National Library of Energy BETA

Sample records for liquids oxygenates fuel

  1. Plant for producing an oxygen-containing additive as an ecologically beneficial component for liquid motor fuels

    DOE Patents [OSTI]

    Siryk, Yury Paul; Balytski, Ivan Peter; Korolyov, Volodymyr George; Klishyn, Olexiy Nick; Lnianiy, Vitaly Nick; Lyakh, Yury Alex; Rogulin, Victor Valery

    2013-04-30

    A plant for producing an oxygen-containing additive for liquid motor fuels comprises an anaerobic fermentation vessel, a gasholder, a system for removal of sulphuretted hydrogen, and a hotwell. The plant further comprises an aerobic fermentation vessel, a device for liquid substance pumping, a device for liquid aeration with an oxygen-containing gas, a removal system of solid mass residue after fermentation, a gas distribution device; a device for heavy gases utilization; a device for ammonia adsorption by water; a liquid-gas mixer; a cavity mixer, a system that serves superficial active and dispersant matters and a cooler; all of these being connected to each other by pipelines. The technical result being the implementation of a process for producing an oxygen containing additive, which after being added to liquid motor fuels, provides an ecologically beneficial component for motor fuels by ensuring the stability of composition fuel properties during long-term storage.

  2. Liquid Fuel From Bacteria: Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from CO2, Hydrogen, and Oxygen

    SciTech Connect (OSTI)

    2010-07-15

    Electrofuels Project: MIT is using solar-derived hydrogen and common soil bacteria called Ralstonia eutropha to turn carbon dioxide (CO2) directly into biofuel. This bacteria already has the natural ability to use hydrogen and CO2 for growth. MIT is engineering the bacteria to use hydrogen to convert CO2 directly into liquid transportation fuels. Hydrogen is a flammable gas, so the MIT team is building an innovative reactor system that will safely house the bacteria and gas mixture during the fuel-creation process. The system will pump in precise mixtures of hydrogen, oxygen, and CO2, and the online fuel-recovery system will continuously capture and remove the biofuel product.

  3. Fuel cell oxygen electrode

    DOE Patents [OSTI]

    Shanks, H.R.; Bevolo, A.J.; Danielson, G.C.; Weber, M.F.

    An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A/sub x/WO/sub 3/ where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt/sub y/WO/sub 3/ where y is at least 0.8.

  4. Fuel cell oxygen electrode

    DOE Patents [OSTI]

    Shanks, Howard R. (Ames, IA); Bevolo, Albert J. (Ames, IA); Danielson, Gordon C. (Ames, IA); Weber, Michael F. (Wichita, KS)

    1980-11-04

    An oxygen electrode for a fuel cell utilizing an acid electrolyte has a substrate of an alkali metal tungsten bronze of the formula: A.sub.x WO.sub.3 where A is an alkali metal and x is at least 0.2, which is covered with a thin layer of platinum tungsten bronze of the formula: Pt.sub.y WO.sub.3 where y is at least 0.8.

  5. Fuel Ethanol Oxygenate Production

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Product: Fuel Ethanol Methyl Tertiary Butyl Ether Merchant Plants Captive Plants Period-Unit: Monthly-Thousand Barrels Monthly-Thousand Barrels per Day Annual-Thousand Barrels ...

  6. Conversion of cellulosic wastes to liquid fuels

    SciTech Connect (OSTI)

    Kuester, J.L.

    1980-09-01

    The current status and future plans for a project to convert waste cellulosic (biomass) materials to quality liquid hydrocarbon fuels is described. The basic approach is indirect liquefaction, i.e., thermal gasification followed by catalytic liquefaction. The indirect approach results in separation of the oxygen in the biomass feedstock, i.e., oxygenated compounds do not appear in the liquid hydrocarbon fuel product. The process is capable of accepting a wide variety of feedstocks. Potential products include medium quality gas, normal propanol, diesel fuel and/or high octane gasoline. A fluidized bed pyrolysis system is used for gasification. The pyrolyzer can be fluidized with recycle pyrolysis gas, steam or recycle liquefaction system off gas or some combination thereof. Tars are removed in a wet scrubber. Unseparated pyrolysis gases are utilized as feed to a modified Fischer-Tropsch reactor. The liquid condensate from the reactor consists of a normal propanol-water phase and a paraffinic hydrocarbon phase. The reactor can be operated to optimize for either product. The following tasks were specified in the statement of work for the contract period: (1) feedstock studies; (2) gasification system optimization; (3) waste stream characterization; and (4) liquid fuels synthesis. In addition, several equipment improvements were implemented.

  7. Liquid Fuels from Biomass

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs.

  8. Alternative Liquid Fuels (ALF) | Open Energy Information

    Open Energy Info (EERE)

    Liquid Fuels (ALF) Jump to: navigation, search Name: Alternative Liquid Fuels (ALF) Address: P.O. Box 76 Place: McArthur, Ohio Zip: 45651 Sector: Biofuels, Renewable Energy,...

  9. Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

    DOE Patents [OSTI]

    Dumesic, James A.; Ruiz, Juan Carlos Serrano; West, Ryan M.

    2012-04-03

    Described is a method to make liquid chemicals, such as functional intermediates, solvents, and liquid fuels from biomass-derived cellulose. The method is cascading; the product stream from an upstream reaction can be used as the feedstock in the next downstream reaction. The method includes the steps of deconstructing cellulose to yield a product mixture comprising levulinic acid and formic acid, converting the levulinic acid to .gamma.-valerolactone, and converting the .gamma.-valerolactone to pentanoic acid. Alternatively, the .gamma.-valerolactone can be converted to a mixture of n-butenes. The pentanoic acid so formed can be further reacted to yield a host of valuable products. For example, the pentanoic acid can be decarboxylated yield 1-butene or ketonized to yield 5-nonanone. The 5-nonanone can be hydrodeoxygenated to yield nonane, or 5-nonanone can be reduced to yield 5-nonanol. The 5-nonanol can be dehydrated to yield nonene, which can be dimerized to yield a mixture of C.sub.9 and C.sub.18 olefins, which can be hydrogenated to yield a mixture of alkanes. Alternatively, the nonene may be isomerized to yield a mixture of branched olefins, which can be hydrogenated to yield a mixture of branched alkanes. The mixture of n-butenes formed from .gamma.-valerolactone can also be subjected to isomerization and oligomerization to yield olefins in the gasoline, jet and Diesel fuel ranges.

  10. Stationary Liquid Fuel Fast Reactor

    SciTech Connect (OSTI)

    Yang, Won Sik; Grandy, Andrew; Boroski, Andrew; Krajtl, Lubomir; Johnson, Terry

    2015-09-30

    For effective burning of hazardous transuranic (TRU) elements of used nuclear fuel, a transformational advanced reactor concept named SLFFR (Stationary Liquid Fuel Fast Reactor) was proposed based on stationary molten metallic fuel. The fuel enters the reactor vessel in a solid form, and then it is heated to molten temperature in a small melting heater. The fuel is contained within a closed, thick container with penetrating coolant channels, and thus it is not mixed with coolant nor flow through the primary heat transfer circuit. The makeup fuel is semi- continuously added to the system, and thus a very small excess reactivity is required. Gaseous fission products are also removed continuously, and a fraction of the fuel is periodically drawn off from the fuel container to a processing facility where non-gaseous mixed fission products and other impurities are removed and then the cleaned fuel is recycled into the fuel container. A reference core design and a preliminary plant system design of a 1000 MWt TRU- burning SLFFR concept were developed using TRU-Ce-Co fuel, Ta-10W fuel container, and sodium coolant. Conservative design approaches were adopted to stay within the current material performance database. Detailed neutronics and thermal-fluidic analyses were performed to develop a reference core design. Region-dependent 33-group cross sections were generated based on the ENDF/B-VII.0 data using the MC2-3 code. Core and fuel cycle analyses were performed in theta-r-z geometries using the DIF3D and REBUS-3 codes. Reactivity coefficients and kinetics parameters were calculated using the VARI3D perturbation theory code. Thermo-fluidic analyses were performed using the ANSYS FLUENT computational fluid dynamics (CFD) code. Figure 0.1 shows a schematic radial layout of the reference 1000 MWt SLFFR core, and Table 0.1 summarizes the main design parameters of SLFFR-1000 loop plant. The fuel container is a 2.5 cm thick cylinder with an inner radius of 87.5 cm. The fuel container is penetrated by twelve hexagonal control assembly (CA) guide tubes, each of which has 3.0 mm thickness and 69.4 mm flat-to-flat outer distance. The distance between two neighboring CA guide tube is selected to be 26 cm to provide an adequate space for CA driving systems. The fuel container has 18181 penetrating coolant tubes of 6.0 mm inner diameter and 2.0 mm thickness. The coolant tubes are arranged in a triangular lattice with a lattice pitch of 1.21 cm. The fuel, structure, and coolant volume fractions inside the fuel container are 0.386, 0.383, and 0.231, respectively. Separate steel reflectors and B4C shields are used outside of the fuel container. Six gas expansion modules (GEMs) of 5.0 cm thickness are introduced in the radial reflector region. Between the radial reflector and the fuel container is a 2.5 cm sodium gap. The TRU inventory at the beginning of equilibrium cycle (BOEC) is 5081 kg, whereas the TRU inventory at the beginning of life (BOL) was 3541 kg. This is because the equilibrium cycle fuel contains a significantly smaller fissile fraction than the LWR TRU feed. The fuel inventory at BOEC is composed of 34.0 a/o TRU, 41.4 a/o Ce, 23.6 a/o Co, and 1.03 a/o solid fission products. Since uranium-free fuel is used, a theoretical maximum TRU consumption rate of 1.011 kg/day is achieved. The semi-continuous fuel cycle based on the 300-batch, 1- day cycle approximation yields a burnup reactivity loss of 26 pcm/day, and requires a daily reprocessing of 32.5 kg of SLFFR fuel. This yields a daily TRU charge rate of 17.45 kg, including a makeup TRU feed of 1.011 kg recovered from the LWR used fuel. The charged TRU-Ce-Co fuel is composed of 34.4 a/o TRU, 40.6 a/o Ce, and 25.0 a/o Co.

  11. Cellulosic Liquid Fuels Commercial Production Today

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    liquid fuel from wood and other non-food biomass Our key product is Renewable ... petroleum replacement from cellulosic non- food biomass Powerful unit economics - cash ...

  12. Process for vaporizing a liquid hydrocarbon fuel

    DOE Patents [OSTI]

    Szydlowski, Donald F. (East Hartford, CT); Kuzminskas, Vaidotas (Glastonbury, CT); Bittner, Joseph E. (East Hartford, CT)

    1981-01-01

    The object of the invention is to provide a process for vaporizing liquid hydrocarbon fuels efficiently and without the formation of carbon residue on the apparatus used. The process includes simultaneously passing the liquid fuel and an inert hot gas downwardly through a plurality of vertically spaed apart regions of high surface area packing material. The liquid thinly coats the packing surface, and the sensible heat of the hot gas vaporizes this coating of liquid. Unvaporized liquid passing through one region of packing is uniformly redistributed over the top surface of the next region until all fuel has been vaporized using only the sensible heat of the hot gas stream.

  13. Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical...

    Office of Scientific and Technical Information (OSTI)

    Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping Citation Details In-Document Search Title: Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping ...

  14. Air Liquide - Biogas & Fuel Cells

    Broader source: Energy.gov (indexed) [DOE]

    and the environment PT Loma WWTP, Biogas to Fuel Cell Power BioFuels Energy Biogas to BioMethane to 4.5 MW Fuel Cell Power 3 FCE Fuel Cells 2 via directed...

  15. Low contaminant formic acid fuel for direct liquid fuel cell

    DOE Patents [OSTI]

    Masel, Richard I.; Zhu, Yimin; Kahn, Zakia; Man, Malcolm

    2009-11-17

    A low contaminant formic acid fuel is especially suited toward use in a direct organic liquid fuel cell. A fuel of the invention provides high power output that is maintained for a substantial time and the fuel is substantially non-flammable. Specific contaminants and contaminant levels have been identified as being deleterious to the performance of a formic acid fuel in a fuel cell, and embodiments of the invention provide low contaminant fuels that have improved performance compared to known commercial bulk grade and commercial purified grade formic acid fuels. Preferred embodiment fuels (and fuel cells containing such fuels) including low levels of a combination of key contaminants, including acetic acid, methyl formate, and methanol.

  16. Liquid Fuels Market Module - NEMS Documentation

    Reports and Publications (EIA)

    2014-01-01

    Defines the objectives of the Liquid Fuels Market Model (LFMM), describes its basic approach, and provides detail on how it works. This report is intended as a reference document for model analysts, users, and the public.

  17. Process for preparing a liquid fuel composition

    DOE Patents [OSTI]

    Singerman, Gary M. (Monroeville, PA)

    1982-03-16

    A process for preparing a liquid fuel composition which comprises liquefying coal, separating a mixture of phenols from said liquefied coal, converting said phenols to the corresponding mixture of anisoles, subjecting at least a portion of the remainder of said liquefied coal to hydrotreatment, subjecting at least a portion of said hydrotreated liquefied coal to reforming to obtain reformate and then combining at least a portion of said anisoles and at least a portion of said reformate to obtain said liquid fuel composition.

  18. Nonconventional Liquid Fuels (released in AEO2006)

    Reports and Publications (EIA)

    2006-01-01

    Higher prices for crude oil and refined petroleum products are opening the door for nonconventional liquids to displace petroleum in the traditional fuel supply mix. Growing world demand for diesel fuel is helping to jump-start the trend toward increasing production of nonconventional liquids, and technological advances are making the nonconventional alternatives more viable commercially. Those trends are reflected in the Annual Energy Outlook 2006 projections.

  19. Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers National Energy Technology Laboratory Contact NETL About This Technology Publications: PDF Document Publication 13159553.pdf (405 KB) Technology Marketing Summary This patent-pending technology, "Regenerable Mixed Copper-Iron-Inert Support Oxygen Carriers for Solid Fuel Chemical Looping Combustion Process," provides a metal-oxide oxygen

  20. Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

    DOE Patents [OSTI]

    Dumesic, James A [Verona, WI; Ruiz, Juan Carlos Serrano [Madison, WI; West, Ryan M [Madison, WI

    2014-01-07

    Described is a method to make liquid chemicals. The method includes deconstructing cellulose to yield a product mixture comprising levulinic acid and formic acid, converting the levulinic acid to .gamma.-valerolactone, and converting the .gamma.-valerolactone to pentanoic acid. Alternatively, the .gamma.-valerolactone can be conveted to a mixture of n-butenes. The pentanoic acid can be decarboxylated yield 1-butene or ketonized to yield 5-nonanone. The 5-nonanone can be hydrodeoxygenated to yield nonane, or 5-nonanone can be reduced to yield 5-nonanol. The 5-nonanol can be dehydrated to yield nonene, which can be dimerized to yield a mixture of C.sub.9 and C.sub.18 olefins, which can be hydrogenated to yield a mixture of alkanes.

  1. Catalytic conversion of cellulose to liquid hydrocarbon fuels by progressive removal of oxygen to facilitate separation processes and achieve high selectivities

    DOE Patents [OSTI]

    Dumesic, James A.; Ruiz, Juan Carlos Serrano; West, Ryan M.

    2015-06-30

    Described is a method to make liquid chemicals. The method includes deconstructing cellulose to yield a product mixture comprising levulinic acid and formic acid, converting the levulinic acid to .gamma.-valerolactone, and converting the .gamma.-valerolactone to pentanoic acid. Alternatively, the .gamma.-valerolactone can be converted to a mixture of n-butenes. The pentanoic acid can be decarboxylated yield 1-butene or ketonized to yield 5-nonanone. The 5-nonanone can be hydrodeoxygenated to yield nonane, or 5-nonanone can be reduced to yield 5-nonanol. The 5-nonanol can be dehydrated to yield nonene, which can be dimerized to yield a mixture of C.sub.9 and C.sub.18 olefins, which can be hydrogenated to yield a mixture of alkanes.

  2. Advantages of Oxygenates Fuels over Gasoline in Direct Injection...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advantages of Oxygenates Fuels over Gasoline in Direct Injection Spark Ignition Engines Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) ...

  3. Liquid-hydrogen-fueled passenger aircraft

    SciTech Connect (OSTI)

    Not Available

    1986-03-11

    This Chinese translation discusses the idea that passenger aircraft will eventually use liquid-hydrogen fuel. There is a large reserve of hydrogen and hydrogen poses no danger to the environment. Hydrogen has high calorific value, high specific heat, low density, and low temperature. Aircraft will have to have liquid fuel tanks to carry the hydrogen and will have to be partially redesigned. Lockheed and NASA have considered such designs. A problem remains in the planning--the high cost of large extraction of liquid hydrogen.

  4. Air Liquide - Biogas & Fuel Cells | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Air Liquide - Biogas & Fuel Cells Air Liquide - Biogas & Fuel Cells Presentation about Air Liquide's biogas technologies and integration with fuel cells. Presented by Charlie Anderson, Air Liquide, at the NREL/DOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado. PDF icon june2012_biogas_workshop_anderson.pdf More Documents & Publications Biogas Technologies and Integration with Fuel Cells Biogas and Fuel Cells Workshop Summary Report: Proceedings from the

  5. POWER GENERATION FROM LIQUID METAL NUCLEAR FUEL

    DOE Patents [OSTI]

    Dwyer, O.E.

    1958-12-23

    A nuclear reactor system is described wherein the reactor is the type using a liquid metal fuel, such as a dispersion of fissile material in bismuth. The reactor is designed ln the form of a closed loop having a core sectlon and heat exchanger sections. The liquid fuel is clrculated through the loop undergoing flssion in the core section to produce heat energy and transferrlng this heat energy to secondary fluids in the heat exchanger sections. The fission in the core may be produced by a separate neutron source or by a selfsustained chain reaction of the liquid fuel present in the core section. Additional auxiliary heat exchangers are used in the system to convert water into steam which drives a turbine.

  6. Liquid Fuels from Lignins: Annual Report

    SciTech Connect (OSTI)

    Chum, H. L.; Johnson, D. K.

    1986-01-01

    This task was initiated to assess the conversion of lignins into liquid fuels, primarily of lignins relevant to biomass-to-ethanol conversion processes. The task was composed of a literature review of this area and an experimental part to obtain pertinent data on the conversion of lignins germane to biomass-to-ethanol conversion processes.

  7. THERMOCHEMICAL CONVERSION OF FERMENTATION-DERIVED OXYGENATES TO FUELS

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Wang, Yong

    2013-06-01

    At present ethanol generated from renewable resources through fermentation process is the dominant biofuel. But ethanol suffers from undesirable fuel properties such as low energy density and high water solubility. The production capacity of fermentation derived oxygenates are projected to rise in near future beyond the current needs. The conversion of oxygenates to hydrocarbon compounds that are similar to gasoline, diesel and jet fuel is considered as one of the viable option. In this chapter the thermo catalytic conversion of oxygenates generated through fermentation to fuel range hydrocarbons will be discussed.

  8. Integrated production of fuel gas and oxygenated organic compounds from synthesis gas

    DOE Patents [OSTI]

    Moore, Robert B.; Hegarty, William P.; Studer, David W.; Tirados, Edward J.

    1995-01-01

    An oxygenated organic liquid product and a fuel gas are produced from a portion of synthesis gas comprising hydrogen, carbon monoxide, carbon dioxide, and sulfur-containing compounds in a integrated feed treatment and catalytic reaction system. To prevent catalyst poisoning, the sulfur-containing compounds in the reactor feed are absorbed in a liquid comprising the reactor product, and the resulting sulfur-containing liquid is regenerated by stripping with untreated synthesis gas from the reactor. Stripping offgas is combined with the remaining synthesis gas to provide a fuel gas product. A portion of the regenerated liquid is used as makeup to the absorber and the remainder is withdrawn as a liquid product. The method is particularly useful for integration with a combined cycle coal gasification system utilizing a gas turbine for electric power generation.

  9. EIA Estimates of Crude Oil and Liquid Fuels Supply Disruptions

    Reports and Publications (EIA)

    2013-01-01

    Short-Term Energy Outlook Supplement: Energy Information Administration estimates of crude oil and liquid fuels supply disruptions

  10. Oxygen enhanced switching to combustion of lower rank fuels

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.; Wu, Kuang Tsai

    2004-03-02

    A furnace that combusts fuel, such as coal, of a given minimum energy content to obtain a stated minimum amount of energy per unit of time is enabled to combust fuel having a lower energy content, while still obtaining at least the stated minimum energy generation rate, by replacing a small amount of the combustion air fed to the furnace by oxygen. The replacement of oxygen for combustion air also provides reduction in the generation of NOx.

  11. HIGH ENERGY LIQUID FUELS FROM PLANTS

    SciTech Connect (OSTI)

    Nemethy, E. K.; Otvos, J. W.; Calvin, M.

    1980-10-01

    The heptane extract of Euphorbia lathyris has a low oxygen content and a heat valve of 42 MJ/kg which is comparable to that of crude oil (44 MJ/kg). These qualities indicate a potential for use as fuel or chemical feedstock material. Therefore we have investigated the chemical composition of this fraction in some detail. Since the amoun of the methanol fraction is quite substantial we have also identified the major components of this fraction.

  12. Reimagining liquid transportation fuels : sunshine to petrol.

    SciTech Connect (OSTI)

    Johnson, Terry Alan; Hogan, Roy E., Jr.; McDaniel, Anthony H.; Siegel, Nathan Phillip; Dedrick, Daniel E.; Stechel, Ellen Beth; Diver, Richard B., Jr.; Miller, James Edward; Allendorf, Mark D.; Ambrosini, Andrea; Coker, Eric Nicholas; Staiger, Chad Lynn; Chen, Ken Shuang; Ermanoski, Ivan; Kellog, Gary L.

    2012-01-01

    Two of the most daunting problems facing humankind in the twenty-first century are energy security and climate change. This report summarizes work accomplished towards addressing these problems through the execution of a Grand Challenge LDRD project (FY09-11). The vision of Sunshine to Petrol is captured in one deceptively simple chemical equation: Solar Energy + xCO{sub 2} + (x+1)H{sub 2}O {yields} C{sub x}H{sub 2x+2}(liquid fuel) + (1.5x+.5)O{sub 2} Practical implementation of this equation may seem far-fetched, since it effectively describes the use of solar energy to reverse combustion. However, it is also representative of the photosynthetic processes responsible for much of life on earth and, as such, summarizes the biomass approach to fuels production. It is our contention that an alternative approach, one that is not limited by efficiency of photosynthesis and more directly leads to a liquid fuel, is desirable. The development of a process that efficiently, cost effectively, and sustainably reenergizes thermodynamically spent feedstocks to create reactive fuel intermediates would be an unparalleled achievement and is the key challenge that must be surmounted to solve the intertwined problems of accelerating energy demand and climate change. We proposed that the direct thermochemical conversion of CO{sub 2} and H{sub 2}O to CO and H{sub 2}, which are the universal building blocks for synthetic fuels, serve as the basis for this revolutionary process. To realize this concept, we addressed complex chemical, materials science, and engineering problems associated with thermochemical heat engines and the crucial metal-oxide working-materials deployed therein. By project's end, we had demonstrated solar-driven conversion of CO{sub 2} to CO, a key energetic synthetic fuel intermediate, at 1.7% efficiency.

  13. Biomass and Natural Gas to Liquid Transportation Fuels | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy and Natural Gas to Liquid Transportation Fuels Biomass and Natural Gas to Liquid Transportation Fuels Breakout Session 1: New Developments and Hot Topics Session 1-D: Natural Gas & Biomass to Liquids Josephine Elia, Graduate Student, Princeton University PDF icon b13_elia_1-d.pdf More Documents & Publications Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Exploring the Optimum Role of Natural Gas in Biofuels Production GBTL Workshop Attendees

  14. Simulating Impacts of Disruptions to Liquid Fuels Infrastructure |

    Energy Savers [EERE]

    Department of Energy Simulating Impacts of Disruptions to Liquid Fuels Infrastructure Simulating Impacts of Disruptions to Liquid Fuels Infrastructure This report presents a methodology for estimating the impacts of events that damage or disrupt liquid fuels infrastructure. The impact of a disruption depends on which components of the infrastructure are damaged, the time required for repairs, and the position of the disrupted components in the fuels supply network. Impacts are estimated for

  15. Status and future opportunities for conversion of synthesis gas to liquid energy fuels: Final report

    SciTech Connect (OSTI)

    Mills, G. [Delaware Univ., Newark, DE (United States). Center for Catalytic Science and Technology

    1993-05-01

    The manufacture of liquid energy fuels from syngas (a mixture of H{sub 2} and CO, usually containing CO{sub 2}) is of growing importance and enormous potential because: (1) Abundant US supplies of coal, gas, and biomass can be used to provide the needed syngas. (2) The liquid fuels produced, oxygenates or hydrocarbons, can help lessen environmental pollution. Indeed, oxygenates are required to a significant extent by the Clean Air Act Amendments (CAAA) of 1990. (3) Such liquid synfuels make possible high engine efficiencies because they have high octane or cetane ratings. (4) There is new, significantly improved technology for converting syngas to liquid fuels and promising opportunities for further improvements. This is the subject of this report. The purpose of this report is to provide an account and evaluative assessment of advances in the technology for producing liquid energy fuels from syngas and to suggest opportunities for future research deemed promising for practical processes. Much of the improved technology for selective synthesis of desired fuels from syngas has resulted from advances in catalytic chemistry. However, novel process engineering has been particularly important recently, utilizing known catalysts in new configurations to create new catalytic processes. This report is an update of the 1988 study Catalysts for Fuels from Syngas: New Directions for Research (Mills 1988), which is included as Appendix A. Technology for manufacture of syngas is not part of this study. The manufacture of liquid synfuels is capital intensive. Thus, in evaluating advances in fuels technology, focus is on the potential for improved economics, particularly on lowering plant investment costs. A second important criteria is the potential for environmental benefits. The discussion is concerned with two types of hydrocarbon fuels and three types of oxygenate fuels that can be synthesized from syngas. Seven alternative reaction pathways are involved.

  16. Status and future opportunities for conversion of synthesis gas to liquid energy fuels: Final report

    SciTech Connect (OSTI)

    Mills, G. (Delaware Univ., Newark, DE (United States). Center for Catalytic Science and Technology)

    1993-05-01

    The manufacture of liquid energy fuels from syngas (a mixture of H[sub 2] and CO, usually containing CO[sub 2]) is of growing importance and enormous potential because: (1) Abundant US supplies of coal, gas, and biomass can be used to provide the needed syngas. (2) The liquid fuels produced, oxygenates or hydrocarbons, can help lessen environmental pollution. Indeed, oxygenates are required to a significant extent by the Clean Air Act Amendments (CAAA) of 1990. (3) Such liquid synfuels make possible high engine efficiencies because they have high octane or cetane ratings. (4) There is new, significantly improved technology for converting syngas to liquid fuels and promising opportunities for further improvements. This is the subject of this report. The purpose of this report is to provide an account and evaluative assessment of advances in the technology for producing liquid energy fuels from syngas and to suggest opportunities for future research deemed promising for practical processes. Much of the improved technology for selective synthesis of desired fuels from syngas has resulted from advances in catalytic chemistry. However, novel process engineering has been particularly important recently, utilizing known catalysts in new configurations to create new catalytic processes. This report is an update of the 1988 study Catalysts for Fuels from Syngas: New Directions for Research (Mills 1988), which is included as Appendix A. Technology for manufacture of syngas is not part of this study. The manufacture of liquid synfuels is capital intensive. Thus, in evaluating advances in fuels technology, focus is on the potential for improved economics, particularly on lowering plant investment costs. A second important criteria is the potential for environmental benefits. The discussion is concerned with two types of hydrocarbon fuels and three types of oxygenate fuels that can be synthesized from syngas. Seven alternative reaction pathways are involved.

  17. Alternative fuel comprised of sewage sludge and a liquid hydrocarbon fuel

    Office of Scientific and Technical Information (OSTI)

    oil (Patent) | SciTech Connect Alternative fuel comprised of sewage sludge and a liquid hydrocarbon fuel oil Citation Details In-Document Search Title: Alternative fuel comprised of sewage sludge and a liquid hydrocarbon fuel oil An improved fuel composition is provided comprising in minor proportion a non-dewatered sewage sludge and in major proportion an organic fuel comprised of a hydrocarbon fuel oil. A method is also provided for the incineration of sewage sludge comprised of providing

  18. Cellulosic Liquid Fuels Commercial Production Today | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cellulosic Liquid Fuels Commercial Production Today Cellulosic Liquid Fuels Commercial Production Today Keynote Success Story Robert Graham, Chairman and CEO, Ensyn Corporation PDF icon b13_graham_ensyn.pdf More Documents & Publications Advanced Cellulosic Biofuels Production of Renewable Fuels from Biomass by FCC Co-processing 2013 Peer Review Presentations-Integrated Biorefineries

  19. Device for measuring oxygen activity in liquid sodium

    DOE Patents [OSTI]

    Roy, P.; Young, R.S.

    1973-12-01

    A composite ceramic electrolyte in a configuration (such as a closed end tube or a plate) suitable to separate liquid sodium from a reference electrode with a high impedance voltmeter connected to measure EMF between the sodium and the reference electrode as a measure of oxygen activity in the sodium is described. The composite electrolyte consists of zirconiacalcia with a bonded layer of thoria-yttria. The device is used with a gaseous reference electrode on the zirconia-calcia side and liquid sodium on the thoria-yttria side of the electrolyte. (Official Gazette)

  20. First AEO2015 Liquid Fuels Markets Working Group Meeting

    U.S. Energy Information Administration (EIA) Indexed Site

    July 21, 2014 MEMORANDUM FOR: JOHN CONTI ASSISTANT ADMINISTRATOR FOR ENERGY ANALYSYS JOHN POWELL TEAM LEADER, LIQUID FUELS MARKET TEAM MICHAEL SCHAAL DIRECTOR, OFFICE OF ENERGY ANALYSIS FROM: LIQUID FUELS MARKET TEAM SUBJECT: First AEO2015 Liquid Fuels Markets Working Group Meeting Summary (presented on 07-17-2014) Attendees: (EIA) John Powell, Mindi Farber-DeAnda, Mike Cole, Adrian Geagla, Arup Mallik, David Manowitz, Vishakh Mantri, Beth May, Terry Yen, John Conti, Michael Schaal Bryan Just

  1. Liquid fuel molten salt reactors for thorium utilization (Journal Article)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Journal Article: Liquid fuel molten salt reactors for thorium utilization Citation Details In-Document Search This content will become publicly available on April 8, 2017 Title: Liquid fuel molten salt reactors for thorium utilization Molten salt reactors (MSRs) represent a class of reactors that use liquid salt, usually fluoride- or chloride-based, as either a coolant with a solid fuel (such as fluoride salt-cooled high temperature reactors) or as a combined coolant and

  2. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1: Availability of Feedstock and Technology Municipal solid waste (MSW) is a domestic energy resource with the ...

  3. Converting coal to liquid fuels. [US DOE

    SciTech Connect (OSTI)

    Not Available

    1983-07-01

    Liquid fuels play a vital role in the US economy. Oil represents about 40 percent of the energy consumed each year in this country. In many cases, it fills needs for which other energy forms cannot substitute efficiently or economically - in transportation, for example. Despite a current world-wide surplus of oil, conventional petroleum is a depletable resource. It inevitably will become harder and more expensive to extract. Already in the US, most of the cheap, easily reached oil has been found and extracted. Even under optimistic projections of new discoveries, domestic oil production, particularly in the lower 48 states, will most likely continue to drop. A future alternative to conventional petroleum could be liquid fuels made from coal. The technique is called coal liquefaction. From 1 to 3 barrels of oil can be made from each ton of coal. The basic technology is known; the major obstacles in the US have been the high costs of the synthetic oil and the risks of building large, multi-billion dollar first-of-a-kind plants. Yet, as natural petroleum becomes less plentiful and more expensive, oil made from abundant coal could someday become an increasingly important energy option. To prepare for that day, the US government is working with private industries and universities to establish a sound base of technical knowledge in coal liquefaction.

  4. Biomass gasification for liquid fuel production

    SciTech Connect (OSTI)

    Najser, Jan E-mail: vaclav.peer@vsb.cz; Peer, Václav E-mail: vaclav.peer@vsb.cz

    2014-08-06

    In our old fix-bed autothermal gasifier we tested wood chips and wood pellets. We make experiments for Czech company producing agro pellets - pellets made from agricultural waste and fastrenewable natural resources. We tested pellets from wheat and rice straw and hay. These materials can be very perspective, because they dońt compete with food production, they were formed in sufficient quantity and in the place of their treatment. New installation is composed of allothermal biomass fixed bed gasifier with conditioning and using produced syngas for Fischer - Tropsch synthesis. As a gasifying agent will be used steam. Gas purification will have two parts - separation of dust particles using a hot filter and dolomite reactor for decomposition of tars. In next steps, gas will be cooled, compressed and removed of sulphur and chlorine compounds and carbon dioxide. This syngas will be used for liquid fuel synthesis.

  5. Conversion of olefins to liquid motor fuels

    DOE Patents [OSTI]

    Rabo, Jule A.; Coughlin, Peter K.

    1988-01-01

    Linear and/or branched claim C.sub.2 to C.sub.12 olefins are converted to hydrocarbon mixtures suitable for use as liquid motor fuels by contact with a catalyst capable of ensuring the production of desirable products with only a relatively minor amount of heavy products boiling beyond the diesel oil range. The catalyst having desirable stability during continuous production operations, comprises a steam stabilized zeolite Y catalyst of hydrophobic character, desirably in aluminum-extracted form. The olefins such as propylene, may be diluted with inerts, such as paraffins or with water, the latter serving to moderate the acidity of the catalyst, or to further moderate the activity of the aluminum-extracted catalyst, so as to increase the effective life of the catalyst.

  6. Biological production of liquid fuels from biomass

    SciTech Connect (OSTI)

    1982-01-01

    A scheme for the production of liquid fuels from renewable resources such as poplar wood and lignocellulosic wastes from a refuse hydropulper was investigated. The particular scheme being studied involves the conversion of a cellulosic residue, resulting from a solvent delignified lignocellulosic feed, into either high concentration sugar syrups or into ethyl and/or butyl alcohol. The construction of a pilot apparatus for solvent delignifying 150 g samples of lignocellulosic feeds was completed. Also, an analysis method for characterizing the delignified product has been selected and tested. This is a method recommended in the Forage Fiber Handbook. Delignified samples are now being prepared and tested for their extent of delignification and susceptibility to enzyme hydrolysis. Work is continuing on characterizing the cellulase and cellobiase enzyme systems derived from the YX strain of Thermomonospora.

  7. Liquid Fuels and Natural Gas in the Americas

    Reports and Publications (EIA)

    2014-01-01

    The Energy Information Administration's (EIA) Liquid Fuels and Natural Gas in the Americas report, published today, is a Congressionally-requested study examining the energy trends and developments in the Americas over the past decade. The report focuses on liquid fuels and natural gasparticularly reserves and resources, production, consumption, trade, and investmentgiven their scale and significance to the region.

  8. Liquid Fuels and Natural Gas in the Americas

    Reports and Publications (EIA)

    2014-01-01

    The Energy Information Administration's (EIA) Liquid Fuels and Natural Gas in the Americas report, published today, is a Congressionally-requested study examining the energy trends and developments in the Americas over the past decade. The report focuses on liquid fuels and natural gas—particularly reserves and resources, production, consumption, trade, and investment—given their scale and significance to the region.

  9. Conversion of Mixed Oxygenates Generated from Synthesis Gas to Fuel Range Hydrocarbon

    SciTech Connect (OSTI)

    Ramasamy, Karthikeyan K.; Gerber, Mark A.; Lilga, Michael A.; Flake, Matthew D.

    2012-08-19

    The growing dependence in the U.S. on foreign crude oil supplies and increased concerns regarding greenhouse gas emission has generated considerable interest in research to develop renewable and environmentally friendly liquid hydrocarbon transportation fuels. One of the strategies for achieving this is to produce intermediate compounds such as alcohols and other simple oxygenates from biomass generated synthesis gas (mixture of carbon monoxide and hydrogen) and further convert them into liquid hydrocarbons. The focus of this research is to investigate the effects of mixed oxygenates intermediate product compositions on the conversion step to produce hydrocarbon liquids. A typical mixed oxygenate stream is expected to contain water (around 50%), alcohols, such as methanol and ethanol (around 35%), and smaller quantities of oxygenates such as acetaldehyde, acetic acid and ethyl acetate. However the ratio and the composition of the mixed oxygenate stream generated from synthesis gas vary significantly depending on the catalyst used and the process conditions. Zeolite catalyzed deoxygenation of methanol accompanied by chain growth is well understood under Methanol-to-Gasoline (MTG) like reaction conditions using an H-ZSM-5 zeolite as the catalyst6-8. Research has also been conducted to a limited extent in the past with higher alcohols, but not with other oxygenates present9-11. Also there has been little experimental investigation into mixtures containing substantial amounts of water. The latter is of particular interest because water separation from the hydrocarbon product would be less energy intensive than first removing it from the oxygenate intermediate stream prior to hydrocarbon synthesis, potentially reducing overall processing costs.

  10. Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping Citation Details In-Document Search Title: Recovery Act: Novel Oxygen Carriers for Coal-fueled Chemical Looping Chemical Looping Combustion (CLC) could totally negate the necessity of pure oxygen by using oxygen carriers for purification of CO{sub 2} stream during combustion. It splits the single fuel combustion reaction into two linked reactions using oxygen carriers. The two linked

  11. Liquid Fuels and Natural Gas in the Americas

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquid Fuels and Natural Gas in the Americas EIA Conference July 14, 2014 | Washington, DC Liquid fuels production in the Americas surpassed the Middle East in 2013 liquid fuels production by region million barrels per day Source: EIA, International Energy Statistics 2 0 5 10 15 20 25 30 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 Americas Middle East Former Soviet Union Africa Asia and Oceania Europe EIA Conference July 14, 2014 The Americas are the second largest region in oil reserves

  12. International Energy Outlook 2016-Petroleum and other liquid fuels - Energy

    Gasoline and Diesel Fuel Update (EIA)

    Information Administration 2. Petroleum and other liquid fuels Overview In the International Energy Outlook 2016 (IEO2016) Reference case, worldwide consumption of petroleum and other liquid fuels increases from 90 million barrels per day (b/d) in 2012 to 100 million b/d in 2020 and 121 million b/d in 2040. Much of the growth in world liquid fuels consumption is projected for the emerging, non-Organization for Economic Cooperation and Development (non-OECD) economies of Asia, the Middle

  13. Liquid Fuels via Upgrading of Syngas Intermediates Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    11.2.13 Liquid Fuels via Upgrading of Syngas Intermediates March 26 th , 2015 Indirect Liquefaction Technology Area Review Robert A. Dagle, Karthi Ramasamy, Michel J. Gray Pacific ...

  14. Liquid Fuels via Uprading of Syngas Intermediates Presentation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2015 Project Peer Review March 26, 2015 Liquid Fuels via Upgrading of Syngas Intermediates 2.3.1.3052.3.1.306 Jesse Hensley - NREL Ted Krause - ANL This presentation does not ...

  15. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A Techno-economic ... Municipal solid waste (MSW) on the other hand is readily available in large quantities in ...

  16. Liquid Fuel Molten Salt Reactors For Thorium Utilization (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Liquid Fuel Molten Salt Reactors For Thorium Utilization Citation Details In-Document Search Title: Liquid Fuel Molten Salt Reactors For Thorium Utilization Authors: Gehin, Jess C [1] + Show Author Affiliations ORNL Publication Date: 2014-01-01 OSTI Identifier: 1185589 DOE Contract Number: AC05-00OR22725 Resource Type: Conference Resource Relation: Conference: 2014 ANS Winter Meeting and Nuclear Technology Expo, Anaheim, CA, USA, 20141109, 20141113 Research Org: Oak Ridge

  17. NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE FOR ALTERNATIVE LIQUID FUELS.

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE FOR ALTERNATIVE LIQUID FUELS. Citation Details In-Document Search Title: NUCLEAR HYDROGEN AND CAPTURED CARBON DIOXIDE FOR ALTERNATIVE LIQUID FUELS. Abstract not provided. Authors: Middleton, Bobby ; Kazimi, Mujid ; Leung, MinWah Publication Date: 2008-03-01 OSTI Identifier: 1145909 Report Number(s): SAND2008-1979J 518805 DOE Contract Number: DE-AC04-94AL85000 Resource Type: Journal Article

  18. Nuclear Hydrogen and Captured Carbon Dioxide for Alternative Liquid Fuels.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Nuclear Hydrogen and Captured Carbon Dioxide for Alternative Liquid Fuels. Citation Details In-Document Search Title: Nuclear Hydrogen and Captured Carbon Dioxide for Alternative Liquid Fuels. Abstract not provided. Authors: Middleton, Bobby ; Kazimi, Mujid Publication Date: 2007-06-01 OSTI Identifier: 1147847 Report Number(s): SAND2007-3553C 522735 DOE Contract Number: DE-AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: ANS

  19. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1:

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Availability of Feedstock and Technology | Department of Energy 1: Availability of Feedstock and Technology Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1: Availability of Feedstock and Technology Municipal solid waste (MSW) is a domestic energy resource with the potential to provide a significant amount of energy to meet US liquid fuel requirements. MSW is defined as household waste, commercial solid waste, nonhazardous sludge, conditionally exempt, small quantity hazardous

  20. Enhanced catalyst for conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, P.K.; Rabo, J.A.

    1985-12-03

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C[sub 5][sup +] hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising a SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

  1. Enhanced conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K.; Rabo, Jule A.

    1986-01-01

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

  2. Enhanced catalyst for conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K.; Rabo, Jule A.

    1985-01-01

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst system capable of enhancing the selectivity of said conversion to motor fuel range hydrocarbons and the quality of the resulting motor fuel product. The catalyst composition employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component comprising SAPO silicoaluminophosphate, non-zeolitic molecular sieve catalyst.

  3. Alternative Liquid Fuels Simulation Model (AltSim).

    SciTech Connect (OSTI)

    Baker, Arnold Barry; Williams, Ryan; Drennen, Thomas E.; Klotz, Richard

    2007-10-01

    The Alternative Liquid Fuels Simulation Model (AltSim) is a high-level dynamic simulation model which calculates and compares the production costs, carbon dioxide emissions, and energy balances of several alternative liquid transportation fuels. These fuels include: corn ethanol, cellulosic ethanol, biodiesel, and diesels derived from natural gas (gas to liquid, or GTL) and coal (coal to liquid, or CTL). AltSim allows for comprehensive sensitivity analyses on capital costs, operation and maintenance costs, renewable and fossil fuel feedstock costs, feedstock conversion efficiency, financial assumptions, tax credits, CO{sub 2} taxes, and plant capacity factor. This paper summarizes the preliminary results from the model. For the base cases, CTL and cellulosic ethanol are the least cost fuel options, at $1.60 and $1.71 per gallon, respectively. Base case assumptions do not include tax or other credits. This compares to a $2.35/gallon production cost of gasoline at September, 2007 crude oil prices ($80.57/barrel). On an energy content basis, the CTL is the low cost alternative, at $12.90/MMBtu, compared to $22.47/MMBtu for cellulosic ethanol. In terms of carbon dioxide emissions, a typical vehicle fueled with cellulosic ethanol will release 0.48 tons CO{sub 2} per year, compared to 13.23 tons per year for coal to liquid.

  4. Cold-Start and Warm-Up Driveability Performance of Hybrid Electric Vehicles Using Oxygenated Fuels

    SciTech Connect (OSTI)

    Thornton, M.; Jorgensen, S.; Evans, B.; Wright, K.

    2003-11-01

    Provides analysis and results of the driveability performance testing from four hybrid electric vehicles--Honda Civic, Toyota Prius, and two Honda Insights--that used oxygenated fuels.

  5. Radiation chemistry of alternative fuel oxygenates -- Substituted ethers

    SciTech Connect (OSTI)

    Mezyk, S. P.; Cooper, W. J.; Bartels, D. M.; Tobien, T.; O'Shea, K. E.

    1999-11-15

    The electron beam process, an advanced oxidation and reduction technology, is based in the field of radiation chemistry. Fundamental to the development of treatment processes is an understanding of the underlying chemistry. The authors have previously evaluated the bimolecular rate constants for the reactions of methyl tert-butyl ether (MTBE) and with this study have extended their studies to include ethyl tert-butyl ether (ETBE), di-isopropyl ether (DIPE) and tert-amyl methyl ether (TAME) with the hydroxyl radical, hydrogen atom and solvated electron using pulse radiolysis. For all of the oxygenates the reaction with the hydroxyl radical appears to be of primary interest in the destruction of the compounds in water. The rates with the solvated electron are limiting values as the rates appear to be relatively low. The hydrogen atom rate constants are relatively low, coupled with the low yield in radiolysis, they concluded that these are of little significance in the destruction of the alternative fuel oxygenates (and MTBE).

  6. Simulating Impacts of Disruptions to Liquid Fuels Infrastructure

    SciTech Connect (OSTI)

    Wilson, Michael; Corbet, Thomas F.; Baker, Arnold B.; O'Rourke, Julia M.

    2015-04-01

    This report presents a methodology for estimating the impacts of events that damage or disrupt liquid fuels infrastructure. The impact of a disruption depends on which components of the infrastructure are damaged, the time required for repairs, and the position of the disrupted components in the fuels supply network. Impacts are estimated for seven stressing events in regions of the United States, which were selected to represent a range of disruption types. For most of these events the analysis is carried out using the National Transportation Fuels Model (NTFM) to simulate the system-level liquid fuels sector response. Results are presented for each event, and a brief cross comparison of event simulation results is provided.

  7. Process of producing liquid hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Kuester, J.L.

    1987-07-07

    A continuous thermochemical indirect liquefaction process is described to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C[sub 7]-C[sub 17] paraffinic hydrocarbons having cetane indices of 50+. 1 fig.

  8. Process of producing liquid hydrocarbon fuels from biomass

    DOE Patents [OSTI]

    Kuester, James L.

    1987-07-07

    A continuous thermochemical indirect liquefaction process to convert various biomass materials into diesel-type transportation fuels which fuels are compatible with current engine designs and distribution systems comprising feeding said biomass into a circulating solid fluidized bed gasification system to produce a synthesis gas containing olefins, hydrogen and carbon monoxide and thereafter introducing the synthesis gas into a catalytic liquefaction system to convert the synthesis gas into liquid hydrocarbon fuel consisting essentially of C.sub.7 -C.sub.17 paraffinic hydrocarbons having cetane indices of 50+.

  9. A Life-Cycle Assessment Comparing Select Gas-to-Liquid Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shell Gas to Liquids in the context of a Future Fuel Strategy - Technical Marketing Aspects Verification of Shell GTL Fuel as CARB Alternative Diesel Assessment of Environmental ...

  10. Enabling Small-Scale Biomass Gasification for Liquid Fuel Production

    Broader source: Energy.gov [DOE]

    Breakout Session 2A—Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing Enabling Small-Scale Biomass Gasification for Liquid Fuel Production Santosh Gangwal, Director–Business Development, Energy Technologies, Southern Research Institute

  11. A fresh look at coal-derived liquid fuels

    SciTech Connect (OSTI)

    Paul, A.D.

    2009-01-15

    35% of the world's energy comes from oil, and 96% of that oil is used for transportation. The current number of vehicles globally is estimated to be 700 million; that number is expected to double overall by 2030, and to triple in developing countries. Now consider that the US has 27% of the world's supply of coal yet only 2% of the oil. Coal-to-liquids technologies could bridge the gap between US fuel supply and demand. The advantages of coal-derived liquid fuels are discussed in this article compared to the challenges of alternative feedstocks of oil sands, oil shale and renewable sources. It is argued that pollutant emissions from coal-to-liquid facilities could be minimal because sulfur compounds will be removed, contaminants need to be removed for the FT process, and technologies are available for removing solid wastes and nitrogen oxides. If CO{sub 2} emissions for coal-derived liquid plants are captured and sequestered, overall emissions of CO{sub 2} would be equal or less than those from petroleum. Although coal liquefaction requires large volumes of water, most water used can be recycled. Converting coal to liquid fuels could, at least in the near term, bring a higher level of stability to world oil prices and the global economy and could serve as insurance for the US against price hikes from oil-producing countries. 7 figs.

  12. Electrolyte creepage barrier for liquid electrolyte fuel cells

    DOE Patents [OSTI]

    Li, Jian (Alberta, CA); Farooque, Mohammad (Danbury, CT); Yuh, Chao-Yi (New Milford, CT)

    2008-01-22

    A dielectric assembly for electrically insulating a manifold or other component from a liquid electrolyte fuel cell stack wherein the dielectric assembly includes a substantially impermeable dielectric member over which electrolyte is able to flow and a barrier adjacent the dielectric member and having a porosity of less than 50% and greater than 10% so that the barrier is able to measurably absorb and chemically react with the liquid electrolyte flowing on the dielectric member to form solid products which are stable in the liquid electrolyte. In this way, the barrier inhibits flow or creepage of electrolyte from the dielectric member to the manifold or component to be electrically insulated from the fuel cell stack by the dielectric assembly.

  13. EIS-0432: Medicine Bow Fuel & Power Coal-to-Liquid Facility in...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, WY EIS-0432: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, WY Documents Available for ...

  14. Biomass and Coal into Liquid Fuel with CO2 Capture - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search Biomass and Coal into Liquid Fuel with CO2 Capture New Single-step hydrolysis process co-converts coal and any biomass to liquid fuel Savannah ...

  15. Shell Gas to Liquids in the context of a Future Fuel Strategy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Shell Gas to Liquids in the context of a Future Fuel Strategy - Technical Marketing Aspects Shell Gas to Liquids in the context of a Future Fuel Strategy - Technical Marketing ...

  16. Annular core liquid-salt cooled reactor with multiple fuel and...

    Office of Scientific and Technical Information (OSTI)

    Annular core liquid-salt cooled reactor with multiple fuel and blanket zones Citation Details In-Document Search Title: Annular core liquid-salt cooled reactor with multiple fuel ...

  17. Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels This factsheet describes a project that developed fuel-flexible, low-emissions burner technology capable of using biomass-derived liquid fuels, such as glycerin or fatty acids, as a substitute for natural gas. PDF icon low-emissions_burner_technology_factsheet.pdf More Documents & Publications Fuel-Flexible, Low-Emissions Catalytic

  18. A Life-Cycle Assessment Comparing Select Gas-to-Liquid Fuels with

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conventional Fuels in the Transportation Sector | Department of Energy A Life-Cycle Assessment Comparing Select Gas-to-Liquid Fuels with Conventional Fuels in the Transportation Sector A Life-Cycle Assessment Comparing Select Gas-to-Liquid Fuels with Conventional Fuels in the Transportation Sector 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: ConocoPhillips and Nexant Corporatin PDF icon 2004_deer_abbott.pdf More Documents & Publications Shell Gas to Liquids in

  19. LIQUID BIO-FUEL PRODUCTION FROM NON-FOOD BIOMASS VIA HIGH TEMPERATURE STEAM ELECTROLYSIS

    SciTech Connect (OSTI)

    G. L. Hawkes; J. E. O'Brien; M. G. McKellar

    2011-11-01

    Bio-Syntrolysis is a hybrid energy process that enables production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), bio-syntrolysis has the potential to provide a significant alternative petroleum source that could reduce US dependence on imported oil. Combining hydrogen from HTSE with CO from an oxygen-blown biomass gasifier yields syngas to be used as a feedstock for synthesis of liquid transportation fuels via a Fischer-Tropsch process. Conversion of syngas to liquid hydrocarbon fuels, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

  20. Enzymantic Conversion of Coal to Liquid Fuels

    SciTech Connect (OSTI)

    Richard Troiano

    2011-01-31

    The work in this project focused on the conversion of bituminous coal to liquid hydrocarbons. The major steps in this process include mechanical pretreatment, chemical pretreatment, and finally solubilization and conversion of coal to liquid hydrocarbons. Two different types of mechanical pretreatment were considered for the process: hammer mill grinding and jet mill grinding. After research and experimentation, it was decided to use jet mill grinding, which allows for coal to be ground down to particle sizes of 5 {mu}m or less. A Fluid Energy Model 0101 JET-O-MIZER-630 size reduction mill was purchased for this purpose. This machine was completed and final testing was performed on the machine at the Fluid Energy facilities in Telford, PA. The test results from the machine show that it can indeed perform to the required specifications and is able to grind coal down to a mean particle size that is ideal for experimentation. Solubilization and conversion experiments were performed on various pretreated coal samples using 3 different approaches: (1) enzymatic - using extracellular Laccase and Manganese Peroxidase (MnP), (2) chemical - using Ammonium Tartrate and Manganese Peroxidase, and (3) enzymatic - using the live organisms Phanerochaete chrysosporium. Spectral analysis was used to determine how effective each of these methods were in decomposing bituminous coal. After analysis of the results and other considerations, such as cost and environmental impacts, it was determined that the enzymatic approaches, as opposed to the chemical approaches using chelators, were more effective in decomposing coal. The results from the laccase/MnP experiments and Phanerochaete chrysosporium experiments are presented and compared in this final report. Spectra from both enzymatic methods show absorption peaks in the 240nm to 300nm region. These peaks correspond to aromatic intermediates formed when breaking down the coal structure. The peaks then decrease in absorbance over time, corresponding to the consumption of aromatic intermediates as they undergo ring cleavage. The results show that this process happens within 1 hour when using extracellular enzymes, but takes several days when using live organisms. In addition, live organisms require specific culture conditions, control of contaminants and fungicides in order to effectively produce extracellular enzymes that degrade coal. Therefore, when comparing the two enzymatic methods, results show that the process of using extracellular lignin degrading enzymes, such as laccase and manganese peroxidase, appears to be a more efficient method of decomposing bituminous coal.

  1. Simulation studies of diesel engine performance with oxygen enriched air and water emulsified fuels

    SciTech Connect (OSTI)

    Assanis, D.N.; Baker, D. ); Sekar, R.R.; Siambekos, C.T.; Cole, R.L.; Marciniak, T.J. )

    1990-01-01

    A computer simulation code of a turbocharged, turbocompound diesel engine was modified to study the effects of using oxygen-enriched combustion air and water-emulsified diesel fuels. Oxygen levels of 21 percent to 40 percent by volume in the combustion air were studied. Water content in the fuel was varied from 0 percent to 50 percent mass. Simulation studies and a review and analysis of previous work in this area led to the following conclusions about expected engine performance and emissions: the power density of the engine is significantly increased by oxygen enrichment. Ignition delay and particulate emissions are reduced. Combustion temperatures and No{sub x} emissions are increased with oxygen enrichment but could be brought back to the base levels by introducing water in the fuel. The peak cylinder pressure which increases with the power output level might result in mechanical problems with engine components. Oxygen enrichment also provides an opportunity to use cheaper fuel such as No. 6 diesel fuel. Overall, the adverse effects of oxygen enrichment could be countered by the addition of water and it appears that an optimum combination of water content, oxygen level, and base diesel fuel quality may exist. This could yield improved performance and emissions characteristics compared to a state-of-the-art diesel engine. 9 refs., 8 figs.

  2. Enhanced catalyst for converting synthesis gas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K.

    1986-01-01

    The conversion of synthesis gas to liquid molar fuels by means of a cobalt Fischer-Tropsch catalyst composition is enhanced by the addition of molybdenum, tungsten or a combination thereof as an additional component of said composition. The presence of the additive component increases the olefinic content of the hydrocarbon products produced. The catalyst composition can advantageously include a support component, such as a molecular sieve, co-catalyst/support component or a combination of such support components.

  3. Catalyst for converting synthesis gas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K.

    1986-01-01

    The addition of an inert metal component, such as gold, silver or copper, to a Fischer-Tropsch catalyst comprising cobalt enables said catalyst to convert synthesis gas to liquid motor fuels at about 240.degree.-370.degree. C. with advantageously reduced selectivity of said cobalt for methane in said conversion. The catalyst composition can advantageously include a support component, such as a molecular sieve, co-catalyst/support component or a combination of such support components.

  4. Producing liquid fuels from coal: prospects and policy issues

    SciTech Connect (OSTI)

    James T. Bartis; Frank Camm; David S. Ortiz

    2008-07-01

    The increase in world oil prices since 2003 has prompted renewed interest in producing and using liquid fuels from unconventional resources, such as biomass, oil shale, and coal. This book focuses on issues and options associated with establishing a commercial coal-to-liquids (CTL) industry within the United States. It describes the technical status, costs, and performance of methods that are available for producing liquids from coal; the key energy and environmental policy issues associated with CTL development; the impediments to early commercial experience; and the efficacy of alternative federal incentives in promoting early commercial experience. Because coal is not the only near-term option for meeting liquid-fuel needs, this book also briefly reviews the benefits and limitations of other approaches, including the development of oil shale resources, the further development of biomass resources, and increasing dependence on imported petroleum. A companion document provides a detailed description of incentive packages that the federal government could offer to encourage private-sector investors to pursue early CTL production experience while reducing the probability of bad outcomes and limiting the costs that might be required to motivate those investors. (See Rand Technical Report TR586, Camm, Bartis, and Bushman, 2008.) 114 refs., 2 figs., 16 tabs., 3 apps.

  5. NREL Research on Converting Biomass to Liquid Fuels

    ScienceCinema (OSTI)

    None

    2013-05-29

    Unlike other renewable energy sources, biomass can be converted directly into liquid fuels, called "biofuels," to help meet transportation fuel needs. The two most common types of biofuels are ethanol and biodiesel. Today, ethanol is made from starches and sugars, but at the National Renewable Energy Laboratory (NREL) scientists are developing technology to allow it to be made from cellulose and hemicellulose, the fibrous material that makes up the bulk of most plant matter. Biodiesel is made by combining alcohol (usually methanol) with vegetable oil, animal fat, or recycled cooking grease. It can be used as an additive (typically 20%) to reduce vehicle emissions or in its pure form as a renewable alternative fuel for diesel engines. For a text version of this video visit http://www.nrel.gov/learning/re_biofuels.html

  6. Gas-to-liquids synthetic fuels for use in fuel cells : reformability, energy density, and infrastructure compatibility.

    SciTech Connect (OSTI)

    Ahmed, S.; Kopasz, J. P.; Russell, B. J.; Tomlinson, H. L.

    1999-09-08

    The fuel cell has many potential applications, from power sources for electric hybrid vehicles to small power plants for commercial buildings. The choice of fuel will be critical to the pace of its commercialization. This paper reviews the various liquid fuels being considered as an alternative to direct hydrogen gas for the fuel cell application, presents calculations of the hydrogen and carbon dioxide yields from autothermal reforming of candidate liquid fuels, and reports the product gas composition measured from the autothermal reforming of a synthetic fuel in a micro-reactor. The hydrogen yield for a synthetic paraffin fuel produced by a cobalt-based Fischer-Tropsch process was found to be similar to that of retail gasoline. The advantages of the synthetic fuel are that it contains no contaminants that would poison the fuel cell catalyst, is relatively benign to the environment, and could be transported in the existing fuel distribution system.

  7. Superheated fuel injection for combustion of liquid-solid slurries

    DOE Patents [OSTI]

    Robben, F.A.

    1984-10-19

    A method and device are claimed for obtaining, upon injection, flash evaporation of a liquid in a slurry fuel to aid in ignition and combustion. The device is particularly beneficial for use of coal-water slurry fuels in internal combustion engines such as diesel engines and gas turbines, and in external combustion devices such as boilers and furnaces. The slurry fuel is heated under pressure to near critical temperature in an injector accumulator, where the pressure is sufficiently high to prevent boiling. After injection into a combustion chamber, the water temperature will be well above boiling point at a reduced pressure in the combustion chamber, and flash boiling will preferentially take place at solid-liquid surfaces, resulting in the shattering of water droplets and the subsequent separation of the water from coal particles. This prevents the agglomeration of the coal particles during the subsequent ignition and combustion process, and reduces the energy required to evaporate the water and to heat the coal particles to ignition temperature. The overall effect will be to accelerate the ignition and combustion rates, and to reduce the size of the ash particles formed from the coal. 2 figs., 2 tabs.

  8. Superheated fuel injection for combustion of liquid-solid slurries

    DOE Patents [OSTI]

    Robben, Franklin A.

    1985-01-01

    A method and device for obtaining, upon injection, flash evaporation of a liquid in a slurry fuel to aid in ignition and combustion. The device is particularly beneficial for use of coal-water slurry fuels in internal combustion engines such as diesel engines and gas turbines, and in external combustion devices such as boilers and furnaces. The slurry fuel is heated under pressure to near critical temperature in an injector accumulator, where the pressure is sufficiently high to prevent boiling. After injection into a combustion chamber, the water temperature will be well above boiling point at a reduced pressure in the combustion chamber, and flash boiling will preferentially take place at solid-liquid surfaces, resulting in the shattering of water droplets and the subsequent separation of the water from coal particles. This prevents the agglomeration of the coal particles during the subsequent ignition and combustion process, and reduces the energy required to evaporate the water and to heat the coal particles to ignition temperature. The overall effect will be to accelerate the ignition and combustion rates, and to reduce the size of the ash particles formed from the coal.

  9. No loss fueling station for liquid natural gas vehicles

    SciTech Connect (OSTI)

    Cieslukowski, R.E.

    1992-06-16

    This patent describes a no loss fueling station for delivery of liquid natural gas (LNG) to a use device such as a motor vehicle. It comprises: a pressure building tank holding a quantity of LNG and gas head; means for delivering LNG to the pressure building tank; means for selectively building the pressure in the pressure building tank; means for selectively reducing the pressure in the pressure building tank; means for controlling the pressure building and pressure reducing means to maintain a desired pressure in the pressure building tank without venting natural gas to the atmosphere; and means for delivering the LNG from the pressure building tank to the use device.

  10. Catalysts for conversion of syngas to liquid motor fuels

    DOE Patents [OSTI]

    Rabo, Jule A.; Coughlin, Peter K.

    1987-01-01

    Synthesis gas comprising carbon monoxide and hydrogen is converted to C.sub.5.sup.+ hydrocarbons suitable for use as liquid motor fuels by contact with a dual catalyst composition capable of ensuring the production of only relatively minor amounts of heavy products boiling beyond the diesel oil range. The catalyst composition, having desirable stability during continuous production operation, employs a Fischer-Tropsch catalyst, together with a co-catalyst/support component. The latter component is a steam-stabilized zeolite Y catalyst of hydrophobic character, desirably in acid-extracted form.

  11. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, Mark R. (Chesterton, IN)

    1994-01-01

    A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

  12. Fuel and oxygen addition for metal smelting or refining process

    DOE Patents [OSTI]

    Schlichting, M.R.

    1994-11-22

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figs.

  13. Second AEO2-015 Liquid Fuels Markets Working Group Meeting Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    September 24, 2014 MEMORANDUM FOR: JOHN CONTI ASSISTANT ADMINISTRATOR FOR ENERGY ANALYSYS MICHAEL SCHAAL DIRECTOR, OFFICE OF ENERGY ANALYSIS JOHN POWELL TEAM LEADER, LIQUID FUELS MARKET TEAM FROM: LIQUID FUELS MARKET TEAM SUBJECT: Second AEO2015 Liquid Fuels Markets Working Group Meeting Summary (presented on 09-24-2014) Attendees: (EIA) John Powell, Mindi Farber-DeAnda, Mike Cole, Adrian Geagla, David Manowitz, Beth May Seth Meyer (USDA) Austin Brown (NREL) Robert Smith (US DOE) Ben Salisbury

  14. Energy and materials flows in the production of liquid and gaseous oxygen

    SciTech Connect (OSTI)

    Shen, S.; Wolsky, A.M.

    1980-08-01

    Liquid and gaseous oxygen is produced in an energy-intensive air separation processo that also generates nitrogen. More than 65% of the cost of oxygen is attributable to energy costs. Energy use and materials flows are analyzed for various air separation methods. Effective approaches to energy and material conservation in air separation plants include efficient removal of contaminants (carbon dioxide and water), centralization of air products user-industries so that large air separation plants are cost-effective and the energy use in transportation is minimized, and increased production of nitrogen. Air separation plants can produce more than three times more nitrogen than oxygen, but present markets demand, at most, only 1.5 times more. Full utlization of liquid and gaseous nitrogen should be encouraged, so that the wasted separation energy is minimized. There are potential markets for nitrogen in, for example, cryogenic separation of metallic and plastic wastes, cryogenic particle size reduction, and production of ammonia for fertilizer.

  15. Alternative Liquid Fuels Simulation Model (AltSim).

    SciTech Connect (OSTI)

    Williams, Ryan; Baker, Arnold Barry; Drennen, Thomas E.

    2009-12-01

    The Alternative Liquid Fuels Simulation Model (AltSim) is a high-level dynamic simulation model which calculates and compares the production and end use costs, greenhouse gas emissions, and energy balances of several alternative liquid transportation fuels. These fuels include: corn ethanol, cellulosic ethanol from various feedstocks (switchgrass, corn stover, forest residue, and farmed trees), biodiesel, and diesels derived from natural gas (gas to liquid, or GTL), coal (coal to liquid, or CTL), and coal with biomass (CBTL). AltSim allows for comprehensive sensitivity analyses on capital costs, operation and maintenance costs, renewable and fossil fuel feedstock costs, feedstock conversion ratio, financial assumptions, tax credits, CO{sub 2} taxes, and plant capacity factor. This paper summarizes the structure and methodology of AltSim, presents results, and provides a detailed sensitivity analysis. The Energy Independence and Security Act (EISA) of 2007 sets a goal for the increased use of biofuels in the U.S., ultimately reaching 36 billion gallons by 2022. AltSim's base case assumes EPA projected feedstock costs in 2022 (EPA, 2009). For the base case assumptions, AltSim estimates per gallon production costs for the five ethanol feedstocks (corn, switchgrass, corn stover, forest residue, and farmed trees) of $1.86, $2.32, $2.45, $1.52, and $1.91, respectively. The projected production cost of biodiesel is $1.81/gallon. The estimates for CTL without biomass range from $1.36 to $2.22. With biomass, the estimated costs increase, ranging from $2.19 per gallon for the CTL option with 8% biomass to $2.79 per gallon for the CTL option with 30% biomass and carbon capture and sequestration. AltSim compares the greenhouse gas emissions (GHG) associated with both the production and consumption of the various fuels. EISA allows fuels emitting 20% less greenhouse gases (GHG) than conventional gasoline and diesels to qualify as renewable fuels. This allows several of the CBTL options to be included under the EISA mandate. The estimated GHG emissions associated with the production of gasoline and diesel are 19.80 and 18.40 kg of CO{sub 2} equivalent per MMBtu (kgCO{sub 2}e/MMBtu), respectively (NETL, 2008). The estimated emissions are significantly higher for several alternatives: ethanol from corn (70.6), GTL (51.9), and CTL without biomass or sequestration (123-161). Projected emissions for several other alternatives are lower; integrating biomass and sequestration in the CTL processes can even result in negative net emissions. For example, CTL with 30% biomass and 91.5% sequestration has estimated production emissions of -38 kgCO{sub 2}e/MMBtu. AltSim also estimates the projected well-to-wheel, or lifecycle, emissions from consuming each of the various fuels. Vehicles fueled with conventional diesel or gasoline and driven 12,500 miles per year emit 5.72-5.93 tons of CO{sub 2} equivalents per year (tCO{sub 2}e/yr). Those emissions are significantly higher for vehicles fueled with 100% ethanol from corn (8.03 tCO{sub 2}e/yr) or diesel from CTL without sequestration (10.86 to 12.85 tCO{sub 2}/yr). Emissions could be significantly lower for vehicles fueled with diesel from CBTL with various shares of biomass. For example, for CTL with 30% biomass and carbon sequestration, emissions would be 2.21 tCO{sub 2}e per year, or just 39% of the emissions for a vehicle fueled with conventional diesel. While the results presented above provide very specific estimates for each option, AltSim's true potential is as a tool for educating policy makers and for exploring 'what if?' type questions. For example, AltSim allows one to consider the affect of various levels of carbon taxes on the production cost estimates, as well as increased costs to the end user on an annual basis. Other sections of AltSim allow the user to understand the implications of various polices in terms of costs to the government or land use requirements. AltSim's structure allows the end user to explore each of these alternatives and understand the sensitivities implications a

  16. Bioconversion of natural gas to liquid fuel: Opportunities and challenges

    SciTech Connect (OSTI)

    Fei, Q; Guarnieri, MT; Tao, L; Laurens, LML; Dowe, N; Pienkos, PT

    2014-05-01

    Natural gas is a mixture of low molecular weight hydrocarbon gases that can be generated from either fossil or anthropogenic resources. Although natural gas is used as a transportation fuel, constraints in storage, relatively low energy content (MJ/L), and delivery have limited widespread adoption. Advanced utilization of natural gas has been explored for biofuel production by microorganisms. In recent years, the aerobic bioconversion of natural gas (or primarily the methane content of natural gas) into liquid fuels (Bio-GTL) by biocatalysts (methanotrophs) has gained increasing attention as a promising alternative for drop-in biofuel production. Methanotrophic bacteria are capable of converting methane into microbial lipids, which can in turn be converted into renewable diesel via a hydrotreating process. In this paper, biodiversity, catalytic properties and key enzymes and pathways of these microbes are summarized. Bioprocess technologies are discussed based upon existing literature, including cultivation conditions, fermentation modes, bioreactor design, and lipid extraction and upgrading. This review also outlines the potential of Bio-GTL using methane as an alternative carbon source as well as the major challenges and future research needs of microbial lipid accumulation derived from methane, key performance index, and techno-economic analysis. An analysis of raw material costs suggests that methane-derived diesel fuel has the potential to be competitive with petroleum-derived diesel. (C) 2014 The Authors. Published by Elsevier Inc.

  17. Method and system for low-NO.sub.x dual-fuel combustion of liquid and/or gaseous fuels

    DOE Patents [OSTI]

    Gard, Vincent; Chojnacki, Dennis A; Rabovitser, Ioseph K

    2014-12-02

    A method and apparatus for combustion in which a pressurized preheated liquid fuel is atomized and a portion thereof flash vaporized, creating a mixture of fuel vapor and liquid droplets. The mixture is mixed with primary combustion oxidant, producing a fuel/primary oxidant mixture which is then injected into a primary combustion chamber in which the fuel/primary oxidant mixture is partially combusted, producing a secondary gaseous fuel containing hydrogen and carbon oxides. The secondary gaseous fuel is mixed with a secondary combustion oxidant and injected into the second combustion chamber wherein complete combustion of the secondary gaseous fuel is carried out. The resulting second stage flue gas containing very low amounts of NO.sub.x is then vented from the second combustion chamber.

  18. Bioconversion of animal manure into electricity and a liquid fuel

    SciTech Connect (OSTI)

    Fischer, J.R.; Iannotti, E.L.; Stahl, T.; Garcia, A. III; Harris, F.D.

    1983-01-01

    The integrated farm energy system operating at Columbia, Missouri converted animal manure into thermal and electrical energy and a liquid fuel. An anaerobic digester converted 510 kg of volatile solids into 285 m/sup 3/ of biogas consisting of 55% methane. An internal combustion engine coupled to an electrical generator produced 408 kWh/day of electricity and 3 GJ/day of thermal energy. An ethanol production plant converted thermal and electrical energy into 85 liters of ethanol. Subtracting the thermal and electrical demands of the digester and ethanol plant, the system produced a net energy of 277 kWh of electricity, 750 MJ of thermal energy and 85 liters of ethanol. 9 references, 6 figures, 2 tables.

  19. Low-Emissions Burner Technology using Biomass-Derived Liquid Fuels

    SciTech Connect (OSTI)

    2010-07-01

    The University of Alabama will develop fuel-flexible, low-emissions burner technology for the metal processing industry that is capable of using biomass-derived liquid fuels, such as glycerin or fatty acids, as a substitute for natural gas. By replacing a fossil fuel with biomass fuels, this new burner will enable a reduction in energy consumption and greenhouse gas emissions and an increase in fuel flexibility.

  20. Corrosion-resistant fuel cladding allow for liquid metal fast breeder reactors

    DOE Patents [OSTI]

    Brehm, Jr., William F.; Colburn, Richard P.

    1982-01-01

    An aluminide coating for a fuel cladding tube for LMFBRs (liquid metal fast breeder reactors) such as those using liquid sodium as a heat transfer agent. The coating comprises a mixture of nickel-aluminum intermetallic phases and presents good corrosion resistance to liquid sodium at temperatures up to 700.degree. C. while additionally presenting a barrier to outward diffusion of .sup.54 Mn.

  1. LIQUID NATURAL GAS (LNG): AN ALTERNATIVE FUEL FROM LANDFILL GAS (LFG) AND WASTEWATER DIGESTER GAS

    SciTech Connect (OSTI)

    VANDOR,D.

    1999-03-01

    This Research and Development Subcontract sought to find economic, technical and policy links between methane recovery at landfill and wastewater treatment sites in New York and Maryland, and ways to use that methane as an alternative fuel--compressed natural gas (CNG) or liquid natural gas (LNG) -- in centrally fueled Alternative Fueled Vehicles (AFVs).

  2. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2006-03-30

    Professors and graduate students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and hydrocarbon gases and liquids produced from coal. An Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center, and Tier Associates provides guidance on the practicality of the research. The current report summarizes the results obtained in this program during the period October 1, 2002 through March 31, 2006. The results are presented in detailed reports on 16 research projects headed by professors at each of the five CFFS Universities and an Executive Summary. Some of the highlights from these results are: (1) Small ({approx}1%) additions of acetylene or other alkynes to the Fischer-Tropsch (F-T) reaction increases its yield, causes chain initiation, and promotes oxygenate formation. (2) The addition of Mo to Fe-Cu-K/AC F-T catalysts improves catalyst lifetime and activity. (3) The use of gas phase deposition to place highly dispersed metal catalysts on silica or ceria aerogels offers promise for both the F-T and the water-gas shift WGS reactions. (4) Improved activity and selectivity are exhibited by Co F-T catalysts in supercritical hexane. (5) Binary Fe-M (M=Ni, Mo, Pd) catalysts exhibit excellent activity for dehydrogenation of gaseous alkanes, yielding pure hydrogen and carbon nanotubes in one reaction. A fluidized-bed/fixed-bed methane reactor was developed for continuous hydrogen and nanotube production. (6) A process for co-production of hydrogen and methyl formate from methanol has been developed. (7) Pt nanoparticles on stacked-cone carbon nanotubes easily strip hydrogen from liquids such as cyclohexane, methylcyclohexane, tetralin and decalin, leaving rechargeable aromatic phases. (8) Hydrogen volume percentages produced during reforming of methanol in supercritical water in the output stream are {approx}98%, while CO and CO2 percentages are <2 %.

  3. Method of controlling injection of oxygen into hydrogen-rich fuel cell feed stream

    DOE Patents [OSTI]

    Meltser, Mark Alexander; Gutowski, Stanley; Weisbrod, Kirk

    2001-01-01

    A method of operating a H.sub.2 --O.sub.2 fuel cell fueled by hydrogen-rich fuel stream containing CO. The CO content is reduced to acceptable levels by injecting oxygen into the fuel gas stream. The amount of oxygen injected is controlled in relation to the CO content of the fuel gas, by a control strategy that involves (a) determining the CO content of the fuel stream at a first injection rate, (b) increasing the O.sub.2 injection rate, (c) determining the CO content of the stream at the higher injection rate, (d) further increasing the O.sub.2 injection rate if the second measured CO content is lower than the first measured CO content or reducing the O.sub.2 injection rate if the second measured CO content is greater than the first measured CO content, and (e) repeating steps a-d as needed to optimize CO consumption and minimize H.sub.2 consumption.

  4. Method and apparatus for conversion of carbonaceous materials to liquid fuel

    DOE Patents [OSTI]

    Lux, Kenneth W.; Namazian, Mehdi; Kelly, John T.

    2015-12-01

    Embodiments of the invention relates to conversion of hydrocarbon material including but not limited to coal and biomass to a synthetic liquid transportation fuel. The invention includes the integration of a non-catalytic first reaction scheme, which converts carbonaceous materials into a solid product that includes char and ash and a gaseous product; a non-catalytic second reaction scheme, which converts a portion of the gaseous product from the first reaction scheme to light olefins and liquid byproducts; a traditional gas-cleanup operations; and the third reaction scheme to combine the olefins from the second reaction scheme to produce a targeted fuel like liquid transportation fuels.

  5. SUBTASK 3.12 - GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS

    Office of Scientific and Technical Information (OSTI)

    PRODUCTION WITH ILLINOIS COAL (Other) | SciTech Connect Other: SUBTASK 3.12 - GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS PRODUCTION WITH ILLINOIS COAL Citation Details In-Document Search Title: SUBTASK 3.12 - GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS PRODUCTION WITH ILLINOIS COAL The goal of this project was to evaluate the performance of Illinois No. 6 coal blended with biomass in a small-scale entrained-flow gasifier and demonstrate the production of liquid fuels under three

  6. EIS-0432: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon

    Energy Savers [EERE]

    County, WY | Department of Energy 2: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, WY EIS-0432: Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, WY Documents Available for Download November 27, 2009 EIS-0432: Notice of Intent to Prepare an Environmental Impact Statement Federal Loan Guarantee to Support the Construction and Startup of the Medicine Bow Fuel & Power Coal-to-Liquid Facility in Carbon County, Wyoming December 16, 2009

  7. A Low-cost, High-yield Process for the Direct Productin of High Energy Density Liquid Fuel from Biomass

    SciTech Connect (OSTI)

    Agrawal, Rakesh

    2014-02-21

    The primary objective and outcome of this project was the development and validation of a novel, low-cost, high-pressure fast-hydropyrolysis/hydrodeoxygenation (HDO) process (H{sub 2}Bioil) using supplementary hydrogen (H{sub 2}) to produce liquid hydrocarbons from biomass. The research efforts under the various tasks of the project have culminated in the first experimental demonstration of the H2Bioil process, producing 100% deoxygenated >C4+ hydrocarbons containing 36-40% of the carbon in the feed of pyrolysis products from biomass. The demonstrated H{sub 2}Bioil process technology (i.e. reactor, catalyst, and downstream product recovery) is scalable to a commercial level and is estimated to be economically competitive for the cases when supplementary H{sub 2} is sourced from coal, natural gas, or nuclear. Additionally, energy systems modeling has revealed several process integration options based on the H{sub 2}Bioil process for energy and carbon efficient liquid fuel production. All project tasks and milestones were completed or exceeded. Novel, commercially-scalable, high-pressure reactors for both fast-hydropyrolysis and hydrodeoxygenation were constructed, completing Task A. These reactors were capable of operation under a wide-range of conditions; enabling process studies that lead to identification of optimum process conditions. Model compounds representing biomass pyrolysis products were studied, completing Task B. These studies were critical in identifying and developing HDO catalysts to target specific oxygen functional groups. These process and model compound catalyst studies enabled identification of catalysts that achieved 100% deoxygenation of the real biomass feedstock, sorghum, to form hydrocarbons in high yields as part of Task C. The work completed during this grant has identified and validated the novel and commercially scalable H2Bioil process for production of hydrocarbon fuels from biomass. Studies on model compounds as well as real biomass feedstocks were utilized to identify optimized process conditions and selective HDO catalyst for high yield production of hydrocarbons from biomass. In addition to these experimental efforts, in Tasks D and E, we have developed a mathematical optimization framework to identify carbon and energy efficient biomass-to-liquid fuel process designs that integrate the use of different primary energy sources along with biomass (e.g. solar, coal or natural gas) for liquid fuel production. Using this tool, we have identified augmented biomass-to-liquid fuel configurations based on the fast-hydropyrolysis/HDO pathway, which was experimentally studied in this project. The computational approach used for screening alternative process configurations represents a unique contribution to the field of biomass processing for liquid fuel production.

  8. Oxygen reduction and transportation mechanisms in solid oxide fuel cell cathodes

    SciTech Connect (OSTI)

    Li YH, Gemmen R, Liu XB

    2010-06-01

    In recent years, various models have been developed for describing the reaction mechanisms in solid oxide fuel cell (SOFC) especially for the cathode electrode. However, many fundamental issues regarding the transport of oxygen and electrode kinetics have not been fully understood. This review tried to summarize the present status of the SOFC cathode modeling efforts, and associated experimental approaches on this topic. In addition, unsolved problems and possible future research directions for SOFC cathode kinetics had been discussed

  9. Diesel engine experiments with oxygen enrichment, water addition and lower-grade fuel

    SciTech Connect (OSTI)

    Sekar, R.R.; Marr, W.W.; Cole, R.L.; Marciniak, T.J. ); Schaus, J.E. )

    1990-01-01

    The concept of oxygen enriched air applied to reciprocating engines is getting renewed attention in the context of the progress made in the enrichment methods and the tougher emissions regulations imposed on diesel and gasoline engines. An experimental project was completed in which a direct injection diesel engine was tested with intake oxygen levels of 21% -- 35%. Since an earlier study indicated that it is necessary to use a cheaper fuel to make the concept economically attractive, a less refined fuel was included in the test series. Since a major objection to the use of oxygen enriched combustion air had been the increase in NO{sub x} emissions, a method must be found to reduce NO{sub x}. Introduction of water into the engine combustion process was included in the tests for this purpose. Fuel emulsification with water was the means used here even though other methods could also be used. The teat data indicated a large increase in engine power density, slight improvement in thermal efficiency, significant reductions in smoke and particulate emissions and NO{sub x} emissions controllable with the addition of water. 15 refs., 10 figs., 2 tabs.

  10. SUBTASK 3.12 - GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS...

    Office of Scientific and Technical Information (OSTI)

    Other: SUBTASK 3.12 - GASIFICATION, WARM-GAS CLEANUP, AND LIQUID FUELS PRODUCTION WITH ILLINOIS COAL Citation Details In-Document Search Title: SUBTASK 3.12 - GASIFICATION, ...

  11. Liquid Fuel From Renewable Electricity and Bacteria: Electro-Autotrophic Synthesis of Higher Alcohols

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: UCLA is utilizing renewable electricity to power direct liquid fuel production in genetically engineered Ralstonia eutropha bacteria. UCLA is using renewable electricity to convert carbon dioxide into formic acid, a liquid soluble compound that delivers both carbon and energy to the bacteria. The bacteriaare genetically engineered to convert the formic acid into liquid fuelin this case alcohols such as butanol. The electricity required for the process can be generated from sunlight, wind, or other renewable energy sources. In fact, UCLAs electricity-to-fuel system could be a more efficient way to utilize these renewable energy sources considering the energy density of liquid fuel is much higher than the energy density of other renewable energy storage options, such as batteries.

  12. One-step catalytic conversion of biomass-derived carbohydrates to liquid fuels

    DOE Patents [OSTI]

    Sen, Ayusman; Yang, Weiran

    2014-03-18

    The invention relates to a method for manufacture of hydrocarbon fuels and oxygenated hydrocarbon fuels such as alkyl substituted tetrahydrofurans such as 2,5-dimethyltetrahydrofuran, 2-methyltetrahydrofuran, 5-methylfurfural and mixtures thereof. The method generally entails forming a mixture of reactants that includes carbonaceous material, water, a metal catalyst and an acid reacting that mixture in the presence of hydrogen. The reaction is performed at a temperature and for a time sufficient to produce a furan type hydrocarbon fuel. The process may be adapted to provide continuous manufacture of hydrocarbon fuels such as a furan type fuel.

  13. Method for removing solid particulate material from within liquid fuel injector assemblies

    DOE Patents [OSTI]

    Simandl, R.F.; Brown, J.D.; Andriulli, J.B.; Strain, P.D.

    1998-09-08

    A method is described for removing residual solid particulate material from the interior of liquid fuel injectors and other fluid flow control mechanisms having or being operatively associated with a flow-regulating fixed or variable orifice. The method comprises the sequential and alternate introduction of columns of a non-compressible liquid phase and columns of a compressed gas phase into the body of a fuel injector whereby the expansion of each column of the gas phase across the orifice accelerates the liquid phase in each trailing column of the liquid phase and thereby generates turbulence in each liquid phase for lifting and entraining the solid particulates for the subsequent removal thereof from the body of the fuel injector. 1 fig.

  14. Method for removing solid particulate material from within liquid fuel injector assemblies

    DOE Patents [OSTI]

    Simandl, Ronald F. (Knoxville, TN); Brown, John D. (Harriman, TN); Andriulli, John B. (Kingston, TN); Strain, Paul D. (Eads, TN)

    1998-01-01

    A method for removing residual solid particulate material from the interior of liquid fuel injectors and other fluid flow control mechanisms having or being operatively associated with a flow-regulating fixed or variable orifice. The method comprises the sequential and alternate introduction of columns of a non-compressible liquid phase and columns of a compressed gas phase into the body of a fuel injector whereby the expansion of each column of the gas phase across the orifice accelerates the liquid phase in each trailing column of the liquid phase and thereby generates turbulence in each liquid phase for lifting and entraining the solid particulates for the subsequent removal thereof from the body of the fuel injector.

  15. Computational fluid dynamics analysis of a wire-feed, high-velocity oxygen-fuel (HVOF) thermal spray torch

    SciTech Connect (OSTI)

    Lopez, A.R.; Hassan, B.; Oberkampf, W.L.; Neiser, R.A.; Roemer, T.J.

    1996-09-01

    The fluid and particle dynamics of a High-Velocity Oxygen-Fuel Thermal Spray torch are analyzed using computational and experimental techniques. Three-dimensional Computational Fluid Dynamics (CFD) results are presented for a curved aircap used for coating interior surfaces such as engine cylinder bores. The device analyzed is similar to the Metco Diamond Jet Rotating Wire (DJRW) torch. The feed gases are injected through an axisymmetric nozzle into the curved aircap. Premixed propylene and oxygen are introduced from an annulus in the nozzle, while cooling air is injected between the nozzle and the interior wall of the aircap. The combustion process is modeled using a single-step finite-rate chemistry model with a total of 9 gas species which includes dissociation of combustion products. A continually-fed steel wire passes through the center of the nozzle and melting occurs at a conical tip near the exit of the aircap. Wire melting is simulated computationally by injecting liquid steel particles into the flow field near the tip of the wire. Experimental particle velocity measurements during wire feed were also taken using a Laser Two-Focus (L2F) velocimeter system. Flow fields inside and outside the aircap are presented and particle velocity predictions are compared with experimental measurements outside of the aircap.

  16. Assumptions for Annual Energy Outlook 2014: Liquid Fuels Markets Working Group

    U.S. Energy Information Administration (EIA) Indexed Site

    4: Liquid Fuels Markets Working Group AEO2014 Liquid Fuels Markets Working Group Meeting Office of Petroleum, Natural Gas & Biofuels Analysis July 24, 2013 | Washington, DC WORKING GROUP PRESENTATION FOR DISCUSSION PURPOSES DO NOT QUOTE OR CITE AS RESULTS ARE SUBJECT TO CHANGE Discussion topics Office of Petroleum, Natural Gas, & Biofuels Analysis Working Group Presentation for Discussion Purposes Washington DC, July 24, 2013 DO NOT QUOTE OR CITE as results are subject to change 2 *

  17. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Techno-economic Evaluation of the Production of Mixed Alcohols | Department of Energy 2: A Techno-economic Evaluation of the Production of Mixed Alcohols Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A Techno-economic Evaluation of the Production of Mixed Alcohols Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications and thus help meet the Energy Independence and Security Act renewable energy goals (U.S.

  18. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1: Availability of Feedstock and Technology

    SciTech Connect (OSTI)

    Valkenburt, Corinne; Walton, Christie W.; Thompson, Becky L.; Gerber, Mark A.; Jones, Susanne B.; Stevens, Don J.

    2008-12-01

    This report investigated the potential of using municipal solid waste (MSW) to make synthesis gas (syngas) suitable for production of liquid fuels. Issues examined include: MSW physical and chemical properties affecting its suitability as a gasifier feedstock and for liquid fuels synthesis expected process scale required for favorable economics the availability of MSW in quantities sufficient to meet process scale requirements the state-of-the-art of MSW gasification technology.

  19. Techno-Economic Analysis of Liquid Fuel Production from Woody Biomass via

    Office of Scientific and Technical Information (OSTI)

    Hydrothermal Liquefaction (HTL) and Upgrading (Journal Article) | SciTech Connect Journal Article: Techno-Economic Analysis of Liquid Fuel Production from Woody Biomass via Hydrothermal Liquefaction (HTL) and Upgrading Citation Details In-Document Search Title: Techno-Economic Analysis of Liquid Fuel Production from Woody Biomass via Hydrothermal Liquefaction (HTL) and Upgrading Authors: Zhu, Y. ; Biddy, M. J. ; Jones, S. B. ; Elliott, D. C. ; Schmidt, A. J. Publication Date: 2014-09-15 OSTI

  20. Zero Emission Power Plants Using Solid Oxide Fuel Cells and Oxygen Transport Membranes

    SciTech Connect (OSTI)

    Shockling, Larry A.; Huang, Keqin; Gilboy, Thomas E.; Christie, G. Maxwell; Raybold, Troy M.

    2001-11-06

    Siemens Westinghouse Power Corp. (SWPC) is engaged in the development of Solid Oxide Fuel Cell stationary power systems. SWPC has combined DOE Developmental funds with commercial customer funding to establish a record of successful SOFC field demonstration power systems of increasing size. SWPC will soon deploy the first unit of a newly developed 250 kWe Combined Heat Power System. It will generate electrical power at greater than 45% electrical efficiency. The SWPC SOFC power systems are equipped to operate on lower number hydrocarbon fuels such as pipeline natural gas, which is desulfurized within the SOFC power system. Because the system operates with a relatively high electrical efficiency, the CO2 emissions, {approx}1.0 lb CO2/ kW-hr, are low. Within the SOFC module the desulfurized fuel is utilized electrochemically and oxidized below the temperature for NOx generation. Therefore the NOx and SOx emissions for the SOFC power generation system are near negligible. The byproducts of the power generation from hydrocarbon fuels that are released into the environment are CO2 and water vapor. This forward looking DOE sponsored Vision 21 program is supporting the development of methods to capture and sequester the CO2, resulting in a Zero Emission power generation system. To accomplish this, SWPC is developing a SOFC module design, to be demonstrated in operating hardware, that will maintain separation of the fuel cell anode gas, consisting of H2, CO, H2O and CO2, from the vitiated air. That anode gas, the depleted fuel stream, containing less than 18% (H2 + CO), will be directed to an Oxygen Transport Membrane (OTM) Afterburner that is being developed by Praxair, Inc.. The OTM is supplied air and the depleted fuel. The OTM will selectively transport oxygen across the membrane to oxidize the remaining H2 and CO. The water vapor is then condensed from the totally 1.5.DOC oxidized fuel stream exiting the afterburner, leaving only the CO2 in gaseous form. That CO2 can then be compressed and sequestered, resulting in a Zero Emission power generation system operating on hydrocarbon fuel that adds only water vapor to the environment. Praxair has been developing oxygen separation systems based on dense walled, mixed electronic, oxygen ion conducting ceramics for a number of years. The oxygen separation membranes find applications in syngas production, high purity oxygen production and gas purification. In the SOFC afterburner application the chemical potential difference between the high temperature SOFC depleted fuel gas and the supplied air provides the driving force for oxygen transport. This permeated oxygen subsequently combusts the residual fuel in the SOFC exhaust. A number of experiments have been carried out in which simulated SOFC depleted fuel gas compositions and air have been supplied to either side of single OTM tubes in laboratory-scale reactors. The ceramic tubes are sealed into high temperature metallic housings which precludes mixing of the simulated SOFC depleted fuel and air streams. In early tests, although complete oxidation of the residual CO and H2 in the simulated SOFC depleted fuel was achieved, membrane performance degraded over time. The source of degradation was found to be contaminants in the simulated SOFC depleted fuel stream. Following removal of the contaminants, stable membrane performance has subsequently been demonstrated. In an ongoing test, the dried afterburner exhaust composition has been found to be stable at 99.2% CO2, 0.4% N2 and 0.6%O2 after 350 hours online. Discussion of these results is presented. A test of a longer, commercial demonstration size tube was performed in the SWPC test facility. A similar contamination of the simulated SOFC depleted fuel stream occurred and the performance degraded over time. A second test is being prepared. Siemens Westinghouse and Praxair are collaborating on the preliminary design of an OTM equipped Afterburner demonstration unit. The intent is to test the afterburner in conjunction with a reduced size SOFC test module that has the anode gas separation features incorporated into the hardware.

  1. Liquid Fuels Taxes and Credits (released in AEO2010)

    Reports and Publications (EIA)

    2010-01-01

    Provides a review of the treatment of federal fuels taxes and tax credits in Annual Energy Outlook 2010.

  2. Annular core liquid-salt cooled reactor with multiple fuel and blanket

    Office of Scientific and Technical Information (OSTI)

    zones (Patent) | SciTech Connect Patent: Annular core liquid-salt cooled reactor with multiple fuel and blanket zones Citation Details In-Document Search Title: Annular core liquid-salt cooled reactor with multiple fuel and blanket zones A liquid fluoride salt cooled, high temperature reactor having a reactor vessel with a pebble-bed reactor core. The reactor core comprises a pebble injection inlet located at a bottom end of the reactor core and a pebble defueling outlet located at a top end

  3. Second AEO2014 Liquids Fuels Markets Working Group Meeting Summary

    U.S. Energy Information Administration (EIA) Indexed Site

    JOHN CONTI ASSISTANT ADMINISTRATOR FOR ENERGY ANALYSIS JOHN POWELL TEAM LEADER LIQUID ... - The California LCFS draws low carbon intensity biofuels to California - corn ethanol, ...

  4. Enabling Small-Scale Biomass Gasification for Liquid Fuel Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ...activity wax-free Chevron cobalt-zeolite hybrid catalyst - Initial testing carried ... Synthesis Performance of a Chevron Co- Zeolite Hybrid Liquid Selective Catalyst Time on ...

  5. Ignition Capsules with Aerogel-Supported Liquid DT Fuel For The National Ignition Facility

    SciTech Connect (OSTI)

    Ho, D D; Salmonson, J D; Clark, D S; Lindl, J D; Haan, S W; Amendt, P; Wu, K J

    2011-10-25

    For high repetition-rate fusion power plant applications, capsules with aerogel-supported liquid DT fuel can have much reduced fill time compared to {beta}-layering a solid DT fuel layer. The melting point of liquid DT can be lowered once liquid DT is embedded in an aerogel matrix, and the DT vapor density is consequently closer to the desired density for optimal capsule design requirement. We present design for NIF-scale aerogel-filled capsules based on 1-D and 2-D simulations. An optimal configuration is obtained when the outer radius is increased until the clean fuel fraction is within 65-75% at peak velocity. A scan (in ablator and fuel thickness parameter space) is used to optimize the capsule configurations. The optimized aerogel-filled capsule has good low-mode robustness and acceptable high-mode mix.

  6. Liquid Fuels Market Model of the National Energy Modeling System...

    Gasoline and Diesel Fuel Update (EIA)

    correlations), AIChE papers, Petroleum Review. * An extensive review of foreign journals obtained with the aid of ORNL for the high-density jet fuel study. * Contractor...

  7. Liquid Fuels Market Module of the National Energy Modeling System...

    Gasoline and Diesel Fuel Update (EIA)

    correlations), AIChE papers, Petroleum Review. * An extensive review of foreign journals obtained with the aid of ORNL for the high-density jet fuel study. * Contractor...

  8. Modeling CANDU-6 liquid zone controllers for effects of thorium-based fuels

    SciTech Connect (OSTI)

    St-Aubin, E.; Marleau, G.

    2012-07-01

    We use the DRAGON code to model the CANDU-6 liquid zone controllers and evaluate the effects of thorium-based fuels on their incremental cross sections and reactivity worth. We optimize both the numerical quadrature and spatial discretization for 2D cell models in order to provide accurate fuel properties for 3D liquid zone controller supercell models. We propose a low computer cost parameterized pseudo-exact 3D cluster geometries modeling approach that avoids tracking issues on small external surfaces. This methodology provides consistent incremental cross sections and reactivity worths when the thickness of the buffer region is reduced. When compared with an approximate annular geometry representation of the fuel and coolant region, we observe that the cluster description of fuel bundles in the supercell models does not increase considerably the precision of the results while increasing substantially the CPU time. In addition, this comparison shows that it is imperative to finely describe the liquid zone controller geometry since it has a strong impact of the incremental cross sections. This paper also shows that liquid zone controller reactivity worth is greatly decreased in presence of thorium-based fuels compared to the reference natural uranium fuel, since the fission and the fast to thermal scattering incremental cross sections are higher for the new fuels. (authors)

  9. Liquid fuels perspective on ultra low carbon vehicles | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy Fuels challenges in the evolving global energy market PDF icon deer11_simnick.pdf More Documents & Publications Green Racing Initiative: Accelerating the Use of Advanced Technologies & Renewable Fuels Well-to-Wheels Analysis of Energy Use and Greenhouse Gas Emissions of Plug-In Hybrid Electric Vehicles Vehicle Technologies Office Merit Review 2014: VTO Analysis Portfolio

  10. Copper-substituted perovskite compositions for solid oxide fuel cell cathodes and oxygen reduction electrodes in other electrochemical devices

    DOE Patents [OSTI]

    Rieke, Peter C.; Coffey, Gregory W.; Pederson, Larry R.; Marina, Olga A.; Hardy, John S.; Singh, Prabhaker; Thomsen, Edwin C.

    2010-07-20

    The present invention provides novel compositions that find advantageous use in making electrodes for electrochemical cells. Also provided are electrochemical devices that include active oxygen reduction electrodes, such as solid oxide fuel cells, sensors, pumps and the like. The compositions comprises a copper-substituted ferrite perovskite material. The invention also provides novel methods for making and using the electrode compositions and solid oxide fuel cells and solid oxide fuel cell assemblies having cathodes comprising the compositions.

  11. Hydropyrolysis of biomass to produce liquid hydrocarbon fuels. Final report. Biomass Alternative-Fuels Program

    SciTech Connect (OSTI)

    Fujita, R K; Bodle, W W; Yuen, P C

    1982-10-01

    The ojective of the study is to provide a process design and cost estimates for a biomass hydropyrolysis plant and to establish its economic viability for commercial applications. A plant site, size, product slate, and the most probable feedstock or combination of feedstocks were determined. A base case design was made by adapting IGT's HYFLEX process to Hawaiian biomass feedstocks. The HYFLEX process was developed by IGT to produce liquid and/or gaseous fuels from carbonaceous materials. The essence of the process is the simultaneous extraction of valuable oil and gaseous products from cellulosic biomass feedstocks without forming a heavy hard-to-handle tar. By controlling rection time and temperature, the product slate can be varied according to feedstock and market demand. An optimum design and a final assessment of the applicability of the HYFLEX process to the conversion of Hawaiian biomass was made. In order to determine what feedstocks could be available in Hawaii to meet the demands of the proposed hydropyrolysis plant, various biomass sources were studied. These included sugarcane and pineapple wastes, indigenous and cultivated trees and indigenous and cultivated shrubs and grasses.

  12. Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts

    DOE Patents [OSTI]

    Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

    2014-08-12

    Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

  13. Dehydrogenation of liquid fuel in microchannel catalytic reactor

    DOE Patents [OSTI]

    Toseland, Bernard Allen; Pez, Guido Peter; Puri, Pushpinder Singh

    2009-02-03

    The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps: introducing a hydrogenated organic compound to a microchannel reactor incorporating a dehydrogenation catalyst; effecting dehydrogenation of said hydrogenated organic compound under conditions whereby said hydrogenated organic compound is present as a liquid phase; generating a reaction product comprised of a liquid phase dehydrogenated organic compound and gaseous hydrogen; separating the liquid phase dehydrogenated organic compound from gaseous hydrogen; and, recovering the hydrogen and liquid phase dehydrogenated organic compound.

  14. Dehydrogenation of liquid fuel in microchannel catalytic reactor

    DOE Patents [OSTI]

    Toseland, Bernard Allen; Pez, Guido Peter; Puri, Pushpinder Singh

    2010-08-03

    The present invention is an improved process for the storage and delivery of hydrogen by the reversible hydrogenation/dehydrogenation of an organic compound wherein the organic compound is initially in its hydrogenated state. The improvement in the route to generating hydrogen is in the dehydrogenation step and recovery of the dehydrogenated organic compound resides in the following steps: introducing a hydrogenated organic compound to a microchannel reactor incorporating a dehydrogenation catalyst; effecting dehydrogenation of said hydrogenated organic compound under conditions whereby said hydrogenated organic compound is present as a liquid phase; generating a reaction product comprised of a liquid phase dehydrogenated organic compound and gaseous hydrogen; separating the liquid phase dehydrogenated organic compound from gaseous hydrogen; and, recovering the hydrogen and liquid phase dehydrogenated organic compound.

  15. Synthesis of oxygenates from H{sub 2}/CO synthesis gas and use as fuel additives

    SciTech Connect (OSTI)

    Herman, R.G.; Klier, K.; Feeley, O.C.

    1994-12-31

    Alternative processes for synthesizing fuel-grade oxygenates are centered on conversion of synthesis gas into C{sub 1}-C{sub 8} alcohols and ethers. Over Cs/Cu/ZnO-based catalysts, mixtures of methanol/isobutanol are predominantly formed. It has been found that these alcohols can be directly coupled over certain strong acid organic-based catalysts to form unsymmetric C{sub 5} ethers, mainly the kinetically favored methyl isobutyl ether (MIBE) with some of the thermodynamically favored methyl tertiarybutyl ether (MTBE), the symmetric ethers of dimethylether (DME) and diisobutylether (DIBE), or selectively dehydrated to form isobutene over sulfated zirconia. Based on these reactions, a 2-stage, dual catalyst configuration can be utilized to give MTBE as the dominant ether product. The octane numbers and cetane ratings of the oxygenates have been determined and are compared, e.g. adding 10 vol% MIBE and MTBE to 82.3 MON gasoline altered the MON of the gasoline by -1.5 and +1.4 units, respectively, and MIBE has a high cetane number of 53, compared to 42 for typical U.S. diesel fuel.

  16. Catalytic conversion of solar thermal produced pyrolysis gases to liquid fuels

    SciTech Connect (OSTI)

    Hanley, T.R.; Benham, C.B.

    1981-01-01

    The conversion of a simulated pyrolysis gas and synthesis gas using a Fischer-Tropsch catalyst system in a fluidized-bed reactor is investigated. Liquid fuels were produced between 550 and 660/sup 0/F (288 and 349/sup 0/C) for the simulated pyrolysis gas feed. An analysis of both liquid and gaseous product streams is performed. This investigation indicates a need for more extensive research with respect to hydrogen-to-carbon-monoxide usage ratios and with respect to the role of alkenes in fuel production.

  17. Liquid fuel vaporizer and combustion chamber having an adjustable thermal conductor

    DOE Patents [OSTI]

    Powell, Michael R; Whyatt, Greg A; Howe, Daniel T; Fountain, Matthew S

    2014-03-04

    The efficiency and effectiveness of apparatuses for vaporizing and combusting liquid fuel can be improved using thermal conductors. For example, an apparatus having a liquid fuel vaporizer and a combustion chamber can be characterized by a thermal conductor that conducts heat from the combustion chamber to the vaporizer. The thermal conductor can be a movable member positioned at an insertion depth within the combustion chamber that corresponds to a rate of heat conduction from the combustion chamber to the vaporizer. The rate of heat conduction can, therefore, be adjusted by positioning the movable member at a different insertion depth.

  18. Development of Hydrothermal Liquefaction and Upgrading Technologies for Lipid-Extracted Algae Conversion to Liquid Fuels

    SciTech Connect (OSTI)

    Zhu, Yunhua; Albrecht, Karl O.; Elliott, Douglas C.; Hallen, Richard T.; Jones, Susanne B.

    2013-10-01

    Bench-scale tests were performed for lipid-extracted microalgae (LEA) conversion to liquid fuels via hydrotreating liquefaction (HTL) and upgrading processes. Process simulation and economic analysis for a large-scale LEA HTL and upgrading system were developed based on the best available test results. The system assumes an LEA feed rate of 608 dry metric ton/day and that the feedstock is converted to a crude HTL bio-oil and further upgraded via hydrotreating and hydrocracking to produce liquid hydrocarbon fuels, mainly alkanes. Performance and cost results demonstrate that HTL would be an effective option to convert LEA to liquid fuel. The liquid fuels annual yield was estimated to be 26.9 million gallon gasoline-equivalent and the overall energy efficiency at higher heating value basis was estimated to be 69.5%. The minimum fuel selling price (MFSP) was estimated to be $0.75/L with LEA feedstock price at $33.1 metric ton at dry basis and 10% internal rate of return. A sensitivity analysis indicated that the largest effects to production cost would come from the final products yields and the upgrading equipments cost. The impact of plant scale on MFSP was also investigated.

  19. Alternative Liquid Fuels Simulation Model (AltSim) v. 2.0

    Energy Science and Technology Software Center (OSTI)

    2010-02-24

    The Alternative Liquid Fuels Simulation Model (AltSim) is a high-level dynamic simulation model which calculates and compares the production and end use costs, energy balances, and greenhouse gas emissions for several alternative liquid transportation fuels. These fuels include: corn ethanol, cellulosic ethanol from various feedstocks, biodiesel, and diesels derived from natural gas (gas to liquid, or GTL), coal (coal to liquid, or CTL), and coal with biomass (CBTL). AltSim allows for comprehensive sensitivity analyses onmore » capital costs, operation and maintenance costs, renewable and fossil fuel feedstock costs, feedstock conversion efficiency, financial assumptions, tax credits, CO2 taxes, and plant capacity factor. AltSim also includes policy tools to allow for consideration of greenhouse gas offset policies, production tax credits, and land use requirements. The main goal is to allow interested stakeholders to understand the complicated economic and environmental tradeoffs associated with the various options. The software is designed to address policy questions related to the economic competitiveness of technologies under different economic and technical assumptions. This model will be used to inform policy makers and staff about the economic and environmental tradeoffs associated with various fuel alternatives.« less

  20. Comparing liquid fuel costs: grain alcohol versus sunflower oil

    SciTech Connect (OSTI)

    Reining, R.C.; Tyner, W.E.

    1983-08-01

    This paper compares the technical and economic feasibility of small-scale production of fuel grade grain alcohol with sunflower oil. Three scales of ethanol and sunflower oil production are modeled, and sensitivity analysis is conducted for various operating conditions and costs. The general conclusion is that sunflower oil costs less to produce than alcohol. Government subsidies for alcohol, but not sunflower oil, could cause adoption of more expensive alcohol in place of cheaper sunflower oil. However, neither sunflower oil nor alcohol are competitive with diesel fuel. 7 references.

  1. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A.; Im, Chang J.; Wright, Robert E.

    1994-01-01

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  2. Irradiation performance of U-Pu-Zr metal fuels for liquid-metal-cooled reactors

    SciTech Connect (OSTI)

    Tsai, H.; Cohen, A.B.; Billone, M.C.; Neimark, L.A.

    1994-10-01

    This report discusses a fuel system utilizing metallic U-Pu-Zr alloys which has been developed for advanced liquid metal-cooled reactors (LMRs). Result`s from extensive irradiation testing conducted in EBR-II show a design having the following key features can achieve both high reliability and high burnup capability: a cast nominally U-20wt %Pu-10wt %Zr slug with the diameter sized to yield a fuel smear density of {approx}75% theoretical density, low-swelling tempered martensitic stainless steel cladding, sodium bond filling the initial fuel/cladding gap, and an as-built plenum/fuel volume ratio of {approx}1.5. The robust performance capability of this design stems primarily from the negligible loading on the cladding from either fuel/cladding mechanical interaction or fission-gas pressure during the irradiation. The effects of these individual design parameters, e.g., fuel smear density, zirconium content in fuel, plenum volume, and cladding types, on fuel element performance were investigated in a systematic irradiation experiment in EBR-II. The results show that, at the discharge burnup of {approx}11 at. %, variations on zirconium content or plenum volume in the ranges tested have no substantial effects on performance. Fuel smear density, on the other hand, has pronounced but countervailing effects: increased density results in greater cladding strain, but lesser cladding wastage from fuel/cladding chemical interaction.

  3. Liquid Metal Bond for Improved Heat Transfer in LWR Fuel Rods

    SciTech Connect (OSTI)

    Donald Olander

    2005-08-24

    A liquid metal (LM) consisting of 1/3 weight fraction each of Pb, Sn, and Bi has been proposed as the bonding substance in the pellet-cladding gap in place of He. The LM bond eliminates the large AT over the pre-closure gap which is characteristic of helium-bonded fuel elements. Because the LM does not wet either UO2 or Zircaloy, simply loading fuel pellets into a cladding tube containing LM at atmospheric pressure leaves unfilled regions (voids) in the bond. The HEATING 7.3 heat transfer code indicates that these void spaces lead to local fuel hot spots.

  4. Low Emissions Burner Technology for Metal Processing Industry using Byproducts and Biomass Derived Liquid Fuels

    SciTech Connect (OSTI)

    Agrawal, Ajay; Taylor, Robert

    2013-09-30

    This research and development efforts produced low-emission burner technology capable of operating on natural gas as well as crude glycerin and/or fatty acids generated in biodiesel plants. The research was conducted in three stages (1) Concept definition leading to the design and development of a small laboratory scale burner, (2) Scale-up to prototype burner design and development, and (3) Technology demonstration with field vefiication. The burner design relies upon the Flow Blurring (FB) fuel injection based on aerodynamically creating two-phase flow near the injector exit. The fuel tube and discharge orifice both of inside diameter D are separated by gap H. For H < 0.25D, the atomizing air bubbles into liquid fuel to create a two-phase flow near the tip of the fuel tube. Pressurized two-phase fuel-air mixture exits through the discharge orifice, which results in expansion and breakup of air bubbles yielding a spray with fine droplets. First, low-emission combustion of diesel, biodiesel and straight VO (soybean oil) was achieved by utilizing FB injector to yield fine sprays for these fuels with significantly different physical properties. Visual images for these baseline experiments conducted with heat release rate (HRR) of about 8 kW illustrate clean blue flames indicating premixed combustion for all three fuels. Radial profiles of the product gas temperature at the combustor exit overlap each other signifying that the combustion efficiency is independent of the fuel. At the combustor exit, the NOx emissions are within the measurement uncertainties, while CO emissions are slightly higher for straight VO as compared to diesel and biodiesel. Considering the large variations in physical and chemical properties of fuels considered, the small differences observed in CO and NOx emissions show promise for fuel-flexible, clean combustion systems. FB injector has proven to be very effective in atomizing fuels with very different physical properties, and it offers a path forward to utilize both fossil and alternative liquid fuels in the same combustion system. In particular, experiments show that straight VO can be cleanly combusted without the need for chemical processing or preheating steps, which can result in significant economic and environmental benefits. Next, low-emission combustion of glycerol/methane was achieved by utilizing FB injector to yield fine droplets of highly viscous glycerol. Heat released from methane combustion further improves glycerol pre-vaporization and thus its clean combustion. Methane addition results in an intensified reaction zone with locally high temperatures near the injector exit. Reduction in methane flow rate elongates the reaction zone, which leads to higher CO emissions and lower NOx emissions. Similarly, higher air to liquid (ALR) mass ratio improves atomization and fuel pre-vaporization and shifts the flame closer to the injector exit. In spite of these internal variations, all fuel mixes of glycerol with methane produced similar CO and NOx emissions at the combustor exit. Results show that FB concept provides low emissions with the flexibility to utilize gaseous and highly viscous liquid fuels, straight VO and glycerol, without preheating or preprocessing the fuels. Following these initial experiments in quartz combustor, we demonstrated that glycerol combustion can be stably sustained in a metal combustor. Phase Doppler Particle Analyzer (PDPA) measurements in glycerol/methane flames resulted in flow-weighted Sauter Mean Diameter (SMD) of 35 to 40 μm, depending upon the methane percentage. This study verified that lab-scale dual-fuel burner using FB injector can successfully atomize and combust glycerol and presumably other highly viscous liquid fuels at relatively low HRR (<10 kW). For industrial applications, a scaled-up glycerol burner design thus seemed feasible.

  5. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2004-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, West Virginia University, University of Utah, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. Feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification, coalbed methane, light products produced by Fischer-Tropsch (FT) synthesis, methanol, and natural gas.

  6. Liquid fossil-fuel technology. Quarterly technical progress report, April-June 1982

    SciTech Connect (OSTI)

    Linville, B.

    1982-10-01

    This report primarily covers in-house oil, gas, and synfuel research and lists the contracted research. The report is broken into the following areas: liquid fossil fuel cycle, extraction, processing, utilization, and project integration and technology transfer. BETC publications are listed. (DLC)

  7. Sampling and analysis plan for canister liquid and gas sampling at 105 KW fuel storage basin

    SciTech Connect (OSTI)

    Trimble, D.J.

    1996-08-09

    This Sampling and Analysis Plan describes the equipment,procedures and techniques for obtaining gas and liquid samples from sealed K West fuel canisters. The analytical procedures and quality assurance requirements for the subsequent laboratory analysis of the samples are also discussed.

  8. Liquid Fuel From Microbial Communities: Electroalcoholgenesis: Bioelectrochemical Reduction of CO2 to Butanol

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: MUSC is developing an engineered system to create liquid fuels from communities of interdependent microorganisms. MUSC is first pumping carbon dioxide (CO2) and renewable sources of electricity into a battery-like cell. A community of microorganisms uses the electricity to convert the CO2 into hydrogen. That hydrogen is then consumed by another community of microorganisms living in the same system. These new microorganisms convert the hydrogen into acetate, which in turn feed yet another community of microorganisms. This last community of microorganisms uses the acetate to produce a liquid biofuel called butanol. Similar interdependent microbial communities can be found in some natural environments, but they’ve never been coupled together in an engineered cell to produce liquid fuels. MUSC is working to triple the amount of butanol that can be produced in its system and to reduce the overall cost of the process.

  9. Pilot scale production and combustion of liquid fuels from refuse derived fuel (RDF): Part 2

    SciTech Connect (OSTI)

    Klosky, M.K.

    1996-09-01

    EnerTech is developing a process for producing pumpable slurry fuels, comparable to Coal-Water-Fuels (CWF), from solid Refuse Derived Fuels (RDF). Previous reports have described the characteristics of the enhanced carbonized RDF slurry fuels. This paper summarizes those fuel characteristics and reports on the latest combustion tests performed with the final product fuel. The objective of this research was to determine the boiler and emission performance from the carbonized RDF slurry fuel using statistical screening experiments. Eight combustion tests were performed with a pilot scale pulverized coal/oil boiler simulator, with CO, SO{sub 2}, and NO{sub x} emissions determined on-line. The combustion tests produced simultaneous CO and NO{sub x} emissions well below and SO{sub 2} emissions comparable to the promulgated New Source Performance Standards (NSPS). This research will form the basis for later combustion experiments to be performed with the carbonized RDF slurry fuel, in which dioxin/furan and trace metal emissions will be determined.

  10. ZERO EMISSION POWER PLANTS USING SOLID OXIDE FUEL CELLS AND OXYGEN TRANSPORT MEMBRANES

    SciTech Connect (OSTI)

    G. Maxwell Christie; Troy M. Raybold

    2003-06-10

    Over 16,700 hours of operational experience was gained for the Oxygen Transport Membrane (OTM) elements of the proposed SOFC/OTM zero-emission power generation concept. It was repeatedly demonstrated that OTMs with no additional oxidation catalysts were able to completely oxidize the remaining depleted fuel in a simulated SOFC anode exhaust at an O{sub 2} flux that met initial targets. In such cases, neither residual CO nor H{sub 2} were detected to the limits of the gas chromatograph (<10 ppm). Dried OTM afterburner exhaust streams contained up to 99.5% CO{sub 2}. Oxygen flux through modified OTMs was double or even triple that of the standard OTMs used for the majority of testing purposes. Both the standard and modified membranes in laboratory-scale and demonstration-sized formats exhibited stable performance over extended periods (2300 to 3500 hours or 3 to 5 months). Reactor contaminants, were determined to negatively impact OTM performance stability. A method of preventing OTM performance degradation was developed and proven to be effective. Information concerning OTM and seal reliability over extended periods and through various chemical and thermal shocks and cycles was also obtained. These findings were used to develop several conceptual designs for pilot (10 kWe) and commercial-scale (250 kWe) SOFC/OTM zero emission power generation systems.

  11. No loss fueling station for liquid natural gas vehicles

    SciTech Connect (OSTI)

    Gustafson, K.

    1993-07-20

    A no loss liquid natural gas (LNG) delivery system is described comprising: (a) means for storing LNG and natural gas at low pressure; (b) means for delivering LNG from the means for storing to a use device including means for sub-cooling the LNG; (c) means for pre-cooling the means for sub-cooling before the LNG is delivered to the use device to substantially reduce vaporization of the initial LNG delivered to the use device; and (d) means for delivering a selectable quantity of the natural gas in said storing means to said use device with the LNG.

  12. Analysis of liquid natural gas as a truck fuel: a system dynamics approach

    SciTech Connect (OSTI)

    Bray, M.A.; Sebo, D.E.; Mason, T.L.; Mills, J.I.; Rice, R.E.

    1996-10-01

    The purpose of this analysis is to evaluate the potential for growth in use of liquid natural gas (LNG) fueled trucks. . A system dynamics model was constructed for the analysis and a variety of scenarios were investigated. The analysis considers the economics of LNG fuel in the context of the trucking industry to identify barriers to the increased use of LNG trucks and potential interventions or leverage points which may overcome these barriers. The study showed that today, LNG use in trucks is not yet economically viable. A large change in the savings from fuel cost or capital cost is needed for the technology to take off. Fleet owners have no way now to benefit from the environmental benefits of LNG fuel nor do they benefit from the clean burning nature of the fuel. Changes in the fuel cost differential between diesel and LNG are not a research issue. However, quantifying the improvements in reliability and wear from the use of clean fuel could support increased maintenance and warranty periods. Many people involved in the use of LNG for trucks believe that LNG has the potential to occupy a niche within the larger diesel truck business. But if LNG in trucks can become economic, the spread of fuel stations and technology improvements could lead to LNG trucks becoming the dominant technology. An assumption in our simulation work is that LNG trucks will be purchased when economically attractive. None of the simulation results show LNG becoming economic but then only to the level of a niche market.

  13. In-Cylinder Reaction Chemistry and Kinetics During Negative Valve Overlap Fuel Injection Under Low-Oxygen Conditions

    SciTech Connect (OSTI)

    Kalaskar, Vickey B; Szybist, James P; Splitter, Derek A; Pihl, Josh A; Gao, Zhiming; Daw, C Stuart

    2013-01-01

    Fuel injection into the negative valve overlap (NVO) period is a common method for controlling combustion phasing in homogeneous charge compression ignition (HCCI) as well as other forms of advanced combustion. During this event, at least a portion of the fuel hydrocarbons can be converted to products containing significant levels of H2 and CO, as well as other short chain hydrocarbons by means of thermal cracking, water-gas shift, and partial oxidation reactions, depending on the availability of oxygen and the time-temperature-pressure history. The resulting products alter the autoignition properties of the combined fuel mixture for HCCI. Fuel-rich chemistry in a partial oxidation environment is also relevant to other high efficiency engine concepts (e.g., the dedicated EGR (D-EGR) concept from SWRI). In this study, we used a unique 6-stroke engine cycle to experimentally investigate the chemistry of a range of fuels injected during NVO under low oxygen conditions. Fuels investigated included iso-octane, iso-butanol, ethanol, and methanol. Products from NVO chemistry were highly dependent on fuel type and injection timing, with iso-octane producing less than 1.5% hydrogen and methanol producing more than 8%. We compare the experimental trends with CHEMKIN (single zone, 0-D model) predictions using multiple kinetic mechanisms available in the current literature. Our primary conclusion is that the kinetic mechanisms investigated are unable to accurately predict the magnitude and trends of major species we observed.

  14. Liquid Tin Anode Direct Coal Fuel Cell Final Program Report

    SciTech Connect (OSTI)

    Tao, Thomas

    2012-01-26

    This SBIR program will result in improved LTA cell technology which is the fundamental building block of the Direct Coal ECL concept. As described below, ECL can make enormous efficiency and cost contributions to utility scale coal power. This program will improve LTA cells for small scale power generation. As described in the Commercialization section, there are important intermediate military and commercial markets for LTA generators that will provide an important bridge to the coal power application. The specific technical information from this program relating to YSZ electrolyte durability will be broadly applicable SOFC developers working on coal based SOFC generally. This is an area about which very little is currently known and will be critical for successfully applying fuel cells to coal power generation.

  15. Sampling and Analysis Plan for canister liquid and gas sampling at 105-KW fuel storage basin

    SciTech Connect (OSTI)

    Harris, R.A.; Green, M.A.; Makenas, B.J.; Trimble, D.J.

    1995-03-01

    This Sampling and Analysis Plan (SAP) details the sampling and analyses to be performed on fuel canisters transferred to the Weasel Pit of the 105-KW fuel storage basin. The radionuclide content of the liquid and gas in the canisters must be evaluated to support the shipment of fuel elements to the 300 Area in support of the fuel characterization studies (Abrefah, et al. 1994, Trimble 1995). The following sections provide background information and a description of the facility under investigation, discuss the existing site conditions, present the constituents of concern, outline the purpose and scope of the investigation, outline the data quality objectives (DQO), provide analytical detection limit, precision, and accuracy requirements, and address other quality assurance (QA) issues.

  16. Techno-economic Analysis for the Thermochemical Conversion of Biomass to Liquid Fuels

    SciTech Connect (OSTI)

    Zhu, Yunhua; Tjokro Rahardjo, Sandra A.; Valkenburt, Corinne; Snowden-Swan, Lesley J.; Jones, Susanne B.; Machinal, Michelle A.

    2011-06-01

    ). This study is part of an ongoing effort within the Department of Energy to meet the renewable energy goals for liquid transportation fuels. The objective of this report is to present a techno-economic evaluation of the performance and cost of various biomass based thermochemical fuel production. This report also documents the economics that were originally developed for the report entitled “Biofuels in Oregon and Washington: A Business Case Analysis of Opportunities and Challenges” (Stiles et al. 2008). Although the resource assessments were specific to the Pacific Northwest, the production economics presented in this report are not regionally limited. This study uses a consistent technical and economic analysis approach and assumptions to gasification and liquefaction based fuel production technologies. The end fuels studied are methanol, ethanol, DME, SNG, gasoline and diesel.

  17. Design of a reconfigurable liquid hydrogen fuel tank for use in the Genii unmanned aerial vehicle

    SciTech Connect (OSTI)

    Adam, Patrick; Leachman, Jacob

    2014-01-29

    Long endurance flight, on the order of days, is a leading flight performance characteristic for Unmanned Aerial Vehicles (UAVs). Liquid hydrogen (LH2) is well suited to providing multi-day flight times with a specific energy 2.8 times that of conventional kerosene based fuels. However, no such system of LH2 storage, delivery, and use is currently available for commercial UAVs. In this paper, we develop a light weight LH2 dewar for integration and testing in the proton exchange membrane (PEM) fuel cell powered, student designed and constructed, Genii UAV. The fuel tank design is general for scaling to suit various UAV platforms. A cylindrical vacuum-jacketed design with removable end caps was chosen to incorporate various fuel level gauging, pressurizing, and slosh mitigation systems. Heat and mechanical loadings were modeled to compare with experimental results. Mass performance of the fuel tank is characterized by the fraction of liquid hydrogen to full tank mass, and the insulation performance was characterized by effective thermal conductivity and boil-off rate.

  18. Enhanced catalyst and process for converting synthesis gas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K.

    1986-01-01

    The conversion of synthesis gas to liquid molar fuels by means of a cobalt Fischer-Tropsch catalyst composition is enhanced by the addition of molybdenum, tungsten or a combination thereof as an additional component of said composition. The presence of the additive component increases the olefinic content of the hydrocarbon products produced. The catalyst composition can advantageously include a support component, such as a molecular sieve, co-catalyst/support component or a combination of such support components.

  19. Catalyst and process for converting synthesis gas to liquid motor fuels

    DOE Patents [OSTI]

    Coughlin, Peter K.

    1987-01-01

    The addition of an inert metal component, such as gold, silver or copper, to a Fischer-Tropsch catalyst comprising cobalt enables said catalyst to convert synthesis gas to liquid motor fuels at about 240.degree.-370.degree. C. with advantageously reduced selectivity of said cobalt for methane in said conversion. The catalyst composition can advantageously include a support component, such as a molecular sieve, co-catalyst/support component or a combination of such support components.

  20. Synergistic routes to liquid fuel for a petroleum-deprived future

    SciTech Connect (OSTI)

    Agrawal, R.; Singh, N.R.

    2009-07-15

    When compared with biomass gasification/Fischer-Tropsch synthesis, hydropyrolysis/hydrodeoxygenation (HDO)-based processes have a potential to achieve high biomass carbon conversion to liquid fuel with much lower amounts of supplementary H{sub 2}. On the basis of this observation, we suggest a Hydrogen Bio-oil (H{sub 2}Bioil) process using fast hydropyrolysis/HDO that has a potential to produce nearly double the amount of liquid fuel when compared with the existing biofuel processes while requiring only modest quantities of supplementary H{sub 2}. The optimal operating mode for the H{sub 2}Bioil process is suggested to be in an entrained bed mode in presence of H{sub 2} with gas phase HDO of hydropyrolyzed vapors. A remarkable result due to reduced need for the supplementary H{sub 2} is that it provides synergistic integration of the H(2)Bioil process with a coal gasification power plant or a small scale steam natural gas (NG) reformer leading to a dramatic increase in the liquid fuel production from biomass and coal or NG. Here, hot synthesis gas (T>500{sup o}C) from a coal gasifier or methane reformer supplies H{sub 2}/CO for hydropyrolysis and deoxygenation as well as heat for the process. This result is exciting, because it presents us with an option to build integrated H{sub 2}Bioil processes sooner rather than later when the cost effective H{sub 2}, becomes available from a carbon-free energy source such as solar or nuclear. The H{sub 2}Bioil process and its integrated version with a small scale NG reformer have strong potential to be attractive on a small scale while being more efficient than any current biomass to liquid fuel process in operation.

  1. Local government energy management: liquid petroleum gas (LPG) as a motor vehicle fuel

    SciTech Connect (OSTI)

    McCoy, G.A.; Kerstetter, J.

    1983-10-01

    The retrofit or conversion of automotive engines to operate on liquid petroleum gas (LPG) or propane fuel is one of many potentially cost-effective strategies for reducing a local government's annual fleet operating and maintenance costs. The cost effectiveness of an LPG conversion decision is highly dependent on the initial conversion cost, vehicle type, current and projected fuel costs, vehicle fuel economy (miles per gallon), and yearly average mileage. A series of plots have been developed which indicate simple paybacks for the conversion of several vehicle types (passenger car, small and standard pickups, and two and three ton trucks) over a wide range of fuel economies and annual usage patterns. A simple payback of less than three years can be achieved for vehicles with poor fuel economy and high annual use. The figures provided in this report may be used by fleet management personnel as a screening tool to identify those passenger cars, small or standard pickups, or light duty trucks which are candidates for LPG conversion. In addition to examining the benefits of an LPG conversion, local governments should also consider the competing energy management strategies of downsizing, and the acquisition of fuel efficient, diesel powered vehicles.

  2. Liquid natural gas as a transportation fuel in the heavy trucking industry. Final technical report

    SciTech Connect (OSTI)

    Sutton, W.H.

    1997-06-30

    This report encompasses the second year of a proposed three year project with emphasis focused on fundamental research issues in Use of Liquid Natural Gas as a Transportation Fuel in the Heavy Trucking Industry. These issues may be categorized as (1) direct diesel replacement with LNG fuel, and (2) long term storage/utilization of LNG vent gases produced by tank storage and fueling/handling operation. The results of this work are expected to enhance utilization of LNG as a transportation fuel. The paper discusses the following topics: (A) Fueling Delivery to the Engine, Engine Considerations, and Emissions: (1) Atomization and/or vaporization of LNG for direct injection diesel-type natural gas engines; (2) Fundamentals of direct replacement of diesel fuel by LNG in simulated combustion; (3) Distribution of nitric oxide and emissions formation from natural gas injection; and (B) Short and long term storage: (1) Modification by partial direct conversion of natural gas composition for improved storage characteristics; (2) LNG vent gas adsorption and recovery using activate carbon and modified adsorbents; (3) LNG storage at moderate conditions.

  3. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research.

  4. Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

  5. Solid Oxide Fuel Cell Cathodes. Unraveling the Relationship Between Structure, Surface Chemistry and Oxygen Reduction

    SciTech Connect (OSTI)

    Gopalan, Srikanth

    2013-03-31

    In this work we have considered oxygen reduction reaction on LSM and LSCF cathode materials. In particular we have used various spectroscopic techniques to explore the surface composition, transition metal oxidation state, and the bonding environment of oxygen to understand the changes that occur to the surface during the oxygen reduction process. In a parallel study we have employed patterned cathodes of both LSM and LSCF cathodes to extract transport and kinetic parameters associated with the oxygen reduction process.

  6. An analytical model for studying effects of gas release from a failed fuel pin of a liquid-metal reactor

    SciTech Connect (OSTI)

    Shin, Y.W.

    1993-01-01

    A analytical model for describing dynamics of a gas bubble in the liquid sodium of a liquid-metal reactor as the result of failed fuel pins is discussed. A model to describe the coupled response of the liquid sodium surrounding the gas bubble is also discussed. The analysis method is programmed in a computer code and used to analyze some available experimental data, and the results are discussed.

  7. Interactions between liquid-water and gas-diffusion layers in polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Das, Prodip K.; Santamaria, Anthony D.; Weber, Adam Z.

    2015-06-11

    Over the past few decades, a significant amount of research on polymer-electrolyte fuel cells (PEFCs) has been conducted to improve performance and durability while reducing the cost of fuel cell systems. However, the cost associated with the platinum (Pt) catalyst remains a barrier to their commercialization and PEFC durability standards have yet to be established. An effective path toward reducing PEFC cost is making the catalyst layers (CLs) thinner thus reducing expensive Pt content. The limit of thin CLs is high gas-transport resistance and the performance of these CLs is sensitive to the operating temperature due to their inherent low water uptake capacity, which results in higher sensitivity to liquid-water flooding and reduced durability. Therefore, reducing PEFC's cost by decreasing Pt content and improving PEFC's performance and durability by managing liquid-water are still challenging and open topics of research. An overlooked aspect nowadays of PEFC water management is the gas-diffusion layer (GDL). While it is known that GDL's properties can impact performance, typically it is not seen as a critical component. In this work, we present data showing the importance of GDLs in terms of water removal and management while also exploring the interactions between liquid-water and GDL surfaces. The critical interface of GDL and gas-flow-channel in the presence of liquid-water was examined through systematic studies of adhesion forces as a function of water-injection rate for various GDLs of varying thickness. GDL properties (breakthrough pressure and adhesion force) were measured experimentally under a host of test conditions. Specifically, the effects of GDL hydrophobic (PTFE) content, thickness, and water-injection rate were examined to identify trends that may be beneficial to the design of liquid-water management strategies and next-generation GDL materials for PEFCs.

  8. Interactions between liquid-water and gas-diffusion layers in polymer-electrolyte fuel cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, Prodip K.; Santamaria, Anthony D.; Weber, Adam Z.

    2015-06-11

    Over the past few decades, a significant amount of research on polymer-electrolyte fuel cells (PEFCs) has been conducted to improve performance and durability while reducing the cost of fuel cell systems. However, the cost associated with the platinum (Pt) catalyst remains a barrier to their commercialization and PEFC durability standards have yet to be established. An effective path toward reducing PEFC cost is making the catalyst layers (CLs) thinner thus reducing expensive Pt content. The limit of thin CLs is high gas-transport resistance and the performance of these CLs is sensitive to the operating temperature due to their inherent lowmore » water uptake capacity, which results in higher sensitivity to liquid-water flooding and reduced durability. Therefore, reducing PEFC's cost by decreasing Pt content and improving PEFC's performance and durability by managing liquid-water are still challenging and open topics of research. An overlooked aspect nowadays of PEFC water management is the gas-diffusion layer (GDL). While it is known that GDL's properties can impact performance, typically it is not seen as a critical component. In this work, we present data showing the importance of GDLs in terms of water removal and management while also exploring the interactions between liquid-water and GDL surfaces. The critical interface of GDL and gas-flow-channel in the presence of liquid-water was examined through systematic studies of adhesion forces as a function of water-injection rate for various GDLs of varying thickness. GDL properties (breakthrough pressure and adhesion force) were measured experimentally under a host of test conditions. Specifically, the effects of GDL hydrophobic (PTFE) content, thickness, and water-injection rate were examined to identify trends that may be beneficial to the design of liquid-water management strategies and next-generation GDL materials for PEFCs.« less

  9. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2004-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  10. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2005-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of liquid transportation fuel and hydrogen from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, the Air Force Research Laboratory, the U.S. Army National Automotive Center (Tank & Automotive Command--TACOM), and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the six months of the subject contract from October 1, 2002 through March 31, 2003. The results are presented in thirteen detailed reports on research projects headed by various faculty members at each of the five CFFS Universities. Additionally, an Executive Summary has been prepared that summarizes the principal results of all of these projects during the six-month reporting period.

  11. Commercial demonstration of atmospheric medium BTU fuel gas production from biomass without oxygen the Burlington, Vermont Project

    SciTech Connect (OSTI)

    Rohrer, J.W.

    1995-12-31

    The first U.S. demonstration of a gas turbine operating on fuel gas produced by the thermal gasification of biomass occurred at Battelle Columbus Labs (BCL) during 1994 using their high throughput indirect medium Btu gasification Process Research Unit (PRU). Zurn/NEPCO was retained to build a commercial scale gas plant utilizing this technology. This plant will have a throughput rating of 8 to 12 dry tons per hour. During a subsequent phase of the Burlington project, this fuel gas will be utilized in a commercial scale gas turbine. It is felt that this process holds unique promise for economically converting a wide variety of biomass feedstocks efficiently into both a medium Btu (500 Btu/scf) gas turbine and IC engine quality fuel gas that can be burned in engines without modification, derating or efficiency loss. Others are currently demonstrating sub-commercial scale thermal biomass gasification processes for turbine gas, utilizing both atmospheric and pressurized air and oxygen-blown fluid bed processes. While some of these approaches hold merit for coal, there is significant question as to whether they will prove economically viable in biomass facilities which are typically scale limited by fuel availability and transportation logistics below 60 MW. Atmospheric air-blown technologies suffer from large sensible heat loss, high gas volume and cleaning cost, huge gas compressor power consumption and engine deratings. Pressurized units and/or oxygen-blown gas plants are extremely expensive for plant scales below 250 MW. The FERCO/BCL process shows great promise for overcoming the above limitations by utilizing an extremely high throughout circulation fluid bed (CFB) gasifier, in which biomass is fully devolitalized with hot sand from a CFB char combustor. The fuel gas can be cooled and cleaned by a conventional scrubbing system. Fuel gas compressor power consumption is reduced 3 to 4 fold verses low Btu biomass gas.

  12. Annular core liquid-salt cooled reactor with multiple fuel and blanket zones

    DOE Patents [OSTI]

    Peterson, Per F.

    2013-05-14

    A liquid fluoride salt cooled, high temperature reactor having a reactor vessel with a pebble-bed reactor core. The reactor core comprises a pebble injection inlet located at a bottom end of the reactor core and a pebble defueling outlet located at a top end of the reactor core, an inner reflector, outer reflector, and an annular pebble-bed region disposed in between the inner reflector and outer reflector. The annular pebble-bed region comprises an annular channel configured for receiving pebble fuel at the pebble injection inlet, the pebble fuel comprising a combination of seed and blanket pebbles having a density lower than the coolant such that the pebbles have positive buoyancy and migrate upward in said annular pebble-bed region toward the defueling outlet. The annular pebble-bed region comprises alternating radial layers of seed pebbles and blanket pebbles.

  13. Liquid fossil-fuel technology. Quarterly technical progress report, January-March 1983

    SciTech Connect (OSTI)

    Linville, B.

    1983-07-01

    Accomplishments for the quarter ending March 1983 are presented under the following headings: liquid fossil fuel cycle, processing, utilization, and project integration and technology transfer. Feature articles for this quarter are: (1) abandoned oil field reports issued; (2) oilfield water data bank report published; (3) microbial enhanced recovery report issued; (4) polymer-augmented project could be economic today; (5) carbon dioxide EOR estimates given; (6) BETC passes 65th milestone; and (7) fifty achievements for fifty years (1918-1968). BETC publications are also listed. (ATT)

  14. Liquid fuels from co-processing coal with bitumen or heavy oil: A review

    SciTech Connect (OSTI)

    Moschopedis, S.E.; Hepler, L.G.

    1987-01-01

    Coal, bitumen and heavy oil (and various pitches, resids, etc.) are similar in that they require more substantial treatment than does conventional light oil to yield useful liquid fuels. The authors provide a brief and selective review of technologies for liquefying coal, followed by consideration of co-processing coal with bitumen/heavy oil. Such co-processing may be considered as use of bitumen/heavy oil as a solvent and/or hydrogen donor in liquefaction of coal, or as the use of coal to aid upgrading bitumen/heavy oil.

  15. C1 CHEMISTRY FOR THE PRODUCTION OF ULTRA-CLEAN LIQUID TRANSPORTATION FUELS AND HYDROGEN

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-09-30

    The Consortium for Fossil Fuel Science (CFFS) is a research consortium with participants from the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University. The CFFS is conducting a research program to develop C1 chemistry technology for the production of clean transportation fuel from resources such as coal and natural gas, which are more plentiful domestically than petroleum. The processes under development will convert feedstocks containing one carbon atom per molecular unit into ultra clean liquid transportation fuels (gasoline, diesel, and jet fuel) and hydrogen, which many believe will be the transportation fuel of the future. These feedstocks include synthesis gas, a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. Some highlights of the results obtained during the first year of the current research contract are summarized as: (1) Terminal alkynes are an effective chain initiator for Fischer-Tropsch (FT) reactions, producing normal paraffins with C numbers {ge} to that of the added alkyne. (2) Significant improvement in the product distribution towards heavier hydrocarbons (C{sub 5} to C{sub 19}) was achieved in supercritical fluid (SCF) FT reactions compared to that of gas-phase reactions. (3) Xerogel and aerogel silica supported cobalt catalysts were successfully employed for FT synthesis. Selectivity for diesel range products increased with increasing Co content. (4) Silicoaluminophosphate (SAPO) molecular sieve catalysts have been developed for methanol to olefin conversion, producing value-added products such as ethylene and propylene. (5) Hybrid Pt-promoted tungstated and sulfated zirconia catalysts are very effective in cracking n-C{sub 36} to jet and diesel fuel; these catalysts will be tested for cracking of FT wax. (6) Methane, ethane, and propane are readily decomposed to pure hydrogen and carbon nanotubes using binary Fe-based catalysts containing Mo, Ni, or Pd in a single step non-oxidative reaction. (7) Partial dehydrogenation of liquid hydrocarbons (cyclohexane and methyl cyclohexane) has been performed using catalysts consisting of Pt and other metals on stacked-cone carbon nanotubes. (8) An understanding of the catalytic reaction mechanisms of the catalysts developed in the CFFS C1 program is being achieved by structural characterization using multiple techniques, including XAFS and Moessbauer spectroscopy, XRD, TEM, NMR, ESR, and magnetometry.

  16. Electrocatalytic Activity of Transition Metal Oxide-Carbon Composites for Oxygen Reduction in Alkaline Batteries and Fuel Cells

    SciTech Connect (OSTI)

    Malkhandi, S; Trinh, P; Manohar, AK; Jayachandrababu, KC; Kindler, A; Prakash, GKS; Narayanan, SR

    2013-06-07

    Conductive transition metal oxides (perovskites, spinels and pyrochlores) are attractive as catalysts for the air electrode in alkaline rechargeable metal-air batteries and fuel cells. We have found that conductive carbon materials when added to transition metal oxides such as calcium-doped lanthanum cobalt oxide, nickel cobalt oxide and calcium-doped lanthanum manganese cobalt oxide increase the electrocatalytic activity of the oxide for oxygen reduction by a factor of five to ten. We have studied rotating ring-disk electrodes coated with (a) various mass ratios of carbon and transition metal oxide, (b) different types of carbon additives and (c) different types of transition metal oxides. Our experiments and analysis establish that in such composite catalysts, carbon is the primary electro- catalyst for the two-electron electro-reduction of oxygen to hydroperoxide while the transition metal oxide decomposes the hydroperoxide to generate additional oxygen that enhances the observed current resulting in an apparent four-electron process. These findings are significant in that they change the way we interpret previous reports in the scientific literature on the electrocatalytic activity of various transition metal oxide- carbon composites for oxygen reduction, especially where carbon is assumed to be an additive that just enhances the electronic conductivity of the oxide catalyst. (C) 2013 The Electrochemical Society. All rights reserved.

  17. Preparation of low oxygen-to-metal mixed oxide fuels for the advanced fast reactor

    SciTech Connect (OSTI)

    Kato, Masato; Nakamichi, Shinya; Takano, Tatsuo

    2007-07-01

    The preparation process for homogeneous mixed oxide pellets with a precise O/M ratio was established. The process was used to prepare pellets for heat treatments in two stages which consisted of the sintering process at high oxygen potential and the annealing process done in the atmosphere of controlled oxygen partial pressure. In the annealing process, it was found that abnormal growth of pores and occurrence of cracks were caused inside the pellet, and it was necessary for prevention of the microstructure change to control the oxygen potential of the atmosphere. Mixed oxide pellets with minor actinides were fabricated by the process and were provided to irradiation tests. (authors)

  18. Effects of surface chemistry and microstructure of electrolyte on oxygen reduction kinetics of solid oxide fuel cells

    SciTech Connect (OSTI)

    Park, Joong Sun; An, Jihwan; Lee, Min Hwan; Prinz, Friedrich B.; Lee, Wonyoung

    2015-07-10

    In this study, we report systematic investigation of the surface properties of yttria-stabilized zirconia (YSZ) electrolytes with the control of the grain boundary (GB) density at the surface, and its effects on electrochemical activities. The GB density of thin surface layers deposited on single crystal YSZ substrates is controlled by changing the annealing temperature (750-1450 °C). Higher oxygen reduction reactions (ORR) kinetics is observed in samples annealed at lower temperatures. The higher ORR activity is ascribed to the higher GB density at the YSZ surface where 'mobile' oxide ion vacancies are more populated. Meanwhile, oxide ion vacancies concurrently created with yttrium segregation at the surface at the higher annealing temperature are considered inactive to oxygen incorporation reactions. Our results provide additional insight into the interplay between the surface chemistry, microstructures, and electrochemical activity. They potentially provide important guidelines for engineering the electrolyte electrode interfaces of solid oxide fuel cells for higher electrochemical performance.

  19. Microalgae as a source of liquid fuels. Final technical report. [200 references

    SciTech Connect (OSTI)

    Benemann, J.R.; Goebel, R.P.; Weissman, J.C.; Augenstein, D.C.

    1982-05-15

    The economics of liquid-fuels production from microalgae was evaluated. A detailed review of published economic analyses of microalgae biomass production revealed wide variations in the published costs, which ranged from several dollars per pound for existing commercial health-food production in the Far East, to less than .05/lb costs projected for microalgae biomass for fuel conversion. As little design information or specific cost data has been published, a credible cost estimate required the conceptual engineering design and cost estimating of microalgae to liquid-fuels processes. Two systems were analyzed, shallow (2 to 3'') covered ponds and deeper (1 ft) open ponds. Only the latter was selected for an in-depth analysis due to the many technical shortcomings of the former approach. Based on the cost analysis of a very simple and low cost process, the most optimistic costs extrapolated were about $60/barrel. These were based on many optimistic assumptions. Additional, more detailed, engieering and cost analyses would be useful. However, the major emphasis in future work in this area should be on demonstrating the basic premises on which this design was based: high productivity and oil content of microalgae strains that can dominate in open ponds and which can be harvested by a simple bioflocculation process. Several specific basic research needs were identified: (1) Fundamentals of species selection and control in open pond systems. Effects of environmental variables on species dominance is of particular interest. (2) Mechanisms of algae bioflocculation. (3) Photosynthetic pathways and efficiency under conditions of high lipid production. (4) Effects of non-steady state operating conditions, particularly pH (CO/sub 2/ availability), on productivity. 18 figures, 47 tables.

  20. An assessment of energy and environmental issues related to the use of gas-to-liquid fuels in transportation

    SciTech Connect (OSTI)

    Greene, D.L.

    1999-11-01

    Recent technological advances in processes for converting natural gas into liquid fuels, combined with a growing need for cleaner, low-sulfur distillate fuel to mitigate the environmental impacts of diesel engines have raised the possibility of a substantial global gas-to-liquids (G-T-L) industry. This report examines the implications of G-T-L supply for U.S. energy security and the environment. It appears that a G-T-L industry would increase competitiveness in world liquid fuels markets, even if OPEC states are major producers of G-T-L's. Cleaner G-T-L distillates would help reduce air pollution from diesel engines. Implications for greenhouse gas (GHG) emissions could be positive or negative, depending on the sources of natural gas, their alternative uses, and the degree of sequestration that can be achieved for CO{sub 2} emissions produced during the conversion process.

  1. An Assessment of Energy and Environmental Issues Related to the Use of Gas-to-Liquid Fuels in Transportation

    SciTech Connect (OSTI)

    Greene, D.L.

    1999-11-01

    Recent technological advances in processes for converting natural gas into liquid fuels, combined with a growing need for cleaner, low-sulfur distillate fuel to mitigate the environmental impacts of diesel engines have raised the possibility of a substantial global gas-to-liquids (G-T-L) industry. This report examines the implications of G-T-L supply for U.S. energy security and the environment. It appears that a G-T-L industry would increase competitiveness in world liquid fuels markets, even if OPEC states are major producers of G-T-L's. Cleaner G-T-L distillates would help reduce air pollution from diesel engines. Implications for greenhouse gas (GHG) emissions could be positive or negative, depending on the sources of natural gas, their alternative uses, and the degree of sequestration that can be achieved for CO2 emissions produced during the conversion process.

  2. C1 Chemistry for the Production of Ultra-Clean Liquid Transportation Fuels and Hydrogen

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2003-03-31

    Faculty and students from five universities--the University of Kentucky, University of Pittsburgh, University of Utah, West Virginia University, and Auburn University--are collaborating in a research program to develop C1 chemistry processes to produce ultra-clean liquid transportation fuels and hydrogen, the zero-emissions transportation fuel of the future. The feedstocks contain one carbon atom per molecular unit. They include synthesis gas (syngas), a mixture of carbon monoxide and hydrogen produced by coal gasification or reforming of natural gas, methane, methanol, carbon dioxide, and carbon monoxide. An important objective is to develop C1 technology for the production of transportation fuel from domestically plentiful resources such as coal, coalbed methane, and natural gas. An Industrial Advisory Board with representatives from Chevron-Texaco, Eastman Chemical, Conoco-Phillips, Energy International, the Department of Defense, and Tier Associates provides guidance on the practicality of the research. The current report presents results obtained in this research program during the first six months of the subject contract (DE-FC26-02NT-4159), from October 1, 2002 through March 31, 2003.

  3. Activity and Evolution of Vapor Deposited Pt-Pd Oxygen Reduction Catalysts for Solid Acid Fuel Cells

    SciTech Connect (OSTI)

    Papandrew, Alexander B; Chisholm, Calum R; Zecevic, strahinja; Veith, Gabriel M; Zawodzinski, Thomas A

    2013-01-01

    The performance of hydrogen fuel cells based on the crystalline solid proton conductor CsH2PO4 is circumscribed by the mass activity of platinum oxygen reduction catalysts in the cathode. Here we report on the first application of an alloy catalyst in a solid acid fuel cell, and demonstrate an activity 4.5 times greater than Pt at 0.8 V. These activity enhancements were obtained with platinum-palladium alloys that were vapor-deposited directly on CsH2PO4 at 210 C. Catalyst mass activity peaks at a composition of 84 at% Pd, though smaller activity enhancements are observed for catalyst compositions exceeding 50 at% Pd. Prior to fuel cell testing, Pd-rich catalysts display lattice parameter expansions of up to 2% due to the presence of interstitial carbon. After fuel cell testing, a Pt-Pd solid solution absent of lattice dilatation and depleted in carbon is recovered. The structural evolution of the catalysts is correlated with catalyst de-activation.

  4. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas. Final technical report

    SciTech Connect (OSTI)

    Not Available

    1993-02-01

    Through the mid-1980s, Air Products has brought the liquid phase approach to a number of other synthesis gas reactions where effective heat management is a key issue. In 1989, in response to DOE`s PRDA No. DE-RA22-88PC88805, Air Products proposed a research and development program entitled ``Synthesis of Dimethyl Ether and Alternative Fuels in the Liquid Phase from Coal Derived Syngas.`` The proposal aimed at extending the LPMEOH experience to convert coal-derived synthesis gas to other useful fuels and chemicals. The work proposed included development of a novel one-step synthesis of dimethyl ether (DME) from syngas, and exploration of other liquid phase synthesis of alternative fuel directly from syngas. The one-step DME process, conceived in 1986 at Air Products as a means of increasing syngas conversion to liquid products, envisioned the concept of converting product methanol in situ to DME in a single reactor. The slurry reactor based liquid phase technology is ideally suited for such an application, since the second reaction (methanol to DME) can be accomplished by adding a second catalyst with dehydration activity to the methanol producing reactor. An area of exploration for other alternative fuels directly from syngas was single-step slurry phase synthesis of hydrocarbons via methanol and DME as intermediates. Other possibilities included the direct synthesis of mixed alcohols and mixed ethers in a slurry reactor.

  5. Ambient pressure fuel cell system

    DOE Patents [OSTI]

    Wilson, Mahlon S.

    2000-01-01

    An ambient pressure fuel cell system is provided with a fuel cell stack formed from a plurality of fuel cells having membrane/electrode assemblies (MEAs) that are hydrated with liquid water and bipolar plates with anode and cathode sides for distributing hydrogen fuel gas and water to a first side of each one of the MEAs and air with reactant oxygen gas to a second side of each one of the MEAs. A pump supplies liquid water to the fuel cells. A recirculating system may be used to return unused hydrogen fuel gas to the stack. A near-ambient pressure blower blows air through the fuel cell stack in excess of reaction stoichiometric amounts to react with the hydrogen fuel gas.

  6. DEVELOPMENT OF METHODOLOGY AND FIELD DEPLOYABLE SAMPLING TOOLS FOR SPENT NUCLEAR FUEL INTERROGATION IN LIQUID STORAGE

    SciTech Connect (OSTI)

    Berry, T.; Milliken, C.; Martinez-Rodriguez, M.; Hathcock, D.; Heitkamp, M.

    2012-06-04

    This project developed methodology and field deployable tools (test kits) to analyze the chemical and microbiological condition of the fuel storage medium and determine the oxide thickness on the spent fuel basin materials. The overall objective of this project was to determine the amount of time fuel has spent in a storage basin to determine if the operation of the reactor and storage basin is consistent with safeguard declarations or expectations. This project developed and validated forensic tools that can be used to predict the age and condition of spent nuclear fuels stored in liquid basins based on key physical, chemical and microbiological basin characteristics. Key parameters were identified based on a literature review, the parameters were used to design test cells for corrosion analyses, tools were purchased to analyze the key parameters, and these were used to characterize an active spent fuel basin, the Savannah River Site (SRS) L-Area basin. The key parameters identified in the literature review included chloride concentration, conductivity, and total organic carbon level. Focus was also placed on aluminum based cladding because of their application to weapons production. The literature review was helpful in identifying important parameters, but relationships between these parameters and corrosion rates were not available. Bench scale test systems were designed, operated, harvested, and analyzed to determine corrosion relationships between water parameters and water conditions, chemistry and microbiological conditions. The data from the bench scale system indicated that corrosion rates were dependent on total organic carbon levels and chloride concentrations. The highest corrosion rates were observed in test cells amended with sediment, a large microbial inoculum and an organic carbon source. A complete characterization test kit was field tested to characterize the SRS L-Area spent fuel basin. The sampling kit consisted of a TOC analyzer, a YSI multiprobe, and a thickness probe. The tools were field tested to determine their ease of use, reliability, and determine the quality of data that each tool could provide. Characterization was done over a two day period in June 2011, and confirmed that the L Area basin is a well operated facility with low corrosion potential.

  7. Lance for fuel and oxygen injection into smelting or refining furnace

    DOE Patents [OSTI]

    Schlichting, Mark R. (Chesterton, IN)

    1994-01-01

    A furnace 10 for smelting iron ore and/or refining molten iron 20 is equipped with an overhead pneumatic lance 40, through which a center stream of particulate coal 53 is ejected at high velocity into a slag layer 30. An annular stream of nitrogen or argon 51 enshrouds the coal stream. Oxygen 52 is simultaneously ejected in an annular stream encircling the inert gas stream 51. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus 84 to react with carbon monoxide gas rising from slag layer 30, thereby adding still more heat to the furnace.

  8. Lance for fuel and oxygen injection into smelting or refining furnace

    DOE Patents [OSTI]

    Schlichting, M.R.

    1994-12-20

    A furnace for smelting iron ore and/or refining molten iron is equipped with an overhead pneumatic lance, through which a center stream of particulate coal is ejected at high velocity into a slag layer. An annular stream of nitrogen or argon enshrouds the coal stream. Oxygen is simultaneously ejected in an annular stream encircling the inert gas stream. The interposition of the inert gas stream between the coal and oxygen streams prevents the volatile matter in the coal from combusting before it reaches the slag layer. Heat of combustion is thus more efficiently delivered to the slag, where it is needed to sustain the desired reactions occurring there. A second stream of lower velocity oxygen can be delivered through an outermost annulus to react with carbon monoxide gas rising from slag layer, thereby adding still more heat to the furnace. 7 figures.

  9. Engineering Ralstonia eutropha for Production of Isobutanol (IBT) Motor Fuel from Carbon Dioxide, Hydrogen, and Oxygen Project Final Report

    SciTech Connect (OSTI)

    Sinskey, Anthony J.; Worden, Robert Mark; Brigham, Christopher; Lu, Jingnan; Quimby, John Westlake; Gai, Claudia; Speth, Daan; Elliott, Sean; Fei, John Qiang; Bernardi, Amanda; Li, Sophia; Grunwald, Stephan; Grousseau, Estelle; Maiti, Soumen; Liu, Chole

    2013-12-16

    This research project is a collaboration between the Sinskey laboratory at MIT and the Worden laboratory at Michigan State University. The goal of the project is to produce Isobutanol (IBT), a branched-chain alcohol that can serve as a drop-in transportation fuel, through the engineered microbial biosynthesis of Carbon Dioxide, Hydrogen, and Oxygen using a novel bioreactor. This final technical report presents the findings of both the biological engineering work at MIT that extended the native branched-chain amino acid pathway of the wild type Ralstonia eutropha H16 to perform this biosynthesis, as well as the unique design, modeling, and construction of a bioreactor for incompatible gasses at Michigan State that enabled the operational testing of the complete system. This 105 page technical report summarizing the three years of research includes 72 figures and 11 tables of findings. Ralstonia eutropha (also known as Cupriavidus necator) is a Gram-negative, facultatively chemolithoautotrophic bacteria. It has been the principle organism used for the study of polyhydroxybutyrate (PHB) polymer biosynthesis. The wild-type Ralstonia eutropha H16 produces PHB as an intracellular carbon storage material while under nutrient stress in the presence of excess carbon. Under this stress, it can accumulate approximately 80 % of its cell dry weight (CDW) as this intracellular polymer. With the restoration of the required nutrients, the cells are then able to catabolize this polymer. If extracted from the cell, this PHB polymer can be processed into biodegradable and biocompatible plastics, however for this research, it is the efficient metabolic pathway channeling the captured carbon that is of interest. R. eutropha is further unique in that it contains two carbon-fixation Calvin–Benson–Bassham cycle operons, two oxygen-tolerant hydrogenases, and several formate dehydrogenases. It has also been much studied for its ability in the presence of oxygen, to fix carbon dioxide into complex cellular molecules using the energy from hydrogen. In this research project, engineered strains of R. eutropha redirected the excess carbon from PHB storage into the production of isobutanol and 3-methyl-1-butanol (branched-chain higher alcohols). These branched-chain higher alcohols can be used directly as substitutes for fossil-based fuels and are seen as alternative biofuels to ethanol and biodiesel. Importantly, these alcohols have approximately 98 % of the energy content of gasoline, 17 % higher than the current gasoline additive ethanol, without impacting corn market production for feed or food. Unlike ethanol, these branched-chain alcohols have low vapor pressure, hygroscopicity, and water solubility, which make them readily compatible with the existing pipelines, gasoline pumps, and engines in our transportation infrastructure. While the use of alternative energies from solar, wind, geothermal, and hydroelectric has spread for stationary power applications, these energy sources cannot be effectively or efficiently employed in current or future transportation systems. With the ongoing concerns of fossil fuel availability and price stability over the long term, alternative biofuels like branched-chain higher alcohols hold promise as a suitable transportation fuel in the future. We showed in our research that various mutant strains of R. eutropha with isobutyraldehyde dehydrogenase activity, in combination with the overexpression of plasmid-borne, native branched-chain amino acid biosynthesis pathway genes and the overexpression of heterologous ketoisovalerate decarboxylase gene, would produce isobutanol and 3-methyl-1-butanol when initiated during nitrogen or phosphorus limitation. Early on, we isolated one mutant R. eutropha strain which produced over 180 mg/L branched-chain alcohols in flask culture while being more tolerant of isobutanol toxicity. After the targeted elimination of genes encoding several potential carbon sinks (ilvE, bkdAB, and aceE), the production titer of the improved to 270 mg/L isobutanol and 40 mg/L 3-methyl-1-butanol. Semicontinuous flask cultivation supplied the cells with sufficient nutrients while minimizing the toxicity caused by isobutanol. Under this cultivation, the R. eutropha mutant grew and produced more than 14 g/L branched-chain alcohols over the duration of 50 days. These results demonstrate that R. eutropha carbon flux can be redirected from PHB to branched-chain alcohols and that engineered R. eutropha can be cultivated over prolonged periods of time for product biosynthesis. While this bioengineering work was being done at the Sinskey laboratory at MIT, the researchers at the Worden laboratory at Michigan State were working on the design and construction of the required specialty bioreactor for incompatible gasses (BIG) that would allow the safe feeding of microbes on Carbon Dioxide, Hydrogen, and Oxygen without explosive results. The early design and assembly work in year 1 incorporated a novel microbubble generator to maximize the bioavailability of gasses within the system comprised of small scale hollow fiber reactors. The early success of the microbubble generator eliminated the need to investigate potentially toxic surfactants within the system. For operational control, the system design incorporated a Opto22-based control network. The researchers also selected the specific hollow fiber material suitable for the bioreactor application. A variety of commercially available hollow fiber membranes were compared with regard to their pore sizes, cell affinity, and potential interference to cell viability assays. The selected membrane with its spongy layer was then tested for diffusivity of O2 and CO2. The instrumented system was then fully assembled for experimentally measuring the heterotrophic growth rate of immobilized R. eutropha cells. The requisite procedures for inoculation, measurement, and cleaning were established enabling the system performance to be validated under controlled laboratory conditions. In year 2, the researchers completed the Opto22 based cross-platform control network, and the system’s communications across the Sartorius fermentation system and Bruker gas chromatograph was established via open platform communications (OPC) protocol. Using the revised system, measurements were taken of the R.eutropha cell growth rate and substrate mass transfer rate in the hollow fiber membrane. Several IBT recovery strategies were explored and resin adsorption was determined to be optimal solution for lab scale operations. The adsorption capacity of the resin column was then measured and IBT desorption using methanol has been demonstrated. With the growing body of experimental data in hand, mathematical models were constructed to demonstrate and map the cellular kinetics, mass transfer of heterotrophic and autotrophic substrates in the hollow fiber, and the adsorption process in the resin column. A structured kinetic model was constructed to describe the competition between cell mass generation and IBT production. The reactor was then scaled up from single fiber to a membrane area of 180 cm2 and then further to 1 ft2. In Year 3 of the research, the IBT mass transfer across the membrane was characterized within the system with experiments to empirically measure the IBT diffusion coefficient in the BIG spongy layer. Using the refined mathematical models, the researchers are now able to explain the experimental observations and predict bioreactor performance under a wide range of experimental conditions. The Big system is able to demonstrate continuous controlled operations with the integrated IBT recovery system. Both heterotrophic and autotrophic production have been shown during continuous operation with heterotrophic and autotrophic stages. Performance of BIG system has been measured during continuous run with alternating heterotrophic growth on fructose and autotrophic product formation on H2, CO2, and O2. Volumetric productivities of IBT at 325 mg/(L day) and of 3M1B at 50 mg/(L day) were achieved, which were comparable to that achieved under heterotrophic conditions. Using the mathematical model, researchers are able to predict system performance for scaled-up BIG system. The apparent diffusion coefficient of IBT in the spongy layer of XM-50 hollow fiber membranes has been measured at various lumen liquid flow rates. The experiment is simulated in COMSOL to validate the results. The constructed COMSOL model is able to simulate BIG system performance in both batch and continuous mode. Mathematical simulations of the system performance have been run to identify the most crucial operational conditions, identifying the rate-limiting factors in autotrophic production of IBT, and quantitating the rate of IBT catabolism. Investigations of the productivity of the production system have suggested and the modeling of the system has revealed a particular sensitivity to the catabolism of the produced IBT by the engineered R. eutropha. Experiments have been designed and executed to quantify the IBT catabolism of R. eutropha, which open up possibilities for further system improvements through future, targeted bioengineering of the strain. Finally, the researchers at Michigan State performed an economic analysis of the system, based on the collective results, and their findings are presented in full within the report.

  10. State-of-the-art processes for manufacturing synthetic liquid fuels via the Fischer-Tropsch synthesis

    SciTech Connect (OSTI)

    A.Y. Krylova; E.A. Kozyukov

    2007-12-15

    Processes for manufacturing synthetic liquid fuels on the basis of the Fischer-Tropsch synthesis from alternative feedstock (natural gas, coal, biomass of various origins, etc.) are surveyed. State-of-the-art technology, companies that offer such processes, and the quality of products in comparison with their oil analogs, as well as economic features of the processes, are considered.

  11. Capacity Enhancement of Aqueous Borohydride Fuels for hydrogen storage in liquids

    SciTech Connect (OSTI)

    Schubert, David M.; Neiner, Doinita; Bowden, Mark E.; Whittemore, Sean M.; Holladay, Jamelyn D.; Huang, Zhenguo; Autrey, Thomas

    2015-10-05

    In this work we demonstrate enhanced hydrogen storage capacities through increased solubility of sodium borate product species in aqueous media achieved by adjusting the sodium (NaOH) to boron (B(OH)3) ratio, i.e., M/B, to obtain a distribution of polyborate anions. For a 1:1 mole ratio of NaOH to B(OH)3, M/B = 1, the ratio of the hydrolysis product formed from NaBH4 hydrolysis, the sole borate species formed and observed by 11B NMR is sodium metaborate, NaB(OH)4. When the ratio is 1:3 NaOH to B(OH)3, M/B = 0.33, a mixture of borate anions is formed and observed as a broad peak in the 11B NMR spectrum. The complex polyborate mixture yields a metastable solution that is difficult to crystallize. Given the enhanced solubility of the polyborate mixture formed when M/B = 0.33 it should follow that the hydrolysis of sodium octahydrotriborate, NaB3H8, can provide a greater storage capacity of hydrogen for fuel cell applications compared to sodium borohydride while maintaining a single phase. Accordingly, the hydrolysis of a 23 wt% NaB3H8 solution in water yields a solution having the same complex polyborate mixture as formed by mixing a 1:3 molar ratio of NaOH and B(OH)3 and releases >8 eq of H2. By optimizing the M/B ratio a complex mixture of soluble products, including B3O3(OH)52-, B4O5(OH)42-, B3O3(OH)4-, B5O6(OH)4- and B(OH)3, can be maintained as a single liquid phase throughout the hydrogen release process. Consequently, hydrolysis of NaB3H8 can provide a 40% increase in H2 storage density compared to the hydrolysis of NaBH4 given the decreased solubility of sodium metaborate. The authors would like to thank Jim Sisco and Paul Osenar of Protonex Inc. for useful discussion regarding liquid hydrogen storage materials for portable power applications and the U.S. DoE Office of Energy Efficiency and Renewable Energy Fuel Cell Technologies Office for their continued interest in liquid hydrogen storage carriers. Pacific Northwest National Laboratory is a multi-program national laboratory operated for DOE by Battelle. The authors dedicate the work to the memory of Professor Sheldon Shore. His contributions to boron hydride chemistry set the foundation for many who have followed.

  12. Low Cost High-H2 Syngas Production for Power and Liquid Fuels

    SciTech Connect (OSTI)

    Zhou, S. James

    2015-07-31

    This report summarizes the technical progress made of the research project entitled “Low Cost High-H2 Syngas Production for Power and Liquid Fuels,” under DOE Contract No. DE-FE-0011958. The period of performance was October 1, 2013 through July 30, 2015. The overall objectives of this project was to determine the technical and economic feasibility of a systems approach for producing high hydrogen syngas from coal with the potential to reduce significantly the cost of producing power, chemical-grade hydrogen or liquid fuels, with carbon capture to reduce the environmental impact of gasification. The project encompasses several areas of study and the results are summarized here. (1) Experimental work to determine the technical feasibility of a novel hybrid polymer/metal H2-membrane to recover pure H2 from a coal-derived syngas was done. This task was not successful. Membranes were synthesized and show impermeability of any gases at required conditions. The cause of this impermeability was most likely due to the densification of the porous polymer membrane support made from polybenzimidazole (PBI) at test temperatures above 250 °C. (2) Bench-scale experimental work was performed to extend GTI's current database on the University of California Sulfur Recovery Process-High Pressure (UCSRP-HP) and recently renamed Sulfur Removal and Recovery (SR2) process for syngas cleanup including removal of sulfur and other trace contaminants, such as, chlorides and ammonia. The SR2 process tests show >90% H2S conversion with outlet H2S concentrations less than 4 ppmv, and 80-90% ammonia and chloride removal with high mass transfer rates. (3) Techno-economic analyses (TEA) were done for the production of electric power, chemical-grade hydrogen and diesel fuels, from a mixture of coal- plus natural gas-derived syngas using the Aerojet Rocketdyne (AR) Advanced Compact coal gasifier and a natural gas partial oxidation reactor (POX) with SR2 technology. Due to the unsuccessful experimental results with the hybrid polymer/metal H2 membrane, a conventional CO2 capture (single-stage Selexol) and hydrogen purification (PSA) technologies were used in the appropriate cases. In all cases, the integrated system of Advanced Compact coal gasifier, non-catalytic natural gas partial oxidation, and SR2 multicontaminant removal with state-of-the-art auxiliary system provided a 5-25% cost advantage over the base line plants using GEE coal gasifier with conventional Selexol/Claus sulfur removal and recovery. These plants also produce 18-30% less CO2 than with the conventional coal gasification plants.

  13. Ionic liquids and ionic liquid acids with high temperature stability for fuel cell and other high temperature applications, method of making and cell employing same

    DOE Patents [OSTI]

    Angell, C. Austen; Xu, Wu; Belieres, Jean-Philippe; Yoshizawa, Masahiro

    2011-01-11

    Disclosed are developments in high temperature fuel cells including ionic liquids with high temperature stability and the storage of inorganic acids as di-anion salts of low volatility. The formation of ionically conducting liquids of this type having conductivities of unprecedented magnitude for non-aqueous systems is described. The stability of the di-anion configuration is shown to play a role in the high performance of the non-corrosive proton-transfer ionic liquids as high temperature fuel cell electrolytes. Performance of simple H.sub.2(g) electrolyte/O.sub.2(g) fuel cells with the new electrolytes is described. Superior performance both at ambient temperature and temperatures up to and above 200.degree. C. are achieved. Both neutral proton transfer salts and the acid salts with HSO.sup.-.sub.4 anions, give good results, the bisulphate case being particularly good at low temperatures and very high temperatures. The performance of all electrolytes is improved by the addition of a small amount of involatile base of pK.sub.a value intermediate between those of the acid and base that make the bulk electrolyte. The preferred case is the imidazole-doped ethylammonium hydrogensulfate which yields behavior superior in all respects to that of the industry standard phosphoric acid electrolyte.

  14. Solid Fuel - Oxygen Fired Combustion for Production of Nodular Reduced Iron to Reduce CO2 Emissions and Improve Energy Efficiencies

    SciTech Connect (OSTI)

    Donald R. Fosnacht; Richard F. Kiesel; David W. Hendrickson; David J. Englund; Iwao Iwasaki; Rodney L. Bleifuss; Mathew A. Mlinar

    2011-12-22

    The current trend in the steel industry is an increase in iron and steel produced in electric arc furnaces (EAF) and a gradual decline in conventional steelmaking from taconite pellets in blast furnaces. In order to expand the opportunities for the existing iron ore mines beyond their blast furnace customer base, a new material is needed to satisfy the market demands of the emerging steel industry while utilizing the existing infrastructure and materials handling capabilities. This demand creates opportunity to convert iron ore or other iron bearing materials to Nodular Reduced Iron (NRI) in a recently designed Linear Hearth Furnace (LHF). NRI is a metallized iron product containing 98.5 to 96.0% iron and 2.5 to 4% C. It is essentially a scrap substitute with little impurity that can be utilized in a variety of steelmaking processes, especially the electric arc furnace. The objective of this project was to focus on reducing the greenhouse gas emissions (GHG) through reducing the energy intensity using specialized combustion systems, increasing production and the use of biomass derived carbon sources in this process. This research examined the use of a solid fuel-oxygen fired combustion system and compared the results from this system with both oxygen-fuel and air-fuel combustion systems. The solid pulverized fuels tested included various coals and a bio-coal produced from woody biomass in a specially constructed pilot scale torrefaction reactor at the Coleraine Minerals Research Laboratory (CMRL). In addition to combustion, the application of bio-coal was also tested as a means to produce a reducing atmosphere during key points in the fusion process, and as a reducing agent for ore conversion to metallic iron to capture the advantage of its inherent reduced carbon footprint. The results from this study indicate that the approaches taken can reduce both greenhouse gas emissions and the associated energy intensity with the Linear Hearth Furnace process for converting iron ore to metallic iron nodules. Various types of coals including a bio-coal produced though torrefaction can result in production of NRI at reduced GHG levels. The process results coupled with earlier already reported developments indicate that this process technique should be evaluated at the next level in order to develop parameter information for full scale process design. Implementation of the process to full commercialization will require a full cost production analysis and comparison to other reduction technologies and iron production alternatives. The technical results verify that high quality NRI can be produced under various operating conditions at the pilot level.

  15. Development of Geothermally Assisted Process for Production of Liquid Fuels and Chemicals from Wheat Straw

    SciTech Connect (OSTI)

    Murphy, V.G.; Linden, J.C.; Moreira, A.R.; Lenz, T.G.

    1981-06-01

    Recently there has been much interest in developing processes for producing liquid fuels from renewable resources. The most logical long term approach in terms of economics derives the carbohydrate substrate for fermentation from the hydrolysis of cellulosic crop and forest residues rather than from grains or other high grade food materials (1,2). Since the presence of lignin is the main barrier to the hydrolysis of cellulose from lignocellulosic materials, delignification processes developed by the wood pulping industry have been considered as possible prehydrolysis treatments. The delignification process under study in our laboratory is envisioned as a synthesis of two recently developed pulping processes. In the first step, called autohydrolysis, hot water is used directly to solubilize hemicellulose and to depolymerize lignin (3). Then, in a second step known as organosolv pulping (4), the autohydrolyzed material is extracted with aqueous alcohol. A s shown in Figure 1, this process can separate the original lignocellulosic material into three streams--hemicellulose in water, lignin in aqueous alcohol, and a cellulose pulp. Without further mechanical milling, delignified cellulose can be enzymatically hydrolyzed at 45-50 C to greater than 80% theoretical yield of glucose using fungal cellulases (5, 6). The resulting glucose syrup can then be fermented by yeast to produce ethanol or by selected bacteria to produce acetone and butanol or acetic and propionic acids (7). One objection to such a process, however, is the large energy input that is required. In order to extend our supplies of liquid fuels and chemicals, it is important that the use of fossil fuels in any lignocellulosic conversion process be minimized. The direct use of geothermal hot water in carrying out the autohydrolysis and extraction operations, therefore, seems especially attractive. On the one hand, it facilitates the conversion of non-food biomass to fuels and chemicals without wasting fossil fuel; and on the other hand, it provides a means for ''exporting'' geothermal energy from the well site. The primary goal of the work discussed in this report was to investigate the effects of variations in autohydrolysis conditions on the production of fermentable sugars from wheat straw. In assessing the relative merits of various sets of conditions, we considered both the direct production of sugar from the autohydrolysis of hemicellulose and the subsequent yield from the enzymatic hydrolysis of cellulose. The principal parameters studied were time, temperature, and water/fiber weight ratio; however, we also investigated the effects of adding minor amounts of phenol and aluminum sulfate to the autohydrolysis charge. Phenol was selected for study because it was reported (8) to be effective in suppressing repolymerization of reactive lignin fragments. Aluminum sulfate, on the other hand, was chosen as a representative of the Lewis acids which, we hoped, would catalyze the delignification reactions.

  16. Comparative analysis of the production costs and life-cycle GHG emissions of FT liquid fuels from coal and natural gas

    SciTech Connect (OSTI)

    Paulina Jaramillo; W. Michael Griffin; H. Scott Matthews

    2008-10-15

    Liquid transportation fuels derived from coal and natural gas could help the United States reduce its dependence on petroleum. The fuels could be produced domestically or imported from fossil fuel-rich countries. The goal of this paper is to determine the life-cycle GHG emissions of coal- and natural gas-based Fischer-Tropsch (FT) liquids, as well as to compare production costs. The results show that the use of coal- or natural gas-based FT liquids will likely lead to significant increases in greenhouse gas (GHG) emissions compared to petroleum-based fuels. In a best-case scenario, coal- or natural gas-based FT-liquids have emissions only comparable to petroleum-based fuels. In addition, the economic advantages of gas-to-liquid (GTL) fuels are not obvious: there is a narrow range of petroleum and natural gas prices at which GTL fuels would be competitive with petroleum-based fuels. CTL fuels are generally cheaper than petroleum-based fuels. However, recent reports suggest there is uncertainty about the availability of economically viable coal resources in the United States. If the U.S. has a goal of increasing its energy security, and at the same time significantly reducing its GHG emissions, neither CTL nor GTL consumption seem a reasonable path to follow. 28 refs., 2 figs., 4 tabs.

  17. Synthesis of oxygenate products for high volume fuels applications. Quarterly technical progress report, November 1, 1994--January 31, 1995

    SciTech Connect (OSTI)

    1995-03-08

    The objective of this project is to develop high yield syntheses of oxygenate products that are liquid at room temperature using as starting materials dimethy ether (DME) or methanol. The identified products include: Dimethyl Carbonate (DMC), 1,1-Dimethoxyethane (DMOE), C{sub 2}{sup +} Alcohols/Ethers (C{sub 2}AE). The technical strategy is outlined below: (A) Synthesis of DMC via oxidative carbonylation of DME instead of methanol. Since this synthesis would not co-produce water as a byproduct, there is a potential for very high DME conversions in contrast to the low (ca 20%) conversions obtained in conventional plants. Technical emphasis will be placed on development of a supported copper catalyst with a capability for cleavage of DME into its chemisorbed organic moieties. (B) Synthesis of 1,1-dimethoxymethane (DMOE) from acetylene/CO/H{sub 2} process streams obtained from commercial methane oxidative pyrolysis processes. In the overall processing scheme the syngas would be converted to DME. The wet acetylene stream would be partially condensed to retain an equivalent of water and then condensed with DME to produce EMOE. (C) Direct conversion of DME or DME/methanol to ethanol/propanol or their methyl ethers. Under the influence of functionalized alcohol condensation catalysts developed exclusively at Amoco it should be possible to achieve direct conversion of dimethyl ether (or methanol) to ethanol/propanol and/or the methyl ethers of these alcohols. Although this reaction is not currently known, a combination of key catalyst components from identified systems should result in a DME conversion catalyst to C{sub 2}+ oxygenates. (D) Reaction of DME or acetylene with synthesis gas (CO/H{sub 2}) or methanol. A variety of catalysts will be tested for conversion of acetylene/CO/H{sub 2} or acetylene/methanol to propylene and conversion of DME/CO/H{sub 2} or DME/methanol to dimenthyoxymethane (DMM) and/or other oxygenates.

  18. Effects of surface chemistry and microstructure of electrolyte on oxygen reduction kinetics of solid oxide fuel cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Park, Joong Sun; An, Jihwan; Lee, Min Hwan; Prinz, Friedrich B.; Lee, Wonyoung

    2015-07-10

    In this study, we report systematic investigation of the surface properties of yttria-stabilized zirconia (YSZ) electrolytes with the control of the grain boundary (GB) density at the surface, and its effects on electrochemical activities. The GB density of thin surface layers deposited on single crystal YSZ substrates is controlled by changing the annealing temperature (750-1450 °C). Higher oxygen reduction reactions (ORR) kinetics is observed in samples annealed at lower temperatures. The higher ORR activity is ascribed to the higher GB density at the YSZ surface where 'mobile' oxide ion vacancies are more populated. Meanwhile, oxide ion vacancies concurrently created withmore » yttrium segregation at the surface at the higher annealing temperature are considered inactive to oxygen incorporation reactions. Our results provide additional insight into the interplay between the surface chemistry, microstructures, and electrochemical activity. They potentially provide important guidelines for engineering the electrolyte electrode interfaces of solid oxide fuel cells for higher electrochemical performance.« less

  19. Computational analysis of a three-dimensional High-Velocity Oxygen-Fuel (HVOF) Thermal Spray torch

    SciTech Connect (OSTI)

    Hassan, B.; Lopez, A.R.; Oberkampf, W.L.

    1995-07-01

    An analysis of a High-Velocity Oxygen-Fuel Thermal Spray torch is presented using computational fluid dynamics (CFD). Three-dimensional CFD results are presented for a curved aircap used for coating interior surfaces such as engine cylinder bores. The device analyzed is similar to the Metco Diamond Jet Rotating Wire torch, but wire feed is not simulated. To the authors` knowledge, these are the first published 3-D results of a thermal spray device. The feed gases are injected through an axisymmetric nozzle into the curved aircap. Argon is injected through the center of the nozzle. Pre-mixed propylene and oxygen are introduced from an annulus in the nozzle, while cooling air is injected between the nozzle and the interior wall of the aircap. The combustion process is modeled assuming instantaneous chemistry. A standard, two-equation, K-{var_epsilon} turbulence model is employed for the turbulent flow field. An implicit, iterative, finite volume numerical technique is used to solve the coupled conservation of mass, momentum, and energy equations for the gas in a sequential manner. Flow fields inside and outside the aircap are presented and discussed.

  20. Proceedings of the 6. international conference on stability and handling of liquid fuels. Volume 1

    SciTech Connect (OSTI)

    Giles, H.N.

    1998-12-01

    Volume 1 of these proceedings contain 29 papers related to aviation fuels and long term and strategic storage. Studies investigated fuel contamination, separation processes, measurement techniques, thermal stability, compatibility with fuel system materials, oxidation reactions, and degradation during storage.

  1. Method for providing oxygen ion vacancies in lanthanide oxides

    DOE Patents [OSTI]

    Kay, D. Alan R.; Wilson, William G.

    1989-12-05

    A method for desulfurization of fuel gases resulting from the incomplete combustion of sulfur containing hydrocarbons whereby the gases are treated with lanthanide oxides containing large numbers of oxygen-ion vacancies providing ionic porosity which enhances the ability of the lanthanide oxides to react more rapidly and completely with the sulfur in the fuel gases whereby the sulfur in such gases is reduced to low levels suitable for fuels for firing into boilers of power plants generating electricity with steam turbine driven generators, gas turbines, fuel cells and precursors for liquid fuels such as methanol and the like.

  2. Liquid phase fluid dynamic (methanol) run in the LaPorte alternative fuels development unit

    SciTech Connect (OSTI)

    Bharat L. Bhatt

    1997-05-01

    A fluid dynamic study was successfully completed in a bubble column at DOE's Alternative Fuels Development Unit (AFDU) in LaPorte, Texas. Significant fluid dynamic information was gathered at pilot scale during three weeks of Liquid Phase Methanol (LPMEOJP) operations in June 1995. In addition to the usual nuclear density and temperature measurements, unique differential pressure data were collected using Sandia's high-speed data acquisition system to gain insight on flow regime characteristics and bubble size distribution. Statistical analysis of the fluctuations in the pressure data suggests that the column was being operated in the churn turbulent regime at most of the velocities considered. Dynamic gas disengagement experiments showed a different behavior than seen in low-pressure, cold-flow work. Operation with a superficial gas velocity of 1.2 ft/sec was achieved during this run, with stable fluid dynamics and catalyst performance. Improvements included for catalyst activation in the design of the Clean Coal III LPMEOH{trademark} plant at Kingsport, Tennessee, were also confirmed. In addition, an alternate catalyst was demonstrated for LPMEOH{trademark}.

  3. System dynamics of the competition of municipal solid waste to landfill, electricity, and liquid fuel in California

    SciTech Connect (OSTI)

    Westbrook, Jessica; Malczynski, Leonard A.; Manley, Dawn Kataoka

    2014-03-01

    A quantitative system dynamics model was created to evaluate the economic and environmental tradeoffs between biomass to electricity and to liquid fuel using MSW biomass in the state of California as a case study. From an environmental perspective, landfilling represents the worst use of MSW over time, generating more greenhouse gas (GHG) emissions compared to converting MSW to liquid fuel or to electricity. MSW to ethanol results in the greatest displacement of GHG emissions per dollar spent compared to MSW to electricity. MSW to ethanol could save the state of California approximately $60 billion in energy costs by 2050 compared to landfilling, while also reducing GHG emissions state-wide by approximately 140 million metric tons during that timeframe. MSW conversion to electricity creates a significant cost within the state's electricity sector, although some conversion technologies are cost competitive with existing renewable generation.

  4. Modifying woody plants for efficient conversion to liquid and gaseous fuels

    SciTech Connect (OSTI)

    Dinus, R.J.; Dimmel, D.R.; Feirer, R.P.; Johnson, M.A.; Malcolm, E.W. )

    1990-07-01

    The Short Rotation Woody Crop Program (SRWCP), Department of Energy, is developing woody plant species as sources of renewable energy. Much progress has been made in identifying useful species, and testing site adaptability, stand densities, coppicing abilities, rotation lengths, and harvesting systems. Conventional plant breeding and intensive cultural practices have been used to increase above-ground biomass yields. Given these and foreseeable accomplishments, program leaders are now shifting attention to prospects for altering biomass physical and chemical characteristics, and to ways for improving the efficiency with which biomass can be converted to gaseous and liquid fuels. This report provides a review and synthesis of literature concerning the quantity and quality of such characteristics and constituents, and opportunities for manipulating them via conventional selection and breeding and/or molecular biology. Species now used by SRWCP are emphasized, with supporting information drawn from others as needed. Little information was found on silver maple (Acer saccharinum), but general comparisons (Isenberg 1981) suggest composition and behavior similar to those of the other species. Where possible, conclusions concerning means for and feasibility of manipulation are given, along with expected impacts on conversion efficiency. Information is also provided on relationships to other traits, genotype X environment interactions, and potential trade-offs or limitations. Biomass productivity per se is not addressed, except in terms of effects that may by caused by changes in constituent quality and/or quantity. Such effects are noted to the extent they are known or can be estimated. Likely impacts of changes, however effected, on suitability or other uses, e.g., pulp and paper manufacture, are notes. 311 refs., 4 figs., 9 tabs.

  5. Direct Observation of the Oxygenated Species during Oxygen Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray ...

  6. Proceedings of the 6. international conference on stability and handling of liquid fuels. Volume 2

    SciTech Connect (OSTI)

    Giles, H.N.

    1998-12-01

    Volume 2 of these proceedings contain 42 papers arranged under the following topical sections: Fuel blending and compatibility; Middle distillates; Microbiology; Alternative fuels; General topics (analytical methods, tank remediation, fuel additives, storage stability); and Poster presentations (analysis methods, oxidation kinetics, health problems).

  7. Cladding inner surface wastage for mixed-oxide liquid metal reactor fuel pins

    SciTech Connect (OSTI)

    Lawrence, L.A.; Bard, F.E.; Cannon, N.S.

    1990-11-01

    Cladding inner surface wastage was measured on reference fuel pins with stainless steel and D9 cladding irradiated beyond goal burnup in the Fast Flux Test Facility. Measurements were compared to the Experimental Breeder Reactor No. 2 based fuel-cladding chemical interaction correlation developed for uranium-plutonium oxide fuels with 20% cold-worked stainless steel cladding. The fuel-cladding chemical interaction was also measured in fuel pins irradiated with HT9 cladding. Comparison of the measurements with the design correlation showed the correlation adequately accounted for the extent of interaction in the Fast Flux Test Facility fuel pins with cold-worked stainless steel D9, and HT9 cladding. 9 refs., 6 figs.

  8. A Life-Cycle Assessment Comparing Select Gas-to-Liquid Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... VOC's, CO ) for many fuel pathways. * Process Industries Modeling System (PIMS) Model - ... for the Reduction and Assessment of Chemical and Other Environmental Impacts (TRACI ...

  9. The effect of oxygen-to-fuel stoichiometry on coal ash fine-fragmentation mode formation mechanisms.

    SciTech Connect (OSTI)

    Fix, G.; Seames, W. S.; Mann, M. D.; Benson, S. A.; Miller, D. J.

    2011-04-01

    Ash particles smaller than 2.5 {micro}m in diameter generated during pulverized coal combustion are difficult to capture and may pose greater harm to the environment and human health than the discharge of larger particles. Recent research efforts on coal ash formation have revealed a middle fine-fragment mode centered around 2 {micro}m. Formation of this middle or fine-fragment mode (FFM) is less well understood compared to larger coarse and smaller ultrafine ash. This study is part of an overall effort aimed at determining the key factors that impact the formation of FFM. This work examined the effects of oxygen-to-fuel stoichiometry (OFS). Pulverized Illinois No.6 bituminous coal was combusted and the ash generated was size segregated in a Dekati low pressure inertial impactor. The mass of each fraction was measured and the ash was analyzed using scanning electron microscopy (SEM) and X-ray microanalysis. The FFM ash types were classified based on the SEM images to evaluate the significant fine-fragment ash formation mechanisms and determine any possible link between stoichiometry and formation mechanism. From the particle size distributions (PSDs), the coarse mode appears unaffected by the change in OFS, however, the OFS 1.05 lowered the fraction of ultrafine ash in relation to the higher OFS settings, and appears to increase the portion of the FFM. An intermediate minimum was found in the FFM at 1.3 {micro}m for the 1.20 and 1.35 OFS tests but was not observed in the 1.05 OFS. SEM analysis also suggests that OFS may contribute to changing formation mechanisms.

  10. Literature search for the non-aqueous separation of zinc from fuel rod cladding. [After dissolution in liquid metal

    SciTech Connect (OSTI)

    Sandvig, R. L.; Dyer, S. J.; Lambert, G. A.; Baldwin, C. E.

    1980-06-21

    This report reviews the literature of processes for the nonaqueous separation of zinc from dissolved fuel assembly cladding. The processes considered were distillation, pyrochemical processing, and electrorefining. The last two techniques were only qualitatively surveyed while the first, distillation, was surveyed in detail. A survey of available literature from 1908 through 1978 on the distillation of zinc was performed. The literature search indicated that a zinc recovery rate in excess of 95% is possible; however, technical problems exist because of the high temperatures required and the corrosive nature of liquid zinc. The report includes a bibliography of the surveyed literature and a computer simulation of vapor pressures in binary systems. 129 references.

  11. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 31 for fourth quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  12. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 19 for first quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  13. Direct conversion of light hydrocarbon gases to liquid fuel. Quarterly technical status report No. 23 for second quarter FY 1991

    SciTech Connect (OSTI)

    Foral, M.J.

    1991-12-31

    The objective of this program is to investigate the direct conversion of light gaseous hydrocarbons, such as those produced during Fischer-Tropsch synthesis or as a product of gasification, to liquid transportation fuels via a partial oxidation process. The process will be tested in an existing pilot plant to obtain credible mass balances. Specific objectives to be met include determination of optimal process conditions, investigation of various processing options (e.g. feed injection, product quench, and recycle systems), and evaluation of an enhanced yield thermal/catalytic system. Economic evaluation of the various options will be performed as experimental data become available.

  14. Algae: The Source of Reliable, Scalable, and Sustainable Liquid Transportation Fuels

    Broader source: Energy.gov [DOE]

    At the February 12, 2009 joint Web conference of DOE's Biomass and Clean Cities programs, Brian Goodall (Sapphire Energy) spoke on Continental Airlines’ January 7th Biofuels Test. The flight was fueled, in part, by Sapphire’s algae-based jet fuel.

  15. Production of liquid fuels out of plant biomass and refuse: Methods, cost, potential

    SciTech Connect (OSTI)

    Woick, B.; Friedrich, R.

    1981-09-01

    Different ways of producing biomass and its conversion into high grade fuel for vehicles are reviewed with particular reference to physical and geographical factors, pertaining in the Federal Republic of Germany (FRG). Even with the potentially small amount of biomass in the FRG, the fueling of diesel engines with rape oil or modified ethanol, which can be obtained from any cellulosic feedstock, seems to pose the fewest difficulties and promises greatest efficiency. However, the amount of fuel produced from biomass can probably only meet a very small percentage of the total amount required.

  16. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  17. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  18. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650[degrees]F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  19. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01

    The R&D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650{degrees}F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  20. EA-1850: Flambeau River BioFuels, Inc. Proposed Wood Biomass-to-Liquid Fuel Biorefinery, Park Falls, Wisconsin

    Broader source: Energy.gov [DOE]

    NOTE: This EA has been cancelled. This EA will evaluate the environmental impacts of a proposal to provide federal funding to Flambeau River Biofuels (FRB) to construct and operate a biomass-to-liquid biorefinery in Park Falls, Wisconsin, on property currently used by Flambeau Rivers Paper, LLC (FRP) for a pulp and paper mill and Johnson Timber Corporation's (JTC) Summit Lake Yard for timber storage. This project would design a biorefinery which would produce up to 1,150 barrels per day (bpd) of clean syncrude. The biorefinery would also supply steam to the FRP mill, meeting the majority of the mill's steam demand and reducing or eliminating the need for the existing biomass/coal-fired boiler. The biorefinery would also include a steam turbine generator that will produce "green" electrical power for use by the biorefinery or for sale to the electric utility.

  1. Development of a Liquid to Compressed Natural Gas (LCNG) Fueling Station. Final Report

    SciTech Connect (OSTI)

    Moore, J. A.

    1999-06-30

    The program objective was the development of equipment and processes to produce compressed natural gas (CNG) from liquified natural gas (LNG) for heavy duty vehicular applications. The interest for this technology is a result of the increased use of alternative fuels for the reduction of emissions and dependency of foreign energy. Technology of the type developed under this program is critical for establishing natural gas as an economical alternative fuel.

  2. Fuel cell electric power production

    DOE Patents [OSTI]

    Hwang, Herng-Shinn; Heck, Ronald M.; Yarrington, Robert M.

    1985-01-01

    A process for generating electricity from a fuel cell includes generating a hydrogen-rich gas as the fuel for the fuel cell by treating a hydrocarbon feed, which may be a normally liquid feed, in an autothermal reformer utilizing a first monolithic catalyst zone having palladium and platinum catalytic components therein and a second, platinum group metal steam reforming catalyst. Air is used as the oxidant in the hydrocarbon reforming zone and a low oxygen to carbon ratio is maintained to control the amount of dilution of the hydrogen-rich gas with nitrogen of the air without sustaining an insupportable amount of carbon deposition on the catalyst. Anode vent gas may be utilized as the fuel to preheat the inlet stream to the reformer. The fuel cell and the reformer are preferably operated at elevated pressures, up to about a pressure of 150 psia for the fuel cell.

  3. Recent developments in the production of liquid fuels via catalytic conversion of microalgae: experiments and simulations

    SciTech Connect (OSTI)

    Shi,Fan; Wang, Pin; Duan, Yuhua; Link, Dirk; Morreale, Bryan

    2012-01-01

    Due to continuing high demand, depletion of non-renewable resources and increasing concerns about climate change, the use of fossil fuel-derived transportation fuels faces relentless challenges both from a world markets and an environmental perspective. The production of renewable transportation fuel from microalgae continues to attract much attention because of its potential for fast growth rates, high oil content, ability to grow in unconventional scenarios, and inherent carbon neutrality. Moreover, the use of microalgae would minimize ‘‘food versus fuel’’ concerns associated with several biomass strategies, as microalgae do not compete with food crops in the food chain. This paper reviews the progress of recent research on the production of transportation fuels via homogeneous and heterogeneous catalytic conversions of microalgae. This review also describes the development of tools that may allow for a more fundamental understanding of catalyst selection and conversion processes using computational modelling. The catalytic conversion reaction pathways that have been investigated are fully discussed based on both experimental and theoretical approaches. Finally, this work makes several projections for the potential of various thermocatalytic pathways to produce alternative transportation fuels from algae, and identifies key areas where the authors feel that computational modelling should be directed to elucidate key information to optimize the process.

  4. Structured catalyst bed and method for conversion of feed materials to chemical products and liquid fuels

    DOE Patents [OSTI]

    Wang, Yong (Richland, WA), Liu; Wei (Richland, WA)

    2012-01-24

    The present invention is a structured monolith reactor and method that provides for controlled Fischer-Tropsch (FT) synthesis. The invention controls mass transport limitations leading to higher CO conversion and lower methane selectivity. Over 95 wt % of the total product liquid hydrocarbons obtained from the monolithic catalyst are in the carbon range of C.sub.5-C.sub.18. The reactor controls readsorption of olefins leading to desired products with a preselected chain length distribution and enhanced overall reaction rate. And, liquid product analysis shows readsorption of olefins is reduced, achieving a narrower FT product distribution.

  5. Temperature, Oxygen, and Soot-Volume-Fraction Measurements in a Turbulent C2H4-Fueled Jet Flame

    SciTech Connect (OSTI)

    Kearney, Sean P.; Guildenbecher, Daniel Robert; Winters, Caroline; Farias, Paul Abraham; Grasser, Thomas W.; Hewson, John C.

    2015-09-01

    We present a detailed set of measurements from a piloted, sooting, turbulent C 2 H 4 - fueled diffusion flame. Hybrid femtosecond/picosecond coherent anti-Stokes Raman scattering (CARS) is used to monitor temperature and oxygen, while laser-induced incandescence (LII) is applied for imaging of the soot volume fraction in the challenging jet-flame environment at Reynolds number, Re = 20,000. Single-laser shot results are used to map the mean and rms statistics, as well as probability densities. LII data from the soot-growth region of the flame are used to benchmark the soot source term for one-dimensional turbulence (ODT) modeling of this turbulent flame. The ODT code is then used to predict temperature and oxygen fluctuations higher in the soot oxidation region higher in the flame.

  6. Review of the SIMMER-II analyses of liquid-metal-cooled fast breeder reactor core-disruptive accident fuel escape

    SciTech Connect (OSTI)

    DeVault, G.P.; Bell, C.R.

    1985-01-01

    Early fuel removal from the active core of a liquid-metal-cooled fast breeder reactor undergoing a core-disruptive accident may reduce the potential for large energetics resulting from recriticalities. This paper presents a review of analyses with the SIMMER-II computer program of the effectiveness of possible fuel escape paths. Where possible, how SIMMER-II compares with or is validated against experiments that simulated the escape paths also is discussed.

  7. Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fueling the Next Generation of Vehicle Technology Fueling the Next Generation of Vehicle Technology February 6, 2013 - 11:20am Addthis Professor Jack Brouwer, Associate Director and Chief Technology Officer of the National Fuel Cell Research Center, points out the tri-generation facility that uses biogas from Orange County Sanitation District’s wastewater treatment plant to produce hydrogen, heat and power. | Photo courtesy of the Energy Department. Professor Jack Brouwer, Associate

  8. In Situ Grouting of Liquid Waste Disposal Trenches and Experimental Reactor Fuel Disposal Wells at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Johnson, Ch.; Cange, J.; Lambert, R. [Bechtel Jacobs Company, LLC, Oak Ridge, TN (United States); Trujillo, E. [BWXT Pantex, LLC, Amarillo, TX (United States); Julius, J. [U.S. DOE, Oak Ridge Operations Office, Oak Ridge, TN (United States)

    2008-07-01

    In the early to mid-1960's, liquid low-level wastes (LLLW) generated at Oak Ridge National Laboratory were disposed of in specially-constructed, gravel-filled trenches within the Melton Valley watershed at the lab. The initial selected remedy for Trenches 5 and 7 was in situ vitrification; however, an amendment to the record of decision changed the remedy to in situ grouting of the trenches. The work was accomplished by filling the void space within the crushed stone section of each trench with cementitious grout. The contaminated soil surrounding the trenches (1-m perimeter) was then grouted with acrylamide grout. At the HRE fuel wells, a 1-m ring of soil surrounding the fuel wells was grouted with acrylamide. The results of the hydraulic conductivity tests ranged from 4.74 x 10{sup -6} to 3.60 x 10{sup -7} cm/sec, values that were well below the 1 x 10{sup -5} cm/sec design criterion. In summary: The ISG Project was conducted to decrease hydraulic conductivity and thereby decrease water flow and contaminate migration from the area of the trenches. The initial remedy for Trenches 5 and 7 in the Melton Valley ROD was for in situ vitrification of the trench matrix. The remedy was changed to in situ grouting of the trenches and HRE fuel wells through an amendment to the ROD after moisture was found in the trenches. The grouting of the trenches was accomplished by filling the void space within the crushed stone section of each trench with cementitious grout. The contaminated soil surrounding the trenches (1-m perimeter) was then grouted with acrylamide grout to further reduce water infiltration. Soil backfill above each of the seven HRE fuel wells was removed to a depth of approximately 1 m by augering, and the soils were replaced with a cement plug to prevent water infiltration from migrating down the original borehole. Soil surrounding the fuel wells was then grouted with acrylamide to ensure water infiltration through the HRE fuel wells is prevented. A summary of the quantities used is shown. After completion of grouting, in-situ hydraulic conductivities of the grouted materials were measured to verify attainment of the design objective. The areas were then covered with multi-layer caps as part of the MV hydrologic isolation project. (authors)

  9. Method of removing Pu(IV) polymer from nuclear fuel reclaiming liquid

    DOE Patents [OSTI]

    Tallent, Othar K.; Mailen, James C.; Bell, Jimmy T.; Arwood, Phillip C.

    1982-01-01

    A Pu(IV) polymer not extractable from a nuclear fuel reclaiming solution by conventional processes is electrolytically converted to Pu.sup.3+ and PuO.sub.2.sup.2+ ions which are subsequently converted to Pu.sup.4+ ions extractable by the conventional processes.

  10. FIELD-DEPLOYABLE SAMPLING TOOLS FOR SPENT NUCLEAR FUEL INTERROGATION IN LIQUID STORAGE

    SciTech Connect (OSTI)

    Berry, T.; Milliken, C.; Martinez-Rodriguez, M.; Hathcock, D.; Heitkamp, M.

    2012-09-12

    Methodology and field deployable tools (test kits) to analyze the chemical and microbiological condition of aqueous spent fuel storage basins and determine the oxide thickness on the spent fuel basin materials were developed to assess the corrosion potential of a basin. this assessment can then be used to determine the amount of time fuel has spent in a storage basin to ascertain if the operation of the reactor and storage basin is consistent with safeguard declarations or expectations and assist in evaluating general storage basin operations. The test kit was developed based on the identification of key physical, chemical and microbiological parameters identified using a review of the scientific and basin operations literature. The parameters were used to design bench scale test cells for additional corrosion analyses, and then tools were purchased to analyze the key parameters. The tools were used to characterize an active spent fuel basin, the Savannah River Site (SRS) L-Area basin. The sampling kit consisted of a total organic carbon analyzer, an YSI multiprobe, and a thickness probe. The tools were field tested to determine their ease of use, reliability, and determine the quality of data that each tool could provide. Characterization confirmed that the L Area basin is a well operated facility with low corrosion potential.

  11. Fuel pin

    DOE Patents [OSTI]

    Christiansen, David W. (Kennewick, WA); Karnesky, Richard A. (Richland, WA); Leggett, Robert D. (Richland, WA); Baker, Ronald B. (Richland, WA)

    1989-01-01

    A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

  12. Fuel pin

    DOE Patents [OSTI]

    Christiansen, D.W.; Karnesky, R.A.; Leggett, R.D.; Baker, R.B.

    1987-11-24

    A fuel pin for a liquid metal nuclear reactor is provided. The fuel pin includes a generally cylindrical cladding member with metallic fuel material disposed therein. At least a portion of the fuel material extends radially outwardly to the inner diameter of the cladding member to promote efficient transfer of heat to the reactor coolant system. The fuel material defines at least one void space therein to facilitate swelling of the fuel material during fission.

  13. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived synthesis gas

    SciTech Connect (OSTI)

    Bhatt, B.L.

    1992-09-01

    As part of the DOE-sponsored contract for the Synthesis of Dimethyl Ether (DME) and Alternative Fuels in the Liquid Phase from Coal- Derived Syngas, the single-step, slurry phase DME synthesis process was developed. The development involved screening of catalyst systems, process variable studies, and catalyst life studies in two 300 ml stirred autoclaves. As a spin-off of the Liquid Phase Methanol (LPMEOH*) process, the new process significantly improves the syngas conversion efficiency of the LPMEOH process. This improvement can be achieved by replacing a portion of methanol catalyst with a dehydration catalyst in the reactor, resulting in the product methanol being converted to DME, thus avoiding the thermodynamic equilibrium constraint of the methanol reaction. Overall, this increases syngas conversion per-pass. The selectivity and productivity of DME and methanol are affected by the catalyst system employed as well as operating conditions. A preferred catalyst system, consisting of a physical mixture of a methanol catalyst and a gamma alumina, was identified. An improvement of about 50% in methanol equivalent productivity was achieved compared to the LPMEOH process. Results from the process variable study indicate that higher pressure and CO[sub 2] removal benefit the process significantly. Limited life studies performed on the preferred catalyst system suggest somewhat higher than expected deactivation rate for the methanol catalyst. Several DME/methanol mixtures were measured for their key properties as transportation fuels. With small amounts of DME added, significant improvements in both flash points and Reid Vapor Pressure (RVP) were observed over the corresponding values of methanol alone.

  14. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Status of Ongoing DOE Bio-Derived Liquids to Hydrogen Distributed Reforming R&D ... Liquid Fuels, Arlene Anderson, DOE Fuel Cell Technologies Office Renewable Liquids ...

  15. Study concerning the utilization of the ocean spreading center environment for the conversion of biomass to a liquid fuel. (Includes Appendix A: hydrothermal petroleum genesis). [Supercritical water

    SciTech Connect (OSTI)

    Steverson, M.; Stormberg, G.

    1985-01-01

    This document contains a report on the feasibility of utilizing energy obtained from ocean spreading centers as process heat for the conversion of municipal solid wastes to liquid fuels. The appendix contains a paper describing hydrothermal petroleum genesis. Both have been indexed separately for inclusion in the Energy Data Base. (DMC)

  16. Production of chemicals and fuels from biomass

    DOE Patents [OSTI]

    Woods, Elizabeth M.; Qiao, Ming; Myren, Paul; Cortright, Randy D.; Kania, John

    2015-12-15

    Described are methods, reactor systems, and catalysts for converting biomass to fuels and chemicals in a batch and/or continuous process. The process generally involves the conversion of water insoluble components of biomass, such as hemicellulose, cellulose and lignin, to volatile C.sub.2+O.sub.1-2 oxygenates, such as alcohols, ketones, cyclic ethers, esters, carboxylic acids, aldehydes, and mixtures thereof. In certain applications, the volatile C.sub.2+O.sub.1-2 oxygenates can be collected and used as a final chemical product, or used in downstream processes to produce liquid fuels, chemicals and other products.

  17. Comparative Study on the Sulfur Tolerance and Carbon Resistance of Supported Noble Metal Catalysts in Steam Reforming of Liquid Hydrocarbon Fuel

    SciTech Connect (OSTI)

    Xie, Chao; Chen, Yongsheng; Engelhard, Mark H.; Song, Chunshan

    2012-04-18

    This work was conducted to clarify the influence of the type of metal and support on the sulfur tolerance and carbon resistance of supported noble metal catalysts in steam reforming of liquid hydrocarbons. Al2O3-supported noble metal catalysts (Rh, Ru, Pt, and Pd), Rh catalysts on different supports (Al2O3, CeO2, SiO2, and MgO), and Pt catalyst supported on CeO2 and Al2O3, were examined for steam reforming of a liquid hydrocarbon fuel (Norpar13 from Exxon Mobil) at 800 C for 55 h. The results indicate that (1) Rh/Al2O3 shows higher sulfur tolerance than the Ru, Pt, and Pd catalysts on the same support; (2) both Al2O3 and CeO2 are promising supports for Rh catalyst to process sulfur-containing hydrocarbons; and (3) Pt/CeO2 exhibits better catalytic performance than Pt/Al2O3 in the reaction with sulfur. TEM results demonstrate that the metal particles in Rh/Al2O3 were better dispersed (mostly in 1-3 nm) compared with the other catalysts after reforming the sulfur-containing feed. As revealed by XPS, the binding energy of Rh 3d for Rh/Al2O3 is notably higher than that for Rh/CeO2, implying the formation of electron-deficient Rh particles in the former. The strong sulfur tolerance of Rh/Al2O3 may be related to the formation of well-dispersed electron-deficient Rh particles on the Al2O3 support. Sulfur K-edge XANES illustrates the preferential formation of sulfonate and sulfate on Rh/Al2O3, which is believed to be beneficial for improving its sulfur tolerance as their oxygen-shielded sulfur structure may hinder direct Rh-S interaction. Due to its strong sulfur tolerance, the carbon deposition on Rh/Al2O3 was significantly lower than that on the Al2O3-supported Ru, Pt, and Pd catalysts after the reaction with sulfur. The superior catalytic performance of CeO2-supported Rh and Pt catalysts in the presence of sulfur can be ascribed mainly to the promotion effect of CeO2 on carbon gasification, leading to much lower carbon deposition compared with the Rh/Al2O3, Rh/MgO, Rh/SiO2 and Pt/Al2O3 catalysts.

  18. Alternative Fuels Data Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    alternative fuels are defined as methanol, ethanol, natural gas, liquefied petroleum gas (propane), coal-derived liquid fuels, hydrogen, electricity, biodiesel, renewable diesel,...

  19. Photoacoustically Measured Speeds of Sound of Liquid HBO2: On Unlocking the Fuel Potential of Boron

    SciTech Connect (OSTI)

    Bastea, S; Crowhurst, J; Armstrong, M; ., N T

    2010-03-24

    Elucidation of geodynamic, geochemical, and shock induced processes is often limited by challenges to accurately determine molecular fluid equations of state (EOS). High pressure liquid state reactions of carbon species underlie physiochemical mechanisms such as differentiation of planetary interiors, deep carbon sequestration, propellant deflagration, and shock chemistry. Here we introduce a versatile photoacoustic technique developed to measure accurate and precise speeds of sound (SoS) of high pressure molecular fluids and fluid mixtures. SoS of an intermediate boron oxide, HBO{sub 2} are measured up to 0.5 GPa along the 277 C isotherm. A polarized Exponential-6 interatomic potential form, parameterized using our SoS data, enables EOS determinations and corresponding semi-empirical evaluations of > 2000 C thermodynamic states including energy release from bororganic formulations. Our thermochemical model propitiously predicts boronated hydrocarbon shock Hugoniot results.

  20. Environmentally based siting assessment for synthetic-liquid-fuels facilities. Final report

    SciTech Connect (OSTI)

    1980-01-01

    A detailed assessment of the major environmental constraints to siting a synthetic fuels industry and the results of that assessment are used to determine on a regional basis the potential for development of such an industry with minimal environmental conflicts. Secondly, the ability to mitigate some of the constraining impacts through alternative institutional arrangements, especially in areas that are judged to have a low development potential is also assessed. Limitations of the study are delineated, but specifically, the study is limited geographically to well-defined boundaries that include the prime coal and oil shale resource areas. The critical factors used in developing the framework are air quality, water availability, socioeconomic capacity, ecological sensitivity, environmental health, and the management of Federally owned lands. (MCW)

  1. Pilot-Scale Demonstration of a Novel, Low-Cost Oxygen Supply Process and its Integration with Oxy-Fuel Coal-Fired Boilers

    SciTech Connect (OSTI)

    Krish Krishnamurthy; Divy Acharya; Frank Fitch

    2008-09-30

    In order to achieve DOE targets for carbon dioxide capture, it is crucial not only to develop process options that will generate and provide oxygen to the power cycle in a cost-effective manner compared to the conventional oxygen supply methods based on cryogenic air separation technology, but also to identify effective integration options for these new technologies into the power cycle with carbon dioxide capture. The Linde/BOC developed Ceramic Autothermal Recovery (CAR) process remains an interesting candidate to address both of these issues by the transfer of oxygen from the air to a recycled CO{sub 2} rich flue-gas stream in a cyclic process utilizing the high temperature sorption properties of perovskites. Good progress was made on this technology in this project, but significant challenges remain to be addressed before CAR oxygen production technology is ready for commercial exploitation. Phase 1 of the project was completed by the end of September 2008. The two-bed 0.7 tons/day O2 CAR process development unit (PDU) was installed adjacent to WRI's pilot scale coal combustion test facility (CTF). Start-up and operating sequences for the PDU were developed and cyclic operation of the CAR process demonstrated. Controlled low concentration methane addition allowed the beds to be heated up to operational temperature (800-900 C) and then held there during cyclic operation of the 2-bed CAR process, in this way overcoming unavoidable heat losses from the beds during steady state operation. The performance of the PDU was optimized as much as possible, but equipment limitations prevented the system from fully achieving its target performance. Design of the flue gas recirculation system to integrate CAR PDU with the CTF and the system was completed and integrated tests successfully performed at the end of the period. A detailed techno-economic analysis was made of the CAR process for supplying the oxygen in oxy-fuel combustion retrofit option using AEP's 450 MW Conesville, Ohio plant and contrasted with the cryogenic air separation option (ASU). Design of a large scale CAR unit was completed to support this techno-economic assessment. Based on the finding that the overall cost potential of the CAR technology compared to cryogenic ASU is nominal at current performance levels and that the risks related to both material and process scale up are still significant, the team recommended not to proceed to Phase 2. CAR process economics continue to look attractive if the original and still 'realistic' target oxygen capacities could be realized in practice. In order to achieve this end, a new fundamental materials development program would be needed. With the effective oxygen capacities of the current CAR materials there is, however, insufficient economic incentive to use this commercially unproven technology in oxy-fuel power plant applications in place of conventional ASUs. In addition, it is now clear that before a larger scale pilot demonstration of the CAR technology is made, a better understanding of the impact of flue-gas impurities on the CAR materials and of thermal transients in the beds is required.

  2. A nuclear wind/solar oil-shale system for variable electricity and liquid fuels production

    SciTech Connect (OSTI)

    Forsberg, C.

    2012-07-01

    The recoverable reserves of oil shale in the United States exceed the total quantity of oil produced to date worldwide. Oil shale contains no oil, rather it contains kerogen which when heated decomposes into oil, gases, and a carbon char. The energy required to heat the kerogen-containing rock to produce the oil is about a quarter of the energy value of the recovered products. If fossil fuels are burned to supply this energy, the greenhouse gas releases are large relative to producing gasoline and diesel from crude oil. The oil shale can be heated underground with steam from nuclear reactors leaving the carbon char underground - a form of carbon sequestration. Because the thermal conductivity of the oil shale is low, the heating process takes months to years. This process characteristic in a system where the reactor dominates the capital costs creates the option to operate the nuclear reactor at base load while providing variable electricity to meet peak electricity demand and heat for the shale oil at times of low electricity demand. This, in turn, may enable the large scale use of renewables such as wind and solar for electricity production because the base-load nuclear plants can provide lower-cost variable backup electricity. Nuclear shale oil may reduce the greenhouse gas releases from using gasoline and diesel in half relative to gasoline and diesel produced from conventional oil. The variable electricity replaces electricity that would have been produced by fossil plants. The carbon credits from replacing fossil fuels for variable electricity production, if assigned to shale oil production, results in a carbon footprint from burning gasoline or diesel from shale oil that may half that of conventional crude oil. The U.S. imports about 10 million barrels of oil per day at a cost of a billion dollars per day. It would require about 200 GW of high-temperature nuclear heat to recover this quantity of shale oil - about two-thirds the thermal output of existing nuclear reactors in the United States. With the added variable electricity production to enable renewables, additional nuclear capacity would be required. (authors)

  3. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Definition The following fuels are defined as alternative fuels by the Energy Policy Act (EPAct) of 1992: pure methanol, ethanol, and other alcohols; blends of 85% or more of alcohol with gasoline; natural gas and liquid fuels domestically produced from natural gas; liquefied petroleum gas (propane); coal-derived liquid fuels; hydrogen; electricity; pure biodiesel (B100); fuels, other than alcohol, derived from biological materials; and P-Series fuels. In addition, the U.S.

  4. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Definition and Specifications Alternative fuels include biofuel, ethanol, methanol, hydrogen, coal-derived liquid fuels, electricity, natural gas, propane gas, or a synthetic transportation fuel. Biofuel is defined as a renewable, biodegradable, combustible liquid or gaseous fuel derived from biomass or other renewable resources that can be used as transportation fuel, combustion fuel, or refinery feedstock and that meets ASTM specifications and federal quality requirements for

  5. Bioconversion of coal-derived synthesis gas to liquid fuels. [Butyribacterium methylotrophicum

    SciTech Connect (OSTI)

    Jain, M.K.

    1991-01-01

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  6. Optimizing immobilized enzyme performance in cell-free environments to produce liquid fuels.

    SciTech Connect (OSTI)

    Kumar, Sanat

    2015-02-05

    The overall goal of this project was to optimize enzyme performance for the production of bio-diesel fuel. Enzyme immobilization has attracted much attention as a means to increase productivity. Mesorporous silica materials have been known to be best suited for immobilizing enzymes. A major challenge is to ensure that the enzymatic activity is retained after immobilization. Two major factors which drive enzymatic deactivation are protein-surface and inter-protein interactions. Previously, we studied protein stability inside pores and how to optimize protein-surface interactions to minimize protein denaturation. In this work we studied eh effect of surface curvature and chemistry on inter-protein interactions. Our goal was to find suitable immobilization supports which minimize these inter-protein interactions. Our studies carried out in the frame work of Hydrophobic-Polar (HP) model showed that enzymes immobilized inside hydrophobic pores of optimal sizes are best suited to minimize these inter-protein interactions. Besides, this study is also of biological importance to understand the role of chaperonins in protein disaggregation. Both of these aspects profited immensely with collaborations with our experimental colleague, Prof. Georges Belfort (RPI), who performed the experimental analog of our theoretical works.

  7. Synthesis of oxygenate products for high volume fuels applications. Quarterly status report No. 5 for the period October through December 1995

    SciTech Connect (OSTI)

    Not Available

    1996-02-15

    A process variables study was carried out with crude DME as feed for the condensation with acetylene to C{sub 2} and higher alcohols. The addition of water to crude DME had a marked effect of promoting selectivity to ethanol, especially at the lower reaction temperatures tested. Experiments designed to reveal the effect of reactor flow rate and temperature demonstrated that lower rates and higher temperatures favored selectivity to propanol and butanol up to a maximum temperature of 460{degrees}C, beyond which selectivity diminished via decomposition reactions. Faster rates and lower temperatures favored selectivity to ethanol. Reactor conditions and feed compositions for optimum target alcohol selectivities have been identified. the overall objective of this project is to develop catalyst and process technology for evaluation as potential routes for the production of high volume fuel oxygenates.

  8. "An Economic Process for Coal Liquefaction to Liquid Fuels" SBIR Phase II -- Final Scientific/Technical Report

    SciTech Connect (OSTI)

    Ganguli, Partha Sarathi

    2009-02-19

    The current commercial processes for direct coal liquefaction utilize expensive backmix-flow reactor system and conventional catalysts resulting in incomplete and retrogressive reactions that produce low distillate liquid yield and high gas yield, with high hydrogen consumption. The new process we have developed, which uses a less expensive reactor system and highly active special catalysts, resulted in high distillate liquid yield, low gas yield and low hydrogen consumption. The new reactor system using the special catalyst can be operated smoothly for direct catalytic coal liquefaction. Due to high hydrogenation and hydrocracking activities of the special catalysts, moderate temperatures and high residence time in each stage of the reactor system resulted in high distillate yield in the C{sub 4}-650{degrees}F range with no 650{degrees}F{sup +} product formed except for the remaining unconverted coal residue. The C{sub 4}-650{degrees}F distillate is more valuable than the light petroleum crude. Since there is no 650{degrees}F{sup +} liquid product, simple reforming and hydrotreating of the C{sub 4}-650{degrees}F product will produce the commercial grade light liquid fuels. There is no need for further refinement using catalytic cracking process that is currently used in petroleum refining. The special catalysts prepared and used in the experimental runs had surface area between 40-155 m{sup 2}/gm. The liquid distillate yield in the new process is >20 w% higher than that in the current commercial process. Coal conversion in the experimental runs was moderate, in the range of 88 - 94 w% maf-coal. Though coal conversion can be increased by adjustment in operating conditions, the purpose of limiting coal conversion to moderate amounts in the process was to use the remaining unconverted coal for hydrogen production by steam reforming. Hydrogen consumption was in the range of 4.0 - 6.0 w% maf-coal. A preliminary economic analysis of the new coal liquefaction process was carried out by comparing the design and costs of the current commercial plant of the Shenhua Corporation in Erdos, Inner Mongolia. The cost of producing synthetic crude oil from coal in the current commercial process was estimated to be $50.5 per barrel compared to the estimated cost of $41.7 per barrel in the new process. As mentioned earlier, the light distillate product in the new process is of higher quality and value than the C{sub 4}-975{degrees}F product in the current commercial process adopted by the Shenhua Corporation. In sum, the new coal liquefaction process is superior and less capital intensive to current commercial process, and has a high potential for commercialization.

  9. Process Modeling Results of Bio-Syntrolysis: Converting Biomass to Liquid Fuel with High Temperature Steam Electrolysis

    SciTech Connect (OSTI)

    G. L. Hawkes; M. G. McKellar; R. Wood; M. M. Plum

    2010-06-01

    A new process called Bio-Syntrolysis is being researched at the Idaho National Laboratory (INL) investigating syngas production from renewable biomass that is assisted with high temperature steam electrolysis (HTSE). The INL is the world leader in researching HTSE and has recently produced hydrogen from high temperature solid oxide cells running in the electrolysis mode setting several world records along the way. A high temperature (~800C) heat source is necessary to heat the steam as it goes into the electrolytic cells. Biomass provides the heat source and the carbon source for this process. Syngas, a mixture of hydrogen and carbon monoxide, can be used for the production of synthetic liquid fuels via Fischer-Tropsch processes. This concept, coupled with fossil-free electricity, provides a possible path to reduced greenhouse gas emissions and increased energy independence, without the major infrastructure shift that would be required for a purely hydrogen-based transportation system. Furthermore, since the carbon source is obtained from recyclable biomass, the entire concept is carbon-neutral

  10. Degradation of lignocellulosic biomass and its subsequent utilization for the production of liquid fuels: Subcontract progress report, 1 March 1984-28 February 1985

    SciTech Connect (OSTI)

    Cooney, C.L.; Demain, A.L.; Sinskey, A.J.; Wang, D.I.C.

    1987-07-01

    This project is a coordinated effort to develop process technology for the degradation of lignocellulosic biomass and its utilization for the production of liquid fuels. Current efforts are based on our prior success in developing a single-step microbiological process for the conversion of lignocellulose to ethanol. This process utilizes a mixed culture of Clostridium thermocellum, a thermophilic celluloytic anaerobe which degrades cellulose and hemicellulose to fermentable sugars and Clostridium thermosaccharolyticum, a thermophilic anaerobe which produces high concentrations of ethanol from both hexoses and pentoses. These studies focus on the use of C. thermocellum and its cellulases for enhanced saccharification of lignocellulose and on the direct fermentation of lignocellulose to liquid fuel. Efforts on saccharification are directed to facilitate the adoption of existing fermentation ethanol plants for cellulosic substrates and to overcome the rate limiting step of saccharification in the mixed culture. 9 refs., 9 figs., 9 tabs.

  11. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Definition - Internal Revenue Code The Internal Revenue Service (IRS) defines alternative fuels as liquefied petroleum gas (propane), compressed natural gas, liquefied natural gas, liquefied hydrogen, liquid fuel derived from coal through the Fischer-Tropsch process, liquid hydrocarbons derived from biomass, and P-Series fuels. Biodiesel, ethanol, and renewable diesel are not considered alternative fuels by the IRS. While the term "hydrocarbons" includes liquids that

  12. fuels | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liquid Fuels Gasoline & Diesel Volatile fuel costs and a desire for energy independence have revived interest in another market for coal gasification technology: the production of liquid transportation fuels, chiefly gasoline and diesel fuel. For the United States, routes to synthesis of liquid fuels from coal add substantial diversity in fuel supply capability, a large capacity for fuels production considering the great extent of domestic coal reserves, and increased energy security that

  13. Degradation of lignocellulosic biomass and its subsequent utilization for the production of liquid fuels: Subcontract progress report, 1 March 1983-29 February 1984

    SciTech Connect (OSTI)

    Cooney, C.L.; Demain, A.L.; Sinskey, A.J.; Wang, D.I.C.

    1987-07-01

    This project is a coordinated effort to develop process technology for the degradation of lignocellulosic biomass and its utilization for the production of liquid fuels. Current efforts are based on our prior success in developing a single-step microbiological process for the conversion of lignocellulose to ethanol. This process utilizes a mixed culture of Clostridium thermocellum, a thermophilic cellulolytic anaerobe which degrades cellulose and hemicellulose to fermentable sugars, and Clostridium thermosaccharolyticum, a thermo anaerobe which produces high concentrations of ethanol from both hexoses and pentoses. The proposed studies will focus on the use of C. thermocellum and its cellulases for enhanced saccharification of lignocellulose and on the direct fermentation of lignocellulose to the liquid fuel, butanol. Efforts on saccharification are directed to facilitate the adoption of existing fermentation ethanol plants for cellulosic substrates and to overcome the rate limiting step of saccharification in the mixed culture. The effort on butanol will extend the concept of direct fermentation to the production of this liquid fuel. 14 refs.

  14. Degradation of lignocellulosic biomass and its subsequent utilization for the production of liquid fuels: Subcontract progress report, 1 September 1981-28 February 1982

    SciTech Connect (OSTI)

    Cooney, C.L.; Demain, A.L.; Sinskey, A.J.; Wang, D.I.C.

    1987-07-01

    This project is a coordinated effort to develop process technology for the degradation of lignocellulosic biomass and its utilization for the production of liquid fuels. Current efforts are based on our prior success in developing a single-step microbiological process for the conversion of lignocellulose to ethanol. This process utilizes a mixed culture of Clostridium thermocellum, a thermophilic cellulolytic anaerobe which degrades cellulose and hemicellulose to fermentable sugars, and Clostridium thermosaccharolyticum, a thermophilic anaerobe which produces high concentrations of ethanol from both hexoses and pentoses. The proposed studies will focus on the use of C. thermocellum and its cellulases for enhanced saccharification of lignocellulose and on the direct fermentation of lignocellulose to the liquid fuel, butanol. Efforts on saccharification are directed to facilitate the adoption of existing fermentation ethanol plants for cellulosic substrates and to overcome the rate limiting step of saccharification in the mixed culture. The effort on butanol will extend the concept of direct fermentation to the production of this liquid fuel.

  15. Degradation of lignocellulosic biomass and its subsequent utilization for the production of liquid fuels: Subcontract progress report, 1 March 1982-31 August 1982

    SciTech Connect (OSTI)

    Cooney, C.L.; Demain, A.L.; Sinskey, A.J.; Wang, D.I.C.

    1987-07-01

    This project is a coordinated effort to develop process technology for the degradation of lignocellulosic biomass and its utilization for the production of liquid fuels. Current efforts are based on our prior success in developing a single-step microbiological process for the conversion of lignocellulose to ethanol. This process utilizes a mixed culture of Clostridium thermocellum, a thermophilic cellulolytic anaerobe which degrades cellulose and hemicellulose to fermentable sugars, and Clostridium thermosaccharolyticum, a thermophilic anaerobic which produces high concentrations of ethanol from both hexoses and pentoses. The proposed studies will focus on the use of C. thermocellum and its cellulases for enhanced saccharification of lignocellulose and on the direct fermentation of lignocellulose to the liquid fuel, butanol. Efforts on saccharification are directed to facilitate the adoption of existing fermentation ethanol plants for cellulosic substrates and to overcome the rate limiting step of saccharification in the mixed culture. The effort on butanol will extend the concept of direct fermentation to the production of this liquid fuel.

  16. Degradation of lignocellulosic biomass and its subsequent utilization for the production of liquid fuels: Subcontract progress report, 1 September 1982-28 February 1983

    SciTech Connect (OSTI)

    Cooney, C.L.; Demain, A.L.; Sinskey, A.J.; Wang, D.I.C.

    1987-07-01

    This project is a coordinated effort to develop process technology for the degradation of lignocellulosic biomass and its utilization for the production of liquid fuels. Current efforts are based on our prior success in developing a single-step microbiological process for the conversion of lignocellulose to ethanol. This process utilizes a mixed culture of Clostridium thermocellum, a thermophilic cellulolytic anaerobe which degrades cellulose and hemicellulose to fermentable sugars, and Clostridium thermosaccharolyticum, a thermophilic anaerobe which produces high concentrations of ethanol from both hexoses and pentoses. The proposed studies will focus on the use of C. thermocellum and its cellulases for enhanced saccharification of lignocellulose and on the direct fermentation of lignocellulose to the liquid fuel, butanol. Efforts on saccharification are directed to facilitate the adoption of existing fermentation ethanol plants for cellulosic substrates and to overcome the rate limiting step of saccharification in the mixed culture. The effort on butanol will extend the concept of direct fermentation to the production of this liquid fuel.

  17. High-performance, low Pt content catalysts for the electroreduction of oxygen in polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Fournier, J.; Faubert, G.; Tilquin, J.Y.; Cote, R.; Guay, D.; Dodelet, J.P.

    1997-01-01

    Pt-included and Pt-supported catalysts have been synthesized using graphite and carbon black supports of various specific areas. The graphites are KS6 (20 m{sup 2}/g), HS100 (110 m{sup 2}/g), and HS300 (305 m{sup 2}/g) from Lonza, and the carbon blacks are Vulcan (254 m{sup 2}/g) and Black Pearls (1475 m{sup 2}/g) from Cabot. The Pt-included and Pt-supported catalysts were used at the cathode of a H{sub 2}/O{sub 2} fuel cell, and their polarization curves were compared to each other and to those of various Pt-supported catalysts from E-TEK. In the high current region of interest to fuel cell developers, it is shown that Pt-supported catalysts perform better than Pt-included ones when the specific area of the support is small. The contrary is true when the specific area of the support is large. The best catalysts are HS300-Pti [8.3 weight percent (w/o) Pt included in HS300 graphite] and Vu-Pti (6.1 w/o Pt included in Vulcan XC-72R). These catalysts display very high mass and specific activities for O{sub 2} reduction. Furthermore, the iR-corrected polarization curves of both HS300-Pti (with a Pt loading of 0.110 mg/cm{sup 2}) and Vu-Pti (with a Pt loading of 0.070 mg/cm{sup 2}) cross at high current the polarization curve of the electrode prepared with E-TEK20 (20 w/o of supported Pt, with a Pt loading of 0.287 mg/cm{sup 2}). Pt inclusion in graphite or carbon black is therefore an interesting way of reducing the Pt loading of fuel cell cathodes without lowering electrochemical performance. HS300-Pti have been characterized by X-ray diffraction, transmission electron microscopy, and X-ray photoelectron spectroscopy. These analyses indicate that they both contain metallic Pt and Pt(II and IV) oxides and/or hydroxides.

  18. Alternative fuels and chemicals from synthesis gas. Quarterly status report number 2, 1 January--31 March 1995

    SciTech Connect (OSTI)

    1995-12-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit. Results are discussed for the following tasks: liquid phase hydrodynamic run; catalyst activation with CO; new processes for DME (dehydration catalyst screening runs, and experiments using Robinson-Mahoney basket internal and pelletized catalysts); new fuels from DME; and new processes for alcohols and oxygenated fuel additives.

  19. Techno-Economic Analysis of Liquid Fuel Production from Woody Biomass via Hydrothermal Liquefaction (HTL) and Upgrading

    SciTech Connect (OSTI)

    Zhu, Yunhua; Biddy, Mary J.; Jones, Susanne B.; Elliott, Douglas C.; Schmidt, Andrew J.

    2014-09-15

    A series of experimental work was conducted to convert woody biomass to gasoline and diesel range products via hydrothermal liquefaction (HTL) and catalytic hydroprocessing. Based on the best available test data, a techno-economic analysis (TEA) was developed for a large scale woody biomass based HTL and upgrading system to evaluate the feasibility of this technology. In this system, 2000 dry metric ton per day woody biomass was assumed to be converted to bio-oil in hot compressed water and the bio-oil was hydrotreated and/or hydrocracked to produce gasoline and diesel range liquid fuel. Two cases were evaluated: a stage-of-technology (SOT) case based on the tests results, and a goal case considering potential improvements based on the SOT case. Process simulation models were developed and cost analysis was implemented based on the performance results. The major performance results included final products and co-products yields, raw materials consumption, carbon efficiency, and energy efficiency. The overall efficiency (higher heating value basis) was 52% for the SOT case and 66% for the goal case. The production cost, with a 10% internal rate of return and 2007 constant dollars, was estimated to be $1.29 /L for the SOT case and $0.74 /L for the goal case. The cost impacts of major improvements for moving from the SOT to the goal case were evaluated and the assumption of reducing the organics loss to the water phase lead to the biggest reduction in the production cost. Sensitivity analysis indicated that the final products yields had the largest impact on the production cost compared to other parameters. Plant size analysis demonstrated that the process was economically attractive if the woody biomass feed rate was over 1,500 dry tonne/day, the production cost was competitive with the then current petroleum-based gasoline price.

  20. Direct Observation of the Oxygenated Species during Oxygen Reduction on a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Platinum Fuel Cell Cathode | Stanford Synchrotron Radiation Lightsource Direct Observation of the Oxygenated Species during Oxygen Reduction on a Platinum Fuel Cell Cathode Friday, December 20, 2013 Fuel Cell Figure 1 Figure 1. In situ x-ray spectroscopy identification and DFT simulations of oxygenated intermediates on a platinum fuel-cell cathode. The study shows that two types of hydroxyl intermediates (non-hydrated OH and hydrated OH) with distinct activities coexist on a fuel-cell

  1. Liquid natural gas as a transportation fuel in the heavy trucking industry. Final technical report, May 10, 1994--December 30, 1995

    SciTech Connect (OSTI)

    Sutton, W.H.

    1995-12-31

    This report encompasses the first year of a proposed three year project with emphasis focused on LNG research issues in Use of Liquid Natural Gas as a Transportation Fuel in the Heavy Trucking Industry. These issues may be categorized as (i) direct diesel replacement with LNG fuel, and (ii) long term storage/utilization of LNG vent gases produced by tank storage and fueling/handling operation. Since this work was for fundamental research in a number of related areas to the use of LNG as a transportation fuel for long haul trucking, many of those results have appeared in numerous refereed journal and conference papers, and significant graduate training experiences (including at least one M.S. thesis and one Ph.D. dissertation) in the first year of this project. In addition, a potential new utilization of LNG fuel has been found, as a part of this work on the fundamental nature of adsorption of LNG vent gases in higher hydrocarbons; follow on research for this and other related applications and transfer of technology are proceeding at this time.

  2. Liquid Fuels Market Module

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    product import and export curves, biodiesel import supply curves, and advanced ethanol import supply curves from Brazil. The nine LFMM regions and importexport curves are...

  3. Degradation of lignocellulosic biomass and its subsequent utilization for the production of liquid fuels: Subcontract progress report, 1 March 1981-31 August 1981

    SciTech Connect (OSTI)

    Cooney, C.L.; Demain, A.L.; Sinskey, A.J.; Wang, D.I.C.

    1987-07-01

    This project is a coordinated effort to develop process technology for the degradation of lignocellulosic biomass and its utilization for the production of liquid fuels. Current efforts are based on our prior success in developing a single-step microbiological process for the conversion of lignocellulose to ethanol. This process utilizes a mixed culture of Clostridium thermocellum, a thermophilic cellulolytic anaerobe which degrades cellulose and hemicellulose to fermentable sugars, and C. thermosaccharolyticum, a thermophilic anaerobe which produces high concentrations of ethanol from both hexoses and pentoses. The proposed studies will focus on the use of C. therocellum and its cellulases for enhanced saccharification of lignocellulose and on the direct fermentation of lignocellulose to the liquid fuel, butanol. Efforts on saccharification are directed to facilitate the adoption of existing fermentation ethanol plants for cellulosic substrates and to overcome the rate limiting step of saccharification in the mixed culture. The effort on butanol will extend the concept of direct fermentation to the production of this fuel. 55 figs., 6 tabs.

  4. Synthesis of oxygenate products for high volume fuels applications. Quarterly status report No. 3 for the period April through June 1995

    SciTech Connect (OSTI)

    Not Available

    1995-09-26

    A rudimentary process variables study of the reaction of acetylene with methanol indicates high activity for the formation of ethanol, n- propanol, and i-butanol with a pure low temperature activated MgO catalyst. Initial results indicate that higher conversions and space- time yields may be obtainable by operation at higher temperatures and reactant feed rates, respectively. Also, ethanol formation was consistently observed to rise with decreasing reaction temperature between 454{degrees}C and 370{degrees}C. A 10% Al{sub 2}O{sub 3}/MgO catalyst exhibited high activity for methanol-dimethyl ether interconversion but was not very active for the condensation of these reactants to either the product alcohols or their methyl ethers. Neither catalyst exhibited significant activity for the condensation to dimethyl ether/water with acetylene to form such products. This lack of activity in the ether systems is attributed to insufficient hydrolysis of dimethyl ether to methanol, and it is expected that feeds containing additional water or methanol (which produces water via condensation) will exhibit higher activity. The aluminum- containing catalyst exhibited diminished condensation activity possibly as a result of deactivation of Mg sites by Al sites. The overall objective of this project is to develop catalyst and process technology for evaluation as potential routes for the production of high volume fuel oxygenates.

  5. Synthesis of oxygenate products for high volume fuels applications. Quarterly status report No. 4 for the period July through September 1995

    SciTech Connect (OSTI)

    Not Available

    1995-12-29

    A rudimentary process variables study of the reaction of acetylene with methanol indicates high activity for the formation of ethanol, n- propanol, and i-butanol with a pure low temperature activated MgO catalyst. Initial results indicate that higher conversions and space- time yields may be obtainable by operation at higher temperatures and reactant feed rates, respectively. Also, ethanol formation was consistently observed to rise with decreasing reaction temperature between 454{degrees}C and 370{degrees}C. A 10% Al{sub 2}O{sub 3}/MgO catalyst exhibited high activity for methanol-dimethyl ether interconversion but was not very active for the condensation of these reactants to either the product alcohols or their methyl ethers. Neither catalyst exhibited significant activity for the condensation of dimethyl ether/water with acetylene to form such products. This lack of activity in the ether systems us attributed to insufficient hydrolysis of dimethyl ether to methanol, and it is expected that feeds containing additional water or methanol (which produces water via condensation) will exhibit higher activity. The aluminum- containing catalyst exhibited diminished condensation activity possibly as the result of deactivation of Mg sites by Al sites. The overall objective of this project is to develop catalyst and process technology for evaluation as potential routes for the production of high volume fuel oxygenates.

  6. Direct liquid injection of liquid petroleum gas

    SciTech Connect (OSTI)

    Lewis, D.J.; Phipps, J.R.

    1984-02-14

    A fuel injector and injection system for injecting liquified petroleum gas (LPG) into at least one air/fuel mixing chamber from a storage means that stores pressurized LPG in its liquid state. The fuel injector (including a body), adapted to receive pressurized LPG from the storage means and for selectively delivering the LPG to the air/fuel mixing chamber in its liquified state. The system including means for correcting the injector activation signal for pressure and density variations in the fuel.

  7. Oxy-fuel combustion with integrated pollution control

    DOE Patents [OSTI]

    Patrick, Brian R.; Ochs, Thomas Lilburn; Summers, Cathy Ann; Oryshchyn, Danylo B.; Turner, Paul Chandler

    2012-01-03

    An oxygen fueled integrated pollutant removal and combustion system includes a combustion system and an integrated pollutant removal system. The combustion system includes a furnace having at least one burner that is configured to substantially prevent the introduction of air. An oxygen supply supplies oxygen at a predetermine purity greater than 21 percent and a carbon based fuel supply supplies a carbon based fuel. Oxygen and fuel are fed into the furnace in controlled proportion to each other and combustion is controlled to produce a flame temperature in excess of 3000 degrees F. and a flue gas stream containing CO2 and other gases. The flue gas stream is substantially void of non-fuel borne nitrogen containing combustion produced gaseous compounds. The integrated pollutant removal system includes at least one direct contact heat exchanger for bringing the flue gas into intimated contact with a cooling liquid to produce a pollutant-laden liquid stream and a stripped flue gas stream and at least one compressor for receiving and compressing the stripped flue gas stream.

  8. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  9. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  10. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  11. Liquid Fuel from Heat-Loving Microorganisms: H2-Dependent Conversion of CO2 to Liquid Electrofuels by Extremely Thermophilic Archaea

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: NC State is working with the University of Georgia to create Electrofuels from primitive organisms called extremophiles that evolved before photosynthetic organisms and live in extreme, hot water environments with temperatures ranging from 167-212 degrees Fahrenheit The team is genetically engineering these microorganisms so they can use hydrogen to turn carbon dioxide directly into alcohol-based fuels. High temperatures are required to distill the biofuels from the water where the organisms live, but the heat-tolerant organisms will continue to thrive even as the biofuels are being distilledmaking the fuel-production process more efficient. The microorganisms dont require light, so they can be grown anywhereinside a dark reactor or even in an underground facility.

  12. Jupiter Oxygen Corporation | Open Energy Information

    Open Energy Info (EERE)

    Place: Schiller Park, Illinois Zip: 60176 Product: Illinois-based oxy-fuel combustion company involved in the capture of CO2. References: Jupiter Oxygen Corporation1...

  13. Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A Techno-economic Evaluation of the Production of Mixed Alcohols

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua; Valkenburt, Corinne

    2009-05-01

    Biomass is a renewable energy resource that can be converted into liquid fuel suitable for transportation applications and thus help meet the Energy Independence and Security Act renewable energy goals (U.S. Congress 2007). However, biomass is not always available in sufficient quantity at a price compatible with fuels production. Municipal solid waste (MSW) on the other hand is readily available in large quantities in some communities and is considered a partially renewable feedstock. Furthermore, MSW may be available for little or no cost. This report provides a techno-economic analysis of the production of mixed alcohols from MSW and compares it to the costs for a wood based plant. In this analysis, MSW is processed into refuse derived fuel (RDF) and then gasified in a plant co-located with a landfill. The resulting syngas is then catalytically converted to mixed alcohols. At a scale of 2000 metric tons per day of RDF, and using current technology, the minimum ethanol selling price at a 10% rate of return is approximately $1.85/gallon ethanol (early 2008 $). However, favorable economics are dependent upon the toxicity characteristics of the waste streams and that a market exists for the by-product scrap metal recovered from the RDF process.

  14. Production of coal-based fuels and value-added products: coal to liquids using petroleum refinery streams

    SciTech Connect (OSTI)

    Clifford, C.E.B.; Schobert, H.H.

    2008-07-01

    We are studying several processes that utilize coal, coal-derived materials, or biomass in existing refining facilities. A major emphasis is the production of a coal-based replacement for JP-8 jet fuel. This fuel is very similar to Jet A and jet A-1 in commercial variation, so this work has significant carry-over into the private sector. We have been focusing on three processes that would be retrofitted into a refinery: (1) coal tar/refinery stream blending and hydro-treatment; (2) coal extraction using refinery streams followed by hydro-treatment; and (3) co-coking of coal blended with refinery streams. 4 figs., 5 tabs.

  15. Transportation fuels from wood

    SciTech Connect (OSTI)

    Baker, E.G.; Elliott, D.C.; Stevens, D.J.

    1980-01-01

    The various methods of producing transportation fuels from wood are evaluated in this paper. These methods include direct liquefaction schemes such as hydrolysis/fermentation, pyrolysis, and thermochemical liquefaction. Indirect liquefaction techniques involve gasification followed by liquid fuels synthesis such as methanol synthesis or the Fischer-Tropsch synthesis. The cost of transportation fuels produced by the various methods are compared. In addition, three ongoing programs at Pacific Northwest Laboratory dealing with liquid fuels from wood are described.

  16. Methylal and Methylal-Diesel Blended Fuels from Use In Compression-Ignition Engines

    SciTech Connect (OSTI)

    Keith D. Vertin; James M. Ohi; David W. Naegeli; Kenneth H. Childress; Gary P. Hagen; Chris I. McCarthy; Adelbert S. Cheng; Robert W. Dibble

    1999-05-05

    Gas-to-liquids catalytic conversion technologies show promise for liberating stranded natural gas reserves and for achieving energy diversity worldwide. Some gas-to-liquids products are used as transportation fuels and as blendstocks for upgrading crude derived fuels. Methylal (CH{sub 3}-O-CH{sub 2}-O-CH{sub 3}) also known as dimethoxymethane or DMM, is a gas-to-liquid chemical that has been evaluated for use as a diesel fuel component. Methylal contains 42% oxygen by weight and is soluble in diesel fuel. The physical and chemical properties of neat methylal and for blends of methylal in conventional diesel fuel are presented. Methylal was found to be more volatile than diesel fuel, and special precautions for distribution and fuel tank storage are discussed. Steady state engine tests were also performed using an unmodified Cummins 85.9 turbocharged diesel engine to examine the effect of methylal blend concentration on performance and emissions. Substantial reductions of particulate matter emissions h ave been demonstrated 3r IO to 30% blends of methylal in diesel fuel. This research indicates that methylal may be an effective blendstock for diesel fuel provided design changes are made to vehicle fuel handling systems.

  17. Synthesis of dimethyl ether and alternative fuels in the liquid phase from coal-derived syngas; Quarterly technical progress report No. 3, 1 July--30 September 1990

    SciTech Connect (OSTI)

    1991-01-25

    Contract objectives are: development of a one-step liquid phase dimethyl ether/methanol process; and investigation of the potential of liquid phase synthesis of alternative fuels from coal-derived synthesis gas. Definition of Preferred Catalyst System was completed after several commercial methanol catalysts and dehydration catalysts were tested. BASF S3-86 and Catapal gamma alumina is the preferred catalyst system of choice. Process Variable Scans on the Preferred Catalyst System was started with Shell gas. Data were obtained at various pressures (750 to 1400 psig), temperatures (250 to 280{degrees}C), and space velocities (5000 to 9000 sl/kg-hr). Increase in system pressure seems to have a very significant benefit to both DME and methanol formation. Both Texaco and Shell gases were evaluated. A ``stoichiometric`` feed composition (50% CO, 50% H{sub 2}) that yields maximum DME productivity at equilibrium was evaluated with a fresh batch of the optimum catalyst system. Productivities with the ``stoichiometric`` gas were much higher compared to Shell or Texaco gas. Following that test, Dow gas was evaluated (41% CO, 41% H{sub 2}, 16% CO{sub 2} and 2% N{sub 2}) using the same catalyst to study the effect of CO{sub 2}. Three DME/MEOH (1--4% DME) mixtures were evaluated by SWRI for their fuel properties. Results indicate that, with small amounts of DME added, significant improvements in both flash point and RVP are possible over the properties of LaPorte MEOH. the slurry-phase dehydration of alcohols to ethers was investigated by feeding 10 mol% mixed alcohols in N{sub 2} over an alumina catalyst suspended in mineral oil. Two alcohol mixture compositions were chosen for this study. One mixture contained methanol, ethanol, and 1-propanol in proportions representative of those in IFP Substifuel, while the other mixture contained methanol, ethanol, and isobutanol in proportions representative of those in Lurgi Octamix. 21 figs., 13 tabs.

  18. Syngas into Fuel: Optofluidic Solar Concentrators

    SciTech Connect (OSTI)

    None

    2010-10-01

    Broad Funding Opportunity Announcement Project: Ohio State has developed an iron-based material and process for converting syngasa synthetic gas mixtureinto electricity, H2, and/or liquid fuel with zero CO2 emissions. Traditional carbon capture methods use chemical solvents or special membranes to separate CO2 from the gas exhaust from coal-fired power plants. Ohio States technology uses an iron-based oxygen carrier to generate CO2 and H2 from syngas in separate, pure product streams by means of a circulating bed reactor configuration. The end products of the system are H2, electricity, and/or liquid fuel, all of which are useful sources of power that can come from coal or syngas derived from biomass. Ohio State is developing a high-pressure pilot-scale unit to demonstrate this process at the National Carbon Capture Center.

  19. Liquid Sunshine to Fuel Your Car (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    ScienceCinema (OSTI)

    Cosgrove, Daniel (Director, Center for Lignocellulose Structure and Formation); CLSF Staff

    2011-11-02

    'Liquid Sunshine to Fuel Your Car' was submitted by the Center for Lignocellulose Structure and Formation (CLSF) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. CLSF is directed by Daniel Cosgrove at Pennsylvania State University and is a partnership of scientists from three institutions: Penn State (lead), North Caroline State University, and Virginia Tech University. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of the Center for Lignocellulose Structure and Formation is 'to dramatically increase our fundamental knowledge of the formation and physical interactions of bio-polymer networks in plant cell walls to provide a basis for improved methods for converting biomass into fuels.' Research topics are: biofuels (biomass), membrane, interfacial characterization, matter by design, and self-assembly.

  20. Liquid Sunshine to Fuel Your Car (A "Life at the Frontiers of Energy Research" contest entry from the 2011 Energy Frontier Research Centers (EFRCs) Summit and Forum)

    SciTech Connect (OSTI)

    Cosgrove, Daniel; CLSF Staff

    2011-05-01

    'Liquid Sunshine to Fuel Your Car' was submitted by the Center for Lignocellulose Structure and Formation (CLSF) to the 'Life at the Frontiers of Energy Research' video contest at the 2011 Science for Our Nation's Energy Future: Energy Frontier Research Centers (EFRCs) Summit and Forum. Twenty-six EFRCs created short videos to highlight their mission and their work. CLSF is directed by Daniel Cosgrove at Pennsylvania State University and is a partnership of scientists from three institutions: Penn State (lead), North Caroline State University, and Virginia Tech University. The Office of Basic Energy Sciences in the U.S. Department of Energy's Office of Science established the 46 Energy Frontier Research Centers (EFRCs) in 2009. These collaboratively-organized centers conduct fundamental research focused on 'grand challenges' and use-inspired 'basic research needs' recently identified in major strategic planning efforts by the scientific community. The overall purpose is to accelerate scientific progress toward meeting the nation's critical energy challenges. The mission of the Center for Lignocellulose Structure and Formation is 'to dramatically increase our fundamental knowledge of the formation and physical interactions of bio-polymer networks in plant cell walls to provide a basis for improved methods for converting biomass into fuels.' Research topics are: biofuels (biomass), membrane, interfacial characterization, matter by design, and self-assembly.

  1. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, William H.

    1986-01-01

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N.sub.2), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable oxygen obtained by decomposing the sample at 1135.degree. C., or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135.degree. C. as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N.sub.2, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  2. Micro fuel cell

    SciTech Connect (OSTI)

    Zook, L.A.; Vanderborgh, N.E. [Los Alamos National Lab., NM (United States); Hockaday, R. [Energy Related Devices Inc., Los Alamos, NM (United States)

    1998-12-31

    An ambient temperature, liquid feed, direct methanol fuel cell device is under development. A metal barrier layer was used to block methanol crossover from the anode to the cathode side while still allowing for the transport of protons from the anode to the cathode. A direct methanol fuel cell (DMFC) is an electrochemical engine that converts chemical energy into clean electrical power by the direct oxidation of methanol at the fuel cell anode. This direct use of a liquid fuel eliminates the need for a reformer to convert the fuel to hydrogen before it is fed into the fuel cell.

  3. MELCOR Model of the Spent Fuel Pool of Fukushima Dai-ichi Unit...

    Office of Scientific and Technical Information (OSTI)

    ALUMINIUM; BOILING; DIMENSIONS; EARTHQUAKES; EXPLOSIONS; FUEL ASSEMBLIES; FUEL RACKS; HYDROGEN; NUCLEAR POWER PLANTS; OXIDATION; OXYGEN; RADIOISOTOPES; REACTOR ACCIDENTS;...

  4. Oxygen analyzer

    DOE Patents [OSTI]

    Benner, W.H.

    1984-05-08

    An oxygen analyzer which identifies and classifies microgram quantities of oxygen in ambient particulate matter and for quantitating organic oxygen in solvent extracts of ambient particulate matter. A sample is pyrolyzed in oxygen-free nitrogen gas (N/sub 2/), and the resulting oxygen quantitatively converted to carbon monoxide (CO) by contact with hot granular carbon (C). Two analysis modes are made possible: (1) rapid determination of total pyrolyzable obtained by decomposing the sample at 1135/sup 0/C, or (2) temperature-programmed oxygen thermal analysis obtained by heating the sample from room temperature to 1135/sup 0/C as a function of time. The analyzer basically comprises a pyrolysis tube containing a bed of granular carbon under N/sub 2/, ovens used to heat the carbon and/or decompose the sample, and a non-dispersive infrared CO detector coupled to a mini-computer to quantitate oxygen in the decomposition products and control oven heating.

  5. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel and Special Fuel Definitions The definition of alternative fuel includes liquefied petroleum gas (propane). Special fuel is defined as all combustible gases and liquids that are suitable for powering an internal combustion engine or motor or are used exclusively for heating, industrial, or farm purposes. Special fuels include biodiesel, blended biodiesel, and natural gas products, including liquefied and compressed natural gas. (Reference Indiana Code 6-6-2.5-1 and 6-6-2.5-22

  6. Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Platinum Monolayer Electrocatalysts for Oxygen Reduction Reaction Download presentation slides from the June 19, 2012, Fuel Cell Technologies Program webinar, "BNL's Low-Platinum Electrocatalysts for Fuel Cell Electric Vehicles (FCEVs)." PDF icon BNL's Low-Platinum Electrocatalysts for Fuel Cell Electric Vehicles (FCEVs) Webinar Slides More Documents & Publications Contiguous Platinum

  7. DIMETHYL ETHER (DME)-FUELED SHUTTLE BUS DEMONSTRATION PROJECT

    SciTech Connect (OSTI)

    Elana M. Chapman; Shirish Bhide; Andre L. Boehman; David Klinikowski

    2003-04-01

    The objectives of this research and demonstration program are to convert a campus shuttle bus to operation on dimethyl ether, a potential ultra-clean alternative diesel fuel. To accomplish this objective, this project includes laboratory evaluation of a fuel conversion strategy, as well as field demonstration of the DME-fueled shuttle bus. Since DME is a fuel with no lubricity (i.e., it does not possess the lubricating quality of diesel fuel), conventional fuel delivery and fuel injection systems are not compatible with dimethyl ether. Therefore, to operate a diesel engine on DME one must develop a fuel-tolerant injection system, or find a way to provide the necessary lubricity to the DME. In this project, they have chosen the latter strategy in order to achieve the objective with minimal need to modify the engine. The strategy is to blend DME with diesel fuel, to obtain the necessary lubricity to protect the fuel injection system and to achieve low emissions. Within the Combustion Laboratory of the Penn State Energy Institute, they have installed and equipped a Navistar V-8 direct-injection turbodiesel engine for measurement of gaseous and particulate emissions and examination of the impact of fuel composition on diesel combustion. They have also reconfigured a high-pressure viscometer for studies of the viscosity, bulk modulus (compressibility) and miscibility of blends of diesel fuel, dimethyl ether and lubricity additives. The results include baseline emissions, performance and combustion measurements on the Navistar engine for operation on a federal low sulfur diesel fuel (300 ppm S). Most recently, they have examined blends of an oxygenated fuel additive (a liquid fuel called CETANER{trademark}) produced by Air Products, for comparison with dimethyl ether blended at the same weight of oxygen addition, 2 wt.%. While they have not operated the engine on DME yet, they are now preparing to do so. A fuel system for delivery of DME/Diesel blends has been configured and initial investigations at low DME blend ratios (around 5-10 vol%) will begin shortly. They have also performed viscosity measurements on diesel fuel, DME and 50-50 blends of DME in diesel. These tests have verified that DME has a much lower viscosity than the diesel fuel and that the viscosity of the blended fuel is also much lower than the diesel base fuel. This has implications for the injection and atomization of the DME/diesel blends.

  8. Conversion of cellulosic wastes to liquid hydrocarbon fuels: Vol. 6, The modeling and design of a staged indirect liquefaction reactor: Final report

    SciTech Connect (OSTI)

    Kuester, J.L.

    1986-11-01

    A staged reactor was designed to convert biomass to useful fuels. The reactor consists of three stages. The first stage is a concentric combustor/pyrolyzer system where the biomass is gasified in a fluidized bed at high temperatures in the absence of oxygen. The second stage is a cyclonic scrubber where particulates and condensable materials are removed from the gas stream while the gas is cooled. In the final stage the gas undergoes a Fischer-Tropsch synthesis in a fluidized bed or slurry reactor. Mathematical models of the system were developed and used to create computer programs that would predict the behavior of the bed. The models were based on fundamental phenomena and were used to predict key dimensions of the staged reactor system. A transparent plastic, full-scale, cold flow reactor simulator was built using the models' predictions. The simulator was used to refine the models and determine the operating characteristics of the reactor. The design was determined to be workable and potentially useful. The reactor was, however, difficult to operate and would require extensive automated control systems.

  9. Bioconversion of coal-derived synthesis gas to liquid fuels. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Jain, M.K.

    1991-12-31

    The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

  10. 2009 Fuel Cell Market Report

    Fuel Cell Technologies Publication and Product Library (EERE)

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of

  11. Synthetic fuel aromaticity and staged combustion

    SciTech Connect (OSTI)

    Longanbach, J. R.; Chan, L. K.; Levy, A.

    1982-11-15

    Samples of middle and heavy SRC-II distillates were distilled into 50 C boiling point range fractions. These were characterized by measurements of their molecular weight, elemental analysis and basic nitrogen content and calculation of average molecular structures. The structures typically consisted of 1 to 3 aromatic rings fused to alicyclic rings with short, 1 to 3 carbon aliphatic side chains. The lower boiling fractions contained significant amounts (1 atom/molecule) of oxygen while the heavier fractions contained so few heteroatoms that they were essentially hydrocarbons. Laboratory scale oxidative-pyrolysis experiments were carried out at pyrolysis temperatures of 500 to 1100 C and oxygen concentrations from 0 to 100 percent of stoichiometry. Analysis of liquid products, collected in condensers cooled with liquid nitrogen showed that aromatization is a major reaction in the absence of oxygen. The oxygen-containing materials (phenolics) seem to be more resistant to thermal pyrolysis than unsubstituted aromatics. Nitrogen converts from basic to nonbasic forms at about 500 C. The nonbasic nitrogen is more stable and survives up to 700 C after which it is slowly removed. A recently constructed 50,000 Btu/hr staged combustor was used to study the chemistry of the nitrogen and aromatics. SRC II combustion was studied under fuel-rich, first-stage conditions at air/fuel ratios from 0.6 to 1.0 times stoichiometric. The chemistry of the fuel during combustion calls for further investigation in order to examine the mechanism by which HCN is evolved as a common intermediate for the formation of the nitrogen-containing gaseous combustion products. 25 references, 45 figures, 25 tables.

  12. Basic properties of a liquidt in anode solid oxide fuel cell

    SciTech Connect (OSTI)

    Harry Abernathy; RandallGemmen; KirkGerdes; Mark Koslowske; ThomasTao

    2010-12-17

    An unconventional high temperature fuel cell system, the liquidt in anode solid oxide fuel cell(LTA-SOFC), is discussed. A thermodynamic analysis of a solid oxide fuel cell with a liquid metal anode is developed. Pertinent thermo chemical and thermo physical properties of liquid tin in particular are detailed. An experimental setup for analysis of LTA-SOFC anode kinetics is described, and data for a planar cell under hydrogen indicated an effective oxygen diffusion coefficient of 5.310?5 cm2 s?1 at 800 ?C and 8.910?5 cm2 s?1 at 900 ?C. This value is similar to previously reported literature values for liquid tin. The oxygen conductivity through the tin, calculated from measured diffusion coefficients and theoretical oxygen solubility limits, is found to be on the same order of thatofyttria-stabilizedzirconia(YSZ), a traditional SOFC electrolyte material. As such,the ohmicloss due to oxygen transport through the tin layer must be considered in practical system cell design since the tin layer will usually be at least as thick as the electrolyte.

  13. Synthesis of oxygenate products for high volume fuels applications. Quarterly technical progress report No. 1, November 1, 1994--January 31, 1995

    SciTech Connect (OSTI)

    1995-03-08

    Construction and setup of twin laboratory gas phase reactors with in-line Gas chromatographic analysers was completed. Calibration and C.G. analysis methods development were carried out, and spreadsheet programs were written for reduction of data to interpretable results. Initial tests were carried out with pentasil zeolite ASM-5 containing very low (0.1%) levels of mercury as potential catalysts for conversion of acetylene/methanol streams to 1,1-dimethoxyethane or to C{sub 2}{sup +} alcohols, both useful as high-oxygenate gasoline blending agents. Trace levels of both types of products were observed, although the predominant products were light olefins at lower reaction temperatures and aromatics at higher temperatures. It is anticipated that less acidic zeolites and/or Zn- containing catalysts will be more active for oxygenate production. Testing of these materials is underway.

  14. EA-1642-S1: Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis, Lexington, KY

    Broader source: Energy.gov [DOE]

    This draft Supplemental Environmental Assessment (SEA) analyzes the potential environmental impacts of DOE’s proposed action of providing cost-shared funding for the University of Kentucky (UK) Center for Applied Energy Research (CAER) Small-Scale Pilot Plant for the Gasification of Coal and Coal-Biomass Blends and Conversion of Derived Syngas to Liquid Fuels via Fischer-Tropsch Synthesis project and of the No-Action Alternative.

  15. Spatially Resolved Mapping of Oxygen Reduction/evolution Reaction on Solid-Oxide Fuel Cell Cathodes with sub-10 nm Resolution

    SciTech Connect (OSTI)

    Kumar, Amit; Leonard, Donovan N; Jesse, Stephen; Ciucci, Francesco; Eliseev, Eugene; Morozovska, A. N.; Biegalski, Michael D; Christen, Hans M; Tselev, Alexander; Mutoro, Eva; Crumlin, Ethan; Morgan, Dane; Shao-Horn, Yang; Borisevich, Albina Y; Kalinin, Sergei

    2013-01-01

    Spatial localization of the oxygen reduction/evolution reactions (ORR/OER) on lanthanum strontium cobaltite (LSCO) surfaces with perovskite and layered perovskite structures is studied on the sub-10 nanometer level. Comparison between Electrochemical Strain Microscopy (ESM) and structural imaging by scanning transmission electron microscopy (STEM) suggest that small-angle grain boundaries act as regions with enhanced electrochemical activity. The ESM activity is compared across a family of LSCO samples, demonstrating excellent agreement with macroscopic behaviors. This study potentially paves the way for deciphering the mechanisms of electrochemical activity of solids on the level of single extended structural defects such as grain boundaries and dislocations.

  16. Fuel Cells & Alternative Fuels | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts. Fuel cell shown with its inputs and outputs. Hydrogen input on left, oxygen input on right, water and heat outputs on the back, with an electrical circuit going around the top. A fuel cell is a device that uses hydrogen (or hydrogen-rich fuel) and oxygen to create electricity. Fuel cells are more energy-efficient than combustion engines and the

  17. Electrocatalyst for Oxygen Reduction with Reduced Platinum Oxidation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is the most efficient electrocatalyst for accelerating the oxygen reduction reaction in fuel cells. Under operating conditions, though, platinum catalysts can dissolve. When used...

  18. Composite oxygen transport membrane

    SciTech Connect (OSTI)

    Christie, Gervase Maxwell; Lane, Jonathan A.

    2014-08-05

    A method of producing a composite oxygen ion membrane and a composite oxygen ion membrane in which a porous fuel oxidation layer and a dense separation layer and optionally, a porous surface exchange layer are formed on a porous support from mixtures of (Ln.sub.1-xA.sub.x).sub.wCr.sub.1-yB.sub.yO.sub.3-.delta. and a doped zirconia. In the porous fuel oxidation layer and the optional porous surface exchange layer, A is Calcium and in the dense separation layer A is not Calcium and, preferably is Strontium. Preferred materials are (La.sub.0.8Ca.sub.0.2).sub.0.95Cr.sub.0.5Mn.sub.0.5O.sub.3-.delta. for the porous fuel oxidation and optional porous surface exchange layers and (La.sub.0.8Sr.sub.0.2).sub.0.95Cr.sub.0.5Fe.sub.0.5O.sub.3-.delta. for the dense separation layer. The use of such materials allows the membrane to sintered in air and without the use of pore formers to reduce membrane manufacturing costs. The use of materials, as described herein, for forming the porous layers have application for forming any type of porous structure, such as a catalyst support.

  19. Ceramic Membranes for Hydrogen/Oxygen Production - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vehicles and Fuels Vehicles and Fuels Startup America Startup America Industrial Technologies Industrial Technologies Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Ceramic Membranes for Hydrogen/Oxygen Production Ceramic Membranes Developed at Argonne May Bring Fuel-Cell Cars Closer to Reality Argonne National Laboratory Contact ANL About This Technology Technology Marketing Summary In the long term, hydrogen is expected to be the fuel of choice for both the

  20. Pyrolysis of Woody Residue Feedstocks: Upgrading of Bio-Oils from Mountain-Pine-Beetle-Killed Trees and Hog Fuel

    SciTech Connect (OSTI)

    Zacher, Alan H.; Elliott, Douglas C.; Olarte, Mariefel V.; Santosa, Daniel M.; Preto, Fernando; Iisa, Kristiina

    2014-12-01

    Liquid transportation fuel blend-stocks were produced by pyrolysis and catalytic upgrading of woody residue biomass. Mountain pine beetle killed wood and hog fuel from a saw mill were pyrolyzed in a 1 kg/h fluidized bed reactor and subsequently upgraded to hydrocarbons in a continuous fixed bed hydrotreater. Upgrading was performed by catalytic hydrotreatment in a two-stage bed at 170°C and 405°C with a per bed LHSV between 0.17 and 0.19. The overall yields from biomass to upgraded fuel were similar for both feeds: 24-25% despite the differences in bio-oil (intermediate) mass yield. Pyrolysis bio-oil mass yield was 61% from MPBK wood, and subsequent upgrading of the bio-oil gave an average mass yield of 41% to liquid fuel blend stocks. Hydrogen was consumed at an average of 0.042g/g of bio-oil fed, with final oxygen content in the product fuel ranging from 0.31% to 1.58% over the course of the test. Comparatively for hog fuel, pyrolysis bio-oil mass yield was lower at 54% due to inorganics in the biomass, but subsequent upgrading of that bio-oil had an average mass yield of 45% to liquid fuel, resulting in a similar final mass yield to fuel compared to the cleaner MPBK wood. Hydrogen consumption for the hog fuel upgrading averaged 0.041 g/g of bio-oil fed, and the final oxygen content of the product fuel ranged from 0.09% to 2.4% over the run. While it was confirmed that inorganic laded biomass yields less bio-oil, this work demonstrated that the resultant bio-oil can be upgraded to hydrocarbons at a higher yield than bio-oil from clean wood. Thus the final hydrocarbon yield from clean or residue biomass pyrolysis/upgrading was similar.

  1. Fuel flexible fuel injector

    DOE Patents [OSTI]

    Tuthill, Richard S; Davis, Dustin W; Dai, Zhongtao

    2015-02-03

    A disclosed fuel injector provides mixing of fuel with airflow by surrounding a swirled fuel flow with first and second swirled airflows that ensures mixing prior to or upon entering the combustion chamber. Fuel tubes produce a central fuel flow along with a central airflow through a plurality of openings to generate the high velocity fuel/air mixture along the axis of the fuel injector in addition to the swirled fuel/air mixture.

  2. Nuclear reactor fuel element

    DOE Patents [OSTI]

    Johnson, Carl E. (Elk Grove, IL); Crouthamel, Carl E. (Richland, WA)

    1980-01-01

    A nuclear reactor fuel element is described which has an outer cladding, a central core of fissionable or mixed fissionable and fertile fuel material and a layer of oxygen gettering material on the inner surface of the cladding. The gettering material reacts with oxygen released by the fissionable material during irradiation of the core thereby preventing the oxygen from reacting with and corroding the cladding. Also described is an improved method for coating the inner surface of the cladding with a layer of gettering material.

  3. ClearFuels-Rentech Pilot-Scale Biorefinery

    Broader source: Energy.gov [DOE]

    The ClearFuels-Rentech pilot-scale biorefinery will use Fisher-Tropsch gas-to-liquids technology to create diesel and jet fuel.

  4. Solar thermochemical fuel production. (Conference) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 09 BIOMASS FUELS; 14 SOLAR ENERGY; BIOMASS; GASIFICATION; LIQUID FUELS; OXIDES; PRODUCTION; REDOX REACTIONS; SOLAR ...

  5. Gas Diffusion Electrodes for Fuel Cells - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    methanol fuel cells have an advantage over hydrogen fuel cells because the liquid methanol has high energy density and is easily transportable. However, one of the...

  6. Fuel properties to enable lifted-flame combustion

    SciTech Connect (OSTI)

    Kurtz, Eric

    2015-03-15

    The Fuel Properties to Enable Lifted-Flame Combustion project responded directly to solicitation DE-FOA-0000239 AOI 1A, Fuels and Lubricants for Advanced Combustion Regimes. This subtopic was intended to encompass clean and highly-efficient, liquid-fueled combustion engines to achieve extremely low engine-out nitrogen oxides (NOx) and particulate matter (PM) as a target and similar efficiency as state-of-the-art direct injection diesel engines. The intent of this project was to identify how fuel properties can be used to achieve controllable Leaner Lifted Flame Combustion (LLFC) with low NOx and PM emissions. Specifically, this project was expected to identify and test key fuel properties to enable LLFC and their compatibility with current fuel systems and to enhance combustion models to capture the effect of fuel properties on advanced combustion. Successful demonstration of LLFC may reduce the need for after treatment devices, thereby reducing costs and improving thermal efficiency. The project team consisted of key technical personnel from Ford Motor Company (FMC), the University of Wisconsin-Madison (UW), Sandia National Laboratories (SNL) and Lawrence Livermore National Laboratories (LLNL). Each partner had key roles in achieving project objectives. FMC investigated fuel properties relating to LLFC and sooting tendency. Together, FMC and UW developed and integrated 3D combustion models to capture fuel property combustion effects. FMC used these modeling results to develop a combustion system and define fuel properties to support a single-cylinder demonstration of fuel-enabled LLFC. UW investigated modeling the flame characteristics and emissions behavior of different fuels, including those with different cetane number and oxygen content. SNL led spray combustion experiments to quantify the effect of key fuel properties on combustion characteristics critical for LLFC, as well as single cylinder optical engine experiments to improve fundamental understanding of flame lift-off, generate model validation data, and demonstrate LLFC concurrent with FMC efforts. Additionally, LLNL was added to the project during the second year to develop a detailed kinetic mechanism for a key oxygenate to support CFD modeling. Successful completion of this project allowed the team to enhance fundamental understanding of LLFC, improve the state of current combustion models and increase understanding of desired fuel properties. This knowledge also improves our knowledge of how cost effective and environmentally friendly renewable fuels can assist in helping meet future emission and greenhouse gas regulations.

  7. Liquid phase Fischer-Tropsch (II) demonstration in the LaPorte Alternative Fuels Development Unit. Volume 1/2, Main Report. Final report

    SciTech Connect (OSTI)

    Bhatt, B.L.

    1995-09-01

    This report presents results from a demonstration of Liquid Phase Fischer-Tropsch (LPFT) technology in DOE`s Alternative Fuels Development Unit (AFDU) at LaPorte, Texas. The run was conducted in a bubble column at the AFDU in May--June 1994. The 10-day run demonstrated a very high level of reactor productivity for LPFT, more than five times the previously demonstrated productivity. The productivity was constrained by mass transfer limitations, perhaps due to slurry thickening as a result of carbon formation on the catalyst. With a cobalt catalyst or an improved iron catalyst, if the carbon formation can be avoided, there is significant room for further improvements. The reactor was operated with 0.7 H{sub 2}/CO synthesis gas in the range of 2400--11700 sl/hr-kg Fe, 175--750 psig and 270--300C. The inlet gas velocity ranged from 0.19 to 0.36 ft/sec. The demonstration was conducted at a pilot scale of 5 T/D. Catalyst activation with CO/N{sub 2} proceeded well. Initial catalyst activity was close to the expectations from the CAER autoclave runs. CO conversion of about 85% was obtained at the baseline condition. The catalyst also showed good water-gas shift activity and a low {alpha}. At high productivity conditions, reactor productivity of 136 grams of HC/hr -- liter of slurry volume was demonstrated, which was within the target of 120--150. However, mass transfer limitations were observed at these conditions. To alleviate these limitations and prevent excessive thickening, the slurry was diluted during the run. This enabled operations under kinetic control later in the run. But, the dilution resulted in lower conversion and reactor productivity. A new reactor internal heat exchanger, installed for high productivity conditions, performed well above design,and the system never limited the performance. The control can expected, the reactor temperature control needed manual intervention. The control can be improved by realigning the utility oil system.

  8. NREL: Transportation Research - Alternative Fuels Characterization

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alternative Fuels Characterization Find out about other biomass research projects at NREL. NREL alternative fuels projects help overcome technical barriers and expand markets for renewable, biodegradable vehicle fuels. These liquid fuels include higher-level ethanol blends, butanol, biodiesel, renewable diesel, other biomass-derived fuels, and natural gas. By studying the fuel chemistry as well as combustion and emissions impacts of alternative fuels, NREL helps improve engine efficiency, reduce

  9. Final Report for NFE-07-00912: Development of Model Fuels Experimental...

    Office of Scientific and Technical Information (OSTI)

    New fuels include bio-fuels such as ethanol or bio-diesel, drop-in bio-derived fuels and those derived from new crude oil sources such as gas-to-liquids, coal-to-liquids, oil ...

  10. Low NOx combustion using cogenerated oxygen and nitrogen streams

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, Lawrence E.; Snyder, William J.

    2009-02-03

    Combustion of hydrocarbon fuel is achieved with less formation of NOx by feeding the fuel into a slightly oxygen-enriched atmosphere, and separating air into oxygen-rich and nitrogen-rich streams which are fed separately into the combustion device.

  11. Fuel and fuel blending components from biomass derived pyrolysis oil

    DOE Patents [OSTI]

    McCall, Michael J.; Brandvold, Timothy A.; Elliott, Douglas C.

    2012-12-11

    A process for the conversion of biomass derived pyrolysis oil to liquid fuel components is presented. The process includes the production of diesel, aviation, and naphtha boiling point range fuels or fuel blending components by two-stage deoxygenation of the pyrolysis oil and separation of the products.

  12. 2008 Fuel Cell Technologies Market Report

    Fuel Cell Technologies Publication and Product Library (EERE)

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of

  13. 2009 Fuel Cell Market Report

    SciTech Connect (OSTI)

    Vincent, Bill; Gangi, Jennifer; Curtin, Sandra; Delmont, Elizabeth

    2010-11-01

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of fuel is supplied. Moreover, fuel cells do not burn fuel, making the process quiet, pollution-free and two to three times more efficient than combustion. Fuel cell systems can be a truly zero-emission source of electricity, if the hydrogen is produced from non-polluting sources. Global concerns about climate change, energy security, and air pollution are driving demand for fuel cell technology. More than 630 companies and laboratories in the United States are investing $1 billion a year in fuel cells or fuel cell component technologies. This report provides an overview of trends in the fuel cell industry and markets, including product shipments, market development, and corporate performance. It also provides snapshots of select fuel cell companies, including general.

  14. Fuel cell water transport

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E.; Hedstrom, James C.

    1990-01-01

    The moisture content and temperature of hydrogen and oxygen gases is regulated throughout traverse of the gases in a fuel cell incorporating a solid polymer membrane. At least one of the gases traverses a first flow field adjacent the solid polymer membrane, where chemical reactions occur to generate an electrical current. A second flow field is located sequential with the first flow field and incorporates a membrane for effective water transport. A control fluid is then circulated adjacent the second membrane on the face opposite the fuel cell gas wherein moisture is either transported from the control fluid to humidify a fuel gas, e.g., hydrogen, or to the control fluid to prevent excess water buildup in the oxidizer gas, e.g., oxygen. Evaporation of water into the control gas and the control gas temperature act to control the fuel cell gas temperatures throughout the traverse of the fuel cell by the gases.

  15. Probing oxygen vacancy concentration and homogeneity in solid-oxide

    Office of Scientific and Technical Information (OSTI)

    fuel-cell cathode materials on the subunit-cell level (Journal Article) | SciTech Connect Probing oxygen vacancy concentration and homogeneity in solid-oxide fuel-cell cathode materials on the subunit-cell level Citation Details In-Document Search Title: Probing oxygen vacancy concentration and homogeneity in solid-oxide fuel-cell cathode materials on the subunit-cell level Oxygen vacancy distributions and dynamics directly control the operation of solid-oxide fuel cells and are

  16. Liquid natural gas as a transportation fuel in the heavy trucking industry. Fourth quarterly progress report, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    Sutton, W.H.

    1995-09-01

    This project encompasses the first year of a proposed three year project with emphasis focused on LNG research issues that may be categorized as direct diesel replacement with LNG fuel, and long term storage/utilization of LNG vent gases produced by tank storage and fueling/handling operation. In addition, a potential new utilization of LNG fuel has been found, as a part of this work on the fundamental nature of adsorption of LNG vent gases in higher hydrocarbons; follow on research for this and other related applications and transfer of technology are proceeding at this time.

  17. Apparatus and method for solid fuel chemical looping combustion

    DOE Patents [OSTI]

    Siriwardane, Ranjani V; Weber, Justin M

    2015-04-14

    The disclosure provides an apparatus and method utilizing fuel reactor comprised of a fuel section, an oxygen carrier section, and a porous divider separating the fuel section and the oxygen carrier section. The porous divider allows fluid communication between the fuel section and the oxygen carrier section while preventing the migration of solids of a particular size. Maintaining particle segregation between the oxygen carrier section and the fuel section during solid fuel gasification and combustion processes allows gases generated in either section to participate in necessary reactions while greatly mitigating issues associated with mixture of the oxygen carrier with char or ash products. The apparatus and method may be utilized with an oxygen uncoupling oxygen carrier such as CuO, Mn.sub.3O.sub.4, or Co.sub.3O.sub.4, or utilized with a CO/H.sub.2 reducing oxygen carrier such as Fe.sub.2O.sub.3.

  18. Fuel cell arrangement

    DOE Patents [OSTI]

    Isenberg, A.O.

    1987-05-12

    A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber. 3 figs.

  19. Fuel cell arrangement

    DOE Patents [OSTI]

    Isenberg, Arnold O. (Forest Hills Boro, PA)

    1987-05-12

    A fuel cell arrangement is provided wherein cylindrical cells of the solid oxide electrolyte type are arranged in planar arrays where the cells within a plane are parallel. Planes of cells are stacked with cells of adjacent planes perpendicular to one another. Air is provided to the interior of the cells through feed tubes which pass through a preheat chamber. Fuel is provided to the fuel cells through a channel in the center of the cell stack; the fuel then passes the exterior of the cells and combines with the oxygen-depleted air in the preheat chamber.

  20. Emergency fuels utilization guidebook. Alternative Fuels Utilization Program

    SciTech Connect (OSTI)

    Not Available

    1980-08-01

    The basic concept of an emergency fuel is to safely and effectively use blends of specification fuels and hydrocarbon liquids which are free in the sense that they have been commandeered or volunteered from lower priority uses to provide critical transportation services for short-duration emergencies on the order of weeks, or perhaps months. A wide variety of liquid hydrocarbons not normally used as fuels for internal combustion engines have been categorized generically, including limited information on physical characteristics and chemical composition which might prove useful and instructive to fleet operators. Fuels covered are: gasoline and diesel fuel; alcohols; solvents; jet fuels; kerosene; heating oils; residual fuels; crude oils; vegetable oils; gaseous fuels.

  1. DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion

    Office of Scientific and Technical Information (OSTI)

    Engines (Technical Report) | SciTech Connect 6, AOP Task 1.1, Fuel Effects on Advanced Combustion Engines Citation Details In-Document Search Title: DOE Project 18546, AOP Task 1.1, Fuel Effects on Advanced Combustion Engines Research in 2011 was focused on diesel range fuels and diesel combustion and fuels evaluated in 2011 included a series of oxygenated biofuels fuels from University of Maine, oxygenated fuel compounds representing materials which could be made from sewage, oxygenated

  2. Single-reactor process for producing liquid-phase organic compounds from biomass

    SciTech Connect (OSTI)

    Dumesic, James A.; Simonetti, Dante A.; Kunkes, Edward L.

    2015-12-08

    Disclosed is a method for preparing liquid fuel and chemical intermediates from biomass-derived oxygenated hydrocarbons. The method includes the steps of reacting in a single reactor an aqueous solution of a biomass-derived, water-soluble oxygenated hydrocarbon reactant, in the presence of a catalyst comprising a metal selected from the group consisting of Cr, Mn, Fe, Co, Ni, Cu, Mo, Tc, Ru, Rh, Pd, Ag, W, Re, Os, Ir, Pt, and Au, at a temperature, and a pressure, and for a time sufficient to yield a self-separating, three-phase product stream comprising a vapor phase, an organic phase containing linear and/or cyclic mono-oxygenated hydrocarbons, and an aqueous phase.

  3. Single-reactor process for producing liquid-phase organic compounds from biomass

    SciTech Connect (OSTI)

    Dumesic, James A.; Simonetti, Dante A.; Kunkes, Edward L.

    2011-12-13

    Disclosed is a method for preparing liquid fuel and chemical intermediates from biomass-derived oxygenated hydrocarbons. The method includes the steps of reacting in a single reactor an aqueous solution of a biomass-derived, water-soluble oxygenated hydrocarbon reactant, in the presence of a catalyst comprising a metal selected from the group consisting of Cr, Mn, Fe, Co, Ni, Cu, Mo, Tc, Ru, Rh, Pd, Ag, W, Re, Os, Ir, Pt, and Au, at a temperature, and a pressure, and for a time sufficient to yield a self-separating, three-phase product stream comprising a vapor phase, an organic phase containing linear and/or cyclic mono-oxygenated hydrocarbons, and an aqueous phase.

  4. NUCLEAR REACTOR FUEL SYSTEMS

    DOE Patents [OSTI]

    Thamer, B.J.; Bidwell, R.M.; Hammond, R.P.

    1959-09-15

    Homogeneous reactor fuel solutions are reported which provide automatic recombination of radiolytic gases and exhibit large thermal expansion characteristics, thereby providing stability at high temperatures and enabling reactor operation without the necessity of apparatus to recombine gases formed by the radiolytic dissociation of water in the fuel and without the necessity of liquid fuel handling outside the reactor vessel except for recovery processes. The fuels consist of phosphoric acid and water solutions of enriched uranium, wherein the uranium is in either the hexavalent or tetravalent state.

  5. DKRW Advanced Fuels LLC | Open Energy Information

    Open Energy Info (EERE)

    Fuels LLC Place: Houston, Texas Zip: 77056 Product: Focues on projects that utilise coal gasification technology, including coal-to-liquids, methanation, and integrated coal...

  6. LIQUID METAL COMPOSITIONS CONTAINING URANIUM

    DOE Patents [OSTI]

    Teitel, R.J.

    1959-04-21

    Liquid metal compositions containing a solid uranium compound dispersed therein is described. Uranium combines with tin to form the intermetallic compound USn/sub 3/. It has been found that this compound may be incorporated into a liquid bath containing bismuth and lead-bismuth components, if a relatively small percentage of tin is also included in the bath. The composition has a low thermal neutron cross section which makes it suitable for use in a liquid metal fueled nuclear reactor.

  7. Coal and Coal-Biomass to Liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Coal-Biomass to Liquids Turning coal into liquid fuels like gasoline, diesel and jet fuel, with biomass to reduce carbon dioxide emissions, is the main goal of the Coal and Coal-Biomass to Liquids program. The program also aims to reduce the cost of these low-emission fuels, and will take advantage of carbon capture and sequestration technologies to further reduce greenhouse gas emissions. Other Coal and Coal-Biomass to Liquids (C&CBTL) Program Activities: The C&CBTL Program

  8. Oxygen-producing inert anodes for SOM process

    SciTech Connect (OSTI)

    Pal, Uday B

    2014-02-25

    An electrolysis system for generating a metal and molecular oxygen includes a container for receiving a metal oxide containing a metallic species to be extracted, a cathode positioned to contact a metal oxide housed within the container; an oxygen-ion-conducting membrane positioned to contact a metal oxide housed within the container; an anode in contact with the oxygen-ion-conducting membrane and spaced apart from a metal oxide housed within the container, said anode selected from the group consisting of liquid metal silver, oxygen stable electronic oxides, oxygen stable crucible cermets, and stabilized zirconia composites with oxygen stable electronic oxides.

  9. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    David R. Thompson; Lawrence E. Bool; Jack C. Chen

    2004-04-01

    Conventional wisdom says adding oxygen to a combustion system enhances product throughput, system efficiency, and, unless special care is taken, increases NOx emissions. This increase in NOx emissions is typically due to elevated flame temperatures associated with oxygen use leading to added thermal NOx formation. Innovative low flame temperature oxy-fuel burner designs have been developed and commercialized to minimize both thermal and fuel NOx formation for gas and oil fired industrial furnaces. To be effective these systems require close to 100% oxy-fuel combustion and the cost of oxygen is paid for by fuel savings and other benefits. For applications to coal-fired utility boilers at the current cost of oxygen, however, it is not economically feasible to use 100% oxygen for NOx control. In spite of this conventional wisdom, Praxair and its team members, in partnership with the US Department of Energy National Energy Technology Laboratory, have developed a novel way to use oxygen to reduce NOx emissions without resorting to complete oxy-fuel conversion. In this concept oxygen is added to the combustion process to enhance operation of a low NOx combustion system. Only a small fraction of combustion air is replaced with oxygen in the process. By selectively adding oxygen to a low NOx combustion system it is possible to reduce NOx emissions from nitrogen-containing fuels, including pulverized coal, while improving combustion characteristics such as unburned carbon. A combination of experimental work and modeling was used to define how well oxygen enhanced combustion could reduce NOx emissions. The results of this work suggest that small amounts of oxygen replacement can reduce the NOx emissions as compared to the air-alone system. NOx emissions significantly below 0.15 lbs/MMBtu were measured. Oxygen addition was also shown to reduce carbon in ash. Comparison of the costs of using oxygen for NOx control against competing technologies, such as SCR, show that this concept offers substantial savings over SCR and is an economically attractive alternative to purchasing NOx credits or installing other conventional technologies. In conjunction with the development of oxygen based low NOx technology, Praxair also worked on developing the economically enhancing oxygen transport membrane (OTM) technology which is ideally suited for integration with combustion systems to achieve further significant cost reductions and efficiency improvements. This OTM oxygen production technology is based on ceramic mixed conductor membranes that operate at high temperatures and can be operated in a pressure driven mode to separate oxygen with infinite selectivity and high flux. An OTM material was selected and characterized. OTM elements were successfully fabricated. A single tube OTM reactor was designed and assembled. Testing of dense OTM elements was conducted with promising oxygen flux results of 100% of target flux. However, based on current natural gas prices and stand-alone air separation processes, ceramic membranes do not offer an economic advantage for this application. Under a different DOE-NETL Cooperative Agreement, Praxair is continuing to develop oxygen transport membranes for the Advanced Boiler where the economics appear more attractive.

  10. Bio-Fuel Production Assisted with High Temperature Steam Electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Michael McKellar

    2012-06-01

    Two hybrid energy processes that enable production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure are presented. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), these two hybrid energy processes have the potential to provide a significant alternative petroleum source that could reduce dependence on imported oil. The first process discusses a hydropyrolysis unit with hydrogen addition from HTSE. Non-food biomass is pyrolyzed and converted to pyrolysis oil. The pyrolysis oil is upgraded with hydrogen addition from HTSE. This addition of hydrogen deoxygenates the pyrolysis oil and increases the pH to a tolerable level for transportation. The final product is synthetic crude that could then be transported to a refinery and input into the already used transportation fuel infrastructure. The second process discusses a process named Bio-Syntrolysis. The Bio-Syntrolysis process combines hydrogen from HTSE with CO from an oxygen-blown biomass gasifier that yields syngas to be used as a feedstock for synthesis of liquid synthetic crude. Conversion of syngas to liquid synthetic crude, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier.

  11. Distributed Reforming of Renewable Liquids via Water Splitting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Presented at the 2007 ...

  12. Process to upgrade coal liquids by extraction prior to hydrodenitrogenation

    DOE Patents [OSTI]

    Schneider, Abraham; Hollstein, Elmer J.; Janoski, Edward J.; Scheibel, Edward G.

    1982-01-01

    Oxygen compounds are removed, e.g., by extraction, from a coal liquid prior to its hydrogenation. As a result, compared to hydrogenation of such a non-treated coal liquid, the rate of nitrogen removal is increased.

  13. AGING EFFECTS ON THE PROPERTIES OF IMIDAZOLIUM, QUATERNARY AMMONIUM, PYRIDINIUM AND PYRROLIDINIUM-BASED IONIC LIQUIDS USED IN FUEL AND ENERGY PRODUCTION

    SciTech Connect (OSTI)

    Fox, E.

    2013-08-13

    Ionic liquids are often cited for their excellent thermal stability, a key property for their use as solvents and in the chemical processing of biofuels. However, there has been little supporting data on the long term aging effect of temperature on these materials. Imizadolium, quaternary ammonium, pyridinium, and pyrrolidnium-based ionic liquids with the bis(trifluoromethylsulfonyl)imide and bis(perfluoroethylsulfonyl)imide anions were aged for 2520 hours (15 weeks) at 200�C in air to determine the effects of an oxidizing environment on their chemical structure and thermal stability over time. It was found that the minor changes in the cation chemistry could greatly affect the properties of the ILs over time.

  14. Carbon Fuel Particles Used in Direct Carbon Conversion Fuel Cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2008-10-21

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  15. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-10-09

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  16. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2012-01-24

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  17. Carbon fuel particles used in direct carbon conversion fuel cells

    DOE Patents [OSTI]

    Cooper, John F.; Cherepy, Nerine

    2011-08-16

    A system for preparing particulate carbon fuel and using the particulate carbon fuel in a fuel cell. Carbon particles are finely divided. The finely dividing carbon particles are introduced into the fuel cell. A gas containing oxygen is introduced into the fuel cell. The finely divided carbon particles are exposed to carbonate salts, or to molten NaOH or KOH or LiOH or mixtures of NaOH or KOH or LiOH, or to mixed hydroxides, or to alkali and alkaline earth nitrates.

  18. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Clean School Bus Program Any school district or charter school may receive a grant through the Texas Commission on Environmental Quality (TCEQ) to pay for the incremental costs to install diesel oxidation catalysts, diesel particulate filters, emission-reducing add-on equipment, and other emissions reduction technologies in qualified school buses. Furthermore, funds may also be used to purchase qualifying fuels, including any liquid or gaseous fuel or additive registered or verified by the U.S.

  19. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Alternative Fuel Tax An excise tax rate of 9% of the average wholesale price on a per gallon basis applies to all special fuels, including diesel, natural gas, liquefied petroleum gas (propane), ethanol, biodiesel, hydrogen, and any other combustible gases and liquids, excluding gasoline, used to propel motor vehicles. For taxation purposes, one gasoline gallon equivalent (GGE) of compressed natural gas (CNG) is equal to 5.66 pounds (lbs.) or 126.67 cubic feet. One GGE of liquefied natural gas

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Biofuel Production Facility Tax Exemption Any newly constructed or expanded biomass-to-energy facility is exempt from state property taxes for up to 10 taxable years immediately following the taxable year in which construction or installation is completed. A biomass-to-energy facility includes any industrial process plant that uses biomass to produce at least 500,000 gallons of cellulosic alcohol fuel, liquid or gaseous fuel, or other source of energy in a quantity with energy content at least

  1. Pyroprocess for processing spent nuclear fuel

    DOE Patents [OSTI]

    Miller, William E.; Tomczuk, Zygmunt

    2002-01-01

    This is a pyroprocess for processing spent nuclear fuel. The spent nuclear fuel is chopped into pieces and placed in a basket which is lowered in to a liquid salt solution. The salt is rich in ZrF.sub.4 and containing alkali or alkaline earth fluorides, and in particular, the salt chosen was LiF-50 mol % ZrF.sub.4 with a eutectic melting point of 500.degree. C. Prior to lowering the basket, the salt is heated to a temperature of between 550.degree. C. and 700.degree. C. in order to obtain a molten solution. After dissolution the oxides of U, Th, rare earth and other like oxides, the salt bath solution is subject to hydro-fluorination to remove the oxygen and then to a fluorination step to remove U as gaseous UF.sub.6. In addition, after dissolution, the basket contains PuO.sub.2 and undissolved parts of the fuel rods, and the basket and its contents are processed to remove the Pu.

  2. Linear air-fuel sensor development

    SciTech Connect (OSTI)

    Garzon, F.; Miller, C.

    1996-12-14

    The electrochemical zirconia solid electrolyte oxygen sensor, is extensively used for monitoring oxygen concentrations in various fields. They are currently utilized in automobiles to monitor the exhaust gas composition and control the air-to-fuel ratio, thus reducing harmful emission components and improving fuel economy. Zirconia oxygen sensors, are divided into two classes of devices: (1) potentiometric or logarithmic air/fuel sensors; and (2) amperometric or linear air/fuel sensors. The potentiometric sensors are ideally suited to monitor the air-to-fuel ratio close to the complete combustion stoichiometry; a value of about 14.8 to 1 parts by volume. This occurs because the oxygen concentration changes by many orders of magnitude as the air/fuel ratio is varied through the stoichiometric value. However, the potentiometric sensor is not very sensitive to changes in oxygen partial pressure away from the stoichiometric point due to the logarithmic dependence of the output voltage signal on the oxygen partial pressure. It is often advantageous to operate gasoline power piston engines with excess combustion air; this improves fuel economy and reduces hydrocarbon emissions. To maintain stable combustion away from stoichiometry, and enable engines to operate in the excess oxygen (lean burn) region several limiting-current amperometric sensors have been reported. These sensors are based on the electrochemical oxygen ion pumping of a zirconia electrolyte. They typically show reproducible limiting current plateaus with an applied voltage caused by the gas diffusion overpotential at the cathode.

  3. Development of alternative fuels from coal-derived syngas

    SciTech Connect (OSTI)

    Brown, D.M.

    1992-05-19

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products' laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively benign'' system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE's program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

  4. Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique

    Broader source: Energy.gov [DOE]

    Presentation slides from the Fuel Cell Technologies Office webinar, Testing Oxygen Reduction Reaction Activity with the Rotating Disc Electrode Technique, held March 12, 2013.

  5. LMFBR fuel assembly design for HCDA fuel dispersal

    DOE Patents [OSTI]

    Lacko, Robert E.; Tilbrook, Roger W.

    1984-01-01

    A fuel assembly for a liquid metal fast breeder reactor having an upper axial blanket region disposed in a plurality of zones within the fuel assembly. The characterization of a zone is dependent on the height of the axial blanket region with respect to the active fuel region. The net effect of having a plurality of zones is to establish a dispersal flow path for the molten materials resulting during a core meltdown accident. Upward flowing molten material can escape from the core region and/or fuel assembly without solidifying on the surface of fuel rods due to the heat sink represented by blanket region pellets.

  6. Nitrogen/oxygen separations in metal-organic frameworks for clean fossil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    fuel combustion | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Nitrogen/oxygen separations in metal-organic frameworks for clean fossil fuel combustion

  7. Vehicle Technologies Office Merit Review 2014: Intake Air Oxygen Sensor

    Broader source: Energy.gov [DOE]

    Presentation given by Robert Bosch at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensors.

  8. Vehicle Technologies Office Merit Review 2015: Intake Air Oxygen Sensor

    Broader source: Energy.gov [DOE]

    Presentation given by Robert Bosch at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about intake air oxygen sensor.

  9. Enhancing SNCR-aided combustion with oxygen addition

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Wu, Kuang Tsai; Bool, III, Lawrence E.

    2004-03-09

    NOx emissions from combustion are reduced, NOx reduction efficiency by SNCR is improved, and other efficiencies are realized, by injecting oxygen into a fuel-rich combustion zone under controlled conditions.

  10. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, Eugene

    1985-01-01

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  11. Fuel cell having dual electrode anode or cathode

    DOE Patents [OSTI]

    Findl, E.

    1984-04-10

    A fuel cell that is characterized by including a dual electrode anode that is operable to simultaneously electro-oxidize a gaseous fuel and a liquid fuel. In alternative embodiments, a fuel cell having a single electrode anode is provided with a dual electrode cathode that is operable to simultaneously reduce a gaseous oxidant and a liquid oxidant to electro-oxidize a fuel supplied to the cell.

  12. Fuel cell system with combustor-heated reformer

    DOE Patents [OSTI]

    Pettit, William Henry

    2000-01-01

    A fuel cell system including a fuel reformer heated by a catalytic combustor fired by anode effluent and/or fuel from a liquid fuel supply providing fuel for the fuel cell. The combustor includes a vaporizer section heated by the combustor exhaust gases for vaporizing the fuel before feeding it into the combustor. Cathode effluent is used as the principle oxidant for the combustor.

  13. Ultrastable Superbase-Derived Protic Ionic Liquids - Energy Innovation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Portal Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Ultrastable Superbase-Derived Protic Ionic Liquids Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryORNL researchers developed a method of producing a new family of conductive,low-volatility protic ionic liquids (PILs). Protic ionic liquids can be used in protonexchange membrane fuel cells for the transformation of chemical energy to electrical energy. These

  14. Electrocatalyst for oxygen reduction with reduced platinum oxidation and dissolution rates

    DOE Patents [OSTI]

    Adzic, Radoslav; Zhang, Junliang; Vukmirovic, Miomir

    2012-11-13

    The invention relates to platinum-metal oxide composite particles and their use as electrocatalysts in oxygen-reducing cathodes and fuel cells. The invention particularly relates to methods for preventing the oxidation of the platinum electrocatalyst in the cathodes of fuel cells by use of these platinum-metal oxide composite particles. The invention additionally relates to methods for producing electrical energy by supplying such a fuel cell with an oxidant, such as oxygen, and a fuel source, such as hydrogen.

  15. Electrocatalyst for oxygen reduction with reduced platinum oxidation and dissolution rates

    DOE Patents [OSTI]

    Adzic, Radoslav; Zhang, Junliang; Vukmirovic, Miomir

    2011-11-22

    The invention relates to platinum-metal oxide composite particles and their use as electrocatalysts in oxygen-reducing cathodes and fuel cells. The invention particularly relates to methods for preventing the oxidation of the platinum electrocatalyst in the cathodes of fuel cells by use of these platinum-metal oxide composite particles. The invention additionally relates to methods for producing electrical energy by supplying such a fuel cell with an oxidant, such as oxygen, and a fuel source, such as hydrogen.

  16. Heated transportable fuel cell cartridges

    DOE Patents [OSTI]

    Lance, Joseph R. (N. Huntingdon, PA); Spurrier, Francis R. (Whitehall, PA)

    1985-01-01

    A fuel cell stack protective system is made where a plurality of fuel cells, each containing liquid electrolyte subject to crystallization, is enclosed by a containing vessel, and where at least one electric heater is placed in the containing vessel and is capable of preventing electrolyte crystallization.

  17. Neutron Emission Characteristics of Two Mixed-Oxide Fuels: Simulations and Initial Experiments

    SciTech Connect (OSTI)

    D. L. Chichester; S. A. Pozzi; J. L. Dolan; M. Flaska; J. T. Johnson; E. H. Seabury; E. M. Gantz

    2009-07-01

    Simulations and experiments have been carried out to investigate the neutron emission characteristics of two mixed-oxide (MOX) fuels at Idaho National Laboratory (INL). These activities are part of a project studying advanced instrumentation techniques in support of the U.S. Department of Energy's Fuel Cycle Research and Development program and it's Materials Protection, Accounting, and Control for Transmutation (MPACT) campaign. This analysis used the MCNP-PoliMi Monte Carlo simulation tool to determine the relative strength and energy spectra of the different neutron source terms within these fuels, and then used this data to simulate the detection and measurement of these emissions using an array of liquid scintillator neutron spectrometers. These calculations accounted for neutrons generated from the spontaneous fission of the actinides in the MOX fuel as well as neutrons created via (alpha,n) reactions with oxygen in the MOX fuel. The analysis was carried out to allow for characterization of both neutron energy as well as neutron coincidences between multiple detectors. Coincidences between prompt gamma rays and neutrons were also analyzed. Experiments were performed at INL with the same materials used in the simulations to benchmark and begin validation tests of the simulations. Data was collected in these experiments using an array of four liquid scintillators and a high-speed waveform digitizer. Advanced digital pulse-shape discrimination algorithms were developed and used to collect this data. Results of the simulation and modeling studies are presented together with preliminary results from the experimental campaign.

  18. Artificial oxygen transport protein

    DOE Patents [OSTI]

    Dutton, P. Leslie

    2014-09-30

    This invention provides heme-containing peptides capable of binding molecular oxygen at room temperature. These compounds may be useful in the absorption of molecular oxygen from molecular oxygen-containing atmospheres. Also included in the invention are methods for treating an oxygen transport deficiency in a mammal.

  19. Ionic Liquids as Multi-Functional Lubricant Additives to Enhance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Technologies Office Merit Review 2014: Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants Ionic Liquids as Novel Engine ...

  20. Low-Emissions Burner Technology using Biomass-Derived Liquid...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    This factsheet describes a project that developed fuel-flexible, low-emissions burner technology capable of using biomass-derived liquid fuels, such as glycerin or fatty acids, as ...

  1. Coal and Coal-Biomass to Liquids FAQs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coal and Coal-Biomass to Liquids FAQs faq-header-big.jpg BASICS Q: How are gasoline and diesel fuel made from coal? A: Gasoline and diesel fuels can be produced from coal in two ...

  2. Fossil fuels -- future fuels

    SciTech Connect (OSTI)

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  3. Short-Term Outlook for Hydrocarbon Gas Liquids - Energy Information...

    U.S. Energy Information Administration (EIA) Indexed Site

    Figures Tables Custom Table Builder Real Prices Viewer Forecast Changes (PDF) Special ... The liquid fuels production forecast reflects a 1.24 million bd decline in crude oil ...

  4. Vehicle Technologies Office Merit Review 2014: Ionic Liquids...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Viscosity Fuel-Efficient Engine Lubricants Vehicle Technologies Office Merit Review 2014: Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity ...

  5. Fuel cell power supply with oxidant and fuel gas switching

    DOE Patents [OSTI]

    McElroy, James F.; Chludzinski, Paul J.; Dantowitz, Philip

    1987-01-01

    This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation.

  6. Fuel cell power supply with oxidant and fuel gas switching

    DOE Patents [OSTI]

    McElroy, J.F.; Chludzinski, P.J.; Dantowitz, P.

    1987-04-14

    This invention relates to a fuel cell vehicular power plant. Fuel for the fuel stack is supplied by a hydrocarbon (methanol) catalytic cracking reactor and CO shift reactor. A water electrolysis subsystem is associated with the stack. During low power operation part of the fuel cell power is used to electrolyze water with hydrogen and oxygen electrolysis products being stored in pressure vessels. During peak power intervals, viz, during acceleration or start-up, pure oxygen and pure hydrogen from the pressure vessel are supplied as the reaction gases to the cathodes and anodes in place of air and methanol reformate. This allows the fuel cell stack to be sized for normal low power/air operation but with a peak power capacity several times greater than that for normal operation. 2 figs.

  7. NEUTRONIC REACTOR FUEL PUMP

    DOE Patents [OSTI]

    Cobb, W.G.

    1959-06-01

    A reactor fuel pump is described which offers long life, low susceptibility to radiation damage, and gaseous fission product removal. An inert-gas lubricated bearing supports a journal on one end of the drive shsft. The other end has an impeller and expansion chamber which effect pumping and gas- liquid separation. (T.R.H.)

  8. Improving Catalyst Efficiency in Bio-Based Hydrocarbon Fuels; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    2015-06-01

    This article investigates upgrading biomass pyrolysis vapors to form hydrocarbon fuels and chemicals using catalysts with different concentrations of acid sites. It shows that greater separation of acid sites makes catalysts more efficient at producing hydrocarbon fuels and chemicals. The conversion of biomass into liquid transportation fuels has attracted significant attention because of depleting fossil fuel reserves and environmental concerns resulting from the use of fossil fuels. Biomass is a renewable resource, which is abundant worldwide and can potentially be exploited to produce transportation fuels that are less damaging to the environment. This renewable resource consists of cellulose (40–50%), hemicellulose (25–35%), and lignin (16–33%) biopolymers in addition to smaller quantities of inorganic materials such as silica and alkali and alkaline earth metals (calcium and potassium). Fast pyrolysis is an attractive thermochemical technology for converting biomass into precursors for hydrocarbon fuels because it produces up to 75 wt% bio-oil,1 which can be upgraded to feedstocks and/or blendstocks for further refining to finished fuels. Bio-oil that has not been upgraded has limited applications because of the presence of oxygen-containing functional groups, derived from cellulose, hemicellulose and lignin, which gives rise to high acidity, high viscosity, low heating value, immiscibility with hydrocarbons and aging during storage. Ex situ catalytic vapor phase upgrading is a promising approach for improving the properties of bio-oil. The goal of this process is to reject oxygen and produce a bio-oil with improved properties for subsequent downstream conversion to hydrocarbons.

  9. Alternative Fuel Vehicle Data - Energy Information Administration

    U.S. Energy Information Administration (EIA) Indexed Site

    & Alternative Fuels - U.S. Energy Information Administration (EIA) U.S. Energy Information Administration - EIA - Independent Statistics and Analysis Sources & Uses Petroleum & Other Liquids Crude oil, gasoline, heating oil, diesel, propane, and other liquids including biofuels and natural gas liquids. Natural Gas Exploration and reserves, storage, imports and exports, production, prices, sales. Electricity Sales, revenue and prices, power plants, fuel use, stocks, generation, trade,

  10. A Comparison of Combustion and Emissions of Diesel Fuels and...

    Broader source: Energy.gov (indexed) [DOE]

    was used to study how selected oxygenated fuels affect combustion and emissions in a modern diesel engine during conventional combustion and low-temperature combustion (LTC). ...

  11. ionic-liquid pretreatment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ionic-liquid pretreatment - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  12. Controlled air injection for a fuel cell system

    DOE Patents [OSTI]

    Fronk, Matthew H. (Honeove Falls, NY)

    2002-01-01

    A method and apparatus for injecting oxygen into a fuel cell reformate stream to reduce the level of carbon monoxide while preserving the level of hydrogen in a fuel cell system.

  13. Controlled air injection for a fuel cell system

    DOE Patents [OSTI]

    Fronk, Matthew H.

    2003-06-10

    A method and apparatus for injecting oxygen into a fuel cell reformate stream to reduce the level of carbon monoxide while preserving the level of hydrogen in a fuel cell system.

  14. 2009 Fuel Cell Market Report, November 2010

    SciTech Connect (OSTI)

    Not Available

    2010-11-01

    Fuel cells are electrochemical devices that combine hydrogen and oxygen to produce electricity, water, and heat. Unlike batteries, fuel cells continuously generate electricity, as long as a source of fuel is supplied. Moreover, fuel cells do not burn fuel, making the process quiet, pollution-free and two to three times more efficient than combustion. Fuel cell systems can be a truly zero-emission source of electricity, if the hydrogen is produced from non-polluting sources. Global concerns about climate change, energy security, and air pollution are driving demand for fuel cell technology. More than 630 companies and laboratories in the United States are investing $1 billion a year in fuel cells or fuel cell component technologies. This report provides an overview of trends in the fuel cell industry and markets, including product shipments, market development, and corporate performance. It also provides snapshots of select fuel cell companies, including general.

  15. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1994-12-31

    Opportunity fuels - fuels that can be converted to other forms of energy at lower cost than standard fossil fuels - are discussed in outline form. The type and source of fuels, types of fuels, combustability, methods of combustion, refinery wastes, petroleum coke, garbage fuels, wood wastes, tires, and economics are discussed.

  16. Palladium-cobalt particles as oxygen-reduction electrocatalysts

    DOE Patents [OSTI]

    Adzic, Radoslav; Huang, Tao

    2009-12-15

    The present invention relates to palladium-cobalt particles useful as oxygen-reducing electrocatalysts. The invention also relates to oxygen-reducing cathodes and fuel cells containing these palladium-cobalt particles. The invention additionally relates to methods for the production of electrical energy by using the palladium-cobalt particles of the invention.

  17. Fuel cell membrane humidification

    DOE Patents [OSTI]

    Wilson, Mahlon S.

    1999-01-01

    A polymer electrolyte membrane fuel cell assembly has an anode side and a cathode side separated by the membrane and generating electrical current by electrochemical reactions between a fuel gas and an oxidant. The anode side comprises a hydrophobic gas diffusion backing contacting one side of the membrane and having hydrophilic areas therein for providing liquid water directly to the one side of the membrane through the hydrophilic areas of the gas diffusion backing. In a preferred embodiment, the hydrophilic areas of the gas diffusion backing are formed by sewing a hydrophilic thread through the backing. Liquid water is distributed over the gas diffusion backing in distribution channels that are separate from the fuel distribution channels.

  18. Properties of Liquid Plutonium

    SciTech Connect (OSTI)

    Freibert, Franz J.; Mitchell, Jeremy N.; Schwartz, Daniel S.; Saleh, Tarik A.; Migliori, Albert

    2012-08-02

    Unalloyed polycrystalline Pu displays extreme thermal expansion behavior, i.e., {alpha} {yields} {beta} {yields} {gamma} {yields} {delta} increases by 25% in volume and {delta} {yields} {var_epsilon} {yields} liquid decreases by 4.5% in volume. Thus, making it difficult to measure density into the liquid state. Dilatometer outfitted with CaF molten metal cell offers a proven capability to measure thermal expansion in molten metals, but has yet to be proven for Pu. Historic data from the liquid nuclear fuels program will prove extremely useful as a guide to future measurements. 3.3at% Ga changes Pu molten metal properties: 50% increase in viscosity and {approx}3% decrease in density. Fe may decrease the density by a small amount assuming an averaging of densities for Pu-Ga and Pu-Fe liquids. More recent Boivineau (2009) work needs some interpretation, but technique is being employed in (U,Pu)O{sub 2} nuclear fuels program (Pu Futures, 2012).

  19. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H. (Sante Fe, NM); Chung, Brandon W. (Los Alamos, NM); Raistrick, Ian D. (Los Alamos, NM); Brosha, Eric L. (Los Alamos, NM)

    1996-01-01

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer.

  20. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Chung, B.W.; Raistrick, I.D.; Brosha, E.L.

    1996-08-06

    Solid state oxygen sensors are provided with a yttria-doped zirconia as an electrolyte and use the electrochemical oxygen pumping of the zirconia electrolyte. A linear relationship between oxygen concentration and the voltage arising at a current plateau occurs when oxygen accessing the electrolyte is limited by a diffusion barrier. A diffusion barrier is formed herein with a mixed electronic and oxygen ion-conducting membrane of lanthanum-containing perovskite or zirconia-containing fluorite. A heater may be used to maintain an adequate oxygen diffusion coefficient in the mixed conducting layer. 4 figs.

  1. Automotive Fuel Processor Development and Demonstration with Fuel Cell Systems

    SciTech Connect (OSTI)

    Nuvera Fuel Cells

    2005-04-15

    The potential for fuel cell systems to improve energy efficiency and reduce emissions over conventional power systems has generated significant interest in fuel cell technologies. While fuel cells are being investigated for use in many applications such as stationary power generation and small portable devices, transportation applications present some unique challenges for fuel cell technology. Due to their lower operating temperature and non-brittle materials, most transportation work is focusing on fuel cells using proton exchange membrane (PEM) technology. Since PEM fuel cells are fueled by hydrogen, major obstacles to their widespread use are the lack of an available hydrogen fueling infrastructure and hydrogen's relatively low energy storage density, which leads to a much lower driving range than conventional vehicles. One potential solution to the hydrogen infrastructure and storage density issues is to convert a conventional fuel such as gasoline into hydrogen onboard the vehicle using a fuel processor. Figure 2 shows that gasoline stores roughly 7 times more energy per volume than pressurized hydrogen gas at 700 bar and 4 times more than liquid hydrogen. If integrated properly, the fuel processor/fuel cell system would also be more efficient than traditional engines and would give a fuel economy benefit while hydrogen storage and distribution issues are being investigated. Widespread implementation of fuel processor/fuel cell systems requires improvements in several aspects of the technology, including size, startup time, transient response time, and cost. In addition, the ability to operate on a number of hydrocarbon fuels that are available through the existing infrastructure is a key enabler for commercializing these systems. In this program, Nuvera Fuel Cells collaborated with the Department of Energy (DOE) to develop efficient, low-emission, multi-fuel processors for transportation applications. Nuvera's focus was on (1) developing fuel processor subsystems (fuel reformer, CO cleanup, and exhaust cleanup) that were small enough to integrate on a vehicle and (2) evaluating the fuel processor system performance for hydrogen production, efficiency, thermal integration, startup, durability and ability to integrate with fuel cells. Nuvera carried out a three-part development program that created multi-fuel (gasoline, ethanol, natural gas) fuel processing systems and investigated integration of fuel cell / fuel processor systems. The targets for the various stages of development were initially based on the goals of the DOE's Partnership for New Generation Vehicles (PNGV) initiative and later on the Freedom Car goals. The three parts are summarized below with the names based on the topic numbers from the original Solicitation for Financial Assistance Award (SFAA).

  2. Combustion process for synthesis of carbon nanomaterials from liquid hydrocarbon

    DOE Patents [OSTI]

    Diener, Michael D.; Alford, J. Michael; Nabity, James; Hitch, Bradley D.

    2007-01-02

    The present invention provides a combustion apparatus for the production of carbon nanomaterials including fullerenes and fullerenic soot. Most generally the combustion apparatus comprises one or more inlets for introducing an oxygen-containing gas and a hydrocarbon fuel gas in the combustion system such that a flame can be established from the mixed gases, a droplet delivery apparatus for introducing droplets of a liquid hydrocarbon feedstock into the flame, and a collector apparatus for collecting condensable products containing carbon nanomaterials that are generated in the combustion system. The combustion system optionally has a reaction zone downstream of the flame. If this reaction zone is present the hydrocarbon feedstock can be introduced into the flame, the reaction zone or both.

  3. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, Fernando H.; Brosha, Eric L.

    1997-01-01

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures.

  4. Vehicle Technologies Office: 2014 Fuel and Lubricant Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Merit Review 2014: Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants Vehicle Technologies Office: 2012 Fuel and Lubricant ...

  5. Fuel assembly transfer basket for pool type nuclear reactor vessels

    DOE Patents [OSTI]

    Fanning, Alan W.; Ramsour, Nicholas L.

    1991-01-01

    A fuel assembly transfer basket for a pool type, liquid metal cooled nuclear reactor having a side access loading and unloading port for receiving and relinquishing fuel assemblies during transfer.

  6. Assessment of Environmental Impacts of Shell GTL Fuel | Department of

    Broader source: Energy.gov (indexed) [DOE]

    Energy cherrillo.pdf More Documents & Publications An Evaluation of Shell GTL Diesel Shell Gas to Liquids in the context of a Future Fuel Strategy - Technical Marketing Aspects Verification of Shell GTL Fuel as CARB Alternative Diesel

  7. Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal-Derived Liquids to Enable HCCI Technology Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion, and Emissions Cetane Performance and Chemistry Comparing ...

  8. FUEL FOR NEUTRONIC REACTORS AND PROCESS OF MAKING

    DOE Patents [OSTI]

    Abraham, B.M.; Flotow, H.E.

    1961-05-01

    A fuel material is offered for nuclear reactors consisting of UO/sub 2// sub .//sub 0//sub 0/ suspended in a sodium-containing liquid metal.

  9. Report: Efficiency, Alternative Fuels to Impact Market Through...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    analyzes projections made by the U.S. Energy Information Administration in its Annual Energy Outlook 2014. Liquid fuelsgasoline, diesel fuel, and E85, which can...

  10. LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Thornton, J.D.

    1957-12-31

    This patent relates to liquid-liquid extraction columns having a means for pulsing the liquid in the column to give it an oscillatory up and down movement, and consists of a packed column, an inlet pipe for the dispersed liquid phase and an outlet pipe for the continuous liquid phase located in the direct communication with the liquid in the lower part of said column, an inlet pipe for the continuous liquid phase and an outlet pipe for the dispersed liquid phase located in direct communication with the liquid in the upper part of said column, a tube having one end communicating with liquid in the lower part of said column and having its upper end located above the level of said outlet pipe for the dispersed phase, and a piston and cylinder connected to the upper end of said tube for applying a pulsating pneumatic pressure to the surface of the liquid in said tube so that said surface rises and falls in said tube.

  11. Coal and Biomass to Liquids | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal to Liquids » Coal and Biomass to Liquids Coal and Biomass to Liquids Over the last several decades, the Office of Fossil Energy performed RD&D activities that made significant advancements in the areas of coal conversion to liquid fuels and chemicals. Technology improvements and cost reductions that were achieved led to the construction of demonstration-scale facilities. The program is now supporting work to reduce the carbon footprint of coal derived liquids by incorporating the

  12. Oil Shale and Other Unconventional Fuels Activities | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Naval Reserves » Oil Shale and Other Unconventional Fuels Activities Oil Shale and Other Unconventional Fuels Activities The Fossil Energy program in oil shale focuses on reviewing the potential of oil shale as a strategic resource for liquid fuels. The Fossil Energy program in oil shale focuses on reviewing the potential of oil shale as a strategic resource for liquid fuels. It is generally agreed that worldwide petroleum supply will eventually reach its productive limit, peak, and begin a

  13. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, D.W.

    1994-09-06

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured. 1 fig.

  14. Oxygen partial pressure sensor

    DOE Patents [OSTI]

    Dees, Dennis W.

    1994-01-01

    A method for detecting oxygen partial pressure and an oxygen partial pressure sensor are provided. The method for measuring oxygen partial pressure includes contacting oxygen to a solid oxide electrolyte and measuring the subsequent change in electrical conductivity of the solid oxide electrolyte. A solid oxide electrolyte is utilized that contacts both a porous electrode and a nonporous electrode. The electrical conductivity of the solid oxide electrolyte is affected when oxygen from an exhaust stream permeates through the porous electrode to establish an equilibrium of oxygen anions in the electrolyte, thereby displacing electrons throughout the electrolyte to form an electron gradient. By adapting the two electrodes to sense a voltage potential between them, the change in electrolyte conductivity due to oxygen presence can be measured.

  15. High temperature methods for forming oxidizer fuel

    DOE Patents [OSTI]

    Bravo, Jose Luis (Houston, TX)

    2011-01-11

    A method of treating a formation fluid includes providing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes carbon dioxide, hydrogen sulfide, hydrocarbons, hydrogen or mixtures thereof. Molecular oxygen is separated from air to form a molecular oxygen stream comprising molecular oxygen. The first gas stream is combined with the molecular oxygen stream to form a combined stream comprising molecular oxygen and the first gas stream. The combined stream is provided to one or more downhole burners.

  16. Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated Nanocrystalline Cubic Zirconia

    SciTech Connect (OSTI)

    Edmondson, P. D.; Weber, William J.; Namavar, Fereydoon; Zhang, Yanwen

    2011-07-13

    The oxygen ion conductivity, attributed to an oxygen vacancy mechanism, of yttria-stabilized zirconia membranes used in solid oxide fuel cells is restricted due to trapping limitations. In this work, a high concentration of oxygen vacancies has been deliberately introduced into nanocrystalline stabilizer-free zirconia through ion-irradiation. Oxygen vacancies with different charge states can be produced by varying irradiation temperatures. Due to the reduced trapping sites and high oxygen vacancy concentration, this work suggests that the efficiency of solid oxide fuel cells can be improved.

  17. Fuel Options

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cycle Research & Development Fuel Cycle Research & Development Fuel Cycle Research & Development The mission of the Fuel Cycle Research and Development (FCRD) program is to conduct research and development to help develop sustainable fuel cycles, as described in the Nuclear Energy Research and Development Roadmap. Sustainable fuel cycle options are those that improve uranium resource utilization, maximize energy generation, minimize waste generation, improve safety, and limit

  18. Alternative Fuels Data Center: Fuel Prices

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Vehicles Printable Version Share this resource Send a link to Alternative Fuels Data Center: Fuel Prices to someone by E-mail Share Alternative Fuels Data Center: Fuel Prices on Facebook Tweet about Alternative Fuels Data Center: Fuel Prices on Twitter Bookmark Alternative Fuels Data Center: Fuel Prices on Google Bookmark Alternative Fuels Data Center: Fuel Prices on Delicious Rank Alternative Fuels Data Center: Fuel Prices on Digg Find More places to share Alternative Fuels Data Center: Fuel

  19. Liquid metal cooled nuclear reactor plant system

    DOE Patents [OSTI]

    Hunsbedt, Anstein; Boardman, Charles E.

    1993-01-01

    A liquid metal cooled nuclear reactor having a passive cooling system for removing residual heat resulting for fuel decay during reactor shutdown, or heat produced during a mishap. The reactor system is enhanced with sealing means for excluding external air from contact with the liquid metal coolant leaking from the reactor vessel during an accident. The invention also includes a silo structure which resists attack by leaking liquid metal coolant, and an added unique cooling means.

  20. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Liquefied Natural Gas (LNG) Tax LNG is taxed at a rate of $0.14 per gallon when used as a motor fuel. For taxation purposes, LNG is converted to its gasoline gallon equivalent (GGE) at the rate of 1.5536 gallons of LNG to equal one volumetric gross gallon of gasoline. LNG is defined as natural gas for use as a motor fuel, which has been cooled to approximately -260 degrees Fahrenheit and is in a liquid state. (Reference South Dakota Statutes 10-47B-3 and 10-47B-4)

  1. Studies on the new fuels with Santilli magnecular structure and their industrial applications

    SciTech Connect (OSTI)

    Pandhurnekar, Chandrashekhar P.

    2015-03-10

    Professor R. M. Santilli, the Italian-American physicist, for the first time in the history of Science, presented the theoretical and experimental evidence on the existence of the new chemical species of magnecules [1]. This new species mainly consist of individual atoms, radicals and conventional molecules bonded together with stable clusters under the new attractive force primarily originating from torroidal polarization of orbitals of atomic electrons under strong magnetic field. The main contribution in this area was the production of Magnegas{sup TM}, new clean fuels developed by Prof. Santilli, which are produced as byproducts of recycling nonradioactive liquid feedstock such as antifreeze waste, engine oil waste, town sewage, crude oil, etc., and generally vary with the liquid used for their production. A new technology, called Plasma Arc FlowTM, flows the waste through a submerged electric arc between conventional electrodes. The arc decomposes the liquid molecules into their atomic constituents, and forms a plasma in the immediate vicinity of the electrodes at about 10,000{sup 0} F. The technology then moves the plasma away from the electrodes, and controls its recombination into environmentally acceptable fuels. In fact, the exhaust of magnegases shows: absence of carcinogenic or other toxic substances; breathable oxygen up 14 percent; and carbon dioxide down to 0.01 percent. Since, in addition, the new fuels can be produced everywhere, and have environmentally acceptable exhausts, Magnegases offer promising possibilities to satisfy our ever increasing energy needs, as well as to contain the alarming environmental problems caused by fossil fuels. Thus, it was thought worthwhile to present some of the industrial applications of environmentally benign fuel consisting magnecular bonds [2, 3, 4, 5]. Also in the present communications, some of the experimental evidences of Santillis new chemical species i. e. Magnecules which had been published recently have been summarized [6, 7, 8].

  2. Methods of producing transportation fuel

    DOE Patents [OSTI]

    Nair, Vijay; Roes, Augustinus Wilhelmus Maria; Cherrillo, Ralph Anthony; Bauldreay, Joanna M.

    2011-12-27

    Systems, methods, and heaters for treating a subsurface formation are described herein. At least one method for producing transportation fuel is described herein. The method for producing transportation fuel may include providing formation fluid having a boiling range distribution between -5.degree. C. and 350.degree. C. from a subsurface in situ heat treatment process to a subsurface treatment facility. A liquid stream may be separated from the formation fluid. The separated liquid stream may be hydrotreated and then distilled to produce a distilled stream having a boiling range distribution between 150.degree. C. and 350.degree. C. The distilled liquid stream may be combined with one or more additives to produce transportation fuel.

  3. Integrated turbomachine oxygen plant

    SciTech Connect (OSTI)

    Anand, Ashok Kumar; DePuy, Richard Anthony; Muthaiah, Veerappan

    2014-06-17

    An integrated turbomachine oxygen plant includes a turbomachine and an air separation unit. One or more compressor pathways flow compressed air from a compressor through one or more of a combustor and a turbine expander to cool the combustor and/or the turbine expander. An air separation unit is operably connected to the one or more compressor pathways and is configured to separate the compressed air into oxygen and oxygen-depleted air. A method of air separation in an integrated turbomachine oxygen plant includes compressing a flow of air in a compressor of a turbomachine. The compressed flow of air is flowed through one or more of a combustor and a turbine expander of the turbomachine to cool the combustor and/or the turbine expander. The compressed flow of air is directed to an air separation unit and is separated into oxygen and oxygen-depleted air.

  4. LIQUID TARGET

    DOE Patents [OSTI]

    Martin, M.D.; Salsig, W.W. Jr.

    1959-01-13

    A liquid handling apparatus is presented for a liquid material which is to be irradiated. The apparatus consists essentially of a reservoir for the liquid, a target element, a drain tank and a drain lock chamber. The target is in the form of a looped tube, the upper end of which is adapted to be disposed in a beam of atomic particles. The lower end of the target tube is in communication with the liquid in the reservoir and a means is provided to continuously circulate the liquid material to be irradiated through the target tube. Means to heat the reservoir tank is provided in the event that a metal is to be used as the target material. The apparatus is provided with suitable valves and shielding to provide maximum safety in operation.

  5. Oxygen-Enriched Combustion

    Broader source: Energy.gov [DOE]

    This tip sheet discusses how an increase in oxygen in combustion air can reduce the energy loss in the exhaust gases and increase process heating system efficiency.

  6. Solid state oxygen sensor

    DOE Patents [OSTI]

    Garzon, F.H.; Brosha, E.L.

    1997-12-09

    A potentiometric oxygen sensor is formed having a logarithmic response to a differential oxygen concentration while operating as a Nernstian-type sensor. Very thin films of mixed conducting oxide materials form electrode services while permitting diffusional oxygen access to the interface between the zirconia electrolyte and the electrode. Diffusion of oxygen through the mixed oxide is not rate-limiting. Metal electrodes are not used so that morphological changes in the electrode structure do not occur during extended operation at elevated temperatures. 6 figs.

  7. Alternative Fuels Data Center: Emerging Fuels

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Emerging Fuels Printable Version Share this resource Send a link to Alternative Fuels Data Center: Emerging Fuels to someone by E-mail Share Alternative Fuels Data Center: Emerging Fuels on Facebook Tweet about Alternative Fuels Data Center: Emerging Fuels on Twitter Bookmark Alternative Fuels Data Center: Emerging Fuels on Google Bookmark Alternative Fuels Data Center: Emerging Fuels on Delicious Rank Alternative Fuels Data Center: Emerging Fuels on Digg Find More places to share Alternative

  8. Alternative Fuels Data Center: Biodiesel Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Biodiesel Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Biodiesel Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Google Bookmark Alternative Fuels Data Center: Biodiesel Fuel Basics on Delicious Rank Alternative Fuels Data Center: Biodiesel Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Biodiesel Fuel Basics on AddThis.com... More in

  9. Alternative Fuels Data Center: Electricity Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Electricity Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Electricity Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Electricity Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Google Bookmark Alternative Fuels Data Center: Electricity Fuel Basics on Delicious Rank Alternative Fuels Data Center: Electricity Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Electricity Fuel Basics on

  10. Alternative Fuels Data Center: Ethanol Fuel Basics

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fuel Basics to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fuel Basics on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fuel Basics on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Google Bookmark Alternative Fuels Data Center: Ethanol Fuel Basics on Delicious Rank Alternative Fuels Data Center: Ethanol Fuel Basics on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fuel Basics on AddThis.com... More in this

  11. Alternative Fuels Data Center: Ethanol Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Ethanol Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Ethanol Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Google Bookmark Alternative Fuels Data Center: Ethanol Fueling Stations on Delicious Rank Alternative Fuels Data Center: Ethanol Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Ethanol Fueling Stations on

  12. Alternative Fuels Data Center: Hydrogen Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Hydrogen Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Hydrogen Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Google Bookmark Alternative Fuels Data Center: Hydrogen Fueling Stations on Delicious Rank Alternative Fuels Data Center: Hydrogen Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Hydrogen Fueling Stations

  13. Alternative Fuels Data Center: Propane Fueling Stations

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fueling Stations to someone by E-mail Share Alternative Fuels Data Center: Propane Fueling Stations on Facebook Tweet about Alternative Fuels Data Center: Propane Fueling Stations on Twitter Bookmark Alternative Fuels Data Center: Propane Fueling Stations on Google Bookmark Alternative Fuels Data Center: Propane Fueling Stations on Delicious Rank Alternative Fuels Data Center: Propane Fueling Stations on Digg Find More places to share Alternative Fuels Data Center: Propane Fueling Stations on

  14. Protected Nuclear Fuel Element

    DOE Patents [OSTI]

    Kittel, J. H.; Schumar, J. F.

    1962-12-01

    A stainless steel-clad actinide metal fuel rod for use in fast reactors is reported. In order to prevert cladding failures due to alloy formation between the actinide metal and the stainless steel, a mesh-like sleeve of expanded metal is interposed between them, the sleeve metal being of niobium, tantalum, molybdenum, tungsten, zirconium, or vanadium. Liquid alkali metal is added as a heat transfer agent. (AEC)

  15. Recent advances in hydrotreating of pyrolysis bio-oil and its oxygen-containing model compounds

    SciTech Connect (OSTI)

    Wang, Huamin; Male, Jonathan L.; Wang, Yong

    2013-05-01

    There is considerable world-wide interest in discovering renewable sources of energy that can substitute for fossil fuels. Lignocellulosic biomass, which is the most abundant and inexpensive renewable feedstock on the planet, has a great potential for sustainable production of fuels, chemicals, and carbon-based materials. Fast pyrolysis integrated with hydrotreating is one of the simplest, most cost-effective and most efficient processes to convert lignocellulosic biomass to liquid hydrocarbon fuels for transportation, which has attracted significant attention in recent decades. However, effective hydrotreating of pyrolysis bio-oil presents a daunting challenge to the commercialization of biomass conversion via pyrolysis-hydrotreating. Specifically, development of active, selective, and stable hydrotreating catalysts is the bottleneck due to the poor quality of pyrolysis bio-oil feedstock (high oxygen content, molecular complexity, coking propensity, and corrosiveness). Significant research has been conducted to address the practical issues and provide the fundamental understanding of the hydrotreating/hydrodeoxygenation (HDO) of bio-oils and their oxygen-containing model compounds, including phenolics, furans, and carboxylic acids. A wide range of catalysts have been studied, including conventional Mo-based sulfide catalysts and noble metal catalysts, with the latter being the primary focus of the recent research because of their excellent catalytic performances and no requirement of environmentally unfriendly sulfur. The reaction mechanisms of HDO of model compounds on noble metal catalysts as well as their efficacy for hydrotreating or stabilization of bio-oil have been recently reported. This review provides a survey of the relevant literatures of recent 10 years about the advances in the understanding of the HDO chemistry of bio-oils and their model compounds mainly on noble metal catalysts.

  16. Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Total Fuel Oil Consumption and Expenditures, 1999" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings (thousand)","Floorspac...

  17. Catalytic Synthesis of Oxygenates: Mechanisms, Catalysts and Controlling Characteristics

    SciTech Connect (OSTI)

    Klier, Kamil; Herman, Richard G

    2005-11-30

    This research focused on catalytic synthesis of unsymmetrical ethers as a part of a larger program involving oxygenated products in general, including alcohols, ethers, esters, carboxylic acids and their derivatives that link together environmentally compliant fuels, monomers, and high-value chemicals. The catalysts studied here were solid acids possessing strong Brnsted acid functionalities. The design of these catalysts involved anchoring the acid groups onto inorganic oxides, e.g. surface-grafted acid groups on zirconia, and a new class of mesoporous solid acids, i.e. propylsulfonic acid-derivatized SBA-15. The former catalysts consisted of a high surface concentration of sulfate groups on stable zirconia catalysts. The latter catalyst consists of high surface area, large pore propylsulfonic acid-derivatized silicas, specifically SBA-15. In both cases, the catalyst design and synthesis yielded high concentrations of acid sites in close proximity to one another. These materials have been well-characterization in terms of physical and chemical properties, as well as in regard to surface and bulk characteristics. Both types of catalysts were shown to exhibit high catalytic performance with respect to both activity and selectivity for the bifunctional coupling of alcohols to form ethers, which proceeds via an efficient SN2 reaction mechanism on the proximal acid sites. This commonality of the dual-site SN2 reaction mechanism over acid catalysts provides for maximum reaction rates and control of selectivity by reaction conditions, i.e. pressure, temperature, and reactant concentrations. This research provides the scientific groundwork for synthesis of ethers for energy applications. The synthesized environmentally acceptable ethers, in part derived from natural gas via alcohol intermediates, exhibit high cetane properties, e.g. methylisobutylether with cetane No. of 53 and dimethylether with cetane No. of 55-60, or high octane properties, e.g. diisopropylether with blending octane No. of 105, and can replace aromatics in liquid fuels.

  18. Transportation Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels DOE would invest $52 million to fund a major fleet transformation at Idaho National Laboratory, along with the installation of nine fuel management systems, purchase of additional flex fuel cars and one E85 ethanol fueling station. Transportation projects, such as the acquisition of highly efficient and alternative-fuel vehicles, are not authorized by ESPC legislation. DOE has twice proportion of medium vehicles and three times as many heavy vehicles as compared to the Federal agency

  19. Liquid uranium alloy-helium fission reactor

    DOE Patents [OSTI]

    Minkov, Vladimir (Skokie, IL)

    1986-01-01

    This invention teaches a nuclear fission reactor having a core vessel and at least one tandem heat exchanger vessel coupled therewith across upper and lower passages to define a closed flow loop. Nuclear fuel such as a uranium alloy in its liquid phase fills these vessels and flow passages. Solid control elements in the reactor core vessel are adapted to be adjusted relative to one another to control fission reaction of the liquid fuel therein. Moderator elements in the other vessel and flow passages preclude fission reaction therein. An inert gas such as helium is bubbled upwardly through the heat exchanger vessel operable to move the liquid fuel upwardly therein and unidirectionally around the closed loop and downwardly through the core vessel. This helium gas is further directed to heat conversion means outside of the reactor vessels to utilize the heat from the fission reaction to generate useful output. The nuclear fuel operates in the 1200.degree.-1800.degree. C. range, and even higher to 2500.degree. C., limited only by the thermal effectiveness of the structural materials, increasing the efficiency of power generation from the normal 30-35% with 300.degree.-500.degree. C. upper limit temperature to 50-65%. Irradiation of the circulating liquid fuel, as contrasted to only localized irradiation of a solid fuel, provides improved fuel utilization.

  20. The Sasol route to fuels

    SciTech Connect (OSTI)

    Dry, M.E.

    1982-12-01

    Details are given of the Sasol operation in South Africa. Flow sheets are provided for Sasol 1 and Sasol 2 and 3. The Sasol 1 plant produces waxes, liquid fuels, pipeline gas and chemicals; the Sasol 2 and 3 plants primarily produce ethylene, gasoline and diesel fuel. The versatility of the process is emphasized. The product selectivities of the fixed bed and Synthol reactors are shown and the properties of the products are compared. The influence of the catalyst on selectivity is examined.

  1. The low-temperature partial oxidation reforming of fuels for transportation fuel cell systems

    SciTech Connect (OSTI)

    Kumar, R.; Ahmed, S.; Krumpelt, M.

    1996-12-31

    Argonne`s partial-oxidation reformer (APOR) is a compact, lightweight, rapid-start, and dynamically responsive device to convert liquid fuels to H{sub 2} for use in automotive fuel cells. An APOR catalyst for methanol has been developed and tested; catalysts for other fuels are being evaluated. Simple in design, operation, and control, the APOR can help develop efficient fuel cell propulsion systems.

  2. Ethanol Fuel Basics | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ethanol Fuel Basics Ethanol Fuel Basics July 30, 2013 - 12:00pm Addthis biomass in beekers Ethanol is a renewable fuel made from various plant materials collectively known as "biomass." Studies have estimated that ethanol and other biofuels could replace 30% or more of U.S. gasoline demand by 2030. More than 95% of U.S. gasoline contains ethanol in a low-level blend to oxygenate the fuel and reduce air pollution. Ethanol is also increasingly available in E85, an alternative fuel that

  3. Fuel-cell-propelled submarine-tanker-system study

    SciTech Connect (OSTI)

    Court, K E; Kumm, W H; O'Callaghan, J E

    1982-06-01

    This report provides a systems analysis of a commercial Arctic Ocean submarine tanker system to carry fossil energy to markets. The submarine is to be propelled by a modular Phosphoric Acid Fuel Cell system. The power level is 20 Megawatts. The DOE developed electric utility type fuel cell will be fueled with methanol. Oxidant will be provided from a liquid oxygen tank carried onboard. The twin screw submarine tanker design is sized at 165,000 deadweight tons and the study includes costs and an economic analysis of the transport system of 6 ships. The route will be under the polar icecap from a loading terminal located off Prudhoe Bay, Alaska to a transshipment facility postulated to be in a Norwegian fjord. The system throughput of the gas-fed methanol cargo will be 450,000 barrels per day. The total delivered cost of the methanol including well head purchase price of natural gas, methanol production, and shipping would be $25/bbl from Alaska to the US East Coast. Of this, the shipping cost is $6.80/bbl. All costs in 1981 dollars.

  4. fuel cells | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    fuel cells

  5. Reformulated diesel fuel and method

    DOE Patents [OSTI]

    McAdams, Hiramie T [Carrollton, IL; Crawford, Robert W [Tucson, AZ; Hadder, Gerald R [Oak Ridge, TN; McNutt, Barry D [Arlington, VA

    2006-08-22

    A method for mathematically identifying at least one diesel fuel suitable for combustion in an automotive diesel engine with significantly reduced emissions and producible from known petroleum blendstocks using known refining processes, including the use of cetane additives (ignition improvers) and oxygenated compounds.

  6. Liquid Transportation Fuels from Coal and Biomass

    Broader source: Energy.gov [DOE]

    Presented at the U.S. Department of Energy sponsored a Light Duty Vehicle Workshop in Washington, D.C. on July 26, 2010.

  7. Chapter 2. Petroleum and other liquid fuels

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    7, 2015 U.S. Gasoline Price Continues to Increase (Long version) The U.S. average retail price for regular gasoline rose to $2.27 a gallon on Monday. That's up 8.3 cents from a week ago, based on the weekly price survey by the U.S. Energy Information Administration. Pump prices were highest in the West Coast states at 2.62 a gallon, up 14.8 cents from a week ago. Prices were lowest in the Rocky Mountain states at 2 dollars a gallon, up 4.9 cents. This is Marcela Rourk, with EIA, in Washington.

  8. Liquid Fuels Market Model (LFMM) Unveiling LFMM

    Gasoline and Diesel Fuel Update (EIA)

    Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1980's 52,883 50,172 48,599 51,573 51,424 1990's 52,546 54,005 52,532 55,989 62,682 65,283 67,648 62,187 65,984 63,882 2000's 66,028 66,218 63,842 66,075 62,467 65,367 60,938 48,485 39,217 33,355 2010's 64,793 70,001 28,298 2,924 16,255 28,381

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2014 29 30 28 25 21 17 18 17 18 20 27 28 2015 27 20 23 24 21 20 17 10 12 14 21 27 2016 26 24

    Year Jan Feb Mar Apr

  9. AEO 2013 Liquid Fuels Markets Working Group

    U.S. Energy Information Administration (EIA) Indexed Site

    ... A: Low due to capital cost. A tax is still likely to be collected in the form of a mileage tax. Slide 8 Most comments here were to keep RFS as is in the model There was discussion ...

  10. Alternative fuels and chemicals from synthesis gas

    SciTech Connect (OSTI)

    Unknown

    1998-08-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  11. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-03-31

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  12. Alternative Fuels and Chemicals from Synthesis Gas

    SciTech Connect (OSTI)

    Peter Tijrn

    2003-01-02

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  13. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    1999-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  14. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-04-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  15. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    1999-01-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  16. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Unknown

    2000-10-01

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  17. ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2000-09-30

    The overall objectives of this program are to investigate potential technologies for the conversion of synthesis gas to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at DOE's LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). The program will involve a continuation of the work performed under the Alternative Fuels from Coal-Derived Synthesis Gas Program and will draw upon information and technologies generated in parallel current and future DOE-funded contracts.

  18. Controlled temperature expansion in oxygen production by molten alkali metal salts

    DOE Patents [OSTI]

    Erickson, Donald C.

    1985-06-04

    A continuous process is set forth for the production of oxygen from an oxygen containing gas stream, such as air, by contacting a feed gas stream with a molten solution of an oxygen acceptor to oxidize the acceptor and cyclically regenerating the oxidized acceptor by releasing oxygen from the acceptor wherein the oxygen-depleted gas stream from the contact zone is treated sequentially to temperature reduction by heat exchange against the feed stream so as to condense out entrained oxygen acceptor for recycle to the process, combustion of the gas stream with fuel to elevate its temperature and expansion of the combusted high temperature gas stream in a turbine to recover power.

  19. Alternative Fuels Data Center: Flexible Fuel Vehicles

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Ethanol Printable Version Share this resource Send a link to Alternative Fuels Data Center: Flexible Fuel Vehicles to someone by E-mail Share Alternative Fuels Data Center: Flexible Fuel Vehicles on Facebook Tweet about Alternative Fuels Data Center: Flexible Fuel Vehicles on Twitter Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicles on Google Bookmark Alternative Fuels Data Center: Flexible Fuel Vehicles on Delicious Rank Alternative Fuels Data Center: Flexible Fuel Vehicles on Digg

  20. Biodiesel Fuel Property Effects on Particulate Matter Reactivity

    SciTech Connect (OSTI)

    Williams, A.; Black, S.; McCormick, R. L.

    2010-06-01

    Controlling diesel particulate emissions to meet the 2007 U.S. standard requires the use of a diesel particulate filter (DPF). The reactivity of soot, or the carbon fraction of particulate matter, in the DPF and the kinetics of soot oxidation are important in achieving better control of aftertreatment devices. Studies showed that biodiesel in the fuel can increase soot reactivity. This study therefore investigated which biodiesel fuel properties impact reactivity. Three fuel properties of interest included fuel oxygen content and functionality, fuel aromatic content, and the presence of alkali metals. To determine fuel effects on soot reactivity, the performance of a catalyzed DPF was measured with different test fuels through engine testing and thermo-gravimetric analysis. Results showed no dependence on the aromatic content or the presence of alkali metals in the fuel. The presence and form of fuel oxygen was the dominant contributor to faster DPF regeneration times and soot reactivity.

  1. Annular feed air breathing fuel cell stack

    DOE Patents [OSTI]

    Wilson, Mahlon S.

    1996-01-01

    A stack of polymer electrolyte fuel cells is formed from a plurality of unit cells where each unit cell includes fuel cell components defining a periphery and distributed along a common axis, where the fuel cell components include a polymer electrolyte membrane, an anode and a cathode contacting opposite sides of the membrane, and fuel and oxygen flow fields contacting the anode and the cathode, respectively, wherein the components define an annular region therethrough along the axis. A fuel distribution manifold within the annular region is connected to deliver fuel to the fuel flow field in each of the unit cells. In a particular embodiment, a single bolt through the annular region clamps the unit cells together. In another embodiment, separator plates between individual unit cells have an extended radial dimension to function as cooling fins for maintaining the operating temperature of the fuel cell stack.

  2. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1996-12-31

    The paper consists of viewgraphs from a conference presentation. A comparison is made of opportunity fuels, defined as fuels that can be converted to other forms of energy at lower cost than standard fossil fuels. Types of fuels for which some limited technical data is provided include petroleum coke, garbage, wood waste, and tires. Power plant economics and pollution concerns are listed for each fuel, and compared to coal and natural gas power plant costs. A detailed cost breakdown for different plant types is provided for use in base fuel pricing.

  3. Fuel Cells and Renewable Gaseous Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cell Technologies Office | 1 7142015 Fuel Cells and Renewable Gaseous Fuels Bioenergy 2015: Renewable Gaseous Fuels Breakout Session Sarah Studer, PhD ORISE Fellow Fuel Cell...

  4. Hydrocarbon Liquid Production via the bioCRACK Process and Catalytic Hydroprocessing of the Product Oil

    SciTech Connect (OSTI)

    Schwaiger, Nikolaus; Elliott, Douglas C.; Ritzberger, Jurgen; Wang, Huamin; Pucher, Peter; Siebenhofer, Matthaus

    2015-02-13

    Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (<0.05), while the residual oxygen ranged from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.

  5. Hydrocarbon Liquid Production via the bioCRACK Process and Catalytic Hydroprocessing of the Product Oil

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schwaiger, Nikolaus; Elliott, Douglas C.; Ritzberger, Jurgen; Wang, Huamin; Pucher, Peter; Siebenhofer, Matthaus

    2015-02-13

    Continuous hydroprocessing of liquid phase pyrolysis bio-oil, provided by BDI-BioEnergy International bioCRACK pilot plant at OMV Refinery in Schwechat/Vienna Austria was investigated. These hydroprocessing tests showed promising results using catalytic hydroprocessing strategies developed for unfractionated bio-oil. A sulfided base metal catalyst (CoMo on Al2O3) was evaluated. The bed of catalyst was operated at 400 °C in a continuous-flow reactor at a pressure of 12.1 MPa with flowing hydrogen. The condensed liquid products were analyzed and found that the hydrocarbon liquid was significantly hydrotreated so that nitrogen and sulfur were below the level of detection (<0.05), while the residual oxygen rangedmore » from 0.7 to 1.2%. The density of the products varied from 0.71 g/mL up to 0.79 g/mL with a correlated change of the hydrogen to carbon atomic ratio from 2.1 down to 1.9. The product quality remained high throughout the extended tests suggesting minimal loss of catalyst activity through the test. These tests provided the data needed to assess the quality of liquid fuel products obtained from the bioCRACK process as well as the activity of the catalyst for comparison with products obtained from hydrotreated fast pyrolysis bio-oils from fluidized-bed operation.« less

  6. Oxygenates du`jour...MTBE? Ethanol? ETBE?

    SciTech Connect (OSTI)

    Wolfe, R.

    1995-12-31

    There are many different liquids that contain oxygen which could be blended into gasoline. The ones that have been tried and make the most sense are in the alcohol (R-OH) and ether (R-O-R) chemical family. The alcohols considered are: methanol (MeOH), ethanol (EtOH), tertiary butyl alcohol (TBA). The ethers are: methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE), tertiary amyl methyl ether (TAME), tertiary amyl ethyl ether (TAEE), di-isopropyl ether (DIPE). Of the eight oxygenates listed above, the author describes the five that are still waiting for widespread marketing acceptance (methanol, TBA, TAME, TAEE, and DIPE). He then discusses the two most widely used oxygenates in the US, MTBE and ethanol, along with the up-and-coming ethanol ether, ETBE. Selected physical properties for all of these oxygenates can be found in Table 2 at the end of this paper. A figure shows a simplified alcohol/ether production flow chart for the oxygenates listed above and how they are interrelated.

  7. Coolant mass flow equalizer for nuclear fuel

    DOE Patents [OSTI]

    Betten, Paul R. (Windsor, CT)

    1978-01-01

    The coolant mass flow distribution in a liquid metal cooled reactor is enhanced by restricting flow in sub-channels defined in part by the peripheral fuel elements of a fuel assembly. This flow restriction, which results in more coolant flow in interior sub-channels, is achieved through the use of a corrugated liner positioned between the bundle of fuel elements and the inner wall of the fuel assembly coolant duct. The corrugated liner is expandable to accommodate irradiation induced growth of fuel assembly components.

  8. Film bonded fuel cell interface configuration

    DOE Patents [OSTI]

    Kaufman, Arthur; Terry, Peter L.

    1985-01-01

    An improved interface configuration for use between adjacent elements of a fuel cell stack. The interface is impervious to gas and liquid and provides resistance to corrosion by the electrolyte of the fuel cell. A multi-layer arrangement for the interface provides bridging electrical contact with a hot-pressed resin filling the void space.

  9. Ignition of deuterium-trtium fuel targets

    DOE Patents [OSTI]

    Musinski, Donald L.; Mruzek, Michael T.

    1991-01-01

    A method of igniting a deuterium-tritium ICF fuel target to obtain fuel burn in which the fuel target initially includes a hollow spherical shell having a frozen layer of DT material at substantially uniform thickness and cryogenic temperature around the interior surface of the shell. The target is permitted to free-fall through a target chamber having walls heated by successive target ignitions, so that the target is uniformly heated during free-fall to at least partially melt the frozen fuel layer and form a liquid single-phase layer or a mixed liquid/solid bi-phase layer of substantially uniform thickness around the interior shell surface. The falling target is then illuminated from exteriorly of the chamber while the fuel layer is at substantially uniformly single or bi-phase so as to ignite the fuel layer and release energy therefrom.

  10. Ignition of deuterium-tritium fuel targets

    DOE Patents [OSTI]

    Musinski, D.L.; Mruzek, M.T.

    1991-08-27

    Disclosed is a method of igniting a deuterium-tritium ICF fuel target to obtain fuel burn in which the fuel target initially includes a hollow spherical shell having a frozen layer of DT material at substantially uniform thickness and cryogenic temperature around the interior surface of the shell. The target is permitted to free-fall through a target chamber having walls heated by successive target ignitions, so that the target is uniformly heated during free-fall to at least partially melt the frozen fuel layer and form a liquid single-phase layer or a mixed liquid/solid bi-phase layer of substantially uniform thickness around the interior shell surface. The falling target is then illuminated from exteriorly of the chamber while the fuel layer is at substantially uniformly single or bi-phase so as to ignite the fuel layer and release energy therefrom. 5 figures.

  11. Synthetic Fuel

    ScienceCinema (OSTI)

    Idaho National Laboratory - Steve Herring, Jim O'Brien, Carl Stoots

    2010-01-08

    Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhouse gass Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhous

  12. Solid oxide fuel cell generator with removable modular fuel cell stack configurations

    DOE Patents [OSTI]

    Gillett, James E.; Dederer, Jeffrey T.; Zafred, Paolo R.; Collie, Jeffrey C.

    1998-01-01

    A high temperature solid oxide fuel cell generator produces electrical power from oxidation of hydrocarbon fuel gases such as natural gas, or conditioned fuel gases, such as carbon monoxide or hydrogen, with oxidant gases, such as air or oxygen. This electrochemical reaction occurs in a plurality of electrically connected solid oxide fuel cells bundled and arrayed in a unitary modular fuel cell stack disposed in a compartment in the generator container. The use of a unitary modular fuel cell stack in a generator is similar in concept to that of a removable battery. The fuel cell stack is provided in a pre-assembled self-supporting configuration where the fuel cells are mounted to a common structural base having surrounding side walls defining a chamber. Associated generator equipment may also be mounted to the fuel cell stack configuration to be integral therewith, such as a fuel and oxidant supply and distribution systems, fuel reformation systems, fuel cell support systems, combustion, exhaust and spent fuel recirculation systems, and the like. The pre-assembled self-supporting fuel cell stack arrangement allows for easier assembly, installation, maintenance, better structural support and longer life of the fuel cells contained in the fuel cell stack.

  13. Solid oxide fuel cell generator with removable modular fuel cell stack configurations

    DOE Patents [OSTI]

    Gillett, J.E.; Dederer, J.T.; Zafred, P.R.; Collie, J.C.

    1998-04-21

    A high temperature solid oxide fuel cell generator produces electrical power from oxidation of hydrocarbon fuel gases such as natural gas, or conditioned fuel gases, such as carbon monoxide or hydrogen, with oxidant gases, such as air or oxygen. This electrochemical reaction occurs in a plurality of electrically connected solid oxide fuel cells bundled and arrayed in a unitary modular fuel cell stack disposed in a compartment in the generator container. The use of a unitary modular fuel cell stack in a generator is similar in concept to that of a removable battery. The fuel cell stack is provided in a pre-assembled self-supporting configuration where the fuel cells are mounted to a common structural base having surrounding side walls defining a chamber. Associated generator equipment may also be mounted to the fuel cell stack configuration to be integral therewith, such as a fuel and oxidant supply and distribution systems, fuel reformation systems, fuel cell support systems, combustion, exhaust and spent fuel recirculation systems, and the like. The pre-assembled self-supporting fuel cell stack arrangement allows for easier assembly, installation, maintenance, better structural support and longer life of the fuel cells contained in the fuel cell stack. 8 figs.

  14. Nuclear reactor composite fuel assembly

    DOE Patents [OSTI]

    Burgess, Donn M.; Marr, Duane R.; Cappiello, Michael W.; Omberg, Ronald P.

    1980-01-01

    A core and composite fuel assembly for a liquid-cooled breeder nuclear reactor including a plurality of elongated coextending driver and breeder fuel elements arranged to form a generally polygonal bundle within a thin-walled duct. The breeder elements are larger in cross section than the driver elements, and each breeder element is laterally bounded by a number of the driver elements. Each driver element further includes structure for spacing the driver elements from adjacent fuel elements and, where adjacent, the thin-walled duct. A core made up of the fuel elements can advantageously include fissile fuel of only one enrichment, while varying the effective enrichment of any given assembly or core region, merely by varying the relative number and size of the driver and breeder elements.

  15. Advantages of liquid fluoride thorium reactor in comparison with light

    Office of Scientific and Technical Information (OSTI)

    water reactor (Journal Article) | SciTech Connect Advantages of liquid fluoride thorium reactor in comparison with light water reactor Citation Details In-Document Search Title: Advantages of liquid fluoride thorium reactor in comparison with light water reactor Liquid Fluoride Thorium Reactor (LFTR) is an innovative design for the thermal breeder reactor that has important potential benefits over the traditional reactor design. LFTR is fluoride based liquid fuel, that use the thorium

  16. NOx reduction in combustion with concentrated coal streams and oxygen injection

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.; Snyder, William J.

    2004-03-02

    NOx formation in the combustion of solid hydrocarbonaceous fuel such as coal is reduced by obtaining, from the incoming feed stream of fuel solids and air, a stream having a ratio of fuel solids to air that is higher than that of the feed steam, and injecting the thus obtained stream and a small amount of oxygen to a burner where the fuel solids are combusted.

  17. Fuel Economy

    Broader source: Energy.gov [DOE]

    The Energy Department is investing in groundbreaking research that will make cars weigh less, drive further and consume less fuel.

  18. Fuels Technologies

    Energy Savers [EERE]

    Fuels Technologies Program Mission To develop more energy efficient and environmentally friendly highway transportation technologies that enable America to use less petroleum. --EERE Strategic Plan, October 2002-- Kevin Stork, Team Leader Fuel Technologies & Technology Deployment Vehicle Technologies Program Energy Efficiency and Renewable Energy U.S. Department of Energy DEER 2008 August 6, 2008 Presentation Outline n Fuel Technologies Research Goals Fuels as enablers for advanced engine

  19. Real Space Mapping of Oxygen Vacancy Diffusion and Electrochemical

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transformations by Hysteretic Current Reversal Curve Measurements - Energy Innovation Portal Hydrogen and Fuel Cell Hydrogen and Fuel Cell Energy Storage Energy Storage Find More Like This Return to Search Real Space Mapping of Oxygen Vacancy Diffusion and Electrochemical Transformations by Hysteretic Current Reversal Curve Measurements Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing SummaryElectrochemical energy storage and conversion systems based on

  20. Update On Monolithic Fuel Fabrication Development

    SciTech Connect (OSTI)

    C. R Clark; J. M. Wight; G. C. Knighton; G. A. Moore; J. F. Jue

    2005-11-01

    Efforts to develop a viable monolithic research reactor fuel plate have continued at Idaho National Laboratory. These efforts have concentrated on both fabrication process refinement and scale-up to produce full sized fuel plates. Advancements have been made in the production of U-Mo foil including full sized foils. Progress has also been made in the friction stir welding and transient liquid phase bonding fabrication processes resulting in better bonding, more stable processes and the ability to fabricate larger fuel plates.

  1. High Selectivity Oxygen Delignification

    SciTech Connect (OSTI)

    Lucian A. Lucia

    2005-11-15

    Project Objective: The objectives of this project are as follows: (1) Examine the physical and chemical characteristics of a partner mill pre- and post-oxygen delignified pulp and compare them to lab generated oxygen delignified pulps; (2) Apply the chemical selectivity enhancement system to the partner pre-oxygen delignified pulps under mill conditions (with and without any predetermined amounts of carryover) to determine how efficiently viscosity is preserved, how well selectivity is enhanced, if strength is improved, measure any yield differences and/or bleachability differences; and (3) Initiate a mill scale oxygen delignification run using the selectivity enhancement agent, collect the mill data, analyze it, and propose any future plans for implementation.

  2. Fuel pins with both target and fuel pellets in an isotope-production reactor

    DOE Patents [OSTI]

    Cawley, W.E.; Omberg, R.P.

    1982-08-19

    A method is described for producing tritium in a fast breeder reactor cooled with liquid metal. Lithium target pellets are placed in close contact with fissile fuel pellets in order to increase the tritium production rate.

  3. Dilute Oxygen Combustion Phase IV Final Report

    SciTech Connect (OSTI)

    Riley, M.F.

    2003-04-30

    Novel furnace designs based on Dilute Oxygen Combustion (DOC) technology were developed under subcontract by Techint Technologies, Coraopolis, PA, to fully exploit the energy and environmental capabilities of DOC technology and to provide a competitive offering for new furnace construction opportunities. Capital cost, fuel, oxygen and utility costs, NOx emissions, oxide scaling performance, and maintenance requirements were compared for five DOC-based designs and three conventional air5-fired designs using a 10-year net present value calculation. A furnace direct completely with DOC burners offers low capital cost, low fuel rate, and minimal NOx emissions. However, these benefits do not offset the cost of oxygen and a full DOC-fired furnace is projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The incremental cost of the improved NOx performance is roughly $6/lb NOx, compared with an estimated $3/lb. NOx for equ8pping a conventional furnace with selective catalytic reduction (SCCR) technology. A furnace fired with DOC burners in the heating zone and ambient temperature (cold) air-fired burners in the soak zone offers low capital cost with less oxygen consumption. However, the improvement in fuel rate is not as great as the full DOC-fired design, and the DOC-cold soak design is also projected to cost $1.30 per ton more to operate than a conventional air-fired furnace. The NOx improvement with the DOC-cold soak design is also not as great as the full DOC fired design, and the incremental cost of the improved NOx performance is nearly $9/lb NOx. These results indicate that a DOC-based furnace design will not be generally competitive with conventional technology for new furnace construction under current market conditions. Fuel prices of $7/MMBtu or oxygen prices of $23/ton are needed to make the DOC furnace economics favorable. Niche applications may exist, particularly where access to capital is limited or floor space limitations are critical. DOC technology will continue to have a highly competitive role in retrofit applications requiring increases in furnace productivity.

  4. DEVELOPMENT OF ALTERNATIVE FUELS AND CHEMICALS FROM SYNTHESIS GAS

    SciTech Connect (OSTI)

    Peter J. Tijrn

    2003-05-31

    This Final Report for Cooperative Agreement No. DE-FC22-95PC93052, the ''Development of Alternative Fuels and Chemicals from Synthesis Gas,'' was prepared by Air Products and Chemicals, Inc. (Air Products), and covers activities from 29 December 1994 through 31 July 2002. The overall objectives of this program were to investigate potential technologies for the conversion of synthesis gas (syngas), a mixture primarily of hydrogen (H{sub 2}) and carbon monoxide (CO), to oxygenated and hydrocarbon fuels and industrial chemicals, and to demonstrate the most promising technologies at the LaPorte, Texas Alternative Fuels Development Unit (AFDU). Laboratory work was performed by Air Products and a variety of subcontractors, and focused on the study of the kinetics of production of methanol and dimethyl ether (DME) from syngas, the production of DME using the Liquid Phase Dimethyl Ether (LPDME{trademark}) Process, the conversion of DME to fuels and chemicals, and the production of other higher value products from syngas. Four operating campaigns were performed at the AFDU during the performance period. Tests of the Liquid Phase Methanol (LPMEOH{trademark}) Process and the LPDME{trademark} Process were made to confirm results from the laboratory program and to allow for the study of the hydrodynamics of the slurry bubble column reactor (SBCR) at a significant engineering scale. Two campaigns demonstrated the conversion of syngas to hydrocarbon products via the slurry-phase Fischer-Tropsch (F-T) process. Other topics that were studied within this program include the economics of production of methyl tert-butyl ether (MTBE), the identification of trace components in coal-derived syngas and the means to economically remove these species, and the study of systems for separation of wax from catalyst in the F-T process. The work performed under this Cooperative Agreement has continued to promote the development of technologies that use clean syngas produced from any one of a variety of sources (including coal) for the production of a spectrum of alternative fuels (hydrocarbons and oxygenate fuels), octane enhancers, and chemicals and chemical intermediates. In particular, the data from the 1995 LPMEOH{trademark} campaign provided confirmation of assumptions used in the design of the catalyst reduction system at the Kingsport LPMEOH{trademark} Commercial Demonstration Project, and the alternate methanol catalyst has been in use there since late 1998. The kinetic model was also expanded to allow for more accurate prediction of methanol production and carbon dioxide (CO{sub 2}) conversion, and more accurate modeling of by-product formation for the alternate methanol catalyst. The outstanding performance results of the LPMEOH{trademark} Process at Kingsport can be attributed in large part to the body of work performed since 1981 in collaboration between the U.S. Department of Energy (DOE) and Air Products. In addition, a pilot-plant-tested LPDME{trademark} Process has been demonstrated, and the product cost of DME from coal-derived syngas can be competitive in certain locations and applications. The need for liquid fuels will continue to be a critical concern for this nation in the 21st century. Efforts are needed to ensure the development and demonstration of economically competitive, efficient, environmentally responsible technologies that produce clean fuels and chemicals from coal under DOE's Vision 21 concept. These liquids will be a component of the fuel mix that will provide the transition from the current reliance on carbon-based fuels to the ultimate use of H{sub 2} as a means of energy transport. Indirect liquefaction, which converts the syngas (H{sub 2} and CO) produced by the gasification of coal to sulfur- and nitrogen-free liquid products, is a key component of the Vision 21 initiative. The results from this current program provide continued support to the objectives for the conversion of domestic coal to electric power and co-produced clean liquid fuels and chemicals in an environmentally superior manner.

  5. LPG fuel supply system. [Patent for automotive

    SciTech Connect (OSTI)

    Pierson, W.V.

    1982-09-07

    A fuel supply system for an internal combustion engine operated on gaseous fuels, for example, liquid petroleum gas (Lpg). The system includes a housing having a chamber for vaporizing liquid gas, including means for heating the vaporizing chamber. Also included in the housing is a mixing chamber for mixing the vaporized gas with incoming air for delivery to the intake manifold of an internal combustion engine through a standard carburetor. The fuel supply system includes means for mounting the system on the carburetor, including means for supporting an air filter circumjacent the mixing chamber.

  6. Annular feed air breathing fuel cell stack

    DOE Patents [OSTI]

    Wilson, Mahlon S.; Neutzler, Jay K.

    1997-01-01

    A stack of polymer electrolyte fuel cells is formed from a plurality of unit cells where each unit cell includes fuel cell components defining a periphery and distributed along a common axis, where the fuel cell components include a polymer electrolyte membrane, an anode and a cathode contacting opposite sides of the membrane, and fuel and oxygen flow fields contacting the anode and the cathode, respectively, wherein the components define an annular region therethrough along the axis. A fuel distribution manifold within the annular region is connected to deliver fuel to the fuel flow field in each of the unit cells. The fuel distribution manifold is formed from a hydrophilic-like material to redistribute water produced by fuel and oxygen reacting at the cathode. In a particular embodiment, a single bolt through the annular region clamps the unit cells together. In another embodiment, separator plates between individual unit cells have an extended radial dimension to function as cooling fins for maintaining the operating temperature of the fuel cell stack.

  7. Lightweight cryogenic-compatible pressure vessels for vehicular fuel storage

    DOE Patents [OSTI]

    Aceves, Salvador; Berry, Gene; Weisberg, Andrew H.

    2004-03-23

    A lightweight, cryogenic-compatible pressure vessel for flexibly storing cryogenic liquid fuels or compressed gas fuels at cryogenic or ambient temperatures. The pressure vessel has an inner pressure container enclosing a fuel storage volume, an outer container surrounding the inner pressure container to form an evacuated space therebetween, and a thermal insulator surrounding the inner pressure container in the evacuated space to inhibit heat transfer. Additionally, vacuum loss from fuel permeation is substantially inhibited in the evacuated space by, for example, lining the container liner with a layer of fuel-impermeable material, capturing the permeated fuel in the evacuated space, or purging the permeated fuel from the evacuated space.

  8. Dilute Oxygen Combustion Phase I Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    1997-10-31

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300°F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  9. Dilute Oxygen Combustion Phase 2 Final Report

    SciTech Connect (OSTI)

    Ryan, H.M.; Riley, M.F.; Kobayashi, H.

    2005-09-30

    A novel burner, in which fuel (natural gas) and oxidant (oxygen or air) are separately injected into a furnace, shows promise for achieving very low nitrogen oxide(s) (NOx) emissions for commercial furnace applications. The dilute oxygen combustion (DOC) burner achieves very low NOx through in-furnace dilution of the oxidant stream prior to combustion, resulting in low flame temperatures, thus inhibiting thermal NOx production. The results of a fundamental and applied research effort on the development of the DOC burner are presented. In addition, the results of a market survey detailing the potential commercial impact of the DOC system are disclosed. The fundamental aspects of the burner development project involved examining the flame characteristics of a natural gas turbulent jet in a high-temperature (~1366 K) oxidant (7-27% O2 vol. wet). Specifically, the mass entrainment rate, the flame lift-off height, the velocity field and major species field of the jet were evaluated as a function of surrounding-gas temperature and composition. The measured entrainment rate of the fuel jet decreased with increasing oxygen content in the surrounding high-temperature oxidant, and was well represented by the d+ scaling correlation found in the literature. The measured flame lift-off height decreased with increasing oxygen content and increasing temperature of the surrounding gas. An increase in surrounding-gas oxygen content and/or temperature inhibited the velocity decay within the jet periphery as a function of axial distance as compared to isothermal turbulent jets. However, the velocity measurements were only broadly represented by the d+ scaling correlation. Several DOC burner configurations were tested in a laboratory-scale furnace at a nominal firing rate of 185 kW (~0.63 MMBtu/h). The flue gas composition was recorded as a function of furnace nitrogen content, furnace temperature, burner geometric arrangement, firing rate, and fuel injection velocity. NOx emissions increased with increasing furnace nitrogen content and furnace temperature, but remained relatively insensitive to variations in fuel injection velocity and firing rate. NOx emissions below 5-10-3 g/MJ (10 ppm-air equivalent at 3% O2 dry) were obtained for furnace temperatures below 1533 K (2300?F) and furnace nitrogen levels between 1 and 40%. CO emissions were typically low (<35 ppm). Detailed in-furnace species measurements revealed the importance of the interior furnace circulation patterns, as influenced by fuel and oxidant injection schemes, on pollutant emissions. The combustion stability traits of several DOC burner arrangements were ascertained through furnace pressure measurements, wit6h increased stability occurring as furnace temperature increased and as the separation distance between fuel and oxidant inputs decreased. Based on current market conditions, oxy-fuel conversion of batch steel reheat furnaces with a DOC burner is justified on the basis of lower utility costs alone. However, conversion of continuous steel reheat furnaces, which are responsible for most steel production, required additional economic incentives, such as further fuel savings, increased furnace productivity, or emission credits.

  10. Vehicle Technologies Office Merit Review 2014: Ionic Liquids as Anti-Wear

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants | Department of Energy Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants Vehicle Technologies Office Merit Review 2014: Ionic Liquids as Anti-Wear Additives for Next-Generation Low-Viscosity Fuel-Efficient Engine Lubricants Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit

  11. OXYGEN ENHANCED COMBUSTION FOR NOx CONTROL

    SciTech Connect (OSTI)

    Lawrence E. Bool; Jack C. Chen; David R. Thompson

    2000-07-01

    Increased environmental regulations will require utility boilers to reduce NO{sub x} emissions to less than 0.15lb/MMBtu in the near term. Conventional technologies such as Selective Catalytic Reduction (SCR) and Selective Non-Catalytic Reduction (SNCR) are unable to achieve these lowered emission levels without substantially higher costs and major operating problems. Oxygen enhanced combustion is a novel technology that allows utilities to meet the NO{sub x} emission requirements without the operational problems that occur with SCR and SNCR. Furthermore, oxygen enhanced combustion can achieve these NO{sub x} limits at costs lower than conventional technologies. The objective of this program is to demonstrate the use of oxygen enhanced combustion as a technical and economical method of meeting the EPA State Implementation Plan for NO{sub x} reduction to less than 0.15lb/MMBtu for a wide range of boilers and coal. The oxygen enhanced coal combustion program (Task 1) focused this quarter on the specific objective of exploration of the impact of oxygen enrichment on NO{sub x} formation utilizing small-scale combustors for parametric testing. Research efforts toward understanding any limitations to the applicability of the technology to different burners and fuels such as different types of coal are underway. The objective of the oxygen transport membrane (OTM) materials development program (Task 2.1) is to ascertain a suitable material composition that can be fabricated into dense tubes capable of producing the target oxygen flux under the operating conditions. This requires that the material have sufficient oxygen permeation resulting from high oxygen ion conductivity, high electronic conductivity and high oxygen surface exchange rate. The OTM element development program (Task 2.2) objective is to develop, fabricate and characterize OTM elements for laboratory and pilot reactors utilizing quality control parameters to ensure reproducibility and superior performance. A specific goal is to achieve a material that will sinter to desired density without compromising other variables such as reaction to binder systems or phase purity. Oxygen-enhanced combustion requires a facility which is capable of supplying high purity oxygen (>99.5%) at low costs. This goal can be achieved through the thermal integration of high temperature air separation with ceramic OTM. The objective of the OTM process development program (Task 2.3) is to demonstrate successfully the program objectives on a lab-scale single OTM tube reactor under process conditions comparable to those of an optimum large-scale oxygen facility. This quarterly technical progress report will summarize work accomplished for the Program through the first quarter April--June 2000 in the following task areas: Task 1 Oxygen Enhanced Coal Combustion; Task 2 Oxygen Transport Membranes; and Task 4 Program Management.

  12. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect (OSTI)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

  13. A study on a voloxidizer with an oxygen concentration controller for a scale-up DESIGN

    SciTech Connect (OSTI)

    Kim, Young-Hwan; Yoon, Ji-Sup; Park, Byung-Suk; Jung, Jae-Hoo

    2007-07-01

    For a oxidation of UO{sub 2} pellets of tens/kg in a vol-oxidizer, the existing devices take a long time, also, for their scale-up to an engineering scale, we need the optimum oxygen concentration with an maximum oxidation efficiency. In this study, we attained the optimum oxygen concentration to shorten the oxidation time of a simulation fuel using a vol-oxidizer with an oxygen concentration controller and sensor. We compared the characteristics of a galvanic sensor with a zirconium oxide (ZrO{sub 2}) one. The simulation fuel was manufactured with 14 metallic oxides, and used at a mass of 500 g HM/batch. At 500 deg. C, the galvanic and zirconium oxide sensors measured the oxidation time for the simulation fuel. Also, the oxidation time of the simulation fuel was measured according to a change of the oxygen concentration with the selected sensor, and the sample was analyzed. (authors)

  14. Optical oxygen concentration monitor

    DOE Patents [OSTI]

    Kebabian, P.

    1997-07-22

    A system for measuring and monitoring the concentration of oxygen uses as a light source an argon discharge lamp, which inherently emits light with a spectral line that is close to one of oxygen`s A-band absorption lines. In a preferred embodiment, the argon line is split into sets of components of shorter and longer wavelengths by a magnetic field of approximately 2,000 Gauss that is parallel to the light propagation from the lamp. The longer wavelength components are centered on an absorption line of oxygen and thus readily absorbed, and the shorter wavelength components are moved away from that line and minimally absorbed. A polarization modulator alternately selects the set of the longer wavelength, or upshifted, components or the set of the shorter wavelength, or downshifted, components and passes the selected set to an environment of interest. After transmission over a path through that environment, the transmitted optical flux of the argon line varies as a result of the differential absorption. The system then determines the concentration of oxygen in the environment based on the changes in the transmitted optical flux between the two sets of components. In alternative embodiments modulation is achieved by selectively reversing the polarity of the magnetic field or by selectively supplying the magnetic field to either the emitting plasma of the lamp or the environment of interest. 4 figs.

  15. Coal to Liquids | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal to Liquids Coal to Liquids Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in Charleston, WV, the Yeager facility was constructed and operated with support from the Office of Fossil Energy’s National Energy Technology Laboratory. Major General Allen Tackett of the National Guard's 130th Airlift Wing dispenses the first fill-up of hydrogen fuel from the Yeager facility. Located in

  16. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, R.R.; Bond, J.A.

    1994-03-29

    A high-voltage electrical insulator for electrically insulating a thermoelectric module in a spacecraft from a niobium-1% zirconium alloy wall of a heat exchanger filled with liquid lithium while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator has a single crystal alumina layer (SxAl[sub 2]O[sub 3], sapphire) with a niobium foil layer bonded thereto on the surface of the alumina crystal facing the heat exchanger wall, and a molybdenum layer bonded to the niobium layer to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface. 3 figures.

  17. Electrical insulator assembly with oxygen permeation barrier

    DOE Patents [OSTI]

    Van Der Beck, Roland R.; Bond, James A.

    1994-01-01

    A high-voltage electrical insulator (21) for electrically insulating a thermoelectric module (17) in a spacecraft from a niobium-1% zirconium alloy wall (11) of a heat exchanger (13) filled with liquid lithium (16) while providing good thermal conductivity between the heat exchanger and the thermoelectric module. The insulator (21) has a single crystal alumina layer (SxAl.sub.2 O.sub.3, sapphire) with a niobium foil layer (32) bonded thereto on the surface of the alumina crystal (26) facing the heat exchanger wall (11), and a molybdenum layer (31) bonded to the niobium layer (32) to act as an oxygen permeation barrier to preclude the oxygen depleting effects of the lithium from causing undesirable niobium-aluminum intermetallic layers near the alumina-niobium interface.

  18. Superbase-derived protic ionic liquids

    DOE Patents [OSTI]

    Dai, Sheng; Luo, Huimin; Baker, Gary A.

    2013-09-03

    Protic ionic liquids having a composition of formula (A.sup.-)(BH.sup.+) wherein A.sup.- is a conjugate base of an acid HA, and BH.sup.+ is a conjugate acid of a superbase B. In particular embodiments, BH.sup.+ is selected from phosphazenium species and guanidinium species encompassed, respectively, by the general formulas: ##STR00001## The invention is also directed to films and membranes containing these protic ionic liquids, with particular application as proton exchange membranes for fuel cells.

  19. Development of alternative fuels from coal-derived syngas. Quarterly status report No. 6, January 1--March 31, 1992

    SciTech Connect (OSTI)

    Brown, D.M.

    1992-05-19

    The overall objectives of this program are to investigate potential technologies for the conversion of coal-derived synthesis gas to oxygenated fuels, hydrocarbon fuels, fuel intermediates, and octane enhancers; and to demonstrate the most promising technologies at DOE`s LaPorte, Texas, Slurry Phase Alternative Fuels Development Unit (AFDU). BASF continues to have difficulties in scaling-up the new isobutanol synthesis catalyst developed in Air Products` laboratories. Investigations are proceeding, but the proposed operation at LaPorte in April is now postponed. DOE has accepted a proposal to demonstrate Liquid Phase Shift (LPS) chemistry at LaPorte as an alternative to isobutanol. There are two principal reasons for carrying out this run. First, following the extensive modifications at the site, operation on a relatively ``benign`` system is needed before we start on Fischer-Tropsch technology in July. Second, use of shift catalyst in a slurry reactor will enable DOE`s program on coal-based Fischer-Tropsch to encompass commercially available cobalt catalysts-up to now they have been limited to iron-based catalysts which have varying degrees of shift activity. In addition, DOE is supportive of continued fuel testing of LaPorte methanol-tests of MIOO at Detroit Diesel have been going particularly well. LPS offers the opportunity to produce methanol as the catalyst, in the absence of steam, is active for methanol synthesis.

  20. Utilization of Renewable Oxygenates as Gasoline Blending Components

    SciTech Connect (OSTI)

    Yanowitz, J.; Christensen, E.; McCormick, R. L.

    2011-08-01

    This report reviews the use of higher alcohols and several cellulose-derived oxygenates as blend components in gasoline. Material compatibility issues are expected to be less severe for neat higher alcohols than for fuel-grade ethanol. Very little data exist on how blending higher alcohols or other oxygenates with gasoline affects ASTM Standard D4814 properties. Under the Clean Air Act, fuels used in the United States must be 'substantially similar' to fuels used in certification of cars for emission compliance. Waivers for the addition of higher alcohols at concentrations up to 3.7 wt% oxygen have been granted. Limited emission testing on pre-Tier 1 vehicles and research engines suggests that higher alcohols will reduce emissions of CO and organics, while NOx emissions will stay the same or increase. Most oxygenates can be used as octane improvers for standard gasoline stocks. The properties of 2-methyltetrahydrofuran, dimethylfuran, 2-methylfuran, methyl pentanoate and ethyl pentanoate suggest that they may function well as low-concentration blends with gasoline in standard vehicles and in higher concentrations in flex fuel vehicles.

  1. Natural Ores as Oxygen Carriers in Chemical Looping Combustion

    SciTech Connect (OSTI)

    Tian, Hanjing; Siriwardane, Ranjani; Simonyi, Thomas; Poston, James

    2013-08-01

    Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. The use of natural minerals as oxygen carriers has advantages, such as lower cost and availability. Eight materials, based on copper or iron oxides, were selected for screening tests of CLC processes using coal and methane as fuels. Thermogravimetric experiments and bench-scale fixed-bed reactor tests were conducted to investigate the oxygen transfer capacity, reaction kinetics, and stability during cyclic reduction/oxidation reaction. Most natural minerals showed lower combustion capacity than pure CuO/Fe{sub 2}O{sub 3} due to low-concentrations of active oxide species in minerals. In coal CLC, chryscolla (Cu-based), magnetite, and limonite (Fe-based) demonstrated better reaction performances than other materials. The addition of steam improved the coal CLC performance when using natural ores because of the steam gasification of coal and the subsequent reaction of gaseous fuels with active oxide species in the natural ores. In methane CLC, chryscolla, hematite, and limonite demonstrated excellent reactivity and stability in 50-cycle thermogravimetric analysis tests. Fe{sub 2}O{sub 3}-based ores possess greater oxygen utilization but require an activation period before achieving full performance in methane CLC. Particle agglomeration issues associated with the application of natural ores in CLC processes were also studied by scanning electron microscopy (SEM).

  2. Solid fuel applications to transportation engines

    SciTech Connect (OSTI)

    Rentz, Richard L.; Renner, Roy A.

    1980-06-01

    The utilization of solid fuels as alternatives to liquid fuels for future transportation engines is reviewed. Alternative liquid fuels will not be addressed nor will petroleum/solid fuel blends except for the case of diesel engines. With respect to diesel engines, coal/oil mixtures will be addressed because of the high interest in this specific application as a result of the large number of diesel engines currently in transportation use. Final assessments refer to solid fuels only for diesel engines. The technical assessments of solid fuels utilization for transportation engines is summarized: solid fuel combustion in transportation engines is in a non-developed state; highway transportation is not amenable to solid fuels utilization due to severe environmental, packaging, control, and disposal problems; diesel and open-cycle gas turbines do not appear worthy of further development, although coal/oil mixtures for slow speed diesels may offer some promise as a transition technology; closed-cycle gas turbines show some promise for solid fuels utilization for limited applications as does the Stirling engine for use of cleaner solid fuels; Rankine cycle engines show good potential for limited applications, such as for locomotives and ships; and any development program will require large resources and sophisticated equipment in order to advance the state-of-the-art.

  3. Fuel from Bacteria, CO2, Water, and Solar Energy: Engineering a Bacterial Reverse Fuel Cell

    SciTech Connect (OSTI)

    2010-07-01

    Electrofuels Project: Harvard is engineering a self-contained, scalable Electrofuels production system that can directly generate liquid fuels from bacteria, carbon dioxide (CO2), water, and sunlight. Harvard is genetically engineering bacteria called Shewanella, so the bacteria can sit directly on electrical conductors and absorb electrical current. This current, which is powered by solar panels, gives the bacteria the energy they need to process CO2 into liquid fuels. The Harvard team pumps this CO2 into the system, in addition to water and other nutrients needed to grow the bacteria. Harvard is also engineering the bacteria to produce fuel molecules that have properties similar to gasoline or diesel fuelmaking them easier to incorporate into the existing fuel infrastructure. These molecules are designed to spontaneously separate from the water-based culture that the bacteria live in and to be used directly as fuel without further chemical processing once theyre pumped out of the tank.

  4. Fuel Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuel Cells Fact Sheets Research Team Members Key Contacts Fuel Cells The Solid State Energy Conversion Alliance (SECA) program is responsible for coordinating Federal efforts to facilitate development of a commercially relevant and robust solid oxide fuel cell (SOFC) system. Specific objectives include achieving an efficiency of greater than 60 percent, meeting a stack cost target of $175 per kW, and demonstrating lifetime performance degradation of less than 0.2 percent per 1000 hours over a

  5. Monolithic solid electrolyte oxygen pump

    DOE Patents [OSTI]

    Fee, Darrell C.; Poeppel, Roger B.; Easler, Timothy E.; Dees, Dennis W.

    1989-01-01

    A multi-layer oxygen pump having a one-piece, monolithic ceramic structure affords high oxygen production per unit weight and volume and is thus particularly adapted for use as a portable oxygen supply. The oxygen pump is comprised of a large number of small cells on the order of 1-2 millimeters in diameter which form the walls of the pump and which are comprised of thin, i.e., 25-50 micrometers, ceramic layers of cell components. The cell components include an air electrode, an oxygen electrode, an electrolyte and interconnection materials. The cell walls form the passages for input air and for exhausting the oxygen which is transferred from a relatively dilute gaseous mixture to a higher concentration by applying a DC voltage across the electrodes so as to ionize the oxygen at the air electrode, whereupon the ionized oxygen travels through the electrolyte and is converted to oxygen gas at the oxygen electrode.

  6. Fuel-air munition and device

    DOE Patents [OSTI]

    Carlson, Gary A.

    1976-01-01

    An aerially delivered fuel-air munition consisting of an impermeable tank filled with a pressurized liquid fuel and joined at its two opposite ends with a nose section and a tail assembly respectively to complete an aerodynamic shape. On impact the tank is explosively ruptured to permit dispersal of the fuel in the form of a fuel-air cloud which is detonated after a preselected time delay by means of high explosive initiators ejected from the tail assembly. The primary component in the fuel is methylacetylene, propadiene, or mixtures thereof to which is added a small mole fraction of a relatively high vapor pressure liquid diluent or a dissolved gas diluent having a low solubility in the primary component.

  7. Fuel pin cladding

    DOE Patents [OSTI]

    Vaidyanathan, S.; Adamson, M.G.

    1986-01-28

    Disclosed is an improved fuel pin cladding, particularly adapted for use in breeder reactors, consisting of composite tubing with austenitic steel on the outer portion of the thickness of the tube wall and with nickel and/or ferritic material on the inner portion of the thickness of the tube wall. The nickel forms a sacrificial barrier as it reacts with certain fission products thereby reducing fission product activity at the austenitic steel interface. The ferritic material forms a preventive barrier for the austenitic steel as it is immune to liquid metal embrittlement. The improved cladding permits the use of high density fuel which in turn leads to a better breeding ratio in breeder reactors, and will increase the threshold at which failure occurs during temperature transients. 2 figs.

  8. Fuel pin cladding

    DOE Patents [OSTI]

    Vaidyanathan, S.; Adamson, M.G.

    1983-12-16

    An improved fuel pin cladding, particularly adapted for use in breeder reactors, is described which consist of composite tubing with austenitic steel on the outer portion of the thickness of the tube wall and with nickel an/or ferritic material on the inner portion of the thickness of the tube wall. The nickel forms a sacrificial barrier as it reacts with certain fission products thereby reducing fission product activity at the austenitic steel interface. The ferritic material forms a preventive barrier for the austenitic steel as it is immune to liquid metal embrittlement. The improved cladding permits the use of high density fuel which in turn leads to a better breeding ratio in breeder reactors, and will increase the threshold at which failure occurs during temperature transients.

  9. Fuel pin cladding

    DOE Patents [OSTI]

    Vaidyanathan, Swaminathan; Adamson, Martyn G.

    1986-01-01

    An improved fuel pin cladding, particularly adapted for use in breeder reactors, consisting of composite tubing with austenitic steel on the outer portion of the thickness of the tube wall and with nickel and/or ferritic material on the inner portion of the thickness of the tube wall. The nickel forms a sacrificial barrier as it reacts with certain fission products thereby reducing fission product activity at the austenitic steel interface. The ferritic material forms a preventive barrier for the austenitic steel as it is immune to liquid metal embrittlement. The improved cladding permits the use of high density fuel which in turn leads to a better breeding ratio in breeder reactors, and will increase the threshold at which failure occurs during temperature transients.

  10. Process for stabilization of coal liquid fractions

    DOE Patents [OSTI]

    Davies, Geoffrey; El-Toukhy, Ahmed

    1987-01-01

    Coal liquid fractions to be used as fuels are stabilized against gum formation and viscosity increases during storage, permitting the fuel to be burned as is, without further expensive treatments to remove gums or gum-forming materials. Stabilization is accomplished by addition of cyclohexanol or other simple inexpensive secondary and tertiary alcohols, secondary and tertiary amines, and ketones to such coal liquids at levels of 5-25% by weight with respect to the coal liquid being treated. Cyclohexanol is a particularly effective and cost-efficient stabilizer. Other stabilizers are isopropanol, diphenylmethanol, tertiary butanol, dipropylamine, triethylamine, diphenylamine, ethylmethylketone, cyclohexanone, methylphenylketone, and benzophenone. Experimental data indicate that stabilization is achieved by breaking hydrogen bonds between phenols in the coal liquid, thereby preventing or retarding oxidative coupling. In addition, it has been found that coal liquid fractions stabilized according to the invention can be mixed with petroleum-derived liquid fuels to produce mixtures in which gum deposition is prevented or reduced relative to similar mixtures not containing stabilizer.

  11. Radiation Chemistry and Photochemistry of Ionic Liquids

    SciTech Connect (OSTI)

    Wishart, J.F.; Takahaski, K.

    2010-12-01

    As our understanding of ionic liquids and their tunable properties has grown, it is possible to see many opportunities for ionic liquids to contribute to the sustainable use of energy. The potential safety and environmental benefits of ionic liquids, as compared to conventional solvents, have attracted interest in their use as processing media for the nuclear fuel cycle. Therefore, an understanding of the interactions of ionizing radiation and photons with ionic liquids is strongly needed. However, the radiation chemistry of ionic liquids is still a relatively unexplored topic although there has been a significant increase in the number of researchers in the field recently. This article provides a brief introduction to ionic liquids and their interesting properties, and recent advances in the radiation chemistry and photochemistry of ionic liquids. In this article, we will mainly focus on excess electron dynamics and radical reaction dynamics. Because solvation dynamics processes in ionic liquids are much slower than in molecular solvents, one of the distinguishing characteristics is that pre-solvated electrons play an important role in ionic liquid radiolysis. It will be also shown that the reaction dynamics of radical ions is significantly different from that observed in molecular solvents because of the Coulombic screening effects and electrostatic interactions in ionic liquids.

  12. Electrorefining of uranium and plutonium from liquid cadmium

    SciTech Connect (OSTI)

    Tomczuk, Z.; Poa, D.S.; Miller, W.E.; Steunenberg, R.K.

    1985-01-01

    Feasibility of electrorefining of U, Pu, and mixtures thereof using a liquid Cd anode and a molten-salt electrolyte was investigated for the proposed pyrometallurgical process for the Integral Fast Reactor fuel. (DLC)

  13. Hydrogen Production: Biomass-Derived Liquid Reforming | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Others (for example, bio-oils) may be reformed on-site. The process for reforming ... The liquid fuel is reacted with steam at high temperatures in the presence of a catalyst ...

  14. Fuel Cell Animation (Text Version) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Information Resources » Multimedia » Fuel Cell Animation (Text Version) Fuel Cell Animation (Text Version) This text version of the fuel cell animation demonstrates how a fuel cell uses hydrogen to produce electricity, with only water and heat as byproducts. Fuel cell shown with its inputs and outputs. Hydrogen input on left, oxygen input on right, water and heat outputs on the back, with an electrical circuit going around the top. A fuel cell is a device that uses hydrogen (or hydrogen-rich

  15. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, Amy A.

    1994-01-01

    A dropping electrolyte electrode for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions.

  16. Generator configuration for solid oxide fuel cells

    DOE Patents [OSTI]

    Reichner, Philip

    1989-01-01

    Disclosed are improvements in a solid oxide fuel cell generator 1 having a multiplicity of electrically connected solid oxide fuel cells 2, where a fuel gas is passed over one side of said cells and an oxygen-containing gas is passed over the other side of said cells resulting in the generation of heat and electricity. The improvements comprise arranging the cells in the configuration of a circle, a spiral, or folded rows within a cylindrical generator, and modifying the flow rate, oxygen concentration, and/or temperature of the oxygen-containing gases that flow to those cells that are at the periphery of the generator relative to those cells that are at the center of the generator. In these ways, a more uniform temperature is obtained throughout the generator.

  17. Conversion of raw carbonaceous fuels

    DOE Patents [OSTI]

    Cooper, John F.

    2007-08-07

    Three configurations for an electrochemical cell are utilized to generate electric power from the reaction of oxygen or air with porous plates or particulates of carbon, arranged such that waste heat from the electrochemical cells is allowed to flow upwards through a storage chamber or port containing raw carbonaceous fuel. These configurations allow combining the separate processes of devolatilization, pyrolysis and electrochemical conversion of carbon to electric power into a single unit process, fed with raw fuel and exhausting high BTU gases, electric power, and substantially pure CO.sub.2 during operation.

  18. ionic liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy Nuclear

  19. Fuel Model | NISAC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fuels Model This model informs analyses of the availability of transportation fuel in the event the fuel supply chain is disrupted. The portion of the fuel supply system...

  20. Fuel cell tubes and method of making same

    DOE Patents [OSTI]

    Borglum, Brian P.

    1999-11-30

    A method of manufacturing porous ceramic tubes for fuel cells with improved properties and higher manufacturing yield is disclosed. The method involves extruding a closed end fuel cell tube, such as an air electrode of a solid oxide fuel cell, in which the closed end also functions as the sintering support. The resultant fuel cell tube has a superior porosity distribution which allows improved diffusion of oxygen at the closed end of the tube during operation of the fuel cell. Because this region has the highest current density, performance enhancement and improved reliability of the fuel cell tube result. Furthermore, the higher manufacturing yield associated with the present method decreases the overall fuel cell cost. A method of manufacturing porous ceramic tubes for fuel cells with improved properties and higher manufacturing yield is disclosed. The method involves extruding a closed end fuel cell tube, such as an air electrode of a solid oxide fuel cell, in which the closed end also functions as the sintering support. The resultant fuel cell tube has a superior porosity distribution which allows improved diffusion of oxygen at the closed end of the tube during operation of the fuel cell. Because this region has the highest current density, performance enhancement and improved reliability of the fuel cell tube result. Furthermore, the higher manufacturing yield associated with the present method decreases the overall fuel cell cost.