National Library of Energy BETA

Sample records for liquor red liquor

  1. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, Arthur L.

    1987-07-28

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediatley above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone.

  2. Gasification of black liquor

    DOE Patents [OSTI]

    Kohl, A.L.

    1987-07-28

    A concentrated aqueous black liquor containing carbonaceous material and alkali metal sulfur compounds is treated in a gasifier vessel containing a relatively shallow molten salt pool at its bottom to form a combustible gas and a sulfide-rich melt. The gasifier vessel, which is preferably pressurized, has a black liquor drying zone at its upper part, a black liquor solids gasification zone located below the drying zone, and a molten salt sulfur reduction zone which comprises the molten salt pool. A first portion of an oxygen-containing gas is introduced into the gas space in the gasification zone immediately above the molten salt pool. The remainder of the oxygen-containing gas is introduced into the molten salt pool in an amount sufficient to cause gasification of carbonaceous material entering the pool from the gasification zone but not sufficient to create oxidizing conditions in the pool. The total amount of the oxygen-containing gas introduced both above the pool and into the pool constitutes between 25 and 55% of the amount required for complete combustion of the black liquor feed. A combustible gas is withdrawn from an upper portion of the drying zone, and a melt in which the sulfur content is predominantly in the form of alkali metal sulfide is withdrawn from the molten salt sulfur reduction zone. 2 figs.

  3. Causticizing for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    Scott Sinquefeld; James Cantrell; Xiaoyan Zeng; Alan Ball; Jeff Empie

    2009-01-07

    The cost-benefit outlook of black liquor gasification (BLG) could be greatly improved if the smelt causticization step could be achieved in situ during the gasification step. Or, at a minimum, the increase in causticizing load associated with BLG could be mitigated. A number of chemistries have been proven successful during black liquor combustion. In this project, three in situ causticizing processes (titanate, manganate, and borate) were evaluated under conditions suitable for high temperature entrained flow BLG, and low temperature steam reforming of black liquor. The evaluation included both thermodynamic modeling and lab experimentation. Titanate and manganate were tested for complete direct causticizing (to thus eliminate the lime cycle), and borates were evaluated for partial causticizing (to mitigate the load increase associated with BLG). Criteria included high carbonate conversion, corresponding hydroxide recovery upon hydrolysis, non process element (NPE) removal, and economics. Of the six cases (three chemistries at two BLG conditions), only two were found to be industrially viable: titanates for complete causticizing during high temperature BLG, and borates for partial causticizing during high temperature BLG. These two cases were evaluated for integration into a gasification-based recovery island. The Larsen [28] BLG cost-benefit study was used as a reference case for economic forecasting (i.e. a 1500 tpd pulp mill using BLG and upgrading the lime cycle). By comparison, using the titanate direct causticizing process yielded a net present value (NPV) of $25M over the NPV of BLG with conventional lime cycle. Using the existing lime cycle plus borate autocausticizing for extra capacity yielded a NPV of $16M.

  4. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Jun Wei

    2005-03-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  5. Recovery of sugars from ionic liquid biomass liquor by solvent...

    Office of Scientific and Technical Information (OSTI)

    Recovery of sugars from ionic liquid biomass liquor by solvent extraction Citation Details In-Document Search Title: Recovery of sugars from ionic liquid biomass liquor by solvent ...

  6. Big Island Demonstration Project - Black Liquor

    SciTech Connect (OSTI)

    2006-08-01

    Black liquor is a papermaking byproduct that also serves as a fuel for pulp and paper mills. This project involves the design, construction, and operation of a black liquor gasifier that will be integrated into Georgia-Pacific's Big Island facility in Virginia, a mill that has been in operation for more than 100 years.

  7. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

    2005-04-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  8. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Alireza Rezaie

    2004-10-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  9. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang

    2005-10-01

    The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected/developed that either react with the gasifier environment to form protective surfaces in-situ; and

  10. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang

    2005-07-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  11. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Liang; Jun Wei

    2005-01-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  12. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie

    2003-12-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  13. REFRACTORY FOR BLACK LIQUOR GASIFIERS

    SciTech Connect (OSTI)

    William L. Headrick Jr.; Alireza Rezaie

    2003-12-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  14. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie; Xiaoting Liang; Musa Karakus; Jun Wei

    2005-12-01

    The University of Missouri-Rolla identified materials that permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project was to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study attempted to define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials were selected or developed that reacted with the gasifier environment to form protective surfaces in-situ; and

  15. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Alireza Rezaie

    2003-08-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  16. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    Robert E. Moore; William L. Headrick; Alireza Rezaie

    2003-03-31

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the materials problems encountered during the operation of low-pressure high-temperature (LFHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  17. Refractory for Black Liquor Gasifiers

    SciTech Connect (OSTI)

    William L. Headrick Jr; Musa Karakus; Xiaoting Laing

    2005-10-01

    The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in

  18. Proceedings of the black liquor research program review fourth meeting held July 28--30, 1987

    SciTech Connect (OSTI)

    Emerson, D. B.; Whitworth, B. A.

    1987-10-01

    Research programs, presented at the black liquor review meeting are described. Research topics include the following: Cooperative Program in Kraft Recovery; Black Liquor Physical Properties; Viscosity of Strong Black Liquor; Ultrafiltration of Kraft Black Liquor; Molecular Weight Distribution of Kraft Lignin; Black Liquor Droplet Formation Project; Fundamental Studies of Black Liquor Combustion; Black Liquor Combustion Sensors; Flash X-ray Imagining of Black Liquor Sprays; Laser Induced Fluorescence For Process Control In The Pulp and Paper Industry; Recovery Boiler Optimization; Black Liquor Gasification and Use of the Products in Combined-Cycle Cogeneration; Black Liquor Steam Plasma Automization; The B and W Pyrosonic 2000R System; Monsteras Boiler Control System; and Cooperative Program Project Reviews. Individual projects are processed separately for the data bases.

  19. Drum drying of black liquor using superheated steam impinging jets

    SciTech Connect (OSTI)

    Shiravi, A.H.; Mujumdar, A.S.; Kubes, G.J. [McGill Univ., Montreal, Quebec (Canada)

    1997-05-01

    A novel drum dryer for black liquor utilizing multiple impinging jets of superheated steam was designed and built to evaluate the performance characteristics and effects of various operating parameters thereon. Appropriate ranges of parameters such as steam jet temperature and velocity were examined experimentally to quantify the optimal operating conditions for the formation of black liquor film on the drum surface as well as the drying kinetics.

  20. Black liquor gasification phase 2D final report

    SciTech Connect (OSTI)

    Kohl, A.L.; Stewart, A.E.

    1988-06-01

    This report covers work conducted by Rockwell International under Amendment 5 to Subcontract STR/DOE-12 of Cooperative Agreement DE-AC-05-80CS40341 between St. Regis Corporation (now Champion International) and the Department of Energy (DOE). The work has been designated Phase 2D of the overall program to differentiate it from prior work under the same subcontract. The overall program is aimed at demonstrating the feasibility of and providing design data for the Rockwell process for gasifying Kraft black liquor. In this process, concentrated black liquor is converted into low-Btu fuel gas and reduced melt by reaction with air in a specially designed gasification reactor.

  1. Advancement of High Temperature Black Liquor Gasification Technology

    SciTech Connect (OSTI)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and

  2. A comprehensive program to develop correlations for physical properties of kraft black liquor. Final report

    SciTech Connect (OSTI)

    Fricke, A.L.; Zaman, A.A.

    1998-05-01

    The overall objective of the program was to develop correlations to predict physical properties within requirements of engineering precision from a knowledge of pulping conditions and of kraft black liquor composition, if possible. These correlations were to include those relating thermodynamic properties to pulping conditions and liquor composition. The basic premise upon which the research was based is the premise that black liquor behaves as a polymer solution. This premise has proven to be true, and has been used successfully in developing data reduction methods and in interpreting results. A three phase effort involving pulping, analysis of liquor composition, and measurement of liquor properties was conducted.

  3. Physical properties of kraft black liquor. Final report. Phase I

    SciTech Connect (OSTI)

    Fricke, A.L.

    1983-12-01

    Methods were selected, equipment installed, and procedures developed for determining rheological properties; for determining thermal properties (stability, density, thermal expansion, and heat capacity); for purification and characterization of lignin (glass transition, stability, weight average molecular weight, and number average molecular weight); and for performing chemical analyses (negative inorganic ions, positive inorganic ions, acid organic salts, lignin, and total solids). A strategy for pulping to supply test liquors was developed, and a statistically designed pulping experiment was specified for a Southern softwood species. Arrangements were made for performing initial pulping work in an industrial pilot plant, and a preliminary set of pulping experiments were conducted. Liquors from the preliminary pulping experiments were used to test procedures and to determine reproducibility of the experiment. Literature was also surveyed and preliminary selection of designs for a pilot digester, and for equipment to determine surface tension were made.

  4. Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer

    SciTech Connect (OSTI)

    Kevin Whitty

    2007-06-30

    University of Utah's project entitled 'Investigation of Fuel Chemistry and Bed Performance in a Fluidized Bed Black Liquor Steam Reformer' (DOE Cooperative Agreement DE-FC26-02NT41490) was developed in response to a solicitation released by the U.S. Department of Energy in December 2001, requesting proposals for projects targeted towards black liquor/biomass gasification technology support research and development. Specifically, the solicitation was seeking projects that would provide technical support for Department of Energy supported black liquor and biomass gasification demonstration projects under development at the time.

  5. Method for improving separation of carbohydrates from wood pulping and wood or biomass hydrolysis liquors

    DOE Patents [OSTI]

    Griffith, William Louis; Compere, Alicia Lucille; Leitten, Jr., Carl Frederick

    2010-04-20

    A method for separating carbohydrates from pulping liquors includes the steps of providing a wood pulping or wood or biomass hydrolysis pulping liquor having lignin therein, and mixing the liquor with an acid or a gas which forms an acid upon contact with water to initiate precipitation of carbohydrate to begin formation of a precipitate. During precipitation, at least one long chain carboxylated carbohydrate and at least one cationic polymer, such as a polyamine or polyimine are added, wherein the precipitate aggregates into larger precipitate structures. Carbohydrate gel precipitates are then selectively removed from the larger precipitate structures. The method process yields both a carbohydrate precipitate and a high purity lignin.

  6. Use of sulfide-containing liquors for removing mercury from flue gases

    SciTech Connect (OSTI)

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2003-01-01

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  7. Use of sulfide-containing liquors for removing mercury from flue gases

    SciTech Connect (OSTI)

    Nolan, Paul S.; Downs, William; Bailey, Ralph T.; Vecci, Stanley J.

    2006-05-02

    A method and apparatus for reducing and removing mercury in industrial gases, such as a flue gas, produced by the combustion of fossil fuels, such as coal, adds sulfide ions to the flue gas as it passes through a scrubber. Ideally, the source of these sulfide ions may include at least one of: sulfidic waste water, kraft caustic liquor, kraft carbonate liquor, potassium sulfide, sodium sulfide, and thioacetamide. The sulfide ion source is introduced into the scrubbing liquor as an aqueous sulfide species. The scrubber may be either a wet or dry scrubber for flue gas desulfurization systems.

  8. Simultaneous and rapid determination of multiple component concentrations in a Kraft liquor process stream

    DOE Patents [OSTI]

    Li, Jian; Chai, Xin Sheng; Zhu, Junyoung

    2008-06-24

    The present invention is a rapid method of determining the concentration of the major components in a chemical stream. The present invention is also a simple, low cost, device of determining the in-situ concentration of the major components in a chemical stream. In particular, the present invention provides a useful method for simultaneously determining the concentrations of sodium hydroxide, sodium sulfide and sodium carbonate in aqueous kraft pulping liquors through use of an attenuated total reflectance (ATR) tunnel flow cell or optical probe capable of producing a ultraviolet absorbency spectrum over a wavelength of 190 to 300 nm. In addition, the present invention eliminates the need for manual sampling and dilution previously required to generate analyzable samples. The inventive method can be used in Kraft pulping operations to control white liquor causticizing efficiency, sulfate reduction efficiency in green liquor, oxidation efficiency for oxidized white liquor and the active and effective alkali charge to kraft pulping operations.

  9. Mill Integration-Pulping, Stream Reforming and Direct Causticization for Black Liquor Recovery

    SciTech Connect (OSTI)

    Adriaan van Heiningen

    2007-06-30

    MTCI/StoneChem developed a steam reforming, fluidized bed gasification technology for biomass. DOE supported the demonstration of this technology for gasification of spent wood pulping liquor (or 'black liquor') at Georgia-Pacific's Big Island, Virginia mill. The present pre-commercial R&D project addressed the opportunities as well as identified negative aspects when the MTCI/StoneChem gasification technology is integrated in a pulp mill production facility. The opportunities arise because black liquor gasification produces sulfur (as H{sub 2}S) and sodium (as Na{sub 2}CO{sub 3}) in separate streams which may be used beneficially for improved pulp yield and properties. The negative aspect of kraft black liquor gasification is that the amount of Na{sub 2}CO{sub 3} which must be converted to NaOH (the so called causticizing requirement) is increased. This arises because sulfur is released as Na{sub 2}S during conventional kraft black liquor recovery, while during gasification the sodium associated Na{sub 2}S is partly or fully converted to Na{sub 2}CO{sub 3}. The causticizing requirement can be eliminated by including a TiO{sub 2} based cyclic process called direct causticization. In this process black liquor is gasified in the presence of (low sodium content) titanates which convert Na{sub 2}CO{sub 3} to (high sodium content) titanates. NaOH is formed when contacting the latter titanates with water, thereby eliminating the causticizing requirement entirely. The leached and low sodium titanates are returned to the gasification process. The project team comprised the University of Maine (UM), North Carolina State University (NCSU) and MTCI/ThermoChem. NCSU and MTCI are subcontractors to UM. The principal organization for the contract is UM. NCSU investigated the techno-economics of using advanced pulping techniques which fully utilize the unique cooking liquors produced by steam reforming of black liquor (Task 1). UM studied the kinetics and agglomeration problems of

  10. Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment

    SciTech Connect (OSTI)

    Kevin Whitty

    2008-06-30

    The University of Utah's project 'Investigation of Pressurized Entrained-Flow Kraft Black Liquor Gasification in an Industrially Relevant Environment' (U.S. DOE Cooperative Agreement DE-FC26-04NT42261) was a response to U.S. DOE/NETL solicitation DE-PS36-04GO94002, 'Biomass Research and Development Initiative' Topical Area 4-Kraft Black Liquor Gasification. The project began September 30, 2004. The objective of the project was to improve the understanding of black liquor conversion in high pressure, high temperature reactors that gasify liquor through partial oxidation with either air or oxygen. The physical and chemical characteristics of both the gas and condensed phase were to be studied over the entire range of liquor conversion, and the rates and mechanisms of processes responsible for converting the liquor to its final smelt and syngas products were to be investigated. This would be accomplished by combining fundamental, lab-scale experiments with measurements taken using a new semi-pilot scale pressurized entrained-flow gasifier. As a result of insufficient availability of funds and changes in priority within the Office of Biomass Programs of the U.S. Department of Energy, the research program was terminated in its second year. In total, only half of the budgeted funding was made available for the program, and most of this was used during the first year for construction of the experimental systems to be used in the program. This had a severe impact on the program. As a consequence, most of the planned research was unable to be performed. Only studies that relied on computational modeling or existing experimental facilities started early enough to deliver useful results by the time to program was terminated Over the course of the program, small scale (approx. 1 ton/day) entrained-flow gasifier was designed and installed at the University of Utah's off-campus Industrial Combustion and Gasification Research Facility. The system is designed to operate at

  11. Technical Report Cellulosic Based Black Liquor Gasification and Fuels Plant Final Technical Report

    SciTech Connect (OSTI)

    Fornetti, Micheal; Freeman, Douglas

    2012-10-31

    The Cellulosic Based Black Liquor Gasification and Fuels Plant Project was developed to construct a black liquor to Methanol biorefinery in Escanaba, Michigan. The biorefinery was to be co-located at the existing pulp and paper mill, NewPage’s Escanaba Paper Mill and when in full operation would: • Generate renewable energy for Escanaba Paper Mill • Produce Methanol for transportation fuel of further refinement to Dimethyl Ether • Convert black liquor to white liquor for pulping. Black liquor is a byproduct of the pulping process and as such is generated from abundant and renewable lignocellulosic biomass. The biorefinery would serve to validate the thermochemical pathway and economic models for black liquor gasification. It was a project goal to create a compelling new business model for the pulp and paper industry, and support the nation’s goal for increasing renewable fuels production and reducing its dependence on foreign oil. NewPage Corporation planned to replicate this facility at other NewPage Corporation mills after this first demonstration scale plant was operational and had proven technical and economic feasibility. An overview of the process begins with black liquor being generated in a traditional Kraft pulping process. The black liquor would then be gasified to produce synthesis gas, sodium carbonate and hydrogen sulfide. The synthesis gas is then cleaned with hydrogen sulfide and carbon dioxide removed, and fed into a Methanol reactor where the liquid product is made. The hydrogen sulfide is converted into polysulfide for use in the Kraft pulping process. Polysulfide is a known additive to the Kraft process that increases pulp yield. The sodium carbonate salts are converted to caustic soda in a traditional recausticizing process. The caustic soda is then part of the white liquor that is used in the Kraft pulping process. Cellulosic Based Black Liquor Gasification and Fuels Plant project set out to prove that black liquor gasification could

  12. Generator-Absorber heat exchange transfer apparatus and method using an intermediate liquor

    DOE Patents [OSTI]

    Phillips, Benjamin A.; Zawacki, Thomas S.

    1996-11-05

    Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use the working solution of the absorption system for the heat transfer medium where the working solution has an intermediate liquor concentration.

  13. Novel Pulping Technology: Directed Green Liquor Utilization (D-GLU) Pulping

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15

    The general objectives of this new project are the same as those described in the original proposal. Conventional kraft pulping technologies will be modified for significant improvements in pulp production, such as strength, bleachability, and yield by using green liquor, a naturally high, kraft mill-derived sulfidity source. Although split white liquor sulfidity and other high sulfidity procedures have the promise of addressing several of the latter important economic needs of pulp mills, they require considerable engineering/capital retrofits, redesigned production methods, and thus add to overall mill expenditures. Green liquor use, however, possesses the required high sulfidity to obtain in general the benefits attributable to higher sulfidity cooking, without the required capital constraints for implementation. Before introduction of green liquor in our industrial operations, a stronger understanding of its fundamental chemical interaction with the lignin and carbohydrates in US hardwood and softwoods must be obtained. In addition, its effect on bleachability, enhancement of pulp properties, and influence on the overall energy and recovery of the mill requires further exploration before the process witnesses widespread mill use in North America. Thus, proof of principle will be accomplished in this work and the consequent effect of green liquor and other high sulfide sources on the pulping and bleaching operations will be explored for US kraft mills. The first year of this project will generate the pertinent information to validate its ability for implementation in US pulping operations, whereas year two will continue this work while proceeding to analyze pulp bleachability and final pulp/paper properties and develop a general economic and feasibility analysis for its eventual implementation in North America.

  14. Black liquor combustion validated recovery boiler modeling, five-year report

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1996-08-01

    The objective of this project was to develop a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The project originated in October 1990 and was scheduled to run for four years. At that time, there was considerable emphasis on developing accurate predictions of the physical carryover of macroscopic particles of partially burnt black liquor and smelt droplets out of the furnace, since this was seen as the main cause of boiler plugging. This placed a major emphasis on gas flow patterns within the furnace and on the mass loss rates and swelling and shrinking rates of burning black liquor drops. As work proceeded on developing the recovery boiler furnace model, it became apparent that some recovery boilers encounter serious plugging problems even when physical carryover was minimal. After the original four-year period was completed, the project was extended to address this issue. The objective of the extended project was to improve the utility of the models by including the black liquor chemistry relevant to air emissions predictions and aerosol formation, and by developing the knowledge base and computational tools to relate furnace model outputs to fouling and plugging of the convective sections of the boilers. The work done to date includes CFD model development and validation, acquisition of information on black liquor combustion fundamentals and development of improved burning models, char bed model development, and model application and simplification.

  15. Regeneration of FGD waste liquors: Production of ammonium and potassium sulfate mixed fertilizer. Quarterly technical report, July 1993--September 1993

    SciTech Connect (OSTI)

    Randolph, A.D.; Kwon, T.M.

    1993-12-01

    Regeneration of the Fe{sup II}-EDTA scrubbing liquors for simultaneous removal of SO{sub 2} and NO{sub x} in flue gas involves removing the nitrogen-sulfur (N-S) compounds accumulated in the liquor. In this paper, the authors investigated a simple regeneration process which selectively precipitates the N-S compounds as potassium salts and then hydrolyzes them to yield ammonium/potassium sulfate as a marketable byproduct. They believe this is the first report on precipitation and hydrolysis characteristics of the N-S compounds in actual waste scrubbing liquor. Precipitation of the N-S compounds was achieved by adding K{sub 2}SO{sub 4} to the scrubbing liquor. Effects of the amount of added K{sub 2}SO{sub 4} on the amount of removed N-S compounds, precipitated crystals, and the potassium left over in the scrubbing liquor were studied. Hydrolysis of the precipitated N-S compounds to ammonium sulfate was performed in a sulfuric acid environment. Effects of acidity, concentration of N-S compounds, and temperature on the hydrolysis are discussed. Analysis of the observed hydrolysis pattern showed that the reaction proceeded following first order kinetics in terms of N-S compound concentration.

  16. System for removing solids from a used lime or limestone slurry scrubbing liquor in flue gas desulfurization

    SciTech Connect (OSTI)

    Randolph, A.D.

    1981-10-13

    The flue gas desulfurization process using a lime or limestone slurry scrubbing solution produces used liquor containing calcium sulfite or sulfate (Typically gypsum). Precipitated particles are removed by feeding the used scrubbing liquor to an agitated crystallization zone to grow crystals and directing part of the used scrubbing liquor from that zone to a quiescent crystallization zone, in which particles are settled back into the agitated zone. An underflow stream from the agitated zone containing large crystals is combined with an overflow stream from the quiescent zone, which combined stream is clarified with the fines being returned to the scrubber and the large crystals being removed as a waste product. Apparatus for performing the above process in which the agitated and quiescent crystallization zones form part of a single crystallization vessel, and the two zones are separated by a baffle.

  17. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 4 (Appendix IV)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 4 contains the following appendix sections: Radiative heat transfer properties for black liquor combustion -- Facilities and techniques and Spectral absorbance and emittance data; and Radiate heat transfer determination of the optical constants of ash samples from kraft recovery boilers -- Calculation procedure; Computation program; Density determination; Particle diameter determination; Optical constant data; and Uncertainty analysis.

  18. Stability and Regeneration of Catalysts for the Destruction of Tars from Bio-mass Black Liquor Gasification

    SciTech Connect (OSTI)

    Pradeep Agrawal

    2004-09-07

    The goal of this project was to develop catalytic materials and processes that would be effective in the destruction of tars formed during the gasification of black liquor and biomass. We report here the significant results obtained at the conclusion of this two year project.

  19. HIGHLY ENERGY EFFICIENT D-GLU (DIRECTED-GREEN LIQ-UOR UTILIZATION) PULPING

    SciTech Connect (OSTI)

    Lucia, Lucian A

    2013-04-19

    Purpose: The purpose of the project was to retrofit the front end (pulp house) of a commercial kraft pulping mill to accommodate a mill green liquor (GL) impregna-tion/soak/exposure and accrue downstream physical and chemical benefits while prin-cipally reducing the energy footprint of the mill. A major player in the mill contrib-uting to excessive energy costs is the lime kiln. The project was intended to offload the energy (oil or natural gas) demands of the kiln by by-passing the causticization/slaking site in the recovery area and directly using green liquor as a pulping medium for wood. Scope: The project was run in two distinct, yet mutually compatible, phases: Phase 1 was the pre-commercial or laboratory phase in which NC State University and the Insti-tute of Paper Science and Technology (at the Georgia Institute of Technology) ran the pulping and associated experiments, while Phase 2 was the mill scale trial. The first tri-al was run at the now defunct Evergreen Pulp Mill in Samoa, CA and lead to a partial retrofit of the mill that was not completed because it went bankrupt and the work was no longer the low-hanging fruit on the tree for the new management. The second trial was run at the MeadWestvaco Pulp Mill in Evedale, TX which for all intents and pur-poses was a success. They were able to fully retrofit the mill, ran the trial, studied the pulp properties, and gave us conclusions.

  20. Direct Causticizing for Black Liquor Gasification in a Circulating Fluidized Bed

    SciTech Connect (OSTI)

    Scott Sinquefield; Xiaoyan Zeng, Alan Ball

    2010-03-02

    Gasification of black liquor (BLG) has distinct advantages over direct combustion in Tomlinson recovery boilers. In this project we seek to resolve causticizing issues in order to make pressurized BLG even more efficient and cost-effective. One advantage of BLG is that the inherent partial separation of sulfur and sodium during gasification lends itself to the use of proven high yield variants to conventional kraft pulping which require just such a separation. Processes such as polysulfide, split sulfidity, ASAQ, and MSSAQ can increase pulp yield from 1% to 10% over conventional kraft but require varying degrees of sulfur/sodium separation, which requires additional [and costly] processing in a conventional Tomlinson recovery process. However during gasification, the sulfur is partitioned between the gas and smelt phases, while the sodium all leaves in the smelt; thus creating the opportunity to produce sulfur-rich and sulfur-lean white liquors for specialty pulping processes. A second major incentive of BLG is the production of a combustible product gas, rich in H2 and CO. This product gas (a.k.a. “syngas”) can be used in gas turbines for combined cycle power generation (which is twice as efficient as the steam cycle alone), or it can be used as a precursor to form liquid fuels, such as dimethyl ether or Fischer Tropsh diesel. There is drawback to BLG, which has the potential to become a third major incentive if this work is successful. The causticizing load is greater for gasification of black liquor than for combustion in a Tomlinson boiler. So implementing BLG in an existing mill would require costly increases to the causticizing capacity. In situ causticizing [within the gasifier] would handle the entire causticizing load and therefore eliminate the lime cycle entirely. Previous work by the author and others has shown that titanate direct causticizing (i.e. in situ) works quite well for high-temperature BLG (950°C), but was limited to pressures below

  1. Causes and solutions for cracking of coextruded and weld overlay floor tubes in black liquor recovery boilers

    SciTech Connect (OSTI)

    Keiser, J.R.; Taljat, B.; Wang, X.L.

    1998-09-01

    Cracking of coextruded, black liquor recovery boiler floor tubes is both a safety and an economic issue to mill operators. In an effort to determine the cause of the cracking and to identify a solution, extensive studies, described in this and three accompanying papers, are being conducted. In this paper, results of studies to characterize both the cracking and the chemical and thermal environment are reported. Based on the results described in this series of papers, a possible mechanism is presented and means to lessen the likelihood of cracking or to totally avoid cracking of floor tubes are offered.

  2. Controlling emissions from a black liquor fluidized bed evaporator (Copeland reactor) using a regenerative thermal oxidizer and a prefilter

    SciTech Connect (OSTI)

    Grzanka, R.

    1997-12-31

    This paper reports on an intriguing pilot project developed to control air emissions from a pulp mill. Testing is complete, and the results show favorable emissions reductions. Stone Container Corporation, REECO, NCASI, the Ohio DEP, and the US EPA, have all worked together and approved the installation of control equipment, for VOC and HAP emissions under Presumptive MACT, setting the standard for the Copeland Reactor process in a semi chem pulp mill. The equipment, once operational, will reduce VOC and CO emissions by greater than 90%. This installation will be done at one seventh the cost of the significant process modifications required to accomplish the same emission reduction. In addition, increased process operating efficiency will be achieved with the use of an energy recovery system. The process is a black liquor fluidized bed boiler, which is used to generate sodium carbonate from the black liquor. The vapor emissions were high in VOCs, CO and particulate. After much study and testing, a wet electrostatic precipitator was chosen as the filter system for particulate control, followed by a regenerative thermal oxidizer for VOC and HAP control, finally an air-to-air heat exchanger is being used to preheat the combustion air entering the process.

  3. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 2 (Appendices I, section 5 and II, section 1)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 2 contains the last section of Appendix I, Radiative heat transfer in kraft recovery boilers, and the first section of Appendix II, The effect of temperature and residence time on the distribution of carbon, sulfur, and nitrogen between gaseous and condensed phase products from low temperature pyrolysis of kraft black liquor.

  4. Production of ammonium sulfate fertilizer from FGD waste liquors. Quarterly technical report, October 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Randolph, A.D.; Mukhopadhyay, S.; Unrau, E.

    1994-12-31

    During this quarterly period, an experimental investigation was performed to study the precipitation kinetics and hydrolysis characteristics of calcium imido disulfonate crystals (CaADS). The CaADS crystals were precipitated by a metathetical reaction of lime, supplied by Dravo Lime Co., with flue gas desulfurization (FGD) scrubber waste liquor. Before approaching for the continuous Double Draw-Off (DDO) crystallization studies, the influence of a Dravo lime slurry on the precipitation characteristics of N-S compounds will be established. A series of N-S compound batch crystallization studies were completed in a wide range of pH (7.0--9.0), and the influence of pH on the amount of lime required, as well as the amount of precipitate obtained, was investigated. Although the amount of precipitate increased with increase in solution pH, the safe or optimum pH for the precipitation of CaADS lies in the vicinity of 8.2 to 8.3. For studying the crystallization characteristics of CaADS crystals, a bench scale 7.0 liter DDO crystallizer was built. DDO crystallizer is found to be superior compared to Mixed Suspension Mixed Product Removal (MSMPR) crystallizer. The precipitated crystals were analyzed for elemental composition by chemical analysis. The crystals were also examined under optical microscope for their morphological features. The present studies confirmed our prediction that N-S compounds in the waste liquor can be precipitated by a reaction with lime slurry. The precipitated crystals were mostly calcium imido disulfonate.

  5. Regeneration of FGD waste liquors: Production of ammonium and potassium sulfate mixed fertilizer. Quarterly technical report, April 1993--June 1993

    SciTech Connect (OSTI)

    Randolph, A.D.; Kwon, T.M.

    1993-12-01

    Precipitation and hydrolysis of the N-S compounds in the waste scrubbing liquor provided by Dravo Lime Co. was investigated. Precipitation of N-S compounds by a metathetical reaction with potassium sulfate was performed in continuous crystallizers. A preliminary operation showed that compared to a typical Mixed-Suspension-Mixed-Product-Removal (MSMPR) crystallizer, the Double-Draw-Off (DDO) crystallizer was superior by increasing the average size of the precipitated crystals of N-S compounds from 173 {mu}m to 218 {mu}m. However, the hydrolysis characteristics of the precipitated crystals were not dependent upon crystallizer type. A brief description of a new process which uses lime/limestone for precipitation of N-S compounds in the scrubbing liquor is presented. Preliminary investigations showed the lime/limestone process is efficient in precipitating N-S compounds and the precipitated crystals were shown to be more easily hydrolyzed than potassium salts of N-S compounds. This lime/limestone process is a novel process which seems better than the K{sub 2}SO{sub 4} process because one does not need to purchase/introduce a new chemical additive to precipitate in the lime/limestone Fe-EDTA wet scrubbing processes. Up to the present, the authors focused on developing the K{sub 2}SO{sub 4} process following their original proposal. However, the new lime/limestone process seems more advantageous in terms of economy and environmental safety. Therefore, it seems desirable changing research phase and putting an emphasis on the development of the lime/limestone process. Future study will include investigation of the DDO crystallizer operation to increase the size of precipitated crystals and thus to enhance their processibility. This study seems to be essential to the new lime/limestone process since the precipitated crystals are relatively small in size and thus poor in filterability.

  6. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 1 (Main text and Appendix I, sections 1--4)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 1 contains the main body of the report and the first 4 sections of Appendix 1: Modeling of black liquor recovery boilers -- summary report; Flow and heat transfer modeling in the upper furnace of a kraft recovery boiler; Numerical simulation of black liquor combustion; and Investigation of turbulence models and prediction of swirling flows for kraft recovery furnaces.

  7. Black liquor combustion validated recovery boiler modeling: Final year report. Volume 3 (Appendices II, sections 2--3 and III)

    SciTech Connect (OSTI)

    Grace, T.M.; Frederick, W.J.; Salcudean, M.; Wessel, R.A.

    1998-08-01

    This project was initiated in October 1990, with the objective of developing and validating a new computer model of a recovery boiler furnace using a computational fluid dynamics (CFD) code specifically tailored to the requirements for solving recovery boiler flows, and using improved submodels for black liquor combustion based on continued laboratory fundamental studies. The key tasks to be accomplished were as follows: (1) Complete the development of enhanced furnace models that have the capability to accurately predict carryover, emissions behavior, dust concentrations, gas temperatures, and wall heat fluxes. (2) Validate the enhanced furnace models, so that users can have confidence in the predicted results. (3) Obtain fundamental information on aerosol formation, deposition, and hardening so as to develop the knowledge base needed to relate furnace model outputs to plugging and fouling in the convective sections of the boiler. (4) Facilitate the transfer of codes, black liquid submodels, and fundamental knowledge to the US kraft pulp industry. Volume 3 contains the following appendix sections: Formation and destruction of nitrogen oxides in recovery boilers; Sintering and densification of recovery boiler deposits laboratory data and a rate model; and Experimental data on rates of particulate formation during char bed burning.

  8. Role of vanadium(V) in the aging of the organic phase in the extraction of uranium(VI) by Alamine 336 from acidic sulfate leach liquors

    SciTech Connect (OSTI)

    Chagnes, A.; Cote, G.; Courtaud, B.; Thiry, J.

    2008-07-01

    The present work is focussed on the chemical degradation of Alamine 336-tridecanol-n-dodecane solvent which used in the recovery of uranium by solvent extraction. Degradation occurs due to the presence of vanadium(V), an oxidant, in the feed solution. After a brief overview of the chemistry of vanadium, the kinetics of degradation of the solvent when contacted with acidic sulfate leach liquor was investigated and interpreted by the Michelis-Menten mechanism. GCMS analyses evidenced the presence of tridecanoic acid and dioctylamine as degradation products. A mechanism of degradation is discussed. (authors)

  9. Regeneration of FGD waste liquors: Production of ammonium and potassium sulfate mixed fertilizer. Quarterly technical report, October 1993--December 1993

    SciTech Connect (OSTI)

    Randolph, A.D.

    1993-12-31

    In the 2nd quarterly report, we discussed the lime/limestone process which precipitates N-S containing compounds by adding lime/limestone in a narrow pH range, and which can be an alternative to the K{sub 2}SO{sub 4} process. In this report, we focused on investigations of the lime/limestone process. First, we established an overall flow diagram for the lime/limestone process. Based on the diagram, we performed preliminary experimental investigations to outline practical process conditions. Out major investigations concerned about effects of pH on precipitation of the N-S compounds and precipitation characteristics of N-S compounds in a continuous crystallization system. We also performed an experimental investigation to study crystallization characteristic of the ammonium sulfate in the hydrolysis liquor. In studying effects of pH, we performed batch precipitation of the N-S compounds in a broad range of pH and investigated the effects of pH on the amount of required lime, the amount of the precipitate, and the fraction of N-S compounds precipitated. The result revealed the optimum range for precipitation of N-S compounds to be pH = 7.6--8.6. In studying continuous crystallization characteristics of the N-S compounds, a bench scale 4-liter continuous crystallization system was built to compare a typical Mixed-Suspension-Mixed-Product-Removal (MSMPR) crystallizer and Double-Draw-Off (DDO) crystallizer. In a preliminary test, the DDO was shown to be superior by increasing the average size of the precipitated crystals of N-S compounds from 97 {mu}m to 142 {mu}m and thus enhancing the filterability. In order to obtain information for a practical design of the lime/limestone process, we also set up a material balance for a 300 MWe power plant facility. A preliminary calculation showed that a process on the scale could produce approximately 56 tons ammonium sulfate fertilizer per day.

  10. High-solids black liquor firing in pulp and paper industry kraft recovery boilers: Phase 1 -- Final report. Volume 2: Project technical results

    SciTech Connect (OSTI)

    Southards, W.T.; Clement, J.L.; McIlroy, R.A.; Tharp, M.R.; Verrill, C.L.; Wessell, R.A.

    1995-11-01

    This project is a multiple-phase effort to develop technologies to improve high-solids black liquor firing in pulp mill recovery boilers. The principal means to this end is to construct and operate a pilot-scale recovery furnace simulator (RFS) in which these technologies can be tested. The Phase 1 objectives are to prepare a preliminary design for the RFS, delineate a project concept for evaluating candidate technologies, establish industrial partners, and report the results. Phase 1 addressed the objectives with seven tasks: Develop a preliminary design of the RFS; estimate the detailed design and construction costs of the RFS and the balance of the project; identify interested parties in the paper industry and key suppliers; plan the Phase 2 and Phase 3 tests to characterize the RFS; evaluate the economic justification for high-solids firing deployment in the industry; evaluate high-solids black liquor property data to support the RFS design; manage the project and reporting results, which included planning the future program direction.

  11. Influence of corn steep liquor and glucose on colonization of control and CCB (Cu/Cr/B)-treated wood by brown rot fungi

    SciTech Connect (OSTI)

    Humar, Miha; Pohleven, Franc

    2006-07-01

    There are increasing problems with regard to the disposal of treated wood waste. Due to heavy metals or arsenic in impregnated wood waste, burning and landfill disposal options are not considered to be environmentally friendly solutions for dealing with this problem. Extraction of the heavy metals and recycling of the preservatives from the wood waste is a much more promising and environmentally friendly solution. In order to study the scale up of this process, copper/chromium/boron-treated wood specimens were exposed to copper tolerant (Antrodia vaillantii and Leucogyrophana pinastri) and copper sensitive wood decay fungi (Gloeophyllum trabeum and Poria monticola). Afterwards, the ability of fungal hyphae to penetrate and overgrow the wood specimens was investigated. The fungal growths were stimulated by immersing the specimens into aqueous solution of glucose or corn steep liquor prior to exposure to the fungi. The fastest colonization of the impregnated wood was by the copper tolerant A. vaillantii. Addition of glucose onto the surface of the wood specimens increased the fungi colonization of the specimens; however, immersion of the specimens into the solution of corn steep liquor did not have the same positive influence. These results are important in elucidating copper toxicity in wood decay fungi and for using these fungi for bioremediation of treated wood wastes.

  12. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Black Liquor Gasification

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01

    As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for removal of acid gases from black liquor-derived syngas for use in both power and liquid fuels synthesis. Two 3,200 metric tonne per day gasification schemes, both low-temperature/low-pressure (1100 deg F, 40 psi) and high-temperature/high-pressure (1800 deg F, 500 psi) were used for syngas production. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory and Princeton University. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

  13. Integration of the Mini-Sulfide Sulfite Anthraquinone (MSS-AQ) Pulping Process and Black Liquor Gasification in a Pulp Mill

    SciTech Connect (OSTI)

    Hasan Jameel, North Carolina State University; Adrianna Kirkman, North Carolina State University; Ravi Chandran,Thermochem Recovery International Brian Turk Research Triangle Institute; Brian Green, Research Triangle Institute

    2010-01-27

    As many of the recovery boilers and other pieces of large capital equipment of U.S. pulp mills are nearing the end of their useful life, the pulp and paper industry will soon need to make long-term investments in new technologies. The ability to install integrated, complete systems that are highly efficient will impact the industry’s energy use for decades to come. Developing a process for these new systems is key to the adoption of state-of-the-art technologies in the Forest Products industry. This project defined an integrated process model that combines mini-sulfide sulfite anthraquinone (MSS-AQ) pulping and black liquor gasification with a proprietary desulfurization process developed by the Research Triangle Institute. Black liquor gasification is an emerging technology that enables the use of MSS-AQ pulping, which results in higher yield, lower bleaching cost, lower sulfur emissions, and the elimination of causticization requirements. The recently developed gas cleanup/absorber technology can clean the product gas to a state suitable for use in a gas turbine and also regenerate the pulping chemicals needed to for the MSS-AQ pulping process. The combination of three advanced technologies into an integrated design will enable the pulping industry to achieve a new level of efficiency, environmental performance, and cost savings. Because the three technologies are complimentary, their adoption as a streamlined package will ensure their ability to deliver maximum energy and cost savings benefits. The process models developed by this project will enable the successful integration of new technologies into the next generation of chemical pulping mills. When compared to the Kraft reference pulp, the MSS-AQ procedures produced pulps with a 10-15 % yield benefit and the ISO brightness was 1.5-2 times greater. The pulp refined little easier and had a slightly lower apparent sheet density (In both the cases). At similar levels of tear index the MSS-AQ pulps also

  14. RECOVERY OF URANIUM FROM CARBONATE LEACH LIQUORS

    DOE Patents [OSTI]

    Wilson, H.F.

    1958-07-01

    An improved process is described for the recovery of uranium from vanadifrous ores. In the prior art such ores have been digested with alkali carbonate solutions at a pH of less than 10 and then contacted with a strong base anion exchange resin to separate uranium from vanadium. It has been found that if the exchamge resin feed solution has its pH adjusted to the range 10.8 to 11.8, that vanadium adsorption on the resin is markedly decreased and the separation of uranium from the vanadium is thereby improved.

  15. Definition:Black Liquor | Open Energy Information

    Open Energy Info (EERE)

    into paper pulp removing lignin, hemicelluloses and other extractives from the wood to free the cellulose fibers. View in Wikipedia Retrieved from "http:en.openei.orgw...

  16. CLEAR LIQUOR SCRUBBING WITH ANHYDRITE PRODUCTION

    SciTech Connect (OSTI)

    R.C. SKARUPA; T.R. CAREY

    1998-08-01

    This project is funded by the US Department of Energy's Federal Energy Technology Center (DOE/FETC) under a cost-sharing PRDA with Radian International. The Electric Power Research Institute (EPRI) is providing co-funding and technical oversight. The project is part of FETC's Advanced Power Systems Program, whose mission is to accelerate the commercialization of affordable, high-efficiency, low emission, coal-fueled electric generating technologies. This project was submitted in response to Area 4 of DOE's Mega-PRDA: Advanced High-Performance SO{sub 2} Control Concepts. The goals of this research area are to develop advanced flue gas desulfurization (FGD) processes that achieve greater than 99% SO{sub 2} removal efficiency, are 25% cheaper than commercial FGD systems, and provide a valuable byproduct that will be recycled rather than disposed. Area 4 also included the development of a byproduct process that could be added to FGD systems to produce high value byproducts for reuse rather than disposal.

  17. Big Island Demonstration Project – Black Liquor

    Broader source: Energy.gov [DOE]

    This fact sheet summarizes a U.S. Department of Energy Biomass Program research and development project.

  18. Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping

    SciTech Connect (OSTI)

    2007-07-01

    This factsheet describes a project that seeks to develop feasible chemical modifications during kraft pulping operations to obtain significant energy and product benefits for U.S. kraft pulp and paper mills.

  19. Fuel Chemistry and Bed Performance in a Black Liquor Steam Reformer

    SciTech Connect (OSTI)

    2006-04-01

    The objective of this research is to address critical issues that inhibit successful commercialization of low-temperature BLG systems, including the steam reforming technology developed by Manufacturing and Technology Conversion International, Inc.

  20. Recovery of sugars from ionic liquid biomass liquor by solvent extraction

    DOE Patents [OSTI]

    Brennan, Timothy Charles R.; Holmes, Bradley M.; Simmons, Blake A.; Blanch, Harvey W.

    2015-10-13

    The present invention provides for a composition comprising a solution comprising (a) an ionic liquid (IL) or ionic liquid-aqueous (ILA) phase and (b) an organic phase, wherein the solution comprises a sugar and a boronic acid. The present invention also provides for a method of removing a sugar from a solution, comprising: (a) providing a solution comprising (i) an IL or ILA phase and (ii) an organic phase, wherein the solution comprises an IL, a sugar and a boronic acid; (b) contacting the sugar with the boronic acid to form a sugar-boronic acid complex, (c) separating the organic phase and the aqueous phase, wherein the organic phase contains the sugar-boronic acid complex, and optionally (d) separating the sugar from the organic phase.

  1. Highly Energy Efficient Directed Green Liquor Utilization (D-GLU) Pulping

    Broader source: Energy.gov [DOE]

    This factsheet describes a project that seeks to develop feasible chemical modifications during kraft pulping operations to obtain significant energy and product benefits for U.S. kraft pulp and paper mills.

  2. 1990,"AK","Total Electric Power Industry","All Sources",4208809...

    U.S. Energy Information Administration (EIA) Indexed Site

    ... coke, waste oil, and propane gas." "Wood and Wood Derived Fuels includes paper pellets, railroad ties, utility poles, wood chips, bark, red liquor, sludge wood, spent ...

  3. Energy-saving regeneration of hydrochloric acid pickling liquor: NICE3 steel project fact sheet (NICE3 2000 award winners)

    SciTech Connect (OSTI)

    2000-06-19

    This is a fact sheet written for the NICE3 [National Industrial Competititveness through Energy, Environment, and Economics] Program on a new process for reusing hydrochloric acid from steel pickling operations.

  4. Red Sky with Red Mesa

    ScienceCinema (OSTI)

    None

    2014-06-23

    The Red Sky/Red Mesa supercomputing platform dramatically reduces the time required to simulate complex fuel models, from 4-6 months to just 4 weeks, allowing researchers to accelerate the pace at which they can address these complex problems. Its speed also reduces the need for laboratory and field testing, allowing for energy reduction far beyond data center walls.

  5. Red Sky with Red Mesa

    SciTech Connect (OSTI)

    2011-04-14

    The Red Sky/Red Mesa supercomputing platform dramatically reduces the time required to simulate complex fuel models, from 4-6 months to just 4 weeks, allowing researchers to accelerate the pace at which they can address these complex problems. Its speed also reduces the need for laboratory and field testing, allowing for energy reduction far beyond data center walls.

  6. Red Lake Weatherization Project

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    REVIEW RED LAKE WEATHERIZATION PROJECT BERT VAN WERT ENERGY ACTIVITIES COORDINATOR Project Overview To develop the capacity to conduct energy audits Implement energy efficiency measures into Tribal homes Develop a Tribally administered Energy Efficiency Program and business PROJECT LOCATION Our project is located at Red Lake Housing Authority Red Lake Band of Chippewa Indians Red Lake , MN Red Lake Band of Chippewas Area overview Reservation (Diminished Lands) and Surroundings Red Lake Band of

  7. Table 3.5 Selected Byproducts in Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    Blast Pulping Liquor NAICS FurnaceCoke Petroleum or Wood ... Black Liquor Bark Total United States 311 Food 11 0 7 0 0 1 ... 0 0 324110 Petroleum Refineries 1,901 0 1,347 553 0 0 ...

  8. Thor's Hammer/Red Storm

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Camp & Jim Tomkins The Design Specification and Initial Implementation of the Red Storm ... technologies Computing domains at Sandia Red Storm is targeting the highest-end market ...

  9. Red | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Red Red Arm Amputation Due to Explosion - University of Hawaii Lessons Learned Read more about Arm Amputation Due to Explosion - University of Hawaii Lessons Learned 2015 LL Chemical Explosion Causes Eye Injury 6-11-15 Read more about 2015 LL Chemical Explosion Causes Eye Injury 6-11-15 12-14-1999 - Sodium Potassium (NaK) Reaction Results in Personnel Injuries Read more about 12-14-1999 - Sodium Potassium (NaK) Reaction Results in Personnel Injuries 11-23-1998 - Update of Type A Investigation of

  10. Walmart Red Bluff | Open Energy Information

    Open Energy Info (EERE)

    Walmart Red Bluff Jump to: navigation, search Name Walmart Red Bluff Facility Walmart Red Bluff Sector Wind energy Facility Type Community Wind Facility Status In Service Owner...

  11. Red Mesa | Open Energy Information

    Open Energy Info (EERE)

    Mesa Jump to: navigation, search Name Red Mesa Facility Red Mesa Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner NextEra Energy Resources...

  12. Red Canyon Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Canyon Wind Farm Jump to: navigation, search Name Red Canyon Wind Farm Facility Red Canyon Wind Farm Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  13. Carbon Emissions: Paper Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Btu Renewable Energy Sources (no net emissions): -- Pulping liquor: 882 trillion Btu -- Wood chips and bark: 389 trillion Btu Energy Information Administration, "1994...

  14. Oxygen-Enriched Combustion; Industrial Technologies Program ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Industry Applications Steel Reheat, soaking pits, ladles Aluminum Melting Copper Smelting and melting Glass Melting Pulp and Paper Lime kilns, black liquor boilers ...

  15. Manufacturing Consumption of Energy 1994

    U.S. Energy Information Administration (EIA) Indexed Site

    central thermal fluid system. 1436 1437 1438 1439 1440 1441 1442 Multi-effect falling-film evaporators for black liquor evaporation and concentration Part F - SPECIFIC...

  16. South Carolina Nuclear Profile - All Fuels

    U.S. Energy Information Administration (EIA) Indexed Site

    solid waste, batteries, chemicals, hydrogen, pitch, purchased steam, sulfur, tire-derived fuel, and miscellaneous technologies." "Other Renewable: Wood, black liquor, other wood ...

  17. FORM EIA-846(F)

    U.S. Energy Information Administration (EIA) Indexed Site

    packing materials, etc.) Pulping or black liquor Waste oils and tars Biomass Hydrogen Other combustible energy sources: (List separately), K? Census use only sv(2) 216...

  18. Red Power Energy Documentary Premiere

    Broader source: Energy.gov [DOE]

    Presented by the Indigenous Film & Arts Festival, the documentary film Red Power Energy, told from the Native perspective, presents a portrait of renewable and nonrenewable energy resources on American Indian lands in five states and examines the challenges involved in balancing economic development interests and cultural and environmental concerns.

  19. EA-1692: Red River Environmental Products, LLC Activated Carbon...

    Office of Environmental Management (EM)

    2: Red River Environmental Products, LLC Activated Carbon Manufacturing Facility, Red River Parish, LA EA-1692: Red River Environmental Products, LLC Activated Carbon Manufacturing ...

  20. Red River Biodiesel Ltd | Open Energy Information

    Open Energy Info (EERE)

    Ltd Jump to: navigation, search Name: Red River Biodiesel, Ltd. Place: Houston, Texas Zip: 77006 Product: Red River operates a biodiesel plant in Houstion, Texas with a capacity of...

  1. Red Sun Energy | Open Energy Information

    Open Energy Info (EERE)

    Red Sun Energy Place: Long An Province, Vietnam Product: A Vietnam-based PV module manufacturer References: Red Sun Energy1 This article is a stub. You can help OpenEI by...

  2. Science On Tap - Red Wine and Mars

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science On Tap - Red Wine and Mars Science On Tap - Red Wine and Mars WHEN: Jun 18, 2015 5:30 PM - 7:00 PM WHERE: UnQuarked Wine Room 145 Central Park Square, Los Alamos, New...

  3. Red Hills Wind Farm | Open Energy Information

    Open Energy Info (EERE)

    Hills Wind Farm Jump to: navigation, search Name Red Hills Wind Farm Facility Red Hills Wind Farm Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service...

  4. ORISE Faculty Research Experiences: Dr. Eddie Red

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Eddie Red Professor Makes Important Connections through Research Experience Dr. Eddie Red In ORNL's Chemical Sciences Division, Dr. Eddie Red of Morehouse College studies nanotube characteristics-technology that could impact future solar cells, as well as battery and fuel cells. Eddie C. Red, Ph.D., has longed to set up a functional research laboratory for the training and development of under-represented minorities in physics and engineering at Morehouse College, where he is a professor.

  5. Redding, Connecticut: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Redding, Connecticut: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 41.3025955, -73.3834532 Show Map Loading map... "minzoom":false,"mappings...

  6. RESOURCE ENERGY DATA - The RED Book

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16 Page i Bonneville Power Administration Conservation RESOURCE ENERGY DATA (The RED Book) INTRODUCTION On December 5, 1980, the 96 th Congress passed the Pacific Northwest...

  7. Redding Electric - Residential and Commercial Energy Efficiency...

    Broader source: Energy.gov (indexed) [DOE]

    REU for Commercial Program Info Sector Name Utility Administrator Redding Electric Utility Website http:www2.reupower.comrebates.asp State California Program Type Rebate...

  8. EA-1692: Red River Environmental Products, LLC Activated Carbon

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Manufacturing Facility, Red River Parish, LA | Department of Energy 2: Red River Environmental Products, LLC Activated Carbon Manufacturing Facility, Red River Parish, LA EA-1692: Red River Environmental Products, LLC Activated Carbon Manufacturing Facility, Red River Parish, LA June 1, 2010 EA-1692: Final Environmental Assessment Construction and Start-Up of an Activated Carbon Manufacturing Facility in Red River Parish, Louisiana June 11, 2010 EA-1692: Finding of No Significant Impact Red

  9. Modeling and simulation of Red Teaming. Part 1, Why Red Team M&S?

    SciTech Connect (OSTI)

    Skroch, Michael J.

    2009-11-01

    Red teams that address complex systems have rarely taken advantage of Modeling and Simulation (M&S) in a way that reproduces most or all of a red-blue team exchange within a computer. Chess programs, starting with IBM's Deep Blue, outperform humans in that red-blue interaction, so why shouldn't we think computers can outperform traditional red teams now or in the future? This and future position papers will explore possible ways to use M&S to augment or replace traditional red teams in some situations, the features Red Team M&S should possess, how one might connect live and simulated red teams, and existing tools in this domain.

  10. Sigurd Red Butte No2 | Open Energy Information

    Open Energy Info (EERE)

    Sigurd Red Butte No2 Jump to: navigation, search NEPA Document Collection for: Sigurd Red Butte No2 EIS for NA Sigurd to Red Butte No. 2 345kV Transmission Project General NEPA...

  11. City of Redding, California (Utility Company) | Open Energy Informatio...

    Open Energy Info (EERE)

    City of Redding, California (Utility Company) Jump to: navigation, search Name: City of Redding Place: California Phone Number: 530.245.7000 Website: www.reupower.com Outage...

  12. Renewable Energy Development Group Ltd RED | Open Energy Information

    Open Energy Info (EERE)

    Group Ltd RED Jump to: navigation, search Name: Renewable Energy Development Group Ltd (RED) Place: Edinburgh, United Kingdom Zip: EH1 2DP Sector: Biomass, Hydro, Wind energy...

  13. U-200: Red Hat Directory Server Information Disclosure Security...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0: Red Hat Directory Server Information Disclosure Security Issue and Vulnerability U-200: Red Hat Directory Server Information Disclosure Security Issue and Vulnerability June 27,...

  14. Red River Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Red River Hot Springs Geothermal Area Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Red River Hot Springs Geothermal Area Contents 1 Area Overview 2 History and...

  15. Town of Red Springs, North Carolina (Utility Company) | Open...

    Open Energy Info (EERE)

    Help Apps Datasets Community Login | Sign Up Search Page Edit with form History Town of Red Springs, North Carolina (Utility Company) Jump to: navigation, search Name: Red Springs...

  16. T-678: Red Hat Enterprise Virtualization Hypervisor VLAN Packet...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8: Red Hat Enterprise Virtualization Hypervisor VLAN Packet Processing Flaw Lets Remote Users Deny Service T-678: Red Hat Enterprise Virtualization Hypervisor VLAN Packet...

  17. MHK Technologies/RED HAWK | Open Energy Information

    Open Energy Info (EERE)

    RED HAWK < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage RED HAWK.jpg Technology Profile Primary Organization Natural Currents Energy Services...

  18. Red River Hot Springs Pool & Spa Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Springs Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Red River Hot Springs Pool & Spa Low Temperature Geothermal Facility Facility Red River Hot...

  19. Renewable Energies Development RED 2002 | Open Energy Information

    Open Energy Info (EERE)

    Development RED 2002 Jump to: navigation, search Name: Renewable Energies Development (RED) 2002 Place: Rome, Italy Zip: 142 Product: PV systems integrator. Coordinates:...

  20. City of Red Cloud, Nebraska (Utility Company) | Open Energy Informatio...

    Open Energy Info (EERE)

    Red Cloud, Nebraska (Utility Company) Jump to: navigation, search Name: Red Cloud Municipal Power Place: Nebraska Phone Number: 402-746-2215 Website: www.redcloudnebraska.comgover...

  1. Belgium's Red Electrical Devils Win $1 Million for Innovative...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Belgium's Red Electrical Devils Win 1 Million for Innovative Inverter Design NREL ... Google and IEEE announced today that Belgium's Red Electrical Devils, a team from CE+T ...

  2. Host compounds for red phosphorescent OLEDs

    SciTech Connect (OSTI)

    Xia, Chuanjun; Cheon, Kwang -Ohk

    2015-08-25

    Novel compounds containing a triphenylene moiety linked to an .alpha..beta. connected binaphthyl ring system are provided. These compounds have surprisingly good solubility in organic solvents and are useful as host compounds in red phosphorescent OLEDs.

  3. Redding Electric- Renewable Energy Rebate Program

    Broader source: Energy.gov [DOE]

    The Earth Advantage Rebate Program was designed to offer rebates to residential and business customers of Redding Electric Utility (REU) for solar PV, solar thermal, and geothermal heat pump...

  4. EERE: VTO - Red Leaf PNG Image | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Red Leaf PNG Image EERE: VTO - Red Leaf PNG Image red_leaf_18215.png (11.54 MB) More Documents & Publications EERE: VTO - Hybrid Bus PNG Image EERE: VTO - UPS Truck PNG Image RedLeaf Resources Ecoshale Project

  5. 7X performance results - final report : ASCI Red vs Red Storm.

    SciTech Connect (OSTI)

    Dinge, Dennis C.; Davis, Michael E.; Haskell, Karen H.; Ballance, Robert A.; Gardiner, Thomas Anthony; Stevenson, Joel O.; Noe, John P.

    2011-04-01

    The goal of the 7X performance testing was to assure Sandia National Laboratories, Cray Inc., and the Department of Energy that Red Storm would achieve its performance requirements which were defined as a comparison between ASCI Red and Red Storm. Our approach was to identify one or more problems for each application in the 7X suite, run those problems at multiple processor sizes in the capability computing range, and compare the results between ASCI Red and Red Storm. The first part of this report describes the two computer systems, the applications in the 7X suite, the test problems, and the results of the performance tests on ASCI Red and Red Storm. During the course of the testing on Red Storm, we had the opportunity to run the test problems in both single-core mode and dual-core mode and the second part of this report describes those results. Finally, we reflect on lessons learned in undertaking a major head-to-head benchmark comparison.

  6. Red mud characterization using nuclear analytical techniques

    SciTech Connect (OSTI)

    Obhodas, J.; Sudac, D.; Matjacic, L.; Valkovic, V.

    2011-07-01

    Red mud is a toxic waste left as a byproduct in aluminum production Bayer process. Since it contains significant concentrations of other chemical elements interesting for industry, including REE, it is also potential secondary ore source. Recent events in some countries have shown that red mud presents a serious environmental hazard if not properly stored. The subject of our study is the red mud from an ex-aluminum plant in Obrovac, Croatia, left from processing of bauxite mined during late 70's and early 80's at the eastern Adriatic coast and since than stored in open concrete basins for more than 30 years. We have used energy dispersive x-ray fluorescence analysis (both tube and radioactive source excitation), fast neutron activation analysis and passive gamma spectrometry to identify a number of elements present in the red mud, their concentration levels and radioactivity in the red mud. The high concentrations of Al, Si, Ca, Ti and Fe have been measured. Chemical elements Sc, Cr, Mn, Co, Ni, Cu, Zn, Ga, As, Se, Br, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Pb, Th and U were found in lower concentrations. No significant levels of radioactivity have been measured. (authors)

  7. Science On Tap - Red Wine and Mars

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Science On Tap - Red Wine and Mars Science On Tap - Red Wine and Mars WHEN: Jun 18, 2015 5:30 PM - 7:00 PM WHERE: UnQuarked Wine Room 145 Central Park Square, Los Alamos, New Mexico 87544, USA SPEAKER: Nina Lanza, Geochemist and Planetary Scientist CONTACT: Jessica Privette 505 667-0375 CATEGORY: Bradbury INTERNAL: Calendar Login Science on Tap series Event Description Science On Tap happens every third Thursday of the month, featuring a new topic each week. It begins with an informal 15-minute

  8. The FIRST-2MASS Red Quasar Survey

    SciTech Connect (OSTI)

    Glikman, E; Helfand, D J; White, R L; Becker, R H; Gregg, M D; Lacy, M

    2007-06-28

    Combining radio observations with optical and infrared color selection--demonstrated in our pilot study to be an efficient selection algorithm for finding red quasars--we have obtained optical and infrared spectroscopy for 120 objects in a complete sample of 156 candidates from a sky area of 2716 square degrees. Consistent with our initial results, we find our selection criteria--J-K > 1.7,R-K > 4.0--yield a {approx} 50% success rate for discovering quasars substantially redder than those found in optical surveys. Comparison with UVX- and optical color-selected samples shows that {approx}> 10% of the quasars are missed in a magnitude-limited survey. Simultaneous two-frequency radio observations for part of the sample indicate that a synchrotron continuum component is ruled out as a significant contributor to reddening the quasars spectra. We go on to estimate extinctions for our objects assuming their red colors are caused by dust. Continuum fits and Balmer decrements suggest E(B-V) values ranging from near zero to 2.5 magnitudes. Correcting the K-band magnitudes for these extinctions, we find that for K {le} 14.0, red quasars make up between 25% and 60% of the underlying quasar population; owing to the incompleteness of the 2MASS survey at fainter K-band magnitudes, we can only set a lower limit to the radio-detected red quasar population of > 20-30%.

  9. ASCI Red for dummies : a recipe book for easy use of the ASCI Red platform.

    SciTech Connect (OSTI)

    Kelly, Suzanne Marie; Quinlan, Gerald F.; Miller, Joel D.; Sault, Allen G.; McAllister, Paula L.

    2003-11-01

    It has been recognized that documentation for new customers of ASCI Red, aka janus or the Intel Teraflops at Sandia National Laboratories, has been sadly lacking. This document has been prepared by a team of subject matter experts to fill that void and to provide a starting point for providing a similar document for ASCI Red Storm in the future. This document is intended for SNL users who need to jumpstart their use of Janus and Janus-s.

  10. Rooftop Solar Challenge to Cut Solar's Red Tape | Department...

    Energy Savers [EERE]

    Rooftop Solar Challenge to Cut Solar's Red Tape Rooftop Solar Challenge to Cut Solar's Red Tape December 1, 2011 - 4:35pm Addthis Ginny Simmons Ginny Simmons Former Managing Editor ...

  11. Red Lake Electric Coop, Inc | Open Energy Information

    Open Energy Info (EERE)

    Red Lake Electric Coop, Inc Jump to: navigation, search Name: Red Lake Electric Coop, Inc Place: Minnesota Phone Number: 218-253-2168 or 800-245-6068 Website: www.redlakeelectric.c...

  12. V-198: Red Hat Enterprise MRG Messaging Qpid Python Certificate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8: Red Hat Enterprise MRG Messaging Qpid Python Certificate Validation Flaw Lets Remote Users Conduct Man-in-the-Middle Attacks V-198: Red Hat Enterprise MRG Messaging Qpid Python...

  13. Red River Valley Coop Pwr Assn | Open Energy Information

    Open Energy Info (EERE)

    Red River Valley Coop Pwr Assn Jump to: navigation, search Name: Red River Valley Coop Pwr Assn Place: Minnesota Website: www.rrvcoop.com Facebook: https:www.facebook.comRRVCPA...

  14. Suzhou Red Maple Wind Blade Mould Co | Open Energy Information

    Open Energy Info (EERE)

    Red Maple Wind Blade Mould Co Jump to: navigation, search Name: Suzhou Red Maple Wind Blade Mould Co Place: Jiangsu Province, China Zip: 215400 Sector: Wind energy Product: Jiangsu...

  15. Characterization and Isolation of Constituents Causing Red Coloration in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Desert Arroyo Seepage Water | Department of Energy Characterization and Isolation of Constituents Causing Red Coloration in Desert Arroyo Seepage Water Characterization and Isolation of Constituents Causing Red Coloration in Desert Arroyo Seepage Water Characterization and Isolation of Constituents Causing Red Coloration in Desert Arroyo Seepage Water Characterization and Isolation of Constituents Causing Red Coloration in Desert Arroyo Seepage Water (863.48 KB) More Documents &

  16. Red Cliffs Campground, Cedar City District, Utah | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Red Cliffs Campground, Cedar City District, Utah Red Cliffs Campground, Cedar City District, Utah Photo of Field Station at Red Cliffs Campground in Utah's Cedar City District The Bureau of Land Management (BLM) has remote field stations in Arizona, California, Utah, Idaho, and Alaska. This photograph shows the field station at Red Cliffs Campground in Utah's Cedar City District. Photovoltaic power systems allow the people working in these remote areas to have the convenience of continuous

  17. RedLeaf Resources Ecoshale Project | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RedLeaf Resources Ecoshale Project RedLeaf Resources Ecoshale Project Overview of oil shale reserves, unique oil extraction issues, novel approach for cost-effective extraction deer08_patten.pdf (6.04 MB) More Documents & Publications Secure Fuels from Domestic Resources - Oil Shale and Tar Sands Oil Shale Research in the United States EERE: VTO - Red Leaf PNG Image

  18. Hidden values in bauxite residue (red mud): Recovery of metals

    SciTech Connect (OSTI)

    Liu, Yanju; Naidu, Ravi

    2014-12-15

    Highlights: • Current iron recovery techniques using red mud are depicted. • Advantages and disadvantages exist in different recovering processes. • Economic and environmental friendly integrated usage of red mud is promising. - Abstract: Bauxite residue (red mud) is a hazardous waste generated from alumina refining industries. Unless managed properly, red mud poses significant risks to the local environment due to its extreme alkalinity and its potential impacts on surface and ground water quality. The ever-increasing generation of red mud poses significant challenges to the aluminium industries from management perspectives given the low proportion that are currently being utilized beneficially. Red mud, in most cases, contains elevated concentrations of iron in addition to aluminium, titanium, sodium and valuable rare earth elements. Given the scarcity of iron supply globally, the iron content of red mud has attracted increasing research interest. This paper presents a critical overview of the current techniques employed for iron recovery from red mud. Information on the recovery of other valuable metals is also reviewed to provide an insight into the full potential usage of red mud as an economic resource rather than a waste. Traditional hydrometallurgy and pyrometallurgy are being investigated continuously. However, in this review several new techniques are introduced that consider the process of iron recovery from red mud. An integrated process which can achieve multiple additional values from red mud is much preferred over the single process methods. The information provided here should help to improve the future management and utilization of red mud.

  19. RedLeaf Resources Ecoshale Project

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RedLeaf Resources Ecoshale Project Overview DEER 2008 Energy demand is exploding but "renewable energy" can't fill gap. Existing conventional oil production is "peaking" Lower extraction costs and demand have accelerated unconventional oil sands. * Unconventional Hydrocarbons - The hidden opportunity, oil industry consultancy Wood Mackenzie: "by 2025 unconventional oil is expected to supply more than 20% of global demand. Canada's UNCONVENTIONAL climb to the top of world

  20. V-138: Red Hat update for icedtea-web | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    8: Red Hat update for icedtea-web V-138: Red Hat update for icedtea-web April 19, 2013 - 6:00am Addthis PROBLEM: Red Hat has issued an update for icedtea-web PLATFORM: Red Hat ...

  1. redMaGiC. Selecting Luminous Red Galaxies from the DES Science Verification Data

    SciTech Connect (OSTI)

    Rozo, E.

    2015-07-20

    We introduce redMaGiC, an automated algorithm for selecting Luminous Red Galaxies (LRGs). The algorithm was developed to minimize photometric redshift uncertainties in photometric large-scale structure studies. redMaGiC achieves this by self-training the color-cuts necessary to produce a luminosity-thresholded LRG sam- ple of constant comoving density. Additionally, we demonstrate that redMaGiC photo-zs are very nearly as accurate as the best machine-learning based methods, yet they require minimal spectroscopic training, do not suffer from extrapolation biases, and are very nearly Gaussian. We apply our algorithm to Dark Energy Survey (DES) Science Verification (SV) data to produce a redMaGiC catalog sampling the redshift range z ϵ [0.2,0.8]. Our fiducial sample has a comoving space density of 10-3 (h-1Mpc)-3, and a median photo-z bias (zspec zphoto) and scatter (σz=(1 + z)) of 0.005 and 0.017 respectively.The corresponding 5σ outlier fraction is 1.4%. We also test our algorithm with Sloan Digital Sky Survey (SDSS) Data Release 8 (DR8) and Stripe 82 data, and discuss how spectroscopic training can be used to control photo-z biases at the 0.1% level.

  2. Redding Direct Interconnection Project, Shasta County, California:

    SciTech Connect (OSTI)

    Not Available

    1986-01-01

    As required under the California Environemtnal Quality Act (CEQA), the City of Redding (City) has prepared an Environmental Impact report (EIR) for the proposed Direct interconnection Project. Western Area Power Administration (Western) is also required to prepare an environmental assessment (EA) under the National Environmental Policy Act (NEPA) due to its involvement in the Project. Since the City has alrady prepared their EIR, this EA will briefly summarize the impact assessment field work and findings from the City's EIR. The EIR is attached as an appendix to this EA. 21 refs., 20 figs., 10 tabs.

  3. Blue, green, orange, and red upconversion laser

    DOE Patents [OSTI]

    Xie, Ping; Gosnell, Timothy R.

    1998-01-01

    A laser for outputting visible light at the wavelengths of blue, green, orange and red light. This is accomplished through the doping of a substrate, such as an optical fiber or waveguide, with Pr.sup.3+ ions and Yb.sup.3+ ions. A light pump such as a diode laser is used to excite these ions into energy states which will produce lasing at the desired wavelengths. Tuning elements such as prisms and gratings can be employed to select desired wavelengths for output.

  4. Blue, green, orange, and red upconversion laser

    DOE Patents [OSTI]

    Xie, P.; Gosnell, T.R.

    1998-09-08

    A laser is disclosed for outputting visible light at the wavelengths of blue, green, orange and red light. This is accomplished through the doping of a substrate, such as an optical fiber or waveguide, with Pr{sup 3+} ions and Yb{sup 3+} ions. A light pump such as a diode laser is used to excite these ions into energy states which will produce lasing at the desired wavelengths. Tuning elements such as prisms and gratings can be employed to select desired wavelengths for output. 11 figs.

  5. CX-004710: Categorical Exclusion Determination

    Broader source: Energy.gov [DOE]

    Highly Energy Efficient Directed-Green Liquor PulpingCX(s) Applied: B3.6Date: 12/14/2010Location(s): ColoradoOffice(s): Energy Efficiency and Renewable Energy, Golden Field Office

  6. Mercantile (Retail Other Than Mall) | Open Energy Information

    Open Energy Info (EERE)

    Other Than Mall) Definition Buildings used for the sale and display of goods other than food. Sub Categories retail store; beer, wine, or liquor store; rental center; dealership or...

  7. SSF Experimental Protocols -- Lignocellulosic Biomass Hydrolysis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... 8.22.7 Sample size: See flask preparation instructions. 8.22.8 Sample storage: Store liquor samples in the freezer if the analysis is not going to be carried out within a day. ...

  8. Redding Electric- Residential and Commercial Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Redding Electric Utility offers a variety of financial incentives for energy efficiency through its Residential and Commercial Rebate Programs. Rebates are for weatherization measures, HVAC...

  9. Microsoft Word - RED_Book_FY08_FINAL.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    16 Page i Bonneville Power Administration Conservation RESOURCE ENERGY DATA (The RED Book) INTRODUCTION On December 5, 1980, the 96 th Congress passed the Pacific Northwest...

  10. Red Bank, New Jersey: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    (Redirected from Red Bank, NJ) Jump to: navigation, search Equivalent URI DBpedia Coordinates 40.3470543, -74.0643065 Show Map Loading map... "minzoom":false,"mappingservice":...

  11. Kevin Redding | Center for Bio-Inspired Solar Fuel Production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ana Moore Anne Jones Devens Gust Don Seo Giovanna Ghirlanda Hao Yan James Allen Kevin Redding Petra Fromme Thomas Moore Yan Liu Kevin Redding Associate Director of the Center Principal Investigator Phone: 480-965-0136 Fax: 480-965-2747 E-mail: kevin.redding@asu.edu Associate Professor Kevin Redding contributes to the EFRC in the area of management as an Associate Director of the Center. As a Principal Investigator of the Center he is primarily focussed on the area of EPR analysis of the

  12. JLab to host Red Cross Blood Drive | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to host Red Cross Blood Drive JLab to host Red Cross Blood Drive on Aug. 16 The next American Red Cross Blood Drive taking place at Jefferson Lab will be held on Tuesday, Aug. 16, from 10 a.m. to 4 p.m. in CEBAF Center, Room F113. New and repeat donors are encouraged to attend. Walk-ins are welcome. All participation is appreciated as the Red Cross has a significant blood shortage. Please visit this webpage for eligibility requirements:

  13. Saccrifical Protective Coating Materials that can be Regenerated In-Situ to Enable High Performance and Low Cost Membranes

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Peter Malati, Rahul Ganguli and Vivek Mehrotra Teledyne Scientific Company U.S. DOE Advanced Manufacturing Office Peer Review Meeting Washington, D.C. May 6-7, 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Objective Pulp and Paper Mill Currently, energy-intensive evaporators * Separate water from Weak Black Liquor (WBL) for reuse * Resulting strong black liquor burned in recovery unit  Develop membrane filtration for

  14. U-159: Red Hat Enterprise MRG Messaging Qpid Bug Lets Certain...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9: Red Hat Enterprise MRG Messaging Qpid Bug Lets Certain Remote Users Bypass Authentication U-159: Red Hat Enterprise MRG Messaging Qpid Bug Lets Certain Remote Users Bypass...

  15. V-163: Red Hat Network Satellite Server Inter-Satellite Sync...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3: Red Hat Network Satellite Server Inter-Satellite Sync Remote Authentication Bypass V-163: Red Hat Network Satellite Server Inter-Satellite Sync Remote Authentication Bypass May...

  16. Red River Valley REA- Heat Pump Loan Program

    Broader source: Energy.gov [DOE]

    The Red River Valley Rural Electric Association (RRVREA) offers a loan program to its members for air-source and geothermal heat pumps. Loans are available for geothermal heat pumps at a 5% fixed...

  17. Red River Parish, Louisiana: Energy Resources | Open Energy Informatio...

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Red River Parish is a county in Louisiana. Its FIPS County Code is 081. It is classified as...

  18. Red Bank, New Jersey: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Red Bank is a borough in Monmouth County, New Jersey. It falls under New Jersey's 6th...

  19. Red River Valley Rrl Elec Assn | Open Energy Information

    Open Energy Info (EERE)

    Elec Assn Jump to: navigation, search Name: Red River Valley Rrl Elec Assn Place: Oklahoma Phone Number: 1-800-749-3364 or 580-564-1800 Website: www.rrvrea.com Twitter:...

  20. Red River County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Red River County is a county in Texas. Its FIPS County Code is 387. It is classified as...

  1. Red Feather Lakes, Colorado: Energy Resources | Open Energy Informatio...

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Red Feather Lakes is a census-designated place in Larimer County, Colorado.1 References...

  2. Red Willow County, Nebraska: Energy Resources | Open Energy Informatio...

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Red Willow County is a county in Nebraska. Its FIPS County Code is 145. It is classified as...

  3. City of Red Bud, Illinois (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    Bud, Illinois (Utility Company) Jump to: navigation, search Name: Red Bud City of Place: Illinois Phone Number: 618.282.3339 or 618.282.2315 Website: www.cityofredbud.orgdepartmen...

  4. Red Mesa, Arizona: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Red Mesa is a census-designated place in Apache County, Arizona.1 References US...

  5. Red Hill, Pennsylvania: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Red Hill is a borough in Montgomery County, Pennsylvania. It falls under Pennsylvania's...

  6. Red Lake County, Minnesota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Red Lake County is a county in Minnesota. Its FIPS County Code is 125. It is classified as...

  7. Microsoft Word - RED_Book_FY11_FINAL without cover

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    E V I L L E P O W E R A D M I N I S T R A T I O N Conservation Resource Energy Data The RED Book Fiscal Year 2011 Table of Contents INTRODUCTION ......

  8. Red Butte, Wyoming: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Red Butte is a census-designated place in Natrona County, Wyoming. It falls under Wyoming's...

  9. Red Bank, Tennessee: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Red Bank is a city in Hamilton County, Tennessee. It falls under Tennessee's 3rd...

  10. Red Cliff, Colorado: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Red Cliff is a town in Eagle County, Colorado. It falls under Colorado's 2nd congressional...

  11. Western Red-tailed Skink Distribution in Southern Nevada

    SciTech Connect (OSTI)

    Hall, D. B. and Gergor, P. D.

    2011-11-01

    This slide show reports a study to: determine Western Red-tailed Skink (WRTS) distribution on Nevada National Security Site (NNSS); identify habitat where WRTS occur; learn more about WRTS natural history; and document distribution of other species.

  12. Energy Secretary Bodman Tours Alabama Red Cross Facility and Attends

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Day of Prayer and Remembrance Service with Governor Riley | Department of Energy Tours Alabama Red Cross Facility and Attends National Day of Prayer and Remembrance Service with Governor Riley Energy Secretary Bodman Tours Alabama Red Cross Facility and Attends National Day of Prayer and Remembrance Service with Governor Riley September 16, 2005 - 10:24am Addthis MONTGOMERY, AL - Today, Secretary of Energy Samuel W. Bodman traveled to Montgomery, Alabama, to commemorate a National

  13. Red Storm usage model :Version 1.12.

    SciTech Connect (OSTI)

    Jefferson, Karen L.; Sturtevant, Judith E.

    2005-12-01

    Red Storm is an Advanced Simulation and Computing (ASC) funded massively parallel supercomputer located at Sandia National Laboratories (SNL). The Red Storm Usage Model (RSUM) documents the capabilities and the environment provided for the FY05 Tri-Lab Level II Limited Availability Red Storm User Environment Milestone and the FY05 SNL Level II Limited Availability Red Storm Platform Milestone. This document describes specific capabilities, tools, and procedures to support both local and remote users. The model is focused on the needs of the ASC user working in the secure computing environments at Los Alamos National Laboratory (LANL), Lawrence Livermore National Laboratory (LLNL), and SNL. Additionally, the Red Storm Usage Model maps the provided capabilities to the Tri-Lab ASC Computing Environment (ACE) requirements. The ACE requirements reflect the high performance computing requirements for the ASC community and have been updated in FY05 to reflect the community's needs. For each section of the RSUM, Appendix I maps the ACE requirements to the Limited Availability User Environment capabilities and includes a description of ACE requirements met and those requirements that are not met in that particular section. The Red Storm Usage Model, along with the ACE mappings, has been issued and vetted throughout the Tri-Lab community.

  14. Assessment of Biomass Energy Opportunities for the Red Lake Band of Chippewa Indians

    SciTech Connect (OSTI)

    Scott Haase

    2005-09-30

    Assessment of biomass energy and biobased product manufacturing opportunities for the Red Lake Tribe.

  15. T-678: Red Hat Enterprise Virtualization Hypervisor VLAN Packet Processing Flaw Lets Remote Users Deny Service

    Office of Energy Efficiency and Renewable Energy (EERE)

    Red Hat Enterprise Virtualization Hypervisor VLAN Packet Processing Flaw Lets Remote Users Deny Service.

  16. Red phosphors for use in high CRI fluorescent lamps

    DOE Patents [OSTI]

    Srivastava, Alok; Comanzo, Holly; Manivannan, Vankatesan; Setlur, Anant Achyut

    2005-11-15

    Novel red emitting phosphors for use in fluorescent lamps resulting in superior color rendering index values compared to conventional red phosphors. Also disclosed is a fluorescent lamp including a phosphor layer comprising blends of one or more of a blue phosphor, a blue-green phosphor, a green phosphor and a red a phosphor selected from the group consisting of SrY.sub.2 O.sub.4 :Eu.sup.3+, (Y,Gd)Al.sub.3 B.sub.4 O.sub.12 :Eu.sup.3+, and [(Y.sub.1-x-y-m La.sub.y)Gd.sub.x ]BO.sub.3 :Eu.sub.m wherein y<0.50 and m=0.001-0.3. The phosphor layer can optionally include an additional deep red phosphor and a yellow emitting phosphor. The resulting lamp will exhibit a white light having a color rendering index of 90 or higher with a correlated color temperature of from 2500 to 10000 Kelvin. The use of the disclosed red phosphors in phosphor blends of lamps results in high CRI light sources with increased stability and acceptable lumen maintenance over the course of the lamp life.

  17. American Red Cross Blood Drive Hanford Health and Safety Exposition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Red Cross Blood Drive Hanford Health and Safety Exposition 6600 Burden Blvd. - TRAC Center Tuesday,May13,2014 10:00 AM - 3:00 PM To schedule your appointment go online to www.redcrossblood.org/make- donation, enter EXPO for sponsor code and follow further instructions. redcrossblood.org I 1-800-RED CROSS (1-800 - 733-2767) [!] ........ Use your smartphone to scan the OR code at left, or go to redcrossblood .org/social to follow us on Facebook and Twitter. Identif ication is requ ired to don ate.

  18. Method for determining properties of red blood cells

    DOE Patents [OSTI]

    Gourley, Paul L.

    2001-01-01

    A method for quantifying the concentration of hemoglobin in a cell, and indicia of anemia, comprises determining the wavelength of the longitudinal mode of a liquid in a laser microcavity; determining the wavelength of the fundamental transverse mode of a red blood cell in the liquid in the laser microcavity; and determining if the cell is anemic from the difference between the wavelength of the longitudinal mode and the fundamental transverse mode. In addition to measuring hemoglobin, the invention includes a method using intracavity laser spectroscopy to measure the change in spectra as a function of time for measuring the influx of water into a red blood cell and the cell's subsequent rupture.

  19. Los Alamos laser instrument arrives on Red Planet's surface

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laser instrument arrives on Red Planet's surface Los Alamos laser instrument arrives on Red Planet's surface The ChemCam laser characterization instrument was developed at LANL and the French space institute, IRAP. August 6, 2012 Curiosity zaps Mars for vital signs: ChemCam, designed by Lab team, looks for elements such as carbon, nitrogen, and oxygen, all of which are crucial for life. Curiosity zaps Mars for vital signs: ChemCam, designed by Lab team, looks for elements such as carbon,

  20. PREPARATION OF UO$sub 2$ FOR NUCLEAR REACTOR FUEL PELLETS

    DOE Patents [OSTI]

    Googin, J.M.

    1962-06-01

    A method is given for preparing high-density UO/sub 2/ compacts. An aqueous uranyl fluoride solution is contacted with an aqueous ammonium hydroxide solution at an ammonium to-uranium ratio of 25: 1 to 30:1 to form a precipitate. The precipitate is separated from the- mother liquor, dried, and contacted with steam at a uniform temperature within the range of 400 to 650 deg C to produce U/ sub 3/O/sub 8/. The U/sub 3/O/sub 8/ is red uced to UO/sub 2/ with hydrogen at a uniform temperature within the range of 550 to 600 deg C. The UO/sub 2/ is then compressed into compacts and sintered. High-density compacts are fabricated to close tolerances without use of a binder and without machining or grinding. (AEC)

  1. New red phosphor for near-ultraviolet light-emitting diodes with high color-purity

    SciTech Connect (OSTI)

    Wang, Zhengliang; He, Pei; Wang, Rui; Zhao, Jishou; Gong, Menglian

    2010-02-15

    New red phosphors, Na{sub 5}Eu(MoO{sub 4}){sub 4} doped with boron oxide were prepared by the solid-state reaction. Their structure and photo-luminescent properties were investigated. With the introduction of boron oxide, the red emission intensity of the phosphors under 395 nm excitation is strengthened, with high color-purity (x = 0.673, y = 0.327). The single red light-emitting diode was obtained by combining InGaN chip with the red phosphor, bright red light can be observed by naked eyes from the red light-emitting diodes under a forward bias of 20 mA.

  2. Magnetic braking of stellar cores in red giants and supergiants

    SciTech Connect (OSTI)

    Maeder, André; Meynet, Georges E-mail: georges.meynet@unige.ch

    2014-10-01

    Magnetic configurations, stable on the long term, appear to exist in various evolutionary phases, from main-sequence stars to white dwarfs and neutron stars. The large-scale ordered nature of these fields, often approximately dipolar, and their scaling according to the flux conservation scenario favor a fossil field model. We make some first estimates of the magnetic coupling between the stellar cores and the outer layers in red giants and supergiants. Analytical expressions of the truncation radius of the field coupling are established for a convective envelope and for a rotating radiative zone with horizontal turbulence. The timescales of the internal exchanges of angular momentum are considered. Numerical estimates are made on the basis of recent model grids. The direct magnetic coupling of the core to the extended convective envelope of red giants and supergiants appears unlikely. However, we find that the intermediate radiative zone is fully coupled to the core during the He-burning and later phases. This coupling is able to produce a strong spin down of the core of red giants and supergiants, also leading to relatively slowly rotating stellar remnants such as white dwarfs and pulsars. Some angular momentum is also transferred to the outer convective envelope of red giants and supergiants during the He-burning phase and later.

  3. AmeriFlux US-Wi4 Mature red pine (MRP) (Dataset) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Wi4 Mature red pine (MRP) Citation Details In-Document Search Title: AmeriFlux US-Wi4 Mature red pine (MRP) This is the AmeriFlux version of the carbon flux data for the site ...

  4. RedSeal Comments on "Smart Grid RFI: Addressing Policy and Logistical...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    RedSeal Comments on "Smart Grid RFI: Addressing Policy and Logistical Challenges. RedSeal's core technology is the ability to understand the access control of the network as a ...

  5. EVMS Training Snippet: 5.7 PARSII Analysis: OAPM Red Yellow Report...

    Office of Environmental Management (EM)

    7 PARSII Analysis: OAPM Red Yellow Report EVMS Training Snippet: 5.7 PARSII Analysis: OAPM Red Yellow Report This EVMS Training Snippet, sponsored by the Office of Project ...

  6. DOE Tour of Zero: The Greenbank Red House (Leganza) by Clifton...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Greenbank Red House (Leganza) by Clifton View Homes DOE Tour of Zero: The Greenbank Red House (Leganza) by Clifton View Homes Addthis 1 of 6 This is a certified U.S. DOE Zero...

  7. T-563: Red Hat Directory Server Bugs Let Local Users Gain Elevated...

    Broader source: Energy.gov (indexed) [DOE]

    server and command line utilities for server administration. Addthis Related Articles T-671: Red Hat system-config-firewall Lets Local Users Gain Root Privileges V-041: Red Hat...

  8. EERE Success Story-Nationwide: Slashing Red Tape To Speed Solar...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Slashing Red Tape To Speed Solar Deployment for Homes and Businesses EERE Success Story-Nationwide: Slashing Red Tape To Speed Solar Deployment for Homes and Businesses January 24, ...

  9. T-712: Red Hat Enterprise MRG Grid 2.0 security, bug fix and...

    Office of Environmental Management (EM)

    A local user can access the broker password. PLATFORM: Red Hat Enterprise MRG v2 for Red ... A local user can access the file to obtain the broker username and password. A local user ...

  10. U-156: Red Hat update for JBoss Enterprise Portal Platform | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 56: Red Hat update for JBoss Enterprise Portal Platform U-156: Red Hat update for JBoss Enterprise Portal Platform April 26, 2012 - 7:00am Addthis PROBLEM: Red Hat update for JBoss Enterprise Portal Platform PLATFORM: JBoss Enterprise Portal Platform 5.x ABSTRACT: Update for JBoss Enterprise Portal Platform Reference Links: Secunia Advisory SA48954 CVE-2011-4314 CVE-2012-0818 IMPACT ASSESSMENT: Medium Discussion: Red Hat has issued an update for JBoss Enterprise Portal Platform. This

  11. Red Lake Band of Chippewa Indians- 2003 Project

    Broader source: Energy.gov [DOE]

    The Red Lake Band of Chippewa Indians, located in the northwest corner of Minnesota near the Canadian border, will assess the potential to expand the use of biomass resources for energy autonomy and economic development on tribal lands. Specifically, the tribe will evaluate the technical, market, financial, and cultural aspects of using its extensive, forested lands to create a sustainable bioproducts-based business and will develop a business plan to guide tribal industry development.

  12. T-712: Red Hat Enterprise MRG Grid 2.0 security, bug fix and enhancement

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    update | Department of Energy 12: Red Hat Enterprise MRG Grid 2.0 security, bug fix and enhancement update T-712: Red Hat Enterprise MRG Grid 2.0 security, bug fix and enhancement update September 8, 2011 - 10:30am Addthis PROBLEM: A flaw was discovered in Cumin where it would log broker authentication credentials to the Cumin log file. A vulnerability was reported in Red Hat Enterprise MRG Grid. A local user can access the broker password. PLATFORM: Red Hat Enterprise MRG v2 for Red Hat

  13. RedSeal Comments on "Smart Grid RFI: Addressing Policy and Logistical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Challenges. | Department of Energy RedSeal Comments on "Smart Grid RFI: Addressing Policy and Logistical Challenges. RedSeal Comments on "Smart Grid RFI: Addressing Policy and Logistical Challenges. RedSeal Comments on "Smart Grid RFI: Addressing Policy and Logistical Challenges. RedSeal's core technology is the ability to understand the access control of the network as a whole - not simply the behavior of a single device. RedSeal analyzes the interactions of firewalls,

  14. T-712: Red Hat Enterprise MRG Grid 2.0 security, bug fix and enhancement

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    update | Department of Energy 12: Red Hat Enterprise MRG Grid 2.0 security, bug fix and enhancement update T-712: Red Hat Enterprise MRG Grid 2.0 security, bug fix and enhancement update September 8, 2011 - 10:30am Addthis PROBLEM: A flaw was discovered in Cumin where it would log broker authentication credentials to the Cumin log file. A vulnerability was reported in Red Hat Enterprise MRG Grid. A local user can access the broker password. PLATFORM: Red Hat Enterprise MRG v2 for Red Hat

  15. Method using CO for extending the useful shelf-life of refrigerated red blood cells

    DOE Patents [OSTI]

    Bitensky, M.W.

    1995-12-19

    A method is disclosed using CO for extending the useful shelf-life of refrigerated red blood cells. Carbon monoxide is utilized for stabilizing hemoglobin in red blood cells to be stored at low temperature. Changes observed in the stored cells are similar to those found in normal red cell aging in the body, the extent thereof being directly related to the duration of refrigerated storage. Changes in cell buoyant density, vesiculation, and the tendency of stored cells to bind autologous IgG antibody directed against polymerized band 3 IgG, all of which are related to red blood cell senescence and increase with refrigerated storage time, have been substantially slowed when red blood cells are treated with CO. Removal of the carbon monoxide from the red blood cells is readily and efficiently accomplished by photolysis in the presence of oxygen so that the stored red blood cells may be safely transfused into a recipient. 5 figs.

  16. Method using CO for extending the useful shelf-life of refrigerated red blood cells

    DOE Patents [OSTI]

    Bitensky, Mark W.

    1995-01-01

    Method using CO for extending the useful shelf-life of refrigerated red blood cells. Carbon monoxide is utilized for stabilizing hemoglobin in red blood cells to be stored at low temperature. Changes observed in the stored cells are similar to those found in normal red cell aging in the body, the extent thereof being directly related to the duration of refrigerated storage. Changes in cell buoyant density, vesiculation, and the tendency of stored cells to bind autologous IgG antibody directed against polymerized band 3 IgG, all of which are related to red blood cell senescence and increase with refrigerated storage time, have been substantially slowed when red blood cells are treated with CO. Removal of the carbon monoxide from the red blood cells is readily and efficiently accomplished by photolysis in the presence of oxygen so that the stored red blood cells may be safely transfused into a recipient.

  17. Sacrificial adsorbate for surfactants utilized in chemical floods of enhanced oil recovery operations

    DOE Patents [OSTI]

    Johnson, Jr., James S.; Westmoreland, Clyde G.

    1982-01-01

    The present invention is directed to a sacrificial or competitive adsorbate for surfactants contained in chemical flooding emulsions for enhanced oil recovery operations. The adsorbate to be utilized in the method of the present invention is a caustic effluent from the bleach stage or the weak black liquor from the digesters and pulp washers of the kraft pulping process. This effluent or weak black liquor is injected into an oil-bearing subterranean earth formation prior to or concurrent with the chemical flood emulsion and is adsorbed on the active mineral surfaces of the formation matrix so as to effectively reduce adsorption of surfactant in the chemical flood. Alternatively, the effluent or liquor can be injected into the subterranean earth formation subsequent to a chemical flood to displace the surfactant from the mineral surfaces for the recovery thereof.

  18. Sacrificial adsorbate for surfactants utilized in chemical floods of enhanced oil recovery operations

    DOE Patents [OSTI]

    Johnson, J.S. Jr.; Westmoreland, C.G.

    1980-08-20

    The present invention is directed to a sacrificial or competitive adsorbate for surfactants contained in chemical flooding emulsions for enhanced oil recovery operations. The adsorbate to be utilized in the method of the present invention is a caustic effluent from the bleach stage or the weak black liquor from the digesters and pulp washers of the kraft pulping process. This effluent or weak black liquor is injected into an oil-bearing subterranean earth formation prior to or concurrent with the chemical flood emulsion and is adsorbed on the active mineral surfaces of the formation matrix so as to effectively reduce adsorption of surfactant in the chemical flood. Alternatively, the effluent or liquor can be injected into the subterranean earth formation subsequent to a chemical flood to displace the surfactant from the mineral surfaces for the recovery thereof.

  19. WHAT DOES CLUSTERING TELL US ABOUT THE BUILDUP OF THE RED SEQUENCE?

    SciTech Connect (OSTI)

    Tinker, Jeremy L.; Wetzel, Andrew R.

    2010-08-10

    We analyze the clustering of red and blue galaxies from four samples spanning a redshift range of 0.4 < z < 2.0 to test the various scenarios by which galaxies evolve onto the red sequence. The data are taken from the UKIDSS Ultra Deep Survey, DEEP2, and COMBO-17. The use of clustering allows us to determine what fraction of the red sequence is made up of central galaxies and satellite galaxies. At all redshifts, including z = 0, the data are consistent with {approx}60% of satellite galaxies being red or quenched, implying that {approx}1/3 of the red sequence is comprised of satellite galaxies. More than three-fourths of red satellite galaxies were moved to the red sequence after they were accreted onto a larger halo. The constant fraction of satellite galaxies that are red yields a quenching time for satellite galaxies that depends on redshift in the same way as halo dynamical times: t{sub Q} {approx} (1 + z){sup -1.5}. In three of the four samples, the data favor a model in which red central galaxies are a random sample of all central galaxies; there is no preferred halo mass scale at which galaxies make the transition from star-forming to red and dead. The large errors on the fourth sample inhibit any conclusions. Theoretical models in which star formation is quenched above a critical halo mass are excluded by these data. A scenario in which mergers create red central galaxies imparts a weaker correlation between halo mass and central galaxy color, but even the merger scenario creates tension with red galaxy clustering at redshifts above 0.5. These results suggest that the mechanism by which central galaxies become red evolves from z = 0.5 to z = 0.

  20. Red Lake Band of Chippewa Indians- 2005 Project

    Broader source: Energy.gov [DOE]

    Nearly 60% of the 1,621 housing units on the reservation lack adequate insulation, ventilation, and efficient and safe furnaces and appliances. The project will achieve the following objectives: (1) to enhance tribal member energy expertise for reducing tribal energy consumption and for implementing energy efficiency measures, (2) to increase the tribe's capacity to secure additional funding for energy conservation, including state-sponsored investments, and (3) to create significant energy savings in tribal homes and promote economic and environmental opportunities to sustain Red Lake.

  1. The digital trigger system for the RED-100 detector

    SciTech Connect (OSTI)

    Naumov, P. P. Akimov, D. Yu.; Belov, V. A.; Bolozdynya, A. I.; Efremenko, Yu. V.; Kaplin, V. A.

    2015-12-15

    The system for forming a trigger for the liquid xenon detector RED-100 is developed. The trigger can be generated for all types of events that the detector needs for calibration and data acquisition, including the events with a single electron of ionization. In the system, a mechanism of event detection is implemented according to which the timestamp and event type are assigned to each event. The trigger system is required in the systems searching for rare events to select and keep only the necessary information from the ADC array. The specifications and implementation of the trigger unit which provides a high efficiency of response even to low-energy events are considered.

  2. Cosmological information in the intrinsic alignments of luminous red galaxies

    SciTech Connect (OSTI)

    Chisari, Nora Elisa; Dvorkin, Cora E-mail: cdvorkin@ias.edu

    2013-12-01

    The intrinsic alignments of galaxies are usually regarded as a contaminant to weak gravitational lensing observables. The alignment of Luminous Red Galaxies, detected unambiguously in observations from the Sloan Digital Sky Survey, can be reproduced by the linear tidal alignment model of Catelan, Kamionkowski and Blandford (2001) on large scales. In this work, we explore the cosmological information encoded in the intrinsic alignments of red galaxies. We make forecasts for the ability of current and future spectroscopic surveys to constrain local primordial non-Gaussianity and Baryon Acoustic Oscillations (BAO) in the cross-correlation function of intrinsic alignments and the galaxy density field. For the Baryon Oscillation Spectroscopic Survey, we find that the BAO signal in the intrinsic alignments is marginally significant with a signal-to-noise ratio of 1.8 and 2.2 with the current LOWZ and CMASS samples of galaxies, respectively, and increasing to 2.3 and 2.7 once the survey is completed. For the Dark Energy Spectroscopic Instrument and for a spectroscopic survey following the EUCLID redshift selection function, we find signal-to-noise ratios of 12 and 15, respectively. Local type primordial non-Gaussianity, parametrized by f{sub NL} = 10, is only marginally significant in the intrinsic alignments signal with signal-to-noise ratios < 2 for the three surveys considered.

  3. RSE Pulp & Chemical, LLC (Subsidiary of Red Shield Environmental, LLC) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy RSE Pulp & Chemical, LLC (Subsidiary of Red Shield Environmental, LLC) RSE Pulp & Chemical, LLC (Subsidiary of Red Shield Environmental, LLC) A fact sheet detailling a proposal of a biorefinery facility in an existing pulp mill to demonstrate the production of cellulosic ethanol from lignocellulosic (wood) extract. RSE Pulp & Chemical, LLC (Subsidiary of Red Shield Environmental, LLC) (19.31 KB) More Documents & Publications Pacific Ethanol, Inc EA-1888:

  4. Measurement of interaction forces between red blood cells in aggregates by optical tweezers

    SciTech Connect (OSTI)

    Maklygin, A Yu; Priezzhev, A V; Karmenian, A; Nikitin, Sergei Yu; Obolenskii, I S; Lugovtsov, Andrei E; Kisun Li

    2012-06-30

    We have fabricated double-beam optical tweezers and demonstrated the possibility of their use for measuring the interaction forces between red blood cells (erythrocytes). It has been established experimentally that prolonged trapping of red blood cells in a tightly focused laser beam does not cause any visible changes in their shape or size. We have measured the interaction between red blood cells in the aggregate, deformed by optical tweezers.

  5. Measuring skewness of red blood cell deformability distribution by laser ektacytometry

    SciTech Connect (OSTI)

    Nikitin, S Yu; Priezzhev, A V; Lugovtsov, A E; Ustinov, V D

    2014-08-31

    An algorithm is proposed for measuring the parameters of red blood cell deformability distribution based on laser diffractometry of red blood cells in shear flow (ektacytometry). The algorithm is tested on specially prepared samples of rat blood. In these experiments we succeeded in measuring the mean deformability, deformability variance and skewness of red blood cell deformability distribution with errors of 10%, 15% and 35%, respectively. (laser biophotonics)

  6. Department of Energy Offers $245 Million Conditional Loan Guarantee to Red

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    River Environmental Products | Department of Energy 45 Million Conditional Loan Guarantee to Red River Environmental Products Department of Energy Offers $245 Million Conditional Loan Guarantee to Red River Environmental Products December 9, 2009 - 12:00am Addthis Washington, DC - Energy Secretary Steven Chu today announced the offer of a $245 million conditional loan guarantee to Red River Environmental Products, LLC to build an activated carbon (AC) manufacturing facility near Coushatta,

  7. U-159: Red Hat Enterprise MRG Messaging Qpid Bug Lets Certain Remote Users Bypass Authentication

    Broader source: Energy.gov [DOE]

    A vulnerability was reported in Red Hat Enterprise MRG Messaging. A remote user can access cluster messages and view the internal configuration.

  8. From: Meredith Brown Subject: Red Alert: Contaminatio...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Meredith Brown Subject: Red Alert: Contamination Spread Outside of RCAs ... Priority Descriptor: REDUrgent (based on the actual spread of contamination offsite) ...

  9. V-233: Red Hat update for JBoss Fuse | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3: Red Hat update for JBoss Fuse V-233: Red Hat update for JBoss Fuse September 3, 2013 - 6:00am Addthis PROBLEM: Red Hat has issued an update for JBoss Fuse PLATFORM: Red Hat JBoss Fuse 6.x ABSTRACT: This fixes multiple vulnerabilities, which can be exploited by malicious people to bypass certain security restrictions and cause a DoS. REFERENCE LINKS: Secunia Advisory SA54683 Redhat Advisory RHSA-2013:1185-1 CVE-2013-0269 CVE-2013-1768 CVE-2013-1821 CVE-2013-2160 IMPACT ASSESSMENT: Medium

  10. Energy Department Invests $12 Million to Slash Red Tape and Speed...

    Energy Savers [EERE]

    once again by 2020, the Energy Department today announced eight teams to spur solar power deployment by cutting red tape for residential and small commercial rooftop solar systems. ...

  11. Characterization of trace elements and radionuclides and their risk assessment in red mud

    SciTech Connect (OSTI)

    Akinci, Akin; Artir, Recep

    2008-04-15

    Red mud is a waste and tail material from primary aluminum production, and is named for its color, coming from its iron oxide content. The quantity of red mud is almost equal to the primary aluminum production and leads to a considerable environmental issue. Red mud of the ETI Seydisehir Aluminum Plant is considered as detrimental waste for storage due to its content of various metal oxides, elements and caustics. This detrimental effect is classified into two groups: first, environmental health and second, the cost of storage. In order to minimize the negative effect of red mud, there have been or are presently many investigations carried out on usage of red mud in building materials. However, no effective way of utilizing red mud has yet been found. In this study domestic red mud was investigated and chemical analyses were performed by EDAX and XRF techniques. Radioactivity of the samples was also measured with gamma spectroscopy. The concentrations of elemental Na, Al, Si, Ca, Ti, Fe, S and K were determined by EDAX and XRF. In addition, Cr, Zr, Sr, Ni and Y were also identified as impurities. According to gamma spectroscopy results radium, uranium, thorium and potassium were determined as radioactive elements. It was observed that the amounts of the radioactive elements present in the red mud are within safe limits. Therefore, if domestic red mud originated from Seydisehir could be utilized as reinforcement material in composites, and in building materials, it can be considered safe in terms of environmental and human health.

  12. Evaluation of biological treatment of pharmaceutical wastewater with pac addition. Project summary

    SciTech Connect (OSTI)

    Gardner, D.A.; Osantowski, R.A.

    1988-07-01

    The purposes of the study were to: (1) attempt to find the cause of the formation of the viscous floating mass of mixed liquor solids (VFMLS), (2) generate additional research data for total chemical oxygen demand (TCOD) removal from pharmaceutical wastewater using the PACT process, (3) evaluate the efficiency of PACT in removing specific organics, (4) evaluate the effectiveness of PACT in reducing effluent aquatic toxicity, and (5) evaluate the use of a selector to improve the settling characteristics of the mixed liquor. One control unit, two PACT units, and a unit equipped with a series of selector basins were operated.

  13. Table 3.6 Selected Wood and Wood-Related Products in Fuel Consumption, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 3.6 Selected Wood and Wood-Related Products in Fuel Consumption, 2010; Level: National and Regional Data; Row: Selected NAICS Codes; Column: Energy Sources; Unit: Trillion Btu. Wood Residues and Wood-Related Pulping Liquor Wood Byproducts and NAICS or Biomass Agricultural Harvested Directly from Mill Paper-Related Code(a) Subsector and Industry Black Liquor Total(b) Waste(c) from Trees(d) Processing(e) Refuse(f) Total United States 311 Food 0 44 43 * * 1 311221 Wet Corn Milling 0 1 1 0 0 0

  14. Other States Natural Gas Coalbed Methane, Reserves Based Production

    Gasoline and Diesel Fuel Update (EIA)

    August 2009 Revised: October 2009 Next MECS will be conducted in 2010 Table 3.5 Selected Byproducts in Fuel Consumption, 2006; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Trillion Btu. Waste Blast Pulping Liquor Oils/Tars NAICS Furnace/Coke Petroleum or Wood Chips, and Waste Code(a) Subsector and Industry Total Oven Gases Waste Gas Coke Black Liquor Bark Materials Total United States 311 Food 10 0 3 0 0 7 Q 3112 Grain and Oilseed Milling 7 0 1 0 0 6 *

  15. Solvent-extraction and purification of uranium(VI) and molybdenum(VI) by tertiary amines from acid leach solutions

    SciTech Connect (OSTI)

    La Gamma, Ana M.G.; Becquart, Elena T.; Chocron, Mauricio

    2008-07-01

    Considering international interest in the yellow-cake price, Argentina is seeking to exploit new uranium ore bodies and processing plants. A study of similar plants would suggest that solvent- extraction with Alamine 336 is considered the best method for the purification and concentration of uranium present in leaching solutions. In order to study the purification of these leach liquors, solvent-extraction tests under different conditions were performed with simulated solutions which containing molybdenum and molybdenum-uranium mixtures. Preliminary extraction tests carried out on mill acid-leaching liquors are also presented. (authors)

  16. Process for producing fuel grade ethanol by continuous fermentation, solvent extraction and alcohol separation

    DOE Patents [OSTI]

    Tedder, Daniel W.

    1985-05-14

    Alcohol substantially free of water is prepared by continuously fermenting a fermentable biomass feedstock in a fermentation unit, thereby forming an aqueous fermentation liquor containing alcohol and microorganisms. Continuously extracting a portion of alcohol from said fermentation liquor with an organic solvent system containing an extractant for said alcohol, thereby forming an alcohol-organic solvent extract phase and an aqueous raffinate. Said alcohol is separated from said alcohol-organic solvent phase. A raffinate comprising microorganisms and unextracted alcohol is returned to the fermentation unit.

  17. Design, start up, and three years operating experience of an ammonia scrubbing, distillation, and destruction plant

    SciTech Connect (OSTI)

    Gambert, G.

    1996-12-31

    When the rebuilt Coke Plant started operations in November of 1992, it featured a completely new closed circuit secondary cooler, ammonia scrubbing, ammonia distillation, and ammonia destruction plants. This is the second plant of this type to be built in North America. To remove the ammonia from the gas, it is scrubbed with three liquids: Approximately 185 gallons/minute of cooled stripped liquor from the ammonia stills; Light oil plant condensate; and Optionally, excess flushing liquor. These scrubbers typically reduce ammonia content in the gas from 270 Grains/100 standard cubic feet to 0.2 Grains/100 standard cubic feet.

  18. Originally Released: August 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    August 2009 Revised: October 2009 Next MECS will be conducted in 2010 Table 3.5 Selected Byproducts in Fuel Consumption, 2006; Level: National and Regional Data; Row: NAICS Codes; Column: Energy Sources; Unit: Trillion Btu. Waste Blast Pulping Liquor Oils/Tars NAICS Furnace/Coke Petroleum or Wood Chips, and Waste Code(a) Subsector and Industry Total Oven Gases Waste Gas Coke Black Liquor Bark Materials Total United States 311 Food 10 0 3 0 0 7 Q 3112 Grain and Oilseed Milling 7 0 1 0 0 6 *

  19. Apparatus for control of mercury

    SciTech Connect (OSTI)

    Downs, William; Bailey, Ralph T.

    2001-01-01

    A method and apparatus for reducing mercury in industrial gases such as the flue gas produced by the combustion of fossil fuels such as coal adds hydrogen sulfide to the flue gas in or just before a scrubber of the industrial process which contains the wet scrubber. The method and apparatus of the present invention is applicable to installations employing either wet or dry scrubber flue gas desulfurization systems. The present invention uses kraft green liquor as a source for hydrogen sulfide and/or the injection of mineral acids into the green liquor to release vaporous hydrogen sulfide in order to form mercury sulfide solids.

  20. Microsoft Word - Pu Disposition Red Team Report.docx

    National Nuclear Security Administration (NNSA)

    Final Report of the Plutonium Disposition Red Team Date: 13 August 2015 Oak Ridge, Tennessee Thom Mason, Chair This r eport w as p repared a s a n a ccount o f w ork s ponsored b y a n a gency o f t he U nited S tates Government. N either t he U nited S tates G overnment n or any a gency t hereof, n or a ny o f t heir employees, m akes a ny w arranty, e xpress o r i mplied, o r a ssumes a ny l egal l iability o r responsibility f or t he a ccuracy, c ompleteness, o r u sefulness o f a ny i

  1. MAGNESIUM ISOTOPE RATIOS IN {omega} CENTAURI RED GIANTS

    SciTech Connect (OSTI)

    Da Costa, G. S.; Norris, John E.; Yong, David

    2013-05-20

    We have used the high-resolution observations obtained at the Anglo-Australian Telescope with Ultra-High Resolution Facility (R {approx} 100,000) and at Gemini-S with b-HROS (R {approx} 150,000) to determine magnesium isotope ratios for seven {omega} Cen red giants that cover a range in iron abundance from [Fe/H] = -1.78 to -0.78 dex, and for two red giants in M4 (NGC 6121). The {omega} Cen stars sample both the ''primordial'' (i.e., O-rich, Na- and Al-poor) and the ''extreme'' (O-depleted, Na- and Al-rich) populations in the cluster. The primordial population stars in both {omega} Cen and M4 show ({sup 25}Mg, {sup 26}Mg)/{sup 24}Mg isotopic ratios that are consistent with those found for the primordial population in other globular clusters with similar [Fe/H] values. The isotopic ratios for the {omega} Cen extreme stars are also consistent with those for extreme population stars in other clusters. The results for the extreme population stars studied indicate that the {sup 26}Mg/{sup 24}Mg ratio is highest at intermediate metallicities ([Fe/H] < -1.4 dex), and for the highest [Al/Fe] values. Further, the relative abundance of {sup 26}Mg in the extreme population stars is notably higher than that of {sup 25}Mg, in contrast to model predictions. The {sup 25}Mg/{sup 24}Mg isotopic ratio in fact does not show any obvious dependence on either [Fe/H] or [Al/Fe] nor, intriguingly, any obvious difference between the primordial and extreme population stars.

  2. Red-emitting manganese-doped aluminum nitride phosphor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cherepy, Nerine J.; Payne, Stephen A.; Harvey, Nicholas M.; Aberg, Daniel; Seeley, Zachary M.; Holliday, Kiel S.; Tran, Ich C.; Zhou, Fei; Martinez, H. Paul; Demeyer, Jessica M.; et al

    2016-02-10

    Here, we report high efficiency luminescence with a manganese-doped aluminum nitride red-emitting phosphor under 254 nm excitation, as well as its excellent lumen maintenance in fluorescent lamp conditions, making it a candidate replacement for the widely deployed europium-doped yttria red phosphor. Solid-state reaction of aluminum nitride powders with manganese metal at 1900 °C, 10 atm N2 in a reducing environment results in nitrogen deficiency, as revealed diffuse reflectance spectra. When these powders are subsequently annealed in flowing nitrogen at 1650 °C, higher nitrogen content is recovered, resulting in white powders. Silicon was added to samples as an oxygen getter tomore » improve emission efficiency. NEXAFS spectra and DFT calculations indicate that the Mn dopant is divalent. From DFT calculations, the UV absorption band is proposed to be due to an aluminum vacancy coupled with oxygen impurity dopants, and Mn2+ is assumed to be closely associated with this site. In contrast with some previous reports, we find that the highest quantum efficiency with 254 nm excitation (Q.E. = 0.86 ± 0.14) is obtained in aluminum nitride with a low manganese doping level of 0.06 mol.%. The principal Mn2+ decay of 1.25 ms is assigned to non-interacting Mn sites, while additional components in the microsecond range appear with higher Mn doping, consistent with Mn clustering and resultant exchange coupling. Slower components are present in samples with low Mn doping, as well as strong afterglow, assigned to trapping on shallow traps followed by detrapping and subsequent trapping on Mn.« less

  3. Kit for the selective labeling of red blood cells in whole blood with [sup 99]Tc

    DOE Patents [OSTI]

    Srivastava, S.C.; Babich, J.W.; Straub, R.; Richards, P.

    1992-05-26

    Disclosed herein are a method and kit for the preparation of [sup 99m]Tc labeled red blood cells using whole blood in a closed sterile system containing stannous tin in a form such that it will enter the red blood cells and be available therein for reduction of technetium. No Drawings

  4. Kit for the selective labeling of red blood cells in whole blood with .sup.9 TC

    DOE Patents [OSTI]

    Srivastava, Suresh C.; Babich, John W.; Straub, Rita; Richards, Powell

    1992-01-01

    Disclosed herein are a method and kit for the preparation of .sup.99m Tc labeled red blood cells using whole blood in a closed sterile system containing stannous tin in a form such that it will enter the red blood cells and be available therein for reduction of technetium.

  5. AmeriFlux US-Wi7 Red pine clearcut (RPCC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chen, Jiquan [Michigan State University

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-Wi7 Red pine clearcut (RPCC). Site Description - The Wisconsin Clearcut Red Pine site is located in the Washburn Ranger District of the northeastern section of Chequamegon National Forest. A member of the northern coniferous-deciduous biome, surveys from the mid-19th century indicate the region consisted of a mixed stand of red, white, and jack pines. After extensive timber harvesting, wildfires, and farming activity, the region turned into a fragmented mosaic of stands of various ages and composition. The red pine clearcut site is one of ten sites that collectively represent the successional stages of development in the predominant stand types of a physically homogeneous landscape. Thinned every 7 years until they reach 100 to 150 years of age, the red pine plantations or all ages occupy approximately 25% of the region.

  6. AmeriFlux US-Wi2 Intermediate red pine (IRP)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Chen, Jiquan [Michigan State University

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-Wi2 Intermediate red pine (IRP). Site Description - The Wisconsin Intermediate Red Pine site is located in the Washburn Ranger District of the northeastern section of Chequamegon National Forest. A member of the northern coniferous-deciduous biome, surveys from the mid-19th century indicate the region consisted of a mixed stand of red, white, and jack pines. After extensive timber harvesting, wildfires, and farming activity, the region turned into a fragmented mosaic of stands of various ages and composition. The intermediate red pine site is one of ten sites that collectively represent the successional stages of development in the predominant stand types of a physically homogeneous landscape. Thinned every 7 years until they reach 100 to 150 years of age, the red pine plantations of all ages occupy approximately 25% of the region.

  7. ARM: Shortwave Array Spectroradiometer-Hemispheric, Near-InfraRed channel, low-sun angles [a0 data is uncalibrated

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Albert Mendoza; Yan Shi; Connor Flynn

    1990-01-01

    Shortwave Array Spectroradiometer-Hemispheric, Near-InfraRed channel, low-sun angles [a0 data is uncalibrated

  8. ARM: Shortwave Array Spectroradiometer-Hemispheric, Near-InfraRed channel, high-sun angles [a0 data is uncalibrated

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Albert Mendoza; Yan Shi; Connor Flynn

    2011-03-22

    Shortwave Array Spectroradiometer-Hemispheric, Near-InfraRed channel, high-sun angles [a0 data is uncalibrated

  9. ARM: Shortwave Array Spectroradiometer-Hemispheric, Near-InfraRed channel, high-sun angles [a0 data is uncalibrated

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Albert Mendoza; Yan Shi; Connor Flynn

    Shortwave Array Spectroradiometer-Hemispheric, Near-InfraRed channel, high-sun angles [a0 data is uncalibrated

  10. ARM: Shortwave Array Spectroradiometer-Hemispheric, Near-InfraRed channel, low-sun angles [a0 data is uncalibrated

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Albert Mendoza; Yan Shi; Connor Flynn

    Shortwave Array Spectroradiometer-Hemispheric, Near-InfraRed channel, low-sun angles [a0 data is uncalibrated

  11. DRAMATIC CHANGE IN JUPITER'S GREAT RED SPOT FROM SPACECRAFT OBSERVATIONS

    SciTech Connect (OSTI)

    Simon, Amy A.; Wong, Michael H.; De Pater, Imke; Rogers, John H.; Orton, Glenn S.; Carlson, Robert W.; Asay-Davis, Xylar; Marcus, Philip S.

    2014-12-20

    Jupiter's Great Red Spot (GRS) is one of its most distinct and enduring features. Since the advent of modern telescopes, keen observers have noted its appearance and documented a change in shape from very oblong to oval, confirmed in measurements from spacecraft data. It currently spans the smallest latitude and longitude size ever recorded. Here we show that this change has been accompanied by an increase in cloud/haze reflectance as sensed in methane gas absorption bands, increased absorption at wavelengths shorter than 500nm, and increased spectral slope between 500 and 630nm. These changes occurred between 2012 and 2014, without a significant change in internal tangential wind speeds; the decreased size results in a 3.2day horizontal cloud circulation period, shorter than previously observed. As the GRS has narrowed in latitude, it interacts less with the jets flanking its north and south edges, perhaps allowing for less cloud mixing and longer UV irradiation of cloud and aerosol particles. Given its long life and observational record, we expect that future modeling of the GRS's changes, in concert with laboratory flow experiments, will drive our understanding of vortex evolution and stability in a confined flow field crucial for comparison with other planetary atmospheres.

  12. RED CLUMP STARS IN THE SAGITTARIUS TIDAL STREAMS

    SciTech Connect (OSTI)

    Carrell, Kenneth; Chen Yuqin; Wilhelm, Ronald

    2012-07-15

    We have probed a section (l {approx} 150, b {approx} -60) of the trailing tidal arm of the Sagittarius dwarf spheroidal galaxy by identifying a sample of Red Clump (RC) stream stars. RC stars are not generally found in the halo field, but are found in significant numbers in both the Sagittarius galaxy and its tidal streams, making them excellent probes of stream characteristics. Our target sample was selected using photometric data from the Sloan Digital Sky Survey, Data Release 6, which was constrained in color to match the Sagittarius RC stars. Spectroscopic observations of the target stars were conducted at Kitt Peak National Observatory using the WIYN telescope. The resulting spectroscopic sample is magnitude limited and contains both main-sequence disk stars and evolved RC stars. We have developed a method to systematically separate these two stellar classes using kinematic information and a Bayesian approach for surface gravity determination. The resulting RC sample allows us to determine an absolute stellar density of {rho} = 2.7 {+-} 0.5 RC stars kpc{sup -3} at this location in the stream. Future measurements of stellar densities for a variety of populations and at various locations along the streams will lead to a much improved understanding of the original nature of the Sagittarius galaxy and the physical processes controlling its disruption and subsequent stream generation.

  13. DISCOVERY OF SUPER-Li-RICH RED GIANTS IN DWARF SPHEROIDAL GALAXIES

    SciTech Connect (OSTI)

    Kirby, Evan N.; Fu, Xiaoting; Deng, Licai; Guhathakurta, Puragra

    2012-06-10

    Stars destroy lithium (Li) in their normal evolution. The convective envelopes of evolved red giants reach temperatures of millions of kelvin, hot enough for the {sup 7}Li(p, {alpha}){sup 4}He reaction to burn Li efficiently. Only about 1% of first-ascent red giants more luminous than the luminosity function bump in the red giant branch exhibit A(Li) > 1.5. Nonetheless, Li-rich red giants do exist. We present 15 Li-rich red giants-14 of which are new discoveries-among a sample of 2054 red giants in Milky Way dwarf satellite galaxies. Our sample more than doubles the number of low-mass, metal-poor ([Fe/H] {approx}< -0.7) Li-rich red giants, and it includes the most-metal-poor Li-enhanced star known ([Fe/H] = -2.82, A(Li){sub NLTE} = 3.15). Because most of the stars have Li abundances larger than the universe's primordial value, the Li in these stars must have been created rather than saved from destruction. These Li-rich stars appear like other stars in the same galaxies in every measurable regard other than Li abundance. We consider the possibility that Li enrichment is a universal phase of evolution that affects all stars, and it seems rare only because it is brief.

  14. Characterization of red mud-epoxy intumescent char using surface imaging and micro analysis

    SciTech Connect (OSTI)

    Arogundade, A. I. Megat-Yusoff, P. S. M. Faiz, A.; Bhat, A. H.

    2015-07-22

    In this study, red mud (RM), an oxide waste was proposed as reinforcing, synergistic filler for the traditional epoxy intumescent coating (IC). 5.5 wt% of acid-modified and unmodified red mud were introduced into the basic intumescent formulation of ammonium polyphosphate (APP), pentaerythritol (PER) and melamine (MEL). In order to predict effect of modification on its suitability, Field emission electron scanning microscopy and Fourier transform infra red were used to obtain detailed characteristics such as the cell size, pore distribution, homogeneity and chemical composition of the red mud-epoxy carbonaceous char. Both acid-modified and unmodified RM-filled ICs produced chars with smaller and more closely packed cells compared to chars from the unfilled coating. Both coating types had hard carbonaceous metal phosphate coverings that could act as heat barriers. The unmodified red mud was found to be antagonistic to the intumescent action with an expansion of only 2 times the initial thickness. The leached, low iron-red mud produced an expansion of 15 times the initial thickness, but possessed a hollow interior. From these findings, it may be deduced that while acid leaching of red mud may improve intumescent expansion, it would be necessary to optimize the percent filler loading to improve residual mass.

  15. EERE Success Story-Nationwide: Slashing Red Tape To Speed Solar

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deployment for Homes and Businesses | Department of Energy Slashing Red Tape To Speed Solar Deployment for Homes and Businesses EERE Success Story-Nationwide: Slashing Red Tape To Speed Solar Deployment for Homes and Businesses January 24, 2014 - 12:00am Addthis EERE Success Story—Nationwide: Slashing Red Tape To Speed Solar Deployment for Homes and Businesses While solar panels, inverters and other hardware are more affordable than ever before (the average cost of solar PV panels has

  16. The Red Storm Architecture and Early Experiences with Multi-core Processors

    SciTech Connect (OSTI)

    Tomkins, James L; Brightwell, Ron; Camp, William J; Dosanjh, Sudip; Kelly, Suzanne M; Lin, Paul T.; Vaughan, Courtenay T.; Levesque, John; Tipparaju, Vinod

    2010-01-01

    The Red Storm architecture, which was conceived by Sandia National Laboratories and implemented by Cray, Inc., has become the basis for most successful line of commercial supercomputers in history. The success of the Red Storm architecture is due largely to the ability to effectively and efficiently solve a wide range of science and engineering problems. The Cray XT series of machines that embody the Red Storm architecture have allowed for unprecedented scaling and performance of parallel applications spanning many areas of scientific computing. In this paper, we describe the fundamental characteristics of the architecture and its implementation that have enabled this success, even through successive generations of hardware and software.

  17. Microsoft Word - RedSeal_Smart Grid Policy Logistics RFI-sd.docx

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on Smart Grid RFI RedSeal Systems, Inc. 1 October 29, 2010 Office of Electricity Delivery and Energy Reliability US Department of Energy Room 8H033 1000 Independence Avenue, SW Washington, DC 20585 Re: Comments on "Smart Grid RFI: Addressing Policy and Logistical Challenges" 75 FR 57006 [FR Doc. 2010-23251] From: Steve Dauber Vice-President, Marketing RedSeal Systems 2121 South El Camino Real, Suite 300 San Mateo, CA 94403 Ph: 650-645-6209 sdauber@redseal.net www.redseal.net RedSeal

  18. Method for extending the useful shelf-life of refrigerated red blood cells by flushing with inert gas

    DOE Patents [OSTI]

    Bitensky, M.W.; Yoshida, Tatsuro

    1997-04-29

    A method is disclosed using oxygen removal for extending the useful shelf-life of refrigerated red blood cells. A cost-effective, 4 C storage procedure that preserves red cell quality and prolongs post-transfusion in vivo survival is described. Preservation of adenosine triphosphate levels and reduction in hemolysis and in membrane vesicle production of red blood cells stored at 4 C for prolonged periods of time is achieved by removing oxygen from the red blood cells at the time of storage; in particular, by flushing with an inert gas. Adenosine triphosphate levels of the stored red blood cells are boosted in some samples by addition of ammonium phosphate. 4 figs.

  19. Availability and abundance of prey for the red-cockaded woodpecker.

    SciTech Connect (OSTI)

    Hanula, James, L.; Horn, Scott.

    2004-12-31

    Red-cockaded woodpecker; Road to Recovery. Proceedings of the 4th Red-cockaded woodpecker Symposium. Ralph Costa and Susan J. Daniels, eds. Savannah, Georgia. January, 2003. Chapter 11. Prey, Fire, and Community Ecology. Pp 633-645. Abstract: Over a 10-year period we investigated red-cockaded woodpecker (Picoides borealis) prey use, sources of prey, prey distribution within trees and stands, and how forest management decisions affect prey abundance in South Carolina, Alabama, Georgia and Florida. Cameras were operated at 31 nest cavities to record nest visits with prey in 4 locations that ranged in foraging habitat from pine stands established in old fields to an old-growth stand in South Georgia. Examination of nearly 12,000 photographs recorded over 5 years revealed that, although red-cockaded woodpeckers used over 40 arthropods for food, the majority of the nestling diet is comprised of a relatively small number of common arthropods.

  20. The Red Storm Architecture and Early Experiences With Multi-Core...

    Office of Scientific and Technical Information (OSTI)

    With Multi-Core Processors Citation Details In-Document Search Title: The Red Storm Architecture and Early Experiences With Multi-Core Processors Authors: Tomkins, James L 1 ; ...

  1. Color stable white phosphorescent organic light emitting diodes with red emissive electron transport layer

    SciTech Connect (OSTI)

    Wook Kim, Jin; Yoo, Seung Il; Sung Kang, Jin; Eun Lee, Song; Kwan Kim, Young; Hwa Yu, Hyeong; Turak, Ayse; Young Kim, Woo

    2015-06-28

    We analyzed the performance of multi-emissive white phosphorescent organic light-emitting diodes (PHOLEDs) in relation to various red emitting sites of hole and electron transport layers (HTL and ETL). The shift of the recombination zone producing stable white emission in PHOLEDs was utilized as luminance was increased with red emission in its electron transport layer. Multi-emissive white PHOLEDs including the red light emitting electron transport layer yielded maximum external quantum efficiency of 17.4% with CIE color coordinates (−0.030, +0.001) shifting only from 1000 to 10 000 cd/m{sup 2}. Additionally, we observed a reduction of energy loss in the white PHOLED via Ir(piq){sub 3} as phosphorescent red dopant in electron transport layer.

  2. AmeriFlux US-Wi0 Young red pine (YRP)

    SciTech Connect (OSTI)

    Chen, Jiquan

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-Wi0 Young red pine (YRP). Site Description - The Wisconsin Young Red Pine site is located in the Washburn Ranger District of the northeastern section of Chequamegon National Forest. A member of the northern coniferous-deciduous biome, surveys from the mid-19th century indicate the region consisted of a mixed stand of red, white, and jack pines. After extensive timber harvesting, wildfires, and farming activity, the region turned into a fragmented mosaic of stands of various ages and composition. As an assemblage, the ten Wisconsin sites are indicative of the successional stages of development in the predominant stand types of a physically homogeneous landscape. Thinned every 7 years until they reach 100 to 150 years of age, the red pine plantations of all ages occupy approximately 25% of the region.

  3. AmeriFlux US-Wi4 Mature red pine (MRP)

    SciTech Connect (OSTI)

    Chen, Jiquan

    2016-01-01

    This is the AmeriFlux version of the carbon flux data for the site US-Wi4 Mature red pine (MRP). Site Description - The Wisconsin Mature Red Pine site is located in the Washburn Ranger District of the northeastern section of Chequamegon National Forest. A member of the northern coniferous-deciduous biome, surveys from the mid-19th century indicate the region consisted of a mixed stand of red, white, and jack pines. After extensive timber harvesting, wildfires, and farming activity, the region turned into a fragmented mosaic of stands of various ages and composition. As an assemblage, the ten Wisconsin sites are indicative of the successional stages of development in the predominant stand types of a physically homogeneous landscape. Thinned every 7 years until they reach 100 to 150 years of age, the red pine plantations of all ages occupy approximately 25% of the region.

  4. EVOLUTION OF GROUP GALAXIES FROM THE FIRST RED-SEQUENCE CLUSTER SURVEY

    SciTech Connect (OSTI)

    Li, I. H.; Yee, H. K. C.; Hsieh, B. C.; Gladders, M. E-mail: hyee@astro.utoronto.ca E-mail: gladders@oddjob.uchicago.edu

    2012-04-20

    We study the evolution of the red-galaxy fraction (f{sub red}) in 905 galaxy groups with 0.15 {<=} z < 0.52. The galaxy groups are identified by the 'probability friends-of-friends' algorithm from the first Red-Sequence Cluster Survey (RCS1) photometric-redshift sample. There is a high degree of uniformity in the properties of the red sequence of the group galaxies, indicating that the luminous red-sequence galaxies in the groups are already in place by z {approx} 0.5 and that they have a formation epoch of z {approx}> 2. In general, groups at lower redshifts exhibit larger f{sub red} than those at higher redshifts, showing a group Butcher-Oemler effect. We investigate the evolution of f{sub red} by examining its dependence on four parameters, one of which can be classified as intrinsic and three of which can be classified as environmental: galaxy stellar mass (M{sub *}), total group stellar mass (M{sub *,grp}, a proxy for group halo mass), normalized group-centric radius (r{sub grp}), and local galaxy density ({Sigma}{sub 5}). We find that M{sub *} is the dominant parameter such that there is a strong correlation between f{sub red} and galaxy stellar mass. Furthermore, the dependence of f{sub red} on the environmental parameters is also a strong function of M{sub *}. Massive galaxies (M{sub *} {approx}> 10{sup 11} M{sub Sun }) show little dependence of f{sub red} on r{sub grp}, M{sub *,grp}, and {Sigma}{sub 5} over the redshift range. The dependence of f{sub red} on these parameters is primarily seen for galaxies with lower masses, especially for M{sub *} {approx}< 10{sup 10.6} M{sub Sun }. We observe an apparent 'group down-sizing' effect, in that galaxies in lower-mass halos, after controlling for galaxy stellar mass, have lower f{sub red}. We find a dependence of f{sub red} on both r{sub grp} and {Sigma}{sub 5} after the other parameters are controlled. At a fixed r{sub grp}, there is a significant dependence of f{sub red} on {Sigma}{sub 5}, while r{sub grp

  5. Redding Regional High School Science Bowl | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Redding Regional High School Science Bowl National Science Bowl® (NSB) NSB Home About Regional Competitions Rules, Forms, and Resources High School Regionals Middle School Regionals National Finals Volunteers Key Dates Frequently Asked Questions News Media Contact Us WDTS Home Contact Information National Science Bowl® U.S. Department of Energy SC-27/ Forrestal Building 1000 Independence Ave., SW Washington, DC 20585 E: Email Us High School Regionals Redding Regional High School Science Bowl

  6. Redding Regional Middle School Science Bowl | U.S. DOE Office of Science

    Office of Science (SC) Website

    (SC) Redding Regional Middle School Science Bowl National Science Bowl® (NSB) NSB Home About Regional Competitions Rules, Forms, and Resources High School Regionals Middle School Regionals National Finals Volunteers Key Dates Frequently Asked Questions News Media Contact Us WDTS Home Contact Information National Science Bowl® U.S. Department of Energy SC-27/ Forrestal Building 1000 Independence Ave., SW Washington, DC 20585 E: Email Us Middle School Regionals Redding Regional Middle School

  7. EVMS Training Snippet: 5.7 PARSII Analysis: OAPM Red Yellow Report |

    Office of Environmental Management (EM)

    Department of Energy 7 PARSII Analysis: OAPM Red Yellow Report EVMS Training Snippet: 5.7 PARSII Analysis: OAPM Red Yellow Report This EVMS Training Snippet, sponsored by the Office of Project Management (PM) is one in a series regarding PARS II Analysis reports. PARS II offers direct insight into EVM project data from the contractor's internal systems. The reports were developed with the users in mind, organized and presented in an easy to follow manner, with analysis results and key

  8. Energy Department Invests $12 Million to Slash Red Tape and Speed Solar

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deployment for Homes and Businesses | Department of Energy 2 Million to Slash Red Tape and Speed Solar Deployment for Homes and Businesses Energy Department Invests $12 Million to Slash Red Tape and Speed Solar Deployment for Homes and Businesses November 6, 2013 - 8:30am Addthis News Media Contact (202) 586-4940 WASHINGTON - As part of the Obama Administration's efforts to ensure America's continued leadership in clean energy and double renewable electricity generation once again by 2020,

  9. Red & Black Ball raises nearly $82,000 for youth

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Red & Black Ball raises $81,000 for youth Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue: September 1, 2016 all issues All Issues » submit Red & Black Ball raises nearly $82,000 for youth The Family YMCA receives windfall for Española and Los Alamos teen centers. April 4, 2016 From left: LANL Government Affairs Office Director Patrick Woehrle, LANL Community Programs Office Director Kathy Keith, Laboratory Director Charles

  10. Red-Emitting Phosphors for Solid-State Lighting - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Technologies Industrial Technologies Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Red-Emitting Phosphors for Solid-State Lighting Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (851 KB) Technology Marketing SummarySandia has developed red-emitting phosphors that will help to transform the cold blue of many current light-emitting diodes

  11. Generator-absorber-heat exchange heat transfer apparatus and method and use thereof in a heat pump

    DOE Patents [OSTI]

    Phillips, B.A.; Zawacki, T.S.

    1998-07-21

    Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use, as the heat transfer medium, the working fluid of the absorption system taken from the generator at a location where the working fluid has a rich liquor concentration. 5 figs.

  12. Generator-absorber-heat exchange heat transfer apparatus and method and use thereof in a heat pump

    DOE Patents [OSTI]

    Phillips, Benjamin A.; Zawacki, Thomas S.

    1998-07-21

    Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use, as the heat transfer medium, the working fluid of the absorption system taken from the generator at a location where the working fluid has a rich liquor concentration.

  13. Generator-absorber-heat exchange heat transfer apparatus and method and use thereof in a heat pump

    DOE Patents [OSTI]

    Phillips, Benjamin A.; Zawacki, Thomas S.

    1996-12-03

    Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use the working solution of the absorption system for the heat transfer medium. A combination of weak and rich liquor working solution is used as the heat transfer medium.

  14. Recovering metals from spent hydroprocessing catalysts

    SciTech Connect (OSTI)

    Hubred, G. L.; Van Leirshurg, D. A.

    1985-02-19

    A process for recovering the metal values from spent hydroprocessing catalyst particles. The metal values will include at least one metal of Group VIII of the Periodic Table and at least one metal of Group Vb or Group VIb of the Periodic Table. The spent catalyst particles are first roasted at between 400/sup 0/ C. and 600/sup 0/ C. and then contacted with a first aqueous solution of ammonia and an ammonium salt forming a first pregnant liquor. The once-leached spent hydroprocessing catalysts are contacted with a second aqueous solution of sulfur dioxide forming a second pregnant liquor. The metal values are precipitated from the second pregnant liquor with hydrogen sulfide and the precipitate is roasted with unroasted spent hydroprocessing catalysts. The metal values of Group Vb and Group VIb in the first pregnant liquor are transferred into a first organic solution by liquid ion exchange. The first organic solution is stripped by an aqueous strip solution and the metal values separated by sequential precipitation. The metals of Group VIII are separated and purified by serial liquid ion exchange.

  15. SUPERNOVA 2008bk AND ITS RED SUPERGIANT PROGENITOR

    SciTech Connect (OSTI)

    Van Dyk, Schuyler D.; Elias-Rosa, Nancy [Spitzer Science Center/Caltech, Mailcode 220-6, Pasadena, CA 91125 (United States); Davidge, Tim J., E-mail: vandyk@ipac.caltech.edu, E-mail: tim.davidge@nrc.ca [Herzberg Institute of Astrophysics, National Research Council of Canada, Victoria, B.C., V9E 2E7 (Canada); and others

    2012-01-15

    We have obtained limited photometric and spectroscopic data for supernova (SN) 2008bk in NGC 7793, primarily at {approx}> 150 days after explosion. We find that it is a Type II-Plateau (II-P) SN that most closely resembles the low-luminosity SN 1999br in NGC 4900. Given the overall similarity between the observed light curves and colors of SNe 2008bk and 1999br, we infer that the total visual extinction to SN 2008bk (A{sub V} = 0.065 mag) must be almost entirely due to the Galactic foreground, similar to what has been assumed for SN 1999br. We confirm the identification of the putative red supergiant (RSG) progenitor star of the SN in high-quality g'r'i' images we had obtained in 2007 at the Gemini-South 8 m telescope. Little ambiguity exists in this progenitor identification, qualifying it as the best example to date, next to the identification of the star Sk -69 Degree-Sign 202 as the progenitor of SN 1987A. From a combination of photometry of the Gemini images with that of archival, pre-SN, Very Large Telescope JHK{sub s} images, we derive an accurate observed spectral energy distribution (SED) for the progenitor. We find from nebular strong-intensity emission-line indices for several H II regions near the SN that the metallicity in the environment is likely subsolar (Z Almost-Equal-To 0.6 Z{sub Sun }). The observed SED of the star agrees quite well with synthetic SEDs obtained from model RSG atmospheres with effective temperature T{sub eff} = 3600 {+-} 50 K. We find, therefore, that the star had a bolometric luminosity with respect to the Sun of log (L{sub bol}/L{sub Sun} ) = 4.57 {+-} 0.06 and radius R{sub *} = 496 {+-} 34 R{sub Sun} at {approx}6 months prior to explosion. Comparing the progenitor's properties with theoretical massive-star evolutionary models, we conclude that the RSG progenitor had an initial mass in the range of 8-8.5 M{sub Sun }. This mass is consistent with, albeit at the low end of, the inferred range of initial masses for SN II

  16. Anomalously Large Polarization Effect Responsible for Excitonic Red Shifts in PbSe Quantum Dot Solids

    SciTech Connect (OSTI)

    A Wolcott; V Doyeux; C Nelson; R Gearba; K Lei; K Yager; A dolocan; K Williams; D Nguyen; X Zhu

    2011-12-31

    The formation of solid thin films from colloidal semiconductor quantum dots (QDs) is often accompanied by red shifts in excitonic transitions, but the mechanisms responsible for the red shifts are under debate. We quantitatively address this issue using optical absorption spectroscopy of two-dimensional (2D) and three-dimensional (3D) arrays of PbSe QDs with controlled inter-QD distance, which was determined by the length of alkanedithiol linking molecules. With decreasing inter-QD distance, the first and second exciton absorption peaks show increasing red shifts. Using thin films consisting of large and isolated QDs embedded in a matrix of small QDs, we determine that a dominant contribution to the observed red shift is due to changes in polarization of the dielectric environment surrounding each QD ({approx}88%), while electronic or transition dipole coupling plays a lesser role. However, the observed red shifts are more than 1 order of magnitude larger than theoretical predictions based on the dielectric polarization effect for spherical QDs. We attribute this anomalously large polarization effect to deviations of the exciton wave functions from eigenfunctions of the idealized spherical quantum well model.

  17. THE SIZE DIFFERENCE BETWEEN RED AND BLUE GLOBULAR CLUSTERS IS NOT DUE TO PROJECTION EFFECTS

    SciTech Connect (OSTI)

    Webb, Jeremy J.; Harris, William E.; Sills, Alison

    2012-11-10

    Metal-rich (red) globular clusters in massive galaxies are, on average, smaller than metal-poor (blue) globular clusters. One of the possible explanations for this phenomenon is that the two populations of clusters have different spatial distributions. We test this idea by comparing clusters observed in unusually deep, high signal-to-noise images of M87 with a simulated globular cluster population in which the red and blue clusters have different spatial distributions, matching the observations. We compare the overall distribution of cluster effective radii as well as the relationship between effective radius and galactocentric distance for both the observed and simulated red and blue sub-populations. We find that the different spatial distributions does not produce a significant size difference between the red and blue sub-populations as a whole or at a given galactocentric distance. These results suggest that the size difference between red and blue globular clusters is likely due to differences during formation or later evolution.

  18. Enhanced visible light photocatalytic property of red phosphorus via surface roughening

    SciTech Connect (OSTI)

    Li, Weibing; Yue, Jiguang; Hua, Fangxia; Feng, Chang; Bu, Yuyu; Chen, Zhuoyuan

    2015-10-15

    Highlights: • Photocatalytic RhB degradation of red phosphorus was studied for the first time. • Surface rough can increase the photocatalysis reaction active sites. • Surface rough red phosphorus possesses high photocatalytic performance. • Surface rough red phosphorus has high industrial application value. - Abstract: Red phosphorus with rough surface (SRP) was prepared by catalyst-assisted hydrothermal synthesis using Co{sup 2+} catalyst. The photocatalytic Rhodamine B (RhB) degradation of red phosphorus (RP) and SRP was studied for the first time in this work. Rough surface can enhance the dye adsorption ability of RP. About 75% RhB was absorbed by SRP after 30-min adsorption in 100 ml RhB solution with concentration of 10 mg l{sup −1} in dark. After only 10 min of illumination by visible light, more than 95% RhB was degraded, indicating that SRP has a great application potential in the area of photocatalysis. The photocatalytic RhB degradation properties of RP are much weaker than those of SRP. The increase of the number of the active sites for the photocatalytic reactions, the electron mobility and the lifetime of the photogenerated electrons cause the significant improvement of the photocatalytic performance of SRP based on the experimental results obtained.

  19. Tracing recent star formation of red early-type galaxies out to z ∼ 1

    SciTech Connect (OSTI)

    Ko, Jongwan; Lee, Jong Chul; Hwang, Ho Seong; Im, Myungshin; Le Borgne, Damien; Elbaz, David

    2014-08-20

    We study the mid-infrared (IR) excess emission of early-type galaxies (ETGs) on the red sequence at z < 1 using a spectroscopic sample of galaxies in the fields of Great Observatories Origins Deep Survey (GOODS). In the mass-limited sample of 1025 galaxies with M {sub star} > 10{sup 10.5} M {sub ☉} and 0.4 < z < 1.05, we identify 696 Spitzer 24 μm detected (above the 5σ) galaxies and find them to have a wide range of NUV-r and r-[12 μm] colors despite their red optical u – r colors. Even in the sample of very massive ETGs on the red sequence with M {sub star} > 10{sup 11.2} M {sub ☉}, more than 18% show excess emission over the photospheric emission in the mid-IR. The combination with the results of red ETGs in the local universe suggests that the recent star formation is not rare among quiescent, red ETGs at least out to z ∼ 1 if the mid-IR excess emission results from intermediate-age stars or/and from low-level ongoing star formation. Our color-color diagram including near-UV and mid-IR emissions are efficient not only for identifying ETGs with recent star formation, but also for distinguishing quiescent galaxies from dusty star-forming galaxies.

  20. Red Lake Band of Chippewa Indians - First Steps Toward an Energy Efficient Future and MAP Biomass Project

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    OVERVIEW To develop the capacity to conduct energy audits Implement energy efficiency measures into Tribal homes Develop a Tribally administered Energy Efficiency Program and business PROJECT PARTICIPANTS Red Lake Housing Employees Energy Cents Coalition Staff Red Lake Band Members RELEVANT BACKGROUND INFORMATION The Red Lake Band of Chippewa Indians recognizes the need to develop a more sustainable, affordable and autonomous energy future for Tribal members Nearly 60% of the 1,621 housing units

  1. U-230: Sudo on Red Hat Enterprise Linux %postun Symlink Flaw Lets Local Users Gain Elevated Privileges

    Office of Energy Efficiency and Renewable Energy (EERE)

    An updated sudo package that fixes one security issue and several bugs is now available for Red Hat Enterprise Linux 5.

  2. U-217: Red Hat Certificate System Bugs Let Remote Users Conduct Cross-Site Scripting and Denial of Service Attacks

    Office of Energy Efficiency and Renewable Energy (EERE)

    Two vulnerabilities were reported in Red Hat Certificate System. A remote user can conduct cross-site scripting attacks. A remote authenticated user can revoke the CA certificate.

  3. Method for extending the useful shelf-life of refrigerated red blood cells by flushing with inert gas

    DOE Patents [OSTI]

    Bitensky, Mark W.; Yoshida, Tatsuro

    1997-01-01

    Method using oxygen removal for extending the useful shelf-life of refrigerated red blood cells. A cost-effective, 4.degree. C. storage procedure that preserves red cell quality and prolongs post-transfusion in vivo survival is described. Preservation of adenosine triphosphate levels and reduction in hemolysis and in membrane vesicle production of red blood cells stored at 4.degree. C. for prolonged periods of time is achieved by removing oxygen therefrom at the time of storage; in particular, by flushing with an inert gas. Adenosine triphosphate levels of the stored red blood cells are boosted in some samples by addition of ammonium phosphate.

  4. Prolonged cold storage of red blood cells by oxygen removal and additive usage

    DOE Patents [OSTI]

    Bitensky, M.W.; Yoshida, Tatsuro

    1998-08-04

    Prolonged cold storage of red blood cells by oxygen removal and additive usage. A cost-effective, 4 C storage procedure that preserves red cell quality and prolongs post-transfusion in vivo survival is described. The improved in vivo survival and the preservation of adenosine triphosphate levels, along with reduction in hemolysis and membrane vesicle production of red blood cells stored at 4 C for prolonged periods of time, is achieved by reducing the oxygen level therein at the time of storage; in particular, by flushing the cells with an inert gas, and storing them in an aqueous solution which includes adenine, dextrose, mannitol, citrate ion, and dihydrogen phosphate ion, but no sodium chloride, in an oxygen-permeable container which is located in an oxygen-free environment containing oxygen-scavenging materials. 8 figs.

  5. Prolonged cold storage of red blood cells by oxygen removal and additive usage

    DOE Patents [OSTI]

    Bitensky, Mark W.; Yoshida, Tatsuro

    1998-01-01

    Prolonged cold storage of red blood cells by oxygen removal and additive usage. A cost-effective, 4.degree. C. storage procedure that preserves red cell quality and prolongs post-transfusion in vivo survival is described. The improved in vivo survival and the preservation of adenosine triphosphate levels, along with reduction in hemolysis and membrane vesicle production of red blood cells stored at 4.degree. C. for prolonged periods of time, is achieved by reducing the oxygen level therein at the time of storage; in particular, by flushing the cells with an inert gas, and storing them in an aqueous solution which includes adenine, dextrose, mannitol, citrate ion, and dihydrogen phosphate ion, but no sodium chloride, in an oxygen-permeable container which is located in an oxygen-free environment containing oxygen-scavenging materials.

  6. Hydrothermal synthesis and characteristics of anions-doped calcium molybdate red powder phosphors

    SciTech Connect (OSTI)

    Shi, Shikao; Zhang, Yan; Liu, Qing; Zhou, Ji

    2013-10-15

    Graphical abstract: - Highlights: Four anion-doped CaMoO{sub 4}:Eu{sup 3+} red phosphors were prepared by hydrothermal approach. Some samples exhibit nearly spherical morphology and well-distributed fine particles. The red luminescence can be obviously enhanced after certain amount of anion doping. The improved phosphor system is a potential candidate for white LED applications. - Abstract: Applying hydrothermal and subsequent heat-treatment process, CaMoO{sub 4}:Eu{sup 3+} was doped with four anions (SiO{sub 3}{sup 2?}, PO{sub 4}{sup 3?}, SO{sub 4}{sup 2?} and ClO{sub 3}{sup ?}) to prepare fine red powder phosphors. The introduction of small amount of anions into the host had little influence on the structure, which was confirmed by X-ray diffraction patterns. The anion-doped phosphor samples (except SiO{sub 3}{sup 2?}) exhibited nearly spherical morphology, and the particle sizes were in the range of 0.30.4 ?m for SO{sub 4}{sup 2?}-doped samples, and 0.81.2 ?m for PO{sub 4}{sup 3?} and ClO{sub 3}{sup ?}-doped samples. Excited with 395 nm near-UV light, all samples showed typical Eu{sup 3+} red emission at 615 nm, and PO{sub 4}{sup 3?}, SO{sub 4}{sup 2?} and ClO{sub 3}{sup ?}-doped samples enhanced the red luminescence as compared with the individual CaMoO{sub 4}:Eu{sup 3+} sample. In particular, relative emission intensity for optimum ClO{sub 3}{sup ?}-doped phosphors reached more than 6-fold that of the commercial red phosphor, which is highly desirable for the powder phosphors used in the solid-state lighting industry.

  7. redMaPPer. I. Algorithm and SDSS DR8 catalog

    SciTech Connect (OSTI)

    Rykoff, E. S.; Rozo, E.; Reddick, R.; Wechsler, R. H.; Busha, M. T.; Cunha, C. E.; Finoguenov, A.; Evrard, A.; Koester, B. P.; Hao, J.; Nord, B.; Leauthaud, A.; Pierre, M.; Sadibekova, T.; Sheldon, E. S.

    2014-04-20

    We describe redMaPPer, a new red sequence cluster finder specifically designed to make optimal use of ongoing and near-future large photometric surveys. The algorithm has multiple attractive features: (1) it can iteratively self-train the red sequence model based on a minimal spectroscopic training sample, an important feature for high-redshift surveys. (2) It can handle complex masks with varying depth. (3) It produces cluster-appropriate random points to enable large-scale structure studies. (4) All clusters are assigned a full redshift probability distribution P(z). (5) Similarly, clusters can have multiple candidate central galaxies, each with corresponding centering probabilities. (6) The algorithm is parallel and numerically efficient: it can run a Dark Energy Survey-like catalog in ?500 CPU hours. (7) The algorithm exhibits excellent photometric redshift performance, the richness estimates are tightly correlated with external mass proxies, and the completeness and purity of the corresponding catalogs are superb. We apply the redMaPPer algorithm to ?10, 000 deg{sup 2} of SDSS DR8 data and present the resulting catalog of ?25,000 clusters over the redshift range z in [0.08, 0.55]. The redMaPPer photometric redshifts are nearly Gaussian, with a scatter ? {sub z} ? 0.006 at z ? 0.1, increasing to ? {sub z} ? 0.02 at z ? 0.5 due to increased photometric noise near the survey limit. The median value for |?z|/(1 + z) for the full sample is 0.006. The incidence of projection effects is low (?5%). Detailed performance comparisons of the redMaPPer DR8 cluster catalog to X-ray and Sunyaev-Zel'dovich catalogs are presented in a companion paper.

  8. Crystallographic study of red fluorescent protein eqFP578 and its far-red variant Katushka reveals opposite pH-induced isomerization of chromophore

    SciTech Connect (OSTI)

    Pletneva, Nadya V.; Pletnev, Vladimir Z.; Shemiakina, Irina I.; Chudakov, Dmitriy M.; Artemyev, Igor; Wlodawer, Alexander; Dauter, Zbigniew; Pletnev, Sergei

    2012-08-10

    The wild type red fluorescent protein eqFP578 (from sea anemone Entacmaea quadricolor, {lambda}{sub ex} = 552 nm, {lambda}{sub em} = 578 nm) and its bright far-red fluorescent variant Katushka ({lambda}{sub ex} = 588 nm, {lambda}{sub em} = 635 nm) are characterized by the pronounced pH dependence of their fluorescence. The crystal structures of eqFP578f (eqFP578 with two point mutations improving the protein folding) and Katushka have been determined at the resolution ranging from 1.15 to 1.85 {angstrom} at two pH values, corresponding to low and high level of fluorescence. The observed extinguishing of fluorescence upon reducing pH in eqFP578f and Katushka has been shown to be accompanied by the opposite trans-cis and cis-trans chromophore isomerization, respectively. Asn143, Ser158, His197 and Ser143, Leu174, and Arg197 have been shown to stabilize the respective trans and cis fluorescent states of the chromophores in eqFP578f and Katushka at higher pH. The cis state has been suggested as being primarily responsible for the observed far-red shift of the emission maximum of Katushka relative to that of eqFP578f.

  9. Rooftop Solar Challenge to Cut Solar's Red Tape | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Challenge to Cut Solar's Red Tape Rooftop Solar Challenge to Cut Solar's Red Tape December 1, 2011 - 4:35pm Addthis Ginny Simmons Ginny Simmons Former Managing Editor for Energy.gov, Office of Public Affairs What does this project do? The 22 teams will implement step-by-step actions throughout the next year to standardize solar permitting processes, update planning and zoning codes, improve standards for connecting solar power to the electric grid, and increase access to financing. Up to 40

  10. Red Hat Enterprise Virtualization - KVM-based infrastructure services at BNL

    SciTech Connect (OSTI)

    Cortijo, D.

    2011-06-14

    Over the past 18 months, BNL has moved a large percentage of its Linux-based servers and services into a Red Hat Enterprise Virtualization (RHEV) environment. This presentation will address our approach to virtualization, critical decision points, and a discussion of our implementation. Specific topics will include an overview of hardware and software requirements, networking, and storage; discussion of the decision of Red Hat solution over competing products (VMWare, Xen, etc); details on some of the features of RHEV - both current and on their roadmap; Review of performance and reliability gains since deployment completion; path forward for RHEV at BNL and caveats and potential problems.

  11. Efficient utilization of red maple lumber in glued-laminated timber beams. Forest Service research paper

    SciTech Connect (OSTI)

    Janowiak, J.J.; Manbeck, H.B.; Hernandez, R.; Moody, R.C.; Blankenhorn, P.R.

    1995-09-01

    The feasibility of utilizing cant-sawn hardwood lumber, which would not usually be desired for furniture manufacture, was studied for the manufacture of structural glue-laminated (glulam) timber. Two red maple beam combinations were evaluated. Test results of 42 red maple glulam beams showed that it was feasible to develop structural glulam timber from cant-swan lumber. The glulam combinations made from E-rated lumber exceeded the target design bending stress of 2,400 lb/in 2 and met the target modulus of elasticity (MOE) of 1.8 x 106 lb/in 2.

  12. Method and kit for the selective labeling of red blood cells in whole blood with TC-99M

    DOE Patents [OSTI]

    Srivastava, Suresh C.; Babich, John W.; Straub, Rita; Richards, Powell

    1988-01-01

    Disclosed herein are a method and kit for the preparation of .sup.99m Tc labeled red blood cells using whole blood in a closed sterile system containing stannous tin in a form such that it will enter the red blood cells and be available therein for the reduction of technetium.

  13. Method and kit for the selective labeling of red blood cells in whole blood with Tc-99m

    DOE Patents [OSTI]

    Srivastava, S.C.; Babich, J.W.; Straub, R.; Richards, P.

    1988-07-05

    Disclosed herein are a method and kit for the preparation of [sup 99m]Tc labeled red blood cells using whole blood in a closed sterile system containing stannous tin in a form such that it will enter the red blood cells and be available for the reduction of technetium. No Drawings

  14. Hydrogen-terminated silicon nanowire photocatalysis: Benzene oxidation and methyl red decomposition

    SciTech Connect (OSTI)

    Lian, Suoyuan; School of Chemical Engineering and Materials, Dalian Polytechnic University, Dalian 116034 ; Tsang, Chi Him A.; Centre of Super Diamond and Advanced Films, City University of Hong Kong, Hong Kong ; Kang, Zhenhui; Liu, Yang; Wong, Ningbew; Lee, Shuit-Tong; Centre of Super Diamond and Advanced Films, City University of Hong Kong, Hong Kong

    2011-12-15

    Graphical abstract: H-SiNWs can catalyze hydroxylation of benzene and degradation of methyl red under visible light irradiation. Highlights: Black-Right-Pointing-Pointer Hydrogen-terminated silicon nanowires were active photocatalyst in the hydroxylation of benzene under light. Black-Right-Pointing-Pointer Hydrogen-terminated silicon nanowires were also effective in the decomposition of methyl red dye. Black-Right-Pointing-Pointer The Si/SiO{sub x} core-shell structure is the main reason of the obtained high selectivity during the hydroxylation. -- Abstract: Hydrogen-terminated silicon nanowires (H-SiNWs) were used as heterogeneous photocatalysts for the hydroxylation of benzene and for the decomposition of methyl red under visible light irradiation. The above reactions were monitored by GC-MS and UV-Vis spectrophotometry, respectively, which shows 100% selectivity for the transformation of benzene to phenol. A complete decomposition of a 2 Multiplication-Sign 10{sup -4} M methyl red solution was achieved within 30 min. The high selectivity for the hydroxylation of benzene and the photodecomposition demonstrate the catalytic activity of ultrafine H-SiNWs during nanocatalysis.

  15. Raman scattering and red fluorescence in the photochemical transformation of dry tryptophan particles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lai, Chih Wei; Schwab, Mark; Hill, Steven C.; Santarpia, Joshua; Pan, Yong -Le

    2016-05-19

    Tryptophan is a fluorescent amino acid common in proteins. Its absorption is largest for wavelengths λ ≲ 290 nm and its fluorescence emissions peak around 300–350 nm, depending upon the local environment. Here we report the observation of red fluorescence near 600 nm emerging from 488-nm continuous-wave (CW) laser photoexcitation of dry tryptophan (Trp) particles. With an excitation intensity below 0.5 kW/cm2, dry Trp particles yield distinctive Raman scattering peaks in the presence of relatively weak and spectrally broad emissions with λ ~500–700 nm, allowing estimation of particle temperature at low excitation intensities. When the photoexcitation intensity is increased tomore » 1 kW/cm2 or more for a few minutes, fluorescence intensity dramatically increases by more than two orders of magnitude. The fluorescence continues to increase in intensity and gradually shift to the red when photoexcitation intensity and the duration of exposure are increased. The resulting products absorb at visible wavelengths and generate red fluorescence with λ ~ 650–800 nm with 633-nm CW laser excitation. In conclusion, we attribute the emergence of orange and red fluorescence in the Trp products to a photochemical transformation that is instigated by weak optical transitions to triplet states in Trp with 488-nm excitation and which may be expedited by a photothermal effect.« less

  16. ASTEROSEISMIC CLASSIFICATION OF STELLAR POPULATIONS AMONG 13,000 RED GIANTS OBSERVED BY KEPLER

    SciTech Connect (OSTI)

    Stello, Dennis; Bedding, Timothy R.; Benomar, Othman; White, Timothy R.; Huber, Daniel; Bildsten, Lars; Paxton, Bill; Elsworth, Yvonne P.; Gilliland, Ronald L.; Mosser, Benoit

    2013-03-10

    Of the more than 150,000 targets followed by the Kepler Mission, about 10% were selected as red giants. Due to their high scientific value, in particular for Galaxy population studies and stellar structure and evolution, their Kepler light curves were made public in late 2011. More than 13,000 (over 85%) of these stars show intrinsic flux variability caused by solar-like oscillations making them ideal for large-scale asteroseismic investigations. We automatically extracted individual frequencies and measured the period spacings of the dipole modes in nearly every red giant. These measurements naturally classify the stars into various populations, such as the red giant branch, the low-mass (M/M{sub Sun} {approx}< 1.8) helium-core-burning red clump, and the higher-mass (M/M{sub Sun} {approx}> 1.8) secondary clump. The period spacings also reveal that a large fraction of the stars show rotationally induced frequency splittings. This sample of stars will undoubtedly provide an extremely valuable source for studying the stellar population in the direction of the Kepler field, in particular when combined with complementary spectroscopic surveys.

  17. MULTI-EPOCH OBSERVATIONS OF THE RED WING EXCESS IN THE SPECTRUM OF 3C 279

    SciTech Connect (OSTI)

    Punsly, Brian E-mail: brian.punsly@comdev-usa.com

    2013-01-10

    It has been previously determined that there is a highly significant correlation between the spectral index from 10 GHz to 1350 A and the amount of excess luminosity in the red wing of quasar C IV {lambda}1549 broad emission lines (BELs). Ostensibly, the prominence of the red excess is associated with the radio jet emission mechanism and is most pronounced for lines of sight close to the jet axis. Studying the scant significant differences in the UV spectra of radio-loud and radio-quiet quasars might provide vital clues to the origin of the unknown process that creates powerful relativistic jets that appear in only about 10% of quasars. In this study, the phenomenon is explored with multi-epoch observations of the Mg II {lambda}2798 broad line in 3C 279 which has one of the largest known red wing excesses in a quasar spectrum. The amount of excess that is detected appears to be independent of all directly observed optical continuum, radio, or submillimeter properties (fluxes or polarizations). The only trend that occurs in this sparse data is: the stronger the BEL, the larger the fraction of flux that resides in the red wing. It is concluded that more monitoring is needed and spectropolarimetry with a large telescope is essential during low states to understand more.

  18. May 12 EXPO Event Schedule 8:00-11:00 Red Cross Blood Drive Bloodmobil...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    May 12 EXPO Event Schedule 8:00-11:00 Red Cross Blood Drive Bloodmobile 10:00 & 3:30 Vehicle Accident Demo Arena 5:00-6:30 Bike Rodeo Arena May 13 EXPO Event Schedule 7:30-9:00 MSA...

  19. Stacked white OLED having separate red, green and blue sub-elements

    SciTech Connect (OSTI)

    Forrest, Stephen; Qi, Xiangfei; Slootsky, Michael

    2015-06-23

    The present invention relates to efficient organic light emitting devices (OLEDs). More specifically, the present invention relates to white-emitting OLEDs, or WOLEDs. The devices of the present invention employ three emissive sub-elements, typically emitting red, green and blue, to sufficiently cover the visible spectrum. The sub-elements are separated by charge generating layers.

  20. Using red clump stars to decompose the galactic magnetic field with distance

    SciTech Connect (OSTI)

    Pavel, Michael D.

    2014-09-01

    A new method for measuring the large-scale structure of the Galactic magnetic field is presented. The Galactic magnetic field has been probed through the Galactic disk with near-infrared starlight polarimetry; however, the distance to each background star is unknown. Using red clump stars as near-infrared standard candles, this work presents the first attempt to decompose the line-of-sight structure of the sky-projected Galactic magnetic field. Two example lines of sight are decomposed: toward a field with many red clump stars and toward a field with few red clump stars. A continuous estimate of magnetic field orientation over several kiloparsecs of distance is possible in the field with many red clump stars, while only discrete estimates are possible in the sparse example. Toward the outer Galaxy, there is a continuous field orientation with distance that shows evidence of perturbation by the Galactic warp. Toward the inner Galaxy, evidence for a large-scale change in the magnetic field geometry is consistent with models of magnetic field reversals, independently derived from Faraday rotation studies. A photo-polarimetric method for identifying candidate intrinsically polarized stars is also presented. The future application of this method to large regions of the sky will begin the process of mapping the Galactic magnetic field in a way never before possible.

  1. Radial velocity curves of ellipsoidal red giant binaries in the Large Magellanic Cloud

    SciTech Connect (OSTI)

    Nie, J. D.; Wood, P. R. E-mail: peter.wood@anu.edu.au

    2014-12-01

    Ellipsoidal red giant binaries are close binary systems where an unseen, relatively close companion distorts the red giant, leading to light variations as the red giant moves around its orbit. These binaries are likely to be the immediate evolutionary precursors of close binary planetary nebula and post-asymptotic giant branch and post-red giant branch stars. Due to the MACHO and OGLE photometric monitoring projects, the light variability nature of these ellipsoidal variables has been well studied. However, due to the lack of radial velocity curves, the nature of their masses, separations, and other orbital details has so far remained largely unknown. In order to improve this situation, we have carried out spectral monitoring observations of a large sample of 80 ellipsoidal variables in the Large Magellanic Cloud and we have derived radial velocity curves. At least 12 radial velocity points with good quality were obtained for most of the ellipsoidal variables. The radial velocity data are provided with this paper. Combining the photometric and radial velocity data, we present some statistical results related to the binary properties of these ellipsoidal variables.

  2. Infra-red detector and method of making and using same

    DOE Patents [OSTI]

    Craig, Richard A.; Griffin, Jeffrey W.

    2007-02-20

    A low-cost infra-red detector is disclosed including a method of making and using the same. The detector employs a substrate, a filtering layer, a converting layer, and a diverter to be responsive to wavelengths up to about 1600 nm. The detector is useful for a variety of applications including spectroscopy, imaging, and defect detection.

  3. Red, green, and blue lasing enabled by single-exciton gain in colloidal quantum dot films

    DOE Patents [OSTI]

    Nurmikko, Arto V.; Dang, Cuong

    2016-06-21

    The methods and materials described herein contemplate the use films of colloidal quantum dots as a gain medium in a vertical-cavity surface-emitting laser. The present disclosure demonstrates a laser with single-exciton gain in the red, green, and blue wavelengths. Leveraging this nanocomposite gain, the results realize a significant step toward full-color single-material lasers.

  4. Surface activity and oscillation amplitudes of red giants in eclipsing binaries

    SciTech Connect (OSTI)

    Gaulme, P.; Jackiewicz, J.; Appourchaux, T.; Mosser, B.

    2014-04-10

    Among the 19 red-giant stars belonging to eclipsing binary systems that have been identified in Kepler data, 15 display solar-like oscillations. We study whether the absence of mode detection in the remaining 4 is an observational bias or possibly evidence of mode damping that originates from tidal interactions. A careful analysis of the corresponding Kepler light curves shows that modes with amplitudes that are usually observed in red giants would have been detected if they were present. We observe that mode depletion is strongly associated with short-period systems, in which stellar radii account for 16%-24% of the semi-major axis, and where red-giant surface activity is detected. We suggest that when the rotational and orbital periods synchronize in close binaries, the red-giant component is spun up, so that a dynamo mechanism starts and generates a magnetic field, leading to observable stellar activity. Pressure modes would then be damped as acoustic waves dissipate in these fields.

  5. Stacked white OLED having separate red, green and blue sub-elements

    DOE Patents [OSTI]

    Forrest, Stephen; Qi, Xiangfei; Slootsky, Michael

    2016-06-28

    The present invention relates to efficient organic light emitting devices (OLEDs). More specifically, the present invention relates to white-emitting OLEDs, or WOLEDs. The devices of the present invention employ three emissive sub-elements, typically emitting red, green and blue, to sufficiently cover the visible spectrum. The sub-elements are separated by charge generating layers.

  6. Protect and Restore Red River Watershed, 2007-2008 Annual Report.

    SciTech Connect (OSTI)

    Bransford, Stephanie

    2009-05-04

    The Nez Perce Tribe Department of Fisheries Resource Management, Watershed Division approaches watershed restoration with a ridge-top to ridge-top approach. The Nez Perce Tribe (NPT) and the Nez Perce National Forest (NPNF) have formed a partnership in completing watershed restoration activities, and through this partnership more work is accomplished by sharing funding and resources in our effort. The Nez Perce Tribe began watershed restoration projects within the Red River Watershed of the South Fork Clearwater River in 2001. Progress has been made in restoring the watershed through road decommissioning and culvert replacement. From completing a watershed assessment to two NEPA efforts and a final stream restoration design, we will begin the effort of restoring the mainstem channel of Red River to provide spawning and rearing habitat for anadromous and resident fish species. Roads have been surveyed and prioritized for removal or improvement as well as culverts being prioritized for replacement to accommodate fish passage throughout the watershed. Another major, and extremely, important component of this project is the Red River Meadow Conservation Easement. We have begun the process of pursuing a conservation easement on approximately 270 acres of prime meadow habitat (Red River runs through this meadow and is prime spawning and rearing habitat).

  7. THE ARAUCARIA PROJECT. POPULATION EFFECTS ON THE V- AND I-BAND MAGNITUDES OF RED CLUMP STARS

    SciTech Connect (OSTI)

    Pietrzynski, Grzegorz; Gieren, Wolfgang; Gorski, Marek; Udalski, Andrzej; Ciechanowska, Anna; Laney, David E-mail: pietrzyn@astrouw.edu.p E-mail: udalski@astrouw.edu.p E-mail: cdl@saao.ac.z

    2010-10-15

    We present measurements of the V- and I-band magnitudes of red clump stars in 15 nearby galaxies obtained from recently published homogeneous Hubble Space Telescope photometry. Supplementing these results with similar data for another eight galaxies available in the literature, the populational effects on the V- and I-band magnitudes of red clump stars were investigated. Comparing red clump magnitudes with the I-band magnitude of the tip of the red giant branch in a total sample of 23 galaxies possessing very different environments, we demonstrate that population effects strongly affect both the V- and I-band magnitude of red clump stars in a complex way. Our empirical results basically confirm the theoretical results of Girardi and Salaris, and show that optical (V - I) photometry of red clump stars is not an accurate method for the determination of distances to nearby galaxies at the present moment, as long as the population effects are not better calibrated, both empirically and theoretically. Near-infrared photometry is a much better way to measure galaxy distances with red clump stars given its smaller sensitivity to population effects.

  8. Microsoft PowerPoint - SAND2005-2351C_RedStormEarlyExperiences [Read-Only]

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    multiprogram laboratory operated by Sandia Corporation, a Lockheed Martin Company, for the United States Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. Early Experience with Red Storm April 19, 2005 Sue Kelly and Bob Ballance Sandia National Laboratories smkelly@sandia.gov, 505-845-9770 Outline of Talk * Overview of Red Storm * Where we are * How we got here * Where we're going * What we learned Red Storm is a Massively Parallel Processor Users

  9. A LITHIUM-RICH RED GIANT BELOW THE CLUMP IN THE KEPLER CLUSTER, NGC 6819

    SciTech Connect (OSTI)

    Anthony-Twarog, Barbara J.; Rich, Evan; Twarog, Bruce A.; Deliyannis, Constantine P. E-mail: evan66210@gmail.com E-mail: con@astro.indiana.edu

    2013-04-10

    WIYN/HYDRA spectra in the Li 6708 A region have been obtained for 332 probable members of the old open cluster, NGC 6819. Preliminary analysis shows a pattern of Li depletion from the top of the turnoff to the base of the giant branch. Starting 1 mag below the level of the clump, all brighter giants have A(Li) below 1.0, with most having upper limits below 0.5. Star W007017, located below the first-ascent red giant bump is Li-rich with A(Li) = 2.3. As a highly probable single-star astrometric and radial-velocity cluster member, its discrepant asteroseismic membership could be a by-product of the processes that triggered Li enhancement. Its color-magnitude diagram location is consistent with only one proposed enhanced mixing process among first-ascent red giants.

  10. Red Lake Band of Chippewa Indians: Biomass Energy Feasiblity Study Update

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Health and Bioenergy: Technology Opportunities and Barriers Scott Haase McNeil Technologies June 20, 2003 Red Lake Band of Chippewa Indians: Biomass Energy Feasibility Study Update Presented to DOE Tribal Energy Program Scott Haase October 19, 2004 * Project overview * Resource assessment * Assess on-site electric and thermal applications * Assess local/regional utility market * Economic analysis * Alternative products Presentation Outline * Evaluate and determine potential options for creating

  11. Redbird Red Habitat for Humanity Net Zero Energy Home Project Summary

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Redbird Red Habitat for Humanity Net Zero Energy Home Project Summary The Illinois State University team incorporated Habitat for Humanity's goals and constraints during the design process, as well as designing it to be zero barrier and ADA compliant. Throughout the process the team utilized the existing plan to have a direct comparison to the typical home Habitat for Humanity builds. In addition, the team designed the exterior of the home to compliment the surrounding architecture as well as

  12. Project Reports for Red Lake Band of Chippewa Indians- 2003 Project

    Broader source: Energy.gov [DOE]

    The Red Lake Band of Chippewa Indians, located in the northwest corner of Minnesota near the Canadian border, will assess the potential to expand the use of biomass resources for energy autonomy and economic development on tribal lands. Specifically, the tribe will evaluate the technical, market, financial, and cultural aspects of using its extensive, forested lands to create a sustainable bioproducts-based business and will develop a business plan to guide tribal industry development.

  13. Synthesis and characterization of black, red and yellow nanoparticles pigments from the iron sand

    SciTech Connect (OSTI)

    Mufti, Nandang Atma, T. Fuad, A.; Sutadji, E.

    2014-09-25

    The aim of this research is to synthesize nanoparticles of black pigment of Magnetite (Fe{sub 3}O{sub 4}), red pigment of hematite (α-Fe{sub 2}O{sub 3}), and yellow pigment of ghoetite (α-FeOOH) from the iron sand. The black pigment of Fe{sub 3}O{sub 4} and the yellow pigment α-FeOOH nanoparticles were synthesized by coprecipitation method with variation of pH. Whereas, the red pigment Fe{sub 2}O{sub 3} was synthesized by sintering Fe{sub 3}O{sub 4} nanoparticles at temperature between 400 °C and 700 7°C for 1 hour. All the pigments has been characterized using X-ray diffraction and SEM. The XRD results shown that the particle size of the black pigmen Fe{sub 3}O{sub 4}, red pigment Fe{sub 3}O{sub 4} and yellow pigment α-FeOOH are around 12, 32, and 30 nm respectively. The particle size of Fe{sub 2}O{sub 3} nanoparticles increase by increasing sintering temperature from 32 nm at 400 °C to 39 nm at 700 °C. For yellow pigment of α-FeOOH, the particle size increase by increasing pH from 30,54 nm at pH 4 to 48,60 nm at pH 7. The SEM results shown that the morphologies of black, yellow and red pigments are aglomarated.

  14. Impact of P and T on geological repositories an overview of the EURATOM red impact project

    SciTech Connect (OSTI)

    Westlen, Daniel; Norris, Simon; Gonzalez-Romero, Enrique M.; Greneche, Dominique; Boucher, Lionel; Marivoet, Jan; Zimmerman, Colin; von Lensa, Werner

    2007-07-01

    The European Commission project Red Impact is in a state of conclusion after three years. Within the project, the consequences of P and T on, mainly, geological disposal have been investigated. Six scenarios have been developed, including three considered to be deployable today, and three more advanced scenarios including P and T in different ways. The scenarios all have different strengths and weaknesses, which are discussed in the present paper. (authors)

  15. INTELLIGENT COMPUTING SYSTEM FOR RESERVOIR ANALYSIS AND RISK ASSESSMENT OF THE RED RIVER FORMATION

    SciTech Connect (OSTI)

    Mark A. Sippel; William C. Carrigan; Kenneth D. Luff; Lyn Canter

    2003-11-12

    Integrated software has been written that comprises the tool kit for the Intelligent Computing System (ICS). The software tools in ICS have been developed for characterization of reservoir properties and evaluation of hydrocarbon potential using a combination of inter-disciplinary data sources such as geophysical, geologic and engineering variables. The ICS tools provide a means for logical and consistent reservoir characterization and oil reserve estimates. The tools can be broadly characterized as (1) clustering tools, (2) neural solvers, (3) multiple-linear regression, (4) entrapment-potential calculator and (5) file utility tools. ICS tools are extremely flexible in their approach and use, and applicable to most geologic settings. The tools are primarily designed to correlate relationships between seismic information and engineering and geologic data obtained from wells, and to convert or translate seismic information into engineering and geologic terms or units. It is also possible to apply ICS in a simple framework that may include reservoir characterization using only engineering, seismic, or geologic data in the analysis. ICS tools were developed and tested using geophysical, geologic and engineering data obtained from an exploitation and development project involving the Red River Formation in Bowman County, North Dakota and Harding County, South Dakota. Data obtained from 3D seismic surveys, and 2D seismic lines encompassing nine prospective field areas were used in the analysis. The geologic setting of the Red River Formation in Bowman and Harding counties is that of a shallow-shelf, carbonate system. Present-day depth of the Red River formation is approximately 8000 to 10,000 ft below ground surface. This report summarizes production results from well demonstration activity, results of reservoir characterization of the Red River Formation at demonstration sites, descriptions of ICS tools and strategies for their application.

  16. Biographical sketch - Kevin Redding | Center for Bio-Inspired Solar Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Production Kevin Redding a. Professional Preparation Rice University Biochemistry B. S., 1987 Stanford University Biochemistry Ph. D., 1993 University of Geneva Mol. Biology Postdoctoral studies, 1994 - 1998 b. Area of Specialization: Structure/function analysis of biological electron transfer c. Appointments Arizona State University, Associate Professor of Chemistry (1/1/08 - present) Chercheur associé (CNRS), Institut de Biologie Physico-Chimique, Paris (8/15/07-7/20/08) and Fulbright

  17. A z ∼ 5.7 Lyα emission line with an ultrabroad red wing

    SciTech Connect (OSTI)

    Yang, Huan; Wang, JunXian; Zheng, Zhen-Ya; Malhotra, Sangeeta; Rhoads, James E.; Infante, Leopoldo E-mail: jxw@mail.ustc.edu.cn E-mail: smalhotr@asu.edu E-mail: linfante@astro.puc.cl

    2014-03-20

    Using the Lyα emission line as a tracer of high-redshift, star-forming galaxies, hundreds of Lyα emission line galaxies (LAEs) at z > 5 have been detected. These LAEs are considered to be low-mass young galaxies, critical to the re-ionization of the universe and the metal enrichment of the circumgalactic medium (CGM) and the intergalactic medium (IGM). It is assumed that outflows in LAEs can help both ionizing photons and Lyα photons escape from galaxies. However, we still know little about the outflows in high-redshift LAEs due to observational difficulties, especially at redshift >5. Models of Lyα radiative transfer predict asymmetric Lyα line profiles with broad red wings in LAEs with outflows. Here, we report a z ∼ 5.7 Lyα emission line with a broad red wing extending to >1000 km s{sup –1} relative to the peak of Lyα line, which has been detected in only a couple of z > 5 LAEs until now. If the broad red wing is ascribed to gas outflow instead of active galactic nucleus activity, the outflow velocity could be larger than the escape velocity (∼500 km s{sup –1}) of a typical halo mass of z ∼ 5.7 LAEs, which is consistent with the idea that outflows in LAEs disperse metals to CGM and IGM.

  18. The red-cockaded woodpecker on the Savannah River Site: Aspects of reproductive success.

    SciTech Connect (OSTI)

    Johnston, Peter A.; Imm, Donald, W.; Jarvis, William L.

    2004-12-31

    Red-cockaded woodpecker; Road to Recovery. Proceedings of the 4th Red-cockaded woodpecker Symposium. Ralph Costa and Susan J. Daniels, eds. Savannah, Georgia. January, 2003. Chapter 5. Status and Trends of Populations. Pp 224-229. Abstract: The red-cockaded woodpecker (Picoides borealis) population on the Savannah River Site has been closely monitored and studied over the last 17 years. In 1985, the USDA Forest Service Southern Research Station was given responsibility to study and manage this population in an effort to prevent its extirpation. In December 1985, there were only 4 individuals on the site: 1 pair and 2 solitary males. The population had increased to a total of 175 individuals in 42 active clusters in 2002. Although this represents a very successful recovery effort, there has been substantial annual variation in nesting survival from banding to fledging. Data were analyzed to more completely understand the factors affecting reproduction. No significant effects of age of the breeding male and female, years paired, number of helpers, habitat quality, number of nestings, and time of nest initiation were found when comparing reproductive success in 117 nesting attempts from 1999 to 2002. However, the number of neighboring groups had a direct effect on mortality rates, possibly demonstrating the importance of cluster spacing.

  19. Red emission phosphor for real-time skin dosimeter for fluoroscopy and interventional radiology

    SciTech Connect (OSTI)

    Nakamura, Masaaki Chida, Koichi; Zuguchi, Masayuki

    2014-10-15

    Purpose: There are no effective real-time direct skin dosimeters for interventional radiology. Such a scintillation dosimeter would be available if there was a suitable red emission phosphor in the medical x-ray range, since the silicon photodiode is a highly efficient device for red light. However, it is unknown whether there is a suitable red emission phosphor. The purpose of this study is to find a suitable red emission phosphor that can be used in x-ray dosimeters. Methods: Five kinds of phosphors which emit red light when irradiated with electron beams or ultraviolet rays in practical devices were chosen. For the brightness measurement, phosphor was put into transparent plastic cells or coated onto plastic sheets. The phosphors were irradiated with medical range x-rays [60–120 kV(peak), maximum dose rate of 160 mGy min{sup −1}], and the emission was measured by a luminance meter. Several characteristics, such as brightness, dose rate dependence, tube voltage dependence, and brightness stability, were investigated. Results: The luminescence of Y V O{sub 4}:Eu, (Y,Gd,Eu) BO{sub 3}, and Y{sub 2}O{sub 3}:Eu significantly deteriorated by 5%–10% when irradiated with continuous 2 Gy x-rays. The 0.5MgF{sub 2}⋅3.5MgO⋅GeO{sub 2}:Mn phosphor did not emit enough. Only the Y{sub 2}O{sub 2}S:Eu,Sm phosphor had hardly any brightness deterioration, and it had a linear relationship so that the x-ray dose rate could be determined from the brightness with sufficient accuracy. For the tube voltage dependence of the Y{sub 2}O{sub 2}S:Eu,Sm phosphor, the brightness per unit dose rate with 120 kV(peak) x-rays was 30% higher than that with 60 kV(peak) x-rays. Conclusions: Five kinds of phosphors were chosen as an x-ray scintillator for a real-time direct skin dosimeter. The Y V O{sub 4}:Eu, (Y,Gd,Eu)BO{sub 3}, and Y{sub 2}O{sub 3}:Eu phosphors had brightness deterioration caused by the x-rays. Only the Y{sub 2}O{sub 2}S:Eu,Sm phosphor had hardly any brightness deterioration

  20. T-563: Red Hat Directory Server Bugs Let Local Users Gain Elevated Privileges and Remote and Local Users Deny Service

    Broader source: Energy.gov [DOE]

    Several vulnerabilities were reported in Red Hat Directory Server. A local user can obtain elevated privileges on the target system. A remote user can cause denial of service conditions. A local user can cause denial of service conditions.

  1. Amplifying the Red-Emission of Upconverting Nanoparticles for Biocompatible Clinically Used Prodrug-Induced Photodynamic Therapy

    SciTech Connect (OSTI)

    Punjabi, Amol; Wu, Xiang; Tokatli-Apollon, Amira; El-Rifai, Mahmoud; Lee, Hyungseok; Zhang, Yuanwei; Wang, Chao; Liu, Zhuang; Chan, Emory M.; Duan, Chunying; Han, Gang

    2014-09-25

    A class of biocompatible upconverting nanoparticles (UCNPs) with largely amplified red-emissions was developed. The optimal UCNP shows a high absolute upconversion quantum yield of 3.2% in red-emission, which is 15-fold stronger than the known optimal β-phase core/shell UCNPs. When conjugated to aminolevulinic acid, a clinically used photodynamic therapy (PDT) prodrug, significant PDT effect in tumor was demonstrated in a deep-tissue (>1.2 cm) setting in vivo at a biocompatible laser power density. Furthermore, we show that our UCNP–PDT system with NIR irradiation outperforms clinically used red light irradiation in a deep tumor setting in vivo. This study marks a major step forward in photodynamic therapy utilizing UCNPs to effectively access deep-set tumors.Lastly, it also provides an opportunity for the wide application of upconverting red radiation in photonics and biophotonics.

  2. Effects of storage on irradiated red blood cells: An in-vitro and in-vivo study. Master's thesis

    SciTech Connect (OSTI)

    Knoll, S.E.

    1991-08-01

    Irradiation of red blood cell units has recently become a topic of special concern as the result of increasing reports of graft versus host disease in immunocompetent blood transfusion recipients. This study was designed to evaluate the potassium elevations observed in stored irradiated red blood cells and to evaluate the in vivo survival of stored irradiated red blood cells using a dog model. In the in vitro study ten units of human CPDA-1 packed red blood cells were made into paired aliquots; one aliquot of each pair was irradiated with 3000 rads of gamma radiation and the potassium content measured at points throughout 35 days of storage. A significant increase in potassium levels in the irradiated aliquots was observed from the first day after irradiation and continued through the entire storage period.

  3. Amplifying the Red-Emission of Upconverting Nanoparticles for Biocompatible Clinically Used Prodrug-Induced Photodynamic Therapy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Punjabi, Amol; Wu, Xiang; Tokatli-Apollon, Amira; El-Rifai, Mahmoud; Lee, Hyungseok; Zhang, Yuanwei; Wang, Chao; Liu, Zhuang; Chan, Emory M.; Duan, Chunying; et al

    2014-09-25

    A class of biocompatible upconverting nanoparticles (UCNPs) with largely amplified red-emissions was developed. The optimal UCNP shows a high absolute upconversion quantum yield of 3.2% in red-emission, which is 15-fold stronger than the known optimal β-phase core/shell UCNPs. When conjugated to aminolevulinic acid, a clinically used photodynamic therapy (PDT) prodrug, significant PDT effect in tumor was demonstrated in a deep-tissue (>1.2 cm) setting in vivo at a biocompatible laser power density. Furthermore, we show that our UCNP–PDT system with NIR irradiation outperforms clinically used red light irradiation in a deep tumor setting in vivo. This study marks a major stepmore » forward in photodynamic therapy utilizing UCNPs to effectively access deep-set tumors.Lastly, it also provides an opportunity for the wide application of upconverting red radiation in photonics and biophotonics.« less

  4. Red Sky

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Solar Thermal Test Facility Nuclear ... Climate & Earth Systems Climate Measurement & Modeling ... Tribal Energy Program Intellectual Property Current EC ...

  5. Organic solution-processible electroluminescent molecular glasses for non-doped standard red OLEDs with electrically stable chromaticity

    SciTech Connect (OSTI)

    Bi, Xiaoman; Zuo, Weiwei; Liu, Yingliang Zhang, Zhenru; Zeng, Cen; Xu, Shengang; Cao, Shaokui

    2015-10-15

    Highlights: • The D–A–D electroluminescent molecular glasses are synthesized. • Non-doped red electroluminescent film is fabricated by spin-coating. • Red OLED shows stable wavelength, luminous efficiency and chromaticity. • CIE1931 coordinate is in accord with standard red light in PAL system. - Abstract: Organic light-emitting molecular glasses (OEMGs) are synthesized through the introduction of nonplanar donor and branched aliphatic chain into electroluminescent emitters. The target OEMGs are characterized by {sup 1}H NMR, {sup 13}C NMR, IR, UV–vis and fluorescent spectra as well as elemental analysis, TG and DSC. The results indicated that the optical, electrochemical and electroluminescent properties of OEMGs are adjusted successfully by the replacement of electron-donating group. The non-doped OLED device with a standard red electroluminescent emission is achieved by spin-coating the THF solution of OEMG with a triphenylamine moiety. This non-doped red OLED device takes on an electrically stable electroluminescent performance, including the stable maximum electroluminescent wavelength of 640 nm, the stable luminous efficiency of 2.4 cd/A and the stable CIE1931 coordinate of (x, y) = (0.64, 0.35), which is basically in accord with the CIE1931 coordinate (x, y) = (0.64, 0.33) of standard red light in PAL system.

  6. THE MID-INFRARED AND NEAR-ULTRAVIOLET EXCESS EMISSIONS OF QUIESCENT GALAXIES ON THE RED SEQUENCE

    SciTech Connect (OSTI)

    Ko, Jongwan; Lee, Jong Chul; Hwang, Ho Seong; Sohn, Young-Jong

    2013-04-10

    We study the mid-infrared (IR) and near-ultraviolet (UV) excess emissions of spectroscopically selected quiescent galaxies on the optical red sequence. We use the Wide-field Infrared Survey Explorer mid-IR and Galaxy Evolution Explorer near-UV data for a spectroscopic sample of galaxies in the Sloan Digital Sky Survey Data Release 7 to study the possible connection between quiescent red-sequence galaxies with and without mid-IR/near-UV excess. Among 648 12 {mu}m detected quiescent red-sequence galaxies without H{alpha} emission, 26% and 55% show near-UV and mid-IR excess emissions, respectively. When we consider only bright (M{sub r} < -21.5) galaxies with an early-type morphology, the fraction of galaxies with recent star formation is still 39%. The quiescent red-sequence galaxies with mid-IR and near-UV excess emissions are optically fainter and have slightly smaller D{sub n} 4000 than those without mid-IR and near-UV excess emissions. We also find that mid-IR weighted mean stellar ages of quiescent red-sequence galaxies with mid-IR excess are larger than those with near-UV excess, and smaller than those without mid-IR and near-UV excess. The environmental dependence of the fraction of quiescent red-sequence galaxies with mid-IR and near-UV excess seems strong even though the trends of quiescent red-sequence galaxies with near-UV excess differ from those with mid-IR excess. These results indicate that the recent star formation traced by near-UV ({approx}< 1 Gyr) and mid-IR ({approx}< 2 Gyr) excess is not negligible among nearby, quiescent, red, early-type galaxies. We suggest a possible evolutionary scenario of quiescent red-sequence galaxies from quiescent red-sequence galaxies with near-UV excess to those with mid-IR excess to those without near-UV and mid-IR excess.

  7. RED GIANTS IN ECLIPSING BINARY AND MULTIPLE-STAR SYSTEMS: MODELING AND ASTEROSEISMIC ANALYSIS OF 70 CANDIDATES FROM KEPLER DATA

    SciTech Connect (OSTI)

    Gaulme, P.; McKeever, J.; Rawls, M. L.; Jackiewicz, J.; Mosser, B.; Guzik, J. A.

    2013-04-10

    Red giant stars are proving to be an incredible source of information for testing models of stellar evolution, as asteroseismology has opened up a window into their interiors. Such insights are a direct result of the unprecedented data from space missions CoRoT and Kepler as well as recent theoretical advances. Eclipsing binaries are also fundamental astrophysical objects, and when coupled with asteroseismology, binaries provide two independent methods to obtain masses and radii and exciting opportunities to develop highly constrained stellar models. The possibility of discovering pulsating red giants in eclipsing binary systems is therefore an important goal that could potentially offer very robust characterization of these systems. Until recently, only one case has been discovered with Kepler. We cross-correlate the detected red giant and eclipsing-binary catalogs from Kepler data to find possible candidate systems. Light-curve modeling and mean properties measured from asteroseismology are combined to yield specific measurements of periods, masses, radii, temperatures, eclipse timing variations, core rotation rates, and red giant evolutionary state. After using three different techniques to eliminate false positives, out of the 70 systems common to the red giant and eclipsing-binary catalogs we find 13 strong candidates (12 previously unknown) to be eclipsing binaries, one to be a non-eclipsing binary with tidally induced oscillations, and 10 more to be hierarchical triple systems, all of which include a pulsating red giant. The systems span a range of orbital eccentricities, periods, and spectral types F, G, K, and M for the companion of the red giant. One case even suggests an eclipsing binary composed of two red giant stars and another of a red giant with a {delta}-Scuti star. The discovery of multiple pulsating red giants in eclipsing binaries provides an exciting test bed for precise astrophysical modeling, and follow-up spectroscopic observations of many

  8. Modeling a Typical Winter-time Dust Event over the Arabian Peninsula and the Red Sea

    SciTech Connect (OSTI)

    Kalenderski, S.; Stenchikov, G.; Zhao, Chun

    2013-02-20

    We used WRF-Chem, a regional meteorological model coupled with an aerosol-chemistry component, to simulate various aspects of the dust phenomena over the Arabian Peninsula and Red Sea during a typical winter-time dust event that occurred in January 2009. The model predicted that the total amount of emitted dust was 18.3 Tg for the entire dust outburst period and that the two maximum daily rates were ~2.4 Tg/day and ~1.5 Tg/day, corresponding to two periods with the highest aerosol optical depth that were well captured by ground- and satellite-based observations. The model predicted that the dust plume was thick, extensive, and mixed in a deep boundary layer at an altitude of 3-4 km. Its spatial distribution was modeled to be consistent with typical spatial patterns of dust emissions. We utilized MODIS-Aqua and Solar Village AERONET measurements of the aerosol optical depth (AOD) to evaluate the radiative impact of aerosols. Our results clearly indicated that the presence of dust particles in the atmosphere caused a significant reduction in the amount of solar radiation reaching the surface during the dust event. We also found that dust aerosols have significant impact on the energy and nutrient balances of the Red Sea. Our results showed that the simulated cooling under the dust plume reached 100 W/m2, which could have profound effects on both the sea surface temperature and circulation. Further analysis of dust generation and its spatial and temporal variability is extremely important for future projections and for better understanding of the climate and ecological history of the Red Sea.

  9. Ogaden Basin subsidence history: Another key to the Red Sea-Gulf of Aden tectonic puzzle

    SciTech Connect (OSTI)

    Pigott, J.D.; Neese, D.; Carsten, G.

    1995-08-01

    Previous work has attempted to understand the tectonic evolution of the Red Sea-Gulf of Aden region through a focus upon plate kinematics and reconstruction of plate interactions in a two dimensional sense. A significant complement to the three dimensional puzzle can be derived from a critical examination of the vertical component, tectonic subsidence analysis. By removing the isostatic contributions of sediment loading and unloading, and fluctuations in sea level, the remaining thermal-mechanical contribution to a basin`s subsidence can be determined. Such an analysis of several Ogaden Basin wells reveals multiple pulses of tectonic subsidence and uplift which correspond to far-field tectonic activities in the Red Sea and Gulf of Aden. One of the more dramatic is a Jurassic tectonic pulse circa 145-130 m.a., and a later extensional event which correlates to a major subsidence event ubiquitous through-out the Gulf of Aden, related to Gondwana Land breakup activities. Tectonic uplift during the Tertiary coincides with early Red Sea rifting episodes. Such activities suggest the Ogaden Basin has been a relatively stable East African cratonic basin, but with heating-extension events related to nearby plate interactions. In terms of hydrocarbon generation, the use of steady state present day geothermal gradients, coupled with subsidence analysis shows that potential Paleozoic and Mesozoic source rocks initiated generation as early as the Jurassic. The generating potential of Paleozoic source rocks would only be exacerbated by later heating events. Furthermore, cooling and tectonic uplift during the Tertiary would tend to arrest on-going hydrocarbon generation for Jurassic source rocks in the Ogaden area.

  10. OBSERVABLE SIGNATURES OF PLANET ACCRETION IN RED GIANT STARS. I. RAPID ROTATION AND LIGHT ELEMENT REPLENISHMENT

    SciTech Connect (OSTI)

    Carlberg, Joleen K.; Cunha, Katia; Smith, Verne V.; Majewski, Steven R. E-mail: srm4n@virginia.edu E-mail: cunha@noao.edu

    2012-10-01

    The orbital angular momentum of a close-orbiting giant planet can be sufficiently large that, if transferred to the envelope of the host star during the red giant branch (RGB) evolution, it can spin-up the star's rotation to unusually large speeds. This spin-up mechanism is one possible explanation for the rapid rotators detected among the population of generally slow-rotating red giant stars. These rapid rotators thus comprise a unique stellar sample suitable for searching for signatures of planet accretion in the form of unusual stellar abundances due to the dissemination of the accreted planet in the stellar envelope. In this study, we look for signatures of replenishment in the Li abundances and (to a lesser extent) {sup 12}C/{sup 13}C, which are both normally lowered during RGB evolution. Accurate abundances were measured from high signal-to-noise echelle spectra for samples of both slow and rapid rotator red giant stars. We find that the rapid rotators are on average enriched in lithium compared to the slow rotators, but both groups of stars have identical distributions of {sup 12}C/{sup 13}C within our measurement precision. Both of these abundance results are consistent with the accretion of planets of only a few Jupiter masses. We also explore alternative scenarios for understanding the most Li-rich stars in our sample-particularly Li regeneration during various stages of stellar evolution. Finally, we find that our stellar samples show non-standard abundances even at early RGB stages, suggesting that initial protostellar Li abundances and {sup 12}C/{sup 13}C may be more variable than originally thought.

  11. Red light-emitting diodes based on InP/GaP quantum dots

    SciTech Connect (OSTI)

    Hatami, F.; Lordi, V.; Harris, J.S.; Kostial, H.; Masselink, W.T.

    2005-05-01

    The growth, fabrication, and device characterization of InP quantum-dot light-emitting diodes based on GaP are described and discussed. The diode structures are grown on gallium phosphide substrates using gas-source molecular-beam epitaxy and the active region of the diode consists of self-assembled InP quantum dots embedded in a GaP matrix. Red electroluminescence originating from direct band-gap emission from the InP quantum dots is observed at low temperatures.With increasing temperature, however, the emission line shifts to the longer wavelength. The emission light is measured to above room temperature.

  12. Kit for the rapid preparation of .sup.99m Tc red blood cells

    DOE Patents [OSTI]

    Richards, Powell; Smith, Terry D.

    1976-01-01

    A method and sample kit for the preparation of .sup.99m Tc-labeled red blood cells in a closed, sterile system. A partially evacuated tube, containing a freeze-dried stannous citrate formulation with heparin as an anticoagulant, allows whole blood to be automatically drawn from the patient. The radioisotope is added at the end of the labeling sequence to minimize operator exposure. Consistent 97% yields in 20 minutes are obtained with small blood samples. Freeze-dried kits have remained stable after five months.

  13. Project Reports for Red Lake Band of Chippewa Indians- 2005 Project

    Office of Energy Efficiency and Renewable Energy (EERE)

    Nearly 60% of the 1,621 housing units on the reservation lack adequate insulation, ventilation, and efficient and safe furnaces and appliances. The project will achieve the following objectives: (1) to enhance tribal member energy expertise for reducing tribal energy consumption and for implementing energy efficiency measures, (2) to increase the tribe's capacity to secure additional funding for energy conservation, including state-sponsored investments, and (3) to create significant energy savings in tribal homes and promote economic and environmental opportunities to sustain Red Lake.

  14. Effects of radio transmitters on the behavior of Red-headed Woodpeckers.

    SciTech Connect (OSTI)

    Vukovich, Mark; Kilgo, John, C.

    2009-05-01

    ABSTRACT. Previous studies have revealed that radio-transmitters may affect bird behaviors, including feeding rates, foraging behavior, vigilance, and preening behavior. In addition, depending on the method of attachment, transmitters can potentially affect the ability of cavity-nesting birds to use cavities. Our objective was to evaluate effects of transmitters on the behavior of and use of cavities byRed-headedWoodpeckers (Melanerpes erythrocephalus). Using backpack harnesses, we attached 2.1-g transmitter packages that averaged 3.1% of body weight (range = 2.53.6%) to Red-headed Woodpeckers. We observed both radio-tagged (N = 23) and nonradio-tagged (N = 28) woodpeckers and determined the percentage of time spent engaged in each of five behaviors: flight, foraging, perching, preening, and territorial behavior. We found no difference between the two groups in the percentage of time engaged in each behavior. In addition, we found that transmitters had no apparent effect on use of cavities for roosting by radio-tagged woodpeckers (N = 25).We conclude that backpack transmitters weighing less than 3.6% of body weight had no impact on either their behavior or their ability to use cavities.

  15. Electronic structure descriptor for the discovery of narrow-band red-emitting phosphors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Zhenbin; Chu, Iek -Heng; Zhou, Fei; Ong, Shyue Ping

    2016-05-09

    Narrow-band red-emitting phosphors are a critical component of phosphor-converted light-emitting diodes for highly efficient illumination-grade lighting. In this work, we report the discovery of a quantitative descriptor for narrow-band Eu2+-activated emission identified through a comparison of the electronic structures of known narrow-band and broad-band phosphors. We find that a narrow emission bandwidth is characterized by a large splitting of more than 0.1 eV between the two highest Eu2+ 4f7 bands. By incorporating this descriptor in a high-throughput first-principles screening of 2259 nitride compounds, we identify five promising new nitride hosts for Eu2+-activated red-emitting phosphors that are predicted to exhibit goodmore » chemical stability, thermal quenching resistance, and quantum efficiency, as well as narrow-band emission. Lastly, our findings provide important insights into the emission characteristics of rare-earth activators in phosphor hosts and a general strategy to the discovery of phosphors with a desired emission peak and bandwidth.« less

  16. Adsorption of basic Red 46 using sea mango (Cerbera odollam) based activated carbon

    SciTech Connect (OSTI)

    Azmi, Nur Azira Iqlima; Zainudin, Nor Fauziah; Ali, Umi Fazara Md

    2015-05-15

    Sea mango or Cerbera Odollam is another source of carbonaceous material that can be found abundantly in Malaysia. In this research, it is used as a new agricultural source of activated carbon. Sea mango activated carbon was prepared by chemical activation using potassium hydroxide (KOH). The sea mango was soaked in KOH at impregnation ratio of 1:1 and followed by carbonization at temperature of 600°C for 1 hour. The sample was then characterized using Scanning Electron Microscope (SEM) for surface morphology, while Brunauer-Emmett-Teller (BET) was used to study the surface area. The result shown that sea mango activated carbon (SMAC) developed new pores on its surface and the BET surface area measured was 451.87 m{sup 2}/g. The SMAC performance was then tested for the removal of Basic Red 46 in batch process. The removal of Basic Red 46 (50 mg/L, natural pH, 0.1 g SMAC) was more than 99% in 15 minutes where it reached equilibrium in 30 minutes.

  17. INTELLIGENT COMPUTING SYSTEM FOR RESERVOIR ANALYSIS AND RISK ASSESSMENT OF THE RED RIVER FORMATION

    SciTech Connect (OSTI)

    Kenneth D. Luff

    2002-09-30

    Integrated software has been written that comprises the tool kit for the Intelligent Computing System (ICS). Luff Exploration Company is applying these tools for analysis of carbonate reservoirs in the southern Williston Basin. The integrated software programs are designed to be used by small team consisting of an engineer, geologist and geophysicist. The software tools are flexible and robust, allowing application in many environments for hydrocarbon reservoirs. Keystone elements of the software tools include clustering and neural-network techniques. The tools are used to transform seismic attribute data to reservoir characteristics such as storage (phi-h), probable oil-water contacts, structural depths and structural growth history. When these reservoir characteristics are combined with neural network or fuzzy logic solvers, they can provide a more complete description of the reservoir. This leads to better estimates of hydrocarbons in place, areal limits and potential for infill or step-out drilling. These tools were developed and tested using seismic, geologic and well data from the Red River Play in Bowman County, North Dakota and Harding County, South Dakota. The geologic setting for the Red River Formation is shallow-shelf carbonate at a depth from 8000 to 10,000 ft.

  18. A Photometric redshift galaxy catalog from the Red-Sequence Cluster Survey

    SciTech Connect (OSTI)

    Hsieh, Bau-Ching; Yee, H.K.C.; Lin, H.; Gladders, M.D.; /Carnegie Inst. Observ.

    2005-02-01

    The Red-Sequence Cluster Survey (RCS) provides a large and deep photometric catalog of galaxies in the z' and R{sub c} bands for 90 square degrees of sky, and supplemental V and B data have been obtained for 33.6 deg{sup 2}. They compile a photometric redshift catalog from these 4-band data by utilizing the empirical quadratic polynomial photometric redshift fitting technique in combination with CNOC2 and GOODS/HDF-N redshift data. The training set includes 4924 spectral redshifts. The resulting catalog contains more than one million galaxies with photometric redshifts < 1.5 and R{sub c} < 24, giving an rms scatter {delta}({Delta}z) < 0.06 within the redshift range 0.2 < z < 0.5 and {sigma}({Delta}z) < 0.11 for galaxies at 0.0 < z < 1.5. They describe the empirical quadratic polynomial photometric redshift fitting technique which they use to determine the relation between red-shift and photometry. A kd-tree algorithm is used to divide up the sample to improve the accuracy of the catalog. They also present a method for estimating the photometric redshift error for individual galaxies. They show that the redshift distribution of the sample is in excellent agreement with smaller and much deeper photometric and spectroscopic redshift surveys.

  19. Value recovery from spent alumina-base catalyst

    DOE Patents [OSTI]

    Hyatt, David E.

    1987-01-01

    A process for the recovery of aluminum and at least one other metal selected from the group consisting of molybdenum, nickel and cobalt from a spent hydrogenation catalyst comprising (1) adding about 1 to 3 parts H.sub.2 SO.sub.4 to each part of spent catalyst in a reaction zone of about 20.degree. to 200.degree. C. under sulfide gas pressure between about 1 and about 35 atmospheres, (2) separating the resultant Al.sub.2 (SO.sub.4).sub.3 solution from the sulfide precipitate in the mixture, (3) oxidizing the remaining sulfide precipitate as an aqueous slurry at about 20.degree. to 200.degree. C. in an oxygen-containing atmosphere at a pressure between about 1 and about 35 atmospheres, (4) separating the slurry to obtain solid molybdic acid and a sulfate liquor containing said at least one metal, and (5) recovering said at least one metal from the sulfate liquor in marketable form.

  20. Gold and palladium adsorption from leached electronic scrap using ordered mesoporous carbon nanoscaffolds

    SciTech Connect (OSTI)

    McDowell, Rocklan; Dutech, Guy

    2014-09-01

    Ordered mesoporous carbon (OMC) nanoscaffolds are engineered agglomerates of carbon nanotubes held together by small carbon nanofibers with uniform pore sizes, high pore volume, and high channel permeability. These materials exhibit very high affinity for the adsorption of gold from aqueous acidic mixtures. The efficiency of gold recovery is comparable to those typically accomplished using biopolymer-based adsorbents. The adsorption efficiency for other precious metals such as palladium and platinum is lower. Studies on the precious metal (Au, Pd) adsorption on OMC materials from actual liquors of leached electronics will be presented. Adsorption properties will be compared for several different sorbents used for the recovery of precious metals. The leach liquor compositions for three different types of electronic scrap materials (personal computer board, cell phone and tv input/output board) will be presented. The sorption efficiencies for Au, Pd, together with a spectrum of competing and non-competing metals, from such leach mixtures will be compared.

  1. An experimental study of the impact of location on the effectiveness of recruitment clusters for Red-cockaded Woodpeckers at the Savannah River Site.

    SciTech Connect (OSTI)

    Walters, Jeffrey, R.; Johnston, Peter, A.; Crowder, Larry, B.; Priddy, Jeffrey, A.

    2008-05-31

    An experimental study of the impact of location on the effectiveness of recruitment clusters for Red-Cockaded Woodpeckers at the Savannah River Site.

  2. A Lattice Boltzmann Fictitious Domain Method for Modeling Red Blood Cell Deformation and Multiple-Cell Hydrodynamic Interactions in Flow

    SciTech Connect (OSTI)

    Shi, Xing; Lin, Guang; Zou, Jianfeng; Fedosov, Dmitry A.

    2013-07-20

    To model red blood cell (RBC) deformation in flow, the recently developed LBM-DLM/FD method ([Shi and Lim, 2007)29], derived from the lattice Boltzmann method and the distributed Lagrange multiplier/fictitious domain methodthe fictitious domain method, is extended to employ the mesoscopic network model for simulations of red blood cell deformation. The flow is simulated by the lattice Boltzmann method with an external force, while the network model is used for modeling red blood cell deformation and the fluid-RBC interaction is enforced by the Lagrange multiplier. To validate parameters of the RBC network model, sThe stretching numerical tests on both coarse and fine meshes are performed and compared with the corresponding experimental data to validate the parameters of the RBC network model. In addition, RBC deformation in pipe flow and in shear flow is simulated, revealing the capacity of the current method for modeling RBC deformation in various flows.

  3. The light curve shapes as a key to resolving the origin of long secondary periods in red giant stars

    SciTech Connect (OSTI)

    Soszyński, I.; Udalski, A. E-mail: udalski@astrouw.edu.pl

    2014-06-10

    We present a study of Optical Gravitational Lensing Experiment light curves of red giant stars exhibiting long secondary periods (LSPs)—an enigmatic phenomenon commonly observed in stars on the upper red giant branch and asymptotic giant branch. We show that the light curves of LSP stars are essentially identical to those of the spotted variables with one dark spot on their photospheres. Such behavior can be explained by the presence of a dusty cloud orbiting the red giant together with a low-mass companion in a close, circular orbit. We argue that the binary scenario is in agreement with most of the observational properties of LSP variables, including non-sinusoidal shapes of their radial velocity curves.

  4. THE INFLUENCE OF RED SPIRAL GALAXIES ON THE SHAPE OF THE LOCAL K-BAND LUMINOSITY FUNCTION

    SciTech Connect (OSTI)

    Bonne, Nicolas J.; Brown, Michael J. I.; Jones, Heath; Pimbblet, Kevin A.

    2015-02-01

    We have determined K-band luminosity functions for 13,325 local universe galaxies as a function of morphology and color (for K {sub tot} ≤ 10.75). Our sample is drawn from the Two Micron All Sky Survey Extended Source Catalog, with all sample galaxies having measured morphologies and distances (including 4219 archival redshift-independent distances). The luminosity function for our total sample is in good agreement with previous works, but is relatively smooth at faint magnitudes (due to bulk flow distance corrections). We investigated the differences due to morphological and color selection using 5417 sample galaxies with NASA Sloan Atlas optical colors and find that red spirals comprise 20%-50% of all spirals with –25 ≤ M{sub K}  < –20. Fainter than M{sub K} = –24, red spirals are as common as early types, explaining the different faint end slopes (α = –0.87 and –1.00 for red and early-types, respectively). While we find red spirals comprise more than 50% of all M{sub K}  < –25 spiral galaxies, they do not dominate the bright end of the overall red galaxy luminosity function, which is dominated by early-type galaxies. The brightest red spirals have ongoing star formation and those without are frequently misclassified as early-types. The faintest ones have an appearance and Sérsic indices consistent with faded disks, rather than true bulge-dominated galaxies.

  5. Role of manganese in red long-lasting phosphorescence of manganese-doped diopside for in vivo imaging

    SciTech Connect (OSTI)

    Lecointre, A.; Bessire, A.; Priolkar, K.R.; Gourier, D.; Wallez, G.; Viana, B.

    2013-05-15

    Highlights: ? Long-lasting phosphorescence of CaMgSi{sub 2}O{sub 6}:Mn is studied for bioimaging application. ? CaMgSi{sub 2}O{sub 6}:Mn yields orange and red luminescence of Mn{sup II}{sub Ca} and Mn{sup II}{sub Mg}, respectively. ? Red Mn{sup II}{sub Mg} emission dominates long-lasting phosphorescence spectra. ? Mn mainly substitutes Mg. ? Mn{sup II}{sub Mg} plays the role of hole trap in the persistent luminescence mechanism. - Abstract: Materials with red long-lasting phosphorescence, such as Mn{sup II}-doped diopsides, can be used for small animal in vivo imaging. CaMgSi{sub 2}O{sub 6}:Mn powders with various amounts of Mn were prepared by solgel to investigate their long-lasting phosphorescence mechanism. X-ray diffraction, X-ray absorption fine and near-edge structure and electron paramagnetic resonance showed that manganese is quantitatively introduced in the structure as Mn{sup II}. Most of the Mn doping ions substitute Mg and possess a highly elongated octahedral environment. While photoluminescence and X-ray excited optical luminescence spectra show both orange (585 nm) and red (685 nm) {sup 4}T{sub 1} ({sup 4}G) ? {sup 6}A{sub 1} ({sup 6}S) emission of Mn{sup II}{sub Ca} and Mn{sup II}{sub Mg}, respectively, Mn{sup II}{sub Mg} red emission dominates long-lasting phosphorescence and thermally stimulated luminescence spectra. These results point to Mn{sup II}{sub Mg} as the preferential hole trap and recombination center in the long-lasting phosphorescence mechanism. An intense persistent red emission suitable for in vivo imaging probes is obtained for the highest nominal Mn content (7.5%)

  6. Southern Pine Based on Biorefinery Center

    SciTech Connect (OSTI)

    Ragauskas, Arthur J; Singh, Preet

    2014-01-10

    This program seeks to develop an integrated southern pine wood to biofuels/biomaterials processing facility on the Recipient’s campus, that will test advanced integrated wood processing technologies at the laboratory scale, including: • The generation of the bioethanol from pines residues and hemicelluloses extracted from pine woodchips; • The conversion of extracted woodchips to linerboard and bleach grade pulps; and • The efficient conversion of pine residues, bark and kraft cooking liquor into a useful pyrolysis oil.

  7. Table 7.2 Average Prices of Purchased Energy Sources, 2010;

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 7.2 Average Prices of Purchased Energy Sources, 2010; Level: National and Regional Data; Row: NAICS Codes; Column: All Energy Sources Collected; Unit: U.S. Dollars per Million Btu. Selected Wood and Other Biomass Components Coal Components Coke Electricity Components Natural Gas Components Steam Components Total Wood Residues Bituminous Electricity Diesel Fuel Motor Natural Gas Steam and Wood-Related and Electricity from Sources and Gasoline Pulping Liquor Natural Gas from Sources Steam

  8. Method for aqueous gold thiosulfate extraction using copper-cyanide pretreated carbon adsorption

    SciTech Connect (OSTI)

    Young, Courtney; Melashvili, Mariam; Gow, Nicholas V

    2013-08-06

    A gold thiosulfate leaching process uses carbon to remove gold from the leach liquor. The activated carbon is pretreated with copper cyanide. A copper (on the carbon) to gold (in solution) ratio of at least 1.5 optimizes gold recovery from solution. To recover the gold from the carbon, conventional elution technology works but is dependent on the copper to gold ratio on the carbon.

  9. Development of advanced technology of coke oven gas drainage treatment

    SciTech Connect (OSTI)

    Higashi, Tadayuki; Yamaguchi, Akikazu; Ikai, Kyozou; Kamiyama, Hisarou; Muto, Hiroshi

    1996-12-31

    In April 1994, commercial-scale application of ozone oxidation to ammonia liquor (which is primarily the water condensing from coke oven gas) to reduce its chemical oxygen demand (COD) was started at the Nagoya Works of Nippon Steel Corporation. This paper deals with the results of technical studies on the optimization of process operating conditions and the enlargement of equipment size and the operating purification system.

  10. Level: National and Regional Data; Row: NAICS Codes; Column: All Energy Sources Collected;

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 7.1 Average Prices of Purchased Energy Sources, 2006; Level: National and Regional Data; Row: NAICS Codes; Column: All Energy Sources Collected; Unit: U.S. Dollars per Physical Units. Selected Wood and Other Biomass Components Coal Components Coke Electricity Components Natural Gas Components Steam Components Total Wood Residues Bituminous Electricity Diesel Fuel Motor Natural Gas Steam and Wood-Related and Electricity from Sources and Gasoline Pulping Liquor Natural Gas from Sources

  11. Originally Released: August 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    August 2009" "Revised: October 2009" "Next MECS will be conducted in 2010" "Table 3.5 Selected Byproducts in Fuel Consumption, 2006;" " Level: National and Regional Data; " " Row: NAICS Codes; Column: Energy Sources;" " Unit: Trillion Btu." ,,,,,,,,,,"Waste" ,,,,"Blast",,,,"Pulping Liquor",,"Oils/Tars"

  12. RSE Table 3.5 Relative Standard Errors for Table 3.5

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Relative Standard Errors for Table 3.5;" " Unit: Percents." " "," "," "," "," "," "," "," ","Waste",," " " "," "," ","Blast"," "," ","Pulping Liquor"," ","Oils/Tars" "NAICS"," ","

  13. Released: August 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    RSE Table 3.6 Relative Standard Errors for Table 3.6;" " Unit: Percents." ,,"Selected Wood and Wood-Related Products" ,,,"Biomass" ,,,,,,"Wood Residues" ,,,,,,"and","Wood-Related" " "," ","Pulping Liquor"," "," ","Wood","Byproducts","and",," " "NAICS","

  14. Released: August 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 3.6 Selected Wood and Wood-Related Products in Fuel Consumption, 2006;" " Level: National and Regional Data; " " Row: Selected NAICS Codes; Column: Energy Sources;" " Unit: Trillion Btu." ,,"Selected Wood and Wood-Related Products" ,,,"Biomass" ,,,,,,"Wood Residues" ,,,,,,"and","Wood-Related" " "," ","Pulping Liquor"," ","

  15. Released: May 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    3.6 Selected Wood and Wood-Related Products in Fuel Consumption, 2010;" " Level: National and Regional Data; " " Row: Selected NAICS Codes; Column: Energy Sources;" " Unit: Trillion Btu." ,,"Selected Wood and Wood-Related Products" ,,,"Biomass" ,,,,,,"Wood Residues" ,,,,,,"and","Wood-Related" " "," ","Pulping Liquor"," ","

  16. DOE - Office of Legacy Management -- Rohm and Hass Co - PA 02

    Office of Legacy Management (LM)

    Rohm and Hass Co - PA 02 FUSRAP Considered Sites Site: ROHM & HASS CO. (PA.02 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: 5000 Richmond Street , Philadelphia , Pennsylvania PA.02-1 Evaluation Year: 1985 PA.02-2 Site Operations: Research and development on uranium recovery from carbonate leach liquors in the mid-1950s. PA.02-3 Site Disposition: Eliminated - Radiation levels below criteria PA.02-4 Radioactive Materials Handled:

  17. Pulping wastewater treatment: Aeration processes and equipment. (Latest citations from the Paper and Board, Printing, and Packaging Industries Research Associations database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-06-01

    The bibliography contains citations concerning plant operations and methods, pilot plant and laboratory tests and results of pulping mill wastewater treatment by aeration. Composition of effluent components including condensates, bleaching effluents, and spent liquor are discussed. Foreign and domestic plant efficiency, performance reports, and cost data are considered. Aerator design, lagoon treatment system upgrading considerations, and environmental aspects are included. (Contains a minimum of 88 citations and includes a subject term index and title list.)

  18. Some Lessons Learned from 20 Years in RedOx Flow Battery R&d | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Some Lessons Learned from 20 Years in RedOx Flow Battery R&d Some Lessons Learned from 20 Years in RedOx Flow Battery R&d Presentation by Steve Clarke, Applied Intellectual Capital, at the Flow Cells for Energy Storage Workshop held March 7-8, 2012, in Washington, DC. flowcells2012_clarke.pdf (1.38 MB) More Documents & Publications Flow Cells for Energy Storage Workshop Summary Report Flow Cells for Energy Storage Workshop Overview Energy Storage Systems 2014 Peer

  19. Evaluation of replacement thread lubricants for red lead and graphite in mineral oil

    SciTech Connect (OSTI)

    Jungling, T.L.; Rauth, D.R.; Goldberg, D.

    1998-04-30

    Eight commercially available thread lubricants were evaluated to determine the best replacement for Red Lead and Graphite in Mineral Oil (RLGMO). The evaluation included coefficient of friction testing, high temperature anti-seizing testing, room temperature anti-galling testing, chemical analysis for detrimental impurities, corrosion testing, off-gas testing, and a review of health and environmental factors. The coefficient of friction testing covered a wide variety of factors including stud, nut, and washer materials, sizes, manufacturing methods, surface coatings, surface finishes, applied loads, run-in cycles, and relubrication. Only one lubricant, Dow Corning Molykote P37, met all the criteria established for a replacement lubricant. It has a coefficient of friction range similar to RLGMO. Therefore, it can be substituted directly for RLGMO without changing the currently specified fastener torque values for the sizes, materials and conditions evaluated. Other lubricants did not perform as well as Molykote P37 in one or more test or evaluation categories.

  20. IS DUST FORMING ON THE RED GIANT BRANCH IN 47 Tuc?

    SciTech Connect (OSTI)

    Boyer, Martha L.; Gordon, Karl D.; Meixner, Margaret; Sewilo, Marta; Shiao, Bernie; Van Loon, Jacco Th.; McDonald, Iain; Babler, Brian; Bracker, Steve; Meade, Marilyn; Block, Miwa; Engelbracht, Charles; Misselt, Karl; Hora, Joe; Indebetouw, Remy; Whitney, Barbara

    2010-03-10

    Using Spitzer Infrared Array Camera (IRAC) observations from the SAGE-SMC Legacy program and archived Spitzer IRAC data, we investigate dust production in 47 Tuc, a nearby massive Galactic globular cluster. A previous study detected infrared excess, indicative of circumstellar dust, in a large population of stars in 47 Tuc, spanning the entire red giant branch (RGB). We show that those results suffered from effects caused by stellar blending and imaging artifacts and that it is likely that no stars below {approx}1 mag from the tip of the RGB are producing dust. The only stars that appear to harbor dust are variable stars, which are also the coolest and most luminous stars in the cluster.

  1. Surface plasmon polariton assisted red shift in excitonic emission of semiconductor microflowers

    SciTech Connect (OSTI)

    Parameswaran, Chithra; Warrier, Anita R. Bingi, Jayachandra Vijayan, C.

    2014-10-15

    We report on the study of metal nanoparticle-semiconductor hybrid system composed of β-indium sulfide (β-In{sub 2}S{sub 3}) and gold (Au) nanoparticles. β-In{sub 2}S{sub 3} micron sized flower like structures (∼1 μm) and Au nanoparticles (∼10 nm) were synthesized by chemical route. These Au nanoparticles have surface plasmon resonance at ∼ 520 nm. We study the influence of Au surface plasmon polaritons on the radiative properties of the β-In{sub 2}S{sub 3} microflowers. As a result of the coupling between the surface plasmon polaritons and the excitons there is a red shift ∼ 50 nm in emission spectrum of hybrid β-In{sub 2}S{sub 3}-Au system. Such hybrid systems provide scope for a control on the optical properties of semiconductor microstructures, thus rendering them suitable for specific device applications in optoelectronics and photovoltaics.

  2. Computational design of a red fluorophore ligase for site-specific protein labeling in living cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Daniel S.; Nivon, Lucas G.; Richter, Florian; Goldman, Peter J.; Deerinck, Thomas J.; Yao, Jennifer Z.; Richardson, Douglas; Phipps, William S.; Ye, Anne Z.; Ellisman, Mark H.; et al

    2014-10-13

    In this study, chemical fluorophores offer tremendous size and photophysical advantages over fluorescent proteins but are much more challenging to target to specific cellular proteins. Here, we used Rosetta-based computation to design a fluorophore ligase that accepts the red dye resorufin, starting from Escherichia coli lipoic acid ligase. X-ray crystallography showed that the design closely matched the experimental structure. Resorufin ligase catalyzed the site-specific and covalent attachment of resorufin to various cellular proteins genetically fused to a 13-aa recognition peptide in multiple mammalian cell lines and in primary cultured neurons. We used resorufin ligase to perform superresolution imaging of themore » intermediate filament protein vimentin by stimulated emission depletion and electron microscopies. This work illustrates the power of Rosetta for major redesign of enzyme specificity and introduces a tool for minimally invasive, highly specific imaging of cellular proteins by both conventional and superresolution microscopies.« less

  3. Stacked white OLED having separate red, green and blue sub-elements

    SciTech Connect (OSTI)

    Forrest, Stephen; Qi, Xiangfei; Slootsky, Michael

    2014-07-01

    The present invention relates to efficient organic light emitting devices (OLEDs). The devices employ three emissive sub-elements, typically emitting red, green and blue, to sufficiently cover the visible spectrum. Thus, the devices may be white-emitting OLEDs, or WOLEDs. Each sub-element comprises at least one organic layer which is an emissive layer--i.e., the layer is capable of emitting light when a voltage is applied across the stacked device. The sub-elements are vertically stacked and are separated by charge generating layers. The charge-generating layers are layers that inject charge carriers into the adjacent layer(s) but do not have a direct external connection.

  4. Establishment of a viable population of red-cockaded woodpeckers at the Savannah River Site

    SciTech Connect (OSTI)

    Allen, D.H.

    1989-01-01

    In 1985 the Southeastern Forest Experiment Station in cooperation with the Department of Energy (DOE), the Savannah River Forest Station (SRFS) and the Savannah River Ecology Laboratory (SREL) initiated a research/management program to restore a viable population of red-cockaded woodpeckers (RCW) to the Savannah River Site (SRS). The program has progresses in two phases. The first phase (1985-1987) focused on stabilizing the declining RCW population at SRS. The second phase (1988-present) has focused on facilitating population expansion. In 1989 we have focused our efforts on development of techniques for excavating new RCW cavities, identification of old-growth stands with the potential of providing new nesting habitat to support population expansion, continued flying squirrel control, continued translocations of RCW's as needed, and monitoring clan composition and reproduction.

  5. Computational design of a red fluorophore ligase for site-specific protein labeling in living cells

    SciTech Connect (OSTI)

    Liu, Daniel S.; Nivon, Lucas G.; Richter, Florian; Goldman, Peter J.; Deerinck, Thomas J.; Yao, Jennifer Z.; Richardson, Douglas; Phipps, William S.; Ye, Anne Z.; Ellisman, Mark H.; Drennan, Catherine L.; Baker, David; Ting, Alice Y.

    2014-10-13

    In this study, chemical fluorophores offer tremendous size and photophysical advantages over fluorescent proteins but are much more challenging to target to specific cellular proteins. Here, we used Rosetta-based computation to design a fluorophore ligase that accepts the red dye resorufin, starting from Escherichia coli lipoic acid ligase. X-ray crystallography showed that the design closely matched the experimental structure. Resorufin ligase catalyzed the site-specific and covalent attachment of resorufin to various cellular proteins genetically fused to a 13-aa recognition peptide in multiple mammalian cell lines and in primary cultured neurons. We used resorufin ligase to perform superresolution imaging of the intermediate filament protein vimentin by stimulated emission depletion and electron microscopies. This work illustrates the power of Rosetta for major redesign of enzyme specificity and introduces a tool for minimally invasive, highly specific imaging of cellular proteins by both conventional and superresolution microscopies.

  6. RED SUPERGIANT STARS IN THE LARGE MAGELLANIC CLOUD. I. THE PERIOD-LUMINOSITY RELATION

    SciTech Connect (OSTI)

    Yang Ming; Jiang, B. W. E-mail: bjiang@bnu.edu.cn

    2011-01-20

    From previous samples of red supergiants (RSGs) by various groups, 191 objects are assembled to compose a large sample of RSG candidates in LMC. For 189 of them, the identity as an RSG is verified by their brightness and color indexes in several near- and mid-infrared bands related to the Two Micron All Sky Survey (2MASS) JHK{sub S} bands and the Spitzer/IRAC and Spitzer/MIPS bands. From the visual time-series photometric observations by the ASAS and MACHO projects which cover nearly 8-10 years, the period and amplitude of light variation are analyzed carefully using both the phase dispersion minimization and Period04 methods. According to the properties of light variation, these objects are classified into five categories: (1) 20 objects are saturated in photometry or located in crowded stellar field with poor photometric results, (2) 35 objects with too complex variation to have any certain period, (3) 23 objects with irregular variation, (4) 16 objects with semi-regular variation, and (5) 95 objects with long secondary period (LSP) among which 31 have distinguishable short period and 51 have a long period shorter than 3000 days that can be determined with reasonable accuracy. For the semi-regular variables and the LSP variables with distinguishable short periods, the period-luminosity (P-L) relation is analyzed in the visual, near-infrared, and mid-infrared bands. It is found that the P-L relation is tight in the infrared bands such as the 2MASS JHK{sub S} bands and the Spitzer/IRAC bands, in particular in the Spitzer/IRAC [3.6] and [4.5] bands; meanwhile, the P-L relation is relatively sparse in the V band which may be caused by inhomogeneous interstellar extinction. The results are compared with others' P-L relationships for RSGs and the P-L sequences of red giants in LMC.

  7. Continuous sea-floor spreading in Red Sea: an alternative interpretation of magnetic anomaly pattern

    SciTech Connect (OSTI)

    La Brecque, J.L.; Zitellini

    1985-04-01

    The magnetic anomaly pattern over the Red Sea can be modeled as a continuous system of sea-floor spreading from the early Miocene to the present by using a timevarying process filter. The half spreading rate is approximately 1 cm/yr (0.4 in./yr) since initial rifting. The parameters that determine the process filter and development of the transition zone are the intrusion parameter (a measure of the dispersion of feeder dikes or horizontal strain about the rift axis), a flow parameter (a measure of the average flow width), and the effusion parameter (a measure of the volcanic effusion and thickness of layer 2). The authors estimate the flow parameter to be 2.7km(1.7 mi) and the intrusion parameter to be 7.5km(4.7 mi) at early rifting. These values suggest that a wide distribution of axial dikes or horizontal strain is the dominant factor in forming the magnetic anomaly pattern. Reduction in the width of the intrusion parameter and the effusion rate as rifting proceeded resulted in focusing of the strain, thinning of layer 2, and formation of the Red Sea deeps. Their modeling suggests that phase 2, or the stratoid phase, began about the time of anomaly 5C or chron C5C approximately 16 Ma. This age is compatible with geologic estimates of the initial rifting at the late Oligocene to early Miocene (Coleman, 1974; Gass, 1977). The opening rate for Africa-Arabia plate motion has remained relatively constant since early rifting although the African margin appears to be accreting faster than the Arabian plate.

  8. Factors affecting breeding season survival of Red-Headed Woodpeckers in South Carolina.

    SciTech Connect (OSTI)

    Kilgo, John, C.; Vukovich, Mark

    2011-11-18

    Red-headed woodpecker (Melanerpes erythrocephalus) populations have declined in the United States and Canada over the past 40 years. However, few demographic studies have been published on the species and none have addressed adult survival. During 2006-2007, we estimated survival probabilities of 80 radio-tagged red-headed woodpeckers during the breeding season in mature loblolly pine (Pinus taeda) forests in South Carolina. We used known-fate models in Program MARK to estimate survival within and between years and to evaluate the effects of foliar cover (number of available cover patches), snag density treatment (high density vs. low density), and sex and age of woodpeckers. Weekly survival probabilities followed a quadratic time trend, being lowest during mid-summer, which coincided with the late nestling and fledgling period. Avian predation, particularly by Cooper's (Accipiter cooperii) and sharp-shinned hawks (A. striatus), accounted for 85% of all mortalities. Our best-supported model estimated an 18-week breeding season survival probability of 0.72 (95% CI = 0.54-0.85) and indicated that the number of cover patches interacted with sex of woodpeckers to affect survival; females with few available cover patches had a lower probability of survival than either males or females with more cover patches. At the median number of cover patches available (n = 6), breeding season survival of females was 0.82 (95% CI = 0.54-0.94) and of males was 0.60 (95% CI = 0.42-0.76). The number of cover patches available to woodpeckers appeared in all 3 of our top models predicting weekly survival, providing further evidence that woodpecker survival was positively associated with availability of cover. Woodpecker survival was not associated with snag density. Our results suggest that protection of {ge}0.7 cover patches per ha during vegetation control activities in mature pine forests will benefit survival of this Partners In Flight Watch List species.

  9. FROM BLUE STAR-FORMING TO RED PASSIVE: GALAXIES IN TRANSITION IN DIFFERENT ENVIRONMENTS

    SciTech Connect (OSTI)

    Vulcani, Benedetta; Poggianti, Bianca M.; Fasano, Giovanni; Moretti, Alessia; Fritz, Jacopo; Calvi, Rosa; Paccagnella, Angela

    2015-01-01

    Exploiting a mass-complete (M {sub *}>10{sup 10.25} M {sub ?}) sample at 0.03red passive late types, and blue star-forming early types. Color fractions depend on mass and only for M {sub *}< 10{sup 10.7} M {sub ?} on environment. The incidence of red galaxies increases with increasing mass, and, for M {sub *}< 10{sup 10.7} M {sub ?}, decreases toward the group outskirts and in binary and single galaxies. The relative abundance of green and blue galaxies is independent of environment and increases monotonically with galaxy mass. We also inspect galaxy structural parameters, star-formation properties, histories, and ages and propose an evolutionary scenario for the different subpopulations. Color transformations are due to a reduction and suppression of the star-formation rate in both bulges and disks that does not noticeably affect galaxy structure. Morphological transitions are linked to an enhanced bulge-to-disk ratio that is due to the removal of the disk, not to an increase of the bulge. Our modeling suggests that green colors might be due to star-formation histories declining with long timescales, as an alternative scenario to the classical ''quenching'' processes. Our results suggest that galaxy transformations in star-formation activity and morphology depend neither on the environment nor on being a satellite or the most massive galaxy of a halo. The only environmental dependence we find is the higher fast quenching efficiency in groups giving origin to poststarburst signatures.

  10. Characteristics and sources of intermediate size particles in recovery boilers : final project report.

    SciTech Connect (OSTI)

    Baxter, Larry L.; Shaddix, Christopher R.; Verrill, Christopher L.; Wessel, Richard A.

    2005-02-01

    As part of the U.S. Department of Energy (DOE) Office of Industrial Technologies (OIT) Industries of the Future (IOF) Forest Products research program, a collaborative investigation was conducted on the sources, characteristics, and deposition of particles intermediate in size between submicron fume and carryover in recovery boilers. Laboratory experiments on suspended-drop combustion of black liquor and on black liquor char bed combustion demonstrated that both processes generate intermediate size particles (ISP), amounting to 0.5-2% of the black liquor dry solids mass (BLS). Measurements in two U.S. recovery boilers show variable loadings of ISP in the upper furnace, typically between 0.6-3 g/Nm{sup 3}, or 0.3-1.5% of BLS. The measurements show that the ISP mass size distribution increases with size from 5-100 {micro}m, implying that a substantial amount of ISP inertially deposits on steam tubes. ISP particles are depleted in potassium, chlorine, and sulfur relative to the fuel composition. Comprehensive boiler modeling demonstrates that ISP concentrations are substantially overpredicted when using a previously developed algorithm for ISP generation. Equilibrium calculations suggest that alkali carbonate decomposition occurs at intermediate heights in the furnace and may lead to partial destruction of ISP particles formed lower in the furnace. ISP deposition is predicted to occur in the superheater sections, at temperatures greater than 750 C, when the particles are at least partially molten.

  11. Testing of an advanced thermochemical conversion reactor system

    SciTech Connect (OSTI)

    Not Available

    1990-01-01

    This report presents the results of work conducted by MTCI to verify and confirm experimentally the ability of the MTCI gasification process to effectively generate a high-quality, medium-Btu gas from a wider variety of feedstock and waste than that attainable in air-blown, direct gasification systems. The system's overall simplicity, due to the compact nature of the pulse combustor, and the high heat transfer rates attainable within the pulsating flow resonance tubes, provide a decided and near-term potential economic advantage for the MTCI indirect gasification system. The primary objective of this project was the design, construction, and testing of a Process Design Verification System for an indirectly heated, thermochemical fluid-bed reactor and a pulse combustor an an integrated system that can process alternative renewable sources of energy such as biomass, black liquor, municipal solid waste and waste hydrocarbons, including heavy oils into a useful product gas. The test objectives for the biomass portion of this program were to establish definitive performance data on biomass feedstocks covering a wide range of feedstock qualities and characteristics. The test objectives for the black liquor portion of this program were to verify the operation of the indirect gasifier on commercial black liquor containing 65 percent solids at several temperature levels and to characterize the bed carbon content, bed solids particle size and sulfur distribution as a function of gasification conditions. 6 refs., 59 figs., 29 tabs.

  12. Evaluation of biological treatment of pharmaceutical waste water with PAC (powdered activated carbon) addition. Volume 1. Final report

    SciTech Connect (OSTI)

    Gardner, D.A.; Osantowski, R.A.

    1988-05-01

    A lack of information on applicable removal technologies for total chemical oxygen demand (TCOD) prevented promulgation of best available technology economically achievable (BAT) limitations and new source performance standards (NSPS) for TCOD for pharmaceutical manufacturing plants in 1983 (EPA/440/1-83/084). One technology that was evaluated was powdered activated carbon (PAC) addition to an activated-sludge system (PACT*). A viscous floating mass of mixed-liquor solids (VFMLS) developed in the PACT units and resulted in premature termination of the study. The purposes of the study were to: (1) attempt to find the cause of the formation of the VFMLS; (2) generate additional research data for TCOD removal from pharmaceutical waste water using the PACT process; (3) evaluate the efficiency of PACT in removing specific organics; (4) evaluate the effectiveness of PACT in reducing effluent aquatic toxicity and (5) evaluate the use of a selector to improve the settleability of the mixed liquor. One control unit, two PACT units and a unit equipped with a series of selector basins for improving the settling characteristics of the mixed-liquor suspended solids were operated.

  13. Method of treating alkali metal sulfide and carbonate mixtures

    DOE Patents [OSTI]

    Kohl, Arthur L.; Rennick, Robert D.; Savinsky, Martin W.

    1978-01-01

    A method of removing and preferably recovering sulfur values from an alkali metal sulfide and carbonate mixture comprising the steps of (1) introducing the mixture in an aqueous medium into a first carbonation zone and reacting the mixture with a gas containing a major amount of CO.sub.2 and a minor amount of H.sub.2 S; (2) introducing the resultant product from step 1 into a stripping zone maintained at subatmospheric pressure, and contacting this product with steam to produce a gaseous mixture, comprising H.sub.2 S and water vapor, and a liquor of reduced sulfide content; (3) introducing the liquor of reduced sulfide content into a second carbonation zone, and reacting the liquor with substantially pure gaseous CO.sub.2 in an amount sufficient to precipitate bicarbonate crystals and produce an offgas containing CO.sub.2 and H.sub.2 S for use in step 1; (4) recovering the bicarbonate crystals from step 3, and thermally decomposing the crystals to produce an alkaline metal carbonate product and a substantially pure CO.sub.2 offgas for use in step 3.

  14. Studies on reaction runaways for Urex/Purex solvent-nitric acid and red-oil synthesis

    SciTech Connect (OSTI)

    Kumar, Shekhar; Kumar, Rajnish; Koganti, S.B.

    2008-07-01

    In PUREX/UREX processes for recycling of spent nuclear fuels, 30% TBP solvent is used, This solvent has a small solubility in the aqueous phase. During concentration of the process solutions by an evaporation route, a runaway reaction between TBP and nitric acid is initiated at above 130 deg. C, leading to rapid pressurization and finally containment failure if proper venting is not provided. Red oil was synthesized for the first time in India, and its physical properties as well as thermodynamic parameters for the reaction were determined. It was experimentally established that the presence of metallic nitrates was not essential for red-oil formation as thought earlier. Various experiments have been completed for single-phase as well as two-phase runs. The most important finding of this work was lowering of the limiting acid concentration from the conventional values. In fact, in these experiments, red oil could be formed even at 2 N aqueous acidity. Thus, safety guidelines based on the classical literature are obsolete. New guidelines for the red-oil-safety are required. (authors)

  15. T-649: Red Hat Network Satellite Server Request Validation Flaw Permits Cross-Site Request Forgery Attacks

    Broader source: Energy.gov [DOE]

    The Red Hat Network (RHN) Satellite and Spacewalk services do not properly validate user-supplied. A remote user can create specially crafted HTML that, when loaded by a target authenticated user, will take actions on the target site acting as the target user.

  16. Investigation of intrinsic and extrinsic defects effective role on producing intense red emission in ZnO:Eu nanostructures

    SciTech Connect (OSTI)

    Najafi, Mehrdad Haratizadeh, Hamid

    2015-05-15

    Highlights: • Effective role of defects on producing red emission at indirect excitation. • V{sub Zn} and V{sub O} defects have important role on energy transfer. • Mg related defects and Zn{sub i} defects were responsible for blue emission. • Extrinsic and intrinsic defects mediated energy transfer to sensitize Eu{sup 3+} ions. • Decrease of red emission because of diminishing in oxygen vacancy. - Abstract: Europium doped ZnO nanorads and nanosheets were synthesized by hydrothermal method. Effects of Mg doping, morphology and annealing in oxygen ambient on structural and optical properties of ZnO nanostructures were investigated using X-ray diffraction (XRD), particle size analysis (PSA), thermo gravimetric analysis (TGA), differential thermal analysis (DTA), differential thermo gravimetry (DTG), scanning electron microscopy (SEM) and photoluminescence spectroscopy (PL). This study recommends that both of intrinsic and extrinsic defects facilitate energy transfer (ET) from the ZnO host to Eu{sup 3+} ions and consequently have efficient role on producing intense red emission at indirect excitation. The results also showed that annealing process improved the crystal structure of ZnO nanosheets due to decrease of surface defects; however decreased ET and red emission because of diminishing in oxygen vacancy. In addition in ZnO nanorods sample with more surface area in comparison with ZnO nanosheets sample deep level emissions are enhanced.

  17. Neutral red interlinked gold nanoparticles/multiwalled carbon nanotubes hybrid nanomaterial and its application for the detection of NADH

    SciTech Connect (OSTI)

    Tiwari, Ida Gupta, Mandakini

    2014-01-01

    Graphical abstract: - Highlights: • Fabricated a nanostructured hybrid material of GNPs/neutral red/MWCNTs. • GNPs decorated on MWCNT template by using neutral red as interlinker for first time. • Nanocomposite modified electrode employed successfully as sensor for NADH. • The electrode has high stability as it does not involve any biological entity. - Abstract: A novel nanocomposite of gold nanoparticles/neutral red/MWCNTs was prepared which was used to modify glassy carbon electrode. The prepared nanocomposite was physically characterized by scanning electron microscopy, transmission electron microscopy, zeta potential measurement, energy dispersive X-ray, FTIR spectroscopy, UV–visible spectroscopy. Electrochemical characterization was done using cyclic voltammetry technique. The modified glassy carbon electrode showed electrocatalytic activity toward the oxidation of NADH in 0.1 M phosphate buffer solution, pH 5.0. The modified electrode has better adhesion over the electrode surface, good stability as no leaching of neutral red based nanocomposite was observed. The oxidation of NADH started at 0.37 V and reached maxima at 0.52 V at the modified electrode surface. So the prepared composite modified electrode can be applied as electrochemical sensor for NADH. The sensitivity and detection limits of the modified glassy carbon electrode were found to be 0.588 μA/mM and 5 × 10{sup −7} at signal to noise ratio 3.

  18. A K{sub S} AND IRAC SELECTION OF HIGH-REDSHIFT EXTREMELY RED OBJECTS

    SciTech Connect (OSTI)

    Wang, Wei-Hao; Barger, Amy J.; Cowie, Lennox L.

    2012-01-10

    In order to find the most extreme dust-hidden high-redshift galaxies, we select 196 extremely red objects in the K{sub S} and Infrared Array Camera (IRAC) bands (KIEROs, [K{sub s} - 4.5 {mu}m]{sub AB} > 1.6) in the 0.06 deg{sup 2} Great Observatories Origins Deep Surveys-North (GOODS-N) region. This selection avoids the Balmer breaks of galactic spectra at z < 4 and picks up red galaxies with strong dust extinction. The photometric redshifts of KIEROs are between 1.5 and 5, with {approx}70% at z {approx} 2-4. KIEROs are very massive, with M{sub *} {approx} 10{sup 10}-10{sup 12} M{sub Sun }. They are optically faint and usually cannot be picked out by the Lyman break selection. On the other hand, the KIERO selection includes approximately half of the known millimeter and submillimeter galaxies in the GOODS-N. Stacking analyses in the radio, millimeter, and submillimeter all show that KIEROs are much more luminous than average 4.5 {mu}m-selected galaxies. Interestingly, the stacked fluxes for Advanced Camera for Surveys (ACS)-undetected KIEROs in these wave bands are 2.5-5 times larger than those for ACS-detected KIEROs. With the stacked radio fluxes and the local radio-FIR correlation, we derive mean infrared luminosities of (2-7) Multiplication-Sign 10{sup 12} L{sub Sun} and mean star formation rates (SFRs) of 400-1200 M{sub Sun} yr{sup -1} for KIEROs with redshifts. We do not find evidence of a significant subpopulation of passive KIEROs. The large stellar masses and SFRs imply that KIEROs are z > 2 massive galaxies in rapid formation. Our results show that a large sample of dusty ultraluminous sources can be selected in this way and that a large fraction of high-redshift star formation is hidden by dust.

  19. Assessment of stormwater impoundments as contaminant hazards to red-winged blackbirds

    SciTech Connect (OSTI)

    Eisemann, J.D.; Spading, D.

    1995-12-31

    Stormwater impoundments, a recent engineering solution to the treatment of stormwater, slow runoff and allow the settling of sediments and associated contaminants. They also provide valuable habitat in urban settings. In this study, the authors used red-winged blackbirds (Agelaius phoeniceus) to indicate potential contaminant hazards to avian species reared in stormwater impoundments. The authors studied four types of impoundments, grouped by the development in the supplying drainage; residential, commercial and highway development and a reference site with no development. They examined physiological biomarkers of 56, 8-day old nestlings, nesting parameters and foraging location of parent birds, food items delivered to nestlings, water chemistry, and sediments. Biomarker analysis included whole blood analysis for ALAD, blood serum chemistry (i.e., ALT, AST, CK, LDH, glucose, triglycerides, cholesterol, uric acid) and oxidative stress enzymes in liver tissue. Hepatic EROD and brain acetylcholinesterase levels were analyzed to assess exposure to contaminants other than metals. All samples were assayed for heavy metals by atomic absorption. A total of 198 nests were located. Overall nest success was significantly higher at the impoundment with no development in the supplying drainage. Focal parent feeding observations indicated females foraged less often in impoundments in highway locations. Preliminary analyses indicate sediments are not accumulating high metal levels. Serum and hepatic biomarker analyses indicate no statistically significant effects among drainage types.

  20. THE PERIOD-LUMINOSITY RELATION OF RED SUPERGIANT STARS IN THE SMALL MAGELLANIC CLOUD

    SciTech Connect (OSTI)

    Yang Ming; Jiang, B. W. E-mail: bjiang@bnu.edu.cn

    2012-07-20

    The characteristics of light variation of red supergiant (RSG) stars in the Small Magellanic Cloud (SMC) are analyzed based on the nearly 8-10 year data collected by the ASAS and MACHO projects. The 126 identified RSGs are classified into five categories accordingly: 20 with poor photometry, 55 with no reliable period, 6 with semi-regular variation, 15 with a long secondary period (LSP) and distinguishable short period, and 30 with only an LSP. For the semi-regular variables and the LSP variables with distinguishable short period, the K{sub S} -band period-luminosity (P-L) relation is analyzed and compared with that of the Galaxy, the Large Magellanic Cloud, and M33. It is found that the RSGs in these galaxies obey a similar P-L relation except for those in the Galaxy. In addition, the P-L relations in the infrared bands, namely, the 2MASS JHK{sub S} , Spitzer/IRAC, and Spitzer/MIPS 24 {mu}m bands, are derived with high reliability. The best P-L relation occurs in the Spitzer/IRAC [3.6] and [4.5] bands. Based on the comparison with the theoretical calculation of the P-L relation, the mode of pulsation of RSGs in the SMC is suggested to be the first-overtone radial mode.

  1. DUST IS FORMING ALONG THE RED GIANT BRANCH OF 47 Tuc

    SciTech Connect (OSTI)

    Origlia, Livia; Fusi Pecci, Flavio; Rood, Robert T.; Fabbri, Sara; Ferraro, Francesco R.; Dalessandro, Emanuele; Rich, R. Michael E-mail: flavio.fusipecci@oabo.inaf.i E-mail: sara.fabbri@studio.unibo.i E-mail: emanuele.dalessandr2@unibo.i

    2010-07-20

    We present additional evidence that dust is really forming along the red giant branch (RGB) of 47 Tuc at luminosities ranging from above the horizontal branch to the RGB tip. The presence of dust had been inferred from an infrared excess in the (K - 8) color, with K measured from high spatial resolution ground-based near-IR photometry and '8' referring to Spitzer-Infrared Array Camera (IRAC) 8 {mu}m photometry. We show how (K - 8) is a far more sensitive diagnostic for detecting tiny circumstellar envelopes around warm giants than colors using only the Spitzer-IRAC bands, for example, the (3.6 - 8) color used by Boyer et al. In addition, we also show high-resolution Hubble Space Telescope Advanced Camera for Surveys I-band images of the giant stars that have (K - 8) color excess. These images clearly demonstrate that the Boyer et al. statement that our detections of color excess associated with stars below the RGB tip arise from blends and artifacts is simply not valid.

  2. CYANOGEN IN NGC 1851 RED GIANT BRANCH AND ASYMPTOTIC GIANT BRANCH STARS: QUADRIMODAL DISTRIBUTIONS

    SciTech Connect (OSTI)

    Campbell, S. W.; Stancliffe, R. J.; Lattanzio, J. C.; Angelou, G. C.; D'Orazi, V.; Yong, D.; Wylie-de Boer, E. C.; Martell, S. L.; Grundahl, F.; Sneden, C. E-mail: david.yong@anu.edu.au

    2012-12-10

    The Galactic globular cluster NGC 1851 has raised much interest since Hubble Space Telescope photometry revealed that it hosts a double subgiant branch. Here we report on our homogeneous study into the cyanogen (CN) band strengths in the red giant branch (RGB) population (17 stars) and asymptotic giant branch (AGB) population (21 stars) using AAOmega/2dF spectra with R {approx} 3000. We discover that NGC 1851 hosts a quadrimodal distribution of CN band strengths in its RGB and AGB populations. This result supports the merger formation scenario proposed for this cluster, such that the CN quadrimodality could be explained by the superposition of two 'normal' bimodal populations. A small sample overlap with an abundance catalog allowed us to tentatively explore the relationship between our CN populations and a range of elemental abundances. We found a striking correlation between CN and [O/Na]. We also found that the four CN peaks may be paired-the two CN-weaker populations being associated with low Ba and the two CN-stronger populations with high Ba. If true, then s-process abundances would be a good diagnostic for disentangling the two original clusters in the merger scenario. More observations are needed to confirm the quadrimodality and also the relationship between the subpopulations. We also report CN results for NGC 288 as a comparison. Our relatively large samples of AGB stars show that both clusters have a bias toward CN-weak AGB populations.

  3. Red giant stars from the Sloan digital sky survey. II. Distances

    SciTech Connect (OSTI)

    Tan, Kefeng; Chen, Yuqin; Carrell, Kenneth; Zhao, Jingkun; Zhao, Gang

    2014-10-10

    We present distance determinations for a large and clean sample of red giant branch stars selected from the ninth data release of the Sloan Digital Sky Survey. The distances are calculated based on both observational cluster fiducials and theoretical isochrones. Distributions of distances from the two methods are very similar with peaks at about 10 kpc and tails extending to more than 70 kpc. We find that distances from the two methods agree well for the majority of the sample stars; though, on average, distances based on isochrones are 10% higher than those based on fiducials. We test the accuracy of our distance determinations using 332 stars from 10 Galactic globular and open clusters. The average relative deviation from the literature cluster distances is 4% for the fiducial-based distances and 8% for the isochrone-based distances, both of which are within the uncertainties. We find that the effective temperature and surface gravity derived from low-resolution spectra are not accurate enough to essentially improve the performance of distance determinations. However, for stars with significant extinction, effective temperature may help to better constrain their distances to some extent. We make our sample stars and their distances available from an online catalog. The catalog comprises 17,941 stars with reasonable distance estimations reaching to more than 70 kpc, which is suitable for the investigation of the formation and evolution of the Galaxy, especially the Galactic halo.

  4. METALLICITY AND KINEMATIC DISTRIBUTIONS OF RED HORIZONTAL-BRANCH STARS FROM THE SDSS SURVEY

    SciTech Connect (OSTI)

    Chen, Y. Q.; Zhao, G.; Zhao, J. K.; Xue, X. X.; Schuster, W. J. E-mail: schuster@astrosen.unam.m

    2010-08-15

    On the basis of a recently derived color-metallicity relation and stellar parameters from the Sloan Digital Sky Survey Data Release 7 spectroscopic survey, a large sample of red horizontal-branch (RHB) candidates have been selected to serve as standard candles. The metallicity and kinematic distributions of these stars indicate that they mainly originate from the thick-disk and the halo populations. The typical thick disk is characterized by the first group peaking at [Fe/H] {approx} -0.6, V{sub rot} {approx} 170 km s{sup -1} with a vertical scale height around |Z| {approx} 1.2 kpc, while stars with [Fe/H] < -0.9 are dominated by the halo population. Two sub-populations of the halo are suggested by the RHB stars peaking at [Fe/H] {approx} -1.3: one component with V{sub rot} > 0 km s{sup -1} (Halo I) shows a sign of metallicity gradient in the [Fe/H] versus |Z| diagram, while the other with V{sub rot} < 0 km s{sup -1} (Halo II) does not. The Halo I mainly clumps at the inner halo with R < 10 kpc and the Halo II comes both from the inner halo with R < 10 kpc and the outer halo with R > 10 kpc based on the star distribution in the R versus |Z| diagram.

  5. Infrared tip of the red giant branch and distances to the MAFFEI/IC 342 group

    SciTech Connect (OSTI)

    Wu, Po-Feng; Tully, R. Brent; Jacobs, Bradley A.; Rizzi, Luca; Dolphin, Andrew E.; Karachentsev, Igor D.

    2014-07-01

    In this paper, we extend the use of the tip of the red giant branch (TRGB) method to near-infrared wavelengths from the previously used I-band, using the Hubble Space Telescope (HST) Wide Field Camera 3 (WFC3). Upon calibration of a color dependency of the TRGB magnitude, the IR TRGB yields a random uncertainty of ∼5% in relative distance. The IR TRGB methodology has an advantage over the previously used Advance Camera for Surveys F606W and F814W filter set for galaxies that suffer from severe extinction. Using the IR TRGB methodology, we obtain distances toward three principal galaxies in the Maffei/IC 342 complex, which are located at low Galactic latitudes. New distance estimates using the TRGB method are 3.45{sub −0.13}{sup +0.13} Mpc for IC 342, 3.37{sub −0.23}{sup +0.32} Mpc for Maffei 1, and 3.52{sub −0.30}{sup +0.32} Mpc for Maffei 2. The uncertainties are dominated by uncertain extinction, especially for Maffei 1 and Maffei 2. Our IR calibration demonstrates the viability of the TRGB methodology for observations with the James Webb Space Telescope.

  6. Measuring subhalo mass in redMaPPer clusters with CFHT Stripe 82 Survey

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, Ran; Shan, Huanyuan; Kneib, Jean -Paul; Mo, Houjun; Rozo, Eduardo; Leauthaud, Alexie; Moustakas, John; Xie, Lizhi; Erben, Thomas; Van Waerbeke, Ludovic; et al

    2016-03-07

    Here, we use the shear catalogue from the CFHT Stripe-82 Survey to measure the subhalo masses of satellite galaxies in redMaPPer clusters. Assuming a Chabrier initial mass function and a truncated NFW model for the subhalo mass distribution, we find that the subhalo mass to galaxy stellar mass ratio increases as a function of projected halo-centric radius rp, from Msub/Mstar = 4.43+6.63–2.23 at rp ε [0.1, 0.3] h–1 Mpc to Msub/Mstar = 75.40+19.73–19.09 at rp ε [0.6, 0.9] h–1 Mpc. We also investigate the dependence of subhalo masses on stellar mass by splitting satellite galaxies into two stellar mass bins:more » 10 < log (Mstar/h–1M⊙) < 10.5 and 11 < log (Mstar/h–1 M⊙) < 12. The best-fitting subhalo mass of the more massive satellite galaxy bin is larger than that of the less massive satellites: log(Msub/h–1M⊙) = 11.14+0.66–0.73 (Msub/Mstar = 19.5+19.8–17.9) versus log(Msub/h–1M⊙) = 12.38+0.16–0.16 (Msub/Mstar = 21.1+7.4–7.7).« less

  7. Photoactive transparent nano-crystalline glass-ceramic for remazole red dye degradation

    SciTech Connect (OSTI)

    Gad-Allah, Tarek A.; Margha, Fatma H.

    2012-12-15

    Graphical abstract: Display Omitted Highlights: ? Preparation and characterization of novel transparent nanocrystalline glass-ceramic. ? Precipitation of photoactive phases by using controlled heat-treatment. ? Conservation of transparency along with photoactivity. ? Using the prepared nanocrystalline glass-ceramic in water purification. -- Abstract: Transparent glass ceramic material was prepared from alkali-borosilicate glass containing titania by proper heat treatment scheme. The prepared samples were characterized using differential thermal analysis, X-ray diffraction, transmission electron microscope, selected area electron diffraction and UVvisible spectroscopy. The applied heat treatment program allowed the crystallization of nano-crystalline anatase, rutile, barium titanate, titanium borate and silicate phases while maintaining the transparency. The precipitated nano-crystalline anatase and rutile phases were responsible for the observed high photocatalytic activity of the prepared samples. Samples of 24.29 and 32.39 TiO{sub 2} wt% showed better efficiency for the decolorization of remazole red dye compared with commercial-TiO{sub 2} used in preparation of glass-ceramic. The reuse of prepared glass-ceramic photocatalyst with nearly same efficiency for different times was also proved.

  8. A TALE OF DWARFS AND GIANTS: USING A z = 1.62 CLUSTER TO UNDERSTAND HOW THE RED SEQUENCE GREW OVER THE LAST 9.5 BILLION YEARS

    SciTech Connect (OSTI)

    Rudnick, Gregory H.; Tran, Kim-Vy; Papovich, Casey; Momcheva, Ivelina; Willmer, Christopher

    2012-08-10

    We study the red sequence in a cluster of galaxies at z = 1.62 and follow its evolution over the intervening 9.5 Gyr to the present day. Using deep YJK{sub s} imaging with the HAWK-I instrument on the Very Large Telescope, we identify a tight red sequence and construct its rest-frame i-band luminosity function (LF). There is a marked deficit of faint red galaxies in the cluster that causes a turnover in the LF. We compare the red-sequence LF to that for clusters at z < 0.8, correcting the luminosities for passive evolution. The shape of the cluster red-sequence LF does not evolve between z = 1.62 and z = 0.6 but at z < 0.6 the faint population builds up significantly. Meanwhile, between z = 1.62 and 0.6 the inferred total light on the red sequence grows by a factor of {approx}2 and the bright end of the LF becomes more populated. We construct a simple model for red-sequence evolution that grows the red sequence in total luminosity and matches the constant LF shape at z > 0.6. In this model the cluster accretes blue galaxies from the field whose star formation is quenched and who are subsequently allowed to merge. We find that three to four mergers among cluster galaxies during the 4 Gyr between z = 1.62 and z = 0.6 match the observed LF evolution between the two redshifts. The inferred merger rate is consistent with other studies of this cluster. Our result supports the picture that galaxy merging during the major growth phase of massive clusters is an important process in shaping the red-sequence population at all luminosities.

  9. Color tuning of light-emitting-diodes by modulating the concentration of red-emitting silicon nanocrystal phosphors

    SciTech Connect (OSTI)

    Barillaro, G. Strambini, L. M.

    2014-03-03

    Luminescent forms of nanostructured silicon have received significant attention in the context of quantum-confined light-emitting devices thanks to size-tunable emission wavelength and high-intensity photoluminescence, as well as natural abundance, low cost, and non-toxicity. Here, we show that red-emitting silicon nanocrystal (SiN) phosphors, obtained by electrochemical erosion of silicon, allow for effectively tuning the color of commercial light-emitting-diodes (LEDs) from blue to violet, magenta, and red, by coating the LED with polydimethylsiloxane encapsulating different SiN concentrations. High reliability of the tuning process, with respect to SiN fabrication and concentration, and excellent stability of the tuning color, with respect to LED bias current, is demonstrated through simultaneous electrical/optical characterization of SiN-modified commercial LEDs, thus envisaging exciting perspectives for silicon nanocrystals in the field of light-emitting applications.

  10. SDSS J001641-000925: THE FIRST STABLE RED DWARF CONTACT BINARY WITH A CLOSE-IN STELLAR COMPANION

    SciTech Connect (OSTI)

    Qian, S.-B.; Jiang, L.-Q.; Zhu, L.-Y.; Zhao, E. G.; He, J.-J.; Liao, W.-P.; Wang, J.-J.; Liu, L.; Zhou, X.; Liu, N. P.; Fernández Lajús, E.; Soonthornthum, B.; Rattanasoon, S.; Aukkaravittayapun, S.

    2015-01-10

    SDSS J001641-000925 is the first red dwarf contact binary star with an orbital period of 0.19856 days that is one of the shortest known periods among M-dwarf binary systems. The orbital period was detected to be decreasing rapidly at a rate of P-dot ∼8 s yr{sup −1}. This indicated that SDSS J001641-000925 was undergoing coalescence via a dynamical mass transfer or loss and thus this red dwarf contact binary is dynamically unstable. To understand the properties of the period change, we monitored the binary system photometrically from 2011 September 2 to 2014 October 1 by using several telescopes in the world and 25 eclipse times were determined. It is discovered that the rapid decrease of the orbital period is not true. This is contrary to the prediction that the system is merging driven by rapid mass transfer or loss. Our preliminary analysis suggests that the observed minus calculated (O–C) diagram shows a cyclic oscillation with an amplitude of 0.00255 days and a period of 5.7 yr. The cyclic variation can be explained by the light travel time effect via the presence of a cool stellar companion with a mass of M {sub 3}sin i' ∼ 0.14 M {sub ☉}. The orbital separation between the third body and the central binary is about 2.8 AU. These results reveal that the rarity of red dwarf contact binaries could not be explained by rapidly dynamical destruction and the presence of the third body helps to form the red dwarf contact binary.

  11. Engineering ESPT Pathways Based on Structural Analysis of LSSmKate Red Fluorescent Proteins with Large Stokes Shift

    SciTech Connect (OSTI)

    Piatkevich, K.; Malashkevich, V; Almo, S; Verkhusha, V

    2010-01-01

    LSSmKate1 and LSSmKate2 are monomeric red fluorescent proteins (RFPs) with large Stokes shifts (LSSs), which allows for efficient separation of absorbance and emission maxima, as well as for excitation with conventional two-photon laser sources. These LSSmKates differ by a single amino acid substitution at position 160 and exhibit absorbance maxima around 460 nm, corresponding to a neutral DsRed-like chromophore. However, excitation at 460 nm leads to fluorescence emission above 600 nm. Structures of LSSmKate1 and LSSmKate2, determined at resolutions of 2.0 and 1.5 {angstrom}, respectively, revealed that the predominant DsRed-chromophore configurations are cis for LSSmKate1 but trans for LSSmKate2. Crystallographic and mutagenesis analyses, as well as isotope and temperature dependences, suggest that an excited-state proton transfer (ESPT) is responsible for the LSSs observed in LSSmKates. Hydrogen bonding between the chromophore hydroxyl and Glu160 in LSSmKate1 and a proton relay involving the chromophore tyrosine hydroxyl, Ser158, and the Asp160 carboxylate in LSSmKate2 represent the putative ESPT pathways. Comparisons with mKeima LSS RFP suggest that similar proton relays could be engineered in other FPs. Accordingly, we mutated positions 158 and 160 in several conventional red-shifted FPs, including mNeptune, mCherry, mStrawberry, mOrange, and mKO, and the resulting FP variants exhibited LSS fluorescence emission in a wide range of wavelengths from 560 to 640 nm. These data suggest that different chromophores formed by distinct tripeptides in different environments can be rationally modified to yield RFPs with novel photochemical properties.

  12. Rotational and radial velocities of 1.3-2.2 M {sub ☉} red giants in open clusters

    SciTech Connect (OSTI)

    Carlberg, Joleen K.

    2014-06-01

    This study presents the rotational distribution of red giant (RG) stars in 11 old to intermediate age open clusters. The masses of these stars are all above the Kraft break, so they lose negligible amounts of their birth angular momentum (AM) during the main-sequence (MS) evolution. However, they do span a mass range with quite different AM distributions imparted during formation, with the stars less massive than ∼1.6M {sub ☉} arriving on the MS with lower rotation rates than the more massive stars. The majority of RGs in this study are slow rotators across the entire red giant branch regardless of mass, supporting the picture that intermediate-mass stars rapidly spin down when they evolve off the MS and develop convection zones capable of driving a magnetic dynamo. Nevertheless, a small fraction of RGs in open clusters show some level of enhanced rotation, and faster rotators are as common in these clusters as in the field RG population. Most of these enhanced rotators appear to be red clump stars, which is also true of the underlying stellar sample, while others are clearly RGs that are above or below the clump. In addition to rotational velocities, the radial velocities (RVs) and membership probabilities of individual stars are also presented. Cluster heliocentric RVs for NGC 6005 and Pismis 18 are reported for the first time.

  13. Primer on Use of Multi-Spectral and Infra Red Imaging for On-Site Inspections

    SciTech Connect (OSTI)

    Henderson, J R

    2010-10-26

    The purpose of an On-Site Inspection (OSI) is to determine whether a nuclear explosion has occurred in violation of the Comprehensive Nuclear Test Ban Treaty (CTBT), and to gather information which might assist in identifying the violator (CTBT, Article IV, Paragraph 35) Multi-Spectral and Infra Red Imaging (MSIR) is allowed by the treaty to detect observables which might help reduce the search area and thus expedite an OSI and make it more effective. MSIR is permitted from airborne measurements, and at and below the surface to search for anomalies and artifacts (CTBT, Protocol, Part II, Paragraph 69b). The three broad types of anomalies and artifacts MSIR is expected to be capable of observing are surface disturbances (disturbed earth, plant stress or anomalous surface materials), human artifacts (man-made roads, buildings and features), and thermal anomalies. The purpose of this Primer is to provide technical information on MSIR relevant to its use for OSI. It is expected that this information may be used for general background information, to inform decisions about the selection and testing of MSIR equipment, to develop operational guidance for MSIR use during an OSI, and to support the development of a training program for OSI Inspectors. References are provided so readers can pursue a topic in more detail than the summary information provided here. The following chapters will provide more information on how MSIR can support an OSI (Section 2), a short summary what Multi-Spectral Imaging and Infra Red Imaging is (Section 3), guidance from the CTBT regarding the use of MSIR (Section 4), and a description of several nuclear explosion scenarios (Section 5) and consequent observables (Section 6). The remaining sections focus on practical aspects of using MSIR for an OSI, such as specification and selection of MSIR equipment, operational considerations for deployment of MISR equipment from an aircraft, and the conduct of field exercises to mature MSIR for an OSI

  14. EVIDENCE FOR (AND AGAINST) PROGENITOR BIAS IN THE SIZE GROWTH OF COMPACT RED GALAXIES

    SciTech Connect (OSTI)

    Keating, Stephanie K.; Abraham, Roberto G.; Schiavon, Ricardo; Graves, Genevieve; Damjanov, Ivana; Yan, Renbin; Newman, Jeffrey; Simard, Luc

    2015-01-01

    Most massive, passive galaxies are compact at high redshifts, but similarly compact massive galaxies are rare in the local universe. The most common interpretation of this phenomenon is that massive galaxies have grown in size by a factor of about five since redshift z = 2. An alternative explanation is that recently quenched massive galaxies are larger (a {sup p}rogenitor bias{sup )}. In this paper, we explore the importance of progenitor bias by looking for systematic differences in the stellar populations of compact early-type galaxies in the DEEP2 survey as a function of size. Our analysis is based on applying the statistical technique of bootstrap resampling to constrain differences in the median ages of our samples and to begin to characterize the distribution of stellar populations in our co-added spectra. The light-weighted ages of compact early-type galaxies at redshifts 0.5 < z < 1.4 are compared to those of a control sample of larger galaxies at similar redshifts. We find that massive compact early-type galaxies selected on the basis of red color and high bulge-to-total ratio are younger than similarly selected larger galaxies, suggesting that size growth in these objects is not driven mainly by progenitor bias, and that individual galaxies grow as their stellar populations age. However, compact early-type galaxies selected on the basis of image smoothness and high bulge-to-total ratio are older than a control sample of larger galaxies. Progenitor bias will play a significant role in defining the apparent size changes of early-type galaxies if they are selected on the basis of the smoothness of their light distributions.

  15. PLANET ENGULFMENT BY {approx}1.5-3 M{sub sun} RED GIANTS

    SciTech Connect (OSTI)

    Kunitomo, M.; Ikoma, M.; Sato, B.; Ida, S.; Katsuta, Y.

    2011-08-20

    Recent radial-velocity surveys for GK clump giants have revealed that planets also exist around {approx}1.5-3 M{sub sun} stars. However, no planets have been found inside 0.6 AU around clump giants, in contrast to solar-type main-sequence stars, many of which harbor short-period planets such as hot Jupiters. In this study, we examine the possibility that planets were engulfed by host stars evolving on the red-giant branch (RGB). We integrate the orbital evolution of planets in the RGB and helium-burning phases of host stars, including the effects of stellar tide and stellar mass loss. Then we derive the critical semimajor axis (or the survival limit) inside which planets are eventually engulfed by their host stars after tidal decay of their orbits. Specifically, we investigate the impact of stellar mass and other stellar parameters on the survival limit in more detail than previous studies. In addition, we make detailed comparisons with measured semimajor axes of planets detected so far, which no previous study has done. We find that the critical semimajor axis is quite sensitive to stellar mass in the range between 1.7 and 2.1 M{sub sun}, which suggests a need for careful comparison between theoretical and observational limits of the existence of planets. Our comparison demonstrates that all planets orbiting GK clump giants that have been detected are beyond the survival limit, which is consistent with the planet-engulfment hypothesis. However, on the high-mass side (>2.1M{sub sun}), the detected planets are orbiting significantly far from the survival limit, which suggests that engulfment by host stars may not be the main reason for the observed lack of short-period giant planets. To confirm our conclusion, the detection of more planets around clump giants, especially with masses {approx}> 2.5M{sub sun}, is required.

  16. THE RED SUPERGIANT PROGENITOR OF SUPERNOVA 2012aw (PTF12bvh) IN MESSIER 95

    SciTech Connect (OSTI)

    Van Dyk, Schuyler D. [Spitzer Science Center/Caltech, Mailcode 220-6, Pasadena, CA 91125 (United States); Cenko, S. Bradley; Filippenko, Alexei V., E-mail: vandyk@ipac.caltech.edu, E-mail: cenko@berkeley.edu, E-mail: afilippenko@berkeley.edu [Department of Astronomy, University of California, Berkeley, CA 94720-3411 (United States); and others

    2012-09-10

    We report on the direct detection and characterization of the probable red supergiant (RSG) progenitor of the intermediate-luminosity Type II-Plateau (II-P) supernova (SN) 2012aw in the nearby (10.0 Mpc) spiral galaxy Messier 95 (M95; NGC 3351). We have identified the star in both Hubble Space Telescope images of the host galaxy, obtained 17-18 yr prior to the explosion, and near-infrared ground-based images, obtained 6-12 yr prior to the SN. The luminous supergiant showed evidence for substantial circumstellar dust, manifested as excess line-of-sight extinction. The effective total-to-selective ratio of extinction to the star was R'{sub V} Almost-Equal-To 4.35, which is significantly different from that of diffuse interstellar dust (i.e., R{sub V} = 3.1), and the total extinction to the star was therefore, on average, A{sub V} Almost-Equal-To 3.1 mag. We find that the observed spectral energy distribution for the progenitor star is consistent with an effective temperature of 3600 K (spectral type M3), and that the star therefore had a bolometric magnitude of -8.29. Through comparison with recent theoretical massive-star evolutionary tracks we can infer that the RSG progenitor had an initial mass 15 {approx}< M{sub ini}(M{sub Sun }) < 20. Interpolating by eye between the available tracks, we surmise that the star had initial mass {approx}17-18 M{sub Sun }. The circumstellar dust around the progenitor must have been destroyed in the explosion, as the visual extinction to the SN is found to be low (A{sub V} = 0.24 mag with R{sub V} = 3.1).

  17. CHEMICAL ABUNDANCE ANALYSIS OF A NEUTRON-CAPTURE ENHANCED RED GIANT IN THE BULGE PLAUT FIELD

    SciTech Connect (OSTI)

    Johnson, Christian I.; Rich, R. Michael [Department of Physics and Astronomy, UCLA, 430 Portola Plaza, Box 951547, Los Angeles, CA 90095-1547 (United States)] [Department of Physics and Astronomy, UCLA, 430 Portola Plaza, Box 951547, Los Angeles, CA 90095-1547 (United States); McWilliam, Andrew, E-mail: cijohnson@astro.ucla.edu, E-mail: rmr@astro.ucla.edu, E-mail: cjohnson@cfa.harvard.edu, E-mail: andy@obs.carnegiescience.edu [Observatories of the Carnegie Institution of Washington, Pasadena, CA 91101 (United States)] [Observatories of the Carnegie Institution of Washington, Pasadena, CA 91101 (United States)

    2013-09-20

    We present chemical abundances for 27 elements ranging from oxygen to erbium in the metal-poor ([Fe/H] = 1.67) bulge red giant branch star 2MASS 18174532-3353235. The results are based on equivalent width and spectrum synthesis analyses of a high-resolution (R ? 30, 000) spectrum obtained with the Magellan-MIKE spectrograph. While the light (Z ?< 30) element abundance patterns match those of similar metallicity bulge and halo stars, the strongly enhanced heavy element abundances are more similar to 'r-II' halo stars (e.g., CS 22892-052) typically found at [Fe/H] ?< 2.5. We find that the heaviest elements (Z ? 56) closely follow the scaled-solar r-process abundance pattern. We do not find evidence supporting significant s-process contributions; however, the intermediate mass elements (e.g., Y and Zr) appear to have been produced through a different process than the heaviest elements. The light and heavy element abundance patterns of 2MASS 18174532-3353235 are in good agreement with the more metal-poor r-process enhanced stars CS 22892-052 and BD +17{sup o}3248. 2MASS 18174532-3353235 also shares many chemical characteristics with the similar metallicity but comparatively ?-poor Ursa Minor dwarf galaxy giant COS 82. Interestingly, the Mo and Ru abundances of 2MASS 18174532-3353235 are also strongly enhanced and follow a similar trend recently found to be common in moderately metal-poor main-sequence turn-off halo stars.

  18. Fish debris record the hydrothermal activity in the Atlantis II deep sediments (Red Sea)

    SciTech Connect (OSTI)

    Oudin, E.; Cocherie, A.

    1988-01-01

    The REE and U, Th, Zr, Hf, Sc have been analyzed in samples from Atlantis II and Shaban/Jean Charcot Deeps in the Red Sea. The high Zr/Hf ratio in some sediments indicates the presence of fish debris or of finely crystallized apatite. The positive ..sigma..REE vs P/sub 2/O/sub 5/ and ..sigma..REE vs Zr/Hf correlations show that fish debris and finely crystallized apatite are the main REE sink in Atlantis II Deep sediments as in other marine environments. The hydrothermal sediments and the fish debris concentrates have similar REE patterns, characterized by a LREE enrichment and a large positive Eu anomaly. This REE pattern is also observed in E.P.R. hydrothermal solutions. Fish debris from marine environments acquire their REE content and signature mostly from sea water during early diagenesis. The hydrothermal REE signature of Atlantis II Deep fish debris indicate that they probably record the REE signature of their hydrothermal sedimentation and diagenetic environment. The different REE signatures of the Shaban/Jean Charcot and Atlantis II Deep hydrothermal sediments suggest a sea water-dominated brine in the Shaban/Jean Charcot Deep as opposed to the predominantly hydrothermal brine in Atlantis II Deep. Atlantis II Deep fish debris are also characterized by their high U but low Th contents. Their low Th contents probably reflect the low Th content of the various possible sources (sea water, brine, sediments). Their U contents are probably controlled by the redox conditions of sedimentation.

  19. X-ray observation of the shocked red supergiant wind of Cassiopeia A

    SciTech Connect (OSTI)

    Lee, Jae-Joon; Park, Sangwook; Hughes, John P.; Slane, Patrick O.

    2014-07-01

    Cas A is a Galactic supernova remnant whose supernova explosion is observed to be of Type IIb from spectroscopy of its light echo. Having its SN type known, observational constraints on the mass-loss history of Cas A's progenitor can provide crucial information on the final fate of massive stars. In this paper, we study X-ray characteristics of the shocked ambient gas in Cas A using the 1 Ms observation carried out with the Chandra X-Ray Observatory and try to constrain the mass-loss history of the progenitor star. We identify thermal emission from the shocked ambient gas along the outer boundary of the remnant. Comparison of measured radial variations of spectroscopic parameters of the shocked ambient gas to the self-similar solutions of Chevalier show that Cas A is expanding into a circumstellar wind rather than into a uniform medium. We estimate a wind density n {sub H} ? 0.9 0.3 cm{sup 3} at the current outer radius of the remnant (?3 pc), which we interpret as a dense slow wind from a red supergiant (RSG) star. Our results suggest that the progenitor star of Cas A had an initial mass around 16 M {sub ?}, and its mass before the explosion was about 5 M {sub ?}, with uncertainties of several tens of percent. Furthermore, the results suggest that, among the mass lost from the progenitor star (?11 M {sub ?}), a significant amount (more than 6 M {sub ?}) could have been via its RSG wind.

  20. Red giant stars from Sloan Digital Sky Survey. I. The general field

    SciTech Connect (OSTI)

    Chen, Y. Q.; Zhao, G.; Carrell, K.; Zhao, J. K.; Tan, K. F.; Nissen, P. E.; Wei, P. E-mail: pen@phys.au.dk

    2014-11-01

    We have obtained a sample of ∼22,000 red giant branch (RGB) stars based on stellar parameters, provided by the ninth data release of the Sloan Digital Sky Survey, and the CH(G)/MgH indices, measured from the included spectra. The Galactic rest-frame velocity of V {sub gsr} versus longitude for the sample shows the existence of several groups of stars from globular clusters and known streams. Excluding these substructures, a sample of ∼16,000 RGB stars from the general field is used to investigate the properties of the thick disk, the inner halo, and the outer halo of our Galaxy. The metallicity and rotational velocity distributions are investigated for stars at 0 kpc < |Z| < 10 kpc. It is found that the canonical thick disk dominates at 0 kpc < |Z| < 2 kpc and its contribution becomes negligible at |Z| > 3 kpc. The MWTD is present and overlaps with the inner halo at 1 kpc < |Z| < 3 kpc. The inner halo starts at 2 kpc < |Z| < 3 kpc and becomes the dominated population for 4 kpc < |Z| < 10 kpc. For halo stars with |Z| > 5 kpc, bimodal metallicity distributions are found for 20 kpc < |Z| < 25 kpc and 35 kpc < RR < 45 kpc, which suggests a dual halo, the inner and the outer halo, as reported in Carollo et al. at low |Z| values. The peak of metallicity for the inner halo is at [Fe/H] ∼ –1.6 and appears to be at [Fe/H] ∼ –2.3 for the outer halo. The transition point from the inner to the outer halo is located at |Z| ∼ 20 kpc and RR ∼ 35 kpc.

  1. Genetic stratigraphy and reservoir characterization of the Spiro sandstone, Red Oak Field, Arkoma Basin, southeastern Oklahoma

    SciTech Connect (OSTI)

    Horn, B.W. )

    1996-01-01

    The Lower Atokan Spiro sandstone is a mixed carbonate-silicilastic reservoir that produces hydrocarbons from three discrete stratigraphic intervals at the Red Oak Field. Reservoir-quality sandstones develop in the seaward stepping sub-Spiro sequence (highstand system tract), landward stepping Foster [open quote]channel,[close quotes] and upper Spiro depositional sequences (transgressive and highstand system tract). The sub-Spiro and Foster [open quote]channel[close quote] sequences are separated by regional unconformity interpreted as a sequence boundary. Regressive marine shoreface cycles, genetically related to the sub-Spiro shale, comprise the lowermost producing interval. Fluvial/estuarine valley-fill (Foster channel) sandstones progressively onlap the sequence boundary overlying the regressive shoreface cycles and juxtapose reservoir-quality sandstones of different sequences, creating a complex reservoir architecture. Upper Spiro reservoir sandstones are developed within marine shoreface cycles that are deposited in a landward-stepping succession (highstand systems tract) following the drowning of incised paleovalleys. These aggradational / retrogradational successions downlap onto the valley-fill and sub-Spiro sequences representing the final stages of Spiro deposition prior to the high stand of sea level during Middle Atokan time. Regional stratigraphic correlations demonstrate progressive basinward truncation of the sub-Spiro regressive shoreface cycles by an erosional surface, creating a network of incised paleovalleys across the Pennsylvanian shelf. Based on core, well log, and outcrop interpretations, the magnitude of the facies offset across this sequence boundary indicates that a significant volume of reservoir-quality sediment has been partitioned basinward of the current producing areas.

  2. Monomeric [alpha]-Synuclein Binds Congo Red Micelles in a Disordered Manner

    SciTech Connect (OSTI)

    Maltsev, Alexander S.; Grishaev, Alexander; Bax, Ad

    2012-03-15

    The histological dye Congo Red (CR) previously has been shown to inhibit {alpha}-synuclein (aS) fibrillation, but the mode of this inhibition remained unclear. Because of favorable exchange kinetics, interaction between CR and aS lends itself to a detailed nuclear magnetic resonance study, and relaxation dispersion measurements yield the bound fraction and time scales for the interaction of aS with CR. We find that at pH 6, CR exists as a micelle, and at a CR:aS molar ratio of {approx}1, only a small fraction of aS ({approx}2%) is bound to these micelles. Rapid exchange (k{sub ex} {approx} 3000 s{sup -1}) between the free and CR-bound states broadens and strongly attenuates resonances of aS by two processes: a magnetic field-dependent contribution, caused by the chemical shift difference between the two states, and a nearly field-independent contribution caused by slower tumbling of aS bound to the CR micelle. The salt dependence of the interaction suggests a predominantly electrostatic mechanism for the 60 N-terminal residues, while the weaker interaction between residues 61-100 and CR is mostly hydrophobic. Chemical shift and transferred NOE data indicate that aS becomes slightly more helical but remains largely disordered when bound to CR. Results indicate that inhibition of fibril formation does not result from binding of CR to free aS and, therefore, must result from interaction of aS fibrils or protofibrils with CR micelles.

  3. Systematic review of the influence of foraging habitat on red-cockaded woodpecker reproductive success.

    SciTech Connect (OSTI)

    Garabedian, James E.

    2014-04-01

    Relationships between foraging habitat and reproductive success provide compelling evidence of the contribution of specific vegetative features to foraging habitat quality, a potentially limiting factor for many animal populations. For example, foraging habitat quality likely will gain importance in the recovery of the threatened red-cockaded woodpecker Picoides borealis (RCW) in the USA as immediate nesting constraints are mitigated. Several researchers have characterized resource selection by foraging RCWs, but emerging research linking reproductive success (e.g. clutch size, nestling and fledgling production, and group size) and foraging habitat features has yet to be synthesized. Therefore, we reviewed peer-refereed scientific literature and technical resources (e.g. books, symposia proceedings, and technical reports) that examined RCW foraging ecology, foraging habitat, or demography to evaluate evidence for effects of the key foraging habitat features described in the species’ recovery plan on group reproductive success. Fitness-based habitat models suggest foraging habitat with low to intermediate pine Pinus spp. densities, presence of large and old pines, minimal midstory development, and herbaceous groundcover support more productive RCW groups. However, the relationships between some foraging habitat features and RCW reproductive success are not well supported by empirical data. In addition, few regression models account for > 30% of variation in reproductive success, and unstandardized multiple and simple linear regression coefficient estimates typically range from -0.100 to 0.100, suggesting ancillary variables and perhaps indirect mechanisms influence reproductive success. These findings suggest additional research is needed to address uncertainty in relationships between foraging habitat features and RCW reproductive success and in the mechanisms underlying those relationships.

  4. Tracing chemical evolution over the extent of the Milky Way's disk with apogee red clump stars

    SciTech Connect (OSTI)

    Nidever, David L.; Bovy, Jo; Bird, Jonathan C.; Andrews, Brett H.; Johnson, Jennifer A.; Weinberg, David H.; Hayden, Michael; Holtzman, Jon; Feuillet, Diane; Majewski, Steven R.; García Pérez, Ana E.; Smith, Verne; Robin, Annie C.; Sobeck, Jennifer; Cunha, Katia; Allende Prieto, Carlos; Zasowski, Gail; Schiavon, Ricardo P.; Schneider, Donald P.; Shetrone, Matthew; and others

    2014-11-20

    We employ the first two years of data from the near-infrared, high-resolution SDSS-III/APOGEE spectroscopic survey to investigate the distribution of metallicity and α-element abundances of stars over a large part of the Milky Way disk. Using a sample of ≈10, 000 kinematically unbiased red-clump stars with ∼5% distance accuracy as tracers, the [α/Fe] versus [Fe/H] distribution of this sample exhibits a bimodality in [α/Fe] at intermediate metallicities, –0.9 < [Fe/H] <–0.2, but at higher metallicities ([Fe/H] ∼+0.2) the two sequences smoothly merge. We investigate the effects of the APOGEE selection function and volume filling fraction and find that these have little qualitative impact on the α-element abundance patterns. The described abundance pattern is found throughout the range 5 < R < 11 kpc and 0 < |Z| < 2 kpc across the Galaxy. The [α/Fe] trend of the high-α sequence is surprisingly constant throughout the Galaxy, with little variation from region to region (∼10%). Using simple galactic chemical evolution models, we derive an average star-formation efficiency (SFE) in the high-α sequence of ∼4.5 × 10{sup –10} yr{sup –1}, which is quite close to the nearly constant value found in molecular-gas-dominated regions of nearby spirals. This result suggests that the early evolution of the Milky Way disk was characterized by stars that shared a similar star-formation history and were formed in a well-mixed, turbulent, and molecular-dominated ISM with a gas consumption timescale (SFE{sup –1}) of ∼2 Gyr. Finally, while the two α-element sequences in the inner Galaxy can be explained by a single chemical evolutionary track, this cannot hold in the outer Galaxy, requiring, instead, a mix of two or more populations with distinct enrichment histories.

  5. ABUNDANCES OF C, N, Sr, AND Ba ON THE RED GIANT BRANCH OF {omega} CENTAURI

    SciTech Connect (OSTI)

    Stanford, Laura M.; Da Costa, G. S.; Norris, John E. E-mail: gdc@mso.anu.edu.a

    2010-05-10

    Abundances relative to iron for carbon, nitrogen, strontium, and barium are presented for 33 stars on the red giant branch (RGB) of the globular cluster {omega} Centauri. They are based on intermediate-resolution spectroscopic data covering the blue spectral region analyzed using spectrum synthesis techniques. The data reveal the existence of a broad range in the abundances of these elements, and a comparison with similar data for main-sequence stars enables insight into the evolutionary history of the cluster. The majority of the RGB stars were found to be depleted in carbon, i.e., [C/Fe] < 0, while [N/Fe] for the same stars shows a range of {approx}1 dex, from [N/Fe] {approx} 0.7 to 1.7 dex. The strontium-to-iron abundance ratios varied from solar to mildly enhanced (0.0 {<=} [Sr/Fe] {<=} 0.8), with [Ba/Fe] generally equal to or greater than [Sr/Fe]. The carbon and nitrogen abundance ratios for the one known CH star in the sample, ROA 279, are [C/Fe] = 0.6 and [N/Fe] = 0.5 dex. Evidence for evolutionary mixing on the RGB is found from the fact that the relative carbon abundances on the main sequence are generally higher than those on the RGB. However, comparison of the RGB and main-sequence samples shows that the upper level of nitrogen enhancement is similar in both sets at [N/Fe] {approx} 2.0 dex. This is most likely the result of primordial rather than evolutionary mixing processes. One RGB star, ROA 276, was found to have Sr and Ba abundance ratios similar to the anomalous Sr-rich main-sequence star S2015448. High-resolution spectra of ROA 276 were obtained with the Magellan Telescope/MIKE spectrograph combination to confirm this result, revealing that ROA 276 is indeed an unusual star. For this star, calculations of the depletion effect, the potential change in surface abundance that results from the increased depth of the convective envelope as a star moves from the main sequence to the RGB, strongly suggest that the observed Sr enhancement in ROA 276 is of

  6. Seismic Velocity Structure and Depth-Dependence of Anisotropy in the Red Sea and Arabian Shield from Surface Wave Analysis

    SciTech Connect (OSTI)

    Hansen, S; Gaherty, J; Schwartz, S; Rodgers, A; Al-Amri, A

    2007-07-25

    We investigate the lithospheric and upper mantle structure as well as the depth-dependence of anisotropy along the Red Sea and beneath the Arabian Peninsula using receiver function constraints and phase velocities of surface waves traversing two transects of stations from the Saudi Arabian National Digital Seismic Network. Frequency-dependent phase delays of fundamental-mode Love and Rayleigh waves, measured using a cross-correlation procedure, require very slow shear velocities and the presence of anisotropy throughout the upper mantle. Linearized inversion of these data produce path-averaged 1D radially anisotropic models with about 4% anisotropy in the lithosphere, increasing to about 4.8% anisotropy across the lithosphere-asthenosphere boundary (LAB). Models with reasonable crustal velocities in which the mantle lithosphere is isotropic cannot satisfy the data. The lithospheric lid, which ranges in thickness from about 70 km near the Red Sea coast to about 90 km beneath the Arabian Shield, is underlain by a pronounced low-velocity zone with shear velocities as low as 4.1 km/s. Forward models, which are constructed from previously determined shear-wave splitting estimates, can reconcile surface and body wave observations of anisotropy. The low shear velocity values are similar to many other continental rift and oceanic ridge environments. These low velocities combined with the sharp velocity contrast across the LAB may indicate the presence of partial melt beneath Arabia. The anisotropic signature primarily reflects a combination of plate- and density-driven flow associated with active rifting processes in the Red Sea.

  7. Integration of Long-Term Research into a GIS Based Landscape Habitat Model for the Red-Cockaded Woodpecker

    SciTech Connect (OSTI)

    Franzreb, K.; Lloyd, F.T.

    2000-10-01

    The red cockaded woodpecker has been intensively studied since 1985 when the population was on the verge of extinction. The population decline is primarily the result of timber harvesting prior to 1950 and restricted burning. Construction of artificial cavities, translocations, competitor control, and removal of hardwood mid-story has provided suitable habitat. Since 1985, the population has increased from 4 to 99 birds. A GIS model is being developed to simulate the development of habitat at SRS in relation to management and existing vegetation.

  8. Low Power, Red, Green and Blue Carbon Nanotube Enabled Vertical Organic Light Emitting Transistors for Active Matrix OLED Displays

    SciTech Connect (OSTI)

    McCarthy, M. A. [University of Florida, Gainesville; Liu, B. [University of Florida, Gainesville; Donoghue, E. P. [University of Florida, Gainesville; Kravchenko, Ivan I [ORNL; Kim, D. Y. [University of Florida, Gainesville; So, Franky [University of Florida, Gainesville; Rinzler, A. G. [University of Florida, Gainesville

    2011-01-01

    Organic semiconductors are potential alternatives to polycrystalline silicon as the semiconductor used in the backplane of active matrix organic light emitting diode displays. Demonstrated here is a light-emitting transistor with an organic channel, operating with low power dissipation at low voltage, and high aperture ratio, in three colors: red, green and blue. The single-wall carbon nanotube network source electrode is responsible for the high level of performance demonstrated. A major benefit enabled by this architecture is the integration of the drive transistor, storage capacitor and light emitter into a single device. Performance comparable to commercialized polycrystalline-silicon TFT driven OLEDs is demonstrated.

  9. Cation Uptake and Allocation by Red Pine Seedlings under Cation-Nutrient Stress in a Column Growth Experiment

    SciTech Connect (OSTI)

    Shi, Zhenqing; Balogh-Brunstad, Zsuzsanna; Grant, Michael R.; Harsh, James B.; Gill, Richard; Thomashow, Linda; Dohnalkova, Alice; Stacks, Daryl; Letourneau, Melissa; Keller, Chester K.

    2014-01-10

    Background and Aims Plant nutrient uptake is affected by environmental stress, but how plants respond to cation-nutrient stress is poorly understood. We assessed the impact of varying degrees of cation-nutrient limitation on cation uptake in an experimental plant-mineral system. Methods Column experiments, with red pine (Pinus resinosa Ait.) seedlings growing in sand/mineral mixtures, were conducted for up to nine months under a range of Ca- and K-limited conditions. The Ca and K were supplied from both minerals and nutrient solutions with varying Ca and K concentrations. Results Cation nutrient stress had little impact on carbon allocation after nine months of plant growth and K was the limiting nutrient for biomass production. The Ca/Sr and K/Rb ratio results allowed independent estimation of dissolution incongruency and discrimination against Sr and Rb during cation uptake processes. The fraction of K in biomass from biotite increased with decreasing K supply from nutrient solutions. The mineral anorthite was consistently the major source of Ca, regardless of nutrient treatment. Conclusions Red pine seedlings exploited more mineral K in response to more severe K deficiency. This did not occur for Ca. Plant discrimination factors must be carefully considered to accurately identify nutrient sources using cation tracers.

  10. Qualification of the Lasentec M600P Particle Size Analyzer and the Red Valve Model 1151 Pressure Sensor

    SciTech Connect (OSTI)

    JR Bontha; NG Colton; EA Daymo; TD Hylton; CK Bayne; TH May

    2000-01-28

    The Lasentec M600 in-line particle size analyzer was installed at Oak Ridge National Laboratory (ORNL) in August 1998 to support retrieval of the Gunite and Associated Tanks (GAAT). Before installation at ORNL, the sensor underwent validation testing at the Pacific Northwest National Laboratory (PNNL) Instrument Validation facility. Mechanically, the instrument worked well during validation testing and met all expectations. Operationally, much was learned about optimum ways to display and interpret the data. Slurry samples taken during the in-line tests at PNNL were shipped to the vendor for analysis with a benchtop Lasentec sensor. These experiments were performed to determine if off-line analyses yield particle size distributions similar to those generated by the in-line sensor. It was determined that the Lasentec sensor measures repeatable chord lengths as long as particles are ''presenter'' to the sensor window the same way. After the initial non-radioactive simulant testing at PNNL, the instrument was shipped for radioactive validation and acceptance testing in the Slurry Monitoring Test System (SMTS) connected to the Tank W-9 of the GAATs at ORNL. For all acceptance tests conducted at ORNL, the variation in the chord length distribution and the total particle count corresponded very well with the slurry density data as determined using an in-line Promass 63M Coriolis meter. Based on the performance results obtained, the Lasentec M600P FBRM is expected to meet the requirements for measuring the particle size distribution during the slurry transfer operations at Hanford and the Oak Ridge GAAT remediation project. The Red Valve pressure sensor was endorsed at the Hanford Site following instrument validation tests at PNNL and is currently in operation in the Tank 241-C-106 pump pit. While this instrument measures pressure within a transfer line, this type of pressure sensor could be configured to measure pressure drop over time. In turn, the status of a slurry

  11. Monolithic integration of InGaN segments emitting in the blue, green, and red spectral range in single ordered nanocolumns

    SciTech Connect (OSTI)

    Albert, S.; Bengoechea-Encabo, A.; Sanchez-Garcia, M. A.; Calleja, E.

    2013-05-06

    This work reports on the selective area growth by plasma-assisted molecular beam epitaxy and characterization of InGaN/GaN nanocolumnar heterostructures. The optimization of the In/Ga and total III/V ratios, as well as the growth temperature, provides control on the emission wavelength, either in the blue, green, or red spectral range. An adequate structure tailoring and monolithic integration in a single nanocolumnar heterostructure of three InGaN portions emitting in the red-green-blue colors lead to white light emission.

  12. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy

    SciTech Connect (OSTI)

    Patel, Mogon; Bowditch, Martin; Jones, Ben; Netherton, David; Khan, Niaz; Letant, Sonia; Maxwell, Robert S.; Birdsell, Stephen A.

    2012-12-08

    Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75°C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively. We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.

  13. Coupling quantum dots to optical fiber: Low pump threshold laser in the red with a near top hat beam profile

    SciTech Connect (OSTI)

    Cheng, H.; Mironov, A. E.; Ni, J. H.; Yang, H. J.; Chen, W. W.; Dai, Z.; Park, S.-J.; Eden, J. G.; Dragic, P. D.; Dong, J.

    2015-02-23

    Direct coupling of the optical field in a ?244?nm thick, CdSe/ZnS quantum dot film to an optical fiber has yielded lasing in the red (? ? 644?nm) with a threshold pump energy density?

  14. Volatile out gassing characteristics of highly filled ethylene vinyl acetate binder materials: Gas phase infra-red spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Patel, Mogon; Bowditch, Martin; Jones, Ben; Netherton, David; Khan, Niaz; Letant, Sonia; Maxwell, Robert S.; Birdsell, Stephen A.

    2012-12-08

    Gas phase Infra-red (IR) spectroscopy has been used to investigate volatile out gassing properties of highly filled poly (ethylene-co-vinyl acetate) materials. In these studies, a Scout-ENTM heated gas cell was interfaced to a vacuum FTIR spectrometer, and the quantification of evolved species was achieved through calibration of the gas cell with certified gas standards. The volatile out gassing properties were monitored as a function of time during storage at 75°C under vacuum conditions (< 1mbar). Acetic acid, carbon dioxide and water were identified as the major out gassing products through IR absorption peaks at 1797, 2354 and 3853 cm-1, respectively.more » We present a comparison of three highly filled poly (ethyleneco- vinyl acetate) resins.« less

  15. Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Wang, Huamin; Rover, Majorie; Whitmer, Lysle; Smith, Ryan; Brown, Robert C.

    2015-04-13

    Phenolic oils were produced from fast pyrolysis of two different biomass feedstocks, red oak and corn stover and evaluated in hydroprocessing tests for production of liquid hydrocarbon products. The phenolic oils were produced with a bio-oil fractionating process in combination with a simple water wash of the heavy ends from the fractionating process. Phenolic oils derived from the pyrolysis of red oak and corn stover were recovered with yields (wet biomass basis) of 28.7 wt% and 14.9 wt%, respectively, and 54.3% and 58.6% on a carbon basis. Both precious metal catalysts and sulfided base metal catalyst were evaluated for hydrotreating the phenolic oils, as an extrapolation from whole bio-oil hydrotreatment. They were effective in removing heteroatoms with carbon yields as high as 81% (unadjusted for the 90% carbon balance). There was nearly complete heteroatom removal with residual O of only 0.4% to 5%, while N and S were reduced to less than 0.05%. Use of the precious metal catalysts resulted in more saturated products less completely hydrotreated compared to the sulfided base metal catalyst, which was operated at higher temperature. The liquid product was 42-52% gasoline range molecules and about 43% diesel range molecules. Particulate matter in the phenolic oils complicated operation of the reactors, causing plugging in the fixed-beds especially for the corn stover phenolic oil. This difficulty contrasts with the catalyst bed fouling and plugging, which is typically seen with hydrotreatment of whole bio-oil. This problem was substantially alleviated by filtering the phenolic oils before hydrotreating. More thorough washing of the phenolic oils during their preparation from the heavy ends of bio-oil or on-line filtration of pyrolysis vapors to remove particulate matter before condensation of the bio-oil fractions is recommended.

  16. Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Elliott, Douglas C.; Wang, Huamin; Rover, Majorie; Whitmer, Lysle; Smith, Ryan; Brown, Robert C.

    2015-04-13

    Phenolic oils were produced from fast pyrolysis of two different biomass feedstocks, red oak and corn stover and evaluated in hydroprocessing tests for production of liquid hydrocarbon products. The phenolic oils were produced with a bio-oil fractionating process in combination with a simple water wash of the heavy ends from the fractionating process. Phenolic oils derived from the pyrolysis of red oak and corn stover were recovered with yields (wet biomass basis) of 28.7 wt% and 14.9 wt%, respectively, and 54.3% and 58.6% on a carbon basis. Both precious metal catalysts and sulfided base metal catalyst were evaluated for hydrotreatingmore » the phenolic oils, as an extrapolation from whole bio-oil hydrotreatment. They were effective in removing heteroatoms with carbon yields as high as 81% (unadjusted for the 90% carbon balance). There was nearly complete heteroatom removal with residual O of only 0.4% to 5%, while N and S were reduced to less than 0.05%. Use of the precious metal catalysts resulted in more saturated products less completely hydrotreated compared to the sulfided base metal catalyst, which was operated at higher temperature. The liquid product was 42-52% gasoline range molecules and about 43% diesel range molecules. Particulate matter in the phenolic oils complicated operation of the reactors, causing plugging in the fixed-beds especially for the corn stover phenolic oil. This difficulty contrasts with the catalyst bed fouling and plugging, which is typically seen with hydrotreatment of whole bio-oil. This problem was substantially alleviated by filtering the phenolic oils before hydrotreating. More thorough washing of the phenolic oils during their preparation from the heavy ends of bio-oil or on-line filtration of pyrolysis vapors to remove particulate matter before condensation of the bio-oil fractions is recommended.« less

  17. ASSEMBLY OF THE RED SEQUENCE IN INFRARED-SELECTED GALAXY CLUSTERS FROM THE IRAC SHALLOW CLUSTER SURVEY

    SciTech Connect (OSTI)

    Snyder, Gregory F.; Brodwin, Mark; Mancone, Conor M.; Gonzalez, Anthony H.; Zeimann, Gregory R.; Stanford, S. A.; Stern, Daniel; Eisenhardt, Peter R. M.; Brown, Michael J. I.; Dey, Arjun; Jannuzi, Buell; Perlmutter, Saul

    2012-09-10

    We present results for the assembly and star formation histories (SFHs) of massive ({approx}L*) red sequence galaxies (RSGs) in 11 spectroscopically confirmed, infrared-selected galaxy clusters at 1.0 < z < 1.5, the precursors to present-day massive clusters with M {approx} 10{sup 15} M{sub Sun }. Using rest-frame optical photometry, we investigate evolution in the color and scatter of the RSG population, comparing with models of possible SFHs. In contrast to studies of central cluster galaxies at lower redshift (z < 1), these data are clearly inconsistent with the continued evolution of stars formed and assembled primarily at a single, much earlier time. Specifically, we find that the colors of massive cluster galaxies at z Almost-Equal-To 1.5 imply that the bulk of star formation occurred at z {approx} 3, whereas by z Almost-Equal-To 1 their colors imply formation at z {approx} 2; therefore these galaxies exhibit approximately the same luminosity-weighted stellar age at 1 < z < 1.5. This likely reflects star formation that occurs over an extended period, the effects of significant progenitor bias, or both. Our results generally indicate that massive cluster galaxy populations began forming a significant mass of stars at z {approx}> 4, contained some red spheroids by z Almost-Equal-To 1.5, and were actively assembling much of their final mass during 1 < z < 2 in the form of younger stars. Qualitatively, the slopes of the cluster color-magnitude relations are consistent with no significant evolution relative to local clusters.

  18. Highly lead-loaded red plastic scintillators as an X-ray imaging system for the Laser Mega Joule

    SciTech Connect (OSTI)

    Hamel, M.; Normand, S.; Turk, G.; Darbon, S.

    2011-07-01

    The scope of this project intends to record spatially resolved images of core shape and size of a DT micro-balloon during Inertial Confinement Fusion (ICF) experiments at Laser Mega Joule facility (LMJ). We need to develop an X-ray imaging system which can operate in the radiative background generated by an ignition shot of ICF. The scintillator is a part of the imaging system and has to gather a compromise of scintillating properties (scintillating efficiency, decay time, emission wavelength) so as to both operate in the hard radiative environment and to allow the acquisition of spatially resolved images. Inorganic scintillators cannot be used because no compromise can be found regarding the expected scintillating properties, most of them are not fast enough and emit blue light. Organic scintillators are generally fast, but present low X-ray absorption in the 10 to 40 keV range, that does not permit the acquisition of spatially resolved images. To this aim, we have developed highly lead-loaded and red-fluorescent fast plastic scintillators. Such a combination is not currently available via scintillator suppliers, since they propose only blue-fluorescent plastic scintillators doped with up to 12%w Pb. Thus, incorporation ratio up to 27%w Pb has been reached in our laboratory, which can afford a plastic scintillator with an outstanding Z{sub eff} close to 50. X-rays in the 10 to 40 keV range can thus be detected with a higher probability of photoelectric effect than for classic organic scintillators, such as NE102. The strong orange-red fluorescence can be filtered, so that we can eliminate residual Cerenkov light, generated by {gamma}-ray absorption in glass parts of the imaging system. Decay times of our scintillators evaluated under UV excitation were estimated to be in the range 10 to 13 ns. (authors)

  19. Reservoir characterization of the Ordovician Red River Formation in southwest Williston Basin Bowman County, ND and Harding County, SD

    SciTech Connect (OSTI)

    Sippel, M.A.; Luff, K.D.; Hendricks, M.L.; Eby, D.E.

    1998-07-01

    This topical report is a compilation of characterizations by different disciplines of the Red River Formation in the southwest portion of the Williston Basin and the oil reservoirs which it contains in an area which straddles the state line between North Dakota and South Dakota. Goals of the report are to increase understanding of the reservoir rocks, oil-in-place, heterogeneity, and methods for improved recovery. The report is divided by discipline into five major sections: (1) geology, (2) petrography-petrophysical, (3) engineering, (4) case studies and (5) geophysical. Interwoven in these sections are results from demonstration wells which were drilled or selected for special testing to evaluate important concepts for field development and enhanced recovery. The Red River study area has been successfully explored with two-dimensional (2D) seismic. Improved reservoir characterization utilizing 3-dimensional (3D) and has been investigated for identification of structural and stratigraphic reservoir compartments. These seismic characterization tools are integrated with geological and engineering studies. Targeted drilling from predictions using 3D seismic for porosity development were successful in developing significant reserves at close distances to old wells. Short-lateral and horizontal drilling technologies were tested for improved completion efficiency. Lateral completions should improve economics for both primary and secondary recovery where low permeability is a problem and higher density drilling is limited by drilling cost. Low water injectivity and widely spaced wells have restricted the application of waterflooding in the past. Water injection tests were performed in both a vertical and a horizontal well. Data from these tests were used to predict long-term injection and oil recovery.

  20. Structure of the red fluorescent protein from a lancelet (Branchiostoma lanceolatum): a novel GYG chromophore covalently bound to a nearby tyrosine

    SciTech Connect (OSTI)

    Pletnev, Vladimir Z. Pletneva, Nadya V.; Lukyanov, Konstantin A.; Souslova, Ekaterina A.; Fradkov, Arkady F.; Chudakov, Dmitry M.; Chepurnykh, Tatyana; Yampolsky, Ilia V.; Wlodawer, Alexander; Dauter, Zbigniew; Pletnev, Sergei

    2013-09-01

    The crystal structure of the novel red emitting fluorescent protein from lancelet Branchiostoma lanceolatum (Chordata) revealed an unusual five residues cyclic unit comprising Gly58-Tyr59-Gly60 chromophore, the following Phe61 and Tyr62 covalently bound to chromophore Tyr59. A key property of proteins of the green fluorescent protein (GFP) family is their ability to form a chromophore group by post-translational modifications of internal amino acids, e.g. Ser65-Tyr66-Gly67 in GFP from the jellyfish Aequorea victoria (Cnidaria). Numerous structural studies have demonstrated that the green GFP-like chromophore represents the ‘core’ structure, which can be extended in red-shifted proteins owing to modifications of the protein backbone at the first chromophore-forming position. Here, the three-dimensional structures of green laGFP (λ{sub ex}/λ{sub em} = 502/511 nm) and red laRFP (λ{sub ex}/λ{sub em} ≃ 521/592 nm), which are fluorescent proteins (FPs) from the lancelet Branchiostoma lanceolatum (Chordata), were determined together with the structure of a red variant laRFP-ΔS83 (deletion of Ser83) with improved folding. Lancelet FPs are evolutionarily distant and share only ∼20% sequence identity with cnidarian FPs, which have been extensively characterized and widely used as genetically encoded probes. The structure of red-emitting laRFP revealed three exceptional features that have not been observed in wild-type fluorescent proteins from Cnidaria reported to date: (i) an unusual chromophore-forming sequence Gly58-Tyr59-Gly60, (ii) the presence of Gln211 at the position of the conserved catalytic Glu (Glu222 in Aequorea GFP), which proved to be crucial for chromophore formation, and (iii) the absence of modifications typical of known red chromophores and the presence of an extremely unusual covalent bond between the Tyr59 C{sup β} atom and the hydroxyl of the proximal Tyr62. The impact of this covalent bond on the red emission and the large Stokes shift (

  1. Fine tunable red-green upconversion luminescence from glass ceramic containing 5%Er{sup 3+}:NaYF{sub 4} nanocrystals under excitation of two near infrared femtosecond lasers

    SciTech Connect (OSTI)

    Shang, Xiaoying; Cheng, Wenjing; Zhou, Kan; Ma, Jing; Feng, Donghai; Zhang, Shian; Sun, Zhenrong; Jia, Tianqing; Chen, Ping; Qiu, Jianrong

    2014-08-14

    In this paper, we report fine tunable red-green upconversion luminescence of glass ceramic containing 5%Er{sup 3+}: NaYF{sub 4} nanocrystals excited simultaneously by two near infrared femtosecond lasers. When the glass ceramic was irradiated by 800 nm femtosecond laser, weak red emission centered at 670 nm was detected. Bright red light was observed when the fs laser wavelength was tuned to 1490 nm. However, when excited by the two fs lasers simultaneously, the sample emitted bright green light centered at 550 nm, while the red light kept the same intensity. The dependences of the red and the green light intensities on the two pump lasers are much different, which enables us to manipulate the color emission by adjusting the two pump laser intensities, respectively. We present a theoretical model of Er{sup 3+} ions interacting with two fs laser fields, and explain well the experimental results.

  2. A BAYESIAN APPROACH TO LOCATING THE RED GIANT BRANCH TIP MAGNITUDE. II. DISTANCES TO THE SATELLITES OF M31

    SciTech Connect (OSTI)

    Conn, A. R.; Parker, Q. A.; Zucker, D. B.; Ibata, R. A.; Martin, N. F.; Lewis, G. F.; McConnachie, A. W.; Irwin, M. J.; Chapman, S. C.; Tanvir, N.; Fardal, M. A.; Ferguson, A. M. N.; Valls-Gabaud, D.

    2012-10-10

    In 'A Bayesian Approach to Locating the Red Giant Branch Tip Magnitude (Part I)', a new technique was introduced for obtaining distances using the tip of the red giant branch (TRGB) standard candle. Here we describe a useful complement to the technique with the potential to further reduce the uncertainty in our distance measurements by incorporating a matched-filter weighting scheme into the model likelihood calculations. In this scheme, stars are weighted according to their probability of being true object members. We then re-test our modified algorithm using random-realization artificial data to verify the validity of the generated posterior probability distributions (PPDs) and proceed to apply the algorithm to the satellite system of M31, culminating in a three-dimensional view of the system. Further to the distributions thus obtained, we apply a satellite-specific prior on the satellite distances to weight the resulting distance posterior distributions, based on the halo density profile. Thus in a single publication, using a single method, a comprehensive coverage of the distances to the companion galaxies of M31 is presented, encompassing the dwarf spheroidals Andromedas I-III, V, IX-XXVII, and XXX along with NGC 147, NGC 185, M33, and M31 itself. Of these, the distances to Andromedas XXIV-XXVII and Andromeda XXX have never before been derived using the TRGB. Object distances are determined from high-resolution tip magnitude posterior distributions generated using the Markov Chain Monte Carlo technique and associated sampling of these distributions to take into account uncertainties in foreground extinction and the absolute magnitude of the TRGB as well as photometric errors. The distance PPDs obtained for each object both with and without the aforementioned prior are made available to the reader in tabular form. The large object coverage takes advantage of the unprecedented size and photometric depth of the Pan-Andromeda Archaeological Survey. Finally, a

  3. " Row: Selected SIC Codes; Column: Energy Sources;"

    U.S. Energy Information Administration (EIA) Indexed Site

    S5.1. Selected Byproducts in Fuel Consumption, 1998;" " Level: National Data; " " Row: Selected SIC Codes; Column: Energy Sources;" " Unit: Trillion Btu." " "," "," "," "," "," "," "," ","Waste"," ",," " " "," "," ","Blast"," "," ","Pulping Liquor","

  4. Fluorescence analyzer for lignin

    DOE Patents [OSTI]

    Berthold, John W.; Malito, Michael L.; Jeffers, Larry

    1993-01-01

    A method and apparatus for measuring lignin concentration in a sample of wood pulp or black liquor comprises a light emitting arrangement for emitting an excitation light through optical fiber bundles into a probe which has an undiluted sensing end facing the sample. The excitation light causes the lignin concentration to produce fluorescent emission light which is then conveyed through the probe to analyzing equipment which measures the intensity of the emission light. Measures a This invention was made with Government support under Contract Number DOE: DE-FC05-90CE40905 awarded by the Department of Energy (DOE). The Government has certain rights in this invention.

  5. Chemical recovery process using break up steam control to prevent smelt explosions

    DOE Patents [OSTI]

    Kohl, Arthur L.; Stewart, Albert E.

    1988-08-02

    An improvement in a chemical recovery process in which a hot liquid smelt is introduced into a dissolving tank containing a pool of green liquor. The improvement comprises preventing smelt explosions in the dissolving tank by maintaining a first selected superatmospheric pressure in the tank during normal operation of the furnace; sensing the pressure in the tank; and further impinging a high velocity stream of steam upon the stream of smelt whenever the pressure in the tank decreases below a second selected superatmospheric pressure which is lower than said first pressure.

  6. URANIUM RECOVERY PROCESS

    DOE Patents [OSTI]

    Kaufman, D.

    1958-04-15

    A process of recovering uranium from very low-grade ore residues is described. These low-grade uraniumcontaining hydroxide precipitates, which also contain hydrated silica and iron and aluminum hydroxides, are subjected to multiple leachings with aqueous solutions of sodium carbonate at a pH of at least 9. This leaching serves to selectively extract the uranium from the precipitate, but to leave the greater part of the silica, iron, and aluminum with the residue. The uranium is then separated from the leach liquor by the addition of an acid in sufficient amount to destroy the carbonate followed by the addition of ammonia to precipitate uranium as ammonium diuranate.

  7. Extracting alcohols from aqueous solutions. [USDOE patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1981-12-02

    The objective is to provide an efficient process for extracting alcohols in aqueous solutions into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. This is done by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5-18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is then mixed with one or more of a group of polyoxyalkylene polymers to extract the alcohol into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  8. Proceedings of the DOE/Industry Sensor Working Group meeting, Austin, Texas

    SciTech Connect (OSTI)

    Not Available

    1988-11-01

    This paper report contains topics presented at a sensor workshop group meeting. The topics describe measuring instruments of use in the pulp and paper industry. Topics include: measurement of solids fraction; process instrumentation research for the pulp paper industry; real-time non-contact optical surface motion monitor; on-machine sensors to measure paper mechanical properties; hierarchical intelligent control of industrial processes -- an in-parallel lime kiln application; proposal for research on lignin concentration measurement in pulping liquors; and advanced polymeric sensor materials for industrial drying.

  9. Role of mag-enhanced lime scrubbing in the FGD industry

    SciTech Connect (OSTI)

    Babu, M.; College, J.; Smith, K.; Stowe, D.H.

    1997-12-31

    The mag-enhanced lime scrubbing process has been in commercial use in the US since the early 1970`s. At present over 14,000 MW of coal-fired utility plants in the US burning high sulfur coal (2.5--4.0% S) utilize this process with an excellent emission compliance and cost performance record to date. Dravo Lime Company (DLC) being the largest supplier of lime to this industry continues to conduct extensive R and D in this area and provides technical support service to these users. The success of the mag-enhanced lime process is largely attributed to the dual alkali effect of the Mg-Ca ions with a very distinct role for the highly soluble Mg ion in the scrubber liquor. It is well known that the high solubility of the magnesium ions provides alkalinities in the scrubbing liquor far in excess of the limestone systems. As a result of this high alkalinity liquor the mag-lime scrubbers need a much lower liquid to gas ratio, have lower scrubber pressure drop, consume lower parasitic load, are able to handle very high inlet SO{sub 2} concentrations, show little scaling tendency, etc. The scrubbers, recirculation pumps, piping, etc., are much smaller and the systems have lower capital and operating costs over comparable limestone systems. This system typically has a high availability and the process is less severe mechanically on the scrubber, pumps, nozzles, piping than comparable limestone processes. DLC`s patented ThioClear{reg_sign} process is an improvement over the conventional Thiosorbic process in use today. The ThioClear process while providing all of the advantages of the Thiosorbic process uses a nearly clear liquor to scrub and can use an innovative Horizontal Scrubber at gas velocities of up to 7.62--9.14 m/s (25--30 FPS). This process produces an excellent quality gypsum for wall board, cement or other applications and can also produce valuable Mg(OH){sub 2} as by-product. This paper discusses the merits of Thiosorbic/ThioClear processes, innovations with

  10. Method For Screening Microcrystallizations For Crystal Formation

    DOE Patents [OSTI]

    Santarsiero, Bernard D. , Stevens, Raymond C. , Schultz, Peter G. , Jaklevic, Joseph M. , Yegian, Derek T. , Cornell, Earl W. , Nordmeyer, Robert A.

    2003-10-07

    A method is provided for performing array microcrystallizations to determine suitable crystallization conditions for a molecule, the method comprising: forming an array of microcrystallizations, each microcrystallization comprising a drop comprising a mother liquor solution whose composition varies within the array and a molecule to be crystallized, the drop having a volume of less than 1 microliter; storing the array of microcrystallizations under conditions suitable for molecule crystals to form in the drops in the array; and detecting molecule crystal formation in the drops by taking images of the drops.

  11. A Methodology for Post Operational Clean Out of a Highly Active Facility Including Solids Behaviour - 12386

    SciTech Connect (OSTI)

    Edmondson, Michael J.; Ward, Tracy R.; Maxwell, Lisa J.

    2012-07-01

    The Highly Active Liquor Evaporation and Storage (HALES) plant at Sellafield handles acidic fission product containing liquor with typical activities of the order of 18x10{sup 9} Bq/ml. A strategy experimental feedback approach has been used to establish a wash regime for the Post Operational Clean Out (POCO) of the oldest storage tanks for this liquor. Two different wash reagents have been identified as being potentially suitable for removal of acid insoluble fission product precipitates. Ammonium carbamate and sodium carbonate yield similar products during the proposed wash cycle. The proposed wash reagents provide dissolution of caesium phosphomolybdate (CPM) and zirconium molybdate (ZM) solid phases but yields a fine, mobile precipitate of metal carbonates from the Highly Active Liquor (HAL) supernate. Addition of nitric acid to the wash effluent can cause CPM to precipitate where there is sufficient caesium and phosphorous available. Where they are not present (from ZM dissolution) the nitric acid addition initially produces a nitrate precipitate which then re-dissolves, along with the metal carbonates, to give a solid-free solution. The different behaviour of the two solids during the wash cycle has led to the proposal for an amended flowsheet. Additional studies on the potential to change the morphology of crystallising ZM have presented opportunities for changing the rheology of ZM sediments through doping with tellurium or particular organic acids. Two different wash reagents have been identified as being potentially suitable for the POCO of HALES Oldside HASTs. AC and SC both yield similar products during the proposed wash cycle. However, the different behaviour of the two principle HAL solids, CPM and ZM, during the wash cycle has led to the proposal for an amended flowsheet. Additional studies on the potential to change the morphology of crystallising ZM have presented opportunities for changing its rheology through doping with tellurium or certain

  12. Improved wastewater treatment at Wheeling-Pittsburgh Steel Corporations`s Steubenville East Coke Plant

    SciTech Connect (OSTI)

    Goshe, A.J.; Nodianos, M.J.

    1995-12-01

    Wheeling-Pittsburgh Steel Corporation recently improved its wastewater treatment at it`s by-products coke plant. This has led to greatly improved effluent quality. Excess ammonia liquor, along with wastewater from the light oil recovery plant, desulfurization facility, and coal pile runoff, must be treated prior to being discharged into the Ohio River. This is accomplished using a biological wastewater treatment plant to remove 99.99% of the organic contaminants and ammonia. Biologically treated, clarified wastewater is now polished in the newly constructed tertiary treatment plant.

  13. Method for removing heavy metal and nitrogen oxides from flue gas, device for removing heavy metal and nitrogen oxides from flue gas

    SciTech Connect (OSTI)

    Huang, Hann-Sheng; Livengood, Charles David

    1997-12-01

    A method for the simultaneous removal of oxides and heavy metals from a fluid is provided comprising combining the fluid with compounds containing alkali and sulfur to create a mixture; spray drying the mixture to create a vapor phase and a solid phase; and isolating the vapor phase from the solid phase. A device is also provided comprising a means for spray-drying flue gas with alkali-sulfide containing liquor at a temperature sufficient to cause the flue gas to react with the compounds so as to create a gaseous fraction and a solid fraction and a means for directing the gaseous fraction to a fabric filter.

  14. Improving a recombinant Zymomonas mobilis strain 8b through continuous adaptation on dilute acid pretreated corn stover hydrolysate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mohagheghi, Ali; Linger, Jeffrey G.; Yang, Shihui; Smith, Holly; Dowe, Nancy; Zhang, Min; Pienkos, Philip T.

    2015-03-31

    Complete conversion of the major sugars of biomass including both the C5 and C6 sugars is critical for biofuel production processes. Several inhibitory compounds like acetate, hydroxymethylfurfural (HMF), and furfural are produced from the biomass pretreatment process leading to ‘hydrolysate toxicity,’ a major problem for microorganisms to achieve complete sugar utilization. Therefore, development of more robust microorganisms to utilize the sugars released from biomass under toxic environment is critical. In this study, we use continuous culture methodologies to evolve and adapt the ethanologenic bacterium Zymomonas mobilis to improve its ethanol productivity using corn stover hydrolysate. The results are the following:more » A turbidostat was used to adapt the Z. mobilis strain 8b in the pretreated corn stover liquor. The adaptation was initiated using pure sugar (glucose and xylose) followed by feeding neutralized liquor at different dilution rates. Once the turbidostat reached 60% liquor content, the cells began washing out and the adaptation was stopped. Several ‘sub-strains’ were isolated, and one of them, SS3 (sub-strain 3), had 59% higher xylose utilization than the parent strain 8b when evaluated on 55% neutralized PCS (pretreated corn stover) liquor. Using saccharified PCS slurry generated by enzymatic hydrolysis from 25% solids loading, SS3 generated an ethanol yield of 75.5% compared to 64% for parent strain 8b. Furthermore, the total xylose utilization was 57.7% for SS3 versus 27.4% for strain 8b. To determine the underlying genotypes in these new sub-strains, we conducted genomic resequencing and identified numerous single-nucleotide mutations (SNPs) that had arisen in SS3. We further performed quantitative reverse transcription PCR (qRT-PCR) on genes potentially affected by these SNPs and identified significant down-regulation of two genes, ZMO0153 and ZMO0776, in SS3 suggesting potential genetic mechanisms behind SS3’s improved

  15. Improving a recombinant Zymomonas mobilis strain 8b through continuous adaptation on dilute acid pretreated corn stover hydrolysate

    SciTech Connect (OSTI)

    Mohagheghi, Ali; Linger, Jeffrey G.; Yang, Shihui; Smith, Holly; Dowe, Nancy; Zhang, Min; Pienkos, Philip T.

    2015-03-31

    Complete conversion of the major sugars of biomass including both the C5 and C6 sugars is critical for biofuel production processes. Several inhibitory compounds like acetate, hydroxymethylfurfural (HMF), and furfural are produced from the biomass pretreatment process leading to ‘hydrolysate toxicity,’ a major problem for microorganisms to achieve complete sugar utilization. Therefore, development of more robust microorganisms to utilize the sugars released from biomass under toxic environment is critical. In this study, we use continuous culture methodologies to evolve and adapt the ethanologenic bacterium Zymomonas mobilis to improve its ethanol productivity using corn stover hydrolysate. The results are the following: A turbidostat was used to adapt the Z. mobilis strain 8b in the pretreated corn stover liquor. The adaptation was initiated using pure sugar (glucose and xylose) followed by feeding neutralized liquor at different dilution rates. Once the turbidostat reached 60% liquor content, the cells began washing out and the adaptation was stopped. Several ‘sub-strains’ were isolated, and one of them, SS3 (sub-strain 3), had 59% higher xylose utilization than the parent strain 8b when evaluated on 55% neutralized PCS (pretreated corn stover) liquor. Using saccharified PCS slurry generated by enzymatic hydrolysis from 25% solids loading, SS3 generated an ethanol yield of 75.5% compared to 64% for parent strain 8b. Furthermore, the total xylose utilization was 57.7% for SS3 versus 27.4% for strain 8b. To determine the underlying genotypes in these new sub-strains, we conducted genomic resequencing and identified numerous single-nucleotide mutations (SNPs) that had arisen in SS3. We further performed quantitative reverse transcription PCR (qRT-PCR) on genes potentially affected by these SNPs and identified significant down-regulation of two genes, ZMO0153 and ZMO0776, in SS3 suggesting potential genetic mechanisms behind SS3

  16. Released: August 2009

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Relative Standard Errors for Table 3.5;" " Unit: Percents." ,,,,,,,,"Waste",," " ,,,"Blast",,,"Pulping Liquor",,"Oils/Tars" "NAICS",,,"Furnace/Coke",,"Petroleum","or","Wood Chips,","and Waste" "Code(a)","Subsector and Industry","Total","Oven Gases","Waste Gas","Coke","Black

  17. Released: March 2013

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Selected Byproducts in Fuel Consumption, 2010;" " Level: National and Regional Data; " " Row: NAICS Codes; Column: Energy Sources;" " Unit: Trillion Btu." " "," "," "," "," "," "," "," ","Waste" " "," "," ","Blast"," "," ","Pulping Liquor"," ","Oils/Tars" "NAICS","

  18. Forecasting changes in water quality in rivers associated with growing biofuels in the Arkansas-White-Red river drainage, USA

    SciTech Connect (OSTI)

    Jager, Henriette I.; Baskaran, Latha M.; Schweizer, Peter E.; Turhollow, Anthony F.; Brandt, Craig C.; Srinivasan, Raghavan

    2014-05-15

    We study that the mid-section of the Arkansas-White-Red (AWR) river basin near the 100th parallel is particularly promising for sustainable biomass production using cellulosic perennial crops and residues. Along this longitudinal band, precipitation becomes limiting to competing crops that require irrigation from an increasingly depleted groundwater aquifer. In addition, the deep-rooted perennial, switchgrass, produces modest-to-high yields in this region with minimal inputs and could compete against alternative crops and land uses at relatively low cost. Previous studies have also suggested that switchgrass and other perennial feedstocks offer environmentally benign alternatives to corn and corn stover. However, water quality implications remain a significant concern for conversion of marginal lands to bioenergy production because excess nutrients produced by agriculture for food or for energy contribute to eutrophication in the dead-zone in the Gulf of Mexico. This study addresses water quality implications for the AWR river basin. We used the SWAT model to compare water quality in rivers draining a baseline, pre-cellulosic-bioenergy and post-cellulosic-bioenergy landscapes for 2022 and 2030. Simulated water quality responses varied across the region, but with a net tendency toward decreased amounts of nutrient and sediment, particularly in subbasins with large areas of bioenergy crops in 2030 future scenarios. We conclude that water quality is one aspect of sustainability for which cellulosic bioenergy production in this region holds promise.

  19. THREE DISCRETE GROUPS WITH HOMOGENEOUS CHEMISTRY ALONG THE RED GIANT BRANCH IN THE GLOBULAR CLUSTER NGC2808

    SciTech Connect (OSTI)

    Carretta, E.

    2014-11-10

    We present the homogeneous reanalysis of Mg and Al abundances from high resolution UVES/FLAMES spectra for 31 red giants in the globular cluster NGC2808. We found a well defined Mg-Al anticorrelation reaching a regime of subsolar Mg abundance ratios, with a spread of about 1.4dex in [Al/Fe]. The main result from the improved statistics of our sample is that the distribution of stars is not continuous along the anticorrelation because they are neatly clustered into three distinct clumps, each with different chemical compositions. One group (P) shows a primordial composition of field stars of similar metallicity, and the other two (I and E) have increasing abundances of Al and decreasing abundances of Mg. The fraction of stars we found in the three components (P: 68%, I: 19%, E: 13%) is in excellent agreement with the ratios computed for the three distinct main sequences in NGC2808: for the first time there is a clear correspondence between discrete photometric sequences of dwarfs and distinct groups of giants with homogeneous chemistry. The composition of the I group cannot be reproduced by mixing of matter with extreme processing in hot H-burning and gas with pristine, unprocessed composition, as also found in the recent analysis of three discrete groups in NGC6752. This finding suggests that different classes of polluters were probably at work in NGC2808 as well.

  20. Disruption of a red giant star by a supermassive black hole and the case of PS1-10jh

    SciTech Connect (OSTI)

    Bogdanovi?, Tamara; Cheng, Roseanne M.; Amaro-Seoane, Pau E-mail: rcheng@gatech.edu

    2014-06-20

    The development of a new generation of theoretical models for tidal disruptions is timely, as increasingly diverse events are being captured in surveys of the transient sky. Recently, Gezari et al. reported a discovery of a new class of tidal disruption events: the disruption of a helium-rich stellar core, thought to be a remnant of a red giant (RG) star. Motivated by this discovery and in anticipation of others, we consider tidal interaction of an RG star with a supermassive black hole (SMBH) which leads to the stripping of the stellar envelope and subsequent inspiral of the compact core toward the black hole. Once the stellar envelope is removed the inspiral of the core is driven by tidal heating as well as the emission of gravitational radiation until the core either falls into the SMBH or is tidally disrupted. In the case of the tidal disruption candidate PS1-10jh, we find that there is a set of orbital solutions at high eccentricities in which the tidally stripped hydrogen envelope is accreted by the SMBH before the helium core is disrupted. This places the RG core in a portion of parameter space where strong tidal heating can lift the degeneracy of the compact remnant and disrupt it before it reaches the tidal radius. We consider how this sequence of events explains the puzzling absence of the hydrogen emission lines from the spectrum of PS1-10jh and gives rise to its other observational features.

  1. The effect of solvents on the stabilities (color and Fe) of anthocyanin isolated from the red-color-melinjo peels

    SciTech Connect (OSTI)

    Tarmizi, Ermiziar E-mail: ermitarmizi@gmail.com; Saragih, Raskita; Lalasari, Latifa Hanum E-mail: lati003@lipi.go.id

    2015-12-29

    Anthocyanin from the red-color-melinjo peels could be isolated using a polar solvent (ethanol) [ermiziar, 2010]. The amount of hydrocarbons in the structure of anthocyanin might cause that anthocyanin could be isolated using a non polar solvent. The purpose of research is to isolate anthocyanin using non polar solvents (hexane and petroleum ether) with maceration steps for 24 hours and separate solvents using rotary evaporator equipment. The stability of anthocyanin could be observed every week (1,2,3 and 4 weeks) in various environmental conditions (with or without light in refrigerator and open or closed storage). The characterization of anthocyanin was analyzed with visual (physic photo) and or using equipments such as Fourier Transform Infrared Spectroscopy (FTIR) for determining functional groups, Ultraviolet–Visible Spectroscopy (UV/Vis) with 500-550 nm wavelengths for deciding absorption of anthocyanin and atomic absorption spectroscopy (AAS) for analyzing Fe element. The result showed that anthocyanin isolation with hexane solvent has yield higher than petroleum eter solvent. From the results of physic observation for 4 weeks looked that there are changing colors of samples significant after 3 and 4 weeks in cooler with or without light. The stability of anthocyanin color was the best on the storage time until 2 weeks using hexane solvent in refrigerator and closed condition that it has absorption of 0.6740 with 500 nm wavelengths and Fe concentration 6.29 ppm.

  2. The vast population of Wolf-Rayet and red supergiant stars in M101. I. Motivation and first results

    SciTech Connect (OSTI)

    Shara, Michael M.; Bibby, Joanne L.; Zurek, David; Crowther, Paul A.; Moffat, Anthony F. J.; Drissen, Laurent

    2013-12-01

    Assembling a catalog of at least 10,000 Wolf-Rayet (W-R) stars is an essential step in proving (or disproving) that these stars are the progenitors of Type Ib and Type Ic supernovae. To this end, we have used the Hubble Space Telescope (HST) to carry out a deep, He II optical narrowband imaging survey of the ScI spiral galaxy M101. Almost the entire galaxy was imaged with the unprecedented depth and resolution that only the HST affords. Differenced with archival broadband images, the narrowband images allow us to detect much of the W-R star population of M101. We describe the extent of the survey and our images, as well as our data reduction procedures. A detailed broadband-narrowband imaging study of a field east of the center of M101, containing the giant star-forming region NGC 5462, demonstrates our completeness limits, how we find W-R candidates, their properties and spatial distribution, and how we rule out most contaminants. We use the broadband images to locate luminous red supergiant (RSG) candidates. The spatial distributions of the W-R and RSG stars near NGC 5462 are strikingly different. W-R stars dominate the complex core, while RSGs dominate the complex halo. Future papers in this series will describe and catalog more than a thousand W-R and RSG candidates that are detectable in our images, as well as spectra of many of those candidates.

  3. Recent seafloor metallogeneses: examples from the Atlantis II Deep, Red Sea and 21/sup 0/N East Pacific Rise

    SciTech Connect (OSTI)

    Zierenberg, R.A.

    1983-01-01

    Massive sulfide from 21/sup 0/N East Pacific Rise consists of pyrrhotite, cubic cubanite, wurtzite, chalcopyrite, pyrite, sphalerite, marcasite, and traces of galena. The samples show a complex paragenesis with extensive replacement and sulfur isotope disequilibrium. Sulfides in the Atlantis II Deep, Red Sea are very fine grained pyrrhotite, cubic cubanite, chalcopyrite, sphalerite, and pyrite which are interlayered with iron phyllosilicates. Epigenetic veins cutting unlithified metalliferous sediment in the Atlantis II are the conduits for the entry or new hot brine into the Deep. Vein mineralogy is dominated by talc and anhydrite with subordinate sulfides and phyllosilicates. Vertical zoning of vein minerals is related to cooling of hydrothermal fluid. Stable isotope ratios indicate depositional temperatures up to 300/sup 0/C. Stable isotope ratios also suggest that cooling of the hydrothermal fluid is caused by mixing with cooler brine having the approximate composition of the lower brine layer. Geochemical modeling of mixing successfully predicts the observed vertical zonation. The 21/sup 0/N East Pacific Rise deposit and the Atlantis II Deep have similar geochemical systems dominated by interaction with hot tholeiitic basalt. The differences in the deposits are related to their different depositional environments. The 21/sup 0/N East Pacific Rise deposit is forming directly on the seafloor in contact with cold oxygenated seawater, while the Atlantis II Deep deposit is forming beneath a warm, saline, anoxic brine pool.

  4. Small particle aerosol inoculation of cowpox Brighton Red in rhesus monkeys results in a severe respiratory disease

    SciTech Connect (OSTI)

    Johnson, Reed F.; Hammoud, Dima A.; Lackemeyer, Matthew G.; Yellayi, Srikanth; Solomon, Jeffrey; Bohannon, Jordan K.; Janosko, Krisztina B.; Jett, Catherine; Cooper, Kurt; Blaney, Joseph E.; Jahrling, Peter B.

    2015-07-15

    Cowpox virus (CPXV) inoculation of nonhuman primates (NHPs) has been suggested as an alternate model for smallpox (Kramski et al., 2010, PLoS One, 5, e10412). Previously, we have demonstrated that intrabronchial inoculation of CPXV-Brighton Red (CPXV-BR) into cynomolgus monkeys resulted in a disease that shared many similarities to smallpox; however, severe respiratory tract disease was observed (Smith et al., 2011, J. Gen. Virol.). Here we describe the course of disease after small particle aerosol exposure of rhesus monkeys using computed tomography (CT) to monitor respiratory disease progression. Subjects developed a severe respiratory disease that was uniformly lethal at 5.7 log{sub 10} PFU of CPXV-BR. CT indicated changes in lung architecture that correlated with changes in peripheral blood monocytes and peripheral oxygen saturation. While the small particle aerosol inoculation route does not accurately mimic human smallpox, the data suggest that CT can be used as a tool to monitor real-time disease progression for evaluation of animal models for human diseases. - Highlights: • Small particle aerosol exposure of rhesus results in a severe respiratory disease. • CT findings correlated with peripheral oxygen saturation and monocyte increases. • Virus dissemination was limited and mainly confined to the respiratory tract. • CT provides insight into pathogenesis to aid development of animal models of disease.

  5. Forecasting changes in water quality in rivers associated with growing biofuels in the Arkansas-White-Red river basin, USA

    SciTech Connect (OSTI)

    Jager, Yetta; Brandt, Craig C; Baskaran, Latha Malar; Srinivasan, Raghavan; Turhollow Jr, Anthony F; Schweizer, Peter E

    2015-01-01

    The mid-section of the Arkansas-White-Red (AWR) river basin near the 100th parallel is particularly promising for sustainable biomass production using cellulosic perennial crops and residues. Along this longitudinal band, precipitation becomes limiting to competing crops that require irrigation from an increasingly depleted groundwater aquifer. In addition, the deep-rooted perennial, switchgrass, produces modest-to-high yields in this region with minimal inputs and could compete against alternative crops and land uses at relatively low cost. Previous studies have also suggested that switchgrass and other perennial feedstocks offer environmentally benign alternatives to corn and corn stover. However, water quality implications remain a significant concern for conversion of marginal lands to bioenergy production because excess nutrients produced by agriculture for food or for energy contribute to eutrophication in the dead-zone in the Gulf of Mexico. This study addresses water quality implications for the AWR river basin. We used the SWAT model to compare water quality in rivers draining a baseline, pre-cellulosic-bioenergy and post-cellulosic-bioenergy landscapes for 2022 and 2030. Simulated water quality responses varied across the region, but with a net tendency toward decreased amounts of nutrient and sediment, particularly in subbasins with large areas of bioenergy crops in 2030 future scenarios. We conclude that water quality is one aspect of sustainability for which cellulosic bioenergy production in this region holds promise.

  6. Forecasting changes in water quality in rivers associated with growing biofuels in the Arkansas-White-Red river drainage, USA

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jager, Henriette I.; Baskaran, Latha M.; Schweizer, Peter E.; Turhollow, Anthony F.; Brandt, Craig C.; Srinivasan, Raghavan

    2014-05-15

    We study that the mid-section of the Arkansas-White-Red (AWR) river basin near the 100th parallel is particularly promising for sustainable biomass production using cellulosic perennial crops and residues. Along this longitudinal band, precipitation becomes limiting to competing crops that require irrigation from an increasingly depleted groundwater aquifer. In addition, the deep-rooted perennial, switchgrass, produces modest-to-high yields in this region with minimal inputs and could compete against alternative crops and land uses at relatively low cost. Previous studies have also suggested that switchgrass and other perennial feedstocks offer environmentally benign alternatives to corn and corn stover. However, water quality implications remainmore » a significant concern for conversion of marginal lands to bioenergy production because excess nutrients produced by agriculture for food or for energy contribute to eutrophication in the dead-zone in the Gulf of Mexico. This study addresses water quality implications for the AWR river basin. We used the SWAT model to compare water quality in rivers draining a baseline, pre-cellulosic-bioenergy and post-cellulosic-bioenergy landscapes for 2022 and 2030. Simulated water quality responses varied across the region, but with a net tendency toward decreased amounts of nutrient and sediment, particularly in subbasins with large areas of bioenergy crops in 2030 future scenarios. We conclude that water quality is one aspect of sustainability for which cellulosic bioenergy production in this region holds promise.« less

  7. Forecasting changes in water quality in rivers associated with growing biofuels in the Arkansas-White-Red river basin, USA

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jager, Yetta; Brandt, Craig C; Baskaran, Latha Malar; Srinivasan, Raghavan; Turhollow Jr, Anthony F; Schweizer, Peter E

    2015-01-01

    The mid-section of the Arkansas-White-Red (AWR) river basin near the 100th parallel is particularly promising for sustainable biomass production using cellulosic perennial crops and residues. Along this longitudinal band, precipitation becomes limiting to competing crops that require irrigation from an increasingly depleted groundwater aquifer. In addition, the deep-rooted perennial, switchgrass, produces modest-to-high yields in this region with minimal inputs and could compete against alternative crops and land uses at relatively low cost. Previous studies have also suggested that switchgrass and other perennial feedstocks offer environmentally benign alternatives to corn and corn stover. However, water quality implications remain a significant concernmore » for conversion of marginal lands to bioenergy production because excess nutrients produced by agriculture for food or for energy contribute to eutrophication in the dead-zone in the Gulf of Mexico. This study addresses water quality implications for the AWR river basin. We used the SWAT model to compare water quality in rivers draining a baseline, pre-cellulosic-bioenergy and post-cellulosic-bioenergy landscapes for 2022 and 2030. Simulated water quality responses varied across the region, but with a net tendency toward decreased amounts of nutrient and sediment, particularly in subbasins with large areas of bioenergy crops in 2030 future scenarios. We conclude that water quality is one aspect of sustainability for which cellulosic bioenergy production in this region holds promise.« less

  8. Evaluation of dual energy quantitative CT for determining the spatial distributions of red marrow and bone for dosimetry in internal emitter radiation therapy

    SciTech Connect (OSTI)

    Goodsitt, Mitchell M. Shenoy, Apeksha; Howard, David; Christodoulou, Emmanuel; Dewaraja, Yuni K.; Shen, Jincheng; Schipper, Matthew J.; Wilderman, Scott; Chun, Se Young

    2014-05-15

    Purpose: To evaluate a three-equation three-unknown dual-energy quantitative CT (DEQCT) technique for determining region specific variations in bone spongiosa composition for improved red marrow dose estimation in radionuclide therapy. Methods: The DEQCT method was applied to 80/140 kVp images of patient-simulating lumbar sectional body phantoms of three sizes (small, medium, and large). External calibration rods of bone, red marrow, and fat-simulating materials were placed beneath the body phantoms. Similar internal calibration inserts were placed at vertebral locations within the body phantoms. Six test inserts of known volume fractions of bone, fat, and red marrow were also scanned. External-to-internal calibration correction factors were derived. The effects of body phantom size, radiation dose, spongiosa region segmentation granularity [single (∼17 × 17 mm) region of interest (ROI), 2 × 2, and 3 × 3 segmentation of that single ROI], and calibration method on the accuracy of the calculated volume fractions of red marrow (cellularity) and trabecular bone were evaluated. Results: For standard low dose DEQCT x-ray technique factors and the internal calibration method, the RMS errors of the estimated volume fractions of red marrow of the test inserts were 1.2–1.3 times greater in the medium body than in the small body phantom and 1.3–1.5 times greater in the large body than in the small body phantom. RMS errors of the calculated volume fractions of red marrow within 2 × 2 segmented subregions of the ROIs were 1.6–1.9 times greater than for no segmentation, and RMS errors for 3 × 3 segmented subregions were 2.3–2.7 times greater than those for no segmentation. Increasing the dose by a factor of 2 reduced the RMS errors of all constituent volume fractions by an average factor of 1.40 ± 0.29 for all segmentation schemes and body phantom sizes; increasing the dose by a factor of 4 reduced those RMS errors by an average factor of 1.71 ± 0.25. Results

  9. USING CABLE SUSPENDED SUBMERSIBLE PUMPS TO REDUCE PRODUCTION COSTS TO INCREASE ULTIMATE RECOVERY IN THE RED MOUNTAIN FIELD IN SAM JUAN BASIN REGION

    SciTech Connect (OSTI)

    Don L. Hanosh

    2004-08-01

    A joint venture between Enerdyne LLC, a small independent oil and gas producer, and Pumping Solutions Inc., developer of a low volume electric submersible pump, suspended from a cable, both based in Albuquerque, New Mexico, has re-established marginal oil production from the Red Mountain Oil Field, located in the San Juan Basin, New Mexico by working over 17 existing wells and installing submersible pumps.

  10. Crystal structure and luminescence properties of a novel red-emitting phosphor BaAlBO{sub 3}F{sub 2}:Eu{sup 3+}

    SciTech Connect (OSTI)

    Chen, Wanping Zhou, Ahong; Liu, Yan; Dai, Xiaoyan; Yang, Xin

    2014-12-15

    A series of novel red-emitting phosphors BaAlBO{sub 3}F{sub 2}:xEu{sup 3+} (0.001≤x≤0.08) were first synthesized via a high temperature solid-state reaction. X-ray diffraction and photoluminescence spectroscopy were used to characterize the crystal structure and photoluminescence properties of the phosphor, respectively. The phosphor can be effectively excited with a 395 nm light, and shows a dominant {sup 5}D{sub 0}−{sup 7}F{sub 2} emission with chromatic coordination of 0.628 and 0.372. The optimal doping concentration is about 0.04. Rietveld refinement results and the luminescence behavior of Eu{sup 3+} indicate that the Eu{sup 3+} ion occupies a C{sub 3} symmetry site, and the host BaAlBO{sub 3}F{sub 2} has a hexagonal structure with P-6 space group. In addition, the phosphor could be a potential candidate as red-emitting phosphor for application in white light-emitting diode. - Graphical abstract: The luminescence behavior and Rietveld refinement of BaAlBO{sub 3}F{sub 2}:Eu{sup 3+} indicate that the red-emitting phosphor has potential application in white LED and the host has a hexagonal structure with P-6 space group. - Highlights: • A novel red-emitting phosphor BaAlBO{sub 3}F{sub 2}:Eu{sup 3+} is first synthesized. • The crystal structure of BaAlBO{sub 3}F{sub 2} is confirmed. • The phosphor shows potential application in white LED.

  11. Enhanced photoluminescence of SrWO{sub 4}:Eu{sup 3+} red phosphor synthesized by mechanochemically assisted solid state metathesis reaction method at room temperature

    SciTech Connect (OSTI)

    Peter, Anthuvan John Banu, I. B. Shameem

    2015-06-24

    Optically efficient europium activated alkaline earth metal tungstate nano phosphor (SrWO{sub 4}) with different doping concentrations have been synthesized by mechanochemically assisted solid state metathesis reaction at room temperature for the first time. The XRD and Raman spectra results indicated that the prepared powders exhibit a scheelite-type tetragonal structure. FTIR spectra exhibited a high absorption band situated at around 854 cm{sup −1}, which was ascribed to the W–O antisymmetric stretching vibrations into the [WO{sub 4}]{sup 2−} tetrahedron groups. Analysis of the emission spectra with different Eu{sup 3+} concentrations revealed that the optimum dopant concentration for SrWO{sub 4}: x Eu{sup 3+} phosphor is about 8 mol% of Eu{sup 3+}.The red emission intensity of the SSM prepared SrWO{sub 4}: 0.08Eu{sup 3+} phosphors are 2 times greater than that of the commercial Y{sub 2}O{sub 2}S: Eu{sup 3+} red phosphor prepared by the conventional solid state reaction method. All the results indicate that the phosphor is a promising red phosphor pumped by NUV InGaN chip for fabricating WLED.

  12. Nature of red luminescence band in research-grade ZnO single crystals: A “self-activated” configurational transition

    SciTech Connect (OSTI)

    Chen, Y. N.; Xu, S. J. Zheng, C. C.; Ning, J. Q.; Ling, F. C. C.; Anwand, W.; Brauer, G.; Skorupa, W.

    2014-07-28

    By implanting Zn{sup +} ions into research-grade intentionally undoped ZnO single crystal for facilitating Zn interstitials (Zn{sub i}) and O vacancies (V{sub O}) which is revealed by precise X-Ray diffraction rocking curves, we observe an apparent broad red luminescence band with a nearly perfect Gaussian lineshape. This red luminescence band has the zero phonon line at ∼2.4 eV and shows distinctive lattice temperature dependence which is well interpreted with the configurational coordinate model. It also shows a low “kick out” thermal energy and small thermal quenching energy. A “self-activated” optical transition between a shallow donor and the defect center of Zn{sub i}-V{sub O} complex or V{sub Zn}V{sub O} di-vacancies is proposed to be responsible for the red luminescence band. Accompanied with the optical transition, large lattice relaxation simultaneously occurs around the center, as indicated by the generation of multiphonons.

  13. Origin of fluids and the evolution of the Atlantis II deep hydrothermal system, Red Sea: Strontium isotope study

    SciTech Connect (OSTI)

    Anschutz, P.; Blanc, G.; Stille, P.

    1995-12-31

    Atlantis II is the largest and most mineralized of the deeps along the axis of the Red Sea spreading center. Its basaltic substratum is covered by recent layered metalliferous sediments, which precipitated from an overlying brine pool. The {sup 87}Sr/{sup 86}Sr ratio and the strontium concentration of interstitial waters within these sediments range between 0.70708 and 0.70725 and between 43 and 53 ppm, respectively. They are close to what is found for the present-day deep brine pool (0.707105, 45.10 ppm). The strontium concentration and the {sup 87}Sr/{sup 86}Sr ratio of the Atlantis II Deep brines can be derived from those of the interstitial waters of the surrounding Miocene evaporite by hydrothermal interaction with oceanic basaltic rocks at a maximal water/rock ratio 2-3. This water/rock ratio is similar to that calculated for oceanic hydrothermal systems on sediment-free ridges. Interstitial waters show a linear trend on plot of {sup 87}Sr/{sup 86}Sr vs. 1/Sr. The highest strontium concentration and the most radiogenic interstitial waters correspond to sediment samples enriched in iron and manganese oxide minerals. These waters reflect the diagenetic release of strontium by oxide minerals and initially precipitated at the interface between the brine pool and more radiogenic seawater. The solid fraction of the sediment has {sup 87}sr{sup 86}Sr isotopic compositions intermediate to those of the brines and seawater. The solid fraction of the sediment has {sup 87}Sr/{sup 86}Sr isotopic compositions intermediate to those of the brines and seawater. The most radiogenic strontium values were observed in samples strongly enriched in marine microbiota. The gradual isotopic evolution in the lowest part of the western basin sediments testifies to the gradual influence of the hydrothermal activity in the deep in the beginning of the Atlantis II Deep sedimentary history. 62 refs., 6 figs., 2 tabs.

  14. Calcium accumulated by sickle cell anemia red cells does not affect their potassium (86Rb+) flux components

    SciTech Connect (OSTI)

    Ortiz, O.E.; Lew, V.L.; Bookchin, R.M.

    1986-03-01

    We investigate here the hypothesis that the high Ca content of sickle cell anemia (SS) red cells may produce a sustained activation of the Ca2+-dependent K+ permeability (Gardos effect) and that the particularly high Ca levels in the dense SS cell fraction rich in irreversibly sickled cells (ISCs) might account for the Na pump inhibition observed in these cells. We measured active and passive 86Rb+ influx (as a marker for K+) in density-fractionated SS cells before and after extraction of their excess Ca by exposure to the Ca ionophore (A23187) and ethylene glycol tetra-acetic acid and with or without adenosine triphosphate depletion or addition of quinine. None of these maneuvers revealed any evidence of a Ca2+-dependent K leak in SS discocytes or dense cells. Na pump inhibition in the dense SS cells was associated with normal activation by external K+ and a low Vmax that persisted after Ca extraction from the cells. These results are consistent with our recent findings that the excess Ca in these cells is compartmentalized in intracellular inside-out vesicles and unavailable as free Ca2+ to the inner membrane surface. Although the steady-state free cytoplasmic Ca2+ in oxygenated SS cells must be below the levels needed to activate the K+ channel, possible brief activation of the channels of some SS cells resulting from transient elevations of cell Ca2+ during deoxygenation-induced sickling cannot be excluded. The dense, ISC-rich SS cell fraction showed a Ca2+-independent increase in the ouabain-resistant, nonsaturable component of 86Rb+ influx that, if uncompensated by Na+ gain, could contribute to the dehydration of these cells.

  15. Integrated Forest Products Refinery (IFPR)

    SciTech Connect (OSTI)

    van Heiningen, Adriaan R. P.

    2010-05-29

    about 1% (on pulp). By using the wet-end retention aid guar gum during the adsorption process at a charge of 0.5% on pulp the yield gain may be increased to about 5%. Unfortunately, most of this yield increase is lost during subsequent alkaline treatments in the pulp bleach plant. It was found that by performing the adsorption at alkaline conditions the adsorption loss during alkaline treatment in the bleach plant is mostly avoided. Thus a permanent adsorption yield of about 3 and 1.5% (on pulp) was obtained with addition of guar gum at a charge of 0.5 and 0.1% respectively during adsorption of GL hardwood extract on pre-extracted kraft pulp at optimal conditions of pH 11.5, 90 C for 60 minutes at 5% consistency. The beatability of the adsorbed kraft pulps was improved. Also, significant physical strength improvements were achieved. Further study is needed to determine whether the improvements in pulp yield and paper properties make this an economic IFPR concept. Application of the wood solids of a hot water extract of Acer rubrum wood strands as a substitute for polystyrene used for production of SMC maintained the water adsorption properties of the final product. Further work on the physical properties of the hemicellulose containing SMCs need to be completed to determine the potential of wood extracts for the production of partially renewable SMCs. The discovery of the “near-neutral” green liquor extraction process for hardwood was formed the basis for a commercial Integrated Biorefinery that will extract hemicelluloses from wood chips to make biofuels and other specialty chemicals. The pulp production process will be maintained as is proposed in the present researched IFBR concept. This Integrated Biorefinery will be constructed by Red Shield Acquisition LLC (RSA) at the Old Town kraft pulp mill in Maine. RSA in collaboration with the University of Maine will develop and commercialize the hemicellulose extraction process, the conversion of the hemicellulose

  16. Right Turn on Red!

    Broader source: Energy.gov [DOE]

    Read about a great example of how state and local governments can learn from each other – and how a very simple policy change can produce huge benefits for the country, helping us all save money by saving energy.

  17. The Tip of the red giant branch distance to the perfect spiral galaxy M74 hosting three core-collapse supernovae

    SciTech Connect (OSTI)

    Sung Jang, In; Gyoon Lee, Myung E-mail: mglee@astro.snu.ac.kr

    2014-09-01

    M74 (NGC 628) is a famous face-on spiral galaxy, hosting three core-collapse supernovae (SNe): SN Ic 2002ap, SN II-P 2003gd, and SN II-P 2013ej. However, its distance is not well known. We present a distance estimation for this galaxy based on the Tip of the Red Giant Branch (TRGB) method. We obtain photometry of the resolved stars in the arm-free region of M74 from F555W and F814W images in the Hubble Space Telescope archive. The color-magnitude diagram of the resolved stars shows a dominant red giant branch (RGB) as well as blue main sequence stars, red helium burning stars, and asymptotic giant branch stars. The I-band luminosity function of the RGB stars shows the TRGB to be at I {sub TRGB} = 26.13 ± 0.03 mag, and T {sub RGB} = 25.97 ± 0.03. From this, we derive the distance modulus to M74 to be 30.04 ± 0.04 (random) ± 0.12 (systematic) (corresponding to a linear distance of 10.19 ± 0.14 ± 0.56 Mpc). With this distance estimate, we calibrate the standardized candle method for SNe II-P. From the absolute magnitudes of SN 2003gd, we derive a value of the Hubble constant, H {sub 0} = 72 ± 6 (random) ± 7 (systematic) km s{sup –1} Mpc{sup –1}. It is similar to recent estimates based on the luminosity calibration of Type Ia supernovae.

  18. New asteroseismic scaling relations based on the Hayashi track relation applied to red giant branch stars in NGC 6791 and NGC 6819

    SciTech Connect (OSTI)

    Wu, T.; Li, Y.; Hekker, S. E-mail: ly@ynao.ac.cn

    2014-01-20

    Stellar mass M, radius R, and gravity g are important basic parameters in stellar physics. Accurate values for these parameters can be obtained from the gravitational interaction between stars in multiple systems or from asteroseismology. Stars in a cluster are thought to be formed coevally from the same interstellar cloud of gas and dust. The cluster members are therefore expected to have some properties in common. These common properties strengthen our ability to constrain stellar models and asteroseismically derived M, R, and g when tested against an ensemble of cluster stars. Here we derive new scaling relations based on a relation for stars on the Hayashi track (√(T{sub eff})∼g{sup p}R{sup q}) to determine the masses and metallicities of red giant branch stars in open clusters NGC 6791 and NGC 6819 from the global oscillation parameters Δν (the large frequency separation) and ν{sub max} (frequency of maximum oscillation power). The Δν and ν{sub max} values are derived from Kepler observations. From the analysis of these new relations we derive: (1) direct observational evidence that the masses of red giant branch stars in a cluster are the same within their uncertainties, (2) new methods to derive M and z of the cluster in a self-consistent way from Δν and ν{sub max}, with lower intrinsic uncertainties, and (3) the mass dependence in the Δν - ν{sub max} relation for red giant branch stars.

  19. NaLaF{sub 4}:Pr{sup 3+},Yb{sup 3+}, an efficient blue to near infra-red quantum cutter

    SciTech Connect (OSTI)

    Guille, A.; Pereira, A.; Moine, B.

    2013-12-01

    In order to reduce the thermalization losses in solar cells, down-conversion of blue photons into near infra-red photons is a promising solution. In the present paper, we analyse the energy transfer processes between Pr{sup 3+} and Yb{sup 3+} in NaLaF{sub 4} and we show that an efficient quantum-cutting process occurs. Nevertheless, we also show that a back transfer from Yb{sup 3+} toward the {sup 1}G{sub 4} level of Pr{sup 3+} ion leading to emission beyond 1??m reduces the potentiality of this material as a quantum cutter for Si solar cells.

  20. Structural basis for bathochromic shift of fluorescence in far-red fluorescent proteins eqFP650 and eqFP670

    SciTech Connect (OSTI)

    Pletnev, Sergei; Pletneva, Nadya V.; Souslova, Ekaterina A.; Wlodawer, Alexander; Dauter, Zbigniew; Pletnev, Vladimir

    2012-09-01

    The crystal structures of the far-red fluorescent proteins eqFP650 and eqFP670 have been solved at 1.8 and 1.6 Å resolution, respectively. This permitted identification of the structural elements responsible for the bathochromic shift in both considered far-red fluorescent proteins. The crystal structures of the far-red fluorescent proteins (FPs) eqFP650 (λ{sub ex}{sup max}/λ{sub em}{sup max} 592/650 nm) and eqFP670 (λ{sub ex}{sup max}/λ{sub em}{sup max} 605/670 nm), the successors of the far-red FP Katushka (λ{sub ex}{sup max}/λ{sub em}{sup max} 588/635 nm), have been determined at 1.8 and 1.6 Å resolution, respectively. An examination of the structures demonstrated that there are two groups of changes responsible for the bathochromic shift of excitation/emission bands of these proteins relative to their predecessor. The first group of changes resulted in an increase of hydrophilicity at the acylimine site of the chromophore due to the presence of one and three water molecules in eqFP650 and eqFP670, respectively. These water molecules provide connection of the chromophore with the protein scaffold via hydrogen bonds causing an ∼15 nm bathochromic shift of the eqFP650 and eqFP670 emission bands. The second group of changes observed in eqFP670 arises from substitution of both Ser143 and Ser158 by asparagines. Asn143 and Asn158 of eqFP670 are hydrogen bonded with each other, as well as with the protein scaffold and with the p-hydroxyphenyl group of the chromophore, resulting in an additional ∼20 nm bathochromic shift of the eqFP670 emission band as compared to eqFP650. The role of the observed structural changes was verified by mutagenesis.

  1. Evaluation of biological treatment of pharmaceutical wastewater with PAC (powdered activated carbon) addition. Volume 2. Appendices. Final report

    SciTech Connect (OSTI)

    Gardner, D.A.; Osantowski, R.A.

    1988-05-01

    A lack of information on applicable removal technologies for total chemical oxygen demand (TCOD) prevented promulgation of best available technology economically achievable (BAT) limitations and new source performance standards (NSPS) for TCOD for pharmaceutical manufacturing plants in 1983 (EPA/440/1-83/084). Therefore, in 1984 EPA conducted a pilot-plant study of activated-carbon-treatment technologies utilizing pharmaceutical waste waters from a manufacturing plant that produces fermentation products (Subcategory A) and chemical synthesis products (Subcategory C). The purposes of the study were to: (1) attempt to find the cause of the formation of the VFMLS; (2) generate additional research data for TCOD removal from pharmaceutical wastewater using the PACT process; (3) evaluate the efficiency of PACT in removing specific organics; (4) evaluate the effectiveness of PACT in reducing effluent aquatic toxicity; and, (5) evaluate the use of a selector to improve the settleability of the mixed liquor. One control unit, two PACT units and a unit equipped with a series of selector basins for improving the settling characteristics of the mixed-liquor suspended solids were operated.

  2. Tubeless evaporation process development: Final report

    SciTech Connect (OSTI)

    Not Available

    1987-12-01

    A tubeless evaporation process which has the potential to combine the advantage of both evaporation and freezing processes, without their disadvantages is being developed. The TEP is capable of concentrating process solutions of such things as sugar, caustic soda, salt, sodium sulfate, black liquor from the pulp and paper industry, cooling tower blowdown, ''spent'' pickling liquor (sulfuric acid) from the steel industry, and nitric acid with potential energy savings of half to three-quarters of the energy required by conventional evaporators, with about half of the capital and maintenance cost. It has similar potential for the production of fresh water from seawater. The process uses working fluids (WF's) at their freezing point to effect direct contact heat exchange. The purpose of this project was to find additional and lower cost WF's in the laboratory, to obtain sizing information for the major equipment for an economic evaluation and a pilot plant design in a bench scale plant, and to perform the economic evaluation, and the pilot plant design and cost estimate. 6 refs., 37 figs., 7 tabs.

  3. URANIUM EXTRACTION

    DOE Patents [OSTI]

    Harrington, C.D.; Opie, J.V.

    1958-07-01

    The recovery of uranium values from uranium ore such as pitchblende is described. The ore is first dissolved in nitric acid, and a water soluble nitrate is added as a salting out agent. The resulting feed solution is then contacted with diethyl ether, whereby the bulk of the uranyl nitrate and a portion of the impurities are taken up by the ether. This acid ether extract is then separated from the aqueous raffinate, and contacted with water causing back extractioa of the uranyl nitrate and impurities into the water to form a crude liquor. After separation from the ether extract, this crude liquor is heated to about 118 deg C to obtain molten uranyl nitrate hexahydratc. After being slightly cooled the uranyl nitrate hexahydrate is contacted with acid free diethyl ether whereby the bulk of the uranyl nitrate is dissolved into the ethcr to form a neutral ether solution while most of the impurities remain in the aqueous waste. After separation from the aqueous waste, the resultant ether solution is washed with about l0% of its volume of water to free it of any dissolved impurities and is then contacted with at least one half its volume of water whereby the uranyl nitrate is extracted into the water to form an aqueous product solution.

  4. Peat biogasification development program. Quarterly progress report No. 2, January 1-March 31, 1980

    SciTech Connect (OSTI)

    Wise, Donald L.; Buivid, Michael G.

    1980-01-01

    Batch experiments have been performed to determine the effects of different alkalis, temperatures, retention times, solids loading, and oxygen partial pressures on the solubility of peat organic material. Oxidation experiments have been performed simultaneously with and separately from solubilization. In both cases kinetic information has been developed based on oxygen consumption. Kinetics based on fermentable product formation are dependent on satisfactory identification methods. Development of analytical procedures for product identification have included: Gel Permeation Chromatography (GPC), solvent extraction, aldehyde precipitation, and Thin Layer Chromatography (TLC). Microorganisms from three inoculation sources are being grown anaerobically using a growth medium containing a standard nutrient and a specific substrate, one of twelve aromatic compounds. The concentration of aromatic compound was increased gradually in order that bacteria acclimate for future use as inocula with pretreated peat liquors. Acids and methane production are being monitored for pretreated peat liquor fermentations using an acclimated microorganism inocula. Apparent viscosity and apparent heat transfer coefficient data are being obtained at three peat slurry solids concentrations (3-5, 10, 15% total solids). A 75% heat recovery would give a positive energy balance around the pretreatment reactor. Development has continued in regards to full scale peat biogasification design (75 x 10/sup 6/ SCFD, pipeline quality methane). The information necessary for continuous PDU scale operation is being evaluated in terms of what processing information may be obtained from various scale units, batch and continuous.

  5. Three-dimensional spectrum mapping of bright emission centers: Investigating the brightness-limiting process in Eu-doped GaN red light emitting diodes

    SciTech Connect (OSTI)

    Ishii, Masashi; Koizumi, Atsushi; Fujiwara, Yasufumi

    2015-08-24

    A pulse-driven emission-spectroscopy mapping technique is used to investigate the bright emission centers in Eu-doped GaN (GaN:Eu) red light emitting diodes (LED). The LEDs are operated in pulse-driven mode, and the emission spectra are acquired for a range of pulse frequencies. This ensemble of emission spectral data yields a three-dimensional mapping that allows the origin of emission lines to be identified by visual inspection. The identification was achieved even for a weak {sup 5}D{sub 0} → {sup 7}F{sub 3} transition in conventional photoluminescence measurements. A peculiar split is observed in the {sup 5}D{sub 0} → {sup 7}F{sub 3} transition for the bright emission center referred to as OMVPE 8. Despite the unique transition at this emission center, the emission efficiencies for the {sup 5}D{sub 0} → {sup 7}F{sub 3} and {sup 5}D{sub 0} → {sup 7}F{sub 2} transitions were identical. This finding indicates that the excitation of the emission centers, rather than the radiative transitions, is the limiting process that determines the GaN:Eu red LED brightness.

  6. GALEX AND PAN-STARRS1 DISCOVERY OF SN IIP 2010aq: THE FIRST FEW DAYS AFTER SHOCK BREAKOUT IN A RED SUPERGIANT STAR

    SciTech Connect (OSTI)

    Gezari, S.; Huber, M. E.; Grav, T.; Rest, A.; Narayan, G.; Forster, K.; Neill, J. D.; Martin, D. C.; Valenti, S.; Smartt, S. J.; Chornock, R.; Berger, E.; Soderberg, A. M.; Mattila, S.; Kankare, E.; Burgett, W. S.; Chambers, K. C.; Dombeck, T.; Heasley, J. N.; Hodapp, K. W.

    2010-09-01

    We present the early UV and optical light curve of Type IIP supernova (SN) 2010aq at z = 0.0862, and compare it to analytical models for thermal emission following SN shock breakout in a red supergiant star. SN 2010aq was discovered in joint monitoring between the Galaxy Evolution Explorer (GALEX) Time Domain Survey (TDS) in the NUV and the Pan-STARRS1 Medium Deep Survey (PS1 MDS) in the g, r, i, and z bands. The GALEX and Pan-STARRS1 observations detect the SN less than 1 day after the shock breakout, measure a diluted blackbody temperature of 31, 000 {+-} 6000 K 1 day later, and follow the rise in the UV/optical light curve over the next 2 days caused by the expansion and cooling of the SN ejecta. The high signal-to-noise ratio of the simultaneous UV and optical photometry allows us to fit for a progenitor star radius of 700 {+-} 200R {sub sun}, the size of a red supergiant star. An excess in UV emission two weeks after shock breakout compared with SNe well fitted by model atmosphere-code synthetic spectra with solar metallicity is best explained by suppressed line blanketing due to a lower metallicity progenitor star in SN 2010aq. Continued monitoring of PS1 MDS fields by the GALEX TDS will increase the sample of early UV detections of Type II SNe by an order of magnitude and probe the diversity of SN progenitor star properties.

  7. SU-E-T-121: Dosimetric Characterization of Gafchromic Film EBT3 Using Vidar DosimetryPro Advantage RED and EPSON Expression 10000XL Scanners

    SciTech Connect (OSTI)

    Medina, L; Adrada, A; Filipuzzi, M; Garrigo, E; Venencia, C

    2014-06-01

    Purpose: The purpose of this paper is to characterize EBT3 using two types of scanner, analyzing the factors of influence of each dosimetry system. Methods: The film used in this study was GAFCHROMIC EBT3, the films were exposed at a dose range between 0Gy a 9Gy in a solid water phantom, SSD=100cm, 5cm depth and perpendicularly to the 6MV photon beam generated by a Novalis TX linear accelerator equipped with an HDMLC. A Farmer type ion chamber TN30013 (PTW) was used to determine the dose delivered to the film. The films were digitized with a scanner EPSON expression 10000XL and the VIDAR DosimetryPro Adventage RED. Software RIT113v6.1 was used for construction of the calibration curve and analysis. The film characteristics investigated were: response at different dose levels, sensitivity to orientation and side and resolution through the results of the spatial response function by analyzing a step pattern. Additionally, 20 IMRT treatment fields were measured with both scanner and compared with calculated dose using gamma index analysis (3%-3mm). Results: The OD obtained for dose level 2Gy in the orientation portrait of the film on the scanner EPSON is (0,222±0,19) and for Vidar RED (0,252±0,10) and landscape is for EPSON (0,211±0,25) and for Vidar RED (0,250±0,11) . The orientation dependence with respect to film side is about 0,09% for EPSON and about 0.03% for VIDAR. The spatial response function increase in response to the Gaussian function FWHM EPSON scanner (0.18mm) compared with VIDAR scanner function (less than 0.06mm) was observed. We analyzed 20 total plan dose distributions the number of pixels with gamma>1 (3%-3mm) was 0.7%±1.2 [0.1%; 2.82%] for EBT3-VIDAR y 2%±2.9 [0.2%; 3.5%] for EBT3-EPSON. Conclusion: VIDAR scanner shows better sensitivity. EBT3 film shows a different response between portrait and landscape orientation. Step pattern is better reproduce by VIDAR scanner.

  8. Photoluminescence properties of a new orange–red emitting Sm{sup 3+}-doped Y{sub 2}Mo{sub 4}O{sub 15} phosphor

    SciTech Connect (OSTI)

    Deng, Huajuan; Zhao, Ze; Wang, Jing; Hei, Zhoufei; Li, Mengxue; Noh, Hyeon Mi; Jeong, Jung Hyun; Yu, Ruijin

    2015-08-15

    A series of novel Y{sub 2}Mo{sub 4}O{sub 15}:xSm{sup 3+} ( (0.01 ≤ x ≤ 0.20) phosphors for white light-emitting (W-LEDs) were successfully prepared by the solid state reaction technology at 973 K for 12 h. X-ray diffraction and photoluminescence spectra were utilized to characterize the structure and luminescence properties of the as-synthesized phosphors. The emission spectra of the Y{sub 2}Mo{sub 4}O{sub 15}:Sm{sup 3+} phosphors consisted of some sharp emission peaks of Sm{sup 3+} ions centered at 565 nm, 605 nm, 650 nm, and 712 nm. The strongest one is located at 605 nm due to {sup 4}G{sub 5/2}–{sup 6}H{sub 7/2} transition of Sm{sup 3+}, generating bright orange–red light. The optimum dopant concentration of Sm{sup 3+} ions in Y{sub 2}Mo{sub 4}O{sub 15}:xSm{sup 3+} is around 5 mol% and the critical transfer distance of Sm{sup 3+} is calculated as 23.32 Å. The CIE chromaticity coordinates of the Y{sub 2}Mo{sub 4}O{sub 15}:0.05Sm{sup 3+} phosphors were located in the orange reddish region. The Y{sub 2}Mo{sub 4}O{sub 15}:Sm{sup 3+} phosphors may be potentially used as red phosphors for white light-emitting diodes. - Graphical abstract: The excitation spectrum of Y{sub 2}Mo{sub 4}O{sub 15}:Sm{sup 3+} is composed of a broad band and some sharp f–f transitions. Under 407 nm excitation, the phosphor presents some sharp emission peaks of Sm{sup 3+} ions. - Highlights: • An orange–red emitting Y{sub 2}Mo{sub 4}O{sub 15}:Sm{sup 3+} phosphor has been firstly synthesized. • Their structures, luminescent properties have also been investigated. • The optical absorption edge for the molybdate lies around 325 nm. • The CIE chromaticity coordinates were located in the orange reddish region.

  9. GALAXY-SCALE STAR FORMATION ON THE RED SEQUENCE: THE CONTINUED GROWTH OF S0s AND THE QUIESCENCE OF ELLIPTICALS

    SciTech Connect (OSTI)

    Salim, Samir; Fang, Jerome J.; Faber, S. M.; Thilker, David A.

    2012-08-20

    This paper examines star formation (SF) in relatively massive, primarily early-type galaxies (ETGs) at z {approx} 0.1. A sample is drawn from bulge-dominated Galaxy Evolution Explorer/Sloan Digital Sky Survey (GALEX/SDSS) galaxies on the optical red sequence with strong UV excess and yet quiescent SDSS spectra. High-resolution far-UV imaging of 27 such ETGs using Hubble Space Telescope Advanced Camera for Surveys/Solar Blind Channel (ACS/SBC) reveals structured UV morphology in 93% of the sample, consistent with low-level ongoing SF ({approx}0.5 M{sub Sun} yr{sup -1}). In 3/4 of the sample the SF is extended on galaxy scales (25-75 kpc), while the rest contains smaller (5-15 kpc) SF patches in the vicinity of an ETG-presumably gas-rich satellites being disrupted. Optical imaging reveals that all ETGs with galaxy-scale SF in our sample have old stellar disks (mostly S0 type). None is classified as a true elliptical. In our sample, galaxy-scale SF takes the form of UV rings of varying sizes and morphologies. For the majority of such objects we conclude that the gas needed to fuel current SF has been accreted from the intergalactic medium, probably in a prolonged, quasi-static manner, leading in some cases to additional disk buildup. The remaining ETGs with galaxy-scale SF have UV and optical morphologies consistent with minor merger-driven SF or with the final stages of SF in fading spirals. Our analysis excludes that all recent SF on the red sequence resulted from gas-rich mergers. We find further evidence that galaxy-scale SF is almost exclusively an S0 phenomenon ({approx}20% S0s have SF) by examining the overall optically red SDSS ETGs. Conclusion is that significant number of field S0s maintain or resume low-level SF because the preventive feedback is not in place or is intermittent. True ellipticals, on the other hand, stay entirely quiescent even in the field.

  10. Initial test results from the RedFlow 5 kW, 10 kWh zinc-bromide module, phase 1.

    SciTech Connect (OSTI)

    Ferreira, Summer Rhodes; Rose, David Martin

    2012-02-01

    In this paper the performance results of the RedFlow zinc-bromide module (ZBM) Gen 2.0 are reported for Phase 1 of testing, which includes initial characterization of the module. This included physical measurement, efficiency as a function of charge and discharge rates, efficiency as a function of maximum charge capacity, duration of maximum power supplied, and limited cycling with skipped strip cycles. The goal of this first phase of testing was to verify manufacturer specifications of the zinc-bromide flow battery. Initial characterization tests have shown that the ZBM meets the manufacturer's specifications. Further testing, including testing as a function of temperature and life cycle testing, will be carried out during Phase 2 of the testing, and these results will be issued in the final report, after Phase 2 testing has concluded.

  11. Green, red and infrared Er-related emission in implanted GaN:Er and GaN:Er,O samples

    SciTech Connect (OSTI)

    Monteiro, T.; Soares, J.; Correia, M. R.; Alves, E.

    2001-06-01

    Er-related luminescence near 1.54 {mu}m ({similar_to}805 meV) is observed under below band gap excitation at 4.2 K in GaN:Er and GaN:Er,O implanted samples. The spectrum of the recovered damage samples is a multiline structure. So far, these lines are the sharpest ones reported for GaN. Well-resolved green and red luminescences are observed in implanted samples. The dependence of luminescence on the excitation energy as well as the influence of different nominal fluence and annealing conditions is discussed. Combining the results obtained from photoluminescence and Rutherford backscattering spectrometry, different lattice sites for the optical active Er-related centers are identified. {copyright} 2001 American Institute of Physics.

  12. FOUR IRAC SOURCES WITH AN EXTREMELY RED H - [3.6] COLOR: PASSIVE OR DUSTY GALAXIES AT z > 4.5?

    SciTech Connect (OSTI)

    Huang, J.-S.; Fazio, G. G.; Zheng, X. Z.; Rigopoulou, D.; Magdis, G.; Wang, T.

    2011-11-20

    We report the detection of four IRAC sources in the GOODS-South field with an extremely red color of H - [3.6] > 4.5. The four sources are not detected in the deep Hubble Space Telescope WFC3 H-band image with H{sub limit} = 28.3 mag. We find that only three types of SED templates can produce such a red H - [3.6] color: a very dusty SED with the Calzetti extinction of A{sub V} = 16 mag at z = 0.8; a very dusty SED with the SMC extinction of A{sub V} = 8 mag at z = 2.0- 2.2; and an 1 Gyr SSP with A{sub V} {approx} 0.8 at z = 5.7. We argue that these sources are unlikely dusty galaxies at z {<=} 2.2 based on absent strong MIPS 24 {mu}m emission. The old stellar population model at z > 4.5 remains a possible solution for the 4 sources. At z > 4.5, these sources have stellar masses of log(M{sub *}/M{sub Sun }) = 10.6-11.2. One source, ERS-1, is also a type-II X-ray QSO with L{sub 2-8keV} = 1.6 Multiplication-Sign 10{sup 44} erg s{sup -1}. One of the four sources is an X-ray QSO and another one is a HyperLIRG, suggesting a galaxy-merging scenario for the formation of these massive galaxies at high redshifts.

  13. Expression of syndepositional tectonic uplift in Permian Goose Egg formation (Phosphoria equivalent) carbonates and red beds of Sheep Mountain anticline, Bighorn basin, Wyoming

    SciTech Connect (OSTI)

    Simmons, S.P.; Ulmer, D.S.; Scholle, P.A.

    1989-03-01

    Based on detailed field observations at Sheep Mountain, a doubly plunging anticline in the northeastern Bighorn basin in Wyoming, there appears to have been active tectonic uplift at this site contemporaneous with Pennsylvanian and Permian sedimentation. The Permian (Leonardian to Guadalupian) Goose Egg Formation at Sheep Mountain consists of 25-60 m of silty red beds (including minor carbonate and evaporite units) capped by 15-30 m of dominantly intertidal carbonates (the Ervay Member). A strong lateral variation of facies normal to the trend of the anticline is found within the red-bed sequence: carbonate beds on the anticline flanks are transitional with a gypsum/anhydrite facies along the crest. Similarly, shales on the anticline limbs grade into sandstones near the fold axis, indicating a paleohigh roughly coincidental with the present-day anticline crest. Ervay deposition (late Guadalupian) was marked by a more extensive uplifted structure in a marginal marine setting. On Sheep Mountain the unit is typified by intertidal fenestral carbonates, whereas outcrops to the east suggest a restricted marine facies and outcrops to the west reflect a more open marine environment. Thin sand lenses present in the Ervay are thought to represent terrigenous sediments blown onto the sometimes emergent bank which were then captured through adhesion and cementation. Anticlinal features similar to Sheep Mountain are common along the eastern margin of the Bighorn basin. When found in the subsurface, these structures are often associated with hydrocarbon production from the Ervay Member. Tectonic uplift contemporaneous with deposition of this unit may explain the localization of the productive fenestral facies on the present-day anticlines.

  14. A novel red phosphor Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} for near UV white light-emitting diodes

    SciTech Connect (OSTI)

    Yang, Zhigang; Zhao, Zhengyan; Shi, Yurong; Wang, Yuhua

    2013-10-15

    Graphical abstract: - Highlights: Novel red phosphor Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} was prepared by solid-state reaction. Excitation spectra suggested an obvious absorption in near-ultraviolet region. Under 392 nm excitation, the phosphors exhibited a red emission at 614 nm. Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} could be potentially applied in near UV white LEDs. - Abstract: A novel red phosphor Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} was synthesized using a solid-state reaction method, and its luminescence characteristics and charge compensators effect (Li{sup +}, Na{sup +}, K{sup +}) were investigated. The excitation spectra showed a obvious absorption in near-ultraviolet region. Under 392 nm excitation, the phosphors exhibited an intense red emission at 614 nm. The Commission Internationale de lEclairage (CIE) chromaticity coordinates and quantum efficiency (QE) were (0.65, 0.35) and 62.3%, respectively. The good color saturation, high quantum efficiency and small thermal-quenching properties indicate that Ca{sub 12}Al{sub 14}O{sub 32}Cl{sub 2}:Eu{sup 3+} could be potentially applied in near UV white light-emitting diodes.

  15. Synthesis and photoluminescence properties of Ca{sub 19}Mg{sub 2}(PO{sub 4}){sub 14}:Sm{sup 3+} red phosphor for white light emitting diodes

    SciTech Connect (OSTI)

    Zhu, Ge; Ci, Zhipeng; Shi, Yurong; Wang, Yuhua

    2014-07-01

    Highlights: • A novel red phosphor Ca{sub 19}Mg{sub 2}(PO{sub 4}){sub 14}:Sm{sup 3+} was synthesized and investigated firstly. • The structure and characteristic luminescence properties are discussed. • The excellent thermal stability was found and investigated. • It has good color saturation, the CIE is close to that of commercial Y{sub 2}O{sub 3}:Eu{sup 3+}. - Abstract: A series of Sm{sup 3+} doped Ca{sub 19}Mg{sub 2}(PO{sub 4}){sub 14} red phosphors were successfully synthesized. X-ray diffraction analysis indicates that all the samples are single phased. The luminescence property is investigated in detail by measuring their photoluminescence excitation and emission spectra. Ca{sub 19}Mg{sub 2}(PO{sub 4}){sub 14}:Sm{sup 3+} phosphors show strong absorption in 400–410 nm region, which is suitable for application in LEDs. When excited at 403 nm, Ca{sub 19}Mg{sub 2}(PO{sub 4}){sub 14}:Sm{sup 3+} phosphor can emit red emission with CIE chromaticity coordinates (0.615, 0.384). The optimal doping concentration of Sm{sup 3+} doped Ca{sub 19}Mg{sub 2}(PO{sub 4}){sub 14} is measured to be 0.02. The thermal quenching property is also measured and compared with the commercial red phosphor Y{sub 2}O{sub 3}:Eu{sup 3+} (Topstar, TXC-RIA). The results indicate Ca{sub 19}Mg{sub 2}(PO{sub 4}){sub 14}:Sm{sup 3+} phosphors have potential to serve as a red phosphor for white LEDs.

  16. The site occupation and valence of Mn ions in the crystal lattice of Sr{sub 4}Al{sub 14}O{sub 25} and its deep red emission for high color-rendering white light-emitting diodes

    SciTech Connect (OSTI)

    Chen, Lei; Xue, Shaochan; Chen, Xiuling; Bahader, Ali; Deng, Xiaorong; Zhao, Erlong; Jiang, Yang; Chen, Shifu; Chan, Ting-Shan; Zhao, Zhi; Zhang, Wenhua

    2014-12-15

    Highlights: • Different valences of Mn ions in Sr{sub 4}Al{sub 14}O{sub 25} were identified using XANES and EPR. • Red luminescence was attributed to Mn{sup 4+} occupying the center of AlO{sub 6} octahedron. • The Mn{sup 3+} incorporated in the center of AlO{sub 4} tetrahedron was non-luminescent. • The bond-valence theory was used to analyze the effective valences of cations. • A white LED device with CRI up to Ra 93.23 was packaged by using the red phosphor. - Abstract: The synthesis and component of red phosphor, Sr{sub 4}Al{sub 14}O{sub 25}: Mn, were optimized for application in white light-emitting diodes. The microstructure and morphology were investigated by the X-ray diffraction and scanning electron microscopy. Different valences of Mn ions in Sr{sub 4}Al{sub 14}O{sub 25} were discriminated using the electron paramagnetic resonance and X-ray absorption near-edge structure spectroscopy techniques. The bond-valence theory was used to analyze the effective valences of Sr{sup 2+} and Al{sup 3+} in Sr{sub 4}Al{sub 14}O{sub 25}. As a result, the strong covalence of Al{sup 3+} in the AlO{sub 4} tetrahedron other than in the AlO{sub 6} octahedron is disclosed. The deep red emission is attributed to Mn{sup 4+} occupying the center of AlO{sub 6} octahedron. The mechanism of energy transfer is mainly through dipole–dipole interaction, revealed by the analyses of critical distance and concentration quench. A high color rendering white LED prototype with color-rendering index up to Ra 93.23 packaged by using the red phosphor demonstrates its applicability.

  17. Calibration of EBT2 film using a red-channel PDD method in combination with a modified three-channel technique

    SciTech Connect (OSTI)

    Chang, Liyun; Ho, Sheng-Yow; Lee, Tsair-Fwu; Yeh, Shyh-An; Ding, Hueisch-Jy; Chen, Pang-Yu

    2015-10-15

    Purpose: Ashland Inc. EBT2 and EBT3 films are widely used in quality assurance for radiation therapy; however, there remains a relatively high degree of uncertainty [B. Hartmann, M. Martisikova, and O. Jakel, “Homogeneity of Gafchromic EBT2 film,” Med. Phys. 37, 1753–1756 (2010)]. Micke et al. (2011) recently improved the spatial homogeneity using all color channels of a flatbed scanner; however, van Hoof et al. (2012) pointed out that the corrected nonuniformity still requires further investigation for larger fields. To reduce the calibration errors and the uncertainty, the authors propose a new red-channel percentage-depth-dose method in combination with a modified three-channel technique. Methods: For the ease of comparison, the EBT2 film image used in the authors’ previous study (2012) was reanalyzed using different approaches. Photon beams of 6-MV were delivered to two different films at two different beam on times, resulting in the absorption doses of ranging from approximately 30 to 300 cGy at the vertical midline of the film, which was set to be coincident with the central axis of the beam. The film was tightly sandwiched in a 30{sup 3}-cm{sup 3} polystyrene phantom, and the pixel values for red, green, and blue channels were extracted from 234 points on the central axis of the beam and compared with the corresponding depth doses. The film was first calibrated using the multichannel method proposed by Micke et al. (2010), accounting for nonuniformities in the scanner. After eliminating the scanner and dose-independent nonuniformities, the film was recalibrated via the dose-dependent optical density of the red channel and fitted to a power function. This calibration was verified via comparisons of the dose profiles extracted from the films, where three were exposed to a 60° physical wedge field and three were exposed to composite fields, and all of which were measured in a water phantom. A correction for optical attenuation was implemented, and

  18. DISTANCE AND PROPER MOTION MEASUREMENT OF THE RED SUPERGIANT, PZ CAS, IN VERY LONG BASELINE INTERFEROMETRY H{sub 2}O MASER ASTROMETRY

    SciTech Connect (OSTI)

    Kusuno, K.; Asaki, Y. [Department of Space and Astronautical Science, School of Physical Sciences, Graduate University for Advanced Studies (SOKENDAI), 3-1-1 Yoshinodai, Chuou-Ku, Sagamihara, Kanagawa 252-5210 (Japan); Imai, H. [Department of Physics and Astronomy, Graduate School of Science and Engineering, Kagoshima University, 1-21-35 Korimoto, Kagoshima 890-0065 (Japan); Oyama, T., E-mail: kusuno@vsop.isas.jaxa.jp, E-mail: asaki@vsop.isas.jaxa.jp, E-mail: hiroimai@sci.kagoshima-u.ac.jp, E-mail: t.oyama@nao.ac.jp [Mizusawa VLBI Observatory, National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan)

    2013-09-10

    We present the very long baseline interferometry H{sub 2}O maser monitoring observations of the red supergiant, PZ Cas, at 12 epochs from 2006 April to 2008 May. We fitted maser motions to a simple model composed of a common annual parallax and linear motions of the individual masers. The maser motions with the parallax subtracted were well modeled by a combination of a common stellar proper motion and a radial expansion motion of the circumstellar envelope. We obtained an annual parallax of 0.356 {+-} 0.026 mas and a stellar proper motion of {mu}{sub {alpha}}{sup *} cos {delta} = -3.7 {+-} 0.2 and {mu}{sup *}{sub {delta}}=-2.0{+-}0.3 mas yr{sup -1} eastward and northward, respectively. The annual parallax corresponds to a trigonometric parallax of 2.81{sup +0.22}{sub -0.19} kpc. By rescaling the luminosity of PZ Cas in any previous studies using our trigonometric parallax, we estimated the location of PZ Cas on a Hertzsprung-Russell diagram and found that it approaches a theoretically evolutionary track around an initial mass of {approx}25 M{sub Sun }. The sky position and the distance to PZ Cas are consistent with the OB association, Cas OB5, which is located in a molecular gas super shell. The proper motion of PZ Cas is close to that of the OB stars and other red supergiants in Cas OB5 measured by the Hipparcos satellite. We derived the peculiar motion of PZ Cas of U{sub s} = 22.8 {+-} 1.5, V{sub s} = 7.1 {+-} 4.4, and W{sub s} = -5.7 {+-} 4.4 km s{sup -1}. This peculiar motion has rather a large U{sub s} component, unlike those of near high-mass star-forming regions with negatively large V{sub s} motions. The uniform proper motions of the Cas OB5 member stars suggest random motions of giant molecular clouds moving into local potential minima in a time-dependent spiral arm, rather than a velocity field caused by the spiral arm density wave.

  19. TWO DISTINCT RED GIANT BRANCH POPULATIONS IN THE GLOBULAR CLUSTER NGC 2419 AS TRACERS OF A MERGER EVENT IN THE MILKY WAY

    SciTech Connect (OSTI)

    Lee, Young-Wook; Han, Sang-Il; Joo, Seok-Joo; Jang, Sohee; Na, Chongsam; Lim, Dongwook; Kim, Hak-Sub; Yoon, Suk-Jin; Okamoto, Sakurako; Arimoto, Nobuo

    2013-11-20

    Recent spectroscopic observations of the outer halo globular cluster (GC) NGC 2419 show that it is unique among GCs, in terms of chemical abundance patterns, and some suggest that it was originated in the nucleus of a dwarf galaxy. Here we show, from the Subaru narrowband photometry employing a calcium filter, that the red giant branch (RGB) of this GC is split into two distinct subpopulations. Comparison with spectroscopy has confirmed that the redder RGB stars in the hk[=(Ca–b) – (b – y)] index are enhanced in [Ca/H] by ∼0.2 dex compared to the bluer RGB stars. Our population model further indicates that the calcium-rich second generation stars are also enhanced in helium abundance by a large amount (ΔY = 0.19). Our photometry, together with the results for other massive GCs (e.g., ω Cen, M22, and NGC 1851), suggests that the discrete distribution of RGB stars in the hk index might be a universal characteristic of this growing group of peculiar GCs. The planned narrowband calcium photometry for the Local Group dwarf galaxies would help to establish an empirical connection between these GCs and the primordial building blocks in the hierarchical merging paradigm of galaxy formation.

  20. Me-3,2-HOPO Complexes of Near Infra-Red (NIR) Emitting Lanthanides: Efficient Sensitization of Yb(III) and Nd(III) in Aqueous Solution

    SciTech Connect (OSTI)

    Moore, Evan G.; Xu, Jide; Dodani, Sheel; Jocher, Christoph; D'Aleo, Anthony; Seitz, Michael; Raymond, Kenneth

    2009-11-10

    The synthesis, X-ray structure, solution stability, and photophysical properties of several trivalent lanthanide complexes of Yb(III) and Nd(III) using both tetradentate and octadentate ligand design strategies and incorporating the 1-methyl-3-hydroxy-pyridin-2-one (Me-3,2-HOPO) chelate group are reported. Both the Yb(III) and Nd(III) complexes have emission bands in the Near Infra-Red (NIR) region, and this luminescence is retained in aqueous solution ({Phi}{sub tot}{sup Yb} {approx} 0.09-0.22%). Furthermore, the complexes demonstrate very high stability (pYb {approx} 18.8-21.9) in aqueous solution, making them good candidates for further development as probes for NIR imaging. Analysis of the low temperature (77 K) photophysical measurements for a model Gd(III) complex were used to gain an insight into the electronic structure, and were found to agree well with corresponding TD-DFT calculations at the B3LYP/6-311G{sup ++}(d,p) level of theory for a simplified model monovalent sodium complex.

  1. Investigation of surface-plasmon coupled red light emitting InGaN/GaN multi-quantum well with Ag nanostructures coated on GaN surface

    SciTech Connect (OSTI)

    Li, Yi; Liu, Bin E-mail: rzhang@nju.edu.cn; Zhang, Rong E-mail: rzhang@nju.edu.cn; Xie, Zili; Zhuang, Zhe; Dai, JiangPing; Tao, Tao; Zhi, Ting; Zhang, Guogang; Chen, Peng; Ren, Fangfang; Zhao, Hong; Zheng, Youdou

    2015-04-21

    Surface-plasmon (SP) coupled red light emitting InGaN/GaN multiple quantum well (MQW) structure is fabricated and investigated. The centre wavelength of 5-period InGaN/GaN MQW structure is about 620?nm. The intensity of photoluminescence (PL) for InGaN QW with naked Ag nano-structures (NS) is only slightly increased due to the oxidation of Ag NS as compared to that for the InGaN QW. However, InGaN QW with Ag NS/SiO{sub 2} structure can evidently enhance the emission efficiency due to the elimination of surface oxide layer of Ag NS. With increasing the laser excitation power, the PL intensity is enhanced by 25%53% as compared to that for the SiO{sub 2} coating InGaN QW. The steady-state electric field distribution obtained by the three-dimensional finite-difference time-domain method is different for both structures. The proportion of the field distributed in the Ag NS for the GaN/Ag NS/SiO{sub 2} structure is smaller as compared to that for the GaN/naked Ag NS structure. As a result, the energy loss of localized SP modes for the GaN/naked Ag NS structure will be larger due to the absorption of Ag layer.

  2. Nanoscale determinant to brighten up GaN:Eu red light-emitting diode: Local potential of Eu-defect complexes

    SciTech Connect (OSTI)

    Ishii, Masashi; Koizumi, Atsushi; Fujiwara, Yasufumi

    2015-04-21

    Emission sites in GaN:Eu red light-emitting diodes (LEDs) were investigated using a new spectroscopy technique, namely, site-selective pulse-driven emission spectroscopy (PDES). The PDES, in which the emission intensity of a pulse-driven LED is recorded with respect to the pulse frequency, revealed the charge-trapping dynamics of the Eu emission sites. We found that a determinant of the emission intensity of the sites was not their relative abundance, but rather the spatial extent of the local potential, which determines the effectiveness of the capture of injection charges. Minor sites with wider potentials enhanced the emission intensity of the LED, resulting in emission spectra that differ from those obtained using the photoluminescence of a GaN:Eu thin film. The potential curve is determined by the atomic structure of the complexes, which consist of a Eu dopant and nearby defects in the GaN host. The extent was characterized by a parameter, namely, cutoff frequency, and the emission sites with the wider and narrower potentials in the GaN:Eu LED were found to have cutoff frequencies of 400 kHz and 3 MHz, respectively. The cutoff frequency of 3 MHz was found to be the upper limit for emission sites in the LED. The emission site with the wider potential is useful for slower devices such as light fixtures, while the site with the narrower potential is useful for faster devices such as opto-isolators.

  3. Modeling the Sedimentation of Red Blood Cells in Flow under Strong External Magnetic Body Force using a Lattice Boltzmann Fictitious Domain Method

    SciTech Connect (OSTI)

    Shi, Xing; Lin, Guang

    2014-11-01

    To model the sedimentation of the red blood cell (RBC) in a square duct and a circular pipe, the recently developed technique derived from the lattice Boltzmann method and the distributed Lagrange multiplier/fictitious domain method (LBM-DLM/FD) is extended to employ the mesoscopic network model for simulations of the sedimentation of the RBC in flow. The flow is simulated by the lattice Boltzmann method with a strong magnetic body force, while the network model is used for modeling RBC deformation. The fluid-RBC interactions are enforced by the Lagrange multiplier. The sedimentation of the RBC in a square duct and a circular pipe is simulated, revealing the capacity of the current method for modeling the sedimentation of RBC in various flows. Numerical results illustrate that that the terminal setting velocity increases with the increment of the exerted body force. The deformation of the RBC has significant effect on the terminal setting velocity due to the change of the frontal area. The larger the exerted force is, the smaller the frontal area and the larger deformation of the RBC are.

  4. A near infra-red video system as a protective diagnostic for electron cyclotron resonance heating operation in the Wendelstein 7-X stellarator

    SciTech Connect (OSTI)

    Preynas, M.; Laqua, H. P.; Marsen, S.; Reintrog, A.; Corre, Y.; Moncada, V.; Travere, J.-M.

    2015-11-15

    The Wendelstein 7-X stellarator is a large nuclear fusion device based at Max-Planck-Institut für Plasmaphysik in Greifswald in Germany. The main plasma heating system for steady state operation in W7-X is electron cyclotron resonance heating (ECRH). During operation, part of plama facing components will be directly heated by the non-absorbed power of 1 MW rf beams of ECRH. In order to avoid damages of such components made of graphite tiles during the first operational phase, a near infra-red video system has been developed as a protective diagnostic for safe and secure ECRH operation. Both the mechanical design housing the camera and the optical system are very flexible and respect the requirements of steady state operation. The full system including data acquisition and control system has been successfully tested in the vacuum vessel, including on-line visualization and data storage of the four cameras equipping the ECRH equatorial launchers of W7-X.

  5. All-optical logic gate based on transient grating from disperse red 1 doped organic-inorganic hybrid films with an improved figure of merit

    SciTech Connect (OSTI)

    Gao, Tianxi; Que, Wenxiu Shao, Jinyou; Wang, Yushu

    2015-10-21

    Azobenzene dyes have large refractive index near their main resonance, but the poor figure of merit (FOM) limits their potential for all-optical applications. To improve this situation, disperse red 1 (DR1) molecules were dispersed in a sol-gel germanium/Ormosil organic-inorganic hybrid matrix. Z-scan measurement results showed a good compatibility between the dopant and the matrix, and also, an improved FOM was obtained as compared to the DR1/polymer films reported previously. To demonstrate the all-optical signal processing effect, a cw Nd:YAG laser emitting at 532 nm and a He-Ne laser emitting at 632.8 nm were used as pump and probe beams, respectively. DR1 acts as an initiator of the photo-induced transient holographic grating, which is attributed to the trans-cis-trans photoisomerization. Thus, a three inputs AND all-optical logic gate was achieved by using choppers with different frequencies. The detailed mechanism of operation is discussed. These results indicate that the DR1 doped germanium/Ormosil organic-inorganic hybrid film with an improved FOM has a great potential in all-optical devices around its main resonance.

  6. Direct transparent electrode patterning on layered GaN substrate by screen printing of indium tin oxide nanoparticle ink for Eu-doped GaN red light-emitting diode

    SciTech Connect (OSTI)

    Kashiwagi, Y. Yamamoto, M.; Saitoh, M.; Takahashi, M.; Ohno, T.; Nakamoto, M.; Koizumi, A.; Fujiwara, Y.; Takemura, Y.; Murahashi, K.; Ohtsuka, K.; Furuta, S.

    2014-12-01

    Transparent electrodes were formed on Eu-doped GaN-based red-light-emitting diode (GaN:Eu LED) substrates by the screen printing of indium tin oxide nanoparticle (ITO np) inks as a wet process. The ITO nps with a mean diameter of 25?nm were synthesized by the controlled thermolysis of a mixture of indium complexes and tin complexes. After the direct screen printing of ITO np inks on GaN:Eu LED substrates and sintering at 850?C for 10?min under atmospheric conditions, the resistivity of the ITO film was 5.2?m??cm. The fabricated LED up to 3?mm square surface emitted red light when the on-voltage was exceeded.

  7. Cobalt-iron red-ox behavior in nanostructured La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} cathodes

    SciTech Connect (OSTI)

    Soldati, Analia L.; Baque, Laura; Napolitano, Federico; Serquis, Adriana

    2013-02-15

    Nano-sized La{sub 0.4}Sr{sub 0.6}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} (LSCF) perovskite samples (prepared by a conventional acetate route and a novel acetate synthesis with HMTA additives), were tested simulating a red-ox cycle. The crystallography was studied by X-ray Powder Diffraction (XPD) and the changes in the oxidation state of the perovskite B-site were evaluated by synchrotron X-ray Absorption Near Edge Spectroscopy (XANES). After a reducing treatment, LSFC particles show the appearance of a new phase that coexists with the original one. The structural change is accompanied by a Co and Fe formal oxidation states decrease, although Fe remains always closer to 4+ and Co closer to 3+. The treatment produces a B-site valence average reduction from 3.52+ to 3.26+ and the formation of oxygen vacancies. A re-oxidation treatment under O{sub 2} rich atmosphere at 800 Degree-Sign C for 10 h shows that the change is reversible and independent of the two chemical methods used to synthesize the LSCF nano-particles. - Graphical abstract: XANES and XPD measurements in nanostructured LSCF before (black) and after (red/green) a red/ox cycle. Highlights: Black-Right-Pointing-Pointer Red-ox treatments in LSCF nano-particles cause a reversible reaction. Black-Right-Pointing-Pointer XPD analyses show that a new 'reduced' phase coexist with the oxidize one. Black-Right-Pointing-Pointer The B-site formal oxidation state decreases and the {delta} increases upon reduction. Black-Right-Pointing-Pointer Fe remains in a higher valence (closer to 4+) than Co (close to 3+). Black-Right-Pointing-Pointer The behavior seems to be independent of the synthesis method used.

  8. Relationship of coarse woody debris to arthropod Availability for Red-Cockaded Woodpeckers and other bark-foraging birds on loblolly pine boles.

    SciTech Connect (OSTI)

    Horn, Scott; Hanula, James, L.

    2008-04-01

    Abstract This study determined if short-term removal of coarse woody debris would reduce prey available to red-cockaded woodpeckers (Picoides borealis Vieillot) and other bark-foraging birds at the Savannah River Site in Aiken and Barnwell counties, SC. All coarse woody debris was removed from four 9-ha plots of mature loblolly pine (Pinus taeda L.) in 1997 and again in 1998. We sampled arthropods in coarse woody debris removal and control stands using crawl traps that captured arthropods crawling up tree boles, burlap bands wrapped around trees, and cardboard panels placed on the ground. We captured 27 orders and 172 families of arthropods in crawl traps whereas 20 arthropod orders were observed under burlap bands and cardboard panels. The most abundant insects collected from crawl traps were aphids (Homoptera: Aphididae) and ants (Hymenoptera: Forrnicidae). The greatest biomass was in the wood cockroaches (Blattaria: Blattellidae), caterpillars (Lepidoptera) in the Family Noctuidae, and adult weevils (Coleoptera: Curculionidae). The most common group observed underneath cardboard panels was lsoptera (termites), and the most common taxon under burlap bands was wood cockroaches. Overall, arthropod abundance and biomass captured in crawl traps was similar in control and removal plots. In contrast, we observed more arthropods under burlap bands (mean & SE; 3,021.5 k 348.6, P= 0.03) and cardboard panels (3,537.25 k 432.4, P= 0.04) in plots with coarse woody debris compared with burlap bands (2325 + 171.3) and cardboard panels (2439.75 + 288.9) in plots where coarse woody debris was removed. Regression analyses showed that abundance beneath cardboard panels was positively correlated with abundance beneath burlap bands demonstrating the link between abundance on the ground with that on trees. Our results demonstrate that short-term removal of coarse woody debris from pine forests reduced overall arthropod availability to bark-foraging birds.

  9. PdBI cold dust imaging of two extremely red H [4.5] > 4 galaxies discovered with SEDS and CANDELS

    SciTech Connect (OSTI)

    Caputi, K. I.; Popping, G.; Spaans, M.; Micha?owski, M. J.; Dunlop, J. S.; Krips, M.; Geach, J. E.; Ashby, M. L. N.; Huang, J.-S.; Fazio, G. G.; Koekemoer, A. M.; Castellano, M.; Fontana, A.; Santini, P.

    2014-06-20

    We report Plateau de Bure Interferometer (PdBI) 1.1 mm continuum imaging toward two extremely red H [4.5] > 4 (AB) galaxies at z > 3, which we have previously discovered making use of Spitzer SEDS and Hubble Space Telescope CANDELS ultra-deep images of the Ultra Deep Survey field. One of our objects is detected on the PdBI map with a 4.3? significance, corresponding to S{sub ?}(1.1 mm)=0.780.18 mJy. By combining this detection with the Spitzer 8 and 24 ?m photometry for this source, and SCUBA2 flux density upper limits, we infer that this galaxy is a composite active galactic nucleus/star-forming system. The infrared (IR)-derived star formation rate is SFR ? 200 100 M {sub ?} yr{sup 1}, which implies that this galaxy is a higher-redshift analogue of the ordinary ultra-luminous infrared galaxies more commonly found at z ? 2-3. In the field of the other target, we find a tentative 3.1? detection on the PdBI 1.1 mm map, but 3.7 arcsec away of our target position, so it likely corresponds to a different object. In spite of the lower significance, the PdBI detection is supported by a close SCUBA2 3.3? detection. No counterpart is found on either the deep SEDS or CANDELS maps, so, if real, the PdBI source could be similar in nature to the submillimeter source GN10. We conclude that the analysis of ultra-deep near- and mid-IR images offers an efficient, alternative route to discover new sites of powerful star formation activity at high redshifts.

  10. The Carina project. VII. Toward the breaking of the age-metallicity degeneracy of red giant branch stars using the C {sub U,} {sub B,} {sub I} index

    SciTech Connect (OSTI)

    Monelli, M.; Milone, A. P.; Gallart, C.; Aparicio, A. [Instituto de Astrofsica de Canarias, Calle Via Lactea s/n, E-38205 La Laguna, Tenerife (Spain); Fabrizio, M.; Cassisi, S.; Buonanno, R. [Istituto Nazionale di Astrofisica-Osservatorio Astronomico Collurania, Via M. Maggini, I-64100 Teramo (Italy); Bono, G. [Dipartimento di Fisica, Universit di Roma Tor Vergata, Via della Ricerca Scientifica 1, I-00133 Rome (Italy); Stetson, P. B. [Dominion Astrophysical Observatory, NRC-Herzberg, 5071 West Saanich Road, Victoria, BC, V9E 2E7 (Canada); Walker, A. R. [Cerro Tololo Inter-American Observatory, National Optical Astronomy Observatory, Casilla 603, La Serena (Chile); Nonino, M. [Istituto Nazionale di Astrofisica-Osservatorio Astronomico di Trieste, Via G. B. Tiepolo 11, I-40131 Trieste (Italy); Dall'Ora, M. [INAFOsservatorio Astronomico di Capodimonte, Salita Moiariello 16, I-80131 Napoli (Italy); Ferraro, I.; Iannicola, G.; Pulone, L. [Istituto Nazionale di Astrofisica-Osservatorio Astronomico di Roma, Via Frascati 33, Monte Porzio Catone, I-00044 Rome (Italy); Thvenin, F., E-mail: monelli@iac.es [Universit de Nice Sophia-antipolis, CNRS, Observatoire de la Cte d'Azur, Laboratoire Lagrange, BP 4229, F-06304 Nice (France)

    2014-12-01

    We present an analysis of photometric and spectroscopic data of the Carina dSph galaxy, testing a new approach similar to that used to disentangle multiple populations in Galactic globular clusters (GCs). We show that a proper color combination is able to separate a significant fraction of the red giant branch (RGB) of the two main Carina populations (the old one, ?12 Gyr, and the intermediate-age one, 4-8 Gyr). In particular, the c {sub U,} {sub B,} {sub I} = (U B) (B I) pseudo-color allows us to follow the RGB of both populations along a relevant portion of the RGB. We find that the oldest stars have a more negative c {sub U,} {sub B,} {sub I} pseudo-color than intermediate-age ones. We correlate the pseudo-color of RGB stars with their chemical properties, finding a significant trend between the iron content and the c {sub U,} {sub B,} {sub I}. Stars belonging to the old population are systematically more metal-poor ([Fe/H] =2.32 0.08 dex) than the intermediate-age ones ([Fe/H] =1.82 0.03 dex). This gives solid evidence of the chemical evolution history of this galaxy, and we have a new diagnostic that can allow us to break the age-metallicity degeneracy of H-burning advanced evolutionary phases. We compared the distribution of stars in the c {sub U,} {sub B,} {sub I} plane with theoretical isochrones, finding that no satisfactory agreement can be reached with models developed in a theoretical framework based on standard heavy element distributions. Finally, we discuss possible systematic differences when compared with multiple populations in GCs.

  11. THE PROPERTIES OF THE 500 K DWARF UGPS J072227.51-054031.2 AND A STUDY OF THE FAR-RED FLUX OF COLD BROWN DWARFS

    SciTech Connect (OSTI)

    Leggett, S. K.; Saumon, D.; Marley, M. S.; Lodders, K.; Fegley, B.; Canty, J.; Lucas, P.; Burningham, Ben; Jones, H. R. A.; Marocco, F.; Pinfield, D. J.; Smart, R. L.; Homeier, D.; Allard, F.; Day-Jones, A.; Ishii, Miki; Tamura, M.

    2012-04-01

    We present i and z photometry for 25 T dwarfs and 1 L dwarf. Combined with published photometry, the data show that the i - z, z - Y, and z - J colors of T dwarfs are very red, and continue to increase through to the late-type T dwarfs, with a hint of a saturation for the latest types with T{sub eff} Almost-Equal-To 600 K. We present new 0.7-1.0 {mu}m and 2.8-4.2 {mu}m spectra for the very late type T dwarf UGPS J072227.51-054031.2, as well as improved astrometry for this dwarf. Examination of the spectral energy distribution using new and published data, with Saumon and Marley models, shows that the dwarf has T{sub eff} = 505 {+-} 10 K, a mass of 3-11 M{sub Jupiter}, and an age between 60 Myr and 1 Gyr. This young age is consistent with the thin disk kinematics of the dwarf. The mass range overlaps with that usually considered to be planetary, despite this being an unbound object discovered in the field near the Sun. This apparently young rapid rotator is also undergoing vigorous atmospheric mixing, as determined by the IRAC and WISE 4.5 {mu}m photometry and the Saumon and Marley models. The optical spectrum for this 500 K object shows clearly detected lines of the neutral alkalis Cs and Rb, which are emitted from deep atmospheric layers with temperatures of 900-1200 K.

  12. The identification of extreme asymptotic giant branch stars and red supergiants in M33 with 24 μm variability

    SciTech Connect (OSTI)

    Montiel, Edward J.; Clayton, Geoffrey C.; Johnson, Christopher B.; Srinivasan, Sundar; Engelbracht, Charles W.

    2015-02-01

    We present the first detection of 24 μm variability in 24 sources in the Local Group galaxy M33. These results are based on 4 epochs of Multiband Imaging Photometer for Spitzer observations, which are irregularly spaced over ∼750 days. We find that these sources are constrained exclusively to the Holmberg radius of the galaxy, which increases their chances of being members of M33. We have constructed spectral energy distributions (SEDs) ranging from the optical to the submillimeter to investigate the nature of these objects. We find that 23 of our objects are most likely heavily self-obscured, evolved stars, while the remaining source is the Giant H ii region, NGC 604. We believe that the observed variability is the intrinsic variability of the central star reprocessed through their circumstellar dust shells. Radiative transfer modeling was carried out to determine their likely chemical composition, luminosity, and dust production rate (DPR). As a sample, our modeling has determined an average luminosity of (3.8±0.9)×10{sup 4} L{sub ⊙} and a total DPR of (2.3±0.1)×10{sup −5} M{sub ⊙} yr{sup −1}. Most of the sources, given the high DPRs and short wavelength obscuration, are likely extreme asymptotic giant branch (XAGB) stars. Five of the sources are found to have luminosities above the classical AGB limit (M{sub bol} <−7.1 mag, L > 54,000 L{sub ⊙}), which classifies them as probable red supergiants (RSGs). Almost all of the sources are classified as oxygen-rich. As also seen in the LMC, a significant fraction of the dust in M33 is produced by a handful of XAGB and RSG stars.

  13. Proliferation Vulnerability Red Team report

    SciTech Connect (OSTI)

    Hinton, J.P.; Barnard, R.W.; Bennett, D.E.

    1996-10-01

    This report is the product of a four-month independent technical assessment of potential proliferation vulnerabilities associated with the plutonium disposition alternatives currently under review by DOE/MD. The scope of this MD-chartered/Sandia-led study was limited to technical considerations that could reduce proliferation resistance during various stages of the disposition processes below the Stored Weapon/Spent Fuel standards. Both overt and covert threats from host nation and unauthorized parties were considered. The results of this study will be integrated with complementary work by others into an overall Nonproliferation and Arms Control Assessment in support of a Secretarial Record of Decision later this year for disposition of surplus U.S. weapons plutonium.

  14. "RSE Table N5.2. Relative Standard Errors for Table N5.2;"

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Relative Standard Errors for Table N5.2;" " Unit: Percents." ,,"S e l e c t e d","W o o d","a n d","W o o d -","R e l a t e d","P r o d u c t s" ,,,,,"B i o m a s s" ,,,,,,"Wood Residues" ,,,,,,"and","Wood-Related" " "," ","Pulping Liquor"," "," ","Wood","Byproducts","and",," "

  15. Method for producing hydrocarbon and alcohol mixtures. [Patent application

    DOE Patents [OSTI]

    Compere, A.L.; Googin, J.M.; Griffith, W.L.

    1980-12-01

    It is an object of this invention to provide an efficient process for extracting alcohols and ketones from an aqueous solution containing the same into hydrocarbon fuel mixtures, such as gasoline, diesel fuel and fuel oil. Another object of the invention is to provide a mixture consisting of hydrocarbon, alcohols or ketones, polyoxyalkylene polymer and water which can be directly added to fuels or further purified. The above stated objects are achieved in accordance with a preferred embodiment of the invention by contacting an aqueous fermentation liquor with a hydrocarbon or hydrocarbon mixture containing carbon compounds having 5 to 18 carbon atoms, which may include gasoline, diesel fuel or fuel oil. The hydrocarbon-aqueous alcohol solution is mixed in the presence or one or more of a group of polyoxyalkylene polymers described in detail hereinafter; the fermentation alcohol being extracted into the hydrocarbon fuel-polyoxyalkylene polymer mixture.

  16. Guides to pollution prevention: The pharmaceutical industry. Final report

    SciTech Connect (OSTI)

    Not Available

    1991-10-01

    Pharmaceutical manufacturers generate a variety of wastes during manufacturing, maintenance, and housekeeping operations which can be reduced or minimized through source reduction and recycling. The typical waste streams are spent fermentation broths, process liquors, solvents, equipment wash water, spilled materials, off-spec products, and used processing aids. Suggestions include improvements to operational practices, solvent recycling and implementing good materials management and housekeeping practices. To help companies in the industry identify opportunities for waste reduction at their own facilities, the guide includes a set of worksheets which take the user step-by-step through an analysis of the on-site waste generating operations and the possibilities for minimizing each waste. The guide and its worksheets would also be instructive to consultants serving the pharmaceutical manufacturing industry and government agencies who regulate waste streams generated from these firms.

  17. Use of solvent extraction technique in Brazilian uranium mills - an overview

    SciTech Connect (OSTI)

    Gomiero, Luiz A.

    2008-07-01

    Solvent extraction has been applied to uranium-concentrate production in Brazil. At the first plant, uranium minerals associated with Zr and Mo were acid leached. Extraction was carried out by a mixture of Alamine 336 and Alamine 304, followed by selective Zr, U, and Mo stripping. At the currently operating facilities, a single U mineral is processed by acid heap leaching. Uranium is extracted with Alamine 336 and stripped with NaCl solution. As all water is recycled, chloride contents in the liquor have increased, causing detrimental effects to the extraction process. The current plant operating conditions and the improvements arisen from the research developed to solve these problems are presented. (authors)

  18. Superheater Corrosion Produced By Biomass Fuels

    SciTech Connect (OSTI)

    Sharp, William; Singbeil, Douglas; Keiser, James R

    2012-01-01

    About 90% of the world's bioenergy is produced by burning renewable biomass fuels. Low-cost biomass fuels such as agricultural wastes typically contain more alkali metals and chlorine than conventional fuels. Although the efficiency of a boiler's steam cycle can be increased by raising its maximum steam temperature, alkali metals and chlorine released in biofuel boilers cause accelerated corrosion and fouling at high superheater steam temperatures. Most alloys that resist high temperature corrosion protect themselves with a surface layer of Cr{sub 2}O{sub 3}. However, this Cr{sub 2}O{sub 3} can be fluxed away by reactions that form alkali chromates or volatilized as chromic acid. This paper reviews recent research on superheater corrosion mechanisms and superheater alloy performance in biomass boilers firing black liquor, biomass fuels, blends of biomass with fossil fuels and municipal waste.

  19. Sumas, WA LNG Imports from Canada

    Gasoline and Diesel Fuel Update (EIA)

    Alabama Alabama total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 5,043 15.6 37,941 24.9 Coal 11,441 35.3 63,050 41.4 Hydro and Pumped Storage 3,272 10.1 8,704 5.7 Natural Gas 11,936 36.8 39,235 25.8 Other 1 100 0.3 643 0.4 Other Renewable 1 583 1.8 2,377 1.6 Petroleum 43 0.1 200 0.1 Total 32,417 100.0 152,151 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture

  20. URANIUM RECOVERY PROCESS

    DOE Patents [OSTI]

    Stevenson, J.W.; Werkema, R.G.

    1959-07-28

    The recovery of uranium from magnesium fluoride slag obtained as a by- product in the production of uranium metal by the bomb reduction prccess is presented. Generally the recovery is accomplished by finely grinding the slag, roasting ihe ground slag air, and leaching the roasted slag with a hot, aqueous solution containing an excess of the sodium bicarbonate stoichiometrically required to form soluble uranium carbonate complex. The roasting is preferably carried out at between 425 and 485 deg C for about three hours. The leaching is preferably done at 70 to 90 deg C and under pressure. After leaching and filtration the uranium may be recovered from the clear leach liquor by any desired method.

  1. Improved Recovery Boiler Performance Through Control of Combustion, Sulfur, and Alkali Chemistry

    SciTech Connect (OSTI)

    Baxter, Larry L.

    2008-06-09

    This project involved the following objectives: 1. Determine black liquor drying and devolatilization elemental and total mass release rates and yields. 2. Develop a public domain physical/chemical kinetic model of black liquor drop combustion, including new information on drying and devolatilization. 3. Determine mechanisms and rates of sulfur scavenging in recover boilers. 4. Develop non-ideal, public-domain thermochemistry models for alkali salts appropriate for recovery boilers 5. Develop data and a one-dimensional model of a char bed in a recovery boiler. 6. Implement all of the above in comprehensive combustion code and validate effects on boiler performance. 7. Perform gasification modeling in support of INEL and commercial customers. The major accomplishments of this project corresponding to these objectives are as follows: 1. Original data for black liquor and biomass data demonstrate dependencies of particle reactions on particle size, liquor type, gas temperature, and gas composition. A comprehensive particle submodel and corresponding data developed during this project predicts particle drying (including both free and chemisorbed moisture), devolatilization, heterogeneous char oxidation, char-smelt reactions, and smelt oxidation. Data and model predictions agree, without adjustment of parameters, within their respective errors. The work performed under these tasks substantially exceeded the original objectives. 2. A separate model for sulfur scavenging and fume formation in a recovery boiler demonstrated strong dependence on both in-boiler mixing and chemistry. In particular, accurate fume particle size predictions, as determined from both laboratory and field measurements, depend on gas mixing effects in the boilers that lead to substantial particle agglomeration. Sulfur scavenging was quantitatively predicted while particle size required one empirical mixing factor to match data. 3. Condensed-phase thermochemistry algorithms were developed for salt

  2. Clean Air Act Title IV: Lessons learned from Phase I; getting ready for Phase II

    SciTech Connect (OSTI)

    Miller, M.J.

    1997-12-31

    The 1990 Clean Air Act Amendments have required significant reductions in SO{sub 2} and NO{sub x} emissions from fossil fuel-fired power plants in the US. This paper examines some of the key technical lessons learned in Phase I following retrofit of low NO{sub x} systems, FGD systems, and continuous emissions monitors. Some of the key problems encountered have been waterwall wastage as a result of low NO{sub x} burner retrofits; high LOI (carbon) ash as a result of low NO{sub x} operation; high O&M costs associated with CEMs; and the heat rate discrepancy which has arisen between CEMs and conventional heat rate calculations. As Phase II approaches, EPRI and the electric utility industry are investigating improvements in FGD systems (e.g., clear liquor scrubbing), advances in NO{sub x} control technologies, more robust CEM systems, and tools to help in the technology decision-making process.

  3. Method for recovering and using lignin in adhesive resins by extracting demethylated lignin

    DOE Patents [OSTI]

    Schroeder, Herbert A.

    1991-01-01

    Lignin, or a lignin derived material, which has been significantly demethylated (e.g., the demethylated lignin found in the raffinate produced as a by-product of dimethyl sulfide production which can be carried out using the spent liquor from wood pulping operations) can be isolated by a process wherein an organic solvent is added to a lignin-containing aqueous solution. The organic solvent is typically a polar, and at least a partially water-immiscible substance such as, for example, ethyl acetate. The resulting lignin-containing aqueous solution/organic solvent mixture is acidified to produce a water layer which is discarded and an organic solvent layer which contains the demethylated lignin. Upon its recovery, the demethylated lignin is dissolved in an alkaline solution to which an aldehyde source is added to produce a resol-type resin. The aldehyde source may be formaldehyde in solution, paraformaldehyde, hexamethylenetetramine, or other aldehydes including acetaldehyde, furfural, and their derivatives.

  4. Method for recovering and using lignin in adhesive resins

    DOE Patents [OSTI]

    Schroeder, Herbert A.

    1993-01-01

    Lignin, or a lignin derived material, which has been significantly demethylated (e.g., the demethylated lignin found in the raffinate produced as a by-product of dimethyl sulfide production which can be carried out using the spent liquor from wood pulping operations) can be isolated by a process wherein an organic solvent is added to a lignin-containing aqueous solution. The organic solvent is typically a polar, and at least a partially water-immiscible substance such as, for example, ethyl acetate. The resulting lignin-containing aqueous solution/organic solvent mixture is acidified to produce a water layer which is discarded and an organic solvent layer which contains the demethylated lignin. Upon its recovery, the demethylated lignin is dissolved in an alkaline solution to which an aldehyde source is added to produce a resol-type resin. The aldehyde source may be formaldehyde in solution, paraformaldehyde, hexamethylenetetramine, or other aldehydes including acetaldehyde, furfural, and their derivatives.

  5. Wastewater treatment with biomass carriers made from steelmaking by-product

    SciTech Connect (OSTI)

    Aritome, Kiyoshi; Miki, Osamu; Okuno, Yoshio

    1995-07-01

    It is economical to use microorganisms in wastewater treatment. In steelmaking, ammonia liquor from coke-oven plant, for example, is treated using microorganisms. To treat wastewater efficiently in biological processes, the following conditions are necessary: appropriate conditions for activities of microorganisms; proper concentration of microorganisms in reactor; effective contact of wastewater and microorganisms; and reliable separation of treated wastewater and microorganisms. Three types of biomass carriers made from granulated slag to satisfy these conditions have been developed. Research efforts have been under way to apply these carriers in reduction of COD (chemical oxygen demand) in wastewater. Developed biomass carriers can reduce the volume of COD oxidation reactor and promise easy operation compared with the conventional activated sludge processes. This result has been substantialized in sewage treatment facilities, factory wastewater treatment facilities and deodorization facilities. For the future, nitrate reduction in stainless pickling wastewater with fixed-bed biomass carriers will be also investigated.

  6. Method for recovering and using lignin in adhesive resins by extracting demethylated lignin

    DOE Patents [OSTI]

    Schroeder, Herbert A.

    1991-01-01

    Lignin, or a lignin derived material, which has been significantly demethylated (e.g., the demethylated lignin found in the raffinate produced as a by-product of dimethyl sulfide production which can be carried out using the spent liquor from wood pulping operations) can be isolated by a process wherein an organic solvent is added to a lignin-containing aqueous solution. The organic solvent is typically a polar, and at least a partially water-immiscible substance such as, for example, ethyl acetate. The resulting lignin-containing aqueous solution/organic solvent mixture is acidified to produce a water layer which is discarded and an organic solvent layer which contains the demethylated lignin. Upon its recovery, the demethylated lignin is preferably dried and stored until it is used (along with an alkali, an aldehyde and an adhesive filler) in compounding an adhesive of the type generally used in the manufacture of plywood.

  7. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    Alabama Alabama total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 5,043 15.6 37,941 24.9 Coal 11,441 35.3 63,050 41.4 Hydro and Pumped Storage 3,272 10.1 8,704 5.7 Natural Gas 11,936 36.8 39,235 25.8 Other 1 100 0.3 643 0.4 Other Renewable 1 583 1.8 2,377 1.6 Petroleum 43 0.1 200 0.1 Total 32,417 100.0 152,151 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture

  8. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    Arizona Arizona Total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 3,937 14.9 31,200 27.9 Coal 6,233 23.6 43,644 39.1 Hydro and Pumped Storage 2,937 11.1 6,831 6.1 Natural Gas 13,012 49.3 29,676 26.6 Other 1 - - 15 * Other Renewable 1 181 0.7 319 0.3 Petroleum 93 0.4 66 0.1 Total 26,392 100.0 111,751 100.0 * = Absolute percentage less than 0.05. - = No data reported. Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid

  9. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    Arkansas Arkansas total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 1,835 11.5 15,023 24.6 Coal 4,535 28.4 28,152 46.2 Hydro and Pumped Storage 1,369 8.6 3,658 6.0 Natural Gas 7,894 49.4 12,469 20.4 Other 1 - - 28 * Other Renewable 1 326 2.0 1,624 2.7 Petroleum 22 0.1 45 0.1 Total 15,981 100.0 61,000 100.0 * = Absolute percentage less than 0.05. - = No data reported. Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid

  10. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    7 California California total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 4,390 6.5 32,201 15.8 Coal 374 0.6 2,100 1.0 Hydro and Pumped Storage 13,954 20.7 33,260 16.3 Natural Gas 41,370 61.4 107,522 52.7 Other 1 220 0.3 2,534 1.2 Other Renewable 1 6,319 9.4 25,450 12.5 Petroleum 701 1.0 1,059 0.5 Total 67,328 100.0 204,126 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste,

  11. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    9 Connecticut Connecticut total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 2,103 25.4 16,750 50.2 Coal 564 6.8 2,604 7.8 Hydro and Pumped Storage 151 1.8 400 1.2 Natural Gas 2,292 27.7 11,716 35.1 Other 1 27 0.3 730 2.2 Other Renewable 1 159 1.9 740 2.2 Petroleum 2,989 36.1 409 1.2 Total 8,284 100.0 33,350 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture

  12. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Florida Florida total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 3,924 6.6 23,936 10.4 Coal 9,975 16.9 59,897 26.1 Hydro and Pumped Storage 55 0.1 177 0.1 Natural Gas 31,563 53.4 128,634 56.1 Other 1 544 0.9 2,842 1.2 Other Renewable 1 1,053 1.8 4,487 2.0 Petroleum 12,033 20.3 9,122 4.0 Total 59,147 100.0 229,096 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture

  13. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Georgia Georgia total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 4,061 11.1 33,512 24.4 Coal 13,230 36.1 73,298 53.3 Hydro and Pumped Storage 3,851 10.5 3,044 2.2 Natural Gas 12,668 34.6 23,884 17.4 Other 1 - - 18 * Other Renewable 1 637 1.7 3,181 2.3 Petroleum 2,189 6.0 641 0.5 Total 36,636 100.0 137,577 100.0 * = Absolute percentage less than 0.05. - = No data reported. Other Renewable: Wood, black liquor, other wood waste, biogenic municipal

  14. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    7 Illinois Illinois total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 11,441 25.9 96,190 47.8 Coal 15,551 35.2 93,611 46.5 Hydro and Pumped Storage 34 0.1 119 0.1 Natural Gas 13,771 31.2 5,724 2.8 Other 1 145 0.3 461 0.2 Other Renewable 1 2,078 4.7 5,138 2.6 Petroleum 1,106 2.5 110 0.1 Total 44,127 100.0 201,352 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture

  15. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    21 Louisiana Louisiana total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 2,142 8.0 18,639 18.1 Coal 3,417 12.8 23,924 23.3 Hydro and Pumped Storage 192 0.7 1,109 1.1 Natural Gas 19,574 73.2 51,344 49.9 Other 1 213 0.8 2,120 2.1 Other Renewable 1 325 1.2 2,468 2.4 Petroleum 881 3.3 3,281 3.2 Total 26,744 100.0 102,885 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture

  16. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Maryland Maryland total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 1,705 13.6 13,994 32.1 Coal 4,886 39.0 23,668 54.3 Hydro and Pumped Storage 590 4.7 1,667 3.8 Natural Gas 2,041 16.3 2,897 6.6 Other 1 152 1.2 485 1.1 Other Renewable 1 209 1.7 574 1.3 Petroleum 2,933 23.4 322 0.7 Total 12,516 100.0 43,607 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture

  17. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Massachusetts Massachusetts total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 685 5.0 5,918 13.8 Coal 1,669 12.2 8,306 19.4 Hydro and Pumped Storage 1,942 14.2 659 1.5 Natural Gas 6,063 44.3 25,582 59.8 Other 1 3 * 771 1.8 Other Renewable 1 304 2.2 1,274 3.0 Petroleum 3,031 22.1 296 0.7 Total 13,697 100.0 42,805 100.0 * = Absolute percentage less than 0.05. Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste,

  18. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    7 Michigan Michigan total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 3,947 13.2 29,625 26.6 Coal 11,531 38.7 65,604 58.8 Hydro and Pumped Storage 2,109 7.1 228 0.2 Natural Gas 11,033 37.0 12,249 11.0 Other 1 - - 631 0.6 Other Renewable 1 571 1.9 2,832 2.5 Petroleum 640 2.1 382 0.3 Total 29,831 100.0 111,551 100.0 - = No data reported. Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste,

  19. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    9 Minnesota Minnesota total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 1,594 10.8 13,478 25.1 Coal 4,789 32.5 28,083 52.3 Hydro and Pumped Storage 193 1.3 840 1.6 Natural Gas 4,936 33.5 4,341 8.1 Other 1 13 0.1 258 0.5 Other Renewable 1 2,395 16.3 6,640 12.4 Petroleum 795 5.4 31 0.1 Total 14,715 100.0 53,670 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture

  20. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Mississippi Mississippi total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 1,251 8.0 9,643 17.7 Coal 2,526 16.1 13,629 25.0 Natural Gas 11,640 74.2 29,619 54.4 Other 1 4 * 10 * Other Renewable 1 235 1.5 1,504 2.8 Petroleum 35 0.2 81 0.1 Total 15,691 100.0 54,487 100.0 * = Absolute percentage less than 0.05. Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture byproducts,

  1. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    1 Missouri Missouri total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 1,190 5.5 8,996 9.7 Coal 12,070 55.5 75,047 81.3 Hydro and Pumped Storage 1,221 5.6 2,427 2.6 Natural Gas 5,579 25.7 4,690 5.1 Other 1 - - 39 * Other Renewable 1 466 2.1 988 1.1 Petroleum 1,212 5.6 126 0.1 Total 21,739 100.0 92,313 100.0 * = Absolute percentage less than 0.05. - = No data reported. Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid

  2. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    41 New Jersey New Jersey total electric power industry, summer capacity and net generation, by source, 2010 Nuclear 4,108 22.3 32,771 49.9 Coal 2,036 11.1 6,418 9.8 Hydro and Pumped Storage 404 2.2 -176 -0.3 Natural Gas 10,244 55.6 24,902 37.9 Other 1 56 0.3 682 1.0 Other Renewable 1 226 1.2 850 1.3 Petroleum 1,351 7.3 235 0.4 Total 18,424 100.0 65,682 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture byproducts,

  3. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    3 New York New York total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 5,271 13.4 41,870 30.6 Coal 2,781 7.1 13,583 9.9 Hydro and Pumped Storage 5,714 14.5 24,942 18.2 Natural Gas 17,407 44.2 48,916 35.7 Other 1 45 0.1 832 0.6 Other Renewable 1 1,719 4.4 4,815 3.5 Petroleum 6,421 16.3 2,005 1.5 Total 39,357 100.0 136,962 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste,

  4. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    34 North Carolina North Carolina total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 4,958 17.9 40,740 31.7 Coal 12,766 46.1 71,951 55.9 Hydro and Pumped Storage 2,042 7.4 4,757 3.7 Natural Gas 6,742 24.4 8,447 6.6 Other 1 50 0.2 407 0.3 Other Renewable 1 543 2.0 2,083 1.6 Petroleum 573 2.1 293 0.2 Total 27,674 100.0 128,678 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste,

  5. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Ohio Ohio total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 2,134 6.5 15,805 11.0 Coal 21,360 64.6 117,828 82.1 Hydro and Pumped Storage 101 0.3 429 0.3 Natural Gas 8,203 24.8 7,128 5.0 Other 1 123 0.4 266 0.2 Other Renewable 1 130 0.4 700 0.5 Petroleum 1,019 3.1 1,442 1.0 Total 33,071 100.0 143,598 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture byproducts,

  6. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    48 Pennsylvania Pennsylvania total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 9,540 20.9 77,828 33.9 Coal 18,481 40.6 110,369 48.0 Hydro and Pumped Storage 2,268 5.0 1,624 0.7 Natural Gas 9,415 20.7 33,718 14.7 Other 1 100 0.2 1,396 0.6 Other Renewable 1 1,237 2.7 4,245 1.8 Petroleum 4,534 9.9 571 0.2 Total 45,575 100.0 229,752 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste,

  7. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    1 South Carolina South Carolina total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 6,486 27.0 51,988 49.9 Coal 7,230 30.1 37,671 36.2 Hydro and Pumped Storage 4,006 16.7 1,442 1.4 Natural Gas 5,308 22.1 10,927 10.5 Other 1 - - 61 0.1 Other Renewable 1 284 1.2 1,873 1.8 Petroleum 670 2.8 191 0.2 Total 23,982 100.0 104,153 100.0 - = No data reported. Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas,

  8. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    6 Texas Texas total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 4,966 4.6 41,335 10.0 Coal 22,335 20.6 150,173 36.5 Hydro and Pumped Storage 689 0.6 1,262 0.3 Natural Gas 69,291 64.0 186,882 45.4 Other 1 477 0.4 3,630 0.9 Other Renewable 1 10,295 9.5 27,705 6.7 Petroleum 204 0.2 708 0.2 Total 108,258 100.0 411,695 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture

  9. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Virginia Virginia total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 3,501 14.5 26,572 36.4 Coal 5,868 24.3 25,459 34.9 Hydro and Pumped Storage 4,107 17.0 10 * Natural Gas 7,581 31.4 16,999 23.3 Other 1 - - 414 0.6 Other Renewable 1 621 2.6 2,220 3.0 Petroleum 2,432 10.1 1,293 1.8 Total 24,109 100.0 72,966 100.0 * = Absolute percentage less than 0.05. - = No data reported. Other Renewable: Wood, black liquor, other wood waste, biogenic municipal

  10. State Nuclear Profiles 2010

    U.S. Energy Information Administration (EIA) Indexed Site

    63 Wisconsin Wisconsin total electric power industry, summer capacity and net generation, by energy source, 2010 Nuclear 1,584 8.9 13,281 20.7 Coal 8,063 45.2 40,169 62.5 Hydro and Pumped Storage 492 2.8 2,112 3.3 Natural Gas 6,110 34.3 5,497 8.5 Other 1 21 0.1 63 0.1 Other Renewable 1 775 4.3 2,474 3.8 Petroleum 790 4.4 718 1.1 Total 17,836 100.0 64,314 100.0 Other Renewable: Wood, black liquor, other wood waste, biogenic municipal solid waste, landfill gas, sludge waste, agriculture

  11. Red phosphor Ca{sub 2}Ge{sub 7}O{sub 16}:Eu{sup 3+} for potential application in field emission displays and white light-emitting diodes

    SciTech Connect (OSTI)

    Wang, Ting; Xu, Xuhui; Zhou, Dacheng; Qiu, Jianbei; Yu, Xue

    2014-12-15

    Abstract: A novel red emitting phosphor of Eu{sup 3+} doped Ca{sub 2}Ge{sub 7}O{sub 16} was prepared through the solid state reaction. The luminescence properties were studied in detail by photoluminescence excitation (PLE), emission (PL) spectra and cathodoluminescence (CL). Under the excitation of ultraviolet light, Ca{sub 2}Ge{sub 7}O{sub 16}:Eu{sup 3+} phosphor shows the characteristic {sup 5}D{sub 0}-{sup 7}F{sub J}(J = 1, 2, 3, 4) transition of Eu{sup 3+} with two different emissions due to the two kinds of Eu{sup 3+} ions. The luminescent intensity could be improved by co-doping with the charge compensators R{sup +} (Li, Na, K) which partially substitute for Ca{sup 2+} crystal sites. CL spectra show that Eu{sup 3+} ions were excited by the plasma produced by the incident electrons and the CL properties of Ca{sub 2}Ge{sub 7}O{sub 16}:Eu{sup 3+}, Li{sup +} as a function of accelerating voltage and probe current were investigated. Ca{sub 2}Ge{sub 7}O{sub 16}:Eu{sup 3+} phosphor offers higher thermal stability compared with the commercial red phosphor Y{sub 2}O{sub 3}:Eu{sup 3+}. The results indicate that Ca{sub 2}Ge{sub 7}O{sub 16}:Eu{sup 3+} can be a suitable red-emitting phosphor candidate for FEDs and w-LEDs.

  12. Acoustic transfer of protein crystals from agarose pedestals to micromeshes for high-throughput screening

    SciTech Connect (OSTI)

    Cuttitta, Christina M.; Ericson, Daniel L.; Scalia, Alexander; Roessler, Christian G.; Teplitsky, Ella; Joshi, Karan; Campos, Olven; Agarwal, Rakhi; Allaire, Marc; Orville, Allen M.; Sweet, Robert M.; Soares, Alexei S.

    2014-06-01

    Acoustic droplet ejection (ADE) is an emerging technology with broad applications in serial crystallography such as growing, improving and manipulating protein crystals. One application of this technology is to gently transfer crystals onto MiTeGen micromeshes with minimal solvent. Once mounted on a micromesh, each crystal can be combined with different chemicals such as crystal-improving additives or a fragment library. Acoustic crystal mounting is fast (2.33 transfers s-1) and all transfers occur in a sealed environment that is in vapor equilibrium with the mother liquor. Here, a system is presented to retain crystals near the ejection point and away from the inaccessible dead volume at the bottom of the well by placing the crystals on a concave agarose pedestal (CAP) with the same chemical composition as the crystal mother liquor. The bowl-shaped CAP is impenetrable to crystals. Consequently, gravity will gently move the crystals into the optimal location for acoustic ejection. It is demonstrated that an agarose pedestal of this type is compatible with most commercially available crystallization conditions and that protein crystals are readily transferred from the agarose pedestal onto micromeshes with no loss in diffraction quality. It is also shown that crystals can be grown directly on CAPs, which avoids the need to transfer the crystals from the hanging drop to a CAP. This technology has been used to combine thermolysin and lysozyme crystals with an assortment of anomalously scattering heavy atoms. The results point towards a fast nanolitre method for crystal mounting and high-throughput screening.

  13. Acoustic transfer of protein crystals from agarose pedestals to micromeshes for high-throughput screening

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Cuttitta, Christina M.; Ericson, Daniel L.; Scalia, Alexander; Roessler, Christian G.; Teplitsky, Ella; Joshi, Karan; Campos, Olven; Agarwal, Rakhi; Allaire, Marc; Orville, Allen M.; et al

    2014-06-01

    Acoustic droplet ejection (ADE) is an emerging technology with broad applications in serial crystallography such as growing, improving and manipulating protein crystals. One application of this technology is to gently transfer crystals onto MiTeGen micromeshes with minimal solvent. Once mounted on a micromesh, each crystal can be combined with different chemicals such as crystal-improving additives or a fragment library. Acoustic crystal mounting is fast (2.33 transfers s-1) and all transfers occur in a sealed environment that is in vapor equilibrium with the mother liquor. Here, a system is presented to retain crystals near the ejection point and away from themore » inaccessible dead volume at the bottom of the well by placing the crystals on a concave agarose pedestal (CAP) with the same chemical composition as the crystal mother liquor. The bowl-shaped CAP is impenetrable to crystals. Consequently, gravity will gently move the crystals into the optimal location for acoustic ejection. It is demonstrated that an agarose pedestal of this type is compatible with most commercially available crystallization conditions and that protein crystals are readily transferred from the agarose pedestal onto micromeshes with no loss in diffraction quality. It is also shown that crystals can be grown directly on CAPs, which avoids the need to transfer the crystals from the hanging drop to a CAP. This technology has been used to combine thermolysin and lysozyme crystals with an assortment of anomalously scattering heavy atoms. The results point towards a fast nanolitre method for crystal mounting and high-throughput screening.« less

  14. Acoustic transfer of protein crystals from agarose pedestals to micromeshes for high-throughput screening

    SciTech Connect (OSTI)

    Cuttitta, Christina M.; Ericson, Daniel L.; Scalia, Alexander; Roessler, Christian G.; Teplitsky, Ella; Joshi, Karan; Campos, Olven; Agarwal, Rakhi; Allaire, Marc; Orville, Allen M.; Sweet, Robert M.; Soares, Alexei S.

    2015-01-01

    An acoustic high-throughput screening method is described for harvesting protein crystals and combining the protein crystals with chemicals such as a fragment library. Acoustic droplet ejection (ADE) is an emerging technology with broad applications in serial crystallography such as growing, improving and manipulating protein crystals. One application of this technology is to gently transfer crystals onto MiTeGen micromeshes with minimal solvent. Once mounted on a micromesh, each crystal can be combined with different chemicals such as crystal-improving additives or a fragment library. Acoustic crystal mounting is fast (2.33 transfers s{sup −1}) and all transfers occur in a sealed environment that is in vapor equilibrium with the mother liquor. Here, a system is presented to retain crystals near the ejection point and away from the inaccessible dead volume at the bottom of the well by placing the crystals on a concave agarose pedestal (CAP) with the same chemical composition as the crystal mother liquor. The bowl-shaped CAP is impenetrable to crystals. Consequently, gravity will gently move the crystals into the optimal location for acoustic ejection. It is demonstrated that an agarose pedestal of this type is compatible with most commercially available crystallization conditions and that protein crystals are readily transferred from the agarose pedestal onto micromeshes with no loss in diffraction quality. It is also shown that crystals can be grown directly on CAPs, which avoids the need to transfer the crystals from the hanging drop to a CAP. This technology has been used to combine thermolysin and lysozyme crystals with an assortment of anomalously scattering heavy atoms. The results point towards a fast nanolitre method for crystal mounting and high-throughput screening.

  15. The newest achievements of studies on the reutilization, treatment, and disposal technology of hazardous wastes

    SciTech Connect (OSTI)

    Liu Peizhe

    1996-12-31

    From 1991 to 1996, key studies on the reutilization, treatment, and disposal technology of hazardous wastes have been incorporated into the national plan for environmental protection science and technology. At present, the research achievements have been accomplished, have passed national approval, and have been accepted. The author of this paper, as leader of the national group for this research work, expounds the newest achievements of the studies involving four parts: (1) the reutilization technology of electroplating sludge, including the ion-exchange process for recovering the sludge and waste liquor for producing chromium tanning agent and extracting chromium and colloidal protein from tanning waste residue; on the recovery of heavy metals from the electroplating waste liquor with microbic purification; on the demonstration project of producing modified plastics from the sludge and the waste plastics; and on the demonstration of the recovery of heavy metals from waste electroplating sludge by using the ammonia-leaching process; (2) the demonstrative research of reutilization technology of chromium waste residues, including production of self-melting ore and smelting of chromium-containing pig iron, and of pyrolytic detoxification of the residue with cyclone furnace; (3) the incineration technology of hazardous wastes with successful results of the industrial incinerator system for polychlorinated biphenyls; and (4) the safety landfill technology for disposal of hazardous wastes, with a complete set of technology for pretreatment, selection of the site, development of the antipercolating materials, and design and construction of the landfill. Only a part of the achievements is introduced in this paper, most of which has been built and is being operated for demonstration to further spreading application and accumulate experience. 6 refs., 7 figs., 6 tabs.

  16. Recovery of yttrium from cathode ray tubes and lamps’ fluorescent powders: experimental results and economic simulation

    SciTech Connect (OSTI)

    Innocenzi, V. De Michelis, I.; Ferella, F.; Vegliò, F.

    2013-11-15

    Highlights: • Fluorescent powder of lamps. • Fluorescent powder of cathode ray rubes. • Recovery of yttrium from fluorescent powders. • Economic simulation for the processes to recover yttrium from WEEE. - Abstract: In this paper, yttrium recovery from fluorescent powder of lamps and cathode ray tubes (CRTs) is described. The process for treating these materials includes the following: (a) acid leaching, (b) purification of the leach liquors using sodium hydroxide and sodium sulfide, (c) precipitation of yttrium using oxalic acid, and (d) calcinations of oxalates for production of yttrium oxides. Experimental results have shown that process conditions necessary to purify the solutions and recover yttrium strongly depend on composition of the leach liquor, in other words, whether the powder comes from treatment of CRTs or lamp. In the optimal experimental conditions, the recoveries of yttrium oxide are about 95%, 55%, and 65% for CRT, lamps, and CRT/lamp mixture (called MIX) powders, respectively. The lower yields obtained during treatments of MIX and lamp powders are probably due to the co-precipitation of yttrium together with other metals contained in the lamps powder only. Yttrium loss can be reduced to minimum changing the experimental conditions with respect to the case of the CRT process. In any case, the purity of final products from CRT, lamps, and MIX is greater than 95%. Moreover, the possibility to treat simultaneously both CRT and lamp powders is very important and interesting from an industrial point of view since it could be possible to run a single plant treating fluorescent powder coming from two different electronic wastes.

  17. Method for minimizing environmental release of toxic compounds in the incineration of wastes

    SciTech Connect (OSTI)

    Lerner, B.J.

    1993-08-24

    A method is described for reducing the discharge of contaminated liquid streams in the treatment of hot waste incinerator exhaust gases containing hydrochloric acid gas, particulate fly ash, toxic metal oxides and toxic organic compounds, comprising the steps of: contacting the exhaust gases with an alkaline material; reacting the major portion of the hydrochloric acid gas content of the exhaust gases with the alkaline material; removing substantially all of the reacted spent alkaline material, fly ash and other particulate matter from the gas in a solids separation stage; treating the particulate-free exhaust gases from the solids separation stage in at least two wet scrubber contact stages operating in series; operating each of the wet scrubber stages with separate dedicated salt-free aqueous scrubbing solutions; scrubbing the gas in the successive wet scrubber contact stages with acid solutions of diminishing acid concentration; absorbing in the scrubbing liquor of the wet scrubber stages substantially all of the residual hydrochloric acid and a portion of the toxic organic compounds from the particulate-free exhaust gases; operating at least the first wet scrubber stage with a recycle aqueous salt-free scrubbing solution loop; recycling a portion of the aqueous acid scrubbing solution from a downstream wet scrubber stage to the initial wet scrubber contactor stage; collecting and conveying the contaminated acid liquid blowdown stream from the initial wet scrubbing liquid recycle loop to the waste incinerator; reincinerating the acid liquor blowdown stream in the waste incinerator for destruction of the organic toxics; removing the major portion of the recycled acid gas in the first alkaline dry solids gas treatment stage and thereby eliminating discharge of a contaminated liquid stream to the environment; and thereafter recovering a purified gaseous stream from the wet scrubbing stages.

  18. LINE LISTS FOR THE A {sup 2}Π-X {sup 2}Σ{sup +} (RED) AND B {sup 2}Σ{sup +}-X {sup 2}Σ{sup +} (VIOLET) SYSTEMS OF CN, {sup 13}C{sup 14}N, AND {sup 12}C{sup 15}N, AND APPLICATION TO ASTRONOMICAL SPECTRA

    SciTech Connect (OSTI)

    Sneden, Christopher; Lucatello, Sara; Ram, Ram S.; Brooke, James S. A.; Bernath, Peter E-mail: sara.lucatello@oapd.inaf.it E-mail: jsabrooke@gmail.com

    2014-10-01

    New red and violet system line lists for the CN isotopologues {sup 13}C{sup 14}N and {sup 12}C{sup 15}N have been generated. These new transition data are combined with those previously derived for {sup 12}C{sup 14}N, and applied to the determination of CNO abundances in the solar photosphere and in four red giant stars: Arcturus, the bright, very low-metallicity star HD 122563, and the carbon-enhanced metal-poor stars HD 196944 and HD 201626. When both red and violet system lines are detectable in a star, their derived N abundances are in good agreement. The mean N abundances determined in this work are also generally in accord with published values.

  19. Infrared Multiphoton Dissociation Spectroscopy of a Gas-Phase Complex of Uranyl and 3-Oxa-Glutaramide: An Extreme Red-Shift of the [O=U=O]²⁺ Asymmetric Stretch

    SciTech Connect (OSTI)

    Gibson, John K.; Hu, Hanshi; Van Stipdonk, Michael J.; Berden, Giel; Oomens, Jos; Li, Jun

    2015-04-09

    The gas-phase complex UO₂(TMOGA)₂²⁺ (TMOGA = tetramethyl-3-oxa-glutaramide) prepared by electrospray ionization was characterized by infrared multiphoton dissociation (IRMPD) spectroscopy. The IRMPD spectrum from 700–1800 cm⁻¹ was interpreted using a computational study based on density functional theory. The predicted vibrational frequencies are in good agreement with the measured values, with an average deviation of only 8 cm⁻¹ (<1%) and a maximum deviation of 21 cm⁻¹ (<2%). The only IR peak assigned to the linear uranyl moiety was the asymmetric ν₃ mode, which appeared at 965 cm⁻¹ and was predicted by DFT as 953 cm⁻¹. This ν₃ frequency is red-shifted relative to bare uranyl, UO₂²⁺, by ca. 150 cm⁻¹ due to electron donation from the TMOGA ligands. Based on the degree of red-shifting, it is inferred that two TMOGA oxygen-donor ligands have a greater effective gas basicity than the four monodentate acetone ligands in UO₂(acetone)₄²⁺. The uranyl ν₃ frequency was also computed for uranyl coordinated by two TMGA ligands, in which the central Oether of TMOGA has been replaced by CH₂. The computed ν₃ for UO₂(TMGA)₂²⁺, 950 cm⁻¹, is essentially the same as that for UO₂(TMOGA)₂²⁺, suggesting that electron donation to uranyl from the Oether of TMOGA is minor. The computed ν₃ asymmetric stretching frequencies for the three actinyl complexes, UO₂(TMOGA)₂²⁺, NpO₂(TMOGA)₂²⁺ and PuO₂(TMOGA)₂²⁺, are comparable. This similarity is discussed in the context of the relationship between ν₃ and intrinsic actinide-oxygen bond energies in actinyl complexes.

  20. Defect correlated fluorescent quenching and electron phonon coupling in the spectral transition of Eu{sup 3+} in CaTiO{sub 3} for red emission in display application

    SciTech Connect (OSTI)

    Som, S. E-mail: swarthc@ufs.ac.za; Kumar, Vinod; Kumar, Vijay; Terblans, J. J.; Swart, H. C. E-mail: swarthc@ufs.ac.za; Kunti, A. K.; Dutta, S.; Chowdhury, M.; Sharma, S. K.

    2014-05-21

    This paper reports on the defect correlated self-quenching and spectroscopic investigation of calcium titanate (CaTiO{sub 3}) phosphors. A series of CaTiO{sub 3} phosphors doped with trivalent europium (Eu{sup 3+}) and codoped with potassium (K{sup +}) ions were prepared by the solid state reaction method. The X-ray diffraction results revealed that the obtained powder phosphors consisted out of a single-phase orthorhombic structure and it also indicated that the incorporation of the dopants/co-dopants did not affect the crystal structure. The scanning electron microscopy images revealed the irregular morphology of the prepared phosphors consisting out of ?m sized diameter particles. The Eu{sup 3+} doped phosphors illuminated with ultraviolet light showed the characteristic red luminescence corresponding to the {sup 5}D{sub 0}?{sup 7}F{sub J} transitions of Eu{sup 3+}. As a charge compensator, K{sup +} ions were incorporated into the CaTiO{sub 3}:Eu{sup 3+} phosphors, which enhanced the photoluminescence (PL) intensities depending on the doping concentration of K{sup +}. The concentration quenching of Eu{sup 3+} in this host is discussed in the light of ion-ion interaction, electron phonon coupling, and defect to ion energy transfer. The spectral characteristics and the Eu-O ligand behaviour were determined using the Judd-Ofelt theory from the PL spectra instead of the absorption spectra. The CIE (International Commission on Illumination) parameters were calculated using spectral energy distribution functions and McCamy's empirical formula. Photometric characterization indicated the suitability of K{sup +} compensated the CaTiO{sub 3}:Eu{sup 3+} phosphor for pure red emission in light-emitting diode applications.