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1

Isotope and Temperature Effects in Liquid Water Probed by Soft...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many...

2

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure plays a crucial role in understanding the properties of the liquid state. Consequently, information essential for insight into chemical and biological processes in aqueous environments is lacking. To address this need, researchers from Germany and the U.S. have used soft x-ray spectroscopy at the ALS to gain detailed insight into the electronic structure of liquid water. Their spectra show a strong isotope and a weak temperature effect, and, for the first time, a splitting of the primary emission line in x-ray emission spectra. By making use of the internal "femtosecond clock" of the core-hole lifetime, a detailed picture of the electronic structure can be painted that involves fast dissociation processes of the probed water molecules.

3

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure plays a crucial role in understanding the properties of the liquid state. Consequently, information essential for insight into chemical and biological processes in aqueous environments is lacking. To address this need, researchers from Germany and the U.S. have used soft x-ray spectroscopy at the ALS to gain detailed insight into the electronic structure of liquid water. Their spectra show a strong isotope and a weak temperature effect, and, for the first time, a splitting of the primary emission line in x-ray emission spectra. By making use of the internal "femtosecond clock" of the core-hole lifetime, a detailed picture of the electronic structure can be painted that involves fast dissociation processes of the probed water molecules.

4

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure plays a crucial role in understanding the properties of the liquid state. Consequently, information essential for insight into chemical and biological processes in aqueous environments is lacking. To address this need, researchers from Germany and the U.S. have used soft x-ray spectroscopy at the ALS to gain detailed insight into the electronic structure of liquid water. Their spectra show a strong isotope and a weak temperature effect, and, for the first time, a splitting of the primary emission line in x-ray emission spectra. By making use of the internal "femtosecond clock" of the core-hole lifetime, a detailed picture of the electronic structure can be painted that involves fast dissociation processes of the probed water molecules.

5

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure plays a crucial role in understanding the properties of the liquid state. Consequently, information essential for insight into chemical and biological processes in aqueous environments is lacking. To address this need, researchers from Germany and the U.S. have used soft x-ray spectroscopy at the ALS to gain detailed insight into the electronic structure of liquid water. Their spectra show a strong isotope and a weak temperature effect, and, for the first time, a splitting of the primary emission line in x-ray emission spectra. By making use of the internal "femtosecond clock" of the core-hole lifetime, a detailed picture of the electronic structure can be painted that involves fast dissociation processes of the probed water molecules.

6

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure plays a crucial role in understanding the properties of the liquid state. Consequently, information essential for insight into chemical and biological processes in aqueous environments is lacking. To address this need, researchers from Germany and the U.S. have used soft x-ray spectroscopy at the ALS to gain detailed insight into the electronic structure of liquid water. Their spectra show a strong isotope and a weak temperature effect, and, for the first time, a splitting of the primary emission line in x-ray emission spectra. By making use of the internal "femtosecond clock" of the core-hole lifetime, a detailed picture of the electronic structure can be painted that involves fast dissociation processes of the probed water molecules.

7

Probing Properties of Glassy Water and Other Liquids with Site Selective Spectroscopies  

SciTech Connect (OSTI)

The standard non-photochemical hole burning (NPHB) mechanism, which involves phonon-assisted tunneling in the electronically excited state, was originally proposed to explain the light-induced frequency change of chemically stable molecules in glassy solids at liquid helium temperatures by this research group more than two decades ago. The NPHB mechanism was then further elucidated and the concept of intrinsic to glass configurational relaxation processes as pre-mediating step to the hole burning process was introduced. The latter provided the theoretical basis for NPHB to evolve into a powerful tool probing the dynamics and nature of amorphous media, which aside from ''simple'' inorganic glasses may include also ''complex'' biological systems such as living cells and cancerous/normal tissues. Presented in this dissertation are the experimental and theoretical results of hole burning properties of aluminum phthalocyanine tetrasulphonate (APT) in several different matrices: (1) hyperquenched glassy water (HGW); (2) cubic ice (I{sub c}); and (3) water confined into poly(2-hydroxyethylmethacrylate) (poly-HEMA). In addition, results of photochemical hole burning (PHB) studies obtained for phthalocyanine tetrasulphonate (PcT) in HGW and free base phthalocyanine (Pc) in ortho-dichlorobenzene (DCB) glass are reported. The goal of this dissertation was to provide further evidence supporting the NPHB mechanism and to provide more insight that leads to a better understanding of the kinetic events (dynamics) in glasses, and various dynamical processes of different fluorescent chromorphores in various amorphous solids and the liquid that exist above the glass transition temperature (T{sub g}). The following issues are addressed in detail: (1) time evolution of hole being burned under different conditions and in different hole burning systems; (2) temperature dependent hole profile; and (3) the structure/dynamics of water in confined space, which has been studied, in part because of the importance of non-freezable water in biological systems.

Nhan Chuong Dang

2005-08-12T23:59:59.000Z

8

Probing Liquid Water Saturation in Diffusion Media of Polymer Electrolyte Fuel Cells  

E-Print Network [OSTI]

of information strongly needed to characterize the level of cathode DM flooding or anode dry-out. In this paper liquid water in the anode DM for the thin membrane case. In addition, the two-phase simulation results be realized. One of these is related to flooding phenomena. Due to the presence of liquid water inside a PEFC

9

Probing the Mobility of Supercooled Liquid 3-Methylpentane at...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Mobility of Supercooled Liquid 3-Methylpentane at Temperatures Near the Glass Transition Using Rare Gas Permeation. Probing the Mobility of Supercooled Liquid 3-Methylpentane at...

10

High-Throughput Mode Liquid Microjunction Surface Sampling Probe  

SciTech Connect (OSTI)

A simple and automated spot sampling operation mode for a liquid microjunction surface sampling probe/electrospray ionization mass spectrometry (LMJ-SSP/ESI-MS) system is reported. Prior manual and automated spot sampling methods with this probe relied on a careful, relatively slow alignment of the probe and surface distance (<20 m spacing) to form the probe-to-surface liquid microjunction critical to successful surface sampling. Moreover, sampling multiple spots required retraction of the surface from the probe and a repeat of this careful probe-to-surface distance alignment at the next sampling position. With the method described here, the probe was not positioned as close to the surface, the exact probeto-surface positioning was found to be less critical (spanning distances from about 100-300 m), and this distance was not altered during the sampling of an entire array of sample spots. With the probe positioned within the appropriate distance from the surface, the liquid microjunction was formed by letting the liquid from the sampling end of the probe extend out from the probe to the surface. This was accomplished by reducing the selfaspiration liquid flow rate of the probe to a value less than the volume flow rate pumped into the probe. When the self-aspiration rate of the probe was subsequently increased, analytes on the surface that dissolved at the liquid microjunction were aspirated back into the probe with the liquid that created the liquid microjunction and electrosprayed. Presented here are the basics of this new sampling mode, as well as data that illustrate the potential analytical capabilities of the device to conduct highthroughput quantitative analysis.

Van Berkel, Gary J [ORNL; Kertesz, Vilmos [ORNL; King, Richard C. [PharmaCadence

2009-01-01T23:59:59.000Z

11

Probing Liquid Surfaces under Vacuum Using SEM and TOF-SIMS....  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

beneath it. This window supports the liquid against the vacuum by the liquid’s surface tension, while limiting the high-density vapor region traversed by the probe beams...

12

Ground-Based and Airborne (PMS 2-D Probe Canister-Mounted) 183 GHz Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ground-Based and Airborne (PMS 2-D Probe Canister-Mounted) 183 GHz Water Ground-Based and Airborne (PMS 2-D Probe Canister-Mounted) 183 GHz Water Vapor Radiometer Pazmany, Andrew ProSensing Inc. Category: Instruments ProSensing Inc. has developed a G-band (183 GHz, 1.5 mm wavelength) water vapor radiometer (GVR) for the measurement of low concentrations of atmospheric water vapor and liquid water. The instrument's precipitable water vapor measurement precision is approximately 0.01 mm in dry (<2 mm vapor column) conditions. The ground-based version of the instrument was first deployed at ProSensing's facility in Amherst, MA in February 2005, then at the North Slope of Alaska DOE ARM site in Barrow AK in April 2005, where it has been continuously operating since. An airborne version, designed to operate from a standard PMS 2-D probe canister, is now being

13

Core-softened Fluids, Water-like Anomalies and the Liquid-Liquid Critical Points  

E-Print Network [OSTI]

. INTRODUCTION Water is characterized by well-known thermodynamic and kinetic liquid-state anomalies; for examplePREPRINT Core-softened Fluids, Water-like Anomalies and the Liquid-Liquid Critical Points Evy simulations are used to examine the relationship between water-like anoma- lies and the liquid-liquid critical

Barbosa, Marcia C. B.

14

Phase effects for electrons in liquid water and water vapor  

SciTech Connect (OSTI)

The objective of these studies is to compare transport, energy loss, and other phenomena for electrons in water in the liquid and vapor phases. Understanding the differences and similarities is an interesting physics problem in its own right. It is also important for applying the relatively large body of experimental data available for the vapor to the liquid, which is of greater relevance in radiobiology. This paper presents a summary of results from a series of collaborative studies carried out by the authors at Oak Ridge National Laboratory (ORNL) and the Gesellschaft fuer Strahlen- und Umweltforschung (GSF). 14 figs.

Turner, J.E.; Paretzke, H.G.; Wright, H.A.; Hamm, R.N.; Ritchie, R.H.

1988-01-01T23:59:59.000Z

15

Dual harmonic Kelvin probe force microscopy at the graphene–liquid interface  

SciTech Connect (OSTI)

Kelvin probe force microscopy (KPFM) is a powerful technique for the determination of the contact potential difference (CPD) between an atomic force microscope tip and a sample under ambient and vacuum conditions. However, for many energy storage and conversion systems, including graphene-based electrochemical capacitors, understanding electrochemical phenomena at the solid–liquid interface is paramount. Despite the vast potential to provide fundamental insight for energy storage materials at the nanoscale, KPFM has found limited applicability in liquid environments to date. Here, using dual harmonic (DH)-KPFM, we demonstrate CPD imaging of graphene in liquid. We find good agreement with measurements performed in air, highlighting the potential of DH-KPFM to probe electrochemistry at the graphene–liquid interface.

Collins, Liam; Rodriguez, Brian J., E-mail: brian.rodriguez@ucd.ie [School of Physics, University College Dublin, Belfield, Dublin 4 (Ireland); Conway Institute of Biomolecular and Biomedical Research, University College Dublin, Belfield, Dublin 4 (Ireland); Kilpatrick, Jason I.; Weber, Stefan A. L. [Conway Institute of Biomolecular and Biomedical Research, University College Dublin, Belfield, Dublin 4 (Ireland); Vlassiouk, Ivan V. [Energy and Transportation Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Tselev, Alexander; Jesse, Stephen; Kalinin, Sergei V. [Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

2014-03-31T23:59:59.000Z

16

3-D Nano-Fiber Manufacturing by Controlled Pulling of Liquid Polymers using Nano-Probes  

E-Print Network [OSTI]

3-D Nano-Fiber Manufacturing by Controlled Pulling of Liquid Polymers using Nano-Probes Amrinder S) nano-scale manufacturing tools in this paper. Commercially available Atomic Force Microscope (AFM) systems are mainly limited to 1-D or 2-D manipulation tasks, and advanced 3-D nano

Sitti, Metin

17

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived a new energy criterion for H-bonds based on experimental data. With this new criterion based on analysis of the temperature dependence of the x-ray absorption spectra of normal and supercooled liquid water, they concluded that the traditional structural model of water is valid.

18

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived a new energy criterion for H-bonds based on experimental data. With this new criterion based on analysis of the temperature dependence of the x-ray absorption spectra of normal and supercooled liquid water, they concluded that the traditional structural model of water is valid.

19

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived a new energy criterion for H-bonds based on experimental data. With this new criterion based on analysis of the temperature dependence of the x-ray absorption spectra of normal and supercooled liquid water, they concluded that the traditional structural model of water is valid.

20

Potential structure of discharge plasma inside liquid directly measured by an electrostatic probe  

SciTech Connect (OSTI)

Potential structures of a discharge plasma inside a liquid are investigated by an electrostatic probe measurement. The time evolution of radial profiles of the floating potential for the plasma inside liquid reveals that the dominant negative charges in the plasma are the negative ion species such as OH{sup -} and O{sub 2}{sup -} rather than electrons. In addition, a positive potential gradient exists at the plasma-liquid interface due to the presence of an electrical double layer which is caused by the separation of low-mass positive ion of H{sup +} and high-mass negative ions of OH{sup -} and O{sub 2}{sup -} near the plasma-liquid interface.

Chen, Qiang; Hatakeyama, Rikizo [Department of Electronic Engineering, Tohoku University, Sendai 980-8579 (Japan)] [Department of Electronic Engineering, Tohoku University, Sendai 980-8579 (Japan); Kaneko, Toshiro [Department of Electronic Engineering, Tohoku University, Sendai 980-8579 (Japan) [Department of Electronic Engineering, Tohoku University, Sendai 980-8579 (Japan); CREST/JST, Tokyo 102-0075 (Japan); Matsuda, Naoki [Measurement Solution Research Center, AIST, Tosu 841-0052 (Japan)] [Measurement Solution Research Center, AIST, Tosu 841-0052 (Japan)

2013-06-17T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy  

SciTech Connect (OSTI)

We present the first femtosecond soft x-ray spectroscopy in liquids, enabling the observation of changes in hydrogen bond structures in water via core-hole excitation. The oxygen K-edge of vibrationally excited water is probed with femtosecond soft x-ray pulses, exploiting the relation between different water structures and distinct x-ray spectral features. After excitation of the intramolecular OH stretching vibration, characteristic x-ray absorption changes monitor the conversion of strongly hydrogen-bonded water structures to more disordered structures with weaker hydrogen-bonding described by a single subpicosecond time constant. The latter describes the thermalization time of vibrational excitations and defines the characteristic maximum rate with which nonequilibrium populations of more strongly hydrogen-bonded water structures convert to less-bonded ones. On short time scales, the relaxation of vibrational excitations leads to a transient high-pressure state and a transient absorption spectrum different from that of statically heated water.

Wen, Haidan; Huse, Nils; Schoenlein, Robert W.; Lindenberg, Aaron M.

2010-05-01T23:59:59.000Z

22

Water at the Surfaces of Aligned Phospholipid Multibilayer Model Membranes Probed with Ultrafast Vibrational  

E-Print Network [OSTI]

Water at the Surfaces of Aligned Phospholipid Multibilayer Model Membranes Probed with Ultrafast@stanford.edu Abstract: The dynamics of water at the surface of artificial membranes composed of aligned multibilayers pump-probe spectroscopy. The experiments are performed at various hydration levels, x ) 2 - 16 water

Fayer, Michael D.

23

A flexible, highly stable electrochemical scanning probe microscope for nanoscale studies at the solid-liquid interface  

E-Print Network [OSTI]

low-noise measurements in ambient, in situ, and electrochemical environments. II. DESIGNA flexible, highly stable electrochemical scanning probe microscope for nanoscale studies at the solid-liquid interface, specifically in electrolyte environments. Quantification of system noise limits

Gimzewski, James

24

Water an Unusual Liquid; LCLS Provides New Insights | Stanford Synchrotron  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water an Unusual Liquid; LCLS Provides New Insights Water an Unusual Liquid; LCLS Provides New Insights Wednesday, November 13, 2013 - 3:00pm SLAC, Redtail Hawk Conference Room 108A Anders Nilsson, SUNCAT The anomalous physical properties of water are responsible for sustaining much of life on earth; for example, water displays a higher heat capacity than common liquids and expands upon freezing. Some of these anomalous physical properties become dramatically enhanced upon supercooling below the freezing point. In particular, extrapolations of the thermal expansion coefficient, isothermal compressibility, heat capacity and correlation length can all be fitted with a power law divergence with the same apparent singularity temperature of about 228 K. Experiments on pure bulk water below about ~240 K have so far been difficult: water crystallization occurs

25

Extraction of ethanol from water with liquid propylene  

SciTech Connect (OSTI)

To separate EtOH from water by distillation requires 40 to 50 times the minimum Gibbs free energy of mixing. Also, EtOH forms an azeotrope with water, limiting the EtOH purity to 92%. These considerations have prompted investigations of solvent extraction. This paper describes the use of liquid propylene as solvent. The process application is also described. (DLC)

Victor, J.G.

1983-01-01T23:59:59.000Z

26

ARM - Evaluation Product - MWR Retrievals of Cloud Liquid Water and Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ProductsMWR Retrievals of Cloud Liquid Water and ProductsMWR Retrievals of Cloud Liquid Water and Water Vapor Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Evaluation Product : MWR Retrievals of Cloud Liquid Water and Water Vapor 2005.02.01 - 2011.04.25 Site(s) FKB GRW HFE NIM PYE SBS General Description A new algorithm is being developed for the ARM Program to derive liquid water path (LWP) and precipitable water vapor (PWV) from the 2-channel (23.8 and 31.4 GHz) microwave radiometers (MWRs) deployed at ARM climate research facilities. This algorithm utilizes the "monoRTM" radiative transfer model (http://rtweb.aer.com), a combination of both an advanced statistical and physical-iterative retrieval, and brightness temperature offsets applied before the retrieval is performed. This allows perhaps the

27

Low-Dimensional Water on Ru(0001)Model System for X-ray Absorption Spectroscopy Studies of Liquid Water  

SciTech Connect (OSTI)

We present an x-ray absorption spectroscopy results for fully broken to a complete H-bond network of water molecules on Ru(0001) by varying the morphology from isolated water molecules via two-dimensional clusters to a fully covered monolayer as probed by scanning tunneling microscopy. The sensitivity of x-ray absorption to the symmetry of H-bonding is further elucidated for the amino (-NH{sub 2}) group in glycine adsorbed on Cu(110) where the E-vector is parallel either to the NH donating an H-bond or to the non-H-bonded NH. The results give further evidence for the interpretation of the various spectral features of liquid water and for the general applicability of x-ray absorption spectroscopy to analyze H-bonded systems.

Nordlund, D

2012-02-14T23:59:59.000Z

28

Low-Dimensional Water on Ru(0001); Model System for X-ray Absorption Spectroscopy Studies of Liquid Water  

SciTech Connect (OSTI)

We present an x-ray absorption spectroscopy results for fully broken to a complete H-bond network of water molecules on Ru(0001) by varying the morphology from isolated water molecules via two-dimensional clusters to a fully covered monolayer as probed by scanning tunneling microscopy. The sensitivity of x-ray absorption to the symmetry of H-bonding is further elucidated for the amino (-NH{sub 2}) group in glycine adsorbed on Cu(110) where the E-vector is parallel either to the NH donating an H-bond or to the non-H-bonded NH. The results give further evidence for the interpretation of the various spectral features of liquid water and for the general applicability of x-ray absorption spectroscopy to analyze H-bonded systems.

Nordlund, D.; Ogasawara, H.; Andersson, K.J.; Tatarkhanov, M.; Salmeron, M.; Pettersson, L. G. M.; Nilsson, A.

2009-05-11T23:59:59.000Z

29

Structure and Depletion at Fluorocarbon and Hydrocarbon/Water Liquid/Liquid Interfaces  

Science Journals Connector (OSTI)

The results of x-ray reflectivity studies of two oil/water (liquid/liquid) interfaces are inconsistent with recent predictions of the presence of a vaporlike depletion region at hydrophobic/aqueous interfaces. One of the oils, perfluorohexane, is a fluorocarbon whose superhydrophobic interface with water provides a stringent test for the presence of a depletion layer. The other oil, heptane, is a hydrocarbon and, therefore, is more relevant to the study of biomolecular hydrophobicity. These results are consistent with the subangstrom proximity of water to soft hydrophobic materials.

Kaoru Kashimoto; Jaesung Yoon; Binyang Hou; Chiu-hao Chen; Binhua Lin; Makoto Aratono; Takanori Takiue; Mark L. Schlossman

2008-08-14T23:59:59.000Z

30

Air-Assisted Liquid Liquid–Microextraction for the Analysis of Fungicides from Environmental Water and Juice Samples  

Science Journals Connector (OSTI)

......2014 research-article Article Air-Assisted Liquid Liquid-Microextraction...work, a rapid method based on air-assisted liquid liquid microextraction...the continuous injection of air by a 20-mL glass syringe...resulting in the possible pollution of water, fruits and vegetables......

Shiju Wu; Tingting Jin; Jing Cheng; Hongbin Zhou; Min Cheng

2014-10-01T23:59:59.000Z

31

Equation of State for Supercooled Water Near the Liquid-Liquid Critical Point  

E-Print Network [OSTI]

We have developed a scaled parametric equation of state to describe and predict thermodynamic properties of supercooled water. The equation of state, built on the growing evidence that the critical point of supercooled liquid-liquid water separation exists, is universal in terms of theoretical scaling fields and is shown to belong to the Ising-model class of universality. The theoretical scaling fields are postulated to be analytical combinations of the physical fields, pressure and temperature. The equation of state enables us to accurately locate the "Widom line" (the locus of stability minima) and determine that the critical pressure is considerably lower than predicted by computer simulations.

M. A. Anisimov; D. A. Fuentevilla

2006-09-19T23:59:59.000Z

32

An Evaluation of MWR Retrievals of Liquid Water Path  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Evaluation of MWR Retrievals Evaluation of MWR Retrievals of Liquid Water Path and Precipitable Water Vapor R. T. Marchand and T. P. Ackerman Pacific Northwest National Laboratory Richland, Washington Introduction This paper offers some observations on the quality of Microwave Radiometer (MWR) retrievals of precipitable water vapor (PWV) and liquid water path (LWP). The paper shows case study comparisons between the standard "statistical" approach and those obtained using an iterative solution of the microwave radiative transfer equations. These examples show how improvements in the retrieval of LWP can be obtained by using an iterative approach, but that possible improvements are limited by the accuracy of the forward model absorption coefficients and errors in the brightness temperature measurements. Each of these effects limits the

33

Empirical Relationships for Estimating Liquid Water Fraction of Melting Snowflakes  

Science Journals Connector (OSTI)

The liquid water fraction of individual snowflakes f is an important parameter when calculating the radar reflectivity of a melting layer. A ground-based observation of f at Nagaoka, Japan, was conducted by using dye-treated filter papers that ...

Ryohei Misumi; Hiroki Motoyoshi; Satoru Yamaguchi; Sento Nakai; Masaaki Ishizaka; Yasushi Fujiyoshi

2014-10-01T23:59:59.000Z

34

Water dynamics: dependence on local structure probed with vibrational echo correlation spectroscopy  

E-Print Network [OSTI]

Water dynamics: dependence on local structure probed with vibrational echo correlation spectroscopy­D stretching band of HOD in H2O and molecular dynamics simulations are employed to investigate water dynamics. The wavelength dependence of the measured dynamics demonstrates that different hydrogen bonded water species

Fayer, Michael D.

35

Probing Spin Liquids with a New Pulsed-Magnet System | Advanced Photon  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

a Magnetic Moment in a Split Picosecond a Magnetic Moment in a Split Picosecond Unpeeling Atoms and Molecules from the Inside Out Butterfly Wing Yields Clues to Light-Altering Structures Squeezing Information from Materials under Extreme Pressure Quick-Change Molecules Caught in the Act Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Probing Spin Liquids with a New Pulsed-Magnet System AUGUST 26, 2010 Bookmark and Share The (008) intensity color map on a θ vs. 2θ mesh. With increasing magnetic field the peak splits at a critical field of H ~29 T, which is a hallmark of a structural phase transition with a reduction from cubic to tetragonal or orthorhombic symmetry. Above the critical field,

36

Probing the hydrogen-bond network of water via time-resolved soft x-ray spectroscopy  

SciTech Connect (OSTI)

We report time-resolved studies of hydrogen bonding in liquid H2O, in response to direct excitation of the O-H stretch mode at 3 mu m, probed via soft x-ray absorption spectroscopy at the oxygen K-edge. This approach employs a newly developed nanofluidic cell for transient soft x-ray spectroscopy in liquid phase. Distinct changes in the near-edge spectral region (XANES) are observed, and are indicative of a transient temperature rise of 10K following transient laser excitation and rapid thermalization of vibrational energy. The rapid heating occurs at constant volume and the associated increase in internal pressure, estimated to be 8MPa, is manifest by distinct spectral changes that differ from those induced by temperature alone. We conclude that the near-edge spectral shape of the oxygen K-edge is a sensitive probe of internal pressure, opening new possibilities for testing the validity of water models and providing new insight into the nature of hydrogen bonding in water.

Huse, Nils; Wen, Haidan; Nordlund, Dennis; Szilagyi, Erzsi; Daranciang, Dan; Miller, Timothy A.; Nilsson, Anders; Schoenlein, Robert W.; Lindenberg, Aaron M.

2009-04-24T23:59:59.000Z

37

Elastic parameters of a water-based magnetic liquid  

SciTech Connect (OSTI)

The authors repeat studies on the acoustic parameters of water-based magnetic liquids to find a better method of measuring the speed and to cover a wider concentration range. The pulse method is used, as it works well in measuring the speed of sound in ordinary liquids. A figure shows the block diagram. Figures show the dependence of magnetization on field strength and temperature dependence of ultrasound. The speeds measured for the specimens show that the parameter obtained remains constant within the errors of measurement in longitudinal and transverse fields.

Berkovskii, B.M.

1986-07-01T23:59:59.000Z

38

Pore-scale simulation of liquid CO2 displacement of water using...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model. Pore-scale simulation of liquid CO2 displacement of water using a two-phase...

39

ARM - PI Product - MWR Retrievals of Cloud Liquid Water and Water Vapor  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

govDataPI Data ProductsMWR Retrievals of Cloud Liquid Water and Water govDataPI Data ProductsMWR Retrievals of Cloud Liquid Water and Water Vapor Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : MWR Retrievals of Cloud Liquid Water and Water Vapor 2005.02.01 - 2011.04.25 Site(s) FKB GRW HFE NIM PYE SBS General Description A new algorithm is being developed for the ARM Program to derive liquid water path (LWP) and precipitable water vapor (PWV) from the 2-channel (23.8 and 31.4 GHz) microwave radiometers (MWRs) deployed at ARM climate research facilities. This algorithm utilizes the "monoRTM" radiative transfer model (http://rtweb.aer.com), a combination of both an advanced statistical and physical-iterative retrieval, and brightness temperature offsets applied before the retrieval is performed. This allows perhaps the

40

A lander mission to probe subglacial water on Saturn's moon enceladus for life  

Science Journals Connector (OSTI)

Abstract The plumes discovered by the Cassini mission emanating from the south pole of Saturn's moon Enceladus and the unique chemistry found in them have fueled speculations that Enceladus may harbor life. The presumed aquiferous fractures from which the plumes emanate would make a prime target in the search for extraterrestrial life and would be more easily accessible than the moon's subglacial ocean. A lander mission that is equipped with a subsurface ice melting probe will be most suitable to assess the existence of life on Enceladus. A lander would have to land at a safe distance away from a plume source and melt its way to the inner wall of the fracture to analyze the plume subsurface liquids before potential biosignatures are degraded or destroyed by exposure to the vacuum of space. A possible approach for the in situ detection of biosignatures in such samples, can be based on the hypothesis of universal evolutionary convergence, meaning that the independent and repeated emergence of life and certain adaptive traits is wide-spread throughout the cosmos. We thus present a hypothetical evolutionary trajectory leading towards the emergence of methanogenic chemoautotrophic microorganisms as the baseline for putative biological complexity on Enceladus. To detect their presence, several instruments are proposed that may be taken aboard a future subglacial melting probe. The “Enceladus Explorer” (EnEx) project funded by the German Space Administration (DLR), aims to develop a terrestrial navigation system for a subglacial research probe and eventually test it under realistic conditions in Antarctica using the EnEx-IceMole, a novel maneuverable subsurface ice melting probe for clean sampling and in situ analysis of ice and subglacial liquids. As part of the EnEx project, an initial concept study is foreseen for a lander mission to Enceladus to deploy the IceMole near one of the active water plumes on the moon's South-Polar Terrain, where it will search for signatures of life. The general mission concept is to place the Lander at a safe distance from an active plume. The IceMole would then be deployed to melt its way through the ice crust to an aquiferous fracture at a depth of 100 m or more for an in situ examination for the presence of microorganisms. The driving requirement for the mission is the high energy demand by the IceMole to melt through the cold Enceladan ices. This requirement is met by a nuclear reactor providing 5 kW of electrical power. The nuclear reactor and the IceMole are placed on a pallet lander platform. An Orbiter element is also foreseen, with the main function of acting as a communications relay between the Lander and Earth. After launch, the Lander and Orbiter will perform the interplanetary transfer to Saturn together, using the on-board nuclear reactor to power electric thrusters. After Saturn orbit insertion, the combined spacecraft will continue using nuclear electric propulsion to reach the orbit of Enceladus. After orbit insertion at Enceladus, the Orbiter will perform a detailed reconnaissance of the South-Polar Terrain. At the end of the reconnaissance phase, the Lander will separate from the Orbiter and an autonomously guided landing sequence will place it near one of the active vapor plumes. Once landed, the IceMole will be deployed and start melting through the ice, while navigating around hazards and towards a target subglacial aquiferous fracture. An initial estimation of the mission's cost is given, as well as recommendations on the further development of enabling technologies. The planetary protection challenges posed by such a mission are also addressed.

Konstantinos Konstantinidis; Claudio Flores Martinez; Bernd Dachwald; Andreas Ohndorf; Paul Dykta; Pascal Bowitz; Martin Rudolph; Ilya Digel; Julia Kowalski; Konstantin Voigt; Roger Förstner

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Probing the Interaction of Amorphous Solid Water on a Hydrophobic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Surface: Dewetting and Crystallization Kinetics of ASW on Abstract: Desorption of carbon tetrachloride from beneath an amorphous solid water (ASW) overlayer is explored...

42

Gas-Liquid Coexistence in the Primitive Model for Water  

E-Print Network [OSTI]

We evaluate the location of the gas-liquid coexistence line and of the associated critical point for the primitive model for water (PMW), introduced by Kolafa and Nezbeda [J. Kolafa and I. Nezbeda, Mol. Phys. 61, 161 (1987)]. Besides being a simple model for a molecular network forming liquid, the PMW is representative of patchy proteins and novel colloidal particles interacting with localized directional short-range attractions. We show that the gas-liquid phase separation is metastable, i.e. it takes place in the region of the phase diagram where the crystal phase is thermodynamically favored, as in the case of articles interacting via short-range attractive spherical potentials. Differently from spherical potentials, we do not observe crystallization close to the critical point. The region of gas-liquid instability of this patchy model is significantly reduced as compared to equivalent models of spherically interacting particles, confirming the possibility of observing kinetic arrest in an homogeneous sample driven by bonding as opposed to packing.

F. Romano; P. Tartaglia; F. Sciortino

2007-05-08T23:59:59.000Z

43

Spin states of para-water and ortho-water molecule in gas and liquid phases  

E-Print Network [OSTI]

Spin degrees of freedom of water molecule in gas and liquid state were investigated in order to provide a reasonable answer about the unsolved problem of a long-term behavior of water spin isomers. The approach used involves an assumption that molecules change their spin state from a pure state to a mixed one when they interact with some sorts of adsorbent surface. Some models and conceptions of the quantum information processing were used.

V. K. Konyukhov

2009-09-23T23:59:59.000Z

44

Distribution of binding energies of a water molecule in the water liquid-vapor interface  

SciTech Connect (OSTI)

Distributions of binding energies of a water molecule in the water liquid-vapor interface are obtained on the basis of molecular simulation with the SPC/E model of water. These binding energies together with the observed interfacial density profile are used to test a minimally conditioned Gaussian quasi-chemical statistical thermodynamic theory. Binding energy distributions for water molecules in that interfacial region clearly exhibit a composite structure. A minimally conditioned Gaussian quasi-chemical model that is accurate for the free energy of bulk liquid water breaks down for water molecules in the liquid-vapor interfacial region. This breakdown is associated with the fact that this minimally conditioned Gaussian model would be inaccurate for the statistical thermodynamics of a dilute gas. Aggressive conditioning greatly improves the performance of that Gaussian quasi-chemical model. The analogy between the Gaussian quasi-chemical model and dielectric models of hydration free energies suggests that naive dielectric models without the conditioning features of quasi-chemical theory will be unreliable for these interfacial problems. Multi-Gaussian models that address the composite nature of the binding energy distributions observed in the interfacial region might provide a mechanism for correcting dielectric models for practical applications.

Chempath, Shaji [Los Alamos National Laboratory; Pratt, Lawrence R [TULANE UNIV

2008-01-01T23:59:59.000Z

45

Microsoft PowerPoint - Ultrasonic Liquid Level ProbeSRNL-L9100-2009-00145TechBriefp1.ppt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Self-Targeting Ultrasonic Self-Targeting Ultrasonic Liquid Level Probe at a glance  U.S. patent 7,802,470  protected ultrasonic transducer  top, side, bottom mount without signal loss  penetrates metals or liquids  audible alarm and LED indicators  reduces or eliminates personnel exposure An ultrasonic transducer is mounted on the "dry" side of a dual chamber well with the beam directed at a "target" located at the far end of the flooded or "wet" side. Internal spring loading maintains a constant level of pressure on the transducer and eliminates air gaps at the interface. When the wet side becomes fully flooded during filling operations, an ultrasonic wave is transmitted through the liquid where it reaches and is reflected by the target returning the wave back to the

46

Colorimetric Au Nanoparticle Probe for Speciation Test of Arsenite and Arsenate Inspired by Selective Interaction between Phosphonium Ionic Liquid and Arsenite  

Science Journals Connector (OSTI)

Colorimetric Au Nanoparticle Probe for Speciation Test of Arsenite and Arsenate Inspired by Selective Interaction between Phosphonium Ionic Liquid and Arsenite ... With the colorimetric probe, we developed a protocol for naked eye speciation test of AsIII and AsV at levels below the World Health Organization (WHO) guideline of 10 µg L?1. ...

Zhiqiang Tan; Jingfu Liu; Yongguang Yin; Qiantao Shi; Chuanyong Jing; Guibin Jiang

2014-10-21T23:59:59.000Z

47

Direct Analysis of Reversed-Phase HPTLC Separated Tryptic Protein Digests using a Liquid Microjunction Surface Sampling Probe/ESI-MS System  

SciTech Connect (OSTI)

The sampling, ionization and detection of tryptic peptides separated in one-dimension on reversed phase HPTLC plates was performed using liquid microjunction surface sampling probe electrospray ionization mass spectrometry. Tryptic digests of five proteins (cytochrome c., myoglobin, beta-casein, lysozyme, and bovine serum albumin) were spotted on reversed phase HPTLC RP-8 F254s and HPTLC RP-18 F254s plates. The plates were then developed using 70/30 methanol/water with 0.1 M ammonium acetate. A dual purpose extraction/electrospray solution containing 70/30/0.1 water/methanol/formic acid was infused through the sampling probe during analysis of the developed lanes. Both full scan mass spectra and data dependent tandem mass spectra were acquired for each development lane to detect and verify the peptide distributions. Data dependent tandem mass spectra provided both protein identification and sequence coverage information. Highest sequence coverages were achieved for cytochrome c. and myoglobin (62.5% and 58.3%, respectively) on reversed phase RP-8 plates. While the tryptic peptides were separated enough for identification, the peptide bands did show some overlap with most peptides located in the lower half of the development lane. Proteins whose peptides were more separated gave higher sequence coverage. Larger proteins such as beta-casein and BSA which were spotted in lower relative amounts gave much lower sequence coverage than the smaller proteins.

Emory, Joshua F [ORNL; Walworth, Matthew J [ORNL; Van Berkel, Gary J [ORNL; Schulz, Michael [Merck Research Laboratories; Minarik, susanne [Merck Research Laboratories

2010-01-01T23:59:59.000Z

48

Combustion of Nano-Aluminum and Liquid Water G.A. Risha, S.F. Son  

E-Print Network [OSTI]

1 Combustion of Nano-Aluminum and Liquid Water G.A. Risha, S.F. Son , R.A. Yetter, V. Yang, and B: Supplemental materials submitted #12;2 Combustion of Nano-Aluminum and Liquid Water G.A. Risha, S.F. Son, R of nano-aluminum (nAl) and liquid water has been conducted. In particular, linear and mass-burning rates

Yang, Vigor

49

Detachment of Liquid-Water Droplets from Gas-Diffusion Layers  

E-Print Network [OSTI]

PEMFC cathode where liquid-water is produced in the catalystcathode side of the PEMFC, causing less oxygen to reach the active catalyst

Das, Prodip K.

2013-01-01T23:59:59.000Z

50

Detachment of Liquid-Water Droplets from Gas-Diffusion Layers  

SciTech Connect (OSTI)

A critical issue for optimal water management in proton-exchange-membrane fuel cells at lower temperatures is the removal of liquid water from the cell. This pathway is intimately linked with the phenomena of liquid-water droplet removal from surface of the gas-diffusion layer and into the flow channel. Thus, a good understanding of liquid-water transport and droplet growth and detachment from the gas-diffusion layer is critical. In this study, liquid-water droplet growth and detachment on the gas-diffusion layer surfaces are investigated experimentally to improve the understating of water transport through and removal from gas-diffusion layers. An experiment using a sliding-angle measurement is designed and used to quantify and directly measure the adhesion force for liquid-water droplets, and to understand the droplets? growth and detachment from the gas-diffusion layers.

Das, Prodip K.; Grippin, Adam; Weber, Adam Z.

2011-07-01T23:59:59.000Z

51

Fabrication, Dynamics, and Electrical Properties of Insulated SPM Probes for Electrical and Electromechanical Imaging in Liquids  

SciTech Connect (OSTI)

Insulated cantilever probes with a high aspect ratio conducting apex have been fabricated and their dynamic and electrical properties analyzed. The cantilevers were coated with silicon dioxide and a via was fabricated through the oxide at the tip apex and backfilled with tungsten to create an insulated probe with a conducting tip. The stiffness and Q-factor of the cantilevers increased after the modifications and their resonances shifted to higher frequencies. The coupling strength between the cantilever and the coating are determined. The applications to conductive and electromechanical imaging of ferroelectric domains are illustrated, and a probe apex repair process is demonstrated.

Rodriguez, Brian J [ORNL; Jesse, Stephen [ORNL; Seal, Katyayani [ORNL; Baddorf, Arthur P [ORNL; Kalinin, Sergei V [ORNL; Rack, Philip D [ORNL

2007-01-01T23:59:59.000Z

52

Infrared Pump–Probe Study of Nanoconfined Water Structure in Reverse Micelle  

Science Journals Connector (OSTI)

In the cases of the HN3 molecules in bulk water as well as in large RMs, the azido IR PP signal does not completely decay to zero due to the local heating contribution to the PP signal. ... This libration decay rate is consistent with the results of previous IR pump-probe measurement analyses for the appearance of heat following excitation resonant with the bend or stretch fundamentals. ...

Jooyong Lee; Micha? Maj; Kyungwon Kwak; Minhaeng Cho

2014-09-19T23:59:59.000Z

53

Liquid-liquid phase transition model incorporating evidence for ferroelectric state near the lambda-point anomaly in supercooled water  

E-Print Network [OSTI]

We propose a unified model combining the first-order liquid-liquid and the second-order ferroelectric phase transitions models and explaining various features of the $\\lambda$-point of liquid water within a single theoretical framework. It becomes clear within the proposed model that not only does the long-range dipole-dipole interaction of water molecules yield a large value of dielectric constant $\\epsilon$ at room temperatures, our analysis shows that the large dipole moment of the water molecules also leads to a ferroelectric phase transition at a temperature close to the lambda-point. Our more refined model suggests that the phase transition occurs only in the low density component of the liquid and is the origin of the singularity of the dielectric constant recently observed in experiments with supercooled liquid water at temperature T~233K. This combined model agrees well with nearly every available set of experiments and explains most of the well-known and even recently obtained results of MD simulations.

Peter O. Fedichev; Leonid I. Menshikov

2012-01-30T23:59:59.000Z

54

Sensor for detection of liquid spills on surfaces  

DOE Patents [OSTI]

A surface liquid detector is disclosed for detecting liquids spilled on surfaces such as floors. A temperature-sensitive thermistor probe is used in a bridge circuit to detect the change in resistance in the thermistor due to the change in thermal conductivity that occurs when a liquid contacts the probe. The device is characterized by the ability to detect either conductive or nonconductive liquids, such as water or oil spills.

Davis, Brent C. (Oak Ridge, TN); Gayle, Tom M. (Oak Ridge, TN)

1989-01-01T23:59:59.000Z

55

Analysis of liquified coal for nitrogenous bases; separation by high performance liquid chromatography and identification by probe microdistillation/mass spectrometry  

E-Print Network [OSTI]

ANALYSIS OF LIQUIFIED COAL FOR NITROGENOUS BASES; SEPARATION BY HIGH PERFORMANCE LIQUID CHROMATOGRAPHY AND IDENTIFICATION BY PROBE MICRODISTILLATION/MASS SPECTROMETRY A Thesis by LEONARD ROYCE SCHRONK Submitted to the Graduate College... AND IDENTIFICATION BY PROBE MICRODISTILLATION/MASS SPECTROMETRY A Thesis by LEONARD ROYCE SCHRONK Approved as to style and content by: Co-Charrman o Commlxtte ) (Co-Chazrman o Committee Me er Hea of Department December 1978 ABSTRACT Analysis of Liquified...

Schronk, Leonard Royce

1978-01-01T23:59:59.000Z

56

Water-saving liquid-gas conditioning system  

DOE Patents [OSTI]

A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

Martin, Christopher; Zhuang, Ye

2014-01-14T23:59:59.000Z

57

Probing the Earth's interior with a large-volume liquid scintillator detector  

E-Print Network [OSTI]

A future large-volume liquid scintillator detector would provide a high-statistics measurement of terrestrial antineutrinos originating from $\\beta$-decays of the uranium and thorium chains. In addition, the forward displacement of the neutron in the detection reaction $\\bar\

Kathrin A. Hochmuth; Franz v. Feilitzsch; Brian D. Fields; Teresa Marrodan Undagoitia; Lothar Oberauer; Walter Potzel; Georg G. Raffelt; Michael Wurm

2005-09-13T23:59:59.000Z

58

Ultrafast, Unimpeded Liquid Water Transport Through Graphene-Based Nanochannels Measured by Isotope Labelling  

E-Print Network [OSTI]

Graphene-based laminates, with ultralong and tortuous nanocapillaries formed by simply stacking graphene flakes together, have great promises in filtration and separation. However, the information on liquid water trans-membrane permeation is lacking, which is the most fundamental problem and of crucial importance in solution-based mass transport. Here, based on isotope labelling, we investigate the liquid water transportation through graphene-based nanocapillaries under no external hydrostatic pressures. Liquid water can afford an unimpeded permeation through graphene-based nanochannels with a diffusion coefficient 4~5 orders of magnitude larger than through sub-micrometer-sized polymeric channels. When dissolving ions in sources, the diffusion coefficient of ions through graphene channels lies in the same order of magnitude as water, while the ion diffusion is faster than water, indicating that the ions are mainly transported by fast water flows and the delicate interactions between ions and nanocapillary wa...

Sun, Pengzhan; Wang, Kunlin; Zhong, Minlin; Wu, Dehai; Zhu, Hongwei

2014-01-01T23:59:59.000Z

59

Absorption Spectra and Photolysis of Methyl Peroxide in Liquid and Frozen Water  

E-Print Network [OSTI]

, University of California, Irvine, California 92697, United States Department of Physical Chemistry with low temperatures, in the presence of clouds with a high liquid-water content and large solar zenith

Nizkorodov, Sergey

60

Volatile liquid hydrocarbon characterization of underwater hydrocarbon vents and formation waters from offshore production operations  

Science Journals Connector (OSTI)

Volatile liquid hydrocarbon characterization of underwater hydrocarbon vents and formation waters from offshore production operations ... The environmental implications of offshore oil and gas activities ... The environmental implications of offshore oil and gas activities ...

Theodor C. Sauer

1981-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The Near Infrared Absorption Band of Liquid Water at 1.79?  

Science Journals Connector (OSTI)

The near infrared absorption band of liquid water at 1.79? has been studied at various temperatures. No apparent changes in the band were detected in the temperature range from 4°C to 137°C.

J. R. Collins

1937-07-15T23:59:59.000Z

62

Ab initio calculation of the electronic absorption spectrum of liquid water  

SciTech Connect (OSTI)

The electronic absorption spectrum of liquid water was investigated by coupling a one-body energy decomposition scheme to configurations generated by classical and Born-Oppenheimer Molecular Dynamics (BOMD). A Frenkel exciton Hamiltonian formalism was adopted and the excitation energies in the liquid phase were calculated with the equation of motion coupled cluster with single and double excitations method. Molecular dynamics configurations were generated by different approaches. Classical MD were carried out with the TIP4P-Ew and AMOEBA force fields. The BLYP and BLYP-D3 exchange-correlation functionals were used in BOMD. Theoretical and experimental results for the electronic absorption spectrum of liquid water are in good agreement. Emphasis is placed on the relationship between the structure of liquid water predicted by the different models and the electronic absorption spectrum. The theoretical gas to liquid phase blue-shift of the peak positions of the electronic absorption spectrum is in good agreement with experiment. The overall shift is determined by a competition between the O–H stretching of the water monomer in liquid water that leads to a red-shift and polarization effects that induce a blue-shift. The results illustrate the importance of coupling many-body energy decomposition schemes to molecular dynamics configurations to carry out ab initio calculations of the electronic properties in liquid phase.

Martiniano, Hugo F. M. C.; Galamba, Nuno [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal)] [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Cabral, Benedito J. Costa, E-mail: ben@cii.fc.ul.pt [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal) [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa (Portugal); Instituto de Física da Universidade de São Paulo, CP 66318, 05314-970 São Paulo, SP (Brazil)

2014-04-28T23:59:59.000Z

63

Nuclear tanker producing liquid fuels from air and water  

E-Print Network [OSTI]

Emerging technologies in CO? air capture, high temperature electrolysis, microchannel catalytic conversion, and Generation IV reactor plant systems have the potential to create a shipboard liquid fuel production system ...

Galle-Bishop, John Michael

2011-01-01T23:59:59.000Z

64

Nuclear quantum effects in liquid water from an ab initio force matching approach  

E-Print Network [OSTI]

We have applied path integral simulations, in combination with new ab initio based water potentials, to investigate nuclear quantum effects in liquid water. Because direct ab initio path integral simulations are computationally expensive, a flexible water model is parameterized by force-matching to density functional theory-based molecular dynamics simulations. The resulting effective potentials provide an inexpensive replacement for direct \\textit{ab inito} molecular dynamics simulations and furthermore allow an efficient simulation of nuclear quantum effects. Static and dynamic properties of liquid water at ambient conditions are presented and the role of nuclear quantum effects, exchange-correlation functionals and dispersion corrections are discussed in regards to reproducing the experimental properties of liquid water.

Spura, Thomas; Habershon, Scott; Kühne, Thomas D

2014-01-01T23:59:59.000Z

65

Simultaneous liquid–liquid and vapour–liquid equilibria predictions of selected oxygenated aromatic molecules in mixtures with alkanes, alcohols, water, using the polar GC-PC-SAFT  

Science Journals Connector (OSTI)

Abstract Phase equilibria of oxygen-bearing aromatic compounds, hydrocarbons and water mixtures are of essential interest in many processes using feeds originating from biomass. The strong non-ideal thermodynamic behavior of these systems sometimes results in immiscibility with both water and alkanes. To address this problem, the GC-PPC-SAFT equation of state [Tamouza et al., 2004; Nguyen-Huynh et al., 2008a] is extended to some selected components: phenol, alkyl-phenols, alkyl-benzoates, benzaldehyde and anisole. However, as in these multifunctional compounds, the proximity of polar functional groups may result in a lack of transferability of the parameters from the monofunctional homologous species, some parameters have been adapted in view of physical arguments. Next, liquid–vapour and liquid–liquid equilibria of mixtures with n-alkanes were evaluated, using a predictive method for the binary interaction parameters (kij) [Nguyen-Huynh et al., 2008b]. Finally, mixtures with other associating compounds, as alcohols and water have also been considered. In all cases, both correlations and predictions are qualitatively and quantitatively satisfactory. The relative deviations obtained on bubble pressure of vapor–liquid equilibria are 4–8%, that is comparable to those obtained on previously investigated systems.

Nguyen-Huynh Dong; de Hemptinne Jean-Charles; Lugo Rafael; Passarello Jean-Philippe; Tobaly Pascal

2014-01-01T23:59:59.000Z

66

A liquid water management strategy for PEM fuel cell stacks  

E-Print Network [OSTI]

Gas and water management are key to achieving good performance from a PEM fuel cell stack. Previous experimentation had found, and this experimentation confirms, that one very effective method of achieving proper gas and water management is the use...

Van Nguyen, Trung; Knobbe, M. W.

2003-02-25T23:59:59.000Z

67

Determination of triclosan and triclocarban in environmental water samples with ionic liquid/ionic liquid dispersive liquid-liquid microextraction prior to HPLC-ESI-MS/MS  

Science Journals Connector (OSTI)

A hydrophobic ionic liquid was finely dispersed in aqueous solution along with a hydrophilic ionic liquid. Following centrifugation, the two phases aggregate to form relatively large droplets. Based on this pheno...

Ru-Song Zhao; Xia Wang; Jing Sun; Cong Hu; Xi-Kui Wang

2011-07-01T23:59:59.000Z

68

Liquid Water Dynamics in a Model Polymer Electrolyte Fuel Cell Flow Channel  

E-Print Network [OSTI]

Liquid Water Dynamics in a Model Polymer Electrolyte Fuel Cell Flow Channel by Chris Miller in a Model Polymer Electrolyte Fuel Cell Flow Channel by Chris Miller Bachelors of Engineering, University in a polymer electrolyte fuel cell is a critical issue in ensuring high cell performance. The water production

Victoria, University of

69

Mesoscopic modeling of liquid water transport in polymer electrolyte fuel cells  

SciTech Connect (OSTI)

A key performance limitation in polymer electrolyte fuel cells (PEFC), manifested in terms of mass transport loss, originates from liquid water transport and resulting flooding phenomena in the constituent components. Liquid water leads to the coverage of the electrochemically active sites in the catalyst layer (CL) rendering reduced catalytic activity and blockage of the available pore space in the porous CL and fibrous gas diffusion layer (GDL) resulting in hindered oxygen transport to the active reaction sites. The cathode CL and the GDL therefore playa major role in the mass transport loss and hence in the water management of a PEFC. In this article, we present the development of a mesoscopic modeling formalism coupled with realistic microstructural delineation to study the profound influence of the pore structure and surface wettability on liquid water transport and interfacial dynamics in the PEFC catalyst layer and gas diffusion layer.

Mukherjee, Partha P [Los Alamos National Laboratory; Wang, Chao Yang [PENNSTATE UNIV.

2008-01-01T23:59:59.000Z

70

Continuous Flow Liquid Microjunction Surface Sampling Probe Connected On-line with HPLC/MS for Spatially Resolved Analysis of Small Molecules and Proteins  

SciTech Connect (OSTI)

RATIONALE: A continuous flow liquid microjunction surface sampling probe extracts soluble material from surfaces for direct ionization and detection by MS. Demonstrated here is the on-line coupling of such a probe with HPLC/MS enabling extraction, separation and detection of small molecules and proteins from surfaces in a spatially resolved (~0.5 mm diameter spots) manner. Methods: A continuous flow liquid microjunction surface sampling probe was connected to a 6-port, 2-position valve for extract collection and injection to an HPLC column. A QTRAP 5500 hybrid triple quadrupole linear ion trap equipped with a Turbo V ion source operated in positive ESI mode was used for all experiments. System operation was tested with extraction, separation and detection of propranolol and associated metabolites from drug dosed tissues and proteins from dried sheep blood spots on paper. Results: Confirmed in the tissue were the parent drug and two different hydroxypropranolol glucuronides. The mass spectrometric response for these compounds from different locations in the liver showed an increase with increasing extraction time (5, 20 and 40 s extractions). For on-line separation and detection/identification of extracted proteins from dried sheep blood spots, two major protein peaks dominated the chromatogram and could be correlated with the expected masses for the hemoglobin and chains. Conclusions: Spatially resolved sampling, separation, and detection of small molecules and proteins from surfaces can be accomplished using a continuous flow liquid microjunction surface sampling probe coupled on-line with HPLC/MS detection.

Van Berkel, Gary J [ORNL; Kertesz, Vilmos [ORNL

2013-01-01T23:59:59.000Z

71

Short-range precipitation forecasts using assimilation of simulated satellite water vapor profiles and column cloud liquid water amounts  

SciTech Connect (OSTI)

These observing system simulation experiments investigate the assimilation of satellite-observed water vapor and cloud liquid water data in the initialization of a limited-area primitive equations model with the goal of improving short-range precipitation forecasts. The assimilation procedure presented includes two aspects: specification of an initial cloud liquid water vertical distribution and diabatic initialization. The satellite data is simulated for the next generation of polar-orbiting satellite instruments, the Advanced Microwave Sounding Unit (AMSU) and the High-Resolution Infrared Sounder (HIRS), which are scheduled to be launched on the NOAA-K satellite in the mid-1990s. Based on cloud-top height and total column cloud liquid water amounts simulated for satellite data a diagnostic method is used to specify an initial cloud water vertical distribution and to modify the initial moisture distribution in cloudy areas. Using a diabatic initialization procedure, the associated latent heating profiles are directly assimilated into the numerical model. The initial heating is estimated by time averaging the latent heat release from convective and large-scale condensation during the early forecast stage after insertion of satellite-observed temperature, water vapor, and cloud water formation.

Wu, X.; Diak, G.R.; Hayden, C.M.; Young, J.A. [Univ. of Wisconsin, Madison, WI (United States)] [Univ. of Wisconsin, Madison, WI (United States)

1995-02-01T23:59:59.000Z

72

Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Integration of Global Positioning System and Scanning Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates V. Mattioli and P. Basili Department of Electronic and Information Engineering University of Perugia Perugia, Italy E. R. Westwater Cooperative Institute for Research in Environmental Sciences University of Colorado National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado Introduction In recent years the Global Positioning System (GPS) has proved to be a reliable instrument for measuring precipitable water vapor (PWV) (Bevis et al. 1992), offering an independent source of information on water vapor when compared with microwave radiometers (MWRs), and/or radiosonde

73

Estimating the lunar mantle water budget from phosphates: Complications associated with silicate-liquid-immiscibility  

Science Journals Connector (OSTI)

Abstract The discovery of water within the lunar mantle has broad implications for the formation of the Earth–Moon system, differentiation of the Moon, and the magmatic evolution of lunar basalts, as well as the highland rocks. Recently, there has been considerable interest in using combined water abundances and H-isotope systematics of lunar apatites from mare basalts to quantify the origin and extent of water within the Moon’s mantle. However, the petrologic and geochemical conditions that govern apatite crystallization are not well-constrained, especially for high-FeO basaltic melts that crystallize at fO2 values below the iron–wüstite buffer. Apatites are typically located within the late-stage interstitial regions. In this contribution, we present detailed textural descriptions of late-stage inter-cumulus, residual-liquid pockets (i.e., mesostasis pockets), in order to understand the petrogenesis of lunar apatite. Results from five mare basalts demonstrate that the majority of the residual liquids in mesostasis regions have undergone silicate-liquid immiscibility (SLI) splitting into Si–K-rich (felsic) and Fe-rich (Fe-basaltic) conjugate liquids. We demonstrate the complexity of these residual liquids by documenting a wide range of water contents for apatites in several mesostasis pockets within a single mare basalt, a complexity common to many basalts. These data illustrate that individual apatite-hosting mesostasis pockets behave as independent sub-systems, even within a single rock. Furthermore, we present water concentrations for another phosphate phase, merrillite, indicating additional uncertainties during considerations of water partitioning into apatite. Fractional crystallization trends have been used in order to assess the conditions under which magmas are likely to undergo SLI. Predicted liquid lines of descent indicate that it is the late-stage residual liquids of lunar basalts with relatively low-Mg# (e.g., ?50) may not intersect the two-liquid field depending upon the fractionation trends in the late-stage mesostasis pockets. For samples that undergo SLI, the apatite/melt-partition coefficients required for back-calculating water abundances of the parental melts are compromised by the generation of two populations of apatites-merrillites from conjugate immiscible liquids. This process highlights an important complexity inherent to all water back-calculations that use apatite, as this requires an additional set of partition coefficients. We emphasize that the complex petrologic nature and common development of SLI of apatite-bearing, late-stage mesostasis pockets have not been considered in published apatite-volatile data. These factors, in additional to other considerations, illustrate why water back-calculations to model the primary melts from such data must be viewed with caution.

J.F. Pernet-Fisher; G.H. Howarth; Y. Liu; Y. Chen; L.A. Taylor

2014-01-01T23:59:59.000Z

74

Equations Governing Space-Time Variability of Liquid Water Path in Stratus Clouds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Equations Governing Space-Time Variability of Equations Governing Space-Time Variability of Liquid Water Path in Stratus Clouds K. Ivanova Pennsylvania State University University Park, Pennsylvania T. P. Ackerman Pacific Northwest National Laboratory Richland, Washington M. Ausloos University of Liège B-4000 Liège, Belgium Abstract We present a method on how to derive an underlying mathematical (statistical or model free) equation for a liquid water path (LWP) signal directly from empirical data. The evolution of the probability density functions (PDFs) from small to large time scales is explicitly derived in the framework of Fokker-Planck equation. A drift and a diffusion term describing the deterministic and stochastic influences on the non-Gaussian fat tails of the liquid water probability distributions are obtained from

75

The existence of supercooled liquid water at 150?K  

Science Journals Connector (OSTI)

... previously. The growth conditions used here produce optically flat non-porous water films,. A roughened interface between the isotopic layers, which in the worst case would result in intermixing ...

R. Scott Smith; Bruce D. Kay

1999-04-29T23:59:59.000Z

76

Gas-liquid-liquid equilibria in mixtures of water, light gases, and hydrocarbons  

SciTech Connect (OSTI)

Phase equilibrium in mixtures of water + light gases and water + heavy hydrocarbons has been investigated with the development of new local composition theory, new equations of state, and new experimental data. The preferential segregation and orientation of molecules due to different energies of molecular interaction has been simulated with square well molecules. Extensive simulation has been made for pure square well fluids and mixtures to find the local composition at wide ranges of states. A theory of local composition has been developed and an equation of state has been obtained for square well fluids. The new local composition theory has been embedded in several equations of state. The pressure of water is decoupled into a polar pressure and non-polar pressure according to the molecular model of water of Jorgensen et al. The polar pressure of water is combined with the BACK equation for the general description of polar fluids and their mixtures. Being derived from the steam table, the Augmented BACK equation is particularly suited for mixtures of water + non-polar substances such as the hydrocarbons. The hydrophobic character of the hydrocarbons had made their mixtures with water a special challenge. A new group contribution equation of state is developed to describe phase equilibrium and volumetric behavior of fluids while requiring only to know the molecular structure of the components. 15 refs., 1 fig.

Chao, K.C.

1990-01-01T23:59:59.000Z

77

Heating-induced glass-glass and glass-liquid transformations in computer simulations of water  

SciTech Connect (OSTI)

Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T “phase diagram” for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related, both being associated with the limit of kinetic stability of LDA (HDA)

Chiu, Janet; Giovambattista, Nicolas [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States)] [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States); Starr, Francis W. [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)] [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)

2014-03-21T23:59:59.000Z

78

Remote sensing of total integrated water vapor, wind speed, and cloud liquid water over the ocean using the Special Sensor Microwave/Imager (SSM/I)  

E-Print Network [OSTI]

A modified D-matrix retrieval method is the basis of the refined total integrated water vapor (TIWV), total integrated cloud liquid water (CLW), and surface wind speed (WS) retrieval methods that are developed. The 85 GHZ polarization difference...

Manning, Norman Willis William

2012-06-07T23:59:59.000Z

79

Comment on "Structure and dynamics of liquid water on rutile TiO2(110)  

SciTech Connect (OSTI)

Liu and co-workers [Phys. Rev. B 82, 161415 (2010)] discussed the long-standing debate regarding whether H2O molecules on the defect-free (110) surface of rutile ( -TiO2) sorb associatively, or there is dissociation of some or all first-layer water to produce hydroxyl surface sites. They conducted static density functional theory (DFT) and DFT molecular dynamics (DFT-MD) investigations using a range of cell configurations and functionals. We have reproduced their static DFT calculations of the influence of crystal slab thickness on water sorption energies. However, we disagree with several assertions made by these authors: (a) that second-layer water structuring and hydrogen bonding to surface oxygens and adsorbed water molecules are weak ; (b) that translational diffusion of water molecules in direct contact with the surface approaches that of bulk liquid water; and (c) that there is no dissociation of adsorbed water at this surface in contact with liquid water. These assertions directly contradict our publishedwork, which compared synchrotron x-ray crystal truncation rod, second harmonic generation, quasielastic neutron scattering, surface charge titration, and classical MD simulations of rutile (110) single-crystal surfaces and (110)-dominated powders in contact with bulk water, and (110)-dominated rutile nanoparticles with several monolayers of adsorbed water.

Wesolowski, David J [ORNL; Sofo, Jorge O. [Pennsylvania State University; Bandura, Andrei V. [St. Petersburg State University, St. Petersburg, Russia; Zhang, Zhan [Argonne National Laboratory (ANL); Mamontov, Eugene [ORNL; Predota, M. [University of South Bohemia, Czech Republic; Kumar, Nitin [ORNL; Kubicki, James D. [Pennsylvania State University; Kent, Paul R [ORNL; Vlcek, Lukas [ORNL; Machesky, Michael L. [Illinois State Water Survey, Champaign, IL; Fenter, Paul [Argonne National Laboratory (ANL); Cummings, Peter T [ORNL; Anovitz, Lawrence {Larry} M [ORNL; Skelton, A A [Vanderbilt University; Rosenqvist, Jorgen K [ORNL

2012-01-01T23:59:59.000Z

80

Time-Dependent Properties of Liquid Water:? A Comparison of Car?Parrinello and Born?Oppenheimer Molecular Dynamics Simulations  

Science Journals Connector (OSTI)

Time-Dependent Properties of Liquid Water:? A Comparison of Car?Parrinello and Born?Oppenheimer Molecular Dynamics Simulations ... Dynamical information of water interacting with its local environment can be gleaned from the vibrational power spectrum. ...

I-Feng W. Kuo; Christopher J. Mundy; Matthew J. McGrath; J. Ilja Siepmann

2006-07-27T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Nuclear quantum effects in liquid water from path-integral simulations using an ab initio force matching approach  

E-Print Network [OSTI]

We have applied path integral simulations, in combination with new ab initio based water potentials, to investigate nuclear quantum effects in liquid water. Because direct ab initio path integral simulations are computationally expensive, a flexible water model is parameterized by force-matching to density functional theory-based molecular dynamics simulations. The resulting effective potentials provide an inexpensive replacement for direct ab inito molecular dynamics simulations and allow efficient simulation of nuclear quantum effects. Static and dynamic properties of liquid water at ambient conditions are presented and the role of nuclear quantum effects, exchange-correlation functionals and dispersion corrections are discussed in regards to reproducing the experimental properties of liquid water.

Thomas Spura; Christopher John; Scott Habershon; Thomas D. Kühne

2014-02-06T23:59:59.000Z

82

Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reforming of Renewable Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) * U. (Balu) Balachandran, T. H. Lee, C. Y. Park, and S. E. Dorris Energy Systems Division E-mail: balu@anl.gov * Work supported by the Hydrogen, Fuel Cells, and Infrastructure Technologies Program of DOE's Office of Energy Efficiency and Renewable Energy Presented at the Bio-derived Liquids Working Group (BILIWG) Meeting, Nov. 6, 2007. BILIWG Meeting, Nov. 6, 2007 2 Objective & Rationale Objective: Develop compact dense ceramic membrane reactors that enable the efficient and cost-effective production of hydrogen by reforming renewable liquid fuels using pure oxygen produced by water splitting and transported by an OTM. Rationale: Membrane technology provides the means to attack barriers to the

83

Optical Kerr effect of liquid and supercooled water: the experimental and data analysis perspective  

E-Print Network [OSTI]

The time-resolved optical Kerr effect spectroscopy (OKE) is a powerful experimental tool enabling accurate investigations of the dynamic phenomena in molecular liquids. We introduced innovative experimental and fitting procedures, that permit a safe deconvolution of sample response function from the instrumental function. This is a critical issue in order to measure the dynamics of sample presenting weak signal, e.g. liquid water. We report OKE data on water measuring intermolecular vibrations and the structural relaxation processes in an extended temperature range, inclusive of the supercooled states. The unpreceded data quality makes possible a solid comparison with few theoretical models; the multi-mode Brownian oscillator model, the Kubo's discrete random jump model and the schematic mode-coupling model. All these models produce reasonable good fits of the OKE data of stable liquid water, i.e. over the freezing point. The features of water dynamics in the OKE data becomes unambiguous only at lower temperatures, i.e. for water in the metastable supercooled phase. Hence this data enable a valid comparison between the model fits. We found that the schematic mode-coupling model provides the more rigorous and complete model for water dynamics, even if is intrinsic hydrodynamic approach hide the molecular information.

A. Taschin; P. Bartolini; R. Eramo; R. Righini; R. Torre

2014-06-20T23:59:59.000Z

84

Measurement of Liquid Water Accumulation in a PEMFC with Dead-Ended Anode  

E-Print Network [OSTI]

Measurement of Liquid Water Accumulation in a PEMFC with Dead-Ended Anode Jason B. Siegel,a, *,z electrolyte membrane fuel cell PEMFC with a dead-ended anode is observed using neutron imaging gas diffusion layer. Even though dry hydrogen is supplied to the anode via pressure regulation

Stefanopoulou, Anna

85

NATURAL RADIONUCLIDES MEASUREMENTS IN DRINKING WATER BY LIQUID SCINTILLATION COUNTING. METHODS AND RESULTS  

E-Print Network [OSTI]

to dose evaluation, namely gross alpha and beta activity, uranium and radium isotopes content. For tritium activity and uranium isotope concentration have been measured. A Quantulus-Wallac scintillation counter hasNATURAL RADIONUCLIDES MEASUREMENTS IN DRINKING WATER BY LIQUID SCINTILLATION COUNTING. METHODS

86

Monte Carlo Simulation of Electromagnetic Interactions of Radiation with Liquid Water in  

E-Print Network [OSTI]

; nevertheless the concept of dose is not adequate to estimate the radiation effects when microscopic entitiesMonte Carlo Simulation of Electromagnetic Interactions of Radiation with Liquid Water. They address a physics domain relevant to the simulation of radiation effects in biological systems, where

Paris-Sud XI, Université de

87

Pulse radiolysis of liquid water using picosecond electron pulses produced by a table-top terawatt laser system  

E-Print Network [OSTI]

Pulse radiolysis of liquid water using picosecond electron pulses produced by a table-top terawatt into a supersonic helium gas jet are used to ionize liquid water. The decay of the hydrated electrons produced electron generator is shown, for the first time, to produce sufficient charge to conduct time resolved

Umstadter, Donald

88

HIGH TEMPERATURE CONDUCTIVITY PROBE FOR MONITORING CONTAMINATION LEVELS IN POWER PLANT BOILER WATER.  

E-Print Network [OSTI]

??A high temperature/high pressure flow through probe was designed to measure high temperature electrical conductivity of aqueous (aq) dilute electrolyte solutions, an application which can… (more)

Hipple, Sarah

2008-01-01T23:59:59.000Z

89

Radiative Importance of ThinŽ Liquid Water Clouds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Program Program Accomplishments of the Instantaneous Radiative Flux (IRF) Working Group August 2006 AERI Observations at Southern Great Plains Improve Infrared Radiative Transfer Models Turner et al., JAS, 2004 * AERI observations used to evaluate clear sky IR radiative transfer models * Long-term comparisons have improved - Spectral line database parameters - Water vapor continuum absorption models * Reduced errors in computation of downwelling radiative IR flux by approx 4; current uncertainty is on the order of 1.5 W/m 2 AERI - (Pre-ARM Model) AERI - (Model in 2003) 1 RU = 1 mW / (m 2 sr cm -1 ) Excellent Agreement in Clear Sky Shortwave Radiative Transfer Between Obs and Calcs Shortwave Flux Bias (Solid) Shortwave Flux RMS (Hatched) W m -2 * Comparison of shortwave radiative flux at the surface

90

The Structure of Water in Crystalline Aluminophosphates: Isolated Water and Intermolecular Clusters Probed by Raman Spectroscopy, NMR and Structural Modeling  

E-Print Network [OSTI]

of water in different states, e.g., bulk water, water clusters, aqueous solutions of ions or organicThe Structure of Water in Crystalline Aluminophosphates: Isolated Water and Intermolecular Clusters are used to elucidate the properties of water in Metavariscite, AlPO4-H3, AlPO4-8 and VPI-5. The framework

Goddard III, William A.

91

Capillary filling with giant liquid/solid slip: dynamics of water uptake by carbon nanotubes  

E-Print Network [OSTI]

This article discusses the way the standard description of capillary filling dynamics has to be modified to account for liquid/solid slip in nanometric pores. It focuses in particular on the case of a large slip length compared to the pore size. It is shown that the liquid viscosity does not play a role, and that the flow is only controlled by the friction coefficient of the liquid at the wall. Moreover in the Washburn regime, the filling velocity does not depend on the tube radius. Finally, molecular dynamics simulations suggest that this standard description fails to describe the early stage of capillary filling of carbon nanotubes by water, since viscous dissipation at the tube entrance must be taken into account.

Laurent Joly

2011-12-06T23:59:59.000Z

92

Liquid-Water Uptake and Removal in PEM Fuel-Cell Components  

SciTech Connect (OSTI)

Management of liquid water is critical for optimal fuel-cell operation, especially at low temperatures. It is therefore important to understand the wetting properties and water holdup of the various fuel-cell layers. While the gas-diffusion layer is relatively hydrophobic and exhibits a strong intermediate wettability, the catalyst layer is predominantly hydrophilic. In addition, the water content of the ionomer in the catalyst layer is lower than that of the bulk membrane, and is affected by platinum surfaces. Liquid-water removal occurs through droplets on the surface of the gas-diffusion layer. In order to predict droplet instability and detachment, a force balance is used. While the pressure or drag force on the droplet can be derived, the adhesion or surface-tension force requires measurement using a sliding-angle approach. It is shown that droplets produced by forcing water through the gas-diffusion layer rather than placing them on top of it show much stronger adhesion forces owing to the contact to the subsurface water.

Das, Prodip K.; Gunterman, Haluna P.; Kwong, Anthony; Weber, Adam Z.

2011-09-23T23:59:59.000Z

93

Validation of Satellite-Derived Liquid Water Paths Using ARM SGP Microwave Radiometers  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Satellite-Derived Liquid Water Paths Using Satellite-Derived Liquid Water Paths Using ARM SGP Microwave Radiometers M. M. Khaiyer and J. Huang Analytical Services & Materials, Inc. Hampton, Virginia P. Minnis, B. Lin, and W. L. Smith, Jr. National Aeronautics and Space Administration Langley Research Center Hampton, Virginia A. Fan Science Applications International Corporation Hampton, Virginia A. Rapp Colorado State University Fort Collins, Colorado Introduction Satellites are useful for monitoring climatological parameters over large domains. They are especially useful for measuring various cloud microphysical and radiative parameters where ground-based instruments are not available. The geostationary operational environmental satellite (GOES) has been used to retrieve cloud and radiative properties over an extended domain centered on the Atmospheric

94

Ab-initio molecular dynamics simulation of liquid water by Quantum Monte Carlo  

E-Print Network [OSTI]

Despite liquid water is ubiquitous in chemical reactions at roots of life and climate on earth, the prediction of its properties by high-level ab initio molecular dynamics simulations still represents a formidable task for quantum chemistry. In this article we present a room temperature simulation of liquid water based on the potential energy surface obtained by a many-body wave function through quantum Monte Carlo (QMC) methods. The simulated properties are in excellent agreement with recent neutron scattering and X-ray experiments, particularly concerning the position of the oxygen-oxygen peak in the radial distribution function, at variance of previous Density Functional Theory attempts. Given the excellent performances of QMC on large scale supercomputers, this work opens new perspectives for predictive and reliable ab-initio simulations of complex chemical systems.

Zen, Andrea; Mazzola, Guglielmo; Guidoni, Leonardo; Sorella, Sandro

2014-01-01T23:59:59.000Z

95

Ab-initio molecular dynamics simulation of liquid water by Quantum Monte Carlo  

E-Print Network [OSTI]

Despite liquid water is ubiquitous in chemical reactions at roots of life and climate on earth, the prediction of its properties by high-level ab initio molecular dynamics simulations still represents a formidable task for quantum chemistry. In this article we present a room temperature simulation of liquid water based on the potential energy surface obtained by a many-body wave function through quantum Monte Carlo (QMC) methods. The simulated properties are in excellent agreement with recent neutron scattering and X-ray experiments, particularly concerning the position of the oxygen-oxygen peak in the radial distribution function, at variance of previous Density Functional Theory attempts. Given the excellent performances of QMC on large scale supercomputers, this work opens new perspectives for predictive and reliable ab-initio simulations of complex chemical systems.

Andrea Zen; Ye Luo; Guglielmo Mazzola; Leonardo Guidoni; Sandro Sorella

2014-12-09T23:59:59.000Z

96

Ionic Liquid?Water Mixtures: Enhanced Kw for Efficient Cellulosic Biomass Conversion  

Science Journals Connector (OSTI)

† Departments of Chemistry and ... Under relatively mild conditions (?140 °C, 1 atm) and in the absence of added acid catalysts typically employed in biomass conversion, cellulose dissolved in certain ionic liquids (ILs) has been converted into water-soluble reducing sugars in high total reducing sugar yield (up to 97%), or directly into the biomass platform chemical 5-hydroxymethyl furfural (HMF) in high conversion (up to 89%) when CrCl2 is added. ...

Yuetao Zhang; Hongbo Du; Xianghong Qian; Eugene Y.-X. Chen

2010-03-10T23:59:59.000Z

97

Ice-water and liquid-vapor phase transitions by a Ginzburg–Landau model  

Science Journals Connector (OSTI)

A model for the first order phase transitions as ice-water and liquid-vapor is proposed using the Ginzburg–Landau equation for the order parameter ? . In this model the density ? is composed of two quantities ? 0 and ? 1 such that 1 / ? = 1 / ? 0 + 1 / ? 1 where ? 1 is strictly connected to the order parameter ? . By means of this decomposition we are able to represent the Andrew diagram without the use of the heuristic van der Waals equation.

Mauro Fabrizio

2008-01-01T23:59:59.000Z

98

Three-dimensional effects of liquid water flooding in the cathode of a PEM fuel cell  

E-Print Network [OSTI]

. Researchers all over the world are focusing on optimizing this system to be cost competitive with energy conversion devices currently available. It is a well known fact that the cathode of the PEM fuel cell is the performance limiting component due...THREE DIMENSIONAL EFFECTS OF LIQUID WATER FLOODING IN THE CATHODE OF A PEM FUEL CELL by Dilip Natarajan and Trung Van Nguyen* Department of Chemical and Petroleum Engineering University of Kansas Lawrence, KS 66045, USA Submitted...

Natarajan, Dilip; Van Nguyen, Trung

2003-03-27T23:59:59.000Z

99

Neutron scattering from polycrystalline ice (Ih): Some keys to understanding the collective behavior of liquid water  

Science Journals Connector (OSTI)

The phonon dispersion in the second Brillouin zone of polycrystalline ice (Ih) has been measured. The results confirm the predictions of a previous lattice-dynamics calculation [A. Criado, F.J. Bermejo, M. García-Hernández, and J.L. Martínez, Phys. Rev. E 47, 3516 (1993)] where anomalously steep dispersion curves of an apparent acoustic origin were found. The relevance of the present findings for explaining some apparently anomalous features concerning the collective dynamics of liquid water is finally discussed.

F. J. Bermejo; E. Frikkee; M. García-Hernández; J. L. Martínez; A. Criado

1993-09-01T23:59:59.000Z

100

Online 1H NMR Spectroscopic Study of the Reaction Kinetics in Mixtures of Acetaldehyde and Water Using a New Microreactor Probe Head  

Science Journals Connector (OSTI)

Mixtures of acetaldehyde and water are reactive multicomponent systems because poly(oxymethylmethylene) glycols are formed. A study on the kinetics of the formation of these oligomers was carried out using a new microreactor NMR probe head that combines ...

Andreas Scheithauer; Alexander Brächer; Thomas Grützner; Daniel Zollinger; Werner R. Thiel; Erik von Harbou; Hans Hasse

2014-10-16T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Electronic structure effects in liquid water studied by photoelectron spectroscopy and density functional theory  

SciTech Connect (OSTI)

We present valence photoelectron emission spectra of liquid water in comparison with gas-phase water, ice close to the melting point, low temperature amorphous and crystalline ice. All aggregation states have major electronic structure changes relative to the free molecule, with rehybridization and development of bonding and anti-bonding states accompanying the hydrogen bond formation. Sensitivity to the local structural order, most prominent in the shape and splitting of the occupied 3a{sub 1} orbital, is understood from the electronic structure averaging over various geometrical structures, and reflects the local nature of the orbital interaction.

Nordlund, Dennis; Odelius, Michael; Bluhm, Hendrik; Ogasawara, Hirohito; Pettersson, Lars G.M.; Nilsson, Anders

2008-04-29T23:59:59.000Z

102

Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process  

SciTech Connect (OSTI)

Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

2011-10-16T23:59:59.000Z

103

Rapid analysis of cyanuric acid in swimming pool waters by high performance liquid chromatography using porous graphitic carbon  

Science Journals Connector (OSTI)

An approach is presented for reducing analysis times of cyanuric acid in swimming pool waters by high performance liquid chromatography (HPLC ... ) to fully resolve cyanuric acid from other pool interferences wit...

R. Cantú; O. Evans; M. L. Magnuson

2001-04-01T23:59:59.000Z

104

Influence of Liquid Water Content and Temperature on the Form and Growth of Branched Planar Snow Crystals in a Cloud  

Science Journals Connector (OSTI)

How liquid water content (LWC) and temperature affect the growth of branched planar snow crystals is poorly understood. To address this issue, a vertical supercooled cloud tunnel was used to grow 167 individual snow crystals for 10 min under ...

Tsuneya Takahashi

2014-11-01T23:59:59.000Z

105

A ‘first principles’ potential energy surface for liquid water from VRT spectroscopy of water clusters  

Science Journals Connector (OSTI)

...the many-body induction energy (Leforestier et al. 2005). This new potential was named VRT...ordinary water: substance. New York: Hafner. Dyke, T. R...mechanics and path integrals New York: McGraw- Hill. Frenkel...

2005-01-01T23:59:59.000Z

106

Effect of direct liquid water injection and interdigitated flow field on the performance of proton exchange membrane fuel cells  

E-Print Network [OSTI]

70-108B One Cyclotron Road Berkeley, California 94720 December 2, 1997 Key Words: Proton Exchange Membrane fuel cells, humidification, gas distribution, direct liquid water injection, interdigitated flow fields. * Corresponding... of the catalyst layers were made of waterproof, carbon fiber cloths. Liquid water was injected by two metering pumps into two heated stainless steel coils, where it was preheated to the cell operating temperatures, and then directly into the gas streams...

Wood, D. L.; Yi, Y. S.; Nguyen, Trung Van

1998-01-01T23:59:59.000Z

107

Breaking Through the Glass Ceiling: Recent Experimental Approaches to Probe the Properties of Supercooled Liquids near the Glass Transition.  

SciTech Connect (OSTI)

Experimental measurements of the properties supercooled liquids at temperatures near their respective glass transition temperatures, Tg, are requisite for understanding the behavior of glasses and amorphous solids. Unfortunately, many supercooled molecular liquids rapidly crystallize at temperatures far above their Tg making such measurements difficult to nearly impossible. In this perspective we discuss some recent alternative approaches to obtain experimental data in the temperature regime near Tg. These new approaches may yield the additional experimental data necessary to test current theoretical models of the dynamical slowdown that occurs in supercooled liquids approaching the glass transition.

Smith, R. Scott; Kay, Bruce D.

2012-03-15T23:59:59.000Z

108

Ionic liquid effects on mass transfer efficiency in extractive distillation of water–ethanol mixtures  

Science Journals Connector (OSTI)

Abstract The relatively high viscosities of ionic liquids could reduce the mass transfer efficiency of the extractive distillation process. The rate-based model was adopted to analyze this phenomenon since it predicted the performance of an extractive distillation pilot plant using ionic liquids as solvent. For the water–ethanol separation, three ionic liquids: 1-ethyl-3-methylimidazolium chloride, 1-ethyl-3-methylimidazolium acetate and 1-ethyl-3-methylimidazolium dicyanamide and the organic solvent ethylene glycol were used for the analysis. Simulations were conducted for sieve trays and Mellapak® 250Y. The results indicate that relatively high viscosities affect the mass transfer efficiency. However, the improvements in relative volatilities obtained from the ionic liquids help to overcome this effect. However, with high solvent viscosities (>65 mPa s at T = 353.15 K) it was not possible to overcome the reductions. Additionally, at higher distillate rates high relative volatilities yielded negative effects on mass transfer efficiency because of a decrease in vapor velocity.

E. Quijada-Maldonado; G. Wytze Meindersma; André B. de Haan

2014-01-01T23:59:59.000Z

109

Effect of potassium halide salts on mutual solubility of water + aromatic hydrocarbons liquid–liquid interface studied with surface and interfacial tensions  

Science Journals Connector (OSTI)

Abstract Surface tension (?, mN/m) of benzene, toluene and ethylbenzene (EB) aromatic hydrocarbons (AHCs, low density liquids, LDL) and interfacial tension (IFT, mN/m) both with water and aqueous 0.1, 0.5, 1.0 mol kg? 1 KF, KCl, KBr, KI (high density liquids, HDL) separately at 303.15 K are reported. Contributions of –CH3 and –CH2CH3 of toluene and EB to hydrophobic interactions are calculated from ?toluene–?benzene and ?EB–?benzene, respectively. \\{IFTs\\} of water + AHCs liquid–liquid interfaces (LLI) are as toluene (34.71) > EB (32.35) > benzene (32.32 mN m? 1), with a ~ 32.32 mN m? 1 decrease from 71.40 mN m? 1 of water. \\{AHCs\\} with hyperconjugation (HC) and positive inductive effects (+ ve IE) with toluene and EB LLI have reduced IFT by 39.08, 2.39, ? 1.56 mN m? 1, respectively. The effects of ?-conjugation, –H, –CH3 and –CH2CH3 on surface tension are calculated as ?-conjugation = ?(IFTair–liquid ? IFTAPHS–benzene), –CH3 = ?(IFTAPHS–toluene ? IFTAPHS–benzene). The effects of halide salts on hypercongugation –H(–CH3)/3, –CH2CH3 are obtained from ?(IFTAPHS–EB ? IFTAPHS–benzene).

Man Singh

2014-01-01T23:59:59.000Z

110

Laser Ablation Sampling of Materials Directly into the Formed Liquid Microjunction of a Continuous Flow Surface Sampling Probe/Electrospray Ionization Emitter for Mass Spectral Analysis and Imaging  

SciTech Connect (OSTI)

Transmission geometry laser ablation directly into a formed liquid microjunction of a continuous flow liquid microjunction surface sampling probe/electrospray ionization emitter was utilized for molecular and elemental detection and mass spectrometry imaging. The ability to efficiently capture and ionize ablated material was demonstrated by the detection of various small soluble n-mers of polyaniline and silver ion solvent clusters formed from laser ablation of electropolymerized polyaniline and silver thin films, respectively. In addition, analysis of surfaces that contain soluble components was accomplished by coating or laminating the sample with an insoluble film to enable liquid junction formation without directly extracting material from the surface. The ability to perform mass spectrometry imaging at a spatial resolution of about 50 m was illustrated by using laminated inked patterns on a microscope slide. In general, these data demonstrate at least an order of magnitude signal enhancement compared to the non-contact, laser ablation droplet capture-based surface sampling/ionization approaches that have been previously presented.

Ovchinnikova, Olga S [ORNL] [ORNL; Lorenz, Matthias [ORNL] [ORNL; Kertesz, Vilmos [ORNL] [ORNL; Van Berkel, Gary J [ORNL] [ORNL

2013-01-01T23:59:59.000Z

111

Nanoparticle enhanced evaporation of liquids: A case study of silicone oil and water  

E-Print Network [OSTI]

Evaporation is a fundamental physical phenomenon, of which many challenging questions remain unanswered. Enhanced evaporation of liquids in some occasions is of enormous practical significance. Here we report the enhanced evaporation of the nearly permanently stable silicone oil by dispersing with nanopariticles including CaTiO3, anatase and rutile TiO2. The results can inspire the research of atomistic mechanism for nanoparticle enhanced evaporation and exploration of evaporation control techniques for treatment of oil pollution and restoration of dirty water.

Wenbin Zhang; Rong Shen; Kunquan Lu; Ailing Ji; Zexian Cao

2012-10-23T23:59:59.000Z

112

Effects of liquid pore water on acoustic wave propagation in snow as a Biot-type porous material  

E-Print Network [OSTI]

A method to estimate phase velocity and attenuation of acoustic waves in the presence of liquid water in a snowpack is presented. The method is based on Biot's theory of wave propagation in porous materials. Empirical relations and a priori information is used to characterize snow as a porous material as a function of porosity. Plane wave theory and an equivalent pore fluid are used to solve Biot's differential equations and to asses the impact of the air and water in the pore space. The liquid water in the pore space of a snow pack reduces the velocity of the first compressional wave by roughly 300 m/s for every 0.1 increase in liquid water saturation. Also the attenuation of the compressional waves is increased with increasing liquid water content. Two end member models for compaction are evaluated to asses the importance of an independent density measurement for an estimate of liquid pore water saturation in snow with acoustic waves. The two end members correspond to no compaction at all and to a melting s...

Sidler, Rolf

2015-01-01T23:59:59.000Z

113

Evaluating the phase equilibria of liquid water + natural gas mixtures using cubic equations of state with asymmetric mixing rules  

Science Journals Connector (OSTI)

Based on a previously developed liquid–liquid mixing rule we present a modified and robust mixing rule for accurate prediction of water content of natural gas mixtures and the natural gas solubility in liquid water phase. The non-density dependent mixing rule (NDD) and the new mixing rule are incorporated into the Peng–Robinson (PR), Soave–Redlich–Kwong (SRK), and Nasrifar–Bolland (NB) equations of state to investigate their accuracies in estimating the water content of the gas phase as well as the gas solubility in the aqueous phase. For each binary system water + hydrocarbon, water + carbon dioxide, water + hydrogen sulfide, and water + nitrogen, three binary interaction parameters are required to describe the gas–liquid water equilibria. In this work, experimental data from literature were used to tune the parameters. The results are in good agreement with experimental data, demonstrating the reliability of the new mixing rule and the thermodynamic approach used in this work.

P. Reshadi; Kh. Nasrifar; M. Moshfeghian

2011-01-01T23:59:59.000Z

114

Kinematical relations among radar-observed water concentrations, vertical motions, and liquid-water drop-size spectra in convective clouds  

E-Print Network [OSTI]

and liquid- water concentration, a one-dimensional (vertical) continuity equation for water substance is considered. Atmospheric values of parameters which appear in the continuity equation are determined from radar reflectivity measurements. Empirical... viii I INTRODUCTION Cloud Motions in General Equations Governing Cloud Parameters A Kinematical Equation Based on the Continuity of Water Substance Determinati. on of the Values of the Atmospheric Variables Appearing in the Kinematical Equation...

Runnels, Robert Clayton

2012-06-07T23:59:59.000Z

115

Isotopic mass-dependence of metal cation diffusion coefficients in liquid water  

SciTech Connect (OSTI)

Isotope distributions in natural systems can be highly sensitive to the mass (m) dependence of solute diffusion coefficients (D) in liquid water. Isotope geochemistry studies routinely have assumed that this mass dependence either is negligible (as predicted by hydrodynamic theories) or follows a kinetic-theory-like inverse square root relationship (D {proportional_to} m{sup -0.5}). However, our recent experimental results and molecular dynamics (MD) simulations showed that the mass dependence of D is intermediate between hydrodynamic and kinetic theory predictions (D {proportional_to} m{sup -{beta}} with 0 {<=} {beta} < 0.2 for Li{sup +}, Cl{sup -}, Mg{sup 2+}, and the noble gases). In this paper, we present new MD simulations and experimental results for Na{sup +}, K{sup +}, Cs{sup +}, and Ca{sup 2+} that confirm the generality of the inverse power-law relation D {proportional_to} m{sup -{beta}}. Our new findings allow us to develop a general description of the influence of solute valence and radius on the mass dependence of D for monatomic solutes in liquid water. This mass dependence decreases with solute radius and with the magnitude of solute valence. Molecular-scale analysis of our MD simulation results reveals that these trends derive from the exponent {beta} being smallest for those solutes whose motions are most strongly coupled to solvent hydrodynamic modes.

Bourg, I.C.; Richter, F.M.; Christensen, J.N.; Sposito, G.

2009-01-11T23:59:59.000Z

116

Probing water properties and cationic exchange in calcium-silicate-hydrate : an atomistic modeling study  

E-Print Network [OSTI]

Two problems related to the assessment of the performance of cementitious materials in the nuclear fuel cycle are investigated by means of atomistic simulations. The first is the structural and dynamic nature of water ...

Youssef, Mostafa Youssef Mahmoud

2010-01-01T23:59:59.000Z

117

Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR  

E-Print Network [OSTI]

We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

Nicodemus, Rebecca A.

118

Local Depolarization in Hydrophobic and Hydrophilic Ionic Liquids/Water Mixtures: Car–Parrinello and Classical Molecular Dynamics Simulation  

Science Journals Connector (OSTI)

Local Depolarization in Hydrophobic and Hydrophilic Ionic Liquids/Water Mixtures: Car–Parrinello and Classical Molecular Dynamics Simulation ... Their analysis of the molecular electrostatic properties compared with the previous work on smaller number of ion pairs per unit cell shows that the immediate liquid environment predominantly affects the molecular electric dipole moments, whereas the bulk contributions appear to be minor. ... The ion-pair/water interaction energy (Einter), which is defined as the difference between the energy of the ion pair and water system (EIL-W) and the sum of the energies of the single ion pair (EIL) and water (EW), can be calculated by:(1)Each complex and corresponding water and anion were optimized for structure and energy at the B3LYP/6-311++G(d,p) level of theory by the above computational procedure. ...

Mohammad Hadi Ghatee; Amin Reza Zolghadr

2013-01-08T23:59:59.000Z

119

An Assessment of Microwave Absorption Models and Retrievals of Cloud Liquid Water Using Clear-Sky Data  

SciTech Connect (OSTI)

Passive microwave radiometers have a long history in the remote sensing of atmospheric liquid and water vapor. Retrievals of these quantities are sensitive to variations in pressure and temperature of the liquid and water vapor. Rather than use a statistical or climatological approach to account for the natural variability in atmospheric pressure and temperature, additional information on the atmospheric profile at the time of the radiometer measurements can be directly incorporated into the retrieval process. Such an approach has been referred to in the literature as a “physical-iterative” solution. This paper presents an assessment of the accuracy of the column liquid water path that can be expected using such an iterative technique as a result of uncertainties in the microwave emissions from oxygen and water vapor. It is shown that the retrieval accuracy is influenced by the accuracy of the instrument measurements and the quality of the atmospheric profiles of temperature and pressure, as one would expect. But also critical is the uncertainty in the absorption coefficients used in the underlying microwave radiative transfer model. The uncertainty in the absorption coefficients is particularly problematic in that it may well bias the liquid water retrieval. The differences between 3 absorption models examined in this paper are equivalent to a bias of 15 to 30 g/m2, depending on the total column water vapor. An examination of typical liquid water paths from the Southern Great Plains region of the United States shows that errors of this magnitude have significant implications for shortwave radiation and retrievals of cloud effective particle size.

Marchand, Roger T.; Ackerman, Thomas P.; Westwater, Ed R.; Clough, Shepard A.; Cady-Pereira, Karen; Liljegren, James C.

2003-12-19T23:59:59.000Z

120

Sensitivity of the simulated climate to a diagnostic formulation for cloud liquid water  

SciTech Connect (OSTI)

The accurate treatment of clouds and their radiative properties is widely regarded to be among the most important problems facing global climate modeling. A number of the more serious systematic simulation biases in the NCAR Community Climate Model (CCM2) appear to be related to deficiencies in the treatment of cloud optical properties. In this paper, a simple diagnostic parameterization for cloud liquid water is presented. The sensitivity of the simulated climate to this alternative formulation, both in terms of mean climate metrics and measures of the climate system response, is illustrated. Resulting simulations show significant reductions in CCM2 systematic biases, particularly with respect to surface temperature, precipitation, and extratropical geopotential height-field anomalies. Many aspects of the simulated response to ENSO forcing are also substantially improved.

Hack, J.J. [National Center for Atmospheric Research, Boulder, CO (United States)] [National Center for Atmospheric Research, Boulder, CO (United States)

1998-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

The Influence of Chain Dynamics on the Far Infrared Spectrum of Liquid Methanol-Water Mixtures  

SciTech Connect (OSTI)

Far-infrared absorption spectroscopy has been used to study the low frequency ({center_dot} 100 cm{sup -1}) intermolecular modes of methanol in mixtures with water. With the aid of a first principles molecular dynamics simulation on an equivalent system, a detailed understanding about the origin of the low frequency IR modes has been established. The total dipole spectrum from the simulation suggests that the bands appearing in the experimental spectra at approximately 55 cm{sup -1} and 70 cm{sup -1} in methanol and methanol-rich mixtures arise from both fluctuations and torsional motions occurring within the methanol hydrogen-bonded chains. The influence of these modes on both the solvation dynamics and the relaxation mechanisms in the liquid are discussed within the context of recent experimental and theoretical results that have emerged from studies focusing on the short time dynamics in the methanol hydrogen bond network.

Woods, K.N.; /Stanford U., Phys. Dept.; Wiedemann, H.; /SLAC, SSRL; ,

2005-07-12T23:59:59.000Z

122

In situ diagnostic of liquid water distribution in cathode catalyst layer in an operating PEMFC by high-resolution soft X-ray radiography  

Science Journals Connector (OSTI)

To investigate the water transport behavior in the cathode catalyst layer (CCL) of an operating proton exchange membrane fuel cell (PEMFC), we examined transversal liquid water distributions in the CCL by using high-resolution soft X-ray radiography. The liquid water concentration gradient across the CCL was observed at a spatial resolution of 1.5 ?m. More liquid water accumulated in the CCL at the gas diffusion layer side than at the polymer electrolyte membrane side. The effect of accumulated liquid water in the CCL on the charge-transfer resistance was confirmed by electrochemical impedance spectroscopy. Liquid water accumulation in the CCL corresponds to deterioration of charge-transfer in the electrode.

Phengxay Deevanhxay; Takashi Sasabe; Shohji Tsushima; Shuichiro Hirai

2012-01-01T23:59:59.000Z

123

Mesoscopic structuring and dynamics of alcohol/water solutions probed by Terahertz Time-Domain Spectroscopy and Pulsed Field Gradient Nuclear Magnetic Resonance  

E-Print Network [OSTI]

in the structure of alcohol/water mixtures. Taking aqueous ethanol as a representative example, excess enthalpy, heat capacity, diffusivity, and viscosity all exhibit maxima or minima at ?15?20 mol %;12,16,20?23 this is attributable to Received: March 20, 2014... dielectric spectroscopy and the results were compared to femtosecond infrared pump? probe studies. By investigating a range of concentrations of aqueous tetramethylurea solutions it was found that the dynamics of the water molecules in close vicinity...

Li, Ruoyu; D'Agostino, Carmine; McGregor, James; Mantle, Michael D.; Zeitler, J. Axel; Gladden, Lynn F.

2014-08-12T23:59:59.000Z

124

Analysis of two independent methods for retrieving liquid water profiles in spring and summer Arctic boundary clouds  

E-Print Network [OSTI]

-based remote sensing, optimal estimation, LES model with explicit microphysics, cloud liquid water algorithms Heat Budget of the Arctic Ocean (SHEBA) project. An algorithm developed by Frisch et al. [1995, 1998 matrix of the LWC profile is calculated, an optimal estimation method is applied to the SHEBA data

Shupe, Matthew

125

Charge transfer effects of ions at the liquid water/vapor interface  

SciTech Connect (OSTI)

Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 Å away from the surface.

Soniat, Marielle; Rick, Steven W., E-mail: srick@uno.edu [Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148 (United States)

2014-05-14T23:59:59.000Z

126

Absorption spectra of liquid water and aqueous buffers between 0.3 and Department of Physics, University of California, Santa Barbara, California 93106  

E-Print Network [OSTI]

Absorption spectra of liquid water and aqueous buffers between 0.3 and 3.72 THz Jing Xua Department-dependent terahertz absorption with attenuation lengths on the order of tens of micrometers. To access this spectral.5 THz, these studies provide a well- documented absorption spectrum for liquid water, at approxi- mately

Xu, Jing

127

The Individual and Collective Effects of Exact Exchange and Dispersion Interactions on the Ab Initio Structure of Liquid Water  

E-Print Network [OSTI]

In this work, we report the results of a series of density functional theory (DFT) based ab initio molecular dynamics (AIMD) simulations of ambient liquid water using a hierarchy of exchange-correlation (XC) functionals to investigate the individual and collective effects of exact exchange (Exx), via the PBE0 hybrid functional, non-local vdW/dispersion interactions, via a fully self-consistent density-dependent dispersion correction, and approximate nuclear quantum effects (aNQE), via a 30 K increase in the simulation temperature, on the microscopic structure of liquid water. Based on these AIMD simulations, we found that the collective inclusion of Exx, vdW, and aNQE as resulting from a large-scale AIMD simulation of (H$_2$O)$_{128}$ at the PBE0+vdW level of theory, significantly softens the structure of ambient liquid water and yields an oxygen-oxygen structure factor, $S_{\\rm OO}(Q)$, and corresponding oxygen-oxygen radial distribution function, $g_{\\rm OO}(r)$, that are now in quantitative agreement with the best available experimental data. This level of agreement between simulation and experiment as demonstrated herein originates from an increase in the relative population of water molecules in the interstitial region between the first and second coordination shells, a collective reorganization in the liquid phase which is facilitated by a weakening of the hydrogen bond strength by the use of the PBE0 hybrid XC functional, coupled with a relative stabilization of the resultant disordered liquid water configurations by the inclusion of non-local vdW/dispersion interactions.

Robert A. DiStasio Jr.; Biswajit Santra; Zhaofeng Li; Xifan Wu; Roberto Car

2014-05-20T23:59:59.000Z

128

Probing the thermal character of analogue Hawking radiation for shallow water waves?  

E-Print Network [OSTI]

We study and numerically compute the scattering coefficients of shallow water waves blocked by a stationary counterflow. When the flow is transcritical, the coefficients closely follow Hawking's prediction according to which black holes should emit a thermal spectrum. We study how the spectrum deviates from thermality when reducing the maximal flow velocity, with a particular attention to subcritical flows since these have been recently used to test Hawking's prediction. For such flows, we show that the emission spectrum is strongly suppressed, and that its Planckian character is completely lost. For low frequencies, we also show that the scattering coefficients are dominated by elastic hydrodynamical channels. Our numerical results reproduce rather well the observations made by S. Weinfurtner {\\it et al.} in the Vancouver experiment. Nevertheless, we propose a new interpretation of what has been observed, as well as new experimental tests.

Florent Michel; Renaud Parentani

2014-09-15T23:59:59.000Z

129

Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation)  

Broader source: Energy.gov [DOE]

Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland.

130

Removal of a liquid paraffin film from a water surface by short pulses from a CO{sub 2} laser  

SciTech Connect (OSTI)

The process of removal of a liquid paraffin film from a water surface irradiated by 40 - 270-{mu}s pulses from a CO{sub 2} laser is studied experimentally and theoretically. It is found for the first time that the mass of removed paraffin can exceed that of paraffin located in the region irradiated by the laser pulse. A theoretical model is proposed which explains the results obtained. (laser applications and other topics in quantum electronics)

Antonova, L I; Drobyazko, S V; Evdokimov, I A; Krasyukov, A G; Likhanskii, V V; Loboiko, A I; Senatorov, Yu M [State Research Center of Russian Federation 'Troitsk Institute for Innovation and Fusion Research', Troitsk, Moscow Region (Russian Federation)

2002-02-28T23:59:59.000Z

131

TIME-DEPENDENT PROPERTIES OF LIQUID WATER: A COMPARISON OF CAR-PARRINELLO AND BORN-OPPENHIEMER MOLECULAR DYNAMICS SIMULATIONS  

SciTech Connect (OSTI)

A series of 30 ps first principles molecular dynamics simulations in the microcanonical ensemble were carried out to investigate transport and vibrational properties of liquid water. To allow for sufficient sampling, the thermodynamic constraints were set to an elevated temperature of around 423 K and a density of 0.71 g/cm{sup 3} corresponding to the saturated liquid density for the Becke-Lee-Yang-Parr (BLYP) representation of water. Four simulations using the Car-Parrinello molecular dynamics (CPMD) technique with varying values of the fictitious electronic mass ({mu}) and two simulations using the Born-Oppenheimer molecular dynamics (BOMD) technique are analyzed to yield structural and dynamical information. At the selected state point, the simulations are found to exhibit non-glassy dynamics and yield consistent results for the liquid structure and the self-diffusion coefficient, although the statistical uncertainties in the latter quantity are quite large. Consequently, it can be said that the CPMD and BOMD methods produce equivalent results for these properties on the time scales reported here. However, it was found that the choice of {mu} affects the frequency spectrum of the intramolecular modes, shifting them slightly to regions of lower frequency. Using a value of {mu} = 400 a.u. results in a significant drift in the electronic kinetic energy of the system over the course of 30 ps and a downward drift in the ionic temperature. Therefore, for long trajectories at elevated temperatures, lower values of this parameter are recommended for CPMD simulations of water.

Kuo, I W; Mundy, C; McGrath, M; Siepmann, J I

2005-12-29T23:59:59.000Z

132

The Individual and Collective Effects of Exact Exchange and Dispersion Interactions on the Ab Initio Structure of Liquid Water  

E-Print Network [OSTI]

In this work, we report the results of a series of density functional theory (DFT) based ab initio molecular dynamics (AIMD) simulations of ambient liquid water using a hierarchy of exchange-correlation (XC) functionals to investigate the individual and collective effects of exact exchange (Exx), via the PBE0 hybrid functional, non-local vdW/dispersion interactions, via a fully self-consistent density-dependent dispersion correction, and approximate nuclear quantum effects (aNQE), via a 30 K increase in the simulation temperature, on the microscopic structure of liquid water. Based on these AIMD simulations, we found that the collective inclusion of Exx, vdW, and aNQE as resulting from a large-scale AIMD simulation of (H$_2$O)$_{128}$ at the PBE0+vdW level of theory, significantly softens the structure of ambient liquid water and yields an oxygen-oxygen structure factor, $S_{\\rm OO}(Q)$, and corresponding oxygen-oxygen radial distribution function, $g_{\\rm OO}(r)$, that are now in quantitative agreement with ...

DiStasio, Robert A; Li, Zhaofeng; Wu, Xifan; Car, Roberto

2014-01-01T23:59:59.000Z

133

Determination of Selected Herbicides and Phenols in Water and Soils by Solid-Phase Extraction and High-Performance Liquid Chromatography  

Science Journals Connector (OSTI)

......1987). 6. G.E. Batley. Applications of liquid chromatography with electro- chemical detection to the analysis of oil shale process waters. J. Chromatogr. 382: 409416 (1987). 7. H. Farber, K. Nick, and H.F. Scoeler. Determination......

Irena Baranowska; Celina Pieszko

2000-05-01T23:59:59.000Z

134

A liquid film motor  

Science Journals Connector (OSTI)

It is well known that electro-hydrodynamical effects in freely suspended liquid films can force liquids to flow. Here, we report a purely electrically driven rotation in water and some other liquid suspended film...

A. Amjadi; R. Shirsavar; N. Hamedani Radja…

2009-05-01T23:59:59.000Z

135

Probing Aqueous Surfaces by ToF-SIMS. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

beneath it. This window supports the liquid against the vacuum by the liquid’s surface tension and limits the high-density vapor region traversed by the probe beams to...

136

High temperature probe  

DOE Patents [OSTI]

A high temperature probe for sampling, for example, smokestack fumes, and is able to withstand temperatures of 3000.degree. F. The probe is constructed so as to prevent leakage via the seal by placing the seal inside the water jacket whereby the seal is not exposed to high temperature, which destroys the seal. The sample inlet of the probe is also provided with cooling fins about the area of the seal to provide additional cooling to prevent the seal from being destroyed. Also, a heated jacket is provided for maintaining the temperature of the gas being tested as it passes through the probe. The probe includes pressure sensing means for determining the flow velocity of an efficient being sampled. In addition, thermocouples are located in various places on the probe to monitor the temperature of the gas passing there through.

Swan, Raymond A. (Fremont, CA)

1994-01-01T23:59:59.000Z

137

Life in the Solar System Assume we need energy, liquid water, and organic materials.  

E-Print Network [OSTI]

would land on the ice pack, use heat from a nuclear reactor to melt through it, and release a hydrobot;Comets ­ Reservoirs of Icy Water #12;Comets ­ Reservoirs of Icy Water #12;Herschel Space Observatory #12

Shirley, Yancy

138

Concentration and High Pressure Liquid Chromatographic Determination of Pyrazon in Water  

Science Journals Connector (OSTI)

......dissolved In the water. A 500 ml sample of lake water with 25% dissolved...evaporated under nitrogen and the residue...been determined in water (1-3), soils...1,4,7), gas chromatography...due to decreased solubility of the herbi......

Gathu Nyagah

1981-10-01T23:59:59.000Z

139

1-Methyl Naphthalene Reorientation at the Air-Liquid Interface upon Water Saturation Studied by Vibrational Broad Bandwidth Sum Frequency Generation Spectroscopy  

E-Print Network [OSTI]

will encounter gas-phase water molecules or may react with atmospheric oxidants. The uptake and reaction1-Methyl Naphthalene Reorientation at the Air-Liquid Interface upon Water Saturation Studied by Vibrational Broad Bandwidth Sum Frequency Generation Spectroscopy Elizabeth L. Hommel and Heather C. Allen

140

Design and testing of a deep sea formation water and temeperature sampling probe for the Ocean Drilling Program  

E-Print Network [OSTI]

. Components were then fabricated by a local machine shop. All components under went quality inspection and were then assembled. Full scale testing at the Ocean Drilling Programs Annex is the next step. If successful, the probe is to undergo sea trials...

Fisseler, Patrick James

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Trace determination of triclosan and triclocarban in environmental water samples with ionic liquid dispersive liquid-phase microextraction prior to HPLC–ESI-MS–MS  

Science Journals Connector (OSTI)

A novel and environmentally friendly microextraction method, termed ionic liquid dispersive liquid-phase microextraction (IL-DLPME), has been developed for rapid enrichment of triclosan and triclocarban before an...

Ru-Song Zhao; Xia Wang; Jing Sun; Shan-Shan Wang…

2010-06-01T23:59:59.000Z

142

Pore-Level Liquid Water Transport Through Composite Diffusion Media of PEMFC  

E-Print Network [OSTI]

, and Chao-Yang Wang*,z Electrochemical Engine Center and Department of Mechanical and Nuclear Engineering of liquid injection sites into the GDL. © 2010 The Electrochemical Society. DOI: 10.1149/1.3491359 All, low operation temperature, and low noise. The low operation tempera- ture allows for fast startup

143

Monitoring of Precipitable Water Vapor and Cloud Liquid Path from Scanning Microwave Radiometers During the 2003 Cloudiness Inter-Comparison Experiment  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Monitoring of Precipitable Water Vapor and Cloud Liquid Monitoring of Precipitable Water Vapor and Cloud Liquid Path from Scanning Microwave Radiometers During the 2003 Cloudiness Inter-Comparison Experiment V. Mattioli Department of Electronic and Information Engineering University of Perugia Perugia, Italy E. R. Westwater Cooperative Institute for Research in Environmental Sciences University of Colorado National Oceanic and Atmospheric Administration Environmental Technology Laboratory Boulder, Colorado V. Morris Pacific Northwest National Laboratory Richland, Washington Introduction Ground-based microwave radiometers (MWR) are widely used to measure atmospheric precipitable water vapor (PWV) and cloud liquid path (CLP). Comparisons of PWV derived from MWRs with water vapor retrievals from instruments like radiosondes, Global Positioning System (GPS) and Raman

144

Decontamination of Nuclear Liquid Wastes Status of CEA and AREVA R and D: Application to Fukushima Waste Waters - 12312  

SciTech Connect (OSTI)

Liquid wastes decontamination processes are mainly based on two techniques: Bulk processes and the so called Cartridges processes. The first technique has been developed for the French nuclear fuel reprocessing industry since the 60's in Marcoule and La Hague. It is a proven and mature technology which has been successfully and quickly implemented by AREVA at Fukushima site for the processing of contaminated waters. The second technique, involving cartridges processes, offers new opportunities for the use of innovative adsorbents. The AREVA process developed for Fukushima and some results obtained on site will be presented as well as laboratory scale results obtained in CEA laboratories. Examples of new adsorbents development for liquid wastes decontamination are also given. A chemical process unit based on co-precipitation technique has been successfully and quickly implemented by AREVA at Fukushima site for the processing of contaminated waters. The asset of this technique is its ability to process large volumes in a continuous mode. Several chemical products can be used to address specific radioelements such as: Cs, Sr, Ru. Its drawback is the production of sludge (about 1% in volume of initial liquid volume). CEA developed strategies to model the co-precipitation phenomena in order to firstly minimize the quantity of added chemical reactants and secondly, minimize the size of co-precipitation units. We are on the way to design compact units that could be mobilized very quickly and efficiently in case of an accidental situation. Addressing the problem of sludge conditioning, cementation appears to be a very attractive solution. Fukushima accident has focused attention on optimizations that should be taken into account in future studies: - To better take account for non-typical aqueous matrixes like seawater; - To enlarge the spectrum of radioelements that can be efficiently processed and especially short lives radioelements that are usually less present in standard effluents resulting from nuclear activities; - To develop reversible solid adsorbents for cartridge-type applications in order to minimize wastes. (authors)

Fournel, B.; Barre, Y.; Lepeytre, C.; Peycelon, H. [CEA Marcoule, DTCD, BP17171, 30207 Bagnols sur Ceze (France); Grandjean, A. [Institut de Chimie Separative de Marcoule, UMR5257 CEA-CNRS-UM2-ENSCM, BP17171, 30207 Bagnols sur Ceze (France); Prevost, T.; Valery, J.F. [AREVA NC, Paris La Defense (France); Shilova, E.; Viel, P. [CEA Saclay, DSM/IRAMIS/SPCSI, 91191 Gif sur Yvette (France)

2012-07-01T23:59:59.000Z

145

7-88 A geothermal power plant uses geothermal liquid water at 160C at a specified rate as the heat source. The actual and maximum possible thermal efficiencies and the rate of heat rejected from this power plant  

E-Print Network [OSTI]

and potential energy changes are zero. 3 Steam properties are used for geothermal water. Properties Using7-31 7-88 A geothermal power plant uses geothermal liquid water at 160ºC at a specified rate saturated liquid properties, the source and the sink state enthalpies of geothermal water are (Table A-4) k

Bahrami, Majid

146

Liquid-Water Uptake and Removal in PEM Fuel-Cell Components  

E-Print Network [OSTI]

Uptake and Removal in PEM Fuel-Cell Components Prodip K. DasWater management in PEM fuel cells is critical for optimumof droplet dynamics in PEM fuel-cell gas flow channels has

Das, Prodip K.

2013-01-01T23:59:59.000Z

147

Advanced Scintillator Detector Concept (ASDC): A Concept Paper on the Physics Potential of Water-Based Liquid Scintillator  

E-Print Network [OSTI]

The recent development of Water-based Liquid Scintillator (WbLS), and the concurrent development of high-efficiency and high-precision-timing light sensors, has opened up the possibility for a new kind of large-scale detector capable of a very broad program of physics. The program would include determination of the neutrino mass hierarchy and observation of CP violation with long-baseline neutrinos, searches for proton decay, ultra-precise solar neutrino measurements, geo- and supernova neutrinos including diff?use supernova antineutrinos, and neutrinoless double beta decay. We outline here the basic requirements of the Advanced Scintillation Detector Concept (ASDC), which combines the use of WbLS, doping with a number of potential isotopes for a range of physics goals, high efficiency and ultra-fast timing photosensors, and a deep underground location. We are considering such a detector at the Long Baseline Neutrino Facility (LBNF) far site, where the ASDC could operate in conjunction with the liquid argon t...

Alonso, J R; Bergevin, M; Bernstein, A; Bignell, L; Blucher, E; Calaprice, F; Conrad, J M; Descamps, F B; Diwan, M V; Dwyer, D A; Dye, S T; Elagin, A; Feng, P; Grant, C; Grullon, S; Hans, S; Jaffe, D E; Kettell, S H; Klein, J R; Lande, K; Learned, J G; Luk, K B; Maricic, J; Marleau, P; Mastbaum, A; McDonough, W F; Oberauer, L; Gann, G D Orebi; Rosero, R; Rountree, S D; Sanchez, M C; Shaevitz, M H; Shokair, T M; Smy, M B; Strait, M; Svoboda, R; Tolich, N; Vagins, M R; van Bibber, K A; Viren, B; Vogelaar, R B; Wetstein, M J; Winslow, L; Wonsak, B; Worcester, E T; Wurm, M; Yeh, M; Zhang, C

2014-01-01T23:59:59.000Z

148

Advanced Scintillator Detector Concept (ASDC): A Concept Paper on the Physics Potential of Water-Based Liquid Scintillator  

E-Print Network [OSTI]

The recent development of Water-based Liquid Scintillator (WbLS), and the concurrent development of high-efficiency and high-precision-timing light sensors, has opened up the possibility for a new kind of large-scale detector capable of a very broad program of physics. The program would include determination of the neutrino mass hierarchy and observation of CP violation with long-baseline neutrinos, searches for proton decay, ultra-precise solar neutrino measurements, geo- and supernova neutrinos including diffuse supernova antineutrinos, and neutrinoless double beta decay. We outline here the basic requirements of the Advanced Scintillation Detector Concept (ASDC), which combines the use of WbLS, doping with a number of potential isotopes for a range of physics goals, high efficiency and ultra-fast timing photosensors, and a deep underground location. We are considering such a detector at the Long Baseline Neutrino Facility (LBNF) far site, where the ASDC could operate in conjunction with the liquid argon tracking detector proposed by the LBNE collaboration. The goal is the deployment of a 30-100 kiloton-scale detector, the basic elements of which are being developed now in experiments such as WATCHMAN, ANNIE, SNO+, and EGADS.

J. R. Alonso; N. Barros; M. Bergevin; A. Bernstein; L. Bignell; E. Blucher; F. Calaprice; J. M. Conrad; F. B. Descamps; M. V. Diwan; D. A. Dwyer; S. T. Dye; A. Elagin; P. Feng; C. Grant; S. Grullon; S. Hans; D. E. Jaffe; S. H. Kettell; J. R. Klein; K. Lande; J. G. Learned; K. B. Luk; J. Maricic; P. Marleau; A. Mastbaum; W. F. McDonough; L. Oberauer; G. D. Orebi Gann; R. Rosero; S. D. Rountree; M. C. Sanchez; M. H. Shaevitz; T. M. Shokair; M. B. Smy; A. Stahl; M. Strait; R. Svoboda; N. Tolich; M. R. Vagins; K. A. van Bibber; B. Viren; R. B. Vogelaar; M. J. Wetstein; L. Winslow; B. Wonsak; E. T. Worcester; M. Wurm; M. Yeh; C. Zhang

2014-10-24T23:59:59.000Z

149

The influence of irrigation water salinity on optimal nitrogen, phosphorus, and potassium liquid fertilizer rates  

E-Print Network [OSTI]

of nitrogen fertilizer to compensate for leaching losses (Miyamoto, 1984). The effect of salt stress on mineral status of plants has been studied extensively for many agronomic and horticultural crops (Al-Saidi and Alawi, 1984; Al-Saidi et al. , 1985... cultivars (Al-Saidi and Alawi, 1984; Al- Saidi et al. , 1985). Ten flowering annuals were grown in saline water with electrical conductivities of 0. 8, 1. 5, 3. 0, or 4. 5 dS m from a 2:1 equivalent weight basis of CaCI2 and NaCI in tap water (Devitt...

Campos Nu?n?ez, Ricardo

2012-06-07T23:59:59.000Z

150

Liquid Water Transport in Gas Diffusion Layer of Polymer Electrolyte Fuel Cells  

E-Print Network [OSTI]

. In addition, at high current densities, excessive amount of water is generated and condenses, filling as a promising candidate for high-efficiency, low-emission power sources. High-current-density operation of PEFCs, The Pennsylvania State University, University Park, Pennsylvania 16802, USA High-current-density performance

151

Water clusters: Untangling the mysteries of the liquid, one molecule at a time  

Science Journals Connector (OSTI)

...the structures of clathrate hydrates (95). The hexamer represents...water hexamer determined in the gas phase resembles the basic unit...100 Feynman R P Leighton R B Sands M ( 1964 ) in The Feynman Lectures...eds Feynman R P Leighton R B Sands M ( Addison–Wesley , Reading...

Frank N. Keutsch; Richard J. Saykally

2001-01-01T23:59:59.000Z

152

Limestone-Particle-Stabilized Macroemulsion of Liquid and Supercritical Carbon Dioxide in Water for Ocean Sequestration  

Science Journals Connector (OSTI)

In relation to ocean disposal of CO2 from power plants, a comprehensive plume model was developed to simulate the dynamic, near-field behavior of CO2 released in the water column as either a buoyant liq. ... from flue gases and injected into the oceans. ...

D. Golomb; E. Barry; D. Ryan; C. Lawton; P. Swett

2004-07-20T23:59:59.000Z

153

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for conductive liquids for vertical installation in a tank, the detector having a probe positioned within a sheath and insulated therefrom by a seal so that the tip of the probe extends proximate to but not below the lower end of the sheath, the lower end terminating in a rim that is provided with notches, said lower end being tapered, the taper and notches preventing debris collection and bubble formation, said lower end when contacting liquid as it rises will form an airtight cavity defined by the liquid, the interior sheath wall, and the seal, the compression of air in the cavity preventing liquid from further entry into the sheath and contact with the seal. As a result, the liquid cannot deposit a film to form an electrical bridge across the seal.

Tshishiku, Eugene M. (Augusta, GA)

2011-08-09T23:59:59.000Z

154

Task 15 -- Remediation of organically contaminated soil using hot/liquid (subcritical) water. Semi-annual report, April 1--September 30, 1997  

SciTech Connect (OSTI)

This activity involves a pilot-scale demonstration of the use of hot/liquid water for the removal of organic contaminants from soil at the pilot (20 to 40 kg) scale. Lab-scale studies are being performed to determine the optimum temperature, contact time, and flow rates for removal of the organic contaminants. Initial investigations into using carbon sorbents to clean the extractant water for recycle use and to concentrate the extracted contaminants in a small volume for disposal are also being performed. Liquid water is normally considered to be too polar a solvent to be effective for removal of organic contaminants from contaminated soils and sludges. However, the Energy and Environmental Research Center (EERC) has demonstrated that the polarity of liquid water can be changed from that of a very polar solvent at ambient conditions to that of an organic solvent (e.g., ethanol or acetonitrile) by simply raising the temperature. The EERC has exploited this unique property of liquid water to obtain highly selective extractions of polar (at lower temperatures) to nonpolar (at 200 to 250 C) organics from contaminated soils and sludges. Only moderate pressures (a maximum of about 45 atm at 250 C and lower pressures at lower temperatures) are required. With this procedure, all detectable hazardous organics were removed from the sludge, thus making the remaining material (about 99% of the original mass) a nonhazardous material. The present understanding of hot/liquid water extraction for the removal of hazardous organics from contaminated soils and sludges is being used to develop the engineering parameters needed to perform a pilot-scale demonstration of the remediation technology. Progress during the report period is summarized.

Hawthorne, S.B.

1997-12-31T23:59:59.000Z

155

Generating Singlet Oxygen Bubbles: A New Mechanism for Gas–Liquid Oxidations in Water  

Science Journals Connector (OSTI)

Our interest in developing a singlet oxygen [1O2 (1?g)]-sparging reactor came from small-scale devices for disinfection of, for example, municipal and well water, but which used filtration, ozone, and/or UV light. ... In front of the A10449 mechanical shutter of the detector was placed either a 25-mm-diameter, 1150 nm long pass filter (FEL1150, Thorlabs Inc.) or one of three 25-mm-diameter NIR bandpass filters centered at 1220, 1270, and 1315 nm (OD4 blocking, fwhm = 15 nm, Omega, Brattleboro, VT). ... (19) Drying of the composite was done at 50 °C for 10 h to avoid destruction of the confined phthalocyanine molecules, producing an aerogel that shrunk ?10% where some, but not all adsorbed water was removed. ...

Dorota Bartusik; David Aebisher; BiBi Ghafari; Alan M. Lyons; Alexander Greer

2012-01-20T23:59:59.000Z

156

Cloud fraction, liquid and ice water contents derived from long-term radar, lidar, and microwave radiometer data are systematically compared to models to quantify and  

E-Print Network [OSTI]

Cloud fraction, liquid and ice water contents derived from long-term radar, lidar, and microwave a systematic evaluation of clouds in forecast models. Clouds and their associated microphysical processes for end users of weather forecasts, who may be interested not only in cloud cover, but in other variables

Hogan, Robin

157

Viscosity, specific (for liquids)  

Science Journals Connector (OSTI)

n. The ratio between the viscosity of a liquid and the viscosity of water at the same temperature. Specific viscosity is sometimes used interchangeably with relative viscosity for liquids.

2007-01-01T23:59:59.000Z

158

Dynamics of water probed with vibrational echo correlation spectroscopy John B. Asbury, Tobias Steinel, and Kyungwon Kwak  

E-Print Network [OSTI]

and the time scale for the production of vibrational relaxation induced broken hydrogen bond ``photoproducts infrared experimental methods have been applied to extract information about hydrogen bond dynamics from to the study of water,5,15­19,40 provide a direct method for accessing hydrogen bond dynamics through

Fayer, Michael D.

159

Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model  

SciTech Connect (OSTI)

A lattice Boltzmann color-fluid model, which was recently proposed by Liu et al. [H. Liu, A.J. Valocchi, and Q. Kang. Three-dimensional lattice Boltzmann model for immiscible two-phase flow simulations. Phys. Rev. E, 85:046309, 2012.] based on a concept of continuum surface force, is improved to simulate immiscible two-phase flows in porous media. The new improvements allow the model to account for different kinematic viscosities of both fluids and to model fluid-solid interactions. The capability and accuracy of this model is first validated by two benchmark tests: a layered two-phase flow with a viscosity ratio, and a dynamic capillary intrusion. This model is then used to simulate liquid CO2 (LCO2) displacing water in a dual-permeability pore network. The extent and behavior of LCO2 preferential flow (i.e., fingering) is found to depend on the capillary number (Ca), and three different displacement patterns observed in previous micromodel experiments are reproduced. The predicted variation of LCO2 saturation with Ca, as well as variation of specific interfacial length with LCO2 saturation, are both in good agreement with the experimental observations. To understand the effect of heterogeneity on pore-scale displacement, we also simulate LCO2 displacing water in a randomly heterogeneous pore network, which has the same size and porosity as the dual-permeability pore network. In comparison to the dual-permeability case, the transition from capillary fingering to viscous fingering occurs at a higher Ca, and LCO2 saturation is higher at low Ca but lower at high Ca. In either pore network, the LCO2-water specific interfacial length is found to obey a power-law dependence on LCO2 saturation.

Liu, Haihu; Valocchi, Albert J.; Werth, Charles J.; Kang, Oinjun; Oostrom, Martinus

2014-11-01T23:59:59.000Z

160

Variable path length spectrophotometric probe  

DOE Patents [OSTI]

A compact, variable pathlength, fiber optic probe for spectrophotometric measurements of fluids in situ. The probe comprises a probe body with a shaft having a polished end penetrating one side of the probe, a pair of optic fibers, parallel and coterminous, entering the probe opposite the reflecting shaft, and a collimating lens to direct light from one of the fibers to the reflecting surface of the shaft and to direct the reflected light to the second optic fiber. The probe body has an inlet and an outlet port to allow the liquid to enter the probe body and pass between the lens and the reflecting surface of the shaft. A linear stepper motor is connected to the shaft to cause the shaft to advance toward or away from the lens in increments so that absorption measurements can be made at each of the incremental steps. The shaft is sealed to the probe body by a bellows seal to allow freedom of movement of the shaft and yet avoid leakage from the interior of the probe.

O'Rourke, Patrick E. (157 Greenwood Dr., Martiney, GA 30907); McCarty, Jerry E. (104 Recreation Dr., Aiken, SC 29803); Haggard, Ricky A. (1144 Thornwood Drive, North Augusta, SC 29891)

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
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161

Evaluation of autotrophic growth of ammonia-oxidizers associated with granular activated carbon used for drinking water purification by DNA-stable isotope probing  

Science Journals Connector (OSTI)

Abstract Nitrification is an important biological function of granular activated carbon (GAC) used in advanced drinking water purification processes. Newly discovered ammonia-oxidizing archaea (AOA) have challenged the traditional understanding of ammonia oxidation, which considered ammonia-oxidizing bacteria (AOB) as the sole ammonia-oxidizers. Previous studies demonstrated the predominance of AOA on GAC, but the contributions of AOA and AOB to ammonia oxidation remain unclear. In the present study, DNA-stable isotope probing (DNA-SIP) was used to investigate the autotrophic growth of AOA and AOB associated with GAC at two different ammonium concentrations (0.14 mg N/L and 1.4 mg N/L). GAC samples collected from three full-scale drinking water purification plants in Tokyo, Japan, had different abundance of AOA and AOB. These samples were fed continuously with ammonium and 13C-bicarbonate for 14 days. The DNA-SIP analysis demonstrated that only AOA assimilated 13C-bicarbonate at low ammonium concentration, whereas AOA and AOB exhibited autotrophic growth at high ammonium concentration. This indicates that a lower ammonium concentration is preferable for AOA growth. Since AOA could not grow without ammonium, their autotrophic growth was coupled with ammonia oxidation. Overall, our results point towards an important role of AOA in nitrification in GAC filters treating low concentration of ammonium.

Jia Niu; Ikuro Kasuga; Futoshi Kurisu; Hiroaki Furumai; Takaaki Shigeeda

2013-01-01T23:59:59.000Z

162

pH Meter probe assembly  

DOE Patents [OSTI]

An assembly for mounting a pH probe in a flowing solution, such as a sanitary sewer line, which prevents the sensitive glass portion of the probe from becoming coated with grease, oil, and other contaminants, whereby the probe gives reliable pH indication over an extended period of time. The pH probe assembly utilizes a special filter media and a timed back-rinse feature for flushing clear surface contaminants of the filter. The flushing liquid is of a known pH and is utilized to check performance of the probe.

Hale, Charles J. (San Jose, CA)

1983-01-01T23:59:59.000Z

163

A system to test the effects of materials on the electron drift lifetime in liquid argon and observations on the effect of water  

SciTech Connect (OSTI)

A materials test system (MTS) has been developed at FNAL to assess the suitability of materials for use in a large liquid argon time projection chamber. During development of the MTS, it was noted that controlling the cryostat pressure with a 'raining' condenser reduced the electron drift lifetime in the liquid argon. The effect of condensing has been investigated using a series of passive materials to filter the condensate. We report the results of these studies and of tests on different candidate materials for detector construction. The inferred reduction of electron drift lifetime by water concentrations in the parts per trillion is of particular interest.

Andrews, R.; Jaskierny, W.; Jostlein, H.; Kendziora, C.; Pordes, S.; Tope, T.; /Fermilab; ,

2009-07-01T23:59:59.000Z

164

Probing the Reaction Intermediates for the Water-Gas Shift over Inverse CeOx/Au(111) Catalysts  

SciTech Connect (OSTI)

The water-gas shift (WGS) is an important reaction for the production of molecular H{sub 2} from CO and H{sub 2}O. An inverse CeO{sub x}/Au(1 1 1) catalyst exhibits a very good WGS activity, better than that of copper surfaces or Cu nanoparticles dispersed on a ZnO(0 0 0 {bar 1}) substrate which model current WGS industrial catalysts. In this work we report on intermediates likely to arise during the CO + H{sub 2}O reaction over CeO{sub x}/Au(1 1 1) using soft X-ray photoemission (sXPS) and near-edge X-ray absorption fine structure (NEXAFS). Several potential intermediates including formates (HCOO), carbonates (CO{sub 3}) and carboxylates (HOCO) are considered. Adsorption of HCOOH and CO{sub 2} is used to create both HCOO and CO{sub 3} on the CeO{sub x}/Au(1 1 1) surface, respectively. HCOO appears to have greater stability with desorption temperatures up to 600 K while CO{sub 3} only survives on the surface up to 300 K. On the CeO{sub x}/Au(1 1 1) catalysts, the presence of Ce{sup 3+} leads to the dissociation of H{sub 2}O to give OH groups. We demonstrate experimentally that the OH species are stable on the surface up to 600 K and interact with CO to yield weakly bound intermediates. When there is an abundance of Ce{sup 4+}, the OH concentration is diminished and the likely intermediates are carbonates. As the surface defects are increased and the Ce{sup 3+}/Ce{sup 4+} ratio grows, the OH concentration also grows and both carbonate and formate species are observed on the surface after dosing CO to H{sub 2}O/CeO{sub x}/Au(1 1 1). The addition of ceria nanoparticles to Au(1 1 1) is essential to generate an active WGS catalyst and to increase the production and stability of key reaction intermediates (OH, HCOO and CO{sub 3}).

Rodriguez, J.A.; Senanayake, S.D.; Stacchiola, D.; Evans, J.; Estrella, M.; Barrio-Pliego, L.; Pérez, M.; Hrbek, J.

2010-05-04T23:59:59.000Z

165

Probing the Reaction Intermediates for the Water–gas Shift over Inverse CeOx / Au(1 1 1) Catalysts  

SciTech Connect (OSTI)

The water-gas shift (WGS) is an important reaction for the production of molecular H{sub 2} from CO and H{sub 2}O. An inverse CeO{sub x}/Au(1 1 1) catalyst exhibits a very good WGS activity, better than that of copper surfaces or Cu nanoparticles dispersed on a ZnO(0 0 0 {bar 1}) substrate which model current WGS industrial catalysts. In this work we report on intermediates likely to arise during the CO + H{sub 2}O reaction over CeO{sub x}/Au(1 1 1) using soft X-ray photoemission (sXPS) and near-edge X-ray absorption fine structure (NEXAFS). Several potential intermediates including formates (HCOO), carbonates (CO{sub 3}) and carboxylates (HOCO) are considered. Adsorption of HCOOH and CO{sub 2} is used to create both HCOO and CO{sub 3} on the CeO{sub x}/Au(1 1 1) surface, respectively. HCOO appears to have greater stability with desorption temperatures up to 600 K while CO{sub 3} only survives on the surface up to 300 K. On the CeO{sub x}/Au(1 1 1) catalysts, the presence of Ce{sup 3+} leads to the dissociation of H{sub 2}O to give OH groups. We demonstrate experimentally that the OH species are stable on the surface up to 600 K and interact with CO to yield weakly bound intermediates. When there is an abundance of Ce{sup 4+}, the OH concentration is diminished and the likely intermediates are carbonates. As the surface defects are increased and the Ce{sup 3+}/Ce{sup 4+} ratio grows, the OH concentration also grows and both carbonate and formate species are observed on the surface after dosing CO to H{sub 2}O/CeO{sub x}/Au(1 1 1). The addition of ceria nanoparticles to Au(1 1 1) is essential to generate an active WGS catalyst and to increase the production and stability of key reaction intermediates (OH, HCOO and CO{sub 3}).

Senanayake, S.; Stacchiola, D; Evans, J; Estrella, M; Barrio, L; Perez, M; Hrbek, J; Rodriguez, J

2010-01-01T23:59:59.000Z

166

Cloud Liquid Water Measurements  

E-Print Network [OSTI]

Pdry ­ Dry Power Term Pwet ­ Wet Power Term P=PdryPwet #12;Dry Power Term Energy is transferred, and temperature PdryC Ts-Ta pv x King et. al, 1981 · C ­ Calibration Constant · x - Calibration Constant · Ts the fact that this model does not pass through (0,0). va=kvx a #12;Calibration Equation Dry Term is: Pdry

Delene, David J.

167

Efficient production of 5-hydroxymethylfurfural through the dehydration of sugars with caprolactam hydrogen sulfate ([CPL]HSO4) ionic liquid catalyst in a water/proprylene glycol monomethyl ether mixed solvent  

Science Journals Connector (OSTI)

Efficient production of 5-hydroxymethylfurfural (HMF) through the dehydration of sugars...4) ionic liquid or using metal halide as the co-catalyst in a new water/proprylene glycol monomethyl ether solvent system....

Pingzhen Huang; Aijuan Gu; Jinxing Wang

2014-04-01T23:59:59.000Z

168

Energetics of Hydrogen Bond Network Rearrangements in Liquid...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Wednesday, 25 May 2005 00:00 The unique...

169

Formation of Liquid Methane-Water Mixture during Combustion of a Laminar Methane Jet at Supercritical Pressures  

E-Print Network [OSTI]

and sometimes exceeding 10 MPa. For example, current aviation gas turbines operate at conditions approaching 4 MPa, and the pressures in the liquid propellant rocket engine combustion chambers may reach up to 20

Gülder, �mer L.

170

Atom Probe Tomography | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atom Probe Tomography Atom Probe Tomography The LEAP 4000 XHR local electrode atom probe tomography instrument enabled the first-ever comprehensive and accurate 3-D chemical...

171

Frostbite Theater - Liquid Nitrogen Experiments - Dry Ice vs. Liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Egg + Liquid Nitrogen + Time-lapse! Egg + Liquid Nitrogen + Time-lapse! Previous Video (Egg + Liquid Nitrogen + Time-lapse!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Cooled Dry Ice in Water!) Liquid Nitrogen Cooled Dry Ice in Water! Dry Ice vs. Liquid Nitrogen! Dry ice is cold. Liquid nitrogen is cold, too. What happens when the two are mixed together? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Have you ever wondered what happens when you mix dry ice and liquid nitrogen? Steve: Well, we just happen to have a chunk of dry ice left over from when we filmed 'How to Make a Cloud Chamber,' and here at Jefferson Lab, liquid nitrogen flows like water, so we're going to find out!

172

750 MHz Radiological NMR Bokan (Liquids, Solids) | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

spectroscopy (in development). The 750-MHz WB system comprises three solid-state NMR probes, four liquid-state probes, and five micro-imaging inserts (see below). In...

173

Design of a Shadowband Spectral Radiometer for the Retrieval of Thin Cloud Optical Depth, Liquid Water Path, and the Effective Radius  

SciTech Connect (OSTI)

The design and operation of a Thin-Cloud Rotating Shadowband Radiometer (TCRSR) described here was used to measure the radiative intensity of the solar aureole and enable the simultaneous retrieval of cloud optical depth, drop effective radius, and liquid water path. The instrument consists of photodiode sensors positioned beneath two narrow metal bands that occult the sun by moving alternately from horizon to horizon. Measurements from the narrowband 415-nm channel were used to demonstrate a retrieval of the cloud properties of interest. With the proven operation of the relatively inexpensive TCRSR instrument, its usefulness for retrieving aerosol properties under cloud-free skies and for ship-based observations is discussed.

Bartholomew M. J.; Reynolds, R. M.; Vogelmann, A. M.; Min, Q.; Edwards, R.; Smith, S.

2011-11-01T23:59:59.000Z

174

Mach flow angularity probes for scramjet engine flow path diagnostics  

SciTech Connect (OSTI)

Mach-flow angularity (MFA) probes were developed for use in scramjet flow path probe rakes. Prototype probes were fabricated to demonstrate the assembly processes (numerical control machining, furnace brazing, and electron beam welding). Tests of prototype probes confirmed the thermal durability margins and life cycle. Selected probes were calibrated in air at Mach numbers from 1.75 to 6.0. Acceptance criteria for the production probes stressed thermal durability and pressure (and, consequently, Mach number) measurement quality. This new water-cooled MFA probe has 0.397-cm shaft diameter and is capable of withstanding heat fluxes of 2.724 kW/sq cm.

Jalbert, P.A.; Hiers, R.S. Jr. [Sverdrup Technology, Inc., Arnold AFS, TN (United States)

1993-12-31T23:59:59.000Z

175

Surfactant-assisted spreading of an oil-in-water emulsion on the surface of a liquid bath  

E-Print Network [OSTI]

This fluid dynamics video shows how an oil-in-water emulsion stabilized by an ionic surfactant spreads on the free surface of a layer of pure water. The spreading shows two intriguing features: a transparent area surrounding the source of oil droplets, and a fast retraction of the layer of oil droplets on itself once the source has emptied. We show that the dynamics of spreading are strongly connected to the interfacial/bulk properties of the surfactant.

Roche, Matthieu; Griffiths, Ian; Saint-Jalmes, Arnaud; Stone, Howard A

2010-01-01T23:59:59.000Z

176

Comparison of Cloud Fraction and Liquid Water Path between ECMWF simulations and ARM long-term Observations at the NSA Site  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

this poster, seasonal and annual variations of this poster, seasonal and annual variations of cloudiness and liquid water path (LWP) from European Center for Medium-Range Weather Forecasts (ECMWF) model were compared with surface measurement from the ARM Climate Research Facility (ARCF) North Slope of Alaska ( N S A ) s i t e b e t we e n J a n u a r y 1 9 9 9 and December 2004. ● Model simulated large scale features match well with observations. ● There are significant differences in cloud vertical and temporal distributions and in the magnitude. FIG. 1: Time-height display of cloud fraction from model simulations and observations in September 1999. ● Model overestimates high clouds, especially in warm seasons. ● Model makes close estimation for middle clouds. ● Model underestimates low clouds in warm seasons, especially in

177

Development of a generalized correlation for phase-velocity measurements obtained from impedance-probe pairs in two-phase flow systems. [PWR  

SciTech Connect (OSTI)

A flag type electrical impedance probe has been developed at the Oak Ridge National Lab (ORNL) to measure liquid- and vapor-phase velocities in steam-water mixtures flowing through rod bundles. Measurements are made by utilizing the probes in pairs, installed in line, parallel to the flow direction, and extending out into the flow channel. The present study addresses performance difficulties by examining from a fundamental point of view the two-phase flow system which the impedance probes typically operate in. Specifically, the governing equations (continuity, momentum, energy) were formulated for both air-water and steam-water systems, and then subjected to a scaling analysis. The scaling analysis yielded the appropriate dimensionless parameters of significance in both kinds of systems. Additionally, with the aid of experimental data obtained at ORNL, those parameters of significant magnitude were established. As a result, a generalized correlation was developed for liquid and vapor phase velocities that makes it possible to employ the impedance probe velocity measurement technique in a wide variety of test configurations and fluid combinations.

Hsu, C.T.; Keshock, E.G.; McGill, R.N.

1983-01-01T23:59:59.000Z

178

Water and Energy Issues in Gas-to-Liquid Processes: Assessment and Integration of Different Gas-Reforming Alternatives  

Science Journals Connector (OSTI)

Energy and water management effects are analyzed for the development of syngas processes under the integration of three gas reforming alternatives ... Gandrick et al.(9) considered the recycling of the light gas from FT synthesis and refining areas to fire gas turbines to produce electricity and the reuse of the gas turbines to produce superheated steam. ... We address in this paper several aspects related to such issues: (a) A comparative analysis is developed for assesing the impact of the use of different reforming technologies on energy and water usage. ...

Diana Yered Martínez; Arturo Jiménez-Gutiérrez; Patrick Linke; Kerron J. Gabriel; Mohamed M. B. Noureldin; Mahmoud M. El-Halwagi

2013-10-24T23:59:59.000Z

179

Solid-Phase Extraction Combined with High-Performance Liquid Chromatography?Atmospheric Pressure Chemical Ionization?Mass Spectrometry Analysis of Pesticides in Water:? Method Performance and Application in a Reconnaissance Survey of Residues in Drinking Water in Greater Cairo, Egypt  

Science Journals Connector (OSTI)

Solid-Phase Extraction Combined with High-Performance Liquid Chromatography?Atmospheric Pressure Chemical Ionization?Mass Spectrometry Analysis of Pesticides in Water:? Method Performance and Application in a Reconnaissance Survey of Residues in Drinking Water in Greater Cairo, Egypt ... Each shipment, which included 24 cartridges, weighed <454 g and cost approximately 200 Egyptian pounds ($40 U.S.). ...

Thomas L. Potter; Mahmoud A. Mohamed; Hannah Ali

2006-12-22T23:59:59.000Z

180

Parameterization of GDL Liquid Water Front Propagation and Channel Accumulation for Anode Purge Scheduling in Fuel Cells  

E-Print Network [OSTI]

. I. INTRODUCTION Water produced at the cathode catalyst layer can diffuse back to the anode side due of the catalyst support in the cathode [4]. Therefore, scheduling an occasional purge of the anode volume that was observed via neutron imaging of an operational 53 cm2 PEMFC. Simulation results for the GDL and Membrane

Stefanopoulou, Anna

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

ESTABLISHMENT OF A METHOD FOR 222RN DETERMINATION IN WATER BY LOW-LEVEL LIQUID SCINTILLATION COUNTER  

Science Journals Connector (OSTI)

......region, northern part of Serbia: it includes Novi Sad-the capital city of Vojvodina with 400 000 inhabitants, and Fruska Gora...because of numerous underground hot springs and sources of natural gas, as well as some crude oil reservoirs(6). The water samples......

Nataša Todorovi?; Ivana Jakoni?; Jovana Nikolov; Jan Hansman; Miroslav Veskovi?

2014-07-01T23:59:59.000Z

182

Electric field and humidity effects on adsorbed water behavior on BaTiO3 ferroelectric domains studied by scanning probe microscopy  

E-Print Network [OSTI]

Electric field and humidity effects on adsorbed water behavior on BaTiO3 ferroelectric domains 2014; published online 28 August 2014) Distribution of the adsorbed water on BaTiO3 ferroelectric, which adsorb on the material surface, cause delayed cracking and fracture of ferroelectric ceramics.15

Volinsky, Alex A.

183

1.2 What pressure difference must be generated across the length of a 15 cm vertical drinking straw in order to drink a water-like liquid of density 1.0 g cm-3  

E-Print Network [OSTI]

in order to drink a water-like liquid of density 1.0 g cm-3 ? 1.6 Charles' law is sometimes expressed1.2 What pressure difference must be generated across the length of a 15 cm vertical drinking straw

Findley, Gary L.

184

Hydrodynamic ultrasonic probe  

DOE Patents [OSTI]

An improved probe for in-service ultrasonic inspection of long lengths of a workpiece, such as small diameter tubing from the interior. The improved probe utilizes a conventional transducer or transducers configured to inspect the tubing for flaws and/or wall thickness variations. The probe utilizes a hydraulic technique, in place of the conventional mechanical guides or bushings, which allows the probe to move rectilinearly or rotationally while preventing cocking thereof in the tube and provides damping vibration of the probe. The probe thus has lower friction and higher inspection speed than presently known probes.

Day, Robert A. (Livermore, CA); Conti, Armond E. (San Jose, CA)

1980-01-01T23:59:59.000Z

185

Nanoparticle diffusion probing of the structure of water and aqueous organic solutions near a porous surface and in its bulk in a wide temperature interval  

Science Journals Connector (OSTI)

Scattering of laser radiation by nanoparticles (latex balls and silver nanoparticles) is investigated in a wide temperature interval. It is demonstrated that water is structured near the porous surface of a solid...

V. V. Bryukhanov; I. G. Samusev; A. M. Ivanov; N. A. Myslitskaya

2009-02-01T23:59:59.000Z

186

Numerical Simulation of Hydrodynamics of a Heavy Liquid Drop Covered by Vapor Film in a Water Pool  

SciTech Connect (OSTI)

A numerical study on the hydrodynamics of a droplet covered by vapor film in water pool is carried out. Two level set functions are used as to implicitly capture the interfaces among three immiscible fluids (melt-drop, vapor and coolant). This approach leaves only one set of conservation equations for the three phases. A high-order Navier-Stokes solver, called Cubic-Interpolated Pseudo-Particle (CIP) algorithm, is employed in combination with level set approach, which allows large density ratios (up to 1000), surface tension and jump in viscosity. By this calculation, the hydrodynamic behavior of a melt droplet falling into a volatile coolant is simulated, which is of great significance to reveal the mechanism of steam explosion during a hypothetical severe reactor accident. (authors)

Ma, W.M.; Yang, Z.L.; Giri, A.; Sehgal, B.R. [Royal Institute of Technology (KTH), Drottning Kristinas vaeg 33 A, 100 44, Stockholm (Sweden)

2002-07-01T23:59:59.000Z

187

Reading Comprehension - Liquid Nitrogen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquid Nitrogen Liquid Nitrogen Nitrogen is the most common substance in Earth's _________ crust oceans atmosphere trees . In the Earth's atmosphere, nitrogen is a gas. The particles of a gas move very quickly. They run around and bounce into everyone and everything. The hotter a gas is, the _________ slower faster hotter colder the particles move. When a gas is _________ cooled warmed heated compressed , its particles slow down. If a gas is cooled enough, it can change from a gas to a liquid. For nitrogen, this happens at a very _________ strange warm low high temperature. If you want to change nitrogen from a gas to a liquid, you have to bring its temperature down to 77 Kelvin. That's 321 degrees below zero _________ Kelvin Celsius Centigrade Fahrenheit ! Liquid nitrogen looks like water, but it acts very differently. It

188

Viscosity of liquid Fe at high pressure  

Science Journals Connector (OSTI)

Synchrotron x-ray radiography has been used to measure the viscosity of pure liquid Fe at high pressure and temperature in a large volume press. A probe sphere rising through liquid Fe at high pressure and temperature is imaged, in situ, allowing for the derivation of sample viscosity through a modified form of Stokes’ equation. The effect of pressure on viscosity is fit by the semi empirical framework for transport coefficients in liquid metals, providing experimental verification of constant viscosity at the pressure-dependent melting temperature of liquid Fe where no change in liquid structure occurs.

Michael D. Rutter; Richard A. Secco; Hongjian Liu; Takeyuki Uchida; Mark L. Rivers; Stephen R. Sutton; Yanbin Wang

2002-08-14T23:59:59.000Z

189

MagLab Audio Dictionary: Probe  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probe? Now Playing: What's a Probe? Enable Javascript and Flash to stream the Magnet Minute Greg Boebinger Associated Links Meet the Probes What's a Probe? Probe Development for...

190

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freeze the Rainbow! Freeze the Rainbow! Previous Video (Freeze the Rainbow!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and Fire!) Liquid Nitrogen and Fire! Liquid Nitrogen and Antifreeze! What happens when the freezing power of liquid nitrogen meets the antifreezing power of ethylene glycol? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: What happens when the freezing power of liquid nitrogen... Steve: ...meets the antifreezing power of ethylene glycol! Joanna: While a mix of 70 percent ethylene glycol and 30 percent water doesn't freeze until 60 degrees below zero, it's still no match for liquid nitrogen. At 321 degrees below zero, liquid nitrogen easily freezes

191

Bubbly Flow Experiment in Channel Using an Optical Probe and Tracking Algorithm  

E-Print Network [OSTI]

communication between the computer and optoelectronic unit. The probe takes advantage of the physics between two mediums, air and water (Fig. 8). The optical fiber, manufactured from glass, relays the signal in the probe. Internal reflection allows...

Khan, Abdul

2012-10-19T23:59:59.000Z

192

Orifice mixing of immiscible liquids  

E-Print Network [OSTI]

measured with an Ostwald Viscosimeter relative to tap water also, All of these physical measurements were made at 83c F, the average tempera- ture noted during the runs. The liquid upon which these measurements were made were samples of the liquids...

McDonough, Joseph Aloysius

1960-01-01T23:59:59.000Z

193

ARM - Measurement - Liquid water content  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

MicrowaveImager (SSMI): Satellite 14 SSMI15 : Special Sensor MicrowaveImager (SSMI): Satellite 15 Datastreams ECMWFDIAG : European Centre for Medium Range Weather Forecasts...

194

ARM - Measurement - Liquid water path  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cloud Products Using Visst Algorithm PRECIPRET : Precipitation Retrievals WRF-CHEM : Weather Research and Forecasting (WRF) Model Output Value-Added Products MWRAVG :...

195

Closed-field capacitive liquid level sensor  

DOE Patents [OSTI]

A liquid level sensor based on a closed field circuit comprises a ring oscillator using a symmetrical array of plate units that creates a displacement current. The displacement current varies as a function of the proximity of a liquid to the plate units. The ring oscillator circuit produces an output signal with a frequency inversely proportional to the presence of a liquid. A continuous liquid level sensing device and a two point sensing device are both proposed sensing arrangements. A second set of plates may be located inside of the probe housing relative to the sensing plate units. The second set of plates prevent any interference between the sensing plate units.

Kronberg, J.W.

1995-01-01T23:59:59.000Z

196

Three-Phase Vapor?Liquid?Liquid Equilibria for Methane + n-Octane + Monoethylene Glycol + Water at Pressures from (3.1 to 15.0) MPa and Temperatures from (281 to 363) K  

Science Journals Connector (OSTI)

There are several commercial processes available for the dehydration of gas, such as the use of liquid or solid desiccants and expansion refrigeration. ... The gaseous part of the liquid samples, and the gas phase samples direct from the equilibrium cell, were expanded into a series of evacuated vessels of known volume from which the total amount of substance was determined from the perfect gas equation using the measured low-pressure PVT data. ... To predict the losses of MEG in processes for the dehydration of natural gas, the concentrations of MEG in the vapor phase are of interest to the gas industry. ...

Stanley J. Ashcroft; Gerd Brunner; Hansjörg Vollmer; Christopher W. Sweeney

2009-03-06T23:59:59.000Z

197

Probing Mercury's Partnering Preferences  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Preferences Probing Mercury's Partnering Preferences Merc.gif Why it Matters: Mercury (Hg) is a major global pollutant arising from both natural and anthropogenic sources....

198

Probing metal solidification nondestructively  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting and...

199

Probing metal solidification nondestructively  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting...

200

Spinon-phonon interaction in algebraic spin liquids  

E-Print Network [OSTI]

Motivated by a search for experimental probes to access the physics of fractionalized excitations called spinons in spin liquids, we study the interaction of spinons with lattice vibrations. We consider the case of algebraic ...

Serbyn, Maksym

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Freezing of a Liquid Marble  

E-Print Network [OSTI]

In this study, we present for the first time the observations of a freezing liquid marble. In the experiment, liquid marbles are gently placed on the cold side of a Thermo-Electric Cooler (TEC) and the morphological changes are recorded and characterized thereafter. These liquid marbles are noticed to undergo a shape transition from a spherical to a flying-saucer shaped morphology. The freezing dynamics of liquid marbles is observed to be very different from that of a freezing water droplet on a superhydrophobic surface. For example, the pointy tip appearing on a frozen water drop could not be observed for a frozen liquid marble. In the end, we highlight a possible explanation for the observed morphology.

Ali Hashmi; Adam Strauss; Jie Xu

2012-07-03T23:59:59.000Z

202

Enrichment and Determination of Trace Estradiol in Environmental Water Samples by Hollow-Fiber Liquid-Phase Microextraction Prior to HPLC  

Science Journals Connector (OSTI)

......samples were sur- face water collected from the...immersed in the aqueous water. The extraction...dryness at 90 C under nitrogen gas for about 20 min...were performed in water at an estradiol concentration...should have a low solubility in water and non-volatile......

Haixia Li; Ye Jiang; Yan Liu

2011-10-01T23:59:59.000Z

203

The relationship between local liquid density and force applied on a tip of atomic force microscope: A theoretical analysis for simple liquids  

SciTech Connect (OSTI)

The density of a liquid is not uniform when placed on a solid. The structured liquid pushes or pulls a probe employed in atomic force microscopy, as demonstrated in a number of experimental studies. In the present study, the relation between the force on a probe and the local density of a liquid is derived based on the statistical mechanics of simple liquids. When the probe is identical to a solvent molecule, the strength of the force is shown to be proportional to the vertical gradient of ln(?{sub DS}) with the local liquid's density on a solid surface being ?{sub DS}. The intrinsic liquid's density on a solid is numerically calculated and compared with the density reconstructed from the force on a probe that is identical or not identical to the solvent molecule.

Amano, Ken-ichi, E-mail: aman@tohoku-pharm.ac.jp; Takahashi, Ohgi [Faculty of Pharmaceutical Sciences, Tohoku Pharmaceutical University, 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558 (Japan)] [Faculty of Pharmaceutical Sciences, Tohoku Pharmaceutical University, 4-4-1 Komatsushima, Aoba-ku, Sendai 981-8558 (Japan); Suzuki, Kazuhiro [Department of Electronic Science and Engineering, Kyoto University, Katsura, Nishikyo, Kyoto 615-8510 (Japan)] [Department of Electronic Science and Engineering, Kyoto University, Katsura, Nishikyo, Kyoto 615-8510 (Japan); Fukuma, Takeshi [Bio-AFM Frontier Research Center, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan)] [Bio-AFM Frontier Research Center, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan); Onishi, Hiroshi [Department of Chemistry, Faculty of Science, Kobe University, Nada-ku, Kobe 657-8501 (Japan)] [Department of Chemistry, Faculty of Science, Kobe University, Nada-ku, Kobe 657-8501 (Japan)

2013-12-14T23:59:59.000Z

204

EMSL - liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquids en Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 °C. http:www.emsl.pnl.govemslwebpublicationsiodine-solubility-low-activity-waste-borosilicate...

205

Soft X-ray emission spectroscopy of liquids and lithium batterymaterials  

SciTech Connect (OSTI)

Lithium ion insertion into electrode materials is commonly used in rechargeable battery technology. The insertion implies changes in both the crystal structure and the electronic structure of the electrode material. Side-reactions may occur on the surface of the electrode which is exposed to the electrolyte and form a solid electrolyte interface (SEI). The understanding of these processes is of great importance for improving battery performance. The chemical and physical properties of water and alcohols are complicated by the presence of strong hydrogen bonding. Various experimental techniques have been used to study geometrical structures and different models have been proposed to view the details of how these liquids are geometrically organized by hydrogen bonding. However, very little is known about the electronic structure of these liquids, mainly due to the lack of suitable experimental tools. In this thesis examples of studies of lithium battery electrodes and liquid systems using soft x-ray emission spectroscopy will be presented. Monochromatized synchrotron radiation has been used to accomplish selective excitation, in terms of energy and polarization. The electronic structure of graphite electrodes has been studied, before and after lithium intercalation. Changes in the electronic structure upon lithiation due to transfer of electrons into the graphite {pi}-bands have been observed. Transfer of electrons in to the 3d states of transition metal oxides upon lithiation have been studied, through low energy excitations as dd- and charge transfer-excitations. A SEI was detected on cycled graphite electrodes. By the use of selective excitation different carbon sites were probed in the SEI. The local electronic structure of water, methanol and mixtures of the two have been examined using a special liquid cell, to separate the liquid from the vacuum in the experimental chamber. Results from the study of liquid water showed a strong influence on the 3a1 molecular orbital and orbital mixing between water molecules upon hydrogen bonding. Apart from the four-hydrogen-bonding structure in water, a structure where one hydrogen bond is broken could be separated and identified. The soft x-ray emission study of methanol showed the existence of ring and chain formations in the liquid phase and the dominating structures are formed of 6 and 8 molecules. Upon mixing of the two liquids, a segregation at the molecular level was found and the formation of new structures, which could explain the unexpected low increase of the entropy.

Augustsson, Andreas

2004-10-27T23:59:59.000Z

206

Structure and dynamics of liquid water on rutile TiO2(110) Li-Min Liu, Changjun Zhang, Geoff Thornton, and Angelos Michaelides  

E-Print Network [OSTI]

those between water and titanium dioxide TiO2 . Water-TiO2 interfaces are relevant to photocatalysis on which adsorption state the water molecules are in at the interface: dissociated or molecular? Many, density-functional theory DFT studies predict either molecular or dissociative adsorption on the perfect

Alavi, Ali

207

Chemical sensing flow probe  

DOE Patents [OSTI]

A new chemical probe determines the properties of an analyte using the light absorption of the products of a reagent/analyte reaction. The probe places a small reaction volume in contact with a large analyte volume. Analyte diffuses into the reaction volume. Reagent is selectively supplied to the reaction volume. The light absorption of the reaction in the reaction volume indicates properties of the original analyte. The probe is suitable for repeated use in remote or hostile environments. It does not require physical sampling of the analyte or result in significant regent contamination of the analyte reservoir.

Laguna, George R. (Albuquerque, NM); Peter, Frank J. (Albuquerque, NM); Butler, Michael A. (Albuquerque, NM)

1999-01-01T23:59:59.000Z

208

ccsd00001732, Development behavior of liquid plasma produced by  

E-Print Network [OSTI]

water with a melted NaCl is used as a test liquid. The liquid plasma is produced by the fundamental waveccsd­00001732, version 2 ­ 7 Nov 2004 Development behavior of liquid plasma produced by YAG laser the hazardous material called the environment material. Then, the plasma produced in liquid by the laser light

209

Spiers Memorial Lecture Recent experimental advances in studies of liquid/liquid  

E-Print Network [OSTI]

complicated processes such as molecular transport across cell membranes. A variety of techniques have been on the interaction of a hydrophobic surface with water, and ion and solute transport across these and other liquid/hydrophilic properties of liquid/ liquid interfaces. In biological systems, protein folding and membrane formation rely

Richmond, Geraldine L.

210

The gridded electromagnet probe  

E-Print Network [OSTI]

We attempted to measure the anisotropy in the electron distribution function in magnetized plasma by exploiting the adiabatic invariance of the electron's magnetic moment with a probe comprising a grid, a collector, and ...

Shadman, K. (Khashayar), 1972-

2003-01-01T23:59:59.000Z

211

Sorptive extraction using polydimethylsiloxane/metal–organic framework coated stir bars coupled with high performance liquid chromatography-fluorescence detection for the determination of polycyclic aromatic hydrocarbons in environmental water samples  

Science Journals Connector (OSTI)

Abstract In this work, metal–organic frameworks (MOFs, Al-MIL-53-NH2) were synthesized via the hydrothermal method, and novel polydimethylsiloxane/metal–organic framework (PDMS/MOFs, PDMS/Al-MIL-53-NH2)-coated stir bars were prepared by the sol–gel technique. The preparation reproducibility of the PDMS/MOFs-coated stir bar was good, with relative standard deviations (RSDs) ranging from 4.8% to 14.9% (n = 7) within one batch and from 6.2% to 16.9% (n = 6) among different batches. Based on this fact, a new method of PDMS/MOFs-coated stir bar sorptive extraction (SBSE) and ultrasonic-assisted liquid desorption (UALD) coupled with high performance liquid chromatography-fluorescence detection (HPLC-FLD) was developed for the determination of polycyclic aromatic hydrocarbons (PAHs) in environmental water samples. To obtain the best extraction performance for PAHs, several parameters affecting SBSE, such as extraction time, stirring rate, and extraction temperature, were investigated. Under optimal experimental conditions, wide linear ranges and good \\{RSDs\\} (n = 7) were obtained. With enrichment factors (EFs) of 16.1- to 88.9-fold (theoretical EF, 142-fold), the limits of detection (LODs, S/N = 3) of the developed method for the target \\{PAHs\\} were found to be in the range of 0.05–2.94 ng/L. The developed method was successfully applied to the analysis of \\{PAHs\\} in Yangtze River and East Lake water samples.

Cong Hu; Man He; Beibei Chen; Cheng Zhong; Bin Hu

2014-01-01T23:59:59.000Z

212

LNG liquid-liquid immiscibility  

SciTech Connect (OSTI)

Although natural gas species rarely exhibit liquid-liquid immiscibility in binary systems, the presence of additional components can extend the domain of immiscibility in those few binary systems where it already exists or produce immiscibility in binary systems where it had not existed. If the solute has the proper molecular relation to the solvent mixture background, liquid-liquid-vapor (LLV) behavior will occur; such phenomena greatly complicate the design of LNG processing equipment. To aid LNG engineers, researchers mapped the thermodynamic behavior of four ternary LLV systems and examined the effects of the second solvents - ethane, propane, n-butane, and CO/sub 2/ - on the binary methane + n-octane system.

Luks, K.D.; Kohn, J.P.

1981-09-01T23:59:59.000Z

213

Ionic Liquids as Green Solvents for Alkylation and Acylation  

Science Journals Connector (OSTI)

Many clean solvents like water, ionic liquids, supercritical fluid, polyglycol, fluorine-containing solvents, and so on are employed to replace the conventional organic solvents. Among these, ionic liquids have a...

Zhongkui Zhao; Yitao Dai

2012-01-01T23:59:59.000Z

214

Convective heat flow probe  

DOE Patents [OSTI]

A convective heat flow probe device is provided which measures heat flow and fluid flow magnitude in the formation surrounding a borehole. The probe comprises an elongate housing adapted to be lowered down into the borehole; a plurality of heaters extending along the probe for heating the formation surrounding the borehole; a plurality of temperature sensors arranged around the periphery of the probe for measuring the temperature of the surrounding formation after heating thereof by the heater elements. The temperature sensors and heater elements are mounted in a plurality of separate heater pads which are supported by the housing and which are adapted to be radially expanded into firm engagement with the walls of the borehole. The heat supplied by the heater elements and the temperatures measured by the temperature sensors are monitored and used in providing the desired measurements. The outer peripheral surfaces of the heater pads are configured as segments of a cylinder and form a full cylinder when taken together. A plurality of temperature sensors are located on each pad so as to extend along the length and across the width thereof, with a heating element being located in each pad beneath the temperature sensors. An expansion mechanism driven by a clamping motor provides expansion and retraction of the heater pads and expandable packet-type seals are provided along the probe above and below the heater pads.

Dunn, J.C.; Hardee, H.C.; Striker, R.P.

1984-01-09T23:59:59.000Z

215

Two-phase air-water stratified flow measurement using ultrasonic techniques  

SciTech Connect (OSTI)

In this paper, a time resolved ultrasound system was developed for investigating two-phase air-water stratified flow. The hardware of the system includes a pulsed wave transducer, a pulser/receiver, and a digital oscilloscope. The time domain cross correlation method is used to calculate the velocity profile along ultrasonic beam. The system is able to provide velocities with spatial resolution of around 1mm and the temporal resolution of 200?s. Experiments were carried out on single phase water flow and two-phase air-water stratified flow. For single phase water flow, the flow rates from ultrasound system were compared with those from electromagnetic flow (EM) meter, which showed good agreement. Then, the experiments were conducted on two-phase air-water stratified flow and the results were given. Compared with liquid height measurement from conductance probe, it indicated that the measured velocities were explainable.

Fan, Shiwei; Yan, Tinghu; Yeung, Hoi [School of Engineering, Cranfield University, Cranfield, Bedfordshire MK43 0AL (United Kingdom)

2014-04-11T23:59:59.000Z

216

Ultrafast Core-Hole Induced Dynamics in Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ultrafast Core-Hole Induced Dynamics in Water Print Ultrafast Core-Hole Induced Dynamics in Water Print A thorough understanding of the chemical processes that are initiated when radiation interacts with aqueous systems is essential for many diverse fields, from condensed matter physics to medicine to environmental science. An incoming photon with enough energy to produce a core hole in a water molecule sets off motions that can affect bonding configurations, which in turn affect subsequent chemical-reaction pathways. However, it is a fundamental challenge for the radiation chemistry community to unravel the early time dynamics of electronically excited states in water because their short (femtosecond) time scales are difficult to access directly with pump-probe measurements. Using a combination of isotope substitution experiments and molecular dynamics simulations, researchers from Sweden, Germany, and the U.S. have shown that the ultrafast (0- to 10-fs) dissociation dynamics of liquid water can be successfully probed with x-ray emission spectroscopy.

217

Ultrafast Core-Hole Induced Dynamics in Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ultrafast Core-Hole Induced Ultrafast Core-Hole Induced Dynamics in Water Ultrafast Core-Hole Induced Dynamics in Water Print Wednesday, 22 February 2006 00:00 A thorough understanding of the chemical processes that are initiated when radiation interacts with aqueous systems is essential for many diverse fields, from condensed matter physics to medicine to environmental science. An incoming photon with enough energy to produce a core hole in a water molecule sets off motions that can affect bonding configurations, which in turn affect subsequent chemical-reaction pathways. However, it is a fundamental challenge for the radiation chemistry community to unravel the early time dynamics of electronically excited states in water because their short (femtosecond) time scales are difficult to access directly with pump-probe measurements. Using a combination of isotope substitution experiments and molecular dynamics simulations, researchers from Sweden, Germany, and the U.S. have shown that the ultrafast (0- to 10-fs) dissociation dynamics of liquid water can be successfully probed with x-ray emission spectroscopy.

218

Ultrafast Core-Hole Induced Dynamics in Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ultrafast Core-Hole Induced Dynamics in Water Print Ultrafast Core-Hole Induced Dynamics in Water Print A thorough understanding of the chemical processes that are initiated when radiation interacts with aqueous systems is essential for many diverse fields, from condensed matter physics to medicine to environmental science. An incoming photon with enough energy to produce a core hole in a water molecule sets off motions that can affect bonding configurations, which in turn affect subsequent chemical-reaction pathways. However, it is a fundamental challenge for the radiation chemistry community to unravel the early time dynamics of electronically excited states in water because their short (femtosecond) time scales are difficult to access directly with pump-probe measurements. Using a combination of isotope substitution experiments and molecular dynamics simulations, researchers from Sweden, Germany, and the U.S. have shown that the ultrafast (0- to 10-fs) dissociation dynamics of liquid water can be successfully probed with x-ray emission spectroscopy.

219

Ultrafast Core-Hole Induced Dynamics in Water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ultrafast Core-Hole Induced Dynamics in Water Print Ultrafast Core-Hole Induced Dynamics in Water Print A thorough understanding of the chemical processes that are initiated when radiation interacts with aqueous systems is essential for many diverse fields, from condensed matter physics to medicine to environmental science. An incoming photon with enough energy to produce a core hole in a water molecule sets off motions that can affect bonding configurations, which in turn affect subsequent chemical-reaction pathways. However, it is a fundamental challenge for the radiation chemistry community to unravel the early time dynamics of electronically excited states in water because their short (femtosecond) time scales are difficult to access directly with pump-probe measurements. Using a combination of isotope substitution experiments and molecular dynamics simulations, researchers from Sweden, Germany, and the U.S. have shown that the ultrafast (0- to 10-fs) dissociation dynamics of liquid water can be successfully probed with x-ray emission spectroscopy.

220

Water Rock Interaction [WRI 14] Macroscopic thermodynamics of interfaces at the water pore  

E-Print Network [OSTI]

they should be relevant. 2. Liquid-air interfacial curvature Capillary water in non-saturated porous system 7327, BP 36009, 45060 Orléans, France Abstract The possible role of liquid-air and solid-liquid (liquid-air concave curvature toward air), and curved solid as a function of pore sizes (solid-liquid

Boyer, Edmond

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Multispectral imaging probe  

DOE Patents [OSTI]

A multispectral imaging probe delivers a range of wavelengths of excitation light to a target and collects a range of expressed light wavelengths. The multispectral imaging probe is adapted for mobile use and use in confined spaces, and is sealed against the effects of hostile environments. The multispectral imaging probe comprises a housing that defines a sealed volume that is substantially sealed from the surrounding environment. A beam splitting device mounts within the sealed volume. Excitation light is directed to the beam splitting device, which directs the excitation light to a target. Expressed light from the target reaches the beam splitting device along a path coaxial with the path traveled by the excitation light from the beam splitting device to the target. The beam splitting device directs expressed light to a collection subsystem for delivery to a detector. 8 figs.

Sandison, D.R.; Platzbecker, M.R.; Descour, M.R.; Armour, D.L.; Craig, M.J.; Richards-Kortum, R.

1999-07-27T23:59:59.000Z

222

Multispectral imaging probe  

DOE Patents [OSTI]

A multispectral imaging probe delivers a range of wavelengths of excitation light to a target and collects a range of expressed light wavelengths. The multispectral imaging probe is adapted for mobile use and use in confined spaces, and is sealed against the effects of hostile environments. The multispectral imaging probe comprises a housing that defines a sealed volume that is substantially sealed from the surrounding environment. A beam splitting device mounts within the sealed volume. Excitation light is directed to the beam splitting device, which directs the excitation light to a target. Expressed light from the target reaches the beam splitting device along a path coaxial with the path traveled by the excitation light from the beam splitting device to the target. The beam splitting device directs expressed light to a collection subsystem for delivery to a detector.

Sandison, David R. (Moriarty, NM); Platzbecker, Mark R. (Albuquerque, NM); Descour, Michael R. (Tucson, AZ); Armour, David L. (Albuquerque, NM); Craig, Marcus J. (Albuquerque, NM); Richards-Kortum, Rebecca (Austin, TX)

1999-01-01T23:59:59.000Z

223

Nuclear quantum effects in water  

E-Print Network [OSTI]

In this work, a path integral Car-Parrinello molecular dynamics simulation of liquid water is performed. It is found that the inclusion of nuclear quantum effects systematically improves the agreement of first principles simulations of liquid water with experiment. In addition, the proton momentum distribution is computed utilizing a recently developed open path integral molecular dynamics methodology. It is shown that these results are in good agreement with neutron Compton scattering data for liquid water and ice.

Joseph A. Morrone; Roberto Car

2008-03-25T23:59:59.000Z

224

Fireside corrosion probes for fossil fuel combustion  

SciTech Connect (OSTI)

Electrochemical corrosion rate probes have been constructed and tested along with mass loss coupons in environments consisting of N2/O2/CO2/SO2 plus water vapor. Temperatures ranged from 450° to 700°C. Results show that electrochemical corrosion rates for ash-covered mild steel are a function of time, temperature, and gaseous environment. Correlation between the electrochemical and mass loss corrosion rates was poor.

Covino, B.S., Jr.; Bullard, S.J.; Ziomek-Moroz, M.; Holcomb, G.R.; Eden, D.A. (Intercorr International, Houston, TX)

2006-03-01T23:59:59.000Z

225

Properties of liquid marbles BY PASCALE AUSSILLOUS  

E-Print Network [OSTI]

it evaporates). A water marble can even be transferred at the surface of a water pool on which it does temperature, which permits the conservation of biological samples. Thus, liquid marbles could be relevant, and stress their relative robustness. 2. Principles Two water marbles are shown in figure 1

Aussillous, Pascale

226

Frostbite Theater - Liquid Nitrogen Experiments - Insulators!  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Popping Film Canisters! Popping Film Canisters! Previous Video (Popping Film Canisters!) Frostbite Theater Main Index Next Video (Liquid Nitrogen Show!) Liquid Nitrogen Show! Insulators! Cups full of water are placed into bowls of liquid nitrogen! Which cup will insulate the best? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a container of liquid nitrogen! Steve: And these are two plastic cups! Joanna: Let's see which cup is the better insulator! Steve: Okay! So, um, how do we do that? Joanna: Well, we'll pour water into each of the cups and then we'll pour the liquid nitrogen into each of the bowls. If we then place the cup in the bowl, the heat from the water will try to pass through the cup into the

227

Haze Formation and Behavior in Liquid-Liquid Extraction Processes  

SciTech Connect (OSTI)

Aqueous haze formation and behavior was studied in the liquid-liquid system tri-n-butyl phosphate in odorless kerosene and 3M nitric acid with uranyl nitrate and cesium nitrate representing the major solute and an impurity, respectively. A pulsed column, mixer-settler and centrifugal contactor were chosen to investigate the effect of different turbulence characteristics on the manifestation of haze since these contactors exhibit distinct mixing phenomena. The dispersive processes of drop coalescence and breakage, and water precipitation in the organic phase were observed to lead to the formation of haze drops of {approx}1 um in diameter. The interaction between the haze and primary drops of the dispersion was critical to the separation efficiency of the liquid-liquid extraction equipment. Conditions of high power input and spatially homogeneous mixing enabled the haze drops to become rapidly assimilated within the dispersion to maximize the scrub performance and separation efficiency of the equipment.

Arm, Stuart T.; Jenkins, J. A.

2006-07-31T23:59:59.000Z

228

Water Management in A PEMFC: Water Transport Mechanism and Material  

E-Print Network [OSTI]

Water Management in A PEMFC: Water Transport Mechanism and Material Degradation in Gas Diffusion on the water management of the PEMFC, namely the transport of product water (both liquid and vapor its water management performance and func- tion as indicators of the degradation of GDL material

Kandlikar, Satish

229

Vibrational Energy Relaxation of Thiocyanate Ions in Liquid-to-Supercritical Light and Heavy Water. A Fermi’s Golden Rule Analysis  

Science Journals Connector (OSTI)

As was discussed above, the solute stretching excitation is resonantly transferred to the bending–librational combination level (direct V–VR), and the energy transfer decelerates because the solvent acceptor level experiences an energetic downshift upon isobaric heating, thereby gradually lifting the solute–solvent resonance. ... Clearly, this infrared activity cannot correspond to the (?b + ?L) band of heavy water because the bending–librational combination tone should shift to lower energies with increasing temperature as it does for light water (see the absorption edge at 2300 cm–1 in Figure 4a). ...

Denis Czurlok; Jeannine Gleim; Jörg Lindner; Peter Vöhringer

2014-09-15T23:59:59.000Z

230

Acidic ionic liquid/water solution as both medium and proton source for electrocatalytic H2 evolution by [Ni(P2N2)2]2+ complexes  

Science Journals Connector (OSTI)

...by passage through a water/oxygen/hydrocarbon trap S7 (Restek 22464) and an...Atlantic Microlab Inc. using V2O5 as a combustion catalyst. Electrochemical Methods...portions. After the first addition, heat was evolved and a white vapor formed...

Douglas H. Pool; Michael P. Stewart; Molly O’Hagan; Wendy J. Shaw; John A. S. Roberts; R. Morris Bullock; Daniel L. DuBois

2012-01-01T23:59:59.000Z

231

Acidic ionic liquid/water solution as both medium and proton source for electrocatalytic H2 evolution by [Ni(P2N2)2]2+ complexes  

Science Journals Connector (OSTI)

...regressions use the data shown with...water/oxygen/hydrocarbon trap S7...using V2O5 as a combustion catalyst. Electrochemical...Fc+ /Fc couple. Data from t = 0.038...first addition, heat was evolved and a...6], so only the data with [6] spanning...

Douglas H. Pool; Michael P. Stewart; Molly O’Hagan; Wendy J. Shaw; John A. S. Roberts; R. Morris Bullock; Daniel L. DuBois

2012-01-01T23:59:59.000Z

232

H atom probes of radiation chemistry: Solids and liquids  

SciTech Connect (OSTI)

H atoms are ubiquitous in radiation chemistry. Radiolysis of most substances yield H atoms and studies of the mechanisms of their production are as old as the field of radiation chemistry. The problem is that study or products does not easily reveal the chemical mechanisms involved even with the clever use of isotopes. Time-resolved pulsed electron paramagnetic resonance (EPR) was used to study formation and decay kinetics of spin-polarized mobile H atoms in radiolysis of wet fused silica containing {approximately} 1,200 ppm of SiOH groups. Two reactions of H atoms can be distinguished: a slow component corresponding to scavenging of H atoms by metastable paramagnetic centers and a fast component which is ascribed to a reaction of a short-lived small polaron (intrinsic hole) with H atoms.

Trifunac, A.D.; Shkrob, I.A. [Argonne National Lab., IL (United States). Chemistry Div.

1998-12-31T23:59:59.000Z

233

2.1 What Does Life Water on Earth  

E-Print Network [OSTI]

1 2.1 What Does Life Require? Water Water on Earth Can exist in all 3 physical states Liquid Solid Gas Not all animals must drink liquid water. Can get water from food. Can get water through metabolism of glucose. Water on Earth Source % of Supply Oceans 97.08 Ice Sheets and Glaciers 1.99 Ground

Cochran-Stafira, D. Liane

234

Dark Energy Probes of Dark Energy  

E-Print Network [OSTI]

19/12/2013 1 Dark Energy Probes of Dark Energy Probes Dark Energy Supernovae Ia probing luminosity (Betti numbers) #12;19/12/2013 2 Dark Energy Probes: Comparison Method Strengths Weaknesses Systematics

Weijgaert, Rien van de

235

Liquid electrode  

DOE Patents [OSTI]

A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

Ekechukwu, A.A.

1994-07-05T23:59:59.000Z

236

Sewage sludge dewatering using flowing liquid metals  

DOE Patents [OSTI]

A method and apparatus for reducing the moisture content of a moist sewage sludge having a moisture content of about 50% to 80% and formed of small cellular micro-organism bodies having internally confined water is provided. A hot liquid metal is circulated in a circulation loop and the moist sewage sludge is injected in the circulation loop under conditions of temperature and pressure such that the confined water vaporizes and ruptures the cellular bodies. The vapor produced, the dried sludge, and the liquid metal are then separated. Preferably, the moist sewage sludge is injected into the hot liquid metal adjacent the upstream side of a venturi which serves to thoroughly mix the hot liquid metal and the moist sewage sludge. The venturi and the drying zone after the venturi are preferably vertically oriented. The dried sewage sludge recovered is available as a fuel and is preferably used for heating the hot liquid metal.

Carlson, Larry W. (Oswego, IL)

1986-01-01T23:59:59.000Z

237

Bubble departure in the direct-contact boiling field with a continuous liquid-liquid interface  

SciTech Connect (OSTI)

Behavior of vapor bubbles was experimentally investigated in the boiling field where a volatile liquid layer of per-fluorocarbon PF5050 (boiling point 306K) was directly in contact with an immiscible hot liquid layer of water above it. Heat was supplied to the continuous liquid-liquid interface by the impingement of the downward hot water jet. Vapor bubbles were generated not only from this continuous interface but from a large number of PF5050 droplets floating on it. According to precise observation, incipience of boiling did not occur at the liquid-liquid interface but in the PF5050 liquid close to the interface in both cases of continuous and dispersed interfaces. As a result, the bubbles broke up the thin PF5050 liquid film above them and rose up into the water layer. This bubble departure phenomenon, which does not occur in the ordinary pool boiling field on the solid heating wall, is very important to evaluate the heat transfer performance in the present direct-contact boiling system. For modeling this behavior, sizes of the bubbles were measured at the moment just after they were released into the water pool. Volumes of the bubbles were larger in the case of departing from the continuous liquid-liquid interface than from the droplets. This tendency could be explained by taking into account the buoyancy force acting on unit area of the thin PF5050 liquid film above the bubble before departure, which was one of the most important parameters for the liquid film breakdown. (author)

Kadoguchi, Katsuhiko [Energy Technology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 16-1 Onogawa, Tsukuba, Ibaraki 305-8569 (Japan)

2007-01-15T23:59:59.000Z

238

Electromagnetic Probes in PHENIX  

E-Print Network [OSTI]

Electromagnetic probes are arguably the most universal tools to study the different physics processes in high energy hadron and heavy ion collisions. In this paper we summarize recent measurements of real and virtual direct photons at central rapidity by the PHENIX experiment at RHIC in p+p, d+Au and Au+Au collisions. We also discuss the impact of the results and the constraints they put on theoretical models. At the end we report on the immediate as well as on the mid-term future of photon measurements at RHIC.

Gabor David

2006-09-21T23:59:59.000Z

239

Techniques for geothermal liquid sampling and analysis  

SciTech Connect (OSTI)

A methodology has been developed that is particularly suited to liquid-dominated resources and adaptable to a variety of situations. It is intended to be a base methodology upon which variations can be made to meet specific needs or situations. The approach consists of recording flow conditions at the time of sampling, a specific insertable probe sampling system, a sample stabilization procedure, commercially available laboratory instruments, and data quality check procedures.

Kindle, C.H.; Woodruff, E.M.

1981-07-01T23:59:59.000Z

240

Guidance Document Cryogenic Liquids  

E-Print Network [OSTI]

Guidance Document Cryogenic Liquids [This is a brief and general summary. Read the full MSDS for more details before handling.] Introduction: All cryogenic liquids are gases at normal temperature liquefies them. Cryogenic liquids are kept in the liquid state at very low temperatures. Cryogenic liquids

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Training: Probing Solar Photoconversion Using Flash-Photolysis Time-Resolved Microwave Conductivity (FP-TRMC)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing Probing solar photoconversion using flash---photolysis 6 me--- resolved microwave conduc6vity (FP---TRMC) Chemical & Nanosciences Group Chemical & Materials Science Center NREL is a na*onal laboratory of the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, operated by the Alliance for Sustainable Energy, LLC. TRMC users ๏ PI: Garry Rumbles ๏ Current users - Rebecca Callahan (liquid crystal donor materials) - Ryan Crisp (semiconductor NC

242

EPR investigations of phase transitions in amphiphilic systems using hydrophilic spin probes  

E-Print Network [OSTI]

1653 EPR investigations of phase transitions in amphiphilic systems using hydrophilic spin probes D technique de sonde EPR a été utilisée pour étudier les transitions coagel-gel et gel-cristal liquide dans de phase est observée à ~ 120 °C. Abstract. - The EPR spin probe technique was used to study coagel

Paris-Sud XI, Université de

243

Self-Assembly of Microscale Objects at a Liquid/Liquid Interface through Lateral Capillary Forces  

E-Print Network [OSTI]

Self-Assembly of Microscale Objects at a Liquid/Liquid Interface through Lateral Capillary Forces allowed to self-assemble at the perfluorodecalin/water interface. These plates were fabricated from, the designs of hydrophobic edges necessary to generate menisci useful in self-assembly were different for 100

Prentiss, Mara

244

Quantification of feather structure, wettability and resistance to liquid penetration  

Science Journals Connector (OSTI)

...wettability and resistance to liquid penetration Siddarth Srinivasan 1 Shreerang...liquid droplets that retard the rate of drying of the wet plumage...repellency and resistance to water penetration. Wilson J. Ornithol. 122...WA Jesser. 2011 The water penetration and repellency of feathers...

2014-01-01T23:59:59.000Z

245

Reorientation of the ‘free OH’ group in the top-most layer of air/water interface of sodium fluoride aqueous solution probed with sum-frequency generation vibrational spectroscopy  

SciTech Connect (OSTI)

Many experimental and theoretical studies have established the specific anion, as well as cation effects on the hydrogen-bond structures at the air/water interface of electrolyte solutions. However, the ion effects on the top-most layer of the air/water interface, which is signified by the non-hydrogen-bonded so-called ‘free O-H’ group, has not been discussed or studied. In this report, we present the measurement of changes of the orientational angle of the ‘free O-H’ group at the air/water interface of the sodium fluoride (NaF) solutions at different concentrations using the interface selective sum-frequency generation vibrational spectroscopy (SFG-VS) in the ssp and ppp polarizations. The polarization dependent SFG-VS results show that the average tilt angle of the ‘free O-H’ changes from about 35.3 degrees ± 0.5 degrees to 43.4 degrees ± 2.1degrees as the NaF concentration increase from 0 to 0.94M (nearly saturated). Such tilt angle change is around the axis of the other O-H group of the same water molecule at the top-most layer at the air/water interface that is hydrogen-bonded to the water molecules below the top-most layer. These results provide quantitative molecular details of the ion effects of the NaF salt on the structure of the water molecules at the top-most layer of the air/water interfacial, even though both the Na+ cation and the F- anion are believed to be among the most excluded ions from the air/water interface.

Feng, Ran-Ran; Guo, Yuan; Wang, Hongfei

2014-09-17T23:59:59.000Z

246

Vibrational Density of States of Strongly H-Bonded Interfacial Water: Insights from Inelastic Neutron Scattering and Theory  

SciTech Connect (OSTI)

The vibrational dynamics of water and OH sorbed on SnO2 nanoparticles were probed with inelastic neutron scattering and analyzed with the assistance of ab-initio molecular dynamics. The combined analysis points to the existence of very strong hydrogen bonds at the surface with a formation enthalpy twice the average value for liquid water. This unusually large interaction results in (i) decoupling of the hydrated surface from the water system due to an epitaxially-induced screening layer, resulting in an apparent ice-like INS signal at multilayer coverage, (ii) splitting of OH wagging modes that can be used as an experimental indication of the strength of the surface hydrogen bonds, and (iii) high proton exchange rates and high degree of water dissociation at the interface. Our analysis provides general guidance into the tuning of surface hydrophobicity at the molecular level.

Wang, Hsiu-Wen [ORNL; Dellostritto, Mark J [ORNL; Kumar, Nitin [ORNL; Kolesnikov, Alexander I [ORNL; Kent, Paul R [ORNL; Kubicki, James D. [Pennsylvania State University; Wesolowski, David J [ORNL; Sofo, Jorge O. [Pennsylvania State University

2014-01-01T23:59:59.000Z

247

Trapping and Probing Antihydrogen  

SciTech Connect (OSTI)

Precision spectroscopy of antihydrogen is a promising path to sensitive tests of CPT symmetry. The most direct route to achieve this goal is to create and probe antihydrogen in a magnetic minimum trap. Antihydrogen has been synthesized and trapped for 1000s at CERN by the ALPHA Collaboration. Some of the challenges associated with achieving these milestones will be discussed, including mixing cryogenic positron and antiproton plasmas to synthesize antihydrogen with kinetic energy less than the trap potential of .5K. Recent experiments in which hyperfine transitions were resonantly induced with microwaves will be presented. The opportunity for gravitational measurements in traps based on detailed studies of antihydrogen dynamics will be described. The talk will conclude with a discussion future antihydrogen research that will use a new experimental apparatus, ALPHA-I.

Wurtele, Jonathan [UC Berkeley and LBNL

2013-03-27T23:59:59.000Z

248

High temperature electrochemical corrosion rate probes for combustion environments  

SciTech Connect (OSTI)

Electrochemical corrosion rate probes have been constructed and tested along with mass loss coupons in an air plus water vapor and a N2/O2/CO2 plus water vapor environment. Temperatures ranged from 200? to 700?C. Results show that electrochemical corrosion rates for ash-covered mild steel are a function of time, temperature and process environment. Correlation between the electrochemical and mass loss corrosion rates was poor.

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, Margaret; Eden, David A. (Intercorr International Inc.); Kane, Russell D. (Intercorr International Inc.); Eden, Dawn C. (Intercorr International Inc.)

2004-01-01T23:59:59.000Z

249

2010 Water & Aqueous Solutions  

SciTech Connect (OSTI)

Water covers more than two thirds of the surface of the Earth and about the same fraction of water forms the total mass of a human body. Since the early days of our civilization water has also been in the focus of technological developments, starting from converting it to wine to more modern achievements. The meeting will focus on recent advances in experimental, theoretical, and computational understanding of the behavior of the most important and fascinating liquid in a variety of situations and applications. The emphasis will be less on water properties per se than on water as a medium in which fundamental dynamic and reactive processes take place. In the following sessions, speakers will discuss the latest breakthroughs in unraveling these processes at the molecular level: Water in Solutions; Water in Motion I and II; Water in Biology I and II; Water in the Environment I and II; Water in Confined Geometries and Water in Discussion (keynote lecture and poster winners presentations).

Dor Ben-Amotz

2010-08-13T23:59:59.000Z

250

Review of state of the art methods for measuring water in landfills  

SciTech Connect (OSTI)

In recent years several types of sensors and measurement techniques have been developed for measuring the moisture content, water saturation, or the volumetric water content of landfilled wastes. In this work, we review several of the most promising techniques. The basic principles behind each technique are discussed and field applications of the techniques are presented, including cost estimates. For several sensors, previously unpublished data are given. Neutron probes, electrical resistivity (impedance) sensors, time domain reflectometry (TDR) sensors, and the partitioning gas tracer technique (PGTT) were field tested with results compared to gravimetric measurements or estimates of the volumetric water content or moisture content. Neutron probes were not able to accurately measure the volumetric water content, but could track changes in moisture conditions. Electrical resistivity and TDR sensors tended to provide biased estimates, with instrument-determined moisture contents larger than independent estimates. While the PGTT resulted in relatively accurate measurements, electrical resistivity and TDR sensors provide more rapid results and are better suited for tracking infiltration fronts. Fiber optic sensors and electrical resistivity tomography hold promise for measuring water distributions in situ, particularly during infiltration events, but have not been tested with independent measurements to quantify their accuracy. Additional work is recommended to advance the development of some of these instruments and to acquire an improved understanding of liquid movement in landfills by application of the most promising techniques in the field.

Imhoff, Paul T. [Department of Civil and Environmental Engineering, University of Delaware, Newark, DE 19716 (United States)], E-mail: imhoff@udel.edu; Reinhart, Debra R. [Department of Civil and Environmental Engineering, University of Central Florida, Orlando, FL 32816-2450 (United States); Englund, Marja [Fortum Service Ltd., P.O. Box 10, FIN-00048, Fortum (Finland); Guerin, Roger [Universite Pierre et Marie Curie-Paris 6, UMR 7619 Sisyphe, case courrier 105, 4 place Jussieu, 75252 Paris cedex 05 (France); Gawande, Nitin [Department of Civil and Environmental Engineering, University of Central Florida, Orlando, FL 32816-2450 (United States); Han, Byunghyun [Department of Civil and Environmental Engineering, University of Delaware, Newark, DE 19716 (United States); Jonnalagadda, Sreeram; Townsend, Timothy G. [Civil and Environmental Engineering Sciences Department, Gainesville, FL 32609 (United States); Yazdani, Ramin [Planning, Resources, and Public Works Department, Division of Integrated Waste Management, 292 West Beamer Street, Woodland, CA 95695 (United States)

2007-07-01T23:59:59.000Z

251

Alien liquid detector and control  

SciTech Connect (OSTI)

An alien liquid detector employs a monitoring element and an energizing circuit for maintaining the temperature of the monitoring element substantially above ambient temperature. For this purpose an electronic circit controls a flow of heating current to the monitoring element. The presence of an alien liquid is detected by sensing a predetermined change in heating current flow to the monitoring element, e.g., to distinguish between water and oil. In preferred embodiments the monitoring element is a thermistor whose resistance is compared with a reference resistance and heating current through the thermistor is controlled in accordance with the difference. In one embodiment a bridge circuit senses the resistance difference; the difference may be sensed by an operational amplifier arrangement. Features of the invention include positioning the monitoring element at the surface of water, slightly immersed, so that the power required to maintain the thermistor temperature substantially above ambient temperature serves to detect presence of oil pollution at the surface.

Potter, B.M.

1980-09-02T23:59:59.000Z

252

Rotating concave eddy current probe  

DOE Patents [OSTI]

A rotating concave eddy current probe for detecting fatigue cracks hidden from view underneath the head of a raised head fastener, such as a buttonhead-type rivet, used to join together structural skins, such as aluminum aircraft skins. The probe has a recessed concave dimple in its bottom surface that closely conforms to the shape of the raised head. The concave dimple holds the probe in good alignment on top of the rivet while the probe is rotated around the rivet's centerline. One or more magnetic coils are rigidly embedded within the probe's cylindrical body, which is made of a non-conducting material. This design overcomes the inspection impediment associated with widely varying conductivity in fastened joints.

Roach, Dennis P. (Albuquerque, NM); Walkington, Phil (Albuquerque, NM); Rackow, Kirk A. (Albuquerque, NM); Hohman, Ed (Albuquerque, NM)

2008-04-01T23:59:59.000Z

253

Frostbite Theater - Liquid Oxygen vs. Liquid Nitrogen - Liquid Oxygen and  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cells vs. Liquid Nitrogen! Cells vs. Liquid Nitrogen! Previous Video (Cells vs. Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Paramagnetism) Paramagnetism Liquid Oxygen and Fire! What happens when nitrogen and oxygen are exposed to fire? [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: And this is a test tube of liquid nitrogen! Steve: And this is a test tube of liquid oxygen! Joanna: Let's see what happens when nitrogen and oxygen are exposed to fire. Steve: Fire?! Joanna: Yeah! Steve: Really?! Joanna: Why not! Steve: Okay! Joanna: As nitrogen boils, it changes into nitrogen gas. Because it's so cold, it's denser than the air in the room. The test tube fills up with

254

Water preheater system  

SciTech Connect (OSTI)

A heat transfer liquid collects heat in a solar collector and transfers the heat to water in a preheater heat exchanger. Use of a negative-pressure collector by means of an ejector and pressure relief valve allows inexpensive and readily available materials to be used in the collector. Preferably, the preheat heat exchanger is a converted gas hot water heater in which the heat transfer liquid is sprayed onto a portion of the storage tank and is collected in a reservoir. The negative-pressure solar collector can also be used to heat swimming pool water.

Dunstan, Ph.E.

1985-03-12T23:59:59.000Z

255

Safetygram #9- Liquid Hydrogen  

Broader source: Energy.gov [DOE]

Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

256

Conducted Electrical Weapon Deployed Probe Wounds  

Science Journals Connector (OSTI)

Deployment of probes is a common method of use for some handheld conducted electrical weapons (CEWs). Probe deployment allows for greater...

Donald M. Dawes M.D.; Jeffrey D. Ho M.D.

2012-01-01T23:59:59.000Z

257

Probing Organic Transistors with Infrared Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing Organic Transistors with Infrared Beams Probing Organic Transistors with Infrared Beams Print Wednesday, 26 July 2006 00:00 Silicon-based transistors are well-understood,...

258

Solar probe technology challenges  

Science Journals Connector (OSTI)

A mission close to the sun is only possible if new spacecraft technologies can be developed and incorporated into a state?of?the?art spacecraft concept. The perihelion goal of 4 solar radii requires a shielded spacecraft that can tolerate the almost 3000 suns solar flux while maintaining the electronics components at room temperature. In addition the shield surface should sublimate at a rate of less than 3mg/s at perihelion. Many shield configuration designs have been studied and the most promising is a parabolic shape that functions as both a shield and a large high gain antenna. The shield material chosen for this design is a carbon?carbon material with highly emissive surface properties. A mission requirement for a high telecommunications power stems from the expected interference when attempting to transmit data through the solar corona. It is expected that the large carbon?carbon shield/antenna will have a high power gain even at high temperatures and will return adequate telemetry at the X?band radio frequency chosen for the Solar Probe mission. Other key technology needs include a non?nuclear power subsystem that can function in the extreme environments of the mission from Earth to Jupiter and onward to a 4 solar radii perihelion.

James E. Randolph; Robert N. Miyake; Bill J. Nesmith; Ray B. Dirling Jr.; Richard J. Howard

1996-01-01T23:59:59.000Z

259

Long duration ash probe  

DOE Patents [OSTI]

A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during sootblowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon.

Hurley, John P. (Grand Forks, ND); McCollor, Don P. (Grand Forks, ND); Selle, Stanley J. (Grand Forks, MN)

1994-01-01T23:59:59.000Z

260

Long duration ash probe  

DOE Patents [OSTI]

A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during soot blowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon. 8 figs.

Hurley, J.P.; McCollor, D.P.; Selle, S.J.

1994-07-26T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Exact probes of orientifolds  

E-Print Network [OSTI]

We compute the exact vacuum expectation value of circular Wilson loops for Euclidean ${\\cal N}=4$ super Yang-Mills with $G=SO(N),Sp(N)$, in the fundamental and spinor representations. These field theories are dual to type IIB string theory compactified on $AdS_5\\times {\\mathbb R} {\\mathbb P}^5$ plus certain choices of discrete torsion, and we use our results to probe this holographic duality. We first revisit the LLM-type geometries having $AdS_5\\times {\\mathbb R} {\\mathbb P}^5$ as ground state. Our results clarify and refine the identification of these LLM-type geometries as bubbling geometries arising from fermions on a half harmonic oscillator. We furthermore identify the presence of discrete torsion with the one-fermion Wigner distribution becoming negative at the origin of phase space. We then turn to the string world-sheet interpretation of our results and argue that for the quantities considered they imply two features: first, the contribution coming from world-sheets with a single crosscap is closely ...

Fiol, Bartomeu; Torrents, Genis

2014-01-01T23:59:59.000Z

262

Differential probes aid flow measurement  

SciTech Connect (OSTI)

Nonconstricting differential pressure flow probes which help solve the problems of clogging, wear, and pressure loss at the Seawater Filtration Facility in Saudi Arabia are described. Treated seawater is pumped into oil-bearing formations for secondary recovery. Figures showing principle of operation for probes, installation schematic and long-term accuracy results (flow probes vs. orifice meters) are presented. The new diamond-shaped design flow sensor offers accurate flow measurement with low permanent pressure loss, which translates into cost savings for the operator.

Mesnard, D.R.

1982-07-01T23:59:59.000Z

263

Optic probe for semiconductor characterization  

DOE Patents [OSTI]

Described herein is an optical probe (120) for use in characterizing surface defects in wafers, such as semiconductor wafers. The optical probe (120) detects laser light reflected from the surface (124) of the wafer (106) within various ranges of angles. Characteristics of defects in the surface (124) of the wafer (106) are determined based on the amount of reflected laser light detected in each of the ranges of angles. Additionally, a wafer characterization system (100) is described that includes the described optical probe (120).

Sopori, Bhushan L. (Denver, CO); Hambarian, Artak (Yerevan, AM)

2008-09-02T23:59:59.000Z

264

Water's Hydrogen Bond Strength  

E-Print Network [OSTI]

Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

Martin Chaplin

2007-06-10T23:59:59.000Z

265

Liquid soap film generates electricity  

E-Print Network [OSTI]

We have observed that a rotating liquid soap film generates electricity when placed between two non-contact electrodes with a sufficiently large potential difference. In our experiments suspended liquid film (water + soap film) is formed on the surface of a circular frame, which is forced to rotate in the $x-y$ horizontal plane by a motor. This system is located at the center of two capacitor-like vertical plates to apply an external electric voltage difference in the $x-$direction. The produced electric current is collected from the liquid film using two conducting electrodes that are separated in the $y-$direction. We previously reported that a liquid film in an external electric field rotates when an electric current passes through it, naming it the liquid film motor (LFM). In this paper we report a novel technique, in which a similar device can be used as an electric generator, converting the rotating mechanical energy to electrical energy. The liquid film electric generator (LFEG) is in stark contrast to the LFM, both of which could be designed similarly in very small scales like micro scales with different applications. Although the device is comparable to commercial electric motors or electric generators, there is a significant difference in their working principles. Usually in an electric motor or generator the magnetic field causes the driving force, while in a LFM or LFEG the Coulomb force is the driving force. This fact is also interesting from the Bio-science point of view and brings a similarity to bio motors. Here we have investigated the electrical characteristics of such a generator for the first time experimentally and modelled the phenomenon with electroconvection governing equations. A numerical simulation is performed using the local approximation for the charge-potential relation and results are in qualitative agreement with experiments.

Ahmad Amjadi; Sadegh Feiz; Reza Montazeri Namin

2014-04-24T23:59:59.000Z

266

PDF Rotating Probe VW Dwg  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

7.350 PDF Rotating Probe Drawing 45 T 32 mm bore Top Loading into mixture dilution refrigerator 30 mK< T < 900 mK Heater & Thermometer location 24 pin SIP connector BeCu Spring...

267

Switchable stiffness scanning microscope probe  

E-Print Network [OSTI]

Atomic Force Microscopy (AFM) has rapidly gained widespread utilization as an imaging device and micro/nano-manipulator during recent years. This thesis investigates the new concept of a dual stiffness scanning probe with ...

Mueller-Falcke, Clemens T. (Clemens Tobias)

2005-01-01T23:59:59.000Z

268

President's panel probes sustainable development  

Science Journals Connector (OSTI)

President's panel probes sustainable development ... The President's Council on Sustainable Development, a blue-ribbon advisory panel established by President Bill Clinton last June, held its first meeting outside the nation's capital earlier this month in the Seattle. ...

DEBORAH ILLMAN

1994-01-31T23:59:59.000Z

269

Electrokinetic Hydrogen Generation from Liquid Water Microjets  

E-Print Network [OSTI]

Electrochemical hydrogen production methods are quiteonly causative hydrogen production method. Although the massa method for the production of molecular hydrogen from

Duffin, Andrew M.; Saykally, Richard J.

2007-01-01T23:59:59.000Z

270

Electrokinetic Hydrogen Generation from Liquid Water Microjets  

E-Print Network [OSTI]

currents and hydrogen production rates are shown to followmolecules. The hydrogen production efficiency is currentlycurrently available hydrogen production routes that can be

Duffin, Andrew M.; Saykally, Richard J.

2007-01-01T23:59:59.000Z

271

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for low pressure boilers. A boiler tank, from which apor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, Albert P. (Vernon, CT)

1986-01-01T23:59:59.000Z

272

Liquid level detector  

DOE Patents [OSTI]

A liquid level detector for low pressure boilers. A boiler tank, from which vapor, such as steam, normally exits via a main vent, is provided with a vertical side tube connected to the tank at the desired low liquid level. When the liquid level falls to the level of the side tube vapor escapes therethrough causing heating of a temperature sensitive device located in the side tube, which, for example, may activate a liquid supply means for adding liquid to the boiler tank. High liquid level in the boiler tank blocks entry of vapor into the side tube, allowing the temperature sensitive device to cool, for example, to ambient temperature.

Grasso, A.P.

1984-02-21T23:59:59.000Z

273

Water quality Water quantity  

E-Print Network [OSTI]

01-1 · Water quality · Water quantity · Remediation strategies MinE 422: Water Resources: Younger, Banwart and Hedin. 2002. Mine Water. Hydrology, Pollution, Remediation. Impacts of mining on water mining ­ Often the largest long term issue ­ Water quality affected, surface/ground water pollution

Boisvert, Jeff

274

Water quality Water quantity  

E-Print Network [OSTI]

· Water quality · Water quantity · Remediation strategies MinE 422: Water Resources: Younger, Banwart and Hedin. 2002. Mine Water. Hydrology, Pollution, Remediation. Impacts of mining on water mining ­ Often the largest long term issue ­ Water quality affected, surface/ground water pollution

Boisvert, Jeff

275

Liquid-Liquid Transition at Tg and Stable-Glass Phase Nucleation Rate Maximum at the Kauzmann Temperature TK  

E-Print Network [OSTI]

An undercooled liquid is unstable. The driving force of the glass transition at Tg is a change of the undercooled-liquid Gibbs free energy. The classical Gibbs free energy change for a crystal formation is completed including an enthalpy saving. The crystal growth critical nucleus is used as a probe to observe the Laplace pressure change Dp accompanying the enthalpy change -Vm*Dp at Tg where Vm is the molar volume. A stable glass-liquid transition model predicts the specific heat jump of fragile liquids at temperatures smaller than Tg, the Kauzmann temperature TK where the liquid entropy excess with regard to crystal goes to zero, the equilibrium enthalpy between TK and Tg, the maximum nucleation rate at TK of superclusters containing magic atom numbers, and the equilibrium latent heats at Tg and TK. Strong-to-fragile and strong-to-strong liquid transitions at Tg are also described and all their thermodynamic parameters are determined from their specific heat jumps. The existence of fragile liquids quenched in the amorphous state, which do not undergo liquid-liquid transition during heating preceding their crystallization, is predicted. Long ageing times leading to the formation at TK of a stable glass composed of superclusters containing up to 147 atoms, touching and interpenetrating, are evaluated from nucleation rates.

Robert Felix Tournier

2014-04-10T23:59:59.000Z

276

Interface for liquid chromatograph-mass spectrometer  

DOE Patents [OSTI]

A moving belt interface for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer.

Andresen, Brian D. (Pleasanton, CA); Fought, Eric R. (Livermore, CA)

1989-01-01T23:59:59.000Z

277

Interface for liquid chromatograph-mass spectrometer  

DOE Patents [OSTI]

A moving belt interface is described for real-time, high-performance liquid chromatograph (HPLC)/mass spectrometer (MS) analysis which strips away the HPLC solvent as it emerges from the end of the HPLC column and leaves a residue suitable for mass-spectral analysis. The interface includes a portable, stand-alone apparatus having a plural stage vacuum station, a continuous ribbon or belt, a drive train magnetically coupled to an external drive motor, a calibrated HPLC delivery system, a heated probe tip and means located adjacent the probe tip for direct ionization of the residue on the belt. The interface is also capable of being readily adapted to fit any mass spectrometer. 8 figs.

Andresen, B.D.; Fought, E.R.

1989-09-19T23:59:59.000Z

278

Liquid Piston Stirling Engines  

Science Journals Connector (OSTI)

The Fluidyne liquid piston engine is a simple free-piston Stirling engine that can be made from nothing more...

Graham Walker Ph. D.; J. R. Senft Ph.D.

1985-01-01T23:59:59.000Z

279

Some Functions of Bacteria in the Purification of Polluted Water  

Science Journals Connector (OSTI)

...failed. 528 BACTERIA AND PURIFICATION OF WATER dilute media. This finding...unusual natural 530 BACTERIA AND PURIFICATION OF WATER environment or by artificial...concen- 532 BACTERIA AND PURIFICATION OF WATER 533 tration in liquid media...

C. T. Butterfield

1940-05-01T23:59:59.000Z

280

Rotary union for use with ultrasonic thickness measuring probe  

DOE Patents [OSTI]

A rotary union for rotatably supporting an ultrasonic probe operable to nondestructively measure the thickness of steam generator tubes to determine the amount of corrosion experienced by the tubes includes a stationary body having a bore therethrough and an outlet drain, and a fitting rotatably mounted within the upper end of the body. The fitting has a bore aligned with the bore of the body. An electrical cable positioned within a water supply tube in an annular arrangement passes through the bore of the body and the bore of the fitting. This annular arrangement, in turn, is positioned within a connector element which extends outwardly from the fitting bore and is connected to the ultrasonic probe. An elastomeric lower bushing seals the annular arrangement to the lower end of the rotary union body and an elastomeric upper bushing seals the connector element to the fitting to permit the connector element and the ultrasonic probe connected thereto to rotate with the fitting relative to the body. The lower and upper bushings permit water to be passed through the annular arrangement and into the ultrasonic probe and thereafter discharged between the annular arrangement and the connector element to the outlet drain of the rotary union body. 5 figs.

Nachbar, H.D.

1992-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Imaging Density Disturbances in Water with a 41.3-Attosecond Time Resolution  

Science Journals Connector (OSTI)

We show that the momentum flexibility of inelastic x-ray scattering may be exploited to invert its loss function, allowing real time imaging of density disturbances in a medium. We show the disturbance arising from a point source in liquid water, with a resolution of 41.3 attoseconds (4.13×10-17???s) and 1.27???Å (1.27×10-8???cm). This result is used to determine the structure of the electron cloud around a photoexcited chromophore in solution, as well as the wake generated in water by a 9 MeV gold ion. We draw an analogy with pump-probe techniques and suggest that energy-loss scattering may be applied more generally to the study of attosecond phenomena.

P. Abbamonte; K. D. Finkelstein; M. D. Collins; S. M. Gruner

2004-06-11T23:59:59.000Z

282

Short Time Dynamics of Ionic Liquids in AIMD-Based Power Spectra  

Science Journals Connector (OSTI)

Short Time Dynamics of Ionic Liquids in AIMD-Based Power Spectra ... A Car-Parrinello study of 1-ethyl-3-methyl-imidazolium chloride water mixture ...

Katharina Wendler; Martin Brehm; Friedrich Malberg; Barbara Kirchner; Luigi Delle Site

2012-04-04T23:59:59.000Z

283

OIL DROPLET MANIPULATION USING LIQUID DIELECTROPHORESIS ON ELECTRET WITH SUPERLYOPHOBIC  

E-Print Network [OSTI]

OIL DROPLET MANIPULATION USING LIQUID DIELECTROPHORESIS ON ELECTRET WITH SUPERLYOPHOBIC SURFACES flow friction for water and oil. Charge stability of electret in liquid is much improved with new hysteresis of SLS for oil droplets are experimentally demonstrated, indicating low motion resistance

Kasagi, Nobuhide

284

Definition: Liquid natural gas | Open Energy Information  

Open Energy Info (EERE)

Liquid natural gas Liquid natural gas Jump to: navigation, search Dictionary.png Liquid natural gas Natural gas (primarily methane) that has been liquefied by reducing its temperature to -260 degrees Fahrenheit at atmospheric pressure.[1] View on Wikipedia Wikipedia Definition Liquefied natural gas or LNG is natural gas that has been converted to liquid form for ease of storage or transport. Liquefied natural gas takes up about 1/600th the volume of natural gas in the gaseous state. It is odorless, colorless, non-toxic and non-corrosive. Hazards include flammability after vaporization into a gaseous state, freezing and asphyxia. The liquefaction process involves removal of certain components, such as dust, acid gases, helium, water, and heavy hydrocarbons, which could cause difficulty downstream. The natural gas is then condensed into a

285

Argonne CNM: Proximal Probes Capabilities  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Proximal Probes Proximal Probes Capabilities Omicron VT-AFM XA microscope scanning tunneling microscope VIew high-resolution image. Variable-temperature, ultra-high-vacuum, atomic force microscope/scanning tunneling microscope: Omicron VT-AFM XA (N. Guisinger, Electronic & Magnetic Materials & Devices Group) Measurement modes include: Contact and non-contact AFM Magnetic force microscopy (MFM) Scanning tunneling spectroscopy Preparation tools include: Resistive sample heating Direct current heating E-beam heating Sputter ion etching Gas dosing E-beam evaporation An analysis chamber contains combined four-grid LEED/Auger optics Omicron nanoprobe View high-resolution image Scanning probe/scanning electron microscopy: Omicron UHV Nanoprobe (N. Guisinger, Electronic & Magnetic Materials & Devices Group)

286

Hand-held survey probe  

DOE Patents [OSTI]

A system for providing operational feedback to a user of a detection probe may include an optical sensor to generate data corresponding to a position of the detection probe with respect to a surface; a microprocessor to receive the data; a software medium having code to process the data with the microprocessor and pre-programmed parameters, and making a comparison of the data to the parameters; and an indicator device to indicate results of the comparison. A method of providing operational feedback to a user of a detection probe may include generating output data with an optical sensor corresponding to the relative position with respect to a surface; processing the output data, including comparing the output data to pre-programmed parameters; and indicating results of the comparison.

Young, Kevin L. (Idaho Falls, ID) [Idaho Falls, ID; Hungate, Kevin E. (Idaho Falls, ID) [Idaho Falls, ID

2010-02-23T23:59:59.000Z

287

Designing liquid repellent surfaces for fabrics, feathers and fog  

E-Print Network [OSTI]

Omniphobicity refers to a property of surfaces which are not wetted by water, oils, alcohols and other low surface tension liquids. Robust omniphobic surfaces can be applied in many areas including fabrics with chemical / ...

Chhatre, Shreerang S. (Shreerang Sharad)

2013-01-01T23:59:59.000Z

288

Boiling and condensation in a liquid-filled enclosure  

E-Print Network [OSTI]

A combined experimental and analytical investigation of boiling and condensation in a liquid-filled enclosure, with water and Freon- 113 as the working fluids, is described. The operating characteristics of a boiling system, ...

Bar-Cohen Avram

1971-01-01T23:59:59.000Z

289

Alkyl Chain Ordering of Asymmetric Phosphatidylcholines Adsorbed at a Liquid-Liquid B. L. Smiley and G. L. Richmond*  

E-Print Network [OSTI]

Alkyl Chain Ordering of Asymmetric Phosphatidylcholines Adsorbed at a Liquid-Liquid Interface B. L chain ordering in phosphatidylcholines (PCs) adsorbed from aqueous solution to a carbon tetrachloride-dimensional phases are discussed. Introduction Surfactant monolayers adsorbed at oil-water interfaces in biological

Richmond, Geraldine L.

290

Polarity Programmed Gas-Liquid Chromatography  

Science Journals Connector (OSTI)

......component on the carrier gas, is investigated...component of the carrier gas. Introduction One...strength, i.e., the solubility of the solute in...temperature programming in gas-liquid chromatography...of carrier gas for nitrogen, helium, methane...of other solutes. Water vapor or steam are......

Jon F. Parcher; Theodore N. Westlake

1976-07-01T23:59:59.000Z

291

The Properties of Liquid Ethane and Propane  

Science Journals Connector (OSTI)

... of Liebig's Annalen. Owing to the greater ease with which it undergoes liquefaction, propane was first investigated. The hydrocarbon was obtained in a state of purity by means ... transferred to a gas-holder over water In order to determine the boiling-point of propane, the purified gas was first condensed to the liquid state in a U-tube ...

A. E. TUTTON

1894-11-15T23:59:59.000Z

292

Liquid Wall Chambers  

SciTech Connect (OSTI)

The key feature of liquid wall chambers is the use of a renewable liquid layer to protect chamber structures from target emissions. Two primary options have been proposed and studied: wetted wall chambers and thick liquid wall (TLW) chambers. With wetted wall designs, a thin layer of liquid shields the structural first wall from short ranged target emissions (x-rays, ions and debris) but not neutrons. Various schemes have been proposed to establish and renew the liquid layer between shots including flow-guiding porous fabrics (e.g., Osiris, HIBALL), porous rigid structures (Prometheus) and thin film flows (KOYO). The thin liquid layer can be the tritium breeding material (e.g., flibe, PbLi, or Li) or another liquid metal such as Pb. TLWs use liquid jets injected by stationary or oscillating nozzles to form a neutronically thick layer (typically with an effective thickness of {approx}50 cm) of liquid between the target and first structural wall. In addition to absorbing short ranged emissions, the thick liquid layer degrades the neutron flux and energy reaching the first wall, typically by {approx}10 x x, so that steel walls can survive for the life of the plant ({approx}30-60 yrs). The thick liquid serves as the primary coolant and tritium breeding material (most recent designs use flibe, but the earliest concepts used Li). In essence, the TLW places the fusion blanket inside the first wall instead of behind the first wall.

Meier, W R

2011-02-24T23:59:59.000Z

293

Sliding Luttinger liquid phases  

Science Journals Connector (OSTI)

We study systems of coupled spin-gapped and gapless Luttinger liquids. First, we establish the existence of a sliding Luttinger liquid phase for a system of weakly coupled parallel quantum wires, with and without disorder. It is shown that the coupling can stabilize a Luttinger liquid phase in the presence of disorder. We then extend our analysis to a system of crossed Luttinger liquids and establish the stability of a non-Fermi-liquid state: the crossed sliding Luttinger liquid phase. In this phase the system exhibits a finite-temperature, long-wavelength, isotropic electric conductivity that diverges as a power law in temperature T as T?0. This two-dimensional system has many properties of a true isotropic Luttinger liquid, though at zero temperature it becomes anisotropic. An extension of this model to a three-dimensional stack exhibits a much higher in-plane conductivity than the conductivity in a perpendicular direction.

Ranjan Mukhopadhyay; C. L. Kane; T. C. Lubensky

2001-07-09T23:59:59.000Z

294

Water Cooling | Open Energy Information  

Open Energy Info (EERE)

Cooling: Cooling: Water cooling is commonly defined as a method of using water as a heat conduction to remove heat from an object, machine, or other substance by passing cold water over or through it. In energy generation, water cooling is typically used to cool steam back into water so it can be used again in the generation process. Other definitions:Wikipedia Reegle Water Cooling Typical water cooled condenser used for condensing steam Water or liquid cooling is the most efficient cooling method and requires the smallest footprint when cold water is readily available. When used in power generation the steam/vapor that exits the turbine is condensed back into water and reused by means of a heat exchanger. Water cooling requires a water resource that is cold enough to bring steam, typically

295

2-M Probe Survey At Coso Geothermal Area (2007) | Open Energy Information  

Open Energy Info (EERE)

2-M Probe Survey At Coso Geothermal Area (2007) 2-M Probe Survey At Coso Geothermal Area (2007) Exploration Activity Details Location Coso Geothermal Area Exploration Technique 2-M Probe Survey Activity Date 2007 Usefulness useful regional reconnaissance DOE-funding Unknown Exploration Basis Analyze if coupling remote sensing and field data is effective for determining geothermal areas using 1-M probe Notes The field data include subsurface temperature measured with temperature probes at depths down to 1 m, surface temperatures recorded with a hand-held infrared camera and an infrared thermometer, reflectance of contrasting surfaces measured with a hand-held spectroradiometer for the purpose of estimating the albedo effect, and radiosonde atmospheric profiles of temperature, water vapor, and pressure in order to apply

296

Water mist injection in oil shale retorting  

DOE Patents [OSTI]

Water mist is utilized to control the maximum temperature in an oil shale retort during processing. A mist of water droplets is generated and entrained in the combustion supporting gas flowing into the retort in order to distribute the liquid water droplets throughout the retort. The water droplets are vaporized in the retort in order to provide an efficient coolant for temperature control.

Galloway, T.R.; Lyczkowski, R.W.; Burnham, A.K.

1980-07-30T23:59:59.000Z

297

Examination system utilizing ionizing radiation and a flexible, miniature radiation detector probe  

DOE Patents [OSTI]

An optimized examination system and method based on the Reverse Geometry X-Ray{trademark} (RGX{trademark}) radiography technique are presented. The examination system comprises a radiation source, at least one flexible, miniature radiation detector probe positioned in appropriate proximity to the object to be examined and to the radiation source with the object located between the source and the probe, a photodetector device attachable to an end of the miniature radiation probe, and a control unit integrated with a display device connected to the photodetector device. The miniature radiation detector probe comprises a scintillation element, a flexible light guide having a first end optically coupled to the scintillation element and having a second end attachable to the photodetector device, and an opaque, environmentally-resistant sheath surrounding the flexible light guide. The probe may be portable and insertable, or may be fixed in place within the object to be examined. An enclosed, flexible, liquid light guide is also presented, which comprises a thin-walled flexible tube, a liquid, preferably mineral oil, contained within the tube, a scintillation element located at a first end of the tube, closures located at both ends of the tube, and an opaque, environmentally-resistant sheath surrounding the flexible tube. The examination system and method have applications in non-destructive material testing for voids, cracks, and corrosion, and may be used in areas containing hazardous materials. In addition, the system and method have applications for medical and dental imaging. 5 figs.

Majewski, S.; Kross, B.J.; Zorn, C.J.; Majewski, L.A.

1996-10-22T23:59:59.000Z

298

Nuclear Physics with Electroweak Probes  

E-Print Network [OSTI]

In recent years, the italian theoretical Nuclear Physics community has played a leading role in the development of a unified approach, allowing for a consistent and fully quantitative description of the nuclear response to electromagnetic and weak probes. In this paper I review the main achievements in both fields, point out some of the open problems, and outline the most promising prospects.

Omar Benhar

2009-02-26T23:59:59.000Z

299

Scanning Probe Alloying Nanolithography (SPAN)  

E-Print Network [OSTI]

or silicon nitride. Probes shapes can be pyramidal or conical and may be sharpened. Figure 1.8. Two kinds of cantilevers; triangle and rectangle shapes. (Courtesy of PNI) 1.2.7. Mode The AFM become much more versatile and capable than before...

Lee, Hyungoo

2010-07-14T23:59:59.000Z

300

Water, water everywhere  

Science Journals Connector (OSTI)

... available water resources, either locally or globally, are by no means exhausted. At present desalination -- the removal of salt from sea water or brackish water -- is very ... or brackish water -- is very expensive, mainly because it consumes so much energy. Desalination provides less than 0.2 per cent of all the water used in the world ...

Philip Ball

2000-01-27T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Understanding the operation and use of high temperature electrochemical corrosion rate probes  

SciTech Connect (OSTI)

Electrochemical corrosion rate probes were constructed and tested along with mass loss coupons in a N2/O2/CO2 plus water vapor environment. Temperatures ranged from 450 to 600 C. Corrosion rates for ash-covered mild steel, 304L SS, and 316L SS probes using electrochemical techniques were a function of time, temperature, and process environment. Correlation between electrochemical and mass loss corrosion rates was good.

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, M.; Cayard, Michael S. (InterCorr International Inc.); Eden, David A. (InterCorr International Inc.)

2004-01-01T23:59:59.000Z

302

Extracting CO2 from seawater: Climate change mitigation and renewable liquid fuel  

E-Print Network [OSTI]

Photosynthesis Biomass Renewable liquid fuel Fuel synthesis #12;Renewable liquid fuel Combustion CO2 separation emissions from all sectors IEA, 2012; CO2 emissions from fuel combustion: Highlights. · Solar · Wind · CO2. R. Soc. A, 368, 3343, 2010 #12;Biological renewable liquid fuel Combustion Water CO2 in air

Homes, Christopher C.

303

Cantilevered probe detector with piezoelectric element  

DOE Patents [OSTI]

A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

Adams, Jesse D; Sulchek, Todd A; Feigin, Stuart C

2013-04-30T23:59:59.000Z

304

Screening model for nanowire surface-charge sensors in liquid  

E-Print Network [OSTI]

The conductance change of nanowire field-effect transistors is considered a highly sensitive probe for surface charge. However, Debye screening of relevant physiological liquid environments challenge device performance due to competing screening from the ionic liquid and nanowire charge carriers. We discuss this effect within Thomas-Fermi and Debye-Huckel theory and derive analytical results for cylindrical wires which can be used to estimate the sensitivity of nanowire surface-charge sensors. We study the interplay between the nanowire radius, the Thomas-Fermi and Debye screening lengths, and the length of the functionalization molecules. The analytical results are compared to finite-element calculations on a realistic geometry.

Martin H. Sorensen; Niels Asger Mortensen; Mads Brandbyge

2007-08-17T23:59:59.000Z

305

Free energy surface of supercooled water  

Science Journals Connector (OSTI)

We present a detailed analysis of the free energy surface of a well characterized rigid model for water in supercooled states. We propose a functional form for the liquid free energy, supported by recent theoretical predictions [Y. Rosenfeld and P. Tarazona, Mol. Phys. 95, 141 (1998)], and use it to locate the position of a liquid-liquid critical point at TC?=130±5 K, PC?=290±30 MPa, and ?C?=1.10±0.03 g/cm3. The observation of the critical point strengthens the possibility that the extended simple point charge model of water may undergo a liquid-liquid phase transition. Finally, we discuss the possibility that the approach to the liquid-liquid critical point could be pre-empted by the glass transition.

A. Scala; F. W. Starr; E. La Nave; H. E. Stanley; F. Sciortino

2000-12-01T23:59:59.000Z

306

Supercooled water and the kinetic glass transition F. Sciortino,1  

E-Print Network [OSTI]

-dynamics study of the self-dynamics of water molecules in deeply supercooled liquid states. We find the superheated, stretched, and supercooled states of liquid water 4­6 ; ii the existence of a meta- stable, lowSupercooled water and the kinetic glass transition F. Sciortino,1 P. Gallo,2 P. Tartaglia,1 and S

Sciortino, Francesco

307

Superheated Water Extraction of Essential Oils of Origanum micranthum  

Science Journals Connector (OSTI)

......followed by 4 mL of water. The sample...with 4 mL of water. Then it was...5 min using a nitrogen gas flow. Following...Hawthorne. Solubility of liquid organic...hot/liquid) water from 298 K to...two-dimensional gas chromatography......

Fahrettin Gogus; Mustafa. Z. Ozel; Alastair C. Lewis

2005-02-01T23:59:59.000Z

308

SLOSHING OF LIQUIDS IN RIGID ANNULAR CYLINDRICAL AND TORUS TANKS DUE TO SEISMIC GROUND MOTIONS  

E-Print Network [OSTI]

response of water in annular tank model of water = 1 underof Fixed-Base Liquid Storage Tank,'' U.S. , Japan Seminar onSloshing in Axisymmetric Tanks, 11 Ph.D. Dissertation,

Aslam, M.

2013-01-01T23:59:59.000Z

309

Spring Semester, Course Title: Scanned Probe Techniques  

E-Print Network [OSTI]

: a fundamental understanding of the theoretical underpinnings behind each scanned probe technique Probe Microscopy: Atomic Scale Engineering by Forces and Currents - Adam Foster and Werner Hofer Applied Scanning Probe Methods (Vol. 1-13) ­ Bharat Bhushan, ed. Springer Handbook of Nanotechnology - Bharat

Sherrill, David

310

Water Resources Water Quality and Water Treatment  

E-Print Network [OSTI]

Water Resources TD 603 Lecture 1: Water Quality and Water Treatment CTARA Indian Institute of Technology, Bombay 2nd November, 2011 #12;OVERVIEW Water Quality WATER TREATMENT PLANTS WATER TREATMENT PLANTS WATER TREATMENT PLANTS WATER TRE OVERVIEW OF THE LECTURE 1. Water Distribution Schemes Hand Pump

Sohoni, Milind

311

Ultrasonic liquid level detector  

DOE Patents [OSTI]

An ultrasonic liquid level detector for use within a shielded container, the detector being tubular in shape with a chamber at its lower end into which liquid from in the container may enter and exit, the chamber having an ultrasonic transmitter and receiver in its top wall and a reflector plate or target as its bottom wall whereby when liquid fills the chamber a complete medium is then present through which an ultrasonic wave may be transmitted and reflected from the target thus signaling that the liquid is at chamber level.

Kotz, Dennis M. (North Augusta, SC); Hinz, William R. (Augusta, GA)

2010-09-28T23:59:59.000Z

312

Downhole probes evaluate cavern integrity  

SciTech Connect (OSTI)

Obtaining natural-gas storage caverns` pressures and temperatures with downhole probes has allowed TransGas Ltd., Regina, to monitor and evaluate cavern integrity. TransGas has more than 5 years` experience with the devices. The acquired data have also helped determine gas-in-place inventory and confirm and assess changes in spatial volumes. These changes may have resulted from cavern creep (shrinkage or closure) or downhole abnormality such as fluid infill or collapse of the side walls or roof. This first of two articles presents background and many of the details and lessons to date of TransGas` cavern gas-storage probe program; the conclusion describes a specific storage site with some results.

Crossley, N.G. [TransGas Ltd., Regina, Saskatchewan (Canada)

1997-03-03T23:59:59.000Z

313

Ethics of reproductive technologies probed  

Science Journals Connector (OSTI)

Ethics of reproductive technologies probed ... Creation of human reproductive technologies—such as in-vitro fertilization, cryopreservation of embryos, and surrogate motherhood— has advanced far more rapidly than development of legal, social, and ethical frameworks to deal with the wave of issues raised. ... The 11-member panel, chaired by Howard W. Jones Jr. of Eastern Virginia Medical School, includes physicians, scientists, lawyers, a theologian, and an ethicist. ...

1986-09-15T23:59:59.000Z

314

ccsd-00001732,version2-7Nov2004 Development behavior of liquid plasma produced by  

E-Print Network [OSTI]

ccsd-00001732,version2-7Nov2004 Development behavior of liquid plasma produced by YAG laser Jun called the environment material. Then, the plasma produced in liquid by the laser light is studied and the plasma development is observed by a streak camera. The ultra pure water or the ultra pure water

Paris-Sud XI, Université de

315

Metal-air cell comprising an electrolyte with a room temperature ionic liquid and hygroscopic additive  

DOE Patents [OSTI]

An electrochemical cell comprising an electrolyte comprising water and a hydrophobic ionic liquid comprising positive ions and negative ions. The electrochemical cell also includes an air electrode configured to absorb and reduce oxygen. A hydrophilic or hygroscopic additive modulates the hydrophobicity of the ionic liquid to maintain a concentration of the water in the electrolyte is between 0.001 mol % and 25 mol %.

Friesen, Cody A.; Krishnan, Ramkumar; Tang, Toni; Wolfe, Derek

2014-08-19T23:59:59.000Z

316

Liquid heat capacity lasers  

DOE Patents [OSTI]

The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

Comaskey, Brian J. (Walnut Creek, CA); Scheibner, Karl F. (Tracy, CA); Ault, Earl R. (Livermore, CA)

2007-05-01T23:59:59.000Z

317

Carbon monoxide absorbing liquid  

SciTech Connect (OSTI)

The present disclosure is directed to a carbon monoxide absorbing liquid containing a cuprous ion, hydrochloric acid and titanum trichloride. Titanium trichloride is effective in increasing the carbon monoxide absorption quantity. Furthermore, titanium trichloride remarkably increases the oxygen resistance. Therefore, this absorbing liquid can be used continuously and for a long time.

Arikawa, Y.; Horigome, S.; Kanehori, K.; Katsumoto, M.

1981-07-07T23:59:59.000Z

318

Precision liquid level sensor  

DOE Patents [OSTI]

A precision liquid level sensor utilizes a balanced R. F. bridge, each arm including an air dielectric line. Changes in liquid level along one air dielectric line imbalance the bridge and create a voltage which is directly measurable across the bridge.

Field, Michael E. (Albuquerque, NM); Sullivan, William H. (Albuquerque, NM)

1985-01-01T23:59:59.000Z

319

Field-scale estimation of volumetric water content using ground-penetrating radar ground wave techniques  

E-Print Network [OSTI]

sampling, time domain reflectometry (TDR), neutron probe logging, and tensiometers [Prichard, 1999 were compared to gravimetric water content, time domain reflectometry, and soil texture measurements

Hubbard, Susan

320

Liquid Fuels Market Module  

U.S. Energy Information Administration (EIA) Indexed Site

Liquid Fuels Market Module Liquid Fuels Market Module This page inTenTionally lefT blank 145 U.S. Energy Information Administration | Assumptions to the Annual Energy Outlook 2013 Liquid Fuels Market Module The NEMS Liquid Fuels Market Module (LFMM) projects petroleum product prices and sources of supply for meeting petroleum product demand. The sources of supply include crude oil (both domestic and imported), petroleum product imports, unfinished oil imports, other refinery inputs (including alcohols, ethers, esters, corn, biomass, and coal), natural gas plant liquids production, and refinery processing gain. In addition, the LFMM projects capacity expansion and fuel consumption at domestic refineries. The LFMM contains a linear programming (LP) representation of U.S. petroleum refining

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Probing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the understanding of this family of compounds is YMnO 3 , which has a ferrielectric transition at T C 900 K. 3-5 This gives rise to a small distortion of the two-dimensional...

322

The Solubility of Oxygen and Ozone in Liquids  

Science Journals Connector (OSTI)

This review covers the solubility of oxygen and ozone in liquids as a function of temperature and pressure. Solubility data for individual systems were critically evaluated and recommended or tentative values presented in many cases. The trend of solubilities in homologous series or related solvents is discussed. Liquids include water;seawater; aqueous salt solutions; mixed solvents; hydrocarbons; organic compounds containing oxygen halogen sulfur nitrogen or silicon; olive oil; and human blood. For ozone only its solubility in water is presented. Key words: aqueous solutions; biological fluids; gas solubility; hydrocarbons; mixed solvents; organic solvents; oxygen; ozone;seawater;water.

Rubin Battino; Timothy R. Rettich; Toshihiro Tominaga

1983-01-01T23:59:59.000Z

323

Graphene Transistor as a Probe for Streaming Potential  

Science Journals Connector (OSTI)

Graphene; streaming potential; electric double layer; flow sensor; ionic strength sensor; microfluidics ... Here R ? 1.3 × 10(12) Pa·s·m–3 is the hydraulic flow resistance over a distance L estimated from the Poiseulle’s law,(33) ? ? 0.89 × 10–3 Pa·s is the viscosity of water,(34) ? is the electrostatic zeta-potential at the boundary between the compact and the diffusive layer, e is the elementary charge, ? is the static dielectric constant of water, ? is the residual ionic concentration in the liquid due to impurity ions,(28) and ?i ? 10–7 m2V–1s–1 is the effective ionic mobility estimated by measuring the electrical conductivity of the liquid. ... We speculate that residues of the electron-beam resist, poly(methyl methacrylate) (PMMA), used in device fabrication still remain on the surface of the channel and can contribute to the observed decreased values of the ?-potential. ...

A. K. M. Newaz; D. A. Markov; D. Prasai; K. I. Bolotin

2012-05-08T23:59:59.000Z

324

Air Liquide - Biogas & Fuel Cells  

Broader source: Energy.gov (indexed) [DOE]

Liquide - Biogas & Fuel Cells Hydrogen Energy Biogas Upgrading Technology 12 June 2012 Charlie.Anderson@airliquide.com 2 Air Liquide, world leader in gases for industry,...

325

Sandia National Laboratories: ionic liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquid Biofuels Blend Right In: Researchers Show Ionic Liquids Effective for Pretreating Mixed Blends of Biofuel Feedstocks On February 26, 2013, in Biofuels, Biomass, Energy,...

326

Liquids in Temple Ritual  

E-Print Network [OSTI]

were performed. The water of purification could be presenteddrinking the water provided a sense of purification from the17 - 20). Purification with the four jars of water: take the

Poo, Mu-Chou

2010-01-01T23:59:59.000Z

327

Liquid sampling system  

DOE Patents [OSTI]

A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

Larson, L.L.

1984-09-17T23:59:59.000Z

328

Liquid sampling system  

DOE Patents [OSTI]

A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed.

Larson, Loren L. (Idaho Falls, ID)

1987-01-01T23:59:59.000Z

329

Liquid-level detector  

DOE Patents [OSTI]

Aliquid level sensor is described which has a pair of upright conductors spaced by an insulator defining a first high resistance path between the conductors. An electrically conductive path is interposed between the upright conductors at a discrete location at which liquid level is to be measured. It includes a liquid accessible gap of a dimension such that the electrical resistance across the conductor when the gap is filled with the liquid is detectably less than when the gap is emptied. The conductor might also be physically altered by temperature changes to serve also as an indicator of elevated temperature.

Not Available

1981-01-29T23:59:59.000Z

330

Liquid metal electric pump  

DOE Patents [OSTI]

An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

1992-01-14T23:59:59.000Z

331

Electronic Structure of Cobalt Nanocrystals Suspended in Liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Advances in the synthesis of crystals of nanometer dimensions, narrow size distribution, and controlled shape have generated interest because of the potential to create novel materials with tailored physical and chemical properties. New properties arise from quantum confinement effects and from the increasing fraction of surface atoms with unique bonding and geometrical configurations. At the ALS, an international team of scientists has performed an electronic structure study of colloidal nanocrystals-nanocrystals suspended in the liquid solvent in which they were grown. A range of photon-in/photon-out spectroscopies, including x-ray absorption spectroscopy (XAS), was applied. These techniques are element-selective, as they involve core atomic levels and can thus probe the local electronic structure of selected species in complex systems.

332

Electronic Structure of Cobalt Nanocrystals Suspended in Liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Advances in the synthesis of crystals of nanometer dimensions, narrow size distribution, and controlled shape have generated interest because of the potential to create novel materials with tailored physical and chemical properties. New properties arise from quantum confinement effects and from the increasing fraction of surface atoms with unique bonding and geometrical configurations. At the ALS, an international team of scientists has performed an electronic structure study of colloidal nanocrystals-nanocrystals suspended in the liquid solvent in which they were grown. A range of photon-in/photon-out spectroscopies, including x-ray absorption spectroscopy (XAS), was applied. These techniques are element-selective, as they involve core atomic levels and can thus probe the local electronic structure of selected species in complex systems.

333

Electronic Structure of Cobalt Nanocrystals Suspended in Liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Electronic Structure of Cobalt Nanocrystals Suspended in Liquid Print Advances in the synthesis of crystals of nanometer dimensions, narrow size distribution, and controlled shape have generated interest because of the potential to create novel materials with tailored physical and chemical properties. New properties arise from quantum confinement effects and from the increasing fraction of surface atoms with unique bonding and geometrical configurations. At the ALS, an international team of scientists has performed an electronic structure study of colloidal nanocrystals-nanocrystals suspended in the liquid solvent in which they were grown. A range of photon-in/photon-out spectroscopies, including x-ray absorption spectroscopy (XAS), was applied. These techniques are element-selective, as they involve core atomic levels and can thus probe the local electronic structure of selected species in complex systems.

334

Water Efficiency  

Energy Savers [EERE]

Wheeler - Water Savers, LLC * fwheeler@watersaversllc.com Topics * Performance contracting analysis * Water industry terms * Federal reduction goals * Water balance * Water...

335

2-M Probe Survey At Salt Wells Area (Coolbaugh, Et Al., 2006) | Open Energy  

Open Energy Info (EERE)

Salt Wells Area (Coolbaugh, Et Al., 2006) Salt Wells Area (Coolbaugh, Et Al., 2006) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: 2-M Probe Survey At Salt Wells Area (Coolbaugh, Et Al., 2006) Exploration Activity Details Location Salt Wells Geothermal Area Exploration Technique 2-M Probe Survey Activity Date 2005 - 2006 Usefulness useful DOE-funding Unknown Exploration Basis Geochemical water sampling, mineral distribution mapping, and shallow (30 cm) temperature probe measurements were conducted to expand on a previous field mapping study of surface geothermal features at Salt Wells, in order to evaluate the relationship between these features and structures that control geothermal fluid flow. Notes This study used a modified version of the 2 m temperature probe survey,

336

Heat Exchangers for Solar Water Heating Systems | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Heat Exchangers for Solar Water Heating Systems Heat Exchangers for Solar Water Heating Systems Heat Exchangers for Solar Water Heating Systems May 30, 2012 - 3:40pm Addthis Image of a heat exchanger. | Photo from iStockphoto.com Image of a heat exchanger. | Photo from iStockphoto.com Solar water heating systems use heat exchangers to transfer solar energy absorbed in solar collectors to the liquid or air used to heat water or a space. Heat exchangers can be made of steel, copper, bronze, stainless steel, aluminum, or cast iron. Solar heating systems usually use copper, because it is a good thermal conductor and has greater resistance to corrosion. Types of Heat Exchangers Solar water heating systems use three types of heat exchangers: Liquid-to-liquid A liquid-to-liquid heat exchanger uses a heat-transfer fluid that

337

Hydrophilization of Liquid Surfaces by Plasma Treatment  

E-Print Network [OSTI]

The impact of the cold radiofrequency air plasma on the surface properties of silicone oils (polydimethylsiloxane) was studied. Silicone oils of various molecular masses were markedly hydrophilized by the cold air plasma treatment. A pronounced decrease of the apparent water contact angles was observed after plasma treatment. A general theoretical approach to the calculation of apparent contact angles is proposed. The treated liquid surfaces demonstrated hydrophobic recovery. The characteristic time of the hydrophobic recovery grew with the molecular mass of the silicone oil.

Victor Multanen; Gilad Chaniel; Roman Grynyov; Ron Yosef Loew; Naor Siany; Edward Bormashenko

2014-09-01T23:59:59.000Z

338

INNOVATIVE EDDY CURRENT PROBE FOR MICRO DEFECTS  

SciTech Connect (OSTI)

This paper reports the development of an innovative eddy current (EC) probe, and its application to micro-defects on the root of the Friction Stir Welding (FSW). The new EC probe presents innovative concept issues, allowing 3D induced current in the material, and a lift-off independence. Validation experiments were performed on aluminium alloys processed by FSW. The results clearly show that the new EC probe is able to detect and sizing surface defects about 60 microns depth.

Santos, Telmo G.; Vilaca, Pedro; Quintino, Luisa [IDMEC, Av. Rovisco Pais, 1049-001 Lisbon (Portugal); Santos, Jorge dos [GKSS, Max-Planck-Street 1, D-21502 Geesthacht (Germany); Rosado, Luis [IST, UTL, Av. Rovisco Pais, 1049-001 Lisbon (Portugal)

2010-02-22T23:59:59.000Z

339

Microsoft Word - PumpProbe  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pump/Probe Pump/Probe Resources Available - BE Current Mid 2014 Mid 2016 Beamline X-ray Source Total Total Total NSLS-I 0.25 0.15 0 U4B Bend 0.05 0 0 U4IR Bend 0.2 0.15 0 APS 4.75 4.75 4.75 4-ID-C CPU 0 0 0 7-ID-C&D Undulator 1 1 1 7-BM-B Bend 1 1 1 10-ID-B Undulator 0.5 0.5 0.5 11-ID-D Undulator 1 1 1 14-ID-B Undulator 1 1 1 20-ID Undulator 0.25 0.25 0.25 ALS 3 3 3 4.0.2 EPU 0 0 0 6.0.1 Undulator 1 1 1 6.0.2 Undulator 1 1 1 6.1.2 Bend 0 0 0 9.0.2 Undulator 1 1 1 11.0.1 EPU 0 0 0 11.0.2 EPU 0 0 0 SSRL 0.15 0.45 0.45

340

Renewable Liquid Fuels Reforming  

Broader source: Energy.gov [DOE]

The Program anticipates that distributed reforming of biomass-derived liquid fuels could be commercial during the transition to hydrogen and used in the mid- and long-term time frames.

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Synthetic investigation of small-molecule probes.  

E-Print Network [OSTI]

??A series of small molecules was synthesized to probe three protein targets in order to elucidate the key small molecule-protein interactions required for potency. Triclosan… (more)

Bromba, Caleb

2012-01-01T23:59:59.000Z

342

Probing Organic Transistors with Infrared Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing Organic Transistors with Infrared Beams Print Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is...

343

Isentropic compression of hydrogen: Probing conditions deep in planetary interiors  

Science Journals Connector (OSTI)

We perform ab initio calculations for the equation of state of dense liquid hydrogen and deuterium using quantum molecular dynamics simulations based on finite-temperature density functional theory. This extensive data set allows us to determine specific density-temperature-pressure tracks such as the cold curve, precompressed and principal Hugoniot curves, and isentropes which are essential for the analysis and interpretation of high-pressure experiments. In this study we focus on conditions probed by recent quasi-isentropic shock compression experiments that have reached a so-far unprecedented 108-fold compression of gaseous deuterium. As these states of matter are relevant for the deep interior of Jupiter-like exoplanets we simultaneously give predictions for their isentropes.

Andreas Becker, Nadine Nettelmann, Bastian Holst, and Ronald Redmer

2013-07-19T23:59:59.000Z

344

Method for imaging liquid and dielectric materials with scanning polarization force microscopy  

SciTech Connect (OSTI)

The invention images dielectric polarization forces on surfaces induced by a charged scanning force microscope (SFM) probe tip. On insulators, the major contribution to the surface polarizability at low frequencies is from surface ions. The mobility of these ions depends strongly on the humidity. Using the inventive SFM, liquid films, droplets, and other weakly adsorbed materials have been imaged. 9 figs.

Hu, J.; Ogletree, D.F.; Salmeron, M.; Xiao, X.

1999-03-09T23:59:59.000Z

345

Plasmas in Multiphase Media: Bubble Enhanced Discharges in Liquids and Plasma/Liquid Phase Boundaries  

SciTech Connect (OSTI)

In this research project, the interaction of atmospheric pressure plasmas with multi-phase media was computationally investigated. Multi-phase media includes liquids, particles, complex materials and porous surfaces. Although this investigation addressed fundamental plasma transport and chemical processes, the outcomes directly and beneficially affected applications including biotechnology, medicine and environmental remediation (e.g., water purification). During this project, we made advances in our understanding of the interaction of atmospheric pressure plasmas in the form of dielectric barrier discharges and plasma jets with organic materials and liquids. We also made advances in our ability to use computer modeling to represent these complex processes. We determined the method that atmospheric pressure plasmas flow along solid and liquid surfaces, and through endoscopic like tubes, deliver optical and high energy ion activation energy to organic and liquid surfaces, and produce reactivity in thin liquid layers, as might cover a wound. We determined the mechanisms whereby plasmas can deliver activation energy to the inside of liquids by sustaining plasmas in bubbles. These findings are important to the advancement of new technology areas such as plasma medicine

Kushner, Mark Jay [University of Michigan] [University of Michigan

2014-07-10T23:59:59.000Z

346

Potential Distribution in Functionalized Graphene Devices Probed by Kelvin Probe Force Microscopy  

E-Print Network [OSTI]

graphene sheet (FGS) [1] can be utilized in sensor technology, batteries and supercapacitors becausePotential Distribution in Functionalized Graphene Devices Probed by Kelvin Probe Force Microscopy Institute of Physics. Related Articles Ferromagnetic fluctuation in doped armchair graphene nanoribbons J

Aksay, Ilhan A.

347

Yosemite Waters Vehicle Evaluation Report: Final Results  

SciTech Connect (OSTI)

Document details the evaluation of Fischer-Tropsch diesel, a gas-to-liquid fuel, in medium-duty delivery vehicles at Yosemite Waters. The study was conducted by NREL at the company's Fullerton, California, bottling headquarters.

Eudy, L.; Barnitt, R.; Alleman, T. L.

2005-08-01T23:59:59.000Z

348

X-rays at Solid-Liquid Surfaces  

SciTech Connect (OSTI)

Solid-liquid interfaces play an important role in many areas of current and future technologies, and in our biosphere. They play a key role in the development of nanofluidics and nanotribology, which sensitively depend on our knowledge of the microscopic structures and phenomena at the solid-liquid interface. The detailed understanding of how a fluid meets a wall is also a theoretical challenge. In particular, the phenomena at repulsive walls are of interest, since they affect many different phenomena, such as water-repellent surfaces or the role of the hydrophobic interaction in protein folding. Recent x-ray reflectivity studies of various solid-liquid interfaces have disclosed rather intriguiing phenomena, which will be discussed in this lecture: premelting of ice in contact with silica; liquid Pb in contact with Si; water in contact with hydrophobic surfaces. These experiments, carried out with high-energy x-ray microbeams, reveal detailed insight into the liquid density profile closest to the wall. A detailed insight into atomistic phenomena at solid-liquid interfaces is also a prerequisite in the microscopic control of electrochemical reactions at interfaces. Recent x-ray studies show the enormous future potential of such non-destructive analytical tools for the in situ observation of (electro-)chemical surface reactions. This lecture will review recent x-ray experiments on solid-liquid interfaces.

Dosch, Helmut (Max Planck Institute for Metals Research) [Max Planck Institute for Metals Research

2007-05-02T23:59:59.000Z

349

Measurement and correlation of phase equilibria for (water + aromatic hydrocarbon) binary mixtures at T = (573 to 623) K using microfluidic mixing  

Science Journals Connector (OSTI)

(Vapour + liquid) and (liquid + liquid) equilibria for (water + p-xylene) and (water + decalin) mixtures at T = (573 to 623) K were measured by a flow type apparatus with microfluidic system. The liquid–liquid slug flows in the microfluidic system were used for mixing of water and hydrocarbon due to high mass transfer between two liquid phases. The formations of the liquid–liquid slugs for (water + p-xylene) system were studied by changing the flow rate. The results of the liquid–liquid slug formations at hydrocarbon and water rich compositions were used for the measurements for (vapour + liquid) and (liquid + liquid) equilibria, respectively. It was found that the phase equilibria using the apparatus with the microfluidic system can be measured in a short residential time (1.6 to 3.2) min. The experimental results of the phase equilibria for (water + p-xylene) and (water + decalin) systems give that the regions of the (vapour + liquid) and (liquid + liquid) equilibria for both mixtures reduce with the increasing temperature. The mixture of (water + decalin) at T = (583 to 623) K forms the two phase regions of the (vapour + liquid) and (liquid + liquid) equilibria larger than those for (water + p-xylene) mixture. The experimental data of the phase equilibria obtained in this work were correlated with Peng–Robinson–Stryjek–Vera equation of state. The correlated results of the (liquid + liquid) equilibria for both systems represent the experimental data. For (vapour + liquid) equilibria, the results give the qualitative representations in the shape of the two phase region for both mixtures.

Masaki Togo; Taisuke Maeda; Akira Ito; Yusuke Shimoyama

2013-01-01T23:59:59.000Z

350

Millimeter-wave active probe  

DOE Patents [OSTI]

A millimeter-wave active probe for use in injecting signals with frequencies above 50GHz to millimeter-wave and ultrafast devices and integrated circuits including a substrate upon which a frequency multiplier consisting of filter sections and impedance matching sections are fabricated in uniplanar transmission line format. A coaxial input and uniplanar 50 ohm transmission line couple an approximately 20 GHz input signal to a low pass filter which rolls off at approximately 25 GHz. An input impedance matching section couples the energy from the low pass filter to a pair of matched, antiparallel beam lead diodes. These diodes generate odd-numberd harmonics which are coupled out of the diodes by an output impedance matching network and bandpass filter which suppresses the fundamental and third harmonics and selects the fifth harmonic for presentation at an output.

Majidi-Ahy, Gholamreza (Sunnyvale, CA); Bloom, David M. (Portola Valley, CA)

1991-01-01T23:59:59.000Z

351

MERIT Pump/Probe Data OutlineOutline  

E-Print Network [OSTI]

MERIT Pump/Probe Data Analysis OutlineOutline The pump/probe program Particle detector response correction Pump/probe analysis results NFMCC Collaboration Meeting , LBNL, January 26, 2009 Ilias Efthymiopoulos - CERN #12;The pump/probe program #12;The pump/probe program Use of the CERN PS flexibility

McDonald, Kirk

352

A Finite Element Model for Ice Ball Evolution in a Multi-probe Cryosurgery  

E-Print Network [OSTI]

to intracellular ice injury for fast cooling rates, and solution effects injury for slow cooling rates. BasicallyA Finite Element Model for Ice Ball Evolution in a Multi-probe Cryosurgery RICHARD WANa, *, ZHIHONG October 2002; In final form 8 May 2003) The ice formation in a water body is examined for the computation

Wan, Richard G.

353

Nile-Red–Nanoclay Hybrids: Red Emissive Optical Probes for Use in Aqueous Dispersion  

Science Journals Connector (OSTI)

Nile-Red–Nanoclay Hybrids: Red Emissive Optical Probes for Use in Aqueous Dispersion ... Water-dispersible and (bio)functionalizable nanoclays have a considerable potential as inexpensive carriers for organic molecules like drugs and fluorophores. ... Otherwise, fluorescent nanoclays can be obtained via covalent attachment of reactive dyes at the edges of the nanoclay sheets after surface modification using silanization chemistries. ...

Tom Felbeck; Thomas Behnke; Katrin Hoffmann; Markus Grabolle; Marina M. Lezhnina; Ulrich H. Kynast; Ute Resch-Genger

2013-08-13T23:59:59.000Z

354

Sustaining dry surfaces under water  

E-Print Network [OSTI]

Rough surfaces immersed under water remain practically dry if the liquid-solid contact is on roughness peaks, while the roughness valleys are filled with gas. Mechanisms that prevent water from invading the valleys are well studied. However, to remain practically dry under water, additional mechanisms need consideration. This is because trapped gas (e.g. air) in the roughness valleys can dissolve into the water pool, leading to invasion. Additionally, water vapor can also occupy the roughness valleys of immersed surfaces. If water vapor condenses, that too leads to invasion. These effects have not been investigated, and are critically important to maintain surfaces dry under water. In this work, we identify the critical roughness scale below which it is possible to sustain the vapor phase of water and/or trapped gases in roughness valleys - thus keeping the immersed surface dry. Theoretical predictions are consistent with molecular dynamics simulations and experiments.

Paul R. Jones; Xiuqing Hao; Eduardo R. Cruz-Chu; Konrad Rykaczewski; Krishanu Nandy; Thomas M. Schutzius; Kripa K. Varanasi; Constantine M. Megaridis; Jens H. Walther; Petros Koumoutsakos; Horacio D. Espinosa; Neelesh A. Patankar

2014-09-29T23:59:59.000Z

355

Scanning Probe Microscopy Studies of Carbon Nanotubes  

E-Print Network [OSTI]

Scanning Probe Microscopy Studies of Carbon Nanotubes Teri Wang Odom1 , Jason H. Hafner1 relationship between Single-Walled Carbon Nanotube (SWNT) atomic structure and electronic properties, (2, properties and application of carbon nanotube probe microscopy tips to ultrahigh resolution and chemically

Odom, Teri W.

356

Nuclear Imaging Probes: from Bench to Bedside  

Science Journals Connector (OSTI)

...specific imaging probes is the nuclear fuel for molecular imaging by positron emission...cancer. Cancer Res 2001;61:110-7. 24 Price DT, Coleman RE, Liao RP, Robertson CN...specific imaging probes is the nuclear fuel for molecular imaging by positron emission...

Hans-Jürgen Wester

2007-06-15T23:59:59.000Z

357

Liquid-liquid interfacial nanoparticle assemblies  

DOE Patents [OSTI]

Self-assembly of nanoparticles at the interface between two fluids, and methods to control such self-assembly process, e.g., the surface density of particles assembling at the interface; to utilize the assembled nanoparticles and their ligands in fabrication of capsules, where the elastic properties of the capsules can be varied from soft to tough; to develop capsules with well-defined porosities for ultimate use as delivery systems; and to develop chemistries whereby multiple ligands or ligands with multiple functionalities can be attached to the nanoparticles to promote the interfacial segregation and assembly of the nanoparticles. Certain embodiments use cadmium selenide (CdSe) nanoparticles, since the photoluminescence of the particles provides a convenient means by which the spatial location and organization of the particles can be probed. However, the systems and methodologies presented here are general and can, with suitable modification of the chemistries, be adapted to any type of nanoparticle.

Emrick, Todd S. (South Deerfield, MA); Russell, Thomas P. (Amherst, MA); Dinsmore, Anthony (Amherst, MA); Skaff, Habib (Amherst, MA); Lin, Yao (Amherst, MA)

2008-12-30T23:59:59.000Z

358

ECO2M: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2, Including Super- and Sub-Critical Conditions, and Phase Change Between Liquid and Gaseous CO2  

SciTech Connect (OSTI)

ECO2M is a fluid property module for the TOUGH2 simulator (Version 2.0) that was designed for applications to geologic storage of CO{sub 2} in saline aquifers. It includes a comprehensive description of the thermodynamics and thermophysical properties of H{sub 2}O - NaCl - CO{sub 2} mixtures, that reproduces fluid properties largely within experimental error for temperature, pressure and salinity conditions in the range of 10 C {le} T {le} 110 C, P {le} 600 bar, and salinity from zero up to full halite saturation. The fluid property correlations used in ECO2M are identical to the earlier ECO2N fluid property package, but whereas ECO2N could represent only a single CO{sub 2}-rich phase, ECO2M can describe all possible phase conditions for brine-CO{sub 2} mixtures, including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO{sub 2}. This allows for seamless modeling of CO{sub 2} storage and leakage. Flow processes can be modeled isothermally or non-isothermally, and phase conditions represented may include a single (aqueous or CO{sub 2}-rich) phase, as well as two-and three-phase mixtures of aqueous, liquid CO{sub 2} and gaseous CO{sub 2} phases. Fluid phases may appear or disappear in the course of a simulation, and solid salt may precipitate or dissolve. TOUGH2/ECO2M is upwardly compatible with ECO2N and accepts ECO2N-style inputs. This report gives technical specifications of ECO2M and includes instructions for preparing input data. Code applications are illustrated by means of several sample problems, including problems that had been previously solved with TOUGH2/ECO2N.

Pruess, K.

2011-04-01T23:59:59.000Z

359

Proximal Probes | Center for Functional Nanomaterials  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Proximal Probes Facility Proximal Probes Facility proximal probes The Proximal Probes Facility consists of laboratories for microscopy, spectroscopy, and probing of nanostructured materials and their functional properties. At the core of the facility is a suite of instruments for in-situ microscopy of surfaces and nanostructures under extreme conditions, e.g., in reactive gases, and at high or low temperatures. Unique instruments enable in-situ and in-operando studies of surface chemistry and catalysis at pressures from ultrahigh vacuum (UHV) to 5 bar via complementary scanning tunneling microscopy imaging and photoelectron spectroscopy, coupled with real-time gas analysis. Several UHV systems are available for scanning tunneling and atomic force microscopy, as well as low-energy electron microscopy and synchrotron photoelectron microscopy. A

360

Rugged fiber optic probe for raman measurement  

DOE Patents [OSTI]

An optical probe for conducting light scattering analysis is disclosed. The probe comprises a hollow housing and a probe tip. A fiber assembly made up of a transmitting fiber and a receiving bundle is inserted in the tip. A filter assembly is inserted in the housing and connected to the fiber assembly. A signal line from the light source and to the spectrometer also is connected to the filter assembly and communicates with the fiber assembly. By using a spring-loaded assembly to hold the fiber connectors together with the in-line filters, complex and sensitive alignment procedures are avoided. The close proximity of the filter assembly to the probe tip eliminates or minimizes self-scattering generated by the optical fiber. Also, because the probe can contact the sample directly, sensitive optics can be eliminated.

O'Rourke, Patrick E. (Martinez, GA); Toole, Jr., William R. (Aiken, SC); Nave, Stanley E. (Evans, GA)

1998-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Individual quantum probes for optimal thermometry  

E-Print Network [OSTI]

The unknown temperature of a sample may be estimated with minimal disturbance by putting it in thermal contact with an individual quantum probe. If the interaction time is sufficiently long so that the probe thermalizes, the temperature can be read out directly from its steady state. Here we prove that the optimal quantum probe, acting as a thermometer with maximal thermal sensitivity, is an effective two-level atom with a maximally degenerate excited state. When the total interaction time is insufficient to produce full thermalization, we optimize the estimation protocol by breaking it down into sequential stages of probe preparation, thermal contact and measurement. We observe that frequently interrogated probes initialized in the ground state achieve the best performance. For both fully and partly thermalized thermometers, the sensitivity grows significantly with the number of levels, though optimization over their energy spectrum remains always crucial.

Luis A. Correa; Mohammad Mehboudi; Gerardo Adesso; Anna Sanpera

2014-11-23T23:59:59.000Z

362

Viscosity of Interfacial Water  

Science Journals Connector (OSTI)

The effective shear viscosity and frequency-dependent dynamic oscillatory shear spectra of water containing monovalent or divalent ions (ionic strength 25 mM), confined between mica crystals at 1–2 water molecules thickness, oscillated with twist angle with the period expected for the pseudohexagonal surface lattice. The effective viscosity varied by orders of magnitude as the twist angle was changed. Confinement appeared to imprint lateral spatial correlation on the ultrathin liquid, the more so the better the confining lattices were aligned, but the oft-proposed “ice structure” was not observed dynamically.

Yingxi Zhu and Steve Granick

2001-08-10T23:59:59.000Z

363

A water film motor  

E-Print Network [OSTI]

We report on electrically-induced rotations in water films, which can function at many length scales. The device consists of a two-dimensional cell used for electrolysis of water films, as simple as an insulator frame with two electrodes on the sides, to which an external in-plane electric field perpendicular to the mean electrolysis current density is applied. If either the external field or the electrolysis current exceeds some threshold (while the other one is not zero), the liquid film begins to rotate.

R. Shirsavar; A. Amjadi; N. Hamedani Radja; M. D. Niry; M. Reza Rahimi Tabar; M. R. Ejtehadi

2006-05-01T23:59:59.000Z

364

Design of a Probe for Strain Sensitivity Studies of Critical Current Densities in SC Wires and Tapes  

SciTech Connect (OSTI)

The design of a variable-temperature probe used to perform strain sensitivity measurements on LTS wires and HTS wires and tapes is described. The measurements are intended to be performed at liquid helium temperatures (4.2 K). The wire or tape to be measured is wound and soldered on to a helical spring device, which is fixed at one end and subjected to a torque at the free end. The design goal is to be able to achieve {+-} 0.8 % strain in the wire and tape. The probe is designed to carry a current of 2000A.

Dhanaraj, N.; Barzi, E.; Turrioni, D.; Rusy, A.; Lombardo, V.; /Fermilab

2011-07-01T23:59:59.000Z

365

Water inertial reorientation: Hydrogen bond strength and the angular potential  

E-Print Network [OSTI]

Water inertial reorientation: Hydrogen bond strength and the angular potential David E. Moilanen) The short-time orientational relaxation of water is studied by ultrafast infrared pump-probe spectroscopy with recent molecular dynamics simulations employing the simple point charge-extended water model at room

Fayer, Michael D.

366

A study of boiling water flow regimes at low pressures  

E-Print Network [OSTI]

"A comprehensive experimental program to examine flow regimes at pressures below 100 psia for boiling of water in tubes was carried out. An electrical probe, which measures the resistance of the fluid between the centerline ...

Fiori, Mario P.

1966-01-01T23:59:59.000Z

367

MagLab - MagLab Dictionary: Probe (Transcript)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

means, "stick on which you put the sample," but probe sounds more scientific Listen Audio version Related Links Meet the Probes A magnet without a probe is like a drill without...

368

Comparison of neutron probe and time domain reflectometry techniques of soil moisture analysis  

SciTech Connect (OSTI)

The Environmental Science Group of Los Alamos National Laboratory collected soil water content data using Time Domain Reflectometry (TDR) and neutron probe in order to correlate the results from the two techniques in a study performed at Los Alamos, NM. Two well-characterized field plots (3m {times} 10m) were instrumented with TDR waveguides and neutron probe access tubes at four locations. At each location, TDR rod pairs were placed horizontally at 5-,15-,30-,45- and 60-cm depths and vertical sets of rod pairs with lengths of 15-,30-,45- and 60-cm were installed. Neutron probe measurements were taken at 15-,30-,45- and 60-cm depths. Because the neutron probe measures a spherical volume, soil water content values were compared with horizontal TDR readings averaged over the same zone. Additionally, vertical TDR readings were compared to neutron probe readings averaged over the depths corresponding to each TDR length. Measurements for each technique were taken weekly since Fall of 1992. A time series comparison of the results is presented.

Schofield, T.G.; Langhorst, G.J.; Trujillo, G.; Bostick, K.V.; Hansen, W.R.

1994-04-01T23:59:59.000Z

369

Liquid Scintillator Purification  

SciTech Connect (OSTI)

The KamLAND collaboration has studied background requirements and purification methods needed to observe the 7Be neutrino from the sun. First we will discuss the present background situation in KamLAND where it is found that the main background components are 210Pb and 85Kr. It is then described how to purify the liquid scintillator. The present status and results on how to remove 210Pb from the liquid scintillator are discussed. Specifically, the detailed analysis of the effects of distillation and adsorption techniques are presented.

Kishimoto, Y. [Research Center for Neutrino Science, Tohoku University (Japan)

2005-09-08T23:59:59.000Z

370

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen in a  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freeze Liquid Nitrogen! Freeze Liquid Nitrogen! Previous Video (Let's Freeze Liquid Nitrogen!) Frostbite Theater Main Index Next Video (Freeze the Rainbow!) Freeze the Rainbow! Liquid Nitrogen in a Microwave! What happens when the world's most beloved cryogenic liquid meets one of the most common household appliances? Find out when we try to microwave liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: A little while ago we received an email from Star of the Sea Catholic School in Virginia Beach, Virginia, asking what happens when you place liquid nitrogen in a microwave. Well, I just happen to have some liquid nitrogen! Steve: And I just happen to have a microwave!

371

Lyophilic liquid porosimetry and a new liquid autoporosimeter  

SciTech Connect (OSTI)

Lyophilic liquid porosimetry determines the volumes of different size pores by measuring the amount of liquid in these pores, thus, providing pore volume distribution (PVD) data for porous structures. Any liquid that wets the sample may be used. This opens unique opportunities for porous structure evaluation. It provides realistic PVD analysis when the liquid of interest changes the porous structure. It determines uptake/drainage hysteresis of real liquids. It allows direct measurements of uptake and retention capillary pressures with different amounts of liquid in a sample. Lyophilic liquid porosimetry determines liquid/solid contact angles of different size pores within the sample. It can also be used for PVD analysis of both soft, brittle materials and porous metal materials.

Tyomkin, I. [TRI/Princeton, NJ (United States)

1998-12-31T23:59:59.000Z

372

Two-state thermodynamics of the ST2 model for supercooled water  

SciTech Connect (OSTI)

Thermodynamic properties of the ST2 model for supercooled liquid water exhibit anomalies similar to those observed in real water. A possible explanation of these anomalies is the existence of a metastable, liquid–liquid transition terminated by a critical point. This phenomenon, whose possible existence in real water is the subject of much current experimental work, has been unambiguously demonstrated for this particular model by most recent simulations. In this work, we reproduce the anomalies of two versions of the ST2 model with an equation of state describing water as a non-ideal “mixture” of two different types of local molecular order. We show that the liquid–liquid transition in the ST2 water is energy-driven. This is in contrast to another popular model, mW, in which non-ideality in mixing of two alternative local molecular orders is entropy-driven, and is not sufficiently strong to induce a liquid–liquid transition.

Holten, Vincent; Anisimov, Mikhail A., E-mail: anisimov@umd.edu [Institute for Physical Science and Technology and Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, Maryland 20742 (United States); Palmer, Jeremy C.; Debenedetti, Pablo G. [Department of Chemical and Biological Engineering, Princeton University, Princeton, New Jersey 08544 (United States)] [Department of Chemical and Biological Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Poole, Peter H. [Department of Physics, St. Francis Xavier University, Antigonish, Nova Scotia B2G 2W5 (Canada)] [Department of Physics, St. Francis Xavier University, Antigonish, Nova Scotia B2G 2W5 (Canada)

2014-03-14T23:59:59.000Z

373

Surfactants for ground water remediation  

Science Journals Connector (OSTI)

Ground water contamination is a most intractable form of pollution. Spilled solvent or fuel liquids are trapped below the water table by colloidal forces. Surfactants may be used to dramatically improve contaminated aquifer remediation rates. Principal remediation mechanisms include micellar solubilization and mobilization of the trapped liquids by lowering of the oil/water interfacial tension. Surfactant selection is a key to the successful design of a remediation effort, and involves consideration of factors including Krafft Point, surfactant adsorption onto the aquifer solids, and the phase behavior of the oil/water/surfactant system. Successful field demonstrations have occurred in recent months and the technology is moving rapidly toward commercialization. Critical research issues remain including acceptable clean-up levels, surfactant/contaminant in situ biodegradation rates, and surfactant decontamination and reuse.

Jeffrey H. Harwell; David A. Sabatini; R.C. Knox

1999-01-01T23:59:59.000Z

374

Probing Fukushima with cosmic rays should help speed cleanup...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing Fukushima with cosmic rays Probing Fukushima with cosmic rays should help speed cleanup of damaged plant The initiative could reduce the time required to clean up the...

375

Using Rare Gas Permeation to Probe Methanol Diffusion near the...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Rare Gas Permeation to Probe Methanol Diffusion near the Glass Transition Temperature. Using Rare Gas Permeation to Probe Methanol Diffusion near the Glass Transition Temperature....

376

Contribution of atom-probe tomography to a better understanding...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

atom-probe tomography to a better understanding of glass alteration mechanisms: application to a nuclear glass Contribution of atom-probe tomography to a better understanding of...

377

Understanding Atom Probe Tomography of Oxide-Supported Metal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atom Probe Tomography of Oxide-Supported Metal Nanoparticles by Correlation with Atomic Resolution Electron Understanding Atom Probe Tomography of Oxide-Supported Metal...

378

Water in a Crowd In many situations, form biology to geology, water occurs not as the pure bulk  

E-Print Network [OSTI]

Water in a Crowd In many situations, form biology to geology, water occurs not as the pure bulk species, and interacting with large organic molecules. In such situations, water does not behave in the same manner as it does in the pure bulk liquid. Water dynamics are fundamental to many processes

Fayer, Michael D.

379

Viscosity of Liquids  

Science Journals Connector (OSTI)

6 November 1952 research-article Viscosity of Liquids E. N. da C. Andrade The Royal Society is collaborating with JSTOR to digitize, preserve, and extend access to Proceedings of the Royal Society of London. Series A, Mathematical and Physical Sciences. www.jstor.org

1952-01-01T23:59:59.000Z

380

The Viscosity of Liquids  

Science Journals Connector (OSTI)

... of momentum between them. In the case of a gas, Maxwell showed how the viscosity can be derived by considering this momentum as being communicated by molecules transferring themselves bodily ... fulfilment of the conditions postulated in Maxwell's treatment, and the fact that while gas viscosity goes up with temperature liquid ...

E. N. DA C. ANDRADE

1930-04-12T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Detonation in Liquid Explosives  

Science Journals Connector (OSTI)

... Laboratory, on the initiative of Dr. A. H. Davis, into the process of detonation in explosives, the programme including a photographic study of the ... in explosives, the programme including a photographic study of the detonation Waves in transparent liquid explosives—the sensitivity of some of which can be varied by ...

D. CRONEY

1948-09-25T23:59:59.000Z

382

Liquid Natural Gas  

Science Journals Connector (OSTI)

Liquid Natural Gas ... IN A new technique for storing natural gas at the East Ohio Gas Co. plant, Cleveland, Ohio, the gas is liquefied before passing to the gas holders. ... Natural gas contains moisture and carbon dioxide, both of which liquefy before the natural gas and are somewhat of a nuisance because upon solidification they clog the pipes. ...

W. F. SCHAPHORST

1941-04-25T23:59:59.000Z

383

Instrument Series: Microscopy Atom Probe The LEAP  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atom Probe Atom Probe The LEAP ® 4000 XHR local electrode atom probe tomography instrument enabled the first- ever comprehensive and accurate 3-D chemical imaging studies of low electrical conductivity materials, such as ceramics, semiconductors and oxides. The LEAP capability is assisting EMSL's efforts to further scientific advancements in interface analysis and microstructural characterization, providing a new tool for understanding the relationship between the nanoscale structure of materials and their macroscopic properties. Research Applications Geochemistry - Studying chemical processes that compose rocks and soils has long been used to determine matter cycles and transport in the environment, which supports critical EMSL research in areas including bioremediation.

384

Characterization of Fiber Optic CMM Probe System  

SciTech Connect (OSTI)

This report documents a study completed on the fiber optic probe system that is a part of the Werth optical CMM. This study was necessary due to a lack of documentation from the vendor for the proper use and calibration of the fiber probe, and was performed in support of the Lithographie Galvanoformung Abformung (LIGA) development program at the FM&T. As a result of this study, a better understanding of the fiber optic probe has been developed, including guidelines for its proper use and calibration.

K.W.Swallow

2007-05-15T23:59:59.000Z

385

Acoustic probing of salt using sonar  

E-Print Network [OSTI]

ACOUSTIC PROBING OF SALT USING SONAR A Thesis by KENNETH BRYAN BUTLER Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE Oecember 1977 Major Subject...: Geophysics ACOUSTIC PROBING OF SALT USING SONAR A Thesis by KENNETH BRYAN BUTLER Approved as to style and content by: C airman of Com ttee ea of e r nt em er ember December 1977 ABSTRACT Acoustic Probing of Salt Using Sonar. (December 1977...

Butler, Kenneth Bryan

2012-06-07T23:59:59.000Z

386

Air Liquide- Biogas & Fuel Cells  

Broader source: Energy.gov [DOE]

Presentation about Air Liquide's biogas technologies and integration with fuel cells. Presented by Charlie Anderson, Air Liquide, at the NREL/DOE Biogas and Fuel Cells Workshop held June 11-13, 2012, in Golden, Colorado.

387

The Water Trimer Frank N. Keutsch, Jeffery D. Cruzan, and Richard J. Saykally*  

E-Print Network [OSTI]

theoretical work of Frank and Wen3 predicted that formation of a single hydrogen bond (H-bond) in liquid water presented by those early authors has evolved substantially, there is modern consensus that liquid waterThe Water Trimer Frank N. Keutsch, Jeffery D. Cruzan, and Richard J. Saykally* Department

Cohen, Ronald C.

388

Liquid metal thermal electric converter  

DOE Patents [OSTI]

A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

1989-01-01T23:59:59.000Z

389

Process for removing sulfate anions from waste water  

DOE Patents [OSTI]

A liquid emulsion membrane process for removing sulfate anions from waste water is disclosed. The liquid emulsion membrane process includes the steps of: (a) providing a liquid emulsion formed from an aqueous strip solution and an organic phase that contains an extractant capable of removing sulfate anions from waste water; (b) dispersing the liquid emulsion in globule form into a quantity of waste water containing sulfate anions to allow the organic phase in each globule of the emulsion to extract and absorb sulfate anions from the waste water and (c) separating the emulsion including its organic phase and absorbed sulfate anions from the waste water to provide waste water containing substantially no sulfate anions.

Nilsen, David N. (Lebanon, OR); Galvan, Gloria J. (Albany, OR); Hundley, Gary L. (Corvallis, OR); Wright, John B. (Albany, OR)

1997-01-01T23:59:59.000Z

390

A thermoacoustic oscillator powered by vaporized water and ethanol  

Science Journals Connector (OSTI)

We measure the temperature difference required to drive a thermoacoustic oscillator containing air water vapor and liquid water as the working fluids. The oscillator is composed of a large tube containing an array of narrow tubes connected at one end to a tank of liquid water. When the water is heated the temperature difference across the tube array increases until thermoacoustic oscillations occur. The temperature difference at the onset of oscillation is measured to be 56 ? ° C significantly smaller (by ? 200 ? ° C ) than the temperature measured when the tank is filled with dry air instead of water. The temperature difference can be further reduced to 47 ? ° C by using ethanol instead of water.

Daisuke Noda; Yuki Ueda

2013-01-01T23:59:59.000Z

391

Scanning Probe AFM Compound Microscope | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

reveal that significant charge-transfer occurs between atoms... Atomistic simulation of CdTe solid-liquid coexistence equilibria. Atomistic simulations of CdTe using a...

392

Water vapour, sonoluminescence and sonochemistry  

Science Journals Connector (OSTI)

...data we obtain are for steady-state oscillations, i.e. after the decay of initial...forms of mass di usion. In a helium or xenon bubble in water, thermal and pressure...by the liquid throughout the bubble oscillations. The second mechanism is far less productive...

2000-01-01T23:59:59.000Z

393

High temperature liquid level sensor  

DOE Patents [OSTI]

A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.

Tokarz, Richard D. (West Richland, WA)

1983-01-01T23:59:59.000Z

394

2-M Probe Survey | Open Energy Information  

Open Energy Info (EERE)

2-M Probe Survey 2-M Probe Survey (Redirected from 2-M Probe) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: 2-M Probe Survey Details Activities (27) Areas (21) Regions (0) NEPA(3) Exploration Technique Information Exploration Group: Field Techniques Exploration Sub Group: Data Collection and Mapping Parent Exploration Technique: Data Collection and Mapping Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: Identify and delineate shallow thermal anomalies Cost Information Low-End Estimate (USD): 200.0020,000 centUSD 0.2 kUSD 2.0e-4 MUSD 2.0e-7 TUSD / station Median Estimate (USD): 300.0030,000 centUSD 0.3 kUSD 3.0e-4 MUSD 3.0e-7 TUSD / station High-End Estimate (USD): 500.0050,000 centUSD 0.5 kUSD 5.0e-4 MUSD

395

Modulated microwave microscopy and probes used therewith  

DOE Patents [OSTI]

A microwave microscope including a probe tip electrode vertically positionable over a sample and projecting downwardly from the end of a cantilever. A transmission line connecting the tip electrode to the electronic control system extends along the cantilever and is separated from a ground plane at the bottom of the cantilever by a dielectric layer. The probe tip may be vertically tapped near or at the sample surface at a low frequency and the microwave signal reflected from the tip/sample interaction is demodulated at the low frequency. Alternatively, a low-frequency electrical signal is also a non-linear electrical element associated with the probe tip to non-linearly interact with the applied microwave signal and the reflected non-linear microwave signal is detected at the low frequency. The non-linear element may be semiconductor junction formed near the apex of the probe tip or be an FET formed at the base of a semiconducting tip.

Lai, Keji; Kelly, Michael; Shen, Zhi-Xun

2012-09-11T23:59:59.000Z

396

Surface sampling concentration and reaction probe  

DOE Patents [OSTI]

A method of analyzing a chemical composition of a specimen is described. The method can include providing a probe comprising an outer capillary tube and an inner capillary tube disposed co-axially within the outer capillary tube, where the inner and outer capillary tubes define a solvent capillary and a sampling capillary in fluid communication with one another at a distal end of the probe; contacting a target site on a surface of a specimen with a solvent in fluid communication with the probe; maintaining a plug volume proximate a solvent-specimen interface, wherein the plug volume is in fluid communication with the probe; draining plug sampling fluid from the plug volume through the sampling capillary; and analyzing a chemical composition of the plug sampling fluid with an analytical instrument. A system for performing the method is also described.

Van Berkel, Gary J; Elnaggar, Mariam S

2013-07-16T23:59:59.000Z

397

Variable Temperature Scanning Probe Microscope | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

EMSL's ultra-high vacuum, variable-temperature scanning probe microscope system, or UHV VT SPM, is a state-of-the-art surface science tool comprising multiple complementary...

398

Interferometric Probes of Many-Body Localization  

E-Print Network [OSTI]

We propose a method for detecting many-body localization (MBL) in disordered spin systems. The method involves pulsed coherent spin manipulations that probe the dephasing of a given spin due to its entanglement with a set ...

Knap, M.

399

Catheter based magnetic resonance compatible perfusion probe  

E-Print Network [OSTI]

Neurosurgeons are using a thermal based technique to quantify brain perfusion. The thermal diffusion probe (TDP) technology measures perfusion in a relatively small volume of brain tissue. The neurosurgeon chooses the ...

Toretta, Cara Lynne

2007-01-01T23:59:59.000Z

400

1.0 GAS TRANSFER An important process used in water and wastewater treatment. Also very important when  

E-Print Network [OSTI]

of H2S in septic sewers causing pipe corrosion. 2. CO2 Stripping of some ground waters, industrial1.0 GAS TRANSFER An important process used in water and wastewater treatment. Also very important wastewaters to the stream. Gas/Liquid Interface Gas Liquid Gas transfer to the liquid is absorption Gas

Stenstrom, Michael K.

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

AdHoc Probe: End-to-end Capacity Probing in Wireless Ad Hoc Networks  

E-Print Network [OSTI]

AdHoc Probe: End-to-end Capacity Probing in Wireless Ad Hoc Networks Ling-Jyh Chen1 , Tony Sun2 and systematic study in ad hoc, multihop wireless networks is still lacking. Yet the rate of a wireless link can deployment. In this paper, we present AdHoc Probe, a packet-pair based technique, to estimate end-to-end path

Chen, Ling-Jyh

402

Ion Distributions Near a Liquid-Liquid Interface  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ion Distributions Near a Liquid-Liquid Interface Ion Distributions Near a Liquid-Liquid Interface Researchers from the University of Illinois at Chicago; Northern Illinois University; the University of California, Santa Cruz; and ChemMatCARS (sector 15 at the APS) used x-ray reflectivity from ion distributions at the liquid-liquid interface to provide strong evidence that the interfacial structure of a liquid alters the ion distributions near a charged interface, contrary to earlier theories about ions at charged surfaces. Coulomb's Law describes the interaction between two, otherwise isolated, point charges. If many charges are present in the region between these two charges, the net interaction between them is modified. This is commonly found in real systems, such as a plasma gas of electrons and ionized

403

Frostbite Theater - Liquid Nitrogen Experiments - Let's Freeze Liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Shattering Pennies! Shattering Pennies! Previous Video (Shattering Pennies!) Frostbite Theater Main Index Next Video (Liquid Nitrogen in a Microwave!) Liquid Nitrogen in a Microwave! Let's Freeze Liquid Nitrogen! By removing the hottest molecules, we're able to freeze liquid nitrogen! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: Today, we're going to freeze liquid nitrogen! Joanna and Steve: Yeah! Joanna: The obvious way to do this is to put the liquid nitrogen into something colder. Something that we have lots of around here! Something like... liquid helium! Steve: Yes! Joanna: Yeah, but we're not going to do that. Instead, we're going to freeze the nitrogen by removing the hottest molecules!

404

A simple system for nutritional studies with chronic consumption of liquid diet in rats  

E-Print Network [OSTI]

Short note A simple system for nutritional studies with chronic consumption of liquid diet in rats to rats without any loss by evapora- tion is described. A liquid diet stirred continuously is offered to rats in water bottles. The diet is made available to the animals without any clotting throughout the 24

Paris-Sud XI, Université de

405

Selection and use of equipment for the sampling of liquids  

SciTech Connect (OSTI)

The selection of sampling equipment for the collection of liquid waste is based on factors such as the viscosity of the sample matrix, matrix compatibility with the construction materials of the sampling device, and the physical location of the sampling point. This report provides information relating to sampling from such matrices as ground and surface waters, vadose zones, containerized liquids, lagoons, and seeps. It is intended to be a reference tool for personnel involved with the collection of liquid samples throughout the Department of Energy complex. This report provides a general overview of many liquid sampling devices used and for each device it provides a short narrative regarding applicability, an outline of the basic procedure for use, a list of advantages and disadvantages, and an illustration.

Johnson, M.

1995-11-01T23:59:59.000Z

406

Fiber optic probe for light scattering measurements  

DOE Patents [OSTI]

This invention is comprised of a fiber optic probe and a method for using the probe for light scattering analyses of a sample. The probe includes a probe body with an inlet for admitting a sample into an interior sample chamber, a first optical fiber for transmitting light from a source into the chamber, and a second optical fiber for transmitting light to a detector such as a spectrophotometer. The interior surface of the probe carries a coating that substantially prevents non-scattered light from reaching the second fiber. The probe is placed in a region where the presence and concentration of an analyte of interest are to be detected, and a sample is admitted into the chamber. Exciting light is transmitted into the sample chamber by the first fiber, where the light interacts with the sample to produce Raman-scattered light. At least some of the Raman- scattered light is received by the second fiber and transmitted to the detector for analysis. Two Raman spectra are measured, at different pressures. The first spectrum is subtracted from the second to remove background effects, and the resulting sample Raman spectrum is compared to a set of stored library spectra to determine the presence and concentration of the analyte.

Nave, S.E.; Livingston, R.R.; Prather, W.S.

1993-01-01T23:59:59.000Z

407

Fiber optic probe for light scattering measurements  

DOE Patents [OSTI]

A fiber optic probe and a method for using the probe for light scattering analyses of a sample. The probe includes a probe body with an inlet for admitting a sample into an interior sample chamber, a first optical fiber for transmitting light from a source into the chamber, and a second optical fiber for transmitting light to a detector such as a spectrophotometer. The interior surface of the probe carries a coating that substantially prevents non-scattered light from reaching the second fiber. The probe is placed in a region where the presence and concentration of an analyte of interest are to be detected, and a sample is admitted into the chamber. Exciting light is transmitted into the sample chamber by the first fiber, where the light interacts with the sample to produce Raman-scattered light. At least some of the Raman-scattered light is received by the second fiber and transmitted to the detector for analysis. Two Raman spectra are measured, at different pressures. The first spectrum is subtracted from the second to remove background effects, and the resulting sample Raman spectrum is compared to a set of stored library spectra to determine the presence and concentration of the analyte.

Nave, Stanley E. (Evans, GA); Livingston, Ronald R. (Aiken, SC); Prather, William S. (Augusta, GA)

1995-01-01T23:59:59.000Z

408

Graphene-coated tapered nanowire infrared probe: a comparison with metal-coated probes  

Science Journals Connector (OSTI)

We propose in this paper a graphene-coated tapered nanowire probe providing strong field enhancement in the infrared regimes. The analytical field distributions and characteristic...

Zhu, Bofeng; Ren, Guobin; Gao, Yixiao; Yang, Yang; Lian, Yudong; Jian, Shuisheng

2014-01-01T23:59:59.000Z

409

Application of holographic interferometry for determining the solubility of gases in liquids  

Science Journals Connector (OSTI)

The effect of a gas dissolved in a liquid on the variation ... sensitivity of this method allows the compressibility of water and the solubility of helium and nitrogen to be studied at pressures below 4 ... for o...

V. B. Konstantinov; A. F. Malyi; V. A. Babenko

2003-07-01T23:59:59.000Z

410

Determinants of Hospital's Financial Liquidity  

Science Journals Connector (OSTI)

Abstract The purpose of the articles is to identify key factors that may affect the level of hospital's liquidity ratio. We’ve posed four research hypotheses, assuming that, the level of financial liquidity in hospitals depends on several factors (number of beds, annual income per bed, profitability ratios, debt ratio). We’ve found that: 1) there is a positive relationship between debt ratio and liquidity and profitability ratio and liquidity 2) the relationship between the size of the hospital and the financial liquidity is not statistically significant. In the study we’ve use statistical tools: Pearson's correlation coefficient, T-Student's test with Cohran-Cox's correction.

Agnieszka Bem; Katarzyna Pr?dkiewicz; Pawe? Pr?dkiewicz; Paulina Ucieklak-Je?

2014-01-01T23:59:59.000Z

411

Methane Consumption in Temperate and Subarctic Forest Soils: Rates, Vertical Zonation, and Responses to Water and Nitrogen  

Science Journals Connector (OSTI)

...diffusive gas transport...sphere and the water content of...29). Soil nitrogen content and...Influence of nitrogen fertilization...in mineral waters with resorcinol...Low-pressure solubility of gases in liquid water. Chem. Rev...

A. P. S. Adamsen; G. M. King

1993-02-01T23:59:59.000Z

412

TiO2 Nanoparticles as a Soft X-ray Molecular Probe  

SciTech Connect (OSTI)

With the emergence of soft x-ray techniques for imaging cells, there is a pressing need to develop protein localization probes that can be unambiguously identified within the region of x-ray spectrum used for imaging. TiO2 nanocrystal colloids, which have a strong absorption cross-section within the "water-window" region of x-rays, areideally suited as soft x-ray microscopy probes. To demonstrate their efficacy, TiO2-streptavidin nanoconjugates were prepared and subsequently labeled microtubules polymerized from biotinylated tubulin. The microtubules were imaged using scanning transmission x-ray microscopy (STXM), and the TiO2 nanoparticle tags were specifically identified using x-ray absorption near edge spectroscopy (XANES). These experiments demonstrate that TiO2 nanoparticles are potential probes for protein localization analyses using soft x-ray microscopy.

Larabell, Carolyn; Ashcroft, Jared M.; Gu, Weiwei; Zhang, Tierui; Hughes, Steven M.; Hartman, Keith B.; Hofmann, Cristina; Kanaras, Antonios G.; Kilcoyne, David A.; Le Gros, Mark; Yin, Yadong; Alivisatos, A. Paul; Larabell, Carolyn A.

2007-06-30T23:59:59.000Z

413

Method of treating waste water  

DOE Patents [OSTI]

A process of treating water to remove metal ion contaminants contained therein, said metal ion contaminants selected from the group consisting of metals in Groups 8, 1b, 2b, 4a, 5a, or 6a of the periodic table, lanthanide metals, and actinide metals including transuranic element metals, by adjusting the pH of a metal ion contaminant-containing water source to within the range of about 6.5 to about 14.0, admixing the water source with a mixture of an alkali or alkaline earth ferrate and a water soluble salt, e.g., a zirconium salt, in an amount sufficient to form a precipitate within the water source, the amount the mixture of ferrate and water soluble salt effective to reduce the metal ion contaminant concentration in the water source, permitting the precipitate in the admixture to separate and thereby yield a supernatant liquid having a reduced metal ion contaminant concentration, and separating the supernatant liquid having the reduced metal ion contaminant concentration from the admixture is provided. A composition of matter including an alkali or alkaline earth ferrate and a water soluble salt, e.g., a zirconium salt, is also provided.

Deininger, James P. (Colorado Springs, CO); Chatfield, Linda K. (Colorado Springs, CO)

1995-01-01T23:59:59.000Z

414

Magnetic stabilization and vorticity in submillimeter paramagnetic liquid tubes  

Science Journals Connector (OSTI)

...this can be easily understood from the diagrams in Fig. 4. The field gradient...paramagnetic liquid is colored pink in the diagrams, and the water pale blue. The magnetization...2001 ) A minute magnetohydrodynamic (MHD) stirrer . Sensors Actuators B 79 : 207...

J. Michael D. Coey; Ryoichi Aogaki; Fiona Byrne; Plamen Stamenov

2009-01-01T23:59:59.000Z

415

Quantal Ising Liquid  

Science Journals Connector (OSTI)

An example is presented of a model of an amorphous quantum mechanical system, a liquid of quantal Ising spins, which can be solved exactly within certain many-body theories. Analytical solutions of the model in mean-field theory are shown to reveal a decrease in the extent of the ferromagnetic region (compared to an equivalent classical system) and the occurrence of some degree of quantum localization. Both phenomena are analyzed as a competition between quantum mechanics and the condensed phase.

Richard M. Stratt

1984-10-01T23:59:59.000Z

416

RHIC The Perfect Liquid  

ScienceCinema (OSTI)

Evidence to date suggests that gold-gold collisions the Relativistic Heavy Ion Collider at Brookhaven are indeed creating a new state of hot, dense matter, but one quite different and even more remarkable than had been predicted. Instead of behaving like a gas of free quarks and gluons, as was expected, the matter created in RHIC's heavy ion collisions appears to be more like a "perfect" liquid.

BNL

2009-09-01T23:59:59.000Z

417

Theory of fermion liquids  

Science Journals Connector (OSTI)

We develop a general theory of fermion liquids in spatial dimensions greater than 1. The principal method, bosonization, is applied to the cases of short- and long-range longitudinal interactions and to transverse gauge interactions. All the correlation funtions of the system may be obtained with the use of a generating functional. Short-range and Coulomb interactions do not destroy the Landau-Fermi fixed point. Non-Fermi liquid fixed points are found, however, in the cases of a super-long-range longitudinal interaction in two dimensions and transverse gauge interactions in two and three spatial dimensions. We consider in some detail the (2+1)-dimensional problem of a Chern-Simons gauge action combined with a longitudinal two-body interaction V(q)??q?y-1, which controls the density, and hence gauge, fluctuations. For y0 the interaction is relevant and the fixed point cannot be accessed by bosonization. Of special importance is the case y=0 (Coulomb interaction), which describes the Halperin-Lee-Read theory of the half-filled Landau level. We obtain the full quasiparticle propagator, which is of a marginal Fermi-liquid form. Using Ward identities, we show that neither the inclusion of nonlinear terms in the fermion dispersion nor vertex corrections alters our results: the fixed point is accessible by bosonization. As the two-point fermion Green’s function is not gauge invariant, we also invetigate the gauge-invariant density response function. Near momentum Q=2kF, in addition to the Kohn anomaly we find other nonanalytic behavior. In the appendies we present a numerical calculation of the spectral function for a Fermi liquid with Landau parameter f0?0. We also show how Kohn’s theorem is satisfied within the bosonization framework.

H.-J. Kwon; A. Houghton; J. B. Marston

1995-09-15T23:59:59.000Z

418

What constitutes a simple liquid?  

E-Print Network [OSTI]

Simple liquids are traditionally defined as many-body systems of classical particles interacting via radially symmetric pair potentials. We suggest that a simple liquid should be defined instead by the property of having strong correlation between virial and potential energy equilibrium fluctuations in the NVT ensemble. There is considerable overlap between the two definitions, but also some notable differences. For instance, in the new definition simplicity is not a property of the intermolecular potential only because a liquid is usually only strongly correlating in part of its phase diagram. Moreover, according to the new definition not all simple liquids are atomic (i.e., with radially symmetric pair potentials) and not all atomic liquids are simple. The main part of the paper motivates the new definition of liquid simplicity by presenting evidence that a liquid is strongly correlating if and only if its intermolecular interactions may be ignored beyond the first coordination shell (FCS). This is demonstrated by NVT simulations of structure and dynamics of 15 atomic and molecular model liquids with a shifted-forces cutoff placed at the first minimum of the radial distribution function. No proof is given that the chemical characterization follows from the strong correlation property, but it is shown to be consistent with the existence of isomorphs in strongly correlating liquids' phase diagram. Finally, we note that the FCS characterization of simple liquids calls into question the basis for standard perturbation theory, according to which the repulsive and attractive forces play fundamentally different roles for the physics of liquids.

Trond S. Ingebrigtsen; Thomas B. Schrøder; Jeppe C. Dyre

2011-11-15T23:59:59.000Z

419

Probing thermonuclear supernova explosions with neutrinos  

E-Print Network [OSTI]

Aims: We present neutrino light curves and energy spectra for two representative type Ia supernova explosion models: a pure deflagration and a delayed detonation. Methods: We calculate the neutrino flux from $\\beta$ processes using nuclear statistical equilibrium abundances convoluted with approximate neutrino spectra of the individual nuclei and the thermal neutrino spectrum (pair+plasma). Results: Although the two considered thermonuclear supernova explosion scenarios are expected to produce almost identical electromagnetic output, their neutrino signatures appear vastly different, which allow an unambiguous identification of the explosion mechanism: a pure deflagration produces a single peak in the neutrino light curve, while the addition of the second maximum characterizes a delayed-detonation. We identified the following main contributors to the neutrino signal: (1) weak electron neutrino emission from electron captures (in particular on the protons Co55 and Ni56) and numerous beta-active nuclei produced by the thermonuclear flame and/or detonation front, (2) electron antineutrinos from positron captures on neutrons, and (3) the thermal emission from pair annihilation. We estimate that a pure deflagration supernova explosion at a distance of 1 kpc would trigger about 14 events in the future 50 kt liquid scintillator detector and some 19 events in a 0.5 Mt water Cherenkov-type detector. Conclusions: While in contrast to core-collapse supernovae neutrinos carry only a very small fraction of the energy produced in the thermonuclear supernova explosion, the SN Ia neutrino signal provides information that allows us to unambiguously distinguish between different possible explosion scenarios. These studies will become feasible with the next generation of proposed neutrino observatories.

A. Odrzywolek; T. Plewa

2011-03-27T23:59:59.000Z

420

Liquid fossil fuel technology  

SciTech Connect (OSTI)

Progress reports are presented under the following headings: (1) extraction (technology assessment, oil research, gas research); (2) liquid processing (characterization, thermodynamics, processing technology); (3) utilization (energy conservation); and (4) project integration and technology transfer. BETC publications are also listed. Some of the highlights for this period are: the Bartlesville Energy Technology Center was converted into NIPER, the National Institute for Petroleum and Energy Research on October 1, 1983; modelling of enthalpies, heat capacities and volumes of aqueous surfactant solutions began using a mass action model; a series of experiments were run on upgrading by hydrogenation SRC-II coal liquid at different degrees of severity and the products have been analyzed; heavy crude oil extracts were separated into fraction with high performance liquid chromatography by Lawrence Berkeley Laboratory and the mass spectra and electron spin resonance were determin ed; and particulates from exhaust gases of diesel engines using fire fuel types are being collected and will be analyzed by chemical methods and results will be compared with those obtained by biological assay. (ATT)

Not Available

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Removal of nitrogen and phosphorus from reject water of municipal wastewater treatment plant.  

E-Print Network [OSTI]

??Reject water, the liquid fraction produced after dewatering of anaerobically digested activated sludge on a municipal wastewater treatment plant (MWWTP), contains from 750 to 1500… (more)

Guo, Chenghong

2011-01-01T23:59:59.000Z

422

Liquid Phases Used in Packed Gas Chromatographic Columns. Part II. Use of Liquid Phases Which Are Not Polysiloxanes  

Science Journals Connector (OSTI)

......as well as trace water, be removed from the carrier gas by using suitable...in the carrier gas lines. There is...bottles out with nitrogen and seal the filled...liquid phases in gas chromatography...Superoxes show low solubility in the common organic......

Joel A. Yancey

1985-08-01T23:59:59.000Z

423

Water Evaporation: A Transition Path Sampling Study  

E-Print Network [OSTI]

We use transition path sampling to study evaporation in the SPC/E model of liquid water. Based on thousands of evaporation trajectories, we characterize the members of the transition state ensemble (TSE), which exhibit a liquid-vapor interface with predominantly negative mean curvature at the site of evaporation. We also find that after evaporation is complete, the distributions of translational and angular momenta of the evaporated water are Maxwellian with a temperature equal to that of the liquid. To characterize the evaporation trajectories in their entirety, we find that it suffices to project them onto just two coordinates: the distance of the evaporating molecule to the instantaneous liquid-vapor interface, and the velocity of the water along the average interface normal. In this projected space, we find that the TSE is well-captured by a simple model of ballistic escape from a deep potential well, with no additional barrier to evaporation beyond the cohesive strength of the liquid. Equivalently, they are consistent with a near-unity probability for a water molecule impinging upon a liquid droplet to condense. These results agree with previous simulations and with some, but not all, recent experiments.

Patrick Varilly; David Chandler

2012-10-11T23:59:59.000Z

424

Frostbite Theater - Liquid Nitrogen Experiments - Let's Pour Liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Shattering Flowers! Shattering Flowers! Previous Video (Shattering Flowers!) Frostbite Theater Main Index Next Video (Giant Koosh Ball!) Giant Koosh Ball! Let's Pour Liquid Nitrogen on the Floor! Liquid nitrogen?! On the floor?! Who's going to clean that mess up?! See what really happens when one of the world's most beloved cryogenic liquids comes into contact with a room temperature floor. [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: From time to time, we spill a little liquid nitrogen! The reaction we sometimes get is.... Shannon: Did they just pour LIQUID NITROGEN on the FLOOR?!?! Joanna: Yes. Yes we did. Steve: One thing people seem to have a problem with is the mess that liquid

425

Water Electrolysis  

Science Journals Connector (OSTI)

In this chapter, water electrolysis technology and its applications for nuclear hydrogen ... of the chapter, a general classification of water electrolysis systems is given, the fundamentals of water electrolysis

Greg F. Naterer; Ibrahim Dincer…

2013-01-01T23:59:59.000Z

426

Water Intoxication  

E-Print Network [OSTI]

2008, May 14). Too much water raises seizure risk in babies.id=4844 9. Schoenly, Lorry. “Water Intoxication and Inmates:article/246650- overview>. 13. Water intoxication alert. (

Lingampalli, Nithya

2013-01-01T23:59:59.000Z

427

Method of treating waste water  

DOE Patents [OSTI]

A process of treating water to remove transuranic elements contained therein by adjusting the pH of a transuranic element-containing water source to within the range of about 6.5 to about 14.0, admixing the water source with an alkali or alkaline earth ferrate in an amount sufficient to form a precipitate within the water source, the amount of ferrate effective to reduce the transuranic element concentration in the water source, permitting the precipitate in the admixture to separate and thereby yield a supernatant liquid having a reduced transuranic element concentration, and separating the supernatant liquid having the reduced transuranic element concentration from the admixture is provided. Additionally, a water soluble salt, e.g., a zirconium salt, can be added with the alkali or alkaline earth ferrate in the process to provide greater removal efficiencies. A composition of matter including an alkali or alkaline earth ferrate and a water soluble salt, e.g., a zirconium salt, is also provided.

Deininger, J. Paul (Colorado Springs, CO); Chatfield, Linda K. (Colorado Springs, CO)

1991-01-01T23:59:59.000Z

428

A Better Way to Probe Biological Polymorphs | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Composite Battery Boost Composite Battery Boost Water-Like Properties of Soft Nanoparticle Suspensions Real-Time Capture of Intermediates in Enzymatic Reactions A New Multilayer-Based Grating for Hard X-ray Grating Interferometry The Most Detailed Picture Yet of a Key AIDS Protein Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed A Better Way to Probe Biological Polymorphs December 3, 2013 Bookmark and Share The byssus of the bivalve Anomia simplex provides the anchor between mussel and substrate. Panel A shows a schematic cross-section of the animal (left) and (right) a three-dimensional micro-computed-tomography rendering of the mineralized byssus. The red lines mark three layers that were investigated

429

Protein structure and hydration probed by SANS and osmotic stress  

SciTech Connect (OSTI)

Interactions governing protein folding, stability, recognition, and activity are mediated by hydration. Here, we use small-angle neutron scattering coupled with osmotic stress to investigate the hydration of two proteins, lysozyme and guanylate kinase (GK), in the presence of solutes. By taking advantage of the neutron contrast variation that occurs upon addition of these solutes, the number of protein-associated (solute-excluded) water molecules can be estimated from changes in both the zero-angle scattering intensity and the radius of gyration. Poly(ethylene glycol) exclusion varies with molecular weight. This sensitivity can be exploited to probe structural features such as the large internal GK cavity. For GK, small-angle neutron scattering is complemented by isothermal titration calorimetry with osmoticstress to also measure hydration changes accompanying ligand binding. These results provide a framework for studying other biomolecular systems and assemblies using neutron scattering together with osmotic stress.

Rau, Dr. Donald [National Institutes of Health

2008-01-01T23:59:59.000Z

430

The Use of Stable Isotope Labeling and Liquid Chromatography—Tandem Mass Spectrometry Techniques To Simultaneously Determine the Oral and Ophthalmic Bioavailability of Timolol in Dogs  

Science Journals Connector (OSTI)

......liquid chromatography with atmospheric-pressure chemical-ionization...Phillipsburg, NJ). Water (deionized) was generated using a Barnstead generator (Dubuque, IA). Dosing...solution of its maleate salt in water at a concentration of 0......

J.D. Gilbert; T.V. Olah; M.J. Morris; A. Bortnick; J. Brunner

1998-04-01T23:59:59.000Z

431

A fresh look at coal-derived liquid fuels  

SciTech Connect (OSTI)

35% of the world's energy comes from oil, and 96% of that oil is used for transportation. The current number of vehicles globally is estimated to be 700 million; that number is expected to double overall by 2030, and to triple in developing countries. Now consider that the US has 27% of the world's supply of coal yet only 2% of the oil. Coal-to-liquids technologies could bridge the gap between US fuel supply and demand. The advantages of coal-derived liquid fuels are discussed in this article compared to the challenges of alternative feedstocks of oil sands, oil shale and renewable sources. It is argued that pollutant emissions from coal-to-liquid facilities could be minimal because sulfur compounds will be removed, contaminants need to be removed for the FT process, and technologies are available for removing solid wastes and nitrogen oxides. If CO{sub 2} emissions for coal-derived liquid plants are captured and sequestered, overall emissions of CO{sub 2} would be equal or less than those from petroleum. Although coal liquefaction requires large volumes of water, most water used can be recycled. Converting coal to liquid fuels could, at least in the near term, bring a higher level of stability to world oil prices and the global economy and could serve as insurance for the US against price hikes from oil-producing countries. 7 figs.

Paul, A.D. [Benham Companies LLC (USA)

2009-01-15T23:59:59.000Z

432

Radiation Chemistry of Ionic Liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Liquids Liquids James F. Wishart, Alison M. Funston, and Tomasz Szreder in "Molten Salts XIV" Mantz, R. A., et al., Eds.; The Electrochemical Society, Pennington, NJ, (2006) pp. 802-813. [Information about the volume (look just above this link)] Abstract: Ionic liquids have potentially important applications in nuclear fuel and waste processing, energy production, improving the efficiency and safety of industrial chemical processes, and pollution prevention. Successful use of ionic liquids in radiation-filled environments will require an understanding of ionic liquid radiation chemistry. For example, characterizing the primary steps of ionic liquid radiolysis will reveal radiolytic degradation pathways and suggest ways to prevent them or mitigate their effects on the properties of the material

433

Microscopic Analysis of Corn Fiber Using Corn Starch- and Cellulose-Specific Molecular Probes  

SciTech Connect (OSTI)

Ethanol is the primary liquid transportation fuel produced from renewable feedstocks in the United States today. The majority of corn grain, the primary feedstock for ethanol production, has been historically processed in wet mills yielding products such as gluten feed, gluten meal, starch, and germ. Starch extracted from the grain is used to produce ethanol in saccharification and fermentation steps; however the extraction of starch is not 100% efficient. To better understand starch extraction during the wet milling process, we have developed fluorescent probes that can be used to visually localize starch and cellulose in samples using confocal microscopy. These probes are based on the binding specificities of two types of carbohydrate binding modules (CBMs), which are small substrate-specific protein domains derived from carbohydrate degrading enzymes. CBMs were fused, using molecular cloning techniques, to a green fluorescent protein (GFP) or to the red fluorescent protein DsRed (RFP). Using these engineered probes, we found that the binding of the starch-specific probe correlates with starch content in corn fiber samples. We also demonstrate that there is starch internally localized in the endosperm that may contribute to the high starch content in corn fiber. We also surprisingly found that the cellulose-specific probe did not bind to most corn fiber samples, but only to corn fiber that had been hydrolyzed using a thermochemical process that removes the residual starch and much of the hemicellulose. Our findings should be of interest to those working to increase the efficiency of the corn grain to ethanol process.

Porter, S. E.; Donohoe, B. S.; Beery, K. E.; Xu, Q.; Ding, S.-Y.; Vinzant, T. B.; Abbas, C. A.; Himmel, M. E.

2007-09-01T23:59:59.000Z

434

Lightning strokes can probe the ionosphere  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lightning Strokes Can Probe Ionosphere Lightning Strokes Can Probe Ionosphere Lightning strokes can probe the ionosphere Researchers have made measurements during thunderstorms to study the affect of lightning on the lower ionosphere and radiofrequency signals. April 11, 2013 Lightning. Credit: National Oceanic and Atmospheric Administration (NOAA) The team found that the electron density in the lower ionosphere decreased in response to lightning discharges. Thunderstorms, and the resulting partially ionized plasma of the ionosphere, can distort radio signals traveling to satellites important to communications, navigation or national security Los Alamos researchers and a collaborator have made measurements during thunderstorms to study the affect of lightning on the lower ionosphere and radiofrequency signals. This study supports one theory for how tropospheric

435

Probing Organic Transistors with Infrared Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing Organic Transistors with Infrared Beams Print Probing Organic Transistors with Infrared Beams Print Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also have the advantage of being easy to mass-produce at very low cost. However, even though this class of devices is finding a growing number of applications, electronic processes in organic materials are still not well understood. A group of researchers from the University of California and the ALS has succeeded in probing the intrinsic electronic properties of the charge carriers in organic FETs using infrared spectromicroscopy. The results of their study could help in the future development of sensors, large-area displays, and other plastic electronic components.

436

Lightning strokes can probe the ionosphere  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lightning Strokes Can Probe Ionosphere Lightning Strokes Can Probe Ionosphere Lightning strokes can probe the ionosphere Researchers have made measurements during thunderstorms to study the affect of lightning on the lower ionosphere and radiofrequency signals. April 11, 2013 Lightning. Credit: National Oceanic and Atmospheric Administration (NOAA) The team found that the electron density in the lower ionosphere decreased in response to lightning discharges. Thunderstorms, and the resulting partially ionized plasma of the ionosphere, can distort radio signals traveling to satellites important to communications, navigation or national security Los Alamos researchers and a collaborator have made measurements during thunderstorms to study the affect of lightning on the lower ionosphere and radiofrequency signals. This study supports one theory for how tropospheric

437

Gamma-ray blind beta particle probe  

DOE Patents [OSTI]

An intra-operative beta particle probe is provided by placing a suitable photomultiplier tube (PMT), micro channel plate (MCP) or other electron multiplier device within a vacuum housing equipped with: 1) an appropriate beta particle permeable window; and 2) electron detection circuitry. Beta particles emitted in the immediate vicinity of the probe window will be received by the electron multiplier device and amplified to produce a detectable signal. Such a device is useful as a gamma insensitive, intra-operative, beta particle probe in surgeries where the patient has been injected with a beta emitting radiopharmaceutical. The method of use of such a device is also described, as is a position sensitive such device.

Weisenberger, Andrew G. (Grafton, VA)

2001-01-01T23:59:59.000Z

438

2-M Probe Survey | Open Energy Information  

Open Energy Info (EERE)

2-M Probe Survey 2-M Probe Survey Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Technique: 2-M Probe Survey Details Activities (27) Areas (21) Regions (0) NEPA(3) Exploration Technique Information Exploration Group: Field Techniques Exploration Sub Group: Data Collection and Mapping Parent Exploration Technique: Data Collection and Mapping Information Provided by Technique Lithology: Stratigraphic/Structural: Hydrological: Thermal: Identify and delineate shallow thermal anomalies Cost Information Low-End Estimate (USD): 200.0020,000 centUSD 0.2 kUSD 2.0e-4 MUSD 2.0e-7 TUSD / station Median Estimate (USD): 300.0030,000 centUSD 0.3 kUSD 3.0e-4 MUSD 3.0e-7 TUSD / station High-End Estimate (USD): 500.0050,000 centUSD 0.5 kUSD 5.0e-4 MUSD 5.0e-7 TUSD / station

439

2-M Probe At Salt Wells Area (Shevenell, Et Al., 2008) | Open Energy  

Open Energy Info (EERE)

Wells Area (Shevenell, Et Al., 2008) Wells Area (Shevenell, Et Al., 2008) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: 2-M Probe At Salt Wells Area (Shevenell, Et Al., 2008) Exploration Activity Details Location Salt Wells Area Exploration Technique 2-M Probe Activity Date Usefulness useful DOE-funding Unknown Notes One additional method may be used in the future to locate blind geothermal systems. Several thousand shallow (12") temperature measurements were made for a study conducted at Salt Wells in collaboration with Amp Resources (prior to their being acquired by Enel). After a strong, structurally controlled thermal anomaly was identified on the north end of the study area, a 2 m hole was dug into a playa in which the water temperature at the bottom of the hole was 84.8°C. Water was allowed to collect in the bottom

440

Examination of Liquid Fluoride Salt Heat Transfer  

SciTech Connect (OSTI)

The need for high efficiency power conversion and energy transport systems is increasing as world energy use continues to increase, petroleum supplies decrease, and global warming concerns become more prevalent. There are few heat transport fluids capable of operating above about 600oC that do not require operation at extremely high pressures. Liquid fluoride salts are an exception to that limitation. Fluoride salts have very high boiling points, can operate at high temperatures and low pressures and have very good heat transfer properties. They have been proposed as coolants for next generation fission reactor systems, as coolants for fusion reactor blankets, and as thermal storage media for solar power systems. In each case, these salts are used to either extract or deliver heat through heat exchange equipment, and in order to design this equipment, liquid salt heat transfer must be predicted. This paper discusses the heat transfer characteristics of liquid fluoride salts. Historically, heat transfer in fluoride salts has been assumed to be consistent with that of conventional fluids (air, water, etc.), and correlations used for predicting heat transfer performance of all fluoride salts have been the same or similar to those used for water conventional fluids an, water, etc). A review of existing liquid salt heat transfer data is presented, summarized, and evaluated on a consistent basis. Less than 10 experimental data sets have been found in the literature, with varying degrees of experimental detail and measured parameters provided. The data has been digitized and a limited database has been assembled and compared to existing heat transfer correlations. Results vary as well, with some data sets following traditional correlations; in others the comparisons are less conclusive. This is especially the case for less common salt/materials combinations, and suggests that additional heat transfer data may be needed when using specific salt eutectics in heat transfer equipment designs. All of the data discussed above were taken under forced convective conditions (both laminar and turbulent). Some recent data taken at ORNL under free convection conditions are also presented and results discussed. This data was taken using a simple crucible experiment with an instrumented nickel heater inserted in the salt to induce natural circulation within the crucible. The data was taken over a temperature range of 550oC to 650oC in FLiNaK salt. This data covers both laminar and turbulent natural convection conditions, and is compared to existing forms of natural circulation correlations.

Yoder Jr, Graydon L [ORNL] [ORNL

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Process for preparing liquid wastes  

DOE Patents [OSTI]

A process for preparing radioactive and other hazardous liquid wastes for treatment by the method of vitrification or melting is provided for.

Oden, Laurance L. (Albany, OR); Turner, Paul C. (Albany, OR); O'Connor, William K. (Lebanon, OR); Hansen, Jeffrey S. (Corvallis, OR)

1997-01-01T23:59:59.000Z

442

FLARE, Fermilab Liquid Argon Experiments  

E-Print Network [OSTI]

Mature technology of Liquid Argon Time Projection Chambers in conjunction with intense neutrino beams constructed at Fermilab offer a broad program of neutrino physics for the next decade.

L. Bartoszek

2004-08-24T23:59:59.000Z

443

Polarizable molecules in the vibrational spectroscopy of water  

E-Print Network [OSTI]

correlation functions and transport properties of liquid water that were im- pressive for their time. Stillinger (2) described the peculiar chemical and physical properties of water in terms of the microscopic bonding in water. The potential energy models developed in these early studies provided guidelines

Berne, Bruce J.

444

ARM - Measurement - Total cloud water  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cloud water cloud water ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Total cloud water The total concentration (mass/vol) of ice and liquid water particles in a cloud; this includes condensed water content (CWC). Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded for diagnostic or quality assurance purposes. External Instruments NCEPGFS : National Centers for Environment Prediction Global Forecast System Field Campaign Instruments CSI : Cloud Spectrometer and Impactor PDI : Phase Doppler Interferometer

445

Model of a nuclear - optically - pumped liquid laser  

SciTech Connect (OSTI)

The model of a nuclear - optically - pumped liquid laser is constructed and the laser characteristics are analysed for different parameters of the setup and pump pulse, compositions of the converter media and active elements. The lasing parameters of the liquid laser using heavy-water solution of {sup 245}Cm as the converter medium and neodymium-containing phosphorous oxychloride (phosphoryl chloride) as the active element are calculated. It follows from the results of calculations that lasing can be achieved in these media pumped by neutrons from the BARS-6 reactor. (lasers)

Seregin, A A; D'yachenko, P P; Seregina, E A [State Scientific Center of the Russian Federation 'A.I. Leipunski Institute for Physics and Power Engineering', Obninsk, Kaluga Region (Russian Federation)

2003-06-30T23:59:59.000Z

446

Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems  

E-Print Network [OSTI]

interest in subcritical (hot/liquid) water from 298 K to 473subcritical region. Modeling Studies on the Transport of Benzene and H 2 S in CO 2 -Water

Zheng, L.

2011-01-01T23:59:59.000Z

447

CONDENSATION As noted previously, heat energy imparted to water as it  

E-Print Network [OSTI]

CONDENSATION As noted previously, heat energy imparted to water as it evaporates is returned to liquid water as vapor condenses. During low tide, the rate of evaporation typically exceeds the rate

Brody, James P.

448

Dynamics of water and aqueous protons studied using ultrafast multi-dimensional infrared spectroscopy  

E-Print Network [OSTI]

Liquid water consists of a highly dynamic network of hydrogen bonds, which evolves on timescales ranging from tens of femtoseconds to a few picoseconds. The fast structural evolution of water's hydrogen bond network is at ...

Ramasesha, Krupa

2013-01-01T23:59:59.000Z

449

Using Caenorhabditis elegans to probe toxicity of 1-alkyl-3-methylimidazolium chloride based ionic liquids  

E-Print Network [OSTI]

are gaining attention as new solvents within the green chemistry community; however this attention has quickly attention as new solvents within the green chemistry community.1 This attention is due in part 35487, USA. E-mail: RDRogers@bama.ua.edu; Fax: 205-348-0823; Tel: 205-348-4323 b Center for Green

Caldwell, Guy

450

Testing dark energy with the Advanced Liquid-mirror Probe of Asteroids, Cosmology and Astrophysics  

Science Journals Connector (OSTI)

......Papers Testing dark energy with the Advanced...Columbia University, New York, NY 10027, USA 2...Columbia University, New York, NY 10027, USA 3...Columbia University, New York, NY 10027, USA 4...for studying dark energy. The bulk of the......

Pier Stefano Corasaniti; Marilena LoVerde; Arlin Crotts; Chris Blake

2006-06-21T23:59:59.000Z

451

Testing dark energy with the Advanced Liquid-mirror Probe of Asteroids, Cosmology and Astrophysics  

Science Journals Connector (OSTI)

......the constraints on dark energy from the estimated...duration of the survey, and from the expected...coverage of the survey, these measurements...competitive constraints on dark energy parameters (Pogosian...al. 2005). The survey will also provide......

Pier Stefano Corasaniti; Marilena LoVerde; Arlin Crotts; Chris Blake

2006-06-21T23:59:59.000Z

452

Temperature-dependent vibrational relaxation in polyatomic liquids: Picosecond infrared pump-probe experiments  

E-Print Network [OSTI]

stretching vibration (-1980 cm-`) of Cr(CO), and W(CO& dissolved in carbon tetrachloride (Ccl hexacarbonyl [W(CO),] and chromium hexacarbonyl [Cr(CO),] in two solvents, carbon tetrachloride (CC14

Fayer, Michael D.

453

Frostbite Theater - Liquid Nitrogen Experiments - Liquid Nitrogen and Fire!  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Antifreeze! Antifreeze! Previous Video (Liquid Nitrogen and Antifreeze!) Frostbite Theater Main Index Next Video (Liquid Nitrogen and the Tea Kettle Mystery!) Liquid Nitrogen and the Tea Kettle Mystery! Liquid Nitrogen and Fire! A burning candle is placed in a container of liquid nitrogen! Filmed in front of a live studio audience. Well, they were live when we started... [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Steve: Now, then. I'm a little bit afraid to ask this next question because I think I already know the answer, but is anyone in here feeling a little... dangerous? You're willing to take a chance? Because I am willing to do an experiment they haven't let me do since 'The Incident.' Now, because of the danger, I cannot have a volunteer. I must do this on my

454

A new Diffractometer for Studies of Liquid-Liquid Interfaces  

SciTech Connect (OSTI)

We have designed a novel, dedicated diffractometer for surface x-ray scattering studies of liquid-liquid and liquid-gas interfaces for the PETRA III High Resolution Diffraction Beamline. Using a double crystal beam-tilter in Bragg geometry this new instrument enables reflectivity and grazing incidence diffraction investigations without moving the sample, which is mechanically decoupled from the rest of the diffractometer. This design minimizes external excitation of surface vibrations, a key prerequisite for studies of liquid interfaces. The instrument operates over the energy range 6.4 keV to 30 keV, the higher energy range being optimal for penetration through liquid sample environments. Vertical momentum transfer up to q{sub z} 2.5 A{sup -1} and lateral q{sub ||} up to 4 A{sup -1}will be available.

Murphy, B. M.; Greve, M.; Runge, B.; Koops, C. T.; Elsen, A.; Stettner, J.; Magnussen, O. M. [IEAP, Christian-Albrechts-Universitaet zu Kiel, D-24098 Kiel (Germany); Seeck, O. H. [PETRA III at DESY, Notkestr. 85, D-22603 Hamburg (Germany)

2010-06-23T23:59:59.000Z

455

Frostbite Theater - Liquid Nitrogen Experiments - Cells vs. Liquid  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Superconductors! Superconductors! Previous Video (Superconductors!) Frostbite Theater Main Index Next Video (Liquid Oxygen and Fire!) Liquid Oxygen and Fire! Cells vs. Liquid Nitrogen! Let's say you've carelessly dunked your hand into a vat of liquid nitrogen and let it freeze solid. Every movie you've seen where this happens tells you that your hand will shatter like fine china should you bump it into something. If you're extremely careful, will your hand be okay once it thaws out? We'll explore this issue, using flower and onion cells rather than our hands! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: By now, we all know what happens when you place a flower in liquid

456

Probing Organic Transistors with Infrared Beams  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Probing Organic Transistors with Probing Organic Transistors with Infrared Beams Probing Organic Transistors with Infrared Beams Print Wednesday, 26 July 2006 00:00 Silicon-based transistors are well-understood, basic components of contemporary electronic technology. In contrast, there is growing need for the development of electronic devices based on organic polymer materials. Organic field-effect transistors (FETs) are ideal for special applications that require large areas, light weight, and structural flexibility. They also have the advantage of being easy to mass-produce at very low cost. However, even though this class of devices is finding a growing number of applications, electronic processes in organic materials are still not well understood. A group of researchers from the University of California and the ALS has succeeded in probing the intrinsic electronic properties of the charge carriers in organic FETs using infrared spectromicroscopy. The results of their study could help in the future development of sensors, large-area displays, and other plastic electronic components.

457

Complementarity of future dark energy probes  

Science Journals Connector (OSTI)

......alternative to the standard figure of merit of a survey (Albrecht et al...actually a better figure of merit than the one put forward by...probes discussed have their merits, but weak lensing and baryon...simulation data. We sincerely thank Nick Kaiser for providing us information......

Jiayu Tang; Filipe B. Abdalla; Jochen Weller

2011-09-21T23:59:59.000Z

458

High temperature electrochemical corrosion rate probes  

SciTech Connect (OSTI)

Corrosion occurs in the high temperature sections of energy production plants due to a number of factors: ash deposition, coal composition, thermal gradients, and low NOx conditions, among others. Electrochemical corrosion rate (ECR) probes have been shown to operate in high temperature gaseous environments that are similar to those found in fossil fuel combustors. ECR probes are rarely used in energy production plants at the present time, but if they were more fully understood, corrosion could become a process variable at the control of plant operators. Research is being conducted to understand the nature of these probes. Factors being considered are values selected for the Stern-Geary constant, the effect of internal corrosion, and the presence of conductive corrosion scales and ash deposits. The nature of ECR probes will be explored in a number of different atmospheres and with different electrolytes (ash and corrosion product). Corrosion rates measured using an electrochemical multi-technique capabilities instrument will be compared to those measured using the linear polarization resistance (LPR) technique. In future experiments, electrochemical corrosion rates will be compared to penetration corrosion rates determined using optical profilometry measurements.

Bullard, Sophie J.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Ziomek-Moroz, M.

2005-09-01T23:59:59.000Z

459

Marketing water  

E-Print Network [OSTI]

management, water conservation programs Story by Kathy Wythe tx H2O | pg. 17 public information programs and materials that increase awareness about regional water issues. The company recently opened the TecH2O, a water resource learning center...tx H2O | pg. 16 W ith rapid population growth and the memory of the worst drought in 50 years, cities and groups are promoting programs that educate their constituents about water quality, water conservation, and landscape management. Many...

Wythe, Kathy

2008-01-01T23:59:59.000Z

460

Isotope Fractionation of Water during Evaporation without Condensation  

Science Journals Connector (OSTI)

Specifially, isotope fractionation factors associated with free evaporation (?evap) have been measured as a function of the isotopic composition and temperature of the liquid. ... Liquid-vapor fractionation of oxygen and hydrogen isotopes of water from the freezing to the critical temperature ...

Christopher D. Cappa; Walter S. Drisdell; Jared D. Smith; Richard J. Saykally; Ronald C. Cohen

2005-12-03T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Enhanced liquid hydrocarbon recovery process  

SciTech Connect (OSTI)

This patent describes a process for recovering liquid hydrocarbons. It comprises: injecting into a fractured subterranean formation a polymer enhanced foam comprising a polymer selected from a synthetic polymer or a biopolymer, a surfactant, an aqueous solvent and a gas, recovering liquid hydrocarbons from the formation.

Sydansk, R.D.

1992-07-14T23:59:59.000Z

462

Laboratory solvent reuse -- Liquid chromatography  

SciTech Connect (OSTI)

The objective of this work was to develop a method for reduction of waste solvent in the Process Engineering Chemistry Laboratory. The liquid chromatographs are the largest generators of explosive-contaminated waste in the laboratory. We developed a successful process for the reuse of solvents from the liquid chromatographs and demonstrated the utility of the process in the assay of hexanitrostilbene.

Quinlin, W.T.; Schaffer, C.L.

1992-11-01T23:59:59.000Z

463

Liquid-permeable electrode  

DOE Patents [OSTI]

Electrodes for use in an electrolytic cell, which are liquid-permeable and have low electrical resistance and high internal surface area are provided of a rigid, porous, carbonaceous matrix having activated carbon uniformly embedded throughout. The activated carbon may be catalyzed with platinum for improved electron transfer between electrode and electrolyte. Activated carbon is mixed with a powdered thermosetting phenolic resin and compacted to the desired shape in a heated mold to melt the resin and form the green electrode. The compact is then heated to a pyrolyzing temperature to carbonize and volatilize the resin, forming a rigid, porous structure. The permeable structure and high internal surface area are useful in electrolytic cells where it is necessary to continuously remove the products of the electrochemical reaction.

Folser, George R. (Lower Burrell, PA)

1980-01-01T23:59:59.000Z

464

Vibrational dynamics in water from the molecule's perspective  

E-Print Network [OSTI]

Liquid water is a fascinating substance, ubiquitous in chemistry, physics, and biology. Its remarkable physical and chemical properties stem from the intricate network of hydrogen bonds that connect molecular participants. ...

Eaves, Joel David, 1976-

2005-01-01T23:59:59.000Z

465

Structural Rearrangements in Water Viewed Through Two- Dimensional Infrared Spectroscopy  

E-Print Network [OSTI]

Compared with other molecular liquids, water is highly structured because of its ability to form up to four hydrogen bonds, resulting in a tetrahedral network of molecules. However, this underlying intermolecular structure ...

Roberts, Sean Thomas

466

Development of a graphite probe calorimeter for absolute clinical dosimetry  

SciTech Connect (OSTI)

The aim of this work is to present the numerical design optimization, construction, and experimental proof of concept of a graphite probe calorimeter (GPC) conceived for dose measurement in the clinical environment (U.S. provisional patent 61/652,540). A finite element method (FEM) based numerical heat transfer study was conducted using a commercial software package to explore the feasibility of the GPC and to optimize the shape, dimensions, and materials used in its design. A functioning prototype was constructed inhouse and used to perform dose to water measurements under a 6 MV photon beam at 400 and 1000 MU/min, in a thermally insulated water phantom. Heat loss correction factors were determined using FEM analysis while the radiation field perturbation and the graphite to water absorbed dose conversion factors were calculated using Monte Carlo simulations. The difference in the average measured dose to water for the 400 and 1000 MU/min runs using the TG-51 protocol and the GPC was 0.2% and 1.2%, respectively. Heat loss correction factors ranged from 1.001 to 1.002, while the product of the perturbation and dose conversion factors was calculated to be 1.130. The combined relative uncertainty was estimated to be 1.4%, with the largest contributors being the specific heat capacity of the graphite (type B, 0.8%) and the reproducibility, defined as the standard deviation of the mean measured dose (type A, 0.6%). By establishing the feasibility of using the GPC as a practical clinical absolute photon dosimeter, this work lays the foundation for further device enhancements, including the development of an isothermal mode of operation and an overall miniaturization, making it potentially suitable for use in small and composite radiation fields. It is anticipated that, through the incorporation of isothermal stabilization provided by temperature controllers, a subpercent overall uncertainty will be achieved.

Renaud, James; Seuntjens, Jan; Sarfehnia, Arman [Medical Physics Unit, McGill University, Montreal, Quebec H3G 1A4 (Canada); Marchington, David [Ionizing Radiation Standards, National Research Council of Canada, Ottawa, Ontario K1A 0R6 (Canada)

2013-02-15T23:59:59.000Z

467

Magnetically focused liquid drop radiator  

DOE Patents [OSTI]

A magnetically focused liquid drop radiator for application in rejecting energy from a spacecraft, characterized by a magnetizable liquid or slurry disposed in operative relationship within the liquid droplet generator and its fluid delivery system, in combination with magnetic means disposed in operative relationship around a liquid droplet collector of the LDR. The magnetic means are effective to focus streams of droplets directed from the generator toward the collector, thereby to assure that essentially all of the droplets are directed into the collector, even though some of the streams may be misdirected as they leave the generator. The magnetic focusing means is also effective to suppress splashing of liquid when the droplets impinge on the collector.

Botts, T.E.; Powell, J.R.; Lenard, R.

1984-12-10T23:59:59.000Z

468

Semiconductor nanocrystal probes for biological applications and process for making and using such probes  

DOE Patents [OSTI]

A semiconductor nanocrystal compound and probe are described. The compound is capable of linking to one or more affinity molecules. The compound comprises (1) one or more semiconductor nanocrystals capable of, in response to exposure to a first energy, providing a second energy, and (2) one or more linking agents, having a first portion linked to the one or more semiconductor nanocrystals and a second portion capable of linking to one or more affinity molecules. One or more semiconductor nanocrystal compounds are linked to one or more affinity molecules to form a semiconductor nanocrystal probe capable of bonding with one or more detectable substances in a material being analyzed, and capable of, in response to exposure to a first energy, providing a second energy. Also described are processes for respectively: making the semiconductor nanocrystal compound; making the semiconductor nanocrystal probe; and treating materials with the probe.

Weiss, Shimon; Bruchez, Marcel; Alivisatos, Paul

2014-01-28T23:59:59.000Z

469

Vibrational Sum Frequency Spectroscopy and Molecular Dynamics Simulation of the Carbon Tetrachloride-Water and 1,2-Dichloroethane-Water Interfaces  

E-Print Network [OSTI]

and bonding at the carbon tetrachloride-water (CCl4-H2O) and the 1,2-dichloroethane-water (DCE-H2O) liquidVibrational Sum Frequency Spectroscopy and Molecular Dynamics Simulation of the Carbon Tetrachloride-Water and 1,2-Dichloroethane-Water Interfaces Dave S. Walker, Fred G. Moore, and Geraldine L

Richmond, Geraldine L.

470

Constrained water cloud generator  

Science Journals Connector (OSTI)

The fast generation of large cloudy volumes with imposed cloud cover fractions and ambient vertical profiles is very important for the realistic simulation of atmospheric scenes. The model proposed here is the second step of a two-step model composed on the one hand of a volume generator based on a Fourier filtering method and on the other hand of a physical generator filling the volume with physical parameters. After a description of the general generation scheme, this paper focuses on the simulation of vertical profiles of water content (liquid, vapour) coupled with other state parameters (temperature, pressure, vertical velocity) via thermodynamic and hydrodynamic equations by local forcing of ambient conditions. The method for solving these equations is explained and applied to practical cases. First, by assuming that the actual temperature at the cloud base is equal to the dew temperature and by imposing a moist pseudo-adiabatic temperature gradient between the cloud top and bottom, the temperature profile in the cloud is found. When conditional instability occurs, the initial temperature profile between the ground and the cloud base is iteratively shifted to lower values until absolute stability is reached. Then the liquid water content is calculated by integrating the equation of water conservation, and the water vapour content by assuming that the cloud is everywhere saturated. Eventually, the vertical velocity is estimated by integration of the momentum equation. This method gives results in good agreement with published measurements, analytical and numerical models. Eventually, further developments of the column model, including the effects of phase transitions, turbulence, horizontal motions and mixing with the surrounding medium, are proposed in the concluding section.

Roland P.H. Berton

2008-01-01T23:59:59.000Z

471

Steady and unsteady calibration of multi-hole probes  

E-Print Network [OSTI]

This thesis presents the development of a data crographics. reduction algorithm for multi-hole pressure probes. The algorithm has been developed for the reduction of calibration data from miniature non-nulling multi-hole probes in compressible...

Johansen, Espen S

1998-01-01T23:59:59.000Z

472

Lens-array PDV Probe Using a Pyramid Prism  

SciTech Connect (OSTI)

A bug eye probe is shown using a pyramid prism, and its advantages and disadvantages are enumerated. Also shown is abug eye imaging probe, with its advantages and disadvantages enumerated.

Malone, R. M., Kaufman, M. I., Cox, B., Romero, V., Cata B., Sorenson, D. Pazuchanics, P.

2011-11-01T23:59:59.000Z

473

New probe at EMSL observes interface kinetics | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

new microfluidic E probe, developed at PNNL and available at EMSL, in position on a ToF-SIMS instrument. A new imaging capability provides direct probing of the solid...

474

In situ chemical probing of the electrode-electrolyte interface...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

chemical probing of the electrode-electrolyte interface by ToF-SIMS. In situ chemical probing of the electrode-electrolyte interface by ToF-SIMS. Abstract: A portable vacuum...

475

Equation of State of Supercooled Water from the Sedimentation Profile  

E-Print Network [OSTI]

To study the coexistence of two liquid states of water within one simulation box, we implement an equilibrium sedimentation method--which involves applying a gravitational field to the system and measuring/calculating the resulting density profile in equilibrium. We simulate a system of particles interacting via the ST2 potential, a model for water. We detect the coexistence of two liquid phases at low temperature.

M. Yamada; H. E. Stanley; F. Sciortino

2002-08-23T23:59:59.000Z

476

Investigations of Probe Induced Perturbations in a Hall Thruster  

SciTech Connect (OSTI)

An electrostatic probe used to measure spatial plasma parameters in a Hall thruster generates perturbations of the plasma. These perturbations are examined by varying the probe material, penetration distance, residence time, and the nominal thruster conditions. The study leads us to recommendations for probe design and thruster operating conditions to reduce discharge perturbations, including metal shielding of the probe insulator and operation of the thruster at lower densities.

D. Staack; Y. Raitses; N.J. Fisch

2002-08-12T23:59:59.000Z

477

Probing Single-Molecule Protein Conformational Dynamics. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Single-Molecule Protein Conformational Dynamics. Probing Single-Molecule Protein Conformational Dynamics. Abstract: Protein conformational fluctuations and dynamics, often...

478

Method of measuring a liquid pool volume  

DOE Patents [OSTI]

A method of measuring a molten metal liquid pool volume and in particular molten titanium liquid pools, including the steps of (a) generating an ultrasonic wave at the surface of the molten metal liquid pool, (b) shining a light on the surface of a molten metal liquid pool, (c) detecting a change in the frequency of light, (d) detecting an ultrasonic wave echo at the surface of the molten metal liquid pool, and (e) computing the volume of the molten metal liquid.

Garcia, Gabe V. (Las Cruces, NM); Carlson, Nancy M. (Idaho Falls, ID); Donaldson, Alan D. (Idaho Falls, ID)

1991-01-01T23:59:59.000Z

479

Solar pumping installation for pumping liquid and solar collector construction  

SciTech Connect (OSTI)

A solar pumping system, comprises, a pumping housing which defines a pump chamber therein which is adapted to be positioned in the ground below ground water level. Displacer means in the form of, for example, a bladder, arranged within the pump chamber, is capable of displacing liquid out of the pump chamber in response to a pressurized medium acting thereon to expel the water out of the chamber and up to a level above the ground for use. A suction valve connected into the chamber permits the ground water to flow into the chamber and a discharge valve connected out of the chamber permits the outflow of the ground water during the action of the displacer means. The construction includes a solar collector having at least one hydride conduit which is adapted to be exposed to the sun for solar heating to act on the hydride to cause hydrogen to be formed, the pressure of which acts against the displacer means to displace the ground liquid out of the pump chamber. When the solar collector is shielded and the hydride is permitted to cool or is cooled rapidly by the circulation of water thereover, the pressure of the generated hydrogen decreases, permitting ground water to enter into the pumping chamber once again through the suction valves.

Seidel, A.; Wolf, D.

1984-03-27T23:59:59.000Z

480

Synthesis of multiwall carbon nanotubes by electric arc discharge in liquid environments  

Science Journals Connector (OSTI)

This work reports the experimental results from the production of multiwall carbon nanotubes (MWCN) synthesized by an electric arc discharge performed in liquid environments between pure graphite electrodes. Both liquid nitrogen and deionised water were suitable for a successful synthesis of this form of carbon aggregation. We report a successful synthesis of MWCN by arc discharge submerged in deionised water. Electron microscopy observations of both the reaction products and the surface of the as-synthesized raw material showed the presence of structural degradation of the MWCN, which probably operates after their growth at the cathode. The degradation is tentatively ascribed to a combination of overheating and high current density experienced by the as-synthesized MWNT, which can be caused by the loose structure of the as-deposited material. The damage appeared to be less severe in water environments, probably owing to the better cooling capacity of water relative to liquid nitrogen.

Marco Vittori Antisari; Renzo Marazzi; Radenka Krsmanovic

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "liquid water probed" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Elastic interpretation of the glass transition in aluminosilicate liquids  

Science Journals Connector (OSTI)

One of the remaining puzzles of the glass transition is the origin of a glass-forming liquid's “fragility,” which quantifies the departure of its relaxation time from Arrhenius-activated kinetics. According to the shoving model proposed by Dyre, fragility is controlled by the instantaneous shear modulus of the liquid, since any flow event requires a local volume increase, and the related activation energy is equal to the work done in shoving aside the surrounding atoms. Here, we present an in situ high-temperature Brillouin spectroscopy test of the shoving model near the glass transition of eight aluminosilicate glass-forming systems. We find that the measured viscosity data agree qualitatively with the measured temperature dependence of shear moduli, as predicted by the shoving model. However, the model systematically underpredicts the values of fragility for our aluminosilicate liquids. This suggests that the dynamics of the glass transition are governed by additional factors beyond the evolution of the shear modulus, such as configurational entropy. We have also compared the glass transition temperature (Tg,vis) obtained from viscosity (temperature at 1012 Pa s) with the onset temperatures of the decrease in elastic moduli (Tg,elas) and increase in the thermal expansion coefficient (Tg,CTE) during heating. While we find an approximate one-to-one correlation between Tg,vis and Tg,CTE, it is clear that the elastic moduli probe a different frequency response of the glass structure, since Tg,elas is systematically lower than Tg,vis.

Morten M. Smedskjaer; Liping Huang; Garth Scannell; John C. Mauro

2012-04-27T23:59:59.000Z

482

The Muon g-2 Experiment The NMR Probe Circuitry  

E-Print Network [OSTI]

The Muon g-2 Experiment The NMR Probe Circuitry Upgrading the Circuit Building the Circuit Future Work Updating NMR Probe Electronics in the Muon g-2 Experiment Audrey Kvam University of Washington September 1, 2014 Audrey Kvam Updating NMR Probe Electronics in the Muon g-2 Experiment #12;The Muon g-2

Washington at Seattle, University of - Department of Physics, Electroweak Interaction Research Group

483

Can a Pump-probe Experiment be Simulated Efficiently?  

E-Print Network [OSTI]

Can a Pump-probe Experiment be Simulated Efficiently? Thesis Submitted for the Degree Doctor things in the world. #12;i ABSTRACT Measuring a quantum system disturbs its evolution. A pump-probe exper measurements. Modeling the evolution of observables in the pump-probe experiment is an essential ingredient

Kosloff, Ronnie

484

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...  

Broader source: Energy.gov (indexed) [DOE]

Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

485

Liquid chromatographic extraction medium  

DOE Patents [OSTI]

A method and apparatus are disclosed for extracting strontium and technetium values from biological, industrial and environmental sample solutions using a chromatographic column. An extractant medium for the column is prepared by generating a solution of a diluent containing a Crown ether and dispersing the solution on a resin substrate material. The sample solution is highly acidic and is introduced directed to the chromatographic column and strontium or technetium is eluted using deionized water. 1 fig.

Horwitz, E.P.; Dietz, M.L.

1994-09-13T23:59:59.000Z

486

Liquid chromatographic extraction medium  

DOE Patents [OSTI]

A method and apparatus for extracting strontium and technetium values from biological, industrial and environmental sample solutions using a chromatographic column is described. An extractant medium for the column is prepared by generating a solution of a diluent containing a Crown ether and dispersing the solution on a resin substrate material. The sample solution is highly acidic and is introduced directed to the chromatographic column and strontium or technetium is eluted using deionized water.

Horwitz, E. Philip (Naperville, IL); Dietz, Mark L. (Evanston, IL)

1994-01-01T23:59:59.000Z

487

Variable temperature, relative humidity ,,0%100%..., and liquid neutron reflectometry sample cell suitable for polymeric and biomimetic materials  

E-Print Network [OSTI]

Variable temperature, relative humidity ,,0%­100%..., and liquid neutron reflectometry sample cell , and bulk liquid neutron reflectometry sample cell suitable for the study of polymeric and biomimetic. This permits the study, by neutron reflectometry, of samples that are intrinsically unstable in bulk water

Barrett, Christopher

488

Frostbite Theater - Liquid Nitrogen Experiments - Instant Liquid Nitrogen  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Freezing Balloons! Freezing Balloons! Previous Video (Freezing Balloons!) Frostbite Theater Main Index Next Video (Shattering Flowers!) Shattering Flowers! Instant Liquid Nitrogen Balloon Party! Need a bunch of balloons blown-up quickly? Liquid nitrogen to the rescue! [ Show Transcript ] Announcer: Frostbite Theater presents... Cold Cuts! No baloney! Joanna and Steve: Just science! Joanna: Hi! I'm Joanna! Steve: And I'm Steve! Joanna: We've been making videos for a while now and we've learned that people like balloons and liquid nitrogen! Steve: So... Here you go! Balloon: Crackling... Balloon: Pop! Joanna: Ooh! Balloon: Pop! Balloon: Pop! Steve: If you'd like to know the science of what's going on behind this, please one of our first videos, "Liquid Nitrogen Experiments: The Balloon."

489

High-Resolution Estimation of Near-Subsurface Water Content using Surface GPR Ground Wave Information  

E-Print Network [OSTI]

-scarce agricultural areas. Conventional measurements of water content (such as from time domain reflectometry [TDR], neutron probe or gravimetric techniques) are intrusive and provide information at a 'point' scale, which

Rubin, Yoram

490

Highly controlled fabrication of carbon nanotube based probes for atomic force microscopy  

E-Print Network [OSTI]

phase images taken with the CNC MFM probe. 5.7 References J.silicon substrate using (a) A CNC probe. (b) A commercial Sithe Si MFM probe, and (b) the CNC MFM probe ……..…. ………. …94

Chen, I-Chen

2007-01-01T23:59:59.000Z

491

Site tests validate benefits of cavern probes  

SciTech Connect (OSTI)

More than 5 years` experience with downhole probes has allowed TransGas Ltd., Regina, to monitor and evaluate cavern integrity. The devices access natural-gas storage caverns` pressures and temperatures. Acquired data have helped determine gas-in-place inventory volumes, confirm spatial volumes, and assess changes in spatial volumes that may have resulted from cavern creep (shrinkage or closure) or downhole abnormality such as fluid infill or collapse of the side walls or roof areas. This conclusion of two articles presents details and results of a specific storage-site. The first article presented background and many of the details and lessons of TransGas` cavern gas-storage probe program.

Crossley, N.G. [TransGas Ltd., Regina, Saskatchewan (Canada)

1997-03-10T23:59:59.000Z

492

Probing the curvature and dark energy  

Science Journals Connector (OSTI)

Two new one-parameter tracking behavior dark energy representations ?=?0/(1+z) and ?=?0ez/(1+z)/(1+z) are used to probe the geometry of the Universe and the property of dark energy. The combined type Ia supernova, Sloan Digital Sky Survey, and Wilkinson Microwave Anisotropy Probe data indicate that the Universe is almost spatially flat and that dark energy contributes about 72% of the matter content of the present universe. The observational data also tell us that ?(0)?-1. It is argued that the current observational data can hardly distinguish different dark energy models to the zeroth order. The transition redshift when the expansion of the Universe changed from deceleration phase to acceleration phase is around zT?0.6 by using our one-parameter dark energy models.

Yungui Gong and Yuan-Zhong Zhang

2005-08-22T23:59:59.000Z

493

Probing the curvature and dark energy  

E-Print Network [OSTI]

Two new one-parameter tracking behavior dark energy representations $\\omega=\\omega_0/(1+z)$ and $\\omega=\\omega_0 e^{z/(1+z)}/(1+z)$ are used to probe the geometry of the Universe and the property of dark energy. The combined type Ia supernova (SN Ia), Sloan Digital Sky Survey (SDSS), and Wilkinson Microwave Anisotropy Probe (WMAP) data indicate that the Universe is almost spatially flat and that dark energy contributes about 72% of the matter content of the present universe. The observational data also tell us that $\\omega(0)\\sim -1$. It is argued that the current observational data can hardly distinguish different dark energy models to the zeroth order. The transition redshift when the expansion of the Universe changed from deceleration phase to acceleration phase is around $z_{\\rm T}\\sim 0.6$ by using our one-parameter dark energy models.

Yungui Gong; Yuan-Zhong Zhang

2005-02-14T23:59:59.000Z

494

Probing Nano-Mechanical QED Effects  

E-Print Network [OSTI]

We propose and study an "intrinsic probing" approach, without introducing any external detector, to mimic cavity QED effects in a qubit-nanomechanical resonator system. This metallic nanomechanical resonator can act as an intrinsic detector when a weak driving current passes through it. The nanomechanical resonator acts as both the cavity and the detector. A cavity QED-like effect is demonstrated by the correlation spectrum of the electromotive force between the two ends of the nanomechanical resonator. Using the quantum regression theorem and perturbation theory, we analytically calculate the correlation spectrum. In the weak driving limit, we study the effect on the vacuum Rabi splitting of both the strength of the driving as well as the frequency-detuning between the charge qubit and the nanomechanical resonator. Numerical calculations confirm the validity of our intrinsic probing approach.

Y. B. Gao; S. Yang; Yu-xi Liu; C. P. Sun; Franco Nori

2009-02-15T23:59:59.000Z

495

BALTEX BRIDGE cloud liquid water network project: CLIWA-NET  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3/2008 3/2008 ARM-08 Photo courtesy Bjorn Stevens ARM-GEWEX Cloud System Studies (GCSS) Collaborations: Past-Present-Future A. Pier Siebesma siebesma@knmi.nl chair GCCS KNMI, De Bilt, The Netherlands Technical University Delft Multiscale Physics Group Delft, The Netherlands 4/3/2008 ARM-08 Topics Introduction to GCSS activities Examples and Results for parameterization development in the past. (has it made a difference?) Past and Present Collaborations and results between ARM and GCSS The Future: How can we do better? 4/3/2008 ARM-08 Objective of GCSS GCSS is developing improved parameterizations of cloud systems for climate models and numerical weather prediction models by improving our understanding of the physical processes for all the climate relevant cloud types 4/3/2008 ARM-08

496

Radiative Importance of ThinŽ Liquid Water Clouds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Program Program Accomplishments of the Cloud Properties Working Group (CPWG) August 2006 Cloud Radiative Forcing at the ARM Climate Research Facility: Using ARM Data to Establish Testable Metrics for GCM Predictions of Cloud Feedback Gerald Mace University of Utah, Salt Lake City, Utah The scientific underpinning of the Atmospheric Radiation Measurement (ARM) Program is largely based on the premise that long term ground-based measurements of certain quantities provide information sufficient to test the skill of general circulation models (GCMs) to predict radiative heating and cloud feedbacks (Stokes and Schwartz, 1994; Ackerman and Stokes, 2003). This hypothesis is based on the assumption that some set of long-term ground-based measurements provide sufficient information to characterize the physical state of the atmospheric