Sample records for liquid water probed

  1. Probing Properties of Glassy Water and Other Liquids with Site Selective Spectroscopies

    SciTech Connect (OSTI)

    Nhan Chuong Dang

    2005-08-12T23:59:59.000Z

    The standard non-photochemical hole burning (NPHB) mechanism, which involves phonon-assisted tunneling in the electronically excited state, was originally proposed to explain the light-induced frequency change of chemically stable molecules in glassy solids at liquid helium temperatures by this research group more than two decades ago. The NPHB mechanism was then further elucidated and the concept of intrinsic to glass configurational relaxation processes as pre-mediating step to the hole burning process was introduced. The latter provided the theoretical basis for NPHB to evolve into a powerful tool probing the dynamics and nature of amorphous media, which aside from ''simple'' inorganic glasses may include also ''complex'' biological systems such as living cells and cancerous/normal tissues. Presented in this dissertation are the experimental and theoretical results of hole burning properties of aluminum phthalocyanine tetrasulphonate (APT) in several different matrices: (1) hyperquenched glassy water (HGW); (2) cubic ice (I{sub c}); and (3) water confined into poly(2-hydroxyethylmethacrylate) (poly-HEMA). In addition, results of photochemical hole burning (PHB) studies obtained for phthalocyanine tetrasulphonate (PcT) in HGW and free base phthalocyanine (Pc) in ortho-dichlorobenzene (DCB) glass are reported. The goal of this dissertation was to provide further evidence supporting the NPHB mechanism and to provide more insight that leads to a better understanding of the kinetic events (dynamics) in glasses, and various dynamical processes of different fluorescent chromorphores in various amorphous solids and the liquid that exist above the glass transition temperature (T{sub g}). The following issues are addressed in detail: (1) time evolution of hole being burned under different conditions and in different hole burning systems; (2) temperature dependent hole profile; and (3) the structure/dynamics of water in confined space, which has been studied, in part because of the importance of non-freezable water in biological systems.

  2. A Passive Probe for Subsurface Oceans and Liquid Water in Jupiter's Icy Moons

    E-Print Network [OSTI]

    Romero-Wolf, Andrew; Maiwald, Frank; Heggy, Essam; Ries, Paul; Liewer, Kurt

    2014-01-01T23:59:59.000Z

    We describe an interferometric reflectometer method for passive detection of subsurface oceans and liquid water in Jovian icy moons using Jupiter's decametric radio emission (DAM). The DAM flux density exceeds 3,000 times the galactic background in the neighborhood of the Jovian icy moons, providing a signal that could be used for passive radio sounding. An instrument located between the icy moon and Jupiter could sample the DAM emission along with its echoes reflected in the ice layer of the target moon. Cross-correlating the direct emission with the echoes would provide a measurement of the ice shell thickness along with its dielectric properties. The interferometric reflectometer provides a simple solution to sub-Jovian radio sounding of ice shells that is complementary to ice penetrating radar measurements better suited to measurements in the anti-Jovian hemisphere that shadows Jupiter's strong decametric emission. The passive nature of this technique also serves as risk reduction in case of radar transmi...

  3. Active probing of cloud multiple scattering, optical depth, vertical thickness, and liquid water content using wide-angle imaging LIDAR.

    SciTech Connect (OSTI)

    Love, Steven P.; Davis, A. B. (Anthony B.); Rohde, C. A. (Charles A.); Tellier, L. L. (Larry L.); Ho, Cheng,

    2002-01-01T23:59:59.000Z

    At most optical wavelengths, laser light in a cloud lidar experiment is not absorbed but merely scattered out of the beam, eventually escaping the cloud via multiple scattering. There is much information available in this light scattered far from the input beam, information ignored by traditional 'on-beam' lidar. Monitoring these off-beam returns in a fully space- and time-resolved manner is the essence of our unique instrument, Wide Angle Imaging Lidar (WAIL). In effect, WAIL produces wide-field (60-degree full-angle) 'movies' of the scattering process and records the cloud's radiative Green functions. A direct data product of WAIL is the distribution of photon path lengths resulting from multiple scattering in the cloud. Following insights from diffusion theory, we can use the measured Green functions to infer the physical thickness and optical depth of the cloud layer, and, from there, estimate the volume-averaged liquid water content. WAIL is notable in that it is applicable to optically thick clouds, a regime in which traditional lidar is reduced to ceilometry. Here we present recent WAIL data oti various clouds and discuss the extension of WAIL to full diurnal monitoring by means of an ultra-narrow magneto-optic atomic line filter for daytime measurements.

  4. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Cadeddu, Maria

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  5. Probing Liquid Surfaces under Vacuum Using SEM and TOF-SIMS....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Liquid Surfaces under Vacuum Using SEM and TOF-SIMS. Probing Liquid Surfaces under Vacuum Using SEM and TOF-SIMS. Abstract: Applying vacuum-based molecular probes of liquid...

  6. Far-Infrared Dielectric Properties of Polar Liquids Probed by Femtosecond Terahertz Pulse Spectroscopy

    E-Print Network [OSTI]

    the microwave and the FIR regions; the motions that are probed at these frequencies bridge the gap between bulk to study gases,2 semiconductors,3 super- conductors,4 dielectrics,5 nonpolar liquids,6 and water.7 We are generated by the excitation of charge carriers in a semiconductor material with ultrashort pulses of above

  7. High-precision gigahertz-to-terahertz spectroscopy of aqueous salt solutions as a probe of the femtosecond-to-picosecond dynamics of liquid water

    E-Print Network [OSTI]

    Vinh, N Q; Allen, S James; George, D K; Rahmani, A J; Plaxco, Kevin W

    2015-01-01T23:59:59.000Z

    Because it is sensitive to fluctuations occurring over femtoseconds to picoseconds, gigahertz-to-terahertz dielectric relaxation spectroscopy can provide a valuable window into water's most rapid intermolecular motions. In response, we have built a vector network analyzer dielectric spectrometer capable of measuring absorbance and index of refraction in this frequency regime with unprecedented precision. Using this to determine the complex dielectric response of water and aqueous salt solutions from 5.9 GHz to 1.12 THz (which we provide in the SI), we have obtained strong new constraints on theories of water's collective dynamics. For example, while the salt-dependencies we observe for water's two slower relaxations (8 and 1 ps) are easily reconciled with suggestions that they arise due to rotations of fully and partially hydrogen bonded molecules, respectively, the salt-dependence of the fastest relaxation (180 fs) appears difficult to reconcile with its prior assignment to liberations of single hydrogen bon...

  8. Proton Electrodynamics in Liquid Water

    E-Print Network [OSTI]

    A. A. Volkov; V. G. Artemov; A. V. Pronin

    2013-02-20T23:59:59.000Z

    The dielectric spectrum of liquid water, $10^{4} - 10^{11}$ Hz, is interpreted in terms of diffusion of charges, formed as a result of self-ionization of H$_{2}$O molecules. This approach explains the Debye relaxation and the dc conductivity as two manifestations of this diffusion. The Debye relaxation is due to the charge diffusion with a fast recombination rate, $1/\\tau_{2}$, while the dc conductivity is a manifestation of the diffusion with a much slower recombination rate, $1/\\tau_{1}$. Applying a simple model based on Brownian-like diffusion, we find $\\tau_{2} \\simeq 10^{-11}$ s and $\\tau_{1} \\simeq 10^{-6}$ s, and the concentrations of the charge carriers, involved in each of the two processes, $N_{2} \\simeq 5 \\times 10^{26}$ m$^{-3}$ and $N_{1} \\simeq 10^{14}$ m$^{-3}$. Further, we relate $N_{2}$ and $N_{1}$ to the total concentration of H$_{3}$O$^{+}$--OH$^{-}$ pairs and to the pH index, respectively, and find the lifetime of a single water molecule, $\\tau_{0} \\simeq 10^{-9}$ s. Finally, we show that the high permittivity of water results mostly from flickering of separated charges, rather than from reorientations of intact molecular dipoles.

  9. LOCAL PROBE IN A RAYLEIGH-BENARD EXPERIMENT IN LIQUID HELIUM

    E-Print Network [OSTI]

    Boyer, Edmond

    L-369 LOCAL PROBE IN A RAYLEIGH-BENARD EXPERIMENT IN LIQUID HELIUM A. LIBCHABER and J. MAURER. Abstract. 2014 We have measured, in a Rayleigh-Benard experiment in liquid helium, the time dependent-Benard experiment in liquid helium, using for the first time a local probe. Time dependent effects above

  10. Electrokinetic Power Generation from Liquid Water Microjets

    SciTech Connect (OSTI)

    Duffin, Andrew M.; Saykally, Richard J.

    2008-02-15T23:59:59.000Z

    Although electrokinetic effects are not new, only recently have they been investigated for possible use in energy conversion devices. We have recently reported the electrokinetic generation of molecular hydrogen from rapidly flowing liquid water microjets [Duffin et al. JPCC 2007, 111, 12031]. Here, we describe the use of liquid water microjets for direct conversion of electrokinetic energy to electrical power. Previous studies of electrokinetic power production have reported low efficiencies ({approx}3%), limited by back conduction of ions at the surface and in the bulk liquid. Liquid microjets eliminate energy dissipation due to back conduction and, measuring only at the jet target, yield conversion efficiencies exceeding 10%.

  11. Distributed Reforming of Renewable Liquids via Water Splitting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport...

  12. Dynamics in Organic Ionic Liquids in Distinct Regions Using Charged and Uncharged Orientational Relaxation Probes

    E-Print Network [OSTI]

    Fayer, Michael D.

    Dynamics in Organic Ionic Liquids in Distinct Regions Using Charged and Uncharged Orientational probe molecules display markedly different rotational dynamics when analyzed using Stokes increasingly subslip as the length of ionic liquid alkyl chain is increased. The dynamics approach those

  13. Global cloud liquid water path simulations

    SciTech Connect (OSTI)

    Lemus, L. [Southern Hemisphere Meteorology, Clayton, Victoria (Australia)] [Southern Hemisphere Meteorology, Clayton, Victoria (Australia); Rikus, L. [Bureau of Meteorology Research Centre, Melbourne, Victoria (Australia)] [Bureau of Meteorology Research Centre, Melbourne, Victoria (Australia); Martin, C.; Platt, R. [CSIRO, Aspendale, Victoria (Australia)] [CSIRO, Aspendale, Victoria (Australia)

    1997-01-01T23:59:59.000Z

    A new parameterization of cloud liquid water and ice content has been included in the Bureau of Meteorology Global Assimilation and Prediction System. The cloud liquid water content is derived from the mean cloud temperatures in the model using an empirical relationship based on observations. The results from perpetual January and July simulations are presented and show that the total cloud water path steadily decreases toward high latitudes, with two relative maxima at midlatitudes and a peak at low latitudes. To validate the scheme, the simulated fields need to be processed to produce liquid water paths that can be directly compared with the corresponding field derived from Special Sensor Microwave/Imager (SSM/I) data. This requires the identification of cloud ice water content within the parameterization and a prescription to account for the treatment of strongly precipitating subgrid-scale cloud. The resultant cloud liquid water paths agree qualitatively with the SSM/I data but show some systematic errors that are attributed to corresponding errors in the model`s simulation of cloud amounts. Given that a more quantitative validation requires substantial improvement in the model`s diagnostic cloud scheme, the comparison with the SSM/I data indicates that the cloud water path, derived from the cloud liquid water content parameterization introduced in this paper, is consistent with the observations and can be usefully incorporated in the prediction system. 40 refs., 11 figs., 1 tab.

  14. II. Properties of Water 1. Ice and Liquid water structure

    E-Print Network [OSTI]

    Frey, Terry

    Heat Capacity 4. Solvent Properties 5. Dissociation: Acids & Bases / pH II. Organic Chemistry A transport in plants #12;Water has a high specific heat capacity specific heat capacity = amount of energyII. Properties of Water 1. Ice and Liquid water structure 2. Cohesion / Surface Tension 3. High

  15. Liquid Water Oceans in Ice Giants

    E-Print Network [OSTI]

    Sloane J. Wiktorowicz; Andrew P. Ingersoll

    2006-09-26T23:59:59.000Z

    Aptly named, ice giants such as Uranus and Neptune contain significant amounts of water. While this water cannot be present near the cloud tops, it must be abundant in the deep interior. We investigate the likelihood of a liquid water ocean existing in the hydrogen-rich region between the cloud tops and deep interior. Starting from an assumed temperature at a given upper tropospheric pressure (the photosphere), we follow a moist adiabat downward. The mixing ratio of water to hydrogen in the gas phase is small in the photosphere and increases with depth. The mixing ratio in the condensed phase is near unity in the photosphere and decreases with depth; this gives two possible outcomes. If at some pressure level the mixing ratio of water in the gas phase is equal to that in the deep interior, then that level is the cloud base. Alternately, if the mixing ratio of water in the condensed phase reaches that in the deep interior, then the surface of a liquid ocean will occur. We find that Neptune is both too warm (photospheric temperature too high) and too dry (mixing ratio of water in the deep interior too low) for liquid oceans to exist at present. To have a liquid ocean, Neptune's deep interior water to gas ratio would have to be higher than current models allow, and the density at 19 kbar would have to be ~ 0.8 g/cm^3. Such a high density is inconsistent with gravitational data obtained during the Voyager flyby. As Neptune cools, the probability of a liquid ocean increases. Extrasolar "hot Neptunes," which presumably migrate inward toward their parent stars, cannot harbor liquid water oceans unless they have lost almost all of the hydrogen and helium from their deep interiors.

  16. Liquid chromatographic determination of water

    DOE Patents [OSTI]

    Fortier, N.E.; Fritz, J.S.

    1990-11-13T23:59:59.000Z

    A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present. 1 fig.

  17. On the Fluctuations that Order and Frustrate Liquid Water

    E-Print Network [OSTI]

    Limmer, David

    2013-01-01T23:59:59.000Z

    Most nonpolar liquids have heat capacities that range from 8the maximum liquid state heat capacity[173]. ExperimentallyLIQUID AND SOLID WATER (a) Density (b) Compressibility (c) Heat Capacity

  18. Surfactant/Water Interactions at the Air/Water Interface Probed by Vibrational Sum Frequency Generation

    E-Print Network [OSTI]

    Richmond, Geraldine L.

    Surfactant/Water Interactions at the Air/Water Interface Probed by Vibrational Sum Frequency and orientation of water molecules at an air/water interface has been measured in the presence of cationic spectrum of both the surfactant and water molecules at the water surface. In the presence of the charged

  19. A quantitative account of quantum effects in liquid water. |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    report quantum statistical mechanical simulations of liquid water with the TTM2.1-F flexible, polarizable interaction potential for water. The potential is the first...

  20. The physics of liquid water Bernard Cabane1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    with extraordinary properties: it has unusually high melting and boiling temperatures, a huge heat capacity, oneThe physics of liquid water Bernard Cabane1 , Rodolphe Vuilleumier2 1 PMMH, ESPCI, 10 rue Vauquelin, France Abstract Liquid water is a liquid with extraordinary properties: it has a very high cohesion

  1. Response functions near the liquid-liquid critical point of ST2 water

    E-Print Network [OSTI]

    Stanley, H. Eugene

    speci¿c heat capacity CP and the isothermal compressibility KT . We use two different methods: (i) fromResponse functions near the liquid-liquid critical point of ST2 water Erik Lascaris , T. A, and for four different system sizes, N = 63, 73, 83, and 93. We locate the liquid-liquid phase transition line

  2. On the Fluctuations that Order and Frustrate Liquid Water

    E-Print Network [OSTI]

    Limmer, David

    2013-01-01T23:59:59.000Z

    the forces of hydrogen bonds to the properties of liquid andhydrogen bond network couples to the dynamically heterogeneous propertiesproperties of liquid water manifest how the strength of these hydrogen

  3. Dual harmonic Kelvin probe force microscopy at the grapheneliquid interface

    SciTech Connect (OSTI)

    Collins, Liam; Rodriguez, Brian J., E-mail: brian.rodriguez@ucd.ie [School of Physics, University College Dublin, Belfield, Dublin 4 (Ireland); Conway Institute of Biomolecular and Biomedical Research, University College Dublin, Belfield, Dublin 4 (Ireland); Kilpatrick, Jason I.; Weber, Stefan A. L. [Conway Institute of Biomolecular and Biomedical Research, University College Dublin, Belfield, Dublin 4 (Ireland); Vlassiouk, Ivan V. [Energy and Transportation Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Tselev, Alexander; Jesse, Stephen; Kalinin, Sergei V. [Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

    2014-03-31T23:59:59.000Z

    Kelvin probe force microscopy (KPFM) is a powerful technique for the determination of the contact potential difference (CPD) between an atomic force microscope tip and a sample under ambient and vacuum conditions. However, for many energy storage and conversion systems, including graphene-based electrochemical capacitors, understanding electrochemical phenomena at the solidliquid interface is paramount. Despite the vast potential to provide fundamental insight for energy storage materials at the nanoscale, KPFM has found limited applicability in liquid environments to date. Here, using dual harmonic (DH)-KPFM, we demonstrate CPD imaging of graphene in liquid. We find good agreement with measurements performed in air, highlighting the potential of DH-KPFM to probe electrochemistry at the grapheneliquid interface.

  4. Liquid-liquid equilibria of fuel oxygenate + water + hydrocarbon mixtures. 3: Effect of temperature

    SciTech Connect (OSTI)

    Wagner, G. [Universitaet Karlsruhe (Germany). Institut fuer Thermische Verfahrenstechnik; Sandler, S.I. [Univ. of Delaware, Newark, DE (United States). Center for Molecular and Engineering Thermodynamics

    1995-09-01T23:59:59.000Z

    The authors have measured the ternary liquid-liquid equilibria of water + ethanol mixtures with, separately, 2,2,4-trimethylpentane and toluene at 5 and 40 C, water + tert-amyl alcohol (TAOH) mixtures with, separately, toluene and hexane at 5 and 40 C, and of water + TAOH + pentane mixtures at 5 C. The ethanol-containing systems exhibit type 1 liquid-liquid phase behavior, and the TAOH-containing systems exhibit type 2 behavior. These data, together with the data they have previously reported at 25 C, provide information on how the liquid-liquid equilibria of these systems change as a function of temperature. While the addition of ethanol is found to increase the solubility of hydrocarbons in the aqueous phase, the concentration of the hydrocarbon in the water-rich phase decreases with increasing temperature. With the exception of hydrocarbon in the water-rich phase, the experimental data could be correlated quite well with either the UNIQUAC or NRTL models. For most of the systems considered here the predictions of the phase behavior with the liquid-liquid UNIFAC group-contribution model are only qualitatively correct. However, the liquid-liquid UNIFAC model erroneously predicts type 2 phase behavior to occur for water + ethanol + 2,2,4-trimethylpentane system at 5 C.

  5. Liquid-liquid equilibria of water + methanol + 1-octanol and water + ethanol + 1-octanol at various temperatures

    SciTech Connect (OSTI)

    Arce, A.; Blanco, A.; Souza, P.; Vidal, I. (Univ. of Santiago de Compostela (Spain). Dept. of Chemical Engineering)

    1994-04-01T23:59:59.000Z

    This study is part of a wider program of research on the recovery of light alcohols from dilute aqueous solutions using high molecular weight solvents. The authors report liquid-liquid equilibrium data and binodal curves for the systems water + methanol + 1-octanol and water + ethanol + 1-octanol at 25, 35, and 45 C. The data were fitted to the NRTL and UNIQUAC equations.

  6. Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy

    SciTech Connect (OSTI)

    Wen, Haidan; Huse, Nils; Schoenlein, Robert W.; Lindenberg, Aaron M.

    2010-05-01T23:59:59.000Z

    We present the first femtosecond soft x-ray spectroscopy in liquids, enabling the observation of changes in hydrogen bond structures in water via core-hole excitation. The oxygen K-edge of vibrationally excited water is probed with femtosecond soft x-ray pulses, exploiting the relation between different water structures and distinct x-ray spectral features. After excitation of the intramolecular OH stretching vibration, characteristic x-ray absorption changes monitor the conversion of strongly hydrogen-bonded water structures to more disordered structures with weaker hydrogen-bonding described by a single subpicosecond time constant. The latter describes the thermalization time of vibrational excitations and defines the characteristic maximum rate with which nonequilibrium populations of more strongly hydrogen-bonded water structures convert to less-bonded ones. On short time scales, the relaxation of vibrational excitations leads to a transient high-pressure state and a transient absorption spectrum different from that of statically heated water.

  7. Isothermal vapor-liquid equilibria for methanol + ethanol + water, methanol + water, and ethanol + water

    SciTech Connect (OSTI)

    Kurihara, Kiyofumi; Takeda, Kouichi; Kojima, Kazuo [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Minoura, Tsuyoshi [Mitui Engineering and Shipbuilding Co., Ltd., Tokyo (Japan)

    1995-05-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria were measured for the ternary system methanol + ethanol + water and its constituent binary systems of methanol + water and ethanol + water at 323.15, 328.15, and 333.15 K. The apparatus that was used made it possible to control the measured temperature and total pressure by computer. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

  8. VAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE FROM

    E-Print Network [OSTI]

    ) and their binary mixtures (between 348 and 393 K). The properties of supercritical carbon dioxide were determinedVAPOR + LIQUID EQUILIBRIUM OF WATER, CARBON DIOXIDE, AND THE BINARY SYSTEM WATER + CARBON DIOXIDE the vapor-liquid equilibrium of water (between 323 and 573 K), carbon dioxide (between 230 and 290 K

  9. Spectroscopic investigations of hydrogen bond dynamics in liquid water

    E-Print Network [OSTI]

    Fecko, Christopher J., 1975-

    2004-01-01T23:59:59.000Z

    Many of the remarkable physical and chemical properties of liquid water are due to the strong influence hydrogen bonds have on its microscopic dynamics. However, because of the fast timescales involved, there are relatively ...

  10. Liquid water: A very complex fluid H EUGENE STANLEY

    E-Print Network [OSTI]

    Stanley, H. Eugene

    Liquid water: A very complex fluid H EUGENE STANLEY Center for Polymer Studies and Department, M Canpolat, M Meyer, O Mishima, R Sadr-Lahijany, A Scala and F W Starr. It is also based on earlier

  11. Water at the Surfaces of Aligned Phospholipid Multibilayer Model Membranes Probed with Ultrafast Vibrational

    E-Print Network [OSTI]

    Fayer, Michael D.

    Water at the Surfaces of Aligned Phospholipid Multibilayer Model Membranes Probed with Ultrafast@stanford.edu Abstract: The dynamics of water at the surface of artificial membranes composed of aligned multibilayers pump-probe spectroscopy. The experiments are performed at various hydration levels, x ) 2 - 16 water

  12. Process for blending coal with water immiscible liquid

    DOE Patents [OSTI]

    Heavin, Leonard J. (Olympia, WA); King, Edward E. (Gig Harbor, WA); Milliron, Dennis L. (Lacey, WA)

    1982-10-26T23:59:59.000Z

    A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

  13. Out of equilibrium GigaPa Young modulus of water nanobridge probed by Force Feedback Microscopy

    E-Print Network [OSTI]

    Simon Carpentier; Mario S. Rodrigues; Luca Costa; Miguel V. Vitorino; Elisabeth Charlaix; Joel Chevrier

    2015-03-18T23:59:59.000Z

    Because of capillary condensation, water droplets appear in nano/micropores. The large associated surface interactions can deeply influence macroscopic properties as in granular media. We report that dynamical properties of such nanobridge dramatically change when probed at different time scales. Using a novel AFM mode, the Force Feedback Microscopy, the gap between the nanotip and the surface is continuously varied, and we observe this change in the simultaneous measurements, at different frequencies, of the stiffness G'(N/m), the dissipative coefficient G"(kg/sec) together with the static force. As the measuring time approaches the microsecond, the liquid droplet exhibits a large positive stiffness (it is small and negative in the long time limit). Although clearly controlled by surface effects, it compares to the stiffness of a solid nanobridge with a 1 GigaPa Young modulus. We argue that as evaporation and condensation gradually lose efficiency, the contact line progressively becomes immobile, which explains this behavior.

  14. Out of equilibrium GigaPa Young modulus of water nanobridge probed by Force Feedback Microscopy

    E-Print Network [OSTI]

    Carpentier, Simon; Costa, Luca; Vitorino, Miguel V; Charlaix, Elisabeth; Chevrier, Joel

    2015-01-01T23:59:59.000Z

    Because of capillary condensation, water droplets appear in nano/micropores. The large associated surface interactions can deeply influence macroscopic properties as in granular media. We report that dynamical properties of such nanobridge dramatically change when probed at different time scales. Using a novel AFM mode, the Force Feedback Microscopy, the gap between the nanotip and the surface is continuously varied, and we observe this change in the simultaneous measurements, at different frequencies, of the stiffness G'(N/m), the dissipative coefficient G"(kg/sec) together with the static force. As the measuring time approaches the microsecond, the liquid droplet exhibits a large positive stiffness (it is small and negative in the long time limit). Although clearly controlled by surface effects, it compares to the stiffness of a solid nanobridge with a 1 GigaPa Young modulus. We argue that as evaporation and condensation gradually lose efficiency, the contact line progressively becomes immobile, which expla...

  15. Behavior of Supercooled Aqueous Solutions Stemming from Hidden Liquid-Liquid Transition in Water

    E-Print Network [OSTI]

    John W. Biddle; Vincent Holten; Mikhail A. Anisimov

    2014-08-21T23:59:59.000Z

    A popular hypothesis that explains the anomalies of supercooled water is the existence of a metastable liquid-liquid transition hidden below the line of homogeneous nucleation. If this transition exists and if it is terminated by a critical point, the addition of a solute should generate a line of liquid-liquid critical points emanating from the critical point of pure metastable water. We have analyzed thermodynamic consequences of this scenario. In particular, we consider the behavior of two systems, H2O-NaCl and H2O-glycerol. We find the behavior of the heat capacity in supercooled aqueous solutions of NaCl, as reported by Archer and Carter, to be consistent with the presence of the metastable liquid-liquid transition. We suggest an interpretation of the liquid-liquid transition in aqueous solutions of glycerol, recently observed by Murata and Tanaka, elucidating the non-conserved nature of the order parameter, its coupling with density and concentration, and the peculiarity of "spinodal decomposition without phase separation". We also show how the shape of the critical line in a solution controls the difference in concentration of the coexisting liquid phases.

  16. Isotope and Temperature Effects in Liquid Water Probed by Soft...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    processes in aqueous environments is lacking. To address this need, researchers from Germany and the U.S. have used soft x-ray spectroscopy at the ALS to gain detailed insight...

  17. Dynamics of Nanoscopic Water: Vibrational Echo and Infrared Pump-Probe Studies of Reverse Micelles

    E-Print Network [OSTI]

    Fayer, Michael D.

    Dynamics of Nanoscopic Water: Vibrational Echo and Infrared Pump-Probe Studies of Reverse MicellesVersity, Stanford, California 94305 ReceiVed: April 8, 2005; In Final Form: May 12, 2005 The dynamics of water of the hydrogen-bond network dynamics. Pump-probe experiments show that the vibrational lifetime of the OD stretch

  18. Structure and Depletion at Fluoro- and Hydro-carbon/Water Liquid/Liquid Interfaces

    E-Print Network [OSTI]

    Kaoru Kashimoto; Jaesung Yoon; Binyang Hou; Chiu-hao Chen; Binhua Lin; Makoto Aratono; Takanori Takiue; Mark L. Schlossman

    2008-07-18T23:59:59.000Z

    The results of x-ray reflectivity studies of two oil/water (liquid/liquid) interfaces are inconsistent with recent predictions of the presence of a vapor-like depletion region at hydrophobic/aqueous interfaces. One of the oils, perfluorohexane, is a fluorocarbon whose super-hydrophobic interface with water provides a stringent test for the presence of a depletion layer. The other oil, heptane, is a hydrocarbon and, therefore, is more relevant to the study of biomolecular hydrophobicity. These results are consistent with the sub-angstrom proximity of water to soft hydrophobic materials.

  19. Local Structure Analysis in $Ab$ $Initio$ Liquid Water

    E-Print Network [OSTI]

    Biswajit Santra; Robert A. DiStasio Jr.; Fausto Martelli; Roberto Car

    2015-02-27T23:59:59.000Z

    Within the framework of density functional theory, the inclusion of exact exchange and non-local van der Waals/dispersion (vdW) interactions is crucial for predicting a microscopic structure of ambient liquid water that quantitatively agrees with experiment. In this work, we have used the local structure index (LSI) order parameter to analyze the local structure in such highly accurate $ab$ $initio$ liquid water. At ambient conditions, the LSI probability distribution, P($I$), was unimodal with most water molecules characterized by more disordered high-density-like local environments. With thermal excitations removed, the resultant bimodal P($I$) in the inherent potential energy surface (IPES) exhibited a 3:1 ratio between high- and low-density-like molecules, with the latter forming small connected clusters amid the predominant population. By considering the spatial correlations and hydrogen bond network topologies $among$ water molecules with the same LSI identities, we demonstrate that the signatures of the experimentally observed low- (LDA) and high-density (HDA) amorphous phases of ice are present in the IPES of ambient liquid water. Analysis of the LSI autocorrelation function uncovered a persistence time of $\\sim$ 4 ps---a finding consistent with the fact that natural thermal fluctuations are responsible for transitions between these distinct yet transient local aqueous environments in ambient liquid water.

  20. How the Liquid-Liquid Transition Affects Hydrophobic Hydration in Deeply Supercooled Water

    E-Print Network [OSTI]

    Dietmar Paschek

    2005-03-21T23:59:59.000Z

    We determine the phase diagram of liquid supercooled water by extensive computer simulations using the TIP5P-E model [J. Chem. Phys. {\\bf 120}, 6085 (2004)]. We find that the transformation of water into a low density liquid in the supercooled range strongly enhances the solubility of hydrophobic particles. The transformation of water into a tetrahedrally structured liquid is accompanied by a minimum in the hydration entropy and enthalpy. The corresponding change in sign of the solvation heat capacity indicates a loss of one characteristic signature of hydrophobic hydration. The observed behavior is found to be qualitatively in accordance with the predictions of the information theory model of Garde et al. [Phys. Rev. Lett. {\\bf 77}, 4966 (1996)].

  1. Liquid-Liquid Phase Transition in Confined Water: A Monte Carlo Study Martin Meyer and H. Eugene Stanley*

    E-Print Network [OSTI]

    Stanley, H. Eugene

    Liquid-Liquid Phase Transition in Confined Water: A Monte Carlo Study Martin Meyer and H. Eugene Stanley* Center for Polymer Studies and Department of Physics, Boston UniVersity, Boston, Massachusetts

  2. Local Structure Analysis in $Ab$ $Initio$ Liquid Water

    E-Print Network [OSTI]

    Santra, Biswajit; Martelli, Fausto; Car, Roberto

    2015-01-01T23:59:59.000Z

    Within the framework of density functional theory, the inclusion of exact exchange and non-local van der Waals/dispersion (vdW) interactions is crucial for predicting a microscopic structure of ambient liquid water that quantitatively agrees with experiment. In this work, we have used the local structure index (LSI) order parameter to analyze the local structure in such highly accurate $ab$ $initio$ liquid water. At ambient conditions, the LSI probability distribution, P($I$), was unimodal with most water molecules characterized by more disordered high-density-like local environments. With thermal excitations removed, the resultant bimodal P($I$) in the inherent potential energy surface (IPES) exhibited a 3:1 ratio between high- and low-density-like molecules, with the latter forming small connected clusters amid the predominant population. By considering the spatial correlations and hydrogen bond network topologies $among$ water molecules with the same LSI identities, we demonstrate that the signatures of th...

  3. Glass transition in biomolecules and the liquid-liquid critical point of water

    E-Print Network [OSTI]

    P. Kumar; Z. Yan; L. Xu; M. G. Mazza; S. V. Buldyrev; S. -H. Chen; S. Sastry; H. E. Stanley

    2006-08-28T23:59:59.000Z

    Using molecular dynamics simulations, we investigate the relation between the dynamic transitions of biomolecules (lysozyme and DNA) and the dynamic and thermodynamic properties of hydration water. We find that the dynamic transition of the macromolecules, sometimes called a ``protein glass transition'', occurs at the temperature of dynamic crossover in the diffusivity of hydration water, and also coincides with the maxima of the isobaric specific heat $C_P$ and the temperature derivative of the orientational order parameter. We relate these findings to the hypothesis of a liquid-liquid critical point in water. Our simulations are consistent with the possibility that the protein glass transition results from crossing the Widom line, which is defined as the locus of correlation length maxima emanating from the hypothesized second critical point of water.

  4. Water dynamics: dependence on local structure probed with vibrational echo correlation spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Water dynamics: dependence on local structure probed with vibrational echo correlation spectroscopyD stretching band of HOD in H2O and molecular dynamics simulations are employed to investigate water dynamics. The wavelength dependence of the measured dynamics demonstrates that different hydrogen bonded water species

  5. Soil Water Retention Measurements Using a Combined Tensiometer-Coiled Time Domain Reflectometry Probe

    E-Print Network [OSTI]

    Wildenschild, Dorthe

    Soil Water Retention Measurements Using a Combined Tensiometer-Coiled Time Domain Reflectometry al., 1975; Arya et al.,that can be used to determine soil water retention curves in both 1975; Royer of a standard tensiometer. The combined tensiometer-coiled TDR probe was con- of soil water retention curves

  6. Probing the hydrogen-bond network of water via time-resolved soft x-ray spectroscopy

    SciTech Connect (OSTI)

    Huse, Nils; Wen, Haidan; Nordlund, Dennis; Szilagyi, Erzsi; Daranciang, Dan; Miller, Timothy A.; Nilsson, Anders; Schoenlein, Robert W.; Lindenberg, Aaron M.

    2009-04-24T23:59:59.000Z

    We report time-resolved studies of hydrogen bonding in liquid H2O, in response to direct excitation of the O-H stretch mode at 3 mu m, probed via soft x-ray absorption spectroscopy at the oxygen K-edge. This approach employs a newly developed nanofluidic cell for transient soft x-ray spectroscopy in liquid phase. Distinct changes in the near-edge spectral region (XANES) are observed, and are indicative of a transient temperature rise of 10K following transient laser excitation and rapid thermalization of vibrational energy. The rapid heating occurs at constant volume and the associated increase in internal pressure, estimated to be 8MPa, is manifest by distinct spectral changes that differ from those induced by temperature alone. We conclude that the near-edge spectral shape of the oxygen K-edge is a sensitive probe of internal pressure, opening new possibilities for testing the validity of water models and providing new insight into the nature of hydrogen bonding in water.

  7. Liquid-liquid equilibrium of cyclohexane-n-hexane-methanol mixtures; Effect of water content

    SciTech Connect (OSTI)

    Alessi, P.; Fermeglia, M.; Kikic, I. (Istituto di Chimica Applicata e Industriale, University of Trieste, via Valerio 2, I-34127 Trieste (IT))

    1989-04-01T23:59:59.000Z

    Experimental liquid-liquid equilibrium data for the ternary system cyclohexane-n-hexane-methanol and for the binary systems n-hexane-methanol and cyclohexane-methanol are presented over a temperature range from 284 to 298{Kappa} at pressure of 0.1 MPa. Attention is given to the effect of the purity of methanol as far as the water content is concerned. The data are correlated by means of excess Gibbs energy models (NRTL and UNIQUAC), and the binary interaction parameters are reported.

  8. Measurement of Liquid Water Accumulation in a PEMFC with Dead-Ended Anode

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    Measurement of Liquid Water Accumulation in a PEMFC with Dead-Ended Anode Jason B. Siegel,a, *,z, Maryland 20899, USA The operation and accumulation of liquid water within the cell structure of a polymer, accumulation of liquid water in the anode gas distribution channels was observed in most tested conditions

  9. Liquid water transport in fuel cell gas diffusion layers Aimy Ming Jii Bazylak

    E-Print Network [OSTI]

    Victoria, University of

    Liquid water transport in fuel cell gas diffusion layers by Aimy Ming Jii Bazylak Bachelor means, without the permission of the author. #12;ii Liquid water transport in fuel cell gas diffusion State University) Abstract Liquid water management has a major impact on the performance and durability

  10. Coupled cluster benchmarks of water monomers and dimers extracted from density-functional theory liquid water: The importance of monomer

    E-Print Network [OSTI]

    Alavi, Ali

    Coupled cluster benchmarks of water monomers and dimers extracted from density-functional theory functionals in simulations of liquid water, water monomers and dimers were extracted from a PBE simulation liquid water: The importance of monomer deformations Biswajit Santra,1 Angelos Michaelides,1,2,a

  11. Distributed Reforming of Renewable Liquids via Water Splitting using

    E-Print Network [OSTI]

    circuitry/power supply Non-galvanic Single material (no electrodes) Ethanol/NG Steam O2- 1/2 O2 + 2e- 1/2 O.C2H5OH + 1/2 O2 2CO + 3H2 Predominant products of ethanol reforming: H2, CO, CO2, CH4, H2O #12Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM

  12. Gas-Liquid Coexistence in the Primitive Model for Water

    E-Print Network [OSTI]

    F. Romano; P. Tartaglia; F. Sciortino

    2007-05-08T23:59:59.000Z

    We evaluate the location of the gas-liquid coexistence line and of the associated critical point for the primitive model for water (PMW), introduced by Kolafa and Nezbeda [J. Kolafa and I. Nezbeda, Mol. Phys. 61, 161 (1987)]. Besides being a simple model for a molecular network forming liquid, the PMW is representative of patchy proteins and novel colloidal particles interacting with localized directional short-range attractions. We show that the gas-liquid phase separation is metastable, i.e. it takes place in the region of the phase diagram where the crystal phase is thermodynamically favored, as in the case of articles interacting via short-range attractive spherical potentials. Differently from spherical potentials, we do not observe crystallization close to the critical point. The region of gas-liquid instability of this patchy model is significantly reduced as compared to equivalent models of spherically interacting particles, confirming the possibility of observing kinetic arrest in an homogeneous sample driven by bonding as opposed to packing.

  13. Water clusters: Untangling the mysteries of the liquid, one molecule at a time

    E-Print Network [OSTI]

    Cohen, Ronald C.

    to accurately calculate the properties of liquid water (e.g., heat capacity, density, dielectric constantWater clusters: Untangling the mysteries of the liquid, one molecule at a time Frank N. Keutsch- ative hydrogen bonding and promises to lead to a more complete molecular description of the liquid

  14. Probing the Interaction of Amorphous Solid Water on a Hydrophobic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface: Dewetting and Crystallization Kinetics of ASW on Abstract: Desorption of carbon tetrachloride from beneath an amorphous solid water (ASW) overlayer is explored...

  15. Selective extraction of copper, mercury, silver and palladium ions from water using hydrophobic ionic liquids.

    E-Print Network [OSTI]

    Papaiconomou, Nicolas; Lee, Jong-Min; Salminen, Justin; Von Stosch, Moritz; Prausnitz, John M.

    2008-01-01T23:59:59.000Z

    for metal-ion extraction from water. All ionic liquids (useful for extraction of cations from water. 9-15 Previoussingle extraction of mercury in water with either [3MOPYR

  16. Liquid-liquid equilibria of the ternary system water + acetic acid + 2-methyl-2-butanol

    SciTech Connect (OSTI)

    Fahim, M.A.; Al-Muhtaseb, S.A. [United Arab Emirates Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering] [United Arab Emirates Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering

    1996-11-01T23:59:59.000Z

    Liquid-liquid equilibria for the ternary system water + acetic acid + 2-methyl-2-butanol were measured over a temperature range of (288 to 323) K. The results were used to estimate the interaction parameters between each of the three compounds for the NRTL and UNIQUAC models and between each of the main groups of H{sub 2}O, CH{sub 2} (paraffinic CH{sub 2}), OH, and COOH for the UJNIFAC model as a function of temperature. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the three models. The NRTL equation was the most accurate model in correlating the overall equilibrium compositions of the studied system. The UNIFAC model satisfactorily predicted the equilibrium compositions.

  17. Liquid-liquid equilibria of the ternary system water + acetic acid + 1-hexanol

    SciTech Connect (OSTI)

    Fahim, M.A. [Kuwait Univ., Safat (Kuwait). Dept. of Chemical Engineering] [Kuwait Univ., Safat (Kuwait). Dept. of Chemical Engineering; Al-Muhtaseb, S.A.; Al-Nashef, I.M. [U.A.E. Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering] [U.A.E. Univ., Al-Ain (United Arab Emirates). Dept. of Chemical and Petroleum Engineering

    1997-01-01T23:59:59.000Z

    The recovery of organic acids from dilute solutions resulting from fermentation processes is important and many solvents have been tried to improve such recovery. Liquid-liquid equilibria for the ternary system water + acetic acid + 1-hexanol were measured over a temperature range of (288 to 323) K. The results were used to estimate the interaction parameters between each of the three compounds for the NRTL and UNIQUAC models and between each of the main groups of H{sub 2}O, CH{sub 2} (paraffinic CH{sub 2}), OH, and COOH for the UNIFAC model as a function of temperature. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the three models. The NRTL equation was the most accurate model in correlating the overall equilibrium compositions of the studied system. The UNIQUAC and UNIFAC models satisfactorily predicted the equilibrium compositions.

  18. Reference Correlations for Thermophysical Properties of Liquid Water Jaroslav Ptek, Jan Hrub,a...

    E-Print Network [OSTI]

    Magee, Joseph W.

    of sound , viscosity, thermal con- ductivity, and static dielectric constant of liquid water as a function capacity; speed of sound; thermal conductivity; ther- modynamic properties; viscosity; water. CONTENTS 1Reference Correlations for Thermophysical Properties of Liquid Water at 0.1 MPa Jaroslav Pátek, Jan

  19. Direct Analysis of Reversed-Phase HPTLC Separated Tryptic Protein Digests using a Liquid Microjunction Surface Sampling Probe/ESI-MS System

    SciTech Connect (OSTI)

    Emory, Joshua F [ORNL; Walworth, Matthew J [ORNL; Van Berkel, Gary J [ORNL; Schulz, Michael [Merck Research Laboratories; Minarik, susanne [Merck Research Laboratories

    2010-01-01T23:59:59.000Z

    The sampling, ionization and detection of tryptic peptides separated in one-dimension on reversed phase HPTLC plates was performed using liquid microjunction surface sampling probe electrospray ionization mass spectrometry. Tryptic digests of five proteins (cytochrome c., myoglobin, beta-casein, lysozyme, and bovine serum albumin) were spotted on reversed phase HPTLC RP-8 F254s and HPTLC RP-18 F254s plates. The plates were then developed using 70/30 methanol/water with 0.1 M ammonium acetate. A dual purpose extraction/electrospray solution containing 70/30/0.1 water/methanol/formic acid was infused through the sampling probe during analysis of the developed lanes. Both full scan mass spectra and data dependent tandem mass spectra were acquired for each development lane to detect and verify the peptide distributions. Data dependent tandem mass spectra provided both protein identification and sequence coverage information. Highest sequence coverages were achieved for cytochrome c. and myoglobin (62.5% and 58.3%, respectively) on reversed phase RP-8 plates. While the tryptic peptides were separated enough for identification, the peptide bands did show some overlap with most peptides located in the lower half of the development lane. Proteins whose peptides were more separated gave higher sequence coverage. Larger proteins such as beta-casein and BSA which were spotted in lower relative amounts gave much lower sequence coverage than the smaller proteins.

  20. Combustion of Nano-Aluminum and Liquid Water G.A. Risha, S.F. Son

    E-Print Network [OSTI]

    Yang, Vigor

    1 Combustion of Nano-Aluminum and Liquid Water G.A. Risha, S.F. Son , R.A. Yetter, V. Yang, and B: Supplemental materials submitted #12;2 Combustion of Nano-Aluminum and Liquid Water G.A. Risha, S.F. Son, R of nano-aluminum (nAl) and liquid water has been conducted. In particular, linear and mass-burning rates

  1. Probing Water Phases in Cement Blends using 1 Magnetic Resonance Relaxometry

    E-Print Network [OSTI]

    Sheffield, University of

    Probing Water Phases in Cement Blends using 1 H Nuclear Magnetic Resonance Relaxometry Jean)114 222 5973 Fax: +44 (0)114 222 5943 E-Mail: j.gorce@sheffield.ac.uk Extended Abstract: Cement and Concrete Science, Warwick, 16th + 17th September 2004 Introduction The nuclear industry uses blended cement

  2. Probing water transport in polymer electrolyte fuel cells with neutron radiography

    E-Print Network [OSTI]

    Mench, Matthew M.

    and Fuel Cell Dynamics and Diagnostics Laboratory, The Pennsylvania State University, USA b ResearchProbing water transport in polymer electrolyte fuel cells with neutron radiography Kyu Taek Cho a Available online 5 February 2009 Keywords: Polymer electrolyte fuel cell Gas purge Neutron radiography Heavy

  3. Basalt weathering rates on Earth and the duration of liquid water on the plains of Gusev Crater, Mars

    E-Print Network [OSTI]

    Hausrath, E.M.

    2008-01-01T23:59:59.000Z

    Basalt weathering rates on Earth and the duration of liquidCarlisle, PA 17013 Earth Sciences Division, Lawrencetime to liquid water: on Earth, mineral persistence times

  4. Electrokinetic Hydrogen Generation from Liquid WaterMicrojets

    SciTech Connect (OSTI)

    Duffin, Andrew M.; Saykally, Richard J.

    2007-05-31T23:59:59.000Z

    We describe a method for generating molecular hydrogen directly from the charge separation effected via rapid flow of liquid water through a metal orifice, wherein the input energy is the hydrostatic pressure times the volume flow rate. Both electrokinetic currents and hydrogen production rates are shown to follow simple equations derived from the overlap of the fluid velocity gradient and the anisotropic charge distribution resulting from selective adsorption of hydroxide ions to the nozzle surface. Pressure-driven fluid flow shears away the charge balancing hydronium ions from the diffuse double layer and carries them out of the aperture. Downstream neutralization of the excess protons at a grounded target electrode produces gaseous hydrogen molecules. The hydrogen production efficiency is currently very low (ca. 10-6) for a single cylindrical jet, but can be improved with design changes.

  5. Isobaric vapor-liquid equilibria for methanol + ethanol + water and the three constituent binary systems

    SciTech Connect (OSTI)

    Kurihara, Kiyofumi; Nakamichi, Mikiyoshi; Kojima, Kazuo (Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry)

    1993-07-01T23:59:59.000Z

    Vapor-liquid equilibrium data for methanol + ethanol + water and its three constituent binary systems methanol + ethanol, ethanol + water, and methanol + water were measured at 101.3 kPa using a liquid-vapor ebullition-type equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system methanol + ethanol + water was predicted by means of the binary NRTL parameters with good accuracy.

  6. 1 DECEMBER 1995 Validation of Satellite Retrievals of Cloud Microphysics and Liquid Water Path

    E-Print Network [OSTI]

    Han, Quingyuan

    1 DECEMBER 1995 Validation of Satellite Retrievals of Cloud Microphysics and Liquid Water Path Using Observations from FIRE 1, Introduction Q. HAN, * W. Rossow, t R. WELCH, * A. WHITE, * * AND J Cloud effective radii (r) and cloud liquid water path (LWP) are derived from ISCCP spatially sampled

  7. Decomposing aerosol cloud radiative effects into cloud cover, liquid water path and Twomey components

    E-Print Network [OSTI]

    Daniel, Rosenfeld

    Decomposing aerosol cloud radiative effects into cloud cover, liquid water path and Twomey interactions radiative effects, i.e., the cloud cover, liquid water path (LWP) and cloud drop radius (Twomey negative radiative forcing on the global scale, mainly due to the cloud cover effect. 2013 Elsevier B

  8. Network analysis of proton transfer in liquid water

    SciTech Connect (OSTI)

    Shevchuk, Roman; Rao, Francesco, E-mail: francesco.rao@frias.uni-freiburg.de [Freiburg Institute for Advanced Studies, School of Soft Matter Research, Freiburg im Breisgau (Germany); Agmon, Noam [Institute of Chemistry, The Hebrew University of Jerusalem, Jerusalem (Israel)

    2014-06-28T23:59:59.000Z

    Proton transfer in macromolecular systems is a fascinating yet elusive process. In the last ten years, molecular simulations have shown to be a useful tool to unveil the atomistic mechanism. Notwithstanding, the large number of degrees of freedom involved make the accurate description of the process very hard even for the case of proton diffusion in bulk water. Here, multi-state empirical valence bond molecular dynamics simulations in conjunction with complex network analysis are applied to study proton transfer in liquid water. Making use of a transition network formalism, this approach takes into account the time evolution of several coordinates simultaneously. Our results provide evidence for a strong dependence of proton transfer on the length of the hydrogen bond solvating the Zundel complex, with proton transfer enhancement as shorter bonds are formed at the acceptor site. We identify six major states (nodes) on the network leading from the special pair to a more symmetric Zundel complex required for transferring the proton. Moreover, the second solvation shell specifically rearranges to promote the transfer, reiterating the idea that solvation beyond the first shell of the Zundel complex plays a crucial role in the process.

  9. Parameterization of GDL Liquid Water Front Propagation and Channel Accumulation for Anode Purge Scheduling in Fuel Cells

    E-Print Network [OSTI]

    Stefanopoulou, Anna

    Parameterization of GDL Liquid Water Front Propagation and Channel Accumulation for Anode Purge, and (2) accumulation and transport of liquid water in the Gas Diffusion Layer (GDL) originally presented experimentally iden- tified parameter to match the rate of liquid water accumulation in the anode channel

  10. Long time fluctuation of liquid water: l/f spectrum of energy fluctuation in hydrogen bond network rearrangement dynamics

    E-Print Network [OSTI]

    Ramaswamy, Ram

    Long time fluctuation of liquid water: l/f spectrum of energy fluctuation in hydrogen bond network of the potential energy fluctuation of liquid water is examined and found to yield so-called l/f frequency of hydrogen bond network relaxations in liquid water. A simple model of cellular dynamics is proposed

  11. MODELING OF LIQUID WATER ON CM PARENT BODIES AND IMPLICATIONS FOR AMINO ACID RACEMIZATION. B. A. Cohen

    E-Print Network [OSTI]

    Cohen, Barbara Anne

    the most recent tem- perature-dependent expressions for thermal conductiv- ity, heat capacity, densityMODELING OF LIQUID WATER ON CM PARENT BODIES AND IMPLICATIONS FOR AMINO ACID RACEMIZATION. B. A and duration of a liquid water phase [1]. The characteris- tics of the liquid water phase are critical

  12. On the Fluctuations that Order and Frustrate Liquid Water

    E-Print Network [OSTI]

    Limmer, David

    2013-01-01T23:59:59.000Z

    Quantitative water model . . . . . . . . . . . . . . . .5.3 Determining T g for water . . . . . . . . . . . . . . .iv Contents 6 Frustrating water at ordered surfaces 6.1

  13. Free energy surface of ST2 water near the liquid-liquid phase transition Peter H. Poole, Richard K. Bowles, Ivan Saika-Voivod, and Francesco Sciortino

    E-Print Network [OSTI]

    Sciortino, Francesco

    Free energy surface of ST2 water near the liquid-liquid phase transition Peter H. Poole, Richard K://jcp.aip.org/about/rights_and_permissions #12;THE JOURNAL OF CHEMICAL PHYSICS 138, 034505 (2013) Free energy surface of ST2 water near umbrella sampling Monte Carlo simulations to evaluate the free energy surface of the ST2 model of water

  14. Water-saving liquid-gas conditioning system

    DOE Patents [OSTI]

    Martin, Christopher; Zhuang, Ye

    2014-01-14T23:59:59.000Z

    A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

  15. Probing the Earth's interior with a large-volume liquid scintillator detector

    E-Print Network [OSTI]

    Kathrin A. Hochmuth; Franz v. Feilitzsch; Brian D. Fields; Teresa Marrodan Undagoitia; Lothar Oberauer; Walter Potzel; Georg G. Raffelt; Michael Wurm

    2006-10-04T23:59:59.000Z

    A future large-volume liquid scintillator detector would provide a high-statistics measurement of terrestrial antineutrinos originating from $\\beta$-decays of the uranium and thorium chains. In addition, the forward displacement of the neutron in the detection reaction $\\bar\

  16. Ab initio calculation of the electronic absorption spectrum of liquid water

    SciTech Connect (OSTI)

    Martiniano, Hugo F. M. C.; Galamba, Nuno [Grupo de Fsica Matemtica da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal)] [Grupo de Fsica Matemtica da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Cabral, Benedito J. Costa, E-mail: ben@cii.fc.ul.pt [Grupo de Fsica Matemtica da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal) [Grupo de Fsica Matemtica da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Departamento de Qumica e Bioqumica, Faculdade de Cincias, Universidade de Lisboa, 1749-016 Lisboa (Portugal); Instituto de Fsica da Universidade de So Paulo, CP 66318, 05314-970 So Paulo, SP (Brazil)

    2014-04-28T23:59:59.000Z

    The electronic absorption spectrum of liquid water was investigated by coupling a one-body energy decomposition scheme to configurations generated by classical and Born-Oppenheimer Molecular Dynamics (BOMD). A Frenkel exciton Hamiltonian formalism was adopted and the excitation energies in the liquid phase were calculated with the equation of motion coupled cluster with single and double excitations method. Molecular dynamics configurations were generated by different approaches. Classical MD were carried out with the TIP4P-Ew and AMOEBA force fields. The BLYP and BLYP-D3 exchange-correlation functionals were used in BOMD. Theoretical and experimental results for the electronic absorption spectrum of liquid water are in good agreement. Emphasis is placed on the relationship between the structure of liquid water predicted by the different models and the electronic absorption spectrum. The theoretical gas to liquid phase blue-shift of the peak positions of the electronic absorption spectrum is in good agreement with experiment. The overall shift is determined by a competition between the OH stretching of the water monomer in liquid water that leads to a red-shift and polarization effects that induce a blue-shift. The results illustrate the importance of coupling many-body energy decomposition schemes to molecular dynamics configurations to carry out ab initio calculations of the electronic properties in liquid phase.

  17. Polymer formulation for removing hydrogen and liquid water from an enclosed space

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA)

    2006-02-21T23:59:59.000Z

    This invention describes a solution to the particular problem of liquid water formation in hydrogen getters exposed to quantities of oxygen. Water formation is usually desired because the recombination reaction removes hydrogen without affecting gettering capacity and the oxygen removal reduces the chances for a hydrogen explosion once free oxygen is essentially removed. The present invention describes a getter incorporating a polyacrylate compound that can absorb up to 500% of its own weight in liquid water without significantly affecting its hydrogen gettering/recombination properties, but that also is insensitive to water vapor.

  18. Neutron scattering as a probe of liquid crystal polymer-reinforced composite materials

    SciTech Connect (OSTI)

    Hjelm, R.P.; Douglas, E.P.; Benicewicz, B.C.; Langlois, D.A.

    1995-12-31T23:59:59.000Z

    This is the final report of a three-year Laboratory-Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This research project sought to obtain nanoscale and molecular level information on the mechanism of reinforcement in liquid crystal polymer (LCP)-reinforced composites, to realize molecular-reinforced LCP composites, and to test the validity of the concept of molecular reinforcement. Small-angle neutron scattering was used to study the structures in the ternary phase diagram of LCP with liquid crystal thermosets and solvent on length scales ranging from 1-100 nm. The goal of the scattering measurements is to understand the phase morphology and degree of segregation of the reinforcing and matrix components. This information helps elucidate the physics of self assembly in these systems. This work provides an experimental basis for a microengineering approach to composites of vastly improved properties.

  19. Nuclear tanker producing liquid fuels from air and water

    E-Print Network [OSTI]

    Galle-Bishop, John Michael

    2011-01-01T23:59:59.000Z

    Emerging technologies in CO? air capture, high temperature electrolysis, microchannel catalytic conversion, and Generation IV reactor plant systems have the potential to create a shipboard liquid fuel production system ...

  20. Using Tender x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Axnanda, Stephanus [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Crumlin, Ethan J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Mao, Baohua [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Rani, Sana [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chang, Rui [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Karlsson, Patrik G. [VG Scienta,Uppsala (Sweden); Edwards, Mrten O. M. [VG Scienta,Uppsala (Sweden); Lundqvist, Mns [VG Scienta,Uppsala (Sweden); Moberg, Robert [VG Scienta,Uppsala (Sweden); Ross, Phil [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Hussain, Zahid [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Liu, Zhi [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chinese Academy of Sciences, Shanghai (Republic of China); Shanghai Tech Univ., Shanghai (China)

    2015-05-07T23:59:59.000Z

    We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of detecting high kinetic energy photoelectrons (7 keV) at a pressure up to 110 Torr has been constructed and commissioned. Additionally, we have deployed a dip & pull method to create a stable nanometers-thick aqueous electrolyte on platinum working electrode surface. Combining the newly constructed AP-XPS system, dip & pull approach, with a tender X-ray synchrotron source (2 keV7 keV), we are able to access the interface between liquid and solid dense phases with photoelectrons and directly probe important phenomena occurring at the narrow solid-liquid interface region in an electrochemical system. Using this approach, we have performed electrochemical oxidation of the Pt electrode at an oxygen evolution reaction (OER) potential. Under this potential, we observe the formation of both Pt? and Pt?? interfacial species on the Pt working electrode in situ. We believe this thin-film approach and the use of tender AP-XPS highlighted in this study is an innovative new approach to probe this key solid-liquid interface region of electrochemistry.

  1. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria, E-mail: Valeria.Molinero@utah.edu [Department of Chemistry, The University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112-0850 (United States)

    2014-11-14T23:59:59.000Z

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  2. Simultaneous photon absorption as a probe of molecular interaction and hydrogen-bond correlation in liquids

    E-Print Network [OSTI]

    Sander Woutersen

    2007-03-06T23:59:59.000Z

    We have investigated the simultaneous absorption of near-infrared photons by pairs of neighboring molecules in liquid methanol. Simultaneous absorption by two OH-stretching modes is found to occur at an energy higher than the sum of the two absorbing modes. This frequency shift arises from interaction between the modes, and its value has been used to determine the average coupling between neighboring methanol molecules. We find a rms coupling strength of 46+/-1 cm-1, much larger than can be explained from transition-dipole coupling, suggesting that hydrogen-bond mediated interactions between neighboring molecules play an important role in liquid methanol. The most important aspect of simultaneous vibrational absorption is that it allows for a quantitative investigation of hydrogen-bond cooperativity. We derive the extent to which the hydrogen-bond strengths of neighboring molecules are correlated by comparing the line shape of the absorption band caused by simultaneous absorption with that of the fundamental transition. Surprisingly, neighboring hydrogen bonds in methanol are found to be strongly correlated, and from the data we obtain a hydrogen-bond correlation coefficient of 0.69+/-0.12.

  3. Liquid-liquid equilibria of the ternary systems water + acetic acid + ethyl acetate and water + acetic acid + isophorene (3,5,5-trimethyl-2-cyclohexen-1-one)

    SciTech Connect (OSTI)

    Colombo, A.; Battilana, P.; Ragaini, V.; Bianchi, C.L. [Milan Univ. (Italy). Dept. of Physical Chemistry and Electrochemistry] [Milan Univ. (Italy). Dept. of Physical Chemistry and Electrochemistry; Carvoli, G. [Chemial S.p.A., Cavaglia (Italy)] [Chemial S.p.A., Cavaglia (Italy)

    1999-01-01T23:59:59.000Z

    Liquid-liquid equilibria for the ternary systems water + acetic acid + ethyl acetate and water + acetic acid + isophorone (3,5,5-trimethyl-2-cyclohexen-1-one) were measured over the temperature range (283 to 313) K. The results were used to estimate the interaction parameters between each of the three compounds of the systems studied for the NRTL and UNIQUAC models. The estimated interaction parameters were successfully used to predict the equilibrium compositions by the two models; experimental data were successfully reproduced. The UNIQUAC model was the most accurate in correlating the overall equilibrium composition of the studied systems. Also the NRTL model satisfactorily predicted the equilibrium composition. Isophorone experimentally resulted in a better extraction capacity for acetic acid and in a lower miscibility with water.

  4. A liquid water management strategy for PEM fuel cell stacks

    E-Print Network [OSTI]

    Van Nguyen, Trung; Knobbe, M. W.

    2003-02-25T23:59:59.000Z

    Gas and water management are key to achieving good performance from a PEM fuel cell stack. Previous experimentation had found, and this experimentation confirms, that one very effective method of achieving proper gas and water management is the use...

  5. Liquid Water Dynamics in a Model Polymer Electrolyte Fuel Cell Flow Channel

    E-Print Network [OSTI]

    Victoria, University of

    Liquid Water Dynamics in a Model Polymer Electrolyte Fuel Cell Flow Channel by Chris Miller in a Model Polymer Electrolyte Fuel Cell Flow Channel by Chris Miller Bachelors of Engineering, University in a polymer electrolyte fuel cell is a critical issue in ensuring high cell performance. The water production

  6. Estimate of the global distribution of stratiform supercooled liquid water clouds using the LITE lidar

    E-Print Network [OSTI]

    Hogan, Robin

    them to generally have a greater effect on the net radiative fluxes than any ice clouds in the profileEstimate of the global distribution of stratiform supercooled liquid water clouds using the LITE layers that have a much larger radiative impact than ice clouds of the same water content because

  7. Continuous Flow Liquid Microjunction Surface Sampling Probe Connected On-line with HPLC/MS for Spatially Resolved Analysis of Small Molecules and Proteins

    SciTech Connect (OSTI)

    Van Berkel, Gary J [ORNL; Kertesz, Vilmos [ORNL

    2013-01-01T23:59:59.000Z

    RATIONALE: A continuous flow liquid microjunction surface sampling probe extracts soluble material from surfaces for direct ionization and detection by MS. Demonstrated here is the on-line coupling of such a probe with HPLC/MS enabling extraction, separation and detection of small molecules and proteins from surfaces in a spatially resolved (~0.5 mm diameter spots) manner. Methods: A continuous flow liquid microjunction surface sampling probe was connected to a 6-port, 2-position valve for extract collection and injection to an HPLC column. A QTRAP 5500 hybrid triple quadrupole linear ion trap equipped with a Turbo V ion source operated in positive ESI mode was used for all experiments. System operation was tested with extraction, separation and detection of propranolol and associated metabolites from drug dosed tissues and proteins from dried sheep blood spots on paper. Results: Confirmed in the tissue were the parent drug and two different hydroxypropranolol glucuronides. The mass spectrometric response for these compounds from different locations in the liver showed an increase with increasing extraction time (5, 20 and 40 s extractions). For on-line separation and detection/identification of extracted proteins from dried sheep blood spots, two major protein peaks dominated the chromatogram and could be correlated with the expected masses for the hemoglobin and chains. Conclusions: Spatially resolved sampling, separation, and detection of small molecules and proteins from surfaces can be accomplished using a continuous flow liquid microjunction surface sampling probe coupled on-line with HPLC/MS detection.

  8. Using Tender x-ray ambient pressure x-Ray photoelectron spectroscopy as a direct probe of solid-liquid interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Axnanda, Stephanus; Crumlin, Ethan J.; Mao, Baohua; Rani, Sana; Chang, Rui; Karlsson, Patrik G.; Edwards, Mrten O. M.; Lundqvist, Mns; Moberg, Robert; Ross, Phil; et al

    2015-05-07T23:59:59.000Z

    We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS) endstation that is capable of detecting high kinetic energy photoelectrons (7 keV) at a pressure up to 110 Torr has been constructed and commissioned. Additionally, we have deployed a dip & pull method to create a stable nanometers-thick aqueous electrolyte on platinum working electrode surface. Combining the newly constructed AP-XPS system, dip & pull approach, with a tender X-ray synchrotron source (2 keV7 keV), we are able to access the interface between liquidmoreand solid dense phases with photoelectrons and directly probe important phenomena occurring at the narrow solid-liquid interface region in an electrochemical system. Using this approach, we have performed electrochemical oxidation of the Pt electrode at an oxygen evolution reaction (OER) potential. Under this potential, we observe the formation of both Pt? and Pt?? interfacial species on the Pt working electrode in situ. We believe this thin-film approach and the use of tender AP-XPS highlighted in this study is an innovative new approach to probe this key solid-liquid interface region of electrochemistry.less

  9. REVIEW OF SCIENTIFIC INSTRUMENTS 82, 034904 (2011) Fiber optic probe hydrophone for the study of acoustic cavitation in water

    E-Print Network [OSTI]

    Davitt, Kristina

    of acoustic cavitation in water Arnaud Arvengas, Kristina Davitt, and Frédéric Caupina) Laboratoire de. Accord- ing to nucleation theory, increasing the ultrasound frequency increases the cavitation threshold in liquids. We are able to resolve the fractional change in the pressure threshold for cavitation in water

  10. Liquid-liquid equilibria for water + ethanol + 2-methylpropyl ethanoate and water + ethanol + 1,2-dibromoethane at 298. 15 K

    SciTech Connect (OSTI)

    Solimo, H.N.; Barnes de Arreguez, N.G. (Univ. Nacional de Tucuman, San Miguel de Tucuman (Argentina). Inst. de Fisica)

    1994-01-01T23:59:59.000Z

    Liquid-liquid equilibrium, distribution coefficients, and selectivities of the systems water + ethanol + 2-methylpropyl ethanoate or + 1,2-dibromoethane have been determined at 298.15 K in order to evaluate their suitability in preferentially extracting ethanol from aqueous solution. Tie-line data were satisfactorily correlated by the Othmer and Tobias method, and the plait point coordinates for the two systems were estimated. The experimental data was compared with the values calculated by the NRTL and UNIQUAC models. The water + ethanol + 2-methylpropyl ethanoate system was also compared with the values predicted by the UNIFAC model. Poor qualitative agreement was obtained with these models. From the experimental results, they can conclude that both solvents are inappropriate for ethanol extraction processes from aqueous solutions.

  11. Heating-induced glass-glass and glass-liquid transformations in computer simulations of water

    SciTech Connect (OSTI)

    Chiu, Janet; Giovambattista, Nicolas [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States)] [Department of Physics, Brooklyn College of the City University of New York, Brooklyn, New York 11210 (United States); Starr, Francis W. [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)] [Department of Physics, Wesleyan University, Middletown, Connecticut 06459 (United States)

    2014-03-21T23:59:59.000Z

    Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T phase diagram for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related, both being associated with the limit of kinetic stability of LDA (HDA)

  12. Remote sensing of total integrated water vapor, wind speed, and cloud liquid water over the ocean using the Special Sensor Microwave/Imager (SSM/I)

    E-Print Network [OSTI]

    Manning, Norman Willis William

    1997-01-01T23:59:59.000Z

    A modified D-matrix retrieval method is the basis of the refined total integrated water vapor (TIWV), total integrated cloud liquid water (CLW), and surface wind speed (WS) retrieval methods that are developed. The 85 GHZ polarization difference...

  13. Vapor-liquid equilibria of the water + 1,3-propanediol and water + 1,3-propanediol + lithium bromide systems

    SciTech Connect (OSTI)

    Mun, S.Y.; Lee, H.

    1999-12-01T23:59:59.000Z

    Vapor-liquid equilibrium data of the water + 1,3-propanediol and water + 1,3-propanediol + lithium bromide systems were measured at 60, 160, 300, and 760 mmHg at temperatures ranging from 315 to 488 K. The apparatus used in this work is a modified still especially designed for the measurement of low-pressure VLE, in which both liquid and vapor are continuously recirculated. For the analysis of salt-containing solutions, a method incorporating refractometry and gravimetry was used. From the experimental measurements, the effect of lithium bromide on the VLE behavior of water + 1,3-propanediol was investigated. The experimental data of the salt-free system were successfully correlated using the Wilson, NRTL, and UNIQUAC models. In addition, the extended UNIQUAC model of Sander et al. was applied to the VLE calculation of salt-containing mixtures.

  14. Effect of direct liquid water injection and interdigitated flow field on the performance of proton exchange membrane fuel cells

    E-Print Network [OSTI]

    Wood, D. L.; Yi, Y. S.; Van Nguyen, Trung

    1998-01-01T23:59:59.000Z

    Proper water management is vital to ensuring successful performance of proton exchange membrane fuel cells. The effectiveness of the direct liquid water injection scheme and the interdigitated flow field design towards providing adequate gas...

  15. Optical Kerr effect of liquid and supercooled water: the experimental and data analysis perspective

    E-Print Network [OSTI]

    A. Taschin; P. Bartolini; R. Eramo; R. Righini; R. Torre

    2014-06-20T23:59:59.000Z

    The time-resolved optical Kerr effect spectroscopy (OKE) is a powerful experimental tool enabling accurate investigations of the dynamic phenomena in molecular liquids. We introduced innovative experimental and fitting procedures, that permit a safe deconvolution of sample response function from the instrumental function. This is a critical issue in order to measure the dynamics of sample presenting weak signal, e.g. liquid water. We report OKE data on water measuring intermolecular vibrations and the structural relaxation processes in an extended temperature range, inclusive of the supercooled states. The unpreceded data quality makes possible a solid comparison with few theoretical models; the multi-mode Brownian oscillator model, the Kubo's discrete random jump model and the schematic mode-coupling model. All these models produce reasonable good fits of the OKE data of stable liquid water, i.e. over the freezing point. The features of water dynamics in the OKE data becomes unambiguous only at lower temperatures, i.e. for water in the metastable supercooled phase. Hence this data enable a valid comparison between the model fits. We found that the schematic mode-coupling model provides the more rigorous and complete model for water dynamics, even if is intrinsic hydrodynamic approach hide the molecular information.

  16. Park City/ANS 1 ANALYSIS OF LIQUID CRYOGEN-WATER EXPERIMENTS WITH THE MELCOR CODE

    E-Print Network [OSTI]

    California at Los Angeles, University of

    Park City/ANS 1 ANALYSIS OF LIQUID CRYOGEN-WATER EXPERIMENTS WITH THE MELCOR CODE R.C. Duckworth, J code, MELCOR. Experimental results showed that no large `shock' pressures were observed. Thus, one can to benchmark the code and show its usefulness in determining potential critical issues involving these fusion

  17. Life in the Solar System Assume we need energy, liquid water, and organic materials.

    E-Print Network [OSTI]

    Shirley, Yancy

    high pressure, no sunlight, high temperature. Not much chance of life there. Gas Giants #12;The moonsLife in the Solar System Assume we need energy, liquid water, and organic materials. #12;Size N2 Titan Thick atmo Thick atmo Thin atmo #12;Small rocky bodies are unlikely to host life: too hot

  18. Electrokinetic Hydrogen Generation from Liquid Water Microjets Andrew M. Duffin and Richard J. Saykally,*

    E-Print Network [OSTI]

    Cohen, Ronald C.

    of natural gas. These thermal methods are relatively cheap, but they do not mitigate difficulties associatedElectrokinetic Hydrogen Generation from Liquid Water Microjets Andrew M. Duffin and Richard J, 2007; In Final Form: May 31, 2007 We describe a method for generating molecular hydrogen directly from

  19. Evaluating specific error characteristics of microwave-derived cloud liquid water products

    E-Print Network [OSTI]

    Christopher, Sundar A.

    of cloud LWP products globally using concurrent data from visible/ infrared satellite sensors. The approachEvaluating specific error characteristics of microwave-derived cloud liquid water products Thomas J microwave satellite measurements. Using coincident visible/infrared satellite data, errors are isolated

  20. New Mexico cloud super cooled liquid water survey final report 2009.

    SciTech Connect (OSTI)

    Beavis, Nick; Roskovensky, John K.; Ivey, Mark D.

    2010-02-01T23:59:59.000Z

    Los Alamos and Sandia National Laboratories are partners in an effort to survey the super-cooled liquid water in clouds over the state of New Mexico in a project sponsored by the New Mexico Small Business Assistance Program. This report summarizes the scientific work performed at Sandia National Laboratories during the 2009. In this second year of the project a practical methodology for estimating cloud super-cooled liquid water was created. This was accomplished through the analysis of certain MODIS sensor satellite derived cloud products and vetted parameterizations techniques. A software code was developed to analyze multiple cases automatically. The eighty-one storm events identified in the previous year effort from 2006-2007 were again the focus. Six derived MODIS products were obtained first through careful MODIS image evaluation. Both cloud and clear-sky properties from this dataset were determined over New Mexico. Sensitivity studies were performed that identified the parameters which most influenced the estimation of cloud super-cooled liquid water. Limited validation was undertaken to ensure the soundness of the cloud super-cooled estimates. Finally, a path forward was formulized to insure the successful completion of the initial scientific goals which include analyzing different of annual datasets, validation of the developed algorithm, and the creation of a user-friendly and interactive tool for estimating cloud super-cooled liquid water.

  1. VALIDATION OF CLOUD LIQUID WATER PATH RETRIEVALS FROM SEVIRI ON METEOSAT-8 USING CLOUDNET OBSERVATIONS

    E-Print Network [OSTI]

    Haak, Hein

    on global cloud statistics and radiation budget #12;(Feijt et al., 2003). With the launch of Meteosat Second effective radius and Cloud Liquid Water Path (CLWP) over Europe. The CloudNET research project, supported forecast models. The radiative behavior of clouds depends predominantly on cloud properties

  2. Molecular Density Functional Theory for water with liquid-gas coexistence and correct pressure

    E-Print Network [OSTI]

    Jeanmairet, Guillaume; Sergiievskyi, Volodymyr; Borgis, Daniel

    2015-01-01T23:59:59.000Z

    The solvation of hydrophobic solutes in water is special because liquid and gas are almost at coexistence. In the common hypernetted chain approximation to integral equations, or equivalently in the homogenous reference fluid of molecular density functional theory, coexistence is not taken into account. Hydration structures and energies of nanometer-scale hydrophobic solutes are thus incorrect. In this article, we propose a bridge functional that corrects this thermodynamic inconsistency by introducing a metastable gas phase for the homogeneous solvent. We show how this can be done by a third order expansion of the functional around the bulk liquid density that imposes the right pressure and the correct second order derivatives. Although this theory is not limited to water, we apply it to study hydrophobic solvation in water at room temperature and pressure and compare the results to all-atom simulations. With this correction, molecular density functional theory gives, at a modest computational cost, quantita...

  3. Effect of calcium nitrate on the vapor-liquid equilibria of ethanol + water and 2-propanol + water

    SciTech Connect (OSTI)

    Polka, H.M.; Gmehling, J. (Univ. of Oldenburg (Germany). Chair of Industrial Chemistry)

    1994-07-01T23:59:59.000Z

    The effect of calcium nitrate on the vapor-liquid equilibria of ethanol + water and 2-propanol + water was studied using a Swietoslawski ebulliometer. The measurements were performed for two constant salt molalities (1 and 2 mol[center dot]kg[sup [minus]1]) under isobaric conditions at 50.66 kPa. Strong salting-out of the alcohol was observed in all cases, leading to a complete elimination of the azeotropic point at relatively low salt concentrations. The results were correlated using an extension of the NRTL equation for mixed solvent electrolyte systems proposed by Mock, Evans, and Chen.

  4. Linking Europa's plume activity to tides, tectonics, and liquid water

    E-Print Network [OSTI]

    Rhoden, Alyssa R; Roth, Lorenz; Retherford, Kurt

    2015-01-01T23:59:59.000Z

    Much of the geologic activity preserved on Europa's icy surface has been attributed to tidal deformation, mainly due to Europa's eccentric orbit. Although the surface is geologically young (30 - 80 Myr), there is little information as to whether tidally-driven surface processes are ongoing. However, a recent detection of water vapor near Europa's south pole suggests that it may be geologically active. Initial observations indicated that Europa's plume eruptions are time-variable and may be linked to its tidal cycle. Saturn's moon, Enceladus, which shares many similar traits with Europa, displays tidally-modulated plume eruptions, which bolstered this interpretation. However, additional observations of Europa at the same time in its orbit failed to yield a plume detection, casting doubt on the tidal control hypothesis. The purpose of this study is to analyze the timing of plume eruptions within the context of Europa's tidal cycle to determine whether such a link exists and examine the inferred similarities and...

  5. A model of vapor-liquid equilibria for acid gas-alkanolamine-water systems

    SciTech Connect (OSTI)

    Austgen, D.M. Jr.

    1989-01-01T23:59:59.000Z

    A physico-chemical model was developed for representing liquid phase chemical equilibria and vapor-liquid (phase) equilibria of H{sub 2}SCO{sub 2}-alkanolamine-water systems. The equilibrium composition of the liquid phase is determined by minimization of the Gibbs free energy. Activity coefficients are represented with the Electrolyte-NRTL equation treating both long-range electrostatic interactions and short-range binary interactions between liquid phase species. Vapor phase fugacity coefficients are calculated using the Redlich-Kwong-Soave Equation of State. Adjustable parameters of the model, binary interaction parameters and carbamate stability constants, were fitted on published binary system alkanolamine-water and ternary system (H{sub 2}S-alkanolamine-water, CO{sub 2}-alkanolamine-water) VLE data. The Data Regression System of ASPEN PLUS, based upon the Maximum Likelihood Principle, was used to estimate adjustable parameters. Ternary system measurements used in parameter estimation ranged in temperature from 25 to 120{degree}C in alkanolamine concentration from 1 to 5 M, in acid gas loading from 0 to 1.5 moles per mole alkanolamine, and in acid gas partial pressure from 0.1 to 1,000 kPa. Maximum likelihood estimates of ternary system H{sub 2} or CO{sub 2} equilibrium partial pressures and liquid phase concentrations were found to be in good agreement with measurements for aqueous solutions of monoethanolamine (MEA), diethanolamine (DEA), diglycolamine (DGA), and methyldiethanolamine (MDEA) indicating that the model successfully represents ternary system data. The model was extended to represent CO{sub 2} solubility in aqueous mixtures of MDEA with MEA or DEA. The solubility was measured at 40 and 80{degree}C over a wide range of CO{sub 2} partial pressures. These measurements were used to estimate additional binary parameters of the mixed solvent systems.

  6. Radiometric Determination of Uranium in Natural Waters after Enrichment and Separation by Cation-Exchange and Liquid-Liquid Extraction

    E-Print Network [OSTI]

    I. Pashalidis; H. Tsertos

    2003-04-28T23:59:59.000Z

    The alpha-radiometric determination of uranium after its pre-concentration from natural water samples using the cation-exchange resin Chelex-100, its selective extraction by tributylphosphate and electrodeposition on stainless steel discs is reported. The validity of the separation procedure and the chemical recoveries were checked by addition of uranium standard solution as well as by tracing with U-232. The average uranium yield was determined to be (97 +- 2) % for the cation-exchange, (95 +- 2) % for the liquid-liquid extraction, and more than 99% for the electrodeposition. Employing high-resolution alpha-spectroscopy, the measured activity of the U-238 and U-234 radioisotopes was found to be of similar magnitude; i.e. ~7 mBq/L and ~35 mBq/L for ground- and seawater samples, respectively. The energy resolution (FWHM) of the alpha-peaks was 22 keV, while the Minimum Detectable Activity (MDA) was estimated to be 1 mBq/L (at the 95% confidence limit).

  7. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your Home as Ready for Summer as You Are? Is Your Home

  8. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your Home as Ready for Summer as You Are? Is Your HomeIsotope and

  9. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your Home as Ready for Summer as You Are? Is Your HomeIsotope

  10. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is Your Home as Ready for Summer as You Are? Is Your

  11. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer ReviewIron isIsIsotope

  12. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer ReviewIron isIsIsotopeIsotope and

  13. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer ReviewIron isIsIsotopeIsotope andIsotope

  14. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer ReviewIron isIsIsotopeIsotope

  15. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer ReviewIron isIsIsotopeIsotopeIsotope and

  16. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer ReviewIron isIsIsotopeIsotopeIsotope

  17. Ab-initio molecular dynamics simulation of liquid water by Quantum Monte Carlo

    E-Print Network [OSTI]

    Andrea Zen; Ye Luo; Guglielmo Mazzola; Leonardo Guidoni; Sandro Sorella

    2015-04-21T23:59:59.000Z

    Although liquid water is ubiquitous in chemical reactions at roots of life and climate on the earth, the prediction of its properties by high-level ab initio molecular dynamics simulations still represents a formidable task for quantum chemistry. In this article we present a room temperature simulation of liquid water based on the potential energy surface obtained by a many-body wave function through quantum Monte Carlo (QMC) methods. The simulated properties are in good agreement with recent neutron scattering and X-ray experiments, particularly concerning the position of the oxygen-oxygen peak in the radial distribution function, at variance of previous Density Functional Theory attempts. Given the excellent performances of QMC on large scale supercomputers, this work opens new perspectives for predictive and reliable ab-initio simulations of complex chemical systems.

  18. Ab-initio molecular dynamics simulation of liquid water by Quantum Monte Carlo

    E-Print Network [OSTI]

    Andrea Zen; Ye Luo; Guglielmo Mazzola; Leonardo Guidoni; Sandro Sorella

    2014-12-09T23:59:59.000Z

    Despite liquid water is ubiquitous in chemical reactions at roots of life and climate on earth, the prediction of its properties by high-level ab initio molecular dynamics simulations still represents a formidable task for quantum chemistry. In this article we present a room temperature simulation of liquid water based on the potential energy surface obtained by a many-body wave function through quantum Monte Carlo (QMC) methods. The simulated properties are in excellent agreement with recent neutron scattering and X-ray experiments, particularly concerning the position of the oxygen-oxygen peak in the radial distribution function, at variance of previous Density Functional Theory attempts. Given the excellent performances of QMC on large scale supercomputers, this work opens new perspectives for predictive and reliable ab-initio simulations of complex chemical systems.

  19. A focused liquid jet formed by a water hammer in a test tube

    E-Print Network [OSTI]

    Kiyama, Akihito; Ando, Keita; Kameda, Masaharu

    2015-01-01T23:59:59.000Z

    We investigate motion of a gas-liquid interface in a test tube induced by a large acceleration via impulsive force. We conduct simple experiments in which the tube partially filled with a liquid falls under gravity and impacts a rigid floor. A curved gas-liquid interface inside the tube reverses and eventually forms an elongated jet (i.e. the so-called a focused jet). In our experiments, there arises either vibration of the interface or increment in the velocity of a liquid jet accompanied by the onset of cavitation in the liquid column. These phenomena cannot be explained by considering pressure impulse in a classical potential flow analysis, which does not account for finite speeds of sound as well as phase change. Here we model such water-hammer events as a result of one-dimensional pressure wave propagation and its interaction with boundaries through acoustic impedance mismatching. The method of characteristics is applied to describe pressure wave interactions and the subsequent cavitation. The proposed m...

  20. Physica A 257 (1998) 213232 The puzzling statistical physics of liquid water

    E-Print Network [OSTI]

    Stanley, H. Eugene

    1998-01-01T23:59:59.000Z

    Physica A 257 (1998) 213232 The puzzling statistical physics of liquid water H.E. Stanley a; , S.V. Buldyrev a , M. Canpolat a; 1 , M. Meyer a , O. Mishima b , M.R. Sadr-Lahijany a , A. Scala a , F.W. Starr-4371(98)00264-7 #12;214 H.E. Stanley et al. / Physica A 257 (1998) 213232 At a pressure of 1 atm, the maximum density

  1. Analysis and Calibration of CRF Raman Lidar Cloud Liquid Water Measurements

    SciTech Connect (OSTI)

    Turner, D.D.

    2007-10-31T23:59:59.000Z

    The Atmospheric Radiation Measurement (ARM) Raman lidar (RL), located at the Southern Great Plains (SGP) Climate Research Facility (CRF), is a unique state-of-the-art active remote sensor that is able to measure profiles of water vapor, aerosol, and cloud properties at high temporal and vertical resolution throughout the diurnal cycle. In October 2005, the capability of the RL was extended by the addition of a new detection channel that is sensitive to the Raman scattering of liquid water. This new channel permits the system, in theory, to measure profiles of liquid water content (LWC) by the RL. To our knowledge, the ARM RL is the only operation lidar with this capability. The liquid water Raman backscattering cross-section is a relatively weak and spectrally broad feature, relative to the water vapor Raman backscatter signal. The wide bandpass required to achieve reasonable signal-to-noise in the liquid water channel essentially eliminates the ability to measure LWC profiles during the daytime in the presence of large solar background, and thus all LWC observations are nighttime only. Additionally, the wide bandpass increases the probability that other undesirable signals, such as fluorescence from aerosols, may contaminate the observation. The liquid water Raman cross-section has a small amount of overlap with the water vapor Raman cross-section, and thus there will be a small amount of cross-talk between the two signals, with water vapor contributing a small amount of signal to the LWC observation. And finally, there is significant uncertainty in the actual strength of the liquid water Raman cross-section in the literature. The calibrated LWC profiles, together with the coincident cloud backscatter observations also made by the RL, can be used to derive profiles of cloud droplet effective radius. By combining these profiles of effective radius in the lower portion of the cloud with the aerosol extinction measurements made below the cloud by the RL, the first aerosol indirect effect can be investigated using a single instrument, thereby reducing the uncertainty associated with aligning the different sampling periods and fields of view of multiple instruments. We have applied a first principles calibration to the LWC profiles. This approach requires that the relative differences in optical efficiency between the water vapor and liquid water channels be known; this relative difference is easily computed using the efficiency values of the beam splitters and interference filters in the lidar that were provided by the vendors of these components. The first principles approach then transfers the calibration from the water vapor mixing ratio to the LWC using the difference in the optical efficiency and an interpolated value of the liquid water Raman cross section from the literature, and the better established water vapor Raman cross section. After accounting for all known error sources, the vertical integral of LWC was compared against a similar value retrieved from a co-located ground-based infrared radiometer. The RL and infrared radiometer have significantly different fields of view; thus to compare the two sensors the data were averaged to 5 min intervals where only cloudy samples were included in the average of each. While there is fair scatter in the data (r=0.47), there is also a clear indication of a positive correlation between the infrared and the RL values. The value of the slope of the regression is 0.49, which indicates a tendency of the RL measurements to underestimate the total liquid amount with respect to the infrared retrieval. Research continues to investigate the source of the bias, but the most likely candidate is the large uncertainty in the liquid water Raman cross-section as there have been no direct measurements made of this parameter at the lidars laser wavelength of 355 nm. The calibrated LWC profile was then used together with the cloud backscatter coefficient profile from the RL to derive profiles of cloud droplet effective radius and cloud droplet number density. These profiles o

  2. Electronic structure effects in liquid water studied by photoelectron spectroscopy and density functional theory

    SciTech Connect (OSTI)

    Nordlund, Dennis; Odelius, Michael; Bluhm, Hendrik; Ogasawara, Hirohito; Pettersson, Lars G.M.; Nilsson, Anders

    2008-04-29T23:59:59.000Z

    We present valence photoelectron emission spectra of liquid water in comparison with gas-phase water, ice close to the melting point, low temperature amorphous and crystalline ice. All aggregation states have major electronic structure changes relative to the free molecule, with rehybridization and development of bonding and anti-bonding states accompanying the hydrogen bond formation. Sensitivity to the local structural order, most prominent in the shape and splitting of the occupied 3a{sub 1} orbital, is understood from the electronic structure averaging over various geometrical structures, and reflects the local nature of the orbital interaction.

  3. Liquid polymorphism, order-disorder transitions and anomalous a Monte Carlo study of the Bell-Lavis model for water

    E-Print Network [OSTI]

    Barbosa, Marcia C. B.

    the lack of consensus concerning the origin of water-like anomalies, it is widely believed of the Bell-Lavis model for water Carlos E. Fiore Departamento de Fisica, Universidade Federal do Paran for liquid water is investigated through numerical simulations. The lattice- gas model on a triangular

  4. Investigating the solid-liquid phase transition of water nanofilms using the generalized replica exchange method

    SciTech Connect (OSTI)

    Lu, Qing [Division of Materials Science and Engineering, Boston University, Brookline, Massachusetts 02446 (United States); Kim, Jaegil; Straub, John E., E-mail: straub@bu.edu [Department of Chemistry, Boston University, Boston, Massachusetts 02215 (United States); Farrell, James D.; Wales, David J. [University Chemical Laboratories, Lensfield Road, Cambridge CB2 1EW (United Kingdom)

    2014-11-14T23:59:59.000Z

    The generalized Replica Exchange Method (gREM) was applied to study a solid-liquid phase transition in a nanoconfined bilayer water system using the monatomic water (mW) model. Exploiting optimally designed non-Boltzmann sampling weights with replica exchanges, gREM enables an effective sampling of configurations that are metastable or unstable in the canonical ensemble via successive unimodal energy distributions across phase transition regions, often characterized by S-loop or backbending in the statistical temperature. Extensive gREM simulations combined with Statistical Temperature Weighted Histogram Analysis Method (ST-WHAM) for nanoconfined mW water at various densities provide a comprehensive characterization of diverse thermodynamic and structural properties intrinsic to phase transitions. Graph representation of minimized structures of bilayer water systems determined by the basin-hopping global optimization revealed heterogeneous ice structures composed of pentagons, hexagons, and heptagons, consistent with an increasingly ordered solid phase with decreasing density. Apparent crossover from a first-order solid-liquid transition to a continuous one in nanoconfined mW water with increasing density of the system was observed in terms of a diminishing S-loop in the statistical temperature, smooth variation of internal energies and heat capacities, and a characteristic variation of lateral radial distribution functions, and transverse density profiles across transition regions.

  5. Crystalline, liquid crystalline, and isotropic phases of sodium deoxycholate in water

    SciTech Connect (OSTI)

    Su, Ziyang; Luthra, Suman; Krzyzaniak, Joseph F.; Agra-Kooijman, Dena M.; Kumar, Satyendra; Byrn, Stephen R.; Shalaev, Evgenyi Y. (Pfizer); (Purdue); (Kent)

    2012-09-06T23:59:59.000Z

    Sodium deoxycholate (NaDC) is an important example of bile salts, representing systems with complex phase behavior involving both crystalline and mesophase structures. In this study, properties of NaDC-water mixtures were evaluated as a function of composition and temperature via X-ray diffraction with synchrotron (sXRD) and laboratory radiation sources, water sorption, polarized light, hot-stage microscopy, and freezing-point osmometry. Several phases were detected depending on the composition and temperature, including isotropic solution phase, liquid crystalline (LC) phase, crystalline hydrate, and ice. The LC phase was identified as hexagonal structure by sXRD, with up to 14 high-order reflections detected. The crystalline phase was found to be nonstoichiometric hydrate, based on XRD and water sorption data. The phase diagram of NaDC-water system has been refined based on both results of this study and other reports in literature.

  6. Estimating Entropy of Liquids from Atom-Atom Radial Distribution Functions: Silica, Beryllium Fluoride and Water

    E-Print Network [OSTI]

    Ruchi Sharma; Manish Agarwal; Charusita Chakravarty

    2008-09-24T23:59:59.000Z

    Molecular dynamics simulations of water, liquid beryllium fluoride and silica melt are used to study the accuracy with which the entropy of ionic and molecular liquids can be estimated from atom-atom radial distribution function data. All three systems are known to display similar liquid-state thermodynamic and kinetic anomalies due to a region of anomalous excess entropy behaviour where entropy rises on isothermal compression. The pair correlation entropy is demonstrated to be sufficiently accurate that the density-temperature regime of anomalous behaviour as well as the strength of the entropy anomaly can be predicted reliably for both ionic melts as well as different rigid-body pair potentials for water. Errors in the total thermodynamic entropy for ionic melts due to the pair correlation approximation are of the order of 10% or less for most state points but can be significantly larger in the anomalous regime at very low temperatures. In the case of water, as expected given the rigid-body constraints for a molecular liquids, the pair correlation approximation causes significantly larger errors, between 20 and 30%, for most state points. Comparison of the excess entropy, Se, of ionic melts with the pair correlation entropy, S2, shows that the temperature dependence of Se is well described by T ??2=5 scaling across both the normal and anomalous regimes, unlike in the case of S2. As a function of density, the Se(rho) curves shows only a single maximum while the S2(rho) curves show both a maximum and a minimum. These differences in the behaviour of S2 and Se are due to the fact that the residual multiparticle entropy, delta(S) = Se - S2, shows a strong negative correlation with tetrahedral order in the anomalous regime.

  7. Simultaneous probing of bulk liquid phase and catalytic gas-liquid-solid interface under working conditions using attenuated total reflection infrared spectroscopy

    SciTech Connect (OSTI)

    Meemken, Fabian; Mller, Philipp; Hungerbhler, Konrad; Baiker, Alfons, E-mail: baiker@chem.ethz.ch [Department of Chemistry and Applied Biosciences, Institute for Chemical and Bioengineering, ETH Zrich, Hnggerberg, HCI, CH-8093 Zrich (Switzerland)

    2014-08-15T23:59:59.000Z

    Design and performance of a reactor set-up for attenuated total reflection infrared (ATR-IR) spectroscopy suitable for simultaneous reaction monitoring of bulk liquid and catalytic solid-liquid-gas interfaces under working conditions are presented. As advancement of in situ spectroscopy an operando methodology for gas-liquid-solid reaction monitoring was developed that simultaneously combines catalytic activity and molecular level detection at the catalytically active site of the same sample. Semi-batch reactor conditions are achieved with the analytical set-up by implementing the ATR-IR flow-through cell in a recycle reactor system and integrating a specifically designed gas feeding system coupled with a bubble trap. By the use of only one spectrometer the design of the new ATR-IR reactor cell allows for simultaneous detection of the bulk liquid and the catalytic interface during the working reaction. Holding two internal reflection elements (IRE) the sample compartments of the horizontally movable cell are consecutively flushed with reaction solution and pneumatically actuated, rapid switching of the cell (<1 s) enables to quasi simultaneously follow the heterogeneously catalysed reaction at the catalytic interface on a catalyst-coated IRE and in the bulk liquid on a blank IRE. For a complex heterogeneous reaction, the asymmetric hydrogenation of 2,2,2-trifluoroacetophenone on chirally modified Pt catalyst the elucidation of catalytic activity/enantioselectivity coupled with simultaneous monitoring of the catalytic solid-liquid-gas interface is shown. Both catalytic activity and enantioselectivity are strongly dependent on the experimental conditions. The opportunity to gain improved understanding by coupling measurements of catalytic performance and spectroscopic detection is presented. In addition, the applicability of modulation excitation spectroscopy and phase-sensitive detection are demonstrated.

  8. The Structure of Water in Crystalline Aluminophosphates: Isolated Water and Intermolecular Clusters Probed by Raman Spectroscopy, NMR and Structural Modeling

    E-Print Network [OSTI]

    Goddard III, William A.

    The Structure of Water in Crystalline Aluminophosphates: Isolated Water and Intermolecular Clusters are used to elucidate the properties of water in Metavariscite, AlPO4-H3, AlPO4-8 and VPI-5. The framework density of the aluminophosphates decreases along this sequence, the pore size increases, and the water

  9. Method and apparatus for electrokinetic co-generation of hydrogen and electric power from liquid water microjets

    DOE Patents [OSTI]

    Saykally, Richard J; Duffin, Andrew M; Wilson, Kevin R; Rude, Bruce S

    2013-02-12T23:59:59.000Z

    A method and apparatus for producing both a gas and electrical power from a flowing liquid, the method comprising: a) providing a source liquid containing ions that when neutralized form a gas; b) providing a velocity to the source liquid relative to a solid material to form a charged liquid microjet, which subsequently breaks up into a droplet spay, the solid material forming a liquid-solid interface; and c) supplying electrons to the charged liquid by contacting a spray stream of the charged liquid with an electron source. In one embodiment, where the liquid is water, hydrogen gas is formed and a streaming current is generated. The apparatus comprises a source of pressurized liquid, a microjet nozzle, a conduit for delivering said liquid to said microjet nozzle, and a conductive metal target sufficiently spaced from said nozzle such that the jet stream produced by said microjet is discontinuous at said target. In one arrangement, with the metal nozzle and target electrically connected to ground, both hydrogen gas and a streaming current are generated at the target as it is impinged by the streaming, liquid spray microjet.

  10. New Technique for Retrieving Liquid Water Path over Land using Satellite Microwave Observations

    SciTech Connect (OSTI)

    Deeter, M.N.; Vivekanandan, J.

    2005-03-18T23:59:59.000Z

    We present a new methodology for retrieving liquid water path over land using satellite microwave observations. As input, the technique exploits the Advanced Microwave Scanning Radiometer for earth observing plan (EOS) (AMSR-E) polarization-difference signals at 37 and 89 GHz. Regression analysis performed on model simulations indicates that over variable atmospheric and surface conditions the polarization-difference signals can be simply parameterized in terms of the surface emissivity polarization difference ({Delta}{var_epsilon}), surface temperature, liquid water path (LWP), and precipitable water vapor (PWV). The resulting polarization-difference parameterization (PDP) enables fast and direct (noniterative) retrievals of LWP with minimal requirements for ancillary data. Single- and dual-channel retrieval methods are described and demonstrated. Data gridding is used to reduce the effects of instrumental noise. The methodology is demonstrated using AMSR-E observations over the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site during a six day period in November and December, 2003. Single- and dual-channel retrieval results mostly agree with ground-based microwave retrievals of LWP to within approximately 0.04 mm.

  11. Nanoparticle enhanced evaporation of liquids: A case study of silicone oil and water

    E-Print Network [OSTI]

    Wenbin Zhang; Rong Shen; Kunquan Lu; Ailing Ji; Zexian Cao

    2012-10-23T23:59:59.000Z

    Evaporation is a fundamental physical phenomenon, of which many challenging questions remain unanswered. Enhanced evaporation of liquids in some occasions is of enormous practical significance. Here we report the enhanced evaporation of the nearly permanently stable silicone oil by dispersing with nanopariticles including CaTiO3, anatase and rutile TiO2. The results can inspire the research of atomistic mechanism for nanoparticle enhanced evaporation and exploration of evaporation control techniques for treatment of oil pollution and restoration of dirty water.

  12. Journal of Power Sources 164 (2007) 189195 Modeling water transport in liquid feed direct methanol fuel cells

    E-Print Network [OSTI]

    2007-01-01T23:59:59.000Z

    Journal of Power Sources 164 (2007) 189195 Modeling water transport in liquid feed direct methanol management in direct methanol fuel cells (DMFCs) is very critical and complicated because of many interacting rights reserved. Keywords: Direct methanol fuel cell; Water transport; Mathematical modeling; Three

  13. Isobaric vapor-liquid equilibria of the water + 1-propanol system at 30, 60, and 100 kPa

    SciTech Connect (OSTI)

    Gabaldon, C.; Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica] [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica

    1996-09-01T23:59:59.000Z

    Isobaric vapor-liquid equilibria for the water + 1-propanol system are reported at 30, 60, and 100 kPa. The results were found to be thermodynamically consistent according to Van Ness-Byer-Gibbs, Kojima, and Wisniak methods. The system shows a minimum boiling azeotrope, and the azeotropic composition is scarcely shifted with pressure. Results were compared with literature values. The data were correlated with Margules, Van Laar, Wilson, NRTL, and UNIQUAC liquid-phase activity coefficient models.

  14. Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR

    E-Print Network [OSTI]

    Nicodemus, Rebecca A.

    We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

  15. Probing water properties and cationic exchange in calcium-silicate-hydrate : an atomistic modeling study

    E-Print Network [OSTI]

    Youssef, Mostafa Youssef Mahmoud

    2010-01-01T23:59:59.000Z

    Two problems related to the assessment of the performance of cementitious materials in the nuclear fuel cycle are investigated by means of atomistic simulations. The first is the structural and dynamic nature of water ...

  16. NEW VIEW of the young earth covered in oceans of liquid water as early as 4.4 billion years ago

    E-Print Network [OSTI]

    Carlson, Anders

    sun. Averaging 75 times the speed of sound, each impactor scorched the surface--shattering, meltingNEW VIEW of the young earth covered in oceans of liquid water as early as 4.4 billion years ago into a crust, before continents could form, be- fore the dense, steamy atmosphere could pool as liquid water

  17. Visualization of Liquid Water Transport in a PEFC X. G. Yang,* F. Y. Zhang, A. L. Lubawy, and C. Y. Wang*,z

    E-Print Network [OSTI]

    electrolyte fuel cell PEFC , the mechanics of liquid water transport, starting from droplet emergence and methanol PEFCs. Neutron beams can penetrate through a metal fuel cell to image the real-time liquid water to achieve high performance and lon- gevity of polymer electrolyte fuel cells PEFCs . At high current density

  18. Isothermal vapor-liquid equilibria for water + 2-aminoethanol + dimethyl sulfoxide and its constituent three binary systems

    SciTech Connect (OSTI)

    Tochigi, Katsumi; Akimoto, Kentarou; Ochi, Kenji [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry] [Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry; Liu, Fangyhi; Kawase, Yasuhito [Nippon Refine Co., Ltd., Tokyo (Japan)] [Nippon Refine Co., Ltd., Tokyo (Japan)

    1999-05-01T23:59:59.000Z

    Isothermal vapor-liquid equilibria were measured for the ternary system water + 2-aminoethanol + dimethyl sulfoxide and its three constituent binary mixtures at 363.15 K. The apparatus used was a modified Rogalski-Malanoski equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system was predicted using the binary NRTL parameters with good accuracy.

  19. Quantification of Liquid Water Saturation in a PEM Fuel Cell Diffusion Medium Using X-ray Microtomography

    E-Print Network [OSTI]

    , at shutdown, may freeze under subzero tem- peratures and makes cold start of a PEM fuel cell difficult conditions. MRI is used to visualize the transport of liquid water across a polymer electrolyte membrane opportunities for imaging pore-scale flow and multiphase transport in porous me- dia. In recent years, X

  20. Sudden structural change at ati air/binary liquid interface: Sum frequency study of the air/acetonitrile-water interface

    E-Print Network [OSTI]

    Eisenthal, Kenneth B.

    Sudden structural change at ati air/binary liquid interface: Sum frequency study of the air/acetonitrile change in an air/acetonitrile-water interface as the solution composition varies; the abruptness of which and in the polarization of the signal from the acetonitrile molecules in the interface observed using infrared + visible

  1. Liquid chromatographic method for determination of water in soils and the optimization of anion separations by capillary zone electrophoresis

    SciTech Connect (OSTI)

    Benz, N.

    1994-10-01T23:59:59.000Z

    A liquid chromatographic method for the determination of water in soil or clay samples is presented. In a separate study, the optimization of electrophoretic separation of alkylated phenolate ions was optimized by varying the pH and acetonitrile concentration of the buffer solutions.

  2. Near-Global Survey of Effective Droplet Radii in Liquid Water Clouds Using ISCCP Data 1 . Introduction

    E-Print Network [OSTI]

    Han, Quingyuan

    VOLUME 7 Near-Global Survey of Effective Droplet Radii in Liquid Water Clouds Using ISCCP Data 1 indicate the magnitude ofaerosol effects on clouds. A method, based on a complete radiative transfer model the radiative effects ofwater vapor and clouds and the hydrological cycle, and create several important cloud

  3. Charge transfer effects of ions at the liquid water/vapor interface

    SciTech Connect (OSTI)

    Soniat, Marielle; Rick, Steven W., E-mail: srick@uno.edu [Department of Chemistry, University of New Orleans, New Orleans, Louisiana 70148 (United States)

    2014-05-14T23:59:59.000Z

    Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 away from the surface.

  4. Mesoscopic structuring and dynamics of alcohol/water solutions probed by Terahertz Time-Domain Spectroscopy and Pulsed Field Gradient Nuclear Magnetic Resonance

    E-Print Network [OSTI]

    Li, Ruoyu; D'Agostino, Carmine; McGregor, James; Mantle, Michael D.; Zeitler, J. Axel; Gladden, Lynn F.

    2014-08-12T23:59:59.000Z

    , and engineering applications; examples include protein folding, membrane self-assembly, electron transfer reactions, heterogeneous catalysis, and fuel cell technology.1?4 Despite this, however, the influence of the solute molecules upon the structure of water... -Domain Spectroscopy. The THz-TDS transmission setup used in this study has been described previously.32 The liquid samples were contained within a liquid cell (PIKE Technologies, Madison U.S.A.) contained between 3 mm thick z-cut quartz windows, which are transparent...

  5. The Individual and Collective Effects of Exact Exchange and Dispersion Interactions on the Ab Initio Structure of Liquid Water

    E-Print Network [OSTI]

    Robert A. DiStasio Jr.; Biswajit Santra; Zhaofeng Li; Xifan Wu; Roberto Car

    2014-05-20T23:59:59.000Z

    In this work, we report the results of a series of density functional theory (DFT) based ab initio molecular dynamics (AIMD) simulations of ambient liquid water using a hierarchy of exchange-correlation (XC) functionals to investigate the individual and collective effects of exact exchange (Exx), via the PBE0 hybrid functional, non-local vdW/dispersion interactions, via a fully self-consistent density-dependent dispersion correction, and approximate nuclear quantum effects (aNQE), via a 30 K increase in the simulation temperature, on the microscopic structure of liquid water. Based on these AIMD simulations, we found that the collective inclusion of Exx, vdW, and aNQE as resulting from a large-scale AIMD simulation of (H$_2$O)$_{128}$ at the PBE0+vdW level of theory, significantly softens the structure of ambient liquid water and yields an oxygen-oxygen structure factor, $S_{\\rm OO}(Q)$, and corresponding oxygen-oxygen radial distribution function, $g_{\\rm OO}(r)$, that are now in quantitative agreement with the best available experimental data. This level of agreement between simulation and experiment as demonstrated herein originates from an increase in the relative population of water molecules in the interstitial region between the first and second coordination shells, a collective reorganization in the liquid phase which is facilitated by a weakening of the hydrogen bond strength by the use of the PBE0 hybrid XC functional, coupled with a relative stabilization of the resultant disordered liquid water configurations by the inclusion of non-local vdW/dispersion interactions.

  6. Probing the thermal character of analogue Hawking radiation for shallow water waves?

    E-Print Network [OSTI]

    Florent Michel; Renaud Parentani

    2014-09-15T23:59:59.000Z

    We study and numerically compute the scattering coefficients of shallow water waves blocked by a stationary counterflow. When the flow is transcritical, the coefficients closely follow Hawking's prediction according to which black holes should emit a thermal spectrum. We study how the spectrum deviates from thermality when reducing the maximal flow velocity, with a particular attention to subcritical flows since these have been recently used to test Hawking's prediction. For such flows, we show that the emission spectrum is strongly suppressed, and that its Planckian character is completely lost. For low frequencies, we also show that the scattering coefficients are dominated by elastic hydrodynamical channels. Our numerical results reproduce rather well the observations made by S. Weinfurtner {\\it et al.} in the Vancouver experiment. Nevertheless, we propose a new interpretation of what has been observed, as well as new experimental tests.

  7. Isobaric vapor-liquid equilibria of the water + 2-propanol system at 30, 60, and 100 kPa

    SciTech Connect (OSTI)

    Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Departamento de Ingenieria Quimica] [Univ. de Valencia (Spain). Departamento de Ingenieria Quimica

    1996-05-01T23:59:59.000Z

    Distillation is perhaps the separation process most widely used in the chemical processing industry. The correct design of distillation columns requires the availability of accurate and, if possible, thermodynamically consistent vapor-liquid equilibria (VLE) data. The present work is part of a project studying the effect of pressure on the behavior of the azeotropic point in mixtures in which at least one component is an alcohol. Isobaric vapor-liquid equilibria were obtained for the water + 2-propanol system at 30, 60, and 100 kPa. The activity coefficients were found to be thermodynamically consistent by the methods of Van Ness-Byer-Gibbs, Kojima, and Wisniak. The data were correlated with five liquid phase activity coefficient models (Margules, Van Laar, Wilson, NRTL, and UNIQUAC).

  8. MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2)

    SciTech Connect (OSTI)

    Gaustad, KL; Turner, DD; McFarlane, SA

    2011-07-25T23:59:59.000Z

    This report provides a short description of the Atmospheric Radiation Measurement (ARM) Climate Research Facility microwave radiometer (MWR) Retrieval (MWRRET) value-added product (VAP) algorithm. This algorithm utilizes a complementary physical retrieval method and applies brightness temperature offsets to reduce spurious liquid water path (LWP) bias in clear skies resulting in significantly improved precipitable water vapor (PWV) and LWP retrievals. We present a general overview of the technique, input parameters, output products, and describe data quality checks. A more complete discussion of the theory and results is given in Turner et al. (2007b).

  9. Boson Peak in Deeply Cooled Confined Water: A Possible Way to Explore the Existence of the Liquid-to-Liquid Transition in Water

    E-Print Network [OSTI]

    Wang, Zhe

    The boson peak in deeply cooled water confined in nanopores is studied with inelastic neutron scattering. We show that in the (P, T) plane, the locus of the emergence of the boson peak is nearly parallel to the Widom line ...

  10. Pore-scale simulation of liquid CO2 displacement of water using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    this model is first validated by two benchmark tests: a layered two-phase flow with a viscosity ratio, and a dynamic capillary intrusion. This model is then used to simulate liquid...

  11. Calculation of releases of radioactive materials in gaseous and liquid effluents from pressurized water reactors (PWR-GALE Code). Revision 1

    SciTech Connect (OSTI)

    Chandrasekaran, T.; Lee, J.Y.; Willis, C.A.

    1985-04-01T23:59:59.000Z

    This report revises the original issuance of NUREG-0017, ''Calculation of Releases of Radioactive Materials in Gaseous and Liquid Effluents from Pressurized Water Reactors (PWR-GALE-Code)'' (April 1976), to incorporate more recent operating data now available as well as the results of a number of in-plant measurement programs at operating pressurized water reactors. The PWR-GALE Code is a computerized mathematical model for calculating the releases of radioactive material in gaseous and liquid effluents (i.e., the gaseous and liquid source terms). The US Nuclear Regulatory Commission uses the PWR-GALE Code to determine conformance with the requirements of Appendix I to 10 CFR Part 50.

  12. Liquid chromatographic analysis of coal surface properties

    SciTech Connect (OSTI)

    Kwon, K.C.

    1991-01-01T23:59:59.000Z

    The main objectives of this proposed research are to refine further the inverse liquid chromatography technique for the study of surface properties of raw coals, treated coals and coal minerals in water, to evaluate relatively surface properties of raw coals, treated coals and coal minerals by inverse liquid chromatography, and to evaluate floatability of various treated coals in conjunction with surface properties of coals. Alcohols such as methanol, ethanol, isopropanol, isobutanol, tert-butanol, heptanol, 1-hexadecanol, 2-methyl-pentanol, 4-methyl-2-penthanol (methylisobutyl carbinol), n-octanol, s-octanol, and cyclohexanol as probe compounds are utilized to evaluate hydrophilicity of coals and coal minerals. N-alkanes such as hexane, heptane and octane, and stearic acid are employed as probe compounds to evaluate hydrophobicity of coals and coal minerals. Aromatic compounds such as benzene and toluene as probe compounds are used to examine aromaticity of coal surface. Aromatic acids such as o-cresol, m-cresol, p-cresol, phenol and B-naphthol are used to detect aromatic acidic sites of coal surface. Hydrophilicity, hydrophobicity and aromaticity of surfaces for either raw coals or treated coals in water are relatively determined by evaluating both equilibrium physical/chemical adsorption and dynamic adsorption of probe compounds on various raw coals and treated coals to compare affinities of coals for water.

  13. Apparatus and method for pumping hot, erosive slurry of coal solids in coal derived, water immiscible liquid

    DOE Patents [OSTI]

    Ackerman, Carl D. (Olympia, WA)

    1983-03-29T23:59:59.000Z

    An apparatus for and method of pumping hot, erosive slurry of coal solids in a coal derived, water immiscible liquid to higher pressure involves the use of a motive fluid which is miscible with the liquid of the slurry. The apparatus includes a pump 12, a remote check valve 14 and a chamber 16 between and in fluid communication with the pump 12 and check valve 14 through conduits 18,20. Pump 12 exerts pressure on the motive fluid and thereby on the slurry through a concentration gradient of coal solids within chamber 16 to alternately discharge slurry under pressure from the outlet port of check valve 14 and draw slurry in through the inlet port of check valve 14.

  14. Equation of state of water under negative pressure Kristina Davitt,a

    E-Print Network [OSTI]

    Caupin, Frédéric

    on the simultaneous measurements of the speed of sound and the density in liquid water under negative pressure the speed of sound during the passage of a 1 MHz ultrasonic wave. This is coupled with a fiber optic probe. Application of a focused acoustic wave to the bulk liquid is able to generate negative pressures before

  15. Excited state dynamics of liquid water: Insight from the dissociation reaction following two-photon excitation

    E-Print Network [OSTI]

    Elles, Christopher G.; Shkrob, Ilya A.; Crowell, Robert A.; Bradforth, Stephen E.

    2007-04-25T23:59:59.000Z

    V to ionization at 12.4eV. The two channels occur with similar yield for an excitation energy of 9.3eV. For the lowest excitation energy, the transient absorption at 267nm probes the geminate recombination kinetics of the H and OH fragments, providing a window...

  16. Liquid film thickness measurement by two-line TDLAS

    SciTech Connect (OSTI)

    Yang, Huinan [School of Energy and Power Engineering, University of Shanghai for Science and Technology, 200093, Shanghai, China and IVG, University of Duisburg-Essen, 47057, Duisburg (Germany); Chen, Jun; Cai, Xiaoshu [School of Energy and Power Engineering, University of Shanghai for Science and Technology, 200093, Shanghai (China); Greszik, Daniel; Dreier, Thomas; Schulz, Christof [IVG, University of Duisburg-Essen, 47057, Duisburg (Germany)

    2014-04-11T23:59:59.000Z

    A fiber-based two-line tunable diode-laser absorption sensor with two near-infrared (NIR) distributed-feedback (DFB) diode lasers at ?1.4 ?m was used for non-intrusive time-resolved liquid water film thickness measurement. When probing the liquid film at two different wavelengths with significantly different absorption cross-sections, the additional signal losses due to surface fowling, reflection and beam steering can be eliminated. In this work, the evaporation process of a liquid film on transparent quartz plate was tracked and large fluctuations of film thickness were found at the end of the evaporation.

  17. Stir bar sorptive extraction coupled to liquid chromatography-tandem mass spectrometry for the2 determination of pesticides in water samples: method validation and measurement uncertainty3

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    carry-over between consecutive extractions with the same stir21 bar. Pesticide quantification in water1 Title :1 Stir bar sorptive extraction coupled to liquid chromatography-tandem mass spectrometry for the2 determination of pesticides in water samples: method validation and measurement uncertainty3

  18. The Hydrated Proton at the Water Liquid/Vapor Interface Matt K. Petersen, Srinivasan S. Iyengar, Tyler J. F. Day, and Gregory A. Voth*,

    E-Print Network [OSTI]

    Iyengar, Srinivasan S.

    The Hydrated Proton at the Water Liquid/Vapor Interface Matt K. Petersen, Srinivasan S. Iyengar ReceiVed: July 23, 2004; In Final Form: August 22, 2004 The hydrated proton was studied at the water the migration of the excess proton to and about the interface through the fluctuating bond topology described

  19. A Fixed Point Charge Model for Water Optimized to the Vapor-Liquid Coexistence Properties

    E-Print Network [OSTI]

    the temperature range of the liquid. Results were compared to the SPC, SPC/E, and MSPC/E models, vapor pressures, critical parameters, and the second virial coefficient. It is inferior to the SPC interactions. Models of this type include the Bernal-Fowler1 , ST22 , TIPS23 , TIP4P4 , SPC5 , SPC/E6

  20. 7-88 A geothermal power plant uses geothermal liquid water at 160C at a specified rate as the heat source. The actual and maximum possible thermal efficiencies and the rate of heat rejected from this power plant

    E-Print Network [OSTI]

    Bahrami, Majid

    7-31 7-88 A geothermal power plant uses geothermal liquid water at 160C at a specified rate and potential energy changes are zero. 3 Steam properties are used for geothermal water. Properties Using saturated liquid properties, the source and the sink state enthalpies of geothermal water are (Table A-4) k

  1. Decontamination of Nuclear Liquid Wastes Status of CEA and AREVA R and D: Application to Fukushima Waste Waters - 12312

    SciTech Connect (OSTI)

    Fournel, B.; Barre, Y.; Lepeytre, C.; Peycelon, H. [CEA Marcoule, DTCD, BP17171, 30207 Bagnols sur Ceze (France); Grandjean, A. [Institut de Chimie Separative de Marcoule, UMR5257 CEA-CNRS-UM2-ENSCM, BP17171, 30207 Bagnols sur Ceze (France); Prevost, T.; Valery, J.F. [AREVA NC, Paris La Defense (France); Shilova, E.; Viel, P. [CEA Saclay, DSM/IRAMIS/SPCSI, 91191 Gif sur Yvette (France)

    2012-07-01T23:59:59.000Z

    Liquid wastes decontamination processes are mainly based on two techniques: Bulk processes and the so called Cartridges processes. The first technique has been developed for the French nuclear fuel reprocessing industry since the 60's in Marcoule and La Hague. It is a proven and mature technology which has been successfully and quickly implemented by AREVA at Fukushima site for the processing of contaminated waters. The second technique, involving cartridges processes, offers new opportunities for the use of innovative adsorbents. The AREVA process developed for Fukushima and some results obtained on site will be presented as well as laboratory scale results obtained in CEA laboratories. Examples of new adsorbents development for liquid wastes decontamination are also given. A chemical process unit based on co-precipitation technique has been successfully and quickly implemented by AREVA at Fukushima site for the processing of contaminated waters. The asset of this technique is its ability to process large volumes in a continuous mode. Several chemical products can be used to address specific radioelements such as: Cs, Sr, Ru. Its drawback is the production of sludge (about 1% in volume of initial liquid volume). CEA developed strategies to model the co-precipitation phenomena in order to firstly minimize the quantity of added chemical reactants and secondly, minimize the size of co-precipitation units. We are on the way to design compact units that could be mobilized very quickly and efficiently in case of an accidental situation. Addressing the problem of sludge conditioning, cementation appears to be a very attractive solution. Fukushima accident has focused attention on optimizations that should be taken into account in future studies: - To better take account for non-typical aqueous matrixes like seawater; - To enlarge the spectrum of radioelements that can be efficiently processed and especially short lives radioelements that are usually less present in standard effluents resulting from nuclear activities; - To develop reversible solid adsorbents for cartridge-type applications in order to minimize wastes. (authors)

  2. Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy

    E-Print Network [OSTI]

    Wen, Haidan

    2010-01-01T23:59:59.000Z

    manifesting in fewer/weaker hydrogen bonds and structuralstructures with weaker hydrogen-bonding is recorded viais characteristic of the hydrogen bond network in water. The

  3. The influence of irrigation water salinity on optimal nitrogen, phosphorus, and potassium liquid fertilizer rates

    E-Print Network [OSTI]

    Campos Nu?n?ez, Ricardo

    1990-01-01T23:59:59.000Z

    of poor quality water (high in soluble salts) and high concentrations of water-soluble fertilizers can induce salt damage in plants. The objective of this work was to investigate the effects of salinity in irrigation water on optimal fertilization rates... in salt-sensitive tropical foliage. Spafhiphyllum 'Petite' and Dieffenbachia 'Camille' were grown using 9 levels of water-soluble fertilizers (0, 25, 50, 100, 200, 400, 800, 1600, 3200 mg I N in a 3-1-2 ratio of N-P205-K20), and two levels of salinity...

  4. NATURAL RADIONUCLIDES MEASUREMENTS IN DRINKING WATER BY LIQUID SCINTILLATION COUNTING. METHODS AND RESULTS

    E-Print Network [OSTI]

    procedure, standardized by International Standard Organization.4 On the contrary, total indicative dose in view of a large scale monitoring program. World Health Organization guidelines for drinking water

  5. Measurements of the Distribution of Solutes between Liquid Water and Steam

    SciTech Connect (OSTI)

    Palmer, D.A.; Simonson, J.M.; Ho, P.C.

    1997-12-31T23:59:59.000Z

    Direct measurements of the concentration of solutes in both liquid and steam phases in equilibrium with each other have been made in a static mode utilizing a platinum-lined autoclave to a maximum of 350 deg C. Partitioning constants were derived from these measurements based on existing experimental or estimated values of the stoichiometric mean activity coefficients for the solutes in the liquid phase. Independent measurements of the conductance of some of the solutes in dilute aqueous solutions to 600 deg C and 300MPa were also made. The combined results are discussed in terms of a speciated model and the implications of these results to industrial and natural hydrothermal processes are presented. PARTITIONING CONSTANT, ION-ASSOCIATION, CONDUCTIVITY, SPECIATION, CORROSION.

  6. On the Existence of Two-Phase Fluid in Good Communication with Liquid Water

    SciTech Connect (OSTI)

    Grant, Malcolm A.

    1980-12-16T23:59:59.000Z

    It has been argued that wells of high discharge enthalpy (two-phase wells) at Baca must be isolated from communication with an extensive liquid reservoir. It is shown that such communication has existed, and been maintained, during the history of Wairakei and Broadlands fields. Interpretation of downhole measurements in two-phase fields, and the nature of the two-phase reservoir fluid, is also treated.

  7. High-Resolution Electrospray Ionization Mass Spectrometry Analysis of Water- Soluble Organic Aerosols Collected with a Particle into Liquid Sampler

    SciTech Connect (OSTI)

    Bateman, Adam P.; Nizkorodov, Serguei; Laskin, Julia; Laskin, Alexander

    2010-10-01T23:59:59.000Z

    This work demonstrates the utility of a particle-into-liquid sampler (PILS) a technique traditionally used for identification of inorganic ions present in ambient or laboratory aerosols for the analysis of water soluble organic aerosol (OA) using high resolution electrospray ionization mass spectrometry (HR ESI-MS). Secondary organic aerosol (SOA) was produced from 0.5 ppm mixing ratios of limonene and ozone in a 5 m3 Teflon chamber. SOA was collected simultaneously using a traditional filter sampler and a PILS. The filter samples were later extracted with either water or acetonitrile, while the aqueous PILS samples were analyzed directly. In terms of peak intensities, types of detectable compounds, average O:C ratios, and organic mass to organic carbon ratios, the resulting high resolution mass spectra were essentially identical for the PILS and filter based samples. SOA compounds extracted from both filter/acetonitrile extraction and PILS/water extraction accounted for >95% of the total ion current in ESI mass spectra. This similarity was attributed to high solubility of limonene SOA in water. In contrast, significant differences in detected ions and peak abundances were observed for pine needle biomass burning organic aerosol (BBOA) collected with PILS and filter sampling. The water soluble fraction of BBOA is considerably smaller than for SOA, and a number of unique peaks were detectable only by the filter/acetonitrile method. The combination of PILS collection with HR-ESI-MS analysis offers a new approach for molecular analysis of the water-soluble organic fraction in biogenic SOA, aged photochemical smog, and BBOA.

  8. Spectrophotometric probe

    DOE Patents [OSTI]

    Prather, William S. (Augusta, GA); O'Rourke, Patrick E. (Martinez, GA)

    1994-01-01T23:59:59.000Z

    A support structure bearing at least one probe for making spectrophotometric measurements of a fluid using a source of light and a spectrophotometer. The probe includes a housing with two optical fibers and a planoconvex lens. A sleeve bearing a mirror surrounds the housing. The lens is separated from the mirror by a fixed distance, defining an interior space for receiving a volume of the fluid sample. A plurality of throughholes extending through the sleeve communicate between the sample volume and the exterior of the probe, all but one hole bearing a screen. A protective jacket surrounds the probe. A hollow conduit bearing a tube is formed in the wall of the probe for venting any air in the interior space when fluid enters. The probe is held at an acute angle so the optic fibers carrying the light to and from the probe are not bent severely on emergence from the probe.

  9. Spectrophotometric probe

    DOE Patents [OSTI]

    Prather, W.S.; O'Rourke, P.E.

    1994-08-02T23:59:59.000Z

    A support structure is described bearing at least one probe for making spectrophotometric measurements of a fluid using a source of light and a spectrophotometer. The probe includes a housing with two optical fibers and a planoconvex lens. A sleeve bearing a mirror surrounds the housing. The lens is separated from the mirror by a fixed distance, defining an interior space for receiving a volume of the fluid sample. A plurality of throughholes extending through the sleeve communicate between the sample volume and the exterior of the probe, all but one hole bearing a screen. A protective jacket surrounds the probe. A hollow conduit bearing a tube is formed in the wall of the probe for venting any air in the interior space when fluid enters. The probe is held at an acute angle so the optic fibers carrying the light to and from the probe are not bent severely on emergence from the probe. 3 figs.

  10. Liquid-phase and vapor-phase dehydration of organic/water solutions

    DOE Patents [OSTI]

    Huang, Yu (Palo Alto, CA); Ly, Jennifer (San Jose, CA); Aldajani, Tiem (San Jose, CA); Baker, Richard W. (Palo Alto, CA)

    2011-08-23T23:59:59.000Z

    Processes for dehydrating an organic/water solution by pervaporation or vapor separation using fluorinated membranes. The processes are particularly useful for treating mixtures containing light organic components, such as ethanol, isopropanol or acetic acid.

  11. Scalability of mass transfer in liquid-liquid flow

    E-Print Network [OSTI]

    Woitalka, A.

    We address liquidliquid mass transfer between immiscible liquids using the system 1-butanol and water, with succinic acid as the mass transfer component. Using this system we evaluate the influence of two-phase flow ...

  12. Advanced Scintillator Detector Concept (ASDC): A Concept Paper on the Physics Potential of Water-Based Liquid Scintillator

    E-Print Network [OSTI]

    Alonso, J R; Bergevin, M; Bernstein, A; Bignell, L; Blucher, E; Calaprice, F; Conrad, J M; Descamps, F B; Diwan, M V; Dwyer, D A; Dye, S T; Elagin, A; Feng, P; Grant, C; Grullon, S; Hans, S; Jaffe, D E; Kettell, S H; Klein, J R; Lande, K; Learned, J G; Luk, K B; Maricic, J; Marleau, P; Mastbaum, A; McDonough, W F; Oberauer, L; Gann, G D Orebi; Rosero, R; Rountree, S D; Sanchez, M C; Shaevitz, M H; Shokair, T M; Smy, M B; Strait, M; Svoboda, R; Tolich, N; Vagins, M R; van Bibber, K A; Viren, B; Vogelaar, R B; Wetstein, M J; Winslow, L; Wonsak, B; Worcester, E T; Wurm, M; Yeh, M; Zhang, C

    2014-01-01T23:59:59.000Z

    The recent development of Water-based Liquid Scintillator (WbLS), and the concurrent development of high-efficiency and high-precision-timing light sensors, has opened up the possibility for a new kind of large-scale detector capable of a very broad program of physics. The program would include determination of the neutrino mass hierarchy and observation of CP violation with long-baseline neutrinos, searches for proton decay, ultra-precise solar neutrino measurements, geo- and supernova neutrinos including diff?use supernova antineutrinos, and neutrinoless double beta decay. We outline here the basic requirements of the Advanced Scintillation Detector Concept (ASDC), which combines the use of WbLS, doping with a number of potential isotopes for a range of physics goals, high efficiency and ultra-fast timing photosensors, and a deep underground location. We are considering such a detector at the Long Baseline Neutrino Facility (LBNF) far site, where the ASDC could operate in conjunction with the liquid argon t...

  13. Advanced Scintillator Detector Concept (ASDC): A Concept Paper on the Physics Potential of Water-Based Liquid Scintillator

    E-Print Network [OSTI]

    J. R. Alonso; N. Barros; M. Bergevin; A. Bernstein; L. Bignell; E. Blucher; F. Calaprice; J. M. Conrad; F. B. Descamps; M. V. Diwan; D. A. Dwyer; S. T. Dye; A. Elagin; P. Feng; C. Grant; S. Grullon; S. Hans; D. E. Jaffe; S. H. Kettell; J. R. Klein; K. Lande; J. G. Learned; K. B. Luk; J. Maricic; P. Marleau; A. Mastbaum; W. F. McDonough; L. Oberauer; G. D. Orebi Gann; R. Rosero; S. D. Rountree; M. C. Sanchez; M. H. Shaevitz; T. M. Shokair; M. B. Smy; A. Stahl; M. Strait; R. Svoboda; N. Tolich; M. R. Vagins; K. A. van Bibber; B. Viren; R. B. Vogelaar; M. J. Wetstein; L. Winslow; B. Wonsak; E. T. Worcester; M. Wurm; M. Yeh; C. Zhang

    2014-10-24T23:59:59.000Z

    The recent development of Water-based Liquid Scintillator (WbLS), and the concurrent development of high-efficiency and high-precision-timing light sensors, has opened up the possibility for a new kind of large-scale detector capable of a very broad program of physics. The program would include determination of the neutrino mass hierarchy and observation of CP violation with long-baseline neutrinos, searches for proton decay, ultra-precise solar neutrino measurements, geo- and supernova neutrinos including diffuse supernova antineutrinos, and neutrinoless double beta decay. We outline here the basic requirements of the Advanced Scintillation Detector Concept (ASDC), which combines the use of WbLS, doping with a number of potential isotopes for a range of physics goals, high efficiency and ultra-fast timing photosensors, and a deep underground location. We are considering such a detector at the Long Baseline Neutrino Facility (LBNF) far site, where the ASDC could operate in conjunction with the liquid argon tracking detector proposed by the LBNE collaboration. The goal is the deployment of a 30-100 kiloton-scale detector, the basic elements of which are being developed now in experiments such as WATCHMAN, ANNIE, SNO+, and EGADS.

  14. Liquid level detector

    DOE Patents [OSTI]

    Tshishiku, Eugene M. (Augusta, GA)

    2011-08-09T23:59:59.000Z

    A liquid level detector for conductive liquids for vertical installation in a tank, the detector having a probe positioned within a sheath and insulated therefrom by a seal so that the tip of the probe extends proximate to but not below the lower end of the sheath, the lower end terminating in a rim that is provided with notches, said lower end being tapered, the taper and notches preventing debris collection and bubble formation, said lower end when contacting liquid as it rises will form an airtight cavity defined by the liquid, the interior sheath wall, and the seal, the compression of air in the cavity preventing liquid from further entry into the sheath and contact with the seal. As a result, the liquid cannot deposit a film to form an electrical bridge across the seal.

  15. Niobium-based sputtered thin films for Corrosion Protection of proton-irradiated liquid water targets for [18F] production

    E-Print Network [OSTI]

    Skliarova, H; Dousset, O; Johnson, R R; Palmieri, V

    2013-01-01T23:59:59.000Z

    Chemically inert Coatings on Havar entrance foils of the targets for [18F] production via proton irradiation of enriched water at pressurized conditions are needed to decrease the amount of ionic contaminants released from Havar. In order to find the most effective protective coatings, the Nb-based coating microstructure and barrier properties have been correlated with deposition parameters as: substrate temperature, applied bias, deposition rate and sputtering gas pressure. Aluminated quartz used as a substrate allowed us to verify the protection efficiency of the desirable coatings as diffusion barriers. Two modeling corrosion tests based on the extreme susceptibility of aluminum to liquid gallium and acid corrosion were applied. Pure Niobium coatings have been found less effective barriers than Niobium-titanium coatings. But Niobium oxide films, according to the corrosion tests performed, showed superior barrier properties. Therefore Multi-layered Niobium-Niobium oxide films have been suggested, since they...

  16. PHYSICAL REVIEW E 87, 012403 (2013) Layer with reduced viscosity at water-oil interfaces probed by fluorescence correlation spectroscopy

    E-Print Network [OSTI]

    Chan, Derek Y C

    2013-01-01T23:59:59.000Z

    . Not surprisingly, therefore, its structure, properties, and interactions with other substances have been are not able to form hydrogen bonds with the polar water molecules. As a result, water repels them in favor hydrophobic surface, however, disrupts the hydrogen-bonding pattern, as supported by existence of dangling OH

  17. Task 15 -- Remediation of organically contaminated soil using hot/liquid (subcritical) water. Semi-annual report, April 1--September 30, 1997

    SciTech Connect (OSTI)

    Hawthorne, S.B.

    1997-12-31T23:59:59.000Z

    This activity involves a pilot-scale demonstration of the use of hot/liquid water for the removal of organic contaminants from soil at the pilot (20 to 40 kg) scale. Lab-scale studies are being performed to determine the optimum temperature, contact time, and flow rates for removal of the organic contaminants. Initial investigations into using carbon sorbents to clean the extractant water for recycle use and to concentrate the extracted contaminants in a small volume for disposal are also being performed. Liquid water is normally considered to be too polar a solvent to be effective for removal of organic contaminants from contaminated soils and sludges. However, the Energy and Environmental Research Center (EERC) has demonstrated that the polarity of liquid water can be changed from that of a very polar solvent at ambient conditions to that of an organic solvent (e.g., ethanol or acetonitrile) by simply raising the temperature. The EERC has exploited this unique property of liquid water to obtain highly selective extractions of polar (at lower temperatures) to nonpolar (at 200 to 250 C) organics from contaminated soils and sludges. Only moderate pressures (a maximum of about 45 atm at 250 C and lower pressures at lower temperatures) are required. With this procedure, all detectable hazardous organics were removed from the sludge, thus making the remaining material (about 99% of the original mass) a nonhazardous material. The present understanding of hot/liquid water extraction for the removal of hazardous organics from contaminated soils and sludges is being used to develop the engineering parameters needed to perform a pilot-scale demonstration of the remediation technology. Progress during the report period is summarized.

  18. Life in the Solar System Assume we need energy, liquid water, and organic materials.

    E-Print Network [OSTI]

    Shirley, Yancy

    wells up and spreads over the surface. A potential mission to Europa would land on the ice pack, use in the last few years! #12;Mars PHOENIX Lander digs up apparent water ice which evaporates Ice chunks Gone, with surface ice. Callisto is heavily cratered, but may also have a deep buried ocean. #12;Enceladus An Icy

  19. Life in the Solar System Assume we need energy, liquid water, and organic materials.

    E-Print Network [OSTI]

    Shirley, Yancy

    ;Small rocky bodies are unlikely to host life: too hot or cold for water, no protective atmosphere so too. #12;Venus is hot (molten lead can exist on its surface!), high pressure (90 atmospheres), toxic, no sunlight, high temperature. Not much chance of life there. Gas Giants #12;The moons of the giant planets

  20. Liquid Water Storage, Distribution, and Removal from Diffusion Media in PEFCS

    E-Print Network [OSTI]

    Mench, Matthew M.

    . Turhan,* K. Heller, J. Brenizer, and M. M. Mench**,z Fuel Cell Dynamics and Diagnostics Laboratory media DM of polymer electrolyte fuel cells PEFCs is a function of design geometry, surface geometry. Available electronically August 28, 2006. The management of water within a polymer electrolyte fuel cell

  1. The Role of Confined Water in Ionic Liquid Electrolytes for Dye-Sensitized Solar Cells

    E-Print Network [OSTI]

    Goddard III, William A.

    for improving the performance of IL DSSC by replacing water with additives that would play the same role Structure, Quantum Chemistry,General Theory The dye-sensitized solar cell (DSSC) proposed by Gratzel et al.1, and nonflammable. However, with current ILs, the DSSC performance is degraded due to decreased reductant rates

  2. Cloud fraction, liquid and ice water contents derived from long-term radar, lidar, and microwave radiometer data are systematically compared to models to quantify and

    E-Print Network [OSTI]

    Hogan, Robin

    Cloud fraction, liquid and ice water contents derived from long-term radar, lidar, and microwave a systematic evaluation of clouds in forecast models. Clouds and their associated microphysical processes for end users of weather forecasts, who may be interested not only in cloud cover, but in other variables

  3. Analysis of liquified coal for nitrogenous bases; separation by high performance liquid chromatography and identification by probe microdistillation/mass spectrometry

    E-Print Network [OSTI]

    Schronk, Leonard Royce

    1978-01-01T23:59:59.000Z

    units 82 CHAPTER I RESEARCH OBJECTIVE AND REVIEW OF LITERATURE Objective and Importance of Work The objective of this research is to develop a new method for analyzing coal liquefaction products through a combination of high performance liquid... in demand. These needs have necessi- tated the development of new sources of fuel. One of these new sources of fuel is synthetic crude derived from coal by liquefaction processes. It provides a promising temporary alternative to a long-term solution...

  4. Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model

    SciTech Connect (OSTI)

    Liu, Haihu; Valocchi, Albert J.; Werth, Charles J.; Kang, Oinjun; Oostrom, Martinus

    2014-11-01T23:59:59.000Z

    A lattice Boltzmann color-fluid model, which was recently proposed by Liu et al. [H. Liu, A.J. Valocchi, and Q. Kang. Three-dimensional lattice Boltzmann model for immiscible two-phase flow simulations. Phys. Rev. E, 85:046309, 2012.] based on a concept of continuum surface force, is improved to simulate immiscible two-phase flows in porous media. The new improvements allow the model to account for different kinematic viscosities of both fluids and to model fluid-solid interactions. The capability and accuracy of this model is first validated by two benchmark tests: a layered two-phase flow with a viscosity ratio, and a dynamic capillary intrusion. This model is then used to simulate liquid CO2 (LCO2) displacing water in a dual-permeability pore network. The extent and behavior of LCO2 preferential flow (i.e., fingering) is found to depend on the capillary number (Ca), and three different displacement patterns observed in previous micromodel experiments are reproduced. The predicted variation of LCO2 saturation with Ca, as well as variation of specific interfacial length with LCO2 saturation, are both in good agreement with the experimental observations. To understand the effect of heterogeneity on pore-scale displacement, we also simulate LCO2 displacing water in a randomly heterogeneous pore network, which has the same size and porosity as the dual-permeability pore network. In comparison to the dual-permeability case, the transition from capillary fingering to viscous fingering occurs at a higher Ca, and LCO2 saturation is higher at low Ca but lower at high Ca. In either pore network, the LCO2-water specific interfacial length is found to obey a power-law dependence on LCO2 saturation.

  5. Isobaric vapor-liquid equilibria for binary and ternary systems composed of water, 1-propanol, and 2-propanol at 100 kPa

    SciTech Connect (OSTI)

    Gabaldon, C.; Marzal, P.; Monton, J.B.; Rodrigo, M.A. [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica] [Univ. de Valencia (Spain). Dept. de Ingenieria Quimica

    1996-11-01T23:59:59.000Z

    Isobaric vapor-liquid equilibria data were obtained for the 2-propanol + 1-propanol binary system and the water + 1-propanol + 2-propanol ternary system at 100 kPa. The data were found to be thermodynamically consistent according to the Van Ness-Byer-Gibbs method for the binary system and according to the McDermott-Ellis method for the ternary one. The binary system is well represented by assuming ideal behavior. The binary interaction parameters obtained from this and previous work are used to predict the vapor-liquid equilibrium for the ternary system using the UNIQUAC, NRTL, and Wilson models. The ternary system is well predicted from binary data.

  6. A system to test the effects of materials on the electron drift lifetime in liquid argon and observations on the effect of water

    SciTech Connect (OSTI)

    Andrews, R.; Jaskierny, W.; Jostlein, H.; Kendziora, C.; Pordes, S.; Tope, T.; /Fermilab; ,

    2009-07-01T23:59:59.000Z

    A materials test system (MTS) has been developed at FNAL to assess the suitability of materials for use in a large liquid argon time projection chamber. During development of the MTS, it was noted that controlling the cryostat pressure with a 'raining' condenser reduced the electron drift lifetime in the liquid argon. The effect of condensing has been investigated using a series of passive materials to filter the condensate. We report the results of these studies and of tests on different candidate materials for detector construction. The inferred reduction of electron drift lifetime by water concentrations in the parts per trillion is of particular interest.

  7. pH Meter probe assembly

    DOE Patents [OSTI]

    Hale, C.J.

    1983-11-15T23:59:59.000Z

    An assembly for mounting a pH probe in a flowing solution, such as a sanitary sewer line, which prevents the sensitive glass portion of the probe from becoming coated with grease, oil, and other contaminants, whereby the probe gives reliable pH indication over an extended period of time. The pH probe assembly utilizes a special filter media and a timed back-rinse feature for flushing clear surface contaminants of the filter. The flushing liquid is of a known pH and is utilized to check performance of the probe. 1 fig.

  8. Acidic Ionic Liquid/Water Solution as Both Medium and Proton Source for Electrocatalytic H2 Evolution by [Ni(P2N2)2]2+ Complexes

    SciTech Connect (OSTI)

    Pool, Douglas H.; Stewart, Michael P.; O'Hagan, Molly J.; Shaw, Wendy J.; Roberts, John A.; Bullock, R. Morris; DuBois, Daniel L.

    2012-09-25T23:59:59.000Z

    The electrocatalytic reduction of protons to H2 by [Ni(PPh2NC6H4-hex2)2](BF4)2 (where PPh2NC6H4-hex2 = 1,5-di(4-n-hexylphenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) in the highly acidic ionic liquid dibutylformamidium bis(trifluoromethanesulfonyl)amide shows a strong dependence on added water. A turnover frequency of 43,000-53,000 s-1 has been measured for hydrogen production at 25 C when the mole fraction of water (?H2O) is 0.72. The same catalyst in acetonitrile with added dimethylformamidium trifluoromethanesulfonate and water has a turnover frequency of 720 s?1. Thus the use of an ionic liquid/aqueous solution enhances the observed catalytic rates by more than a factor of 50 compared to acids in traditional organic solvents such as acetonitrile. Complexes [Ni(PPh2NC6H4X2)2](BF4)2 (X = H, OMe, CH2P(O)(OEt)2, Br) are also catalysts in the ionic liquid/water mixture, and the observed catalytic rates correlate with the hydrophobicity of X. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  9. Solute retention in column liquid chromatography. X. Determination of solute infinite-dilution activity coefficients in methanol, water, and their mixtures, by combined gas-liquid and liquid-liquid chromatography

    SciTech Connect (OSTI)

    Djerki, R.A.; Laub, R.J.

    1988-01-01T23:59:59.000Z

    The Raoult's-law activity coefficients of 3- to 7-carbon aliphatic aldehyde, ketone, ester, and alcohol solutes at infinite dilution in methanol, water, and mixtures of the two and in polydimethysiloxane, all at 293-308 K, have been determined for the first time by appropriate combination of GLC and LLC retention data. The latter data are reported in terms of mole factions, while the former are given in concentration units of molality. However, interpretation of the data is difficult because of the multiplicity of the retention mechanisms. Nevertheless, the combined GLC/LLC technique, which had been applied previously only to pure solvents, is said to offer a number of advantages over static techniques for the determination of solute infinite-dilution activity coefficients with volatile solvents, especially with mixtures of solvents.

  10. Liquid Phase Heating Systems

    E-Print Network [OSTI]

    Mordt, E. H.

    1979-01-01T23:59:59.000Z

    Temperature Water (HTW) central district heating systems are far superior to steam systems in large, spread out installations such as airports, universities and office complexes. Water, pressurized to keep it in the liquid state, is distributed at 400o...

  11. Synthesis of Ag-deionized water nanofluids using multi-beam laser ablation in liquids

    SciTech Connect (OSTI)

    Tran, P.X.; Soong, Yee; Chyu, M.K.

    2007-12-01T23:59:59.000Z

    Multi-pulse laser ablation of silver in deionized water was studied. The laser beams were arranged in a cross-beam configuration. In our experiments, two single-mode, Q-switched Nd-Yag lasers operating at 1064 nm, pulse duration of 5.5 ns and 10 Hz rep rate were used. The laser fluence of the second beam was 0.265 J/cm2 for all tests. Two levels of the laser fluences were used for the ablating beam: 0.09 and 0.265 J/cm2 (11,014 and 33,042 J/cm2 at the focal point, respectively). The silver target was at 50mm from the cell window and 10mm deep. The second beam was aligned parallelly with the silver target and focused at 2mm in front of the focal point of the ablating beam. For all cases, the delay time between the ablating beam and the cross-beam was 40 ms. In general, the ablated particles were almost all spherical. For fluence of 0.09 J/cm 2 and single-beam approach, the mean particle size was about 29 nm. The majority of the particles, however, were in 1935nm range and there were some big ones as large as 5060nm in size. For double-beam approach, the particles were smaller with the average size of about 18nm and the majority of the particles were in 921nm range with few big one as large as 40 nm. For the beam fluence of 0.265 J/cm2 and single-beam configuration, the particle sizes were smaller, the mean particles size was about 18nm and the majority of the particles were in the range of 1022nm with some big one as large as 40 nm. For double-beam approach, the mean particle size was larger (24.2 nm) and the majority of the particle were distributed from 14 to 35nm with some big particles can be found with sizes as big as 70 nm. Preliminary measurements of the thermal conductivity and viscosity of the produced samples showed that the thermal conductivity increased about 35% and the viscosity increased 3.7% above the base fluid viscosity even with the particle volume concentration as low as 0.01%.

  12. Energetics of Hydrogen Bond Network Rearrangements in Liquid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly...

  13. Interpreting the drying kinetics of a soil using a macroscopic thermodynamic non-equilibrium of water between the liquid

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    by diffusion mechanisms within the material [1]. When modelling this second phase, the state variable chosen about liquid-gas phase change in porous media that suggest that the establishment of equilibrium, 9]. Vapour diffusion and liquid-vapour phase change are considered as the main phenomena

  14. An Investigation of Ammonia Extraction from Liquid Manure Using a Gas-Permeable Membrane Pollution of air, soil and water caused by excessive ammonia (NH3) emission and deposition from animal

    E-Print Network [OSTI]

    Mukhtar, Saqib

    An Investigation of Ammonia Extraction from Liquid Manure Using a Gas-Permeable Membrane Summary Pollution of air, soil and water caused by excessive ammonia (NH3) emission and deposition from animal by extracting it from liquid manure and potentially using the recovered NH3 as fertilizer. For this purpose, lab

  15. Millimeter-wave Radiometer for High Sensitivity Water Vapor Profiling in Arid Regions

    SciTech Connect (OSTI)

    Pazmany, Andrew

    2006-11-09T23:59:59.000Z

    Abstract - ProSensing Inc. has developed a G-band (183 GHz) water Vapor Radiometer (GVR) for long-term, unattended measurements of low concentrations of atmospheric water vapor and liquid water. Precipitable water vapor and liquid water path are estimated from zenith brightness temperatures measured from four double-sideband receiver channels, centered at 183.31 1, 3 and 7, and 14 GHz. A prototype ground-based version of the instrument was deployed at the DOE ARM program?s North Slope of Alaska site near Barrow AK in April 2005, where it collected data continuously for one year. A compact, airborne version of this instrument, packaged to operate from a standard 2-D PMS probe canister, has been tested on the ground and is scheduled for test flights in the summer of 2006. This paper presents design details, laboratory test results and examples of retrieved precipitable water vapor and liquid water path from measured brightness temperature data.

  16. Liquid Metal Transformers

    E-Print Network [OSTI]

    Sheng, Lei; Liu, Jing

    2014-01-01T23:59:59.000Z

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

  17. Detecting internal corrosion of natural gas transmission pipelines: field tests of probes and systems for real-time corrosion measurement

    SciTech Connect (OSTI)

    Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, M.; Kane, R.D. (InterCorr International); Meidinger, B. (Rocky Mountain Oilfield Testing Center)

    2005-01-01T23:59:59.000Z

    A field study was conducted to evaluate the use of automated, multi-technique electrochemical corrosion-rate monitoring devices and probes for detecting corrosion in environments similar to those found in natural gas transmission pipelines. It involved measurement of real-time corrosion signals from operating pipelines. Results and interpretation were reported from four different field test locations. Standard flush-mount and custom flange probes were used in four different environments at a gas-gathering site and one environment but two different probe orientations at a natural gas site. These sites were selected to represent normal and upset conditions common in gas transmission pipelines. The environments consisted of two different levels of humidified natural gas, liquid hydrocarbon, and water from natural gas. Probe locations included the 6 and 12 o?clock positions of a natural gas pipeline carrying 2-phase gas/liquid flow. The probe data was monitored using completely remote solar powered systems that provided real-time data transmission via wireless back to a pipeline control station. Data are also presented comparing the ECR probe data to that for coupons used to determine corrosion rate and to detect the presence of microbiologically influenced corrosion (MIC).

  18. Characterization of water-based liquid scintillator response to gammas and neutrons at varying scintillator-surfactant concentrations

    E-Print Network [OSTI]

    Chilton, Lauren (Lauren M.)

    2012-01-01T23:59:59.000Z

    Large scale solar neutron and neutrino flux experiments require many tons of bulk liquid organic scintillator to take spectroscopic data of these energetic particles. However, material and chemical concerns make such ...

  19. Field tests of probes for detecting internal corrosion of natural gas transmission pipelines

    SciTech Connect (OSTI)

    Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, M.; Cayard, Michael S. (Intercorr International Inc.); Kane, Russell D. (Intercorr International Inc.); Meidinger, Brian (RMOTC-DOE)

    2005-01-01T23:59:59.000Z

    A field study was conducted to evaluate the use of electrochemical corrosion rate (ECR) probes for detecting corrosion in environments similar to those found in natural gas transmission pipelines. Results and interpretation will be reported from four different field tests. Flange and flush-mount probes were used in four different environments at a gas-gathering site and one environment but two different orientations at a natural gas plant. These sites were selected to represent normal and upset conditions in a gas transmission pipeline. The environments consisted of 2 different levels of humidified natural gas/organic/water mixtures removed from natural gas, and the environments at the 6 and 12 o'clock positions of a natural gas pipeline carrying 2-phase gas/liquid flow. Data are also presented comparing the ECR probe data to that for coupons used to determine corrosion rate and to detect the presence of microbiologically influenced corrosion (MIC).

  20. Structural transformation in supercooled water controls the crystallization rate of ice

    E-Print Network [OSTI]

    Emily B. Moore; Valeria Molinero

    2011-09-27T23:59:59.000Z

    One of water's unsolved puzzles is the question of what determines the lowest temperature to which it can be cooled before freezing to ice. The supercooled liquid has been probed experimentally to near the homogeneous nucleation temperature TH{\\approx}232 K, yet the mechanism of ice crystallization - including the size and structure of critical nuclei - has not yet been resolved. The heat capacity and compressibility of liquid water anomalously increase upon moving into the supercooled region according to a power law that would diverge at Ts{\\approx}225 K,(1,2) so there may be a link between water's thermodynamic anomalies and the crystallization rate of ice. But probing this link is challenging because fast crystallization prevents experimental studies of the liquid below TH. And while atomistic studies have captured water crystallization(3), the computational costs involved have so far prevented an assessment of the rates and mechanism involved. Here we report coarse-grained molecular simulations with the mW water model(4) in the supercooled regime around TH, which reveal that a sharp increase in the fraction of four-coordinated molecules in supercooled liquid water explains its anomalous thermodynamics and also controls the rate and mechanism of ice formation. The simulations reveal that the crystallization rate of water reaches a maximum around 225 K, below which ice nuclei form faster than liquid water can equilibrate. This implies a lower limit of metastability of liquid water just below TH and well above its glass transition temperature Tg{\\approx}136 K. By providing a relationship between the structural transformation in liquid water, its anomalous thermodynamics and its crystallization rate, this work provides a microscopic foundation to the experimental finding that the thermodynamics of water determines the rates of homogeneous nucleation of ice.(5)

  1. Liquid-Liquid Extraction Processes

    E-Print Network [OSTI]

    Fair, J. R.; Humphrey, J. L.

    1983-01-01T23:59:59.000Z

    Liquid-liquid extraction is the separation of one or more components of a liquid solution by contact with a second immiscible liquid called the solvent. If the components in the original liquid solution distribute themselves differently between...

  2. Development of Nanofluidic Cells for Ultrafast X-ray Studies of Water

    SciTech Connect (OSTI)

    Irizarry, Melvin E.; /Puerto Rico U., Mayaguez /SLAC

    2006-08-23T23:59:59.000Z

    In order to study the molecular structure and dynamics of liquid water with soft x-ray probes, samples with nanoscale dimensions are needed. This paper describes a simple method for preparing nanofluidic water cells. The idea is to confine a thin layer of water between two silicon nitride windows. The windows are 1 mm x 1 mm and 0.5 mm x 0.5 mm in size and have a thickness of 150 nm. The thickness of the water layer was measured experimentally by probing the infrared spectrum of water in the cells with a Fourier Transform InfraRed (FTIR) apparatus and from soft x-ray static measurements at the Advanced Light Source (ALS) at Lawrence Berkeley National Laboratory. Water layers ranging from 10 nm to more than 2 {micro}m were observed. Evidence for changes in the water structure compared to bulk water is observed in the ultrathin cells.

  3. Measuring Diffusivity in Supercooled Liquid Nanoscale Films using...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    gas has been shown to be an effective probe of the diffusivity of supercooled liquid methanol in the experimentally challenging regime near the glass transition temperature. The...

  4. Liquid chromatographic analysis of coal surface properties. Quarterly progress report, September--December 1991

    SciTech Connect (OSTI)

    Kwon, K.C.

    1991-12-31T23:59:59.000Z

    The main objectives of this proposed research are to refine further the inverse liquid chromatography technique for the study of surface properties of raw coals, treated coals and coal minerals in water, to evaluate relatively surface properties of raw coals, treated coals and coal minerals by inverse liquid chromatography, and to evaluate floatability of various treated coals in conjunction with surface properties of coals. Alcohols such as methanol, ethanol, isopropanol, isobutanol, tert-butanol, heptanol, 1-hexadecanol, 2-methyl-pentanol, 4-methyl-2-penthanol (methylisobutyl carbinol), n-octanol, s-octanol, and cyclohexanol as probe compounds are utilized to evaluate hydrophilicity of coals and coal minerals. N-alkanes such as hexane, heptane and octane, and stearic acid are employed as probe compounds to evaluate hydrophobicity of coals and coal minerals. Aromatic compounds such as benzene and toluene as probe compounds are used to examine aromaticity of coal surface. Aromatic acids such as o-cresol, m-cresol, p-cresol, phenol and B-naphthol are used to detect aromatic acidic sites of coal surface. Hydrophilicity, hydrophobicity and aromaticity of surfaces for either raw coals or treated coals in water are relatively determined by evaluating both equilibrium physical/chemical adsorption and dynamic adsorption of probe compounds on various raw coals and treated coals to compare affinities of coals for water.

  5. Acoustic attenuation, phase and group velocities in liquid-filled pipes: Theory, experiment, and examples of water and

    E-Print Network [OSTI]

    Sóbester, András

    ­311 1971 formulation, which predicts the phase speed of propagating axisymmetric modes inside a liquid speed, of the modes as a function of frequency. Measurements of the sound speeds and the attenuations investigated and the measured sound speeds and the damping of the modes were compared with the theoretical

  6. NORIA-SP: A finite element computer program for analyzing liquid water transport in porous media; Yucca Mountain Site Characterization Project

    SciTech Connect (OSTI)

    Hopkins, P.L.; Eaton, R.R.; Bixler, N.E.

    1991-12-01T23:59:59.000Z

    A family of finite element computer programs has been developed at Sandia National Laboratories (SNL) most recently, NORIA-SP. The original NORIA code solves a total of four transport equations simultaneously: liquid water, water vapor, air, and energy. Consequently, use of NORIA is computer-intensive. Since many of the applications for which NORIA is used are isothermal, we decided to ``strip`` the original four-equation version, leaving only the liquid water equation. This single-phase version is NORIA-SP. The primary intent of this document is to provide the user of NORIA-SP an accurate user`s manual. Consequently, the reader should refer to the NORIA manual if additional detail is required regarding the equation development and finite element methods used. The single-equation version of the NORIA code (NORIA-SP) has been used most frequently for analyzing various hydrological scenarios for the potential underground nuclear waste repository at Yucca Mountain in western Nevada. These analyses are generally performed assuming a composite model to represent the fractured geologic media. In this model the material characteristics of the matrix and the fractures are area weighted to obtain equivalent material properties. Pressure equilibrium between the matrix and fractures is assumed so a single conservation equation can be solved. NORIA-SP is structured to accommodate the composite model. The equations for water velocities in both the rock matrix and the fractures are presented. To use the code for problems involving a single, nonfractured porous material, the user can simply set the area of the fractures to zero.

  7. Influence of wettability on liquid water transport in gas diffusion layer of proton exchange membrane fuel cells (PEMFC)

    E-Print Network [OSTI]

    Hamza Chraibi; L. Ceballos; M. Prat; Michel Quintard; Alexandre Vabre

    2009-09-16T23:59:59.000Z

    Water management is a key factor that limits PEFC's performance. We show how insights into this problem can be gained from pore-scale simulations of water invasion in a model fibrous medium. We explore the influence of contact angle on the water invasion pattern and water saturation at breakthrough and show that a dramatic change in the invasion pattern, from fractal to compact, occurs as the system changes from hydrophobic to hydrophilic. Then, we explore the case of a system of mixed wettability, i.e. containing both hydrophilic and hydrophobic pores. The saturation at breakthrough is studied as a function of the fraction of hydrophilic pores. The results are discussed in relation with the water management problem, the optimal design of a GDL and the fuel cell performance degradation mechanisms. We outline how the study could be extended to 3D systems, notably from binarised images of GDLs obtained by X ray microtomography.

  8. Liquid Metal Transformers

    E-Print Network [OSTI]

    Lei Sheng; Jie Zhang; Jing Liu

    2014-01-30T23:59:59.000Z

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clarified. Such events are hard to achieve otherwise on rigid metal or conventional liquid spheres. This finding has both fundamental and practical significances which suggest a generalized way of making smart soft machine, collecting discrete metal fluids, as well as flexibly manipulating liquid metal objects including accompanying devices.

  9. Integrated Optical Probes

    SciTech Connect (OSTI)

    Brent Frogget, Douglas DeVore, Vincent Romero, David Esquibel, and David Holtkamp

    2008-09-04T23:59:59.000Z

    Optical probes used in velocimetry measurements have typically been individual probes that collect data for a single diagnostic at a single point. These probes have been used in diagnostics such as VISAR, PDV, and radiometry, which measure surface velocity, temperature, and other characteristics. When separate probes are used for these measurements, the different diagnostic points measured must be significantly separated. We have developed integrated probes that collect data for multiple optical diagnostics; these probes measure points in close proximity.

  10. Path Integral Molecular Dynamics within the Grand Canonical-like Adaptive Resolution Technique: Quantum-Classical Simulation of Liquid Water

    E-Print Network [OSTI]

    Agarwal, Animesh

    2015-01-01T23:59:59.000Z

    Quantum effects due to the spatial delocalization of light atoms are treated in molecular simulation via the path integral technique. Among several methods, Path Integral (PI) Molecular Dynamics (MD) is nowadays a powerful tool to investigate properties induced by spatial delocalization of atoms; however computationally this technique is very demanding. The abovementioned limitation implies the restriction of PIMD applications to relatively small systems and short time scales. One possible solution to overcome size and time limitation is to introduce PIMD algorithms into the Adaptive Resolution Simulation Scheme (AdResS). AdResS requires a relatively small region treated at path integral level and embeds it into a large molecular reservoir consisting of generic spherical coarse grained molecules. It was previously shown that the realization of the idea above, at a simple level, produced reasonable results for toy systems or simple/test systems like liquid parahydrogen. Encouraged by previous results, in this ...

  11. Molecular Mechanism of the Adsorption Process of an Iodide Anion into Liquid-Vapor Interfaces of Water-Methanol Mixtures

    SciTech Connect (OSTI)

    Annapureddy, Harsha V.; Dang, Liem X.

    2012-12-07T23:59:59.000Z

    To enhance our understanding of the molecular mechanism of ion adsorption to the interface of mixtures, we systematically carried out a free energy calculations study involving the transport of an iodide anion across the interface of a water-methanol mixture. Many body affects are taken into account to describe the interactions among the species. The surface propensities of I- at interfaces of pure water and methanol are well understood. In contrast, detailed knowledge of the molecular level adsorption process of I- at aqueous mixture interfaces has not been reported. In this paper, we explore how this phenomenon will be affected for mixed solvents with varying compositions of water and methanol. Our potential of mean force study as function of varying compositions indicated that I- adsorption free energies decrease from pure water to pure methanol but not linearly with the concentration of methanol. We analyze the computed density profiles and hydration numbers as a function of concentrations and ion positions with respect to the interface to further explain the observed phenomenon. This work was supported by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for DOE by Battelle. The calculations were carried out using computer resources provided by BES.

  12. Investigation of trace amounts of gas on microvave water-cut measurement

    E-Print Network [OSTI]

    Liu, Jin

    2006-08-16T23:59:59.000Z

    sampling probe or a sampling port on the pipeline. Then, the oil and water are separated using a centrifuge. Finally, the volume of the separated water is measured and the water-cut of the sample is calculated based on the total volume of the liquid... pipeline; 2. The oil/water monitor generates the current or electrical signal transmit to a zero-&- span adjuster; 3. From the zero-&-span adjuster, the data is transmitted from analog to digital at converter and calculator and to a comparator. 4...

  13. Hydrodynamic ultrasonic probe

    DOE Patents [OSTI]

    Day, Robert A. (Livermore, CA); Conti, Armond E. (San Jose, CA)

    1980-01-01T23:59:59.000Z

    An improved probe for in-service ultrasonic inspection of long lengths of a workpiece, such as small diameter tubing from the interior. The improved probe utilizes a conventional transducer or transducers configured to inspect the tubing for flaws and/or wall thickness variations. The probe utilizes a hydraulic technique, in place of the conventional mechanical guides or bushings, which allows the probe to move rectilinearly or rotationally while preventing cocking thereof in the tube and provides damping vibration of the probe. The probe thus has lower friction and higher inspection speed than presently known probes.

  14. Early Events in Ionic Liquid Radiation Chemistry

    SciTech Connect (OSTI)

    Wishart, J.F.; Cook, A.; Rimmer, R.D.; Gohdo, M.

    2010-09-14T23:59:59.000Z

    Ionic liquids are interesting and useful materials whose solvation time scales are up to thousands of times longer than in conventional solvents. The extended lifetimes of pre-solvated electrons and other energetic species in ionic liquids has profound consequences for the radiolytic product distributions and reactivity patterns. We use a newly developed, multiplexed variation of pulse-probe spectroscopy to measure the kinetics of the early dynamical and reactive events in ionic liquids.

  15. Probing the interiors of the ice giants: Shock compression of water to 700 GPa and 3.8 g/ccm

    E-Print Network [OSTI]

    Knudson, M D; Lemke, R W; Mattsson, T R; French, M; Nettelmann, N; Redmer, R

    2012-01-01T23:59:59.000Z

    Recently there has been tremendous increase in the number of identified extra-solar planetary systems. Our understanding of their formation is tied to exoplanet internal structure models, which rely upon equations of state of light elements and compounds like water. Here we present shock compression data for water with unprecedented accuracy that shows water equations of state commonly used in planetary modeling significantly overestimate the compressibility at conditions relevant to planetary interiors. Furthermore, we show its behavior at these conditions, including reflectivity and isentropic response, is well described by a recent first-principles based equation of state. These findings advocate this water model be used as the standard for modeling Neptune, Uranus, and "hot Neptune" exoplanets, and should improve our understanding of these types of planets.

  16. Probing the Interiors of the Ice Giants: Shock Compression of Water to 700 GPa and 3.8 g/cm

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knudson, M. D.; Desjarlais, M. P.; Lemke, R. W.; Mattsson, T. R.; French, M.; Nettelmann, N.; Redmer, R.

    2012-02-01T23:59:59.000Z

    Recently, there has been a tremendous increase in the number of identified extrasolar planetary systems. Our understanding of their formation is tied to exoplanet internal structure models, which rely upon equations of state of light elements and compounds such as water. Here, we present shock compression data for water with unprecedented accuracy that show that water equations of state commonly used in planetary modeling significantly overestimate the compressibility at conditions relevant to planetary interiors. Furthermore, we show that its behavior at these conditions, including reflectivity and isentropic response, is well-described by a recent first-principles based equation of state. These findingsmoreadvocate that this water model be used as the standard for modeling Neptune, Uranus, and hot Neptune exoplanets and should improve our understanding of these types of planets.less

  17. Probing the Interiors of the Ice Giants: Shock Compression of Water to 700 GPa and 3.8 g/cm

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Knudson, M. D.; Desjarlais, M. P.; Lemke, R. W.; Mattsson, T. R.; French, M.; Nettelmann, N.; Redmer, R.

    2012-02-01T23:59:59.000Z

    Recently, there has been a tremendous increase in the number of identified extrasolar planetary systems. Our understanding of their formation is tied to exoplanet internal structure models, which rely upon equations of state of light elements and compounds such as water. Here, we present shock compression data for water with unprecedented accuracy that show that water equations of state commonly used in planetary modeling significantly overestimate the compressibility at conditions relevant to planetary interiors. Furthermore, we show that its behavior at these conditions, including reflectivity and isentropic response, is well-described by a recent first-principles based equation of state. These findings advocate that this water model be used as the standard for modeling Neptune, Uranus, and hot Neptune exoplanets and should improve our understanding of these types of planets.

  18. INEEL Liquid Effluent Inventory

    SciTech Connect (OSTI)

    Major, C.A.

    1997-06-01T23:59:59.000Z

    The INEEL contractors and their associated facilities are required to identify all liquid effluent discharges that may impact the environment at the INEEL. This liquid effluent information is then placed in the Liquid Effluent Inventory (LEI) database, which is maintained by the INEEL prime contractor. The purpose of the LEI is to identify and maintain a current listing of all liquid effluent discharge points and to identify which discharges are subject to federal, state, or local permitting or reporting requirements and DOE order requirements. Initial characterization, which represents most of the INEEL liquid effluents, has been performed, and additional characterization may be required in the future to meet regulations. LEI information is made available to persons responsible for or concerned with INEEL compliance with liquid effluent permitting or reporting requirements, such as the National Pollutant Discharge Elimination System, Wastewater Land Application, Storm Water Pollution Prevention, Spill Prevention Control and Countermeasures, and Industrial Wastewater Pretreatment. The State of Idaho Environmental Oversight and Monitoring Program also needs the information for tracking liquid effluent discharges at the INEEL. The information provides a baseline from which future liquid discharges can be identified, characterized, and regulated, if appropriate. The review covered new and removed buildings/structures, buildings/structures which most likely had new, relocated, or removed LEI discharge points, and at least 10% of the remaining discharge points.

  19. Erasing no-man's land by thermodynamically stabilizing the liquid-liquid transition in tetrahedral particles

    E-Print Network [OSTI]

    Loss, Daniel

    compressibility KT and the isobaric heat capacity CP . In the LLCP hypothesis, the density anomalies of waterErasing no-man's land by thermodynamically stabilizing the liquid-liquid transition in tetrahedral, Sapienza, Universit´a di Roma, Piazzale Aldo Moro 2, I-00185, Roma, Italy. EFFECTS OF THE LIQUID-LIQUID

  20. Ultrafast scanning probe microscopy

    DOE Patents [OSTI]

    Weiss, Shimon (El Cerrito, CA); Chemla, Daniel S. (Kensington, CA); Ogletree, D. Frank (El Cerrito, CA); Botkin, David (San Francisco, CA)

    1995-01-01T23:59:59.000Z

    An ultrafast scanning probe microscopy method for achieving subpicosecond-temporal resolution and submicron-spatial resolution of an observation sample. In one embodiment of the present claimed invention, a single short optical pulse is generated and is split into first and second pulses. One of the pulses is delayed using variable time delay means. The first pulse is then directed at an observation sample located proximate to the probe of a scanning probe microscope. The scanning probe microscope produces probe-sample signals indicative of the response of the probe to characteristics of the sample. The second pulse is used to modulate the probe of the scanning probe microscope. The time delay between the first and second pulses is then varied. The probe-sample response signal is recorded at each of the various time delays created between the first and second pulses. The probe-sample response signal is then plotted as a function of time delay to produce a cross-correlation of the probe sample response. In so doing, the present invention provides simultaneous subpicosecond-temporal resolution and submicron-spatial resolution of the sample.

  1. Ultrafast scanning probe microscopy

    DOE Patents [OSTI]

    Weiss, S.; Chemla, D.S.; Ogletree, D.F.; Botkin, D.

    1995-05-16T23:59:59.000Z

    An ultrafast scanning probe microscopy method is described for achieving subpicosecond-temporal resolution and submicron-spatial resolution of an observation sample. In one embodiment of the present claimed invention, a single short optical pulse is generated and is split into first and second pulses. One of the pulses is delayed using variable time delay means. The first pulse is then directed at an observation sample located proximate to the probe of a scanning probe microscope. The scanning probe microscope produces probe-sample signals indicative of the response of the probe to characteristics of the sample. The second pulse is used to modulate the probe of the scanning probe microscope. The time delay between the first and second pulses is then varied. The probe-sample response signal is recorded at each of the various time delays created between the first and second pulses. The probe-sample response signal is then plotted as a function of time delay to produce a cross-correlation of the probe sample response. In so doing, the present invention provides simultaneous subpicosecond-temporal resolution and submicron-spatial resolution of the sample. 6 Figs.

  2. Closed-field capacitive liquid level sensor

    DOE Patents [OSTI]

    Kronberg, J.W.

    1995-01-01T23:59:59.000Z

    A liquid level sensor based on a closed field circuit comprises a ring oscillator using a symmetrical array of plate units that creates a displacement current. The displacement current varies as a function of the proximity of a liquid to the plate units. The ring oscillator circuit produces an output signal with a frequency inversely proportional to the presence of a liquid. A continuous liquid level sensing device and a two point sensing device are both proposed sensing arrangements. A second set of plates may be located inside of the probe housing relative to the sensing plate units. The second set of plates prevent any interference between the sensing plate units.

  3. Quantum fluctuations and isotope effects in ab initio descriptions of water

    E-Print Network [OSTI]

    Lu Wang; Michele Ceriotti; Thomas E. Markland

    2014-06-24T23:59:59.000Z

    Nuclear quantum effects, such as zero-point energy and tunneling, cause significant changes to the structure and dynamics of hydrogen bonded systems such as liquid water. However, due to the current inability to simulate liquid water using an exact description of its electronic structure, the interplay between nuclear and electronic quantum effects remains unclear. Here we use simulations that incorporate the quantum mechanical nature of both the nuclei and electrons to provide a fully ab initio determination of the particle quantum kinetic energies, free energy change upon exchanging hydrogen for deuterium and the isotope fractionation ratio in water. These properties, which selectively probe the quantum nature of the nuclear degrees of freedom, allow us to make direct comparison to recent experiments and elucidate how electronic exchange and correlation and nuclear quantum fluctuations determine the structure of the hydrogen bond in water.

  4. ARM - Measurement - Liquid water content

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDC documentationBarrow,icegovMeasurementsLightning stroke ARM

  5. ARM - Measurement - Liquid water path

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDC documentationBarrow,icegovMeasurementsLightning stroke ARMpath

  6. Ultrafast photo-acoustic spectroscopy of super-cooled liquids

    E-Print Network [OSTI]

    Klieber, Christoph

    2010-01-01T23:59:59.000Z

    Picosecond laser ultrasonic techniques for acoustic wave generation and detection were adapted to probe longitudinal and transverse acoustic waves in liquids at gigahertz frequencies. The experimental effort was designed ...

  7. Directional intraoperative probe

    DOE Patents [OSTI]

    Majewski, Stanislaw; Popov, Vladimir; Loutts, Georgii

    2003-11-04T23:59:59.000Z

    An introperative surgical probe incorporating both a fiber optic imaging system and multi-element beta/gamma radiation directional indicating system is described.

  8. Water and Energy Interactions

    E-Print Network [OSTI]

    McMahon, James E.

    2013-01-01T23:59:59.000Z

    storage. Power towers capture energy from the sun reflectedtower where water or molten salt is flowing to absorb the solar energy.towers or ponds). For liquid fuels, increased reliance on bioenergy will increase the correlation of water and energy

  9. NMR Studies on the Temperature-Dependent Dynamics of Confined Water

    E-Print Network [OSTI]

    Matthias Sattig; Stefan Reutter; Franz Fujara; Mayke Werner; Gerd Buntkowsky; Michael Vogel

    2014-07-16T23:59:59.000Z

    We use $^2$H NMR to study the rotational motion of supercooled water in silica pores of various diameters, specifically, in the MCM-41 materials C10, C12, and C14. Combination of spin-lattice relaxation, line-shape, and stimulated-echo analyses allows us to determine correlation times in very broad time and temperature ranges. For the studied pore diameters, 2.1-2.9 nm, we find two crossovers in the temperature-dependent correlation times of liquid water upon cooling. At 220-230 K, a first kink in the temperature dependence is accompanied by a solidification of a fraction of the confined water, implying that the observed crossover is due to a change from bulk-like to interface-dominated water dynamics, rather than to a liquid-liquid phase transition. Moreover, the results provide evidence that $\\alpha$ process-like dynamics is probed above the crossover temperature, whereas $\\beta$ process-like dynamics is observed below. At 180-190 K, we find a second change of the temperature dependence, which resembles that reported for the $\\beta$ process of supercooled liquids during the glass transition, suggesting a value of $T_g\\!\\approx\\!185$ K for interface-affected liquid water. In the high-temperature range, $T\\!>\\!225$ K, the temperature dependence of water reorientation is weaker in the smaller C10 pores than in the larger C12 and C14 pores, where it is more bulk-like, indicating a significant effect of the silica confinement on the $\\alpha$ process of water in the former 2.1 nm confinement. By contrast, the temperature dependence of water reorientation is largely independent of the confinement size and described by an Arrhenius law with an activation energy of $E_a\\!\\approx\\!0.5\\ $eV in the low-temperature range, $T\\!water.

  10. Abstract--To study the lung water clearance in vivo at the time of the birth, MR experiments were conducted on newborn lamb immediately after uterine incision deliverance. Images obtained with a fast spin echo sequence enable to quantify lung liquid each

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Abstract-- To study the lung water clearance in vivo at the time of the birth, MR experiments were echo sequence enable to quantify lung liquid each 5 minutes during 30 minutes then each 10 minutes for 1.5 hour. From the lung contours, pulmonary volume, pulmonary water, and spatial gradient

  11. IEEE International Conference on Dielectric Liquids (ICDL-2008), Poitiers, June 30-July 4, 2008 Drop-on-demand Extraction from a Water Meniscus by

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Drop-on-demand Extraction from a Water Meniscus by a High Field Pulse P. Atten, A. Ouiguini, J. Raisin of a small drop electrically neutral. The experimental results of water drops extraction in oil are presented, France Abstract- As a part of a study of electrocoalescence of water droplets in oil, the controlled

  12. Carbon nanotube based electromechanical probes

    E-Print Network [OSTI]

    Yaglioglu, Onnik, 1976-

    2007-01-01T23:59:59.000Z

    Electromechanical probing applications continuously require smaller pitches, faster manufacturing and lower electrical resistance. Conventional techniques, such as MEMS based cantilever probes have their shortcomings in ...

  13. Chemical sensing flow probe

    DOE Patents [OSTI]

    Laguna, George R. (Albuquerque, NM); Peter, Frank J. (Albuquerque, NM); Butler, Michael A. (Albuquerque, NM)

    1999-01-01T23:59:59.000Z

    A new chemical probe determines the properties of an analyte using the light absorption of the products of a reagent/analyte reaction. The probe places a small reaction volume in contact with a large analyte volume. Analyte diffuses into the reaction volume. Reagent is selectively supplied to the reaction volume. The light absorption of the reaction in the reaction volume indicates properties of the original analyte. The probe is suitable for repeated use in remote or hostile environments. It does not require physical sampling of the analyte or result in significant regent contamination of the analyte reservoir.

  14. Focus: DNA probes

    SciTech Connect (OSTI)

    Not Available

    1986-11-01T23:59:59.000Z

    Progress in the development of DNA probes for the identification and quantitation of specific genetic sequences in biological samples is reviewed. Current research efforts in the development of DNA probes for the diagnosis of a wide variety of bacterial, viral, and other infectious diseases, such as herpes simplex and cytomegalovirus, and inherited genetic diseases such as cystic fibrosis and sickle cell anemia are discussed. Progress in development of DNA probe assays for cancer diagnosis, detection of Salmonella food poisoning, tissue typing (detection of histocompatibility antigens), mutagen screening, and animal diseases, among other applications is included.

  15. SEPARATION OF COPPER FROM METALS IN AN ALLOY BY LIQUID-LIQUID EXTRACTION

    E-Print Network [OSTI]

    Weston, Ken

    /L. Extraction. The extraction procedure is the same for the sample, standards and blank (water between sample extractions with water. The chloroform extracts at this point will normally be cloudySEPARATION OF COPPER FROM METALS IN AN ALLOY BY LIQUID-LIQUID EXTRACTION Background Reading: Harris

  16. Small ASM probes

    SciTech Connect (OSTI)

    Fritz, J.N.; Olinger, B.; Vorthman, J.E.; Wilder, L.

    1988-10-01T23:59:59.000Z

    A part of the ongoing effort to miniaturize the adjoint sensitivity method (ASM) probe, six small probes in different configurations were tested on a single experiment. The results of the different configurations are presented. The ASM probe is quite accurate and its performance is well understood in those situations where we have a relatively large area that has 1-D flow. Area is expensive and it is desirable to make measurements using a minimum of this resource. When we confine ourselves to a small area we get electromagnetic effects and perturbations in the hydrodynamic flows that were absent in experiments whose lateral extent was large enough to effectively eliminate these problems. We are forced toward magnet and coil configurations that are not ideal for best accuracy. In the experiment described in this report, we describe and report the results of six ASM probes that approach the goal of using less area. 2 refs., 23 figs., 2 tabs.

  17. Oxygen as a site specific structural probe in neutron diffraction

    SciTech Connect (OSTI)

    Neuefeind, Joerg C [ORNL; Simonson, J Michael {Mike} [ORNL; Salmon, Phil [University of Bath; Zeidler, Anita [University of Bath; Fischer, Henry E [Institut Laue-Langevin (ILL); Rauch, Helmut [E141 Atominstitut der & #xD6; sterreichischen Universit& #xE4; ten,; Markland, Thomas [Columbia University; Lemmel, Hartmut [Technical University Vienna

    2011-01-01T23:59:59.000Z

    Oxygen is a ubiquitous element, playing an essential role in most scientific and technological disciplines, and is often incorporated within a structurally disordered material where examples include molten silicates in planetary science, glasses used for lasers and optical communication, and water in biological processes. Establishing the structure of a liquid or glassy oxide and thereby its relation to the functional properties of a material is not, however, a trivial task owing to the complexity associated with atomic disorder. Here we approach this challenge by measuring the bound coherent neutron scattering lengths of the oxygen isotopes with the sensitive technique of neutron interferometry. We find that there is a small but finite contrast of 0.204(6) fm between the scattering lengths of the isotope 18O and oxygen of natural isotopic abundance natO, contrary to tables of recommended values. This has enabled us to investigate the structure of both light and heavy water by exploiting, for the first time, the method of oxygen isotope substitution in neutron diffraction, thus circumventing many of the significant problems associated with more traditional methods in which hydrogen is substituted by deuterium. We find a difference of ~0.5% between the O-H and O-D intra-molecular bond distances which is much smaller than recent estimates based on diffraction data and is found to be in excellent agreement with path integral molecular dynamics simulations made with a flexible polarisable water model. Our results demonstrate the potential for using oxygen isotope substitution as a powerful and effective site specific probe in a plethora of materials, of pertinence as instrumentation at next generation neutron sources comes online

  18. Two-phase air-water stratified flow measurement using ultrasonic techniques

    SciTech Connect (OSTI)

    Fan, Shiwei; Yan, Tinghu; Yeung, Hoi [School of Engineering, Cranfield University, Cranfield, Bedfordshire MK43 0AL (United Kingdom)

    2014-04-11T23:59:59.000Z

    In this paper, a time resolved ultrasound system was developed for investigating two-phase air-water stratified flow. The hardware of the system includes a pulsed wave transducer, a pulser/receiver, and a digital oscilloscope. The time domain cross correlation method is used to calculate the velocity profile along ultrasonic beam. The system is able to provide velocities with spatial resolution of around 1mm and the temporal resolution of 200?s. Experiments were carried out on single phase water flow and two-phase air-water stratified flow. For single phase water flow, the flow rates from ultrasound system were compared with those from electromagnetic flow (EM) meter, which showed good agreement. Then, the experiments were conducted on two-phase air-water stratified flow and the results were given. Compared with liquid height measurement from conductance probe, it indicated that the measured velocities were explainable.

  19. Probing neutrinoless double beta decay with SNO+

    E-Print Network [OSTI]

    Evelina Arushanova; Ashley R. Back

    2015-05-01T23:59:59.000Z

    Probing neutrinoless double beta decay is one of the primary goals for SNO+, SNOLAB's multi-purpose neutrino detector. In order to achieve this goal the SNO detector has been adapted so that it can be filled with Te-loaded liquid scintillator. During the initial double beta phase the target loading is 0.3% natural Te, which equates to $\\sim790$ kg of double beta isotope. Estimating the sensitivity to neutrinoless double beta decay requires a well understood background model. For SNO+ this is provided by a comprehensive study considering all possible background contributions, whether they originate from within the liquid scintillator cocktail, the surrounding parts of the detector or other irreducible backgrounds. Given these considerations, for five years running in the initial phase, the expected sensitivity is $T_{1/2}^{0\

  20. Probing neutrinoless double beta decay with SNO+

    E-Print Network [OSTI]

    Arushanova, Evelina

    2015-01-01T23:59:59.000Z

    Probing neutrinoless double beta decay is one of the primary goals for SNO+, SNOLAB's multi-purpose neutrino detector. In order to achieve this goal the SNO detector has been adapted so that it can be filled with Te-loaded liquid scintillator. During the initial double beta phase the target loading is 0.3% natural Te, which equates to $\\sim790$ kg of double beta isotope. Estimating the sensitivity to neutrinoless double beta decay requires a well understood background model. For SNO+ this is provided by a comprehensive study considering all possible background contributions, whether they originate from within the liquid scintillator cocktail, the surrounding parts of the detector or other irreducible backgrounds. Given these considerations, for five years running in the initial phase, the expected sensitivity is $T_{1/2}^{0\

  1. Convective heat flow probe

    DOE Patents [OSTI]

    Dunn, J.C.; Hardee, H.C.; Striker, R.P.

    1984-01-09T23:59:59.000Z

    A convective heat flow probe device is provided which measures heat flow and fluid flow magnitude in the formation surrounding a borehole. The probe comprises an elongate housing adapted to be lowered down into the borehole; a plurality of heaters extending along the probe for heating the formation surrounding the borehole; a plurality of temperature sensors arranged around the periphery of the probe for measuring the temperature of the surrounding formation after heating thereof by the heater elements. The temperature sensors and heater elements are mounted in a plurality of separate heater pads which are supported by the housing and which are adapted to be radially expanded into firm engagement with the walls of the borehole. The heat supplied by the heater elements and the temperatures measured by the temperature sensors are monitored and used in providing the desired measurements. The outer peripheral surfaces of the heater pads are configured as segments of a cylinder and form a full cylinder when taken together. A plurality of temperature sensors are located on each pad so as to extend along the length and across the width thereof, with a heating element being located in each pad beneath the temperature sensors. An expansion mechanism driven by a clamping motor provides expansion and retraction of the heater pads and expandable packet-type seals are provided along the probe above and below the heater pads.

  2. Nuclear quantum effects in water

    E-Print Network [OSTI]

    Joseph A. Morrone; Roberto Car

    2008-03-25T23:59:59.000Z

    In this work, a path integral Car-Parrinello molecular dynamics simulation of liquid water is performed. It is found that the inclusion of nuclear quantum effects systematically improves the agreement of first principles simulations of liquid water with experiment. In addition, the proton momentum distribution is computed utilizing a recently developed open path integral molecular dynamics methodology. It is shown that these results are in good agreement with neutron Compton scattering data for liquid water and ice.

  3. Orifice mixing of immiscible liquids

    E-Print Network [OSTI]

    McDonough, Joseph Aloysius

    1960-01-01T23:59:59.000Z

    solution (7). The present study of orif1ce mixing is a continuation of previous research on this project which yielded a relationship explaining the effect of operating conditions upon the format1on of 1nterfacial area for the system water-kerosene.... The experimental technique evolved by Helch (18), Vesselhoff (19), McNair (8), and Scott (IA) was changed only slightly. Their work on water-kerosene was repeated for the liquid pairs trichloroethylene-water, heptanol-water, 20 per oent aqueous sucrose-kerosene...

  4. Investigating Water

    E-Print Network [OSTI]

    Howard Jr., Ronald A.

    2002-01-02T23:59:59.000Z

    substances. It covers most of the earth?s surface, sometimes to a depth of more than a mile. It exists as a colorless gas in the atmosphere. It caps the poles with ice and occurs in the snows of winter. Liquid water fills brooks, streams, rivers, lakes, ponds...

  5. Grabbing water

    E-Print Network [OSTI]

    P. M. Reis; J. Hure; S. Jung; J. W. M. Bush; C. Clanet

    2012-07-16T23:59:59.000Z

    We introduce a novel technique for grabbing water with a flexible solid. This new passive pipetting mechanism was inspired by floating flowers and relies purely on the coupling of the elasticity of thin plates and the hydrodynamic forces at the liquid interface. Developing a theoretical model has enabled us to design petal-shaped objects with maximum grabbing capacity.

  6. A numerical method for the simulation of low Mach number liquid-gas flows.

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    consisting of the air bubbles and the liquid water are investigated. They are driven by a heat supply

  7. Multispectral imaging probe

    DOE Patents [OSTI]

    Sandison, D.R.; Platzbecker, M.R.; Descour, M.R.; Armour, D.L.; Craig, M.J.; Richards-Kortum, R.

    1999-07-27T23:59:59.000Z

    A multispectral imaging probe delivers a range of wavelengths of excitation light to a target and collects a range of expressed light wavelengths. The multispectral imaging probe is adapted for mobile use and use in confined spaces, and is sealed against the effects of hostile environments. The multispectral imaging probe comprises a housing that defines a sealed volume that is substantially sealed from the surrounding environment. A beam splitting device mounts within the sealed volume. Excitation light is directed to the beam splitting device, which directs the excitation light to a target. Expressed light from the target reaches the beam splitting device along a path coaxial with the path traveled by the excitation light from the beam splitting device to the target. The beam splitting device directs expressed light to a collection subsystem for delivery to a detector. 8 figs.

  8. aux interfaces liquide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (81 C), its relative safety (compared to liquids such as benzene and toluene of graphite under water and under cyclohexane will be discussed. From the results of this...

  9. Synchrotrons Explore Water's Molecular Mysteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory's Advanced Light Source, scientists observed a surprisingly dense form of water that remained liquid well beyond its typical freezing point. Researchers applied a...

  10. Apparatus for measuring the local void fraction in a flowing liquid containing a gas

    DOE Patents [OSTI]

    Dunn, Patrick F. (Downers Grove, IL)

    1981-01-01T23:59:59.000Z

    The local void fraction in liquid containing a gas is measured by placing an impedance-variation probe in the liquid, applying a controlled voltage or current to the probe, and measuring the probe current or voltage. A circuit for applying the one electrical parameter and measuring the other includes a feedback amplifier that minimizes the effect of probe capacitance and a digitizer to provide a clean signal. Time integration of the signal provides a measure of the void fraction, and an oscilloscope display also shows bubble size and distribution.

  11. Probing Mercury's Partnering Preferences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeedingTechnical News, informationPriority Firm Exchange . .ProbingProbing

  12. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, Amy A. (Augusta, GA)

    1994-01-01T23:59:59.000Z

    A dropping electrolyte electrode for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions.

  13. Probing the Mobility of Supercooled Liquid 3-Methylpentane at...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    well described by the Vogel-Fulcher-Tamman equation. Comparison with the literature viscosity shows that the Stokes-Einstein equation breaks down at temperatures approaching Tg....

  14. Sewage sludge dewatering using flowing liquid metals

    DOE Patents [OSTI]

    Carlson, Larry W. (Oswego, IL)

    1986-01-01T23:59:59.000Z

    A method and apparatus for reducing the moisture content of a moist sewage sludge having a moisture content of about 50% to 80% and formed of small cellular micro-organism bodies having internally confined water is provided. A hot liquid metal is circulated in a circulation loop and the moist sewage sludge is injected in the circulation loop under conditions of temperature and pressure such that the confined water vaporizes and ruptures the cellular bodies. The vapor produced, the dried sludge, and the liquid metal are then separated. Preferably, the moist sewage sludge is injected into the hot liquid metal adjacent the upstream side of a venturi which serves to thoroughly mix the hot liquid metal and the moist sewage sludge. The venturi and the drying zone after the venturi are preferably vertically oriented. The dried sewage sludge recovered is available as a fuel and is preferably used for heating the hot liquid metal.

  15. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1994-07-05T23:59:59.000Z

    A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

  16. SOLVENT EXTRACTION OF PHENOLS FROM WATER

    E-Print Network [OSTI]

    Greminger, Douglas C.

    2012-01-01T23:59:59.000Z

    Waste Water Treatment by Solvent Extraction," Canadian J.A.F. Preuss, "Extraction of Phenol from Water with a Liquid1980 SOLVENT EXTRACTION OF PHENOLS FROM WATER LP,WRENCE BERv

  17. Creaming and breaking of liquid emulsions: a free boundary problem 1 / 48 Creaming and breaking of liquid

    E-Print Network [OSTI]

    Rosso, Fabio

    , as opposite to the other case called instead a water-in-oil emulsion. #12;Creaming and breaking of liquid emulsions: a free boundary problem 4 / 48 What is an emulsion? Everyday life examples (a) water-in-oil of the model 5 A priori estimates 6 Existence and uniqueness #12;Creaming and breaking of liquid emulsions

  18. Environ. Sci. Technol. 1994, 28, 1331-1340 Semlempirical Thermodynamic Modeling of Liquid-Liquid Phase Equilibria

    E-Print Network [OSTI]

    Peters, Catherine A.

    -Liquid Phase Equilibria: Coal Tar Dissolutionin Water-Miscible Solvents Catherine A. Peters'it and Richard 0 coaltar, solvent,and water using the nonrandom, two-liquid (NRTL) equation, a semi- empiricalexcessfreeenergyequation. Coaltar,a complex mixtureofpolycyclicaromatichydrocarbons(PAHs),was represented

  19. Liquid foams of graphene

    E-Print Network [OSTI]

    Alcazar Jorba, Daniel

    2012-01-01T23:59:59.000Z

    Liquid foams are dispersions of bubbles in a liquid. Bubbles are stabilized by foaming agents that position at the interface between the gas and the liquid. Most foaming agents, such as the commonly used sodium dodecylsulfate, ...

  20. Rapid microwave hydrothermal synthesis of ZnGa{sub 2}O{sub 4} with high photocatalytic activity toward aromatic compounds in air and dyes in liquid water

    SciTech Connect (OSTI)

    Sun Meng [School of Resources and Environment, University of Jinan, Jinan 250022 (China); Research Institute of Photocatalysis, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002 (China); Li Danzhen, E-mail: dzli@fzu.edu.cn [Research Institute of Photocatalysis, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002 (China); Zhang Wenjuan; Chen Zhixin; Huang Hanjie; Li Wenjuan; He Yunhui; Fu Xianzhi [Research Institute of Photocatalysis, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002 (China)

    2012-06-15T23:59:59.000Z

    ZnGa{sub 2}O{sub 4} was synthesized from Ga(NO{sub 3}){sub 3} and ZnCl{sub 2} via a rapid and facile microwave-assisted hydrothermal method. The photocatalytic properties of the as-prepared ZnGa{sub 2}O{sub 4} were evaluated by the degradation of pollutants in air and aqueous solution under ultraviolet (UV) light illumination. The results demonstrated that ZnGa{sub 2}O{sub 4} had exhibited efficient photocatalytic activities higher than that of commercial P25 (Degussa Co.) in the degradation of benzene, toluene, and ethylbenzene, respectively. In the liquid phase degradation of dyes (methyl orange, Rhodamine B, and methylene blue), ZnGa{sub 2}O{sub 4} has also exhibited remarkable activities higher than that of P25. After 32 min of UV light irradiation, the decomposition ratio of methyl orange (10 ppm, 150 mL) over ZnGa{sub 2}O{sub 4} (0.06 g) was up to 99%. The TOC tests revealed that the mineralization ratio of MO (10 ppm, 150 mL) was 88.1% after 90 min of reaction. A possible mechanism of the photocatalysis over ZnGa{sub 2}O{sub 4} was also proposed. - Graphical abstract: In the degradation of RhB under UV light irradiation, ZnGa{sub 2}O{sub 4} had exhibited efficient photo-activity, and after only 24 min of irradiation the decomposition ratio was up to 99.8%. Highlights: Black-Right-Pointing-Pointer A rapid and facile M-H method to synthesize ZnGa{sub 2}O{sub 4} photocatalyst. Black-Right-Pointing-Pointer The photocatalyst exhibits high activity toward benzene and dyes. Black-Right-Pointing-Pointer The catalyst possesses more surface hydroxyl sites than TiO{sub 2} (P25). Black-Right-Pointing-Pointer Deep oxidation of different aromatic compounds and dyes over catalyst.

  1. Flexible high-temperature pH probe

    DOE Patents [OSTI]

    Bielawski, John C. (Scotia, NY); Outwater, John O. (Cambridge, MA); Halbfinger, George P. (Schenectady, NY)

    2003-04-22T23:59:59.000Z

    A flexible pH probe device is provided for use in hot water and other high temperature environments up to about 590.degree. F. The pH probe includes a flexible, inert tubular probe member, an oxygen anion conducting, solid state electrolyte plug located at the distal end of the tubular member, oxide powder disposed at the distal end of the tubular member; a metal wire extending along the tubular member and having a distal end in contact with the oxide powder so as to form therewith an internal reference electrode; and a compression fitting forming a pressure boundary seal around a portion of the tubular member remote from the distal end thereof. Preferably, the tubular member is made of polytetrafluoroethylene, and the solid state electrolyte plug is made of stabilized zirconia. The flexibility of the probe member enables placement of the electrode into the area of interest, including around corners, into confined areas and the like.

  2. Experimental probes of axions

    SciTech Connect (OSTI)

    Chou, Aaron S.; /Fermilab

    2009-10-01T23:59:59.000Z

    Experimental searches for axions or axion-like particles rely on semiclassical phenomena resulting from the postulated coupling of the axion to two photons. Sensitive probes of the extremely small coupling constant can be made by exploiting familiar, coherent electromagnetic laboratory techniques, including resonant enhancement of transitions using microwave and optical cavities, Bragg scattering, and coherent photon-axion oscillations. The axion beam may either be astrophysical in origin as in the case of dark matter axion searches and solar axion searches, or created in the laboratory from laser interactions with magnetic fields. This note is meant to be a sampling of recent experimental results.

  3. Probing metal solidification nondestructively

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeedingTechnical News, informationPriority Firm ExchangeSynchrotronProbing

  4. Interactions of Water and Energy Mediate Responses of High-Latitude Terrestrial Ecosystems to Climate Change

    E-Print Network [OSTI]

    Subin, Zachary Marc

    2012-01-01T23:59:59.000Z

    of the heat capacity of the ice mass and liquid water mass.all the ice (liquid) is melted (frozen). Heat capacities are

  5. Ultrasonic probe deployment device for increased wave transmission and rapid area scan inspections

    DOE Patents [OSTI]

    DiMambro, Joseph; Roach, Dennis P; Rackow, Kirk A; Nelson, Ciji L; Dasch, Cameron J; Moore, David G

    2013-02-12T23:59:59.000Z

    An ultrasonic probe deployment device in which an ultrasound-transmitting liquid forms the portion of the ultrasonic wave path in contact with the surface being inspected (i.e., the inspection surface). A seal constrains flow of the liquid, for example preventing the liquid from surging out and flooding the inspection surface. The seal is not rigid and conforms to variations in the shape and unevenness of the inspection surface, thus forming a seal (although possibly a leaky seal) around the liquid. The probe preferably is held in place to produce optimum ultrasonic focus on the area of interest. Use of encoders can facilitate the production of C-scan area maps of the material being inspected.

  6. Ultrasonic probe deployment device for increased wave transmission and rapid area scan inspections

    SciTech Connect (OSTI)

    DiMambro, Joseph (Placitas, NM); Roach, Dennis P. (Albuquerque, NM); Rackow, Kirk A. (Albuquerque, NM); Nelson, Ciji L. (Albuquerque, NM); Dasch, Cameron J. (Boomfield Hills, MI); Moore, David G. (Albuquerque, NM)

    2012-01-03T23:59:59.000Z

    An ultrasonic probe deployment device in which an ultrasound-transmitting liquid forms the portion of the ultrasonic wave path in contact with the surface being inspected (i.e., the inspection surface). A seal constrains flow of the liquid, for example preventing the liquid from surging out and flooding the inspection surface. The seal is not rigid and conforms to variations in the shape and unevenness of the inspection surface, thus forming a seal (although possibly a leaky seal) around the liquid. The probe preferably is held in place to produce optimum ultrasonic focus on the area of interest. Use of encoders can facilitate the production of C-scan area maps of the material being inspected.

  7. Probing Multiparton Correlations at CEBAF

    E-Print Network [OSTI]

    Jianwei Qiu

    1998-08-08T23:59:59.000Z

    In this talk, I explore the possibilities of probing the multiparton correlation functions at CEBAF at its current energy and the energies with its future upgrades.

  8. Alien liquid detector and control

    SciTech Connect (OSTI)

    Potter, B.M.

    1980-09-02T23:59:59.000Z

    An alien liquid detector employs a monitoring element and an energizing circuit for maintaining the temperature of the monitoring element substantially above ambient temperature. For this purpose an electronic circit controls a flow of heating current to the monitoring element. The presence of an alien liquid is detected by sensing a predetermined change in heating current flow to the monitoring element, e.g., to distinguish between water and oil. In preferred embodiments the monitoring element is a thermistor whose resistance is compared with a reference resistance and heating current through the thermistor is controlled in accordance with the difference. In one embodiment a bridge circuit senses the resistance difference; the difference may be sensed by an operational amplifier arrangement. Features of the invention include positioning the monitoring element at the surface of water, slightly immersed, so that the power required to maintain the thermistor temperature substantially above ambient temperature serves to detect presence of oil pollution at the surface.

  9. Liquid Cooling in Data Centers

    SciTech Connect (OSTI)

    Cader, Tahir; Sorell,, Vali; Westra, Levi; Marquez, Andres

    2009-05-01T23:59:59.000Z

    Semiconductor manufacturers have aggressively attacked the problem of escalating microprocessor power consumption levels. Today, server manufacturers can purchase microprocessors that currently have power consumption levels capped at 100W maximum. However, total server power levels continue to increase, with the increase in power consumption coming from the supportin chipsets, memory, and other components. In turn, full rack heat loads are very aggressivley climbing as well, and this is making it increasingly difficult and cost-prohibitive for facility owners to cool these high power racks. As a result, facilities owners are turning to alternative, and more energy efficient, cooling solutions that deploy liquids in one form or another. The paper discusses the advent of the adoption of liquid-cooling in high performance computing centers. An overview of the following competing rack-based, liquid-cooling, technologies is provided: in-row, above rack, refrigerated/enclosed rack, rear door heat exchanger, and device-level (i.e., chip-level). Preparation for a liquid-cooled data center, retroft and greenfield (new), is discussed, with a focus on the key issues that are common to all liquid-cooling technologies that depend upon the delivery of water to the rack (or in some deployments, a Coolant Distribution Unit). The paper then discusses, in some detail, the actual implementation and deployment of a liquid device-level cooled (spray cooled) supercomputer at the Pacific Northwest National Laboratory. Initial results from a successful 30 day compliance test show excellent hardware stability, operating system (OS) and software stack stability, application stability and performance, and an availability level that exceeded expectations at 99.94%. The liquid-cooled supercomputer achieved a peak performance of 9.287 TeraFlops, which placed it at number 101 in the June 2007 Top500 fastest supercomputers worldwide. Long-term performance and energy efficiency testing is currently underway, and detailed results will be reported in upcoming publications.

  10. TRANSPORT AND DYNAMICS IN SUPERCOOLED CONFINED WATER

    E-Print Network [OSTI]

    Stanley, H. Eugene

    Systems B. The Water Heat Capacity VIII. The NMR and the Configurational Heat Capacity IX. Concluding Remarks References Liquid Polymorphism: Advances in Chemical Physics, Volume 152, First Edition. Edited, inside this stable phase, water can also exist in liquid form. When this occurs, water is said

  11. Vapor-liquid equilibrium of water-acetone-air at ambient temperatures and pressures. An analysis of different VLE-fitting methods

    SciTech Connect (OSTI)

    Lichtenbelt, J.H.; Schram, B.J.

    1985-04-01T23:59:59.000Z

    The availability of accurate equilibrium data is of high importance in chemical engineering practice both for design and research purposes. It appeared that for the gas absorption system water-acetone-air in the range of special interest for absorption and desorption operations, neither literature data nor calculations following UNIFAC gave a sufficient accuracy. An experimental program was set up to determine equilibrium data with an accuracy within 2% for low acetone concentrations (up to 7 wt % gas phase) at ambient temperature (16-30/sup 0/C) and atmospheric pressure (740-860 mmHg). From experiments the activity coefficient at infinite dilution of acetone ..gamma.. is found to be 6.79 (0.01) at 20/sup 0/C and 7.28 (0.01) at 25/sup 0/C, while the total error in ..gamma.. is 1.5%. The equilibrium constant can be calculated from ..gamma.. and shows the same error. The experimental data-fitting with procedures of Margules (two parameters) and Van Laar were successful, but NRTL, Wilson, and UNIQUAC failed, probably because of the small concentration range used.

  12. FLUORESCENCE AND FIBER-OPTICS BASED REAL-TIME THICKNESS SENSOR FOR DYNAMIC LIQUID FILMS

    E-Print Network [OSTI]

    Narain, Amitabh

    /analyzed the incident reflected waves to identify and measure the total transit time of the sound wave (of known wave-speed1 FLUORESCENCE AND FIBER-OPTICS BASED REAL-TIME THICKNESS SENSOR FOR DYNAMIC LIQUID FILMS T. W. Ng/disadvantages of many known liquid film thickness sensing devices (viz. conductivity probes, reflectance based fiber

  13. Reorientation of the free OH group in the top-most layer of air/water interface of sodium fluoride aqueous solution probed with sum-frequency generation vibrational spectroscopy

    SciTech Connect (OSTI)

    Feng, Ran-Ran; Guo, Yuan; Wang, Hongfei

    2014-09-17T23:59:59.000Z

    Many experimental and theoretical studies have established the specific anion, as well as cation effects on the hydrogen-bond structures at the air/water interface of electrolyte solutions. However, the ion effects on the top-most layer of the air/water interface, which is signified by the non-hydrogen-bonded so-called free O-H group, has not been discussed or studied. In this report, we present the measurement of changes of the orientational angle of the free O-H group at the air/water interface of the sodium fluoride (NaF) solutions at different concentrations using the interface selective sum-frequency generation vibrational spectroscopy (SFG-VS) in the ssp and ppp polarizations. The polarization dependent SFG-VS results show that the average tilt angle of the free O-H changes from about 35.3 degrees 0.5 degrees to 43.4 degrees 2.1degrees as the NaF concentration increase from 0 to 0.94M (nearly saturated). Such tilt angle change is around the axis of the other O-H group of the same water molecule at the top-most layer at the air/water interface that is hydrogen-bonded to the water molecules below the top-most layer. These results provide quantitative molecular details of the ion effects of the NaF salt on the structure of the water molecules at the top-most layer of the air/water interfacial, even though both the Na+ cation and the F- anion are believed to be among the most excluded ions from the air/water interface.

  14. Modeling of thermal processes in very high pressure liquid chromatography for column immersed in a water bath: Application of the selected models

    SciTech Connect (OSTI)

    Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL; Kaczmarski, Krzysztof [University of Tennessee and Rzeszow University of Technology, Poland

    2010-01-01T23:59:59.000Z

    Currently, chromatographic analyses are carried out by operating columns packed with sub-2 {micro}m particles under very high pressure gradients, up to 1200 bar for 5 cm long columns. This provides the high flow rates that are necessary for the achievement of high column efficiencies and short analysis times. However, operating columns at high flow rates under such high pressure gradients generate a large amount of heat due to the viscous friction of the mobile phase stream that percolates through a low permeability bed. The evacuation of this heat causes the formation of significant or even large axial and radial gradients of all the physico-chemical parameters characterizing the packing material and the mobile phase, eventually resulting in a loss of column efficiency. We previously developed and successfully applied a model combining the heat and the mass balances of a chromatographic column operated under very high pressure gradients (VHPLC). The use of this model requires accurate estimates of the dispersion coefficients at each applied mobile phase velocity. This work reports on a modification of the mass balance model such that only one measurement is now necessary to accurately predict elution peak profiles in a wide range of mobile phase velocities. The conditions under which the simple equilibrium-dispersive (ED) and transport-dispersive (TD) models are applicable in VHPLC are also discussed. This work proves that the new combination of the heat transfer and the ED model discussed in this work enables the calculation of accurate profiles for peaks eluted under extreme conditions, like when the column is thermostated in a water bath.

  15. Rosetta probe makes history

    E-Print Network [OSTI]

    Bandara, Arosha

    The lure of urban living As the waters rise Living with rising seas Privacy versus security Why one doesn city 38 Privacy vs secUriTy In the great debate, which do you value more? 40 as The waTers rise How UniversiTy maTTers From Vice-Chancellor Martin Bean 50 Three wOrds OU alumnus Stuart Wright explains why he

  16. 2010 Water & Aqueous Solutions

    SciTech Connect (OSTI)

    Dor Ben-Amotz

    2010-08-13T23:59:59.000Z

    Water covers more than two thirds of the surface of the Earth and about the same fraction of water forms the total mass of a human body. Since the early days of our civilization water has also been in the focus of technological developments, starting from converting it to wine to more modern achievements. The meeting will focus on recent advances in experimental, theoretical, and computational understanding of the behavior of the most important and fascinating liquid in a variety of situations and applications. The emphasis will be less on water properties per se than on water as a medium in which fundamental dynamic and reactive processes take place. In the following sessions, speakers will discuss the latest breakthroughs in unraveling these processes at the molecular level: Water in Solutions; Water in Motion I and II; Water in Biology I and II; Water in the Environment I and II; Water in Confined Geometries and Water in Discussion (keynote lecture and poster winners presentations).

  17. Safetygram #9- Liquid Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  18. Heat transfer probe

    DOE Patents [OSTI]

    Frank, Jeffrey I.; Rosengart, Axel J.; Kasza, Ken; Yu, Wenhua; Chien, Tai-Hsin; Franklin, Jeff

    2006-10-10T23:59:59.000Z

    Apparatuses, systems, methods, and computer code for, among other things, monitoring the health of samples such as the brain while providing local cooling or heating. A representative device is a heat transfer probe, which includes an inner channel, a tip, a concentric outer channel, a first temperature sensor, and a second temperature sensor. The inner channel is configured to transport working fluid from an inner inlet to an inner outlet. The tip is configured to receive at least a portion of the working fluid from the inner outlet. The concentric outer channel is configured to transport the working fluid from the inner outlet to an outer outlet. The first temperature sensor is coupled to the tip, and the second temperature sensor spaced apart from the first temperature sensor.

  19. Cosmological Probes for Supersymmetry

    E-Print Network [OSTI]

    Khlopov, Maxim

    2015-01-01T23:59:59.000Z

    The multi-parameter character of supersymmetric dark-matter models implies the combination of their experimental studies with astrophysical and cosmological probes. The physics of the early Universe provides nontrivial effects of non-equilibrium particles and primordial cosmological structures. Primordial black holes (PBHs) are a profound signature of such structures that may arise as a cosmological consequence of supersymmetric (SUSY) models. SUSY-based mechanisms of baryosynthesis can lead to the possibility of antimatter domains in a baryon asymmetric Universe. In the context of cosmoparticle physics, which studies the fundamental relationship of the micro- and macro-worlds, the development of SUSY illustrates the main principles of this approach, as the physical basis of the modern cosmology provides cross-disciplinary tests in physical and astronomical studies.

  20. Growth of flower-like CdSe dendrites from a Brnsted acidbase ionic liquid precursor{

    E-Print Network [OSTI]

    Utrecht, Universiteit

    solution of water, ethanol and ionic liquid based on formic acid and N,N-dimethylformamide. Experimental, ethanol, an ionic liquid based on formic acid and N,N-dimethylformamide, cadmium chloride and sel

  1. Rotating concave eddy current probe

    SciTech Connect (OSTI)

    Roach, Dennis P. (Albuquerque, NM); Walkington, Phil (Albuquerque, NM); Rackow, Kirk A. (Albuquerque, NM); Hohman, Ed (Albuquerque, NM)

    2008-04-01T23:59:59.000Z

    A rotating concave eddy current probe for detecting fatigue cracks hidden from view underneath the head of a raised head fastener, such as a buttonhead-type rivet, used to join together structural skins, such as aluminum aircraft skins. The probe has a recessed concave dimple in its bottom surface that closely conforms to the shape of the raised head. The concave dimple holds the probe in good alignment on top of the rivet while the probe is rotated around the rivet's centerline. One or more magnetic coils are rigidly embedded within the probe's cylindrical body, which is made of a non-conducting material. This design overcomes the inspection impediment associated with widely varying conductivity in fastened joints.

  2. Flowmeter for determining average rate of flow of liquid in a conduit

    DOE Patents [OSTI]

    Kennerly, J.M.; Lindner, G.M.; Rowe, J.C.

    1981-04-30T23:59:59.000Z

    This invention is a compact, precise, and relatively simple device for use in determining the average rate of flow of a liquid through a conduit. The liquid may be turbulent and contain bubbles of gas. In a preferred embodiment, the flowmeter includes an electrical circuit and a flow vessel which is connected as a segment of the conduit conveying the liquid. The vessel is provided with a valved outlet and is partitioned by a vertical baffle into coaxial chambers whose upper regions are vented to permit the escape of gas. The inner chamber receives turbulent downflowing liquid from the conduit and is sized to operate at a lower pressure than the conduit, thus promoting evolution of gas from the liquid. Lower zones of the two chambers are interconnected so that the downflowing liquid establishes liquid levels in both chambers. The liquid level in the outer chamber is comparatively calm, being to a large extent isolated from the turbulence in the inner chamber once the liquid in the outer chamber has risen above the liquid-introduction zone for that chamber. Lower and upper probes are provided in the outer chamber for sensing the liquid level therein at points above its liquid-introduction zone. An electrical circuit is connected to the probes to display the time required for the liquid level in the outer chamber to successively contact the lower and upper probes. The average rate of flow through the conduit can be determined from the above-mentioned time and the vessel volume filled by the liquid during that time.

  3. Flowmeter for determining average rate of flow of liquid in a conduit

    DOE Patents [OSTI]

    Kennerly, John M. (Knoxville, TN); Lindner, Gordon M. (Oak Ridge, TN); Rowe, John C. (Oak Ridge, TN)

    1982-01-01T23:59:59.000Z

    This invention is a compact, precise, and relatively simple device for use in determining the average rate of flow of a liquid through a conduit. The liquid may be turbulent and contain bubbles of gas. In a preferred embodiment, the flowmeter includes an electrical circuit and a flow vessel which is connected as a segment of the conduit conveying the liquid. The vessel is provided with a valved outlet and is partitioned by a vertical baffle into coaxial chambers whose upper regions are vented to permit the escape of gas. The inner chamber receives turbulent downflowing liquid from the conduit and is sized to operate at a lower pressure than the conduit, thus promoting evolution of gas from the liquid. Lower zones of the two chambers are interconnected so that the downflowing liquid establishes liquid levels in both chambers. The liquid level in the outer chamber is comparatively calm, being to a large extent isolated from the turbulence in the inner chamber once the liquid in the outer chamber has risen above the liquid-introduction zone for that chamber. Lower and upper probes are provided in the outer chamber for sensing the liquid level therein at points above its liquid-introduction zone. An electrical circuit is connected to the probes to display the time required for the liquid level in the outer chamber to successively contact the lower and upper probes. The average rate of flow through the conduit can be determined from the above-mentioned time and the vessel volume filled by the liquid during that time.

  4. Liquid soap film generates electricity

    E-Print Network [OSTI]

    Ahmad Amjadi; Sadegh Feiz; Reza Montazeri Namin

    2014-04-24T23:59:59.000Z

    We have observed that a rotating liquid soap film generates electricity when placed between two non-contact electrodes with a sufficiently large potential difference. In our experiments suspended liquid film (water + soap film) is formed on the surface of a circular frame, which is forced to rotate in the $x-y$ horizontal plane by a motor. This system is located at the center of two capacitor-like vertical plates to apply an external electric voltage difference in the $x-$direction. The produced electric current is collected from the liquid film using two conducting electrodes that are separated in the $y-$direction. We previously reported that a liquid film in an external electric field rotates when an electric current passes through it, naming it the liquid film motor (LFM). In this paper we report a novel technique, in which a similar device can be used as an electric generator, converting the rotating mechanical energy to electrical energy. The liquid film electric generator (LFEG) is in stark contrast to the LFM, both of which could be designed similarly in very small scales like micro scales with different applications. Although the device is comparable to commercial electric motors or electric generators, there is a significant difference in their working principles. Usually in an electric motor or generator the magnetic field causes the driving force, while in a LFM or LFEG the Coulomb force is the driving force. This fact is also interesting from the Bio-science point of view and brings a similarity to bio motors. Here we have investigated the electrical characteristics of such a generator for the first time experimentally and modelled the phenomenon with electroconvection governing equations. A numerical simulation is performed using the local approximation for the charge-potential relation and results are in qualitative agreement with experiments.

  5. Fiberoptic probe and system for spectral measurements

    DOE Patents [OSTI]

    Dai, S.; Young, J.P.

    1998-10-13T23:59:59.000Z

    A fused fiberoptic probe, a system, method and embodiments thereof for conducting spectral measurements are disclosed. The fused fiberoptic probe comprises a probe tip having a specific geometrical configuration, an exciting optical fiber and at least one collection optical fiber fused within a housing, preferably silica. The specific geometrical configurations in which the probe tip can be shaped include a slanted probe tip with an angle greater than 0{degree}, an inverted cone-shaped probe tip, and a lens head. 12 figs.

  6. Scanning Probe AFM Compound Microscope | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probe AFM Compound Microscope Scanning Probe AFM Compound Microscope The atomic force microscope (AFM) compound microscope is designed primarily for fluorescence imaging in the...

  7. Long duration ash probe

    DOE Patents [OSTI]

    Hurley, J.P.; McCollor, D.P.; Selle, S.J.

    1994-07-26T23:59:59.000Z

    A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during soot blowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon. 8 figs.

  8. Long duration ash probe

    DOE Patents [OSTI]

    Hurley, John P. (Grand Forks, ND); McCollor, Don P. (Grand Forks, ND); Selle, Stanley J. (Grand Forks, MN)

    1994-01-01T23:59:59.000Z

    A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during sootblowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon.

  9. Water's Hydrogen Bond Strength

    E-Print Network [OSTI]

    Martin Chaplin

    2007-06-10T23:59:59.000Z

    Water is necessary both for the evolution of life and its continuance. It possesses particular properties that cannot be found in other materials and that are required for life-giving processes. These properties are brought about by the hydrogen bonded environment particularly evident in liquid water. Each liquid water molecule is involved in about four hydrogen bonds with strengths considerably less than covalent bonds but considerably greater than the natural thermal energy. These hydrogen bonds are roughly tetrahedrally arranged such that when strongly formed the local clustering expands, decreasing the density. Such low density structuring naturally occurs at low and supercooled temperatures and gives rise to many physical and chemical properties that evidence the particular uniqueness of liquid water. If aqueous hydrogen bonds were actually somewhat stronger then water would behave similar to a glass, whereas if they were weaker then water would be a gas and only exist as a liquid at sub-zero temperatures. The overall conclusion of this investigation is that water's hydrogen bond strength is poised centrally within a narrow window of its suitability for life.

  10. Optic probe for semiconductor characterization

    DOE Patents [OSTI]

    Sopori, Bhushan L. (Denver, CO); Hambarian, Artak (Yerevan, AM)

    2008-09-02T23:59:59.000Z

    Described herein is an optical probe (120) for use in characterizing surface defects in wafers, such as semiconductor wafers. The optical probe (120) detects laser light reflected from the surface (124) of the wafer (106) within various ranges of angles. Characteristics of defects in the surface (124) of the wafer (106) are determined based on the amount of reflected laser light detected in each of the ranges of angles. Additionally, a wafer characterization system (100) is described that includes the described optical probe (120).

  11. Liquid Hydrogen Absorber for MICE

    E-Print Network [OSTI]

    Ishimoto, S.

    2010-01-01T23:59:59.000Z

    REFERENCES Figure 5: Liquid hydrogen absorber and test6: Cooling time of liquid hydrogen absorber. Eight CernoxLIQUID HYDROGEN ABSORBER FOR MICE S. Ishimoto, S. Suzuki, M.

  12. Instabilities during liquid migration into superheated hydrothermal systems

    SciTech Connect (OSTI)

    Fitzgerald, Shaun D.; Woods, Andrew W.

    1995-01-26T23:59:59.000Z

    Hydrothermal systems typically consist of hot permeable rock which contains either liquid or liquid and saturated steam within the voids. These systems vent fluids at the surface through hot springs, fumaroles, mud pools, steaming ground and geysers. They are simultaneously recharged as meteoric water percolates through the surrounding rock or through the active injection of water at various geothermal reservoirs. In a number of geothermal reservoirs from which significant amounts of hot fluid have been extracted and passed through turbines, superheated regions of vapor have developed. As liquid migrates through a superheated region of a hydrothermal system, some of the liquid vaporizes at a migrating liquid-vapor interface. Using simple physical arguments, and analogue laboratory experiments we show that, under the influence of gravity, the liquid-vapor interface may become unstable and break up into fingers.

  13. Monitoring probe for groundwater flow

    DOE Patents [OSTI]

    Looney, B.B.; Ballard, S.

    1994-08-23T23:59:59.000Z

    A monitoring probe for detecting groundwater migration is disclosed. The monitor features a cylinder made of a permeable membrane carrying an array of electrical conductivity sensors on its outer surface. The cylinder is filled with a fluid that has a conductivity different than the groundwater. The probe is placed in the ground at an area of interest to be monitored. The fluid, typically saltwater, diffuses through the permeable membrane into the groundwater. The flow of groundwater passing around the permeable membrane walls of the cylinder carries the conductive fluid in the same general direction and distorts the conductivity field measured by the sensors. The degree of distortion from top to bottom and around the probe is precisely related to the vertical and horizontal flow rates, respectively. The electrical conductivities measured by the sensors about the outer surface of the probe are analyzed to determine the rate and direction of the groundwater flow. 4 figs.

  14. Monitoring probe for groundwater flow

    DOE Patents [OSTI]

    Looney, Brian B. (Aiken, SC); Ballard, Sanford (Albuquerque, NM)

    1994-01-01T23:59:59.000Z

    A monitoring probe for detecting groundwater migration. The monitor features a cylinder made of a permeable membrane carrying an array of electrical conductivity sensors on its outer surface. The cylinder is filled with a fluid that has a conductivity different than the groundwater. The probe is placed in the ground at an area of interest to be monitored. The fluid, typically saltwater, diffuses through the permeable membrane into the groundwater. The flow of groundwater passing around the permeable membrane walls of the cylinder carries the conductive fluid in the same general direction and distorts the conductivity field measured by the sensors. The degree of distortion from top to bottom and around the probe is precisely related to the vertical and horizontal flow rates, respectively. The electrical conductivities measured by the sensors about the outer surface of the probe are analyzed to determine the rate and direction of the groundwater flow.

  15. Water: A Complex Liquid Marcia C. Barbosa

    E-Print Network [OSTI]

    Liu, I-Shih

    and Entropy (S - S )(V - V ) #12;Diffusion - SPC/E Berendsen, Grigera, Straatsma, JCP 91, 6269 (87) #12;Diffusion - SPC/E Netz, Starr, Stanley, Barbosa JCP 115, 344 (01) #12;Rotation Diffusion - SPC/E Netz, Starr) Particles make four bonds BUT they have five neighbors!!! #12;Frequency - SPC/E Netz, Starr, MCB and Stanley

  16. Damping of liquid sloshing by foams

    E-Print Network [OSTI]

    Alban Sauret; Franois Boulogne; Jean Cappello; Emilie Dressaire; Howard A. Stone

    2015-02-01T23:59:59.000Z

    When a container is set in motion, the free surface of the liquid starts to oscillate or slosh. Such effects can be observed when a glass of water is handled carelessly and the fluid sloshes or even spills over the rims of the container. However, beer does not slosh as readily as water, which suggests that foam could be used to damp sloshing. In this work, we study experimentally the effect on sloshing of a liquid foam placed on top of a liquid bath. We generate a monodisperse two-dimensional liquid foam in a rectangular container and track the motion of the foam. The influence of the foam on the sloshing dynamics is experimentally characterized: only a few layers of bubbles are sufficient to significantly damp the oscillations. We rationalize our experimental findings with a model that describes the foam contribution to the damping coefficient through viscous dissipation on the walls of the container. Then we extend our study to confined three-dimensional liquid foam and observe that the behavior of 2D and confined 3D systems are very similar. Thus we conclude that only the bubbles close to the walls have a significant impact on the dissipation of energy. The possibility to damp liquid sloshing using foam is promising in numerous industrial applications such as the transport of liquefied gas in tankers or for propellants in rocket engines.

  17. Predictions of Dynamic Behavior under Pressure for Two Scenarios to Explain Water Anomalies Pradeep Kumar,1

    E-Print Network [OSTI]

    Franzese, Giancarlo

    of maximum correlation length in the (T, P) plane. Response functions, such as the isobaric heat capacity CP crossover is independent of whether water at very low temperature is characterized by a ``liquid-liquid scenarios are commonly used to interpret the anomalies of water [1,2]: (i) The liquid-liquid critical point

  18. Equation for liquid density

    SciTech Connect (OSTI)

    Yaws, C.L.; Yang, H.C.; Hopper, J.R.; Cawley, W.A. (Lamar Univ., Beaumont, TX (US))

    1991-01-01T23:59:59.000Z

    Saturated liquid densities for organic chemicals are given as functions of temperature using a modified Rackett equation.

  19. aux interfaces solide-liquide: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (81 C), its relative safety (compared to liquids such as benzene and toluene of graphite under water and under cyclohexane will be discussed. From the results of this...

  20. OIL DROPLET MANIPULATION USING LIQUID DIELECTROPHORESIS ON ELECTRET WITH SUPERLYOPHOBIC

    E-Print Network [OSTI]

    Kasagi, Nobuhide

    OIL DROPLET MANIPULATION USING LIQUID DIELECTROPHORESIS ON ELECTRET WITH SUPERLYOPHOBIC SURFACES flow friction for water and oil. Charge stability of electret in liquid is much improved with new hysteresis of SLS for oil droplets are experimentally demonstrated, indicating low motion resistance

  1. Liquid detection circuit

    DOE Patents [OSTI]

    Regan, Thomas O. (North Aurora, IL)

    1987-01-01T23:59:59.000Z

    Herein is a circuit which is capable of detecting the presence of liquids, especially cryogenic liquids, and whose sensor will not overheat in a vacuum. The circuit parameters, however, can be adjusted to work with any liquid over a wide range of temperatures.

  2. WATER INFLOW INTO BOREHOLES DURING THE STRIPA HEATER EXPERIMENTS

    E-Print Network [OSTI]

    Nelson, P.H.

    2010-01-01T23:59:59.000Z

    is plotted against water extraction rate with temper aturei^ H 2 _ -i I Liquid water extraction rate (liters/day) XBLholi? s due to water extraction was negligible because the

  3. NUMERICAL SIMULATION OF RESERVOIR COMPACTION IN LIQUID DOMINATED GEOTHERMAL SYSTEMS

    E-Print Network [OSTI]

    Lippmann, M.J.

    2010-01-01T23:59:59.000Z

    13. modeling of liquid geothermal systems: Ph.D. thesis,of water dominated geothermal fields with large temper~of land subsidence in geothermal areas: Proc. 2nd Int. Symp.

  4. Boiling and condensation in a liquid-filled enclosure

    E-Print Network [OSTI]

    Bar-Cohen Avram

    1971-01-01T23:59:59.000Z

    A combined experimental and analytical investigation of boiling and condensation in a liquid-filled enclosure, with water and Freon- 113 as the working fluids, is described. The operating characteristics of a boiling system, ...

  5. Designing liquid repellent surfaces for fabrics, feathers and fog

    E-Print Network [OSTI]

    Chhatre, Shreerang S. (Shreerang Sharad)

    2013-01-01T23:59:59.000Z

    Omniphobicity refers to a property of surfaces which are not wetted by water, oils, alcohols and other low surface tension liquids. Robust omniphobic surfaces can be applied in many areas including fabrics with chemical / ...

  6. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, J.E.; Bolton, R.D.

    1999-03-02T23:59:59.000Z

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans. 4 figs.

  7. Radiation monitor for liquids

    DOE Patents [OSTI]

    Koster, James E. (Los Alamos, NM); Bolton, Richard D. (Los Alamos, NM)

    1999-01-01T23:59:59.000Z

    A radiation monitor for use with liquids that utilizes air ions created by alpha radiation emitted by the liquids as its detectable element. A signal plane, held at an electrical potential with respect to ground, collects these air ions. A guard plane or guard rings is used to limit leakage currents. In one embodiment, the monitor is used for monitoring liquids retained in a tank. Other embodiments monitor liquids flowing through a tank, and bodies of liquids, such as ponds, lakes, rivers and oceans.

  8. Rotary union for use with ultrasonic thickness measuring probe

    DOE Patents [OSTI]

    Nachbar, H.D.

    1992-09-15T23:59:59.000Z

    A rotary union for rotatably supporting an ultrasonic probe operable to nondestructively measure the thickness of steam generator tubes to determine the amount of corrosion experienced by the tubes includes a stationary body having a bore therethrough and an outlet drain, and a fitting rotatably mounted within the upper end of the body. The fitting has a bore aligned with the bore of the body. An electrical cable positioned within a water supply tube in an annular arrangement passes through the bore of the body and the bore of the fitting. This annular arrangement, in turn, is positioned within a connector element which extends outwardly from the fitting bore and is connected to the ultrasonic probe. An elastomeric lower bushing seals the annular arrangement to the lower end of the rotary union body and an elastomeric upper bushing seals the connector element to the fitting to permit the connector element and the ultrasonic probe connected thereto to rotate with the fitting relative to the body. The lower and upper bushings permit water to be passed through the annular arrangement and into the ultrasonic probe and thereafter discharged between the annular arrangement and the connector element to the outlet drain of the rotary union body. 5 figs.

  9. Liquid Wall Chambers

    SciTech Connect (OSTI)

    Meier, W R

    2011-02-24T23:59:59.000Z

    The key feature of liquid wall chambers is the use of a renewable liquid layer to protect chamber structures from target emissions. Two primary options have been proposed and studied: wetted wall chambers and thick liquid wall (TLW) chambers. With wetted wall designs, a thin layer of liquid shields the structural first wall from short ranged target emissions (x-rays, ions and debris) but not neutrons. Various schemes have been proposed to establish and renew the liquid layer between shots including flow-guiding porous fabrics (e.g., Osiris, HIBALL), porous rigid structures (Prometheus) and thin film flows (KOYO). The thin liquid layer can be the tritium breeding material (e.g., flibe, PbLi, or Li) or another liquid metal such as Pb. TLWs use liquid jets injected by stationary or oscillating nozzles to form a neutronically thick layer (typically with an effective thickness of {approx}50 cm) of liquid between the target and first structural wall. In addition to absorbing short ranged emissions, the thick liquid layer degrades the neutron flux and energy reaching the first wall, typically by {approx}10 x x, so that steel walls can survive for the life of the plant ({approx}30-60 yrs). The thick liquid serves as the primary coolant and tritium breeding material (most recent designs use flibe, but the earliest concepts used Li). In essence, the TLW places the fusion blanket inside the first wall instead of behind the first wall.

  10. Electronmagnetic induction probe calibration for electrical conductivity measurements and moisture content determination of Hanford high level waste

    SciTech Connect (OSTI)

    Wittekind, W.D., Westinghouse Hanford

    1996-05-23T23:59:59.000Z

    Logic of converting EMI measured electrical conductivity to moisture with expected uncertainty. Estimates from present knowledge, assumptions, and measured data. Archie`s Law has been used since the 1940`s to relate electrical conductivity in porous media to liquid volume fraction. Measured electrical conductivity to moisture content uses: Porosity, Interstitial liquid electrical conductivity, Solid particle density,Interstitial liquid density, and interstitial liquid water content. The uncertainty of assumed values is calculated to determine the final moisture wt.% result uncertainty.

  11. Hand-held survey probe

    DOE Patents [OSTI]

    Young, Kevin L. (Idaho Falls, ID) [Idaho Falls, ID; Hungate, Kevin E. (Idaho Falls, ID) [Idaho Falls, ID

    2010-02-23T23:59:59.000Z

    A system for providing operational feedback to a user of a detection probe may include an optical sensor to generate data corresponding to a position of the detection probe with respect to a surface; a microprocessor to receive the data; a software medium having code to process the data with the microprocessor and pre-programmed parameters, and making a comparison of the data to the parameters; and an indicator device to indicate results of the comparison. A method of providing operational feedback to a user of a detection probe may include generating output data with an optical sensor corresponding to the relative position with respect to a surface; processing the output data, including comparing the output data to pre-programmed parameters; and indicating results of the comparison.

  12. Detection of supercooled liquid in mixedphase clouds using radar Doppler spectra

    E-Print Network [OSTI]

    Shupe, Matthew

    in the temperature range from 0 to -40°C, where both liquid and ice hydrometeor phases are sustainable of their hydrometeors (i.e., liquid or ice). Current cloud parameterizations that parti- tion water into liquid and ice 2010; published 1 October 2010. [1] Cloud phase identification from active remote sensors

  13. Water mist injection in oil shale retorting

    DOE Patents [OSTI]

    Galloway, T.R.; Lyczkowski, R.W.; Burnham, A.K.

    1980-07-30T23:59:59.000Z

    Water mist is utilized to control the maximum temperature in an oil shale retort during processing. A mist of water droplets is generated and entrained in the combustion supporting gas flowing into the retort in order to distribute the liquid water droplets throughout the retort. The water droplets are vaporized in the retort in order to provide an efficient coolant for temperature control.

  14. Water on Earth Source % of Supply

    E-Print Network [OSTI]

    Cochran-Stafira, D. Liane

    of heat. High Heat Capacity · Water absorbs or releases more heat than many substances for each degree is lowered. · spread salt on streets in winter to prevent ice formation. High Heat Capacity · Water vapor in our environment. · On earth, water is found as a liquid, as a solid (ice) or as a gas (water vapor

  15. Modeling Interfacial Liquid Layers in Environmental Ices SUPPLEMENTARY MATERIAL

    E-Print Network [OSTI]

    Meskhidze, Nicholas

    Symbol Quantity ice wf Fugacity of pure ice brine wf^ Fugacity of water in brine layer vap wf Fugacity of water in vapor space above ice wf Fugacity of pure liquid water wx Mole fraction of water in brine layer ice wH Enthalpy of ice at T, P 0,ice wH Enthalpy of ice at reference state brine wH Partial molar

  16. ADVANCED MATERIALS Membranes for Clean Water

    E-Print Network [OSTI]

    ADVANCED MATERIALS Membranes for Clean Water Objective This project provides measurement solutions that probe the surface and internal structure of polymer membranes used in water purification, and correlate that structure to the transport of water and other species through the membrane. Our methods are focused

  17. Examination system utilizing ionizing radiation and a flexible, miniature radiation detector probe

    DOE Patents [OSTI]

    Majewski, S.; Kross, B.J.; Zorn, C.J.; Majewski, L.A.

    1996-10-22T23:59:59.000Z

    An optimized examination system and method based on the Reverse Geometry X-Ray{trademark} (RGX{trademark}) radiography technique are presented. The examination system comprises a radiation source, at least one flexible, miniature radiation detector probe positioned in appropriate proximity to the object to be examined and to the radiation source with the object located between the source and the probe, a photodetector device attachable to an end of the miniature radiation probe, and a control unit integrated with a display device connected to the photodetector device. The miniature radiation detector probe comprises a scintillation element, a flexible light guide having a first end optically coupled to the scintillation element and having a second end attachable to the photodetector device, and an opaque, environmentally-resistant sheath surrounding the flexible light guide. The probe may be portable and insertable, or may be fixed in place within the object to be examined. An enclosed, flexible, liquid light guide is also presented, which comprises a thin-walled flexible tube, a liquid, preferably mineral oil, contained within the tube, a scintillation element located at a first end of the tube, closures located at both ends of the tube, and an opaque, environmentally-resistant sheath surrounding the flexible tube. The examination system and method have applications in non-destructive material testing for voids, cracks, and corrosion, and may be used in areas containing hazardous materials. In addition, the system and method have applications for medical and dental imaging. 5 figs.

  18. Examination system utilizing ionizing radiation and a flexible, miniature radiation detector probe

    DOE Patents [OSTI]

    Majewski, Stanislaw (Grafton, VA); Kross, Brian J. (Yorktown, VA); Zorn, Carl J. (Yorktown, VA); Majewski, Lukasz A. (Grafton, VA)

    1996-01-01T23:59:59.000Z

    An optimized examination system and method based on the Reverse Geometry X-Ray.RTM. (RGX.RTM.) radiography technique are presented. The examination system comprises a radiation source, at least one flexible, miniature radiation detector probe positioned in appropriate proximity to the object to be examined and to the radiation source with the object located between the source and the probe, a photodetector device attachable to an end of the miniature radiation probe, and a control unit integrated with a display device connected to the photodetector device. The miniature radiation detector probe comprises a scintillation element, a flexible light guide having a first end optically coupled to the scintillation element and having a second end attachable to the photodetector device, and an opaque, environmentally-resistant sheath surrounding the flexible light guide. The probe may be portable and insertable, or may be fixed in place within the object to be examined. An enclosed, flexible, liquid light guide is also presented, which comprises a thin-walled flexible tube, a liquid, preferably mineral oil, contained within the tube, a scintillation element located at a first end of the tube, closures located at both ends of the tube, and an opaque, environmentally-resistant sheath surrounding the flexible tube. The examination system and method have applications in non-destructive material testing for voids, cracks, and corrosion, and may be used in areas containing hazardous materials. In addition, the system and method have applications for medical and dental imaging.

  19. Kinetics of complex plasma with liquid droplets

    SciTech Connect (OSTI)

    Misra, Shikha; Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India); Mishra, S. K. [Institute for Plasma Research (IPR), Gandhinagar 382428 (India)] [Institute for Plasma Research (IPR), Gandhinagar 382428 (India)

    2013-12-15T23:59:59.000Z

    This paper provides a theoretical basis for the reduction of electron density by spray of water (or other liquids) in hot plasma. This phenomenon has been observed in a hypersonic flight experiment for relief of radio black out, caused by high ionization in the plasma sheath of a hypersonic vehicle, re-entering the atmosphere. The analysis incorporates a rather little known phenomenon for de-charging of the droplets, viz., evaporation of ions from the surface and includes the charge balance on the droplets and number cum energy balance of electrons, ions, and neutral molecules; the energy balance of the evaporating droplets has also been taken into account. The analysis has been applied to a realistic situation and the transient variations of the charge and radius of water droplets, and other plasma parameters have been obtained and discussed. The analysis through made in the context of water droplets is applicable to all liquids.

  20. (Ionization in liquids)

    SciTech Connect (OSTI)

    Not Available

    1991-01-01T23:59:59.000Z

    This document describes charge transport following ionization of model liquids and how this process may be important in carcinogenesis. 15 refs., 2 figs., 4 tabs. (MHB)

  1. Ultrasonic liquid level detector

    DOE Patents [OSTI]

    Kotz, Dennis M. (North Augusta, SC); Hinz, William R. (Augusta, GA)

    2010-09-28T23:59:59.000Z

    An ultrasonic liquid level detector for use within a shielded container, the detector being tubular in shape with a chamber at its lower end into which liquid from in the container may enter and exit, the chamber having an ultrasonic transmitter and receiver in its top wall and a reflector plate or target as its bottom wall whereby when liquid fills the chamber a complete medium is then present through which an ultrasonic wave may be transmitted and reflected from the target thus signaling that the liquid is at chamber level.

  2. Liquid Crystal Optofluidics

    SciTech Connect (OSTI)

    Vasdekis, Andreas E.; Cuennet, J. G.; Psaltis, D.

    2012-10-11T23:59:59.000Z

    By employing anisotropic fluids and namely liquid crystals, fluid flow becomes an additional degree of freedom in designing optofluidic devices. In this paper, we demonstrate optofluidic liquid crystal devices based on the direct flow of nematic liquid crystals in microfluidic channels. Contrary to previous reports, in the present embodiment we employ the effective phase delay acquired by light travelling through flowing liquid crystal, without analysing the polarisation state of the transmitted light. With this method, we demonstrate the variation in the diffraction pattern of an array of microfluidic channels acting as a grating. We also discuss our recent activities in integrating mechanical oscillators for on-chip peristaltic pumping.

  3. Nuclear Physics with Electroweak Probes

    E-Print Network [OSTI]

    Omar Benhar

    2009-02-26T23:59:59.000Z

    In recent years, the italian theoretical Nuclear Physics community has played a leading role in the development of a unified approach, allowing for a consistent and fully quantitative description of the nuclear response to electromagnetic and weak probes. In this paper I review the main achievements in both fields, point out some of the open problems, and outline the most promising prospects.

  4. Unloading using auger tool and foam and experimental identification of liquid loading of low rate natural gas wells

    E-Print Network [OSTI]

    Bose, Rana

    2007-09-17T23:59:59.000Z

    flow rate versus liquid flow rate at 30 psi 68 8.1b Air flow rate versus liquid flow rate at 22 psi 68 8.1c Air flow rate versus liquid flow rate at 15 psi 69 8.2a Liquid holdup through the tubing at 30 psi... with and without Auger (air-water) and with and without Auger (air-foam)70 8.2b Liquid holdup through the tubing at 22 psi with and without Auger(air-water) and with and without Auger (air-foam) 71 8.2c Liquid...

  5. The Videofil probe, a novel instrument to extend the coke oven service life

    SciTech Connect (OSTI)

    Gaillet, J.P.; Isler, D. [Centre de Pyrolyse de Marienau, Forbach (France)

    1997-12-31T23:59:59.000Z

    To prolong the service life of coke oven batteries, the Centre de Pyrolyse de Marienau developed the Videofil probe, a novel instrument to conduct diagnoses and to help repair operations of coke ovens. The Videofil probe is a flexible non-water-cooled endoscope which is used to locate flue wall damage and estimate its importance, to define the oven zones to repair and guide the repair work and to control the quality of the repair work and its durability.

  6. Liquid level, void fraction, and superheated steam sensor for nuclear-reactor cores. [PWR; BWR

    DOE Patents [OSTI]

    Tokarz, R.D.

    1981-10-27T23:59:59.000Z

    This disclosure relates to an apparatus for monitoring the presence of coolant in liquid or mixed liquid and vapor, and superheated gaseous phases at one or more locations within an operating nuclear reactor core, such as pressurized water reactor or a boiling water reactor.

  7. Metal-air cell comprising an electrolyte with a room temperature ionic liquid and hygroscopic additive

    DOE Patents [OSTI]

    Friesen, Cody A.; Krishnan, Ramkumar; Tang, Toni; Wolfe, Derek

    2014-08-19T23:59:59.000Z

    An electrochemical cell comprising an electrolyte comprising water and a hydrophobic ionic liquid comprising positive ions and negative ions. The electrochemical cell also includes an air electrode configured to absorb and reduce oxygen. A hydrophilic or hygroscopic additive modulates the hydrophobicity of the ionic liquid to maintain a concentration of the water in the electrolyte is between 0.001 mol % and 25 mol %.

  8. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D; Sulchek, Todd A; Feigin, Stuart C

    2013-04-30T23:59:59.000Z

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  9. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D; Sulchek, Todd A; Feigin, Stuart C

    2014-04-29T23:59:59.000Z

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  10. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D. (Reno, NV); Sulchek, Todd A. (Oakland, CA); Feigin, Stuart C. (Reno, NV)

    2012-07-10T23:59:59.000Z

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  11. Cantilevered probe detector with piezoelectric element

    DOE Patents [OSTI]

    Adams, Jesse D.; Sulchek, Todd A.; Feigin, Stuart C.

    2010-04-06T23:59:59.000Z

    A disclosed chemical detection system for detecting a target material, such as an explosive material, can include a cantilevered probe, a probe heater coupled to the cantilevered probe, and a piezoelectric element disposed on the cantilevered probe. The piezoelectric element can be configured as a detector and/or an actuator. Detection can include, for example, detecting a movement of the cantilevered probe or a property of the cantilevered probe. The movement or a change in the property of the cantilevered probe can occur, for example, by adsorption of the target material, desorption of the target material, reaction of the target material and/or phase change of the target material. Examples of detectable movements and properties include temperature shifts, impedance shifts, and resonant frequency shifts of the cantilevered probe. The overall chemical detection system can be incorporated, for example, into a handheld explosive material detection system.

  12. Handheld force-controlled ultrasound probe

    E-Print Network [OSTI]

    Gilbertson, Matthew Wright

    2010-01-01T23:59:59.000Z

    An hand-held force controlled ultrasound probe has been developed. The controller maintains a prescribed contact force between the probe and a patient's body. The device will enhance the diagnostic capability of free-hand ...

  13. Holographic non-Fermi liquid in a background magnetic field

    SciTech Connect (OSTI)

    Basu, Pallab; He Jianyang; Mukherjee, Anindya; Shieh, Hsien-Hang [Department of Physics and Astronomy, University of British Columbia, 6224 Agricultural Road, Vancouver, B.C. V6T 1Z1 (Canada)

    2010-08-15T23:59:59.000Z

    We study the effects of a nonzero magnetic field on a class of 2+1 dimensional non-Fermi liquids, recently found in [Hong Liu, John McGreevy, and David Vegh, arXiv:0903.2477.] by considering properties of a Fermionic probe in an extremal AdS{sup 4} black hole background. Introducing a similar fermionic probe in a dyonic AdS{sup 4} black hole geometry, we find that the effect of a magnetic field could be incorporated in a rescaling of the probe fermion's charge. From this simple fact, we observe interesting effects like gradual disappearance of the Fermi surface and quasiparticle peaks at large magnetic fields and changes in other properties of the system. We also find Landau level like structures and oscillatory phenomena similar to the de-Haas-van Alphen effect.

  14. Electron probe microanalysis in geoscience: a tutorial

    SciTech Connect (OSTI)

    Gooley, R.

    1981-01-01T23:59:59.000Z

    A tutorial on the history, theory and use of electron probe microanalysis in the geosciences is presented. (ACR)

  15. Probing Nanoscale Surface Enhanced Raman Scattering Fluctuation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale Surface Enhanced Raman Scattering Fluctuation Dynamics using Correalted AFM and Confocal Ultramicroscopy. Probing Nanoscale Surface Enhanced Raman Scattering Fluctuation...

  16. Probing Exotic Physics With Supernova Neutrinos

    SciTech Connect (OSTI)

    Kelso, Chris; Hooper, Dan

    2010-09-01T23:59:59.000Z

    Future galactic supernovae will provide an extremely long baseline for studying the properties and interactions of neutrinos. In this paper, we discuss the possibility of using such an event to constrain (or discover) the effects of exotic physics in scenarios that are not currently constrained and are not accessible with reactor or solar neutrino experiments. In particular, we focus on the cases of neutrino decay and quantum decoherence. We calculate the expected signal from a core-collapse supernova in both current and future water Cerenkov, scintillating, and liquid argon detectors, and find that such observations will be capable of distinguishing between many of these scenarios. Additionally, future detectors will be capable of making strong, model-independent conclusions by examining events associated with a galactic supernova's neutronization burst.

  17. Synthesis of ionic liquids

    DOE Patents [OSTI]

    Dai, Sheng [Knoxville, TN; Luo, Huimin [Knoxville, TN

    2008-09-09T23:59:59.000Z

    Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic liqand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

  18. Synthesis of ionic liquids

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Luo, Huimin (Knoxville, TN)

    2011-11-01T23:59:59.000Z

    Ionic compounds which are liquids at room temperature are formed by the method of mixing a neutral organic ligand with the salt of a metal cation and its conjugate anion. The liquids are hydrophobic, conductive and stable and have uses as solvents and in electrochemical devices.

  19. Liquid heat capacity lasers

    DOE Patents [OSTI]

    Comaskey, Brian J. (Walnut Creek, CA); Scheibner, Karl F. (Tracy, CA); Ault, Earl R. (Livermore, CA)

    2007-05-01T23:59:59.000Z

    The heat capacity laser concept is extended to systems in which the heat capacity lasing media is a liquid. The laser active liquid is circulated from a reservoir (where the bulk of the media and hence waste heat resides) through a channel so configured for both optical pumping of the media for gain and for light amplification from the resulting gain.

  20. Automated position control of a surface array relative to a liquid microjunction surface sampler

    DOE Patents [OSTI]

    Van Berkel, Gary J. (Clinton, TN); Kertesz, Vilmos (Knoxville, TN); Ford, Michael James (Little Rock, AR)

    2007-11-13T23:59:59.000Z

    A system and method utilizes an image analysis approach for controlling the probe-to-surface distance of a liquid junction-based surface sampling system for use with mass spectrometric detection. Such an approach enables a hands-free formation of the liquid microjunction used to sample solution composition from the surface and for re-optimization, as necessary, of the microjunction thickness during a surface scan to achieve a fully automated surface sampling system.

  1. Water Resources Water Quality and Water Treatment

    E-Print Network [OSTI]

    Sohoni, Milind

    Water Resources TD 603 Lecture 1: Water Quality and Water Treatment CTARA Indian Institute of Technology, Bombay 2nd November, 2011 #12;OVERVIEW Water Quality WATER TREATMENT PLANTS WATER TREATMENT PLANTS WATER TREATMENT PLANTS WATER TRE OVERVIEW OF THE LECTURE 1. Water Distribution Schemes Hand Pump

  2. Optical probe with reference fiber

    DOE Patents [OSTI]

    Da Silva, Luiz B. (Danville, CA); Chase, Charles L. (Dublin, CA)

    2006-03-14T23:59:59.000Z

    A system for characterizing tissue includes the steps of generating an emission signal, generating a reference signal, directing the emission signal to and from the tissue, directing the reference signal in a predetermined manner relative to the emission signal, and using the reference signal to compensate the emission signal. In one embodiment compensation is provided for fluctuations in light delivery to the tip of the probe due to cable motion.

  3. Liquid sampling system

    DOE Patents [OSTI]

    Larson, L.L.

    1984-09-17T23:59:59.000Z

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed. 5 figs.

  4. Liquid sampling system

    DOE Patents [OSTI]

    Larson, Loren L. (Idaho Falls, ID)

    1987-01-01T23:59:59.000Z

    A conduit extends from a reservoir through a sampling station and back to the reservoir in a closed loop. A jet ejector in the conduit establishes suction for withdrawing liquid from the reservoir. The conduit has a self-healing septum therein upstream of the jet ejector for receiving one end of a double-ended cannula, the other end of which is received in a serum bottle for sample collection. Gas is introduced into the conduit at a gas bleed between the sample collection bottle and the reservoir. The jet ejector evacuates gas from the conduit and the bottle and aspirates a column of liquid from the reservoir at a high rate. When the withdrawn liquid reaches the jet ejector the rate of flow therethrough reduces substantially and the gas bleed increases the pressure in the conduit for driving liquid into the sample bottle, the gas bleed forming a column of gas behind the withdrawn liquid column and interrupting the withdrawal of liquid from the reservoir. In the case of hazardous and toxic liquids, the sample bottle and the jet ejector may be isolated from the reservoir and may be further isolated from a control station containing remote manipulation means for the sample bottle and control valves for the jet ejector and gas bleed.

  5. Atom probe field ion microscopy and related topics: A bibliography 1989

    SciTech Connect (OSTI)

    Miller, M.K.; Hawkins, A.R.; Russell, K.F.

    1990-12-01T23:59:59.000Z

    This bibliography includes references related to the following topics: atom probe field ion microscopy (APFIM), field ion spectroscopy (FIM), field emission microscopy (FEM), liquid metal ion sources (LMIS), scanning tunneling microscopy (STM), and theory. Technique-orientated studies and applications are included. This bibliography covers the period 1989. The references contained in this document were compiled from a variety of sources including computer searches and personal lists of publications.

  6. Electrically Deformable Liquid Marbles

    E-Print Network [OSTI]

    Edward Bormashenko; Roman Pogreb; Tamir Stein; Gene Whyman; Marcelo Schiffer; Doron Aurbach

    2011-02-17T23:59:59.000Z

    Liquid marbles, which are droplets coated with a hydrophobic powder, were exposed to a uniform electric field. It was established that a threshold value of the electric field, 15 cgse, should be surmounted for deformation of liquid marbles. The shape of the marbles was described as a prolate spheroid. The semi-quantitative theory describing deformation of liquid marbles in a uniform electric field is presented. The scaling law relating the radius of the contact area of the marble to the applied electric field shows a satisfactory agreement with the experimental data.

  7. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

    1992-01-14T23:59:59.000Z

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

  8. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

    1992-01-01T23:59:59.000Z

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

  9. Ionic liquids and electrochemistry: from proteins to electrochromic devices.

    SciTech Connect (OSTI)

    Keizer, T. S. (Timothy S.); McCleskey, T. M. (Thomas Mark); Baker, G. A. (Gary A.); Burrell, A. K. (Anthony K.); Baker, S. N. (Sheila N.); Warner, B. P. (Benjamin P.); Hall, S. B. (Simon B.)

    2004-01-01T23:59:59.000Z

    We will report on a wide range of activities within the chemistry division at Los Alamos National Laboratory. Results on basic and applied research involving electrochemistry will be discussed. Topics will include electrochemistry of proteins, sensors based on electrochemical signals, temperature sensors, electrochromic devices in ionic liquids and the characterization of organic cation radicals. We have recently developed several applications in ionic liquids that include electrochromic devices, temperature sensors and chemical sensors. The electrochromic windows are being marketed as selftinting automotive mirrors. The ionic liquid based temperature sensor is stable and accurate over a wide range and has the potential to provide high-resolution temperature imaging. Chemical sensors have been developed that use electrochemistry to detect low levels of potential chemical agents in air. We have also studied the basic chemistry of charge transfer complexes and proteins in ionic liquids. Charge transfer complexes display unique behavior in ionic liquid compare to traditional solvents. Proteins can be solubilized at high levels that make it possible to probe electrochemistry in the proper ionic liquid.

  10. Hydrophilization of Liquid Surfaces by Plasma Treatment

    E-Print Network [OSTI]

    Victor Multanen; Gilad Chaniel; Roman Grynyov; Ron Yosef Loew; Naor Siany; Edward Bormashenko

    2014-09-01T23:59:59.000Z

    The impact of the cold radiofrequency air plasma on the surface properties of silicone oils (polydimethylsiloxane) was studied. Silicone oils of various molecular masses were markedly hydrophilized by the cold air plasma treatment. A pronounced decrease of the apparent water contact angles was observed after plasma treatment. A general theoretical approach to the calculation of apparent contact angles is proposed. The treated liquid surfaces demonstrated hydrophobic recovery. The characteristic time of the hydrophobic recovery grew with the molecular mass of the silicone oil.

  11. Noble Travails: Noble Liquid Dark Matter Detectors

    E-Print Network [OSTI]

    Golwala, Sunil

    , or water, 0.1x flux per 10 cm Cosmic Ray Muons generate high energy neutrons 50 MeV - 3 GeV which are toughGaitskell Noble Travails: Noble Liquid Dark Matter Detectors Rick Gaitskell Particle Astrophysics://particleastro.brown.edu/ http://gaitskell.brown.edu v1 #12;LUX Dark Matter Collaboration 2007 v01_7mm Dark Matter Theory

  12. Probes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible forPortsmouth/Paducah47,193.70 Hg Mercury 35 Br Bromine 43 cPoints ofJanoschek

  13. A route to explain water anomalies from results on an aqueous solution of salt

    E-Print Network [OSTI]

    D. Corradini; M. Rovere; P. Gallo

    2010-03-26T23:59:59.000Z

    In this paper we investigate the possibility to detect the hypothesized liquid-liquid critical point of water in supercooled aqueous solutions of salts. Molecular dynamics computer simulations are conducted on bulk TIP4P water and on an aqueous solution of sodium chloride in TIP4P water, with concentration c = 0.67 mol/kg. The liquid-liquid critical point is found both in the bulk and in the solution. Its position in the thermodynamic plane shifts to higher temperature and lower pressure for the solution. Comparison with available experimental data allowed us to produce the phase diagrams of both bulk water and the aqueous solution as measurable in experiments. Given the position of the liquid-liquid critical point in the solution as obtained from our simulations, the experimental determination of the hypothesized liquid-liquid critical point of water in aqueous solutions of salts appears possible.

  14. Liquidity facilities and signaling

    E-Print Network [OSTI]

    Arregui, Nicols

    2010-01-01T23:59:59.000Z

    This dissertation studies the role of signaling concerns in discouraging access to liquidity facilities like the IMF contingent credit lines (CCL) and the Discount Window (DW). In Chapter 1, I analyze the introduction of ...

  15. Plasmas in Multiphase Media: Bubble Enhanced Discharges in Liquids and Plasma/Liquid Phase Boundaries

    SciTech Connect (OSTI)

    Kushner, Mark Jay [University of Michigan] [University of Michigan

    2014-07-10T23:59:59.000Z

    In this research project, the interaction of atmospheric pressure plasmas with multi-phase media was computationally investigated. Multi-phase media includes liquids, particles, complex materials and porous surfaces. Although this investigation addressed fundamental plasma transport and chemical processes, the outcomes directly and beneficially affected applications including biotechnology, medicine and environmental remediation (e.g., water purification). During this project, we made advances in our understanding of the interaction of atmospheric pressure plasmas in the form of dielectric barrier discharges and plasma jets with organic materials and liquids. We also made advances in our ability to use computer modeling to represent these complex processes. We determined the method that atmospheric pressure plasmas flow along solid and liquid surfaces, and through endoscopic like tubes, deliver optical and high energy ion activation energy to organic and liquid surfaces, and produce reactivity in thin liquid layers, as might cover a wound. We determined the mechanisms whereby plasmas can deliver activation energy to the inside of liquids by sustaining plasmas in bubbles. These findings are important to the advancement of new technology areas such as plasma medicine

  16. Molecular Structure of Water at Gold Electrodes Revealed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecular Structure of Water at Gold Electrodes Revealed Print The structure of liquid water has been intensely studied, but until recently, it has not been clear what happens to...

  17. Process for exchanging hydrogen isotopes between gaseous hydrogen and water

    DOE Patents [OSTI]

    Hindin, Saul G. (Mendham, NJ); Roberts, George W. (Westfield, NJ)

    1980-08-12T23:59:59.000Z

    A process for exchanging isotopes of hydrogen, particularly tritium, between gaseous hydrogen and water is provided whereby gaseous hydrogen depeleted in tritium and liquid or gaseous water containing tritium are reacted in the presence of a metallic catalyst.

  18. Apparatus for imaging liquid and dielectric materials with scanning polarization force microscopy

    DOE Patents [OSTI]

    Hu, Jun (Berkeley, CA); Ogletree, D. Frank (El Cerrito, CA); Salmeron, Miguel (El Cerrito, CA); Xiao, Xudong (Kowloon, CN)

    1998-01-01T23:59:59.000Z

    The invention images dielectric polarization forces on surfaces induced by a charged scanning force microscope (SFM) probe tip. On insulators, the major contribution to the surface polarizability at low frequencies is from surface ions. The mobility of these ions depends strongly on the humidity. Using the inventive SFM, liquid films, droplets, and other weakly adsorbed materials have been imaged.

  19. Method for imaging liquid and dielectric materials with scanning polarization force microscopy

    DOE Patents [OSTI]

    Hu, Jun (Berkeley, CA); Ogletree, D. Frank (El Cerrito, CA); Salmeron, Miguel (El Cerrito, CA); Xiao, Xudong (Kowloon, CN)

    1999-01-01T23:59:59.000Z

    The invention images dielectric polarization forces on surfaces induced by a charged scanning force microscope (SFM) probe tip. On insulators, the major contribution to the surface polarizability at low frequencies is from surface ions. The mobility of these ions depends strongly on the humidity. Using the inventive SFM, liquid films, droplets, and other weakly adsorbed materials have been imaged.

  20. Liquid crystalline composites containing phyllosilicates

    DOE Patents [OSTI]

    Chaiko, David J.

    2004-07-13T23:59:59.000Z

    The present invention provides phyllosilicate-polymer compositions which are useful as liquid crystalline composites. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while at the same time be transparent. Because of the ordering of the particles liquid crystalline composite, liquid crystalline composites are particularly useful as barriers to gas transport.

  1. Liquid mixing device

    SciTech Connect (OSTI)

    O'Leary, R. P.

    1985-08-06T23:59:59.000Z

    A mixing device for mixing at least two liquids to produce a homogenous mixture. The device includes an elongated chamber in which a vertically oriented elongated mixing cavity is located. The cavity is sealed at its lower end and it is open at its upper end and in communication with the interior of the chamber. An elongated conduit extends the length of the cavity and is adapted to receive liquids to be mixed. The conduit includes a plurality of ports located at longitudinally spaced positions therealong and which ports are directed in different directions. The ports create plural streams of liquid which interact and mix with one another within the cavity. The mixed liquids overflow the cavity and out its top end into the chamber 24. The chamber 24 includes an outlet from which the mixed liquids are withdrawn. In accordance with the preferred embodiment gas eductor means are provided in the inlet to the conduit to introduce gas bubbles within the cavity. Gas vent means are also provided in the device to vent any introduced gases from the device so that only the mixed liquids flow out the outlet.

  2. Department of Energy and Mineral Engineering Spring 2013 Preliminary Plant Design For Bitumen Separation Using Ionic Liquid

    E-Print Network [OSTI]

    Demirel, Melik C.

    For Bitumen Separation Using Ionic Liquid Overview IL Fuels LLC invented a novel way to separate bitumen from of producing 5,000 barrels of bitumen per day while maximizing the recovery of ionic liquid and water of bitumen/day Maintain a maximum of 0.2% loss of ionic liquids to the cleaned sands Improve overall

  3. Using liquid desiccant as a regenerable filter for capturing and deactivating contaminants

    DOE Patents [OSTI]

    Slayzak, Steven J. (Denver, CO); Anderson, Ren S. (Broomfield, CO); Judkoff, Ronald D. (Golden, CO); Blake, Daniel M. (Golden, CO); Vinzant, Todd B. (Golden, CO); Ryan, Joseph P. (Golden, CO)

    2007-12-11T23:59:59.000Z

    A method, and systems for implementing such method, for purifying and conditioning air of weaponized contaminants. The method includes wetting a filter packing media with a salt-based liquid desiccant, such as water with a high concentration of lithium chloride. Air is passed through the wetted filter packing media and the contaminants in are captured with the liquid desiccant while the liquid desiccant dehumidifies the air. The captured contaminants are then deactivated in the liquid desiccant, which may include heating the liquid desiccant. The liquid desiccant is regenerated by applying heat to the liquid desiccant and then removing moisture. The method includes repeating the wetting with the regenerated liquid desiccant which provides a regenerable filtering process that captures and deactivates contaminants on an ongoing basis while also conditioning the air. The method may include filtration effectiveness enhancement by electrostatic or inertial means.

  4. X-rays at Solid-Liquid Surfaces

    SciTech Connect (OSTI)

    Dosch, Helmut (Max Planck Institute for Metals Research) [Max Planck Institute for Metals Research

    2007-05-02T23:59:59.000Z

    Solid-liquid interfaces play an important role in many areas of current and future technologies, and in our biosphere. They play a key role in the development of nanofluidics and nanotribology, which sensitively depend on our knowledge of the microscopic structures and phenomena at the solid-liquid interface. The detailed understanding of how a fluid meets a wall is also a theoretical challenge. In particular, the phenomena at repulsive walls are of interest, since they affect many different phenomena, such as water-repellent surfaces or the role of the hydrophobic interaction in protein folding. Recent x-ray reflectivity studies of various solid-liquid interfaces have disclosed rather intriguiing phenomena, which will be discussed in this lecture: premelting of ice in contact with silica; liquid Pb in contact with Si; water in contact with hydrophobic surfaces. These experiments, carried out with high-energy x-ray microbeams, reveal detailed insight into the liquid density profile closest to the wall. A detailed insight into atomistic phenomena at solid-liquid interfaces is also a prerequisite in the microscopic control of electrochemical reactions at interfaces. Recent x-ray studies show the enormous future potential of such non-destructive analytical tools for the in situ observation of (electro-)chemical surface reactions. This lecture will review recent x-ray experiments on solid-liquid interfaces.

  5. Entangled quantum probes for dynamical environmental noise

    E-Print Network [OSTI]

    Matteo A. C. Rossi; Matteo G. A. Paris

    2015-03-11T23:59:59.000Z

    We address the use of entangled qubits as quantum probes to characterize the dynamical noise induced by complex environments. In particular, we show that entangled probes improve estimation of the correlation time for a broad class of environmental noises compared to any sequential strategy involving single qubit preparation. The effect is present when the noise is faster than a threshold value, a regime which may always be achieved by tuning the coupling between the quantum probe and the environment inducing the noise. Our scheme exploits time-dependent sensitivity of quantum systems to decoherence and does not require dynamical control on the probes. We derive the optimal interaction time and the optimal probe preparation, showing that it corresponds to multiqubit GHZ states when entanglement is useful. We also show robustness of the scheme against depolarization or dephasing of the probe, and discuss simple measurements approaching optimal precision.

  6. INNOVATIVE EDDY CURRENT PROBE FOR MICRO DEFECTS

    SciTech Connect (OSTI)

    Santos, Telmo G.; Vilaca, Pedro; Quintino, Luisa [IDMEC, Av. Rovisco Pais, 1049-001 Lisbon (Portugal); Santos, Jorge dos [GKSS, Max-Planck-Street 1, D-21502 Geesthacht (Germany); Rosado, Luis [IST, UTL, Av. Rovisco Pais, 1049-001 Lisbon (Portugal)

    2010-02-22T23:59:59.000Z

    This paper reports the development of an innovative eddy current (EC) probe, and its application to micro-defects on the root of the Friction Stir Welding (FSW). The new EC probe presents innovative concept issues, allowing 3D induced current in the material, and a lift-off independence. Validation experiments were performed on aluminium alloys processed by FSW. The results clearly show that the new EC probe is able to detect and sizing surface defects about 60 microns depth.

  7. Yosemite Waters Vehicle Evaluation Report: Final Results

    SciTech Connect (OSTI)

    Eudy, L.; Barnitt, R.; Alleman, T. L.

    2005-08-01T23:59:59.000Z

    Document details the evaluation of Fischer-Tropsch diesel, a gas-to-liquid fuel, in medium-duty delivery vehicles at Yosemite Waters. The study was conducted by NREL at the company's Fullerton, California, bottling headquarters.

  8. Disinfecting Water Wells by Shock Chlorination

    E-Print Network [OSTI]

    Dozier, Monty; McFarland, Mark L.

    2005-09-30T23:59:59.000Z

    If your well has been flooded, it must be shock chlorinated before it can be used as a source of drinking water. This publication explains how to disinfect a well using either dry chlorine or liquid household bleach....

  9. PROBING DENSE NUCLEAR MATTER VIA NUCLEAR COLLISIONS

    E-Print Network [OSTI]

    Stocker, H.

    2012-01-01T23:59:59.000Z

    University of California. LBL-12095 Probing Dense NuclearMatter Nuclear Collisions* v~a H. Stocker, M.Gyulassy and J. Boguta Nuclear Science Division Lawrence

  10. Sandia National Laboratories: scanning probe microscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    focus on stainless steels. Dr. An is an internationally recognized expert on scanning probe microscopy, such as atomic force microscopy and scanning ... Last Updated:...

  11. Optical pumpterahertz probe spectroscopy of dyes in solutions: Probing the dynamics of liquid solvent or solid precipitate?

    E-Print Network [OSTI]

    Ku?el, Petr

    dynamics simulations to investigate ultrafast dynamics following electronic excitation of Coumarin 153 and dynamics, preferably at a molecular level of reso- lution. In particular, solvent relaxation following body of time-resolved spectro- scopic studies, as well as molecular dynamics MD simula- tions have been

  12. Proceedings of "Optical Probes of Dynamics in Complex Environments"

    SciTech Connect (OSTI)

    Sension, R; Tokmakoff, A

    2008-04-01T23:59:59.000Z

    This document contains the proceedings from the symposium on Optical Probes of Dynamics in Complex Environments, which organized as part of the 235th National Meeting of the American Chemical Society in New Orleans, LA from April 6 to 10, 2008. The study of molecular dynamics in chemical reaction and biological processes using time ???????????????resolved spectroscopy plays an important role in our understanding of energy conversion, storage, and utilization problems. Fundamental studies of chemical reactivity, molecular rearrangements, and charge transport are broadly supported by the DOE Office of Science because of their role in the development of alternative energy sources, the understanding of biological energy conversion processes, the efficient utilization of existing energy resources, and the mitigation of reactive intermediates in radiation chemistry. In addition, time resolved spectroscopy is central to all of DOEs grand challenges for fundamental energy science. This symposium brought together leaders in the field of ultrafast spectroscopy, including experimentalists, theoretical chemists, and simulators, to discuss the most recent scientific and technological advances. DOE support for this conference was used to help young US and international scientists travel to the meeting. The latest technology in ultrafast infrared, optical, and xray spectroscopy and the scientific advances that these methods enable were covered. Particular emphasis was placed on new experimental methods used to probe molecular dynamics in liquids, solids, interfaces, nanostructured materials, and biomolecules.

  13. Liquid-liquid interfacial nanoparticle assemblies

    DOE Patents [OSTI]

    Emrick, Todd S. (South Deerfield, MA); Russell, Thomas P. (Amherst, MA); Dinsmore, Anthony (Amherst, MA); Skaff, Habib (Amherst, MA); Lin, Yao (Amherst, MA)

    2008-12-30T23:59:59.000Z

    Self-assembly of nanoparticles at the interface between two fluids, and methods to control such self-assembly process, e.g., the surface density of particles assembling at the interface; to utilize the assembled nanoparticles and their ligands in fabrication of capsules, where the elastic properties of the capsules can be varied from soft to tough; to develop capsules with well-defined porosities for ultimate use as delivery systems; and to develop chemistries whereby multiple ligands or ligands with multiple functionalities can be attached to the nanoparticles to promote the interfacial segregation and assembly of the nanoparticles. Certain embodiments use cadmium selenide (CdSe) nanoparticles, since the photoluminescence of the particles provides a convenient means by which the spatial location and organization of the particles can be probed. However, the systems and methodologies presented here are general and can, with suitable modification of the chemistries, be adapted to any type of nanoparticle.

  14. Used powdex resin for liquid waste processing

    SciTech Connect (OSTI)

    Pearson, C.J.; Bramblett, J.W.

    1995-05-01T23:59:59.000Z

    Powdex resin has traditionally been used on the Secondary side for condensate polishing. The resins on these polishers are backwashed periodically based on chemical breakthrough or high differential pressure. Upon the backwash, the ion exchange capacity on the powdex resin is not completely exhausted. In the past, this partially used powdex resin was sluiced to a liner and treated as waste for disposal. In an effort to reduce radioactivity being released from segregated, high chemical concentration wastes, the idea of trying used powdex resin was initiated. In 1992, Duke Power Company began processing problem liquid waste streams with used Secondary powdex and subsequent decanting of the waste water for release. the results have shown significant reductions in the activity of this water. This paper will detail the history, method, and the results of using Secondary powdex for liquid radwaste processing. It will also describe the benefits, such as: (1) Processing waste streams not suitable for bead resin demineralizers. (2) Ability to process large volumes of waste water in a short period of time. (3) Recycling media thought to be useless. (4) > 80% Reduction in activity of water processed. (5) Overall curies reduction. (6) Improved bead demineralizer performance.

  15. MERIT Pump/Probe Data OutlineOutline

    E-Print Network [OSTI]

    McDonald, Kirk

    MERIT Pump/Probe Data Analysis OutlineOutline The pump/probe program Particle detector response correction Pump/probe analysis results NFMCC Collaboration Meeting , LBNL, January 26, 2009 Ilias Efthymiopoulos - CERN #12;The pump/probe program #12;The pump/probe program Use of the CERN PS flexibility

  16. VOC and HAP recovery using ionic liquids

    SciTech Connect (OSTI)

    Michael R. Milota : Kaichang Li

    2007-05-29T23:59:59.000Z

    During the manufacture of wood composites, paper, and to a lesser extent, lumber, large amounts of volatile organic compounds (VOCs) such as terpenes, formaldehyde, and methanol are emitted to air. Some of these compounds are hazardous air pollutants (HAPs). The air pollutants produced in the forest products industry are difficult to manage because the concentrations are very low. Presently, regenerative thermal oxidizers (RTOs and RCOs) are commonly used for the destruction of VOCs and HAPs. RTOs consume large amounts of natural gas to heat air and moisture. The combustion of natural gas generates increased CO2 and NOx, which have negative implications for global warming and air quality. The aforementioned problems are addressed by an absorption system containing a room-temperature ionic liquid (RTIL) as an absorbent. RTILs are salts, but are in liquid states at room temperature. RTILs, an emerging technology, are receiving much attention as replacements for organic solvents in industrial processes with significant cost and environmental benefits. Some of these processes include organic synthesis, extraction, and metal deposition. RTILs would be excellent absorbents for exhausts from wood products facilities because of their unique properties: no measurable vapor pressure, high solubility of wide range of organic compounds, thermal stability to 200C (almost 400F), and immisciblity with water. Room temperature ionic liquids were tested as possible absorbents. Four were imidizolium-based and were eight phosphonium-based. The imidizolium-based ionic liquids proved to be unstable at the conditions tested and in the presence of water. The phosphonium-based ionic liquids were stable. Most were good absorbents; however, cleaning the contaminates from the ionic liquids was problematic. This was overcome with a higher temperature (120C) than originally proposed and a very low pressure (1 kPa. Absorption trials were conducted with tetradecy(trihexyl)phosphonium dicyanamide as the RTIL. It was determined that it has good absorption properties for methanol and ?-pinene, is thermally stable, and is relatively easy to synthesize. It has a density of 0.89 g/mL at 20C and a molecular weight of 549.9 g/mol. Trials were conducted with a small absorption system and a larger absorption system. Methanol, formaldehyde, and other HAPs were absorbed well, nearly 100%. Acetaldehyde was difficult to capture. Total VOC capture, while satisfactory on methanol and ?-pinene in a lab system, was less than expected in the field, 60-80%. The inability to capture the broad spectrum of total organics is likely due to difficulties in cleaning them from the ionic liquid rather than the ability of the ionic liquid to absorb. Its likely that a commercial system could be constructed to remove 90 to 100% of the gas contaminates. Selecting the correct ionic liquid would be key to this. Absorption may not be the main selection criterion, but rather how easily the ionic liquid can be cleaned is very important. The ionic liquid absorption system might work very well in a system with a limited spectrum of pollutants, such as a paint spray line, where there are not very high molecular weight, non volatile, compounds in the exhaust.

  17. In-situ spectrophotometric probe

    DOE Patents [OSTI]

    Prather, W.S.

    1992-12-15T23:59:59.000Z

    A spectrophotometric probe is described for in situ absorption spectra measurements comprising a first optical fiber carrying light from a remote light source, a second optical fiber carrying light to a remote spectrophotometer, the proximal ends of the first and second optical fibers parallel and co-terminal, a planoconvex lens to collimate light from the first optical fiber, a reflecting grid positioned a short distance from the lens to reflect the collimated light back to the lens for focusing on the second optical fiber. The lens is positioned with the convex side toward the optical fibers. A substrate for absorbing analyte or an analyte and reagent mixture may be positioned between the lens and the reflecting grid. 5 figs.

  18. Millimeter-wave active probe

    DOE Patents [OSTI]

    Majidi-Ahy, Gholamreza (Sunnyvale, CA); Bloom, David M. (Portola Valley, CA)

    1991-01-01T23:59:59.000Z

    A millimeter-wave active probe for use in injecting signals with frequencies above 50GHz to millimeter-wave and ultrafast devices and integrated circuits including a substrate upon which a frequency multiplier consisting of filter sections and impedance matching sections are fabricated in uniplanar transmission line format. A coaxial input and uniplanar 50 ohm transmission line couple an approximately 20 GHz input signal to a low pass filter which rolls off at approximately 25 GHz. An input impedance matching section couples the energy from the low pass filter to a pair of matched, antiparallel beam lead diodes. These diodes generate odd-numberd harmonics which are coupled out of the diodes by an output impedance matching network and bandpass filter which suppresses the fundamental and third harmonics and selects the fifth harmonic for presentation at an output.

  19. ECO2M: A TOUGH2 Fluid Property Module for Mixtures of Water, NaCl, and CO2, Including Super- and Sub-Critical Conditions, and Phase Change Between Liquid and Gaseous CO2

    SciTech Connect (OSTI)

    Pruess, K.

    2011-04-01T23:59:59.000Z

    ECO2M is a fluid property module for the TOUGH2 simulator (Version 2.0) that was designed for applications to geologic storage of CO{sub 2} in saline aquifers. It includes a comprehensive description of the thermodynamics and thermophysical properties of H{sub 2}O - NaCl - CO{sub 2} mixtures, that reproduces fluid properties largely within experimental error for temperature, pressure and salinity conditions in the range of 10 C {le} T {le} 110 C, P {le} 600 bar, and salinity from zero up to full halite saturation. The fluid property correlations used in ECO2M are identical to the earlier ECO2N fluid property package, but whereas ECO2N could represent only a single CO{sub 2}-rich phase, ECO2M can describe all possible phase conditions for brine-CO{sub 2} mixtures, including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO{sub 2}. This allows for seamless modeling of CO{sub 2} storage and leakage. Flow processes can be modeled isothermally or non-isothermally, and phase conditions represented may include a single (aqueous or CO{sub 2}-rich) phase, as well as two-and three-phase mixtures of aqueous, liquid CO{sub 2} and gaseous CO{sub 2} phases. Fluid phases may appear or disappear in the course of a simulation, and solid salt may precipitate or dissolve. TOUGH2/ECO2M is upwardly compatible with ECO2N and accepts ECO2N-style inputs. This report gives technical specifications of ECO2M and includes instructions for preparing input data. Code applications are illustrated by means of several sample problems, including problems that had been previously solved with TOUGH2/ECO2N.

  20. Corrosion probes for fireside monitoring in coal-fired boilers

    SciTech Connect (OSTI)

    Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, M.; Holcomb, Gordon R.

    2005-01-01T23:59:59.000Z

    Corrosion probes are being developed and combined with an existing measurement technology to provide a tool for assessing the extent of corrosion of metallic materials on the fireside in coal-fired boilers. The successful development of this technology will provide power plant operators the ability to (1) accurately monitor metal loss in critical regions of the boiler, such as waterwalls, superheaters, and reheaters; and (2) use corrosion rates as process variables. In the former, corrosion data could be used to schedule maintenance periods and in the later, processes can be altered to decrease corrosion rates. The research approach involves laboratory research in simulated environments that will lead to field tests of corrosion probes in coal-fired boilers. Laboratory research has already shown that electrochemically-measured corrosion rates for ash-covered metals are similar to actual mass loss corrosion rates. Electrochemical tests conducted using a potentiostat show the corrosion reaction of ash-covered probes at 500?C to be electrochemical in nature. Corrosion rates measured are similar to those from an automated corrosion monitoring system. Tests of corrosion probes made with mild steel, 304L stainless steel (SS), and 316L SS sensors showed that corrosion of the sensors in a very aggressive incinerator ash was controlled by the ash and not by the alloy content. Corrosion rates in nitrogen atmospheres tended to decrease slowly with time. The addition of oxygen-containing gases, oxygen and carbon dioxide to nitrogen caused a more rapid decrease in corrosion rate, while the addition of water vapor increased the corrosion rate.

  1. Design of a Probe for Strain Sensitivity Studies of Critical Current Densities in SC Wires and Tapes

    SciTech Connect (OSTI)

    Dhanaraj, N.; Barzi, E.; Turrioni, D.; Rusy, A.; Lombardo, V.; /Fermilab

    2011-07-01T23:59:59.000Z

    The design of a variable-temperature probe used to perform strain sensitivity measurements on LTS wires and HTS wires and tapes is described. The measurements are intended to be performed at liquid helium temperatures (4.2 K). The wire or tape to be measured is wound and soldered on to a helical spring device, which is fixed at one end and subjected to a torque at the free end. The design goal is to be able to achieve {+-} 0.8 % strain in the wire and tape. The probe is designed to carry a current of 2000A.

  2. Thermodynamics of D-brane Probes

    E-Print Network [OSTI]

    E. Kiritsis; T. R. Taylor

    1999-06-05T23:59:59.000Z

    We discuss the dynamics and thermodynamics of particle and D-brane probes moving in non-extremal black hole/brane backgrounds. When a probe falls from asymptotic infinity to the horizon, it transforms its potential energy into heat, $TdS$, which is absorbed by the black hole in a way consistent with the first law of thermodynamics. We show that the same remains true in the near-horizon limit, for BPS probes only, with the BPS probe moving from AdS infinity to the horizon. This is a quantitative indication that the brane-probe reaching the horizon corresponds to thermalization in gauge theory. It is shown that this relation provides a way to reliably compute the entropy away from the extremal limit (towards the Schwarzschild limit).

  3. Rugged fiber optic probe for raman measurement

    DOE Patents [OSTI]

    O'Rourke, Patrick E. (Martinez, GA); Toole, Jr., William R. (Aiken, SC); Nave, Stanley E. (Evans, GA)

    1998-01-01T23:59:59.000Z

    An optical probe for conducting light scattering analysis is disclosed. The probe comprises a hollow housing and a probe tip. A fiber assembly made up of a transmitting fiber and a receiving bundle is inserted in the tip. A filter assembly is inserted in the housing and connected to the fiber assembly. A signal line from the light source and to the spectrometer also is connected to the filter assembly and communicates with the fiber assembly. By using a spring-loaded assembly to hold the fiber connectors together with the in-line filters, complex and sensitive alignment procedures are avoided. The close proximity of the filter assembly to the probe tip eliminates or minimizes self-scattering generated by the optical fiber. Also, because the probe can contact the sample directly, sensitive optics can be eliminated.

  4. Protective shield for an instrument probe

    DOE Patents [OSTI]

    Johnsen, Howard A.; Ross, James R.; Birtola, Sal R.

    2004-10-26T23:59:59.000Z

    A shield is disclosed that is particularly useful for protecting exposed optical elements at the end of optical probes used in the analysis of hazardous emissions in and around an industrial environment from the contaminating effects of those emissions. The instant invention provides a hood or cowl in the shape of a right circular cylinder that can be fitted over the end of such optical probes. The hood provides a clear aperture through which the probe can perform unobstructed analysis. The probe optical elements are protected from the external environment by passing a dry gas through the interior of the hood and out through the hood aperture in sufficient quantity and velocity to prevent any significant mixing between the internal and external environments. Additionally, the hood is provided with a cooling jacket to lessen the potential for damaging the probe due to temperature excursions.

  5. Water inertial reorientation: Hydrogen bond strength and the angular potential

    E-Print Network [OSTI]

    Fayer, Michael D.

    Water inertial reorientation: Hydrogen bond strength and the angular potential David E. Moilanen) The short-time orientational relaxation of water is studied by ultrafast infrared pump-probe spectroscopy with recent molecular dynamics simulations employing the simple point charge-extended water model at room

  6. liquid nberwp.tex Liquidity Constraints and Precautionary Saving

    E-Print Network [OSTI]

    Niebur, Ernst

    liquid nberwp.tex Liquidity Constraints and Precautionary Saving Christopher D. Carroll ccarroll to the optimal consumption/saving problem under uncertainty have long known that there are quantitatively important in- teractions between liquidity constraints and precautionary saving behavior. This paper

  7. A study of boiling water flow regimes at low pressures

    E-Print Network [OSTI]

    Fiori, Mario P.

    1966-01-01T23:59:59.000Z

    "A comprehensive experimental program to examine flow regimes at pressures below 100 psia for boiling of water in tubes was carried out. An electrical probe, which measures the resistance of the fluid between the centerline ...

  8. The Release of Trapped Gases from Amorphous Solid Water Films...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    I. Top-Down" Crystallization-Induced Crack Propagation Probed The Release of Trapped Gases from Amorphous Solid Water Films: I. Top-Down" Crystallization-Induced Crack Propagation...

  9. Properties of Liquid Plutonium

    SciTech Connect (OSTI)

    Freibert, Franz J. [Los Alamos National Laboratory; Mitchell, Jeremy N. [Los Alamos National Laboratory; Schwartz, Daniel S. [Los Alamos National Laboratory; Saleh, Tarik A. [Los Alamos National Laboratory; Migliori, Albert [Los Alamos National Laboratory

    2012-08-02T23:59:59.000Z

    Unalloyed polycrystalline Pu displays extreme thermal expansion behavior, i.e., {alpha} {yields} {beta} {yields} {gamma} {yields} {delta} increases by 25% in volume and {delta} {yields} {var_epsilon} {yields} liquid decreases by 4.5% in volume. Thus, making it difficult to measure density into the liquid state. Dilatometer outfitted with CaF molten metal cell offers a proven capability to measure thermal expansion in molten metals, but has yet to be proven for Pu. Historic data from the liquid nuclear fuels program will prove extremely useful as a guide to future measurements. 3.3at% Ga changes Pu molten metal properties: 50% increase in viscosity and {approx}3% decrease in density. Fe may decrease the density by a small amount assuming an averaging of densities for Pu-Ga and Pu-Fe liquids. More recent Boivineau (2009) work needs some interpretation, but technique is being employed in (U,Pu)O{sub 2} nuclear fuels program (Pu Futures, 2012).

  10. Breakup of Liquid Filaments

    E-Print Network [OSTI]

    Castrejon-Pita, Alfonso A.; Castrejon-Pita, J.R.; Hutchings, I.M.

    2012-01-01T23:59:59.000Z

    , including the dispersion of liquid drugs into res- pirable droplets, microfluidics, crop- and paint-spraying, and ink-jet printing [24]. There are also biological sys- tems in which either long filaments remain intact, or many droplets are formed [5, 6...

  11. Water in a Crowd In many situations, form biology to geology, water occurs not as the pure bulk

    E-Print Network [OSTI]

    Fayer, Michael D.

    Water in a Crowd In many situations, form biology to geology, water occurs not as the pure bulk species, and interacting with large organic molecules. In such situations, water does not behave in the same manner as it does in the pure bulk liquid. Water dynamics are fundamental to many processes

  12. Imaging Liquids Using Microfluidic Cells

    SciTech Connect (OSTI)

    Yu, Xiao-Ying; Liu, Bingwen; Yang, Li

    2013-05-10T23:59:59.000Z

    Chemistry occurring in the liquid and liquid surface is important in many applications. Chemical imaging of liquids using vacuum based analytical techniques is challenging due to the difficulty in working with liquids with high volatility. Recent development in microfluidics enabled and increased our capabilities to study liquid in situ using surface sensitive techniques such as electron microscopy and spectroscopy. Due to its small size, low cost, and flexibility in design, liquid cells based on microfluidics have been increasingly used in studying and imaging complex phenomena involving liquids. This paper presents a review of microfluidic cells that were developed to adapt to electron microscopes and various spectrometers for in situ chemical analysis and imaging of liquids. The following topics will be covered including cell designs, fabrication techniques, unique technical features for vacuum compatible cells, and imaging with electron microscopy and spectroscopy. Challenges are summarized and recommendations for future development priority are proposed.

  13. Liquid crystalline composites containing phyllosilicates

    DOE Patents [OSTI]

    Chaiko; David J. (Naperville, IL)

    2007-05-08T23:59:59.000Z

    The present invention provides barrier films having reduced gas permeability for use in packaging and coating applications. The barrier films comprise an anisotropic liquid crystalline composite layer formed from phyllosilicate-polymer compositions. Phyllosilicate-polymer liquid crystalline compositions of the present invention can contain a high percentage of phyllosilicate while remaining transparent. Because of the ordering of the particles in the liquid crystalline composite, barrier films comprising liquid crystalline composites are particularly useful as barriers to gas transport.

  14. NMR evidence of a sharp change in a measure of local order in deeply supercooled confined water

    E-Print Network [OSTI]

    Stanley, H. Eugene

    in thermody- namical properties such as compressibility, isobaric heat capacity, and thermal expansion of maximum correlation length at 240 K, consistent with the liquid-liquid critical point hypothesis for water received support from various theoretical studies (4­7) is the liquid-liquid (LL) critical point hypothesis

  15. Condensate Water Collection for an Institutional Building in Doha, Qatar: An Opportunity for Water Sustainability

    E-Print Network [OSTI]

    Bryant, J. A.; Ahmed, T.

    2008-01-01T23:59:59.000Z

    conditioning system. Internal loads and additional outside ventilation air all generate considerable latent loads on these systems and exacerbate the already difficult moisture control problem. A manifestation of this load is the liquid water condensate...

  16. On a phase field model for solid-liquid phase transitions

    E-Print Network [OSTI]

    distinct phases. This is the case for solid-liquid mix- tures (e.g. ice-water or alloys duringOn a phase field model for solid-liquid phase transitions S. Benzoni-Gavage , L. Chupin , D. Jamet 3.2 Back to physical variables . . . . . . . . . . . . . . . . . . . . 16 4 Well-posedness 17 4

  17. The recoiling of liquid droplets upon collision with solid surfaces H.-Y. Kima)

    E-Print Network [OSTI]

    Kim, Ho-Young

    solid surfaces polycarbonate and silicon oxide . The droplet dynamics are experimentally studied using of different liquid droplets water, ink, and silicone oil on different solid surfaces polycarbonate and silicon. Fukai et al.14,15 conducted a theoretical study on the spreading and recoiling of a liquid droplet upon

  18. Liquid-solid phase transitions in a deformable Pavel Krejci, Elisabetta Rocca, and Jurgen Sprekels

    E-Print Network [OSTI]

    Rocca, Elisabetta

    differences in the specific volume, specific heat and speed of sound in the solid and liquid phases and of the liquid phase, assuming first that the speed of sound and the specific heat are the same in solid the speed of sound in water is less than one half of the one in ice. The main goal of this contribution

  19. Three-Dimensional Simulations of Liquid Feed Direct Methanol Wenpeng Liu*,a

    E-Print Network [OSTI]

    Three-Dimensional Simulations of Liquid Feed Direct Methanol Fuel Cells Wenpeng Liu*,a and Chao that performance and design of a liquid feed direct methanol fuel cell DMFC is controlled not only by electrochemical kinetics and methanol crossover but also by water transport and by their complex interactions

  20. ORIGINAL ARTICLE Energy harvesting from organic liquids in micro-sized

    E-Print Network [OSTI]

    OPEN ORIGINAL ARTICLE Energy harvesting from organic liquids in micro-sized microbial fuel cells (MFCs) are miniature energy harvesters that use bacteria to convert biomass from liquids into usable advantages of MFCs is that they can be used to both clean water and produce electrical power, the objective

  1. American Institute of Aeronautics and Astronautics Development of a Compact Liquid Fueled Pulsed Detonation

    E-Print Network [OSTI]

    Texas at Arlington, University of

    automotive ignition system. Pre-heated liquid fuel is sprayed into a current of pre-heated air and thoroughly Hz. The PDE set up is water cooled allowing long duration testing. Diagnostics are performed using it necessary to preheat the fuel and/or air and to use nozzles to finely atomize the fuel spray. Liquid fueled

  2. High temperature liquid level sensor

    DOE Patents [OSTI]

    Tokarz, Richard D. (West Richland, WA)

    1983-01-01T23:59:59.000Z

    A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.

  3. Process for removing sulfate anions from waste water

    DOE Patents [OSTI]

    Nilsen, David N. (Lebanon, OR); Galvan, Gloria J. (Albany, OR); Hundley, Gary L. (Corvallis, OR); Wright, John B. (Albany, OR)

    1997-01-01T23:59:59.000Z

    A liquid emulsion membrane process for removing sulfate anions from waste water is disclosed. The liquid emulsion membrane process includes the steps of: (a) providing a liquid emulsion formed from an aqueous strip solution and an organic phase that contains an extractant capable of removing sulfate anions from waste water; (b) dispersing the liquid emulsion in globule form into a quantity of waste water containing sulfate anions to allow the organic phase in each globule of the emulsion to extract and absorb sulfate anions from the waste water and (c) separating the emulsion including its organic phase and absorbed sulfate anions from the waste water to provide waste water containing substantially no sulfate anions.

  4. Liquid membrane coated ion-exchange column solids

    DOE Patents [OSTI]

    Barkey, Dale P. (Berkeley, CA)

    1989-01-01T23:59:59.000Z

    This invention relates to a method for improving the performance of liquid embrane separations by coating a liquid membrane onto solid ion-exchange resin beads in a fixed bed. Ion-exchange beads fabricated from an ion-exchange resin are swelled with water and are coated with a liquid membrane material that forms a film over the beads. The beads constitute a fixed bed ion-exchange column. Fluid being treated that contains the desired ion to be trapped by the ion-exchange particle is passed through the column. A carrier molecule, contained in the liquid membrane ion-exchange material, is selected for the desired ion in the fluid. The carrier molecule forms a complex with the desired ion, transporting it through the membrane and thus separating it from the other ions. The solution is fed continuously until breakthrough occurs at which time the ion is recovered, and the bed is regenerated.

  5. Liquid membrane coated ion-exchange column solids

    DOE Patents [OSTI]

    Barkey, Dale P. (Berkeley, CA)

    1988-01-01T23:59:59.000Z

    This invention relates to a method for improving the performance of liquid membrane separations by coating a liquid membrane onto solid ion-exchange resin beads in a fixed bed. Ion-exchange beads fabricated from an ion-exchange resin are swelled with water and are coated with a liquid membrane material that forms a film over the beads. The beads constitute a fixed bed ion-exchange column. Fluid being treated that contains the desired ion to be trapped by the ion-exchange particle is passed through the column. A carrier molecule, contained in the liquid membrane ion-exchange material, is selective for the desired ion in the fluid. The carrier molecule forms a complex with the desired ion, transporting it through the membrane and thus separating it from the other ions. The solution is fed continuously until breakthrough occurs at which time the ion is recovered, and the bed is regenerated.

  6. Probing Signal Design for Power System Identification

    SciTech Connect (OSTI)

    Pierre, John W.; Zhou, Ning; Tuffner, Francis K.; Hauer, John F.; Trudnowski, Daniel J.; Mittelstadt, William

    2010-05-31T23:59:59.000Z

    This paper investigates the design of effective input signals for low-level probing of power systems. In 2005, 2006, and 2008 the Western Electricity Coordinating Council (WECC) conducted four large-scale system wide tests of the western interconnected power system where probing signals were injected by modulating the control signal at the Celilo end of the Pacific DC intertie. A major objective of these tests is the accurate estimation of the inter-area electromechanical modes. A key aspect of any such test is the design of an effective probing signal that leads to measured outputs rich in information about the modes. This paper specifically studies low-level probing signal design for power-system identification. The paper describes the design methodology and the advantages of this new probing signal which was successfully applied during these tests. This probing input is a multi-sine signal with its frequency content focused in the range of the inter-area modes. The period of the signal is over two minutes providing high-frequency resolution. Up to 15 cycles of the signal are injected resulting in a processing gain of 15. The resulting system response is studied in the time and frequency domains. Because of the new probing signal characteristics, these results show significant improvement in the output SNR compared to previous tests.

  7. In-Situ Transmission Electron Microscopy Probing of Native Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing of Native Oxide and Artificial Layers on Silicon Nanoparticles for Lithium Ion In-Situ Transmission Electron Microscopy Probing of Native Oxide and Artificial...

  8. Quantitatively Probing the Al Distribution in Zeolites. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Quantitatively Probing the Al Distribution in Zeolites. Quantitatively Probing the Al Distribution in Zeolites. Abstract: The degree of substitution of Si4+ by Al3+ in the...

  9. Atmospheric Solids Analysis Probe Mass Spectrometry: A New Approach...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atmospheric Solids Analysis Probe Mass Spectrometry: A New Approach for Airborne Particle Analysis. Atmospheric Solids Analysis Probe Mass Spectrometry: A New Approach for Airborne...

  10. Scanning Probe Direct-Write of Germanium Nanostructures. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probe Direct-Write of Germanium Nanostructures. Scanning Probe Direct-Write of Germanium Nanostructures. Abstract: Bottom-up nanostructure synthesis has played a pivotal role in...

  11. Performance Evaluation for Modular, Scalable Liquid-Rack Cooling Systems in Data Centers

    E-Print Network [OSTI]

    Xu, TengFang

    2009-01-01T23:59:59.000Z

    the modular liquid cooling system with varying supply waterinlet supply air temperature, while modular system coolingcooling needed (up to 9.8 kW/rack) at various supply water

  12. X-ray Absorption Spectroscopy of Liquid Methanol Microjets: Bulk Electronic Structure and Hydrogen Bonding Network

    E-Print Network [OSTI]

    Cohen, Ronald C.

    of ice,15,16 or at the liquid-gas interface.3 As expected, water in its various phases is a natural, Sweden, AdVanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720

  13. Water Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water Quality Water Quality We protect water quality through stormwater control measures and an extensive network of monitoring wells and stations encompassing groundwater, surface...

  14. Factors influencing quantitative liquid (scanning) transmission...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Factors influencing quantitative liquid (scanning) transmission electron microscopy. Factors influencing quantitative liquid (scanning) transmission electron microscopy. Abstract:...

  15. Analysis & Simulation of Dynamics in Supercooled Liquids

    E-Print Network [OSTI]

    Elmatad, Yael Sarah

    2011-01-01T23:59:59.000Z

    Moreover, the heat capacity of that liquid is also higherthe intensive heat capacities of the liquid and the crystal,

  16. A new probe for corrosion monitoring of stainless steel piping systems

    SciTech Connect (OSTI)

    Valen, S.; Johnsen, R.; Gartland, P.O. [CorrOcean as, Trondheim (Norway); Hollen, I.H. [AS Norske Shell, Kristiansund (Norway)

    1995-12-01T23:59:59.000Z

    This paper presents theoretical background and development of a probe for corrosion monitoring of process- and piping systems made of stainless steels. The probe will be installed in two piping systems on the Draugen platform in the North Sea. One installation is for monitoring of a produced water systems made of duplex stainless steel (UNS S31803), and one for monitoring in a seawater system made of high-alloy austenitic stainless steel of the 6 Mo type (UNS S31254). Equipment for logging and storing data is also described.

  17. The Boson peak in supercooled water

    E-Print Network [OSTI]

    Pradeep Kumar; K. Thor Wikfeldt; Daniel Schlesinger; Lars G. M. Pettersson; H. E. Stanley

    2013-05-19T23:59:59.000Z

    We perform extensive molecular dynamics simulations of the TIP4P/2005 model of water to investigate the origin of the Boson peak reported in experiments on supercooled water in nanoconfined pores, and in hydration water around proteins. We find that the onset of the Boson peak in supercooled bulk water coincides with the crossover to a predominantly low-density-like liquid below the Widom line $T_W$. The frequency and onset temperature of the Boson peak in our simulations of bulk water agree well with the results from experiments on nanoconfined water. Our results suggest that the Boson peak in water is not an exclusive effect of confinement. We further find that, similar to other glass-forming liquids, the vibrational modes corresponding to the Boson peak are spatially extended and are related to transverse phonons found in the parent crystal, here ice Ih.

  18. Characterization of Fiber Optic CMM Probe System

    SciTech Connect (OSTI)

    K.W.Swallow

    2007-05-15T23:59:59.000Z

    This report documents a study completed on the fiber optic probe system that is a part of the Werth optical CMM. This study was necessary due to a lack of documentation from the vendor for the proper use and calibration of the fiber probe, and was performed in support of the Lithographie Galvanoformung Abformung (LIGA) development program at the FM&T. As a result of this study, a better understanding of the fiber optic probe has been developed, including guidelines for its proper use and calibration.

  19. Integrated photoelectrochemical cell and system having a liquid electrolyte

    DOE Patents [OSTI]

    Deng, Xunming (Sylvania, OH); Xu, Liwei (Sylvania, OH)

    2010-07-06T23:59:59.000Z

    An integrated photoelectrochemical (PEC) cell generates hydrogen and oxygen from water while being illuminated with radiation. The PEC cell employs a liquid electrolyte, a multi-junction photovoltaic electrode, and a thin ion-exchange membrane. A PEC system and a method of making such PEC cell and PEC system are also disclosed.

  20. Liquid Holdup Profiles in Structured Packing Determined via Neutron Radiography

    E-Print Network [OSTI]

    Eldridge, R. Bruce

    scans of an operating air-water contactor were performed at the NIST Center for Neutron Research (NCNR packings are widely employed in vapor-liquid contacting devices for distillation, absorption, and stripping. The high specific surface areas (ap), regular geometries, and high void fraction () of structured packing

  1. Modeling Liquid-Liquid Equilibrium of Ionic Liquid Systems with NRTL, Electrolyte-NRTL, and UNIQUAC

    E-Print Network [OSTI]

    Stadtherr, Mark A.

    Modeling Liquid-Liquid Equilibrium of Ionic Liquid Systems with NRTL, Electrolyte-NRTL, and UNIQUAC different excess Gibbs free energy models are evaluated: the NRTL, UNIQUAC and electrolyte- NRTL (eNRTL) models. In the case of eNRTL, a new formulation of the model is used, based on a symmetric reference

  2. Help cut pollution with vapor/liquid and liquid/liquid separators

    SciTech Connect (OSTI)

    Woinsky, S.G.

    1994-10-01T23:59:59.000Z

    Vapor/liquid and liquid/liquid separators are common in chemical process industries plants. In addition to separating phases, these devices can aid in reducing pollution in the plant. Two-phase separators achieve pollution prevention via recycling of intermediates and final products. It is doubtful that most vapor/liquid and liquid/liquid separators are used specifically for pollution prevention projects. They may have another purpose yet provide pollution prevention as a bonus. The first step in achieving pollution prevention by design is for operating companies to be aware of vapor/liquid and liquid/liquid separators as potential pollution prevention devices. Then, likely applications need to be investigated. Since the quantities of material recovered are relatively small, higher value products are the most likely targets, especially for liquid/liquid separators. However, for vapor/liquid separators, the costs involved are usually relatively low since only the cost of a separator pad is normally involved, and more moderately valued products can be targets.

  3. Decommissioning and Dismantling of Liquid Waste Storage and Liquid Waste Treatment Facility from Paldiski Nuclear Site, Estonia

    SciTech Connect (OSTI)

    Varvas, M. [AS ALARA, Leetse tee 21, Paldiski, 76806 (Estonia); Putnik, H. [Delegation of the European Commission to Russia, Kadashevskaja nab. 14/1 119017 Moscow (Russian Federation); Nirvin, B.; Pettersson, S. [SKB, Box 5864, Stockholm, SE-102 40 (Sweden); Johnsson, B. [Studsvik RadWaste, Nykoping, SE-611 82 (Sweden)

    2006-07-01T23:59:59.000Z

    The Paldiski Nuclear Facility in Estonia, with two nuclear reactors was owned by the Soviet Navy and was used for training the navy personnel to operate submarine nuclear reactors. After collapse of Soviet Union the Facility was shut down and handed over to the Estonian government in 1995. In co-operation with the Paldiski International Expert Reference Group (PIERG) decommission strategy was worked out and started to implement. Conditioning of solid and liquid operational waste and dismantling of contaminated installations and buildings were among the key issues of the Strategy. Most of the liquid waste volume, remained at the Facility, was processed in the frames of an Estonian-Finnish co-operation project using a mobile wastewater purification unit NURES (IVO International OY) and water was discharged prior to the site take-over. In 1999-2002 ca 120 m{sup 3} of semi-liquid tank sediments (a mixture of ion exchange resins, sand filters, evaporator and flocculation slurry), remained after treatment of liquid waste were solidified in steel containers and stored into interim storage. The project was carried out under the Swedish - Estonian co-operation program on radiation protection and nuclear safety. Contaminated installations in buildings, used for treatment and storage of liquid waste (Liquid Waste Treatment Facility and Liquid Waste Storage) were then dismantled and the buildings demolished in 2001-2004. (authors)

  4. Liquid filtration simulation

    SciTech Connect (OSTI)

    Corey, I.; Bergman, W.

    1996-06-01T23:59:59.000Z

    We have a developed a computer code that simulates 3-D filtration of suspended particles in fluids in realistic filter structures. This code, being the most advanced filtration simulation package developed to date, provides LLNL and DOE with new capabilities to address problems in cleaning liquid wastes, medical fluid cleaning, and recycling liquids. The code is an integrated system of commercially available and LLNL-developed software; the most critical are the computational fluid dynamics (CFD) solver and the particle transport program. For the CFD solver, we used a commercial package based on Navier-Stokes equations and a LLNL-developed package based on Boltzman-lattice gas equations. For the particle transport program, we developed a cod based on the 3-D Langevin equation of motion and the DLVO theory of electrical interactions. A number of additional supporting packages were purchased or developed to integrate the simulation tasks and to provide visualization output.

  5. Adsorptive Drying of Organic Liquids- An Update

    E-Print Network [OSTI]

    Joshi, S.; Humphrey, J. L.; Fair, J. R.

    (which is very heat sensitive and can poly merize in the presence of adsorbents) by freeze drying at -20 0 C and centrifuging the ice crystals. The water oontent was reduced from 700 ppm to 1~0 ppm. Pervaporation One of the recent advances... at The University of Texas at Austin will also be given. INTRODUCTION In the process industries it is often necessary to dry fluids before they can be processed further. For example, if a liquid is to be subjected to cryo genic conditions, its frost point must...

  6. Schrodinger Fermi Liquids

    E-Print Network [OSTI]

    Wang, Juven

    2013-01-01T23:59:59.000Z

    We study a class of strongly interacting many-body fermionic systems in 2+1D non-relativistic conformal field theory via holography. The 5D charged black hole with asymptotic Schrodinger isometry in the bulk gravity side introduces parameters of background density and finite particle number into the boundary field theory. We propose the holographic dictionary, and realize a quantum phase transition of this fermionic liquid with fixed particle number by tuning the background density $\\beta$ at zero temperature. On the larger $\\beta$ side, we find the signal of a sharp quasiparticle pole on the spectral function A(k,w), indicating a well-defined Fermi surface. On the smaller $\\beta$ side, we find only a hump with no sharp peak for A(k,w), indicating the disappearance of Fermi surface. The dynamical exponent $z$ of quasiparticle dispersion goes from being Fermi-liquid-like $z\\simeq1$ scaling at larger $\\beta$ to a non-Fermi-liquid scaling $z\\simeq 3/2$ at smaller $\\beta$. By comparing the structure of Green's fu...

  7. Microscopic linear liquid streams in vacuum: Injection of solvated biological samples into X-ray free electron lasers

    SciTech Connect (OSTI)

    Doak, R. B.; DePonte, D. P.; Nelson, G.; Camacho-Alanis, F.; Ros, A.; Spence, J. C. H.; Weierstall, U. [Arizona State University, Tempe, AZ 85287-1504 (United States); Centre for Free-Electron Laser Science, DESY, D-22607 Hamburg (Germany); Arizona State University, Tempe, AZ 85287-1504 (United States)

    2012-11-27T23:59:59.000Z

    Microscopic linear liquid free-streams offer a means of gently delivering biological samples into a probe beam in vacuum while maintaining the sample species in a fully solvated state. By employing gas dynamic forces to form the microscopic liquid stream (as opposed to a conventional solid-walled convergent nozzle), liquid free-streams down to 300 nm diameter have been generated. Such 'Gas Dynamic Virtual Nozzles' (GDVN) are ideally suited to injecting complex biological species into an X-ray Free Electron Laser (XFEL) to determine the structure of the biological species via Serial Femtosecond Crystallography (SFX). GDVN injector technology developed for this purpose is described.

  8. Modulated microwave microscopy and probes used therewith

    DOE Patents [OSTI]

    Lai, Keji; Kelly, Michael; Shen, Zhi-Xun

    2012-09-11T23:59:59.000Z

    A microwave microscope including a probe tip electrode vertically positionable over a sample and projecting downwardly from the end of a cantilever. A transmission line connecting the tip electrode to the electronic control system extends along the cantilever and is separated from a ground plane at the bottom of the cantilever by a dielectric layer. The probe tip may be vertically tapped near or at the sample surface at a low frequency and the microwave signal reflected from the tip/sample interaction is demodulated at the low frequency. Alternatively, a low-frequency electrical signal is also a non-linear electrical element associated with the probe tip to non-linearly interact with the applied microwave signal and the reflected non-linear microwave signal is detected at the low frequency. The non-linear element may be semiconductor junction formed near the apex of the probe tip or be an FET formed at the base of a semiconducting tip.

  9. Self-referencing remote optical probe

    DOE Patents [OSTI]

    O'Rourke, P.E.; Prather, W.S.; Livingston, R.R.

    1991-08-13T23:59:59.000Z

    A probe is described for remote spectrometric measurements of fluid samples having a hollow probe body with a sliding reflective plug therein and a lens at one end, ports for admitting and expelling the fluid sample and a means for moving the reflector so that reference measurement can be made with the reflector in a first position near the lens and a sample measurement can be made with the reflector away from the lens and the fluid sample between the reflector and the lens. Comparison of the two measurements will yield the composition of the fluid sample. The probe is preferably used for remote measurements and light is carried to and from the probe via fiber optic cables. 3 figures.

  10. Surface sampling concentration and reaction probe

    DOE Patents [OSTI]

    Van Berkel, Gary J; Elnaggar, Mariam S

    2013-07-16T23:59:59.000Z

    A method of analyzing a chemical composition of a specimen is described. The method can include providing a probe comprising an outer capillary tube and an inner capillary tube disposed co-axially within the outer capillary tube, where the inner and outer capillary tubes define a solvent capillary and a sampling capillary in fluid communication with one another at a distal end of the probe; contacting a target site on a surface of a specimen with a solvent in fluid communication with the probe; maintaining a plug volume proximate a solvent-specimen interface, wherein the plug volume is in fluid communication with the probe; draining plug sampling fluid from the plug volume through the sampling capillary; and analyzing a chemical composition of the plug sampling fluid with an analytical instrument. A system for performing the method is also described.

  11. Catheter based magnetic resonance compatible perfusion probe

    E-Print Network [OSTI]

    Toretta, Cara Lynne

    2007-01-01T23:59:59.000Z

    Neurosurgeons are using a thermal based technique to quantify brain perfusion. The thermal diffusion probe (TDP) technology measures perfusion in a relatively small volume of brain tissue. The neurosurgeon chooses the ...

  12. Scanning Probe AFM Compound Microscope | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a dye-sensitization system,... Tip-Enhanced Near-Field Raman Spectroscopy Probing Single Dye-Sensitized TiO2 Nanoparticles. The correlated metallic tip-enhanced Raman spectroscopy...

  13. Single Molecule Probes of Lipid Membrane Structure

    E-Print Network [OSTI]

    Livanec, Philip W.

    2009-12-14T23:59:59.000Z

    Biological membranes are highly heterogeneous structures that are thought to use this heterogeneity to organize and modify the function of membrane constituents. Probing membrane organization, structure, and changes therein ...

  14. Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage

    E-Print Network [OSTI]

    Nielsen, L.C.

    2013-01-01T23:59:59.000Z

    and transport properties of carbon dioxide for molecularinterfacial properties of binary carbon dioxide waterCarbon dioxides liquidvapor coexistence curve and critical properties

  15. Electron localization in liquid acetonitrile.

    SciTech Connect (OSTI)

    Shkrob, I. A.; Sauer, M. C.; Chemistry

    2002-10-03T23:59:59.000Z

    Time-resolved one- and two-pulse laser dc photoconductivity has been used to observe two kinds of reducing species, anion-1 and anion-2, in liquid acetonitrile. At 25 C, the standard enthalpy of conversion from anion-1 to anion-2 is -44.3 {+-} 3.6 kJ/mol and the conversion time is 3 ns. The high-temperature form, anion-1, absorbs in the IR and migrates >3.3 times faster than any other ion in acetonitrile. This rapid migration has a low activation energy of 3.2 kJ/mol (vs 7.6 kJ/mol for other ions). Anion-1 rapidly transfers the electron to acceptors with high electron affinity, with rate constant up to 10{sup 11} M{sup -1} s{sup -1}. The low-temperature form, anion-2, absorbs in the visible and exhibits normal mobility and electron-transfer rates, ca. 1.5 x 10{sup 10} M{sup -1} s{sup -1}. It reacts, by proton transfer, with two hydrogen-bonded molecules of water and/or aliphatic alcohols. Laser photoexcitation of these two solvent anions in their respective absorption bands leads to the formation of CH{sub 3} and CN{sup -}. We present arguments indicating that anion-2 is a dimer radical anion of acetonitrile, whereas anion-1 is a multimer radical anion that may be regarded as a 'solvated electron'.

  16. Fiber optic probe for light scattering measurements

    DOE Patents [OSTI]

    Nave, Stanley E. (Evans, GA); Livingston, Ronald R. (Aiken, SC); Prather, William S. (Augusta, GA)

    1995-01-01T23:59:59.000Z

    A fiber optic probe and a method for using the probe for light scattering analyses of a sample. The probe includes a probe body with an inlet for admitting a sample into an interior sample chamber, a first optical fiber for transmitting light from a source into the chamber, and a second optical fiber for transmitting light to a detector such as a spectrophotometer. The interior surface of the probe carries a coating that substantially prevents non-scattered light from reaching the second fiber. The probe is placed in a region where the presence and concentration of an analyte of interest are to be detected, and a sample is admitted into the chamber. Exciting light is transmitted into the sample chamber by the first fiber, where the light interacts with the sample to produce Raman-scattered light. At least some of the Raman-scattered light is received by the second fiber and transmitted to the detector for analysis. Two Raman spectra are measured, at different pressures. The first spectrum is subtracted from the second to remove background effects, and the resulting sample Raman spectrum is compared to a set of stored library spectra to determine the presence and concentration of the analyte.

  17. Fiber optic probe for light scattering measurements

    DOE Patents [OSTI]

    Nave, S.E.; Livingston, R.R.; Prather, W.S.

    1993-01-01T23:59:59.000Z

    This invention is comprised of a fiber optic probe and a method for using the probe for light scattering analyses of a sample. The probe includes a probe body with an inlet for admitting a sample into an interior sample chamber, a first optical fiber for transmitting light from a source into the chamber, and a second optical fiber for transmitting light to a detector such as a spectrophotometer. The interior surface of the probe carries a coating that substantially prevents non-scattered light from reaching the second fiber. The probe is placed in a region where the presence and concentration of an analyte of interest are to be detected, and a sample is admitted into the chamber. Exciting light is transmitted into the sample chamber by the first fiber, where the light interacts with the sample to produce Raman-scattered light. At least some of the Raman- scattered light is received by the second fiber and transmitted to the detector for analysis. Two Raman spectra are measured, at different pressures. The first spectrum is subtracted from the second to remove background effects, and the resulting sample Raman spectrum is compared to a set of stored library spectra to determine the presence and concentration of the analyte.

  18. Water Dynamics at Rough Interfaces

    E-Print Network [OSTI]

    Markus Rosenstihl; Kerstin Kmpf; Felix Klameth; Matthias Sattig; Michael Vogel

    2014-07-21T23:59:59.000Z

    We use molecular dynamics computer simulations and nuclear magnetic resonance experiments to investigate the dynamics of water at interfaces of molecular roughness and low mobility. We find that, when approaching such interfaces, the structural relaxation of water, i.e., the $\\alpha$ process, slows down even when specific attractive interactions are absent. This prominent effect is accompanied by a smooth transition from Vogel to Arrhenius temperature dependence and by a growing importance of jump events. Consistently, at protein surfaces, deviations from Arrhenius behavior are weak when free water does not exist. Furthermore, in nanoporous silica, a dynamic crossover of liquid water occurs when a fraction of solid water forms near 225 K and, hence, the liquid dynamics changes from bulk-like to interface-dominated. At sufficiently low temperatures, water exhibits a quasi-universal $\\beta$ process, which is characterized by an activation energy of $E_a\\!=\\!0.5$ eV and involves anisotropic reorientation about large angles. As a consequence of its large amplitude, the faster $\\beta$ process destroys essentially all orientational correlation, rendering observation of a possible slower $\\alpha$ process difficult in standard experiments. Nevertheless, we find indications for the existence of structural relaxation down to a glass transition of interfacial water near 185 K. Hydrated proteins show a highly restricted backbone motion with an amplitude, which decreases upon cooling and vanishes at comparable temperatures, providing evidence for a high relevance of water rearrangements in the hydration shell for secondary protein relaxations.

  19. Probing thermonuclear supernova explosions with neutrinos

    E-Print Network [OSTI]

    A. Odrzywolek; T. Plewa

    2011-03-27T23:59:59.000Z

    Aims: We present neutrino light curves and energy spectra for two representative type Ia supernova explosion models: a pure deflagration and a delayed detonation. Methods: We calculate the neutrino flux from $\\beta$ processes using nuclear statistical equilibrium abundances convoluted with approximate neutrino spectra of the individual nuclei and the thermal neutrino spectrum (pair+plasma). Results: Although the two considered thermonuclear supernova explosion scenarios are expected to produce almost identical electromagnetic output, their neutrino signatures appear vastly different, which allow an unambiguous identification of the explosion mechanism: a pure deflagration produces a single peak in the neutrino light curve, while the addition of the second maximum characterizes a delayed-detonation. We identified the following main contributors to the neutrino signal: (1) weak electron neutrino emission from electron captures (in particular on the protons Co55 and Ni56) and numerous beta-active nuclei produced by the thermonuclear flame and/or detonation front, (2) electron antineutrinos from positron captures on neutrons, and (3) the thermal emission from pair annihilation. We estimate that a pure deflagration supernova explosion at a distance of 1 kpc would trigger about 14 events in the future 50 kt liquid scintillator detector and some 19 events in a 0.5 Mt water Cherenkov-type detector. Conclusions: While in contrast to core-collapse supernovae neutrinos carry only a very small fraction of the energy produced in the thermonuclear supernova explosion, the SN Ia neutrino signal provides information that allows us to unambiguously distinguish between different possible explosion scenarios. These studies will become feasible with the next generation of proposed neutrino observatories.

  20. Reproducible cavitation activity in water-particle suspensions Bram M. Borkent, Manish Arora, and Claus-Dieter Ohla

    E-Print Network [OSTI]

    Ohl, Claus-Dieter

    Reproducible cavitation activity in water-particle suspensions Bram M. Borkent, Manish Arora January 2007 The study of cavitation inception in liquids rarely yields reproducible data, unless special technique is demonstrated which allows repeatable measurements of cavitation activity in liquid

  1. Vapor-liquid equilibria prediction using a lattice theory of solutions

    E-Print Network [OSTI]

    Clinkscales, Thomas Albert

    1967-01-01T23:59:59.000Z

    OF TABLES TABLE I. Sum of the squares of the pressure residues for predicted pressures by rigid lattice solution model ?. . . . . . . . ?. . . . . . . . . . . . . . . . , . . PAGE 66 II. Types of interactions possible for alcohol- water system... function of liquid mole fraction for methanol-water at 59. 4oC. . . 12. Alcohol activity coefficient error curves for methanol-water at 59. 4 C. z=3, 12, 40. . . . . . . 13. Alcohol activity coefficient error curves for methanol-water at 59. 4 C. z=4...

  2. Liquid class predictor for liquid handling of complex mixtures

    DOE Patents [OSTI]

    Seglke, Brent W. (San Ramon, CA); Lekin, Timothy P. (Livermore, CA)

    2008-12-09T23:59:59.000Z

    A method of establishing liquid classes of complex mixtures for liquid handling equipment. The mixtures are composed of components and the equipment has equipment parameters. The first step comprises preparing a response curve for the components. The next step comprises using the response curve to prepare a response indicator for the mixtures. The next step comprises deriving a model that relates the components and the mixtures to establish the liquid classes.

  3. Evaluation of probes used to detect alpha radiation

    E-Print Network [OSTI]

    Sackett, Gregory Duane

    1995-01-01T23:59:59.000Z

    such probes were evaluated in this study, the 350A Alpha Probe of Dosimeter Corporation and the AB100 Scintillator Probe produced by Harshaw Bicron. As an additional comparison, a Ludlum Model 44-9 (Pancake) GM Probe was also evaluated, since it has served...

  4. Evaluation of probes used to detect alpha radiation

    E-Print Network [OSTI]

    Sackett, Gregory Duane

    1995-01-01T23:59:59.000Z

    such probes were evaluated in this study, the 350A Alpha Probe of Dosimeter Corporation and the AB100 Scintillator Probe produced by Harshaw Bicron. As an additional comparison, a Ludlum Model 44-9 (Pancake) GM Probe was also evaluated, since it has served...

  5. Coaxial probe for nuclear magnetic resonance diffusion and relaxation correlation experiments

    SciTech Connect (OSTI)

    Tang, Yiqiao; Hrlimann, Martin; Mandal, Soumyajit; Paulsen, Jeffrey; Song, Yi-Qiao, E-mail: ysong@slb.com [Schlumberger-Doll Research, 1 Hampshire Street, Cambridge, Massachusetts 02139 (United States)

    2014-02-21T23:59:59.000Z

    A coaxial nuclear magnetic resonance (NMR) probe is built to measure diffusion and relaxation properties of liquid samples. In particular, we demonstrate the acquisition of two-dimensional (2D) distribution functions (T{sub 1}-T{sub 2} and diffusionT{sub 2}), essential for fluids characterization. The compact design holds promise for miniaturization, thus enabling the measurement of molecular diffusion that is inaccessible to conventional micro-NMR setups. Potential applications range from crude oil characterization to biomolecular screening and detections.

  6. A fresh look at coal-derived liquid fuels

    SciTech Connect (OSTI)

    Paul, A.D. [Benham Companies LLC (USA)

    2009-01-15T23:59:59.000Z

    35% of the world's energy comes from oil, and 96% of that oil is used for transportation. The current number of vehicles globally is estimated to be 700 million; that number is expected to double overall by 2030, and to triple in developing countries. Now consider that the US has 27% of the world's supply of coal yet only 2% of the oil. Coal-to-liquids technologies could bridge the gap between US fuel supply and demand. The advantages of coal-derived liquid fuels are discussed in this article compared to the challenges of alternative feedstocks of oil sands, oil shale and renewable sources. It is argued that pollutant emissions from coal-to-liquid facilities could be minimal because sulfur compounds will be removed, contaminants need to be removed for the FT process, and technologies are available for removing solid wastes and nitrogen oxides. If CO{sub 2} emissions for coal-derived liquid plants are captured and sequestered, overall emissions of CO{sub 2} would be equal or less than those from petroleum. Although coal liquefaction requires large volumes of water, most water used can be recycled. Converting coal to liquid fuels could, at least in the near term, bring a higher level of stability to world oil prices and the global economy and could serve as insurance for the US against price hikes from oil-producing countries. 7 figs.

  7. Physicochemical properties and toxicities of hydrophobicpiperidinium and pyrrolidinium ionic liquids

    SciTech Connect (OSTI)

    Salminen, Justin; Papaiconomou, Nicolas; Kumar, R. Anand; Lee,Jong-Min; Kerr, John; Newman, John; Prausnitz, John M.

    2007-06-25T23:59:59.000Z

    Some properties are reported for hydrophobic ionic liquids (IL) containing 1-methyl-1-propyl pyrrolidinium [MPPyrro]{sup +}, 1-methyl-1-butyl pyrrolidinium [MBPyrro]{sup +}, 1-methyl-1-propyl piperidinium [MPPip]{sup +}, 1-methyl-1-butyl piperidinium [MBPip]{sup +}, 1-methyl-1-octylpyrrolidinium [MOPyrro]{sup +} and 1-methyl-1-octylpiperidinium [MOPip]{sup +} cations. These liquids provide new alternatives to pyridinium and imidazolium ILs. High thermal stability of an ionic liquid increases safety in applications like rechargeable lithium-ion batteries and other electrochemical devices. Thermal properties, ionic conductivities, viscosities, and mutual solubilities with water are reported. In addition, toxicities of selected ionic liquids have been measured using a human cancer cell-line. The ILs studied here are sparingly soluble in water but hygroscopic. We show some structure-property relationships that may help to design green solvents for specific applications. While ionic liquids are claimed to be environmentally-benign solvents, as yet few data have been published to support these claims.

  8. Portable liquid collection electrostatic precipitator

    DOE Patents [OSTI]

    Carlson, Duane C.; DeGange, John J.; Halverson, Justin E.

    2005-10-18T23:59:59.000Z

    A portable liquid collection electrostatic collection precipitator for analyzing air is provided which is a relatively small, self-contained device. The device has a tubular collection electrode, a reservoir for a liquid, and a pump. The pump pumps the liquid into the collection electrode such that the liquid flows down the exterior of the collection electrode and is recirculated to the reservoir. An air intake is provided such that air to be analyzed flows through an ionization section to ionize analytes in the air, and then flows near the collection electrode where ionized analytes are collected. A portable power source is connected to the air intake and the collection electrode. Ionizable constituents in the air are ionized, attracted to the collection electrode, and precipitated in the liquid. The precipitator may also have an analyzer for the liquid and may have a transceiver allowing remote operation and data collection.

  9. Holographic backgrounds from D-brane probes

    E-Print Network [OSTI]

    Micha Moskovic

    2015-01-09T23:59:59.000Z

    This thesis focuses on the derivation of holographic backgrounds from the field theory side, without using any supergravity equations of motion. Instead, we rely on the addition of probe D-branes to the stack of D-branes generating the background. From the field theory description of the probe branes, one can compute an effective action for the probes (in a suitable low-energy/near-horizon limit) by integrating out the background branes. Comparing this action with the generic probe D-brane action then allows to determine the holographic background dual to the considered field theory vacuum. In the first part, the required pre-requisites of field and string theory are recalled and this strategy to derive holographic backgrounds is explained in more detail on the basic case of D3-branes in flat space probed by a small number of D-instantons. The second part contains our original results, which have already appeared in arXiv:1301.3738, arXiv:1301.7062 and arXiv:1312.0621. We first derive the duals to three continuous deformations (Coulomb branch, $\\beta$ and non-commutative deformations) of N=4 super-Yang-Mills. We then derive the enhan\\c{c}on mechanism in a simple N=2 quiver gauge theory setup by using a fractional D-instanton as a probe and exploiting recent exact results on the Coulomb branch of N=2 quivers. Finally, we obtain the near-horizon D4-brane geometry by probing the D4-branes with a small number of D0-branes.

  10. Quantum probes for fractional Gaussian processes

    E-Print Network [OSTI]

    Matteo G. A. Paris

    2014-07-19T23:59:59.000Z

    We address the characterization of classical fractional random noise via quantum probes. In particular, we focus on estimation and discrimination problems involving the fractal dimension of the trajectories of a system subject to fractional Brownian noise. We assume that the classical degree of freedom exposed to the environmental noise is coupled to a quantum degree of freedom of the same system, e.g. its spin, and exploit quantum limited measurements on the spin part to characterize the classical fractional noise. More generally, our approach may be applied to any two-level system subject to dephasing perturbations described by fractional Brownian noise, in order to assess the precision of quantum limited measurements in the characterization of the external noise. In order to assess the performances of quantum probes we evaluate the Bures metric, as well as the Helstrom and the Chernoff bound, and optimize their values over the interaction time. We find that quantum probes may be successfully employed to obtain a reliable characterization of fractional Gaussian process when the coupling with the environment is weak or strong. In the first case decoherence is not much detrimental and for long interaction times the probe acquires information about the environmental parameters without being too much mixed. Conversely, for strong coupling, information is quickly impinged on the quantum probe and can effectively retrieved by measurements performed in the early stage of the evolution. In the intermediate situation, none of the two above effects take place: information is flowing from the environment to the probe too slowly compared to decoherence, and no measurements can be effectively employed to extract it from the quantum probe. The two regimes of weak- and strong-coupling are defined in terms of a threshold value of the coupling, which itself increases with the fractional dimension.

  11. Examination of Liquid Fluoride Salt Heat Transfer

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L [ORNL] [ORNL

    2014-01-01T23:59:59.000Z

    The need for high efficiency power conversion and energy transport systems is increasing as world energy use continues to increase, petroleum supplies decrease, and global warming concerns become more prevalent. There are few heat transport fluids capable of operating above about 600oC that do not require operation at extremely high pressures. Liquid fluoride salts are an exception to that limitation. Fluoride salts have very high boiling points, can operate at high temperatures and low pressures and have very good heat transfer properties. They have been proposed as coolants for next generation fission reactor systems, as coolants for fusion reactor blankets, and as thermal storage media for solar power systems. In each case, these salts are used to either extract or deliver heat through heat exchange equipment, and in order to design this equipment, liquid salt heat transfer must be predicted. This paper discusses the heat transfer characteristics of liquid fluoride salts. Historically, heat transfer in fluoride salts has been assumed to be consistent with that of conventional fluids (air, water, etc.), and correlations used for predicting heat transfer performance of all fluoride salts have been the same or similar to those used for water conventional fluids an, water, etc). A review of existing liquid salt heat transfer data is presented, summarized, and evaluated on a consistent basis. Less than 10 experimental data sets have been found in the literature, with varying degrees of experimental detail and measured parameters provided. The data has been digitized and a limited database has been assembled and compared to existing heat transfer correlations. Results vary as well, with some data sets following traditional correlations; in others the comparisons are less conclusive. This is especially the case for less common salt/materials combinations, and suggests that additional heat transfer data may be needed when using specific salt eutectics in heat transfer equipment designs. All of the data discussed above were taken under forced convective conditions (both laminar and turbulent). Some recent data taken at ORNL under free convection conditions are also presented and results discussed. This data was taken using a simple crucible experiment with an instrumented nickel heater inserted in the salt to induce natural circulation within the crucible. The data was taken over a temperature range of 550oC to 650oC in FLiNaK salt. This data covers both laminar and turbulent natural convection conditions, and is compared to existing forms of natural circulation correlations.

  12. Corrosion monitoring with hydrogen probes in the oilfield

    SciTech Connect (OSTI)

    Thomason, W.H.

    1984-05-01T23:59:59.000Z

    An overview of the application of hydrogen probes for corrosion monitoring in the oilfield is presented. The three basic types of hydrogen probes are described and their relative merits discussed. The construction and installation of a simple and inexpensive electrochemical hydrogen probe is described. Experiences with hydrogen probes in oilfield operations are discussed, and it is concluded from these experiences that production systems where hydrogen probes can provide useful corrosion data are limited.

  13. Liquid monobenzoxazine based resin system

    DOE Patents [OSTI]

    Tietze, Roger; Nguyen, Yen-Loan; Bryant, Mark

    2014-10-07T23:59:59.000Z

    The present invention provides a liquid resin system including a liquid monobenzoxazine monomer and a non-glycidyl epoxy compound, wherein the weight ratio of the monobenzoxazine monomer to the non-glycidyl epoxy compound is in a range of about 25:75 to about 60:40. The liquid resin system exhibits a low viscosity and exceptional stability over an extended period of time making its use in a variety of composite manufacturing methods highly advantageous.

  14. Supported liquid membrane electrochemical separators

    DOE Patents [OSTI]

    Pemsler, J. Paul (Lexington, MA); Dempsey, Michael D. (Revere, MA)

    1986-01-01T23:59:59.000Z

    Supported liquid membrane separators improve the flexibility, efficiency and service life of electrochemical cells for a variety of applications. In the field of electrochemical storage, an alkaline secondary battery with improved service life is described in which a supported liquid membrane is interposed between the positive and negative electrodes. The supported liquid membranes of this invention can be used in energy production and storage systems, electrosynthesis systems, and in systems for the electrowinning and electrorefining of metals.

  15. Carbon Dioxide Separation with Supported Ionic Liquid Membranes

    SciTech Connect (OSTI)

    Luebke, D.R.; Ilconich, J.B.; Pennline, H.W.; Myers, C.R.

    2007-05-01T23:59:59.000Z

    A practical form of CO2 capture at water-gas shift conditions in the IGCC process could serve the dual function of producing a pure CO2 stream for sequestration and forcing the equilibrium-limited shift reaction to completion enriching the stream in H2. The shift temperatures, ranging from the low temperature shift condition of 260C to the gasification condition of 900C, limit capture options by diminishing associative interactions which favor removal of CO2 from the gas stream. Certain sorption interactions, such as carbonate formation, remain available but generally involve exceptionally high sorbent regeneration energies that contribute heavily to parasitic power losses. Carbon dioxide selective membranes need only establish an equilibrium between the gas phase and sorption states in order to transport CO2, giving them a potential energetic advantage over other technologies. Supported liquid membranes take advantage of high, liquid phase diffusivities and a solution diffusion mechanism similar to that observed in polymeric membranes to achieve superior permeabilities and selectivites. The primary shortcoming of the supported liquid membranes demonstrated in past research has been the lack of stability caused by volatilization of the transport liquid. Ionic liquids, which possess high CO2 solubility relative to light gases such as H2, are excellent candidates for this type of membrane since they have negligible vapor pressure and are not susceptible to evaporation. A study has been conducted evaluating the use of ionic liquids including 1-hexyl-3-methyl-imidazolium bis(trifuoromethylsulfonyl)imide in supported ionic liquid membranes for the capture of CO2 from streams containing H2. In a joint project, researchers at the University of Notre Dame synthesized and characterized ionic liquids, and researchers at the National Energy Technology Laboratory incorporated candidate ionic liquids into supports and evaluated the resulting materials for membrane performance. Improvements to the ionic liquid and support have allowed testing of these supported ionic liquid membranes at temperatures up to 300C without loss of support mechanical stability or degradation of the ionic liquid. Substantial improvements in selectivity have also been observed at elevated temperature with the best membrane currently achieving optimum performance at 75C.

  16. Process for preparing liquid wastes

    DOE Patents [OSTI]

    Oden, Laurance L. (Albany, OR); Turner, Paul C. (Albany, OR); O'Connor, William K. (Lebanon, OR); Hansen, Jeffrey S. (Corvallis, OR)

    1997-01-01T23:59:59.000Z

    A process for preparing radioactive and other hazardous liquid wastes for treatment by the method of vitrification or melting is provided for.

  17. Selection of liquid-level monitoring method for the Oak Ridge National Laboratory inactive liquid low-level waste tanks, remedial investigation/feasibility study

    SciTech Connect (OSTI)

    Not Available

    1994-11-01T23:59:59.000Z

    Several of the inactive liquid low-level waste (LLLW) tanks at Oak Ridge National Laboratory contain residual wastes in liquid or solid (sludge) form or both. A plan of action has been developed to ensure that potential environmental impacts from the waste remaining in the inactive LLLW tank systems are minimized. This document describes the evaluation and selection of a methodology for monitoring the level of the liquid in inactive LLLW tanks. Criteria are established for comparison of existing level monitoring and leak testing methods; a preferred method is selected and a decision methodology for monitoring the level of the liquid in the tanks is presented for implementation. The methodology selected can be used to continuously monitor the tanks pending disposition of the wastes for treatment and disposal. Tanks that are empty, are scheduled to be emptied in the near future, or have liquid contents that are very low risk to the environment were not considered to be candidates for installing level monitoring. Tanks requiring new monitoring equipment were provided with conductivity probes; tanks with existing level monitoring instrumentation were not modified. The resulting data will be analyzed to determine inactive LLLW tank liquid level trends as a function of time.

  18. The Nexus of Energy & Water APS, Berkeley, CA

    E-Print Network [OSTI]

    Kammen, Daniel M.

    Freshwater Is A Small Part of the Total Supply Liquid Assets, Jill Boberg, RAND #12;Michael E. Webber, Ph There Are Two Main Cooling Approaches Open-Loop Cooling Closed-Loop Cooling Most water that is withdrawn and Water 16 March 5, 2011 The Thermoelectric Power Sector Uses Water for Cooling Withdrawals [gal

  19. North Dakota Water Resources Research Institute Annual Technical Report

    E-Print Network [OSTI]

    total PCBs and PCDFs in water samples. The objective was accomplished coupling solid-liquid extraction, namely water extraction, application of phosphorescence enhancers to the extraction membrane, and direct RTP detection on the extracting substrate. The water sample (10-100 mL) is processed through

  20. Lecs 2 and 3. Properties of air and water and Earth system; GFD1 AS509/OC512 Winter 2011

    E-Print Network [OSTI]

    sound speed (or `compressibility'), specific heat capacity, thermal expansion coefficient, freezing hydrogen molecules attract one another giving the liquid some long-range order. Water is a generally density than liquid water (most substances are more dense when frozen). The density of pure water, about

  1. Scanning probe microscopy: Sulfate minerals in scales and cements

    SciTech Connect (OSTI)

    Hall, C. [Schlumberger Cambridge Research (United Kingdom)

    1995-11-01T23:59:59.000Z

    The principles of scanning probe microscopy (SPM) are illustrated with examples from oilfield mineralogy, particularly emphasizing sulfate minerals involved in scale formation and cement hydration chemistry. The topography of the (010) cleavage surface of gypsum observed by atomic force microscopy shows atomically flat terraces separated by shallow steps often only one unit cell high. SPM allows direct observation of processes on mineral surfaces while they are in contact with solutions. The dissolution etching and crystal growth of gypsum and barite are discussed and rates of step migration estimated. The orientation of steps is related to the crystallographic axes. The action of phosphonate crystal growth inhibitor on gypsum and of a chelating scale solvent on barite are also shown. The multiphase microstructure of an oilwell cement clinker is described in relation to its hydration chemistry in contact with water and its reaction with sulfate ions.

  2. Protein structure and hydration probed by SANS and osmotic stress

    SciTech Connect (OSTI)

    Rau, Dr. Donald [National Institutes of Health

    2008-01-01T23:59:59.000Z

    Interactions governing protein folding, stability, recognition, and activity are mediated by hydration. Here, we use small-angle neutron scattering coupled with osmotic stress to investigate the hydration of two proteins, lysozyme and guanylate kinase (GK), in the presence of solutes. By taking advantage of the neutron contrast variation that occurs upon addition of these solutes, the number of protein-associated (solute-excluded) water molecules can be estimated from changes in both the zero-angle scattering intensity and the radius of gyration. Poly(ethylene glycol) exclusion varies with molecular weight. This sensitivity can be exploited to probe structural features such as the large internal GK cavity. For GK, small-angle neutron scattering is complemented by isothermal titration calorimetry with osmoticstress to also measure hydration changes accompanying ligand binding. These results provide a framework for studying other biomolecular systems and assemblies using neutron scattering together with osmotic stress.

  3. Microscopic Analysis of Corn Fiber Using Corn Starch- and Cellulose-Specific Molecular Probes

    SciTech Connect (OSTI)

    Porter, S. E.; Donohoe, B. S.; Beery, K. E.; Xu, Q.; Ding, S.-Y.; Vinzant, T. B.; Abbas, C. A.; Himmel, M. E.

    2007-09-01T23:59:59.000Z

    Ethanol is the primary liquid transportation fuel produced from renewable feedstocks in the United States today. The majority of corn grain, the primary feedstock for ethanol production, has been historically processed in wet mills yielding products such as gluten feed, gluten meal, starch, and germ. Starch extracted from the grain is used to produce ethanol in saccharification and fermentation steps; however the extraction of starch is not 100% efficient. To better understand starch extraction during the wet milling process, we have developed fluorescent probes that can be used to visually localize starch and cellulose in samples using confocal microscopy. These probes are based on the binding specificities of two types of carbohydrate binding modules (CBMs), which are small substrate-specific protein domains derived from carbohydrate degrading enzymes. CBMs were fused, using molecular cloning techniques, to a green fluorescent protein (GFP) or to the red fluorescent protein DsRed (RFP). Using these engineered probes, we found that the binding of the starch-specific probe correlates with starch content in corn fiber samples. We also demonstrate that there is starch internally localized in the endosperm that may contribute to the high starch content in corn fiber. We also surprisingly found that the cellulose-specific probe did not bind to most corn fiber samples, but only to corn fiber that had been hydrolyzed using a thermochemical process that removes the residual starch and much of the hemicellulose. Our findings should be of interest to those working to increase the efficiency of the corn grain to ethanol process.

  4. Molecular dynamics simulations of water structure and diffusion in silica nanopores

    E-Print Network [OSTI]

    Bourg, I.C.

    2013-01-01T23:59:59.000Z

    the extended simple point charge (SPC/E) water model 64 forcoefficient of bulk liquid SPC/E water (D 0 = 2.4 ? 0.4 ?To account for the fact that the SPC/E model over- estimates

  5. Dynamics of water and aqueous protons studied using ultrafast multi-dimensional infrared spectroscopy

    E-Print Network [OSTI]

    Ramasesha, Krupa

    2013-01-01T23:59:59.000Z

    Liquid water consists of a highly dynamic network of hydrogen bonds, which evolves on timescales ranging from tens of femtoseconds to a few picoseconds. The fast structural evolution of water's hydrogen bond network is at ...

  6. Turbid water Clear water

    E-Print Network [OSTI]

    Jaffe, Jules

    : The submersible laser bathymetric (LBath) optical system is capable of simultaneously providing visual images- dynamical wing. This underwater package is pulled through the water by a single towed cable with fiber optic special high energy density optical fibers. A remote Pentium based PC also at the surface is used

  7. Gamma-ray blind beta particle probe

    DOE Patents [OSTI]

    Weisenberger, Andrew G. (Grafton, VA)

    2001-01-01T23:59:59.000Z

    An intra-operative beta particle probe is provided by placing a suitable photomultiplier tube (PMT), micro channel plate (MCP) or other electron multiplier device within a vacuum housing equipped with: 1) an appropriate beta particle permeable window; and 2) electron detection circuitry. Beta particles emitted in the immediate vicinity of the probe window will be received by the electron multiplier device and amplified to produce a detectable signal. Such a device is useful as a gamma insensitive, intra-operative, beta particle probe in surgeries where the patient has been injected with a beta emitting radiopharmaceutical. The method of use of such a device is also described, as is a position sensitive such device.

  8. Remote adjustable focus Raman spectroscopy probe

    DOE Patents [OSTI]

    Schmucker, John E. (Hurt, VA); Blasi, Raymond J. (Harrison City, PA); Archer, William B. (Bethel Park, PA)

    1999-01-01T23:59:59.000Z

    A remote adjustable focus Raman spectroscopy probe allows for analyzing Raman scattered light from a point of interest external probe. An environmental barrier including at least one window separates the probe from the point of interest. An optical tube is disposed adjacent to the environmental barrier and includes a long working length compound lens objective next to the window. A beam splitter and a mirror are at the other end. A mechanical means is used to translated the prove body in the X, Y, and Z directions resulting in a variable focus optical apparatus. Laser light is reflected by the beam splitter and directed toward the compound lens objective, then through the window and focused on the point of interest. Raman scattered light is then collected by the compound lens objective and directed through the beam splitter to a mirror. A device for analyzing the light, such as a monochrometer, is coupled to the mirror.

  9. Water Intoxication

    E-Print Network [OSTI]

    Lingampalli, Nithya

    2013-01-01T23:59:59.000Z

    2008, May 14). Too much water raises seizure risk in babies.id=4844 9. Schoenly, Lorry. Water Intoxication and Inmates:article/246650- overview>. 13. Water intoxication alert. (

  10. Liquid honing evaluation

    SciTech Connect (OSTI)

    Slanina, J.T.

    1991-07-01T23:59:59.000Z

    The conveyorized wetblast machine was characterized for epoxy/glass and polyimide/glass multilayers using a 12-run Plackett-Burman screening experiment and a four-variable factorial experiment. Test panels were processed using slurry and water mixtures and water only. Plated-through-holes were evaluated after wetblasting and copper plating for plating characteristics. Test panels were wetblasted and processed through photolithography operations. Photoresist adhesion characteristics were evaluated. As a result of this study, the optimum production conditions were determined for slurry concentration, blast pressure, oscillator speed, conveyor speed, and blast gun distance. 2 figs., 18 tabs.

  11. Liquid crystal polyester thermosets

    DOE Patents [OSTI]

    Benicewicz, Brian C. (Los Alamos, NM); Hoyt, Andrea E. (Los Alamos, NM)

    1992-01-01T23:59:59.000Z

    The present invention provides (1) curable liquid crystalline polyester monomers represented by the formula: R.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3 --R.sup.2 where R.sup.1 and R.sup.2 are radicals selected from the group consisting of maleimide, substituted maleimide, nadimide, substituted naimide, ethynyl, and (C(R.sup.3).sub.2).sub.2 where R.sup.3 is hydrogen with the proviso that the two carbon atoms of (C(R.sup.3).sub.2).sub.2 are bound on the aromatic ring of A.sup.1 or A.sup.3 to adjacent carbon atoms, A.sup.1 and A.sup.3 are 1,4-phenylene and the same where said group contains one or more substituents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro lower alkyl, e.g., methyl, ethyl, or propyl, alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl, e.g., trifluoromethyl, pentafluoroethyl and the like, A.sup.2 is selected from the group consisting of 1,4-phenylene, 4,4'-biphenyl, 2,6-naphthylene and the same where said groups contain one or more substituents selected from the group consisting of halo, e.g., fluoro, chloro, bromo, or iodo, nitro, lower alkyl, e.g., methyl, ethyl, and propyl, lower alkoxy, e.g., methoxy, ethoxy, or propoxy, and fluoroalkyl or fluoroalkoxy, e.g., trifluoromethyl, pentafluoroethyl and the like, and B.sup.1 and B.sup.2 are selected from the group consisting of --C(O)--O-- and --O--C(O)--, (2) thermoset liquid crystalline polyester compositions comprised of heat-cured segments derived from monomers represented by the formula: R.sup.1 --A.sup.1 --B.sup.1 --A.sup.2 --B.sup.2 --A.sup.3 --R.sup.2 as described above, (3) curable blends of at least two of the polyester monomers and (4) processes of preparing the curable liquid crystalline polyester monomers.

  12. Lithium-loaded liquid scintillators

    DOE Patents [OSTI]

    Dai, Sheng (Knoxville, TN); Kesanli, Banu (Mersin, TR); Neal, John S. (Knoxville, TN)

    2012-05-15T23:59:59.000Z

    The invention is directed to a liquid scintillating composition containing (i) one or more non-polar organic solvents; (ii) (lithium-6)-containing nanoparticles having a size of up to 10 nm and surface-capped by hydrophobic molecules; and (iii) one or more fluorophores. The invention is also directed to a liquid scintillator containing the above composition.

  13. Scintillation probe with photomultiplier tube saturation indicator

    DOE Patents [OSTI]

    Ruch, Jeffrey F. (Bethel Park, PA); Urban, David J. (Glassport, PA)

    1996-01-01T23:59:59.000Z

    A photomultiplier tube saturation indicator is formed by supplying a supplemental light source, typically an light emitting diode (LED), adjacent to the photomultiplier tube. A switch allows the light source to be activated. The light is forwarded to the photomultiplier tube by an optical fiber. If the probe is properly light tight, then a meter attached to the indicator will register the light from the LED. If the probe is no longer light tight, and the saturation indicator is saturated, no signal will be registered when the LED is activated.

  14. Monitoring system for a liquid-cooled nuclear fission reactor

    DOE Patents [OSTI]

    DeVolpi, Alexander (Bolingbrook, IL)

    1987-01-01T23:59:59.000Z

    A monitoring system for detecting changes in the liquid levels in various regions of a water-cooled nuclear power reactor, viz., in the downcomer, in the core, in the inlet and outlet plenums, at the head, and elsewhere; and also for detecting changes in the density of the liquid in these regions. A plurality of gamma radiation detectors are used, arranged vertically along the outside of the reactor vessel, and collimator means for each detector limits the gamma-radiation it receives as emitting from only isolated regions of the vessel. Excess neutrons produced by the fission reaction will be captured by the water coolant, by the steel reactor walls, or by the fuel or control structures in the vessel. Neutron capture by steel generates gamma radiation having an energy level of the order of 5-12 MeV, whereas neutron capture by water provides an energy level of approximately 2.2 MeV, and neutron capture by the fission fuel or its cladding provides an energy level of 1 MeV or less. The intensity of neutron capture thus changes significantly at any water-metal interface. Comparative analysis of adjacent gamma detectors senses changes from the normal condition with liquid coolant present to advise of changes in the presence and/or density of the coolant at these specific regions. The gamma detectors can also sense fission-product gas accumulation at the reactor head to advise of a failure of fuel-pin cladding.

  15. Water Quality

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of desalination research. The primary technological method of generating additional water supplies is through desalination and enhanced water reuse and recycling technologies....

  16. Water Efficiency

    Energy Savers [EERE]

    Water Efficiency Hosted by: FEDERAL UTILITY PARTNERSHIP WORKING GROUP SEMINAR November 5-6, 2014 Cape Canaveral, Florida WATER EFFICIENCY Federal Utility Partnership Working Group...

  17. Temperature-dependent vibrational relaxation in polyatomic liquids: Picosecond infrared pump-probe experiments

    E-Print Network [OSTI]

    Fayer, Michael D.

    , California 94305 (Received 24 November 1993; accepted 10 March 1994) Vibrational lifetimes of metal carbonyl those in CHCls. A decrease in the vibrational lifetime with temperature is seen for both metal carbonyls a detailed study of the temperature-dependent relax- ation of a vibrational mode of two molecules, tungsten

  18. Terahertz Spectroscopy of Individual Single-Walled Carbon Nanotubes as a Probe of Luttinger Liquid Physics

    E-Print Network [OSTI]

    Prober, Daniel E.

    researchers Aviad Frydman, Misha Reznikov, Bertrand Reulet, and Venkat Chandrasekhar for the insight

  19. Method for treating liquid wastes

    DOE Patents [OSTI]

    Katti, K.V.; Volkert, W.A.; Singh, P.; Ketring, A.R.

    1995-12-26T23:59:59.000Z

    The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering {sup 99}Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of {sup 99}TcO{sub 4}{sup {minus}} from aqueous solutions into organic solvents or mixed organic/polar media, extraction of {sup 99}Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester {sup 99}Tc from those liquids. 6 figs.

  20. Method for treating liquid wastes

    DOE Patents [OSTI]

    Katti, Kattesh V. (Columbia, MO); Volkert, Wynn A. (Columbia, MO); Singh, Prahlad (Columbia, MO); Ketring, Alan R. (Columbia, MO)

    1995-01-01T23:59:59.000Z

    The method of treating liquid waste in a media is accomplished by exposing the media to phosphinimines and sequestering .sup.99 Tc from the media by the phosphinimine (PN) functionalities. The system for treating the liquid waste in the media includes extraction of .sup.99 TcO.sub.4.sup.- from aqueous solutions into organic solvents or mixed organic/polar media, extraction of .sup.99 Tc from solutions on a solid matrix by using a container containing PN functionalities on solid matrices including an inlet and outlet for allowing flow of media through an immobilized phosphinimine ligand system contained within the container. Also, insoluble suspensions of phosphinimine functionalities on solid matrices in liquid solutions or present on supported liquid membranes (SLM) can be used to sequester .sup.99 Tc from those liquids.

  1. Parameter exploration of optically trapped liquid aerosols

    E-Print Network [OSTI]

    D. R. Burnham; P. J. Reece; D. McGloin

    2010-06-24T23:59:59.000Z

    When studying the motion of optically trapped particles on the $\\mu s$ time scale, in low viscous media such as air, inertia cannot be neglected. Resolution of unusual and interesting behaviour not seen in colloidal trapping experiments is possible. In attempt to explain the phenomena we use power spectral methods to perform a parameter study of the Brownian motion of optically trapped liquid aerosol droplets concentrated around the critically damped regime. We present evidence that the system is suitably described by a simple harmonic oscillator model which must include a description of Fax\\'{e}n's correction, but not necessarily frequency dependent hydrodynamic corrections to Stokes' law. We also provide results describing how the system behaves under several variables and discuss the difficulty in decoupling the parameters responsible for the observed behaviour. We show that due to the relatively low dynamic viscosity and high trap stiffness it is easy to transfer between over- and under-damped motion by experimentally altering either trap stiffness or damping. Our results suggest stable aerosol trapping may be achieved in under-damped conditions, but the onset of deleterious optical forces at high trapping powers prevents the probing of the upper stability limits due to Brownian motion.

  2. In-situ continuous water monitoring system

    DOE Patents [OSTI]

    Thompson, C.V.; Wise, M.B.

    1998-03-31T23:59:59.000Z

    An in-situ continuous liquid monitoring system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container by the flow of carrier gas into the liquid directing device. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectrometer and the volatile components are continuously analyzed by the mass spectrometer. 2 figs.

  3. In-situ continuous water monitoring system

    DOE Patents [OSTI]

    Thompson, Cyril V. (Knoxville, TN); Wise, Marcus B. (Kingston, TN)

    1998-01-01T23:59:59.000Z

    An in-situ continuous liquid monitoring system for continuously analyzing volatile components contained in a water source comprises: a carrier gas supply, an extraction container and a mass spectrometer. The carrier gas supply continuously supplies the carrier gas to the extraction container and is mixed with a water sample that is continuously drawn into the extraction container by the flow of carrier gas into the liquid directing device. The carrier gas continuously extracts the volatile components out of the water sample. The water sample is returned to the water source after the volatile components are extracted from it. The extracted volatile components and the carrier gas are delivered continuously to the mass spectrometer and the volatile components are continuously analyzed by the mass spectrometer.

  4. Vibrational Sum Frequency Spectroscopy and Molecular Dynamics Simulation of the Carbon Tetrachloride-Water and 1,2-Dichloroethane-Water Interfaces

    E-Print Network [OSTI]

    Richmond, Geraldine L.

    and bonding at the carbon tetrachloride-water (CCl4-H2O) and the 1,2-dichloroethane-water (DCE-H2O) liquidVibrational Sum Frequency Spectroscopy and Molecular Dynamics Simulation of the Carbon Tetrachloride-Water and 1,2-Dichloroethane-Water Interfaces Dave S. Walker, Fred G. Moore, and Geraldine L

  5. The nanofluidics can explain ascent of water in tallest trees

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    The nanofluidics can explain ascent of water in tallest trees Henri Gouin Abstract. In Amazing, inhomogeneous liquid nanolayers wet the xylem walls of microtubes. The nanofluidic model of crude sap in tall

  6. Vibrational dynamics in water from the molecule's perspective

    E-Print Network [OSTI]

    Eaves, Joel David, 1976-

    2005-01-01T23:59:59.000Z

    Liquid water is a fascinating substance, ubiquitous in chemistry, physics, and biology. Its remarkable physical and chemical properties stem from the intricate network of hydrogen bonds that connect molecular participants. ...

  7. NOCHAR Polymers: An Aqueous and Organic Liquid Solidification Process for Cadarache LOR (Liquides Organiques Radioactifs) - 13195

    SciTech Connect (OSTI)

    Vaudey, Claire-Emilie; Renou, Sebastien; Porco, Julien [AREVA CL BU, STMI ZAC de Courcelle 1 route de la Noue 91196 Gif-sur-Yvette (France)] [AREVA CL BU, STMI ZAC de Courcelle 1 route de la Noue 91196 Gif-sur-Yvette (France); Kelley, Dennis [Pacific World Trade, Inc. Hillsdale Technical Center 6970 Hillsdale Court Indianapolis, Indiana 46250 (United States)] [Pacific World Trade, Inc. Hillsdale Technical Center 6970 Hillsdale Court Indianapolis, Indiana 46250 (United States); Cochaud, Chantal [CEA Cadarache, DSN/SGTD, 13108 St Paul Lez Durance Cedex (France)] [CEA Cadarache, DSN/SGTD, 13108 St Paul Lez Durance Cedex (France); Serrano, Roger [CEA Marcoule, DPAD, BP 17171, 30207 Bagnols sur Ceze Cedex (France)] [CEA Marcoule, DPAD, BP 17171, 30207 Bagnols sur Ceze Cedex (France)

    2013-07-01T23:59:59.000Z

    To handle the Very Low Level Waste (VLLW) and the Low Level Waste (LLW) in France, two options can be considered: the incineration at CENTRACO facility and the disposal facility on ANDRA sites. The waste acceptance in these radwaste routes is dependent upon the adequacy between the waste characteristics (physical chemistry and radiological) and the radwaste route specifications. If the waste characteristics are incompatible with the radwaste route specifications (presence of significant quantities of chlorine, fluorine, organic component etc or/and high activity limits), it is necessary to find an alternative solution that consists of a waste pre-treatment process. In the context of the problematic Cadarache LOR (Liquides Organiques Radioactifs) waste streams, two radioactive scintillation cocktails have to be treated. The first one is composed of organic liquids at 13.1 % (diphenyloxazol, mesitylene, TBP, xylene) and water at 86.9 %. The second one is composed of TBP at 8.6 % and water at 91.4 %. They contain chlorine, fluorine and sulphate and have got alpha/beta/gamma spectra with mass activities equal to some kBq.g{sup -1}. Therefore, tritium is present and creates the second problematic waste stream. As a consequence, in order for disposal acceptance at the ANDRA site, it is necessary to pre-treat the waste. The NOCHAR polymers as an aqueous and organic liquid solidification process seem to be an adequate solution. Indeed, these polymers constitute an important variety of products applied to the treatment of radioactive aqueous and organic liquids (solvent, oil, solvent/oil mixing etc) and sludge through a mechanical and chemical solidification process. For Cadarache LOR, N910 and N960 respectively dedicated to the organic and aqueous liquids solidification are considered. With the N910, the organic waste solidification occurs in two steps. As the organic liquid travels moves through the polymer strands, the strands swell and immobilise the liquid. Then as the polymer-organic cure, over time, the polymer continues to collapse on the organic to create a permanent bond. The N960 has the ability to absorb aqueous waste up to 100 times its own weight. It creates a strong mechanical bond which permanently traps the contamination imbedded in the aqueous liquids. As a consequence, these two polymers seem to be able to constitute a suitable solidification matrix for a final acceptance in storage on ANDRA sites. In order to validate the polymers as an acceptable aqueous and organic solidification process for Cadarache LOR, some solidification tests realized with N910 and N960, have been carried out for different Waste/Polymer ratios. The determination of the best Waste/Polymer ratio and of the optimal experimental parameters has been made through an exudation test. Indeed, the process prevents leaching and it results in the absence of residual free organic or aqueous liquid which is forbidden in storage by ANDRA specifications. With these test results, we generated scientific data which are fundamental to obtain an ANDRA agreement. As a conclusion, the aim of this study is to demonstrate that the solidification by polymers can constitute a pre-treatment solution for Cadarache LOR and more generally, for various organic and mixed organic/aqueous waste which can not be directly acceptable at CENTRACO facility or at ANDRA storage sites. This work is, therefore, a solid background to demonstrate the feasibility of the waste pre-treatment by solidification with polymers and to encourage the development of this process. (authors)

  8. Corrosion mitigation considerations in planning for zero liquid discharge

    SciTech Connect (OSTI)

    DeWitt-Dick, D.B. [Ashland Chemical Co., Portland, TX (United States). Drew Industrial Division; Lee, B. [Ashland Chemical Co., Boonton, NJ (United States). Drew Industrial Division

    1995-12-01T23:59:59.000Z

    A reduction in the availability and in the quality of water, coupled with more significantly more stringent water discharge restrictions, has resulted in increasing numbers of industrial complexes investigating water reuse and zero liquid discharge. Their investigation generally includes a survey of the potential impact of increased dissolved solids on the formation of mineral salt scales on heat transfer surfaces. These predictive tools are readily available and fairly accurate. The prediction of corrosion potential, however, is not as clearly defined, and as a consequence, little consideration is given to the effects of increased solids on corrosion. In addition to the potential for accelerated corrosion related to increased dissolved solids, many reuse waters contain elevated levels of biological activity and are rich in the nutrients that feed these micro organisms. This paper looks at the reasons for selecting zero liquid discharge as a means of water conservation and discharge reduction, the unit operations available to achieve these goals, and the corrosion mechanisms and mitigation associated with reuse water.

  9. Singular Limits in Polymer Stabilized Liquid Crystals

    E-Print Network [OSTI]

    1910-31-00T23:59:59.000Z

    We investigate equilibrium configurations for a polymer stabilized liquid crys- tal material ... eling the cross section of the liquid crystal-polymer fiber composite.

  10. Imaging Liquids Using Microfluidic Cells. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the difficulty in working with liquids with high volatility. Recent development in microfluidics enabled and increased our capabilities to study liquid in situ using surface...

  11. Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...

    Broader source: Energy.gov (indexed) [DOE]

    Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

  12. Probing nuclear matter with jet conversions

    E-Print Network [OSTI]

    Liu, W.; Fries, Rainer J.

    2008-01-01T23:59:59.000Z

    We discuss the flavor of leading jet partons as a valuable probe of nuclear matter. We point out that the coupling of jets to nuclear matter naturally leads to an alteration of jet chemistry even at high transverse momentum PT. In particular...

  13. Radiation Belt Storm Probes Ion Composition Experiment

    E-Print Network [OSTI]

    current produced the "bays" (decreases in the ground-level geomagnetic field) measured in magnetogram current" around Earth and its association with geomagnetic storms began in the early days of the twentieth Storm Probes (RBSP) spacecraft is the magnetosphere ring current instrument that will provide data

  14. Vertically aligned nanostructure scanning probe microscope tips

    DOE Patents [OSTI]

    Guillorn, Michael A.; Ilic, Bojan; Melechko, Anatoli V.; Merkulov, Vladimir I.; Lowndes, Douglas H.; Simpson, Michael L.

    2006-12-19T23:59:59.000Z

    Methods and apparatus are described for cantilever structures that include a vertically aligned nanostructure, especially vertically aligned carbon nanofiber scanning probe microscope tips. An apparatus includes a cantilever structure including a substrate including a cantilever body, that optionally includes a doped layer, and a vertically aligned nanostructure coupled to the cantilever body.

  15. Probe and method for DNA detection

    SciTech Connect (OSTI)

    Yeh, Hsin-Chih; Werner, James Henry; Sharma, Jaswinder Kumar; Martinez, Jennifer Suzanne

    2013-07-02T23:59:59.000Z

    A hybridization probe containing two linear strands of DNA lights up upon hybridization to a target DNA using silver nanoclusters that have been templated onto one of the DNA strands. Hybridization induces proximity between the nanoclusters on one strand and an overhang on the other strand, which results in enhanced fluorescence emission from the nanoclusters.

  16. Astrophysikalisches Institut Potsdam Probes of Dark Energy

    E-Print Network [OSTI]

    Astrophysikalisches Institut Potsdam Probes of Dark Energy using Cosmological Simulations Nonlinear component, called dark energy. This unknown energy causes the expansion of the universe to accelerate theoretical model of dark energy has been developed. Instead a number of models have been proposed that range

  17. Water Heaters and Hot Water Distribution Systems

    E-Print Network [OSTI]

    Lutz, Jim

    2012-01-01T23:59:59.000Z

    the temperature of the residual water encountered by theof hot water and the residual water might occur: (1) thehot water might drive the residual water through the piping

  18. Water Heaters and Hot Water Distribution Systems

    E-Print Network [OSTI]

    Lutz, Jim

    2012-01-01T23:59:59.000Z

    Transportation Water Heaters and Hot Water DistributionLaboratory). 2008. Water Heaters and Hot Water Distributionfor instantaneous gas water heaters; and pressure loss

  19. Organo luminescent semiconductor nanocrystal probes for biological applications and process for making and using such probes

    DOE Patents [OSTI]

    Weiss, Shimon (Pinole, CA); Bruchez, Jr., Marcel (Albany, CA); Alivisatos, Paul (Oakland, CA)

    2002-01-01T23:59:59.000Z

    A semiconductor nanocrystal compound is described capable of linking to an affinity molecule. The compound comprises (1) a semiconductor nanocrystal capable of emitting electromagnetic radiation and/or absorbing energy, and/or scattering or diffracting electromagnetic radiation--when excited by an electromagnetic radiation source or a particle beam; and (2) at least one linking agent, having a first portion linked to the semiconductor nanocrystal and a second portion capable of linking to an affity molecule. The compound is linked to an affinity molecule to form a semiconductor nanocrystal probe capable of bonding with a detectable substance. Subsequent exposure to excitation energy will excite the semiconductor nanocrystal in he probe, causing the emission of electromagnetic radiation. Further described are processes for respectively: making the semiconductor nanocrystal compound; making the semiconductor nanocrystal probe; and using the probe to determine the presence of a detectable substance in a material.

  20. Organo luminescent semiconductor nanocrystal probes for biological applications and process for making and using such probes

    DOE Patents [OSTI]

    Weiss, Shimon (Pinole, CA); Bruchez, Jr., Marcel (Albany, CA); Alivisatos, Paul (Oakland, CA)

    2004-03-02T23:59:59.000Z

    A semiconductor nanocrystal compound is described capable of linking to an affinity molecule. The compound comprises (1) a semiconductor nanocrystal capable of emitting electromagnetic radiation and/or absorbing energy, and/or scattering or diffracting electromagnetic radiation--when excited by an electromagnetic radiation source or a particle beam; and (2) at least one linking agent, having a first portion linked to the semiconductor nanocrystal and a second portion capable of linking to an affinity molecule. The compound is linked to an affinity molecule to form a semiconductor nanocrystal probe capable of bonding with a detectable substance. Subsequent exposure to excitation energy will excite the semiconductor nanocrystal in the probe, causing the emission of electromagnetic radiation. Further described are processes for respectively: making the semiconductor nanocrystal compound; making the semiconductor nanocrystal probe; and using the probe to determine the presence of a detectable substance in a material.