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1

Kraft Liquor Corrosion Margaret Gorog  

E-Print Network [OSTI]

1 Kraft Liquor Corrosion Margaret Gorog Federal Way, WA Pulp and Paper Corrosion Symposium Georgia Tech Renewable Bioproducts Institute November 2014 · Brown Stock Corrosion · Alkaline Liquor Corrosion · Black Liquor Corrosion ­ Evaporators ­ Research · High Solids Black Liquor Corrosion of Stainless Steel

Das, Suman

2

Gasification of black liquor  

SciTech Connect (OSTI)

A process is described for treating a concentrated aqueous black liquor carbonaceous material and alkali metal sulfur compounds to form a combustible gas and a sulfide-rich melt comprising: (a) providing a gasifier vessel maintained at a pressure of from about 1 to 50 atmospheres and containing a relatively shallow molten salt pool at its bottom within a sump equipped with an overflow discharge; (b) introducing into the top of the drying zone the concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds; (c) evaporating water from the concentrated aqueous black liquor in the drying zone by direct contact of the aqueous black liquor with the hot gas rising from the gasification zone to produce dried black liquor solids; (d) introducing a first portion of an oxygen-containing gas into the gas space in the gasification zone located below the drying zone immediately above the molten salt pool to partially oxidize and gasify a fraction of the carbonaceous material in the dried black liquor solids falling through the zone to form a hot combustible gas; (e) introducing a second portion of the oxygen-containing gas beneath the surface of the molten salt pool in an amount sufficient to cause gasification of essentially all carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool; (f) withdrawing the cooled combustible gas having a higher heating value of at least about 90 Btu/scf (dry basis) from an upper portion of the drying zone; and (g) withdrawing from the overflow discharge in the molten salt reduction zone a melt in which the sulfur content is predominantly in the form of alkali metal sulfide.

Kohl, A.L.

1987-07-28T23:59:59.000Z

3

Gasification of black liquor  

DOE Patents [OSTI]

A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

Kohl, Arthur L. (Woodland Hills, CA)

1987-07-28T23:59:59.000Z

4

Gasification of black liquor  

DOE Patents [OSTI]

A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediately above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone. 2 figs.

Kohl, A.L.

1987-07-28T23:59:59.000Z

5

Combustion of black liquor  

SciTech Connect (OSTI)

This patent describes an improvement in the combustion of black liquor in an existing Tomlison recovery boiler unit in which black liquor is sprayed into a furnace in which it is successively dried, pyrolyzed and converted to a bed of solid carbonaceous residue, using a primary air stream and a secondary air stream and the residue is subsequently converted to a smelt. The improvement comprises: the addition of between an effective amount up to 5% oxygen by volume to the primary air stream directed at the bed of solid carbonaceous residue, the amount of oxygen added being sufficient to increase the adiabatic flame temperature, the combustion rate of the solid carbonaceous material, the rate of pyrolysis, the temperature in the lower portion of the furnace, the the drying rate of black liquor droplets, and to decrease the temperature of the gases entering the heat transfer surfaces in the upper portion of the furnace and the rate of deposit formation on the surfaces and wherein the amount of black liquor combusted is increased as compared with the amount combusted in the same furnace operated without the addition of oxygen to the primary air.

Mullen, W.T.

1989-08-15T23:59:59.000Z

6

Kraft black liquor delivery systems  

SciTech Connect (OSTI)

Improvement of spray nozzles for black liquor injection into kraft recovery furnaces is expected to result from obtaining a controlled, well-defined droplet size distribution. Work this year has centered on defining the capabilities of commercial black liquor nozzles currently in use. Considerations of the observed mechanism of droplet formation suggest a major revision is needed in the theory of how droplets form from these nozzles. High resolution, high sensitivity video has been shown to be superior to flash x-ray as a technique for measuring the droplet size distribution as well as the formation history. An environmentally sound spray facility capable of spraying black liquor at temperatures up to normal firing conditions is being constructed before data acquisition continues. Preliminary correlations have been developed between liquor properties, nozzle design, and droplet size. Three aspects of nozzle design have been investigated: droplet size distribution, fluid sheet thickness, and flow and pressure drop characteristics. The standard deviation about the median droplet size for black liquor is nearly the same as the for a wide variety of other fluids and nozzle types. Preliminary correlation for fluid sheet thickness on the plate of a splashplate nozzle show the strong similarities of black liquor to other fluids. The flow and pressure drop characteristic of black liquor nozzle, follow a simple two-term relationship similar to other flow devices. This means that in routine mill operation of black liquor nozzles only the fluid acceleration in the nozzle is important, viscous losses are quiet small. 21 refs., 53 figs., 10 tabs.

Adams, T.N.; Empie, H.L.; Obuskovic, N.; Spielbauer, T.M.

1990-02-01T23:59:59.000Z

7

Combustion properties of Kraft Black Liquors  

SciTech Connect (OSTI)

In a previous study of the phenomena involved in the combustion of black liquor droplets a numerical model was developed. The model required certain black liquor specific combustion information which was then not currently available, and additional data were needed for evaluating the model. The overall objectives of the project reported here was to provide experimental data on key aspects of black liquor combustion, to interpret the data, and to put it into a form which would be useful for computational models for recovery boilers. The specific topics to be investigated were the volatiles and char carbon yields from pyrolysis of single black liquor droplets; a criterion for the onset of devolatilization and the accompanying rapid swelling; and the surface temperature of black liquor droplets during pyrolysis, combustion, and gasification. Additional information on the swelling characteristics of black liquor droplets was also obtained as part of the experiments conducted.

Frederick, W.J. Jr.; Hupa, M. (Aabo Akademi, Turku (Finland))

1993-04-01T23:59:59.000Z

8

Black Liquor Research Program symposium: proceedings  

SciTech Connect (OSTI)

In the paper pulp industry's recovery boilers, black liquor is sprayed in through nozzle guns near the top of the furnace. This report includes eight papers. (DLC)

Emerson, D.B.; Whitworth, B.A.

1985-03-01T23:59:59.000Z

9

Highly Energy Efficient Directed Green Liquor Utilization (D...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping This factsheet describes a...

10

Causticizing for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The cost-benefit outlook of black liquor gasification (BLG) could be greatly improved if the smelt causticization step could be achieved in situ during the gasification step. Or, at a minimum, the increase in causticizing load associated with BLG could be mitigated. A number of chemistries have been proven successful during black liquor combustion. In this project, three in situ causticizing processes (titanate, manganate, and borate) were evaluated under conditions suitable for high temperature entrained flow BLG, and low temperature steam reforming of black liquor. The evaluation included both thermodynamic modeling and lab experimentation. Titanate and manganate were tested for complete direct causticizing (to thus eliminate the lime cycle), and borates were evaluated for partial causticizing (to mitigate the load increase associated with BLG). Criteria included high carbonate conversion, corresponding hydroxide recovery upon hydrolysis, non process element (NPE) removal, and economics. Of the six cases (three chemistries at two BLG conditions), only two were found to be industrially viable: titanates for complete causticizing during high temperature BLG, and borates for partial causticizing during high temperature BLG. These two cases were evaluated for integration into a gasification-based recovery island. The Larsen [28] BLG cost-benefit study was used as a reference case for economic forecasting (i.e. a 1500 tpd pulp mill using BLG and upgrading the lime cycle). By comparison, using the titanate direct causticizing process yielded a net present value (NPV) of $25M over the NPV of BLG with conventional lime cycle. Using the existing lime cycle plus borate autocausticizing for extra capacity yielded a NPV of $16M.

Scott Sinquefeld; James Cantrell; Xiaoyan Zeng; Alan Ball; Jeff Empie

2009-01-07T23:59:59.000Z

11

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. This report covers Task 1.3, Simulative corrosion of candidate materials developed by refractory producers and in the laboratory based on the results of Task 1.1 and Task 1.2. Refractories provided by in-kind sponsors were tested by cup testing, density/porosity determinations, chemical analysis and microscopy. The best performing materials in the cup testing were fused cast materials. However, 2 castables appear to outperforming any of the previously tested materials and may perform better than the fused cast materials in operation. The basis of the high performance of these materials is the low open porosity and permeability to black liquor smelt.

William L. Headrick Jr; Musa Karakus; Jun Wei

2005-03-01T23:59:59.000Z

12

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

2004-10-01T23:59:59.000Z

13

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO2 and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick; Musa Karakus; Alireza Rezaie

2004-03-30T23:59:59.000Z

14

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

2004-07-01T23:59:59.000Z

15

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected/developed that either react with the gasifier environment to form protective surfaces in-situ; and were functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development were divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang

2005-10-01T23:59:59.000Z

16

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr.; Alireza Rezaie

2004-04-01T23:59:59.000Z

17

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

2005-04-01T23:59:59.000Z

18

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang

2005-07-01T23:59:59.000Z

19

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO{sub 2} and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

2005-01-01T23:59:59.000Z

20

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Alireza Rezaie

2003-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected or developed that reacted with the gasifier environment to form protective surfaces in-situ; and were functionally-graded to give the best combination of thermal, mechanical and physical properties and chemical stability; and are relatively inexpensive, reliable repair materials. Material development was divided into 2 tasks: Task 1 was development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesium aluminate and barium aluminate for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO2 and SiC. Task 2 was finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Alireza Rezaie; Xiaoting Liang; Musa Karakus; Jun Wei

2005-12-01T23:59:59.000Z

22

REFRACTORY FOR BLACK LIQUOR GASIFIERS  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr.; Alireza Rezaie

2003-12-01T23:59:59.000Z

23

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

William L. Headrick Jr; Alireza Rezaie

2003-08-01T23:59:59.000Z

24

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. Material development will be divided into 2 tasks: Task 1, Development and property determinations of improved and existing refractory systems for black liquor containment. Refractory systems of interest include magnesia aluminate and baria aluminate spinels for binder materials, both dry and hydratable, and materials with high alumina contents, 85-95 wt%, aluminum oxide, 5.0-15.0 wt%, and BaO, SrO, CaO, ZrO and SiC. Task 2, Finite element analysis of heat flow and thermal stress/strain in the refractory lining and steel shell of existing and proposed vessel designs. Stress and strain due to thermal and chemical expansion has been observed to be detrimental to the lifespan of existing black liquor gasifiers. The thermal and chemical strain as well as corrosion rates must be accounted for in order to predict the lifetime of the gasifier containment materials.

Robert E. Moore; William L. Headrick; Alireza Rezaie

2003-03-31T23:59:59.000Z

25

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. This report covers Task 1.4, Industrial Trial of candidate materials developed by refractory producers and in the laboratory based on the results of Task 1.1, 1.2 and 1.3. Refractories provided by in-kind sponsors to industrial installations tested by cup testing, density/porosity determinations, chemical analysis and microscopy. None of the materials produced in this program have been tried in high temperature gasifiers, but the mortar developed Morcocoat SP-P is outperforming other mortars tested at ORNL. MORCO PhosGun M-90-O has shown in laboratory testing to be an acceptable candidate for hot and cold repairs of existing high temperature gasifiers. It may prove to be an acceptable lining material.

William L. Headrick Jr; Musa Karakus; Xiaoting Laing

2005-10-01T23:59:59.000Z

26

Lowering kraft black liquor viscosity of ultrafiltration  

SciTech Connect (OSTI)

High viscosity is a major factor limiting the percentage total dissolved solids (%TDS) to which kraft black liquor (KBL), a spent pulping liquor, can be concentrated before it is burned to recover its fuel value and its inorganic chemicals. The effect on black liquor viscosity of removing high molecular weight lignin by ultrafiltration of 16% and 24% TDS liquors was studied. Viscosities of ultrafiltration permeates were reduced relative to feed black liquors. When a permeate was concentrated to higher %TDS levels, its viscosity decreased yet further relative to feed samples evaporated to similar solids levels. Retentate viscosity was very high relative to both feed and permeate. Ultrafiltration was carried out at 75/degrees/C using polysulfone membranes in a plate-and-frame or hollow fiber system. Flux rates varied greatly depending upon the specific liquor used. Flux was enhanced by increased temperature and increased linear velocity. The membrane molecular weight cutoff (MWCO) typically used was 50,000; increasing 100,000 or 200,000 did not enhance flux.

Hill, M.K.; Violette, D.A.; Woerner, D.L.

1988-10-01T23:59:59.000Z

27

Black liquor gasifier/gas turbine cogeneration  

SciTech Connect (OSTI)

The kraft process dominates pulp and paper production worldwide. Black liquor, a mixture of lignin and inorganic chemicals, is generated in this process as fiber is extracted from wood. At most kraft mills today, black liquor is burned in Tomlinson boilers to produce steam for on-site heat and power and to recover the inorganic chemicals for reuse in the process. Globally, the black liquor generation rate is about 85,000 MW{sub fuel} (or 0.5 million tonnes of dry solids per day), with nearly 50% of this in North America. The majority of presently installed Tomlinson boilers will reach the end of their useful lives during the next 5 to 20 years. As a replacement for Tomlinson-based cogeneration, black liquor-gasifier/gas turbine cogeneration promises higher electrical efficiency, with prospective environmental, safety, and capital cost benefits for kraft mills. Several companies are pursuing commercialization of black liquor gasification for gas turbine applications. This paper presents results of detailed performance modeling of gasifier/gas turbine cogeneration systems using different black liquor gasifiers modeled on proposed commercial designs.

Consonni, S. [Politecnico di Milano (Italy). Dept. di Energetica; Larson, E.D.; Keutz, T.G. [Princeton Univ., NJ (United States); Berglin, N. [Chalmers Univ. of Technology, Goteborg (Sweden). Dept. of Heat and Power Technology

1998-07-01T23:59:59.000Z

28

Pulsed combustion process for black liquor gasification  

SciTech Connect (OSTI)

The objective of this project is to test an energy efficient, innovative black liquor recovery system on an industrial scale. In the MTCI recovery process, black liquor is sprayed directly onto a bed of sodium carbonate solids which is fluidized by steam. Direct contact of the black liquor with hot bed solids promotes high rates of heating and pyrolysis. Residual carbon, which forms as a deposit on the particle surface, is then gasified by reaction with steam. Heat is supplied from pulse combustor resonance tubes which are immersed within the fluid bed. A portion of the gasifier product gas is returned to the pulse combustors to provide the energy requirements of the reactor. Oxidized sulfur species are partially reduced by reaction with the gasifier products, principally carbon monoxide and hydrogen. The reduced sulfur decomposed to solid sodium carbonate and gaseous hydrogen sulfide (H{sub 2}S). Sodium values are recovered by discharging a dry sodium carbonate product from the gasifier. MTCI's indirectly heated gasification technology for black liquor recovery also relies on the scrubbing of H{sub 2}S for product gases to regenerate green liquor for reuse in the mill circuit. Due to concerns relative to the efficiency of sulfur recovery in the MTCI integrated process, an experimental investigation was undertaken to establish performance and design data for this portion of the system.

Durai-Swamy, K.; Mansour, M.N.; Warren, D.W.

1991-02-01T23:59:59.000Z

29

Improved recovery of tall oil from black liquors  

SciTech Connect (OSTI)

Applying a d.c. of less than 15 V to acidified black liquor separates a significant amount of tall oil remaining in the black liquor sludge. An apparatus with graphite electrodes for this process is described.

Zucker, J.

1980-12-09T23:59:59.000Z

30

In Situ Causticizing for Black Liquor Gasification  

SciTech Connect (OSTI)

Black liquor gasification offers a number of attractive incentives to replace Tomlinson boilers but it also leads to an increase in the causticizing load. Reasons for this have been described in previous reports (FY04 ERC, et.al.). The chemistries have also been covered but will be reviewed here briefly. Experimental results of the causticizing reactions with black liquor are presented here. Results of the modeling work were presented in detail in the Phase 1 report. They are included in Table 2 for comparison but will not be discussed in detail. The causticizing agents were added to black liquor in the ratios shown in Table 1, mixed, and then spray-dried. The mixture ratios (doping levels) reflect amount calculated from the stoichiometry above to achieve specified conversions shown in the table. The solids were sieved to 63-90 microns for use in the entrained flow reactors. The firing conditions are shown in Table 2. Pictures and descriptions of the reactors can be found in the Phase 1 annual report. Following gasification, the solids (char) was collected and analyzed by coulometric titration (for carbonate and total carbon), and by inductively coupled plasma emission spectroscopy (ICP) for a wide array of metals.

Scott Alan Sinquefield

2005-10-01T23:59:59.000Z

31

Electrochemical treatment of black liquor from straw pulping  

SciTech Connect (OSTI)

The conventional black liquor regeneration process is not always suitable for pulping plants of nonwood fibers due to the unfavorable ratio of organic to inorganic solids. This paper presents an alternative treatment based on an electrolysis process of the soda black liquor from straw pulping. This alternative method minimizes the environmental impact by recovering the caustic at the same time that the liquor is acidified, which favors the later separation of the lignin.

Blanco, M.A.; Negro, C.; Tijero, J. [Complutense Univ., Madrid (Spain)] [and others

1996-11-01T23:59:59.000Z

32

Thermal processing of black liquor from alkaline straw pulping  

SciTech Connect (OSTI)

Black liquor is the wastewater from the cooking of wood or straw in the production of pulp and paper. Nowadays new processes are being investigated as alternatives to the traditional recovery boiler used for black liquor treatment. One of the processes which appears to be more promising is gasification, for which further research is needed for its full industrial implementation. There is not much data about the behavior of soda black liquors from straw cooking in the literature. Therefore the thermal decomposition of one of these liquors has been studied in a thermobalance, in inert (N{sub 2}) atmosphere. The kinetic constants from isothermal experiments have been obtained.

Sanchez, J.L.; Garcia, L.; Gea, G.; Bilbao, R.; Arauzo, J. [Univ. of Zaragoza (Spain)

1996-12-31T23:59:59.000Z

33

Physical properties of Kraft Black Liquor. Interim report, Phase II  

SciTech Connect (OSTI)

Objectives are to determine the rheological, thermal, and surface properties of Kraft Black Liquors, and to relate these properties to the chemical composition and to pulping conditions. A four-variable, multi-level pulping experiment is being conducted. Pulping results are reported. Complete analyses of the liquors have been done. Thermal analyses have been done. DSC was employed to determine heat capacities of black liquors and lignins. Rheological (viscosity) studies are being conducted. Density and thermal expansion have been studied for seven liquors. Energy savings through more efficient recovery systems are appreciable.

Fricke, A.L.

1985-03-01T23:59:59.000Z

34

Fundamental studies of black liquor combustion  

SciTech Connect (OSTI)

The fundamentals of black liquor combustion are being studied in a project being carried out for the US Department of Energy by the Institute of Paper Science Technology (IPST, formerly the Institute of Paper Chemistry) and the National Institute of Science Technology (NIST, formerly the National Bureau of Standards). The project was divided into four phases. This report covers the completion of Phase 1 (in-flight processes), the results of all of the work on Phase 2 (char bed processes), Phase 3 (fume processes), and Phase 4 (furnace simulation). 41 refs., 62 figs., 30 tabs.

Clay, D.T.; Lien, S.J.; Grace, T.M.; Brown, C.A.; Empie, H.L.; Macek, A.; Amin, N.; Charangundla, S.R.

1990-03-01T23:59:59.000Z

35

Effect of pulping conditions and black liquor composition on Newtonian viscosity of high solids kraft black liquors  

SciTech Connect (OSTI)

The influence of black liquor composition and solids concentrations on the Newtonian viscosity of slash pine black liquors over wide ranges of temperature (up to 140 C) and solids concentrations (between 50% and 83% solids) has been studied. It was found that the zero shear rate viscosity of high solids black liquors depends strongly on the cooking conditions and/or black liquor composition. Not only is high solids viscosity affected by lignin molecular weight and lignin concentration in the liquor but other organic and inorganic constituents of black liquor also make a significant contribution to viscosity. The dependency of zero shear rate viscosity on solids concentrations, and temperature is defined. The Newtonian viscosities vary over a wide range depending on temperature, solids concentrations and solids composition. The results indicate that, at fixed levels of effective alkali and sulfidity, the zero shear rate viscosities can be described as a function of both lignin concentration and lignin molecular weight. The viscosity of black liquor is an increasing function of the organics-to-inorganics ratio and is a decreasing function of the concentration of sodium and chloride ions and pH of the liquor.

Zaman, A.A.; Fricke, A.L. [Univ. of Florida, Gainesville, FL (United States). Dept. of Chemical Engineering] [Univ. of Florida, Gainesville, FL (United States). Dept. of Chemical Engineering

1996-02-01T23:59:59.000Z

36

Liquor Activity Reduction (LAR) Programme - 12397  

SciTech Connect (OSTI)

Waste material from the reprocessing of irradiated fuel has been stored under water for several decades leading to the water becoming highly radioactive. As a critical enabler to the decommissioning strategy for the Sellafield site, the Liquor Activity Reduction (LAR) programme has been established to provide a processing route for this highly radioactive liquor. This paper reviews the progress that has been made since the start of routine LAR transfer cycles (July 2010) and follows on from the earlier paper presented at WM2011. The paper focuses on the learning from the first full year of routine LAR transfer cycles and the application of this learning to the wider strategies for the treatment of further radioactive liquid effluents on the Sellafield site. During this period over 100,000 Curies of radioactivity has been safely removed and treated. The past year has witnessed the very successful introduction of the LAR programme. This has lead to hazard reduction at MSSS and demonstration that the SIXEP facility can meet the significantly increased challenge that the LAR programme represents. Part of the success has been the ability to predict and deliver a realistic production schedule with the availability of the MSSS, EDT and SIXEP facilities being central to this. Most importantly, the LAR programme has been successful in bringing together key stakeholders to deliver this work while integrating with the existing, day to day, demands of the Sellafield site. (authors)

Pether, Colin; Carrol, Phil; Birkett, Eddie; Kibble, Matthew [Sellafield Ltd, Cumbria (United Kingdom)

2012-07-01T23:59:59.000Z

37

Kraft black liquor combustion: Advancement in fundamental understanding  

SciTech Connect (OSTI)

Self-generated fuel streams plus purchased fossil fuel and power supply the pulp and paper industry with its energy requirements. The total industry energy use for 1986 was approximately 2.3 Quad (2300 trillion Btus). Self-generated and residue fuels accounted for 57% of the energy requirements. Spent pulping liquors provide the single largest self-generated energy source, approximately one Quad (900 trillion Btus). The pulp and paper industry also leads the nation in cogeneration performance. In 1986 eighty-nine percent (89%) of the 46 billion KWHs generated were produced by cogeneration. Spent pulping liquors supply the single largest fuel source (35%) to these cogeneration facilities. Spent pulping liquors consist of solubilized wood organics, spent inorganic chemicals, and water. Since kraft pulp dominates the North American market, 74%, kraft black liquor is the dominant spent pulping liquor. Effective recovery of high level energy and chemicals from black liquor contributes heavily toward dominance of kraft pulping. The kraft chemical recovery cycle centers around the recovery boiler. Kraft recovery boilers have been commercially available for over 50 years. The potential still exists, however, for significant improvements in energy recovery and black liquor throughput. Potential energy benefits from black liquor combustion research amount to 30 trillion Btus. Energy recovery increases often are an additional benefit from modifications made to increase black liquor throughput. Capacity increases of at least 5% are often achievable. Increased energy productivity of the kraft chemical recovery boiler will come by incorporation of improved fundamental knowledge into the technology used for boiler upgrades and new boiler construction. 5 refs., 9 figs.

Clay, D.T.

1987-10-01T23:59:59.000Z

38

Proceedings of the black liquor research program review fourth meeting held July 28--30, 1987  

SciTech Connect (OSTI)

Research programs, presented at the black liquor review meeting are described. Research topics include the following: Cooperative Program in Kraft Recovery; Black Liquor Physical Properties; Viscosity of Strong Black Liquor; Ultrafiltration of Kraft Black Liquor; Molecular Weight Distribution of Kraft Lignin; Black Liquor Droplet Formation Project; Fundamental Studies of Black Liquor Combustion; Black Liquor Combustion Sensors; Flash X-ray Imagining of Black Liquor Sprays; Laser Induced Fluorescence For Process Control In The Pulp and Paper Industry; Recovery Boiler Optimization; Black Liquor Gasification and Use of the Products in Combined-Cycle Cogeneration; Black Liquor Steam Plasma Automization; The B and W Pyrosonic 2000R System; Monsteras Boiler Control System; and Cooperative Program Project Reviews. Individual projects are processed separately for the data bases.

Emerson, D. B.; Whitworth, B. A.

1987-10-01T23:59:59.000Z

39

Char reactions during kraft black liquor pyrolysis  

SciTech Connect (OSTI)

The pyrolysis characteristics of dried black liquor particles were investigated at high heating rates in a laminar entrained-flow reactor at temperatures of 600-1100{degrees}C. Primary pyrolysis of the organic fraction occurred very rapidly, in less 0.5 seconds. Char yields at the end or volatiles evolution were 58-72%. The decreased with increasing reactor temperature to 900{degrees}C but remained constant at higher temperatures. 35-65% of the fuel nitrogen was volatilized, nearly all in less than 0.5 s. Relatively little fuel nitrogen was evolved from the char. Significant alkali metal chloride volatization from the char occurred at all temperatures, while additional sodium volatilization became important above 900{degrees}C. Reduction of sulfur species in the char increased rapidly with increasing temperature. A temperature-dependent delay time in the onset of Na{sub 2}S formation was observed.

Frederick, W.J.; Sricharoenchaikul, V.; Reis, V.V. [Oregon State Univ., Corvallis, OR (United States)

1995-12-01T23:59:59.000Z

40

Demonstration of Black Liquor Gasification at Big Island  

SciTech Connect (OSTI)

This Final Technical Report provides an account of the project for the demonstration of Black Liquor Gasification at Georgia-Pacific LLC's Big Island, VA facility. This report covers the period from May 5, 2000 through November 30, 2006.

Robert DeCarrera

2007-04-14T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Drum drying of black liquor using superheated steam impinging jets  

SciTech Connect (OSTI)

A novel drum dryer for black liquor utilizing multiple impinging jets of superheated steam was designed and built to evaluate the performance characteristics and effects of various operating parameters thereon. Appropriate ranges of parameters such as steam jet temperature and velocity were examined experimentally to quantify the optimal operating conditions for the formation of black liquor film on the drum surface as well as the drying kinetics.

Shiravi, A.H.; Mujumdar, A.S.; Kubes, G.J. [McGill Univ., Montreal, Quebec (Canada)

1997-05-01T23:59:59.000Z

42

Controlled black liquor viscosity reduction through salting-in  

SciTech Connect (OSTI)

Black liquor viscosity increases exponentially with solids content and therefore causes processing problems for the paper industry by being a limiting factor in the Kraft pulp process. This study investigates a new approach for achieving viscosity reduction by salting-in black liquor through the addition of thiocyanate salts. These salts generally increase the solubility of the polymer constituents in black liquor, leading to a decrease in its viscosity. Several thiocyanate salts capable of reducing liquor viscosity by more than two orders of magnitude have been identified, with viscosity reduction greatest at high solids content. Salting-in of black liquor depends on the cation paired with the thiocyanate anion, as well as on solution pH and temperature. Comparative studies reveal the most effective viscosity-reducing agent of the series examined and that lignin plays an important role in the viscosity behavior of both unmodified and salted-in black liquor at high solids concentrations. These experimental findings are interpreted in terms of the underlying principles that describe salting-in and how it affects aqueous solution structure.

Roberts, J.E.; Khan, S.A.; Spontak, R.J. [North Carolina State Univ., Raleigh, NC (United States)] [North Carolina State Univ., Raleigh, NC (United States)

1996-08-01T23:59:59.000Z

43

Proceedings of the black liquor research program review fifth meeting  

SciTech Connect (OSTI)

On June 14--17, 1988 the participants and invited guests of the Cooperative Program in Kraft Recovery gathered in Charleston, South Carolina, to review progress on four major black liquor research programs being executed at the Institute of Paper Chemistry, the University of Maine, the National Bureau of Standards, and the University of Florida. These programs include: (1) Black Liquor Properties; (2) Black Liquor Droplet Formation; (3) Black Liquor Nozzle Evaluation; and (4) Black Liquor Combustion. In addition to the objectives of previous meetings, this meeting made a direct attempt to gather ideas on how to improve our ability to move from new technology concepts to commercial implementation. Also attached is the agenda for the Charleston meeting. The first two days were involved with updates and reviews of the four major black liquor programs. A half day was spent discussing pathways to implementation and developing thoughts on what industry, DOE and academia could do to facilitate commercial implementation of the research results. This publication is a summary of the presentations made in Charleston and the industry responses to the research work. Readers are cautioned that the contents are in-progress updates on the status of the research and do not represent referred technical papers. Any questions regarding the content should be referred to the principal investigators of the project.

Not Available

1988-09-01T23:59:59.000Z

44

Measurement of black liquor surface tension: Technical report No. 3. [Black liquor  

SciTech Connect (OSTI)

Surface tension and density of two kraft black liquors were measured at a series of temperatures, from a minimum value when gas bubbles can be blown into the liquor to a maximum value near the elevated boiling point of a particular sample. Available methods for the measurement of surface tension were evaluated critically and, as a result, the maximum bubble pressure method was selected. Varying the flow rate of the gas changes the frequency of bubble formation and thereby the age of the surface. The parameter has been utilized by many researchers to monitor the diffusion of low surface energy components (e.g., surfactants) to the liquid/air interface. The effect of bubble frequency when tested with a few pure liquids, indicated that the dynamics of bubble formation had to be further examined to separate out inertial and viscous effects from purely surface tension related pressure. The pressure versus flow rate data were extrapolated to zero flow rate and surface tension and density were calculated using these extrapolated values. As expected, surface tension decreased with increasing temperature for all the samples. Surface tension decreases with increasing solids content (when compared with the value for water) to a certain level (about 20%) and it starts to increase again. The decrease in surface tension in the dilute black liquor, is probably due to the decrease in the concentration of water, which has a high surface tension value. The occurrence of the minimum is probably due to the effect of inorganic components dominating over the effect of surfactants and other components. Reduction in the solubilities of the inorganics, promotion of micelles of the surfactants and reduction in the diffusion of surfactants to the surface, also could contribute to this phenomenon. 54 refs., 54 figs., 12 tabs.

Krishnagopalan, J.

1987-09-01T23:59:59.000Z

45

Recaustization of kraft black liquor via bipolar electrodialysis  

SciTech Connect (OSTI)

The US Department of Energy in conjunction with HPD Inc. supported a research program to perform a laboratory feasibility study with various black liquor samples for the recaustization of these samples via bipolar electrodialysis. The research was conducted at the HPD pilot plant facility in Plainfield, Illinois, beginning in April 1989. This report is a summary of the work completed thru November 1989. The program was designed to operate the electrodialyzer in order to obtain performance and engineering data such as current efficiency, power consumption per gram of NaOH produced, and assess fouling and/or membrane durability. Prior to the electrodialysis laboratory runs, the black liquor samples were pretreated in order to remove as much lignin as possible. The black liquor samples were air oxidized, acidified to pH = 9.0 and pH = 2.0 and later filtered via a Buchner funnel under vacuum. The filtrate was then utilized to become the feed to the electrodialysis stack. Initial test runs were performed with synthetic solutions of either sodium sulfate or sodium bicarbonate in order to determine acceptable operating current, power, current efficiencies, and fouling behavior. A second set of test were conducted with a series of four Southern Kraft black liquor samples. Based on the results of this study, it was determined that the use of bipolar electrodialysis for producing a caustic stream and an acidified black liquor stream is feasible and was demonstrated. 9 refs., 27 figs., 32 tabs.

Koumoundouros, J.A.; Oshen, S.; Lynch, J.D.

1990-05-01T23:59:59.000Z

46

Ultrafiltration of kraft black liquor: Final report, Phase 3  

SciTech Connect (OSTI)

Since 1981, a research program has been in progress to determine the physical properties of kraft black liquors and to develop methods for reduction of data and correlation of properties with pumping conditions. The basic premise that has been used to direct the research program is that kraft black liquor behaves as a polymer solution, particularly at high solids, and that the behavior is dominated by the characteristics of the lignin present. This premise is proving to be correct, and the principles that follow from this premise are proving to be successful for data reduction and correlation. The research has been a complex program involving experimental pulping, chemical analysis, lignin separation and characterization, thermal analysis, rheological measurements, and considerable equipment and methods development. Due to the complexity of the program, the unforeseen need to expend a great deal of effort in development of experimental techniques for analysis, and the fact that our liquors proved to be unstable at high temperatures and solids, all of the original objectives could not be accomplished. However, our program has added substantially to the body of knowledge of physical properties of black liquor. Our results indicate that the goal of developing correlations for physical properties of kraft black liquor is practical and can be realized through extension of the present work. 21 refs., 32 figs.

Hill, M.K.

1988-04-01T23:59:59.000Z

47

Black liquor gasification phase 2D final report  

SciTech Connect (OSTI)

This report covers work conducted by Rockwell International under Amendment 5 to Subcontract STR/DOE-12 of Cooperative Agreement DE-AC-05-80CS40341 between St. Regis Corporation (now Champion International) and the Department of Energy (DOE). The work has been designated Phase 2D of the overall program to differentiate it from prior work under the same subcontract. The overall program is aimed at demonstrating the feasibility of and providing design data for the Rockwell process for gasifying Kraft black liquor. In this process, concentrated black liquor is converted into low-Btu fuel gas and reduced melt by reaction with air in a specially designed gasification reactor.

Kohl, A.L.; Stewart, A.E.

1988-06-01T23:59:59.000Z

48

Advancement of High Temperature Black Liquor Gasification Technology  

SciTech Connect (OSTI)

Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and procurement of facility upgrades. Chemrec AB is also operating a pressurized, O2-blown gasifier pilot facility in Piteaa, Sweden. There was an exchange of knowledge with the pressurized projects including utilization of the experimental results from facilities in Piteaa, Sweden. Resources at the Georgia Tech Research Corporation (GTRC, a.k.a., the Institute of Paper Science and Technology) were employed primarily to conduct the fundamental investigations on scaling and plugging mechanisms and characterization of green liquor dregs. The project also tapped GTRC expertise in the development of the critical underlying black liquor gasification rate subroutines employed in the CFD code. The actual CFD code development and application was undertaken by Process Simulation, Ltd (PSL) and Simulent, Ltd. PSL focused on the overall integrated gasifier CFD code, while Simulent focused on modeling the black liquor nozzle and description of the black liquor spray. For nozzle development and testing Chemrec collaborated with ETC (Energy Technology Centre) in Piteae utilizing their test facility for nozzle spray investigation. GTI (Gas Technology Institute), Des Plains, IL supported the team with advanced gas analysis equipment during the gasifier test period in June 2005.

Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

2008-03-31T23:59:59.000Z

49

A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report  

SciTech Connect (OSTI)

The overall objective of the program was to develop correlations to predict physical properties within requirements of engineering precision from a knowledge of pulping conditions and of kraft black liquor composition, if possible. These correlations were to include those relating thermodynamic properties to pulping conditions and liquor composition. The basic premise upon which the research was based is the premise that black liquor behaves as a polymer solution. This premise has proven to be true, and has been used successfully in developing data reduction methods and in interpreting results. A three phase effort involving pulping, analysis of liquor composition, and measurement of liquor properties was conducted.

Fricke, A.L.; Zaman, A.A.

1998-05-01T23:59:59.000Z

50

Report on the WORKSHOP ON COMMERCIALIZATION OF BLACK LIQUOR  

E-Print Network [OSTI]

Report on the WORKSHOP ON COMMERCIALIZATION OF BLACK LIQUOR AND BIOMASS GASIFICATION FOR GAS or industry cycle (BGCC) technologies for pulp and paper co~mitm~nt to the develo~ment of gasification systems (existing) technology with an greenhouse gas emissions mitigation measures. emerging (gasification

51

CHAMPAIGN-URBANA FOOD AND LIQUOR GUIDE 1. Introduction  

E-Print Network [OSTI]

(217) 352-7467. Excellent Mexican and Latin American- influenced food. Service can be a bit slowCHAMPAIGN-URBANA FOOD AND LIQUOR GUIDE 1. Introduction This is a short, incomplete, and personally. It is standard to tip 15-20% for reasonable service. A indicates a place that we like, and indicates a place we

Athreya, Jayadev

52

Sodium and sulfur release and recapture during black liquor burning  

SciTech Connect (OSTI)

The objective of this study was to provide data on sulfur and sodium volatilization during black liquor burning, and on SO2 capture by solid sodium carbonate and sodium chloride. This data was interpreted and modeled into rate equations suitable for use in computational models for recovery boilers.

Frederick, W.J.; Iisa, K.; Wag, K.; Reis, V.V.; Boonsongsup, L.; Forssen, M.; Hupa, M.

1995-08-01T23:59:59.000Z

53

In situ analysis of ash deposits from black liquor combustion  

SciTech Connect (OSTI)

Aerosols formed during combustion of black liquor cause a significant fire-side fouling problem in pulp mill recovery boilers. The ash deposits reduce heat transfer effectiveness, plug gas passages, and contribute to corrosion. Both vapors and condensation aerosols lead to the formation of such deposits. The high ash content of the fuel and the low dew point of the condensate salts lead to a high aerosol and vapor concentration in most boilers. In situ measurements of the chemical composition of these deposits is an important step in gaining a fundamental understanding of the deposition process. Infrared emission spectroscopy is used to characterize the composition of thin film deposits resulting from the combustion of black liquor and the deposition of submicron aerosols and vapors. New reference spectra of Na{sub 2}SO{sub 4}, K{sub 2}SO{sub 4}, Na{sub 2}CO{sub 3} and K{sub 2}CO{sub 3} pure component films were recorded and compared with the spectra of the black liquor deposit. All of the black liquor emission bands were identified using a combination of literature data and ab initio calculations. Ab initio calculations also predict the locations and intensities of bands for the alkali vapors of interest. 39 refs., 9 figs.

Bernath, P. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Toronto, Ontario (Canada); Sinquefield, S.A. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Oregon State Univ., Eugene, OR (United States); Baxter, L.L.; Sclippa, G.; Rohlfing, C. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility; Barfield, M. [Sandia National Labs., Livermore, CA (United States). Combustion Research Facility]|[Univ. of Arizona, Tucson, AZ (United States)

1996-05-01T23:59:59.000Z

54

A comprehensive program to develop correlations for the physical properties of kraft black liquors  

SciTech Connect (OSTI)

Experimental work includes pulping, liquor analysis, lignin purification and characterization, vapor-liquid equilibria, heat capacity, heats of solution and combustion, and viscosity measurements. It is now possible to operate the digester as a closed, rotating reactor or as a batch reactor with liquor circulation. When operated with liquor circulation, temperatures within the chip bed can be monitored during cooking. Cooking is reproducible, and cooks are being performed to produce liquors for experimental studies. The digester could be further modified to permit them to conduct rapid exchange batch pulping or to permit them to simulate continuous pulping. Liquors are now routinely analyzed to determine all components, except higher molecular weight organic acids and extractives. Lignin determination by UV-visible means has been improved. Lignin purification from black liquor has been improved and lignin molecular weights are determined routinely. The paper describes the digestor, the large scale evaporation, liquor analysis, thermal studies, and viscosity results. 31 figs., 5 tabs.

Fricke, A.L.

1990-12-01T23:59:59.000Z

55

Recovery of solvent and by-products from organosolv black liquor  

SciTech Connect (OSTI)

The recovery of alcohol and by-products from ethanol-water and methanol-water pulping liquors was studied. The recovery system proposed consists of three stages: black liquor flashing, lignin precipitation, and precipitation distillation of mother liquor. At the flash stage, 47 and 51% of the alcohol in the black liquor are recovered for ethanol and methanol processes, respectively. The lignin recovery yield at the precipitation stage is 67% for ethanol black liquor and 73% for methanol black liquor. The distillation of precipitation mother liquors enables recovery of 98% ethanol and 96% methanol from this stream as distillate, whereas the distillation residue contains significant amounts of sugars, furfural, and acetic acid that can be recovered. The study concludes with the overall mass balance for the recovery system proposed.

Botello, J.I.; Gilarranz, M.A.; Rodriguez, F.; Oliet, M. [Univ. Complutense de Madrid (Spain). Dept. de Ingenieria Quimica] [Univ. Complutense de Madrid (Spain). Dept. de Ingenieria Quimica

1999-09-01T23:59:59.000Z

56

Physical properties of kraft black liquor. Final report. Phase I  

SciTech Connect (OSTI)

Methods were selected, equipment installed, and procedures developed for determining rheological properties; for determining thermal properties (stability, density, thermal expansion, and heat capacity); for purification and characterization of lignin (glass transition, stability, weight average molecular weight, and number average molecular weight); and for performing chemical analyses (negative inorganic ions, positive inorganic ions, acid organic salts, lignin, and total solids). A strategy for pulping to supply test liquors was developed, and a statistically designed pulping experiment was specified for a Southern softwood species. Arrangements were made for performing initial pulping work in an industrial pilot plant, and a preliminary set of pulping experiments were conducted. Liquors from the preliminary pulping experiments were used to test procedures and to determine reproducibility of the experiment. Literature was also surveyed and preliminary selection of designs for a pilot digester, and for equipment to determine surface tension were made.

Fricke, A.L.

1983-12-01T23:59:59.000Z

57

Conceptual design of a black liquor gasification pilot plant  

SciTech Connect (OSTI)

In July 1985, Champion International completed a study of kraft black liquor gasification and use of the product gases in a combined cycle cogeneration system based on gas turbines. That study indicated that gasification had high potential as an alternative to recovery boiler technology and offered many advantages. This paper describes the design of the plant, the construction of the pilot plant, and finally presents data from operation of the plant.

Kelleher, E. G.

1987-08-01T23:59:59.000Z

58

Freeze crystallization technology for Kraft black liquor concentration. Third report  

SciTech Connect (OSTI)

About 25% of the purchased energy in the pulp and paper industry is used to concentrate black liquor. The technical feasibility of using freeze concentration to supplement evaporation has been successfully demonstrated, and results indicate that energy consumption can be reduced 45%. After compiling a considerable data base on the characteristics of black liquor at low temperature and after developing a computer program to aid analysis, the process chosen was vacuum freezing-vapor absorption (VFVA). A pilot plant was built and operated; however, due to problems with crystallization of the absorbent and contamination, it was found that maintaining the conditions necessary for a continuous process was not practical at the present state of development. Therefore, indirect freezing was used for all subsequent work. This required the design and fabrication of a simple shuttle crystallizer to replace scraped surface units conventionally used. CSI also developed an integrated ice separation column that combined crystal growth, a concentration gradient, and washing all in one unit. Finally, extensive heat transfer coefficient data were collected so that a preliminary design could be completed for a 350 TPD industrial freeze concentration unit. An economic analysis was calculated in order to compare using evaporation and freeze concentration to process the increased liquor flow from a pulp mill expansion. A 200,000 lb/hr freezing unit used to preconcentrate the mill's entire stream up to 18.7% solids would save $10 to $16 per ton of pulp.

Johnson, W.E.; Rhodes, C.R.

1985-04-01T23:59:59.000Z

59

A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report  

SciTech Connect (OSTI)

A wide variety of experimental techniques have been used in this work, and many of these have been developed completely or improved significantly in the course of the research done during this program. Therefore, it is appropriate to describe these techniques in detail as a reference for future workers so that the techniques can be used in future work with little additional effort or so that the results reported from this program can be compared better with future results from other work. In many cases, the techniques described are for specific analytical instruments. It is recognized that these may be superseded by future developments and improvements in instrumentation if a complete description of techniques used successfully in the past on other instrumentation is available. The total pulping and liquor preparation research work performed included chip and white liquor preparation, digestion, pulp washing, liquor and wash recovery, liquor sampling, weak liquor concentration in two steps to about 45--50% solids with an intermediate soap skimming at about 140F and 27--30% solids, determination of pulp yield and Kappa number, determination of total liquor solids, and a check on the total material balance for pulping. All other research was performed either on a sample of the weak black liquor (the combined black liquor and washes from the digester) or on the skimmed liquor that had been concentrated.

Fricke, A.L.; Zaman, A.A.; Stoy, M.O.; Schmidl, G.W.; Dong, D.J.; Speck, B.

1998-04-01T23:59:59.000Z

60

Ultrafiltration of Kraft Black Liquor: Phase II, Final report  

SciTech Connect (OSTI)

The major justification for examining ultrafiltration was to lower the viscosity of the Kraft Black Liquor by recovering it as an ultrafiltration permeate from which the highest MW lignin had been removed. The liquor could then be concentrated to a higher percentage solids before firing into the recovery boiler. Consequent energy savings for the 1000 ton/day pulp mill would be 2.05 x 10 Btu/y for each percentage increase in TDS (total dissolved solids) to the recovery boiler. This Phase II report gives data on viscosity with percentage solids of KBL permeates. Another favorable effect of ultrafiltration on the permeate properties is disproportionate removal of multivalent ions including the major scaling ion CaS . If this high-viscosity high-Ca retentate could be treated to lower its viscosity and to release the Ca in a non-scaling form, this would enhance the possibility that ultrafiltration might be useful in a mill situation. Included in this report are data on the results of treating the retentate fraction. Other justifications for this program included further information in KBL properties: lignin MW in the KBL at high pH; elemental and sugar analyses; and differential properties of lignins in the retentate and the permeate fractions. A preliminary economic analysis of ultrafiltration is contained in this report. These analyses indicate that with flux rates now attainable, ultrafiltration would not be economically justified at this time if the only justification is to lower KBL viscosity. For certain situations where high Ca liquors present a scaling problem, especially in an evaporator-limited mill, the economics are more favorable. There are also unsolved problems relating to the use of the high viscosity retentate.

Hill, M.K.

1987-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

DEMONSTRATION OF BLACK LIQUOR GASIFICATION AT BIG ISLAND  

SciTech Connect (OSTI)

This Technical Progress Report provides an account of the status of the project for the demonstration of Black Liquor Gasification at Georgia-Pacific Corporation's Big Island, VA facility. The report also includes budget information and a milestone schedule. The project to be conducted by G-P is a comprehensive, complete commercial-scale demonstration that is divided into two phases. Phase I is the validation of the project scope and cost estimate. Phase II is project execution, data acquisition and reporting, and consists of procurement of major equipment, construction and start-up of the new system. Phase II also includes operation of the system for a period of time to demonstrate the safe operation and full integration of the energy and chemical recovery systems in a commercial environment. The objective of Phase I is to validate the process design and to engineer viable solutions to any technology gaps. This phase includes engineering and planning for the integration of the full-scale MTCI/StoneChem PulseEnhanced{trademark} black liquor steam-reformer chemical recovery system into G-P's operating pulp and paper mill at Big Island, Virginia. During this phase, the scope and cost estimate will be finalized to confirm the cost of the project and its integration into the existing system at the mill. The objective of Phase II of the project is the successful and safe completion of the engineering, construction and functional operation of the fully integrated full-scale steam reformer process system. This phase includes installation of all associated support systems and equipment required for the enhanced recovery of both energy and chemicals from all of the black liquor generated from the pulping process at the Big Island Mill. The objective also includes operation of the steam reformer system to demonstrate the ability of the system to operate reliably and achieve designed levels of energy and chemical recovery while maintaining environmental emissions at or below the limits set by the environmental permits.

Robert DeCarrera

2003-10-20T23:59:59.000Z

62

Ultrafiltration of Kraft Black Liquor. Final report, Phase I  

SciTech Connect (OSTI)

Kraft Black Liquor (KBL) is ultrafiltered to favorably affect the properties of the KBL permeate. The major property to be changed is viscosity. If the high molecular weight lignin is removed by ultrafiltration, the KBL permeate should show a significant drop in viscosity. An objective of the work reported was to examine how much KBL viscosity is lowered relative to membrane and membrane pore size used in the ultrafiltration. Another objective was an initial evaluation of ultrafiltration equipment and membranes. Operating characteristics were determined for selected equipment and membranes. Decreases in KBL permeate viscosity were indeed seen. (LEW)

Hill, M.K.

1985-10-01T23:59:59.000Z

63

Freeze crystallization technology for black liquor concentration. Second interim report  

SciTech Connect (OSTI)

The pulp and paper industry is one of the largest consumers of energy. Concentration of black liquor (the stream resulting from the chemical separation of wood fibers in the pulping operation) uses 25% of the purchased energy to produce pulp, an equivalent of 33 million barrels of oil in 1982. Here it is shown that freeze concentration, an emerging concentration technology, has the potential of reducing the energy consumption by at least 45%. This amounts to a cost savings of $5 to $15 per ton of pulp depending on the cost of energy, geographical location, and method of application.

Not Available

1983-07-01T23:59:59.000Z

64

Vapor pressure and boiling point elevation of slash pine black liquors: Predictive models with statistical approach  

SciTech Connect (OSTI)

Vapor-liquid equilibria and boiling point elevation of slash pine kraft black liquors over a wide range of solid concentrations (up to 85% solids) has been studied. The liquors are from a statistically designed pulping experiment for pulping slash pine in a pilot scale digester with four cooking variables of effective alkali, sulfidity, cooking time, and cooking temperature. It was found that boiling point elevation of black liquors is pressure dependent, and this dependency is more significant at higher solids concentrations. The boiling point elevation data at different solids contents (at a fixed pressure) were correlated to the dissolved solids (S/(1 {minus} S)) in black liquor. Due to the solubility limit of some of the salts in black liquor, a change in the slope of the boiling point elevation as a function of the dissolved solids was observed at a concentration of around 65% solids. An empirical method was developed to describe the boiling point elevation of each liquor as a function of pressure and solids mass fraction. The boiling point elevation of slash pine black liquors was correlated quantitatively to the pulping variables, using different statistical procedures. These predictive models can be applied to determine the boiling point rise (and boiling point) of slash pine black liquors at processing conditions from the knowledge of pulping variables. The results are presented, and their utility is discussed.

Zaman, A.A.; McNally, T.W.; Fricke, A.L. [Univ. of Florida, Gainesville, FL (United States)] [Univ. of Florida, Gainesville, FL (United States)

1998-01-01T23:59:59.000Z

65

Effect of sulfidity on the corrosivity of white, green, and black liquors  

SciTech Connect (OSTI)

Corrosion testing was performed in white, green, and black liquors from a kraft mill. The liquors were modified in composition to simulate conditions of high (40%) sulfidity and low (30%) sulfidity, and then heated in laboratory autoclaves to the temperatures of the respective tanks from which the samples were taken. Specimens of carbon and stainless steels were exposed under free corrosion potential conditions, and their corrosion rates determined from weight loss measurements. In white, green, 45% solids black, and flash tank liquors, active corrosion rates for the carbon steels were typically 20 to 75% higher in the higher sulfidity liquors. In 15% solids weak black liquor there was no appreciable difference in corrosion rates, with carbon steels remaining passive in both low and high sulfidity. In 26% solids intermediate black liquor there were large increases in the corrosion rates of carbon steel between low and high sulfidity liquors, resulting from a change from passive to active conditions. Stainless steels UNS S30403, S32304, and S31803 had very low corrosion rates in all the liquors tested, regardless of sulfidity.

Wensley, A.; Champagne, P.

1999-07-01T23:59:59.000Z

66

A comprehensive program to develop correlations for the physical properties of kraft black liquors. Interim report No.3  

SciTech Connect (OSTI)

The black liquor properties program has conducted a systematic collection data of properties, liquor composition, and lignin characteristics. Complete data, except for some density data, has been collected for Slash Pine black liquors made by experimental pulping at a total of 25 different pulping conditions that cover the entire range used for commercial pulping. In addition, complete data has been collected for some mill liquors and partial properties or composition data has been collected on Slash Pine black liquors made at 16 different pulping conditions and some mill liquors. Data reduction methods have been developed or extended for correlation of viscosity, heat capacity, heat of dilution, and density. Correlation of properties to pulping conditions and of composition to pulping conditions has begun. In most cases, data reduction methods have been developed that are fundamentally based and that have been shown to be generally applicable to all black liquors. While it has not proven to be possible to include research for comprehensive correlations for properties for liquors from other species, we have shown that the behavior of liquors made from other species is similar to that which has been explored extensively for Slash Pine liquors. This report reviews the methods used, describes examples of data reduction methods that have been developed, and presents some preliminary results for correlation of liquor composition and properties to pulping conditions for Slash Pine black liquors.

Fricke, A.L.; Dong, D.J.; Schmidl, G.W.; Stoy, M.A.; Zaman, A.A.

1993-09-01T23:59:59.000Z

67

INVESTIGATION OF FUEL CHEMISTRY AND BED PERFORMANCE IN A FLUIDIZED BED BLACK LIQUOR STEAM REFORMER  

SciTech Connect (OSTI)

The University of Utah project ''Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer'' (DOE award number DE-FC26-02NT41490) was developed in response to a solicitation for projects to provide technical support for black liquor and biomass gasification. The primary focus of the project is to provide support for a DOE-sponsored demonstration of MTCI's black liquor steam reforming technology at Georgia-Pacific's paper mill in Big Island, Virginia. A more overarching goal is to improve the understanding of phenomena that take place during low temperature black liquor gasification. This is achieved through five complementary technical tasks: (1) construction of a fluidized bed black liquor gasification test system, (2) investigation of bed performance, (3) evaluation of product gas quality, (4) black liquor conversion analysis and modeling and (5) computational modeling of the Big Island gasifier. Four experimental devices have been constructed under this project. The largest facility, which is the heart of the experimental effort, is a pressurized fluidized bed gasification test system. The system is designed to be able to reproduce conditions near the black liquor injectors in the Big Island steam reformer, so the behavior of black liquor pyrolysis and char gasification can be quantified in a representative environment. The gasification test system comprises five subsystems: steam generation and superheating, black liquor feed, fluidized bed reactor, afterburner for syngas combustion and a flue gas cooler/condenser. The three-story system is located at University of Utah's Industrial Combustion and Gasification Research Facility, and all resources there are available to support the research.

Kevin Whitty

2003-12-01T23:59:59.000Z

68

Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer  

SciTech Connect (OSTI)

University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

Kevin Whitty

2007-06-30T23:59:59.000Z

69

Use of sulfide-containing liquors for removing mercury from flue gases  

DOE Patents [OSTI]

A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

Nolan, Paul S. (North Canton, OH); Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH); Vecci, Stanley J. (Alliance, OH)

2003-01-01T23:59:59.000Z

70

Method for improving separation of carbohydrates from wood pulping and wood or biomass hydrolysis liquors  

DOE Patents [OSTI]

A method for separating carbohydrates from pulping liquors includes the steps of providing a wood pulping or wood or biomass hydrolysis pulping liquor having lignin therein, and mixing the liquor with an acid or a gas which forms an acid upon contact with water to initiate precipitation of carbohydrate to begin formation of a precipitate. During precipitation, at least one long chain carboxylated carbohydrate and at least one cationic polymer, such as a polyamine or polyimine are added, wherein the precipitate aggregates into larger precipitate structures. Carbohydrate gel precipitates are then selectively removed from the larger precipitate structures. The method process yields both a carbohydrate precipitate and a high purity lignin.

Griffith, William Louis; Compere, Alicia Lucille; Leitten Jr., Carl Frederick

2010-04-20T23:59:59.000Z

71

Low temperature pyrolysis of black liquor and polymerization of products in alkali aqueous medium  

SciTech Connect (OSTI)

Atmospheric pressure pyrolysis for the production of liquids and gases from black liquor and its calcium salts and acidic precipitate have been carried out in a little stainless steel tube. Yields, sum of liquid and gas products, from black liquor and its calcium salts and acidic precipitate were 44.7%, 52.0% and 59.1% of dry basis respectively. The precipitates obtained from black liquor by acidifying with hydrochloric acid and passing carbon dioxide have been polymerized in aqueous acetone containing formaldehyde and ammonia, and converted a polymeric resin.

Demirbas, A. (Dept. of Chemical Education, Karadeniz Teknik Univ., Trabzon (TR)); Ucan, H. (Dept. of Chemistry, Selcuk Univ., Konya (TR))

1991-01-01T23:59:59.000Z

72

Energy considerations for steam plasma gasification of black liquor and chemical recovery  

SciTech Connect (OSTI)

This paper investigates the energy economics of using a hybrid steam plasma process to gasify black liquor. In the pulp and paper industry, gasification is gaining credibility as an incremental method to supplement the standard Kraft process, which bums the black liquor in large furnaces to recover energy and inorganic chemicals (sodium and sulfur) that are recycled back into the wood pulping process. This paper shows that despite the energy intensive nature of steam plasma processing, several fortuitous conditions arise that make it a viable technology for the gasification of black liquor.

Grandy, J.D.; Kong, P.C.

1995-10-01T23:59:59.000Z

73

Energy considerations for steam plasma gasification of black liquor and chemical recovery  

SciTech Connect (OSTI)

This paper investigates the energy economics of using a hybrid steam plasma process to gasify black liquor. In the pulp and paper industry, gasification is gaining credibility as an incremental method to supplement the standard Kraft process, which burns the black liquor in large furnaces to recover energy and inorganic chemicals (sodium and sulfur) that are recycled back into the wood pulping process. This paper shows that despite the energy intensive nature of steam plasma processing, several fortuitous conditions arise that make it a viable technology for the gasification of black liquor.

Grandy, J.D.; Kong, P.C. [Idaho National Engineering Lab., Idaho Falls, ID (United States)

1995-07-01T23:59:59.000Z

74

Biomass gasification project gets funding to solve black liquor safety and landfill problems  

SciTech Connect (OSTI)

This paper reports on biomass gasifications. The main by-product in pulp making is black liquor from virgin fiber; the main by-product in paper recycling is fiber residue. Although the black liquor is recycled for chemical and energy recovery, safety problems plague the boilers currently used to do this. The fiber residue is usually transported to a landfill. The system being developed by MTCI will convert black liquor and fiber residue into a combustible gas, which can then be used for a wide variety of thermal or power generation applications.

Black, N.P.

1991-02-01T23:59:59.000Z

75

Use of sulfide-containing liquors for removing mercury from flue gases  

DOE Patents [OSTI]

A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

2006-05-02T23:59:59.000Z

76

Kinetics of gasification of black liquor char by steam  

SciTech Connect (OSTI)

This paper reports on the steam gasification kinetics of kraft black liquor char that were studied in a thermogravimetric analysis reactor. The effect of steam and hydrogen concentration on gasification rate can be described by Langmuir-Hinshelwood type kinetics. An activation energy of 210 kJ/mol was obtained. Methane formation was negligible, and H{sub 2}S was the major gaseous sulfur-containing product obtained over the temperature range studied, 873-973 K. The CO{sub 2} concentration was higher than calculated for the water-shift reaction at equilibrium. A gasification mechanism is proposed whereby CO{sub 2} is one of the primary gasification products.

Li, J.; van Heiningen, A.R.P. (Dept. of Chemical Engineering, McGill Univ., Pulp and Paper Research Inst. of Canada, Montreal, Quebec (CA))

1991-07-01T23:59:59.000Z

77

Simultaneous and rapid determination of multiple component concentrations in a Kraft liquor process stream  

DOE Patents [OSTI]

The present invention is a rapid method of determining the concentration of the major components in a chemical stream. The present invention is also a simple, low cost, device of determining the in-situ concentration of the major components in a chemical stream. In particular, the present invention provides a useful method for simultaneously determining the concentrations of sodium hydroxide, sodium sulfide and sodium carbonate in aqueous kraft pulping liquors through use of an attenuated total reflectance (ATR) tunnel flow cell or optical probe capable of producing a ultraviolet absorbency spectrum over a wavelength of 190 to 300 nm. In addition, the present invention eliminates the need for manual sampling and dilution previously required to generate analyzable samples. The inventive method can be used in Kraft pulping operations to control white liquor causticizing efficiency, sulfate reduction efficiency in green liquor, oxidation efficiency for oxidized white liquor and the active and effective alkali charge to kraft pulping operations.

Li, Jian (Marietta, GA); Chai, Xin Sheng (Atlanta, GA); Zhu, Junyoung (Marietta, GA)

2008-06-24T23:59:59.000Z

78

E-Print Network 3.0 - alkaline black liquor Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by Explorit Topic List Advanced Search Sample search results for: alkaline black liquor Page: << < 1 2 3 4 5 > >> 1 Journal of Membrane Science, 33 (1987) 83-95 Elsevier Science...

79

A comprehensive program to develop correlations for the physical properties of Kraft black liquor. Interim report No. 3  

SciTech Connect (OSTI)

The black liquor properties program has been conducted over this last period so as to systematically collect data on properties, liquor composition, and lignin characteristics very carefully by methods that have developed during this program. Complete data has been collected for Slash Pine black liquors made by experimental pulping at different pulping conditions. In addition, data has been collected for mill liquors and partial properties or composition data has been collected on Slash Pine black liquors. Data reduction methods have been developed or extended for correlation of viscosity, heat capacity, heat of dilution, and density. Correlation of properties to pulping conditions and of composition to. pulping conditions has begun. In most cases, data reduction methods have been developed that are fundamentally based and that have been shown to be generally applicable to all black liquors. In the near future, we fully expect to accomplish our goal of developing generalized correlations relating physical properties of Slash Pine kraft black liquors to liquor composition. This interim report reviews the methods used, describes examples of data reduction methods that have been developed, and presents some preliminary results for correlation of liquor composition and properties to pulping conditions for Slash Pine black liquors.

Fricke, A.L.; Dong, D.J.; Schmidl, G.W.; Stoy, M.A.; Zaman, A.A.

1993-09-01T23:59:59.000Z

80

Swelling of kraft black liquor: an understanding of the associated phenomena during pyrolysis  

SciTech Connect (OSTI)

The objectives of this thesis were to quantify the swelling of black liquor during pyrolysis in a nitrogen atmosphere and to determine what factors were responsible for swelling. The first part of the investigation studied the process variables: pyrolysis temperature, solid content, heating rate and particle size. A temperature of 500/sup 0/C resulted in maximum swelling for the investigated temperature range of 300-900/sup 0/C. The swelling of black liquor occurred during the evolution of pyrolysis gases; however, there was no correlation found between the amount of pyrolysis gases evolved and the change in char volume. The initial solid content of black liquor had a small influence on the swelling of black liquor. The heating rate was found to effect the rate of swelling but not the final volume. Particle size had no effect on the swollen volume per unit particle weight. The effect of black liquor composition was studied. An interaction between sugar acids and kraft lignin was responsible for swelling. The extractives interfered with the swelling mechanism of black liquor, while inorganic salts acted as a diluent. The swelling behavior of black liquor appeared to be dictated by the surface active and viscous forces present in black liquor during pyrolysis. Surface active forces were evidenced by the formation of small bubbles (50-150 microns in diameter) which appeared necessary for highly swollen chars. Low swelling chars did not exhibit this phenomenon. Bubble formation began at 250/sup 0/C, which closely corresponded to the thermal decomposition temperature of sugar acids. The sugar acids formed bubbles when pyrolyzed but did not swell significantly during pyrolysis. Kraft lignin appeared to enhance the swelling of the sugar acids by increasing the viscosity and stabilizing the bubbles during pyrolysis.

Miller, P.T.

1986-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Fuel nitrogen release during black liquor pyrolysis; Part 1: Laboratory measurements at different conditions  

SciTech Connect (OSTI)

Fuel nitrogen release during black liquor pyrolysis is high. There is only minor release during the drying stage. Ammonia is the main fixed nitrogen species formed. The rate of fixed nitrogen release increases with increasing temperature. The level of fixed nitrogen released by birch liquor is almost twice the level for pine liquor. Assuming complete conversion to NO, fixed nitrogen yields gave NO concentrations near typically measured values for flue gases in full scale recovery boilers. The purpose of this work was to gain more detailed information about the behavior of the fuel nitrogen in black liquor combustion. The work focused on the pyrolysis or devolatilization of the combustion process. Devolatilization is the stage at which the majority (typically 50--80%) of the liquor organics release from a fuel particle or droplet as gaseous species due to the rapid destruction of the organic macromolecules in the liquor. In this paper, the authors use the terms devolatilization and pyrolysis interchangeably with no difference in their meaning.

Aho, K.; Vakkilainen, E. (A. Ahistrom Corp., Varkaus (Finland)); Hupa, M. (Abo Akademi Univ., Turku (Finland). Chemical Engineering Dept.)

1994-05-01T23:59:59.000Z

82

Effect of pulsation on black liquor gasification. Final report  

SciTech Connect (OSTI)

Pyrolysis is an endothermic process. The heat of reaction is provided either by partial combustion of the waste or by heat transfer from an external combustion process. In one proposed system black liquor is pyrolized in a fluidized bed to which heat is added through a series of pulse combustor tail pipes submerged in the bed material. This system appears promising because of the relatively high heat transfer in pulse combustors and in fluidized beds. Other advantages of pulse combustors are discussed elsewhere. The process is, however, only economically viable if a part of the pyrolysis products can be used to fire the pulse combustors. The overall goals of this study were to determine: (1) which is the limiting heat transfer rate in the process of transferring heat from the hot combustion products to the pipe, through the pipe, from the tail pipe to the bed and through the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the heat transfer benefits of the pulse combustor can be utilized while maintaining the temperature in the bed within the narrow temperature range required by the process without generating hot spots in the bed; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.

Zinn, B.T.; Jagoda, J.; Jeong, H.; Kushari, A.; Rosen, L.J.

1998-12-01T23:59:59.000Z

83

Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery  

SciTech Connect (OSTI)

MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and agglomeration problems of the conversion of Na{sub 2}CO{sub 3} to (high sodium) titanates during gasification of black liquor in the presence of (low sodium) titanates or TiO{sub 2} (Task 2). MTCI/ThermoChem tested the performance and operability of the combined technology of steam reforming and direct causticization in their Process Development Unit (PDU) (Task 3). The specific objectives were: (1) to investigate how split sulfidity and polysulfide (+ AQ) pulping can be used to increase pulp fiber yield and properties compared to conventional kraft pulping; (2) to determine the economics of black liquor gasification combined with these pulping technologies in comparison with conventional kraft pulping and black liquor recovery; (3) to determine the effect of operating conditions on the kinetics of the titanate-based direct causticization reaction during black liquor gasification at relatively low temperatures ({le} 750 C); (4) to determine the mechanism of particle agglomeration during gasification of black liquor in the presence of titanates at relatively low temperatures ({le} 750 C); and (5) to verify performance and operability of the combined technology of steam reforming and direct causticization of black liquor in a pilot scale fluidized bed test facility.

Adriaan van Heiningen

2007-06-30T23:59:59.000Z

84

Research on droplet formation for application to kraft black liquors: Final report: Tasks I and III, report No. 4  

SciTech Connect (OSTI)

The overall objective of this project is to generate technical data with which to design nozzles for kraft black liquor recovery boilers which can reduce under and over size droplets and adjust for changing black liquor properties and production requirements. The research is organized into five tasks: Droplet formation from a single jet, theoretical and experimental--ambient gas medium; Surface tensions of black liquor; Aerodynamic/hydrodynamic stability/instability of droplets once formed; Black liquor droplet formation from a single jet--furnace gas medium; Prototype of a new nozzle design. 88 figs.

Stockel, I.H.

1988-10-01T23:59:59.000Z

85

Physical properties of kraft black liquor: Summary report, Phases 1 and 2  

SciTech Connect (OSTI)

Since 1981, a research program has been in progress to determine the physical properties of kraft black liquors and to develop methods for reduction of data and correlation of properties with pumping conditions. The basic premise that has been used to direct the research program is that kraft black liquor behaves as a polymer solution, particularly at high solids, and that the behavior is dominated by the characteristics of the lignin present. This premise is proving to be correct, and the principles that follow from this premise are proving to be successful for data reduction and correlation. The research has been a complex program involving experimental pulping, chemical analysis, lignin separation and characterization, thermal analysis, rheological measurements, and considerable equipment and methods development. Due to the complexity of the program, the unforeseen need to expend a great deal of effort in development of experimental techniques for analysis, and the fact that our liquors proved to be unstable at high temperatures and solids, all of the original objectives could not be accomplished. However, our program has added substantially to the body of knowledge of physical properties of black liquor. Our results indicate that the goal of developing correlations for physical properties of kraft black liquor is practical and can be realized through extension of the present work.

Fricke, A.L.

1987-09-01T23:59:59.000Z

86

Improved Materials for High-Temperature Black Liquor Gasification  

SciTech Connect (OSTI)

The laboratory immersion test system built and operated at ORNL was found to successfully screen samples from numerous refractory suppliers, including both commercially available and experimental materials. This system was found to provide an accurate prediction of how these materials would perform in the actual gasifier environment. Test materials included mullites, alumino-silicate bricks, fusion-cast aluminas, alumina-based and chrome-containing mortars, phosphate-bonded mortars, coated samples provided under an MPLUS-funded project, bonded spinels, different fusion-cast magnesia-alumina spinels with magnesia content ranging from 2.5% to about 60%, high-MgO castable and brick materials, spinel castables, and alkali-aluminate materials. This testing identified several candidate material systems that perform well in the New Bern gasifier. Fusion-cast aluminas were found to survive for nearly one year, and magnesia-alumina spinels have operated successfully for 18 months and are expected to survive for two years. Alkali-aluminates and high-MgO-content materials have also been identified for backup lining applications. No other material with a similar structure and chemical composition to that of the fusion-cast magnesium-aluminum spinel brick currently being used for the hot-face lining is commercially available. Other materials used for this application have been found to have inferior service lives, as previously discussed. Further, over 100 laboratory immersion tests have been performed on other materials (both commercial and experimental), but none to date has performed as well as the material currently being used for the hot-face lining. Operating experience accumulated with the high-temperature gasifier at New Bern, North Carolina, has confirmed that the molten alkali salts degrade many types of refractories. Fusion-cast alumina materials were shown to provide a great improvement in lifetime over materials used previously. Further improvement was realized with fusion-cast magnesia-alumina spinel refractory, which appears to be the most resistant to degradation found to date, exhibiting over a year of service life and expected to be capable of over two years of service life. Regarding the use of refractory mortar, it was found that expansion of the current chrome-alumina mortar when subjected to black liquor smelt is likely contributing to the strains seen on the vessel shell. Additionally, the candidate high-alumina mortar that was originally proposed as a replacement for the current chrome-alumina mortar also showed a large amount of expansion when subjected to molten smelt. A UMR experimental mortar, composed of a phosphate bonded system specifically designed for use with fusion-cast magnesium-aluminum spinel, was found to perform well in the molten smelt environment. Strain gauges installed on the gasifier vessel shell provided valuable information about the expansion of the refractory, and a new set of strain gauges and thermocouples has been installed in order to monitor the loading caused by the currently installed spinel refractory. These results provide information for a direct comparison of the expansion of the two refractories. Measurements to date suggest that the fusion-cast magnesia-alumina spinel is expanding less than the fusion-cast {alpha}/{beta}-alumina used previously. A modified liquor nozzle was designed and constructed to test a number of materials that should be more resistant to erosion and corrosion than the material currently used. Inserts made of three erosion-resistant metallic materials were fabricated, along with inserts made of three ceramic materials. The assembled system was sent to the New Bern mill for installation in the gasifer in 2005. Following operation of the gasifier using the modified nozzle, inserts should be removed and analyzed for wear by erosion/corrosion. Although no materials have been directly identified for sensor/thermocouple protection tubes, several of the refractory material systems identified for lining material applications may be applicable for use in this

Keiser, J.R.; Hemrick, J.G.; Gorog, J.P.; Leary, R.

2006-06-29T23:59:59.000Z

87

Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment  

SciTech Connect (OSTI)

The University of Utah's project 'Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment' (U.S. DOE Cooperative Agreement DE-FC26-04NT42261) was a response to U.S. DOE/NETL solicitation DE-PS36-04GO94002, 'Biomass Research and Development Initiative' Topical Area 4-Kraft Black Liquor Gasification. The project began September 30, 2004. The objective of the project was to improve the understanding of black liquor conversion in high pressure, high temperature reactors that gasify liquor through partial oxidation with either air or oxygen. The physical and chemical characteristics of both the gas and condensed phase were to be studied over the entire range of liquor conversion, and the rates and mechanisms of processes responsible for converting the liquor to its final smelt and syngas products were to be investigated. This would be accomplished by combining fundamental, lab-scale experiments with measurements taken using a new semi-pilot scale pressurized entrained-flow gasifier. As a result of insufficient availability of funds and changes in priority within the Office of Biomass Programs of the U.S. Department of Energy, the research program was terminated in its second year. In total, only half of the budgeted funding was made available for the program, and most of this was used during the first year for construction of the experimental systems to be used in the program. This had a severe impact on the program. As a consequence, most of the planned research was unable to be performed. Only studies that relied on computational modeling or existing experimental facilities started early enough to deliver useful results by the time to program was terminated Over the course of the program, small scale (approx. 1 ton/day) entrained-flow gasifier was designed and installed at the University of Utah's off-campus Industrial Combustion and Gasification Research Facility. The system is designed to operate at pressures as high as 32 atmospheres, and at temperatures as high as 1500 C (2730 F). Total black liquor processing capacity under pressurized, oxygen-blown conditions should be in excess of 1 ton black liquor solids per day. Many sampling ports along the conversion section of the system will allow detailed analysis of the environment in the gasifier under industrially representative conditions. Construction was mostly completed before the program was terminated, but resources were insufficient to operate the system. A system for characterizing black liquor sprays in hot environments was designed and constructed. Silhouettes of black liquor sprays formed by injection of black liquor through a twin fluid (liquor and atomizing air) nozzle were videoed with a high-speed camera, and the resulting images were analyzed to identify overall characteristics of the spray and droplet formation mechanisms. The efficiency of liquor atomization was better when the liquor was injected through the center channel of the nozzle, with atomizing air being introduced in the annulus around the center channel, than when the liquor and air feed channels were reversed. Atomizing efficiency and spray angle increased with atomizing air pressure up to a point, beyond which additional atomizing air pressure had little effect. Analysis of the spray patterns indicates that two classifications of droplets are present, a finely dispersed 'mist' of very small droplets and much larger ligaments of liquor that form at the injector tip and form one or more relatively large droplets. This ligament and subsequent large droplet formation suggests that it will be challenging to obtain a narrow distribution of droplet sizes when using an injector of this design. A model for simulating liquor spray and droplet formation was developed by Simulent, Inc. of Toronto. The model was able to predict performance when spraying water that closely matched the vendor specifications. Simulation of liquor spray indicates that droplets on the order 200-300 microns can be expected, and that higher liquor flow will result in be

Kevin Whitty

2008-06-30T23:59:59.000Z

88

Formation of fuel NO[sub x] during black-liquor combustion  

SciTech Connect (OSTI)

Fuel NOx and thermal NOx were measured in combustion gases from black liquors in two laboratory furnaces. Combustion at 950 C in air (8% O[sub 2]) produced NOx concentrations of 40-80ppm. Combustion at 950 C in synthetic air containing no nitrogen (21% 0[sub 2] in Ar) produced the same result, demonstrating that all of the NOx produced during combustion at 950 C was fuel NOx. Formation of fuel NOx increased moderately with increasing temperature in the range of 800-1,000 C, but temperature sensitivity of fuel NOx was much less than that of thermal NOx. The results imply that the major source of NOx in recovery furnace emissions is the fuel NOx in recovery furnace formed by conversion of liquor-bound nitrogen during combustion. This is consistent with thermal NOx theory, which postulates that black-liquor combustion temperatures are too low to generate significant amounts of thermal NOx.

Nichols, K.M. (Weyerhaeuser Paper Co., Tacoma, WA (United States)); Lien, S.J. (Inst. of Paper Science and Technology, Atlanta, GA (United States))

1993-03-01T23:59:59.000Z

89

Research on droplet formation for application to kraft black liquors---Final project report  

SciTech Connect (OSTI)

The objective of this project was to generate technical data to guide the design of new nozzles for kraft black liquor recovery boilers. The goal of new nozzle designs would be to narrow the droplet size distribution compared to current nozzles and to adjust for changing black liquor properties and production requirements. Uniform droplets in a recovery boiler should reduce fouling of superheater tubes and caused a more efficient burning of the black liquor, both of which result in improved energy efficiency. The research was organized into five tasks which are described in the next chapter. This fifth and final project report contains the details of Task 4 and 5 and further analysis of Task 1 results. The details of the other tasks are reported in previous technical reports. The major results from the entire project are highlighted in this section in order of significance.

Bousfield, D.W.

1990-01-01T23:59:59.000Z

90

A comprehensive program to develop correlations for the physical properties of Kraft black liquor. Interim report No. 2  

SciTech Connect (OSTI)

Experimental effort for the program to evaluate physical properties of kraft black liquors is now proceeding well. Experimental work includes pulping, liquor analysis, lignin purification and characterization, vapor-liquid equilibria, heat capacity, heats of solution and combustion, and viscosity measurements. Measurement of thermal conductivity has not yet begun. Collection of the data necessary for development of generalized correlations is proceeding, but will require about two more years. The digester is operating very well. It is now possible to operate the digester as a closed, rotating reactor or as a batch reactor with liquor circulation. When operated with liquor circulation, temperatures within the chip bed can be monitored during cooking. Cooking is reproducible, and cooks are being performed to produce liquors for experimental studies. The digester could be further modified to permit us to conduct rapid exchange batch pulping or to permit us to simulate continuous pulping. Liquors to be used in experimental studies are concentrated in our large scale evaporator or in our small scale evaporator. The large scale evaporator is used to concentrate liquors to about 50% solids for storage and for use in studies requiring high solids liquors. The small scale evaporator is used for preparing final samples to as high as 85% solids and for measuring vapor-liquid equilibria. Liquors are now routinely analyzed to determine all components, except higher molecular weight organic acids and extractives. Lignin determination by uv-visible means has been improved. Lignin purification from black liquor has been improved and lignin molecular weights are determined routinely. Work on lignin molecular weight distribution is still not satisfactory, but recent developments holds promise.

Fricke, A.L.

1990-12-01T23:59:59.000Z

91

High-solids black liquor firing in pulp and paper industry kraft recovery boilers. Quarterly report, Phase 1a: Black liquor gasifier evaluation  

SciTech Connect (OSTI)

This project phase addresses the following workscope: Conduct bench-scale tests of a low temperature, partial combustion gasifier; Prepare a gasifier pilot-plant preliminary design and cost estimate and prepare a budgetary cost estimate of the balance of the program; Outline a test program to evaluate gasification; Prepare an economic/market analysis of gasification and solicit pulp and paper industry support for subsequent phases; and Prepare a final report and conduct a project review prior to commencement of work leading to construction of any pilot scale components or facilities. The primary accomplishments included completion of installation of the bench-scale black liquor gasifier and supporting systems, preparing test plans and related safety procedures and detailed operating procedures, defining the functional design requirements and outlining the test plans for the pilot-scale gasifier, and preparing a preliminary economic assessment of the black liquor gasifier. This work accomplished under Phase 1a during this period is further described by task.

NONE

1996-07-01T23:59:59.000Z

92

Energy conservation in black-liquor evaporator of pulp and paper industry  

SciTech Connect (OSTI)

This paper is an attempt on energy conservation in a quintuple effect evaporator used to concentrate dilute black liquor solution by raising their steam economy through the changes in the operating variables. It also describes the steam economy of the evaporator for the various feed arrangements so as to determine the ranges of the variables for which evaporation occurs profitable.

Agarwal, V.K.; Gupta, S.C. [Univ. of Roorkee (India). Dept. of Chemical Engineering

1995-12-31T23:59:59.000Z

93

Assessment of the release of atomic Na from a burning black liquor droplet using quantitative PLIF  

SciTech Connect (OSTI)

The quantitative measurement of atomic sodium (Na) release, at high concentration, from a burning black liquor droplet has been demonstrated using a planar laser-induced fluorescence (PLIF) technique, corrected for fluorescence trapping. The local temperature of the particle was measured to be approximately 1700 C, at a height of 10 mm above a flat flame burner. The PLIF technique was used to assess the temporal release of atomic Na from the combustion of black liquor and compare it with the Na concentration in the remaining smelt. A first-order model was made to provide insight using a simple Plug Flow Reactor model based on the independently measured concentration of residual Na in the smelt as a function of time. This model also required the dilution ratio of the combustion products in the flat flame entrained into the plume gas from the black liquor particle to be estimated. The key findings of these studies are: (i) the peak concentration of atomic Na from the combustion of the black liquor droplets is around 1.4 ppm; (ii) very little atomic Na is present during the drying, devolatilisation or char combustion stages; and (iii) the presence of atomic Na during smelt phase dominates over that from the other combustion stages. (author)

Saw, Woei L.; Nathan, Graham J. [Centre for Energy Technology, The Environment Institute, School of Mechanical Engineering, The University of Adelaide, SA 5005 (Australia); Ashman, Peter J.; Alwahabi, Zeyad T. [Centre for Energy Technology, The Environment Institute, School of Chemical Engineering, The University of Adelaide, SA 5005 (Australia)

2009-07-15T23:59:59.000Z

94

Final technical report. In-situ FT-IR monitoring of a black liquor recovery boiler  

SciTech Connect (OSTI)

This project developed and tested advanced Fourier transform infrared (FT-IR) instruments for process monitoring of black liquor recovery boilers. The state-of-the-art FT-IR instruments successfully operated in the harsh environment of a black liquor recovery boiler and provided a wealth of real-time process information. Concentrations of multiple gas species were simultaneously monitored in-situ across the combustion flow of the boiler and extractively at the stack. Sensitivity to changes of particulate fume and carryover levels in the process flow were also demonstrated. Boiler set-up and operation is a complex balance of conditions that influence the chemical and physical processes in the combustion flow. Operating parameters include black liquor flow rate, liquor temperature, nozzle pressure, primary air, secondary air, tertiary air, boiler excess oxygen and others. The in-process information provided by the FT-IR monitors can be used as a boiler control tool since species indicative of combustion efficiency (carbon monoxide, methane) and pollutant emissions (sulfur dioxide, hydrochloric acid and fume) were monitored in real-time and observed to fluctuate as operating conditions were varied. A high priority need of the U.S. industrial boiler market is improved measurement and control technology. The sensor technology demonstrated in this project is applicable to the need of industry.

James Markham; Joseph Cosgrove; David Marran; Jorge Neira; Chad Nelson; Peter Solomon

1999-05-31T23:59:59.000Z

95

Black liquor viscosity reduction through salt additives: A novel environmentally benign processing alternative  

SciTech Connect (OSTI)

Processing black liquor at high solids would reduce SO{sub x} emissions, facilitate the use of non-chlorine bleaching techniques and enhance the energy efficiency of the pulping process. However, black liquor exhibits and exponential increase in viscosity as its solids content rises, thus hindering its processability in the composition range of interest (>70% solids). In this study, we present a new approach for controlling viscosity at high solids content by {open_quotes}salting in{close_quotes} black liquor through addition of thiocyanate salts. These salts increases the solubility of the polymer constituents in black liquor leading to a decrease in its viscosity. Several salts capable of viscosity reduction by as much as two orders of magnitude have been identified. The effects of cation size, solution pH and temperature on viscosity reduction is presented and interpreted in terms of the underlying principles of {open_quotes}salting in{close_quotes} and how it affects aqueous solution structure.

Roberts, J.E.; Khan, S.A.; Spontak, R.J. [North Carolina State Univ., Raleigh, NC (United States)

1996-10-01T23:59:59.000Z

96

Generator-Absorber heat exchange transfer apparatus and method using an intermediate liquor  

DOE Patents [OSTI]

Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use the working solution of the absorption system for the heat transfer medium where the working solution has an intermediate liquor concentration.

Phillips, Benjamin A. (Benton Harbor, MI); Zawacki, Thomas S. (St. Joseph, MI)

1996-11-05T23:59:59.000Z

97

Separation of kraft lignin from kraft black liquor: Final report, July 1984-April 1987  

SciTech Connect (OSTI)

All the objectives were accomplished: a high-quality kraft lignin containing less than 50 ppM sodium was separated into a solvent phase (freon) from as much as 1000 lb kraft black liquor. Supporting data (infrared spectra, chemical analyses, etc.) are included. (DLC)

Kurple, K.R.

1988-04-15T23:59:59.000Z

98

Coliquefaction of coal and black liquor to environmentally acceptable liquid fuels  

SciTech Connect (OSTI)

Previous work in the laboratories has demonstrated that addition to lignin to coal during liquefaction significantly increases the depolymerization of coal and enhances the quality of the liquid products. It is believed that thermolysis of the lignin results in the formation of phenoxyl and other reactive radicals at temperatures too low for significant thermolysis of the coal matrix; such radicals are effective and active intermediates that depolymerize coal by cleaving methylene bridges. It has been reported that alkali is also effective for extraction of liquids from coal. The work presented here combines these two reactive agents by utilizing the black liquor waste stream from the Kraft pulping process for coal depolymerization. That waste stream contains large amounts of lignin and sodium hydroxide, as well as other components. To permit comparative evaluations of the extent of coal depolymerization by coprocessing coal and black liquor, reference runs were performed with tetralin alone, sodium hydroxide in tetralin, and lignin in tetralin. Results indicated that the sodium hydroxide-tetralin system resulted in almost 67% conversion at 375 C, 1 hour. The black liquor system exhibited a lower conversion of 60%, indicating some inhibition of the depolymerization reactions by components in the black liquor.

Kim, J. [Korea Inst. of Energy Research, Taejon (Korea, Republic of); Lalvani, S.B.; Muchmore, C.B.; Akash, B.A. [Southern Illinois Univ., Carbondale, IL (United States)

1999-11-01T23:59:59.000Z

99

BIOMASS AND BLACK LIQUOR GASIFIER/GAS TURBINE COGENERATION AT PULP AND PAPER MILLS  

E-Print Network [OSTI]

BIOMASS AND BLACK LIQUOR GASIFIER/GAS TURBINE COGENERATION AT PULP AND PAPER MILLS ERIC D. LARSON modeling of gasifier/gas turbine pulp-mill cogeneration systemsusing gasifier designs under commercial gasification. The use of biomass fuels with gas turbines could transform a typical pulp mill from a net

100

National Dioxin Study Tier 4 - combustion sources: final test report - Site 8, Black-liquor boiler BLB-C  

SciTech Connect (OSTI)

This report summarizes the results of a dioxin/furan emissions test of a black-liquor recovery boiler equipped with a drybottom electrostatic precipitator for particulate emissions control. Black-liquor recovery boilers are used at kraft pulp mills to produce process steam and to reclaim inorganic chemicals from spent wood pulping liquors. The dioxin/furan emissions test was conducted under Tier 4 of the National Dioxin Study. The primary objective of Tier 4 is to determine if various combustion sources are sources of dioxin and/or furan emissions. If any of the combustion sources are found to emit dioxin or furan, the secondary objective of Tier 4 is to quantify these emissions. Black-liquor recovery boilers are one of 8 combustion-source categories that have been tested in the Tier 4 program. The tested black-liquor boiler, BLB-C, was selected for the test after an initial information screening and a one-day pretest survey visit. Boiler BLB-C is considered representative of black-liquor recovery boilers with dry-bottom electrostatic precipitators. The amount of chloride present in the black-liquor circuit at this site is considered intermediate to high relative to that found at other kraft pulp mills. Data presented in the report include dioxin (tetra through octa homologue +2378 TCDD) and furan (tetra through octa homologue +2378 TCDF) results for both stack samples and ash samples. In addition, process data collected during sampling are also presented.

Jamgochian, C.L.; Keller, L.E.

1987-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Novel Pulping Technology: Directed Green Liquor Utilization (D-GLU) Pulping  

SciTech Connect (OSTI)

The general objectives of this new project are the same as those described in the original proposal. Conventional kraft pulping technologies will be modified for significant improvements in pulp production, such as strength, bleachability, and yield by using green liquor, a naturally high, kraft mill-derived sulfidity source. Although split white liquor sulfidity and other high sulfidity procedures have the promise of addressing several of the latter important economic needs of pulp mills, they require considerable engineering/capital retrofits, redesigned production methods, and thus add to overall mill expenditures. Green liquor use, however, possesses the required high sulfidity to obtain in general the benefits attributable to higher sulfidity cooking, without the required capital constraints for implementation. Before introduction of green liquor in our industrial operations, a stronger understanding of its fundamental chemical interaction with the lignin and carbohydrates in US hardwood and softwoods must be obtained. In addition, its effect on bleachability, enhancement of pulp properties, and influence on the overall energy and recovery of the mill requires further exploration before the process witnesses widespread mill use in North America. Thus, proof of principle will be accomplished in this work and the consequent effect of green liquor and other high sulfide sources on the pulping and bleaching operations will be explored for US kraft mills. The first year of this project will generate the pertinent information to validate its ability for implementation in US pulping operations, whereas year two will continue this work while proceeding to analyze pulp bleachability and final pulp/paper properties and develop a general economic and feasibility analysis for its eventual implementation in North America.

Lucian A. Lucia

2005-11-15T23:59:59.000Z

102

Black liquor combustion validated recovery boiler modeling, five-year report  

SciTech Connect (OSTI)

The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1996-08-01T23:59:59.000Z

103

Combustion processes in black liquor recovery: Analysis and interpretation of combustion rate data and an engineering design model  

SciTech Connect (OSTI)

The overall objective of this project is to develop computational models for predicting the combustion times for black liquor droplets in a recovery furnace environment. These models are needed as an important component of large-scale, global recovery boiler models. The work is divided into two tasks: interpretation of experimental black liquor single droplet combustion data from two laboratories; and formulation and evaluation of computational models for the stages of combustion of black liquor droplets. This report contains the results of the project. 109 refs., 64 figs., 12 tabs.

Fredrick, W.J.

1990-03-01T23:59:59.000Z

104

Fundamental Study of Black Liquor Gasification Kinetics. Quarterly progress report for the period October 1999 to December 1999  

SciTech Connect (OSTI)

The overall objective of this research is to evaluate the kinetics of gasification of kraft black liquor under laboratory conditions simulating pressurized, oxygen-blown gasification. The significant independent variables are gasifier temperature, black liquor composition particle size, and particle residence time. The authors will quantify their impact on the concentration of major and trace gas phase species, as well as the composition of condensed phase inorganic products, including specification of the Na- and S-containing compounds and overall carbon conversion.

NONE

2000-01-31T23:59:59.000Z

105

Development of viscometers for kraft black liquor. Summary report, Phase 2 and 2A  

SciTech Connect (OSTI)

This report documents the results of the evaluation of the on-line prototype viscometers for kraft black liquors carried out at the Pilot Plant facilities of the University of Florida. The original plan called for the evaluation of five prototype on-line viscometers along with laboratory bench versions. At a later stage in the project an additional experimental prototype under development at Southwest Research Institute was added. The viscometers are evaluated for accuracy and repeatability under varying process conditions, such as black liquor species, solids content, temperature, flow rate, and contaminants, as well as for maintenance and reliability. This document reports extensive results of the evaluations and recommendations for design modifications and for the installation of the instruments in industrial pulping mills for further field evaluations in Phase 3 of the project. The report also documents relevant details of the final design of the pilot flow loop used to support the experiments.

Fricke, A.L.; Crisalle, O.D.

1996-11-01T23:59:59.000Z

106

Comparison of Refractory Performance in Black Liquor Gasifiers and a Smelt Test System  

SciTech Connect (OSTI)

Prior laboratory corrosion studies along with experience at the black liquor gasifier in New Bern, North Carolina, clearly demonstrate that serious material problems exist with the gasifier's refractory lining. Mullite-based and alumina-based refractories used at the New Bern facility suffered significant degradation even though they reportedly performed adequately in smaller scale systems. Oak Ridge National Laboratory's involvement in the failure analysis, and the initial exploration of suitable replacement materials, led to the realization that a simple and reliable, complementary method for refractory screening was needed. The development of a laboratory test system and its suitability for simulating the environment of black liquor gasifiers was undertaken. Identification and characterization of corrosion products were used to evaluate the test system as a rapid screening tool for refractory performance and as a predictor of refractory lifetime. Results from the test systems and pl ants were qualitatively similar.

Peascoe, RA

2001-09-25T23:59:59.000Z

107

Feasibility of black liquor gasification in combined cycle cogeneration. Final report, Phase I  

SciTech Connect (OSTI)

A small-scale test program of 65% solids black liquor gasification was conducted in the bench-scale molten salt gasifier. Nine tests were performed using both air and oxygen as the oxidant. The black liquor gasified readily and the product gas had a dry-basis heating value of 70 Btu/scf with air and about 250 Btu/scf with oxygen. These values were almost identical to values predicted on the basis of thermodynamic equilibrium in the gas phase, indicating that the system had achieved near-equilibrium. However, the reduction of the melt to sodium sulfide was generally low. An independent research program aimed at improving the performance of air-blown black liquor gasification was conducted. That work resulted in a modified gasifier system design which increased the off-gas heating value to 120 Btu/scf and the reduction of the melt to over 95%. This was an improvement that would potentially allow use of the scrubbed product gas as a feed to a combustion gas turbine without prior enrichment.

Kelleher, E.G.

1983-06-30T23:59:59.000Z

108

Combined biomass and black liquor gasifier/gas turbine cogeneration at pulp and paper mills  

SciTech Connect (OSTI)

Kraft pulp and paper mills generate large quantities of black liquor and byproduct biomass suitable for gasification. These fuels are used today for onsite cogeneration of heat and power in boiler/steam turbine systems. Gasification technologies under development would enable these fuels to be used in gas turbines. This paper reports results of detailed full-load performance modeling of pulp-mill cogeneration systems based on gasifier/gas turbine technologies. Pressurized, oxygen-blown black liquor gasification, the most advanced of proposed commercial black liquor gasifier designs, is considered, together with three alternative biomass gasifier designs under commercial development (high-pressure air-blown, low-pressure air-blown, and low-pressure indirectly-heated). Heavy-duty industrial gas turbines of the 70-MW{sub e} and 25-MW {sub e} class are included in the analysis. Results indicate that gasification-based cogeneration with biomass-derived fuels would transform a typical pulp mill into significant power exporter and would also offer possibilities for net reductions in emissions of carbon dioxide relative to present practice.

Larson, E.D.; Kreutz, T.G. [Princeton Univ., NJ (United States). Center for Energy and Environmental Studies; Consonni, S. [Politecnico di Milano, Milan (Italy). Dipt. di Energetica

1999-07-01T23:59:59.000Z

109

Pulsed combustion process for black liquor gasification. Second annual report, [November 1990--February 1992  

SciTech Connect (OSTI)

This second annual report summarizes the work accomplished during the period November 1990 through February 1992 for DOE Cooperative Agreement No. DE-FC05-90CE40893. The overall project objective is to field test an energy-efficient, innovative black liquor recovery system at a significant industrial scale. This is intended to demonstrate the maturity of the technology in an industrial environment and serve as an example to the industry of the safer and more energy-efficient processing technique. The project structure is comprised of three primary activities: process characterization testing, scale-up hardware development, and field testing. The objective of the process characterization testing was to resolve key technical issues regarding the black liquor recovery process that were identified during earlier laboratory verification tests. This was intended to provide a sound engineering data base for the design, construction and testing of a nominal 1.0 TPH integrated black liquor recovery gasifier. The objective of the scale-up hardware development effort was to ensure that key hardware components, in particular the pulse heater module, would perform reliably and safely in the field. Finally, the objective of the field test is to develop an industrial data base sufficient to demonstrate the capabilities and performance of the operating system with respect to thermal efficiency, product quality, fuel handling, system control, reliability and cost. These tests are to provide long-term and continuous operating data at a capacity unattainable in the bench-scale apparatus.

Not Available

1993-02-01T23:59:59.000Z

110

Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers  

SciTech Connect (OSTI)

This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

Keiser, J.R.

2001-10-22T23:59:59.000Z

111

Effect of pulsations on black liquor gasification. Progress report, July--September 1995  

SciTech Connect (OSTI)

The objective of this study is to investigate the use of pulse combustion to provide the energy required for the endothermic gasification of black liquor in a fluidized bed. In this process it is critical that the temperature remain in the small window above the gasification temperature but below the smelting temperature of the inorganic salts in the black liquor. Pulse combustors have been shown to have high heat transfer rates between the hot combustion products and the combustor tailpipe. Similarly, fluidized beds have high heat transfer rates within the bed itself, promoting temperature uniformity throughout. Typical analysis of the gasified black liquor shows there is a large percentage of combustible gases in the products of the gasification process (approximately 70%). The potential exists, therefore, for using this fuel mixture to fire the pulse combustor. This makes the entire process more efficient and may be necessary to make it economically feasible. The overall goals of this study are to determine (1) which is the limiting heat transfer rate in the process of transferring the heat from the hot combustion products to the pipe, through the pipe, from the tailpipe to the bed and then throughout the bed; i.e., whether increased heat transfer within the pulse combustor will significantly increase the overall heat transfer rate; (2) whether the temperature distribution in the bed can be maintained within the narrow temperature range required by the process without generating hot spots in the bed even if the heat transfer from the pulse combustor is significantly increased; and (3) whether the fuel gas produced during the gasification process can be used to efficiently fire the pulse combustor.

Kushari, A.; Jeong, H.; Jagoda, J.I.; Zinn, B.T.

1995-12-31T23:59:59.000Z

112

Improved Materials for Use as Components in Kraft Black Liquor Recovery Boilers  

SciTech Connect (OSTI)

This Cooperative Research and Development Agreement (CRADA) was undertaken to evaluate current and improved materials and materials processing conditions for use as components in kraft black liquor recovery boilers and other unit processes. The main areas addressed were: (1) Improved Black Liquor Nozzles, (2) Weld Overlay of Composite Floor Tubes, and (3) Materials for Lime Kilns. Iron aluminide was evaluated as an alternate material for the nozzles used to inject an aqueous solution known as black liquor into recovery boilers as well for the uncooled lining in the ports used for the nozzles. Although iron aluminide is known to have much better sulfidation resistance in gases than low alloy and stainless steels, it did not perform adequately in the environment where it came into contact with molten carbonate, sulfide and sulfate salts. Weld overlaying carbon steel tubes with a layer of stainless weld metal was a proposed method of extending the life of recovery boiler floor tubes that have experienced considerable fireside corrosion. After exposure under service conditions, sections of weld overlaid floor tubes were removed from a boiler floor and examined metallographically. Examination results indicated satisfactory performance of the tubes. Refractory-lined lime kilns are a critical component of the recovery process in kraft pulp mills, and the integrity of the lining is essential to the successful operation of the kiln. A modeling study was performed to determine the cause of, and possible solutions for, the repeated loss of the refractory lining from the cooled end of a particular kiln. The evaluation showed that the temperature, the brick shape and the coefficient of friction between the bricks were the most important parameters influencing the behavior of the refractory lining.

Keiser, J.R.

2000-04-18T23:59:59.000Z

113

Conversion of a black liquor recovery boiler to wood firing: A case history  

SciTech Connect (OSTI)

In 1983 a large integrated pulp and paper mill in southeastern United States retired an older chemical recovery boiler when it was replaced by a newer and larger unit as part of a mill expansion. At that time the mill was generating steam and power using wood waste, natural gas and black liquor, a common fuel mix for pulp mills. The retirement of the recovery boiler presented an opportunity for the mill and corporate engineering to evaluate various mixes of fuels for the mill.

Eleniewski, M.A. [Detroit Stoker Company, Monroe, MI (United States)

1994-12-31T23:59:59.000Z

114

Eucalyptus kraft black liquor enhances growth and productivity of Spirulina in outdoor cultures  

SciTech Connect (OSTI)

Mass cultivation of microalgae for commercial applications suffers from poor productivities when measured against laboratory results or theoretical projections. In an effort to reduce this gap it was discovered that addition of eucalyptus kraft black liquor (BL) enhanced biomass productivity in outdoor cultures of Spirulina by increasing growth rate by 38% and biomass yield by 43%. BL treatment resulted in elevation of nitrogen assimilating enzyme activities and efficiency of phosphate utilization. Analyses of forenoon and afternoon oxygen production rates (OPRs) indicated higher photosynthetic and respiratory activity in BL-treated cultures compared to untreated cultures. 20 refs., 1 fig., 2 tabs.

Chauhan, V.S.; Singh, G.; Ramamurthy, V. [Thapar Institute of Engineering and Technology, Patiala (India)

1995-07-01T23:59:59.000Z

115

Electronic nose with a new feature reduction method and a multi-linear classifier for Chinese liquor classification  

SciTech Connect (OSTI)

An electronic nose (e-nose) was designed to classify Chinese liquors of the same aroma style. A new method of feature reduction which combined feature selection with feature extraction was proposed. Feature selection method used 8 feature-selection algorithms based on information theory and reduced the dimension of the feature space to 41. Kernel entropy component analysis was introduced into the e-nose system as a feature extraction method and the dimension of feature space was reduced to 12. Classification of Chinese liquors was performed by using back propagation artificial neural network (BP-ANN), linear discrimination analysis (LDA), and a multi-linear classifier. The classification rate of the multi-linear classifier was 97.22%, which was higher than LDA and BP-ANN. Finally the classification of Chinese liquors according to their raw materials and geographical origins was performed using the proposed multi-linear classifier and classification rate was 98.75% and 100%, respectively.

Jing, Yaqi; Meng, Qinghao, E-mail: qh-meng@tju.edu.cn; Qi, Peifeng; Zeng, Ming; Li, Wei; Ma, Shugen [Tianjin Key Laboratory of Process Measurement and Control, Institute of Robotics and Autonomous Systems, School of Electrical Engineering and Automation, Tianjin University, Tianjin 300072 (China)] [Tianjin Key Laboratory of Process Measurement and Control, Institute of Robotics and Autonomous Systems, School of Electrical Engineering and Automation, Tianjin University, Tianjin 300072 (China)

2014-05-15T23:59:59.000Z

116

Black liquor combustion validated recovery boiler modeling: Final year report. Volume 4 (Appendix IV)  

SciTech Connect (OSTI)

This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 4 contains the following appendix sections: Radiative heat transfer properties for black liquor combustion -- Facilities and techniques and Spectral absorbance and emittance data; and Radiate heat transfer determination of the optical constants of ash samples from kraft recovery boilers -- Calculation procedure; Computation program; Density determination; Particle diameter determination; Optical constant data; and Uncertainty analysis.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

117

Material Characterization and Analysis for Selection of Refractories Used In Black Liquor Gasification  

SciTech Connect (OSTI)

Black liquor gasification provides the pulp and paper industry with a technology which could potentially replace recovery boilers with equipment that could reduce emissions and, if used in a combined cycle system, increase the power production of the mill allowing it to be a net exporter of electrical power. In addition, rather than burning the syngas produced in a gasifier, this syngas could be used to produce higher value chemicals or fuels. However, problems with structural materials, and particularly the refractory lining of the reactor vessel, have caused unplanned shutdowns and resulted in component replacement much sooner than originally planned. Through examination of exposed materials, laboratory corrosion tests and cooperative efforts with refractory manufacturers, many refractory materials issues in high-temperature black liquor gasification have been addressed and optimized materials have been selected for this application. In this paper, the characterization and analysis techniques used for refractory screening and selection will be discussed along with characteristic results from these methods which have led to the selection of optimized materials for this application.

Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta Ann [ORNL; Gorog, John Peter [ORNL

2008-01-01T23:59:59.000Z

118

Material Characterization and Analysis for Selection of Refractories Used in Black Liquor Gasification  

SciTech Connect (OSTI)

Black liquor gasification provides the pulp and paper industry with a technology which could potentially replace recovery boilers with equipment that could reduce emissions and, if used in a combined cycle system, increase the power production of the mill allowing it to be a net exporter of electrical power. In addition, rather than burning the syngas produced in a gasifier, this syngas could be used to produce higher value chemicals or fuels. However, problems with structural materials such as the refractory lining of the reactor vessel have caused unplanned shutdowns and resulted in component replacement much sooner than originally planned. Through examination of exposed materials, laboratory corrosion tests and cooperative efforts with refractory manufacturers, many refractory materials issues in high-temperature black liquor gasification have been addressed and optimized materials have been selected for this application. In this paper, an updated summary of the characterization and analysis techniques used for refractory screening and selection will be discussed along with characteristic results from these methods which have led to the selection of optimized materials for both the hot-face and back-up linings used in this application.

Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta A [University of Tennessee, Knoxville (UTK) & Oak Ridge National Laboratory (ORNL)

2010-01-01T23:59:59.000Z

119

Separation and characterization of lignins from the black liquor of oil palm trunk fiber pulping  

SciTech Connect (OSTI)

Six lignin preparations, isolated by a novel two-step precipitation method instead of the traditional one-step precipitation method from the oil palm trunk fiber pulping (OPTFP) black liquor, were found to be relatively free of nonlignin materials such as polysaccharide degradation products, ash, and salts. A lignin fraction with a purity of 99.5% was obtained at an optimum precipitation pH 1.5 after isolation of the nonlignin materials in ethanol. About 94% of the total lignin was recovered by this novel method at this condition, and the value of COD in the treated black liquor reduced significantly to lower 250. The isolated lignin fractions contained syringyl, guaiacyl, and p-hydroxyphenyl units in an approximate molar ratio of 16--20:5:1 on the basis of chemical and spectroscopic analysis. Small amounts of p-hydroxybenzoic acids were found to be esterified to lignin, while ferulic acids were associated to lignin by ether linkage. {sup 13}C-NMR indicated the presence of {beta}-O-4 ether bonds, and {beta}-5 and 5-5{prime} carbon-carbon linkages between the lignin molecules.

Sun, R.; Tomkinson, J.; Bolton, J.

1999-11-01T23:59:59.000Z

120

MOLTEN SALT CORROSION OF SUPERHEATERS IN BLACK LIQUOR RECOVERY BOILERS John Bohling, University of Tennessee Georgia Tech SURF 2010 Fellow  

E-Print Network [OSTI]

MOLTEN SALT CORROSION OF SUPERHEATERS IN BLACK LIQUOR RECOVERY BOILERS John Bohling, University If the temperature is above the first melting point of the scale, severe corrosion of the tubes can result temperatures, reducing efficiency. The corrosive nature of the superheater environment arises primarily from

Li, Mo

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Stability and Regeneration of Catalysts for the Destruction of Tars from Bio-mass Black Liquor Gasification  

SciTech Connect (OSTI)

The goal of this project was to develop catalytic materials and processes that would be effective in the destruction of tars formed during the gasification of black liquor and biomass. We report here the significant results obtained at the conclusion of this two year project.

Pradeep Agrawal

2004-09-07T23:59:59.000Z

122

PERFORMANCE OF BLACK LIQUOR GASIFIER/GAS TURBINE COMBINED CYCLE COGENERATION IN mE KRAFT PULP  

E-Print Network [OSTI]

PERFORMANCE OF BLACK LIQUOR GASIFIER/GAS TURBINE COMBINED CYCLE COGENERATION IN mE KRAFT PULP high-temperature gasifiers for gas turbine applications. ABB and MTCr/Stonechem are developing low-load performance of gasifier/gas turbine systemsincorporating the four above-noted gasifier designs are reported

123

Refractory Testing and Evaluation at Oak Ridge National Laboratory for Black Liquor Gasifier Applications.  

SciTech Connect (OSTI)

Work is on-going at Oak Ridge National Laboratory to evaluate refractory containment and smelt contact materials for black liquor gasification applications. Materials have been evaluated and selected for low temperature gasification processes, with a number of materials being installed in commercial units currently under construction. For high temperature low pressure gasification processes, efforts have focused on screening candidate lining materials through immersion testing, improving existing refractory performance through the application of surface treatments, and the installation and evaluation of samples in an operating gasifier in New Bern, NC. Efforts concerning high temperature high pressure gasification have involved the identification and testing of suitable refractory materials for the coating of a helical carbon steel cooling coil arrangment.

Hemrick, James Gordon [ORNL; Keiser, James R [ORNL; Meisner, Roberta Ann [ORNL; Hubbard, Camden R [ORNL; Lara-Curzio, Edgar [ORNL

2006-01-01T23:59:59.000Z

124

Separation of kraft lignin from kraft black liquor: Final report, July 1984-April 1987  

SciTech Connect (OSTI)

The importance of this work is related to the fact that with over 16 million tons of kraft lignin available annually, practically all of it is burned just for its heat value. In essence, kraft lignin has no real value except its heat value. The major accomplishments of this research has shown that it is possible to produce high purity kraft lignin from kraft black liquor. This patented technology represents a way of producing a material that can be utilized in a wide variety of markets. Kraft lignin that was produced using this technology was sent to major corporations who used this kraft lignin as a starting material in their chemical processes. 3 figs.

Kurple, K.R.

1988-04-15T23:59:59.000Z

125

Cracking and Corrosion of Composite Tubes in Black Liquor Recovery Boiler Primary Air Ports  

SciTech Connect (OSTI)

Black liquor recovery boilers are an essential part of kraft mills. Their design and operating procedures have changed over time with the goal of providing improved boiler performance. These performance improvements are frequently associated with an increase in heat flux and/or operating temperature with a subsequent increase in the demand on structural materials associated with operation at higher temperatures and/or in more corrosive environments. Improvements in structural materials have therefore been required. In most cases the alternate materials have provided acceptable solutions. However, in some cases the alternate materials have solved the original problem but introduced new issues. This report addresses the performance of materials in the tubes forming primary air port openings and, particularly, the problems associated with use of stainless steel clad carbon steel tubes and the solutions that have been identified.

Keiser, James R.; Singbeil, Douglas L.; Sarma, Gorti B.; Kish, Joseph R.; Yuan, Jerry; Frederick, Laurie A.; Choudhury, Kimberly A.; Gorog, J. Peter; Jett, Francois R.; Hubbard, Camden R.; Swindeman, Robert W.; Singh, Prett M.; Maziasz, Phillip J.

2006-10-01T23:59:59.000Z

126

HIGHLY ENERGY EFFICIENT D-GLU (DIRECTED-GREEN LIQ-UOR UTILIZATION) PULPING  

SciTech Connect (OSTI)

Purpose: The purpose of the project was to retrofit the front end (pulp house) of a commercial kraft pulping mill to accommodate a mill green liquor (GL) impregna-tion/soak/exposure and accrue downstream physical and chemical benefits while prin-cipally reducing the energy footprint of the mill. A major player in the mill contrib-uting to excessive energy costs is the lime kiln. The project was intended to offload the energy (oil or natural gas) demands of the kiln by by-passing the causticization/slaking site in the recovery area and directly using green liquor as a pulping medium for wood. Scope: The project was run in two distinct, yet mutually compatible, phases: Phase 1 was the pre-commercial or laboratory phase in which NC State University and the Insti-tute of Paper Science and Technology (at the Georgia Institute of Technology) ran the pulping and associated experiments, while Phase 2 was the mill scale trial. The first tri-al was run at the now defunct Evergreen Pulp Mill in Samoa, CA and lead to a partial retrofit of the mill that was not completed because it went bankrupt and the work was no longer the low-hanging fruit on the tree for the new management. The second trial was run at the MeadWestvaco Pulp Mill in Evedale, TX which for all intents and pur-poses was a success. They were able to fully retrofit the mill, ran the trial, studied the pulp properties, and gave us conclusions.

Lucia, Lucian A

2013-04-19T23:59:59.000Z

127

Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 5: Appendix V  

SciTech Connect (OSTI)

This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

128

Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 4: Appendix IV  

SciTech Connect (OSTI)

This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

129

Gasification of kraft black liquor and use of the products in combined cycle cogeneration. Final report, Phase II  

SciTech Connect (OSTI)

This Phase II study of kraft black liquor gasification and use of the product gases in combined cycle cogeneration based on combustion gas turbines was motivated by the very promising results of the Phase I feasibility study. The Phase I study indicated that the alternative technology to the Tomlinson recovery furnace had the potential of improving the energy efficiency and safety of combusting black liquor, reducing the capital and operating costs, increasing the electric power output, and providing an economical system for incremental kraft capacity additions. During Phase II, additional bench-scale experiments were run, pilot-scale experiments were conducted, equipment systems were investigated, and performance and economics were reanalyzed. All of the objectives of the Phase II project were met. Recommendations are summarized.

Kelleher, E.G.

1985-07-01T23:59:59.000Z

130

Simultaneous measurement of the surface temperature and the release of atomic sodium from a burning black liquor droplet  

SciTech Connect (OSTI)

Simultaneous measurement of the concentration of released atomic sodium, swelling, surface and internal temperature of a burning black liquor droplet under a fuel lean and rich condition has been demonstrated. Two-dimensional two-colour optical pyrometry was employed to determine the distribution of surface temperature and swelling of a burning black liquor droplet while planar laser-induced fluorescence (PLIF) was used to assess the temporal release of atomic sodium. The key findings of these studies are: (i) the concentration of atomic sodium released during the drying and devolatilisation stages was found to be correlated with the external surface area; and (ii) the insignificant presence of atomic sodium during the char consumption stage shows that sodium release is suppressed by the lower temperature and by the high CO{sub 2} content in and around the particle. (author)

Saw, Woei L.; Nathan, Graham J. [Centre for Energy Technology, The University of Adelaide, SA 5006 (Australia); School of Mechanical Engineering, The University of Adelaide (Australia); Ashman, Peter J.; Alwahabi, Zeyad T. [Centre for Energy Technology, The University of Adelaide, SA 5006 (Australia); School of Chemical Engineering, The University of Adelaide (Australia); Hupa, Mikko [Process Chemistry Centre, Aabo Akademi, Biskopsgatan 8 FI-20500 Aabo (Finland)

2010-04-15T23:59:59.000Z

131

Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed  

SciTech Connect (OSTI)

Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. syngas) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950C), but was limited to pressures below about 5 bar. It is desirable however to operate BLG at 20-30 bar for efficiency reasons related to either firing the syngas in a turbine, or catalytically forming liquid fuels. This work focused on achieving high direct causticizing yields at 20 bars pressure. The titanate direct causticizing reactions are inhibited by CO2. Previous work has shown that the partial pressure of CO2 should be kept below about 0.5 bar in order for the process to work. This translates to a total reactor pressure limit of about 5 bar for airblown BLG, and only 2 bar for O2-blown BLG. In this work a process was developed in which the CO2 partial pressure could be manipulated to a level under 0.5 bar with the total system pressure at 10 bar during O2-blown BLG. This fell short of our 20 bar goal but still represents a substantial increase in the pressure limit. A material and energy balance was performed, as well as first-pass economics based on capital and utilities costs. Compared to a reference case of using BLG with a conventional lime cycle [Larson, 2003], the IRR and NVP were estimated for further replacing the lime kiln with direct causticizing. The economics are strongly dependent on the price of lime kiln fuel. At $6/mmBTU the lime cycle is the clear choice. At $8/mmBTU the NPV is $10M with IRR of 17%. At $12/mmBTU the NPV is $45M with IRR of 36%. To further increase the total allowable pressure, the CO2 could be further decreased by further decreasing the temperature. Testing should be done at 750C. Also a small pilot should be built.

Scott Sinquefield; Xiaoyan Zeng, Alan Ball

2010-03-02T23:59:59.000Z

132

Ethanol production from spent sulfite liquor fortified by hydrolysis of pulp mill primary clarifier sludge  

SciTech Connect (OSTI)

Some low-yield sulfite pulping operations ferment spent sulfite liquor (SSL) to remove biochemical oxygen demand associated with dissolved sugars while at the same time generating ethanol as a salable product. Simultaneous saccharification and fermentation (SSF) of primary clarifier sludge in a medium of SSL was proposed as a means of reducing the amount of sludge to be disposed of while at the same time increasing ethanol productivity. In this article, the option of fortifying existing SSL fermenting processes with the sugars produced via in situ enzymatic hydrolysis of sulfite primary clarifier sludge (PCS) has been explored. In 100% SSL PCS hydrolysis rates as high as 3.4 g/(L{center_dot}h) were observed at an initial enzyme loading of 10 filter paper units (FPU)/g PCS. To reduce the deleterious effects of glucose inhibition, single-stage SSF was carried out using cellulose enzymes and Saccharomyces cerevisiae. The production rate of ethanol in SSL was increased by as much as 25% through the SSF process. 12 refs., 4 figs., 2 tabs.

Moritz, J.W.; Duff, S.J.B. [Univ. of British Columbia, Vancouver (Canada)

1996-12-31T23:59:59.000Z

133

Mechanical Design of Steel Tubing for Use in Black Liquor Recovery Boilers  

SciTech Connect (OSTI)

Finite element models were developed for thermal-mechanical analysis of black liquor recovery boiler floor tubes. Residual stresses in boiler floors due to various manufacturing processes were analyzed. The modeling results were verified by X-ray and neutron diffraction measurements at room temperature on as-manufactured tubes as well as tubes after service. The established finite element models were then used to evaluate stress conditions during boiler operation. Using these finite element models, a parametric response surface study was performed to investigate the influence of material properties of the clad layer on stresses in the floor tubes during various boiler operating conditions, which yielded a generalized solution of stresses in the composite tube floors. The results of the study are useful for identifying the mechanisms of cracking experienced by recovery boilers. Based on the results of the response surface study, a recommendation was made for more suitable materials in terms of the analyzed mechanical properties. Alternative materials and manufacturing processes are being considered to improve the resistance to cracking and the in-service life of composite tubes. To avoid numerous FE stress-strain analyses of composite tubes made of different material combinations, a response surface study was performed that considered two essential mechanical properties of the clad material - coefficient of thermal expansion and yield stress - as independent variables. The response surface study provided a generalized solution of stresses in the floor in terms of the two selected parameters.

Taljat, B.; Zacharaia, T.; Wang, X.; Kesier, J.; Swindeman, R.; Hubbard, C.

1999-05-26T23:59:59.000Z

134

Dynamic air deposited coatings for power and black liquor recovery boilers  

SciTech Connect (OSTI)

Dynamic Air Deposition (DyAir) is a novel coating method designed to protect the tubing of power and black liquor recovery boilers against corrosion attack at elevated temperatures. The method utilizes the energy of combustion of gaseous fuel and air to heat the powder material to a temperature just below its melting point and accelerate it over 600 m/s to form a coating. The Ni-Cr and Ni-Cr-Mo DyAir coatings revealed no gas permeability and extremely low oxygen content. Compared to the electric arc and HVOF-sprayed coatings, the DyAir coatings exhibited higher hardness and better crack resistance. During aging at 400 and 700 C the bond strength and crack resistance of the DyAir coatings increased dramatically due to intensive diffusion processes in absence of internal corrosion attack. The DyAir coatings revealed outstanding resistance to corrosion, such as sulfidation attack in presence of hydrochloric acid gas at 400 C, oxidation attack at 700 C and oxidation attack in presence of chlorine at 400 C.

Verstak, A.A.; Baranovski, V.E. [Advanced Surface Technologies Inc., Richmond, VA (United States)

1999-11-01T23:59:59.000Z

135

Black liquor combustion validated recovery boiler modeling: Final year report. Volume 5 (Appendix V)  

SciTech Connect (OSTI)

This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 5 contains model validation simulations and comparison with data.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

136

Gasification behavior of carbon residue in bed solids of black liquor gasifier  

SciTech Connect (OSTI)

Steam gasification of carbon residue in bed solids of a low-temperature black liquor gasifier was studied using a thermogravimetric system at 3 bar. Complete gasification of the carbon residue, which remained unreactive at 600 C, was achieved in about 10 min as the temperature increased to 800 C. The rate of gasification and its temperature dependence were evaluated from the non-isothermal experiment results. Effects of particle size and adding H{sub 2} and CO to the gasification agent were also studied. The rate of steam gasification could be taken as zero order in carbon until 80% of carbon was gasified, and for the rest of the gasification process the rate appeared to be first order in carbon. The maximum rate of carbon conversion was around 0.003/s and the activation energy was estimated to be in the range of 230-300 kJ/mol. The particle size did not show significant effect on the rate of gasification. Hydrogen and carbon monoxide appeared to retard the onset of the gasification process. (author)

Preto, Fernando; Zhang, Xiaojie (Frank); Wang, Jinsheng [CANMET Energy Technology Centre, Natural Resources (Canada)

2008-07-15T23:59:59.000Z

137

Alkali salt ash formation during black liquor combustion at kraft recovery boilers  

SciTech Connect (OSTI)

Recovery boiler is an essential part of paper pulping process, where waste sludge called black liquor is burned for chemical recovery and energy production. This study was carried out at an operating industrial recovery boiler in Finland. Measurement of aerosol particles was carried out at bullnose level of furnace, at boiler exit, and at outlet of electrostatic precipitator (ESP). Aerosol mass size distributions in size range 0.02--50 {micro}m were measured with Berner type low pressure impactor (BLPI) operated with precyclone. BLPI samples were further analyzed with ion chromatography for water soluble Na, K, SO{sub 4}, and Cl. Particle morphology was studied with scanning electron microscopy (SEM). Phase composition of crystalline salts was measured with X-ray diffraction (XRD). Particles larger than 1 {micro}m were analyzed with computer controlled scanning electron microscopy (CCSEM) to derive particle composition classes. At ESP inlet mass size distribution was bimodal with a major mode at about 1.2 {micro}m and a minor mode at about 5 {micro}m (aerodynamic diameter). At ESP outlet the mass size distribution showed only one peak at about 1.2 {micro}m. Both submicron and supermicron particles were agglomerates formed from 0.3 to 0.5 {micro}m spherical primary particles. XRD analyses indicated that particles were crystalline with two phases of Na{sub 2}SO{sub 4} (thenardite and sodium sulphate) and K{sub 3}Na(SO{sub 4}){sub 2}. CCSEM results of individual particles larger than 1 {micro}m showed that 79 to 88 volume percent of particles contained mainly Na and S, 7 to 10 volume percent Na, K, and S with minor amount of particles containing Na, S, and Ca.

Mikkanen, P. Kauppinen, E.I.; Pyykoenen, J.; Jokiniemi, J.K. [VTT (Finland); Maekinen, M. [Finnish Meterological Inst., Helsinki (Finland)

1996-12-31T23:59:59.000Z

138

Pyrometric temperature measurement method and apparatus for measuring particle temperatures in hot furnaces: Application to reacting black liquor  

SciTech Connect (OSTI)

A specialized two-color pyrometric method has been developed for the measurement of particle surface temperatures in hot, radiating environments. In this work, the method has been applied to the measurement of surface temperatures of single reacting black liquor char particles in an electrically heated muffle furnace. Black liquor was introduced into the hot furnace as wet droplets. After drying, the resulted particles were processed in different atmospheres corresponding to combustion, pyrolysis, and gasification at furnace temperatures of 700{endash}900{degree}C. The pyrometric measurement is performed using two silicon photodiode detectors and 10 nm bandpass filters centered at 650 and 1050 nm. Thermal radiation is transferred using an uncooled fiberoptic probe brought into the vicinity of the char particle. The key features of the pyrometric apparatus and analysis method are: (1) Single particle temperature is resolved temporally at high speed. (2) The thermal radiation originating from the furnace and reflected by the particle is accounted for in the measurement of the surface temperature. (3) Particle temperatures above or below the furnace temperature can be measured without the need of a cooled background assisting the measurement in the hot furnace. To accomplish this, a minimum particle size is needed that is a function of the temperature difference between the particle and furnace. Particles cooler than the furnace can be measured if their diameter is more than 0.7 mm. Surface temperatures of 300{endash}400{degree}C above the furnace temperature were measured during combustion of black liquor char particles in air. In atmospheres corresponding to gasification, endothermic reactions occurred, and char temperature remained typically 40{degree} below the furnace temperature. {copyright} {ital 1996 American Institute of Physics.}

Stenberg, J. [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland)] [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland); Frederick, W.J. [Oregon State University, Gleeson 103, Corvallis, Oregon 97331 (United States)] [Oregon State University, Gleeson 103, Corvallis, Oregon 97331 (United States); Bostroem, S. [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)] [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland); Hernberg, R. [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland)] [Tampere University of Technology, P.O. Box 692, Tampere SF-33101 (Finland); Hupa, M. [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)] [Abo Akademi University, Lemminkaeisenkatu 14-18 B, Turku SF-20520 (Finland)

1996-05-01T23:59:59.000Z

139

Causes and solutions for cracking of coextruded and weld overlay floor tubes in black liquor recovery boilers  

SciTech Connect (OSTI)

Cracking of coextruded, black liquor recovery boiler floor tubes is both a safety and an economic issue to mill operators. In an effort to determine the cause of the cracking and to identify a solution, extensive studies, described in this and three accompanying papers, are being conducted. In this paper, results of studies to characterize both the cracking and the chemical and thermal environment are reported. Based on the results described in this series of papers, a possible mechanism is presented and means to lessen the likelihood of cracking or to totally avoid cracking of floor tubes are offered.

Keiser, J.R.; Taljat, B.; Wang, X.L. [and others

1998-09-01T23:59:59.000Z

140

Electrolysis of weak black liquor: Part II. Effect of process parameters on the energy efficiency of the electrolytic cell  

SciTech Connect (OSTI)

A laboratory study of the effect of eight process parameters on the performance of the electrolytic cell when electrolyzing weak black liquor (WBL) showed that current density and temperature are critical to the operation. These two variables showed an interaction effect upon the operation of the cell. The addition of sodium sulfate to the WBL was beneficial to the energy efficiency. No chlorine gas was produced when electrolyzing WBL containing sodium chloride within the pH range of 5.4 to 13.

Cloutier, J.N.; Azarniouch, M.K.; Callender, D.

1994-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Study of soluble scale fouling control in high solids black liquor concentrators. Progress report, quarter 5 (October 1, 1999 - December 31, 1999)  

SciTech Connect (OSTI)

During this quarter, work has finally resumed on the black liquor solubility experiments, but no new data have been generated. The crystallization experiments with inorganic model solutions have been completed, and crystallization experiments with kraft black liquor have been started. The Annular Test Cell apparatus is now fully operational, while construction of the falling film evaporator pilot plant is nearly complete. Startup of this unit is planned for late in Quarter 6. In the CFD model development work, the relaxation of simplifying assumptions in the falling film model have been completed, and expressions were developed to estimate film velocity/film Reynolds number relations. Also, thin film data taken for a range of conventional fluids were compared to predictions using selected methods, and attempts were initiated to extrapolate to approximate black liquor evaporator conditions.

W.J. Frederick; F. Chen; G. Hsieh; S. Lien; R.W. Murphy; R.W. Rousseau; W. Schmidl

2000-01-01T23:59:59.000Z

142

Controlling emissions from a black liquor fluidized bed evaporator (Copeland reactor) using a regenerative thermal oxidizer and a prefilter  

SciTech Connect (OSTI)

This paper reports on an intriguing pilot project developed to control air emissions from a pulp mill. Testing is complete, and the results show favorable emissions reductions. Stone Container Corporation, REECO, NCASI, the Ohio DEP, and the US EPA, have all worked together and approved the installation of control equipment, for VOC and HAP emissions under Presumptive MACT, setting the standard for the Copeland Reactor process in a semi chem pulp mill. The equipment, once operational, will reduce VOC and CO emissions by greater than 90%. This installation will be done at one seventh the cost of the significant process modifications required to accomplish the same emission reduction. In addition, increased process operating efficiency will be achieved with the use of an energy recovery system. The process is a black liquor fluidized bed boiler, which is used to generate sodium carbonate from the black liquor. The vapor emissions were high in VOCs, CO and particulate. After much study and testing, a wet electrostatic precipitator was chosen as the filter system for particulate control, followed by a regenerative thermal oxidizer for VOC and HAP control, finally an air-to-air heat exchanger is being used to preheat the combustion air entering the process.

Grzanka, R.

1997-12-31T23:59:59.000Z

143

Black liquor combustion validated recovery boiler modeling: Final year report. Volume 2 (Appendices I, section 5 and II, section 1)  

SciTech Connect (OSTI)

This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 2 contains the last section of Appendix I, Radiative heat transfer in kraft recovery boilers, and the first section of Appendix II, The effect of temperature and residence time on the distribution of carbon, sulfur, and nitrogen between gaseous and condensed phase products from low temperature pyrolysis of kraft black liquor.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

144

Fundamental study of black liquor gasification kinetics using a pressurized entrained-flow reactor (PEFR). Quarterly progress report for the period July 1999 to September 1999  

SciTech Connect (OSTI)

The goal of the program is to identify the optimal operating window for black liquor gasification. The goals during this year are to prepare the PEFR for operation, conduct a series of preliminary screening tests to bracket BLG operating conditions, and develop a process model that can guide identification of the optimal operating window.

NONE

1999-10-29T23:59:59.000Z

145

High-solids black liquor firing in pulp and paper industry Kraft recovery boilers. Final report, Phase 1, Volume 1: Executive summary  

SciTech Connect (OSTI)

This project is a multiple-phase effort to develop technologies to improve high-solids black liquor firing in pulp mill recovery boilers. The objectives are to develop a preliminary design of a recovery furnace simulator; evaluate the economics of high-solids; and delineate a project concept for evaluating candidate technologies to improve chemical recovery.

Southards, W.T.; Clement, J.L.; McIlroy, R.A.; Tharp, M.R.; Verrill, C.L.; Wessell, R.A.

1995-11-01T23:59:59.000Z

146

Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 3: Appendix II, Sections 2 & 3 and Appendix III  

SciTech Connect (OSTI)

This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

1998-08-01T23:59:59.000Z

147

Detection of estrogen- and dioxin-like activity in pulp and paper mill black liquor and effluent using in vitro bioassays  

SciTech Connect (OSTI)

Pulp and paper mill effluent contains a complex mixture of compounds which adversely affect fish physiologically and at the population level. These effects include compromised reproductive fitness and the induction of mixed-function oxidase activities; two classic responses mediated by the estrogen and/or Ah receptor. In vitro recombinant receptor/reporter gene assays were used to examine pulp and paper mill black liquor and effluent for estrogenic, dioxin-like and antiestrogenic activities. Using MCF7 cells transiently transfected with a Gal4-estrogen receptor chimeric construct (Gal4-HEGO) and a Gal4-regulated luciferase reporter gene (17m5-G-Luc), it was estimated that black liquor contains 4 {+-} 2 ppb ``estrogen equivalents``, while negligible estrogenic activity was observed in a methanol-extracted pulp and paper mill effluent fraction (MF). A dioxin response element (DRE)-regulated luciferase reporter gene (pGudLucl.1) transiently transfected into Hepalclc7 wild type cells exhibited a dose-dependent increase in luciferase activity following treatment with 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDO), black liquor and MF. Based on the dose response curves, black liquor and MF contain 10 {+-} 4 ppb and 20 {+-} 6 ppt ``TCDD equivalents``, respectively. Moreover, MF exhibited significant AhR-mediated antiestrogenic activity. These results demonstrate the utility of these bioassays and suggest that the effects observed in fish exposed to pulp and paper mill effluent may be due to unidentified ER and AhR ligands not detected by conventional chemical analysis due to the lack of appropriate chemical standards.

Zacharewski, T.; Berhane, K.; Gillesby, B.; Burnison, K. [Univ. of Western Ontario, London, Ontario (Canada). Dept. of Pharmacology and Toxicology; [National Water Research Inst., Burlington, Ontario (Canada). Aquatic Ecosystem Conservation Branch

1995-12-31T23:59:59.000Z

148

Development of an alternative kraft black liquor recovery process based on low-temperature processing in fluidized beds. Final technical report on Annex 9, Task 1  

SciTech Connect (OSTI)

The overall objective of this research program was to provide the fundamental knowledge and experimental data from pilot scale operation for an alternative black liquor recovery technology which would have a higher overall energy efficiency, would not suffer from the smelt-water explosion hazard and would be lower in capital cost. In addition, the alternative process would be more flexible and well suited for incremental recovery capacity or for new pulping processes, such as the new sulfide-sulfide-AQ process. The research program consists of number of specific research objectives with the aim to achieve the ultimate objective of developing an alternative recovery process which is shown in Figure 1. The specific objectives are linked to individual unit operations and they represent the following research topics: (1) superheated steam drying of kraft black liquors; (2) fast pyrolysis of black liquor; (3) hydrogen sulfide absorption from flue gas; (4) reduction of sodium sulfate in solid phase with gaseous hydrogen; and (5) verification of the fundamental results in fluidized bed pilot plant. The accomplishments in each of these objectives are described.

Kubes, G.J.

1994-03-24T23:59:59.000Z

149

Black liquor combustion validated recovery boiler modeling: Final year report. Volume 1 (Main text and Appendix I, sections 1--4)  

SciTech Connect (OSTI)

This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 1 contains the main body of the report and the first 4 sections of Appendix 1: Modeling of black liquor recovery boilers -- summary report; Flow and heat transfer modeling in the upper furnace of a kraft recovery boiler; Numerical simulation of black liquor combustion; and Investigation of turbulence models and prediction of swirling flows for kraft recovery furnaces.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

150

Black liquor combustion validated recovery boiler modeling: Final year report. Volume 3 (Appendices II, sections 2--3 and III)  

SciTech Connect (OSTI)

This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 3 contains the following appendix sections: Formation and destruction of nitrogen oxides in recovery boilers; Sintering and densification of recovery boiler deposits laboratory data and a rate model; and Experimental data on rates of particulate formation during char bed burning.

Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

1998-08-01T23:59:59.000Z

151

Materials for the pulp and paper industry. Section 1: Development of materials for black liquor recovery boilers  

SciTech Connect (OSTI)

Black liquor recovery boilers are essential components of kraft pulp and paper mills because they are a critical element of the system used to recover the pulping chemicals required in the kraft pulping process. In addition, the steam produced in these boilers is used to generate a significant portion of the electrical power used in the mill. Recovery boilers require the largest capital investment of any individual component of a paper mill, and these boilers are a major source of material problems in a mill. The walls and floors of these boilers are constructed of tube panels that circulate high pressure water. Molten salts (smelt) accumulate on the floor of recovery boilers, and leakage of water into the boiler can result in a violent explosion when the leaked water instantly vaporizes upon contacting the molten smelt. Because corrosion of the conventionally-used carbon steel tubing was found to be excessive in the lower section of recovery boilers, use of stainless steel/carbon steel co-extruded tubing was adopted for boiler walls to lessen corrosion and reduce the likelihood of smelt/water explosions. Eventually, this co-extruded or composite (as it is known in the industry) tubing was selected for use as a portion or all of the floor of recovery boilers, particularly those operating at pressures > 6.2 MPa (900 psi), because of the corrosion problems encountered in carbon steel floor tubes. Since neither the cause of the cracking nor an effective solution has been identified, this program was established to develop a thorough understanding of the degradation that occurs in the composite tubing used for walls and floors. This is being accomplished through a program that includes collection and review of technical reports, examination of unexposed and cracked tubes from boiler floors, computer modeling to predict residual stresses under operating conditions, and operation of laboratory tests to study corrosion, stress corrosion cracking, and thermal fatigue.

Keiser, J.R.; Hubbard, C.R.; Payzant, E.A. [Oak Ridge National Lab., TN (United States)] [and others

1997-04-01T23:59:59.000Z

152

Engineering Study for a Full Scale Demonstration of Steam Reforming Black Liquor Gasification at Georgia-Pacific's Mill in Big Island, Virginia  

SciTech Connect (OSTI)

Georgia-Pacific Corporation performed an engineering study to determine the feasibility of installing a full-scale demonstration project of steam reforming black liquor chemical recovery at Georgia-Pacific's mill in Big Island, Virginia. The technology considered was the Pulse Enhanced Steam Reforming technology that was developed and patented by Manufacturing and Technology Conversion, International (MTCI) and is currently licensed to StoneChem, Inc., for use in North America. Pilot studies of steam reforming have been carried out on a 25-ton per day reformer at Inland Container's Ontario, California mill and on a 50-ton per day unit at Weyerhaeuser's New Bern, North Carolina mill.

Robert De Carrera; Mike Ohl

2002-03-19T23:59:59.000Z

153

High-solids black liquor firing in pulp and paper industry kraft recovery boilers: Phase 1 -- Final report. Volume 2: Project technical results  

SciTech Connect (OSTI)

This project is a multiple-phase effort to develop technologies to improve high-solids black liquor firing in pulp mill recovery boilers. The principal means to this end is to construct and operate a pilot-scale recovery furnace simulator (RFS) in which these technologies can be tested. The Phase 1 objectives are to prepare a preliminary design for the RFS, delineate a project concept for evaluating candidate technologies, establish industrial partners, and report the results. Phase 1 addressed the objectives with seven tasks: Develop a preliminary design of the RFS; estimate the detailed design and construction costs of the RFS and the balance of the project; identify interested parties in the paper industry and key suppliers; plan the Phase 2 and Phase 3 tests to characterize the RFS; evaluate the economic justification for high-solids firing deployment in the industry; evaluate high-solids black liquor property data to support the RFS design; manage the project and reporting results, which included planning the future program direction.

Southards, W.T.; Clement, J.L.; McIlroy, R.A.; Tharp, M.R.; Verrill, C.L.; Wessell, R.A.

1995-11-01T23:59:59.000Z

154

Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Black Liquor Gasification  

SciTech Connect (OSTI)

As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for removal of acid gases from black liquor-derived syngas for use in both power and liquid fuels synthesis. Two 3,200 metric tonne per day gasification schemes, both low-temperature/low-pressure (1100 deg F, 40 psi) and high-temperature/high-pressure (1800 deg F, 500 psi) were used for syngas production. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory and Princeton University. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

Nexant Inc.

2006-05-01T23:59:59.000Z

155

Corn steep liquor and fermented ammoniated condensed whey as protein sources for lactating cows and yearling heifers grazing winter native range  

SciTech Connect (OSTI)

Corn steep liquor (CSL) and fermented ammoniated condensed whey (FACW) were compared to cottonseed meal (CSM) as protein sources for wintering 61 lactating first-calf Hereford heifers and 32 yearling Hereford heifers on native range. Cattle were allotted by weight and individually fed 6 days per week for 12 weeks one of four protein treatments: negative control (NC), positive control (PC), CSL and FACW to provide .7, 1.5, .15 and 1.5 lb crude protein (CP) per day, respectively, to the lacating heifers and .2, .4, .4 and .4lb cP per day, respectively, to the yearling heifers. CMS was supplied in the CSL and FACW treatments at the same level as in the negative control. Lactating heifers fed the NC lost more (P less than .005) weight and body condition (120 lb and 1.6 units) than those fed the PC (45.8 lb and .9 units). Weight and condition losses were similar (P more than .05) for lactating heifers fed PC, CSL and FACW. Yearling heifers fed the NC lost more (P less than .005) weight than those fed the PC (49.4 vs 10.6 lb). Yearling heifers fed CSL and FACW gained more (P less than .005) weight than those fed the PC (17.6 and 9.3 vs - 10.6 lb). Feeding CSL resulted in signficantly lower rumen pH, lower ruminal acetate and higher ruminal butyrate, isovalerate and caproate levels than did feeding either control. Supplementing with FACW produced significantly lower rumen pH, higher rumen ammonia and soluble carbohydrate levels, lower ruminal acetate, and higher ruminal propionate and butyrate concentrations than did either control supplement. Corn steep liquor and FDCW appear to be effective protein sources for cows and heifers grazing winter native range.

Wagner, J.J.; Lusby, K.S.; Horn, G.W.; Dvorak, M.J.

1982-06-01T23:59:59.000Z

156

Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 2: Appendix I, Section 5, and Appendix II, Section 1  

SciTech Connect (OSTI)

This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler; and (4) Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

1998-08-01T23:59:59.000Z

157

Black Liquor Combustion Validated Recovery Boiler Modeling, Final Year Report, Volume 1: Main Text and Appendix I, Sections 1-4  

SciTech Connect (OSTI)

This project was initiated in October 1990 with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. Many of these objectives were accomplished at the end of the first five years and documented in a comprehensive report on that work (DOE/CE/40936-T3, 1996). A critical review of recovery boiler modeling, carried out in 1995, concluded that further enhancements of the model were needed to make reliable predictions of key output variables. In addition, there was a need for sufficient understanding of fouling and plugging processes to allow model outputs to be interpreted in terms of the effect on plugging and fouling. As a result, the project was restructured and reinitiated at the end of October 1995, and was completed in June 1997. The entire project is now complete and this report summarizes all of the work done on the project since it was restructured. The key tasks to be accomplished under the restructured project were to (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes; (2) Validate the enhanced furnace models, so that users can have confidence in the results; (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. Facilitate the transfer of codes, black liquor submodels, and fundamental knowledge to the U.S. kraft pulp industry.

T.M. Grace, W.J. Frederick, M. Salcudean, R.A. Wessel

1998-08-01T23:59:59.000Z

158

Integration of the Mini-Sulfide Sulfite Anthraquinone (MSS-AQ) Pulping Process and Black Liquor Gasification in a Pulp Mill  

SciTech Connect (OSTI)

As many of the recovery boilers and other pieces of large capital equipment of U.S. pulp mills are nearing the end of their useful life, the pulp and paper industry will soon need to make long-term investments in new technologies. The ability to install integrated, complete systems that are highly efficient will impact the industrys energy use for decades to come. Developing a process for these new systems is key to the adoption of state-of-the-art technologies in the Forest Products industry. This project defined an integrated process model that combines mini-sulfide sulfite anthraquinone (MSS-AQ) pulping and black liquor gasification with a proprietary desulfurization process developed by the Research Triangle Institute. Black liquor gasification is an emerging technology that enables the use of MSS-AQ pulping, which results in higher yield, lower bleaching cost, lower sulfur emissions, and the elimination of causticization requirements. The recently developed gas cleanup/absorber technology can clean the product gas to a state suitable for use in a gas turbine and also regenerate the pulping chemicals needed to for the MSS-AQ pulping process. The combination of three advanced technologies into an integrated design will enable the pulping industry to achieve a new level of efficiency, environmental performance, and cost savings. Because the three technologies are complimentary, their adoption as a streamlined package will ensure their ability to deliver maximum energy and cost savings benefits. The process models developed by this project will enable the successful integration of new technologies into the next generation of chemical pulping mills. When compared to the Kraft reference pulp, the MSS-AQ procedures produced pulps with a 10-15 % yield benefit and the ISO brightness was 1.5-2 times greater. The pulp refined little easier and had a slightly lower apparent sheet density (In both the cases). At similar levels of tear index the MSS-AQ pulps also produced a comparable tensile and burst index pulps. Product gas composition determined using computer simulations The results demonstrate that RVS-1 can effectively remove > 99.8% of the H2S present in simulated synthesis gas generated from the gasification of black liquor. This level of sulfur removal was consistent over simulated synthesis gas mixtures that contained from 6 to 9.5 vol % H2S.A significant amount of the sulfur in the simulated syngas was recovered as SO2 during regeneration. The average recovery of sulfur as SO2 was about 75%. Because these are first cycle results, this sulfur recovery is expected to improve. Developed WINGems model of the process.The total decrease in variable operating costs for the BLG process compared to the HERB was in excess of $6,200,000 per year for a mill producing 350,000 tons of pulp per year. This represents a decrease in operating cost of about $17.7/ton of oven dry pulp produced. There will be additional savings in labor and maintenance cost that has not been taken into account. The capital cost for the MSSAQ based gasifier system was estimated at $164,000,000, which is comparable to a High Efficiency Recovery Boiler. The return on investment was estimated at 4%. A gasifier replacement cannot be justified on its own, however if the recovery boiler needs to be replaced the MSSAQ gasifier system shows significantly higher savings. Before black liquor based gasifer technology can be commercialized more work is necessary. The recovery of the absorbed sulfur in the absorbent as sulfur dioxide is only 75%. This needs to be greater than 90% for economical operation. It has been suggested that as the number of cycles is increased the sulfur dioxide recovery might improve. Further research is necessary. Even though a significant amount of work has been done on a pilot scale gasifiers using liquors containing sulfur, both at low and high temperatures the lack of a commercial unit is an impediment to the implementation of the MSSAQ technology. The implementation of a commercial unit needs to be facilated before the benefits of

Hasan Jameel, North Carolina State University; Adrianna Kirkman, North Carolina State University; Ravi Chandran,Thermochem Recovery International Brian Turk Research Triangle Institute; Brian Green, Research Triangle Institute

2010-01-27T23:59:59.000Z

159

High-solids black liquor firing in pulp and paper industry kraft recovery boilers: Phase Ia - Low-temperature gasifier evaluation. Final report, November 1, 1995--October 31, 1996  

SciTech Connect (OSTI)

This project, conducted under The United States Department of Energy (DOE) Cooperative Agreement DE-FC36-94GO10002/A002, was part of a multiple-phase effort to develop technologies that improve the energy efficiency and economics of chemical process recovery in the pulp and paper industry. The approach taken was to consider two major alternatives in two phases. Phase I, conducted previously, considered means to improve pulp mill recovery boilers using high-solids advanced combustion of black liquor; while this project, Phase la, considered means to recover kraft pulping mill process chemicals by low-temperature black liquor gasification. The principal steps previously proposed in this program were: (1) Evaluate these two technologies, high-solids advanced combustion and gasification, and then select a path forward using the more promising of these two options for future work. (2) Design and construct a pilot-scale unit based on the selected technology, and using that unit, develop the precompetitive data necessary to make commercialization attractive. (3) Develop and deploy a first-of-a-kind (FOAK) commercial unit in a kraft pulp mill. Phase I, which evaluated the high-solids advanced combustion option, was concluded in 1995. Results of that project phase were reported previously. This report describes the work conducted in Phase Ia. The work is described in Sections 1 through 4 and six appendices provide additional detail.

Southards, W.T.; Blude, J.D.; Dickinson, J.A. [and others

1997-06-01T23:59:59.000Z

160

Viscosity of black liquor project  

SciTech Connect (OSTI)

The discussion of magnetic resonance in this report is confined to nuclides with a spin quantum number of 1/2. Included is a basic discussion of magnetic resonance; magnetic resonance relaxation and viscosity; and rhometers and viscometers. Many other effects are ignored for the sake of clarity.

Barrall, G.A.

1998-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Big Island Demonstration Project Black Liquor  

Broader source: Energy.gov [DOE]

This fact sheet summarizes a U.S. Department of Energy Biomass Program research and development project.

162

Black Liquor Gasification Process Review and Status Update  

E-Print Network [OSTI]

facilities (0.2 tph) focused on developing pressurized gasifiers. Their work is complemented by research at VIT (The Technical Research Centre of Finland) who have a 0.2 tph pressurized fluid bed test facility. The purpose of this paper is to describe...

Brown, C.

163

Oxidation of sewage supernatant liquor by trickling filtration  

E-Print Network [OSTI]

', '': . . 195~9 ":, ' '59 9- ", 19. , -: '; '; 15'F9-;: . :: 418 ?: 499'' ', , : P "-. 8'~5, . : ?. ;. 159 9 . -', ::". , $9-. -:. . . : P P$3I8. :;. "-, . -. , :s8138: '439, ": . ::"::14i:, 9', . ::-', , '-- 4N ' -", ';, '. , :" XL' ". . -:, ' 14..., -. ;;. , ';. ;. . . XiqnM, :or es. crest. sn4-;~ss od As jskNsi' ':5xo, nsg4j~s's1'nips ?', :; . , "::, ' ', : digssegos emik mme-, el@, -er&kling-;Blear srs -eaiu nnies=smpg+sk'in ehs bra semsne. ok' ehs 'soles~, shd erssemiame nf ehs 1@n$4, 'rsspsnei'vole A eriohlkng...

Styner, Pete

1956-01-01T23:59:59.000Z

164

acid leach liquor: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MgOTiB2. Open Access Theses and Dissertations Summary: ??The stoichiometric Self-propagating High-temperature Synthesis (SHS) thermite reaction involving magnesium oxide...

165

acid leach liquors: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MgOTiB2. Open Access Theses and Dissertations Summary: ??The stoichiometric Self-propagating High-temperature Synthesis (SHS) thermite reaction involving magnesium oxide...

166

The preparation and analysis of ammonia base sulfite pulping liquor  

E-Print Network [OSTI]

NH3 Concentrations . . . . . , ~ . ~ . . ~ ~ . ~ q IV The Distribution of S02 in a 2. 82$ RR3 Solution for Various Total SO2 Concentrations . . . . . . , . . . ~ . . . 31 FIGURES l. Variation of pH with Percent NH3 in Solution. . . . . ~. . . 25... 2. Variation of pH with S02 Concentration in Solutions of Various NH Concentrations . . . . ~ . . . ~ . ~ o ~ . o . ~ 27 3 ~ Composition of Solutions to give a Constant pH of T and 2. 5 , ~ 2Q 4. The Variation of the Ratio of Free S02 to Total SO2...

Honstead, John Frederick

1950-01-01T23:59:59.000Z

167

Oil palm vegetation liquor: a new source of phenolic bioactives  

E-Print Network [OSTI]

Waste from agricultural products represents a disposal liability, which needs to be addressed. Palm oil is the most widely traded edible oil globally, and its production generates 85 million tons of aqueous by-products ...

Sambandan, T. G.

168

Emerging energy-efficient technologies for industry  

E-Print Network [OSTI]

recycled glass cullet Black liquor gasification Condebeltwastewater Microturbines Black liquor gasification Efficienttechnologies are black liquor gasification (a potentially

2001-01-01T23:59:59.000Z

169

Emerging energy-efficient technologies for industry  

E-Print Network [OSTI]

recycled glass cullet Black liquor gasification Condebeltwastewater Microturbines Black liquor gasification Efficienttechnologies are black liquor gasification (a potentially

2004-01-01T23:59:59.000Z

170

World Best Practice Energy Intensity Values for Selected Industrial Sectors  

E-Print Network [OSTI]

recovered from the black liquor recovery process (combustingand development in black liquor gasification has not yetgreen liquor, similar to the black liquor recovery process,

Worrell, Ernst; Price, Lynn; Neelis, Maarten; Galitsky, Christina; Zhou, Nan

2007-01-01T23:59:59.000Z

171

Analysis of Energy-Efficiency Opportunities for the Pulp and Paper Industry in China  

E-Print Network [OSTI]

efficiently utilize black liquor and other waste biomass forbiomass is used and black liquor is converted intoRecovery Falling film black liquor evaporation Black liquor

Kong, Lingbo

2014-01-01T23:59:59.000Z

172

High-solids enrichment of thermophilic microbial communities and their enzymes on bioenergy feedstocks  

E-Print Network [OSTI]

strain isolated from black liquor. Bioresource Technologyhave been enriched in black liquor samples from paper

Reddy, A. P.

2012-01-01T23:59:59.000Z

173

Oil palm vegetation liquor: a new source of phenolic bioactives Ravigadevi Sambanthamurthi1  

E-Print Network [OSTI]

teratological studies on rats up to the third generation and did not find any congenital anomalies. Thus for harvesting water-soluble antioxidants from oil palm has become available(12,14­17) . During the palm oil milling process, water-soluble pheno- lics are discarded in the waste stream, amounting to 85 million tons

Sinskey, Anthony J.

174

Recovery of Sugars from Ionic Liquid Biomass Liquor by Solvent Extraction  

E-Print Network [OSTI]

Bioenerg. Res. (2010) 3:123133 DOI 10.1007/s12155-010-9091-has been shown to be an Bioenerg. Res. (2010) 3:123133 12.Division, Joint BioEnergy Institute, Emeryville, CA, USA e-

Brennan, Timothy C.; Datta, Supratim; Blanch, Harvey W.; Simmons, Blake A.; Holmes, Bradley M.

2010-01-01T23:59:59.000Z

175

Study of soluble scale fouling control in high solids black liquor concentrators  

SciTech Connect (OSTI)

The quarterly project review meeting was held at IPST on August 2, 1999 and was attended by IPST, Georgia Tech, and ORNL principal investigators, members of the Industrial Advisory Group, and a U.S. DOE representative. Although steady progress is being made, this project is currently behind schedule. The specific tasks that are behind schedule, the reasons for the delays, and the expected completion dates are discussed. The remaining tasks are either on schedule, or have not been started.

Frederick, W. J.; Chen, F.; Hsieh, G.; Lien, S.; Murphy, R.W.; Rousseau, R.W.

1999-09-30T23:59:59.000Z

176

E-Print Network 3.0 - acidic leach liquor Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

NOx1 specified.2 Proler Rotary... of dioxins, acid gases and other problematic pollutants. The processes studied in detail; identified... -condensible compounds. Also, the...

177

Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping |  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-UpHeatMulti-Dimensional Subject:Ground HawaiiWaste Heat Recovery:|Department of

178

Subsidizing Solar: The Case for an Environmental Goods and Services Carve-out from the Global Subsidies Regime  

E-Print Network [OSTI]

IRS concluded that black liquor, a carbon-based byproductits application to black liquor almost certainly did. Thisthe application to black liquor) to create a perverse

Simmons, Zachary Scott

2014-01-01T23:59:59.000Z

179

Emerging energy-efficient industrial technologies  

E-Print Network [OSTI]

and P. Parthsarathy. 1999. Black Liquor Gasification: AKreutz, N. Berglin. 1998. Black Liquor Gasifier/Gas TurbineSystem Options with Black Liquor Gasification. In Pulp and

2000-01-01T23:59:59.000Z

180

Emerging Energy-Efficient Technologies for Industry  

E-Print Network [OSTI]

recycled glass cullet Black liquor gasification CondebeltBeam Sterilization Black liquor gasification Efficient cellSensors and controls Black liquor gasification Near net

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

The use of a permanent magnet for water content measurements of wood chips  

E-Print Network [OSTI]

making machine. The black liquor left over from the pulpingchips, brownstock, and black liquor. This report describes acellulose and water) and black liquor using the bench scale

2001-01-01T23:59:59.000Z

182

Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry  

E-Print Network [OSTI]

54 3.5.1. Black Liquor2006. "Ultrafiltration of black liquor using rotating diskultrafiltration of Kraft black liquor using rotating disk

Kong, Lingbo

2014-01-01T23:59:59.000Z

183

The Costs and Benefits of Compliance with Renewable Portfolio Standards: Reviewing Experience to Date  

E-Print Network [OSTI]

the inception of this RPS, black liquor gasification hasprimary source of RECs; black liquor typically costs lesspart of the main tier, black liquor represented 33% of the

Heeter, Jenny

2014-01-01T23:59:59.000Z

184

Opportunities to improve energy efficiency and reduce greenhouse gas emissions in the U.S. pulp and paper industry  

E-Print Network [OSTI]

Atlas, 1996b (? ). Black Liquor gasification IntroductionBerglin, N. July, 1998. Black Liquor Gasifier/Gas TurbinePreliminary Economics of Black Liquor Gasification Combined

Martin, Nathan; Anglani, N.; Einstein, D.; Khrushch, M.; Worrell, E.; Price, L.K.

2000-01-01T23:59:59.000Z

185

Magnet options for sensors for the pulp and paper industry  

E-Print Network [OSTI]

constituents of the black liquor leaving the paper digester,a papermaking machine. The black liquor left over from themoisture content of the black liquor leaving the digester,

Green, M.A.

2011-01-01T23:59:59.000Z

186

Strategies for Low Carbon Growth In India: Industry and Non Residential Sectors  

E-Print Network [OSTI]

uses heat and yields black liquor that can potentially be2007). However, the black liquor recovery in agro-residueHigh concentration of black liquor Continuous digester

Sathaye, Jayant

2011-01-01T23:59:59.000Z

187

ENERGY EFFICIENCY OPPORTUNITIES IN THE U.S. PULP AND PAPER INDUSTRY  

E-Print Network [OSTI]

chemicals (i.e. , black liquor) [5, 9]. Electricity is usedand other operations. Black liquor is the dominant fuel forconcentration Thick black liquor Refiner Steam Electricity

Kramer, Klaas Jan

2010-01-01T23:59:59.000Z

188

Clean Energy Technologies: A Preliminary Inventory of the Potential for Electricity Generation  

E-Print Network [OSTI]

21 13. Black LiquorChlorine-Alkaline Industry Black Liquor Gasification ResidueDC (LBNL-46990). 13. Black Liquor Gasification In standard

Bailey, Owen; Worrell, Ernst

2005-01-01T23:59:59.000Z

189

Opportunities to improve energy efficiency in the U.S. pulp and paper industry  

E-Print Network [OSTI]

Benefit Assessment of Black Liquor Gasifier/Combined CycleRecovery Falling film black liquor evaporation Tampellafiring Falling film black liquor evaporation Enzyme-assisted

Worrell, Ernst; Martin, Nathan; Anglani, Norma; Einstein, Dan; Khrushch, Marta; Price, Lynn

2001-01-01T23:59:59.000Z

190

Biofuel Boundaries: Estimating the Medium-Term Supply Potential of Domestic Biofuels  

E-Print Network [OSTI]

industrial residues - such as black liquor and sawdust, andindustry residues such as black liquor are mostly (93%) (18)industry residues, such as black liquor from their current

Jones, Andrew; O'Hare, Michael; Farrell, Alexander

2007-01-01T23:59:59.000Z

191

Emerging Energy-Efficiency and Greenhouse Gas Mitigation Technologies for the Pulp and Paper Industry  

E-Print Network [OSTI]

that extracts lignin from black liquor with the potential todissolving in the black liquor along with lignin (Hamzeh etextracts lignin from pulp mill black liquor: LignoBoost.

Kong, Lingbo

2014-01-01T23:59:59.000Z

192

Constraining uncertainties about the sources and magnitude of ambient air exposures to polycyclic aromatic hydrocarbons (PAHs): The state of Minnesota as a case study  

E-Print Network [OSTI]

wood, wood waste, and black liquor are reported by thee other= wood waste, black liquor, used oil, petroleum coke,

Lobscheid, Agnes B.; McKone, Thomas E.

2004-01-01T23:59:59.000Z

193

Potentials and policy implications of energy and material efficiency improvement  

E-Print Network [OSTI]

mechanical pulping Black liquor gasification/gasturbinefuels such as bark and black liquor, provide over 50% of the

Worrell, Ernst; Levine, Mark; Price, Lynn; Martin, Nathan; van den Broek, Richard; Block, Kornelis

1997-01-01T23:59:59.000Z

194

Determination of taurine concentration during cheddar cheese manufacture and examination of antioxidant properties of whey, permeate, mother liquor, and taurine  

E-Print Network [OSTI]

. 5 cm) to separate taurine from lactose. Six Iil of "C-taurine or "C-lactose (American Radiolabeled Chemicals, Inc. , St. Louis, MO ) was added to 10 ml of 1 mM taurine or I mM lactose solutions (pH 9. 74) respectively, to prepare standards... with "C-taurine or "C-lactose. 20 Amino Acid Analysis All chemicals used for amino acid analysis were purchased Irom the Sigma company (St. Louis, MO) except HPLC grade methanol and HPLC grade H, O which were obtained from the Fisher Co, , (Pittsburgh...

Li, Xin

1999-01-01T23:59:59.000Z

195

"Table 7b. Natural Gas Price, Electric Power Sector, Actual vs. Projected"  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:SeadovCooperativeA2. World9, 2014 International PetroleumFuel Oil8Status Total Totalb.

196

"Table HC1.1.3 Housing Unit Characteristics by Average Floorspace--"  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:SeadovCooperativeA2. World9, 2014 International PetroleumFuel Oil8Status Total Totalb.3

197

"Table HC1.2.3 Living Space Characteristics by Average Floorspace--"  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:SeadovCooperativeA2. World9, 2014 International PetroleumFuel Oil8Status Total Totalb.33

198

"Table HC1.3 Heated Floorspace Usage Indicators, 2005" " Million U.S. Housing Units"  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:SeadovCooperativeA2. World9, 2014 International PetroleumFuel Oil8Status Total Totalb.333

199

"Table HC1.4 Cooled Floorspace Usage Indicators, 2005" " Million U.S. Housing Units"  

U.S. Energy Information Administration (EIA) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia:FAQ < RAPID Jump to:SeadovCooperativeA2. World9, 2014 International PetroleumFuel Oil8Status Total Totalb.3334

200

Industry  

E-Print Network [OSTI]

Air bottoming cycle Black liquor gasification combined cycleCEPI, 2001), and that use continues to grow. Black liquorgasification: Black liquor is the residue from chemical

Bernstein, Lenny

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Waste Growth Challenges Local Democracy. The Politics of Waste between Europe and the Mediterranean: a Focus on Italy  

E-Print Network [OSTI]

capita); hydro (20%), black liquor, 6 peat, coal, wood fuel,to-door systems, but Black liquor is a byproduct of pulp,

Mengozzi, Alessandro

2010-01-01T23:59:59.000Z

202

Magnet options for sensors for the pulp and paper industry  

E-Print Network [OSTI]

the lignin and moisture content of the black liquor leavingof lignin and other constituents was measured black liquorlignin and cellulose that are dissolved in the black liquor.

Green, M.A.

2011-01-01T23:59:59.000Z

203

BIOLOGICAL ENGINEERING Program of Study  

E-Print Network [OSTI]

reaction engineering in wood pulping and pulp bleaching, char bed modeling, black liquor gasification

Thomas, Andrew

204

Nombramientos SECRETARIOS  

E-Print Network [OSTI]

types of fungal bioreactors with inmmobilized Trametes versicolor for post-treated weak black liquor

205

The Department of Chemical Engineering and Materials Science Michigan State University  

E-Print Network [OSTI]

a softwood kraft black liquor to determine the properties of solubilized lignin that resulted in their phase in the polysaccharide content of the black liquor, an effect of polysaccharide degradation and re- #12;adsorption

206

Evaluation of hydropyrolysis as an energy-saving alternative to the Tomlinson furnace. Task II. Chemistry of hydropyrolysis  

SciTech Connect (OSTI)

Studies were conducted of reactions involving model compounds of black liquor and reaction products when reacting black liquor at extreme conditions for the purpose of understanding the chemistry occurring in hydropyrolysis. Reaction studies of model compounds included: lignin precipitated from black liquor, the sodium salt of saccharinic acid, sodium lactate, sodium glycolate, sodium oxalate, sodium acetate and sodium formate.

Not Available

1981-01-01T23:59:59.000Z

207

E-Print Network 3.0 - arrest defective-1 controls Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: 12005 200500001 TO: FROM: Arrest Type WARRANT, SELLGIVE LIQUOR TO MINORS 1603 WOOTEN DR 132005 200500002 TO... : FROM: Arrest Type DRIVING WLICENSE SUSPEND-ARREST...

208

E-Print Network 3.0 - arrester wires Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: 12005 200500001 TO: FROM: Arrest Type WARRANT, SELLGIVE LIQUOR TO MINORS 1603 WOOTEN DR 132005 200500002 TO... : FROM: Arrest Type DRIVING WLICENSE SUSPEND-ARREST...

209

E-Print Network 3.0 - arrest refractory retroperitoneal Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: 12005 200500001 TO: FROM: Arrest Type WARRANT, SELLGIVE LIQUOR TO MINORS 1603 WOOTEN DR 132005 200500002 TO... : FROM: Arrest Type DRIVING WLICENSE SUSPEND-ARREST...

210

E-Print Network 3.0 - arrests Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: 12005 200500001 TO: FROM: Arrest Type WARRANT, SELLGIVE LIQUOR TO MINORS 1603 WOOTEN DR 132005 200500002 TO... : FROM: Arrest Type DRIVING WLICENSE SUSPEND-ARREST...

211

E-Print Network 3.0 - arrested mammaryacini predicts Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: 12005 200500001 TO: FROM: Arrest Type WARRANT, SELLGIVE LIQUOR TO MINORS 1603 WOOTEN DR 132005 200500002 TO... : FROM: Arrest Type DRIVING WLICENSE SUSPEND-ARREST...

212

E-Print Network 3.0 - agonist xct-790 arrests Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: 12005 200500001 TO: FROM: Arrest Type WARRANT, SELLGIVE LIQUOR TO MINORS 1603 WOOTEN DR 132005 200500002 TO... : FROM: Arrest Type DRIVING WLICENSE SUSPEND-ARREST...

213

E-Print Network 3.0 - arrester beds Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: 12005 200500001 TO: FROM: Arrest Type WARRANT, SELLGIVE LIQUOR TO MINORS 1603 WOOTEN DR 132005 200500002 TO... : FROM: Arrest Type DRIVING WLICENSE SUSPEND-ARREST...

214

E-Print Network 3.0 - arrested unfertilized sea Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: 12005 200500001 TO: FROM: Arrest Type WARRANT, SELLGIVE LIQUOR TO MINORS 1603 WOOTEN DR 132005 200500002 TO... : FROM: Arrest Type DRIVING WLICENSE...

215

E-Print Network 3.0 - adaptation growth arrest Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: 12005 200500001 TO: FROM: Arrest Type WARRANT, SELLGIVE LIQUOR TO MINORS 1603 WOOTEN DR 132005 200500002 TO... : FROM: Arrest Type DRIVING WLICENSE...

216

art bottom-up methods: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquor Moutai, or a clever counterfeit. Moutai has been dubbed the "national wine... Hacker, Randi; Boyd, David 2011-03-30 2 introduction videogame stimuli bottom-up...

217

alcoholic beverage hormesis: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alcohol Defined: Any liquor (distilled spirits), beer (fermented malt beverage) or wine containing ethyl alcohol. Boise State Barrash, Warren 48 THE OHIO STATE UNIVERSITY at...

218

alcoholic beverage preference: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alcohol Defined: Any liquor (distilled spirits), beer (fermented malt beverage) or wine containing ethyl alcohol. Boise State Barrash, Warren 50 THE OHIO STATE UNIVERSITY at...

219

alcoholic beverages: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alcohol Defined: Any liquor (distilled spirits), beer (fermented malt beverage) or wine containing ethyl alcohol. Boise State Barrash, Warren 47 THE OHIO STATE UNIVERSITY at...

220

Energy-Efficiency Improvement Opportunities for the Textile Industry  

E-Print Network [OSTI]

A.B. ; Can, M. , 2009. ?Waste-heat recovery potential inwaste liquor Recovery of waste heat Heat released fromsafety modifications, waste heat from air compressors can be

Hasanbeigi, Ali

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Effect of raw material and Kraft Pulping Conditions on Characteristics of Dissolved Lignin.  

E-Print Network [OSTI]

?? Lignin is one of the main components in wood and during the chemical pulping processes it is degraded and dissolved into the cooking liquor. (more)

Svrd, Antonia

2014-01-01T23:59:59.000Z

222

Lignin as Both Fuel and Fusing Binder in Briquetted Anthracite Fines for Foundry Coke Substitute.  

E-Print Network [OSTI]

??Lignin that had been extracted from Kraft black liquor was investigated as a fusing binder in briquetted anthracite fines for a foundry coke substitute. Cupola (more)

Lumadue, Matthew

2012-01-01T23:59:59.000Z

223

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 PARTICULATES #1PARTICULATES #1  

E-Print Network [OSTI]

Leather waste ~5 Estonian oil shale ~40 OrimulsionTM ~1.5 Black liquor solids 30 - 40 #12;HELSINKI 2 - 8 Oil oil oil

Zevenhoven, Ron

224

This document must be cited according to its final version which is published in a conference proceeding as  

E-Print Network [OSTI]

. White liquor and pre- steamed chips are introduced at the top of the digester into the impregnation zone of cold, dilute liquor. This effectively quenches the delignification reaction. The quality of the resulting pulp is described by Kappa #, which is a measure of the residual lignin content. A typical control

Boyer, Edmond

225

Method for cleaning sinter plant gas emissions  

SciTech Connect (OSTI)

A method for cleaning sinter plant gas emissions using a wet electrostatic precipitator system having separate recirculating wash liquor loops for the high voltage precipitator section and the pre-scrubber section. The system is operated with acidic washing liquor to avoid scaling and deposition of solids within the system.

Herman, S.T.; Jassund, S.A.; Mazer, M.R.

1981-03-17T23:59:59.000Z

226

UBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation Into the Wheat Straw Paper  

E-Print Network [OSTI]

pulping is the black liquor residue. Regarding the black liquor, a by-product of wheat straw pulping, Vibratory Shear Enhanced Process (VSEP) shows that lignin and hemicelluloses can be extracted from the blackUBC Social Ecological Economic Development Studies (SEEDS) Student Report An Investigation

227

A History of the Social Phases of the Temperance Movement in Kansas  

E-Print Network [OSTI]

staff in the KU Libraries Center for Digital Scholarship. http://kuscholarworks.ku.edu S u b m i t t e d t o t h e D e p a r t m e n t o f Sociology and the Faculty of the Graduate School in part ial ful f i l lment of the requirements... Riot. (3) The First Laws. (4) A Petition to the Topeka Movement. (5) The First Liquor Vote in Lawrence, (6) The Liquor Law of 1859. (7) How the Liquor Business Fared under the License Lav;. (8) The First Temperance Organization in Kansas. (9...

Lacy, Lester D.

1916-01-01T23:59:59.000Z

228

ANNUAL REPORT RESEARCH PROGRAM  

E-Print Network [OSTI]

........................................................16 A Simulation Analysis of Cotton Gin Financial Viability Under Risk.............. 17 Cottonseed of the World's Leading Producers...................................20 Structural Models of the U Liquor Gasification..................................................................28 Effects of Social

Rock, Chris

229

GLOBAL OPTIMIZATION OF ENERGY AND PRODUCTION IN PROCESS INDUSTRIES: A  

E-Print Network [OSTI]

(collection and treatment) depart- ment, the auxiliary boiler and the turbogenerator. The water department) The task of the auxiliary boiler, together with the recovery boiler, is to produce high-pressure steam (HPS) (the recovery boiler also produces green liquor).

Neumaier, Arnold

230

Method of recovering uranium from aqueous solution  

SciTech Connect (OSTI)

Anion exchange resin derived from insoluble crosslinked polymers of vinyl benzyl chloride which are prepared by polymerizing vinyl benzyl chloride and a crosslinking monomer are particularly suitable in the treatment of uranium bearing leach liquors.

Albright, R.L.

1980-01-22T23:59:59.000Z

231

Size dependent study of MeOH decomposition over size-selected Pt nanoparticles synthesized via micelle encapsulation  

E-Print Network [OSTI]

in fuel cell vehicles [3]. Methanol can be produced from a number of renewable resources such as black liquor, animal waste, and dedicated energy crops, giving it environmental as well as economic appeal

Kik, Pieter

232

Control of scale in flue gas scrubbers  

SciTech Connect (OSTI)

This patent describes a flue gas desulfurization system in which sulfur dioxide-containing flue gas is passed in countercurrent flow with an aqueous calcium-bearing scrubbing liquor whereby the sulfur dioxide is removed from the flue gas by being absorbed by the scrubbing liquor and converted to calcium sulfite and/or calcium sulfate. The improvement of minimizing the formation of calcium scale on the surfaces of the system comprises maintaining in the scrubbing liquor about 0.1-25 ppm of a 1:1 diisobutylene-maleic anhydride copolymer having an average molecular weight of 11000. The copolymer is incorporated in the scrubbing liquor as a 10-15% aqueous dispersion.

Thomas, P.A.; Dewitt-Dick, D.B.

1987-06-02T23:59:59.000Z

233

Establishment of ultraviolet absorption analysis at 2050 A as a viable indicator of delignification rate  

SciTech Connect (OSTI)

The UV absorption of diluted black liquor samples at 2050 A and the percent lignin removed from wood (Pinus strobus) during kraft pulping, when plotted against each other, produced a linear relation with a correlation coefficient of 0.961. This result indicated the viability of using UV absorption analysis of black liquor samples in the determination of reaction rate of lignin within the chip.

Bobier, W.D.; Poniatowski, S.E.; Walkinshaw, J.W.

1981-01-01T23:59:59.000Z

234

Direct fuel cell for the production of electricity from lignin  

SciTech Connect (OSTI)

This report describes the use of an anthraquinone mediated fuel cell for the direct production of electrical energy from sulfonated lignin and Kraft Black Liquor. The cell produces the equivalent of one kWh for each 2-3 lb sulfonated lignin and 5-8 lb black liquor combustibles. In the case of the sulfonated lignin, chain session occurs during the oxidation process, reducing the molecular weight from ca. 2 x 10/sup 4/ to less than 1000 D.

Weetall, H.H.; Forsyth, B.D.; Hertl, W.

1985-07-01T23:59:59.000Z

235

Kraft recovery boiler physical and chemical processes  

SciTech Connect (OSTI)

The focus of this book is on the recent research into the physical and chemical processes occurring in and around a black liquor recovery boiler. Almost all of the detailed technical information in this book has previously appeared in the open literature. The purpose here is not to present research for the first time, but to present it in a context of the other processes occurring in recovery boilers. Topics covered include: general characteristics of recovery boilers; black liquor thermal and transport properties; black liquor droplet formation and combustion; recovery boiler char bed processes; flow and mixing in Kraft recovery boilers; entrainment and carryover in recovery furnaces; fume formation and dust chemistry; deposits and boiler plugging; and recovery boiler thermal performance. 257 refs., 102 figs., 38 tabs.

Adams, T.N.; Frederick, W.J. (Adams (Terry N.), Tacoma, WA (USA); Oregon State Univ., Corvallis, OR (USA). Dept. of Chemical Engineering)

1988-01-01T23:59:59.000Z

236

Sacrificial adsorbate for surfactants utilized in chemical floods of enhanced oil recovery operations  

SciTech Connect (OSTI)

The present invention is directed to a sacrificial or competitive adsorbate for surfactants contained in chemical flooding emulsions for enhanced oil recovery operations. The adsorbate to be utilized in the method of the present invention is a caustic effluent from the bleach stage or the weak black liquor from the digesters and pulp washers of the kraft pulping process. This effluent or weak black liquor is injected into an oil-bearing subterranean earth formation prior to or concurrent with the chemical flood emulsion and is adsorbed on the active mineral surfaces of the formation matrix so as to effectively reduce adsorption of surfactant in the chemical flood. Alternatively, the effluent or liquor can be injected into the subterranean earth formation subsequent to a chemical flood to displace the surfactant from the mineral surfaces for the recovery thereof.

Johnson, J.S.; Westmoreland, C.G.

1982-02-02T23:59:59.000Z

237

Sacrificial adsorbate for surfactants utilized in chemical floods of enhanced oil recovery operations  

DOE Patents [OSTI]

The present invention is directed to a sacrificial or competitive adsorbate for surfactants contained in chemical flooding emulsions for enhanced oil recovery operations. The adsorbate to be utilized in the method of the present invention is a caustic effluent from the bleach stage or the weak black liquor from the digesters and pulp washers of the kraft pulping process. This effluent or weak black liquor is injected into an oil-bearing subterranean earth formation prior to or concurrent with the chemical flood emulsion and is adsorbed on the active mineral surfaces of the formation matrix so as to effectively reduce adsorption of surfactant in the chemical flood. Alternatively, the effluent or liquor can be injected into the subterranean earth formation subsequent to a chemical flood to displace the surfactant from the mineral surfaces for the recovery thereof.

Johnson, Jr., James S. (Oak Ridge, TN); Westmoreland, Clyde G. (Rockwood, TN)

1982-01-01T23:59:59.000Z

238

Sacrificial adsorbate for surfactants utilized in chemical floods of enhanced oil recovery operations  

DOE Patents [OSTI]

The present invention is directed to a sacrificial or competitive adsorbate for surfactants contained in chemical flooding emulsions for enhanced oil recovery operations. The adsorbate to be utilized in the method of the present invention is a caustic effluent from the bleach stage or the weak black liquor from the digesters and pulp washers of the kraft pulping process. This effluent or weak black liquor is injected into an oil-bearing subterranean earth formation prior to or concurrent with the chemical flood emulsion and is adsorbed on the active mineral surfaces of the formation matrix so as to effectively reduce adsorption of surfactant in the chemical flood. Alternatively, the effluent or liquor can be injected into the subterranean earth formation subsequent to a chemical flood to displace the surfactant from the mineral surfaces for the recovery thereof.

Johnson, J.S. Jr.; Westmoreland, C.G.

1980-08-20T23:59:59.000Z

239

Apparatus for control of mercury  

DOE Patents [OSTI]

A method and apparatus for reducing mercury in industrial gases such as the flue gas produced by the combustion of fossil fuels such as coal adds hydrogen sulfide to the flue gas in or just before a scrubber of the industrial process which contains the wet scrubber. The method and apparatus of the present invention is applicable to installations employing either wet or dry scrubber flue gas desulfurization systems. The present invention uses kraft green liquor as a source for hydrogen sulfide and/or the injection of mineral acids into the green liquor to release vaporous hydrogen sulfide in order to form mercury sulfide solids.

Downs, William (Alliance, OH); Bailey, Ralph T. (Uniontown, OH)

2001-01-01T23:59:59.000Z

240

Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant  

SciTech Connect (OSTI)

When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

Gambert, G.

1996-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Process for producing fuel grade ethanol by continuous fermentation, solvent extraction and alcohol separation  

DOE Patents [OSTI]

Alcohol substantially free of water is prepared by continuously fermenting a fermentable biomass feedstock in a fermentation unit, thereby forming an aqueous fermentation liquor containing alcohol and microorganisms. Continuously extracting a portion of alcohol from said fermentation liquor with an organic solvent system containing an extractant for said alcohol, thereby forming an alcohol-organic solvent extract phase and an aqueous raffinate. Said alcohol is separated from said alcohol-organic solvent phase. A raffinate comprising microorganisms and unextracted alcohol is returned to the fermentation unit.

Tedder, Daniel W. (Marietta, GA)

1985-05-14T23:59:59.000Z

242

Advanced Modeling and Materials in Kraft Pulp Mills  

SciTech Connect (OSTI)

This CRADA provided technical support to the Weyerhaeuser Company on a number of issues related to the performance and/or selection of materials at a number of locations in a pulp and paper mill. The studies related primarily to components for black liquor recovery boilers, but some effort was directed toward black liquor gasifiers and rolls for paper machines. The purpose of this CRADA was to assist Weyerhaeuser in the evaluation of materials exposed in various paper mill environments and to provide direction in the selection of alternate materials, when appropriate.

Keiser, J.R.; Gorog, J.P.

2002-05-15T23:59:59.000Z

243

Total organic carbon as an indicator of wood delignification  

SciTech Connect (OSTI)

Kraft pulping experiments were performed in a 12-liter electrically heated laboratory digester to determine pulp yields and residual lignin content (kappa number) as a function of time. Samples of the pulp and the black liquor were analyzed for total organic carbon (TOC) content by oxidizing the samples in a combustion furnace and measuring the released CO/sub 2/ gravimetrically. The experimental data on TOC were correlated with kappa number and yield. Results can be explained satisfactorily using a mathematical model based upon the principle of conservation of mass. The TOC content of black liquor appears to be a useful parameter for batch digester control. 17 references.

Genco, J.M.; Hassler, J.C.; Busayasakul, N.

1984-07-01T23:59:59.000Z

244

Wastewater Recycle- A Sustainable Approach Towards Desalination  

E-Print Network [OSTI]

for biomass control and solids separation. Thus the quality of the MBR effluent is independent of the quality (settlability) of the mixed liquor and that even if the biological process is upset the membrane can ensure that there will be no suspended solids... in the effluent. ? Mixed liquor suspended solids (MLSS) concentration in MBR is typically 3?5 (8000-15000 mg/lit) times as that in ASP, due to which, with same biomass inventory, in MBR it is possible to reduce bioreactor volume to one-third to one...

Mittal, A.

2013-01-01T23:59:59.000Z

245

Modification of alkaline pulping to facilitate the isolation of aliphatic acids. Part 1. Sodium hydroxide pretreatment of pine wood  

SciTech Connect (OSTI)

Pretreating pine chips (Pinus sylvestris) with sodium hydroxide prior to the alkaline delignification kraft, kraft-anthraquinone, and soda-anthraquinone) can facilitate the recovery of the carbohydrate degradation products from alkaline pulping liquors. Under suitable pretreatment conditions large amounts of carbohydrate degradation products (alipahtic acids) were formed relative to lignin. The lignin fraction was composed of comparatively low-molecular-weight fragments. Although the delignification was considerably retarded and the yield (based on wood) was decreased by 1-3%, the properties of the resulting pulp were essentially maintained despite pretreatment. Finally, data are given for the composition of aliphatic acids in liquors resulting from pretreatments.

Alen, R.; Niemelae, K.; Sjoestroem, E.

1984-01-01T23:59:59.000Z

246

PEER REVIEWED FIBER SUPPLY Beetle-killed spruce utilization in the Kenai peninsula  

E-Print Network [OSTI]

in a stainless-steel digester with pumped liquor circulation and indirect steam heating. Each log was pulped wood. Burst and tensile strength were strongly depen- dent on the amount of log decay, as measured quality when com- pared to the control. 48 TAPPI JOURNAL JUNE 2000 #12;

Abubakr, Said

247

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 NITROGEN #1NITROGEN #1  

E-Print Network [OSTI]

fuels Biomasses & waste - derived fuels Coal 0.5 ­ 3 Wood 0.1 ­ 0.5 Bark ~ 0.5 Oil Petroleum coke ~ 3 Auto shredder residue (ASR) ~ 0.5 Leather waste ~ 12 OrimulsionTM ~ 4 Black liquor solids

Zevenhoven, Ron

248

Generator-absorber-heat exchange heat transfer apparatus and method and use thereof in a heat pump  

DOE Patents [OSTI]

Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use, as the heat transfer medium, the working fluid of the absorption system taken from the generator at a location where the working fluid has a rich liquor concentration. 5 figs.

Phillips, B.A.; Zawacki, T.S.

1998-07-21T23:59:59.000Z

249

www.ku.edu/safety The Clery Act Annual Security Report  

E-Print Network [OSTI]

attain maximum effectiveness unless everyone contributes to making it work. Safety and security are bothwww.ku.edu/safety The Clery Act Annual Security Report The Annual Fire Report Calendar Year 2012 of drug and liquor laws In this report you will find information about: Reporting Crime Safety

250

Pulp and Paper Corrosion Symposium Georgia Tech Renewable Bioproducts Institute  

E-Print Network [OSTI]

1 Pulp and Paper Corrosion Symposium Georgia Tech Renewable Bioproducts Institute November 2014 Digester Corrosion Margaret Gorog Federal Way, WA 2 · Chips plus a mixture of white and black liquor · The pulp is then blown from the bottom of the vessel into a blow tank · Corrosion occurs during filling

Das, Suman

251

Energy-Efficiency Improvement Opportunities for the Textile Industry  

E-Print Network [OSTI]

is a high demand for low-temperature hot water in textilehot waste water in autoclaves Autoclave (high temperature/high-temperature dyeing at 130 for optimum heat recovery, C maximum cut-off between hot bath liquors and rinsing water,

Hasanbeigi, Ali

2010-01-01T23:59:59.000Z

252

Process for producing peracids from aliphatic hydroxy carboxylic acids  

SciTech Connect (OSTI)

This patent describes a wood pulp processing system of the type producing both pulp and a stream of lactic acid-containing black liquor solution, the processor for production of peracid bleaching agents from hydroxy acid contained in the black liquor solution, comprising: adjusting the pH of the black liquor solution to the range of about 8-9 by exposing the solution to CO/sub 2/ carbon dioxide to form an alkaline precipitate; separating solids from the black liquor solution to produce a residual solution containing lower aliphatic hydroxy acids selected from the group consisting of lactic acid, glycolic acid, 2-hydroxybutanoic acid, xyloisosaccharinic acid, and glucoisosaccharinic acid; decarboxylating the lower aliphatic hydroxy acids to corresponding gaseous aliphatic aldehydes by admixing a powdered semiconductor with the residual solution to form a slurry; removing the gaseous aldehydes from the residual solution by sweeping gas flow as soon as they are generated to prevent further oxidation to carboxylic acids; reacting the gaseous aldehydes with oxygen to form corresponding peracids; and applying the peracids as bleaching agents to the pulp produced in the pulp processing system.

Chum, H.L.; Ratcliff, M.A.; Palasz, P.D.

1986-10-14T23:59:59.000Z

253

Generator-absorber-heat exchange heat transfer apparatus and method and use thereof in a heat pump  

DOE Patents [OSTI]

Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use the working solution of the absorption system for the heat transfer medium. A combination of weak and rich liquor working solution is used as the heat transfer medium.

Phillips, Benjamin A. (Benton Harbor, MI); Zawacki, Thomas S. (St. Joseph, MI)

1996-12-03T23:59:59.000Z

254

Generator-absorber-heat exchange heat transfer apparatus and method and use thereof in a heat pump  

DOE Patents [OSTI]

Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use, as the heat transfer medium, the working fluid of the absorption system taken from the generator at a location where the working fluid has a rich liquor concentration.

Phillips, Benjamin A. (Benton Harbor, MI); Zawacki, Thomas S. (St. Joseph, MI)

1998-07-21T23:59:59.000Z

255

A Guide on Local Agriculture for Houstonians Sarita Panchang  

E-Print Network [OSTI]

stores and supermarkets, while poor areas have a higher level of liquor stores and fast food restaurants steadily rising since 1994; between 2008 and 2009 alone there was a 13% increase.1 This report serves produce within metropolitan Houston (inside Beltway 8), to focus on food access for communities in poverty

Richards-Kortum, Rebecca

256

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 SULPHUR #1SULPHUR #1  

E-Print Network [OSTI]

) ·· HH22S (gasification) highly poisonousS (gasification) highly poisonous oxidation to SOoxidation to SO. · natural gases / raw fuel gases á H2S · unrefined oil / heavy fuel oils á small amounts of sulphur · waste-derived fuels á e.g. vulcaniser, food-derived waste (garlic, onion), "black liquor" etc. organic á sulphides

Zevenhoven, Ron

257

EMERGINGTECHN0 LOGIES COM:MERCIALlZING BLACK  

E-Print Network [OSTI]

COMMERCIALPRODUC710N REQUIRES WORK AND INVEST~ENT BY MANY PAR11Es. -- B LACK UQUOR AND BIOMASS GASIFIER DEVELOPMENT by the suc- by the U.S.Departmentof Energy(4), providesa mecha- cessful introduction of black liquor gasifier/combined nism for the industry to work togethertoward commer- cycle (BLGCC) and biomass gasifier/combined cycle

258

Preparedfor theTAPPIInternationalChemicalRecoveryConference .Tampa, Florida, 1-4June1998  

E-Print Network [OSTI]

of a specific gas turbine. There are many different models from which to choose, but with only a fixed set applications. A perfect match between the fuel requirement of a gas turbine and the fuel that can be generated and prospective economics of BLGCC systems involving a fixed-size gas turbine at mills with black liquor

259

Bottoms Up  

E-Print Network [OSTI]

Broadcast Transcript: "Bottoms up!" Or, "gan bei," as they say here in China. But what are you drinking? It could either be the authentic 144-proof sorghum-based liquor Moutai, or a clever counterfeit. Moutai has been dubbed the "national wine...

Hacker, Randi; Boyd, David

2011-03-30T23:59:59.000Z

260

RESEARCH Open Access Agave proves to be a low recalcitrant  

E-Print Network [OSTI]

is well known for tequila and other liquor production in Mexico, has recently gained attention because of its attractive potential to launch sustainable bioenergy feedstock solutions for semi-arid and arid of studying agave's low recalcitrance for developments in improving cellulosic energy crops. Keywords: Agave

California at Riverside, University of

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

The Dalhousie Employee Guide to Materials Management on Campus Look for the 4 system bins around campus designated for recyclables, paper/cardboard, organics and garbage.  

E-Print Network [OSTI]

, straws, and dvd cases (garbage) Foams & soft # 6 plastics (garbage) Broken glass (garbage) What belongs cans, liquor/beer containers Milk containers Glass bottles and containers Tin, steel, and aluminum sweepings Broken glass (must be boxed & taped) Disposable gloves (latex, vinyl, etc.) Ceramics Packaging

Brownstone, Rob

262

Are BKME effects on fish caused by chlorinated compounds?  

SciTech Connect (OSTI)

Much of the debate about the use and environmental impacts of chlorinated compounds has been fueled by attempts to regulate the effluents discharged by pulp and paper mills. Swedish field studies have associated effects on fish health and reproduction with the discharge of AOX. A recent study has demonstrated that the effect of black liquor is three orders of magnitude more potent than the first chlorine dioxide bleachery effluent on fish. Black liquors from various pulp mills, including a mill which uses alcohol to extract lignin, also suggest that effects on fish could be caused by non-chlorinated wood extractives, Chemical analysis of isolated fractions from final BKME effluent and pure compound bioassays also indicate the high probability that non-chlorinated compounds may be responsible for fish effects. While chlorination may increase the potency of these compounds, it is clear that chlorine is not essential for effects on fish.

Burnison, B.K.; Hodson, P.V.; Parrott, J. [National Water Research Institute, Ontario (Canada)] [and others

1995-12-31T23:59:59.000Z

263

Southern Pine Based on Biorefinery Center  

SciTech Connect (OSTI)

This program seeks to develop an integrated southern pine wood to biofuels/biomaterials processing facility on the Recipients campus, that will test advanced integrated wood processing technologies at the laboratory scale, including: The generation of the bioethanol from pines residues and hemicelluloses extracted from pine woodchips; The conversion of extracted woodchips to linerboard and bleach grade pulps; and The efficient conversion of pine residues, bark and kraft cooking liquor into a useful pyrolysis oil.

Ragauskas, Arthur J; Singh, Preet

2014-01-10T23:59:59.000Z

264

Development of advanced technology of coke oven gas drainage treatment  

SciTech Connect (OSTI)

In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

1996-12-31T23:59:59.000Z

265

Method for aqueous gold thiosulfate extraction using copper-cyanide pretreated carbon adsorption  

DOE Patents [OSTI]

A gold thiosulfate leaching process uses carbon to remove gold from the leach liquor. The activated carbon is pretreated with copper cyanide. A copper (on the carbon) to gold (in solution) ratio of at least 1.5 optimizes gold recovery from solution. To recover the gold from the carbon, conventional elution technology works but is dependent on the copper to gold ratio on the carbon.

Young, Courtney; Melashvili, Mariam; Gow, Nicholas V

2013-08-06T23:59:59.000Z

266

Calculating Fired Heater Efficiency  

E-Print Network [OSTI]

bills. A review of the Heat Loss and Input/Output methods of efficiency analyses is presented, along with a discussion of their relative accuracy. Examples cited include refinery mixed fuel gas, coal, and chemical recovery fueled applications, using.... 75 percent excess 02 (dry basis) -- a respectable operation. Eva luate boi ler effieiency when burning mixed refinery gas (at an oil refinery), coa1 (at a central power station) and black liquor (at a paper mill). The practical definition of LHV...

Harriz, J. T.; Ritter, E. L.

267

"Separations: Dust to Dust" or " You Can't Escape Em"  

E-Print Network [OSTI]

OH) as absorbent. In this case the water, vaporized under vacuum at a low temperature, serves as the refrigerant. The counter-current wash column was selected over centrifugation because of the higher losses normally experienced with the latter. A vacuum... nitrites. Freeze crystallization is being developed for concentrating black liquor in the paper making process. Evaporation has been applied to the plating process to eliminate a waste disposal problem. INTRODUCTI ON In the broadest sense, separation...

Massey, R. G.

268

Test procedures and instructions for Hanford tank waste supernatant cesium removal  

SciTech Connect (OSTI)

This document provides specific test procedures and instructions to implement the test plan for the preparation and conduct of a cesium removal test using Hanford Double-Shell Slurry Feed supernatant liquor from tank 251-AW-101 in a bench-scale column.Cesium sorbents to be tested include resorcinol-formaldehyde resin and crystalline silicotitanate. The test plan for which this provides instructions is WHC-SD-RE-TP-022, Hanford Tank Waste Supernatant Cesium Removal Test Plan.

Hendrickson, D.W., Westinghouse Hanford

1996-05-31T23:59:59.000Z

269

Kraft lignin recovery by ultrafiltration: economic feasibility and impact on the kraft recovery system  

SciTech Connect (OSTI)

The widespread use of the kraft pulping process could provide a ready supply of lignin materials for many uses. Simulation studies demonstrate that recovery of the high-molecular-weight kraft lignin by ultrafiltration of a fraction of the black liquor flow is attractive from both an economic and an operational standpoint. Benefits are derived from relief of a furnace-limited recovery system and from the marketing of the lignin or modified lignin products. 10 references.

Kirkman, A.G.; Gratzl, J.S.; Edwards, L.L.

1986-05-01T23:59:59.000Z

270

Treatability study of industrial waste using sanitary sewage to supply nutrients  

E-Print Network [OSTI]

are: (1) insufficient nutrients will cause the development of filamentous bacteria and they will be predominant in the mixed liquor suspended solids and interfere with the conversion of organic materials to end products and reduce the efficiency... biochemical oxygen demand (BOD ), total organic carbon (TOC), pH, total phosphorus (P), total Kjeldahl nitrogen (TKN), ammonia nitrogen (NH3-N), total suspended solids (TSS), total dis- solved solids (TDS), total volatile solids (TVS) and fixed residue...

Ferguson, James Ritchie

1978-01-01T23:59:59.000Z

271

A clarifier design technique for contact - stabilization plants in Texas  

E-Print Network [OSTI]

on 2 800 gp ? overflow rate). The organic loading intensity was 0. 5 lb. d ft 80D per lb. MLSS, with 2000 ? mixed liquor suspended solids and 33 200 ~ DOS. Dick's example showed that when clarifiers for an ll, activated sludge process have... suspended solids concentration. The curve describing this relationship could be used to replace the Texas state standard and, thus, assure proper clarifier design for clarification and thickening. ACKNOWLEDGMENTS The author w1shes to express his...

Boles, Michael Hayden

1974-01-01T23:59:59.000Z

272

Ion exchange as a tertiary treatment  

E-Print Network [OSTI]

that these treatment methods are capable of removing an appreciable amount of objection? able dissolved organic and inorganic materi aJ s from the final effluent. Color and turbidity were greatly reduced and an appreciable amount of the suspended solids were... Demand Re Resin A General Anion mg. /1. MLVSS psi gpm Milligrams per I. iter Mixed Liquor Volatile Suspended Solids Pounds per Square Inch Gallons per Minute. mm Mi llimeters kgr meq ml Kilogram Milliequilavent Millimeter S. S. BV...

Westervelt, Ronald David

1968-01-01T23:59:59.000Z

273

Characteristics and sources of intermediate size particles in recovery boilers : final project report.  

SciTech Connect (OSTI)

As part of the U.S. Department of Energy (DOE) Office of Industrial Technologies (OIT) Industries of the Future (IOF) Forest Products research program, a collaborative investigation was conducted on the sources, characteristics, and deposition of particles intermediate in size between submicron fume and carryover in recovery boilers. Laboratory experiments on suspended-drop combustion of black liquor and on black liquor char bed combustion demonstrated that both processes generate intermediate size particles (ISP), amounting to 0.5-2% of the black liquor dry solids mass (BLS). Measurements in two U.S. recovery boilers show variable loadings of ISP in the upper furnace, typically between 0.6-3 g/Nm{sup 3}, or 0.3-1.5% of BLS. The measurements show that the ISP mass size distribution increases with size from 5-100 {micro}m, implying that a substantial amount of ISP inertially deposits on steam tubes. ISP particles are depleted in potassium, chlorine, and sulfur relative to the fuel composition. Comprehensive boiler modeling demonstrates that ISP concentrations are substantially overpredicted when using a previously developed algorithm for ISP generation. Equilibrium calculations suggest that alkali carbonate decomposition occurs at intermediate heights in the furnace and may lead to partial destruction of ISP particles formed lower in the furnace. ISP deposition is predicted to occur in the superheater sections, at temperatures greater than 750 C, when the particles are at least partially molten.

Baxter, Larry L. (Brigham Young University, Provo, UT); Shaddix, Christopher R.; Verrill, Christopher L. (Georgia Institute of Technology, Institute of Paper Science and Technology, Atlanta, GA); Wessel, Richard A. (Babcock & Wilcox Company, Barberton, OH)

2005-02-01T23:59:59.000Z

274

Combustion of concentrates resulting from ultrafiltration of bleached-kraft effluents  

SciTech Connect (OSTI)

This paper reports that closed cycle concentrates were simulated by laboratory-scale ultrafiltration of (C + D) and first E-stage effluents from two bleached-kraft mills. The concentrates were found to be similar to typical kraft black liquor in carbon content, heating value, and density, Viscosities of concentrates were similar to or slightly above the values over which black liquor viscosities commonly range. Burning rates for the dried solids from the concentrates were found to be similar to burning rates reported for black liquor. Volatiles yields (percentage of initial dried solids evolving as pyrolysis gases under pyrolytic conditions) were 46-50% and were not strongly dependent on final heating temperature. Char yields (percentage of initial dried solids gasified by heterogeneous char oxidation reactions) were strongly dependent on final heating temperature, increasing from nearly zero at 600{degrees} C to 42% at 1000{degrees} C. A simplistic combustion rate model was developed to predict the overall burning rates. It should prove useful for approximating the rates of combustion of ultrafiltration concentrates. The model includes a first-order rate expression for volatiles evolution and a pseudo-first order rate expression for char burning.

Nichols, K.M. (Div. of Chemical and Biological Sciences, Inst. of Paper Science and Technology, Atlanta, GA (US))

1992-04-01T23:59:59.000Z

275

Alternatives for balanced production of fibers, chemicals, and energy from wood  

SciTech Connect (OSTI)

Increased oil prices and shortage of fossil materials have recently focused interest on the possibilities of conversion of wood to various forms of fuels and chemicals. It is to be expected that new approaches are emerging from the totality of the research effort now in progress. However, irrespective of this, the function of wood as a construction material and a source for fibers presumably remains unchanged or even becomes more important in the future. In regard to the principal pulping methods for production of fibers, no abrupt changes in current practices are probable, apart from important progress in energy saving. In a very favorable situation of the kraft process, when surplus energy generated from the burning of black liquor is availiable, a partial recovery of dissolved organic solids, such as lignin and carbohydrates and their degradation products, becomes more attractive. Quite different is the case of the conventional sulfite process when evaporation and burning of the spent liquor result in severe air pollution. Successful recovery, conversion, and marketing of the dissolved solids can then be the only way to compensate for the expense of using external fuel. Alternatives for production of organic chemicals from kraft and sulfite spent liquors are discussed by taking into consideration the fiber production, composition of dissolved solids, energy requirements, pollution problems, and recovery of inorganic pulping chemicals. 11 references, 10 figures, 5 tables

Sjoestroem, E.

1983-01-01T23:59:59.000Z

276

Testing of an advanced thermochemical conversion reactor system  

SciTech Connect (OSTI)

This report presents the results of work conducted by MTCI to verify and confirm experimentally the ability of the MTCI gasification process to effectively generate a high-quality, medium-Btu gas from a wider variety of feedstock and waste than that attainable in air-blown, direct gasification systems. The system's overall simplicity, due to the compact nature of the pulse combustor, and the high heat transfer rates attainable within the pulsating flow resonance tubes, provide a decided and near-term potential economic advantage for the MTCI indirect gasification system. The primary objective of this project was the design, construction, and testing of a Process Design Verification System for an indirectly heated, thermochemical fluid-bed reactor and a pulse combustor an an integrated system that can process alternative renewable sources of energy such as biomass, black liquor, municipal solid waste and waste hydrocarbons, including heavy oils into a useful product gas. The test objectives for the biomass portion of this program were to establish definitive performance data on biomass feedstocks covering a wide range of feedstock qualities and characteristics. The test objectives for the black liquor portion of this program were to verify the operation of the indirect gasifier on commercial black liquor containing 65 percent solids at several temperature levels and to characterize the bed carbon content, bed solids particle size and sulfur distribution as a function of gasification conditions. 6 refs., 59 figs., 29 tabs.

Not Available

1990-01-01T23:59:59.000Z

277

Chemical recovery process using break up steam control to prevent smelt explosions  

DOE Patents [OSTI]

An improvement in a chemical recovery process in which a hot liquid smelt is introduced into a dissolving tank containing a pool of green liquor. The improvement comprises preventing smelt explosions in the dissolving tank by maintaining a first selected superatmospheric pressure in the tank during normal operation of the furnace; sensing the pressure in the tank; and further impinging a high velocity stream of steam upon the stream of smelt whenever the pressure in the tank decreases below a second selected superatmospheric pressure which is lower than said first pressure.

Kohl, Arthur L. (Woodland Hills, CA); Stewart, Albert E. (Eagle Rock, CA)

1988-08-02T23:59:59.000Z

278

Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant  

SciTech Connect (OSTI)

Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

Goshe, A.J.; Nodianos, M.J. [Wheeling-Pittsburgh Steel Corp., Follansbee, WV (United States)

1995-12-01T23:59:59.000Z

279

Nature, Causes and Correction of Discoloration of Canned Blackeye and Purple Hull Peas.  

E-Print Network [OSTI]

- cent ammonium alum or aluminum sulfate as a blanching solution, or by the use of a high-temperature and short-time sterilization process, or by combining these two methods. Unless pressurized cooling facilities are available, the use of a high...-temperature and short-time process is not recommended. A desirable side-effect derived f,rom the use of aluminum salts in the blanch solution is the reduction of both the vis- cosity of the liquor and gelling in the can. Though ammonium alum is used extensively...

Cain, R. F.; Culver, W. H.

1952-01-01T23:59:59.000Z

280

Laser-induced breakdown spectroscopy at high temperatures in industrial boilers and furnaces.  

SciTech Connect (OSTI)

Laser-induced breakdown spectroscopy (LIBS) was applied (1) near the superheater of an electric power generation boiler burning biomass, coat, or both, (2) at the exit of a glass-melting furnace burning natural gas and oxygen, and (3) near the nose arches of two paper mill recovery boilers burning black liquor. Difficulties associated with the high temperatures and high particle loadings in these environments were surmounted by use of novel LIBS probes. Echelle and linear spectrometers coupled to intensified CCD cameras were used individually and sometimes simultaneously. Elements detected include Na, K, Ca, Mg, C, B, Si, Mn, Al, Fe, Rb, Cl, and Ti.

Walsh, Peter M. (University of Alabama at Birmingham and Southern Research Institute, Birmingham, AL); Shaddix, Christopher R.; Sickafoose, Shane M.; Blevins, Linda Gail

2003-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Ultrafiltration. (Latest citations from the NTIS bibliographic database). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations concerning ultrafiltration, the separation of colloids or fine solid materials by filtration through microporous or semi-permeable materials. Citations discuss the use of the ultrafiltration process for removing dissolved toxic metals from groundwater, production of food-grade protein, treating kraft black liquor from pulp and paper processing, decontamination of low-level radioactive waste water, desalination, and hemodialysis. Topics also include ultrafiltration equipment and membrane descriptions. Procedures for preventing fouling and the cleaning of the filtration materials and membranes are also presented. (Contains a minimum of 133 citations and includes a subject term index and title list.)

Not Available

1994-12-01T23:59:59.000Z

282

Ultrafiltration. (Latest citations from the NTIS Bibliographic database). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations concerning ultrafiltration, the separation of colloids or fine solid materials by filtration through microporous or semi-permeable materials. Citations discuss the use of the ultrafiltration process for removing dissolved toxic metals from groundwater, production of food-grade protein, treating kraft black liquor from pulp and paper processing, decontamination of low-level radioactive waste water, desalination, and hemodialysis. Topics also include ultrafiltration equipment and membrane descriptions. Procedures for preventing fouling and the cleaning of the filtration materials and membranes are also presented. (Contains a minimum of 116 citations and includes a subject term index and title list.)

Not Available

1993-12-01T23:59:59.000Z

283

Ultrafiltration. (Latest citations from the NTIS bibliographic database). Published Search  

SciTech Connect (OSTI)

The bibliography contains citations concerning ultrafiltration, the separation of colloids or fine solid materials by filtration through microporous or semi-permeable materials. Citations discuss the use of the ultrafiltration process for removing dissolved toxic metals from groundwater, production of food-grade protein, treating kraft black liquor from pulp and paper processing, decontamination of low-level radioactive waste water, desalination, and hemodialysis. Topics also include ultrafiltration equipment and membrane descriptions. Procedures for preventing fouling and the cleaning of the filtration materials and membranes are also presented. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1995-12-01T23:59:59.000Z

284

Why Do Kraft Recovery Boiler Composite Floor Tubes Crack?  

SciTech Connect (OSTI)

Cracks were first reported in 1992 in co-extruded 304L stainless steel/SA210 Gd Al carbon steel floor tubes of North American black liquor recovery boilers. Since then, a considerable amount of information has been collected on the tube environment, crack characteristics, the stress state of the tubes, and the crack initiation and propagation mechanisms. These studies have identified both operating procedures that apparently can greatly lessen the likelihood of crack formation in the stainless steel layer and alternate materials that appear to be much more resistant to cracking than is 304L stainless.

Keiser, J.R.

2001-10-22T23:59:59.000Z

285

Control of the accumulation of non-process elements and organic compounds in pulp mills with bleach filtrate reuse. Quarterly report 3, January--March, 1997  

SciTech Connect (OSTI)

Progress during this quarter is described on four tasks. The first task involves the recovery of organic matter from bleach effluents and black liquors, separation of carbohydrates and lignin degradation products, analysis of functional groups, and characterization of carbohydrate polymers. Progress in the second task was made in the selection of model compounds. Several subtasks are complete in Task 3, but the paper summarizes progress made in the determination of the residual hemicellulose content in the pulp samples. Finally, results are given for the measurement of metal adsorption isotherms on wood pulp. Goals for the next quarter are listed.

Frederick, W.J.; Laver, M.L.; Rorrer, G.L.

1997-05-01T23:59:59.000Z

286

Fluorescence analyzer for lignin  

SciTech Connect (OSTI)

A method and apparatus for measuring lignin concentration in a sample of wood pulp or black liquor comprises a light emitting arrangement for emitting an excitation light through optical fiber bundles into a probe which has an undiluted sensing end facing the sample. The excitation light causes the lignin concentration to produce fluorescent emission light which is then conveyed through the probe to analyzing equipment which measures the intensity of the emission light. Measures a This invention was made with Government support under Contract Number DOE: DE-FC05-90CE40905 awarded by the Department of Energy (DOE). The Government has certain rights in this invention.

Berthold, John W. (Salem, OH); Malito, Michael L. (Hubbard, OH); Jeffers, Larry (Alliance, OH)

1993-01-01T23:59:59.000Z

287

Proceedings of the DOE/Industry Sensor Working Group meeting, Austin, Texas  

SciTech Connect (OSTI)

This paper report contains topics presented at a sensor workshop group meeting. The topics describe measuring instruments of use in the pulp and paper industry. Topics include: measurement of solids fraction; process instrumentation research for the pulp paper industry; real-time non-contact optical surface motion monitor; on-machine sensors to measure paper mechanical properties; hierarchical intelligent control of industrial processes -- an in-parallel lime kiln application; proposal for research on lignin concentration measurement in pulping liquors; and advanced polymeric sensor materials for industrial drying.

Not Available

1988-11-01T23:59:59.000Z

288

Relationship between the physical and mineralogical properties of two clays and their bloating characteristics  

E-Print Network [OSTI]

. Water Absorbtion of Clay at 22aC and 100 Percent Relative Humidity 3. Chemical Analysis Using Emission Spectrograph 4. Magnetic Properties of Clays and Aggregates 5. Carbon Analysis 6. Compositions of the Mixed Red Clay Samples 11 13 23 28... capacity of some clays. Successful attempts have 3 been made with lignin sulfite liquor and diesel fuel. ((hen the clay structure is destroyed, 11 large amounts of (OH) are released to react with the exchange ions in the clay. Therefore, the clay...

Abbott, Ute Agnes

1973-01-01T23:59:59.000Z

289

29 Virgins  

E-Print Network [OSTI]

." "Hnmm," said McCoy, reaching for the bottom drawer of his desk. He lifted out two glasses. The bottle followed, and the amber bouquet of pungent liquor bloomed almost visibly 1n the small room as he poured. "Start at the beginning," he suggested... forward and closed a switch on McCoy's desk. Her cheekbones showed a flush that rapidly covered her whole face as she said, "I heard. With the captain's permission, there may be a solution. "I'd be glad to hear one." Chapel kept her chin up and her...

Ferguson, Syn

1982-01-01T23:59:59.000Z

290

A new process for volume reduction of radwaste, drying and calcination of crystals  

SciTech Connect (OSTI)

The facility COMPLEX-1 designed for carrying out the processes of mass crystallization from solutions, separation of the resulting solid phase from mother liquor, drying of crystals, their calcination and loading the product obtained into containers, is described. The facility is entirely hermetic. It works in vacuum and has an autonomous system of gas purification, excluding the carryover of dust during the thermal treatment of the product obtained. All the technological processes are continuous and carried out in a minimum volume without pumping the products from apparatus to apparatus. The facility is compact and ecologically safer than the familiar analogous facilities. Each unit of the facility may be of special interest for users.

Krapukhin, V.B.; Kareta, V.I.; Zurin, V.D.; Lavricov, V.A.; Grushevsky, S.E. [Russian Academy of Sciences, Moscow (Russian Federation). Inst. of Physical Chemistry

1993-12-31T23:59:59.000Z

291

Extracting alcohols from aqueous solutions. [USDOE patent application  

DOE Patents [OSTI]

The objective is to provide an efficient process for extracting alcohols in aqueous solutions into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. This is done by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5-18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is then mixed with one or more of a group of polyoxyalkylene polymers to extract the alcohol into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

Compere, A.L.; Googin, J.M.; Griffith, W.L.

1981-12-02T23:59:59.000Z

292

A nautical archaeological study of Kublai Khan's fleets  

E-Print Network [OSTI]

huge cabins and masts. One ship could carry several hundred people and a year's provisions. Pig raising and liquor brewing were done on board. The cargo capacity of these ships was great. They did not have to fear big waves, but had to be careful... by the crew. The main compartment was divided into four sections and used, most likely, for cargo storage. The after compartment was a cabin for officers or special guests. A deckhouse used for similar purposes rose to a height of about three meters above...

Inoue, Takahiko

1991-01-01T23:59:59.000Z

293

Aluminum nitrate recrystallization and recovery from liquid extraction raffinates  

SciTech Connect (OSTI)

The solid sludges resulting form biodenitrification of discarded aluminum nitrate are the largest Y-12 Plant process solid waste. Aluminum nitrate feedstocks also represent a major plant materials cost. The chemical constraints on aluminum nitrate recycle were investigated to determine the feasibility of increasing recycle while maintaining acceptable aluminum nitrate purity. Reported phase behavior of analogous systems, together with bench research, indicated that it would be possible to raise the recycle rate from 35% to between 70 and 90% by successive concentration and recrystallization of the mother liquor. A full scale pilot test successfully confirmed the ability to obtain 70% recycle in existing process equipment.

Griffith, W.L.; Compere, A.L.; Googin, J.M.; Huxtable, W.P.

1991-09-01T23:59:59.000Z

294

Advanced separation technology for flue gas cleanup. Quarterly technical report No. 8, [January--March 1994  

SciTech Connect (OSTI)

During the first quarter of 1994, we continued work on Tasks 2, 3, 4, 5, and 6. We also began work on Task 7. In Task 2, we incorporated 4.5% O{sub 2} into our simulated flue gas stream during this quarter`s NO{sub x}-absorption experiments. We also ran experiments using Cobalt (II)-phthalocyanine as an absorbing agent We observed higher absorption capacities when using this solution with the simulated flue gas containing O{sub 2}. In Task 3, we synthesized a few EDTA polymer analogs. We also began scaled up synthesis of Co(II)-phthalocyanine for use in Task 5. In Task 4, we performed experiments for measuring distribution coefficients (m{sub i}) Of SO{sub 2} between aqueous and organic phases. This was done using the liquor regenerating apparatus described in Task 6. In Task 5, we began working with Co(II)-phthalocyanine in the 301 fiber hollow fiber contactor. We also calculated mass transfer coefficients (K{sub olm}) for these runs, and we observed that the gas side resistance dominates mass transfer. In Task 6, in the liquor regeneration apparatus, we observed 90% recovery of SO{sub 2} by DMA from water used as the scrubbing solution. We also calculated the distribution of coefficients (m{sub i}). In Task 7, we established and began implementing a methodology for completing this task.

Bhown, A.S.; Alvarado, D.; Pakala, N.; Ventura, S. [SRI International, Menlo Park, CA (United States)] [SRI International, Menlo Park, CA (United States); Sirkar, K.K.; Majumdar, S.; Bhaumick, D. [New Jersey Inst. of Tech., Newark, NJ (United States)] [New Jersey Inst. of Tech., Newark, NJ (United States)

1994-03-01T23:59:59.000Z

295

Method of and apparatus for removing sulfur oxides from exhaust gases formed by combustion  

SciTech Connect (OSTI)

A process is described for removing sulfur oxides from exhaust gas formed by combustion particularly exhaust gas from an electricity generating power plant. The exhaust gas flows through a reaction zone which operates like a spray dryer. A purifying liquor consisting of an aqueous solution of sodium carbonate and/or sodium bicarbonate is sprayed into the reaction zone, in which the heat content of the exhaust gases causes virtually all of the water content of the purifying liquor to be evaporated. The exhaust gas is subsequently passed through a filter. Anhydrous solids are withdrawn from the reaction zone and the filter and contain at least 75% of sodium sulfite, sodium sulfate and sodium chloride and are processed to form sodium carbonate. To that end the solids are dissolved and sulfite is oxidized to form sulfate so that a solution that contains sodium sulfate and sodium chloride is formed. The sulfate is separated from that solution and the remaining solution is used in the recovery of sodium carbonate by the solvay process.

Voeste, T.

1981-01-27T23:59:59.000Z

296

Constitutive Model for the Time-Dependent Mechanical Behavior of 430 Stainless Steel and FeCrAlY Foams in Sulfur-Bearing Environments  

SciTech Connect (OSTI)

The mechanical behavior of 430 stainless steel and pre-oxidized FeCrAlY open-cell foam materials of various densities was evaluated in compression at temperatures between 450 C and 600 C in an environment containing hydrogen sulfide and water vapor. Both materials showed negligible corrosion due to the gaseous atmosphere for up to 168 hours. The monotonic stress-strain response of these materials was found to be dependent on both the strain rate and their density, and the 430 stainless steel foam materials exhibited less stress relaxation than FeCrAlY for similar experimental conditions. Using the results from multiple hardening-relaxation and monotonic tests, an empirical constitutive equation was derived to predict the stress-strain behavior of FeCrAlY foams as a function of temperature and strain rate. These results are discussed in the context of using these materials in a black liquor gasifier to accommodate the chemical expansion of the refractory liner resulting from its reaction with the soda in the black liquor.

Hemrick, James Gordon [ORNL; Lara-Curzio, Edgar [ORNL

2013-01-01T23:59:59.000Z

297

Sulphidation resistance of composite boiler tube materials  

SciTech Connect (OSTI)

A lab-based testing program was undertaken to generate data to better define the sulphidation resistance of composite tubes installed in the lower-furnace section of black liquor recovery boilers. All composite tube cladding alloys tested were observed to have an acceptable corrosion rate at normal operating temperatures (up to 400 C) in the synthetic lower-furnace gaseous environment tested (1% H{sub 2}S-99% N{sub 2}). This acceptable corrosion resistance is due to the expected formation of a relatively protective chromium-rich inner sulphide scale. An increase in temperature up to 560 C was found to significantly increase the corrosion rate. Of the various alloys tested, Alloy HR11N exhibited the lowest corrosion rate at each of the three temperatures tested. Moreover, the corrosion rate was found not to be strongly dependent on the fabrication route (weld overlay versus co-extruded). To minimize corrosion, operating conditions that promote prolonged exposure to elevated temperatures in the lower-furnace section of black liquor recovery boilers should be avoided, regardless of the type of composite tube installed.

Kish, Joseph [McMaster University; Eng, Philip [FPInnovations; Singbeil, Douglas [FPInnovations; Keiser, James R [ORNL

2008-01-01T23:59:59.000Z

298

Molecular weight and molecular weight distribution of kraft lignins  

SciTech Connect (OSTI)

Kraft lignins are the lignin degradation products from kraft pulping. They are complex, heterogeneous polymers with some polar character. The molecular weight of kraft lignins greatly affect the physical properties of black liquors, and are of primary importance in separation from black liquor and in evaluating potential uses. Several purified kraft lignins from slash pine were analyzed for number average molecular weight by vapor pressure osmometry (VPO), for weight average molecular weight by low angle laser light scattering (LALLS), and for the molecular weight distribution by high temperature size exclusion chromatography (SEC). The lignins were run in tetrahydrofuran (THF), N,N-dimethyl formamide (DMF), DMF with 0.1M LiBr, and pyridine at conditions above the Theta temperature. Experimental methods are discussed. The results show that VPO may be used to determine M[sub n] for kraft lignins if the purity of the lignins and the identity of the impurities are known. LALLS can be used to determine M[sub w] for kraft lignins if measurements are made at or above the Theta temperature of the lignin-solvent pair. SEC should be used at temperatures at, or above, the Theta temperature of the lignin-solvent pair. Size separation is highly dependent on the solvent used, and DMF is a much better solvent than THF for high temperature SEC. Future work using moment resolution procedures to derive an accurate calibration curve are also discussed.

Schmidl, W.; Dong, D.; Fricke, A.L. (Univ. of Florida, Gainesville, FL (United States))

1990-01-01T23:59:59.000Z

299

Aluminum Solubility in Complex Electrolytes - 13011  

SciTech Connect (OSTI)

Predicting aluminum solubility for Hanford and Savannah River waste liquids is very important for their disposition. It is a key mission goal at each Site to leach as much aluminum as practical from sludges in order to minimize the amount of vitrified high level waste. And it is correspondingly important to assure that any soluble aluminum does not precipitate during subsequent decontamination of the liquid leachates with ion exchange. This report shows a very simple and yet thermodynamic model for aluminum solubility that is consistent with a wide range of Al liquors, from simple mixtures of hydroxide and aluminate to over 300 Hanford concentrates and to a set of 19 Bayer liquors for temperatures from 20-100 deg. C. This dimer-dS{sub mix} (DDS) model incorporates an ideal entropy of mixing along with previous reports for the Al dimer, water activities, gibbsite, and bayerite thermodynamics. We expect this model will have broad application for nuclear wastes as well as the Bayer gibbsite process industry. (authors)

Agnew, S.F. [Columbia Energy and Environmental Services, Inc., 1806 Terminal Dr., Richland, WA 99354 (United States)] [Columbia Energy and Environmental Services, Inc., 1806 Terminal Dr., Richland, WA 99354 (United States); Johnston, C.T. [Dept. of Crop, Soil, and Environmental Sciences, Purdue University, West Lafayette, IN 47907 (United States)] [Dept. of Crop, Soil, and Environmental Sciences, Purdue University, West Lafayette, IN 47907 (United States)

2013-07-01T23:59:59.000Z

300

Selenium Speciation and Management in Wet FGD Systems  

SciTech Connect (OSTI)

This report discusses results from bench- and pilot-scale simulation tests conducted to determine the factors that impact selenium speciation and phase partitioning in wet FGD systems. The selenium chemistry in wet FGD systems is highly complex and not completely understood, thus extrapolation and scale-up of these results may be uncertain. Control of operating parameters and application of scrubber additives have successfully demonstrated the avoidance or decrease of selenite oxidation at the bench and pilot scale. Ongoing efforts to improve sample handling methods for selenium speciation measurements are also discussed. Bench-scale scrubber tests explored the impacts of oxidation air rate, trace metals, scrubber additives, and natural limestone on selenium speciation in synthetic and field-generated full-scale FGD liquors. The presence and concentration of redox-active chemical species as well as the oxidation air rate contribute to the oxidation-reduction potential (ORP) conditions in FGD scrubbers. Selenite oxidation to the undesirable selenate form increases with increasing ORP conditions, and decreases with decreasing ORP conditions. Solid-phase manganese [Mn(IV)] appeared to be the significant metal impacting the oxidation of selenite to selenate. Scrubber additives were tested for their ability to inhibit selenite oxidation. Although dibasic acid and other scrubber additives showed promise in early clear liquor (sodium based and without calcium solids) bench-scale tests, these additives did not show strong inhibition of selenite oxidation in tests with higher manganese concentrations and with slurries from full-scale wet FGD systems. In bench-tests with field liquors, addition of ferric chloride at a 250:1 iron-to-selenium mass ratio sorbed all incoming selenite to the solid phase, although addition of ferric salts had no impact on native selenate that already existed in the field slurry liquor sample. As ORP increases, selenite may oxidize to selenate more rapidly than it sorbs to ferric solids. Though it was not possible to demonstrate a decrease in selenium concentrations to levels below the project?¢????s target of 50 ???µg/L during pilot testing, some trends observed in bench-scale testing were evident at the pilot scale. Specifically, reducing oxidation air rate and ORP tends to either retain selenium as selenite in the liquor or shift selenium phase partitioning to the solid phase. Oxidation air flow rate control may be one option for managing selenium behavior in FGD scrubbers. Units that cycle load widely may find it more difficult to impact ORP conditions with oxidation air flow rate control alone. Because decreasing oxidation air rates to the reaction tank showed that all ?¢????new?¢??? selenium reported to the solids, the addition of ferric chloride to the pilot scrubber could not show further improvements in selenium behavior. Ferric chloride addition did shift mercury to the slurry solids, specifically to the fine particles. Several competing pathways may govern the reporting of selenium to the slurry solids: co-precipitation with gypsum into the bulk solids and sorption or co-precipitation with iron into the fine particles. Simultaneous measurement of selenium and mercury behavior suggests a holistic management strategy is best to optimize the fate of both of these elements in FGD waters. Work conducted under this project evaluated sample handling and analytical methods for selenium speciation in FGD waters. Three analytical techniques and several preservation methods were employed. Measurements of selenium speciation over time indicated that for accurate selenium speciation, it is best to conduct measurements on unpreserved, filtered samples as soon after sampling as possible. The capital and operating costs for two selenium management strategies were considered: ferric chloride addition and oxidation air flow rate control. For ferric chloride addition, as migh

Searcy, K.; Richardson, M.; Blythe, G.; Wallschlaeger, D.; Chu, P.; Dene, C.

2012-02-29T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Use of solvent extraction technique in Brazilian uranium mills - an overview  

SciTech Connect (OSTI)

Solvent extraction has been applied to uranium-concentrate production in Brazil. At the first plant, uranium minerals associated with Zr and Mo were acid leached. Extraction was carried out by a mixture of Alamine 336 and Alamine 304, followed by selective Zr, U, and Mo stripping. At the currently operating facilities, a single U mineral is processed by acid heap leaching. Uranium is extracted with Alamine 336 and stripped with NaCl solution. As all water is recycled, chloride contents in the liquor have increased, causing detrimental effects to the extraction process. The current plant operating conditions and the improvements arisen from the research developed to solve these problems are presented. (authors)

Gomiero, Luiz A. [Industrias Nucleares do Brasil S/A-INB, Unidade de Caetite, P.0. Box 7, 46400-000, Caetite, BA (Brazil); Morais, Carlos A. [Centro de Desenvolvimento da Tecnologia Nuclear CDTN/CNEN, Rua Mario Werneck, s/n, Campus da UFMG, Pampulha, 30123-970, Belo Horizonte, MG (Brazil)

2008-07-01T23:59:59.000Z

302

Electric Power Research Institute, High Sulfur Test Center report to the Steering Committee, March 1994. [Monthly report  

SciTech Connect (OSTI)

Operations and maintenance continued this month at the Electric Power Research Institute`s High Sulfur Test Center. The Suncor Limestone Reagent and Dewatering tests were completed on the Pilot unit this month. As this test block ended, the Pilot unit was modified for the High Velocity Scrubbing tests. This testing began on March 28, 1994 with test PHV-AN. As Phase II of the Mini-Pilot Clear Liquor Scrubbing test block was completed this month, the unit was taken off-line. Testing on the Cold-Side Selective Catalytic Reduction (SCR) unit continued this month as ammonia slip measurements were conducted. Catalyst material from the reactor was inspected and sampled during a scheduled outage this month in preparation for a low temperature test block.

Not Available

1994-08-01T23:59:59.000Z

303

Materials selection for kraft batch digesters  

SciTech Connect (OSTI)

Several candidate materials were evaluated by corrosion testing in autoclaves containing white and black liquors for batch digesters. The relationship between corrosion rate and corrosion potential was determined for ASTM SA516-Grade 70 carbon steel, UNS S30403 (Type 304L) austenitic stainless steel, UNS S31803 (2205) and UNS S32550 (2605) duplex stainless steels, and two stainless steel weld overlays, applied by the GMAW (gas metal arc welding) and SAW (submerged arc welding) processes. The tests revealed that SA516-Grade 70 carbon steel and type 304L stainless steel can experience high rates of corrosion. For the duplex stainless steels and weld overlays, corrosion resistance improved with chromium content. A chromium content of at least 25% was found to be necessary for good corrosion resistance.

Wensley, A. [Bacon Donaldson Consulting Engineers, Richmond, British Columbia (Canada); Moskal, M. [Stone Container Corp., Burr Ridge, IL (United States); Wilton, W. [Stone-Consolidated Corp., Fort Frances, Ontario (Canada)

1997-08-01T23:59:59.000Z

304

Thermal Behavior of Floor Tubes in a Kraft Recovery Boiler  

SciTech Connect (OSTI)

The temperatures of floor tubes in a slope-floored black liquor recovery boiler were measured using an array of thermocouples located on the tube crowns. It was found that sudden, short duration temperature increases occurred with a frequency that increased with distance from the spout wall. To determine if the temperature pulses were associated with material falling from the convective section of the boiler, the pattern of sootblower operation was recorded and compared with the pattern of temperature pulses. During the period from September, 1998, through February, 1999, it was found that more than 2/3 of the temperature pulses occurred during the time when one of the fast eight sootblowers, which are directed at the back of the screen tubes and the leading edge of the first superheater bank, was operating.

Barker, R.E.; Choudhury, K.A.; Gorog, J.P.; Hall, L.M.; Keiser, J.R.; Sarma, G.B.

1999-09-12T23:59:59.000Z

305

Low Odor, High Yield Kraft Pulping  

SciTech Connect (OSTI)

In laboratory cooks pure oxygen was profiled into the circulation line of a batch digester during two periods of the cooking cycle: The first injection occurred during the heating steps for the purpose of in-situ generation of polysulfide. This chip treatment was studied to explore stabilization against alkaline induced carbohydrate peeling and to increase pulp yield. Under optimum conditions small amounts of polysulfide were produced with yield increase of about 0.5% These increases fell below earlier reports suggesting that unknown differences in liquor composition may influence the relative amounts of polysulfide and thiosulfate generated during the oxidation. Consequently, further studies are required to understand the factors that influence the ratios of those two sulfur species.

W.T. McKean

2000-12-15T23:59:59.000Z

306

A Flexural Mode Tuning Technique for Membraned Boiler Tubing  

SciTech Connect (OSTI)

Corrosion of tubing used in black-liquor recovery boilers is a major concern in all pulp and paper mills. Extensive corrosion in recovery boiler tubes can result in a significant safety and environmental hazard. Considerable plant resources are expended to inspect recovery boiler tubing. Currently, visual and ultrasonic inspections are primarily used during the annual maintenance shutdown to monitor corrosion rates and cracking of tubing. This project is developing guided acoustic waves for use on recovery boiler tubing. The feature of this acoustic technique is its cost-effectiveness in inspecting long lengths of tubes from a single inspection point. A piezoelectric or electromagnetic transducer induces guided waves into the tubes. The transducer detects fireside defects from the cold side or fireside of the tube. Cracking and thinning on recovery boiler tubes have been detected with this technique in both laboratory and field applications.

Quarry, M J; Chinn, D J; Rose, J L

2005-03-21T23:59:59.000Z

307

Application of a fluidized bed combustor to the DARS process  

SciTech Connect (OSTI)

Australian Paper has built the world`s first and only operational Direct Alkali Recovery System (DARS) to recover caustic soda for a soda AQ chemical pulp mill. At the heart of the DARS process, concentrated spent pulping liquor is burnt in a fluidized bed. The bed material is made up of coarse, dense iron oxide pellets which require a high fluidizing velocity. Bubbling is violent and gives robust fluidization of the iron and sodium compounds. The plant suffered a protracted startup because of equipment failures, air flow instability problems, and process and equipment design errors. A large amount of post construction development work was required. This paper discusses the experiences and knowledge gained in adapting a fluidized bed to the DARS process.

Scott-Young, R.E. [Australian Paper, Burnie, Tasmania (Australia). Pulp Mill and Services Unit

1995-12-31T23:59:59.000Z

308

Superheater Corrosion Produced By Biomass Fuels  

SciTech Connect (OSTI)

About 90% of the world's bioenergy is produced by burning renewable biomass fuels. Low-cost biomass fuels such as agricultural wastes typically contain more alkali metals and chlorine than conventional fuels. Although the efficiency of a boiler's steam cycle can be increased by raising its maximum steam temperature, alkali metals and chlorine released in biofuel boilers cause accelerated corrosion and fouling at high superheater steam temperatures. Most alloys that resist high temperature corrosion protect themselves with a surface layer of Cr{sub 2}O{sub 3}. However, this Cr{sub 2}O{sub 3} can be fluxed away by reactions that form alkali chromates or volatilized as chromic acid. This paper reviews recent research on superheater corrosion mechanisms and superheater alloy performance in biomass boilers firing black liquor, biomass fuels, blends of biomass with fossil fuels and municipal waste.

Sharp, William (Sandy) [SharpConsultant] [SharpConsultant; Singbeil, Douglas [FPInnovations] [FPInnovations; Keiser, James R [ORNL] [ORNL

2012-01-01T23:59:59.000Z

309

Magnet options for sensors for the pulp and paper industry  

SciTech Connect (OSTI)

The Lawrence Berkeley National Laboratory (LBNL) has been developing sensors for the pulp and paper industry that uses a magnetic field. The applications for magnetic sensors that have studied include (1) sensors for the measurement of the water and ice content of wood chips entering the pulping mill, (2) sensors for measuring the water content and other constituents of the black liquor leaving the paper digester, and (3) sensors for measuring paper thickness and water content as the paper is being processed. These tasks can be done using nuclear magnetic resonance (NMR). The magnetic field used for doing the NMR can come from either permanent magnets or superconducting magnets. The choice of the magnet is dependent on a number of factors, which include the size of the sample and field strength needed to do the sensing task at hand. This paper describes some superconducting magnet options that can be used in the pulp and paper industry.

Green, M.A.; Barale, P.J.; Fong, C.G.; Luft, P.A.; Reimer, J.A.; Yahnke, M.S.

2001-05-05T23:59:59.000Z

310

Process for coating tungsten carbide with cobalt metal  

SciTech Connect (OSTI)

A process is described for coating tungsten carbide with cobalt metal, the process comprising: (a) forming an aqueous slurry of tungsten carbide having a particle size of no greater than - 100 mesh, and zinc metal powder; (b) adding ammonia to the slurry with the amount of the ammonia being sufficient so that the slurry is basic after the subsequent addition of cobalt chloride in step c; (c) adding to the resulting ammoniated slurry, a solution of cobalt chloride with agitation, to form a coating of partially reduced cobalt on the tungsten carbide; (d) removing the resulting cobalt coated tungsten carbide from the resulting liquor; and (e) heating the cobalt coated tungsten carbide in a reducing atmosphere to effect the essentially complete reduction of the cobalt and to produce a cobalt metal coating on the tungsten carbide, the coating making up no greater than about 15% of weight of the tungsten carbide.

Ritsko, J.E.; Lee, J.S.

1989-01-31T23:59:59.000Z

311

Method for producing hydrocarbon and alcohol mixtures. [Patent application  

DOE Patents [OSTI]

It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

Compere, A.L.; Googin, J.M.; Griffith, W.L.

1980-12-01T23:59:59.000Z

312

Improved Recovery Boiler Performance Through Control of Combustion, Sulfur, and Alkali Chemistry  

SciTech Connect (OSTI)

This project involved the following objectives: 1. Determine black liquor drying and devolatilization elemental and total mass release rates and yields. 2. Develop a public domain physical/chemical kinetic model of black liquor drop combustion, including new information on drying and devolatilization. 3. Determine mechanisms and rates of sulfur scavenging in recover boilers. 4. Develop non-ideal, public-domain thermochemistry models for alkali salts appropriate for recovery boilers 5. Develop data and a one-dimensional model of a char bed in a recovery boiler. 6. Implement all of the above in comprehensive combustion code and validate effects on boiler performance. 7. Perform gasification modeling in support of INEL and commercial customers. The major accomplishments of this project corresponding to these objectives are as follows: 1. Original data for black liquor and biomass data demonstrate dependencies of particle reactions on particle size, liquor type, gas temperature, and gas composition. A comprehensive particle submodel and corresponding data developed during this project predicts particle drying (including both free and chemisorbed moisture), devolatilization, heterogeneous char oxidation, char-smelt reactions, and smelt oxidation. Data and model predictions agree, without adjustment of parameters, within their respective errors. The work performed under these tasks substantially exceeded the original objectives. 2. A separate model for sulfur scavenging and fume formation in a recovery boiler demonstrated strong dependence on both in-boiler mixing and chemistry. In particular, accurate fume particle size predictions, as determined from both laboratory and field measurements, depend on gas mixing effects in the boilers that lead to substantial particle agglomeration. Sulfur scavenging was quantitatively predicted while particle size required one empirical mixing factor to match data. 3. Condensed-phase thermochemistry algorithms were developed for salt mixtures and compared with sodium-based binary and higher order systems. Predictions and measurements were demonstrated for both salt systems and for some more complex silicate-bearing systems, substantially exceeding the original scope of this work. 4. A multi-dimensional model of char bed reactivity developed under this project demonstrated that essentially all reactions in char beds occur on or near the surface, with the internal portions of the bed being essentially inert. The model predicted composition, temperature, and velocity profiles in the bed and showed that air jet penetration is limited to the immediate vicinity of the char bed, with minimal impact on most of the bed. The modeling efforts substantially exceeded the original scope of this project. 5. Near the completion of this project, DOE withdrew the BYU portion of a multiparty agreement to complete this and additional work with no advanced warning, which compromised the integration of all of this material into a commercial computer code. However, substantial computer simulations of much of this work were initiated, but not completed. 6. The gasification modeling is nearly completed but was aborted near its completion according to a DOE redirection of funds. This affected both this and the previous tasks.

Baxter, Larry L.

2008-06-09T23:59:59.000Z

313

Recovery Boiler Superheater Ash Corrosion Field Study  

SciTech Connect (OSTI)

With the trend towards increasing the energy efficiency of black liquor recovery boilers operated in North America, there is a need to utilize superheater tubes with increased corrosion resistance that will permit operation at higher temperatures and pressures. In an effort to identify alloys with improved corrosion resistance under more harsh operating conditions, a field exposure was conducted that involved the insertion of an air-cooled probe, containing six candidate alloys, into the superheater section of an operating recovery boiler. A metallographic examination, complete with corrosion scale characterization using EMPA, was conducted after a 1,000 hour exposure period. Based on the results, a ranking of alloys based on corrosion performance was obtained.

Keiser, James R [ORNL] [ORNL; Kish, Joseph [McMaster University] [McMaster University; Singbeil, Douglas [FPInnovations] [FPInnovations

2010-01-01T23:59:59.000Z

314

Method for recovering and using lignin in adhesive resins by extracting demethylated lignin  

DOE Patents [OSTI]

Lignin, or a lignin derived material, which has been significantly demethylated (e.g., the demethylated lignin found in the raffinate produced as a by-product of dimethyl sulfide production which can be carried out using the spent liquor from wood pulping operations) can be isolated by a process wherein an organic solvent is added to a lignin-containing aqueous solution. The organic solvent is typically a polar, and at least a partially water-immiscible substance such as, for example, ethyl acetate. The resulting lignin-containing aqueous solution/organic solvent mixture is acidified to produce a water layer which is discarded and an organic solvent layer which contains the demethylated lignin. Upon its recovery, the demethylated lignin is dissolved in an alkaline solution to which an aldehyde source is added to produce a resol-type resin. The aldehyde source may be formaldehyde in solution, paraformaldehyde, hexamethylenetetramine, or other aldehydes including acetaldehyde, furfural, and their derivatives.

Schroeder, Herbert A. (Ft. Collins, CO)

1991-01-01T23:59:59.000Z

315

Method for recovering and using lignin in adhesive resins by extracting demethylated lignin  

DOE Patents [OSTI]

Lignin, or a lignin derived material, which has been significantly demethylated (e.g., the demethylated lignin found in the raffinate produced as a by-product of dimethyl sulfide production which can be carried out using the spent liquor from wood pulping operations) can be isolated by a process wherein an organic solvent is added to a lignin-containing aqueous solution. The organic solvent is typically a polar, and at least a partially water-immiscible substance such as, for example, ethyl acetate. The resulting lignin-containing aqueous solution/organic solvent mixture is acidified to produce a water layer which is discarded and an organic solvent layer which contains the demethylated lignin. Upon its recovery, the demethylated lignin is preferably dried and stored until it is used (along with an alkali, an aldehyde and an adhesive filler) in compounding an adhesive of the type generally used in the manufacture of plywood.

Schroeder, Herbert A. (Ft. Collins, CO)

1991-01-01T23:59:59.000Z

316

Method for recovering and using lignin in adhesive resins  

DOE Patents [OSTI]

Lignin, or a lignin derived material, which has been significantly demethylated (e.g., the demethylated lignin found in the raffinate produced as a by-product of dimethyl sulfide production which can be carried out using the spent liquor from wood pulping operations) can be isolated by a process wherein an organic solvent is added to a lignin-containing aqueous solution. The organic solvent is typically a polar, and at least a partially water-immiscible substance such as, for example, ethyl acetate. The resulting lignin-containing aqueous solution/organic solvent mixture is acidified to produce a water layer which is discarded and an organic solvent layer which contains the demethylated lignin. Upon its recovery, the demethylated lignin is dissolved in an alkaline solution to which an aldehyde source is added to produce a resol-type resin. The aldehyde source may be formaldehyde in solution, paraformaldehyde, hexamethylenetetramine, or other aldehydes including acetaldehyde, furfural, and their derivatives.

Schroeder, Herbert A. (Ft. Collins, CO)

1993-01-01T23:59:59.000Z

317

Preliminary feasibility study of pulping catalyst production from lignin  

SciTech Connect (OSTI)

A preliminary evaluation of the economic feasibility of preparing anthraquinone, a pulping catalyst, from readily available lignin has been performed. The proposed process begins with a fractionation of lignin from a black liquor stream by means of a supercritical fluid or conventional solvent extraction to give a low molecular weight fraction conductive to further chemical treatment. This fraction is sequentially oxidized with H{sub 2}O{sub 2}, treated with a diene and dehydrogenated to give anthraquinone. The cost of the proposed process is most dependent on the overall yield of the chemical processing steps with a smaller contribution noted for lignin processing. The projections indicate that anthraquinone could be produced for as low as $1.00--$1.25/lb using this process. Details of the process, chemical reactions and calculations are included.

Power, A.J. (Power (Arthur J.) and Associates, Boulder, CO (USA)); Bozell, J.J.; Chum, H.L. (Solar Energy Research Inst., Golden, CO (USA))

1989-11-01T23:59:59.000Z

318

Advanced ThioClear process testing. Final report  

SciTech Connect (OSTI)

Wet scrubbing is the leading proven commercial post-combustion FGD technology available to meet the sulfur dioxide reductions required by the Clean Air Act Amendments. To reduce costs associated with wet FGD, Dravo Lime Company has developed the ThioClear process. ThioClear is an ex-situ forced oxidation magnesium-enhanced lime FGD process. ThioClear process differs from the conventional magnesium-enhanced lime process in that the recycle liquor has minimal suspended solids and the by-products are wallboard quality gypsum and magnesium hydroxide, an excellent reagent for water treatment. The process has demonstrated sulfur dioxide removal efficiencies of +95% in both a vertical spray scrubber tower and a horizontal absorber operating at gas velocities of 16 fps, respectively. This report details the optimization studies and associated economics from testing conducted at Dravo Lime Company`s pilot plant located at the Miami Fort Station of the Cincinnati Gas and Electric Company.

Lani, B.

1998-03-01T23:59:59.000Z

319

Recovery of yttrium from cathode ray tubes and lamps fluorescent powders: experimental results and economic simulation  

SciTech Connect (OSTI)

Highlights: Fluorescent powder of lamps. Fluorescent powder of cathode ray rubes. Recovery of yttrium from fluorescent powders. Economic simulation for the processes to recover yttrium from WEEE. - Abstract: In this paper, yttrium recovery from fluorescent powder of lamps and cathode ray tubes (CRTs) is described. The process for treating these materials includes the following: (a) acid leaching, (b) purification of the leach liquors using sodium hydroxide and sodium sulfide, (c) precipitation of yttrium using oxalic acid, and (d) calcinations of oxalates for production of yttrium oxides. Experimental results have shown that process conditions necessary to purify the solutions and recover yttrium strongly depend on composition of the leach liquor, in other words, whether the powder comes from treatment of CRTs or lamp. In the optimal experimental conditions, the recoveries of yttrium oxide are about 95%, 55%, and 65% for CRT, lamps, and CRT/lamp mixture (called MIX) powders, respectively. The lower yields obtained during treatments of MIX and lamp powders are probably due to the co-precipitation of yttrium together with other metals contained in the lamps powder only. Yttrium loss can be reduced to minimum changing the experimental conditions with respect to the case of the CRT process. In any case, the purity of final products from CRT, lamps, and MIX is greater than 95%. Moreover, the possibility to treat simultaneously both CRT and lamp powders is very important and interesting from an industrial point of view since it could be possible to run a single plant treating fluorescent powder coming from two different electronic wastes.

Innocenzi, V., E-mail: valentina.innocenzi1@univaq.it; De Michelis, I.; Ferella, F.; Vegli, F.

2013-11-15T23:59:59.000Z

320

Correlation of Process Data and Electrocheical Noise to Assess Kraft Digester Corrosion: Second Year at Spring Grove  

SciTech Connect (OSTI)

Electrochemical noise (EN) probes were deployed in the carbon steel continuous kraft digester at Spring Grove at four locations and at one location in the bottom cone of the associated flash tank for a second consecutive year of a corrosion study. The probes contained dual electrodes of 309LSi stainless steel overlay--representing a field repair material applied to a portion of the vessel--and dual electrodes of 312 stainless steel overlay. Current and potential noise, the temperature at each probe location, and the value of 23 process parameters (flow rates, liquor chemistry, etc.) were again monitored continuously for a period of almost one year. Historical vessel inspection data and post-test evaluation of the probe components were used to assess/compare EN corrosion activity with physical changes in wall thickness and corrosion patterns on the digester shell. In addition, attempts were made to correlate EN activity from each electrode type with process parameters. The results indicate the corrosion conditions aggressive to mild steel persist within the digester, as post-test inspection of the vessel revealed localized corrosion of mild steel in locations previously free of attack. Further, there was evidence that the depth of localized attack of exposed steel had increased in some locations. Nevertheless, the stainless steel overlay in the digester was essentially immune to corrosion, as evidenced by retained surface relief and heat tint associated with the original deposition process. The 309LSi electrodes also appeared visually pristine, and post-exposure metallographic examination of the 309LSi electrode materials revealed no attack. The 312 electrode materials were similar in appearance, but exhibited very minor interdendritic attack over the exposed surface. The silver electrodes in the probes were consumed (to Ag{sub 2}S) to variable degree over the course of the exposure indicating a useful life of not more than a year in digester service in this vessel. Since the stainless steel overlay electrodes were immune to corrosion during the exposure, the current and potential noise activity on these probes is likely related to redox processes on the electrode surfaces. Analysis of this activity as a function of position (and year) in the vessel suggests that redox chemistry/conditions vary by a significant amount on a consistent basis--even on opposite sides of the vessel at the same elevation--and that these differences are not identified by process parameters tracked at the mill. These variable environmental conditions (flow, temperature, liquor chemistry) appear to have little effect on stainless steel overlays under evaluation, but apparently can be quite corrosive to steel as determined in the initial study in the digester at Spring Grove. With the exception of start-up and shutdown activity, including brief upsets for ''hanging columns'' or brief maintenance periods, no regular correlation was observed between tracked process variables and EN activity on any of the probes. In combination with the variable redox activity, this result suggests that the liquor sampling and flow data compiled at the mill do not represent the corrosion conditions in the vessel particularly well.

Pawel, SJ

2004-04-27T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

In situ exploitation of deep set porphyry ores  

SciTech Connect (OSTI)

Disclosed is a method of economically exploiting deep set porphyry ore bodies of the type containing metal values such as sulfidic copper, nickel, or uranium minerals and minerals capable of absorbing copper, uranium, and nickel ions. The method involves establishing communication with the ore body through access and recovery wells and passing fluids sequentially therethrough. If necessary, thief zones of as low as 25 to 50 md in igneous rock of 1 to 5 md are prevented from distorting flow, by the injection of a polymeric solution of macromolecules with molecular weights of the order of 5 million along the entire wellbore, the higher permeability zones initially accepting the majority of the flow and being impaired at a much faster rate than the less permeable zones. In a first stage, the permeability of the leaching interval is stimulated as an ammoniated solution of sodium, potassium, or ammonium nitrate or chloride contacts calcium containing minerals to promote ion exchange, resulting in clay contraction or calcium carbonate dissolution. In a second stage, the leaching interval is primed as calcium ion is displaced with an aqueous solution of ammonium salt, a calcium sulfate scale inhibitor, and oxygen gas. In a third stage, a two-phase lixiviant comprising entrained oxygen containing bubbles and an ammoniacal leach liquor having a pH less than 10.5 and less than 1.0 mole/liter ammonia is passed through the leaching interval to solubilize copper, nickel, uranium, and other metal values.

Hard, R.A.; Harvey, W.W.; Lingane, P.J.; Park, W.C.; Redman, M.J.

1981-09-29T23:59:59.000Z

322

Zinc recovery by ultrasound acid leaching of double kiln treated electric arc furnace dust  

SciTech Connect (OSTI)

The need to convert 70,000 tons a year of electric arc furnace (EAF) dust into an environmentally safe or recyclable product has encouraged studies to reclaim zinc from this waste material. Successful characterization of a double-kiln calcine, produced from EAF dust, has shown that the calcine pellets consisted mainly of zinc oxide plates with some iron oxide particles. Preliminary leaching tests using hydrochloric and sulfuric acids indicated that this calcine is suitable for selective ultrasound leaching of zinc. A factorially designed screening test using hydrochloric acid showed that ultrasound significantly lowered iron dissolution and increased zinc dissolution, thus enhancing the selective leaching of zinc. Ultrasound, temperature, air bubbling rate and acidity increased the sulfuric acid selectivity, while fluorosilicic acid was not selective. Reactor characterization through ultrasonic field measurements led to the selection of reactor and ultrasound bath, which were utilized to enhance the selectivity of a laboratory scale sulfuric acid leaching of a double-kiln treated electric arc furnace dust. Results indicated that ultrasonic leaching of this calcine is a satisfactory technique to selectively separate zinc from iron. After further iron removal by precipitation and cementation of nickel, it was possible to electrowin zinc from the leach liquor under common industrial conditions, with current efficiencies from 86% through 92% being observed. Calcine washing showed that a substantial chloride removal is possible, but fluoride ion in the electrolyte caused deposit sticking during electrowinning.

Barrera Godinez, J.A.

1989-01-01T23:59:59.000Z

323

Immobilization of Fast Reactor First Cycle Raffinate  

SciTech Connect (OSTI)

This paper describes the results of work to bring forward the timing for the immobilization of first cycle raffinate from reprocessing fuel from the Dounreay Prototype Fast Reactor (PFR). First cycle raffinate is the liquor which contains > 99% of the fission products separated from spent fuel during reprocessing. Approximately 203 m3 of raffinate from the reprocessing of PFR fuel is held in four tanks at the UKAEA's site at Dounreay, Scotland. Two methods of immobilization of this high level waste (HLW) have been considered: vitrification and cementation. Vitrification is the standard industry practice for the immobilization of first cycle raffinate, and many papers have been presented on this technique elsewhere. However, cementation is potentially feasible for immobilizing first cycle raffinate because the heat output is an order of magnitude lower than typical HLW from commercial reprocessing operations such as that at the Sellafield site in Cumbria, England. In fact, it falls within the upper end of the UK definition of intermediate level waste (ILW). Although the decision on which immobilization technique will be employed has yet to be made, initial development work has been undertaken to identify a suitable cementation formulation using inactive simulant of the raffinate. An approach has been made to the waste disposal company Nirex to consider the disposability of the cemented product material. The paper concentrates on the process development work that is being undertaken on cementation to inform the decision making process for selection of the immobilization method.

Langley, K. F.; Partridge, B. A.; Wise, M.

2003-02-26T23:59:59.000Z

324

Ammonia removal process upgrade to the Acme Steel Coke Plant  

SciTech Connect (OSTI)

The need to upgrade the ammonia removal process at the Acme Steel Coke Plant developed with the installation of the benzene NESHAP (National Emission Standard for Hazardous Air Pollutants) equipment, specifically the replacement of the final cooler. At Acme Steel it was decided to replace the existing open cooling tower type final cooler with a closed loop direct spray tar/water final cooler. This new cooler has greatly reduced the emissions of benzene, ammonia, hydrogen sulfide and hydrogen cyanide to the atmosphere, bringing them into environmental compliance. At the time of its installation it was not fully recognized as to the effect this would have on the coke oven gas composition. In the late seventies the decision had been made at Acme Steel to stop the production of ammonia sulfate salt crystals. The direction chosen was to make a liquid ammonia sulfate solution. This product was used as a pickle liquor at first and then as a liquid fertilizer as more markets were developed. In the fall of 1986 the ammonia still was brought on line. The vapors generated from the operation of the stripping still are directed to the inlet of the ammonia absorber. At that point in time it was decided that an improvement to the cyclical ammonia removal process was needed. The improvements made were minimal yet allowed the circulation of solution through the ammonia absorber on a continuous basis. The paper describes the original batch process and the modifications made which allowed continuous removal.

Harris, J.L. [Acme Steel Co., Chicago, IL (United States). Chicago Coke Plant

1995-12-01T23:59:59.000Z

325

Collector main replacement at Indianapolis Coke  

SciTech Connect (OSTI)

Indianapolis Coke is a merchant coke producer, supplying both foundry and blast furnace coke to the industry. The facility has three coke batteries: two 3 meter batteries, one Wilputte four divided and one Koppers Becker. Both batteries are underjet batteries and are producing 100% foundry coke at a net coking time of 30.6 hours. This paper deals with the No. 1 coke battery, which is a 72 oven, gun fired, 5 meter Still battery. No. 1 battery produces both foundry and blast furnace coke at a net coking rate of 25.4 hours. No. 1 battery was commissioned in 1979. The battery is equipped with a double collector main. Although many renovations have been completed to the battery, oven machinery and heating system, to date no major construction projects have taken place. Deterioration of the collector main was caused in part from elevated levels of chlorides in the flushing liquor, and temperature fluctuations within the collector main. The repair procedures are discussed.

Sickle, R.R. Van

1997-12-31T23:59:59.000Z

326

Enhanced Ethanol Production from De-Ashed Paper Sludge by Simultaneous Saccharification and Fermentation and Simultaneous Saccharification and Co-Fermentation  

SciTech Connect (OSTI)

A previous study demonstrated that paper sludges with high ash contents can be converted to ethanol by simultaneous saccharification and fermentation (SSF) or simultaneous saccharification and co-fermentation (SSCF). High ash content in the sludge, however, limited solid loading in the bioreactor, causing low product concentration. To overcome this problem, sludges were de-ashed before SSF and SSCF. Low ash content in sludges also increased the ethanol yield to the extent that the enzyme dosage required to achieve 70% yield in the fermentation process was reduced by 30%. High solid loading in SSF and SSCF decreased the ethanol yield. High agitation and de-ashing of the sludges were able to restore the part of the yield loss caused by high solid loading. Substitution of the laboratory fermentation medium (peptone and yeast extract) with corn steep liquor did not bring about any adverse effects in the fermentation. Fed-batch operation of the SSCF and SSF using low-ash content sludges was effective in raising the ethanol concentration, achieving 47.8 g/L and 60.0 g/L, respectively.

Kang, L.; Wang, W.; Pallapolu, V. R.; Lee, Y. Y.

2011-11-01T23:59:59.000Z

327

Methane production from ozonated pulp mill effluent  

SciTech Connect (OSTI)

A study was made of the production of methane from desugared spent sulfite liquor (SSL) reacted with ozone. The ozonated SSL was fed continuously to three anaerobic fermenters for three months as the sole source of carbon and energy. The fermenters were inoculated with anaerobic bacteria obtained from sewage sludge and acclimated for 1 month in ozonated SSL prior to continuous fermentation. Chemical and biological parameters such as COD, BOD, total sulfur content, redox potential, pH, fatty acid composition, and methane bacteria populations were monitored to determine changes in the SSL during fermentation. Methane production from ozone-treated SSL averaged 1.7 liters/ liter or 17 ml of CH/sub 4/ produced/gram of volatile solids fed. Fatty acis analysis of fermenter effluent indicated a net production of 58 mM/ liter of acetate during ozonated SSL fermentation. This acetic acid production shows future potential for further fermentation by protein-producing yeast. Although the rate of conversion of volatile solids to CH/sub 4/ in this process was not competitive with domestic or agricultural waste digesters, this study did indicate the potential benefits of ozonating organic wastes for increased methane fermentation yields.

Bremmon, C.E.; Jurgensen, M.F.; Patton, J.T.

1980-07-01T23:59:59.000Z

328

Simplified model for determining local heat flux boundary conditions for slagging wall  

SciTech Connect (OSTI)

In this work, two models for calculating heat transfer through a cooled vertical wall covered with a running slag layer are investigated. The first one relies on a discretization of the velocity equation, and the second one relies on an analytical solution. The aim is to find a model that can be used for calculating local heat flux boundary conditions in computational fluid dynamics (CFD) analysis of such processes. Two different cases where molten deposits exist are investigated: the black liquor recovery boiler and the coal gasifier. The results show that a model relying on discretization of the velocity equation is more flexible in handling different temperature-viscosity relations. Nevertheless, a model relying on an analytical solution is the one fast enough for a potential use as a CFD submodel. Furthermore, the influence of simplifications to the heat balance in the model is investigated. It is found that simplification of the heat balance can be applied when the radiation heat flux is dominant in the balance. 9 refs., 7 figs., 10 tabs.

Bingzhi Li; Anders Brink; Mikko Hupa [Aabo Akademi University, Turku (Finland). Process Chemistry Centre

2009-07-15T23:59:59.000Z

329

Pattern of Thermal Fluctuations in a Recovery Boiler Floor  

SciTech Connect (OSTI)

The floor of a black liquor recovey boiler at a mill in central Canada has experienced cracking and delamination of the composite tubing near the spout wall and deformation of the floor panels that is most severe in the vicinity of the spout wall. One possible explanation for the observed damage is impacts of salt cake falling from the convective section onto the floor. In order to determine if such impacts do occur, strain gauges and thermocouples were installed on the boiler floor in areas where cracking and deformation were most frequent. The data obtained from these instruments indicate that brief, sudden temperature fluctuations do occur, and changes in the strain experienced by the affected tube occur simultaneously. These fluctuations appear to occur less often along the spout wall and more frequently with increasing distance from the wall. The frequency of these temperature fluctuations is insufficient for thermal fatigue to be the sole cause of the cracking observed on the tubes, but the data are consistent with what might be expected from pieces of falling salt cake.

Abdullah, Z.; Gorog, J.P.; Keiser, J.R.; Meyers, L.E.; Swindeman, R.W.

1999-04-25T23:59:59.000Z

330

Test method for the measurement of methanol emissions from stationary sources  

SciTech Connect (OSTI)

Methanol was designated under Title III of the Clean Air Act Amendments of 1990 as a pollutant to be regulated. A test method has been developed for the measurement of methanol emissions from stationary sources. The methanol sampling train (MST) consists of a glass-lined heated probe, two condensate knockout traps, and three sorbent cartridges packed with Anasorb 747. The Anasorb samples were desorbed with a 1:1 mixture of carbon disulfide and N,N-dimethylformamide. All samples were analyzed by gas chromatography with flame ionization detection. Following laboratory testing, field tests of the MST and the National Council of the Paper Industry for Air and Stream Improvement (NCASI) sampling method for methanol were conducted at two pulp and paper mills. In accordance with EPA Methol 301, two pairs of trains were run in parallel for six runs, collecting a total of 24 samples by each method. During each run, half of the trains were spiked with a known amount of methanol. The sampling location at the first test was an inlet vent to a softwood bleach plant scrubber where the methanol concentration was about 30 ppm. A second field test was conducted at the vent of a black liquor oxidation tank where the methanol concentration was about 350 ppm. Samples were shown to be stable for at least 2 weeks after collection.

Pate, B.A.; Peterson, M.R.; Rickman, E.E.; Jayanty, R.K.M.

1994-05-01T23:59:59.000Z

331

Assessment of Gasification-Based Biorefining at Kraft Pulp and Paper Mills in the United States, Part A: Background and Assumptions  

SciTech Connect (OSTI)

Commercialization of black liquor and biomass gasification technologies is anticipated in the 2010-2015 time frame, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are already commercially established in the gas-to-liquids or coal-to-liquids industries. This set of two papers describes key results from a major assessment of the prospective energy, environmental, and financial performance of commercial gasification-based biorefineries integrated with kraft pulp and paper mills [1]. Seven detailed biorefinery designs were developed for a reference mill in the southeastern United States, together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which could be refined to vehicle fuels at an existing petroleum refinery), dimethyl ether (a diesel engine fuel or propane substitute), or an ethanol-rich mixed-alcohol product. This paper describes the key assumptions that underlie the biorefinery designs. Part B will present analytical results.

Larson, E. D.; Consonni, S.; Katofsky, R. E.; Iisa, K.; Frederick, W. J., Jr.

2008-11-01T23:59:59.000Z

332

Guided wave acoustic monitoring of corrosion in recovery boiler tubing  

SciTech Connect (OSTI)

Corrosion of tubing used in black-liquor recovery boilers is a major concern in all pulp and paper mills. Extensive corrosion in recovery boiler tubes can result in a significant safety and environmental hazard. Considerable plant resources are expended to inspect recovery boiler tubing. Currently, visual and ultrasonic inspections are primarily used during the annual maintenance shutdown to monitor corrosion rates and cracking of tubing. This Department of Energy, Office of Industrial Technologies project is developing guided acoustic waves for use on recovery boiler tubing. The feature of this acoustic technique is its cost-effectiveness in inspecting long lengths of tubes from a single inspection point. A piezoelectric or electromagnetic transducer induces guided waves into the tubes. The transducer detects fireside defects from the coldside or fireside of the tube. Cracking and thinning on recovery boiler tubes have been detected with this technique in both laboratory and field applications. This technique appears very promising for recovery boiler tube application, potentially expediting annual inspection of tube integrity.

Quarry, M J; Chinn, D J

2004-02-19T23:59:59.000Z

333

Pattern of thermal fluctuations in a recovery boiler floor  

SciTech Connect (OSTI)

The floor of a black liquor recovery boiler at a mill in central Canada has experienced cracking and delamination of the composite tubing near the spout wall and deformation of the floor panels that is most severe in the vicinity of the spout wail. One possible explanation for the observed damage is impacts of salt cake falling from the convective section onto the floor. In order to determine if such impacts do occur, strain gauges and thermocouples were installed on the boiler floor in areas where cracking and deformation were most frequent. The data obtained from these instruments indicate that brief, sudden temperature fluctuations do occur, and changes in the strain experienced by-the affected tube occur simultaneously. These fluctuations appear to occur less often along the spout wall and more frequently with increasing distance from the wall. The frequency of these temperature fluctuations is insufficient for thermal fatigue to be the sole cause of the cracking observed on the tubes, but the data are consistent with what might be expected from pieces of falling salt cake.

Keiser, J.R.; Meyers, L.E.; Swindeman, R.W.; Gorog, J.P.; Abdullah, Z.

1999-07-01T23:59:59.000Z

334

Final Report: Guided Acoustic Wave Monitoring of Corrosion in Recovery Boiler Tubing  

SciTech Connect (OSTI)

Corrosion of tubing used in black-liquor recovery boilers is a major concern in all pulp and paper mills. Extensive corrosion in recovery boiler tubes can result in a significant safety and environmental hazard. Considerable plant resources are expended to inspect recovery boiler tubing. Currently, visual and ultrasonic inspections are primarily used during the annual maintenance shutdown to monitor corrosion rates and cracking of tubing. This Department of Energy, Office of Industrial Technologies project is developing guided acoustic waves for use on recovery boiler tubing. The feature of this acoustic technique is its cost-effectiveness in inspecting long lengths of tubes from a single inspection point. A piezoelectric or electromagnetic transducer induces guided waves into the tubes. The transducer detects fireside defects from the cold side or fireside of the tube. Cracking and thinning on recovery boiler tubes have been detected with this technique in both laboratory and field applications. This technique appears very promising for recovery boiler tube application, potentially expediting annual inspection of tube integrity.

Chinn, D J; Quarry, M J; Rose, J L

2005-03-31T23:59:59.000Z

335

Status Report on Studies of Recovery Boiler Composite Floor Tube Cracking  

SciTech Connect (OSTI)

Cracking of the stainless steel layer of co-extruded 304L stainless steel/SA210 Gd A 1 carbon steel black liquor recovery boiler floor tubes has been identified as one of the most serious material problems in the pulp and paper industry. A DOE-funded study was initiated in 1995 with the goal of determining the cause of and possible solutions to this cracking problem. These studies have characterized tube cracking as well as the chemical and thermal environment and stress state of floor tubes. Investigations of possible cracking mechanisms indicate that stress corrosion cracking rather than thermal fatigue is a more likely cause of crack initiation. The cracking mechanism appears to require the presence of hydrated sodium sulfide and is most likely active during shut-downs and/or start-ups. Based on these results and operating experience, certain alloys appear to be more resistant than others to cracking in the floor environment, and certain operating practices appear to significantly lessen the likelihood of cracking. This report is the latest in a series of progress reports presented on this project.

Eng, P.; Frederick, L.A.; Hoffmann, C.M.; Keiser, J.R.; Mahmood, J.; Maziasz, P.J.; Prescott, R.; Sarma, G.B.; Singbeil, D.L.; Singh, P.M.; Swindeman, R.W.; Wang, X.-L.

1999-09-12T23:59:59.000Z

336

Studies of Degraded Smelt Spout Opening Tubes  

SciTech Connect (OSTI)

Co-extruded type 304L stainless steel/SA210 carbon steel tubes have been used on the floors and lower walls of many black liquor recovery boilers to address the wall thinning problem that had been an issue for boiler owners and operators. Use of these tubes greatly reduced the corrosion issue, but corrosion was still sometimes observed and cracking was discovered in some tubes, particularly those that are bent to form the openings for smelt spouts. Because cracks in the opening tubes were sometimes observed to extend a significant distance into the tube wall and because these cracks were found fairly frequently, tubes made from a number of alternate cladding materials were tried in place of the 304L clad opening tubes. This paper describes the results of examinations of spout opening tubes of the standard 304L/carbon steel and of several of the alternate materials that have been tried. In addition to the corrosion and cracking seen in the spout opening tubes, another issue associated with these tubes has been observed. Preferential corrosion of the cap welds is sometimes seen on butt welds attaching the spout opening tubes made with alternate cladding materials to the standard 304L/carbon steel co-extruded wall tubes. Some information on the observations of this corrosion is also included in this paper.

Keiser, James R [ORNL; Kish, Joseph R. [Paprican; Willoughby, Adam W [ORNL; Longmire, Hu Foster [ORNL; Singbeil, Douglas [Paprican

2007-01-01T23:59:59.000Z

337

Fluorescence analyzer for lignin  

SciTech Connect (OSTI)

An apparatus for measuring lignin concentration with time resolved fluorescence in an undiluted wood pulp or black liquor sample, on a real-time, in situ basis is described, comprising: light source means for applying excitation light pulses at a selected wavelength and at known time intervals to the undiluted sample for causing the lignin concentration to produce fluorescent emission light with a fluorescence intensity that monotonically decreases in a quenched fluorescence regime; light detector means for measuring the emission light at the known time intervals and establishing signals indicative thereof; switching means for turning said light detector means on at precise specified time intervals after each excitation light pulse; and signal processing means connected to the light source means and the light detector means for comparing intensities of the emission light from the lignin in the quenched fluorescence regime to the intensities of the excitation light pulses on a time resolved basis for providing a measurement of the lignin concentration in the undiluted sample as a function of the time resolved emission light intensity.

Berthold, J.W.; Malito, M.L.; Jeffers, L.

1993-06-01T23:59:59.000Z

338

Recovery of non-ferrous metals from smelter flue dusts and sludges  

SciTech Connect (OSTI)

A method is described for treating a smelter by-product so as to recover copper, nickel, zinc, an cobalt metal therefrom and convert any arsenic and sulfur in the smelter by-product into non-leachable forms of arsenic and sulfur, the method comprising: (a) mixing the smelter by-product with hydrated lime to form a paste; (b) forming the paste into agglomerates, (c) roasting the agglomerates in air at a temperature sufficient to oxidize the arsenic and sulfur therein and cause said oxidized arsenic and sulfur to react with the lime in the agglomerates to form non-leachable arsenic-containing and sulfur-containing calcium compounds within the roasted agglomerates; and (d) contacting the roasted agglomerates with a basic aqueous lixiviant solution comprising dissolved ammonia and an ammonium salt so as to dissolve copper, nickel, zinc and cobalt from the roasted agglomerates into the lixiviant solution, thereby converting the lixiviant solution to a pregnant liquor enriched in said copper, nickel, zinc and cobalt.

Bartlett, R.W.

1993-08-10T23:59:59.000Z

339

FGD Additives to Segregate and Sequester Mercury in Solid Byproducts - Final Report  

SciTech Connect (OSTI)

Many mercury control strategies for U.S. coal-fired power generating plants involve co-benefit capture of oxidized mercury from flue gases treated by wet flue gas desulfurization (FGD) systems. For these processes to be effective at overall mercury control, the captured mercury must not be re-emitted to the atmosphere or into surface or ground water. The project sought to identify scrubber additives and FGD operating conditions under which mercury re-emissions would decrease and mercury would remain in the liquor and be blown down from the system in the chloride purge stream. After exiting the FGD system, mercury would react with precipitating agents to form stable solid byproducts and would be removed in a dewatering step. The FGD gypsum solids, free of most of the mercury, could then be disposed or processed for reuse as wallboard or in other beneficial reuse. The project comprised extensive bench-scale FGD scrubber tests in Phases I and II. During Phase II, the approaches developed at the bench scale were tested at the pilot scale. Laboratory wastewater treatment tests measured the performance of precipitating agents in removing mercury from the chloride purge stream. Finally, the economic viability of the approaches tested was evaluated.

Searcy, K; Bltyhe, G M; Steen, W A

2012-02-28T23:59:59.000Z

340

Energy minimization of separation processes using conventional/membrane hybrid systems  

SciTech Connect (OSTI)

The purpose of this study was to identify the general principles governing the choice of hybrid separation systems over straight membrane or straight nonmembrane systems and to do so by examining practical applications (process design and economics). Our focus was to examine the energy consumption characteristics and overall cost factors of the membrane and nonmembrane technologies that cause hybrid systems to be preferred over nonhybrid systems. We evaluated four cases studies, chosen on the basis of likelihood of commercial viability of a hybrid system and magnitude of energy savings: (1) propane/propylene separation; (2) removal of nitrogen from natural gas; (3) concentration of Kraft black liquor; and (4)solvent deasphalting. For propane/propylene splitting, the membrane proved to be superior to distillation in both thermodynamic efficiency and processing cost (PC) when the product was 95% pure propylene. However, to produce higher purity products, the membrane alone could not perform the separation, and a membrane/distillation hybrid was required. In these cases, there is an optimum amount of separation to be accomplished by the membrane (expressed as the fraction of the total availability change of the membrane/distillation hybrid that takes place in the membrane and defined as {phi}{sub m}, the thermodynamic extent of separation). Qualitative and quantitative guidelines are discussed with regard to choosing a hybrid system. 54 refs., 66 figs., 36 tabs.

Gottschlich, D.E.; Roberts, D.L. (SRI International, Menlo Park, CA (USA))

1990-09-28T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

The adsorption of gold, palladium and platinum from acidic chloride solutions on mesoporous carbons.  

SciTech Connect (OSTI)

Studies on the adsorption characteristics of gold, palladium and platinum on mesoporous carbon (CMK-3) and sulfur-impregnated mesoporous carbon (CMK-3/S) evaluated the benefits/drawbacks of the presence of a layer of elemental sulfur inside mesoporous carbon structures. Adsorption isotherms collected for Au(III), Pd(II) and Pt(IV) on those materials suggest that sulfur does enhance the adsorption of those metal ions in mildly acidic environment (pH 3). The isotherms collected in 1 M HCl show that the benefit of sulfur disappears due to the competing influence of large concentration of hydrogen ions on the ion-exchanging mechanism of metal ions sorption on mesoporous carbon surfaces. The collected acid dependencies illustrate similar adsorption characteristics for CMK-3 and CMK-3/S in 1-5 M HCl concentration range. Sorption of metal ions from diluted aqueous acidic mixtures of actual leached electronic waste demonstrated the feasibility of recovery of gold from such liquors.

Peter Zalupski; Rocklan McDowell; Guy Dutech

2014-10-01T23:59:59.000Z

342

Evaluation of plasma melter technology for verification of high-sodium content low-level radioactive liquid wastes: Demonstration test No. 4 preliminary test report  

SciTech Connect (OSTI)

This document provides a preliminary report of plasma arc vitrification testing by a vendor in support of the Hanford Tank Waste Remediation System Low-Level Waste (LLW) Vitrification Program. Phase I test conduct included 26 hours (24 hours steady state) of melting of simulated high-sodium low-level radioactive liquid waste. Average processing rate was 4.9 kg/min (peak rate 6.2 kg/min), producing 7330 kg glass product. Free-flowing glass pour point was 1250 C, and power input averaged 1530 kW(e), for a total energy consumption of 19,800 kJ/kg glass. Restart capability was demonstrated following a 40-min outage involving the scrubber liquor heat exchanger, and glass production was continued for another 2 hours. Some volatility losses were apparent, probably in the form of sodium borates. Roughly 275 samples were collected and forwarded for analysis. Sufficient process data were collected for heat/material balances. Recommendations for future work include lower boron contents and improved tuyere design/operation.

McLaughlin, D.F.; Gass, W.R.; Dighe, S.V.; D`Amico, N.; Swensrud, R.L.; Darr, M.F.

1995-01-10T23:59:59.000Z

343

Preparation and Analysis of Biomass Lignins  

SciTech Connect (OSTI)

Lignin, comprised primarily of three randomly polymerized phenylpropenyl monomers, is, arguably, the second most common organic molecule on earth. In current biorefinery applications, lignin is burned, usually in concentrated pulping or hydrolysis liquor, as a source of process steam and both internal and exported electricity. The aromatic content of lignin makes it a potentially attractive feedstock for highly-valued aromatic chemicals, polymers, and carbon products (graphite, activated carbon, and carbon fiber). Revenue from production of lignin-based chemicals could play a major role in biorefinery profitability if cost-effective methods for lignin separation and purification can be developed. This article presents descriptions of methods for assessing and purifying biorefinery lignins so that they can be evaluated for use as feedstocks for production of chemical products. Areas covered are: 1) initial evaluations of as-received lignin samples (visual, microscopic, separable organics), 2) analysis of common contaminants (bulk and filterable ash and particulate contaminants in liquid and dry lignin samples), 3) preparation of lignins for experimental use as chemical feedstocks (prefiltration, filtration using bench-scale chemical apparatus and larger scale bag filters, one-step lignin precipitation, two-step carbohydrate and lignin precipitation, desalting of dry powdered or precipitated lignin, and lyophilization). These methods have been used successfully at bench-scale to produce the 1 50 kg amounts of wood and grass lignins typically required for bench-scale assessment as chemical feedstocks

Compere, A L [ORNL; Griffith, William {Bill} L [ORNL

2009-01-01T23:59:59.000Z

344

Model of penetration of coal boilers and cogeneration in the paper industry  

SciTech Connect (OSTI)

A model has been developed to forecast the penetration of coal boilers and cogeneration of electricity in the paper industry. Given the demand for energy services (process steam and electricity) by the paper industry, the Penetration Model forecasts the demand for purchased fuel and electricity. The model splits the demand for energy service between energy carriers (coal, fuel oil/natural gas, bark, and spent liquor) on the basis of the installed capacity of 16 types of boilers (combinations of four types of energy carriers and four types of throttle conditions). Investment in new boilers is allocated by an empirical distribution function among the 16 types of boilers on the basis of life cycle cost. In the short run (5 years), the Penetration Model has a small price response. The model has a large price response in the long run (30 years). For constant fuel prices, the model forecasts a 19-percent share for coal and a 65-percent share for residual oil in the year 2000. If the real price of oil and gas doubles by the year 2000, the model forecasts a 68-percent share for coal and a 26-percent share for residual oil.

Reister, D.B.

1982-01-01T23:59:59.000Z

345

GASIFICATION FOR DISTRIBUTED GENERATION  

SciTech Connect (OSTI)

A recent emphasis in gasification technology development has been directed toward reduced-scale gasifier systems for distributed generation at remote sites. The domestic distributed power generation market over the next decade is expected to be 5-6 gigawatts per year. The global increase is expected at 20 gigawatts over the next decade. The economics of gasification for distributed power generation are significantly improved when fuel transport is minimized. Until recently, gasification technology has been synonymous with coal conversion. Presently, however, interest centers on providing clean-burning fuel to remote sites that are not necessarily near coal supplies but have sufficient alternative carbonaceous material to feed a small gasifier. Gasifiers up to 50 MW are of current interest, with emphasis on those of 5-MW generating capacity. Internal combustion engines offer a more robust system for utilizing the fuel gas, while fuel cells and microturbines offer higher electric conversion efficiencies. The initial focus of this multiyear effort was on internal combustion engines and microturbines as more realistic near-term options for distributed generation. In this project, we studied emerging gasification technologies that can provide gas from regionally available feedstock as fuel to power generators under 30 MW in a distributed generation setting. Larger-scale gasification, primarily coal-fed, has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries. Commercial-scale gasification activities are under way at 113 sites in 22 countries in North and South America, Europe, Asia, Africa, and Australia, according to the Gasification Technologies Council. Gasification studies were carried out on alfalfa, black liquor (a high-sodium waste from the pulp industry), cow manure, and willow on the laboratory scale and on alfalfa, black liquor, and willow on the bench scale. Initial parametric tests evaluated through reactivity and product composition were carried out on thermogravimetric analysis (TGA) equipment. These tests were evaluated and then followed by bench-scale studies at 1123 K using an integrated bench-scale fluidized-bed gasifier (IBG) which can be operated in the semicontinuous batch mode. Products from tests were solid (ash), liquid (tar), and gas. Tar was separated on an open chromatographic column. Analysis of the gas product was carried out using on-line Fourier transform infrared spectroscopy (FT-IR). For selected tests, gas was collected periodically and analyzed using a refinery gas analyzer GC (gas chromatograph). The solid product was not extensively analyzed. This report is a part of a search into emerging gasification technologies that can provide power under 30 MW in a distributed generation setting. Larger-scale gasification has been used commercially for more than 50 years to produce clean synthesis gas for the refining, chemical, and power industries, and it is probable that scaled-down applications for use in remote areas will become viable. The appendix to this report contains a list, description, and sources of currently available gasification technologies that could be or are being commercially applied for distributed generation. This list was gathered from current sources and provides information about the supplier, the relative size range, and the status of the technology.

Ronald C. Timpe; Michael D. Mann; Darren D. Schmidt

2000-05-01T23:59:59.000Z

346

Systematic evaluation of satellite remote sensing for identifying uranium mines and mills.  

SciTech Connect (OSTI)

In this report, we systematically evaluate the ability of current-generation, satellite-based spectroscopic sensors to distinguish uranium mines and mills from other mineral mining and milling operations. We perform this systematic evaluation by (1) outlining the remote, spectroscopic signal generation process, (2) documenting the capabilities of current commercial satellite systems, (3) systematically comparing the uranium mining and milling process to other mineral mining and milling operations, and (4) identifying the most promising observables associated with uranium mining and milling that can be identified using satellite remote sensing. The Ranger uranium mine and mill in Australia serves as a case study where we apply and test the techniques developed in this systematic analysis. Based on literature research of mineral mining and milling practices, we develop a decision tree which utilizes the information contained in one or more observables to determine whether uranium is possibly being mined and/or milled at a given site. Promising observables associated with uranium mining and milling at the Ranger site included in the decision tree are uranium ore, sulfur, the uranium pregnant leach liquor, ammonia, and uranyl compounds and sulfate ion disposed of in the tailings pond. Based on the size, concentration, and spectral characteristics of these promising observables, we then determine whether these observables can be identified using current commercial satellite systems, namely Hyperion, ASTER, and Quickbird. We conclude that the only promising observables at Ranger that can be uniquely identified using a current commercial satellite system (notably Hyperion) are magnesium chlorite in the open pit mine and the sulfur stockpile. Based on the identified magnesium chlorite and sulfur observables, the decision tree narrows the possible mineral candidates at Ranger to uranium, copper, zinc, manganese, vanadium, the rare earths, and phosphorus, all of which are milled using sulfuric acid leaching.

Blair, Dianna Sue; Stork, Christopher Lyle; Smartt, Heidi Anne; Smith, Jody Lynn

2006-01-01T23:59:59.000Z

347

Evaluation and validation of criticality codes for fuel dissolver calculations  

SciTech Connect (OSTI)

During the past ten years an OECD/NEA Criticality Working Group has examined the validity of criticality safety computational methods. International calculation tools which were shown to be valid in systems for which experimental data existed were demonstrated to be inadequate when extrapolated to fuel dissolver media. The spread of the results in the international calculation amounted to {plus minus} 12,000 pcm in the realistic fuel dissolver exercise n{degrees} 19 proposed by BNFL, and to {plus minus} 25,000 pcm in the benchmark n{degrees} 20 in which fissile material in solid form is surrounded by fissile material in solution. A theoretical study of the main physical parameters involved in fuel dissolution calculations was performed, i.e. range of moderation, variation of pellet size and the fuel double heterogeneity effect. The APOLLO/P{sub IC} method developed to treat latter effect, permits us to supply the actual reactivity variation with pellet dissolution and to propose international reference values. The disagreement among contributors' calculations was analyzed through a neutron balance breakdown, based on three-group microscopic reaction rates solicited from the participants. The results pointed out that fast and resonance nuclear data in criticality codes are not sufficiently reliable. Moreover the neutron balance analysis emphasized the inadequacy of the standard self-shielding formalism (NITAWL in the international SCALE package) to account for {sup 238}U resonance mutual self-shielding in the pellet-fissile liquor interaction. Improvements in the up-dated 1990 contributions, as do recent complementary reference calculations (MCNP, VIM, ultrafine slowing-down CGM calculation), confirm the need to use rigorous self-shielding methods in criticality design-oriented codes. 6 refs., 11 figs., 3 tabs.

Santamarina, A.; Smith, H.J. (CEA Centre d'Etudes Nucleaires de Cadarache, 13 - Saint-Paul-lez-Durance (France)); Whitesides, G.E. (Oak Ridge National Lab., TN (United States))

1991-01-01T23:59:59.000Z

348

Recovery of manganese oxides from spent alkaline and zinccarbon batteries. An application as catalysts for VOCs elimination  

SciTech Connect (OSTI)

Highlights: Manganese oxides were synthesized using spent batteries as raw materials. Spent alkaline and zinccarbon size AA batteries were used. A biohydrometallurgical process was employed to bio-lixiviate batteries. Manganese oxides were active in the oxidation of VOCs (ethanol and heptane). - Abstract: Manganese, in the form of oxide, was recovered from spent alkaline and zinccarbon batteries employing a biohydrometallurgy process, using a pilot plant consisting in: an air-lift bioreactor (containing an acid-reducing medium produced by an Acidithiobacillus thiooxidans bacteria immobilized on elemental sulfur); a leaching reactor (were battery powder is mixed with the acid-reducing medium) and a recovery reactor. Two different manganese oxides were recovered from the leachate liquor: one of them by electrolysis (EMO) and the other by a chemical precipitation with KMnO{sub 4} solution (CMO). The non-leached solid residue was also studied (RMO). The solids were compared with a MnO{sub x} synthesized in our laboratory. The characterization by XRD, FTIR and XPS reveal the presence of Mn{sub 2}O{sub 3} in the EMO and the CMO samples, together with some Mn{sup 4+} cations. In the solid not extracted by acidic leaching (RMO) the main phase detected was Mn{sub 3}O{sub 4}. The catalytic performance of the oxides was studied in the complete oxidation of ethanol and heptane. Complete conversion of ethanol occurs at 200 C, while heptane requires more than 400 C. The CMO has the highest oxide selectivity to CO{sub 2}. The results show that manganese oxides obtained using spent alkaline and zinccarbon batteries as raw materials, have an interesting performance as catalysts for elimination of VOCs.

Gallegos, Mara V., E-mail: plapimu@yahoo.com.ar [Pla.Pi.Mu-Planta Piloto Multipropsito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina); Falco, Lorena R., E-mail: mlfalco@quimica.unlp.edu.ar [Pla.Pi.Mu-Planta Piloto Multipropsito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina); Peluso, Miguel A., E-mail: apelu@quimica.unlp.edu.ar [Centro de Investigacin y Desarrollo en Ciencias Aplicadas, Dr. J. Ronco CINDECA (CONICET CCT La Plata), 47 N257, La Plata, Buenos Aires (Argentina); Sambeth, Jorge E., E-mail: sambeth@quimica.unlp.edu.ar [Centro de Investigacin y Desarrollo en Ciencias Aplicadas, Dr. J. Ronco CINDECA (CONICET CCT La Plata), 47 N257, La Plata, Buenos Aires (Argentina); Thomas, Horacio J. [Pla.Pi.Mu-Planta Piloto Multipropsito, (CICPBA-UNLP) Cno. Centenario y 505, M.B. Gonnet, Buenos Aires (Argentina)

2013-06-15T23:59:59.000Z

349

Sulfur dioxide and nitrogen oxides emissions from U.S. pulp and paper mills, 1980-2005  

SciTech Connect (OSTI)

Estimates of total SO{sub 2} and NOx emissions from U.S. pulp and paper mills were developed from industry-wide surveys conducted at 5-yr intervals from 1980 to 2005. The following conclusions were drawn from these estimates: (1) Total SO{sub 2} emissions from pulp and paper mills were 340,000 t in 2005. Since 1980, SO{sub 2} emissions have decreased steadily. The decline over the 25-yr period was over 60%. Paper production increased by 50% over the same period. (2) Boilers burning coal and oil are the primary source of SO{sub 2} emissions, with minor contributions from black liquor combustion in kraft recovery furnaces and the burning of noncondensable gases in boilers at kraft pulp mills. Factors contributing to the decline in boiler SO{sub 2} emissions include large reductions in residual oil use, recent decreases in coal use, declines in the average sulfur content of residual oil and coal being burned, and increasing use of flue gas desulfurization systems.(3) NOx emissions from pulp and paper mills were 230,000 t in 2005. NOx emissions were fairly constant through 1995, but then declined by 12% in 2000 and an additional 17% between 2000 and 2005. (4) In 2005, boilers accounted for two-thirds of the NOx emissions, and kraft mill sources approximately 30%. Boiler NOx emissions exhibited very little change through 1995, but decreased by one third in the next 10 yr. The lower emissions resulted from declines in fossil fuel use, a reduction in the EPA emission factors for natural gas combustion in boilers without NOx controls, and more widespread use of combustion modifications and add-on NOx control technologies, particularly on coal-fired boilers subject to EPA's NOx SIP call. Total NOx emissions from kraft mill sources changed little over the 25-yr period. 7 refs., 4 figs., 3 tabs.

John E. Pinkerton [National Council of the Paper Industry for Air and Stream Improvement Inc., Research Triangle Park, NC (United States). Air Quality Program

2007-08-15T23:59:59.000Z

350

Briquette comprising caking coal and municipal solid waste  

SciTech Connect (OSTI)

Briquettes of specified geometry and composition are produced to serve as feed material or ''burden'' in a moving-burden gasifier for the production of a synthesis or fuel gas from organic solid waste materials and coal, including especially, the so-called ''caking'' coals, as in the process of copending application number 675,918. The briquettes are formed from a well-blended mixture of shredded organic solid wastes, including especially, municipal solid waste (Msw) or biomass, and crushed caking coal, including coal fines. A binder material may or may not be required, depending on the coal/msw ratio and the compaction pressure employed. The briquettes may be extruded, stamped, or pressed, employing compaction pressures in excess of 1000 psi, and preferably in the range of 2000 to 10,000 psi. The briquettes may be circular, polygonal, or irregular in cross-section; they may be solid, or concentrically perforated to form a hollow cylinder or polygon; they may be formed into saddles, pillows or doughnuts. The ratio of caking coal to shredded municipal solid waste is controlled so that each part of the predominantly cellulosic organic solid waste will be blended with 0.5 to 3.0 parts of crushed coal. Suitable binder materials include dewatered sewage slude (Dss), ''black liquor'' rich in lignin derivatives, black strap molasses, waste oil, and starch. The binder concentration is preferably in the range of 2 to 6 percent. If coals high in sulfur content are to be processed, at least a stoichiometric equivalent of dolomite may be included in the briquette formulation to eliminate a major fraction of the sulfur with the slag.

Schulz, H.W.

1980-09-30T23:59:59.000Z

351

Emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans from various industrial sources  

SciTech Connect (OSTI)

This study characterized the emissions of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) from the stack flue gases of 17 industrial sources, which were classified into 10 categories. The results show that the mean PCDD/PCDF concentration of secondary zinc smelter (Zn-S) and secondary copper smelter (Cu-S) is 2.44 ng international toxic equivalent (I-TEQ)/Nm{sup 3} (N represents normal conditions at 0{sup o}C, 760 mmHg), which was found to be significantly greater than that of industrial waste incinerators (mean concentration = 0.15 ng I-TEQ/Nm{sup 3}). These results imply that the controlling of secondary metallurgical melting processes is more important than industrial waste incineration for the reduction of PCDD/PCDF emissions. The mean emission factors of cement production, Zn-S and Cu-S, are 0.052, 1.99, and 1.73 {mu}g I-TEQ/t product, respectively. The cement plant uses bituminous coal as fuel. For industrial waste incineration, the mean emission factors of waste rubber, waste liquor, waste sludge, industrial waste solid (IWI)-1, IWI-2, IWI-3, and IWI-4 are 0.752, 0.435, 0.760, 6.64, 1.67, 2.38, and 0.094 {mu}g I-TEQ/t feed, respectively. Most of the PCDD/PCDF emission factors established in this study are less than those reported in previous studies, which could be because of the more stringent regulations for PCDD/PCDF emissions in recent years. 20 refs., 1 fig., 7 tabs.

Long-Full Lin; Wen-Jhy Lee; Guo-Ping Chang-Chien [National Cheng Kung University, Tainan (Taiwan). Department of Environmental Engineering, and Sustainable Environment Research Center

2006-12-15T23:59:59.000Z

352

Electric Power Research Institute Environmental Control Technology Center: Report to the Steering Committee, June 1996  

SciTech Connect (OSTI)

Operations and maintenance continued this month at the Electric Power Research Institute`s (EPRI`s) Environmental Control Technology Center (ECTC). Testing for the Hazardous Air Pollutant (HAP) test block was conducted using the 4.0 MW Spray Dryer Absorber System (SDA) and Pulse Jet Fabric Filter (PJFF) - Carbon Injection System. Investigations also continued across the B&W/CHX Heat Exchanger unit, while the 1.0 MW Selective Catalytic Reduction (SCR) unit remained idle this month in a cold-standby mode as monthly inspections were conducted. Pilot Testing Highlights Testing efforts in June were focused on the HAP test block and the Trace Elements Removal (TER) test block. Both programs were conducted on the 4.0 MW wet FGD pilot unit and PJFF unit. The HAP test block was temporarily concluded in June to further review the test data. This program began in March as part of the DOE Advanced Power Systems Program; the mission of this program is to accelerate the commercialization of affordable, high-efficiency, low-emission, coal-fueled electric generating technologies. The 1996 HAP test block focuses on three research areas, including: Catalytic oxidation of vapor-phase elemental mercury; Enhanced particulate-phase HAPs removal by electrostatic charging of liquid droplets; and Enhanced mercury removal by addition of additives to FGD process liquor. The TER test block is part of EPRI`s overall program to develop control technology options for reduction of trace element emissions. This experimental program investigates mercury removal and mercury speciation under different operating conditions.

NONE

1996-06-01T23:59:59.000Z

353

Separation of Mercury from Flue Gas Desulfurization Scrubber Produced Gypsum  

SciTech Connect (OSTI)

Frontier Geosciences (Frontier; FGS) proposed for DOE Grant No. DE-FG02-07ER84669 that mercury control could be achieved in a wet scrubber by the addition of an amendment to the wet-FGD scrubber. To demonstrate this, a bench-scale scrubber and synthetic flue-gas supply was designed to simulate the limestone fed, wet-desulfurization units utilized by coal-fired power plants. Frontier maintains that the mercury released from these utilities can be controlled and reduced by modifying the existing equipment at installations where wet flue-gas desulfurization (FGD) systems are employed. A key element of the proposal was FGS-PWN, a liquid-based mercury chelating agent, which can be employed as the amendment for removal of all mercury species which enter the wet-FGD scrubber. However, the equipment design presented in the proposal was inadequate to demonstrate these functions and no significant progress was made to substantiate these claims. As a result, funding for a Phase II continuation of this work will not be pursued. The key to implementing the technology as described in the proposal and report appears to be a high liquid-to-gas ratio (L/G) between the flue-gas and the scrubber liquor, a requirement not currently implemented in existing wet-FGD designs. It may be that this constraint can be reduced through parametric studies, but that was not apparent in this work. Unfortunately, the bench-scale system constructed for this project did not function as intended and the funds and time requested were exhausted before the separation studies could occur.

Hensman, Carl, E., P.h.D; Baker, Trevor

2008-06-16T23:59:59.000Z

354

Leaching studies for tin recovery from waste e-scrap  

SciTech Connect (OSTI)

Printed circuit boards (PCBs) are the most essential components of all electrical and electronic equipments, which contain noteworthy quantity of metals, some of which are toxic to life and all of which are valuable resources. Therefore, recycling of PCBs is necessary for the safe disposal/utilization of these metals. Present paper is a part of developing Indo-Korean recycling technique consists of organic swelling pre-treatment technique for the liberation of thin layer of metallic sheet and the treatment of epoxy resin to remove/recover toxic soldering material. To optimize the parameters required for recovery of tin from waste PCBs, initially the bench scale studies were carried out using fresh solder (containing 52.6% Sn and 47.3% Pb) varying the acid concentration, temperature, mixing time and pulp density. The experimental data indicate that 95.79% of tin was leached out from solder material using 5.5 M HCl at fixed pulp density 50 g/L and temperature 90 Degree-Sign C in mixing time 165 min. Kinetic studies followed the chemical reaction controlled dense constant size cylindrical particles with activation energy of 117.68 kJ/mol. However, 97.79% of tin was found to be leached out from solder materials of liberated swelled epoxy resin using 4.5 M HCl at 90 Degree-Sign C, mixing time 60 min and pulp density 50 g/L. From the leach liquor of solder materials of epoxy resin, the precipitate of sodium stannate as value added product was obtained at pH 1.9. The Pb from the leach residue was removed by using 0.1 M nitric acid at 90 Degree-Sign C in mixing time 45 min and pulp density 10 g/L. The metal free epoxy resin could be disposed-of safely/used as filling material without affecting the environment.

Jha, Manis Kumar, E-mail: maniskrjha@gmail.com [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Choubey, Pankaj Kumar; Jha, Amrita Kumari; Kumari, Archana [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Lee, Jae-chun, E-mail: jclee@kigam.re.kr [Mineral Resources Research Division, Korea Institute of Geosciences and Mineral Resources, Daejeon 305-350 (Korea, Republic of); Kumar, Vinay [Metal Extraction and Forming Division, National Metallurgical Laboratory (NML), Jamshedpur 831 007 (India); Jeong, Jinki [Mineral Resources Research Division, Korea Institute of Geosciences and Mineral Resources, Daejeon 305-350 (Korea, Republic of)

2012-10-15T23:59:59.000Z

355

Integrated Forest Products Refinery (IFPR)  

SciTech Connect (OSTI)

Pre-extractionkraft studies of hardwoods showed that when extracting about 10% of the wood, the final kraft pulp yield and physical properties could only be maintained at a level similar to that of regular kraft pulp when the final extract pH was close to neutral. This so-called near neutral pre-extraction condition at a level of 10% wood dissolution was achieved by contacting the wood chips with green liquor (GL) at a charge of about 3% (as Na2O on wood) at 160 C for almost 2 hours (or an H-factor of about 800 hrs.). During subsequent kraft cooking of the pre-extracted hardwood chips the effective alkali charge could be reduced by about 3% (as Na2O on wood) and the cooking time shortened relative to that during regular kraft cooking, while still producing the same bleachable grade kappa number as the kraft control pulp. For softwood, no extraction conditions were discovered in the present investigation whereby both the final kraft pulp yield and physical properties could be maintained at a level similar to that of regular softwood kraft pulp. Therefore for hardwoods the near- neutral green liquor pre-extraction conditions do meet the requirements of the IFPR concept, while for softwood, no extraction conditions were discovered which do meet these requirements. Application of simulated industrial GL at an extraction H-factor of about 800 hrs and 3% GL charge in a recirculating digester produced an hardwood extract containing about 4% (on wood) of total anhydro-sugars, 2% of acetic acid, and 1.3% of lignin. Xylan comprised of 80% of the sugars of which about 85% is oligomeric. Since only polymeric hemicelluloses and lignin may be adsorbed on pulp (produced at a yield of about 50% from the original wood), the maximum theoretical yield increase due to adsorption may be estimated as 10% on pulp (or 5% on wood). However, direct application of raw GL hardwood extract for hemicelluloses adsorption onto hardwood kraft pulp led to a yield increase of only about 1% (on pulp). By using the wet-end retention aid guar gum during the adsorption process at a charge of 0.5% on pulp the yield gain may be increased to about 5%. Unfortunately, most of this yield increase is lost during subsequent alkaline treatments in the pulp bleach plant. It was found that by performing the adsorption at alkaline conditions the adsorption loss during alkaline treatment in the bleach plant is mostly avoided. Thus a permanent adsorption yield of about 3 and 1.5% (on pulp) was obtained with addition of guar gum at a charge of 0.5 and 0.1% respectively during adsorption of GL hardwood extract on pre-extracted kraft pulp at optimal conditions of pH 11.5, 90 C for 60 minutes at 5% consistency. The beatability of the adsorbed kraft pulps was improved. Also, significant physical strength improvements were achieved. Further study is needed to determine whether the improvements in pulp yield and paper properties make this an economic IFPR concept. Application of the wood solids of a hot water extract of Acer rubrum wood strands as a substitute for polystyrene used for production of SMC maintained the water adsorption properties of the final product. Further work on the physical properties of the hemicellulose containing SMCs need to be completed to determine the potential of wood extracts for the production of partially renewable SMCs. The discovery of the near-neutral green liquor extraction process for hardwood was formed the basis for a commercial Integrated Biorefinery that will extract hemicelluloses from wood chips to make biofuels and other specialty chemicals. The pulp production process will be maintained as is proposed in the present researched IFBR concept. This Integrated Biorefinery will be constructed by Red Shield Acquisition LLC (RSA) at the Old Town kraft pulp mill in Maine. RSA in collaboration with the University of Maine will develop and commercialize the hemicellulose extraction process, the conversion of the hemicellulose sugars into butanol by fermentation, and the separation of specialty chemicals such as acetic acid fr

van Heiningen, Adriaan R. P.

2010-05-29T23:59:59.000Z

356

Recovery of lithium and cobalt from waste lithium ion batteries of mobile phone  

SciTech Connect (OSTI)

Graphical abstract: Recovery of valuable metals from scrap batteries of mobile phone. - Highlights: Recovery of Co and Li from spent LIBs was performed by hydrometallurgical route. Under the optimum condition, 99.1% of lithium and 70.0% of cobalt were leached. The mechanism of the dissolution of lithium and cobalt was studied. Activation energy for lithium and cobalt were found to be 32.4 kJ/mol and 59.81 kJ/mol, respectively. After metal recovery, residue was washed before disposal to the environment. - Abstract: In view of the stringent environmental regulations, availability of limited natural resources and ever increasing need of alternative energy critical elements, an environmental eco-friendly leaching process is reported for the recovery of lithium and cobalt from the cathode active materials of spent lithium-ion batteries of mobile phones. The experiments were carried out to optimize the process parameters for the recovery of lithium and cobalt by varying the concentration of leachant, pulp density, reductant volume and temperature. Leaching with 2 M sulfuric acid with the addition of 5% H{sub 2}O{sub 2} (v/v) at a pulp density of 100 g/L and 75 C resulted in the recovery of 99.1% lithium and 70.0% cobalt in 60 min. H{sub 2}O{sub 2} in sulfuric acid solution acts as an effective reducing agent, which enhance the percentage leaching of metals. Leaching kinetics of lithium in sulfuric acid fitted well to the chemical controlled reaction model i.e. 1 ? (1 ? X){sup 1/3} = k{sub c}t. Leaching kinetics of cobalt fitted well to the model ash diffusion control dense constant sizes spherical particles i.e. 1 ? 3(1 ? X){sup 2/3} + 2(1 ? X) = k{sub c}t. Metals could subsequently be separated selectively from the leach liquor by solvent extraction process to produce their salts by crystallization process from the purified solution.

Jha, Manis Kumar, E-mail: mkjha@nmlindia.org; Kumari, Anjan; Jha, Amrita Kumari; Kumar, Vinay; Hait, Jhumki; Pandey, Banshi Dhar

2013-09-15T23:59:59.000Z

357

Field Testing of a Wet FGD Additive for Enhanced Mercury Control - Pilot-Scale Test Results  

SciTech Connect (OSTI)

This Topical Report summarizes progress on Cooperative Agreement DE-FC26-04NT42309, ''Field Testing of a Wet FGD Additive.'' The objective of the project is to demonstrate the use of a flue gas desulfurization (FGD) additive, Degussa Corporation's TMT-15, to prevent the reemissions of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project intends to demonstrate that the additive can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine TMT salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project will conduct pilot and full-scale tests of the TMT-15 additive in wet FGD absorbers. The tests are intended to determine required additive dosage requirements to prevent Hg{sup 0} reemissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Power River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, TXU Generation Company LP, Southern Company, and Degussa Corporation. TXU Generation has provided the Texas lignite/PRB co-fired test site for pilot FGD tests, Monticello Steam Electric Station Unit 3. Southern Company is providing the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, as well as the pilot and full-scale jet bubbling reactor (JBR) FGD systems to be tested. A third utility, to be named later, will provide the high-sulfur Eastern bituminous coal full-scale FGD test site. Degussa Corporation is providing the TMT-15 additive and technical support to the test program. The project is being conducted in six tasks. Of the six project tasks, Task 1 involves project planning and Task 6 involves management and reporting. The other four tasks involve field testing on FGD systems, either at pilot or full scale. The four tasks include: Task 2 - Pilot Additive Testing in Texas Lignite Flue Gas; Task 3 - Full-scale FGD Additive Testing in High Sulfur Eastern Bituminous Flue Gas; Task 4 - Pilot Wet Scrubber Additive Tests at Yates; and Task 5 - Full-scale Additive Tests at Plant Yates. This topical report presents the results from the Task 2 and Task 4 pilot-scale additive tests. The Task 3 and Task 5 full-scale additive tests will be conducted later in calendar year 2006.

Gary M. Blythe

2006-03-01T23:59:59.000Z

358

Recovery of yttrium from fluorescent powder of cathode ray tube, CRT: Zn removal by sulphide precipitation  

SciTech Connect (OSTI)

Highlights: Treatment of fluorescent powder of CRT waste. Factorial experimental designs to study acid leaching of fluorescent powder and the purification of leach liquors. Recover of yttrium by precipitation using oxalic acid. Suitable flowsheet to recover yttrium from fluorescent powder. - Abstract: This work is focused on the recovery of yttrium and zinc from fluorescent powder of cathode ray tube (CRT). Metals are extracted by sulphuric acid in the presence of hydrogen peroxide. Leaching tests are carried out according to a 2{sup 2} full factorial plan and the highest extraction yields for yttrium and zinc equal to 100% are observed under the following conditions: 3 M of sulphuric acid, 10% v/v of H{sub 2}O{sub 2} concentrated solution at 30% v/v, 10% w/w pulp density, 70 C and 3 h of reaction. Two series of precipitation tests for zinc are carried out: a 2{sup 2} full factorial design and a completely randomized factorial design. In these series the factors investigated are pH of solution during the precipitation and the amount of sodium sulphide added to precipitate zinc sulphide. The data of these tests are used to describe two empirical mathematical models for zinc and yttrium precipitation yields by regression analysis. The highest precipitation yields for zinc are obtained under the following conditions: pH equal to 22.5% and 1012% v/v of Na{sub 2}S concentrated solution at 10% w/v. In these conditions the coprecipitation of yttrium is of 1520%. Finally further yttrium precipitation experiments by oxalic acid on the residual solutions, after removing of zinc, show that yttrium could be recovered and calcined to obtain the final product as yttrium oxide. The achieved results allow to propose a CRT recycling process based on leaching of fluorescent powder from cathode ray tube and recovery of yttrium oxide after removing of zinc by precipitation. The final recovery of yttrium is 7580%.

Innocenzi, Valentina, E-mail: valentina.innocenzi1@univaq.it [Department of Industrial Engineering and Information and Economy, University of LAquila, Via Giovanni Gronchi n.18, Nucleo Ind.le di Pile, 67100 LAquila (Italy); De Michelis, Ida; Ferella, Francesco [Department of Industrial Engineering and Information and Economy, University of LAquila, Via Giovanni Gronchi n.18, Nucleo Ind.le di Pile, 67100 LAquila (Italy); Beolchini, Francesca [Department of Marine Sciences, Polytechnic Institute of Marche, Via Brecce Bianche, 60131 Ancona (Italy); Kopacek, Bernd [SAT, Austrian Society for Systems Engineering and Automation, Gurkasse 43/2, A-1140 Vienna (Austria); Vegli, Francesco [Department of Industrial Engineering and Information and Economy, University of LAquila, Via Giovanni Gronchi n.18, Nucleo Ind.le di Pile, 67100 LAquila (Italy)

2013-11-15T23:59:59.000Z

359

Final Report, Materials for Industrial Heat Recovery Systems, Tasks 3 and 4 Materials for Heat Recovery in Recovery Boilers  

SciTech Connect (OSTI)

The DOE-funded project on materials for industrial heat recovery systems included four research tasks: materials for aluminum melting furnace recuperator tubes, materials and operational changes to prevent cracking and corrosion of the co-extruded tubes that form primary air ports in black liquor recovery boilers, the cause of and means to prevent corrosion of carbon steel tubes in the mid-furnace area of recovery boilers, and materials and operational changes to prevent corrosion and cracking of recovery boiler superheater tubes. Results from studies on the latter two topics are given in this report while separate reports on results for the first two tasks have already been published. Accelerated, localized corrosion has been observed in the mid-furnace area of kraft recovery boilers. This corrosion of the carbon steel waterwall tubes is typically observed in the vicinity of the upper level of air ports where the stainless clad co-extruded wall tubes used in the lower portion of the boiler are welded to the carbon steel tubes that extend from this transition point or cut line to the top of the boiler. Corrosion patterns generally vary from one boiler to another depending on boiler design and operating parameters, but the corrosion is almost always found within a few meters of the cut line and often much closer than that. This localized corrosion results in tube wall thinning that can reach the level where the integrity of the tube is at risk. Collection and analysis of gas samples from various areas near the waterwall surface showed reducing and sulfidizing gases were present in the areas where corrosion was accelerated. However, collection of samples from the same areas at intervals over a two year period showed the gaseous environment in the mid-furnace section can cycle between oxidizing and reducing conditions. These fluctuations are thought to be due to gas flow instabilities and they result in an unstable or a less protective scale on the carbon steel tubes. Also, these fluctuating air flow patterns can result in deposition of black liquor on the wall tubes, and during periods when deposition is high, there is a noticeable increase in the concentrations of sulfur-bearing gases like hydrogen sulfide and methyl mercaptan. Laboratory studies have shown that chromized and aluminized surface treatments on carbon steel improve the resistance to sulfidation attack. Studies of superheater corrosion and cracking have included laboratory analyses of cracked tubes, laboratory corrosion studies designed to simulate the superheater environment and field tests to study the movement of superheater tubes and to expose a corrosion probe to assess the corrosion behavior of alternate superheater alloys, particularly alloys that would be used for superheaters operating at higher temperatures and higher pressures than most current boilers. In the laboratory corrosion studies, samples of six alternate materials were immersed in an aggressive, low melting point salt mixture and exposed for times up to 336 h, at temperatures of 510, 530 or 560C in an inert or reactive cover gas. Using weight change and results of metallographic examination, the samples were graded on their resistance to the various environments. For the superheater corrosion probe studies, samples of the same six materials were exposed on an air-cooled corrosion probe exposed in the superheater section of a recovery boiler for 1000 h. Post exposure examination showed cracking and/or subsurface attack in the samples exposed at the higher temperatures with the attack being more severe for samples 13 exposed above the first melting temperature of the deposits that collected on the superheater tubes. From these superheater studies, a ranking was developed for the six materials tested. The task addressing cracking and corrosion of primary air port tubes that was part of this project produced results that have been extensively implemented in recovery boilers in North America, the Nordic countries and many other parts of the world. By utilizing these results, boilers ar

Keiser, James R.; Kish, Joseph R.; Singh, Preet M.; Sarma, Gorti B.; Yuan, Jerry; Gorog, J. Peter; Frederick, Laurie A.; Jette, Francois R.; Meisner, Roberta A.; Singbeil, Douglas L.

2007-12-31T23:59:59.000Z

360

Biomass Gasification Research Facility Final Report  

SciTech Connect (OSTI)

While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-03GO13175 and DE-FC36-02GO12024) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. This multi-year effort to develop methods to effectively monitor gaseous species produced in thermochemical process streams resulted in a sampling and analysis approach that is continuous, sensitive, comprehensive, accurate, reliable, economical, and safe. The improved approach for sampling thermochemical processes that GTI developed and demonstrated in its series of field demonstrations successfully provides continuous transport of vapor-phase syngas streams extracted from the main gasification process stream to multiple, commercially available analyzers. The syngas stream is carefully managed through multiple steps to successfully convey it to the analyzers, while at the same time bringing the stream to temperature and pressure conditions that are compatible with the analyzers. The primary principle that guides the sample transport is that throughout the entire sampling train, the temperature of the syngas stream is maintained above the maximum condensation temperature of the vapor phase components of the conveyed sample gas. In addition, to minimize adsorption or chemical changes in the syngas components prior to analysis, the temperature of the transported stream is maintained as hot as is practical, while still being cooled only as much necessary prior to entering the analyzer(s). The successful transport of the sample gas stream to the analyzer(s) is accomplished through the managed combination of four basic gas conditioning methods that are applied as specifically called for by the process conditions, the gas constituent concentrations, the analyzer requirements, and the objectives of the syngas analyses: 1) removing entrained particulate matter from the sample stream; 2) maintaining the temperature of the sample gas stream; 3) lowering the pressure of the sample gas stream to decrease the vapor pressures of all the component vapor species in the sample stream; and 4) diluting the gas stream with a metered, inert gas, such as nitrogen. Proof-of-concept field demonstrations of the sampling approach were conducted for gasification process streams from a black liquor gasifier, and from the gasification of biomass and coal feedstocks at GTIs Flex-Fuel Test Facility. In addition to the descriptions and data included in this Final Report, GTI produced a Special Topical Report, Design and Protocol for Monitoring Gaseous Species in Thermochemical Processes, that explains and describes in detail the objectives, principles, design, hardware, installation, operation and representative data produced during this successful developmental effort. Although the specific analyzers used under Cooperative Agreement DE-FC36-02GO12024 were referenced in the Topical Report and this Final Report, the sampling interface design they present is generic enough to adapt to other analyzers that may be more appropriate to alternate process streams or facilities.

Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

2007-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "liquor totalb wastec" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Field Testing of a Wet FGD Additive for Enhanced Mercury Control  

SciTech Connect (OSTI)

This document is the final report for DOE-NETL Cooperative Agreement DE-FC26-04NT42309, 'Field Testing of a Wet FGD Additive'. The objective of the project has been to demonstrate the use of two flue gas desulfurization (FGD) additives, Evonik Degussa Corporation's TMT-15 and Nalco Company's Nalco 8034, to prevent the re-emission of elemental mercury (Hg{sup 0}) in flue gas exiting wet FGD systems on coal-fired boilers. Furthermore, the project was intended to demonstrate whether such additives can be used to precipitate most of the mercury (Hg) removed in the wet FGD system as a fine salt that can be separated from the FGD liquor and bulk solid byproducts for separate disposal. The project involved pilot- and full-scale tests of the additives in wet FGD absorbers. The tests were intended to determine required additive dosages to prevent Hg{sup 0} re-emissions and to separate mercury from the normal FGD byproducts for three coal types: Texas lignite/Powder River Basin (PRB) coal blend, high-sulfur Eastern bituminous coal, and low-sulfur Eastern bituminous coal. The project team consists of URS Group, Inc., EPRI, Luminant Power (was TXU Generation Company LP), Southern Company, IPL (an AES company), Evonik Degussa Corporation and the Nalco Company. Luminant Power provided the Texas lignite/PRB co-fired test site for pilot FGD tests and project cost sharing. Southern Company provided the low-sulfur Eastern bituminous coal host site for wet scrubbing tests, the pilot- and full-scale jet bubbling reactor (JBR) FGD systems tested, and project cost sharing. IPL provided the high-sulfur Eastern bituminous coal full-scale FGD test site and cost sharing. Evonik Degussa Corporation provided the TMT-15 additive, and the Nalco Company provided the Nalco 8034 additive. Both companies also supplied technical support to the test program as in-kind cost sharing. The project was conducted in six tasks. Of the six tasks, Task 1 involved project planning and Task 6 involved management and reporting. The other four tasks involved field testing on FGD systems, either at pilot or full scale. These four tasks included: Task 2 - Pilot Additive Testing in Texas Lignite Flue Gas; Task 3 - Full-scale FGD Additive Testing in High-sulfur Eastern Bituminous Flue Gas; Task 4 - Pilot Wet Scrubber Additive Tests at Plant Yates; and Task 5 - Full-scale Additive Tests at Plant Yates. The pilot-scale tests were completed in 2005 and the full-scale test using high-sulfur coal was completed in 2006; only the TMT-15 additive was tested in these efforts. The Task 5 full-scale additive tests conducted at Southern Company's Plant Yates Unit 1 were completed in 2007, and both the TMT-15 and Nalco 8034 additives were tested.

Gary Blythe; MariJon Owens

2007-12-31T23:59:59.000Z

362

Notes on Well-Posed, Ensemble Averaged Conservation Equations for Multiphase, Multi-Component, and Multi-Material Flows  

SciTech Connect (OSTI)

At the INL researchers and engineers routinely encounter multiphase, multi-component, and/or multi-material flows. Some examples include: Reactor coolant flows Molten corium flows Dynamic compaction of metal powders Spray forming and thermal plasma spraying Plasma quench reactor Subsurface flows, particularly in the vadose zone Internal flows within fuel cells Black liquor atomization and combustion Wheat-chaff classification in combine harvesters Generation IV pebble bed, high temperature gas reactor The complexity of these flows dictates that they be examined in an averaged sense. Typically one would begin with known (or at least postulated) microscopic flow relations that hold on the small scale. These include continuum level conservation of mass, balance of species mass and momentum, conservation of energy, and a statement of the second law of thermodynamics often in the form of an entropy inequality (such as the Clausius-Duhem inequality). The averaged or macroscopic conservation equations and entropy inequalities are then obtained from the microscopic equations through suitable averaging procedures. At this stage a stronger form of the second law may also be postulated for the mixture of phases or materials. To render the evolutionary material flow balance system unique, constitutive equations and phase or material interaction relations are introduced from experimental observation, or by postulation, through strict enforcement of the constraints or restrictions resulting from the averaged entropy inequalities. These averaged equations form the governing equation system for the dynamic evolution of these mixture flows. Most commonly, the averaging technique utilized is either volume or time averaging or a combination of the two. The flow restrictions required for volume and time averaging to be valid can be severe, and violations of these restrictions are often found. A more general, less restrictive (and far less commonly used) type of averaging known as ensemble averaging can also be used to produce the governing equation systems. In fact volume and time averaging can be viewed as special cases of ensemble averaging. Ensemble averaging is beginning to gain some notice, for example the general-purpose multi-material flow simulation code CFDLib under continuing developed at the Los Alamos National Laboratory [Kashiwa and Rauenzahn 1994] is based on an ensemble averaged formulation. The purpose of this short note is to give an introduction to the ensemble averaging methodology and to show how ensemble averaged balance equations and entropy inequality can be obtained from the microscopic balances. It then details some seven-equation, two-pressure, two-velocity hyperbolic, well-posed models for two-phase flows. Lastly, a simple example is presented of a model in which the flow consists of two barotropic fluids with no phase change in which an equilibrium pressure equation is obtained in the spirit of pressure-based methods of computational fluid dynamics.

Ray A. Berry

2005-07-01T23:59:59.000Z

363

A Cost-Benefit Assessment of Gasification-Based Biorefining in the Kraft Pulp and Paper Industry  

SciTech Connect (OSTI)

Production of liquid fuels and chemicals via gasification of kraft black liquor and woody residues (''biorefining'') has the potential to provide significant economic returns for kraft pulp and paper mills replacing Tomlinson boilers beginning in the 2010-2015 timeframe. Commercialization of gasification technologies is anticipated in this period, and synthesis gas from gasifiers can be converted into liquid fuels using catalytic synthesis technologies that are in most cases already commercially established today in the ''gas-to-liquids'' industry. These conclusions are supported by detailed analysis carried out in a two-year project co-funded by the American Forest and Paper Association and the Biomass Program of the U.S. Department of Energy. This work assessed the energy, environment, and economic costs and benefits of biorefineries at kraft pulp and paper mills in the United States. Seven detailed biorefinery process designs were developed for a reference freesheet pulp/paper mill in the Southeastern U.S., together with the associated mass/energy balances, air emissions estimates, and capital investment requirements. Commercial (''Nth'') plant levels of technology performance and cost were assumed. The biorefineries provide chemical recovery services and co-produce process steam for the mill, some electricity, and one of three liquid fuels: a Fischer-Tropsch synthetic crude oil (which would be refined to vehicle fuels at existing petroleum refineries), dimethyl ether (a diesel engine fuel or LPG substitute), or an ethanol-rich mixed-alcohol product. Compared to installing a new Tomlinson power/recovery system, a biorefinery would require larger capital investment. However, because the biorefinery would have higher energy efficiencies, lower air emissions, and a more diverse product slate (including transportation fuel), the internal rates of return (IRR) on the incremental capital investments would be attractive under many circumstances. For nearly all of the cases examined in the study, the IRR lies between 14% and 18%, assuming a 25-year levelized world oil price of $50/bbl--the US Department of Energy's 2006 reference oil price projection. The IRRs would rise to as high as 35% if positive incremental environmental benefits associated with biorefinery products are monetized (e.g., if an excise tax credit for the liquid fuel is available comparable to the one that exists for ethanol in the United States today). Moreover, if future crude oil prices are higher ($78/bbl levelized price, the US Department of Energy's 2006 high oil price scenario projection, representing an extrapolation of mid-2006 price levels), the calculated IRR exceeds 45% in some cases when environmental attributes are also monetized. In addition to the economic benefits to kraft pulp/paper producers, biorefineries widely implemented at pulp mills in the U.S. would result in nationally-significant liquid fuel production levels, petroleum savings, greenhouse gas emissions reductions, and criteria-pollutant reductions. These are quantified in this study. A fully-developed pulpmill biorefinery industry could be double or more the size of the current corn-ethanol industry in the United States in terms of annual liquid fuel production. Forest biomass resources are sufficient in the United States to sustainably support such a scale of forest biorefining in addition to the projected growth in pulp and paper production.

Eric D. Larson; Stefano Consonni; Ryan E. Katofsky; Kristiina Iisa; W. James Frederick

2007-03-31T23:59:59.000Z

364

Biomass Gasification Research Facility Final Report  

SciTech Connect (OSTI)

While thermochemical syngas production facilities for biomass utilization are already employed worldwide, exploitation of their potential has been inhibited by technical limitations encountered when attempting to obtain real-time syngas compositional data required for process optimization, reliability, and syngas quality assurance. To address these limitations, the Gas Technology Institute (GTI) carried out two companion projects (under US DOE Cooperative Agreements DE-FC36-02GO12024 and DE-FC36-03GO13175) to develop and demonstrate the equipment and methods required to reliably and continuously obtain accurate and representative on-line syngas compositional data. These objectives were proven through a stepwise series of field tests of biomass and coal gasification process streams. GTI developed the methods and hardware for extractive syngas sample stream delivery and distribution, necessary to make use of state-of-the-art on-line analyzers to evaluate and optimize syngas cleanup and conditioning. The primary objectives of Cooperative Agreement DE-FC36-02GO12024 were the selection, acquisition, and application of a suite of gas analyzers capable of providing near real-time gas analyses to suitably conditioned syngas streams. A review was conducted of sampling options, available analysis technologies, and commercially available analyzers, that could be successfully applied to the challenging task of on-line syngas characterization. The majority of thermochemical process streams comprise multicomponent gas mixtures that, prior to crucial, sequential cleanup procedures, include high concentrations of condensable species, multiple contaminants, and are often produced at high temperatures and pressures. Consequently, GTI engaged in a concurrent effort under Cooperative Agreement DE-FC36-03GO13175 to develop the means to deliver suitably prepared, continuous streams of extracted syngas to a variety of on-line gas analyzers. The review of candidate analysis technology also addressed safety concerns associated with thermochemical process operation that constrain the location and configuration of potential gas analysis equipment. Initial analyzer costs, reliability, accuracy, and operating and maintenance costs were also considered prior to the assembly of suitable analyzers for this work. Initial tests at GTIs Flex-Fuel Test Facility (FFTF) in late 2004 and early 2005 successfully demonstrated the transport and subsequent analysis of a single depressurized, heat-traced syngas stream to a single analyzer (an Industrial Machine and Control Corporation (IMACC) Fourier-transform infrared spectrometer (FT-IR)) provided by GTI. In March 2005, our sampling approach was significantly expanded when this project participated in the U.S. DOEs Novel Gas Cleaning (NGC) project. Syngas sample streams from three process locations were transported to a distribution manifold for selectable analysis by the IMACC FT-IR, a Stanford Research Systems QMS300 Mass Spectrometer (SRS MS) obtained under this Cooperative Agreement, and a Varian micro gas chromatograph with thermal conductivity detector (?GC) provided by GTI. A syngas stream from a fourth process location was transported to an Agilent Model 5890 Series II gas chromatograph for highly sensitive gas analyses. The on-line analyses made possible by this sampling system verified the syngas cleaning achieved by the NGC process. In June 2005, GTI collaborated with Weyerhaeuser to characterize the ChemrecTM black liquor gasifier at Weyerhaeusers New Bern, North Carolina pulp mill. Over a ten-day period, a broad range of process operating conditions were characterized with the IMACC FT-IR, the SRS MS, the Varian ?GC, and an integrated Gas Chromatograph, Mass Selective Detector, Flame Ionization Detector and Sulfur Chemiluminescence Detector (GC/MSD/FID/SCD) system acquired under this Cooperative Agreement from Wasson-ECE. In this field application, a single sample stream was extracted from this low-pressure, low-temperature process and successfully analyzed by these devices. In late 2005,

Snyder, Todd R.; Bush, Vann; Felix, Larry G.; Farthing, William E.; Irvin, James H.

2007-09-30T23:59:59.000Z

365

Filtration and Leach Testing for PUREX Cladding Sludge and REDOX Cladding Sludge Actual Waste Sample Composites  

SciTech Connect (OSTI)

A testing program evaluating actual tank waste was developed in response to Task 4 from the M-12 External Flowsheet Review Team (EFRT) issue response plan (Barnes and Voke 2006). The test program was subdivided into logical increments. The bulk water-insoluble solid wastes that are anticipated to be delivered to the Hanford Waste Treatment and Immobilization Plant (WTP) were identified according to type such that the actual waste testing could be targeted to the relevant categories. Under test plan TP RPP WTP 467 (Fiskum et al. 2007), eight broad waste groupings were defined. Samples available from the 222S archive were identified and obtained for testing. Under this test plan, a waste testing program was implemented that included: Homogenizing the archive samples by group as defined in the test plan. Characterizing the homogenized sample groups. Performing parametric leaching testing on each group for compounds of interest. Performing bench-top filtration/leaching tests in the hot cell for each group to simulate filtration and leaching activities if they occurred in the UFP2 vessel of the WTP Pretreatment Facility. This report focuses on a filtration/leaching test performed using two of the eight waste composite samples. The sample groups examined in this report were the plutonium-uranium extraction (PUREX) cladding waste sludge (Group 3, or CWP) and reduction-oxidation (REDOX) cladding waste sludge (Group 4, or CWR). Both the Group 3 and 4 waste composites were anticipated to be high in gibbsite, thus requiring caustic leaching. WTP RPT 167 (Snow et al. 2008) describes the homogenization, characterization, and parametric leaching activities before benchtop filtration/leaching testing of these two waste groups. Characterization and initial parametric data in that report were used to plan a single filtration/leaching test using a blend of both wastes. The test focused on filtration testing of the waste and caustic leaching for aluminum, in the form of gibbsite, and its impact on filtration. The initial sample was diluted with a liquid simulant to simulate the receiving concentration of retrieved tank waste into the UFP2 vessel (< 10 wt% undissolved solids). Filtration testing was performed on the dilute waste sample and dewatered to a higher solids concentration. Filtration testing was then performed on the concentrated slurry. Afterwards, the slurry was caustic leached to remove aluminum present in the undissolved solid present in the waste. The leach was planned to simulate leaching conditions in the UFP2 vessel. During the leach, slurry supernate samples were collected to measure the dissolution rate of aluminum in the waste. After the slurry cooled down from the elevated leach temperature, the leach liquor was dewatered from the solids. The remaining slurry was rinsed and dewatered with caustic solutions to remove a majority of the dissolved aluminum from the leached slurry. The concentration of sodium hydroxide in the rinse solutions was high enough to maintain the solubility of the aluminum in the dewatered rinse solutions after dilution of the slurry supernate. Filtration tests were performed on the final slurry to compare to filtration performance before and after caustic leaching.

Shimskey, Rick W.; Billing, Justin M.; Buck, Edgar C.; Casella, Amanda J.; Crum, Jarrod V.; Daniel, Richard C.; Draper, Kathryn E.; Edwards, Matthew K.; Hallen, Richard T.; Kozelisky, Anne E.; MacFarlan, Paul J.; Peterson, Reid A.; Swoboda, Robert G.

2009-03-02T23:59:59.000Z

366

Characterization of Vadose Zone Sediments Below the T Tank Farm: Boreholes C4104, C4105, 299-W10-196 and RCRA Borehole 299-W11-39  

SciTech Connect (OSTI)

This report contains geologic, geochemical, and physical characterization data collected on sediment recovered from boreholes C4104 and C4105 in the T Tank Farm, and 299-W-11-39 installed northeast of the T Tank Farm. The measurements on sediments from borehole C4104 are compared to a nearby borehole 299-W10-196 placed through the plume from the 1973 T-106 tank leak. This report also presents the data in the context of sediment types, the vertical extent of contamination, the migration potential of the contaminants, and the likely source of the contamination in the vadose zone and groundwater below the T Tank Farm. Sediment samples were characterized for: moisture content, gamma-emission radionuclides, one-to-one water extracts (which provide soil pH, electrical conductivity, cation, trace metal, radionuclide and anion data), total carbon and inorganic carbon content, and 8 M nitric acid extracts (which provide a measure of the total leachable sediment content of contaminants). Overall, our analyses showed that common ion exchange is a key mechanism that influences the distribution of contaminants within that portion of the vadose zone affected by tank liquor. We observed slight elevated pH values in samples from borehole C4104. The sediments from the three boreholes, C4104, C4105, and 299-W10-196 do show that sodium-, nitrate-, and sulfate-dominated fluids are present below tank T-106 and have formed a salt plume. The fluids are more dilute than tank fluids observed below tanks at the SX and BX Tank Farms and slightly less than those from the most saline porewater found in contaminated TX tank farm sediments. The boreholes could not penetrate below the gravel-rich strata of the Ringold Formation Wooded Island member (Rwi) (refusal was met at about 130 ft bgs); therefore, we could not identify the maximum vertical penetration of the tank related plumes. The moisture content, pH, electrical conductivity, nitrate, and technetium-99 profiles versus depth in the three contaminated boreholes around T-106 do not clearly identify the leading edge of the plume. However, the profiles do collectively suggest that bulk of tank-related fluids (center of mass) still resides in Ringold Formation Taylor Flats member fine-grained sediments. Most of the chemical data, especially the nitrate and technetium-99 distributions with depth, support a flow conceptual model that suggests vertical percolation through the Hanford formation H2 unit near T-106 and then a strong horizontal spreading within the CCUu unit followed by more slow vertical percolation, perhaps via diffusion, into the deeper strata. Slow flushing by enhanced recharge and rapid snow melt events (Feb. 1979) appear to lead to more horizontal movement of the tank fluids downgradient towards C4105. The inventories as a function of depth of potential contaminants of concern, nitrate, technetium, uranium, and chromium, are provided. In-situ Kd values were calculated from water and acid extract measurements. For conservative modeling purposes we recommend using Kd values of 0 mL/g for nitrate, Co-60, and technetium-99, a value of 0.1 mL/g for uranium near borehole C4104 and 10 mL/g for U near borehole C4105, and 1 mL/g for chromium to represent the entire vadose zone profile from the bottoms of the tanks to the water table. A technetium-99 groundwater plume exists northeast and east of T WMA. The highest technetium-99 concentration in fiscal year 2003 was 9,200 pCi/L in well 299-W11-39. The most probable source for the technetium-99 is the T waste management area. Groundwater from wells in the west (upgradient) and north of WMA T appear to be highly influenced by wastes disposed to the cribs and trenches on the west side of the WMA. Groundwater from wells at the northeast corner and the east side of the WMA appears to be evolving towards tank waste that has leaked from T-101 or T-106.

Serne, R JEFFREY.; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; LeGore, Virginia L.; Geiszler, Keith N.; Baum, Steven R.; Valenta, Michelle M.; Kutnyakov, Igor V.; Vickerman, Tanya S.; Orr, Robert D.; Brown, Christopher F.

2004-09-01T23:59:59.000Z