technology Development (ATD) program. This multi-national laboratory program is dedicated to improving lithium-ion batteries for high-power HEV and FCEV applications. As part of the FreedomCAR Partnership, this program is addressing the three key barriers for high-power lithium-ion batteries: calendar life, abuse tolerance, and cost. All three of these barriers can be addressed by the choice of materials used in the cell chemistry. To date, the ATD program has developed two high-power cell chemistries, denoted our Gen 1 and Gen 2 cell chemistries. The selection of materials for use in the Gen 2 cell chemistry was based largely on reducing material cost and extending cell calendar life, relative to our Gen 1 cell chemistry. Table 1 provides a list of the materials used in our Gen 2 cell chemistry and their projected costs, when produced in large-scale quantities. In evaluating advanced materials, we have focused our efforts on materials that are lower cost than those listed in Table 1, while simultaneously offering enhanced chemical, structural, and thermal stability. Therefore, we have focused on natural graphite anode materials (having round-edge particle morphologies), cathode materials that contain more Mn and less Co and Ni (which can be produced via low-cost processes), lower cost electrode binders and/or binders that possess superior bonding properties at lower concentrations, and lower cost salts and solvents (with superior thermal and oxidation/reduction stability) for use in the electrolyte. The purpose of this report is to document the results of screening tests that were performed on a large number of advanced low-cost materials. These materials were screened for their potential to impact positively on the calendar life, safety, and/or cost of high-power lithium-ion cell chemistries, relative to our Gen 2 cell chemistry. As part of this effort, we developed and employed a set of standard test protocols to evaluate all of the materials. After brief descriptions of the screening test methodologies and equipment, relevant data on each material are summarized in the body of this report. We have evaluated five categories of materials, and the report is organized accordingly. Results will be presented on advanced carbons for anodes, improved cathode materials, new salts and solvent systems, alternative binders, and novel separators.

Liu, J.; Kahaian, A.; Belharouak, I.; Kang, S.; Oliver, S.; Henriksen, S.; Amine, K.

2003-04-24T23:59:59.000Z

429

Lithium Diffusion in Graphitic Carbon  

NLE Websites -- All DOE Office Websites (Extended Search)

Volume 1 Start Page 1176 Issue 8 Pagination 1176-1180 Keywords anode, diffusion, graphene, lithium ion battery, transport Abstract Graphitic carbon is currently considered the...

430

Lithium-Assisted Electrochemical Welding in Silicon Nanowire Battery Electrodes  

E-Print Network (OSTI)

-healing, interfacial lithium diffusivity, in situ TEM, lithium-ion battery Silicon is an auspicious candidate to replace today's widely utilized graphitic anodes in lithium ion batteries because its specific energy evidence of facile transport of lithium ions, which are both desirable properties for enhanced battery

Li, Teng

431

In situ XAFS of the Li{sub x}Ni{sub 0.8}Co{sub 0.2} cathode for lithium-ion batteries  

DOE Green Energy (OSTI)

The layered LiNi{sub 0.8}Co{sub 0.2}O{sub 2} system is being considered as a new cathode material for the lithium-ion battery. Compared with LiCoO{sub 2}, the standard cathode formulation, it possesses improved electrochemical performance at a projected lower cost. In situ x-ray absorption fine-structure spectroscopy (XAFS) measurements were conducted on a cell cycled at a moderate rate and normal Li-ion operating voltages (3.0--4.1 V). The XAFS data collected at the Ni and Co edges approximately every 30 min. revealed details about the response of the cathode to Li insertion and extraction. These measurements on the Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2} cathode (0.29 < x < 0.78) demonstrated the excellent reversibility of the cathode's short-range structure. However, the Co and Ni atoms behaved differently in response to Li insertion. This study corroborates previous work that explains the XAFS of the Ni atoms in terms of a Ni{sup 3+} Jahn-Teller ion. An analysis of the metal-metal distances suggests, contrary to a qualitative analysis of the x-ray absorption near-edge structure (XANES), that the Co{sup 3+} is oxidized to the maximum extent possible (within the Li content range of this experiment) at x = 0.47 {+-} 0.04, and further oxidation occurs at the Ni site.

Kropf, J.; Johnson, C. S.

2000-01-17T23:59:59.000Z

432

Science and applications of mixed conductors for lithium batteries.  

DOE Green Energy (OSTI)

Mixed conductors show significant mobility of both electronic and ionic species and were the subject of an earlier review in MRS Bulletin. The current review is restricted to those mixed conductors of interest for use in lithium batteries, with an emphasis on commercialization. The first lithium batteries were primary cells using pure lithium anodes and carbon monofluoride or manganese oxide as the cathode. Both were developed in Japan, the former for use in fishing floats and the latter for calculators and similar small devices. Such primary cells based mainly on MnO{sub 2} or FeS{sub 2} cathodes are still extensively used in watches, cameras, and so on. Lithium primary cells are also the main power source for many medical devices, such as pacemakers. In some of these applications, silver vanadate is the cathode. The recognition of the role of intercalation/ insertion reactions in battery electrodes just over 25 years ago allowed significant progress to be made in secondary (rechargeable) lithium batteries. From the first prototypical titanium disulfide cells, the technology has more recently been commercialized by Sony Corp. in the Li-ion cell, using a cobalt oxide insertion cathode and a carbon insertion anode. In the former, commercialized by Exxon, the reaction is the simple intercalation of lithium ions between sheets of TiS{sub 2}.

Thackeray, M. M.; Thomas, J.; Whittingham, M. S.; Chemical Engineering

2000-03-01T23:59:59.000Z

433

Phase Field Model of Li-Plating in Lithium Ion Battery  

Science Conference Proceedings (OSTI)

Abstract Scope, Li plating limits the maximum safe charging rate of Li-ion batteries, and thus the amount of energy that can be captured by regenerative braking.

434

Failure modes in high-power lithium-ion batteries for use in hybrid electric vehicles  

E-Print Network (OSTI)

BATTERIES FOR USE IN HYBRID ELECTRIC VEHICLES R. Kostecki,ion batteries for hybrid electric vehicles. Nine 18650-sizebatteries for hybrid electric vehicle (HEV) applications.

2001-01-01T23:59:59.000Z

435

Visualization of Charge Distribution in a Lithium Battery Electrode  

E-Print Network (OSTI)

of a Lithium-Polymer Battery. J. Power Sources 2006, 163,of a Lithium-Polymer Battery. J. Power Sources 2008, 180,Up of a Lithium-Ion Polymer Battery. J. Power Sources 2009,

Liu, Jun

2010-01-01T23:59:59.000Z

436

Imaging Lithium Atoms at Sub-Angstrom Resolution  

E-Print Network (OSTI)

110] orientation for LiCoO 2 without lithium atoms ( upper)and with lithium atoms (lower). Images are simulated at 0.9ÅHorn LBNL-56646 resolution of lithium ions in LiCoO 2 . Fall

O'Keefe, Michael A.; Shao-Horn, Yang

2005-01-01T23:59:59.000Z

437

Electrical and Electrochemical Performance Characteristics of Small Commercial Li-Ion Cells  

DOE Green Energy (OSTI)

Advanced rechargeable lithium-ion batteries are presently being developed and commercialized worldwide for use in consumer electronics, military and space applications. At Sandia National Laboratories we have used different electrochemical techniques such as impedance and charge/discharge at ambient and subambient temperatures to probe the various electrochemical processes that are occurring in Li-ion cell. The purpose of this study is to identify the component that reduces the cell performance at subambient temperatures. Our impedance data suggest that while the variation in the electrolyte resistance between room temperature and {minus}20 C is negligible the anode electrolyte interfacial resistance increases by an order of magnitude in the same temperature regime. We believe that the solid electrolyte interface (SEI) layer on the carbon anode may be responsible for the increase in cell impedance. We have also evaluated the cells in hybrid mode with capacitors. High-current operation in the hybrid mode allowed fill usage of the Li-ion cell capacity at 25 C and showed a factor of 5 improvement in delivered capacity at {minus}20 C.

Ingersoll, D.; Nagasubramanian, G.; Roth, E.P.

1998-12-22T23:59:59.000Z

438

Thermal Stability of Li-Ion Cells  

DOE Green Energy (OSTI)

The thermal stability of Li-ion cells with intercalating carbon anodes and metal oxide cathodes was measured as a function of state of charge and temperature for two advanced cell chemistries. Cells of the 18650 design with Li{sub x}CoO{sub 2} cathodes (commercial SONY cells) and Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2} cathodes were measured for thermal reactivity in the open circuit cell condition. Accelerating rate calorimetry (ARC) was used to measure cell thermal runaway as a function of state of charge (SOC). Microcalorimetry was used to measure the time dependence of heat generating side reactions also as a function of SOC. Components of cells were measured using differential scanning calorimetry (DSC) to study the thermal reactivity of the individual electrodes to determine the temperature regimes and conditions of the major thermal reactions. Thermal decomposition of the SEI layer at the anodes was identified as the initiating source for thermal runaway. The cells with Li{sub x}CoO{sub 2} cathodes showed greater sensitivity to SOC and higher accelerating heating rates than seen for the cells with Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2}cathodes. Lower temperature reactions starting as low as 40 C were also observed that were SOC dependent but not accelerating. These reactions were also measured in the microcalorimeter and observed to decay over time with a power-law dependence and are believed to result in irreversible capacity loss in the cells.

ROTH,EMANUEL P.

1999-09-17T23:59:59.000Z

439

Lithium intercalation in porous carbon anodes  

DOE Green Energy (OSTI)

Carbon foams derived from the phase separation of polyacrylonitrile/solvent mixtures were investigated as lithium intercalation anodes for rechargeable lithium-ion batteries. The carbon foams have a bulk density of 0.35--0.5 g/cm{sup 3}, low surface area (< 50 m{sup 2}/g), and an average cell size of 5--10 {mu}m. Polyacrylonitrile-based carbon foams doped with phosphoric acid had capacity as high as 450 mAh/g. Carbon capacity increased with increasing phosphoric acid concentration in the doping solution. The doped porous carbon anodes exhibited good cyclability and excellent coulombic efficiency.

Tran, T.D.; Pekala, R.W. [Lawrence Livermore National Lab., CA (United States). Chemistry and Materials Science Dept.; Mayer, S.T. [Polystor Corp., Livermore, CA (United States)

1994-11-23T23:59:59.000Z

440

Understanding the redox shuttle stability of 3,5-di-tert-butyl-1,2-dimethoxybenzene for overcharge protection of lithium-ion batteries.  

DOE Green Energy (OSTI)

3,5-di-tert-butyl-1,2-dimethoxybenzene (DBDB) has been synthesized as a new redox shuttle additive for overcharge protection of lithium-ion batteries. DBDB can easily dissolve in carbonate-based electrolytes, which facilitates its practical use in lithium-ion batteries; however, it has poor electrochemical stability compared to 2,5-di-tert-butyl-1,4-dimethoxybenzene (DDB). The structures of DBDB and DDB were investigated using X-ray crystallography and density functional calculations. The structures differ in the conformations of the alkoxy bonds probably due to the formation of an intramolecular hydrogen bond in the case of DBDB. We investigated reaction energies for decomposition pathways of neutral DBDB and DDB and their radical cations and found little difference in the reaction energies, although it is clear that kinetically, decomposition of DBDB is more favorable.

Zhang, Z.; Zhang, L.; Schlueter, J. A.; Redfern, P. C.; Curtiss, L.; Amine, K.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Photon and positive ion production from collisions of superthermal hydrogen atoms with lithium atoms and molecules. [1 to 10 eV, cross sections, emission spectra  

DOE Green Energy (OSTI)

Photon and positive ion production from superthermal collisions of hydrogen atoms with lithium atoms and molecules is reported. These are the first results in the difficult 1 to 10 eV collision regime obtained with recently developed high intensity plasma-arc source of H atoms. These superthermal H atoms (approximately 5 eV average kinetic energy but not velocity selected in these experiments) have been collided with an intense supersonic lithium beam (approximately 10 percent Li/sub 2/; Li/sub 3/ undetectable) with cold internal degrees of freedom (T/sub vib/ = 195/sup 0/K, T/sub rot/ = 70/sup 0/K). The other aspects of the apparatus have been given previously. Low resolution photon and positive ion production in the collision chamber scattering center and also medium resolution; photon production in the magnet chamber between the skimmer and the magnet were detected.

Crooks, J.B.; Way, K.R.; Yang, S.C.; Wu, C.Y.R.; Stwalley, W.C.

1978-01-01T23:59:59.000Z

442

Simulations of Plug-in Hybrid Vehicles Using Advanced Lithium Batteries and Ultracapacitors on Various Driving Cycles  

E-Print Network (OSTI)

technology is a lithium-ion battery using lithium titanateof lithium-ion batteries of various chemistries Batterylithium-ion batteries were 20-22 kg and in the zinc-air battery,

Burke, Andy; Zhao, Hengbing

2010-01-01T23:59:59.000Z

443

Synthesis of molybdenum disulfide (MoS{sub 2}) for lithium ion battery applications  

Science Conference Proceedings (OSTI)

This paper reports the use of a rheological phase reaction method for preparing MoS{sub 2} nanoflakes. The characterization by powder X-ray diffraction indicated that MoS{sub 2} had been formed. High resolution electron microscopy observation revealed that the as-prepared MoS{sub 2} nanoflakes had started to curve and partly form MoS{sub 2} nanotubes. The lithium intercalation/de-intercalation behavior of as-prepared MoS{sub 2} nanoflake electrode was also investigated. It was found that the MoS{sub 2} nanoflake electrode exhibited higher specific capacity, with very high cycling stability, compared to MoS{sub 2} nanoparticle electrode. The possible reasons for the high electrochemical performance of the nanoflakes electrodes are also discussed. The outstanding electrochemical properties of MoS{sub 2} nanoflakes obtained by this method make it possible for MoS{sub 2} to be used as a promising anode material.

Feng Chuanqi [Key Laboratory for Synthesis and Applications of Organic Functional Molecules, Hubei University, Wuhan 430062 (China); Institute for Superconducting and Electronic Materials, University of Wollongong, NSW 2522 (Australia); Ma Jun; Li Hua [Key Laboratory for Synthesis and Applications of Organic Functional Molecules, Hubei University, Wuhan 430062 (China); Zeng Rong [Institute for Superconducting and Electronic Materials, University of Wollongong, NSW 2522 (Australia); Guo Zaiping, E-mail: zguo@uow.edu.au [School of Mechanical, Materials and Mechatronic Engineering, University of Wollongong, NSW 2522 (Australia); Institute for Superconducting and Electronic Materials, University of Wollongong, NSW 2522 (Australia); ARC Centre of Excellence for Electromaterials Science, University of Wollongong, NSW 2522 (Australia); Liu Huakun [Institute for Superconducting and Electronic Materials, University of Wollongong, NSW 2522 (Australia); ARC Centre of Excellence for Electromaterials Science, University of Wollongong, NSW 2522 (Australia)

2009-09-15T23:59:59.000Z

444

Anode for a secondary, high-temperature electrochemical cell  

DOE Patents (OSTI)

A high-temperature, secondary electrochemical cell includes an anode containing lithium, an electrolyte containing lithium ions and a cathode containing a chalcogen material such as sulfur or a metallic sulfide. The anode includes a porous substrate formed of, for instance, a compacted mass of entangled metallic fibers providing interstitial crevices for receiving molten lithium metal. The surfaces of the interstitial crevices are provided with a coating of cobalt metal to enhance the retention of the molten lithium metal within the substrate.

Vissers, Donald R. (Naperville, IL); Tani, Benjamin S. (Chicago, IL)

1976-01-01T23:59:59.000Z

445

Internal resistance variances in lithium-ion batteries and implications in manufacturing  

E-Print Network (OSTI)

This thesis addresses issues in manufacturing that lead to cell DC internal resistance (DCIR) variance, provides an overview of generally accepted cell degradation mechanisms and modeling techniques associated with IR as ...

Gogoana, Radu

2012-01-01T23:59:59.000Z

446

Performance Characteristics of Lithium-ion Batteries of Various Chemistries for Plug-in Hybrid Vehicles  

E-Print Network (OSTI)

Battery, Hybrid and Fuel Cell Electric Vehicle Symposiumof a plug-in hybrid-electric vehicle is the selection of theHybrid and Fuel Cell Electric Vehicle Symposium negative)

Burke, Andrew; Miller, Marshall

2009-01-01T23:59:59.000Z

447

Thin-film rechargeable lithium batteries  

SciTech Connect

Rechargeable thin-films batteries with lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have been fabricated and characterized. The cathodes include TiS{sub 2}, the {omega} phase of V{sub 2}O{sub 5}, and the cubic spinel Li{sub x}Mn{sub 2}O{sub 4} with open circuit voltages at full charge of about 2.5 V, 3.7 V, and 4.2 V, respectively. The development of these robust cells, which can be cycled thousands of times, was possible because of the stability of the amorphous lithium electrolyte, lithium phosphorus oxynitride. This material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46} and a conductivity at 25 C of 2 {mu}S/cm. Thin-film cells have been cycled at 100% depth of discharge using current densities of 2 to 100 {mu}A/cm{sup 2}. The polarization resistance of the cells is due to the slow insertion rate of Li{sup +} ions into the cathode. Chemical diffusion coefficients for Li{sup +} ions in the three types of cathodes have been estimated from the analysis of ac impedance measurements.

Bates, J.B.; Gruzalski, G.R.; Dudney, N.J.; Luck, C.F.; Yu, X.

1993-11-01T23:59:59.000Z

448

Thin-film Rechargeable Lithium Batteries  

DOE R&D Accomplishments (OSTI)

Rechargeable thin films batteries with lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have been fabricated and characterized. The cathodes include TiS{sub 2}, the {omega} phase of V{sub 2}O{sub 5}, and the cubic spinel Li{sub x}Mn{sub 2}O{sub 4} with open circuit voltages at full charge of about 2.5 V, 3.7 V, and 4.2 V, respectively. The development of these robust cells, which can be cycled thousands of times, was possible because of the stability of the amorphous lithium electrolyte, lithium phosphorus oxynitride. This material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46} and a conductivity at 25 C of 2 {mu}S/cm. Thin film cells have been cycled at 100% depth of discharge using current densities of 2 to 100 {mu}A/cm{sup 2}. The polarization resistance of the cells is due to the slow insertion rate of Li{sup +} ions into the cathode. Chemical diffusion coefficients for Li{sup +} ions in the three types of cathodes have been estimated from the analysis of ac impedance measurements.

Bates, J. B.; Gruzalski, G. R.; Dudney, N. J.; Luck, C. F.; Yu, X.

1993-11-00T23:59:59.000Z

449

Enhanced performance of graphite anode materials by AlF3 coating for lithium-ion batteries  

Science Conference Proceedings (OSTI)

In order to form the stable surface film and to further enhance the long-term cycling stability of the graphite anodes of lithium-ion batteries, the surface of graphite powders has been modified by AlF3 coating through chemical precipitation method. The AlF3-coated graphite shows no evident changes in the bulk structure and a thin AlF3-coating layer of about 2 nm thick is found to uniformly cover the graphite particles with 2 wt% AlF3 content. However, it delivers a higher initial discharge capacity and largely improved rate performances compared to the pristine graphite. Remarkably, AlF3 coated graphite demonstrated a much better cycle life. After 300 cycles, AlF3 coated graphite and uncoated graphite show capacity retention of 92% and 81%, respectively. XPS measurement shows that a more conductive solid electrode interface (SEI) layer was formed on AlF3 coated graphite as compared to uncoated graphite. SEM monograph also reveals that the AlF3-coated graphite particles have a much more stable surface morphology after long-term cycling. Therefore, the improved electrochemical performance of AlF3 coated graphite can be attributed to a more stable and conductive SEI formed on coated graphite anode during cycling process.

Ding, Fei; Xu, Wu; Choi, Daiwon; Wang, Wei; Li, Xiaolin; Engelhard, Mark H.; Chen, Xilin; Yang, Zhenguo; Zhang, Jiguang

2012-04-27T23:59:59.000Z

450

Spinel LiMn(2)O(4)/Reduced Graphene Oxide Hybrid for High Rate Lithium Ion Batteries  

DOE Green Energy (OSTI)

A well-crystallized and nano-sized spinel LiMn{sub 2}O{sub 4}/reduced graphene oxide hybrid cathode material for high rate lithium-ion batteries has been successfully synthesized via a microwave-assisted hydrothermal method at 200 C for 30 min without any post heat-treatment. The nano-sized LiMn{sub 2}O{sub 4} particles were evenly dispersed on the reduced graphene oxide template without agglomeration, which allows the inherent high active surface area of individual LiMn{sub 2}O{sub 4} nanoparticles in the hybrid. These unique structural and morphological properties of LiMn{sub 2}O{sub 4} on the highly conductive reduced graphene oxide sheets in the hybrid enable achieving the high specific capacity, an excellent high rate capability and stable cycling performance. An analysis of the cyclic voltammogram data revealed that a large surface charge storage contribution of the LiMn{sub 2}O{sub 4}/reduced graphene oxide hybrid plays an important role in achieving faster charge/discharge.

Bak, S.M.; Nam, K.; Lee, C.-W.; Kim, K.-H.; Jung, H.-C.; Yang, X-Q.; Kim, K.-B.

2011-10-04T23:59:59.000Z

451

Electrochemical-thermal modeling and microscale phase change for passive internal thermal management of lithium ion batteries.  

SciTech Connect

A fully coupled electrochemical and thermal model for lithium-ion batteries is developed to investigate the impact of different thermal management strategies on battery performance. In contrast to previous modeling efforts focused either exclusively on particle electrochemistry on the one hand or overall vehicle simulations on the other, the present work predicts local electrochemical reaction rates using temperature-dependent data on commercially available batteries designed for high rates (C/LiFePO{sub 4}) in a computationally efficient manner. Simulation results show that conventional external cooling systems for these batteries, which have a low composite thermal conductivity ({approx}1 W/m-K), cause either large temperature rises or internal temperature gradients. Thus, a novel, passive internal cooling system that uses heat removal through liquid-vapor phase change is developed. Although there have been prior investigations of phase change at the microscales, fluid flow at the conditions expected here is not well understood. A first-principles based cooling system performance model is developed and validated experimentally, and is integrated into the coupled electrochemical-thermal model for assessment of performance improvement relative to conventional thermal management strategies. The proposed cooling system passively removes heat almost isothermally with negligible thermal resistances between the heat source and cooling fluid. Thus, the minimization of peak temperatures and gradients within batteries allow increased power and energy densities unencumbered by thermal limitations.

Fuller, Thomas F. (Georgia Institute of Technology, Atlanta, GA); Bandhauer, Todd (Georgia Institute of Technology, Atlanta, GA); Garimella, Srinivas (Georgia Institute of Technology, Atlanta, GA)

2012-01-01T23:59:59.000Z

452

Lithium battery management system  

SciTech Connect

Provided is a system for managing a lithium battery system having a plurality of cells. The battery system comprises a variable-resistance element electrically connected to a cell and located proximate a portion of the cell; and a device for determining, utilizing the variable-resistance element, whether the temperature of the cell has exceeded a predetermined threshold. A method of managing the temperature of a lithium battery system is also included.

Dougherty, Thomas J. (Waukesha, WI)

2012-05-08T23:59:59.000Z

453

Lithium-Ion Battery Safety Study Using Multi-Physics Internal Short-Circuit Model (Presentation)  

DOE Green Energy (OSTI)

This presentation outlines NREL's multi-physics simulation study to characterize an internal short by linking and integrating electrochemical cell, electro-thermal, and abuse reaction kinetics models.

Kim, G-.H.; Smith, K.; Pesaran, A.

2009-06-01T23:59:59.000Z

454

Thermal characteristics of air flow cooling in the lithium ion batteries experimental chamber  

DOE Green Energy (OSTI)

A battery pack prototype has been designed and built to evaluate various air cooling concepts for the thermal management of Li-ion batteries. The heat generation from the Li-Ion batteries was simulated with electrical heat generation devices with the same dimensions as the Li-Ion battery (200 mm x 150 mm x 12 mm). Each battery simulator generates up to 15W of heat. There are 20 temperature probes placed uniformly on the surface of the battery simulator, which can measure temperatures in the range from -40 C to +120 C. The prototype for the pack has up to 100 battery simulators and temperature probes are recorder using a PC based DAQ system. We can measure the average surface temperature of the simulator, temperature distribution on each surface and temperature distributions in the pack. The pack which holds the battery simulators is built as a crate, with adjustable gap (varies from 2mm to 5mm) between the simulators for air flow channel studies. The total system flow rate and the inlet flow temperature are controlled during the test. The cooling channel with various heat transfer enhancing devices can be installed between the simulators to investigate the cooling performance. The prototype was designed to configure the number of cooling channels from one to hundred Li-ion battery simulators. The pack is thermally isolated which prevents heat transfer from the pack to the surroundings. The flow device can provide the air flow rate in the gap of up to 5m/s velocity and air temperature in the range from -30 C to +50 C. Test results are compared with computational modeling of the test configurations. The present test set up will be used for future tests for developing and validating new cooling concepts such as surface conditions or heat pipes.

Lukhanin A.; Rohatgi U.; Belyaev, A.; Fedorchenko, D.; Khazhmuradov, M.; Lukhanin, O; Rudychev, I.

2012-07-08T23:59:59.000Z

455

Single-Crystal Intermetallic M-Sn (M ) Fe, Cu, Co, Ni) Nanospheres as Negative Electrodes for Lithium-Ion Batteries  

DOE Green Energy (OSTI)

FeSn{sub 2}, Cu{sub 6}Sn{sub 5}, CoSn{sub 3}, and Ni{sub 3}Sn{sub 4} single-crystalline nanospheres with a characteristic uniform particle size of 40 nm have been synthesized via a modified polyol process, aiming at determining and understanding their intrinsic cycling performance as negative electrode materials for lithium-ion batteries. We find that, in this morphologically controlled condition, the reversible capacities follow FeSn{sub 2} > Cu{sub 6}Sn{sub 5} {approx} CoSn{sub 3} > Ni{sub 3}Sn{sub 4}, which is not directly decided by their theoretical capacities or lithium-driven volume changes. FeSn{sub 2} exhibits the best electrochemical activity among these intermetallic nanospheres and an effective solid electrolyte interface, which explains its superior cycling performance. The small particle dimension also improves cycling stability and Li{sup +} diffusion.

Wang, X.; Han, W; Chen, J; Graetz, J

2010-01-01T23:59:59.000Z

456

Lithium-endohedral C{sub 60} complexes.  

DOE Green Energy (OSTI)

High capacity, reversible, lithium intercalated carbon anodes have been prepared, 855 m.Ah/g, which exceed the capacity for stage 1 lithium intercalated carbon anodes, 372 mAh/g. Since there is very little hydrogen content in the high capacity anode, the fullerene C{sub 60} lattice is used to investigate the nature of lithium ion bonding and spacing between lithiums in endohedral lithium complexes of C{sub 60}. Three lithium-endohedral complexes have been investigated using ab initio molecular orbital calculations involving 2,3 and 5 lithium. The calculated results suggest that lithium cluster formation may be important for achieving the high capacity lithium carbon anodes.

Scanlon, L. G.

1998-05-04T23:59:59.000Z

457

Designing Safe Lithium-Ion Battery Packs Using Thermal Abuse Models (Presentation)  

DOE Green Energy (OSTI)

NREL and NASA developed a thermal-electrical model that resolves PTC and cell behavior under external shorting, now being used to evaluate safety margins of battery packs for spacesuit applications.

Pesaran, A. A.; Kim, G. H.; Smith, K.; Darcy, E.

2008-12-01T23:59:59.000Z

458

Pseudocapacitive Lithium-Ion Storage in Oriented Anatase TiO2 Nanotube Arrays  

SciTech Connect

We report on the synthesis and electrochemical properties of oriented anatase TiO{sub 2} nanotube (NT) arrays as electrodes for Li-ion batteries. The TiO{sub 2} NT electrodes displayed both pseudocapacitive Li{sup +} storage associated with the NT surface and the Li{sup +} storage within the bulk material. The relative contribution of the pseudocapacitive and bulk storages depends strongly on the scan rate. While the charges are stored primarily in the bulk at low scan rates (<< 1 mV/s), the surface storage dominates the total storage capacity at higher scan rates (>1 mV/s). The storage capacity of the NT electrodes as a function of charge/discharge rates showed no dependence on the NT film thickness, suggesting that the Li{sup +} insertion/extraction processes occur homogeneously across the entire length of NT arrays. These results indicated that the electron conduction along the NT walls and the ion conduction within the electrolyte do not cause significant hindering of the charge/discharge kinetics for NT electrode architectures. As a result of the surface pseudocapacitive storage, the reversible Li{sup +} storage capacities for TiO{sub 2} NT electrodes were higher than the theoretical storage capacity for bulk anatase TiO{sub 2} materials.

Zhu, K.; Wang, Q.; Kim, J. H.; Pesaran, A. A.; Frank, A. J.

2012-06-07T23:59:59.000Z

459

Method of preparing a negative electrode including lithium alloy for use within a secondary electrochemical cell  

DOE Patents (OSTI)

A negative electrode that includes a lithium alloy as active material is prepared by briefly submerging a porous, electrically conductive substrate within a melt of the alloy. Prior to solidification, excess melt can be removed by vibrating or otherwise manipulating the filled substrate to expose interstitial surfaces. Electrodes of such as solid lithium-aluminum filled within a substrate of metal foam are provided.

Tomczuk, Zygmunt (Palos Hills, IL); Olszanski, Theodore W. (Roselle, IL); Battles, James E. (Oak Forest, IL)

1977-03-08T23:59:59.000Z

460

LiFe(x)Mn(1-x)PO(4): A Cathode for Lithium-ion Batteries  

DOE Green Energy (OSTI)

The high redox potential of LiMnPO{sub 4}, {approx}4.0 vs. (Li{sup +}/Li), and its high theoretical capacity of 170 mAh g{sup -1} makes it a promising candidate to replace LiCoO{sub 2} as the cathode in Li-ion batteries. However, it has attracted little attention because of its severe kinetic problems during cycling. Introducing iron into crystalline LiMnPO{sub 4} generates a solid solution of LiFe{sub x}Mn{sub 1-x}PO{sub 4} and increases kinetics; hence, there is much interest in determining the Fe-to-Mn ratio that will optimize electrochemical performance. To this end, we synthesized a series of nanoporous LiFe{sub x}Mn{sub 1-x}PO{sub 4} compounds (with x = 0, 0.05, 0.1, 0.15, and 0.2), using an inexpensive solid-state reaction. The electrodes were characterized using X-ray diffraction and energy-dispersive spectroscopy to examine their crystal structure and elemental distribution. Scanning-, tunneling-, and transmission-electron microscopy (viz., SEM, STEM, and TEM) were employed to characterize the micromorphology of these materials; the carbon content was analyzed by thermogravimetric analyses (TGAs). We demonstrate that the electrochemical performance of LiFe{sub x}Mn{sub 1-x}PO{sub 4} rises continuously with increasing iron content. In situ synchrotron studies during cycling revealed a reversible structural change when lithium is inserted and extracted from the crystal structure. Further, introducing 20% iron (e.g., LiFe{sub 0.2}Mn{sub 0.8}PO{sub 4}) resulted in a promising capacity (138 mAh g{sup -1} at C/10), comparable to that previously reported for nano-LiMnPO{sub 4}.

J Hong; F Wang; X Wang; J Graetz

2011-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Graphene Modified LiFePO4 Cathode Materials for High Power Lithium ion Batteries  

Science Conference Proceedings (OSTI)

Graphene-modified LiFePO{sub 4} composite has been developed as a Li-ion battery cathode material with excellent high-rate capability and cycling stability. The composite was prepared with LiFePO{sub 4} nanoparticles and graphene oxide nanosheets by spray-drying and annealing processes. The LiFePO{sub 4} primary nanoparticles embedded in micro-sized spherical secondary particles were wrapped homogeneously and loosely with a graphene 3D network. Such a special nanostructure facilitated electron migration throughout the secondary particles, while the presence of abundant voids between the LiFePO{sub 4} nanoparticles and graphene sheets was beneficial for Li{sup +} diffusion. The composite cathode material could deliver a capacity of 70 mAh g{sup -1} at 60C discharge rate and showed a capacity decay rate of <15% when cycled under 10C charging and 20C discharging for 1000 times.

Zhou, X.; Wang, F.; Zhu, Y.; Liu, Z.

2011-01-24T23:59:59.000Z

462

CHARACTERIZATION OF LOW-FLAMMABILITY ELECTROLYTES FOR LITHIUM-ION BATTERIES  

DOE Green Energy (OSTI)

In an effort to develop low-flammability electrolytes for a new generation of Li-ion batteries, we have evaluated physical and electrochemical properties of electrolytes with two proprietary phosphazene additives. We have studied performance quantities including conductivity, viscosity, flash point, and electrochemical window of electrolytes as well as formation of solid electrolyte interphase (SEI) films. In the course of study, the necessity for a simple method of SEI characterization was realized. Therefore, a new method and new criteria were developed and validated on 10 variations of electrolyte/electrode substrates. Based on the summation of determined physical and electrochemical properties of phosphazene-based electrolytes, one structure of phosphazene compound was found better than the other. This capability helps to direct our further synthetic work in phosphazene chemistry.

Sergiy V. Sazhin; Mason K. Harrup; Kevin L. Gering

2011-04-01T23:59:59.000Z

463

Intermetallic electrodes for lithium batteries - Energy ...  

This invention relates to intermetallic negative electrode compounds for non-aqueous, electrochemical lithium cells and batteries. More specifically, ...

464

Ab initio Molecular Dynamics Simulations of the Initial Stages of Solid-electrolyte Interphase Formation on Lithium Ion Battery Graphitic Anodes  

E-Print Network (OSTI)

The decomposition of ethylene carbonate (EC) during the initial growth of solid-electrolyte interphase (SEI) films at the solvent-graphitic anode interface is critical to lithium ion battery operations. Ab initio molecular dynamics simulations of explicit liquid EC/graphite interfaces are conducted to study these electrochemical reactions. We show that carbon edge terminations are crucial at this stage, and that achievable experimental conditions can lead to surprisingly fast EC breakdown mechanisms, yielding decomposition products seen in experiments but not previously predicted.

Leung, Kevin; 10.1039/B925853A

2010-01-01T23:59:59.000Z

465

Thin-film rechargeable lithium batteries  

SciTech Connect

Small thin-film rechargeable cells have been fabricated with a lithium phosphorus oxyniuide electrolyte, Li metal anode, and Li{sub 1-x}Mn{sub 2}O{sub 4} as the cathode film. The cathode films were fabricated by several different techniques resulting in both crystalline and amorphous films. These were compared by observing the cell discharge behavior. Estimates have been made for the scale-up of such a thin-film battery to meet the specifications for the electric vehicle application. The specific energy, energy density, and cycle life are expected to meet the USABC mid-term criteria. However, the areas of the thin-films needed to fabricate such a cell are very large. The required areas could be greatly reduced by operating the battery at temperatures near 100{degrees}C or by enhancing the lithium ion transport rate in the cathode material.

Dudney, N.J.; Bates, J.B.; Lubben, D.

1994-11-01T23:59:59.000Z

466

TransForum v8n2 - Advanced Lithium Battery Conference  

NLE Websites -- All DOE Office Websites (Extended Search)

lithium batteries for transportation applications, organizers from the U.S., Japan and Korea jointly initiated the conference. Among available battery technologies, lithium-ion...

467

Rechargeable thin-film lithium batteries  

Science Conference Proceedings (OSTI)

Rechargeable thin-film batteries consisting of lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have been fabricated and characterized. These include Li-TiS{sub 2}, Li-V{sub 2}O{sub 5}, and Li-Li{sub x}Mn{sub 2}O{sub 4} cells with open circuit voltages at full charge of about 2.5 V, 3.7 V, and 4.2 V, respectively. The realization of these robust cells, which can be cycled thousands of times, was possible because of the stability of the amorphous lithium electrolyte, lithium phosphorus oxynitride. This material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46}and a conductivity at 25 C of 2 {mu}S/cm. The thin-film cells have been cycled at 100% depth of discharge using current densities of 5 to 100 {mu}A/cm{sup 2}. Over most of the charge-discharge range, the internal resistance appears to be dominated by the cathode, and the major source of the resistance is the diffusion of Li{sup +} ions from the electrolyte into the cathode. Chemical diffusion coefficients were determined from ac impedance measurements.

Bates, J.B.; Gruzalski, G.R.; Dudney, N.J.; Luck, C.F.; Yu, X.

1993-09-01T23:59:59.000Z

468

Phosphate-stabilized Lithium intercalation compounds  

DOE Green Energy (OSTI)

Four manganese and iron phosphates with alluaudite or fillowite structures have been prepared by solid state reactions: Na2FeMn2(PO4)3, LiNaFeMn2(PO4)3, NaFe3(PO4)3, and Na2Mn3(PO4)3. LixNa2-xFeMn2(PO4)3 with x close to 2 was prepared from Na2FeMn2(PO4)3 by molten salt ion exchange. These materials are similar in stoichiometry to the phospho-olivines LiFe(Mn)PO4, but have a more complex structure that can accommodate mixed transition metal oxidation states. They are of interest as candidates for lithium battery cathodes because of their somewhat higher electronic conductivity, high intercalant ion mobility, and ease of preparation. Their performance as intercalation electrodes in non-aqueous lithium cells was, however, poor.

Richardson, Thomas J.

2002-07-22T23:59:59.000Z

469

Nanopower: Avoiding Electrolyte Failure in Nanoscale Lithium ...  

Science Conference Proceedings (OSTI)

... most of which is the battery itself—which ... wide—solid-state lithium ion batteries to see just ... cathode material, electrolyte, and anode materials with ...

2012-04-11T23:59:59.000Z

470

Surface Modification Agents for Lithium Batteries  

Increased safety and life of lithium-ion batteries, ... Electric and plug-in hybrid electric vehicles; Portable electronic devices; Medical devices; and

471

Argonne Transportation Technology R&D Center - Lithium-ion Batteries,  

NLE Websites -- All DOE Office Websites (Extended Search)

Alternative Fuels Autonomie Batteries Downloadable Dynamometer Database Engines Green Racing GREET Hybrid Electric Vehicles Hydrogen & Fuel Cells Materials Modeling, Simulation & Software Plug-In Hybrid Electric Vehicles PSAT Smart Grid Student Competitions Technology Analysis Transportation Research and Analysis Computing Center Working With Argonne Contact TTRDC Photo of battery developers that links to story Press Coverage What's New Multimedia Logo of the Wharton School of Business Dec. 13. Knowledge@Wharton. Green SPorts and Transportation: The Elephant in the Room Logo of Crain's Chicago Business Dec. 10. Crain's Chicago Business. Argonne chemist Pete Chupas named one of Crain's 2013 "40 under 40" Logo of the Sioux City Journal Dec. 2. Sioux City Journal. Ethanol Supporters Say the Numbers Support Their Industry

472

Phase transitions in insertion electrodes for lithium batteries  

DOE Green Energy (OSTI)

Phase transitions that occur during lithium insertion into layered and framework structures are discussed in the context of their application as positive and negative electrodes in lithium-ion batteries. The discussion is focused on the two-dimensional structures of graphite, LiNi{sub 1{minus}x}M{sub x}O{sub 2} (M = Co, Ti and Mg), and Li{sub 1.2}V{sub 3}O{sub 8}; examples of framework structures with a three-dimensional interstitial space for Li{sup +}-ion transport include the spinel oxides and intermetallic compounds with zinc-blende-type structures. The phase transitions are discussed in terms of their tolerance to lithium insertion and extraction and to the chemical stability of the electrodes in the cell environment.

Thackeray, M. M.

2000-02-02T23:59:59.000Z

473

Method of preparing a negative electrode including lithium alloy for use within a secondary electrochemical cell  

DOE Patents (OSTI)

A negative electrode that includes a lithium alloy as active material is prepared by briefly submerging a porous, electrically conductive substrate within a melt of the alloy. Prior to solidification, excess melt can be removed by vibrating or otherwise manipulating the filled substrate to expose interstitial surfaces. Electrodes of such a solid lithium--aluminum filled within a substrate of metal foam are provided. 1 figure, 1 table.

Tomczuk, Z.; Olszanski, W.; Battles, J.E.

1975-12-09T23:59:59.000Z

474

Rechargeable thin-film lithium batteries  

SciTech Connect

Rechargeable thin-film batteries consisting of lithium metal anodes, an amorphous inorganic electrolyte, and cathodes of lithium intercalation compounds have recently been developed. The batteries, which are typically less than 6-{mu}m thick, can be fabricated to any specified size, large or small, onto a variety of substrates including ceramics, semiconductors, and plastics. The cells that have been investigated include Li-TiS{sub 2}, Li-V{sub 2}O{sub 5}, and Li-Li{sub x}Mn{sub 2}O{sub 4}, with open circuit voltages at full charge of about 2.5, 3.6, and 4.2, respectively. The development of these batteries would not have been possible without the discovery of a new thin-film lithium electrolyte, lithium phosphorus oxynitride, that is stable in contact with metallic lithium at these potentials. Deposited by rf magnetron sputtering of Li{sub 3}PO{sub 4} in N{sub 2}, this material has a typical composition of Li{sub 2.9}PO{sub 3.3}N{sub 0.46} and a conductivity at 25{degrees}C of 2 {mu}S/cm. The maximum practical current density obtained from the thin-film cells is limited to about 100 {mu}A/cm{sup 2} due to a low diffusivity of Li{sup +} ions in the cathodes. In this work, the authors present a short review of their work on rechargeable thin-film lithium batteries.

Bates, J.B.; Gruzalski, G.R.; Dudney, N.J.; Luck, C.F.; Yu, Xiaohua

1993-08-01T23:59:59.000Z

475

Diagnostic evaluation of power fade phenomena and calendar lifereduction in high-power lithium-ion batteries  

DOE Green Energy (OSTI)

High-power Li-ion cells with graphite anodes and LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} cathodes that were cycled and stored at elevated temperatures showed a significant impedance rise and capacity fade, which were associated primarily with the LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} cathode. A combination of electrochemical, physical, and chemical diagnostic techniques, including Raman, SEM, and current-sensing AFM, was used to characterize the cathodes from these cells in order to produce a clear picture of the mechanism for cell degradation. Systematic Raman mapping of 50 x 80 {mu}m areas at 0.9 {mu}m spatial resolution produced semi-quantitative composition maps of cathode surfaces. Raman microscopy surface composition maps and SEM images of cathodes from tested cells revealed that cell cycling or storage at elevated temperatures led to significant changes in the LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2}/elemental-carbon surface concentration ratio. The loss of conductive carbon correlated with the power and capacity fade of the tested cathodes and the loss of surface electronic conductivity.

Kostecki, Robert; McLarnon, Frank

2004-05-01T23:59:59.000Z

476

Ionic liquids for rechargeable lithium batteries  

SciTech Connect

We have investigated possible anticipated advantages of ionic-liquid electrolytes for use in lithium-ion batteries. Thermal stabilities and phase behavior were studied by thermal gravimetric analysis and differential scanning calorimetry. The ionic liquids studied include various imidazoliumTFSI systems, pyrrolidiniumTFSI, BMIMPF{sub 6}, BMIMBF{sub 4}, and BMIMTf. Thermal stabilities were measured for neat ionic liquids and for BMIMBF{sub 4}-LiBF{sub 4}, BMIMTf-LiTf, BMIMTFSI-LiTFSI mixtures. Conductivities have been measured for various ionic-liquid lithium-salt systems. We show the development of interfacial impedance in a Li|BMIMBF{sub 4} + LiBF{sub 4}|Li cell and we report results from cycling experiments for a Li|BMIMBF{sub 4} + 1 mol/kg LIBF{sub 4}|C cell. The interfacial resistance increases with time and the ionic liquid reacts with the lithium electrode. As expected, imidazolium-based ionic liquids react with lithium electrodes. We seek new ionic liquids that have better chemical stabilities.

Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz,John; Newman, John

2005-09-29T23:59:59.000Z

477

Feature - Lithium-air Batteries  

NLE Websites -- All DOE Office Websites (Extended Search)

Develop Lithium-Air Battery Li-air Li-air batteries hold the promise of increasing the energy density of Li-ion batteries by as much as five to 10 times. But that potential will...

478

Electrochemical and microstructural studies of AlPO?-nanoparticle coated LiCoO? for lithium-ion batteries  

E-Print Network (OSTI)

AlPO?-nanoparticle coated LiCoO? is studied as a positive electrode for lithium rechargeable batteries for a high-voltage charge limit of 4.7V. To understand the role of the coating in transport phenomena and in deintercalation ...

Appapillai, Anjuli T. (Anjuli Tara)

2006-01-01T23:59:59.000Z

479

Free air breathing planar PEM fuel cell design for portable electronics  

E-Print Network (OSTI)

PEM fuel cell technology is an energy source that can provide several times more energy per unit volume then current lithium ion batteries. However, PEM fuel cells remain to be optimized in volume and mass to create a ...

Crumlin, Ethan J

2005-01-01T23:59:59.000Z

480

Improvement of Thermal Stability of Li-Ion Batteries by Polymer Coating of LiMn2O4  

E-Print Network (OSTI)

lithium-ion battery by arresting the Mn + dissolution, thereby increasing the battery stability. Key Words: Lithium Battery, Cathode,

Stroeve, Pieter; Vidu, Ruxandra

2004-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "lithium ion cells" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

SnO{sub 2}/ZnO composite structure for the lithium-ion battery electrode  

SciTech Connect

In this article, SnO{sub 2}/ZnO composite structures have been synthesized by two steps hydrothermal method and investigated their lithium storage capacity as compared with pure ZnO. It has been found that these composite structures combining the large specific surface area, stability and catalytic activity of SnO{sub 2} micro-crystals, demonstrate the higher initial discharge capacity of 1540 mA h g{sup -1} with a Coulombic efficiency of 68% at a rate of 120 mA h g{sup -1} between 0.02 and 2 V and found much better than that of any previously reported ZnO based composite anodes. In addition, a significantly enhanced cycling performance, i.e., a reversible capacity of 497 mA h g{sup -1} is retained after 40 cycles. The improved lithium storage capacity and cycle life is attributed to the addition of SnO{sub 2} structure, which act as good electronic conductors and better accommodation of the large volume change during lithiation/delithiation process. - Graphical abstract: SnO{sub 2}/ZnO composite structures demonstrate the improved lithium storage capacity and cycle life as compared with pure ZnO nanostructure. Highlights: Black-Right-Pointing-Pointer Synthesis of SnO{sub 2}/ZnO composite structures by two steps hydrothermal approach. Black-Right-Pointing-Pointer Investigation of lithium storage capacity. Black-Right-Pointing-Pointer Excellent lithium storage capacity and cycle life of SnO{sub 2}/ZnO composite structures.

Ahmad, Mashkoor, E-mail: mashkoorahmad2003@yahoo.com [Beijing National Center for Electron Microscopy, The State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Material, China Iron and Steel Research Institute Group, Department of Material Science and Engineering, Tsinghua University, Beijing 100084 (China) [Beijing National Center for Electron Microscopy, The State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Material, China Iron and Steel Research Institute Group, Department of Material Science and Engineering, Tsinghua University, Beijing 100084 (China); Nanomaterial Research Group, Physics Division, PINSTECH, P.O. Nilore, Islamabad (Pakistan); Yingying, Shi [Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China)] [Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Sun, Hongyu [Beijing National Center for Electron Microscopy, The State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Material, China Iron and Steel Research Institute Group, Department of Material Science and Engineering, Tsinghua University, Beijing 100084 (China)] [Beijing National Center for Electron Microscopy, The State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Material, China Iron and Steel Research Institute Group, Department of Material Science and Engineering, Tsinghua University, Beijing 100084 (China); Shen, Wanci [Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China)] [Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Zhu, Jing, E-mail: jzhu@mail.tsinghua.edu.cn [Beijing National Center for Electron Microscopy, The State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Material, China Iron and Steel Research Institute Group, Department of Material Science and Engineering, Tsinghua University, Beijing 100084 (China)] [Beijing National Center for Electron Microscopy, The State Key Laboratory of New Ceramics and Fine Processing, Laboratory of Advanced Material, China Iron and Steel Research Institute Group, Department of Material Science and Engineering, Tsinghua University, Beijing 100084 (China)

2012-12-15T23:59:59.000Z

482

Guidance on the use of Lithium Batteries in NERC Version 1.0 8th  

E-Print Network (OSTI)

a lithium or lithium ion battery fire. · Use plenty of water as a fine spray to swamp and wash away spiltGuidance on the use of Lithium Batteries in NERC Version 1.0 8th March 2007 1. Introduction Lithium. There are several types of lithium batteries but they are all high energy power sources and all are potentially

Edinburgh, University of

483

24 JOM May 1998 The lightest of all metals, lithium is used  

E-Print Network (OSTI)

24 JOM · May 1998 Overview Lithium The lightest of all metals, lithium is used in a variety- nesium, and as the anode in rechargeable lithium ion batteries. All of the world's pri- mary lithium is produced by molten salt electrolysis. This article reviews the current technology for lithium extraction

Sadoway, Donald Robert

484

Layered Nickel Oxide-Based Cathodes for Lithium Cells: Analysis ofPerformance Loss Mechanisms  

DOE Green Energy (OSTI)

Spectroscopic and electrochemical diagnostic measurements are reported for the cell components of a Generation 2 (Gen 2) Li-Ion cell from the US Department of Energy's Advanced Technology Development (ATD) project. The cells are composed of LiNi{sub 0.8}Co{sub 0.15}Al{sub 0.05}O{sub 2} positive electrodes (cathode), carbon graphite anodes and electrolyte consisting of 1.2 M LiPF{sub 6} in EC:EMC 3:7. Fluorophosphates were observed by {sup 19}F and {sup 31}P NMR in the electrolyte obtained from a Gen 2 cell aged 72 weeks at 45 C and presenting 50% power fade. These electrolyte decomposition products were also observed by {sup 31}P solid-state NMR on the surface of the cathode of the same cell. Samples were cut from the aged cathode from the original cell, subjected to different treatments (ultrasonic washing in anhydrous DMC, pressing, ultrasonic washing and pressing), and subsequently reassembled into small lab cells for electrochemical characterization. These treatments recovered the capacity of the electrodes to within a few percent of the original value, with the most improvement being obtained with the washed and pressed cathode. The impedance of the cathodes was also lowered after the ultrasonic washing and pressing treatments. Electron microscopy revealed that the ultrasonic washing of the aged Gen 2 cathode material resulted in the removal of small particles covering the surface of the active cathode. These findings are interpreted in terms of a model whereby capacity loss, and thus power capability, is restored by removing the fluorophosphate deposit and restoring electronic contact to the active cathode material.

Kerlau, Marie; Reimer, Jeffrey A.; Cairns, Elton J.

2004-10-01T23:59:59.000Z

485

A Facile synthesis of flower-like Co{sub 3}O{sub 4} porous spheres for the lithium-ion battery electrode  

Science Conference Proceedings (OSTI)

The porous hierarchical spherical Co{sub 3}O{sub 4} assembled by nanosheets have been successfully fabricated. The porosity and the particle size of the product can be controlled by simply altering calcination temperature. SEM, TEM and SAED were performed to confirm that mesoporous Co{sub 3}O{sub 4} nanostructures are built-up by numerous nanoparticles with random attachment. The BET specific surface area and pore size of the product calcined at 280 deg. C are 72.5 m{sup 2} g{sup -1} and 4.6 nm, respectively. Our experiments further demonstrated that electrochemical performances of the synthesized products working as an anode material of lithium-ion battery are strongly dependent on the porosity. - Graphical abstract: The flower-like Co{sub 3}O{sub 4} porous spheres with hierarchical structure have been successfully prepared via a simple calcination process using cobalt hydroxide as precursor.

Zheng Jun; Liu Jing; Lv Dongping; Kuang Qin [State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Jiang Zhiyuan, E-mail: zyjiang@xmu.edu.c [State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Xie Zhaoxiong; Huang Rongbin; Zheng Lansun [State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)

2010-03-15T23:59:59.000Z

486

Stark spectroscopy of a probe lithium beam excited with two dye lasers as a technique to study a high-power ion-beam diode  

SciTech Connect

A non-disturbing measurement of electric field distributions is a subject of special interest in plasma physics and high-voltage devices. In this paper we describe a diagnostic technique for remote sensing of electric fields via injection of a probe beam of lithium atoms and cascade excitation of resonance fluorescence with two broadband dye lasers. The fluorescence spectrum was recorded using a monochromator equipped with an optical multi-channel analyser. The magnitude of the local electric field was retrieved from the Stark-shifted components of the 3d-2plithium spectral line. The technique was applied to measurements of the electric field in the applied-B-field high-voltage diode of the 1 TW KALIF ion-beam accelerator.

Knyazev, B. A. [Budker Institute of Nuclear Physics SB RAS, 630090 Novosibirsk (Russian Federation); An, W.; Bluhm, H. [Karlsruhe Institute of Technology (KIT), Institute for Pulsed Power and Microwave Technology (IHM), D-76131 Karlsruhe (Germany)

2012-03-15T23:59:59.000Z

487

White Paper for U.S. Army Rapid Equipping Force: Waste Heat Recovery with Thermoelectric and Lithium-Ion Hybrid Power System  

DOE Green Energy (OSTI)

By harvesting waste heat from engine exhaust and storing it in light-weight high-capacity modules, it is believed that the need for energy transport by convoys can be lowered significantly. By storing this power during operation, substantial electrical power can be provided during long periods of silent operation, while the engines are not operating. It is proposed to investigate the potential of installing efficient thermoelectric generators on the exhaust systems of trucks and other vehicles to generate electrical power from the waste heat contained in the exhaust and to store that power in advanced power packs comprised of polymer-gel lithium ion batteries. Efficient inexpensive methods for production of the thermoelectric generator are also proposed. The technology that exists at LLNL, as well as that which exists at industrial partners, all have high technology readiness level (TRL). Work is needed for integration and deployment.

Farmer, J C

2007-11-26T23:59:59.000Z

488

Cathode limited charge transport and performance of thin-film rechargeable lithium batteries  

DOE Green Energy (OSTI)

Several types of thin-film rechargeable batteries based on lithium metal anodes and amorphous V{sub 2}O{sub 5} (aV{sub 2}O{sub 5}), LiMn{sub 2}O{sub 4}, and LiCoO{sub 2} cathodes have been investigated in this laboratory. In all cases, the current density of these cells is limited by lithium ion transport in the cathodes. This paper, discusses sources of this impedance in Li-aV{sub 2}O{sub 5} and Li-LiMn{sub 2}O{sub 4} thin-film cells and their effect on cell performance.

Bates, J.B.; Hart, F.X.; Lubben, D.; Kwak, B.S.; van Zomeren, A.

1994-11-01T23:59:59.000Z

489

Atomic layer deposition of Al2O3 on V2O5 xerogel film for enhanced lithium-ion intercalation stability  

SciTech Connect

V2O5 xerogel films were fabricated by casting V2O5 sols onto fluorine-doped tin oxide glass substrates at room temperature. Five, ten and twenty atomic layers of Al2O3 were grown onto as-fabricated films respectively. The bare film and Al2O3-deposited films all exhibited hydrous V2O5 phase only. Electrochemical impedance spectroscopy study revealed increased surface charge-transfer resistance of V2O5 films as more Al2O3 atomic layers were deposited. Lithium-ion intercalation tests at 600 mAg_1 showed that bare V2O5 xerogel film possessed high initial discharge capacity of 219 mAhg_1 but suffered from severe capacity degradation, i.e., having only 136 mAhg_1 after 50 cycles. After deposition of ten atomic layers of Al2O3, the initial discharge capacity was 195 mAhg_1 but increased over cycles before stabilizing; after 50 cycles, the discharge capacity was as high as 225 mAhg_1. The noticeably improved cyclic stability of Al2O3-deposited V2O5 xerogel film could be attributed to the improved surface chemistry and enhanced mechanical strength. During repeated lithium-ion intercalation/de-intercalation, atomic layers of Al2O3 which were coated onto V2O5 surface could prevent V2O5 electrode dissolution into electrolyte by reducing direct contact between active electrode and electrolyte while at the same time acting as binder to maintain good mechanical contact between nanoparticles inside the film. VC 2012 American Vacuum Society.

Liu, Dawei; Liu, Yanyi; Candelaria, Stephanie L.; Cao, Guozhong; Liu, Jun; Jeong, Yoon-Ha

2012-01-29T23:59:59.000Z

490

Kirkendall-effect-based growth of dendrite-shaped CuO hollow micro/nanostructures for lithium-ion battery anodes  

SciTech Connect

Three-dimensional (3D) dendrite-shaped CuO hollow micro/nanostructures have been prepared via a Kirkendall-effect-based approach for the first time and have been demonstrated as a high-performance anode material for lithium-ion batteries. The as-prepared hollow structures were investigated by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and electrochemical properties. A CuO hollow structure composed of nanocubes outside and a dense film inside was selected as a typical example of the optimized design; it exhibited significantly improved cyclability at a current rate of 0.5 C, with the average Coulombic efficiency of {approx}97.0% and 57.9% retention of the discharge capacity of the second cycle after 50 cycles. The correlation between the structure features of the hollow CuO and their electrochemical behavior was discussed in detail. Smaller size of primary structure and larger internal space of electrode materials are crucial to better electrochemical performance. This work represents that Kirkendall effect is a promising method to fabricate excellent hollow electrode materials for Li-ion batteries. - Graphical abstract: SEM images of 3D dendrite-shaped CuO hollow micro/nanostructures prepared via a Kirkendall-effect-based approach have been shown. The as-prepared CuO electrode exhibited significantly improved cyclability for Li-ion batteries.

Hu Yingying, E-mail: yyhu@phy.ccnu.edu.c [Center for Nanoscience and Nanotechnology, Huazhong Normal University, Wuhan 430079, Hubei (China); Huang Xintang, E-mail: xthuang@phy.ccnu.edu.c [Center for Nanoscience and Nanotechnology, Huazhong Normal University, Wuhan 430079, Hubei (China); Wang Kai; Liu Jinping; Jiang Jian; Ding Ruimin; Ji Xiaoxu; Li Xin [Center for Nanoscience and Nanotechnology, Huazhong Normal University, Wuhan 430079, Hubei (China)

2010-03-15T23:59:59.000Z

491

Treatment of electrochemical cell components with lithium tetrachloroaluminate (LiAlCl.sub.4) to promote electrolyte wetting  

DOE Patents (OSTI)

Electrochemical cell components such as interelectrode separators, retaining screens and current collectors are contacted with lithium tetrachloroaluminate prior to contact with molten electrolytic salt to improve electrolyte wetting. The LiAlCl.sub.4 can be applied in powdered, molten or solution form but, since this material has a lower melting point than the electrolytic salt used in high-temperature cells, the powdered LiAlCl.sub.4 forms a molten flux prior to contact by the molten electrolyte when both materials are initially provided in solid form. Components of materials such as boron nitride and other materials which are difficult to wet with molten salts are advantageously treated by this process.

Eberhart, James G. (Naperville, IL); Battles, James E. (Oak Forest, IL)

1980-01-01T23:59:59.000Z

492

Lithium disulfide battery  

DOE Patents (OSTI)

Disclosed is a negative electrode-limited secondary electrochemical cell having dense FeS/sub 2/ positive electrode operating exclusively on the upper plateau, a Li alloy negative electrode and a suitable lithium-containing electrolyte. The electrolyte preferably is 25 mole % LiCl, 38 mole % LiBr and 37 mole % KBr. The cell may be operated isothermally.

Kaun, T.D.

1986-05-29T23:59:59.000Z

493

Lithium disulfide battery  

SciTech Connect

A negative electrode limited secondary electrochemical cell having dense FeS.sub.2 positive electrode operating exclusively on the upper plateau, a Li alloy negative electrode and a suitable lithium-containing electrolyte. The electrolyte preferably is 25 mole percent LiCl, 38 mole percent LiBr and 37 mole percent KBr. The cell may be operated isothermally.

Kaun, Thomas D. (New Lenox, IL)

1988-01-01T23:59:59.000Z