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We encourage you to perform a real-time search of NLEBeta
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1

Isotope and Temperature Effects in Liquid Water Probed by Soft...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of temperature and isotope substitution (replacing the hydrogen with deuterium to make "heavy" water). Their findings shed new light on the unique microscopic and macroscopic...

2

A Passive Probe for Subsurface Oceans and Liquid Water in Jupiter's Icy Moons  

E-Print Network [OSTI]

We describe an interferometric reflectometer method for passive detection of subsurface oceans and liquid water in Jovian icy moons using Jupiter's decametric radio emission (DAM). The DAM flux density exceeds 3,000 times the galactic background in the neighborhood of the Jovian icy moons, providing a signal that could be used for passive radio sounding. An instrument located between the icy moon and Jupiter could sample the DAM emission along with its echoes reflected in the ice layer of the target moon. Cross-correlating the direct emission with the echoes would provide a measurement of the ice shell thickness along with its dielectric properties. The interferometric reflectometer provides a simple solution to sub-Jovian radio sounding of ice shells that is complementary to ice penetrating radar measurements better suited to measurements in the anti-Jovian hemisphere that shadows Jupiter's strong decametric emission. The passive nature of this technique also serves as risk reduction in case of radar transmi...

Romero-Wolf, Andrew; Maiwald, Frank; Heggy, Essam; Ries, Paul; Liewer, Kurt

2014-01-01T23:59:59.000Z

3

High-Throughput Mode Liquid Microjunction Surface Sampling Probe  

SciTech Connect (OSTI)

A simple and automated spot sampling operation mode for a liquid microjunction surface sampling probe/electrospray ionization mass spectrometry (LMJ-SSP/ESI-MS) system is reported. Prior manual and automated spot sampling methods with this probe relied on a careful, relatively slow alignment of the probe and surface distance (<20 m spacing) to form the probe-to-surface liquid microjunction critical to successful surface sampling. Moreover, sampling multiple spots required retraction of the surface from the probe and a repeat of this careful probe-to-surface distance alignment at the next sampling position. With the method described here, the probe was not positioned as close to the surface, the exact probeto-surface positioning was found to be less critical (spanning distances from about 100-300 m), and this distance was not altered during the sampling of an entire array of sample spots. With the probe positioned within the appropriate distance from the surface, the liquid microjunction was formed by letting the liquid from the sampling end of the probe extend out from the probe to the surface. This was accomplished by reducing the selfaspiration liquid flow rate of the probe to a value less than the volume flow rate pumped into the probe. When the self-aspiration rate of the probe was subsequently increased, analytes on the surface that dissolved at the liquid microjunction were aspirated back into the probe with the liquid that created the liquid microjunction and electrosprayed. Presented here are the basics of this new sampling mode, as well as data that illustrate the potential analytical capabilities of the device to conduct highthroughput quantitative analysis.

Van Berkel, Gary J [ORNL; Kertesz, Vilmos [ORNL; King, Richard C. [PharmaCadence

2009-01-01T23:59:59.000Z

4

ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

Cadeddu, Maria

5

Far-Infrared Dielectric Properties of Polar Liquids Probed by Femtosecond Terahertz Pulse Spectroscopy  

E-Print Network [OSTI]

the microwave and the FIR regions; the motions that are probed at these frequencies bridge the gap between bulk to study gases,2 semiconductors,3 super- conductors,4 dielectrics,5 nonpolar liquids,6 and water.7 We are generated by the excitation of charge carriers in a semiconductor material with ultrashort pulses of above

6

Probing Liquid Surfaces under Vacuum Using SEM and TOF-SIMS....  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

beneath it. This window supports the liquid against the vacuum by the liquid’s surface tension, while limiting the high-density vapor region traversed by the probe beams...

7

Distributed Reforming of Renewable Liquids via Water Splitting...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport...

8

Core-softened Fluids, Water-like Anomalies and the Liquid-Liquid Critical Points  

E-Print Network [OSTI]

. INTRODUCTION Water is characterized by well-known thermodynamic and kinetic liquid-state anomalies; for examplePREPRINT Core-softened Fluids, Water-like Anomalies and the Liquid-Liquid Critical Points Evy simulations are used to examine the relationship between water-like anoma- lies and the liquid-liquid critical

Barbosa, Marcia C. B.

9

II. Properties of Water 1. Ice and Liquid water structure  

E-Print Network [OSTI]

Heat Capacity 4. Solvent Properties 5. Dissociation: Acids & Bases / pH II. Organic Chemistry A transport in plants #12;Water has a high specific heat capacity specific heat capacity = amount of energyII. Properties of Water 1. Ice and Liquid water structure 2. Cohesion / Surface Tension 3. High

Frey, Terry

10

Liquid Water Oceans in Ice Giants  

E-Print Network [OSTI]

Aptly named, ice giants such as Uranus and Neptune contain significant amounts of water. While this water cannot be present near the cloud tops, it must be abundant in the deep interior. We investigate the likelihood of a liquid water ocean existing in the hydrogen-rich region between the cloud tops and deep interior. Starting from an assumed temperature at a given upper tropospheric pressure (the photosphere), we follow a moist adiabat downward. The mixing ratio of water to hydrogen in the gas phase is small in the photosphere and increases with depth. The mixing ratio in the condensed phase is near unity in the photosphere and decreases with depth; this gives two possible outcomes. If at some pressure level the mixing ratio of water in the gas phase is equal to that in the deep interior, then that level is the cloud base. Alternately, if the mixing ratio of water in the condensed phase reaches that in the deep interior, then the surface of a liquid ocean will occur. We find that Neptune is both too warm (photospheric temperature too high) and too dry (mixing ratio of water in the deep interior too low) for liquid oceans to exist at present. To have a liquid ocean, Neptune's deep interior water to gas ratio would have to be higher than current models allow, and the density at 19 kbar would have to be ~ 0.8 g/cm^3. Such a high density is inconsistent with gravitational data obtained during the Voyager flyby. As Neptune cools, the probability of a liquid ocean increases. Extrasolar "hot Neptunes," which presumably migrate inward toward their parent stars, cannot harbor liquid water oceans unless they have lost almost all of the hydrogen and helium from their deep interiors.

Sloane J. Wiktorowicz; Andrew P. Ingersoll

2006-09-26T23:59:59.000Z

11

On the Fluctuations that Order and Frustrate Liquid Water  

E-Print Network [OSTI]

Most nonpolar liquids have heat capacities that range from 8the maximum liquid state heat capacity[173]. ExperimentallyLIQUID AND SOLID WATER (a) Density (b) Compressibility (c) Heat Capacity

Limmer, David

2013-01-01T23:59:59.000Z

12

Phase effects for electrons in liquid water and water vapor  

SciTech Connect (OSTI)

The objective of these studies is to compare transport, energy loss, and other phenomena for electrons in water in the liquid and vapor phases. Understanding the differences and similarities is an interesting physics problem in its own right. It is also important for applying the relatively large body of experimental data available for the vapor to the liquid, which is of greater relevance in radiobiology. This paper presents a summary of results from a series of collaborative studies carried out by the authors at Oak Ridge National Laboratory (ORNL) and the Gesellschaft fuer Strahlen- und Umweltforschung (GSF). 14 figs.

Turner, J.E.; Paretzke, H.G.; Wright, H.A.; Hamm, R.N.; Ritchie, R.H.

1988-01-01T23:59:59.000Z

13

The physics of liquid water Bernard Cabane1  

E-Print Network [OSTI]

with extraordinary properties: it has unusually high melting and boiling temperatures, a huge heat capacity, oneThe physics of liquid water Bernard Cabane1 , Rodolphe Vuilleumier2 1 PMMH, ESPCI, 10 rue Vauquelin, France Abstract Liquid water is a liquid with extraordinary properties: it has a very high cohesion

Paris-Sud XI, Université de

14

Response functions near the liquid-liquid critical point of ST2 water  

E-Print Network [OSTI]

speci¿c heat capacity CP and the isothermal compressibility KT . We use two different methods: (i) fromResponse functions near the liquid-liquid critical point of ST2 water Erik Lascaris , T. A, and for four different system sizes, N = 63, 73, 83, and 93. We locate the liquid-liquid phase transition line

Stanley, H. Eugene

15

Dual harmonic Kelvin probe force microscopy at the graphene–liquid interface  

SciTech Connect (OSTI)

Kelvin probe force microscopy (KPFM) is a powerful technique for the determination of the contact potential difference (CPD) between an atomic force microscope tip and a sample under ambient and vacuum conditions. However, for many energy storage and conversion systems, including graphene-based electrochemical capacitors, understanding electrochemical phenomena at the solid–liquid interface is paramount. Despite the vast potential to provide fundamental insight for energy storage materials at the nanoscale, KPFM has found limited applicability in liquid environments to date. Here, using dual harmonic (DH)-KPFM, we demonstrate CPD imaging of graphene in liquid. We find good agreement with measurements performed in air, highlighting the potential of DH-KPFM to probe electrochemistry at the graphene–liquid interface.

Collins, Liam; Rodriguez, Brian J., E-mail: brian.rodriguez@ucd.ie [School of Physics, University College Dublin, Belfield, Dublin 4 (Ireland); Conway Institute of Biomolecular and Biomedical Research, University College Dublin, Belfield, Dublin 4 (Ireland); Kilpatrick, Jason I.; Weber, Stefan A. L. [Conway Institute of Biomolecular and Biomedical Research, University College Dublin, Belfield, Dublin 4 (Ireland); Vlassiouk, Ivan V. [Energy and Transportation Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Tselev, Alexander; Jesse, Stephen; Kalinin, Sergei V. [Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2014-03-31T23:59:59.000Z

16

Probing the Mobility of Supercooled Liquid 3-Methylpentane at Temperatures  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - SeptemberMicroneedles for4-16 FORPoints ofProbingDewetting andits Radical Anion:

17

3-D Nano-Fiber Manufacturing by Controlled Pulling of Liquid Polymers using Nano-Probes  

E-Print Network [OSTI]

3-D Nano-Fiber Manufacturing by Controlled Pulling of Liquid Polymers using Nano-Probes Amrinder S) nano-scale manufacturing tools in this paper. Commercially available Atomic Force Microscope (AFM) systems are mainly limited to 1-D or 2-D manipulation tasks, and advanced 3-D nano

Sitti, Metin

18

Liquid-liquid equilibria of fuel oxygenate + water + hydrocarbon mixtures. 3: Effect of temperature  

SciTech Connect (OSTI)

The authors have measured the ternary liquid-liquid equilibria of water + ethanol mixtures with, separately, 2,2,4-trimethylpentane and toluene at 5 and 40 C, water + tert-amyl alcohol (TAOH) mixtures with, separately, toluene and hexane at 5 and 40 C, and of water + TAOH + pentane mixtures at 5 C. The ethanol-containing systems exhibit type 1 liquid-liquid phase behavior, and the TAOH-containing systems exhibit type 2 behavior. These data, together with the data they have previously reported at 25 C, provide information on how the liquid-liquid equilibria of these systems change as a function of temperature. While the addition of ethanol is found to increase the solubility of hydrocarbons in the aqueous phase, the concentration of the hydrocarbon in the water-rich phase decreases with increasing temperature. With the exception of hydrocarbon in the water-rich phase, the experimental data could be correlated quite well with either the UNIQUAC or NRTL models. For most of the systems considered here the predictions of the phase behavior with the liquid-liquid UNIFAC group-contribution model are only qualitatively correct. However, the liquid-liquid UNIFAC model erroneously predicts type 2 phase behavior to occur for water + ethanol + 2,2,4-trimethylpentane system at 5 C.

Wagner, G. [Universitaet Karlsruhe (Germany). Institut fuer Thermische Verfahrenstechnik; Sandler, S.I. [Univ. of Delaware, Newark, DE (United States). Center for Molecular and Engineering Thermodynamics

1995-09-01T23:59:59.000Z

19

Liquid-liquid equilibria of water + methanol + 1-octanol and water + ethanol + 1-octanol at various temperatures  

SciTech Connect (OSTI)

This study is part of a wider program of research on the recovery of light alcohols from dilute aqueous solutions using high molecular weight solvents. The authors report liquid-liquid equilibrium data and binodal curves for the systems water + methanol + 1-octanol and water + ethanol + 1-octanol at 25, 35, and 45 C. The data were fitted to the NRTL and UNIQUAC equations.

Arce, A.; Blanco, A.; Souza, P.; Vidal, I. (Univ. of Santiago de Compostela (Spain). Dept. of Chemical Engineering)

1994-04-01T23:59:59.000Z

20

Isothermal vapor-liquid equilibria for methanol + ethanol + water, methanol + water, and ethanol + water  

SciTech Connect (OSTI)

Isothermal vapor-liquid equilibria were measured for the ternary system methanol + ethanol + water and its constituent binary systems of methanol + water and ethanol + water at 323.15, 328.15, and 333.15 K. The apparatus that was used made it possible to control the measured temperature and total pressure by computer. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

Kurihara, Kiyofumi; Takeda, Kouichi; Kojima, Kazuo [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Minoura, Tsuyoshi [Mitui Engineering and Shipbuilding Co., Ltd., Tokyo (Japan)

1995-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy  

SciTech Connect (OSTI)

We present the first femtosecond soft x-ray spectroscopy in liquids, enabling the observation of changes in hydrogen bond structures in water via core-hole excitation. The oxygen K-edge of vibrationally excited water is probed with femtosecond soft x-ray pulses, exploiting the relation between different water structures and distinct x-ray spectral features. After excitation of the intramolecular OH stretching vibration, characteristic x-ray absorption changes monitor the conversion of strongly hydrogen-bonded water structures to more disordered structures with weaker hydrogen-bonding described by a single subpicosecond time constant. The latter describes the thermalization time of vibrational excitations and defines the characteristic maximum rate with which nonequilibrium populations of more strongly hydrogen-bonded water structures convert to less-bonded ones. On short time scales, the relaxation of vibrational excitations leads to a transient high-pressure state and a transient absorption spectrum different from that of statically heated water.

Wen, Haidan; Huse, Nils; Schoenlein, Robert W.; Lindenberg, Aaron M.

2010-05-01T23:59:59.000Z

22

A flexible, highly stable electrochemical scanning probe microscope for nanoscale studies at the solid-liquid interface  

E-Print Network [OSTI]

low-noise measurements in ambient, in situ, and electrochemical environments. II. DESIGNA flexible, highly stable electrochemical scanning probe microscope for nanoscale studies at the solid-liquid interface, specifically in electrolyte environments. Quantification of system noise limits

Gimzewski, James

23

Water at the Surfaces of Aligned Phospholipid Multibilayer Model Membranes Probed with Ultrafast Vibrational  

E-Print Network [OSTI]

Water at the Surfaces of Aligned Phospholipid Multibilayer Model Membranes Probed with Ultrafast@stanford.edu Abstract: The dynamics of water at the surface of artificial membranes composed of aligned multibilayers pump-probe spectroscopy. The experiments are performed at various hydration levels, x ) 2 - 16 water

Fayer, Michael D.

24

E-Print Network 3.0 - acidic liquid water Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquid water Search Powered by Explorit Topic List Advanced Search Sample search results for: acidic liquid water Page: << < 1 2 3 4 5 > >> 1 Mallinckrodt Specialty Chemicals Co....

25

Spectroscopic investigations of hydrogen bond dynamics in liquid water  

E-Print Network [OSTI]

Many of the remarkable physical and chemical properties of liquid water are due to the strong influence hydrogen bonds have on its microscopic dynamics. However, because of the fast timescales involved, there are relatively ...

Fecko, Christopher J., 1975-

2004-01-01T23:59:59.000Z

26

Out of equilibrium GigaPa Young modulus of water nanobridge probed by Force Feedback Microscopy  

E-Print Network [OSTI]

Because of capillary condensation, water droplets appear in nano/micropores. The large associated surface interactions can deeply influence macroscopic properties as in granular media. We report that dynamical properties of such nanobridge dramatically change when probed at different time scales. Using a novel AFM mode, the Force Feedback Microscopy, the gap between the nanotip and the surface is continuously varied, and we observe this change in the simultaneous measurements, at different frequencies, of the stiffness G'(N/m), the dissipative coefficient G"(kg/sec) together with the static force. As the measuring time approaches the microsecond, the liquid droplet exhibits a large positive stiffness (it is small and negative in the long time limit). Although clearly controlled by surface effects, it compares to the stiffness of a solid nanobridge with a 1 GigaPa Young modulus. We argue that as evaporation and condensation gradually lose efficiency, the contact line progressively becomes immobile, which explains this behavior.

Simon Carpentier; Mario S. Rodrigues; Luca Costa; Miguel V. Vitorino; Elisabeth Charlaix; Joel Chevrier

2015-03-18T23:59:59.000Z

27

Out of equilibrium GigaPa Young modulus of water nanobridge probed by Force Feedback Microscopy  

E-Print Network [OSTI]

Because of capillary condensation, water droplets appear in nano/micropores. The large associated surface interactions can deeply influence macroscopic properties as in granular media. We report that dynamical properties of such nanobridge dramatically change when probed at different time scales. Using a novel AFM mode, the Force Feedback Microscopy, the gap between the nanotip and the surface is continuously varied, and we observe this change in the simultaneous measurements, at different frequencies, of the stiffness G'(N/m), the dissipative coefficient G"(kg/sec) together with the static force. As the measuring time approaches the microsecond, the liquid droplet exhibits a large positive stiffness (it is small and negative in the long time limit). Although clearly controlled by surface effects, it compares to the stiffness of a solid nanobridge with a 1 GigaPa Young modulus. We argue that as evaporation and condensation gradually lose efficiency, the contact line progressively becomes immobile, which expla...

Carpentier, Simon; Costa, Luca; Vitorino, Miguel V; Charlaix, Elisabeth; Chevrier, Joel

2015-01-01T23:59:59.000Z

28

Process for blending coal with water immiscible liquid  

DOE Patents [OSTI]

A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

Heavin, Leonard J. (Olympia, WA); King, Edward E. (Gig Harbor, WA); Milliron, Dennis L. (Lacey, WA)

1982-10-26T23:59:59.000Z

29

Behavior of Supercooled Aqueous Solutions Stemming from Hidden Liquid-Liquid Transition in Water  

E-Print Network [OSTI]

A popular hypothesis that explains the anomalies of supercooled water is the existence of a metastable liquid-liquid transition hidden below the line of homogeneous nucleation. If this transition exists and if it is terminated by a critical point, the addition of a solute should generate a line of liquid-liquid critical points emanating from the critical point of pure metastable water. We have analyzed thermodynamic consequences of this scenario. In particular, we consider the behavior of two systems, H2O-NaCl and H2O-glycerol. We find the behavior of the heat capacity in supercooled aqueous solutions of NaCl, as reported by Archer and Carter, to be consistent with the presence of the metastable liquid-liquid transition. We suggest an interpretation of the liquid-liquid transition in aqueous solutions of glycerol, recently observed by Murata and Tanaka, elucidating the non-conserved nature of the order parameter, its coupling with density and concentration, and the peculiarity of "spinodal decomposition without phase separation". We also show how the shape of the critical line in a solution controls the difference in concentration of the coexisting liquid phases.

John W. Biddle; Vincent Holten; Mikhail A. Anisimov

2014-08-21T23:59:59.000Z

30

Structure and Depletion at Fluoro- and Hydro-carbon/Water Liquid/Liquid Interfaces  

E-Print Network [OSTI]

The results of x-ray reflectivity studies of two oil/water (liquid/liquid) interfaces are inconsistent with recent predictions of the presence of a vapor-like depletion region at hydrophobic/aqueous interfaces. One of the oils, perfluorohexane, is a fluorocarbon whose super-hydrophobic interface with water provides a stringent test for the presence of a depletion layer. The other oil, heptane, is a hydrocarbon and, therefore, is more relevant to the study of biomolecular hydrophobicity. These results are consistent with the sub-angstrom proximity of water to soft hydrophobic materials.

Kaoru Kashimoto; Jaesung Yoon; Binyang Hou; Chiu-hao Chen; Binhua Lin; Makoto Aratono; Takanori Takiue; Mark L. Schlossman

2008-07-18T23:59:59.000Z

31

Local Structure Analysis in $Ab$ $Initio$ Liquid Water  

E-Print Network [OSTI]

Within the framework of density functional theory, the inclusion of exact exchange and non-local van der Waals/dispersion (vdW) interactions is crucial for predicting a microscopic structure of ambient liquid water that quantitatively agrees with experiment. In this work, we have used the local structure index (LSI) order parameter to analyze the local structure in such highly accurate $ab$ $initio$ liquid water. At ambient conditions, the LSI probability distribution, P($I$), was unimodal with most water molecules characterized by more disordered high-density-like local environments. With thermal excitations removed, the resultant bimodal P($I$) in the inherent potential energy surface (IPES) exhibited a 3:1 ratio between high- and low-density-like molecules, with the latter forming small connected clusters amid the predominant population. By considering the spatial correlations and hydrogen bond network topologies $among$ water molecules with the same LSI identities, we demonstrate that the signatures of the experimentally observed low- (LDA) and high-density (HDA) amorphous phases of ice are present in the IPES of ambient liquid water. Analysis of the LSI autocorrelation function uncovered a persistence time of $\\sim$ 4 ps---a finding consistent with the fact that natural thermal fluctuations are responsible for transitions between these distinct yet transient local aqueous environments in ambient liquid water.

Biswajit Santra; Robert A. DiStasio Jr.; Fausto Martelli; Roberto Car

2015-02-27T23:59:59.000Z

32

Equation of State for Supercooled Water Near the Liquid-Liquid Critical Point  

E-Print Network [OSTI]

We have developed a scaled parametric equation of state to describe and predict thermodynamic properties of supercooled water. The equation of state, built on the growing evidence that the critical point of supercooled liquid-liquid water separation exists, is universal in terms of theoretical scaling fields and is shown to belong to the Ising-model class of universality. The theoretical scaling fields are postulated to be analytical combinations of the physical fields, pressure and temperature. The equation of state enables us to accurately locate the "Widom line" (the locus of stability minima) and determine that the critical pressure is considerably lower than predicted by computer simulations.

M. A. Anisimov; D. A. Fuentevilla

2006-09-19T23:59:59.000Z

33

Local Structure Analysis in $Ab$ $Initio$ Liquid Water  

E-Print Network [OSTI]

Within the framework of density functional theory, the inclusion of exact exchange and non-local van der Waals/dispersion (vdW) interactions is crucial for predicting a microscopic structure of ambient liquid water that quantitatively agrees with experiment. In this work, we have used the local structure index (LSI) order parameter to analyze the local structure in such highly accurate $ab$ $initio$ liquid water. At ambient conditions, the LSI probability distribution, P($I$), was unimodal with most water molecules characterized by more disordered high-density-like local environments. With thermal excitations removed, the resultant bimodal P($I$) in the inherent potential energy surface (IPES) exhibited a 3:1 ratio between high- and low-density-like molecules, with the latter forming small connected clusters amid the predominant population. By considering the spatial correlations and hydrogen bond network topologies $among$ water molecules with the same LSI identities, we demonstrate that the signatures of th...

Santra, Biswajit; Martelli, Fausto; Car, Roberto

2015-01-01T23:59:59.000Z

34

Soil Water Retention Measurements Using a Combined Tensiometer-Coiled Time Domain Reflectometry Probe  

E-Print Network [OSTI]

Soil Water Retention Measurements Using a Combined Tensiometer-Coiled Time Domain Reflectometry al., 1975; Arya et al.,that can be used to determine soil water retention curves in both 1975; Royer of a standard tensiometer. The combined tensiometer-coiled TDR probe was con- of soil water retention curves

Wildenschild, Dorthe

35

Water dynamics: dependence on local structure probed with vibrational echo correlation spectroscopy  

E-Print Network [OSTI]

Water dynamics: dependence on local structure probed with vibrational echo correlation spectroscopy­D stretching band of HOD in H2O and molecular dynamics simulations are employed to investigate water dynamics. The wavelength dependence of the measured dynamics demonstrates that different hydrogen bonded water species

Fayer, Michael D.

36

Probing the hydrogen-bond network of water via time-resolved soft x-ray spectroscopy  

SciTech Connect (OSTI)

We report time-resolved studies of hydrogen bonding in liquid H2O, in response to direct excitation of the O-H stretch mode at 3 mu m, probed via soft x-ray absorption spectroscopy at the oxygen K-edge. This approach employs a newly developed nanofluidic cell for transient soft x-ray spectroscopy in liquid phase. Distinct changes in the near-edge spectral region (XANES) are observed, and are indicative of a transient temperature rise of 10K following transient laser excitation and rapid thermalization of vibrational energy. The rapid heating occurs at constant volume and the associated increase in internal pressure, estimated to be 8MPa, is manifest by distinct spectral changes that differ from those induced by temperature alone. We conclude that the near-edge spectral shape of the oxygen K-edge is a sensitive probe of internal pressure, opening new possibilities for testing the validity of water models and providing new insight into the nature of hydrogen bonding in water.

Huse, Nils; Wen, Haidan; Nordlund, Dennis; Szilagyi, Erzsi; Daranciang, Dan; Miller, Timothy A.; Nilsson, Anders; Schoenlein, Robert W.; Lindenberg, Aaron M.

2009-04-24T23:59:59.000Z

37

Pore-scale simulation of liquid CO2 displacement of water using...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model. Pore-scale simulation of liquid CO2 displacement of water using a two-phase...

38

Liquid-liquid equilibrium of cyclohexane-n-hexane-methanol mixtures; Effect of water content  

SciTech Connect (OSTI)

Experimental liquid-liquid equilibrium data for the ternary system cyclohexane-n-hexane-methanol and for the binary systems n-hexane-methanol and cyclohexane-methanol are presented over a temperature range from 284 to 298{Kappa} at pressure of 0.1 MPa. Attention is given to the effect of the purity of methanol as far as the water content is concerned. The data are correlated by means of excess Gibbs energy models (NRTL and UNIQUAC), and the binary interaction parameters are reported.

Alessi, P.; Fermeglia, M.; Kikic, I. (Istituto di Chimica Applicata e Industriale, University of Trieste, via Valerio 2, I-34127 Trieste (IT))

1989-04-01T23:59:59.000Z

39

VAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE FROM  

E-Print Network [OSTI]

(for water: the SPC-, SPC/E-, and TIP4P-potential models; for carbon dioxide: the EPM2 potential model dioxide are calculated. For water, the SPC- and TIP4P-models give superior results for the vapor pressure when compared to the SPC/E-model. The vapor liquid equilibrium of the binary mixture carbon dioxide

40

Probes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - SeptemberMicroneedles for4-16 FORPoints of Contact Privacy Points ofPrivateProbes

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Probing the Interaction of Amorphous Solid Water on a Hydrophobic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Surface: Dewetting and Crystallization Kinetics of ASW on Abstract: Desorption of carbon tetrachloride from beneath an amorphous solid water (ASW) overlayer is explored...

42

Gas-Liquid Coexistence in the Primitive Model for Water  

E-Print Network [OSTI]

We evaluate the location of the gas-liquid coexistence line and of the associated critical point for the primitive model for water (PMW), introduced by Kolafa and Nezbeda [J. Kolafa and I. Nezbeda, Mol. Phys. 61, 161 (1987)]. Besides being a simple model for a molecular network forming liquid, the PMW is representative of patchy proteins and novel colloidal particles interacting with localized directional short-range attractions. We show that the gas-liquid phase separation is metastable, i.e. it takes place in the region of the phase diagram where the crystal phase is thermodynamically favored, as in the case of articles interacting via short-range attractive spherical potentials. Differently from spherical potentials, we do not observe crystallization close to the critical point. The region of gas-liquid instability of this patchy model is significantly reduced as compared to equivalent models of spherically interacting particles, confirming the possibility of observing kinetic arrest in an homogeneous sample driven by bonding as opposed to packing.

F. Romano; P. Tartaglia; F. Sciortino

2007-05-08T23:59:59.000Z

43

Water clusters: Untangling the mysteries of the liquid, one molecule at a time  

E-Print Network [OSTI]

to accurately calculate the properties of liquid water (e.g., heat capacity, density, dielectric constantWater clusters: Untangling the mysteries of the liquid, one molecule at a time Frank N. Keutsch- ative hydrogen bonding and promises to lead to a more complete molecular description of the liquid

Cohen, Ronald C.

44

Liquid-liquid equilibria of the ternary system water + acetic acid + 2-methyl-2-butanol  

SciTech Connect (OSTI)

Liquid-liquid equilibria for the ternary system water + acetic acid + 2-methyl-2-butanol were measured over a temperature range of (288 to 323) K. The results were used to estimate the interaction parameters between each of the three compounds for the NRTL and UNIQUAC models and between each of the main groups of H{sub 2}O, CH{sub 2} (paraffinic CH{sub 2}), OH, and COOH for the UJNIFAC model as a function of temperature. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the three models. The NRTL equation was the most accurate model in correlating the overall equilibrium compositions of the studied system. The UNIFAC model satisfactorily predicted the equilibrium compositions.

Fahim, M.A.; Al-Muhtaseb, S.A. [United Arab Emirates Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering] [United Arab Emirates Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering

1996-11-01T23:59:59.000Z

45

Liquid-liquid equilibria of the ternary system water + acetic acid + 1-hexanol  

SciTech Connect (OSTI)

The recovery of organic acids from dilute solutions resulting from fermentation processes is important and many solvents have been tried to improve such recovery. Liquid-liquid equilibria for the ternary system water + acetic acid + 1-hexanol were measured over a temperature range of (288 to 323) K. The results were used to estimate the interaction parameters between each of the three compounds for the NRTL and UNIQUAC models and between each of the main groups of H{sub 2}O, CH{sub 2} (paraffinic CH{sub 2}), OH, and COOH for the UNIFAC model as a function of temperature. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the three models. The NRTL equation was the most accurate model in correlating the overall equilibrium compositions of the studied system. The UNIQUAC and UNIFAC models satisfactorily predicted the equilibrium compositions.

Fahim, M.A. [Kuwait Univ., Safat (Kuwait). Dept. of Chemical Engineering] [Kuwait Univ., Safat (Kuwait). Dept. of Chemical Engineering; Al-Muhtaseb, S.A.; Al-Nashef, I.M. [U.A.E. Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering] [U.A.E. Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering

1997-01-01T23:59:59.000Z

46

Spin states of para-water and ortho-water molecule in gas and liquid phases  

E-Print Network [OSTI]

Spin degrees of freedom of water molecule in gas and liquid state were investigated in order to provide a reasonable answer about the unsolved problem of a long-term behavior of water spin isomers. The approach used involves an assumption that molecules change their spin state from a pure state to a mixed one when they interact with some sorts of adsorbent surface. Some models and conceptions of the quantum information processing were used.

V. K. Konyukhov

2009-09-23T23:59:59.000Z

47

Direct Analysis of Reversed-Phase HPTLC Separated Tryptic Protein Digests using a Liquid Microjunction Surface Sampling Probe/ESI-MS System  

SciTech Connect (OSTI)

The sampling, ionization and detection of tryptic peptides separated in one-dimension on reversed phase HPTLC plates was performed using liquid microjunction surface sampling probe electrospray ionization mass spectrometry. Tryptic digests of five proteins (cytochrome c., myoglobin, beta-casein, lysozyme, and bovine serum albumin) were spotted on reversed phase HPTLC RP-8 F254s and HPTLC RP-18 F254s plates. The plates were then developed using 70/30 methanol/water with 0.1 M ammonium acetate. A dual purpose extraction/electrospray solution containing 70/30/0.1 water/methanol/formic acid was infused through the sampling probe during analysis of the developed lanes. Both full scan mass spectra and data dependent tandem mass spectra were acquired for each development lane to detect and verify the peptide distributions. Data dependent tandem mass spectra provided both protein identification and sequence coverage information. Highest sequence coverages were achieved for cytochrome c. and myoglobin (62.5% and 58.3%, respectively) on reversed phase RP-8 plates. While the tryptic peptides were separated enough for identification, the peptide bands did show some overlap with most peptides located in the lower half of the development lane. Proteins whose peptides were more separated gave higher sequence coverage. Larger proteins such as beta-casein and BSA which were spotted in lower relative amounts gave much lower sequence coverage than the smaller proteins.

Emory, Joshua F [ORNL; Walworth, Matthew J [ORNL; Van Berkel, Gary J [ORNL; Schulz, Michael [Merck Research Laboratories; Minarik, susanne [Merck Research Laboratories

2010-01-01T23:59:59.000Z

48

Reference Correlations for Thermophysical Properties of Liquid Water Jaroslav Ptek, Jan Hrub,a...  

E-Print Network [OSTI]

of sound , viscosity, thermal con- ductivity, and static dielectric constant of liquid water as a function capacity; speed of sound; thermal conductivity; ther- modynamic properties; viscosity; water. CONTENTS 1Reference Correlations for Thermophysical Properties of Liquid Water at 0.1 MPa Jaroslav Pátek, Jan

Magee, Joseph W.

49

Combustion of Nano-Aluminum and Liquid Water G.A. Risha, S.F. Son  

E-Print Network [OSTI]

1 Combustion of Nano-Aluminum and Liquid Water G.A. Risha, S.F. Son , R.A. Yetter, V. Yang, and B: Supplemental materials submitted #12;2 Combustion of Nano-Aluminum and Liquid Water G.A. Risha, S.F. Son, R of nano-aluminum (nAl) and liquid water has been conducted. In particular, linear and mass-burning rates

Yang, Vigor

50

Electrokinetic Hydrogen Generation from Liquid WaterMicrojets  

SciTech Connect (OSTI)

We describe a method for generating molecular hydrogen directly from the charge separation effected via rapid flow of liquid water through a metal orifice, wherein the input energy is the hydrostatic pressure times the volume flow rate. Both electrokinetic currents and hydrogen production rates are shown to follow simple equations derived from the overlap of the fluid velocity gradient and the anisotropic charge distribution resulting from selective adsorption of hydroxide ions to the nozzle surface. Pressure-driven fluid flow shears away the charge balancing hydronium ions from the diffuse double layer and carries them out of the aperture. Downstream neutralization of the excess protons at a grounded target electrode produces gaseous hydrogen molecules. The hydrogen production efficiency is currently very low (ca. 10-6) for a single cylindrical jet, but can be improved with design changes.

Duffin, Andrew M.; Saykally, Richard J.

2007-05-31T23:59:59.000Z

51

Isobaric vapor-liquid equilibria for methanol + ethanol + water and the three constituent binary systems  

SciTech Connect (OSTI)

Vapor-liquid equilibrium data for methanol + ethanol + water and its three constituent binary systems methanol + ethanol, ethanol + water, and methanol + water were measured at 101.3 kPa using a liquid-vapor ebullition-type equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system methanol + ethanol + water was predicted by means of the binary NRTL parameters with good accuracy.

Kurihara, Kiyofumi; Nakamichi, Mikiyoshi; Kojima, Kazuo (Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry)

1993-07-01T23:59:59.000Z

52

Network analysis of proton transfer in liquid water  

SciTech Connect (OSTI)

Proton transfer in macromolecular systems is a fascinating yet elusive process. In the last ten years, molecular simulations have shown to be a useful tool to unveil the atomistic mechanism. Notwithstanding, the large number of degrees of freedom involved make the accurate description of the process very hard even for the case of proton diffusion in bulk water. Here, multi-state empirical valence bond molecular dynamics simulations in conjunction with complex network analysis are applied to study proton transfer in liquid water. Making use of a transition network formalism, this approach takes into account the time evolution of several coordinates simultaneously. Our results provide evidence for a strong dependence of proton transfer on the length of the hydrogen bond solvating the Zundel complex, with proton transfer enhancement as shorter bonds are formed at the acceptor site. We identify six major states (nodes) on the network leading from the “special pair” to a more symmetric Zundel complex required for transferring the proton. Moreover, the second solvation shell specifically rearranges to promote the transfer, reiterating the idea that solvation beyond the first shell of the Zundel complex plays a crucial role in the process.

Shevchuk, Roman; Rao, Francesco, E-mail: francesco.rao@frias.uni-freiburg.de [Freiburg Institute for Advanced Studies, School of Soft Matter Research, Freiburg im Breisgau (Germany); Agmon, Noam [Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem (Israel)

2014-06-28T23:59:59.000Z

53

On the Fluctuations that Order and Frustrate Liquid Water  

E-Print Network [OSTI]

of supercooled water and heavy water. Science, 181:342–344,Density hysteresis of heavy water confined in a nanoporous

Limmer, David

2013-01-01T23:59:59.000Z

54

Liquid-liquid phase transition model incorporating evidence for ferroelectric state near the lambda-point anomaly in supercooled water  

E-Print Network [OSTI]

We propose a unified model combining the first-order liquid-liquid and the second-order ferroelectric phase transitions models and explaining various features of the $\\lambda$-point of liquid water within a single theoretical framework. It becomes clear within the proposed model that not only does the long-range dipole-dipole interaction of water molecules yield a large value of dielectric constant $\\epsilon$ at room temperatures, our analysis shows that the large dipole moment of the water molecules also leads to a ferroelectric phase transition at a temperature close to the lambda-point. Our more refined model suggests that the phase transition occurs only in the low density component of the liquid and is the origin of the singularity of the dielectric constant recently observed in experiments with supercooled liquid water at temperature T~233K. This combined model agrees well with nearly every available set of experiments and explains most of the well-known and even recently obtained results of MD simulations.

Peter O. Fedichev; Leonid I. Menshikov

2012-01-30T23:59:59.000Z

55

Analysis of liquified coal for nitrogenous bases; separation by high performance liquid chromatography and identification by probe microdistillation/mass spectrometry  

E-Print Network [OSTI]

ANALYSIS OF LIQUIFIED COAL FOR NITROGENOUS BASES; SEPARATION BY HIGH PERFORMANCE LIQUID CHROMATOGRAPHY AND IDENTIFICATION BY PROBE MICRODISTILLATION/MASS SPECTROMETRY A Thesis by LEONARD ROYCE SCHRONK Submitted to the Graduate College... AND IDENTIFICATION BY PROBE MICRODISTILLATION/MASS SPECTROMETRY A Thesis by LEONARD ROYCE SCHRONK Approved as to style and content by: Co-Charrman o Commlxtte ) (Co-Chazrman o Committee Me er Hea of Department December 1978 ABSTRACT Analysis of Liquified...

Schronk, Leonard Royce

1978-01-01T23:59:59.000Z

56

MODELING OF LIQUID WATER ON CM PARENT BODIES AND IMPLICATIONS FOR AMINO ACID RACEMIZATION. B. A. Cohen  

E-Print Network [OSTI]

the most recent tem- perature-dependent expressions for thermal conductiv- ity, heat capacity, densityMODELING OF LIQUID WATER ON CM PARENT BODIES AND IMPLICATIONS FOR AMINO ACID RACEMIZATION. B. A and duration of a liquid water phase [1]. The characteris- tics of the liquid water phase are critical

Cohen, Barbara Anne

57

Long time fluctuation of liquid water: l/f spectrum of energy fluctuation in hydrogen bond network rearrangement dynamics  

E-Print Network [OSTI]

Long time fluctuation of liquid water: l/f spectrum of energy fluctuation in hydrogen bond network of the potential energy fluctuation of liquid water is examined and found to yield so-called l/f frequency of hydrogen bond network relaxations in liquid water. A simple model of cellular dynamics is proposed

Ramaswamy, Ram

58

Water-saving liquid-gas conditioning system  

DOE Patents [OSTI]

A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

Martin, Christopher; Zhuang, Ye

2014-01-14T23:59:59.000Z

59

Probing the Earth's interior with a large-volume liquid scintillator detector  

E-Print Network [OSTI]

A future large-volume liquid scintillator detector would provide a high-statistics measurement of terrestrial antineutrinos originating from $\\beta$-decays of the uranium and thorium chains. In addition, the forward displacement of the neutron in the detection reaction $\\bar\

Kathrin A. Hochmuth; Franz v. Feilitzsch; Brian D. Fields; Teresa Marrodan Undagoitia; Lothar Oberauer; Walter Potzel; Georg G. Raffelt; Michael Wurm

2006-10-04T23:59:59.000Z

60

Neutron scattering as a probe of liquid crystal polymer-reinforced composite materials  

SciTech Connect (OSTI)

This is the final report of a three-year Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This research project sought to obtain nanoscale and molecular level information on the mechanism of reinforcement in liquid crystal polymer (LCP)-reinforced composites, to realize molecular-reinforced LCP composites, and to test the validity of the concept of molecular reinforcement. Small-angle neutron scattering was used to study the structures in the ternary phase diagram of LCP with liquid crystal thermosets and solvent on length scales ranging from 1-100 nm. The goal of the scattering measurements is to understand the phase morphology and degree of segregation of the reinforcing and matrix components. This information helps elucidate the physics of self assembly in these systems. This work provides an experimental basis for a microengineering approach to composites of vastly improved properties.

Hjelm, R.P.; Douglas, E.P.; Benicewicz, B.C.; Langlois, D.A.

1995-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Absorption Spectra and Photolysis of Methyl Peroxide in Liquid and Frozen Water  

E-Print Network [OSTI]

, University of California, Irvine, California 92697, United States Department of Physical Chemistry with low temperatures, in the presence of clouds with a high liquid-water content and large solar zenith

Nizkorodov, Sergey

62

Ab initio calculation of the electronic absorption spectrum of liquid water  

SciTech Connect (OSTI)

The electronic absorption spectrum of liquid water was investigated by coupling a one-body energy decomposition scheme to configurations generated by classical and Born-Oppenheimer Molecular Dynamics (BOMD). A Frenkel exciton Hamiltonian formalism was adopted and the excitation energies in the liquid phase were calculated with the equation of motion coupled cluster with single and double excitations method. Molecular dynamics configurations were generated by different approaches. Classical MD were carried out with the TIP4P-Ew and AMOEBA force fields. The BLYP and BLYP-D3 exchange-correlation functionals were used in BOMD. Theoretical and experimental results for the electronic absorption spectrum of liquid water are in good agreement. Emphasis is placed on the relationship between the structure of liquid water predicted by the different models and the electronic absorption spectrum. The theoretical gas to liquid phase blue-shift of the peak positions of the electronic absorption spectrum is in good agreement with experiment. The overall shift is determined by a competition between the O–H stretching of the water monomer in liquid water that leads to a red-shift and polarization effects that induce a blue-shift. The results illustrate the importance of coupling many-body energy decomposition schemes to molecular dynamics configurations to carry out ab initio calculations of the electronic properties in liquid phase.

Martiniano, Hugo F. M. C.; Galamba, Nuno [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal)] [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Cabral, Benedito J. Costa, E-mail: ben@cii.fc.ul.pt [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal) [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa (Portugal); Instituto de Física da Universidade de São Paulo, CP 66318, 05314-970 São Paulo, SP (Brazil)

2014-04-28T23:59:59.000Z

63

Polymer formulation for removing hydrogen and liquid water from an enclosed space  

DOE Patents [OSTI]

This invention describes a solution to the particular problem of liquid water formation in hydrogen getters exposed to quantities of oxygen. Water formation is usually desired because the recombination reaction removes hydrogen without affecting gettering capacity and the oxygen removal reduces the chances for a hydrogen explosion once free oxygen is essentially removed. The present invention describes a getter incorporating a polyacrylate compound that can absorb up to 500% of its own weight in liquid water without significantly affecting its hydrogen gettering/recombination properties, but that also is insensitive to water vapor.

Shepodd, Timothy J. (Livermore, CA)

2006-02-21T23:59:59.000Z

64

Nuclear tanker producing liquid fuels from air and water  

E-Print Network [OSTI]

Emerging technologies in CO? air capture, high temperature electrolysis, microchannel catalytic conversion, and Generation IV reactor plant systems have the potential to create a shipboard liquid fuel production system ...

Galle-Bishop, John Michael

2011-01-01T23:59:59.000Z

65

Probing Liquid Surfaces under Vacuum Using SEM and TOF-SIMS. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - SeptemberMicroneedles for4-16 FORPoints of ContactLiquid Surfaces under Vacuum

66

Simultaneous photon absorption as a probe of molecular interaction and hydrogen-bond correlation in liquids  

E-Print Network [OSTI]

We have investigated the simultaneous absorption of near-infrared photons by pairs of neighboring molecules in liquid methanol. Simultaneous absorption by two OH-stretching modes is found to occur at an energy higher than the sum of the two absorbing modes. This frequency shift arises from interaction between the modes, and its value has been used to determine the average coupling between neighboring methanol molecules. We find a rms coupling strength of 46+/-1 cm-1, much larger than can be explained from transition-dipole coupling, suggesting that hydrogen-bond mediated interactions between neighboring molecules play an important role in liquid methanol. The most important aspect of simultaneous vibrational absorption is that it allows for a quantitative investigation of hydrogen-bond cooperativity. We derive the extent to which the hydrogen-bond strengths of neighboring molecules are correlated by comparing the line shape of the absorption band caused by simultaneous absorption with that of the fundamental transition. Surprisingly, neighboring hydrogen bonds in methanol are found to be strongly correlated, and from the data we obtain a hydrogen-bond correlation coefficient of 0.69+/-0.12.

Sander Woutersen

2007-03-06T23:59:59.000Z

67

Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water  

SciTech Connect (OSTI)

Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria, E-mail: Valeria.Molinero@utah.edu [Department of Chemistry, The University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850 (United States)

2014-11-14T23:59:59.000Z

68

A liquid water management strategy for PEM fuel cell stacks  

E-Print Network [OSTI]

Gas and water management are key to achieving good performance from a PEM fuel cell stack. Previous experimentation had found, and this experimentation confirms, that one very effective method of achieving proper gas and water management is the use...

Van Nguyen, Trung; Knobbe, M. W.

2003-02-25T23:59:59.000Z

69

Continuous Flow Liquid Microjunction Surface Sampling Probe Connected On-line with HPLC/MS for Spatially Resolved Analysis of Small Molecules and Proteins  

SciTech Connect (OSTI)

RATIONALE: A continuous flow liquid microjunction surface sampling probe extracts soluble material from surfaces for direct ionization and detection by MS. Demonstrated here is the on-line coupling of such a probe with HPLC/MS enabling extraction, separation and detection of small molecules and proteins from surfaces in a spatially resolved (~0.5 mm diameter spots) manner. Methods: A continuous flow liquid microjunction surface sampling probe was connected to a 6-port, 2-position valve for extract collection and injection to an HPLC column. A QTRAP 5500 hybrid triple quadrupole linear ion trap equipped with a Turbo V ion source operated in positive ESI mode was used for all experiments. System operation was tested with extraction, separation and detection of propranolol and associated metabolites from drug dosed tissues and proteins from dried sheep blood spots on paper. Results: Confirmed in the tissue were the parent drug and two different hydroxypropranolol glucuronides. The mass spectrometric response for these compounds from different locations in the liver showed an increase with increasing extraction time (5, 20 and 40 s extractions). For on-line separation and detection/identification of extracted proteins from dried sheep blood spots, two major protein peaks dominated the chromatogram and could be correlated with the expected masses for the hemoglobin and chains. Conclusions: Spatially resolved sampling, separation, and detection of small molecules and proteins from surfaces can be accomplished using a continuous flow liquid microjunction surface sampling probe coupled on-line with HPLC/MS detection.

Van Berkel, Gary J [ORNL; Kertesz, Vilmos [ORNL

2013-01-01T23:59:59.000Z

70

Liquid-liquid equilibria of the ternary systems water + acetic acid + ethyl acetate and water + acetic acid + isophorene (3,5,5-trimethyl-2-cyclohexen-1-one)  

SciTech Connect (OSTI)

Liquid-liquid equilibria for the ternary systems water + acetic acid + ethyl acetate and water + acetic acid + isophorone (3,5,5-trimethyl-2-cyclohexen-1-one) were measured over the temperature range (283 to 313) K. The results were used to estimate the interaction parameters between each of the three compounds of the systems studied for the NRTL and UNIQUAC models. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the two models; experimental data were successfully reproduced. The UNIQUAC model was the most accurate in correlating the overall equilibrium composition of the studied systems. Also the NRTL model satisfactorily predicted the equilibrium composition. Isophorone experimentally resulted in a better extraction capacity for acetic acid and in a lower miscibility with water.

Colombo, A.; Battilana, P.; Ragaini, V.; Bianchi, C.L. [Milan Univ. (Italy). Dept. of Physical Chemistry and Electrochemistry] [Milan Univ. (Italy). Dept. of Physical Chemistry and Electrochemistry; Carvoli, G. [Chemial S.p.A., Cavaglia (Italy)] [Chemial S.p.A., Cavaglia (Italy)

1999-01-01T23:59:59.000Z

71

Liquid Water Dynamics in a Model Polymer Electrolyte Fuel Cell Flow Channel  

E-Print Network [OSTI]

Liquid Water Dynamics in a Model Polymer Electrolyte Fuel Cell Flow Channel by Chris Miller in a Model Polymer Electrolyte Fuel Cell Flow Channel by Chris Miller Bachelors of Engineering, University in a polymer electrolyte fuel cell is a critical issue in ensuring high cell performance. The water production

Victoria, University of

72

Short-range precipitation forecasts using assimilation of simulated satellite water vapor profiles and column cloud liquid water amounts  

SciTech Connect (OSTI)

These observing system simulation experiments investigate the assimilation of satellite-observed water vapor and cloud liquid water data in the initialization of a limited-area primitive equations model with the goal of improving short-range precipitation forecasts. The assimilation procedure presented includes two aspects: specification of an initial cloud liquid water vertical distribution and diabatic initialization. The satellite data is simulated for the next generation of polar-orbiting satellite instruments, the Advanced Microwave Sounding Unit (AMSU) and the High-Resolution Infrared Sounder (HIRS), which are scheduled to be launched on the NOAA-K satellite in the mid-1990s. Based on cloud-top height and total column cloud liquid water amounts simulated for satellite data a diagnostic method is used to specify an initial cloud water vertical distribution and to modify the initial moisture distribution in cloudy areas. Using a diabatic initialization procedure, the associated latent heating profiles are directly assimilated into the numerical model. The initial heating is estimated by time averaging the latent heat release from convective and large-scale condensation during the early forecast stage after insertion of satellite-observed temperature, water vapor, and cloud water formation.

Wu, X.; Diak, G.R.; Hayden, C.M.; Young, J.A. [Univ. of Wisconsin, Madison, WI (United States)] [Univ. of Wisconsin, Madison, WI (United States)

1995-02-01T23:59:59.000Z

73

REVIEW OF SCIENTIFIC INSTRUMENTS 82, 034904 (2011) Fiber optic probe hydrophone for the study of acoustic cavitation in water  

E-Print Network [OSTI]

of acoustic cavitation in water Arnaud Arvengas, Kristina Davitt, and Frédéric Caupina) Laboratoire de. Accord- ing to nucleation theory, increasing the ultrasound frequency increases the cavitation threshold in liquids. We are able to resolve the fractional change in the pressure threshold for cavitation in water

Davitt, Kristina

74

Liquid-liquid equilibria for water + ethanol + 2-methylpropyl ethanoate and water + ethanol + 1,2-dibromoethane at 298. 15 K  

SciTech Connect (OSTI)

Liquid-liquid equilibrium, distribution coefficients, and selectivities of the systems water + ethanol + 2-methylpropyl ethanoate or + 1,2-dibromoethane have been determined at 298.15 K in order to evaluate their suitability in preferentially extracting ethanol from aqueous solution. Tie-line data were satisfactorily correlated by the Othmer and Tobias method, and the plait point coordinates for the two systems were estimated. The experimental data was compared with the values calculated by the NRTL and UNIQUAC models. The water + ethanol + 2-methylpropyl ethanoate system was also compared with the values predicted by the UNIFAC model. Poor qualitative agreement was obtained with these models. From the experimental results, they can conclude that both solvents are inappropriate for ethanol extraction processes from aqueous solutions.

Solimo, H.N.; Barnes de Arreguez, N.G. (Univ. Nacional de Tucuman, San Miguel de Tucuman (Argentina). Inst. de Fisica)

1994-01-01T23:59:59.000Z

75

Heating-induced glass-glass and glass-liquid transformations in computer simulations of water  

SciTech Connect (OSTI)

Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T “phase diagram” for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related, both being associated with the limit of kinetic stability of LDA (HDA)

Chiu, Janet; Giovambattista, Nicolas [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States)] [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States); Starr, Francis W. [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)] [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)

2014-03-21T23:59:59.000Z

76

Gas-liquid-liquid equilibria in mixtures of water, light gases, and hydrocarbons  

SciTech Connect (OSTI)

Phase equilibrium in mixtures of water + light gases and water + heavy hydrocarbons has been investigated with the development of new local composition theory, new equations of state, and new experimental data. The preferential segregation and orientation of molecules due to different energies of molecular interaction has been simulated with square well molecules. Extensive simulation has been made for pure square well fluids and mixtures to find the local composition at wide ranges of states. A theory of local composition has been developed and an equation of state has been obtained for square well fluids. The new local composition theory has been embedded in several equations of state. The pressure of water is decoupled into a polar pressure and non-polar pressure according to the molecular model of water of Jorgensen et al. The polar pressure of water is combined with the BACK equation for the general description of polar fluids and their mixtures. Being derived from the steam table, the Augmented BACK equation is particularly suited for mixtures of water + non-polar substances such as the hydrocarbons. The hydrophobic character of the hydrocarbons had made their mixtures with water a special challenge. A new group contribution equation of state is developed to describe phase equilibrium and volumetric behavior of fluids while requiring only to know the molecular structure of the components. 15 refs., 1 fig.

Chao, K.C.

1990-01-01T23:59:59.000Z

77

Vapor-liquid equilibria of the water + 1,3-propanediol and water + 1,3-propanediol + lithium bromide systems  

SciTech Connect (OSTI)

Vapor-liquid equilibrium data of the water + 1,3-propanediol and water + 1,3-propanediol + lithium bromide systems were measured at 60, 160, 300, and 760 mmHg at temperatures ranging from 315 to 488 K. The apparatus used in this work is a modified still especially designed for the measurement of low-pressure VLE, in which both liquid and vapor are continuously recirculated. For the analysis of salt-containing solutions, a method incorporating refractometry and gravimetry was used. From the experimental measurements, the effect of lithium bromide on the VLE behavior of water + 1,3-propanediol was investigated. The experimental data of the salt-free system were successfully correlated using the Wilson, NRTL, and UNIQUAC models. In addition, the extended UNIQUAC model of Sander et al. was applied to the VLE calculation of salt-containing mixtures.

Mun, S.Y.; Lee, H.

1999-12-01T23:59:59.000Z

78

Remote sensing of total integrated water vapor, wind speed, and cloud liquid water over the ocean using the Special Sensor Microwave/Imager (SSM/I)  

E-Print Network [OSTI]

A modified D-matrix retrieval method is the basis of the refined total integrated water vapor (TIWV), total integrated cloud liquid water (CLW), and surface wind speed (WS) retrieval methods that are developed. The 85 GHZ polarization difference...

Manning, Norman Willis William

2012-06-07T23:59:59.000Z

79

Nuclear quantum effects in liquid water from path-integral simulations using an ab initio force matching approach  

E-Print Network [OSTI]

We have applied path integral simulations, in combination with new ab initio based water potentials, to investigate nuclear quantum effects in liquid water. Because direct ab initio path integral simulations are computationally expensive, a flexible water model is parameterized by force-matching to density functional theory-based molecular dynamics simulations. The resulting effective potentials provide an inexpensive replacement for direct ab inito molecular dynamics simulations and allow efficient simulation of nuclear quantum effects. Static and dynamic properties of liquid water at ambient conditions are presented and the role of nuclear quantum effects, exchange-correlation functionals and dispersion corrections are discussed in regards to reproducing the experimental properties of liquid water.

Thomas Spura; Christopher John; Scott Habershon; Thomas D. Kühne

2014-02-06T23:59:59.000Z

80

Optical Kerr effect of liquid and supercooled water: the experimental and data analysis perspective  

E-Print Network [OSTI]

The time-resolved optical Kerr effect spectroscopy (OKE) is a powerful experimental tool enabling accurate investigations of the dynamic phenomena in molecular liquids. We introduced innovative experimental and fitting procedures, that permit a safe deconvolution of sample response function from the instrumental function. This is a critical issue in order to measure the dynamics of sample presenting weak signal, e.g. liquid water. We report OKE data on water measuring intermolecular vibrations and the structural relaxation processes in an extended temperature range, inclusive of the supercooled states. The unpreceded data quality makes possible a solid comparison with few theoretical models; the multi-mode Brownian oscillator model, the Kubo's discrete random jump model and the schematic mode-coupling model. All these models produce reasonable good fits of the OKE data of stable liquid water, i.e. over the freezing point. The features of water dynamics in the OKE data becomes unambiguous only at lower temperatures, i.e. for water in the metastable supercooled phase. Hence this data enable a valid comparison between the model fits. We found that the schematic mode-coupling model provides the more rigorous and complete model for water dynamics, even if is intrinsic hydrodynamic approach hide the molecular information.

A. Taschin; P. Bartolini; R. Eramo; R. Righini; R. Torre

2014-06-20T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Electrokinetic Hydrogen Generation from Liquid Water Microjets Andrew M. Duffin and Richard J. Saykally,*  

E-Print Network [OSTI]

of natural gas. These thermal methods are relatively cheap, but they do not mitigate difficulties associatedElectrokinetic Hydrogen Generation from Liquid Water Microjets Andrew M. Duffin and Richard J, 2007; In Final Form: May 31, 2007 We describe a method for generating molecular hydrogen directly from

Cohen, Ronald C.

82

Life in the Solar System Assume we need energy, liquid water, and organic materials.  

E-Print Network [OSTI]

high pressure, no sunlight, high temperature. Not much chance of life there. Gas Giants #12;The moonsLife in the Solar System Assume we need energy, liquid water, and organic materials. #12;Size N2 Titan Thick atmo Thick atmo Thin atmo #12;Small rocky bodies are unlikely to host life: too hot

Shirley, Yancy

83

The Role of Confined Water in Ionic Liquid Electrolytes for Dye-Sensitized Solar Cells  

E-Print Network [OSTI]

The Role of Confined Water in Ionic Liquid Electrolytes for Dye- Sensitized Solar Cells Jiwon Jeon %) for applications such as nonvolatile electrolytes for dye-sensitized solar cells (DSSCs). This suggests a strategy Structure, Quantum Chemistry,General Theory The dye-sensitized solar cell (DSSC) proposed by Gratzel et al.1

Goddard III, William A.

84

Pulse radiolysis of liquid water using picosecond electron pulses produced by a table-top terawatt laser system  

E-Print Network [OSTI]

Pulse radiolysis of liquid water using picosecond electron pulses produced by a table-top terawatt into a supersonic helium gas jet are used to ionize liquid water. The decay of the hydrated electrons produced electron generator is shown, for the first time, to produce sufficient charge to conduct time resolved

Umstadter, Donald

85

HIGH TEMPERATURE CONDUCTIVITY PROBE FOR MONITORING CONTAMINATION LEVELS IN POWER PLANT BOILER WATER.  

E-Print Network [OSTI]

??A high temperature/high pressure flow through probe was designed to measure high temperature electrical conductivity of aqueous (aq) dilute electrolyte solutions, an application which can… (more)

Hipple, Sarah

2008-01-01T23:59:59.000Z

86

Molecular Density Functional Theory for water with liquid-gas coexistence and correct pressure  

E-Print Network [OSTI]

The solvation of hydrophobic solutes in water is special because liquid and gas are almost at coexistence. In the common hypernetted chain approximation to integral equations, or equivalently in the homogenous reference fluid of molecular density functional theory, coexistence is not taken into account. Hydration structures and energies of nanometer-scale hydrophobic solutes are thus incorrect. In this article, we propose a bridge functional that corrects this thermodynamic inconsistency by introducing a metastable gas phase for the homogeneous solvent. We show how this can be done by a third order expansion of the functional around the bulk liquid density that imposes the right pressure and the correct second order derivatives. Although this theory is not limited to water, we apply it to study hydrophobic solvation in water at room temperature and pressure and compare the results to all-atom simulations. With this correction, molecular density functional theory gives, at a modest computational cost, quantita...

Jeanmairet, Guillaume; Sergiievskyi, Volodymyr; Borgis, Daniel

2015-01-01T23:59:59.000Z

87

Effect of calcium nitrate on the vapor-liquid equilibria of ethanol + water and 2-propanol + water  

SciTech Connect (OSTI)

The effect of calcium nitrate on the vapor-liquid equilibria of ethanol + water and 2-propanol + water was studied using a Swietoslawski ebulliometer. The measurements were performed for two constant salt molalities (1 and 2 mol[center dot]kg[sup [minus]1]) under isobaric conditions at 50.66 kPa. Strong salting-out of the alcohol was observed in all cases, leading to a complete elimination of the azeotropic point at relatively low salt concentrations. The results were correlated using an extension of the NRTL equation for mixed solvent electrolyte systems proposed by Mock, Evans, and Chen.

Polka, H.M.; Gmehling, J. (Univ. of Oldenburg (Germany). Chair of Industrial Chemistry)

1994-07-01T23:59:59.000Z

88

Linking Europa's plume activity to tides, tectonics, and liquid water  

E-Print Network [OSTI]

Much of the geologic activity preserved on Europa's icy surface has been attributed to tidal deformation, mainly due to Europa's eccentric orbit. Although the surface is geologically young (30 - 80 Myr), there is little information as to whether tidally-driven surface processes are ongoing. However, a recent detection of water vapor near Europa's south pole suggests that it may be geologically active. Initial observations indicated that Europa's plume eruptions are time-variable and may be linked to its tidal cycle. Saturn's moon, Enceladus, which shares many similar traits with Europa, displays tidally-modulated plume eruptions, which bolstered this interpretation. However, additional observations of Europa at the same time in its orbit failed to yield a plume detection, casting doubt on the tidal control hypothesis. The purpose of this study is to analyze the timing of plume eruptions within the context of Europa's tidal cycle to determine whether such a link exists and examine the inferred similarities and...

Rhoden, Alyssa R; Roth, Lorenz; Retherford, Kurt

2015-01-01T23:59:59.000Z

89

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for andFuel-Efficient Engines |Iron is theIs

90

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for andFuel-Efficient Engines |Iron is theIsIsotope and

91

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for andFuel-Efficient Engines |Iron is theIsIsotope

92

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for andFuel-Efficient Engines |Iron is

93

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/SurfacePump-Testing Sign InIsotope

94

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/SurfacePump-Testing Sign InIsotopeIsotope and

95

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/SurfacePump-Testing Sign InIsotopeIsotope andIsotope

96

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/SurfacePump-Testing Sign InIsotopeIsotope

97

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/SurfacePump-Testing Sign InIsotopeIsotopeIsotope and

98

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponsesIon/SurfacePump-Testing Sign InIsotopeIsotopeIsotope

99

A model of vapor-liquid equilibria for acid gas-alkanolamine-water systems  

SciTech Connect (OSTI)

A physico-chemical model was developed for representing liquid phase chemical equilibria and vapor-liquid (phase) equilibria of H{sub 2}SCO{sub 2}-alkanolamine-water systems. The equilibrium composition of the liquid phase is determined by minimization of the Gibbs free energy. Activity coefficients are represented with the Electrolyte-NRTL equation treating both long-range electrostatic interactions and short-range binary interactions between liquid phase species. Vapor phase fugacity coefficients are calculated using the Redlich-Kwong-Soave Equation of State. Adjustable parameters of the model, binary interaction parameters and carbamate stability constants, were fitted on published binary system alkanolamine-water and ternary system (H{sub 2}S-alkanolamine-water, CO{sub 2}-alkanolamine-water) VLE data. The Data Regression System of ASPEN PLUS, based upon the Maximum Likelihood Principle, was used to estimate adjustable parameters. Ternary system measurements used in parameter estimation ranged in temperature from 25 to 120{degree}C in alkanolamine concentration from 1 to 5 M, in acid gas loading from 0 to 1.5 moles per mole alkanolamine, and in acid gas partial pressure from 0.1 to 1,000 kPa. Maximum likelihood estimates of ternary system H{sub 2} or CO{sub 2} equilibrium partial pressures and liquid phase concentrations were found to be in good agreement with measurements for aqueous solutions of monoethanolamine (MEA), diethanolamine (DEA), diglycolamine (DGA), and methyldiethanolamine (MDEA) indicating that the model successfully represents ternary system data. The model was extended to represent CO{sub 2} solubility in aqueous mixtures of MDEA with MEA or DEA. The solubility was measured at 40 and 80{degree}C over a wide range of CO{sub 2} partial pressures. These measurements were used to estimate additional binary parameters of the mixed solvent systems.

Austgen, D.M. Jr.

1989-01-01T23:59:59.000Z

100

The Structure of Water in Crystalline Aluminophosphates: Isolated Water and Intermolecular Clusters Probed by Raman Spectroscopy, NMR and Structural Modeling  

E-Print Network [OSTI]

of water in different states, e.g., bulk water, water clusters, aqueous solutions of ions or organicThe Structure of Water in Crystalline Aluminophosphates: Isolated Water and Intermolecular Clusters are used to elucidate the properties of water in Metavariscite, AlPO4-H3, AlPO4-8 and VPI-5. The framework

Goddard III, William A.

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Capillary filling with giant liquid/solid slip: dynamics of water uptake by carbon nanotubes  

E-Print Network [OSTI]

This article discusses the way the standard description of capillary filling dynamics has to be modified to account for liquid/solid slip in nanometric pores. It focuses in particular on the case of a large slip length compared to the pore size. It is shown that the liquid viscosity does not play a role, and that the flow is only controlled by the friction coefficient of the liquid at the wall. Moreover in the Washburn regime, the filling velocity does not depend on the tube radius. Finally, molecular dynamics simulations suggest that this standard description fails to describe the early stage of capillary filling of carbon nanotubes by water, since viscous dissipation at the tube entrance must be taken into account.

Laurent Joly

2011-12-06T23:59:59.000Z

102

Liquid-Water Uptake and Removal in PEM Fuel-Cell Components  

SciTech Connect (OSTI)

Management of liquid water is critical for optimal fuel-cell operation, especially at low temperatures. It is therefore important to understand the wetting properties and water holdup of the various fuel-cell layers. While the gas-diffusion layer is relatively hydrophobic and exhibits a strong intermediate wettability, the catalyst layer is predominantly hydrophilic. In addition, the water content of the ionomer in the catalyst layer is lower than that of the bulk membrane, and is affected by platinum surfaces. Liquid-water removal occurs through droplets on the surface of the gas-diffusion layer. In order to predict droplet instability and detachment, a force balance is used. While the pressure or drag force on the droplet can be derived, the adhesion or surface-tension force requires measurement using a sliding-angle approach. It is shown that droplets produced by forcing water through the gas-diffusion layer rather than placing them on top of it show much stronger adhesion forces owing to the contact to the subsurface water.

Das, Prodip K.; Gunterman, Haluna P.; Kwong, Anthony; Weber, Adam Z.

2011-09-23T23:59:59.000Z

103

A focused liquid jet formed by a water hammer in a test tube  

E-Print Network [OSTI]

We investigate motion of a gas-liquid interface in a test tube induced by a large acceleration via impulsive force. We conduct simple experiments in which the tube partially filled with a liquid falls under gravity and impacts a rigid floor. A curved gas-liquid interface inside the tube reverses and eventually forms an elongated jet (i.e. the so-called a focused jet). In our experiments, there arises either vibration of the interface or increment in the velocity of a liquid jet accompanied by the onset of cavitation in the liquid column. These phenomena cannot be explained by considering pressure impulse in a classical potential flow analysis, which does not account for finite speeds of sound as well as phase change. Here we model such water-hammer events as a result of one-dimensional pressure wave propagation and its interaction with boundaries through acoustic impedance mismatching. The method of characteristics is applied to describe pressure wave interactions and the subsequent cavitation. The proposed m...

Kiyama, Akihito; Ando, Keita; Kameda, Masaharu

2015-01-01T23:59:59.000Z

104

Ab-initio molecular dynamics simulation of liquid water by Quantum Monte Carlo  

E-Print Network [OSTI]

Despite liquid water is ubiquitous in chemical reactions at roots of life and climate on earth, the prediction of its properties by high-level ab initio molecular dynamics simulations still represents a formidable task for quantum chemistry. In this article we present a room temperature simulation of liquid water based on the potential energy surface obtained by a many-body wave function through quantum Monte Carlo (QMC) methods. The simulated properties are in excellent agreement with recent neutron scattering and X-ray experiments, particularly concerning the position of the oxygen-oxygen peak in the radial distribution function, at variance of previous Density Functional Theory attempts. Given the excellent performances of QMC on large scale supercomputers, this work opens new perspectives for predictive and reliable ab-initio simulations of complex chemical systems.

Andrea Zen; Ye Luo; Guglielmo Mazzola; Leonardo Guidoni; Sandro Sorella

2014-12-09T23:59:59.000Z

105

Three-dimensional effects of liquid water flooding in the cathode of a PEM fuel cell  

E-Print Network [OSTI]

. Researchers all over the world are focusing on optimizing this system to be cost competitive with energy conversion devices currently available. It is a well known fact that the cathode of the PEM fuel cell is the performance limiting component due...THREE DIMENSIONAL EFFECTS OF LIQUID WATER FLOODING IN THE CATHODE OF A PEM FUEL CELL by Dilip Natarajan and Trung Van Nguyen* Department of Chemical and Petroleum Engineering University of Kansas Lawrence, KS 66045, USA Submitted...

Natarajan, Dilip; Van Nguyen, Trung

2003-03-27T23:59:59.000Z

106

Analysis and Calibration of CRF Raman Lidar Cloud Liquid Water Measurements  

SciTech Connect (OSTI)

The Atmospheric Radiation Measurement (ARM) Raman lidar (RL), located at the Southern Great Plains (SGP) Climate Research Facility (CRF), is a unique state-of-the-art active remote sensor that is able to measure profiles of water vapor, aerosol, and cloud properties at high temporal and vertical resolution throughout the diurnal cycle. In October 2005, the capability of the RL was extended by the addition of a new detection channel that is sensitive to the Raman scattering of liquid water. This new channel permits the system, in theory, to measure profiles of liquid water content (LWC) by the RL. To our knowledge, the ARM RL is the only operation lidar with this capability. The liquid water Raman backscattering cross-section is a relatively weak and spectrally broad feature, relative to the water vapor Raman backscatter signal. The wide bandpass required to achieve reasonable signal-to-noise in the liquid water channel essentially eliminates the ability to measure LWC profiles during the daytime in the presence of large solar background, and thus all LWC observations are nighttime only. Additionally, the wide bandpass increases the probability that other undesirable signals, such as fluorescence from aerosols, may contaminate the observation. The liquid water Raman cross-section has a small amount of overlap with the water vapor Raman cross-section, and thus there will be a small amount of ‘cross-talk’ between the two signals, with water vapor contributing a small amount of signal to the LWC observation. And finally, there is significant uncertainty in the actual strength of the liquid water Raman cross-section in the literature. The calibrated LWC profiles, together with the coincident cloud backscatter observations also made by the RL, can be used to derive profiles of cloud droplet effective radius. By combining these profiles of effective radius in the lower portion of the cloud with the aerosol extinction measurements made below the cloud by the RL, the first aerosol indirect effect can be investigated using a single instrument, thereby reducing the uncertainty associated with aligning the different sampling periods and fields of view of multiple instruments. We have applied a “first principles” calibration to the LWC profiles. This approach requires that the relative differences in optical efficiency between the water vapor and liquid water channels be known; this relative difference is easily computed using the efficiency values of the beam splitters and interference filters in the lidar that were provided by the vendors of these components. The first principles approach then transfers the calibration from the water vapor mixing ratio to the LWC using the difference in the optical efficiency and an interpolated value of the liquid water Raman cross section from the literature, and the better established water vapor Raman cross section. After accounting for all known error sources, the vertical integral of LWC was compared against a similar value retrieved from a co-located ground-based infrared radiometer. The RL and infrared radiometer have significantly different fields of view; thus to compare the two sensors the data were averaged to 5 min intervals where only cloudy samples were included in the average of each. While there is fair scatter in the data (r=0.47), there is also a clear indication of a positive correlation between the infrared and the RL values. The value of the slope of the regression is 0.49, which indicates a tendency of the RL measurements to underestimate the total liquid amount with respect to the infrared retrieval. Research continues to investigate the source of the bias, but the most likely candidate is the large uncertainty in the liquid water Raman cross-section as there have been no direct measurements made of this parameter at the lidar’s laser wavelength of 355 nm. The calibrated LWC profile was then used together with the cloud backscatter coefficient profile from the RL to derive profiles of cloud droplet effective radius and cloud droplet number density. These profiles o

Turner, D.D.

2007-10-31T23:59:59.000Z

107

Electronic structure effects in liquid water studied by photoelectron spectroscopy and density functional theory  

SciTech Connect (OSTI)

We present valence photoelectron emission spectra of liquid water in comparison with gas-phase water, ice close to the melting point, low temperature amorphous and crystalline ice. All aggregation states have major electronic structure changes relative to the free molecule, with rehybridization and development of bonding and anti-bonding states accompanying the hydrogen bond formation. Sensitivity to the local structural order, most prominent in the shape and splitting of the occupied 3a{sub 1} orbital, is understood from the electronic structure averaging over various geometrical structures, and reflects the local nature of the orbital interaction.

Nordlund, Dennis; Odelius, Michael; Bluhm, Hendrik; Ogasawara, Hirohito; Pettersson, Lars G.M.; Nilsson, Anders

2008-04-29T23:59:59.000Z

108

Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process  

SciTech Connect (OSTI)

Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

2011-10-16T23:59:59.000Z

109

Investigating the solid-liquid phase transition of water nanofilms using the generalized replica exchange method  

SciTech Connect (OSTI)

The generalized Replica Exchange Method (gREM) was applied to study a solid-liquid phase transition in a nanoconfined bilayer water system using the monatomic water (mW) model. Exploiting optimally designed non-Boltzmann sampling weights with replica exchanges, gREM enables an effective sampling of configurations that are metastable or unstable in the canonical ensemble via successive unimodal energy distributions across phase transition regions, often characterized by S-loop or backbending in the statistical temperature. Extensive gREM simulations combined with Statistical Temperature Weighted Histogram Analysis Method (ST-WHAM) for nanoconfined mW water at various densities provide a comprehensive characterization of diverse thermodynamic and structural properties intrinsic to phase transitions. Graph representation of minimized structures of bilayer water systems determined by the basin-hopping global optimization revealed heterogeneous ice structures composed of pentagons, hexagons, and heptagons, consistent with an increasingly ordered solid phase with decreasing density. Apparent crossover from a first-order solid-liquid transition to a continuous one in nanoconfined mW water with increasing density of the system was observed in terms of a diminishing S-loop in the statistical temperature, smooth variation of internal energies and heat capacities, and a characteristic variation of lateral radial distribution functions, and transverse density profiles across transition regions.

Lu, Qing [Division of Materials Science and Engineering, Boston University, Brookline, Massachusetts 02446 (United States); Kim, Jaegil; Straub, John E., E-mail: straub@bu.edu [Department of Chemistry, Boston University, Boston, Massachusetts 02215 (United States); Farrell, James D.; Wales, David J. [University Chemical Laboratories, Lensfield Road, Cambridge CB2 1EW (United Kingdom)

2014-11-14T23:59:59.000Z

110

Liquid polymorphism, order-disorder transitions and anomalous a Monte Carlo study of the Bell-Lavis model for water  

E-Print Network [OSTI]

the lack of consensus concerning the origin of water-like anomalies, it is widely believed of the Bell-Lavis model for water Carlos E. Fiore Departamento de F´isica, Universidade Federal do Paran for liquid water is investigated through numerical simulations. The lattice- gas model on a triangular

Barbosa, Marcia C. B.

111

Simultaneous probing of bulk liquid phase and catalytic gas-liquid-solid interface under working conditions using attenuated total reflection infrared spectroscopy  

SciTech Connect (OSTI)

Design and performance of a reactor set-up for attenuated total reflection infrared (ATR-IR) spectroscopy suitable for simultaneous reaction monitoring of bulk liquid and catalytic solid-liquid-gas interfaces under working conditions are presented. As advancement of in situ spectroscopy an operando methodology for gas-liquid-solid reaction monitoring was developed that simultaneously combines catalytic activity and molecular level detection at the catalytically active site of the same sample. Semi-batch reactor conditions are achieved with the analytical set-up by implementing the ATR-IR flow-through cell in a recycle reactor system and integrating a specifically designed gas feeding system coupled with a bubble trap. By the use of only one spectrometer the design of the new ATR-IR reactor cell allows for simultaneous detection of the bulk liquid and the catalytic interface during the working reaction. Holding two internal reflection elements (IRE) the sample compartments of the horizontally movable cell are consecutively flushed with reaction solution and pneumatically actuated, rapid switching of the cell (<1 s) enables to quasi simultaneously follow the heterogeneously catalysed reaction at the catalytic interface on a catalyst-coated IRE and in the bulk liquid on a blank IRE. For a complex heterogeneous reaction, the asymmetric hydrogenation of 2,2,2-trifluoroacetophenone on chirally modified Pt catalyst the elucidation of catalytic activity/enantioselectivity coupled with simultaneous monitoring of the catalytic solid-liquid-gas interface is shown. Both catalytic activity and enantioselectivity are strongly dependent on the experimental conditions. The opportunity to gain improved understanding by coupling measurements of catalytic performance and spectroscopic detection is presented. In addition, the applicability of modulation excitation spectroscopy and phase-sensitive detection are demonstrated.

Meemken, Fabian; Müller, Philipp; Hungerbühler, Konrad; Baiker, Alfons, E-mail: baiker@chem.ethz.ch [Department of Chemistry and Applied Biosciences, Institute for Chemical and Bioengineering, ETH Zürich, Hönggerberg, HCI, CH-8093 Zürich (Switzerland)

2014-08-15T23:59:59.000Z

112

Laser Ablation Sampling of Materials Directly into the Formed Liquid Microjunction of a Continuous Flow Surface Sampling Probe/Electrospray Ionization Emitter for Mass Spectral Analysis and Imaging  

SciTech Connect (OSTI)

Transmission geometry laser ablation directly into a formed liquid microjunction of a continuous flow liquid microjunction surface sampling probe/electrospray ionization emitter was utilized for molecular and elemental detection and mass spectrometry imaging. The ability to efficiently capture and ionize ablated material was demonstrated by the detection of various small soluble n-mers of polyaniline and silver ion solvent clusters formed from laser ablation of electropolymerized polyaniline and silver thin films, respectively. In addition, analysis of surfaces that contain soluble components was accomplished by coating or laminating the sample with an insoluble film to enable liquid junction formation without directly extracting material from the surface. The ability to perform mass spectrometry imaging at a spatial resolution of about 50 m was illustrated by using laminated inked patterns on a microscope slide. In general, these data demonstrate at least an order of magnitude signal enhancement compared to the non-contact, laser ablation droplet capture-based surface sampling/ionization approaches that have been previously presented.

Ovchinnikova, Olga S [ORNL] [ORNL; Lorenz, Matthias [ORNL] [ORNL; Kertesz, Vilmos [ORNL] [ORNL; Van Berkel, Gary J [ORNL] [ORNL

2013-01-01T23:59:59.000Z

113

Method and apparatus for electrokinetic co-generation of hydrogen and electric power from liquid water microjets  

DOE Patents [OSTI]

A method and apparatus for producing both a gas and electrical power from a flowing liquid, the method comprising: a) providing a source liquid containing ions that when neutralized form a gas; b) providing a velocity to the source liquid relative to a solid material to form a charged liquid microjet, which subsequently breaks up into a droplet spay, the solid material forming a liquid-solid interface; and c) supplying electrons to the charged liquid by contacting a spray stream of the charged liquid with an electron source. In one embodiment, where the liquid is water, hydrogen gas is formed and a streaming current is generated. The apparatus comprises a source of pressurized liquid, a microjet nozzle, a conduit for delivering said liquid to said microjet nozzle, and a conductive metal target sufficiently spaced from said nozzle such that the jet stream produced by said microjet is discontinuous at said target. In one arrangement, with the metal nozzle and target electrically connected to ground, both hydrogen gas and a streaming current are generated at the target as it is impinged by the streaming, liquid spray microjet.

Saykally, Richard J; Duffin, Andrew M; Wilson, Kevin R; Rude, Bruce S

2013-02-12T23:59:59.000Z

114

New Technique for Retrieving Liquid Water Path over Land using Satellite Microwave Observations  

SciTech Connect (OSTI)

We present a new methodology for retrieving liquid water path over land using satellite microwave observations. As input, the technique exploits the Advanced Microwave Scanning Radiometer for earth observing plan (EOS) (AMSR-E) polarization-difference signals at 37 and 89 GHz. Regression analysis performed on model simulations indicates that over variable atmospheric and surface conditions the polarization-difference signals can be simply parameterized in terms of the surface emissivity polarization difference ({Delta}{var_epsilon}), surface temperature, liquid water path (LWP), and precipitable water vapor (PWV). The resulting polarization-difference parameterization (PDP) enables fast and direct (noniterative) retrievals of LWP with minimal requirements for ancillary data. Single- and dual-channel retrieval methods are described and demonstrated. Data gridding is used to reduce the effects of instrumental noise. The methodology is demonstrated using AMSR-E observations over the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site during a six day period in November and December, 2003. Single- and dual-channel retrieval results mostly agree with ground-based microwave retrievals of LWP to within approximately 0.04 mm.

Deeter, M.N.; Vivekanandan, J.

2005-03-18T23:59:59.000Z

115

Effects of liquid pore water on acoustic wave propagation in snow as a Biot-type porous material  

E-Print Network [OSTI]

A method to estimate phase velocity and attenuation of acoustic waves in the presence of liquid water in a snowpack is presented. The method is based on Biot's theory of wave propagation in porous materials. Empirical relations and a priori information is used to characterize snow as a porous material as a function of porosity. Plane wave theory and an equivalent pore fluid are used to solve Biot's differential equations and to asses the impact of the air and water in the pore space. The liquid water in the pore space of a snow pack reduces the velocity of the first compressional wave by roughly 300 m/s for every 0.1 increase in liquid water saturation. Also the attenuation of the compressional waves is increased with increasing liquid water content. Two end member models for compaction are evaluated to asses the importance of an independent density measurement for an estimate of liquid pore water saturation in snow with acoustic waves. The two end members correspond to no compaction at all and to a melting s...

Sidler, Rolf

2015-01-01T23:59:59.000Z

116

Quantification of Liquid Water Saturation in a PEM Fuel Cell Diffusion Medium Using X-ray Microtomography  

E-Print Network [OSTI]

Quantification of Liquid Water Saturation in a PEM Fuel Cell Diffusion Medium Using X understanding of the two-phase flow and flooding occurrence in proton exchange membrane PEM fuel cells. We have as ice formation during cold start of PEM fuel cells. The water present in these porous layers

117

Probing the Interaction of Amorphous Solid Water on a Hydrophobic Surface:  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - SeptemberMicroneedles for4-16 FORPoints ofProbingDewetting and Crystallization

118

Isobaric vapor-liquid equilibria of the water + 1-propanol system at 30, 60, and 100 kPa  

SciTech Connect (OSTI)

Isobaric vapor-liquid equilibria for the water + 1-propanol system are reported at 30, 60, and 100 kPa. The results were found to be thermodynamically consistent according to Van Ness-Byer-Gibbs, Kojima, and Wisniak methods. The system shows a minimum boiling azeotrope, and the azeotropic composition is scarcely shifted with pressure. Results were compared with literature values. The data were correlated with Margules, Van Laar, Wilson, NRTL, and UNIQUAC liquid-phase activity coefficient models.

Gabaldon, C.; Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica] [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica

1996-09-01T23:59:59.000Z

119

Probing water properties and cationic exchange in calcium-silicate-hydrate : an atomistic modeling study  

E-Print Network [OSTI]

Two problems related to the assessment of the performance of cementitious materials in the nuclear fuel cycle are investigated by means of atomistic simulations. The first is the structural and dynamic nature of water ...

Youssef, Mostafa Youssef Mahmoud

2010-01-01T23:59:59.000Z

120

Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR  

E-Print Network [OSTI]

We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

Nicodemus, Rebecca A.

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

An Assessment of Microwave Absorption Models and Retrievals of Cloud Liquid Water Using Clear-Sky Data  

SciTech Connect (OSTI)

Passive microwave radiometers have a long history in the remote sensing of atmospheric liquid and water vapor. Retrievals of these quantities are sensitive to variations in pressure and temperature of the liquid and water vapor. Rather than use a statistical or climatological approach to account for the natural variability in atmospheric pressure and temperature, additional information on the atmospheric profile at the time of the radiometer measurements can be directly incorporated into the retrieval process. Such an approach has been referred to in the literature as a “physical-iterative” solution. This paper presents an assessment of the accuracy of the column liquid water path that can be expected using such an iterative technique as a result of uncertainties in the microwave emissions from oxygen and water vapor. It is shown that the retrieval accuracy is influenced by the accuracy of the instrument measurements and the quality of the atmospheric profiles of temperature and pressure, as one would expect. But also critical is the uncertainty in the absorption coefficients used in the underlying microwave radiative transfer model. The uncertainty in the absorption coefficients is particularly problematic in that it may well bias the liquid water retrieval. The differences between 3 absorption models examined in this paper are equivalent to a bias of 15 to 30 g/m2, depending on the total column water vapor. An examination of typical liquid water paths from the Southern Great Plains region of the United States shows that errors of this magnitude have significant implications for shortwave radiation and retrievals of cloud effective particle size.

Marchand, Roger T.; Ackerman, Thomas P.; Westwater, Ed R.; Clough, Shepard A.; Cady-Pereira, Karen; Liljegren, James C.

2003-12-19T23:59:59.000Z

122

The Influence of Chain Dynamics on the Far Infrared Spectrum of Liquid Methanol-Water Mixtures  

SciTech Connect (OSTI)

Far-infrared absorption spectroscopy has been used to study the low frequency ({center_dot} 100 cm{sup -1}) intermolecular modes of methanol in mixtures with water. With the aid of a first principles molecular dynamics simulation on an equivalent system, a detailed understanding about the origin of the low frequency IR modes has been established. The total dipole spectrum from the simulation suggests that the bands appearing in the experimental spectra at approximately 55 cm{sup -1} and 70 cm{sup -1} in methanol and methanol-rich mixtures arise from both fluctuations and torsional motions occurring within the methanol hydrogen-bonded chains. The influence of these modes on both the solvation dynamics and the relaxation mechanisms in the liquid are discussed within the context of recent experimental and theoretical results that have emerged from studies focusing on the short time dynamics in the methanol hydrogen bond network.

Woods, K.N.; /Stanford U., Phys. Dept.; Wiedemann, H.; /SLAC, SSRL; ,

2005-07-12T23:59:59.000Z

123

Probing Water Phases in Cement Blends using 1 Magnetic Resonance Relaxometry  

E-Print Network [OSTI]

the corrosion. In the long term, the volume increase due to the formation of corrosion products creates ratio (w:s). Pastes were poured into 1 cm OD diameter glass test tubes, vibrated to remove entrapped air their relative content. Relative content of chemically bound water was estimated by subtracting the CPMG

Sheffield, University of

124

Mesoscopic structuring and dynamics of alcohol/water solutions probed by Terahertz Time-Domain Spectroscopy and Pulsed Field Gradient Nuclear Magnetic Resonance  

E-Print Network [OSTI]

in the structure of alcohol/water mixtures. Taking aqueous ethanol as a representative example, excess enthalpy, heat capacity, diffusivity, and viscosity all exhibit maxima or minima at ?15?20 mol %;12,16,20?23 this is attributable to Received: March 20, 2014... dielectric spectroscopy and the results were compared to femtosecond infrared pump? probe studies. By investigating a range of concentrations of aqueous tetramethylurea solutions it was found that the dynamics of the water molecules in close vicinity...

Li, Ruoyu; D'Agostino, Carmine; McGregor, James; Mantle, Michael D.; Zeitler, J. Axel; Gladden, Lynn F.

2014-08-12T23:59:59.000Z

125

Isothermal vapor-liquid equilibria for water + 2-aminoethanol + dimethyl sulfoxide and its constituent three binary systems  

SciTech Connect (OSTI)

Isothermal vapor-liquid equilibria were measured for the ternary system water + 2-aminoethanol + dimethyl sulfoxide and its three constituent binary mixtures at 363.15 K. The apparatus used was a modified Rogalski-Malanoski equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

Tochigi, Katsumi; Akimoto, Kentarou; Ochi, Kenji [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry] [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Liu, Fangyhi; Kawase, Yasuhito [Nippon Refine Co., Ltd., Tokyo (Japan)] [Nippon Refine Co., Ltd., Tokyo (Japan)

1999-05-01T23:59:59.000Z

126

Analysis of two independent methods for retrieving liquid water profiles in spring and summer Arctic boundary clouds  

E-Print Network [OSTI]

-based remote sensing, optimal estimation, LES model with explicit microphysics, cloud liquid water algorithms Heat Budget of the Arctic Ocean (SHEBA) project. An algorithm developed by Frisch et al. [1995, 1998 matrix of the LWC profile is calculated, an optimal estimation method is applied to the SHEBA data

Shupe, Matthew

127

Sudden structural change at ati air/binary liquid interface: Sum frequency study of the air/acetonitrile-water interface  

E-Print Network [OSTI]

Sudden structural change at ati air/binary liquid interface: Sum frequency study of the air/acetonitrile change in an air/acetonitrile-water interface as the solution composition varies; the abruptness of which and in the polarization of the signal from the acetonitrile molecules in the interface observed using infrared + visible

Eisenthal, Kenneth B.

128

Liquid chromatographic method for determination of water in soils and the optimization of anion separations by capillary zone electrophoresis  

SciTech Connect (OSTI)

A liquid chromatographic method for the determination of water in soil or clay samples is presented. In a separate study, the optimization of electrophoretic separation of alkylated phenolate ions was optimized by varying the pH and acetonitrile concentration of the buffer solutions.

Benz, N.

1994-10-01T23:59:59.000Z

129

Formation of Liquid Methane-Water Mixture during Combustion of a Laminar Methane Jet at Supercritical Pressures  

E-Print Network [OSTI]

Formation of Liquid Methane-Water Mixture during Combustion of a Laminar Methane Jet in laminar jet flames of methane at elevated pressures in a high-pressure combustion chamber, we have MPa, after the laminar methane jet flame had been stabilized on a co-flow circular nozzle-type burner

Gülder, �mer L.

130

Charge transfer effects of ions at the liquid water/vapor interface  

SciTech Connect (OSTI)

Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 Å away from the surface.

Soniat, Marielle; Rick, Steven W., E-mail: srick@uno.edu [Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148 (United States)

2014-05-14T23:59:59.000Z

131

Absorption spectra of liquid water and aqueous buffers between 0.3 and Department of Physics, University of California, Santa Barbara, California 93106  

E-Print Network [OSTI]

Absorption spectra of liquid water and aqueous buffers between 0.3 and 3.72 THz Jing Xua Department-dependent terahertz absorption with attenuation lengths on the order of tens of micrometers. To access this spectral.5 THz, these studies provide a well- documented absorption spectrum for liquid water, at approxi- mately

Xu, Jing

132

NEW VIEW of the young earth covered in oceans of liquid water as early as 4.4 billion years ago  

E-Print Network [OSTI]

sun. Averaging 75 times the speed of sound, each impactor scorched the surface--shattering, meltingNEW VIEW of the young earth covered in oceans of liquid water as early as 4.4 billion years ago into a crust, before continents could form, be- fore the dense, steamy atmosphere could pool as liquid water

Carlson, Anders

133

The Individual and Collective Effects of Exact Exchange and Dispersion Interactions on the Ab Initio Structure of Liquid Water  

E-Print Network [OSTI]

In this work, we report the results of a series of density functional theory (DFT) based ab initio molecular dynamics (AIMD) simulations of ambient liquid water using a hierarchy of exchange-correlation (XC) functionals to investigate the individual and collective effects of exact exchange (Exx), via the PBE0 hybrid functional, non-local vdW/dispersion interactions, via a fully self-consistent density-dependent dispersion correction, and approximate nuclear quantum effects (aNQE), via a 30 K increase in the simulation temperature, on the microscopic structure of liquid water. Based on these AIMD simulations, we found that the collective inclusion of Exx, vdW, and aNQE as resulting from a large-scale AIMD simulation of (H$_2$O)$_{128}$ at the PBE0+vdW level of theory, significantly softens the structure of ambient liquid water and yields an oxygen-oxygen structure factor, $S_{\\rm OO}(Q)$, and corresponding oxygen-oxygen radial distribution function, $g_{\\rm OO}(r)$, that are now in quantitative agreement with the best available experimental data. This level of agreement between simulation and experiment as demonstrated herein originates from an increase in the relative population of water molecules in the interstitial region between the first and second coordination shells, a collective reorganization in the liquid phase which is facilitated by a weakening of the hydrogen bond strength by the use of the PBE0 hybrid XC functional, coupled with a relative stabilization of the resultant disordered liquid water configurations by the inclusion of non-local vdW/dispersion interactions.

Robert A. DiStasio Jr.; Biswajit Santra; Zhaofeng Li; Xifan Wu; Roberto Car

2014-05-20T23:59:59.000Z

134

Probing the thermal character of analogue Hawking radiation for shallow water waves?  

E-Print Network [OSTI]

We study and numerically compute the scattering coefficients of shallow water waves blocked by a stationary counterflow. When the flow is transcritical, the coefficients closely follow Hawking's prediction according to which black holes should emit a thermal spectrum. We study how the spectrum deviates from thermality when reducing the maximal flow velocity, with a particular attention to subcritical flows since these have been recently used to test Hawking's prediction. For such flows, we show that the emission spectrum is strongly suppressed, and that its Planckian character is completely lost. For low frequencies, we also show that the scattering coefficients are dominated by elastic hydrodynamical channels. Our numerical results reproduce rather well the observations made by S. Weinfurtner {\\it et al.} in the Vancouver experiment. Nevertheless, we propose a new interpretation of what has been observed, as well as new experimental tests.

Florent Michel; Renaud Parentani

2014-09-15T23:59:59.000Z

135

Isobaric vapor-liquid equilibria of the water + 2-propanol system at 30, 60, and 100 kPa  

SciTech Connect (OSTI)

Distillation is perhaps the separation process most widely used in the chemical processing industry. The correct design of distillation columns requires the availability of accurate and, if possible, thermodynamically consistent vapor-liquid equilibria (VLE) data. The present work is part of a project studying the effect of pressure on the behavior of the azeotropic point in mixtures in which at least one component is an alcohol. Isobaric vapor-liquid equilibria were obtained for the water + 2-propanol system at 30, 60, and 100 kPa. The activity coefficients were found to be thermodynamically consistent by the methods of Van Ness-Byer-Gibbs, Kojima, and Wisniak. The data were correlated with five liquid phase activity coefficient models (Margules, Van Laar, Wilson, NRTL, and UNIQUAC).

Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Departamento de Ingenieria Quimica] [Univ. de Valencia (Spain). Departamento de Ingenieria Quimica

1996-05-01T23:59:59.000Z

136

MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2)  

SciTech Connect (OSTI)

This report provides a short description of the Atmospheric Radiation Measurement (ARM) Climate Research Facility microwave radiometer (MWR) Retrieval (MWRRET) value-added product (VAP) algorithm. This algorithm utilizes a complementary physical retrieval method and applies brightness temperature offsets to reduce spurious liquid water path (LWP) bias in clear skies resulting in significantly improved precipitable water vapor (PWV) and LWP retrievals. We present a general overview of the technique, input parameters, output products, and describe data quality checks. A more complete discussion of the theory and results is given in Turner et al. (2007b).

Gaustad, KL; Turner, DD; McFarlane, SA

2011-07-25T23:59:59.000Z

137

Removal of a liquid paraffin film from a water surface by short pulses from a CO{sub 2} laser  

SciTech Connect (OSTI)

The process of removal of a liquid paraffin film from a water surface irradiated by 40 - 270-{mu}s pulses from a CO{sub 2} laser is studied experimentally and theoretically. It is found for the first time that the mass of removed paraffin can exceed that of paraffin located in the region irradiated by the laser pulse. A theoretical model is proposed which explains the results obtained. (laser applications and other topics in quantum electronics)

Antonova, L I; Drobyazko, S V; Evdokimov, I A; Krasyukov, A G; Likhanskii, V V; Loboiko, A I; Senatorov, Yu M [State Research Center of Russian Federation 'Troitsk Institute for Innovation and Fusion Research', Troitsk, Moscow Region (Russian Federation)

2002-02-28T23:59:59.000Z

138

Using LiF:Mg,Cu,P TLDs to estimate the absorbed dose to water in liquid water around an {sup 192}Ir brachytherapy source  

SciTech Connect (OSTI)

Purpose: The absorbed dose to water is the fundamental reference quantity for brachytherapy treatment planning systems and thermoluminescence dosimeters (TLDs) have been recognized as the most validated detectors for measurement of such a dosimetric descriptor. The detector response in a wide energy spectrum as that of an{sup 192}Ir brachytherapy source as well as the specific measurement medium which surrounds the TLD need to be accounted for when estimating the absorbed dose. This paper develops a methodology based on highly sensitive LiF:Mg,Cu,P TLDs to directly estimate the absorbed dose to water in liquid water around a high dose rate {sup 192}Ir brachytherapy source. Methods: Different experimental designs in liquid water and air were constructed to study the response of LiF:Mg,Cu,P TLDs when irradiated in several standard photon beams of the LNE-LNHB (French national metrology laboratory for ionizing radiation). Measurement strategies and Monte Carlo techniques were developed to calibrate the LiF:Mg,Cu,P detectors in the energy interval characteristic of that found when TLDs are immersed in water around an{sup 192}Ir source. Finally, an experimental system was designed to irradiate TLDs at different angles between 1 and 11 cm away from an {sup 192}Ir source in liquid water. Monte Carlo simulations were performed to correct measured results to provide estimates of the absorbed dose to water in water around the {sup 192}Ir source. Results: The dose response dependence of LiF:Mg,Cu,P TLDs with the linear energy transfer of secondary electrons followed the same variations as those of published results. The calibration strategy which used TLDs in air exposed to a standard N-250 ISO x-ray beam and TLDs in water irradiated with a standard{sup 137}Cs beam provided an estimated mean uncertainty of 2.8% (k = 1) in the TLD calibration coefficient for irradiations by the {sup 192}Ir source in water. The 3D TLD measurements performed in liquid water were obtained with a maximum uncertainty of 11% (k = 1) found at 1 cm from the source. Radial dose values in water were compared against published results of the American Association of Physicists in Medicine and the European Society for Radiotherapy and Oncology and no significant differences (maximum value of 3.1%) were found within uncertainties except for one position at 9 cm (5.8%). At this location the background contribution relative to the TLD signal is relatively small and an unexpected experimental fluctuation in the background estimate may have caused such a large discrepancy. Conclusions: This paper shows that reliable measurements with TLDs in complex energy spectra require a study of the detector dose response with the radiation quality and specific calibration methodologies which model accurately the experimental conditions where the detectors will be used. The authors have developed and studied a method with highly sensitive TLDs and contributed to its validation by comparison with results from the literature. This methodology can be used to provide direct estimates of the absorbed dose rate in water for irradiations with HDR{sup 192}Ir brachytherapy sources.

Lucas, P. Avilés, E-mail: paz.aviles@ciemat.es; Aubineau-Lanièce, I.; Lourenço, V.; Vermesse, D.; Cutarella, D. [CEA, LIST, Laboratoire National Henri Becquerel, 91191 Gif-sur-Yvette (France)] [CEA, LIST, Laboratoire National Henri Becquerel, 91191 Gif-sur-Yvette (France)

2014-01-15T23:59:59.000Z

139

High temperature probe  

DOE Patents [OSTI]

A high temperature probe for sampling, for example, smokestack fumes, and is able to withstand temperatures of 3000.degree. F. The probe is constructed so as to prevent leakage via the seal by placing the seal inside the water jacket whereby the seal is not exposed to high temperature, which destroys the seal. The sample inlet of the probe is also provided with cooling fins about the area of the seal to provide additional cooling to prevent the seal from being destroyed. Also, a heated jacket is provided for maintaining the temperature of the gas being tested as it passes through the probe. The probe includes pressure sensing means for determining the flow velocity of an efficient being sampled. In addition, thermocouples are located in various places on the probe to monitor the temperature of the gas passing there through.

Swan, Raymond A. (Fremont, CA)

1994-01-01T23:59:59.000Z

140

Calculation of releases of radioactive materials in gaseous and liquid effluents from pressurized water reactors (PWR-GALE Code). Revision 1  

SciTech Connect (OSTI)

This report revises the original issuance of NUREG-0017, ''Calculation of Releases of Radioactive Materials in Gaseous and Liquid Effluents from Pressurized Water Reactors (PWR-GALE-Code)'' (April 1976), to incorporate more recent operating data now available as well as the results of a number of in-plant measurement programs at operating pressurized water reactors. The PWR-GALE Code is a computerized mathematical model for calculating the releases of radioactive material in gaseous and liquid effluents (i.e., the gaseous and liquid source terms). The US Nuclear Regulatory Commission uses the PWR-GALE Code to determine conformance with the requirements of Appendix I to 10 CFR Part 50.

Chandrasekaran, T.; Lee, J.Y.; Willis, C.A.

1985-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Liquid chromatographic analysis of coal surface properties  

SciTech Connect (OSTI)

The main objectives of this proposed research are to refine further the inverse liquid chromatography technique for the study of surface properties of raw coals, treated coals and coal minerals in water, to evaluate relatively surface properties of raw coals, treated coals and coal minerals by inverse liquid chromatography, and to evaluate floatability of various treated coals in conjunction with surface properties of coals. Alcohols such as methanol, ethanol, isopropanol, isobutanol, tert-butanol, heptanol, 1-hexadecanol, 2-methyl-pentanol, 4-methyl-2-penthanol (methylisobutyl carbinol), n-octanol, s-octanol, and cyclohexanol as probe compounds are utilized to evaluate hydrophilicity of coals and coal minerals. N-alkanes such as hexane, heptane and octane, and stearic acid are employed as probe compounds to evaluate hydrophobicity of coals and coal minerals. Aromatic compounds such as benzene and toluene as probe compounds are used to examine aromaticity of coal surface. Aromatic acids such as o-cresol, m-cresol, p-cresol, phenol and B-naphthol are used to detect aromatic acidic sites of coal surface. Hydrophilicity, hydrophobicity and aromaticity of surfaces for either raw coals or treated coals in water are relatively determined by evaluating both equilibrium physical/chemical adsorption and dynamic adsorption of probe compounds on various raw coals and treated coals to compare affinities of coals for water.

Kwon, K.C.

1991-01-01T23:59:59.000Z

142

Equation of state of water under negative pressure Kristina Davitt,a  

E-Print Network [OSTI]

on the simultaneous measurements of the speed of sound and the density in liquid water under negative pressure the speed of sound during the passage of a 1 MHz ultrasonic wave. This is coupled with a fiber optic probe. Application of a focused acoustic wave to the bulk liquid is able to generate negative pressures before

Caupin, Frédéric

143

Design and testing of a deep sea formation water and temeperature sampling probe for the Ocean Drilling Program  

E-Print Network [OSTI]

. Components were then fabricated by a local machine shop. All components under went quality inspection and were then assembled. Full scale testing at the Ocean Drilling Programs Annex is the next step. If successful, the probe is to undergo sea trials...

Fisseler, Patrick James

2012-06-07T23:59:59.000Z

144

A Fixed Point Charge Model for Water Optimized to the Vapor-Liquid Coexistence Properties  

E-Print Network [OSTI]

the temperature range of the liquid. Results were compared to the SPC, SPC/E, and MSPC/E models, vapor pressures, critical parameters, and the second virial coefficient. It is inferior to the SPC interactions. Models of this type include the Bernal-Fowler1 , ST22 , TIPS23 , TIP4P4 , SPC5 , SPC/E6

145

Pore-Level Liquid Water Transport Through Composite Diffusion Media of PEMFC  

E-Print Network [OSTI]

, and Chao-Yang Wang*,z Electrochemical Engine Center and Department of Mechanical and Nuclear Engineering of liquid injection sites into the GDL. © 2010 The Electrochemical Society. DOI: 10.1149/1.3491359 All, low operation temperature, and low noise. The low operation tempera- ture allows for fast startup

146

Decontamination of Nuclear Liquid Wastes Status of CEA and AREVA R and D: Application to Fukushima Waste Waters - 12312  

SciTech Connect (OSTI)

Liquid wastes decontamination processes are mainly based on two techniques: Bulk processes and the so called Cartridges processes. The first technique has been developed for the French nuclear fuel reprocessing industry since the 60's in Marcoule and La Hague. It is a proven and mature technology which has been successfully and quickly implemented by AREVA at Fukushima site for the processing of contaminated waters. The second technique, involving cartridges processes, offers new opportunities for the use of innovative adsorbents. The AREVA process developed for Fukushima and some results obtained on site will be presented as well as laboratory scale results obtained in CEA laboratories. Examples of new adsorbents development for liquid wastes decontamination are also given. A chemical process unit based on co-precipitation technique has been successfully and quickly implemented by AREVA at Fukushima site for the processing of contaminated waters. The asset of this technique is its ability to process large volumes in a continuous mode. Several chemical products can be used to address specific radioelements such as: Cs, Sr, Ru. Its drawback is the production of sludge (about 1% in volume of initial liquid volume). CEA developed strategies to model the co-precipitation phenomena in order to firstly minimize the quantity of added chemical reactants and secondly, minimize the size of co-precipitation units. We are on the way to design compact units that could be mobilized very quickly and efficiently in case of an accidental situation. Addressing the problem of sludge conditioning, cementation appears to be a very attractive solution. Fukushima accident has focused attention on optimizations that should be taken into account in future studies: - To better take account for non-typical aqueous matrixes like seawater; - To enlarge the spectrum of radioelements that can be efficiently processed and especially short lives radioelements that are usually less present in standard effluents resulting from nuclear activities; - To develop reversible solid adsorbents for cartridge-type applications in order to minimize wastes. (authors)

Fournel, B.; Barre, Y.; Lepeytre, C.; Peycelon, H. [CEA Marcoule, DTCD, BP17171, 30207 Bagnols sur Ceze (France); Grandjean, A. [Institut de Chimie Separative de Marcoule, UMR5257 CEA-CNRS-UM2-ENSCM, BP17171, 30207 Bagnols sur Ceze (France); Prevost, T.; Valery, J.F. [AREVA NC, Paris La Defense (France); Shilova, E.; Viel, P. [CEA Saclay, DSM/IRAMIS/SPCSI, 91191 Gif sur Yvette (France)

2012-07-01T23:59:59.000Z

147

NATURAL RADIONUCLIDES MEASUREMENTS IN DRINKING WATER BY LIQUID SCINTILLATION COUNTING. METHODS AND RESULTS  

E-Print Network [OSTI]

procedure, standardized by International Standard Organization.4 On the contrary, total indicative dose in view of a large scale monitoring program. World Health Organization guidelines for drinking water

148

7-88 A geothermal power plant uses geothermal liquid water at 160C at a specified rate as the heat source. The actual and maximum possible thermal efficiencies and the rate of heat rejected from this power plant  

E-Print Network [OSTI]

and potential energy changes are zero. 3 Steam properties are used for geothermal water. Properties Using7-31 7-88 A geothermal power plant uses geothermal liquid water at 160ºC at a specified rate saturated liquid properties, the source and the sink state enthalpies of geothermal water are (Table A-4) k

Bahrami, Majid

149

Measurements of the Distribution of Solutes between Liquid Water and Steam  

SciTech Connect (OSTI)

Direct measurements of the concentration of solutes in both liquid and steam phases in equilibrium with each other have been made in a static mode utilizing a platinum-lined autoclave to a maximum of 350 deg C. Partitioning constants were derived from these measurements based on existing experimental or estimated values of the stoichiometric mean activity coefficients for the solutes in the liquid phase. Independent measurements of the conductance of some of the solutes in dilute aqueous solutions to 600 deg C and 300MPa were also made. The combined results are discussed in terms of a speciated model and the implications of these results to industrial and natural hydrothermal processes are presented. PARTITIONING CONSTANT, ION-ASSOCIATION, CONDUCTIVITY, SPECIATION, CORROSION.

Palmer, D.A.; Simonson, J.M.; Ho, P.C.

1997-12-31T23:59:59.000Z

150

Spectrophotometric probe  

DOE Patents [OSTI]

A support structure is described bearing at least one probe for making spectrophotometric measurements of a fluid using a source of light and a spectrophotometer. The probe includes a housing with two optical fibers and a planoconvex lens. A sleeve bearing a mirror surrounds the housing. The lens is separated from the mirror by a fixed distance, defining an interior space for receiving a volume of the fluid sample. A plurality of throughholes extending through the sleeve communicate between the sample volume and the exterior of the probe, all but one hole bearing a screen. A protective jacket surrounds the probe. A hollow conduit bearing a tube is formed in the wall of the probe for venting any air in the interior space when fluid enters. The probe is held at an acute angle so the optic fibers carrying the light to and from the probe are not bent severely on emergence from the probe. 3 figs.

Prather, W.S.; O'Rourke, P.E.

1994-08-02T23:59:59.000Z

151

High-Resolution Electrospray Ionization Mass Spectrometry Analysis of Water- Soluble Organic Aerosols Collected with a Particle into Liquid Sampler  

SciTech Connect (OSTI)

This work demonstrates the utility of a particle-into-liquid sampler (PILS) a technique traditionally used for identification of inorganic ions present in ambient or laboratory aerosols for the analysis of water soluble organic aerosol (OA) using high resolution electrospray ionization mass spectrometry (HR ESI-MS). Secondary organic aerosol (SOA) was produced from 0.5 ppm mixing ratios of limonene and ozone in a 5 m3 Teflon chamber. SOA was collected simultaneously using a traditional filter sampler and a PILS. The filter samples were later extracted with either water or acetonitrile, while the aqueous PILS samples were analyzed directly. In terms of peak intensities, types of detectable compounds, average O:C ratios, and organic mass to organic carbon ratios, the resulting high resolution mass spectra were essentially identical for the PILS and filter based samples. SOA compounds extracted from both filter/acetonitrile extraction and PILS/water extraction accounted for >95% of the total ion current in ESI mass spectra. This similarity was attributed to high solubility of limonene SOA in water. In contrast, significant differences in detected ions and peak abundances were observed for pine needle biomass burning organic aerosol (BBOA) collected with PILS and filter sampling. The water soluble fraction of BBOA is considerably smaller than for SOA, and a number of unique peaks were detectable only by the filter/acetonitrile method. The combination of PILS collection with HR-ESI-MS analysis offers a new approach for molecular analysis of the water-soluble organic fraction in biogenic SOA, aged photochemical smog, and BBOA.

Bateman, Adam P.; Nizkorodov, Serguei; Laskin, Julia; Laskin, Alexander

2010-10-01T23:59:59.000Z

152

Liquid-phase and vapor-phase dehydration of organic/water solutions  

DOE Patents [OSTI]

Processes for dehydrating an organic/water solution by pervaporation or vapor separation using fluorinated membranes. The processes are particularly useful for treating mixtures containing light organic components, such as ethanol, isopropanol or acetic acid.

Huang, Yu (Palo Alto, CA); Ly, Jennifer (San Jose, CA); Aldajani, Tiem (San Jose, CA); Baker, Richard W. (Palo Alto, CA)

2011-08-23T23:59:59.000Z

153

Liquid-Water Uptake and Removal in PEM Fuel-Cell Components  

E-Print Network [OSTI]

Uptake and Removal in PEM Fuel-Cell Components Prodip K. DasWater management in PEM fuel cells is critical for optimumof droplet dynamics in PEM fuel-cell gas flow channels has

Das, Prodip K.

2013-01-01T23:59:59.000Z

154

Advanced Scintillator Detector Concept (ASDC): A Concept Paper on the Physics Potential of Water-Based Liquid Scintillator  

E-Print Network [OSTI]

The recent development of Water-based Liquid Scintillator (WbLS), and the concurrent development of high-efficiency and high-precision-timing light sensors, has opened up the possibility for a new kind of large-scale detector capable of a very broad program of physics. The program would include determination of the neutrino mass hierarchy and observation of CP violation with long-baseline neutrinos, searches for proton decay, ultra-precise solar neutrino measurements, geo- and supernova neutrinos including diffuse supernova antineutrinos, and neutrinoless double beta decay. We outline here the basic requirements of the Advanced Scintillation Detector Concept (ASDC), which combines the use of WbLS, doping with a number of potential isotopes for a range of physics goals, high efficiency and ultra-fast timing photosensors, and a deep underground location. We are considering such a detector at the Long Baseline Neutrino Facility (LBNF) far site, where the ASDC could operate in conjunction with the liquid argon tracking detector proposed by the LBNE collaboration. The goal is the deployment of a 30-100 kiloton-scale detector, the basic elements of which are being developed now in experiments such as WATCHMAN, ANNIE, SNO+, and EGADS.

J. R. Alonso; N. Barros; M. Bergevin; A. Bernstein; L. Bignell; E. Blucher; F. Calaprice; J. M. Conrad; F. B. Descamps; M. V. Diwan; D. A. Dwyer; S. T. Dye; A. Elagin; P. Feng; C. Grant; S. Grullon; S. Hans; D. E. Jaffe; S. H. Kettell; J. R. Klein; K. Lande; J. G. Learned; K. B. Luk; J. Maricic; P. Marleau; A. Mastbaum; W. F. McDonough; L. Oberauer; G. D. Orebi Gann; R. Rosero; S. D. Rountree; M. C. Sanchez; M. H. Shaevitz; T. M. Shokair; M. B. Smy; A. Stahl; M. Strait; R. Svoboda; N. Tolich; M. R. Vagins; K. A. van Bibber; B. Viren; R. B. Vogelaar; M. J. Wetstein; L. Winslow; B. Wonsak; E. T. Worcester; M. Wurm; M. Yeh; C. Zhang

2014-10-24T23:59:59.000Z

155

The influence of irrigation water salinity on optimal nitrogen, phosphorus, and potassium liquid fertilizer rates  

E-Print Network [OSTI]

to Dieffenbachia when the amount of fertilizers in the irrigation water increased above the optimum range. In a second experiment with Spa thi phyllum and cucumber, the combination of 5 levels of fertilizers (0, 125, 250, 375, 500 mg I N) and 5 salinity levels... (0, 500, 1000, 1500, 2000 mg I salts) were tested. Nutrient analysis were performed in leaves, petioles, and roots of Spathiphyilum. In Spathiphyllum, the maximum growth was observed at 250 mg I N and no salts. With high salinity in the water (2000...

Campos Nu?n?ez, Ricardo

1990-01-01T23:59:59.000Z

156

Determination of cloud liquid water distribution using 3D cloud tomography  

E-Print Network [OSTI]

, but they provide a less direct measurement of cloud water content (since radar reflectivity depends strongly, the number of scanning angles, the radiometer characteristics (e.g., noise level, beam width), the physical accuracy. For a setup consisting of four microwave radiometers of typical noise level 0.3 K, the tomography

157

Evaluation of ground-based remotely sensed liquid water cloud properties using shortwave radiation measurements  

E-Print Network [OSTI]

properties of low level water clouds. A number of remote sensing retrieval techniques provide either radar-only retrie- vals or combine millimeter-wave radar with microwave radiometer measurements (Frisch et al., 1995 radiation measurements from the ground. The remote sensing observations of radar reflectivity, microwave

Haak, Hein

158

Life in the Solar System Assume we need energy, liquid water, and organic materials.  

E-Print Network [OSTI]

;Small rocky bodies are unlikely to host life: too hot or cold for water, no protective atmosphere so too. #12;Venus is hot (molten lead can exist on its surface!), high pressure (90 atmospheres), toxic, no sunlight, high temperature. Not much chance of life there. Gas Giants #12;The moons of the giant planets

Shirley, Yancy

159

Liquid Water Transport in Gas Diffusion Layer of Polymer Electrolyte Fuel Cells  

E-Print Network [OSTI]

. In addition, at high current densities, excessive amount of water is generated and condenses, filling as a promising candidate for high-efficiency, low-emission power sources. High-current-density operation of PEFCs, The Pennsylvania State University, University Park, Pennsylvania 16802, USA High-current-density performance

160

Task 15 -- Remediation of organically contaminated soil using hot/liquid (subcritical) water. Semi-annual report, April 1--September 30, 1997  

SciTech Connect (OSTI)

This activity involves a pilot-scale demonstration of the use of hot/liquid water for the removal of organic contaminants from soil at the pilot (20 to 40 kg) scale. Lab-scale studies are being performed to determine the optimum temperature, contact time, and flow rates for removal of the organic contaminants. Initial investigations into using carbon sorbents to clean the extractant water for recycle use and to concentrate the extracted contaminants in a small volume for disposal are also being performed. Liquid water is normally considered to be too polar a solvent to be effective for removal of organic contaminants from contaminated soils and sludges. However, the Energy and Environmental Research Center (EERC) has demonstrated that the polarity of liquid water can be changed from that of a very polar solvent at ambient conditions to that of an organic solvent (e.g., ethanol or acetonitrile) by simply raising the temperature. The EERC has exploited this unique property of liquid water to obtain highly selective extractions of polar (at lower temperatures) to nonpolar (at 200 to 250 C) organics from contaminated soils and sludges. Only moderate pressures (a maximum of about 45 atm at 250 C and lower pressures at lower temperatures) are required. With this procedure, all detectable hazardous organics were removed from the sludge, thus making the remaining material (about 99% of the original mass) a nonhazardous material. The present understanding of hot/liquid water extraction for the removal of hazardous organics from contaminated soils and sludges is being used to develop the engineering parameters needed to perform a pilot-scale demonstration of the remediation technology. Progress during the report period is summarized.

Hawthorne, S.B.

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Cloud fraction, liquid and ice water contents derived from long-term radar, lidar, and microwave radiometer data are systematically compared to models to quantify and  

E-Print Network [OSTI]

Cloud fraction, liquid and ice water contents derived from long-term radar, lidar, and microwave a systematic evaluation of clouds in forecast models. Clouds and their associated microphysical processes for end users of weather forecasts, who may be interested not only in cloud cover, but in other variables

Hogan, Robin

162

Colloidal gold nanoparticle probe-based immunochromatographic assay for the rapid detection of chromium ions in water and serum samples  

SciTech Connect (OSTI)

An immunochromatographic assay (ICA) using gold nanoparticles coated with monoclonal antibody (McAb) for the detection of chromium ions (Cr) in water and serum samples was developed, optimized, and validated. Gold nanoparticles coated with affinity- purified monoclonal antibodies against isothiocyanobenzyl-EDTA (iEDTA)-chelated Cr3+ were used as the detecting reagent in this completive immunoassay-based one- step test strip. The ICA was investigated to measure chromium speciation in water samples. Chromium standard samples of 0-80 ng/mL in water were determined by the test strips. The results showed that the visual lowest detection limit (LDL) of the test strip was 50.0 ng/mL. A portable colorimetric lateral flow reader was used for the quantification of Cr. The results indicated that the linear range of the ICA with colorimetric detection was 5-80 ng/mL. The ICA was also validated for the detection of chromium ions in serum samples. The test trips showed high stability in that they could be stored at at 37 C for at least 12 weeks without significant loss of activity. The test strip also showed good selectivity for Cr detection with negligible interference from other heavy metals. Because of its low cost and short testing time (within 5 min), the test strip is especially suitable for on-site large- scale screening of Cr-polluted water samples, biomonitoring of Cr exposure, and many other field applications.

Liu, Xi; Xiang, Jun-Jian; Tang, Yong; Zhang, Xiao-Li; Fu, Qiang-Qiang; Zou, Jun-Hui; Lin, Yuehe

2012-09-01T23:59:59.000Z

163

Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model  

SciTech Connect (OSTI)

A lattice Boltzmann color-fluid model, which was recently proposed by Liu et al. [H. Liu, A.J. Valocchi, and Q. Kang. Three-dimensional lattice Boltzmann model for immiscible two-phase flow simulations. Phys. Rev. E, 85:046309, 2012.] based on a concept of continuum surface force, is improved to simulate immiscible two-phase flows in porous media. The new improvements allow the model to account for different kinematic viscosities of both fluids and to model fluid-solid interactions. The capability and accuracy of this model is first validated by two benchmark tests: a layered two-phase flow with a viscosity ratio, and a dynamic capillary intrusion. This model is then used to simulate liquid CO2 (LCO2) displacing water in a dual-permeability pore network. The extent and behavior of LCO2 preferential flow (i.e., fingering) is found to depend on the capillary number (Ca), and three different displacement patterns observed in previous micromodel experiments are reproduced. The predicted variation of LCO2 saturation with Ca, as well as variation of specific interfacial length with LCO2 saturation, are both in good agreement with the experimental observations. To understand the effect of heterogeneity on pore-scale displacement, we also simulate LCO2 displacing water in a randomly heterogeneous pore network, which has the same size and porosity as the dual-permeability pore network. In comparison to the dual-permeability case, the transition from capillary fingering to viscous fingering occurs at a higher Ca, and LCO2 saturation is higher at low Ca but lower at high Ca. In either pore network, the LCO2-water specific interfacial length is found to obey a power-law dependence on LCO2 saturation.

Liu, Haihu; Valocchi, Albert J.; Werth, Charles J.; Kang, Oinjun; Oostrom, Martinus

2014-11-01T23:59:59.000Z

164

pH Meter probe assembly  

DOE Patents [OSTI]

An assembly for mounting a pH probe in a flowing solution, such as a sanitary sewer line, which prevents the sensitive glass portion of the probe from becoming coated with grease, oil, and other contaminants, whereby the probe gives reliable pH indication over an extended period of time. The pH probe assembly utilizes a special filter media and a timed back-rinse feature for flushing clear surface contaminants of the filter. The flushing liquid is of a known pH and is utilized to check performance of the probe.

Hale, Charles J. (San Jose, CA)

1983-01-01T23:59:59.000Z

165

pH Meter probe assembly  

DOE Patents [OSTI]

An assembly for mounting a pH probe in a flowing solution, such as a sanitary sewer line, which prevents the sensitive glass portion of the probe from becoming coated with grease, oil, and other contaminants, whereby the probe gives reliable pH indication over an extended period of time. The pH probe assembly utilizes a special filter media and a timed back-rinse feature for flushing clear surface contaminants of the filter. The flushing liquid is of a known pH and is utilized to check performance of the probe. 1 fig.

Hale, C.J.

1983-11-15T23:59:59.000Z

166

Isobaric vapor-liquid equilibria for binary and ternary systems composed of water, 1-propanol, and 2-propanol at 100 kPa  

SciTech Connect (OSTI)

Isobaric vapor-liquid equilibria data were obtained for the 2-propanol + 1-propanol binary system and the water + 1-propanol + 2-propanol ternary system at 100 kPa. The data were found to be thermodynamically consistent according to the Van Ness-Byer-Gibbs method for the binary system and according to the McDermott-Ellis method for the ternary one. The binary system is well represented by assuming ideal behavior. The binary interaction parameters obtained from this and previous work are used to predict the vapor-liquid equilibrium for the ternary system using the UNIQUAC, NRTL, and Wilson models. The ternary system is well predicted from binary data.

Gabaldon, C.; Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica] [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica

1996-11-01T23:59:59.000Z

167

A system to test the effects of materials on the electron drift lifetime in liquid argon and observations on the effect of water  

SciTech Connect (OSTI)

A materials test system (MTS) has been developed at FNAL to assess the suitability of materials for use in a large liquid argon time projection chamber. During development of the MTS, it was noted that controlling the cryostat pressure with a 'raining' condenser reduced the electron drift lifetime in the liquid argon. The effect of condensing has been investigated using a series of passive materials to filter the condensate. We report the results of these studies and of tests on different candidate materials for detector construction. The inferred reduction of electron drift lifetime by water concentrations in the parts per trillion is of particular interest.

Andrews, R.; Jaskierny, W.; Jostlein, H.; Kendziora, C.; Pordes, S.; Tope, T.; /Fermilab; ,

2009-07-01T23:59:59.000Z

168

Acidic Ionic Liquid/Water Solution as Both Medium and Proton Source for Electrocatalytic H2 Evolution by [Ni(P2N2)2]2+ Complexes  

SciTech Connect (OSTI)

The electrocatalytic reduction of protons to H2 by [Ni(PPh2NC6H4-hex2)2](BF4)2 (where PPh2NC6H4-hex2 = 1,5-di(4-n-hexylphenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) in the highly acidic ionic liquid dibutylformamidium bis(trifluoromethanesulfonyl)amide shows a strong dependence on added water. A turnover frequency of 43,000-53,000 s-1 has been measured for hydrogen production at 25 °C when the mole fraction of water (?H2O) is 0.72. The same catalyst in acetonitrile with added dimethylformamidium trifluoromethanesulfonate and water has a turnover frequency of 720 s?1. Thus the use of an ionic liquid/aqueous solution enhances the observed catalytic rates by more than a factor of 50 compared to acids in traditional organic solvents such as acetonitrile. Complexes [Ni(PPh2NC6H4X2)2](BF4)2 (X = H, OMe, CH2P(O)(OEt)2, Br) are also catalysts in the ionic liquid/water mixture, and the observed catalytic rates correlate with the hydrophobicity of X. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

Pool, Douglas H.; Stewart, Michael P.; O'Hagan, Molly J.; Shaw, Wendy J.; Roberts, John A.; Bullock, R. Morris; DuBois, Daniel L.

2012-09-25T23:59:59.000Z

169

Solute retention in column liquid chromatography. X. Determination of solute infinite-dilution activity coefficients in methanol, water, and their mixtures, by combined gas-liquid and liquid-liquid chromatography  

SciTech Connect (OSTI)

The Raoult's-law activity coefficients of 3- to 7-carbon aliphatic aldehyde, ketone, ester, and alcohol solutes at infinite dilution in methanol, water, and mixtures of the two and in polydimethysiloxane, all at 293-308 K, have been determined for the first time by appropriate combination of GLC and LLC retention data. The latter data are reported in terms of mole factions, while the former are given in concentration units of molality. However, interpretation of the data is difficult because of the multiplicity of the retention mechanisms. Nevertheless, the combined GLC/LLC technique, which had been applied previously only to pure solvents, is said to offer a number of advantages over static techniques for the determination of solute infinite-dilution activity coefficients with volatile solvents, especially with mixtures of solvents.

Djerki, R.A.; Laub, R.J.

1988-01-01T23:59:59.000Z

170

Probing the Reaction Intermediates for the Water-Gas Shift over Inverse CeOx/Au(111) Catalysts  

SciTech Connect (OSTI)

The water-gas shift (WGS) is an important reaction for the production of molecular H{sub 2} from CO and H{sub 2}O. An inverse CeO{sub x}/Au(1 1 1) catalyst exhibits a very good WGS activity, better than that of copper surfaces or Cu nanoparticles dispersed on a ZnO(0 0 0 {bar 1}) substrate which model current WGS industrial catalysts. In this work we report on intermediates likely to arise during the CO + H{sub 2}O reaction over CeO{sub x}/Au(1 1 1) using soft X-ray photoemission (sXPS) and near-edge X-ray absorption fine structure (NEXAFS). Several potential intermediates including formates (HCOO), carbonates (CO{sub 3}) and carboxylates (HOCO) are considered. Adsorption of HCOOH and CO{sub 2} is used to create both HCOO and CO{sub 3} on the CeO{sub x}/Au(1 1 1) surface, respectively. HCOO appears to have greater stability with desorption temperatures up to 600 K while CO{sub 3} only survives on the surface up to 300 K. On the CeO{sub x}/Au(1 1 1) catalysts, the presence of Ce{sup 3+} leads to the dissociation of H{sub 2}O to give OH groups. We demonstrate experimentally that the OH species are stable on the surface up to 600 K and interact with CO to yield weakly bound intermediates. When there is an abundance of Ce{sup 4+}, the OH concentration is diminished and the likely intermediates are carbonates. As the surface defects are increased and the Ce{sup 3+}/Ce{sup 4+} ratio grows, the OH concentration also grows and both carbonate and formate species are observed on the surface after dosing CO to H{sub 2}O/CeO{sub x}/Au(1 1 1). The addition of ceria nanoparticles to Au(1 1 1) is essential to generate an active WGS catalyst and to increase the production and stability of key reaction intermediates (OH, HCOO and CO{sub 3}).

Rodriguez, J.A.; Senanayake, S.D.; Stacchiola, D.; Evans, J.; Estrella, M.; Barrio-Pliego, L.; Pérez, M.; Hrbek, J.

2010-05-04T23:59:59.000Z

171

Probing the Reaction Intermediates for the Water–gas Shift over Inverse CeOx / Au(1 1 1) Catalysts  

SciTech Connect (OSTI)

The water-gas shift (WGS) is an important reaction for the production of molecular H{sub 2} from CO and H{sub 2}O. An inverse CeO{sub x}/Au(1 1 1) catalyst exhibits a very good WGS activity, better than that of copper surfaces or Cu nanoparticles dispersed on a ZnO(0 0 0 {bar 1}) substrate which model current WGS industrial catalysts. In this work we report on intermediates likely to arise during the CO + H{sub 2}O reaction over CeO{sub x}/Au(1 1 1) using soft X-ray photoemission (sXPS) and near-edge X-ray absorption fine structure (NEXAFS). Several potential intermediates including formates (HCOO), carbonates (CO{sub 3}) and carboxylates (HOCO) are considered. Adsorption of HCOOH and CO{sub 2} is used to create both HCOO and CO{sub 3} on the CeO{sub x}/Au(1 1 1) surface, respectively. HCOO appears to have greater stability with desorption temperatures up to 600 K while CO{sub 3} only survives on the surface up to 300 K. On the CeO{sub x}/Au(1 1 1) catalysts, the presence of Ce{sup 3+} leads to the dissociation of H{sub 2}O to give OH groups. We demonstrate experimentally that the OH species are stable on the surface up to 600 K and interact with CO to yield weakly bound intermediates. When there is an abundance of Ce{sup 4+}, the OH concentration is diminished and the likely intermediates are carbonates. As the surface defects are increased and the Ce{sup 3+}/Ce{sup 4+} ratio grows, the OH concentration also grows and both carbonate and formate species are observed on the surface after dosing CO to H{sub 2}O/CeO{sub x}/Au(1 1 1). The addition of ceria nanoparticles to Au(1 1 1) is essential to generate an active WGS catalyst and to increase the production and stability of key reaction intermediates (OH, HCOO and CO{sub 3}).

Senanayake, S.; Stacchiola, D; Evans, J; Estrella, M; Barrio, L; Perez, M; Hrbek, J; Rodriguez, J

2010-01-01T23:59:59.000Z

172

Energetics of Hydrogen Bond Network Rearrangements in Liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly...

173

Millimeter-wave Radiometer for High Sensitivity Water Vapor Profiling in Arid Regions  

SciTech Connect (OSTI)

Abstract - ProSensing Inc. has developed a G-band (183 GHz) water Vapor Radiometer (GVR) for long-term, unattended measurements of low concentrations of atmospheric water vapor and liquid water. Precipitable water vapor and liquid water path are estimated from zenith brightness temperatures measured from four double-sideband receiver channels, centered at 183.31 1, 3 and 7, and 14 GHz. A prototype ground-based version of the instrument was deployed at the DOE ARM program?s North Slope of Alaska site near Barrow AK in April 2005, where it collected data continuously for one year. A compact, airborne version of this instrument, packaged to operate from a standard 2-D PMS probe canister, has been tested on the ground and is scheduled for test flights in the summer of 2006. This paper presents design details, laboratory test results and examples of retrieved precipitable water vapor and liquid water path from measured brightness temperature data.

Pazmany, Andrew

2006-11-09T23:59:59.000Z

174

Detecting internal corrosion of natural gas transmission pipelines: field tests of probes and systems for real-time corrosion measurement  

SciTech Connect (OSTI)

A field study was conducted to evaluate the use of automated, multi-technique electrochemical corrosion-rate monitoring devices and probes for detecting corrosion in environments similar to those found in natural gas transmission pipelines. It involved measurement of real-time corrosion signals from operating pipelines. Results and interpretation were reported from four different field test locations. Standard flush-mount and custom flange probes were used in four different environments at a gas-gathering site and one environment but two different probe orientations at a natural gas site. These sites were selected to represent normal and upset conditions common in gas transmission pipelines. The environments consisted of two different levels of humidified natural gas, liquid hydrocarbon, and water from natural gas. Probe locations included the 6 and 12 o?clock positions of a natural gas pipeline carrying 2-phase gas/liquid flow. The probe data was monitored using completely remote solar powered systems that provided real-time data transmission via wireless back to a pipeline control station. Data are also presented comparing the ECR probe data to that for coupons used to determine corrosion rate and to detect the presence of microbiologically influenced corrosion (MIC).

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, M.; Kane, R.D. (InterCorr International); Meidinger, B. (Rocky Mountain Oilfield Testing Center)

2005-01-01T23:59:59.000Z

175

Field tests of probes for detecting internal corrosion of natural gas transmission pipelines  

SciTech Connect (OSTI)

A field study was conducted to evaluate the use of electrochemical corrosion rate (ECR) probes for detecting corrosion in environments similar to those found in natural gas transmission pipelines. Results and interpretation will be reported from four different field tests. Flange and flush-mount probes were used in four different environments at a gas-gathering site and one environment but two different orientations at a natural gas plant. These sites were selected to represent normal and upset conditions in a gas transmission pipeline. The environments consisted of 2 different levels of humidified natural gas/organic/water mixtures removed from natural gas, and the environments at the 6 and 12 o'clock positions of a natural gas pipeline carrying 2-phase gas/liquid flow. Data are also presented comparing the ECR probe data to that for coupons used to determine corrosion rate and to detect the presence of microbiologically influenced corrosion (MIC).

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, M.; Cayard, Michael S. (Intercorr International Inc.); Kane, Russell D. (Intercorr International Inc.); Meidinger, Brian (RMOTC-DOE)

2005-01-01T23:59:59.000Z

176

Characterization of water-based liquid scintillator response to gammas and neutrons at varying scintillator-surfactant concentrations  

E-Print Network [OSTI]

Large scale solar neutron and neutrino flux experiments require many tons of bulk liquid organic scintillator to take spectroscopic data of these energetic particles. However, material and chemical concerns make such ...

Chilton, Lauren (Lauren M.)

2012-01-01T23:59:59.000Z

177

Liquid Metal Transformers  

E-Print Network [OSTI]

The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

Sheng, Lei; Liu, Jing

2014-01-01T23:59:59.000Z

178

Structural transformation in supercooled water controls the crystallization rate of ice  

E-Print Network [OSTI]

One of water's unsolved puzzles is the question of what determines the lowest temperature to which it can be cooled before freezing to ice. The supercooled liquid has been probed experimentally to near the homogeneous nucleation temperature TH{\\approx}232 K, yet the mechanism of ice crystallization - including the size and structure of critical nuclei - has not yet been resolved. The heat capacity and compressibility of liquid water anomalously increase upon moving into the supercooled region according to a power law that would diverge at Ts{\\approx}225 K,(1,2) so there may be a link between water's thermodynamic anomalies and the crystallization rate of ice. But probing this link is challenging because fast crystallization prevents experimental studies of the liquid below TH. And while atomistic studies have captured water crystallization(3), the computational costs involved have so far prevented an assessment of the rates and mechanism involved. Here we report coarse-grained molecular simulations with the mW water model(4) in the supercooled regime around TH, which reveal that a sharp increase in the fraction of four-coordinated molecules in supercooled liquid water explains its anomalous thermodynamics and also controls the rate and mechanism of ice formation. The simulations reveal that the crystallization rate of water reaches a maximum around 225 K, below which ice nuclei form faster than liquid water can equilibrate. This implies a lower limit of metastability of liquid water just below TH and well above its glass transition temperature Tg{\\approx}136 K. By providing a relationship between the structural transformation in liquid water, its anomalous thermodynamics and its crystallization rate, this work provides a microscopic foundation to the experimental finding that the thermodynamics of water determines the rates of homogeneous nucleation of ice.(5)

Emily B. Moore; Valeria Molinero

2011-09-27T23:59:59.000Z

179

Liquid-Liquid Extraction Processes  

E-Print Network [OSTI]

Liquid-liquid extraction is the separation of one or more components of a liquid solution by contact with a second immiscible liquid called the solvent. If the components in the original liquid solution distribute themselves differently between...

Fair, J. R.; Humphrey, J. L.

1983-01-01T23:59:59.000Z

180

Design of a Shadowband Spectral Radiometer for the Retrieval of Thin Cloud Optical Depth, Liquid Water Path, and the Effective Radius  

SciTech Connect (OSTI)

The design and operation of a Thin-Cloud Rotating Shadowband Radiometer (TCRSR) described here was used to measure the radiative intensity of the solar aureole and enable the simultaneous retrieval of cloud optical depth, drop effective radius, and liquid water path. The instrument consists of photodiode sensors positioned beneath two narrow metal bands that occult the sun by moving alternately from horizon to horizon. Measurements from the narrowband 415-nm channel were used to demonstrate a retrieval of the cloud properties of interest. With the proven operation of the relatively inexpensive TCRSR instrument, its usefulness for retrieving aerosol properties under cloud-free skies and for ship-based observations is discussed.

Bartholomew M. J.; Reynolds, R. M.; Vogelmann, A. M.; Min, Q.; Edwards, R.; Smith, S.

2011-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Development of Nanofluidic Cells for Ultrafast X-ray Studies of Water  

SciTech Connect (OSTI)

In order to study the molecular structure and dynamics of liquid water with soft x-ray probes, samples with nanoscale dimensions are needed. This paper describes a simple method for preparing nanofluidic water cells. The idea is to confine a thin layer of water between two silicon nitride windows. The windows are 1 mm x 1 mm and 0.5 mm x 0.5 mm in size and have a thickness of 150 nm. The thickness of the water layer was measured experimentally by probing the infrared spectrum of water in the cells with a Fourier Transform InfraRed (FTIR) apparatus and from soft x-ray static measurements at the Advanced Light Source (ALS) at Lawrence Berkeley National Laboratory. Water layers ranging from 10 nm to more than 2 {micro}m were observed. Evidence for changes in the water structure compared to bulk water is observed in the ultrathin cells.

Irizarry, Melvin E.; /Puerto Rico U., Mayaguez /SLAC

2006-08-23T23:59:59.000Z

182

Acoustic attenuation, phase and group velocities in liquid-filled pipes: Theory, experiment, and examples of water and  

E-Print Network [OSTI]

­311 1971 formulation, which predicts the phase speed of propagating axisymmetric modes inside a liquid speed, of the modes as a function of frequency. Measurements of the sound speeds and the attenuations investigated and the measured sound speeds and the damping of the modes were compared with the theoretical

Sóbester, András

183

Mach flow angularity probes for scramjet engine flow path diagnostics  

SciTech Connect (OSTI)

Mach-flow angularity (MFA) probes were developed for use in scramjet flow path probe rakes. Prototype probes were fabricated to demonstrate the assembly processes (numerical control machining, furnace brazing, and electron beam welding). Tests of prototype probes confirmed the thermal durability margins and life cycle. Selected probes were calibrated in air at Mach numbers from 1.75 to 6.0. Acceptance criteria for the production probes stressed thermal durability and pressure (and, consequently, Mach number) measurement quality. This new water-cooled MFA probe has 0.397-cm shaft diameter and is capable of withstanding heat fluxes of 2.724 kW/sq cm.

Jalbert, P.A.; Hiers, R.S. Jr. [Sverdrup Technology, Inc., Arnold AFS, TN (United States)

1993-12-31T23:59:59.000Z

184

Liquid chromatographic analysis of coal surface properties. Quarterly progress report, September--December 1991  

SciTech Connect (OSTI)

The main objectives of this proposed research are to refine further the inverse liquid chromatography technique for the study of surface properties of raw coals, treated coals and coal minerals in water, to evaluate relatively surface properties of raw coals, treated coals and coal minerals by inverse liquid chromatography, and to evaluate floatability of various treated coals in conjunction with surface properties of coals. Alcohols such as methanol, ethanol, isopropanol, isobutanol, tert-butanol, heptanol, 1-hexadecanol, 2-methyl-pentanol, 4-methyl-2-penthanol (methylisobutyl carbinol), n-octanol, s-octanol, and cyclohexanol as probe compounds are utilized to evaluate hydrophilicity of coals and coal minerals. N-alkanes such as hexane, heptane and octane, and stearic acid are employed as probe compounds to evaluate hydrophobicity of coals and coal minerals. Aromatic compounds such as benzene and toluene as probe compounds are used to examine aromaticity of coal surface. Aromatic acids such as o-cresol, m-cresol, p-cresol, phenol and B-naphthol are used to detect aromatic acidic sites of coal surface. Hydrophilicity, hydrophobicity and aromaticity of surfaces for either raw coals or treated coals in water are relatively determined by evaluating both equilibrium physical/chemical adsorption and dynamic adsorption of probe compounds on various raw coals and treated coals to compare affinities of coals for water.

Kwon, K.C.

1991-12-31T23:59:59.000Z

185

Influence of wettability on liquid water transport in gas diffusion layer of proton exchange membrane fuel cells (PEMFC)  

E-Print Network [OSTI]

Water management is a key factor that limits PEFC's performance. We show how insights into this problem can be gained from pore-scale simulations of water invasion in a model fibrous medium. We explore the influence of contact angle on the water invasion pattern and water saturation at breakthrough and show that a dramatic change in the invasion pattern, from fractal to compact, occurs as the system changes from hydrophobic to hydrophilic. Then, we explore the case of a system of mixed wettability, i.e. containing both hydrophilic and hydrophobic pores. The saturation at breakthrough is studied as a function of the fraction of hydrophilic pores. The results are discussed in relation with the water management problem, the optimal design of a GDL and the fuel cell performance degradation mechanisms. We outline how the study could be extended to 3D systems, notably from binarised images of GDLs obtained by X ray microtomography.

Hamza Chraibi; L. Ceballos; M. Prat; Michel Quintard; Alexandre Vabre

2009-09-16T23:59:59.000Z

186

Liquid Metal Transformers  

E-Print Network [OSTI]

The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clarified. Such events are hard to achieve otherwise on rigid metal or conventional liquid spheres. This finding has both fundamental and practical significances which suggest a generalized way of making smart soft machine, collecting discrete metal fluids, as well as flexibly manipulating liquid metal objects including accompanying devices.

Lei Sheng; Jie Zhang; Jing Liu

2014-01-30T23:59:59.000Z

187

Development of a generalized correlation for phase-velocity measurements obtained from impedance-probe pairs in two-phase flow systems. [PWR  

SciTech Connect (OSTI)

A flag type electrical impedance probe has been developed at the Oak Ridge National Lab (ORNL) to measure liquid- and vapor-phase velocities in steam-water mixtures flowing through rod bundles. Measurements are made by utilizing the probes in pairs, installed in line, parallel to the flow direction, and extending out into the flow channel. The present study addresses performance difficulties by examining from a fundamental point of view the two-phase flow system which the impedance probes typically operate in. Specifically, the governing equations (continuity, momentum, energy) were formulated for both air-water and steam-water systems, and then subjected to a scaling analysis. The scaling analysis yielded the appropriate dimensionless parameters of significance in both kinds of systems. Additionally, with the aid of experimental data obtained at ORNL, those parameters of significant magnitude were established. As a result, a generalized correlation was developed for liquid and vapor phase velocities that makes it possible to employ the impedance probe velocity measurement technique in a wide variety of test configurations and fluid combinations.

Hsu, C.T.; Keshock, E.G.; McGill, R.N.

1983-01-01T23:59:59.000Z

188

Theoretical Studies of Solid-Liquid Interfaces: Molecular Interactions at the MgO(001)-Water Interface  

E-Print Network [OSTI]

as these compounds are major components of rocks, soils, and airborne dust particles. In addition, metal oxides often groups.2-6 Recently, classical molecular mechanical models appeared which can address the structural chemistry are needed. A few quantum mechanical calculations concerning the properties of water and hydroxyl

Truong, Thanh N.

189

The sweet spot of forward osmosis: Treatment of produced water, drilling wastewater, and other complex and difficult liquid streams  

E-Print Network [OSTI]

, and especially oil and gas (O&G) exploration and production wastewaters. High salt concentrations, decentralized generated during exploration and production (E&P) (e.g., drilling muds, hydraulic fracturing flowback water processes, have identified its sweet spot: treatment and desalination of complex industrial streams

190

Hydrodynamic ultrasonic probe  

DOE Patents [OSTI]

An improved probe for in-service ultrasonic inspection of long lengths of a workpiece, such as small diameter tubing from the interior. The improved probe utilizes a conventional transducer or transducers configured to inspect the tubing for flaws and/or wall thickness variations. The probe utilizes a hydraulic technique, in place of the conventional mechanical guides or bushings, which allows the probe to move rectilinearly or rotationally while preventing cocking thereof in the tube and provides damping vibration of the probe. The probe thus has lower friction and higher inspection speed than presently known probes.

Day, Robert A. (Livermore, CA); Conti, Armond E. (San Jose, CA)

1980-01-01T23:59:59.000Z

191

1.2 What pressure difference must be generated across the length of a 15 cm vertical drinking straw in order to drink a water-like liquid of density 1.0 g cm-3  

E-Print Network [OSTI]

in order to drink a water-like liquid of density 1.0 g cm-3 ? 1.6 Charles' law is sometimes expressed1.2 What pressure difference must be generated across the length of a 15 cm vertical drinking straw

Findley, Gary L.

192

Probing the Interiors of the Ice Giants: Shock Compression of Water to 700 GPa and 3.8 g/cm³  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Recently, there has been a tremendous increase in the number of identified extrasolar planetary systems. Our understanding of their formation is tied to exoplanet internal structure models, which rely upon equations of state of light elements and compounds such as water. Here, we present shock compression data for water with unprecedented accuracy that show that water equations of state commonly used in planetary modeling significantly overestimate the compressibility at conditions relevant to planetary interiors. Furthermore, we show that its behavior at these conditions, including reflectivity and isentropic response, is well-described by a recent first-principles based equation of state. These findings advocate that this water model be used as the standard for modeling Neptune, Uranus, and “hot Neptune” exoplanets and should improve our understanding of these types of planets.

Knudson, M. D.; Desjarlais, M. P.; Lemke, R. W.; Mattsson, T. R.; French, M.; Nettelmann, N.; Redmer, R.

2012-02-01T23:59:59.000Z

193

Numerical Simulation of Hydrodynamics of a Heavy Liquid Drop Covered by Vapor Film in a Water Pool  

SciTech Connect (OSTI)

A numerical study on the hydrodynamics of a droplet covered by vapor film in water pool is carried out. Two level set functions are used as to implicitly capture the interfaces among three immiscible fluids (melt-drop, vapor and coolant). This approach leaves only one set of conservation equations for the three phases. A high-order Navier-Stokes solver, called Cubic-Interpolated Pseudo-Particle (CIP) algorithm, is employed in combination with level set approach, which allows large density ratios (up to 1000), surface tension and jump in viscosity. By this calculation, the hydrodynamic behavior of a melt droplet falling into a volatile coolant is simulated, which is of great significance to reveal the mechanism of steam explosion during a hypothetical severe reactor accident. (authors)

Ma, W.M.; Yang, Z.L.; Giri, A.; Sehgal, B.R. [Royal Institute of Technology (KTH), Drottning Kristinas vaeg 33 A, 100 44, Stockholm (Sweden)

2002-07-01T23:59:59.000Z

194

Early Events in Ionic Liquid Radiation Chemistry  

SciTech Connect (OSTI)

Ionic liquids are interesting and useful materials whose solvation time scales are up to thousands of times longer than in conventional solvents. The extended lifetimes of pre-solvated electrons and other energetic species in ionic liquids has profound consequences for the radiolytic product distributions and reactivity patterns. We use a newly developed, multiplexed variation of pulse-probe spectroscopy to measure the kinetics of the early dynamical and reactive events in ionic liquids.

Wishart, J.F.; Cook, A.; Rimmer, R.D.; Gohdo, M.

2010-09-14T23:59:59.000Z

195

INEEL Liquid Effluent Inventory  

SciTech Connect (OSTI)

The INEEL contractors and their associated facilities are required to identify all liquid effluent discharges that may impact the environment at the INEEL. This liquid effluent information is then placed in the Liquid Effluent Inventory (LEI) database, which is maintained by the INEEL prime contractor. The purpose of the LEI is to identify and maintain a current listing of all liquid effluent discharge points and to identify which discharges are subject to federal, state, or local permitting or reporting requirements and DOE order requirements. Initial characterization, which represents most of the INEEL liquid effluents, has been performed, and additional characterization may be required in the future to meet regulations. LEI information is made available to persons responsible for or concerned with INEEL compliance with liquid effluent permitting or reporting requirements, such as the National Pollutant Discharge Elimination System, Wastewater Land Application, Storm Water Pollution Prevention, Spill Prevention Control and Countermeasures, and Industrial Wastewater Pretreatment. The State of Idaho Environmental Oversight and Monitoring Program also needs the information for tracking liquid effluent discharges at the INEEL. The information provides a baseline from which future liquid discharges can be identified, characterized, and regulated, if appropriate. The review covered new and removed buildings/structures, buildings/structures which most likely had new, relocated, or removed LEI discharge points, and at least 10% of the remaining discharge points.

Major, C.A.

1997-06-01T23:59:59.000Z

196

Erasing no-man's land by thermodynamically stabilizing the liquid-liquid transition in tetrahedral particles  

E-Print Network [OSTI]

compressibility KT and the isobaric heat capacity CP . In the LLCP hypothesis, the density anomalies of waterErasing no-man's land by thermodynamically stabilizing the liquid-liquid transition in tetrahedral, Sapienza, Universit´a di Roma, Piazzale Aldo Moro 2, I-00185, Roma, Italy. EFFECTS OF THE LIQUID-LIQUID

Loss, Daniel

197

Ultrafast scanning probe microscopy  

DOE Patents [OSTI]

An ultrafast scanning probe microscopy method for achieving subpicosecond-temporal resolution and submicron-spatial resolution of an observation sample. In one embodiment of the present claimed invention, a single short optical pulse is generated and is split into first and second pulses. One of the pulses is delayed using variable time delay means. The first pulse is then directed at an observation sample located proximate to the probe of a scanning probe microscope. The scanning probe microscope produces probe-sample signals indicative of the response of the probe to characteristics of the sample. The second pulse is used to modulate the probe of the scanning probe microscope. The time delay between the first and second pulses is then varied. The probe-sample response signal is recorded at each of the various time delays created between the first and second pulses. The probe-sample response signal is then plotted as a function of time delay to produce a cross-correlation of the probe sample response. In so doing, the present invention provides simultaneous subpicosecond-temporal resolution and submicron-spatial resolution of the sample.

Weiss, Shimon (El Cerrito, CA); Chemla, Daniel S. (Kensington, CA); Ogletree, D. Frank (El Cerrito, CA); Botkin, David (San Francisco, CA)

1995-01-01T23:59:59.000Z

198

Ultrafast scanning probe microscopy  

DOE Patents [OSTI]

An ultrafast scanning probe microscopy method is described for achieving subpicosecond-temporal resolution and submicron-spatial resolution of an observation sample. In one embodiment of the present claimed invention, a single short optical pulse is generated and is split into first and second pulses. One of the pulses is delayed using variable time delay means. The first pulse is then directed at an observation sample located proximate to the probe of a scanning probe microscope. The scanning probe microscope produces probe-sample signals indicative of the response of the probe to characteristics of the sample. The second pulse is used to modulate the probe of the scanning probe microscope. The time delay between the first and second pulses is then varied. The probe-sample response signal is recorded at each of the various time delays created between the first and second pulses. The probe-sample response signal is then plotted as a function of time delay to produce a cross-correlation of the probe sample response. In so doing, the present invention provides simultaneous subpicosecond-temporal resolution and submicron-spatial resolution of the sample. 6 Figs.

Weiss, S.; Chemla, D.S.; Ogletree, D.F.; Botkin, D.

1995-05-16T23:59:59.000Z

199

Closed-field capacitive liquid level sensor  

DOE Patents [OSTI]

A liquid level sensor based on a closed field circuit comprises a ring oscillator using a symmetrical array of plate units that creates a displacement current. The displacement current varies as a function of the proximity of a liquid to the plate units. The ring oscillator circuit produces an output signal with a frequency inversely proportional to the presence of a liquid. A continuous liquid level sensing device and a two point sensing device are both proposed sensing arrangements. A second set of plates may be located inside of the probe housing relative to the sensing plate units. The second set of plates prevent any interference between the sensing plate units.

Kronberg, J.W.

1995-01-01T23:59:59.000Z

200

ARM - Measurement - Liquid water content  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearch Relatedcontent ARM Data Discovery Browse Data Comments? We would

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

ARM - Measurement - Liquid water path  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc Documentation RUC : XDCResearch Relatedcontent ARM Data Discovery Browse Data Comments? We

202

Quantum fluctuations and isotope effects in ab initio descriptions of water  

E-Print Network [OSTI]

Nuclear quantum effects, such as zero-point energy and tunneling, cause significant changes to the structure and dynamics of hydrogen bonded systems such as liquid water. However, due to the current inability to simulate liquid water using an exact description of its electronic structure, the interplay between nuclear and electronic quantum effects remains unclear. Here we use simulations that incorporate the quantum mechanical nature of both the nuclei and electrons to provide a fully ab initio determination of the particle quantum kinetic energies, free energy change upon exchanging hydrogen for deuterium and the isotope fractionation ratio in water. These properties, which selectively probe the quantum nature of the nuclear degrees of freedom, allow us to make direct comparison to recent experiments and elucidate how electronic exchange and correlation and nuclear quantum fluctuations determine the structure of the hydrogen bond in water.

Lu Wang; Michele Ceriotti; Thomas E. Markland

2014-06-24T23:59:59.000Z

203

Ultrafast photo-acoustic spectroscopy of super-cooled liquids  

E-Print Network [OSTI]

Picosecond laser ultrasonic techniques for acoustic wave generation and detection were adapted to probe longitudinal and transverse acoustic waves in liquids at gigahertz frequencies. The experimental effort was designed ...

Klieber, Christoph

2010-01-01T23:59:59.000Z

204

Spinon-phonon interaction in algebraic spin liquids  

E-Print Network [OSTI]

Motivated by a search for experimental probes to access the physics of fractionalized excitations called spinons in spin liquids, we study the interaction of spinons with lattice vibrations. We consider the case of algebraic ...

Serbyn, Maksym

205

Freezing of a Liquid Marble  

E-Print Network [OSTI]

In this study, we present for the first time the observations of a freezing liquid marble. In the experiment, liquid marbles are gently placed on the cold side of a Thermo-Electric Cooler (TEC) and the morphological changes are recorded and characterized thereafter. These liquid marbles are noticed to undergo a shape transition from a spherical to a flying-saucer shaped morphology. The freezing dynamics of liquid marbles is observed to be very different from that of a freezing water droplet on a superhydrophobic surface. For example, the pointy tip appearing on a frozen water drop could not be observed for a frozen liquid marble. In the end, we highlight a possible explanation for the observed morphology.

Ali Hashmi; Adam Strauss; Jie Xu

2012-07-03T23:59:59.000Z

206

Probing Strain-Induced Changes in Electronic Structure with XMCD  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - SeptemberMicroneedles for4-16 FORPoints of ContactLiquidProbingProbingProbing

207

Carbon nanotube based electromechanical probes  

E-Print Network [OSTI]

Electromechanical probing applications continuously require smaller pitches, faster manufacturing and lower electrical resistance. Conventional techniques, such as MEMS based cantilever probes have their shortcomings in ...

Yaglioglu, Onnik, 1976-

2007-01-01T23:59:59.000Z

208

Wireless remote liquid level detector and indicator for well testing  

DOE Patents [OSTI]

An acoustic system is provided for measuring the fluid level in oil, gas or water wells under pressure conditions that does not require an electrical link to the surface for level detection. A battery powered sound transmitter is integrated with a liquid sensor in the form of a conductivity probe, enclosed in a sealed housing which is lowered into a well by means of a wire line reel assembly. The sound transmitter generates an intense identifiable acoustic emission when the sensor contacts liquid in the well. The acoustic emissions propagate up the well which functions as a waveguide and are detected by an acoustic transducer. The output signal from the transducer is filtered to provide noise rejection outside of the acoustic signal spectrum. The filtered signal is used to indicate to an operator the liquid level in the well has been reached and the depth is read from a footage counter coupled with the wire line reel assembly at the instant the sound signal is received.

Fasching, George E. (Morgantown, WV); Evans, Donald M. (Point Marion, PA); Ernest, John H. (Morgantown, WV)

1985-01-01T23:59:59.000Z

209

Foldable polymers as probes  

DOE Patents [OSTI]

Disclosed herein are novel probes, which can be used to detect and identify target molecules of interest in a sample. The disclosed probes can be used to monitor conformational changes induced by molecular recognition events in addition to providing signaling the presence and/or identity of a target molecule. Methods, including solid phase synthesis techniques, for making probe molecules that exhibit changes in their optical properties upon target molecule binding are described in the disclosure. Also disclosed herein are novel chromophore moieties, which have tailored fluorescent emission spectra.

Li, Alexander D. Q. (Pullman, WA); Wang, Wei (Pullman, WA)

2009-07-07T23:59:59.000Z

210

Chemical sensing flow probe  

SciTech Connect (OSTI)

A new chemical probe determines the properties of an analyte using the light absorption of the products of a reagent/analyte reaction. The probe places a small reaction volume in contact with a large analyte volume. Analyte diffuses into the reaction volume. Reagent is selectively supplied to the reaction volume. The light absorption of the reaction in the reaction volume indicates properties of the original analyte. The probe is suitable for repeated use in remote or hostile environments. It does not require physical sampling of the analyte or result in significant regent contamination of the analyte reservoir. 7 figs.

Laguna, G.R.; Peter, F.J.; Butler, M.A.

1999-02-16T23:59:59.000Z

211

Probing metal solidification nondestructively  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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212

Chemical sensing flow probe  

DOE Patents [OSTI]

A new chemical probe determines the properties of an analyte using the light absorption of the products of a reagent/analyte reaction. The probe places a small reaction volume in contact with a large analyte volume. Analyte diffuses into the reaction volume. Reagent is selectively supplied to the reaction volume. The light absorption of the reaction in the reaction volume indicates properties of the original analyte. The probe is suitable for repeated use in remote or hostile environments. It does not require physical sampling of the analyte or result in significant regent contamination of the analyte reservoir.

Laguna, George R. (Albuquerque, NM); Peter, Frank J. (Albuquerque, NM); Butler, Michael A. (Albuquerque, NM)

1999-01-01T23:59:59.000Z

213

ccsd00001732, Development behavior of liquid plasma produced by  

E-Print Network [OSTI]

water with a melted NaCl is used as a test liquid. The liquid plasma is produced by the fundamental waveccsd­00001732, version 2 ­ 7 Nov 2004 Development behavior of liquid plasma produced by YAG laser the hazardous material called the environment material. Then, the plasma produced in liquid by the laser light

214

NMR Studies on the Temperature-Dependent Dynamics of Confined Water  

E-Print Network [OSTI]

We use $^2$H NMR to study the rotational motion of supercooled water in silica pores of various diameters, specifically, in the MCM-41 materials C10, C12, and C14. Combination of spin-lattice relaxation, line-shape, and stimulated-echo analyses allows us to determine correlation times in very broad time and temperature ranges. For the studied pore diameters, 2.1-2.9 nm, we find two crossovers in the temperature-dependent correlation times of liquid water upon cooling. At 220-230 K, a first kink in the temperature dependence is accompanied by a solidification of a fraction of the confined water, implying that the observed crossover is due to a change from bulk-like to interface-dominated water dynamics, rather than to a liquid-liquid phase transition. Moreover, the results provide evidence that $\\alpha$ process-like dynamics is probed above the crossover temperature, whereas $\\beta$ process-like dynamics is observed below. At 180-190 K, we find a second change of the temperature dependence, which resembles that reported for the $\\beta$ process of supercooled liquids during the glass transition, suggesting a value of $T_g\\!\\approx\\!185$ K for interface-affected liquid water. In the high-temperature range, $T\\!>\\!225$ K, the temperature dependence of water reorientation is weaker in the smaller C10 pores than in the larger C12 and C14 pores, where it is more bulk-like, indicating a significant effect of the silica confinement on the $\\alpha$ process of water in the former 2.1 nm confinement. By contrast, the temperature dependence of water reorientation is largely independent of the confinement size and described by an Arrhenius law with an activation energy of $E_a\\!\\approx\\!0.5\\ $eV in the low-temperature range, $T\\!water.

Matthias Sattig; Stefan Reutter; Franz Fujara; Mayke Werner; Gerd Buntkowsky; Michael Vogel

2014-07-16T23:59:59.000Z

215

Structure and dynamics of liquid water on rutile TiO2(110) Li-Min Liu, Changjun Zhang, Geoff Thornton, and Angelos Michaelides  

E-Print Network [OSTI]

those between water and titanium dioxide TiO2 . Water-TiO2 interfaces are relevant to photocatalysis on which adsorption state the water molecules are in at the interface: dissociated or molecular? Many, density-functional theory DFT studies predict either molecular or dissociative adsorption on the perfect

Alavi, Ali

216

Spiers Memorial Lecture Recent experimental advances in studies of liquid/liquid  

E-Print Network [OSTI]

complicated processes such as molecular transport across cell membranes. A variety of techniques have been on the interaction of a hydrophobic surface with water, and ion and solute transport across these and other liquid/hydrophilic properties of liquid/ liquid interfaces. In biological systems, protein folding and membrane formation rely

Richmond, Geraldine L.

217

Probing Organic Transistors with Infrared Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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218

Probing Organic Transistors with Infrared Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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219

Convective heat flow probe  

DOE Patents [OSTI]

A convective heat flow probe device is provided which measures heat flow and fluid flow magnitude in the formation surrounding a borehole. The probe comprises an elongate housing adapted to be lowered down into the borehole; a plurality of heaters extending along the probe for heating the formation surrounding the borehole; a plurality of temperature sensors arranged around the periphery of the probe for measuring the temperature of the surrounding formation after heating thereof by the heater elements. The temperature sensors and heater elements are mounted in a plurality of separate heater pads which are supported by the housing and which are adapted to be radially expanded into firm engagement with the walls of the borehole. The heat supplied by the heater elements and the temperatures measured by the temperature sensors are monitored and used in providing the desired measurements. The outer peripheral surfaces of the heater pads are configured as segments of a cylinder and form a full cylinder when taken together. A plurality of temperature sensors are located on each pad so as to extend along the length and across the width thereof, with a heating element being located in each pad beneath the temperature sensors. An expansion mechanism driven by a clamping motor provides expansion and retraction of the heater pads and expandable packet-type seals are provided along the probe above and below the heater pads.

Dunn, J.C.; Hardee, H.C.; Striker, R.P.

1984-01-09T23:59:59.000Z

220

Multispectral imaging probe  

DOE Patents [OSTI]

A multispectral imaging probe delivers a range of wavelengths of excitation light to a target and collects a range of expressed light wavelengths. The multispectral imaging probe is adapted for mobile use and use in confined spaces, and is sealed against the effects of hostile environments. The multispectral imaging probe comprises a housing that defines a sealed volume that is substantially sealed from the surrounding environment. A beam splitting device mounts within the sealed volume. Excitation light is directed to the beam splitting device, which directs the excitation light to a target. Expressed light from the target reaches the beam splitting device along a path coaxial with the path traveled by the excitation light from the beam splitting device to the target. The beam splitting device directs expressed light to a collection subsystem for delivery to a detector.

Sandison, David R. (Moriarty, NM); Platzbecker, Mark R. (Albuquerque, NM); Descour, Michael R. (Tucson, AZ); Armour, David L. (Albuquerque, NM); Craig, Marcus J. (Albuquerque, NM); Richards-Kortum, Rebecca (Austin, TX)

1999-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Multispectral imaging probe  

DOE Patents [OSTI]

A multispectral imaging probe delivers a range of wavelengths of excitation light to a target and collects a range of expressed light wavelengths. The multispectral imaging probe is adapted for mobile use and use in confined spaces, and is sealed against the effects of hostile environments. The multispectral imaging probe comprises a housing that defines a sealed volume that is substantially sealed from the surrounding environment. A beam splitting device mounts within the sealed volume. Excitation light is directed to the beam splitting device, which directs the excitation light to a target. Expressed light from the target reaches the beam splitting device along a path coaxial with the path traveled by the excitation light from the beam splitting device to the target. The beam splitting device directs expressed light to a collection subsystem for delivery to a detector. 8 figs.

Sandison, D.R.; Platzbecker, M.R.; Descour, M.R.; Armour, D.L.; Craig, M.J.; Richards-Kortum, R.

1999-07-27T23:59:59.000Z

222

Probing Mercury's Partnering Preferences  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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223

Probing metal solidification nondestructively  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - SeptemberMicroneedles for4-16 FORPoints ofProbing Strain-Induced ChangesProbing

224

Atom Probe Tomography | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone byDear Friend,Arthur J. NozikAtom Probe Tomography Atom Probe

225

Two-phase air-water stratified flow measurement using ultrasonic techniques  

SciTech Connect (OSTI)

In this paper, a time resolved ultrasound system was developed for investigating two-phase air-water stratified flow. The hardware of the system includes a pulsed wave transducer, a pulser/receiver, and a digital oscilloscope. The time domain cross correlation method is used to calculate the velocity profile along ultrasonic beam. The system is able to provide velocities with spatial resolution of around 1mm and the temporal resolution of 200?s. Experiments were carried out on single phase water flow and two-phase air-water stratified flow. For single phase water flow, the flow rates from ultrasound system were compared with those from electromagnetic flow (EM) meter, which showed good agreement. Then, the experiments were conducted on two-phase air-water stratified flow and the results were given. Compared with liquid height measurement from conductance probe, it indicated that the measured velocities were explainable.

Fan, Shiwei; Yan, Tinghu; Yeung, Hoi [School of Engineering, Cranfield University, Cranfield, Bedfordshire MK43 0AL (United Kingdom)

2014-04-11T23:59:59.000Z

226

Water Rock Interaction [WRI 14] Macroscopic thermodynamics of interfaces at the water pore  

E-Print Network [OSTI]

they should be relevant. 2. Liquid-air interfacial curvature Capillary water in non-saturated porous system 7327, BP 36009, 45060 Orléans, France Abstract The possible role of liquid-air and solid-liquid (liquid-air concave curvature toward air), and curved solid as a function of pore sizes (solid-liquid

Boyer, Edmond

227

Fireside corrosion probes for fossil fuel combustion  

SciTech Connect (OSTI)

Electrochemical corrosion rate probes have been constructed and tested along with mass loss coupons in environments consisting of N2/O2/CO2/SO2 plus water vapor. Temperatures ranged from 450° to 700°C. Results show that electrochemical corrosion rates for ash-covered mild steel are a function of time, temperature, and gaseous environment. Correlation between the electrochemical and mass loss corrosion rates was poor.

Covino, B.S., Jr.; Bullard, S.J.; Ziomek-Moroz, M.; Holcomb, G.R.; Eden, D.A. (Intercorr International, Houston, TX)

2006-03-01T23:59:59.000Z

228

Grabbing water  

E-Print Network [OSTI]

We introduce a novel technique for grabbing water with a flexible solid. This new passive pipetting mechanism was inspired by floating flowers and relies purely on the coupling of the elasticity of thin plates and the hydrodynamic forces at the liquid interface. Developing a theoretical model has enabled us to design petal-shaped objects with maximum grabbing capacity.

P. M. Reis; J. Hure; S. Jung; J. W. M. Bush; C. Clanet

2012-07-16T23:59:59.000Z

229

Nuclear quantum effects in water  

E-Print Network [OSTI]

In this work, a path integral Car-Parrinello molecular dynamics simulation of liquid water is performed. It is found that the inclusion of nuclear quantum effects systematically improves the agreement of first principles simulations of liquid water with experiment. In addition, the proton momentum distribution is computed utilizing a recently developed open path integral molecular dynamics methodology. It is shown that these results are in good agreement with neutron Compton scattering data for liquid water and ice.

Joseph A. Morrone; Roberto Car

2008-03-25T23:59:59.000Z

230

Orifice mixing of immiscible liquids  

E-Print Network [OSTI]

solution (7). The present study of orif1ce mixing is a continuation of previous research on this project which yielded a relationship explaining the effect of operating conditions upon the format1on of 1nterfacial area for the system water-kerosene.... The experimental technique evolved by Helch (18), Vesselhoff (19), McNair (8), and Scott (IA) was changed only slightly. Their work on water-kerosene was repeated for the liquid pairs trichloroethylene-water, heptanol-water, 20 per oent aqueous sucrose-kerosene...

McDonough, Joseph Aloysius

1960-01-01T23:59:59.000Z

231

Haze Formation and Behavior in Liquid-Liquid Extraction Processes  

SciTech Connect (OSTI)

Aqueous haze formation and behavior was studied in the liquid-liquid system tri-n-butyl phosphate in odorless kerosene and 3M nitric acid with uranyl nitrate and cesium nitrate representing the major solute and an impurity, respectively. A pulsed column, mixer-settler and centrifugal contactor were chosen to investigate the effect of different turbulence characteristics on the manifestation of haze since these contactors exhibit distinct mixing phenomena. The dispersive processes of drop coalescence and breakage, and water precipitation in the organic phase were observed to lead to the formation of haze drops of {approx}1 um in diameter. The interaction between the haze and primary drops of the dispersion was critical to the separation efficiency of the liquid-liquid extraction equipment. Conditions of high power input and spatially homogeneous mixing enabled the haze drops to become rapidly assimilated within the dispersion to maximize the scrub performance and separation efficiency of the equipment.

Arm, Stuart T.; Jenkins, J. A.

2006-07-31T23:59:59.000Z

232

Adsorptive Drying of Organic Liquids- An Update  

E-Print Network [OSTI]

reactions lowering yields and compro mising product quality. In these several situations where liquids are involved, any of the following means may be used to lower the water content: Inert Gas Purging Liquid Extraction Freeze Drying Pervaporation... Fractional Distillation Adsorption Although fractional distillation and adsorption are almost exclusively used, the others are included to complete the list. Inert Gas Purging This method can be used to dry high boiling liquids such as gear oils...

Joshi, S.; Humphrey, J. L.; Fair, J. R.

233

Probing Strain-Induced Changes in Electronic Structure with XMCD  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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234

Synchrotrons Explore Water's Molecular Mysteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Laboratory's Advanced Light Source, scientists observed a surprisingly dense form of water that remained liquid well beyond its typical freezing point. Researchers applied a...

235

A numerical method for the simulation of low Mach number liquid-gas flows.  

E-Print Network [OSTI]

consisting of the air bubbles and the liquid water are investigated. They are driven by a heat supply

Paris-Sud XI, Université de

236

Water Management in A PEMFC: Water Transport Mechanism and Material  

E-Print Network [OSTI]

Water Management in A PEMFC: Water Transport Mechanism and Material Degradation in Gas Diffusion on the water management of the PEMFC, namely the transport of product water (both liquid and vapor its water management performance and func- tion as indicators of the degradation of GDL material

Kandlikar, Satish

237

Dark Energy Probes of Dark Energy  

E-Print Network [OSTI]

19/12/2013 1 Dark Energy Probes of Dark Energy Probes Dark Energy Supernovae Ia probing luminosity (Betti numbers) #12;19/12/2013 2 Dark Energy Probes: Comparison Method Strengths Weaknesses Systematics

Weijgaert, Rien van de

238

Sonar probing of concrete  

E-Print Network [OSTI]

ABSTRACT Sonar Probing of Concrete (May 1988) John H. Mims, B. A. , Carleton College Chairman of Advisory Committee: Dr. Robert R, Unterberger Two systems were used for acoustical tests at concrete dams. The first system used a pair of donated... reflections from several concrete-air interfaces at the Norfork Dam, Arkansas. A reflection between two walls in the dam's operating gallery which were 6. 73 m apart was recorded at 3. 4 ms (peak value). After subtracting the appropriate delays, this value...

Mims, John Hornsby

1988-01-01T23:59:59.000Z

239

2.1 What Does Life Water on Earth  

E-Print Network [OSTI]

1 2.1 What Does Life Require? Water Water on Earth Can exist in all 3 physical states Liquid Solid Gas Not all animals must drink liquid water. Can get water from food. Can get water through metabolism of glucose. Water on Earth Source % of Supply Oceans 97.08 Ice Sheets and Glaciers 1.99 Ground

Cochran-Stafira, D. Liane

240

Liquid electrode  

DOE Patents [OSTI]

A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

Ekechukwu, A.A.

1994-07-05T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Sewage sludge dewatering using flowing liquid metals  

DOE Patents [OSTI]

A method and apparatus for reducing the moisture content of a moist sewage sludge having a moisture content of about 50% to 80% and formed of small cellular micro-organism bodies having internally confined water is provided. A hot liquid metal is circulated in a circulation loop and the moist sewage sludge is injected in the circulation loop under conditions of temperature and pressure such that the confined water vaporizes and ruptures the cellular bodies. The vapor produced, the dried sludge, and the liquid metal are then separated. Preferably, the moist sewage sludge is injected into the hot liquid metal adjacent the upstream side of a venturi which serves to thoroughly mix the hot liquid metal and the moist sewage sludge. The venturi and the drying zone after the venturi are preferably vertically oriented. The dried sewage sludge recovered is available as a fuel and is preferably used for heating the hot liquid metal.

Carlson, Larry W. (Oswego, IL)

1986-01-01T23:59:59.000Z

242

Experimental probes of axions  

SciTech Connect (OSTI)

Experimental searches for axions or axion-like particles rely on semiclassical phenomena resulting from the postulated coupling of the axion to two photons. Sensitive probes of the extremely small coupling constant can be made by exploiting familiar, coherent electromagnetic laboratory techniques, including resonant enhancement of transitions using microwave and optical cavities, Bragg scattering, and coherent photon-axion oscillations. The axion beam may either be astrophysical in origin as in the case of dark matter axion searches and solar axion searches, or created in the laboratory from laser interactions with magnetic fields. This note is meant to be a sampling of recent experimental results.

Chou, Aaron S.; /Fermilab

2009-10-01T23:59:59.000Z

243

Electromagnetic Probes in PHENIX  

E-Print Network [OSTI]

Electromagnetic probes are arguably the most universal tools to study the different physics processes in high energy hadron and heavy ion collisions. In this paper we summarize recent measurements of real and virtual direct photons at central rapidity by the PHENIX experiment at RHIC in p+p, d+Au and Au+Au collisions. We also discuss the impact of the results and the constraints they put on theoretical models. At the end we report on the immediate as well as on the mid-term future of photon measurements at RHIC.

Gabor David

2006-09-21T23:59:59.000Z

244

Monitoring of Precipitable Water Vapor and Cloud Liquid Path from Scanning Microwave Radiometers During the 2003 Cloudiness Inter-Comparison Experiment  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource ProgramModification andinterface of water.OrganicNov 4 5

245

EPR investigations of phase transitions in amphiphilic systems using hydrophilic spin probes  

E-Print Network [OSTI]

1653 EPR investigations of phase transitions in amphiphilic systems using hydrophilic spin probes D technique de sonde EPR a été utilisée pour étudier les transitions coagel-gel et gel-cristal liquide dans de phase est observée à ~ 120 °C. Abstract. - The EPR spin probe technique was used to study coagel

Paris-Sud XI, Université de

246

Flexible high-temperature pH probe  

DOE Patents [OSTI]

A flexible pH probe device is provided for use in hot water and other high temperature environments up to about 590.degree. F. The pH probe includes a flexible, inert tubular probe member, an oxygen anion conducting, solid state electrolyte plug located at the distal end of the tubular member, oxide powder disposed at the distal end of the tubular member; a metal wire extending along the tubular member and having a distal end in contact with the oxide powder so as to form therewith an internal reference electrode; and a compression fitting forming a pressure boundary seal around a portion of the tubular member remote from the distal end thereof. Preferably, the tubular member is made of polytetrafluoroethylene, and the solid state electrolyte plug is made of stabilized zirconia. The flexibility of the probe member enables placement of the electrode into the area of interest, including around corners, into confined areas and the like.

Bielawski, John C. (Scotia, NY); Outwater, John O. (Cambridge, MA); Halbfinger, George P. (Schenectady, NY)

2003-04-22T23:59:59.000Z

247

Self-Assembly of Microscale Objects at a Liquid/Liquid Interface through Lateral Capillary Forces  

E-Print Network [OSTI]

Self-Assembly of Microscale Objects at a Liquid/Liquid Interface through Lateral Capillary Forces allowed to self-assemble at the perfluorodecalin/water interface. These plates were fabricated from, the designs of hydrophobic edges necessary to generate menisci useful in self-assembly were different for 100

Prentiss, Mara

248

Probing Multiparton Correlations at CEBAF  

E-Print Network [OSTI]

In this talk, I explore the possibilities of probing the multiparton correlation functions at CEBAF at its current energy and the energies with its future upgrades.

Jianwei Qiu

1998-08-08T23:59:59.000Z

249

Neutron diffraction of hydrogenous materials: measuring incoherent and coherent intensities separately from liquid water - a 40-year-old puzzle solved  

E-Print Network [OSTI]

(short version) Accurate determination of the coherent static structure factor of disordered materials containing proton nuclei is prohibitively difficult by neutron diffraction, due to the large incoherent cross section of $^1$H. This notorious problem has set severe obstacles to the structure determination of hydrogenous materials up to now, via introducing large uncertainties into neutron diffraction data processing. Here we present the first accurate separate measurements, using polarized neutron diffraction, of the coherent and incoherent contributions to the total static structure factor of 5 mixtures of light and heavy water, over an unprecedentedly wide momentum transfer range. The structure factors of H$_2$O and D$_2$O mixtures derived in this work may signify the beginning of a new era in the structure determination of hydrogenous materials, using neutron diffraction.

László Temleitner; Anne Stunault; Gabriel Cuello; László Pusztai

2014-10-01T23:59:59.000Z

250

Liquid foams of graphene  

E-Print Network [OSTI]

Liquid foams are dispersions of bubbles in a liquid. Bubbles are stabilized by foaming agents that position at the interface between the gas and the liquid. Most foaming agents, such as the commonly used sodium dodecylsulfate, ...

Alcazar Jorba, Daniel

2012-01-01T23:59:59.000Z

251

Creaming and breaking of liquid emulsions: a free boundary problem 1 / 48 Creaming and breaking of liquid  

E-Print Network [OSTI]

, as opposite to the other case called instead a water-in-oil emulsion. #12;Creaming and breaking of liquid emulsions: a free boundary problem 4 / 48 What is an emulsion? Everyday life examples (a) water-in-oil of the model 5 A priori estimates 6 Existence and uniqueness #12;Creaming and breaking of liquid emulsions

Rosso, Fabio

252

Scanning Probe AFM Compound Microscope | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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253

Ultrasonic probe deployment device for increased wave transmission and rapid area scan inspections  

DOE Patents [OSTI]

An ultrasonic probe deployment device in which an ultrasound-transmitting liquid forms the portion of the ultrasonic wave path in contact with the surface being inspected (i.e., the inspection surface). A seal constrains flow of the liquid, for example preventing the liquid from surging out and flooding the inspection surface. The seal is not rigid and conforms to variations in the shape and unevenness of the inspection surface, thus forming a seal (although possibly a leaky seal) around the liquid. The probe preferably is held in place to produce optimum ultrasonic focus on the area of interest. Use of encoders can facilitate the production of C-scan area maps of the material being inspected.

DiMambro, Joseph; Roach, Dennis P; Rackow, Kirk A; Nelson, Ciji L; Dasch, Cameron J; Moore, David G

2013-02-12T23:59:59.000Z

254

Ultrasonic probe deployment device for increased wave transmission and rapid area scan inspections  

SciTech Connect (OSTI)

An ultrasonic probe deployment device in which an ultrasound-transmitting liquid forms the portion of the ultrasonic wave path in contact with the surface being inspected (i.e., the inspection surface). A seal constrains flow of the liquid, for example preventing the liquid from surging out and flooding the inspection surface. The seal is not rigid and conforms to variations in the shape and unevenness of the inspection surface, thus forming a seal (although possibly a leaky seal) around the liquid. The probe preferably is held in place to produce optimum ultrasonic focus on the area of interest. Use of encoders can facilitate the production of C-scan area maps of the material being inspected.

DiMambro, Joseph (Placitas, NM); Roach, Dennis P. (Albuquerque, NM); Rackow, Kirk A. (Albuquerque, NM); Nelson, Ciji L. (Albuquerque, NM); Dasch, Cameron J. (Boomfield Hills, MI); Moore, David G. (Albuquerque, NM)

2012-01-03T23:59:59.000Z

255

Reorientation of the ‘free OH’ group in the top-most layer of air/water interface of sodium fluoride aqueous solution probed with sum-frequency generation vibrational spectroscopy  

SciTech Connect (OSTI)

Many experimental and theoretical studies have established the specific anion, as well as cation effects on the hydrogen-bond structures at the air/water interface of electrolyte solutions. However, the ion effects on the top-most layer of the air/water interface, which is signified by the non-hydrogen-bonded so-called ‘free O-H’ group, has not been discussed or studied. In this report, we present the measurement of changes of the orientational angle of the ‘free O-H’ group at the air/water interface of the sodium fluoride (NaF) solutions at different concentrations using the interface selective sum-frequency generation vibrational spectroscopy (SFG-VS) in the ssp and ppp polarizations. The polarization dependent SFG-VS results show that the average tilt angle of the ‘free O-H’ changes from about 35.3 degrees ± 0.5 degrees to 43.4 degrees ± 2.1degrees as the NaF concentration increase from 0 to 0.94M (nearly saturated). Such tilt angle change is around the axis of the other O-H group of the same water molecule at the top-most layer at the air/water interface that is hydrogen-bonded to the water molecules below the top-most layer. These results provide quantitative molecular details of the ion effects of the NaF salt on the structure of the water molecules at the top-most layer of the air/water interfacial, even though both the Na+ cation and the F- anion are believed to be among the most excluded ions from the air/water interface.

Feng, Ran-Ran; Guo, Yuan; Wang, Hongfei

2014-09-17T23:59:59.000Z

256

Heat transfer probe  

DOE Patents [OSTI]

Apparatuses, systems, methods, and computer code for, among other things, monitoring the health of samples such as the brain while providing local cooling or heating. A representative device is a heat transfer probe, which includes an inner channel, a tip, a concentric outer channel, a first temperature sensor, and a second temperature sensor. The inner channel is configured to transport working fluid from an inner inlet to an inner outlet. The tip is configured to receive at least a portion of the working fluid from the inner outlet. The concentric outer channel is configured to transport the working fluid from the inner outlet to an outer outlet. The first temperature sensor is coupled to the tip, and the second temperature sensor spaced apart from the first temperature sensor.

Frank, Jeffrey I.; Rosengart, Axel J.; Kasza, Ken; Yu, Wenhua; Chien, Tai-Hsin; Franklin, Jeff

2006-10-10T23:59:59.000Z

257

Vapor-liquid equilibrium of water-acetone-air at ambient temperatures and pressures. An analysis of different VLE-fitting methods  

SciTech Connect (OSTI)

The availability of accurate equilibrium data is of high importance in chemical engineering practice both for design and research purposes. It appeared that for the gas absorption system water-acetone-air in the range of special interest for absorption and desorption operations, neither literature data nor calculations following UNIFAC gave a sufficient accuracy. An experimental program was set up to determine equilibrium data with an accuracy within 2% for low acetone concentrations (up to 7 wt % gas phase) at ambient temperature (16-30/sup 0/C) and atmospheric pressure (740-860 mmHg). From experiments the activity coefficient at infinite dilution of acetone ..gamma.. is found to be 6.79 (0.01) at 20/sup 0/C and 7.28 (0.01) at 25/sup 0/C, while the total error in ..gamma.. is 1.5%. The equilibrium constant can be calculated from ..gamma.. and shows the same error. The experimental data-fitting with procedures of Margules (two parameters) and Van Laar were successful, but NRTL, Wilson, and UNIQUAC failed, probably because of the small concentration range used.

Lichtenbelt, J.H.; Schram, B.J.

1985-04-01T23:59:59.000Z

258

High temperature electrochemical corrosion rate probes for combustion environments  

SciTech Connect (OSTI)

Electrochemical corrosion rate probes have been constructed and tested along with mass loss coupons in an air plus water vapor and a N2/O2/CO2 plus water vapor environment. Temperatures ranged from 200? to 700?C. Results show that electrochemical corrosion rates for ash-covered mild steel are a function of time, temperature and process environment. Correlation between the electrochemical and mass loss corrosion rates was poor.

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, Margaret; Eden, David A. (Intercorr International Inc.); Kane, Russell D. (Intercorr International Inc.); Eden, Dawn C. (Intercorr International Inc.)

2004-01-01T23:59:59.000Z

259

Rotating concave eddy current probe  

SciTech Connect (OSTI)

A rotating concave eddy current probe for detecting fatigue cracks hidden from view underneath the head of a raised head fastener, such as a buttonhead-type rivet, used to join together structural skins, such as aluminum aircraft skins. The probe has a recessed concave dimple in its bottom surface that closely conforms to the shape of the raised head. The concave dimple holds the probe in good alignment on top of the rivet while the probe is rotated around the rivet's centerline. One or more magnetic coils are rigidly embedded within the probe's cylindrical body, which is made of a non-conducting material. This design overcomes the inspection impediment associated with widely varying conductivity in fastened joints.

Roach, Dennis P. (Albuquerque, NM); Walkington, Phil (Albuquerque, NM); Rackow, Kirk A. (Albuquerque, NM); Hohman, Ed (Albuquerque, NM)

2008-04-01T23:59:59.000Z

260

Modeling of thermal processes in very high pressure liquid chromatography for column immersed in a water bath: Application of the selected models  

SciTech Connect (OSTI)

Currently, chromatographic analyses are carried out by operating columns packed with sub-2 {micro}m particles under very high pressure gradients, up to 1200 bar for 5 cm long columns. This provides the high flow rates that are necessary for the achievement of high column efficiencies and short analysis times. However, operating columns at high flow rates under such high pressure gradients generate a large amount of heat due to the viscous friction of the mobile phase stream that percolates through a low permeability bed. The evacuation of this heat causes the formation of significant or even large axial and radial gradients of all the physico-chemical parameters characterizing the packing material and the mobile phase, eventually resulting in a loss of column efficiency. We previously developed and successfully applied a model combining the heat and the mass balances of a chromatographic column operated under very high pressure gradients (VHPLC). The use of this model requires accurate estimates of the dispersion coefficients at each applied mobile phase velocity. This work reports on a modification of the mass balance model such that only one measurement is now necessary to accurately predict elution peak profiles in a wide range of mobile phase velocities. The conditions under which the simple equilibrium-dispersive (ED) and transport-dispersive (TD) models are applicable in VHPLC are also discussed. This work proves that the new combination of the heat transfer and the ED model discussed in this work enables the calculation of accurate profiles for peaks eluted under extreme conditions, like when the column is thermostated in a water bath.

Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL; Kaczmarski, Krzysztof [University of Tennessee and Rzeszow University of Technology, Poland

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Alien liquid detector and control  

SciTech Connect (OSTI)

An alien liquid detector employs a monitoring element and an energizing circuit for maintaining the temperature of the monitoring element substantially above ambient temperature. For this purpose an electronic circit controls a flow of heating current to the monitoring element. The presence of an alien liquid is detected by sensing a predetermined change in heating current flow to the monitoring element, e.g., to distinguish between water and oil. In preferred embodiments the monitoring element is a thermistor whose resistance is compared with a reference resistance and heating current through the thermistor is controlled in accordance with the difference. In one embodiment a bridge circuit senses the resistance difference; the difference may be sensed by an operational amplifier arrangement. Features of the invention include positioning the monitoring element at the surface of water, slightly immersed, so that the power required to maintain the thermistor temperature substantially above ambient temperature serves to detect presence of oil pollution at the surface.

Potter, B.M.

1980-09-02T23:59:59.000Z

262

Interactions of Water and Energy Mediate Responses of High-Latitude Terrestrial Ecosystems to Climate Change  

E-Print Network [OSTI]

of the heat capacity of the ice mass and liquid water mass.all the ice (liquid) is melted (frozen). Heat capacities are

Subin, Zachary Marc

2012-01-01T23:59:59.000Z

263

FLUORESCENCE AND FIBER-OPTICS BASED REAL-TIME THICKNESS SENSOR FOR DYNAMIC LIQUID FILMS  

E-Print Network [OSTI]

/analyzed the incident reflected waves to identify and measure the total transit time of the sound wave (of known wave-speed1 FLUORESCENCE AND FIBER-OPTICS BASED REAL-TIME THICKNESS SENSOR FOR DYNAMIC LIQUID FILMS T. W. Ng/disadvantages of many known liquid film thickness sensing devices (viz. conductivity probes, reflectance based fiber

Narain, Amitabh

264

TRANSPORT AND DYNAMICS IN SUPERCOOLED CONFINED WATER  

E-Print Network [OSTI]

Systems B. The Water Heat Capacity VIII. The NMR and the Configurational Heat Capacity IX. Concluding Remarks References Liquid Polymorphism: Advances in Chemical Physics, Volume 152, First Edition. Edited, inside this stable phase, water can also exist in liquid form. When this occurs, water is said

Stanley, H. Eugene

265

Safetygram #9- Liquid Hydrogen  

Broader source: Energy.gov [DOE]

Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

266

Long duration ash probe  

DOE Patents [OSTI]

A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during soot blowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon. 8 figs.

Hurley, J.P.; McCollor, D.P.; Selle, S.J.

1994-07-26T23:59:59.000Z

267

Long duration ash probe  

DOE Patents [OSTI]

A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during sootblowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon.

Hurley, John P. (Grand Forks, ND); McCollor, Don P. (Grand Forks, ND); Selle, Stanley J. (Grand Forks, MN)

1994-01-01T23:59:59.000Z

268

Probing Organic Transistors with Infrared Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing Organic Transistors with Infrared Beams Probing Organic Transistors with Infrared Beams Print Wednesday, 26 July 2006 00:00 Silicon-based transistors are well-understood,...

269

Optic probe for semiconductor characterization  

DOE Patents [OSTI]

Described herein is an optical probe (120) for use in characterizing surface defects in wafers, such as semiconductor wafers. The optical probe (120) detects laser light reflected from the surface (124) of the wafer (106) within various ranges of angles. Characteristics of defects in the surface (124) of the wafer (106) are determined based on the amount of reflected laser light detected in each of the ranges of angles. Additionally, a wafer characterization system (100) is described that includes the described optical probe (120).

Sopori, Bhushan L. (Denver, CO); Hambarian, Artak (Yerevan, AM)

2008-09-02T23:59:59.000Z

270

Differential probes aid flow measurement  

SciTech Connect (OSTI)

Nonconstricting differential pressure flow probes which help solve the problems of clogging, wear, and pressure loss at the Seawater Filtration Facility in Saudi Arabia are described. Treated seawater is pumped into oil-bearing formations for secondary recovery. Figures showing principle of operation for probes, installation schematic and long-term accuracy results (flow probes vs. orifice meters) are presented. The new diamond-shaped design flow sensor offers accurate flow measurement with low permanent pressure loss, which translates into cost savings for the operator.

Mesnard, D.R.

1982-07-01T23:59:59.000Z

271

Growth of flower-like CdSe dendrites from a Brnsted acidbase ionic liquid precursor{  

E-Print Network [OSTI]

solution of water, ethanol and ionic liquid based on formic acid and N,N-dimethylformamide. Experimental, ethanol, an ionic liquid based on formic acid and N,N-dimethylformamide, cadmium chloride and sel

Utrecht, Universiteit

272

Switchable stiffness scanning microscope probe  

E-Print Network [OSTI]

Atomic Force Microscopy (AFM) has rapidly gained widespread utilization as an imaging device and micro/nano-manipulator during recent years. This thesis investigates the new concept of a dual stiffness scanning probe with ...

Mueller-Falcke, Clemens T. (Clemens Tobias)

2005-01-01T23:59:59.000Z

273

Liquid soap film generates electricity  

E-Print Network [OSTI]

We have observed that a rotating liquid soap film generates electricity when placed between two non-contact electrodes with a sufficiently large potential difference. In our experiments suspended liquid film (water + soap film) is formed on the surface of a circular frame, which is forced to rotate in the $x-y$ horizontal plane by a motor. This system is located at the center of two capacitor-like vertical plates to apply an external electric voltage difference in the $x-$direction. The produced electric current is collected from the liquid film using two conducting electrodes that are separated in the $y-$direction. We previously reported that a liquid film in an external electric field rotates when an electric current passes through it, naming it the liquid film motor (LFM). In this paper we report a novel technique, in which a similar device can be used as an electric generator, converting the rotating mechanical energy to electrical energy. The liquid film electric generator (LFEG) is in stark contrast to the LFM, both of which could be designed similarly in very small scales like micro scales with different applications. Although the device is comparable to commercial electric motors or electric generators, there is a significant difference in their working principles. Usually in an electric motor or generator the magnetic field causes the driving force, while in a LFM or LFEG the Coulomb force is the driving force. This fact is also interesting from the Bio-science point of view and brings a similarity to bio motors. Here we have investigated the electrical characteristics of such a generator for the first time experimentally and modelled the phenomenon with electroconvection governing equations. A numerical simulation is performed using the local approximation for the charge-potential relation and results are in qualitative agreement with experiments.

Ahmad Amjadi; Sadegh Feiz; Reza Montazeri Namin

2014-04-24T23:59:59.000Z

274

Water's Hydrogen Bond Strength  

E-Print Network [OSTI]

Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

Martin Chaplin

2007-06-10T23:59:59.000Z

275

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for low pressure boilers. A boiler tank, from which apor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, Albert P. (Vernon, CT)

1986-01-01T23:59:59.000Z

276

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for low pressure boilers. A boiler tank, from which vapor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, A.P.

1984-02-21T23:59:59.000Z

277

Liquid Hydrogen Absorber for MICE  

E-Print Network [OSTI]

REFERENCES Figure 5: Liquid hydrogen absorber and test6: Cooling time of liquid hydrogen absorber. Eight CernoxLIQUID HYDROGEN ABSORBER FOR MICE S. Ishimoto, S. Suzuki, M.

Ishimoto, S.

2010-01-01T23:59:59.000Z

278

Water: A Complex Liquid Marcia C. Barbosa  

E-Print Network [OSTI]

and Entropy (S - S )(V - V ) #12;Diffusion - SPC/E Berendsen, Grigera, Straatsma, JCP 91, 6269 (87) #12;Diffusion - SPC/E Netz, Starr, Stanley, Barbosa JCP 115, 344 (01) #12;Rotation Diffusion - SPC/E Netz, Starr) Particles make four bonds BUT they have five neighbors!!! #12;Frequency - SPC/E Netz, Starr, MCB and Stanley

Liu, I-Shih

279

Electrokinetic Hydrogen Generation from Liquid Water Microjets  

E-Print Network [OSTI]

currents and hydrogen production rates are shown to followmolecules. The hydrogen production efficiency is currentlycurrently available hydrogen production routes that can be

Duffin, Andrew M.; Saykally, Richard J.

2007-01-01T23:59:59.000Z

280

Liquid-Liquid Transition at Tg and Stable-Glass Phase Nucleation Rate Maximum at the Kauzmann Temperature TK  

E-Print Network [OSTI]

An undercooled liquid is unstable. The driving force of the glass transition at Tg is a change of the undercooled-liquid Gibbs free energy. The classical Gibbs free energy change for a crystal formation is completed including an enthalpy saving. The crystal growth critical nucleus is used as a probe to observe the Laplace pressure change Dp accompanying the enthalpy change -Vm*Dp at Tg where Vm is the molar volume. A stable glass-liquid transition model predicts the specific heat jump of fragile liquids at temperatures smaller than Tg, the Kauzmann temperature TK where the liquid entropy excess with regard to crystal goes to zero, the equilibrium enthalpy between TK and Tg, the maximum nucleation rate at TK of superclusters containing magic atom numbers, and the equilibrium latent heats at Tg and TK. Strong-to-fragile and strong-to-strong liquid transitions at Tg are also described and all their thermodynamic parameters are determined from their specific heat jumps. The existence of fragile liquids quenched in the amorphous state, which do not undergo liquid-liquid transition during heating preceding their crystallization, is predicted. Long ageing times leading to the formation at TK of a stable glass composed of superclusters containing up to 147 atoms, touching and interpenetrating, are evaluated from nucleation rates.

Robert Felix Tournier

2014-04-25T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Instabilities during liquid migration into superheated hydrothermal systems  

SciTech Connect (OSTI)

Hydrothermal systems typically consist of hot permeable rock which contains either liquid or liquid and saturated steam within the voids. These systems vent fluids at the surface through hot springs, fumaroles, mud pools, steaming ground and geysers. They are simultaneously recharged as meteoric water percolates through the surrounding rock or through the active injection of water at various geothermal reservoirs. In a number of geothermal reservoirs from which significant amounts of hot fluid have been extracted and passed through turbines, superheated regions of vapor have developed. As liquid migrates through a superheated region of a hydrothermal system, some of the liquid vaporizes at a migrating liquid-vapor interface. Using simple physical arguments, and analogue laboratory experiments we show that, under the influence of gravity, the liquid-vapor interface may become unstable and break up into fingers.

Fitzgerald, Shaun D.; Woods, Andrew W.

1995-01-26T23:59:59.000Z

282

Probing Strain-Induced Changes in Electronic Structure with XMCD  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - SeptemberMicroneedles for4-16 FORPoints of ContactLiquidProbing Strain-Induced

283

Probing Strain-Induced Changes in Electronic Structure with XMCD  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - SeptemberMicroneedles for4-16 FORPoints of ContactLiquidProbing

284

Guidance Document Cryogenic Liquids  

E-Print Network [OSTI]

with air. Liquid carbon monoxide is extremely toxic and extremely flammable. #12;Cryogenic liquids connecting cylinder to lower pressure piping or systems. 6. Use a check valve or trap in the discharge line

285

Interface for liquid chromatograph-mass spectrometer  

DOE Patents [OSTI]

A moving belt interface for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer.

Andresen, Brian D. (Pleasanton, CA); Fought, Eric R. (Livermore, CA)

1989-01-01T23:59:59.000Z

286

Interface for liquid chromatograph-mass spectrometer  

DOE Patents [OSTI]

A moving belt interface is described for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer. 8 figs.

Andresen, B.D.; Fought, E.R.

1989-09-19T23:59:59.000Z

287

Equation for liquid density  

SciTech Connect (OSTI)

Saturated liquid densities for organic chemicals are given as functions of temperature using a modified Rackett equation.

Yaws, C.L.; Yang, H.C.; Hopper, J.R.; Cawley, W.A. (Lamar Univ., Beaumont, TX (US))

1991-01-01T23:59:59.000Z

288

Damping of liquid sloshing by foams  

E-Print Network [OSTI]

When a container is set in motion, the free surface of the liquid starts to oscillate or slosh. Such effects can be observed when a glass of water is handled carelessly and the fluid sloshes or even spills over the rims of the container. However, beer does not slosh as readily as water, which suggests that foam could be used to damp sloshing. In this work, we study experimentally the effect on sloshing of a liquid foam placed on top of a liquid bath. We generate a monodisperse two-dimensional liquid foam in a rectangular container and track the motion of the foam. The influence of the foam on the sloshing dynamics is experimentally characterized: only a few layers of bubbles are sufficient to significantly damp the oscillations. We rationalize our experimental findings with a model that describes the foam contribution to the damping coefficient through viscous dissipation on the walls of the container. Then we extend our study to confined three-dimensional liquid foam and observe that the behavior of 2D and confined 3D systems are very similar. Thus we conclude that only the bubbles close to the walls have a significant impact on the dissipation of energy. The possibility to damp liquid sloshing using foam is promising in numerous industrial applications such as the transport of liquefied gas in tankers or for propellants in rocket engines.

Alban Sauret; François Boulogne; Jean Cappello; Emilie Dressaire; Howard A. Stone

2015-02-01T23:59:59.000Z

289

Rotary union for use with ultrasonic thickness measuring probe  

DOE Patents [OSTI]

A rotary union for rotatably supporting an ultrasonic probe operable to nondestructively measure the thickness of steam generator tubes to determine the amount of corrosion experienced by the tubes includes a stationary body having a bore therethrough and an outlet drain, and a fitting rotatably mounted within the upper end of the body. The fitting has a bore aligned with the bore of the body. An electrical cable positioned within a water supply tube in an annular arrangement passes through the bore of the body and the bore of the fitting. This annular arrangement, in turn, is positioned within a connector element which extends outwardly from the fitting bore and is connected to the ultrasonic probe. An elastomeric lower bushing seals the annular arrangement to the lower end of the rotary union body and an elastomeric upper bushing seals the connector element to the fitting to permit the connector element and the ultrasonic probe connected thereto to rotate with the fitting relative to the body. The lower and upper bushings permit water to be passed through the annular arrangement and into the ultrasonic probe and thereafter discharged between the annular arrangement and the connector element to the outlet drain of the rotary union body. 5 figs.

Nachbar, H.D.

1992-09-15T23:59:59.000Z

290

Liquid detection circuit  

DOE Patents [OSTI]

Herein is a circuit which is capable of detecting the presence of liquids, especially cryogenic liquids, and whose sensor will not overheat in a vacuum. The circuit parameters, however, can be adjusted to work with any liquid over a wide range of temperatures.

Regan, Thomas O. (North Aurora, IL)

1987-01-01T23:59:59.000Z

291

Predictions of Dynamic Behavior under Pressure for Two Scenarios to Explain Water Anomalies Pradeep Kumar,1  

E-Print Network [OSTI]

of maximum correlation length in the (T, P) plane. Response functions, such as the isobaric heat capacity CP crossover is independent of whether water at very low temperature is characterized by a ``liquid-liquid scenarios are commonly used to interpret the anomalies of water [1,2]: (i) The liquid-liquid critical point

Franzese, Giancarlo

292

Hand-held survey probe  

DOE Patents [OSTI]

A system for providing operational feedback to a user of a detection probe may include an optical sensor to generate data corresponding to a position of the detection probe with respect to a surface; a microprocessor to receive the data; a software medium having code to process the data with the microprocessor and pre-programmed parameters, and making a comparison of the data to the parameters; and an indicator device to indicate results of the comparison. A method of providing operational feedback to a user of a detection probe may include generating output data with an optical sensor corresponding to the relative position with respect to a surface; processing the output data, including comparing the output data to pre-programmed parameters; and indicating results of the comparison.

Young, Kevin L. (Idaho Falls, ID) [Idaho Falls, ID; Hungate, Kevin E. (Idaho Falls, ID) [Idaho Falls, ID

2010-02-23T23:59:59.000Z

293

OIL DROPLET MANIPULATION USING LIQUID DIELECTROPHORESIS ON ELECTRET WITH SUPERLYOPHOBIC  

E-Print Network [OSTI]

OIL DROPLET MANIPULATION USING LIQUID DIELECTROPHORESIS ON ELECTRET WITH SUPERLYOPHOBIC SURFACES flow friction for water and oil. Charge stability of electret in liquid is much improved with new hysteresis of SLS for oil droplets are experimentally demonstrated, indicating low motion resistance

Kasagi, Nobuhide

294

Boiling and condensation in a liquid-filled enclosure  

E-Print Network [OSTI]

A combined experimental and analytical investigation of boiling and condensation in a liquid-filled enclosure, with water and Freon- 113 as the working fluids, is described. The operating characteristics of a boiling system, ...

Bar-Cohen Avram

1971-01-01T23:59:59.000Z

295

Designing liquid repellent surfaces for fabrics, feathers and fog  

E-Print Network [OSTI]

Omniphobicity refers to a property of surfaces which are not wetted by water, oils, alcohols and other low surface tension liquids. Robust omniphobic surfaces can be applied in many areas including fabrics with chemical / ...

Chhatre, Shreerang S. (Shreerang Sharad)

2013-01-01T23:59:59.000Z

296

NUMERICAL SIMULATION OF RESERVOIR COMPACTION IN LIQUID DOMINATED GEOTHERMAL SYSTEMS  

E-Print Network [OSTI]

13. modeling of liquid geothermal systems: Ph.D. thesis,of water dominated geothermal fields with large temper~of land subsidence in geothermal areas: Proc. 2nd Int. Symp.

Lippmann, M.J.

2010-01-01T23:59:59.000Z

297

Liquid Wall Chambers  

SciTech Connect (OSTI)

The key feature of liquid wall chambers is the use of a renewable liquid layer to protect chamber structures from target emissions. Two primary options have been proposed and studied: wetted wall chambers and thick liquid wall (TLW) chambers. With wetted wall designs, a thin layer of liquid shields the structural first wall from short ranged target emissions (x-rays, ions and debris) but not neutrons. Various schemes have been proposed to establish and renew the liquid layer between shots including flow-guiding porous fabrics (e.g., Osiris, HIBALL), porous rigid structures (Prometheus) and thin film flows (KOYO). The thin liquid layer can be the tritium breeding material (e.g., flibe, PbLi, or Li) or another liquid metal such as Pb. TLWs use liquid jets injected by stationary or oscillating nozzles to form a neutronically thick layer (typically with an effective thickness of {approx}50 cm) of liquid between the target and first structural wall. In addition to absorbing short ranged emissions, the thick liquid layer degrades the neutron flux and energy reaching the first wall, typically by {approx}10 x x, so that steel walls can survive for the life of the plant ({approx}30-60 yrs). The thick liquid serves as the primary coolant and tritium breeding material (most recent designs use flibe, but the earliest concepts used Li). In essence, the TLW places the fusion blanket inside the first wall instead of behind the first wall.

Meier, W R

2011-02-24T23:59:59.000Z

298

Examination system utilizing ionizing radiation and a flexible, miniature radiation detector probe  

DOE Patents [OSTI]

An optimized examination system and method based on the Reverse Geometry X-Ray.RTM. (RGX.RTM.) radiography technique are presented. The examination system comprises a radiation source, at least one flexible, miniature radiation detector probe positioned in appropriate proximity to the object to be examined and to the radiation source with the object located between the source and the probe, a photodetector device attachable to an end of the miniature radiation probe, and a control unit integrated with a display device connected to the photodetector device. The miniature radiation detector probe comprises a scintillation element, a flexible light guide having a first end optically coupled to the scintillation element and having a second end attachable to the photodetector device, and an opaque, environmentally-resistant sheath surrounding the flexible light guide. The probe may be portable and insertable, or may be fixed in place within the object to be examined. An enclosed, flexible, liquid light guide is also presented, which comprises a thin-walled flexible tube, a liquid, preferably mineral oil, contained within the tube, a scintillation element located at a first end of the tube, closures located at both ends of the tube, and an opaque, environmentally-resistant sheath surrounding the flexible tube. The examination system and method have applications in non-destructive material testing for voids, cracks, and corrosion, and may be used in areas containing hazardous materials. In addition, the system and method have applications for medical and dental imaging.

Majewski, Stanislaw (Grafton, VA); Kross, Brian J. (Yorktown, VA); Zorn, Carl J. (Yorktown, VA); Majewski, Lukasz A. (Grafton, VA)

1996-01-01T23:59:59.000Z

299

Examination system utilizing ionizing radiation and a flexible, miniature radiation detector probe  

DOE Patents [OSTI]

An optimized examination system and method based on the Reverse Geometry X-Ray{trademark} (RGX{trademark}) radiography technique are presented. The examination system comprises a radiation source, at least one flexible, miniature radiation detector probe positioned in appropriate proximity to the object to be examined and to the radiation source with the object located between the source and the probe, a photodetector device attachable to an end of the miniature radiation probe, and a control unit integrated with a display device connected to the photodetector device. The miniature radiation detector probe comprises a scintillation element, a flexible light guide having a first end optically coupled to the scintillation element and having a second end attachable to the photodetector device, and an opaque, environmentally-resistant sheath surrounding the flexible light guide. The probe may be portable and insertable, or may be fixed in place within the object to be examined. An enclosed, flexible, liquid light guide is also presented, which comprises a thin-walled flexible tube, a liquid, preferably mineral oil, contained within the tube, a scintillation element located at a first end of the tube, closures located at both ends of the tube, and an opaque, environmentally-resistant sheath surrounding the flexible tube. The examination system and method have applications in non-destructive material testing for voids, cracks, and corrosion, and may be used in areas containing hazardous materials. In addition, the system and method have applications for medical and dental imaging. 5 figs.

Majewski, S.; Kross, B.J.; Zorn, C.J.; Majewski, L.A.

1996-10-22T23:59:59.000Z

300

Nuclear Physics with Electroweak Probes  

E-Print Network [OSTI]

In recent years, the italian theoretical Nuclear Physics community has played a leading role in the development of a unified approach, allowing for a consistent and fully quantitative description of the nuclear response to electromagnetic and weak probes. In this paper I review the main achievements in both fields, point out some of the open problems, and outline the most promising prospects.

Omar Benhar

2009-02-26T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Cantilevered probe detector with piezoelectric element  

DOE Patents [OSTI]

A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

Adams, Jesse D. (Reno, NV); Sulchek, Todd A. (Oakland, CA); Feigin, Stuart C. (Reno, NV)

2012-07-10T23:59:59.000Z

302

Cantilevered probe detector with piezoelectric element  

DOE Patents [OSTI]

A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

Adams, Jesse D; Sulchek, Todd A; Feigin, Stuart C

2014-04-29T23:59:59.000Z

303

Cantilevered probe detector with piezoelectric element  

DOE Patents [OSTI]

A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

Adams, Jesse D; Sulchek, Todd A; Feigin, Stuart C

2013-04-30T23:59:59.000Z

304

Handheld force-controlled ultrasound probe  

E-Print Network [OSTI]

An hand-held force controlled ultrasound probe has been developed. The controller maintains a prescribed contact force between the probe and a patient's body. The device will enhance the diagnostic capability of free-hand ...

Gilbertson, Matthew Wright

2010-01-01T23:59:59.000Z

305

Detection of supercooled liquid in mixedphase clouds using radar Doppler spectra  

E-Print Network [OSTI]

in the temperature range from 0 to -40°C, where both liquid and ice hydrometeor phases are sustainable of their hydrometeors (i.e., liquid or ice). Current cloud parameterizations that parti- tion water into liquid and ice 2010; published 1 October 2010. [1] Cloud phase identification from active remote sensors

Shupe, Matthew

306

Water mist injection in oil shale retorting  

DOE Patents [OSTI]

Water mist is utilized to control the maximum temperature in an oil shale retort during processing. A mist of water droplets is generated and entrained in the combustion supporting gas flowing into the retort in order to distribute the liquid water droplets throughout the retort. The water droplets are vaporized in the retort in order to provide an efficient coolant for temperature control.

Galloway, T.R.; Lyczkowski, R.W.; Burnham, A.K.

1980-07-30T23:59:59.000Z

307

The Videofil probe, a novel instrument to extend the coke oven service life  

SciTech Connect (OSTI)

To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

Gaillet, J.P.; Isler, D. [Centre de Pyrolyse de Marienau, Forbach (France)

1997-12-31T23:59:59.000Z

308

Understanding the operation and use of high temperature electrochemical corrosion rate probes  

SciTech Connect (OSTI)

Electrochemical corrosion rate probes were constructed and tested along with mass loss coupons in a N2/O2/CO2 plus water vapor environment. Temperatures ranged from 450 to 600 C. Corrosion rates for ash-covered mild steel, 304L SS, and 316L SS probes using electrochemical techniques were a function of time, temperature, and process environment. Correlation between electrochemical and mass loss corrosion rates was good.

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, M.; Cayard, Michael S. (InterCorr International Inc.); Eden, David A. (InterCorr International Inc.)

2004-01-01T23:59:59.000Z

309

Screening model for nanowire surface-charge sensors in liquid  

E-Print Network [OSTI]

The conductance change of nanowire field-effect transistors is considered a highly sensitive probe for surface charge. However, Debye screening of relevant physiological liquid environments challenge device performance due to competing screening from the ionic liquid and nanowire charge carriers. We discuss this effect within Thomas-Fermi and Debye-Huckel theory and derive analytical results for cylindrical wires which can be used to estimate the sensitivity of nanowire surface-charge sensors. We study the interplay between the nanowire radius, the Thomas-Fermi and Debye screening lengths, and the length of the functionalization molecules. The analytical results are compared to finite-element calculations on a realistic geometry.

Martin H. Sorensen; Niels Asger Mortensen; Mads Brandbyge

2007-08-17T23:59:59.000Z

310

SLOSHING OF LIQUIDS IN RIGID ANNULAR CYLINDRICAL AND TORUS TANKS DUE TO SEISMIC GROUND MOTIONS  

E-Print Network [OSTI]

response of water in annular tank model of water = 1 underof Fixed-Base Liquid Storage Tank,'' U.S. , Japan Seminar onSloshing in Axisymmetric Tanks, 11 Ph.D. Dissertation,

Aslam, M.

2013-01-01T23:59:59.000Z

311

Kinetics of complex plasma with liquid droplets  

SciTech Connect (OSTI)

This paper provides a theoretical basis for the reduction of electron density by spray of water (or other liquids) in hot plasma. This phenomenon has been observed in a hypersonic flight experiment for relief of radio black out, caused by high ionization in the plasma sheath of a hypersonic vehicle, re-entering the atmosphere. The analysis incorporates a rather little known phenomenon for de-charging of the droplets, viz., evaporation of ions from the surface and includes the charge balance on the droplets and number cum energy balance of electrons, ions, and neutral molecules; the energy balance of the evaporating droplets has also been taken into account. The analysis has been applied to a realistic situation and the transient variations of the charge and radius of water droplets, and other plasma parameters have been obtained and discussed. The analysis through made in the context of water droplets is applicable to all liquids.

Misra, Shikha; Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India); Mishra, S. K. [Institute for Plasma Research (IPR), Gandhinagar 382428 (India)] [Institute for Plasma Research (IPR), Gandhinagar 382428 (India)

2013-12-15T23:59:59.000Z

312

Ultrasonic liquid level detector  

DOE Patents [OSTI]

An ultrasonic liquid level detector for use within a shielded container, the detector being tubular in shape with a chamber at its lower end into which liquid from in the container may enter and exit, the chamber having an ultrasonic transmitter and receiver in its top wall and a reflector plate or target as its bottom wall whereby when liquid fills the chamber a complete medium is then present through which an ultrasonic wave may be transmitted and reflected from the target thus signaling that the liquid is at chamber level.

Kotz, Dennis M. (North Augusta, SC); Hinz, William R. (Augusta, GA)

2010-09-28T23:59:59.000Z

313

Liquid Crystal Optofluidics  

SciTech Connect (OSTI)

By employing anisotropic fluids and namely liquid crystals, fluid flow becomes an additional degree of freedom in designing optofluidic devices. In this paper, we demonstrate optofluidic liquid crystal devices based on the direct flow of nematic liquid crystals in microfluidic channels. Contrary to previous reports, in the present embodiment we employ the effective phase delay acquired by light travelling through flowing liquid crystal, without analysing the polarisation state of the transmitted light. With this method, we demonstrate the variation in the diffraction pattern of an array of microfluidic channels acting as a grating. We also discuss our recent activities in integrating mechanical oscillators for on-chip peristaltic pumping.

Vasdekis, Andreas E.; Cuennet, J. G.; Psaltis, D.

2012-10-11T23:59:59.000Z

314

(Ionization in liquids)  

SciTech Connect (OSTI)

This document describes charge transport following ionization of model liquids and how this process may be important in carcinogenesis. 15 refs., 2 figs., 4 tabs. (MHB)

Not Available

1991-01-01T23:59:59.000Z

315

Supercooled water and the kinetic glass transition F. Sciortino,1  

E-Print Network [OSTI]

-dynamics study of the self-dynamics of water molecules in deeply supercooled liquid states. We find the superheated, stretched, and supercooled states of liquid water 4­6 ; ii the existence of a meta- stable, lowSupercooled water and the kinetic glass transition F. Sciortino,1 P. Gallo,2 P. Tartaglia,1 and S

Sciortino, Francesco

316

Prediction of annular liquid-gas flow with entrainment: cocurrent vertical pipe flow with gravity. [PWR; BWR  

SciTech Connect (OSTI)

A simplified semi-empirical model is developed for annular two-phase (gas-liquid) flow with liquid entrainment in a vertical pipe. Gravity effects are included. Model predictions are compared to test data obtained with air-water, air-trichloroethane, and steam-water mixtures. The agreement is generally good between model and test results for pressure drop, liquid film thickness and wavyness, and liquid entrainment.

Levy, S.; Healzer, J.M.

1980-09-01T23:59:59.000Z

317

Downhole probes evaluate cavern integrity  

SciTech Connect (OSTI)

Obtaining natural-gas storage caverns` pressures and temperatures with downhole probes has allowed TransGas Ltd., Regina, to monitor and evaluate cavern integrity. TransGas has more than 5 years` experience with the devices. The acquired data have also helped determine gas-in-place inventory and confirm and assess changes in spatial volumes. These changes may have resulted from cavern creep (shrinkage or closure) or downhole abnormality such as fluid infill or collapse of the side walls or roof. This first of two articles presents background and many of the details and lessons to date of TransGas` cavern gas-storage probe program; the conclusion describes a specific storage site with some results.

Crossley, N.G. [TransGas Ltd., Regina, Saskatchewan (Canada)

1997-03-03T23:59:59.000Z

318

Optical probe with reference fiber  

DOE Patents [OSTI]

A system for characterizing tissue includes the steps of generating an emission signal, generating a reference signal, directing the emission signal to and from the tissue, directing the reference signal in a predetermined manner relative to the emission signal, and using the reference signal to compensate the emission signal. In one embodiment compensation is provided for fluctuations in light delivery to the tip of the probe due to cable motion.

Da Silva, Luiz B. (Danville, CA); Chase, Charles L. (Dublin, CA)

2006-03-14T23:59:59.000Z

319

Holographic non-Fermi liquid in a background magnetic field  

SciTech Connect (OSTI)

We study the effects of a nonzero magnetic field on a class of 2+1 dimensional non-Fermi liquids, recently found in [Hong Liu, John McGreevy, and David Vegh, arXiv:0903.2477.] by considering properties of a Fermionic probe in an extremal AdS{sup 4} black hole background. Introducing a similar fermionic probe in a dyonic AdS{sup 4} black hole geometry, we find that the effect of a magnetic field could be incorporated in a rescaling of the probe fermion's charge. From this simple fact, we observe interesting effects like gradual disappearance of the Fermi surface and quasiparticle peaks at large magnetic fields and changes in other properties of the system. We also find Landau level like structures and oscillatory phenomena similar to the de-Haas-van Alphen effect.

Basu, Pallab; He Jianyang; Mukherjee, Anindya; Shieh, Hsien-Hang [Department of Physics and Astronomy, University of British Columbia, 6224 Agricultural Road, Vancouver, B.C. V6T 1Z1 (Canada)

2010-08-15T23:59:59.000Z

320

Study of liquid retention in fixed-bed reactors with upward flow of gas and liquid  

SciTech Connect (OSTI)

A literature survey of the measurement techniques for the determination of liquid retention in cocurrent upward gas and liquid flow in fixed-bed reactors is presented. A number of these techniques were used in this work in columns of different diameters (Dc = 0.05 m, 0.10 m, and 0.15 m). Porous alumina particles of two different diameters (dp = 0.002 m and 0.0028 m) with both nonfoaming (water, cyclohexane, heptane, and propanol) and foaming liquids (kerosene, LCO, and diesel fuel) have been investigated. The gas used was either air or N[sub 2]. The methods investigated include volumetry, gravimetry, gammametry, and determination of residence-time distribution by tracer technique. A simple correlation for the prediction of total gas and liquid retention for bubble and pulsed flow is proposed and verified.

Yang, X.L.; Euzen, J.P. (Inst. Francais du Petrole, Vernaison (France)); Wild, G. (Lab. des Sciences du Genie Chimique, Nancy (France))

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

ccsd-00001732,version2-7Nov2004 Development behavior of liquid plasma produced by  

E-Print Network [OSTI]

ccsd-00001732,version2-7Nov2004 Development behavior of liquid plasma produced by YAG laser Jun called the environment material. Then, the plasma produced in liquid by the laser light is studied and the plasma development is observed by a streak camera. The ultra pure water or the ultra pure water

Paris-Sud XI, Université de

322

Metal-air cell comprising an electrolyte with a room temperature ionic liquid and hygroscopic additive  

DOE Patents [OSTI]

An electrochemical cell comprising an electrolyte comprising water and a hydrophobic ionic liquid comprising positive ions and negative ions. The electrochemical cell also includes an air electrode configured to absorb and reduce oxygen. A hydrophilic or hygroscopic additive modulates the hydrophobicity of the ionic liquid to maintain a concentration of the water in the electrolyte is between 0.001 mol % and 25 mol %.

Friesen, Cody A.; Krishnan, Ramkumar; Tang, Toni; Wolfe, Derek

2014-08-19T23:59:59.000Z

323

Liquid level, void fraction, and superheated steam sensor for nuclear-reactor cores. [PWR; BWR  

DOE Patents [OSTI]

This disclosure relates to an apparatus for monitoring the presence of coolant in liquid or mixed liquid and vapor, and superheated gaseous phases at one or more locations within an operating nuclear reactor core, such as pressurized water reactor or a boiling water reactor.

Tokarz, R.D.

1981-10-27T23:59:59.000Z

324

Absorption of sound in liquids and liquid mixtures  

E-Print Network [OSTI]

ABSORPTION OF SOUND IN LIQUIDS AND LIQUID MIXTURES A Thesis Raiq S. causa Approved as to style and content by: (Chairman of Committee) January 1955 L1BRARY A 4 M COLLEOE OF IEXAS ADSORPTION OF SOfP@ LIQUIDS AND LIQUID NIXTURES A Thesis... Introduction to the Problem Experimental Methods and Procedures Results Discussion of Results Acknowledgements Bib 1 io graphy 22 4I 42 Introduction to the Problem The study of sound absorption in liquids and liquid mixtures is of considerable...

Musa, Raiq S

2012-06-07T23:59:59.000Z

325

Carbon monoxide absorbing liquid  

SciTech Connect (OSTI)

The present disclosure is directed to a carbon monoxide absorbing liquid containing a cuprous ion, hydrochloric acid and titanum trichloride. Titanium trichloride is effective in increasing the carbon monoxide absorption quantity. Furthermore, titanium trichloride remarkably increases the oxygen resistance. Therefore, this absorbing liquid can be used continuously and for a long time.

Arikawa, Y.; Horigome, S.; Kanehori, K.; Katsumoto, M.

1981-07-07T23:59:59.000Z

326

Synthesis of ionic liquids  

DOE Patents [OSTI]

Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic liqand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

Dai, Sheng [Knoxville, TN; Luo, Huimin [Knoxville, TN

2008-09-09T23:59:59.000Z

327

Liquid heat capacity lasers  

DOE Patents [OSTI]

The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

Comaskey, Brian J. (Walnut Creek, CA); Scheibner, Karl F. (Tracy, CA); Ault, Earl R. (Livermore, CA)

2007-05-01T23:59:59.000Z

328

Water Resources Water Quality and Water Treatment  

E-Print Network [OSTI]

Water Resources TD 603 Lecture 1: Water Quality and Water Treatment CTARA Indian Institute of Technology, Bombay 2nd November, 2011 #12;OVERVIEW Water Quality WATER TREATMENT PLANTS WATER TREATMENT PLANTS WATER TREATMENT PLANTS WATER TRE OVERVIEW OF THE LECTURE 1. Water Distribution Schemes Hand Pump

Sohoni, Milind

329

Automated position control of a surface array relative to a liquid microjunction surface sampler  

DOE Patents [OSTI]

A system and method utilizes an image analysis approach for controlling the probe-to-surface distance of a liquid junction-based surface sampling system for use with mass spectrometric detection. Such an approach enables a hands-free formation of the liquid microjunction used to sample solution composition from the surface and for re-optimization, as necessary, of the microjunction thickness during a surface scan to achieve a fully automated surface sampling system.

Van Berkel, Gary J. (Clinton, TN); Kertesz, Vilmos (Knoxville, TN); Ford, Michael James (Little Rock, AR)

2007-11-13T23:59:59.000Z

330

Atom probe field ion microscopy and related topics: A bibliography 1989  

SciTech Connect (OSTI)

This bibliography includes references related to the following topics: atom probe field ion microscopy (APFIM), field ion spectroscopy (FIM), field emission microscopy (FEM), liquid metal ion sources (LMIS), scanning tunneling microscopy (STM), and theory. Technique-orientated studies and applications are included. This bibliography covers the period 1989. The references contained in this document were compiled from a variety of sources including computer searches and personal lists of publications.

Miller, M.K.; Hawkins, A.R.; Russell, K.F.

1990-12-01T23:59:59.000Z

331

Surface formation in immiscible liquids with orifice mixers  

E-Print Network [OSTI]

investigation of the mixing of isadscible liquids (Kerosene and water) with orifices was made as a continuation of previous work done by Murdoch and McNair. Data were obtained by making film exposures of flow conditions inside a pipe section aud just below... stable, Water and kerosene, for example, are a pair of liquids with high 0 interfacial tension (/+8 dynes/cm at 20 0), while water and ethyl ether are a pair with relatively low interfacial tension (10, '7 dynes/cm at 20oC ). Consequently, it is more...

Welch, Nathan Edgar

1956-01-01T23:59:59.000Z

332

Air Liquide - Biogas & Fuel Cells  

Broader source: Energy.gov (indexed) [DOE]

Liquide - Biogas & Fuel Cells Hydrogen Energy Biogas Upgrading Technology 12 June 2012 Charlie.Anderson@airliquide.com 2 Air Liquide, world leader in gases for industry,...

333

Liquid sampling system  

DOE Patents [OSTI]

A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

Larson, L.L.

1984-09-17T23:59:59.000Z

334

Liquid metal electric pump  

DOE Patents [OSTI]

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1992-01-01T23:59:59.000Z

335

Liquid metal electric pump  

DOE Patents [OSTI]

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

336

Entangled quantum probes for dynamical environmental noise  

E-Print Network [OSTI]

We address the use of entangled qubits as quantum probes to characterize the dynamical noise induced by complex environments. In particular, we show that entangled probes improve estimation of the correlation time for a broad class of environmental noises compared to any sequential strategy involving single qubit preparation. The effect is present when the noise is faster than a threshold value, a regime which may always be achieved by tuning the coupling between the quantum probe and the environment inducing the noise. Our scheme exploits time-dependent sensitivity of quantum systems to decoherence and does not require dynamical control on the probes. We derive the optimal interaction time and the optimal probe preparation, showing that it corresponds to multiqubit GHZ states when entanglement is useful. We also show robustness of the scheme against depolarization or dephasing of the probe, and discuss simple measurements approaching optimal precision.

Matteo A. C. Rossi; Matteo G. A. Paris

2015-03-11T23:59:59.000Z

337

Tunable nanowire nonlinear optical probe  

SciTech Connect (OSTI)

One crucial challenge for subwavelength optics has been thedevelopment of a tunable source of coherent laser radiation for use inthe physical, information, and biological sciences that is stable at roomtemperature and physiological conditions. Current advanced near-fieldimaging techniques using fiber-optic scattering probes1,2 have alreadyachieved spatial resolution down to the 20-nm range. Recently reportedfar-field approaches for optical microscopy, including stimulatedemission depletion (STED)3, structured illumination4, and photoactivatedlocalization microscopy (PALM)5, have also enabled impressive,theoretically-unlimited spatial resolution of fluorescent biomolecularcomplexes. Previous work with laser tweezers6-8 has suggested the promiseof using optical traps to create novel spatial probes and sensors.Inorganic nanowires have diameters substantially below the wavelength ofvisible light and have unique electronic and optical properties9,10 thatmake them prime candidates for subwavelength laser and imagingtechnology. Here we report the development of an electrode-free,continuously-tunable coherent visible light source compatible withphysiological environments, from individual potassium niobate (KNbO3)nanowires. These wires exhibit efficient second harmonic generation(SHG), and act as frequency converters, allowing the local synthesis of awide range of colors via sum and difference frequency generation (SFG,DFG). We use this tunable nanometric light source to implement a novelform of subwavelength microscopy, in which an infrared (IR) laser is usedto optically trap and scan a nanowire over a sample, suggesting a widerange of potential applications in physics, chemistry, materials science,and biology.

Nakayama, Yuri; Pauzauskie, Peter J.; Radenovic, Aleksandra; Onorato, Robert M.; Saykally, Richard J.; Liphardt, Jan; Yang, Peidong

2008-02-18T23:59:59.000Z

338

Hydrophilization of Liquid Surfaces by Plasma Treatment  

E-Print Network [OSTI]

The impact of the cold radiofrequency air plasma on the surface properties of silicone oils (polydimethylsiloxane) was studied. Silicone oils of various molecular masses were markedly hydrophilized by the cold air plasma treatment. A pronounced decrease of the apparent water contact angles was observed after plasma treatment. A general theoretical approach to the calculation of apparent contact angles is proposed. The treated liquid surfaces demonstrated hydrophobic recovery. The characteristic time of the hydrophobic recovery grew with the molecular mass of the silicone oil.

Victor Multanen; Gilad Chaniel; Roman Grynyov; Ron Yosef Loew; Naor Siany; Edward Bormashenko

2014-09-01T23:59:59.000Z

339

Noble Travails: Noble Liquid Dark Matter Detectors  

E-Print Network [OSTI]

, or water, 0.1x flux per 10 cm Cosmic Ray Muons generate high energy neutrons 50 MeV - 3 GeV which are toughGaitskell Noble Travails: Noble Liquid Dark Matter Detectors Rick Gaitskell Particle Astrophysics://particleastro.brown.edu/ http://gaitskell.brown.edu v1 #12;LUX Dark Matter Collaboration 2007 v01_7mm Dark Matter Theory

Golwala, Sunil

340

Liquidity facilities and signaling  

E-Print Network [OSTI]

This dissertation studies the role of signaling concerns in discouraging access to liquidity facilities like the IMF contingent credit lines (CCL) and the Discount Window (DW). In Chapter 1, I analyze the introduction of ...

Arregui, Nicolás

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Probing Organic Transistors with Infrared Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing Organic Transistors with Infrared Beams Print Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is...

342

PROBING DENSE NUCLEAR MATTER VIA NUCLEAR COLLISIONS  

E-Print Network [OSTI]

University of California. LBL-12095 Probing Dense NuclearMatter Nuclear Collisions* v~a H. Stocker, M.Gyulassy and J. Boguta Nuclear Science Division Lawrence

Stocker, H.

2012-01-01T23:59:59.000Z

343

Method for imaging liquid and dielectric materials with scanning polarization force microscopy  

SciTech Connect (OSTI)

The invention images dielectric polarization forces on surfaces induced by a charged scanning force microscope (SFM) probe tip. On insulators, the major contribution to the surface polarizability at low frequencies is from surface ions. The mobility of these ions depends strongly on the humidity. Using the inventive SFM, liquid films, droplets, and other weakly adsorbed materials have been imaged. 9 figs.

Hu, J.; Ogletree, D.F.; Salmeron, M.; Xiao, X.

1999-03-09T23:59:59.000Z

344

Atmosphere Sciences Instrumentation Lab  

E-Print Network [OSTI]

Liquid Water Probe ­ Robert Mitchell High Volume Precipitation Spectrometer (HVPS) ­ Matt Ham Dew Point is computed into a liquid water content. Accurate from .1g/m3 ­ 5g/m3 King Hot Wire Liquid Water Probe Robert Water Probe Robert Mitchell Challenge: · Power varies with Temperature, Pressure, Airspeed, and Others

Delene, David J.

345

Plasmas in Multiphase Media: Bubble Enhanced Discharges in Liquids and Plasma/Liquid Phase Boundaries  

SciTech Connect (OSTI)

In this research project, the interaction of atmospheric pressure plasmas with multi-phase media was computationally investigated. Multi-phase media includes liquids, particles, complex materials and porous surfaces. Although this investigation addressed fundamental plasma transport and chemical processes, the outcomes directly and beneficially affected applications including biotechnology, medicine and environmental remediation (e.g., water purification). During this project, we made advances in our understanding of the interaction of atmospheric pressure plasmas in the form of dielectric barrier discharges and plasma jets with organic materials and liquids. We also made advances in our ability to use computer modeling to represent these complex processes. We determined the method that atmospheric pressure plasmas flow along solid and liquid surfaces, and through endoscopic like tubes, deliver optical and high energy ion activation energy to organic and liquid surfaces, and produce reactivity in thin liquid layers, as might cover a wound. We determined the mechanisms whereby plasmas can deliver activation energy to the inside of liquids by sustaining plasmas in bubbles. These findings are important to the advancement of new technology areas such as plasma medicine

Kushner, Mark Jay [University of Michigan] [University of Michigan

2014-07-10T23:59:59.000Z

346

Liquid crystalline composites containing phyllosilicates  

DOE Patents [OSTI]

The present invention provides phyllosilicate-polymer compositions which are useful as liquid crystalline composites. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while at the same time be transparent. Because of the ordering of the particles liquid crystalline composite, liquid crystalline composites are particularly useful as barriers to gas transport.

Chaiko, David J.

2004-07-13T23:59:59.000Z

347

Optical pumpterahertz probe spectroscopy of dyes in solutions: Probing the dynamics of liquid solvent or solid precipitate?  

E-Print Network [OSTI]

dynamics simulations to investigate ultrafast dynamics following electronic excitation of Coumarin 153 and dynamics, preferably at a molecular level of reso- lution. In particular, solvent relaxation following body of time-resolved spectro- scopic studies, as well as molecular dynamics MD simula- tions have been

KuÂ?el, Petr

348

Molecular Structure of Water at Gold Electrodes Revealed  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to...

349

Process for exchanging hydrogen isotopes between gaseous hydrogen and water  

DOE Patents [OSTI]

A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

Hindin, Saul G. (Mendham, NJ); Roberts, George W. (Westfield, NJ)

1980-08-12T23:59:59.000Z

350

Comparing the performance of plasma impedance probes and Langmuir probes for RF plasma diagnostics  

E-Print Network [OSTI]

Comparing the performance of plasma impedance probes and Langmuir probes for RF plasma diagnostics probing, a less developed technique, can possibly overcome these problems. Better plasma diagnostic tools Ethan Dale, Dr. Mitchell Walker High-Power Electric Propulsion Laboratory Objective Plasma is the most

Walker, Mitchell

351

Millimeter-wave active probe  

DOE Patents [OSTI]

A millimeter-wave active probe for use in injecting signals with frequencies above 50GHz to millimeter-wave and ultrafast devices and integrated circuits including a substrate upon which a frequency multiplier consisting of filter sections and impedance matching sections are fabricated in uniplanar transmission line format. A coaxial input and uniplanar 50 ohm transmission line couple an approximately 20 GHz input signal to a low pass filter which rolls off at approximately 25 GHz. An input impedance matching section couples the energy from the low pass filter to a pair of matched, antiparallel beam lead diodes. These diodes generate odd-numberd harmonics which are coupled out of the diodes by an output impedance matching network and bandpass filter which suppresses the fundamental and third harmonics and selects the fifth harmonic for presentation at an output.

Majidi-Ahy, Gholamreza (Sunnyvale, CA); Bloom, David M. (Portola Valley, CA)

1991-01-01T23:59:59.000Z

352

Using liquid desiccant as a regenerable filter for capturing and deactivating contaminants  

DOE Patents [OSTI]

A method, and systems for implementing such method, for purifying and conditioning air of weaponized contaminants. The method includes wetting a filter packing media with a salt-based liquid desiccant, such as water with a high concentration of lithium chloride. Air is passed through the wetted filter packing media and the contaminants in are captured with the liquid desiccant while the liquid desiccant dehumidifies the air. The captured contaminants are then deactivated in the liquid desiccant, which may include heating the liquid desiccant. The liquid desiccant is regenerated by applying heat to the liquid desiccant and then removing moisture. The method includes repeating the wetting with the regenerated liquid desiccant which provides a regenerable filtering process that captures and deactivates contaminants on an ongoing basis while also conditioning the air. The method may include filtration effectiveness enhancement by electrostatic or inertial means.

Slayzak, Steven J. (Denver, CO); Anderson, Ren S. (Broomfield, CO); Judkoff, Ronald D. (Golden, CO); Blake, Daniel M. (Golden, CO); Vinzant, Todd B. (Golden, CO); Ryan, Joseph P. (Golden, CO)

2007-12-11T23:59:59.000Z

353

Department of Energy and Mineral Engineering Spring 2013 Preliminary Plant Design For Bitumen Separation Using Ionic Liquid  

E-Print Network [OSTI]

For Bitumen Separation Using Ionic Liquid Overview IL Fuels LLC invented a novel way to separate bitumen from of producing 5,000 barrels of bitumen per day while maximizing the recovery of ionic liquid and water of bitumen/day Maintain a maximum of 0.2% loss of ionic liquids to the cleaned sands Improve overall

Demirel, Melik C.

354

X-rays at Solid-Liquid Surfaces  

SciTech Connect (OSTI)

Solid-liquid interfaces play an important role in many areas of current and future technologies, and in our biosphere. They play a key role in the development of nanofluidics and nanotribology, which sensitively depend on our knowledge of the microscopic structures and phenomena at the solid-liquid interface. The detailed understanding of how a fluid meets a wall is also a theoretical challenge. In particular, the phenomena at repulsive walls are of interest, since they affect many different phenomena, such as water-repellent surfaces or the role of the hydrophobic interaction in protein folding. Recent x-ray reflectivity studies of various solid-liquid interfaces have disclosed rather intriguiing phenomena, which will be discussed in this lecture: premelting of ice in contact with silica; liquid Pb in contact with Si; water in contact with hydrophobic surfaces. These experiments, carried out with high-energy x-ray microbeams, reveal detailed insight into the liquid density profile closest to the wall. A detailed insight into atomistic phenomena at solid-liquid interfaces is also a prerequisite in the microscopic control of electrochemical reactions at interfaces. Recent x-ray studies show the enormous future potential of such non-destructive analytical tools for the in situ observation of (electro-)chemical surface reactions. This lecture will review recent x-ray experiments on solid-liquid interfaces.

Dosch, Helmut (Max Planck Institute for Metals Research) [Max Planck Institute for Metals Research

2007-05-02T23:59:59.000Z

355

MERIT Pump/Probe Data OutlineOutline  

E-Print Network [OSTI]

MERIT Pump/Probe Data Analysis OutlineOutline The pump/probe program Particle detector response correction Pump/probe analysis results NFMCC Collaboration Meeting , LBNL, January 26, 2009 Ilias Efthymiopoulos - CERN #12;The pump/probe program #12;The pump/probe program Use of the CERN PS flexibility

McDonald, Kirk

356

Scanning Probe Microscopy Studies of Carbon Nanotubes  

E-Print Network [OSTI]

Scanning Probe Microscopy Studies of Carbon Nanotubes Teri Wang Odom1 , Jason H. Hafner1 relationship between Single-Walled Carbon Nanotube (SWNT) atomic structure and electronic properties, (2, properties and application of carbon nanotube probe microscopy tips to ultrahigh resolution and chemically

Odom, Teri W.

357

A Finite Element Model for Ice Ball Evolution in a Multi-probe Cryosurgery  

E-Print Network [OSTI]

to intracellular ice injury for fast cooling rates, and solution effects injury for slow cooling rates. BasicallyA Finite Element Model for Ice Ball Evolution in a Multi-probe Cryosurgery RICHARD WANa, *, ZHIHONG October 2002; In final form 8 May 2003) The ice formation in a water body is examined for the computation

Wan, Richard G.

358

Yosemite Waters Vehicle Evaluation Report: Final Results  

SciTech Connect (OSTI)

Document details the evaluation of Fischer-Tropsch diesel, a gas-to-liquid fuel, in medium-duty delivery vehicles at Yosemite Waters. The study was conducted by NREL at the company's Fullerton, California, bottling headquarters.

Eudy, L.; Barnitt, R.; Alleman, T. L.

2005-08-01T23:59:59.000Z

359

Disinfecting Water Wells by Shock Chlorination  

E-Print Network [OSTI]

If your well has been flooded, it must be shock chlorinated before it can be used as a source of drinking water. This publication explains how to disinfect a well using either dry chlorine or liquid household bleach....

Dozier, Monty; McFarland, Mark L.

2005-09-30T23:59:59.000Z

360

Rugged fiber optic probe for raman measurement  

DOE Patents [OSTI]

An optical probe for conducting light scattering analysis is disclosed. The probe comprises a hollow housing and a probe tip. A fiber assembly made up of a transmitting fiber and a receiving bundle is inserted in the tip. A filter assembly is inserted in the housing and connected to the fiber assembly. A signal line from the light source and to the spectrometer also is connected to the filter assembly and communicates with the fiber assembly. By using a spring-loaded assembly to hold the fiber connectors together with the in-line filters, complex and sensitive alignment procedures are avoided. The close proximity of the filter assembly to the probe tip eliminates or minimizes self-scattering generated by the optical fiber. Also, because the probe can contact the sample directly, sensitive optics can be eliminated.

O'Rourke, Patrick E. (Martinez, GA); Toole, Jr., William R. (Aiken, SC); Nave, Stanley E. (Evans, GA)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Protective shield for an instrument probe  

DOE Patents [OSTI]

A shield is disclosed that is particularly useful for protecting exposed optical elements at the end of optical probes used in the analysis of hazardous emissions in and around an industrial environment from the contaminating effects of those emissions. The instant invention provides a hood or cowl in the shape of a right circular cylinder that can be fitted over the end of such optical probes. The hood provides a clear aperture through which the probe can perform unobstructed analysis. The probe optical elements are protected from the external environment by passing a dry gas through the interior of the hood and out through the hood aperture in sufficient quantity and velocity to prevent any significant mixing between the internal and external environments. Additionally, the hood is provided with a cooling jacket to lessen the potential for damaging the probe due to temperature excursions.

Johnsen, Howard A.; Ross, James R.; Birtola, Sal R.

2004-10-26T23:59:59.000Z

362

Individual quantum probes for optimal thermometry  

E-Print Network [OSTI]

The unknown temperature of a sample may be estimated with minimal disturbance by putting it in thermal contact with an individual quantum probe. If the interaction time is sufficiently long so that the probe thermalizes, the temperature can be read out directly from its steady state. Here we prove that the optimal quantum probe, acting as a thermometer with maximal thermal sensitivity, is an effective two-level atom with a maximally degenerate excited state. When the total interaction time is insufficient to produce full thermalization, we optimize the estimation protocol by breaking it down into sequential stages of probe preparation, thermal contact and measurement. We observe that frequently interrogated probes initialized in the ground state achieve the best performance. For both fully and partly thermalized thermometers, the sensitivity grows significantly with the number of levels, though optimization over their energy spectrum remains always crucial.

Luis A. Correa; Mohammad Mehboudi; Gerardo Adesso; Anna Sanpera

2014-11-23T23:59:59.000Z

363

Liquid-liquid interfacial nanoparticle assemblies  

DOE Patents [OSTI]

Self-assembly of nanoparticles at the interface between two fluids, and methods to control such self-assembly process, e.g., the surface density of particles assembling at the interface; to utilize the assembled nanoparticles and their ligands in fabrication of capsules, where the elastic properties of the capsules can be varied from soft to tough; to develop capsules with well-defined porosities for ultimate use as delivery systems; and to develop chemistries whereby multiple ligands or ligands with multiple functionalities can be attached to the nanoparticles to promote the interfacial segregation and assembly of the nanoparticles. Certain embodiments use cadmium selenide (CdSe) nanoparticles, since the photoluminescence of the particles provides a convenient means by which the spatial location and organization of the particles can be probed. However, the systems and methodologies presented here are general and can, with suitable modification of the chemistries, be adapted to any type of nanoparticle.

Emrick, Todd S. (South Deerfield, MA); Russell, Thomas P. (Amherst, MA); Dinsmore, Anthony (Amherst, MA); Skaff, Habib (Amherst, MA); Lin, Yao (Amherst, MA)

2008-12-30T23:59:59.000Z

364

Design of a Probe for Strain Sensitivity Studies of Critical Current Densities in SC Wires and Tapes  

SciTech Connect (OSTI)

The design of a variable-temperature probe used to perform strain sensitivity measurements on LTS wires and HTS wires and tapes is described. The measurements are intended to be performed at liquid helium temperatures (4.2 K). The wire or tape to be measured is wound and soldered on to a helical spring device, which is fixed at one end and subjected to a torque at the free end. The design goal is to be able to achieve {+-} 0.8 % strain in the wire and tape. The probe is designed to carry a current of 2000A.

Dhanaraj, N.; Barzi, E.; Turrioni, D.; Rusy, A.; Lombardo, V.; /Fermilab

2011-07-01T23:59:59.000Z

365

ECO2M: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2, Including Super- and Sub-Critical Conditions, and Phase Change Between Liquid and Gaseous CO2  

SciTech Connect (OSTI)

ECO2M is a fluid property module for the TOUGH2 simulator (Version 2.0) that was designed for applications to geologic storage of CO{sub 2} in saline aquifers. It includes a comprehensive description of the thermodynamics and thermophysical properties of H{sub 2}O - NaCl - CO{sub 2} mixtures, that reproduces fluid properties largely within experimental error for temperature, pressure and salinity conditions in the range of 10 C {le} T {le} 110 C, P {le} 600 bar, and salinity from zero up to full halite saturation. The fluid property correlations used in ECO2M are identical to the earlier ECO2N fluid property package, but whereas ECO2N could represent only a single CO{sub 2}-rich phase, ECO2M can describe all possible phase conditions for brine-CO{sub 2} mixtures, including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO{sub 2}. This allows for seamless modeling of CO{sub 2} storage and leakage. Flow processes can be modeled isothermally or non-isothermally, and phase conditions represented may include a single (aqueous or CO{sub 2}-rich) phase, as well as two-and three-phase mixtures of aqueous, liquid CO{sub 2} and gaseous CO{sub 2} phases. Fluid phases may appear or disappear in the course of a simulation, and solid salt may precipitate or dissolve. TOUGH2/ECO2M is upwardly compatible with ECO2N and accepts ECO2N-style inputs. This report gives technical specifications of ECO2M and includes instructions for preparing input data. Code applications are illustrated by means of several sample problems, including problems that had been previously solved with TOUGH2/ECO2N.

Pruess, K.

2011-04-01T23:59:59.000Z

366

Sustaining dry surfaces under water  

E-Print Network [OSTI]

Rough surfaces immersed under water remain practically dry if the liquid-solid contact is on roughness peaks, while the roughness valleys are filled with gas. Mechanisms that prevent water from invading the valleys are well studied. However, to remain practically dry under water, additional mechanisms need consideration. This is because trapped gas (e.g. air) in the roughness valleys can dissolve into the water pool, leading to invasion. Additionally, water vapor can also occupy the roughness valleys of immersed surfaces. If water vapor condenses, that too leads to invasion. These effects have not been investigated, and are critically important to maintain surfaces dry under water. In this work, we identify the critical roughness scale below which it is possible to sustain the vapor phase of water and/or trapped gases in roughness valleys - thus keeping the immersed surface dry. Theoretical predictions are consistent with molecular dynamics simulations and experiments.

Paul R. Jones; Xiuqing Hao; Eduardo R. Cruz-Chu; Konrad Rykaczewski; Krishanu Nandy; Thomas M. Schutzius; Kripa K. Varanasi; Constantine M. Megaridis; Jens H. Walther; Petros Koumoutsakos; Horacio D. Espinosa; Neelesh A. Patankar

2014-09-29T23:59:59.000Z

367

Probing Signal Design for Power System Identification  

SciTech Connect (OSTI)

This paper investigates the design of effective input signals for low-level probing of power systems. In 2005, 2006, and 2008 the Western Electricity Coordinating Council (WECC) conducted four large-scale system wide tests of the western interconnected power system where probing signals were injected by modulating the control signal at the Celilo end of the Pacific DC intertie. A major objective of these tests is the accurate estimation of the inter-area electromechanical modes. A key aspect of any such test is the design of an effective probing signal that leads to measured outputs rich in information about the modes. This paper specifically studies low-level probing signal design for power-system identification. The paper describes the design methodology and the advantages of this new probing signal which was successfully applied during these tests. This probing input is a multi-sine signal with its frequency content focused in the range of the inter-area modes. The period of the signal is over two minutes providing high-frequency resolution. Up to 15 cycles of the signal are injected resulting in a processing gain of 15. The resulting system response is studied in the time and frequency domains. Because of the new probing signal characteristics, these results show significant improvement in the output SNR compared to previous tests.

Pierre, John W.; Zhou, Ning; Tuffner, Francis K.; Hauer, John F.; Trudnowski, Daniel J.; Mittelstadt, William

2010-05-31T23:59:59.000Z

368

A study of boiling water flow regimes at low pressures  

E-Print Network [OSTI]

"A comprehensive experimental program to examine flow regimes at pressures below 100 psia for boiling of water in tubes was carried out. An electrical probe, which measures the resistance of the fluid between the centerline ...

Fiori, Mario P.

1966-01-01T23:59:59.000Z

369

Atmospheric Solids Analysis Probe Mass Spectrometry: A New Approach...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atmospheric Solids Analysis Probe Mass Spectrometry: A New Approach for Airborne Particle Analysis. Atmospheric Solids Analysis Probe Mass Spectrometry: A New Approach for Airborne...

370

Understanding Atom Probe Tomography of Oxide-Supported Metal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atom Probe Tomography of Oxide-Supported Metal Nanoparticles by Correlation with Atomic Resolution Electron Understanding Atom Probe Tomography of Oxide-Supported Metal...

371

Water inertial reorientation: Hydrogen bond strength and the angular potential  

E-Print Network [OSTI]

Water inertial reorientation: Hydrogen bond strength and the angular potential David E. Moilanen) The short-time orientational relaxation of water is studied by ultrafast infrared pump-probe spectroscopy with recent molecular dynamics simulations employing the simple point charge-extended water model at room

Fayer, Michael D.

372

Probing Organic Transistors with Infrared Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar Home DesignPresentationsSRS Responds toPrivacy ActProbingProbingProbing

373

Properties of Liquid Plutonium  

SciTech Connect (OSTI)

Unalloyed polycrystalline Pu displays extreme thermal expansion behavior, i.e., {alpha} {yields} {beta} {yields} {gamma} {yields} {delta} increases by 25% in volume and {delta} {yields} {var_epsilon} {yields} liquid decreases by 4.5% in volume. Thus, making it difficult to measure density into the liquid state. Dilatometer outfitted with CaF molten metal cell offers a proven capability to measure thermal expansion in molten metals, but has yet to be proven for Pu. Historic data from the liquid nuclear fuels program will prove extremely useful as a guide to future measurements. 3.3at% Ga changes Pu molten metal properties: 50% increase in viscosity and {approx}3% decrease in density. Fe may decrease the density by a small amount assuming an averaging of densities for Pu-Ga and Pu-Fe liquids. More recent Boivineau (2009) work needs some interpretation, but technique is being employed in (U,Pu)O{sub 2} nuclear fuels program (Pu Futures, 2012).

Freibert, Franz J. [Los Alamos National Laboratory; Mitchell, Jeremy N. [Los Alamos National Laboratory; Schwartz, Daniel S. [Los Alamos National Laboratory; Saleh, Tarik A. [Los Alamos National Laboratory; Migliori, Albert [Los Alamos National Laboratory

2012-08-02T23:59:59.000Z

374

Two-state thermodynamics of the ST2 model for supercooled water  

SciTech Connect (OSTI)

Thermodynamic properties of the ST2 model for supercooled liquid water exhibit anomalies similar to those observed in real water. A possible explanation of these anomalies is the existence of a metastable, liquid–liquid transition terminated by a critical point. This phenomenon, whose possible existence in real water is the subject of much current experimental work, has been unambiguously demonstrated for this particular model by most recent simulations. In this work, we reproduce the anomalies of two versions of the ST2 model with an equation of state describing water as a non-ideal “mixture” of two different types of local molecular order. We show that the liquid–liquid transition in the ST2 water is energy-driven. This is in contrast to another popular model, mW, in which non-ideality in mixing of two alternative local molecular orders is entropy-driven, and is not sufficiently strong to induce a liquid–liquid transition.

Holten, Vincent; Anisimov, Mikhail A., E-mail: anisimov@umd.edu [Institute for Physical Science and Technology and Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742 (United States); Palmer, Jeremy C.; Debenedetti, Pablo G. [Department of Chemical and Biological Engineering, Princeton University, Princeton, New Jersey 08544 (United States)] [Department of Chemical and Biological Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Poole, Peter H. [Department of Physics, St. Francis Xavier University, Antigonish, Nova Scotia B2G 2W5 (Canada)] [Department of Physics, St. Francis Xavier University, Antigonish, Nova Scotia B2G 2W5 (Canada)

2014-03-14T23:59:59.000Z

375

Ch.9 Water Resources ! Hydrologic cycle  

E-Print Network [OSTI]

Energy Balance G Ts Td H LE Q t = Rn - LE - H - G where Q/t is the heat storage change of soil column in the liquid or solid phase at or near the land surface becomes water vapor. Water Bare soil Vegetated of the water molecules to a solid surface (e.g., soil or glass). #12;A simple soil-water-balance equation

Pan, Feifei

376

Imaging Liquids Using Microfluidic Cells  

SciTech Connect (OSTI)

Chemistry occurring in the liquid and liquid surface is important in many applications. Chemical imaging of liquids using vacuum based analytical techniques is challenging due to the difficulty in working with liquids with high volatility. Recent development in microfluidics enabled and increased our capabilities to study liquid in situ using surface sensitive techniques such as electron microscopy and spectroscopy. Due to its small size, low cost, and flexibility in design, liquid cells based on microfluidics have been increasingly used in studying and imaging complex phenomena involving liquids. This paper presents a review of microfluidic cells that were developed to adapt to electron microscopes and various spectrometers for in situ chemical analysis and imaging of liquids. The following topics will be covered including cell designs, fabrication techniques, unique technical features for vacuum compatible cells, and imaging with electron microscopy and spectroscopy. Challenges are summarized and recommendations for future development priority are proposed.

Yu, Xiao-Ying; Liu, Bingwen; Yang, Li

2013-05-10T23:59:59.000Z

377

Caution on the Use of Liquid Nitrogen Traps in Stable Hydrogen Isotope-Ratio Mass Spectrometry  

E-Print Network [OSTI]

-mail: tbcoplen@usgs.gov. (1) Kirshenbaum, I. In Physical Properties and Analysis of Heavy Water; Urey, H. C with the process of adding liquid nitrogen (LN2) to top off the dewar of a stainless-steel water trap on a gaseous hydrogen-water platinum equilibration system. Al- though the cause of this isotopic fractionation

378

A new probe for corrosion monitoring of stainless steel piping systems  

SciTech Connect (OSTI)

This paper presents theoretical background and development of a probe for corrosion monitoring of process- and piping systems made of stainless steels. The probe will be installed in two piping systems on the Draugen platform in the North Sea. One installation is for monitoring of a produced water systems made of duplex stainless steel (UNS S31803), and one for monitoring in a seawater system made of high-alloy austenitic stainless steel of the 6 Mo type (UNS S31254). Equipment for logging and storing data is also described.

Valen, S.; Johnsen, R.; Gartland, P.O. [CorrOcean as, Trondheim (Norway); Hollen, I.H. [AS Norske Shell, Kristiansund (Norway)

1995-12-01T23:59:59.000Z

379

Liquid metal thermal electric converter  

DOE Patents [OSTI]

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

380

Liquid crystalline composites containing phyllosilicates  

DOE Patents [OSTI]

The present invention provides barrier films having reduced gas permeability for use in packaging and coating applications. The barrier films comprise an anisotropic liquid crystalline composite layer formed from phyllosilicate-polymer compositions. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while remaining transparent. Because of the ordering of the particles in the liquid crystalline composite, barrier films comprising liquid crystalline composites are particularly useful as barriers to gas transport.

Chaiko; David J. (Naperville, IL)

2007-05-08T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Water in a Crowd In many situations, form biology to geology, water occurs not as the pure bulk  

E-Print Network [OSTI]

Water in a Crowd In many situations, form biology to geology, water occurs not as the pure bulk species, and interacting with large organic molecules. In such situations, water does not behave in the same manner as it does in the pure bulk liquid. Water dynamics are fundamental to many processes

Fayer, Michael D.

382

High temperature liquid level sensor  

DOE Patents [OSTI]

A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.

Tokarz, Richard D. (West Richland, WA)

1983-01-01T23:59:59.000Z

383

Catheter based magnetic resonance compatible perfusion probe  

E-Print Network [OSTI]

Neurosurgeons are using a thermal based technique to quantify brain perfusion. The thermal diffusion probe (TDP) technology measures perfusion in a relatively small volume of brain tissue. The neurosurgeon chooses the ...

Toretta, Cara Lynne

2007-01-01T23:59:59.000Z

384

Modulated microwave microscopy and probes used therewith  

DOE Patents [OSTI]

A microwave microscope including a probe tip electrode vertically positionable over a sample and projecting downwardly from the end of a cantilever. A transmission line connecting the tip electrode to the electronic control system extends along the cantilever and is separated from a ground plane at the bottom of the cantilever by a dielectric layer. The probe tip may be vertically tapped near or at the sample surface at a low frequency and the microwave signal reflected from the tip/sample interaction is demodulated at the low frequency. Alternatively, a low-frequency electrical signal is also a non-linear electrical element associated with the probe tip to non-linearly interact with the applied microwave signal and the reflected non-linear microwave signal is detected at the low frequency. The non-linear element may be semiconductor junction formed near the apex of the probe tip or be an FET formed at the base of a semiconducting tip.

Lai, Keji; Kelly, Michael; Shen, Zhi-Xun

2012-09-11T23:59:59.000Z

385

Lecture Notes on Langmuir Probe Diagnostics  

E-Print Network [OSTI]

University of California, Los Angeles Mini-Course on Plasma Diagnostics, IEEE-ICOPS meeting, Jeju, KoreaLecture Notes on Langmuir Probe Diagnostics Francis F. Chen Electrical Engineering Department...................................................................25 1. Fully ionized plasmas

Chen, Francis F.

386

Surface sampling concentration and reaction probe  

DOE Patents [OSTI]

A method of analyzing a chemical composition of a specimen is described. The method can include providing a probe comprising an outer capillary tube and an inner capillary tube disposed co-axially within the outer capillary tube, where the inner and outer capillary tubes define a solvent capillary and a sampling capillary in fluid communication with one another at a distal end of the probe; contacting a target site on a surface of a specimen with a solvent in fluid communication with the probe; maintaining a plug volume proximate a solvent-specimen interface, wherein the plug volume is in fluid communication with the probe; draining plug sampling fluid from the plug volume through the sampling capillary; and analyzing a chemical composition of the plug sampling fluid with an analytical instrument. A system for performing the method is also described.

Van Berkel, Gary J; Elnaggar, Mariam S

2013-07-16T23:59:59.000Z

387

Probes of strong-field gravity  

E-Print Network [OSTI]

In this thesis, I investigate several ways to probe gravity in the strong-field regime. These investigations focus on observables from the gravitational dynamics, i.e. when time derivatives are large: thus I focus on sources ...

Stein, Leo Chaim

2012-01-01T23:59:59.000Z

388

Single Molecule Probes of Lipid Membrane Structure  

E-Print Network [OSTI]

Biological membranes are highly heterogeneous structures that are thought to use this heterogeneity to organize and modify the function of membrane constituents. Probing membrane organization, structure, and changes therein ...

Livanec, Philip W.

2009-12-14T23:59:59.000Z

389

Self-referencing remote optical probe  

DOE Patents [OSTI]

A probe for remote spectrometric measurements of fluid samples having a hollow probe body with a sliding reflective plug therein and a lens at one end, ports for admitting and expelling the fluid sample and a means for moving the reflector so that reference measurement can be made with the reflector in a first position near the lens and a sample measurement can be made with the reflector away from the lens and the fluid sample between the reflector and the lens. Comparison of the two measurements will yield the composition of the fluid sample. The probe is preferably used for remote measurements and light is carried to and from the probe via fiber optic cables.

O'Rourke, Patrick E. (157 Greenwood Dr., Martinez, GA 30907); Prather, William S. (2419 Dickey Rd., Augusta, GA 30906); Livingston, Ronald R. (137 Breckenridge Dr., N. Augusta, GA)

1991-01-01T23:59:59.000Z

390

Self-referencing remote optical probe  

DOE Patents [OSTI]

A probe is described for remote spectrometric measurements of fluid samples having a hollow probe body with a sliding reflective plug therein and a lens at one end, ports for admitting and expelling the fluid sample and a means for moving the reflector so that reference measurement can be made with the reflector in a first position near the lens and a sample measurement can be made with the reflector away from the lens and the fluid sample between the reflector and the lens. Comparison of the two measurements will yield the composition of the fluid sample. The probe is preferably used for remote measurements and light is carried to and from the probe via fiber optic cables. 3 figures.

O'Rourke, P.E.; Prather, W.S.; Livingston, R.R.

1991-08-13T23:59:59.000Z

391

Water Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water Quality Water Quality We protect water quality through stormwater control measures and an extensive network of monitoring wells and stations encompassing groundwater, surface...

392

Condensate Water Collection for an Institutional Building in Doha, Qatar: An Opportunity for Water Sustainability  

E-Print Network [OSTI]

conditioning system. Internal loads and additional outside ventilation air all generate considerable latent loads on these systems and exacerbate the already difficult moisture control problem. A manifestation of this load is the liquid water condensate...

Bryant, J. A.; Ahmed, T.

393

AdHoc Probe: End-to-end Capacity Probing in Wireless Ad Hoc Networks  

E-Print Network [OSTI]

AdHoc Probe: End-to-end Capacity Probing in Wireless Ad Hoc Networks Ling-Jyh Chen1 , Tony Sun2 and systematic study in ad hoc, multihop wireless networks is still lacking. Yet the rate of a wireless link can deployment. In this paper, we present AdHoc Probe, a packet-pair based technique, to estimate end-to-end path

Chen, Ling-Jyh

394

The Water Trimer Frank N. Keutsch, Jeffery D. Cruzan, and Richard J. Saykally*  

E-Print Network [OSTI]

theoretical work of Frank and Wen3 predicted that formation of a single hydrogen bond (H-bond) in liquid water presented by those early authors has evolved substantially, there is modern consensus that liquid waterThe Water Trimer Frank N. Keutsch, Jeffery D. Cruzan, and Richard J. Saykally* Department

Cohen, Ronald C.

395

NMR evidence of a sharp change in a measure of local order in deeply supercooled confined water  

E-Print Network [OSTI]

in thermody- namical properties such as compressibility, isobaric heat capacity, and thermal expansion of maximum correlation length at 240 K, consistent with the liquid-liquid critical point hypothesis for water received support from various theoretical studies (4­7) is the liquid-liquid (LL) critical point hypothesis

Stanley, H. Eugene

396

Fiber optic probe for light scattering measurements  

DOE Patents [OSTI]

A fiber optic probe and a method for using the probe for light scattering analyses of a sample. The probe includes a probe body with an inlet for admitting a sample into an interior sample chamber, a first optical fiber for transmitting light from a source into the chamber, and a second optical fiber for transmitting light to a detector such as a spectrophotometer. The interior surface of the probe carries a coating that substantially prevents non-scattered light from reaching the second fiber. The probe is placed in a region where the presence and concentration of an analyte of interest are to be detected, and a sample is admitted into the chamber. Exciting light is transmitted into the sample chamber by the first fiber, where the light interacts with the sample to produce Raman-scattered light. At least some of the Raman-scattered light is received by the second fiber and transmitted to the detector for analysis. Two Raman spectra are measured, at different pressures. The first spectrum is subtracted from the second to remove background effects, and the resulting sample Raman spectrum is compared to a set of stored library spectra to determine the presence and concentration of the analyte.

Nave, Stanley E. (Evans, GA); Livingston, Ronald R. (Aiken, SC); Prather, William S. (Augusta, GA)

1995-01-01T23:59:59.000Z

397

Fiber optic probe for light scattering measurements  

DOE Patents [OSTI]

This invention is comprised of a fiber optic probe and a method for using the probe for light scattering analyses of a sample. The probe includes a probe body with an inlet for admitting a sample into an interior sample chamber, a first optical fiber for transmitting light from a source into the chamber, and a second optical fiber for transmitting light to a detector such as a spectrophotometer. The interior surface of the probe carries a coating that substantially prevents non-scattered light from reaching the second fiber. The probe is placed in a region where the presence and concentration of an analyte of interest are to be detected, and a sample is admitted into the chamber. Exciting light is transmitted into the sample chamber by the first fiber, where the light interacts with the sample to produce Raman-scattered light. At least some of the Raman- scattered light is received by the second fiber and transmitted to the detector for analysis. Two Raman spectra are measured, at different pressures. The first spectrum is subtracted from the second to remove background effects, and the resulting sample Raman spectrum is compared to a set of stored library spectra to determine the presence and concentration of the analyte.

Nave, S.E.; Livingston, R.R.; Prather, W.S.

1993-01-01T23:59:59.000Z

398

Process for removing sulfate anions from waste water  

DOE Patents [OSTI]

A liquid emulsion membrane process for removing sulfate anions from waste water is disclosed. The liquid emulsion membrane process includes the steps of: (a) providing a liquid emulsion formed from an aqueous strip solution and an organic phase that contains an extractant capable of removing sulfate anions from waste water; (b) dispersing the liquid emulsion in globule form into a quantity of waste water containing sulfate anions to allow the organic phase in each globule of the emulsion to extract and absorb sulfate anions from the waste water and (c) separating the emulsion including its organic phase and absorbed sulfate anions from the waste water to provide waste water containing substantially no sulfate anions.

Nilsen, David N. (Lebanon, OR); Galvan, Gloria J. (Albany, OR); Hundley, Gary L. (Corvallis, OR); Wright, John B. (Albany, OR)

1997-01-01T23:59:59.000Z

399

Thermal-wave resonator cavity design and measurements of the thermal diffusivity of liquids  

E-Print Network [OSTI]

Thermal-wave resonator cavity design and measurements of the thermal diffusivity of liquids J. A for the measurement of the thermal diffusivity of liquids. The thermal diffusivities of distilled water, glycerol the thermal diffusivity of gases, particularly air,8,9 and vapors10 to a high degree of precision. Although

Mandelis, Andreas

400

American Institute of Aeronautics and Astronautics Development of a Compact Liquid Fueled Pulsed Detonation  

E-Print Network [OSTI]

automotive ignition system. Pre-heated liquid fuel is sprayed into a current of pre-heated air and thoroughly Hz. The PDE set up is water cooled allowing long duration testing. Diagnostics are performed using it necessary to preheat the fuel and/or air and to use nozzles to finely atomize the fuel spray. Liquid fueled

Texas at Arlington, University of

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Liquid-solid phase transitions in a deformable Pavel Krejci, Elisabetta Rocca, and Jurgen Sprekels  

E-Print Network [OSTI]

differences in the specific volume, specific heat and speed of sound in the solid and liquid phases and of the liquid phase, assuming first that the speed of sound and the specific heat are the same in solid the speed of sound in water is less than one half of the one in ice. The main goal of this contribution

Rocca, Elisabetta

402

Analysis & Simulation of Dynamics in Supercooled Liquids  

E-Print Network [OSTI]

Moreover, the heat capacity of that liquid is also higherthe intensive heat capacities of the liquid and the crystal,

Elmatad, Yael Sarah

2011-01-01T23:59:59.000Z

403

Modeling Liquid-Liquid Equilibrium of Ionic Liquid Systems with NRTL, Electrolyte-NRTL, and UNIQUAC  

E-Print Network [OSTI]

Modeling Liquid-Liquid Equilibrium of Ionic Liquid Systems with NRTL, Electrolyte-NRTL, and UNIQUAC different excess Gibbs free energy models are evaluated: the NRTL, UNIQUAC and electrolyte- NRTL (eNRTL) models. In the case of eNRTL, a new formulation of the model is used, based on a symmetric reference

Stadtherr, Mark A.

404

Performance Evaluation for Modular, Scalable Liquid-Rack Cooling Systems in Data Centers  

E-Print Network [OSTI]

the modular liquid cooling system with varying supply waterinlet supply air temperature, while modular system coolingcooling needed (up to 9.8 kW/rack) at various supply water

Xu, TengFang

2009-01-01T23:59:59.000Z

405

Probing thermonuclear supernova explosions with neutrinos  

E-Print Network [OSTI]

Aims: We present neutrino light curves and energy spectra for two representative type Ia supernova explosion models: a pure deflagration and a delayed detonation. Methods: We calculate the neutrino flux from $\\beta$ processes using nuclear statistical equilibrium abundances convoluted with approximate neutrino spectra of the individual nuclei and the thermal neutrino spectrum (pair+plasma). Results: Although the two considered thermonuclear supernova explosion scenarios are expected to produce almost identical electromagnetic output, their neutrino signatures appear vastly different, which allow an unambiguous identification of the explosion mechanism: a pure deflagration produces a single peak in the neutrino light curve, while the addition of the second maximum characterizes a delayed-detonation. We identified the following main contributors to the neutrino signal: (1) weak electron neutrino emission from electron captures (in particular on the protons Co55 and Ni56) and numerous beta-active nuclei produced by the thermonuclear flame and/or detonation front, (2) electron antineutrinos from positron captures on neutrons, and (3) the thermal emission from pair annihilation. We estimate that a pure deflagration supernova explosion at a distance of 1 kpc would trigger about 14 events in the future 50 kt liquid scintillator detector and some 19 events in a 0.5 Mt water Cherenkov-type detector. Conclusions: While in contrast to core-collapse supernovae neutrinos carry only a very small fraction of the energy produced in the thermonuclear supernova explosion, the SN Ia neutrino signal provides information that allows us to unambiguously distinguish between different possible explosion scenarios. These studies will become feasible with the next generation of proposed neutrino observatories.

A. Odrzywolek; T. Plewa

2011-03-27T23:59:59.000Z

406

Liquid filtration simulation  

SciTech Connect (OSTI)

We have a developed a computer code that simulates 3-D filtration of suspended particles in fluids in realistic filter structures. This code, being the most advanced filtration simulation package developed to date, provides LLNL and DOE with new capabilities to address problems in cleaning liquid wastes, medical fluid cleaning, and recycling liquids. The code is an integrated system of commercially available and LLNL-developed software; the most critical are the computational fluid dynamics (CFD) solver and the particle transport program. For the CFD solver, we used a commercial package based on Navier-Stokes equations and a LLNL-developed package based on Boltzman-lattice gas equations. For the particle transport program, we developed a cod based on the 3-D Langevin equation of motion and the DLVO theory of electrical interactions. A number of additional supporting packages were purchased or developed to integrate the simulation tasks and to provide visualization output.

Corey, I.; Bergman, W.

1996-06-01T23:59:59.000Z

407

Evaluation of probes used to detect alpha radiation  

E-Print Network [OSTI]

such probes were evaluated in this study, the 350A Alpha Probe of Dosimeter Corporation and the AB100 Scintillator Probe produced by Harshaw Bicron. As an additional comparison, a Ludlum Model 44-9 (Pancake) GM Probe was also evaluated, since it has served...

Sackett, Gregory Duane

1995-01-01T23:59:59.000Z

408

Liquid Holdup Profiles in Structured Packing Determined via Neutron Radiography  

E-Print Network [OSTI]

scans of an operating air-water contactor were performed at the NIST Center for Neutron Research (NCNR packings are widely employed in vapor-liquid contacting devices for distillation, absorption, and stripping. The high specific surface areas (ap), regular geometries, and high void fraction () of structured packing

Eldridge, R. Bruce

409

Integrated photoelectrochemical cell and system having a liquid electrolyte  

DOE Patents [OSTI]

An integrated photoelectrochemical (PEC) cell generates hydrogen and oxygen from water while being illuminated with radiation. The PEC cell employs a liquid electrolyte, a multi-junction photovoltaic electrode, and a thin ion-exchange membrane. A PEC system and a method of making such PEC cell and PEC system are also disclosed.

Deng, Xunming (Sylvania, OH); Xu, Liwei (Sylvania, OH)

2010-07-06T23:59:59.000Z

410

Probing Porosity and Pore Interconnectivity in Crystalline Mesoporous TiO2  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - SeptemberMicroneedles for4-16 FORPoints of ContactLiquid SurfacesProbing

411

Electron localization in liquid acetonitrile.  

SciTech Connect (OSTI)

Time-resolved one- and two-pulse laser dc photoconductivity has been used to observe two kinds of reducing species, anion-1 and anion-2, in liquid acetonitrile. At 25 C, the standard enthalpy of conversion from anion-1 to anion-2 is -44.3 {+-} 3.6 kJ/mol and the conversion time is 3 ns. The high-temperature form, anion-1, absorbs in the IR and migrates >3.3 times faster than any other ion in acetonitrile. This rapid migration has a low activation energy of 3.2 kJ/mol (vs 7.6 kJ/mol for other ions). Anion-1 rapidly transfers the electron to acceptors with high electron affinity, with rate constant up to 10{sup 11} M{sup -1} s{sup -1}. The low-temperature form, anion-2, absorbs in the visible and exhibits normal mobility and electron-transfer rates, ca. 1.5 x 10{sup 10} M{sup -1} s{sup -1}. It reacts, by proton transfer, with two hydrogen-bonded molecules of water and/or aliphatic alcohols. Laser photoexcitation of these two solvent anions in their respective absorption bands leads to the formation of CH{sub 3} and CN{sup -}. We present arguments indicating that anion-2 is a dimer radical anion of acetonitrile, whereas anion-1 is a multimer radical anion that may be regarded as a 'solvated electron'.

Shkrob, I. A.; Sauer, M. C.; Chemistry

2002-10-03T23:59:59.000Z

412

Corrosion monitoring with hydrogen probes in the oilfield  

SciTech Connect (OSTI)

An overview of the application of hydrogen probes for corrosion monitoring in the oilfield is presented. The three basic types of hydrogen probes are described and their relative merits discussed. The construction and installation of a simple and inexpensive electrochemical hydrogen probe is described. Experiences with hydrogen probes in oilfield operations are discussed, and it is concluded from these experiences that production systems where hydrogen probes can provide useful corrosion data are limited.

Thomason, W.H.

1984-05-01T23:59:59.000Z

413

Removal of nitrogen and phosphorus from reject water of municipal wastewater treatment plant.  

E-Print Network [OSTI]

??Reject water, the liquid fraction produced after dewatering of anaerobically digested activated sludge on a municipal wastewater treatment plant (MWWTP), contains from 750 to 1500… (more)

Guo, Chenghong

2011-01-01T23:59:59.000Z

414

Water Dynamics at Rough Interfaces  

E-Print Network [OSTI]

We use molecular dynamics computer simulations and nuclear magnetic resonance experiments to investigate the dynamics of water at interfaces of molecular roughness and low mobility. We find that, when approaching such interfaces, the structural relaxation of water, i.e., the $\\alpha$ process, slows down even when specific attractive interactions are absent. This prominent effect is accompanied by a smooth transition from Vogel to Arrhenius temperature dependence and by a growing importance of jump events. Consistently, at protein surfaces, deviations from Arrhenius behavior are weak when free water does not exist. Furthermore, in nanoporous silica, a dynamic crossover of liquid water occurs when a fraction of solid water forms near 225 K and, hence, the liquid dynamics changes from bulk-like to interface-dominated. At sufficiently low temperatures, water exhibits a quasi-universal $\\beta$ process, which is characterized by an activation energy of $E_a\\!=\\!0.5$ eV and involves anisotropic reorientation about large angles. As a consequence of its large amplitude, the faster $\\beta$ process destroys essentially all orientational correlation, rendering observation of a possible slower $\\alpha$ process difficult in standard experiments. Nevertheless, we find indications for the existence of structural relaxation down to a glass transition of interfacial water near 185 K. Hydrated proteins show a highly restricted backbone motion with an amplitude, which decreases upon cooling and vanishes at comparable temperatures, providing evidence for a high relevance of water rearrangements in the hydration shell for secondary protein relaxations.

Markus Rosenstihl; Kerstin Kämpf; Felix Klameth; Matthias Sattig; Michael Vogel

2014-07-21T23:59:59.000Z

415

Method of treating waste water  

DOE Patents [OSTI]

A process of treating water to remove metal ion contaminants contained therein, said metal ion contaminants selected from the group consisting of metals in Groups 8, 1b, 2b, 4a, 5a, or 6a of the periodic table, lanthanide metals, and actinide metals including transuranic element metals, by adjusting the pH of a metal ion contaminant-containing water source to within the range of about 6.5 to about 14.0, admixing the water source with a mixture of an alkali or alkaline earth ferrate and a water soluble salt, e.g., a zirconium salt, in an amount sufficient to form a precipitate within the water source, the amount the mixture of ferrate and water soluble salt effective to reduce the metal ion contaminant concentration in the water source, permitting the precipitate in the admixture to separate and thereby yield a supernatant liquid having a reduced metal ion contaminant concentration, and separating the supernatant liquid having the reduced metal ion contaminant concentration from the admixture is provided. A composition of matter including an alkali or alkaline earth ferrate and a water soluble salt, e.g., a zirconium salt, is also provided.

Deininger, James P. (Colorado Springs, CO); Chatfield, Linda K. (Colorado Springs, CO)

1995-01-01T23:59:59.000Z

416

Water Evaporation: A Transition Path Sampling Study  

E-Print Network [OSTI]

We use transition path sampling to study evaporation in the SPC/E model of liquid water. Based on thousands of evaporation trajectories, we characterize the members of the transition state ensemble (TSE), which exhibit a liquid-vapor interface with predominantly negative mean curvature at the site of evaporation. We also find that after evaporation is complete, the distributions of translational and angular momenta of the evaporated water are Maxwellian with a temperature equal to that of the liquid. To characterize the evaporation trajectories in their entirety, we find that it suffices to project them onto just two coordinates: the distance of the evaporating molecule to the instantaneous liquid-vapor interface, and the velocity of the water along the average interface normal. In this projected space, we find that the TSE is well-captured by a simple model of ballistic escape from a deep potential well, with no additional barrier to evaporation beyond the cohesive strength of the liquid. Equivalently, they are consistent with a near-unity probability for a water molecule impinging upon a liquid droplet to condense. These results agree with previous simulations and with some, but not all, recent experiments.

Patrick Varilly; David Chandler

2012-10-11T23:59:59.000Z

417

Reproducible cavitation activity in water-particle suspensions Bram M. Borkent, Manish Arora, and Claus-Dieter Ohla  

E-Print Network [OSTI]

Reproducible cavitation activity in water-particle suspensions Bram M. Borkent, Manish Arora January 2007 The study of cavitation inception in liquids rarely yields reproducible data, unless special technique is demonstrated which allows repeatable measurements of cavitation activity in liquid

Ohl, Claus-Dieter

418

Scanning probe microscopy: Sulfate minerals in scales and cements  

SciTech Connect (OSTI)

The principles of scanning probe microscopy (SPM) are illustrated with examples from oilfield mineralogy, particularly emphasizing sulfate minerals involved in scale formation and cement hydration chemistry. The topography of the (010) cleavage surface of gypsum observed by atomic force microscopy shows atomically flat terraces separated by shallow steps often only one unit cell high. SPM allows direct observation of processes on mineral surfaces while they are in contact with solutions. The dissolution etching and crystal growth of gypsum and barite are discussed and rates of step migration estimated. The orientation of steps is related to the crystallographic axes. The action of phosphonate crystal growth inhibitor on gypsum and of a chelating scale solvent on barite are also shown. The multiphase microstructure of an oilwell cement clinker is described in relation to its hydration chemistry in contact with water and its reaction with sulfate ions.

Hall, C. [Schlumberger Cambridge Research (United Kingdom)

1995-11-01T23:59:59.000Z

419

Protein structure and hydration probed by SANS and osmotic stress  

SciTech Connect (OSTI)

Interactions governing protein folding, stability, recognition, and activity are mediated by hydration. Here, we use small-angle neutron scattering coupled with osmotic stress to investigate the hydration of two proteins, lysozyme and guanylate kinase (GK), in the presence of solutes. By taking advantage of the neutron contrast variation that occurs upon addition of these solutes, the number of protein-associated (solute-excluded) water molecules can be estimated from changes in both the zero-angle scattering intensity and the radius of gyration. Poly(ethylene glycol) exclusion varies with molecular weight. This sensitivity can be exploited to probe structural features such as the large internal GK cavity. For GK, small-angle neutron scattering is complemented by isothermal titration calorimetry with osmoticstress to also measure hydration changes accompanying ligand binding. These results provide a framework for studying other biomolecular systems and assemblies using neutron scattering together with osmotic stress.

Rau, Dr. Donald [National Institutes of Health

2008-01-01T23:59:59.000Z

420

Fireside corrosion probes--an update  

SciTech Connect (OSTI)

The ability to monitor the corrosion degradation of key metallic components in fossil fuel power plants will become increasingly important for FutureGen and ultra-supercritical power plants. A number of factors (ash deposition, coal composition changes, thermal gradients, and low NOx conditions, among others) which occur in the high temperature sections of energy production facilities, will contribute to fireside corrosion. Several years of research have shown that high temperature corrosion rate probes need to be better understood before corrosion rate can be used as a process variable by power plant operators. Our recent research has shown that electrochemical corrosion probes typically measure lower corrosion rates than those measured by standard mass loss techniques. While still useful for monitoring changes in corrosion rates, absolute probe corrosion rates will need a calibration factor to be useful. Continuing research is targeted to help resolve these issues.

Covino, B.S., Jr.; Bullard, S.J.; Holcomb, G.R.; Ziomek-Moroz, M.; Matthes, S.A.

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Gamma-ray blind beta particle probe  

DOE Patents [OSTI]

An intra-operative beta particle probe is provided by placing a suitable photomultiplier tube (PMT), micro channel plate (MCP) or other electron multiplier device within a vacuum housing equipped with: 1) an appropriate beta particle permeable window; and 2) electron detection circuitry. Beta particles emitted in the immediate vicinity of the probe window will be received by the electron multiplier device and amplified to produce a detectable signal. Such a device is useful as a gamma insensitive, intra-operative, beta particle probe in surgeries where the patient has been injected with a beta emitting radiopharmaceutical. The method of use of such a device is also described, as is a position sensitive such device.

Weisenberger, Andrew G. (Grafton, VA)

2001-01-01T23:59:59.000Z

422

Remote adjustable focus Raman spectroscopy probe  

DOE Patents [OSTI]

A remote adjustable focus Raman spectroscopy probe allows for analyzing Raman scattered light from a point of interest external probe. An environmental barrier including at least one window separates the probe from the point of interest. An optical tube is disposed adjacent to the environmental barrier and includes a long working length compound lens objective next to the window. A beam splitter and a mirror are at the other end. A mechanical means is used to translated the prove body in the X, Y, and Z directions resulting in a variable focus optical apparatus. Laser light is reflected by the beam splitter and directed toward the compound lens objective, then through the window and focused on the point of interest. Raman scattered light is then collected by the compound lens objective and directed through the beam splitter to a mirror. A device for analyzing the light, such as a monochrometer, is coupled to the mirror.

Schmucker, John E. (Hurt, VA); Blasi, Raymond J. (Harrison City, PA); Archer, William B. (Bethel Park, PA)

1999-01-01T23:59:59.000Z

423

Ionic Liquid Pretreatment Technologies  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in3.pdfEnergy Health andofIan KalinResearch,IntroducingIonic Liquid Pretreatment EERE

424

A fresh look at coal-derived liquid fuels  

SciTech Connect (OSTI)

35% of the world's energy comes from oil, and 96% of that oil is used for transportation. The current number of vehicles globally is estimated to be 700 million; that number is expected to double overall by 2030, and to triple in developing countries. Now consider that the US has 27% of the world's supply of coal yet only 2% of the oil. Coal-to-liquids technologies could bridge the gap between US fuel supply and demand. The advantages of coal-derived liquid fuels are discussed in this article compared to the challenges of alternative feedstocks of oil sands, oil shale and renewable sources. It is argued that pollutant emissions from coal-to-liquid facilities could be minimal because sulfur compounds will be removed, contaminants need to be removed for the FT process, and technologies are available for removing solid wastes and nitrogen oxides. If CO{sub 2} emissions for coal-derived liquid plants are captured and sequestered, overall emissions of CO{sub 2} would be equal or less than those from petroleum. Although coal liquefaction requires large volumes of water, most water used can be recycled. Converting coal to liquid fuels could, at least in the near term, bring a higher level of stability to world oil prices and the global economy and could serve as insurance for the US against price hikes from oil-producing countries. 7 figs.

Paul, A.D. [Benham Companies LLC (USA)

2009-01-15T23:59:59.000Z

425

Microscopic Analysis of Corn Fiber Using Corn Starch- and Cellulose-Specific Molecular Probes  

SciTech Connect (OSTI)

Ethanol is the primary liquid transportation fuel produced from renewable feedstocks in the United States today. The majority of corn grain, the primary feedstock for ethanol production, has been historically processed in wet mills yielding products such as gluten feed, gluten meal, starch, and germ. Starch extracted from the grain is used to produce ethanol in saccharification and fermentation steps; however the extraction of starch is not 100% efficient. To better understand starch extraction during the wet milling process, we have developed fluorescent probes that can be used to visually localize starch and cellulose in samples using confocal microscopy. These probes are based on the binding specificities of two types of carbohydrate binding modules (CBMs), which are small substrate-specific protein domains derived from carbohydrate degrading enzymes. CBMs were fused, using molecular cloning techniques, to a green fluorescent protein (GFP) or to the red fluorescent protein DsRed (RFP). Using these engineered probes, we found that the binding of the starch-specific probe correlates with starch content in corn fiber samples. We also demonstrate that there is starch internally localized in the endosperm that may contribute to the high starch content in corn fiber. We also surprisingly found that the cellulose-specific probe did not bind to most corn fiber samples, but only to corn fiber that had been hydrolyzed using a thermochemical process that removes the residual starch and much of the hemicellulose. Our findings should be of interest to those working to increase the efficiency of the corn grain to ethanol process.

Porter, S. E.; Donohoe, B. S.; Beery, K. E.; Xu, Q.; Ding, S.-Y.; Vinzant, T. B.; Abbas, C. A.; Himmel, M. E.

2007-09-01T23:59:59.000Z

426

Supported liquid membrane electrochemical separators  

DOE Patents [OSTI]

Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

Pemsler, J. Paul (Lexington, MA); Dempsey, Michael D. (Revere, MA)

1986-01-01T23:59:59.000Z

427

Liquid monobenzoxazine based resin system  

DOE Patents [OSTI]

The present invention provides a liquid resin system including a liquid monobenzoxazine monomer and a non-glycidyl epoxy compound, wherein the weight ratio of the monobenzoxazine monomer to the non-glycidyl epoxy compound is in a range of about 25:75 to about 60:40. The liquid resin system exhibits a low viscosity and exceptional stability over an extended period of time making its use in a variety of composite manufacturing methods highly advantageous.

Tietze, Roger; Nguyen, Yen-Loan; Bryant, Mark

2014-10-07T23:59:59.000Z

428

Examination of Liquid Fluoride Salt Heat Transfer  

SciTech Connect (OSTI)

The need for high efficiency power conversion and energy transport systems is increasing as world energy use continues to increase, petroleum supplies decrease, and global warming concerns become more prevalent. There are few heat transport fluids capable of operating above about 600oC that do not require operation at extremely high pressures. Liquid fluoride salts are an exception to that limitation. Fluoride salts have very high boiling points, can operate at high temperatures and low pressures and have very good heat transfer properties. They have been proposed as coolants for next generation fission reactor systems, as coolants for fusion reactor blankets, and as thermal storage media for solar power systems. In each case, these salts are used to either extract or deliver heat through heat exchange equipment, and in order to design this equipment, liquid salt heat transfer must be predicted. This paper discusses the heat transfer characteristics of liquid fluoride salts. Historically, heat transfer in fluoride salts has been assumed to be consistent with that of conventional fluids (air, water, etc.), and correlations used for predicting heat transfer performance of all fluoride salts have been the same or similar to those used for water conventional fluids an, water, etc). A review of existing liquid salt heat transfer data is presented, summarized, and evaluated on a consistent basis. Less than 10 experimental data sets have been found in the literature, with varying degrees of experimental detail and measured parameters provided. The data has been digitized and a limited database has been assembled and compared to existing heat transfer correlations. Results vary as well, with some data sets following traditional correlations; in others the comparisons are less conclusive. This is especially the case for less common salt/materials combinations, and suggests that additional heat transfer data may be needed when using specific salt eutectics in heat transfer equipment designs. All of the data discussed above were taken under forced convective conditions (both laminar and turbulent). Some recent data taken at ORNL under free convection conditions are also presented and results discussed. This data was taken using a simple crucible experiment with an instrumented nickel heater inserted in the salt to induce natural circulation within the crucible. The data was taken over a temperature range of 550oC to 650oC in FLiNaK salt. This data covers both laminar and turbulent natural convection conditions, and is compared to existing forms of natural circulation correlations.

Yoder Jr, Graydon L [ORNL] [ORNL

2014-01-01T23:59:59.000Z

429

Scintillation probe with photomultiplier tube saturation indicator  

DOE Patents [OSTI]

A photomultiplier tube saturation indicator is formed by supplying a supplemental light source, typically an light emitting diode (LED), adjacent to the photomultiplier tube. A switch allows the light source to be activated. The light is forwarded to the photomultiplier tube by an optical fiber. If the probe is properly light tight, then a meter attached to the indicator will register the light from the LED. If the probe is no longer light tight, and the saturation indicator is saturated, no signal will be registered when the LED is activated.

Ruch, Jeffrey F. (Bethel Park, PA); Urban, David J. (Glassport, PA)

1996-01-01T23:59:59.000Z

430

Process for preparing liquid wastes  

DOE Patents [OSTI]

A process for preparing radioactive and other hazardous liquid wastes for treatment by the method of vitrification or melting is provided for.

Oden, Laurance L. (Albany, OR); Turner, Paul C. (Albany, OR); O'Connor, William K. (Lebanon, OR); Hansen, Jeffrey S. (Corvallis, OR)

1997-01-01T23:59:59.000Z

431

FLARE, Fermilab Liquid Argon Experiments  

E-Print Network [OSTI]

Mature technology of Liquid Argon Time Projection Chambers in conjunction with intense neutrino beams constructed at Fermilab offer a broad program of neutrino physics for the next decade.

L. Bartoszek

2004-08-24T23:59:59.000Z

432

Method of treating waste water  

DOE Patents [OSTI]

A process of treating water to remove transuranic elements contained therein by adjusting the pH of a transuranic element-containing water source to within the range of about 6.5 to about 14.0, admixing the water source with an alkali or alkaline earth ferrate in an amount sufficient to form a precipitate within the water source, the amount of ferrate effective to reduce the transuranic element concentration in the water source, permitting the precipitate in the admixture to separate and thereby yield a supernatant liquid having a reduced transuranic element concentration, and separating the supernatant liquid having the reduced transuranic element concentration from the admixture is provided. Additionally, a water soluble salt, e.g., a zirconium salt, can be added with the alkali or alkaline earth ferrate in the process to provide greater removal efficiencies. A composition of matter including an alkali or alkaline earth ferrate and a water soluble salt, e.g., a zirconium salt, is also provided.

Deininger, J. Paul (Colorado Springs, CO); Chatfield, Linda K. (Colorado Springs, CO)

1991-01-01T23:59:59.000Z

433

Terahertz Spectroscopy of Individual Single-Walled Carbon Nanotubes as a Probe of Luttinger Liquid Physics  

E-Print Network [OSTI]

researchers Aviad Frydman, Misha Reznikov, Bertrand Reulet, and Venkat Chandrasekhar for the insight

Prober, Daniel E.

434

Temperature-dependent vibrational relaxation in polyatomic liquids: Picosecond infrared pump-probe experiments  

E-Print Network [OSTI]

stretching vibration (-1980 cm-`) of Cr(CO), and W(CO& dissolved in carbon tetrachloride (Ccl hexacarbonyl [W(CO),] and chromium hexacarbonyl [Cr(CO),] in two solvents, carbon tetrachloride (CC14

Fayer, Michael D.

435

Selection of liquid-level monitoring method for the Oak Ridge National Laboratory inactive liquid low-level waste tanks, remedial investigation/feasibility study  

SciTech Connect (OSTI)

Several of the inactive liquid low-level waste (LLLW) tanks at Oak Ridge National Laboratory contain residual wastes in liquid or solid (sludge) form or both. A plan of action has been developed to ensure that potential environmental impacts from the waste remaining in the inactive LLLW tank systems are minimized. This document describes the evaluation and selection of a methodology for monitoring the level of the liquid in inactive LLLW tanks. Criteria are established for comparison of existing level monitoring and leak testing methods; a preferred method is selected and a decision methodology for monitoring the level of the liquid in the tanks is presented for implementation. The methodology selected can be used to continuously monitor the tanks pending disposition of the wastes for treatment and disposal. Tanks that are empty, are scheduled to be emptied in the near future, or have liquid contents that are very low risk to the environment were not considered to be candidates for installing level monitoring. Tanks requiring new monitoring equipment were provided with conductivity probes; tanks with existing level monitoring instrumentation were not modified. The resulting data will be analyzed to determine inactive LLLW tank liquid level trends as a function of time.

Not Available

1994-11-01T23:59:59.000Z

436

Model of a nuclear - optically - pumped liquid laser  

SciTech Connect (OSTI)

The model of a nuclear - optically - pumped liquid laser is constructed and the laser characteristics are analysed for different parameters of the setup and pump pulse, compositions of the converter media and active elements. The lasing parameters of the liquid laser using heavy-water solution of {sup 245}Cm as the converter medium and neodymium-containing phosphorous oxychloride (phosphoryl chloride) as the active element are calculated. It follows from the results of calculations that lasing can be achieved in these media pumped by neutrons from the BARS-6 reactor. (lasers)

Seregin, A A; D'yachenko, P P; Seregina, E A [State Scientific Center of the Russian Federation 'A.I. Leipunski Institute for Physics and Power Engineering', Obninsk, Kaluga Region (Russian Federation)

2003-06-30T23:59:59.000Z

437

Water Intoxication  

E-Print Network [OSTI]

2008, May 14). Too much water raises seizure risk in babies.id=4844 9. Schoenly, Lorry. “Water Intoxication and Inmates:article/246650- overview>. 13. Water intoxication alert. (

Lingampalli, Nithya

2013-01-01T23:59:59.000Z

438

Polarizable molecules in the vibrational spectroscopy of water  

E-Print Network [OSTI]

correlation functions and transport properties of liquid water that were im- pressive for their time. Stillinger (2) described the peculiar chemical and physical properties of water in terms of the microscopic bonding in water. The potential energy models developed in these early studies provided guidelines

Berne, Bruce J.

439

WATER, PROPERTIES D Hillel, Columbia University, New York, NY, USA  

E-Print Network [OSTI]

with an abundance of it, even with a surfeit, so that often the problem is how to dispose of excess water. Arid, inert liquid, water is a highly reactive substance, a solvent and a transporter of numerous substances. In the Middle Ages, people believed that fresh water emanated magically from the bowels of the earth. They could

440

The Nexus of Energy & Water APS, Berkeley, CA  

E-Print Network [OSTI]

Freshwater Is A Small Part of the Total Supply Liquid Assets, Jill Boberg, RAND #12;Michael E. Webber, Ph There Are Two Main Cooling Approaches Open-Loop Cooling Closed-Loop Cooling Most water that is withdrawn and Water 16 March 5, 2011 The Thermoelectric Power Sector Uses Water for Cooling Withdrawals [gal

Kammen, Daniel M.

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Water Quality  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of desalination research. The primary technological method of generating additional water supplies is through desalination and enhanced water reuse and recycling technologies....

442

Probe and method for DNA detection  

DOE Patents [OSTI]

A hybridization probe containing two linear strands of DNA lights up upon hybridization to a target DNA using silver nanoclusters that have been templated onto one of the DNA strands. Hybridization induces proximity between the nanoclusters on one strand and an overhang on the other strand, which results in enhanced fluorescence emission from the nanoclusters.

Yeh, Hsin-Chih; Werner, James Henry; Sharma, Jaswinder Kumar; Martinez, Jennifer Suzanne

2013-07-02T23:59:59.000Z

443

Probe Measurements of Electrostatic Fluctuations in LDX  

E-Print Network [OSTI]

-axis ­ Motor positioning controlled with PLC · VERTICAL PROBES: ­ -pos: one - two meters off mid-plane ­ -pos density. Density(cm-3 ) 0.00118 0.0000 PlasmaFlux (Tesla/sec) 1010 109 #12;7 Electric Fluctuations

444

Astrophysikalisches Institut Potsdam Probes of Dark Energy  

E-Print Network [OSTI]

Astrophysikalisches Institut Potsdam Probes of Dark Energy using Cosmological Simulations Nonlinear component, called dark energy. This unknown energy causes the expansion of the universe to accelerate theoretical model of dark energy has been developed. Instead a number of models have been proposed that range

445

High temperature electrochemical corrosion rate probes  

SciTech Connect (OSTI)

Corrosion occurs in the high temperature sections of energy production plants due to a number of factors: ash deposition, coal composition, thermal gradients, and low NOx conditions, among others. Electrochemical corrosion rate (ECR) probes have been shown to operate in high temperature gaseous environments that are similar to those found in fossil fuel combustors. ECR probes are rarely used in energy production plants at the present time, but if they were more fully understood, corrosion could become a process variable at the control of plant operators. Research is being conducted to understand the nature of these probes. Factors being considered are values selected for the Stern-Geary constant, the effect of internal corrosion, and the presence of conductive corrosion scales and ash deposits. The nature of ECR probes will be explored in a number of different atmospheres and with different electrolytes (ash and corrosion product). Corrosion rates measured using an electrochemical multi-technique capabilities instrument will be compared to those measured using the linear polarization resistance (LPR) technique. In future experiments, electrochemical corrosion rates will be compared to penetration corrosion rates determined using optical profilometry measurements.

Bullard, Sophie J.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Ziomek-Moroz, M.

2005-09-01T23:59:59.000Z

446

Lecs 2 and 3. Properties of air and water and Earth system; GFD1 AS509/OC512 Winter 2011  

E-Print Network [OSTI]

sound speed (or `compressibility'), specific heat capacity, thermal expansion coefficient, freezing hydrogen molecules attract one another giving the liquid some long-range order. Water is a generally density than liquid water (most substances are more dense when frozen). The density of pure water, about

447

When preparing for a disaster, it is important to provide for an adequate supply of water for drinking and cook-  

E-Print Network [OSTI]

in a household needs about 2 quarts of liquid per day for drinking and cooking. This can come from water for drinking as well as other liquids, such as juices or soft drinks. Additional clean water is neededWhen preparing for a disaster, it is important to provide for an adequate supply of water

Liskiewicz, Maciej

448

Molecular dynamics simulations of water structure and diffusion in silica nanopores  

E-Print Network [OSTI]

the extended simple point charge (SPC/E) water model 64 forcoefficient of bulk liquid SPC/E water (D 0 = 2.4 ? 0.4 ?To account for the fact that the SPC/E model over- estimates

Bourg, I.C.

2013-01-01T23:59:59.000Z

449

Dynamics of water and aqueous protons studied using ultrafast multi-dimensional infrared spectroscopy  

E-Print Network [OSTI]

Liquid water consists of a highly dynamic network of hydrogen bonds, which evolves on timescales ranging from tens of femtoseconds to a few picoseconds. The fast structural evolution of water's hydrogen bond network is at ...

Ramasesha, Krupa

2013-01-01T23:59:59.000Z

450

Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems  

E-Print Network [OSTI]

interest in subcritical (hot/liquid) water from 298 K to 473subcritical region. Modeling Studies on the Transport of Benzene and H 2 S in CO 2 -Water

Zheng, L.

2011-01-01T23:59:59.000Z

451

Lithium-loaded liquid scintillators  

DOE Patents [OSTI]

The invention is directed to a liquid scintillating composition containing (i) one or more non-polar organic solvents; (ii) (lithium-6)-containing nanoparticles having a size of up to 10 nm and surface-capped by hydrophobic molecules; and (iii) one or more fluorophores. The invention is also directed to a liquid scintillator containing the above composition.

Dai, Sheng (Knoxville, TN); Kesanli, Banu (Mersin, TR); Neal, John S. (Knoxville, TN)

2012-05-15T23:59:59.000Z

452

ELECTROSTATIC PROBE DIAGNOSTICS ON THE LBL 10 AMPERE NEUTRAL BEAM ION SOURCE  

E-Print Network [OSTI]

Probes," in Plasma Diagnostics (Lochte- Holtgreven, eds. ),Electric Probes," in Plasma Diagnostic Techniques (R. H.Spatial probe diagnostics schematic. Radial plasma profile:

Schoenberg, Kurt F.

2011-01-01T23:59:59.000Z

453

Semiconductor nanocrystal probes for biological applications and process for making and using such probes  

DOE Patents [OSTI]

A semiconductor nanocrystal compound and probe are described. The compound is capable of linking to one or more affinity molecules. The compound comprises (1) one or more semiconductor nanocrystals capable of, in response to exposure to a first energy, providing a second energy, and (2) one or more linking agents, having a first portion linked to the one or more semiconductor nanocrystals and a second portion capable of linking to one or more affinity molecules. One or more semiconductor nanocrystal compounds are linked to one or more affinity molecules to form a semiconductor nanocrystal probe capable of bonding with one or more detectable substances in a material being analyzed, and capable of, in response to exposure to a first energy, providing a second energy. Also described are processes for respectively: making the semiconductor nanocrystal compound; making the semiconductor nanocrystal probe; and treating materials with the probe.

Weiss, Shimon; Bruchez, Marcel; Alivisatos, Paul

2014-01-28T23:59:59.000Z

454

Semiconductor nanocrystal probes for biological applications and process for making and using such probes  

DOE Patents [OSTI]

A semiconductor nanocrystal compound and probe are described. The compound is capable of linking to one or more affinity molecules. The compound comprises (1) one or more semiconductor nanocrystals capable of, in response to exposure to a first energy, providing a second energy, and (2) one or more linking agents, having a first portion linked to the one or more semiconductor nanocrystals and a second portion capable of linking to one or more affinity molecules. One or more semiconductor nanocrystal compounds are linked to one or more affinity molecules to form a semiconductor nanocrystal probe capable of bonding with one or more detectable substances in a material being analyzed, and capable of, in response to exposure to a first energy, providing a second energy. Also described are processes for respectively: making the semiconductor nanocrystal compound; making the semiconductor nanocrystal probe; and treating materials with the probe.

Weiss, Shimon; Bruchez, Marcel; Alivisatos, Paul

2012-10-16T23:59:59.000Z

455

Development of a graphite probe calorimeter for absolute clinical dosimetry  

SciTech Connect (OSTI)

The aim of this work is to present the numerical design optimization, construction, and experimental proof of concept of a graphite probe calorimeter (GPC) conceived for dose measurement in the clinical environment (U.S. provisional patent 61/652,540). A finite element method (FEM) based numerical heat transfer study was conducted using a commercial software package to explore the feasibility of the GPC and to optimize the shape, dimensions, and materials used in its design. A functioning prototype was constructed inhouse and used to perform dose to water measurements under a 6 MV photon beam at 400 and 1000 MU/min, in a thermally insulated water phantom. Heat loss correction factors were determined using FEM analysis while the radiation field perturbation and the graphite to water absorbed dose conversion factors were calculated using Monte Carlo simulations. The difference in the average measured dose to water for the 400 and 1000 MU/min runs using the TG-51 protocol and the GPC was 0.2% and 1.2%, respectively. Heat loss correction factors ranged from 1.001 to 1.002, while the product of the perturbation and dose conversion factors was calculated to be 1.130. The combined relative uncertainty was estimated to be 1.4%, with the largest contributors being the specific heat capacity of the graphite (type B, 0.8%) and the reproducibility, defined as the standard deviation of the mean measured dose (type A, 0.6%). By establishing the feasibility of using the GPC as a practical clinical absolute photon dosimeter, this work lays the foundation for further device enhancements, including the development of an isothermal mode of operation and an overall miniaturization, making it potentially suitable for use in small and composite radiation fields. It is anticipated that, through the incorporation of isothermal stabilization provided by temperature controllers, a subpercent overall uncertainty will be achieved.

Renaud, James; Seuntjens, Jan; Sarfehnia, Arman [Medical Physics Unit, McGill University, Montreal, Quebec H3G 1A4 (Canada); Marchington, David [Ionizing Radiation Standards, National Research Council of Canada, Ottawa, Ontario K1A 0R6 (Canada)

2013-02-15T23:59:59.000Z

456

Method for treating liquid wastes  

DOE Patents [OSTI]

The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering {sup 99}Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of {sup 99}TcO{sub 4}{sup {minus}} from aqueous solutions into organic solvents or mixed organic/polar media, extraction of {sup 99}Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester {sup 99}Tc from those liquids. 6 figs.

Katti, K.V.; Volkert, W.A.; Singh, P.; Ketring, A.R.

1995-12-26T23:59:59.000Z

457

Method for treating liquid wastes  

DOE Patents [OSTI]

The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering .sup.99 Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of .sup.99 TcO.sub.4.sup.- from aqueous solutions into organic solvents or mixed organic/polar media, extraction of .sup.99 Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester .sup.99 Tc from those liquids.

Katti, Kattesh V. (Columbia, MO); Volkert, Wynn A. (Columbia, MO); Singh, Prahlad (Columbia, MO); Ketring, Alan R. (Columbia, MO)

1995-01-01T23:59:59.000Z

458

Surface enhanced Raman gene probe and methods thereof  

DOE Patents [OSTI]

The subject invention disclosed herein is a new gene probe biosensor and methods based on surface enhanced Raman scattering (SERS) label detection. The SER gene probe biosensor comprises a support means, a SER gene probe having at least one oligonucleotide strand labeled with at least one SERS label, and a SERS active substrate disposed on the support means and having at least one of the SER gene probes adsorbed thereon. Biotargets such as bacterial and viral DNA, RNA and PNA are detected using a SER gene probe via hybridization to oligonucleotide strands complementary to the SER gene probe. The support means supporting the SERS active substrate includes a fiberoptic probe, an array of fiberoptic probes for performance of multiple assays and a waveguide microsensor array with charge-coupled devices or photodiode arrays. 18 figs.

Vo-Dinh, T.

1998-09-29T23:59:59.000Z

459

Surface enhanced Raman gene probe and methods thereof  

DOE Patents [OSTI]

The subject invention disclosed is a new gene probe biosensor and methods based on surface enhanced Raman scattering (SERS) label detection. The SER gene probe biosensor comprises a support means, a SER gene probe having at least one oligonucleotide strand labeled with at least one SERS label, and a SERS active substrate disposed on the support means and having at least one of the SER gene probes adsorbed. Biotargets such as bacterial and viral DNA, RNA and PNA are detected using a SER gene probe via hybridization to oligonucleotide strands complementary to the SER gene probe. The support means supporting the SERS active substrate includes a fiberoptic probe, an array of fiberoptic probes for performance of multiple assays and a waveguide microsensor array with charge-coupled devices or photodiode arrays. 18 figs.

Vo-Dinh, T.

1998-07-21T23:59:59.000Z

460

Lens-array PDV Probe Using a Pyramid Prism  

SciTech Connect (OSTI)

A bug eye probe is shown using a pyramid prism, and its advantages and disadvantages are enumerated. Also shown is abug eye imaging probe, with its advantages and disadvantages enumerated.

Malone, R. M., Kaufman, M. I., Cox, B., Romero, V., Cata B., Sorenson, D. Pazuchanics, P.

2011-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Surface enhanced Raman gene probe and methods thereof  

DOE Patents [OSTI]

The subject invention disclosed is a new gene probe biosensor and methods based on surface enhanced Raman scattering (SERS) label detection. The SER gene probe biosensor comprises a support means, a SER gene probe having at least one oligonucleotide strand labeled with at least one SERS label, and a SERS active substrate disposed on the support means and having at least one of the SER gene probes adsorbed thereon. Biotargets such as bacterial and viral DNA, RNA and PNA are detected using a SER gene probe via hybridization to oligonucleotide strands complementary to the SER gene probe. The support means includes a fiberoptic probe, an array of fiberoptic probes for performance of multiple assays and a waveguide microsensor array with charge-coupled devices or photodiode arrays. 18 figs.

Vo-Dinh, T.

1998-02-24T23:59:59.000Z

462

acceleration probe studying: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

23 24 25 Next Page Last Page Topic Index 1 Supernova Acceleration Probe: Studying Dark Energy with Type Ia Supernovae Astrophysics (arXiv) Summary: The Supernova Acceleration Probe...

463

Steady and unsteady calibration of multi-hole probes  

E-Print Network [OSTI]

This thesis presents the development of a data crographics. reduction algorithm for multi-hole pressure probes. The algorithm has been developed for the reduction of calibration data from miniature non-nulling multi-hole probes in compressible...

Johansen, Espen S

1998-01-01T23:59:59.000Z

464

Monitoring system for a liquid-cooled nuclear fission reactor  

DOE Patents [OSTI]

A monitoring system for detecting changes in the liquid levels in various regions of a water-cooled nuclear power reactor, viz., in the downcomer, in the core, in the inlet and outlet plenums, at the head, and elsewhere; and also for detecting changes in the density of the liquid in these regions. A plurality of gamma radiation detectors are used, arranged vertically along the outside of the reactor vessel, and collimator means for each detector limits the gamma-radiation it receives as emitting from only isolated regions of the vessel. Excess neutrons produced by the fission reaction will be captured by the water coolant, by the steel reactor walls, or by the fuel or control structures in the vessel. Neutron capture by steel generates gamma radiation having an energy level of the order of 5-12 MeV, whereas neutron capture by water provides an energy level of approximately 2.2 MeV, and neutron capture by the fission fuel or its cladding provides an energy level of 1 MeV or less. The intensity of neutron capture thus changes significantly at any water-metal interface. Comparative analysis of adjacent gamma detectors senses changes from the normal condition with liquid coolant present to advise of changes in the presence and/or density of the coolant at these specific regions. The gamma detectors can also sense fission-product gas accumulation at the reactor head to advise of a failure of fuel-pin cladding.

DeVolpi, Alexander (Bolingbrook, IL)

1987-01-01T23:59:59.000Z

465

Shearing Flows in Liquid Crystal Models  

E-Print Network [OSTI]

The liquid crystal phase is a phase of matter between the solid and liquid phase whose flow is characterized by a velocity field and a director field which describes locally the orientation of the liquid crystal. In this ...

Dorn, Timothy

2012-05-31T23:59:59.000Z

466

Drop-size distribution for crosscurrent breakup of a liquid jet in a convective airstream  

E-Print Network [OSTI]

for the injected liquid, distilled water, is held constant at 10.240 atm for the five different nozzle orifice diameters. A water rotameter is used to vary flowrates from 0.75 to 5.0 GPH and airflow Reynolds numbers are set at 50,000, 60,000, and 70,000 depending...

Lyn, Gregory Michael

2012-06-07T23:59:59.000Z

467

In-situ continuous water monitoring system  

DOE Patents [OSTI]

An in-situ continuous liquid monitoring system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container by the flow of carrier gas into the liquid directing device. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectrometer and the volatile components are continuously analyzed by the mass spectrometer. 2 figs.

Thompson, C.V.; Wise, M.B.

1998-03-31T23:59:59.000Z

468

NOCHAR Polymers: An Aqueous and Organic Liquid Solidification Process for Cadarache LOR (Liquides Organiques Radioactifs) - 13195  

SciTech Connect (OSTI)

To handle the Very Low Level Waste (VLLW) and the Low Level Waste (LLW) in France, two options can be considered: the incineration at CENTRACO facility and the disposal facility on ANDRA sites. The waste acceptance in these radwaste routes is dependent upon the adequacy between the waste characteristics (physical chemistry and radiological) and the radwaste route specifications. If the waste characteristics are incompatible with the radwaste route specifications (presence of significant quantities of chlorine, fluorine, organic component etc or/and high activity limits), it is necessary to find an alternative solution that consists of a waste pre-treatment process. In the context of the problematic Cadarache LOR (Liquides Organiques Radioactifs) waste streams, two radioactive scintillation cocktails have to be treated. The first one is composed of organic liquids at 13.1 % (diphenyloxazol, mesitylene, TBP, xylene) and water at 86.9 %. The second one is composed of TBP at 8.6 % and water at 91.4 %. They contain chlorine, fluorine and sulphate and have got alpha/beta/gamma spectra with mass activities equal to some kBq.g{sup -1}. Therefore, tritium is present and creates the second problematic waste stream. As a consequence, in order for disposal acceptance at the ANDRA site, it is necessary to pre-treat the waste. The NOCHAR polymers as an aqueous and organic liquid solidification process seem to be an adequate solution. Indeed, these polymers constitute an important variety of products applied to the treatment of radioactive aqueous and organic liquids (solvent, oil, solvent/oil mixing etc) and sludge through a mechanical and chemical solidification process. For Cadarache LOR, N910 and N960 respectively dedicated to the organic and aqueous liquids solidification are considered. With the N910, the organic waste solidification occurs in two steps. As the organic liquid travels moves through the polymer strands, the strands swell and immobilise the liquid. Then as the polymer-organic cure, over time, the polymer continues to collapse on the organic to create a permanent bond. The N960 has the ability to absorb aqueous waste up to 100 times its own weight. It creates a strong mechanical bond which permanently traps the contamination imbedded in the aqueous liquids. As a consequence, these two polymers seem to be able to constitute a suitable solidification matrix for a final acceptance in storage on ANDRA sites. In order to validate the polymers as an acceptable aqueous and organic solidification process for Cadarache LOR, some solidification tests realized with N910 and N960, have been carried out for different Waste/Polymer ratios. The determination of the best Waste/Polymer ratio and of the optimal experimental parameters has been made through an exudation test. Indeed, the process prevents leaching and it results in the absence of residual free organic or aqueous liquid which is forbidden in storage by ANDRA specifications. With these test results, we generated scientific data which are fundamental to obtain an ANDRA agreement. As a conclusion, the aim of this study is to demonstrate that the solidification by polymers can constitute a pre-treatment solution for Cadarache LOR and more generally, for various organic and mixed organic/aqueous waste which can not be directly acceptable at CENTRACO facility or at ANDRA storage sites. This work is, therefore, a solid background to demonstrate the feasibility of the waste pre-treatment by solidification with polymers and to encourage the development of this process. (authors)

Vaudey, Claire-Emilie; Renou, Sebastien; Porco, Julien [AREVA CL BU, STMI ZAC de Courcelle 1 route de la Noue 91196 Gif-sur-Yvette (France)] [AREVA CL BU, STMI ZAC de Courcelle 1 route de la Noue 91196 Gif-sur-Yvette (France); Kelley, Dennis [Pacific World Trade, Inc. Hillsdale Technical Center 6970 Hillsdale Court Indianapolis, Indiana 46250 (United States)] [Pacific World Trade, Inc. Hillsdale Technical Center 6970 Hillsdale Court Indianapolis, Indiana 46250 (United States); Cochaud, Chantal [CEA Cadarache, DSN/SGTD, 13108 St Paul Lez Durance Cedex (France)] [CEA Cadarache, DSN/SGTD, 13108 St Paul Lez Durance Cedex (France); Serrano, Roger [CEA Marcoule, DPAD, BP 17171, 30207 Bagnols sur Ceze Cedex (France)] [CEA Marcoule, DPAD, BP 17171, 30207 Bagnols sur Ceze Cedex (France)

2013-07-01T23:59:59.000Z

469

Method of measuring a liquid pool volume  

DOE Patents [OSTI]

A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid.

Garcia, Gabe V. (Las Cruces, NM); Carlson, Nancy M. (Idaho Falls, ID); Donaldson, Alan D. (Idaho Falls, ID)

1991-01-01T23:59:59.000Z

470

Structural Rearrangements in Water Viewed Through Two- Dimensional Infrared Spectroscopy  

E-Print Network [OSTI]

Compared with other molecular liquids, water is highly structured because of its ability to form up to four hydrogen bonds, resulting in a tetrahedral network of molecules. However, this underlying intermolecular structure ...

Roberts, Sean Thomas

471

Vibrational dynamics in water from the molecule's perspective  

E-Print Network [OSTI]

Liquid water is a fascinating substance, ubiquitous in chemistry, physics, and biology. Its remarkable physical and chemical properties stem from the intricate network of hydrogen bonds that connect molecular participants. ...

Eaves, Joel David, 1976-

2005-01-01T23:59:59.000Z

472

Vibrational Sum Frequency Spectroscopy and Molecular Dynamics Simulation of the Carbon Tetrachloride-Water and 1,2-Dichloroethane-Water Interfaces  

E-Print Network [OSTI]

and bonding at the carbon tetrachloride-water (CCl4-H2O) and the 1,2-dichloroethane-water (DCE-H2O) liquidVibrational Sum Frequency Spectroscopy and Molecular Dynamics Simulation of the Carbon Tetrachloride-Water and 1,2-Dichloroethane-Water Interfaces Dave S. Walker, Fred G. Moore, and Geraldine L

Richmond, Geraldine L.

473

Can a Pump-probe Experiment be Simulated Efficiently?  

E-Print Network [OSTI]

Can a Pump-probe Experiment be Simulated Efficiently? Thesis Submitted for the Degree Doctor things in the world. #12;i ABSTRACT Measuring a quantum system disturbs its evolution. A pump-probe exper measurements. Modeling the evolution of observables in the pump-probe experiment is an essential ingredient

Kosloff, Ronnie

474

Corrosion mitigation considerations in planning for zero liquid discharge  

SciTech Connect (OSTI)

A reduction in the availability and in the quality of water, coupled with more significantly more stringent water discharge restrictions, has resulted in increasing numbers of industrial complexes investigating water reuse and zero liquid discharge. Their investigation generally includes a survey of the potential impact of increased dissolved solids on the formation of mineral salt scales on heat transfer surfaces. These predictive tools are readily available and fairly accurate. The prediction of corrosion potential, however, is not as clearly defined, and as a consequence, little consideration is given to the effects of increased solids on corrosion. In addition to the potential for accelerated corrosion related to increased dissolved solids, many reuse waters contain elevated levels of biological activity and are rich in the nutrients that feed these micro organisms. This paper looks at the reasons for selecting zero liquid discharge as a means of water conservation and discharge reduction, the unit operations available to achieve these goals, and the corrosion mechanisms and mitigation associated with reuse water.

DeWitt-Dick, D.B. [Ashland Chemical Co., Portland, TX (United States). Drew Industrial Division; Lee, B. [Ashland Chemical Co., Boonton, NJ (United States). Drew Industrial Division

1995-12-01T23:59:59.000Z

475

Renewable Liquid Fuels Reforming | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Renewable Liquid Fuels Reforming The Program anticipates that distributed reforming of biomass-derived liquid fuels could be commercial during the transition to hydrogen and used...

476

Singular Limits in Polymer Stabilized Liquid Crystals  

E-Print Network [OSTI]

We investigate equilibrium configurations for a polymer stabilized liquid crys- tal material ... eling the cross section of the liquid crystal-polymer fiber composite.

1910-31-00T23:59:59.000Z

477

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...  

Broader source: Energy.gov (indexed) [DOE]

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

478

Marketing water  

E-Print Network [OSTI]

management, water conservation programs Story by Kathy Wythe tx H2O | pg. 17 public information programs and materials that increase awareness about regional water issues. The company recently opened the TecH2O, a water resource learning center...tx H2O | pg. 16 W ith rapid population growth and the memory of the worst drought in 50 years, cities and groups are promoting programs that educate their constituents about water quality, water conservation, and landscape management. Many...

Wythe, Kathy

2008-01-01T23:59:59.000Z

479

Equation of State of Supercooled Water from the Sedimentation Profile  

E-Print Network [OSTI]

To study the coexistence of two liquid states of water within one simulation box, we implement an equilibrium sedimentation method--which involves applying a gravitational field to the system and measuring/calculating the resulting density profile in equilibrium. We simulate a system of particles interacting via the ST2 potential, a model for water. We detect the coexistence of two liquid phases at low temperature.

M. Yamada; H. E. Stanley; F. Sciortino

2002-08-23T23:59:59.000Z

480

Liquid chromatographic extraction medium  

DOE Patents [OSTI]

A method and apparatus for extracting strontium and technetium values from biological, industrial and environmental sample solutions using a chromatographic column is described. An extractant medium for the column is prepared by generating a solution of a diluent containing a Crown ether and dispersing the solution on a resin substrate material. The sample solution is highly acidic and is introduced directed to the chromatographic column and strontium or technetium is eluted using deionized water.

Horwitz, E. Philip (Naperville, IL); Dietz, Mark L. (Evanston, IL)

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Liquid chromatographic extraction medium  

DOE Patents [OSTI]

A method and apparatus are disclosed for extracting strontium and technetium values from biological, industrial and environmental sample solutions using a chromatographic column. An extractant medium for the column is prepared by generating a solution of a diluent containing a Crown ether and dispersing the solution on a resin substrate material. The sample solution is highly acidic and is introduced directed to the chromatographic column and strontium or technetium is eluted using deionized water. 1 fig.

Horwitz, E.P.; Dietz, M.L.

1994-09-13T23:59:59.000Z

482

Site tests validate benefits of cavern probes  

SciTech Connect (OSTI)

More than 5 years` experience with downhole probes has allowed TransGas Ltd., Regina, to monitor and evaluate cavern integrity. The devices access natural-gas storage caverns` pressures and temperatures. Acquired data have helped determine gas-in-place inventory volumes, confirm spatial volumes, and assess changes in spatial volumes that may have resulted from cavern creep (shrinkage or closure) or downhole abnormality such as fluid infill or collapse of the side walls or roof areas. This conclusion of two articles presents details and results of a specific storage-site. The first article presented background and many of the details and lessons of TransGas` cavern gas-storage probe program.

Crossley, N.G. [TransGas Ltd., Regina, Saskatchewan (Canada)

1997-03-10T23:59:59.000Z

483

Non-Contact Gaging with Laser Probe  

SciTech Connect (OSTI)

A gage has been constructed using conventional (high end) components for the application of measuring fragile syntactic foam parts in a non-contact mode. Success with this approach has been achieved through a novel method of transferring (mapping) high accuracy local measurements of a coated aluminum master, taken on a Leitz Coordinate Measurement Machine (CMM), to the gage software system. The mapped data is then associated with local voltage readings from two (inner and outer) laser triangulating probes. This couples discreet laser probe offset and linearity characteristics to the measured master geometry. The gage software compares real part measured data against the master data to provide non-contact part inspection that results in a high accuracy and low uncertainty performance. Uncertainty from the part surface becomes the prevailing contributor to the gaging process. The gaging process provides a high speed, hands off measurement with nearly zero impedance.

Clinesmith, Mike

2009-03-20T23:59:59.000Z

484

Probing Nano-Mechanical QED Effects  

E-Print Network [OSTI]

We propose and study an "intrinsic probing" approach, without introducing any external detector, to mimic cavity QED effects in a qubit-nanomechanical resonator system. This metallic nanomechanical resonator can act as an intrinsic detector when a weak driving current passes through it. The nanomechanical resonator acts as both the cavity and the detector. A cavity QED-like effect is demonstrated by the correlation spectrum of the electromotive force between the two ends of the nanomechanical resonator. Using the quantum regression theorem and perturbation theory, we analytically calculate the correlation spectrum. In the weak driving limit, we study the effect on the vacuum Rabi splitting of both the strength of the driving as well as the frequency-detuning between the charge qubit and the nanomechanical resonator. Numerical calculations confirm the validity of our intrinsic probing approach.

Y. B. Gao; S. Yang; Yu-xi Liu; C. P. Sun; Franco Nori

2009-02-15T23:59:59.000Z

485

Probe for EPMA v. 10.3.5 User's Guide and Reference  

E-Print Network [OSTI]

Database for Data Integrity...........................................................15 History of Probe

486

Regenerable activated bauxite adsorbent alkali monitor probe  

DOE Patents [OSTI]

A regenerable activated bauxite adsorber alkali monitor probe for field applications to provide reliable measurement of alkali-vapor concentration in combustion gas with special emphasis on pressurized fluidized-bed combustion (PFBC) off-gas. More particularly, the invention relates to the development of a easily regenerable bauxite adsorbent for use in a method to accurately determine the alkali-vapor content of PFBC exhaust gases. 6 figs.

Lee, S.H.D.

1992-12-22T23:59:59.000Z

487

Hydrophobic ionic liquids  

DOE Patents [OSTI]

Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F--, Cl--, CF.sub.3 --, SF.sub.5 --, CF.sub.3 S--, (CF.sub.3).sub.2 CHS-- or (CF.sub.3).sub.3 CS--; and X.sup.- is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 .ANG..sup.3.

Koch, Victor R. (Lincoln, MA); Nanjundiah, Chenniah (Lynn, MA); Carlin, Richard T. (Nashua, NH)

1998-01-01T23:59:59.000Z

488

Hydrophobic ionic liquids  

DOE Patents [OSTI]

Ionic liquids having improved properties for application in non-aqueous batteries, electrochemical capacitors, electroplating, catalysis and chemical separations are disclosed. Exemplary compounds have one of the following formulas shown in a diagram wherein R{sub 1}, R{sub 2}, R{sub 3}, R{sub 4}, R{sub 5}, and R{sub 6} are either H; F; separate alkyl groups of from 1 to 4 carbon atoms, respectively, or joined together to constitute a unitary alkylene radical of from 2 to 4 carbon atoms forming a ring structure converging on N; or separate phenyl groups; and wherein the alkyl groups, alkylene radicals or phenyl groups may be substituted with electron withdrawing groups, preferably F-, Cl-, CF{sub 3}-, SF{sub 5}-, CF{sub 3}S-, (CF{sub 3}){sub 2}CHS- or (CF{sub 3}){sub 3}CS-; and X{sup {minus}} is a non-Lewis acid-containing polyatomic anion having a van der Waals volume exceeding 100 {angstrom}{sup 3}. 4 figs.

Koch, V.R.; Nanjundiah, C.; Carlin, R.T.

1998-10-27T23:59:59.000Z

489

Electrical detection of liquid lithium leaks from pipe joints  

SciTech Connect (OSTI)

A test stand for flowing liquid lithium is under construction at Princeton Plasma Physics Laboratory. As liquid lithium reacts with atmospheric gases and water, an electrical interlock system for detecting leaks and safely shutting down the apparatus has been constructed. A defense in depth strategy is taken to minimize the risk and impact of potential leaks. Each demountable joint is diagnosed with a cylindrical copper shell electrically isolated from the loop. By monitoring the electrical resistance between the pipe and the copper shell, a leak of (conductive) liquid lithium can be detected. Any resistance of less than 2 k? trips a relay, shutting off power to the heaters and pump. The system has been successfully tested with liquid gallium as a surrogate liquid metal. The circuit features an extensible number of channels to allow for future expansion of the loop. To ease diagnosis of faults, the status of each channel is shown with an analog front panel LED, and monitored and logged digitally by LabVIEW.

Schwartz, J. A., E-mail: jschwart@pppl.gov; Jaworski, M. A.; Mehl, J.; Kaita, R.; Mozulay, R. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543-0451 (United States)

2014-11-15T23:59:59.000Z

490

Use of a fiber optic probe for organic species determination  

DOE Patents [OSTI]

A fiber optic probe for remotely detecting the presence and concentration organic species in aqueous solutions. The probe includes a cylindrical housing with an organic species indicator, preferably diaminonaphthyl sulfonic acid adsorbed in a silica gel (DANS-modified gel), contained in the probe's distal end. The probe admits aqueous solutions to the probe interior for mixing within the DANS-modified gel. An optical fiber transmits light through the DANS-modified gel while the indicator reacts with organic species present in the solution, thereby shifting the location of the fluorescent peak. The altered light is reflected to a receiving fiber that carries the light to a spectrophotometer or other analysis device.

Ekechukwu, Amy A. (Augusta, GA)

1996-01-01T23:59:59.000Z

491

Dielectric covered hairpin probe for its application in reactive plasmas  

SciTech Connect (OSTI)

The hairpin probe is a well known technique for measuring local electron density in low temperature plasmas. In reactive plasmas, the probe characteristics are affected by surface sputtering, contamination, and secondary electron emission. At higher densities, the plasma absorbs the entire electromagnetic energy of hairpin and hence limits the density measurements. These issues can be resolved by covering the hairpin surface with a thin layer of dielectric. In this letter, the dielectric contribution to the probe characteristics is incorporated in a theory which is experimentally verified. The dielectric covering improves the performance of probe and also allows the hairpin tip to survive in reactive plasma where classical electrical probes are easily damaged.

Gogna, G. S.; Gaman, C.; Turner, M. M. [NCPST, School of Physical Sciences, Dublin City University, Dublin 9 (Ireland); Karkari, S. K. [Institute for Plasma Research Center, Bhat Gandhinagar, Gujarat 382428 (India)

2012-07-23T23:59:59.000Z

492

Molecular Simulation of Henry's Constant at Vapor-Liquid and Liquid-Liquid Phase Richard J. Sadus  

E-Print Network [OSTI]

coexistence. 1. Introduction Henry's constant is a well-known measure of a solute's solubility in a particularMolecular Simulation of Henry's Constant at Vapor-Liquid and Liquid-Liquid Phase Boundaries Richard to determine Henry's constant from the residual chemical potential at infinite dilution at the vapor-liquid

493

Design and analysis of mismatch probes for long oligonucleotide microarrays  

SciTech Connect (OSTI)

Nonspecific hybridization is currently a major concern with microarray technology. One of most effective approaches to estimating nonspecific hybridizations in oligonucleotide microarrays is the utilization of mismatch probes; however, this approach has not been used for longer oligonucleotide probes. Here, an oligonucleotide microarray was constructed to evaluate and optimize parameters for 50-mer mismatch probe design. A perfect match (PM) and 28 mismatch (MM) probes were designed for each of ten target genes selected from three microorganisms. The microarrays were hybridized with synthesized complementary oligonucleotide targets at different temperatures (e.g., 42, 45 and 50 C). In general, the probes with evenly distributed mismatches were more distinguishable than those with randomly distributed mismatches. MM probes with 3, 4 and 5 mismatched nucleotides were differentiated for 50-mer oligonucleotide probes hybridized at 50, 45 and 42 C, respectively. Based on the experimental data generated from this study, a modified positional dependent nearest neighbor (MPDNN) model was constructed to adjust the thermodynamic parameters of matched and mismatched dimer nucleotides in the microarray environment. The MM probes with four flexible positional mismatches were designed using the newly established MPDNN model and the experimental results demonstrated that the redesigned MM probes could yield more consistent hybridizations. Conclusions: This study provides guidance on the design of MM probes for long oligonucleotides (e.g., 50 mers). The novel MPDNN model has improved the consistency for long MM probes, and this modeling method can potentially be used for the prediction of oligonucleotide microarray hybridizations.

Deng, Ye; He, Zhili; Van Nostrand, Joy D.; Zhou, Jizhong

2008-08-15T23:59:59.000Z

494

Cone penetrometer fiber optic raman spectroscopy probe assembly  

DOE Patents [OSTI]

A chemically and mechanically robust optical Raman spectroscopy probe assembly that can be incorporated in a cone penetrometer (CPT) for subsurface deployment. This assembly consists of an optical Raman probe and a penetrometer compatible optical probe housing. The probe is intended for in-situ chemical analysis of chemical constituents in the surrounding environment. The probe is optically linked via fiber optics to the light source and the detection system at the surface. A built-in broadband light source provides a strobe method for direct measurement of sample optical density. A mechanically stable sapphire window is sealed directly into the side-wall of the housing using a metallic, chemically resistant, hermetic seal design. This window permits transmission of the interrogation light beam and the resultant signal. The spectroscopy probe assembly is capable of accepting Raman, Laser induced Fluorescence, reflectance, and other optical probes with collimated output for CPT deployment.

Kyle, Kevin R. (Brentwood, CA); Brown, Steven B. (Livermore, CA)

2000-01-01T23:59:59.000Z

495

Sampling probe for microarray read out using electrospray mass spectrometry  

DOE Patents [OSTI]

An automated electrospray based sampling system and method for analysis obtains samples from surface array spots having analytes. The system includes at least one probe, the probe including an inlet for flowing at least one eluting solvent to respective ones of a plurality of spots and an outlet for directing the analyte away from the spots. An automatic positioning system is provided for translating the probe relative to the spots to permit sampling of any spot. An electrospray ion source having an input fluidicly connected to the probe receives the analyte and generates ions from the analyte. The ion source provides the generated ions to a structure for analysis to identify the analyte, preferably being a mass spectrometer. The probe can be a surface contact probe, where the probe forms an enclosing seal along the periphery of the array spot surface.

Van Berkel, Gary J.

2004-10-12T23:59:59.000Z

496

Cooling and solidification of heavy hydrocarbon liquid streams  

DOE Patents [OSTI]

A process and apparatus for cooling and solidifying a stream of heavy hydrocarbon material normally boiling above about 850.degree. F., such as vacuum bottoms material from a coal liquefaction process. The hydrocarbon stream is dropped into a liquid bath, preferably water, which contains a screw conveyor device and the stream is rapidly cooled, solidified and broken therein to form discrete elongated particles. The solid extrudates or prills are then dried separately to remove substantially all surface moisture, and passed to further usage.

Antieri, Salvatore J. (Trenton, NJ); Comolli, Alfred G. (Yardley, PA)

1983-01-01T23:59:59.000Z

497

Surface formation in immiscible liquids with orifice mixers  

E-Print Network [OSTI]

~ . ~ Fraction, ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ 77 21. Variation of Specific Area with Votume Orifice Diameter 0. 6875 inches . . . ~ Fraction, ~ ~ ~ ~ P ~ ~ ~ ~ 1 ~ 78 22. Rotameter Calibration, Kerosene ~ ~ 4 ~ ~ 0 ~ ~ ~ a ~ ~ ~ a 79 23, Rotameter Calibration... liquids, water in kerosene, with orifices was made as a continuation of previous work performed by P. G. Nczdoch and H. WcMair, and K. V. Andrews and M. E. Welch. Data were taken by the photoelectric measuresmnt of mbctures inside a window section...

Wesselhoft, Robert Dale

1955-01-01T23:59:59.000Z

498

Thermal signature reduction through liquid nitrogen and water injection  

E-Print Network [OSTI]

values at thermocouple locations. ................................. 45 IV Temperature values (K)at TC locations for LN2 injection on both gridsandtwoexperimentaldatasets................... 45 x LIST OF FIGURES FIGURE Page 1 Basic elements of a spin... partialdiffr(rhovr)+ rhovr r = Sm (3.4) partialdiffrho partialdifft(rho vectorV + nabla?(rhovectorV vectorV )=-nablaP + nabla???tau + rhovectorg + vectorF (3.5) partialdiffrho partialdifft(rhoE)+nabla?( vectorV (rhoE + P)) = -nabla(kef f nablaT + ??tauef f...

Guarnieri, Jason Antonio

2005-02-17T23:59:59.000Z

499