National Library of Energy BETA

Sample records for liquid water paths

  1. ARM - Measurement - Liquid water path

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    path ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Liquid water path A measure of the weight of the liquid water droplets in the atmosphere above a unit surface area on the earth, given in units of kg m-2. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument

  2. Monitoring of Precipitable Water Vapor and Cloud Liquid Path...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Monitoring of Precipitable Water Vapor and Cloud Liquid Path from Scanning Microwave ... used to measure atmospheric precipitable water vapor (PWV) and cloud liquid path (CLP). ...

  3. An Evaluation of MWR Retrievals of Liquid Water Path

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Evaluation of MWR Retrievals of Liquid Water Path and Precipitable Water Vapor R. T. Marchand and T. P. Ackerman Pacific Northwest National Laboratory Richland, Washington Introduction This paper offers some observations on the quality of Microwave Radiometer (MWR) retrievals of precipitable water vapor (PWV) and liquid water path (LWP). The paper shows case study comparisons between the standard "statistical" approach and those obtained using an iterative solution of the microwave

  4. Comparison of Cloud Fraction and Liquid Water Path between ECMWF...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Comparison of Cloud Fraction and Liquid Water Path between ECMWF Simulations and ARM Long-term Observations at the NSA Site Ming Zhao (mzhao@uwyo.edu) and Zhien Wang ...

  5. MWRRET Value-Added Product: The Retrieval of Liquid Water Path...

    Office of Scientific and Technical Information (OSTI)

    MWRRET Value-Added Product: The Retrieval of Liquid Water Path and Precipitable Water Vapor from Microwave Radiometer (MWR) Data Sets (Revision 2) Citation Details In-Document ...

  6. Equations Governing Space-Time Variability of Liquid Water Path in Stratus Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Equations Governing Space-Time Variability of Liquid Water Path in Stratus Clouds K. Ivanova Pennsylvania State University University Park, Pennsylvania T. P. Ackerman Pacific Northwest National Laboratory Richland, Washington M. Ausloos University of Liège B-4000 Liège, Belgium Abstract We present a method on how to derive an underlying mathematical (statistical or model free) equation for a liquid water path (LWP) signal directly from empirical data. The evolution of the probability density

  7. Remote Spectroscopic Sounding of Liquid Water Path in Thick Clouds in Winter Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Remote Spectroscopic Sounding of Liquid Water Path in Thick Clouds in Winter Conditions S. V. Dvoryashin and G. S. Golitsyn A. M. Obukhov Institute of Atmospheric Physics Russian Academy of Sciences Moscow, Russia The liquid water path (LWP) in mixed clouds is restored based on remote measurements of spectral brightness of a cloudy layer in the spectral range 2.15-2.35µm. The results of spectroscopic sounding of dense clouds sounding are presented. Introduction Since the 1980s, in A. M. Obukhov

  8. Validation of Satellite-Derived Liquid Water Paths Using ARM SGP Microwave Radiometers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Satellite-Derived Liquid Water Paths Using ARM SGP Microwave Radiometers M. M. Khaiyer and J. Huang Analytical Services & Materials, Inc. Hampton, Virginia P. Minnis, B. Lin, and W. L. Smith, Jr. National Aeronautics and Space Administration Langley Research Center Hampton, Virginia A. Fan Science Applications International Corporation Hampton, Virginia A. Rapp Colorado State University Fort Collins, Colorado Introduction Satellites are useful for monitoring climatological parameters over

  9. Observed and simulated temperature dependence of the liquid water path of low clouds

    SciTech Connect (OSTI)

    Del Genio, A.D.; Wolf, A.B.

    1996-04-01

    Data being acquired at the Atmospheric Radiation Measurement (ARM) Southern great Plains (SGP) Cloud and Radiation Testbed (CART) site can be used to examine the factors determining the temperature dependence of cloud optical thickness. We focus on cloud liquid water and physical thickness variations which can be derived from existing ARM measurements.

  10. ARM - Measurement - Ice water path

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    path ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Ice water path A measure of the weight of the ice particles in the atmosphere above a unit surface area in kg m-2. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements,

  11. A New Model for Liquid Water Absorption

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Model for Liquid Water Absorption For original submission and image(s), see ARM Research Highlights http://www.arm.gov/science/highlights/ Research Highlight Liquid water path (LWP) is a critical measurement for a wide range of atmospheric studies, as the amount of liquid in a cloud is critical to understanding many cloud processes. For example, the radiative impact of the cloud (in both the longwave and shortwave portions of the spectrum) depends heavily on the LWP. Thus, the Atmospheric

  12. Determining Cloud Ice Water Path from High-Frequency Microwave...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determining Cloud Ice Water Path from High-Frequency Microwave Measurements G. Liu ... A better understanding of cloud water content and its large-scale distribution ...

  13. Supercooled liquid water Estimation Tool

    Energy Science and Technology Software Center (OSTI)

    2012-05-04

    The Cloud Supercooled liquid water Estimation Tool (SEET) is a user driven Graphical User Interface (GUI) that estimates cloud supercooled liquid water (SLW) content in terms of vertical column and total mass from Moderate resolution Imaging Supercooled liquid water Estimation Tool Spectroradiometer (MODIS) spatially derived cloud products and realistic vertical cloud parameterizations that are user defined. It also contains functions for post-processing of the resulting data in tabular and graphical form.

  14. Identifying the primitive path mesh in entangled polymer liquids.

    SciTech Connect (OSTI)

    Sukumaran, Sathish K.; Kremer, Kurt; Grest, Gary Stephen; Everaers, Ralf

    2004-10-01

    Similar to entangled ropes, polymer chains cannot slide through each other. These topological constraints, the so-called entanglements, dominate the viscoelastic behavior of high-molecular-weight polymeric liquids. Tube models of polymer dynamics and rheology are based on the idea that entanglements confine a chain to small fluctuations around a primitive path which follows the coarse-grained chain contour. To establish the microscopic foundation for these highly successful phenomenological models, we have recently introduced a method for identifying the primitive path mesh that characterizes the microscopic topological state of computer-generated conformations of long-chain polymer melts and solutions. Here we give a more detailed account of the algorithm and discuss several key aspects of the analysis that are pertinent for its successful use in analyzing the topology of the polymer configurations. We also present a slight modification of the algorithm that preserves the previously neglected self-entanglements and allows us to distinguish between local self-knots and entanglements between distant sections of the same chain. Our results indicate that the latter make a negligible contribution to the tube and that the contour length between local self-knots, N{sub 1k} is significantly larger than the entanglement length N{sub e}.

  15. ARM - Measurement - Liquid water content

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    content ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Liquid water content The concentration (mass/vol) of liquid water droplets in a cloud. Categories Cloud Properties Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including those recorded

  16. Determination of Ice Water Path Over the ARM SGP Using Combined...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Determination of Ice Water Path Over the ARM SGP Using Combined Surface and Satellite ... Global information of cloud ice water path (IWP) is urgently needed for testing ...

  17. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    2004-02-19

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  18. ARM: Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Maria Cadeddu

    Microwave Radiometer data (MWR Profiles - QME), water vapor, temp, cloud liquid water, precip water retrievals

  19. ARM - PI Product - Large Scale Ice Water Path and 3-D Ice Water Content

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsLarge Scale Ice Water Path and 3-D Ice Water Content ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send PI Product : Large Scale Ice Water Path and 3-D Ice Water Content Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM

  20. Flight Path 5

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    05 Target 1 Flight Path 05 (1FP05) utilizes low-energy neutrons from a water moderator on the 1L target. Target 1 Flight Path 05 (ER1) Target 1 Flight Path 05 (ER1) utilizes thermalized neutrons from the 1L target. This flight path is located in experiment building ER-1 (MPF-30) at the Manual Lujan Jr. Neutron Scattering Center at LANSCE. The flight path utilizes a liquid mercury shutter to control the neutron beam transmission from the target. The relatively short flight path (6 meters) is

  1. Transport diffusion of liquid water and methanol through membranes...

    Office of Scientific and Technical Information (OSTI)

    Transport diffusion of liquid water and methanol through membranes Citation Details In-Document Search Title: Transport diffusion of liquid water and methanol through membranes The ...

  2. Dataset used to improve liquid water absorption models in the...

    Office of Scientific and Technical Information (OSTI)

    Dataset used to improve liquid water absorption models in the microwave Title: Dataset used to improve liquid water absorption models in the microwave Two datasets, one a ...

  3. Thin Liquid Water Clouds: Their Importance and Our Challenge...

    Office of Scientific and Technical Information (OSTI)

    Thin Liquid Water Clouds: Their Importance and Our Challenge Citation Details In-Document Search Title: Thin Liquid Water Clouds: Their Importance and Our Challenge Many of the ...

  4. Liquid chromatographic determination of water

    DOE Patents [OSTI]

    Fortier, Nancy E.; Fritz, James S.

    1990-11-13

    A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present.

  5. Liquid chromatographic determination of water

    DOE Patents [OSTI]

    Fortier, N.E.; Fritz, J.S.

    1990-11-13

    A sensitive method for the determination of water in the presence of common interferences is presented. The detection system is based on the effect of water on the equilibrium which results from the reaction aryl aldehydes, such as cinnamaldehyde and methanol in the eluent to form cinnamaldehyde dimethylacetal, plus water. This equilibrium is shifted in a catalytic atmosphere of a hydrogen ion form past column reactor. The extent of the shift and the resulting change in absorbance are proportional to the amount of water present. 1 fig.

  6. Solar Water Heater Roadmap Leads Path to Market Expansion (Fact...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovative strategy to reduce installed cost of solar water heater systems can rival conventional natural gas water heaters in the marketplace. Researchers in the Residential ...

  7. Distributed Reforming of Renewable Liquids via Water Splitting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) ...

  8. First Principles Simulations of the Infrared Spectrum of Liquid Water |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Infrared spectra of liquid water Infrared spectra of liquid water computed using hybrid (solid lines) and semi-local (dotted line) functionals, computed by ab-initio molecular dynamics with the Qbox code. Cui Zhang, UC-Davis. First Principles Simulations of the Infrared Spectrum of Liquid Water PI Name: Giulia Galli PI Email: gagalli@ucdavis.edu Institution: University of California-Davis Allocation Program: INCITE Allocation Hours at ALCF: 15 Million

  9. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print Wednesday, 25 May 2005 00:00 The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the

  10. Posters Radar/Radiometer Retrievals of Cloud Liquid Water and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for retrieving cloud liquid water content and drizzle characteristics using a K -band Doppler radar (Kropfli et al. 1990) and microwave radiometer (Hogg et al. 1983). The...

  11. ARM - Evaluation Product - MWR Retrievals of Cloud Liquid Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ProductsMWR Retrievals of Cloud Liquid Water and Water Vapor ARM Data Discovery Browse Data Documentation Use the Data File Inventory tool to view data availability at the file...

  12. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  13. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  14. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  15. Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Transport Membrane (OTM) (Presentation) | Department of Energy Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Distributed Reforming of Renewable Liquids via Water Splitting using Oxygen Transport Membrane (OTM) (Presentation) Presented at the 2007 Bio-Derived Liquids to Hydrogen Distributed Reforming Working Group held November 6, 2007 in Laurel, Maryland. 11_anl_distributed_reforming_using_otm.pdf (809.59 KB) More Documents & Publications Cost

  16. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  17. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  18. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  19. Energetics of Hydrogen Bond Network Rearrangements in Liquid Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energetics of Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen bonding (H-bonding) network structure and its associated dynamics. However, despite intense experimental and theoretical scrutiny, a complete description of this structure has been elusive. Recently, with the help of their novel liquid microjet apparatus, a University of California, Berkeley, group derived

  20. Interactions between liquid-water and gas-diffusion layers in polymer-electrolyte fuel cells

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Das, Prodip K.; Santamaria, Anthony D.; Weber, Adam Z.

    2015-06-11

    Over the past few decades, a significant amount of research on polymer-electrolyte fuel cells (PEFCs) has been conducted to improve performance and durability while reducing the cost of fuel cell systems. However, the cost associated with the platinum (Pt) catalyst remains a barrier to their commercialization and PEFC durability standards have yet to be established. An effective path toward reducing PEFC cost is making the catalyst layers (CLs) thinner thus reducing expensive Pt content. The limit of thin CLs is high gas-transport resistance and the performance of these CLs is sensitive to the operating temperature due to their inherent lowmore » water uptake capacity, which results in higher sensitivity to liquid-water flooding and reduced durability. Therefore, reducing PEFC's cost by decreasing Pt content and improving PEFC's performance and durability by managing liquid-water are still challenging and open topics of research. An overlooked aspect nowadays of PEFC water management is the gas-diffusion layer (GDL). While it is known that GDL's properties can impact performance, typically it is not seen as a critical component. In this work, we present data showing the importance of GDLs in terms of water removal and management while also exploring the interactions between liquid-water and GDL surfaces. The critical interface of GDL and gas-flow-channel in the presence of liquid-water was examined through systematic studies of adhesion forces as a function of water-injection rate for various GDLs of varying thickness. GDL properties (breakthrough pressure and adhesion force) were measured experimentally under a host of test conditions. Specifically, the effects of GDL hydrophobic (PTFE) content, thickness, and water-injection rate were examined to identify trends that may be beneficial to the design of liquid-water management strategies and next-generation GDL materials for PEFCs.« less

  1. Interactions between liquid-water and gas-diffusion layers in polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Das, Prodip K.; Santamaria, Anthony D.; Weber, Adam Z.

    2015-06-11

    Over the past few decades, a significant amount of research on polymer-electrolyte fuel cells (PEFCs) has been conducted to improve performance and durability while reducing the cost of fuel cell systems. However, the cost associated with the platinum (Pt) catalyst remains a barrier to their commercialization and PEFC durability standards have yet to be established. An effective path toward reducing PEFC cost is making the catalyst layers (CLs) thinner thus reducing expensive Pt content. The limit of thin CLs is high gas-transport resistance and the performance of these CLs is sensitive to the operating temperature due to their inherent low water uptake capacity, which results in higher sensitivity to liquid-water flooding and reduced durability. Therefore, reducing PEFC's cost by decreasing Pt content and improving PEFC's performance and durability by managing liquid-water are still challenging and open topics of research. An overlooked aspect nowadays of PEFC water management is the gas-diffusion layer (GDL). While it is known that GDL's properties can impact performance, typically it is not seen as a critical component. In this work, we present data showing the importance of GDLs in terms of water removal and management while also exploring the interactions between liquid-water and GDL surfaces. The critical interface of GDL and gas-flow-channel in the presence of liquid-water was examined through systematic studies of adhesion forces as a function of water-injection rate for various GDLs of varying thickness. GDL properties (breakthrough pressure and adhesion force) were measured experimentally under a host of test conditions. Specifically, the effects of GDL hydrophobic (PTFE) content, thickness, and water-injection rate were examined to identify trends that may be beneficial to the design of liquid-water management strategies and next-generation GDL materials for PEFCs.

  2. Thermoluminescence dosimetry measurements of brachytherapy sources in liquid water

    SciTech Connect (OSTI)

    Tailor, Ramesh; Tolani, Naresh; Ibbott, Geoffrey S.

    2008-09-15

    Radiation therapy dose measurements are customarily performed in liquid water. The characterization of brachytherapy sources is, however, generally based on measurements made with thermoluminescence dosimeters (TLDs), for which contact with water may lead to erroneous readings. Consequently, most dosimetry parameters reported in the literature have been based on measurements in water-equivalent plastics, such as Solid Water. These previous reports employed a correction factor to transfer the dose measurements from a plastic phantom to liquid water. The correction factor most often was based on Monte Carlo calculations. The process of measuring in a water-equivalent plastic phantom whose exact composition may be different from published specifications, then correcting the results to a water medium leads to increased uncertainty in the results. A system has been designed to enable measurements with TLDs in liquid water. This system, which includes jigs to support water-tight capsules of lithium fluoride in configurations suitable for measuring several dosimetric parameters, was used to determine the correction factor from water-equivalent plastic to water. Measurements of several {sup 125}I and {sup 131}Cs prostate brachytherapy sources in liquid water and in a Solid Water phantom demonstrated a correction factor of 1.039{+-}0.005 at 1 cm distance. These measurements are in good agreement with a published value of this correction factor for an {sup 125}I source.

  3. New Mexico cloud super cooled liquid water survey final report 2009.

    SciTech Connect (OSTI)

    Beavis, Nick; Roskovensky, John K.; Ivey, Mark D.

    2010-02-01

    Los Alamos and Sandia National Laboratories are partners in an effort to survey the super-cooled liquid water in clouds over the state of New Mexico in a project sponsored by the New Mexico Small Business Assistance Program. This report summarizes the scientific work performed at Sandia National Laboratories during the 2009. In this second year of the project a practical methodology for estimating cloud super-cooled liquid water was created. This was accomplished through the analysis of certain MODIS sensor satellite derived cloud products and vetted parameterizations techniques. A software code was developed to analyze multiple cases automatically. The eighty-one storm events identified in the previous year effort from 2006-2007 were again the focus. Six derived MODIS products were obtained first through careful MODIS image evaluation. Both cloud and clear-sky properties from this dataset were determined over New Mexico. Sensitivity studies were performed that identified the parameters which most influenced the estimation of cloud super-cooled liquid water. Limited validation was undertaken to ensure the soundness of the cloud super-cooled estimates. Finally, a path forward was formulized to insure the successful completion of the initial scientific goals which include analyzing different of annual datasets, validation of the developed algorithm, and the creation of a user-friendly and interactive tool for estimating cloud super-cooled liquid water.

  4. Elucidating through-plane liquid water profile in a polymer electrolyt...

    Office of Scientific and Technical Information (OSTI)

    liquid water profile in a polymer electrolyte membrane fuel cell. Citation Details In-Document Search Title: Elucidating through-plane liquid water profile in a ...

  5. Dielectric Properties of Ice and Liquid Water from First Principles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Calculations | Argonne Leadership Computing Facility Dielectric Properties of Ice and Liquid Water from First Principles Calculations Authors: Lu, D., Gygi, F., Galli, G. We present a first-principles study of the static dielectric properties of ice and liquid water. The eigenmodes of the dielectric matrix ϵ are analyzed in terms of maximally localized dielectric functions similar, in their definition, to maximally localized Wannier orbitals obtained from Bloch eigenstates of the electronic

  6. Entropy of Liquid Water from Ab Initio Molecular Dynamics | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Leadership Computing Facility Entropy of Liquid Water from Ab Initio Molecular Dynamics Authors: Zhang, C., Spanu,L., Galli, G. We have computed the entropy of liquid water using a two-phase thermodynamic model and trajectories generated by ab initio molecular dynamics simulations. We present the results obtained with semilocal, hybrid, and van der Waals density functionals. We show that in all cases, at the experimental equilibrium density and at temperatures in the vicinity of 300 K, the

  7. Process for blending coal with water immiscible liquid

    DOE Patents [OSTI]

    Heavin, Leonard J.; King, Edward E.; Milliron, Dennis L.

    1982-10-26

    A continuous process for blending coal with a water immiscible liquid produces a uniform, pumpable slurry. Pulverized raw feed coal and preferably a coal derived, water immiscible liquid are continuously fed to a blending zone (12 and 18) in which coal particles and liquid are intimately admixed and advanced in substantially plug flow to form a first slurry. The first slurry is withdrawn from the blending zone (12 and 18) and fed to a mixing zone (24) where it is mixed with a hot slurry to form the pumpable slurry. A portion of the pumpable slurry is continuously recycled to the blending zone (12 and 18) for mixing with the feed coal.

  8. Heating-induced glass-glass and glass-liquid transformations in computer simulations of water

    SciTech Connect (OSTI)

    Chiu, Janet; Giovambattista, Nicolas; Starr, Francis W.

    2014-03-21

    Water exists in at least two families of glassy states, broadly categorized as the low-density (LDA) and high-density amorphous ice (HDA). Remarkably, LDA and HDA can be reversibly interconverted via appropriate thermodynamic paths, such as isothermal compression and isobaric heating, exhibiting first-order-like phase transitions. We perform out-of-equilibrium molecular dynamics simulations of glassy water using the ST2 model to study the evolution of LDA and HDA upon isobaric heating. Depending on pressure, glass-to-glass, glass-to-crystal, glass-to-vapor, as well as glass-to-liquid transformations are found. Specifically, heating LDA results in the following transformations, with increasing heating pressures: (i) LDA-to-vapor (sublimation), (ii) LDA-to-liquid (glass transition), (iii) LDA-to-HDA-to-liquid, (iv) LDA-to-HDA-to-liquid-to-crystal, and (v) LDA-to-HDA-to-crystal. Similarly, heating HDA results in the following transformations, with decreasing heating pressures: (a) HDA-to-crystal, (b) HDA-to-liquid-to-crystal, (c) HDA-to-liquid (glass transition), (d) HDA-to-LDA-to-liquid, and (e) HDA-to-LDA-to-vapor. A more complex sequence may be possible using lower heating rates. For each of these transformations, we determine the corresponding transformation temperature as function of pressure, and provide a P-T “phase diagram” for glassy water based on isobaric heating. Our results for isobaric heating dovetail with the LDA-HDA transformations reported for ST2 glassy water based on isothermal compression/decompression processes [Chiu et al., J. Chem. Phys. 139, 184504 (2013)]. The resulting phase diagram is consistent with the liquid-liquid phase transition hypothesis. At the same time, the glass phase diagram is sensitive to sample preparation, such as heating or compression rates. Interestingly, at least for the rates explored, our results suggest that the LDA-to-liquid (HDA-to-liquid) and LDA-to-HDA (HDA-to-LDA) transformation lines on heating are related

  9. ARM - PI Product - MWR Retrievals of Cloud Liquid Water and Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govDataPI Data ProductsMWR Retrievals of Cloud Liquid Water and Water Vapor ARM Data Discovery Browse Data Comments? We would love to hear from you Send us a note below or call us...

  10. Passive cooling system for liquid metal cooled nuclear reactors with backup coolant flow path

    DOE Patents [OSTI]

    Hunsbedt, Anstein; Boardman, Charles E.

    1993-01-01

    A liquid metal cooled nuclear fission reactor plant having a passive auxiliary safety cooling system for removing residual heat resulting from fuel decay during reactor shutdown, or heat produced during a mishap. This reactor plant is enhanced by a backup or secondary passive safety cooling system which augments the primary passive auxiliary cooling system when in operation, and replaces the primary system when rendered inoperable.

  11. Flight Path 5 - About

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (ER1) Target 1 Flight Path 05 (1FP05) utilizes low-energy neutrons from a water moderator on the 1L target. About Target 1 Flight Path 05 (ER1 and Silo) Target 1 Flight Path 05 ...

  12. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    2008-01-15

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  13. Large Scale Ice Water Path and 3-D Ice Water Content

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Liu, Guosheng

    Cloud ice water concentration is one of the most important, yet poorly observed, cloud properties. Developing physical parameterizations used in general circulation models through single-column modeling is one of the key foci of the ARM program. In addition to the vertical profiles of temperature, water vapor and condensed water at the model grids, large-scale horizontal advective tendencies of these variables are also required as forcing terms in the single-column models. Observed horizontal advection of condensed water has not been available because the radar/lidar/radiometer observations at the ARM site are single-point measurement, therefore, do not provide horizontal distribution of condensed water. The intention of this product is to provide large-scale distribution of cloud ice water by merging available surface and satellite measurements. The satellite cloud ice water algorithm uses ARM ground-based measurements as baseline, produces datasets for 3-D cloud ice water distributions in a 10 deg x 10 deg area near ARM site. The approach of the study is to expand a (surface) point measurement to an (satellite) areal measurement. That is, this study takes the advantage of the high quality cloud measurements at the point of ARM site. We use the cloud characteristics derived from the point measurement to guide/constrain satellite retrieval, then use the satellite algorithm to derive the cloud ice water distributions within an area, i.e., 10 deg x 10 deg centered at ARM site.

  14. Final Scientific/Technical Report. A closed path methane and water vapor gas analyzer

    SciTech Connect (OSTI)

    Xu, Liukang; McDermitt, Dayle; Anderson, Tyler; Riensche, Brad; Komissarov, Anatoly; Howe, Julie

    2012-02-01

    Robust, economical, low-power and reliable closed-path methane (CH4), carbon dioxide (CO2), and water vapor (H2O) analyzers suitable for long-term measurements are not readily available commercially. Such analyzers are essential for quantifying the amount of CH4 and CO2 released from various ecosystems (wetlands, rice paddies, forests, etc.) and other surface contexts (e.g. landfills, animal husbandry lots, etc.), and for understanding the dynamics of the atmospheric CH4 and CO2 budget and their impact on climate change and global warming. The purpose of this project is to develop a closed-path methane, carbon dioxide gas and water vapor analyzer capable of long-term measurements in remote areas for global climate change and environmental research. The analyzer will be capable of being deployed over a wide range of ecosystems to understand methane and carbon dioxide exchange between the atmosphere and the surface. Measurements of methane and carbon dioxide exchange need to be made all year-round with limited maintenance requirements. During this Phase II effort, we successfully completed the design of the electronics, optical bench, trace gas detection method and mechanical infrastructure. We are using the technologies of two vertical cavity surface emitting lasers, a multiple-pass Herriott optical cell, wavelength modulation spectroscopy and direct absorption to measure methane, carbon dioxide, and water vapor. We also have designed the instrument application software, Field Programmable Gate Array (FPGA), along with partial completion of the embedded software. The optical bench has been tested in a lab setting with very good results. Major sources of optical noise have been identified and through design, the optical noise floor is approaching -60dB. Both laser modules can be temperature controlled to help maximize the stability of the analyzer. Additionally, a piezo electric transducer has been

  15. Measurement of radiation damage of water-based liquid scintillator and liquid scintillator

    SciTech Connect (OSTI)

    Bignell, L. J.; Diwan, M. V.; Hans, S.; Jaffe, D. E.; Rosero, R.; Vigdor, S.; Viren, B.; Worcester, E.; Yeh, M.; Zhang, C.

    2015-10-19

    Liquid scintillating phantoms have been proposed as a means to perform real-time 3D dosimetry for proton therapy treatment plan verification. We have studied what effect radiation damage to the scintillator will have upon this application. We have performed measurements of the degradation of the light yield and optical attenuation length of liquid scintillator and water-based liquid scintillator after irradiation by 201 MeV proton beams that deposited doses of approximately 52 Gy, 300 Gy, and 800 Gy in the scintillator. Liquid scintillator and water-based liquid scintillator (composed of 5% scintillating phase) exhibit light yield reductions of 1.74 ± 0.55 % and 1.31 ± 0.59 % after ≈ 800 Gy of proton dose, respectively. Some increased optical attenuation was observed in the irradiated samples, the measured reduction to the light yield is also due to damage to the scintillation light production. Based on our results and conservative estimates of the expected dose in a clinical context, a scintillating phantom used for proton therapy treatment plan verification would exhibit a systematic light yield reduction of approximately 0.1% after a year of operation.

  16. Measurement of radiation damage of water-based liquid scintillator and liquid scintillator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bignell, L. J.; Diwan, M. V.; Hans, S.; Jaffe, D. E.; Rosero, R.; Vigdor, S.; Viren, B.; Worcester, E.; Yeh, M.; Zhang, C.

    2015-10-19

    Liquid scintillating phantoms have been proposed as a means to perform real-time 3D dosimetry for proton therapy treatment plan verification. We have studied what effect radiation damage to the scintillator will have upon this application. We have performed measurements of the degradation of the light yield and optical attenuation length of liquid scintillator and water-based liquid scintillator after irradiation by 201 MeV proton beams that deposited doses of approximately 52 Gy, 300 Gy, and 800 Gy in the scintillator. Liquid scintillator and water-based liquid scintillator (composed of 5% scintillating phase) exhibit light yield reductions of 1.74 ± 0.55 % andmore » 1.31 ± 0.59 % after ≈ 800 Gy of proton dose, respectively. Some increased optical attenuation was observed in the irradiated samples, the measured reduction to the light yield is also due to damage to the scintillation light production. Based on our results and conservative estimates of the expected dose in a clinical context, a scintillating phantom used for proton therapy treatment plan verification would exhibit a systematic light yield reduction of approximately 0.1% after a year of operation.« less

  17. Water-saving liquid-gas conditioning system (Patent) | SciTech...

    Office of Scientific and Technical Information (OSTI)

    Patent: Water-saving liquid-gas conditioning system Citation Details In-Document Search Title: Water-saving liquid-gas conditioning system A method for treating a process gas with ...

  18. Flight Path 12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 This flight path is located in experiment building ER-2 (MPF-30) at the Manual Lujan Jr. Neutron Scattering Center at LANSCE. Target 1 Flight Path 12 (1FP12) Target 1 Flight Path 12 utilizes cold neutrons from the 1L target. This flight path is located in experiment building ER-2 (MPF-30) at the Manual Lujan Jr. Neutron Scattering Center at LANSCE. The flight path utilizes a liquid mercury shutter to control the neutron beam transmission from the target. The flight path views the partially

  19. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  20. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  1. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  2. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  3. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  4. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  5. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  6. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  7. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding between water molecules that gives liquid water its peculiar characteristics, the electronic structure

  8. Flight Path 14 - About DANCE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lujan Jr. Neutron Scattering Center at LANSCE. The flight path utilizes a liquid mercury shutter to control the neutron beam transmission from the target. About Target 1...

  9. Solar Water Heater Roadmap Leads Path to Market Expansion (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-09-01

    Innovative strategy to reduce installed cost of solar water heater systems can rival conventional natural gas water heaters in the marketplace.

  10. MWRRET Value-Added Product: The Retrieval of Liquid Water Path...

    Office of Scientific and Technical Information (OSTI)

    public from the National Technical Information Service, Springfield, VA at www.ntis.gov. ... microwave radiometer (MWR) Retrieval (MWRRET) value-added product (VAP) algorithm. ...

  11. Characterization and Modeling of a Water-based Liquid Scintillator

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    L. J. Bignell; Beznosko, D.; Diwan, M. V.; Hans, S.; Jaffe, D. E.; S. Kettell; Rosero, R.; Themann, H. W.; Viren, B.; Worcester, E.; et al

    2015-12-15

    We characterised Water-based Liquid Scintillator (WbLS) using low energy protons, UV-VIS absorbance, and fluorescence spectroscopy. We have also developed and validated a simulation model that describes the behaviour of WbLS in our detector configurations for proton beam energies of 210 MeV, 475 MeV, and 2 GeV and for two WbLS compositions. These results have enabled us to estimate the light yield and ionisation quenching of WbLS, as well as to understand the influence of the wavelength shifting of Cherenkov light on our measurements. These results are relevant to the suitability of WbLS materials for next generation intensity frontier experiments.

  12. Electrokinetic Hydrogen Generation from Liquid WaterMicrojets

    SciTech Connect (OSTI)

    Duffin, Andrew M.; Saykally, Richard J.

    2007-05-31

    We describe a method for generating molecular hydrogen directly from the charge separation effected via rapid flow of liquid water through a metal orifice, wherein the input energy is the hydrostatic pressure times the volume flow rate. Both electrokinetic currents and hydrogen production rates are shown to follow simple equations derived from the overlap of the fluid velocity gradient and the anisotropic charge distribution resulting from selective adsorption of hydroxide ions to the nozzle surface. Pressure-driven fluid flow shears away the charge balancing hydronium ions from the diffuse double layer and carries them out of the aperture. Downstream neutralization of the excess protons at a grounded target electrode produces gaseous hydrogen molecules. The hydrogen production efficiency is currently very low (ca. 10-6) for a single cylindrical jet, but can be improved with design changes.

  13. Detachment of Liquid-Water Droplets from Gas-Diffusion Layers

    SciTech Connect (OSTI)

    Das, Prodip K.; Grippin, Adam; Weber, Adam Z.

    2011-07-01

    A critical issue for optimal water management in proton-exchange-membrane fuel cells at lower temperatures is the removal of liquid water from the cell. This pathway is intimately linked with the phenomena of liquid-water droplet removal from surface of the gas-diffusion layer and into the flow channel. Thus, a good understanding of liquid-water transport and droplet growth and detachment from the gas-diffusion layer is critical. In this study, liquid-water droplet growth and detachment on the gas-diffusion layer surfaces are investigated experimentally to improve the understating of water transport through and removal from gas-diffusion layers. An experiment using a sliding-angle measurement is designed and used to quantify and directly measure the adhesion force for liquid-water droplets, and to understand the droplets? growth and detachment from the gas-diffusion layers.

  14. Network analysis of proton transfer in liquid water

    SciTech Connect (OSTI)

    Shevchuk, Roman; Rao, Francesco; Agmon, Noam

    2014-06-28

    Proton transfer in macromolecular systems is a fascinating yet elusive process. In the last ten years, molecular simulations have shown to be a useful tool to unveil the atomistic mechanism. Notwithstanding, the large number of degrees of freedom involved make the accurate description of the process very hard even for the case of proton diffusion in bulk water. Here, multi-state empirical valence bond molecular dynamics simulations in conjunction with complex network analysis are applied to study proton transfer in liquid water. Making use of a transition network formalism, this approach takes into account the time evolution of several coordinates simultaneously. Our results provide evidence for a strong dependence of proton transfer on the length of the hydrogen bond solvating the Zundel complex, with proton transfer enhancement as shorter bonds are formed at the acceptor site. We identify six major states (nodes) on the network leading from the special pair to a more symmetric Zundel complex required for transferring the proton. Moreover, the second solvation shell specifically rearranges to promote the transfer, reiterating the idea that solvation beyond the first shell of the Zundel complex plays a crucial role in the process.

  15. Flight Path 14 - DANCE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 Target 1 Flight Path 14 (1FP14) utilizes thermal and epithermal neutrons from the 1L target. This flight path is located in experiment building ER-2 (MPF-30) at the Manual Lujan Jr. Neutron Scattering Center at LANSCE. The flight path utilizes a liquid mercury shutter to control the neutron beam transmission from the target. Target 1 Flight Path 14 (DANCE) Detector for Advanced Neutron Capture Experiments (DANCE) is a 4π detector array that consists of up to 160 elements of barium fluoride

  16. Structural and Vibrational Properties of Liquid Water from van der Waals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Density Functionals | Argonne Leadership Computing Facility Structural and Vibrational Properties of Liquid Water from van der Waals Density Functionals Authors: Zhang, C., Wu, J., Gygi, F., Galli, G. We present results for the structural and vibrational properties of the water molecule, water dimer, and liquid water at the experimental equilibrium density, as obtained with several van der Waals density functionals. The functional form originally proposed by Dion et al. [ Phys. Rev. Lett.

  17. Elucidating through-plane liquid water profile in a polymer electrolyte membrane fuel cell.

    SciTech Connect (OSTI)

    Wang, Yun; Chen, Ken Shuang

    2010-10-01

    In this paper, a numerical model incorporating micro-porous layers (MPLs) is presented for simulating water transport within the gas diffusion layers (GDLs) and MPLs as well as across their interfaces in a polymer electrolyte membrane (PEM) fuel cell. One-dimensional analysis is conducted to investigate the impacts of MPL and GDL properties on the liquid-water profile across the anode GDL-MPL and cathode MPL-GDL regions. Furthermore, two-dimensional numerical simulations that take MPLs into account are also carried out to elucidate liquid water transport, particularly through-plane liquid-water profile in a PEM fuel cell. Results from case studies are presented.

  18. Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Isotope and Temperature Effects in Liquid Water Probed by Soft X Rays Print Wednesday, 24 September 2008 00:00 The geometric structure of liquid water has been investigated in detail by many techniques, but many details are still under debate, such as the actual number of hydrogen bonds (at a given time) between the various water molecules. Even less is known about the electronic structure. Since it is the intermittent bonding

  19. Water-saving liquid-gas conditioning system

    DOE Patents [OSTI]

    Martin, Christopher; Zhuang, Ye

    2014-01-14

    A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

  20. ARM - Publications: Science Team Meeting Documents: Liquid water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    models (Liebe,1987; Rosenkranz,1998; Liljegren, 2004) and 3 liquid dielectric models (Grant, 1957; Liebe, 1991; Rosenkranz, 2003) are evaluated. The choice of gaseous...

  1. Path Finder

    Energy Science and Technology Software Center (OSTI)

    2014-01-07

    PathFinder is a graph search program, traversing a directed cyclic graph to find pathways between labeled nodes. Searches for paths through ordered sequences of labels are termed signatures. Determining the presence of signatures within one or more graphs is the primary function of Path Finder. Path Finder can work in either batch mode or interactively with an analyst. Results are limited to Path Finder whether or not a given signature is present in the graph(s).

  2. Grain Boundary Character Along Intergranular Stress Corrosion Crack Paths in Austenitic Stainless Alloys Removed from High-Temperature Water Service

    SciTech Connect (OSTI)

    Gertsman, Valerii Y.; Bruemmer, Stephen M.

    2002-01-01

    Stress-corrosion cracks produced in high-temperature water environments were examined in alloy 600 and stainless steel samples. The alloy 600 samples were removed from pressurized-water reactor (PWR) steam generator tubing after exhibiting cracking in service or after model-boiler stress corrosion cracking tests. The 304 and 316 stainless steel samples also experienced intergranular stress corrosion cracking (IGSCC) in high-temperature-water environments similar to a PWR steam generator. Grain boundary misorientations were measured along IG crack paths as well as in the bulk. In general, only twin Sigma 3 boundaries exhibited improved resistance to crack propagation. If the Sigma 3 were factored out, the fractions of grain boundary types of cracked boundaries corresponded to their frequency of occurrence in the bulk alloy. Other boundaries with coincident site lattice misorientations, including Sigma 9 and Sigma 27, were observed to crack. The cracks were often (but not always) arrested at grain boundary junctions containing Sigma 3 boundaries. The results obtained indicate that grain boundary crystallography does not fully determine its susceptibility to IGSCC in typical commercial alloys. Other factors must be taken into account when assessing material?s propensity to IG failure.

  3. Integration of Global Positioning System and Scanning Water Vapor Radiometers for Precipitable Water Vapor and Cloud Liquid Path Estimates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Integrating the Production of Biofuels and Bioproducts Integrating the Production of Biofuels and Bioproducts April 28, 2016 - 11:25am Addthis Non-food biomass such as the crop residue (the leftover material from crops like stalks, leaves, and husks of corn plants following harvest) pictured above can be converted to biofuels as well as high-value products such as plastics, chemicals, and fertilizers. Non-food biomass such as the crop residue (the leftover material from crops like

  4. Process for hydrogen isotope concentration between liquid water and hydrogen gas

    DOE Patents [OSTI]

    Stevens, William H.

    1976-09-21

    A process for hydrogen isotope exchange and concentration between liquid water and hydrogen gas, wherein liquid water and hydrogen gas are contacted, in an exchange section, with one another and with at least one catalyst body comprising at least one metal selected from Group VIII of the Periodic Table and preferably a support therefor, the catalyst body has a liquid-water-repellent, gas permeable polymer or organic resin coating, preferably a fluorinated olefin polymer or silicone coating, so that the isotope concentration takes place by two simultaneously occurring steps, namely, ##EQU1## WHILE THE HYDROGEN GAS FED TO THE EXCHANGE SECTION IS DERIVED IN A REACTOR VESSEL FROM LIQUID WATER THAT HAS PASSED THROUGH THE EXCHANGE SECTION.

  5. Ab initio calculation of the electronic absorption spectrum of liquid water

    SciTech Connect (OSTI)

    Martiniano, Hugo F. M. C.; Galamba, Nuno; Cabral, Benedito J. Costa; Departamento de Qumica e Bioqumica, Faculdade de Cincias, Universidade de Lisboa, 1749-016 Lisboa; Instituto de Fsica da Universidade de So Paulo, CP 66318, 05314-970 So Paulo, SP

    2014-04-28

    The electronic absorption spectrum of liquid water was investigated by coupling a one-body energy decomposition scheme to configurations generated by classical and Born-Oppenheimer Molecular Dynamics (BOMD). A Frenkel exciton Hamiltonian formalism was adopted and the excitation energies in the liquid phase were calculated with the equation of motion coupled cluster with single and double excitations method. Molecular dynamics configurations were generated by different approaches. Classical MD were carried out with the TIP4P-Ew and AMOEBA force fields. The BLYP and BLYP-D3 exchange-correlation functionals were used in BOMD. Theoretical and experimental results for the electronic absorption spectrum of liquid water are in good agreement. Emphasis is placed on the relationship between the structure of liquid water predicted by the different models and the electronic absorption spectrum. The theoretical gas to liquid phase blue-shift of the peak positions of the electronic absorption spectrum is in good agreement with experiment. The overall shift is determined by a competition between the OH stretching of the water monomer in liquid water that leads to a red-shift and polarization effects that induce a blue-shift. The results illustrate the importance of coupling many-body energy decomposition schemes to molecular dynamics configurations to carry out ab initio calculations of the electronic properties in liquid phase.

  6. Polymer formulation for removing hydrogen and liquid water from an enclosed space

    DOE Patents [OSTI]

    Shepodd, Timothy J.

    2006-02-21

    This invention describes a solution to the particular problem of liquid water formation in hydrogen getters exposed to quantities of oxygen. Water formation is usually desired because the recombination reaction removes hydrogen without affecting gettering capacity and the oxygen removal reduces the chances for a hydrogen explosion once free oxygen is essentially removed. The present invention describes a getter incorporating a polyacrylate compound that can absorb up to 500% of its own weight in liquid water without significantly affecting its hydrogen gettering/recombination properties, but that also is insensitive to water vapor.

  7. Pressure Effect on the Boson Peak in Deeply Cooled Confined Water: Evidence of a Liquid-Liquid Transition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Zhe; Kolesnikov, Alexander I.; Ito, Kanae; Podlesnyak, Andrey; Chen, Sow-Hsin

    2015-12-03

    We studied the boson peak in deeply cooled water confined in nanopores in order to examine the liquid-liquid transition (LLT). Below ~180 K, the boson peaks at pressures P higher than ~3.5 kbar are evidently distinct from those at low pressures by higher mean frequencies and lower heights. Moreover, the higher-P boson peaks can be rescaled to a master curve while the lower-P boson peaks can be rescaled to a different one. Moreover, these phenomena agree with the existence of two liquid phases with different densities and local structures and the associated LLT in the measured (P, T) region. Additionally,more » the P dependence of the librational band also agrees with the above conclusion.« less

  8. Flight Path 5 - Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Publications Target 1 Flight Path 05 (1FP05) utilizes low-energy neutrons from a water moderator on the 1L target. Energy resolved neutron radiography at LANSCE pulsed neutron ...

  9. Vapor deposition of water on graphitic surfaces: Formation of amorphous ice, bilayer ice, ice I, and liquid water

    SciTech Connect (OSTI)

    Lupi, Laura; Kastelowitz, Noah; Molinero, Valeria

    2014-11-14

    Carbonaceous surfaces are a major source of atmospheric particles and could play an important role in the formation of ice. Here we investigate through molecular simulations the stability, metastability, and molecular pathways of deposition of amorphous ice, bilayer ice, and ice I from water vapor on graphitic and atomless Lennard-Jones surfaces as a function of temperature. We find that bilayer ice is the most stable ice polymorph for small cluster sizes, nevertheless it can grow metastable well above its region of thermodynamic stability. In agreement with experiments, the simulations predict that on increasing temperature the outcome of water deposition is amorphous ice, bilayer ice, ice I, and liquid water. The deposition nucleation of bilayer ice and ice I is preceded by the formation of small liquid clusters, which have two wetting states: bilayer pancake-like (wetting) at small cluster size and droplet-like (non-wetting) at larger cluster size. The wetting state of liquid clusters determines which ice polymorph is nucleated: bilayer ice nucleates from wetting bilayer liquid clusters and ice I from non-wetting liquid clusters. The maximum temperature for nucleation of bilayer ice on flat surfaces, T{sub B}{sup max} is given by the maximum temperature for which liquid water clusters reach the equilibrium melting line of bilayer ice as wetting bilayer clusters. Increasing water-surface attraction stabilizes the pancake-like wetting state of liquid clusters leading to larger T{sub B}{sup max} for the flat non-hydrogen bonding surfaces of this study. The findings of this study should be of relevance for the understanding of ice formation by deposition mode on carbonaceous atmospheric particles, including soot.

  10. Distributed Reforming of Renewable Liquids via Water Splitting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water Splitting using Oxygen Transport Membrane (OTM) * U. (Balu) Balachandran, T. H. ... Objective & Rationale Objective: Develop compact dense ceramic membrane reactors that ...

  11. Anomalous Density Properties and Ion Solvation in Liquid Water...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to a number of fields, ranging from biologybiochemistry to energy storage and electrochemistry. Several key properties of water, are crucial for understanding and predicting...

  12. Liquid Water the Key to Arctic Cloud Radiative Closure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Water the Key to Arctic Cloud Radiative Closure For original submission and image(s), see ARM Research Highlights http:www.arm.govsciencehighlights Research Highlight...

  13. Path ANalysis

    Energy Science and Technology Software Center (OSTI)

    2007-07-14

    The PANL software determines path through an Adversary Sequence Diagram (ASD) with minimum Probability of Interruption, P(I), given the ASD information and data about site detection, delay, and response force times. To accomplish this, the software generates each path through the ASD, then applies the Estimate of Adversary Sequence Interruption (EASI) methodology for calculating P(I) to each path, and keeps track of the path with the lowest P(I). Primary use is for training purposes duringmore » courses on physical security design. During such courses PANL will be used to demonstrate to students how more complex software codes are used by the US Department of Energy to determine the most-vulnerable paths and, where security needs improvement, how such codes can help determine physical security upgrades.« less

  14. Radiative Importance of ThinŽ Liquid Water Clouds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Program Accomplishments of the Instantaneous Radiative Flux (IRF) Working Group August 2006 AERI Observations at Southern Great Plains Improve Infrared Radiative Transfer Models Turner et al., JAS, 2004 * AERI observations used to evaluate clear sky IR radiative transfer models * Long-term comparisons have improved - Spectral line database parameters - Water vapor continuum absorption models * Reduced errors in computation of downwelling radiative IR flux by approx 4; current uncertainty is on

  15. Dataset used to improve liquid water absorption models in the microwave

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Turner, David

    2015-12-14

    Two datasets, one a compilation of laboratory data and one a compilation from three field sites, are provided here. These datasets provide measurements of the real and imaginary refractive indices and absorption as a function of cloud temperature. These datasets were used in the development of the new liquid water absorption model that was published in Turner et al. 2015.

  16. Ultrafast conversions between hydrogen bonded structures in liquid water observed by femtosecond x-ray spectroscopy

    SciTech Connect (OSTI)

    Wen, Haidan; Huse, Nils; Schoenlein, Robert W.; Lindenberg, Aaron M.

    2010-05-01

    We present the first femtosecond soft x-ray spectroscopy in liquids, enabling the observation of changes in hydrogen bond structures in water via core-hole excitation. The oxygen K-edge of vibrationally excited water is probed with femtosecond soft x-ray pulses, exploiting the relation between different water structures and distinct x-ray spectral features. After excitation of the intramolecular OH stretching vibration, characteristic x-ray absorption changes monitor the conversion of strongly hydrogen-bonded water structures to more disordered structures with weaker hydrogen-bonding described by a single subpicosecond time constant. The latter describes the thermalization time of vibrational excitations and defines the characteristic maximum rate with which nonequilibrium populations of more strongly hydrogen-bonded water structures convert to less-bonded ones. On short time scales, the relaxation of vibrational excitations leads to a transient high-pressure state and a transient absorption spectrum different from that of statically heated water.

  17. Active probing of cloud multiple scattering, optical depth, vertical thickness, and liquid water content using wide-angle imaging LIDAR.

    SciTech Connect (OSTI)

    Love, Steven P.; Davis, A. B.; Rohde, C. A.; Tellier, L. L.; Ho, Cheng,

    2002-01-01

    At most optical wavelengths, laser light in a cloud lidar experiment is not absorbed but merely scattered out of the beam, eventually escaping the cloud via multiple scattering. There is much information available in this light scattered far from the input beam, information ignored by traditional 'on-beam' lidar. Monitoring these off-beam returns in a fully space- and time-resolved manner is the essence of our unique instrument, Wide Angle Imaging Lidar (WAIL). In effect, WAIL produces wide-field (60-degree full-angle) 'movies' of the scattering process and records the cloud's radiative Green functions. A direct data product of WAIL is the distribution of photon path lengths resulting from multiple scattering in the cloud. Following insights from diffusion theory, we can use the measured Green functions to infer the physical thickness and optical depth of the cloud layer, and, from there, estimate the volume-averaged liquid water content. WAIL is notable in that it is applicable to optically thick clouds, a regime in which traditional lidar is reduced to ceilometry. Here we present recent WAIL data oti various clouds and discuss the extension of WAIL to full diurnal monitoring by means of an ultra-narrow magneto-optic atomic line filter for daytime measurements.

  18. Formation of H-type liquid crystal dimer at air-water interface

    SciTech Connect (OSTI)

    Karthik, C. Gupta, Adbhut Joshi, Aditya Manjuladevi, V. Gupta, Raj Kumar; Varia, Mahesh C.; Kumar, Sandeep

    2014-04-24

    We have formed the Langmuir monolayer of H-shaped Azo linked liquid crystal dimer molecule at the air-water interface. Isocycles of the molecule showed hysteresis suggesting the ir-reversible nature of the monolayer formed. The thin film deposited on the silicon wafer was characterized using Atomic Force Microscopy (AFM) and Field Emission Scanning Electron Microscopy (FESEM). The images showed uniform domains of the dimer molecule. We propose that these molecules tend to take book shelf configuration in the liquid phase.

  19. Liquid-Water Uptake and Removal in PEM Fuel-Cell Components

    SciTech Connect (OSTI)

    Das, Prodip K.; Gunterman, Haluna P.; Kwong, Anthony; Weber, Adam Z.

    2011-09-23

    Management of liquid water is critical for optimal fuel-cell operation, especially at low temperatures. It is therefore important to understand the wetting properties and water holdup of the various fuel-cell layers. While the gas-diffusion layer is relatively hydrophobic and exhibits a strong intermediate wettability, the catalyst layer is predominantly hydrophilic. In addition, the water content of the ionomer in the catalyst layer is lower than that of the bulk membrane, and is affected by platinum surfaces. Liquid-water removal occurs through droplets on the surface of the gas-diffusion layer. In order to predict droplet instability and detachment, a force balance is used. While the pressure or drag force on the droplet can be derived, the adhesion or surface-tension force requires measurement using a sliding-angle approach. It is shown that droplets produced by forcing water through the gas-diffusion layer rather than placing them on top of it show much stronger adhesion forces owing to the contact to the subsurface water.

  20. The effects of charge transfer on the properties of liquid water

    SciTech Connect (OSTI)

    Lee, Alexis J.; Rick, Steven W.

    2011-05-14

    A method for treating charge transfer interactions in classical potential models is developed and applied to water. In this method, a discrete amount of charge is transferred for each hydrogen bond formed. It is designed to be simple to implement, to be applicable to a variety of potential models, and to satisfy various physical requirements. The method does not transfer charge at large intramolecular distances, it does not result in a conductive liquid, and it can be easily parameterized to give the correct amount of charge transfer. Two charge transfer models are developed for a polarizable and a non-polarizable potential. The models reproduce many of the properties of liquid water, including the structure, the diffusion constant, and thermodynamic properties over a range of temperatures.

  1. Ab initio molecular dynamics simulation of liquid water by quantum Monte Carlo

    SciTech Connect (OSTI)

    Zen, Andrea; Luo, Ye Mazzola, Guglielmo Sorella, Sandro; Guidoni, Leonardo

    2015-04-14

    Although liquid water is ubiquitous in chemical reactions at roots of life and climate on the earth, the prediction of its properties by high-level ab initio molecular dynamics simulations still represents a formidable task for quantum chemistry. In this article, we present a room temperature simulation of liquid water based on the potential energy surface obtained by a many-body wave function through quantum Monte Carlo (QMC) methods. The simulated properties are in good agreement with recent neutron scattering and X-ray experiments, particularly concerning the position of the oxygen-oxygen peak in the radial distribution function, at variance of previous density functional theory attempts. Given the excellent performances of QMC on large scale supercomputers, this work opens new perspectives for predictive and reliable ab initio simulations of complex chemical systems.

  2. Generic component failure data base for light water and liquid sodium reactor PRAs (probabilistic risk assessments)

    SciTech Connect (OSTI)

    Eide, S.A.; Chmielewski, S.V.; Swantz, T.D.

    1990-02-01

    A comprehensive generic component failure data base has been developed for light water and liquid sodium reactor probabilistic risk assessments (PRAs). The Nuclear Computerized Library for Assessing Reactor Reliability (NUCLARR) and the Centralized Reliability Data Organization (CREDO) data bases were used to generate component failure rates. Using this approach, most of the failure rates are based on actual plant data rather than existing estimates. 21 refs., 9 tabs.

  3. Ultrafast dynamics of liquid water: Frequency fluctuations of the OH stretch and the HOH bend

    SciTech Connect (OSTI)

    Imoto, Sho; Xantheas, Sotiris S.; Saito, Shinji

    2013-07-28

    Frequency fluctuations of the OH stretch and the HOH bend in liquid water are reported from the third-order response function evaluated using the TTM3-F potential for water. The simulated two-dimensional infrared (IR) spectra of the OH stretch are similar to previously reported theoretical results. The present study suggests that the frequency fluctuation of the HOH bend is faster than that of the OH stretch. The ultrafast loss of the frequency correlation of the HOH bend is due to the strong couplings with the OH stretch as well as the intermolecular hydrogen bond bend.

  4. IR and SFG vibrational spectroscopy of the water bend in the bulk liquid and at the liquid-vapor interface, respectively

    SciTech Connect (OSTI)

    Ni, Yicun; Skinner, J. L.

    2015-07-07

    Vibrational spectroscopy of the water bending mode has been investigated experimentally to study the structure of water in condensed phases. In the present work, we calculate the theoretical infrared (IR) and sum-frequency generation (SFG) spectra of the HOH bend in liquid water and at the water liquid/vapor interface using a mixed quantum/classical approach. Classical molecular dynamics simulation is performed by using a recently developed water model that explicitly includes three-body interactions and yields a better description of the water surface. Ab-initio-based transition frequency, dipole, polarizability, and intermolecular coupling maps are developed for the spectral calculations. The calculated IR and SFG spectra show good agreement with the experimental measurements. In the theoretical imaginary part of the SFG susceptibility for the water liquid/vapor interface, we find two features: a negative band centered at 1615 cm{sup −1} and a positive band centered at 1670 cm{sup −1}. We analyze this spectrum in terms of the contributions from molecules in different hydrogen-bond classes to the SFG spectral density and also compare to SFG results for the OH stretch. SFG of the water bending mode provides a complementary picture of the heterogeneous hydrogen-bond configurations at the water surface.

  5. Zero Liquid Discharge (ZLD) System for Flue-Gas Derived Water From Oxy-Combustion Process

    SciTech Connect (OSTI)

    Sivaram Harendra; Danylo Oryshchyn; Thomas Ochs; Stephen J. Gerdemann; John Clark

    2011-10-16

    Researchers at the National Energy Technology Laboratory (NETL) located in Albany, Oregon, have patented a process - Integrated Pollutant Removal (IPR) that uses off-the-shelf technology to produce a sequestration ready CO{sub 2} stream from an oxy-combustion power plant. Capturing CO{sub 2} from fossil-fuel combustion generates a significant water product which can be tapped for use in the power plant and its peripherals. Water condensed in the IPR{reg_sign} process may contain fly ash particles, sodium (from pH control), and sulfur species, as well as heavy metals, cations and anions. NETL is developing a treatment approach for zero liquid discharge while maximizing available heat from IPR. Current treatment-process steps being studied are flocculation/coagulation, for removal of cations and fine particles, and reverse osmosis, for anion removal as well as for scavenging the remaining cations. After reverse osmosis process steps, thermal evaporation and crystallization steps will be carried out in order to build the whole zero liquid discharge (ZLD) system for flue-gas condensed wastewater. Gypsum is the major product from crystallization process. Fast, in-line treatment of water for re-use in IPR seems to be one practical step for minimizing water treatment requirements for CO{sub 2} capture. The results obtained from above experiments are being used to build water treatment models.

  6. Method and apparatus for electrokinetic co-generation of hydrogen and electric power from liquid water microjets

    DOE Patents [OSTI]

    Saykally, Richard J; Duffin, Andrew M; Wilson, Kevin R; Rude, Bruce S

    2013-02-12

    A method and apparatus for producing both a gas and electrical power from a flowing liquid, the method comprising: a) providing a source liquid containing ions that when neutralized form a gas; b) providing a velocity to the source liquid relative to a solid material to form a charged liquid microjet, which subsequently breaks up into a droplet spay, the solid material forming a liquid-solid interface; and c) supplying electrons to the charged liquid by contacting a spray stream of the charged liquid with an electron source. In one embodiment, where the liquid is water, hydrogen gas is formed and a streaming current is generated. The apparatus comprises a source of pressurized liquid, a microjet nozzle, a conduit for delivering said liquid to said microjet nozzle, and a conductive metal target sufficiently spaced from said nozzle such that the jet stream produced by said microjet is discontinuous at said target. In one arrangement, with the metal nozzle and target electrically connected to ground, both hydrogen gas and a streaming current are generated at the target as it is impinged by the streaming, liquid spray microjet.

  7. Molecular origin of the difference in the HOH bend of the IR spectra between liquid water and ice

    SciTech Connect (OSTI)

    Imoto, Sho; Xantheas, Sotiris S.; Saito, Shinji

    2013-02-07

    The intensity of the HOH bend in the IR spectrum of ice is significantly smaller than the corresponding one in liquid water. This difference in the IR intensities of the HOH bend in the two systems is investigated using MD simulations with the flexible, polarizable, ab-initio based TTM3-F model for water, a potential that correctly reproduces the experimentally observed increase of the HOH bend in liquid water and ice from the water monomer value. We have identified two factors that are responsible for the difference in the intensity of the HOH bend in liquid water and ice: (i) the decrease of the intensity of the HOH bend in ice caused by the strong anti-correlation between the permanent dipole moment of a molecule and the induced dipole moment of a neighboring hydrogen bond acceptor molecule and (ii) the weakening of this anti-correlation by the disordered hydrogen bond network in liquid water. The presence of the anti-correlation in ice is further confirmed by ab initio electronic structure calculations of water pentamer clusters extracted from the trajectories of the MD simulations for ice and liquid water.

  8. Advantages of liquid fluoride thorium reactor in comparison with light water reactor

    SciTech Connect (OSTI)

    Bahri, Che Nor Aniza Che Zainul Majid, Amran Ab.; Al-Areqi, Wadeeah M.

    2015-04-29

    Liquid Fluoride Thorium Reactor (LFTR) is an innovative design for the thermal breeder reactor that has important potential benefits over the traditional reactor design. LFTR is fluoride based liquid fuel, that use the thorium dissolved in salt mixture of lithium fluoride and beryllium fluoride. Therefore, LFTR technology is fundamentally different from the solid fuel technology currently in use. Although the traditional nuclear reactor technology has been proven, it has perceptual problems with safety and nuclear waste products. The aim of this paper is to discuss the potential advantages of LFTR in three aspects such as safety, fuel efficiency and nuclear waste as an alternative energy generator in the future. Comparisons between LFTR and Light Water Reactor (LWR), on general principles of fuel cycle, resource availability, radiotoxicity and nuclear weapon proliferation shall be elaborated.

  9. A cobalt(II) bis(salicylate)-based ionic liquid that shows thermoresponsive and selective water coordination

    SciTech Connect (OSTI)

    Kohno, Y; Cowan, MG; Masuda, M; Bhowmick, I; Shores, MP; Gin, DL; Noble, RD

    2014-01-01

    A metal-containing ionic liquid (MCIL) has been prepared in which the [CoII(salicylate)(2)](2-) anion is able to selectively coordinate two water molecules with a visible colour change, even in the presence of alcohols. Upon moderate heating or placement in vacuo, the hydrated MCIL undergoes reversible thermochromism by releasing the bound water molecules.

  10. Determination of formate in natural waters by a coupled enzymatic/high-performance liquid chromatographic technique

    SciTech Connect (OSTI)

    Kieber, D.J.; Vaughan, G.M.; Mopper, K.

    1988-09-01

    An enzymatic method was developed to quantify formic acid in natural water samples at submicromolar concentrations. The method is based on the oxidation of formate by formate dehydrogenase with corresponding reduction of ..beta..-nicotinamide adenine dinucleotide (..beta..-NAD/sup +/) to reduced ..beta..-NAD/sup +/ (..beta..-NADH); ..beta..-NADH is quantified by reversed-phase high-performance liquid chromatography with fluorometric detection. An important feature of this method is that the enzymatic reaction occurs directly in aqueous media, even sea water, and does not require sample pretreatment other than sample filtration. The reaction proceeds at room temperature at a slightly alkaline pH (7.5 - 8.5) and is specific for formate with a detection limit of 0.5 ..mu..M (S/N = 4) for a 200-..mu..L injection. The precision of the method was 4.6% relative standard deviation (n = 6) for a 0.6 ..mu..M standard addition of formate to Sargasso sea water. Average recoveries of 2 ..mu..M additions of formate to sea water, pore water, or rain were 103, 103, and 87%, respectively. Intercalibration with a Dionex ion chromatographic system showed an excellent agreement of 98%. Concentrations of formate present in natural samples ranged from 0.2 to 0.8 ..mu..M for Biscayne Bay sea water, 0.4 to 10.0 ..mu..M for Miami rain, and 0.9 to 8.4 ..mu..M for Biscayne Bay sediment pore water.

  11. The individual and collective effects of exact exchange and dispersion interactions on the ab initio structure of liquid water

    SciTech Connect (OSTI)

    DiStasio, Robert A.; Santra, Biswajit; Li, Zhaofeng; Wu, Xifan; Car, Roberto

    2014-08-28

    In this work, we report the results of a series of density functional theory (DFT) based ab initio molecular dynamics (AIMD) simulations of ambient liquid water using a hierarchy of exchange-correlation (XC) functionals to investigate the individual and collective effects of exact exchange (Exx), via the PBE0 hybrid functional, non-local van der Waals/dispersion (vdW) interactions, via a fully self-consistent density-dependent dispersion correction, and an approximate treatment of nuclear quantum effects, via a 30 K increase in the simulation temperature, on the microscopic structure of liquid water. Based on these AIMD simulations, we found that the collective inclusion of Exx and vdW as resulting from a large-scale AIMD simulation of (H{sub 2}O){sub 128} significantly softens the structure of ambient liquid water and yields an oxygen-oxygen structure factor, S{sub OO}(Q), and corresponding oxygen-oxygen radial distribution function, g{sub OO}(r), that are now in quantitative agreement with the best available experimental data. This level of agreement between simulation and experiment demonstrated herein originates from an increase in the relative population of water molecules in the interstitial region between the first and second coordination shells, a collective reorganization in the liquid phase which is facilitated by a weakening of the hydrogen bond strength by the use of a hybrid XC functional, coupled with a relative stabilization of the resultant disordered liquid water configurations by the inclusion of non-local vdW/dispersion interactions. This increasingly more accurate description of the underlying hydrogen bond network in liquid water also yields higher-order correlation functions, such as the oxygen-oxygen-oxygen triplet angular distribution, P{sub OOO}(θ), and therefore the degree of local tetrahedrality, as well as electrostatic properties, such as the effective molecular dipole moment, that are in much better agreement with experiment.

  12. Method of extracting iodine from liquid mixtures of iodine, water and hydrogen iodide

    DOE Patents [OSTI]

    Mysels, Karol J.

    1979-01-01

    The components of a liquid mixture consisting essentially of HI, water and at least about 50 w/o iodine are separated in a countercurrent extraction zone by treating with phosphoric acid containing at least about 90 w/o H.sub.3 PO.sub.4. The bottom stream from the extraction zone is substantially completely molten iodine, and the overhead stream contains water, HI, H.sub.3 PO.sub.4 and a small fraction of the amount of original iodine. When the water and HI are present in near-azeotropic proportions, there is particular advantage in feeding the overhead stream to an extractive distillation zone wherein it is treated with additional concentrated phosphoric acid to create an anhydrous HI vapor stream and bottoms which contain at least about 85 w/o H.sub.3 PO.sub.4. Concentration of these bottoms provides phosphoric acid infeed for both the countercurrent extraction zone and for the extractive distillation zone.

  13. Dynamics of soft Nanomaterials captured by transmission electron microscopy in liquid water

    SciTech Connect (OSTI)

    Proetto, Maria T.; Rush, Anthony M.; Chien, Miao-Ping; Abellan Baeza, Patricia; Patterson, Joseph P.; Thompson, Matthew P.; Olson, Norman H.; Moore, Curtis E.; Rheingold, Arnold L.; Andolina, Christopher; Millstone, Jill; Howell, Stephen B.; Browning, Nigel D.; Evans, James E.; Gianneschi, Nathan C.

    2014-01-14

    In this paper we present in situ transmission electron microscopy (TEM) of soft, synthetic nanoparticles with a comparative analysis using conventional TEM methods. This comparison is made with the simple aim of describing what is an unprecedented example of in situ imaging by TEM. However, we contend the technique will quickly become essential in the characterization of analogous systems, especially where dynamics are of interest in the solvated state. In this case, particles were studied which were obtained from the direct polymerization of an oxaliplatin analog, designed for an ongoing program in novel chemotherapeutic delivery systems. The resulting nanoparticles provided sufficient contrast for facile imaging in situ, and point toward key design parameters that enable this new characterization approach for organic nanomaterials. We describe the preparation of the synthetic micellar nanoparticles to- gether with their characterization in liquid water.

  14. The Influence of Chain Dynamics on the Far Infrared Spectrum of Liquid Methanol-Water Mixtures

    SciTech Connect (OSTI)

    Woods, K.N.; Wiedemann, H.; /SLAC, SSRL

    2005-07-12

    Far-infrared absorption spectroscopy has been used to study the low frequency ({center_dot} 100 cm{sup -1}) intermolecular modes of methanol in mixtures with water. With the aid of a first principles molecular dynamics simulation on an equivalent system, a detailed understanding about the origin of the low frequency IR modes has been established. The total dipole spectrum from the simulation suggests that the bands appearing in the experimental spectra at approximately 55 cm{sup -1} and 70 cm{sup -1} in methanol and methanol-rich mixtures arise from both fluctuations and torsional motions occurring within the methanol hydrogen-bonded chains. The influence of these modes on both the solvation dynamics and the relaxation mechanisms in the liquid are discussed within the context of recent experimental and theoretical results that have emerged from studies focusing on the short time dynamics in the methanol hydrogen bond network.

  15. Charge transfer effects of ions at the liquid water/vapor interface

    SciTech Connect (OSTI)

    Soniat, Marielle; Rick, Steven W.

    2014-05-14

    Charge transfer (CT), the movement of small amounts of electron density between non-bonded pairs, has been suggested as a driving force for a variety of physical processes. Herein, we examine the effect of CT on ion adsorption to the water liquid-vapor interface. Using a CT force field for molecular dynamics, we construct a potential of mean force (PMF) for Na{sup +}, K{sup +}, Cl{sup ?}, and I{sup ?}. The PMFs were produced with respect to an average interface and an instantaneous interface. An analysis of the PMF relative to the instantaneous surface reveals that the area in which the anions experience a free energy minimum is quite narrow, and the cations feel a steeply repulsive free energy near the interface. CT is seen to have only minor effects on the overall free energy profiles. However, the long-ranged effects of ions are highlighted by the CT model. Due to CT, the water molecules at the surface become charged, even when the ion is over 15 away from the surface.

  16. Flight Paths at WNR

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Neutron and Nuclear Science Flight Paths . Overview of Flight Paths Each Flight Path's name identifies the target and the direction of the flight path (FP) with respect to the proton beam. For example, 4FP15R is a FP (flight path) that starts at Target 4 and is 15 degrees to the right (15R) of the incoming proton beam. The beams are transmitted at three different vertical levels: Target 4, Target 2, and Lujan Center (Target 1). flight_paths The layout of the flight paths at the LANSCE neuron

  17. The melting temperature of liquid water with the effective fragment potential

    SciTech Connect (OSTI)

    Brorsen, Kurt R.; Willow, Soohaeng Y.; Xantheas, Sotiris S.; Gordon, Mark S.

    2015-09-17

    Direct simulation of the solid-liquid water interface with the effective fragment potential (EFP) via the constant enthalpy and pressure (NPH) ensemble was used to estimate the melting temperature (Tm) of ice-Ih. Initial configurations and velocities, taken from equilibrated constant pressure and temperature (NPT) simulations at T = 300 K, 350 K and 400 K, respectively, yielded corresponding Tm values of 37816 K, 38214 K and 38415 K. These estimates are consistently higher than experiment, albeit to the same degree with previously reported estimates using density functional theory (DFT)-based Born-Oppenheimer simulations with the Becke-Lee-Yang-Parr functional plus dispersion corrections (BLYP-D). KRB was supported by a Computational Science Graduate Fellowship from the Department of Energy. MSG was supported by a U.S. National Science Foundation Software Infrastructure (SI2) grant (ACI 1047772). SSX acknowledges support from the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences and Biosciences. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle.

  18. The absolute path command

    Energy Science and Technology Software Center (OSTI)

    2012-05-11

    The ap command traveres all symlinks in a given file, directory, or executable name to identify the final absolute path. It can print just the final path, each intermediate link along with the symlink chan, and the permissions and ownership of each directory component in the final path. It has functionality similar to "which", except that it shows the final path instead of the first path. It is also similar to "pwd", but it canmore » provide the absolute path to a relative directory from the current working directory.« less

  19. Flight Path 15R

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    R Flight Path 15R is a flexible general-purpose experimental area that can be used for a wide range of experiments. A fission ionization chamber for measuring neutron flux is available. Target 4 Flight Path 15R Target 4 Flight Path 15R is located in building 1302 with length approximately 13m-29m. Magnets in the flight path deflect charged particles. Flight path 15R has a variable jaw shutter up to 4" square. Flight Path 15R is a flexible general-purpose experimental area that can be used

  20. Flight Path 12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    This flight path is located in experiment building ER-2 (MPF-30) at the Manual Lujan Jr. Neutron Scattering Center at LANSCE. . Target 1 Flight Path 12 (1FP12) Collaborators SPIDER ...

  1. Distribution of radionuclides and water in Bandelier Tuff beneath a former Los Alamos liquid waste disposal site after 33 years

    SciTech Connect (OSTI)

    Nyhan, J.W.; Drennon, B.J.; Abeele, W.V.; Trujillo, G.; Herrera, W.J.; Wheeler, M.L.; Booth, J.W.; Purtymun, W.D.

    1984-07-01

    The distribution of radionuclides and water in Bandelier Tuff beneath a former liquid waste disposal site at Los Alamos was investigated. The waste use history of the site was described, as well as several pertinent laboratory and field studies of water and radionuclide migration in Bandelier Tuff. The distribution of plutonium, /sup 241/Am, and water was determined in a set of about 800 tuff samples collected to sampling depths of 30 m beneath two absorption beds. These data were then related to site geohydrologic data. Water and radionuclide concentrations found after 33 years were compared with the results of similar studies previously performed at this site, and the implications of these comparisons are discussed relative to nuclear waste management. 19 references, 6 figures, 4 tables.

  2. Apparatus and method for pumping hot, erosive slurry of coal solids in coal derived, water immiscible liquid

    DOE Patents [OSTI]

    Ackerman, Carl D.

    1983-03-29

    An apparatus for and method of pumping hot, erosive slurry of coal solids in a coal derived, water immiscible liquid to higher pressure involves the use of a motive fluid which is miscible with the liquid of the slurry. The apparatus includes a pump 12, a remote check valve 14 and a chamber 16 between and in fluid communication with the pump 12 and check valve 14 through conduits 18,20. Pump 12 exerts pressure on the motive fluid and thereby on the slurry through a concentration gradient of coal solids within chamber 16 to alternately discharge slurry under pressure from the outlet port of check valve 14 and draw slurry in through the inlet port of check valve 14.

  3. Silicon Ink Technology Offers Path to Higher Efficiency Solar Cells at Lower Cost

    Broader source: Energy.gov [DOE]

    EERE supported the development of the first liquid silicon on the market that offers a novel path to producing more efficient solar cells at lower cost.

  4. Flight Path 12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Scientific Applications This flight path is located in experiment building ER-2 (MPF-30) at the Manual Lujan Jr. Neutron Scattering Center at LANSCE. . SPIDER Detector at LANSCE ...

  5. Liquid-level detector

    DOE Patents [OSTI]

    Not Available

    1981-01-29

    Aliquid level sensor is described which has a pair of upright conductors spaced by an insulator defining a first high resistance path between the conductors. An electrically conductive path is interposed between the upright conductors at a discrete location at which liquid level is to be measured. It includes a liquid accessible gap of a dimension such that the electrical resistance across the conductor when the gap is filled with the liquid is detectably less than when the gap is emptied. The conductor might also be physically altered by temperature changes to serve also as an indicator of elevated temperature.

  6. Low-Pressure Solubility of Gases in Liquid Water | Open Energy...

    Open Energy Info (EERE)

    Water Abstract Abstract unavailable. Authors Emmerich Wilhelm, Rubin Battino and Robert J. Wilcock Published Journal Chemical reviews, 1977 DOI Not Provided Check for DOI...

  7. Decontamination of Nuclear Liquid Wastes Status of CEA and AREVA R and D: Application to Fukushima Waste Waters - 12312

    SciTech Connect (OSTI)

    Fournel, B.; Barre, Y.; Lepeytre, C.; Peycelon, H.; Grandjean, A.; Prevost, T.; Valery, J.F.; Shilova, E.; Viel, P.

    2012-07-01

    Liquid wastes decontamination processes are mainly based on two techniques: Bulk processes and the so called Cartridges processes. The first technique has been developed for the French nuclear fuel reprocessing industry since the 60's in Marcoule and La Hague. It is a proven and mature technology which has been successfully and quickly implemented by AREVA at Fukushima site for the processing of contaminated waters. The second technique, involving cartridges processes, offers new opportunities for the use of innovative adsorbents. The AREVA process developed for Fukushima and some results obtained on site will be presented as well as laboratory scale results obtained in CEA laboratories. Examples of new adsorbents development for liquid wastes decontamination are also given. A chemical process unit based on co-precipitation technique has been successfully and quickly implemented by AREVA at Fukushima site for the processing of contaminated waters. The asset of this technique is its ability to process large volumes in a continuous mode. Several chemical products can be used to address specific radioelements such as: Cs, Sr, Ru. Its drawback is the production of sludge (about 1% in volume of initial liquid volume). CEA developed strategies to model the co-precipitation phenomena in order to firstly minimize the quantity of added chemical reactants and secondly, minimize the size of co-precipitation units. We are on the way to design compact units that could be mobilized very quickly and efficiently in case of an accidental situation. Addressing the problem of sludge conditioning, cementation appears to be a very attractive solution. Fukushima accident has focused attention on optimizations that should be taken into account in future studies: - To better take account for non-typical aqueous matrixes like seawater; - To enlarge the spectrum of radioelements that can be efficiently processed and especially short lives radioelements that are usually less present in

  8. Flight Path 15R

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    R - Publications Flight Path 15R is a flexible general-purpose experimental area that can be used for a wide range of experiments. A fission ionization chamber for measuring neutron flux is available. R. Yanez, L. Yao, J. King, W. Loveland, F. Tovesson, and N. Fotiades,"Excitation energy dependence of the total kinetic energy release in 235U(n,f)",Phys. Rev. C89, 051604(R) (2014). Links Flight Path Overview 4FP15R About Flight Path 15R Scientific Applications Collaborators Publications

  9. Liquid-phase and vapor-phase dehydration of organic/water solutions

    DOE Patents [OSTI]

    Huang, Yu; Ly, Jennifer; Aldajani, Tiem; Baker, Richard W.

    2011-08-23

    Processes for dehydrating an organic/water solution by pervaporation or vapor separation using fluorinated membranes. The processes are particularly useful for treating mixtures containing light organic components, such as ethanol, isopropanol or acetic acid.

  10. Flight Path Target 2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Target 2 provides experimenters direct access to the 800 MeV proton beam as well as several flight paths. Target 2 is located in MPF-7 at LANSCE.. About Target 2 - Lead Slowing ...

  11. Flight Path 12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Publications This flight path is located in experiment building ER-2 (MPF-30) at the Manual Lujan Jr. Neutron Scattering Center at LANSCE. . New instrument aids fission-fragment ...

  12. Flight Path Target 2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Target 2 provides experimenters direct access to the 800 MeV proton beam as well as several flight paths. Target 2 is located in MPF-7 at LANSCE.. Target 2 Target 2 is housed in ...

  13. Flight Path Target 2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    - Scientific Applications Target 2 provides experimenters direct access to the 800 MeV proton beam as well as several flight paths. Target 2 is located in MPF-7 at LANSCE.. Lead ...

  14. Tortuous path chemical preconcentrator

    DOE Patents [OSTI]

    Manginell, Ronald P.; Lewis, Patrick R.; Adkins, Douglas R.; Wheeler, David R.; Simonson, Robert J.

    2010-09-21

    A non-planar, tortuous path chemical preconcentrator has a high internal surface area having a heatable sorptive coating that can be used to selectively collect and concentrate one or more chemical species of interest from a fluid stream that can be rapidly released as a concentrated plug into an analytical or microanalytical chain for separation and detection. The non-planar chemical preconcentrator comprises a sorptive support structure having a tortuous flow path. The tortuosity provides repeated twists, turns, and bends to the flow, thereby increasing the interfacial contact between sample fluid stream and the sorptive material. The tortuous path also provides more opportunities for desorption and readsorption of volatile species. Further, the thermal efficiency of the tortuous path chemical preconcentrator is comparable or superior to the prior non-planar chemical preconcentrator. Finally, the tortuosity can be varied in different directions to optimize flow rates during the adsorption and desorption phases of operation of the preconcentrator.

  15. Interactions between drops of molten Al-Li alloys and liquid water

    SciTech Connect (OSTI)

    Hyder, M.L.; Nelson, L.S.; Duda, P.M.; Hyndman, D.A.

    1993-08-01

    Sandia National Laboratories, at the request of the Savannah River Technology Center (SRTC), studied the interactions between single drops of molten aluminum-lithium alloys and water. Most experiments were performed with ``B`` alloy (3.1 w/o Li, balance A1). Objectives were to develop experimental procedures for preparing and delivering the melt drops and diagnostics for characterizing the interactions, measure hydrogen generated by the reaction between melt and water, examine debris recovered after the interaction, determine changes in the aqueous phase produced by the melt-water chemical reactions, and determine whether steam explosions occur spontaneously under the conditions studied. Although many H{sub 2} bubbles were generated after the drops entered the water, spontaneous steam explosions never occurred when globules of the ``B`` alloy at temperatures between 700 and 1000C fell freely through water at room temperature, or upon or during subsequent contact with submerged aluminum or stainless steel surfaces. Total amounts of H{sub 2} (STP) increased from about 2 to 9 cm{sup 3}/per gram of melt as initial melt temperature increased over this range of temperatures.

  16. Ultrafast dynamics of liquid water: Energy relaxation and transfer processes of the OH stretch and the HOH bend

    SciTech Connect (OSTI)

    Imoto, Sho; Xantheas, Sotiris S.; Saito, Shinji

    2015-08-27

    The vibrational energy relaxation and transfer processes of the OH stretching and the HOH bending vibrations in liquid water are investigated via the theoretical calculation of the pump-probe spectra obtained from non-equilibrium molecular dynamics simulations with the TTM3-F interaction potential. The excitation of the OH stretch induces an instantaneous response of the high frequency librational motions in the 600-1000 cm-1 range. In addition, the excess energy of the OH stretch of a water molecule quickly transfers to the OH stretches of molecules in its first hydration shell with a time constant of ~50 fs, followed by relaxation to the HOH bends of the surrounding molecules with a time constant of 230 fs. The excitation of the HOH bend also results in the ultrafast excitation of the high frequency librational motions. The energy of the excited HOH bend of a water molecule decays, with a time constant of 200 fs, mainly to the relaxation of the HOH bends of its surrounding molecules. The energies of the HOH bends were found to transfer quickly to the intermolecular motions via the coupling with the high frequency librational motions. The excess energy of the OH stretch or the HOH bend relaxes to the high frequency intermolecular librational motions and eventually to the hot ground state with a time scale of ~1 ps via the coupling with the librational and translational motions. The energy relaxation and transfer processes were found to depend on the local hydrogen bonding network; the relaxations of the excess energy of the OH stretch and the HOH bend of four- and five-coordinated molecules are faster than those of a three-coordinated molecule due to the delocalization of the vibrational motions of the former (four- and five-coordinated molecules) compared to those of the later (three-coordinated molecules). The present results highlight the importance of the high frequency intermolecular librational modes in facilitating the ultrafast energy relaxation process in

  17. High-brightness water-window electron-impact liquid-jet microfocus source

    SciTech Connect (OSTI)

    Skoglund, P.; Lundstroem, U.; Vogt, U.; Hertz, H. M.

    2010-02-22

    We demonstrate stable high-brightness operation of an electron-impact water-jet-anode soft x-ray source. A 30 kV, 7.8 W electron beam is focused onto a 20 mum diameter jet resulting in water-window oxygen line emission at 525 eV/2.36 nm with a brightness of 3.0x10{sup 9} ph/(sxmum{sup 2}xsrxline). Monte Carlo-based modeling shows good quantitative agreement with the experiments. The source has potential to increase the x-ray power and brightness by another 1-2 orders of magnitude and fluid-dynamical jet instabilities is determined to be the most important limiting factor. The source properties make it an attractive alternative for table-top x-ray microscopy.

  18. Thin liquid/gas diffusion layers for high-efficiency hydrogen production from water splitting

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mo, Jingke; Retterer, Scott T.; Cullen, David A.; Toops, Todd J.; Green, Jr, Johney Boyd; Zhang, Feng-Yuan

    2016-06-13

    Liquid/gas diffusion layers (LGDLs) play a crucial role in electrochemical energy technology and hydrogen production, and are expected to simultaneously transport electrons, heat, and reactants/products with minimum voltage, current, thermal, interfacial, and fluidic losses. In addition, carbon materials, which are typically used in proton exchange membrane fuel cells (PEMFCs), are unsuitable for PEM electrolyzer cells (PEMECs). In this study, a novel titanium thin LGDL with well-tunable pore morphologies was developed by employing nano-manufacturing and was applied in a standard PEMEC. The LGDL tests show significant performance improvements. The operating voltages required at a current density of 2.0 A/cm2 were asmore » low as 1.69 V, and its efficiency reached a report high of up to 88%. The new thin and flat LGDL with well-tunable straight pores has been demonstrated to remarkably reduce the ohmic, interfacial and transport losses. In addition, well-tunable features, including pore size, pore shape, pore distribution, and thus porosity and permeability, will be very valuable for developing PEMEC models and for validation of its simulations with optimal and repeatable performance. The LGDL thickness reduction from greater than 350 μm of conventional LGDLs to 25 μm will greatly decrease the weight and volume of PEMEC stacks, and represents a new direction for future developments of low-cost PEMECs with high performance.« less

  19. Counting paths in digraphs

    SciTech Connect (OSTI)

    Sullivan, Blair D; Seymour, Dr. Paul Douglas

    2010-01-01

    Say a digraph is k-free if it has no directed cycles of length at most k, for k {element_of} Z{sup +}. Thomasse conjectured that the number of induced 3-vertex directed paths in a simple 2-free digraph on n vertices is at most (n-1)n(n+1)/15. We present an unpublished result of Bondy proving there are at most 2n{sup 3}/25 such paths, and prove that for the class of circular interval digraphs, an upper bound of n{sup 3}/16 holds. We also study the problem of bounding the number of (non-induced) 4-vertex paths in 3-free digraphs. We show an upper bound of 4n{sup 4}/75 using Bondy's result for Thomasse's conjecture.

  20. Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model

    SciTech Connect (OSTI)

    Liu, Haihu; Valocchi, Albert J.; Werth, Charles J.; Kang, Oinjun; Oostrom, Martinus

    2014-11-01

    A lattice Boltzmann color-fluid model, which was recently proposed by Liu et al. [H. Liu, A.J. Valocchi, and Q. Kang. Three-dimensional lattice Boltzmann model for immiscible two-phase flow simulations. Phys. Rev. E, 85:046309, 2012.] based on a concept of continuum surface force, is improved to simulate immiscible two-phase flows in porous media. The new improvements allow the model to account for different kinematic viscosities of both fluids and to model fluid-solid interactions. The capability and accuracy of this model is first validated by two benchmark tests: a layered two-phase flow with a viscosity ratio, and a dynamic capillary intrusion. This model is then used to simulate liquid CO2 (LCO2) displacing water in a dual-permeability pore network. The extent and behavior of LCO2 preferential flow (i.e., fingering) is found to depend on the capillary number (Ca), and three different displacement patterns observed in previous micromodel experiments are reproduced. The predicted variation of LCO2 saturation with Ca, as well as variation of specific interfacial length with LCO2 saturation, are both in good agreement with the experimental observations. To understand the effect of heterogeneity on pore-scale displacement, we also simulate LCO2 displacing water in a randomly heterogeneous pore network, which has the same size and porosity as the dual-permeability pore network. In comparison to the dual-permeability case, the transition from capillary fingering to viscous fingering occurs at a higher Ca, and LCO2 saturation is higher at low Ca but lower at high Ca. In either pore network, the LCO2-water specific interfacial length is found to obey a power-law dependence on LCO2 saturation.

  1. Effects of excluded volume and correlated molecular orientations on Frster resonance energy transfer in liquid water

    SciTech Connect (OSTI)

    Yang, Mino

    2014-04-14

    Frster theory for the survival probability of excited chromophores is generalized to include the effects of excluded volume and orientation correlation in the molecular distribution. An analytical expression for survival probability was derived and written in terms of a few simple elementary functions. Because of the excluded volume, the survival probability exhibits exponential decay at early times and stretched exponential decay at later times. Experimental schemes to determine the size of the molecular excluded volume are suggested. With the present generalization of theory, we analyzed vibrational resonance energy transfer kinetics in neat water. Excluded volume effects prove to be important and slow down the kinetics at early times. The majority of intermolecular resonance energy transfer was found to occur with exponential kinetics, as opposed to the stretched exponential behavior predicted by Frster theory. Quantum yields of intra-molecular vibrational relaxation, intra-, and intermolecular energy transfer were calculated to be 0.413, 0.167, and 0.420, respectively.

  2. ARM: Microwave Radiometer Retrievals (MWRRET) of Cloud Liquid...

    Office of Scientific and Technical Information (OSTI)

    Microwave Radiometer Retrievals (MWRRET) of Cloud Liquid Water and Precipitable Water Vapor Title: ARM: Microwave Radiometer Retrievals (MWRRET) of Cloud Liquid Water and ...

  3. Systems and methods for analyzing liquids under vacuum

    DOE Patents [OSTI]

    Yu, Xiao-Ying; Yang, Li; Cowin, James P.; Iedema, Martin J.; Zhu, Zihua

    2013-10-15

    Systems and methods for supporting a liquid against a vacuum pressure in a chamber can enable analysis of the liquid surface using vacuum-based chemical analysis instruments. No electrical or fluid connections are required to pass through the chamber walls. The systems can include a reservoir, a pump, and a liquid flow path. The reservoir contains a liquid-phase sample. The pump drives flow of the sample from the reservoir, through the liquid flow path, and back to the reservoir. The flow of the sample is not substantially driven by a differential between pressures inside and outside of the liquid flow path. An aperture in the liquid flow path exposes a stable portion of the liquid-phase sample to the vacuum pressure within the chamber. The radius, or size, of the aperture is less than or equal to a critical value required to support a meniscus of the liquid-phase sample by surface tension.

  4. Flight Path 13

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3 FP-13 is a general-purpose flight path that was configured for making total cross section measurements. It views the upper-tier cold hydrogen moderator. The current configuration uses an evacuated neutron guide for the first 30 m, with a collimator in air at 30 m. The beam is then transported in an eight-inch vacuum pipe to 60 m, after which there is about 5 m available for experiment setup. With 6 mm diameter collimation at 30 m, the beam spot is approx. 13 cm square at 63 m. fp13 Total cross

  5. Flight Path Target 2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 Target 2 provides experimenters direct access to the 800 MeV proton beam as well as several flight paths. Target 2 is located in MPF-7 at LANSCE.. Target 2 Target 2 is housed in the Blue Room in MPF-7 at LANSCE and provides experimenters direct access to the LANSCE proton beam. The Blue Room is a domed room with a diameter of 40 feet. The main floor of the Blue Room is constructed primarily of aluminum and elevated 20 feet above the basement floor to minimize neutron wall return for

  6. NNSA Organizational Redress Strengthens Path Forward | National...

    National Nuclear Security Administration (NNSA)

    Strengthens Path Forward NNSA Organizational Redress Strengthens Path Forward Press Release Mar 14, 2001 NNSA Organizational Redress Strengthens Path Forward (PDF - 0.02Mb)...

  7. On the Path to SunShot

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Path to SunShot - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear

  8. CASL - Nuclear Energy - Supercomputer speeds path forward

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Energy - Supercomputer speeds path forward When run on graphics processing units, Denovo ran 3.5 times faster than what was possible with ORNL's Jaguar, which uses only central processing units. With this increase, 3D simulations are now within reach, said Tom Evans, who led the Denovo development team. Titan is a GPU/CPU hybrid to be installed over the next several months. This research supports the Consortium for Advanced Simulation of Light Water Reactors (http://www.casl.gov/).

  9. Thermoalgebras and path integral

    SciTech Connect (OSTI)

    Khanna, F.C. Malbouisson, A.P.C. Malbouisson, J.M.C. Santana, A.E.

    2009-09-15

    Using a representation for Lie groups closely associated with thermal problems, we derive the algebraic rules of the real-time formalism for thermal quantum field theories, the so-called thermo-field dynamics (TFD), including the tilde conjugation rules for interacting fields. These thermo-group representations provide a unified view of different approaches for finite-temperature quantum fields in terms of a symmetry group. On these grounds, a path integral formalism is constructed, using Bogoliubov transformations, for bosons, fermions and non-abelian gauge fields. The generalization of the results for quantum fields in (S{sup 1}){sup d}xR{sup D-d} topology is addressed.

  10. On the Path to SunShot - Environmental Benefits of Solar | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the environment by reducing water scarcity, curbing pollution, mitigating climate change, and creating better health outcomes. Learn more about the reports in the On the Path ...

  11. Flight Path 90L - TPC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    90L . Target 4 Flight Path 90L (TPC) Target 4 Flight Path 90L is primarily used for fission cross section measurements. The flight path length is approximately 7 to 15m long. Instruments used on this flight path have included fission chambers and the fission Time Projection Chamber (TPC). Fission chambers placed on FP90L have been used to measure cross-sections, yields, and total kinetic energy of fission fragments. The fission TPC is used to measure energy-differential neutron-induced fission

  12. Vapor-liquid Equilibria and Polarization Behavior of the GCP Water Model: Gaussian Charge-on-spring versus Dipole Self-consistent Field approaches to induced polarization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chialvo, Ariel A; Moucka, Filip; Vlcek, Lukas; Nezbeda, Ivo

    2015-01-01

    We implemented the Gaussian charge-on-spring (GCOS) version of the original self-consistent field implementation of the Gaussian Charge Polarizable water model and test its accuracy to represent the polarization behavior of the original model involving smeared charges and induced dipole moments. For that purpose we adapted the recently developed multiple-particle-move (MPM) within the Gibbs and isochoric-isothermal ensembles Monte Carlo methods for the efficient simulation of polarizable fluids. We assessed the accuracy of the GCOS representation by a direct comparison of the resulting vapor-liquid phase envelope, microstructure, and relevant microscopic descriptors of water polarization along the orthobaric curve against the corresponding quantitiesmore » from the actual GCP water model.« less

  13. Vapor–Liquid Equilibrium and Polarization Behavior of the GCP Water Model: Gaussian Charge-on-Spring versus Dipole Self-Consistent Field Approaches to Induced Polarization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chialvo, Ariel A.; Moucka, Filip; Vlcek, Lukas; Nezbeda, Ivo

    2015-03-24

    Here we implemented the Gaussian charge-on-spring (GCOS) version of the original self-consistent field implementation of the Gaussian Charge Polarizable water model and test its accuracy to represent the polarization behavior of the original model involving smeared charges and induced dipole moments. Moreover, for that purpose we adapted the recently developed multiple-particle-move (MPM) within the Gibbs and isochoric-isothermal ensembles Monte Carlo methods for the efficient simulation of polarizable fluids. We also assessed the accuracy of the GCOS representation by a direct comparison of the resulting vapor-liquid phase envelope, microstructure, and relevant microscopic descriptors of water polarization along the orthobaric curve againstmore » the corresponding quantities from the actual GCP water model.« less

  14. Energetics of Hydrogen Bond Network Rearrangements in Liquid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Bond Network Rearrangements in Liquid Water Print The unique chemical and physical properties of liquid water are thought to result from the highly directional hydrogen ...

  15. Advantages of liquid fluoride thorium reactor in comparison with...

    Office of Scientific and Technical Information (OSTI)

    comparison with light water reactor Citation Details In-Document Search Title: Advantages of liquid fluoride thorium reactor in comparison with light water reactor Liquid Fluoride ...

  16. A dual-reservoir remote loading water target system for {sup 18}F and {sup 13}N production with direct in-target liquid level sensing

    SciTech Connect (OSTI)

    Ferrieri, R.A.; Alexoff, D.L.; Schlyer, D.J.; Wolf, A.P.

    1991-12-31

    This report describes our universal water target loading system that serves both [{sup 18}F] and [{sup 13}N] production targets, and a radionuclide delivery system that is specific for [{sup 18}F] fluoride. The system was designed and fabricated around the operation of a single pneumatic syringe dispenser that accesses one of two reservoirs filled with [{sup 18}O] enriched water for [{sup 18}F] fluoride production from the {sup 18}O(p,n){sup 18}F reaction and natural abundance water for [{sup 13}N] nitrate/nitrite production from the {sup 16}O(p,{alpha}){sup 13}N reaction and loads one of two targets depending on the radionuclide desired. The system offers several novel features for reliable radionuclide production. First, there exists an in-target probe for direct liquid level sensing using the conductivity response of water. In addition, transfer of [{sup 18}F] fluoride to the Hot Lab is completely decoupled from the irradiated water through the actions of a resin/recovery system which is located in the cyclotron vault, thus maintaining transfer line integrity. This feature also provides a mechanism for vault-containment of long-lived contaminants generated through target activation and leaching into the water.

  17. A dual-reservoir remote loading water target system for sup 18 F and sup 13 N production with direct in-target liquid level sensing

    SciTech Connect (OSTI)

    Ferrieri, R.A.; Alexoff, D.L.; Schlyer, D.J.; Wolf, A.P.

    1991-01-01

    This report describes our universal water target loading system that serves both ({sup 18}F) and ({sup 13}N) production targets, and a radionuclide delivery system that is specific for ({sup 18}F) fluoride. The system was designed and fabricated around the operation of a single pneumatic syringe dispenser that accesses one of two reservoirs filled with ({sup 18}O) enriched water for ({sup 18}F) fluoride production from the {sup 18}O(p,n){sup 18}F reaction and natural abundance water for ({sup 13}N) nitrate/nitrite production from the {sup 16}O(p,{alpha}){sup 13}N reaction and loads one of two targets depending on the radionuclide desired. The system offers several novel features for reliable radionuclide production. First, there exists an in-target probe for direct liquid level sensing using the conductivity response of water. In addition, transfer of ({sup 18}F) fluoride to the Hot Lab is completely decoupled from the irradiated water through the actions of a resin/recovery system which is located in the cyclotron vault, thus maintaining transfer line integrity. This feature also provides a mechanism for vault-containment of long-lived contaminants generated through target activation and leaching into the water.

  18. Technical Note: Improvements in GEANT4 energy-loss model and the effect on low-energy electron transport in liquid water

    SciTech Connect (OSTI)

    Kyriakou, I.; Incerti, S.

    2015-07-15

    Purpose: The GEANT4-DNA physics models are upgraded by a more accurate set of electron cross sections for ionization and excitation in liquid water. The impact of the new developments on low-energy electron transport simulations by the GEANT4 Monte Carlo toolkit is examined for improving its performance in dosimetry applications at the subcellular and nanometer level. Methods: The authors provide an algorithm for an improved implementation of the Emfietzoglou model dielectric response function of liquid water used in the GEANT4-DNA existing model. The algorithm redistributes the imaginary part of the dielectric function to ensure a physically motivated behavior at the binding energies, while retaining all the advantages of the original formulation, e.g., the analytic properties and the fulfillment of the f-sum-rule. In addition, refinements in the exchange and perturbation corrections to the Born approximation used in the GEANT4-DNA existing model are also made. Results: The new ionization and excitation cross sections are significantly different from those of the GEANT4-DNA existing model. In particular, excitations are strongly enhanced relative to ionizations, resulting in higher W-values and less diffusive dose-point-kernels at sub-keV electron energies. Conclusions: An improved energy-loss model for the excitation and ionization of liquid water by low-energy electrons has been implemented in GEANT4-DNA. The suspiciously low W-values and the unphysical long tail in the dose-point-kernel have been corrected owing to a different partitioning of the dielectric function.

  19. Quantum calculations of the IR spectrum of liquid water using ab initio and model potential and dipole moment surfaces and comparison with experiment

    SciTech Connect (OSTI)

    Liu, Hanchao; Wang, Yimin; Bowman, Joel M.

    2015-05-21

    The calculation and characterization of the IR spectrum of liquid water have remained a challenge for theory. In this paper, we address this challenge using a combination of ab initio approaches, namely, a quantum treatment of IR spectrum using the ab initio WHBB water potential energy surface and a refined ab initio dipole moment surface. The quantum treatment is based on the embedded local monomer method, in which the three intramolecular modes of each embedded H{sub 2}O monomer are fully coupled and also coupled singly to each of six intermolecular modes. The new dipole moment surface consists of a previous spectroscopically accurate 1-body dipole moment surface and a newly fitted ab initio intrinsic 2-body dipole moment. A detailed analysis of the new dipole moment surface in terms of the coordinate dependence of the effective atomic charges is done along with tests of it for the water dimer and prism hexamer double-harmonic spectra against direct ab initio calculations. The liquid configurations are taken from previous molecular dynamics calculations of Skinner and co-workers, using the TIP4P plus E3B rigid monomer water potential. The IR spectrum of water at 300 K in the range of 0–4000 cm{sup −1} is calculated and compared with experiment, using the ab initio WHBB potential and new ab initio dipole moment, the q-TIP4P/F potential, which has a fixed-charged description of the dipole moment, and the TTM3-F potential and dipole moment surfaces. The newly calculated ab initio spectrum is in very good agreement with experiment throughout the above spectral range, both in band positions and intensities. This contrasts to results with the other potentials and dipole moments, especially the fixed-charge q-TIP4P/F model, which gives unrealistic intensities. The calculated ab initio spectrum is analyzed by examining the contribution of various transitions to each band.

  20. Electron mean free path from angle-dependent photoelectron spectroscopy of aerosol particles

    SciTech Connect (OSTI)

    Goldmann, Maximilian; Miguel-Sánchez, Javier; West, Adam H. C.; Yoder, Bruce L.; Signorell, Ruth

    2015-06-14

    We propose angle-resolved photoelectron spectroscopy of aerosol particles as an alternative way to determine the electron mean free path of low energy electrons in solid and liquid materials. The mean free path is obtained from fits of simulated photoemission images to experimental ones over a broad range of different aerosol particle sizes. The principal advantage of the aerosol approach is twofold. First, aerosol photoemission studies can be performed for many different materials, including liquids. Second, the size-dependent anisotropy of the photoelectrons can be exploited in addition to size-dependent changes in their kinetic energy. These finite size effects depend in different ways on the mean free path and thus provide more information on the mean free path than corresponding liquid jet, thin film, or bulk data. The present contribution is a proof of principle employing a simple model for the photoemission of electrons and preliminary experimental data for potassium chloride aerosol particles.

  1. Flight Path 60R - GEANIE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    60R GErmanium Array for Neutron Induced Excitations (GEANIE) is the first large-scale, escape-suppressed, high-resolution gamma-ray spectrometer to be used at a white neutron source. Target 4 Flight Path 60R (GEANIE) Target 4 Flight Path 60R utilizes the neutrons that scatter off the tungsten spallation source at approximately 60 degrees to beam right. The experiments utilizing this flight path are located 15-meters from the target in experiment building MPF-29 at the Neutron and Nuclear Science

  2. EnerPath | Open Energy Information

    Open Energy Info (EERE)

    EnerPath Jump to: navigation, search Logo: EnerPath Name: EnerPath Address: 1758 Orange Tree Lane Place: Redlands, California Zip: 92374 Region: Southern CA Area Sector: Buildings,...

  3. Hydrogen Education Curriculum Path at Michigan Technological...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Curriculum Path at Michigan Technological University Hydrogen Education Curriculum Path at Michigan Technological University 2009 DOE Hydrogen Program and Vehicle Technologies ...

  4. Transition pathways in a many-body system: Application to hydrogen-bond breaking in water

    SciTech Connect (OSTI)

    Csajka, F.S.; Chandler, D.

    1998-07-01

    We apply a stochastic method introduced by Dellago {ital et al.} [J. Chem. Phys. {bold 108}, 1964 (1998)] to sample transition paths in high-dimensional systems. The method connects two endpoint regions (for example a reactant and a product region) by a set of space-time paths. This approach is an importance sampling for rare events that does not require prior knowledge of the location of dynamical bottlenecks. Transition paths are generated with a weight corresponding to a chain of Metropolis Monte Carlo steps. We derive Monte Carlo algorithms and apply the technique to the dynamics of hydrogen-bond breaking in liquid water. We obtain averages in a transition path ensemble for the structure and energy along the trajectory. While characterized by a rate constant, hydrogen-bond breaking in water occurs frequently enough to be studied by standard methods. The process therefore provides a useful test of path sampling methods. The comparison between path sampling and standard Monte Carlo demonstrate the feasibility of transition path sampling for a many-body system with a rough potential energy surface. {copyright} {ital 1998 American Institute of Physics.}

  5. ARM: Microwave Water Radiometer (MWR): water liq. and vapor along...

    Office of Scientific and Technical Information (OSTI)

    Microwave Water Radiometer (MWR): water liq. and vapor along line of sight (LOS) path Title: ARM: Microwave Water Radiometer (MWR): water liq. and vapor along line of sight (LOS) ...

  6. PUMPS FOR LIQUID CURRENT-CONDUCTING MATERIAL

    DOE Patents [OSTI]

    Watt, D.A.

    1958-12-23

    An induction-type liquid conductor pump is described wherein the induced current flow is substantially tnansverse to the flow of the liquid in the duct, thus eliminating parallel current flow that tends to cause unwanted pressures resulting in turbulence, eddy-flow, heating losses, and reduced pumping efficiency. This improvement is achieved by offering the parallel current a path of lower impedance along the duct than that offered by the liquid so that the induced currents remaining in the liquid flow in a substantially transverse directlon. Thick copper bars are brazed to the liquid duct parallel to the flow, and additional induced currents are created in the copper bars of appropriate magnitude to balance the ohmic drop ln the current paths outside of the liquid metal.

  7. Characterization of Flow Paths, Residence Time and Media Chemistry in Complex Landscapes to Integrate Surface, Groundwater and Stream Processes and Inform Models of Hydrologic and Water Quality Response to Land Use Activities; Savannah River Site

    SciTech Connect (OSTI)

    Bitew, Menberu; Jackson, Rhett

    2015-02-01

    The objective of this report is to document the methodology used to calculate the three hydro-geomorphic indices: C Index, Nhot spot, and Interflow Contributing Area (IFC Area). These indices were applied in the Upper Four Mile Creek Watershed in order to better understand the potential mechanisms controlling retention time, path lengths, and potential for nutrient and solute metabolism and exchange associated with the geomorphic configurations of the upland contributing areas, groundwater, the riparian zone, and stream channels.

  8. Tokamak with liquid metal toroidal field coil

    DOE Patents [OSTI]

    Ohkawa, Tihiro; Schaffer, Michael J.

    1981-01-01

    Tokamak apparatus includes a pressure vessel for defining a reservoir and confining liquid therein. A toroidal liner disposed within the pressure vessel defines a toroidal space within the liner. Liquid metal fills the reservoir outside said liner. Electric current is passed through the liquid metal over a conductive path linking the toroidal space to produce a toroidal magnetic field within the toroidal space about the major axis thereof. Toroidal plasma is developed within the toroidal space about the major axis thereof.

  9. Molecular Mechanism of the Adsorption Process of an Iodide Anion into Liquid-Vapor Interfaces of Water-Methanol Mixtures

    SciTech Connect (OSTI)

    Annapureddy, Harsha V.; Dang, Liem X.

    2012-12-07

    To enhance our understanding of the molecular mechanism of ion adsorption to the interface of mixtures, we systematically carried out a free energy calculations study involving the transport of an iodide anion across the interface of a water-methanol mixture. Many body affects are taken into account to describe the interactions among the species. The surface propensities of I- at interfaces of pure water and methanol are well understood. In contrast, detailed knowledge of the molecular level adsorption process of I- at aqueous mixture interfaces has not been reported. In this paper, we explore how this phenomenon will be affected for mixed solvents with varying compositions of water and methanol. Our potential of mean force study as function of varying compositions indicated that I- adsorption free energies decrease from pure water to pure methanol but not linearly with the concentration of methanol. We analyze the computed density profiles and hydration numbers as a function of concentrations and ion positions with respect to the interface to further explain the observed phenomenon. This work was supported by the U.S. Department of Energy (DOE), Office of Basic Energy Sciences (BES), Division of Chemical Sciences, Geosciences, and Biosciences. Pacific Northwest National Laboratory is a multiprogram national laboratory operated for DOE by Battelle. The calculations were carried out using computer resources provided by BES.

  10. On the thermal neutron transport processes in liquid H/sub 2/O-D/sub 2/O mixtures

    SciTech Connect (OSTI)

    Barnsal, R.M.; Tewari, S.P.

    1983-06-01

    Using the recently developed thermal neutron scattering kernels for water and heavy water, which incorporate both the collective and the molecular modes present in water and heavy water, the thermal neutron transport studies of asymptotic decay constants lambda/sub 0/, diffusion coefficient D/sub 0/, diffusion cooling coefficient C, and the transport mean-free-path lambda /SUB tr/ are studied for liquid H/sub 2/O-D/sub 2/O mixtures with varying molecular contents and for various assembly sizes at 21 and 5/sup 0/C. The calculated values of the physical constants, lambda/sub 0/, D/sub 0/, C, and lambda /SUB tr/ are found to be in good agreement with the corresponding experimental results. Both the collective motion and the molecular modes present in the liquid H/sub 2/O-D/sub 2/O mixtures play significant roles in the thermal neutron transport processes.

  11. Vibrational spectroscopy of liquid mixtures and solid/liquid interfaces |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Molecular orbital representation of the electronic states in the first solvation shell in water. The inset shows different contributions (total, inter- and intra-molecular) to the IR stretching band of liquid water. Vibrational spectroscopy of liquid mixtures and solid/liquid interfaces PI Name: Giulia Galli PI Email: gagalli@ucdavis.edu Institution: University of California, Davis Allocation Program: INCITE Allocation Hours at ALCF: 1 Million Year: 2010

  12. Oxidation Protection of Uranium Nitride Fuel using Liquid Phase Sintering

    SciTech Connect (OSTI)

    Dr. Paul A. Lessing

    2012-03-01

    Two methods are proposed to increase the oxidation resistance of uranium nitride (UN) nuclear fuel. These paths are: (1) Addition of USi{sub x} (e.g. U3Si2) to UN nitride powder, followed by liquid phase sintering, and (2) 'alloying' UN nitride with various compounds (followed by densification via Spark Plasma Sintering or Liquid Phase Sintering) that will greatly increase oxidation resistance. The advantages (high thermal conductivity, very high melting point, and high density) of nitride fuel have long been recognized. The sodium cooled BR-10 reactor in Russia operated for 18 years on uranium nitride fuel (UN was used as the driver fuel for two core loads). However, the potential advantages (large power up-grade, increased cycle lengths, possible high burn-ups) as a Light Water Reactor (LWR) fuel are offset by uranium nitride's extremely low oxidation resistance (UN powders oxidize in air and UN pellets decompose in hot water). Innovative research is proposed to solve this problem and thereby provide an accident tolerant LWR fuel that would resist water leaks and high temperature steam oxidation/spalling during an accident. It is proposed that we investigate two methods to increase the oxidation resistance of UN: (1) Addition of USi{sub x} (e.g. U{sub 3}Si{sub 2}) to UN nitride powder, followed by liquid phase sintering, and (2) 'alloying' UN nitride with compounds (followed by densification via Spark Plasma Sintering) that will greatly increase oxidation resistance.

  13. Impact of zeolite aging in hot liquid water on activity for acid-catalyzed dehydration of alcohols

    SciTech Connect (OSTI)

    Vjunov, Aleksei; Derewinski, Miroslaw A.; Fulton, John L.; Camaioni, Donald M.; Lercher, Johannes A.

    2015-08-19

    The catalytic performance of zeolite in aqueous medium depends on a multitude of factors, such as the concentration and distribution of active sites and framework integrity. Al K–edge extended X–ray absorption fine structure and 27Al MAS NMR spectroscopies in combination with DFT calculations are used to determine the distribution of tetrahedral Al sites both qualitatively and quantitatively for both parent and 48 h 160 ºC water treated HBEA catalysts. There is no evidence of Al coordination modification after aging in water. The distribution and concentration of Al T–sites, active centers for the dehydration of cyclohexanol, do not markedly impact the catalytic performance in water, because the Brønsted acidic protons are present in the form of hydrated hydronium ions and thus have very similar acid properties. The results suggest that all Brønsted acid sites are equally active in aqueous medium. The decrease of zeolite catalytic performance after water treatment is attributed to the reduced concentration of Brønsted acid sites. Increasing the stability of pore walls and decreasing the rate of Si–O–Si group hydrolysis may result in improved apparent zeolite catalytic performance in aqueous medium. Authors thank B. W. Arey (PNNL) for HIM measurements, T. Huthwelker for support during Al XAFS measurements at the Swiss Light Source (PSI, Switzerland), J. Z. Hu and S. D. Burton (PNNL) for support during NMR experiments. This work was supported by the U. S. Department of Energy (DOE), Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. MD acknowledges support by the Materials Synthesis and Simulation Across Scales (MS3 Initiative) conducted under Laboratory Directed Research & Development Program at PNNL. HIM imaging and NMR experiments were performed at the Environmental Molecular Sciences Laboratory, a national scientific user facility sponsored by the DOE Office of Science, Office of Biological

  14. Sodium-Water Reaction and Thermal Hydraulics at Gas-Liquid Interface: Numerical Interpretation of Experimental Observations

    SciTech Connect (OSTI)

    Yamaguchi, Akira; Takata, Takashi; Ohshima, Hiroyuki; Suda, Kazunori

    2006-07-01

    In a sodium-cooled fast reactor development, coupled phenomena of thermal-hydraulics and chemical reaction of sodium and water vapor are of importance from the safety viewpoint. However, the sodium-water reaction (SWR) phenomena are generally complex and the experimental measurement technology is not well matured. Therefore, a numerical simulation is used for the investigation of the SWR. In this paper, a new computer program has been developed and the SWR in a counter-flow diffusion flame is studied by a numerical simulations and an experiment as well. In the computer program, Navier-Stokes equations and chemical reaction equations are solved interactively. In addition, a dynamic equation of airborne particulates is coupled with the governing equations of thermal hydraulics. A source of the particulates is the chemical reaction products, i.e. sodium hydroxide and sodium oxide. The SWR experiment is decided based on the numerical simulation. To obtain a stable reaction flame and to measure the temperature and reaction product distributions, the flow field in the experimental cell needs to be optimized. The numerical simulation is useful for designing experiments of complex phenomena and for obtaining the data. The computations are compared with experimental data. It has been demonstrated that the computational fluid dynamics code coupled with chemical reaction well predict the SWR. (authors)

  15. The Path a Proton Takes Through a Fuel Cell Membrane

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Path a Proton Takes Through a Fuel Cell Membrane The Path a Proton Takes Through a Fuel Cell Membrane October 11, 2012 Linda Vu, lvu@lbl.gov, +1 510 495 2402 Ram.jpg The cover represents the environment around the side chain. The right side is the water network that exists between the sulfonate groups shown in yellow. The left side is the short chain with the sulfonate group. Many experts believe that fuel cells may someday serve as revolutionary clean energy conversion devices for

  16. Clear Path IV Exercise Summary Report

    Broader source: Energy.gov [DOE]

    In April 2016, DOE led Clear Path IV in Portland, Oregon and Washington, DC. Clear Path IV was an interagency exercise focused on testing and evaluating energy sector response plans to address...

  17. PathScale Compliers at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1-800-66-NERSC, option 3 or 510-486-8611 Home For Users Software Compilers PathScale PathScale Compilers (Fortran, C, C++) Availability The Pathscale...

  18. Liquid metal cooled nuclear reactors

    SciTech Connect (OSTI)

    Barnes, S.

    1980-10-07

    The vault of a liquid metal cooled nuclear reactor is lined with thermal insulation. The insulation is in two layers, a first layer cladding the vault surface is of solid ceramic material while a second layer cladding the first layer is of fibrous or metallic material. In the event of a breach of the vessel leakage of liquid metal is absorbed by the second layer providing a conduction path to the first layer thereby enhancing heat loss to the concrete of the vault and maintaining the internal temperature at a safe limit.

  19. Graphene-based battery electrodes having continuous flow paths

    DOE Patents [OSTI]

    Zhang, Jiguang; Xiao, Jie; Liu, Jun; Xu, Wu; Li, Xiaolin; Wang, Deyu

    2014-05-24

    Some batteries can exhibit greatly improved performance by utilizing electrodes having randomly arranged graphene nanosheets forming a network of channels defining continuous flow paths through the electrode. The network of channels can provide a diffusion pathway for the liquid electrolyte and/or for reactant gases. Metal-air batteries can benefit from such electrodes. In particular Li-air batteries show extremely high capacities, wherein the network of channels allow oxygen to diffuse through the electrode and mesopores in the electrode can store discharge products.

  20. The STEM Path to Antarctica

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    STEM skills Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue: September 1, 2016 all issues All Issues » submit The STEM Path to Antarctica Nina Lanza, a staff scientist at the Laboratory realizes her dream of being a space scientist and hunts for space rocks at the ends of the earth March 1, 2016 Nina Lanza, a staff scientist on the ChemCam instrument team for the Curiosity Mars Rover, spent two month on the frozen glaciers with the

  1. TowPath Renewable Ventures | Open Energy Information

    Open Energy Info (EERE)

    TowPath Renewable Ventures Jump to: navigation, search Name: TowPath Renewable Ventures Place: Washington, Washington, DC Zip: 20007 Sector: Renewable Energy Product: TowPath...

  2. LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Thornton, J.D.

    1957-12-31

    This patent relates to liquid-liquid extraction columns having a means for pulsing the liquid in the column to give it an oscillatory up and down movement, and consists of a packed column, an inlet pipe for the dispersed liquid phase and an outlet pipe for the continuous liquid phase located in the direct communication with the liquid in the lower part of said column, an inlet pipe for the continuous liquid phase and an outlet pipe for the dispersed liquid phase located in direct communication with the liquid in the upper part of said column, a tube having one end communicating with liquid in the lower part of said column and having its upper end located above the level of said outlet pipe for the dispersed phase, and a piston and cylinder connected to the upper end of said tube for applying a pulsating pneumatic pressure to the surface of the liquid in said tube so that said surface rises and falls in said tube.

  3. Purple Path toward High Temperature Superconductivity? | The Ames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory Purple Path toward High Temperature Superconductivity? Discovery of an unconventional charge density wave (CDW) in purple bronze, a molybdenum oxide, points to a possible new pathway to high temperature superconductivity. A CDW is a state of matter where electrons bunch together periodically, like a standing wave of light or water. CDWs and superconductivity are frenemies, since they share a common origin and often coexist, yet compete for dominance. Conventional CDWs and

  4. Prescriptive Path compliance form | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Prescriptive Path compliance form Prescriptive Path compliance form This Prescriptive Path compliance form shall be submitted to: doechallengehome@newportpartnersllc.com challenge_home_prescriptive_compliance_5-12.docx (20.98 KB) More Documents & Publications Version Tracking Document for DOE Challenge Homes, National Program Requirements (Rev. 03) DOE Zero Energy Ready Home National Program Requirements (Rev. 04) Washington DOE ZERH Program Requirements

  5. Formation of iron complexs from trifluoroacetic acid based liquid...

    Office of Scientific and Technical Information (OSTI)

    spectrometric analysis of liquid chromatography ... Accurate mass measurement and tandem mass spectrometry ... WATER Electrospray; System; Contaminants; Cell; ...

  6. Flight Path Target 4 East Port

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 East Port Target 4 East Port Links Flight Path Overview Target 4 East Port About Target 4 East Port Collaborators Publications Links

  7. Career Paths | National Nuclear Security Administration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Paths | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy...

  8. ClearPath | Open Energy Information

    Open Energy Info (EERE)

    TOOL Name: ClearPath AgencyCompany Organization: ICLEI Local Governmets for Sustainability USA Sector: Climate Focus Area: GHG Inventory Development, Greenhouse Gas Phase:...

  9. Critical function and success path summary display

    DOE Patents [OSTI]

    Scarola, Kenneth; Jamison, David S.; Manazir, Richard M.; Rescorl, Robert L.; Harmon, Daryl L.

    1995-01-01

    The content of and hierarchical access to three levels of display pages containing information on critical function monitoring and success path monitoring.

  10. Flight Path 15L - Chi-Nu

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    L This flight path is primarily used for the Chi-Nu experiments at 22 meters and neutron detector development and calibration at 90 meters. Target 4 Flight Path 15L (Chi-Nu) Target 4 Flight Path 15L (4FP15L) utilizes the neutrons that are produced at an angle of 15-degrees to the incident proton beam from the spallation source. It is unique among the WNR flight paths in that it has two experimental locations available at distances of 22 and 90 meters from the spallation target. The rectangular

  11. Flight Path Target 4 East Port

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4 East Port Target 4 East Port Links Flight Path Overview Target 4 East Port About Target 4 East Port Collaborators Publications Links

  12. LIQUID TARGET

    DOE Patents [OSTI]

    Martin, M.D.; Salsig, W.W. Jr.

    1959-01-13

    A liquid handling apparatus is presented for a liquid material which is to be irradiated. The apparatus consists essentially of a reservoir for the liquid, a target element, a drain tank and a drain lock chamber. The target is in the form of a looped tube, the upper end of which is adapted to be disposed in a beam of atomic particles. The lower end of the target tube is in communication with the liquid in the reservoir and a means is provided to continuously circulate the liquid material to be irradiated through the target tube. Means to heat the reservoir tank is provided in the event that a metal is to be used as the target material. The apparatus is provided with suitable valves and shielding to provide maximum safety in operation.

  13. Methodology for Augmenting Existing Paths with Additional Parallel Transects

    SciTech Connect (OSTI)

    Wilson, John E.

    2013-09-30

    Visual Sample Plan (VSP) is sample planning software that is used, among other purposes, to plan transect sampling paths to detect areas that were potentially used for munition training. This module was developed for application on a large site where existing roads and trails were to be used as primary sampling paths. Gap areas between these primary paths needed to found and covered with parallel transect paths. These gap areas represent areas on the site that are more than a specified distance from a primary path. These added parallel paths needed to optionally be connected together into a single paththe shortest path possible. The paths also needed to optionally be attached to existing primary paths, again with the shortest possible path. Finally, the process must be repeatable and predictable so that the same inputs (primary paths, specified distance, and path options) will result in the same set of new paths every time. This methodology was developed to meet those specifications.

  14. Temperature, Water Vapor, and Clouds"

    Office of Scientific and Technical Information (OSTI)

    Radiometric Studies of Temperature, Water Vapor, and Clouds" Project ID: 0011106 ... measurements of column amounts of water vapor and cloud liquid has been well ...

  15. Satellite determination of stratus cloud microphysical properties...

    Office of Scientific and Technical Information (OSTI)

    of liquid water path from SSMI, broadband albedo from ERBE, and cloud characteristics from ISCCP are used to study stratus regions. An average cloud liquid water path of ...

  16. Flight Path 30L - ICE House

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    L The shape of the neutron spectrum on the 30° flight paths is very similar to that of neutrons produced in the atmosphere by cosmic rays but with a neutron flux a million times higher, depending on altitude. This large flux allows testing of semiconductor devices at greatly accelerated rates. Target 4 Flight Path 30L (ICE House) Target 4 Flight Path 30L (4FP30L) utilizes the neutrons that scatter off the tungsten spallation source at approximately 30 degrees to beam left. The experiments

  17. Flight Path 30R | ICE II

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    R The shape of the neutron spectrum here is very similar to that of neutrons produced in the atmosphere by cosmic rays but with a neutron flux a million times higher, depending on altitude. This large flux allows testing of semiconductor devices at greatly accelerated rates. Target 4 Flight Path 30R (ICE II) Target 4 Flight Path 30R (4FP30R) utilizes the neutrons that scatter off the tungsten spallation source at approximately 30 degrees to beam right. The experiments utilizing this flight path

  18. Variable path length spectrophotometric probe

    DOE Patents [OSTI]

    O'Rourke, Patrick E.; McCarty, Jerry E.; Haggard, Ricky A.

    1992-01-01

    A compact, variable pathlength, fiber optic probe for spectrophotometric measurements of fluids in situ. The probe comprises a probe body with a shaft having a polished end penetrating one side of the probe, a pair of optic fibers, parallel and coterminous, entering the probe opposite the reflecting shaft, and a collimating lens to direct light from one of the fibers to the reflecting surface of the shaft and to direct the reflected light to the second optic fiber. The probe body has an inlet and an outlet port to allow the liquid to enter the probe body and pass between the lens and the reflecting surface of the shaft. A linear stepper motor is connected to the shaft to cause the shaft to advance toward or away from the lens in increments so that absorption measurements can be made at each of the incremental steps. The shaft is sealed to the probe body by a bellows seal to allow freedom of movement of the shaft and yet avoid leakage from the interior of the probe.

  19. Study concerning the utilization of the ocean spreading center environment for the conversion of biomass to a liquid fuel. (Includes Appendix A: hydrothermal petroleum genesis). [Supercritical water

    SciTech Connect (OSTI)

    Steverson, M.; Stormberg, G.

    1985-01-01

    This document contains a report on the feasibility of utilizing energy obtained from ocean spreading centers as process heat for the conversion of municipal solid wastes to liquid fuels. The appendix contains a paper describing hydrothermal petroleum genesis. Both have been indexed separately for inclusion in the Energy Data Base. (DMC)

  20. Microfluidics Transport and Path Control via Programmable Electrowetting on Dielectric

    SciTech Connect (OSTI)

    Theodore W. Von Bitner, Ph.D.

    2002-08-22

    This research was conducted in collaboration with Professor Chang-Jin Kim of the University of California, Los Angeles. In phase I, the IOS-UCLA collaboration demonstrated the transport and manipulation of insulting liquid droplets using the principles of EWOD. A postage stamp sized array of electronically addressable Teflon pads, whose surface tension characteristics could be altered on command through computer algorithms, was developed and tested using deionized water as the liquid. Going beyond the tasks originally proposed for Phase I, droplet manipulation was achieved and droplet stability in the EWOD device was examined.

  1. Flight Path 90L - About TPC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 to 15m long. Instruments used on this flight path have included fission chambers and the fission Time Projection Chamber (TPC). tpc2 Partial view of FP90L (2013)...

  2. Vibrational Spectroscopy of Liquid Mixtures and Solid/Liquid Interfaces |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Argonne Leadership Computing Facility Simulations were carried out with the Qbox code Square modulus ( blue surface) of the highest occupied orbital (HOMO) of a chloride anion (green sphere) in liquid water (oxygen and hydrogen atoms are represented by red and white spheres, respectively), as obtained with ab initio molecular dynamics simulations using hybrid functionals. The relative positions of the anion HOMO and the valence band maximum (VBM) and conduction band minimum (CBM) of liquid

  3. FACT SHEET: The Path Forward on Nuclear Waste Disposal | Department...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FACT SHEET: The Path Forward on Nuclear Waste Disposal FACT SHEET: The Path Forward on Nuclear Waste Disposal FACT SHEET: The Path Forward on Nuclear Waste Disposal More Documents...

  4. EIA - Natural Gas Pipeline Network - Natural Gas Transmission Path Diagram

    U.S. Energy Information Administration (EIA) Indexed Site

    Transmission Path Diagram About U.S. Natural Gas Pipelines - Transporting Natural Gas based on data through 2007/2008 with selected updates Natural Gas Transmission Path Natural Gas Transmission Path

  5. Path optimization with limited sensing ability

    SciTech Connect (OSTI)

    Kang, Sung Ha Kim, Seong Jun Zhou, Haomin

    2015-10-15

    We propose a computational strategy to find the optimal path for a mobile sensor with limited coverage to traverse a cluttered region. The goal is to find one of the shortest feasible paths to achieve the complete scan of the environment. We pose the problem in the level set framework, and first consider a related question of placing multiple stationary sensors to obtain the full surveillance of the environment. By connecting the stationary locations using the nearest neighbor strategy, we form the initial guess for the path planning problem of the mobile sensor. Then the path is optimized by reducing its length, via solving a system of ordinary differential equations (ODEs), while maintaining the complete scan of the environment. Furthermore, we use intermittent diffusion, which converts the ODEs into stochastic differential equations (SDEs), to find an optimal path whose length is globally minimal. To improve the computation efficiency, we introduce two techniques, one to remove redundant connecting points to reduce the dimension of the system, and the other to deal with the entangled path so the solution can escape the local traps. Numerical examples are shown to illustrate the effectiveness of the proposed method.

  6. Path Integral for Stochastic Inflation: Non-Perturbative Volume...

    Office of Scientific and Technical Information (OSTI)

    Path Integral for Stochastic Inflation: Non-Perturbative Volume Weighting, Complex ... Title: Path Integral for Stochastic Inflation: Non-Perturbative Volume Weighting, Complex ...

  7. EIS-0516: Clean Path Energy Center Project; San Juan County,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Path Energy Center Project; San Juan County, New Mexico EIS-0516: Clean Path Energy Center Project; San Juan County, New Mexico Summary DOE's Western Area Power Administration is ...

  8. Path to Deterministic Single Donor Devices using Focused Top...

    Office of Scientific and Technical Information (OSTI)

    Path to Deterministic Single Donor Devices using Focused Top-Down Ion Implantation. Citation Details In-Document Search Title: Path to Deterministic Single Donor Devices using ...

  9. New Reports Chart Offshore Wind's Path Forward | Department of...

    Office of Environmental Management (EM)

    Reports Chart Offshore Wind's Path Forward New Reports Chart Offshore Wind's Path Forward ... The answer to this question, among many others, is explored in two new reports released ...

  10. The Path to Program Sustainability | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Path to Program Sustainability The Path to Program Sustainability The strategies outlined below help create self-sustaining clean energy finance programs. Prove Energy ...

  11. Commercial Light Water Production of Tritium: Update and Path Forward

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation from the 32nd Tritium Focus Group Meeting held in Germantown, Maryland on April 23-25, 2013.

  12. Commercial Light Water Production of Tritium Update and Path...

    Office of Environmental Management (EM)

    ... SOLID BOTTOM END PLUG LOWER CRUCIFORM SPACER A B CROSS SECTION Nom 1" PELLETS A A INNER LINER PELLET STACKS with - Nominal 1" Pellets - Inner Liner Nom 1" PELLETS UPPER CRUCIFORM ...

  13. Hybrid Rotor Compression for Multiphase and Liquids-Rich Wellhead

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    but also allows for compression of wet gas, or gas that contains liquid content. At many natural gas wellheads, liquids-typically heavier hydrocarbons and water-are present in the...

  14. Adaptive path planning algorithm for cooperating unmanned air vehicles

    SciTech Connect (OSTI)

    Cunningham, C T; Roberts, R S

    2001-02-08

    An adaptive path planning algorithm is presented for cooperating Unmanned Air Vehicles (UAVs) that are used to deploy and operate land-based sensor networks. The algorithm employs a global cost function to generate paths for the UAVs, and adapts the paths to exceptions that might occur. Examples are provided of the paths and adaptation.

  15. An Adaptive Path Planning Algorithm for Cooperating Unmanned Air Vehicles

    SciTech Connect (OSTI)

    Cunningham, C.T.; Roberts, R.S.

    2000-09-12

    An adaptive path planning algorithm is presented for cooperating Unmanned Air Vehicles (UAVs) that are used to deploy and operate land-based sensor networks. The algorithm employs a global cost function to generate paths for the UAVs, and adapts the paths to exceptions that might occur. Examples are provided of the paths and adaptation.

  16. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, Amy A.

    1994-01-01

    A dropping electrolyte electrode for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions.

  17. Intercomparison of the Cloud Water Phase among Global Climate Models

    SciTech Connect (OSTI)

    Komurcu, Muge; Storelvmo, Trude; Tan, Ivy; Lohmann, U.; Yun, Yuxing; Penner, Joyce E.; Wang, Yong; Liu, Xiaohong; Takemura, T.

    2014-03-27

    Mixed-phase clouds (clouds that consist of both cloud droplets and ice crystals) are frequently present in the Earths atmosphere and influence the Earths energy budget through their radiative properties, which are highly dependent on the cloud water phase. In this study, the phase partitioning of cloud water is compared among six global climate models (GCMs) and with Cloud and Aerosol Lidar with Orthogonal Polarization retrievals. It is found that the GCMs predict vastly different distributions of cloud phase for a given temperature, and none of them are capable of reproducing the spatial distribution or magnitude of the observed phase partitioning. While some GCMs produced liquid water paths comparable to satellite observations, they all failed to preserve sufficient liquid water at mixed-phase cloud temperatures. Our results suggest that validating GCMs using only the vertically integrated water contents could lead to amplified differences in cloud radiative feedback. The sensitivity of the simulated cloud phase in GCMs to the choice of heterogeneous ice nucleation parameterization is also investigated. The response to a change in ice nucleation is quite different for each GCM, and the implementation of the same ice nucleation parameterization in all models does not reduce the spread in simulated phase among GCMs. The results suggest that processes subsequent to ice nucleation are at least as important in determining phase and should be the focus of future studies aimed at understanding and reducing differences among the models.

  18. On the Path to SunShot- Environmental Benefits of Solar

    Office of Energy Efficiency and Renewable Energy (EERE)

    In the On the Path to SunShot report series, the Environmental and Public Health Benefits of Achieving High Penetration of Solar Energy in the United States report highlights how increasing the amount of solar energy connected to the grid will benefit the environment by reducing water scarcity, curbing pollution, mitigating climate change, and creating better health outcomes.

  19. Analysis of methyl neodecanamide in lake water by reversed-phase high performance liquid chromatography and gas chromatography-mass spectrometry

    SciTech Connect (OSTI)

    Rasmussen, H.T.; Friedman, S.K.; Mustilli, A.J.; McDonough, R.; McPherson, B.P. )

    1994-01-01

    Methyl Neodecanamide (MNDA) has been quantified in lake water at levels of 0.1 to 1,000 ppm. Total recoveries from spiked placebos were 99.8 [+-] 2.3% at the 1,000 ppm level and 98.3 [+-] 4.3% at the 0.1 ppm level (based on 54 determinations at each level). Plots of actual concentrations vs. determined concentrations were linear from 0.07--0.13 and 700--1,300 ppm (r > 0.999). Stability of MNDA in lake water was verified by determining the composition by GC/MS immediately after dissolution and after 3 days.

  20. Folded-path optical analysis gas cell

    DOE Patents [OSTI]

    Carangelo, R.M.; Wright, D.D.

    1995-08-08

    A folded-path gas cell employs an elliptical concave mirror in confronting relationship to two substantially spherical concave mirrors. At least one of the spherical mirrors, and usually both, are formed with an added cylindrical component to increase orthogonal foci coincidence and thereby to increase the radiation energy throughput characteristic of the cell. 10 figs.

  1. Folded-path optical analysis gas cell

    DOE Patents [OSTI]

    Carangelo, Robert M. (Glastonbury, CT); Wright, David D. (Vershire, VT)

    1995-01-01

    A folded-path gas cell employs an elliptical concave mirror in confronting relationship to two substantially spherical concave mirrors. At least one of the spherical mirrors, and usually both, are formed with an added cylindrical component to increase orthogonal focii coincidence and thereby to increase the radiation energy throughput characteristic of the cell.

  2. Liquid electrode

    DOE Patents [OSTI]

    Ekechukwu, A.A.

    1994-07-05

    A dropping electrolyte electrode is described for use in electrochemical analysis of non-polar sample solutions, such as benzene or cyclohexane. The liquid electrode, preferably an aqueous salt solution immiscible in the sample solution, is introduced into the solution in dropwise fashion from a capillary. The electrolyte is introduced at a known rate, thus, the droplets each have the same volume and surface area. The electrode is used in making standard electrochemical measurements in order to determine properties of non-polar sample solutions. 2 figures.

  3. Bio-Derived Liquids to Hydrogen Distributed Reforming Working...

    Broader source: Energy.gov (indexed) [DOE]

    The Working Group is addressing technical challenges to distributed reforming of biomass-derived, renewable liquid fuels to hydrogen, including the reforming, water-gas shift, and ...

  4. Hybrid Quantum Mechanics/Molecular Mechanics-Based Molecular Dynamics Simulation of Acid-Catalyzed Dehydration of Polyols in Liquid Water

    SciTech Connect (OSTI)

    Caratzoulas, Stavros; Courtney, Timothy; Vlachos, Dionisios G.

    2011-01-01

    We use the conversion of protonated glycerol to acrolein for a case study of the mechanism of acid-catalyzed dehydration of polyols in aqueous environments. We employ hybrid Quamtum Mechanics/Molecular Mechanics Molecular Dynamics (QM/MM MD) simulations with biased sampling and perform free energy calculations for the elementary steps of the reaction. We investigate the effects of solvent dynamics and in particular the role of quantum mechanical water in the dehydration mechanism. We present results supporting a mechanism that proceeds via water-mediated proton transfers and thus through an enol intermediate. We find that the first dehydration may take place by two, low-energy pathways requiring, respectively, 20.9 and 18.8 kcal/mol of activation free energy. The second dehydration requires 19.9 kcal/mol of activation free energy while for the overall reaction we compute a free energy change of -8 kcal/mol.

  5. Membrane separation of ionic liquid solutions

    SciTech Connect (OSTI)

    Campos, Daniel; Feiring, Andrew Edward; Majumdar, Sudipto; Nemser, Stuart

    2015-09-01

    A membrane separation process using a highly fluorinated polymer membrane that selectively permeates water of an aqueous ionic liquid solution to provide dry ionic liquid. Preferably the polymer is a polymer that includes polymerized perfluoro-2,2-dimethyl-1,3-dioxole (PDD). The process is also capable of removing small molecular compounds such as organic solvents that can be present in the solution. This membrane separation process is suitable for drying the aqueous ionic liquid byproduct from precipitating solutions of biomass dissolved in ionic liquid, and is thus instrumental to providing usable lignocellulosic products for energy consumption and other industrial uses in an environmentally benign manner.

  6. Synchrotrons Explore Water's Molecular Mysteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Laboratory's Advanced Light Source, scientists observed a surprisingly dense form of water that remained liquid well beyond its typical freezing point. Researchers applied a...

  7. On the path integral of constrained systems

    SciTech Connect (OSTI)

    Muslih, Sami I.

    2004-10-04

    Constrained Hamiltonian systems are investigated by using Gueler's method. Integration of a set of equations of motion and the action function is discussed. It is shown that the canonical path integral quantization is obtained directly as an integration over the canonical phase-space coordinates without any need to enlarge the initial phase-space by introducing extra- unphysical variables as in the Batalin-Fradkin-Tyutin (BFT) method. The abelian Proca model is analyzed by the two methods.

  8. PathSci | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PathSci The Princeton Plasma Physics Laboratory's Pathways to Science program is now partnering with ARISE (Advanced Research and Innovation in Science Education) and the Association of Women in Science of Central NJ to build a community of mentorship among students and scientists. Together, we provide students in the New Jersey area with sustained exposure to and inspiration from scientists of all backgrounds. Students: Our partners at ARISE will try to match you with a mentor as soon as

  9. The Flight Paths for Biojet Fuel

    U.S. Energy Information Administration (EIA) Indexed Site

    Flight Paths for Biojet Fuel Tony Radich October 9, 2015 Independent Statistics & Analysis www.eia.gov U.S. Energy Information Administration Washington, DC 20585 This paper is released to encourage discussion and critical comment. The analysis and conclusions expressed here are those of the authors and not necessarily those of the U.S. Energy Information Administration. WORKING PAPER SERIES October 2015 Tony Radich | U.S. Energy Information Administration | This paper is released to

  10. Flight Path 30R - About ICE II

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    flight path of WNR. At this angle, the shape of the neutron spectrum here is very similar to that of neutrons produced in the atmosphere by cosmic rays but with a neutron flux a million times higher, depending on altitude. This large flux allows testing of semiconductor devices at greatly accelerated rates. Companies from around the world can use the WNR high-energy-neutron source to characterize components and study various failure modes caused by neutron radiation Accelerated Neutron Testing

  11. Video Highlights Accomplishments, Path Forward for WIPP

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    March 17, 2016 Video Highlights Accomplishments, Path Forward for WIPP Participants at the Waste Management Symposium in Phoenix learned last week about the progress that has been made to recover the Department of Energy's Waste Isolation Pilot Plant (WIPP) and what steps remain to restart WIPP, the nation's only deep-geologic repository for defense transuranic waste later this year. As part of the update, WIPP's leadership team showed a short video that provides key elements of the recovery

  12. Development of a promising filtration method for liquid clarification in nuclear facilities. [For TMI-2 water, reprocessing dissolver solutions, ZnBr/sub 2/ shielding solutions

    SciTech Connect (OSTI)

    Collins, E.D.; Knauer, J.B.; Byrd, L.A.; Ross, R.G.; Savage, H.C.

    1982-01-01

    Conclusions reached are that deep beds of diatomaceous earths are especially attractive for clarification of radioactive solutions, or slurries containing insoluble radioactive material, because the diatomaceous material provides a noncompressible medium that is retentive for a wide variety of particle sizes. Also, the diatomaceous material, because of its inorganic composition, is resistant to degradation by radiation from the retained particulate matter. Its silicious character is especially appropriate for conversion to vitrified or cement-type waste forms. This paper studied the use of diatomaceous earth to filter synthetic TMI-2 water, reprocessing dissolver solutions, and zinc bromide solutions (hot-cell shielding).

  13. Sewage sludge dewatering using flowing liquid metals

    DOE Patents [OSTI]

    Carlson, Larry W.

    1986-01-01

    A method and apparatus for reducing the moisture content of a moist sewage sludge having a moisture content of about 50% to 80% and formed of small cellular micro-organism bodies having internally confined water is provided. A hot liquid metal is circulated in a circulation loop and the moist sewage sludge is injected in the circulation loop under conditions of temperature and pressure such that the confined water vaporizes and ruptures the cellular bodies. The vapor produced, the dried sludge, and the liquid metal are then separated. Preferably, the moist sewage sludge is injected into the hot liquid metal adjacent the upstream side of a venturi which serves to thoroughly mix the hot liquid metal and the moist sewage sludge. The venturi and the drying zone after the venturi are preferably vertically oriented. The dried sewage sludge recovered is available as a fuel and is preferably used for heating the hot liquid metal.

  14. Solar Decathlon 2013 Infographic: The Path to a Brighter Future...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Infographic: The Path to a Brighter Future Solar Decathlon 2013 Infographic: The Path to a Brighter Future September 13, 2013 - 11:50am Addthis Our latest infographic -- Solar...

  15. The Path a Proton Takes Through a Fuel Cell Membrane

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Path a Proton Takes Through a Fuel Cell Membrane The Path a Proton Takes Through a Fuel Cell Membrane October 11, 2012 Linda Vu, lvu@lbl.gov, +1 510 495 2402 Ram.jpg The cover ...

  16. Solar Decathlon 2013 Infographic: The Path to a Brighter Future...

    Energy Savers [EERE]

    Infographic: The Path to a Brighter Future Solar Decathlon 2013 Infographic: The Path to a Brighter Future September 13, 2013 - 11:50am Addthis Our latest infographic -- Solar ...

  17. A Surprising Path for Proton Transfer Without Hydrogen Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Surprising Path for Proton Transfer Without Hydrogen Bonds A Surprising Path for Proton Transfer Without Hydrogen Bonds Print Wednesday, 25 July 2012 00:00 Hydrogen bonds are...

  18. Working with Utilities: Effective Paths for Tribal Governments...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Working with Utilities: Effective Paths for Tribal Governments Webinar Working with Utilities: Effective Paths for Tribal Governments Webinar September 30, 2015 11:00AM to 12:30PM...

  19. EECBG Success Story: Atlanta Suburb Greases the Path to Savings...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Atlanta Suburb Greases the Path to Savings with Biodiesel EECBG Success Story: Atlanta Suburb Greases the Path to Savings with Biodiesel December 7, 2011 - 3:33pm Addthis Downtown ...

  20. Rapid microwave hydrothermal synthesis of ZnGa{sub 2}O{sub 4} with high photocatalytic activity toward aromatic compounds in air and dyes in liquid water

    SciTech Connect (OSTI)

    Sun Meng; Li Danzhen; Zhang Wenjuan; Chen Zhixin; Huang Hanjie; Li Wenjuan; He Yunhui; Fu Xianzhi

    2012-06-15

    ZnGa{sub 2}O{sub 4} was synthesized from Ga(NO{sub 3}){sub 3} and ZnCl{sub 2} via a rapid and facile microwave-assisted hydrothermal method. The photocatalytic properties of the as-prepared ZnGa{sub 2}O{sub 4} were evaluated by the degradation of pollutants in air and aqueous solution under ultraviolet (UV) light illumination. The results demonstrated that ZnGa{sub 2}O{sub 4} had exhibited efficient photocatalytic activities higher than that of commercial P25 (Degussa Co.) in the degradation of benzene, toluene, and ethylbenzene, respectively. In the liquid phase degradation of dyes (methyl orange, Rhodamine B, and methylene blue), ZnGa{sub 2}O{sub 4} has also exhibited remarkable activities higher than that of P25. After 32 min of UV light irradiation, the decomposition ratio of methyl orange (10 ppm, 150 mL) over ZnGa{sub 2}O{sub 4} (0.06 g) was up to 99%. The TOC tests revealed that the mineralization ratio of MO (10 ppm, 150 mL) was 88.1% after 90 min of reaction. A possible mechanism of the photocatalysis over ZnGa{sub 2}O{sub 4} was also proposed. - Graphical abstract: In the degradation of RhB under UV light irradiation, ZnGa{sub 2}O{sub 4} had exhibited efficient photo-activity, and after only 24 min of irradiation the decomposition ratio was up to 99.8%. Highlights: Black-Right-Pointing-Pointer A rapid and facile M-H method to synthesize ZnGa{sub 2}O{sub 4} photocatalyst. Black-Right-Pointing-Pointer The photocatalyst exhibits high activity toward benzene and dyes. Black-Right-Pointing-Pointer The catalyst possesses more surface hydroxyl sites than TiO{sub 2} (P25). Black-Right-Pointing-Pointer Deep oxidation of different aromatic compounds and dyes over catalyst.

  1. Liquid CO{sub 2}/Coal Slurry for Feeding Low Rank Coal to Gasifiers

    SciTech Connect (OSTI)

    Marasigan, Jose; Goldstein, Harvey; Dooher, John

    2013-09-30

    This study investigates the practicality of using a liquid CO{sub 2}/coal slurry preparation and feed system for the E-Gas™ gasifier in an integrated gasification combined cycle (IGCC) electric power generation plant configuration. Liquid CO{sub 2} has several property differences from water that make it attractive for the coal slurries used in coal gasification-based power plants. First, the viscosity of liquid CO{sub 2} is much lower than water. This means it should take less energy to pump liquid CO{sub 2} through a pipe compared to water. This also means that a higher solids concentration can be fed to the gasifier, which should decrease the heat requirement needed to vaporize the slurry. Second, the heat of vaporization of liquid CO{sub 2} is about 80% lower than water. This means that less heat from the gasification reactions is needed to vaporize the slurry. This should result in less oxygen needed to achieve a given gasifier temperature. And third, the surface tension of liquid CO{sub 2} is about 2 orders of magnitude lower than water, which should result in finer atomization of the liquid CO{sub 2} slurry, faster reaction times between the oxygen and coal particles, and better carbon conversion at the same gasifier temperature. EPRI and others have recognized the potential that liquid CO{sub 2} has in improving the performance of an IGCC plant and have previously conducted systemslevel analyses to evaluate this concept. These past studies have shown that a significant increase in IGCC performance can be achieved with liquid CO{sub 2} over water with certain gasifiers. Although these previous analyses had produced some positive results, they were still based on various assumptions for liquid CO{sub 2}/coal slurry properties. This low-rank coal study extends the existing knowledge base to evaluate the liquid CO{sub 2}/coal slurry concept on an E-Gas™-based IGCC plant with full 90% CO{sub 2} capture. The overall objective is to determine if this

  2. High order Chin actions in path integral Monte Carlo

    SciTech Connect (OSTI)

    Sakkos, K.; Casulleras, J.; Boronat, J.

    2009-05-28

    High order actions proposed by Chin have been used for the first time in path integral Monte Carlo simulations. Contrary to the Takahashi-Imada action, which is accurate to the fourth order only for the trace, the Chin action is fully fourth order, with the additional advantage that the leading fourth-order error coefficients are finely tunable. By optimizing two free parameters entering in the new action, we show that the time step error dependence achieved is best fitted with a sixth order law. The computational effort per bead is increased but the total number of beads is greatly reduced and the efficiency improvement with respect to the primitive approximation is approximately a factor of 10. The Chin action is tested in a one-dimensional harmonic oscillator, a H{sub 2} drop, and bulk liquid {sup 4}He. In all cases a sixth-order law is obtained with values of the number of beads that compare well with the pair action approximation in the stringent test of superfluid {sup 4}He.

  3. Path to High Efficiency Gasoline Engine | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Path to High Efficiency Gasoline Engine Path to High Efficiency Gasoline Engine Path to High Efficiency Gasoline Engine deer10_johansson.pdf (4.97 MB) More Documents & Publications Partially Premixed Combustion High-Efficiency, Ultra-Low Emission Combustion in a Heavy-Duty Engine via Fuel Reactivity Control Advanced Lean-Burn DI Spark Ignition Fuels Research

  4. REDISTRIBUTOR FOR LIQUID-LIQUID EXTRACTION COLUMNS

    DOE Patents [OSTI]

    Bradley, J.G.

    1957-10-29

    An improved baffle plate construction to intimately mix immiscible liquid solvents for solvent extraction processes in a liquid-liquid pulse column is described. To prevent the light and heavy liquids from forming separate continuous homogeneous vertical channels through sections of the column, a baffle having radially placed rectangular louvers with deflection plates opening upon alternate sides of the baffle is placed in the column, normal to the axis. This improvement substantially completely reduces strippiig losses due to poor mixing.

  5. Sensor for detection of liquid spills on surfaces

    DOE Patents [OSTI]

    Davis, Brent C.; Gayle, Tom M.

    1989-07-04

    A surface liquid detector is disclosed for detecting liquids spilled on surfaces such as floors. A temperature-sensitive thermistor probe is used in a bridge circuit to detect the change in resistance in the thermistor due to the change in thermal conductivity that occurs when a liquid contacts the probe. The device is characterized by the ability to detect either conductive or nonconductive liquids, such as water or oil spills.

  6. Sensor for detection of liquid spills on surfaces

    DOE Patents [OSTI]

    Davis, Brent C.; Gayle, Tom M.

    1989-01-01

    A surface liquid detector is disclosed for detecting liquids spilled on surfaces such as floors. A temperature-sensitive thermistor probe is used in a bridge circuit to detect the change in resistance in the thermistor due to the change in thermal conductivity that occurs when a liquid contacts the probe. The device is characterized by the ability to detect either conductive or nonconductive liquids, such as water or oil spills.

  7. Vertical tube liquid pollutant separators

    SciTech Connect (OSTI)

    Lynch, W.M.

    1982-06-08

    A plurality of elongated hollow, circular, foraminous substantially vertical tubes contiguously stacked transversely to the direction flowing liquid such as waste water containing foreign matter, I.E., settable solids and free oil, in a coalescer-separator apparatus provide a filter body providing for significant surface area contact by the liquid on both inside and outside surfaces of the tubes to entrap the foreign matter but defining substantially vertical passages permitting the entrapped foreign matter to be gravity separated with the lighter matter coalescing and floating upwardly and the heavier matter settling downwardly so that substantially clarified effluent flows from the apparatus. The stacked tube filter body is contained within an insulated closed container of a sufficient capacity, and the arrays of holes in the tube walls are coordinated with respect to the intended volumetric capacity of the apparatus, so that turbulence in the liquid flowing through the filter body is minimized.

  8. 2007 Report Appendix - Path Charts - Final for posting 122007.xls

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ranking Maximum Seasonal Values from 1999 through 2005 % of Time Path Actual Flow exceeds 75% of Path OTC 0 10 20 30 40 50 60 70 80 90 100 19 50 22 47 30 36 3 8 48 35 17 66 65 15 31 1 26 45 49 18 20 34 51 14 WECC Path Number % Time Path Flow Exceeds 75% of OTC W Sp Su Represents the highest Seasonal Loading for each Path, from 1999 thru 2005 50% of Time 25% of Time Bridger West Cholla - Pinnacle Pk SW of 4C S. New Mex. TOT 1A (CO to Utah) TOT 3 (WY to CO)

  9. Flight Path 30L - About ICE House

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    L The shape of the neutron spectrum here is very similar to that of neutrons produced in the atmosphere by cosmic rays but with a neutron flux a million times higher, depending on altitude. This large flux allows testing of semiconductor devices at greatly accelerated rates. About ICE House Irradiation of Chips Electronics (ICE House) is located on the 30° flight path of WNR. At this angle, the shape of the neutron spectrum here is very similar to that of neutrons produced in the atmosphere by

  10. Flight Path 60R - About GEANIE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Target 4 Flight Path 60R (GEANIE) GErmanium Array for Neutron Induced Excitations (GEANIE) is the first large-scale, escape-suppressed, high-resolution gamma-ray spectrometer to be used at a white neutron source. It is now installed at the WNR high-energy neutron facility at LANSCE. The operation and upgrade of GEANIE is a joint project of the Lawrence Livermore and Los Alamos National Laboratories, funded primarily by the Stockpile Stewardship program of the NNSA. geanie2 The GEANIE Array